WorldWideScience

Sample records for surface temperatures initially

  1. The international surface temperature initiative's global land surface databank

    Science.gov (United States)

    Lawrimore, J. H.; Rennie, J.; Gambi de Almeida, W.; Christy, J.; Flannery, M.; Gleason, B.; Klein-Tank, A.; Mhanda, A.; Ishihara, K.; Lister, D.; Menne, M. J.; Razuvaev, V.; Renom, M.; Rusticucci, M.; Tandy, J.; Thorne, P. W.; Worley, S.

    2013-09-01

    The International Surface Temperature Initiative (ISTI) consists of an end-to-end process for land surface air temperature analyses. The foundation is the establishment of a global land surface Databank. This builds upon the groundbreaking efforts of scientists in the 1980s and 1990s. While using many of their principles, a primary aim is to improve aspects including data provenance, version control, openness and transparency, temporal and spatial coverage, and improved methods for merging disparate sources. The initial focus is on daily and monthly timescales. A Databank Working Group is focused on establishing Stage-0 (original observation forms) through Stage-3 data (merged dataset without quality control). More than 35 sources of data have already been added and efforts have now turned to development of the initial version of the merged dataset. Methods have been established for ensuring to the extent possible the provenance of all data from the point of observation through all intermediate steps to final archive and access. Databank submission procedures were designed to make the process of contributing data as easy as possible. All data are provided openly and without charge. We encourage the use of these data and feedback from interested users.

  2. International Surface Temperature Initiative (ISTI) Global Land Surface Temperature Databank - Stage 2 Monthly

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The global land surface temperature databank contains monthly timescale mean, max, and min temperature for approximately 40,000 stations globally. It was developed...

  3. International Surface Temperature Initiative (ISTI) Global Land Surface Temperature Databank - Stage 2 Daily

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The global land surface temperature databank contains monthly timescale mean, max, and min temperature for approximately 40,000 stations globally. It was developed...

  4. International Surface Temperature Initiative (ISTI) Global Land Surface Temperature Databank - Stage 3 Monthly

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Global Land Surface Temperature Databank contains monthly timescale mean, maximum, and minimum temperature for approximately 40,000 stations globally. It was...

  5. International Surface Temperature Initiative (ISTI) Global Land Surface Temperature Databank - Stage 1 Daily

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The global land surface temperature databank contains monthly timescale mean, max, and min temperature for approximately 40,000 stations globally. It was developed...

  6. International Surface Temperature Initiative (ISTI) Global Land Surface Temperature Databank - Stage 1 Monthly

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The global land surface temperature databank contains monthly timescale mean, max, and min temperature for approximately 40,000 stations globally. It was developed...

  7. Estimation of Surface Heat Flux and Surface Temperature during Inverse Heat Conduction under Varying Spray Parameters and Sample Initial Temperature

    Directory of Open Access Journals (Sweden)

    Muhammad Aamir

    2014-01-01

    Full Text Available An experimental study was carried out to investigate the effects of inlet pressure, sample thickness, initial sample temperature, and temperature sensor location on the surface heat flux, surface temperature, and surface ultrafast cooling rate using stainless steel samples of diameter 27 mm and thickness (mm 8.5, 13, 17.5, and 22, respectively. Inlet pressure was varied from 0.2 MPa to 1.8 MPa, while sample initial temperature varied from 600°C to 900°C. Beck’s sequential function specification method was utilized to estimate surface heat flux and surface temperature. Inlet pressure has a positive effect on surface heat flux (SHF within a critical value of pressure. Thickness of the sample affects the maximum achieved SHF negatively. Surface heat flux as high as 0.4024 MW/m2 was estimated for a thickness of 8.5 mm. Insulation effects of vapor film become apparent in the sample initial temperature range of 900°C causing reduction in surface heat flux and cooling rate of the sample. A sensor location near to quenched surface is found to be a better choice to visualize the effects of spray parameters on surface heat flux and surface temperature. Cooling rate showed a profound increase for an inlet pressure of 0.8 MPa.

  8. Estimation of surface heat flux and surface temperature during inverse heat conduction under varying spray parameters and sample initial temperature.

    Science.gov (United States)

    Aamir, Muhammad; Liao, Qiang; Zhu, Xun; Aqeel-ur-Rehman; Wang, Hong; Zubair, Muhammad

    2014-01-01

    An experimental study was carried out to investigate the effects of inlet pressure, sample thickness, initial sample temperature, and temperature sensor location on the surface heat flux, surface temperature, and surface ultrafast cooling rate using stainless steel samples of diameter 27 mm and thickness (mm) 8.5, 13, 17.5, and 22, respectively. Inlet pressure was varied from 0.2 MPa to 1.8 MPa, while sample initial temperature varied from 600°C to 900°C. Beck's sequential function specification method was utilized to estimate surface heat flux and surface temperature. Inlet pressure has a positive effect on surface heat flux (SHF) within a critical value of pressure. Thickness of the sample affects the maximum achieved SHF negatively. Surface heat flux as high as 0.4024 MW/m(2) was estimated for a thickness of 8.5 mm. Insulation effects of vapor film become apparent in the sample initial temperature range of 900°C causing reduction in surface heat flux and cooling rate of the sample. A sensor location near to quenched surface is found to be a better choice to visualize the effects of spray parameters on surface heat flux and surface temperature. Cooling rate showed a profound increase for an inlet pressure of 0.8 MPa.

  9. Surface-initiated atom transfer radical polymerization of methyl methacrylate from magnetite nanoparticles at ambient temperature.

    Science.gov (United States)

    Raghuraman, G K; Dhamodharan, R

    2006-07-01

    The synthesis of methyl methacrylate (MMA) brush from the surface of magnetite nanoparticles (core-shell structure), from initiator moieties anchored covalently to the nanoparticles, via room temperature atom transfer radical polymerization (ATRP) is described. The surface-initiated polymerization was carried out from a surface-confined initiator containing a 2-bromoisobutyrate moiety with Cu(I)Br/PMDETA catalytic system. The initiator moiety was covalently anchored to the nanoparticles via a two step modification reaction scheme. Controlled polymerization was observed if ethyl-2-bromoisobutyrate (2-EiBrB) was added as a free/sacrificial initiator. A linear increase of molecular weight and a narrow molecular weight distribution of the PMMA formed in solution, provide evidence for a controlled surface-initiated polymerization, leading to surface-attached polymer brushes under mild conditions. The grafted PMMA provides good stability and dispersibility for the nanoparticles in organic solvents.

  10. A Surface Temperature Initiated Closure (STIC) for surface energy balance fluxes

    DEFF Research Database (Denmark)

    Mallick, Kaniska; Jarvis, Andrew J.; Boegh, Eva;

    2014-01-01

    of four state equations. Taking advantage of the psychrometric relationship between temperature and vapor pressure, the present method also estimates the near surface moisture availability (M) from TS, air temperature (TA) and relative humidity (RH), thereby being capable of decomposing λ...

  11. Assessment of Sea Surface Temperature and Sea Ice Initial Conditions on Coupled Model Forecasts

    Science.gov (United States)

    Intrieri, J. M.; Solomon, A.; Persson, O. P. G.; Capotondi, A.; LaFontaine, F.; Jedlovec, G.

    2016-12-01

    We present weather-scale (0-10 day) sea ice forecast validation and skill results from an experimental coupled ice-ocean-atmosphere model during the fall freeze-up periods for 2015 and 2016. The model is a mesoscale, coupled atmosphere-ice-ocean mixed-layer model, termed RASM-ESRL, that was developed from the larger-scale Regional Arctic System Model (RASM) architecture. The atmospheric component of RASM-ESRL consists of the Weather Research and Forecasting (WRF) model, the sea-ice component is the Los Alamos CICE model, and the ocean model is POP. Experimental 5-day forecasts were run daily with RASM-ESRL from July through mid-November in 2015 and 2016. Our project focuses on how the modeled sea ice evolution compares to observed physical processes including atmospheric forcing of sea ice movement, melt, and freeze-up through energy fluxes. Model hindcast output is validated against buoy observations, satellite measurements, and concurrent in situ flux observations made from the R/V Sikuliaq in the fall of 2015. Model skill in predicting atmospheric state variables, wind and boundary layer structures, synoptic features, cloud microphysical and ocean properties will be discussed. We will show results of using different initializations of ocean sea surface temperature and sea ice extent and the impacts on sea ice edge prediction.

  12. Fabrication and evaluation of temperature responsive molecularly imprinted sorbents based on surface of yeast via surface-initiated AGET ATRP

    Science.gov (United States)

    Pan, Jianming; Hang, Hui; Li, Xiuxiu; Zhu, Wenjing; Meng, Minjia; Dai, Xiaohui; Dai, Jiangdong; Yan, Yongsheng

    2013-12-01

    Temperature responsive molecularly imprinted polymers (T-MIPs) were prepared based on the surface of yeast by electron transfer atom transfer radical polymerization (AGET ATRP). The as-prepared T-MIPs were charcterized by FT-IR, SEM, TGA and elemental analysis, which indicated that T-MIPs exhibited thermal stability and composed of temperature responsive imprinted layer. Then T-MIPs were evaluated as sorbents to selectively recognise and release cefalexin (CFX) molecules. The results suggested binding properties of T-MIPs were related to the testing temperature. The maximum adsorption capacity of T-MIPs at 303 K was 59.4 mg g-1, and the maximum release proportion for T-MIPs at 293 K in water for 24 h was 71.08%. The selective recognition experiments demonstrated high affinity and selectivity of T-MIPs towards CFX over competitive compounds, and the specific recognition of binding sites may be based on the distinct size, structure and functional group to the template molecules.

  13. Fabrication and evaluation of temperature responsive molecularly imprinted sorbents based on surface of yeast via surface-initiated AGET ATRP

    Energy Technology Data Exchange (ETDEWEB)

    Pan, Jianming, E-mail: pjm@ujs.edu.cn; Hang, Hui; Li, Xiuxiu; Zhu, Wenjing; Meng, Minjia; Dai, Xiaohui; Dai, Jiangdong; Yan, Yongsheng

    2013-12-15

    Temperature responsive molecularly imprinted polymers (T-MIPs) were prepared based on the surface of yeast by electron transfer atom transfer radical polymerization (AGET ATRP). The as-prepared T-MIPs were charcterized by FT-IR, SEM, TGA and elemental analysis, which indicated that T-MIPs exhibited thermal stability and composed of temperature responsive imprinted layer. Then T-MIPs were evaluated as sorbents to selectively recognise and release cefalexin (CFX) molecules. The results suggested binding properties of T-MIPs were related to the testing temperature. The maximum adsorption capacity of T-MIPs at 303 K was 59.4 mg g{sup −1}, and the maximum release proportion for T-MIPs at 293 K in water for 24 h was 71.08%. The selective recognition experiments demonstrated high affinity and selectivity of T-MIPs towards CFX over competitive compounds, and the specific recognition of binding sites may be based on the distinct size, structure and functional group to the template molecules.

  14. A stable, unbiased, long-term satellite based data record of sea surface temperature from ESA's Climate Change Initiative

    Science.gov (United States)

    Rayner, Nick; Good, Simon; Merchant, Chris

    2013-04-01

    The study of climate change demands long-term, stable observational records of climate variables such as sea surface temperature (SST). ESA's Climate Change Initiative was set up to unlock the potential of satellite data records for this purpose. As part of this initiative, 13 projects were established to develop the data records for different essential climate variables - aerosol, cloud, fire, greenhouse gases, glaciers, ice sheets, land cover, ocean colour, ozone, sea ice, sea level, soil moisture and SST. In this presentation we describe the development work that has taken place in the SST project and present new prototype data products that are available now for users to trial. The SST project began in 2010 and has now produced two prototype products. The first is a long-term product (covering mid-1991 - 2010 currently, but with a view to update this in the future), which prioritises length of data record and stability over other considerations. It is based on data from the Along-Track Scanning Radiometer (ATSR) and Advanced Very-High Resolution Radiometer (AVHRR) series of satellite instruments. The product aims to combine the favourable stability and bias characteristics of ATSR data with the geographical coverage achieved with the AVHRR series. Following an algorithm selection process, an optimal estimation approach to retrieving SST from the satellite measurements from both sensors was adopted. The retrievals do not depend on in situ data and so this data record represents an independent assessment of SST change. In situ data are, however, being used to validate the resulting data. The second data product demonstrates the coverage that can be achieved using the modern satellite observing system including, for example, geostationary satellite data. Six months worth of data have been processed for this demonstration product. The prototype SST products will be released in April to users to trial in their work. The long term product will be available as

  15. Grafting N-Isopropyl Acrylamide) from Poly(vinylidene Fluoride) Mirofiltration, Membranes via Direct Surface-Initiated Atom Transfer Radical Polymerization, and Temperature Sensitivity

    Science.gov (United States)

    Chen, Yiwang; Xiao, Jichun; Zhou, Weihua; Deng, Qilan; Nie, Huarong; Wan, Meixiang; Bai, Fenglian

    Well-defined poly(N-isopropyl acrylamide) (PNIPAAm) brushes on commercial hydrophobic poly(vinylidene fluoride) (PVDF) microfiltration membrane surfaces were prepared, via direct atom transfer radical polymerization (ATRP) with the secondary fluorinated site of PVDF as initiator and water as solvent at 80°C. The effect of solvents on the ATRP was studied in detail. The water as reaction solvent was in favor of surface-initiated ATRP of N-isopropyl acrylamide (NIPAAm) from secondary fluoride of PVDF membranes. The chemical composition and structure of the modified PVDF membrane surfaces were determined by attenuated total reflectance (ATR) Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. The surface and cross-section morphology of membranes were studied by scanning electron microscopy (SEM). The pore sizes of the pristine PVDF membrane and the PNIPAAm-grafted PVDF membranes were measured using micro-image analysis and process software. The introduction of the well-defined PNIPAAm on the PVDF membrane gave rise to hydrophilicity. Water contact angles of PVDF membranes reduced after the surface grafting of PNIPAAm. Water fluxes and protein solution permeation experiments revealed that the PNIPAAm-grafted PVDF membranes exhibited temperature-responsive permeability. The unique microstructure of PNIPAAm brushes facilitated hydrophilicity below the lower critical solution temperature.

  16. Impact of satellite-based lake surface observations on the initial state of HIRLAM. Part II: Analysis of lake surface temperature and ice cover

    Directory of Open Access Journals (Sweden)

    Homa Kheyrollah Pour

    2014-09-01

    Full Text Available This paper presents results from a study on the impact of remote-sensing Lake Surface Water Temperature (LSWT observations in the analysis of lake surface state of a numerical weather prediction (NWP model. Data assimilation experiments were performed with the High Resolution Limited Area Model (HIRLAM, a three-dimensional operational NWP model. Selected thermal remote-sensing LSWT observations provided by the Moderate Resolution Imaging Spectroradiometer (MODIS and Advanced Along-Track Scanning Radiometer (AATSR sensors onboard the Terra/Aqua and ENVISAT satellites, respectively, were included into the assimilation. The domain of our experiments, which focussed on two winters (2010–2011 and 2011–2012, covered northern Europe. Validation of the resulting objective analyses against independent observations demonstrated that the description of the lake surface state can be improved by the introduction of space-borne LSWT observations, compared to the result of pure prognostic parameterisations or assimilation of the available limited number of in-situ lake temperature observations. Further development of the data assimilation methods and solving of several practical issues are necessary in order to fully benefit from the space-borne observations of lake surface state for the improvement of the operational weather forecast. This paper is the second part of a series of two papers aimed at improving the objective analysis of lake temperature and ice conditions in HIRLAM.

  17. Impact of satellite-based lake surface observations on the initial state of HIRLAM. Part I: evaluation of remotely-sensed lake surface water temperature observations

    Directory of Open Access Journals (Sweden)

    Homa Kheyrollah Pour

    2014-05-01

    Full Text Available Lake Surface Water Temperature (LSWT observations are used to improve the lake surface state in the High Resolution Limited Area Model (HIRLAM, a three-dimensional numerical weather prediction (NWP model. In this paper, satellite-derived LSWT observations from the Moderate Resolution Imaging Spectroradiometer (MODIS and the Along-Track Scanning Radiometer (AATSR are evaluated against in-situ measurements collected by the Finnish Environment Institute (SYKE for a selection of large- to medium-size lakes during the open-water season. Data assimilation of these LSWT observations into the HIRLAM is in the paper Part II. Results show a good agreement between MODIS and in-situ measurements from 22 Finnish lakes, with a mean bias of −1.13°C determined over five open-water seasons (2007–2011. Evaluation of MODIS during an overlapping period (2007–2009 with the AATSR-L2 product currently distributed by the European Space Agency (ESA shows a mean (cold bias error of −0.93°C for MODIS and a warm mean bias of 1.08°C for AATSR-L2. Two additional LSWT retrieval algorithms were applied to produce more accurate AATSR products. The algorithms use ESA's AATSR-L1B brightness temperature product to generate new L2 products: one based on Key et al. (1997 and the other on Prata (2002 with a finer resolution water mask than used in the creation of the AATSR-L2 product distributed by ESA. The accuracies of LSWT retrievals are improved with the Key and Prata algorithms with biases of 0.78°C and −0.11°C, respectively, compared to the original AATSR-L2 product (3.18°C.

  18. Surface Temperature Data Analysis

    Science.gov (United States)

    Hansen, James; Ruedy, Reto

    2012-01-01

    Small global mean temperature changes may have significant to disastrous consequences for the Earth's climate if they persist for an extended period. Obtaining global means from local weather reports is hampered by the uneven spatial distribution of the reliably reporting weather stations. Methods had to be developed that minimize as far as possible the impact of that situation. This software is a method of combining temperature data of individual stations to obtain a global mean trend, overcoming/estimating the uncertainty introduced by the spatial and temporal gaps in the available data. Useful estimates were obtained by the introduction of a special grid, subdividing the Earth's surface into 8,000 equal-area boxes, using the existing data to create virtual stations at the center of each of these boxes, and combining temperature anomalies (after assessing the radius of high correlation) rather than temperatures.

  19. Temperature initiated passive cooling system

    Science.gov (United States)

    Forsberg, Charles W.

    1994-01-01

    A passive cooling system for cooling an enclosure only when the enclosure temperature exceeds a maximum standby temperature comprises a passive heat transfer loop containing heat transfer fluid having a particular thermodynamic critical point temperature just above the maximum standby temperature. An upper portion of the heat transfer loop is insulated to prevent two phase operation below the maximum standby temperature.

  20. GODAE, SFCOBS - Surface Temperature Observations

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — GODAE, SFCOBS - Surface Temperature Observations: Ship, fixed/drifting buoy, and CMAN in-situ surface temperature. Global Telecommunication System (GTS) Data. The...

  1. Ocean Surface Temperature Response to Atmosphere-Ocean Interaction of the MJO. A Component of Coupled Air-Wave-Sea Processes in the Subtropics Departmental Research Initiative

    Science.gov (United States)

    2013-09-30

    Airborne IR imagery will provide high spatial resolution calibrated SST variability. The image scale will be roughly 500 m to 1000 m (depending on...array performance will allow for the determination of temperature variability of less than 50 mK. 3 Additionally, we will deploy a JADE LWIR 570...that are calibrated to better than 0.05ºC. The upward- looking instrumentation will be used to discriminate real from apparent ice surface temperature

  2. GISS Surface Temperature Analysis

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The GISTEMP dataset is a global 2x2 gridded temperature anomaly dataset. Temperature data is updated around the middle of every month using current data files from...

  3. Temperature dependence of surface nanobubbles

    NARCIS (Netherlands)

    Berkelaar, R.P.; Seddon, James Richard Thorley; Zandvliet, Henricus J.W.; Lohse, Detlef

    2012-01-01

    The temperature dependence of nanobubbles was investigated experimentally using atomic force microscopy. By scanning the same area of the surface at temperatures from 51 °C to 25 °C it was possible to track geometrical changes of individual nanobubbles as the temperature was decreased.

  4. Design, Construction, and Initial Test of High Spatial Resolution Thermometry Arrays for Detection of Surface Temperature Profiles on SRF Cavities in Super Fluid Helium

    Energy Technology Data Exchange (ETDEWEB)

    Ari Palczewski, Rongli Geng, Grigory Eremeev

    2011-07-01

    We designed and built two high resolution (0.6-0.55mm special resolution [1.1-1.2mm separation]) thermometry arrays prototypes out of the Allen Bradley 90-120 ohm 1/8 watt resistor to measure surface temperature profiles on SRF cavities. One array was designed to be physically flexible and conform to any location on a SRF cavity; the other was modeled after the common G-10/stycast 2850 thermometer and designed to fit on the equator of an ILC (Tesla 1.3GHz) SRF cavity. We will discuss the advantages and disadvantages of each array and their construction. In addition we will present a case study of the arrays performance on a real SRF cavity TB9NR001. TB9NR001 presented a unique opportunity to test the performance of each array as it contained a dual (4mm separation) cat eye defect which conventional methods such as OST (Oscillating Superleak second-sound Transducers) and full coverage thermometry mapping were unable to distinguish between. We will discuss the new arrays ability to distinguish between the two defects and their preheating performance.

  5. The surface temperature of Europa

    CERN Document Server

    Ashkenazy, Yosef

    2016-01-01

    Previous estimates of the surface temperature of Jupiter's moon, Europa, neglected the effect of the eccentricity of Jupiter's orbit around the Sun, the effect of the eclipse of Europa (i.e., the relative time that Europa is within the shadow of Jupiter), and the effect of Europa's internal heating. Here we estimate the surface temperature of Europa, when Europa's obliquity, eclipse and internal heating, as well as the eccentricity of Jupiter, are all taken into account. For a typical internal heating rate of 0.05 W/m$^2$ (corresponding to an ice thickness of about 10 kms), the equator, pole, and global mean surface temperatures are 101.7 K, 45.26 K, and 94.75 K, respectively. We found that the temperature at the high latitudes is significantly affected by the internal heating. We also studied the effect of the internal heating on the mean thickness of Europa's icy shell and conclude that the polar region temperature can be used to constrain the internal heating and the depth of the ice. Our approach and form...

  6. Development of an Operational Calibration Methodology for the Landsat Thermal Data Archive and Initial Testing of the Atmospheric Compensation Component of a Land Surface Temperature (LST Product from the Archive

    Directory of Open Access Journals (Sweden)

    Monica Cook

    2014-11-01

    Full Text Available The Landsat program has been producing an archive of thermal imagery that spans the globe and covers 30 years of the thermal history of the planet at human scales (60–120 m. Most of that archive’s absolute radiometric calibration has been fixed through vicarious calibration techniques. These calibration ties to trusted values have often taken a year or more to gather sufficient data and, in some cases, it has been over a decade before calibration certainty has been established. With temperature being such a critical factor for all living systems and the ongoing concern over the impacts of climate change, NASA and the United States Geological Survey (USGS are leading efforts to provide timely and accurate temperature data from the Landsat thermal data archive. This paper discusses two closely related advances that are critical steps toward providing timely and reliable temperature image maps from Landsat. The first advance involves the development and testing of an autonomous procedure for gathering and performing initial screening of large amounts of vicarious calibration data. The second advance discussed in this paper is the per-pixel atmospheric compensation of the data to permit calculation of the emitted surface radiance (using ancillary sources of emissivity data and the corresponding land surface temperature (LST.

  7. Magellan: initial analysis of venus surface modification.

    Science.gov (United States)

    Arvidson, R E; Baker, V R; Elachi, C; Saunders, R S; Wood, J A

    1991-04-12

    Initial Magellan observations reveal a planet with high dielectric constant materials exposed preferentially in elevated regions with high slopes, ejecta deposits extending up to 1000 kilometers to the west of several impact craters, windblown deposits and features in areas where there are both obstacles and a source of particulate material, and evidence for slow, steady degradation by atmosphere-surface interactions and mass movements.

  8. The initial interactions of oxygen with polycrystalline titanium surfaces

    Science.gov (United States)

    Azoulay, A.; Shamir, N.; Fromm, E.; Mintz, M. H.

    1997-01-01

    The interactions of gaseous oxygen and different types of polycrystalline titanium surfaces were studied at room temperature within the exposure range of 0-1000 L. Combined measurements utilizing direct recoils spectrometry (DRS), Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), and work function variations enabled the distinction between processes occurring on the topmost atomic layer and those associated with subsurface incorporation of oxygen. Also, the different chemical forms (oxidation states) developing during the exposure course were identified. The results were compared for three types of surfaces, each prepared by a different cleaning procedure. It has been concluded that: (i) Oxygen initially accumulates on the topmost atomic layer, regardless of the type of the studied surface. No preferred subsurface occupation has been observed. (ii) The kinetics of initial accumulation (up to a complete surface coverage) are similar for all the different types of surfaces. (iii) Mixtures of different oxidation states of titanium (0, +2, +3, +4) are present during the whole course of exposure. Qualitatively, increasing proportions of the higher valence states are displayed for higher oxygen exposures. However, the quantitative estimates of their relative amounts indicate a strong dependence on the type of surface, with preferred high oxidation (+4) states obtained for high temperature annealed samples (as compared with room temperature sputtered surfaces). (iv) Topmost oxygen atoms which terminate the oxides surfaces are less negatively charged than the underlying (i.e., subsurface) "oxidic" atoms. These results may account for some of the controversies presented in the literature.

  9. Reintroducing radiometric surface temperature into the Penman-Monteith formulation

    DEFF Research Database (Denmark)

    Mallick, Kaniska; Bøgh, Eva; Trebs, Ivonne;

    2015-01-01

    Here we demonstrate a novel method to physically integrate radiometric surface temperature (TR) into the Penman-Monteith (PM) formulation for estimating the terrestrial sensible and latent heat fluxes (H and λE) in the framework of a modified Surface Temperature Initiated Closure (STIC). It combi...

  10. Extended Reconstructed Sea Surface Temperature (ERSST)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Extended Reconstructed Sea Surface Temperature (ERSST) dataset is a global monthly sea surface temperature analysis derived from the International Comprehensive...

  11. NOAA Global Surface Temperature (NOAAGlobalTemp)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The NOAA Global Surface Temperature Dataset (NOAAGlobalTemp) is a merged land–ocean surface temperature analysis (formerly known as MLOST) (link is external). It is...

  12. The Pacific sea surface temperature

    Energy Technology Data Exchange (ETDEWEB)

    Douglass, David H., E-mail: douglass@pas.rochester.edu [Department of Physics and Astronomy, University of Rochester, Rochester, NY 14627-0171 (United States)

    2011-12-05

    The Pacific sea surface temperature data contains two components: N{sub L}, a signal that exhibits the familiar El Niño/La Niña phenomenon and N{sub H}, a signal of one-year period. Analysis reveals: (1) The existence of an annual solar forcing F{sub S}; (2) N{sub H} is phase locked directly to F{sub S} while N{sub L} is frequently phase locked to the 2nd or 3rd subharmonic of F{sub S}. At least ten distinct subharmonic time segments of N{sub L} since 1870 are found. The beginning or end dates of these segments have a near one-to-one correspondence with the abrupt climate changes previously reported. Limited predictability is possible. -- Highlights: ► El Niño/La Niña consists of 2 components phase-locked to annual solar cycle. ► The first component N{sub L} is the familiar El Niño/La Niña effect. ► The second N{sub H} component has a period of 1 cycle/year. ► N{sub L} can be phase-locked to 2nd or 3rd subharmonic of annual cycle. ► Ends of phase-locked segments correspond to abrupt previously reported climate changes.

  13. Surface temperature measurements of diamond

    CSIR Research Space (South Africa)

    Masina, BN

    2006-07-01

    Full Text Available ) and the waist position (z0) 3. TEMPERATURE MEASUREMENTS There are many methods to measure the temperature of a body. Here we used a thermocou- ple and a pyrometer, while future plans involve emission spectroscopy. A thermocouple is a temperature... sensor that consists of two wires con- nected together made from different metals, which produces an electrical voltage that is dependant on tem- perature. A Newport electronic thermocou- ple was used to meas- ured temperature. It can measure...

  14. Steam Initiated Surface Modification of Aluminium Alloys

    DEFF Research Database (Denmark)

    Din, Rameez Ud

    -friendly alternative processes. In the present work high temperature steam-based process has been investigated as a possible chromate free conversion coating. Investigations in the thesis includes the effect of alloy type, substrate microstructure, surface finish, and various chemistries on the coating formation......, and interface structure of the coatings were analysed using SEM, FIB-SEM,TEM, GI-XRD, FTIR, XPS, AFM, contact angle, and boiling test. Chapter 1 of this thesis provides a background to the work and available literature information. Materials and experimental methods are outlined in chapter 2. The chapters 3...... using autoclave or using spray system, and with or without various chemistries as accelerators. In general, results show the formation of 650 nm – 3000 nm thick conversion coating, where the thickness depend on the treatment parameters and steam chemistry. Further, the formed coating provide good...

  15. Fission Surface Power System Initial Concept Definition

    Science.gov (United States)

    2010-01-01

    Under the NASA Exploration Technology Development Program (ETDP) and in partnership with the Department of Energy (DOE), NASA has embarked on a project to develop Fission Surface Power (FSP) technology. The primary goals of the project are to 1) develop FSP concepts that meet expected surface power requirements at reasonable cost with added benefits over other options, 2) establish a hardwarebased technical foundation for FSP design concepts and reduce overall development risk, 3) reduce the cost uncertainties for FSP and establish greater credibility for flight system cost estimates, and 4) generate the key products to allow NASA decision-makers to consider FSP as a preferred option for flight development. The FSP project was initiated in 2006 as the Prometheus Program and the Jupiter Icy Moons Orbiter (JIMO) mission were phased-out. As a first step, NASA Headquarters commissioned the Affordable Fission Surface Power System Study to evaluate the potential for an affordable FSP development approach. With a cost-effective FSP strategy identified, the FSP team evaluated design options and selected a Preliminary Reference Concept to guide technology development. Since then, the FSP Preliminary Reference Concept has served as a point-of-departure for several NASA mission architecture studies examining the use of nuclear power and has provided the foundation for a series of "Pathfinder" hardware tests. The long-term technology goal is a Technology Demonstration Unit (TDU) integrated system test using full-scale components and a non-nuclear reactor simulator. The FSP team consists of Glenn Research Center (GRC), Marshall Space Flight Center (MSFC) and the DOE National Laboratories at Los Alamos (LANL), Idaho (INL), Oak Ridge (ORNL), and Sandia (SNL). The project is organized into two main elements: Concept Definition and Risk Reduction. Under Concept Definition, the team performs trade studies, develops analytical tools, and formulates system concepts. Under Risk

  16. Modelling global fresh surface water temperature

    NARCIS (Netherlands)

    Beek, L.P.H. van; Eikelboom, T.; Vliet, M.T.H. van; Bierkens, M.F.P.

    2011-01-01

    Temperature directly determines a range of water physical properties including vapour pressure, surface tension, density and viscosity, and the solubility of oxygen and other gases. Indirectly water temperature acts as a strong control on fresh water biogeochemistry, influencing sediment

  17. Modelling global fresh surface water temperature

    NARCIS (Netherlands)

    Beek, L.P.H. van; Eikelboom, T.; Vliet, M.T.H. van; Bierkens, M.F.P.

    2011-01-01

    Temperature directly determines a range of water physical properties including vapour pressure, surface tension, density and viscosity, and the solubility of oxygen and other gases. Indirectly water temperature acts as a strong control on fresh water biogeochemistry, influencing sediment concentrati

  18. Role of surface temperature in fluorocarbon plasma-surface interactions

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, Caleb T.; Overzet, Lawrence J.; Goeckner, Matthew J. [Department of Electrical Engineering, University of Texas at Dallas, PO Box 830688, Richardson, TX 75083 (United States)

    2012-07-15

    This article examines plasma-surface reaction channels and the effect of surface temperature on the magnitude of those channels. Neutral species CF{sub 4}, C{sub 2}F{sub 6}, and C{sub 3}F{sub 8} are produced on surfaces. The magnitude of the production channel increases with surface temperature for all species, but favors higher mass species as the temperature is elevated. Additionally, the production rate of CF{sub 2} increases by a factor of 5 as the surface temperature is raised from 25 Degree-Sign C to 200 Degree-Sign C. Fluorine density, on the other hand, does not change as a function of either surface temperature or position outside of the plasma glow. This indicates that fluorine addition in the gas-phase is not a dominant reaction. Heating reactors can result in higher densities of depositing radical species, resulting in increased deposition rates on cooled substrates. Finally, the sticking probability of the depositing free radical species does not change as a function of surface temperature. Instead, the surface temperature acts together with an etchant species (possibly fluorine) to elevate desorption rates on that surface at temperatures lower than those required for unassisted thermal desorption.

  19. Age-surface temperature estimation model: When will oil palm plantation reach the same surface temperature as natural forest?

    Science.gov (United States)

    Rushayati, S. B.; Hermawan, R.; Meilani, R.

    2017-01-01

    Oil palm plantation has often been accused as the cause of global warming. However, along with its growth, it would be able to decrease surface temperature. The question is ‘when will the plantation be able to reach the same surface temperature as natural forest’. This research aimed to estimate the age of oil palm plantation that create similar surface temperature to those in natural forest (land cover before the opening and planting of oil palm). The method used in this research was spatial analysis of land cover and surface temperature distribution. Based on the spatial analysis of surface temperature, five points was randomly taken from each planting age (age 1 15 years). Linear regression was then employed in the analysis. The linear regression formula between surface temperature and age of oil palm plantation was Y = 26.002 – 0.1237X. Surface temperature will decrease as much as 0.1237 ° C with one year age growth oil palm. Surface temperature that was similar to the initial temperature, when the land cover was natural forest (23.04 °C), was estimated to occur when the oil palm plantation reach the age 24 year.

  20. Gravity increased by lunar surface temperature

    Science.gov (United States)

    Keene, James

    2013-04-01

    Quantitatively large effects of lunar surface temperature on apparent gravitational force measured by lunar laser ranging (LLR) and lunar perigee may challenge widely accepted theories of gravity. LLR data grouped by days from full moon shows the moon is about 5 percent closer to earth at full moon compared to 8 days before or after full moon. In a second, related result, moon perigees were least distant in days closer to full moon. Moon phase was used as proxy independent variable for lunar surface temperature. The results support the prediction by binary mechanics that gravitational force increases with object surface temperature.

  1. Satellite Sensed Skin Sea Surface Temperature

    Science.gov (United States)

    Donlon, Craig

    1997-01-01

    Quantitative predictions of spatial and temporal changes the global climate rely heavily on the use of computer models. Unfortunately, such models cannot provide the basis for climate prediction because key physical processes are inadequately treated. Consequently, fine tuning procedures are often used to optimize the fit between model output and observational data and the validation of climate models using observations is essential if model based predictions of climate change are to be treated with any degree of confidence. Satellite Sea Surface Temperature (SST) observations provide high spatial and temporal resolution data which is extremely well suited to the initialization, definition of boundary conditions and, validation of climate models. In the case of coupled ocean-atmosphere models, the SST (or more correctly the 'Skin' SST (SSST)) is a fundamental diagnostic variable to consider in the validation process. Daily global SST maps derived from satellite sensors also provide adequate data for the detection of global patterns of change which, unlike any other SST data set, repeatedly extend into the southern hemisphere extra-tropical regions. Such data are essential to the success of the spatial 'fingerprint' technique, which seeks to establish a north-south asymmetry where warming is suppressed in the high latitude Southern Ocean. Some estimates suggest that there is a greater than 80% chance of directly detecting significant change (97.5 % confidence level) after 10-12 years of consistent global observations of mean sea surface temperature. However, these latter statements should be qualified with the assumption that a negligible drift in the observing system exists and that biases between individual instruments required to derive a long term data set are small. Given that current estimates for the magnitude of global warming of 0.015 K yr(sup -1) - 0.025 K yr(sup -1), satellite SST data sets need to be both accurate and stable if such a warming trend is to

  2. Sea Surface Temperature Average_SST_Master

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Sea surface temperature collected via satellite imagery from http://www.esrl.noaa.gov/psd/data/gridded/data.noaa.ersst.html and averaged for each region using ArcGIS...

  3. OW NOAA GOES Sea-Surface Temperature

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The dataset contains satellite-derived sea-surface temperature measurements collected by means of the Geostationary Orbiting Environmental Satellite. The data is...

  4. evaluation of land surface temperature parameterization ...

    African Journals Online (AJOL)

    user

    1 DEPARTMENT OF PHYSICS, ADEYEMI COLLEGE OF EDUCATION, ONDO, ... Surface temperature (Ts) is vital to the study of land-atmosphere interactions and climate variabilities. .... value = 0.167 m3m-3), and very low for dry days (mean.

  5. Monthly Near-Surface Air Temperature Averages

    Data.gov (United States)

    National Aeronautics and Space Administration — Global surface temperatures in 2010 tied 2005 as the warmest on record. The International Satellite Cloud Climatology Project (ISCCP) was established in 1982 as part...

  6. Sea Surface Temperature (14 KM North America)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Product shows local sea surface temperatures (degrees C). It is a composite gridded-image derived from 8-km resolution SST Observations. It is generated every 48...

  7. Analysed foundation sea surface temperature, global

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The through-cloud capabilities of microwave radiometers provide a valuable picture of global sea surface temperature (SST). To utilize this, scientists at Remote...

  8. Urban aerosol effects on surface insolation and surface temperature

    Science.gov (United States)

    Jin, M.; Burian, S. J.; Remer, L. A.; Shepherd, M. J.

    2007-12-01

    Urban aerosol particulates may play a fundamental role in urban microclimates and city-generated mesoscale circulations via its effects on energy balance of the surface. Key questions that need to be addressed include: (1) How do these particles affect the amount of solar energy reaching the surface and resulting surface temperature? (2) Is the effect the same in all cities? and (3) How does it vary from city to city? Using NASA AERONET in-situ observations, a radiative transfer model, and a regional climate mode (MM5), we assess aerosol effects on surface insolation and surf ace temperature for dense urban-polluted regions. Two big cities, one in a developing country (Beijing, P.R. China) and another in developed country (New York City, USA), are selected for inter-comparison. The study reveals that aerosol effects on surface temperature depends largely on aerosols' optical and chemical properties as well as atmosphere and land surface conditions, such as humidity and land cover. Therefore, the actual magnitudes of aerosol effects differ from city to city. Aerosol measurements from AERONET show both average and extreme cases for aerosol impacts on surface insolation. In general, aerosols reduce surface insolation by 30Wm-2. Nevertheless, in extreme cases, such reduction can exceed 100 Wm-2. Consequently, this reduces surface skin temperature 2-10C in an urban environment.

  9. Modeling of global surface air temperature

    Science.gov (United States)

    Gusakova, M. A.; Karlin, L. N.

    2012-04-01

    A model to assess a number of factors, such as total solar irradiance, albedo, greenhouse gases and water vapor, affecting climate change has been developed on the basis of Earth's radiation balance principle. To develop the model solar energy transformation in the atmosphere was investigated. It's a common knowledge, that part of the incoming radiation is reflected into space from the atmosphere, land and water surfaces, and another part is absorbed by the Earth's surface. Some part of outdoing terrestrial radiation is retained in the atmosphere by greenhouse gases (carbon dioxide, methane, nitrous oxide) and water vapor. Making use of the regression analysis a correlation between concentration of greenhouse gases, water vapor and global surface air temperature was obtained which, it is turn, made it possible to develop the proposed model. The model showed that even smallest fluctuations of total solar irradiance intensify both positive and negative feedback which give rise to considerable changes in global surface air temperature. The model was used both to reconstruct the global surface air temperature for the 1981-2005 period and to predict global surface air temperature until 2030. The reconstructions of global surface air temperature for 1981-2005 showed the models validity. The model makes it possible to assess contribution of the factors listed above in climate change.

  10. Recovery of an initial temperature from discrete sampling

    KAUST Repository

    DeVore, Ronald

    2014-11-01

    The problem of recovering the initial temperature of a body from discrete temperature measurements made at later times is studied. While this problem has a general formulation, the results of this paper are only given in the simplest setting of a finite (one-dimensional), constant coefficient, linear rod. It is shown that with a judicious placement of a thermometer on this rod, the initial temperature profile of the rod can be completely determined by later time measurements. The paper then studies the number of measurements that are needed to recover the initial profile to a prescribed accuracy and provides an optimal reconstruction algorithm under the assumption that the initial profile is in a Sobolev class. © 2014 World Scientific Publishing Company.

  11. Responsive PET nano/microfibers via surface-initiated polymerization.

    Science.gov (United States)

    Özçam, A Evren; Roskov, Kristen E; Genzer, Jan; Spontak, Richard J

    2012-01-01

    Poly(ethylene terephthalate) (PET) is one of the most important thermoplastics in ubiquitous use today because of its mechanical properties, clarity, solvent resistance, and recyclability. In this work, we functionalize the surface of electrospun PET microfibers by growing poly(N-isopropylacrylamide) (PNIPAAm) brushes through a chemical sequence that avoids PET degradation to generate thermoresponsive microfibers that remain mechanically robust. Amidation of deposited 3-aminopropyltriethoxysilane, followed by hydrolysis, yields silanol groups that permit surface attachment of initiator molecules, which can be used to grow PNIPAAm via "grafting from" atom-transfer radical polymerization. Spectroscopic analyses performed after each step confirm the expected reaction and the ultimate growth of PNIPAAm brushes. Water contact-angle measurements conducted at temperatures below and above the lower critical solution temperature of PNIPAAm, coupled with adsorption of Au nanoparticles from aqueous suspension, demonstrate that the brushes retain their reversible thermoresponsive nature, thereby making PNIPAAm-functionalized PET microfibers suitable for filtration media, tissue scaffolds, delivery vehicles, and sensors requiring robust microfibers. © 2012 American Chemical Society

  12. Calibration of surface temperature on rocky exoplanets

    Science.gov (United States)

    Kashyap Jagadeesh, Madhu

    2016-07-01

    Study of exoplanets and the search for life elsewhere has been a very fascinating area in recent years. Presently, lots of efforts have been channelled in this direction in the form of space exploration and the ultimate search for the habitable planet. One of the parametric methods to analyse the data available from the missions such as Kepler, CoRoT, etc, is the Earth Similarity Index (ESI), defined as a number between zero (no similarity) and one (identical to Earth), introduced to assess the Earth likeness of exoplanets. A multi-parameter ESI scale depends on the radius, density, escape velocity and surface temperature of exoplanets. Our objective is to establish how exactly the individual parameters, entering the interior ESI and surface ESI, are contributing to the global ESI, using the graphical analysis. Presently, the surface temperature estimates are following a correction factor of 30 K, based on the Earth's green-house effect. The main objective of this work in calculations of the global ESI using the HabCat data is to introduce a new method to better estimate the surface temperature of exoplanets, from theoretical formula with fixed albedo factor and emissivity (Earth values). From the graphical analysis of the known data for the Solar System objects, we established the calibration relation between surface and equilibrium temperatures for the Solar System objects. Using extrapolation we found that the power function is the closest description of the trend to attain surface temperature. From this we conclude that the correction term becomes very effective way to calculate the accurate value of the surface temperature, for further analysis with our graphical methodology.

  13. Integrative inversion of land surface component temperature

    Institute of Scientific and Technical Information of China (English)

    FAN Wenjie; XU Xiru

    2005-01-01

    In this paper, the row winter wheat was selected as the example to study the component temperature inversion method of land surface target in detail. The result showed that the structural pattern of row crop can affect the inversion precision of component temperature evidently. Choosing appropriate structural pattern of row crop can improve the inversion precision significantly. The iterative method combining inverse matrix was a stable method that was fit for inversing component temperature of land surface target. The result of simulation and field experiment showed that the integrative method could remarkably improve the inversion accuracy of the lighted soil surface temperature and the top layer canopy temperature, and enhance inversion stability of components temperature. Just two parameters were sufficient for accurate atmospheric correction of multi-angle and multi-spectral thermal infrared data: atmospheric transmittance and the atmospheric upwelling radiance. If the atmospheric parameters and component temperature can be inversed synchronously, the really and truly accurate atmospheric correction can be achieved. The validation using ATSRII data showed that the method was useful.

  14. Preacclimation alters Salmonella Enteritidis surface properties and its initial attachment to food contact surfaces.

    Science.gov (United States)

    Yang, Yishan; Kumar, Amit; Zheng, Qianwang; Yuk, Hyun-Gyun

    2015-04-01

    Exposure of Salmonella to environmental stress, prior to its adherence to a food contact surface, may change the cell surface properties and consequently affect its initial attachment and biofilm formation. This study investigated the influence of temperature and pH preacclimation on the initial attachment of Salmonella Enteritidis to acrylic and stainless steel. Besides, changes in physicochemical properties of cells were examined; and their surface attachment was modeled by xDLVO theory. Results showed that control cells pre-grown at 37°C had significantly (P0.05) different from control cells pre-grown at pH 7.3, but they were significantly higher compared to cells pre-grown at pH 8.3 and 9.0. No significant difference was observed between cell attachment to acrylic and stainless steel, although they had different physicochemical properties. The xDLVO theory successfully explained higher attachment for cells pre-grown at optimal condition on both contact surfaces. However, the xDLVO theory could not explain the similar attachment of cells to acrylic and stainless steel. This study elucidates that commonly used intervention technologies including cold storage, thermal treatment, and alkaline antimicrobial agents might alter the physicochemical properties of S. Enteritidis cells and result in varied initial attachment levels.

  15. Electroassisted Functionalization of Nitinol Surface, a Powerful Strategy for Polymer Coating through Controlled Radical Surface Initiation.

    Science.gov (United States)

    Arrotin, Bastien; Delhalle, Joseph; Dubois, Philippe; Mespouille, Laetitia; Mekhalif, Zineb

    2017-03-28

    Coating Nitinol (NiTi) surfaces with a polymer layer has become very appealing in the past few years owing to its increased attraction in the biomedical field. Although its intrinsic properties helped ensure its popularity, its extensive implementation is still hampered by its nickel inclusion, making it sensitive to pitting corrosion and therefore leading to the release of carcinogenic Ni(2+) ions. Among all recent ways to modify NiTi surfaces, elaboration of self-assembled monolayers is of great interest as their high order confers a reinforcement of the metal surface corrosion resistance and brings new functionalities to the metal for postmodification processes. In this work, we compare the electroassisted and thermally assisted self-assembling of 11-(2-bromoisobutyrate)-undecyl-1-phosphonic acid (BUPA) to the classical immersion process on NiTi surfaces initially submitted to a hydrothermal treatment. Among all tested conditions, the electroassisted grafting of BUPA at room temperature appears to be the most promising alternative, as it allows grafting in very short times (5-10 min), thus preventing its degradation. The thus-formed layer has been proven to be sufficient to enable the surface-initiated atom transfer radical polymerization (SI-ATRP) of 2-(dimethylamino)ethyl methacrylate.

  16. Interfacial re-arrangement in initial microbial adhesion to surfaces

    NARCIS (Netherlands)

    Busscher, Henk J.; Norde, Willem; Sharma, Prashant K.; van der Mei, Henny C.

    2010-01-01

    Upon initial microbial adhesion to a surface multiple events occur that include interfacial re-arrangements in the region between an adhering organism and a surface Application of physico-chemical mechanisms to explain microbial adhesion to surfaces requires better knowledge of the interfacial re ar

  17. Temperature limit values for gripping cold surfaces

    NARCIS (Netherlands)

    Malchaire, J.; Geng, Q.; Den Hartog, E.; Havenith, G.; Holmer, I.; Piette, A.; Powell, S.L.; Rintamäki, H.; Rissanen, S.

    2002-01-01

    Objectives. At the request of the European Commission and in the framework of the European Machinery Directive, research was conducted jointly in five different laboratories to develop specifications for surface temperature limit values for the gripping and handling of cold items. Methods. Four

  18. Temperature limit values for gripping cold surfaces

    NARCIS (Netherlands)

    Malchaire, J.; Geng, Q.; Den Hartog, E.; Havenith, G.; Holmer, I.; Piette, A.; Powell, S.L.; Rintamäki, H.; Rissanen, S.

    2002-01-01

    Objectives. At the request of the European Commission and in the framework of the European Machinery Directive, research was conducted jointly in five different laboratories to develop specifications for surface temperature limit values for the gripping and handling of cold items. Methods. Four hund

  19. Surface temperature excess in heterogeneous catalysis

    NARCIS (Netherlands)

    Zhu, L.

    2005-01-01

    In this dissertation we study the surface temperature excess in heterogeneous catalysis. For heterogeneous reactions, such as gas-solid catalytic reactions, the reactions take place at the interfaces between the two phases: the gas and the solid catalyst. Large amount of reaction heats are released

  20. Surface temperature excess in heterogeneous catalysis

    NARCIS (Netherlands)

    Zhu, L.

    2005-01-01

    In this dissertation we study the surface temperature excess in heterogeneous catalysis. For heterogeneous reactions, such as gas-solid catalytic reactions, the reactions take place at the interfaces between the two phases: the gas and the solid catalyst. Large amount of reaction heats are released

  1. Trend patterns in global sea surface temperature

    DEFF Research Database (Denmark)

    Barbosa, S.M.; Andersen, Ole Baltazar

    2009-01-01

    Isolating long-term trend in sea surface temperature (SST) from El Nino southern oscillation (ENSO) variability is fundamental for climate studies. In the present study, trend-empirical orthogonal function (EOF) analysis, a robust space-time method for extracting trend patterns, is applied...

  2. DISAGGREGATION OF GOES LAND SURFACE TEMPERATURES USING SURFACE EMISSIVITY

    Science.gov (United States)

    Accurate temporal and spatial estimation of land surface temperatures (LST) is important for modeling the hydrological cycle at field to global scales because LSTs can improve estimates of soil moisture and evapotranspiration. Using remote sensing satellites, accurate LSTs could be routine, but unfo...

  3. Surface defects and temperature on atomic friction

    Energy Technology Data Exchange (ETDEWEB)

    Fajardo, O Y; Mazo, J J, E-mail: yovany@unizar.es [Departamento de Fisica de la Materia Condensada and Instituto de Ciencia de Materiales de Aragon, CSIC-Universidad de Zaragoza, 50009 Zaragoza (Spain)

    2011-09-07

    We present a theoretical study of the effect of surface defects on atomic friction in the stick-slip dynamical regime of a minimalistic model. We focus on how the presence of defects and temperature change the average properties of the system. We have identified two main mechanisms which modify the mean friction force of the system when defects are considered. As expected, defects change the potential profile locally and thus affect the friction force. But the presence of defects also changes the probability distribution function of the tip slip length and thus the mean friction force. We corroborated both effects for different values of temperature, external load, dragging velocity and damping. We also show a comparison of the effects of surface defects and surface disorder on the dynamics of the system. (paper)

  4. Surface temperature distribution in broiler houses

    Directory of Open Access Journals (Sweden)

    MS Baracho

    2011-09-01

    Full Text Available In the Brazilian meat production scenario broiler production is the most dynamic segment. Despite of the knowledge generated in the poultry production chain, there are still important gaps on Brazilian rearing conditions as housing is different from other countries. This research study aimed at analyzing the variation in bird skin surface as function of heat distribution inside broiler houses. A broiler house was virtually divided into nine sectors and measurements were made during the first four weeks of the grow-out in a commercial broiler farm in the region of Rio Claro, São Paulo, Brazil. Rearing ambient temperature and relative humidity, as well as light intensity and air velocity, were recorded in the geometric center of each virtual sector to evaluate the homogeneity of these parameters. Broiler surface temperatures were recorded using infrared thermography. Differences both in surface temperature (Ts and dry bulb temperature (DBT were significant (p<0.05 as a function of week of rearing. Ts was different between the first and fourth weeks (p<0.05 in both flocks. Results showed important variations in rearing environment parameters (temperature and relative humidity and in skin surface temperature as a function of week and house sector. Air velocity data were outside the limits in the first and third weeks in several sectors. Average light intensity values presented low variation relative to week and house sector. The obtained values were outside the recommended ranges, indicating that broilers suffered thermal distress. This study points out the need to record rearing environment data in order to provide better environmental control during broiler grow-out.

  5. Geomagnetic effects on the average surface temperature

    Science.gov (United States)

    Ballatore, P.

    Several results have previously shown as the solar activity can be related to the cloudiness and the surface solar radiation intensity (Svensmark and Friis-Christensen, J. Atmos. Sol. Terr. Phys., 59, 1225, 1997; Veretenenkoand Pudovkin, J. Atmos. Sol. Terr. Phys., 61, 521, 1999). Here, the possible relationships between the averaged surface temperature and the solar wind parameters or geomagnetic activity indices are investigated. The temperature data used are the monthly SST maps (generated at RAL and available from the related ESRIN/ESA database) that represent the averaged surface temperature with a spatial resolution of 0.5°x0.5° and cover the entire globe. The interplanetary data and the geomagnetic data are from the USA National Space Science Data Center. The time interval considered is 1995-2000. Specifically, possible associations and/or correlations of the average temperature with the interplanetary magnetic field Bz component and with the Kp index are considered and differentiated taking into account separate geographic and geomagnetic planetary regions.

  6. Surface Initiated Polymerizations via e-ATRP in Pure Water

    NARCIS (Netherlands)

    Hosseiny, Seyed Schwan; van Rijn, Patrick

    2013-01-01

    Here we describe the combined process of surface modification with electrochemical atom transfer radical polymerization (e-ATRP) initiated from the surface of a modified gold-electrode in a pure aqueous solution without any additional supporting electrolyte. This approach allows for a very controlle

  7. MODIS Surface Temperatures for Cryosphere Studies (Invited)

    Science.gov (United States)

    Hall, D. K.; Comiso, J. C.; DiGirolamo, N. E.; Shuman, C. A.; Riggs, G. A.

    2013-12-01

    We have used Moderate-resolution Imaging Spectroradiometer (MODIS) land-surface temperature (LST) and ice-surface temperature (IST) products for several applications in studies of the cryosphere. A climate-quality climate data record (CDR) of the IST of the Greenland ice sheet has been developed and was one of the data sources used to monitor the extreme melt event covering nearly the entire Greenland ice sheet on 11 - 12 July 2012. The IST CDR is available online for users to employ in models, and to study temperature distributions and melt trends on the ice sheet. We continue to assess accuracy of the IST product through comparative analysis with air temperature data from the NOAA Logan temperature sensor at Summit Station, Greenland. We find a small offset between the air temperature and the IST with the IST being slightly lower which is consistent with findings of other studies. The LST data product has been applied in studies of snow melt in regions where snow is a significant water resource. We have used LST data in seasonally snow-covered areas such as the Wind River Range, Wyoming, to monitor the relationship between LST and seasonal streamflow. A close association between a sudden and sustained increase in LST and complete snowmelt, and between melt-season maximum LST and maximum daily streamflow has been documented. Use of LST and MODIS snow-cover and products in hydrological models increases the accuracy of the modeled prediction of runoff. The IST and LST products have also been applied to study of sea ice, e.g. extent and concentration, and lake ice, such as determining ice-out dates, and these efforts will also be described.

  8. Atomic simulations for surface-initiated melting of Nb(111)

    Institute of Scientific and Technical Information of China (English)

    YANG Xi-yuan; WU Dan

    2009-01-01

    A modified analytic embedded-atom model(MAEAM) was applied to investigate surface premelting and melting behaviors of Nb(111) plane by molecular dynamics(MD) simulations. First the relaxation of surface interface space at 300 K was studied. Then a number N of the disordered atoms per unit area was determined at the given temperatures to investigate the surface premelting and melting evolution. The obtained results indicated that the premelting phenomena occurred at about 1 100 K and a liquid-like layer emerged on (111) plane simultaneously. As temperature increased up to 2 200 K, the number N grew logarithmically for short-range metallic interactions. Upon 2 350 K surface melting generated originally and the number N increased exponentially with the incremental temperature.

  9. Facile synthesis of thermally stable poly(N-vinylpyrrolidone)-modified gold surfaces by surface-initiated atom transfer radical polymerization.

    Science.gov (United States)

    Liu, Xiaoli; Sun, Kai; Wu, Zhaoqiang; Lu, Jianhong; Song, Bo; Tong, Weifang; Shi, Xiujuan; Chen, Hong

    2012-06-26

    Well-controlled polymerization of N-vinylpyrrolidone (NVP) on Au surfaces by surface-initiated atom transfer radical polymerization (SI-ATRP) was carried out at room temperature by a silanization method. Initial attempts to graft poly(N-vinylpyrrolidone) (PVP) layers from initiators attached to alkanethiol monolayers yielded PVP films with thicknesses less than 5 nm. The combined factors of the difficulty in the controllable polymerization of NVP and the instability of alkanethiol monolayers led to the difficulty in the controlled polymerization of NVP on Au surfaces. Therefore, the silanization method was employed to form an adhesion layer for initiator attachment. This method allowed well-defined ATRP polymerization to occur on Au surfaces. Water contact angle, X-ray photoelectron spectroscopy (XPS), and reflectance Fourier transform infrared (reflectance FTIR) spectroscopy were used to characterize the modified surfaces. The PVP-modified gold surface remained stable at 130 °C for 3 h, showing excellent thermal stability. Thus, postfunctionalization of polymer brushes at elevated temperatures is made possible. The silanization method was also applied to modify SPR chips and showed potential applications in biosensors and biochips.

