WorldWideScience

Sample records for surface tension gas

  1. Nanofluidic bubble pump using surface tension directed gas injection

    NARCIS (Netherlands)

    Tas, Niels Roelof; Berenschot, Johan W.; Lammerink, Theodorus S.J.; Elwenspoek, Michael Curt; van den Berg, Albert

    2002-01-01

    A new concept for liquid manipulation has been developed and implemented in surface-micromachined fluid channels. It is based on the surface tension directed injection of a gas into the liquid flow through micrometer-sized holes in the microchannel wall. The injected gas is directed to an exhaust by

  2. Nonzero Ideal Gas Contribution to the Surface Tension of Water.

    Science.gov (United States)

    Sega, Marcello; Fábián, Balázs; Jedlovszky, Pál

    2017-06-15

    Surface tension, the tendency of fluid interfaces to behave elastically and minimize their surface, is routinely calculated as the difference between the lateral and normal components of the pressure or, invoking isotropy in momentum space, of the virial tensor. Here we show that the anisotropy of the kinetic energy tensor close to a liquid-vapor interface can be responsible for a large part of its surface tension (about 15% for water, independent from temperature).

  3. A hybrid model to predict the onset of gas entrainment with surface tension effects

    International Nuclear Information System (INIS)

    Saleh, W.; Bowden, R.C.; Hassan, I.G.; Kadem, L.

    2008-01-01

    The onset of gas entrainment, in a single downward oriented discharge from a stratified gas-liquid region with was modeled. The assumptions made in the development of the model reduced the problem to that of a potential flow. The discharge was modeled as a point-sink. Through use of the Kelvin-Laplace equation the model included the effects of surface tension. The resulting model required further knowledge of the flow field, specifically the dip radius of curvature prior to the onset of gas entrainment. The dip shape and size was investigated experimentally and correlations were provided to characterize the dip in terms of the discharge Froude number. The experimental correlation was used in conjunction with the theoretical model to predict the critical height. The results showed that by including surface tension effects the predicted critical height showed excellent agreement with experimental data. Surface tension reduces the critical height through the Bond number

  4. Improvement of gas entrainment prediction method. Introduction of surface tension effect

    International Nuclear Information System (INIS)

    Ito, Kei; Sakai, Takaaki; Ohshima, Hiroyuki; Uchibori, Akihiro; Eguchi, Yuzuru; Monji, Hideaki; Xu, Yongze

    2010-01-01

    A gas entrainment (GE) prediction method has been developed to establish design criteria for the large-scale sodium-cooled fast reactor (JSFR) systems. The prototype of the GE prediction method was already confirmed to give reasonable gas core lengths by simple calculation procedures. However, for simplification, the surface tension effects were neglected. In this paper, the evaluation accuracy of gas core lengths is improved by introducing the surface tension effects into the prototype GE prediction method. First, the mechanical balance between gravitational, centrifugal, and surface tension forces is considered. Then, the shape of a gas core tip is approximated by a quadratic function. Finally, using the approximated gas core shape, the authors determine the gas core length satisfying the mechanical balance. This improved GE prediction method is validated by analyzing the gas core lengths observed in simple experiments. Results show that the analytical gas core lengths calculated by the improved GE prediction method become shorter in comparison to the prototype GE prediction method, and are in good agreement with the experimental data. In addition, the experimental data under different temperature and surfactant concentration conditions are reproduced by the improved GE prediction method. (author)

  5. In situ droplet surface tension and viscosity measurements in gas metal arc welding

    International Nuclear Information System (INIS)

    Bachmann, B; Siewert, E; Schein, J

    2012-01-01

    In this paper, we present an adaptation of a drop oscillation technique that enables in situ measurements of thermophysical properties of an industrial pulsed gas metal arc welding (GMAW) process. Surface tension, viscosity, density and temperature were derived expanding the portfolio of existing methods and previously published measurements of surface tension in pulsed GMAW. Natural oscillations of pure liquid iron droplets are recorded during the material transfer with a high-speed camera. Frame rates up to 30000 fps were utilized to visualize iron droplet oscillations which were in the low kHz range. Image processing algorithms were employed for edge contour extraction of the droplets and to derive parameters such as oscillation frequencies and damping rates along different dimensions of the droplet. Accurate surface tension measurements were achieved incorporating the effect of temperature on density. These are compared with a second method that has been developed to accurately determine the mass of droplets produced during the GMAW process which enables precise surface tension measurements with accuracies up to 1% and permits the study of thermophysical properties also for metals whose density highly depends on temperature. Thermophysical properties of pure liquid iron droplets formed by a wire with 1.2 mm diameter were investigated in a pulsed GMAW process with a base current of 100 A and a pulse current of 600 A. Surface tension and viscosity of a sample droplet were 1.83 ± 0.02 N m -1 and 2.9 ± 0.3 mPa s, respectively. The corresponding droplet temperature and density are 2040 ± 50 K and 6830 ± 50 kg m -3 , respectively. (paper)

  6. Measurement of the surface tension by the method of maximum gas bubble pressure

    International Nuclear Information System (INIS)

    Dugne, Jean

    1971-01-01

    A gas bubble method for measuring surface tension was studied. Theoretical investigations demonstrated that the maximum pressure can be represented by the envelope of a certain family of curves and that the physical nature of the capillary tube imposes an upper limit to its useful radius. With a given tube and a specified liquid, the dynamic evolution of the gas bubble depends only upon the variation of the mass of gas contained with time; this fact may restrict the choice of tubes. The use of one single tube requires important corrections. Computer treatment of the problem led to some accurate equations for calculating γ. Schroedinger equations and Sudgen's table are examined. The choice of tubes, the necessary corrections, density measurement, and the accuracy attainable are discussed. Experiments conducted with water and mercury using the sessile drop method and continuous recording of the pressure verified the theoretical ideas. (author) [fr

  7. A thermodynamical model for the surface tension of silicate melts in contact with H2O gas

    Science.gov (United States)

    Colucci, Simone; Battaglia, Maurizio; Trigila, Raffaello

    2016-01-01

    Surface tension plays an important role in the nucleation of H2O gas bubbles in magmatic melts and in the time-dependent rheology of bubble-bearing magmas. Despite several experimental studies, a physics based model of the surface tension of magmatic melts in contact with H2O is lacking. This paper employs gradient theory to develop a thermodynamical model of equilibrium surface tension of silicate melts in contact with H2O gas at low to moderate pressures. In the last decades, this approach has been successfully applied in studies of industrial mixtures but never to magmatic systems. We calibrate and verify the model against literature experimental data, obtained by the pendant drop method, and by inverting bubble nucleation experiments using the Classical Nucleation Theory (CNT). Our model reproduces the systematic decrease in surface tension with increased H2O pressure observed in the experiments. On the other hand, the effect of temperature is confirmed by the experiments only at high pressure. At atmospheric pressure, the model shows a decrease of surface tension with temperature. This is in contrast with a number of experimental observations and could be related to microstructural effects that cannot be reproduced by our model. Finally, our analysis indicates that the surface tension measured inverting the CNT may be lower than the value measured by the pendant drop method, most likely because of changes in surface tension controlled by the supersaturation.

  8. Analysis of effect of temperature gradients on surface-tension phenomena in gas-tungsten-arc welds

    International Nuclear Information System (INIS)

    Lee, H.A.; Chien, P.S.J.

    1982-10-01

    Fluid motion directed by surface tension is considered as a contributor to heat penetration in a weld pool. The potential phenomena at the gas-liquid interface were analyzed, and the dependence of surface motion on temperature in the gas-tungsten-arc (GTA) welding process was examined. An existing heat-transfer model was used and was able to predict weld size to +- 50% of the actual value. A momentum-transfer equation was derived by considering the contribution of Lorentz force. The momentum boundary condition was developed and was able to predict the Marangoni effect. The magnitude of surface-tension-driven force is comparable to the gravitational force on one gram. An empirical approach was proposed to couple heat-transfer and momentum-transfer phenomena. A dimensional analysis identified the pertinent dimensionless groups as Reynolds, Weber, Froude, Peclet, and Power numbers and a dimensionless velocity. A simplified form of the correction was developed by combining dimensionless groups to yield a correlation with the Bond, Prandtl, and modified power numbers. Future experimental work was proposed to test the functionality of the dimensionless groups

  9. Quantum surface tension in ideal gases

    International Nuclear Information System (INIS)

    Sisman, A.

    2005-01-01

    Due to wave character of atoms, an ideal gas confined in a finite domain exhibits Casimir like size effects. These effects become appreciable in a domain with at least one dimension in the order of micron. On this scale, thermodynamic state functions of an ideal gas become shape and size dependent and some new effects appear. In the literature, only some domains of regular shapes have been considered. In this study, the results are generalized to a domain of an arbitrary shape by using Weyl s conjecture for density of states. It is seen that free energy expression of an ideal Maxwellian gas consists of a classical volume dependent term and also a quantum originated surface dependent term, which causes a quantum surface tension. In a rectangular box filled by an ideal gas and separated by a movable wall into two parts, it is shown that a lateral force appears on the movable wall due to quantum surface tension

  10. Surface Tension Confines Cryogenic Liquid

    Science.gov (United States)

    Castles, Stephen H.; Schein, Michael E.

    1989-01-01

    New type of Dewar provides passive, constant-temperature cryogenic cooling for scientific instruments under normal-to low-gravity conditions. Known as Surface-Tension-Contained Liquid Cryogen Cooler (STCLCC), keeps liquid cryogen in known location inside the Dewar by trapping liquid inside spongelike material. Unique sponge material fills most of volume of inner tank. Sponge is all-silica, open-cell material similar to that used for Space Shuttle thermal-protection tiles.

  11. Axelrod's model with surface tension

    Science.gov (United States)

    Pace, Bruno; Prado, Carmen P. C.

    2014-06-01

    In this work we propose a subtle change in Axelrod's model for the dissemination of culture. The mechanism consists of excluding from the set of potentially interacting neighbors those that would never possibly exchange. Although the alteration proposed does not alter the state space topologically, it yields significant qualitative changes, specifically the emergence of surface tension, driving the system in some cases to metastable states. The transient behavior is considerably richer, and cultural regions become stable leading to the formation of different spatiotemporal patterns. A metastable "glassy" phase emerges between the globalized phase and the disordered, multicultural phase.

  12. Dynamical modeling of surface tension

    International Nuclear Information System (INIS)

    Brackbill, J.U.; Kothe, D.B.

    1996-01-01

    In a recent review it is said that free-surface flows ''represent some of the difficult remaining challenges in computational fluid dynamics''. There has been progress with the development of new approaches to treating interfaces, such as the level-set method and the improvement of older methods such as the VOF method. A common theme of many of the new developments has been the regularization of discontinuities at the interface. One example of this approach is the continuum surface force (CSF) formulation for surface tension, which replaces the surface stress given by Laplace's equation by an equivalent volume force. Here, we describe how CSF might be made more useful. Specifically, we consider a derivation of the CSF equations from a minimization of surface energy as outlined by Jacqmin. This reformulation suggests that if one eliminates the computation of curvature in terms of a unit normal vector, parasitic currents may be eliminated For this reformulation to work, it is necessary that transition region thickness be controlled. Various means for this, in addition to the one discussed by Jacqmin are discussed

  13. Density and surface tension of ionic liquids.

    Science.gov (United States)

    Kolbeck, C; Lehmann, J; Lovelock, K R J; Cremer, T; Paape, N; Wasserscheid, P; Fröba, A P; Maier, F; Steinrück, H-P

    2010-12-30

    We measured the density and surface tension of 9 bis[(trifluoromethyl)sulfonyl]imide ([Tf(2)N](-))-based and 12 1-methyl-3-octylimidazolium ([C(8)C(1)Im](+))-based ionic liquids (ILs) with the vibrating tube and the pendant drop method, respectively. This comprehensive set of ILs was chosen to probe the influence of the cations and anions on density and surface tension. When the alkyl chain length in the [C(n)C(1)Im][Tf(2)N] series (n = 1, 2, 4, 6, 8, 10, 12) is increased, a decrease in density is observed. The surface tension initially also decreases but reaches a plateau for alkyl chain lengths greater than n = 8. Functionalizing the alkyl chains with ethylene glycol groups results in a higher density as well as a higher surface tension. For the dependence of density and surface tension on the chemical nature of the anion, relations are only found for subgroups of the studied ILs. Density and surface tension values are discussed with respect to intermolecular interactions and surface composition as determined by angle-resolved X-ray photoelectron spectroscopy (ARXPS). The absence of nonvolatile surface-active contaminants was proven by ARXPS.

  14. Surface tension of normal and heavy water

    International Nuclear Information System (INIS)

    Straub, J.; Rosner, N.; Grigull, V.

    1980-01-01

    A Skeleton Table and simple interpolation equation for the surface tension of light water was developed by the Working Group III of the International Association for the Properties of Steam and is recommended as an International Standard. The Skeleton Table is based on all known measurements of the surface tension and individual data were weighted corresponding to the accuracy of the measurements. The form of the interpolation equation is based on a physical concept. It represents an extension of van der Waals-equation, where the exponent conforms to the 'Scaling Laws'. In addition for application purposes simple relations for the Laplace-coefficient and for the density difference between the liquid and gaseous phases of light water are given. The same form of interpolation equation for the surface tension can be used for heavy water, for which the coefficients are given. However, this equation is based only on a single set of data. (orig.) [de

  15. Contact Angles and Surface Tension of Germanium-Silicon Melts

    Science.gov (United States)

    Croell, A.; Kaiser, N.; Cobb, S.; Szofran, F. R.; Volz, M.; Rose, M. Franklin (Technical Monitor)

    2001-01-01

    Precise knowledge of material parameters is more and more important for improving crystal growth processes. Two important parameters are the contact (wetting) angle and the surface tension, determining meniscus shapes and surface-tension driven flows in a variety of methods (Czochralski, EFG, floating-zone, detached Bridgman growth). The sessile drop technique allows the measurement of both parameters simultaneously and has been used to measure the contact angles and the surface tension of Ge(1-x)Si(x) (0 less than or equal to x less than or equal to 1.3) alloys on various substrate materials. Fused quartz, Sapphire, glassy carbon, graphite, SiC, carbon-based aerogel, pyrolytic boron nitride (pBN), AIN, Si3N4, and polycrystalline CVD diamond were used as substrate materials. In addition, the effect of different cleaning procedures and surface treatments on the wetting behavior were investigated. Measurements were performed both under dynamic vacuum and gas atmospheres (argon or forming gas), with temperatures up to 1100 C. In some experiments, the sample was processed for longer times, up to a week, to investigate any changes of the contact angle and/or surface tension due to slow reactions with the substrate. For pure Ge, stable contact angles were found for carbon-based substrates and for pBN, for Ge(1-x)Si(x) only for pBN. The highest wetting angles were found for pBN substrates with angles around 170deg. For the surface tension of Ge, the most reliable values resulted in gamma(T) = (591- 0.077 (T-T(sub m)) 10(exp -3)N/m. The temperature dependence of the surface tension showed similar values for Ge(1-x)Si(x), around -0.08 x 10(exp -3)N/m K, and a compositional dependence of 2.2 x 10(exp -3)N/m at%Si.

  16. Surface Tension Measurements with a Smartphone

    Science.gov (United States)

    Goy, Nicolas-Alexandre; Denis, Zakari; Lavaud, Maxime; Grolleau, Adrian; Dufour, Nicolas; Deblais, Antoine; Delabre, Ulysse

    2017-01-01

    Smartphones are increasingly used in higher education and at university in mechanics, acoustics, and even thermodynamics as they offer a unique way to do simple science experiments. In this article, we show how smartphones can be used in fluid mechanics to measure surface tension of various liquids, which could help students understand the concept…

  17. Exact analytical density profiles and surface tension

    Indian Academy of Sciences (India)

    journal of. May 2005 physics pp. 785–801. Classical charged fluids at equilibrium near ... is provided by the excess surface tension for an air–water interface, which is determined ... the potential drop created by the electric layer which appears as soon as the fluid has ...... radii, by symmetry, the charge density profile is flat,.

  18. Integral analysis of cavity pressurization in a fuel rod during an ULOF driven TOP with inclusion of surface tension effects on froth gas bubbles and variable cavity conditions due to fuel melting and ejection

    International Nuclear Information System (INIS)

    Royl, P.

    1984-02-01

    The transient cavity pressurization in an ULOF driven TOP excursion has been analyzed for the SPX-1 reactor with an equation of state that allows to simulate the contribution of small froth gas bubbles to the pressure build-up in a fuel pin with inclusion of restraints from surface tension. Calculations were performed for various bubble parameters. Estimates are made for effective gas availabilities at fuel melting which can be used in a cavity model with an ideal gas equation to arrive at similar pressure transients

  19. Surface tension in soap films: revisiting a classic demonstration

    International Nuclear Information System (INIS)

    Behroozi, F

    2010-01-01

    We revisit a classic demonstration for surface tension in soap films and introduce a more striking variation of it. The demonstration shows how the film, pulling uniformly and normally on a loose string, transforms it into a circular arc under tension. The relationship between the surface tension and the string tension is analysed and presented in a useful graphical form. (letters and comments)

  20. Surface tension in soap films: revisiting a classic demonstration

    Energy Technology Data Exchange (ETDEWEB)

    Behroozi, F [Department of Physics, University of Northern Iowa, Cedar Falls, IA 50614 (United States)], E-mail: behroozi@uni.edu

    2010-01-15

    We revisit a classic demonstration for surface tension in soap films and introduce a more striking variation of it. The demonstration shows how the film, pulling uniformly and normally on a loose string, transforms it into a circular arc under tension. The relationship between the surface tension and the string tension is analysed and presented in a useful graphical form. (letters and comments)

  1. Surface tension confined liquid cryogen cooler

    Science.gov (United States)

    Castles, Stephen H. (Inventor); Schein, Michael E. (Inventor)

    1989-01-01

    A cryogenic cooler is provided for use in craft such as launch, orbital, and space vehicles subject to substantial vibration, changes in orientation, and weightlessness. The cooler contains a small pore, large free volume, low density material to restrain a cryogen through surface tension effects during launch and zero-g operations and maintains instrumentation within the temperature range of 10 to 140 K. The cooler operation is completely passive, with no inherent vibration or power requirements.

  2. Generalized surface tension bounds in vacuum decay

    Science.gov (United States)

    Masoumi, Ali; Paban, Sonia; Weinberg, Erick J.

    2018-02-01

    Coleman and De Luccia (CDL) showed that gravitational effects can prevent the decay by bubble nucleation of a Minkowski or AdS false vacuum. In their thin-wall approximation this happens whenever the surface tension in the bubble wall exceeds an upper bound proportional to the difference of the square roots of the true and false vacuum energy densities. Recently it was shown that there is another type of thin-wall regime that differs from that of CDL in that the radius of curvature grows substantially as one moves through the wall. Not only does the CDL derivation of the bound fail in this case, but also its very formulation becomes ambiguous because the surface tension is not well defined. We propose a definition of the surface tension and show that it obeys a bound similar in form to that of the CDL case. We then show that both thin-wall bounds are special cases of a more general bound that is satisfied for all bounce solutions with Minkowski or AdS false vacua. We discuss the limit where the parameters of the theory attain critical values and the bound is saturated. The bounce solution then disappears and a static planar domain wall solution appears in its stead. The scalar field potential then is of the form expected in supergravity, but this is only guaranteed along the trajectory in field space traced out by the bounce.

  3. A micro surface tension pump (MISPU) in a glass microchip.

    Science.gov (United States)

    Peng, Xing Yue Larry

    2011-01-07

    A non-membrane micro surface tension pump (MISPU) was fabricated on a glass microchip by one-step glass etching. It needs no material other than glass and is driven by digital gas pressure. The MISPU can be seen working like a piston pump inside the glass microchip under a microscope. The design of the valves (MISVA) and pistons (MISTON) was based on the surface tension theory of the micro surface tension alveolus (MISTA). The digital gas pressure controls the moving gas-liquid interface to open or close the input and output MISVAs to refill or drive the MISTON for pumping a liquid. Without any moving parts, a MISPU is a kind of long-lasting micro pump for micro chips that does not lose its water pumping efficiency over a 20-day period. The volumetric pump output varied from 0 to 10 nl s(-1) when the pump cycle time decreased from 5 min to 15 s. The pump head pressure was 1 kPa.

  4. Surface tension of H2O and D2O

    International Nuclear Information System (INIS)

    Vargaftik, N.B.; Voljak, L.D.; Volkov, B.N.

    1975-01-01

    There is a great number of works on surface tension of clean water (H 2 O) at temperatures up to 100 deg C and very few above the boiling point. Works on surface tension of heavy water (D 2 O) are insufficient. A review of works on surface tension of both kinds of water is given

  5. The law of corresponding states and surface tension of metals

    International Nuclear Information System (INIS)

    Digilov, R.

    2001-01-01

    Full Text: Surface tension of liquid metals is one of fundamental and most important quantities in theory and practice of material processing and its temperature dependence leads to the well-known Marangoni convection. Although currently methods are sufficiently precise to measure the surface tension, there are uncertainties in experimental data and its temperature dependence mainly due to impurity, which even a trace of it strongly affects the results of measurements. The theoretical treatment from the first principles is unwieldy and not always permits one to calculate the surface tension with certainty. Another active research field deals with empirical correlation between the surface tension and bulk thermodynamic properties, which we interpret as a simple consequence of the law of corresponding states. In order to relate the surface tension and to bulk properties of liquid metals the reduced formula is derived by scaling with the melting point T m (0) at p = 0 and atomic volume Ω 0 2/3 at T = 0 K as macroscopic parameters for scaling ε and a characterizing the interatomic potential in metals. The reduced surface tension and the reduced surface entropy obtained in high temperature limit are discussed and compared with the experiment. The reduced temperature coefficient of the surface tension found is a universal constant for the metals of the same structure. It is shown that pressure dependence of the surface tension, so called baric coefficient of the surface tension, can be described by pressure dependence of scaling parameters T m (p) and Ω 0 (p). (author)

  6. Surface tension of liquid Al-Cu binary alloys.

    OpenAIRE

    Schmitz, Julianna; Brillo, Jürgen; Egry, Ivan; Schmid-Fetzer, Rainer

    2009-01-01

    Surface tension data of liquid Al–Cu binary alloys have been measured contactlessly using the technique of electromagnetic levitation. A digital CMOS-camera (400 fps) recorded image sequences of the oscillating liquid sample and surface tensions were determined from analysis of the frequency spectra. Measurements were performed for samples covering the entire range of composition and precise data were obtained in a broad temperature range. It was found that the surface tensions can ...

  7. On relation between the quark-gluon bag surface tension and the colour tube string tension

    International Nuclear Information System (INIS)

    Bugaev, K.A.; Zinovjev, G.M.

    2010-01-01

    We revisit the bag phenomenology of deconfining phase transition aiming to replenish it by introducing systematically the bag surface tension. Comparing the free energies of such bags and the strings confining the static quark-antiquark pair, we express the string tension in terms of the bag surface tension and the bulk pressure in order to estimate the bag characteristics using the lattice QCD (LQCD) data. Our analysis of the bag entropy density demonstrates that the surface tension coefficient is amazingly negative at the cross-over (continuous transition). The approach developed allows us to naturally account for an origin of a pronounced maximum (observed in the LQCD studies) in the behaviour of heavy quark-antiquark pair entropy. The vicinity of the (tri-)critical endpoint is also analyzed to clarify the meaning of vanishing surface tension coefficient.

  8. Measurement for Surface Tension of Aqueous Inorganic Salt

    Directory of Open Access Journals (Sweden)

    Jiming Wen

    2018-03-01

    Full Text Available Bubble columns are effective means of filtration in filtered containment venting systems. Here, the surface tension has a significant influence on bubble size distribution and bubble deformation, which have a strong impact on the behavior of the bubble column. The influence of aqueous inorganic compounds on the surface tension depends on the electrolytic activity, Debye length, entropy of ion hydration, and surface deficiencies or excess. In this work, the surface tensions of same specific aqueous solutions have been measured by different methods including platinum plate method, platinum ring method, and maximum bubble pressure method. The measured surface tensions of both sodium hydroxide and sodium thiosulfate are less than that of water. As solution temperature ranges from 20 to 75°C, the surface tension of 0.5 mol/L sodium hydroxide solution decreases from 71 to 55 mN/m while that of 1 mol/L solution decreases from 60 to 45 mN/m. Similarly during the same temperature range, the surface tension of 0.5 mol/L sodium thiosulfate decreases from 70 to 38 mN/m, and that of 1 mol/L sodium thiosulfate is between 68 and 36 mN/m. The analysis for the influence mechanism of aqueous inorganic on surface tension is provided. In addition, experimental results show that the surface tension of solid aerosol suspension liquid has no obvious difference from that of distilled water.

  9. Surface tension and related thermodynamic quantities of aqueous electrolyte solutions

    CERN Document Server

    Matubayasi, Norihiro

    2013-01-01

    Surface tension provides a thermodynamic avenue for analyzing systems in equilibrium and formulating phenomenological explanations for the behavior of constituent molecules in the surface region. While there are extensive experimental observations and established ideas regarding desorption of ions from the surfaces of aqueous salt solutions, a more successful discussion of the theory has recently emerged, which allows the quantitative calculation of the distribution of ions in the surface region. Surface Tension and Related Thermodynamic Quantities of Aqueous Electrolyte Solutions provides a d

  10. Surface tension effects on vertical upward annular flows in a small diameter pipe

    Energy Technology Data Exchange (ETDEWEB)

    Sadatomi, Michio, E-mail: sadatomi@mech.kumamoto-u.ac.jp [Dept. of Advanced Mechanical Systems, Kumamoto Univ., 39-1, Kurokami 2-chome, Chuou-ku, Kumamoto 860-8555 (Japan); Kawahara, Akimaro [Dept. of Advanced Mechanical Systems, Kumamoto Univ., 39-1, Kurokami 2-chome, Chuou-ku, Kumamoto 860-8555 (Japan); Suzuki, Aruta [Plant Design & Engineering Dept., Environment, Energy & Plant Headquarters, Hitachi Zosen Corporation, 7-89, Nankokita 1-chome, Suminoe-ku, Osaka, 559-8559 (Japan)

    2016-12-15

    Highlights: • Surface tension effects were clarified on annular flow in a small diameter pipe. • The mean liquid film thickness became thinner with decreasing of surface tension. • The liquid droplet fraction and the interfacial shear stress became higher with it. • New prediction methods for the above parameters were developed and validated. - Abstract: Experiments were conducted to study the surface tension effects on vertical upward annular flows in a 5 mm I.D. pipe using water and low surface tension water with a little surfactant as the test liquid and air as the test gas. Firstly, the experimental results on the mean liquid film thickness, the liquid droplet fraction and the interfacial shear stress in annular flows together with some flow pictures are presented to clarify the surface tension effects. From these, the followings are clarified: In the low surface tension case, the liquid film surface becomes rough, the liquid film thickness thin, the liquid droplet fraction high, and the interfacial shear stress high. Secondary, correlations in literatures for the respective parameters are tested against the present data. The test results show that no correlation for the respective parameters could predict well the present data. Thus, correlations are revised by accounting for the surface tension effects. The results of the experiments, the correlations tests and their revisions mentioned above are presented in the present paper.

  11. Surface tension modelling of liquid Cd-Sn-Zn alloys

    Science.gov (United States)

    Fima, Przemyslaw; Novakovic, Rada

    2018-06-01

    The thermodynamic model in conjunction with Butler equation and the geometric models were used for the surface tension calculation of Cd-Sn-Zn liquid alloys. Good agreement was found between the experimental data for limiting binaries and model calculations performed with Butler model. In the case of ternary alloys, the surface tension variation with Cd content is better reproduced in the case of alloys lying on vertical sections defined by high Sn to Zn molar fraction ratio. The calculated surface tension is in relatively good agreement with the available experimental data. In addition, the surface segregation of liquid ternary Cd-Sn-Zn and constituent binaries has also been calculated.

  12. Fatigue crack growth behaviour of semi-elliptical surface cracks for an API 5L X65 gas pipeline under tension

    Science.gov (United States)

    Shaari, M. S.; Akramin, M. R. M.; Ariffin, A. K.; Abdullah, S.; Kikuchi, M.

    2018-02-01

    The paper is presenting the fatigue crack growth (FCG) behavior of semi-elliptical surface cracks for API X65 gas pipeline using S-version FEM. A method known as global-local overlay technique was used in this study to predict the fatigue behavior that involve of two separate meshes each specifically for global (geometry) and local (crack). The pre-post program was used to model the global geometry (coarser mesh) known as FAST including the material and boundary conditions. Hence, the local crack (finer mesh) will be defined the exact location and the mesh control accordingly. The local mesh was overlaid along with the global before the numerical computation taken place to solve the engineering problem. The stress intensity factors were computed using the virtual crack closure-integral method (VCCM). The most important results is the behavior of the fatigue crack growth, which contains the crack depth (a), crack length (c) and stress intensity factors (SIF). The correlation between the fatigue crack growth and the SIF shows a good growth for the crack depth (a) and dissimilar for the crack length (c) where stunned behavior was resulted. The S-version FEM will benefiting the user due to the overlay technique where it will shorten the computation process.

  13. Surface tension of compositions of polyhexametyleneguanidine hydrochloride - surfactants

    Directory of Open Access Journals (Sweden)

    S. Kumargaliyeva

    2012-12-01

    Full Text Available We made up songs bactericidal polyhexamethyleneguanidine hydrochloride (metacyde with the surface-active substances - anionic sodium dodecylsulfate, cationic cetylpyridinium bromide, and nonionic Tween-80 and measured the surface tension of water solutions. The study showed that the composition metacyde with surface-active agents have a greater surface activity than the individual components.

  14. Influence of liquid viscosity and surface tension on the gas-liquid mass transfer coefficient for solid foam packings in co-current two-phase flow

    NARCIS (Netherlands)

    Stemmet, C.P.; Bartelds, F.; Schaaf, van der J.; Kuster, B.F.M.; Schouten, J.C.

    2008-01-01

    The gas–liquid mass transfer coefficient and other hydrodynamic parameters such as liquid holdup and frictional pressure drop are presented for gas and liquid moving in co-current upflow and downflow through solid foam packings of 10 and of 40 pores per linear inch (ppi). The effect of increasing

  15. Surface tension alteration on calcite, induced by ion substitution

    DEFF Research Database (Denmark)

    Sakuma, Hiroshi; Andersson, Martin Peter; Bechgaard, Klaus

    2014-01-01

    The interaction of water and organic molecules with mineral surfaces controls many processes in nature and industry. The thermodynamic property, surface tension, is usually determined from the contact angle between phases, but how does one understand the concept of surface tension at the nanoscale...... preferentially as ion pairs at solution-calcite interfaces. Mg2+ incorporation weakens organic molecule adhesion while strengthening water adsorption so Mg2+ substitution renders calcite more water wet. When Mg2+ replaces 10% of surface Ca2+, the contact angle changes dramatically, by 40 to 70, converting...

  16. Effects of surface tension on tray point efficiencies

    Energy Technology Data Exchange (ETDEWEB)

    Chen, G.X.; Afacan, A.; Chuang, K.T. (Alberta Univ., Edmonton, AB (Canada))

    1994-08-01

    Sieve tray efficiencies for the distillation of methanol/water, acetic acid/water, and cyclohexane/n-heptane mixtures were measured as a function of composition under fixed vapor and liquid rates in a 0.15 m diameter distillation column. The three binary distillation systems used in the study had a wide range of surface tensions measured as a function of composition. From the efficiencies measured, the number of vapor- and liquid-phase transfer units (Ng and Nl) was determined and the effects of surface tension on Ng and Nl were identified. To further verify the results obtained from the distillation column, bubble sizes in froths for air/water, air/methanol, and air/(water + surfactant) systems with different surface tensions were measured. The results show that surface tension has a significant effect on tray efficiency and the number of transfer units. Bubble sizes in the tray froths were mainly determined by surface tension, and bubble breakup and coalescence occur in the froths. 45 refs., 15 figs., 1 tab.

  17. A density gradient theory based method for surface tension calculations

    DEFF Research Database (Denmark)

    Liang, Xiaodong; Michelsen, Michael Locht; Kontogeorgis, Georgios

    2016-01-01

    The density gradient theory has been becoming a widely used framework for calculating surface tension, within which the same equation of state is used for the interface and bulk phases, because it is a theoretically sound, consistent and computationally affordable approach. Based on the observation...... that the optimal density path from the geometric mean density gradient theory passes the saddle point of the tangent plane distance to the bulk phases, we propose to estimate surface tension with an approximate density path profile that goes through this saddle point. The linear density gradient theory, which...... assumes linearly distributed densities between the two bulk phases, has also been investigated. Numerical problems do not occur with these density path profiles. These two approximation methods together with the full density gradient theory have been used to calculate the surface tension of various...

  18. Modeling of surface tension effects in venturi scrubbing

    Science.gov (United States)

    Ott, Robert M.; Wu, Tatsu K. L.; Crowder, Jerry W.

    A modified model of venturi scrubber performance has been developed that addresses two effects of liquid surface tension: its effect on droplet size and its effect on particle penetration into the droplet. The predictions of the model indicate that, in general, collection efficiency increases with a decrease in liquid surface tension, but the range over which this increase is significant depends on the particle size and on the scrubber operating parameters. The predictions further indicate that the increases in collection efficiency are almost totally due to the effect of liquid surface tension on the mean droplet size, and that the collection efficiency is not significantly affected by the ability of the particle to penetrate the droplet.

  19. Surface tension and density of Si-Ge melts

    Science.gov (United States)

    Ricci, Enrica; Amore, Stefano; Giuranno, Donatella; Novakovic, Rada; Tuissi, Ausonio; Sobczak, Natalia; Nowak, Rafal; Korpala, Bartłomiej; Bruzda, Grzegorz

    2014-06-01

    In this work, the surface tension and density of Si-Ge liquid alloys were determined by the pendant drop method. Over the range of measurements, both properties show a linear temperature dependence and a nonlinear concentration dependence. Indeed, the density decreases with increasing silicon content exhibiting positive deviation from ideality, while the surface tension increases and deviates negatively with respect to the ideal solution model. Taking into account the Si-Ge phase diagram, a simple lens type, the surface tension behavior of the Si-Ge liquid alloys was analyzed in the framework of the Quasi-Chemical Approximation for the Regular Solutions model. The new experimental results were compared with a few data available in the literature, obtained by the containerless method.

  20. Surface tension in microsystems engineering below the capillary length

    CERN Document Server

    Lambert, Pierre

    2014-01-01

    This book describes how surface tension effects can be used by engineers to provide mechanical functions in miniaturized products (<1 mm). Even if precursors of this field such as Jurin or Laplace already date back to the 18th century, describing surface tension effects from a mechanical perspective is very recent. The originality of this book is to consider the effects of capillary bridges on solids, including forces and torques exerted both statically and dynamically by the liquid along the 6 degrees-of-freedom. It provides a comprehensive approach to various applications, such as capillary adhesion (axial force), centering force in packaging and micro-assembly (lateral force) and recent developments such as a capillary motor (torque). It devises how surface tension can be used to provide mechanical functions such as actuation (bubble-actuated compliant table), sealing and tightness, energy harvesting, nanodispending.

  1. Surface tension mediated conversion of light to work

    Science.gov (United States)

    Okawa, David; Pastine, Stefan J; Zettl, Alexander K; Frechet, Jean M. J

    2014-12-02

    Disclosed are a method and apparatus for converting light energy to mechanical energy by modification of surface tension on a supporting fluid. The apparatus comprises an object which may be formed as a composite object comprising a support matrix and a highly light absorptive material. The support matrix may comprise a silicon polymer. The highly light absorptive material may comprise vertically aligned carbon nanotubes (VANTs) embedded in the support matrix. The composite object is supported on a fluid. By exposing the highly light absorptive material to light, heat is generated, which changes the surface tension of the composite object, causing it to move physically within the fluid.

  2. Semi-implicit surface tension formulation with a Lagrangian surface mesh on an Eulerian simulation grid

    KAUST Repository

    Schroeder, Craig; Zheng, Wen; Fedkiw, Ronald

    2012-01-01

    -implicit and fully-coupled viscosity, pressure, and Lagrangian forces. We apply our new framework for forces on a Lagrangian mesh to the case of a surface tension force, which when treated explicitly leads to a tight time step restriction. By applying surface tension

  3. Dynamic Bubble Surface Tension Measurements in Northwest Atlantic Seawater

    Science.gov (United States)

    Kieber, D. J.; Long, M. S.; Keene, W. C.; Kinsey, J. D.; Frossard, A. A.; Beaupre, S. R.; Duplessis, P.; Maben, J. R.; Lu, X.; Chang, R.; Zhu, Y.; Bisgrove, J.

    2017-12-01

    Numerous reports suggest that most organic matter (OM) associated with newly formed primary marine aerosol (PMA) originates from the sea-surface microlayer. However, surface-active OM rapidly adsorbs onto bubble surfaces in the water column and is ejected into the atmosphere when bubbles burst at the air-water interface. Here we present dynamic surface tension measurements of bubbles produced in near surface seawater from biologically productive and oligotrophic sites and in deep seawater collected from 2500 m in the northwest Atlantic. In all cases, the surface tension of bubble surfaces decreased within seconds after the bubbles were exposed to seawater. These observations demonstrate that bubble surfaces are rapidly saturated by surfactant material scavenged from seawater. Spatial and diel variability in bubble surface evolution indicate corresponding variability in surfactant concentrations and/or composition. Our results reveal that surface-active OM is found throughout the water column, and that at least some surfactants are not of recent biological origin. Our results also support the hypothesis that the surface microlayer is a minor to negligible source of OM associated with freshly produced PMA.

  4. Effect of potential attraction term on surface tension of ionic liquids

    Science.gov (United States)

    Vaziri, N.; Khordad, R.; Rezaei, G.

    2018-03-01

    In this work, we have studied the effect of attraction term of molecular potential on surface tension of ionic liquids (ILs). For this purpose, we have introduced two different potential models to obtain analytical expressions for the surface tension of ILs. The introduced potential models have different attraction terms. The obtained surface tensions in this work have been compared with other theoretical methods and also experimental data. Using the calculated surface tension, the sound velocity is also estimated. We have studied the structural effects on the surface tensions of imidazolium-based ionic liquids. It is found that the cation alkyl chain length and the anion size play important roles to the surface tension of the selected ionic liquids. The calculated surface tensions show a good harmony with experimental data. It is clear that the attraction term of molecular potential has an important role on surface tension and sound velocity of our system.

  5. Prognosis in Acute Cerebrovascular Accidents in Relation to Respiratory Pattern and Blood—gas Tensions

    Science.gov (United States)

    Rout, M. W.; Lane, D. J.; Wollner, L.

    1971-01-01

    Respiratory pattern and arterial blood gas tensions were assessed in patients with acute cerebrovascular accidents. Hyperventilation, low Pco2, and high arterial pH were associated with a poor prognosis, whereas patients with normal respiratory pattern and blood gas tensions survived. Periodic and Cheyne-Stokes breathing carried an intermediate prognosis. PMID:5091916

  6. Liquid metal actuator driven by electrochemical manipulation of surface tension

    Science.gov (United States)

    Russell, Loren; Wissman, James; Majidi, Carmel

    2017-12-01

    We examine the electrocapillary properties of a fluidic actuator composed of a liquid metal droplet that is submerged in electrolytic solution and attached to an elastic beam. The beam deflection is controlled by electrochemically driven changes in the surface energy of the droplet. The metal is a eutectic gallium-indium alloy that is liquid at room temperature and forms an nm-thin Ga2O3 skin when oxidized. The effective surface tension of the droplet changes dramatically with oxidation and reduction, which are reversibly controlled by applying low voltage to the electrolytic bath. Wetting the droplet to two copper pads allows for a controllable tensile force to be developed between the opposing surfaces. We demonstrate the ability to reliably control force by changing the applied oxidizing voltage. Actuator forces and droplet geometries are also examined by performing a computational fluid mechanics simulation using Surface Evolver. The theoretical predictions are in qualitative agreement with the experimental measurements and provide additional confirmation that actuation is driven by surface tension.

  7. Surface tension and density of liquid In-Sn-Zn alloys

    Science.gov (United States)

    Pstruś, Janusz

    2013-01-01

    Using the dilatometric method, measurements of the density of liquid alloys of the ternary system In-Sn-Zn in four sections with a constant ratio Sn:In = 24:1, 3:1, 1:1, 1:3, for various Zn additions (5, 10, 14, 20, 3 5, 50 and 75 at.% Zn) were performed at the temperature ranges of 500-1150 K. Density decreases linearly for all compositions. The molar volume calculated from density data exhibits close to ideal dependence on composition. Measurements of the surface tension of liquid alloys have been conducted using the method of maximum pressure in the gas bubbles. There were observed linear dependences on temperature with a negative gradients dσ/dT. Generally, with two exceptions, there was observed the increase of surface tension with increasing content of zinc. Using the Butler's model, the surface tension isotherms were calculated for temperatures T = 673 and 1073 K. Calculations show that only for high temperatures and for low content of zinc (up to about 35 at.%), the modeling is in very good agreement with experiment. Using the mentioned model, the composition of the surface phase was defined at two temperatures T = 673 and 973 K. Regardless of the temperature and of the defined section, the composition of the bulk is very different in comparison with the composition of the surface.

  8. Surface tension propulsion of fungal spores by use of microdroplets

    OpenAIRE

    Noblin, Xavier; Yang, Sylvia; Dumais, Jacques

    2010-01-01

    Many edible mushrooms eject their spores (about 10 microns in size) at high speed (about 1 m/s) using surface tension forces in a few microseconds. Basically the coalescence of a droplet with the spore generates the necessary momentum to eject the spore. We have detailed this mechanism in \\cite{noblin2}. In this article, we give some details about the high speed movies (up to 250000 fps) of mushrooms' spores ejection attached to this submission. This video was submitted as part of the Gallery...

  9. Surface tension, hydrophobicity, and black holes: The entropic connection

    International Nuclear Information System (INIS)

    Callaway, D.J.

    1996-01-01

    The geometric entropy arising from partitioning space in a fluid open-quote open-quote field theory close-quote close-quote is shown to be linearly proportional to the area of an excluded region. The coefficient of proportionality is related to surface tension by a thermodynamic argument. Good agreement with experimental data is obtained for a number of fluids. The calculation employs a density-matrix formalism developed previously for studying the origin of black hole entropy. This approach may lead to a practical technique for the evaluation of thermodynamic quantities with important entropic components. copyright 1996 The American Physical Society

  10. A thermodynamic perturbation theory for the surface tension and ion density profile of a liquid metal

    International Nuclear Information System (INIS)

    Evans, R.; Kumaravadivel, R.

    1976-01-01

    A simple scheme for determining the ion density profile and the surface tension of a liquid metal is described. Assuming that the interaction between metallic pseudo-ions is of the form introduced by Evans, an approximate expression for the excess free energy of the system is derived using the thermodynamic perturbation theory of Weeks, Chandler and Anderson. This excess free energy is then minimized with respect to a parameter which specifies the ion density profile, and the surface tension is given directly. From a consideration of the dependence of the interionic forces on the electron density it is predicted that the ions should take up a very steep density profile at the liquid metal surface. This behaviour is contrasted with that to be expected for rare-gas fluids in which the interatomic forces are density-independent. The values of the surface tension calculated for liquid Na, K and Al from a simplified version of the theory are in reasonable agreement with experiment. (author)

  11. Superfluid 3He A-B surface tension

    International Nuclear Information System (INIS)

    Bartkowiak, M.; Haley, R.P.; Fisher, S.N.; Guenault, A.M.; Pickett, G.R.; Skyba, P.

    2003-01-01

    We have made two different measurements of interfacial energies below 300 μK, at zero pressure and in magnetic fields up to 400 mT. A variable magnetic field profile allows us to stabilize and precisely manipulate the position of the A-B interface. First, we can derive the difference in wall wetting energies from the behaviour of the phase boundary as it enters and exits a stack of glass capillary tubes. Secondly, we can measure the surface tension from the level of over- or under-magnetization needed to force the interface through an aperture. These are the first surface energy measurements in high magnetic fields in the zero-temperature limit. Our results are in surprising agreement with earlier measurements at high pressure close to T c

  12. Backward flow in a surface tension driven micropump

    International Nuclear Information System (INIS)

    Ju, Jongil; Park, Joong Yull; Lee, Sang-Hoon; Kim, Kyung Chun; Kim, Hyundong; Berthier, Erwin; Beebe, David J

    2008-01-01

    A surface tension driven micropump harnessing the pressure difference generated by drops of different curvature radii proves to be a simple and attractive passive method to drive fluid flow in microdevices. Here we observed the appearance of backward flow when the initial sizes of the droplets at the inlet and outlet ports are similar. To explain this phenomenon several hypotheses have been investigated. Consideration of the inertia of the fluid in the channel revealed that it alone is insufficient to explain the observed backward flow. We discovered that rotational flow inside the outlet droplet could be a source of inertia, explaining the generation of the backward flow. In addition, we have experimentally determined that the ratio of the volumes of the initial outlet drop and inlet drop correlates with the occurrence of the backward flow. (note)

  13. Fowler's approximation for the surface tension and surface energy of Lennard-Jones fluids revisited

    International Nuclear Information System (INIS)

    Mulero, A; Galan, C; Cuadros, F

    2003-01-01

    We present a detailed study of the validity of Fowler's approximation for calculating the surface tension and the surface energy of Lennard-Jones fluids. To do so, we consider three different explicit analytical expressions for the radial distribution function (RDF), including one proposed by our research group, together with very accurate expressions for the liquid and vapour densities, also proposed by our group. The calculation of the surface tension from the direct correlation function using both the Percus-Yevick and the hypernetted-chain approximations is also considered. Finally, our results are compared with those obtained by other authors by computer simulations or through relevant theoretical approximations. In particular, we consider the analytical expression proposed by Kalikmanov and Hofmans (1994 J. Phys.: Condens. Matter 6 2207-14) for the surface tension. Our results indicate that the values for the surface energy in Fowler's approximation obtained by other authors are adequate, and can be calculated from the RDF models. For the surface tension, however, the values considered as valid in previous works seem to be incorrect. The correct values can be obtained from our model for the RDF or from the Kalikmanov and Hofmans expression with suitable inputs

  14. Using the surface tension to estimate the condensate density of superfluid 4He

    International Nuclear Information System (INIS)

    Campbell, L.J.

    1983-01-01

    Distortion of the condensate wavefunction at the free surface of superfluid 4 He contributes to the surface tension in proportion to the condensate fraction n 0 (T). Using this to resolve the present discrepancy between the measured and predicted temperature dependencies of the surface tension gives n 0 (T) in good agreement with results from neutron and x-ray scattering measurements. This picture is also consistent with the measured 3 He- 4 He interfacial tension

  15. Effect of Surface Tension Anisotropy and Welding Parameters on Initial Instability Dynamics During Solidification: A Phase-Field Study

    Science.gov (United States)

    Yu, Fengyi; Wei, Yanhong

    2018-05-01

    The effects of surface tension anisotropy and welding parameters on initial instability dynamics during gas tungsten arc welding of an Al-alloy are investigated by a quantitative phase-field model. The results show that the surface tension anisotropy and welding parameters affect the initial instability dynamics in different ways during welding. The surface tension anisotropy does not influence the solute diffusion process but does affect the stability of the solid/liquid interface during solidification. The welding parameters affect the initial instability dynamics by varying the growth rate and thermal gradient. The incubation time decreases, and the initial wavelength remains stable as the welding speed increases. When welding power increases, the incubation time increases and the initial wavelength slightly increases. Experiments were performed for the same set of welding parameters used in modeling, and the results of the experiments and simulations were in good agreement.

  16. Tensioned Fabric Structures with Surface in the Form of Chen-Gackstatter

    Directory of Open Access Journals (Sweden)

    Yee Hooi Min

    2016-01-01

    Full Text Available Form-finding has to be carried out for tensioned fabric structure in order to determine the initial equilibrium shape under prescribed support condition and prestress pattern. Tensioned fabric structures are normally designed to be in the form of equal tensioned surface. Tensioned fabric structure is highly suited to be used for realizing surfaces of complex or new forms. However, research study on a new form as a tensioned fabric structure has not attracted much attention. Another source of inspiration minimal surface which could be adopted as form for tensioned fabric structure is very crucial. The aim of this study is to propose initial equilibrium shape of tensioned fabric structures in the form of Chen-Gackstatter. Computational form-finding using nonlinear analysis method is used to determine the Chen-Gackstatter form of uniformly stressed surfaces. A tensioned fabric structure must curve equally in opposite directions to give the resulting surface a three dimensional stability. In an anticlastic doubly curved surface, the sum of all positive and all negative curvatures is zero. This study provides an alternative choice for structural designer to consider the Chen-Gackstatter applied in tensioned fabric structures. The results on factors affecting initial equilibrium shape can serve as a reference for proper selection of surface parameter for achieving a structurally viable surface.

  17. A waveless free surface flow past a submerged triangular obstacle in presence of surface tension

    Directory of Open Access Journals (Sweden)

    Hakima Sekhri

    2016-07-01

    Full Text Available We consider the Free surface flows passing a submerged triangular obstacle at the bottom of a channel. The problem is characterized by a nonlinear boundary condition on the surface of unknown configuration. The analytical exact solutions for these problems are not known. Following Dias and Vanden Broeck [6], we computed numerically the solutions via a series truncation method. These solutions depend on two parameters: the Weber number $\\alpha$ characterizing the strength of the surface tension and the angle $\\beta$ at the base characterizing the shape of the apex. Although free surface flows with surface tension admit capillary waves, it is found that solution exist only for values of the Weber number greater than $\\alpha_0$ for different configurations of the triangular obstacle.

  18. Surface Tension Driven Instability in the Regime of Stokes Flow

    Science.gov (United States)

    Yao, Zhenwei; Bowick, Mark; Xing, Xiangjun

    2010-03-01

    A cylinder of liquid inside another liquid is unstable towards droplet formation. This instability is driven by minimization of surface tension energy and was analyzed first by [1,2] and then by [3]. We revisit this problem in the limit of small Laplace number, where the inertial of liquids can be completely ignored. The stream function is found to obey biharmonic equation, and its analytic solutions are found. We rederive Tomotika's main results, and also obtain many new analytic results about the velocity fields. We also apply our formalism to study the recent experiment on toroidal liquid droplet[4]. Our framework shall have many applications in micro-fluidics. [1] L.Rayleigh, On The Instability of A Cylinder of Viscous Liquid Under Capillary Force, Scientific Papers, Cambridge, Vol.III, 1902. [2] L.Rayleigh, On The Instability of Cylindrical Fluid Surfaces, Scientific Papers, Cambridge, Vol.III, 1902. [3] S.Tomotika, On the Instability of a Cylindrical Thread of a Viscous Liquid surround by Another Viscous Fluid, Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences, Volume 150, Issue 870, pp. 322-337. [4] E.Pairam and A.Fern'andez-Nieves, Generation and Stability of Toroidal Droplets in a Viscous Liquid, Physical Review Letters 102, 234501 (2009).

  19. Incorporating contact angles in the surface tension force with the ACES interface curvature scheme

    Science.gov (United States)

    Owkes, Mark

    2017-11-01

    In simulations of gas-liquid flows interacting with solid boundaries, the contact line dynamics effect the interface motion and flow field through the surface tension force. The surface tension force is directly proportional to the interface curvature and the problem of accurately imposing a contact angle must be incorporated into the interface curvature calculation. Many commonly used algorithms to compute interface curvatures (e.g., height function method) require extrapolating the interface, with defined contact angle, into the solid to allow for the calculation of a curvature near a wall. Extrapolating can be an ill-posed problem, especially in three-dimensions or when multiple contact lines are near each other. We have developed an accurate methodology to compute interface curvatures that allows for contact angles to be easily incorporated while avoiding extrapolation and the associated challenges. The method, known as Adjustable Curvature Evaluation Scale (ACES), leverages a least squares fit of a polynomial to points computed on the volume-of-fluid (VOF) representation of the gas-liquid interface. The method is tested by simulating canonical test cases and then applied to simulate the injection and motion of water droplets in a channel (relevant to PEM fuel cells).

  20. Theory of the surface dipole layer and of surface tension in liquids of charged particles

    International Nuclear Information System (INIS)

    Senatore, G.; Tosi, M.P.

    1980-01-01

    The problem of the surface density profiles and of the surface tension of a two-component liquid of charged particles in equilibrium with its vapour is examined. The exact equilibrium conditions for the profiles are given in terms of the inverse response functions of the inhomogeneous fluid, and alternative exact expressions for the surface tension are derived. The use of a density gradient expansion reduces the problem to knowledge of properties of a homogeneous charged fluid on a uniform neutralizing background, in which the total particle density and the charge density are independent variables. Additional simplifications are discussed for special cases for which a perturbative treatment of the surface charge density profile can be developed, and in particular for nearly symmetric ionic liquids and for simple liquid metals. (author)

  1. Dynamic surface tension measurements of ionic surfactants using maximum bubble pressure tensiometry

    Science.gov (United States)

    Ortiz, Camilla U.; Moreno, Norman; Sharma, Vivek

    Dynamic surface tension refers to the time dependent variation in surface tension, and is intimately linked with the rate of mass transfer of a surfactant from liquid sub-phase to the interface. The diffusion- or adsorption-limited kinetics of mass transfer to interfaces is said to impact the so-called foamability and the Gibbs-Marangoni elasticity of surfaces. Dynamic surface tension measurements carried out with conventional methods like pendant drop analysis, Wilhelmy plate, etc. are limited in their temporal resolution (>50 ms). In this study, we describe design and application of maximum bubble pressure tensiometry for the measurement of dynamic surface tension effects at extremely short (1-50 ms) timescales. Using experiments and theory, we discuss the overall adsorption kinetics of charged surfactants, paying special attention to the influence of added salt on dynamic surface tension.

  2. Wetting and surface tension of bismate glass melt

    International Nuclear Information System (INIS)

    Shim, Seung-Bo; Kim, Dong-Sun; Hwang, Seongjin; Kim, Hyungsun

    2009-01-01

    Lead oxide glass frits are used widely in the electronics industry for low-temperature firing. On the other hand, one of the low-sintering and low-melting lead-free glass systems available, the bismate glass system, is considered to be an alternative to lead oxide glass. In order to extend the applications of Bi 2 O 3 glasses, this study examined the thermophysical properties of low-melting Bi 2 O 3 -B 2 O 3 -ZnO-BaO-Al 2 O 3 -SiO 2 glass frits with various ZnO/B 2 O 3 ratios. The fundamental thermal properties, such as glass transition temperature and softening point, were examined by differential thermal analysis and a glass softening point determination system. The wetting angles, viscosities and surface tension of the various bismate glasses on an alumina substrate were measured using hot-stage microscopy and the sessile drop method. These thermophysical properties will be helpful in understanding the work of adhesion and the liquid spread kinetics of glass frits.

  3. Mapping surface tension induced menisci with application to tensiometry and refractometry.

    Science.gov (United States)

    Mishra, Avanish; Kulkarni, Varun; Khor, Jian-Wei; Wereley, Steve

    2015-07-28

    In this work, we discuss an optical method for measuring surface tension induced menisci. The principle of measurement is based upon the change in the background pattern produced by the curvature of the meniscus acting as a lens. We measure the meniscus profile over an inclined glass plate and utilize the measured meniscus for estimation of surface tension and refractive index.

  4. Prediction of viscosities and surface tensions of fuels using a new corresponding states model

    DEFF Research Database (Denmark)

    Queimada, A.J.; Rolo, L.I.; Caco, A.I.

    2006-01-01

    While some properties of diesels are cheap, easy and fast to measure, such as densities, others such as surface tensions and viscosities are expensive and time consuming. A new approach that uses some basic information such as densities to predict viscosities and surface tensions is here proposed......) 2005 Elsevier Ltd. All rights reserved....

  5. Density functional theory of simple polymers in a slit pore. III. Surface tension

    International Nuclear Information System (INIS)

    Hooper, Justin B.; McCoy, John D.; Curro, John G.; Swol, Frank van

    2000-01-01

    In a previous study of tangent hard-site chains near a surface, the inhomogeneous density profiles were found through density functional theory. In the current study, the surface tensions of these systems are found from the results of the previous study through a thermodynamic integration. The calculated surface tensions are then compared to those found directly through computer simulation. Both the surface tension and surface excess for polymeric systems are shown to differ qualitatively from those of atomic systems, although certain similarities are seen at high densities. (c) 2000 American Institute of Physics

  6. A novel technique for including surface tension in PLIC-VOF methods

    Energy Technology Data Exchange (ETDEWEB)

    Meier, M.; Yadigaroglu, G. [Swiss Federal Institute of Technology, Nuclear Engineering Lab. ETH-Zentrum, CLT, Zurich (Switzerland); Smith, B. [Paul Scherrer Inst. (PSI), Villigen (Switzerland). Lab. for Thermal-Hydraulics

    2002-02-01

    Various versions of Volume-of-Fluid (VOF) methods have been used successfully for the numerical simulation of gas-liquid flows with an explicit tracking of the phase interface. Of these, Piecewise-Linear Interface Construction (PLIC-VOF) appears as a fairly accurate, although somewhat more involved variant. Including effects due to surface tension remains a problem, however. The most prominent methods, Continuum Surface Force (CSF) of Brackbill et al. and the method of Zaleski and co-workers (both referenced later), both induce spurious or 'parasitic' currents, and only moderate accuracy in regards to determining the curvature. We present here a new method to determine curvature accurately using an estimator function, which is tuned with a least-squares-fit against reference data. Furthermore, we show how spurious currents may be drastically reduced using the reconstructed interfaces from the PLIC-VOF method. (authors)

  7. Surface tension and related thermodynamic parameters of alcohols using the Traube stalagmometer

    International Nuclear Information System (INIS)

    Dilmohamud, B A; Seeneevassen, J; Rughooputh, S D D V; Ramasami, P

    2005-01-01

    An apparatus was devised using the Traube Stalagmometer for the determination of the surface tension of the alcohols methanol, ethanol, propan-1-ol and butan-1-ol. Measurements were made under atmospheric pressure at temperatures between 288.15 K and 313.15 K. The surface tension values were correlated with temperature and surface thermodynamic parameters, namely surface entropy and surface enthalpy, were also calculated. The results obtained are in agreement with the literature and they are promising for the use of this low cost arrangement for accurate measurement of surface tension. Surface tension values were obtained with a maximum error of 0.5 mN m -1 and a maximum standard deviation of 0.8 mN m -1 . We recommend this arrangement for students in advanced university courses and it can also be used for research work

  8. Surface tension and Wulff shape for a lattice model without spin flip symmetry.

    CERN Document Server

    Bodineau, T

    2003-01-01

    We propose a new definition of surface tension and check it in a spin model of the Pirogov-Sinai class where the spin flip symmetry is broken. We study the model at low temperatures on the phase transitions line and prove: (i) existence of the surface tension in the thermodynamic limit, for any orientation of the surface and in all dimensions $d\\ge 2$; (ii) the Wulff shape constructed with such a surface tension coincides with the equilibrium shape of the cluster which appears when fixing the total spin magnetization (Wulff problem).

  9. Semi-implicit surface tension formulation with a Lagrangian surface mesh on an Eulerian simulation grid

    KAUST Repository

    Schroeder, Craig

    2012-02-01

    We present a method for applying semi-implicit forces on a Lagrangian mesh to an Eulerian discretization of the Navier Stokes equations in a way that produces a sparse symmetric positive definite system. The resulting method has semi-implicit and fully-coupled viscosity, pressure, and Lagrangian forces. We apply our new framework for forces on a Lagrangian mesh to the case of a surface tension force, which when treated explicitly leads to a tight time step restriction. By applying surface tension as a semi-implicit Lagrangian force, the resulting method benefits from improved stability and the ability to take larger time steps. The resulting discretization is also able to maintain parasitic currents at low levels. © 2011.

  10. Investigations of the surface tension of coal ash slags under gasification conditions; Untersuchungen zur Oberflaechenspannung von Kohleschlacken unter Vergasungsbedingungen

    Energy Technology Data Exchange (ETDEWEB)

    Melchior, Tobias

    2011-10-26

    In the context of CO{sub 2}-emission-induced global warming, greenhouse gases resulting from the production of electricity in coal-fired power plants gain increasing attention. One possible way to reduce such emissions is to gasify coal instead of burning it. The corresponding process is referred to as Integrated Gasification Combined Cycle and allows for the separation of CO{sub 2} before converting a synthesis gas into electrical energy. However, further improvements in efficiency and availability of this plant technology are needed to render the alternative generation of electricity sensible from an economic point of view. One corresponding approach introduces hot gas cleaning facilities to the gasification plant which guarantee a removal of slag particles from the synthesis gas at high temperatures. The development of such filters depends on the availability of data on the material properties of the coal ash slags to be withdrawn. In this respect, the surface tension is a relevant characteristic. Currently, the surface tension of real coal ash slags as well as of synthetic model systems was measured successfully by means of the sessile drop and the maximum bubble pressure method. With regard to the sessile drop technique, those experiments were conducted in a gasification-like atmosphere at temperatures of up to 1500 C. Furthermore, the pressure inside the experimental vessel was raised to 10 bar in order to allow for deriving the influence of this variable on the surface tension. In contrast, maximum bubble pressure trials were realised at atmospheric pressure while the gas atmosphere assured inert conditions. For performing sessile drop measurements, a corresponding apparatus was set up and is described in detail in this thesis. Three computer algorithms were employed to calculate surface tensions out of the photos of sessile drops and their individual performance was evaluated. A very good agreement between two of the codes was found while the third one

  11. Density-functional calculations of the surface tension of liquid Al and Na

    Science.gov (United States)

    Stroud, D.; Grimson, M. J.

    1984-01-01

    Calculations of the surface tensions of liquid Al and Na are described using the full ionic density functional formalism of Wood and Stroud (1983). Surface tensions are in good agreement with experiment in both cases, with results substantially better for Al than those found previously in the gradient approximation. Preliminary minimization with respect to surface profile leads to an oscillatory profile superimposed on a nearly steplike ionic density disribution; the oscillations have a wavellength of about a hardsphere diameter.

  12. Theoretical calculations of the surface tension of Ag(1-x)-Cu(x) liquid alloys

    International Nuclear Information System (INIS)

    Aqra, Fathi; Ayyad, Ahmed

    2011-01-01

    Highlights: → A thermodynamic model for calculating the surface tension, and its temperature and composition dependences, of liquid binary alloys is described. → The model does not require the prior knowledge of the surface concentration and Gibbs energy. → The surface tension of the liquid Ag-Cu binary alloys has been calculated as a function of temperature and concentration. → The calculated values agree well with existing experimental data. - Abstract: The surface tension of silver-copper binary liquid alloys is calculated, in the frame work of Eyring theory. The calculations were made for different compositions (mole fraction, x Cu = 0, 0.2, 0.4, 0.6, 0.8 and 1), in the temperature range 1100-1800 K. The surface tension decreases with temperature increase, at a fixed copper fraction x Cu , and increases with increasing copper content. The calculated results are appropriately compared with existing literature data.

  13. A Computational Study of Richtmyer-Meshkov Instability with Surface Tension

    Science.gov (United States)

    Francois, Marianne; Velechovsky, Jan; Jibben, Zach; Masser, Thomas; LANL Collaboration

    2017-11-01

    We have added the capability to model surface tension in our adaptive mesh refinement compressible flow solver, xRage. Our surface tension capability employs the continuum surface force to model surface tension and the height function method to compute curvatures. We have verified our model implementation for the static and oscillating droplets test cases and the linear regime of the Rayleigh-Taylor instability. With this newly added capability, we have performed a numerical study of the effects of surface tension on single-mode and multi-mode Richtmyer-Meshkov instability. This work was performed under the auspices of the National Nuclear Security Administration of the U.S. Department of Energy at Los Alamos National Laboratory under Contract No. DE-AC52 - 06NA25396.

  14. Surface tension anomalies in room temperature ionic liquids-acetone solutions

    Science.gov (United States)

    Abe, Hiroshi; Murata, Keisuke; Kiyokawa, Shota; Yoshimura, Yukihiro

    2018-05-01

    Surface tension anomalies were observed in room temperature ionic liquid (RTIL)-acetone solutions. The RTILs are 1-alkyl-3-methylimidazorium iodide with [Cnmim][I] in a [Cnmim][I]-x mol% acetone. The maximum value of the surface tension appeared at 40 mol% acetone, although density decreased monotonically with an increase in acetone concentration. A small alkyl chain length effect of the Cnmim+ cations was observed in the surface tension. By the Gibbs adsorption isotherm, it was found that I- anion-mediated surface structure became dominant above 40 mol%. In the different [Cnmim][TFSI]-acetone mixtures, normal decay of the surface tension was observed on the acetone concentration scale, where TFSI- is bis(trifluoromethanesulfonyl)imide.

  15. Dynamics of two-phase interfaces and surface tensions: A density-functional theory perspective

    Science.gov (United States)

    Yatsyshin, Petr; Sibley, David N.; Duran-Olivencia, Miguel A.; Kalliadasis, Serafim

    2016-11-01

    Classical density functional theory (DFT) is a statistical mechanical framework for the description of fluids at the nanoscale, where the inhomogeneity of the fluid structure needs to be carefully accounted for. By expressing the grand free-energy of the fluid as a functional of the one-body density, DFT offers a theoretically consistent and computationally accessible way to obtain two-phase interfaces and respective interfacial tensions in a ternary solid-liquid-gas system. The dynamic version of DFT (DDFT) can be rigorously derived from the Smoluchowsky picture of the dynamics of colloidal particles in a solvent. It is generally agreed that DDFT can capture the diffusion-driven evolution of many soft-matter systems. In this context, we use DDFT to investigate the dynamic behaviour of two-phase interfaces in both equilibrium and dynamic wetting and discuss the possibility of defining a time-dependent surface tension, which still remains in debate. We acknowledge financial support from the European Research Council via Advanced Grant No. 247031 and from the Engineering and Physical Sciences Research Council of the UK via Grants No. EP/L027186 and EP/L020564.

  16. Prediction of surface tension of binary mixtures with the parachor method

    Directory of Open Access Journals (Sweden)

    Němec Tomáš

    2015-01-01

    Full Text Available The parachor method for the estimation of the surface tension of binary mixtures is modified by considering temperature-dependent values of the parachor parameters. The temperature dependence is calculated by a least-squares fit of pure-solvent surface tension data to the binary parachor equation utilizing the Peng-Robinson equation of state for the calculation of equilibrium densities. A very good agreement between experimental binary surface tension data and the predictions of the modified parachor method are found for the case of the mixtures of carbon dioxide and butane, benzene, and cyclohexane, respectively. The surface tension is also predicted for three refrigerant mixtures, i.e. propane, isobutane, and chlorodifluoromethane, with carbon dioxide.

  17. The interfacial surface tension of a quark-gluon plasma fireball in a ...

    Indian Academy of Sciences (India)

    surface tension with the cube of the critical transition temperature is in overall ... more rigorous structures may be built depending on the phenomenological success .... k +dk in a spherically symmetric situation, and gi is the degeneracy factor ( ...

  18. Evaluation on Dorsey Method in Surface Tension Measurement of Solder Liquids Containing Surfactants

    Science.gov (United States)

    Zhao, Xingke; Xie, Feiming; Fan, Jinsheng; Liu, Dayong; Huang, Jihua; Chen, Shuhai

    2018-06-01

    With the purpose of developing a feasible approach for measuring the surface tension of solders containing surfactants, the surface tension of Sn-3Ag-0.5Cu-xP solder alloys, with various drop sizes as well as different phosphorus (P) content, was evaluated using the Dorsey method based on the sessile drop test. The results show that the accuracy of the surface tension calculations depends on both of sessile drop size and the liquid metal composition. With a proper drop size, in the range of 4.5 mm to 5.3 mm in equivalent spherical diameters, the deviation of the surface tension calculation can be limited to 1.43 mN·m-1 and 6.30 mN·m-1 for SnAgCu and SnAgCu-P, respectively. The surface tension of SnAgCu-xP solder alloys decreases quickly to a minimum value when the P content reaches 0.5 wt% and subsequently increases slowly with the P content further increasing. The formation of a P-enriched surface layer and Sn4P3 intermetallic phases is regarded to be responsible for the decreasing and subsequent increasing of surface tension, respectively.

  19. Critical Assessment of the Surface Tension determined by the Maximum Pressure Bubble Method

    OpenAIRE

    Benedetto, Franco Emmanuel; Zolotucho, Hector; Prado, Miguel Oscar

    2015-01-01

    The main factors that influence the value of surface tension of a liquid measured with the Maximum Pressure Bubble Method are critically evaluated. We present experimental results showing the effect of capillary diameter, capillary depth, bubble spheroidicity and liquid density at room temperature. We show that the decrease of bubble spheroidicity due to increase of capillary immersion depth is not sufficient to explain the deviations found in the measured surface tension values. Thus, we pro...

  20. Axisymmetric Drop Shape Analysis for Estimating the Surface Tension of Cell Aggregates by Centrifugation

    OpenAIRE

    Kalantarian, Ali; Ninomiya, Hiromasa; Saad, Sameh M.I.; David, Robert; Winklbauer, Rudolf; Neumann, A. Wilhelm

    2009-01-01

    Biological tissues behave in certain respects like liquids. Consequently, the surface tension concept can be used to explain aspects of the in vitro and in vivo behavior of multicellular aggregates. Unfortunately, conventional methods of surface tension measurement cannot be readily applied to small cell aggregates. This difficulty can be overcome by an experimentally straightforward method consisting of centrifugation followed by axisymmetric drop shape analysis (ADSA). Since the aggregates ...

  1. Atomic forces between noble gas atoms, alkali ions, and halogen ions for surface interactions

    Science.gov (United States)

    Wilson, J. W.; Outlaw, R. A.; Heinbockel, J. H.

    1988-01-01

    The components of the physical forces between noble gas atoms, alkali ions, and halogen ions are analyzed and a data base developed from analysis of the two-body potential data, the alkali-halide molecular data, and the noble gas crystal and salt crystal data. A satisfactory global fit to this molecular and crystal data is then reproduced by the model to within several percent. Surface potentials are evaluated for noble gas atoms on noble gas surfaces and salt crystal surfaces with surface tension neglected. Within this context, the noble gas surface potentials on noble gas and salt crystals are considered to be accurate to within several percent.

  2. Experiment and model for the surface tension of amine–ionic liquids aqueous solutions

    International Nuclear Information System (INIS)

    Zhang, Pan; Du, LeiXia; Fu, Dong

    2014-01-01

    Highlights: • The surface tensions of MEA/DEA–ionic liquids aqueous solutions were measured. • The experiments were modeled satisfactorily by using a thermodynamic equation. • The temperature dependence of the surface tension was illustrated. • The effects of the mass fractions of MEA/DEA and ionic liquids were demonstrated. - Abstract: The surface tension (γ) of 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim][BF 4 ])–monoethanolamine (MEA), 1-butyl-3-methylimidazolium bromide ([Bmim][Br])–MEA, [Bmim][BF 4 ]–diethanolamine (DEA) and [Bmim][Br]–DEA aqueous solutions was measured by using the BZY-1 surface tension meter. The temperature ranged from (293.2 to 323.2) K. The mass fraction of amines and ionic liquids (ILS) respectively ranged from 0.15 to 0.30 and 0.05 to 0.10. A thermodynamic equation was proposed to model the surface tension of amines–ILS aqueous solutions and the calculated results agreed well with the experiments. The effects of temperature, mass fraction of amines and ILS on the surface tension were demonstrated on the basis of experiments and calculations

  3. Combined influence of inertia, gravity, and surface tension on the linear stability of Newtonian fiber spinning

    Science.gov (United States)

    Bechert, M.; Scheid, B.

    2017-11-01

    The draw resonance effect appears in fiber spinning processes if the ratio of take-up to inlet velocity, the so-called draw ratio, exceeds a critical value and manifests itself in steady oscillations of flow velocity and fiber diameter. We study the effect of surface tension on the draw resonance behavior of Newtonian fiber spinning in the presence of inertia and gravity. Utilizing an alternative scaling makes it possible to visualize the results in stability maps of highly practical relevance. The interplay of the destabilizing effect of surface tension and the stabilizing effects of inertia and gravity lead to nonmonotonic stability behavior and local stability maxima with respect to the dimensionless fluidity and the dimensionless inlet velocity. A region of unconditional instability caused by the influence of surface tension is found in addition to the region of unconditional stability caused by inertia, which was described in previous works [M. Bechert, D. W. Schubert, and B. Scheid, Eur. J. Mech B 52, 68 (2015), 10.1016/j.euromechflu.2015.02.005; Phys. Fluids 28, 024109 (2016), 10.1063/1.4941762]. Due to its importance for a particular group of fiber spinning applications, a viscous-gravity-surface-tension regime, i.e., negligible effect of inertia, is analyzed separately. The mechanism underlying the destabilizing effect of surface tension is discussed and established stability criteria are tested for validity in the presence of surface tension.

  4. Surface tension and density of fusible metal melt with sulphur and selenium

    International Nuclear Information System (INIS)

    Najdich, Yu.V.; Krasovskij, Yu.P.; Chuvashov, Yu.N.

    1990-01-01

    Surface tension and density at 970 K have been determined for melts of Ga, In, Sn and Pb with S and Se. High surface activity of chalcogens in the melts has been found. A maximal adsorption of the active components and their ultimate surface activity that correlate with thermodinamical strength of the corresponding sulfides and selenides have been calculated

  5. Some remarks on the solid surface tension determination from contact angle measurements

    Energy Technology Data Exchange (ETDEWEB)

    Zdziennicka, Anna; Szymczyk, Katarzyna; Krawczyk, Joanna; Jańczuk, Bronisław, E-mail: bronislaw.janczuk@poczta.umcs.lublin.pl

    2017-05-31

    Graphical abstract: Surface tension of PE, nylon 6 and quartz from different approaches to the interface tension. - Highlights: • New values of water and formamide surface tension components were established. • Quartz surface tension depends on its crystal face. • Usefulness of different approaches for solid surface tension determination was tested. - Abstract: The measurements of water, formamide and diiodomethane contact angle (θ) on polytetrafluoroethylene (PTFE), polyethylene (PE), polymethyl methacrylate (PMMA), nylon 6, quartz and silica were performed. Based on the θ values of these liquids obtained on PTFE, the Lifshitz-van der Waals and acid-base and/or dispersion and polar components of their surface tension (ST) were determined. In turn, the θ values for water, formamide and diiodomethane on PMMA were applied to calculate the electron-acceptor and electron-donor parameters of the Lewis acid-base component of the formamide ST. For this calculation the same values of the electron-acceptor and electron-donor parameters for water ST were used. Taking into account the values of components and parameters of water, formamide and diiodomethane ST obtained by us, van Oss et al. and from the water(formamide)-n-alkane and water-diiodomethane interface tension, the components and parameters of studied solids ST were calculated. To this end different approaches to the interface tension were considered. The obtained values were compared with those in the literature. It was concluded that for determination of solid ST components and parameters, those of water, formamide and diiodomethane ST obtained from the θ measurements on the model solids should be used.

  6. Surface tension of droplets and Tolman lengths of real substances and mixtures from density functional theory

    Science.gov (United States)

    Rehner, Philipp; Gross, Joachim

    2018-04-01

    The curvature dependence of interfacial properties has been discussed extensively over the last decades. After Tolman published his work on the effect of droplet size on surface tension, where he introduced the interfacial property now known as Tolman length, several studies were performed with varying results. In recent years, however, some consensus has been reached about the sign and magnitude of the Tolman length of simple model fluids. In this work, we re-examine Tolman's equation and how it relates the Tolman length to the surface tension and we apply non-local classical density functional theory (DFT) based on the perturbed chain statistical associating fluid theory (PC-SAFT) to characterize the curvature dependence of the surface tension of real fluids as well as mixtures. In order to obtain a simple expression for the surface tension, we use a first-order expansion of the Tolman length as a function of droplet radius Rs, as δ(Rs) = δ0 + δ1/Rs, and subsequently expand Tolman's integral equation for the surface tension, whereby a second-order expansion is found to give excellent agreement with the DFT result. The radius-dependence of the surface tension of increasingly non-spherical substances is studied for n-alkanes, up to icosane. The infinite diameter Tolman length is approximately δ0 = -0.38 Å at low temperatures. For more strongly non-spherical substances and for temperatures approaching the critical point, however, the infinite diameter Tolman lengths δ0 turn positive. For mixtures, even if they contain similar molecules, the extrapolated Tolman length behaves strongly non-ideal, implying a qualitative change of the curvature behavior of the surface tension of the mixture.

  7. Surface tension and contact angles: Molecular origins and associated microstructure

    Science.gov (United States)

    Davis, H. T.

    1982-01-01

    Gradient theory converts the molecular theory of inhomogeneous fluid into nonlinear boundary value problems for density and stress distributions in fluid interfaces, contact line regions, nuclei and microdroplets, and other fluid microstructures. The relationship between the basic patterns of fluid phase behavior and the occurrence and stability of fluid microstructures was clearly established by the theory. All the inputs of the theory have molecular expressions which are computable from simple models. On another level, the theory becomes a phenomenological framework in which the equation of state of homogeneous fluid and sets of influence parameters of inhomogeneous fluids are the inputs and the structures, stress tensions and contact angles of menisci are the outputs. These outputs, which find applications in the science and technology of drops and bubbles, are discussed.

  8. Effect of waveforms of inspired gas tension on the respiratory oscillations of carotid body discharge.

    Science.gov (United States)

    Kumar, P; Nye, P C; Torrance, R W

    1991-07-01

    The responses of carotid body chemoreceptor discharge to repeated ramps (20- to 60-s forcing cycle durations) of inspired gas tensions were studied in spontaneously breathing and in artificially ventilated pentobarbitone-anesthetized cats. In all animals the mean intensity of chemoreceptor discharge followed the frequency of the forcing cycle, and superimposed on this were oscillations at the frequency of ventilation (breath-by-breath oscillations). The amplitude of the breath-by-breath oscillations in discharge was often large, and it waxed and waned with the forcing cycle. It was greatest when the mean level of discharge was falling and smallest near the peak of mean discharge. No qualitative differences were observed between PO2-alone forcing in constant normocapnia and PCO2-alone forcing in constant hypoxia. The variation in the amplitudes of breath-by-breath oscillations was shown to be due primarily to variations in the amplitudes of the downslope component of the discharge oscillation. Variations in the upslope component of individual oscillations were small. The factors responsible for the breath-by-breath oscillations are discussed, and it is concluded that the shape of the waveform of arterial gas tensions that stimulate the peripheral chemoreceptors departs markedly from that of a line joining end-tidal gas tensions. This causes breath-by-breath oscillations of discharge to be very large after an "off" stimulus. Reflex studies involving the forcing of respiratory gases should therefore include consideration of these effects.

  9. An apparatus with a horizontal capillary tube intended for measurement of the surface tension of supercooled liquids

    Science.gov (United States)

    Vinš, Václav; Hošek, Jan; Hykl, Jiří; Hrubý, Jan

    2015-05-01

    New experimental apparatus for measurement of the surface tension of liquids under the metastable supercooled state has been designed and assembled in the study. The measuring technique is similar to the method employed by P.T. Hacker [NACA TN 2510] in 1951. A short liquid thread of the liquid sample was sucked inside a horizontal capillary tube partly placed in a temperature-controlled glass chamber. One end of the capillary tube was connected to a setup with inert gas which allowed for precise tuning of the gas overpressure in order of hundreds of Pa. The open end of the capillary tube was precisely grinded and polished before the measurement in order to assure planarity and perpendicularity of the outer surface. The liquid meniscus at the open end was illuminated by a laser beam and observed by a digital camera. Application of an increasing overpressure of the inert gas at the inner meniscus of the liquid thread caused variation of the outer meniscus such that it gradually changed from concave to flat and subsequently convex shape. The surface tension at the temperature of the inner meniscus could be evaluated from the overpressure corresponding to exactly planar outer meniscus. Detailed description of the new setup together with results of the preliminary tests is provided in the study.

  10. Surface Tension of Multi-phase Flow with Multiple Junctions Governed by the Variational Principle

    International Nuclear Information System (INIS)

    Matsutani, Shigeki; Nakano, Kota; Shinjo, Katsuhiko

    2011-01-01

    We explore a computational model of an incompressible fluid with a multi-phase field in three-dimensional Euclidean space. By investigating an incompressible fluid with a two-phase field geometrically, we reformulate the expression of the surface tension for the two-phase field found by Lafaurie et al. (J Comput Phys 113:134–147, 1994) as a variational problem related to an infinite dimensional Lie group, the volume-preserving diffeomorphism. The variational principle to the action integral with the surface energy reproduces their Euler equation of the two-phase field with the surface tension. Since the surface energy of multiple interfaces even with singularities is not difficult to be evaluated in general and the variational formulation works for every action integral, the new formulation enables us to extend their expression to that of a multi-phase (N-phase, N ≥ 2) flow and to obtain a novel Euler equation with the surface tension of the multi-phase field. The obtained Euler equation governs the equation for motion of the multi-phase field with different surface tension coefficients without any difficulties for the singularities at multiple junctions. In other words, we unify the theory of multi-phase fields which express low dimensional interface geometry and the theory of the incompressible fluid dynamics on the infinite dimensional geometry as a variational problem. We apply the equation to the contact angle problems at triple junctions. We computed the fluid dynamics for a two-phase field with a wall numerically and show the numerical computational results that for given surface tension coefficients, the contact angles are generated by the surface tension as results of balances of the kinematic energy and the surface energy.

  11. Determination of surface tension coefficient of liquids by diffraction of light on capillary waves

    International Nuclear Information System (INIS)

    Nikolić, D; Nešić, Lj

    2012-01-01

    This paper describes a simple technique for determining the coefficient of the surface tension of liquids, based on laser light diffraction on capillary waves. Capillary waves of given frequency are created by an exciter needle acting on the surface of liquid and represent a reflective diffraction grating, the constant of which (the wavelength of capillary waves) can be determined based on a known incidence angle of light (grazing angle). We obtain the coefficient of the surface tension of liquids by applying the dispersion relation for capillary waves and analyze the difficulties that arise when setting up and conducting the experiment in detail. (paper)

  12. Temporal instability of viscous liquid microjets with spatially varying surface tension

    Energy Technology Data Exchange (ETDEWEB)

    Furlani, E P [Integrated Materials and Microstructures Laboratory, Electronic Imaging Products, Eastman Kodak Company, Rochester, NY 14650-2121 (United States)

    2005-01-07

    A linear theory is developed for the temporal instability of a viscous liquid microjet of Newtonian fluid with a spatially periodic variation of surface tension imposed along its length. The variation of surface tension induces Marangoni flow within the jet that leads to breakup and drop formation. An analytical expression is derived for the behaviour of the free surface of the microjet. This expression is useful for parametric analysis of jet instability and breakup as a function of jet radius, wavelength and fluid properties.

  13. Temporal instability of viscous liquid microjets with spatially varying surface tension

    International Nuclear Information System (INIS)

    Furlani, E P

    2005-01-01

    A linear theory is developed for the temporal instability of a viscous liquid microjet of Newtonian fluid with a spatially periodic variation of surface tension imposed along its length. The variation of surface tension induces Marangoni flow within the jet that leads to breakup and drop formation. An analytical expression is derived for the behaviour of the free surface of the microjet. This expression is useful for parametric analysis of jet instability and breakup as a function of jet radius, wavelength and fluid properties

  14. Surface tension of liquid Cu-Ti binary alloys measured by electromagnetic levitation and thermodynamic modelling

    International Nuclear Information System (INIS)

    Amore, S.; Brillo, J.; Egry, I.; Novakovic, R.

    2011-01-01

    The surface tension of liquid Cu-Ti alloys has been measured by using the containerless technique of electromagnetic levitation and theoretically calculated in the framework of the compound formation model. Measurements have been carried out on alloys covering the entire range of composition and over the temperature range 1275-2050 K. For all investigated alloys the surface tension can be described by a linear function of the temperature with negative slope. Due to the presence of different intermetallic compounds in the solid state the surface properties of liquid Cu-Ti alloys are satisfactory described by the compound formation model.

  15. Bubble extinction in Hele-Shaw flow with surface tension and kinetic undercooling regularization

    International Nuclear Information System (INIS)

    Dallaston, Michael C; McCue, Scott W

    2013-01-01

    We perform an analytic and numerical study of an inviscid contracting bubble in a two-dimensional Hele-Shaw cell, where the effects of both surface tension and kinetic undercooling on the moving bubble boundary are not neglected. In contrast to expanding bubbles, in which both boundary effects regularize the ill-posedness arising from the viscous (Saffman–Taylor) instability, we show that in contracting bubbles the two boundary effects are in competition, with surface tension stabilizing the boundary, and kinetic undercooling destabilizing it. This competition leads to interesting bifurcation behaviour in the asymptotic shape of the bubble in the limit it approaches extinction. In this limit, the boundary may tend to become either circular, or approach a line or ‘slit’ of zero thickness, depending on the initial condition and the value of a nondimensional surface tension parameter. We show that over a critical range of surface tension values, both these asymptotic shapes are stable. In this regime there exists a third, unstable branch of limiting self-similar bubble shapes, with an asymptotic aspect ratio (dependent on the surface tension) between zero and one. We support our asymptotic analysis with a numerical scheme that utilizes the applicability of complex variable theory to Hele-Shaw flow. (paper)

  16. Unusual shapes for a catenary under the effects of surface tension and gravity: A variational treatment

    International Nuclear Information System (INIS)

    Behroozi, F.; Mohazzabi, P.; McCrickard, J.

    1995-01-01

    The familiar catenary is the shape assumed by a chain or string as it hangs from two points. The mathematical equation of the catenary was first published more than three hundred years ago by Leibnitz and Huygen, among others. Here we consider the shapes assumed by a hanging string in the presence of gravity and surface tension. The surface tension is introduced by suspending the string from a thin horizontal rod while the area bounded by the string and the rod is covered with a soap film. The string then assumes new and wonderful shapes depending on the relative strength of the surface tension and the weight per unit length of the string. When surface tension dominates, the string is pulled inward, assuming a convex shape similar to the Greek letter γ. On the other hand, when gravity is dominant the string is pulled outward and assumes a concave shape best described as a distorted catenary. However, when the gravitational force normal to the string matches the surface tension, the string takes a linear configuration similar to the letter V. Under suitable conditions, the string can be made to assume any of the three configurations by adjusting the separation of its end points. The equations that describe the shape of the string are derived by minimizing the total energy of the system and are presented for the three principal configurations

  17. Axisymmetric drop shape analysis for estimating the surface tension of cell aggregates by centrifugation.

    Science.gov (United States)

    Kalantarian, Ali; Ninomiya, Hiromasa; Saad, Sameh M I; David, Robert; Winklbauer, Rudolf; Neumann, A Wilhelm

    2009-02-18

    Biological tissues behave in certain respects like liquids. Consequently, the surface tension concept can be used to explain aspects of the in vitro and in vivo behavior of multicellular aggregates. Unfortunately, conventional methods of surface tension measurement cannot be readily applied to small cell aggregates. This difficulty can be overcome by an experimentally straightforward method consisting of centrifugation followed by axisymmetric drop shape analysis (ADSA). Since the aggregates typically show roughness, standard ADSA cannot be applied and we introduce a novel numerical method called ADSA-IP (ADSA for imperfect profile) for this purpose. To examine the new methodology, embryonic tissues from the gastrula of the frog, Xenopus laevis, deformed in the centrifuge are used. It is confirmed that surface tension measurements are independent of centrifugal force and aggregate size. Surface tension is measured for ectodermal cells in four sample batches, and varies between 1.1 and 7.7 mJ/m2. Surface tension is also measured for aggregates of cells expressing cytoplasmically truncated EP/C-cadherin, and is approximately half as large. In parallel, such aggregates show a reduction in convergent extension-driven elongation after activin treatment, reflecting diminished intercellular cohesion.

  18. Surface tension estimation of high temperature melts of the binary alloys Ag-Au

    Science.gov (United States)

    Dogan, Ali; Arslan, Hüseyin

    2017-11-01

    Surface tension calculation of the binary alloys Ag-Au at the temperature of 1381 K, where Ag and Au have similar electronic structures and their atomic radii are comparable, are carried out in this study using several equations over entire composition range of Au. Apparently, the deviations from ideality of the bulk solutions, such as activities of Ag and Au are small and the maximum excess Gibbs free energy of mixing of the liquid phase is for instance -4500 J/mol at XAu = 0.5. Besides, the results obtained in Ag-Au alloys that at a constant temperature the surface tension increases with increasing composition while the surface tension decreases as the temperature increases for entire composition range of Au. Although data about surface tension of the Ag-Au alloy are limited, it was possible to make a comparison for the calculated results for the surface tension in this study with the available experimental data. Taken together, the average standard error analysis that especially the improved Guggenheim model in the other models gives the best agreement along with the experimental results at temperature 1383 K although almost all models are mutually in agreement with the other one.

  19. Design of an experimental apparatus for measurement of the surface tension of metastable fluids

    Science.gov (United States)

    Vinš, V.; Hrubý, J.; Hykl, J.; Blaha, J.; Šmíd, B.

    2013-04-01

    A unique experimental apparatus for measurement of the surface tension of aqueous mixtures has been designed, manufactured, and tested in our laboratory. The novelty of the setup is that it allows measurement of surface tension by two different methods: a modified capillary elevation method in a long vertical capillary tube and a method inspired by the approach of Hacker (National Advisory Committee for Aeronautics, Technical Note 2510, 1-20, 1951), i.e. in a short horizontal capillary tube. Functionality of all main components of the apparatus, e.g., glass chamber with the capillary tube, temperature control unit consisting of two thermostatic baths with special valves for rapid temperature jumps, helium distribution setup allowing pressure variation above the liquid meniscus inside the capillary tube, has been successfully tested. Preliminary results for the surface tension of the stable and metastable supercooled water measured by the capillary elevation method at atmospheric pressure are provided. The surface tension of water measured at temperatures between +26 °C and -11 °C is in good agreement with the extrapolated IAPWS correlation (IAPWS Release on Surface Tension of Ordinary Water Substance, September 1994); however it disagrees with data by Hacker.

  20. Modeling the surface tension of complex, reactive organic-inorganic mixtures

    Science.gov (United States)

    Schwier, A. N.; Viglione, G. A.; Li, Z.; McNeill, V. Faye

    2013-11-01

    Atmospheric aerosols can contain thousands of organic compounds which impact aerosol surface tension, affecting aerosol properties such as heterogeneous reactivity, ice nucleation, and cloud droplet formation. We present new experimental data for the surface tension of complex, reactive organic-inorganic aqueous mixtures mimicking tropospheric aerosols. Each solution contained 2-6 organic compounds, including methylglyoxal, glyoxal, formaldehyde, acetaldehyde, oxalic acid, succinic acid, leucine, alanine, glycine, and serine, with and without ammonium sulfate. We test two semi-empirical surface tension models and find that most reactive, complex, aqueous organic mixtures which do not contain salt are well described by a weighted Szyszkowski-Langmuir (S-L) model which was first presented by Henning et al. (2005). Two approaches for modeling the effects of salt were tested: (1) the Tuckermann approach (an extension of the Henning model with an additional explicit salt term), and (2) a new implicit method proposed here which employs experimental surface tension data obtained for each organic species in the presence of salt used with the Henning model. We recommend the use of method (2) for surface tension modeling of aerosol systems because the Henning model (using data obtained from organic-inorganic systems) and Tuckermann approach provide similar modeling results and goodness-of-fit (χ2) values, yet the Henning model is a simpler and more physical approach to modeling the effects of salt, requiring less empirically determined parameters.

  1. Spreading of oil films on water in the surface tension regime

    Energy Technology Data Exchange (ETDEWEB)

    Camp, D.W.

    1985-01-01

    Surface tension forces will cause an oil to spread over water if the tension of the oil film (the summed surface and interfacial tensions for bulk oil films, or the equilibrium spreading tension for monomolecular films) is less than the surface tension of water. For oil films spreading in a 40 cm long channel, measurements are made of leading edge position and lateral profiles of film thickness, velocity, and tension as a function of time. Measurements of the tension profiles, important for evaluating proposed theories, is made possible by the development of a new technique based on the Wilhelmy method. The oils studied were silicones, fatty acids and alcohols, and mixtures of surfactants in otherwise nonspreading oils. The single-component oils show an acceleration zone connecting a slow-moving inner region with a fast-moving leading monolayer. The dependence of film tension on film thickness for spreading single-component oils often differs from that at equilibrium. The mixtures show a bulk oil film configuration which extends to the leading edge and have velocity profiles which increase smoothly. The theoretical framework, similarity transformation, and asymptotic solutions of Foda and Cox for single-component oils were shown to be valid. An analysis of spreading surfactant-oil mixtures is developed which allows them to be treated under this framework. An easily-used semi-empirical model is proposed which allows them to be treated under this framework. An easily-used semi-empirical model is proposed which allows accurate prediction of detailed spreading behavior for any spreading oil.

  2. Expressions of the radius and the surface tension of surface of tension in terms of the pressure distribution for nanoscale liquid threads

    International Nuclear Information System (INIS)

    Yan Hong; Wei Jiu-An; Cui Shu-Wen; Zhu Ru-Zeng

    2013-01-01

    The expressions of the radius and the surface tension of surface of tension R s and γ s in terms of the pressure distribution for nanoscale liquid threads are of great importance for molecular dynamics (MD) simulations of the interfacial phenomena of nanoscale fluids; these two basic expressions are derived in this paper. Although these expressions were derived first in the literature [Kim B G, Lee J S, Han M H, and Park S, 2006 Nanoscale and Microscale Thermophysical Engineering, 10, 283] and used widely thereafter, the derivation is wrong both in logical structure and physical thought. In view of the importance of these basic expressions, the logic and physical mistakes appearing in that derivation are pointed out. (condensed matter: structural, mechanical, and thermal properties)

  3. The surface tension of pure liquids. Thermodynamic components and corresponding states

    NARCIS (Netherlands)

    Lyklema, J.

    1999-01-01

    From the temperature dependency of surface and interfacial tensions the surface excess energy and entropy per unit area can be obtained. The excess energy is a liquid-specific property; it varies over about three decades between liquid helium and molten metals. On the other hand, the excess entropy

  4. Performing chemical reactions in virtual capillary of surface tension ...

    Indian Academy of Sciences (India)

    The flow paths were fabricated by making parallel lines using permanent marker pen ink or other polymer on glass surfaces. Two mirror image patterned glass plates were then sandwiched one on top of the other, separated by a thin gap - created using a spacer. The aqueous liquid moves between the surfaces by capillary ...

  5. Concentration Dependences of the Surface Tension and Density of Solutions of Acetone-Ethanol-Water Systems at 293 K

    Science.gov (United States)

    Dadashev, R. Kh.; Dzhambulatov, R. S.; Mezhidov, V. Kh.; Elimkhanov, D. Z.

    2018-05-01

    Concentration dependences of the surface tension and density of solutions of three-component acetone-ethanol-water systems and the bounding binary systems at 273 K are studied. The molar volume, adsorption, and composition of surface layers are calculated. Experimental data and calculations show that three-component solutions are close to ideal ones. The surface tensions of these solutions are calculated using semi-empirical and theoretical equations. Theoretical equations qualitatively convey the concentration dependence of surface tension. A semi-empirical method based on the Köhler equation allows us to predict the concentration dependence of surface tension within the experimental error.

  6. Noncontact surface tension and viscosity measurements of rhenium in the liquid and undercooled states

    International Nuclear Information System (INIS)

    Ishikawa, Takehiko; Paradis, Paul-Francois; Yoda, Shinichi

    2004-01-01

    Surface tension and viscosity of liquid rhenium, which have hardly been measured due to the extremely high melting temperature of rhenium, were measured using an electrostatic levitation method combined with the oscillation drop technique. Sample position instability problems caused by the photon pressure of the heating lasers and by sample evaporation were solved by modifying the electrodes design. Good sample stability allowed the measurements of the surface tension and the viscosity over wide temperature ranges including the undercooled states. Over the 2800-3600 K interval, the surface tension of rhenium was measured as σ(T)=2.71x10 3 -0.23(T-T m ), where T m is the melting temperature, 3453 K. At T m , the datum agrees well with the literature values. Similarly, on the same temperature range, the viscosity was determined as η(T)=0.08 exp[1.33x10 5 /(RT)] (mPa s)

  7. Predicting the minimum liquid surface tension activity of pseudomonads expressing biosurfactants.

    Science.gov (United States)

    Mohammed, I U; Deeni, Y; Hapca, S M; McLaughlin, K; Spiers, A J

    2015-01-01

    Bacteria produce a variety of biosurfactants capable of significantly reducing liquid (aqueous) surface tension (γ) with a range of biological roles and biotechnological uses. To determine the lowest achievable surface tension (γMin ), we tested a diverse collection of Pseudomonas-like isolates from contaminated soil and activated sludge and identified those expressing biosurfactants by drop-collapse assay. Liquid surface tension-reducing ability was quantitatively determined by tensiometry, with 57 isolates found to significantly lower culture supernatant surface tensions to 24·5-49·1 mN m(-1) . Differences in biosurfactant behaviour determined by foaming, emulsion and oil-displacement assays were also observed amongst isolates producing surface tensions of 25-27 mN m(-1) , suggesting that a range of structurally diverse biosurfactants were being expressed. Individual distribution identification (IDI) analysis was used to identify the theoretical probability distribution that best fitted the surface tension data, which predicted a γMin of 24·24 mN m(-1) . This was in agreement with predictions based on earlier work of published mixed bacterial spp. data, suggesting a fundamental limit to the ability of bacterial biosurfactants to reduce surface tensions in aqueous systems. This implies a biological restriction on the synthesis and export of these agents or a physical-chemical restriction on their functioning once produced. Numerous surveys of biosurfactant-producing bacteria have been conducted, but only recently has an attempt been made to predict the minimum liquid surface tension these surface-active agents can achieve. Here, we determine a theoretical minimum of 24 mN m(-1) by statistical analysis of tensiometry data, suggesting a fundamental limit for biosurfactant activity in bacterial cultures incubated under standard growth conditions. This raises a challenge to our understanding of biosurfactant expression, secretion and function, as well as

  8. Effect of electrolytes on surface tension and surface adsorption of 1-hexyl-3-methylimidazolium chloride ionic liquid in aqueous solution

    International Nuclear Information System (INIS)

    Ghasemian, Ensieh; Najafi, Mojgan; Rafati, Amir Abbas; Felegari, Zahra

    2010-01-01

    Surface and bulk properties of 1-hexyl-3-methylimidazolium chloride [C 6 mim][Cl] as an ionic liquid (IL) have been investigated by surface tension and electrical conductivity techniques at various temperatures. Results reveal that the ionic liquid behaves as surfactant-like and aggregates in aqueous solution. Critical aggregation concentration (cac) values obtained by conductivity and surface tension measurements are in good agreement with values found in the literature. A series of important and useful adsorption parameters including cac, surface excess concentration (Γ), and minimum surface area per molecule (A min ) at the air + water interface were estimated from surface tension in the presence and absence of different electrolytes. Obtained data show that the surface tension as well as the cac of [C 6 mim][Cl] is reduced by electrolytes. Also, values of surface excess concentration (Γ) show that the IL ions in the presence of electrolyte have much larger affinity to adsorption at the surface and this affinity increased in aqueous electrolyte solution in the order of I - > Br - > Cl - for counter ion of salts that was explained in terms of a larger repulsion of chloride anions from interface to the bromide and iodide anion as well as difference in their excess polarizability.

  9. A new corresponding state-based correlation for the surface tension of organic fatty acids

    Science.gov (United States)

    Zhang, Cuihua; Tian, Jianxiang; Zheng, Mengmeng; Yi, Huili; Zhang, Laibin; Liu, Shuzhen

    2018-01-01

    In this paper, we proposed a new corresponding state-based correlation for organic fatty (aliphatic, carboxylic and polyfunctional) acids. By using the recently published surface tension data of the 99 acids [A. Mulero and I. Cachadiña, J. Phys. Chem. Ref. Data 45 (2016) 033105] and comparing with the recently published other corresponding state correlations, we found that this correlation reproduces the lowest absolute average deviation (AAD) values for 82 acids out of the 99 acids. It can reproduce the surface tension data with AAD less than 10% for 89 out of the 99 acids.

  10. Surface tension effect on the mechanical properties of nanomaterials measured by atomic force microscopy

    Science.gov (United States)

    Cuenot, Stéphane; Frétigny, Christian; Demoustier-Champagne, Sophie; Nysten, Bernard

    2004-04-01

    The effect of reduced size on the elastic properties measured on silver and lead nanowires and on polypyrrole nanotubes with an outer diameter ranging between 30 and 250 nm is presented and discussed. Resonant-contact atomic force microscopy (AFM) is used to measure their apparent elastic modulus. The measured modulus of the nanomaterials with smaller diameters is significantly higher than that of the larger ones. The latter is comparable to the macroscopic modulus of the materials. The increase of the apparent elastic modulus for the smaller diameters is attributed to surface tension effects. The surface tension of the probed material may be experimentally determined from these AFM measurements.

  11. An adaptive finite element method for simulating surface tension with the gradient theory of fluid interfaces

    KAUST Repository

    Kou, Jisheng; Sun, Shuyu

    2014-01-01

    The gradient theory for the surface tension of simple fluids and mixtures is rigorously analyzed based on mathematical theory. The finite element approximation of surface tension is developed and analyzed, and moreover, an adaptive finite element method based on a physical-based estimator is proposed and it can be coupled efficiently with Newton's method as well. The numerical tests are carried out both to verify the proposed theory and to demonstrate the efficiency of the proposed method. © 2013 Elsevier B.V. All rights reserved.

  12. An adaptive finite element method for simulating surface tension with the gradient theory of fluid interfaces

    KAUST Repository

    Kou, Jisheng

    2014-01-01

    The gradient theory for the surface tension of simple fluids and mixtures is rigorously analyzed based on mathematical theory. The finite element approximation of surface tension is developed and analyzed, and moreover, an adaptive finite element method based on a physical-based estimator is proposed and it can be coupled efficiently with Newton\\'s method as well. The numerical tests are carried out both to verify the proposed theory and to demonstrate the efficiency of the proposed method. © 2013 Elsevier B.V. All rights reserved.

  13. A simple laboratory experiment to measure the surface tension of a liquid in contact with air

    International Nuclear Information System (INIS)

    Riba, Jordi-Roger; Esteban, Bernat

    2014-01-01

    A simple and accurate laboratory experiment to measure the surface tension of liquids has been developed, which is well suited to teach the behaviour of liquids to first- or second-year students of physics, engineering or chemistry. The experimental setup requires relatively inexpensive equipment usually found in physics and chemistry laboratories, since it consists of a used or recycled burette, an analytical balance and a stereoscopic microscope or a micrometer. Experimental data and error analysis show that the surface tension of distilled water, 1-butanol and glycerol can be determined with accuracy better than 1.4%. (paper)

  14. Interrelation of surface tension, optical turbidity, and color of operational transformer oils

    International Nuclear Information System (INIS)

    L’vov, S. Yu.; Lyut’ko, E. O.; Lankau, Ya. V.; Komarov, V. B.; Seliverstov, A. F.; Bondareva, V. N.; L’vov, Yu. N.; L’vov, M. Yu.; Ershov, B. G.

    2011-01-01

    Measurements of the acidity, optical turbidity, surface tension, and color of transformer oil from 54 power transformers, autotransformers, and shunt reactors are reported. Changes in surface tension, optical turbidity, and color are found to obey adequate linear correlations, while the acidity has no correlation with any of these properties. Numerical criteria for the maximum permissible state (quality) of the oil with respect to optical turbidity and color are obtained. Recommendations to operating staff are provided for cases in which the criteria for optical turbidity and color are exceeded.

  15. Multi-phase-field method for surface tension induced elasticity

    Science.gov (United States)

    Schiedung, Raphael; Steinbach, Ingo; Varnik, Fathollah

    2018-01-01

    A method, based on the multi-phase-field framework, is proposed that adequately accounts for the effects of a coupling between surface free energy and elastic deformation in solids. The method is validated via a number of analytically solvable problems. In addition to stress states at mechanical equilibrium in complex geometries, the underlying multi-phase-field framework naturally allows us to account for the influence of surface energy induced stresses on phase transformation kinetics. This issue, which is of fundamental importance on the nanoscale, is demonstrated in the limit of fast diffusion for a solid sphere, which melts due to the well-known Gibbs-Thompson effect. This melting process is slowed down when coupled to surface energy induced elastic deformation.

  16. Simulation of Flow Behavior of Gas Condensate at Low Interfacial Tension

    DEFF Research Database (Denmark)

    Wang, Peng; Stenby, Erling Halfdan; Pope, Gary A.

    1996-01-01

    A vertical, long-core experiment of natural depletion of a gas condensate that was conducted by Elf Aquitaine is simulated by an equation-of-state (EOS) compositional simulator, UTCOMP. The Peng-Robinson (PR) EOS is used for phase-behavior calculation. Because of low interfactial tension (IFT......) in the measurement, more attention is paid to the influence of IFT on gas/oil flow behavior. Two different types of model are used to compute the relative permeability. Model I is a Corey-type model combined with the capillary number concept. Model II is a modified form of the model proposed by Coats.The simulation...... results indicate that the effect of low IFT on relative permeability can be reasonably described by the two models selected, although the producing gas-oil ratio (GOR) obtained using Model I deviates somewhat from the experimental values in later depletion stages. The condensed liquid can be a mobile...

  17. Adhesion of bubbles and drops to solid surfaces, and anisotropic surface tensions studied by capillary meniscus dynamometry

    NARCIS (Netherlands)

    Danov, Krassimir D.; Stanimirova, Rumyana D.; Kralchevsky, Peter A.; Marinova, Krastanka G.; Stoyanov, Simeon D.; Blijdenstein, Theodorus B.J.; Cox, Andrew R.; Pelan, Eddie G.

    2016-01-01

    Here, we review the principle and applications of two recently developed methods: the capillary meniscus dynamometry (CMD) for measuring the surface tension of bubbles/drops, and the capillary bridge dynamometry (CBD) for quantifying the bubble/drop adhesion to solid surfaces. Both methods are

  18. Simultaneous measurement of surface tension and viscosity using freely decaying oscillations of acoustically levitated droplets

    Science.gov (United States)

    Kremer, J.; Kilzer, A.; Petermann, M.

    2018-01-01

    Oscillations of small liquid drops around a spherical shape have been of great interest to scientists measuring physical properties such as interfacial tension and viscosity, over the last few decades. A powerful tool for contactless positioning is acoustic levitation, which has been used to simultaneously determine the surface tension and viscosity of liquids at ambient pressure. In order to extend this acoustic levitation measurement method to high pressure systems, the method is first evaluated under ambient pressure. To measure surface tension and viscosity using acoustically levitated oscillating drops, an image analysis method has to be developed and factors which may affect measurement, such as sound field or oscillation amplitude, have to be analyzed. In this paper, we describe the simultaneous measurement of surface tension and viscosity using freely decaying shape oscillations of acoustically levitated droplets of different liquids (silicone oils AK 5 and AK 10, squalane, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, 1-heptanol, and 1-octanol) in air. These liquids vary in viscosity from 2 to about 30 mPa s. An acoustic levitation system, including an optimized standing wave acoustic levitator and a high-speed camera, was used for this study. An image analysis was performed with a self-written Matlab® code. The frequency of oscillation and the damping constant, required for the determination of surface tension and viscosity, respectively, were calculated from the evolution of the equatorial and polar radii. The results and observations are compared to data from the literature in order to analyze the accuracy of surface tension and viscosity determination, as well as the effect of non-spherical drop shape or amplitude of oscillation on measurement.

  19. A nonpolar, nonamphiphilic molecule can accelerate adsorption of phospholipids and lower their surface tension at the air/water interface.

    Science.gov (United States)

    Nguyen, Phuc Nghia; Trinh Dang, Thuan Thao; Waton, Gilles; Vandamme, Thierry; Krafft, Marie Pierre

    2011-10-04

    The adsorption dynamics of a series of phospholipids (PLs) at the interface between an aqueous solution or dispersion of the PL and a gas phase containing the nonpolar, nonamphiphilic linear perfluorocarbon perfluorohexane (PFH) was studied by bubble profile analysis tensiometry. The PLs investigated were dioctanoylphosphatidylcholine (DiC(8)-PC), dilaurylphosphatidylcholine, dimyristoylphosphatidylcholine, and dipalmitoylphosphatidylcholine. The gas phase consisted of air or air saturated with PFH. The perfluorocarbon gas was found to have an unexpected, strong effect on both the adsorption rate and the equilibrium interfacial tension (γ(eq)) of the PLs. First, for all of the PLs, and at all concentrations investigated, the γ(eq) values were significantly lower (by up to 10 mN m(-1)) when PFH was present in the gas phase. The efficacy of PFH in decreasing γ(eq) depends on the ability of PLs to form micelles or vesicles in water. For vesicles, it also depends on the gel or fluid state of the membranes. Second, the adsorption rates of all the PLs at the interface (as assessed by the time required for the initial interfacial tension to be reduced by 30%) are significantly accelerated (by up to fivefold) by the presence of PFH for the lower PL concentrations. Both the surface-tension reducing effect and the adsorption rate increasing effect establish that PFH has a strong interaction with the PL monolayer and acts as a cosurfactant at the interface, despite the absence of any amphiphilic character. Fitting the adsorption profiles of DiC(8)-PC at the PFH-saturated air/aqueous solution interface with the modified Frumkin model indicated that the PFH molecule lay horizontally at the interface. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Shapes of an Air Taylor Bubble in Stagnant Liquids Influenced by Different Surface Tensions

    Science.gov (United States)

    Lertnuwat, B.

    2018-02-01

    The aim of this work is to propose an empirical model for predicting shapes of a Taylor bubble, which is a part of slug flows, under different values of the surface tension in stagnant liquids by employing numerical simulations. The k - Ɛ turbulence model was used in the framework of finite volume method for simulating flow fields in a unit of slug flow and also the pressure distribution on a Taylor bubble surface. Assuming that an air pressure distribution inside the Taylor bubble must be uniform, a grid search method was exploited to find an appropriate shape of a Taylor bubble for six values of surface tension. It was found that the shape of a Taylor bubble would be blunter if the surface tension was increased. This was because the surface tension affected the Froude number, controlling the flow around a Taylor bubble. The simulation results were also compared with the Taylor bubble shape, created by the Dumitrescu-and-Taylor model and former studies in order to ensure that they were consistent. Finally, the empirical model was presented from the simulation results.

  1. Combined Molecular Dynamics Simulation-Molecular-Thermodynamic Theory Framework for Predicting Surface Tensions.

    Science.gov (United States)

    Sresht, Vishnu; Lewandowski, Eric P; Blankschtein, Daniel; Jusufi, Arben

    2017-08-22

    A molecular modeling approach is presented with a focus on quantitative predictions of the surface tension of aqueous surfactant solutions. The approach combines classical Molecular Dynamics (MD) simulations with a molecular-thermodynamic theory (MTT) [ Y. J. Nikas, S. Puvvada, D. Blankschtein, Langmuir 1992 , 8 , 2680 ]. The MD component is used to calculate thermodynamic and molecular parameters that are needed in the MTT model to determine the surface tension isotherm. The MD/MTT approach provides the important link between the surfactant bulk concentration, the experimental control parameter, and the surfactant surface concentration, the MD control parameter. We demonstrate the capability of the MD/MTT modeling approach on nonionic alkyl polyethylene glycol surfactants at the air-water interface and observe reasonable agreement of the predicted surface tensions and the experimental surface tension data over a wide range of surfactant concentrations below the critical micelle concentration. Our modeling approach can be extended to ionic surfactants and their mixtures with both ionic and nonionic surfactants at liquid-liquid interfaces.

  2. Experimental and theoretical study of surface tension of binary mixtures of (n-alkyl acetates + heptane, benzene, and toluene)

    International Nuclear Information System (INIS)

    Rafati, Amir Abbas; Ghasemian, Ensieh

    2009-01-01

    Surface properties of binary mixtures of (n-alkyl acetates + heptane, benzene, and toluene) have been measured by surface tension method at T = 298.15 K and atmospheric pressure. Also, the surface tension has been predicted based on the Suarez method. This method combines a model for the description of surface tension of liquid mixtures with a group contribution method for the calculation of activity coefficient. The mean relative standard deviations obtained from the comparison of experimental (measured) and calculated surface tension values for the eight binary systems are less than 1.5%, which leads to concluding that the model shows a good accuracy in different situations in comparison with other predicted equations. In addition, the relative Gibbs adsorption and the surface mole fraction have been evaluated using this model. The surface tension deviations were calculated from experimental results and have been fitted to the Redlich-Kister type polynomial relation

  3. Fowler's approximation for the surface tension and surface energy of Lennard-Jones fluids revisited

    Energy Technology Data Exchange (ETDEWEB)

    Mulero, A [Departamento de Fisica, Universidad de Extremadura, 06071-Badajoz (Spain); Galan, C [Departamento de Fisica, Universidad de Extremadura, 06071-Badajoz (Spain); Cuadros, F [Departamento de Fisica, Universidad de Extremadura, 06071-Badajoz (Spain)

    2003-04-16

    We present a detailed study of the validity of Fowler's approximation for calculating the surface tension and the surface energy of Lennard-Jones fluids. To do so, we consider three different explicit analytical expressions for the radial distribution function (RDF), including one proposed by our research group, together with very accurate expressions for the liquid and vapour densities, also proposed by our group. The calculation of the surface tension from the direct correlation function using both the Percus-Yevick and the hypernetted-chain approximations is also considered. Finally, our results are compared with those obtained by other authors by computer simulations or through relevant theoretical approximations. In particular, we consider the analytical expression proposed by Kalikmanov and Hofmans (1994 J. Phys.: Condens. Matter 6 2207-14) for the surface tension. Our results indicate that the values for the surface energy in Fowler's approximation obtained by other authors are adequate, and can be calculated from the RDF models. For the surface tension, however, the values considered as valid in previous works seem to be incorrect. The correct values can be obtained from our model for the RDF or from the Kalikmanov and Hofmans expression with suitable inputs.

  4. Measurement and Modeling of Surface Tensions of Asymmetric Systems: Heptane, Eicosane, Docosane, Tetracosane and their Mixtures

    DEFF Research Database (Denmark)

    Queimada, Antonio; Silva, Filipa A. E.; Caco, Ana I.

    2003-01-01

    To extend the surface tension database for heavy or asymmetric n-alkane mixtures, measurements were performed using the Wilhelmy plate method. Measured systems included the binary mixtures heptane + eicosane, heptane + docosane and heptane + tetracosane and the ternary mixture heptane + eicosane ...

  5. Measurement and Modeling of Surface Tensions of Asymmetric Systems: Heptane, Eicosane, Docosane, Tetracosane and their Mixtures

    DEFF Research Database (Denmark)

    Queimada, Antonio; Silva, Filipa A.E; Caco, Ana I.

    2003-01-01

    To extend the surface tension database for heavy or asymmetric n-alkane mixtures, measurements were performed using the Wilhelmy plate method. Measured systems included the binary mixtures heptane + eicosane, heptane + docosane and heptane + tetracosane and the ternary mixture heptane + eicosane...

  6. Generation of Recommendable Values for the Surface Tension of Water Using a Nonparametric Regression

    Czech Academy of Sciences Publication Activity Database

    Pátek, Jaroslav; Součková, Monika; Klomfar, Jaroslav

    2016-01-01

    Roč. 61, č. 2 (2016), s. 928-935 ISSN 0021-9568 R&D Projects: GA ČR GA13-00145S Institutional support: RVO:61388998 Keywords : water * surface tension * experimental data * recommended data Subject RIV: BJ - Thermodynamics Impact factor: 2.323, year: 2016

  7. Standard reference data for the air-liquid and vapor-liquid surface tension of benzene

    Czech Academy of Sciences Publication Activity Database

    Součková, Monika; Klomfar, Jaroslav; Pátek, Jaroslav

    2013-01-01

    Roč. 356, October (2013), s. 329-337 ISSN 0378-3812 R&D Projects: GA ČR GA101/09/0010 Institutional support: RVO:61388998 Keywords : benzene * surface tension * experimental data * standard reference data Subject RIV: BJ - Thermodynamics Impact factor: 2.241, year: 2013 http://www.sciencedirect.com/science/article/pii/S0378381213004196

  8. Estimation of the Critical Temperatures of Some More Deep Eutectic Solvents from Their Surface Tensions

    Directory of Open Access Journals (Sweden)

    Yizhak Marcus

    2018-01-01

    Full Text Available The critical temperatures of two dozen deep eutectic solvents, for only some of which these have been estimated previously, were estimated from the temperature dependences of their surface tensions and densities available in the literature according to the Eötvös and the Guggenheim expressions.

  9. Density, viscosity and surface tension of liquid phase Beckmann rearrangement mixtures

    NARCIS (Netherlands)

    Zuidhof, K.T.; Croon, de M.H.J.M.; Schouten, J.C.; Tinge, J.T.

    2015-01-01

    We have determined the density, dynamic viscosity, and surface tension of liquid phase Beckmann rearrangement mixtures, consisting of e-caprolactam and fuming oleum. These important properties have been measured in wide ranges of both temperature and molar ratios of acid and e-caprolactam, covering

  10. Surface tension phenomena in the xylem sap of three diffuse porous temperate tree species

    Science.gov (United States)

    K. K. Christensen-Dalsgaard; M. T. Tyree; P. G. Mussone

    2011-01-01

    In plant physiology models involving bubble nucleation, expansion or elimination, it is typically assumed that the surface tension of xylem sap is equal to that of pure water, though this has never been tested. In this study we collected xylem sap from branches of the tree species Populus tremuloides, Betula papyrifera and Sorbus...

  11. On the theory of type-I superconductor surface tension and twinning-plane-superconductivity

    International Nuclear Information System (INIS)

    Mishonov, T.M.

    1990-01-01

    A correction is found to the surface tension in type-I superconductors which is proportional to the square root of the Ginsburg-Landau parameter. This correction is essential for obtaining the phase diagram and other thermodynamical variables of the narrow superconducting layer arising near the twinning plane in some metals

  12. Development of corresponding states model for estimation of the surface tension of chemical compounds

    DEFF Research Database (Denmark)

    Gharagheizi, Farhad; Eslamimanesh, Ali; Sattari, Mehdi

    2013-01-01

    include critical temperature or temperature/critical volume/acentric factor/critical pressure/reduced temperature/reduced normal boiling point temperature/molecular weight of the compounds. Around 1,300 surface tension data of 118 random compounds are used for developing the first model (a four...

  13. Relationship between surface tension and refractive index in binary non-electrolyte mixtures

    International Nuclear Information System (INIS)

    Acevedo, I.L.; Pedrosa, G.C.; Katz, M.

    1990-01-01

    Lorentz-Lorenz equation for molecular refraction has been combined with Sugden's parachor equation for binary non-electrolyte mixtures at 298.15 K. The obtained equation has been shown successful in calculating values of surface tensions, by measuring refractive indices of the binary mixtures at the same mole fractions. The estimated error decreases when the mixtures present possible isorefractives. (Author) [es

  14. Surface tension of heptane, decane, hexadecane, eicosane, and some of their binary mixtures

    DEFF Research Database (Denmark)

    Rolo, Lara I.; Caco, Ana I.; Queimada, Antonio

    2002-01-01

    Surface tension measurements were performed by the Wilhelmy plate method. Measured systems included pure heptane, decane, hexadecane, eicosane, and some of their binary mixtures at temperatures from 293.15 K to 343.15 K with an average absolute deviation of 1.6%. The results were compared with a ...

  15. On Surface Tension for Compact Stars R. Sharma & S. D. Maharaj

    Indian Academy of Sciences (India)

    Abstract. In an earlier analysis it was demonstrated that general rel- ativity gives higher values of surface tension in strange stars with quark matter than neutron stars.We generate the modified Tolman–Oppenheimer–. Volkoff equation to incorporate anisotropic matter and use this to show that pressure anisotropy provides ...

  16. Spreading of oil on water in the surface-tension regime

    Energy Technology Data Exchange (ETDEWEB)

    Camp, D.W.; Berg, J.C.

    1987-11-01

    Data which describe the unidirectional spreading of several pure oils and oil-surfactant mixtures on water in the surface-tension regime are reported. Leading-edge position and profiles of velocity, thickness and film tension are given as functions of time. The data are consistent with the numerical similarity solution of Foda and Cox (1980), although the measured dependence of the film tension on the film thickness often differs from the equilibrium relationship. The configuration of the oil film near the spreading origin may be either a coherent multimolecular layer or a multitude of thinning, outward-moving lenses surrounded by monolayer. The pure oils show an acceleration zone connecting the slow-moving inner region to a fast-moving outer region, while the oil-surfactant mixtures show a much more gradual increase in film velocity.

  17. Account for the surface tension in hydraulic modeling of the weir with a sharp threshold

    Directory of Open Access Journals (Sweden)

    Medzveliya Manana Levanovna

    Full Text Available In the process of calculating and simulating water discharge in free channels it is necessary to know the flow features in case of small values of Reynolds and Weber numbers. The article considers the influence of viscosity and surface tension on the coefficient of a weir flow with sharp threshold. In the article the technique of carrying out experiments is stated, the equation is presented, which considers the influence of all factors: pressure over a spillway threshold, threshold height over a course bottom, speed of liquid, liquid density, dynamic viscosity, superficial tension, gravity acceleration, unit discharge, the width of the course. The surface tension and liquid density for the applied liquids changed a little. In the rectangular tray (6000x100x200 spillway with a sharp threshold was established. It is shown that weir flow coefficient depends on Reynolds number (in case Re < ~ 2000 and Webers number. A generalized expression for determining weir flow coefficient considering the influence of the forces of viscosity and surface tension is received.

  18. Single-Step Fabrication of High-Density Microdroplet Arrays of Low-Surface-Tension Liquids.

    Science.gov (United States)

    Feng, Wenqian; Li, Linxian; Du, Xin; Welle, Alexander; Levkin, Pavel A

    2016-04-01

    A facile approach for surface patterning that enables single-step fabrication of high-density arrays of low-surface-tension organic-liquid microdroplets is described. This approach enables miniaturized and parallel high-throughput screenings in organic solvents, formation of homogeneous arrays of hydrophobic nanoparticles, polymer micropads of specific shapes, and polymer microlens arrays. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Surface density profile and surface tension of the one-component classical plasma

    International Nuclear Information System (INIS)

    Ballone, P.; Senatore, G.; Trieste Univ.; Tosi, M.P.; Oxford Univ.

    1982-08-01

    The density profile and the interfacial tension of two classical plasmas in equilibrium at different densities are evaluated in the square-density-gradient approximation. For equilibrium in the absence of applied external voltage, the profile is oscillatory in the higher-density plasma and the interfacial tension is positive. The amplitude and phase of these oscillations and the magnitude of the interfacial tension are related to the width of the background profile. Approximate representations of the equilibrium profile by matching of its asymptotic forms are analyzed. A comparison with computer simulation data and a critical discussion of a local-density theory are also presented. (author)

  20. Numerical simulation of binary collisions using a modified surface tension model with particle method

    International Nuclear Information System (INIS)

    Sun Zhongguo; Xi Guang; Chen Xi

    2009-01-01

    The binary collision of liquid droplets is of both practical importance and fundamental value in computational fluid mechanics. We present a modified surface tension model within the moving particle semi-implicit (MPS) method, and carry out two-dimensional simulations to investigate the mechanisms of coalescence and separation of the droplets during binary collision. The modified surface tension model improves accuracy and convergence. A mechanism map is established for various possible deformation pathways encountered during binary collision, as the impact speed is varied; a new pathway is reported when the collision speed is critical. In addition, eccentric collisions are simulated and the effect of the rotation of coalesced particle is explored. The results qualitatively agree with experiments and the numerical protocol may find applications in studying free surface flows and interface deformation

  1. Density and surface tension of melts of zirconium and hafnium fluorides with lithium fluoride

    International Nuclear Information System (INIS)

    Katyshev, S.F.; Artemov, V.V.; Desyatnik, V.N.

    1988-01-01

    A study was conducted to determine the temperature dependence of the density and surface tension of melts of LiF-ZrF 4 and LiF-HfF 4 . Density and surface tension were determined by the method of maximum pressure in an argon bubble. On the basis of experimental data over the entire concentration range the molar volumes and their relative deviations from the additive molar volumes were calculated for 1100 0 K. The positive deviations of the molar volumes from additivity in the LiF-HfF 4 system (22.45%) were greater than in the LiF-ZrF 4 system (15.75%). This indicated that the reaction with lithium fluoride is intensified with the switch to the hafnium fluoride. Results also demonstrated that the fluorides are surface-active components in the molten mixtures

  2. The Role of Surface Tension in the Crystallization of Metal Halide Perovskites

    KAUST Repository

    Zhumekenov, Ayan A.

    2017-07-06

    The exciting intrinsic properties discovered in single crystals of metal halide perovskites still await their translation into optoelectronic devices. The poor understanding and control of the crystallization process of these materials are current bottlenecks retarding the shift towards single crystal-based optoelectronics. Here we theoretically and experimentally elucidate the role of surface tension in the rapid synthesis of perovskite single crystals by inverse temperature crystallization (ITC). Understanding the nucleation and growth mechanisms enabled us to exploit surface tension to direct the growth of monocrystalline films of perovskites (AMX3, where A = CH3NH3+ or MA; M = Pb2+, Sn2+; X = Br-, I-) on the solution surface. We achieve up to 1 cm2-sized monocrystalline films with thickness on the order of the charge carrier diffusion length (~5-10 µm). Our work paves the way to control the crystallization process of perovskites, including thin film deposition, which is essential to advance the performance benchmarks of perovskite optoelectronics.

  3. Contact angle and surface tension measurements of a five-ring polyphenyl ether

    Science.gov (United States)

    Jones, W. R., Jr.

    1986-01-01

    Contact angle measurements were performed for a five-ring polyphenyl ether isomeric mixture on M-50 steel in a dry nitrogen atmosphere. Two different techniques were used: (1) a tilting plate apparatus, and (2) a sessile drop apparatus. Measurements were made for the temperature range 25 to 190 C. Surface tension was measured by a differential maximum bubble pressure technique over the range 23 to 220 C in room air. The critical surface energy of spreading (gamma /sub c/) was determined for the polyphenyl ether by plotting the cosine of the contact angle (theta) versus the surface tension (gamma /sub LV/). The straight line intercept at cosine theta = 1 is defined as gamma (sub c). Gamma (sub c) was found to be 30.1 dyn/cm for the tilting plate technique and 31.3 dyn/cm for the sessile drop technique. These results indicate that the polyphenyl ether is inherently autophobic (i.e., it will not spread on its own surface film until its surface tension is less than gamma /sub c/). This phenomenon is discussed in light of the wettability and wear problems encountered with this fluid.

  4. Relationships among ventilation-perfusion distribution, multiple inert gas methodology and metabolic blood-gas tensions.

    Science.gov (United States)

    Lee, A S; Patterson, R W; Kaufman, R D

    1987-12-01

    The retention equations upon which the Multiple Inert Gas Method is based are derived from basic principles using elementary algebra. It is shown that widely disparate distributions produce indistinguishable sets of retentions. The limits of resolution of perfused compartments in the VA/Q distribution obtainable by the use of the multiple inert gas method are explored mathematically, and determined to be at most shunt and two alveolar compartments ("tripartite" distribution). Every continuous distribution studied produced retentions indistinguishable from those of its unique "matching" tripartite distribution. When a distribution is minimally specified, it is unique. Any additional specification (increased resolution--more compartments) of the distribution results in the existence of an infinitude of possible distributions characterized by indistinguishable sets of retention values. No further increase in resolution results from the use of more tracers. When sets of retention values were extracted from published multiple inert gas method continuous distributions, and compared with the published "measured" retention sets, substantial differences were found. This illustrates the potential errors incurred in the practical, in vivo application of the multiple inert gas method. In preliminary studies, the tripartite distribution could be determined with at least comparable accuracy by blood-gas (oxygen, carbon dioxide) measurements.

  5. Determination of enthalpy, temperature, surface tension and geometry of the material transfer in PGMAW for the system argon–iron

    International Nuclear Information System (INIS)

    Siewert, E; Schein, J; Forster, G

    2013-01-01

    The metal transfer is a fundamental process in gas metal arc welding, which substantially determines the shape of the weld seam and strongly influences arc formation and stability. In this investigation the material transfer from the wire electrode (anode) to the workpiece (cathode) is analysed experimentally with high accuracy using various innovative diagnostic techniques for a pulsed gas metal arc welding (PGMAW) process. A high-speed two-colour pyrometer, a calorimeter, thermocouples, a stereo optical setup and a droplet oscillation technique are used to analyse a precisely defined PGMAW process. Thus, results obtained are verified by different measurement techniques and enable a comprehensive description of the material transfer procedure. The surface temperature of both electrodes as well as the droplet temperature, enthalpy and surface tension were determined. Furthermore, the geometry of the arc, wire, droplets and weld pool were extracted in three dimensions in order to describe the interaction between the material transfer and the formation of the weld seam. The experiments are performed using argon as shielding gas and pure iron as filler and base material to reduce complex chemical processes. It turned out that the wire feed rate has the biggest influence on droplet temperature and detachment. A correlation between weld pool formation and weld pool surface temperature gradient was observed, which is mainly a function of welding speed and wire feed rate. The experimental results obtained provide a detailed data pool for use in modelling. (paper)

  6. A finite-volume HLLC-based scheme for compressible interfacial flows with surface tension

    Energy Technology Data Exchange (ETDEWEB)

    Garrick, Daniel P. [Department of Aerospace Engineering, Iowa State University, Ames, IA (United States); Owkes, Mark [Department of Mechanical and Industrial Engineering, Montana State University, Bozeman, MT (United States); Regele, Jonathan D., E-mail: jregele@iastate.edu [Department of Aerospace Engineering, Iowa State University, Ames, IA (United States)

    2017-06-15

    Shock waves are often used in experiments to create a shear flow across liquid droplets to study secondary atomization. Similar behavior occurs inside of supersonic combustors (scramjets) under startup conditions, but it is challenging to study these conditions experimentally. In order to investigate this phenomenon further, a numerical approach is developed to simulate compressible multiphase flows under the effects of surface tension forces. The flow field is solved via the compressible multicomponent Euler equations (i.e., the five equation model) discretized with the finite volume method on a uniform Cartesian grid. The solver utilizes a total variation diminishing (TVD) third-order Runge–Kutta method for time-marching and second order TVD spatial reconstruction. Surface tension is incorporated using the Continuum Surface Force (CSF) model. Fluxes are upwinded with a modified Harten–Lax–van Leer Contact (HLLC) approximate Riemann solver. An interface compression scheme is employed to counter numerical diffusion of the interface. The present work includes modifications to both the HLLC solver and the interface compression scheme to account for capillary force terms and the associated pressure jump across the gas–liquid interface. A simple method for numerically computing the interface curvature is developed and an acoustic scaling of the surface tension coefficient is proposed for the non-dimensionalization of the model. The model captures the surface tension induced pressure jump exactly if the exact curvature is known and is further verified with an oscillating elliptical droplet and Mach 1.47 and 3 shock-droplet interaction problems. The general characteristics of secondary atomization at a range of Weber numbers are also captured in a series of simulations.

  7. Novel method for the simultaneous estimation of density and surface tension of liquids

    International Nuclear Information System (INIS)

    Thirunavukkarasu, G.; Srinivasan, G.J.

    2003-01-01

    The conventional Hare's apparatus generally used for the determination of density of liquids has been modified by replacing its vertical arms (glass tubes) with capillary tubes of 30 cm length and 0.072 cm diameter. When the columns of liquids are drawn through the capillary tubes with reduced pressure at the top of the liquid columns and kept at equilibrium with the atmospheric pressure acting on the liquid surface outside the capillary tubes, the downward pressure due to gravity of the liquid columns has to be coupled with the pressure arising due to the effect of surface tension of the liquids. A fresh expression for the density and surface tension of liquids has been arrived at while equating the pressure balancing system for the two individual liquid columns of the modified Hare's apparatus. The experimental results showed that the proposed method is precise and accurate in the simultaneous estimation of density and surface tension of liquids, with an error of less than 5%

  8. Non-invasive high throughput approach for protein hydrophobicity determination based on surface tension.

    Science.gov (United States)

    Amrhein, Sven; Bauer, Katharina Christin; Galm, Lara; Hubbuch, Jürgen

    2015-12-01

    The surface hydrophobicity of a protein is an important factor for its interactions in solution and thus the outcome of its production process. Yet most of the methods are not able to evaluate the influence of these hydrophobic interactions under natural conditions. In the present work we have established a high resolution stalagmometric method for surface tension determination on a liquid handling station, which can cope with accuracy as well as high throughput requirements. Surface tensions could be derived with a low sample consumption (800 μL) and a high reproducibility (content. The protein influence on the solutions' surface tension was correlated to the hydrophobicity of lysozyme, human lysozyme, BSA, and α-lactalbumin. Differences in proteins' hydrophobic character depending on pH and species could be resolved. Within this work we have developed a pH dependent hydrophobicity ranking, which was found to be in good agreement with literature. For the studied pH range of 3-9 lysozyme from chicken egg white was identified to be the most hydrophilic. α-lactalbumin at pH 3 exhibited the most pronounced hydrophobic character. The stalagmometric method occurred to outclass the widely used spectrophotometric method with bromophenol blue sodium salt as it gave reasonable results without restrictions on pH and protein species. © 2015 Wiley Periodicals, Inc.