  10. Low Temperature Surface Carburization of Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Collins, Sunniva R; Heuer, Arthur H; Sikka, Vinod K

    2007-12-07

    Low-temperature colossal supersaturation (LTCSS) is a novel surface hardening method for carburization of austenitic stainless steels (SS) without the precipitation of carbides. The formation of carbides is kinetically suppressed, enabling extremely high or colossal carbon supersaturation. As a result, surface carbon concentrations in excess of 12 at. % are routinely achieved. This treatment increases the surface hardness by a factor of four to five, improving resistance to wear, corrosion, and fatigue, with significant retained ductility. LTCSS is a diffusional surface hardening process that provides a uniform and conformal hardened gradient surface with no risk of delamination or peeling. The treatment retains the austenitic phase and is completely non-magnetic. In addition, because parts are treated at low temperature, they do not distort or change dimensions. During this treatment, carbon diffusion proceeds into the metal at temperatures that constrain substitutional diffusion or mobility between the metal alloy elements. Though immobilized and unable to assemble to form carbides, chromium and similar alloying elements nonetheless draw enormous amounts of carbon into their interstitial spaces. The carbon in the interstitial spaces of the alloy crystals makes the surface harder than ever achieved before by more conventional heat treating or diffusion process. The carbon solid solution manifests a Vickers hardness often exceeding 1000 HV (equivalent to 70 HRC). This project objective was to extend the LTCSS treatment to other austenitic alloys, and to quantify improvements in fatigue, corrosion, and wear resistance. Highlights from the research include the following: • Extension of the applicability of the LTCSS process to a broad range of austenitic and duplex grades of steels • Demonstration of LTCSS ability for a variety of different component shapes and sizes • Detailed microstructural characterization of LTCSS-treated samples of 316L and other alloys

  11. The surface temperature of free evaporating drops

    Science.gov (United States)

    Borodulin, V. Y.; Letushko, V. N.; Nizovtsev, M. I.; Sterlyagov, A. N.

    2016-10-01

    Complex experimental and theoretical investigation of heat and mass transfer processes was performed at evaporation of free liquid drops. For theoretical calculation the emission-diffusion model was proposed. This allowed taking into account the characteristics of evaporation of small droplets, for which heat and mass transfer processes are not described in the conventional diffusion model. The calculation results of evaporation of droplets of different sizes were compared using two models: the conventional diffusion and emission-diffusion models. To verify the proposed physical model, the evaporation of droplets suspended on a polypropylene fiber was experimentally investigated. The form of droplets in the evaporation process was determined using microphotographing. The temperature was measured on the surfaces of evaporating drops using infrared thermography. The experimental results have showed good agreement with the numerical data for the time of evaporation and the temperature of evaporating drops.

  12. Low temperature surface conductivity of hydrogenated diamond

    Energy Technology Data Exchange (ETDEWEB)

    Sauerer, C.; Ertl, F.; Nebel, C.E.; Stutzmann, M. [Technische Univ. Muenchen, Garching (Germany). Walter-Schottky-Inst. fuer Physikalische Grundlagen der Halbleiterelektronik; Bergonzo, P. [LIST(CEA-Recherche Technology)/DIMIR/SIAR/Saclay, Gif-sur-Yvette (France); Williams, O.A.; Jackman, R.A. [University Coll., London (United Kingdom). Dept. of Electrical and Electronic Engineering

    2001-07-23

    Conductivity and Hall experiments are performed on hydrogenated poly-CVD, atomically flat homoepitaxially grown Ib and natural type IIa diamond layers in the regime 0.34 to 400 K. For all experiments hole transport is detected with sheet resistivities at room temperature in the range 10{sup 4} to 10{sup 5} {omega}/{radical}. We introduce a transport model where a disorder induced tail of localized states traps holes at very low temperatures (T < 70 K). The characteristic energy of the tail is in the range of 6 meV. Towards higher temperatures (T > 70 K) the hole density is approximately constant and the hole mobility {mu} is increasing two orders of magnitude. In the regime 70 K < T < 200 K, {mu} is exponentially activated with 22 meV, above it follows a {proportional_to}T{sup 3/2} law. The activation energy of the hole density at T < 70 K is governed by the energy gap between holes trapped in the tail and the mobility edge which they can propagate. In the temperature regime T < 25 K an increasing hole mobility is detected which is attributed to transport in delocalized states at the surface. (orig.)

  13. Synthesis, Characterization, and Surface Initiated Polymerization of Carbazole Functionalized Isocyanides

    NARCIS (Netherlands)

    Schwartz, Erik; Lim, Eunhee; Gowda, Chandrakala M.; Liscio, Andrea; Fenwick, Oliver; Tu, Guoli; Palermo, Vincenzo; Gelder, de Rene; Cornelissen, Jeroen J.L.M.; Eck, van Ernst R.H.; Kentgens, Arno P.M.; Cacialli, Franco; Nolte, Roeland J.M.; Samori, Paolo; Huck, Wilhelm T.S.; Rowan, Alan E.

    2010-01-01

    We describe the design and synthesis of carbazole functionalized isocyanides and the detailed investigation of their properties. Characterization by solid state NMR, CD, and IR spectroscopic techniques reveals that the polymer has a well-defined helical architecture. Surface-initiated polymerization

  14. Palladium-Mediated Surface-Initiated Kumada Catalyst Polycondensation: A Facile Route Towards Oriented Conjugated Polymers.

    Science.gov (United States)

    Huddleston, N Eric; Sontag, S Kyle; Bilbrey, Jenna A; Sheppard, Gareth R; Locklin, Jason

    2012-12-21

    Palladium-mediated surface-initiated Kumada catalyst transfer polycondensation is used to generate poly(3-methyl thiophene) films with controlled thickness up to 100 nm. The palladium initiator density is measured using cyclic voltammetry and a ferrocene-capping agent, where the surface density is found to be 55% (1.1 × 10(14) molecules per cm(2)). UV-Vis spectroscopy and AFM show increased aggregation in palladium-initiated films due to the higher grafting density of palladium initiators on the surface. The anisotropy of the P3MT films is determined using polarized UV-Vis spectroscopy, which indicates a degree of orientation perpendicular to the substrate. Evidence that palladium can maintain π-complexation even at elevated temperatures, is also shown through the exclusive intramolecular coupling of both a phenyl and thiophene-based magnesium bromide with different dihaloarenes.

  15. Extended Reconstructed Sea Surface Temperature (ERSST), Version 4

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Extended Reconstructed Sea Surface Temperature (ERSST) dataset is a global monthly sea surface temperature analysis on a 2x2 degree grid derived from the...

  16. NOAA Global Surface Temperature Dataset, Version 4.0

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The NOAA Global Surface Temperature Dataset (NOAAGlobalTemp) is derived from two independent analyses: the Extended Reconstructed Sea Surface Temperature (ERSST)...

  17. HTPro: Low-temperature Surface Hardening of Stainless Steel

    DEFF Research Database (Denmark)

    Christiansen, Thomas Lundin; Somers, Marcel A. J.

    2013-01-01

    Low-temperature surface hardening of stainless steel provides the required performance properties without affecting corrosion resistance.......Low-temperature surface hardening of stainless steel provides the required performance properties without affecting corrosion resistance....

  18. Merged Land and Ocean Surface Temperature, Version 3.5

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The historical Merged Land-Ocean Surface Temperature Analysis (MLOST) is derived from two independent analyses, an Extended Reconstructed Sea Surface Temperature...

  19. On Surface-Initiated Atom Transfer Radical Polymerization Using Diazonium Chemistry To Introduce the Initiator Layer

    DEFF Research Database (Denmark)

    Chernyy, Sergey; Lillethorup, Mie; Ceccato, Marcel

    2011-01-01

    of bromine shows a gradual transition from mushroom to brush-type conformation of the surface anchored chains in both polar and nonpolar reaction medium. Interestingly, it is revealed that very thick polymer brushes, on the order of 1 μm, can be obtained at high bromine content of the initiator layer...

  20. Middle Pliocene sea surface temperature variability

    Science.gov (United States)

    Dowsett, H.J.; Chandler, M.A.; Cronin, T. M.; Dwyer, G.S.

    2005-01-01

    Estimates of sea surface temperature (SST) based upon foraminifer, diatom, and ostracod assemblages from ocean cores reveal a warm phase of the Pliocene between about 3.3 and 3.0 Ma. Pollen records and plant megafossils, although not as well dated, show evidence for a warmer climate at about the same time. Increased greenhouse forcing and altered ocean heat transport are the leading candidates for the underlying cause of Pliocene global warmth. Despite being a period of global warmth, this interval encompasses considerable variability. Two new SST reconstructions are presented that are designed to provide a climatological error bar for warm peak phases of the Pliocene and to document the spatial distribution and magnitude of SST variability within the mid-Pliocene warm period. These data suggest long-term stability of low-latitude SST and document greater variability in regions of maximum warming. Copyright 2005 by the American Geophysical Union.

  1. Impact of Atlantic sea surface temperatures on the warmest global surface air temperature of 1998

    Science.gov (United States)

    Lu, Riyu

    2005-03-01

    The year 1998 is the warmest year in the record of instrumental measurements. In this study, an atmospheric general circulation model is used to investigate the role of sea surface temperatures (SSTs) in this warmth, with a focus on the role of the Atlantic Ocean. The model forced with the observed global SSTs captures the main features of land surface air temperature anomalies in 1998. A sensitivity experiment shows that in comparison with the global SST anomalies, the Atlantic SST anomalies can explain 35% of the global mean surface air temperature (GMAT) anomaly, and 57% of the land surface air temperature anomaly in 1998. The mechanisms through which the Atlantic Ocean influences the GMAT are likely different from season to season. Possible detailed mechanisms involve the impact of SST anomalies on local convection in the tropical Atlantic region, the consequent excitation of a Rossby wave response that propagates into the North Atlantic and the Eurasian continent in winter and spring, and the consequent changes in tropical Walker circulation in summer and autumn that induce changes in convection over the tropical Pacific. This in turn affects climate in Asia and Australia. The important role of the Atlantic Ocean suggests that attention should be paid not only to the tropical Pacific Ocean, but also to the tropical Atlantic Ocean in understanding the GMAT variability and its predictability.

  2. Low Temperature Surface Carburization of Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Collins, Sunniva R; Heuer, Arthur H; Sikka, Vinod K

    2007-12-07

    Low-temperature colossal supersaturation (LTCSS) is a novel surface hardening method for carburization of austenitic stainless steels (SS) without the precipitation of carbides. The formation of carbides is kinetically suppressed, enabling extremely high or colossal carbon supersaturation. As a result, surface carbon concentrations in excess of 12 at. % are routinely achieved. This treatment increases the surface hardness by a factor of four to five, improving resistance to wear, corrosion, and fatigue, with significant retained ductility. LTCSS is a diffusional surface hardening process that provides a uniform and conformal hardened gradient surface with no risk of delamination or peeling. The treatment retains the austenitic phase and is completely non-magnetic. In addition, because parts are treated at low temperature, they do not distort or change dimensions. During this treatment, carbon diffusion proceeds into the metal at temperatures that constrain substitutional diffusion or mobility between the metal alloy elements. Though immobilized and unable to assemble to form carbides, chromium and similar alloying elements nonetheless draw enormous amounts of carbon into their interstitial spaces. The carbon in the interstitial spaces of the alloy crystals makes the surface harder than ever achieved before by more conventional heat treating or diffusion process. The carbon solid solution manifests a Vickers hardness often exceeding 1000 HV (equivalent to 70 HRC). This project objective was to extend the LTCSS treatment to other austenitic alloys, and to quantify improvements in fatigue, corrosion, and wear resistance. Highlights from the research include the following: • Extension of the applicability of the LTCSS process to a broad range of austenitic and duplex grades of steels • Demonstration of LTCSS ability for a variety of different component shapes and sizes • Detailed microstructural characterization of LTCSS-treated samples of 316L and other alloys

  3. Surface Initiated Polymerizations via e-ATRP in Pure Water

    Directory of Open Access Journals (Sweden)

    Seyed Schwan Hosseiny

    2013-10-01

    Full Text Available Here we describe the combined process of surface modification with electrochemical atom transfer radical polymerization (e-ATRP initiated from the surface of a modified gold-electrode in a pure aqueous solution without any additional supporting electrolyte. This approach allows for a very controlled growth of the polymer chains leading towards a steady increase in film thickness. Electrochemical quartz crystal microbalance displayed a highly regular increase in surface confined mass only after the addition of the pre-copper catalyst which is reduced in situ and transformed into the catalyst. Even after isolation and washing of the modified electrode surface, reinitiation was achieved with retention of the controlled electrochemical ATRP reaction. This reinitiation after isolation proves the livingness of the polymerization. This approach has interesting potential for smart thin film materials and offers also the possibility of post-modification via additional electrochemical induced reactions.

  4. Turbulent Flow past High Temperature Surfaces

    Science.gov (United States)

    Mehmedagic, Igbal; Thangam, Siva; Carlucci, Pasquale; Buckley, Liam; Carlucci, Donald

    2014-11-01

    Flow over high-temperature surfaces subject to wall heating is analyzed with applications to projectile design. In this study, computations are performed using an anisotropic Reynolds-stress model to study flow past surfaces that are subject to radiative flux. The model utilizes a phenomenological treatment of the energy spectrum and diffusivities of momentum and heat to include the effects of wall heat transfer and radiative exchange. The radiative transport is modeled using Eddington approximation including the weighted effect of nongrayness of the fluid. The time-averaged equations of motion and energy are solved using the modeled form of transport equations for the turbulence kinetic energy and the scalar form of turbulence dissipation with an efficient finite-volume algorithm. The model is applied for available test cases to validate its predictive capabilities for capturing the effects of wall heat transfer. Computational results are compared with experimental data available in the literature. Applications involving the design of projectiles are summarized. Funded in part by U.S. Army, ARDEC.

  5. Use of satellite land surface temperatures in the EUSTACE global surface air temperature analysis

    Science.gov (United States)

    Ghent, D.; Good, E.; Rayner, N. A.

    2015-12-01

    EUSTACE (EU Surface Temperatures for All Corners of Earth) is a Horizon2020 project that will produce a spatially complete, near-surface air temperature (NSAT) analysis for the globe for every day since 1850. The analysis will be based on both satellite and in situ surface temperature observations over land, sea, ice and lakes, which will be combined using state-of-the-art statistical methods. The use of satellite data will enable the EUSTACE analysis to offer improved estimates of NSAT in regions that are poorly observed in situ, compared with existing in-situ based analyses. This presentation illustrates how satellite land surface temperature (LST) data - sourced from the European Space Agency (ESA) Data User Element (DUE) GlobTemperature project - will be used in EUSTACE. Satellite LSTs represent the temperature of the Earth's skin, which can differ from the corresponding NSAT by several degrees or more, particularly during the hottest part of the day. Therefore the first challenge is to develop an approach to estimate global NSAT from satellite observations. Two methods will be trialled in EUSTACE, both of which are summarised here: an established empirical regression-based approach for predicting NSAT from satellite data, and a new method whereby NSAT is calculated from LST and other parameters using a physics-based model. The second challenge is in estimating the uncertainties for the satellite NSAT estimates, which will determine how these data are used in the final blended satellite-in situ analysis. This is also important as a key component of EUSTACE is in delivering accurate uncertainty information to users. An overview of the methods to estimate the satellite NSATs is also included in this presentation.

  6. Initial value problem of the toroidal ion temperature gradient mode

    Energy Technology Data Exchange (ETDEWEB)

    Kuroda, T.; Sugama, H.; Kanno, R.; Okamoto, M. [National Inst. for Fusion Science, Toki, Gifu (Japan); Horton, W.

    1998-06-01

    The initial value problem of the toroidal ion temperature gradient mode is studied based on the Laplace transform of the ion gyrokinetic equation and the electron Boltzmann relation with the charge neutrality condition. Due to the toroidal magnetic drift, the Laplace-transformed density and potential perturbations have a branch cut as well as poles on the complex-frequency plane. The inverse Laplace transform shows that the temporal evolution of the density and potential perturbations consists of the normal modes and the continuum mode, which correspond to contributions from the poles and the branch cut, respectively. The normal modes have exponential time dependence with the eigenfrequencies determined by the dispersion relation while the continuum mode shows power-law decay oscillation. For the stable case, the long-time asymptotic behavior of the potential and density perturbations is dominated by the continuum mode which decays slower than the normal modes. (author)

  7. Stable glass transformation to supercooled liquid via surface-initiated growth front.

    Science.gov (United States)

    Swallen, Stephen F; Traynor, Katherine; McMahon, Robert J; Ediger, M D; Mates, Thomas E

    2009-02-13

    Highly stable glasses of tris-naphthylbenzene transform into a liquid when annealed above the glass transition temperature T_{g}. In contrast to the predictions of standard models, the observed transformation is spatially inhomogeneous. Secondary ion mass spectrometry experiments on isotopically labeled multilayer films show that the liquid grows into the stable glass with sharp growth fronts initiated at the free surface and at the interface with the substrate. For the free surface, the growth velocity is constant in time and has the same temperature dependence as self-diffusion in the equilibrium supercooled liquid. These stable glasses are packed so efficiently that surfaces and interfaces are required to initiate the transformation to the liquid even well above T_{g}.

  8. Footwear and Foam Surface Alter Gait Initiation of Typical Subjects.

    Directory of Open Access Journals (Sweden)

    Marcus Fraga Vieira

    Full Text Available Gait initiation is the task commonly used to investigate the anticipatory postural adjustments necessary to begin a new gait cycle from the standing position. In this study, we analyzed whether and how foot-floor interface characteristics influence the gait initiation process. For this purpose, 25 undergraduate students were evaluated while performing a gait initiation task in three experimental conditions: barefoot on a hard surface (barefoot condition, barefoot on a soft surface (foam condition, and shod on a hard surface (shod condition. Two force plates were used to acquire ground reaction forces and moments for each foot separately. A statistical parametric mapping (SPM analysis was performed in COP time series. We compared the anterior-posterior (AP and medial-lateral (ML resultant center of pressure (COP paths and average velocities, the force peaks under the right and left foot, and the COP integral x force impulse for three different phases: the anticipatory postural adjustment (APA phase (Phase 1, the swing-foot unloading phase (Phase 2, and the support-foot unloading phase (Phase 3. In Phase 1, significantly smaller ML COP paths and velocities were found for the shod condition compared to the barefoot and foam conditions. Significantly smaller ML COP paths were also found in Phase 2 for the shod condition compared to the barefoot and foam conditions. In Phase 3, increased AP COP velocities were found for the shod condition compared to the barefoot and foam conditions. SPM analysis revealed significant differences for vector COP time series in the shod condition compared to the barefoot and foam conditions. The foam condition limited the impulse-generating capacity of COP shift and produced smaller ML force peaks, resulting in limitations to body-weight transfer from the swing to the support foot. The results suggest that footwear and a soft surface affect COP and impose certain features of gait initiation, especially in the ML

  9. Footwear and Foam Surface Alter Gait Initiation of Typical Subjects.

    Science.gov (United States)

    Vieira, Marcus Fraga; Sacco, Isabel de Camargo Neves; Nora, Fernanda Grazielle da Silva Azevedo; Rosenbaum, Dieter; Lobo da Costa, Paula Hentschel

    2015-01-01

    Gait initiation is the task commonly used to investigate the anticipatory postural adjustments necessary to begin a new gait cycle from the standing position. In this study, we analyzed whether and how foot-floor interface characteristics influence the gait initiation process. For this purpose, 25 undergraduate students were evaluated while performing a gait initiation task in three experimental conditions: barefoot on a hard surface (barefoot condition), barefoot on a soft surface (foam condition), and shod on a hard surface (shod condition). Two force plates were used to acquire ground reaction forces and moments for each foot separately. A statistical parametric mapping (SPM) analysis was performed in COP time series. We compared the anterior-posterior (AP) and medial-lateral (ML) resultant center of pressure (COP) paths and average velocities, the force peaks under the right and left foot, and the COP integral x force impulse for three different phases: the anticipatory postural adjustment (APA) phase (Phase 1), the swing-foot unloading phase (Phase 2), and the support-foot unloading phase (Phase 3). In Phase 1, significantly smaller ML COP paths and velocities were found for the shod condition compared to the barefoot and foam conditions. Significantly smaller ML COP paths were also found in Phase 2 for the shod condition compared to the barefoot and foam conditions. In Phase 3, increased AP COP velocities were found for the shod condition compared to the barefoot and foam conditions. SPM analysis revealed significant differences for vector COP time series in the shod condition compared to the barefoot and foam conditions. The foam condition limited the impulse-generating capacity of COP shift and produced smaller ML force peaks, resulting in limitations to body-weight transfer from the swing to the support foot. The results suggest that footwear and a soft surface affect COP and impose certain features of gait initiation, especially in the ML direction of

  10. Monitoring temperature and pressure over surfaces using sensitive paints

    Science.gov (United States)

    Guerrero-Viramontes, J. Ascención; Moreno Hernández, David; Mendoza Santoyo, Fernando; Morán Loza, José Miguel; García Arreola, Alicia

    2007-03-01

    Two techniques for monitoring temperature and pressure variations over surfaces using sensitive paints are presented. The analysis is done by the acquisition of a set of images of the surface under analysis. The surface is painted by a paint called Pressure Sensitive Paint (PSP) for pressure measurements and Temperature Sensitive Paints (TSP) for temperature measurements. These kinds of paints are deposited over the surface under analysis. The recent experimental advances in calibration process are presented in this paper.

  11. Impact of land-surface initialization on sub-seasonal to seasonal forecasts over Europe

    Science.gov (United States)

    Prodhomme, Chloé; Doblas-Reyes, Francisco; Bellprat, Omar; Dutra, Emanuel

    2016-08-01

    Land surfaces and soil conditions are key sources of climate predictability at the seasonal time scale. In order to estimate how the initialization of the land surface affects the predictability at seasonal time scale, we run two sets of seasonal hindcasts with the general circulation model EC-Earth2.3. The initialization of those hindcasts is done either with climatological or realistic land initialization in May using the ERA-Land re-analysis. Results show significant improvements in the initialized run occurring up to the last forecast month. The prediction of near-surface summer temperatures and precipitation at the global scale and over Europe are improved, as well as the warm extremes prediction. As an illustration, we show that the 2010 Russian heat wave is only predicted when soil moisture is initialized. No significant improvement is found for the retrospective prediction of the 2003 European heat wave, suggesting this event to be mainly large-scale driven. Thus, we confirm that late-spring soil moisture conditions can be decisive in triggering high-impact events in the following summer in Europe. Accordingly, accurate land-surface initial conditions are essential for seasonal predictions.

  12. Estimation of sea surface temperature (SST) using marine seismic data

    Digital Repository Service at National Institute of Oceanography (India)

    Sinha, S.K.; Dewangan, P.; Sain, K.

    .g. Wu et al. [1999]). However, due to the skin effect, sea surface temperatures as measured by satellites can be very different from temperatures a few centimeters below the sea surface (i.e. in-situ temperatures) [Emery et al., 1994]. Therefore...

  13. Noncontact Monitoring of Surface Temperature Distribution by Laser Ultrasound Scanning

    Science.gov (United States)

    Yamada, Hiroyuki; Kosugi, Akira; Ihara, Ikuo

    2011-07-01

    A laser ultrasound scanning method for measuring a surface temperature distribution of a heated material is presented. An experiment using an aluminum plate heated up to 120 °C is carried out to verify the feasibility of the proposed method. A series of one-dimensional surface acoustic wave (SAW) measurements within an area of a square on the aluminum surface are performed by scanning a pulsed laser for generating SAW using a galvanometer system, where the SAWs are detected at a fixed location on the surface. An inverse analysis is then applied to SAW data to determine the surface temperature distribution in a certain direction. The two-dimensional distribution of the surface temperature in the square is constructed by combining the one-dimensional surface temperature distributions obtained within the square. The surface temperature distributions obtained by the proposed method almost agrees with those obtained using an infrared radiation camera.

  14. Technique for the estimation of surface temperatures from embedded temperature sensing for rapid, high energy surface deposition.

    Energy Technology Data Exchange (ETDEWEB)

    Watkins, Tyson R.; Schunk, Peter Randall; Roberts, Scott Alan

    2014-07-01

    Temperature histories on the surface of a body that has been subjected to a rapid, highenergy surface deposition process can be di cult to determine, especially if it is impossible to directly observe the surface or attach a temperature sensor to it. In this report, we explore two methods for estimating the temperature history of the surface through the use of a sensor embedded within the body very near to the surface. First, the maximum sensor temperature is directly correlated with the peak surface temperature. However, it is observed that the sensor data is both delayed in time and greatly attenuated in magnitude, making this approach unfeasible. Secondly, we propose an algorithm that involves tting the solution to a one-dimensional instantaneous energy solution problem to both the sensor data and to the results of a one-dimensional CVFEM code. This algorithm is shown to be able to estimate the surface temperature 20 C.

  15. The impact of heterogeneous surface temperatures on the 2-m air temperature over the Arctic Ocean in spring

    Directory of Open Access Journals (Sweden)

    A. Tetzlaff

    2012-07-01

    Full Text Available The influence of spatial surface temperature changes over the Arctic Ocean on the 2-m air temperature variability is estimated using backward trajectories based on ERA-Interim and the JRA25 wind fields. They are initiated at Alert, Barrow and at the Tara drifting station. Three different methods are used. The first one compares mean ice surface temperatures along the trajectories to the observed 2-m air temperatures at the stations. The second one correlates the observed temperatures to air temperatures obtained using a simple Lagrangian box model which only includes the effect of sensible heat fluxes. For the third method, mean sensible heat fluxes from the model are correlated with the difference of the air temperatures at the model starting point and the observed temperatures at the stations. The calculations are based on MODIS ice surface temperatures and four different sets of ice concentration derived from SSM/I and AMSR-E data. Under nearly cloud free conditions, up to 90% of the 2-m air temperature variance can be explained for Alert, and 60% for Barrow using these methods. The differences are attributed to the different ice conditions, which are characterized by high ice concentration around Alert and lower ice concentration near Barrow. These results are robust for the different sets of reanalyses and ice concentration data. Near-surface winds of both reanalyses show a large inconsistency in the Central Arctic, which leads to a large difference in the correlations between modeled and observed 2-m air temperatures at Tara. Explained variances amount to 70% using JRA and only 45% using ERA. The results also suggest that near-surface temperatures at a given site are influenced by the variability of surface temperatures in a domain of about 150 to 350 km radius around the site.

  16. Metrology to enable high temperature erosion testing - A new european initiative

    DEFF Research Database (Denmark)

    Fry, A.T.; Gee, M.G.; Clausen, Sønnik

    2014-01-01

    or mineral matter in oil excavation. In all cases the performance of materials can be improved through better surface engineering and coatings, but the development of these is restricted due to lack of generic models, well controlled and instrumented tests and international standards. A framework is required...... therefore that can be applied to these different situations to characterise the high temperature erosion performance of new materials and coatings and thereby accelerate their development and design. To achieve this, a step change in the test methods and control of high temperature solid particle erosion...... is required. However, limitations in current measurement capability within this form of test prevent the advancement. A new European initiative, METROSION, on the development of high temperature solid particle erosion testing has a primary aim to develop this metrological framework. Several key parameters...

  17. Determination of Land Surface Temperature (LST) and Potential ...

    African Journals Online (AJOL)

    Determination of Land Surface Temperature (LST) and Potential Urban Heat Island Effect in Parts of Lagos State using Satellite ... Changes in temperature appear to be closely related to concentrations of atmospheric carbon dioxide.

  18. Initial stages of Zr-Fe-Si alloy formation on Zr(0001) surface

    Science.gov (United States)

    Horáková, Kateřina; Cichoň, Stanislav; Lančok, Ján; Sajdl, Petr; Cháb, Vladimír

    2017-03-01

    We studied initial stages of Fe and Si atoms interaction with the Zr(0001) surface. Fe and Si were deposited in-situ on the clean Zr surface up to coverage of one monolayer. Chemical state of Zr as a function of annealing temperature and the surface composition was investigated. Characteristic (1×1) LEED (Low Energy Electron Diffraction) pattern of the clean Zr surface becomes significantly modified when Fe and Si are deposited and annealed at 400 °C. The arrangement of new spots of the pattern corresponds to the (2√3×2√3)R30° structure, stable up to annealing at 750 °C. Changes in the electronic structure were identified from the images of equi-energy cuts of the k-space covering the entire Brillouin zone. The results imply that hydrogen, typically present in the clean surface, was eliminated either by annealing or upon the deposition of Fe and Si.

  19. Temperature dependent droplet impact dynamics on flat and textured surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Azar Alizadeh; Vaibhav Bahadur; Sheng Zhong; Wen Shang; Ri Li; James Ruud; Masako Yamada; Liehi Ge; Ali Dhinojwala; Manohar S Sohal (047160)

    2012-03-01

    Droplet impact dynamics determines the performance of surfaces used in many applications such as anti-icing, condensation, boiling and heat transfer. We study impact dynamics of water droplets on surfaces with chemistry/texture ranging from hydrophilic to superhydrophobic and across a temperature range spanning below freezing to near boiling conditions. Droplet retraction shows very strong temperature dependence especially for hydrophilic surfaces; it is seen that lower substrate temperatures lead to lesser retraction. Physics-based analyses show that the increased viscosity associated with lower temperatures can explain the decreased retraction. The present findings serve to guide further studies of dynamic fluid-structure interaction at various temperatures.

  20. Initial stage of flat plate impact onto liquid free surface

    Science.gov (United States)

    Iafrati, Alessandro; Korobkin, Alexander A.

    2004-07-01

    The liquid flow and the free surface shape during the initial stage of flat plate impact onto liquid half-space are investigated. Method of matched asymptotic expansions is used to derive equations of motion and boundary conditions in the main flow region and in small vicinities of the plate edges. Asymptotic analysis is performed within the ideal and incompressible liquid model. The liquid flow is assumed potential and two dimensional. The ratio of the plate displacement to the plate width plays the role of a small parameter. In the main region the flow is given in the leading order by the pressure-impulse theory. This theory provides the flow field around the plate after a short acoustic stage and predicts unbounded velocity of the liquid at the plate edges. In order to resolve the singular flow caused by the normal impact of a flat plate, the fine pattern of the flow in small vicinities of the plate edges is studied. It is shown that the initial flow close to the plate edges is self-similar in the leading order and is governed by nonlinear boundary-value problem with unknown shape of the free surface. The Kutta conditions are imposed at the plate edges, in order to obtain a nonsingular inner solution. This boundary-value problem is solved numerically by iterations. At each step of iterations the "inner" velocity potential is calculated by the boundary-element method. The asymptotics of the inner solution in both the far field and the jet region are obtained to make the numerical algorithm more efficient. The numerical procedure is carefully verified. Agreement of the computed free surface shape with available experimental data is fairly good. Stability of the numerical solution and its convergence are discussed.

  1. Metrology to enable high temperature erosion testing - A new european initiative

    DEFF Research Database (Denmark)

    Fry, A.T.; Gee, M.G.; Clausen, Sønnik

    2014-01-01

    or mineral matter in oil excavation. In all cases the performance of materials can be improved through better surface engineering and coatings, but the development of these is restricted due to lack of generic models, well controlled and instrumented tests and international standards. A framework is required...... is required. However, limitations in current measurement capability within this form of test prevent the advancement. A new European initiative, METROSION, on the development of high temperature solid particle erosion testing has a primary aim to develop this metrological framework. Several key parameters...

  2. Heat-transfer dynamics during cryogen spray cooling of substrate at different initial temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Jia Wangcun [Beckman Laser Institute, University of California, 1002 Health Sciences Road East, Irvine, CA 92612-1475 (United States); Aguilar, Guillermo [Beckman Laser Institute, University of California, 1002 Health Sciences Road East, Irvine, CA 92612-1475 (United States); Wang Guoxiang [Department of Mechanical Engineering, University of Akron, OH 44325 (United States); Nelson, J Stuart [Beckman Laser Institute, University of California, 1002 Health Sciences Road East, Irvine, CA 92612-1475 (United States)

    2004-12-07

    Cryogen spray cooling (CSC) is used to minimize the risk of epidermal damage during laser dermatologic therapy. However, the dominant mechanisms of heat transfer during the transient cooling process are incompletely understood. The objective of this study is to elucidate the physics of CSC by measuring the effect of initial substrate temperature (T{sub 0}) on cooling dynamics. Cryogen was delivered by a straight-tube nozzle onto a skin phantom. A fast-response thermocouple was used to record the phantom temperature changes before, during and after the cryogen spray. Surface heat fluxes (q'') and heat-transfer coefficients (h) were computed using an inverse heat conduction algorithm. The maximum surface heat flux (q''{sub max}) was observed to increase with T{sub 0}. The surface temperature corresponding to q''{sub max} also increased with T{sub 0} but the latter has no significant effect on h. It is concluded that heat transfer between the cryogen spray and skin phantom remains in the nucleate boiling region even if T{sub 0} is 80 {sup 0}C.

  3. Predicting monsoon rainfall and pressure indices from sea surface temperature

    Digital Repository Service at National Institute of Oceanography (India)

    Sadhuram, Y.

    The relationship between the sea surface temperature (SST) in the Indian Ocean and monsoon rainfall has been examined by using 21 years data set (1967-87) of MOHSST.6 (Met. Office Historical Sea Surface Temperature data set, obtained from U.K. Met...

  4. Metal surface temperature induced by moving laser beams

    NARCIS (Netherlands)

    Römer, G.R.B.E.; Meijer, J.

    1995-01-01

    Whenever a metal is irradiated with a laser beam, electromagnetic energy is transformed into heat in a thin surface layer. The maximum surface temperature is the most important quantity which determines the processing result. Expressions for this maximum temperature are provided by the literature fo

  5. Recent trends in sea surface temperature off Mexico

    NARCIS (Netherlands)

    Lluch-Cota, S.E.; Tripp-Valdéz, M.; Lluch-Cota, D.B.; Lluch-Belda, D.; Verbesselt, J.; Herrera-Cervantes, H.; Bautista-Romero, J.

    2013-01-01

    Changes in global mean sea surface temperature may have potential negative implications for natural and socioeconomic systems; however, measurements to predict trends in different regions have been limited and sometimes contradictory. In this study, an assessment of sea surface temperature change si

  6. Recent trends in sea surface temperature off Mexico

    NARCIS (Netherlands)

    Lluch-Cota, S.E.; Tripp-Valdéz, M.; Lluch-Cota, D.B.; Lluch-Belda, D.; Verbesselt, J.; Herrera-Cervantes, H.; Bautista-Romero, J.

    2013-01-01

    Changes in global mean sea surface temperature may have potential negative implications for natural and socioeconomic systems; however, measurements to predict trends in different regions have been limited and sometimes contradictory. In this study, an assessment of sea surface temperature change

  7. Predicting Initial Formation Temperature for Deep Well Engineering with a New Method

    Institute of Scientific and Technical Information of China (English)

    Fuzong Zhou; Yucheng Xiong; Ming Tian

    2015-01-01

    With the progress of science and technology, human beings explore the energy under-ground with thousands of meters. As a thermophysical parameter, initial formation temperature (IFT) plays an essential role in deep well engineering. However, it is not easy to predict the IFT ac-curately before drilling. This work uses a new method to analyze the effect factors of the under-ground temperature field, and assumes an artificial surface to eliminate the disturbance of the hu-man errors and equipment errors on the surface temperature and thermal conductivity. Consider-ing different distributions of the formation thermal conductivity and the rock radiogenic heat pro-duction, an optimized model was established. With this model, the paper predicted the bottom tem-perature of the main hole of the Chinese Continental Scientific Drilling (CCSD) as 132.80 ºC at 4 725 m depth with 0.5% error. When the thermal conduction is dominant in the formation, this simple method can predict the IFT distribution effectively for deep well in the exploration stage. However, it is almost impossible to avoid aquifers in the formation of drilling deep well, an existing drillhole including groundwater is needed to predict for testing the model’s accuracy.

  8. Interferometric measurements of sea surface temperature and emissivity

    Science.gov (United States)

    Fiedler, Lars; Bakan, Stephan

    1997-09-01

    A new multispectral method to derive sea surface emissivity and temperature by using interferometer measurements of the near surface upwelling radiation in the infrared window region is presented. As reflected sky radiation adds substantial spectral variability to the otherwise spectrally smooth surface radiation, an appropriate estimate of surface emissivity allows the measured upwelling radiation to be corrected for the reflected sky component. The remaining radiation, together with the estimated surface emissivity, yields an estimate of the sea surface temperature. Measurements from an ocean pier in the Baltic Sea in October 1995 indicate an accuracy of about 0.1 K for the sea surface temperature thus derived. A strong sea surface skin effect of about 0.6 K is found in that particular case.

  9. A Modeling and Verification Study of Summer Precipitation Systems Using NASA Surface Initialization Datasets

    Science.gov (United States)

    Jonathan L. Case; Kumar, Sujay V.; Srikishen, Jayanthi; Jedlovec, Gary J.

    2010-01-01

    One of the most challenging weather forecast problems in the southeastern U.S. is daily summertime pulse-type convection. During the summer, atmospheric flow and forcing are generally weak in this region; thus, convection typically initiates in response to local forcing along sea/lake breezes, and other discontinuities often related to horizontal gradients in surface heating rates. Numerical simulations of pulse convection usually have low skill, even in local predictions at high resolution, due to the inherent chaotic nature of these precipitation systems. Forecast errors can arise from assumptions within parameterization schemes, model resolution limitations, and uncertainties in both the initial state of the atmosphere and land surface variables such as soil moisture and temperature. For this study, it is hypothesized that high-resolution, consistent representations of surface properties such as soil moisture, soil temperature, and sea surface temperature (SST) are necessary to better simulate the interactions between the surface and atmosphere, and ultimately improve predictions of summertime pulse convection. This paper describes a sensitivity experiment using the Weather Research and Forecasting (WRF) model. Interpolated land and ocean surface fields from a large-scale model are replaced with high-resolution datasets provided by unique NASA assets in an experimental simulation: the Land Information System (LIS) and Moderate Resolution Imaging Spectroradiometer (MODIS) SSTs. The LIS is run in an offline mode for several years at the same grid resolution as the WRF model to provide compatible land surface initial conditions in an equilibrium state. The MODIS SSTs provide detailed analyses of SSTs over the oceans and large lakes compared to current operational products. The WRF model runs initialized with the LIS+MODIS datasets result in a reduction in the overprediction of rainfall areas; however, the skill is almost equally as low in both experiments using

  10. Linking leaf initiation to the aerial environment: when air temperature is not the whole story

    NARCIS (Netherlands)

    Savvides, A.

    2014-01-01

    The initiation of new leaves, which takes place at the shoot apical meristem, is essential for plant growth and development. Leaf initiation rate (LIR) is very sensitive to meristem temperature. However, in practice meristem temperature is hardly ever monitored and air temperature is often used

  11. Constraining storm-scale forecasts of deep convective initiation with surface weather observations

    Science.gov (United States)

    Madaus, Luke

    Successfully forecasting when and where individual convective storms will form remains an elusive goal for short-term numerical weather prediction. In this dissertation, the convective initiation (CI) challenge is considered as a problem of insufficiently resolved initial conditions and dense surface weather observations are explored as a possible solution. To better quantify convective-scale surface variability in numerical simulations of discrete convective initiation, idealized ensemble simulations of a variety of environments where CI occurs in response to boundary-layer processes are examined. Coherent features 1-2 hours prior to CI are found in all surface fields examined. While some features were broadly expected, such as positive temperature anomalies and convergent winds, negative temperature anomalies due to cloud shadowing are the largest surface anomaly seen prior to CI. Based on these simulations, several hypotheses about the required characteristics of a surface observing network to constrain CI forecasts are developed. Principally, these suggest that observation spacings of less than 4---5 km would be required, based on correlation length scales. Furthermore, it is anticipated that 2-m temperature and 10-m wind observations would likely be more relevant for effectively constraining variability than surface pressure or 2-m moisture observations based on the magnitudes of observed anomalies relative to observation error. These hypotheses are tested with a series of observing system simulation experiments (OSSEs) using a single CI-capable environment. The OSSE results largely confirm the hypotheses, and with 4-km and particularly 1-km surface observation spacing, skillful forecasts of CI are possible, but only within two hours of CI time. Several facets of convective-scale assimilation, including the need for properly-calibrated localization and problems from non-Gaussian ensemble estimates of the cloud field are discussed. Finally, the characteristics

  12. Preparation of polyamide 6/silica nanocomposites from silica surface initiated ring-opening anionic polymerization

    Directory of Open Access Journals (Sweden)

    2007-07-01

    Full Text Available Polyamide 6/silica nanocomposites were synthesized by in situ ring-opening anionic polymerization of ε-caprolactam in the presence of sodium caprolactamate as a catalyst and caprolactam-functionalized silica as an initiator. The initiator precursor, isocyanate-functionalized silica, was prepared by directly reacting commercial silica with excess toluene 2,4-diisocyanate. This polymerization was found to occur in a highly efficient manner at relatively low reaction temperature (170°C and short reaction times (6 h. FTIR spectroscopy was utilized to follow the introduction and consumption of isocyanate groups on the silica surface. Thermogravimetric analysis indicated that the polyamide 6 was successfully grown from the silica surface. Transmission electron microscopy was utilized to image polymer-functionalized silica, showing fine dispersion of silica particles and their size ranging from 20 to 40 nm.

  13. Preparation of CoP films by ultrasonic electroless deposition at low initial temperature

    Institute of Scientific and Technical Information of China (English)

    Yundan Yu; Zhenlun Song; Hongliang Ge; Guoying Wei

    2014-01-01

    Electroless deposition technology has been considered as a kind of common ways to obtain cobalt alloy films. However, in order to get cobalt alloy films, high temperature (353 K) is necessary during the electroless deposition process which will increase costs and energy consumption. Ultrasonic was introduced during electroless plating process to obtain cobalt alloy films at lower initial temperature. It was found that the cobalt thin films could be prepared at lower initial temperature (323 K) with the introduction of ultrasonic. Therefore, different powers of ultrasonic were applied during the electroless deposition process to prepare CoP thin films on copper substrates from an alkaline bath in this investigation. The effects of different powers of ultrasonic on deposition rate, surface morphology, anticorrosion performance and magnetic property of films were studied. It was found that the deposition rate increased gradually with the rise in ultrasonic powers due to cavitation phenomenon. All the CoP films presented the typical spherical nodular structures with the impact of ultrasonic. Smaller and regular shaped structures could be observed when the films were deposited with higher power of ultrasonic which contributed directly to enhancement of anticorrosion performance. Saturation magnetization and coercivity of thin films increased gradually with the rise in ultrasonic powers during the electroless deposition process due to the higher amounts of cobalt.

  14. Evaluation of MODIS Land Surface Temperature with In Situ Snow Surface Temperature from CREST-SAFE

    Science.gov (United States)

    Perez Diaz, C. L.; Lakhankar, T.; Romanov, P.; Munoz, J.; Khanbilvardi, R.; Yu, Y.

    2016-12-01

    This paper presents the procedure and results of a temperature-based validation approach for the Moderate Resolution Imaging Spectroradiometer (MODIS) Land Surface Temperature (LST) product provided by the National Aeronautics and Space Administration (NASA) Terra and Aqua Earth Observing System satellites using in situ LST observations recorded at the Cooperative Remote Sensing Science and Technology Center - Snow Analysis and Field Experiment (CREST-SAFE) during the years of 2013 (January-April) and 2014 (February-April). A total of 314 day and night clear-sky thermal images, acquired by the Terra and Aqua satellites, were processed and compared to ground-truth data from CREST-SAFE with a frequency of one measurement every 3 min. Additionally, this investigation incorporated supplementary analyses using meteorological CREST-SAFE in situ variables (i.e. wind speed, cloud cover, incoming solar radiation) to study their effects on in situ snow surface temperature (T-skin) and T-air. Furthermore, a single pixel (1km2) and several spatially averaged pixels were used for satellite LST validation by increasing the MODIS window size to 5x5, 9x9, and 25x25 windows for comparison. Several trends in the MODIS LST data were observed, including the underestimation of daytime values and nighttime values. Results indicate that, although all the data sets (Terra and Aqua, diurnal and nocturnal) showed high correlation with ground measurements, day values yielded slightly higher accuracy ( 1°C), both suggesting that MODIS LST retrievals are reliable for similar land cover classes and atmospheric conditions. Results from the CREST-SAFE in situ variables' analyses indicate that T-air is commonly higher than T-skin, and that a lack of cloud cover results in: lower T-skin and higher T-air minus T-skin difference (T-diff). Additionally, the study revealed that T-diff is inversely proportional to cloud cover, wind speed, and incoming solar radiation. Increasing the MODIS window size

  15. Estimation of minimum surface temperature at stage ll (Short Communication

    Directory of Open Access Journals (Sweden)

    A. P. Dimri

    2001-04-01

    Full Text Available Forecasting minimum surface temperature at a station, Stage II, located in mountainous region requires information on the meteorological fields. An attempt has been made to develop a statistical model for forecasting minimum temperature at ground level using previous years' data. Surface data were collected at StageII (longitude 73 oB, latitude 34 oN, and altitude 2650 m. Atmospheric variables are influenced by complex orography and surface features to a great extent. In the present study, statistical relationship between atmosphere parameters and minimum temperature at the site has been established. Multivariate linear regression analysis has been used to establish the relationship to predict the minimum surface temperature for the following day. A comparison between the observed and the calculated forecast minimum temperature has been made. Most of the cases are well predicted (multiple correlation coefficient of 0.94.

  16. Toward Improved Land Surface Initialization in Support of Regional WRF Forecasts at the Kenya Meteorological Department

    Science.gov (United States)

    Case. Jonathan; Mungai, John; Sakwa, Vincent; Kabuchanga, Eric; Zavodsky, Bradley T.; Limaye, Ashutosh S.

    2014-01-01

    ) will be run at a comparable resolution to provide real-time, daily soil initialization data in place of interpolated Global Forecast System soil moisture and temperature data. Additionally, real-time green vegetation fraction data from the Visible Infrared Imaging Radiometer Suite will be incorporated into the KMD-WRF runs, once it becomes publicly available from the National Environmental Satellite Data and Information Service. Finally, model verification capabilities will be transitioned to KMD using the Model Evaluation Tools (MET) package, in order to quantify possible improvements in simulated temperature, moisture and precipitation resulting from the experimental land surface initialization. The transition of these MET tools will enable KMD to monitor model forecast accuracy in near real time. This presentation will highlight preliminary verification results of WRF runs over east Africa using the LIS land surface initialization.

  17. North American regional climate reconstruction from ground surface temperature histories

    Science.gov (United States)

    Jaume-Santero, Fernando; Pickler, Carolyne; Beltrami, Hugo; Mareschal, Jean-Claude

    2016-12-01

    Within the framework of the PAGES NAm2k project, 510 North American borehole temperature-depth profiles were analyzed to infer recent climate changes. To facilitate comparisons and to study the same time period, the profiles were truncated at 300 m. Ground surface temperature histories for the last 500 years were obtained for a model describing temperature changes at the surface for several climate-differentiated regions in North America. The evaluation of the model is done by inversion of temperature perturbations using singular value decomposition and its solutions are assessed using a Monte Carlo approach. The results within 95 % confidence interval suggest a warming between 1.0 and 2.5 K during the last two centuries. A regional analysis, composed of mean temperature changes over the last 500 years and geographical maps of ground surface temperatures, show that all regions experienced warming, but this warming is not spatially uniform and is more marked in northern regions.

  18. Ground-based measurement of surface temperature and thermal emissivity

    Science.gov (United States)

    Owe, M.; Van De Griend, A. A.

    1994-01-01

    Motorized cable systems for transporting infrared thermometers have been used successfully during several international field campaigns. Systems may be configured with as many as four thermal sensors up to 9 m above the surface, and traverse a 30 m transect. Ground and canopy temperatures are important for solving the surface energy balance. The spatial variability of surface temperature is often great, so that averaged point measurements result in highly inaccurate areal estimates. The cable systems are ideal for quantifying both temporal and spatial variabilities. Thermal emissivity is also necessary for deriving the absolute physical temperature, and measurements may be made with a portable measuring box.

  19. Effect of milling temperatures on surface area, surface energy and cohesion of pharmaceutical powders.

    Science.gov (United States)

    Shah, Umang V; Wang, Zihua; Olusanmi, Dolapo; Narang, Ajit S; Hussain, Munir A; Tobyn, Michael J; Heng, Jerry Y Y

    2015-11-10

    Particle bulk and surface properties are influenced by the powder processing routes. This study demonstrates the effect of milling temperatures on the particle surface properties, particularly surface energy and surface area, and ultimately on powder cohesion. An active pharmaceutical ingredient (API) of industrial relevance (brivanib alaninate, BA) was used to demonstrate the effect of two different, but most commonly used milling temperatures (cryogenic vs. ambient). The surface energy of powders milled at both cryogenic and room temperatures increased with increasing milling cycles. The increase in surface energy could be related to the generation of surface amorphous regions. Cohesion for both cryogenic and room temperature milled powders was measured and found to increase with increasing milling cycles. For cryogenic milling, BA had a surface area ∼ 5× higher than the one obtained at room temperature. This was due to the brittle nature of this compound at cryogenic temperature. By decoupling average contributions of surface area and surface energy on cohesion by salinization post-milling, the average contribution of surface energy on cohesion for powders milled at room temperature was 83% and 55% at cryogenic temperature.

  20. Improving the Accuracy of Satellite Sea Surface Temperature Measurements by Explicitly Accounting for the Bulk-Skin Temperature Difference

    Science.gov (United States)

    Castro, Sandra L.; Emery, William J.

    2002-01-01

    The focus of this research was to determine whether the accuracy of satellite measurements of sea surface temperature (SST) could be improved by explicitly accounting for the complex temperature gradients at the surface of the ocean associated with the cool skin and diurnal warm layers. To achieve this goal, work centered on the development and deployment of low-cost infrared radiometers to enable the direct validation of satellite measurements of skin temperature. During this one year grant, design and construction of an improved infrared radiometer was completed and testing was initiated. In addition, development of an improved parametric model for the bulk-skin temperature difference was completed using data from the previous version of the radiometer. This model will comprise a key component of an improved procedure for estimating the bulk SST from satellites. The results comprised a significant portion of the Ph.D. thesis completed by one graduate student and they are currently being converted into a journal publication.

  1. Air Temperature estimation from Land Surface temperature and solar Radiation parameters

    Science.gov (United States)

    Lazzarini, Michele; Eissa, Yehia; Marpu, Prashanth; Ghedira, Hosni

    2013-04-01

    Air Temperature (AirT) is a fundamental parameter in a wide range of applications such as climate change studies, weather forecast, energy balance modeling, efficiency of Photovoltaic (PV) solar cells, etc. Air temperature data are generally obtained through regular measurements from meteorological stations. The distribution of these stations is normally sparse, so the spatial pattern of this parameter cannot be accurately estimated by interpolation methods. This work investigated the relationship between Air Temperature measured at meteorological stations and spatially contiguous measurements derived from Remote Sensing techniques, such as Land Surface Temperature (LST) maps, emissivity maps and shortwave radiation maps with the aim of creating a continuous map of AirT. For LST and emissivity, MSG-SEVIRI LST product from Land Surface Analysis Satellite Applications Facility (LSA-SAF) has been used. For shortwave radiation maps, an Artificial Neural Networks ensemble model has been developed and previously tested to create continuous maps from Global Horizontal Irradiance (GHI) point measurements, utilizing six thermal channels of MSG-SEVIRI. The testing sites corresponded to three meteorological stations located in the United Arab Emirates (UAE), where in situ measurements of Air Temperature were available. From the starting parameters, energy fluxes and net radiation have been calculated, in order to have information on the incoming and outgoing long-wave radiation and the incoming short-wave radiation. The preliminary analysis (day and Night measurements, cloud free) showed a strong negative correlation (0.92) between Outgoing long-wave radiation - GHI and LST- AirT, with a RMSE of 1.84 K in the AirT estimation from the initial parameters. Regression coefficients have been determined and tested on all the ground stations. The analysis also demonstrated the predominant impact of the incoming short-wave radiation in the AirT hourly variation, while the incoming

  2. Effects of nano-surface properties on initial osteoblast adhesion and Ca/P adsorption ability for titanium alloys.

    Science.gov (United States)

    Wang, C C; Hsu, Y C; Hsieh, M C; Yang, S P; Su, F C; Lee, T M

    2008-08-20

    Titanium alloys (Ti6Al4V), while subjected to high temperature surface treatment, experience altered nano-surface characteristics. The effects of such surface treatments are examined, including the initial adhesion force experienced by osteoblasts, the Ca/P adsorption capability, and the nano-surface properties, including the amounts of amphoteric Ti-OH groups, surface topography, and surface roughness. The initial adhesion force is considered a quantitative indicator of cyto-compatibility in vitro. Previously, a cyto-detacher was applied in a pioneer attempt measuring the initial adhesion force of fibroblasts on a metal surface. Presently, the cyto-detacher is further applied to evaluate the initial adhesion force of osteoblasts. Results reveal that (1) titanium alloys subjected to heat treatment could promote the adsorption capability of Ca and P; (2) titanium alloys subjected to heat treatment could have higher initial osteoblast adhesion forces; (3) the adhesion strength of osteoblasts, ranging from 38.5 to 58.9 nN (nanonewtons), appears stronger for rougher surfaces. It is concluded that the heat treatment could have impacted the biocompatibility in terms of the initial osteoblast adhesion force and Ca/P adsorption capability.

  3. TEMPERATURE CONTROL CIRCUIT FOR SURFACE ACOUSTIC WAVE (SAW RESONATORS

    Directory of Open Access Journals (Sweden)

    Zainab Mohamad Ashari

    2011-10-01

    Full Text Available Surface Acoustic Wave (SAW resonators are key components in oscillators, frequency synthesizers and transceivers. One of the drawbacks of SAW resonators are that its piezoelectric substrates are highly sensitive to ambient temperature resulting in performance degradation. This work propose a simple circuit design which stabalizes the temperature of the SAW resonator, making it independet of temperature change. This circuit is based on the oven control method which elevates the temperature of the resonator to a high temperature, making it tolerant to minor changes in ambient temperature.This circuit consist of a temperature sensor, heaters and a comparator which turn the heater on or off depending on the ambient temperature. Several SAW resonator were tested using this circuit. Experimental results indicate the temperature coefficient of frequency (TCF decreases from maximum of 130.44/°C to a minimum of -1.11/°C. 

  4. An Open and Transparent Databank of Global Land Surface Temperature

    Science.gov (United States)

    Rennie, J.; Thorne, P.; Lawrimore, J. H.; Gleason, B.; Menne, M. J.; Williams, C.

    2013-12-01

    The International Surface Temperature Initiative (ISTI) consists of an effort to create an end-to-end process for land surface air temperature analyses. The foundation of this process is the establishment of a global land surface databank. The databank builds upon the groundbreaking efforts of scientists who led efforts to construct global land surface datasets in the 1980's and 1990's. A primary aim of the databank is to improve aspects including data provenance, version control, temporal and spatial coverage, and improved methods for bringing dozens of source data together into an integrated dataset. The databank consists of multiple stages, with each successive stage providing a higher level of processing, quality and integration. Currently more than 50 sources of data have been added to the databank. An automated algorithm has been developed that merges these sources into one complete dataset by removing duplicate station records, identifying two or more station records that can be merged into a single record, and incorporating new and unique stations. The program runs iteratively through all the sources which are ordered based upon criteria established by the ISTI. The highest preferred source, known as the target, runs through all the candidate sources, calculating station comparisons that are acceptable for merging. The process is probabilistic in approach, and the final fate of a candidate station is based upon metadata matching and data equivalence criteria. If there is not enough information, the station is withheld for further investigation. The algorithm has been validated using a pseudo-source of stations with a known time of observation bias, and correct matches have been made nearly 95% of the time. The final product, endorsed and recommended by ISTI, contains over 30,000 stations, however slight changes in the algorithm can perturb results. Subjective decisions, such as the ordering of the sources, or changing metadata and data matching thresholds

  5. Mapping the body surface temperature of cattle by infrared thermography.

    Science.gov (United States)

    Salles, Marcia Saladini Vieira; da Silva, Suelen Corrêa; Salles, Fernando André; Roma, Luiz Carlos; El Faro, Lenira; Bustos Mac Lean, Priscilla Ayleen; Lins de Oliveira, Celso Eduardo; Martello, Luciane Silva

    2016-12-01

    Infrared thermography (IRT) is an alternative non-invasive method that has been studied as a tool for identifying many physiological and pathological processes related to changes in body temperature. The objective of the present study was to evaluate the body surface temperature of Jersey dairy cattle in a thermoneutral environment in order to contribute to the determination of a body surface temperature pattern for animals of this breed in a situation of thermal comfort. Twenty-four Jersey heifers were used over a period of 35 days at APTA Brazil. Measurements were performed on all animals, starting with the physiological parameters. Body surface temperature was measured by IRT collecting images in different body regions: left and right eye area, right and left eye, caudal left foreleg, cranial left foreleg, right and left flank, and forehead. High correlations were observed between temperature and humidity index (THI) and right flank, left flank and forehead temperatures (0.85, 0.81, and 0.81, respectively). The IRT variables that exhibited the five highest correlation coefficients in principal component 1 were, in decreasing order: forehead (0.90), right flank (0.87), left flank (0.84), marker 1 caudal left foreleg (0.83), marker 2 caudal left foreleg (0.74). The THI showed a high correlation coefficient (0.88) and moderate to low correlations were observed for the physiological variables rectal temperature (0.43), and respiratory frequency (0.42). The thermal profile obtained indicates a surface temperature pattern for each region studied in a situation of thermal comfort and may contribute to studies investigating body surface temperature. Among the body regions studied, IRT forehead temperature showed the highest association with rectal temperature, and forehead and right and left flank temperatures are strongly associated with THI and may be adopted in future studies on thermoregulation and body heat production.