  9. Analytical description of concentration dependence of surface tension in multicomponent systems

    Energy Technology Data Exchange (ETDEWEB)

    Dadashev, R; Kutuev, R [Complex Science Research Institute of the Science Academy of the Chechen Republic, 21 Staropromisl. shosse, Grozny 364096 (Russian Federation); Elimkhanov, D [Science Academy of the Chechen Republic (Russian Federation)], E-mail: edzhabrail@mail.ru

    2008-02-15

    From the basic fundamental thermodynamic expressions the equation of isotherms of the surface tension of a ternary system is received. Various assumptions concerning the concentration dependence of molar areas are usually made when the equation is derived. The dependence of the molar areas is calculated as an additive function of the structure of a volumetric phase or the structure of a surface layer. To define the concentration dependence of the molar areas we used a stricter thermodynamic expression offered by Butler. In the received equation the dependence of molar areas on the structure of the solution is taken into account. Therefore, the equation can be applied for the calculation of surface tension over a wide concentration range of the components. Unlike the known expressions, the equation includes the surface tension properties of lateral binary systems, which makes the accuracy of the calculated values considerably higher. Thus, among the advantages of the offered equation we can point out the mathematical simplicity of the received equation and the fact that the equation includes physical parameters the experimental definition of which does not present any special difficulties.

  10. Discrepancies over the onset of surfactant monomer aggregation interpreted by fluorescence, conductivity and surface tension methods

    Directory of Open Access Journals (Sweden)

    Maria de Fátima Carvalho Costa

    1998-06-01

    Full Text Available Molecular probe techniques have made important contributions to the determination of microstructure of surfactant assemblies such as size, stability, micropolarity and conformation. Conductivity and surface tension were used to determine the critical aggregation concentration (cac of polymer-surfactant complexes and the critical micellar concentration (cmc of aqueous micellar aggregates. The results are compared with those of fluorescent techniques. Several surfactant systems were examined, 1-butanol-sodium dodecylsulfate (SDS mixtures, solutions containing poly(ethylene oxide-SDS, poly(vinylpyrrolidone-SDS and poly(acrylic acid-alkyltrimethylammonium bromide complexes. We found differences between the cac and cmc values obtained by conductivity or surface tension and those obtained by techniques which use hydrophobic probe.

  11. Light Meets Water in Nonlocal Media: Surface Tension Analogue in Optics

    Science.gov (United States)

    Horikis, Theodoros P.; Frantzeskakis, Dimitrios J.

    2017-06-01

    Shallow water wave phenomena find their analogue in optics through a nonlocal nonlinear Schrödinger (NLS) model in 2 +1 dimensions. We identify an analogue of surface tension in optics, namely, a single parameter depending on the degree of nonlocality, which changes the sign of dispersion, much like surface tension does in the shallow water wave problem. Using multiscale expansions, we reduce the NLS model to a Kadomtsev-Petviashvili (KP) equation, which is of the KPII (KPI) type, for strong (weak) nonlocality. We demonstrate the emergence of robust optical antidark solitons forming Y -, X -, and H -shaped wave patterns, which are approximated by colliding KPII line solitons, similar to those observed in shallow waters.

  12. On the Problem of Determining Aggregation Numbers from Surface Tension Measurements.

    Science.gov (United States)

    Rusanov, Anatoly I

    2017-11-07

    In view of the recent discovery of variable aggregation numbers in the vicinity of the critical micelle concentration (CMC), the mass-action-law theory of the surface tension isotherm of a micellar solution with variable aggregation numbers is formulated both for nonionic and ionic surfactants. It is shown that the shape of the surface tension isotherm should be concave in the logarithmic scale above the CMC. Considering a change in the isotherm slope at the CMC apparent break point, the problems of determining the aggregation number for nonionic micelles and the degree of counterion binding for ionic micelles are discussed. In case of the aggregation number variability near the CMC, finding the aggregation number above the CMC apparent break point is considered and a computational scheme is elaborated, requiring a higher precision for experiment. Some experimental data from the literature are analyzed, and the method of estimating the degree of counterion binding is improved.

  13. Interfacial Tension and Surface Pressure of High Density Lipoprotein, Low Density Lipoprotein, and Related Lipid Droplets

    DEFF Research Database (Denmark)

    Ollila, O. H. S.; Lamberg, A.; Lehtivaara, M.

    2012-01-01

    ) are essentially lipid droplets surrounded by specific proteins, their main function being to transport cholesterol. Interfacial tension and surface pressure of these particles are of great interest because they are related to the shape and the stability of the droplets and to protein adsorption at the interface....... Here we use coarse-grained molecular-dynamics simulations to consider a number of related issues by calculating the interfacial tension in protein-free lipid droplets, and in HDL and LDL particles mimicking physiological conditions. First, our results suggest that the curvature dependence......Lipid droplets play a central role in energy storage and metabolism on a cellular scale. Their core is comprised of hydrophobic lipids covered by a surface region consisting of amphiphilic lipids and proteins. For example, high and low density lipoproteins (HDL and LDL, respectively...

  14. Surface Tension Flows inside Surfactant-Added Poly(dimethylsiloxane Microstructures with Velocity-Dependent Contact Angles

    Directory of Open Access Journals (Sweden)

    Jyh Jian Chen

    2014-03-01

    Full Text Available Filling of liquid samples is realized in a microfluidic device with applications including analytical systems, biomedical devices, and systems for fundamental research. The filling of a disk-shaped polydimethylsiloxane (PDMS microchamber by liquid is analyzed with reference to microstructures with inlets and outlets. The microstructures are fabricated using a PDMS molding process with an SU-8 mold. During the filling, the motion of the gas-liquid interface is determined by the competition among inertia, adhesion, and surface tension. A single ramp model with velocity-dependent contact angles is implemented for the accurate calculation of surface tension forces in a three-dimensional volume-of-fluid based model. The effects of the parameters of this functional form are investigated. The influences of non-dimensional parameters, such as the Reynolds number and the Weber number, both determined by the inlet velocity, on the flow characteristics are also examined. An oxygen-plasma-treated PDMS substrate is utilized, and the microstructure is modified to be hydrophilic. Flow experiments are conducted into both hydrophilic and hydrophobic PDMS microstructures. Under a hydrophobic wall condition, numerical simulations with imposed boundary conditions of static and dynamic contact angles can successfully predict the moving of the meniscus compared with experimental measurements. However, for a hydrophilic wall, accurate agreement between numerical and experimental results is obvious as the dynamic contact angles were implemented.

  15. A finite-density calculation of the surface tension of isotropic-nematic interfaces

    International Nuclear Information System (INIS)

    Moore, B.G.; McMullen, W.E.

    1992-01-01

    The surface tension of the isotropic-nematic interface in a fluid of intermediate-sized hard particles is studied and calculated. The transition from isotropic to nematic is fixed to occur in a continuous fashion by varying the biaxiality of the model particles. A reversal in the preferred orientation of the bulk nematic relative to the isotropic-nematic interface suggests an oblique orientation of the bulk nematic. 32 refs., 8 figs

  16. Let’s not forget the critical role of surface tension in xylem water relations

    Science.gov (United States)

    Jean-Christophe Domec

    2011-01-01

    The widely supported cohesion–tension theory of water transport explains the importance of a continuous water column and the mechanism of long-distance ascent of sap in plants (Dixon 1914, Tyree 2003, Angeles et al. 2004). The evaporation of water from the surfaces of mesophyll cells causes the air–water interface to retreat into the cellulose matrix of the plant cell...

  17. A Synthetic Phased Array Surface Acoustic Wave Sensor for Quantifying Bolt Tension

    Directory of Open Access Journals (Sweden)

    Rasim Guldiken

    2012-09-01

    Full Text Available In this paper, we report our findings on implementing a synthetic phased array surface acoustic wave sensor to quantify bolt tension. Maintaining proper bolt tension is important in many fields such as for ensuring safe operation of civil infrastructures. Significant advantages of this relatively simple methodology is its capability to assess bolt tension without any contact with the bolt, thus enabling measurement at inaccessible locations, multiple bolt measurement capability at a time, not requiring data collection during the installation and no calibration requirements. We performed detailed experiments on a custom-built flexible bench-top experimental setup consisting of 1018 steel plate of 12.7 mm (½ in thickness, a 6.4 mm (¼ in grade 8 bolt and a stainless steel washer with 19 mm (¾ in of external diameter. Our results indicate that this method is not only capable of clearly distinguishing properly bolted joints from loosened joints but also capable of quantifying how loose the bolt actually is. We also conducted detailed signal-to-noise (SNR analysis and showed that the SNR value for the entire bolt tension range was sufficient for image reconstruction.

  18. Effect of liquid surface tension on circular and linear hydraulic jumps; theory and experiments

    Science.gov (United States)

    Bhagat, Rajesh Kumar; Jha, Narsing Kumar; Linden, Paul F.; Wilson, David Ian

    2017-11-01

    The hydraulic jump has attracted considerable attention since Rayleigh published his account in 1914. Watson (1964) proposed the first satisfactory explanation of the circular hydraulic jump by balancing the momentum and hydrostatic pressure across the jump, but this solution did not explain what actually causes the jump to form. Bohr et al. (1992) showed that the hydraulic jump happens close to the point where the local Froude number equals to one, suggesting a balance between inertial and hydrostatic contributions. Bush & Aristoff (2003) subsequently incorporated the effect of surface tension and showed that this is important when the jump radius is small. In this study, we propose a new account to explain the formation and evolution of hydraulic jumps under conditions where the jump radius is strongly influenced by the liquid surface tension. The theory is compared with experiments employing liquids of different surface tension and different viscosity, in circular and linear configurations. The model predictions and the experimental results show excellent agreement. Commonwealth Scholarship Commission, St. John's college, University of Cambridge.

  19. Surface tension and wetting properties of rapeseed oil to biofuel conversion by-products

    Science.gov (United States)

    Muszyński, Siemowit; Sujak, Agnieszka; Stępniewski, Andrzej; Kornarzyński, Krzysztof; Ejtel, Marta; Kowal, Natalia; Tomczyk-Warunek, Agnieszka; Szcześniak, Emil; Tomczyńska-Mleko, Marta; Mleko, Stanisław

    2018-04-01

    This work presents a study on the surface tension, density and wetting behaviour of distilled glycerol, technical grade glycerol and the matter organic non-glycerin fraction. The research was conducted to expand the knowledge about the physical properties of wastes from the rapeseed oil biofuel production. The results show that the densities of technical grade glycerol (1.300 g cm-3) and distilled glycerol (1.267 g cm-3) did not differ and were significantly lower than the density of the matter organic non-glycerin fraction (1.579 g cm-3). Furthermore, the surface tension of distilled glycerol (49.6 mN m-1) was significantly higher than the matter organic non-glycerin fraction (32.7 mN m-1) and technical grade glycerol (29.5 mN m-1). As a result, both technical grade glycerol and the matter organic non-glycerin fraction had lower contact angles than distilled glycerol. The examined physical properties of distilled glycerol were found to be very close to that of the commercially available pure glycerol. The results suggest that technical grade glycerol may have potential application in the production of glycerol/fuel blends or biosurfactants. The presented results indicate that surface tension measurements are more useful when examining the quality of biofuel wastes than is density determination, as they allow for a more accurate analysis of the effects of impurities on the physical properties of the biofuel by-products.

  20. The behavior of surface tension on steady-state rotating fluids in the low gravity environments

    Science.gov (United States)

    Hung, R. J.; Leslie, Fred W.

    1987-01-01

    The effect of surface tension on steady-state rotating fluids in a low gravity environment is studied. All the values of the physical parameters used in these calculations, except in the low gravity environments, are based on the measurements carried out by Leslie (1985) in the low gravity environment of a free-falling aircraft. The profile of the interface of two fluids is derived from Laplace's equation relating the pressure drop across an interface to the radii of curvature which has been applied to a low gravity rotating bubble that contacts the container boundary. The interface shape depends on the ratio of gravity to surface tension forces, the ratio of centrifugal to surface tension forces, the contact radius of the interface to the boundary, and the contact angle. The shape of the bubble is symmetric about its equator in a zero-gravity environment. This symmetry disappears and gradually shifts to parabolic profiles as the gravity environment becomes non-zero. The location of the maximum radius of the bubble moves upward from the center of the depth toward the top boundary of the cylinder as gravity increases. The contact radius of interface to the boundary r0 at the top side of cylinder increases and r0 at the bottom side of the cylinder decreases as the gravity environment increases from zero to 1 g.

  1. Surface crack growth in cylindrical hollow specimen subject to tension and torsion

    Directory of Open Access Journals (Sweden)

    V. Shlyannikov

    2015-07-01

    Full Text Available The subject for studies is an aluminium cylindrical hollow specimen with external axial and part circumferential semi-elliptical surface crack undergoing fatigue loads. Both the optical microscope measurements and the crack opening displacement (COD method are used to monitor and calculate both crack depth and crack length during the tests. The variation of crack growth behaviour is studied under cyclic axial tension, pure torsion and combined tension+torsion fatigue loading. For the particular surface flaw geometries considered, the elastic and plastic in-plane and out-of-plane constraint parameters, as well as the governing parameter for stress fields in the form of In-integral and plastic stress intensity factor, are obtained as a function of the aspect ratio, dimensionless crack length and crack depth. The combined effect of tension and torsion loading and initial surface flaw orientation on the crack growth for two type of aluminium alloys is made explicit. The experimental and numerical results of the present study provided the opportunity to explore the suggestion that fatigue crack propagation may be governed more strongly by the plastic stress intensity factor rather than the magnitude of the elastic SIFs alone. One advantage of the plastic SIF is its sensitivity to combined loading due to accounting for the plastic properties of the material.

  2. Two Surface-Tension Formulations For The Level Set Interface-Tracking Method

    International Nuclear Information System (INIS)

    Shepel, S.V.; Smith, B.L.

    2005-01-01

    The paper describes a comparative study of two surface-tension models for the Level Set interface tracking method. In both models, the surface tension is represented as a body force, concentrated near the interface, but the technical implementation of the two options is different. The first is based on a traditional Level Set approach, in which the surface tension is distributed over a narrow band around the interface using a smoothed Delta function. In the second model, which is based on the integral form of the fluid-flow equations, the force is imposed only in those computational cells through which the interface passes. Both models have been incorporated into the Finite-Element/Finite-Volume Level Set method, previously implemented into the commercial Computational Fluid Dynamics (CFD) code CFX-4. A critical evaluation of the two models, undertaken in the context of four standard Level Set benchmark problems, shows that the first model, based on the smoothed Delta function approach, is the more general, and more robust, of the two. (author)

  3. On the modelling of semi-insulating GaAs including surface tension and bulk stresses

    Energy Technology Data Exchange (ETDEWEB)

    Dreyer, W.; Duderstadt, F.

    2004-07-01

    Necessary heat treatment of single crystal semi-insulating Gallium Arsenide (GaAs), which is deployed in micro- and opto- electronic devices, generate undesirable liquid precipitates in the solid phase. The appearance of precipitates is influenced by surface tension at the liquid/solid interface and deviatoric stresses in the solid. The central quantity for the description of the various aspects of phase transitions is the chemical potential, which can be additively decomposed into a chemical and a mechanical part. In particular the calculation of the mechanical part of the chemical potential is of crucial importance. We determine the chemical potential in the framework of the St. Venant-Kirchhoff law which gives an appropriate stress/strain relation for many solids in the small strain regime. We establish criteria, which allow the correct replacement of the St. Venant-Kirchhoff law by the simpler Hooke law. The main objectives of this study are: (i) We develop a thermo-mechanical model that describes diffusion and interface motion, which both are strongly influenced by surface tension effects and deviatoric stresses. (ii) We give an overview and outlook on problems that can be posed and solved within the framework of the model. (iii) We calculate non-standard phase diagrams, i.e. those that take into account surface tension and non-deviatoric stresses, for GaAs above 786 C, and we compare the results with classical phase diagrams without these phenomena. (orig.)

  4. Faraday forcing of high-temperature levitated liquid metal drops for the measurement of surface tension.

    Science.gov (United States)

    Brosius, Nevin; Ward, Kevin; Matsumoto, Satoshi; SanSoucie, Michael; Narayanan, Ranga

    2018-01-01

    In this work, a method for the measurement of surface tension using continuous periodic forcing is presented. To reduce gravitational effects, samples are electrostatically levitated prior to forcing. The method, called Faraday forcing, is particularly well suited for fluids that require high temperature measurements such as liquid metals where conventional surface tension measurement methods are not possible. It offers distinct advantages over the conventional pulse-decay analysis method when the sample viscosity is high or the levitation feedback control system is noisy. In the current method, levitated drops are continuously translated about a mean position at a small, constant forcing amplitude over a range of frequencies. At a particular frequency in this range, the drop suddenly enters a state of resonance, which is confirmed by large executions of prolate/oblate deformations about the mean spherical shape. The arrival at this resonant condition is a signature that the parametric forcing frequency is equal to the drop's natural frequency, the latter being a known function of surface tension. A description of the experimental procedure is presented. A proof of concept is given using pure Zr and a Ti 39.5 Zr 39.5 Ni 21 alloy as examples. The results compare favorably with accepted literature values obtained using the pulse-decay method.

  5. Effects of Ce concentrations on ignition temperature and surface tension of Mg-9wt.%Al alloy

    OpenAIRE

    Deng Zhenghua; Li Huaji; Zhao Wanjun

    2013-01-01

    Magnesium alloys are well known for their excellent properties, but the potential issues with oxidation and burning during melting and casting largely limit its industrial applications. The addition of Ce in magnesium alloys can significantly raise ignition-proof performance and change the structure of the oxide film on the surface of the molten metal as well as the surface tension values. Surface tension is an important physical parameter of the metal melts, and it plays an important role in...

  6. Influence of Contact Angle, Growth Angle and Melt Surface Tension on Detached Solidification of InSb

    Science.gov (United States)

    Wang, Yazhen; Regel, Liya L.; Wilcox, William R.

    2000-01-01

    We extended the previous analysis of detached solidification of InSb based on the moving meniscus model. We found that for steady detached solidification to occur in a sealed ampoule in zero gravity, it is necessary for the growth angle to exceed a critical value, the contact angle for the melt on the ampoule wall to exceed a critical value, and the melt-gas surface tension to be below a critical value. These critical values would depend on the material properties and the growth parameters. For the conditions examined here, the sum of the growth angle and the contact angle must exceed approximately 130, which is significantly less than required if both ends of the ampoule are open.

  7. The influence of microstructure on surface strain distributions in a nickel micro-tension specimen

    International Nuclear Information System (INIS)

    Turner, T J; Shade, P A; Schuren, J C; Groeber, M A

    2013-01-01

    This work presents an integrated experimental and modeling approach for examining the deformation of a pure nickel polycrystal utilizing micro-mechanical testing and a crystal-based elasto-viscoplastic finite-element model (CPFEM). The objective is to study the influence of microstructure on the heterogeneous deformation in polycrystalline materials, and to utilize a modeling framework to explore aspects of the deformation that are difficult or impossible to measure experimentally. To accomplish this, a micro-tension specimen containing 259 grains was created from a pure nickel foil material and deformed in uniaxial tension. After the deformation, the specimen was destructively serial sectioned in concert with electron back scattering diffraction, and these data were used to instantiate a CPFEM simulation. The material parameters in the CPFEM model were calibrated by matching the experimental macroscopic stress-strain response of the micro-tension specimen, and then the simulation results were compared with experimental surface deformations measured with digital image correlation. After validating the simulation results by comparing measured and predicted surface strain distributions, a parametric study of the influence of both crystallographic texture and grain morphology is presented to better understand the influence of microstructure on the development of heterogeneous deformation in the pure nickel polycrystalline material. (paper)

  8. Effects of Ce concentrations on ignition temperature and surface tension of Mg-9wt.%Al alloy

    Directory of Open Access Journals (Sweden)

    Deng Zhenghua

    2013-03-01

    Full Text Available Magnesium alloys are well known for their excellent properties, but the potential issues with oxidation and burning during melting and casting largely limit its industrial applications. The addition of Ce in magnesium alloys can significantly raise ignition-proof performance and change the structure of the oxide film on the surface of the molten metal as well as the surface tension values. Surface tension is an important physical parameter of the metal melts, and it plays an important role in the formation of surface oxide film. In this present work, the ignition temperature and the surface tension of Mg-9wt.%Al alloy with different Ce concentrations were studied. Surface tensions was measured using the maximum bubble pressure method (MBPM. Ignition temperature was measured using NiCr-NiSi type thermocouples and was monitored and recorded via a WXT-604 desk recording device. The results show that the ignition point of Mg-9wt.%Al alloy can be effectively elevated by adding Ce. The ignition temperature reaches its highest point of 720 ℃ when the addition of Ce is 1wt.%. The surface tension of the molten Mg-9wt.%Al alloy decreases exponentially with the increase of Ce addition at the same temperature. Similarly, the experiment also shows that the surface tension of Mg-9wt.%Al alloy decreases exponentially with the increase of temperature.

  9. Surface tension of a coal extract in an organic solvent; Sekitan chushutsu seibun no kaigo to hyomen choryoku

    Energy Technology Data Exchange (ETDEWEB)

    Kikuchi, T.; Hayasaka, K.; Takanohashi, T.; Iino, M. [Tohoku University, Sendai (Japan). Institute for Chemical Reaction Science

    1996-10-28

    The behavior and properties of associated bodies were studied through measurement of surface tension considering acetone-soluble fraction relatively light among various solvent extracts of coal. In experiment, the acetone-soluble fraction was extracted from the substances extracted from Upper Freeport coal as standard specimen using the mixed solvent of carbon disulfide (CS2) and N-methyl-2-pyrrolidinone (NMP), and it was dissolved into NMP after drying. Surface tension was measured by Wilhelmy method. The experimental results are as follows. Equilibrium surface tension is equal to the surface tension of pure solvent in a low concentration range of solution, and decreases with an increase in concentration approaching a fixed value at 0 in log concentration, nearly showing an S curve. Adsorption of species with non-polar aromatic ring of the acetone-soluble fraction on a solution surface probably decreases surface tension. Change with time in surface tension is observed which suggests fast initial reaction and slow subsequent reaction. 4 figs.

  10. On a Hele-Shaw flow with a time-dependent gap in the presence of surface tension

    International Nuclear Information System (INIS)

    Savina, T V; Nepomnyashchy, A A

    2015-01-01

    The introduction of surface tension into a Hele-Shaw problem makes it more realistic from the physical viewpoint, but more difficult from the mathematical viewpoint. In this paper we discuss a Hele-Shaw flow with a time-dependent gap taking into account the surface tension of the free boundary. We use the Schwarz function method to find asymptotic solutions for the interior problem in the case when the initial shape of the droplet is a weakly distorted circle. (paper)

  11. A waveless two-dimensional flow in a channel against an inclined wall with surface tension effect

    International Nuclear Information System (INIS)

    Merzougui, Abdelkrim; Mekias, Hocine; Guechi, Fairouz

    2007-01-01

    Surface tension effect on a two-dimensional channel flow against an inclined wall is considered. The flow is assumed to be steady, irrotational, inviscid and incompressible. The effect of surface tension is taken into account and the effect of gravity is neglected. Numerical solutions are obtained via series truncation procedure. The problem is solved numerically for various values of the Weber number α and for various values of the inclination angle β between the horizontal bottom and the inclined wall

  12. A waveless two-dimensional flow in a channel against an inclined wall with surface tension effect

    Energy Technology Data Exchange (ETDEWEB)

    Merzougui, Abdelkrim [Departement de Mathematiques, Faculte des sciences, Universite Mohamed Boudiaf, M' sila, 28000 (Algeria); Mekias, Hocine [Departement de Mathematiques, Faculte des sciences, Universite Farhat Abbas Setif 19000 (Algeria); Guechi, Fairouz [Departement de Mathematiques, Faculte des sciences, Universite Farhat Abbas Setif 19000 (Algeria)

    2007-11-23

    Surface tension effect on a two-dimensional channel flow against an inclined wall is considered. The flow is assumed to be steady, irrotational, inviscid and incompressible. The effect of surface tension is taken into account and the effect of gravity is neglected. Numerical solutions are obtained via series truncation procedure. The problem is solved numerically for various values of the Weber number {alpha} and for various values of the inclination angle {beta} between the horizontal bottom and the inclined wall.

  13. Annotated bibliography for liquid metal surface tensions of groups III-A, IV-A, and V-A metals

    International Nuclear Information System (INIS)

    Murtha, M.J.; Burnet, G.

    1976-04-01

    An annotated bibliography has been prepared which includes summaries of 82 publications dating from 1920 and dealing with the measurement of the surface tensions of Groups III-A, IV-A, and V-A metals in the liquid state. The bibliography is organized by key element investigated, and contains a tabulation of correlations for surface tension as a function of temperature. A brief discussion dealing with variables and methods has been included

  14. Use of local and global limit load solutions for plates with surface cracks under tension

    Energy Technology Data Exchange (ETDEWEB)

    Lei, Y. [British Energy Generation Ltd, Barnett Way, Bamwood, Gloucester GL4 3RS (United Kingdom)], E-mail: yuebao.lei@british-energy.com

    2007-09-15

    Some available experimental results for the ductile failure of plates with surface cracks under tension are reviewed. The response of crack driving force, J, and the ligament strain near the local and global limit loads are investigated by performing elastic-perfectly plastic finite element (FE) analysis of a plate with a semi-elliptical crack under tension. The results show that a ligament may survive until the global collapse load is reached when the average ligament strain at the global collapse load, which depends on the uniaxial strain corresponding to the flow stress of the material and the crack geometry, is less than the true fracture strain of the material obtained from uniaxial tension tests. The FE analysis shows that ligament yielding corresponding to the local limit load has little effect on J and the average ligament strain, whereas approach to global collapse corresponds to a sharp increase in both J and the average ligament strain. The prediction of the FE value of J using the reference stress method shows that the global limit load is more relevant to J-estimation than the local one.

  15. Use of local and global limit load solutions for plates with surface cracks under tension

    International Nuclear Information System (INIS)

    Lei, Y.

    2007-01-01

    Some available experimental results for the ductile failure of plates with surface cracks under tension are reviewed. The response of crack driving force, J, and the ligament strain near the local and global limit loads are investigated by performing elastic-perfectly plastic finite element (FE) analysis of a plate with a semi-elliptical crack under tension. The results show that a ligament may survive until the global collapse load is reached when the average ligament strain at the global collapse load, which depends on the uniaxial strain corresponding to the flow stress of the material and the crack geometry, is less than the true fracture strain of the material obtained from uniaxial tension tests. The FE analysis shows that ligament yielding corresponding to the local limit load has little effect on J and the average ligament strain, whereas approach to global collapse corresponds to a sharp increase in both J and the average ligament strain. The prediction of the FE value of J using the reference stress method shows that the global limit load is more relevant to J-estimation than the local one

  16. The influence of surface-active agents in gas mixture on the intensity of jet condensation

    Science.gov (United States)

    Yezhov, YV; Okhotin, VS

    2017-11-01

    The report presents: the methodology of calculation of contact condensation of steam from the steam-gas mixture into the stream of water, taking into account: the mass flow of steam through the boundary phase, particularly the change in turbulent transport properties near the interface and their connection to the interface perturbations due to the surface tension of the mixture; the method of calculation of the surface tension at the interface water - a mixture of fluorocarbon vapor and water, based on the previously established analytical methods we calculate the surface tension for simple one - component liquid-vapor systems. The obtained analytical relation to calculate the surface tension of the mixture is a function of temperature and volume concentration of the fluorocarbon gas in the mixture and is true for all sizes of gas molecules. On the newly created experimental stand is made verification of experimental studies to determine the surface tension of pure substances: water, steam, C3F8 pair C3F8, produced the first experimental data on surface tension at the water - a mixture of water vapor and fluorocarbon C3F8. The obtained experimental data allow us to refine the values of the two constants used in the calculated model of the surface tension of the mixture. Experimental study of jet condensation was carried out with the flow in the zone of condensation of different gases. The condensation process was monitored by measurement of consumption of water flowing from the nozzle, and the formed condensate. When submitting C3F8, there was a noticeable, intensification condensation process compared with the condensation of pure water vapor. The calculation results are in satisfactory agreement with the experimental data on surface tension of the mixture and steam condensation from steam-gas mixture. Analysis of calculation results shows that the presence of surfactants in the condensation zone affects the partial vapor pressure on the interfacial surface, and

  17. The approximate determination of the critical temperature of a liquid by measuring surface tension versus the temperature

    International Nuclear Information System (INIS)

    Maroto, J A; Nieves, F J de las; Quesada-Perez, M

    2004-01-01

    A classical experience in a physics student laboratory is to determine the surface tension of a liquid versus the temperature and to check the linear appearance of the obtained graph. In this work we show a simple method to estimate the critical temperature of three liquids by using experimental data of surface tension at different temperatures. By a logarithm fitting between surface tension and temperature, the critical temperature can be determined and compared with data from the literature. For two liquids (butanol and nitrobenzene) the comparison is acceptable but the differences are too high for the third liquid (water). By discussing the results it seems to be clear that the difference between the critical temperature of the liquid and the maximum temperature of the surface tension measurements is the determining factor in obtaining acceptable results. From this study it is possible to obtain more information on the liquid characteristics from surface tension measurements that are currently carried out in a student laboratory. Besides, in this paper it is shown how to select the most suitable liquids which provide both acceptable values for the critical temperature and measurements of the surface tension at moderate temperatures. The complementary use of numerical methods permits us to offer a complete experience for the students with a simple laboratory experiment which we recommend for physics students in advanced university courses

  18. Surface tension effects on the behavior of a cavity growing, collapsing, and rebounding near a rigid wall.

    Science.gov (United States)

    Zhang, Zhen-yu; Zhang, Hui-sheng

    2004-11-01

    Surface tension effects on the behavior of a pure vapor cavity or a cavity containing some noncondensible contents, which is growing, collapsing, and rebounding axisymmetrically near a rigid wall, are investigated numerically by the boundary integral method for different values of dimensionless stand-off parameter gamma, buoyancy parameter delta, and surface tension parameter beta. It is found that at the late stage of the collapse, if the resultant action of the Bjerknes force and the buoyancy force is not small, surface tension will not have significant effects on bubble behavior except that the bubble collapse time is shortened and the liquid jet becomes wider. If the resultant action of the two force is small enough, surface tension will have significant and in some cases substantial effects on bubble behavior, such as changing the direction of the liquid jet, making a new liquid jet appear, in some cases preventing the bubble from rebound before jet impact, and in other cases causing the bubble to rebound or even recollapse before jet impact. The mechanism of surface tension effects on the collapsing behavior of a cavity has been analyzed. The mechanisms of some complicated phenomena induced by surface tension effects are illustrated by analysis of the computed velocity fields and pressure contours of the liquid flow outside the bubble at different stages of the bubble evolution.

  19. Investigations of surface-tension effects due to small-scale complex boundaries

    Science.gov (United States)

    Feng, Jiansheng

    In this Ph.D. dissertation, we have investigated some important surface-tension phenomena including capillarity, wetting, and wicking. We mainly focus on the geometric aspects of these problems, and to learn about how structures affect properties. . In the first project (Chapter 2), we used numerical simulations and experiments to study the meniscus of a fluid confined in capillaries with complicated cross-sectional geometries. In the simulations, we computed the three-dimensional shapes of the menisci formed in polygonal and star-shaped capillaries with sharp or rounded corners. Height variations across the menisci were used to quantify the effect of surface tension. Analytical solutions were derived for all the cases where the cross-sectional geometry was a regular polygon or a regular star-shape. Power indices that characterize the effects of corner rounding were extracted from simulation results. These findings can serve as guide for fabrications of unconventional three-dimensional structures in Capillary Force Lithography experiments. Experimental demonstrations of the working principle was also performed. Although quantitative matching between simulation and experimental results was not achieved due to the limitation of material properties, clear qualitative trends were observed and interesting three-dimensional nano-structures were produced. A second project (Chapter 3) focused on developing techniques to produce three-dimensional hierarchically structured superhydrophobic surfaces with high aspect ratios. We experimented with two different high-throughput electron-beam-lithography processes featuring single and dual electron-beam exposures. After a surface modification procedure with a hydrophobic silane, the structured surfaces exhibited two distinct superhydrophobic behaviors---high and low adhesion. While both types of superhydrophobic surfaces exhibited very high (approximately 160° water advancing contact angles, the water receding contact angles on

  20. Short-Time Structural Stability of Compressible Vortex Sheets with Surface Tension

    Science.gov (United States)

    Stevens, Ben

    2016-11-01

    Assume we start with an initial vortex-sheet configuration which consists of two inviscid fluids with density bounded below flowing smoothly past each other, where a strictly positive fixed coefficient of surface tension produces a surface tension force across the common interface, balanced by the pressure jump. We model the fluids by the compressible Euler equations in three space dimensions with a very general equation of state relating the pressure, entropy and density such that the sound speed is positive. We prove that, for a short time, there exists a unique solution of the equations with the same structure. The mathematical approach consists of introducing a carefully chosen artificial viscosity-type regularisation which allows one to linearise the system so as to obtain a collection of transport equations for the entropy, pressure and curl together with a parabolic-type equation for the velocity which becomes fairly standard after rotating the velocity according to the interface normal. We prove a high order energy estimate for the non-linear equations that is independent of the artificial viscosity parameter which allows us to send it to zero. This approach loosely follows that introduced by Shkoller et al. in the setting of a compressible liquid-vacuum interface. Although already considered by Coutand et al. [10] and Lindblad [17], we also make some brief comments on the case of a compressible liquid-vacuum interface, which is obtained from the vortex sheets problem by replacing one of the fluids by vacuum, where it is possible to obtain a structural stability result even without surface tension.

  1. Effect of increased surface tension and assisted ventilation on /sup 99m/Tc-DTPA clearance

    International Nuclear Information System (INIS)

    Jefferies, A.L.; Kawano, T.; Mori, S.; Burger, R.

    1988-01-01

    Experiments were performed to determine the effects of conventional mechanical ventilation (CMV) and high-frequency oscillation (HFO) on the clearance of technetium-99m-labeled diethylenetriamine pentaacetate (/sup 99m/Tc-DTPA) from lungs with altered surface tension properties. A submicronic aerosol of /sup 99m/Tc-DTPA was insufflated into the lungs of anesthetized, tracheotomized rabbits before and 1 h after the administration of the aerosolized detergent dioctyl sodium sulfosuccinate (OT). Rabbits were ventilated by one of four methods: 1) spontaneous breathing; 2) CMV at 12 cmH2O mean airway pressure (MAP); 3) HFO at 12 cmH2O MAP; 4) HFO at 16 cmH2O MAP. Administration of OT resulted in decreased arterial PO2 (PaO2), increased lung wet-to-dry weight ratios, and abnormal lung pressure-volume relationships, compatible with increased surface tension. /sup 99m/Tc-DTPA clearance was accelerated after OT in all groups. The post-OT rate of clearance (k) was significantly faster (P less than 0.05) in the CMV at 12 cmH2O MAP [k = 7.57 +/- 0.71%/min (SE)] and HFO at 16 cmH2O MAP (k = 6.92 +/- 0.61%/min) groups than in the spontaneously breathing (k = 4.32 +/- 0.55%/min) and HFO at 12 cmH2O MAP (4.68 +/- 0.63%/min) groups. The clearance curves were biexponential in the former two groups. We conclude that pulmonary clearance of /sup 99m/Tc-DTPA is accelerated in high surface tension pulmonary edema, and this effect is enhanced by both conventional ventilation and HFO at high mean airway pressure

  2. Adhesion of bubbles and drops to solid surfaces, and anisotropic surface tensions studied by capillary meniscus dynamometry.

    Science.gov (United States)

    Danov, Krassimir D; Stanimirova, Rumyana D; Kralchevsky, Peter A; Marinova, Krastanka G; Stoyanov, Simeon D; Blijdenstein, Theodorus B J; Cox, Andrew R; Pelan, Eddie G

    2016-07-01

    Here, we review the principle and applications of two recently developed methods: the capillary meniscus dynamometry (CMD) for measuring the surface tension of bubbles/drops, and the capillary bridge dynamometry (CBD) for quantifying the bubble/drop adhesion to solid surfaces. Both methods are based on a new data analysis protocol, which allows one to decouple the two components of non-isotropic surface tension. For an axisymmetric non-fluid interface (e.g. bubble or drop covered by a protein adsorption layer with shear elasticity), the CMD determines the two different components of the anisotropic surface tension, σs and σφ, which are acting along the "meridians" and "parallels", and vary throughout the interface. The method uses data for the instantaneous bubble (drop) profile and capillary pressure, but the procedure for data processing is essentially different from that of the conventional drop shape analysis (DSA) method. In the case of bubble or drop pressed against a substrate, which forms a capillary bridge, the CBD method allows one to determine also the capillary-bridge force for both isotropic (fluid) and anisotropic (solidified) adsorption layers. The experiments on bubble (drop) detachment from the substrate show the existence of a maximal pulling force, Fmax, that can be resisted by an adherent fluid particle. Fmax can be used to quantify the strength of adhesion of bubbles and drops to solid surfaces. Its value is determined by a competition of attractive transversal tension and repulsive disjoining pressure forces. The greatest Fmax values have been measured for bubbles adherent to glass substrates in pea-protein solutions. The bubble/wall adhesion is lower in solutions containing the protein HFBII hydrophobin, which could be explained with the effect of sandwiched protein aggregates. The applicability of the CBD method to emulsion systems is illustrated by experiments with soybean-oil drops adherent to hydrophilic and hydrophobic substrates in

  3. Viscosity and surface tension of binary systems of N,N-dimethylformamide with alkan-1-ols at different temperatures

    International Nuclear Information System (INIS)

    Mohammad, Abubaker A.; Alkhaldi, Khaled H.A.E.; AlTuwaim, Mohammad S.; Al-Jimaz, Adel S.

    2013-01-01

    Highlights: ► Physical properties of binary mixtures of DMF+1-pentanol, 1-hexanol, or 1-heptanol. ► Viscosity and surface tension were measured. ►Δη, Δσ σ and G ∗E were calculated using the experimental data. ► H σ and S σ were determined using the surface tension data. ► Semi-empirical relations were used to estimate the viscosity of liquid mixtures. - Abstract: Viscosity η and surface tension σ were measured for binary mixtures of N,N-dimethylformamide DMF with pentan-1-ol, hexan-1-ol, and heptan-1-ol at T = (298.15, 303.15, 308.15, and 313.15) K and atmospheric pressure over the entire mole fraction range. Deviations in viscosity Δη and surface tension Δσ were calculated using experimental results. Moreover, the values of the excess Gibbs free energy of activation G ∗E , surface enthalpy H σ and surface entropy S σ of these mixtures were determined. Viscosity measurements of the binary systems were correlated with Grunberg and Nissan, the three-body and four-body McAllister expressions. Viscosity deviation, surface tension deviation and excess Gibbs energy of activation functions were fitted to the method of Redlich–Kister (R–K) polynomial to estimate the coefficients and standard deviations. The effects of chain length of alkan-1-ols and temperature on the thermodynamic properties of binary systems were studied.

  4. A sharp interface method for compressible liquid–vapor flow with phase transition and surface tension

    Energy Technology Data Exchange (ETDEWEB)

    Fechter, Stefan, E-mail: stefan.fechter@iag.uni-stuttgart.de [Institut für Aerodynamik und Gasdynamik, Universität Stuttgart, Pfaffenwaldring 21, 70569 Stuttgart (Germany); Munz, Claus-Dieter, E-mail: munz@iag.uni-stuttgart.de [Institut für Aerodynamik und Gasdynamik, Universität Stuttgart, Pfaffenwaldring 21, 70569 Stuttgart (Germany); Rohde, Christian, E-mail: Christian.Rohde@mathematik.uni-stuttgart.de [Institut für Angewandte Analysis und Numerische Simulation, Universität Stuttgart, Pfaffenwaldring 57, 70569 Stuttgart (Germany); Zeiler, Christoph, E-mail: Christoph.Zeiler@mathematik.uni-stuttgart.de [Institut für Angewandte Analysis und Numerische Simulation, Universität Stuttgart, Pfaffenwaldring 57, 70569 Stuttgart (Germany)

    2017-05-01

    The numerical approximation of non-isothermal liquid–vapor flow within the compressible regime is a difficult task because complex physical effects at the phase interfaces can govern the global flow behavior. We present a sharp interface approach which treats the interface as a shock-wave like discontinuity. Any mixing of fluid phases is avoided by using the flow solver in the bulk regions only, and a ghost-fluid approach close to the interface. The coupling states for the numerical solution in the bulk regions are determined by the solution of local two-phase Riemann problems across the interface. The Riemann solution accounts for the relevant physics by enforcing appropriate jump conditions at the phase boundary. A wide variety of interface effects can be handled in a thermodynamically consistent way. This includes surface tension or mass/energy transfer by phase transition. Moreover, the local normal speed of the interface, which is needed to calculate the time evolution of the interface, is given by the Riemann solution. The interface tracking itself is based on a level-set method. The focus in this paper is the description of the two-phase Riemann solver and its usage within the sharp interface approach. One-dimensional problems are selected to validate the approach. Finally, the three-dimensional simulation of a wobbling droplet and a shock droplet interaction in two dimensions are shown. In both problems phase transition and surface tension determine the global bulk behavior.

  5. Standard practice for fracture testing with surface-crack tension specimens

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2003-01-01

    1.1 This practice covers the design, preparation, and testing of surface-crack tension (SCT) specimens. It relates specifically to testing under continuously increasing force and excludes cyclic and sustained loadings. The quantity determined is the residual strength of a specimen having a semielliptical or circular-segment fatigue crack in one surface. This value depends on the crack dimensions and the specimen thickness as well as the characteristics of the material. 1.2 Metallic materials that can be tested are not limited by strength, thickness, or toughness. However, tests of thick specimens of tough materials may require a tension test machine of extremely high capacity. The applicability of this practice to nonmetallic materials has not been determined. 1.3 This practice is limited to specimens having a uniform rectangular cross section in the test section. The test section width and length must be large with respect to the crack length. Crack depth and length should be chosen to suit the ultimate pu...

  6. Effects of surface tension and viscosity on the forming and transferring process of microscale droplets

    Science.gov (United States)

    Chen, Shulei; Liu, Kun; Liu, Cunbin; Wang, Dongyang; Ba, Dechun; Xie, Yuanhua; Du, Guangyu; Ba, Yaoshuai; Lin, Qiao

    2016-12-01

    Surface tension and viscosity act as important roles on the fluid flow in microchannel channels. In order to understand the influencing mechanism, three dimensional numerical simulations as well as experimental investigations were carried out on the slug formation and transfer in a rectangle T-junction microchannel. The simulation showed that the increasing Capillary number (Ca) resulted in the decreasing slug volume. Due to the existence of film thickness and corner flow, the characteristic length of slug was not the same trend completely. The results also showed that the pressure of junction point fluctuated periodically in the process of slug formation, which can reflect the slug formation period and the effect of the various conditions on pressure change. Two other pressure monitoring points were located in vertical channel and main channel and they monitored the pressure of two phase flow respectively. The increasing surface tension resulted in an increasing of total pressure, the interface pressure drop of two phases and the period of slug formation. The frequency of slug formation and two phases total pressure increased with the viscosity of continuous phase.

  7. An accessible micro-capillary electrophoresis device using surface-tension-driven flow

    Science.gov (United States)

    Mohanty, Swomitra K.; Warrick, Jay; Gorski, Jack; Beebe, David J.

    2010-01-01

    We present a rapidly fabricated micro-capillary electrophoresis chip that utilizes surface-tension-driven flow for sample injection and extraction of DNA. Surface-tension-driven flow (i.e. passive pumping) injects a fixed volume of sample that can be predicted mathematically. Passive pumping eliminates the need for tubing, valves, syringe pumps, and other equipment typically needed for interfacing with microelectrophoresis chips. This method requires a standard micropipette to load samples before separation, and remove the resulting bands after analysis. The device was made using liquid phase photopolymerization to rapidly fabricate the chip without the need of special equipment typically associated with the construction of microelectrophoresis chips (e.g. cleanroom). Batch fabrication time for the device presented here was 1.5 h including channel coating time to suppress electroosmotic flow. Devices were constructed out of poly-isobornyl acrylate and glass. A standard microscope with a UV source was used for sample detection. Separations were demonstrated using Promega BenchTop 100 bp ladder in hydroxyl ethyl cellulose (HEC) and oligonucleotides of 91 and 118 bp were used to characterize sample injection and extraction of DNA bands. The end result was an inexpensive micro-capillary electrophoresis device that uses tools (e.g. micropipette, electrophoretic power supplies, and microscopes) already present in most labs for sample manipulation and detection, making it more accessible for potential end users. PMID:19425002

  8. Surface tension driven aggregation of organic nanowires via lab in a droplet.

    Science.gov (United States)

    Gu, Jianmin; Yin, Baipeng; Fu, Shaoyan; Feng, Man; Zhang, Ziming; Dong, Haiyun; Gao, Faming; Zhao, Yong Sheng

    2018-06-05

    Directing the architecture of complex organic nanostructures is desirable and still remains a challenge in areas of materials science due to their structure-dependent collective optoelectronic properties. Herein, we demonstrate a simple and versatile solution strategy that allows surface tension to drive low-dimensional nanostructures to aggregate into complex structures via a lab in a droplet technique. By selecting a suitable combination of a solvent and an anti-solvent with controllable surface tension difference, the droplets can be automatically cracked into micro-droplets, which provides an aggregation force directed toward the centre of the droplet to drive the low-dimensional building blocks to form the special aggregations during the self-assembly process. This synthetic strategy has been shown to be universal for organic materials, which is beneficial for further optimizing the optoelectronic properties. These results contribute to gaining an insightful understanding on the detailed growth mechanism of complex organic nanostructures and greatly promoting the development of organic nanophotonics.

  9. d-α-tocopherol nanoemulsions: Size properties, rheological behavior, surface tension, osmolarity and cytotoxicity

    Directory of Open Access Journals (Sweden)

    M.C. Teixeira

    2017-02-01

    Full Text Available The aim of this study was the assessment of the physicochemical stability of d-α-tocopherol formulated in medium chain triglyceride nanoemulsions, stabilized with Tween®80 and Lipoid®S75 as surfactant and co-surfactant, respectively. d-α-tocopherol was selected as active ingredient because of its well-recognized interesting anti-oxidant properties (such as radical scavenger for food and pharmaceutical industries. A series of nanoemulsions of mean droplet size below 90 nm (polydispersity index < 0.15 have been produced by high-pressure homogenization, and their surface electrical charge (zeta potential, pH, surface tension, osmolarity, and rheological behavior, were characterized as a function of the d-α-tocopherol loading. In vitro studies in Caco-2 cell lines confirmed the safety profile of the developed nanoemulsions with percentage of cell viability above 90% for all formulations.

  10. Surface tension-induced high aspect-ratio PDMS micropillars with concave and convex lens tips

    KAUST Repository

    Li, Huawei

    2013-04-01

    This paper reports a novel method for the fabrication of 3-dimensional (3D) Polydimethylsiloxane (PDMS) micropillars with concave and convex lens tips in a one-step molding process, using a CO2 laser-machined Poly(methyl methacrylate) (PMMA) mold with through holes. The PDMS micropillars are 4 mm high and have an aspect ratio of 251. The micropillars are formed by capillary force drawing up PDMS into the through hole mold. The concave and convex lens tips of the PDMS cylindrical micropillars are induced by surface tension and are controllable by changing the surface wetting properties of the through holes in the PMMA mold. This technique eliminates the requirements of expensive and complicated facilities to prepare a 3D mold, and it provides a simple and rapid method to fabricate 3D PDMS micropillars with controllable dimensions and tip shapes. © 2013 IEEE.

  11. Surface tension-induced high aspect-ratio PDMS micropillars with concave and convex lens tips

    KAUST Repository

    Li, Huawei; Fan, Yiqiang; Yi, Ying; Foulds, Ian G.

    2013-01-01

    This paper reports a novel method for the fabrication of 3-dimensional (3D) Polydimethylsiloxane (PDMS) micropillars with concave and convex lens tips in a one-step molding process, using a CO2 laser-machined Poly(methyl methacrylate) (PMMA) mold with through holes. The PDMS micropillars are 4 mm high and have an aspect ratio of 251. The micropillars are formed by capillary force drawing up PDMS into the through hole mold. The concave and convex lens tips of the PDMS cylindrical micropillars are induced by surface tension and are controllable by changing the surface wetting properties of the through holes in the PMMA mold. This technique eliminates the requirements of expensive and complicated facilities to prepare a 3D mold, and it provides a simple and rapid method to fabricate 3D PDMS micropillars with controllable dimensions and tip shapes. © 2013 IEEE.

  12. New sensitive micro-measurements of dynamic surface tension and diffusion coefficients

    DEFF Research Database (Denmark)

    Kinoshita, Koji; Ortiz, Elisa Parra; Needham, David

    2017-01-01

    Currently available dynamic surface tension (DST) measurement methods, such as Wilhelmy plate, droplet- or bubble-based methods, still have various experimental limitations such as the large size of the interface, convection in the solution, or a certain “dead time” at initial measurement....... These limitations create inconsistencies for the kinetic analysis of surfactant adsorption/desorption, especially significant for ionic surfactants. Here, the “micropipette interfacial area-expansion method” was introduced and validated as a new DST measurement having a high enough sensitivity to detect diffusion...... for surface excess concentration. We found that the measured diffusion coefficient of 1-Octanol, 7.2 ± 0.8 × 10−6 cm2/s, showed excellent agreement with the result from an alternative method, “single microdroplet catching method”, to measure the diffusion coefficient from diffusion-controlled microdroplet...

  13. Surface tension and wetting behaviour of Bi-In-Sn alloys

    International Nuclear Information System (INIS)

    Ervina Efzan Mohd Noor; Ahmad Badri Ismail; Soong, T.K.; Chin, Y.T.; Luay Bakir Hussain

    2007-01-01

    Concerns about possible landfill contamination, influent discharge from production process are one of the reasons convert from lead-containing electronics to lead-free containing. The surface and interfacial properties of Bi-In-Sn lead-free solder system as a basic system of multicomponent alloys proposed as lead-free solder materials have been studied. The surface tension of Bi-In-Sn lead-free solder system of melting temperature 60 degree Celsius has been measured the temperature range 80 degree Celsius and 140 degree Celsius. The study of the wetting behaviour of Bi-In-Sn lead-free solder system on a Cu substrate has been performed by measuring contact angle on various metal substrates by Optical Microscopy with software. (author)

  14. Asymptotic stability of shear-flow solutions to incompressible viscous free boundary problems with and without surface tension

    Science.gov (United States)

    Tice, Ian

    2018-04-01

    This paper concerns the dynamics of a layer of incompressible viscous fluid lying above a rigid plane and with an upper boundary given by a free surface. The fluid is subject to a constant external force with a horizontal component, which arises in modeling the motion of such a fluid down an inclined plane, after a coordinate change. We consider the problem both with and without surface tension for horizontally periodic flows. This problem gives rise to shear-flow equilibrium solutions, and the main thrust of this paper is to study the asymptotic stability of the equilibria in certain parameter regimes. We prove that there exists a parameter regime in which sufficiently small perturbations of the equilibrium at time t=0 give rise to global-in-time solutions that return to equilibrium exponentially in the case with surface tension and almost exponentially in the case without surface tension. We also establish a vanishing surface tension limit, which connects the solutions with and without surface tension.

  15. Surface Tension Directed Fluidic Self-Assembly of Semiconductor Chips across Length Scales and Material Boundaries

    Directory of Open Access Journals (Sweden)

    Shantonu Biswas

    2016-03-01

    Full Text Available This publication provides an overview and discusses some challenges of surface tension directed fluidic self-assembly of semiconductor chips which are transported in a liquid medium. The discussion is limited to surface tension directed self-assembly where the capture, alignment, and electrical connection process is driven by the surface free energy of molten solder bumps where the authors have made a contribution. The general context is to develop a massively parallel and scalable assembly process to overcome some of the limitations of current robotic pick and place and serial wire bonding concepts. The following parts will be discussed: (2 Single-step assembly of LED arrays containing a repetition of a single component type; (3 Multi-step assembly of more than one component type adding a sequence and geometrical shape confinement to the basic concept to build more complex structures; demonstrators contain (3.1 self-packaging surface mount devices, and (3.2 multi-chip assemblies with unique angular orientation. Subsequently, measures are discussed (4 to enable the assembly of microscopic chips (10 μm–1 mm; a different transport method is introduced; demonstrators include the assembly of photovoltaic modules containing microscopic silicon tiles. Finally, (5 the extension to enable large area assembly is presented; a first reel-to-reel assembly machine is realized; the machine is applied to the field of solid state lighting and the emerging field of stretchable electronics which requires the assembly and electrical connection of semiconductor devices over exceedingly large area substrates.

  16. Studies on surface tension effect for free surface flow around floating models; Futai mokei mawari no jiyu hyomenryu ni oyobosu hyomen choryoku no eikyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, K [Yokohama National Univ., Yokohama (Japan). Faculty of Engineering; Akiba, H [Toyo Construction Co. Ltd., Tokyo (Japan)

    1997-12-31

    The effect of surface tension on free surface flow around floating models is discussed experimentally and numerically. Three-dimensional free surface flow around vertical circular cylinders floating in a circulating water channel was visually observed, where a surface-active agent was added to water. The results are analyzed using Weber number. The numerical analysis was done for vertical cylinder and CY100 models using the Rankine source method. Weber number of at least around 120 is necessary to eliminate the effect of surface tension from free surface flow around the CY100 model. The numerical analysis for the cylinder model needs simulation with wavelength shorter than that of free surface wave used by the Rankine source method. The model for the resistance test should be at least around 7m long to eliminate the effect of surface tension at Froude number of 0.1 or higher. 15 refs., 12 figs., 2 tabs.

  17. Studies on surface tension effect for free surface flow around floating models; Futai mokei mawari no jiyu hyomenryu ni oyobosu hyomen choryoku no eikyo ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    Suzuki, K. [Yokohama National Univ., Yokohama (Japan). Faculty of Engineering; Akiba, H. [Toyo Construction Co. Ltd., Tokyo (Japan)

    1996-12-31

    The effect of surface tension on free surface flow around floating models is discussed experimentally and numerically. Three-dimensional free surface flow around vertical circular cylinders floating in a circulating water channel was visually observed, where a surface-active agent was added to water. The results are analyzed using Weber number. The numerical analysis was done for vertical cylinder and CY100 models using the Rankine source method. Weber number of at least around 120 is necessary to eliminate the effect of surface tension from free surface flow around the CY100 model. The numerical analysis for the cylinder model needs simulation with wavelength shorter than that of free surface wave used by the Rankine source method. The model for the resistance test should be at least around 7m long to eliminate the effect of surface tension at Froude number of 0.1 or higher. 15 refs., 12 figs., 2 tabs.

  18. Drought limitations to leaf-level gas exchange: results from a model linking stomatal optimization and cohesion-tension theory

    Science.gov (United States)

    Kimberly A. Novick; Chelcy F. Miniat; James M. Vose

    2016-01-01

    We merge concepts from stomatal optimization theory and cohesion–tension theory to examine the dynamics of three mechanisms that are potentially limiting to leaf-level gas exchange in trees during drought: (1) a ‘demand limitation’ driven by an assumption of optimal stomatal functioning; (2) ‘hydraulic limitation’ of water movement from the roots to the leaves...

  19. Surface chemistry theory and applications

    CERN Document Server

    Bikerman, J J

    2013-01-01

    Surface Chemistry Theory and Applications focuses on liquid-gas, liquid-liquid, solid-gas, solid-liquid, and solid-solid surfaces. The book first offers information on liquid-gas surfaces, including surface tension, measurement of surface tension, rate of capillarity rise, capillary attraction, bubble pressure and pore size, and surface tension and temperature. The text then ponders on liquid-liquid and solid-gas surfaces. Discussions focus on surface energy of solids, surface roughness and cleanness, adsorption of gases and vapors, adsorption hysteresis, interfacial tension, and interfacial t

  20. Pendent_Drop: An ImageJ Plugin to Measure the Surface Tension from an Image of a Pendent Drop

    Directory of Open Access Journals (Sweden)

    Adrian Daerr

    2016-01-01

    Full Text Available The pendent drop method for surface tension measurement consists in analysing the shape of an axisymmetric drop hanging from a capillary tube. This software is an add-on for the public domain image processing software ImageJ which matches a theoretical profile to the contour of a pendent drop, either interactively or by automatically minimising the mismatch. It provides an estimate of the surface tension, drop volume and surface area from the best matching parameters. It can be used in a headless setup. It is hosted on http://fiji.sc/List_of_update_sites with the source code on https://github.com/adaerr/pendent-drop

  1. Effect of temperature and composition on the surface tension and surface properties of binary mixtures containing DMSO and short chain alcohols

    International Nuclear Information System (INIS)

    Bagheri, Ahmad; Fazli, Mostafa; Bakhshaei, Malihe

    2016-01-01

    Highlights: • Surface tension of DMSO + alcohol (methanol, ethanol and isopropanol) at various temperatures was measured. • The surface tension data of binary mixtures were correlated with four equations. • Intermolecular interaction of DMSO with alcohol was discussed. • The surface mole fraction of alcohol increase with increasing the length of alcohol chain. - Abstract: Surface tension of binary mixtures of methanol, ethanol and isopropanol with DMSO (dimethyl sulfoxide) was measured over the whole range of composition at atmospheric pressure of 82.5 kPa within the temperatures between (298.15 and 328.15) K. The experimental measurements were used to calculate in surface tension deviations (Δσ). The sign of Δσ for all temperatures is negative (except of methanol/DMSO system) because of the factors of hydrogen bonding and dipole–dipole interactions in the DMSO-alcohol systems. Surface tension values of the binary systems were correlated with FLW, MS, RK and LWW models. The mean standard deviation obtained from the comparison of experimental and calculated surface tension values for binary systems with three models (FLW, MS and RK) at various temperatures is less than 0.83. Also, the results of the LWW model were used to account for the interaction energy between alcohols and DMSO in binary mixtures. The temperature dependence of σ (surface tension) at fixed composition of solutions was used to estimate surface enthalpy, H s , and surface entropy, S s . The results obtained show that the values of the thermodynamic parameters for alcohol/DMSO mixtures decrease with increasing alkyl chain length of alcohol. Finally, the results are discussed in terms of surface mole fraction and lyophobicity using the extended Langmuir (EL) isotherm.

  2. The dynamics of nucleation and growth of a particle in the ternary alloy melt with anisotropic surface tension.

    Science.gov (United States)

    Chen, Ming-Wen; Li, Lin-Yan; Guo, Hui-Min

    2017-08-28

    The dynamics of nucleation and growth of a particle affected by anisotropic surface tension in the ternary alloy melt is studied. The uniformly valid asymptotic solution for temperature field, concentration field, and interface evolution of nucleation and particle growth is obtained by means of the multiple variable expansion method. The asymptotic solution reveals the critical radius of nucleation in the ternary alloy melt and an inward melting mechanism of the particle induced by the anisotropic effect of surface tension. The critical radius of nucleation is dependent on isotropic surface tension, temperature undercooling, and constitutional undercooling in the ternary alloy melt, and the solute diffusion melt decreases the critical radius of nucleation. Immediately after a nucleus forms in the initial stage of solidification, the anisotropic effect of surface tension makes some parts of its interface grow inward while some parts grow outward. Until the inward melting attains a certain distance (which is defined as "the melting depth"), these parts of interface start to grow outward with other parts. The interface of the particle evolves into an ear-like deformation, whose inner diameter may be less than two times the critical radius of nucleation within a short time in the initial stage of solidification. The solute diffusion in the ternary alloy melt decreases the effect of anisotropic surface tension on the interface deformation.

  3. The Effect of Surface Tension on the Gravity-driven Thin Film Flow of Newtonian and Power-law Fluids

    Science.gov (United States)

    Hu, Bin; Kieweg, Sarah L.

    2012-01-01

    Gravity-driven thin film flow is of importance in many fields, as well as for the design of polymeric drug delivery vehicles, such as anti-HIV topical microbicides. There have been many prior works on gravity-driven thin films. However, the incorporation of surface tension effect has not been well studied for non-Newtonian fluids. After surface tension effect was incorporated into our 2D (i.e. 1D spreading) power-law model, we found that surface tension effect not only impacted the spreading speed of the microbicide gel, but also had an influence on the shape of the 2D spreading profile. We observed a capillary ridge at the front of the fluid bolus. Previous literature shows that the emergence of a capillary ridge is strongly related to the contact line fingering instability. Fingering instabilities during epithelial coating may change the microbicide gel distribution and therefore impact how well it can protect the epithelium. In this study, we focused on the capillary ridge in 2D flow and performed a series of simulations and showed how the capillary ridge height varies with other parameters, such as surface tension coefficient, inclination angle, initial thickness, and power-law parameters. As shown in our results, we found that capillary ridge height increased with higher surface tension, steeper inclination angle, bigger initial thickness, and more Newtonian fluids. This study provides the initial insights of how to optimize the flow and prevent the appearance of a capillary ridge and fingering instability. PMID:23687391

  4. Dynamic surface tension measurement for the screening of biosurfactants produced by Lactobacillus plantarum subsp. plantarum PTCC 1896.

    Science.gov (United States)

    Bakhshi, Nafiseh; Soleimanian-Zad, Sabihe; Sheikh-Zeinoddin, Mahmoud

    2017-06-01

    Currently, screening of microbial biosurfactants (BSs) is based on their equilibrium surface tension values obtained using static surface tension measurement. However, a good surfactant should not only have a low equilibrium surface tension, but its dynamic surface tension (DST) should also decrease rapidly with time. In this study, screening of BSs produced by Lactobacillus plantarum subsp. plantarum PTCC 1896 (probiotic) was performed based on their DST values measured by Wilhelmy plate tensiometry. The relationship between DST and structural and functional properties (anti-adhesive activity) of the BSs was investigated. The results showed that the changes in the yield, productivity and structure of the BSs were growth medium and incubation time dependent (p<0.05). Structurally different BSs produced exhibited identical equilibrium surface tension values. However, differences among the structure/yield of the BSs were observed through the measurement of their DST. The considerable dependence of DST on the concentration and composition of the BS proteins was observed (p<0.05). Moreover, the anti-adhesive activity of the BS was found to be positively correlated with its DST. The results suggest that the DST measurement could serve as an efficient method for the clever screening of BSs producer/production condition, and consequently, for the investigation of probiotic features of bacteria, since the anti-adhesive activity is an important criterion of probiotics. Copyright © 2017 Elsevier Inc. All rights reserved.

  5. Marangoni instability in a thin film heated from below: Effect of nonmonotonic dependence of surface tension on temperature

    Science.gov (United States)

    Sarma, Rajkumar; Mondal, Pranab Kumar

    2018-04-01

    We investigate Marangoni instability in a thin liquid film resting on a substrate of low thermal conductivity and separated from the surrounding gas phase by a deformable free surface. Considering a nonmonotonic variation of surface tension with temperature, here we analytically derive the neutral stability curve for the monotonic and oscillatory modes of instability (for both the long-wave and short-wave perturbations) under the framework of linear stability analysis. For the long-wave instability, we derive a set of amplitude equations using the scaling k ˜(Bi) 1 /2 , where k is the wave number and Bi is the Biot number. Through this investigation, we demonstrate that for such a fluid layer upon heating from below, both monotonic and oscillatory instability can appear for a certain range of the dimensionless parameters, viz., Biot number (Bi ) , Galileo number (Ga ) , and inverse capillary number (Σ ) . Moreover, we unveil, through this study, the influential role of the above-mentioned parameters on the stability of the system and identify the critical values of these parameters above which instability initiates in the liquid layer.

  6. Modeling of a Curvilinear Planar Crack with a Curvature-Dependent Surface Tension

    KAUST Repository

    Zemlyanova, A. Y.; Walton, J. R.

    2012-01-01

    An approach to modeling fracture incorporating interfacial mechanics is applied to the example of a curvilinear plane strain crack. The classical Neumann boundary condition is augmented with curvature-dependent surface tension. It is shown that the considered model eliminates the integrable crack-tip stress and strain singularities of order 1/2 present in the classical linear fracture mechanics solutions, and also leads to the sharp crack opening that is consistent with empirical observations. Unlike for the case of a straight crack, for a general curvilinear crack some components of the stresses and the derivatives of the displacements may still possess weaker singularities of a logarithmic type. Generalizations of the present study that lead to complete removal of all crack-tip singularities, including logarithmic, are the subject of a future paper. © 2012 Society for Industrial and Applied Mathematics.

  7. A multiscale method for compressible liquid-vapor flow with surface tension*

    Directory of Open Access Journals (Sweden)

    Jaegle Felix

    2013-01-01

    Full Text Available Discontinuous Galerkin methods have become a powerful tool for approximating the solution of compressible flow problems. Their direct use for two-phase flow problems with phase transformation is not straightforward because this type of flows requires a detailed tracking of the phase front. We consider the fronts in this contribution as sharp interfaces and propose a novel multiscale approach. It combines an efficient high-order Discontinuous Galerkin solver for the computation in the bulk phases on the macro-scale with the use of a generalized Riemann solver on the micro-scale. The Riemann solver takes into account the effects of moderate surface tension via the curvature of the sharp interface as well as phase transformation. First numerical experiments in three space dimensions underline the overall performance of the method.

  8. Measurement uncertainty evaluation of cellular spheroids surface tension in compressing tests using Young-Laplace equation

    Science.gov (United States)

    Beatrici, Anderson; Santos Baptista, Leandra; Mauro Granjeiro, José

    2018-03-01

    Regenerative Medicine comprises the Biotechnology, Tissue Engineering and Biometrology for stem cell therapy. Starting from stem cells extracted from the patient, autologous implant, these cells are cultured and differentiated into other tissues, for example, articular cartilage. These cells are reorganized into microspheres (cell spheroids). Such tissue units are recombined into functional tissues constructs that can be implanted in the injured region for regeneration. It is necessary the biomechanical characterization of these constructed to determine if their properties are similar to native tissue. In this study was carried out the modeling of the calculation of uncertainty of the surface tension of cellular spheroids with the use of the Young-Laplace equation. We obtained relative uncertainties about 10%.

  9. Effect of surface tension on the behavior of adhesive contact based on Lennard-Jones potential law

    Science.gov (United States)

    Zhu, Xinyao; Xu, Wei

    2018-02-01

    The present study explores the effect of surface tension on adhesive contact behavior where the adhesion is interpreted by long-range intermolecular forces. The adhesive contact is analyzed using the equivalent system of a rigid sphere and an elastic half space covered by a membrane with surface tension. The long-range intermolecular forces are modeled with the Lennard‒Jones (L‒J) potential law. The current adhesive contact issue can be represented by a nonlinear integral equation, which can be solved by Newton‒Raphson method. In contrast to previous studies which consider intermolecular forces as short-range, the present study reveals more details of the features of adhesive contact with surface tension, in terms of jump instabilities, pull-off forces, pressure distribution within the contact area, etc. The transition of the pull-off force is not only consistent with previous studies, but also presents some new interesting characteristics in the current situation.

  10. Elastic-Plastic J-Integral Solutions or Surface Cracks in Tension Using an Interpolation Methodology

    Science.gov (United States)

    Allen, P. A.; Wells, D. N.

    2013-01-01

    No closed form solutions exist for the elastic-plastic J-integral for surface cracks due to the nonlinear, three-dimensional nature of the problem. Traditionally, each surface crack must be analyzed with a unique and time-consuming nonlinear finite element analysis. To overcome this shortcoming, the authors have developed and analyzed an array of 600 3D nonlinear finite element models for surface cracks in flat plates under tension loading. The solution space covers a wide range of crack shapes and depths (shape: 0.2 less than or equal to a/c less than or equal to 1, depth: 0.2 less than or equal to a/B less than or equal to 0.8) and material flow properties (elastic modulus-to-yield ratio: 100 less than or equal to E/ys less than or equal to 1,000, and hardening: 3 less than or equal to n less than or equal to 20). The authors have developed a methodology for interpolating between the goemetric and material property variables that allows the user to reliably evaluate the full elastic-plastic J-integral and force versus crack mouth opening displacement solution; thus, a solution can be obtained very rapidly by users without elastic-plastic fracture mechanics modeling experience. Complete solutions for the 600 models and 25 additional benchmark models are provided in tabular format.

  11. Influence of additives on melt viscosity, surface tension, and film formation of dry powder coatings.

    Science.gov (United States)

    Sauer, Dorothea; McGinity, James W

    2009-06-01

    Limited information on thermally cured dry-powder coatings used for solid dosage forms has been available in the literature. The aim of this study was to characterize the film formation process of Eudragit L 100-55 dry-powder coatings and to investigate the influence of film additives on melt viscosity and surface tension. The coating process employed no liquids and the plasticizer was combined with the polymer using hot melt extrusion. Thermoanalytical methods including differential scanning calorimetry and thermogravimetric analysis (TGA) were used to investigate the thermal properties of the dry-coating formulations. The rheological behavior of the coating formulations were characterized with the extrusion torque, and the surface energy parameters were determined from contact angle measurements. The influence of the level of triethyl citrate (TEC) as plasticizer and polyethylene glycol (PEG) 3350 in the polymer film on film formation was investigated using a digital force tester. TGA confirmed thermal stability of all coating excipients at the investigated curing conditions. Increasing TEC levels and the addition of PEG 3350 as a low melting excipient in the coating reduced the viscosity of the polymer. Plasticization of the polymer with TEC increased the surface free energy, whereas the admixture of 10% PEG 3350 did not affect the surface free energy of Eudragit L 100-55. The spreading coefficient of the polymers over two sample tablet formulations was reduced with increasing surface free energy. During the curing process, puncture strength, and elongation of powder-cast films increased. The effect of curing time on the mechanical properties was dependent on the plasticizer content. The incorporation of TEC and PEG 3350 into the Eudragit L 100-55 powder coating formulation improved film formation. Mechanical testing of powder-cast films showed an increase of both elongation and puncture strength over the curing process as criterion for polymer particle fusion

  12. Alkyl chain interaction at the surface of room temperature ionic liquids: systematic variation of alkyl chain length (R = C(1)-C(4), C(8)) in both cation and anion of [RMIM][R-OSO(3)] by sum frequency generation and surface tension.

    Science.gov (United States)

    Santos, Cherry S; Baldelli, Steven

    2009-01-29

    The gas-liquid interface of halide-free 1,3-dialkylimidazolium alkyl sulfates [RMIM][R-OSO(3)] with R chain length from C(1)-C(4) and C(8) has been studied systematically using the surface-specific sum frequency generation (SFG) vibrational spectroscopy and surface tension measurements. From the SFG spectra, vibrational modes from the methyl group of both cation and anion are observed for all ionic liquid samples considered in the present study. These results suggest the presence of both ions at the gas-liquid interface, which is further supported by surface tension measurements. Surface tension data show a decreasing trend as the alkyl chain in the imidazolium cation is varied from methyl to butyl chain, with a specific anion. A similar trend is observed when the alkyl chain of the anion is modified and the cation is fixed.

  13. Ground-based PIV and numerical flow visualization results from the Surface Tension Driven Convection Experiment

    Science.gov (United States)

    Pline, Alexander D.; Werner, Mark P.; Hsieh, Kwang-Chung

    1991-01-01

    The Surface Tension Driven Convection Experiment (STDCE) is a Space Transportation System flight experiment to study both transient and steady thermocapillary fluid flows aboard the United States Microgravity Laboratory-1 (USML-1) Spacelab mission planned for June, 1992. One of the components of data collected during the experiment is a video record of the flow field. This qualitative data is then quantified using an all electric, two dimensional Particle Image Velocimetry (PIV) technique called Particle Displacement Tracking (PDT), which uses a simple space domain particle tracking algorithm. Results using the ground based STDCE hardware, with a radiant flux heating mode, and the PDT system are compared to numerical solutions obtained by solving the axisymmetric Navier Stokes equations with a deformable free surface. The PDT technique is successful in producing a velocity vector field and corresponding stream function from the raw video data which satisfactorily represents the physical flow. A numerical program is used to compute the velocity field and corresponding stream function under identical conditions. Both the PDT system and numerical results were compared to a streak photograph, used as a benchmark, with good correlation.

  14. Surface tensions of binary mixtures of ionic liquids with bis(trifluoromethylsulfonyl)imide as the common anion

    International Nuclear Information System (INIS)

    Oliveira, M.B.; Domínguez-Pérez, M.; Cabeza, O.; Lopes-da-Silva, J.A.; Freire, M.G.; Coutinho, J.A.P.

    2013-01-01

    Highlights: • Novel data for the surface tensions of mixtures [C 4 mim][NTf 2 ] + [C 4 C 1 mim]/[C 3 mpy]/[C 3 mpyr]/[C 3 mpip][NTf 2 ] are presented. • γ were determined at a fixed temperature, 298.2 K, and at atmospheric pressure, for the whole composition range. • Surface tension deviations showed the near ideal behavior of the selected mixtures. • Gibbs adsorption isotherms showed the surface preferential adsorption of one ionic liquid over the other. -- Abstract: While values for thermophysical properties of ionic liquids are becoming widely available, data for ionic liquid mixtures are still scarce. In an effort to overcome this limitation and understand the behavior of ionic liquid mixtures, novel data for the surface tension of mixtures composed of 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, [C 4 mim][NTf 2 ], with other ionic liquids with a common anion, namely 1-butyl-2,3-dimethylimidazolium, [C 4 C 1 mim] + , 3-methyl-1-propylpyridinium, [C 3 mpy] + , 1-methyl-1-propylpyrrolidinium, [C 3 mpyr] + , and 1-methyl-1-propylpiperidinium, [C 3 mpip] + , were measured at T = 298.2 K and atmospheric pressure over the entire composition range. From the surface tension deviations derived from the experimental results, it was possible to infer that the cation alkyl chain length of the second ionic liquid constituting the mixture has a stronger influence in the ideal mixture behavior than the type of family the ionic liquid cation belongs to. The Gibbs adsorption isotherms, estimated from the experimental values, show that the composition of the vapor–liquid interface is not the same as that of the bulk and that the interface is richer in the ionic liquid with the lowest surface tension, [C 4 mim][NTf 2

  15. Reducing surface tension in endodontic chelator solutions has no effect on their ability to remove calcium from instrumented root canals.

    Science.gov (United States)

    Zehnder, Matthias; Schicht, Olivier; Sener, Beatrice; Schmidlin, Patrick

    2005-08-01

    The aim of this study was to evaluate the effect of reducing surface tension in endodontic chelator solutions on their ability to remove calcium from instrumented root canals. Aqueous solutions containing 15.5% EDTA, 10% citric acid, or 18% 1- hydroxyethylidene-1, 1-bisphosphonate (HEBP) were prepared with and without 1% (wt/wt) polysorbate (Tween) 80 and 9% propylene glycol. Surface tension in these solutions was measured using the Wilhelmy method. Sixty-four extracted, single-rooted human teeth of similar length were instrumented and irrigated with a 1% sodium hypochlorite solution and then randomly assigned (n = 8 per group) to receive a final one-minute rinse with 5 ml of test solutions, water, or the pure aqueous Tween/propylene glycol solution. Calcium concentration in eluates was measured using atomic absorption spectrometry. Incorporation of wetting agents resulted in a reduction of surface tension values by approximately 50% in all tested solutions. However, none of the solutions with reduced surface tension chelated more calcium from canals than their pure counterparts (p > 0.05).

  16. Determination of Surface Tension of Surfactant Solutions through Capillary Rise Measurements: An Image-Processing Undergraduate Laboratory Experiment

    Science.gov (United States)

    Huck-Iriart, Cristia´n; De-Candia, Ariel; Rodriguez, Javier; Rinaldi, Carlos

    2016-01-01

    In this work, we described an image processing procedure for the measurement of surface tension of the air-liquid interface using isothermal capillary action. The experiment, designed for an undergraduate course, is based on the analysis of a series of solutions with diverse surfactant concentrations at different ionic strengths. The objective of…

  17. Density, viscosity, and surface tension of synthesis grade imidazolium,pyridinium, and pyrrolidinium based room temperature ionic liquids

    NARCIS (Netherlands)

    Galan Sanchez, L.M.; Espel, J.R.; Onink, S.A.F.; Meindersma, G.W.; Haan, de A.B.

    2009-01-01

    Density, viscosity, and surface tension data sets of 13 ionic liquids formed by imidazolium, pyridinium, or pyrrolidinium cations paired with dicyanamide (DCA), tetrafluoroborate (BF4¯), thiocyanate (SCN¯),methylsulfate (MeSO4¯), and trifluoroacetate (TFA) anions are reported. The properties were

  18. Surface Effects on Nanoscale Gas Flows

    Science.gov (United States)

    Beskok, Ali; Barisik, Murat

    2010-11-01

    3D MD simulations of linear Couette flow of argon gas confined within nano-scale channels are performed in the slip, transition and free molecular flow regimes. The velocity and density profiles show deviations from the kinetic theory based predictions in the near wall region that typically extends three molecular diameters (s) from each surface. Utilizing the Irwin-Kirkwood theorem, stress tensor components for argon gas confined in nano-channels are investigated. Outside the 3s region, three normal stress components are identical, and equal to pressure predicted using the ideal gas law, while the shear stress is a constant. Within the 3s region, the normal stresses become anisotropic and the shear stress shows deviations from its bulk value due to the surface virial effects. Utilizing the kinetic theory and MD predicted shear stress values, the tangential momentum accommodation coefficient for argon gas interacting with FCC structured walls (100) plane facing the fluid is calculated to be 0.75; this value is independent of the Knudsen number. Results show emergence of the 3s region as an additional characteristic length scale in nano-confined gas flows.

  19. Studies on the interaction between nanodiamond and human hemoglobin by surface tension measurement and spectroscopy methods.

    Science.gov (United States)

    Pishkar, Leila; Taheri, Saba; Makarem, Somayeh; Alizadeh Zeinabad, Hojjat; Rahimi, Arash; Saboury, Ali Akbar; Falahati, Mojtaba

    2017-02-01

    In this study, a novel method to probe molecular interactions and binding of human hemoglobin (Hb) with nanodiamond (ND) was introduced based on the surface tension measurement. This method complements conventional techniques, which are basically done by zeta potential and dynamic light scattering (DLS) measurements, near and far circular dichroism (CD) spectroscopy, intrinsic and extrinsic fluorescence spectroscopy. Addition of ND to Hb solution increased the surface tension value of Hb-ND complex relative to those of Hb and ND molecules. The zeta potential values reveled that Hb and ND provide identical charge distribution at pH 7.5. DLS measurements demonstrated that Hb, ND, and ND-Hb complex have hydrodynamic radiuses of 98.37 ± 4.57, 122.07 ± 7.88 nm and 62.27 ± 3.70 at pH of 7.5 respectively. Far and near UV-CD results indicated the loss of α-helix structure and conformational changes of Hb, respectively. Intrinsic fluorescence data demonstrated that the fluorescence quenching of Hb by ND was the result of the static quenching. The hydrophobic interaction plays a pivotal role in the interaction of ND with Hb. Fluorescence intensity changes over time revealed conformational change of Hb continues after the mixing of the components (Hb-ND) till 15 min, which is indicative of the denaturation of the Hb relative to the protein control. Extrinsic fluorescence data showed a considerable enhancement of the ANS fluorescence intensity of Hb-ND system relative to the Hb till 60 nM of ND, likely persuaded by greater exposure of nonpolar residues of Hb hydrophobic pocket. The remarkable decrease in T m value of Hb in Hb-ND complex exhibits interaction of Hb with ND conducts to conformational changes of Hb. This study offers consequential discrimination into the interaction of ND with proteins, which may be of significance for further appeal of these nanoparticles in biotechnology prosecution.

  20. Natural convection with evaporation in a vertical cylindrical cavity under the effect of temperature-dependent surface tension

    Science.gov (United States)

    Kozhevnikov, Danil A.; Sheremet, Mikhail A.

    2018-01-01

    The effect of surface tension on laminar natural convection in a vertical cylindrical cavity filled with a weak evaporating liquid has been analyzed numerically. The cylindrical enclosure is insulated at the bottom, heated by a constant heat flux from the side, and cooled by a non-uniform evaporative heat flux from the top free surface having temperature-dependent surface tension. Governing equations with corresponding boundary conditions formulated in dimensionless stream function, vorticity, and temperature have been solved by finite difference method of the second-order accuracy. The influence of Rayleigh number, Marangoni number, and aspect ratio on the liquid flow and heat transfer has been studied. Obtained results have revealed that the heat transfer rate at free surface decreases with Marangoni number and increases with Rayleigh number, while the average temperature inside the cavity has an opposite behavior; namely, it growths with Marangoni number and reduces with Rayleigh number.

  1. Pressure and surface tension of solid-liquid interface using Tara zona density functional theory

    International Nuclear Information System (INIS)

    Moradi, M.; Kavosh Tehrani, M.

    2001-01-01

    The weighted density functional theory proposed by Tara zona is applied to study the solid-liquid interface. In the last two decades the weighted density functional became a useful tool to consider the properties of inhomogeneous liquids. In this theory, the role of the size of molecules or the particles of which the matter is composed, was found to be important. In this research we study a hard sphere fluid beside a hard wall. For this study the liquid is an inhomogeneous system. We use the definition of the direct correlation function as a second derivative of free energy with respect to the density. We use this definition and the definition of the weighting function, then we minimize the grand potential with respect to the density to get the Euler Lagrange equation and we obtain an integral equation to find the inhomogeneous density profile. The obtained density profile as a function of the distance from the wall, for different bulk density is pitted in three dimensions. We also calculate the pressure and compare it with the Carnahan-Starling results, and finally we obtained the surface tension at liquid-solid interface and compared it with the results of Monte Carlo simulation

  2. Theory of melt polyelectrolyte blends and block copolymers: Phase behavior, surface tension, and microphase periodicity

    Energy Technology Data Exchange (ETDEWEB)

    Sing, Charles E. [Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208 (United States); Department of Chemical and Biomolecular Engineering, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Zwanikken, Jos W.; Olvera de la Cruz, Monica [Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208 (United States)

    2015-01-21

    Polymer mixtures such as blends or block copolymers are of great interest in energy applications and functional materials, and often, one or more of these species contain charges. The traditional fashion in which such materials are studied uses Self-Consistent Field Theory (SCFT) methods that incorporate electrostatics using Poisson-Boltzmann (PB) theory. We adapt a new and rigorous approach that does not rely on the mean-field assumptions inherent in the PB theory and instead uses Liquid State (LS) integral equation theory to articulate charge correlations that are completely neglected in PB. We use this theory to calculate phase diagrams for both blends and block copolyelectrolytes using SCFT-LS and demonstrate how their phase behavior is highly dependent on chain length, charge fraction, charge size, and the strength of Coulombic interactions. Beyond providing phase behavior of blends and block copolyelectrolytes, we can use this theory to investigate the interfacial properties such as surface tension and block copolyelectrolyte lamellar spacing. Lamellar spacing provides a way to directly compare the SCFT-LS theory to the results of experiments. SCFT-LS will provide conceptual and mathematical clarification of the role of charge correlations in these systems and aid in the design of materials based on charge polymers.

  3. The Prediction of Surface Tension of Ternary Mixtures at Different Temperatures Using Artificial Neural Networks

    Directory of Open Access Journals (Sweden)

    Ali Khazaei

    2014-07-01

    Full Text Available In this work, artificial neural network (ANN has been employed to propose a practical model for predicting the surface tension of multi-component mixtures. In order to develop a reliable model based on the ANN, a comprehensive experimental data set including 15 ternary liquid mixtures at different temperatures was employed. These systems consist of 777 data points generally containing hydrocarbon components. The ANN model has been developed as a function of temperature, critical properties, and acentric factor of the mixture according to conventional corresponding-state models. 80% of the data points were employed for training ANN and the remaining data were utilized for testing the generated model. The average absolute relative deviations (AARD% of the model for the training set, the testing set, and the total data points were obtained 1.69, 1.86, and 1.72 respectively. Comparing the results with Flory theory, Brok-Bird equation, and group contribution theory has proved the high prediction capability of the attained model.

  4. Theory of melt polyelectrolyte blends and block copolymers: Phase behavior, surface tension, and microphase periodicity

    International Nuclear Information System (INIS)

    Sing, Charles E.; Zwanikken, Jos W.; Olvera de la Cruz, Monica

    2015-01-01

    Polymer mixtures such as blends or block copolymers are of great interest in energy applications and functional materials, and often, one or more of these species contain charges. The traditional fashion in which such materials are studied uses Self-Consistent Field Theory (SCFT) methods that incorporate electrostatics using Poisson-Boltzmann (PB) theory. We adapt a new and rigorous approach that does not rely on the mean-field assumptions inherent in the PB theory and instead uses Liquid State (LS) integral equation theory to articulate charge correlations that are completely neglected in PB. We use this theory to calculate phase diagrams for both blends and block copolyelectrolytes using SCFT-LS and demonstrate how their phase behavior is highly dependent on chain length, charge fraction, charge size, and the strength of Coulombic interactions. Beyond providing phase behavior of blends and block copolyelectrolytes, we can use this theory to investigate the interfacial properties such as surface tension and block copolyelectrolyte lamellar spacing. Lamellar spacing provides a way to directly compare the SCFT-LS theory to the results of experiments. SCFT-LS will provide conceptual and mathematical clarification of the role of charge correlations in these systems and aid in the design of materials based on charge polymers

  5. Pressure and surface tension of soild-liquid interface using Tarazona density functional theory

    Directory of Open Access Journals (Sweden)

    M. M.

    2000-12-01

    Full Text Available   The weighted density functional theory proposed by Tarazona is applied to study the solid-liquid interface. In the last two decades the weighted density functional became a useful tool to consider the properties of inhomogeneous liquids. In this theory, the role of the size of molecules or the particles of which the matter is composed, was found to be important. In this resarch we study a hard sphere fluid beside a hard wall. For this study the liquid is an inhomogeneous system. We use the definition of the direct correlation function as a second derivative of free energy with respect to the density. We use this definition and the definition of the weighting function, then we minimize the grand potential with respect to the density to get the Euler Lagrange equation and we obtain an integral equation to find the inhomogeneous density profile. The obtained density profile as a function of the distance from the wall, for different bulk density is plotted in three dimensions. We also calculate the pressure and compare it with the Carnahan-starling results, and finally we obtained the surface tension at liquid-solid interface and compared it with the results of Monte Carlo simulation.

  6. A Tale of Energy Transition and Tension: The Incomplete Universalization of the Natural Gas Grid in Istanbul

    International Nuclear Information System (INIS)

    Arik, Elvan

    2013-01-01

    Available studies on natural gas networks have so far made little contribution to an understanding of changes in urban management in emerging cities. However, the development of such energy systems, considered as cleaner and more efficient compared to previous systems based primarily on the use of traditional fuels (wood, coal, LPG, biofuels) leads these cities into an energy transition. This process is firstly characterized by the introduction of a new energy resource that then involves changes in certain domestic practices (such as, in our case study, heating and culinary practices). Focusing on the case of the development of the natural gas network in Istanbul, this paper studies the tensions inherent in this transformation. Socio-political and territorial analysis of the deployment of this network, which allows us to evaluate the actual universalization of the service, allows us to turn our attention away from the issue of access to the infrastructure and toward the concrete domestic uses of the service

  7. Lung ventilation injures areas with discrete alveolar flooding, in a surface tension-dependent fashion.

    Science.gov (United States)

    Wu, You; Kharge, Angana Banerjee; Perlman, Carrie E

    2014-10-01

    With proteinaceous-liquid flooding of discrete alveoli, a model of the edema pattern in the acute respiratory distress syndrome, lung inflation over expands aerated alveoli adjacent to flooded alveoli. Theoretical considerations suggest that the overexpansion may be proportional to surface tension, T. Yet recent evidence indicates proteinaceous edema liquid may not elevate T. Thus whether the overexpansion is injurious is not known. Here, working in the isolated, perfused rat lung, we quantify fluorescence movement from the vasculature to the alveolar liquid phase as a measure of overdistension injury to the alveolar-capillary barrier. We label the perfusate with fluorescence; micropuncture a surface alveolus and instill a controlled volume of nonfluorescent liquid to obtain a micropunctured-but-aerated region (control group) or a region with discrete alveolar flooding; image the region at a constant transpulmonary pressure of 5 cmH2O; apply five ventilation cycles with a positive end-expiratory pressure of 0-20 cmH2O and tidal volume of 6 or 12 ml/kg; return the lung to a constant transpulmonary pressure of 5 cmH2O; and image for an additional 10 min. In aerated areas, ventilation is not injurious. With discrete alveolar flooding, all ventilation protocols cause sustained injury. Greater positive end-expiratory pressure or tidal volume increases injury. Furthermore, we determine T and find injury increases with T. Inclusion of either plasma proteins or Survanta in the flooding liquid does not alter T or injury. Inclusion of 2.7-10% albumin and 1% Survanta together, however, lowers T and injury. Contrary to expectation, albumin inclusion in our model facilitates exogenous surfactant activity. Copyright © 2014 the American Physiological Society.

  8. Mass transfer in fuel cells. [electron microscopy of components, thermal decomposition of Teflon, water transport, and surface tension of KOH solutions

    Science.gov (United States)

    Walker, R. D., Jr.

    1973-01-01

    Results of experiments on electron microscopy of fuel cell components, thermal decomposition of Teflon by thermogravimetry, surface area and pore size distribution measurements, water transport in fuel cells, and surface tension of KOH solutions are described.

  9. The effects of temperature and alkyl chain length on the density and surface tension of the imidazolium-based geminal dicationic ionic liquids

    International Nuclear Information System (INIS)

    Moosavi, Majid; Khashei, Fatemeh; Sharifi, Ali; Mirzaei, Mojtaba

    2017-01-01

    Highlights: • Surface tension and density of three GDILs were measured at different temperatures. • Surface entropy and surface enthalpy indicate the surface ordering in these GDILs. • Parachors and critical temperatures of these systems were estimated. • Results of GDILs were compared with the results of corresponding traditional MILs. • Relations between surface tension, density and viscosity of GDILs were demonstrated. - Abstract: Surface tensions and densities of three imidazolium-based geminal dicationic ionic liquids (GDILs) with the bis(trifluoromethylsulfonyl)imide, [NTf 2 ] − , as a common anion, have been measured at ambient pressure at different temperatures in the range from 296.00 to 353.15 K. The surface thermodynamic functions such as surface entropy and surface enthalpy were derived from the temperature dependence of surface tension which indicated the surface ordering in these GDILs. As well as the parachor, the critical temperatures of these systems have been estimated using the Guggenheim and Eotvos correlations. In each case, the results of GDILs have been compared with the results of corresponding traditional monocationic ILs (MILs). Also, the relations between the surface tension and density and also surface tension and viscosity data have been demonstrated and discussed.

  10. Evaluation of salivary surface tension in a cohort of young healthy adults.

    Science.gov (United States)

    Foglio-Bonda, P L; Laguini, E; Davoli, C; Pattarino, F; Foglio-Bonda, A

    2018-03-01

    To determine salivary pH, flow rate (FR) and surface tension (γs) in a cohort of 30 healthy young adults. To acquire cohort biological independent variables (age, gender, weight, height, medications, smoking, pathologies, and allergies) and to correlate them with pH, FR and γs obtained values. Evaluate the possible variation of the γs values during the time after the withdrawal and the influence of the operational abilities of the experimenting operators. Evaluate the relationship between γs, pH and FR  and the dependence between pH and FR. Non-stimulated saliva samples were taken in four different time span, for three days, with a drooling method for 15 minutes. The saliva sample was analyzed, in terms of γs, by two different operators (OP1 and OP2), twice consecutive (γs-1 and γs-2) for a total of 360 measurements. The γs was calculated using the du Noüy method. The FR was evaluated by weighing technique and pH by pH indicator papers. The measurements of γs performed by two different operators (OP1, OP2) showed respectively average values of 46.46 mN/m and 43.45 mN/m, while the mean FR was 0.29 ± 0.13 mL/min and the average pH was 7.1 ± 0.43. There were no significant correlations between γs and the biological variables analyzed. We can consider as reference values, in a sample of young adults, γs 45.56 ± 6.51 mN/m.

  11. Validity and Reliability of Surface Electromyography in the Assessment of Primary Muscle Tension Dysphonia.

    Science.gov (United States)

    Khoddami, Seyyedeh Maryam; Talebian, Saeed; Izadi, Farzad; Ansari, Noureddin Nakhostin

    2017-05-01

    The study aims to evaluate the reliability and the discriminative validity of surface electromyography (sEMG) in the assessment of patients with primary muscle tension dysphonia (MTD). The study design is cross-sectional. Fifteen patients with primary MTD (mean age: 34.07 ± 10.99 years) and 15 healthy volunteers (mean age: 34.53 ± 10.63 years) were included. All participants underwent evaluation of sEMG to record the electrical activity of the thyrohyoid and cricothyroid muscles. The outcome measures were the root mean square (RMS), activity peak, duration, and time to the peak activity, which were obtained during /a/ and /i/ prolongation for test-retest reliability. The test-retest reliability was good to excellent for the RMS and peak activity measures (intraclass correlation coefficient [agreement] [ICC agreement ] = 0.49-0.98). The reliability for the activity duration was poor to excellent (ICC agreement  = 0.19-0.9). Poor test-retest reliability was found for the time to peak measure (ICC agreement  = 0.15-0.37). The standard error of measurement for all sEMG measures was between 0.41 and 2.05. The smallest detectable change (SDC) was calculated between 1.13 and 5.66. The highest SDC values were obtained for the peak and the lowest SDCs were documented for the duration (5.66 and 1.13, respectively). All sEMG measures were not able to discriminate between the MTD patients and healthy subjects (P > 0.05). The sEMG is a reliable tool to measure the RMS, the peak activity, and the activity duration in primary MTD. However, it is not able to discriminate the patients with primary MTD from healthy subjects. Copyright © 2017 The Voice Foundation. Published by Elsevier Inc. All rights reserved.

  12. Dynamic surface tension and adsorption mechanism of surfactin biosurfactant at the air-water interface.

    Science.gov (United States)

    Onaizi, Sagheer A

    2018-03-01

    The dynamic adsorption of the anionic biosurfactant, surfactin, at the air-water interface has been investigated in this work and compared to those of two synthetic surfactants: the anionic sodium dodecylbenzenesulfonate (SDBS) and the nonionic octaethylene glycol monotetradecyl ether (C 14 E 8 ). The results revealed that surfactin adsorption at the air-water interface is purely controlled by diffusion mechanism at the initial stage of the adsorption process (i.e., [Formula: see text]), but shifts towards a mixed diffusion-barrier mechanism when surface tension approaches equilibrium (i.e., [Formula: see text]) due to the development of an energy barrier for adsorption. Such energy barrier has been found to be a function of the surfactin bulk concentration (increases with increasing surfactin concentration) and it is estimated to be in the range of 1.8-9.5 kJ/mol. Interestingly, such a trend (pure diffusion-controlled mechanism at [Formula: see text] and mixed diffusion-barrier mechanism at [Formula: see text]) has been also observed for the nonionic C 14 E 8 surfactant. Unlike the pure diffusion-controlled mechanism of the initial surfactin adsorption, which was the case in the presence and the absence of the sodium ion (Na + ), SDBS showed a mixed diffusion-barrier controlled at both short and long time, with an energy barrier of 3.0-9.0 and 3.8-18.0 kJ/mol, respectively. Such finding highlights the nonionic-like adsorption mechanism of surfactin despite its negative charge.

  13. Direct numerical simulation of turbulent flows over superhydrophobic surfaces with gas pockets using linearized boundary conditions

    Science.gov (United States)

    Seo, Jongmin; Bose, Sanjeeb; Garcia-Mayoral, Ricardo; Mani, Ali

    2012-11-01

    Superhydrophobic surfaces are shown to be effective for surface drag reduction under laminar regime by both experiments and simulations (see for example, Ou and Rothstein, Phys. Fluids 17:103606, 2005). However, such drag reduction for fully developed turbulent flow maintaining the Cassie-Baxter state remains an open problem due to high shear rates and flow unsteadiness of turbulent boundary layer. Our work aims to develop an understanding of mechanisms leading to interface breaking and loss of gas pockets due to interactions with turbulent boundary layers. We take advantage of direct numerical simulation of turbulence with slip and no-slip patterned boundary conditions mimicking the superhydrophobic surface. In addition, we capture the dynamics of gas-water interface, by deriving a proper linearized boundary condition taking into account the surface tension of the interface and kinematic matching of interface deformation and normal velocity conditions on the wall. We will show results from our simulations predicting the dynamical behavior of gas pocket interfaces over a wide range of dimensionless surface tensions. Supported by the Office of Naval Research and the Kwanjeong Educational Scholarship Foundation.

  14. Silica-Assisted Nucleation of Polymer Foam Cells with Nanoscopic Dimensions: Impact of Particle Size, Line Tension, and Surface Functionality.

    Science.gov (United States)

    Liu, Shanqiu; Eijkelenkamp, Rik; Duvigneau, Joost; Vancso, G Julius

    2017-11-01

    Core-shell nanoparticles consisting of silica as core and surface-grafted poly(dimethylsiloxane) (PDMS) as shell with different diameters were prepared and used as heterogeneous nucleation agents to obtain CO 2 -blown poly(methyl methacrylate) (PMMA) nanocomposite foams. PDMS was selected as the shell material as it possesses a low surface energy and high CO 2 -philicity. The successful synthesis of core-shell nanoparticles was confirmed by Fourier transform infrared spectroscopy, thermogravimetric analysis, and transmission electron microscopy. The cell size and cell density of the PMMA micro- and nanocellular materials were determined by scanning electron microscopy. The cell nucleation efficiency using core-shell nanoparticles was significantly enhanced when compared to that of unmodified silica. The highest nucleation efficiency observed had a value of ∼0.5 for nanoparticles with a core diameter of 80 nm. The particle size dependence of cell nucleation efficiency is discussed taking into account line tension effects. Complete engulfment by the polymer matrix of particles with a core diameter below 40 nm at the cell wall interface was observed corresponding to line tension values of approximately 0.42 nN. This line tension significantly increases the energy barrier of heterogeneous nucleation and thus reduces the nucleation efficiency. The increase of the CO 2 saturation pressure to 300 bar prior to batch foaming resulted in an increased line tension length. We observed a decrease of the heterogeneous nucleation efficiency for foaming after saturation with CO 2 at 300 bar, which we attribute to homogenous nucleation becoming more favorable at the expense of heterogeneous nucleation in this case. Overall, it is shown that the contribution of line tension to the free energy barrier of heterogeneous foam cell nucleation must be considered to understand foaming of viscoelastic materials. This finding emphasizes the need for new strategies including the use of

  15. Detachment of polystyrene particles from collector surfaces by surface tension forces induced by air-bubble passage through a parallel plate flow chamber

    NARCIS (Netherlands)

    Wit, PJ; vanderMei, HC; Busscher, HJ

    1997-01-01

    By allowing an air-bubble to pass through a parallel plate flow chamber with negatively charged, colloidal polystyrene particles adhering to the bottom collector plate of the chamber, the detachment of adhering particles stimulated by surface tension forces induced by the passage of a liquid-air

  16. Measurement of the surface tension of Santowax 'R', para-, meta-, and ortho-terphenyl, diphenyl, diphenyl ether and dowtherm 'A'

    International Nuclear Information System (INIS)

    Bowring, R.W.; Garton, D.A.; Kinneir, J.H.

    1961-09-01

    Values of surface tension were obtained over the temperature range from near the melting point to near the normal boiling point of each substance. A capillary rise method was used employing a closed glass U-tube apparatus. The accuracy was ± 3% near the melting point falling to ± 5% near the normal boiling point. Values of the parachor calculated from the experimental data were in excellent agreement with those calculated from the molecular structure using the method proposed by Sugden. The surface tension in each case decreased with ascending temperature from near 30 to 40 dynes/cm close to the melting point to 13 to 15 dynes/cm near the normal boiling point. (author)

  17. Influence of Zinc on the Surface Tension, Density and Molar Volume of (Ag-Sneut +Zn Liquid Alloys

    Directory of Open Access Journals (Sweden)

    Gąsior W.

    2016-03-01

    Full Text Available The dilatometric and maximum bubble pressure methods were applied for the measurements of the density and surface tension of liquid (Ag-Sneut +Zn lead-free solders. The experiments were carried out in the temperature range from 515 to 1223 K for the alloys of the zinc concentration equaling 0.01, 0.02, 0.04, 0.05, 0.1 and 0.2 of the mole fraction. It was found that the temperature dependence of both the density and the surface tension could be thought as linear, so they were interpreted by straight line equations. The experimental data of the molar volume of the investigated alloys were described by the polynomial dependent on the composition and temperature.

  18. The effect of a curvature-dependent surface tension on the singularities at the tips of a straight interface crack

    KAUST Repository

    Zemlyanova, A. Y.

    2013-03-08

    A problem of an interface crack between two semi-planes made out of different materials under an action of an in-plane loading of general tensile-shear type is treated in a semi-analytical manner with the help of Dirichlet-to-Neumann mappings. The boundaries of the crack and the interface between semi-planes are subjected to a curvature-dependent surface tension. The resulting system of six singular integro-differential equations is reduced to the system of three Fredholm equations. It is shown that the introduction of the curvature-dependent surface tension eliminates both classical integrable power singularity of the order 1/2 and an oscillating singularity present in a classical linear elasticity solutions. The numerical results are obtained by solving the original system of singular integro-differential equations by approximating unknown functions with Taylor polynomials. © 2013 The Author.

  19. Effect of Vegetable Oils on the Surface Tension, Diffusion and Efficiency of Sethoxydim to Control Wild oat (Avena ludoviciana Durieu.

    Directory of Open Access Journals (Sweden)

    H. Hammami

    2017-08-01

    Full Text Available Introduction: During last century, population explosion has been pressing man to produce more supplies of food by consuming more energy in agroecosystems like applying chemical management strategies. herbicides have increasingly become a key component of weed management programs. In Iran, using herbicides led to increasing wheat yield about 20% and 22% in rainfed and irrigated farms respectively (20. Nonetheless, herbicides have also a negative impact on environment. A tool for reducing the herbicide usage which allows to decreasing their cost and side effects is the use of adjuvants. They increase the effectiveness of the post-emergence herbicides. Some adjuvants have toxic effects on living organisms such as Polyethoxylated tallowamine adjuvants that they are very toxic in fairy shrimp (Thamnocephalus platyurus (6. Vegetable oils are not phytotoxic and likely are degraded and metabolized quickly in the environment (8. Sethoxydim is an acetyl coenzyme A carboxylase (ACCase inhibitor that is considered to be a key enzyme in lipid biosynthesis. Similar to other foliar applied herbicides, it need to be associated with an adjuvant for more effective control. Vegetable oils can be developed characteristics of sethoxydim solution such as surface tension and spry drop diffusion. Therefore, the objective of this research is to determine the effect of vegetable oils on the surface tension, diffusion and efficiency of sethoxydim to control wild oat (Avena ludoviciana Durieu.. Materials and Metods: To evaluate the effect of vegetable oils on properties of sethoxydim solution, a series of experiments were separately conducted at Ferdowsi University of Mashhad and Khorasan Science and Technology Park in 2012. For evaluating the effect of vegetable oils on surface tension of distilled water and sethoxydim solution and the sethoxydim efficiency on wild oat control, three experiments were conducted as factorial based on completely randomized design. In other

  20. Force Field Benchmark of the TraPPE_UA for Polar Liquids: Density, Heat of Vaporization, Dielectric Constant, Surface Tension, Volumetric Expansion Coefficient, and Isothermal Compressibility.

    Science.gov (United States)

    Núñez-Rojas, Edgar; Aguilar-Pineda, Jorge Alberto; Pérez de la Luz, Alexander; de Jesús González, Edith Nadir; Alejandre, José

    2018-02-08

    The transferable potential for a phase equilibria force field in its united-atom version, TraPPE_UA, is evaluated for 41 polar liquids that include alcohols, thiols, ethers, sulfides, aldehydes, ketones, and esters to determine its ability to reproduce experimental properties that were not included in the parametrization procedure. The intermolecular force field parameters for pure components were fit to reproduce experimental boiling temperature, vapor-liquid coexisting densities, and critical point (temperature, density, and pressure) using Monte Carlo simulations in different ensembles. The properties calculated in this work are liquid density, heat of vaporization, dielectric constant, surface tension, volumetric expansion coefficient, and isothermal compressibility. Molecular dynamics simulations were performed in the gas and liquid phases, and also at the liquid-vapor interface. We found that relative error between calculated and experimental data is 1.2% for density, 6% for heat of vaporization, and 6.2% for surface tension, in good agreement with the experimental data. The dielectric constant is systematically underestimated, and the relative error is 37%. Evaluating the performance of the force field to reproduce the volumetric expansion coefficient and isothermal compressibility requires more experimental data.

  1. Effects of reduced surface tension on two-phase diversion cross-flow between subchannels simplifying triangle tight lattice rod bundle

    International Nuclear Information System (INIS)

    Kawahara, Akimaro; Sadatomi, Michio; Higuchi, Tatsuya

    2009-01-01

    Two-phase diversion cross-flow between tight lattice subchannels has been investigated experimentally and analytically. For hydraulically non-equilibrium flows with the pressure difference between the subchannels, experiments were conducted using a vertical multiple-channel with two subchannels simplifying a triangle tight lattice rod bundle. To know the effects of the reduced surface tension on the diversion cross-flow, water and water with a surfactant were used as the test liquids. Data were obtained on the axial variations in the pressure difference between the subchannels, gas and liquid flow rates and void fraction in each subchannel for slug-churn and annular flows. In the analysis, flow redistribution processes due to the diversion cross-flow have been calculated by our subchannel analysis code based on a two-fluid model. From a comparison between the experiment and the code calculation, the code was found to be valid against the present data if the improved constitutive equations of wall and interfacial friction reported in our previous paper were incorporated to account for the reduced surface tension effects. (author)

  2. Efficient numerical methods for simulating surface tension of multi-component mixtures with the gradient theory of fluid interfaces

    KAUST Repository

    Kou, Jisheng

    2015-08-01

    Surface tension significantly impacts subsurface flow and transport, and it is the main cause of capillary effect, a major immiscible two-phase flow mechanism for systems with a strong wettability preference. In this paper, we consider the numerical simulation of the surface tension of multi-component mixtures with the gradient theory of fluid interfaces. Major numerical challenges include that the system of the Euler-Lagrange equations is solved on the infinite interval and the coefficient matrix is not positive definite. We construct a linear transformation to reduce the Euler-Lagrange equations, and naturally introduce a path function, which is proven to be a monotonic function of the spatial coordinate variable. By using the linear transformation and the path function, we overcome the above difficulties and develop the efficient methods for calculating the interface and its interior compositions. Moreover, the computation of the surface tension is also simplified. The proposed methods do not need to solve the differential equation system, and they are easy to be implemented in practical applications. Numerical examples are tested to verify the efficiency of the proposed methods. © 2014 Elsevier B.V.

  3. The Mechanical of the Small Axisymmetric Oscillations of the Liquid with the Surface Tension Forces in Elastic Tank

    Directory of Open Access Journals (Sweden)

    D. A. Goncharov

    2015-01-01

    Full Text Available In this paper we investigate small axisymmetric oscillations of a liquid in an elastic tank. We also take into account the influence of surface tension forces. For this, we turn to the mechanical analogue of the considered mechanical system. To realize the transition to mechanical analogue we use the energy method: postulating the equality of kinetic and potential energy for the investigated mechanical system and the mechanical system analog. Due to this transition we can further investigate the oscillations of a mechanical analogue. As a mechanical analogue, we consider the oscillator in the spring. The mass of the oscillator is calculated as the weight of the fluid to make oscillations. The oscillator spring constant is calculated using the identity of equations, namely, equation of free small oscillations of the oscillator and equation of free small oscillations of the system under investigation: the fluid in the elastic tank. The identity of equations allows us to draw conclusion about the identity of the natural frequencies for the source mechanical system and the system of a mechanical analogue. Next, we take into consideration the action of the surface tension. We record the Laplace condition for excess pressure because of the forces of surface tension. Then we compile the expression for the generalized force, taking into account the phenomenon of the surface tension. Next, we write the equation of oscillations of a mechanical analogue. The surface tension, due to the introduction of the generalized force in the equation for small oscillations of the mechanical analogue will change the natural frequency of the mechanical analogue. The paper presents the appropriate dependencies. The abovementioned allows us to investigate the stability of small motions of fluid in microgravity or low gravity by studying the stability of small motions of mechanical analogue. The latter is especially important due to the design and development of advanced

  4. Variant of a volume-of-fluid method for surface tension-dominant two ...

    Indian Academy of Sciences (India)

    2013-12-27

    Dec 27, 2013 ... face tension-dominant two-phase flows are explained. ... for one particular fluid inside a cell as its material volume divided by the total ... the reconstructed interface and the velocity field, and the final part ..... Welch S W J and Wilson J 2000 A volume of fluid based method for fluid flows with phase change. J.

  5. Rough surface mitigates electron and gas emission

    International Nuclear Information System (INIS)

    Molvik, A.

    2004-01-01

    Heavy-ion beams impinging on surfaces near grazing incidence (to simulate the loss of halo ions) generate copious amounts of electrons and gas that can degrade the beam. We measured emission coefficients of η e (le) 130 and η 0 ∼ 10 4 respectively, with 1 MeV K + incident on stainless steel. Electron emission scales as η e ∝ 1/cos(θ), where θ is the ion angle of incidence relative to normal. If we were to roughen a surface by blasting it with glass beads, then ions that were near grazing incidence (90 o ) on smooth surface would strike the rims of the micro-craters at angles closer to normal incidence. This should reduce the electron emission: the factor of 10 reduction, Fig. 1(a), implies an average angle of incidence of 62 o . Gas desorption varies more slowly with θ (Fig. 1(b)) decreasing a factor of ∼2, and along with the electron emission is independent of the angle of incidence on a rough surface. In a quadrupole magnet, electrons emitted by lost primary ions are trapped near the wall by the magnetic field, but grazing incidence ions can backscatter and strike the wall a second time at an azimuth where magnetic field lines intercept the beam. Then, electrons can exist throughout the beam (see the simulations of Cohen, HIF News 1-2/04). The SRIM (TRIM) Monte Carlo code predicts that 60-70% of 1 MeV K + ions backscatter when incident at 88-89 o from normal on a smooth surface. The scattered ions are mostly within ∼10 o of the initial direction but a few scatter by up to 90 o . Ion scattering decreases rapidly away from grazing incidence, Fig. 1(c ). At 62 deg. the predicted ion backscattering (from a rough surface) is 3%, down a factor of 20 from the peak, which should significantly reduce electrons in the beam from lost halo ions. These results are published in Phys. Rev. ST - Accelerators and Beams

  6. The effect of a soap film on a catenary: measurement of surface tension from the triangular configuration

    Energy Technology Data Exchange (ETDEWEB)

    Behroozi, F [Department of Physics, University of Northern Iowa, Cedar Falls, IA 50614 (United States); Behroozi, P S, E-mail: behroozi@uni.edu [Department of Physics, Stanford University, Stanford, CA 94305 (United States)

    2011-09-15

    A chain assumes the well-known shape known as a catenary when it hangs loosely from two points in a gravitational field. The correct solution of the catenary was one of the early triumphs of the newly invented calculus of variations at the end of the 17th century. Here we revisit the catenary and show that, for a chain hanging from a horizontal rod, three new and distinct configurations are possible if a soap film covers the area bounded by the chain and the rod. We first review the general problem and discuss the conditions under which the chain assumes a concave, triangular or convex configuration. The deciding factor is the strength of surface tension relative to the gravitational force per unit length of the chain. The conditions under which the chain assumes the shape of a perfect triangle are discussed in greater detail and analysed to obtain the tension along the chain. The triangular configuration is especially intriguing to undergraduates and may be used as a simple experiment to obtain the surface tension of the soap solution by measuring just one angle of the triangle.

  7. The effect of a soap film on a catenary: measurement of surface tension from the triangular configuration

    International Nuclear Information System (INIS)

    Behroozi, F; Behroozi, P S

    2011-01-01

    A chain assumes the well-known shape known as a catenary when it hangs loosely from two points in a gravitational field. The correct solution of the catenary was one of the early triumphs of the newly invented calculus of variations at the end of the 17th century. Here we revisit the catenary and show that, for a chain hanging from a horizontal rod, three new and distinct configurations are possible if a soap film covers the area bounded by the chain and the rod. We first review the general problem and discuss the conditions under which the chain assumes a concave, triangular or convex configuration. The deciding factor is the strength of surface tension relative to the gravitational force per unit length of the chain. The conditions under which the chain assumes the shape of a perfect triangle are discussed in greater detail and analysed to obtain the tension along the chain. The triangular configuration is especially intriguing to undergraduates and may be used as a simple experiment to obtain the surface tension of the soap solution by measuring just one angle of the triangle.

  8. Do the contact angle and line tension of surface-attached droplets depend on the radius of curvature?

    Science.gov (United States)

    Das, Subir K; Egorov, Sergei A; Virnau, Peter; Winter, David; Binder, Kurt

    2018-06-27

    Results from Monte Carlo simulations of wall-attached droplets in the three-dimensional Ising lattice gas model and in a symmetric binary Lennard-Jones fluid, confined by antisymmetric walls, are analyzed, with the aim to estimate the dependence of the contact angle [Formula: see text] on the droplet radius [Formula: see text] of curvature. Sphere-cap shape of the wall-attached droplets is assumed throughout. An approach, based purely on 'thermodynamic' observables, e.g. chemical potential, excess density due to the droplet, etc, is used, to avoid ambiguities in the decision which particles belong (or do not belong, respectively) to the droplet. It is found that the results are compatible with a variation [Formula: see text], [Formula: see text] being the contact angle in the thermodynamic limit ([Formula: see text]). The possibility to use such results to estimate the excess free energy related to the contact line of the droplet, namely the line tension, at the wall, is discussed. Various problems that hamper this approach and were not fully recognized in previous attempts to extract the line tension are identified. It is also found that the dependence of wall tensions on the difference of chemical potential of the droplet from that at the bulk coexistence provides effectively a change of the contact angle of similar magnitude. The simulation approach yields precise estimates for the excess density due to wall-attached droplets and the corresponding free energy excess, relative to a system without a droplet at the same chemical potential. It is shown that this information suffices to estimate nucleation barriers, not affected by ambiguities on droplet shape, contact angle and line tension.

  9. Viscosity and surface tension effects during multiphase flow in propped fractures

    Science.gov (United States)

    Dzikowski, Michał; Dąbrowski, Marcin

    2017-04-01

    Geological sequestration of CO2 was proposed as an important mechanism to reduce its emission into atmosphere. CO2 exhibits a higher affinity to organic matter than methane molecules and, potentially, it could be pumped and stored in shale reservoirs while enhancing late stage shale gas production. A successful analysis of CO2 sequestration in low matrix permeability rocks such as shales requires a thorough understanding of multiphase flow in stimulated rock fractures, which provide most significant pathways for fluids in such systems. Multiphase fracture flows are also of great relevance to brine, oil and gas migration in petroleum systems, water and stream circulation in geothermal reservoirs, and chemical transport of non-aqueous phase liquids in shallow hydrogeological systems, particularly in partially saturated zones. There are various physical models that describe phenomena taking place during multiphase flow through porous media. One of key aspects that need to be considered are pore-scale effects related to capillarity. Unfortunately, detailed models that describe motion and evolution of phase or component boundary require direct numerical simulations and spatial resolutions that are hard to reach when considering industrial relevant systems. Main aim of the presented work was the development of reduced 2.5D models based on Brinkman approximation of thin domain flow that would be able to capture local scale phenomena without expensive 3D simulations. Presented approach was designed specifically to tackle incompressible and immiscible systems and is based on Continuous Surface Force approach presented by Brackbill et al., implemented using Lattice Boltzmann Method. Presented approach where firstly validated against standard test cases with known classical solution and known experimental data. In the second part, we present and discuss two component, immiscible permeability data for rough and propped fracture obtained with our code for a rage of proppants

  10. Surface tension of decane binary and ternary mixtures with eicosane, docosane, and tetracosane

    DEFF Research Database (Denmark)

    Queimada, Antonio; Cao, A.I.; Marrucho, I.M.

    2005-01-01

    -C24H50 and the ternary n-C10H22 + n-C20H42 + n-C24H50 were measured from 293.15 K (or above the solution melting temperature) up to 343.15 K. An average absolute deviation of 1.3% was obtained in comparison with pure component literature data. No mixture information for the reported systems was found......A tensiometer operating on the Wilhelmy plate method was employed to measure liquid-vapor interfacial tensions of three binary mixtures and one ternary mixture of decane with eicosane, docosane, and tetracosane. Tensions of binary mixtures n-C10H22 + n-C20H42, n-C10H22 + n-C22H46, and n-C10H22 + n...

  11. Surface Tension of Supercooled Water Determined by Using a Counterpressure Capillary Rise Method

    Czech Academy of Sciences Publication Activity Database

    Vinš, Václav; Fransen, M. A. L. J.; Hykl, Jiří; Hrubý, Jan

    2015-01-01

    Roč. 119, č. 17 (2015), s. 5567-5575 ISSN 1520-6106 R&D Projects: GA MŠk LG13056; GA ČR GJ15-07129Y Institutional support: RVO:61388998 Keywords : capillary tube * interfacial tension * metastable liquid * supercooled liquid Subject RIV: BJ - Thermodynamics Impact factor: 3.187, year: 2015 http://pubs.acs.org/doi/abs/10.1021/acs.jpcb.5b00545

  12. Comparative simulations of microjetting using atomistic and continuous approaches in the presence of viscosity and surface tension

    Science.gov (United States)

    Durand, O.; Jaouen, S.; Soulard, L.; Heuzé, O.; Colombet, L.

    2017-10-01

    We compare, at similar scales, the processes of microjetting and ejecta production from shocked roughened metal surfaces by using atomistic and continuous approaches. The atomistic approach is based on very large scale molecular dynamics (MD) simulations with systems containing up to 700 × 106 atoms. The continuous approach is based on Eulerian hydrodynamics simulations with adaptive mesh refinement; the simulations take into account the effects of viscosity and surface tension, and the equation of state is calculated from the MD simulations. The microjetting is generated by shock-loading above its fusion point a three-dimensional tin crystal with an initial sinusoidal free surface perturbation, the crystal being set in contact with a vacuum. Several samples with homothetic wavelengths and amplitudes of defect are simulated in order to investigate the influence of viscosity and surface tension of the metal. The simulations show that the hydrodynamic code reproduces with very good agreement the profiles, calculated from the MD simulations, of the ejected mass and velocity along the jet. Both codes also exhibit a similar fragmentation phenomenology of the metallic liquid sheets ejected, although the fragmentation seed is different. We show in particular, that it depends on the mesh size in the continuous approach.

  13. The effects of viscosity, surface tension, and flow rate on gasoil-water flow pattern in microchannels

    Energy Technology Data Exchange (ETDEWEB)

    Boogar, Rahman Sadeghi; Gheshlaghi, Reza; Mahdavi, Mahmood Akhavan [Ferdowsi University of Mashhad, Mashhad (Iran, Islamic Republic of)

    2013-01-15

    A microchannel was fabricated with glass tubes to investigate the effect of viscosity, surface tension, and flow rate on the liquid-liquid two-phase flow regime. Water and gasoil were selected as aqueous and organic working fluids, respectively. The two fluids were injected into the microchannel and created either slug or parallel profile depending on the applied conditions. The range of Reynolds and capillary numbers was chosen in such a way that neither inertia nor interfacial tension forces were negligible. Xanthan gum was used to increase viscosity and Triton X-100 (TX-100) and Sodium Dodecyl Sulfate (SDS) were used to reduce the interfacial tension. The results demonstrated that higher value of viscosity and flow rate increased interfacial area, but slug flow regime remained unchanged. The two surfactants showed different effects on the flow regime and interfacial area. Addition of TX-100 did not change the slug flow but decreased the interfacial area. In contrast, addition of SDS increased interfacial area by decreasing the slug’s length in the low concentrations and by switching from slug to parallel regime at high concentrations.

  14. Equilibrium surface tension and the interaction energy of DMSO with tert-butyl alcohol or iso-amyl alcohol at various temperatures

    International Nuclear Information System (INIS)

    Bagheri, Ahmad; Moradian, Zohreh

    2014-01-01

    Highlights: • Surface tension of non-ideal binary systems of alcohol/DMSO determined. • The surface tension data of binary mixtures were correlated with five equations. • The interaction energy values were calculated by using LWW model. • The U 12 value shows different behavior for two systems with increasing temperature. - Abstract: Surface tension of binary mixtures of tert-butyl alcohol (TBA) and iso-amyl alcohol (IAA) with DMSO (dimethyl sulfoxide) were measured over the entire concentration range at pressure of 82.5 kPa at temperatures between (298.15 and 328.15) K. Correlating the surface tension and surface tension deviation of the above mentioned binary systems was performed with empirical and thermodynamic based models. The average relative error obtained from the comparison of experimental and calculated surface tension values for the two binary systems with five models at various temperatures is less than 2%. The effect of temperature on the interaction energy values in binary mixtures has been used to obtain information about solute structural effects on DMSO. Also, the experimental data were used to evaluate the nature and type of intermolecular interactions in binary mixtures

  15. Uncovering behavioural diversity amongst high-strength Pseudomonas spp. surfactants at the limit of liquid surface tension reduction.

    Science.gov (United States)

    Kabir, Kamaluddeen; Deeni, Yusuf Y; Hapca, Simona M; Moore, Luke; Spiers, Andrew J

    2018-02-01

    Bacterial biosurfactants have a wide range of biological functions and biotechnological applications. Previous analyses had suggested a limit to their reduction of aqueous liquid surface tensions (γMin), and here we confirm this in an analysis of 25 Pseudomonas spp. strains isolated from soil which produce high-strength surfactants that reduce surface tensions to 25.2 ± 0.1-26.5 ± 0.2 mN m-1 (the surface tension of sterile growth medium and pure water was 52.9 ± 0.4 mN m-1 and 72.1 ± 1.2 mN m-1, respectively). Comparisons of culture supernatants produced using different growth media and semi-purified samples indicate that the limit of 24.2-24.7 mN m-1 is not greatly influenced by culture conditions, pH or NaCl concentrations. We have used foam, emulsion and oil-displacement behavioural assays as a simple and cost-effective proxy for in-depth biochemical characterisation, and these suggest that there is significant structural diversity amongst these surfactants that may reflect different biological functions and offer new biotechnological opportunities. Finally, we obtained a draft genome for the strain producing the highest strength surfactant, and identified a cluster of non-ribosomal protein synthase genes that may produce a cyclic lipopeptide (CLP)-like surfactant. Further investigation of this group of related bacteria recovered from the same site will allow a better understanding of the significance of the great variety of surfactants produced by bacterial communities found in soil and elsewhere. © FEMS 2018. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  16. Measurement and modelling of high pressure density and interfacial tension of (gas + n-alkane) binary mixtures

    International Nuclear Information System (INIS)

    Pereira, Luís M.C.; Chapoy, Antonin; Burgass, Rod; Tohidi, Bahman

    2016-01-01

    Highlights: • (Density + IFT) measurements are performed in synthetic reservoir fluids. • Measured systems include CO_2, CH_4 and N_2 with n-decane. • Novel data are reported for temperatures up to 443 K and pressures up to 69 MPa. • Predictive models are tested in 16 (gas + n-alkane) systems. • Best modelling results are achieved with the Density Gradient Theory. - Abstract: The deployment of more efficient and economical extraction methods and processing facilities of oil and gas requires the accurate knowledge of the interfacial tension (IFT) of fluid phases in contact. In this work, the capillary constant a of binary mixtures containing n-decane and common gases such as carbon dioxide, methane and nitrogen was measured. Experimental measurements were carried at four temperatures (313, 343, 393 and 442 K) and pressures up to 69 MPa, or near the complete vaporisation of the organic phase into the gas-rich phase. To determine accurate IFT values, the capillary constants were combined with saturated phase density data measured with an Anton Paar densitometer and correlated with a model based on the Peng–Robinson 1978 equation of state (PR78 EoS). Correlated density showed an overall percentage absolute deviation (%AAD) to measured data of (0.2 to 0.5)% for the liquid phase and (1.5 to 2.5)% for the vapour phase of the studied systems and P–T conditions. The predictive capability of models to accurately describe both the temperature and pressure dependence of the saturated phase density and IFT of 16 (gas + n-alkane) binary mixtures was assessed in this work by comparison with data gathered from the literature and measured in this work. The IFT models considered include the Parachor, the Linear Gradient Theory (LGT) and the Density Gradient Theory (DGT) approaches combined with the Volume-Translated Predictive Peng–Robinson 1978 EoS (VT-PPR78 EoS). With no adjustable parameters, the VT-PPR78 EoS allowed a good description of both solubility and

  17. Effect of surface tension and coefficient of thermal expansion in 30 nm scale nanoimprinting with two flexible polymer molds

    International Nuclear Information System (INIS)

    Kim, Jae Kwan; Cho, Hye Sung; Jung, Ho-Sup; Suh, Kahp-Yang; Lim, Kipil; Kim, Ki-Bum; Choi, Dae-Geun; Jeong, Jun-Ho

    2012-01-01

    We report on nanoimprinting of polymer thin films at 30 nm scale resolution using two types of ultraviolet (UV)-curable, flexible polymer molds: perfluoropolyether (PFPE) and polyurethane acrylate (PUA). It was found that the quality of nanopatterning at the 30 nm scale is largely determined by the combined effects of surface tension and the coefficient of thermal expansion of the polymer mold. In particular, the polar component of surface tension may play a critical role in clean release of the mold, as evidenced by much reduced delamination or broken structures for the less polarized PFPE mold when patterning a relatively hydrophilic PMMA film. In contrast, such problems were not notably observed with a relatively hydrophobic PS film for both polymer molds. In addition, the demolding characteristic was also influenced by the coefficient of thermal expansion so that no delamination or uniformity problems were observed when patterning a UV-curable polymer film at room temperature. These results suggest that a proper polymeric mold material needs to be chosen for patterning polymer films under different surface properties and processing conditions, providing insights into how a clean demolding characteristic can be obtained at 30 nm scale nanopatterning. (paper)

  18. Drought limitations to leaf-level gas exchange: results from a model linking stomatal optimization and cohesion-tension theory.

    Science.gov (United States)

    Novick, Kimberly A; Miniat, Chelcy F; Vose, James M

    2016-03-01

    We merge concepts from stomatal optimization theory and cohesion-tension theory to examine the dynamics of three mechanisms that are potentially limiting to leaf-level gas exchange in trees during drought: (1) a 'demand limitation' driven by an assumption of optimal stomatal functioning; (2) 'hydraulic limitation' of water movement from the roots to the leaves; and (3) 'non-stomatal' limitations imposed by declining leaf water status within the leaf. Model results suggest that species-specific 'economics' of stomatal behaviour may play an important role in differentiating species along the continuum of isohydric to anisohydric behaviour; specifically, we show that non-stomatal and demand limitations may reduce stomatal conductance and increase leaf water potential, promoting wide safety margins characteristic of isohydric species. We used model results to develop a diagnostic framework to identify the most likely limiting mechanism to stomatal functioning during drought and showed that many of those features were commonly observed in field observations of tree water use dynamics. Direct comparisons of modelled and measured stomatal conductance further indicated that non-stomatal and demand limitations reproduced observed patterns of tree water use well for an isohydric species but that a hydraulic limitation likely applies in the case of an anisohydric species. Published 2015. This article is a US Government work and is in the public domain in the USA.

  19. Deleted in Malignant Brain Tumors 1 (DMBT1 is present in hyaline membranes and modulates surface tension of surfactant

    Directory of Open Access Journals (Sweden)

    Griese Matthias

    2007-10-01

    Full Text Available Abstract Background Deleted in Malignant Brain Tumors 1 (DMBT1 is a secreted scavenger receptor cysteine-rich protein that binds various bacteria and is thought to participate in innate pulmonary host defense. We hypothesized that pulmonary DMBT1 could contribute to respiratory distress syndrome in neonates by modulating surfactant function. Methods DMBT1 expression was studied by immunohistochemistry and mRNA in situ hybridization in post-mortem lungs of preterm and full-term neonates with pulmonary hyaline membranes. The effect of human recombinant DMBT1 on the function of bovine and porcine surfactant was measured by a capillary surfactometer. DMBT1-levels in tracheal aspirates of ventilated preterm and term infants were determined by ELISA. Results Pulmonary DMBT1 was localized in hyaline membranes during respiratory distress syndrome. In vitro addition of human recombinant DMBT1 to the surfactants increased surface tension in a dose-dependent manner. The DMBT1-mediated effect was reverted by the addition of calcium depending on the surfactant preparation. Conclusion Our data showed pulmonary DMBT1 expression in hyaline membranes during respiratory distress syndrome and demonstrated that DMBT1 increases lung surface tension in vitro. This raises the possibility that DMBT1 could antagonize surfactant supplementation in respiratory distress syndrome and could represent a candidate target molecule for therapeutic intervention in neonatal lung disease.

  20. The use of computational thermodynamics for the determination of surface tension and Gibbs-Thomson coefficient of multicomponent alloys

    Science.gov (United States)

    Ferreira, D. J. S.; Bezerra, B. N.; Collyer, M. N.; Garcia, A.; Ferreira, I. L.

    2018-04-01

    The simulation of casting processes demands accurate information on the thermophysical properties of the alloy; however, such information is scarce in the literature for multicomponent alloys. Generally, metallic alloys applied in industry have more than three solute components. In the present study, a general solution of Butler's formulation for surface tension is presented for multicomponent alloys and is applied in quaternary Al-Cu-Si-Fe alloys, thus permitting the Gibbs-Thomson coefficient to be determined. Such coefficient is a determining factor to the reliability of predictions furnished by microstructure growth models and by numerical computations of solidification thermal parameters, which will depend on the thermophysical properties assumed in the calculations. The Gibbs-Thomson coefficient for ternary and quaternary alloys is seldom reported in the literature. A numerical model based on Powell's hybrid algorithm and a finite difference Jacobian approximation has been coupled to a Thermo-Calc TCAPI interface to assess the excess Gibbs energy of the liquid phase, permitting liquidus temperature, latent heat, alloy density, surface tension and Gibbs-Thomson coefficient for Al-Cu-Si-Fe hypoeutectic alloys to be calculated, as an example of calculation capabilities for multicomponent alloys of the proposed method. The computed results are compared with thermophysical properties of binary Al-Cu and ternary Al-Cu-Si alloys found in the literature and presented as a function of the Cu solute composition.

  1. Density, viscosity, surface tension, and spectroscopic properties for binary system of 1,2-ethanediamine + diethylene glycol

    International Nuclear Information System (INIS)

    Li, Lihua; Zhang, Jianbin; Li, Qiang; Guo, Bo; Zhao, Tianxiang; Sha, Feng

    2014-01-01

    Graphical abstract: Excess property of the binary system 1,2-ethanediamine (EDA) + diethylene glycol (DEG). - Highlights: • Densities and viscosities of EDA + DEG at 298.15–318.150 K were listed. • Thermodynamics data of EDA + DEG at 298.15–318.15 K were calculated. • Surface tension of EDA + DEG at 298.15 K was measured. • Intermolecular interaction of EDA with DEG was discussed. - Abstract: This paper reports density and viscosity data at T = 298.15, 303.15, 308.15, 313.15, and 318.15 K and surface tension data at 298.15 K for the binary system 1,2-ethanediamine (EDA) + diethylene glycol (DEG) as a function of composition under atmospheric pressure. From the experimental density and viscosity data, the excess molar volume and viscosity deviation were calculated, and the results were fitted to a Redlich–Kister equation to obtain the coefficients and to estimate the standard deviations between the experimental and calculated quantities. Based on the kinematic viscosity data, enthalpy of activation for viscous flow, entropy of activation for the viscous flow, and Gibbs energies of activation of viscous flow were calculated. In addition, based on Fourier transform infrared spectra, UV–vis spectra, and electrical conductivity for the system EDA + DEG with various concentrations, intermolecular interaction of EDA with DEG was discussed

  2. Measurement and study of density, surface tension, and viscosity of quaternary ammonium-based ionic liquids ([N222(n)]Tf2N)

    International Nuclear Information System (INIS)

    Ghatee, Mohammad Hadi; Bahrami, Maryam; Khanjari, Neda

    2013-01-01

    Highlights: • Characterization of high purity synthesized alkyl quaternary ammonium ionic liquids. • Measurement of temperature dependent surface tension, density, viscosity and critical point. • Systematic increase of surface energy and surface entropy having plateau at high chain length. • Accurate application of VFT and fluidity equations to temperature dependent viscosities. • Particular variation of fluidity exponent with a plateau at high alkyl chain length. -- Abstract: In this work five quaternary ammonium-based ionic liquids with bis(trifluoromethylsulfonyl)imide anion were synthesized and their density, viscosity and surface tensions were measured in the temperature range (298 to 373) K. Surface tensions were measured by capillary rise method using a homemade capillary apparatus, in which the liquid/vapor can be brought into equilibrium practically. Measurements of viscosities and surface tensions were performed under water–vapor free atmosphere. The surface tension of quaternary ammonium-based ILs decreases as the alkyl chain length increases. Also surface energy and surface entropy are found as increasing functions of alkyl chain length with a plateau at high lengths in the surface. The viscosities measured by capillary viscometer fit in VFT equation, indication of non-Arrhenius ionic liquids. Viscosities are also fitted quite accurately in the relation we have developed recently as the fluidity equation with the characteristics exponent ϕ. Values of ϕ for ionic liquids are close to one another and tend to the limiting value, almost 0.328, asymptotically as the alkyl chain length increases. The critical temperatures predicted via the temperature dependent surface tensions decrease with increasing alkyl chain length of the cation. The trend of predicted critical temperature of these ionic liquids conforms to those of imidazolium-based ILs

  3. Crystallization of hard spheres revisited. II. Thermodynamic modeling, nucleation work, and the surface of tension.

    Science.gov (United States)

    Richard, David; Speck, Thomas

    2018-06-14

    Combining three numerical methods (forward flux sampling, seeding of droplets, and finite-size droplets), we probe the crystallization of hard spheres over the full range from close to coexistence to the spinodal regime. We show that all three methods allow us to sample different regimes and agree perfectly in the ranges where they overlap. By combining the nucleation work calculated from forward flux sampling of small droplets and the nucleation theorem, we show how to compute the nucleation work spanning three orders of magnitude. Using a variation of the nucleation theorem, we show how to extract the pressure difference between the solid droplet and ambient liquid. Moreover, combining the nucleation work with the pressure difference allows us to calculate the interfacial tension of small droplets. Our results demonstrate that employing bulk quantities yields inaccurate results for the nucleation rate.