  6. eMODIS Global Land Surface Temperature Version 6

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The EROS Moderate Resolution Imaging Spectroradiometer (eMODIS) Aqua Land Surface Temperature (LST) product is similar to the Land Processes Distributed Active...

  7. 2002 Average Monthly Sea Surface Temperature for California

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The NOAA/ NASA AVHRR Oceans Pathfinder sea surface temperature data are derived from the 5-channel Advanced Very High Resolution Radiometers (AVHRR) on board the...

  8. 2003 Average Monthly Sea Surface Temperature for California

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The NOAA/ NASA AVHRR Oceans Pathfinder sea surface temperature data are derived from the 5-channel Advanced Very High Resolution Radiometers (AVHRR) on board the...

  9. Sea surface temperature anomalies in the Arabian Sea

    Digital Repository Service at National Institute of Oceanography (India)

    RameshKumar, M.R.

    . Further analysis has shown that the sea surface anomalies are well correlated to the anomalies of air temperature and latent heat flux values; whereas they are least correlated to the anomalies of wind stress and net radiation values, except over...

  10. An Estimation of Land Surface Temperatures from Landsat ETM+ ...

    African Journals Online (AJOL)

    Dr-Adeline

    2 National Authority for Remote Sensing and Space Sciences, Cairo, Egypt. 3University of ... Keywords: Urban growth, urban heat Island, land surface temperatures, satellite remote sensing .... observed target includes green vegetation or not.

  11. Global 1-km Sea Surface Temperature (G1SST)

    Data.gov (United States)

    National Aeronautics and Space Administration — JPL OurOcean Portal: A daily, global Sea Surface Temperature (SST) data set is produced at 1-km (also known as ultra-high resolution) by the JPL ROMS (Regional Ocean...

  12. COBE-SST2 Sea Surface Temperature and Ice

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A new sea surface temperature (SST) analysis on a centennial time scale is presented. The dataset starts in 1850 with monthly 1x1 means and is periodically updated....

  13. Surface layer temperature inversion in the Arabian Sea during winter

    Digital Repository Service at National Institute of Oceanography (India)

    Pankajakshan, T.; Ghosh, A.K.

    Surface layer temperature inversion in the south eastern Arabian Sea, during winter has been studied using Bathythermograph data collected from 1132 stations. It is found that the inversion in this area is a stable seasonal feature...

  14. Seasonal Sea Surface Temperature Averages, 1985-2001 - Direct Download

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of four images showing seasonal sea surface temperature (SST) averages for the entire earth. Data for the years 1985-2001 are averaged to...

  15. 1996 Average Monthly Sea Surface Temperature for California

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The NOAA/ NASA AVHRR Oceans Pathfinder sea surface temperature data are derived from the 5-channel Advanced Very High Resolution Radiometers (AVHRR) on board the...

  16. 2000 Average Monthly Sea Surface Temperature for California

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The NOAA/ NASA AVHRR Oceans Pathfinder sea surface temperature data are derived from the 5-channel Advanced Very High Resolution Radiometers (AVHRR) on board the...

  17. OW NOAA Pathfinder/GAC Sea-Surface Temperature

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The dataset contains satellite-derived sea-surface temperature measurements collected by means of the Advanced Very High Resolution Radiometer - Global Area Coverage...

  18. OW NOAA AVHRR-GAC Sea-Surface Temperature

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The dataset contains satellite-derived sea-surface temperature measurements collected by means of the Advanced Very High Resolution Radiometer - Global Area Coverage...

  19. NOAA High-Resolution Sea Surface Temperature (SST) Analysis Products

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This archive covers two high resolution sea surface temperature (SST) analysis products developed using an optimum interpolation (OI) technique. The analyses have a...

  20. Tropical sea surface temperatures and the earth's orbital eccentricity cycles

    Digital Repository Service at National Institute of Oceanography (India)

    Gupta, S.M.; Fernandes, A.A.; Mohan, R.

    The tropical oceanic warm pools are climatologically important regions because their sea surface temperatures (SSTs) are positively related to atmospheric greenhouse effect and the cumulonimbus-cirrus cloud anvil. Such a warm pool is also present...

  1. Temperature Distribution Measurement of The Wing Surface under Icing Conditions

    Science.gov (United States)

    Isokawa, Hiroshi; Miyazaki, Takeshi; Kimura, Shigeo; Sakaue, Hirotaka; Morita, Katsuaki; Japan Aerospace Exploration Agency Collaboration; Univ of Notre Dame Collaboration; Kanagawa Institute of Technology Collaboration; Univ of Electro-(UEC) Team, Comm

    2016-11-01

    De- or anti-icing system of an aircraft is necessary for a safe flight operation. Icing is a phenomenon which is caused by a collision of supercooled water frozen to an object. For the in-flight icing, it may cause a change in the wing cross section that causes stall, and in the worst case, the aircraft would fall. Therefore it is important to know the surface temperature of the wing for de- or anti-icing system. In aerospace field, temperature-sensitive paint (TSP) has been widely used for obtaining the surface temperature distribution on a testing article. The luminescent image from the TSP can be related to the temperature distribution. (TSP measurement system) In icing wind tunnel, we measured the surface temperature distribution of the wing model using the TSP measurement system. The effect of icing conditions on the TSP measurement system is discussed.

  2. Scanning tunneling microscopy of initial nitridation processes on oxidized Si(100) surface with radical nitrogen

    CERN Document Server

    Takahashi, R; Ikeda, H; Sakashita, M; Sakai, A; Yasuda, Y; Nakatsuka, O; Zaima, S

    2003-01-01

    We have investigated the initial nitridation processes on oxidized Si(100) with radical nitrogen at a substrate temperature of 850degC using scanning tunneling microscopy (STM) and scanning tunneling spectroscopy (STS). It is found that the thin oxide layer suppresses the changes of original Si step structures during nitridation, and this effect critically depends on the growth conditions of the oxide layer. Comparison of the nitride island morphology to the case of the clean surface suggests that the migration of the precursor during nitridation is suppressed by the oxygen in the layer. (author)

  3. High temperature photoelectron emission and surface photovoltage in semiconducting diamond

    Science.gov (United States)

    Williams, G. T.; Cooil, S. P.; Roberts, O. R.; Evans, S.; Langstaff, D. P.; Evans, D. A.

    2014-08-01

    A non-equilibrium photovoltage is generated in semiconducting diamond at above-ambient temperatures during x-ray and UV illumination that is sensitive to surface conductivity. The H-termination of a moderately doped p-type diamond (111) surface sustains a surface photovoltage up to 700 K, while the clean (2 × 1) reconstructed surface is not as severely affected. The flat-band C 1s binding energy is determined from 300 K measurement to be 283.87 eV. The true value for the H-terminated surface, determined from high temperature measurement, is (285.2 ± 0.1) eV, corresponding to a valence band maximum lying 1.6 eV below the Fermi level. This is similar to that of the reconstructed (2 × 1) surface, although this surface shows a wider spread of binding energy between 285.2 and 285.4 eV. Photovoltage quantification and correction are enabled by real-time photoelectron spectroscopy applied during annealing cycles between 300 K and 1200 K. A model is presented that accounts for the measured surface photovoltage in terms of a temperature-dependent resistance. A large, high-temperature photovoltage that is sensitive to surface conductivity and photon flux suggests a new way to use moderately B-doped diamond in voltage-based sensing devices.

  4. Temperature Compensation of Surface Acoustic Waves on Berlinite

    Science.gov (United States)

    Searle, David Michael Marshall

    The surface acoustic wave properties of Berlinite (a-AlPO4) have been investigated theoretically and experimentally, for a variety of crystallographic orientations, to evaluate its possible use as a substrate material for temperature compensated surface acoustic wave devices. A computer program has been developed to calculate the surface wave properties of a material from its elastic, piezoelectric, dielectric and lattice constants and their temperature derivatives. The program calculates the temperature coefficient of delay, the velocity of the surface wave, the direction of power flow and a measure of the electro-mechanical coupling. These calculations have been performed for a large number of orientations using a modified form of the data given by Chang and Barsch for Berlinite and predict several new temperature compensated directions. Experimental measurements have been made of the frequency-temperature response of a surface acoustic wave oscillator on an 80° X axis boule cut which show it to be temperature compensated in qualitative agreement with the theoretical predictions. This orientation shows a cubic frequency-temperature dependence instead of the expected parabolic response. Measurements of the electro-mechanical coupling coefficient k gave a value lower than predicted. Similar measurements on a Y cut plate gave a value which is approximately twice that of ST cut quartz, but again lower than predicted. The surface wave velocity on both these cuts was measured to be slightly higher than predicted by the computer program. Experimental measurements of the lattice parameters a and c are also presented for a range of temperatures from 25°C to just above the alpha-beta transition at 584°C. These results are compared with the values obtained by Chang and Barsch. The results of this work indicate that Berlinite should become a useful substrate material for the construction of temperature compensated surface acoustic wave devices.

  5. SURFACE TEMPERATURES ON TITAN DURING NORTHERN WINTER AND SPRING

    Energy Technology Data Exchange (ETDEWEB)

    Jennings, D. E.; Cottini, V.; Nixon, C. A.; Achterberg, R. K.; Flasar, F. M.; Kunde, V. G.; Romani, P. N.; Samuelson, R. E. [Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Mamoutkine, A. [ADNET Systems, Inc., Bethesda, MD 20817 (United States); Gorius, N. J. P. [The Catholic University of America, Washington, DC 20064 (United States); Coustenis, A. [Laboratoire d’Etudes Spatiales et d’Instrumentation en Astrophysique (LESIA), Observatoire de Paris, CNRS, UPMC Univ. Paris 06, Univ. Paris-Diderot, 5, place Jules Janssen, F-92195 Meudon Cedex (France); Tokano, T., E-mail: donald.e.jennings@nasa.gov [Universität zu Köln, Albertus-Magnus-Platz, D-50923 Köln (Germany)

    2016-01-01

    Meridional brightness temperatures were measured on the surface of Titan during the 2004–2014 portion of the Cassini mission by the Composite Infrared Spectrometer. Temperatures mapped from pole to pole during five two-year periods show a marked seasonal dependence. The surface temperature near the south pole over this time decreased by 2 K from 91.7 ± 0.3 to 89.7 ± 0.5 K while at the north pole the temperature increased by 1 K from 90.7 ± 0.5 to 91.5 ± 0.2 K. The latitude of maximum temperature moved from 19 S to 16 N, tracking the sub-solar latitude. As the latitude changed, the maximum temperature remained constant at 93.65 ± 0.15 K. In 2010 our temperatures repeated the north–south symmetry seen by Voyager one Titan year earlier in 1980. Early in the mission, temperatures at all latitudes had agreed with GCM predictions, but by 2014 temperatures in the north were lower than modeled by 1 K. The temperature rise in the north may be delayed by cooling of sea surfaces and moist ground brought on by seasonal methane precipitation and evaporation.

  6. Temperature dependence of surface enhanced Raman scattering on C70

    Institute of Scientific and Technical Information of China (English)

    GAO Ying; Zhang Zhenlong; DU Yinxiao; DONG Hua; MO Yujun

    2005-01-01

    The temperature dependence of surface enhanced Raman scattering of the C70 molecule is reported.The Raman scattering of C70 molecules adsorbed on the surface of a silver mirror was measured at different temperatures. The experimental results indicate that the relative intensities of the Raman features vary with the temperature of the sample. When the temperature decreases from room temperature to 0℃, the relative intensities of certain Raman bands decrease abruptly. If we take the strongest band 1565cm-1 as a standard value 100, the greatest decrease approaches to 43%. However, with the further decrease in the temperature these relative intensities increase and resume the value at room temperature. And such a temperature dependence is reversible. Our results show that the adsorption state of the C70 molecules on the silver surface around 0℃changes greatly with the temperature, resulting in a decrease in relative intensities for some main Raman features of C70molecule. When the temperature is lower than 0℃, the adsorption state changes continually and more slowly. Synchronously, eight new Raman featu res, which have not ever been reported in literature, are observed in our experiment and this enriches the basic information of the vibrational modes for C70 molecule.

  7. Sea Surface Temperature from EUMETSAT Including Sentinel-3 SLSTR

    Science.gov (United States)

    O'Carroll, Anne; Bonekamp, Hans; Montagner, Francois; Santacesaria, Vincenzo; Tomazic, Igor

    2015-12-01

    The paper gives an overview of sea surface temperature (SST) activities at EUMETSAT including information on SST planned from the Sea and Land Surface Temperature Radiometer (SLSTR). Operational oceanography activities within the Marine Applications group at EUMETSAT continue with a focus on SST, sea surface winds, sea-ice products, radiative fluxes, significant wave height and sea surface topography. These are achieved through the mandatory, optional and third-party programmes, and for some products with the EUMETSAT Ocean and Sea-Ice Satellite Application Facility (OSI SAF). Progress towards products from sea-ice surface temperature, ocean colour products, turbidity and aerosol optical depth over water continue. Information on oceanography products from EUMETSAT can be found through the product navigator (http://navigator.eumetsat.int). EUMETSAT have been collaborating with ESA for a number of years on the development of SST for SLSTR.

  8. Strain rate and temperature effects on crack initiation of direct aged 718 Alloy

    Directory of Open Access Journals (Sweden)

    Perrais Maxime

    2014-01-01

    Full Text Available During mechanical tests at high temperature in an oxidizing atmosphere, the effects of strain rate on crack initiation are noticeable. This effect is due to a coupling between local mechanical loading and oxidation. Samples were machined in a turbine disk made of direct aged alloy 718. Tests were performed to understand the effect of these couplings on crack initiation and to ensure lifetime is optimized. This study compared the cracking resistance of two different specimen geometries at a given plastic strain and performed quantitative measurement of the mechanical loading conditions inducing crack initiation between 600 ∘C and 650 ∘C. Sample geometries consisted in tensile flat specimens and V-shaped samples. This specific geometry was used to localize strain and damage in the apex of the V and to reach strain rates lower than those possible on standard specimens. Digital image correlation technique was used to provide strain measurements. For each temperature and strain rate, finite element calculations using the identified constitutive law were performed to get a refined level of strain in different areas at the V apex. Tests were stopped after an imposed displacement corresponding to a given plastic strain distribution. SEM observations of the surface of the flat tensile samples revealed no crack initiation. On the contrary, SEM observations at the apex of V specimens for which the level of cumulative strain was close to the level of cumulative strain of flat samples reveal the presence of intergranular damage when the strain rate used was below a given level.

  9. Burning rate characteristics of energetic CMDB propellants (III). Effect of initial propellant temperature; Ko energy CMDB suishinyaku no nensho sokudo tokusei (III). Suishinyaku shoki ondo no koka

    Energy Technology Data Exchange (ETDEWEB)

    Aoki, I. [Nissan Motor Co. Ltd., Tokyo (Japan)

    1998-01-01

    In case of double-base properants, the temperature sensitivity of burning rate for this type of propellants having higher energy becomes smaller than that of propellants having lower energy. When the energy contained in propellants increases, or initial propellant temperatures increase, the burning surface temperature of propellant increases, therefore, the reaction in fizz zone is accelerated, the dark zone temperature increases, and the temperature gradient in fizz zone increases. This increase of temperature gradient increases the burning rate of propellant. In case of HMX-CMDB propellants, when the energy contained in propellants increases, or initial propellant temperatures decrease, the burning surface temperature of propellant decreases, therefore, the reaction in fizz zone is decelerated, the dark zone temperature decreases, and the temperature gradient in fizz zone decreases. This decrease of temperature gradient decreases the burning rate of propellant. As a result, it was clarified that the temperatures as common physical properties which had an effect of initial propellant temperatures on the burning rates were the burning surface temperature and the dark zone temperature. 22 refs., 12 figs., 2 tabs.

  10. A model of the ground surface temperature for micrometeorological analysis

    Science.gov (United States)

    Leaf, Julian S.; Erell, Evyatar

    2017-07-01

    Micrometeorological models at various scales require ground surface temperature, which may not always be measured in sufficient spatial or temporal detail. There is thus a need for a model that can calculate the surface temperature using only widely available weather data, thermal properties of the ground, and surface properties. The vegetated/permeable surface energy balance (VP-SEB) model introduced here requires no a priori knowledge of soil temperature or moisture at any depth. It combines a two-layer characterization of the soil column following the heat conservation law with a sinusoidal function to estimate deep soil temperature, and a simplified procedure for calculating moisture content. A physically based solution is used for each of the energy balance components allowing VP-SEB to be highly portable. VP-SEB was tested using field data measuring bare loess desert soil in dry weather and following rain events. Modeled hourly surface temperature correlated well with the measured data (r 2 = 0.95 for a whole year), with a root-mean-square error of 2.77 K. The model was used to generate input for a pedestrian thermal comfort study using the Index of Thermal Stress (ITS). The simulation shows that the thermal stress on a pedestrian standing in the sun on a fully paved surface, which may be over 500 W on a warm summer day, may be as much as 100 W lower on a grass surface exposed to the same meteorological conditions.

  11. Determination of temperature of moving surface by sensitivity analysis

    CERN Document Server

    Farhanieh, B

    2002-01-01

    In this paper sensitivity analysis in inverse problem solutions is employed to estimate the temperature of a moving surface. Moving finite element method is used for spatial discretization. Time derivatives are approximated using Crank-Nicklson method. The accuracy of the solution is assessed by simulation method. The convergence domain is investigated for the determination of the temperature of a solid fuel.

  12. A new interpolation method for Antarctic surface temperature

    Institute of Scientific and Technical Information of China (English)

    Yetang Wang; Shugui Hou

    2009-01-01

    We propose a new methodology for the spatial interpolation of annual mean temperature into a regular grid with a geographic resolution of 0.01° for Antarctica by applying a recent compilation of the Antarctic temperature data.A multiple linear regression model of the dependence of temperature on some geographic parameters (i.e.,latitude,longitude,and elevation) is proposed empirically,and the kriging method is used to determine the spatial distribution of regional and local deviations from the temperature calculated from the multiple linear regression model.The modeled value and residual grids are combined to derive a high-resolution map of surface air temperature.The performance of our new methodology is superior to a variety of benchmark methods (e.g.,inverse distance weighting,kriging,and spline methods) via cross-validation techniques.Our simulation resembles well with those distinct spatial features of surface temperature,such as the decrease in annual mean surface temperature with increasing latitude and the distance away from the coast line;and it also reveals the complex topographic effects on the spatial distribution of surface temperature.

  13. Sputter deposited bioceramic coatings: surface characterisation and initial protein adsorption studies using surface-MALDI-MS.

    Science.gov (United States)

    Boyd, A R; Burke, G A; Duffy, H; Holmberg, M; O' Kane, C; Meenan, B J; Kingshott, P

    2011-01-01

    Protein adsorption onto calcium phosphate (Ca-P) bioceramics utilised in hard tissue implant applications has been highlighted as one of the key events that influences the subsequent biological response, in vivo. This work reports on the use of surface-matrix assisted laser desorption ionisation mass spectrometry (Surface-MALDI-MS) as a technique for the direct detection of foetal bovine serum (FBS) proteins adsorbed to hybrid calcium phosphate/titanium dioxide surfaces produced by a novel radio frequency (RF) magnetron sputtering method incorporating in situ annealing between 500°C and 700°C during deposition. XRD and XPS analysis indicated that the coatings produced at 700°C were hybrid in nature, with the presence of Ca-P and titanium dioxide clearly observed in the outer surface layer. In addition to this, the Ca/P ratio was seen to increase with increasing annealing temperature, with values of between 2.0 and 2.26 obtained for the 700°C samples. After exposure to FBS solution, surface-MALDI-MS indicated that there were significant differences in the protein patterns as shown by unique peaks detected at masses below 23.1 kDa for the different surfaces. These adsorbates were assigned to a combination of growth factors and lipoproteins present in serum. From the data obtained here it is evident that surface-MALDI-MS has significant utility as a tool for studying the dynamic nature of protein adsorption onto the surfaces of bioceramic coatings, which most likely plays a significant role in subsequent bioactivity of the materials.

  14. Analysis of Anomaly in Land Surface Temperature Using MODIS Products

    Science.gov (United States)

    Yorozu, K.; Kodama, T.; Kim, S.; Tachikawa, Y.; Shiiba, M.

    2011-12-01

    Atmosphere-land surface interaction plays a dominant role on the hydrologic cycle. Atmospheric phenomena cause variation of land surface state and land surface state can affect on atmosphereic conditions. Widely-known article related in atmospheric-land interaction was published by Koster et al. in 2004. The context of this article is that seasonal anomaly in soil moisture or soil surface temperature can affect summer precipitation generation and other atmospheric processes especially in middle North America, Sahel and south Asia. From not only above example but other previous research works, it is assumed that anomaly of surface state has a key factor. To investigate atmospheric-land surface interaction, it is necessary to analyze anomaly field in land surface state. In this study, soil surface temperature should be focused because it can be globally and continuously observed by satellite launched sensor. To land surface temperature product, MOD11C1 and MYD11C1 products which are kinds of MODIS products are applied. Both of them have 0.05 degree spatial resolution and daily temporal resolution. The difference of them is launched satellite, MOD11C1 is Terra and MYD11C1 is Aqua. MOD11C1 covers the latter of 2000 to present and MYD11C1 covers the early 2002 to present. There are unrealistic values on provided products even if daily product was already calibrated or corrected. For pre-analyzing, daily data is aggregated into 8-days data to remove irregular values for stable analysis. It was found that there are spatial and temporal distribution of 10-years average and standard deviation for each 8-days term. In order to point out extreme anomaly in land surface temperature, standard score for each 8-days term is applied. From the analysis of standard score, it is found there are large anomaly in land surface temperature around north China plain in early April 2005 and around Bangladesh in early May 2009.

  15. Radar Backscatter Across the Gulf Stream Sea Surface Temperature Front

    Science.gov (United States)

    Nghiem, S. V.; Li, F. K.; Walsh, E. J.; Lou, S. H.

    1998-01-01

    Ocean backscatter signatures were measured by the Jet Propulsion Laboratory airborne NUSCAT K(sub u)-band scatterometer across the Gulf Stream sea surface temperature front. The measurements were made during the Surface Wave Dynamics Experiment (SWADE) off the coast of Virginia and Maryland in the winter of 1991.

  16. estimation of land surface temperature of kaduna metropolis, nigeria

    African Journals Online (AJOL)

    Zaharaddeen et. al

    Understanding the spatial variation of Land Surface Temperature. (LST), will be ... positive correlation between mean of surface emissivity with date and ... deviation of 1.92 of LST and coefficient determinant R2 (0.46) show a ... (LST), as the prime and basic physical parameter of the earth's ..... thorough review of the paper.

  17. WRF Simulation over the Eastern Africa by use of Land Surface Initialization

    Science.gov (United States)

    Sakwa, V. N.; Case, J.; Limaye, A. S.; Zavodsky, B.; Kabuchanga, E. S.; Mungai, J.

    2014-12-01

    The East Africa region experiences severe weather events associated with hazards of varying magnitude. It receives heavy precipitation which leads to wide spread flooding and lack of sufficient rainfall in some parts results into drought. Cases of flooding and drought are two key forecasting challenges for the Kenya Meteorological Service (KMS). The source of heat and moisture depends on the state of the land surface which interacts with the boundary layer of the atmosphere to produce excessive precipitation or lack of it that leads to severe drought. The development and evolution of precipitation systems are affected by heat and moisture fluxes from the land surface within weakly-sheared environments, such as in the tropics and sub-tropics. These heat and moisture fluxes during the day can be strongly influenced by land cover, vegetation, and soil moisture content. Therefore, it is important to represent the land surface state as accurately as possible in numerical weather prediction models. Improved modeling capabilities within the region have the potential to enhance forecast guidance in support of daily operations and high-impact weather over East Africa. KMS currently runs a configuration of the Weather Research and Forecasting (WRF) model in real time to support its daily forecasting operations, invoking the Non-hydrostatic Mesoscale Model (NMM) dynamical core. They make use of the National Oceanic and Atmospheric Administration / National Weather Service Science and Training Resource Center's Environmental Modeling System (EMS) to manage and produce the WRF-NMM model runs on a 7-km regional grid over Eastern Africa.SPoRT and SERVIR provide land surface initialization datasets and model verification tool. The NASA Land Information System (LIS) provide real-time, daily soil initialization data in place of interpolated Global Forecast System soil moisture and temperature data. Model verification is done using the Model Evaluation Tools (MET) package, in order

  18. ESTIMATION OF PV MODULE SURFACE TEMPERATURE USING ARTIFICIAL NEURAL NETWORKS

    Directory of Open Access Journals (Sweden)

    Can Coskun

    2016-12-01

    Full Text Available This study aimed to use the artificial neural network (ANN method to estimate the surface temperature of a photovoltaic (PV panel. Using the experimentally obtained PV data, the accuracy of the ANN model was evaluated. To train the artificial neural network (ANN, outer temperature solar radiation and wind speed values were inputs and surface temperature was an output. The ANN was used to estimate PV panel surface temperature. Using the Levenberg-Marquardt (LM algorithm the feed forward artificial neural network was trained. Two back propagation type ANN algorithms were used and their performance was compared with the estimate from the LM algorithm. To train the artificial neural network, experimental data were used for two thirds with the remaining third used for testing. Additionally scaled conjugate gradient (SCG back propagation and resilient back propagation (RB type ANN algorithms were used for comparison with the LM algorithm. The performances of these three types of artificial neural network were compared and mean error rates of between 0.005962 and 0.012177% were obtained. The best estimate was produced by the LM algorithm. Estimation of PV surface temperature with artificial neural networks provides better results than conventional correlation methods. This study showed that artificial neural networks may be effectively used to estimate PV surface temperature.

  19. Mathematical model of the metal mould surface temperature optimization

    Energy Technology Data Exchange (ETDEWEB)

    Mlynek, Jaroslav, E-mail: jaroslav.mlynek@tul.cz; Knobloch, Roman, E-mail: roman.knobloch@tul.cz [Department of Mathematics, FP Technical University of Liberec, Studentska 2, 461 17 Liberec, The Czech Republic (Czech Republic); Srb, Radek, E-mail: radek.srb@tul.cz [Institute of Mechatronics and Computer Engineering Technical University of Liberec, Studentska 2, 461 17 Liberec, The Czech Republic (Czech Republic)

    2015-11-30

    The article is focused on the problem of generating a uniform temperature field on the inner surface of shell metal moulds. Such moulds are used e.g. in the automotive industry for artificial leather production. To produce artificial leather with uniform surface structure and colour shade the temperature on the inner surface of the mould has to be as homogeneous as possible. The heating of the mould is realized by infrared heaters located above the outer mould surface. The conceived mathematical model allows us to optimize the locations of infrared heaters over the mould, so that approximately uniform heat radiation intensity is generated. A version of differential evolution algorithm programmed in Matlab development environment was created by the authors for the optimization process. For temperate calculations software system ANSYS was used. A practical example of optimization of heaters locations and calculation of the temperature of the mould is included at the end of the article.

  20. Quality control methods for KOOS operational sea surface temperature products

    Institute of Scientific and Technical Information of China (English)

    YANG Chansu; KIM Sunhwa

    2016-01-01

    Sea surface temperature SST obtained from the initial version of the Korea Operational Oceanographic System (KOOS) SST satellite have low accuracy during summer and daytime. This is attributed to the diurnal warming effect. Error estimation of SST data must be carried out to use the real-time forecasting numerical model of the KOOS. This study suggests two quality control methods for the KOOS SST system. To minimize the diurnal warming effect, SSTs of areas where wind speed is higher than 5 m/s were used. Depending on the wind threshold value, KOOS SST data for August 2014 were reduced by 0.15°C. Errors in SST data are considered to be a combination of random, sampling, and bias errors. To estimate bias error, the standard deviation of bias between KOOS SSTs and climatology SSTs were used. KOOS SST data yielded an analysis error standard deviation value similar to OSTIA and NOAA NCDC (OISST) data. The KOOS SST shows lower random and sampling errors with increasing number of observations using six satellite datasets. In further studies, the proposed quality control methods for the KOOS SST system will be applied through more long-term case studies and comparisons with other SST systems.

  1. Influence of Annealing Temperature on CZTS Thin Film Surface Properties

    Science.gov (United States)

    Feng, Wenmei; Han, Junfeng; Ge, Jun; Peng, Xianglin; Liu, Yunong; Jian, Yu; Yuan, Lin; Xiong, Xiaolu; Cha, Limei; Liao, Cheng

    2017-01-01

    In this work, copper zinc tin sulfide (CZTS) films were deposited by direct current sputtering and the samples were annealed in different oven-set temperatures and atmosphere (Ar and H2S). The surface evolution was investigated carefully by using scanning electron microscopy (SEM), Raman spectroscopy and x-ray photoelectron spectroscopy. The surface of the as-sputtered precursor contained little Cu and large amounts of Zn and Sn. The metallic precursor was continuous and compact without pinholes or cracks. With the increase of the temperature from room temperature to 250°C, Cu atoms diffused to the film surface to form Cu1- x S and covered other compounds. Some small platelets were smaller than 500 nm spreading randomly in the holes of the film surfaces. When the temperature reached 350°C, Zn and Sn atoms began to diffuse to the surface and react with S or Cu1- x S. At 400°C, SEM showed the melting of large particles and small particles with a size from 100 nm to 200 nm in the background of the film surface. Excess Zn segregated towards the surface regions and formed ZnS phase on the surface. In addition, the signal of sodium in the CZTS surface was observed above 400°C. At 600°C, a large amount of regular structures with clear edges and corners were observed in the film surface in SEM images. A clear recrystallized process on the surface was assumed from those observations.

  2. Climate Change Signal Analysis for Northeast Asian Surface Temperature

    Institute of Scientific and Technical Information of China (English)

    Jeong-Hyeong LEE; Byungsoo KIM; Keon-Tae SOHN; Won-Tae KOWN; Seung-Ki MIN

    2005-01-01

    Climate change detection, attribution, and prediction were studied for the surface temperature in the Northeast Asian region using NCEP/NCAR reanalysis data and three coupled-model simulations from ECHAM4/OPYC3, HadCM3, and CCCma GCMs (Canadian Centre for Climate Modeling and Analysis general circulation model). The Bayesian fingerprint approach was used to perform the detection and attribution test for the anthropogenic climate change signal associated with changes in anthropogenic carbon dioxide (CO2) and sulfate aerosol (SO42-) concentrations for the Northeast Asian temperature. It was shown that there was a weak anthropogenic climate change signal in the Northeast Asian temperature change. The relative contribution of CO2 and SOl- effects to total temperature change in Northeast Asia was quantified from ECHAM4/OPYC3 and CCCma GCM simulations using analysis of variance. For the observed temperature change for the period of 1959-1998, the CO2 effect contributed 10%-21% of the total variance and the direct cooling effect of SO42- played a less important role (0% 7%) than the CO2effect. The prediction of surface temperature change was estimated from the second CO2+SO24- scenario run of ECHAM4/OPYC3 which has the least error in the simulation of the present-day temperature field near the Korean Peninsula. The result shows that the area-mean surface temperature near the Korean Peninsula will increase by about 1.1° by the 2040s relative to the 1990s.

  3. Effect of biomass on temperatures of sintering and initial deformation of lignite ash

    Energy Technology Data Exchange (ETDEWEB)

    H. Haykiri-Acma; S. Yama; S. Kucukbayrak [Istanbul Technical University, Istanbul (Turkey). Faculty of Chemical and Metallurgical Engineering

    2010-10-15

    Sintering temperatures and the initial deformation temperatures of ashes from Turkish Elbistan lignite, and biomass species such as hazelnut shell and rice husk were investigated up to 1450{sup o}C by Heating Microscope Technique. Sintering temperatures were found 1300, 1269, and 1320{sup o}C for hazelnut shell, rice husk, and lignite, respectively, while the initial deformation temperatures were >1450, 1370, and >1450{sup o}C. Lignite/biomass blends were prepared by adding of biomass into coal in the ratios of 5 or 10 wt.%, and then effects of biomass presence on sintering temperature and the initial deformation temperature were tested. It was determined that the addition of potassium-rich hazelnut shell reduced the sintering temperatures to 919 and 730{sup o}C for the blends of 5 and 10 wt.%, respectively. Also, initial deformation temperature dropped to 788{sup o}C in case of the blend of 10 wt.%. Such a big antagonistic influence of hazelnut shell on the thermal behaviour of ash is attributed to the interaction of potassium from biomass with silicon compounds found in mineral matter of lignite. In addition, concentration of CaO may be another reason for this. On the other hand, the presence of rice husk showed limited effect on the sintering temperature as well the initial deformation temperature. 20 refs., 3 figs., 5 tabs.

  4. Comment on evidence for surface-initiated homogenous nucleation

    Directory of Open Access Journals (Sweden)

    J. E. Kay

    2003-01-01

    Full Text Available We investigate theoretical, laboratory, and atmospheric evidence for a recently proposed hypothesis: homogenous ice nucleation occurs at the surface, not in the volume, of supercooled water drops. Using existing thermodynamic arguments, laboratory experiments, and atmospheric data, we conclude that ice embryo formation at the surface cannot be confirmed or disregarded. Ice nucleation rates measured as a function of drop size in an air ambient could help distinguish between volume and surface nucleation rates.

  5. Comparison of MODIS Land Surface Temperature and Air Temperature over the Continental USA Meteorological Stations

    Science.gov (United States)

    Zhang, Ping; Bounoua, Lahouari; Imhoff, Marc L.; Wolfe, Robert E.; Thome, Kurtis

    2014-01-01

    The National Land Cover Database (NLCD) Impervious Surface Area (ISA) and MODIS Land Surface Temperature (LST) are used in a spatial analysis to assess the surface-temperature-based urban heat island's (UHIS) signature on LST amplitude over the continental USA and to make comparisons to local air temperatures. Air-temperature-based UHIs (UHIA), calculated using the Global Historical Climatology Network (GHCN) daily air temperatures, are compared with UHIS for urban areas in different biomes during different seasons. NLCD ISA is used to define urban and rural temperatures and to stratify the sampling for LST and air temperatures. We find that the MODIS LST agrees well with observed air temperature during the nighttime, but tends to overestimate it during the daytime, especially during summer and in nonforested areas. The minimum air temperature analyses show that UHIs in forests have an average UHIA of 1 C during the summer. The UHIS, calculated from nighttime LST, has similar magnitude of 1-2 C. By contrast, the LSTs show a midday summer UHIS of 3-4 C for cities in forests, whereas the average summer UHIA calculated from maximum air temperature is close to 0 C. In addition, the LSTs and air temperatures difference between 2006 and 2011 are in agreement, albeit with different magnitude.

  6. Fiber-Optic Surface Temperature Sensor Based on Modal Interference

    Directory of Open Access Journals (Sweden)

    Frédéric Musin

    2016-07-01

    Full Text Available Spatially-integrated surface temperature sensing is highly useful when it comes to controlling processes, detecting hazardous conditions or monitoring the health and safety of equipment and people. Fiber-optic sensing based on modal interference has shown great sensitivity to temperature variation, by means of cost-effective image-processing of few-mode interference patterns. New developments in the field of sensor configuration, as described in this paper, include an innovative cooling and heating phase discrimination functionality and more precise measurements, based entirely on the image processing of interference patterns. The proposed technique was applied to the measurement of the integrated surface temperature of a hollow cylinder and compared with a conventional measurement system, consisting of an infrared camera and precision temperature probe. As a result, the optical technique is in line with the reference system. Compared with conventional surface temperature probes, the optical technique has the following advantages: low heat capacity temperature measurement errors, easier spatial deployment, and replacement of multiple angle infrared camera shooting and the continuous monitoring of surfaces that are not visually accessible.

  7. The effects of artificial surface temperature on mechanical properties and player kinematics during landing and acceleration

    Institute of Scientific and Technical Information of China (English)

    Laura Charalambous a; Wolfgang Potthast c; Gareth Irwin b

    2016-01-01

    Background: Artificial turf is considered a feasible global alternative to natural turf by many sports governing bodies. Consequently, its ability to provide a safe and consistent playing surface regardless of climate becomes essential. The aims of this study were to determine the effects of artificial surface temperature on:(1) mechanical properties of the turf and (2) the kinematics of a turf-sport related movement. Methods: Two identical artificial turf pitches were tested:one with a cold surface temperature (1.8°C–2.4°C) and one with a warm surface temperature (14.5°C–15.2°C). Mechanical testing was performed to measure the surface properties. Four amateur soccer players performed a hurdle jump to sprint acceleration movement, with data (contact time, step length and hip, knee and ankle kinematics) collected using CODASport (200 Hz). Results: The temperature difference had a significant influence on the mechanical properties of the artificial turf, including force absorption, energy restitution, rotational resistance, and the height where the head injury criterion was met. Both step length (p=0.008) and contact time (p=0.002) of the initial step after the landing were significantly longer on the warm surface. In addition, significant range of motion and joint angular velocity differences were found. Conclusion: These findings highlight different demands placed on players due to the surface temperature and suggest a need for coaches, practitioners, and sports governing bodies to be aware of these differences.

  8. Assessment of broiler surface temperature variation when exposed to different air temperatures

    Directory of Open Access Journals (Sweden)

    GR Nascimento

    2011-12-01

    Full Text Available This study was conducted to determine the effect of the air temperature variation on the mean surface temperature (MST of 7- to 35-day-old broiler chickens using infrared thermometry to estimate MST, and to study surface temperature variation of the wings, head, legs, back and comb as affected by air temperature and broiler age. One hundred Cobb® broilers were used in the experiment. Starting on day 7, 10 birds were weekly selected at random, housed in an environmental chamber and reared under three distinct temperatures (18, 25 and 32 ºC to record their thermal profile using an infrared thermal camera. The recorded images were processed to estimate MST by selecting the whole area of the bird within the picture and comparing it with the values obtained using selected equations in literature, and to record the surface temperatures of the body parts. The MST estimated by infrared images were not statistically different (p > 0.05 from the values obtained by the equations. MST values significantly increased (p < 0.05 when the air temperature increased, but were not affected by bird age. However, age influenced the difference between MST and air temperature, which was highest on day 14. The technique of infrared thermal image analysis was useful to estimate the mean surface temperature of broiler chickens.

  9. Surface-initiated Atom Transfer Radical Polymerization - a Technique to Develop Biofunctional Coatings

    DEFF Research Database (Denmark)

    Fristrup, Charlotte Juel; Jankova Atanasova, Katja; Hvilsted, Søren

    2009-01-01

    The initial formation of initiating sites for atom transfer radical polymerization (ATRP) on various polymer surfaces and numerous inorganic and metallic surfaces is elaborated. The subsequent ATRP grafting of a multitude of monomers from such surfaces to generate thin covalently linked polymer...

  10. Investigating the effect of surface water - groundwater interactions on stream temperature using Distributed temperature sensing and instream temperature model

    DEFF Research Database (Denmark)

    Karthikeyan, Matheswaran; Blemmer, Morten; Mortensen, Julie Flor;

    2011-01-01

    Surface water–groundwater interactions at the stream interface influences, and at times controls the stream temperature, a critical water property driving biogeochemical processes. This study investigates the effects of these interactions on temperature of Stream Elverdamsåen in Denmark using...... the Distributed Temperature Sensing (DTS) system and instream temperature modelling. Locations of surface water–groundwater interactions were identified from the temperature data collected over a 2-km stream reach using a DTS system with 1-m spatial and 5-min temporal resolution. The stream under consideration...... exhibits three distinct thermal regimes within a 2 km reach length due to two major interactions. An energy balance model is used to simulate the instream temperature and to quantify the effect of these interactions on the stream temperature. This research demonstrates the effect of reach level small scale...

  11. The impact of temperature changing on surface roughness of FFF process

    Science.gov (United States)

    Chaidas, D.; Kitsakis, K.; Kechagias, J.; Maropoulos, S.

    2016-11-01

    The current study investigates the surface roughness of models produced by a 3D printer. All models were produced by addition of solid material, a process called fused filament fabrication (FFF): initial extrusion into plastic filament, second extrusion and trace-binding during the 3D printing process. A low cost 3D printer Ultimaker was used to print these items. Polylactic acid (PLA) was used as main polymer material for printing. The temperature was parameter under direct variations in order to examine if there was an influence on roughness of 3d printed models. The surface roughness parameters were: the average mean surface roughness (Ra, μm), the surface roughness depth (Rz, μm), the total height of the roughness profile (Rt, μm) and the arithmetic mean width of profile elements (Rsm, μm). The examination showed conditionality: as temperature was increased the surface roughness parameters were further decreased.

  12. Uncertainties and shortcomings of ground surface temperature histories derived from inversion of temperature logs

    OpenAIRE

    Hartmann, Andreas; Rath, Volker

    2008-01-01

    Analysing borehole temperature data in terms of ground surface history can add useful information to reconstructions of past climates. Therefore, a rigorous assessment of uncertainties and error sources is a necessary prerequisite for the meaningful interpretation of such ground surface temperature histories. This study analyses the most prominent sources of uncertainty. The diffusive nature of the process makes the inversion relatively robust against incomplete knowledge of the thermal diffu...

  13. High-Temperature Surface-Acoustic-Wave Transducer

    Science.gov (United States)

    Zhao, Xiaoliang; Tittmann, Bernhard R.

    2010-01-01

    Aircraft-engine rotating equipment usually operates at high temperature and stress. Non-invasive inspection of microcracks in those components poses a challenge for the non-destructive evaluation community. A low-profile ultrasonic guided wave sensor can detect cracks in situ. The key feature of the sensor is that it should withstand high temperatures and excite strong surface wave energy to inspect surface/subsurface cracks. As far as the innovators know at the time of this reporting, there is no existing sensor that is mounted to the rotor disks for crack inspection; the most often used technology includes fluorescent penetrant inspection or eddy-current probes for disassembled part inspection. An efficient, high-temperature, low-profile surface acoustic wave transducer design has been identified and tested for nondestructive evaluation of structures or materials. The development is a Sol-Gel bismuth titanate-based surface-acoustic-wave (SAW) sensor that can generate efficient surface acoustic waves for crack inspection. The produced sensor is very thin (submillimeter), and can generate surface waves up to 540 C. Finite element analysis of the SAW transducer design was performed to predict the sensor behavior, and experimental studies confirmed the results. One major uniqueness of the Sol-Gel bismuth titanate SAW sensor is that it is easy to implement to structures of various shapes. With a spray coating process, the sensor can be applied to surfaces of large curvatures. Second, the sensor is very thin (as a coating) and has very minimal effect on airflow or rotating equipment imbalance. Third, it can withstand temperatures up to 530 C, which is very useful for engine applications where high temperature is an issue.

  14. Investigation of surface properties of high temperature nitrided titanium alloys

    Directory of Open Access Journals (Sweden)

    E. Koyuncu

    2009-12-01

    Full Text Available Purpose: The purpose of paper is to investigate surface properties of high temperature nitrided titanium alloys.Design/methodology/approach: In this study, surface modification of Ti6Al4V titanium alloy was made at various temperatures by plasma nitriding process. Plasma nitriding treatment was performed in 80% N2-20% H2 gas mixture, for treatment times of 2-15 h at the temperatures of 700-1000°C. Surface properties of plasma nitrided Ti6Al4V alloy were examined by metallographic inspection, X-Ray diffraction and Vickers hardness.Findings: Two layers were determined by optic inspection on the samples that were called the compound and diffusion layers. Compound layer contain TiN and Ti2N nitrides, XRD results support in this formations. Maximum hardness was obtained at 10h treatment time and 1000°C treatment temperature. Micro hardness tests showed that hardness properties of the nitrided samples depend on treatment time and temperature.Practical implications: Titanium and its alloys have very attractive properties for many industries. But using of titanium and its alloys is of very low in mechanical engineering applications because of poor tribological properties.Originality/value: The nitriding of titanium alloy surfaces using plasma processes has already reached the industrial application stage in the biomedical field.

  15. Surface Intermediates on Metal Electrodes at High Temperature

    DEFF Research Database (Denmark)

    Zachau-Christiansen, Birgit; Jacobsen, Torben; Bay, Lasse

    1997-01-01

    The mechanisms widely suggested for the O2-reduc-tion or H2-oxidation SOFC reactions involve inter-mediate O/H species adsorbed on the electrode surface. The presence of these intermediates is investigated by linear sweep voltammetry. In airat moderate temperatures (500øC) Pt in contact with YSZ ...... is covered with adsorbed oxygen which vanishes at high temperature (1000øC). On Ni (YSZ) a specific layer of NiO is observed abovethe equilibrium potential while no surface species can identified at SOFC anode conditions....

  16. Determination of sea surface temperatures from microwave and IR data

    Science.gov (United States)

    Rangaswamy, S.; Grover, J.

    1982-01-01

    Microwave measurements from the Nimbus 7 SMMR were used to derive the atmospheric precipitable water, which was then used to obtain the atmospheric correction for use with AVHRR thermal IR measurements to obtain sea surface temperature (SST). The resulting SST's were compared with the NOAA operational sea surface temperature measurements, and the two sets of measurements were found to be in reasonable agreement. The average residuals between the two sets of measurements was 0.15 K with the NOAA operational SST's being slightly greater.

  17. Surface intermediates on metal electrodes at high temperatures

    DEFF Research Database (Denmark)

    Zachau-Christiansen, Birgit; Jacobsen, Torben; Bay, Lasse;

    1998-01-01

    in contact with YSZ is covered with adsorbed oxygen which vanishes at high temperature (1000 degrees C). On Ni (YSZ) a specific layer of NiO is observed above the equilibrium potential while no surface species involving hydrogen can be identified at SOFC anode conditions. (C) 1998 Published by Elsevier......The mechanisms widely conceived for the O(2)-reduction or H(2)-oxidation reactions in SOFC's involve intermediate O/H species adsorbed on the electrode surface. The presence of these intermediates is investigated by linear sweep voltammetry. In air at moderate temperatures (500 degrees C) Pt...

  18. Surface air temperature variability in global climate models

    CERN Document Server

    Davy, Richard

    2012-01-01

    New results from the Coupled Model Inter-comparison Project phase 5 (CMIP5) and multiple global reanalysis datasets are used to investigate the relationship between the mean and standard deviation in the surface air temperature. A combination of a land-sea mask and orographic filter were used to investigate the geographic region with the strongest correlation and in all cases this was found to be for low-lying over-land locations. This result is consistent with the expectation that differences in the effective heat capacity of the atmosphere are an important factor in determining the surface air temperature response to forcing.

  19. Observing the Agulhas Current with sea surface temperature and altimetry data: challenges and perspectives

    CSIR Research Space (South Africa)

    Krug, Marjolaine, J

    2014-06-01

    Full Text Available -Red Sea Surface Temperature datasets still suffer from inadequate cloud masking algorithms, particularly in regions of strong temperature gradient. Despite both Sea Surface Height and Sea Surface Temperature observations being severely compromised...

  20. Initial temperature of the strongly interacting Quark Gluon Plasma created at RHIC

    CERN Document Server

    Csanad, Mate

    2011-01-01

    A 1+3 dimensional solution of relativistic hydrodynamics is analyzed in this paper. Momentum distribution and other observables are calculated from the solution and compared to hadronic measurements from the Relativistic Heavy Ion Collider (RHIC). The solution is compatible with the data, but only the freeze-out point of the evolution is determined. Many equation of states and initial states (initial temperatures) are valid with the same freeze-out distribution, thus the same hadronic observables. The observable that would distinguish between these initial temperatures is momentum distribution of photons, as photons are created throughout the evolution of the fireball created in RHIC collisions. The PHENIX experiment at RHIC measures such data via low invariant mass e+e- pairs. Average temperature from this data is T=221+-23+-18 MeV, while a model calculation with initial temperature 370 MeV agree with the data.

  1. The Land Surface Temperature Impact to Land Cover Types

    Science.gov (United States)

    Ibrahim, I.; Abu Samah, A.; Fauzi, R.; Noor, N. M.

    2016-06-01

    Land cover type is an important signature that is usually used to understand the interaction between the ground surfaces with the local temperature. Various land cover types such as high density built up areas, vegetation, bare land and water bodies are areas where heat signature are measured using remote sensing image. The aim of this study is to analyse the impact of land surface temperature on land cover types. The objectives are 1) to analyse the mean temperature for each land cover types and 2) to analyse the relationship of temperature variation within land cover types: built up area, green area, forest, water bodies and bare land. The method used in this research was supervised classification for land cover map and mono window algorithm for land surface temperature (LST) extraction. The statistical analysis of post hoc Tukey test was used on an image captured on five available images. A pixel-based change detection was applied to the temperature and land cover images. The result of post hoc Tukey test for the images showed that these land cover types: built up-green, built up-forest, built up-water bodies have caused significant difference in the temperature variation. However, built up-bare land did not show significant impact at p<0.05. These findings show that green areas appears to have a lower temperature difference, which is between 2° to 3° Celsius compared to urban areas. The findings also show that the average temperature and the built up percentage has a moderate correlation with R2 = 0.53. The environmental implications of these interactions can provide some insights for future land use planning in the region.

  2. Daytime sensible heat flux estimation over heterogeneous surfaces using multitemporal land-surface temperature observations

    Science.gov (United States)

    Castellví, F.; Cammalleri, C.; Ciraolo, G.; Maltese, A.; Rossi, F.

    2016-05-01

    Equations based on surface renewal (SR) analysis to estimate the sensible heat flux (H) require as input the mean ramp amplitude and period observed in the ramp-like pattern of the air temperature measured at high frequency. A SR-based method to estimate sensible heat flux (HSR-LST) requiring only low-frequency measurements of the air temperature, horizontal mean wind speed, and land-surface temperature as input was derived and tested under unstable conditions over a heterogeneous canopy (olive grove). HSR-LST assumes that the mean ramp amplitude can be inferred from the difference between land-surface temperature and mean air temperature through a linear relationship and that the ramp frequency is related to a wind shear scale characteristic of the canopy flow. The land-surface temperature was retrieved by integrating in situ sensing measures of thermal infrared energy emitted by the surface. The performance of HSR-LST was analyzed against flux tower measurements collected at two heights (close to and well above the canopy top). Crucial parameters involved in HSR-LST, which define the above mentioned linear relationship, were explained using the canopy height and the land surface temperature observed at sunrise and sunset. Although the olive grove can behave as either an isothermal or anisothermal surface, HSR-LST performed close to H measured using the eddy covariance and the Bowen ratio energy balance methods. Root mean square differences between HSR-LST and measured H were of about 55 W m-2. Thus, by using multitemporal thermal acquisitions, HSR-LST appears to bypass inconsistency between land surface temperature and the mean aerodynamic temperature. The one-source bulk transfer formulation for estimating H performed reliable after calibration against the eddy covariance method. After calibration, the latter performed similar to the proposed SR-LST method.

  3. New indexing and surface temperature analysis of exoplanets

    CERN Document Server

    Kashyap, J M; Safonova, M

    2016-01-01

    Study of exoplanets is the holy grail of present research in planetary sciences and astrobiology. Analysis of huge planetary data from space missions such as CoRoT and Kepler is directed ultimately at finding a planet similar to Earth\\-the Earth's twin, and answering the question of potential exo-habitability. The Earth Similarity Index (ESI) is a first step in this quest, ranging from 1 (Earth) to 0 (totally dissimilar to Earth). It was defined for the four physical parameters of a planet: radius, density, escape velocity and surface temperature. The ESI is further sub-divided into interior ESI (geometrical mean of radius and density) and surface ESI (geometrical mean of escape velocity and surface temperature). The challenge here is to determine which exoplanet parameter(s) is important in finding this similarity; how exactly the individual parameters entering the interior ESI and surface ESI are contributing to the global ESI. Since the surface temperature entering surface ESI is a non-observable quantity,...

  4. The Sensitivity of African Easterly Waves to Eastern Tropical Atlantic Sea-Surface Temperatures

    Science.gov (United States)

    Druyan, Leonard M.; Fulakeza, Matthew

    2011-01-01

    The results of two regional atmospheric model simulations are compared to assess the influence of the eastern tropical Atlantic sea-surface temperature maximum on local precipitation, transient easterly waves and the West African summer monsoon. Both model simulations were initialized with reanalysis 2 data (US National Center for Environmental Prediction and Department of Energy) on 15 May 2006 and extended through 6 October 2006, forced by synchronous reanalysis 2 lateral boundary conditions introduced four times daily. One simulation uses 2006 reanalysis 2 sea-surface temperatures, also updated four times daily, while the second simulation considers ocean forcing absent the sea-surface temperature maximum, achieved here by subtracting 3 K at every ocean grid point between 0 and 15 N during the entire simulation. The simulation with 2006 sea-surface temperature forcing produces a realistic distribution of June-September mean precipitation and realistic westward propagating swaths of maximum rainfall, based on validation against Tropical Rainfall Measuring Mission (TRMM) estimates. The simulation without the sea-surface temperature maximum produces only 57% of the control June-September total precipitation over the eastern tropical Atlantic and about 83% of the Sahel precipitation. The simulation with warmer ocean temperatures generates generally stronger circulation, which in turn enhances precipitation by increasing moisture convergence. Some local precipitation enhancement is also attributed to lower vertical thermal stability above the warm water. The study shows that the eastern tropical Atlantic sea-surface temperature maximum enhances the strength of transient easterly waves and broadens the spatial extent of associated precipitation. However, large-scale circulation and its interaction with the African continent, and not sea-surface temperatures, control the timing and trajectories of the waves.

  5. INVESTIGATION OF SURFACE TEMPERATURE IN HIGH-EFFICIENCY DEEP GRINDING

    Institute of Scientific and Technical Information of China (English)

    Zhao Henghua; Cai Guangqi; Jin Tan

    2005-01-01

    A new thermal model with triangular heat flux distribution is given in high-efficiency deep grinding. The mathematical expressions are driven to calculate the surface temperature. The transient behavior of the maximum temperature on contact area is investigated in different grinding conditions with a J-type thermocouple. The maximum contact temperatures measured in different conditions are found to be between 1 000 ℃ and 1 500 ℃ in burn-out conditions. The experiment results show good agreement with the new thermal model.

  6. Transitioning Enhanced Land Surface Initialization and Model Verification Capabilities to the Kenya Meteorological Department (KMD)

    Science.gov (United States)

    Case, Jonathan L.; Mungai, John; Sakwa, Vincent; Zavodsky, Bradley T.; Srikishen, Jayanthi; Limaye, Ashutosh; Blankenship, Clay B.

    2016-01-01

    Flooding, severe weather, and drought are key forecasting challenges for the Kenya Meteorological Department (KMD), based in Nairobi, Kenya. Atmospheric processes leading to convection, excessive precipitation and/or prolonged drought can be strongly influenced by land cover, vegetation, and soil moisture content, especially during anomalous conditions and dry/wet seasonal transitions. It is thus important to represent accurately land surface state variables (green vegetation fraction, soil moisture, and soil temperature) in Numerical Weather Prediction (NWP) models. The NASA SERVIR and the Short-term Prediction Research and Transition (SPoRT) programs in Huntsville, AL have established a working partnership with KMD to enhance its regional modeling capabilities. SPoRT and SERVIR are providing experimental land surface initialization datasets and model verification capabilities for capacity building at KMD. To support its forecasting operations, KMD is running experimental configurations of the Weather Research and Forecasting (WRF; Skamarock et al. 2008) model on a 12-km/4-km nested regional domain over eastern Africa, incorporating the land surface datasets provided by NASA SPoRT and SERVIR. SPoRT, SERVIR, and KMD participated in two training sessions in March 2014 and June 2015 to foster the collaboration and use of unique land surface datasets and model verification capabilities. Enhanced regional modeling capabilities have the potential to improve guidance in support of daily operations and high-impact weather and climate outlooks over Eastern Africa. For enhanced land-surface initialization, the NASA Land Information System (LIS) is run over Eastern Africa at 3-km resolution, providing real-time land surface initialization data in place of interpolated global model soil moisture and temperature data available at coarser resolutions. Additionally, real-time green vegetation fraction (GVF) composites from the Suomi-NPP VIIRS instrument is being incorporated

  7. Initial surface deformations during impact on a liquid pool

    NARCIS (Netherlands)

    Bouwhuis, W.; Hendrix, M.H.W.; van der Meer, Roger M.; Snoeijer, Jacobus Hendrikus

    2015-01-01

    A tiny air bubble can be entrapped at the bottom of a solid sphere that impacts onto a liquid pool. The bubble forms due to the deformation of the liquid surface by a local pressure buildup inside the surrounding gas, as also observed during the impact of a liquid drop on a solid wall. Here, we

  8. The Remote Sensing of Surface Radiative Temperature over Barbados.

    Science.gov (United States)

    remote sensing of surface radiative temperature over Barbados was undertaken using a PRT-5 attached to a light aircraft. Traverses across the centre of the island, over the rugged east coast area, and the urban area of Bridgetown were undertaken at different times of day and night in the last week of June and the first week of December, 1969. These traverses show that surface variations in long-wave radiation emission lie within plus or minus 5% of the observations over grass at a representative site. The quick response of the surface to sunset and sunrise was

  9. A comparison of all-weather land surface temperature products

    Science.gov (United States)

    Martins, Joao; Trigo, Isabel F.; Ghilain, Nicolas; Goettche, Frank-M.; Ermida, Sofia; Olesen, Folke-S.; Gellens-Meulenberghs, Françoise; Arboleda, Alirio

    2017-04-01

    The Satellite Application Facility on Land Surface Analysis (LSA-SAF, http://landsaf.ipma.pt) has been providing land surface temperature (LST) estimates using SEVIRI/MSG on an operational basis since 2006. The LSA-SAF service has since been extended to provide a wide range of satellite-based quantities over land surfaces, such as emissivity, albedo, radiative fluxes, vegetation state, evapotranspiration, and fire-related variables. Being based on infra-red measurements, the SEVIRI/MSG LST product is limited to clear-sky pixels only. Several all-weather LST products have been proposed by the scientific community either based on microwave observations or using Soil-Vegetation-Atmosphere Transfer models to fill the gaps caused by clouds. The goal of this work is to provide a nearly gap-free operational all-weather LST product and compare these approaches. In order to estimate evapotranspiration and turbulent energy fluxes, the LSA-SAF solves the surface energy budget for each SEVIRI pixel, taking into account the physical and physiological processes occurring in vegetation canopies. This task is accomplished with an adapted SVAT model, which adopts some formulations and parameters of the Tiled ECMWF Scheme for Surface Exchanges over Land (TESSEL) model operated at the European Center for Medium-range Weather Forecasts (ECMWF), and using: 1) radiative inputs also derived by LSA-SAF, which includes surface albedo, down-welling fluxes and fire radiative power; 2) a land-surface characterization obtained by combining the ECOCLIMAP database with both LSA-SAF vegetation products and the H(ydrology)-SAF snow mask; 3) meteorological fields from ECMWF forecasts interpolated to SEVIRI pixels, and 4) soil moisture derived by the H-SAF and LST from LSA-SAF. A byproduct of the SVAT model is surface skin temperature, which is needed to close the surface energy balance. The model skin temperature corresponds to the radiative temperature of the interface between soil and atmosphere

  10. Enzyme surface rigidity tunes the temperature dependence of catalytic rates.

    Science.gov (United States)

    Isaksen, Geir Villy; Åqvist, Johan; Brandsdal, Bjørn Olav

    2016-07-12

    The structural origin of enzyme adaptation to low temperature, allowing efficient catalysis of chemical reactions even near the freezing point of water, remains a fundamental puzzle in biocatalysis. A remarkable universal fingerprint shared by all cold-active enzymes is a reduction of the activation enthalpy accompanied by a more negative entropy, which alleviates the exponential decrease in chemical reaction rates caused by lowering of the temperature. Herein, we explore the role of protein surface mobility in determining this enthalpy-entropy balance. The effects of modifying surface rigidity in cold- and warm-active trypsins are demonstrated here by calculation of high-precision Arrhenius plots and thermodynamic activation parameters for the peptide hydrolysis reaction, using extensive computer simulations. The protein surface flexibility is systematically varied by applying positional restraints, causing the remarkable effect of turning the cold-active trypsin into a variant with mesophilic characteristics without changing the amino acid sequence. Furthermore, we show that just restraining a key surface loop causes the same effect as a point mutation in that loop between the cold- and warm-active trypsin. Importantly, changes in the activation enthalpy-entropy balance of up to 10 kcal/mol are almost perfectly balanced at room temperature, whereas they yield significantly higher rates at low temperatures for the cold-adapted enzyme.