  4. On Energy Inequality for the Problem on the Evolution of Two Fluids of Different Types Without Surface Tension

    Science.gov (United States)

    Denisova, Irina Vlad.

    2015-03-01

    The paper deals with the motion of two immiscible viscous fluids in a container, one of the fluids being compressible while another one being incompressible. The interface between the fluids is an unknown closed surface where surface tension is neglected. We assume the compressible fluid to be barotropic, the pressure being given by an arbitrary smooth increasing function. This problem is considered in anisotropic Sobolev-Slobodetskiǐ spaces. We show that the L 2-norms of the velocity and deviation of compressible fluid density from the mean value decay exponentially with respect to time. The proof is based on a local existence theorem (Denisova, Interfaces Free Bound 2:283-312, 2000) and on the idea of constructing a function of generalized energy, proposed by Padula (J Math Fluid Mech 1:62-77, 1999). In addition, we eliminate the restrictions for the viscosities which appeared in Denisova (Interfaces Free Bound 2:283-312, 2000).

  5. Application of the Eötvos and Guggenheim empirical rules for predicting the density and surface tension of ionic liquids analogues

    International Nuclear Information System (INIS)

    Mjalli, Farouq S.; Vakili-Nezhaad, Gholamreza; Shahbaz, Kaveh; AlNashef, Inas M.

    2014-01-01

    Highlights: • Critical temperatures of eight common DES were calculated using two methods. • Density and surface tension were calculated using the Rackett and Guggenheim equations. • The Rackett method should be used in the low temperature range only. • The Eötvos and Guggenheim methods gave best density and surface tension predictions. - Abstract: The recent continuing interest in deep eutectic solvents (DES) as ionic liquids analogues and their successful applications in different areas of separation necessities the existence of reliable physical and thermodynamic properties database. The scarcity of data on the physical properties of such solvents, increases the need for their prediction using reliable methods. In this study, first the critical temperatures of eight DES systems have been calculated based on the Eötvos empirical equation using the experimental data of the density and surface tension at various temperatures, then the density and surface tension values of these systems were predicted from the calculated critical temperatures. For the density prediction the Eötvos and Guggenheim equations were combined to introduce a simple power law equation using the estimated critical temperatures from the Eötvos and the Modified Lydersen–Joback–Reid group contribution methods. Finally, the estimated critical temperatures by these two methods were used in the Guggenheim empirical equation to calculate the surface tension of the DES systems. The prediction quality of the two physical properties under investigation were compared and proper recommendations were postulated

  6. Application of the Eötvos and Guggenheim empirical rules for predicting the density and surface tension of ionic liquids analogues

    Energy Technology Data Exchange (ETDEWEB)

    Mjalli, Farouq S., E-mail: farouqsm@yahoo.com [Petroleum and Chemical Engineering Department, Sultan Qaboos University, 123 Sultanate of Oman (Oman); Vakili-Nezhaad, Gholamreza; Shahbaz, Kaveh [School of Engineering, Taylor' s University, 47500 Selangor (Malaysia); AlNashef, Inas M. [Chemical Engineering Department, King Saud University, Riyadh 11421 (Saudi Arabia)

    2014-01-10

    Highlights: • Critical temperatures of eight common DES were calculated using two methods. • Density and surface tension were calculated using the Rackett and Guggenheim equations. • The Rackett method should be used in the low temperature range only. • The Eötvos and Guggenheim methods gave best density and surface tension predictions. - Abstract: The recent continuing interest in deep eutectic solvents (DES) as ionic liquids analogues and their successful applications in different areas of separation necessities the existence of reliable physical and thermodynamic properties database. The scarcity of data on the physical properties of such solvents, increases the need for their prediction using reliable methods. In this study, first the critical temperatures of eight DES systems have been calculated based on the Eötvos empirical equation using the experimental data of the density and surface tension at various temperatures, then the density and surface tension values of these systems were predicted from the calculated critical temperatures. For the density prediction the Eötvos and Guggenheim equations were combined to introduce a simple power law equation using the estimated critical temperatures from the Eötvos and the Modified Lydersen–Joback–Reid group contribution methods. Finally, the estimated critical temperatures by these two methods were used in the Guggenheim empirical equation to calculate the surface tension of the DES systems. The prediction quality of the two physical properties under investigation were compared and proper recommendations were postulated.

  7. Direct Observation of Domain-Wall Surface Tension by Deflating or Inflating a Magnetic Bubble

    Science.gov (United States)

    Zhang, Xueying; Vernier, Nicolas; Zhao, Weisheng; Yu, Haiming; Vila, Laurent; Zhang, Yue; Ravelosona, Dafiné

    2018-02-01

    The surface energy of a magnetic domain wall (DW) strongly affects its static and dynamic behaviors. However, this effect is seldom directly observed, and some of the related phenomena are not well understood. Moreover, a reliable method to quantify the DW surface energy is still absent. Here, we report a series of experiments in which the DW surface energy becomes a dominant parameter. We observe that a semicircular magnetic domain bubble can spontaneously collapse under the Laplace pressure induced by DW surface energy. We further demonstrate that the surface energy can lead to a geometrically induced pinning when the DW propagates in a Hall cross or from a nanowire into a nucleation pad. Based on these observations, we develop two methods to quantify the DW surface energy, which can be very helpful in the estimation of intrinsic parameters such as Dzyaloshinskii-Moriya interactions or exchange stiffness in magnetic ultrathin films.

  8. Tension Headache

    Science.gov (United States)

    ... tight band around your head. A tension headache (tension-type headache) is the most common type of headache, and ... Headache after a head injury, especially if the headache gets worse ... tension or stress. But research suggests muscle contraction isn't the ...

  9. Effects of non-uniform temperature gradients on surface tension driven two component magneto convection in a porous- fluid system

    Science.gov (United States)

    Manjunatha, N.; Sumithra, R.

    2018-04-01

    The problem of surface tension driven two component magnetoconvection is investigated in a Porous-Fluid system, consisting of anincompressible two component electrically conducting fluid saturatedporous layer above which lies a layer of the same fluid in the presence of a uniform vertical magnetic field. The lower boundary of the porous layeris rigid and the upper boundary of the fluid layer is free with surfacetension effects depending on both temperature and concentration, boththese boundaries are insulating to heat and mass. At the interface thevelocity, shear and normal stress, heat and heat flux, mass and mass fluxare assumed to be continuous suitable for Darcy-Brinkman model. Theeigenvalue problem is solved in linear, parabolic and inverted parabolictemperature profiles and the corresponding Thermal Marangoni Numberis obtained for different important physical parameters.

  10. Mean field diffusion models for precipitation in crystalline GaAs including surface tension and bulk stresses

    Energy Technology Data Exchange (ETDEWEB)

    Dreyer, Wolfgang [Weierstrass-Institut fuer Angewandte Analysis und Stochastik (WIAS) im Forschungsverbund Berlin e.V. (Germany); Kimmerle, Sven-Joachim [Humboldt-Univ. Berlin (Germany). Dept. of Mathematics

    2009-07-01

    Based on a thermodynamically consistent model for precipitation in gallium arsenide crystals including surface tension and bulk stresses by Dreyer and Duderstadt, we propose different mathematical models to describe the size evolution of liquid droplets in a crystalline solid. The first class of models treats the diffusion-controlled regime of interface motion, while the second class is concerned with the interface-controlled regime of interface motion. Our models take care of conservation of mass and substance. We consider homogenised models, where different length scales of the experimental situation have been exploited in order to simplify the equations. These homogenised models generalise the well-known Lifshitz-Slyozov-Wagner model for Ostwald ripening. Mean field models capture the main properties of our system and are well adapted for numerics and further analysis. Numerical evidence suggests in which case which one of the two regimes might be appropriate to the experimental situation. (orig.)

  11. Surface tension, density, and speed of sound for the ternary mixture {l_brace}diethyl carbonate + p-xylene + decane{r_brace}

    Energy Technology Data Exchange (ETDEWEB)

    Mosteiro, Laura; Casas, Lidia M. [Departamento de Fisica Aplicada, Facultad de Ciencias Experimentales, Universidad de Vigo, Lagoas Marcosende s/n, 36310 Vigo (Spain); Legido, Jose L. [Departamento de Fisica Aplicada, Facultad de Ciencias Experimentales, Universidad de Vigo, Lagoas Marcosende s/n, 36310 Vigo (Spain)], E-mail: xllegido@uvigo.es

    2009-05-15

    This paper reports the results of a new experimental study of thermophysical properties for the ternary mixture of {l_brace}diethyl carbonate + p-xylene + decane{r_brace}. Surface tension has been measured at 298.15 K and, density and speed of sound have been measured in the temperature range T = (288.15 to 308.15) K. Excess molar volumes, excess isentropic compressibilities, and surface tension deviations, have been calculated from experimental data. Surface tension deviations have been correlated with Cibulka equation and Nagata and Tamura equation was used for the other excess properties. Good accuracy has been obtained. These excess magnitudes are discussed qualitatively in terms of the nature and type of intermolecular interactions of the components involved.

  12. Effects of the kinematic viscosity and surface tension on the bubble take-off period in a catalase-hydrogen peroxide system.

    Science.gov (United States)

    Sasaki, Satoshi; Iida, Yoshinori

    2009-06-01

    The effect of kinematic viscosity and surface tension of the solution was investigated by adding catalase, glucose oxidase, or glucose on the bubble movement in a catalase-hydrogen peroxide system. The kinematic viscosity was measured using a Cannon-Fenske kinematic viscometer. The surface tension of the solution was measured by the Wilhelmy method using a self-made apparatus. The effects of the hole diameter/cell wall thickness, catalase concentration, glucose concentration, and glucose oxidase concentration on the kinematic viscosity, surface tension, and bubble take-off period were investigated. With our system, the effects of the changes in the solution materiality on the bubble take-off period were proven to be very small in comparison to the change in the oxygen-producing rate.

  13. Simulation of Two-Fluid Flows by the Least-Squares Finite Element Method Using a Continuum Surface Tension Model

    Science.gov (United States)

    Wu, Jie; Yu, Sheng-Tao; Jiang, Bo-nan

    1996-01-01

    In this paper a numerical procedure for simulating two-fluid flows is presented. This procedure is based on the Volume of Fluid (VOF) method proposed by Hirt and Nichols and the continuum surface force (CSF) model developed by Brackbill, et al. In the VOF method fluids of different properties are identified through the use of a continuous field variable (color function). The color function assigns a unique constant (color) to each fluid. The interfaces between different fluids are distinct due to sharp gradients of the color function. The evolution of the interfaces is captured by solving the convective equation of the color function. The CSF model is used as a means to treat surface tension effect at the interfaces. Here a modified version of the CSF model, proposed by Jacqmin, is used to calculate the tension force. In the modified version, the force term is obtained by calculating the divergence of a stress tensor defined by the gradient of the color function. In its analytical form, this stress formulation is equivalent to the original CSF model. Numerically, however, the use of the stress formulation has some advantages over the original CSF model, as it bypasses the difficulty in approximating the curvatures of the interfaces. The least-squares finite element method (LSFEM) is used to discretize the governing equation systems. The LSFEM has proven to be effective in solving incompressible Navier-Stokes equations and pure convection equations, making it an ideal candidate for the present applications. The LSFEM handles all the equations in a unified manner without any additional special treatment such as upwinding or artificial dissipation. Various bench mark tests have been carried out for both two dimensional planar and axisymmetric flows, including a dam breaking, oscillating and stationary bubbles and a conical liquid sheet in a pressure swirl atomizer.

  14. Shale gas development impacts on surface water quality in Pennsylvania

    Science.gov (United States)

    Olmstead, Sheila M.; Muehlenbachs, Lucija A.; Shih, Jhih-Shyang; Chu, Ziyan; Krupnick, Alan J.

    2013-01-01

    Concern has been raised in the scientific literature about the environmental implications of extracting natural gas from deep shale formations, and published studies suggest that shale gas development may affect local groundwater quality. The potential for surface water quality degradation has been discussed in prior work, although no empirical analysis of this issue has been published. The potential for large-scale surface water quality degradation has affected regulatory approaches to shale gas development in some US states, despite the dearth of evidence. This paper conducts a large-scale examination of the extent to which shale gas development activities affect surface water quality. Focusing on the Marcellus Shale in Pennsylvania, we estimate the effect of shale gas wells and the release of treated shale gas waste by permitted treatment facilities on observed downstream concentrations of chloride (Cl−) and total suspended solids (TSS), controlling for other factors. Results suggest that (i) the treatment of shale gas waste by treatment plants in a watershed raises downstream Cl− concentrations but not TSS concentrations, and (ii) the presence of shale gas wells in a watershed raises downstream TSS concentrations but not Cl− concentrations. These results can inform future voluntary measures taken by shale gas operators and policy approaches taken by regulators to protect surface water quality as the scale of this economically important activity increases. PMID:23479604

  15. Flow and Displacement of Non-Newtonian Fluid(Power-Law Model) by Surface Tension and Gravity Force in Inclined Circular Tube

    International Nuclear Information System (INIS)

    Moh, Jeong Hah; Cho, Y. I.

    2014-01-01

    This paper presents the theoretical analysis of a flow driven by surface tension and gravity in an inclined circular tube. A governing equation is developed for describing the displacement of a non-Newtonian fluid(Power-law model) that continuously flows into a circular tube owing to surface tension, which represents a second-order, nonlinear, non-homogeneous, and ordinary differential form. It was found that quantitatively, the theoretical predictions of the governing equation were in excellent agreement with the solutions of the equation for horizontal tubes and the past experimental data. In addition, the predictions compared very well with the results of the force balance equation for steady

  16. Effect of temperature and chain length on the viscosity and surface tension of binary systems of N,N-dimethylformamide with 1-octanol, 1-nonanol and 1-decanol

    International Nuclear Information System (INIS)

    Mohammad, Abubaker A.; Alkhaldi, Khaled H.A.E.; AlTuwaim, Mohammad S.; Al-Jimaz, Adel S.

    2014-01-01

    Highlights: • Effect of temperature and chain length on η and σ of DMF + 1-alkanol binary systems. • Viscosity and surface tension were obtained. • Δη, Δσ and G ∗E were calculated using the experimental data. • H σ and S σ were determined using the surface tension data. • Semi-empirical relations were used to estimate the viscosity of liquid mixtures. - Abstract: Viscosity and surface tension of binary systems of N,N-dimethylformamide DMF with higher 1-alkanols (C 8 –C 10 ) were measured at atmospheric pressure and four different temperatures over the entire range of mole fraction. The experimental measurements were used to calculate the deviations in viscosity and surface tension. Furthermore, the excess Gibbs free energy of activation, surface enthalpy and surface entropy of the (DMF + 1-alkanols) binary mixtures were determined. In addition, the deviation and excess properties were fitted to the method of Redlich–Kister (R–K) polynomial. Viscosity data of the binary systems were correlated with three different expressions (Grunberg and Nissan, the three-body, and four-body McAllister). The effects of the chain length of the higher 1-alkanols and temperature were investigated

  17. The effect of surface tension on the contraction coefficient of a jet

    International Nuclear Information System (INIS)

    Gasmi, A; Mekias, H

    2003-01-01

    Two-dimensional free surface potential flow issued from an opening of a container is considered. The flow is assumed to be inviscid and incompressible. The mathematical problem, which is characterized by the nonlinear boundary condition on the free surface of an unknown equation, is solved via a series truncation. We computed solutions for all Weber numbers. Our problem is an extension of the work done by Ackerberg and Liu (1987 Phys. Fluids 30 289-96), the results confirm and extend their results

  18. KINEMATICAL FEATURES OF FORMATION OF A FLANGE WITH MINIMUM TENSION OF A TRANSIENT TOROIDAL SURFACE

    Directory of Open Access Journals (Sweden)

    M. I. Sidorenko

    2018-01-01

    Full Text Available The technology of plastic forming of wide flanges in tube billets with the predicted length of the transitional toroidal section between the outer plane of the flange and the internal cavity of the pipe is proposed. The procedure for calculating the length of this section is given. In order to eliminate the toroidal portion in the flange formed during the flanging of the pipe, it is proposed to perform its plastic shaping by depositing the cylindrical part of the workpiece. Equations for calculating the extent of the free surface on the toroidal part of the workpiece when it is shaped, depending on the coefficient of contact friction and the presence of a radial support of the flange are obtained. The variant of forming in the flange the toroidal section in the stamp with the compensation cavity is proposed. Equations for calculating the deformation force and the extent of the free surface are given.

  19. Evaluation of surface tension and Tolman length as a function of droplet radius from experimental nucleation rate and supersaturation ratio: metal vapor homogeneous nucleation.

    Science.gov (United States)

    Onischuk, A A; Purtov, P A; Baklanov, A M; Karasev, V V; Vosel, S V

    2006-01-07

    Zinc and silver vapor homogeneous nucleations are studied experimentally at the temperature from 600 to 725 and 870 K, respectively, in a laminar flow diffusion chamber with Ar as a carrier gas at atmospheric pressure. The size, shape, and concentration of aerosol particles outcoming the diffusion chamber are analyzed by a transmission electron microscope and an automatic diffusion battery. The wall deposit is studied by a scanning electron microscope (SEM). Using SEM data the nucleation rate for both Zn and Ag is estimated as 10(10) cm(-3) s(-1). The dependence of critical supersaturation on temperature for Zn and Ag measured in this paper as well as Li, Na, Cs, Ag, Mg, and Hg measured elsewhere is analyzed. To this aim the classical nucleation theory is extended by the dependence of surface tension on the nucleus radius. The preexponent in the formula for the vapor nucleation rate is derived using the formula for the work of formation of noncritical embryo [obtained by Nishioka and Kusaka [J. Chem. Phys. 96, 5370 (1992)] and later by Debenedetti and Reiss [J. Chem. Phys. 108, 5498 (1998)

  20. Computer modeling of the dynamics of surface tension on rotating fluids in low and microgravity environments

    Science.gov (United States)

    Hung, R. J.; Tsao, Y. D.; Hong, B. B.; Leslie, Fred W.

    1989-01-01

    Time-dependent evolutions of the profile of the free surface (bubble shapes) for a cylindrical container partially filled with a Newtonian fluid of constant density, rotating about its axis of symmetry, have been studied. Numerical computations have been carried out with the following situations: (1) linear functions of spin-up and spin-down in low- and microgravity environments, (2) linear functions of increasing and decreasing gravity environments at high- and low-rotating cylinder speeds, and (3) step functions of spin-up and spin-down in a low-gravity environment.

  1. Time-dependent dynamical behavior of surface tension on rotating fluids under microgravity environment

    Science.gov (United States)

    Hung, R. J.; Tsao, Y. D.; Hong, B. B.; Leslie, F. W.

    1988-01-01

    Time dependent evolutions of the profile of free surface (bubble shapes) for a cylindrical container partially filled with a Newtonian fluid of constant density, rotating about its axis of symmetry, have been studied. Numerical computations of the dynamics of bubble shapes have been carried out with the following situations: (1) linear functions of spin-up and spin-down in low and microgravity environments, (2) step functions of spin-up and spin-down in a low gravity environment, and (3) sinusoidal function oscillation of gravity environment in high and low rotating cylinder speeds.

  2. J-integral and limit load analysis of semi-elliptical surface cracks in plates under tension

    International Nuclear Information System (INIS)

    Lei, Y.

    2004-01-01

    Systematic detailed non-linear finite element (FE) analyses are described for semi-elliptical surface cracks in plates under tension. Limit load solutions are obtained from the FE J results through the reference stress method. The results show that the type of the relationship between J and the limit load mainly depends on the ratio a/t, where a is the crack depth and t the thickness of the plate. For a/t≤0.5, J for any position along the crack front can be predicted by the reference stress method using a single limit load value, except for the points very close to the plate surface. For a/t=0.8, J can only be approximately estimated because no single limit load value can be found to satisfy all the FE J solutions along the crack front. However, for all cases considered, the maximum J value along the crack front can still be predicted by using the global limit load in the reference stress method. The limit load data obtained from this work can be well predicted by a global limit load equation developed by Goodall and Webster

  3. Surface tensions of multi-component mixed inorganic/organic aqueous systems of atmospheric significance: measurements, model predictions and importance for cloud activation predictions

    Directory of Open Access Journals (Sweden)

    D. O. Topping

    2007-01-01

    Full Text Available In order to predict the physical properties of aerosol particles, it is necessary to adequately capture the behaviour of the ubiquitous complex organic components. One of the key properties which may affect this behaviour is the contribution of the organic components to the surface tension of aqueous particles in the moist atmosphere. Whilst the qualitative effect of organic compounds on solution surface tensions has been widely reported, our quantitative understanding on mixed organic and mixed inorganic/organic systems is limited. Furthermore, it is unclear whether models that exist in the literature can reproduce the surface tension variability for binary and higher order multi-component organic and mixed inorganic/organic systems of atmospheric significance. The current study aims to resolve both issues to some extent. Surface tensions of single and multiple solute aqueous solutions were measured and compared with predictions from a number of model treatments. On comparison with binary organic systems, two predictive models found in the literature provided a range of values resulting from sensitivity to calculations of pure component surface tensions. Results indicate that a fitted model can capture the variability of the measured data very well, producing the lowest average percentage deviation for all compounds studied. The performance of the other models varies with compound and choice of model parameters. The behaviour of ternary mixed inorganic/organic systems was unreliably captured by using a predictive scheme and this was dependent on the composition of the solutes present. For more atmospherically representative higher order systems, entirely predictive schemes performed poorly. It was found that use of the binary data in a relatively simple mixing rule, or modification of an existing thermodynamic model with parameters derived from binary data, was able to accurately capture the surface tension variation with concentration. Thus

  4. Group contribution and parachor analysis of experimental data on densities and surface tension for six ionic liquids with the [PF6] anion

    Czech Academy of Sciences Publication Activity Database

    Klomfar, Jaroslav; Součková, Monika; Pátek, Jaroslav

    2015-01-01

    Roč. 385, January (2015), s. 62-71 ISSN 0378-3812 R&D Projects: GA ČR GA13-00145S Institutional support: RVO:61388998 Keywords : ionic liquid * density * surface tension * odd-even effect Subject RIV: BJ - Thermodynamics Impact factor: 1.846, year: 2015

  5. Surface tension-induced PDMS micro-pillars with controllable tips and tilt angles

    KAUST Repository

    Li, Huawei; Fan, Yiqiang; Conchouso Gonzalez, David; Foulds, Ian G.

    2013-01-01

    This paper reports a novel method to fabricate three-dimensional (3D) polydimethylsiloxane (PDMS) micro-pillars using a CO2 laser-machined poly(methyl methacrylate) (PMMA) mold with through-holes. This method eliminates the requirements of expensive and complicated facilities to fabricate a 3D mold. The micro-pillars were formed by the capillary force that draws PDMS into the through-holes of the PMMA mold. The tilt angles of the micro-pillars depend on the tilt angles of the through-holes in the mold, and the concave and convex micro-lens tip shapes of the PDMS micro-pillars can be modified by changing the surface wettability of the PMMA through-holes.

  6. Surface tension-induced PDMS micro-pillars with controllable tips and tilt angles

    KAUST Repository

    Li, Huawei

    2013-12-21

    This paper reports a novel method to fabricate three-dimensional (3D) polydimethylsiloxane (PDMS) micro-pillars using a CO2 laser-machined poly(methyl methacrylate) (PMMA) mold with through-holes. This method eliminates the requirements of expensive and complicated facilities to fabricate a 3D mold. The micro-pillars were formed by the capillary force that draws PDMS into the through-holes of the PMMA mold. The tilt angles of the micro-pillars depend on the tilt angles of the through-holes in the mold, and the concave and convex micro-lens tip shapes of the PDMS micro-pillars can be modified by changing the surface wettability of the PMMA through-holes.

  7. Dynamical behavior of surface tension on rotating fluids in low and microgravity environments

    Science.gov (United States)

    Hung, R. J.; Tsao, Y. D.; Hong, B. B.; Leslie, F. W.

    1989-01-01

    Consideration is given to the time-dependent evolutions of the free surface profile (bubble shapes) of a cylindrical container, partially filled with a Newtonian fluid of constant density, rotating about its axis of symmetry in low and microgravity environments. The dynamics of the bubble shapes are calculated for four cases: linear time-dependent functions of spin-up and spin-down in low and microgravity, linear time-dependent functions of increasing and decreasing gravity at high and low rotating cylinder speeds, time-dependent step functions of spin-up and spin-down in low gravity, and sinusoidal function oscillation of the gravity environment in high and low rotating cylinder speeds. It is shown that the computer algorithms developed by Hung et al. (1988) may be used to simulate the profile of time-dependent bubble shapes under variations of centrifugal, capillary, and gravity forces.

  8. Experimental study of gas entrainment from surface swirl

    Energy Technology Data Exchange (ETDEWEB)

    Moudjed, B., E-mail: brahim.moudjed@cea.fr; Excoffon, J.; Riva, R.; Rossi, L., E-mail: lionel.rossi@cea.fr

    2016-12-15

    Gas entrainment from surface swirls is characterized using water experiments. A free surface shear flow is generated in an open channel flow. A suction nozzle is set at the bottom of the test section to induce a downward flow and provoke gas entrainment. An important originality of these experiments is the possibility to change the inlet condition so as to generate different turbulent shear flows. This is done by adding obstacles of different sizes and shapes at the end of a flat plate separating the inlet flow from a “stagnant” water area. Velocity fields and profiles, measured with the PIV technique, are provided both to describe the inlet conditions corresponding to various geometries and flow rates, and to characterize the temporal average shear flow generated within the centre part of the channel. Gas entrainment mappings are established from direct observations of the different flow configurations. These new results show that the threshold for the suction velocities required to entrain gas are similar for the configurations with small obstacles and the flat plate configuration triggering a standard shear flow. Increasing the size of the obstacles promotes gas entrainment and reduces the threshold values of the suction velocity to trigger gas entrainment. Shadowgraphy with image processing is used to present new results characterizing the geometrical properties of surface swirls and the quantity of gas entrained. Inlet configurations with obstacles generate larger surface swirls which move upstream from the suction nozzle centre whereas they are situated downstream with the flat plate configuration. Moreover, dimensionless power laws are found to be good approximations for the surface swirl width and the quantity of gas entrained. In addition to provide new insights about gas entrainment in analytical configurations relevant to Sodium cooled fast nuclear reactor, these results should provide different test cases for the validation of MCFD codes.

  9. Effect of different dosages of nitroglycerin infusion on arterial blood gas tensions in patients undergoing on- pump coronary artery bypass graft surgery.

    Science.gov (United States)

    Masoumi, Gholamreza; Pour, Evaz Hidar; Sadeghpour, Ali; Ziayeefard, Mohsen; Alavi, Mostapha; Anbardan, Sanam Javid; Shirani, Shahin

    2012-02-01

    On-pump coronary artery bypass graft (CABG) surgery impairs gas exchange in the early postoperative period. The main object on this study was evaluation of changes in arterial blood gas values in patients underwent on pump CABG surgery receiving different dose of intravenous nitroglycerin (NTG). sixty-seven consecutive patients undergoing elective on-pump CABG randomly enrolled into three groups receiving NTG 50 μg/min (Group N1, n =67), 100 μg/min (Group N2, n = 67), and 150 μg/min (Group N3, n = 67). Arterial blood gas (ABG) tensions were evaluated just before induction of anesthesia, during anesthesia, at the end of warming up period, and 6 h after admission to the intensive care unit. Pao2 and PH had the highest value during surgery in Group N1, Group N2, and Group N3. No significant difference was noted in mean values of Pao2 and PH during surgery between three groups (P > 0.05). There was no significant difference in HCO3 values in different time intervals among three groups (P > 0.05). our results showed that infusing three different dosage of NTG (50, 100, and 150 μg/min) had no significant effect on ABG tensions in patients underwent on-pump CABG surgery.

  10. Investigation of wettability to evaluate the morphology and surface tension wood filler

    Directory of Open Access Journals (Sweden)

    S. T. Antipov

    2017-01-01

    Full Text Available In this paper, we propose a new scheme of a highly efficient line for preparing safflower grains for processing consisting of an air-sieve separator, a magnetic separator, an ovary, a puppet, and a stone picker. The new after vortex separator is a vibroseparator for separating the products close in physical properties, grinding Machine with a duo-aspirator, a photoseparator and a device for moisture-thermal treatment. Advantages of the proposed line for preparation of safflower grain for processing are that an additional plant in front of the photocarerator of the grinding machine and duo-espirator allows the crest to separate and remove or refine the shell of the seed in the form of a shell layer for more efficient subsequent spectral point analysis, which determines the grain composition for the purpose of sorting it On the basis of chemical composition and color in the photo separator, and sequential placement after the stone separator of a vibro separator for separation of products close in physical properties, a grinding machine with a duo-aspirator, a photoseparator and a device for moisture-thermal treatment, provides an intensification of the technological process of efficient separation of safflower from impurities and its preparation for further processing and Due to the rational layout of equipment.A highly efficient photocell separator is also provided, the advantages of which are that the installation of a storage and vibrating feeder in relation to the slanting tray from the back side and the execution of a smooth curved transition to the vibrating feeder in the upper part of the pitcher allows improving the separation of grain products by reducing the amplitude of grain oscillations, Caused by a rebound from the surface of the tray during the loading of the sorted material from the vibrating feeder.

  11. Electron transfer in gas surface collisions

    International Nuclear Information System (INIS)

    Wunnik, J.N.M. van.

    1983-01-01

    In this thesis electron transfer between atoms and metal surfaces in general is discussed and the negative ionization of hydrogen by scattering protons at a cesiated crystalline tungsten (110) surface in particular. Experimental results and a novel theoretical analysis are presented. In Chapter I a theoretical overview of resonant electron transitions between atoms and metals is given. In the first part of chapter II atom-metal electron transitions at a fixed atom-metal distance are described on the basis of a model developed by Gadzuk. In the second part the influence of the motion of the atom on the atomic charge state is incorporated. Measurements presented in chapter III show a strong dependence of the fraction of negatively charged H atoms scattered at cesiated tungsten, on the normal as well as the parallel velocity component. In chapter IV the proposed mechanism for the parallel velocity effect is incorporated in the amplitude method. The scattering process of protons incident under grazing angles on a cesium covered surface is studied in chapter V. (Auth.)

  12. Facile and rapid DNA extraction and purification from food matrices using IFAST (immiscible filtration assisted by surface tension).

    Science.gov (United States)

    Strotman, Lindsay N; Lin, Guangyun; Berry, Scott M; Johnson, Eric A; Beebe, David J

    2012-09-07

    Extraction and purification of DNA is a prerequisite to detection and analytical techniques. While DNA sample preparation methods have improved over the last few decades, current methods are still time consuming and labor intensive. Here we demonstrate a technology termed IFAST (Immiscible Filtration Assisted by Surface Tension), that relies on immiscible phase filtration to reduce the time and effort required to purify DNA. IFAST replaces the multiple wash and centrifugation steps required by traditional DNA sample preparation methods with a single step. To operate, DNA from lysed cells is bound to paramagnetic particles (PMPs) and drawn through an immiscible fluid phase barrier (i.e. oil) by an external handheld magnet. Purified DNA is then eluted from the PMPs. Here, detection of Clostridium botulinum type A (BoNT/A) in food matrices (milk, orange juice), a bioterrorism concern, was used as a model system to establish IFAST's utility in detection assays. Data validated that the DNA purified by IFAST was functional as a qPCR template to amplify the bont/A gene. The sensitivity limit of IFAST was comparable to the commercially available Invitrogen ChargeSwitch® method. Notably, pathogen detection via IFAST required only 8.5 μL of sample and was accomplished in five-fold less time. The simplicity, rapidity and portability of IFAST offer significant advantages when compared to existing DNA sample preparation methods.

  13. Modelling of hot surface ignition within gas turbines subject to flammable gas in the intake

    DEFF Research Database (Denmark)

    Pedersen, Lea Duedahl; Nielsen, Kenny Krogh; Yin, Chungen

    2017-01-01

    Controlling risks associated with fires and explosions from leaks of flammable fluids at oil and gas facilities is paramount to ensuring safe operations. The gas turbine is a significant potential source of ignition; however, the residual risk is still not adequately understood. A model has been...... but decreases with increase in initial mixture temperature and pressure. The model shows a great potential in reliable prediction of the risk of hot surface ignition within gas turbines in the oil and gas industry. In the future, a dedicated experimental study will be performed not only to improve...

  14. Soil and gas and radon entry potentials for substructure surfaces

    International Nuclear Information System (INIS)

    Harrison, J.; Sextro, R.G.

    1990-01-01

    This paper reports on measurement techniques and parameters that describe the potential for areas of a building substructure to have high soil gas and radon entry rates which have been developed. Flows and pressures measured at test holes in substructure surfaces while the substructure was intentionally depressurized were used in a highly simplified electrical circuit to model the substructure/soil network. Data from four New Jersey houses indicate that the soil was a factor of two to six times more resistant to soil gas flow than substructure surfaces, concrete slab floors, including perimeter gaps, cracks, and other penetrations, were approximately five times more resistant to soil gas movement than hollow block walls, and radon entry potentials were highest for slab floors. These indices of entry potential may be useful for characterizing the relative leakiness of below-grade substructure surfaces and for determining the selection and placement of radon control systems

  15. Vacuum surface flashover and high pressure gas streamers

    International Nuclear Information System (INIS)

    Elizondo, J.M.; Krogh, M.L.; Smith, D.; Stolz, D.; Wright, S.N.

    1997-07-01

    Pre-breakdown current traces obtained during high pressure gas breakdown and vacuum surface flashover show similar signatures. The initial pre-breakdown current spike, a flat constant current phase, and the breakdown phase with voltage collapse and current surge differ mostly in magnitude. Given these similarities, a model, consisting of the initial current spike corresponding to a fast precursor streamer (ionization wave led by a photoionizing front), the flat current stage as the heating or glow phase, and the terminal avalanche and gap closure, is applied to vacuum surface flashover. A simple analytical approximation based on the resistivity changes induced in the vacuum and dielectric surface is presented. The approximation yields an excellent fit to pre-breakdown time delay vs applied field for previously published experimental data. A detailed kinetics model that includes surface and gas contributions is being developed based in the initial approximation

  16. Free surface flow under gravity and surface tension due to an applied pressure distribution: i Bond number greater than one-third

    Energy Technology Data Exchange (ETDEWEB)

    Maleewong, Montri; Asavanant, Jack [Chulalongkorn University, Department of Mathematics and Advanced Virtual Intelligence Computing Center, Bangkok (Thailand); Grimshaw, Roger [Loughborough University, Department of Mathematical Sciences, Loughborough (United Kingdom)

    2005-08-01

    We consider steady free surface two-dimensional flow due to a localized applied pressure distribution under the effects of both gravity and surface tension in water of constant depth, and in the presence of a uniform stream. The fluid is assumed to be inviscid and incompressible, and the flow is irrotational. The behavior of the forced nonlinear waves is characterized by three parameters: the Froude number, F, the Bond number, {tau}>1/3, and the magnitude and sign of the pressure forcing parameter {epsilon}. The fully nonlinear wave problem is solved numerically by using a boundary integral method. For small amplitude waves and F<1 but not too close to 1, linear theory gives a good prediction for the numerical solution of the nonlinear problem in the case of bifurcation from the uniform flow. As F approaches 1, the nonlinear terms need to be taken account of. In this case the forced Korteweg-de Vries equation is found to be an appropriate model to describe bifurcations from an unforced solitary wave. In general, it is found that for given values of F<1 and {tau}>1/3, there exists both elevation and depression waves. In some cases, a limiting configuration in the form of a trapped bubble occurs in the depression wave solutions. (orig.)

  17. Response mechanism for surface acoustic wave gas sensors based on surface-adsorption.

    Science.gov (United States)

    Liu, Jiansheng; Lu, Yanyan

    2014-04-16

    A theoretical model is established to describe the response mechanism of surface acoustic wave (SAW) gas sensors based on physical adsorption on the detector surface. Wohljent's method is utilized to describe the relationship of sensor output (frequency shift of SAW oscillator) and the mass loaded on the detector surface. The Brunauer-Emmett-Teller (BET) formula and its improved form are introduced to depict the adsorption behavior of gas on the detector surface. By combining the two methods, we obtain a theoretical model for the response mechanism of SAW gas sensors. By using a commercial SAW gas chromatography (GC) analyzer, an experiment is performed to measure the frequency shifts caused by different concentration of dimethyl methylphosphonate (DMMP). The parameters in the model are given by fitting the experimental results and the theoretical curve agrees well with the experimental data.

  18. Determination of the Critical Micelle Concentration of Neutral and Ionic Surfactants with Fluorometry, Conductometry, and Surface Tension-A Method Comparison.

    Science.gov (United States)

    Scholz, Norman; Behnke, Thomas; Resch-Genger, Ute

    2018-01-01

    Micelles are of increasing importance as versatile carriers for hydrophobic substances and nanoprobes for a wide range of pharmaceutical, diagnostic, medical, and therapeutic applications. A key parameter indicating the formation and stability of micelles is the critical micelle concentration (CMC). In this respect, we determined the CMC of common anionic, cationic, and non-ionic surfactants fluorometrically using different fluorescent probes and fluorescence parameters for signal detection and compared the results with conductometric and surface tension measurements. Based upon these results, requirements, advantages, and pitfalls of each method are discussed. Our study underlines the versatility of fluorometric methods that do not impose specific requirements on surfactants and are especially suited for the quantification of very low CMC values. Conductivity and surface tension measurements yield smaller uncertainties particularly for high CMC values, yet are more time- and substance consuming and not suitable for every surfactant.

  19. A molecular dynamics investigation of the surface tension of water nanodroplets and a new technique for local pressure determination through density correlation

    Science.gov (United States)

    Leong, Kai-Yang; Wang, Feng

    2018-04-01

    The surface tension of nanoscale droplets of water was studied with molecular dynamics simulations using the BLYPSP-4F water potential. The internal pressure of the droplet was measured using an empirical correlation between the pressure and density, established through a series of bulk simulations performed at pressures from 1 to 1000 bars. Such a procedure allows for reliable determination of internal pressure without the need to calculate the local virial. The surface tension, estimated with the Young-Laplace relation, shows good agreement with the Tolman equation with a Tolman length of -0.48 Å. The interface of a liquid water droplet is shown to be around 1.1-1.3 nm thick depending on radii. The fairly thick interface region puts a lower limit on the size of droplets that still have a bulk-like interior.

  20. Adsorption of gas mixtures on heterogeneous solid surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Jaroniec, M; Rudzinski, W

    1977-01-01

    A review of theoretical studies on the physical adsorption from gas mixtures on heterogeneous solid surfaces, mainly by Jaroniec and coworkers, covers the vector notation used in the calculations; adsorption isotherms for multicomponent gases; the generalized integral equation for adsorption of gas mixtures, its numerical and analytical solutions, applied, (e.g., to interpret the experimental adsorption isotherms of ethane/ethylene on Nuxit-AL); thermodynamic relations, applied, (e.g., to calculating isosteric adsorption heats from experimental parameters for the adsorption of propylene from propane/propylene mixtures on Nuxit-AL); and the derivation and use of a simplified integral equation for describing the adsorption from gas mixtures on heterogeneous surfaces. 75 references.

  1. Bond-selective control of a gas-surface reaction

    Science.gov (United States)

    Killelea, Daniel R.

    The prospect of using light to selectively control chemical reactions has tantalized chemists since the development of the laser. Unfortunately, the realization of laser-directed chemistry is frequently thwarted by the randomization of energy within the molecule through intramolecular vibrational energy distribution (IVR). However, recent results showing vibrational mode-specific reactivity on metal surfaces suggest that IVR may not always be complete for gas-surface reactions. Here, we combine molecular beam techniques and direct laser excitation to characterize the bond-specific reactivity of trideuteromethane on a Ni(111) surface. Our results reveal important details about how vibrational energy is distributed in the reactive molecule. We use a molecular beam to direct state-selected trideuteromethane (CHD 3) molecules onto a nickel single crystal sample and use the results we obtain to describe the flow of vibrational energy in the methane-surface reaction complex. We show that CHD3 molecules initially excited to v=1, J=2, K=0 of the v 1 symmetric C-H stretching mode will dissociate exclusively via C-H cleavage on Ni(111). This result highlights the localization of vibrational energy in the reaction complex, despite the presence of many energy exchange channels with the high state-density surface. We demonstrate, for the first time, highly parallel bond-selective control of a heterogeneously catalyzed reaction. We place our results in the context of recent experiments investigating IVR for molecules in both the gas phase and liquid solutions. If IVR is fast on the reaction timescale, vibrational energy would be randomly distributed throughout the nascent methane-surface reaction complex and vibrational mode-specific behavior would not occur. The short timescale of a direct gas-surface collision may explain how the exchange of energy via IVR is limited to only a small subset of the energetic configurations available to the reaction complex. This framework

  2. Effects of xylazine on acid-base balance and arterial blood-gas tensions in goats under different environmental temperature and humidity conditions

    Directory of Open Access Journals (Sweden)

    E.G.M. Mogoa

    2000-07-01

    Full Text Available The effects of acute exposure to 3 different temperature and humidity conditions on arterial blood-gas and acid-base balance in goats were investigated after intravenous bolus administration of xylazine at a dose of 0.1 mg/kg. Significant (P < 0.05 changes in the variables occurred under all 3 environmental conditions. Decreases in pH, partial pressure of oxygen and oxyhaemoglobin saturation were observed, and the minimum values for oxygen tension and oxyhaemoglobin saturation were observed within 5 min of xylazine administration. The pH decreased to its minimum values between 5 and 15 min. Thereafter, the variables started to return towards baseline, but did not reach baseline values at the end of the 60 min observation period. Increases in the partial pressure of carbon dioxide, total carbon dioxide content, bicarbonate ion concentration, and the actual base excess were observed. The maximum increase in the carbon dioxide tension occurred within 5 min of xylazine administration. The increase in the actual base excess only became significant after 30 min in all 3 environments, and maximal increases were observed at 60 min. There were no significant differences between the variables in the 3 different environments. It was concluded that intravenous xylazine administration in goats resulted in significant changes in arterial blood-gas and acid-base balance that were associated with hypoxaemia and respiratory acidosis, followed by metabolic alkalosis that continued for the duration of the observation period. Acute exposure to different environmental temperature and humidity conditions after xylazine administration did not influence the changes in arterial blood-gas and acid-base balance.

  3. Temperature Dependence of the Surface Tension and Density at 0.1 MPa for 1-Ethyl- and 1-Butyl-3-methylimidazolium Dicyanamide

    Czech Academy of Sciences Publication Activity Database

    Klomfar, Jaroslav; Součková, Monika; Pátek, Jaroslav

    2011-01-01

    Roč. 56, č. 8 (2011), s. 3454-3462 ISSN 0021-9568 R&D Projects: GA ČR GA101/09/0010; GA AV ČR IAA200760701 Institutional research plan: CEZ:AV0Z20760514 Keywords : surface tension * density * dicyanamide * experimental data Subject RIV: BJ - Thermodynamics Impact factor: 1.693, year: 2011 http://pubs.acs.org/doi/abs/10.1021/je200502j

  4. Surface tension and 0.1 MPa densities of imidazolium-, pyridinium-, pyrrolidinium-, and piperidinium-based tris(pentafluoroethyl)trifluorophosphate ionic liquids

    Czech Academy of Sciences Publication Activity Database

    Součková, Monika; Klomfar, Jaroslav; Pátek, Jaroslav

    2012-01-01

    Roč. 333, NOV 15 2012 (2012), s. 38-46 ISSN 0378-3812 R&D Projects: GA ČR GA101/09/0010 Institutional research plan: CEZ:AV0Z20760514 Keywords : ionic liquid * tris(pentafluoroethyl)trifluorophosphate * density * surface tension Subject RIV: BJ - Thermodynamics Impact factor: 2.379, year: 2012 http://www.sciencedirect.com/science/article/pii/S037838121200310X

  5. Surface tension and density for members of four ionic liquid homologous series containing a pyridinium based-cation and the bis(trifluoromethylsulfonyl)imide anion

    Czech Academy of Sciences Publication Activity Database

    Klomfar, Jaroslav; Součková, Monika; Pátek, Jaroslav

    2017-01-01

    Roč. 431, January (2017), s. 24-33 ISSN 0378-3812 R&D Projects: GA ČR GA13-00145S Institutional support: RVO:61388998 Keywords : ionic liquid * pyridinium-based cation * bis(trifluoromethylsulfonyl)imide anion * density-temperature relation * surface tension-temperature relation * recommended property values Subject RIV: BJ - Thermodynamics OBOR OECD: Thermodynamics Impact factor: 2.473, year: 2016

  6. Determination of the enthalpy of vaporization and prediction of surface tension for ionic liquid 1-alkyl-3-methylimidazolium propionate [C(n)mim][Pro](n = 4, 5, 6).

    Science.gov (United States)

    Tong, Jing; Yang, Hong-Xu; Liu, Ru-Jing; Li, Chi; Xia, Li-Xin; Yang, Jia-Zhen

    2014-11-13

    With the use of isothermogravimetrical analysis, the enthalpies of vaporization, Δ(g)lH(o)m(T(av)), at the average temperature, T(av) = 445.65 K, for the ionic liquids (ILs) 1-alkyl-3-methylimidazolium propionate [C(n)mim][Pro](n = 4, 5, 6) were determined. Using Verevkin's method, the difference of heat capacities between the vapor phase and the liquid phase, Δ(g)lC(p)(o)m, for [C(n)mim][Pro](n = 2, 3, 4, 5, 6), were calculated based on the statistical thermodynamics. Therefore, with the use of Δ(g)lC(p)(o)m, the values of Δ(g)lH(o)m(T(av)) were transformed into Δ(g)lH(o)m(298), 126.8, 130.3, and 136.5 for [C(n)mim][Pro](n = 4, 5, 6), respectively. In terms of the new scale of polarity for ILs, the order of the polarity of [C(n)mim][Pro](n = 2, 3, 4, 5, 6) was predicted, that is, the polarity decreases with increasing methylene. A new model of the relationship between the surface tension and the enthalpy of vaporization for aprotic ILs was put forward and used to predict the surface tension for [C(n)mim][Pro](n = 2, 3, 4, 5, 6) and others. The predicted surface tension for the ILs is in good agreement with the experimental one.

  7. The application of computational thermodynamics and a numerical model for the determination of surface tension and Gibbs-Thomson coefficient of aluminum based alloys

    International Nuclear Information System (INIS)

    Jacome, Paulo A.D.; Landim, Mariana C.; Garcia, Amauri; Furtado, Alexandre F.; Ferreira, Ivaldo L.

    2011-01-01

    Highlights: → Surface tension and the Gibbs-Thomson coefficient are computed for Al-based alloys. → Butler's scheme and ThermoCalc are used to compute the thermophysical properties. → Predictive cell/dendrite growth models depend on accurate thermophysical properties. → Mechanical properties can be related to the microstructural cell/dendrite spacing. - Abstract: In this paper, a solution for Butler's formulation is presented permitting the surface tension and the Gibbs-Thomson coefficient of Al-based binary alloys to be determined. The importance of Gibbs-Thomson coefficient for binary alloys is related to the reliability of predictions furnished by predictive cellular and dendritic growth models and of numerical computations of solidification thermal variables, which will be strongly dependent on the thermophysical properties assumed for the calculations. A numerical model based on Powell hybrid algorithm and a finite difference Jacobian approximation was coupled to a specific interface of a computational thermodynamics software in order to assess the excess Gibbs energy of the liquid phase, permitting the surface tension and Gibbs-Thomson coefficient for Al-Fe, Al-Ni, Al-Cu and Al-Si hypoeutectic alloys to be calculated. The computed results are presented as a function of the alloy composition.

  8. The application of computational thermodynamics and a numerical model for the determination of surface tension and Gibbs-Thomson coefficient of aluminum based alloys

    Energy Technology Data Exchange (ETDEWEB)

    Jacome, Paulo A.D.; Landim, Mariana C. [Department of Mechanical Engineering, Fluminense Federal University, Av. dos Trabalhadores, 420-27255-125 Volta Redonda, RJ (Brazil); Garcia, Amauri, E-mail: amaurig@fem.unicamp.br [Department of Materials Engineering, University of Campinas, UNICAMP, PO Box 6122, 13083-970 Campinas, SP (Brazil); Furtado, Alexandre F.; Ferreira, Ivaldo L. [Department of Mechanical Engineering, Fluminense Federal University, Av. dos Trabalhadores, 420-27255-125 Volta Redonda, RJ (Brazil)

    2011-08-20

    Highlights: {yields} Surface tension and the Gibbs-Thomson coefficient are computed for Al-based alloys. {yields} Butler's scheme and ThermoCalc are used to compute the thermophysical properties. {yields} Predictive cell/dendrite growth models depend on accurate thermophysical properties. {yields} Mechanical properties can be related to the microstructural cell/dendrite spacing. - Abstract: In this paper, a solution for Butler's formulation is presented permitting the surface tension and the Gibbs-Thomson coefficient of Al-based binary alloys to be determined. The importance of Gibbs-Thomson coefficient for binary alloys is related to the reliability of predictions furnished by predictive cellular and dendritic growth models and of numerical computations of solidification thermal variables, which will be strongly dependent on the thermophysical properties assumed for the calculations. A numerical model based on Powell hybrid algorithm and a finite difference Jacobian approximation was coupled to a specific interface of a computational thermodynamics software in order to assess the excess Gibbs energy of the liquid phase, permitting the surface tension and Gibbs-Thomson coefficient for Al-Fe, Al-Ni, Al-Cu and Al-Si hypoeutectic alloys to be calculated. The computed results are presented as a function of the alloy composition.

  9. Refined potentials for rare gas atom adsorption on rare gas and alkali-halide surfaces

    Science.gov (United States)

    Wilson, J. W.; Heinbockel, J. H.; Outlaw, R. A.

    1985-01-01

    The utilization of models of interatomic potential for physical interaction to estimate the long range attractive potential for rare gases and ions is discussed. The long range attractive force is calculated in terms of the atomic dispersion properties. A data base of atomic dispersion parameters for rare gas atoms, alkali ion, and halogen ions is applied to the study of the repulsive core; the procedure for evaluating the repulsive core of ion interactions is described. The interaction of rare gas atoms on ideal rare gas solid and alkali-halide surfaces is analyzed; zero coverage absorption potentials are derived.

  10. Erosion of graphite surface exposed to hot supersonic hydrogen gas

    Science.gov (United States)

    Sharma, O. P.

    1972-01-01

    A theoretical model based on laminar boundary layer flow equations was developed to predict the erosion rate of a graphite (AGCarb-101) surface exposed to a hot supersonic stream of hydrogen gas. The supersonic flow in the nozzle outside the boundary layer formed over the surface of the specimen was determined by assuming one-dimensional isentropic conditions. An overall surface reaction rate expression based on experimental studies was used to describe the interaction of hydrogen with graphite. A satisfactory agreement was found between the results of the computation, and the available experimental data. Some shortcomings of the model and further possible improvements are discussed.

  11. Effect of viscosity and surface tension on the growth of Rayleigh-Taylor instability and Richtmyer-Meshkov instability under nonlinear domain

    International Nuclear Information System (INIS)

    Rahul Banerjee; Khan, M.; Mandal, L.K.; Roy, S.; Gupta, M.R.

    2010-01-01

    Complete text of publication follows. The Rayleigh-Taylor (R-T) instability and Richtmyer-Meshkov (R-M) instability are well known problems in the formation of some astrophysical structures such as the supernova remnants in the Eagle and Crab nebula. A core collapse supernova is driven by an externally powerful shock, and strong shocks are the breeding ground of hydrodynamic instability such as Rayleigh-Taylor instability or Richtmyer-Meshkov instability. These instabilities are also important issues in the design of targets for inertial confinement fusion (ICF). In an ICF target, a high density fluid is frequently accelerated by the pressure of a low density fluid and after ablation the density quickly decays. So, small ripples at such an interface will grow. Under potential flow model, the perturbed interface between heavier fluid and lighter fluid form bubble and spike like structures. The bubbles are in the form of columns of lighter fluid interleaved by falling spike of heavy fluid. In this paper, we like to presented the effect of viscosity and surface tension on Rayleigh-Taylor instability and Richtmyer-Meshkov instability under the non-linear Layzer's approach and described the displacement curvature, growth and velocity of the tip of the bubble as well as spike. It is seen that, in absence of surface tension the lowering of the asymptotic velocity of the tip of the bubble which is formed when the lighter fluid penetrates into the denser fluid and thus encounters the viscous drag due to the denser fluid, which depends only on the denser fluid's viscosity coefficient. On the other hand the asymptotic velocity of the tip of the spike formed as the denser fluid penetrates into the lighter fluid is reduced by an amount which depends only on the viscosity coefficient of the lighter fluid and the spike is resisted by the viscous drag due to the lighter fluid. However, in presence of surface tension the asymptotic velocity of the tip of the bubble (spike) and

  12. MCO gas composition for low reactive surface areas

    International Nuclear Information System (INIS)

    Packer, M.J.

    1998-01-01

    This calculation adjusts modeled output (HNF-SD-SNF-TI-040, Rev. 2) by considering lower reactive fuel surface areas and by increasing the input helium backfill overpressure from 0.5 to 1.5 atm (2.5 atm abs) to verify that MCO gas-phase oxygen concentrations can remain below 4 mole % over a 40 year interim period under a worst case condition of zero reactive surface area. Added backfill gas will dilute any gases generated during interim storage and is a strategy within the current design capability. The zero reactive surface area represents a hypothetical worst case example where there is no fuel scrap and/or damaged spent fuel rods in an MCO. Also included is a hypothetical case where only K East fuel exists in an MCO with an added backfill overpressure of 0.5 atm (1.5 atm abs)

  13. Triboelectric Hydrogen Gas Sensor with Pd Functionalized Surface

    Directory of Open Access Journals (Sweden)

    Sung-Ho Shin

    2016-10-01

    Full Text Available Palladium (Pd-based hydrogen (H2 gas sensors have been widely investigated thanks to its fast reaction and high sensitivity to hydrogen. Various sensing mechanisms have been adopted for H2 gas sensors; however, all the sensors must be powered through an external battery. We report here an H2 gas sensor that can detect H2 by measuring the output voltages generated during contact electrification between two friction surfaces. When the H2 sensor, composed of Pd-coated ITO (indium tin oxide and PET (polyethylene Terephthalate film, is exposed to H2, its output voltage is varied in proportion to H2 concentration because the work function (WF of Pd-coated surface changes, altering triboelectric charging behavior. Specifically, the output voltage of the sensor is gradually increased as exposing H2 concentration increases. Reproducible and sensitive sensor response was observed up 1% H2 exposure. The approach introduced here can easily be adopted to development of triboelectric gas sensors detecting other gas species.

  14. Tension headache.

    Science.gov (United States)

    Ziegler, D K

    1978-05-01

    Headache is an extremely common symptom, and many headaches undoubtedly have a relationship to stressful situations. The clear definition, however, of a "tension headache" complex and its differentiation from migraine in some patients is difficult. The problems are in the identification of a specific headache pattern induced by stress or "tension" and the relationship of the symptom to involuntary contraction of neck and scalp muscles. Treatment consists of analgesics and occasionally mild tranquilizers. Psychotherapy consists of reassurance and often other supportive measures, including modification of life styles. Various feedback techniques have been reported of value, but their superiority to suggestion and hypnosis is still problematic.

  15. Gas detection by means of surface plasmon resonance enhanced ellipsometry

    Energy Technology Data Exchange (ETDEWEB)

    Nooke, Alida

    2012-11-01

    This thesis investigated gas sensing by means of surface plasmon resonance enhanced ellipsometry. Surface plasmons were excited in a 40 - 50 nm gold layer by a He-Ne-laser using the Kretschmann configuration, which was arranged on a self-made copper measuring cell. A fixed angle of incidence and the ellipsometric parameter {Delta} as the measured value were used to monitor changes in the gas phase. Different types of gases were investigated: flammable (hydrocarbons and hydrogen), oxidising (oxygen and ozone), toxic (carbon monoxide) and inert (helium and nitrogen). The gas types can be distinguished by their refractive indices, whereas the sensor responds instantly relative to the reference gas with an increase or a decrease in {Delta}. Diluting the analyte gas with a reference gas (nitrogen or air) allowed the detection limits to be determined, these lay in the low % range. The sensor stability was also enhanced as well as the sensitivity by modifying the gold layers with a 3-10 nm additional layer. These additional layers consisted of the inorganic materials TiO{sub 2}, ZrO{sub 2}, MgF{sub 2} and Fe: SnO{sub 2} which were deposited by different coating processes. Surface investigations were made of every utilised layer: scanning electron microscope and atomic force microscope measurements for surface topology and spectroscopic ellipsometry mapping to determine the optical constants and the layer thicknesses. All applied materials protected the gold layer from contaminations and thus prolonged the life span of the sensor. Furthermore, the detection limits were reduced significantly, to the low ppm range. The material Fe: SnO{sub 2} demonstrates a special behaviour in reaction with the toxic gas carbon monoxide: Due to the iron doping, the response to carbon monoxide is extraordinary and concentrations below 1 ppm were detected. In order to approach a future application in industry, the sensor system was adapted to a stainless steel tube. With this measuring

  16. Fission gas detection system

    International Nuclear Information System (INIS)

    Colburn, R.P.

    1984-01-01

    A device for collecting fission gas released by failed fuel rods which device uses a filter adapted to pass coolant but to block passage of fission gas bubbles due to the surface tension of the bubbles. The coolant may be liquid metal. (author)

  17. Modeled heating and surface erosion comparing motile (gas borne) and stationary (surface coating) inert particle additives

    International Nuclear Information System (INIS)

    Buckingham, A.C.; Siekhaus, W.J.

    1982-01-01

    The unsteady, non-similar, chemically reactive, turbulent boundary layer equations are modified for gas plus dispersed solid particle mixtures, for gas phase turbulent combustion reactions and for heterogeneous gas-solid surface erosive reactions. The exterior (ballistic core) edge boundary conditions for the solutions are modified to include dispersed particle influences on core propellant combustion-generated turbulence levels, combustion reactants and products, and reaction-induced, non-isentropic mixture states. The wall surface (in this study it is always steel) is considered either bare or coated with a fixed particle coating which is conceptually non-reactive, insulative, and non-ablative. Two families of solutions are compared. These correspond to: (1) consideration of gas-borne, free-slip, almost spontaneously mobile (motile) solid particle additives which influence the turbulent heat transfer at the uncoated steel surface and, in contrast, (2) consideration of particle-free, gas phase turbulent heat transfer to the insulated surface coated by stationary particles. Significant differences in erosive heat transfer are found in comparing the two families of solutions over a substantial range of interior ballistic flow conditions. The most effective influences on reducing erosive heat transfer appear to favor mobile, gas-borne particle additives

  18. Undulations on the surface of elongated bubbles in confined gas-liquid flows

    Science.gov (United States)

    Magnini, M.; Ferrari, A.; Thome, J. R.; Stone, H. A.

    2017-08-01

    A systematic analysis is presented of the undulations appearing on the surface of long bubbles in confined gas-liquid flows. CFD simulations of the flow are performed with a self-improved version of the open-source solver ESI OpenFOAM (release 2.3.1), for Ca =0.002 -0.1 and Re =0.1 -1000 , where Ca =μ U /σ and Re =2 ρ U R /μ , with μ and ρ being, respectively, the viscosity and density of the liquid, σ the surface tension, U the bubble velocity, and R the tube radius. A model, based on an extension of the classical axisymmetric Bretherton theory, accounting for inertia and for the curvature of the tube's wall, is adopted to better understand the CFD results. The thickness of the liquid film, and the wavelength and decay rate of the undulations extracted from the CFD simulations, agree well with those obtained with the theoretical model. Inertial effects appear when the Weber number of the flow We =Ca Re =O (10-1) and are manifest by a larger number of undulation crests that become evident on the surface of the rear meniscus of the bubble. This study demonstrates that the necessary bubble length for a flat liquid film region to exist between the rear and front menisci rapidly increases above 10 R when Ca >0.01 and the value of the Reynolds number approaches 1000.

  19. Enceladus' near-surface CO2 gas pockets and surface frost deposits

    Science.gov (United States)

    Matson, Dennis L.; Davies, Ashley Gerard; Johnson, Torrence V.; Combe, Jean-Philippe; McCord, Thomas B.; Radebaugh, Jani; Singh, Sandeep

    2018-03-01

    Solid CO2 surface deposits were reported in Enceladus' South Polar Region by Brown et al. (2006). They noted that such volatile deposits are temporary and posited ongoing replenishment. We present a model for this replenishment by expanding on the Matson et al. (2012) model of subsurface heat and chemical transport in Enceladus. Our model explains the distributions of both CO2 frost and complexed CO2 clathrate hydrate as seen in the Cassini Visual and Infrared Mapping Spectrometer (VIMS) data. We trace the journey of CO2 from a subsurface ocean. The ocean-water circulation model of Matson et al. (2012) brings water up to near the surface where gas exsolves to form bubbles. Some of the CO2 bubbles are trapped and form pockets of gas in recesses at the bottom of the uppermost ice layer. When fissures break open these pockets, the CO2 gas is vented. Gas pocket venting is episodic compared to the more or less continuous eruptive plumes, emanating from the "tiger stripes", that are supported by plume chambers. Two styles of gas pocket venting are considered: (1) seeps, and (2) blowouts. The presence of CO2 frost patches suggests that the pocket gas slowly seeped through fractured, cold ice and when some of the gas reached the surface it was cold enough to condense (i.e., T ∼70 to ∼119 K). If the fissure opening is large, a blowout occurs. The rapid escape of gas and drop in pocket pressure causes water in the pocket to boil and create many small aerosol droplets of seawater. These may be carried along by the erupting gas. Electrically charged droplets can couple to the magnetosphere, and be dragged away from Enceladus. Most of the CO2 blowout gas escapes from Enceladus and the remainder is distributed globally. However, CO2 trapped in a clathrate structure does not escape. It is much heavier and slower moving than the CO2 gas. Its motion is ballistic and has an average range of about 17 km. Thus, it contributes to deposits in the vicinity of the vent. Local heat

  20. Noble Gas Surface Flux Simulations And Atmospheric Transport

    Energy Technology Data Exchange (ETDEWEB)

    Carrigan, Charles R. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Sun, Yunwei [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Simpson, Matthew D. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2017-09-30

    Signatures from underground nuclear explosions or UNEs are strongly influenced by the containment regime surrounding them. The degree of gas leakage from the detonation cavity to the surface obviously affects the magnitude of surface fluxes of radioxenon that might be detected during the course of a Comprehensive Test Ban Treaty On-Site Inspection. In turn, the magnitude of surface fluxes will influence the downwind detectability of the radioxenon atmospheric signature from the event. Less obvious is the influence that leakage rates have on the evolution of radioxenon isotopes in the cavity or the downwind radioisotopic measurements that might be made. The objective of this letter report is to summarize our attempt to better understand how containment conditions affect both the detection and interpretation of radioxenon signatures obtained from sampling at the ground surface near an event as well as at greater distances in the atmosphere. In the discussion that follows, we make no attempt to consider other sources of radioactive noble gases such as natural backgrounds or atmospheric contamination and, for simplicity, only focus on detonation-produced radioxenon gases. Summarizing our simulations, they show that the decay of radioxenon isotopes (e.g., Xe-133, Xe-131m, Xe-133m and Xe-135) and their migration to the surface following a UNE means that the possibility of detecting these gases exists within a window of opportunity. In some cases, seeps or venting of detonation gases may allow significant quantities to reach the surface and be released into the atmosphere immediately following a UNE. In other release scenarios – the ones we consider here – hours to days may be required for gases to reach the surface at detectable levels. These release models are most likely more characteristic of “fully contained” events that lack prompt venting, but which still leak gas slowly across the surface for periods of months.

  1. Bead-bead interaction parameters in dissipative particle dynamics: Relation to bead-size, solubility parameter, and surface tension

    Science.gov (United States)

    Maiti, Amitesh; McGrother, Simon

    2004-01-01

    Dissipative particle dynamics (DPD) is a mesoscale modeling method for simulating equilibrium and dynamical properties of polymers in solution. The basic idea has been around for several decades in the form of bead-spring models. A few years ago, Groot and Warren [J. Chem. Phys. 107, 4423 (1997)] established an important link between DPD and the Flory-Huggins χ-parameter theory for polymer solutions. We revisit the Groot-Warren theory and investigate the DPD interaction parameters as a function of bead size. In particular, we show a consistent scheme of computing the interfacial tension in a segregated binary mixture. Results for three systems chosen for illustration are in excellent agreement with experimental results. This opens the door for determining DPD interactions using interfacial tension as a fitting parameter.

  2. A comment on "pH and the surface tension of water" (J. K. Beattie, A. M. Djerdjev, A. Gray-Weale, N. Kallay, J. Lutzenkirchen, T. Preocanin, A. Selmani, J. Colloid Interface Sci. 422 (2014) 54.)

    Czech Academy of Sciences Publication Activity Database

    Jungwirth, Pavel; Tobias, D. J.

    2015-01-01

    Roč. 448, Jun 15 (2015), s. 593 ISSN 0021-9797 Institutional support: RVO:61388963 Keywords : surface tension * Gibbs adsorption equation * hydroxide * water Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.782, year: 2015

  3. Density and surface tension of high-temperature stratifying mixtures of alkali metal bromides and lithium fluoride

    International Nuclear Information System (INIS)

    Rukavishnikova, I.V.; Lokett, V.N.; Burukhin, A.S.; Stepanov, V.P.

    2006-01-01

    The density and interphase tension of molten mixtures of lithium fluoride with potassium, rubidium, and cesium bromides were measured over the temperature range 1120-1320 K in the region of limited mutual solubility by the hydrostatic weighing and meniscus weight methods. The dependences of properties on the size ratio between the mixed ions were determined. The critical order parameters for systems with the predominantly ionic character of interparticle interactions were estimated [ru

  4. Comparison of rheological, mechanical, electrical properties of HDPE filled with BaTiO{sub 3} with different polar surface tension

    Energy Technology Data Exchange (ETDEWEB)

    Su, Jun [Department of Polymer Science and Engineering, College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009 (China); College of Mechanics Engineering, Nanjing Institute of Industry Technology, Nanjing, 210023 (China); Zhang, Jun, E-mail: zhangjun@njtech.edu.cn [Department of Polymer Science and Engineering, College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009 (China)

    2016-12-01

    Graphical abstract: - Highlights: • The non-polar and short vinyl groups can greatly reduce G′ of HDPE composites. • Long chains on BaTiO{sub 3} surface enhance the interaction of BaTiO{sub 3} with HDPE. • Polar amino groups on BaTiO{sub 3} surface raise the interaction of BaTiO{sub 3} with HDPE. • Polar amino groups can boost the dielectric constant of HDPE composites. • The potential use in electronic equipment of the KH550 composites is obtained. - Abstract: In this work, three types of coupling agents: isopropyl trioleic titanate (NDZ105), vinyltriethoxysilane (SG-Si151), 3-aminopropyltriethoxysilane (KH550) were applied to modify the surface tension of Barium titanate (BaTiO{sub 3}) particles. The Fourier transform infrared (FT-IR) spectra confirm the chemical adherence of coupling agents to the particle surface. The long hydrocarbon chains in NDZ105 can cover the particle surface and reduce the polar surface tension of BaTiO{sub 3} from 37.53 mJ/m{sup 2} to 7.51 mJ/m{sup 2}, turning it from hydrophilic to oleophilic properties. The short and non-polar vinyl groups in SG-Si151 does not influence the surface tension of BaTiO{sub 3}, but make BaTiO{sub 3} have both hydrophilic and oleophilic properties. The polar amino in KH550 can keep BaTiO{sub 3} still with hydrophilic properties. It is found that SG-Si151 modified BaTiO{sub 3} has the lowest interaction with HDPE matrix, lowering the storage modulus of HDPE composites to the greatest extent. As for mechanical properties, the polar amino groups in KH550 on BaTiO{sub 3} surface can improve the adhesion of BaTiO{sub 3} with HDPE matrix, which increases the elongation at break of HDPE composites to the greatest extent. In terms of electrical properties, the polar amino groups on surface of BaTiO{sub 3} can boost the dielectric properties of HDPE/BaTiO{sub 3} composites and decrease the volume resistivity of HDPE/BaTiO{sub 3} composites. The aim of this study is to investigate how functional groups

  5. MEASURING PROTOPLANETARY DISK GAS SURFACE DENSITY PROFILES WITH ALMA

    Energy Technology Data Exchange (ETDEWEB)

    Williams, Jonathan P.; McPartland, Conor, E-mail: jpw@ifa.hawaii.edu [Institute for Astronomy, University of Hawaii at Manoa, Honolulu, HI 96822 (United States)

    2016-10-10

    The gas and dust are spatially segregated in protoplanetary disks due to the vertical settling and radial drift of large grains. A fuller accounting of the mass content and distribution in disks therefore requires spectral line observations. We extend the modeling approach presented in Williams and Best to show that gas surface density profiles can be measured from high fidelity {sup 13}CO integrated intensity images. We demonstrate the methodology by fitting ALMA observations of the HD 163296 disk to determine a gas mass, M {sub gas} = 0.048 M {sub ⊙}, and accretion disk characteristic size R {sub c} = 213 au and gradient γ = 0.39. The same parameters match the C{sup 18}O 2–1 image and indicate an abundance ratio [{sup 12}CO]/[C{sup 18}O] of 700 independent of radius. To test how well this methodology can be applied to future line surveys of smaller, lower mass T Tauri disks, we create a large {sup 13}CO 2–1 image library and fit simulated data. For disks with gas masses 3–10 M {sub Jup} at 150 pc, ALMA observations with a resolution of 0.″2–0.″3 and integration times of ∼20 minutes allow reliable estimates of R {sub c} to within about 10 au and γ to within about 0.2. Economic gas imaging surveys are therefore feasible and offer the opportunity to open up a new dimension for studying disk structure and its evolution toward planet formation.

  6. Experiment and analysis of basic phenomena of gas catching by liquid surface. Observation by visualizing vortex structure and gas catching process

    International Nuclear Information System (INIS)

    Kamemoto, Takashi; Nishiyama, Tadao

    1995-01-01

    Since gravity, viscous force, surface tension and so on are related simultaneously to the inertia force of flow, in gas catching phenomena, it is often difficult to grasp exactly its similarity. At the time of designing actual equipment, careful model test is required, and the validity of the evaluation by model test for applying it to actual machines sometimes becomes a problem. In this research, for the purpose of elucidating the essential mechanism of the gas-catching phenomena by vortices, and obtaining the knowledge useful for the probability of the method of evaluating the limit of gas catching, the knowledge obtained so far on the similarity law and model testing method related to the air catching by vortices was put in order, and vortex structure and basic gas-catching process were observed by water flow visualizing experiment, thus the noteworthy flow characteristics for clarifying the essential mechanism of the phenomena were obtained. The main knowledges on the air catching by vortices obtained so far, the experiment of visualizing vortices using water flow and the experimental results are reported. (K.I.)

  7. FORMALDEHYDE GAS INACTIVATION OF BACILLUS ANTHRACIS, BACILLUS SUBTILIS AND GEOBACILLUS STEAROTHERMOPHILUS SPORES ON INDOOR SURFACE MATERIALS.

    Science.gov (United States)

    Research evaluated the decontamination of Bacillus anthracis, Bacillus subtilis, and Geobacillus stearothermophilus spores on indoor surface material using formaldehyde gas. Spores were dried on seven types of indoor surfaces and exposed to 1100 ppm formaldehyde gas for 10 hr. Fo...

  8. A Variational Reduction and the Existence of a Fully Localised Solitary Wave for the Three-Dimensional Water-Wave Problem with Weak Surface Tension

    Science.gov (United States)

    Buffoni, Boris; Groves, Mark D.; Wahlén, Erik

    2018-06-01

    Fully localised solitary waves are travelling-wave solutions of the three- dimensional gravity-capillary water wave problem which decay to zero in every horizontal spatial direction. Their existence has been predicted on the basis of numerical simulations and model equations (in which context they are usually referred to as `lumps'), and a mathematically rigorous existence theory for strong surface tension (Bond number {β} greater than {1/3}) has recently been given. In this article we present an existence theory for the physically more realistic case {0 point of the reduced functional is found by minimising it over its natural constraint set.

  9. Surface Tension of Binary Mixtures Including Polar Components Modeled by the Density Gradient Theory Combined with the PC-SAFT Equation of State

    Czech Academy of Sciences Publication Activity Database

    Vinš, Václav; Planková, Barbora; Hrubý, Jan

    2013-01-01

    Roč. 34, č. 5 (2013), s. 792-812 ISSN 0195-928X R&D Projects: GA AV ČR IAA200760905; GA ČR(CZ) GPP101/11/P046; GA ČR GA101/09/1633 Institutional research plan: CEZ:AV0Z20760514 Institutional support: RVO:61388998 Keywords : chemical polarity * gradient theory * surface tension Subject RIV: BJ - Thermodynamics Impact factor: 0.623, year: 2013 http://www.springerlink.com/openurl.asp?genre=article&id=doi:10.1007/s10765-012-1207-z

  10. Exploring inclusion complexes of ionic liquids with α- and β- cyclodextrin by NMR, IR, mass, density, viscosity, surface tension and conductance study

    Science.gov (United States)

    Barman, Biraj Kumar; Rajbanshi, Biplab; Yasmin, Ananya; Roy, Mahendra Nath

    2018-05-01

    The formation of the host-guest inclusion complexes of ionic liquids namely [BMIm]Cl and [HMIm]Cl with α-CD and β-CD were studied by means of physicochemical and spectroscopic methods. Conductivity and surface tension study were in good agreement with the 1H NMR and FT-IR studies which confirm the formation of the inclusion complexes. The Density and viscosity study also supported the formation of the ICs. Further the stoichiometry was determined 1:1 for each case and the association constants and thermodynamic parameters derived supported the most feasible formation of the [BMIm]Cl- β-CD inclusion complex.

  11. Advanced Gas Tungsten Arc Weld Surfacing Current Status and Application

    Directory of Open Access Journals (Sweden)

    Stephan Egerland

    2015-09-01

    Full Text Available Abstract Gas Shielded Tungsten Arc Welding (GTAW – a process well-known providing highest quality weld results joined though by lower performance. Gas Metal Arc Welding (GMAW is frequently chosen to increase productivity along with broadly accepted quality. Those industry segments, especially required to produce high quality corrosion resistant weld surfacing e.g. applying nickel base filler materials, are regularly in consistent demand to comply with "zero defect" criteria. In this conjunction weld performance limitations are overcome employing advanced 'hot-wire' GTAW systems. This paper, from a Welding Automation perspective, describes the technology of such devices and deals with the current status is this field – namely the application of dual-cathode hot-wire electrode GTAW cladding; considerably broadening achievable limits.

  12. Mineral and surface issues in oil and gas operations

    International Nuclear Information System (INIS)

    Vasseur, P.F.

    1998-01-01

    The Farmers' Advocate Office was created in 1972 to help put Alberta mineral owners on an equal footing with the energy sector. Most mineral owners are at a disadvantage when dealing with the disposition of their minerals because they have little or no knowledge of what they own or what their surface rights are. This paper addresses key features of mineral leasing arrangements in Alberta and explains their potential impact. It also brings to the mineral owner's attention some specific problems and concerns including mineral rights, the lease agreement, signing considerations, length of leases, delayed production payment, drilling rental, royalties, and gas cost allowance. Issues regarding oil and gas production including shut-in wells, off-set clauses , drilling depth, taxes and prepayment for minerals are also discussed from the perspective of a mineral owner

  13. On the theory and computation of surface tension: The elimination of parasitic currents through energy conservation in the second-gradient method

    International Nuclear Information System (INIS)

    Jamet, Didier; Torres, David; Brackbill, J.U.

    2002-01-01

    Errors in the computation of fluid flows with surface tension are examined. These errors cause large parasitic flows when the capillary number is large and have often been attributed to truncation error in underresolved interfacial regions. A study using the second-gradient method reveals that when truncation error is eliminated in the computation of energy exchanges between surface and kinetic energies so that energy is strictly conserved, the parasitic currents are reduced to round-off. The results are based on general thermodynamic arguments and can be used to guide improvements in other methods, such as the continuum-surface-force (CSF) method, which is commonly used with the volume-of-fluid (VOF) method

  14. On the theory and computation of surface tension: The elimination of parasitic currents through energy conservation in the second-gradient method

    CERN Document Server

    Jamet, D; Brackbill, J U

    2002-01-01

    Errors in the computation of fluid flows with surface tension are examined. These errors cause large parasitic flows when the capillary number is large and have often been attributed to truncation error in underresolved interfacial regions. A study using the second-gradient method reveals that when truncation error is eliminated in the computation of energy exchanges between surface and kinetic energies so that energy is strictly conserved, the parasitic currents are reduced to round-off. The results are based on general thermodynamic arguments and can be used to guide improvements in other methods, such as the continuum-surface-force (CSF) method, which is commonly used with the volume-of-fluid (VOF) method.

  15. Gas loading of graphene-quartz surface acoustic wave devices

    Science.gov (United States)

    Whitehead, E. F.; Chick, E. M.; Bandhu, L.; Lawton, L. M.; Nash, G. R.

    2013-08-01

    Graphene was transferred to the propagation path of quartz surface acoustic wave devices and the attenuation due to gas loading of air and argon measured at 70 MHz and 210 MHz and compared to devices with no graphene. Under argon loading, there was no significant difference between the graphene and non-graphene device and the values of measured attenuation agree well with those calculated theoretically. Under air loading, at 210 MHz, there was a significant difference between the non-graphene and graphene devices, with the average value of attenuation obtained with the graphene devices being approximately twice that obtained from the bare quartz devices.

  16. Effect of Al_2O_3 Nanoparticles Additives on the Density, Saturated Vapor Pressure, Surface Tension and Viscosity of Isopropyl Alcohol

    Science.gov (United States)

    Zhelezny, Vitaly; Geller, Vladimir; Semenyuk, Yury; Nikulin, Artem; Lukianov, Nikolai; Lozovsky, Taras; Shymchuk, Mykola

    2018-03-01

    This paper presents results of an experimental study of the density, saturated vapor pressure, surface tension and viscosity of Al_2O_3 nanoparticle colloidal solutions in isopropyl alcohol. Studies of the thermophysical properties of nanofluids were performed at various temperatures and concentrations of Al_2O_3 nanoparticles. The paper gives considerable attention to a turbidimetric analysis of the stability of nanofluid samples. Samples of nanofluids remained stable over the range of parameters of the experiments, ensuring the reliability of the thermophysical property data for the Al_2O_3 nanoparticle colloidal solutions in isopropyl alcohol. The studies show that the addition of Al_2O_3 nanoparticles leads to an increase of the density, saturated vapor pressure and viscosity, as well as a decrease for the surface tension of isopropyl alcohol. The information reported in this paper on the various thermophysical properties for the isopropyl alcohol/Al_2O_3 nanoparticle model system is useful for the development of thermodynamically consistent models for predicting properties of nanofluids and correct modeling of the heat exchange processes.

  17. The Cloud Condensation Nuclei (CCN properties of 2-methyltetrols and C3-C6 polyols from osmolality and surface tension measurements

    Directory of Open Access Journals (Sweden)

    S. Ekström

    2009-02-01

    Full Text Available A significant fraction of the organic material in aerosols is made of highly soluble compounds such as sugars (mono- and polysaccharides and polyols such as the 2-methyltetrols, methylerythritol and methyltreitol. Because of their high solubility these compounds are considered as potentially efficient CCN material. For the 2-methyltetrols, this would have important implications for cloud formation at global scale because they are thought to be produced by the atmospheric oxidation of isoprene. To investigate this question, the complete Köhler curves for C3-C6 polyols and the 2-methyltetrols have been determined experimentally from osmolality and surface tension measurements. Contrary to what was expected, none of these compounds displayed a higher CCN efficiency than organic acids. Their Raoult terms show that this limited CCN efficiency is due to their absence of dissociation in water, this in spite of slight surface-tension effects for the 2-methyltetrols. Thus, compounds such as saccharides and polyols would not contribute more to cloud formation than other organic compounds studied so far. In particular, the presence of 2-methyltetrols in aerosols would not particularly enhance cloud formation in the atmosphere, in contrary to recently suggested.

  18. Adsorção e propriedades de volume de misturas binárias água álcool: um experimento didático com base em medidas de tensão superficial An undergraduate experiment in physical chemistry: adsorption and bulk properties of alcohol-water mixtures based on surface tension measurements

    Directory of Open Access Journals (Sweden)

    Michelly C. dos Santos

    2010-01-01

    Full Text Available An undergraduate physical chemistry experiment based on the drop counting method for surface tension measurements is proposed to demonstrate adsorption isotherms of binary aqueous solutions of ethanol, n-propanol, and n-butanol. Excess surface is obtained by the derivative of surface tension taken with respect to alcohol activity, after this activity calculation using van Laar equation. Laboratory class contents are surface tension, excess surface, percolation of hydrogen bonds, micelle, activity, and ideal solution.

  19. Design of pellet surface grooves for fission gas plenum

    International Nuclear Information System (INIS)

    Carter, T.J.; Jones, L.R.; Macici, N.; Miller, G.C.

    1986-01-01

    In the Canada deuterium uranium pressurized heavy water reactor, short (50-cm) Zircaloy-4 clad bundles are fueled on-power. Although internal void volume within the fuel rods is adequate for the present once-through natural uranium cycle, the authors have investigated methods for increasing the internal gas storage volume needed in high-power, high-burnup, experimental ceramic fuels. This present work sought to prove the methodology for design of gas storage volume within the fuel pellets - specifically the use of grooves pressed or machined into the relatively cool pellet/cladding interface. Preanalysis and design of pellet groove shape and volume was accomplished using the TRUMP heat transfer code. Postirradiation examination (PIE) was used to check the initial design and heat transfer assumptions. Fission gas release was found to be higher for the grooved pellet rods than for the comparison rods with hollow or unmodified pellets. This had been expected from the initial TRUMP thermal analyses. The ELESIM fuel modeling code was used to check in-reactor performance, but some modifications were necessary to accommodate the loss of heat transfer surface to the grooves. It was concluded that for plenum design purposes, circumferential pellet grooves could be adequately modeled by the codes TRUMP and ELESIM

  20. Thin concentrator photovoltaic module with micro-solar cells which are mounted by self-align method using surface tension of melted solder

    Science.gov (United States)

    Hayashi, Nobuhiko; Terauchi, Masaharu; Aya, Youichirou; Kanayama, Shutetsu; Nishitani, Hikaru; Nakagawa, Tohru; Takase, Michihiko

    2017-09-01

    We are developing a thin and lightweight CPV module using small size lens system made from poly methyl methacrylate (PMMA) with a short focal length and micro-solar cells to decrease the transporting and the installing costs of CPV systems. In order to achieve high conversion efficiency in CPV modules using micro-solar cells, the micro-solar cells need to be mounted accurately to the irradiated region of the concentrated sunlight. In this study, we have successfully developed self-align method thanks to the surface tension of the melted solder even utilizing commercially available surface-mounting technology (SMT). Solar cells were self-aligned to the specified positions of the circuit board by this self-align method with accuracy within ±10 µm. We actually fabricated CPV modules using this self-align method and demonstrated high conversion efficiency of our CPV module.

  1. Dynamics of gas-surface interactions atomic-level understanding of scattering processes at surfaces

    CERN Document Server

    Díez Muniño, Ricardo

    2013-01-01

    This book gives a representative survey of the state of the art of research on gas-surface interactions. It provides an overview of the current understanding of gas surface dynamics and, in particular, of the reactive and non-reactive processes of atoms and small molecules at surfaces. Leading scientists in the field, both from the theoretical and the experimental sides, write in this book about their most recent advances. Surface science grew as an interdisciplinary research area over the last decades, mostly because of new experimental technologies (ultra-high vacuum, for instance), as well as because of a novel paradigm, the ‘surface science’ approach. The book describes the second transformation which is now taking place pushed by the availability of powerful quantum-mechanical theoretical methods implemented numerically. In the book, experiment and theory progress hand in hand with an unprecedented degree of accuracy and control. The book presents how modern surface science targets the atomic-level u...

  2. Simulated X-ray galaxy clusters at the virial radius: Slopes of the gas density, temperature and surface brightness profiles

    Science.gov (United States)

    Roncarelli, M.; Ettori, S.; Dolag, K.; Moscardini, L.; Borgani, S.; Murante, G.

    2006-12-01

    Using a set of hydrodynamical simulations of nine galaxy clusters with masses in the range 1.5 × 1014 matter of tension between simulated and observed properties, and up to the virial radius and beyond, where present observations are unable to provide any constraints. We have modelled the radial profiles between 0.3R200 and 3R200 with power laws with one index, two indexes and a rolling index. The simulated temperature and [0.5-2] keV surface brightness profiles well reproduce the observed behaviours outside the core. The shape of all these profiles in the radial range considered depends mainly on the activity of the gravitational collapse, with no significant difference among models including extraphysics. The profiles steepen in the outskirts, with the slope of the power-law fit that changes from -2.5 to -3.4 in the gas density, from -0.5 to -1.8 in the gas temperature and from -3.5 to -5.0 in the X-ray soft surface brightness. We predict that the gas density, temperature and [0.5-2] keV surface brightness values at R200 are, on average, 0.05, 0.60, 0.008 times the measured values at 0.3R200. At 2R200, these values decrease by an order of magnitude in the gas density and surface brightness, by a factor of 2 in the temperature, putting stringent limits on the detectable properties of the intracluster-medium (ICM) in the virial regions.

  3. The effect of plate thickness, surface tension and fluid flow on detachment of drops from a plate

    NARCIS (Netherlands)

    Lexmond, A.S.; Geld, van der C.W.M.; Celata, G.P.

    2004-01-01

    The pinch-off of drops from the downstream end of plates is an important re-entrainment mechanism of condensate in compact condensers. The present experimental study complements a previous one [1], in which ethanol and water drops were created for various mass densities and gas velocities at the

  4. Rarefaction effects in gas flows over curved surfaces

    Science.gov (United States)

    Dongari, Nishanth; White, Craig; Scanlon, Thomas J.; Zhang, Yonghao; Reese, Jason M.

    2012-11-01

    The fundamental test case of gas flow between two concentric rotating cylinders is considered in order to investigate rarefaction effects associated with the Knudsen layers over curved surfaces. We carry out direct simulation Monte Carlo simulations covering a wide range of Knudsen numbers and accommodation coefficients, and for various outer-to-inner cylinder radius ratios. Numerical data is compared with classical slip flow theory and a new power-law (PL) wall scaling model. The PL model incorporates Knudsen layer effects in near-wall regions by taking into account the boundary limiting effects on the molecular free paths. The limitations of both theoretical models are explored with respect to rarefaction and curvature effects. Torque and velocity profile comparisons also convey that mere prediction of integral flow parameters does not guarantee the accuracy of a theoretical model, and that it is important to ensure that prediction of the local flowfield is in agreement with simulation data.

  5. Adsorption properties of biologically active derivatives of quaternary ammonium surfactants and their mixtures at aqueous/air interface. I. Equilibrium surface tension, surfactant aggregation and wettability.

    Science.gov (United States)

    Rojewska, Monika; Biadasz, Andrzej; Kotkowiak, Michał; Olejnik, Anna; Rychlik, Joanna; Dudkowiak, Alina; Prochaska, Krystyna

    2013-10-01

    The adsorption properties of surfactant mixtures containing two types of quaternary derivatives of lysosomotropic substances: alkyl N,N-dimethylalaninates methobromides and alkyl N,N-dimethylglycinates methobromides were studied. Quantitative and qualitative description of the adsorption process was carried out on the basis of experimentally obtained equilibrium surface tension isotherms. The results indicated that most of the systems studied revealed synergistic effect both in adsorption and wetting properties. In vitro studies on human cancer cells were undertaken and the data obtained showed that the mixtures suppressed the cancer cells' proliferation more effectively than individual components. Results of preliminary research on the interaction of catanionic mixtures with phospholipids suggested a possibility of a strong penetration of cell membranes by the mixtures investigated. Copyright © 2013 Elsevier B.V. All rights reserved.

  6. Surface Tension Guided Hanging-Drop: Producing Controllable 3D Spheroid of High-Passaged Human Dermal Papilla Cells and Forming Inductive Microtissues for Hair-Follicle Regeneration.

    Science.gov (United States)

    Lin, Bojie; Miao, Yong; Wang, Jin; Fan, Zhexiang; Du, Lijuan; Su, Yongsheng; Liu, Bingcheng; Hu, Zhiqi; Xing, Malcolm

    2016-03-09

    Human dermal papilla (DP) cells have been studied extensively when grown in the conventional monolayer. However, because of great deviation from the real in vivo three-dimensional (3D) environment, these two-dimensional (2D) grown cells tend to lose the hair-inducible capability during passaging. Hence, these 2D caused concerns have motivated the development of novel 3D culture techniques to produce cellular microtissues with suitable mimics. The hanging-drop approach is based on surface tension-based technique and the interaction between surface tension and gravity field that makes a convergence of liquid drops. This study used this technique in a converged drop to form cellular spheroids of dermal papilla cells. It leads to a controllable 3Dspheroid model for scalable fabrication of inductive DP microtissues. The optimal conditions for culturing high-passaged (P8) DP spheroids were determined first. Then, the morphological, histological and functional studies were performed. In addition, expressions of hair-inductive markers including alkaline phosphatase, α-smooth muscle actin and neural cell adhesion molecule were also analyzed by quantitative RT-PCR, immunostaining and immunoblotting. Finally, P8-DP microtissues were coimplanted with newborn mouse epidermal cells (EPCs) into nude mice. Our results indicated that the formation of 3D microtissues not only endowed P8-DP microtissues many similarities to primary DP, but also confer these microtissues an enhanced ability to induce hair-follicle (HF) neogenesis in vivo. This model provides a potential to elucidate the native biology of human DP, and also shows the promising for the controllable and scalable production of inductive DP cells applied in future follicle regeneration.

  7. Improvement of the free-surface tension model in shallow water basin by using in-situ bottom-friction measurements

    Science.gov (United States)

    Alekseenko, Elena; Kuznetsov, Konstantin; Roux, Bernard

    2016-04-01

    Wind stress on the free surface is the main driving force behind the circulation of the upper part of the ocean, which in hydrodynamic models are usually defined in terms of the coefficient of surface tension (Zhang et al., 2009, Davies et al., 2003). Moreover, wave motion impacts local currents and changes sea level, impacts the transport and the stratification of the entire water column. Influence of surface waves at the bottom currents is particularly pronounced in the shallow coastal systems. However, existing methods of parameterization of the surface tension have significant limits, especially in strong wind waves (Young et al., 2001, Jones et al., 2004) due to the difficulties of measuring the characteristics of surface waves in stormy conditions. Thus, the formula for calculating the coefficient of surface tension in our day is the actual problem in modeling fluid dynamics, particularly in the context of strong surface waves. In the hydrodynamic models usually a coefficient of surface tension is calculated once at the beginning of computation as a constant that depends on the averaged wind waves characteristic. Usually cases of strongly nonlinear wind waves are not taken into account, what significantly reduces the accuracy of the calculation of the flow structures and further calculation of the other processes in water basins, such as the spread of suspended matter and pollutants. Thus, wave motion influencing the pressure on the free surface and at the bottom must be considered in hydrodynamic models particularly in shallow coastal systems. A method of reconstruction of a free-surface drag coefficient based on the measured in-situ bottom pressure fluctuations is developed and applied in a three-dimensional hydrodynamic model MARS3D, developed by the French laboratory of IFREMER (IFREMER - French Research Institute for Marine Dynamics). MARS3D solves the Navier-Stokes equations for incompressible fluid in the Boussinesq approximation and with the

  8. The Equilibrium Spreading Tension of Pulmonary Surfactant

    OpenAIRE

    Dagan, Maayan P.; Hall, Stephen B.

    2015-01-01

    Monomolecular films at an air/water interface coexist at the equilibrium spreading tension (γe) with the bulk phase from which they form. For individual phospholipids, γe is single-valued, and separates conditions at which hydrated vesicles adsorb from tensions at which overcompressed monolayers collapse. With pulmonary surfactant, isotherms show that monolayers compressed on the surface of bubbles coexist with the three-dimensional collapsed phase over a range of surface tensions. γe therefo...

  9. A local leaky-box model for the local stellar surface density-gas surface density-gas phase metallicity relation

    Science.gov (United States)

    Zhu, Guangtun Ben; Barrera-Ballesteros, Jorge K.; Heckman, Timothy M.; Zakamska, Nadia L.; Sánchez, Sebastian F.; Yan, Renbin; Brinkmann, Jonathan

    2017-07-01

    We revisit the relation between the stellar surface density, the gas surface density and the gas-phase metallicity of typical disc galaxies in the local Universe with the SDSS-IV/MaNGA survey, using the star formation rate surface density as an indicator for the gas surface density. We show that these three local parameters form a tight relationship, confirming previous works (e.g. by the PINGS and CALIFA surveys), but with a larger sample. We present a new local leaky-box model, assuming star-formation history and chemical evolution is localized except for outflowing materials. We derive closed-form solutions for the evolution of stellar surface density, gas surface density and gas-phase metallicity, and show that these parameters form a tight relation independent of initial gas density and time. We show that, with canonical values of model parameters, this predicted relation match the observed one well. In addition, we briefly describe a pathway to improving the current semi-analytic models of galaxy formation by incorporating the local leaky-box model in the cosmological context, which can potentially explain simultaneously multiple properties of Milky Way-type disc galaxies, such as the size growth and the global stellar mass-gas metallicity relation.

  10. Unexpected finite size effects in interfacial systems: Why bigger is not always better—Increase in uncertainty of surface tension with bulk phase width

    Science.gov (United States)

    Longford, Francis G. J.; Essex, Jonathan W.; Skylaris, Chris-Kriton; Frey, Jeremy G.

    2018-06-01

    We present an unexpected finite size effect affecting interfacial molecular simulations that is proportional to the width-to-surface-area ratio of the bulk phase Ll/A. This finite size effect has a significant impact on the variance of surface tension values calculated using the virial summation method. A theoretical derivation of the origin of the effect is proposed, giving a new insight into the importance of optimising system dimensions in interfacial simulations. We demonstrate the consequences of this finite size effect via a new way to estimate the surface energetic and entropic properties of simulated air-liquid interfaces. Our method is based on macroscopic thermodynamic theory and involves comparing the internal energies of systems with varying dimensions. We present the testing of these methods using simulations of the TIP4P/2005 water forcefield and a Lennard-Jones fluid model of argon. Finally, we provide suggestions of additional situations, in which this finite size effect is expected to be significant, as well as possible ways to avoid its impact.

  11. Silica-Assisted Nucleation of Polymer Foam Cells with Nanoscopic Dimensions : Impact of Particle Size, Line Tension, and Surface Functionality

    NARCIS (Netherlands)

    Liu, Shanqiu; Eijkelenkamp, Rik; Duvigneau, Joost; Vancso, G. Julius

    2017-01-01

    Core-shell nanoparticles consisting of silica as core and surface-grafted poly(dimethylsiloxane) (PDMS) as shell with different diameters were prepared and used as heterogeneous nucleation agents to obtain CO2-blown poly(methyl methacrylate) (PMMA) nanocomposite foams. PDMS was selected as the shell

  12. Surface tension and 0.1 MPa density of 1-alkyl-3-methylimidazolium tetrafluoroborates in a homologous series perspective

    Czech Academy of Sciences Publication Activity Database

    Součková, Monika; Klomfar, Jaroslav; Pátek, Jaroslav

    2016-01-01

    Roč. 100, September (2016), s. 79-88 ISSN 0021-9614 R&D Projects: GA ČR GA13-00145S Institutional support: RVO:61388998 Keywords : 1-Cn-3-methylimidazolium cation * tetrafluoroborate anion * density–temperature relation * surface tension–temperature relation * recommended property values Subject RIV: BJ - Thermodynamics Impact factor: 2.726, year: 2016

  13. Molecular beam photoionization and gas-surface scattering

    International Nuclear Information System (INIS)

    Ceyer, S.T.

    1979-09-01

    The energetics of the ethylene ion-molecule reactions was investigated in more detail than previously possible in two body collision experiments by photoionization of the neutral van der Waals ethylene dimer. The stability of the (C 2 H 4 ) + C 2 H 4 ion-molecule collision complex has been determined to be 18.2 +- 0.5 kcal. The highest potential barriers along the reaction coordinate for decomposition of this collision complex into C 4 H 7 + + H and C 3 H 5 + + CH 3 have been determined to be 0 +- 1.5 and 8.7 +- 1.5 kcal. In a similar manner, the energetics of the solvated ethylene dimer ion was investigated by the photoionization of the ethylene trimer. The absolute proton affinity of NH 3 (203.6 +- 1.3 kcal/mole) and the proton solvation energies by more than one NH 3 have been determined by molecular beam photoionization. In addition, the NH 3 + -NH 3 interaction energy (0.79 +- 0.05 eV) was measured by photoionization of the neutral van der Waals dimer. These experiments have shown that photoionization of van der Waals clusters is a very powerful method of determining the energetics of gas phase proton solvation. The scattering of helium atomic beams from a high Miller index platinum surface that exhibits ordered, periodic steps on the atomic scale to probe the effect of atomic steps on the scattering distribution is explored. Rainbow scattering is observed when the step edges are perpendicular to the incident helium atoms. The design, construction and operation of a beam-surface scattering apparatus are described. The first data obtained in this apparatus are presented and the interesting dynamical aspects of the oxidation of D, D 2 and CO are discussed. 75 references

  14. A systematic study on the influence of nuclear surface tension and temperature upon the parameterization of the fusion dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Gharaei, R.; Hadikhani, A. [Hakim Sabzevari University, Department of Physics, Sciences Faculty, Sabzevar (Iran, Islamic Republic of)

    2017-07-15

    For the first time the influence of the surface energy coefficient γ and temperature T on the parameterization of the fusion barriers is systematically analyzed within the framework of the proximity formalism, namely proximity 1977, proximity 1988 and proximity 2010 models. A total of 114 fusion reactions with the condition 39 ≤ Z{sub 1}Z{sub 2} ≤ 1520 for the charge product of their participant nuclei have been studied. We present γ-dependent and T -dependent pocket formulas which reproduce the theoretical and empirical data of the fusion barrier height and position for our considered reactions with good accuracy. It is shown that the quality of the γ-dependent formula enhances by increasing the strength of the surface energy coefficient. Moreover, the obtained results confirm that imposing the thermal effects improves the agreement between the parameterized and empirical data of the barrier characteristics. (orig.)

  15. Investigation of surface properties of physico-chemically modified natural fibres using inverse gas chromatography

    CSIR Research Space (South Africa)

    Cordeiro, N

    2011-01-01

    Full Text Available Inverse gas chromatography (IGC) is a suitable method to determine surface energy of natural fibres when compared to wetting techniques. In the present study, the surface properties of raw and modified lignocellulosic fibres have been investigated...

  16. Hygroscopic properties of Amazonian biomass burning and European background HULIS and investigation of their effects on surface tension with two models linking H-TDMA to CCNC data

    Directory of Open Access Journals (Sweden)

    E. O. Fors

    2010-06-01

    Full Text Available HUmic-LIke Substances (HULIS have been identified as major contributors to the organic carbon in atmospheric aerosol. The term "HULIS" is used to describe the organic material found in aerosol particles that resembles the humic organic material in rivers and sea water and in soils. In this study, two sets of filter samples from atmospheric aerosols were collected at different sites. One set of samples was collected at the K-puszta rural site in Hungary, about 80 km SE of Budapest, and a second was collected at a site in Rondônia, Amazonia, Brazil, during the Large-Scale Biosphere-Atmosphere Experiment in Amazonia – Smoke Aerosols, Clouds, Rainfall and Climate (LBA-SMOCC biomass burning season experiment. HULIS were extracted from the samples and their hygroscopic properties were studied using a Hygroscopicity Tandem Differential Mobility Analyzer (H-TDMA at relative humidity (RH <100%, and a cloud condensation nucleus counter (CCNC at RH >100%. The H-TDMA measurements were carried out at a dry diameter of 100 nm and for RH ranging from 30 to 98%. At 90% RH the HULIS samples showed diameter growth factors between 1.04 and 1.07, reaching values of 1.4 at 98% RH. The cloud nucleating properties of the two sets of aerosol samples were analysed using two types of thermal static cloud condensation nucleus counters. Two different parameterization models were applied to investigate the potential effect of HULIS surface activity, both yielding similar results. For the K-puszta winter HULIS sample, the surface tension at the point of activation was estimated to be lowered by between 34% (47.7 mN/m and 31% (50.3 mN/m for dry sizes between 50 and 120 nm in comparison to pure water. A moderate lowering was also observed for the entire water soluble aerosol sample, including both organic and inorganic compounds, where the surface tension was decreased by between 2% (71.2 mN/m and 13% (63.3 mN/m.

  17. Intentions of fast noble gas ions with clean and with oxidized monocrystalline copper surfaces

    International Nuclear Information System (INIS)

    Wit, A.G.J. de.

    1979-01-01

    The thesis reports investigations concerning the distorted shape of the energy distribution of scattered noble gas ions, and investigations of angular distributions of these ions where a quantitative interpretation is less hampered by preferential neutralization. Low energy noble gas ion scattering is used to study the interactions between oxygen gas and Cu(110) surfaces. (Auth.)

  18. Surface tension and 0.1 MPa density data for 1-Cn-3-methylimidazolium iodides with n=3, 4, and 6, validated using a parachor and group contribution model

    Czech Academy of Sciences Publication Activity Database

    Součková, Monika; Klomfar, Jaroslav; Pátek, Jaroslav

    2015-01-01

    Roč. 83, April (2015), s. 52-60 ISSN 0021-9614 R&D Projects: GA ČR GA13-00145S; GA ČR GA101/09/0010 Institutional support: RVO:61388998 Keywords : density * surface tension * 1-alkyl-3-methylimidazolium iodide * group contribution method * parachor Subject RIV: BJ - Thermodynamics Impact factor: 2.196, year: 2015

  19. Surface tension and 0.1 MPa density for members of homologous series of ionic liquids composed of imidazolium-, pyridinium-, and pyrrolidinium-based cations and of cyano-groups containing anions

    Czech Academy of Sciences Publication Activity Database

    Součková, Monika; Klomfar, Jaroslav; Pátek, Jaroslav

    2015-01-01

    Roč. 406, November (2015), s. 181-193 ISSN 0378-3812 R&D Projects: GA ČR GA13-00145S Institutional support: RVO:61388998 Keywords : ionic liquid * surface tension-temperature relation * density -temperature relation * cyano-funcionalized anion Subject RIV: BJ - Thermodynamics Impact factor: 1.846, year: 2015

  20. Oil and gas pipelines with hydrophobic surfaces better equipped to deal with gas hydrate flow assurance issues

    DEFF Research Database (Denmark)

    Perfeldt, Christine Malmos; Sharifi, Hassan; von Solms, Nicolas

    2015-01-01

    Gas hydrate deposition can cause plugging in oil and gas pipelines with resultant flow assurance challenges. Presently, the energy industry uses chemical additives in order to manage hydrate formation, however these chemicals are expensive and may be associated with safety and environmental...... concerns. Here we show the effect of a hydrophobically coated surface on hydrate formation in the presence of an antifreeze protein type I (AFP I) and a biodegradable synthetic polymer (LuvicapBio) in a high pressure crystallizer setup. The hydrophobic surface increased the hydrate induction time...... crystallizer. This indicates that 10 to 14 times less KHI is needed in the presence of a hydrophobically coated surface. These experimental studies suggest that the use of hydrophobic surfaces or pipelines could serve as an alternative or additional flow assurance approach for gas hydration mitigation...

  1. Effect of surface tension on the dynamical behavior of bubble in rotating fluids under low gravity environment

    Science.gov (United States)

    Hung, R. J.; Tsao, Y. D.; Leslie, Fred W.; Hong, B. B.

    1988-01-01

    Time dependent evolutions of the profile of free surface (bubble shapes) for a cylindrical container partially filled with a Newtonian fluid of constant density, rotating about its axis of symmetry, have been studied. Numerical computations of the dynamics of bubble shapes have been carried out with the following situations: (1) linear functions of spin-up and spin-down in low and microgravity environments, (2) linear functions of increasing and decreasing gravity enviroment in high and low rotating cylidner speeds, (3) step functions of spin-up and spin-down in a low gravity environment, and (4) sinusoidal function oscillation of gravity environment in high and low rotating cylinder speeds. The initial condition of bubble profiles was adopted from the steady-state formulations in which the computer algorithms have been developed by Hung and Leslie (1988), and Hung et al. (1988).

  2. Nucleation, growth and transport modelling of helium bubbles under nuclear irradiation in lead–lithium with the self-consistent nucleation theory and surface tension corrections

    International Nuclear Information System (INIS)

    Fradera, J.; Cuesta-López, S.

    2013-01-01

    Highlights: • The work presented in this manuscript provides a reliable computational tool to quantify the He complex phenomena in a HCLL. • A model based on the self-consistent nucleation theory (SCT) is exposed. It includes radiation induced nucleation modelling and surface tension corrections. • Results informed reinforce the necessity of conducting experiments to determine nucleation conditions and bubble transport parameters in LM breeders. • Our findings and model provide a good qualitative insight into the helium nucleation phenomenon in LM systems for fusion technology and can be used to identify key system parameters. -- Abstract: Helium (He) nucleation in liquid metal breeding blankets of a DT fusion reactor may have a significant impact regarding system design, safety and operation. Large He production rates are expected due to tritium (T) fuel self-sufficiency requirement, as both, He and T, are produced at the same rate. Low He solubility, local high concentrations, radiation damage and fluid discontinuities, among other phenomena, may yield the necessary conditions for He nucleation. Hence, He nucleation may have a significant impact on T inventory and may lower the T breeding ratio. A model based on the self-consistent nucleation theory (SCT) with a surface tension curvature correction model has been implemented in OpenFOAM ® CFD code. A modification through a single parameter of the necessary nucleation condition is proposed in order to take into account all the nucleation triggering phenomena, specially radiation induced nucleation. Moreover, the kinetic growth model has been adapted so as to allow for the transition from a critical cluster to a macroscopic bubble with a diffusion growth process. Limitations and capabilities of the models are shown by means of zero-dimensional simulations and sensitivity analyses to key parameters under HCLL breeding unit conditions. Results provide a good qualitative insight into the helium nucleation

  3. Force Field Benchmark of Organic Liquids: Density, Enthalpy of Vaporization, Heat Capacities, Surface Tension, Isothermal Compressibility, Volumetric Expansion Coefficient, and Dielectric Constant.

    Science.gov (United States)

    Caleman, Carl; van Maaren, Paul J; Hong, Minyan; Hub, Jochen S; Costa, Luciano T; van der Spoel, David

    2012-01-10

    The chemical composition of small organic molecules is often very similar to amino acid side chains or the bases in nucleic acids, and hence there is no a priori reason why a molecular mechanics force field could not describe both organic liquids and biomolecules with a single parameter set. Here, we devise a benchmark for force fields in order to test the ability of existing force fields to reproduce some key properties of organic liquids, namely, the density, enthalpy of vaporization, the surface tension, the heat capacity at constant volume and pressure, the isothermal compressibility, the volumetric expansion coefficient, and the static dielectric constant. Well over 1200 experimental measurements were used for comparison to the simulations of 146 organic liquids. Novel polynomial interpolations of the dielectric constant (32 molecules), heat capacity at constant pressure (three molecules), and the isothermal compressibility (53 molecules) as a function of the temperature have been made, based on experimental data, in order to be able to compare simulation results to them. To compute the heat capacities, we applied the two phase thermodynamics method (Lin et al. J. Chem. Phys.2003, 119, 11792), which allows one to compute thermodynamic properties on the basis of the density of states as derived from the velocity autocorrelation function. The method is implemented in a new utility within the GROMACS molecular simulation package, named g_dos, and a detailed exposé of the underlying equations is presented. The purpose of this work is to establish the state of the art of two popular force fields, OPLS/AA (all-atom optimized potential for liquid simulation) and GAFF (generalized Amber force field), to find common bottlenecks, i.e., particularly difficult molecules, and to serve as a reference point for future force field development. To make for a fair playing field, all molecules were evaluated with the same parameter settings, such as thermostats and barostats

  4. Nucleation, growth and transport modelling of helium bubbles under nuclear irradiation in lead–lithium with the self-consistent nucleation theory and surface tension corrections

    Energy Technology Data Exchange (ETDEWEB)

    Fradera, J., E-mail: jfradera@ubu.es; Cuesta-López, S., E-mail: scuesta@ubu.es

    2013-12-15

    Highlights: • The work presented in this manuscript provides a reliable computational tool to quantify the He complex phenomena in a HCLL. • A model based on the self-consistent nucleation theory (SCT) is exposed. It includes radiation induced nucleation modelling and surface tension corrections. • Results informed reinforce the necessity of conducting experiments to determine nucleation conditions and bubble transport parameters in LM breeders. • Our findings and model provide a good qualitative insight into the helium nucleation phenomenon in LM systems for fusion technology and can be used to identify key system parameters. -- Abstract: Helium (He) nucleation in liquid metal breeding blankets of a DT fusion reactor may have a significant impact regarding system design, safety and operation. Large He production rates are expected due to tritium (T) fuel self-sufficiency requirement, as both, He and T, are produced at the same rate. Low He solubility, local high concentrations, radiation damage and fluid discontinuities, among other phenomena, may yield the necessary conditions for He nucleation. Hence, He nucleation may have a significant impact on T inventory and may lower the T breeding ratio. A model based on the self-consistent nucleation theory (SCT) with a surface tension curvature correction model has been implemented in OpenFOAM{sup ®} CFD code. A modification through a single parameter of the necessary nucleation condition is proposed in order to take into account all the nucleation triggering phenomena, specially radiation induced nucleation. Moreover, the kinetic growth model has been adapted so as to allow for the transition from a critical cluster to a macroscopic bubble with a diffusion growth process. Limitations and capabilities of the models are shown by means of zero-dimensional simulations and sensitivity analyses to key parameters under HCLL breeding unit conditions. Results provide a good qualitative insight into the helium

  5. Surface tension of calcium hydroxide associated with different substances Tensão superficial do hidróxido de cálcio associado a diferentes substâncias

    Directory of Open Access Journals (Sweden)

    Carlos Estrela

    2005-06-01

    Full Text Available The purpose of this study was to evaluate the surface tension of calcium hydroxide (CH associated with different substances (deionized distilled water, camphorated paramonochlorophenol, 2% chlorhexidine digluconate, Otosporin, 3% sodium lauryl ether sulphate; Furacin, PMC Furacin using tensiometer. The action of the substances studied on the dentinal structure enhances the property of surface tension. This method consists in the application of force to separate a platinum ring immersed in the substances. Thus, torsion was applied to the screw until the platinum ring separated during substances testing. Considering the methodology applied, the following can be concluded: distilled water alone or associated with CH presented a high surface tension (70.00 and 68.40 dynes/cm; calcium hydroxide in association with anionic detergent showed low surface tension (31.60 dynes/cm; camphorated paramonochlorophenol plus CH presented low surface tension (37.50 dynes/cm; 2% chlorhexidine associated with calcium hydroxide showed high surface tension values (58.00 dynes/cm; Otosporin plus calcium hydroxide showed low surface tension (35.40 dynes/cm; paramonochlorophenol Furacin mixed with calcium hydroxide presented surface tension equal to 45.50 dynes/cm; sodium hypochlorite presented high surface tension (75.00 dynes/cm. Antimicrobial agents more indicated in endodontics, i.e. CH, chlorhexidine and hypochlorite, presented the highest surface tension.Estudou-se a tensão superficial do hidróxido de cálcio associado a diferentes substâncias (água destilada deionizada, paramonoclorofenol canforado, digluconato de clorexidina 2%, Otosporin, sulfato éter lauril sódio 3%, furacin, PMC furacin usando tensiômetro. O modelo experimental consistiu na aplicação de uma força para separar um anel de platina imerso na superfície das substâncias, exercido por um tensiômetro. Considerando a metodologia aplicada, pode-se concluir: a água destilada isolada ou

  6. Numerical investigation on the influence of surface tension and viscous force on the bubble dynamics with a CLSVOF method

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Zhiying; Li, Yikai; Huang, Biao; Gao, Deming [Beijing Institute of Technology, Beijing (China)

    2016-06-15

    We numerically investigated the rising of bubbles in a quiescent liquid layer. The numerical simulation is performed by solving the incompressible, multiphase Navier-Stokes equations via computational code in axisymmetric coordinates using a Coupled level-set and volume-of-fluid (CLSVOF) method. The numerical results show that the CLSVOF method with a novel algebraic relation between F and f for axisymmetric two-phase flows not only can predict the bubble surface accurately, but also overcome the deficiency in preserving volume conservation. The effects of the Reynolds number Re and the Bond number Bo on the bubble deformation and its motion are investigated. The results show that with the increasing of Re (10 < Re < 150), the bubble shape transfers from oblate ellipsoidal cap to toroidal when Bo = 116. With the increasing of Bo (10 < Bo < 700), the bubble shape transfers from oblate ellipsoidal to toroidal when Re = 30. Although the toroidal bubble shapes are reached in these two cases, the transition modes are different. For the case Bo = 116, the bubble front is pierced by an upward jet from the rear of the bubble. While for the case Re = 30, the rear of the bubble is pierced by a downward jet from the front part.

  7. THE INFLUENCE OF AEROSOL GAS-DYNAMIC SUSPENSION CLEANING ON SURFACE OF THE AIRCRAFT PARTS

    Directory of Open Access Journals (Sweden)

    Vitaly D. Hizhko

    2008-02-01

    Full Text Available  The specificity of the surface microgeometry formation under the influence of aerosol gas-dynamic suspension flow was considered. The composition and character of metallic surface layer formation of aircraft parts was investigated. The possibility of surface material composition and properties adjustment changing aerosol gas-dynamic suspension flow parameters was determined. The hypothesis about the possibility of using aerosol gas-dynamic suspension flow to form corrosion-resistant coating on the detail metallic surfaces was set up.

  8. Insights into the interactions among Surfactin, betaines, and PAM: surface tension, small-angle neutron scattering, and small-angle X-ray scattering study.

    Science.gov (United States)

    Xiao, Jingwen; Liu, Fang; Garamus, Vasil M; Almásy, László; Handge, Ulrich A; Willumeit, Regine; Mu, Bozhong; Zou, Aihua

    2014-04-01

    The interactions among neutral polymer polyacrylamide (PAM) and the biosurfactant Surfactin and four betaines, N-dodecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate (SDDAB), N-tetradecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate (STDAB), N-hexadecyl-N,N-dimethyl-3-ammonio-1-propanesulfonate (SHDAB), and N-dodecyl-N,N-dimethyl-2-ammonio-acetate (C12BE), in phosphate buffer solution (PBS) have been studied by surface tension measurements, small-angle neutron scattering (SANS), small-angle X-ray scattering (SAXS), and rheological experiments. It has been confirmed that the length of alkyl chain is a key parameter of interaction between betaines and PAM. Differences in scattering contrast between X-ray and neutrons for surfactants and PAM molecules provide the opportunity to separately follow the changes of structure of PAM and surfactant aggregates. At concentrations of betaines higher than CMC (critical micelle concentration) and C2 (CMC of surfactant with the presence of polymer), spherical micelles are formed in betaines and betaines/PAM solutions. Transition from spherical to rod-like aggregates (micelles) has been observed in solutions of Surfactin and Surfactin/SDDAB (αSurfactin = 0.67 (molar fraction)) with addition of 0.8 wt % of PAM. The conformation change of PAM molecules only can be observed for Surfactin/SDDAB/PAM system. Viscosity values follow the structural changes suggested from scattering measurements i.e., gradually increases for mixtures PAM → Surfactin/PAM → Surfactin/SDDAB/PAM in PBS.

  9. Eletromiograma de superfície durante stress experimental como subsídio no diagnóstico da cefaléia tensional: resultados em 100 casos Surface scalp and neck electromyography with stress as diagnostic criterion in chronic tension headache: results in 100 cases

    Directory of Open Access Journals (Sweden)

    Ceme Ferreira Jordy

    1995-09-01

    Full Text Available Eletromiograma de superfície foi realizado no crânio e pescoço, durante stress provocado por frio, em 100 pacientes sofrendo cefaléia crônica isolada. Os resultados de diagnóstico obtidos com a eletromiografia revelaram erro de 24% a 32% na avaliação clínica da cefaléia tensional segundo os critérios anamnésicos referendados pelo Comitê de Classificação das Cefaléias, da Sociedade Internacional de Cefaléia (1988. A eletromiografia durante stress é proposta como novo critério de diagnóstico da Cefaléia tensional.We report the use of surface scalp and neck electromyography during experimental stress state in a series of 100 out-patients suffering from chronic tension headache. Results revealed a 24% to 32% of diagnostic errors in the diagnostic obtained by routine anamnestic procedures and following the criteria recommended by the Headache Classification Commitee of the International Headache Society (1988. The electromyography with stress is proposed as a new diagnostic criterion for tension headache.

  10. Reactor vessel stud tensioner

    International Nuclear Information System (INIS)

    Malandra, L.J.; Beer, R.W.; Salton, R.B.; Spiegelman, S.R.; Cognevich, M.L.

    1982-01-01

    A quick-acting stud tensioner, for facilitating the loosening or tightening of a stud nut on a reactor vessel stud, has gripper jaws which when the tensioner is lowered into engagement with the upper end of the stud are moved inwards to grip the upper end and which when the tensioner is lifted move outward to release the upper end. (author)

  11. Indium tin oxide surface smoothing by gas cluster ion beam

    CERN Document Server

    Song, J H; Choi, W K

    2002-01-01

    CO sub 2 cluster ions are irradiated at the acceleration voltage of 25 kV to remove hillocks on indium tin oxide (ITO) surfaces and thus to attain highly smooth surfaces. CO sub 2 monomer ions are also bombarded on the ITO surfaces at the same acceleration voltage to compare sputtering phenomena. From the atomic force microscope results, the irradiation of monomer ions makes the hillocks sharper and the surfaces rougher from 1.31 to 1.6 nm in roughness. On the other hand, the irradiation of CO sub 2 cluster ions reduces the height of hillocks and planarize the ITO surfaces as smooth as 0.92 nm in roughness. This discrepancy could be explained by large lateral sputtering yield of the cluster ions and re-deposition of sputtered particles by the impact of the cluster ions on surfaces.

  12. Ion-enhanced gas-surface chemistry: The influence of the mass of the incident ion

    International Nuclear Information System (INIS)

    Gerlach-Meyer, U.; Coburn, J.W.; Kay, E.

    1981-01-01

    There are many examples of situations in which a gas-surface reaction rate is increased when the surface is simultaneously subjected to energetic particle bombardment. There are several possible mechanisms which could be involved in this radiation-enhanced gas-surface chemistry. In this study, the reaction rate of silicon, as determined from the etch yield, is measured during irradiation of the Si surface with 1 keV He + , Ne + , and Ar + ions while the surface is simultaneously subjected to fluxes of XeF 2 or Cl 2 molecules. Etch yields as high as 25 Si atoms/ion are observed for XeF 2 and Ar + on Si. A discussion is presented of the extent to which the results clarify the mechanisms responsible for ion-enhanced gas-surface chemistry. (orig.)

  13. Variation of air--water gas transfer with wind stress and surface viscoelasticity

    OpenAIRE

    Frew, Nelson M.; Bock, Erik J.; McGillis, Wade R.; Karachintsev, Andrey V.; Hara, Tetsu; Münsterer, Thomas; Jähne, Bernd

    1995-01-01

    Previous parameterizations of gas transfer velocity have attempted to cast this quantity as a function of wind speed or wind-stress. This study demonstrates that the presence of a surface film is effective at reducing the gas transfer velocity at constant wind-stress. Gas exchange experiments were performed at WHOI and UH using annular wind-wave tanks of different scales. Systematic variations of wind-stress and surfactant concentration (Triton-X-100) were explored to determ...

  14. Viscosity, surface tension, density and contact angle of selected PbI2, PbCl2 and methylammonium lead halide perovskite solutions used in perovskite solar cells

    Directory of Open Access Journals (Sweden)

    Mohammad-Reza Ahmadian-Yazdi

    2018-02-01

    Full Text Available Perovskite solar cells (PSCs are currently under vigorous research and development, owing to their compelling power conversion efficiencies. PSCs are solution-processed and, therefore, are fabricated using casting and printing methods, such as spin, spray and blade coating. The coating characteristics significantly depend on the physical and rheological properties of the solutions. Thus, due to the scarcity of such properties, in this work, we report the surface tension, viscosity, density, and contact angle of selected methylammonium lead halide perovskite solutions, in order to gain insight into the behavior of the perovskite solutions and the range of such physical properties. The contact angles were measured on PEDOT:PSS and compact TiO2 (c-TiO2 substrates, commonly used as the underneath layers of the perovskite film. In total, 12 solutions of CH3NH3PbI3 and CH3NH3PbI3-xClx dissolved in common solvents, as well as solutions of PbI2, PbCl2, and CH3NH3I were tested. Among the results, it is shown that the tested perovskite solutions are Newtonian, the apparent contact angles on the mesoporous TiO2 (m-TiO2 are close to zero, on the PEDOT:PSS are around 10°, and on the c-TiO2 are around 30°. Also, contact angle hysteresis is observed in the case of the c-TiO2 substrates. Representative impact dynamics and spreading of perovskite solution droplets are also studied, to demonstrate the importance of the solution properties and process parameters on the coating process.

  15. Viscosity, surface tension, density and contact angle of selected PbI2, PbCl2 and methylammonium lead halide perovskite solutions used in perovskite solar cells

    Science.gov (United States)

    Ahmadian-Yazdi, Mohammad-Reza; Rahimzadeh, Amin; Chouqi, Zineb; Miao, Yihe; Eslamian, Morteza

    2018-02-01

    Perovskite solar cells (PSCs) are currently under vigorous research and development, owing to their compelling power conversion efficiencies. PSCs are solution-processed and, therefore, are fabricated using casting and printing methods, such as spin, spray and blade coating. The coating characteristics significantly depend on the physical and rheological properties of the solutions. Thus, due to the scarcity of such properties, in this work, we report the surface tension, viscosity, density, and contact angle of selected methylammonium lead halide perovskite solutions, in order to gain insight into the behavior of the perovskite solutions and the range of such physical properties. The contact angles were measured on PEDOT:PSS and compact TiO2 (c-TiO2) substrates, commonly used as the underneath layers of the perovskite film. In total, 12 solutions of CH3NH3PbI3 and CH3NH3PbI3-xClx dissolved in common solvents, as well as solutions of PbI2, PbCl2, and CH3NH3I were tested. Among the results, it is shown that the tested perovskite solutions are Newtonian, the apparent contact angles on the mesoporous TiO2 (m-TiO2) are close to zero, on the PEDOT:PSS are around 10°, and on the c-TiO2 are around 30°. Also, contact angle hysteresis is observed in the case of the c-TiO2 substrates. Representative impact dynamics and spreading of perovskite solution droplets are also studied, to demonstrate the importance of the solution properties and process parameters on the coating process.

  16. Preliminary findings of the Viking gas exchange experiment and a model for Martian surface chemistry

    International Nuclear Information System (INIS)

    Oyama, V.I.; Berdahl, B.J.; Carle, G.C.

    1977-01-01

    It is stated that O 2 and CO 2 were evolved from humidified Martian soil in the gas exchange experiment on Viking Lander 1. Small changes in N 2 gas were also recorded. A model of the morphology and a hypothesis of the mechanistics of the Martian surface are proposed. (author)

  17. Synthesis of ZnO nanoparticles for oil-water interfacial tension reduction in enhanced oil recovery

    Science.gov (United States)

    Soleimani, Hassan; Baig, Mirza Khurram; Yahya, Noorhana; Khodapanah, Leila; Sabet, Maziyar; Demiral, Birol M. R.; Burda, Marek

    2018-02-01

    Nanoparticles show potential use in applications associated with upstream oil and gas engineering to increase the performance of numerous methods such as wettability alteration, interfacial tension reduction, thermal conductivity and enhanced oil recovery operations. Surface tension optimization is an important parameter in enhanced oil recovery. Current work focuses on the new economical method of surface tension optimization of ZnO nanofluids for oil-water interfacial tension reduction in enhanced oil recovery. In this paper, zinc oxide (ZnO) nanocrystallites were prepared using the chemical route and explored for enhanced oil recovery (EOR). Adsorption of ZnO nanoparticles (NPs) on calcite (111) surface was investigated using the adsorption locator module of Materials Studio software. It was found that ZnO nanoparticles show maximum adsorption energy of - 253 kcal/mol. The adsorption of ZnO on the rock surface changes the wettability which results in capillary force reduction and consequently increasing EOR. The nanofluids have been prepared by varying the concentration of ZnO nanoparticles to find the optimum value for surface tension. The surface tension (ST) was calculated with different concentration of ZnO nanoparticles using the pendant drop method. The results show a maximum value of ST 35.57 mN/m at 0.3 wt% of ZnO NPs. It was found that the nanofluid with highest surface tension (0.3 wt%) resulted in higher recovery efficiency. The highest recovery factor of 11.82% at 0.3 wt% is due to the oil/water interfacial tension reduction and wettability alteration.

  18. Temperature dependence of the surface tension and 0.1 MPa density for 1-Cn-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate with n=2, 4, and 6

    Czech Academy of Sciences Publication Activity Database

    Součková, Monika; Klomfar, Jaroslav; Pátek, Jaroslav

    2012-01-01

    Roč. 48, MAY 2012 (2012), s. 267-275 ISSN 0021-9614 R&D Projects: GA ČR GA101/09/0010 Institutional research plan: CEZ:AV0Z20760514 Keywords : ionic liquid s * tris(pentafluoroethyl)trifluorophosphate * surface tension * group contribution method * density Subject RIV: BJ - Thermodynamics Impact factor: 2.297, year: 2012 http://www.sciencedirect.com/science/article/pii/S0021961411004770

  19. Low Temperature Densities from (218 to 364) K and up to 50 MPa in Pressure and Surface Tension for Trihexyl(tetradecyl)phosphonium Bis(trifluoromethylsulfonyl)imide and Dicyanamide and 1-Hexyl-3-methylimidazolium Hexafluorophosphate

    Czech Academy of Sciences Publication Activity Database

    Klomfar, Jaroslav; Součková, Monika; Pátek, Jaroslav

    2014-01-01

    Roč. 59, July (2014), s. 2263-2274 ISSN 0021-9568 R&D Projects: GA ČR GA13-00145S; GA ČR GA101/09/0010 Institutional support: RVO:61388998 Keywords : trihexyl(tetradecyl)phosphonium cation * 1-hexyl-3-methylimidazolium hexafluorophosphate * bis(trifluoromethylsulfonyl)imide anion * dicyanamide anion * experimental pvT data * surface tension * internal pressure Subject RIV: BJ - Thermodynamics Impact factor: 2.037, year: 2014

  20. Probing gas-surface interactions with a molecular beam

    International Nuclear Information System (INIS)

    Spruit, M.E.M.

    1988-01-01

    The dynamics of direct scattering, trapping and sticking in molecular beam scattering is probed. The O 2 /Ag interaction was chosen, using the close-packed (111) plane of Ag as target surface. 170 refs.; 22 figs.; 3 tabs

  1. Density, viscosity, surface tension, and molar volume of propylene glycol + water mixtures from 293 to 323 K and correlations by the Jouyban–Acree model

    Directory of Open Access Journals (Sweden)

    Ibrahim S. Khattab

    2017-02-01

    Full Text Available Density, viscosity, surface tension and molar volume of propylene glycol + water mixtures at 293, 298, 303, 308, 313, 318, and 323 K are reported, compared with the available literature data and the Jouyban–Acree model was used for mathematical correlation of the data. The mean relative deviation (MRD was used as an error criterion and the MRD values for data correlation of density, viscosity, surface tension and molar volume at different investigated temperatures are 0.1 ± 0.1%, 7.6 ± 6.4%, 3.4 ± 3.7%, and 0.4 ± 0.4%, respectively. The corresponding MRDs for the predicted properties after training the model using the experimental data at 298 K are 0.1 ± 0.2%, 12.8 ± 9.3%, 4.7 ± 4.1% and 0.6 ± 0.5%, respectively for density, viscosity, surface tension, and molar volume data.

  2. Modification on surface oxide layer structure and surface morphology of niobium by gas cluster ion beam treatments

    International Nuclear Information System (INIS)

    Wu, A.T.; Swenson, D.R.; Insepov, Z.

    2010-01-01

    Recently, it was demonstrated that significant reductions in field emission on Nb surfaces could be achieved by means of a new surface treatment technique called gas cluster ion beam (GCIB). Further study as shown in this paper revealed that GCIB treatments could modify surface irregularities and remove surface asperities leading to a smoother surface finish as demonstrated through measurements using a 3D profilometer, an atomic force microscope, and a scanning electron microscope. These experimental observations were supported by computer simulation via atomistic molecular dynamics and a phenomenological surface dynamics. Measurements employing a secondary ion mass spectrometry found that GCIB could also alter Nb surface oxide layer structure. Possible implications of the experimental results on the performance of Nb superconducting radio frequency cavities treated by GCIB will be discussed. First experimental results on Nb single cell superconducting radio frequency cavities treated by GCIB will be reported.

  3. Studies on Gas Sensing Performance of Pure and Surface Chrominated Indium Oxide Thick Film Resistors

    Directory of Open Access Journals (Sweden)

    D. N. CHAVAN

    2010-12-01

    Full Text Available The thick films of AR grade In2O3 were prepared by standard screen-printing technique. The gas sensing performance of thick film was tested for various gases. It showed maximum gas response to ethanol vapor at 350 oC for 80 ppm. To improve the gas response and selectivity of the film towards a particular gas, In2O3 thick films were modified by dipping them in an aqueous solution of 0.1 M CrO3 for different intervals of time. The surface chrominated (20 min In2O3 thick film showed maximum response to H2S gas (40 ppm than pure In2O3 thick film at 250 oC. Chromium oxide on the surface of the film shifts the gas response from ethanol vapor to H2S gas. A systematic study of sensing performance of the sensor indicates the key role played by chromium oxide on the surface of thick film. The selectivity, gas response and recovery time of the sensor were measured and presented.

  4. On the calculation of the free surface temperature of gas-tungsten-arc weld pools from first principles

    International Nuclear Information System (INIS)

    Choo, R.T.C.; Szekely, J.; David, S.A.

    1992-01-01

    By combining a mathematical model of the welding arc and of the weld pool, calculations are presented here to describe the free surface temperature of weld pools for spot welding operations. The novel aspects of the treatment include the calculation of the heat and current fluxes falling on the free weld pool surface from first principles, a realistic allowance for heat losses due to vaporization, and a realistic allowance for the temperature dependence of the surface tension. The most important finding reported in this article is that the free surface temperature of weld pools appears to be limited by Marangoni convection, rather than heat losses due to vaporization. Furthermore, it was found that once thermocapillary flow can produce high enough surface velocities (>25 cm/s), the precise nature of the relationship between temperature and surface tension will become less important

  5. Laser gas assisted texturing and formation of nitride and oxynitride compounds on alumina surface: Surface response to environmental dust

    Science.gov (United States)

    Yilbas, B. S.; Ali, H.; Al-Sharafi, A.; Al-Aqeeli, N.

    2018-03-01

    Laser gas assisted texturing of alumina surface is carried out, and formation of nitride and oxynitride compounds in the surface vicinity is examined. The laser parameters are selected to create the surface topology consisting of micro/nano pillars with minimum defect sites including micro-cracks, voids and large size cavities. Morphological and hydrophobic characteristics of the textured surface are examined using the analytical tools. The characteristics of the environmental dust and its influence on the laser textured surface are studied while mimicking the local humid air ambient. Adhesion of the dry mud on the laser textured surface is assessed through the measurement of the tangential force, which is required to remove the dry mud from the surface. It is found that laser texturing gives rise to micro/nano pillars topology and the formation of AlN and AlON compounds in the surface vicinity. This, in turn, lowers the free energy of the textured surface and enhances the hydrophobicity of the surface. The liquid solution resulted from the dissolution of alkaline and alkaline earth metals of the dust particles in water condensate forms locally scattered liquid islands at the interface of mud and textured surface. The dried liquid solution at the interface increases the dry mud adhesion on the textured surface. Some dry mud residues remain on the textured surface after the dry mud is removed by a pressurized desalinated water jet.