  11. Temperature limit values for touching cold surfaces with the fingertip

    NARCIS (Netherlands)

    Geng, Q.; Holme, I.; Hartog, E.A. den; Havenith, G.; Jay, O.; Malchaires, J.; Piette, A.; Rintama, H.; Rissanen, S.

    2006-01-01

    Objectives: At the request of the European Commission and in the framework of the European Machinery Directive, research was performed in five different laboratories to develop specifications for surface temperature limit values for the short-term accidental touching of the fingertip with cold

  12. Temperature limit values for touching cold surfaces with the fingertip

    NARCIS (Netherlands)

    Geng, Q.; Holme, I.; Hartog, E.A. den; Havenith, G.; Jay, O.; Malchaires, J.; Piette, A.; Rintama, H.; Rissanen, S.

    2006-01-01

    Objectives: At the request of the European Commission and in the framework of the European Machinery Directive, research was performed in five different laboratories to develop specifications for surface temperature limit values for the short-term accidental touching of the fingertip with cold surfa

  13. Climate Prediction Center (CPC) Global Land Surface Air Temperature Analysis

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A station observation-based global land monthly mean surface air temperature dataset at 0.5 x 0.5 latitude-longitude resolution for the period from 1948 to the...

  14. Quantifying and specifying the solar influence on terrestrial surface temperature

    NARCIS (Netherlands)

    de Jager, C.; Duhau, S.; van Geel, B.

    2010-01-01

    This investigation is a follow-up of a paper in which we showed that both major magnetic components of the solar dynamo, viz. the toroidal and the poloidal ones, are correlated with average terrestrial surface temperatures. Here, we quantify, improve and specify that result and search for their caus

  15. A physically based model of global freshwater surface temperature

    NARCIS (Netherlands)

    Beek, van L.P.H.; Eikelboom, T.; Vliet, van M.T.H.; Bierkens, M.F.P.

    2012-01-01

    Temperature determines a range of physical properties of water and exerts a strong control on surface water biogeochemistry. Thus, in freshwater ecosystems the thermal regime directly affects the geographical distribution of aquatic species through their growth and metabolism and indirectly through

  16. Climate Prediction Center (CPC) Global Land Surface Air Temperature Analysis

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A station observation-based global land monthly mean surface air temperature dataset at 0.5 0.5 latitude-longitude resolution for the period from 1948 to the present...

  17. Processes of India's offshore summer intraseasonal sea surface temperature variability

    Digital Repository Service at National Institute of Oceanography (India)

    Kurian, N.; Lengaigne, M.; Gopalakrishna, V.V.; Vialard, J.; Pous, S.; Peter, A-C.; Durand; Naik, Shweta

    ., vol.63; 2013; 329-346 Processes of India’s offshore summer intraseasonal sea surface temperature variability K. Nisha1, M. Lengaigne1,2, V.V. Gopalakrishna,1 J. Vialard2, S. Pous2, A.-C. Peter2, F. Durand3, S.Naik1 1. NIO, CSIR, Goa, India 2...

  18. A physically based model of global freshwater surface temperature

    NARCIS (Netherlands)

    Beek, van L.P.H.; Eikelboom, T.; Vliet, van M.T.H.; Bierkens, M.F.P.

    2012-01-01

    Temperature determines a range of physical properties of water and exerts a strong control on surface water biogeochemistry. Thus, in freshwater ecosystems the thermal regime directly affects the geographical distribution of aquatic species through their growth and metabolism and indirectly through

  19. Surface temperature maps for II Peg during 1999-2002

    CERN Document Server

    Lindborg, M; Tuominen, I; Hackman, T; Ilyin, I; Piskunov, N

    2009-01-01

    The active RS CVn star II Peg has been spectroscopically monitored for almost 18 years with the SOFIN spectrograph at NOT, La Palma, Spain. In this paper we present five new surface temperature maps of the object for the years 1999 (two maps), 2001 (one map) and 2002 (two maps).

  20. A Microring Temperature Sensor Based on the Surface Plasmon Wave

    Directory of Open Access Journals (Sweden)

    Wenchao Li

    2015-01-01

    Full Text Available A structure of microring sensor suitable for temperature measurement based on the surface plasmon wave is put forward in this paper. The sensor uses surface plasmon multilayer waveguiding structure in the vertical direction and U-shaped microring structure in the horizontal direction and utilizes SOI as the thermal material. The transfer function derivation of the structure of surface plasmon microring sensor is according to the transfer matrix method. While the change of refractive index of Si is caused by the change of ambient temperature, the effective refractive index of the multilayer waveguiding structure is changed, resulting in the drifting of the sensor output spectrum. This paper focuses on the transmission characteristics of multilayer waveguide structure and the impact on the output spectrum caused by refractive index changes in temperature parts. According to the calculation and simulation, the transmission performance of the structure is stable and the sensitivity is good. The resonance wavelength shift can reach 0.007 μm when the temperature is increased by 100 k and FSR can reach about 60 nm. This structure achieves a high sensitivity in the temperature sense taking into account a wide range of filter frequency selections, providing a theoretical basis for the preparation of microoptics.

  1. Reduction of the Livestock Ammonia Emission under the Changing Temperature during the Initial Manure Nitrogen Biomineralization

    Directory of Open Access Journals (Sweden)

    Rolandas Bleizgys

    2013-01-01

    Full Text Available Experimental data were applied for the modelling optimal cowshed temperature environment in laboratory test bench by a mass-flow method. The principal factor affecting exponent growth of ammonia emission was increasing air and manure surface temperature. With the manure temperature increasing from 4°C to 30°C, growth in the ammonia emission grew fourfold, that is, from 102 to 430 mg m−2h−1. Especial risk emerges when temperature exceeds 20°C: an increase in temperature of 1°C contributes to the intensity of ammonia emission by 17 mg m−2h−1. The temperatures of air and manure surface as well as those of its layers are important when analysing emission processes from manure. Indeed, it affects the processes occurring on the manure surface, namely, dehydration and crust formation. To reduce ammonia emission from cowshed, it is important to optimize the inner temperature control and to manage air circulation, especially at higher temperatures, preventing the warm ambient air from blowing direct to manure. Decrease in mean annual temperature of 1°C would reduce the annual ammonia emission by some 5.0%. The air temperature range varied between −15°C and 30°C in barns. The highest mean annual temperature (14.6°C and ammonia emission (218 mg m−2h−1 were observed in the semideep cowshed.

  2. Modeling the surface temperature of Earth-like planets

    CERN Document Server

    Vladilo, G; Murante, G; Filippi, L; Provenzale, A

    2015-01-01

    We introduce a novel Earth-like planet surface temperature model (ESTM) for habitability studies based on the spatial-temporal distribution of planetary surface temperatures. The ESTM adopts a surface Energy Balance Model complemented by: radiative-convective atmospheric column calculations, a set of physically-based parameterizations of meridional transport, and descriptions of surface and cloud properties more refined than in standard EBMs. The parameterization is valid for rotating terrestrial planets with shallow atmospheres and moderate values of axis obliquity (epsilon >= 45^o). Comparison with a 3D model of atmospheric dynamics from the literature shows that the equator-to-pole temperature differences predicted by the two models agree within ~5K when the rotation rate, insolation, surface pressure and planet radius are varied in the intervals 0.5 <= Omega/Omega_o <= 2, 0.75 <= S/S_o <= 1.25, 0.3 <= p/(1 bar) <= 10, and 0.5 <= R/R_o <= 2, respectively. The ESTM has an extremely l...

  3. Modeling Apple Surface Temperature Dynamics Based on Weather Data

    Directory of Open Access Journals (Sweden)

    Lei Li

    2014-10-01

    Full Text Available The exposure of fruit surfaces to direct sunlight during the summer months can result in sunburn damage. Losses due to sunburn damage are a major economic problem when marketing fresh apples. The objective of this study was to develop and validate a model for simulating fruit surface temperature (FST dynamics based on energy balance and measured weather data. A series of weather data (air temperature, humidity, solar radiation, and wind speed was recorded for seven hours between 11:00–18:00 for two months at fifteen minute intervals. To validate the model, the FSTs of “Fuji” apples were monitored using an infrared camera in a natural orchard environment. The FST dynamics were measured using a series of thermal images. For the apples that were completely exposed to the sun, the RMSE of the model for estimating FST was less than 2.0 °C. A sensitivity analysis of the emissivity of the apple surface and the conductance of the fruit surface to water vapour showed that accurate estimations of the apple surface emissivity were important for the model. The validation results showed that the model was capable of accurately describing the thermal performances of apples under different solar radiation intensities. Thus, this model could be used to more accurately estimate the FST relative to estimates that only consider the air temperature. In addition, this model provides useful information for sunburn protection management.

  4. A model of the tropical Pacific sea surface temperature climatology

    Science.gov (United States)

    Seager, Richard; Zebiak, Stephen E.; Cane, Mark A.

    1988-01-01

    A model for the climatological mean sea surface temperature (SST) of the tropical Pacific Ocean is developed. The upper ocean response is computed using a time dependent, linear, reduced gravity model, with the addition of a constant depth frictional surface layer. The full three-dimensional temperature equation and a surface heat flux parameterization that requires specification of only wind speed and total cloud cover are used to evaluate the SST. Specification of atmospheric parameters, such as air temperature and humidity, over which the ocean has direct influence, is avoided. The model simulates the major features of the observed tropical Pacific SST. The seasonal evolution of these features is generally captured by the model. Analysis of the results demonstrates the control the ocean has over the surface heat flux from ocean to atmosphere and the crucial role that dynamics play in determining the mean SST in the equatorial Pacific. The sensitivity of the model to perturbations in the surface heat flux, cloud cover specification, diffusivity, and mixed layer depth is discussed.

  5. Temperature maps measurements on 3D surfaces with infrared thermography

    Energy Technology Data Exchange (ETDEWEB)

    Cardone, Gennaro; Ianiro, Andrea [University of Naples Federico II, Department of Aerospace Engineering (DIAS), Naples (Italy); Ioio, Gennaro dello [University of Cambridge, BP Institute for Multiphase Flow, Cambridge, England (United Kingdom); Passaro, Andrea [Alta SpA, Ospedaletto, PI (Italy)

    2012-02-15

    The use of the infrared camera as a temperature transducer in wind tunnel applications is convenient and widespread. Nevertheless, the infrared data are available in the form of 2D images while the observed surfaces are often not planar and the reconstruction of temperature maps over them is a critical task. In this work, after recalling the principles of IR thermography, a methodology to rebuild temperature maps on the surfaces of 3D object is proposed. In particular, an optical calibration is applied to the IR camera by means of a novel target plate with control points. The proposed procedure takes also into account the directional emissivity by estimating the viewing angle. All the needed steps are described and analyzed. The advantages given by the proposed method are shown with an experiment in a hypersonic wind tunnel. (orig.)

  6. Importance of initial buoyancy field on evolution of mantle thermal structure: Implications of surface boundary conditions

    Directory of Open Access Journals (Sweden)

    Petar Glišović

    2015-01-01

    Full Text Available Although there has been significant progress in the seismic imaging of mantle heterogeneity, the outstanding issue that remains to be resolved is the unknown distribution of mantle temperature anomalies in the distant geological past that give rise to the present-day anomalies inferred by global tomography models. To address this question, we present 3-D convection models in compressible and self-gravitating mantle initialised by different hypothetical temperature patterns. A notable feature of our forward convection modelling is the use of self-consistent coupling of the motion of surface tectonic plates to the underlying mantle flow, without imposing prescribed surface velocities (i.e., plate-like boundary condition. As an approximation for the surface mechanical conditions before plate tectonics began to operate we employ the no-slip (rigid boundary condition. A rigid boundary condition demonstrates that the initial thermally-dominated structure is preserved, and its geographical location is fixed during the evolution of mantle flow. Considering the impact of different assumed surface boundary conditions (rigid and plate-like on the evolution of thermal heterogeneity in the mantle we suggest that the intrinsic buoyancy of seven superplumes is most-likely resolved in the tomographic images of present-day mantle thermal structure. Our convection simulations with a plate-like boundary condition reveal that the evolution of an initial cold anomaly beneath the Java-Indonesian trench system yields a long-term, stable pattern of thermal heterogeneity in the lowermost mantle that resembles the present-day Large Low Shear Velocity Provinces (LLSVPs, especially below the Pacific. The evolution of subduction zones may be, however, influenced by the mantle-wide flow driven by deeply-rooted and long-lived superplumes since Archean times. These convection models also detect the intrinsic buoyancy of the Perm Anomaly that has been identified as a unique

  7. Initial stages of benzotriazole adsorption on the Cu(111) surface.

    Science.gov (United States)

    Grillo, Federico; Tee, Daniel W; Francis, Stephen M; Früchtl, Herbert; Richardson, Neville V

    2013-06-21

    Benzotriazole (BTAH) has been used as a copper corrosion inhibitor since the 1950s; however, the molecular level detail of how inhibition occurs remains a matter of debate. The onset of BTAH adsorption on a Cu(111) single crystal was investigated via scanning tunnelling microscopy (STM), vibrational spectroscopy (RAIRS) and supporting DFT modelling. BTAH adsorbs as anionic (BTA(-)), CuBTA is a minority species, while Cu(BTA)2, the majority of the adsorbed species, form chains, whose sections appear to diffuse in a concerted manner. The copper surface appears to reconstruct in a (2 × 1) fashion.

  8. Hydrophilization of poly(ether ether ketone) films by surface-initiated atom transfer radical polymerization

    DEFF Research Database (Denmark)

    Fristrup, Charlotte Juel; Jankova Atanasova, Katja; Hvilsted, Søren

    2010-01-01

    Surface-Initiated Atom Transfer Radical Polymerization (SI-ATRP) has been exploited to hydrophilize PEEK. The ketone groups on the PEEK surface were reduced to hydroxyl groups which were converted to bromoisobutyrate initiating sites for SI-ATRP. The modification steps were followed by contact...

  9. Thermosensitive Nanocables Prepared by Surface-Initiated Atom Transfer Radical Polymerization

    Directory of Open Access Journals (Sweden)

    Wei Qingshan

    2008-01-01

    Full Text Available Abstract Thermosensitive nanocables consisting of Au nanowire cores and poly(N-isopropylacrylamide sheaths (denoted as Au/PNIPAAm were synthesized by surface-initiated atom transfer radical polymerization (SI-ATRP. The formation of PNIPAAm sheath was verified by Fourier transform infrared (FTIR and hydrogen nuclear magnetic resonance (1H NMR spectroscopy. Transmission electron microscope (TEM results confirmed the core/shell structure of nanohybrids. The thickness and density of PNIPAAm sheaths can be adjusted by controlling the amount of cross-linker during the polymerization. Signature temperature response was observed from Au/cross-linked-PNIPAAm nanocables. Such smart nanocables show immense potentials as building blocks for novel thermosensitive nanodevices in future.

  10. Designing high-temperature steels via surface science and thermodynamics

    Science.gov (United States)

    Gross, Cameron T.; Jiang, Zilin; Mathai, Allan; Chung, Yip-Wah

    2016-06-01

    Electricity in many countries such as the US and China is produced by burning fossil fuels in steam-turbine-driven power plants. The efficiency of these power plants can be improved by increasing the operating temperature of the steam generator. In this work, we adopted a combined surface science and computational thermodynamics approach to the design of high-temperature, corrosion-resistant steels for this application. The result is a low-carbon ferritic steel with nanosized transition metal monocarbide precipitates that are thermally stable, as verified by atom probe tomography. High-temperature Vickers hardness measurements demonstrated that these steels maintain their strength for extended periods at 700 °C. We hypothesize that the improved strength of these steels is derived from the semi-coherent interfaces of these thermally stable, nanosized precipitates exerting drag forces on impinging dislocations, thus maintaining strength at elevated temperatures.

  11. Surface layer temperature inversion in the Bay of Bengal

    Science.gov (United States)

    Thadathil, Pankajakshan; Gopalakrishna, V. V.; Muraleedharan, P. M.; Reddy, G. V.; Araligidad, Nilesh; Shenoy, Shrikant

    2002-10-01

    Surface layer temperature inversion occurring in the Bay of Bengal has been addressed. Hydrographic data archived in the Indian Oceanographic Data Center are used to understand various aspects of the temperature inversion of surface layer in the Bay of Bengal, such as occurrence time, characteristics, stability, inter-annual variability and generating mechanisms. Spatially organized temperature inversion occurs in the coastal waters of the western and northeastern Bay during winter (November-February). Although the inversion in the northeastern Bay is sustained until February (with remnants seen even in March), in the western Bay it becomes less organized in January and almost disappears by February. Inversion is confined to the fresh water induced seasonal halocline of the surface layer. Inversions of large temperature difference (of the order of 1.6-2.4°C) and thin layer thickness (10-20 m) are located adjacent to major fresh water inputs from the Ganges, Brahmaputra, Irrawaddy, Krishna and Godavari rivers. The inversion is stable with a mean stability of 3600×10 -8 m -1. Inter-annual variability of the inversion is significantly high and it is caused by the inter-annual variability of fresh water flux and surface cooling in the northern Bay. Fresh water flux leads the occurrence process in association with surface heat flux and advection. The leading role of fresh water flux is understood from the observation that the two occurrence regions of inversion (the western and northeastern Bay) have proximity to the two low salinity (with values about 28-29‰) zones. In the western Bay, the East India Coastal Current brings less saline and cold water from the head of the Bay to the south-west Bay, where it advects over warm, saline water, promoting temperature inversion in this region in association with the surface heat loss. For inversion occurring in the northeastern Bay (where the surface water gains heat from atmosphere), surface advection of the less saline

  12. New Measurements from Old Boreholes: A Look at Interaction Between Surface Air Temperature and Ground Surface Temperature

    Science.gov (United States)

    Heinle, S. M.; Gosnold, W. D.

    2007-12-01

    We recently logged new field measurements of several boreholes throughout the Midwest, including North Dakota, South Dakota, and Nebraska. We then compared these new measurements against measurements previously obtained. Our comparisons included inverse modeling of past and recent measurements as well as climate modeling based on past surface air temperatures obtained from the weather stations. The data show a good correlation between climate warming in the last century and ground surface warming. Of particular importance is that cooling of air temperatures beginning in the mid 1990s reflects in the ground surface temperatures. The boreholes included in the study consist of three boreholes located in north central North Dakota, including two deeper than 200 meters. Two boreholes in the southwestern part of South Dakota, and two from southeastern South Dakota, all approximately 180 meters deep. Also included, were two boreholes (135 meters and over 200 meters deep) located in southwestern Nebraska, and two boreholes in the panhandle of Nebraska, each over 100 meters deep. We obtained historical surface air temperature from climate stations located near the boreholes, both from the United States Historical Climatology Network and from the Western Regional Climate Center.

  13. Surface emissivity and temperature retrieval for a hyperspectral sensor

    Energy Technology Data Exchange (ETDEWEB)

    Borel, C.C.

    1998-12-01

    With the growing use of hyper-spectral imagers, e.g., AVIRIS in the visible and short-wave infrared there is hope of using such instruments in the mid-wave and thermal IR (TIR) some day. The author believes that this will enable him to get around using the present temperature-emissivity separation algorithms using methods which take advantage of the many channels available in hyper-spectral imagers. A simple fact used in coming up with a novel algorithm is that a typical surface emissivity spectrum are rather smooth compared to spectral features introduced by the atmosphere. Thus, a iterative solution technique can be devised which retrieves emissivity spectra based on spectral smoothness. To make the emissivities realistic, atmospheric parameters are varied using approximations, look-up tables derived from a radiative transfer code and spectral libraries. One such iterative algorithm solves the radiative transfer equation for the radiance at the sensor for the unknown emissivity and uses the blackbody temperature computed in an atmospheric window to get a guess for the unknown surface temperature. By varying the surface temperature over a small range a series of emissivity spectra are calculated. The one with the smoothest characteristic is chosen. The algorithm was tested on synthetic data using MODTRAN and the Salisbury emissivity database.

  14. Sea-surface temperature and salinity mapping from remote microwave radiometric measurements of brightness temperature

    Science.gov (United States)

    Hans-Juergen, C. B.; Kendall, B. M.; Fedors, J. C.

    1977-01-01

    A technique to measure remotely sea surface temperature and salinity was demonstrated with a dual frequency microwave radiometer system. Accuracies in temperature of 1 C and in salinity of part thousand for salinity greater than 5 parts per thousand were attained after correcting for the influence of extraterrestrial background radiation, atmospheric radiation and attenuation, sea-surface roughness, and antenna beamwidth. The radiometers, operating at 1.43 and 2.65 GHz, comprise a third-generation system using null balancing and feedback noise injection. Flight measurements from an aircraft at an altitude of 1.4 km over the lower Chesapeake Bay and coastal areas of the Atlantic Ocean resulted in contour maps of sea-surface temperature and salinity with a spatial resolution of 0.5 km.

  15. Ultraviolet surface plasmon-mediated low temperature hydrazine decomposition

    Energy Technology Data Exchange (ETDEWEB)

    Peng, Siying; Sheldon, Matthew T.; Atwater, Harry A. [Thomas J. Watson Laboratories of Applied Physics, California Institute of Technology, Pasadena, California 91125 (United States); Liu, Wei-Guang; Jaramillo-Botero, Andres; Goddard, William Andrew [Materials and Process Simulation Center, California Institute of Technology, Pasadena, California 91125 (United States)

    2015-01-12

    Conventional methods require elevated temperatures in order to dissociate high-energy nitrogen bonds in precursor molecules such as ammonia or hydrazine used for nitride film growth. We report enhanced photodissociation of surface-absorbed hydrazine (N{sub 2}H{sub 4}) molecules at low temperature by using ultraviolet surface plasmons to concentrate the exciting radiation. Plasmonic nanostructured aluminum substrates were designed to provide resonant near field concentration at λ = 248 nm (5 eV), corresponding to the maximum optical cross section for hydrogen abstraction from N{sub 2}H{sub 4}. We employed nanoimprint lithography to fabricate 1 mm × 1 mm arrays of the resonant plasmonic structures, and ultraviolet reflectance spectroscopy confirmed resonant extinction at 248 nm. Hydrazine was cryogenically adsorbed to the plasmonic substrate in a low-pressure ambient, and 5 eV surface plasmons were resonantly excited using a pulsed KrF laser. Mass spectrometry was used to characterize the photodissociation products and indicated a 6.2× overall enhancement in photodissociation yield for hydrazine adsorbed on plasmonic substrates compared with control substrates. The ultraviolet surface plasmon enhanced photodissociation demonstrated here may provide a valuable method to generate reactive precursors for deposition of nitride thin film materials at low temperatures.

  16. Evolution of the Specific Surface Area of Snow in a High Temperature Gradient Metamorphism

    Science.gov (United States)

    Wang, X.; Baker, I.

    2014-12-01

    The structural evolution of low-density snow under a high temperature gradient over a short period usually takes place in the surface layers during diurnal recrystallization or on a clear, cold night. To relate snow microstructures with their thermal properties, we combined X-ray computed microtomography (micro-CT) observations with numerical simulations. Different types of snow were tested over a large range of TGs (100 K m-1- 500 K m-1). The Specific Surface Area (SSA) was used to characterize the temperature gradient metamorphism (TGM). The magnitude of the temperature gradient and the initial snow type both influence the evolution of SSA. The SSA evolution under TGM was dominated by grain growth and the formation of complex surfaces. Fresh snow experienced a logarithmic decrease of SSA with time, a feature been observed previously by others [Calonne et al., 2014; Schneebeli and Sokratov, 2004; Taillandier et al., 2007]. However, for initial rounded and connected snow structures, the SSA will increase during TGM. Understanding the SSA increase is important in order to predict the enhanced uptake of chemical species by snow or increase in snow albedo. Calonne, N., F. Flin, C. Geindreau, B. Lesaffre, and S. Rolland du Roscoat (2014), Study of a temperature gradient metamorphism of snow from 3-D images: time evolution of microstructures, physical properties and their associated anisotropy, The Cryosphere Discussions, 8, 1407-1451, doi:10.5194/tcd-8-1407-2014. Schneebeli, M., and S. A. Sokratov (2004), Tomography of temperature gradient metamorphism of snow and associated changes in heat conductivity, Hydrological Processes, 18(18), 3655-3665, doi:10.1002/hyp.5800. Taillandier, A. S., F. Domine, W. R. Simpson, M. Sturm, and T. A. Douglas (2007), Rate of decrease of the specific surface area of dry snow: Isothermal and temperature gradient conditions, Journal of Geophysical Research: Earth Surface (2003-2012), 112(F3), doi: 10.1029/2006JF000514.

  17. The dependence of surface temperature on IGBTs load and ambient temperature

    Science.gov (United States)

    Alexander, Čaja; Marek, Patsch

    2015-05-01

    Currently, older power electronics and electrotechnics are improvement and at the same time developing new and more efficient devices. These devices produce in their activities a significant part of the heat which, if not effectively drained, causing damage to these elements. In this case, it is important to develop new and more efficient cooling system. The most widespread of modern methods of cooling is the cooling by heat pipe. This contribution is aimed at cooling the insulated-gate bipolar transistor (IGBT) elements by loop heat pipe (LHP). IGBTs are very prone to damage due to high temperatures, and therefore is the important that the surface temperature was below 100°C. It was therefore created a model that examined what impact of surface temperature on the IGBT element and heat removal at different load and constant ambient temperature.

  18. The dependence of surface temperature on IGBTs load and ambient temperature

    Directory of Open Access Journals (Sweden)

    Alexander Čaja

    2015-01-01

    Full Text Available Currently, older power electronics and electrotechnics are improvement and at the same time developing new and more efficient devices. These devices produce in their activities a significant part of the heat which, if not effectively drained, causing damage to these elements. In this case, it is important to develop new and more efficient cooling system. The most widespread of modern methods of cooling is the cooling by heat pipe. This contribution is aimed at cooling the insulated-gate bipolar transistor (IGBT elements by loop heat pipe (LHP. IGBTs are very prone to damage due to high temperatures, and therefore is the important that the surface temperature was below 100°C. It was therefore created a model that examined what impact of surface temperature on the IGBT element and heat removal at different load and constant ambient temperature.

  19. Reconstruction of MODIS daily land surface temperature under clouds

    Science.gov (United States)

    Sun, L.; Gao, F.; Chen, Z.; Song, L.; Xie, D.

    2015-12-01

    Land surface temperature (LST), generally defined as the skin temperature of the Earth's surface, controls the process of evapotranspiration, surface energy balance, soil moisture change and climate change. Moderate Resolution Imaging Spectrometer (MODIS) is equipped with 1km resolution thermal sensor andcapable of observing the earth surface at least once per day.Thermal infrared bands cannot penetrate cloud, which means we cannot get consistency drought monitoring condition at one area. However, the cloudy-sky conditions represent more than half of the actual day-to-day weather around the global. In this study, we developed an LST filled model based on the assumption that under good weather condition, LST difference between two nearby pixels are similar among the closest 8 days. We used all the valid pixels covered by a 9*9 window to reconstruct the gap LST. Each valid pixel is assigned a weight which is determined by the spatial distance and the spectral similarity. This model is applied in the Middle-East of China including Gansu, Ningxia, Shaanxi province. The terrain is complicated in this area including plain and hill. The MODIS daily LST product (MOD11A3) from 2000 to 2004 is tested. Almost all the gap pixels are filled, and the terrain information is reconstructed well and smoothly. We masked two areas in order to validate the model, one located in the plain, another located in the hill. The correlation coefficient is greater than 0.8, even up to 0.92 in a few days. We also used ground measured day maximum and mean surface temperature to valid our model. Although both the temporal and spatial scale are different between ground measured temperature and MODIS LST, they agreed well in all the stations. This LST filled model is operational because it only needs LST and reflectance, and does not need other auxiliary information such as climate factors. We will apply this model to more regions in the future.

  20. Investigating the Impacts of Surface Temperature Anomalies Due to Wildfires in Northern Sub-Saharan Africa

    Science.gov (United States)

    Gabbert, T.; Ichoku, C. M.; Matsui, T.; Capehart, W. J.

    2014-12-01

    The northern Sub-Saharan African region (NSSA) is an area of intense study due to the recent severe droughts that have dire consequences on the population, which relies mostly on rainfed agriculture for its food supply. This region's weather and hydrologic cycle are very complex and are dependent on the West African Monsoon. Different regional processes affect the West African Monsoon cycle and variability. One of the areas of current investigation is the water cycle response to the variability of land surface characteristics. Land surface characteristics are often altered in NSSA due to agricultural practices, grazing, and the fires that occur during the dry season. To better understand the effects of biomass burning on the hydrologic cycle of the sub-Saharan environment, an interdisciplinary team sponsored by NASA is analyzing potential feedback mechanisms due to the fires. As part of this research, this study focuses on the effects of land surface changes, particularly albedo and skin temperature, that are influenced by biomass burning. Surface temperature anomalies can influence the initiation of convective rainfall and surface albedo is linked to the absorption of solar radiation. To capture the effects of fire perturbations on the land surface, NASA's Unified Weather and Research Forecasting (NU-WRF) model coupled with NASA's Land Information System (LIS) is being used to simulate some of the fire-induced surface temperature anomalies and other environmental processes. In this presentation, we will report the strategy for these simulations, and show some preliminary results.

  1. Piglets’ Surface Temperature Change at Different Weights at Birth

    Science.gov (United States)

    Caldara, Fabiana Ribeiro; dos Santos, Luan Sousa; Machado, Sivanilza Teixeira; Moi, Marta; de Alencar Nääs, Irenilza; Foppa, Luciana; Garcia, Rodrigo Garófallo; de Kássia Silva dos Santos, Rita

    2014-01-01

    The study was carried out in order to verify the effects of piglets’ weight at birth on their surface temperature change (ST) after birth, and its relationship with ingestion time of colostrum. Piglets from four different sows were weighed at birth and divided into a totally randomized design with three treatments according to birth weight (PBW): T1 - less than 1.00 kg, T2 - 1.00 to 1.39 kg, and T3 - higher than or equal to 1.40 kg. The time spent for the first colostrum ingestion was recorded (TFS). Images of piglets’ surface by thermal imaging camera were recorded at birth (STB) and 15, 30, 45, 60, and 120 min after birth. The air temperature and relative humidity were recorded every 30 min and the indexes of temperature and humidity (THI) were calculated. A ST drop after 15 min from birth was observed, increasing again after sixty minutes. Positive correlations were found between the PBW and the ST at 30 and 45 min after birth. The PBW was negatively correlated with the TFS. The THI showed high negative correlations (−0.824 and −0.815) with STB and after 15 min from birth. The piglet’s surface temperature at birth was positively correlated with temperature thereof to 15 min, influencing therefore the temperatures in the interval of 45 to 120 min. The birth weight contributes significantly to postnatal hypothermia and consequently to the time it takes for piglets ingest colostrum, requiring special attention to those of low birth weight. PMID:25049971

  2. Piglets' surface temperature change at different weights at birth.

    Science.gov (United States)

    Caldara, Fabiana Ribeiro; Dos Santos, Luan Sousa; Machado, Sivanilza Teixeira; Moi, Marta; de Alencar Nääs, Irenilza; Foppa, Luciana; Garcia, Rodrigo Garófallo; de Kássia Silva Dos Santos, Rita

    2014-03-01

    The study was carried out in order to verify the effects of piglets' weight at birth on their surface temperature change (ST) after birth, and its relationship with ingestion time of colostrum. Piglets from four different sows were weighed at birth and divided into a totally randomized design with three treatments according to birth weight (PBW): T1 - less than 1.00 kg, T2 - 1.00 to 1.39 kg, and T3 - higher than or equal to 1.40 kg. The time spent for the first colostrum ingestion was recorded (TFS). Images of piglets' surface by thermal imaging camera were recorded at birth (STB) and 15, 30, 45, 60, and 120 min after birth. The air temperature and relative humidity were recorded every 30 min and the indexes of temperature and humidity (THI) were calculated. A ST drop after 15 min from birth was observed, increasing again after sixty minutes. Positive correlations were found between the PBW and the ST at 30 and 45 min after birth. The PBW was negatively correlated with the TFS. The THI showed high negative correlations (-0.824 and -0.815) with STB and after 15 min from birth. The piglet's surface temperature at birth was positively correlated with temperature thereof to 15 min, influencing therefore the temperatures in the interval of 45 to 120 min. The birth weight contributes significantly to postnatal hypothermia and consequently to the time it takes for piglets ingest colostrum, requiring special attention to those of low birth weight.

  3. Piglets’ Surface Temperature Change at Different Weights at Birth

    Directory of Open Access Journals (Sweden)

    Fabiana Ribeiro Caldara

    2014-03-01

    Full Text Available The study was carried out in order to verify the effects of piglets’ weight at birth on their surface temperature change (ST after birth, and its relationship with ingestion time of colostrum. Piglets from four different sows were weighed at birth and divided into a totally randomized design with three treatments according to birth weight (PBW: T1 - less than 1.00 kg, T2 - 1.00 to 1.39 kg, and T3 - higher than or equal to 1.40 kg. The time spent for the first colostrum ingestion was recorded (TFS. Images of piglets’ surface by thermal imaging camera were recorded at birth (STB and 15, 30, 45, 60, and 120 min after birth. The air temperature and relative humidity were recorded every 30 min and the indexes of temperature and humidity (THI were calculated. A ST drop after 15 min from birth was observed, increasing again after sixty minutes. Positive correlations were found between the PBW and the ST at 30 and 45 min after birth. The PBW was negatively correlated with the TFS. The THI showed high negative correlations (−0.824 and −0.815 with STB and after 15 min from birth. The piglet’s surface temperature at birth was positively correlated with temperature thereof to 15 min, influencing therefore the temperatures in the interval of 45 to 120 min. The birth weight contributes significantly to postnatal hypothermia and consequently to the time it takes for piglets ingest colostrum, requiring special attention to those of low birth weight.

  4. Near–surface air temperature and snow skin temperature comparison from CREST-SAFE station data with MODIS land surface temperature data

    Directory of Open Access Journals (Sweden)

    C. L. Pérez Díaz

    2015-08-01

    Full Text Available Land Surface Temperature (LST is a key variable (commonly studied to understand the hydrological cycle that helps drive the energy balance and water exchange between the Earth's surface and its atmosphere. One observable constituent of much importance in the land surface water balance model is snow. Snow cover plays a critical role in the regional to global scale hydrological cycle because rain-on-snow with warm air temperatures accelerates rapid snow-melt, which is responsible for the majority of the spring floods. Accurate information on near-surface air temperature (T-air and snow skin temperature (T-skin helps us comprehend the energy and water balances in the Earth's hydrological cycle. T-skin is critical in estimating latent and sensible heat fluxes over snow covered areas because incoming and outgoing radiation fluxes from the snow mass and the air temperature above make it different from the average snowpack temperature. This study investigates the correlation between MODerate resolution Imaging Spectroradiometer (MODIS LST data and observed T-air and T-skin data from NOAA-CREST-Snow Analysis and Field Experiment (CREST-SAFE for the winters of 2013 and 2014. LST satellite validation is imperative because high-latitude regions are significantly affected by climate warming and there is a need to aid existing meteorological station networks with the spatially continuous measurements provided by satellites. Results indicate that near-surface air temperature correlates better than snow skin temperature with MODIS LST data. Additional findings show that there is a negative trend demonstrating that the air minus snow skin temperature difference is inversely proportional to cloud cover. To a lesser extent, it will be examined whether the surface properties at the site are representative for the LST properties within the instrument field of view.

  5. Near-surface air temperature and snow skin temperature comparison from CREST-SAFE station data with MODIS land surface temperature data

    Science.gov (United States)

    Pérez Díaz, C. L.; Lakhankar, T.; Romanov, P.; Muñoz, J.; Khanbilvardi, R.; Yu, Y.

    2015-08-01

    Land Surface Temperature (LST) is a key variable (commonly studied to understand the hydrological cycle) that helps drive the energy balance and water exchange between the Earth's surface and its atmosphere. One observable constituent of much importance in the land surface water balance model is snow. Snow cover plays a critical role in the regional to global scale hydrological cycle because rain-on-snow with warm air temperatures accelerates rapid snow-melt, which is responsible for the majority of the spring floods. Accurate information on near-surface air temperature (T-air) and snow skin temperature (T-skin) helps us comprehend the energy and water balances in the Earth's hydrological cycle. T-skin is critical in estimating latent and sensible heat fluxes over snow covered areas because incoming and outgoing radiation fluxes from the snow mass and the air temperature above make it different from the average snowpack temperature. This study investigates the correlation between MODerate resolution Imaging Spectroradiometer (MODIS) LST data and observed T-air and T-skin data from NOAA-CREST-Snow Analysis and Field Experiment (CREST-SAFE) for the winters of 2013 and 2014. LST satellite validation is imperative because high-latitude regions are significantly affected by climate warming and there is a need to aid existing meteorological station networks with the spatially continuous measurements provided by satellites. Results indicate that near-surface air temperature correlates better than snow skin temperature with MODIS LST data. Additional findings show that there is a negative trend demonstrating that the air minus snow skin temperature difference is inversely proportional to cloud cover. To a lesser extent, it will be examined whether the surface properties at the site are representative for the LST properties within the instrument field of view.

  6. Thermophysical Property Estimation by Transient Experiments: The Effect of a Biased Initial Temperature Distribution

    Directory of Open Access Journals (Sweden)

    Federico Scarpa

    2015-01-01

    Full Text Available The identification of thermophysical properties of materials in dynamic experiments can be conveniently performed by the inverse solution of the associated heat conduction problem (IHCP. The inverse technique demands the knowledge of the initial temperature distribution within the material. As only a limited number of temperature sensors (or no sensor at all are arranged inside the test specimen, the knowledge of the initial temperature distribution is affected by some uncertainty. This uncertainty, together with other possible sources of bias in the experimental procedure, will propagate in the estimation process and the accuracy of the reconstructed thermophysical property values could deteriorate. In this work the effect on the estimated thermophysical properties due to errors in the initial temperature distribution is investigated along with a practical method to quantify this effect. Furthermore, a technique for compensating this kind of bias is proposed. The method consists in including the initial temperature distribution among the unknown functions to be estimated. In this way the effect of the initial bias is removed and the accuracy of the identified thermophysical property values is highly improved.

  7. Temperature-dependent photoluminescence of surface-engineered silicon nanocrystals

    Science.gov (United States)

    Mitra, Somak; Švrček, Vladimir; Macias-Montero, Manual; Velusamy, Tamilselvan; Mariotti, Davide

    2016-01-01

    In this work we report on temperature-dependent photoluminescence measurements (15–300 K), which have allowed probing radiative transitions and understanding of the appearance of various transitions. We further demonstrate that transitions associated with oxide in SiNCs show characteristic vibronic peaks that vary with surface characteristics. In particular we study differences and similarities between silicon nanocrystals (SiNCs) derived from porous silicon and SiNCs that were surface-treated using a radio-frequency (RF) microplasma system. PMID:27296771

  8. Biological control of surface temperature in the Arabian Sea

    Science.gov (United States)

    Sathyendranath, Shubha; Gouveia, Albert D.; Shetye, Satish R.; Ravindran, P.; Platt, Trevor

    1991-01-01

    In the Arabian Sea, the southwest monsoon promotes seasonal upwelling of deep water, which supplies nutrients to the surface layer and leads to a marked increase in phytoplankton growth. Remotely sensed data on ocean color are used here to show that the resulting distribution of phytoplankton exerts a controlling influence on the seasonal evolution of sea surface temperature. This results in a corresponding modification of ocean-atmosphere heat exchange on regional and seasonal scales. It is shown that this biological mechanism may provide an important regulating influence on ocean-atmosphere interactions.

  9. Estimating Temperature Fields from MODIS Land Surface Temperature and Air Temperature Observations in a Sub-Arctic Alpine Environment

    Directory of Open Access Journals (Sweden)

    Scott N. Williamson

    2014-01-01

    Full Text Available Spatially continuous satellite infrared temperature measurements are essential for understanding the consequences and drivers of change, at local and regional scales, especially in northern and alpine environments dominated by a complex cryosphere where in situ observations are scarce. We describe two methods for producing daily temperature fields using MODIS “clear-sky” day-time Land Surface Temperatures (LST. The Interpolated Curve Mean Daily Surface Temperature (ICM method, interpolates single daytime Terra LST values to daily means using the coincident diurnal air temperature curves. The second method calculates daily mean LST from daily maximum and minimum LST (MMM values from MODIS Aqua and Terra. These ICM and MMM models were compared to daily mean air temperatures recorded between April and October at seven locations in southwest Yukon, Canada, covering characteristic alpine land cover types (tundra, barren, glacier at elevations between 1,408 m and 2,319 m. Both methods for producing mean daily surface temperatures have advantages and disadvantages. ICM signals are strongly correlated with air temperature (R2 = 0.72 to 0.86, but have relatively large variability (RMSE = 4.09 to 4.90 K, while MMM values had a stronger correlation to air temperature (R2 = 0.90 and smaller variability (RMSE = 2.67 K. Finally, when comparing 8-day LST averages, aggregated from the MMM method, to air temperature, we found a high correlation (R2 = 0.84 with less variability (RMSE = 1.54 K. Where the trend was less steep and the y-intercept increased by 1.6 °C compared to the daily correlations. This effect is likely a consequence of LST temperature averages being differentially affected by cloud cover over warm and cold surfaces. We conclude that satellite infrared skin temperature (e.g., MODIS LST, which is often aggregated into multi-day composites to mitigate data reductions caused by cloud cover, changes in its relationship to air temperature

  10. Calibration plan for the sea and land surface temperature radiometer

    Science.gov (United States)

    Smith, David L.; Nightingale, Tim J.; Mortimer, Hugh; Middleton, Kevin; Edeson, Ruben; Cox, Caroline V.; Mutlow, Chris T.; Maddison, Brian J.

    2013-10-01

    The Sea and Land Surface Temperature Radiometer (SLSTR) to be flown on ESA's Sentinel-3 mission is a multichannel scanning radiometer that will continue the 21-year datasets of the Along Track Scanning Radiometer (ATSR) series. As its name implies, measurements from SLSTR will be used to retrieve global sea surface temperatures to an uncertainty of SLSTR instrument, infrared calibration sources and alignment equipment. The calibration rig has been commissioned and results of these tests will be presented. Finally the authors will present the planning for the on-orbit monitoring and calibration activities to ensure that calibration is maintained. These activities include vicarious calibration techniques that have been developed through previous missions, and the deployment of ship-borne radiometers.

  11. A surface acoustic wave ICP sensor with good temperature stability.

    Science.gov (United States)

    Zhang, Bing; Hu, Hong; Ye, Aipeng; Zhang, Peng

    2017-07-20

    Intracranial pressure (ICP) monitoring is very important for assessing and monitoring hydrocephalus, head trauma and hypertension patients, which could lead to elevated ICP or even devastating neurological damage. The mortality rate due to these diseases could be reduced through ICP monitoring, because precautions can be taken against the brain damage. This paper presents a surface acoustic wave (SAW) pressure sensor to realize ICP monitoring, which is capable of wireless and passive transmission with antenna attached. In order to improve the temperature stability of the sensor, two methods were adopted. First, the ST cut quartz was chosen as the sensor substrate due to its good temperature stability. Then, a differential temperature compensation method was proposed to reduce the effects of temperature. Two resonators were designed based on coupling of mode (COM) theory and the prototype was fabricated and verified using a system established for testing pressure and temperature. The experiment result shows that the sensor has a linearity of 2.63% and hysteresis of 1.77%. The temperature stability of the sensor has been greatly improved by using the differential compensation method, which validates the effectiveness of the proposed method.

  12. Surface modification of glycidyl-containing poly(methyl methacrylate) microchips using surface-initiated atom-transfer radical polymerization.

    Science.gov (United States)

    Sun, Xuefei; Liu, Jikun; Lee, Milton L

    2008-02-01

    Fabrication of microfluidic systems from polymeric materials is attractive because of simplicity and low cost. Unfortunately, the surfaces of many polymeric materials can adsorb biological samples. Therefore, it is necessary to modify their surfaces before these polymeric materials can be used for separation and analysis. Oftentimes it is difficult to modify polymeric surfaces because of their resistance to chemical reaction. Recently, we introduced a surface-reactive acrylic polymer, poly(glycidyl methacrylate-co-methyl methacrylate) (PGMAMMA), which can be modified easily and is suitable for fabrication of microfluidic devices. Epoxy groups on the surface can be activated by air plasma treatment, hydrolysis, or aminolysis. In this work, the resulting hydroxyl or amino groups were reacted with 2-bromoisobutylryl bromide to introduce an initiator for surface-initiated atom-transfer radical polymerization (SI-ATRP). Polyethylene glycol (PEG) layers grown on the surface using this method were uniform, hydrophilic, stable, and resistant to protein adsorption. Contact angle measurement and X-ray photoelectron spectroscopy (XPS) were used to characterize activated polymer surfaces, initiator-bound surfaces, and PEG-grafted surfaces. We obtained excellent capillary electrophoresis (CE) separations of proteins and peptides with the PEG-modified microchips. A separation efficiency of 4.4 x 10(4) plates for a 3.5 cm long separation channel was obtained.

  13. A New Estimate of the Earth's Land Surface Temperature History

    Science.gov (United States)

    Muller, R. A.; Curry, J. A.; Groom, D.; Jacobsen, B.; Perlmutter, S.; Rohde, R. A.; Rosenfeld, A.; Wickham, C.; Wurtele, J.

    2011-12-01

    The Berkeley Earth Surface Temperature team has re-evaluated the world's atmospheric land surface temperature record using a linear least-squares method that allow the use of all the digitized records back to 1800, including short records that had been excluded by prior groups. We use the Kriging method to estimate an optimal weighting of stations to give a world average based on uniform weighting of the land surface. We have assembled a record of the available data by merging 1.6 billion temperature reports from 16 pre-existing data archives; this data base will be made available for public use. The former Global Historic Climatology Network (GHCN) monthly data base shows a sudden drop in the number of stations reporting monthly records from 1980 to the present; we avoid this drop by calculating monthly averages from the daily records. By using all the data, we reduce the effects of potential data selection bias. We make an independent estimate of the urban heat island effect by calculating the world land temperature trends based on stations chosen to be far from urban sites. We calculate the effect of poor station quality, as documented in the US by the team led by Anthony Watts by estimating the temperature trends based solely on the stations ranked good (1,2 or 1,2,3 in the NOAA ranking scheme). We avoid issues of homogenization bias by using raw data; at times when the records are discontinuous (e.g. due to station moves) we break the record into smaller segments and analyze those, rather than attempt to correct the discontinuity. We estimate the uncertainties in the final results using the jackknife procedure developed by J. Tukey. We calculate spatial uncertainties by measuring the effects of geographical exclusion on recent data that have good world coverage. The results we obtain are compared to those published by the groups at NOAA, NASA-GISS, and Hadley-CRU in the UK.

  14. Effect of floor surface temperature on blood flow and skin temperature in the foot.

    Science.gov (United States)

    Song, G-S

    2008-12-01

    A total of 16 healthy college students participated as subjects to elucidate the hypothesis that blood flow and skin temperature in foot are affected by the floor surface temperature. The floor surface temperature was controlled by varying the temperature of water (tw) flowing underneath the floor, and it ranged from tw 15 to 40 degrees C at 5 degrees C intervals. The blood flow rate was measured in the dorsal right toe, and skin temperatures were measured for 60 min at 8 points: the neck, right scapular, left hand, right shin, left bottom of the toe, right instep, left finger, and rectum. The blood flow rate in the foot tissue was increased until the foot skin temperature warmed up to 34 degrees C (P = 0.000). The final skin temperatures on the bottom of the toe were 19.4 +/- 2.44 degrees C for tw 15 degrees C, 22.4 +/- 2.45 degrees C for tw 20 degrees C, 24.8 +/- 2.80 degrees C for tw 25 degrees C, 27.7 +/- 2.13 degrees C for tw 30 degrees C, 30.6 +/- 2.06 degrees C for tw 35 degrees C, 33.2 +/- 1.45 degrees C for tw 40 degrees C, 34.2 +/- 1.55 degrees C for tw 45 degrees C, and 35.2 +/- 1.65 degrees C for tw 50 degrees C. Considering blood flow and comfort, the partial floor heating system is suggested and the recommended floor surface temperature range is 27-33 degrees C. A warm floor surface can serve to satisfy occupants when the ambient temperature maintained at 20 degrees C which represents an energy conscious temperature. A warm floor can induce high blood perfusion in the feet and consequently improve an occupant's health by treating many vascular-related disorders. Even in a well-insulated residential building, a partially heated floor system could prevent overheating while providing surface warmth.

  15. The sensitivity of multiple equilibria in a cloud resolving model to sea surface temperature changes in weak temperature gradient simulations

    Science.gov (United States)

    Sentic, Stipo; Sessions, Sharon

    2012-10-01

    In the tropics, gravity waves quickly redistribute buoyancy anomalies, which leads to approximately weak temperature gradients (WTG) in the horizontal. In our cloud resolving model (CRM), the WTG approximation is enforced by relaxing potential temperature perturbations to a reference profile which represents the mean state of the atmosphere. To obtain reference profiles, the model is run in a non-WTG mode until radiative convective equilibrium (RCE). RCE vertical profiles of temperature and moisture are then used as reference profiles for WTG simulations. Continuing the work of Sessions et al (2010), we investigate the sensitivity of multiple equilibria in a CRM to changes in sea surface temperatures (SST). Multiple equilibria refers to a precipitating or non-precipitating steady state under identical forcing conditions. Specifically, we run RCE simulations for different SSTs to generate reference profiles representing different large scale environments for WTG simulations. We then perform WTG experiments for each SST with varying surface wind speeds. The model domain is initialized either with a completely dry troposphere, or with a RCE moisture profile. We find that the range of wind speeds maintaining both a dry and a precipitating steady state is strongly dependent on SST.

  16. Actual evaporation estimation from infrared measurement of soil surface temperature

    Directory of Open Access Journals (Sweden)

    Davide Pognant

    2013-09-01

    Full Text Available Within the hydrological cycle, actual evaporation represents the second most important process in terms of volumes of water transported, second only to the precipitation phenomena. Several methods for the estimation of the Ea were proposed by researchers in scientific literature, but the estimation of the Ea from potential evapotranspiration often requires the knowledge of hard-to-find parameters (e.g.: vegetation morphology, vegetation cover, interception of rainfall by the canopy, evaporation from the canopy surface and uptake of water by plant roots and many existing database are characterized by missing or incomplete information that leads to a rough estimation of the actual evaporation amount. Starting from the above considerations, the aim of this study is to develop and validate a method for the estimation of the Ea based on two steps: i the potential evaporation estimation by using the meteorological data (i.e. Penman-Monteith; ii application of a correction factor based on the infrared soil surface temperature measurements. The dataset used in this study were collected during two measurement campaigns conducted both in a plain testing site (Grugliasco, Italy, and in a mountain South-East facing slope (Cogne, Italy. During those periods, hourly measurement of air temperature, wind speed, infrared surface temperature, soil heat flux, and soil water content were collected. Results from the dataset collected in the two testing sites show a good agreement between the proposed method and reference methods used for the Ea estimation.

  17. Land surface temperature shaped by urban fractions in megacity region

    Science.gov (United States)

    Zhang, Xiaoxuan; Hu, Yonghong; Jia, Gensuo; Hou, Meiting; Fan, Yanguo; Sun, Zhongchang; Zhu, Yuxiang

    2017-02-01

    Large areas of cropland and natural vegetation have been replaced by impervious surfaces during the recent rapid urbanization in China, which has resulted in intensified urban heat island effects and modified local or regional warming trends. However, it is unclear how urban expansion contributes to local temperature change. In this study, we investigated the relationship between land surface temperature (LST) change and the increase of urban land signals. The megacity of Tianjin was chosen for the case study because it is representative of the urbanization process in northern China. A combined analysis of LST and urban land information was conducted based on an urban-rural transect derived from Landsat 8 Thermal Infrared Sensor (TIRS), Terra Moderate Resolution Imaging Spectrometer (MODIS), and QuickBird images. The results indicated that the density of urban land signals has intensified within a 1-km2 grid in the urban center with an impervious land fraction >60 %. However, the construction on urban land is quite different with low-/mid-rise buildings outnumbering high-rise buildings in the urban-rural transect. Based on a statistical moving window analysis, positive correlation ( R 2 > 0.9) is found between LST and urban land signals. Surface temperature change (ΔLST) increases by 0.062 °C, which was probably caused by the 1 % increase of urbanized land (ΔIF) in this case region.

  18. A unique approach to demonstrating that apical bud temperature specifically determines leaf initiation rate in the dicot Cucumis sativus

    NARCIS (Netherlands)

    Savvides, Andreas; Dieleman, Anja; Ieperen, van Wim; Marcelis, Leo F.M.

    2016-01-01

    Main conclusion: Leaf initiation rate is largely determined by the apical bud temperature even when apical bud temperature largely deviates from the temperature of other plant organs.We have long known that the rate of leaf initiation (LIR) is highly sensitive to temperature, but previous studies

  19. High temperature surface degradation of III-V nitrides

    Energy Technology Data Exchange (ETDEWEB)

    Vartuli, C.B.; Pearton, S.J.; Abernathy, C.R.; MacKenzie, J.D.; Lambers, E.S. [Univ. of Florida, Gainesville, FL (United States). Dept. of Materials Science and Engineering; Zolper, J.C. [Sandia National Labs., Albuquerque, NM (United States)

    1996-05-01

    The surface stoichiometry, surface morphology and electrical conductivity of AlN, GaN, InN, InGaN and InAlN was examined at rapid thermal annealing temperatures up to 1,150 C. The sheet resistance of the AlN dropped steadily with annealing, but the surface showed signs of roughening only above 1,000 C. Auger Electronic Spectroscopy (AES) analysis showed little change in the surface stoichiometry even at 1,150 C. GaN root mean square (RMS) surface roughness showed an overall improvement with annealing, but the surface became pitted at 1,000 C, at which point the sheet resistance also dropped by several orders of magnitude, and AES confirmed a loss of N from the surface. The InN surface had roughened considerably even at 650 C, and scanning electron microscopy (SEM) showed significant degradation. In contrast to the binary nitrides the sheet resistance of InAlN was found to increase by {approximately} 10{sup 2} from the as grown value after annealing at 800 C and then remain constant up to 1,000 C, while that of InGaN increased rapidly above 700 C. The RMS roughness increased above 800 C and 700 C respectively for InAlN and InGaN samples. In droplets began to form on the surface at 900 C for InAlN and at 800 C for InGaN, and then evaporate at 1,000 C leaving pits. AES analysis showed a decrease in the N concentration in the top 500 {angstrom} of the sample for annealing {ge} 800 C in both materials.

  20. Surface Tensions and Their Variations with Temperature and Impurities

    Science.gov (United States)

    Hardy, S. C.; Fine, J.