  6. Exchange energy of inhomogenous electron gas near a metal surface

    International Nuclear Information System (INIS)

    Miglio, L.; Tosi, M.P.; March, N.H.

    1980-12-01

    Using the first-order density matrix of an infinite-barrier model of a metal surface, the exchange energy density can be evaluated exactly as a function of distance z from the barrier. This result is compared with the local approximation -3/4e 2 (3/π)sup(1/3) rhosup(4/3)(z) where rho is the electron density in the model. The local approximation is demonstrated to be quantitatively accurate at all z. The integrated surface exchange energy is given to within 3% by the local theory. (author)

  7. Investigation and optimization of the depth of flue gas heat recovery in surface heat exchangers

    Science.gov (United States)

    Bespalov, V. V.; Bespalov, V. I.; Melnikov, D. V.

    2017-09-01

    Economic issues associated with designing deep flue gas heat recovery units for natural gas-fired boilers are examined. The governing parameter affecting the performance and cost of surface-type condensing heat recovery heat exchangers is the heat transfer surface area. When firing natural gas, the heat recovery depth depends on the flue gas temperature at the condenser outlet and determines the amount of condensed water vapor. The effect of the outlet flue gas temperature in a heat recovery heat exchanger on the additionally recovered heat power is studied. A correlation has been derived enabling one to determine the best heat recovery depth (or the final cooling temperature) maximizing the anticipated reduced annual profit of a power enterprise from implementation of energy-saving measures. Results of optimization are presented for a surface-type condensing gas-air plate heat recovery heat exchanger for the climatic conditions and the economic situation in Tomsk. The predictions demonstrate that it is economically feasible to design similar heat recovery heat exchangers for a flue gas outlet temperature of 10°C. In this case, the payback period for the investment in the heat recovery heat exchanger will be 1.5 years. The effect of various factors on the optimal outlet flue gas temperature was analyzed. Most climatic, economical, or technological factors have a minor effect on the best outlet temperature, which remains between 5 and 20°C when varying the affecting factors. The derived correlation enables us to preliminary estimate the outlet (final) flue gas temperature that should be used in designing the heat transfer surface of a heat recovery heat exchanger for a gas-fired boiler as applied to the specific climatic conditions.

  8. Free-Energy Barrier of Filling a Spherical Cavity in the Presence of Line Tension: Implication to the Energy Barrier between the Cassie and Wenzel States on a Superhydrophobic Surface with Spherical Cavities.

    Science.gov (United States)

    Iwamatsu, Masao

    2016-09-20

    The free-energy barrier of filling a spherical cavity having an inner wall of various wettabilities is studied. The morphology and free energy of a lens-shaped droplet are determined from the minimum of the free energy. The effect of line tension on the free energy is also studied. Then, the equilibrium contact angle of the droplet is determined from the generalized Young's equation. By increasing the droplet volume within the spherical cavity, the droplet morphology changes from spherical with an equilibrium contact angle of 180° to a lens with a convex meniscus, where the morphological complete drying transition occurs. By further increasing the droplet volume, the meniscus changes from convex to concave. Then, the lens-shaped droplet with concave meniscus spreads over the whole inner wall, resulting in an equilibrium contact angle of 0° to leave a spherical bubble, where the morphological complete wetting transition occurs. Finally, the whole cavity is filled with liquid. The free energy shows a barrier from complete drying to complete wetting as a function of droplet volume, which corresponds to the energy barrier between the Cassie and Wenzel states of the superhydrophobic surface with spherical cavities. The free-energy maximum occurs when the meniscus of the droplet becomes flat, and it is given by an analytic formula. The effect of line tension is expressed by the scaled line tension, and this effect is largest at the free-energy maximum. The positive line tension increases the free-energy maximum, which thus increases the stability of the Cassie superhydrophobic state, whereas the negative line tension destabilizes the superhydrophobic state.

  9. Scattering of low energy noble gas ions from a metal surface

    International Nuclear Information System (INIS)

    Luitjens, S.B.

    1980-01-01

    Reflection of low energy (0.1-10 keV) noble gas ions can be used to analyse a solid surface. To study charge exchange processes, the ion fractions of neon and of argon, scattered from a Cu(100) surface, have been determined. (Auth.)

  10. A gas-cooled reactor surface power system

    International Nuclear Information System (INIS)

    Lipinski, R.J.; Wright, S.A.; Lenard, R.X.; Harms, G.A.

    1999-01-01

    A human outpost on Mars requires plentiful power to assure survival of the astronauts. Anywhere from 50 to 500 kW of electric power (kWe) will be needed, depending on the number of astronauts, level of scientific activity, and life-cycle closure desired. This paper describes a 250-kWe power system based on a gas-cooled nuclear reactor with a recuperated closed Brayton cycle conversion system. The design draws upon the extensive data and engineering experience developed under the various high-temperature gas cooled reactor programs and under the SP-100 program. The reactor core is similar in power and size to the research reactors found on numerous university campuses. The fuel is uranium nitride clad in Nb1%Zr, which has been extensively tested under the SP-100 program. The fuel rods are arranged in a hexagonal array within a BeO block. The BeO softens the spectrum, allowing better use of the fuel and stabilizing the geometry against deformation during impact or other loadings. The system has a negative temperature feedback coefficient so that the power level will automatically follow a variable load without the need for continuous adjustment of control elements. Waste heat is removed by an air-cooled heat exchanger using cold Martian air. The amount of radioactivity in the reactor at launch is very small (less than a Curie, and about equal to a truckload of uranium ore). The system will need to be engineered so that criticality can not occur for any launch accident. This system is also adaptable for electric propulsion or life-support during transit to and from Mars. copyright 1999 American Institute of Physics

  11. A gas-cooled reactor surface power system

    International Nuclear Information System (INIS)

    Lipinski, Ronald J.; Wright, Steven A.; Lenard, Roger X.; Harms, Gary A.

    1999-01-01

    A human outpost on Mars requires plentiful power to assure survival of the astronauts. Anywhere from 50 to 500 kW of electric power (kWe) will be needed, depending on the number of astronauts, level of scientific activity, and life-cycle closure desired. This paper describes a 250-kWe power system based on a gas-cooled nuclear reactor with a recuperated closed Brayton cycle conversion system. The design draws upon the extensive data and engineering experience developed under the various high-temperature gas cooled reactor programs and under the SP-100 program. The reactor core is similar in power and size to the research reactors found on numerous university campuses. The fuel is uranium nitride clad in Nb1%Zr, which has been extensively tested under the SP-100 program. The fuel rods are arranged in a hexagonal array within a BeO block. The BeO softens the spectrum, allowing better use of the fuel and stabilizing the geometry against deformation during impact or other loadings. The system has a negative temperature feedback coefficient so that the power level will automatically follow a variable load without the need for continuous adjustment of control elements. Waste heat is removed by an air-cooled heat exchanger using cold Martian air. The amount of radioactivity in the reactor at launch is very small (less than a Curie, and about equal to a truckload of uranium ore). The system will need to be engineered so that criticality can not occur for any launch accident. This system is also adaptable for electric propulsion or life-support during transit to and from Mars

  12. A Gas-Cooled Reactor Surface Power System

    Energy Technology Data Exchange (ETDEWEB)

    Harms, G.A.; Lenard, R.X.; Lipinski, R.J.; Wright, S.A.

    1998-11-09

    A human outpost on Mars requires plentiful power to assure survival of the astronauts. Anywhere from 50 to 500 kW of electric power (kWe) will be needed, depending on the number of astronauts, level of scientific activity, and life- cycle closure desired. This paper describes a 250-kWe power system based on a gas-cooled nuclear reactor with a recuperated closed Brayton cycle conversion system. The design draws upon the extensive data and engineering experience developed under the various high-temperature gas cooled reactor programs and under the SP-100 program. The reactor core is similar in power and size to the research reactors found on numerous university campuses. The fuel is uranium nitide clad in Nb 1 %Zr, which has been extensively tested under the SP-I 00 program The fiel rods are arranged in a hexagonal array within a BeO block. The BeO softens the spectrum, allowing better use of the fbel and stabilizing the geometty against deformation during impact or other loadings. The system has a negative temperature feedback coefficient so that the power level will automatically follow a variable load without the need for continuous adjustment of control elements. Waste heat is removed by an air-cooled heat exchanger using cold Martian air. The amount of radioactivity in the reactor at launch is very small (less than a Curie, and about equal to a truckload of uranium ore). The system will need to be engineered so that criticality cannot occur for any launch accident. This system is also adaptable for electric propulsion or life-support during transit to and from Mars.

  13. Instabilities of a Fermi gas with nested Fermi surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Schlottmann, Pedro [Department of Physics, Florida State University, Tallahassee, FL (United States)

    2018-01-15

    The nesting of the Fermi surfaces of an electron and a hole pocket separated by a vector Q commensurate with the lattice in conjunction with the interaction between the quasiparticles can give rise to a rich phase diagram. Of particular importance is itinerant antiferromagnetic order in the context of pnictides and heavy fermion compounds. By mismatching the nesting the order can gradually be suppressed and as the Neel temperature tends to zero a quantum critical point is obtained. A superconducting dome above the quantum critical point can be induced by the transfer of pairs of electrons between the pockets. The conditions under which such a dome arises are studied. In addition numerous other phases may arise, e.g. charge density waves, non-Fermi liquid behavior, non-s-wave superconductivity, Pomeranchuk instabilities of the Fermi surface, nematic order, and phases with persistent orbital currents. (copyright 2017 by WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  14. Radial Surface Density Profiles of Gas and Dust in the Debris Disk around 49 Ceti

    Energy Technology Data Exchange (ETDEWEB)

    Hughes, A. Meredith; Lieman-Sifry, Jesse; Flaherty, Kevin M.; Daley, Cail M. [Department of Astronomy, Van Vleck Observatory, Wesleyan University, 96 Foss Hill Drive, Middletown, CT 06459 (United States); Roberge, Aki [Exoplanets and Stellar Astrophysics Laboratory, NASA Goddard Space Flight Center, Code 667, Greenbelt, MD 20771 (United States); Kóspál, Ágnes; Moór, Attila; Ábrahám, Peter [Konkoly Observatory, Research Centre for Astronomy and Earth Sciences, Hungarian Academy of Sciences, P.O. Box 67, 1525 Budapest (Hungary); Kamp, Inga [Kapteyn Astronomical Institute, University of Groningen, Postbus 800, 9700 AV Groningen (Netherlands); Wilner, David J.; Andrews, Sean M. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, MS-51, Cambridge, MA 02138 (United States); Kastner, Joel H., E-mail: amhughes@astro.wesleyan.edu [Rochester Institute of Technology, 54 Lomb Memorial Drive, Rochester, NY 14623 (United States)

    2017-04-20

    We present ∼0.″4 resolution images of CO(3–2) and associated continuum emission from the gas-bearing debris disk around the nearby A star 49 Ceti, observed with the Atacama Large Millimeter/Submillimeter Array (ALMA). We analyze the ALMA visibilities in tandem with the broadband spectral energy distribution to measure the radial surface density profiles of dust and gas emission from the system. The dust surface density decreases with radius between ∼100 and 310 au, with a marginally significant enhancement of surface density at a radius of ∼110 au. The SED requires an inner disk of small grains in addition to the outer disk of larger grains resolved by ALMA. The gas disk exhibits a surface density profile that increases with radius, contrary to most previous spatially resolved observations of circumstellar gas disks. While ∼80% of the CO flux is well described by an axisymmetric power-law disk in Keplerian rotation about the central star, residuals at ∼20% of the peak flux exhibit a departure from axisymmetry suggestive of spiral arms or a warp in the gas disk. The radial extent of the gas disk (∼220 au) is smaller than that of the dust disk (∼300 au), consistent with recent observations of other gas-bearing debris disks. While there are so far only three broad debris disks with well characterized radial dust profiles at millimeter wavelengths, 49 Ceti’s disk shows a markedly different structure from two radially resolved gas-poor debris disks, implying that the physical processes generating and sculpting the gas and dust are fundamentally different.

  15. Improved Main Shaft Seal Life in Gas Turbines Using Laser Surface Texturing

    Science.gov (United States)

    McNickle, Alan D.; Etsion, Izhak

    2002-10-01

    This paper presents a general overview of the improved main shaft seal life in gas turbines using laser surface texturing (LST). The contents include: 1) Laser Surface Texturing System; 2) Seal Schematic with LST applied; 3) Dynamic Rig Tests; 4) Surface Finish Definitions; 5) Wear Test Rig; 6) Dynamic Test Rig; 7) Seal Cross Section-Rig Test; and 8) Typical Test Results. This paper is in viewgraph form.

  16. Simulation of gas compressible flow by free surface water flow

    International Nuclear Information System (INIS)

    Altafini, C.R.; Silva Ferreira, R.T. da

    1981-01-01

    The analogy between the water flow with a free surface and the compressible fluid flow, commonly called hydraulic analogy, is analyzed and its limitations are identified. The water table is the equipment used for this simulation, which allows the quatitative analysis of subsonic and supersonic flow with a low cost apparatus. The hydraulic analogy is applied to subsonic flow around circular cylinders and supersonic flow around cones. The results are compared with available theoretical and experimental data and a good agreement is achieved. (Author) [pt

  17. Observation of surface excitons in rare gas solids

    International Nuclear Information System (INIS)

    Saile, V.; Skibowski, M.; Steinmann, W.; Guertler, P.; Koch, E.E.; Kozevnikov, A.

    1976-04-01

    Evidence is obtained for the excitation of surface excitons in solid Ar, Kr and Xe in optical transmission and reflection experiments using synchrotron radiation. They are located at photon energies ranging from 0.6 eV for Ar to 0.1 eV for Xe below the corresponding bulk excitons excited from the valence bands. Their halfwidths (20-50 MeV) is less than half the values found for the bulk excitons. Some are split by an amount considerably smaller than the spin orbit splitting of the valence bands. (orig.) [de

  18. Detection of Volatile Organic Compound Gas Using Localized Surface Plasmon Resonance of Gold Nanoparticles

    International Nuclear Information System (INIS)

    Sri Nengsih; Akrajas Ali Umar; Muhamad Mat Salleh; Muhammad Yahaya

    2011-01-01

    This paper reports on the detection of several organic vapors using the unique characteristic of localized surface plasmon resonance (LSPR) gold nanoparticles. Gold nanoparticles on quartz substrate were prepared using seed mediated growth method. In a typical process, gold nanoparticles with average size ca. 36 nm were obtained to densely grown on the substrate. Detection of gas was based on the change in the LSPR of the gold nanoparticles film upon the exposure to the gas sample. It was found that gold nanoparticles were sensitive to the presence of volatile organic compound (VOC) gas from the change in the surface plasmon resonance (SPR) intensity. The mechanism for the detection of VOCs gas will be discussed. (author)

  19. Gas migration from closed coal mines to the surface. Risk assessment methodology and prevention means

    International Nuclear Information System (INIS)

    Pokryszka, Z.; Tauziede, Ch.; Lagny, C.; Guise, Y.; Gobillot, R.; Planchenault, J.M.; Lagarde, R.

    2005-01-01

    French law as regards renunciation to mining concessions calls for the mining operator to first undertake analyses of the risks represented by their underground mining works. The problem of gas migration to the surface is especially significant in the context of coal mines. This is because mine gas can migrate to the earth's surface, then present significant risks: explosion, suffocation or gas poisoning risks. As part of the scheduled closure of all coal mining operations in France, INERIS has drawn up, at the request of national mining operator Charbonnages de France, a general methodology for assessing the risk linked to gas in the context of closed coal mines. This article presents the principles of this methodology. An application example based on a true case study is then described. This is completed by a presentation of the preventive and monitoring resources recommended and usually applied in order to manage the risk linked to gaseous emissions. (authors)

  20. Natural gas use in treatment of steel surfaces; Utilizacao de gas natural em tratamento de superficies de aco

    Energy Technology Data Exchange (ETDEWEB)

    Ferraz, Andre Dias; Machado, Antonio Rogerio; Rocha, Ivan; Azevedo, Jorge; Oshiro, Hugo K.; Konishi, Ricardo; Lehmkuhl, Willian [Companhia de Gas de Santa Catarina (SCGAS), Florianopolis, SC (Brazil); Piazza, Walter [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2011-12-21

    The surface treatments of metals, such as carburizing, rely on processing under high temperature in carbon rich atmospheres. The atmosphere is industrially generated using the partial oxidation of a carbon rich fuel, such as propane, butane or methanol. This article reports a study of the production of a carburizing atmosphere for surface treatment of steel from the partial oxidation of natural gas in a catalytic reactor. The reactor studied was a production size reactor with 300 mm of diameter and 1500 mm of length, packed with alumina supported nickel catalyst. The quality of the carburizing gas was evaluated from its carbon potential of the carburizing gas that was calculated from the concentrations of carbon monoxide (CO), carbon dioxide (CO{sub 2}), oxygen (O{sub 2}) and methane (CH{sub 4}) measured at the reactor's exit. The results indicate that CO concentration is very close to equilibrium, while CO{sub 2} is higher and CH{sub 4} is lower. Examining the reactor, the conclusion was that there was an axial temperature gradient, resulting in lower residence time under the required processing temperature. This resulted in smaller decomposition of CH{sub 4} and smaller production of CO{sub 2}. An equilibrium calculation of carbon potential, expressed as weight percent of carbon in iron, was developed to predict the possible optimizations of mixture composition and reactor temperature for a given required carbon potential. Conclusion: it is possible to generate a carburizing atmosphere under well controlled and repeatable conditions for the carbon potentials required for surface carburizing of steels in industrial processing using natural gas and air mixtures. (author)

  1. Electron Gas Dynamic Conductivity Tensor on the Nanotube Surface in Magnetic Field

    Directory of Open Access Journals (Sweden)

    A. M. Ermolaev

    2011-01-01

    Full Text Available Kubo formula was derived for the electron gas conductivity tensor on the nanotube surface in longitudinal magnetic field considering spatial and time dispersion. Components of the degenerate and nondegenerate electron gas conductivity tensor were calculated. The study has showed that under high electron density, the conductivity undergoes oscillations of de Haas-van Alphen and Aharonov-Bohm types with the density of electrons and magnetic field changes.

  2. Dominant rate process of silicon surface etching by hydrogen chloride gas

    International Nuclear Information System (INIS)

    Habuka, Hitoshi; Suzuki, Takahiro; Yamamoto, Sunao; Nakamura, Akio; Takeuchi, Takashi; Aihara, Masahiko

    2005-01-01

    Silicon surface etching and its dominant rate process are studied using hydrogen chloride gas in a wide concentration range of 1-100% in ambient hydrogen at atmospheric pressure in a temperature range of 1023-1423 K, linked with the numerical calculation accounting for the transport phenomena and the surface chemical reaction in the entire reactor. The etch rate, the gaseous products and the surface morphology are experimentally evaluated. The dominant rate equation accounting for the first-order successive reactions at silicon surface by hydrogen chloride gas is shown to be valid. The activation energy of the dominant surface process is evaluated to be 1.5 x 10 5 J mol - 1 . The silicon deposition by the gaseous by-product, trichlorosilane, is shown to have a negligible influence on the silicon etch rate

  3. [INVITED] Laser gas assisted treatment of Ti-alloy: Analysis of surface characteristics

    Science.gov (United States)

    Yilbas, B. S.; Ali, H.; Karatas, C.

    2016-04-01

    Laser gas assisted treatment of Ti6Al4V alloy surface is carried out and nitrogen/oxygen mixture with partial pressure of PO2/PN2=1/3 is introduced during the surface treatment process. Analytical tools are used to characterize the laser treated surfaces. The fracture toughness at the surface and the residual stress in the surface region of the laser treated layer are measured. Scratch tests are carried out to determine the friction coefficient of the treated surface. It is found that closely spaced regular laser scanning tracks generates a self-annealing effect in the laser treated layer while lowering the stress levels in the treated region. Introducing high pressure gas mixture impingement at the surface results in formation of oxide and nitride species including, TiO, TiO2, TiN and TiOxNy in the surface region. A dense layer consisting of fine size grains are formed in the surface region of the laser treated layer, which enhances the microhardness at the surface. The fracture toughness reduces after the laser treatment process because of the microhardness enhancement at the surface. The residual stress formed is comprehensive, which is in the order of -350 MPa.

  4. Tension type headache

    Directory of Open Access Journals (Sweden)

    Debashish Chowdhury

    2012-01-01

    Full Text Available Tension type headaches are common in clinical practice. Earlier known by various names, the diagnosis has had psychological connotations. Recent evidence has helped clarify the neurobiological basis and the disorder is increasingly considered more in the preview of neurologists. The classification, clinical features, differential diagnosis and treatment of tension type headache are discussed in this paper.

  5. Tensions in Distributed Leadership

    Science.gov (United States)

    Ho, Jeanne; Ng, David

    2017-01-01

    Purpose: This article proposes the utility of using activity theory as an analytical lens to examine the theoretical construct of distributed leadership, specifically to illuminate tensions encountered by leaders and how they resolved these tensions. Research Method: The study adopted the naturalistic inquiry approach of a case study of an…

  6. Two-phase gas bubble-liquid boundary layer flow along vertical and inclined surfaces

    International Nuclear Information System (INIS)

    Cheung, F.B.; Epstein, M.

    1985-01-01

    The behavior of a two-phase gas bubble liquid boundary layer along vertical and inclined porous surfaces with uniform gas injection is investigated experimentally and analytically. Using argon gas and water as the working fluids, a photographical study of the two-phase boundary layer flow has been performed for various angles of inclination ranging from 45 0 to 135 0 and gas injection rates ranging from 0.01 to 0.1 m/s. An integral method has been employed to solve the system of equations governing the two-phase motion. The effects of the gas injection rate and the angle of inclination on the growth of the boundary layer have been determined

  7. Two-phase gas bubble-liquid boundary layer flow along vertical and inclined surfaces

    International Nuclear Information System (INIS)

    Cheung, F.B.; Epstein, M.

    1985-01-01

    The behavior of a two-phase gas bubble-liquid boundary layer along vertical and inclined porous surfaces with uniform gas injection is investigated experimentally and analytically. Using argon gas and water as the working fluids, a photographical study of the two-phase boundary layer flow has been performed for various angles of inclination ranging from 45 0 to 135 0 and gas injection rates ranging from 0.01 to 0.1 m/s. An integral method has been employed to solve the system of equations governing the two-phase motion. The effects of the gas injection rate and the angle of inclination on the growth of the boundary layer have been determined. The predicted boundary layer thickness is found to be in good agreement with the experimental results. The calculated axial liquid velocity and the void fraction in the two-phase region are also presented along with the observed flow behavior

  8. Mapping of local argon impingement on a virtual surface: an insight for gas injection during FEBID

    Energy Technology Data Exchange (ETDEWEB)

    Wanzenboeck, H.D.; Hochleitner, G.; Mika, J.; Shawrav, M.M.; Gavagnin, M.; Bertagnolli, E. [Vienna University of Technology, Institute for Solid State Electronics, Vienna (Austria)

    2014-12-15

    During the last decades, focused electron beam induced deposition (FEBID) has become a successful approach for direct-write fabrication of nanodevices. Such a deposition technique relies on the precursor supply to the sample surface which is typically accomplished by a gas injection system using a tube-shaped injector nozzle. This precursor injection strategy implies a position-dependent concentration gradient on the surface, which affects the geometry and chemistry of the final nanodeposit. Although simulations already proposed the local distribution of nozzle-borne gas molecules impinging on the surface, this isolated step in the FEBID process has never been experimentally measured yet. This work experimentally investigates the local distribution of impinging gas molecules on the sample plane, isolating the direct impingement component from surface diffusion or precursor depletion by deposition. The experimental setup used in this work maps and quantifies the local impinging rate of argon gas over the sample plane. This setup simulates the identical conditions for a precursor molecule during FEBID. Argon gas was locally collected with a sniffer tube, which is directly connected to a residual gas analyzer for quantification. The measured distribution of impinging gas molecules showed a strong position dependence. Indeed, a 300-μm shift of the deposition area to a position further away from the impingement center spot resulted in a 50 % decrease in the precursor impinging rate on the surface area. With the same parameters, the precursor distribution was also simulated by a Monte Carlo software by Friedli and Utke and showed a good correlation between the empirical and the simulated precursor distribution. The results hereby presented underline the importance of controlling the local precursor flux conditions in order to obtain reproducible and comparable deposition results in FEBID. (orig.)

  9. Mapping of local argon impingement on a virtual surface: an insight for gas injection during FEBID

    International Nuclear Information System (INIS)

    Wanzenboeck, H.D.; Hochleitner, G.; Mika, J.; Shawrav, M.M.; Gavagnin, M.; Bertagnolli, E.

    2014-01-01

    During the last decades, focused electron beam induced deposition (FEBID) has become a successful approach for direct-write fabrication of nanodevices. Such a deposition technique relies on the precursor supply to the sample surface which is typically accomplished by a gas injection system using a tube-shaped injector nozzle. This precursor injection strategy implies a position-dependent concentration gradient on the surface, which affects the geometry and chemistry of the final nanodeposit. Although simulations already proposed the local distribution of nozzle-borne gas molecules impinging on the surface, this isolated step in the FEBID process has never been experimentally measured yet. This work experimentally investigates the local distribution of impinging gas molecules on the sample plane, isolating the direct impingement component from surface diffusion or precursor depletion by deposition. The experimental setup used in this work maps and quantifies the local impinging rate of argon gas over the sample plane. This setup simulates the identical conditions for a precursor molecule during FEBID. Argon gas was locally collected with a sniffer tube, which is directly connected to a residual gas analyzer for quantification. The measured distribution of impinging gas molecules showed a strong position dependence. Indeed, a 300-μm shift of the deposition area to a position further away from the impingement center spot resulted in a 50 % decrease in the precursor impinging rate on the surface area. With the same parameters, the precursor distribution was also simulated by a Monte Carlo software by Friedli and Utke and showed a good correlation between the empirical and the simulated precursor distribution. The results hereby presented underline the importance of controlling the local precursor flux conditions in order to obtain reproducible and comparable deposition results in FEBID. (orig.)

  10. Mapping of local argon impingement on a virtual surface: an insight for gas injection during FEBID

    Science.gov (United States)

    Wanzenboeck, H. D.; Hochleitner, G.; Mika, J.; Shawrav, M. M.; Gavagnin, M.; Bertagnolli, E.

    2014-12-01

    During the last decades, focused electron beam induced deposition (FEBID) has become a successful approach for direct-write fabrication of nanodevices. Such a deposition technique relies on the precursor supply to the sample surface which is typically accomplished by a gas injection system using a tube-shaped injector nozzle. This precursor injection strategy implies a position-dependent concentration gradient on the surface, which affects the geometry and chemistry of the final nanodeposit. Although simulations already proposed the local distribution of nozzle-borne gas molecules impinging on the surface, this isolated step in the FEBID process has never been experimentally measured yet. This work experimentally investigates the local distribution of impinging gas molecules on the sample plane, isolating the direct impingement component from surface diffusion or precursor depletion by deposition. The experimental setup used in this work maps and quantifies the local impinging rate of argon gas over the sample plane. This setup simulates the identical conditions for a precursor molecule during FEBID. Argon gas was locally collected with a sniffer tube, which is directly connected to a residual gas analyzer for quantification. The measured distribution of impinging gas molecules showed a strong position dependence. Indeed, a 300-µm shift of the deposition area to a position further away from the impingement center spot resulted in a 50 % decrease in the precursor impinging rate on the surface area. With the same parameters, the precursor distribution was also simulated by a Monte Carlo software by Friedli and Utke and showed a good correlation between the empirical and the simulated precursor distribution. The results hereby presented underline the importance of controlling the local precursor flux conditions in order to obtain reproducible and comparable deposition results in FEBID.

  11. Endothelial cell behaviour on gas-plasma-treated PLA surfaces: the roles of surface chemistry and roughness.

    Science.gov (United States)

    Shah, Amita; Shah, Sarita; Mani, Gopinath; Wenke, Joseph; Agrawal, Mauli

    2011-04-01

    Glow-discharge gas-plasma (GP) treatment has been shown to induce surface modifications such that cell adhesion and growth are enhanced. However, it is not known which gas used in GP treatment is optimal for endothelial cell function. Polylactic acid (PLA) films treated oxygen, argon, or nitrogen GP were characterized using contact angles, scanning electron microscopy, atomic force microscopy, optical profilometry, and x-ray photoelectron spectroscopy. All three GP treatments decreased the carbon atomic concentration and surface roughness and increased the oxygen atomic concentration. Human umbilical vein endothelial cells were cultured on the PLA films for up to 7 days. Based on proliferation and live/dead assays, surface chemistry was shown to have the greatest effect on the attachment, proliferation, and viability of these cells, while roughness did not have a significant influence. Of the different gases, endothelial cell viability, attachment and proliferation were most significantly increased on PLA surfaces treated with oxygen and argon gas plasma. Copyright © 2010 John Wiley & Sons, Ltd.

  12. A nanostructured surface increases friction exponentially at the solid-gas interface

    Science.gov (United States)

    Phani, Arindam; Putkaradze, Vakhtang; Hawk, John E.; Prashanthi, Kovur; Thundat, Thomas

    2016-09-01

    According to Stokes’ law, a moving solid surface experiences viscous drag that is linearly related to its velocity and the viscosity of the medium. The viscous interactions result in dissipation that is known to scale as the square root of the kinematic viscosity times the density of the gas. We observed that when an oscillating surface is modified with nanostructures, the experimentally measured dissipation shows an exponential dependence on kinematic viscosity. The surface nanostructures alter solid-gas interplay greatly, amplifying the dissipation response exponentially for even minute variations in viscosity. Nanostructured resonator thus allows discrimination of otherwise narrow range of gaseous viscosity making dissipation an ideal parameter for analysis of a gaseous media. We attribute the observed exponential enhancement to the stochastic nature of interactions of many coupled nanostructures with the gas media.

  13. A nanostructured surface increases friction exponentially at the solid-gas interface.

    Science.gov (United States)

    Phani, Arindam; Putkaradze, Vakhtang; Hawk, John E; Prashanthi, Kovur; Thundat, Thomas

    2016-09-06

    According to Stokes' law, a moving solid surface experiences viscous drag that is linearly related to its velocity and the viscosity of the medium. The viscous interactions result in dissipation that is known to scale as the square root of the kinematic viscosity times the density of the gas. We observed that when an oscillating surface is modified with nanostructures, the experimentally measured dissipation shows an exponential dependence on kinematic viscosity. The surface nanostructures alter solid-gas interplay greatly, amplifying the dissipation response exponentially for even minute variations in viscosity. Nanostructured resonator thus allows discrimination of otherwise narrow range of gaseous viscosity making dissipation an ideal parameter for analysis of a gaseous media. We attribute the observed exponential enhancement to the stochastic nature of interactions of many coupled nanostructures with the gas media.

  14. Detecting buried radium contamination using soil-gas and surface-flux radon meaurements

    International Nuclear Information System (INIS)

    Karp, K.E.

    1988-06-01

    The Technical Measurements Center (TMC) has investigated the effectiveness of using radon soil-gas under surface-flux measurments to locate radium contamination that is buried sufficiently deep to be undetectable by surface gamma methods. At the first test site studied, an indication of a buried source was revealed by mapping anomalous surface-flux and soil-gas concentrations in the near surface overburden. The mapped radon anomalies were found to correspond in rough outline to the shape of the areal extent of the deposit as determined by borehole gamma-ray logs. The 5.9pCi/g radium deposit, buried 2 feet below the surface, went undetected by conventional surface gamma measurements. Similar results were obtained at the second test site where radon and conventional surface gamma measurements were taken in an area having radium concentrations ranging from 13.3 to 341.0 pCi/g at a depth of 4 feet below the surface. The radon methods were found to have a detection limit for buried radium lower than that of the surface gamma methods, as evidenced by the discovery of the 13.3 pCi/g deposit which went undetected by the surface gamma methods. 15 refs., 33 figs., 8 tabs

  15. Well-defined critical association concentration and rapid adsorption at the air/water interface of a short amphiphilic polymer, amphipol A8-35: a study by Förster resonance energy transfer and dynamic surface tension measurements.

    Science.gov (United States)

    Giusti, Fabrice; Popot, Jean-Luc; Tribet, Christophe

    2012-07-17

    Amphipols (APols) are short amphiphilic polymers designed to handle membrane proteins (MPs) in aqueous solutions as an alternative to small surfactants (detergents). APols adsorb onto the transmembrane, hydrophobic surface of MPs, forming small, water-soluble complexes, in which the protein is biochemically stabilized. At variance with MP/detergent complexes, MP/APol ones remain stable even at extreme dilutions. Pure APol solutions self-associate into well-defined micelle-like globules comprising a few APol molecules, a rather unusual behavior for amphiphilic polymers, which typically form ill-defined assemblies. The best characterized APol to date, A8-35, is a random copolymer of acrylic acid, isopropylacrylamide, and octylacrylamide. In the present work, the concentration threshold for self-association of A8-35 in salty buffer (NaCl 100 mM, Tris/HCl 20 mM, pH 8.0) has been studied by Förster resonance energy transfer (FRET) measurements and tensiometry. In a 1:1 mol/mol mixture of APols grafted with either rhodamine or 7-nitro-1,2,3-benzoxadiazole, the FRET signal as a function of A8-35 concentration is essentially zero below a threshold concentration of 0.002 g·L(-1) and increases linearly with concentration above this threshold. This indicates that assembly takes place in a narrow concentration interval around 0.002 g·L(-1). Surface tension measurements decreases regularly with concentration until a threshold of ca. 0.004 g·L(-1), beyond which it reaches a plateau at ca. 30 mN·m(-1). Within experimental uncertainties, the two techniques thus yield a comparable estimate of the critical self-assembly concentration. The kinetics of variation of the surface tension was analyzed by dynamic surface tension measurements in the time window 10 ms-100 s. The rate of surface tension decrease was similar in solutions of A8-35 and of the anionic surfactant sodium dodecylsulfate when both compounds were at a similar molar concentration of n-alkyl moieties. Overall, the

  16. Spectroscopic studies of surface-gas interactions and catalyst restructuring at ambient pressure: mind the gap!

    International Nuclear Information System (INIS)

    Rupprechter, Guenther; Weilach, Christian

    2008-01-01

    Recent progress in the application of surface vibrational spectroscopy at ambient pressure allows us to monitor surface-gas interactions and heterogeneous catalytic reactions under conditions approaching those of technical catalysis. The surface specificity of photon-based methods such as polarization modulation infrared reflection absorption spectroscopy (PM-IRAS) and sum frequency generation (SFG) spectroscopy is utilized to monitor catalytically active surfaces while they function at high pressure and high temperature. Together with complementary information from high-pressure x-ray photoelectron spectroscopy (HP-XPS) and high-resolution transmission electron microscopy (HRTEM), reaction mechanisms can be deduced on a molecular level. Well defined model catalysts, prepared under ultrahigh vacuum (UHV), are typically employed in such studies, including smooth and stepped single crystals, thin oxide films, and oxide-supported nanoparticles. A number of studies on unsupported and supported noble metal (Pd, Rh) catalysts are presented, focusing on the transformation of the catalysts from the 'as-prepared' to the 'active state'. This often involves pronounced alterations in catalyst structure and composition, for example the creation of surface carbon phases, surface oxides or surface alloys, as well as nanoparticle restructuring. The reactivity studies include CH 3 OH, CH 4 and CO oxidation with gas phase analysis by gas chromatography and mass spectrometry. Differing results between studies under ultrahigh vacuum and ambient pressure, and between studies on single crystals and supported nanoparticles, demonstrate the importance of 'minding the gap' between idealized and realistic conditions

  17. Continuous processing of polymers in repetitively pulsed atmospheric pressure discharges with moving surfaces and gas flow

    Energy Technology Data Exchange (ETDEWEB)

    Bhoj, Ananth N [Department of Chemical and Biomolecular Engineering, University of Illinois, Urbana, IL 61801 (United States); Kushner, Mark J [Department of Electrical and Computer Engineering, Iowa State University, Ames, IA 50011 (United States)

    2007-11-21

    Atmospheric pressure corona discharges are industrially employed to treat large areas of commodity polymer sheets by creating new surface functional groups. The most common processes use oxygen containing discharges to affix oxygen to hydrocarbon polymers, thereby increasing their surface energy and wettability. The process is typically continuous and is carried out in a web configuration with film speeds of tens to hundreds of cm s{sup -1}. The densities and relative abundances of functional groups depend on the gas composition, gas flow rate and residence time of the polymer in the discharge zone which ultimately determine the magnitude and mole fractions of reactive fluxes to the surface. In this paper, results are discussed from a two-dimensional computational investigation of the atmospheric pressure plasma functionalization of a moving polypropylene sheet in repetitively pulsed He/O{sub 2}/H{sub 2}O discharges. O and OH typically initiate surface processing by hydrogen abstraction. These species are regenerated during every plasma pulse but are also largely consumed during the inter-pulse period. Longer-lived species such as O{sub 3} accumulate over many pulses and convect downstream with the gas flow. Optimizing the interplay between local rapid reactions, such as H abstraction which occurs dominantly in the discharge zone, and non-local slower processes, such as surface-surface reactions, may enable the customization of the relative abundance of surface functional groups.

  18. Continuous processing of polymers in repetitively pulsed atmospheric pressure discharges with moving surfaces and gas flow

    International Nuclear Information System (INIS)

    Bhoj, Ananth N; Kushner, Mark J

    2007-01-01

    Atmospheric pressure corona discharges are industrially employed to treat large areas of commodity polymer sheets by creating new surface functional groups. The most common processes use oxygen containing discharges to affix oxygen to hydrocarbon polymers, thereby increasing their surface energy and wettability. The process is typically continuous and is carried out in a web configuration with film speeds of tens to hundreds of cm s -1 . The densities and relative abundances of functional groups depend on the gas composition, gas flow rate and residence time of the polymer in the discharge zone which ultimately determine the magnitude and mole fractions of reactive fluxes to the surface. In this paper, results are discussed from a two-dimensional computational investigation of the atmospheric pressure plasma functionalization of a moving polypropylene sheet in repetitively pulsed He/O 2 /H 2 O discharges. O and OH typically initiate surface processing by hydrogen abstraction. These species are regenerated during every plasma pulse but are also largely consumed during the inter-pulse period. Longer-lived species such as O 3 accumulate over many pulses and convect downstream with the gas flow. Optimizing the interplay between local rapid reactions, such as H abstraction which occurs dominantly in the discharge zone, and non-local slower processes, such as surface-surface reactions, may enable the customization of the relative abundance of surface functional groups

  19. Surface functionalization of epitaxial graphene on SiC by ion irradiation for gas sensing application

    International Nuclear Information System (INIS)

    Kaushik, Priya Darshni; Ivanov, Ivan G.; Lin, Pin-Cheng; Kaur, Gurpreet; Eriksson, Jens; Lakshmi, G.B.V.S.; Avasthi, D.K.; Gupta, Vinay; Aziz, Anver; Siddiqui, Azher M.; Syväjärvi, Mikael; Yazdi, G. Reza

    2017-01-01

    Highlights: • For the first time the gas sensing application of SHI irradiated epitaxial graphene on SiC is explored. • Surface morphology of irradiated graphene layers showed graphene folding, hillocks, and formation of wrinkles. • Existence of an optimal fluence which maximize the gas sensing response towards NO_2 and NH_3 gases. - Abstract: In this work, surface functionalization of epitaxial graphene grown on silicon carbide was performed by ion irradiation to investigate their gas sensing capabilities. Swift heavy ion irradiation using 100 MeV silver ions at four varying fluences was implemented on epitaxial graphene to investigate morphological and structural changes and their effects on the gas sensing capabilities of graphene. Sensing devices are expected as one of the first electronic applications using graphene and most of them use functionalized surfaces to tailor a certain function. In our case, we have studied irradiation as a tool to achieve functionalization. Morphological and structural changes on epitaxial graphene layers were investigated by atomic force microscopy, Raman spectroscopy, Raman mapping and reflectance mapping. The surface morphology of irradiated graphene layers showed graphene folding, hillocks, and formation of wrinkles at highest fluence (2 × 10"1"3 ions/cm"2). Raman spectra analysis shows that the graphene defect density is increased with increasing fluence, while Raman mapping and reflectance mapping show that there is also a reduction of monolayer graphene coverage. The samples were investigated for ammonia and nitrogen dioxide gas sensing applications. Sensors fabricated on pristine and irradiated samples showed highest gas sensing response at an optimal fluence. Our work provides new pathways for introducing defects in controlled manner in epitaxial graphene, which can be used not only for gas sensing application but also for other applications, such as electrochemical, biosensing, magnetosensing and spintronic

  20. Surface functionalization of epitaxial graphene on SiC by ion irradiation for gas sensing application

    Energy Technology Data Exchange (ETDEWEB)

    Kaushik, Priya Darshni, E-mail: kaushik.priyadarshni@gmail.com [Department of Physics, Chemistry and Biology, Linköping University, SE-58183 Linköping (Sweden); Department of Physics, Jamia Millia Islamia, New Delhi, 110025 (India); Ivanov, Ivan G.; Lin, Pin-Cheng [Department of Physics, Chemistry and Biology, Linköping University, SE-58183 Linköping (Sweden); Kaur, Gurpreet [Department of Physics and Astrophysics, University of Delhi, Delhi, 110007 (India); Eriksson, Jens [Department of Physics, Chemistry and Biology, Linköping University, SE-58183 Linköping (Sweden); Lakshmi, G.B.V.S. [Inter-University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi, 110067 (India); Avasthi, D.K. [Inter-University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi, 110067 (India); Amity Institute of Nanotechnology, Noida 201313 (India); Gupta, Vinay [Department of Physics and Astrophysics, University of Delhi, Delhi, 110007 (India); Aziz, Anver; Siddiqui, Azher M. [Department of Physics, Jamia Millia Islamia, New Delhi, 110025 (India); Syväjärvi, Mikael [Department of Physics, Chemistry and Biology, Linköping University, SE-58183 Linköping (Sweden); Yazdi, G. Reza, E-mail: yazdi@ifm.liu.se [Department of Physics, Chemistry and Biology, Linköping University, SE-58183 Linköping (Sweden)

    2017-05-01

    Highlights: • For the first time the gas sensing application of SHI irradiated epitaxial graphene on SiC is explored. • Surface morphology of irradiated graphene layers showed graphene folding, hillocks, and formation of wrinkles. • Existence of an optimal fluence which maximize the gas sensing response towards NO{sub 2} and NH{sub 3} gases. - Abstract: In this work, surface functionalization of epitaxial graphene grown on silicon carbide was performed by ion irradiation to investigate their gas sensing capabilities. Swift heavy ion irradiation using 100 MeV silver ions at four varying fluences was implemented on epitaxial graphene to investigate morphological and structural changes and their effects on the gas sensing capabilities of graphene. Sensing devices are expected as one of the first electronic applications using graphene and most of them use functionalized surfaces to tailor a certain function. In our case, we have studied irradiation as a tool to achieve functionalization. Morphological and structural changes on epitaxial graphene layers were investigated by atomic force microscopy, Raman spectroscopy, Raman mapping and reflectance mapping. The surface morphology of irradiated graphene layers showed graphene folding, hillocks, and formation of wrinkles at highest fluence (2 × 10{sup 13} ions/cm{sup 2}). Raman spectra analysis shows that the graphene defect density is increased with increasing fluence, while Raman mapping and reflectance mapping show that there is also a reduction of monolayer graphene coverage. The samples were investigated for ammonia and nitrogen dioxide gas sensing applications. Sensors fabricated on pristine and irradiated samples showed highest gas sensing response at an optimal fluence. Our work provides new pathways for introducing defects in controlled manner in epitaxial graphene, which can be used not only for gas sensing application but also for other applications, such as electrochemical, biosensing, magnetosensing and

  1. Numerical analysis of micro-/nanoscale gas-film lubrication of sliding surface with complicated structure

    International Nuclear Information System (INIS)

    Kawagoe, Yoshiaki; Isono, Susumu; Takeno, Takanori; Yonemura, Shigeru; Takagi, Toshiyuki; Miki, Hiroyuki

    2014-01-01

    It has been reported that the friction between a partially polished diamond-coated surface and a metal surface was drastically reduced to zero when they are slid at a few m/s. Since the sliding was noiseless, it seems that the diamond-coated surface was levitated over the counter surface and the sliding mechanism was the gas film lubrication. Recently, the mechanism of levitation of a slider with a micro/nanoscale surface structure on a rotating disk was theoretically clarified [S. Yonemura et al., Tribol. Lett., (2014), doi:10.1007/s11249-014-0368-2]. Probably, the partially polished diamond-coated surface may be levitated by high gas pressure generated by the micro/nanoscale surface structure on it. In this study, in order to verify our deduction, we performed numerical simulations of sliding of partially polished diamond-coated surface by reproducing its complicated surface structure using the data measured by an atomic force microscope (AFM). As a result, we obtained the lift force which is large enough to levitate the slider used in the experiment

  2. Numerical analysis of micro-/nanoscale gas-film lubrication of sliding surface with complicated structure

    Energy Technology Data Exchange (ETDEWEB)

    Kawagoe, Yoshiaki; Isono, Susumu; Takeno, Takanori [Department of Nanomechanics, Graduate School of Engineering, Tohoku University, 6-6-01 Aoba, Aramaki, Aoba-ku, Sendai 980-8579 (Japan); Yonemura, Shigeru; Takagi, Toshiyuki [Institute of Fluid Science, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577 (Japan); Miki, Hiroyuki [Frontier Research Institute for Interdisciplinary Sciences, Tohoku University, 6-3 Aoba, Aramaki, Aoba-ku, Sendai 980-8578 (Japan)

    2014-12-09

    It has been reported that the friction between a partially polished diamond-coated surface and a metal surface was drastically reduced to zero when they are slid at a few m/s. Since the sliding was noiseless, it seems that the diamond-coated surface was levitated over the counter surface and the sliding mechanism was the gas film lubrication. Recently, the mechanism of levitation of a slider with a micro/nanoscale surface structure on a rotating disk was theoretically clarified [S. Yonemura et al., Tribol. Lett., (2014), doi:10.1007/s11249-014-0368-2]. Probably, the partially polished diamond-coated surface may be levitated by high gas pressure generated by the micro/nanoscale surface structure on it. In this study, in order to verify our deduction, we performed numerical simulations of sliding of partially polished diamond-coated surface by reproducing its complicated surface structure using the data measured by an atomic force microscope (AFM). As a result, we obtained the lift force which is large enough to levitate the slider used in the experiment.

  3. Potential energy surfaces for alkali plus noble gas pairs: a systematic comparison

    Science.gov (United States)

    Blank, L. Aaron; Kedziora, Gary S.; Weeks, David E.

    2010-02-01

    Optically Pumped Alkali Lasers (OPAL) involve interactions of alkali atoms with a buffer gas typically consisting of a noble gas together with C2H4. Line broadening mechanisms are of particular interest because they can be used to match a broad optical pumping source with relatively narrow alkali absorption spectra. To better understand the line broadening processes at work in OPAL systems we focus on the noble gas collisional partners. A matrix of potential energy surfaces (PES) has been generated at the multi-configurational self consistent field (MCSCF) level for M + Ng, where M=Li, Na, K, Rb, Cs and Ng=He, Ne, Ar. The PES include the X2Σ ground state surface and the A2II, B2Σ excited state surfaces. In addition to the MCSCF surfaces, PES for Li+He have been calculated at the multi-reference singles and doubles configuration interaction (MRSDCI) level with spin-orbit splitting effects included. These surfaces provide a way to check the qualitative applicability of the MCSCF calculations. They also exhibit the avoided crossing between the B2Σ and A2II1/2 surfaces that is partially responsible for collision induced relaxation from the 2P3/2 to the 2P1/2 atomic levels.

  4. Comparison of molecular dynamics and kinetic modeling of gas-surface interactions

    NARCIS (Netherlands)

    Frezzotti, A.; Gaastra - Nedea, S.V.; Markvoort, A.J.; Spijker, P.; Gibelli, L.

    2008-01-01

    The interaction of a dilute monatomic gas with a solid surface is studied byMolecular Dynamics (MD) simulations and by numerical solutions of a recently proposed kinetic model. Following previous investigations, the heat transport between parallel walls and Couette flow have been adopted as test

  5. Multibreath alveolar oxygen tension imaging.

    Science.gov (United States)

    Clapp, Justin; Hamedani, Hooman; Kadlecek, Stephen; Xin, Yi; Shaghaghi, Hoora; Siddiqui, Sarmad; Rossman, Milton D; Rizi, Rahim R

    2016-10-01

    This study tested the ability of a multibreath hyperpolarized HP (3) He MRI protocol to increase the accuracy of regional alveolar oxygen tension (PA O2 ) measurements by lessening the influence of gas-flow artifacts. Conventional single-breath PA O2 measurement has been susceptible to error induced by intervoxel gas flow, particularly when used to study subjects with moderate-to-severe chronic obstructive pulmonary disease (COPD). Both single-breath and multibreath PA O2 imaging schemes were implemented in seven human subjects (one healthy, three asymptomatic smokers, and three COPD). The number and location of voxels with nonphysiologic PA O2 values generated by intervoxel gas flow were compared between the two protocols. The multibreath scheme resulted in a significantly lower total percentage of nonphysiologic PA O2 values (6.0%) than the single-breath scheme (13.7%) (P = 0.006). PA O2 maps showed several patterns of gas-flow artifacts that were present in the single-breath protocol but mitigated by the multibreath approach. Multibreath imaging also allowed for the analysis of slow-filling areas that presented no signal after a single breath. A multibreath approach enhances the accuracy and completeness of noninvasive PA O2 measurement by significantly lessening the proportion of nonphysiologic values generated by intervoxel gas flow. Magn Reson Med 76:1092-1101, 2016. © 2015 Wiley Periodicals, Inc. © 2015 Wiley Periodicals, Inc.

  6. Functionalised zinc oxide nanowire gas sensors: Enhanced NO(2) gas sensor response by chemical modification of nanowire surfaces.

    Science.gov (United States)

    Waclawik, Eric R; Chang, Jin; Ponzoni, Andrea; Concina, Isabella; Zappa, Dario; Comini, Elisabetta; Motta, Nunzio; Faglia, Guido; Sberveglieri, Giorgio

    2012-01-01

    Surface coating with an organic self-assembled monolayer (SAM) can enhance surface reactions or the absorption of specific gases and hence improve the response of a metal oxide (MOx) sensor toward particular target gases in the environment. In this study the effect of an adsorbed organic layer on the dynamic response of zinc oxide nanowire gas sensors was investigated. The effect of ZnO surface functionalisation by two different organic molecules, tris(hydroxymethyl)aminomethane (THMA) and dodecanethiol (DT), was studied. The response towards ammonia, nitrous oxide and nitrogen dioxide was investigated for three sensor configurations, namely pure ZnO nanowires, organic-coated ZnO nanowires and ZnO nanowires covered with a sparse layer of organic-coated ZnO nanoparticles. Exposure of the nanowire sensors to the oxidising gas NO(2) produced a significant and reproducible response. ZnO and THMA-coated ZnO nanowire sensors both readily detected NO(2) down to a concentration in the very low ppm range. Notably, the THMA-coated nanowires consistently displayed a small, enhanced response to NO(2) compared to uncoated ZnO nanowire sensors. At the lower concentration levels tested, ZnO nanowire sensors that were coated with THMA-capped ZnO nanoparticles were found to exhibit the greatest enhanced response. ΔR/R was two times greater than that for the as-prepared ZnO nanowire sensors. It is proposed that the ΔR/R enhancement in this case originates from the changes induced in the depletion-layer width of the ZnO nanoparticles that bridge ZnO nanowires resulting from THMA ligand binding to the surface of the particle coating. The heightened response and selectivity to the NO(2) target are positive results arising from the coating of these ZnO nanowire sensors with organic-SAM-functionalised ZnO nanoparticles.

  7. Parachute Cord Tension Sensor

    Data.gov (United States)

    National Aeronautics and Space Administration — To design and fabricate a light weight (few oz), very small (~2 inch length) parachute cord tension sensor demonstrator device.A major challenge for the CPAS (The...

  8. Leadership. Using Creative Tension.

    Science.gov (United States)

    Cook, David L.

    1986-01-01

    Leadership involves maintaining a balance of the variables which comprise leadership. Love and fear, types of power, success and effectiveness, and driving and restraining forces are discussed as sources of the creative tension a leader uses to influence others. (MT)

  9. Study of Si wafer surfaces irradiated by gas cluster ion beams

    International Nuclear Information System (INIS)

    Isogai, H.; Toyoda, E.; Senda, T.; Izunome, K.; Kashima, K.; Toyoda, N.; Yamada, I.

    2007-01-01

    The surface structures of Si (1 0 0) wafers subjected to gas cluster ion beam (GCIB) irradiation have been analyzed by cross-sectional transmission electron microscopy (XTEM) and atomic force microscopy (AFM). GCIB irradiation is a promising technique for both precise surface etching and planarization of Si wafers. However, it is very important to understand the crystalline structure of Si wafers after GCIB irradiation. An Ar-GCIB used for the physically sputtering of Si atoms and a SF 6 -GCIB used for the chemical etching of the Si surface are also analyzed. The GCIB irradiation increases the surface roughness of the wafers, and amorphous Si layers are formed on the wafer surface. However, when the Si wafers are annealed in hydrogen at a high temperature after the GCIB irradiation, the surface roughness decreases to the same level as that before the irradiation. Moreover, the amorphous Si layers disappear completely

  10. Optic nerve oxygen tension

    DEFF Research Database (Denmark)

    la Cour, M; Kiilgaard, Jens Folke; Eysteinsson, T

    2000-01-01

    To investigate the influence of acute changes in intraocular pressure on the oxygen tension in the vicinity of the optic nerve head under control conditions and after intravenous administration of 500 mg of the carbonic anhydrase inhibitor dorzolamide.......To investigate the influence of acute changes in intraocular pressure on the oxygen tension in the vicinity of the optic nerve head under control conditions and after intravenous administration of 500 mg of the carbonic anhydrase inhibitor dorzolamide....

  11. Spontaneous tension haemopneumothorax

    OpenAIRE

    Patterson, Benjamin Oliver; Itam, Sarah; Probst, Fey

    2008-01-01

    Abstract We present a patient with sudden onset progressive shortness of breath and no history of trauma, who rapidly became haemodynamically compromised with a pneumothorax and pleural effusion seen on chest radiograph. He was treated for spontaneous tension pneumothorax but this was soon revealed to be a tension haemopneumothorax. He underwent urgent thoracotomy after persistent bleeding to explore an apical vascular abnormality seen on CT scanning. To our knowledge this is the first such c...

  12. Verification of surface source's characteristics using large-area 2π gas flow counter

    International Nuclear Information System (INIS)

    Abu Naser Waheed, M.M.; Mikami, S.; Kobayashi, H.; Noda, K.

    1998-09-01

    Power Reactor and Nuclear Fuel Development Corporation (PNC) has large-area 2π gas flow counter for the purpose of measuring activity of surface sources of alpha or beta ray emitter. Surface sources are used for the calibration of radiation measuring equipment for radiation control. Due to sequent use of sources, the surface of these sources are inclined to go in bad condition because of unwanted accidental incidents. For the better calibration achievement of radiation measuring instruments the rate of emission of these sources are to be checked periodically by the large-area 2π gas flow counter. In this paper described that eight U 3 O 8 surface sources were selected from many sources of PNC Tokai Works and activity of these sources was measured by the 2π gas flow counter. The results were compared with the values certified by Japan Radio Isotope Association (JRIA). It is evident from the result of comparison that the surface sources are in good condition, i.e., the sources are reliable to calibrate the radiation control instruments. (author)

  13. Tension perturbations of black brane spacetimes

    International Nuclear Information System (INIS)

    Traschen, Jennie; Fox, Daniel

    2004-01-01

    We consider black brane spacetimes that have at least one spatial translation Killing field that is tangent to the brane. A new parameter, the tension of a spacetime, is defined. The tension parameter is associated with spatial translations in much the same way that the ADM mass is associated with the time translation Killing field. In this work, we explore the implications of the spatial translation symmetry for small perturbations around a background black brane. For static-charged black branes we derive a law which relates the tension perturbation to the surface gravity times the change in the horizon area, plus terms that involve variations in the charges and currents. We find that as a black brane evaporates the tension decreases. We also give a simple derivation of a first law for black brane spacetimes. These constructions hold when the background stress-energy is governed by a Hamiltonian, and the results include arbitrary perturbative stress-energy sources

  14. Surface shear stress dependence of gas transfer velocity parameterizations using DNS

    Science.gov (United States)

    Fredriksson, S. T.; Arneborg, L.; Nilsson, H.; Handler, R. A.

    2016-10-01

    Air-water gas-exchange is studied in direct numerical simulations (DNS) of free-surface flows driven by natural convection and weak winds. The wind is modeled as a constant surface-shear-stress and the gas-transfer is modeled via a passive scalar. The simulations are characterized via a Richardson number Ri=Bν/u*4 where B, ν, and u* are the buoyancy flux, kinematic viscosity, and friction velocity respectively. The simulations comprise 0Ric or kg=AShearu*Sc-n, Risurface-characteristics.

  15. Tribological Characteristic of Titanium Alloy Surface Layers Produced by Diode Laser Gas Nitriding

    Directory of Open Access Journals (Sweden)

    Lisiecki A.

    2016-06-01

    Full Text Available In order to improve the tribological properties of titanium alloy Ti6Al4V composite surface layers Ti/TiN were produced during laser surface gas nitriding by means of a novel high power direct diode laser with unique characteristics of the laser beam and a rectangular beam spot. Microstructure, surface topography and microhardness distribution across the surface layers were analyzed. Ball-on-disk tests were performed to evaluate and compare the wear and friction characteristics of surface layers nitrided at different process parameters, base metal of titanium alloy Ti6Al4V and also the commercially pure titanium. Results showed that under dry sliding condition the commercially pure titanium samples have the highest coefficient of friction about 0.45, compared to 0.36 of titanium alloy Ti6Al4V and 0.1-0.13 in a case of the laser gas nitrided surface layers. The volume loss of Ti6Al4V samples under such conditions is twice lower than in a case of pure titanium. On the other hand the composite surface layer characterized by the highest wear resistance showed almost 21 times lower volume loss during the ball-on-disk test, compared to Ti6Al4V samples.

  16. Statistics of surface divergence and their relation to air-water gas transfer velocity

    Science.gov (United States)

    Asher, William E.; Liang, Hanzhuang; Zappa, Christopher J.; Loewen, Mark R.; Mukto, Moniz A.; Litchendorf, Trina M.; Jessup, Andrew T.

    2012-05-01

    Air-sea gas fluxes are generally defined in terms of the air/water concentration difference of the gas and the gas transfer velocity,kL. Because it is difficult to measure kLin the ocean, it is often parameterized using more easily measured physical properties. Surface divergence theory suggests that infrared (IR) images of the water surface, which contain information concerning the movement of water very near the air-water interface, might be used to estimatekL. Therefore, a series of experiments testing whether IR imagery could provide a convenient means for estimating the surface divergence applicable to air-sea exchange were conducted in a synthetic jet array tank embedded in a wind tunnel. Gas transfer velocities were measured as a function of wind stress and mechanically generated turbulence; laser-induced fluorescence was used to measure the concentration of carbon dioxide in the top 300 μm of the water surface; IR imagery was used to measure the spatial and temporal distribution of the aqueous skin temperature; and particle image velocimetry was used to measure turbulence at a depth of 1 cm below the air-water interface. It is shown that an estimate of the surface divergence for both wind-shear driven turbulence and mechanically generated turbulence can be derived from the surface skin temperature. The estimates derived from the IR images are compared to velocity field divergences measured by the PIV and to independent estimates of the divergence made using the laser-induced fluorescence data. Divergence is shown to scale withkLvalues measured using gaseous tracers as predicted by conceptual models for both wind-driven and mechanically generated turbulence.

  17. Dynamic Gas Flow Effects on the ESD of Aerospace Vehicle Surfaces

    Science.gov (United States)

    Hogue, Michael D.; Kapat, Jayanta; Ahmed, Kareem; Cox, Rachel E.; Wilson, Jennifer G.; Calle, Luz M.; Mulligan, Jaysen

    2016-01-01

    The purpose of this work is to develop a dynamic version of Paschen's Law that takes into account the flow of ambient gas past aerospace vehicle surfaces. However, the classic Paschen's Law does not take into account the flow of gas of an aerospace vehicle, whose surfaces may be triboelectrically charged by dust or ice crystal impingement, traversing the atmosphere. The basic hypothesis of this work is that the number of electron-ion pairs created per unit distance by the electric field between the electrodes is mitigated by the electron-ion pairs removed per unit distance by the flow of gas. The revised Paschen equation must be a function of the mean velocity, v(sub xm), of the ambient gas and reduces to the classical version of Paschen's law when the gas mean velocity, v(sub xm) = 0. New formulations of Paschen's Law, taking into account Mach number and dynamic pressure, derived by the authors, will be discussed. These equations will be evaluated by wind tunnel experimentation later this year. Based on the results of this work, it is hoped that the safety of aerospace vehicles will be enhanced with a redefinition of electrostatic launch commit criteria. It is also possible that new products, such as new anti-static coatings, may be formulated from this data.

  18. Reference Data for the Density, Viscosity, and Surface Tension of Liquid Al-Zn, Ag-Sn, Bi-Sn, Cu-Sn, and Sn-Zn Eutectic Alloys

    Science.gov (United States)

    Dobosz, Alexandra; Gancarz, Tomasz

    2018-03-01

    The data for the physicochemical properties viscosity, density, and surface tension obtained by different experimental techniques have been analyzed for liquid Al-Zn, Ag-Sn, Bi-Sn, Cu-Sn, and Sn-Zn eutectic alloys. All experimental data sets have been categorized and described by the year of publication, the technique used to obtain the data, the purity of the samples and their compositions, the quoted uncertainty, the number of data in the data set, the form of data, and the temperature range. The proposed standard deviations of liquid eutectic Al-Zn, Ag-Sn, Bi-Sn, Cu-Sn, and Sn-Zn alloys are 0.8%, 0.1%, 0.5%, 0.2%, and 0.1% for the density, 8.7%, 4.1%, 3.6%, 5.1%, and 4.0% for viscosity, and 1.0%, 0.5%, 0.3%, N/A, and 0.4% for surface tension, respectively, at a confidence level of 95%.

  19. Collisions of ideal gas molecules with a rough/fractal surface. A computational study.

    Science.gov (United States)

    Panczyk, Tomasz

    2007-02-01

    The frequency of collisions of ideal gas molecules (argon) with a rough surface has been studied. The rough/fractal surface was created using random deposition technique. By applying various depositions, the roughness of the surface was controlled and, as a measure of the irregularity, the fractal dimensions of the surfaces were determined. The surfaces were next immersed in argon (under pressures 2 x 10(3) to 2 x 10(5) Pa) and the numbers of collisions with these surfaces were counted. The calculations were carried out using a simplified molecular dynamics simulation technique (only hard core repulsions were assumed). As a result, it was stated that the frequency of collisions is a linear function of pressure for all fractal dimensions studied (D = 2, ..., 2.5). The frequency per unit pressure is quite complex function of the fractal dimension; however, the changes of that frequency with the fractal dimension are not strong. It was found that the frequency of collisions is controlled by the number of weakly folded sites on the surfaces and there is some mapping between the shape of adsorption energy distribution functions and this number of weakly folded sites. The results for the rough/fractal surfaces were compared with the prediction given by the Langmuir-Hertz equation (valid for smooth surface), generally the departure from the Langmuir-Hertz equation is not higher than 48% for the studied systems (i.e. for the surfaces created using the random deposition technique).

  20. Deployment Algorithms of Wireless Sensor Networks for Near-surface Underground Oil and Gas Pipeline Monitoring

    Directory of Open Access Journals (Sweden)

    Hua-Ping YU

    2014-07-01

    Full Text Available Oil and gas pipelines are the infrastructure of national economic development. Deployment problem of wireless underground sensor networks (WUSN for oil and gas pipeline systems is a fundamental problem. This paper firstly analyzed the wireless channel characteristics and energy consumption model in near-surface underground soil, and then studied the spatial structure of oil and gas pipelines and introduced the three-layer system structure of WUSN for oil and gas pipelines monitoring. Secondly, the optimal deployment strategy in XY plane and XZ plane which were projected from three-dimensional oil and gas pipeline structure was analyzed. Thirdly, the technical framework of using kinetic energy of the fluid in pipelines to recharge sensor nodes and partition strategy for energy consumption balance based on the wireless communication technology of magnetic induction waveguide were proposed, which can effectively improve the energy performance and connectivity of the network, and provide theoretical guidance and practical basis for the monitoring of long oil and gas pipeline network, the city tap water pipe network and sewage pipe network.

  1. Opportunities of influence of plasma streams formed in IKA with continuos nor king gas filling en the surface of materials

    International Nuclear Information System (INIS)

    Useinov, B.M.; Useinova, A.M.; Amrenova, A.U.; Pusankov, S.A.; Sartin, S.A.; Virko, P.G.