    1985-01-01

    The surface tensions in this work were determined using the sessile drop technique. This method is based on a comparison of the profile of a liquid drop with the profile calculated by solving the Young-Laplace equation. The comparison can be made in several ways; the traditional Bashforth-Adams procedure was used in conjunction with recently calculated drop shape tables which virtually eliminate interpolation errors. Although previous study has found little difference in measurements with pure and oxygen doped silicon, there is other evidence suggesting that oxygen in dilute concentrations severely depresses the surface tension of silicon. The surface tension of liquid silicon in purified argon atmospheres was measured. A temperature coefficient near -0.28 mJ/square meters K was found. The experiments show a high sensitivity of the surface tension to what is believed are low concentrations of oxygen. Thus one cannot rule out some effect of low levels of oxygen in the results. However, the highest surface tension values obtained in conditions which minimized the residual oxygen pressure are in good agreement with a previous measurement in pure hydrogen. Therefore, depression of the surface tension by oxygen is insignificant in these measurements.

  1. Effect of initial temperature and concentration of catalyst in polyeugenol production

    Energy Technology Data Exchange (ETDEWEB)

    Widayat, E-mail: yayat-99@yahoo.com [Department of Chemical Engineering, Faculty of Engineering, Diponegoro University (Indonesia); Center of Biomass and Renewable Energy Center of Research and Service Diponegoro University Jln Prof. Soedarto, SH. Semarang 50 239, Tel / Fax: (024) 7460058 (Indonesia); Fatuchrohman, Alviano; Gustiasih, Ellen [Department of Chemical Engineering, Faculty of Engineering, Diponegoro University (Indonesia)

    2015-12-29

    Objective of this research to study influencing of sulfuric acid concentration and initials temperature on polymerization of eugenol. Eugenol is the largest compound in the clove oil that used as raw material. Eugenol was polymerized laboratory scale. Polymerization processing conducted in reactor at 30 minutes. Polyeugenol was obtained in polymerization was conducted at temperature 40°C and ratio eugenol to sulfuric acid 1:15 mole. This research was pbtained the highest yield 81.49%. However, the weight would be increase in according with increasing of initial temperature. The polymerization in temperature 50°C with 1:1.5 mole ratio has the heaviest molecule weight; 47,530.76 gr/mole.

  2. Correlation between stoichiometry and surface structure of the polar MgAl2O4(100) surface as a function of annealing temperature

    DEFF Research Database (Denmark)

    Jensen, Thomas Nørregaard; Rasmussen, Morten Karstoft; Knudsen, Jan

    2015-01-01

    The correlation between surface structure, stoichiometry and atomic occupancy of the polar MgAl2O4(100) surface has been studied with an interplay of noncontact atomic force microscopy, x-ray photoelectron spectroscopy and surface x-ray diffraction under ultrahigh vacuum conditions. The Al/Mg ratio...... restores to its initial value, the occupancy of all elements increases, and the surface transforms into a well-defined structure with large flat terraces and straight step edges, indicating a restoration of the surface stoichiometry. It is proposed, that the tetrahedral vacancies at these high temperatures...

  3. Improve oxidation resistance at high temperature by nanocrystalline surface layer.

    Science.gov (United States)

    Xia, Z X; Zhang, C; Huang, X F; Liu, W B; Yang, Z G

    2015-08-13

    An interesting change of scale sequence occurred during oxidation of nanocrystalline surface layer by means of a surface mechanical attrition treatment. The three-layer oxide structure from the surface towards the matrix is Fe3O4, spinel FeCr2O4 and corundum (Fe,Cr)2O3, which is different from the typical two-layer scale consisted of an Fe3O4 outer layer and an FeCr2O4 inner layer in conventional P91 steel. The diffusivity of Cr, Fe and O is enhanced concurrently in the nanocrystalline surface layer, which causes the fast oxidation in the initial oxidation stage. The formation of (Fe,Cr)2O3 inner layer would inhabit fast diffusion of alloy elements in the nanocrystalline surface layer of P91 steel in the later oxidation stage, and it causes a decrease in the parabolic oxidation rate compared with conventional specimens. This study provides a novel approach to improve the oxidation resistance of heat resistant steel without changing its Cr content.

  4. Onset of initial planar instability with surface-tension anisotropy during directional solidification.

    Science.gov (United States)

    Wang, Zhijun; Wang, Jincheng; Yang, Gencang

    2009-11-01

    A simple model is presented to describe the variation of the onset of the initial planar instability with surface tension anisotropy during directional solidification. The effect of surface-tension anisotropy on the incubation time and the initial average wavelength of planar instability are predicted by the simple model quantitatively, which are also verified by phase field simulation. Investigation results reveal that surface-tension anisotropy is one of important factors in the dynamic process of planar instability. The contribution of surface-tension anisotropy to the tilting modulation is also analyzed by comparing the results from the present simple model with those from phase field simulation.

  5. Modeling of surface temperature effects on mixed material migration in NSTX-U

    Science.gov (United States)

    Nichols, J. H.; Jaworski, M. A.; Schmid, K.

    2016-10-01

    NSTX-U will initially operate with graphite walls, periodically coated with thin lithium films to improve plasma performance. However, the spatial and temporal evolution of these films during and after plasma exposure is poorly understood. The WallDYN global mixed-material surface evolution model has recently been applied to the NSTX-U geometry to simulate the evolution of poloidally inhomogenous mixed C/Li/O plasma-facing surfaces. The WallDYN model couples local erosion and deposition processes with plasma impurity transport in a non-iterative, self-consistent manner that maintains overall material balance. Temperature-dependent sputtering of lithium has been added to WallDYN, utilizing an adatom sputtering model developed from test stand experimental data. Additionally, a simplified temperature-dependent diffusion model has been added to WallDYN so as to capture the intercalation of lithium into a graphite bulk matrix. The sensitivity of global lithium migration patterns to changes in surface temperature magnitude and distribution will be examined. The effect of intra-discharge increases in surface temperature due to plasma heating, such as those observed during NSTX Liquid Lithium Divertor experiments, will also be examined. Work supported by US DOE contract DE-AC02-09CH11466.

  6. Modeled Seasonal Variations of Firn Density Induced by Steady State Surface Air Temperature Cycle

    Science.gov (United States)

    Jun, Li; Zwally, H. Jay; Koblinsky, Chester J. (Technical Monitor)

    2001-01-01

    Seasonal variations of firn density in ice-sheet firn layers have been attributed to variations in deposition processes or other processes within the upper firn. A recent high-resolution (mm scale) density profile, measured along a 181 m core from Antarctica, showed small-scale density variations with a clear seasonal cycle that apparently was not-related to seasonal variations in deposition or known near-surface processes (Gerland and others 1999). A recent model of surface elevation changes (Zwally and Li, submitted) produced a seasonal variation in firn densification, and explained the seasonal surface elevation changes observed by satellite radar altimeters. In this study, we apply our 1-D time-dependent numerical model of firn densification that includes a temperature-dependent formulation of firn densification based on laboratory measurements of grain growth. The model is driven by a steady-state seasonal surface temperature and a constant accumulation rate appropriate for the measured Antarctic ice core. The modeled seasonal variations in firn density show that the layers of snow deposited during spring to mid-summer with the highest temperature history compress to the highest density, and the layers deposited during later summer to autumn with the lowest temperature history compress to the lowest density. The initial amplitude of the seasonal difference of about 0.13 reduces to about 0.09 in five years and asymptotically to 0.92 at depth, which is consistent with the core measurements.

  7. National Enforcement Initiative: Preventing Animal Waste from Contaminating Surface and Ground Water

    Science.gov (United States)

    This page describes EPA's goal in preventing animal waste from contaminating surface and ground Water. It is an EPA National Enforcement Initiative. Both enforcement cases, and a map of enforcement actions are provided.

  8. Decadal trends in Red Sea maximum surface temperature

    KAUST Repository

    Chaidez, Veronica

    2017-08-09

    Ocean warming is a major consequence of climate change, with the surface of the ocean having warmed by 0.11 °C decade-1 over the last 50 years and is estimated to continue to warm by an additional 0.6 - 2.0 °C before the end of the century1. However, there is considerable variability in the rates experienced by different ocean regions, so understanding regional trends is important to inform on possible stresses for marine organisms, particularly in warm seas where organisms may be already operating in the high end of their thermal tolerance. Although the Red Sea is one of the warmest ecosystems on earth, its historical warming trends and thermal evolution remain largely understudied. We characterized the Red Sea\\'s thermal regimes at the basin scale, with a focus on the spatial distribution and changes over time of sea surface temperature maxima, using remotely sensed sea surface temperature data from 1982 - 2015. The overall rate of warming for the Red Sea is 0.17 ± 0.07 °C decade-1, while the northern Red Sea is warming between 0.40 and 0.45 °C decade-1, all exceeding the global rate. Our findings show that the Red Sea is fast warming, which may in the future challenge its organisms and communities.

  9. The impact of heterogeneous surface temperatures on the 2-m air temperature over the Arctic Ocean under clear skies in spring

    Directory of Open Access Journals (Sweden)

    A. Tetzlaff

    2013-01-01

    Full Text Available The influence of spatial surface temperature changes over the Arctic Ocean on the 2-m air temperature variability is estimated using backward trajectories based on ERA-Interim and JRA25 wind fields. They are initiated at Alert, Barrow and at the Tara drifting station. Three different methods are used. The first one compares mean ice surface temperatures along the trajectories to the observed 2-m air temperatures at the stations. The second one correlates the observed temperatures to air temperatures obtained using a simple Lagrangian box model that only includes the effect of sensible heat fluxes. For the third method, mean sensible heat fluxes from the model are correlated with the difference of the air temperatures at the model starting point and the observed temperatures at the stations. The calculations are based on MODIS ice surface temperatures and four different sets of ice concentration derived from SSM/I (Special Sensor Microwave Imager and AMSR-E (Advanced Microwave Scanning Radiometer for EOS data. Under nearly cloud-free conditions, up to 90% of the 2-m air temperature variance can be explained for Alert, and 70% for Barrow, using these methods. The differences are attributed to the different ice conditions, which are characterized by high ice concentration around Alert and lower ice concentration near Barrow. These results are robust for the different sets of reanalyses and ice concentration data. Trajectories based on 10-m wind fields from both reanalyses show large spatial differences in the Central Arctic, leading to differences in the correlations between modeled and observed 2-m air temperatures. They are most pronounced at Tara, where explained variances amount to 70% using JRA and 80% using ERA. The results also suggest that near-surface temperatures at a given site are influenced by the variability of surface temperatures in a domain of about 200 km radius around the site.

  10. Temperature-mediated transition from Dyakonov-Tamm surface waves to surface-plasmon-polariton waves

    Science.gov (United States)

    Chiadini, Francesco; Fiumara, Vincenzo; Mackay, Tom G.; Scaglione, Antonio; Lakhtakia, Akhlesh

    2017-08-01

    The effect of changing the temperature on the propagation of electromagnetic surface waves (ESWs), guided by the planar interface of a homogeneous isotropic temperature-sensitive material (namely, InSb) and a temperature-insensitive structurally chiral material (SCM) was numerically investigated in the terahertz frequency regime. As the temperature rises, InSb transforms from a dissipative dielectric material to a dissipative plasmonic material. Correspondingly, the ESWs transmute from Dyakonov-Tamm surface waves into surface-plasmon-polariton waves. The effects of the temperature change are clearly observed in the phase speeds, propagation distances, angular existence domains, multiplicity, and spatial profiles of energy flow of the ESWs. Remarkably large propagation distances can be achieved; in such instances the energy of an ESW is confined almost entirely within the SCM. For certain propagation directions, simultaneous excitation of two ESWs with (i) the same phase speeds but different propagation distances or (ii) the same propagation distances but different phase speeds are also indicated by our results.

  11. Temperature comparison of initial, middle and final point of polypropylene friction stir welded

    Science.gov (United States)

    Kusharjanta, Bambang; Raharjo, Wahyu P.; Triyono

    2016-03-01

    Friction Stir Welding is known as a new solid state joining process. This process is applied in thermoplastic polymers material recently. One of member thermoplastic polymer is polypropylene. Polypropylene sheet 6 mm thick was friction stir welded with a cone cut steel pin. Tool rotation, travelling speed, and plunge depth, as welding parameters were 620 rpm, 7.3 mm/minutes and 0.02 mm respectively. Temperature at the initial, middle, and final point of advance side working piece were measured and compared. Measurement were done by thermocouple and recorded by data acquisition. Based on this research, it is concluded that temperature at the initial, middle and final point of friction stir welding process are different. The highest temperature peak reach at the middle point on the advance side which affects face bending strength.

  12. Gaia FGK Benchmark Stars: Effective temperatures and surface gravities

    CERN Document Server

    Heiter, U; Gustafsson, B; Korn, A J; Soubiran, C; Thévenin, F

    2015-01-01

    Large Galactic stellar surveys and new generations of stellar atmosphere models and spectral line formation computations need to be subjected to careful calibration and validation and to benchmark tests. We focus on cool stars and aim at establishing a sample of 34 Gaia FGK Benchmark Stars with a range of different metallicities. The goal was to determine the effective temperature and the surface gravity independently from spectroscopy and atmospheric models as far as possible. Fundamental determinations of Teff and logg were obtained in a systematic way from a compilation of angular diameter measurements and bolometric fluxes, and from a homogeneous mass determination based on stellar evolution models. The derived parameters were compared to recent spectroscopic and photometric determinations and to gravity estimates based on seismic data. Most of the adopted diameter measurements have formal uncertainties around 1%, which translate into uncertainties in effective temperature of 0.5%. The measurements of bol...

  13. Global Surface Temperature Response Explained by Multibox Energy Balance Models

    Science.gov (United States)

    Fredriksen, H. B.; Rypdal, M.

    2016-12-01

    We formulate a multibox energy balance model, from which global temperature evolution can be described by convolving a linear response function and a forcing record. We estimate parameters in the response function from instrumental data and historic forcing, such that our model can produce a response to both deterministic forcing and stochastic weather forcing consistent with observations. Furthermore, if we make separate boxes for upper ocean layer and atmosphere over land, we can also make separate response functions for global land and sea surface temperature. By describing internal variability as a linear response to white noise, we demonstrate that the power-law form of the observed temperature spectra can be described by linear dynamics, contrary to a common belief that these power-law spectra must arise from nonlinear processes. In our multibox model, the power-law form can arise due to the multiple response times. While one of our main points is that the climate system responds over a wide range of time scales, we cannot find one set of time scales that can be preferred compared to other choices. Hence we think the temperature response can best be characterized as something that is scale-free, but still possible to approximate by a set of well separated time scales.

  14. Protein repellent hydrophilic grafts prepared by surface-initiated atom transfer radical polymerization from polypropylene

    DEFF Research Database (Denmark)

    Fristrup, Charlotte Juel; Jankova Atanasova, Katja; Eskimergen, Rüya

    2012-01-01

    Grafting of poly(ethylene glycol)methacrylate (PEGMA) and N,N-dimethylacrylamide (DMAAm) from UV-initiator modified polypropylene (PP) was performed by Surface-Initiated Atom Transfer Radical Polymerization (SI-ATRP). The modification and hydrophilization of the PP substrates were confirmed...

  15. Surface mapping of field-induced piezoelectric strain at elevated temperature employing full-field interferometry.

    Science.gov (United States)

    Stevenson, Tim; Quast, Tatjana; Bartl, Guido; Schmitz-Kempen, Thorsten; Weaver, Paul M

    2015-01-01

    Piezoelectric actuators and sensors are widely used for flow control valves, including diesel injectors, ultrasound generation, optical positioning, printing, pumps, and locks. Degradation and failure of material and electrical properties at high temperature typically limits these applications to operating temperatures below 200°C, based on the ubiquitous Pb(Zr,Ti)O3 ceramic. There are, however, many applications in sectors such as automotive, aerospace, energy and process control, and oil and gas, where the ability to operate at higher temperatures would open up new markets for piezoelectric actuation. Presented here is a review of recent progress and initial results toward a European effort to develop measurement techniques to characterize high-temperature materials. Full-field, multi-wavelength absolute length interferometry has, for the first time, been used to map the electric-field-induced piezoelectric strain across the surface of a PZT ceramic. The recorded variation as a function of temperature has been evaluated against a newly developed commercial single-beam system. Conventional interferometry allows measurement of the converse piezoelectric effect with high precision and resolution, but is often limited to a single point, average measurement and to limited sample environments because of optical aberrations in varying atmospheres. Here, the full-field technique allows the entire surface to be analyzed for strain and, in a bespoke sample chamber, for elevated temperatures.

  16. Geostatistical Solutions for Downscaling Remotely Sensed Land Surface Temperature

    Science.gov (United States)

    Wang, Q.; Rodriguez-Galiano, V.; Atkinson, P. M.

    2017-09-01

    Remotely sensed land surface temperature (LST) downscaling is an important issue in remote sensing. Geostatistical methods have shown their applicability in downscaling multi/hyperspectral images. In this paper, four geostatistical solutions, including regression kriging (RK), downscaling cokriging (DSCK), kriging with external drift (KED) and area-to-point regression kriging (ATPRK), are applied for downscaling remotely sensed LST. Their differences are analyzed theoretically and the performances are compared experimentally using a Landsat 7 ETM+ dataset. They are also compared to the classical TsHARP method.

  17. Effect of surface nanostructure on temperature programmed reaction spectroscopy

    Science.gov (United States)

    Rieger, Michael; Rogal, Jutta; Reuter, Karsten

    2008-03-01

    Using the catalytic CO oxidation at RuO2(110) as a showcase, we employ first-principles kinetic Monte Carlo simulations to illustrate the intricate effects on temperature programmed reaction (TPR) spectroscopy data brought about by the mere correlations between the locations of the active sites at a nanostructured surface. Even in the absence of lateral interactions, this nanostructure alone can cause inhomogeneities that cannot be grasped by prevalent mean-field data analysis procedures, which thus lead to wrong conclusions on the reactivity of the different surface species. The RuO2(110) surface studied here exhibits only two prominent active sites, arranged in simple alternating rows. Yet, the mere neglection of this still quite trivial nanostructure leads mean-field TPR data analysis [1] to extract kinetic parameters that are in error by several orders of magnitude and that do not even reflect the relative reactivity of the different surface species correctly [2].[1] S. Wendt, M. Knapp, and H. Over, JACS 126, 1537 (2004).[2] M. Rieger, J. Rogal, and K. Reuter, Phys. Rev. Lett (in press).

  18. Surface Roughness of Initial Enamel Caries Lesions in Human Teeth After Resin Infiltration

    Science.gov (United States)

    Arnold, Wolfgang H.; Meyer, Ann-Kathrin; Naumova, Ella A.

    2016-01-01

    Background: Low viscosity resin infiltration of initial caries lesions is a modern microinvasive method to treat initial cries lesions. However, only scarce information is available about the long-term surface alterations of infiltrated lesions. Methods: Twenty-eight premolar teeth exhibiting non-cavitated initial caries lesions (International Caries Detection and Assessment System (ICDAS code 1&2)) were divided into two groups, one of which was infiltrated with resin, and the other remained untreated. The teeth underwent two thermocycling procedures. The surface roughness was determined quantitatively, and the results were evaluated statistically. In addition, the surfaces of the lesions were investigated by scanning electron microscopy (SEM), and the surface was analyzed visually with respect to surface irregularities. Results: The results showed a reduction in the surface roughness that was significant after 2500 thermocycles compared to the untreated surface. In the control specimens, no change in the surface roughness was found. The qualitative SEM data also showed a smooth surface after thermocycling, which supported the statistical findings. Conclusion: After thermocycling, resin-infiltrated enamel surfaces become smoother and had no additional risk for plaque accumulation. PMID:27733877

  19. Detection and attribution of near surface temperature changes over homogenous temperature zones in India

    Science.gov (United States)

    Achutarao, K. M.; R, D.

    2015-12-01

    The IPCC Fifth Assessment Report concluded, "More than half of the observed increase in global mean surface temperature (GMST) from 1951 to 2010 is very likely due to the observed anthropogenic increase in greenhouse gas (GHG) concentrations." Detecting and attributing the changes over regional scales can provide more relevant information to policymakers at the national level but the low signal-to-noise ratios at smaller spatial scales make this a harder problem. In this study, we analyze changes in temperature (annual and seasonal means of mean, minimum, and maximum temperatures) over 7 homogeneous temperature zones of India from 1901 -2005 using models from the CMIP5 database and multiple observational datasets (CRU-3.22, and IITM). We perform Detection and Attribution (D&A) analysis using fingerprint methods by defining a signal that concisely express both spatial and temporal changes found in the model runs with the CMIP5 individual forcing runs; greenhouse (historicalGHG), natural (historicalNat), anthropogenic (historicalAnthro), and anthropogenic aerosols (historicalAA). We are able to detect changes in annual mean temperature over many of the homogenous temperature zones as well as seasonal means in some of the homogenous zones. We quantify the contributions resulting from individual forcings in these cases. Preliminary results indicate large contributions from anthropogenic, forcings with a negligible contribution from natural forcings.

  20. First-principles study on initial stage of oxidation on Si(110) surface

    Energy Technology Data Exchange (ETDEWEB)

    Nagasawa, Takahiro; Shiba, Seiji; Sueoka, Koji [Department of System Engineering, Okayama Prefectural University, 111 Kuboki, Soja, Okayama 719-1197 (Japan)

    2011-03-15

    There is a great deal of engineering interest in Si (110) wafers as the substrates of large scale integrations (LSIs) in the next generation. However, few studies on Si (110) surface have been reported in comparison with those on other low-index surfaces, still less the mechanism of surface oxidation. We analyzed the surface structure and the initial stage of oxidation on the Si (110)-(16 x 2) clean surface with first-principles calculation. The results of our calculations showed that first, the stable structure of the Si (110) clean surface was the adatom-tetramer-interstitial (ATI) reconstruction. Second, pairs of pentagon (PPs) were preferentially oxidized in the initial stage of the oxidation. Third, the oxidation growth should progress with the clustering of O atoms. (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  1. Initial Studies of Low Temperature Ablation in a Helium Hypersonic Wind Tunnel. Draft

    Energy Technology Data Exchange (ETDEWEB)

    Kohlman, D.L.; Elias, L.; Orlik-Ruckemann, K.

    1969-06-15

    A study of the feasibility of investigating the effects of ablation in a helium hypersonic wind tunnel was performed. Exploratory experiments were carried out at Mach 16.4 and at 600 psi stagnation pressure using (a) metal models at room temperature, (b) models with copper inserts, cooled to -140 deg C, and (c) models with carbon dioxide inserts. All models were flat plates at zero incidence, with a sharp leading edge in front of the insert. Surface temperature, surface recession rates and pitot pressure profiles were determined at several longitudinal stations. Suitable model fabrication and experimental techniques have been developed. A simple theoretical method of predicting recession rates and surface temperatures has been proposed. It has been demonstrated that the ablation of carbon dioxide into an unheated Mach 16.4 helium flow at 600 psi stagnation pressure is significant enough to result in measurable flat plate recession rates and measurable changes in pitot pressure profiles. In addition, it has been shown that it is possible to distinguish between the effects on pitot pressure of reduction in surface temperature and of mass addition through sublimation of carbon dioxide. It was also found that the first order theoretical analysis predicts proper trends and correct approximate magnitude of sublimation rates.

  2. Sensitivity of high-temperature weather to initial soil moisture: a case study with the WRF model

    Science.gov (United States)

    Zeng, X.-M.; Wang, B.; Zhang, Y.; Song, S.; Huang, X.; Zheng, Y.; Chen, C.; Wang, G.

    2014-05-01

    Using the Weather Research and Forecasting model (WRF), we investigate the sensitivity of simulated short-range high-temperature weather to initial soil moisture for the East China extremely hot event in late July 2003 via a succession of 24 h simulations. The initial soil moisture (SMOIS) in the Noah land surface scheme is prescribed for five groups of designed simulations, i.e., relative to the control run (CTL), SMOIS is changed by -25, -50, +25 and +50% in the DRY25, DRY50, WET25 and WET50 groups, respectively, with ten 24 h-long integrations performed in each group. We focus on above-35 °C (standard of so-called "high-temperature" event in China) 2 m surface air temperature (SAT) at 06:00 UTC (roughly 12:00 LT in the study domain) to analyze the occurrence of the high-temperature event. Ten-day mean results show that the 06:00 UTC SAT (SAT06) is sensitive to the SMOIS change, i.e., SAT06 exhibits an apparent rising with the SMOIS decrease (e.g., compared with CTL, DRY25 results in a 1 °C SAT06 rising in general over land surface of East China), areas with above-35 °C SAT06 are most affected, and the simulations are found to be more sensitive to the SMOIS decrease than to the SMOIS increase, suggesting that hot weather can be amplified under low soil moisture conditions. With regard to the mechanism of influencing the extreme high SAT06, sensible heat flux shows to directly heat the lower atmosphere, latent heat flux is found to be more sensitive to the SMOIS change and results in the overall increase of surface net radiation due to the increased greenhouse effect (e.g., with the SMOIS increase of 25% from DRY25 to CTL, the ten-day mean net radiation is increased by 5 W m-2), and a negative (positive) feedback is found between regional atmospheric circulation and air temperature in the lower atmosphere (mid-troposphere) due to the unique dynamic nature of the western Pacific subtropical high. Using a method based on an analogous temperature relationship, a

  3. Experimental Study on the Effect of Initial Temperature on CHF in a Vertical Annulus Narrow Channel with Bilateral Heated

    Directory of Open Access Journals (Sweden)

    M. Juarsa

    2011-08-01

    Full Text Available Study on understanding of the complexities of boiling in the narrow channel which was occured in a severe accident on nuclear power plant has been carried out in experimentally using simulation apparatus in order to achieve the safety management capability. Critical Heat Flux (CHF is one important parameter to control heat during transient accident. The methodology of research is an experiment using experiment apparatus called HeaTiNG-01 test section with modifications in the outside pipe using stainless steel material as the reactor vessel wall simulation. Experiments were conducted by heating the heated rod as a simulation of debris until the desired initial temperature by bilateral heated. Then water with a saturation temperature in atmospheric was poured gravitationally into the narrow channel. Data acquisition system recorded temperature changes in transient during the cooling process. The transient temperature profile in double heating surface and rewetting point (rewet fronts was characterized. Experiment was conducted at three initial temperature variations i.e. 650oC, 750oC and 850oC and using channel width 1 mm. Experiment data was used to calculate heat flux then to fitting CHF form boiling curve. The results showed that CHF in outer pipe is higher than heated rod, these conditions explain that more heat is released through the outer pipe, so that the heat control can be done from outside the system to reduce the temperature quickly. The average value of CHF for each vertical position 100 mm and 400 mm at outer pipe are 380 kW/m2 and 733 kW/m2, and then at the heated rod are 250 kW/m2 and 497 kW/m2

  4. An AES Study of the Room Temperature Surface Conditioning of Technological Metal Surfaces by Electron Irradiation

    CERN Document Server

    Scheuerlein, C; Taborelli, M; Brown, A; Baker, M A

    2002-01-01

    The modifications to technological copper and niobium surfaces induced by 2.5 keV electron irradiation have been investigated in the context of the conditioning process occurring in particle accelerator ultra high vacuum systems. Changes in the elemental surface composition have been found using Scanning Auger Microscopy (SAM) by monitoring the carbon, oxygen and metal Auger peak intensities as a function of electron irradiation in the dose range 10-6 to 10-2 C mm-2. The surface analysis results are compared with electron dose dependent secondary electron and electron stimulated desorption yield measurements. Initially the electron irradiation causes a surface cleaning through electron stimulated desorption, in particular of hydrogen. During this period both the electron stimulated desorption and secondary electron yield decrease as a function of electron dose. When the electron dose exceeds 10-4 C mm-2 electron stimulated desorption yields are reduced by several orders of magnitude and the electron beam indu...

  5. Hydrophilization of Poly(ether ether ketone) Films by Surface-initiated Atom Transfer Radical Polymerization

    DEFF Research Database (Denmark)

    Fristrup, Charlotte Juel; Eskimergen, Rüya; Burkrinsky, J.T.

    2008-01-01

    -modified PEEK using Surface-Initiated Atom Transfer Radical Polymerization (SI ATRP). Surface reduction of PEEK to form hydroxyl groups [1, 2, 3] was .performed prior to the attachment of 2-bromoisobutyrate initiating groups. Each modification step of PEEK as well as the polymer grafting was followed...... and confirmed by ATR FTIR, water contact ang;le, and Thermal Gravimetric Analysis (TGA). The surface topography was evaluated by "Atomic Force Microscopy (AFM). X-ray Photoelectron Spectroscopy (XPS) has been used to investigate the degree of functionalization. The performed modification allowed for successful...

  6. Hydrophilization of Poly(ether ether ketone) Films by Surface-initiated Atom Transfer Radical Polymerization

    DEFF Research Database (Denmark)

    Fristrup, Charlotte Juel; Eskimergen, Rüya; Burkrinsky, J.T.

    2008-01-01

    -modified PEEK using Surface-Initiated Atom Transfer Radical Polymerization (SI ATRP). Surface reduction of PEEK to form hydroxyl groups [1, 2, 3] was .performed prior to the attachment of 2-bromoisobutyrate initiating groups. Each modification step of PEEK as well as the polymer grafting was followed...... and confirmed by ATR FTIR, water contact ang;le, and Thermal Gravimetric Analysis (TGA). The surface topography was evaluated by "Atomic Force Microscopy (AFM). X-ray Photoelectron Spectroscopy (XPS) has been used to investigate the degree of functionalization. The performed modification allowed for successful...

  7. Theoretical study of cathode surfaces and high-temperature superconductors

    Science.gov (United States)

    Mueller, Wolfgang

    1995-01-01

    Calculations are presented for the work functions of BaO on W, Os, Pt, and alloys of Re-W, Os-W, and Ir-W that are in excellent agreement with experiment. The observed emission enhancement for alloy relative to tungsten dispenser cathodes is attributed to properties of the substrate crystal structure and explained by the smaller depolarization of the surface dipole on hexagonal as compared to cubic substrates. For Ba and BaO on W(100), the geometry of the adsorbates has been determined by a comparison of inverse photoemission spectra with calculated densities of unoccupied states based on the fully relativistic embedded cluster approach. Results are also discussed for models of scandate cathodes and the electronic structure of oxygen on W(100) at room and elevated temperatures. A detailed comparison is made for the surface electronic structure of the high-temperature superconductor YBa2Cu3O7 as obtained with non-, quasi-, and fully relativistic cluster calculations.

  8. Afforestation in China cools local land surface temperature.

    Science.gov (United States)

    Peng, Shu-Shi; Piao, Shilong; Zeng, Zhenzhong; Ciais, Philippe; Zhou, Liming; Li, Laurent Z X; Myneni, Ranga B; Yin, Yi; Zeng, Hui

    2014-02-25

    China has the largest afforested area in the world (∼62 million hectares in 2008), and these forests are carbon sinks. The climatic effect of these new forests depends on how radiant and turbulent energy fluxes over these plantations modify surface temperature. For instance, a lower albedo may cause warming, which negates the climatic benefits of carbon sequestration. Here, we used satellite measurements of land surface temperature (LST) from planted forests and adjacent grasslands or croplands in China to understand how afforestation affects LST. Afforestation is found to decrease daytime LST by about 1.1 ± 0.5 °C (mean ± 1 SD) and to increase nighttime LST by about 0.2 ± 0.5 °C, on average. The observed daytime cooling is a result of increased evapotranspiration. The nighttime warming is found to increase with latitude and decrease with average rainfall. Afforestation in dry regions therefore leads to net warming, as daytime cooling is offset by nighttime warming. Thus, it is necessary to carefully consider where to plant trees to realize potential climatic benefits in future afforestation projects.

  9. A New Global Climatology of Annual Land Surface Temperature

    Directory of Open Access Journals (Sweden)

    Benjamin Bechtel

    2015-03-01

    Full Text Available Land surface temperature (LST is an important parameter in various fields including hydrology, climatology, and geophysics. Its derivation by thermal infrared remote sensing has long tradition but despite substantial progress there remain limited data availability and challenges like emissivity estimation, atmospheric correction, and cloud contamination. The annual temperature cycle (ATC is a promising approach to ease some of them. The basic idea to fit a model to the ATC and derive annual cycle parameters (ACP has been proposed before but so far not been tested on larger scale. In this study, a new global climatology of annual LST based on daily 1 km MODIS/Terra observations was processed and evaluated. The derived global parameters were robust and free of missing data due to clouds. They allow estimating LST patterns under largely cloud-free conditions at different scales for every day of year and further deliver a measure for its accuracy respectively variability. The parameters generally showed low redundancy and mostly reflected real surface conditions. Important influencing factors included climate, land cover, vegetation phenology, anthropogenic effects, and geology which enable numerous potential applications. The datasets will be available at the CliSAP Integrated Climate Data Center pending additional processing.

  10. MEaSUREs Land Surface Temperature from GOES Satellites

    Science.gov (United States)

    Pinker, Rachel T.; Chen, Wen; Ma, Yingtao; Islam, Tanvir; Borbas, Eva; Hain, Chris; Hulley, Glynn; Hook, Simon

    2017-04-01

    Information on Land Surface Temperature (LST) can be generated from observations made from satellites in low Earth orbit (LEO) such as MODIS and ASTER and by sensors in geostationary Earth orbit (GEO) such as GOES. Under a project titled: "A Unified and Coherent Land Surface Temperature and Emissivity Earth System Data Record for Earth Science" led by Jet Propulsion Laboratory, an effort is underway to develop long term consistent information from both such systems. In this presentation we will describe an effort to derive LST information from GOES satellites. Results will be presented from two approaches: 1) based on regression developed from a wide range of simulations using MODTRAN, SeeBor Version 5.0 global atmospheric profiles and the CAMEL (Combined ASTER and MODIS Emissivity for Land) product based on the standard University of Wisconsin 5 km emissivity values (UWIREMIS) and the ASTER Global Emissivity Database (GED) product; 2) RTTOV radiative transfer model driven with MERRA-2 reanalysis fields. We will present results of evaluation of these two methods against various products, such as MOD11, and ground observations for the five year period of (2004-2008).

  11. A protocol for validating Land Surface Temperature from Sentinel-3

    Science.gov (United States)

    Ghent, D.

    2015-12-01

    One of the main objectives of the Sentinel-3 mission is to measure sea- and land-surface temperature with high-end accuracy and reliability in support of environmental and climate monitoring in an operational context. Calibration and validation are thus key criteria for operationalization within the framework of the Sentinel-3 Mission Performance Centre (S3MPC).Land surface temperature (LST) has a long heritage of satellite observations which have facilitated our understanding of land surface and climate change processes, such as desertification, urbanization, deforestation and land/atmosphere coupling. These observations have been acquired from a variety of satellite instruments on platforms in both low-earth orbit and in geostationary orbit. Retrieval accuracy can be a challenge though; surface emissivities can be highly variable owing to the heterogeneity of the land, and atmospheric effects caused by the presence of aerosols and by water vapour absorption can give a bias to the underlying LST. As such, a rigorous validation is critical in order to assess the quality of the data and the associated uncertainties. The Sentinel-3 Cal-Val Plan for evaluating the level-2 SL_2_LST product builds on an established validation protocol for satellite-based LST. This set of guidelines provides a standardized framework for structuring LST validation activities, and is rapidly gaining international recognition. The protocol introduces a four-pronged approach which can be summarised thus: i) in situ validation where ground-based observations are available; ii) radiance-based validation over sites that are homogeneous in emissivity; iii) intercomparison with retrievals from other satellite sensors; iv) time-series analysis to identify artefacts on an interannual time-scale. This multi-dimensional approach is a necessary requirement for assessing the performance of the LST algorithm for SLSTR which is designed around biome-based coefficients, thus emphasizing the importance of

  12. Sputter deposited bioceramic coatings: surface characterisation and initial protein adsorption studies using surface-MALDI-MS

    DEFF Research Database (Denmark)

    Boyd, A. R.; Burke, G. A.; Duffy, H.

    2011-01-01

    Protein adsorption onto calcium phosphate (Ca–P) bioceramics utilised in hard tissue implant applications has been highlighted as one of the key events that influences the subsequent biological response, in vivo. This work reports on the use of surface-matrix assisted laser desorption ionisation...... to a combination of growth factors and lipoproteins present in serum. From the data obtained here it is evident that surface-MALDI-MS has significant utility as a tool for studying the dynamic nature of protein adsorption onto the surfaces of bioceramic coatings, which most likely plays a significant role...

  13. Surface Wave Speed of Functionally Graded Magneto-Electro-Elastic Materials with Initial Stresses

    Directory of Open Access Journals (Sweden)

    Li Li

    2014-09-01

    Full Text Available The shear surface wave at the free traction surface of half- infinite functionally graded magneto-electro-elastic material with initial stress is investigated. The material parameters are assumed to vary ex- ponentially along the thickness direction, only. The velocity equations of shear surface wave are derived on the electrically or magnetically open circuit and short circuit boundary conditions, based on the equations of motion of the graded magneto-electro-elastic material with the initial stresses and the free traction boundary conditions. The dispersive curves are obtained numerically and the influences of the initial stresses and the material gradient index on the dispersive curves are discussed. The investigation provides a basis for the development of new functionally graded magneto-electro-elastic surface wave devices.

  14. A Preliminary Study of Surface Temperature Cold Bias in COAMPS

    Energy Technology Data Exchange (ETDEWEB)

    Chin, H-N S; Leach, M J; Sugiyama, G A; Aluzzi, F J

    2001-04-27

    It is well recognized that the model predictability is more or less hampered by the imperfect representations of atmospheric state and model physics. Therefore, it is a common problem for any numerical models to exhibit some sorts of biases in the prediction. In this study, the emphasis is focused on the cold bias of surface temperature forecast in Naval Research Laboratory's three-dimensional mesoscale model, COAMPS (Coupled Ocean/Atmosphere Mesoscale Prediction System). Based on the comparison with the ground station data, there were two types of ground temperature cold biases identified in LLNL (Lawrence Livermore National Laboratory) operational forecasts of COAMPS over the California and Nevada regions during the 1999 winter and the 2000 spring. The first type of cold bias appears at high elevation regions covered by snow, and its magnitude can be as large as 30 F - 40 F lower than observed. The second type of cold bias mainly exists in the snow-free clear-sky regions, where the surface temperature is above the freezing point, and its magnitude can be up to 5 F - 10 F lower than observed. These cold biases can affect the low-level stratification, and even the diurnal variation of winds in the mountain regions, and therefore impact the atmospheric dispersion forecast. The main objective of this study is to explore the causes of such cold bias, and to further the improvement of the forecast performance in COAMPS. A series of experiments are performed to gauge the sensitivity of the model forecast due to the physics changes and large-scale data with various horizontal and vertical resolutions.

  15. Reevaluation of mid-Pliocene North Atlantic sea surface temperatures

    Science.gov (United States)

    Robinson, Marci M.; Dowsett, Harry J.; Dwyer, Gary S.; Lawrence, Kira T.

    2008-01-01

    Multiproxy temperature estimation requires careful attention to biological, chemical, physical, temporal, and calibration differences of each proxy and paleothermometry method. We evaluated mid-Pliocene sea surface temperature (SST) estimates from multiple proxies at Deep Sea Drilling Project Holes 552A, 609B, 607, and 606, transecting the North Atlantic Drift. SST estimates derived from faunal assemblages, foraminifer Mg/Ca, and alkenone unsaturation indices showed strong agreement at Holes 552A, 607, and 606 once differences in calibration, depth, and seasonality were addressed. Abundant extinct species and/or an unrecognized productivity signal in the faunal assemblage at Hole 609B resulted in exaggerated faunal-based SST estimates but did not affect alkenone-derived or Mg/Ca–derived estimates. Multiproxy mid-Pliocene North Atlantic SST estimates corroborate previous studies documenting high-latitude mid-Pliocene warmth and refine previous faunal-based estimates affected by environmental factors other than temperature. Multiproxy investigations will aid SST estimation in high-latitude areas sensitive to climate change and currently underrepresented in SST reconstructions.

  16. An AES Study of Initial Oxidation of Ce-La Alloy at Room Temperature and Low Oxygen Pressure

    Institute of Scientific and Technical Information of China (English)

    Yang Jiangrong; Wang Xiaolin; Xiao Hong; Zhou Wei; Jiang Chunli; Lu Lei

    2004-01-01

    Auger Electron Spectroscopy was used to characterize the initial stages of the oxidation of Ce-5% La alloy in an oxygen atmosphere at low pressure( ~ 10-6 Pa) and room temperature after the surface is cleaned by Ar+ ion bombardment.It is shown that exposure of clean cerium to oxygen causes the appearance and development of three new Auger peaks at 97,662 and 676 eV, which steadily grow during oxidation of cerium.Upon oxygen dose less than 20 L,a semi-protective layer of oxide forms on the surface of cerium and its growth follows a logarithmic relationship.With further exposure of oxygen, the oxide film grown in the previous stage becomes thicker and the uptake of oxygen reaches saturation at oxygen exposure of 25 L,and the oxide film mainly consists of Ce2O3.

  17. Retrieving Clear-Sky Surface Skin Temperature for Numerical Weather Prediction Applications from Geostationary Satellite Data

    Directory of Open Access Journals (Sweden)

    Baojuan Shan

    2013-01-01

    Full Text Available Atmospheric models rely on high-accuracy, high-resolution initial radiometric and surface conditions for better short-term meteorological forecasts, as well as improved evaluation of global climate models. Remote sensing of the Earth’s energy budget, particularly with instruments flown on geostationary satellites, allows for near-real-time evaluation of cloud and surface radiation properties. The persistence and coverage of geostationary remote sensing instruments grant the frequent retrieval of near-instantaneous quasi-global skin temperature. Among other cloud and clear-sky retrieval parameters, NASA Langley provides a non-polar, high-resolution land and ocean skin temperature dataset for atmospheric modelers by applying an inverted correlated k-distribution method to clear-pixel values of top-of-atmosphere infrared temperature. The present paper shows that this method yields clear-sky skin temperature values that are, for the most part, within 2 K of measurements from ground-site instruments, like the Southern Great Plains Atmospheric Radiation Measurement (ARM Infrared Thermometer and the National Climatic Data Center Apogee Precision Infrared Thermocouple Sensor. The level of accuracy relative to the ARM site is comparable to that of the Moderate-resolution Imaging Spectroradiometer (MODIS with the benefit of an increased number of daily measurements without added bias or increased error. Additionally, matched comparisons of the high-resolution skin temperature product with MODIS land surface temperature reveal a level of accuracy well within 1 K for both day and night. This confidence will help in characterizing the diurnal and seasonal biases and root-mean-square differences between the retrievals and modeled values from the NASA Goddard Earth Observing System Version 5 (GEOS-5 in preparation for assimilation of the retrievals into GEOS-5. Modelers should find the immediate availability and broad coverage of these skin temperature

  18. Functionalization of nylon membranes via surface-initiated atom-transfer radical polymerization.

    Science.gov (United States)

    Xu, F J; Zhao, J P; Kang, E T; Neoh, K G; Li, J

    2007-07-31

    The ability to manipulate and control the surface properties of nylons is of crucial importance to their widespread applications. In this work, surface-initiated atom-transfer radical polymerization (ATRP) is employed to tailor the functionality of the nylon membrane and pore surfaces in a well-controlled manner. A simple two-step method, involving the activation of surface amide groups with formaldehyde and the reaction of the resulting N-methylol polyamide with 2-bromoisobutyryl bromide, was first developed for the covalent immobilization of ATRP initiators on the nylon membrane and its pore surfaces. Functional polymer brushes of 2-hydroxyethyl methacrylate (HEMA) and poly(ethylene glycol)monomethacrylate (PEGMA) were prepared via surface-initiated ATRP from the nylon membranes. A kinetics study revealed that the chain growth from the membranes was consistent with a "controlled" process. The dormant chain ends of the grafted HEMA polymer (P(HEMA)) and PEGMA polymer (P(PEGMA)) on the nylon membranes could be reactivated for the consecutive surface-initiated ATRP to produce the corresponding nylon membranes functionalized by P(HEMA)-b-P(PEGMA) and P(PEGMA)-b-P(HEMA) diblock copolymer brushes. In addition, membranes with grafted P(HEMA) and P(PEGMA) brushes exhibited good resistance to protein adsorption and fouling under continuous-flow conditions.

  19. Martian Surface Temperature and Spectral Response from the MSL REMS Ground Temperature Sensor

    Science.gov (United States)

    Martin-Torres, Javier; Martínez-Frías, Jesús; Zorzano, María-Paz; Serrano, María; Mendaza, Teresa; Hamilton, Vicky; Sebastián, Eduardo; Armiens, Carlos; Gómez-Elvira, Javier; REMS Team

    2013-04-01

    The Rover Environmental Monitoring Station (REMS) on the Mars Science Laboratory (MSL) offers the opportunity to explore the near surface atmospheric conditions and, in particular will shed new light into the heat budget of the Martian surface. This is important for studies of the atmospheric boundary layer (ABL), as the ground and air temperatures measured directly by REMS control the coupling of the atmosphere with the surface [Zurek et al., 1992]. This coupling is driven by solar insolation. The ABL plays an important role in the general circulation and the local atmospheric dynamics of Mars. One of the REMS sensors, the ground temperature sensor (GTS), provides the data needed to study the thermal inertia properties of the regolith and rocks beneath the MSL rover. The GTS includes thermopile detectors, with infrared bands of 8-14 µm and 16-20 µm [Gómez-Elvira et al., 2012]. These sensors are clustered in a single location on the MSL mast and the 8-14 µm thermopile sounds the surface temperature. The infrared radiation reaching the thermopile is proportional to the emissivity of the surface minerals across these thermal wavelengths. We have developed a radiative transfer retrieval method for the REMS GTS using a database of thermal infrared laboratory spectra of analogue minerals and their mixtures. [Martín Redondo et al. 2009, Martínez-Frías et al. 2012 - FRISER-IRMIX database]. This method will be used to assess the perfomance of the REMS GTS as well as determine, through the error analysis, the surface temperature and emissivity values where MSL is operating. Comparisons with orbiter data will be performed. References Gómez-Elvira et al. [2012], REMS: The Environmental Sensor Suite for the Mars Science Laboratory Rover, Space Science Reviews, Volume 170, Issue 1-4, pp. 583-640. Martín-Redondo et al. [2009] Journal of Environmental Monitoring 11:, pp. 1428-1432. Martínez-Frías et al. [2012] FRISER-IRMIX database http

  20. Plasma Assisted Ignition and Combustion at Low Initial Gas Temperatures: Development of Kinetic Mechanism

    Science.gov (United States)

    2016-10-17

    life time of N2(C 3Πu) is 0.7 ns at the atmospheric pressure and 58 DISTRIBUTION A. Approved for public release: distribution unlimited. 0.12 ns at P...with a heating jacket to keep the 105 DISTRIBUTION A. Approved for public release: distribution unlimited. initial gas temperature between 300 and 700...heating jacket to follow the dynamics of heating, and the third one, mounted into the chamber wall, is used to measure gas temperature before the

  1. Crack initiation at long radial hydrides in Zr-2. 5Nb pressure tube material at elevated temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Choubey, R.; Puls, M.P. (AECL Research, Pinawa, Manitoba (Canada). Whiteshell Labs.)

    1994-05-01

    Crack initiation at hydrides in smooth tensile specimens of Zr-2.5Nb pressure tube material was investigated at elevated temperatures up to 300 C using an acoustic emission (AE) technique. The test specimens contained long, radial hydride platelets. These hydrides have their plate normals oriented in the applied stress direction. Below [approximately]100 C, widespread hydride cracking was initiated at stresses close to the yield stress. An estimate of the hydride's fracture strength from this data yielded a value of [approximately]520 MPa at 100 C. Metallography showed that up to this temperature, cracking occurred along the length of the hydrides. However, at higher temperatures, there was no clear evidence of lengthwise cracking of hydrides, and fewer of the total hydride population fractured during deformation, as indicated by the AE record and the metallography. Moreover, the hydrides showed significant plasticity by-being able to flow along with the matrix material and align themselves parallel to the applied stress direction without fracturing. Near the fracture surface of the specimen, transverse cracking of the flow-reoriented hydrides had occurred at various points along the lengths of the hydrides. These fractures appear to be the result of stresses produced by large plastic strains imposed by the surrounding matrix on the less ductile hydrides.

  2. Eddy-Induced Ekman Pumping from Sea-Surface Temperature and Surface Current Effects

    Science.gov (United States)

    Gaube, P.; Chelton, D. B.; O'Neill, L. W.

    2011-12-01

    Numerous past studies have discussed the biological importance of upwelling of nutrients into the interiors of nonlinear eddies. Such upwelling can occur during the transient stages of formation of cyclones from shoaling of the thermocline. In their mature stages, upwelling can occur from Ekman pumping driven by eddy-induced wind stress curl. Previous investigations of ocean-atmosphere interaction in regions of persistent sea-surface temperature (SST) frontal features have shown that the wind field is locally stronger over warm water and weaker over cold water. Spatial variability of the SST field thus results in a wind stress curl and an associated Ekman pumping in regions of crosswind temperature gradients. It can therefore be anticipated that any SST anomalies associated with eddies can generate Ekman pumping in the eddy interiors. Another mechanism for eddy-induced Ekman pumping is the curl of the stress on the sea surface that arises from the difference between the surface wind velocity and the surface ocean velocity. While SST-induced Ekman upwelling can occur over eddies of either polarity surface current effects on Ekman upwelling occur only over anticyclonic eddies The objective of this study is to determine the spatial structures and relative magnitudes of the two mechanisms for eddy-induced Ekman pumping within the interiors of mesoscale eddies. This is achieved by collocating satellite-based measurements of SST, surface winds and wind stress curl to the interiors of eddies identified and tracked with an automated procedure applied to the sea-surface height (SSH) fields in the Reference Series constructed by AVISO from the combined measurements by two simultaneously operating altimeters. It is shown that, on average, the wind stress curl from eddy-induced surface currents is largest at the eddy center, resulting in Ekman pumping velocities of order 10 cm day-1. While this surface current-induced Ekman pumping depends only weakly on the wind direction

  3. Sensitivity of high-temperature weather to initial soil moisture: a case study using the WRF model

    Science.gov (United States)

    Zeng, X.-M.; Wang, B.; Zhang, Y.; Song, S.; Huang, X.; Zheng, Y.; Chen, C.; Wang, G.

    2014-09-01

    Using a succession of 24 h Weather Research and Forecasting model (WRF) simulations, we investigate the sensitivity to initial soil moisture of a short-range high-temperature weather event that occurred in late July 2003 in East China. The initial soil moisture (SMOIS) in the Noah land surface scheme is adjusted (relative to the control run, CTL) for four groups of simulations: DRY25 (-25%), DRY50 (-50%), WET25 (+25%) and WET50 (+50%). Ten 24 h integrations are performed in each group. We focus on 2 m surface air temperature (SAT) greater than 35 °C (the threshold of "high-temperature" events in China) at 06:00 UTC (roughly 14:00 LT in the study domain) to analyse the occurrence of the high-temperature event. The 10-day mean results show that the 06:00 UTC SAT (SAT06) is sensitive to the SMOIS change; specifically, SAT06 exhibits an apparent increase with the SMOIS decrease (e.g. compared with CTL, DRY25 generally results in a 1 °C SAT06 increase over the land surface of East China), areas with 35 °C or higher SAT06 are the most affected, and the simulations are more sensitive to the SMOIS decrease than to the SMOIS increase, which suggests that hot weather can be amplified under low soil moisture conditions. Regarding the mechanism underlying the extremely high SAT06, sensible heat flux has been shown to directly heat the lower atmosphere, and latent heat flux has been found to be more sensitive to the SMOIS change, resulting in an overall increase in surface net radiation due to the increased greenhouse effect (e.g. with the SMOIS increase from DRY25 to CTL, the 10-day mean net radiation increases by 5 W m-2). Additionally, due to the unique and dynamic nature of the western Pacific subtropical high, negative feedback occurs between the regional atmospheric circulation and the air temperature in the lower atmosphere while positive feedback occurs in the mid-troposphere. Using a method based on an analogous temperature relationship, a detailed analysis of the

  4. Measuring surface temperature of isolated neutron stars and related problems

    Science.gov (United States)

    Teter, Marcus Alton

    New and exciting results for measuring neutron star surface temperatures began with the successful launch of the Chandra X-ray observatory. Among these results are new detections of neutron star surface temperatures which have made it possible to seriously test neutron star thermal evolution theories. The important new temperature determination of the Vela pulsar (Pavlov, et al., 2001a) requires a non-standard cooling scenario to explain it. Apart from this result, we have measured PSR B1055-52's surface temperature in this thesis, determining that it can be explained by standard cooling with heating. Our spectral fit of the combined data from ROSAT and Chandra have shown that a three component model, two thermal blackbodies and an non-thermal power-law, is required to explain the data. Furthermore, our phase resolved spectroscopy has begun to shed light on the geometry of the hot spot on PSR B1055-52's surface as well as the structure of the magnetospheric radiation. Also, there is strong evidence for a thermal distribution over its surface. Most importantly, the fact that PSR B1055-52 does not have a hydrogen atmosphere has been firmly established. To reconcile these two key observations, on the Vela pulsar and PSR B1055-52, we tested neutron star cooling with neutrino processes including the Cooper pair neutrino emission process. Overall, it has been found that a phase change associated with pions being present in the cores of more massive neutron stars explains all current of the data. A transition from neutron matter to pion condensates in the central stellar core explains the difference between standard and non-standard cooling scenarios, because the superfluid suppression of pion cooling will reduce the emissivity of the pion direct URCA process substantially. A neutron star with a mass of [Special characters omitted.] with a medium stiffness equation of state and a T72 type neutron superfluid models the standard cooling case well. A neutron star of [Special

  5. Stratified polymer brushes from microcontact printing of polydopamine initiator on polymer brush surfaces.

    Science.gov (United States)

    Wei, Qiangbing; Yu, Bo; Wang, Xiaolong; Zhou, Feng

    2014-06-01

    Stratified polymer brushes are fabricated using microcontact printing (μCP) of initiator integrated polydopamine (PDOPBr) on polymer brush surfaces and the following surface initiated atom transfer radical polymerization (SI-ATRP). It is found that the surface energy, chemically active groups, and the antifouling ability of the polymer brushes affect transfer efficiency and adhesive stability of the polydopamine film. The stickiness of the PDOPBr pattern on polymer brush surfaces is stable enough to perform continuous μCP and SI-ATRP to prepare stratified polymer brushes with a 3D topography, which have broad applications in cell and protein patterning, biosensors, and hybrid surfaces. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Influence of surface wettability on competitive protein adsorption and initial attachment of osteoblasts

    Energy Technology Data Exchange (ETDEWEB)

    Wei Jianhua; Liu Baolin [Department of Oral and Maxillofacial Surgery, School of Stomatology, Fourth Military Medical University, 145 West Changle Road, Xi' an 710032 (China); Igarashi, Toshio [Department of Oral and Maxillofacial Surgery, Kanagawa Dental College, 82 Inaoka-cho, Yokosuka, Kanagawa 238-8580 (Japan); Okumori, Naoto; Igarashi, Takayasu; Maetani, Takashi [Japan Institute for Advanced Dentistry, 1-8-25 Shiba, Minato-ku, Tokyo 105-0014 (Japan); Yoshinari, Masao, E-mail: yosinari@tdc.ac.j [Division of Oral Implants Research and HRC7, Oral Health Science Center, Tokyo Dental College, 1-2-2 Masago, Mihama-ku, Chiba 261-8502 (Japan)

    2009-08-01

    This study investigated the influence of surface wettability on competitive protein adsorption and the initial attachment of osteoblasts. A thin-film coating of hexamethyldisiloxane (HMDSO) and subsequent O{sub 2}-plasma treatment was carried out on substrates with a mirror surface in order to create a wide range of wettabilities. The adsorption behavior of fibronectin (Fn) and albumin (Alb) in both individual and competitive mode, and the initial attachment of mouse osteoblastic cells (MC3T3-E1) over a wide range of wettabilities were investigated. The contact angle of HMDSO coatings without O{sub 2}-plasma treatment against double-distilled water was more than 100{sup 0}, whereas it dramatically decreased after the O{sub 2}-plasma treatment to almost 0{sup 0}, resulting in super-hydrophilicity. Individually, Fn adsorption showed a biphasic inclination, whereas Alb showed greater adsorption to hydrophobic surfaces. In the competitive mode, in a solution containing both Fn and Alb, Fn showed greater adsorption on hydrophilic surfaces, whereas Alb predominantly adsorbed on hydrophobic surfaces. The initial attachment of osteoblastic cells increased with an increase in surface wettability, in particular, on a super-hydrophilic surface, which correlated well with Fn adsorption in the competitive mode. These results suggest that Fn adsorption may be responsible for increasing cell adhesion on hydrophilic surfaces in a body fluid or culture media under physiological conditions.

  7. High temperature initiation and propagation of cracks in 12%Cr-steel turbine disks

    Directory of Open Access Journals (Sweden)

    S. Foletti

    2013-10-01

    Full Text Available This work aims to study the crack propagation in 12%Cr steel for turbine disks. Creep Crack Growth (CCG tests on CT specimens have been performed to define the proper fracture mechanics which describes the initiation of the crack propagation and the crack growth behaviour for the material at high temperature. Results have been used to study the occurrence of crack initiation on a turbine disk at the extreme working temperature and stress level experienced during service, and validate the use of C* integral in correlating creep growth rate on the disk component, in case C* is numerically calculated through FEM analysis or calculated by the use of reference stress concept.