    2001-01-01

    The results of the investigation of influence of plasma stream formed in IKA with continuous working gas filling on the surface of stainless steel 12X18H10T and aluminum are given in this article. It is shown here that the effect of influence of plasma stream on the surface of materials depends on the way of working gas filling. There is the comparison of influence of plasma stream formed in plasma accelerator with impulse and continuous working gas filling

  2. Surface ignition behaviors of methane–air mixture in a gas oven burner

    International Nuclear Information System (INIS)

    Ryu, Jungwan; Kwon, Jongseo; Kim, Ryanggyun; Kim, Minseong; Kim, Youngsoo; Jeon, Chunghwan; Song, Juhun

    2014-01-01

    In a gas oven burner, commonly used as a residential appliance, a surface igniter is a critical component for creating a pilot flame near the surface that can propagate safely back to the nozzle of the burner. The igniter should meet critical operating requirements: a lower surface temperature needed to ignite a methane–air mixture and a stable/safe ignition sustained. Otherwise, such failure would result in an instantaneous peak in carbon monoxide emission and a safety hazard inside a closed oven. Several theoretical correlations have been used to predict ignition temperature as well as the critical ignition/extinction limit for a stagnation flow ignition. However, there have only been a few studies on ignition modes or relevant stability analysis, and therefore a more detailed examination of the transient ignition process is required. In this study, a high-speed flame visualization technique with temperature measurement was employed to reveal a surface ignition phenomenon and subsequent flame propagation of a cold combustible methane–air mixture in a gas oven burner. The operating parameters were the temperature–time history of the igniter surface, mixture velocity, and the distance of the igniter from the nozzle. The surface ignition temperatures were analyzed for such parameters under a safe ignition mode, while several abnormal modes leading to ignition failure were also recognized. - Highlights: •We revealed a surface ignition behavior of combustible mixture in gas oven burner. •We employed a flame visualization technique with temperature measurement. •We evaluated effects of parameters such as lifetime, mixture velocity and igniter distance. •We recognized several abnormal modes leading to ignition failure

  3. First-principles calculation of adsorption of shale gas on CaCO3 (100) surfaces.

    Science.gov (United States)

    Luo, Qiang; Pan, Yikun; Guo, Ping; Wang, Zhouhua; Wei, Na; Sun, Pengfei; Liu, Yuxiao

    2017-06-16

    To demonstrate the adsorption strength of shale gas to calcium carbonate in shale matrix, the adsorption of shale gas on CaCO3 (100) surfaces was studied using the first-principles method, which is based on the density functional theory (DFT). The structures and electronic properties of CH4, C2H6, CO2 and N2 molecules were calculated by the generalized gradient approximation (GGA), for a coverage of 1 monolayer (ML). Under the same conditions, the density of states (DOS) of CaCO3 (100) surfaces before and after the adsorption of shale gas molecules at high-symmetry adsorption sites were compared. The results showed that the adsorption energies of CH4, C2H6, CO2 and N2 on CaCO3 (100) surfaces were between 0.2683 eV and -0.7388 eV. When a CH4 molecule was adsorbed at a hollow site and its 2 hydrogen atoms were parallel to the long diagonal (H3) on the CaCO3 (100) surface, it had the most stable adsorption, and the adsorption energy was only -0.4160 eV. The change of adsorption energy of CH4 was no more than 0.0535 eV. Compared with the DOS distribution of CH4 before adsorption, it shifted to the left overall after adsorption. At the same time, the partial density of states (PDOS) curves of CaCO3 (100) surfaces before and after adsorption basically overlapped. This work showed that the adsorption effect of shale gas on calcium carbonate is very weak, and the adsorption is physisorption at the molecular level.

  4. Reflection of illumination laser from gas metal arc weld pool surface

    International Nuclear Information System (INIS)

    Ma, Xiaoji; Zhang, YuMing

    2009-01-01

    The weld pool is the core of the welding process where complex welding phenomena originate. Skilled welders acquire their process feedback primarily from the weld pool. Observation and measurement of the three-dimensional weld pool surface thus play a fundamental role in understanding and future control of complex welding processes. To this end, a laser line is projected onto the weld pool surface in pulsed gas metal arc welding (GMAW) and an imaging plane is used to intercept its reflection from the weld pool surface. Resultant images of the reflected laser are analyzed and it is found that the weld pool surface in GMAW does specularly reflect the projected laser as in gas tungsten arc welding (GTAW). Hence, the weld pool surface in GMAW is also specular and it is in principle possible that it may be observed and measured by projecting a laser pattern and then intercepting and imaging the reflection from it. Due to high frequencies of surface fluctuations, GMAW requires a relatively short time to image the reflected laser

  5. Bubble coalescence dynamics and supersaturation in electrolytic gas evolution

    Energy Technology Data Exchange (ETDEWEB)

    Stover, R.L. [Univ. of California, Berkeley, CA (United States). Dept. of Chemical Engineering]|[Lawrence Berkeley National Lab., CA (United States). Energy and Environment Div.

    1996-08-01

    The apparatus and procedures developed in this research permit the observation of electrolytic bubble coalescence, which heretofore has not been possible. The influence of bubble size, electrolyte viscosity, surface tension, gas type, and pH on bubble coalescence was examined. The Navier-Stokes equations with free surface boundary conditions were solved numerically for the full range of experimental variables that were examined. Based on this study, the following mechanism for bubble coalescence emerges: when two gas bubbles coalesce, the surface energy decreases as the curvature and surface area of the resultant bubble decrease, and the energy is imparted into the surrounding liquid. The initial motion is driven by the surface tension and slowed by the inertia and viscosity of the surrounding fluid. The initial velocity of the interface is approximately proportional to the square root of the surface tension and inversely proportional to the square root of the bubble radius. Fluid inertia sustains the oblate/prolate oscillations of the resultant bubble. The period of the oscillations varies with the bubble radius raised to the 3/2 power and inversely with the square root of the surface tension. Viscous resistance dampens the oscillations at a rate proportional to the viscosity and inversely proportional to the square of the bubble radius. The numerical simulations were consistent with most of the experimental results. The differences between the computed and measured saddle point decelerations and periods suggest that the surface tension in the experiments may have changed during each run. By adjusting the surface tension in the simulation, a good fit was obtained for the 150-{micro}m diameter bubbles. The simulations fit the experiments on larger bubbles with very little adjustment of surface tension. A more focused analysis should be done to elucidate the phenomena that occur in the receding liquid film immediately following rupture.

  6. Characterization of photosynthetic gas exchange in leaves under simulated adaxial and abaxial surfaces alternant irradiation.

    Science.gov (United States)

    Zhang, Zi-Shan; Li, Yu-Ting; Gao, Hui-Yuan; Yang, Cheng; Meng, Qing-Wei

    2016-07-05

    Previous investigations on photosynthesis have been performed on leaves irradiated from the adaxial surface. However, leaves usually sway because of wind. This action results in the alternating exposure of both the adaxial and abaxial surfaces to bright sunlight. To simulate adaxial and abaxial surfaces alternant irradiation (ad-ab-alt irradiation), the adaxial or abaxial surface of leaves were exposed to light regimes that fluctuated between 100 and 1,000 μmol m(-2) s(-1). Compared with constant adaxial irradiation, simulated ad-ab-alt irradiation suppressed net photosynthetic rate (Pn) and transpiration (E) but not water use efficiency. These suppressions were aggravated by an increase in alternant frequency of the light intensity. When leaves were transferred from constant light to simulated ad-ab-alt irradiation, the maximum Pn and E during the high light period decreased, but the rate of photosynthetic induction during this period remained constant. The sensitivity of photosynthetic gas exchange to simulated ad-ab-alt irradiation was lower on abaxial surface than adaxial surface. Under simulated ad-ab-alt irradiation, higher Pn and E were measured on abaxial surface compared with adaxial surface. Therefore, bifacial leaves can fix more carbon than leaves with two "sun-leaf-like" surfaces under ad-ab-alt irradiation. Photosynthetic research should be conducted under dynamic conditions that better mimic nature.

  7. Orientation-free and differentially pumped addition of a low-flux reactive gas beam to a surface analysis system.

    Science.gov (United States)

    Harthcock, Colin; Jahanbekam, Abdolreza; Eskelsen, Jeremy R; Lee, David Y

    2016-11-01

    We describe an example of a piecewise gas chamber that can be customized to incorporate a low flux of gas-phase radicals with an existing surface analysis chamber for in situ and stepwise gas-surface interaction experiments without any constraint in orientation. The piecewise nature of this gas chamber provides complete angular freedom and easy alignment and does not require any modification of the existing surface analysis chamber. In addition, the entire gas-surface system is readily differentially pumped with the surface chamber kept under ultra-high-vacuum during the gas-surface measurements. This new design also allows not only straightforward reconstruction to accommodate the orientation of different surface chambers but also for the addition of other desired features, such as an additional pump to the current configuration. Stepwise interaction between atomic oxygen and a highly ordered pyrolytic graphite surface was chosen to test the effectiveness of this design, and the site-dependent O-atom chemisorption and clustering on the graphite surface were resolved by a scanning tunneling microscope in the nm-scale. X-ray photoelectron spectroscopy was used to further confirm the identity of the chemisorbed species on the graphite surface as oxygen.

  8. Experimental Study of gas-liquid two-phase flow affected by wall surface wettability

    International Nuclear Information System (INIS)

    Takamasa, T.; Hazuku, T.; Hibiki, T.

    2008-01-01

    To evaluate the effect of wall surface wettability on the characteristics of upward gas-liquid two-phase flow in a vertical pipe, an experimental study was performed using three test pipes: an acrylic pipe, a hydrophilic pipe and a hydrophobic pipe. Basic flow characteristics such as flow patterns, pressure drop and void fraction were measured in these three pipes. In the hydrophilic pipe, a slug to churn flow transition boundary was shifted to a higher gas velocity at a given liquid velocity, whereas a churn to annular flow transition boundary was shifted to a lower gas velocity at a given liquid velocity. In the hydrophobic pipe, an inverted-churn flow regime was observed in the region where the churn flow regime was observed in the acrylic pipe, while a droplet flow regime was observed in the region where an annular flow regime was observed in the acrylic pipe. At a high gas flow rate, the mean void fraction in the hydrophobic pipe was higher than in the acrylic pipe. The effect of surface wettability on frictional pressure loss was confirmed to be insignificant under the present experimental conditions

  9. Sound propagation through a rarefied gas. Influence of the gas–surface interaction

    International Nuclear Information System (INIS)

    Kalempa, Denize; Sharipov, Felix

    2012-01-01

    Highlights: ► Non-equilibrium gas properties due to sound propagation. ► Influence of gas–surface accommodation coefficients. ► Heat transfer due to thermo-acoustic waves. ► Reciprocal relations. ► Range of validity of the Navier–Stokes equations. - Abstract: Acoustic waves propagating through a rarefied gas between two plates induced by both oscillation and unsteady heating of one of them are considered on the basis of a model of the linearized Boltzmann equation. The gas flow is considered as fully established so that the dependence of all quantities on time is harmonical. The problem is solved for several values of two main parameters determining its solution, namely, the gas rarefaction defined as the ratio of the distance between the plates to the equivalent free path of gaseous molecules, and the oscillation parameter given as the ratio of the intermolecular collision frequency to the wave frequency. The reciprocal relation for such flows is obtained and verified numerically. An influence of the gas–surface accommodation coefficients on the wave characteristics is analyzed by employing the Cercignani–Lampis scattering kernel to the boundary conditions.

  10. Modeling of liquid–gas meniscus for textured surfaces: effects of curvature and local slip length

    International Nuclear Information System (INIS)

    Gaddam, Anvesh; Garg, Mayank; Agrawal, Amit; Joshi, Suhas S

    2015-01-01

    Surface texturing at the micro/nanolevel allows air to be trapped in sufficiently small cavities, thereby reducing the flow resistance over the surface in the laminar regime. The nature of the liquid–gas meniscus plays an important role in defining the boundary condition and it depends on the flow conditions and geometrical properties of textures. In the present work, we employ the unsteady volume of fluid model to investigate the behavior of the liquid–gas meniscus for ridges arranged normal to the flow direction to substantiate the frictional resistance of flow in a microchannel. It is found that the assumption of ‘zero shear stress’ at the liquid–gas interface grossly overpredicts the effective slip length with meniscus curvature and local partial slip length playing the dominant role. Numerical simulations performed in the laminar regime (20  <  Re  <  120) over single layered ridges normal to the flow direction revealed the effect of texture geometry on the reduction in pressure drop. In single layered structures, lotus-like geometries exhibited a greater reduction in drag (more than 30%) when compared to all other texture geometries. It is recognized that the flow experiences expansion and contraction cycles as it flows over the transverse ridges increasing the frictional resistance. Our findings will help to modify the boundary condition at the liquid–gas meniscus for accurate modeling in the laminar regime and to optimize the texture geometry to improve drag reduction. (paper)

  11. Spontaneous tension haemopneumothorax.

    Science.gov (United States)

    Patterson, Benjamin Oliver; Itam, Sarah; Probst, Fey

    2008-10-31

    We present a patient with sudden onset progressive shortness of breath and no history of trauma, who rapidly became haemodynamically compromised with a pneumothorax and pleural effusion seen on chest radiograph. He was treated for spontaneous tension pneumothorax but this was soon revealed to be a tension haemopneumothorax. He underwent urgent thoracotomy after persistent bleeding to explore an apical vascular abnormality seen on CT scanning. To our knowledge this is the first such case reported.Aetiology and current approach to spontaneous haemothorax are discussed briefly.

  12. Spontaneous tension haemopneumothorax

    Directory of Open Access Journals (Sweden)

    Itam Sarah

    2008-10-01

    Full Text Available Abstract We present a patient with sudden onset progressive shortness of breath and no history of trauma, who rapidly became haemodynamically compromised with a pneumothorax and pleural effusion seen on chest radiograph. He was treated for spontaneous tension pneumothorax but this was soon revealed to be a tension haemopneumothorax. He underwent urgent thoracotomy after persistent bleeding to explore an apical vascular abnormality seen on CT scanning. To our knowledge this is the first such case reported. Aetiology and current approach to spontaneous haemothorax are discussed briefly.

  13. Headspace analysis gas-phase infrared spectroscopy: a study of xanthate decomposition on mineral surfaces

    Science.gov (United States)

    Vreugdenhil, Andrew J.; Brienne, Stephane H. R.; Markwell, Ross D.; Butler, Ian S.; Finch, James A.

    1997-03-01

    The O-ethyldithiocarbonate (ethyl xanthate, CH 3CH 2OCS -2) anion is a widely used reagent in mineral processing for the separation of sulphide minerals by froth flotation. Ethyl xanthate interacts with mineral powders to produce a hydrophobic layer on the mineral surface. A novel infrared technique, headspace analysis gas-phase infrared spectroscopy (HAGIS) has been used to study the in situ thermal decomposition products of ethyl xanthate on mineral surfaces. These products include CS 2, COS, CO 2, CH 4, SO 2, and higher molecular weight alkyl-containing species. Decomposition pathways have been proposed with some information determined from 2H- and 13C-isotope labelling experiments.

  14. The final status of a metal surface after multipulse laser irradiation in an ambient gas

    International Nuclear Information System (INIS)

    Boulmer Leborgne, C.; Hermann, J.; Dubreuil, B.

    1993-11-01

    We have investigated the role of the ambient gas nature and pressure, and the influence of the laser pulse total duration and temporal shape in the coupling of the incident laser light of λ = 10.6μm wavelength to a metallic surface at intermediate laser intensities of 10 7 - 10 8 W/cm 2 . A plasma is accompanying then the action of the laser pulse. It is acting as an active moderator among laser beam and target thus determining the final status of the contact surface. (author). 11 refs, 6 figs

  15. Quantum state-resolved gas/surface reaction dynamics probed by reflection absorption infrared spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Chen Li [Department of Dynamics at Surfaces, Max Planck Institute for Biophysical Chemistry, Am Fassberg 11, Goettingen (Germany); Ueta, Hirokazu; Beck, Rainer D. [Laboratoire de Chimie Physique Moleculaire, Ecole Polytechnique Federale de Lausanne (Switzerland); Bisson, Regis [Aix-Marseille Universite, PIIM, CNRS, UMR 7345, 13397 Marseille (France)

    2013-05-15

    We report the design and characterization of a new molecular-beam/surface-science apparatus for quantum state-resolved studies of gas/surface reaction dynamics combining optical state-specific reactant preparation in a molecular beam by rapid adiabatic passage with detection of surface-bound reaction products by reflection absorption infrared spectroscopy (RAIRS). RAIRS is a non-invasive infrared spectroscopic detection technique that enables online monitoring of the buildup of reaction products on the target surface during reactant deposition by a molecular beam. The product uptake rate obtained by calibrated RAIRS detection yields the coverage dependent state-resolved reaction probability S({theta}). Furthermore, the infrared absorption spectra of the adsorbed products obtained by the RAIRS technique provide structural information, which help to identify nascent reaction products, investigate reaction pathways, and determine branching ratios for different pathways of a chemisorption reaction. Measurements of the dissociative chemisorption of methane on Pt(111) with this new apparatus are presented to illustrate the utility of RAIRS detection for highly detailed studies of chemical reactions at the gas/surface interface.

  16. Inverse gas chromatography as a method for determination of surface properties of binding materials

    Science.gov (United States)

    Yu, Jihai; Lu, Xiaolei; Yang, Chunxia; Du, Baoli; Wang, Shuxian; Ye, Zhengmao

    2017-09-01

    Inverse gas chromatography (IGC) is a promising measurement technique for investigating the surface properties of binding materials, which are the major influence element for the adsorption performance of superplasticizer. In this work, using the IGC method, blast furnace slag (BFS), sulphoaluminate cement (SAC) and portland cement (P·O) are employed to systematically evaluate the corresponding dispersive component (γsd), specific surface free energy (γsab), and acid-base properties. The obtained results show that γsd contributes to a major section of the surface free energy in the three binding materials, suggesting they are of a relatively low polarity. Compared to the two kinds of cements, the BFS possesses the highest dispersive and specific surface free energies (the values are 45.01 mJ/m2 and 11.68 mJ/m2, respectively), and also exhibits a wider distribution range of γsd, indicating their surfaces are heterogeneous. For acid-base properties, the results indicate the surfaces of three samples are basic in nature. In addition, the adsorption investigation shows that per unit surface of BFS adsorbs the most superplasticizer molecules, which indicates the higher surface free energies is beneficial to the superplasticizer adsorption.

  17. Adsorption Mechanism of Inhibitor and Guest Molecules on the Surface of Gas Hydrates.

    Science.gov (United States)

    Yagasaki, Takuma; Matsumoto, Masakazu; Tanaka, Hideki

    2015-09-23

    The adsorption of guest and kinetic inhibitor molecules on the surface of methane hydrate is investigated by using molecular dynamics simulations. We calculate the free energy profile for transferring a solute molecule from bulk water to the hydrate surface for various molecules. Spherical solutes with a diameter of ∼0.5 nm are significantly stabilized at the hydrate surface, whereas smaller and larger solutes exhibit lower adsorption affinity than the solutes of intermediate size. The range of the attractive force is subnanoscale, implying that this force has no effect on the macroscopic mass transfer of guest molecules in crystal growth processes of gas hydrates. We also examine the adsorption mechanism of a kinetic hydrate inhibitor. It is found that a monomer of the kinetic hydrate inhibitor is strongly adsorbed on the hydrate surface. However, the hydrogen bonding between the amide group of the inhibitor and water molecules on the hydrate surface, which was believed to be the driving force for the adsorption, makes no contribution to the adsorption affinity. The preferential adsorption of both the kinetic inhibitor and the spherical molecules to the surface is mainly due to the entropic stabilization arising from the presence of cavities at the hydrate surface. The dependence of surface affinity on the size of adsorbed molecules is also explained by this mechanism.

  18. A theoretical and experimental investigation of the interaction between gas molecules and cryogenic surfaces

    International Nuclear Information System (INIS)

    Varlam, M.; Steflea, D.; Chiriloaie, N.

    1992-01-01

    The cryo-pumping performance of a cryo-surface subjected to the impingement of low-pressure, thermal-velocity air flow is experimentally and theoretically investigated. Our purpose is to determine the angular dependence of capture coefficients for gas molecules incident on a cryogenic surface under conditions closely approximating those prevailing in cryo-pumped high vacuum chambers. The classical model for the interaction of gas atoms and the solid surface - the 'soft-tube' model - is developed and the basic assumption are examined. Starting from this theory we have calculated the capture coefficient of the Ag - N system and these values are discussed in terms of principal parameters considered. Despite the many simplifying assumptions, this model has the important attribute that it yields closed-form expressions for the capture coefficient of gas molecules. The molecular beam technique offers a direct experimental method for determining the capture coefficient for molecules with given angles of incidence by measuring the incident and reflected molecular fluxes. An experimental setup is also designed and the method for determining these coefficients is proposed. (Author)

  19. Modelling for near-surface interaction of lithium ceramics and sweep-gas by use of cellular automation

    International Nuclear Information System (INIS)

    Shimura, K.; Terai, T.; Yamawaki, M.; Yamaguchi, K.

    2003-01-01

    Tritium release from the lithium ceramics as a fusion reactor breeder material is strongly affected by the composition of the sweep-gas as result of its influences with the material's surface. The typical surface processes which play important roles are adsorption, desorption and interaction between vacancy site and the constituents of the sweep-gas. Among a large number of studies and models, yet it seems to be difficult to model the overall behaviour of those processes due to its complex time-transient nature. In the present work the coarse grained atomic simulation based on the Cellular Automaton (CA) is used to model the dynamics of near-surface interaction between Li 2 O surface and sweep-gas that is consisting of a noble gas, hydrogen gas and water vapour. (author)

  20. Heat transfer tests of ribbed surfaces for gas-cooled reactors

    International Nuclear Information System (INIS)

    Klepper, O.H.

    1975-07-01

    The performance of gas-cooled reactors is often limited by the heat transfer in the reactor core. Means for modifying core heat transfer surfaces to improve their performance were investigated. The 0.3-in.-OD stainless steel clad heater rods were photo-etched to produce external ribs 0.006 in. high and 0.12 in. wide with a pitch of 0.072 in. Helical ribs with a helix angle of 37 0 (to promote interchannel flow mixing in a multirod array) were provided on one surface. For comparison purposes, a transversely ribbed surface and a smooth rod were also studied. The test surfaces were 49 in. long with a 24-in. heated region, concentrically arranged inside a smooth 0.602-in.-ID stainless steel tube. Nitrogen gas at pressures up to 400 psig was used as the coolant; the linear heat rating ranged to 6.8 kW/ft at surface temperatures up to 1400 0 F; T/sub w/T/sub b/ varied from 1.2 to 2.4 at Re values up to 450,000. Annulus results were recalculated for rod geometry using two different transformations. Good agreement was observed with applicable literature values. The effectiveness of the surfaces was assessed as the ratio E of the heat transfer coefficients of the roughened rods to that of a smooth rod at the same pumping power. The effectiveness of the spiral ribs ranged from 1.3 to 1.4, and from 1.2 to 1.4 for the transverse ribs, spanning Re values from 60,000 to 400,000. These data include variations introduced by alternate transformation methods that were used to make annulus test results applicable to rod geometry. The surfaces investigated in these tests were considered for fast gas-cooled reactors; however, the range of parameters studied also applies to heat transfer from ribbed rod-type fuel elements in thermal gas-cooled reactors. (U.S.)

  1. Creating Tension in Writing.

    Science.gov (United States)

    Folta, Bernarr

    This paper discusses the rationale and teaching methods for a six-week unit, for a high school freshman English Class, on perception, semantics, and writing, which places special focus on developing tension in student writing. The first four objectives of the course focus on perception and the next two focus on semantics. The seventh…

  2. Tension-filled Governance?

    DEFF Research Database (Denmark)

    Celik, Tim Holst

    on the statesituated tension-filled functional relationship between legitimation and accumulation, the study both historically and theoretically reworks this approach and reapplies it for the post-1970s/1990s governance period. It asks whether and to what extent governance has served as a distinctive post- 1970s/1990s...

  3. Rein tension during canter

    NARCIS (Netherlands)

    Egenvall, Agneta; Eisersiö, Marie; Rhodin, Marie; van Weeren, P.R.; Roepstorff, Lars

    2015-01-01

    Riders generally use reins as a means for communication with the horse. At present, the signalling pattern is poorly understood. The aim of this study was to illustrate and analyse the rein tension patterns in a number of rider/horse combinations across a variety of exercises in the canter gait. Our

  4. Optic nerve oxygen tension

    DEFF Research Database (Denmark)

    Kiilgaard, Jens Folke; Pedersen, D B; Eysteinsson, T

    2004-01-01

    The authors have previously reported that carbonic anhydrase inhibitors such as acetazolamide and dorzolamide raise optic nerve oxygen tension (ONPO(2)) in pigs. The purpose of the present study was to investigate whether timolol, which belongs to another group of glaucoma drugs called beta...

  5. Microstructure and erosion characteristic of nodular cast iron surface modified by tungsten inert gas

    International Nuclear Information System (INIS)

    Abboud, Jaafar Hadi

    2012-01-01

    Highlights: ► Local surface melting. ► Significant improvement in erosion resistance. ► The ductile behaviour was found. -- Abstract: The surface of nodular cast iron has been melted and rapidly solidified by Tungsten Inert Gas (TIG) process to produce a chilled structure of high hardness and better erosion resistance. Welding currents of magnitude 100, 150, and 200 A at a constant voltage of 72 have been used to melt the surface of nodular cast iron. Microstructural characterization, hardness measurements, and erosion wear tests have been performed on these modified surfaces as well as on the untreated material. Microstructural characterization has shown that surface melting resulted in complete or partial dissolution of the graphite nodules and resolidification of primary austenite dendrites, which undergo further decomposition into ferrite and cementite, and interdendritic of acicular eutectic; their microhardness measured across the melted depth ranged between 600 and 800 Hv. The scale of the dendrites and the interdendritic eutectic became coarser when a higher current is used. The results also indicated that remelting process by TIG improved erosion resistance by three to four times. Eroded surface observations of the as-received and TIG melted samples showed a ductile behavior with a maximum erosion rate at 30°. The fine microstructures obtained by the rapid cooling and the formation of a large amount of eutectic cementite instead of the graphite have contributed greatly to the plastic flow and consequently to the better erosion resistance of the TIG surface melted samples.

  6. The Assessment of Instruments for Detecting Surface Water Spills Associated with Oil and Gas Operations

    Energy Technology Data Exchange (ETDEWEB)

    Harris, Aubrey E. [West Virginia Univ., Morgantown, WV (United States); National Energy Technology Lab. (NETL), Morgantown, WV (United States); U.S. Bureau of Reclamation, Albuquerque, NM (United States); Hopkinson, Leslie [West Virginia Univ., Morgantown, WV (United States); Soeder, Daniel [National Energy Technology Lab. (NETL), Morgantown, WV (United States)

    2016-12-02

    Surface water and groundwater risks associated with unconventional oil and gas development result from potential spills of the large volumes of chemicals stored on-site during drilling and hydraulic fracturing operations, and the return to the surface of significant quantities of saline water produced during oil or gas well production. To better identify and mitigate risks, watershed models and tools are needed to evaluate the dispersion of pollutants in possible spill scenarios. This information may be used to determine the placement of in-stream water-quality monitoring instruments and to develop early-warning systems and emergency plans. A chemical dispersion model has been used to estimate the contaminant signal for in-stream measurements. Spills associated with oil and gas operations were identified within the Susquehanna River Basin Commission’s Remote Water Quality Monitoring Network. The volume of some contaminants was found to be sufficient to affect the water quality of certain drainage areas. The most commonly spilled compounds and expected peak concentrations at monitoring stations were used in laboratory experiments to determine if a signal could be detected and positively identified using standard water-quality monitoring equipment. The results were compared to historical data and baseline observations of water quality parameters, and showed that the chemicals tested do commonly affect water quality parameters. This work is an effort to demonstrate that hydrologic and water quality models may be applied to improve the placement of in-stream water quality monitoring devices. This information may increase the capability of early-warning systems to alert community health and environmental agencies of surface water spills associated with unconventional oil and gas operations.

  7. Process-based approach for the detection of deep gas invading the surface

    Science.gov (United States)

    Romanak, Katherine; Bennett, Philip C.

    2017-05-09

    The present invention includes a method for determining the level of deep gas in a near surface formation that includes: measuring CO.sub.2, O.sub.2, CH.sub.4, and N.sub.2 levels in percent by volume from one or more surface or near surface geological samples; adding the water vapor content to the measured CO.sub.2, O.sub.2, CH.sub.4, and N.sub.2 levels in percent by volume; normalizing the gas mixture to 100% by volume or 1 atmospheric total pressure; and determining the ratios of: O.sub.2 versus CO.sub.2 to distinguish in-situ vadose zone CO.sub.2 from exogenous deep leakage CO.sub.2; CO.sub.2 versus N.sub.2 to distinguish whether CO.sub.2 is being removed from the near surface formation or CO.sub.2 is added from an exogenous deep leakage input; or CO.sub.2 versus N.sub.2/O.sub.2 to determine the degree of oxygen influx, consumption, or both; wherein the ratios are indicative of natural in situ CO.sub.2 or CO.sub.2 from the exogenous deep leakage input.

  8. Surface modification and stability of detonation nanodiamonds in microwave gas discharge plasma

    International Nuclear Information System (INIS)

    Stanishevsky, Andrei V.; Walock, Michael J.; Catledge, Shane A.

    2015-01-01

    Graphical abstract: - Highlights: • Single and binary gas plasma modification of nanodiamond powders studied. • Temperature-dependent effect of N 2 and N 2 /H 2 plasma reported for the first time. • Role of H 2 in H 2 /N 2 and H 2 /O 2 plasma modification of nanodiamond discussed. - Abstract: Detonation nanodiamonds (DND), with low hydrogen content, were exposed to microwave plasma generated in pure H 2 , N 2 , and O 2 gases and their mixtures, and investigated using X-ray diffraction (XRD), Fourier Transform Infrared (FTIR), Raman, and X-ray photoelectron spectroscopies. Considerable alteration of the DND surface was observed under the plasma conditions for all used gases, but the diamond structure of the DND particle core was preserved in most cases. The stabilizing effect of H 2 in H 2 /N 2 and H 2 /O 2 binary gas plasmas on the DND structure and the temperature-dependent formation of various CNH x surface groups in N 2 and H 2 /N 2 plasmas were observed and discussed for the first time. DND surface oxidation and etching were the main effects of O 2 plasma, whereas the N 2 plasma led to DND surfaces rich in amide groups below 1073 K and nitrile groups at higher temperatures. Noticeable graphitization of the DND core structure was detected only in N 2 plasma when the substrate temperature was above 1103 K.

  9. Surfacing behavior and gas release of the physostome sprat (Sprattus sprattus) in ice-free and ice-covered waters

    KAUST Repository

    Solberg, Ingrid

    2013-10-04

    Upward-facing echosounders that provided continuous, long-term measurements were applied to address the surfacing behavior and gas release of the physostome sprat (Sprattus sprattus) throughout an entire winter in a 150-m-deep Norwegian fjord. During ice-free conditions, the sprat surfaced and released gas bubbles at night with an estimated surfacing rate of 3.5 times per fish day-1. The vertical swimming speeds during surfacing were considerably higher (~10 times) than during diel vertical migrations, especially when returning from the surface, and particularly when the fjord was not ice covered. The sprat released gas a few hours after surfacing, suggesting that the sprat gulped atmospheric air during its excursions to the surface. While the surface activity increased after the fjord became ice covered, the records of gas release decreased sharply. The under-ice fish then displayed a behavior interpreted as "searching for the surface" by repeatedly ascending toward the ice, apparently with limited success of filling the swim bladder. This interpretation was supported by lower acoustic target strength in ice-covered waters. The frequent surfacing behavior demonstrated in this study indicates that gulping of atmospheric air is an important element in the life of sprat. While at least part of the population endured overwintering in the ice-covered habitat, ice covering may constrain those physostome fishes that lack a gas-generating gland in ways that remain to be established. 2013 The Author(s).

  10. Coulomb string tension, asymptotic string tension, and the gluon chain

    OpenAIRE

    Greensite, Jeff; Szczepaniak, Adam P.

    2014-01-01

    We compute, via numerical simulations, the non-perturbative Coulomb potential of pure SU(3) gauge theory in Coulomb gauge. We find that that the Coulomb potential scales nicely in accordance with asymptotic freedom, that the Coulomb potential is linear in the infrared, and that the Coulomb string tension is about four times larger than the asymptotic string tension. We explain how it is possible that the asymptotic string tension can be lower than the Coulomb string tension by a factor of four.

  11. The influence of noble-gas ion bombardment on the electrical and optical properties of clean silicon surfaces

    International Nuclear Information System (INIS)

    Martens, J.W.D.

    1980-01-01

    A study of the effect of argon and helium ion bombardment on the electrical and optical properties of the clean silicon (211) surface is described. The objective of the study was to determine the effect of noble gas ions on the density of surface states at the clean silicon surface. (Auth.)

  12. Heat transfer from the roughened surface of gas cooled fast breeder reactor fuel element

    International Nuclear Information System (INIS)

    Tang, I.M.

    1979-01-01

    The temperature distributions and the augmentation of heat transfer performance by artificial roughening of a gas cooled fast breeder reactor (GCFR) fuel rod cladding are studied. Numerical solutions are based on the axisymmetric assumption for a two-dimensional model for one rib pitch of axial distance. The local and axial clad temperature distributions are obtained for both the rectangular and ramp rib roughened surface geometries. The transformation of experimentally measured convective heat transfer coefficients, in terms of Stanton number, into GCFR values is studied. In addition, the heat transfer performance of a GCFR fuel rod cladding roughened surface design is evaluated. Approximate analytical solution for correlating an average Stanton number is also obtained and satisfactorily compared with the corresponding numerical result for a GCFR design. The analytical correlation is useful in assessing roughened surface heat transfer performance in scoping studies and conceptual design

  13. The tension of framed membranes from computer simulations

    DEFF Research Database (Denmark)

    Hamkens, Daniel; Jeppesen, Claus; Ipsen, John H.

    2018-01-01

    the membranes display power-law characteristics for the equation of state, while higher tension levels includes both an extended linear (elastic) as well as a highly non-linear stretching regime. For semi-flexible membranes a transition from extended to buckled conformations takes place at negative frame......Abstract.: We have analyzed the behavior of a randomly triangulated, self-avoiding surface model of a flexible, fluid membrane subject to a circular boundary by Wang-Landau Monte Carlo computer simulation techniques. The dependence of the canonical free energy and frame tension on the frame area...... is obtained for flexible membranes. It is shown that for low bending rigidities the framed membrane is only stable above a threshold tension, suggesting a discontinuous transition from the collapsed (branched polymer) state to a finite tension extended state. In a tension range above this threshold tension...

  14. Tensão superficial estática de soluções aquosas com óleos minerais e vegetais utilizados na agricultura Surface tension of mineral oils and vegetable oils

    Directory of Open Access Journals (Sweden)

    Cristina G. de Mendonça

    2007-01-01

    Full Text Available O trabalho teve como objetivo avaliar a tensão superficial estática de soluções aquosas com formulações de óleos minerais e vegetais emulsionáveis utilizados como adjuvantes na agricultura. Os óleos minerais e vegetais, quando adicionados aos produtos fitossanitários, podem imprimir características desejáveis à calda de pulverização, como reduzir a tensão superficial em soluções aquosas, possibilitar maior contato da calda com a superfície vegetal ou reduzir o potencial de deriva durante as pulverizações. Foram testados os seguintes produtos comerciais: óleos minerais (Assist, Attach, Dytrol, Iharol, Mineral Oil, Spinner, Sunspray-E e Triona e óleos vegetais (Agrex'oil Vegetal, Crop Oil, Natur'l Óleo, Óleo Vegetal Nortox e Veget Oil, todos com registro de uso na agricultura. A tensão superficial das soluções aquosas foi avaliada em 11 concentrações para cada produto (0,025; 0,05; 0,1; 0,25; 0,5; 0,75; 1,0; 1,5; 2,0; 2,5 e 3,0% v/v. Essa propriedade dos óleos minerais e dos óleos vegetais foi estimada medindo-se a massa das gotas formadas na extremidade de uma bureta. Ao conjunto de dados obtidos para cada produto, na avaliação da tensão superficial, foram determinadas as análises de variância e de regressão, ajustando-se os dados ao Modelo de Mitscherlich. Entre os óleos minerais, destacaram-se os produtos: Assist, Dytrol, Iharol e Mineral Oil por apresentarem as menores tensões superficiais mínimas estimadas pelo Modelo, respectivamente, 29,255; 28,442; 26,097 e 28,584 mN m-1. Os óleos vegetais que apresentaram os menores valores de tensão superficial mínima estimados pelo Modelo, foram: Agrex' oil Vegetal (27,716 mN m-1, Natur'l óleo (28,216 mN m-1, Veget Oil (27,308 mN m-1 e Crop Oil (29,964 mN m-1.The aim of this work was to evaluate the surface tension of water emulsion with mineral oils and vegetable oils used as adjuvant. The mineral and vegetable oils when added to the agrochemicals can

  15. Adsorption of SF6 decomposed gas on anatase (101) and (001) surfaces with oxygen defect: A density functional theory study

    Science.gov (United States)

    Zhang, Xiaoxing; Chen, Qinchuan; Tang, Ju; Hu, Weihua; Zhang, Jinbin

    2014-01-01

    The detection of partial discharge by analyzing the components of SF6 gas in gas-insulated switchgears is important to the diagnosis and assessment of the operational state of power equipment. A gas sensor based on anatase TiO2 is used to detect decomposed gases in SF6. In this paper, first-principle density functional theory calculations are adopted to analyze the adsorption of SO2, SOF2, and SO2F2, the primary decomposition by-products of SF6 under partial discharge, on anatase (101) and (001) surfaces. Simulation results show that the perfect anatase (001) surface has a stronger interaction with the three gases than that of anatase (101), and both surfaces are more sensitive and selective to SO2 than to SOF2 and SO2F2. The selection of a defect surface to SO2, SOF2, and SO2F2 differs from that of a perfect surface. This theoretical result is corroborated by the sensing experiment using a TiO2 nanotube array (TNTA) gas sensor. The calculated values are analyzed to explain the results of the Pt-doped TNTA gas sensor sensing experiment. The results imply that the deposited Pt nanoparticles on the surface increase the active sites of the surface and the gas molecules may decompose upon adsorption on the active sites. PMID:24755845

  16. Surface-Induced Near-Field Scaling in the Knudsen Layer of a Rarefied Gas

    Science.gov (United States)

    Gazizulin, R. R.; Maillet, O.; Zhou, X.; Cid, A. Maldonado; Bourgeois, O.; Collin, E.

    2018-01-01

    We report on experiments performed within the Knudsen boundary layer of a low-pressure gas. The noninvasive probe we use is a suspended nanoelectromechanical string, which interacts with He 4 gas at cryogenic temperatures. When the pressure P is decreased, a reduction of the damping force below molecular friction ∝P had been first reported in Phys. Rev. Lett. 113, 136101 (2014), 10.1103/PhysRevLett.113.136101 and never reproduced since. We demonstrate that this effect is independent of geometry, but dependent on temperature. Within the framework of kinetic theory, this reduction is interpreted as a rarefaction phenomenon, carried through the boundary layer by a deviation from the usual Maxwell-Boltzmann equilibrium distribution induced by surface scattering. Adsorbed atoms are shown to play a key role in the process, which explains why room temperature data fail to reproduce it.

  17. Universal gas metal arc welding - a cost-effective and low dilution surfacing process

    International Nuclear Information System (INIS)

    Shahi, AS.; Pandey, Sunil

    2006-01-01

    This paper describes the use of a new variant of the gas metal arc welding (GMAW) process, termed u niversal gas metal arc welding (UGMAW), for the weld cladding of low carbon steels with stainless steel. The experimental work included single layer cladding of 12 mm thick low carbon steel with austenitic stainless steel 316L solid filler wire of 1.14 mm diameter. Low dilution conditions were employed using both mechanised GMAW and UGMAW processes. Metallurgical aspects of the as welded overlays were studied to evaluate the suitability of these processes for service conditions. It was found that UGMAW claddings contained higher ferrite content; higher concentrations of chromium, nickel and molybdenum; and lower carbon content compared to GMAW claddings. As a result, the UGMAW overlays exhibited superior mechanical and corrosion resistance properties. The findings of this study establish that the new process is technically superior and results in higher productivity, justifying its use for low cost surfacing applications

  18. Linking otolith microchemistry and surface water contamination from natural gas mining.

    Science.gov (United States)

    Keller, David H; Zelanko, Paula M; Gagnon, Joel E; Horwitz, Richard J; Galbraith, Heather S; Velinsky, David J

    2018-09-01

    Unconventional natural gas drilling and the use of hydraulic fracturing technology have expanded rapidly in North America. This expansion has raised concerns of surface water contamination by way of spills and leaks, which may be sporadic, small, and therefore difficult to detect. Here we explore the use of otolith microchemistry as a tool for monitoring surface water contamination from generated waters (GW) of unconventional natural gas drilling. We exposed Brook Trout in the laboratory to three volumetric concentrations of surrogate generated water (SGW) representing GW on day five of drilling. Transects across otolith cross-sections were analyzed for a suite of elements by LA-ICP-MS. Brook Trout exposed to a 0.01-1.0% concentration of SGW for 2, 15, and 30 days showed a significant (p waters and provide support for the use of this technique in natural habitats. To our knowledge, this is the first demonstration of how trace elements in fish otoliths may be used to monitor for surface water contamination from GW. Copyright © 2018 Elsevier Ltd. All rights reserved.

  19. Evaluation of surface dose rate on C-14 scrubber and gas bag

    International Nuclear Information System (INIS)

    Gang, D. W.; Lee, H. S.; Lee, D. H.

    2003-01-01

    In CANDU(Canadian Deuterium Uranium) reactors, purge and discharge of moderator cover gas has been performed via vapor recovery system. The methods employed in C-14 removal are mainly based on reactions of CO 2 with absorber of adsorbent. In order to choose an optimum process, we should consider the characteristics of the process, such as, temperature, pressure, humidity etc. and surface dose rate on C-14 scrubber and gas bag to estimate job-related personnel doses. Assuming that the whole C-14 scrubber was completely replaced after one-cycle operation, and that its C-14 activity for one-cycle operation was 40 mCi, we calculated the surface dose rate at the six points of the C-14 scrubber. This calculation showed that the dose rate on the surface of cartridge was only 1.25μSυ/hγ because of low energy of β ray. It is concluded, therefore, that the cartridge change-out is safe because the operation of C-14 removal system causes only a small increase in dose rate

  20. New sensitive micro-measurements of dynamic surface tension and diffusion coefficients: Validated and tested for the adsorption of 1-Octanol at a microscopic air-water interface and its dissolution into water.

    Science.gov (United States)

    Kinoshita, Koji; Parra, Elisa; Needham, David

    2017-02-15

    Currently available dynamic surface tension (DST) measurement methods, such as Wilhelmy plate, droplet- or bubble-based methods, still have various experimental limitations such as the large size of the interface, convection in the solution, or a certain "dead time" at initial measurement. These limitations create inconsistencies for the kinetic analysis of surfactant adsorption/desorption, especially significant for ionic surfactants. Here, the "micropipette interfacial area-expansion method" was introduced and validated as a new DST measurement having a high enough sensitivity to detect diffusion controlled molecular adsorption at the air-water interfaces. To validate the new technique, the diffusion coefficient of 1-Octanol in water was investigated with existing models: the Ward Tordai model for the long time adsorption regime (1-100s), and the Langmuir and Frumkin adsorption isotherm models for surface excess concentration. We found that the measured diffusion coefficient of 1-Octanol, 7.2±0.8×10 -6 cm 2 /s, showed excellent agreement with the result from an alternative method, "single microdroplet catching method", to measure the diffusion coefficient from diffusion-controlled microdroplet dissolution, 7.3±0.1×10 -6 cm 2 /s. These new techniques for determining adsorption and diffusion coefficients can apply for a range of surface active molecules, especially the less-characterized ionic surfactants, and biological compounds such as lipids, peptides, and proteins. Copyright © 2016 Elsevier Inc. All rights reserved.

  1. Elastic-Plastic J-Integral Solutions or Surface Cracks in Tension Using an Interpolation Methodology. Appendix C -- Finite Element Models Solution Database File, Appendix D -- Benchmark Finite Element Models Solution Database File

    Science.gov (United States)

    Allen, Phillip A.; Wells, Douglas N.

    2013-01-01

    No closed form solutions exist for the elastic-plastic J-integral for surface cracks due to the nonlinear, three-dimensional nature of the problem. Traditionally, each surface crack must be analyzed with a unique and time-consuming nonlinear finite element analysis. To overcome this shortcoming, the authors have developed and analyzed an array of 600 3D nonlinear finite element models for surface cracks in flat plates under tension loading. The solution space covers a wide range of crack shapes and depths (shape: 0.2 less than or equal to a/c less than or equal to 1, depth: 0.2 less than or equal to a/B less than or equal to 0.8) and material flow properties (elastic modulus-to-yield ratio: 100 less than or equal to E/ys less than or equal to 1,000, and hardening: 3 less than or equal to n less than or equal to 20). The authors have developed a methodology for interpolating between the goemetric and material property variables that allows the user to reliably evaluate the full elastic-plastic J-integral and force versus crack mouth opening displacement solution; thus, a solution can be obtained very rapidly by users without elastic-plastic fracture mechanics modeling experience. Complete solutions for the 600 models and 25 additional benchmark models are provided in tabular format.

  2. Surfacing behavior and gas release of the physostome sprat (Sprattus sprattus) in ice-free and ice-covered waters

    KAUST Repository

    Solberg, Ingrid; Kaartvedt, Stein

    2013-01-01

    Upward-facing echosounders that provided continuous, long-term measurements were applied to address the surfacing behavior and gas release of the physostome sprat (Sprattus sprattus) throughout an entire winter in a 150-m-deep Norwegian fjord

  3. The boundary condition for vertical velocity and its interdependence with surface gas exchange

    Science.gov (United States)

    Kowalski, Andrew S.

    2017-07-01

    The law of conservation of linear momentum is applied to surface gas exchanges, employing scale analysis to diagnose the vertical velocity (w) in the boundary layer. Net upward momentum in the surface layer is forced by evaporation (E) and defines non-zero vertical motion, with a magnitude defined by the ratio of E to the air density, as w = E/ρ. This is true even right down at the surface where the boundary condition is w|0 = E/ρ|0 (where w|0 and ρ|0 represent the vertical velocity and density of air at the surface). This Stefan flow velocity implies upward transport of a non-diffusive nature that is a general feature of the troposphere but is of particular importance at the surface, where it assists molecular diffusion with upward gas migration (of H2O, for example) but opposes that of downward-diffusing species like CO2 during daytime. The definition of flux-gradient relationships (eddy diffusivities) requires rectification to exclude non-diffusive transport, which does not depend on scalar gradients. At the microscopic scale, the role of non-diffusive transport in the process of evaporation from inside a narrow tube - with vapour transport into an overlying, horizontal airstream - was described long ago in classical mechanics and is routinely accounted for by chemical engineers, but has been neglected by scientists studying stomatal conductance. Correctly accounting for non-diffusive transport through stomata, which can appreciably reduce net CO2 transport and marginally boost that of water vapour, should improve characterisations of ecosystem and plant functioning.

  4. The boundary condition for vertical velocity and its interdependence with surface gas exchange

    Directory of Open Access Journals (Sweden)

    A. S. Kowalski

    2017-07-01

    Full Text Available The law of conservation of linear momentum is applied to surface gas exchanges, employing scale analysis to diagnose the vertical velocity (w in the boundary layer. Net upward momentum in the surface layer is forced by evaporation (E and defines non-zero vertical motion, with a magnitude defined by the ratio of E to the air density, as w = E/ρ. This is true even right down at the surface where the boundary condition is w|0 = E/ρ|0 (where w|0 and ρ|0 represent the vertical velocity and density of air at the surface. This Stefan flow velocity implies upward transport of a non-diffusive nature that is a general feature of the troposphere but is of particular importance at the surface, where it assists molecular diffusion with upward gas migration (of H2O, for example but opposes that of downward-diffusing species like CO2 during daytime. The definition of flux–gradient relationships (eddy diffusivities requires rectification to exclude non-diffusive transport, which does not depend on scalar gradients. At the microscopic scale, the role of non-diffusive transport in the process of evaporation from inside a narrow tube – with vapour transport into an overlying, horizontal airstream – was described long ago in classical mechanics and is routinely accounted for by chemical engineers, but has been neglected by scientists studying stomatal conductance. Correctly accounting for non-diffusive transport through stomata, which can appreciably reduce net CO2 transport and marginally boost that of water vapour, should improve characterisations of ecosystem and plant functioning.

  5. Protein conformational transitions at the liquid-gas interface as studied by dilational surface rheology.

    Science.gov (United States)

    Noskov, Boris A

    2014-04-01

    Experimental results on the dynamic dilational surface elasticity of protein solutions are analyzed and compared. Short reviews of the protein behavior at the liquid-gas interface and the dilational surface rheology precede the main sections of this work. The kinetic dependencies of the surface elasticity differ strongly for the solutions of globular and non-globular proteins. In the latter case these dependencies are similar to those for solutions of non-ionic amphiphilic polymers and have local maxima corresponding to the formation of the distal region of the surface layer (type I). In the former case the dynamic surface elasticity is much higher (>60 mN/m) and the kinetic dependencies are monotonical and similar to the data for aqueous dispersions of solid nanoparticles (type II). The addition of strong denaturants to solutions of bovine serum albumin and β-lactoglobulin results in an abrupt transition from the type II to type I dependencies if the denaturant concentration exceeds a certain critical value. These results give a strong argument in favor of the preservation of the protein globular structure in the course of adsorption without any denaturants. The addition of cationic surfactants also can lead to the non-monotonical kinetic dependencies of the dynamic surface elasticity indicating destruction of the protein tertiary and secondary structures. The addition of anionic surfactants gives similar results only for the protein solutions of high ionic strength. The influence of cationic surfactants on the local maxima of the kinetic dependencies of the dynamic surface elasticity for solutions of a non-globular protein (β-casein) differs from the influence of anionic surfactants due to the heterogeneity of the charge distribution along the protein chain. In this case one can use small admixtures of ionic surfactants as probes of the adsorption mechanism. The effect of polyelectrolytes on the kinetic dependencies of the dynamic surface elasticity of protein

  6. Molecule-surface interaction processes of relevance to gas blanket type fusion device divertor design

    Energy Technology Data Exchange (ETDEWEB)

    Snowdon, K.J. [Newcastle Univ. (United Kingdom). Dept. of Physics; Tawara, H.

    1997-01-01

    The mechanisms which may lead to the departure of molecular species from surfaces exposed to low energy (0.1-100 eV) particle or photon and electron irradiation are reviewed. Where possible, the charge and electronic state, angular, translational and internal energy distributions of the departing molecules are described and the physical origin of the nature of those distributions identified. The consequences, for the departing molecules, of certain material choices become apparent from such an analysis. Such information may help guide the choice of appropriate materials for plasma facing components of gas-blanket type divertors such as that recently proposed for the International Thermonuclear Experimental Reactor (ITER). (author). 71 refs.

  7. Transitions of tethered chain molecules under tension.

    Science.gov (United States)

    Luettmer-Strathmann, Jutta; Binder, Kurt

    2014-09-21

    An applied tension force changes the equilibrium conformations of a polymer chain tethered to a planar substrate and thus affects the adsorption transition as well as the coil-globule and crystallization transitions. Conversely, solvent quality and surface attraction are reflected in equilibrium force-extension curves that can be measured in experiments. To investigate these effects theoretically, we study tethered chains under tension with Wang-Landau simulations of a bond-fluctuation lattice model. Applying our model to pulling experiments on biological molecules we obtain a good description of experimental data in the intermediate force range, where universal features dominate and finite size effects are small. For tethered chains in poor solvent, we observe the predicted two-phase coexistence at transitions from the globule to stretched conformations and also discover direct transitions from crystalline to stretched conformations. A phase portrait for finite chains constructed by evaluating the density of states for a broad range of solvent conditions and tensions shows how increasing tension leads to a disappearance of the globular phase. For chains in good solvents tethered to hard and attractive surfaces we find the predicted scaling with the chain length in the low-force regime and show that our results are well described by an analytical, independent-bond approximation for the bond-fluctuation model for the highest tensions. Finally, for a hard or slightly attractive surface the stretching of a tethered chain is a conformational change that does not correspond to a phase transition. However, when the surface attraction is sufficient to adsorb a chain it will undergo a desorption transition at a critical value of the applied force. Our results for force-induced desorption show the transition to be discontinuous with partially desorbed conformations in the coexistence region.

  8. A method of surface area measurement of fuel materials by fission gas release at low temperature

    International Nuclear Information System (INIS)

    Kaimal, K.N.G.; Naik, M.C.; Paul, A.R.; Venkateswarlu, K.S.

    1989-01-01

    The present report deals with the development of a method for surface area measurement of nuclear fuel as well as fissile doped materials by fission gas release study at low temperature. The method is based on the evaluation of knock-out release rate of fission 133 Xe from irradiated fuel after sufficient cooling to decay the short lived activity. The report also describes the fabrication of an ampoule breaker unit for such study. Knock-out release rate of 133 Xe has been studied from UO 2 powders having varying surface area 'S' ranging from 270 cm 2 /gm to 4100 cm 2 /gm at two fissioning rates 10 12 f/cm 3 . sec. and 3.2x10 10 f/cm.sec. A relation between K and A has been established and discussed in this report. (author). 6 refs

  9. Surface modification and stability of detonation nanodiamonds in microwave gas discharge plasma

    Energy Technology Data Exchange (ETDEWEB)

    Stanishevsky, Andrei V., E-mail: astan@uab.edu; Walock, Michael J.; Catledge, Shane A.

    2015-12-01

    Graphical abstract: - Highlights: • Single and binary gas plasma modification of nanodiamond powders studied. • Temperature-dependent effect of N{sub 2} and N{sub 2}/H{sub 2} plasma reported for the first time. • Role of H{sub 2} in H{sub 2}/N{sub 2} and H{sub 2}/O{sub 2} plasma modification of nanodiamond discussed. - Abstract: Detonation nanodiamonds (DND), with low hydrogen content, were exposed to microwave plasma generated in pure H{sub 2}, N{sub 2}, and O{sub 2} gases and their mixtures, and investigated using X-ray diffraction (XRD), Fourier Transform Infrared (FTIR), Raman, and X-ray photoelectron spectroscopies. Considerable alteration of the DND surface was observed under the plasma conditions for all used gases, but the diamond structure of the DND particle core was preserved in most cases. The stabilizing effect of H{sub 2} in H{sub 2}/N{sub 2} and H{sub 2}/O{sub 2} binary gas plasmas on the DND structure and the temperature-dependent formation of various CNH{sub x} surface groups in N{sub 2} and H{sub 2}/N{sub 2} plasmas were observed and discussed for the first time. DND surface oxidation and etching were the main effects of O{sub 2} plasma, whereas the N{sub 2} plasma led to DND surfaces rich in amide groups below 1073 K and nitrile groups at higher temperatures. Noticeable graphitization of the DND core structure was detected only in N{sub 2} plasma when the substrate temperature was above 1103 K.

  10. Modification of Low-Alloy Steel Surface by High-Temperature Gas Nitriding Plus Tempering

    Science.gov (United States)

    Jiao, Dongling; Li, Minsong; Ding, Hongzhen; Qiu, Wanqi; Luo, Chengping

    2018-02-01

    The low-alloy steel was nitrided in a pure NH3 gas atmosphere at 640 660 °C for 2 h, i.e., high-temperature gas nitriding (HTGN), followed by tempering at 225 °C, which can produce a high property surface coating without brittle compound (white) layer. The steel was also plasma nitriding for comparison. The composition, microstructure and microhardness of the nitrided and tempered specimens were examined, and their tribological behavior investigated. The results showed that the as-gas-nitrided layer consisted of a white layer composed of FeN0.095 phase (nitrided austenite) and a diffusional zone underneath the white layer. After tempering, the white layer was decomposed to a nano-sized (α-Fe + γ'-Fe4N + retained austenite) bainitic microstructure with a high hardness of 1150HV/25 g. Wear test results showed that the wear resistance and wear coefficient yielded by the complex HTGN plus tempering were considerably higher and lower, respectively, than those produced by the conventional plasma nitriding.

  11. Soil Erosion and Surface Water Quality Impacts of Natural Gas Development in East Texas, USA

    Directory of Open Access Journals (Sweden)

    Matthew McBroom

    2012-11-01

    Full Text Available Due to greater demands for hydrocarbons and improvements in drilling technology, development of oil and natural gas in some regions of the United States has increased dramatically. A 1.4 ha natural gas well pad was constructed in an intermittent stream channel at the Alto Experimental Watersheds in East Texas, USA (F1, while another 1.1 ha well pad was offset about 15 m from a nearby intermittent stream (F2. V-notch weirs were constructed downstream of these well pads and stream sedimentation and water quality was measured. For the 2009 water year, about 11.76 cm, or almost 222% more runoff resulted from F1 than F2. Sediment yield was significantly greater at F1, with 13,972 kg ha−1 yr−1 versus 714 kg ha−1yr−1 at F2 on a per unit area disturbance basis for the 2009 water year. These losses were greater than was observed following forest clearcutting with best management practices (111–224 kg ha−1. Significantly greater nitrogen and phosphorus losses were measured at F1 than F2. While oil and gas development can degrade surface water quality, appropriate conservation practices like retaining streamside buffers can mitigate these impacts.

  12. Gas

    International Nuclear Information System (INIS)

    1996-01-01

    The French government has decided to modify the conditions of extension of local natural gas authorities to neighbouring districts. The European Union is studying the conditions of internal gas market with the objective of more open markets although considering public service requirements

  13. Characterization of the laser gas nitrided surface of NiTi shape memory alloy

    International Nuclear Information System (INIS)

    Cui, Z.D.; Man, H.C.; Yang, X.J.

    2003-01-01

    Owing to its unique properties such as shape memory effects, superelasticity and radiopacity, NiTi alloy is a valuable biomaterial for fabricating implants. The major concern of this alloy for biological applications is the high atomic percentage of nickel in the alloy and the deleterious effects to the body by the corrosion and/or wears products. In this study, a continuous wave Nd-YAG laser was used to conduct laser gas nitriding on the substrate of NiTi alloy. The results show that a continuous and crack-free thin TiN layer was produced in situ on the NiTi substrate. The characteristics of the nitrided surface layer were investigated using SEM, XRD, XPS and AAS. No nickel signal was detected on the top surface of the laser gas nitrided layer. As compared with the mechanical polished NiTi alloy, the nickel ion release rate out of the nitrided NiTi alloy decreased significantly in Hanks' solution at 37 deg. C, especially the initial release rate

  14. GAS SURFACE DENSITY, STAR FORMATION RATE SURFACE DENSITY, AND THE MAXIMUM MASS OF YOUNG STAR CLUSTERS IN A DISK GALAXY. II. THE GRAND-DESIGN GALAXY M51

    International Nuclear Information System (INIS)

    González-Lópezlira, Rosa A.; Pflamm-Altenburg, Jan; Kroupa, Pavel

    2013-01-01

    We analyze the relationship between maximum cluster mass and surface densities of total gasgas ), molecular gas (Σ H 2 ), neutral gas (Σ H I ), and star formation rate (Σ SFR ) in the grand-design galaxy M51, using published gas data and a catalog of masses, ages, and reddenings of more than 1800 star clusters in its disk, of which 223 are above the cluster mass distribution function completeness limit. By comparing the two-dimensional distribution of cluster masses and gas surface densities, we find for clusters older than 25 Myr that M 3rd ∝Σ H I 0.4±0.2 , whereM 3rd is the median of the five most massive clusters. There is no correlation withΣ gas ,Σ H2 , orΣ SFR . For clusters younger than 10 Myr, M 3rd ∝Σ H I 0.6±0.1 and M 3rd ∝Σ gas 0.5±0.2 ; there is no correlation with either Σ H 2 orΣ SFR . The results could hardly be more different from those found for clusters younger than 25 Myr in M33. For the flocculent galaxy M33, there is no correlation between maximum cluster mass and neutral gas, but we have determined M 3rd ∝Σ gas 3.8±0.3 , M 3rd ∝Σ H 2 1.2±0.1 , and M 3rd ∝Σ SFR 0.9±0.1 . For the older sample in M51, the lack of tight correlations is probably due to the combination of strong azimuthal variations in the surface densities of gas and star formation rate, and the cluster ages. These two facts mean that neither the azimuthal average of the surface densities at a given radius nor the surface densities at the present-day location of a stellar cluster represent the true surface densities at the place and time of cluster formation. In the case of the younger sample, even if the clusters have not yet traveled too far from their birth sites, the poor resolution of the radio data compared to the physical sizes of the clusters results in measuredΣ that are likely quite diluted compared to the actual densities relevant for the formation of the clusters.

  15. Greenhouse gas emissions from beef cattle pen surfaces in North Dakota.

    Science.gov (United States)

    Rahman, Shafiqur; Borhan, Md Saidul; Swanson, Kendall

    2013-01-01

    There is a global interest to quantify and mitigate greenhouse gas (GHG) (e.g. methane-CH4, nitrous oxide-N2O and carbon dioxide-CO2) emissions in animal feeding operations. The goal of this study was to quantify GHG emissions from the feedlot pen surface under North Dakota climatic conditions. In this study gaseous flux from the pen surfaces was generated using a custom-made wind tunnel at different times of the year (summer, fall, winter and spring). Gaseous fluxes (air samples) were drawn in the Tedlar bags using a vacuum chamber and gas concentrations were measured using a gas chromatograph within 24 h of sampling. The CH4 concentrations and flux rates (FRs) or flux among the months were not significantly different. Overall CH4, CO2 and N2O concentrations over a 7-month period were 2.66, 452 and 0.67 ppm, respectively. Estimated overall CH4, CO and N2O FRs were 1.32, 602 and 0.90 g m(-2) d(-1), respectively. Estimated emission rates using the wind tunnel were 38 g hd(-1) d(-1), 17 kg hd(-1) d(-1) and 26 g hd(-1) d(-1) for CH4, CO2 and N2O, respectively. The emission factors for GHG estimated in the research for North Dakota climate were the first of its kind, and these emission estimates can be used as a basis for planning and implementing management practices to minimize GHG emissions.

  16. The costs of avoiding environmental impacts from shale-gas surface infrastructure.

    Science.gov (United States)

    Milt, Austin W; Gagnolet, Tamara D; Armsworth, Paul R

    2016-12-01

    Growing energy demand has increased the need to manage conflicts between energy production and the environment. As an example, shale-gas extraction requires substantial surface infrastructure, which fragments habitats, erodes soils, degrades freshwater systems, and displaces rare species. Strategic planning of shale-gas infrastructure can reduce trade-offs between economic and environmental objectives, but the specific nature of these trade-offs is not known. We estimated the cost of avoiding impacts from land-use change on forests, wetlands, rare species, and streams from shale-energy development within leaseholds. We created software for optimally siting shale-gas surface infrastructure to minimize its environmental impacts at reasonable construction cost. We visually assessed sites before infrastructure optimization to test whether such inspection could be used to predict whether impacts could be avoided at the site. On average, up to 38% of aggregate environmental impacts of infrastructure could be avoided for 20% greater development costs by spatially optimizing infrastructure. However, we found trade-offs between environmental impacts and costs among sites. In visual inspections, we often distinguished between sites that could be developed to avoid impacts at relatively low cost (29%) and those that could not (20%). Reductions in a metric of aggregate environmental impact could be largely attributed to potential displacement of rare species, sedimentation, and forest fragmentation. Planners and regulators can estimate and use heterogeneous trade-offs among development sites to create industry-wide improvements in environmental performance and do so at reasonable costs by, for example, leveraging low-cost avoidance of impacts at some sites to offset others. This could require substantial effort, but the results and software we provide can facilitate the process. © 2016 Society for Conservation Biology.

  17. Application of gas chromatography-surface ionization organic mass spectrometry to forensic toxicology.

    Science.gov (United States)

    Ishii, Akira; Watanabe-Suzuki, Kanako; Seno, Hiroshi; Suzuki, Osamu; Katsumata, Yoshinao

    2002-08-25

    Surface ionization (SI), which consists in the formation of positive and negative ions along the course of thermal desorption of particles from a solid surface, was first applied as a detector for gas chromatography (GC), GC-surface ionization detection (SID); we developed many new sensitive methods for the determination of abused and other drugs by GC-SID. Recently, Fujii has devised a combination of SI and a quadrupole mass spectrometer and named this system a surface ionization organic mass spectrometer (SIOMS), which is highly selective and sensitive for organic compounds containing tertiary amino groups. We have tried to apply this mass spectrometer to forensic toxicological study; so far we have succeeded in determining important drugs-of-abuse and toxic compounds, such as phencyclidine (PCP), pethidine, pentazocine, MPTP and its derivatives from human body fluids with high sensitivity and selectivity. In this review, we describe our recent studies on the application of GC-SIOMS to forensic toxicology. Copyright 2002 Elsevier Science B.V.

  18. Theoretical modeling and design of photonic structures in zeolite nanocomposites for gas sensing. Part I: surface relief gratings.

    Science.gov (United States)

    Cody, D; Naydenova, I

    2017-12-01

    The suitability of holographic structures fabricated in zeolite nanoparticle-polymer composite materials for gas sensing applications has been investigated. Theoretical modeling of the sensor response (i.e., change in hologram readout due to a change in refractive index modulation or thickness as a result of gas adsorption) of different sensor designs was carried out using Raman-Nath theory and Kogelnik's coupled wave theory. The influence of a range of parameters on the sensor response of holographically recorded surface and volume photonic grating structures has been studied, namely the phase difference between the diffracted and probe beam introduced by the grating, grating geometry, thickness, spatial frequency, reconstruction wavelength, and zeolite nanoparticle refractive index. From this, the optimum fabrication conditions for both surface and volume holographic gas sensor designs have been identified. Here, in part I, results from theoretical modeling of the influence of design on the sensor response of holographically inscribed surface relief structures for gas sensing applications is reported.

  19. Onset and stability of gas hydrates under permafrost in an environment of surface climatic change : past and future

    International Nuclear Information System (INIS)

    Majorowicz, J.A.; Osadetz, K.; Safanda, J.

    2008-01-01

    This paper presented a model designed to simulate permafrost and gas hydrate formation in a changing surface temperature environment in the Beaufort-Mackenzie Basin (BMB). The numerical model simulated surface forcing due to general cooling trends that began in the late Miocene era. This study modelled the onset of permafrost formation and subsequent gas hydrate formation in the changing surface temperature environment for the BMB. Paleoclimatic data were used. The 1-D model was constrained by deep heat flow from well bottom hole temperatures; conductivity; permafrost thickness; and the thickness of the gas hydrates. The model used latent heat effects for the ice-bearing permafrost and hydrate intervals. Surface temperatures for glacial and interglacial histories for the last 14 million years were considered. The model also used a detailed Holocene temperature history as well as a scenario in which atmospheric carbon dioxide (CO 2 ) levels were twice as high as current levels. Two scenarios were considered: (1) the formation of gas hydrates from gas entrapped under geological seals; and (2) the formation of gas hydrates from gas located in free pore spaces simultaneously with permafrost formation. Results of the study showed that gas hydrates may have formed at a depth of 0.9 km only 1 million years ago. Results of the other modelling scenarios suggested that the hydrates formed 6 million years ago, when temperature changes caused the gas hydrate layer to expand both downward and upward. Detailed models of more recent glacial and interglacial histories showed that the gas hydrate zones will persist under the thick body of the BMB permafrost through current interglacial warming as well as in scenarios where atmospheric CO 2 is doubled. 28 refs., 13 figs

  20. Tension-type headache

    DEFF Research Database (Denmark)

    Bendtsen, Lars; Jensen, Rigmor; Bendtsen, Lars

    2009-01-01

    The substantial societal and individual burdens associated with tension-type headache (TTH) constitute a previously overlooked major public health issue. TTH is prevalent, affecting up to 78% of the general population, and 3% suffer from chronic TTH. Pericranial myofascial nociception probably...... is important for the pathophysiology of episodic TTH, whereas sensitization of central nociceptive pathways seems responsible for the conversion of episodic to chronic TTH. Headache-related disability usually can be reduced by identification of trigger factors combined with nonpharmacologic and pharmacologic...... treatments, but effective treatment modalities are lacking. Benefits can be gained by development of specific and effective treatment strategies....