  8. Deformation and failure of bulk metallic glasses under different initial temperatures

    Directory of Open Access Journals (Sweden)

    Li J.C.

    2015-01-01

    Full Text Available Based on the coupled thermo-mechanical model, a constitutive model for bulk metallic glasses (BMGs, which is generalized to the multi-axial stress state and considers the effects of free volume, heat and hydrostatic stress, has been modified in the present paper. Besides, a failure criterion of critical free volume concentration is introduced based on the coalescence mechanism of free volume. The constitutive model as well as the failure criterion is implemented into the LS-DYNA commercial software by user material subroutine (UMAT. Then FEM simulations for different initial material temperatures are conducted and the evolutions of material parameter as well as corresponding macroscopic mechanical behaviour of material are analyzed. Relative analysis shows that the initial material temperature significantly affects the deformation and failure of material.

  9. Fabrication and Characterization of a Porous Silicon Drug Delivery System with an Initiated Chemical Vapor Deposition Temperature-Responsive Coating.

    Science.gov (United States)

    McInnes, Steven J P; Szili, Endre J; Al-Bataineh, Sameer A; Vasani, Roshan B; Xu, Jingjing; Alf, Mahriah E; Gleason, Karen K; Short, Robert D; Voelcker, Nicolas H

    2016-01-12

    This paper reports on the fabrication of a pSi-based drug delivery system, functionalized with an initiated chemical vapor deposition (iCVD) polymer film, for the sustainable and temperature-dependent delivery of drugs. The devices were prepared by loading biodegradable porous silicon (pSi) with a fluorescent anticancer drug camptothecin (CPT) and coating the surface with temperature-responsive poly(N-isopropylacrylamide-co-diethylene glycol divinyl ether) (pNIPAM-co-DEGDVE) or non-stimulus-responsive poly(aminostyrene) (pAS) via iCVD. CPT released from the uncoated oxidized pSi control with a burst release fashion (∼21 nmol/(cm(2) h)), and this was almost identical at temperatures both above (37 °C) and below (25 °C) the lower critical solution temperature (LCST) of the switchable polymer used, pNIPAM-co-DEGDVE (28.5 °C). In comparison, the burst release rate from the pSi-pNIPAM-co-DEGDVE sample was substantially slower at 6.12 and 9.19 nmol/(cm(2) h) at 25 and 37 °C, respectively. The final amount of CPT released over 16 h was 10% higher at 37 °C compared to 25 °C for pSi coated with pNIPAM-co-DEGDVE (46.29% vs 35.67%), indicating that this material can be used to deliver drugs on-demand at elevated temperatures. pSi coated with pAS also displayed sustainable drug delivery profiles, but these were independent of the release temperature. These data show that sustainable and temperature-responsive delivery systems can be produced by functionalization of pSi with iCVD polymer films. Benefits of the iCVD approach include the application of the iCVD coating after drug loading without causing degradation of the drug commonly caused by exposure to factors such as solvents or high temperatures. Importantly, the iCVD process is applicable to a wide array of surfaces as the process is independent of the surface chemistry and pore size of the nanoporous matrix being coated.

  10. Detecting climate rationality and homogeneities of sea surface temperature data in Longkou marine station using surface air temperature

    Science.gov (United States)

    Li, Yan; Li, Huan; Wang, Qingyuan; Wang, Guosong; Fan, Wenjing

    2017-08-01

    This study presents a systematic evaluation of the climate rationality and homogeneity of monthly sea surface temperature (SST) in Longkou marine station from 1960 to 2011. The reference series are developed using adjacent surface air temperature (SAT) on a monthly timescale. The results suggest SAT as a viable option for use in evaluating climate rationality and homogeneity in the SST data on the coastal China Seas. According to the large-scale atmospheric circulation patterns and SAT of the adjacent meteorological stations, we confirm that there is no climate shift in 1972/1973 and then the climate shift in 1972/1973 is corrected. Besides, the SST time series has serious problems of inhomogeneity. Three documented break points have been checked using penalized maximum T (PMT) test and metadata. The changes in observation instruments and observation system are the main causes of the break points. For the monthly SST time series, the negative adjustments may be greatly due to the SST decreasing after automation. It is found that the increasing trend of annual mean SST after adjustment is higher than before, about 0.24 °C/10 yr.

  11. GHRSST Level 4 ODYSSEA Mediterranean Sea Regional Foundation Sea Surface Temperature Analysis (GDS version 1)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A Group for High Resolution Sea Surface Temperature (GHRSST) Level 4 sea surface temperature analysis produced daily on an operational basis at Ifremer/CERSAT...

  12. Comparison of MTI and Ground Truth Sea Surface Temperatures at Nauru

    Energy Technology Data Exchange (ETDEWEB)

    Kurzeja, R.

    2002-09-05

    This report evaluates MTI-derived surface water temperature near the tropical Pacific island of Nauru. The MTI sea-surface temperatures were determined by the Los Alamos National Laboratory based on the robust retrieval.

  13. GHRSST Level 4 GAMSSA Global Foundation Sea Surface Temperature Analysis (GDS version 1)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A Group for High Resolution Sea Surface Temperature (GHRSST) Level 4 sea surface temperature analysis produced daily on an operational basis at the Australian Bureau...

  14. GHRSST Level 4 RAMSSA Australian Regional Foundation Sea Surface Temperature Analysis (GDS version 1)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A Group for High Resolution Sea Surface Temperature (GHRSST) Level 4 sea surface temperature analysis produced daily on an operational basis at the Australian Bureau...

  15. GHRSST Level 4 EUR Mediterranean Sea Regional Foundation Sea Surface Temperature Analysis (GDS version 2)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A Group for High Resolution Sea Surface Temperature (GHRSST) Level 4 sea surface temperature analysis produced daily by Ifremer/CERSAT (France) using optimal...

  16. GHRSST Level 4 ODYSSEA Global Foundation Sea Surface Temperature Analysis (GDS version 1)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A Group for High Resolution Sea Surface Temperature (GHRSST) Level 4 sea surface temperature analysis produced daily on an operational basis at Ifremer/CERSAT...

  17. GHRSST Level 4 ODYSSEA Eastern Central Pacific Regional Foundation Sea Surface Temperature Analysis (GDS version 1)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A Group for High Resolution Sea Surface Temperature (GHRSST) Level 4 sea surface temperature analysis produced daily on an operational basis at Ifremer/CERSAT...

  18. GHRSST Level 4 G1SST Global Foundation Sea Surface Temperature Analysis (GDS version 1)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A Group for High Resolution Sea Surface Temperature (GHRSST) Level 4 sea surface temperature analysis produced daily on an operational basis by the JPL OurOcean...

  19. GHRSST Level 4 DMI_OI Global Foundation Sea Surface Temperature Analysis (GDS version 2)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A Group for High Resolution Sea Surface Temperature (GHRSST) Level 4 sea surface temperature analysis produced daily on an operational basis by the Danish...

  20. GHRSST Level 4 OSTIA Global Foundation Sea Surface Temperature Analysis (GDS versions 1 and 2)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A Group for High Resolution Sea Surface Temperature (GHRSST) Level 4 sea surface temperature analysis produced daily on an operational basis at the UK Met Office...

  1. GHRSST Level 4 MW_OI Global Foundation Sea Surface Temperature analysis (GDS version 2)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A Group for High Resolution Sea Surface Temperature (GHRSST) global Level 4 sea surface temperature analysis produced daily on a 0.25 degree grid at Remote Sensing...

  2. GHRSST Level 4 MUR North America Regional Foundation Sea Surface Temperature Analysis (GDS version 1)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A Group for High Resolution Sea Surface Temperature (GHRSST) Level 4 sea surface temperature analysis produced as a retrospective dataset at the JPL Physical...

  3. Assessment of surface temperatures of buffalo bulls (Bubalus bubalis) raised under tropical conditions using infrared thermography

    National Research Council Canada - National Science Library

    Barros, D.V; Silva, L.K.X; Kahwage, P.R; Lourenço Júnior, J.B; Sousa, J.S; Silva, A.G.M; Franco, I.M; Martorano, L.G; Garcia, A.R

    2016-01-01

    This paper aimed to evaluate the surface temperatures of buffalo bulls using infrared thermography, considering four distinct anatomical parts over time, and to correlate surface temperatures and thermal comfort indexes...

  4. GHRSST Level 4 OSPO Global Nighttime Foundation Sea Surface Temperature Analysis (GDS version 2)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A Group for High Resolution Sea Surface Temperature (GHRSST) Level 4 sea surface temperature analysis produced daily on an operational basis at the Office of...

  5. GHRSST Level 4 OSPO Global Foundation Sea Surface Temperature Analysis (GDS version 2)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A Group for High Resolution Sea Surface Temperature (GHRSST) Level 4 sea surface temperature analysis produced daily on an operational basis at the Office of...

  6. GHRSST Level 4 AVHRR_AMSR_OI Global Blended Sea Surface Temperature Analysis (GDS version 1)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A Group for High Resolution Sea Surface Temperature (GHRSST) global Level 4 sea surface temperature analysis produced daily on a 0.25 degree grid at the NOAA...

  7. GHRSST Level 4 K10_SST Global 1 meter Sea Surface Temperature Analysis (GDS version 1)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A Group for High Resolution Sea Surface Temperature (GHRSST) Level 4 sea surface temperature analysis produced daily on an operational basis at the Naval...

  8. Initial experimental results of a machine learning-based temperature control system for an RF gun

    CERN Document Server

    Edelen, A L; Milton, S V; Chase, B E; Crawford, D J; Eddy, N; Edstrom, D; Harms, E R; Ruan, J; Santucci, J K; Stabile, P

    2015-01-01

    Colorado State University (CSU) and Fermi National Accelerator Laboratory (Fermilab) have been developing a control system to regulate the resonant frequency of an RF electron gun. As part of this effort, we present initial test results for a benchmark temperature controller that combines a machine learning-based model and a predictive control algorithm. This is part of an on-going effort to develop adaptive, machine learning-based tools specifically to address control challenges found in particle accelerator systems.

  9. The effect of surface modification on initial ice formation on aluminum surfaces

    DEFF Research Database (Denmark)

    Rahimi, Maral; Afshari, Alireza; Fojan, Peter;

    2015-01-01

    One of the most promising energy saving methods in cold climate areas is heat recovery in ventilation system by using air-to-air heat exchangers. However, due to a higher humidity in the exhaust air, there is a risk of ice formation on the heat exchanger fins at subzero temperatures. Since the ma...

  10. Fabrication of nonfouling, bactericidal, and bacteria corpse release multifunctional surface through surface-initiated RAFT polymerization

    Directory of Open Access Journals (Sweden)

    Wang B

    2016-12-01

    Full Text Available Bailiang Wang,1,2 Zi Ye,1 Yihong Tang,1 Yuemei Han,1 Quankui Lin,1,2 Huihua Liu,2 Hao Chen,1,2 Kaihui Nan1,2 1School of Ophthalmology and Optometry, Eye Hospital, Wenzhou Medical University, Wenzhou, 2Wenzhou Institute of Biomaterials and Engineering, Chinese Academy of Sciences, Wenzhou, People’s Republic of China Abstract: Infections after surgery or endophthalmitis are potentially blinding complications caused by bacterial adhesion and subsequent biofilm formation on the intraocular lens. Neither single-function anti-adhesion surface nor contacting killing surface can exhibit ideal antibacterial function. In this work, a novel (2-(dimethylamino-ethyl methacrylate-co-2-methacryloyloxyethyl phosphorylcholine (p (DMAEMA-co-MPC brush was synthesized by “grafting from” method through reversible–addition fragmentation chain transfer polymerization. 1-Bromoheptane was used to quaternize the p (DMAEMA-co-MPC brush coating and to endow the surface with bactericidal function. The success of the surface functionalization was confirmed by atomic force microscopy, water contact angle, and spectroscopic ellipsometry. The quaternary ammonium salt units were employed as efficient disinfection that can eliminate bacteria through contact killing, whereas the 2-methacryloyloxyethyl phosphorylcholine units were introduced to suppress unwanted nonspecific adsorption. The functionalized poly(dimethyl siloxane surfaces showed efficiency in reducing bovine serum albumin adsorption and in inhibiting bacteria adhesion and biofilm formation. The copolymer brushes also demonstrated excellent bactericidal function against gram-positive (Staphylococcus aureus bacteria measured by bacteria live/dead staining and shake-flask culture methods. The surface biocompatibility was evaluated by morphology and activity measurement with human lens epithelial cells in vitro. The achievement of the p (DMAEMA+-co-MPC copolymer brush coating with nonfouling, bactericidal, and

  11. Initial adhesion of Listeria monocytogenes to solid surfaces under liquid flow

    DEFF Research Database (Denmark)

    Szlavik, Julie; Soares Paiva, Dionísio; Mørk, Nils;

    2012-01-01

    strains of L. monocytogenes was investigated under liquid flow at two levels of shear stress on six different surfaces using a flow chamber set-up with microscopy measurements. The surfaces tested were glass and PVC, and glass coated with beef extract, casein, and homogenised and unhomogenised milk....... In addition, the effect of prior environmental stress (5% NaCl, low nutrient availability) on initial adhesion was investigated. The hydrophobicity of the investigated surfaces was determined by contact angle measurements and the surface properties of the investigated L. monocytogenes strains were determined.......001) was observed but not of interactions between surface-shear stress. No correlation between surface hydrophobicity and IAR was observed. Addition of 5% NaCl during propagation resulted in a decrease in IAR whilst propagation in low nutrient media caused an increase indicating a general change in surface...

  12. Estimation of Land Surface Temperature under Cloudy Skies Using Combined Diurnal Solar Radiation and Surface Temperature Evolution

    Directory of Open Access Journals (Sweden)

    Xiaoyu Zhang

    2015-01-01

    Full Text Available Land surface temperature (LST is a key parameter in the interaction of the land-atmosphere system. However, clouds affect the retrieval of LST data from thermal-infrared remote sensing data. Thus, it is important to determine a method for estimating LSTs at times when the sky is overcast. Based on a one-dimensional heat transfer equation and on the evolution of daily temperatures and net shortwave solar radiation (NSSR, a new method for estimating LSTs under cloudy skies (Tcloud from diurnal NSSR and surface temperatures is proposed. Validation is performed against in situ measurements that were obtained at the ChangWu ecosystem experimental station in China. The results show that the root-mean-square error (RMSE between the actual and estimated LSTs is as large as 1.23 K for cloudy data. A sensitivity analysis to the errors in the estimated LST under clear skies (Tclear and in the estimated NSSR reveals that the RMSE of the obtained Tcloud is less than 1.5 K after adding a 0.5 K bias to the actual Tclear and 10 percent NSSR errors to the actual NSSR. Tcloud is estimated by the proposed method using Tclear and NSSR products of MSG-SEVIRI for southern Europe. The results indicate that the new algorithm is practical for retrieving the LST under cloudy sky conditions, although some uncertainty exists. Notably, the approach can only be used during the daytime due to the assumption of the variation in LST caused by variations in insolation. Further, if there are less than six Tclear observations on any given day, the method cannot be used.

  13. Impacts of wind farms on surface air temperatures

    Science.gov (United States)

    Baidya Roy, Somnath; Traiteur, Justin J.

    2010-01-01

    Utility-scale large wind farms are rapidly growing in size and numbers all over the world. Data from a meteorological field campaign show that such wind farms can significantly affect near-surface air temperatures. These effects result from enhanced vertical mixing due to turbulence generated by wind turbine rotors. The impacts of wind farms on local weather can be minimized by changing rotor design or by siting wind farms in regions with high natural turbulence. Using a 25-y-long climate dataset, we identified such regions in the world. Many of these regions, such as the Midwest and Great Plains in the United States, are also rich in wind resources, making them ideal candidates for low-impact wind farms. PMID:20921371

  14. Change point detection of the Persian Gulf sea surface temperature

    Science.gov (United States)

    Shirvani, A.

    2017-01-01

    In this study, the Student's t parametric and Mann-Whitney nonparametric change point models (CPMs) were applied to detect change point in the annual Persian Gulf sea surface temperature anomalies (PGSSTA) time series for the period 1951-2013. The PGSSTA time series, which were serially correlated, were transformed to produce an uncorrelated pre-whitened time series. The pre-whitened PGSSTA time series were utilized as the input file of change point models. Both the applied parametric and nonparametric CPMs estimated the change point in the PGSSTA in 1992. The PGSSTA follow the normal distribution up to 1992 and thereafter, but with a different mean value after year 1992. The estimated slope of linear trend in PGSSTA time series for the period 1951-1992 was negative; however, that was positive after the detected change point. Unlike the PGSSTA, the applied CPMs suggested no change point in the Niño3.4SSTA time series.

  15. Investigation of Sea Surface Temperature (SST) anomalies over Cyprus area

    Science.gov (United States)

    Georgiou, Andreas; Akçit, Nuhcan

    2016-08-01

    The temperature of the sea surface has been identified as an important parameter of the natural environment, governing processes that occur in the upper ocean. This paper focuses on the analysis of the Sea Surface Temperature (SST) anomalies at the greater area of Cyprus. For that, SST data derived from MODerate-resolution Imaging Spectroradiometer (MODIS) instrument on board both Aqua and Terra sun synchronous satellites were used. A four year period was chosen as a first approach to address and describe this phenomenon. Geographical Information Systems (GIS) has been used as an integrated platform of analysis and presentation in addition of the support of MATLAB®. The methodology consists of five steps: (i) Collection of MODIS SST imagery, (ii) Development of the digital geo-database; (iii) Model and run the methodology in GIS as a script; (iv) Calculation of SST anomalies; and (v) Visualization of the results. The SST anomaly values have presented a symmetric distribution over the study area with an increase trend through the years of analysis. The calculated monthly and annual average SST anomalies (ASST) make more obvious this trend, with negative and positive SST changes to be distributed over the study area. In terms of seasons, the same increase trend presented during spring, summer, autumn and winter with 2013 to be the year with maximum ASST observed values. Innovative aspects comprise of straightforward integration and modeling of available tools, providing a versatile platform of analysis and semi-automation of the operation. In addition, the fine resolution maps that extracted from the analysis with a wide spatial coverage, allows the detail representation of SST and ASST respectively in the region.

  16. Two Temperature Magneto-Thermoelasticity with Initial Stress: State Space Formulation

    Directory of Open Access Journals (Sweden)

    Sunita Deswal

    2013-01-01

    Full Text Available Magneto-thermoelastic interactions in an initially stressed isotropic homogeneous elastic half-space with two temperatures are studied using mathematical methods under the purview of the L-S model of linear theory of generalized thermoelasticity. The formalism deals with the state space approach with the purpose of counteracting the difficulties of handling the displacement potential functions. Of specific concern here is the propagation of waves owing to ramp type increase in temperature and load. The medium is considered to be permeated by a uniform magnetic field. The expressions for different field parameters such as displacement, temperature, strain, and stress in the physical domain are obtained by applying a numerical inversion technique. Results of some earlier workers have been deduced from the present formulation. Numerical work is also performed for a suitable material with the aim of illustrating the results.

  17. A study of the coupling relationship between concrete surface temperature and concrete surface emissivity in natural conditions.

    Science.gov (United States)

    Tang, Lin-Ling; Chen, Xiao-Ling; Wang, Jia-Ning; Zhao, Hong-Mei; Huang, Qi-Ting

    2014-07-01

    Land surface emissivity (LSE) has already been recognized as a crucial parameter for the determination of land surface temperature (LST). There is an ill-posed problem for the retrieval of LST and LSE. And laboratory-based emissivity is measured in natural constant conditions, which is limited in the application in thermal remote sensing. To solve the above problems, the coupling of LST and LSE is explored to eliminate temperature effects and improve the accuracy of LES. And then, the estimation accuracy of LST from passive remote sensing images will be improved. For different land surface materials, the coupling of land surface emissivity and land surface temperature is various. This paper focuses on studying concrete surface that is one of the typical man-made materials in urban. First the experiments of measuring concrete surface emissivity and concrete surface temperature in natural conditions are arranged reasonably and the suitable data are selected under ideal atmosphere conductions. Then to improve the determination accuracy of concrete surface emissivity, the algorithm worked on the computer of Fourier Transform Infrared Spectroradiometer (FTIR) has been improved by the most adapted temperature and emissivity separation algorithm. Finally the coupling of concrete surface temperature and concrete surface emissivity is analyzed and the coupling model of concrete surface temperature and concrete surface emissivity is established. The results show that there is a highest correlation coefficient between the second derivative of emissivity spectra and concrete surface temperature, and the correlation coefficient is -0.925 1. The best coupling model is the stepwise regression model, whose determination coefficient (R2) is 0.886. The determination coefficient (R2) is 0.905 and the root mean squares error (RMSE) is 0.292 1 in the validation of the model. The coupling model of concrete surface temperature and concrete surface emissivity under natural conditions

  18. Relationships between substrate, surface characteristics, and vegetation in an initial ecosystem

    Directory of Open Access Journals (Sweden)

    P. Biber

    2013-03-01

    Full Text Available Based on a wide range of empirical data we investigated surface and vegetation dynamics in the artificial initial ecosystem "Chicken Creek" (Lusatia, Germany in the years 2008–2011. We scrutinized three different hypotheses concerning (1 the relations between initial geomorphological and substrate characteristics with surface structure and terrain properties, (2 the effects of the latter on the occurrence of grouped plant species, and (3 vegetation density effects on terrain surface change. Our data comprise annual vegetation monitoring results, terrestrial laser scans twice a year, annual groundwater levels, and initially measured soil characteristics. Using Generalized Linear Models (GLMM and Generalized Additive Mixed Models (GAMM we can mostly confirm our hypotheses, revealing statistically significant relations that partly reflect object or period specific effects but also more general processes which mark the transition from a geo-hydro towards a bio-geo-hydro system, where pure geomorphology or substrate feedbacks are changing into vegetation-substrate feedback processes.

  19. Ocular Surface Temperature in Age-Related Macular Degeneration

    Directory of Open Access Journals (Sweden)

    Andrea Sodi

    2014-01-01

    Full Text Available Background. The aim of this study is to investigate the ocular thermographic profiles in age-related macular degeneration (AMD eyes and age-matched controls to detect possible hemodynamic abnormalities, which could be involved in the pathogenesis of the disease. Methods. 32 eyes with early AMD, 37 eyes with atrophic AMD, 30 eyes affected by untreated neovascular AMD, and 43 eyes with fibrotic AMD were included. The control group consisted of 44 healthy eyes. Exclusion criteria were represented by any other ocular diseases other than AMD, tear film abnormalities, systemic cardiovascular abnormalities, diabetes mellitus, and a body temperature higher than 37.5°C. A total of 186 eyes without pupil dilation were investigated by infrared thermography (FLIR A320. The ocular surface temperature (OST of three ocular points was calculated by means of an image processing technique from the infrared images. Two-sample t-test and one-way analysis of variance (ANOVA test were used for statistical analyses. Results. ANOVA analyses showed no significant differences among AMD groups (P value >0.272. OST in AMD patients was significantly lower than in controls (P>0.05. Conclusions. Considering the possible relationship between ocular blood flow and OST, these findings might support the central role of ischemia in the pathogenesis of AMD.

  20. Retrieval of Temperature and Species Distributions from Multispectral Image Data of Surface Flame Spread in Microgravity

    Science.gov (United States)

    Annen, K. D.; Conant, John A.; Weiland, Karen J.

    2001-01-01

    Weight, size, and power constraints severely limit the ability of researchers to fully characterize temperature and species distributions in microgravity combustion experiments. A powerful diagnostic technique, infrared imaging spectrometry, has the potential to address the need for temperature and species distribution measurements in microgravity experiments. An infrared spectrum imaged along a line-of-sight contains information on the temperature and species distribution in the imaged path. With multiple lines-of-sight and approximate knowledge of the geometry of the combustion flowfield, a three-dimensional distribution of temperature and species can be obtained from one hyperspectral image of a flame. While infrared imaging spectrometers exist for collecting hyperspectral imagery, the remaining challenge is retrieving the temperature and species information from this data. An initial version of an infrared analysis software package, called CAMEO (Combustion Analysis Model et Optimizer), has been developed for retrieving temperature and species distributions from hyperspectral imaging data of combustion flowfields. CAMEO has been applied to the analysis of multispectral imaging data of flame spread over a PMMA surface in microgravity that was acquired in the DARTFire program. In the next section of this paper, a description of CAMEO and its operation is presented, followed by the results of the analysis of microgravity flame spread data.

  1. Effect of Surface Charge on Surface-Initiated Atom Transfer Radical Polymerization from Cellulose Nanocrystals in Aqueous Media.

    Science.gov (United States)

    Zoppe, Justin O; Xu, Xingyu; Känel, Cindy; Orsolini, Paola; Siqueira, Gilberto; Tingaut, Philippe; Zimmermann, Tanja; Klok, Harm-Anton

    2016-04-11

    Cellulose nanocrystals (CNCs) with different charge densities were utilized to examine the role of electrostatic interactions on surface-initiated atom transfer radical polymerization (SI-ATRP) in aqueous media. To this end, growth of hydrophilic uncharged poly(N,N-dimethylacrylamide) (PDMAM) brushes was monitored by electrophoresis, (1)H NMR spectroscopy, and dynamic light scattering (DLS). Molecular weight and polydispersity of PDMAM brushes was determined by GPC analysis of hydrolytically cleaved polymers. Initiator and polymer brush grafting densities, and thus, initiator efficiencies were derived from elemental analysis. Higher initiator efficiency of polymer brush growth was observed for CNCs with higher anionic surface sulfate half-ester group density, but at the expense of high polydispersity caused by inefficient deactivation. PDMAM grafts with number-average molecular weights up to 530 kDa and polydispersity indices interfacial region at the onset of polymerization is proposed. The results presented here could have implications for other substrates that present surface charges and for the assumption that the kinetics of Cu-mediated SI-CRP are analogous to those conducted in solution.

  2. Decadal modulation of global surface temperature by internal climate variability

    Science.gov (United States)

    Dai, Aiguo; Fyfe, John C.; Xie, Shang-Ping; Dai, Xingang

    2015-06-01

    Despite a steady increase in atmospheric greenhouse gases (GHGs), global-mean surface temperature (T) has shown no discernible warming since about 2000, in sharp contrast to model simulations, which on average project strong warming. The recent slowdown in observed surface warming has been attributed to decadal cooling in the tropical Pacific, intensifying trade winds, changes in El Niño activity, increasing volcanic activity and decreasing solar irradiance. Earlier periods of arrested warming have been observed but received much less attention than the recent period, and their causes are poorly understood. Here we analyse observed and model-simulated global T fields to quantify the contributions of internal climate variability (ICV) to decadal changes in global-mean T since 1920. We show that the Interdecadal Pacific Oscillation (IPO) has been associated with large T anomalies over both ocean and land. Combined with another leading mode of ICV, the IPO explains most of the difference between observed and model-simulated rates of decadal change in global-mean T since 1920, and particularly over the so-called `hiatus' period since about 2000. We conclude that ICV, mainly through the IPO, was largely responsible for the recent slowdown, as well as for earlier slowdowns and accelerations in global-mean T since 1920, with preferred spatial patterns different from those associated with GHG-induced warming or aerosol-induced cooling. Recent history suggests that the IPO could reverse course and lead to accelerated global warming in the coming decades.

  3. Inter-annual variability of sea surface temperature, wind speed and sea surface height anomaly over the tropical Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Muraleedharan, P.M.; Pankajakshan, T.; Sathe, P.V.

    have made an attempt to study the annual and inter-annual variability of certain prominent processes occurring over the tropical Indian Ocean. The monthly mean values of Wind Speed (FSU), Sea Surface Temperature (REYNOLDS) and Sea Surface Height Anomaly...

  4. Computer Modeling of Planetary Surface Temperatures in Introductory Astronomy Courses

    Science.gov (United States)

    Barker, Timothy; Goodman, J.

    2013-01-01

    Barker, T., and Goodman, J. C., Wheaton College, Norton, MA Computer modeling is an essential part of astronomical research, and so it is important that students be exposed to its powers and limitations in the first (and, perhaps, only) astronomy course they take in college. Building on the ideas of Walter Robinson (“Modeling Dynamic Systems,” Springer, 2002) we have found that STELLA software (ISEE Systems) allows introductory astronomy students to do sophisticated modeling by the end of two classes of instruction, with no previous experience in computer programming or calculus. STELLA’s graphical interface allows students to visualize systems in terms of “flows” in and out of “stocks,” avoiding the need to invoke differential equations. Linking flows and stocks allows feedback systems to be constructed. Students begin by building an easily understood system: a leaky bucket. This is a simple negative feedback system in which the volume in the bucket (a “stock”) depends on a fixed inflow rate and an outflow that increases in proportion to the volume in the bucket. Students explore how changing inflow rate and feedback parameters affect the steady-state volume and equilibration time of the system. This model is completed within a 50-minute class meeting. In the next class, students are given an analogous but more sophisticated problem: modeling a planetary surface temperature (“stock”) that depends on the “flow” of energy from the Sun, the planetary albedo, the outgoing flow of infrared radiation from the planet’s surface, and the infrared return from the atmosphere. Students then compare their STELLA model equilibrium temperatures to observed planetary temperatures, which agree with model ones for worlds without atmospheres, but give underestimates for planets with atmospheres, thus introducing students to the concept of greenhouse warming. We find that if we give the students part of this model at the start of a 50-minute class they are

  5. Assessing Confidence in Pliocene Sea Surface Temperatures to Evaluate Predictive Models

    Science.gov (United States)

    Dowsett, Harry J.; Robinson, Marci M.; Haywood, Alan M.; Hill, Daniel J.; Dolan, Aisling. M.; Chan, Wing-Le; Abe-Ouchi, Ayako; Chandler, Mark A.; Rosenbloom, Nan A.; Otto-Bliesner, Bette L.; hide

    2012-01-01

    In light of mounting empirical evidence that planetary warming is well underway, the climate research community looks to palaeoclimate research for a ground-truthing measure with which to test the accuracy of future climate simulations. Model experiments that attempt to simulate climates of the past serve to identify both similarities and differences between two climate states and, when compared with simulations run by other models and with geological data, to identify model-specific biases. Uncertainties associated with both the data and the models must be considered in such an exercise. The most recent period of sustained global warmth similar to what is projected for the near future occurred about 3.33.0 million years ago, during the Pliocene epoch. Here, we present Pliocene sea surface temperature data, newly characterized in terms of level of confidence, along with initial experimental results from four climate models. We conclude that, in terms of sea surface temperature, models are in good agreement with estimates of Pliocene sea surface temperature in most regions except the North Atlantic. Our analysis indicates that the discrepancy between the Pliocene proxy data and model simulations in the mid-latitudes of the North Atlantic, where models underestimate warming shown by our highest-confidence data, may provide a new perspective and insight into the predictive abilities of these models in simulating a past warm interval in Earth history.This is important because the Pliocene has a number of parallels to present predictions of late twenty-first century climate.

  6. Assessing confidence in Pliocene sea surface temperatures to evaluate predictive models

    Science.gov (United States)

    Dowsett, Harry J.; Robinson, Marci M.; Haywood, Alan M.; Hill, Daniel J.; Dolan, Aisling M.; Stoll, Danielle K.; Chan, Wing-Le; Abe-Ouchi, Ayako; Chandler, Mark A.; Rosenbloom, Nan A.; Otto-Bliesner, Bette L.; Bragg, Fran J.; Lunt, Daniel J.; Foley, Kevin M.; Riesselman, Christina R.

    2012-01-01

    In light of mounting empirical evidence that planetary warming is well underway, the climate research community looks to palaeoclimate research for a ground-truthing measure with which to test the accuracy of future climate simulations. Model experiments that attempt to simulate climates of the past serve to identify both similarities and differences between two climate states and, when compared with simulations run by other models and with geological data, to identify model-specific biases. Uncertainties associated with both the data and the models must be considered in such an exercise. The most recent period of sustained global warmth similar to what is projected for the near future occurred about 3.3–3.0 million years ago, during the Pliocene epoch. Here, we present Pliocene sea surface temperature data, newly characterized in terms of level of confidence, along with initial experimental results from four climate models. We conclude that, in terms of sea surface temperature, models are in good agreement with estimates of Pliocene sea surface temperature in most regions except the North Atlantic. Our analysis indicates that the discrepancy between the Pliocene proxy data and model simulations in the mid-latitudes of the North Atlantic, where models underestimate warming shown by our highest-confidence data, may provide a new perspective and insight into the predictive abilities of these models in simulating a past warm interval in Earth history. This is important because the Pliocene has a number of parallels to present predictions of late twenty-first century climate.

  7. Surface design of antibody-immobilized thermoresponsive cell culture dishes for recovering intact cells by low-temperature treatment.

    Science.gov (United States)

    Kobayashi, Jun; Hayashi, Masaki; Ohno, Takahiro; Nishi, Masanori; Arisaka, Yoshinori; Matsubara, Yoshinori; Kakidachi, Hiroshi; Akiyama, Yoshikatsu; Yamato, Masayuki; Horii, Akihiro; Okano, Teruo

    2014-11-01

    Antibody-immobilized thermoresponsive poly(N-isopropylacrylamide-co-2-carboxyisopropylacrylamide) [poly(IPAAm-co-CIPAAm)]-grafted cell culture surfaces were designed to enhance both the initial adhesion of weakly adhering cells and the ability of cells to detach in response to low temperature through the regulation of affinity binding between immobilized antibodies and antigens on the cellular surface. Ty-82 cells and neonatal normal human dermal fibroblasts (NHDFs), which express CD90 on the cell surface, adhered to anti-CD90 antibody-immobilized thermoresponsive surfaces at 37°C, a condition at which the grafted thermoresponsive polymer chains shrank. Adherent Ty-82 cells were detached from the surfaces by lowering the temperature to 20°C and applying external forces, such as pipetting, whereas cultured NHDF sheets spontaneously detached themselves from the surface in response to reduced temperature alone. When the temperature was decreased to 20°C, the swelling of grafted thermoresponsive polymer chains weakened the affinity binding between immobilized antibody and antigen on the cells due to the increasing steric hindrance of the polymer chains around the antigen-recognition site of the immobilized antibodies. No contamination was detected on cells harvested from covalently immobilized antibodies on the culture surfaces by low-temperature treatment, whereas a carryover of the antibody and avidin from the avidin-biotin binding surface was observed. Furthermore, the initial adhesion of adipose tissue-derived cells, which adhere weakly to PIPAAm-grafted surfaces, was enhanced on the antibody-immobilized thermoresponsive surfaces.

  8. DNA Polymer Brush Patterning through Photocontrollable Surface-Initiated DNA Hybridization Chain Reaction.

    Science.gov (United States)

    Huang, Fujian; Zhou, Xiang; Yao, Dongbao; Xiao, Shiyan; Liang, Haojun

    2015-11-18

    The fabrication of DNA polymer brushes with spatial resolution onto a solid surface is a crucial step for biochip research and related applications, cell-free gene expression study, and even artificial cell fabrication. Here, for the first time, a DNA polymer brush patterning method is reported based on the photoactivation of an ortho-nitrobenzyl linker-embedded DNA hairpin structure and a subsequent surface-initiated DNA hybridization chain reaction (HCR). Inert DNA hairpins are exposed to ultraviolet light irradiation to generate DNA duplexes with two active sticky ends (toeholds) in a programmable manner. These activated DNA duplexes can initiate DNA HCR to generate multifunctional patterned DNA polymer brushes with complex geometrical shapes. Different multifunctional DNA polymer brush patterns can be fabricated on certain areas of the same solid surface using this method. Moreover, the patterned DNA brush surface can be used to capture target molecules in a desired manner.

  9. Impacts of model initialization on an integrated surface water - groundwater model

    KAUST Repository

    Ajami, Hoori

    2015-04-01

    Integrated hydrologic models characterize catchment responses by coupling the subsurface flow with land surface processes. One of the major areas of uncertainty in such models is the specification of the initial condition and its influence on subsequent simulations. A key challenge in model initialization is that it requires spatially distributed information on model states, groundwater levels and soil moisture, even when such data are not routinely available. Here, the impact of uncertainty in initial condition was explored across a 208 km2 catchment in Denmark using the ParFlow.CLM model. The initialization impact was assessed under two meteorological conditions (wet vs dry) using five depth to water table and soil moisture distributions obtained from various equilibrium states (thermal, root zone, discharge, saturated and unsaturated zone equilibrium) during the model spin-up. Each of these equilibrium states correspond to varying computation times to achieve stability in a particular aspect of the system state. Results identified particular sensitivity in modelled recharge and stream flow to the different initializations, but reduced sensitivity in modelled energy fluxes. Analysis also suggests that to simulate a year that is wetter than the spin-up period, an initialization based on discharge equilibrium is adequate to capture the direction and magnitude of surface water–groundwater exchanges. For a drier or hydrologically similar year to the spin-up period, an initialization based on groundwater equilibrium is required. Variability of monthly subsurface storage changes and discharge bias at the scale of a hydrological event show that the initialization impacts do not diminish as the simulations progress, highlighting the importance of robust and accurate initialization in capturing surface water–groundwater dynamics.

  10. Protein Compatible Polymer Brushes on Polymeric Substrates Prepared by Surface-Initiated Transfer Radica Polymerization

    DEFF Research Database (Denmark)

    Fristrup, Charlotte Juel; Eskimergen, Rüya; Burkrinsky, J.T.

    2008-01-01

    limited. Therefore, a polymer coating containing some of the required properties may expand the use ofpolymers in medical devices. 'The approach was to graft polymer brushes from initiator-functionalized substrates using Surface-Initiated Atom TnlJlsfer Radical Polymerization (SI ATRP). Initial studies......Materials for insulin containers and delivery systems should comply with requirements like compatibility with proteins, sterilisability, 'good barrier properties towards preservatives, and no toxic leachables. The number of commercially available polymer materials which can be u sed is rather...

  11. NOAA Climate Data Record (CDR) of Sea Surface Temperature -WHOI, Version 1.0

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The NOAA Ocean Surface Bundle (OSB) Climate Data Record (CDR) consist of three parts: sea surface temperature, near-surface atmospheric properties, and heat fluxes....

  12. Transient heat transfer behavior of water spray evaporative cooling on a stainless steel cylinder with structured surface for safety design application in high temperature scenario

    Science.gov (United States)

    Aamir, Muhammad; Liao, Qiang; Hong, Wang; Xun, Zhu; Song, Sihong; Sajid, Muhammad

    2017-02-01

    High heat transfer performance of spray cooling on structured surface might be an additional measure to increase the safety of an installation against any threat caused by rapid increase in the temperature. The purpose of present experimental study is to explore heat transfer performance of structured surface under different spray conditions and surface temperatures. Two cylindrical stainless steel samples were used, one with pyramid pins structured surface and other with smooth surface. Surface heat flux of 3.60, 3.46, 3.93 and 4.91 MW/m2 are estimated for sample initial average temperature of 600, 700, 800 and 900 °C, respectively for an inlet pressure of 1.0 MPa. A maximum cooling rate of 507 °C/s was estimated for an inlet pressure of 0.7 MPa at 900 °C for structured surface while for smooth surface maximum cooling rate of 356 °C/s was attained at 1.0 MPa for 700 °C. Structured surface performed better to exchange heat during spray cooling at initial sample temperature of 900 °C with a relative increase in surface heat flux by factor of 1.9, 1.56, 1.66 and 1.74 relative to smooth surface, for inlet pressure of 0.4, 0.7, 1.0 and 1.3 MPa, respectively. For smooth surface, a decreasing trend in estimated heat flux is observed, when initial sample temperature was increased from 600 to 900 °C. Temperature-based function specification method was utilized to estimate surface heat flux and surface temperature. Limited published work is available about the application of structured surface spray cooling techniques for safety of stainless steel structures at very high temperature scenario such as nuclear safety vessel and liquid natural gas storage tanks.

  13. Transient heat transfer behavior of water spray evaporative cooling on a stainless steel cylinder with structured surface for safety design application in high temperature scenario

    Science.gov (United States)

    Aamir, Muhammad; Liao, Qiang; Hong, Wang; Xun, Zhu; Song, Sihong; Sajid, Muhammad

    2016-05-01

    High heat transfer performance of spray cooling on structured surface might be an additional measure to increase the safety of an installation against any threat caused by rapid increase in the temperature. The purpose of present experimental study is to explore heat transfer performance of structured surface under different spray conditions and surface temperatures. Two cylindrical stainless steel samples were used, one with pyramid pins structured surface and other with smooth surface. Surface heat flux of 3.60, 3.46, 3.93 and 4.91 MW/m2 are estimated for sample initial average temperature of 600, 700, 800 and 900 °C, respectively for an inlet pressure of 1.0 MPa. A maximum cooling rate of 507 °C/s was estimated for an inlet pressure of 0.7 MPa at 900 °C for structured surface while for smooth surface maximum cooling rate of 356 °C/s was attained at 1.0 MPa for 700 °C. Structured surface performed better to exchange heat during spray cooling at initial sample temperature of 900 °C with a relative increase in surface heat flux by factor of 1.9, 1.56, 1.66 and 1.74 relative to smooth surface, for inlet pressure of 0.4, 0.7, 1.0 and 1.3 MPa, respectively. For smooth surface, a decreasing trend in estimated heat flux is observed, when initial sample temperature was increased from 600 to 900 °C. Temperature-based function specification method was utilized to estimate surface heat flux and surface temperature. Limited published work is available about the application of structured surface spray cooling techniques for safety of stainless steel structures at very high temperature scenario such as nuclear safety vessel and liquid natural gas storage tanks.

  14. Surface temperature evolution and the location of maximum and average surface temperature of a lithium-ion pouch cell under variable load profiles

    DEFF Research Database (Denmark)

    Goutam, Shovon; Timmermans, Jean-Marc; Omar, Noshin;

    2014-01-01

    , manganese and cobalt (NMC) based and the anode is graphite based. In order to measure the surface temperature, thermal infrared (IR) camera and contact thermocouples were used. A fairly uniform temperature distribution was observed over the cell surface in case of continuous charge and discharge up to 100A...

  15. HEAT TREATMENTS OF HIGH TEMPERATURE DRIED NORWAY SPRUCE BOARDS: SACCHARIDES AND FURFURALS IN SAPWOOD SURFACES

    Directory of Open Access Journals (Sweden)

    Olov Karlsson,

    2012-02-01

    Full Text Available Carbohydrates that migrate to wood surfaces in sapwood during drying might influence properties such as mould susceptibility and colour. Sugars on the surface of Norway spruce boards during various heat treatments were studied. Samples (350mmx125mmx25mm were double-stacked, facing sapwood-side outwards, and dried at 110oC to a target moisture content (MC of 40%. Dried sub-samples (80 mm x 125 mm x 25 mm were stacked in a similar way and further heated at 110oC and at 130oC for 12, 24, and 36 hours, respectively. Glucose, fructose, and sucrose as well as 5-hydroxymethylfurfural (HMF and furfural in the sapwood surface layer of treated wood were analysed using HPLC (RI- and UV-detectors. Carbohydrates degraded to a lower extent at 110oC than at 130oC. Furfural and to a larger extent HMF increased with treatment period and temperature. Heat treatment led to a decrease in lightness and hue of the sapwood surface of sub-samples, while chroma increased somewhat. Furthermore, considerably faster degradation (within a few minutes of the carbohydrates on the surface of the dried spruce boards was observed when single sub-samples were conductively hot pressed at 200oC. Treatment period and initial MC influenced the presence of the carbohydrates in wood surface as well as colour change (Eab of the hot pressed sub-samples.

  16. Using distributed temperature sensing to monitor field scale dynamics of ground surface temperature and related substrate heat flux

    NARCIS (Netherlands)

    Bense, V.F.; Read, T.; Verhoef, A.

    2016-01-01

    We present one of the first studies of the use of distributed temperature sensing (DTS) along fibre-optic cables to purposely monitor spatial and temporal variations in ground surface temperature (GST) and soil temperature, and provide an estimate of the heat flux at the base of the canopy layer

  17. Evidence for an initiation of the methanol-to-olefin process by reactive surface methoxy groups on acidic zeolite catalysts.

    Science.gov (United States)

    Wang, Wei; Buchholz, Andreas; Seiler, Michael; Hunger, Michael

    2003-12-10

    Recent progress reveals that, in the methanol-to-olefin (MTO) process on acidic zeolites, the conversion of an equilibrium mixture of methanol and DME is dominated by a "hydrocarbon pool" mechanism. However, the initial C-C bond formation, that is, the chemistry during the kinetic "induction period" leading to the reactive hydrocarbon pool, still remains unclear. With the application of a stopped-flow protocol, in the present work, pure surface methoxy groups [SiO(CH(3))Al] were prepared on various acidic zeolite catalysts (H-Y, H-ZSM-5, H-SAPO-34) at temperatures lower than 473 K, and the further reaction of these methoxy species was investigated by in situ (13)C MAS NMR spectroscopy. By using toluene and cyclohexane as probe molecules which are possibly involved in the MTO process, we show the high reactivity of surface methoxy species. Most importantly, the formation of hydrocarbons from pure methoxy species alone is demonstrated for the first time. It was found that (i) surface methoxy species react at room temperature with water to methanol, indicating the occurrence of a chemical equilibrium between these species at low temperatures. In the presence of aromatics and alkanes, (ii) the reactivity of surface methoxy groups allows a methylation of these organic compounds at reaction temperatures of ca. 433 and 493 K, respectively. In the absence of water and other organic species, that is, under flow conditions and on partially methylated catalysts, (iii) a conversion of pure methoxy groups alone to hydrocarbons was observed at temperatures of T >/= 523 K. This finding indicates a possible formation of the first hydrocarbons during the kinetic induction period of the MTO process via the conversion of pure surface methoxy species (case iii). After the first hydrocarbons are formed, or in the presence of a small amount of organic impurities, surface methoxy groups contribute to a further methylation of these organic compounds (case ii), leading to the formation of

  18. The impact of built-up surfaces on land surface temperatures in Italian urban areas.

    Science.gov (United States)

    Morabito, Marco; Crisci, Alfonso; Messeri, Alessandro; Orlandini, Simone; Raschi, Antonio; Maracchi, Giampiero; Munafò, Michele

    2016-05-01

    Urban areas are characterized by the very high degree of soil sealing and continuous built-up areas: Italy is one of the European countries with the highest artificial land cover rate, which causes a substantial spatial variation in the land surface temperature (LST), modifying the urban microclimate and contributing to the urban heat island effect. Nevertheless, quantitative data regarding the contribution of different densities of built-up surfaces in determining urban spatial LST changes is currently lacking in Italy. This study, which aimed to provide clear and quantitative city-specific information on annual and seasonal spatial LST modifications resulting from increased urban built-up coverage, was conducted generally throughout the whole year, and specifically in two different periods (cool/cold and warm/hot periods). Four cities (Milan, Rome, Bologna and Florence) were included in the study. The LST layer and the built-up-surface indicator were obtained via use of MODIS remote sensing data products (1km) and a very high-resolution map (5m) of built-up surfaces recently developed by the Italian National Institute for Environmental Protection and Research. The relationships between the dependent (mean daily, daytime and nighttime LST values) and independent (built-up surfaces) variables were investigated through linear regression analyses, and comprehensive built-up-surface-related LST maps were also developed. Statistically significant linear relationships (pcities studied, with a higher impact during the warm/hot period than in the cool/cold ones. Daytime and nighttime LST slope patterns depend on the city size and relative urban morphology. If implemented in the existing city plan, the urban maps of built-up-surface-related LST developed in this study might be able to support more sustainable urban land management practices by identifying the critical areas (Hot-Spots) that would benefit most from mitigation actions by local authorities, land-use decision

  19. Spatial pattern of impervious surfaces and their impacts on land surface temperature in Beijing, China

    Institute of Scientific and Technical Information of China (English)

    XIAO Rong-bo; OUYANG Zhi-yun; ZHENG Hua; LI Wei-feng; SCHIENKE Erich W; WANG Xiao-ke

    2007-01-01

    Land surface temperature (LST), which is heavily influenced by urban surface structures, is a significant parameter in urban environmental analysis. This study examined the effect impervious surfaces (IS) spatial patterns have on LST in Beijing, China. A classification and regression tree model (CART) was adopted to estimate IS as a continuous variable using Landsat images from two seasons combined with QuickBird. LST was retrieved from the Landsat Thematic Mapper (TM) image to examine the relationships between IS and LST. The results revealed that CART was capable of consistently predicting LST with acceptable accuracy (correlation coefficient of 0.94 and the average error of 8.59%). Spatial patterns of IS exhibited changing gradients across the various urban-rural transects, with LST values showing a concentric shape that increased as you moved from the outskirts towards the downtown areas.Transect analysis also indicated that the changes in both IS and LST patterns were similar at various resolution levels, which suggests a distinct linear relationship between them. Results of correlation analysis further showed that IS tended to be positively correlated with LST, and that the correlation coefficients increased from 0.807 to 0.925 with increases in IS pixel size. The findings identified in this study provide a theoretical basis for improving urban planning efforts to lessen urban temperatures and thus dampen urban heat island effects.

  20. The EUSTACE project: delivering global, daily information on surface air temperature

    Science.gov (United States)

    Rayner, Nick

    2017-04-01

    Day-to-day variations in surface air temperature affect society in many ways; however, daily surface air temperature measurements are not available everywhere. A global daily analysis cannot be achieved with measurements made in situ alone, so incorporation of satellite retrievals is needed. To achieve this, in the EUSTACE project (2015-June 2018, https://www.eustaceproject.eu) we are developing an understanding of the relationships between traditional (land and marine) surface air temperature measurements and retrievals of surface skin temperature from satellite measurements, i.e. Land Surface Temperature, Ice Surface Temperature, Sea Surface Temperature and Lake Surface Water Temperature. Here we discuss the science needed to produce a fully-global daily analysis (or ensemble of analyses) of surface air temperature on the centennial scale, integrating different ground-based and satellite-borne data types. Information contained in the satellite retrievals is used to create globally-complete fields in the past, using statistical models of how surface air temperature varies in a connected way from place to place. As the data volumes involved are considerable, such work needs to include development of new "Big Data" analysis methods. We will present recent progress along this road in the EUSTACE project: 1. providing new, consistent, multi-component estimates of uncertainty in surface skin temperature retrievals from satellites; 2. identifying inhomogeneities in daily surface air temperature measurement series from weather stations and correcting for these over Europe; 3. estimating surface air temperature over all surfaces of Earth from surface skin temperature retrievals; 4. using new statistical techniques to provide information on higher spatial and temporal scales than currently available, making optimum use of information in data-rich eras. Information will also be given on how interested users can become involved.

  1. The EUSTACE project: delivering global, daily information on surface air temperature

    Science.gov (United States)

    Morice, C. P.; Rayner, N. A.; Auchmann, R.; Bessembinder, J.; Bronnimann, S.; Brugnara, Y.; Conway, E. A.; Ghent, D.; Good, E.; Herring, K.; Kennedy, J.; Lindgren, F.; Madsen, K. S.; Merchant, C. J.; van der Schrier, G.; Stephens, A.; Tonboe, R. T.; Waterfall, A. M.; Mitchelson, J.; Woolway, I.

    2015-12-01

    Day-to-day variations in surface air temperature affect society in many ways; however, daily surface air temperature measurements are not available everywhere. A global daily analysis cannot be achieved with measurements made in situ alone, so incorporation of satellite retrievals is needed. To achieve this, we must develop an understanding of the relationships between traditional (land and marine) surface air temperature measurements and retrievals of surface skin temperature from satellite measurements, i.e. Land Surface Temperature, Ice Surface Temperature, Sea Surface Temperature and Lake Surface Water Temperature. These relationships can be derived either empirically or with the help of a physical model.Here we discuss the science needed to produce a fully-global daily analysis (or ensemble of analyses) of surface air temperature on the centennial scale, integrating different ground-based and satellite-borne data types. Information contained in the satellite retrievals would be used to create globally-complete fields in the past, using statistical models of how surface air temperature varies in a connected way from place to place. As the data volumes involved are considerable, such work needs to include development of new "Big Data" analysis methods.We will present plans and progress along this road in the EUSTACE project (2015-June 2018), i.e.: • providing new, consistent, multi-component estimates of uncertainty in surface skin temperature retrievals from satellites; • identifying inhomogeneities in daily surface air temperature measurement series from weather stations and correcting for these over Europe; • estimating surface air temperature over all surfaces of Earth from surface skin temperature retrievals; • using new statistical techniques to provide information on higher spatial and temporal scales than currently available, making optimum use of information in data-rich eras.Information will also be given on how interested users can become

  2. Initial stages of growth and the influence of temperature during chemical vapor deposition of sp{sup 2}-BN films

    Energy Technology Data Exchange (ETDEWEB)

    Chubarov, Mikhail; Pedersen, Henrik; Högberg, Hans; Henry, Anne, E-mail: anne.henry@liu.se [Department of Physics, Chemistry and Biology, Linköping University, SE-581 83 Linköping (Sweden); Czigány, Zsolt [Institute of Technical Physics and Materials Science, Centre for Energy Research of Hungarian Academy of Sciences, Konkoly-Thege Miklós út 29-33, H-1121 Budapest (Hungary)

    2015-11-15

    Knowledge of the structural evolution of thin films, starting by the initial stages of growth, is important to control the quality and properties of the film. The authors present a study on the initial stages of growth and the temperature influence on the structural evolution of sp{sup 2} hybridized boron nitride (BN) thin films during chemical vapor deposition (CVD) with triethyl boron and ammonia as precursors. Nucleation of hexagonal BN (h-BN) occurs at 1200 °C on α-Al{sub 2}O{sub 3} with an AlN buffer layer (AlN/α-Al{sub 2}O{sub 3}). At 1500 °C, h-BN grows with a layer-by-layer growth mode on AlN/α-Al{sub 2}O{sub 3} up to ∼4 nm after which the film structure changes to rhombohedral BN (r-BN). Then, r-BN growth proceeds with a mixed layer-by-layer and island growth mode. h-BN does not grow on 6H-SiC substrates; instead, r-BN nucleates and grows directly with a mixed layer-by-layer and island growth mode. These differences may be caused by differences in substrate surface temperature due to different thermal conductivities of the substrate materials. These results add to the understanding of the growth process of sp{sup 2}-BN employing CVD.

  3. The influence of surface effect on vibration behaviors of carbon nanotubes under initial stress

    Science.gov (United States)

    Chen, X.; Fang, C. Q.; Wang, X.

    2017-01-01

    An analytical method is presented to solve the influence of surface effect on non-coaxial resonance of multi-walled carbon nanotubes embedded in matrix utilizing laminated structures model. Due to coupled van der Waals forces between adjacent tubes and surface effect exerted carbon nanotubes, the resonance frequencies and amplitude ratios of multi-walled carbon nanotubes under initial stresses show that the resonant characteristics of the multi-walled carbon nanotubes become complex and the numbers of vibrational modes do not keep increase under identical conditions after considering surface effects. The result obtained can be used as a beneficial reference for investigating the electronic and physical behaviors of carbon nanotubes.

  4. Long-term surface temperature modeling of Pluto

    Science.gov (United States)

    Earle, Alissa M.; Binzel, Richard P.; Young, Leslie A.; Stern, S. A.; Ennico, K.; Grundy, W.; Olkin, C. B.; Weaver, H. A.

    2017-05-01

    NASA's New Horizons' reconnaissance of the Pluto system has revealed at high resolution the striking albedo contrasts from polar to equatorial latitudes on Pluto, as well as the sharpness of boundaries for longitudinal variations. These contrasts suggest that Pluto must undergo dynamic evolution that drives the redistribution of volatiles. Using the New Horizons results as a template, we explore the surface temperature variations driven seasonally on Pluto considering multiple timescales. These timescales include the current orbit (248 years) as well as the timescales for obliquity precession (peak-to-peak amplitude of 23° over 3 million years) and regression of the orbital longitude of perihelion (3.7 million years). These orbital variations create epochs of ;Extreme Seasons; where one pole receives a short, relatively warm summer and long winter, while the other receives a much longer, but less intense summer and short winter. We use thermal modeling to build upon the long-term insolation history model described by Earle and Binzel (2015) and investigate how these seasons couple with Pluto's albedo contrasts to create temperature effects. From this study we find that a bright region at the equator, once established, can become a site for net deposition. We see the region informally known as Sputnik Planitia as an example of this, and find it will be able to perpetuate itself as an ;always available; cold trap, thus having the potential to survive on million year or substantially longer timescales. Meanwhile darker, low-albedo, regions near the equator will remain relative warm and generally not attract volatile deposition. We argue that the equatorial region is a ;preservation zone; for whatever albedo is seeded there. This offers insight as to why the equatorial band of Pluto displays the planet's greatest albedo contrasts.

  5. High-temperature vesuvianite: crystal chemistry and surface considerations

    Science.gov (United States)

    Elmi, Chiara; Brigatti, Maria Franca; Pasquali, Luca; Montecchi, Monica; Laurora, Angela; Malferrari, Daniele; Nannarone, Stefano

    2011-06-01

    A multi-methodical approach has been applied for characterizing the bulk and surface crystal chemical features of a high-temperature vesuvianite crystal from skarns of Mount Somma-Vesuvius Volcano (Naples, Italy). Vesuvianite belongs to the space group P4/ nnc with unit cell parameters a = 15.633(1) Å, c = 11.834(1) Å and chemical formula (Ca18.858 Na0.028 Ba0.004 K0.006 Sr0.005 □0.098)19.000 (Al8.813 Ti0.037 Mg2.954 Mn0.008 Fe{0.114/2+} Fe{1.375/3+} Cr0.008 B0.202)13.511 Si18.000(O0.261 F0.940 OH7.799)9.000. Structure refinement, which converges at R = 0.0328, demonstrates a strong positional disorder down the fourfold axes, indicating that the Y1 site is split into two positions (Y1A and Y1B) alternatively occupied. However, because of X4 proximity to Y1B and Y1A, X4 cannot be occupied if Y1B or Y1A are. Overall Y1 occupancy (Y1A + Y1B) reaches approximately 0.5, as common in vesuvianite and occupancy of Y1B site is extremely limited. Moreover, T1 position, limitedly occupied, accommodates the excess of cations generally related to Y position. A small quantity (0.202 apfu) of boron is sited at the T2 site that, like T1, is poorly occupied. The determination of the amount of each element on the (100) vesuvianite surface, obtained through X-ray photoelectron spectroscopy high-resolution spectra in the region of the Si2p, Al2p, Mg1s, and Ca2p core levels, evidences that a greater amount of aluminum and a smaller amount of calcium characterize the surface with respect to the bulk. Although both of these features require further investigation, we may consider the Al increase can be related to preferential orientation of Al-rich sites on the (100) plane. Furthermore, the surface structure of vesuvianite suggests that Al, Ca, and Mg cations maintain coordination features at the surface similar to the bulk. Silica, however, while presenting fourfold coordination, shows also a [1]-fold small coordinated component at binding energy 99.85 eV, due to broken Si-O bonds at

  6. "Living" free radical photopolymerization initiated from surface-grafted iniferter monolayers

    NARCIS (Netherlands)

    de Boer, B.; Simon, H.K.; Werts, M.P L; van der Vegte, E.W.; Hadziioannou, G

    2000-01-01

    A method for chemically modifying a surface with grafted monolayers of initiator groups, which can be used for a "living" free radical photopolymerization, is described. By using "living" free radical polymerizations, we were able to control the length of the grafted polymer chains and therefore the

  7. Polymer coating comprising 2-methoxyethyl acrylate units synthesized by surface-initiated atom transfer radical polymerization

    DEFF Research Database (Denmark)

    2011-01-01

    Source: US2012184029A The present invention relates to preparation of a polymer coating comprising or consisting of polymer chains comprising or consisting of units of 2-methoxyethyl acrylate synthesized by Surface-Initiated Atom Transfer Radical Polymerization (SI ATRP) such as ARGET SI ATRP...... or AGET SI ATRP and uses of said polymer coating....

  8. Surface-Initiated Atom Transfer Radical Polymerization from Electrospun Mats: An Alternative to Nafion

    DEFF Research Database (Denmark)

    Javakhishvili, Irakli; Dimitrov, Ivaylo; Tynelius, Oskar

    2017-01-01

    Proton exchange membranes for fuel cell applications are synthesized by surface-initiated(SI) atom transfer radical polymerization (ATRP). Poly(vinylidene fluoride-co-chlorotrifluoroethylene)is electrospun into 50 μm thick mat, which is then employed as multifunctionalinitiator for copper...

  9. A fatigue crack initiation model incorporating discrete dislocation plasticity and surface roughness

    NARCIS (Netherlands)

    Brinckmann, Steffen; Van der Giessen, Erik

    2007-01-01

    Although a thorough understanding of fatigue crack initiation is lacking, experiments have shown that the evolution of distinct dislocation distributions and surface roughness are key ingredients. In the present study we introduce a computational framework that ties together dislocation dynamics, th

  10. Late-Time Mixing Sensitivity to Initial Broadband Surface Roughness in High-Energy-Density Shear Layers

    Energy Technology Data Exchange (ETDEWEB)

    Flippo, K. A.; Doss, F. W.; Kline, J. L.; Merritt, E. C.; Capelli, D.; Cardenas, T.; DeVolder, B.; Fierro, F.; Huntington, C. M.; Kot, L.; Loomis, E. N.; MacLaren, S. A.; Murphy, T. J.; Nagel, S. R.; Perry, T. S.; Randolph, R. B.; Rivera, G.; Schmidt, D. W.

    2016-11-23

    Using a large volume high-energy-density fluid shear experiment (8.5 cm3) at the National Ignition Facility, we have demonstrated for the first time the ability to significantly alter the evolution of a supersonic sheared mixing layer by controlling the initial conditions of that layer. By altering the initial surface roughness of the tracer foil, we demonstrate the ability to transition the shear mixing layer from a highly ordered system of coherent structures to a randomly ordered system with a faster growing mix layer, indicative of strong mixing in the layer at a temperature of several tens of electron volts and at near solid density. Simulations using a turbulent-mix model show good agreement with the experimental results and poor agreement without turbulent mix.

  11. Enhanced protein retention on poly(caprolactone) via surface initiated polymerization of acrylamide

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Yuhao; Cai, Mengtan; He, Liu [College of Polymer Science and Engineering, Sichuan University, Chengdu 610065 (China); Luo, Xianglin, E-mail: luoxl@scu.edu.cn [College of Polymer Science and Engineering, Sichuan University, Chengdu 610065 (China); State Key Laboratory of Polymer Material and Engineering, Sichuan University, Chengdu 610065 (China)

    2016-01-01

    Graphical abstract: - Highlights: • Dense package of poly(acrylamide) on poly(caprolactone) surface was achieved by surface-initiated atom transfer radical polymerization. • Poly(acrylamide) grafted surface exhibited high protein retention ability. • Loaded protein was resistant to detachment and maintained its structure without denaturation. - Abstract: To enhance the biocompatibility or extend the biomedical application of poly(caprolactone) (PCL), protein retention on PCL surface is often required. In this study, poly(acrylamide) (PAAm) brushes were grown from PCL surface via surface-initiated atom transfer radical polymerization (SI-ATRP) and served as a protein-capturing platform. Grafted PAAm was densely packed on surface and exhibited superior protein retention ability. Captured protein was found to be resistant to washing under detergent environment. Furthermore, protein structure after being captured was investigated by circular dichroism (CD) spectroscopy, and the CD spectra verified that secondary structure of captured proteins was maintained, indicating no denaturation of protein happened for retention process.

  12. Can you help create the next generation of Land Surface Air Temperature products?

    Science.gov (United States)

    Thorne, Peter; Venema, Victor

    2013-04-01

    The International Surface Temperature Initiative comprises a group of multi-disciplinary researchers constituted in 2010 with the remit of creating a suite of open, transparent Land Surface Air Temperature products suitable for meeting 21st Century science and societal needs and expectations. Since instigation significant progress has been made in the creation of an improved set of 'raw' Land Surface Air Temperature data holdings (to be released in first version in February 2013), constituting in excess of 30,000 stations many going back over a Century, and towards the creation of a rigorous benchmarking framework. What is now requested is that multiple independent groups take up the challenge of creating global and regional products from the databank and submit their algorithms to the benchmarking framework. Key here is to rigorously assess structural uncertainty - it is not sufficient to assume because one group has tackled the problem it is in any meaningful sense mission accomplished. There undoubtedly exist a myriad of issues in the raw data and it is of vital importance to see how sensitive data homogenization is to the set of processing choices independent groups will undertake. This uncertainty will almost certainly be larger at the station or regional level - yet as we move into the 21st Century it is these scales that are of increasing import to end users. It is essential that we serve the right data in the right way with the correct caveats. This can only be achieved if a sufficient number of groups take up the challenge of creating new products from the raw databank. This poster will outline progress to date in the creation of the databank and global benchmarks and outline how investigators and groups can now get involved in creating products from the databank and participate in the benchmarking exercise. Further details upon the Initiative and its aims can be found at www.surfacetemperatures.org and http://surfacetemperatures.blogspot.com/

  13. Seasonal Spatial Patterns of Surface Water Temperature, Surface Heat Fluxes and Meteorological Forcing Over Lake Geneva

    Science.gov (United States)

    Irani Rahaghi, A.; Lemmin, U.; Bouffard, D.; Riffler, M.; Wunderle, S.; Barry, D. A.

    2015-12-01

    In many lakes, surface heat flux (SHF) is the most important component controlling the lake's energy content. Accurate methods for the determination of SHF are valuable for water management, and for use in hydrological and meteorological models. Large lakes, not surprisingly, are subject to spatially and temporally varying meteorological conditions, and hence SHF. Here, we report on an investigation for estimating the SHF of a large European lake, Lake Geneva. We evaluated several bulk formulas to estimate Lake Geneva's SHF based on different data sources. A total of 64 different surface heat flux models were realized using existing representations for different heat flux components. Data sources to run the models included meteorological data (from an operational numerical weather prediction model, COSMO-2) and lake surface water temperature (LSWT, from satellite imagery). Models were calibrated at two points in the lake for which regular depth profiles of temperature are available, and which enabled computation of the total heat content variation. The latter, computed for 03.2008-12.2012, was the metric used to rank the different models. The best calibrated model was then selected to calculate the spatial distribution of SHF. Analysis of the model results shows that evaporative and convective heat fluxes are the dominant terms controlling the spatial pattern of SHF. The former is significant in all seasons while the latter plays a role only in fall and winter. Meteorological observations illustrate that wind-sheltering, and to some extent relative humidity variability, are the main reasons for the observed large-scale spatial variability. In addition, both modeling and satellite observations indicate that, on average, the eastern part of the lake is warmer than the western part, with a greater temperature contrast in spring and summer than in fall and winter whereas the SHF spatial splitting is stronger in fall and winter. This is mainly due to negative heat flux

  14. Analysis of High Temperature Reactor Control Rod Worth for the Initial and Full Core

    Science.gov (United States)

    Oktajianto, Hammam; Setiawati, Evi; Anam, Khoirul; Sugito, Heri

    2017-01-01

    Control rod is one important component in a nuclear reactor. In nuclear reactor operations the control rod functions to shut down the reactor. This research analyses ten control rods worth of HTR (High Temperature Reactor) at initial and full core. The HTR in this research adopts HTR-10 China and HTR- of pebble bed. Core calculations are performed by using MCNPX code after modelling the entire parts of core in condition of ten control rods fully withdrawn, all control rods in with 20 cm ranges of depth and the use of one control rod. Pebble bed and moderator balls are distributed in the core zone using a Body Centred Cubic (BCC) lattice by ratio of 57:43. The research results are obtained that the use of one control rod will decrease the reactor criticality of 2.04±0.12 %Δk/k at initial core and 1.57±0.10 %Δk/k at full core. The deeper control rods are in, the lesser criticality of reactor is with reactivity of ten control rods of 16.41±0.11 %Δk/k at initial core and 15.43±0.11 %Δk/k at full core. The results show that the use of ten control rods at full core will keep achieving subcritical condition even though the reactivity is smaller than reactivity at initial core.

  15. Initiation of vacuum insulator surface high-voltage flashover with electrons produced by laser illumination

    Science.gov (United States)

    Krasik, Ya. E.; Leopold, J. G.

    2015-08-01

    In this paper, experiments are described in which cylindrical vacuum insulator samples and samples inclined at 45° relative to the cathode were stressed by microsecond timescale high-voltage pulses and illuminated by focused UV laser beam pulses. In these experiments, we were able to distinguish between flashover initiated by the laser producing only photo-electrons and when plasma is formed. It was shown that flashover is predominantly initiated near the cathode triple junction. Even dense plasma formed near the anode triple junction does not necessarily lead to vacuum surface flashover. The experimental results directly confirm our conjecture that insulator surface breakdown can be avoided by preventing its initiation [J. G. Leopold et al., Phys. Rev. ST Accel. Beams 10, 060401 (2007)] and complement our previous experimental results [J. Z. Gleizer et al., IEEE Trans. Dielectr. Electr. Insul. 21, 2394 (2014) and J. Z. Gleizer et al., J. Appl. Phys. 117, 073301 (2015)].

  16. Initiation of vacuum insulator surface high-voltage flashover with electrons produced by laser illumination

    Energy Technology Data Exchange (ETDEWEB)

    Krasik, Ya. E.; Leopold, J. G. [Physics Department, Technion, Haifa 32000 (Israel)

    2015-08-15

    In this paper, experiments are described in which cylindrical vacuum insulator samples and samples inclined at 45° relative to the cathode were stressed by microsecond timescale high-voltage pulses and illuminated by focused UV laser beam pulses. In these experiments, we were able to distinguish between flashover initiated by the laser producing only photo-electrons and when plasma is formed. It was shown that flashover is predominantly initiated near the cathode triple junction. Even dense plasma formed near the anode triple junction does not necessarily lead to vacuum surface flashover. The experimental results directly confirm our conjecture that insulator surface breakdown can be avoided by preventing its initiation [J. G. Leopold et al., Phys. Rev. ST Accel. Beams 10, 060401 (2007)] and complement our previous experimental results [J. Z. Gleizer et al., IEEE Trans. Dielectr. Electr. Insul. 21, 2394 (2014) and J. Z. Gleizer et al., J. Appl. Phys. 117, 073301 (2015)].

  17. Transport mechanism of an initially spherical droplet on a combined hydrophilic/hydrophobic surface

    Energy Technology Data Exchange (ETDEWEB)

    Myong, Hyon Kook; Kwon, Young Hoo [Dept. of Mechanical Engineering, Kookmin University, Seoul (Korea, Republic of)

    2015-11-15

    Fluid transport is a key issue in the development of microfluidic systems. Recently, Myong (2014) has proposed a new concept for droplet transport without external power sources, and numerically validated the results for a hypothetical 2D shape, initially having a hemicylindrical droplet shape. Myong and Kwon (2015) have also examined the transport mechanism for an actual water droplet, initially having a 3D hemispherical shape, on a horizontal hydrophilic/hydrophobic surface, based on the numerical results of the time evolution of the droplet shape, as well as the total kinetic, gravitational, pressure and surface free energies inside the droplet. In this study, a 3D numerical analysis of an initially spherical droplet is carried out to establish a new concept for droplet transport. Further, the transport mechanism of an actual water droplet is examined in detail from the viewpoint of the capillarity force imbalance through the numerical results of droplet shape and various energies inside the droplet.

  18. Initial oxidation behaviors of nitride surfaces of uranium by XPS analysis

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Kezhao, E-mail: liukz@hotmail.com [Department of Materials Science and Engineering, Zhejiang University, No. 38 Zheda Road, Hangzhou 310027 (China); Science and Technology on Surface Physics and Chemistry Laboratory, P.O. Box 718-35, Mianyang 621907 (China); Luo, Lizu; Luo, Lili [Science and Technology on Surface Physics and Chemistry Laboratory, P.O. Box 718-35, Mianyang 621907 (China); Long, Zhong [China Academy of Engineering Physics, P.O. Box 919-71, Mianyang 621907 (China); Hong, Zhanglian, E-mail: hong_zhanglian@zju.edu.cn [Department of Materials Science and Engineering, Zhejiang University, No. 38 Zheda Road, Hangzhou 310027 (China); Yang, Hui [Department of Materials Science and Engineering, Zhejiang University, No. 38 Zheda Road, Hangzhou 310027 (China); Wu, Sheng [Science and Technology on Surface Physics and Chemistry Laboratory, P.O. Box 718-35, Mianyang 621907 (China)

    2013-09-01

    The nitride surfaces of uranium were prepared by the surface glow plasma nitriding (SGPN) and plasma immersion ion implantation (PIII) methods. The initial oxidation behaviors of modified surfaces were studied by X-ray photoelectron spectroscopy (XPS). The SGPN on the uranium surface led to a single layer of uranium sesquinitride (U{sub 2}N{sub 3}), while the PIII on the surface resulted in a compound layer composed of U{sub 2}N{sub 3} and uranium dioxide (UO{sub 2}). The oxygen covered on these modified layers led to the formation of UO{sub 2} from U{sub 2}N{sub 3} and U{sub 2}N{sub 3} from UN. The oxidized nitrogen species were also observed on the two types of nitriding layers, with the discussion of the N–O coaction behaviors.

  19. Parametrizing Impulsive X-ray Heating with a Cumulative Initial-Temperature Distribution

    CERN Document Server

    Gayley, K G

    2014-01-01

    In collisional ionization equilibrium (CIE), the X-ray spectrum from a plasma depends on the distribution of emission measure over temperature (DEM). Due to the well-known ill conditioning problem, no precisely resolved DEM can be inverted directly from the spectrum, so often only a gross parametrization of the DEM is used to approximate the data, in hopes that the parametrization can provide useful model-independent constraints on the heating process. However, ill conditioning also introduces ambiguity into the various different parametrizations that could approximate the data, which may spoil the perceived advantages of model independence. Thus, this paper instead suggests a single parametrization for both the heating mechanism and the X-ray sources, based on a model of impulsive heating followed by complete cooling. This approach is similar to a ``cooling flow'' approach, but allows injection at multiple initial temperatures, and applies even when the steady state is distribution of different shock strengt...

  20. Flagella interacting with a carbon nanowire with the variation of time and initial temperature.

    Science.gov (United States)

    Santos, Elson C; Santos, Alessandro J G; Neto, Abel F G; Neto, Antonio M J C; Borges, Rosivaldo S; Ramalho, Teodorico C

    2014-06-01

    The system proposed consists of a flagellum relaxing around a static carbon nanowire to mimics behavior of a natural flagellum moving with damped harmonic motion along a wire under van der Waals and electrostatic forces. This flagellum is composed of a C20 nanosphere with different sizes of his tail formed by hydrocarbons. The thermodynamic properties such as molar entropy variation, as well as molar heat dissipation, efficiency and speed were obtained to evaluate which system is most stable by using the variable temperature. This system has a number of carbon atoms ranging from 103-110, with a maximum of 300 ps for each simulation. We had simulated molar entropy variation, energies and efficiency changing with time and initial temperature. The results indicate that among the systems studied, the flagellum with five carbon atoms achieved greater stability and better results in this search.

  1. The mechanism for the impact of sea surface temperature anomaly on the ridgeline surface of Western Pacific

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Based on the atmospheric circulation data provided by ECMWF and the sea surface temperature data by NOAA, we studied the mechanism for the impact of sea surface temperature anomaly on the ridgeline surface of western Pacific using an improved high truncated spectral model. Our results show that the wave-wave interaction and the wave-mean flow interactions are weaker in the inner dynamic process of atmospheric circulation, when atmospheric circulation is forced by the sea surface temperature of El Ni-o pattern. With the external thermal forcing changed from winter to summer pattern, the range of ridgeline surface of western Pacific moving northward is smaller, which causes the ridgeline surface of western Pacific on south of normal. On the contrary, the wave-wave interaction and the wave-mean flow interaction are stronger, when atmospheric circulation is forced by the sea surface temperature of La Ni-a pattern. With the external thermal forcing turning from winter to summer pattern, the ridgeline surface of western Pacific shifts northward about 19 latitude degrees, which conduces the ridgeline surface of western Pacific on north of normal. After moving to certain latitude, the ridgeline surface of western Pacific oscillates with the most obvious 30-60 d period and the 4°-7° amplitude. It is one of the important reasons for the interannual variation of ridgeline surface of Western Pacific that the at- mospheric inner dynamical process forced out by different sea surface temperature anomaly pattern is different.

  2. Influence of Initial Inclined Surface Crack on Estimated Residual Fatigue Lifetime of Railway Axle

    Science.gov (United States)

    Náhlík, Luboš; Pokorný, Pavel; Ševčík, Martin; Hutař, Pavel

    2016-11-01

    Railway axles are subjected to cyclic loading which can lead to fatigue failure. For safe operation of railway axles a damage tolerance approach taking into account a possible defect on railway axle surface is often required. The contribution deals with an estimation of residual fatigue lifetime of railway axle with initial inclined surface crack. 3D numerical model of inclined semi-elliptical surface crack in railway axle was developed and its curved propagation through the axle was simulated by finite element method. Presence of press-fitted wheel in the vicinity of initial crack was taken into account. A typical loading spectrum of railway axle was considered and residual fatigue lifetime was estimated by NASGRO approach. Material properties of typical axle steel EA4T were considered in numerical calculations and lifetime estimation.

  3. Downscaling MODIS Land Surface Temperature for Urban Public Health Applications

    Science.gov (United States)

    Al-Hamdan, M. Z.; Crosson, W. L.; Estes, M. G., Jr.; Estes, S. M.; Quattrochi, D. A.; Johnson, D.

    2013-12-01

    This study is part of a project funded by the NASA Applied Sciences Public Health Program, which focuses on Earth science applications of remote sensing data for enhancing public health decision-making. Heat related death is currently the number one weather-related killer in the United States. Mortality from these events is expected to increase as a function of climate change. This activity sought to augment current Heat Watch/Warning Systems (HWWS) with NASA remotely sensed data, and models used in conjunction with socioeconomic and heat-related mortality data. The current HWWS do not take into account intra-urban spatial variations in risk assessment. The purpose of this effort is to evaluate a potential method to improve spatial delineation of risk from extreme heat events in urban environments by integrating sociodemographic risk factors with land surface temperature (LST) estimates derived from thermal remote sensing data. In order to further improve the assessment of intra-urban variations in risk from extreme heat, we developed and evaluated a number of spatial statistical techniques for downscaling the 1-km daily MODerate-resolution Imaging Spectroradiometer (MODIS) LST data to 60 m using Landsat-derived LST data, which have finer spatial but coarser temporal resolution than MODIS. We will present these techniques, which have been demonstrated and validated for Phoenix, AZ using data from the summers of 2000-2006.

  4. Spatial Statistical Estimation for Massive Sea Surface Temperature Data

    Science.gov (United States)

    Marchetti, Y.; Vazquez, J.; Nguyen, H.; Braverman, A. J.

    2015-12-01

    We combine several large remotely sensed sea surface temperature (SST) datasets to create a single high-resolution SST dataset that has no missing data and provides an uncertainty associated with each value. This high resolution dataset will optimize estimates of SST in critical parts of the world's oceans, such as coastal upwelling regions. We use Spatial Statistical Data Fusion (SSDF), a statistical methodology for predicting global spatial fields by exploiting spatial correlations in the data. The main advantages of SSDF over spatial smoothing methodologies include the provision of probabilistic uncertainties, the ability to incorporate multiple datasets with varying footprints, measurement errors and biases, and estimation at any desired resolution. In order to accommodate massive input and output datasets, we introduce two modifications of the existing SSDF algorithm. First, we compute statistical model parameters based on coarse resolution aggregated data. Second, we use an adaptive spatial grid that allows us to perform estimation in a specified region of interest, but incorporate spatial dependence between locations in that region and all locations globally. Finally, we demonstrate with a case study involving estimations on the full globe at coarse resolution grid (30 km) and a high resolution (1 km) inset for the Gulf Stream region.

  5. Bias correction methods for decadal sea-surface temperature forecasts

    Directory of Open Access Journals (Sweden)

    Balachandrudu Narapusetty

    2014-04-01

    Full Text Available Two traditional bias correction techniques: (1 systematic mean correction (SMC and (2 systematic least-squares correction (SLC are extended and applied on sea-surface temperature (SST decadal forecasts in the North Pacific produced by Climate Forecast System version 2 (CFSv2 to reduce large systematic biases. The bias-corrected forecast anomalies exhibit reduced root-mean-square errors and also significantly improve the anomaly correlations with observations. The spatial pattern of the SST anomalies associated with the Pacific area average (PAA index (spatial average of SST anomalies over 20°–60°N and 120°E–100°W is improved after employing the bias correction methods, particularly SMC. Reliability diagrams show that the bias-corrected forecasts better reproduce the cold and warm events well beyond the 5-yr lead-times over the 10 forecasted years. The comparison between both correction methods indicates that: (1 prediction skill of SST anomalies associated with the PAA index is improved by SMC with respect to SLC and (2 SMC-derived forecasts have a slightly higher reliability than those corrected by SLC.

  6. Downscaling MODIS Land Surface Temperature for Urban Public Health Applications

    Science.gov (United States)

    Al-Hamdan, Mohammad; Crosson, William; Estes, Maurice, Jr.; Estes, Sue; Quattrochi, Dale; Johnson, Daniel

    2013-01-01

    This study is part of a project funded by the NASA Applied Sciences Public Health Program, which focuses on Earth science applications of remote sensing data for enhancing public health decision-making. Heat related death is currently the number one weather-related killer in the United States. Mortality from these events is expected to increase as a function of climate change. This activity sought to augment current Heat Watch/Warning Systems (HWWS) with NASA remotely sensed data, and models used in conjunction with socioeconomic and heatrelated mortality data. The current HWWS do not take into account intra-urban spatial variation in risk assessment. The purpose of this effort is to evaluate a potential method to improve spatial delineation of risk from extreme heat events in urban environments by integrating sociodemographic risk factors with estimates of land surface temperature (LST) derived from thermal remote sensing data. In order to further improve the consideration of intra-urban variations in risk from extreme heat, we also developed and evaluated a number of spatial statistical techniques for downscaling the 1-km daily MODerate-resolution Imaging Spectroradiometer (MODIS) LST data to 60 m using Landsat-derived LST data, which have finer spatial but coarser temporal resolution than MODIS. In this paper, we will present these techniques, which have been demonstrated and validated for Phoenix, AZ using data from the summers of 2000-2006.

  7. Long-term change in surface air temperature over Eurasian continent and possible contribution from land-surface conditions.

    Science.gov (United States)

    Kim, K.; Jeong, J. H.; Shim, T.

    2015-12-01

    Summertime heat wave over Eurasia is induced by various climatic factors. As internal and external factors are changing under an abrupt climate change, the variability of heat waves exhibits radical changes. In this study, the long-term change in heat wave characteristics over Eurasia for the last several decades was examined and the impact of land-atmosphere interaction modulated by soil moisture variability on the change was investigated. Through the empirical orthogonal functions(EOF) analysis, the principle spatio-temporal pattern of Eurasian heat wave during July-August was objectively detected. The leading pattern (1st EOF mode) of the variability was found be an overall increase in heat waves over eastern Europe and east Asia (Mongol to northern part of China), which seems to be associated mainly with the global warming signal but with interannual variability as well. Through performing JULES(Joint UK Land Environment Simulator) land surface model simulation forced with observational atmospheric forcings, soil moisture and energy flux at surface were estimated, and the impacts of land-atmosphere interaction on the heat wave variability was investigated based on the estimated land surface variables and temperature observations. It is found that there is a distinct dry soil condition accompanying with East Asian heat waves. The dry condition leads to an increase in sensible heat flux from land surface to atmosphere and resulting near-surface warming, which is followed by warm-core high - a typical characteristics of a heatwave sustained by land-atmosphere interaction. This result is consistent with an distinct increase in heatwave in recent years. By using the hindcast of long-range prediction model of KMA, GloSea5, the seasonal predictability of heatwave was examined. GloSea5 reasonably well simulates the spatial pattern of Eurasian heatwaves variability found in observations but shows modest skill in simulating accurate year-to-year variability. This result

  8. Impact of sea surface temperature on satellite retrieval of sea surface salinity

    Science.gov (United States)

    Jin, Xuchen; Zhu, Qiankun; He, Xianqiang; Chen, Peng; Wang, Difeng; Hao, Zengzhou; Huang, Haiqing

    2016-10-01

    Currently, global sea surface salinity (SSS) can be retrieved by the satellite microwave radiometer onboard the satellite, such as the Soil Moisture and Ocean Salinity(SMOS) and the Aqurius. SMOS is an Earth Explorer Opportunity Mission from the European Space Agency(ESA). It was launched at a sun-synchronous orbit in 2009 and one of the payloads is called MIRAS(Microwave Imaging Radiometer using Aperture Synthesis), which is the first interferometric microwave radiometer designed for observing SSS at L-band(1.41 GHz).The foundation of the salinity retrieval by microwave radiometer is that the sea surface radiance at L-band has the most suitable sensitivity with the variation of the salinity. It is well known that the sensitivity of brightness temperatures(TB) to SSS depends on the sea surface temperature (SST), but the quantitative impact of the SST on the satellite retrieval of the SSS is still poorly known. In this study, we investigate the impact of the SST on the accuracy of salinity retrieval from the SMOS. First of all, The dielectric constant model proposed by Klein and Swift has been used to estimate the vertically and horizontally polarized brightness temperatures(TV and TH) of a smooth sea water surface at L-band and derive the derivatives of TV and TH as a function of SSS to show the relative sensitivity at 45° incident angle. Then, we use the GAM(generalized additive model) method to evaluate the association between the satellite-measured brightness temperature and in-situ SSS at different SST. Moreover, the satellite-derived SSS from the SMOS is validated using the ARGO data to assess the RMSE(root mean squared error). We compare the SMOS SSS and ARGO SSS over two regions of Pacific ocean far from land and ice under different SST. The RMSE of retrieved SSS at different SST have been estimated. Our results showed that SST is one of the most significant factors affecting the accuracy of SSS retrieval. The satellite-measured brightness temperature has a

  9. Plasma-initiated rehydrogenation of amorphous silicon to increase the temperature processing window of silicon heterojunction solar cells

    Science.gov (United States)

    Shi, Jianwei; Boccard, Mathieu; Holman, Zachary

    2016-07-01

    The dehydrogenation of intrinsic hydrogenated amorphous silicon (a-Si:H) at temperatures above approximately 300 °C degrades its ability to passivate silicon wafer surfaces. This limits the temperature of post-passivation processing steps during the fabrication of advanced silicon heterojunction or silicon-based tandem solar cells. We demonstrate that a hydrogen plasma can rehydrogenate intrinsic a-Si:H passivation layers that have been dehydrogenated by annealing. The hydrogen plasma treatment fully restores the effective carrier lifetime to several milliseconds in textured crystalline silicon wafers coated with 8-nm-thick intrinsic a-Si:H layers after annealing at temperatures of up to 450 °C. Plasma-initiated rehydrogenation also translates to complete solar cells: A silicon heterojunction solar cell subjected to annealing at 450 °C (following intrinsic a-Si:H deposition) had an open-circuit voltage of less than 600 mV, but an identical cell that received hydrogen plasma treatment reached a voltage of over 710 mV and an efficiency of over 19%.

  10. Molecular Dynamics of Carbon Nanotubes Deposited on a Silicon Surface via Collision: Temperature Dependence

    Energy Technology Data Exchange (ETDEWEB)

    Saha, Leton C.; Mian, Shabeer A.; Kim, Hyo Jeong; Saha, Joyanta K.; Matin, Mohammad A.; Jang, Joon Kyung [Pusan National University, Miryang (Korea, Republic of)

    2011-02-15

    We investigated how temperature influences the structural and energetic dynamics of carbon nanotubes (CNTs) undergoing a high-speed impact with a Si (110) surface. By performing molecular dynamics simulations in the temperature range of 100 - 300 K, we found that a low temperature CNT ends up with a higher vibrational energy after collision than a high temperature CNT. The vibrational temperature of CNT increases by increasing the surface temperature. Overall, the structural and energy relaxation of low temperature CNTs are faster than those of high temperature CNTs.

  11. Comprehensive study on initial thermal oxidation of GaN(0001) surface and subsequent oxide growth in dry oxygen ambient

    Science.gov (United States)

    Yamada, Takahiro; Ito, Joyo; Asahara, Ryohei; Watanabe, Kenta; Nozaki, Mikito; Nakazawa, Satoshi; Anda, Yoshiharu; Ishida, Masahiro; Ueda, Tetsuzo; Yoshigoe, Akitaka; Hosoi, Takuji; Shimura, Takayoshi; Watanabe, Heiji

    2017-01-01

    Initial oxidation of gallium nitride (GaN) (0001) epilayers and subsequent growth of thermal oxides in dry oxygen ambient were investigated by means of x-ray photoelectron spectroscopy, spectroscopic ellipsometry, atomic force microscopy, and x-ray diffraction measurements. It was found that initial oxide formation tends to saturate at temperatures below 800 °C, whereas the selective growth of small oxide grains proceeds at dislocations in the epilayers, followed by noticeable grain growth, leading to a rough surface morphology at higher oxidation temperatures. This indicates that oxide growth and its morphology are crucially dependent on the defect density in the GaN epilayers. Structural characterizations also reveal that polycrystalline α- and β-phase Ga2O3 grains in an epitaxial relation with the GaN substrate are formed from the initial stage of the oxide growth. We propose a comprehensive model for GaN oxidation mediated by nitrogen removal and mass transport and discuss the model on the basis of experimental findings.

  12. Temperature Measurements On Semi-Permanent Mold Surfaces Using Infrared Thermography

    Science.gov (United States)

    Hurley, Ronald G.

    1983-03-01

    Die surface temperature and internal die thermal balance are critical to the quality of semi-permanent mold die castings. Measurements of the surface temperature are currently made using either hand-held contact temperature probes or optical pyrometers. Neither measurement technique provides a thermal map of the entire die surface. This paper discusses the use of infrared thermography for die surface temperature measurement. Using infrared thermographic techniques, scans were made over the surface of an experimental 302 CID semi-permanent mold cylinder head die during several casting cycles. The results obtained were in reasonable agreement with the temperature measurements made using optical pyrometers and the contact probes. In addition, using gray-level conversion the IR technique provided a measure of the temperature gradient over the surface of the die. Such thermal mapping has not been practical using optical or contact temperature probes.

  13. Linking Satellite Derived Land Surface Temperature with Cholera: A Case Study for South Sudan

    Science.gov (United States)

    Aldaach, H. S. V.; Jutla, A.; Akanda, A. S.; Colwell, R. R.

    2014-12-01

    A sudden onset of cholera in South Sudan, in April 2014 in Northern Bari in Juba town resulted in more than 400 cholera cases after four weeks of initial outbreak with a case of fatality rate of CFR 5.4%. The total number of reported cholera cases for the period of April to July, 2014 were 5,141 including 114 deaths. With the limited efficacy of cholera vaccines, it is necessary to develop mechanisms to predict cholera occurrence and thereafter devise intervention strategies for mitigating impacts of the disease. Hydroclimatic processes, primarily precipitation and air temperature are related to epidemic and episodic outbreak of cholera. However, due to coarse resolution of both datasets, it is not possible to precisely locate the geographical location of disease. Here, using Land Surface Temperature (LST) from MODIS sensors, we have developed an algorithm to identify regions susceptible for cholera. Conditions for occurrence of cholera were detectable at least one month in advance in South Sudan and were statistically sensitive to hydroclimatic anomalies of land surface and air temperature, and precipitation. Our results indicate significant spatial and temporal averaging required to infer usable information from LST over South Sudan. Preliminary results that geographically location of cholera outbreak was identifiable within 1km resolution of the LST data.

  14. Evaluation of the ground surface Enthalpy balance from bedrock shallow borehole temperatures (Livingston Island, Maritime Antarctic

    Directory of Open Access Journals (Sweden)

    M. Ramos

    2008-03-01

    Full Text Available The annual evolution of the ground temperatures from Incinerador borehole in Livingston Island (South Shetlands, Antarctic is studied. The borehole is 2.4 m deep and is located in a quartzite outcrop in the proximity of the Spanish Antarctic Station Juan Carlos I. In order to model the movement of the 0°C isotherm (velocity and maximum depth hourly temperature profiles from: (i the cooling periods of the frost seasons of 2000 to 2005, and (ii the warming periods of the thaw seasons of 2002–2003, 2003–2004 and 2004–2005, were studied. In this modelling approach, heat gains and losses across ground surface are considered to be the causes for the 0°C isotherm movement. A methodological approach to calculate the Enthalpy change based on the thermodynamic analysis of the ground during the cooling and warming periods is proposed. The Enthalpy change is equivalent to the heat exchange through the ground surface during each season, thus enabling to describe the interaction ground-atmosphere and providing valuable data for studies on permafrost and periglacial processes. The bedrock density is considered to be constant in the borehole and initial isothermal conditions at 0°C are assumed to run the model. The final stages correspond to the temperatures at the end of the cooling and warming periods (annual minima and maxima.

  15. Temperature-driven oxidation behavior on pure iron surface investigated by time-resolved EXAFS measurements

    Energy Technology Data Exchange (ETDEWEB)

    Doh, S.J.; Lee, J.M.; Je, J.H. [POSTECH, Pohang (Korea, Republic of); Noh, D.Y. [K-JIST, Kwangju (Korea, Republic of). Dept. of Materials Science and Engineering

    1998-12-31

    The surface-front oxidation mechanism of iron was investigated by time-resolved, glancing-angle Fe K-edge fluorescence EXAFS measurements at various oxidation temperatures of 200--700 C. The glancing angle was chosen according to the depth of the oxide layer, roughly 1,500--2,000 {angstrom}. The oxidation behavior under rapid heating (up to 600 C within 10 minutes) was compared with the slowly heated oxidation process using the Quick-EXAFS measurements. In the slowly heated process, Fe{sub 3}O{sub 4} was the dominating phase at a relatively low temperature (300--400 C) initially. However, at a relatively high temperature (above 600 C), the Fe{sub 2}O{sub 3} and FeO crystalline phases are gradually enriched as the successive oxidation process involving intrusive oxygen proceeded. Remarkably under a prolonged heat treatment above 600 C, the stable FeO phase that exists in a deep-lying interface structure and Fe{sub 2}O{sub 3} phase eventually dominates the thick front-surface structure. In a quickly heated process, however, Fe{sub 3}O{sub 4} phase is less dominating, which is contradictory to the commonly accepted oxidation models. The EXAFS results are discussed in conjunction with the x-ray diffraction features under the same heat treatment conditions.

  16. Evaluation of the ground surface Enthalpy balance from bedrock shallow borehole temperatures (Livingston Island, Maritime Antarctic)

    Science.gov (United States)

    Ramos, M.; Vieira, G.

    2008-03-01

    The annual evolution of the ground temperatures from Incinerador borehole in Livingston Island (South Shetlands, Antarctic) is studied. The borehole is 2.4 m deep and is located in a quartzite outcrop in the proximity of the Spanish Antarctic Station Juan Carlos I. In order to model the movement of the 0°C isotherm (velocity and maximum depth) hourly temperature profiles from: (i) the cooling periods of the frost seasons of 2000 to 2005, and (ii) the warming periods of the thaw seasons of 2002-2003, 2003-2004 and 2004-2005, were studied. In this modelling approach, heat gains and losses across ground surface are considered to be the causes for the 0°C isotherm movement. A methodological approach to calculate the Enthalpy change based on the thermodynamic analysis of the ground during the cooling and warming periods is proposed. The Enthalpy change is equivalent to the heat exchange through the ground surface during each season, thus enabling to describe the interaction ground-atmosphere and providing valuable data for studies on permafrost and periglacial processes. The bedrock density is considered to be constant in the borehole and initial isothermal conditions at 0°C are assumed to run the model. The final stages correspond to the temperatures at the end of the cooling and warming periods (annual minima and maxima).

  17. Bio-polymer coatings on neural probe surfaces: Influence of the initial sample composition

    Energy Technology Data Exchange (ETDEWEB)

    Chow, Winnie W.Y. [Department of Physics and Astronomy, Uppsala University, Box 516, 751 20 Uppsala (Sweden); Herwik, Stanislav; Ruther, Patrick [Department of Microsystems Engineering (IMTEK), University of Freiburg (Germany); Goethelid, Emmanuelle [Department of Physics and Astronomy, Uppsala University, Box 516, 751 20 Uppsala (Sweden); Oscarsson, Sven, E-mail: sven@svenoscarsson.com [Department of Organic Chemistry, Stockholm University, Arrhenius Laboratory, SE-106 91 Stockholm (Sweden)

    2012-08-01

    This paper presents the results of the study of hyaluronic acid (HyA) coating on two structural materials, silicon oxide (dielectric) surface and platinum (Pt) surface used for fabrication of probes developed for neurological investigations in the framework of the EU-project NeuroProbes. The silicon-based neural probes consist of multiple Pt electrodes on the probe shafts for neural recording applications. HyA coatings were proposed to apply on the probe surfaces to enhance the biocompatibility. This study aims at understanding the influence of the initial composition of the probe surface on the structure and morphology of HyA coating. HyA was chemically functionalized by SS-pyridin using (N-Succinimidyl 3-[2-pyridyldithio]-propionate) (SPDP) and was immobilized on the surfaces via a covalent bond. The dielectric and Pt surfaces were derivatized by use of (3-mercaptopropyl) methyldimethoxysilane (MPMDMS). The silanol groups in MPMDMS bind to the dielectric surface, leaving the thiol groups at the uppermost surface and the thiol groups then bind covalently to the functionalized HyA. On the Pt surface, it is the thiol group which binds on the Pt surface. The coated surfaces were characterized by X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM). A well-defined HyA layer was observed on both dielectric and Pt surfaces. The coating of two molecular weights (340 kDa and 1.3 MDa) of HyA was examined. The influence of the silanized layer on the HyA coating was also investigated.

  18. Understanding the effects of the impervious surfaces pattern on land surface temperature in an urban area

    Science.gov (United States)

    Nie, Qin; Xu, Jianhua

    2015-06-01

    It is well known that urban impervious surface (IS) has a warming effect on urban land surface temperature (LST). However, the influence of an IS's structure, components, and spatial distribution on LST has rarely been quantitatively studied within strictly urban areas. Using ETM+ remote sensing images from the downtown area of Shanghai, China in 2010, this study characterized and quantified the influence of the IS spatial pattern on LST by selecting the percent cover of each IS cover feature and ten configuration metrics. The IS fraction was estimated by linear spectral mixture analysis (LSMA), and LST was retrieved using a mono-window algorithm. The results indicate that high fraction IS cover features account for the majority of the study area. The high fraction IS cover features are widely distributed and concentrated in groups, which is similar with that of high temperature zones. Both the percent composition and the configuration of IS cover features greatly affect the magnitude of LST, but the percent composition is a more important factor in determining LST than the configuration of those features. The significances and effects of the given configuration variables on LST vary greatly among IS cover features.

  19. Induction heating for surface triggering styrene polymerization on titanium modified with ATRP initiator.

    Science.gov (United States)

    Barthélémy, Bastien; Devillers, Sébastien; Minet, Isabelle; Delhalle, Joseph; Mekhalif, Zineb

    2011-02-15

    Titanium and its alloys present high interests for technological applications due to their high corrosion resistance, mechanical properties and biocompatibility. In combination with these remarkable characteristics, some Ti applications require specific surface properties that can be imparted with suitable surface functionalizations of the TiO(2) oxide layer. The present work aims to study the surface-initiated ATR polymerization of styrene on titanium substrates, using grafted 11-(2-bromoisobutyrate)-undecyl-1-phosphonic acid as initiator and to compare the impact of two different heating ways on the efficiency of this polymerization: induction vs. conventional heating. The ability of the initiator to bind titanium substrates and act as an initiator for ATRP of styrene is investigated: both heating conditions led to the polymerization of styrene on modified titanium substrates. However, induction heating appeared to be much more efficient than conventional heating, leading to the formation of a thicker, much denser polystyrene layer than conventional heating after only 1h of polymerization.

  20. The relative contributions of tropical Pacific sea surface temperatures and atmospheric internal variability to the recent global warming hiatus

    Science.gov (United States)

    Deser, Clara; Guo, Ruixia; Lehner, Flavio

    2017-08-01

    The recent slowdown in global mean surface temperature (GMST) warming during boreal winter is examined from a regional perspective using 10-member initial-condition ensembles with two global coupled climate models in which observed tropical Pacific sea surface temperature anomalies (TPAC SSTAs) and radiative forcings are specified. Both models show considerable diversity in their surface air temperature (SAT) trend patterns across the members, attesting to the importance of internal variability beyond the tropical Pacific that is superimposed upon the response to TPAC SSTA and radiative forcing. Only one model shows a close relationship between the realism of its simulated GMST trends and SAT trend patterns. In this model, Eurasian cooling plays a dominant role in determining the GMST trend amplitude, just as in nature. In the most realistic member, intrinsic atmospheric dynamics and teleconnections forced by TPAC SSTA cause cooling over Eurasia (and North America), and contribute equally to its GMST trend.

  1. Climate Variability in Coastal Ecosystems - Use of MODIS Land Surface and Sea Surface Temperature Observations

    Science.gov (United States)

    Chintalapati, S.; Lakshmi, V.

    2007-12-01

    The intertidal zone, with its complex blend of marine and terrestrial environments, is one of the intensively studied ecosystems, in understanding the effects of climate change on species abundance and distribution. As climatic conditions change, the geographic limits of the intertidal species will likely move towards more tolerable coastal conditions. Traditionally, understanding climate change effects through species physiologic response have involved use of in situ measurements and thermal engineering models. But these approaches are constrained by their data intensive requirements and may not be suitable for predicting change patterns relevant to large scale species distributions. Satellite remote sensing provides an alternate approach, given the regular global coverage at moderate spatial resolutions. The present study uses six years of land surface temperature (LST) and sea surface temperature (SST) data from MODIS/Terra instrument along various coastlines around the globe - East and West Coast US, Southern Africa, Northern Japan and New Zealand. Apart from the dominant annual cycle in LST and SST, the other seasonal cycles vary from dominant semi-annual cycles in lower latitudes to 1.5 and 2 year cycles at higher latitudes. The monthly anomalies show strong spatial structure at lower latitudes when compared to higher latitudes, with the exception of US east coast, where the spatial structure extended almost along the whole coastline, indicating strong regulation from the Gulf Stream. The patterns along different coast lines are consistent with the atmospheric and ocean circulation patterns existing at those regions. These results suggest that the climatology at the coastal regions can be adequately represented using satellite-based temperature data, thus enabling further research in understanding the effects of climate change on species abundance and distribution at larger scales.

  2. Souring in low-temperature surface facilities of two high-temperature Argentinian oil fields.

    Science.gov (United States)

    Agrawal, Akhil; An, Dongshan; Cavallaro, Adriana; Voordouw, Gerrit

    2014-09-01

    Produced waters from the Barrancas and Chihuido de la Salina (CHLS) fields in Argentina had higher concentrations of sulfate than were found in the injection waters, suggesting that the formation waters in these reservoirs had a high sulfate concentration and that sulfate-reducing bacteria were inactive downhole. Incubation of produced waters with produced oil gave rapid reduction of sulfate to sulfide (souring) at 37 °C, some at 60 °C, but none at 80 °C. Alkylbenzenes and alkanes served as electron donor, especially in incubations with CHLS oil. Dilution with water to decrease the ionic strength or addition of inorganic phosphate did not increase souring at 37 or 60 °C. These results indicate that souring in these reservoirs is limited by the reservoir temperature (80 °C for the Barrancas and 65-70 °C for the CHLS field) and that souring may accelerate in surface facilities where the oil-water mixture cools. As a result, significant sulfide concentrations are present in these surface facilities. The activity and presence of chemolithotrophic Gammaproteobacteria of the genus Thiomicrospira, which represented 85% of the microbial community in a water plant in the Barrancas field, indicated reoxidation of sulfide and sulfur to sulfate. The presence of these bacteria offers potential for souring control by microbial oxidation in aboveground facilities, provided that formation of corrosive sulfur can be avoided.

  3. Micromechanism of oxygen transport during initial stage oxidation in Si(100) surface: A ReaxFF molecular dynamics simulation study

    Science.gov (United States)

    Sun, Yu; Liu, Yilun; Chen, Xuefeng; Zhai, Zhi; Xu, Fei; Liu, Yijun

    2017-06-01

    The early stage oxidation in Si(100) surface has been investigated in this work by a reactive force field molecular dynamics (ReaxFF MD) simulation, manifesting that the oxygen transport acted as a dominant issue for initial oxidation process. Due to the oxidation, a compressive stress was generated in the oxide layer which blocked the oxygen transport perpendicular to the Si(100) surface and further prevented oxidation in the deeper layer. In contrast, thermal actuation was beneficial to the oxygen transport into deeper layer as temperature increases. Therefore, a competition mechanism was found for the oxygen transport during early stage oxidation in Si(100) surface. At room temperature, the oxygen transport was governed by the blocking effect of compressive stress, so a better quality oxide film with more uniform interface and more stoichiometric oxide structure was obtained. Indeed, the mechanism presented in this work is also applicable for other self-limiting oxidation (e.g. metal oxidation) and is helpful for the design of high-performance electronic devices.

  4. Retrieval of sea surface air temperature from satellite data over Indian Ocean: An empirical approach

    Digital Repository Service at National Institute of Oceanography (India)

    Sathe, P.V.; Muraleedharan, P.M.

    the surface air temperature and surface humidity is analysed by fitting a polynomial between the two for different regions of the Indian Ocean in different seasons. Taking into account the variation in surface air temperatures, the Indian Ocean is split in 14...

  5. Enhanced protein retention on poly(caprolactone) via surface initiated polymerization of acrylamide

    Science.gov (United States)

    Ma, Yuhao; Cai, Mengtan; He, Liu; Luo, Xianglin

    2016-01-01

    To enhance the biocompatibility or extend the biomedical application of poly(caprolactone) (PCL), protein retention on PCL surface is often required. In this study, poly(acrylamide) (PAAm) brushes were grown from PCL surface via surface-initiated atom transfer radical polymerization (SI-ATRP) and served as a protein-capturing platform. Grafted PAAm was densely packed on surface and exhibited superior protein retention ability. Captured protein was found to be resistant to washing under detergent environment. Furthermore, protein structure after being captured was investigated by circular dichroism (CD) spectroscopy, and the CD spectra verified that secondary structure of captured proteins was maintained, indicating no denaturation of protein happened for retention process.

  6. Holocene hydrological and sea surface temperature changes in the northern coast of the South China Sea

    Science.gov (United States)

    Wu, Mong-Sin; Zong, Yongqiang; Mok, Ka-Man; Cheung, Ka-Ming; Xiong, Haixian; Huang, Guangqing

    2017-03-01

    In order to reconstruct the Holocene environmental history of a coastal site in the northern South China Sea, this study analysed the organic carbon isotope ratios (δ13Corg) and alkenone unsaturation ratios (UK‧37) from a 36.5 m-long sediment core drilled at seabed in the mouth region of the Pearl River estuary and generated a coupled hydrological and temperature record. This record reveals changes of monsoon-induced sediment discharge and sea surface temperature of the Holocene in four stages. In Stage I, the site was under fluvial conditions prior to postglacial marine transgression. Stage II saw an increase of sea surface temperature from c. 23.0 °C to 27.0 °C, associated with a strengthened summer monsoon from c. 10,350 to 8900 cal. years BP. This was also a period of rapid sea-level rise and marine transgression, during which the sea inundated the palaeo-incised channel, i.e. the lower part of the T-shape accommodation space created by the rising sea. In these 1500 years, fluvial discharge was strong and concentrated within the channel, and the high sedimentation rate (11.8 mm/year) was very close to the rate of sea-level rise. In the subsequent 2000 years (Stage III) sea level continued to rise and the sea flooded the broad seabed above the palaeo-incised channel, resulted in fluvial discharge spreading thinly across the wide accommodation space and a much reduced sedimentation rate (1.8 mm/year). Sea surface temperature in this stage reached 27.3 °C initially, but dropped sharply to 26.1 °C towards c. 8200 cal. years BP. The final stage covers the last 7000 years, and the site was under a stable sea level. Sedimentation in this stage varied a little, but averaged at 1.8 mm/year. Whilst fluvial discharge and sea surface temperature didn't change much, two short periods of hydrological and temperature change were observed, which are related to the climatic cooling events of c. 4200 cal. years ago and the Little Ice Age.

  7. Long-term evolution of tidal heating and surface temperature on extrasolar planets

    Science.gov (United States)

    Kanova, Michaela; Behounkova, Marie

    2015-04-01

    Increasing number of detected extrasolar planets provides a unique statistical set that may help us to improve our knowledge about planetary evolution. Indirect detection methods employed in search for exoplanets are most sensitive to objects orbiting close to their host star and this criterion gets particularly important in the case of low-mass terrestrial planets. Here, we focus on long-term orbital and thermal evolution of a single planet subjected to stellar tides. Our approach combines evaluation of surface temperature as well as numerical computation of tidal effects on planetary orbit and internal heating. By calculating the tidal evolution of the orbit [1], we analyze the effect of initial orbital parameters (eccentricity, semi-major axis and rotational frequency) on secular changes in surface temperature and tidal dissipation. The maximum surface temperature and temperature gradient is computed during the process and it evolves together with the semi-major axis, the eccentricity and the ratio of spin and orbital frequency. Significant increase in the surface temperature is observed when the planet encounters a spin-orbit resonance. We solve the heat diffusion equation numerically for both 1D and 3D geometry in a thin spherical shell corresponding to a subsurface layer (see e.g. [2]), where the upper boundary condition is given by energy equilibrium and is strongly non-linear in temperature due to Stefan-Boltzmann law. Additionally, we solve the viscoelastic response to the tidal loading during orbital evolution. Following the method of [3,4], the tidal heating is evaluated for Maxwell or Andrade rheology in the time domain. We study disturbing potential caused by the body's deformation, the time dependence of phase lag and time lag during one orbit and compare our results with traditionally used constant tidal lag models (e.g. [1,5]). The effect of a 3D internal structure on the disturbing potential is investigated as well. This study is our first step

  8. Simulations on the influence of lunar surface temperature profiles on CE-1 lunar microwave sounder brightness temperature

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Surface temperature profile is an important parameter in lunar microwave remote sensing. Based on the analysis of physical properties of the lunar samples brought back by the Apollo and Luna missions, we modeled temporal and spatial variation of lunar surface temperature with the heat conduction equation, and produced temperature distribution in top 6.0 m of lunar regolith of the whole Moon surface. Our simulation results show that the profile of lunar surface temperature varies mainly within the top 20 cm, except at the lunar polar regions where the changes can reach to about 1.0 m depth. The temperature is stable beyond that depth. The variations of lunar surface temperature lead to main changes in brightness temperature (TB) at different channels of the lunar microwave sounder (CELMS) on Chang’E-1 (CE-1). The results of this paper show that the temperature profile influenced CELMS TB, which provides strong validation on the CELMS data, and lays a solid basis for future interpretation and utilization of the CELMS data.

  9. Prediction of daily sea surface temperature using efficient neural networks

    Science.gov (United States)

    Patil, Kalpesh; Deo, Makaranad Chintamani

    2017-04-01

    Short-term prediction of sea surface temperature (SST) is commonly achieved through numerical models. Numerical approaches are more suitable for use over a large spatial domain than in a specific site because of the difficulties involved in resolving various physical sub-processes at local levels. Therefore, for a given location, a data-driven approach such as neural networks may provide a better alternative. The application of neural networks, however, needs a large experimentation in their architecture, training methods, and formation of appropriate input-output pairs. A network trained in this manner can provide more attractive results if the advances in network architecture are additionally considered. With this in mind, we propose the use of wavelet neural networks (WNNs) for prediction of daily SST values. The prediction of daily SST values was carried out using WNN over 5 days into the future at six different locations in the Indian Ocean. First, the accuracy of site-specific SST values predicted by a numerical model, ROMS, was assessed against the in situ records. The result pointed out the necessity for alternative approaches. First, traditional networks were tried and after noticing their poor performance, WNN was used. This approach produced attractive forecasts when judged through various error statistics. When all locations were viewed together, the mean absolute error was within 0.18 to 0.32 °C for a 5-day-ahead forecast. The WNN approach was thus found to add value to the numerical method of SST prediction when location-specific information is desired.

  10. Prediction of daily sea surface temperature using efficient neural networks

    Science.gov (United States)

    Patil, Kalpesh; Deo, Makaranad Chintamani

    2017-02-01

    Short-term prediction of sea surface temperature (SST) is commonly achieved through numerical models. Numerical approaches are more suitable for use over a large spatial domain than in a specific site because of the difficulties involved in resolving various physical sub-processes at local levels. Therefore, for a given location, a data-driven approach such as neural networks may provide a better alternative. The application of neural networks, however, needs a large experimentation in their architecture, training methods, and formation of appropriate input-output pairs. A network trained in this manner can provide more attractive results if the advances in network architecture are additionally considered. With this in mind, we propose the use of wavelet neural networks (WNNs) for prediction of daily SST values. The prediction of daily SST values was carried out using WNN over 5 days into the future at six different locations in the Indian Ocean. First, the accuracy of site-specific SST values predicted by a numerical model, ROMS, was assessed against the in situ records. The result pointed out the necessity for alternative approaches. First, traditional networks were tried and after noticing their poor performance, WNN was used. This approach produced attractive forecasts when judged through various error statistics. When all locations were viewed together, the mean absolute error was within 0.18 to 0.32 °C for a 5-day-ahead forecast. The WNN approach was thus found to add value to the numerical method of SST prediction when location-specific information is desired.

  11. Evaluation and Monitoring of Jpss Land Surface Temperature Data

    Science.gov (United States)

    Yu, Y.; Yu, P.; Liu, Y.; Csiszar, I. A.

    2016-12-01

    Land Surface Temperature (LST) is one of environmental data records (EDRs) produced operationally through the U.S. Joint Polar Satellite System (JPSS) mission. LST is an important parameter for understanding climate change, modeling the hydrological and biogeochemical cycles, and is a prime candidate for Numerical Weather Prediction (NWP) assimilation models. Recently, the international LST and Emissivity Working Ggroup (ILSTE-WG) is promoting to the inclusion of the LST as essential climate variable (ECV) in the Global Climate Observation System (GCOS) of the Word Meteorological Organization (WMO). At the Center for Satellite Applications and Research (STAR) of National Atmospheric and Oceanic Administration (NOAA), we, are as a science team, are responsible to for the science of JPSS LST production. In this work, we present our activities and accomplishments on the JPSS LST evaluation and monitoring since the launch of the first JPSS satellite, i.e. S-NPP, satellite. Beta version, provisional version, and validated stage 1 version of the S-NPP LST products which were announced in May 2013, July 2014, and March 2015, respectively. Evaluation of the LST products have been performed versus ground measurements and other polar-orbiting satellite LST data (e,g. MODIS LSTs); some results will be illustrated. A daily monitoring system of the JPSS LST production has been developed, which presents daily, weekly and monthly global LST maps and inter-comparison results on the STAR JPSS program website. Further, evaluation of the enterprise LST algorithm for JPSS mission which is in development at STAR currently are presented in this work. Finally, evaluation and monitoring plan of the LST production for the JPSS-1 satellite are also presented.

  12. Optical properties of ultra-thin (layers on c-sapphire substrates with different initial growth conditions measured by surface-plasmon enhanced Raman scattering.

    Science.gov (United States)

    Kim, Ho-Jong; Kim, Tae-Soo; Lee, Jin-Gyu; Song, Jung Hoon

    2014-11-01

    We have carried out surface-plasmon enhanced Raman spectroscopy (SERS) on 30 nm-thick GaN samples grown at various temperatures, in order to investigate the properties of ultra thin GaN films on sapphire. We found that the properties, such as the strain and the free-carrier density of the thin layers, were sensitively affected by the growth temperatures. Our results show that SERS, by selectively enhancing the Raman signal near the surface, can be a very useful technique to investigate the optical properties of ultra-thin GaN films and their initial growth mode.

  13. A new algorithm for microwave radiometer remote sensing of sea surface salinity and temperature

    Institute of Scientific and Technical Information of China (English)

    YIN; Xiaobin; LIU; Yuguang; WANG; Zhenzhan

    2006-01-01

    The microwave radiation of the sea surface, which is denoted by the sea surface brightness temperature, is not only related with sea surface salinity (SSS) and temperature (SST), but also influenced by sea surface wind. The errors of wind detected by satellite sensor have significant influences on the accuracy of SSS and SST retrieval. The effects of sea surface wind on sea surface brightness temperature, i.e. △Th,v, and the relations among △Th,v, wind speed, sea surface temperature, sea surface salinity and incidence angle of observation are investigated. Based on the investigations, a new algorithm depending on the design of a single radiometer with double polarizations and multi-incidence angles is proposed. The algorithm excludes the influence of sea surface wind on SSS and SST retrieval, and provides a new method for remote sensing of SSS and SST.

  14. Complex polymer brush gradients based on nanolithography and surface-initiated polymerization.

    Science.gov (United States)

    Lin, Xiankun; He, Qiang; Li, Junbai

    2012-05-07

    Confined surface gradients consisting of polymer brushes have great potential in various applications such as microfluidic devices, sensors, and biophysical research. Among the available fabrication approaches, nanolithographies combined with self-assembled monolayers and surface-initiated polymerization have became powerful tools to engineer confined gradients or predefined complex gradients on the nanometre size. In this tutorial review, we mainly highlight the research progress of the fabrication of confined polymer brush gradients by using electron beam, laser, and probe-based nanolithographies and the physical base for these approaches. The application of these polymer brush gradients in biomedical research is also addressed.

  15. Nitroxide-Mediated Radical Polymerization of Styrene Initiated from the Surface of Titanium Oxide Nanoparticles

    Directory of Open Access Journals (Sweden)

    M. Abbasian

    2016-01-01

    Full Text Available Titanium dioxide (TiO2 nanoparticles, with an average size of about 45 nm, were encapsulated by polystyrene using in situ nitroxide mediated radical polymerization   in the presence of 3-aminopropyl triethoxy silane (APTES as a coupling agent and 2, 2, 6, 6-tetramethylpiperidinyl-1-oxy  as a initiator. First, the initiator for NMRP was covalently bonded onto the surface of Titanium dioxide nanoparticles through our novel method. For this purpose, the surface of TiO2 nanoparticle was treated with 3-aminopropyl triethoxy silane, a silane coupling agent, and then these functionalized nanoparticles was reacted with ±-chloro phenyl acetyl chloride. The chlorine groups were converted to nitroxide mediated groups by coupling with 1-hydroxy-2, 2, 6, 6-tetramethyl piperidine. These modified TiO2 nanoparticles were then dispersed in styrene (St monomers to carry out the in situ free radical polymerization.

  16. Numerical analysis of the movement of an initially hemispherical droplet hydrophilic/hydrophobic surface

    Energy Technology Data Exchange (ETDEWEB)

    Myong, Hyong Kook; Kwon, Young Hoo [Dept. of Mechanical Engineering, Kookmin University, Seoul (Korea, Republic of)

    2015-03-15

    Fluid transport is a key issue in the development of microfluidic systems. Recently, Myong (2014) has proposed a new concept for droplet transport without external power sources and numerically validated the results for a hypothetical 2D, initially having a hemicylindrical droplet. In this paper, the movement of an actual water droplet, initially having a 3D hemispherical shape, on horizontal hydrophilic/hydrophobic surfaces is simulated using a commercial computational fluid dynamics (CFD) package, Fluent, with VOF (volume of fluid) method. The results are compared with the 2D analysis of Myong (2014), and the transport mechanism for the actual water droplet is examined based on the numerical results of the time evolution of the droplet shape, as well as the total kinetic, gravitational, surface free and pressure energies inside the droplet.

  17. Surface-initiated synthesis of poly(3-methylthiophene) from indium tin oxide and its electrochemical properties.

    Science.gov (United States)

    Doubina, Natalia; Jenkins, Judith L; Paniagua, Sergio A; Mazzio, Katherine A; MacDonald, Gordon A; Jen, Alex K-Y; Armstrong, Neal R; Marder, Seth R; Luscombe, Christine K

    2012-01-24

    Poly(3-methylthiophene) (P3MT) was synthesized directly from indium tin oxide (ITO) electrodes modified with a phosphonic acid initiator, using Kumada catalyst transfer polymerization (KCTP). This work represents the first time that polymer thickness has been controlled in a surface initiated KCTP reaction, highlighting the utility of KCTP in achieving controlled polymerizations. Polymer film thicknesses were regulated by the variation of the solution monomer concentration and ranged from 30 to 265 nm. Electrochemical oxidative doping of these films was used to manipulate their near surface composition and effective work function. Doped states of the P3MT film are maintained even after the sample is removed from solution and potential control confirming the robustness of the films. Such materials with controllable thicknesses and electronic properties have the potential to be useful as interlayer materials for organic electronic applications.

  18. Impact of high resolution land surface initialization in Indian summer monsoon simulation using a regional climate model

    Science.gov (United States)

    Unnikrishnan, C. K.; Rajeevan, M.; Rao, S. Vijaya Bhaskara

    2016-06-01

    The direct impact of high resolution land surface initialization on the forecast bias in a regional climate model in recent years over Indian summer monsoon region is investigated. Two sets of regional climate model simulations are performed, one with a coarse resolution land surface initial conditions and second one used a high resolution land surface data for initial condition. The results show that all monsoon years respond differently to the high resolution land surface initialization. The drought monsoon year 2009 and extended break periods were more sensitive to the high resolution land surface initialization. These results suggest that the drought monsoon year predictions can be improved with high resolution land surface initialization. Result also shows that there are differences in the response to the land surface initialization within the monsoon season. Case studies of heat wave and a monsoon depression simulation show that, the model biases were also improved with high resolution land surface initialization. These results show the need for a better land surface initialization strategy in high resolution regional models for monsoon forecasting.

  19. Using SMOS brightness temperature and derived surface-soil moisture to characterize surface conditions and validate land surface models.

    Science.gov (United States)

    Polcher, Jan; Barella-Ortiz, Anaïs; Piles, Maria; Gelati, Emiliano; de Rosnay, Patricia

    2017-04-01

    The SMOS satellite, operated by ESA, observes the surface in the L-band. On continental surface these observations are sensitive to moisture and in particular surface-soil moisture (SSM). In this presentation we will explore how the observations of this satellite can be exploited over the Iberian Peninsula by comparing its results with two land surface models : ORCHIDEE and HTESSEL. Measured and modelled brightness temperatures show a good agreement in their temporal evolution, but their spatial structures are not consistent. An empirical orthogonal function analysis of the brightness temperature's error identifies a dominant structure over the south-west of the Iberian Peninsula which evolves during the year and is maximum in autumn and winter. Hypotheses concerning forcing-induced biases and assumptions made in the radiative transfer model are analysed to explain this inconsistency, but no candidate is found to be responsible for the weak spatial correlations. The analysis of spatial inconsistencies between modelled and measured TBs is important, as these can affect the estimation of geophysical variables and TB assimilation in operational models, as well as result in misleading validation studies. When comparing the surface-soil moisture of the models with the product derived operationally by ESA from SMOS observations similar results are found. The spatial correlation over the IP between SMOS and ORCHIDEE SSM estimates is poor (ρ 0.3). A single value decomposition (SVD) analysis of rainfall and SSM shows that the co-varying patterns of these variables are in reasonable agreement between both products. Moreover the first three SVD soil moisture patterns explain over 80% of the SSM variance simulated by the model while the explained fraction is only 52% of the remotely sensed values. These results suggest that the rainfall-driven soil moisture variability may not account for the poor spatial correlation between SMOS and ORCHIDEE products. Other reasons have to

  20. Simulation of land surface temperatures: comparison of two climate models and satellite retrievals

    Directory of Open Access Journals (Sweden)

    J. M. Edwards

    2009-03-01

    Full Text Available Recently there has been significant progress in the retrieval of land surface temperature from satellite observations. Satellite retrievals of surface temperature offer several advantages, including broad spatial coverage, and such data are potentially of great value in assessing general circulation models of the atmosphere. Here, retrievals of the land surface temperature over the contiguous United States are compared with simulations from two climate models. The models generally simulate the diurnal range realistically, but show significant warm biases during the summer. The models' diurnal cycle of surface temperature is related to their surface flux budgets. Differences in the diurnal cycle of the surface flux budget between the models are found to be more pronounced than those in the diurnal cycle of surface temperature.

  1. Initiation of blood coagulation - Evaluating the relevance of specific surface functionalities using self assembled monolayers

    OpenAIRE

    Fischer, Marion

    2010-01-01

    The surface of biomaterials can induce contacting blood to coagulate, similar to the response initiated by injured blood vessels to control blood loss. This poses a challenge to the use of biomaterials as the resulting coagulation can impair the performance of hemocompatible devices such as catheters, vascular stents and various extracorporeal tubings [1], what can moreover cause severe host reactions like embolism and infarction. Biomaterial induced coagulation processes limit the therape...

  2. Effect of treatment temperature on surface wettability of methylcyclosiloxane layer formed by chemical vapor deposition

    Science.gov (United States)

    Ishizaki, Takahiro; Sasagawa, Keisuke; Furukawa, Takuya; Kumagai, Sou; Yamamoto, Erina; Chiba, Satoshi; Kamiyama, Naosumi; Kiguchi, Takayoshi

    2016-08-01

    The surface wettability of the native Si oxide surfaces were tuned by chemical adsorption of 1,3,5,7-tetramethylcyclotetrasiloxane (TMCTS) molecules through thermal CVD method at different temperature. Water contact angle measurements revealed that the water contact angles of the TMCTS-modified Si oxide surfaces at the temperature of 333-373 K were found to be in the range of 92 ± 2-102 ± 2°. The advancing and receding water contact angle of the surface prepared at 333 K were found to be 97 ± 2/92 ± 2°, showing low contact angle hysteresis surface. The water contact angles of the surfaces prepared at the temperature of 373-413 K increased with an increase in the treatment temperature. When the treatment temperature was more than 423 K, the water contact angles of TMCTS-modified surfaces were found to become more than 150°, showing superhydrophobic surface. AFM study revealed that the surface roughness of the TMCTS-modified surface increased with an increase in the treatment temperature. This geometric morphology enhanced the surface hydrophobicity. The surface roughness could be fabricated due to the hydrolysis/condensation reactions in the gas phase during CVD process. The effect of the treatment temperature on the reactivity of the TMCTS molecules were also investigated using a thermogravimetric analyzer.

  3. Effect of Grinding Temperatures on the Surface Integrity of a Nickel-based Superalloy

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    An experimental study was carried out to investigat e the influence of temperatures on workpiece surface integrity in surface grinding of a cast nickel-based superalloy with alumina abrasive wheels. Temperatur e response at the wheel-workpiece interface was measured using a grindable foil /workpiece thermocouple. Specimens with different grinding temperatures were obt ained through changing grinding conditions including depth of cut, workpiece fee d speed, and coolant supply. Changes in surface roughnes...

  4. Studying randomness and determinism in surface temperature anomaly indices using the recurrence plot method

    Science.gov (United States)

    Kiselev, B. V.

    2016-01-01

    Surface temperature anomalies are studied using the methods of recurrence plots and statistical R/S analysis, as well as the Higuchi method for determining fractal dimension. Anomalies of the surface temperature above continents and the temperature in the World Ocean regions and in the Northern and Southern hemispheres are considered independently. It has been indicated that anomalies are more stochastic and deterministic for land and ocean surfaces, respectively.

  5. A temperature prediction-correction method for estimating surface soil heat flux from soil temperature and moisture data

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Surface soil heat flux is a component of surface energy budget and its estimation is needed in land-atmosphere interaction studies. This paper develops a new simple method to estimate soil heat flux from soil temperature and moisture observations. It gives soil temperature profile with the thermal diffusion equation and, then, adjusts the temperature profile with differences between observed and computed soil temperatures. The soil flux is obtained through integrating the soil temperature profile. Compared with previous methods, the new method does not require accurate thermal conductivity. Case studies based on observations, synthetic data, and sensitivity analyses show that the new method is preferable and the results obtained with it are not sensitive to the availability of temperature data in the topsoil. In addition, we pointed out that the soil heat flux measured with a heat-plate can be quite erroneous in magnitude though its phase is accurate.

  6. Preparation and controlled drug delivery applications of mesoporous silica polymer nanocomposites through the visible light induced surface-initiated ATRP

    Science.gov (United States)

    Huang, Long; Liu, Meiying; Mao, Liucheng; Xu, Dazhuang; Wan, Qing; Zeng, Guangjian; Shi, Yingge; Wen, Yuanqing; Zhang, Xiaoyong; Wei, Yen

    2017-08-01

    The mesoporous materials with large pore size, high specific surface area and high thermal stability have been widely utilized in a variety of fields ranging from environmental remediation to separation and biomedicine. However, surface modification of these silica nanomaterials is required to endow novel properties and achieve better performance for most of these applications. In this work, a new method has been established for surface modification of mesoporous silica nanoparticles (MSNs) that relied on the visible light induced atom transfer radical polymerization (ATRP). In the procedure, the copolymers composited with itaconic acid (IA) and poly(ethylene glycol)methyl acrylate (PEGMA) were grafted from MSNs using IA and PEGMA as the monomers and 10-Phenylphenothiazine(PTH) as the organic catalyst. The successful preparation of final polymer nanocomposites (named as MSNs-NH2-poly(IA-co-PEGMA)) were evidenced by a series of characterization techniques. More importantly, the anticancer agent cisplatin can be effectively loaded on MSNs-NH2-poly(IA-co-PEGMA) and controlled release it from the drug-loading composites with pH responsive behavior. As compared with conventional ATRP, the light induced surface-initiated ATRP could also be utilized for preparation of various silica polymer nanocomposites under rather benign conditions (e.g. absent of transition metal ions, low polymerization temperature and short polymerization time). Taken together, we have developed a rather promising strategy method for fabrication of multifunctional MSNs-NH2-poly(IA-co-PEGMA) with great potential for biomedical applications.

  7. A quality-control procedure for surface temperature and surface layer inversion in the XBT data archive from the Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Pankajakshan, T.; Ghosh, A.K.; Pattanaik, J.; Ratnakaran, L.

    and surface layer temperature inversion. XBT surface temperatrues (XST) are compared with the surface temperature from simultaneous CTD observations from four cruises and the former were found to be erroneous in a number of stations. XSTs are usually corrected...

  8. Surface modification of an epoxy resin with polyamines and polydopamine: The effect on the initial electroless copper deposition

    Science.gov (United States)

    Schaubroeck, David; Mader, Lothar; De Geyter, Nathalie; Morent, Rino; Dubruel, Peter; Vanfleteren, Jan

    2014-06-01

    This paper describes the influence of polydopamine and polyamine surface modifications of an etched epoxy cresol novolak (ECN) resin on the initial electroless copper deposition. Three different strategies to introduce polyamines on a surface in aqueous environment are applied: via polyethyleneimine adsorption (PEI), via polydopamine and via polyamines grafted to polydopamine. Next, the influence of these surface modifications on the catalytic palladium activation is investigated through X-ray photoelectron spectroscopy (XPS) analysis. Finally, the initial electroless copper deposition on modified epoxy surfaces is evaluated using SEM and Energy Dispersive Spectroscopy (EDS). Grafted polyamines on polydopamine surface modifications result in a large increase of the initial deposited copper.

  9. Initial Temperature and Extent of Chemical Equilibration of Partons in Relativistic Collision of Heavy Nuclei

    CERN Document Server

    Srivastava, Dinesh K; Mustafa, Munshi G

    2016-01-01

    We emphasize that a knowledge of energy and entropy densities of quark gluon plasma - a thermalized de-confined matter, formed in relativistic heavy ion collisions fixes the formation temperature and the product of gluon fugacity and formation time uniquely, {\\em provided} we know the relative fugacities of quarks and gluons. This also provides that a smaller formation time would imply larger fugacities for partons. Next we explore the limits of chemical equilibration of partons during the initial stages in relativistic collision of heavy nuclei. The experimentally measured rapidity densities of transverse energy and charged particle multiplicity at RHIC and LHC energies are used to estimate the energy and number densities with the assumption of formation of a thermally equilibrated quark gluon plasma which may be chemically equilibrated to the same or differing extents for quarks and gluons. The estimates are found to be very sensitive to the correction factor used for the Bj\\"{o}rken energy density for iden...

  10. Initial estimation of hydrate formation temperature of sweet natural gases based on new empirical correlation

    Institute of Scientific and Technical Information of China (English)

    Mohammad Mahdi Ghiasi

    2012-01-01

    Production,processing and transportation of natural gases can be significantly affected by clathrate hydrates.Knowing the gas analysis is crucial to predict the right conditions for hydrate formation.Nevertheless,Katz gas gravity method can be used for initial estimation of hydrate formation temperature (HFT) under the circumstances of indeterminate gas composition.So far several correlations have been proposed for gas gravity method,in which the most accurate and reliable one has belonged to Bahadori and Vuthaluru.The main objective of this study is to present a simple and yet accurate correlation for fast prediction of sweet natural gases HFT based on the fit to Katz gravity chart.By reviewing the error analysis results,one can discover that the new proposed correlation has the best estimation capability among the widely accepted existing correlations within the investigated range.

  11. Temperature Calculation in Respect of Basic Elements of Power Oil Transformer on the Basis of Its Tank Surface Temperature Analysis

    Directory of Open Access Journals (Sweden)

    D. Zalizny

    2012-01-01

    Full Text Available The paper proposes a real-time calculation algorithm of oil, winding and magnetic core temperature of power transformer on the basis of measured values of tank surface temperature and air temperature without measuring current. The algorithm is based on the calculation of the equivalent load factor of the transformer. Imitation simulation has confirmed efficiency of the algorithm. After tests on functioning transformers the algorithm can be used in thermal protection devices and diagnostic devices for power oil transformers.

  12. Experimental measurement of surface temperatures during flame-jet induced thermal spallation

    Science.gov (United States)

    Wilkinson, M. A.; Tester, J. W.

    1993-01-01

    Thermal spallation is a method whereby the surface of a rock is rapidly heated causing small (100 1000 μm) flakes or spalls, to form. When applied to drilling, a supersonic, high temperature (2600 K) gas jet is directed at the rock to provide the heat source and sweep away the spalls. Previous studies of thermal spallation drilling indicate that penetration rates of up to 30 m/hr (100 ft/hr), approximately ten times greater than commonly obtained using conventional rotary mechanical methods, can be achieved in competent, non-fractured hard rock such as granite. A total direct operating cost for drilling in granite using a flame-jet spallation drill was estimated by Browning (1981) to be approximately 9/m in 1991 (about 3/ft) compared to “trouble-free” well drilling costs for conventional rotary methods in similar rock to depths of 3 to 7 km (10000 to 21000 ft) of 300 to 900/m (100 to 300/ft) (Tester and Herzog, 1990, 1992). The Browning estimates for spallation drilling are obviously optimistic in that they don't include capital costs for the rig and associated hardware. However, the substantially higher penetration rates, significantly reduced wear of downhole components, and the high efficiency of rock communition in comparison to rotary methods suggest that substantial cost reductions could be possible in deep drilling applications. For example, in the construction of hot dry rock geothermal power plants where rotary mechanical methods are used for well drilling to depths of (4 to 5 km), about half of the initial capital cost would be required for well drilling alone (Tester and Herzog, 1992). The current study has focused on gaining a better understanding of both the rock failure mechanism that occurs during thermal spallation and the heat transfer from the gas jet to the rock surface. Rock mechanics modeling leads to an expression for the surface temperature during spallation as a function of rock physical properties and the incident heat flux. Surface

  13. A framework for global diurnally-resolved observations of Land Surface Temperature

    Science.gov (United States)

    Ghent, Darren; Remedios, John

    2014-05-01

    Land surface temperature (LST) is the radiative skin temperature of the land, and is one of the key parameters in the physics of land-surface processes on regional and global scales. Being a key boundary condition in land surface models, which determine the surface to atmosphere fluxes of heat, water and carbon; thus influencing cloud cover, precipitation and atmospheric chemistry predictions within Global models, the requirement for global diurnal observations of LST is well founded. Earth Observation satellites offer an opportunity to obtain global coverage of LST, with the appropriate exploitation of data from multiple instruments providing a capacity to resolve the diurnal cycle on a global scale. Here we present a framework for the production of global, diurnally resolved, data sets for LST which is a key request from users of LST data. We will show how the sampling of both geostationary and low earth orbit data sets could conceptually be employed to build combined, multi-sensor, pole-to-pole data sets. Although global averages already exist for individual instruments and merging of geostationary based LST is already being addressed operationally (Freitas, et al., 2013), there are still a number of important challenges to overcome. In this presentation, we will consider three of the issues still open in LST remote sensing: 1) the consistency amongst retrievals; 2) the clear-sky bias and its quantification; and 3) merging methods and the propagation of uncertainties. For example, the combined use of both geostationary earth orbit (GEO) and low earth orbit (LEO) data, and both infra-red and microwave data are relatively unexplored but are necessary to make the most progress. Hence this study will suggest what is state-of-the-art and how considerable advances can be made, accounting also for recent improvements in techniques and data quality. The GlobTemperature initiative under the Data User Element of ESA's 4th Earth Observation Envelope Programme (2013

  14. Sea surface height anomaly and upper ocean temperature over the Indian Ocean during contrasting monsoons

    Science.gov (United States)

    Gera, Anitha; Mitra, A. K.; Mahapatra, D. K.; Momin, I. M.; Rajagopal, E. N.; Basu, Swati

    2016-09-01

    Recent research emphasizes the importance of the oceanic feedback to monsoon rainfall over the Asian landmass. In this study, we investigate the differences in the sea surface height anomaly (SSHA) and upper ocean temperature over the tropical Indian Ocean during multiple strong and weak monsoons. Analysis of satellite derived SSHA, sea surface temperature (SST) and ocean reanalysis data reveals that patterns of SSHA, SST, ocean temperature, upper ocean heat content (UOHC) and propagations of Kelvin and Rossby waves differ during strong and weak monsoon years. During strong monsoons positive SSH, SST and UOHC anomalies develop over large parts of north Indian Ocean whereas during weak monsoons much of the north Indian Ocean is covered with negative anomalies. These patterns can be used as a standard tool for evaluating the performance of coupled and ocean models in simulating & forecasting strong and weak monsoons. The rainfall over central India is found to be significantly correlated with SSHA over the regions (Arabian Sea and West central Indian Ocean and Bay of Bengal) where SSHA is positively large during strong monsoons. The SST-SSHA correlation is also very strong over the same area. The study reveals that much convection takes place over these regions during strong monsoons. In contrast during weak monsoons, convection takes place over eastern equatorial region. These changes in SST are largely influenced by oceanic Kelvin and Rossby waves. The Rossby waves initiated in spring at the eastern boundary propagate sub-surface heat content in the ocean influencing SST in summer. The SST anomalies modulate the Hadley circulation and the moisture transport thereby contributing to rainfall over central India. Therefore oceanic Kelvin and Rossby waves influence the rainfall over central India.

  15. Measuring the temperature of high-luminous exitance surfaces with infrared thermography in LED applications

    Science.gov (United States)

    Perera, Indika U.; Narendran, Nadarajah

    2016-09-01

    Recently, light-emitting diode (LED) lighting systems have become popular due to their increased system performance. LED lighting system performance is affected by heat; therefore, it is important to know the temperature of a target surface or bulk medium in the LED system. In-situ temperature measurements of a surface or bulk medium using intrusive methods cause measurement errors. Typically, thermocouples are used in these applications to measure the temperatures of the various components in an LED system. This practice leads to significant errors, specifically when measuring surfaces with high-luminous exitance. In the experimental study presented in this paper, an infrared camera was used as an alternative to temperature probes in measuring LED surfaces with high-luminous exitance. Infrared thermography is a promising method because it does not respond to the visible radiation spectrum in the range of 0.38 to 0.78 micrometers. Usually, infrared thermography equipment is designed to operate either in the 3 to 5 micrometer or the 7 to 14 micrometer wavelength bands. To characterize the LED primary lens, the surface emissivity of the LED phosphor surface, the temperature dependence of the surface emissivity, the temperature of the target surface compared to the surrounding temperature, the field of view of the target, and the aim angle to the target surface need to be investigated, because these factors could contribute towards experimental errors. In this study, the effects of the above-stated parameters on the accuracy of the measured surface temperature were analyzed and reported.

  16. Low temperature gaseous surface hardening of stainless steel

    DEFF Research Database (Denmark)

    Christiansen, Thomas; Somers, Marcel A. J.

    2011-01-01

    The present contribtion gives an overview of some of the technological aspects of low temperature thermochemical treatment of stainless steel. Examples of low temperature gaseous nitriding, carburising and nitrocarburising of stainless steel are presented and discussed. In particular......, the morphology, microstructure and characteristics of so-called expanded austenite "layers" on stainless steel are addressed....

  17. Low temperature gaseous surface hardening of stainless steel

    DEFF Research Database (Denmark)

    Christiansen, Thomas; Somers, Marcel A. J.

    2010-01-01

    The present contribution gives an overview of some of the technological aspects of low temperature thermochemical treatment of stainless steel. Examples of low temperature gaseous nitriding, carburising and nitrocarburising of stainless steel are presented and discussed. In particular......, the morphology, microstructure and characteristics of so-called expanite “layers” on stainless steel are addressed....

  18. Remote Sensing and Synchronous Land Surface Measurements of Soil Moisture and Soil Temperature in the Field

    Science.gov (United States)

    Kolev, N. V.; Penev, K. P.; Kirkova, Y. M.; Krustanov, B. S.; Nazarsky, T. G.; Dimitrov, G. K.; Levchev, C. P.; Prodanov, H. I.; Kraleva, L. H.

    1998-01-01

    The paper presents the results of remote sensing and synchronous land surface measurements for estimation of soil (surface and profile) water content and soil temperature for different soil types in Bulgaria. The relationship between radiometric temperature and soil surface water content is shown. The research is illustrated by some results from aircraft and land surface measurements carried out over three test areas near Pleven, Sofia and Plovdiv, respectively, during the period 1988-1990.

  19. Predicting uncertainty in sediment transport and landscape evolution - the influence of initial surface conditions

    Science.gov (United States)

    Hancock, G. R.; Coulthard, T. J.; Lowry, J. B. C.

    2016-05-01

    Numerical landscape evolution models were initially developed to examine natural catchment hydrology and geomorphology and have become a common tool to examine geomorphic behaviour over a range of time and space scales. These models all use a digital elevation model (DEM) as a representation of the landscape surface and a significant issue is the quality and resolution of this surface. Here we focus on how subtle perturbations or roughness on the DEM surface can produce alternative model results. This study is carried out by randomly varying the elevations of the DEM surface and examining the effect on sediment transport rates and geomorphology for a proposed rehabilitation design for a post-mining landscape using multiple landscape realisations with increasing magnitudes of random changes. We show that an increasing magnitude of random surface variability does not appear to have any significant effect on sediment transport over millennial time scales. However, the random surface variability greatly changes the temporal pattern or delivery of sediment output. A significant finding is that all simulations at the end of the 10,000 year modelled period are geomorphologically similar and present a geomorphological equifinality. However, the individual patterns of erosion and deposition were different for repeat simulations with a different sequence of random perturbations. The alternative positions of random perturbations strongly influence local patterns of hillslope erosion and evolution together with the pattern and behaviour of deposition. The findings demonstrate the complex feedbacks that occur even within a simple modelled system.

  20. MMA/DVB emulsion surface graft polymerization initiated by UV light.

    Science.gov (United States)

    Wang, Yongxin; Yang, Wantai

    2004-07-20

    Methyl methacrylate/1,2-divinylbenzene (MMA/DVB) in an opaque emulsion were successfully grafted onto the surface of polymeric substrate under the irradiation of UV light with benzophenone (BP) as a photoinitiator that was previously coated on the substrate surface. Monomer conversion, grafting efficiency, and grafting yields were determined by the gravimetric method. ATR-IR, AFM, and TEM were used to characterize the surface composition, to observe the topography of the grafted substrates, and to view inter-film colloid particles formed by cross-linking. The results reveal that, with the opaque MMA/DVB emulsion system and CPP film as substrate, the monomer conversion is in the range of 15-55%, the grafting efficiency is about 80%, the grafting yield reaches 5%, and the thickness of the graft layer can be controlled in the range 0.09-1.5 microm. Images of AFM show that the graft layer is piled up by nanoparticles (about 30-50 nm in diameter), which are linked together and tied to the substrate surface with covalent bonds. A possible model of surface graft polymerization including surface initiating, nucleation, and shish kebab growing is put forward to interpreting the above results.

  1. Molecular Dynamics Simulations of the Initial Adsorption Stages of Fibrinogen on Mica and Graphite Surfaces.

    Science.gov (United States)

    Köhler, Stephan; Schmid, Friederike; Settanni, Giovanni

    2015-12-01

    Fibrinogen, a blood glycoprotein of vertebrates, plays an essential role in blood clotting by polymerizing into fibrin when activated. Upon adsorption on material surfaces, it also contributes to determine their biocompatibility and has been implicated in the onset of thrombosis and inflammation at medical implants. Here we present the first fully atomistic simulations of the initial stages of the adsorption process of fibrinogen on mica and graphite surfaces. The simulations reveal a weak adsorption on mica that allows frequent desorption and reorientation events. This adsorption is driven by electrostatic interactions between the protein and the silicate surface as well as the counterion layer. Preferred adsorption orientations for the globular regions of the protein are identified. The adsorption on graphite is found to be stronger with fewer reorientation and desorption events and shows the onset of denaturation of the protein.

  2. On the initial condition problem of the time domain PMCHWT surface integral equation

    KAUST Repository

    Uysal, Ismail E.

    2017-05-13

    Non-physical, linearly increasing and constant current components are induced in marching on-in-time solution of time domain surface integral equations when initial conditions on time derivatives of (unknown) equivalent currents are not enforced properly. This problem can be remedied by solving the time integral of the surface integral for auxiliary currents that are defined to be the time derivatives of the equivalent currents. Then the equivalent currents are obtained by numerically differentiating the auxiliary ones. In this work, this approach is applied to the marching on-in-time solution of the time domain Poggio-Miller-Chan-Harrington-Wu-Tsai surface integral equation enforced on dispersive/plasmonic scatterers. Accuracy of the proposed method is demonstrated by a numerical example.

  3. Long-range cross-correlation between urban impervious surfaces and land surface temperatures

    Institute of Scientific and Technical Information of China (English)

    Qin NIE; Jianhua XU; Wang MAN

    2016-01-01

    The thermal effect of urban impervious surfaces (UIS) is a complex problem.It is thus necessary to study the relationship between UIS and land surface temperatures (LST) using complexity science theory and methods.This paper investigates the long-range cross-correlation between UIS and LST with detrended cross-correlation analysis and multifractal detrended cross-correlation analysis,utilizing data from downtown Shanghai,China.UIS estimates were obtained from linear spectral mixture analysis,and LST was retrieved through application of the mono-window algorithm,using Landsat Thematic Mapper and Enhanced Thematic Mapper Plus data for 1997-2010.These results highlight a positive long-range cross-correlation between UIS and LST across People's Square in Shanghai.LST has a long memory for a certain spatial range of UIS values,such that a large increment in UIS is likely to be followed by a large increment in LST.While the multifractal long-range cross-correlation between UIS and LST was observed over a longer time period in the W-E direction (2002-2010) than in the N-S (2007-2010),these observed correlations show a weakening during the study period as urbanization increased.

  4. Long-range cross-correlation between urban impervious surfaces and land surface temperatures

    Science.gov (United States)

    Nie, Qin; Xu, Jianhua; Man, Wang

    2016-03-01

    The thermal effect of urban impervious surfaces (UIS) is a complex problem. It is thus necessary to study the relationship between UIS and land surface temperatures (LST) using complexity science theory and methods. This paper investigates the long-range cross-correlation between UIS and LST with detrended cross-correlation analysis and multifractal detrended cross-correlation analysis, utilizing data from downtown Shanghai, China. UIS estimates were obtained from linear spectral mixture analysis, and LST was retrieved through application of the mono-window algorithm, using Landsat Thematic Mapper and Enhanced Thematic Mapper Plus data for 1997-2010. These results highlight a positive long-range cross-correlation between UIS and LST across People's Square in Shanghai. LST has a long memory for a certain spatial range of UIS values, such that a large increment in UIS is likely to be followed by a large increment in LST. While the multifractal long-range cross-correlation between UIS and LST was observed over a longer time period in the W-E direction (2002-2010) than in the N-S (2007-2010), these observed correlations show a weakening during the study period as urbanization increased.

  5. IDENTIFYING THE LOCAL SURFACE URBAN HEAT ISLAND THROUGH THE MORPHOLOGY OF THE LAND SURFACE TEMPERATURE

    Directory of Open Access Journals (Sweden)

    J. Wang

    2016-06-01

    Full Text Available Current characterization of the Land Surface Temperature (LST at city scale insufficiently supports efficient mitigations and adaptations of the Surface Urban Heat Island (SUHI at local scale. This research intends to delineate the LST variation at local scale where mitigations and adaptations are more feasible. At the local scale, the research helps to identify the local SUHI (LSUHI at different levels. The concept complies with the planning and design conventions that urban problems are treated with respect to hierarchies or priorities. Technically, the MODerate-resolution Imaging Spectroradiometer satellite image products are used. The continuous and smooth latent LST is first recovered from the raw images. The Multi-Scale Shape Index (MSSI is then applied to the latent LST to extract morphological indicators. The local scale variation of the LST is quantified by the indicators such that the LSUHI can be identified morphologically. The results are promising. It can potentially be extended to investigate the temporal dynamics of the LST and LSUHI. This research serves to the application of remote sensing, pattern analysis, urban microclimate study, and urban planning at least at 2 levels: (1 it extends the understanding of the SUHI to the local scale, and (2 the characterization at local scale facilitates problem identification and support mitigations and adaptations more efficiently.

  6. Low Friction Surfaces for Low Temperature Applications Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Lunar and other extraterrestrial environments put extreme demands on moving mechanical components. Gears must continue to function and surfaces must continue to...

  7. Temperature and detection-wavelength dependence of the electron transfer rates in initial stages of photosynthesis.

    Science.gov (United States)

    Kurzynski, Michal; Chelminiak, Przemyslaw

    2013-10-17

    Unusual temperature behavior, observed in the initial electron transfer stages in the photosynthetic reaction centers of the purple bacteria, and a strong probing pulse wavelength dependence of transfer rates, determined in transient absorption spectroscopy, can easily be explained on assuming that the transfer takes place from dynamically unrelaxed states of protein environment. The transitions from the primary special pair (P) to a single bacteriochlorophyll (B) and next to a bacteriopheophytin (H) are controlled by diffusion down the energy value of underdamped vibrational modes of frequency 200 K, probably determining distances between the succeeding cofactors. The subsequent transition to the quinone A (Q) is controlled by diffusion in the position value of an overdamped conformational mode, probably corresponding to the local polarization. From the fit of available experimental data to simple theoretical formulas, the important physical conclusion arises that the very electronic transitions are fast as compared to the relaxation processes and, in the first approximation, only the latter contribute to the overall times of the initial electron transfer stages in photosynthesis.

  8. Air temperature field distribution estimations over a Chinese mega-city using MODIS land surface temperature data: the case of Shanghai

    Science.gov (United States)

    Ma, Weichun; Zhou, Liguo; Zhang, Hao; Zhang, Yan; Dai, Xiaoyan

    2016-03-01

    The capability of obtaining spatially distributed air temperature data from remote sensing measurements is an improvement for many environmental applications focused on urban heat island, carbon emissions, climate change, etc. This paper is based on the MODIS/Terra and Aqua data utilized to study the effect of the urban atmospheric heat island in Shanghai, China. The correlation between retrieved MODIS land surface temperature (LST) and air temperature measured at local weather stations was initially studied at different temporal and spatial scales. Secondly, the air temperature data with spatial resolutions of 250 m and 1 km were estimated from MODIS LST data and in-situ measured air temperature. The results showed that there is a slightly higher correlation between air temperature and MODIS LST at a 250m resolution in spring and autumn on an annual scale than observed at a 1 km resolution. Although the distribution pattern of the air temperature thermal field varies in different seasons, the urban heat island (UHI) in Shanghai is characterized by a distribution pattern of multiple centers, with the central urban area as the primary center and the built-up regions in each district as the subcenters. This study demonstrates the potential not only for estimating the distribution of the air temperature thermal field from MODIS LST with 250 m resolution in spring and autumn in Shanghai, but also for providing scientific and effective methods for monitoring and studying UHI effect in a Chinese mega-city such as Shanghai.

  9. Investigating the Impacts of Surface Temperature Anomalies due to Burned Area Albedo in Northern sub-Saharan Africa

    Science.gov (United States)

    Gabbert, T.; Matsui, T.; Capehart, W. J.; Ichoku, C. M.; Gatebe, C. K.

    2015-12-01

    The northern Sub-Saharan African region (NSSA) is an area of intense focus due to periodic severe droughts that have dire consequences on the growing population, which relies mostly on rain fed agriculture for its food supply. This region's weather and hydrologic cycle are very complex and are dependent on the West African Monsoon. Different regional processes affect the West African Monsoon cycle and variability. One of the areas of current investigation is the water cycle response to the variability of land surface characteristics. Land surface characteristics are often altered in NSSA due to agricultural practices, grazing, and the fires that occur during the dry season. To better understand the effects of biomass burning on the hydrologic cycle of the sub-Saharan environment, an interdisciplinary team sponsored by NASA is analyzing potential feedback mechanisms due to the fires. As part of this research, this study focuses on the effects of land surface changes, particularly albedo and skin temperature, that are influenced by biomass burning. Surface temperature anomalies can influence the initiation of convective rainfall and surface albedo is linked to the absorption of solar radiation. To capture the effects of fire perturbations on the land surface, NASA's Unified Weather and Research Forecasting (NU-WRF) model coupled with NASA's Land Information System (LIS) is being used to simulate burned area surface albedo inducing surface temperature anomalies and other potential effects to environmental processes. Preliminary sensitivity results suggest an altered surface radiation budget, regional warming of the surface temperature, slight increase in average rainfall, and a change in precipitation locations.

  10. Surface modification of poly(vinyl chloride) by physisorbed free radical initiation for reduced plasticizer migration and antimicrobial properties

    Science.gov (United States)

    McGinty, Kathryn

    Poly(vinyl chloride), PVC, is a particularly important commodity polymer that accounts for an annual world-wide production of 26 million tons. It is used frequently in the medical field as blood storage bags, endotracheal and dialysis tubing and intravenous catheters. Common plasticizers, namely di(2-ethylhexyl) phthalate (DEHP), are added to PVC to improve the processability and flexibility by lowering the glass transition temperature. However, most phthalate plasticizers are potential carcinogens. There has been extensive research on PVC with surface coatings to improve biocompatibility, surface crosslinking to create a barrier to the plasticizer leaching and surface grafting of hydrophilic polymers for both biocompatibility and reduced plasticizer migration. A novel surface grafting technique is the grafting of hydrophilic monomers by physisorbed free radical initiators. This modification method can be applied to PVC to attach vinyl hydrophilic monomers by the "grafting from" method. This approach, extending on earlier work involving polymer brush formation on poly(dimethylsiloxane), involves a two-step process: physisorption of a hydrophobic free radical initiator onto a polymer surface followed by radical polymerization of hydrophilic monomers in water. The key step is creating a hydrophobic/hydrophilic diffusional barrier that promotes radical reactions at the polymer surface. Polymers that have been successfully grafted from PVC films and tubing include: poly(hydroxyethyl methacrylate) (PHEMA), poly(dimethylacrylamide) (PDMA), poly(hydroxyethyl acrylate) (PHEA), poly(dimethylaminoethyl methacrylate) (PDMAEMA), poly(acrylic acid) (PAA), and poly(4-vinylpyridine) (P4VP). Characterization methods performed include bulk chemical composition by transmission infrared spectroscopy, surface composition using X-ray photoelectron spectroscopy, surface wettability by tensiometry and capillary rise, film thickness determination by infrared, gravimetric analysis and UV

  11. Analysis of past surface temperature reconstructions based on the tree-ring chronologies and borehole temperature measurements

    Science.gov (United States)

    Nagornov, O. V.; Nikitaev, V. G.; Pronichev, A. N.; Tyuflin, S. A.; Bukharova, T. I.

    2016-06-01

    There have been done many past surface temperature reconstructions based on the temperature measurements in rock and glacier boreholes. However, the reliability of these reconstructions connected with the uniqueness and stability properties is not studied. We carried out the reconstruction by search of the past surface temperature in form of the finite set of the Fourier series that provides the unique and stable solution. The tree-ring chronologies are used as the high-resolution proxy climate indicator to find out the dominant periods of the Fourier series. The Tikhonov regularization method is applied to solve the inverse problem.

  12. Study on Influence of Initial Rolling Temperature for Rolling Process Based on Numerical Simulation

    Institute of Scientific and Technical Information of China (English)

    YANG Licheng; LIU Bo; XING Sufang; ZHANG Runli

    2006-01-01

    Wire rolling is a typical large deformation process and its principle is very complex, which includes material non-linearity, geometry non-linearity and boundary non-linearity. It is difficult to obtain theory analytical results by trying to roll or physical experiment because they will induce many problems such as high cost, waste time and venture. With the rapid advancement of computing technology and numerical method, the finite element method is regarded as the best one, which can account for the large plastic deformation, thermo-mechanical coupling and complex boundary conditions of the rollers and the workpiece interactions in the rolling process. Under the different initial rolling temperature, the two-pass hot continuous rolling process of high-speed wire has been simulated accurately for the pre-finishing rolling section. The metal fluxion law and the deformation field have been obtained. Strain, temperature, rolling force and torque also have been simulated and discussed. The results of simulation are useful for practical manufacture and the optimization of process-parameters.

  13. Subduction Initiation from a Stagnant Lid: New Insights from Numerical Models with a Free Surface

    Science.gov (United States)

    Crameri, Fabio; Tackley, Paul

    2016-04-01

    Subduction initiation is key in understanding the dynamic evolution of the Earth and its fundamental difference to all other rocky planetary bodies in our solar system. Despite recent progress, the question about how a stiff, mostly stagnant planetary lid can break and become part in the global overturn of the mantle is still unresolved. Here, we present results on subduction initiation obtained by dynamically self-consistent, time-dependent numerical modelling of mantle convection and single-sided subduction (Crameri et al., 2012b) using the finite-difference, multigrid code StagYY (Tackley 2008). We show that the stress distribution and resulting deformation of the lithosphere is strongly controlled by the top boundary formulation: A free surface enables surface topography and plate bending, increases gravitational sliding of the plates and leads to more realistic, lithosphere-scale shear zones. As a consequence, subduction initiation induced by regional mantle flow is significantly favoured by a free surface compared to the commonly-applied, vertically-fixed (i.e., free-slip) surface. In addition, we present global, three-dimensional mantle convection experiments (see e.g. Crameri and Tackley, 2014) that employ basal heating that leads to narrow mantle plumes. Narrow mantle plumes impinging on the base of the plate cause locally weak plate segments and a large topography at the lithosphere-asthenosphere boundary. Both are shown to be key to induce subduction initiation. Finally, our model self-consistently reproduces an episodic lid with a fast global overturn due to the hotter mantle developed below a former stagnant lid. We conclude that once in a stagnant-lid mode, a planet (like Venus) thus preferentially evolves by temporally discrete, global overturn events rather than by a continuous recycling of lid. REFERENCES Crameri, F, Tackley, P.J, Meilick, I, Gerya, T.V, Kaus, B.J.P (2012) A free plate surface and weak oceanic crust produce single-sided subduction

  14. Preparation of polymeric silica composites through polydopamine-mediated surface initiated ATRP for highly efficient removal of environmental pollutants

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Qiang; Liu, Meiying; Wan, Qing; Jiang, Ruming; Mao, Liucheng; Zeng, Guangjian; Huang, Hongye; Deng, Fengjie [Department of Chemistry, Nanchang University, 999 Xuefu Avenue, Nanchang 330031 (China); Zhang, Xiaoyong, E-mail: xiaoyongzhang1980@gmail.com [Department of Chemistry, Nanchang University, 999 Xuefu Avenue, Nanchang 330031 (China); Wei, Yen [Department of Chemistry and the Tsinghua Center for Frontier Polymer Research, Tsinghua University, Beijing 100084 (China)

    2017-06-01

    In this study, we developed a new procedure to prepare monodispersed functionalized SiO{sub 2} (SiO{sub 2}-PDA-PDMC) composites via mussel inspired chemistry and surface initiated atom transfer radical polymerization (SI-ATRP). Samples were characterized by transmission electron microscope (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS) and thermal gravimetric analysis (TGA) measurements. TEM results showed that spherical morphology was unchanged after the functionalization. FT-IR results confirmed the successful modification with polydopamine (PDA) and the presence of poly-([2-(Methacryloyloxy) ethyl] trimethylammonium chloride) (PDMC) layer on the surface of SiO{sub 2} spheres. TGA data showed that the PDMC account for about 12.12 wt% in the sample of SiO{sub 2}-PDA-PDMC composites. The XPS analysis further confirmed the existence of PDMC on the surface of SiO{sub 2}-PDA-PDMC composites. The obtained SiO{sub 2}-PDA-PDMC composites were used as adsorbent for the removal of Congo red (CR) from aqueous solution to evaluate the performance in environment application. The effect of contact time, solution pH, initial CR concentration and temperature on the adsorption of CR onto SiO{sub 2}-PDA-PDMC composites was investigated. Adsorption results demonstrated that adsorption of CR onto SiO{sub 2}-PDA-PDMC composites was a fast and efficient process. The adsorption equilibrium reached within 60 min, and the adsorption process followed the pseudo-second-order model. The experimental data of isotherms were better described by the Freundlich model. Thermodynamic study depicted the endothermic nature of adsorption and the process was spontaneous. Results from the effect of solution pH on the CR adsorption showed that the acidic condition favors the adsorption and provided evidence for the contribution of PDMC on the SiO{sub 2}-PDA-PDMC composites in the removal of CR. This study suggests SiO{sub 2}-PDA-PDMC composites can be

  15. Fast and slow responses of Southern Ocean sea surface temperature to SAM in coupled climate models

    Science.gov (United States)

    Kostov, Yavor; Marshall, John; Hausmann, Ute; Armour, Kyle C.; Ferreira, David; Holland, Marika M.

    2017-03-01

    We investigate how sea surface temperatures (SSTs) around Antarctica respond to the Southern Annular Mode (SAM) on multiple timescales. To that end we examine the relationship between SAM and SST within unperturbed preindustrial control simulations of coupled general circulation models (GCMs) included in the Climate Modeling Intercomparison Project phase 5 (CMIP5). We develop a technique to extract the response of the Southern Ocean SST (55°S-70°S) to a hypothetical step increase in the SAM index. We demonstrate that in many GCMs, the expected SST step response function is nonmonotonic in time. Following a shift to a positive SAM anomaly, an initial cooling regime can transition into surface warming around Antarctica. However, there are large differences across the CMIP5 ensemble. In some models the step response function never changes sign and cooling persists, while in other GCMs the SST anomaly crosses over from negative to positive values only 3 years after a step increase in the SAM. This intermodel diversity can be related to differences in the models' climatological thermal ocean stratification in the region of seasonal sea ice around Antarctica. Exploiting this relationship, we use observational data for the time-mean meridional and vertical temperature gradients to constrain the real Southern Ocean response to SAM on fast and slow timescales.

  16. Torrential precipitations on the Spanish east coast: The role of the Mediterranean sea surface temperature

    Science.gov (United States)

    Millán, M.; Estrela, M. J.; Caselles, V.

    Floods constitute one of the most important natural risks on the Spanish Mediterranean coast. Although it is very difficult to avoid them, a correct understanding of their principal cause, which is torrential rain, can facilitate their prediction and in this way avoid, at least partially, their catastrophic effects (both loss of human lives and material damage). The work presented here is part of a more extensive study underway in the CEAM (Centro de Estudios Ambientales del Mediterráneo). Its objective is the analysis of the conditions that produce torrential precipitations. These can be explained by the hypothesis of the Back Door Front, a mechanism which on its own permits the development of a potentially unstable mass above the Mediterranean sea. Among the different factors that are valued in this hypothesis, the Sea Surface Temperature is considered to play an important role. It is studied by means of satellite images since this is the only technique that permits a synoptic view of this parameter. NOAH satellite images have been used, applying the split-window operative technique. This work presents initial results that confirm the importance of the Sea Surface Temperature (SST) as a moisture source in the Mediterranean cyclogenesis.

  17. Computational simulation of surface waviness in graphite/epoxy woven composites due to initial curing

    Science.gov (United States)

    Sanfeliz, Jose G.; Murthy, Pappu L. N.; Chamis, Christos C.

    1992-01-01

    Several models simulating plain weave, graphite/epoxy woven composites are presented, along with the effects that the simultaneous application of pressure and thermal loads have on their surfaces. The surface effects created by moisture absorption are also examined. The computational simulation consisted of using a two-dimensional finite element model for the composite. The properties of the finite element (FE) model are calculated by using the in-house composite mechanics computer code ICAN (Integrated Composite ANalyzer). MSC/NASTRAN is used for the FE analysis which yields the composite's top surface normalized displacements. These results demonstrate the importance of parameters such as the cure temperature (T sub o) and the resin content in the curing process of polymer-matrix composites. The modification of these parameters will help tailor the composite system to the desired requirements and applications.

  18. Importance of initial buoyancy field on evolution of mantle thermal structure:Implications of surface boundary conditions

    Institute of Scientific and Technical Information of China (English)

    Petar Glisovic; Alessandro M. Forte

    2015-01-01

    Although there has been significant progress in the seismic imaging of mantle heterogeneity, the outstanding issue that remains to be resolved is the unknown distribution of mantle temperature anomalies in the distant geological past that give rise to the present-day anomalies inferred by global tomography models. To address this question, we present 3-D convection models in compressible and self-gravitating mantle initialised by different hypothetical temperature patterns. A notable feature of our forward convection modelling is the use of self-consistent coupling of the motion of surface tectonic plates to the underlying mantle flow, without imposing prescribed surface velocities (i.e., plate-like boundary condition). As an approximation for the surface mechanical conditions before plate tectonics began to operate we employ the no-slip (rigid) boundary condition. A rigid boundary condition dem-onstrates that the initial thermally-dominated structure is preserved, and its geographical location is fixed during the evolution of mantle flow. Considering the impact of different assumed surface boundary conditions (rigid and plate-like) on the evolution of thermal heterogeneity in the mantle we suggest that the intrinsic buoyancy of seven superplumes is most-likely resolved in the tomographic images of present-day mantle thermal structure. Our convection simulations with a plate-like boundary condition reveal that the evolution of an initial cold anomaly beneath the Java-Indonesian trench system yields a long-term, stable pattern of thermal heterogeneity in the lowermost mantle that resembles the present-day Large Low Shear Velocity Provinces (LLSVPs), especially below the Pacific. The evolution of sub-duction zones may be, however, influenced by the mantle-wide flow driven by deeply-rooted and long-lived superplumes since Archean times. These convection models also detect the intrinsic buoyancy of the Perm Anomaly that has been identified as a unique slow feature

  19. Climate change impact of livestock CH4 emission in India: Global temperature change potential (GTP) and surface temperature response.

    Science.gov (United States)

    Kumari, Shilpi; Hiloidhari, Moonmoon; Kumari, Nisha; Naik, S N; Dahiya, R P

    2017-09-12

    Two climate metrics, Global surface Temperature Change Potential (GTP) and the Absolute GTP (AGTP) are used for studying the global surface temperature impact of CH4 emission from livestock in India. The impact on global surface temperature is estimated for 20 and 100 year time frames due to CH4 emission. The results show that the CH4 emission from livestock, worked out to 15.3 Tg in 2012. In terms of climate metrics GTP of livestock-related CH4 emission in India in 2012 were 1030 Tg CO2e (GTP20) and 62 Tg CO2e (GTP100) at the 20 and 100 year time horizon, respectively. The study also illustrates that livestock-related CH4 emissions in India can cause a surface temperature increase of up to 0.7mK and 0.036mK over the 20 and 100 year time periods, respectively. The surface temperature response to a year of Indian livestock emission peaks at 0.9mK in the year 2021 (9 years after the time of emission). The AGTP gives important information in terms of temperature change due to annual CH4 emissions, which is useful when comparing policies that address multiple gases. Copyright © 2017 Elsevier Inc. All rights reserved.

  20. A simple interpretation of the surface temperature/vegetation index space for assessment of surface moisture status

    DEFF Research Database (Denmark)

    Sandholt, Inge; Rasmussen, Kjeld; Andersen, Jens Asger

    2002-01-01

    A simplified land surface dryness index (Temperature-Vegetation Dryness Index, TVDI) based on an empirical parameterisation of the relationship between surface temperature (T-s) and vegetation index (NDVI) is suggested. The index is related to soil moisture and, in comparison to existing interpre......A simplified land surface dryness index (Temperature-Vegetation Dryness Index, TVDI) based on an empirical parameterisation of the relationship between surface temperature (T-s) and vegetation index (NDVI) is suggested. The index is related to soil moisture and, in comparison to existing...... interpretations of the T-s/NDVI space, the index is conceptually and computationally straightforward. It is based on satellite derived information only, and the potential for operational application of the index is therefore large. The spatial pattern and temporal evolution in TVDI has been analysed using 37 NOAA...

  1. Using radiometric surface temperature for surface energy flux estimation in Mediterranean drylands from a two-source perspective

    DEFF Research Database (Denmark)

    Morillas, L.; Garcia Garcia, Monica; Nieto Solana, Hector;

    2013-01-01

    A two-source model (TSM) for surface energy balance, considering explicitly soil and vegetation components, was tested under water stress conditions. The TSM evaluated estimates the sensible heat flux (H) using the surface-air thermal gradient and the latent heat flux (LE) as a residual from...... and parallel; as well as the iterative algorithm included in the TSM to disaggregate the soil-surface composite temperature into its separate components. Continuous field measurements of composite soil-vegetation surface temperature (T) and bare soil temperature (T) from thermal infrared sensors were used...... T and the simplified version that uses separate inputs of T and T' were minor. This demonstrates the robustness of the iterative procedure to disaggregate a composite soil-vegetation temperature into separate soil and vegetation components in semiarid environments with good prospects for image...

  2. Bayesian Estimation for Land Surface Temperature Retrieval: The Nuisance of Emissivities

    CERN Document Server

    Morgan, J A

    2004-01-01

    An approach to the remote sensing of land surface temperature is developed using the methods of Bayesian inference. The starting point is the maximum entropy estimate for the posterior distribution of radiance in multiple bands. In order to convert this quantity to an estimator for surface temperature and emissivity with Bayes' theorem, it is necessary to obtain the joint prior probability for surface temperature and emissivity, given available prior knowledge. The requirement that any pair of distinct observers be able to relate their descriptions of radiance under arbitrary Lorentz transformations uniquely determines the prior probability. Perhaps surprisingly, surface temperature acts as a scale parameter, while emissivity acts as a location parameter, giving the prior probability P(T,emissivity|K)=const./T dT d(emissivity). Given this result, it is a simple matter to construct estimators for surface temperature and emssivity. Monte Carlo simulations of land surface temeprature retrieval in selected MODIS ...

  3. Dynamic behavior of a vibrated droplet on a low-temperature micropillared surface

    Science.gov (United States)

    Tan, Chen-chuan; Jia, Zhi-hai; Yang, Hui-nan; Zhang, Zhi-tao

    2017-02-01

    The dynamic behavior of a vibrated droplet on a micropillared hydrophobic surface under low temperature was investigated in this paper. It was observed that solidified time of droplets on the micropillared surface were much larger than on the smooth surface due to the existence of wetting transition at low temperature, without vibration. The solidified time of droplets was longer while vibration was exerted on the surfaces, even though the wetting transition time of droplets at low temperature was shorter than at room temperature. It was found that resonance frequency of droplet increased as surface tension increased due to low temperature. Moreover, when a droplet was in its resonance frequency, the wetting area between the droplet and the micropillared surface increased obviously and its solidified time decreased substantially, and it led to the decline of anti-icing performance. This work is helpful to design a more efficient anti-icing device.

  4. Predicting temperature timit values for cold touchable surfaces

    NARCIS (Netherlands)

    Hartog, E.A. den

    2005-01-01

    During some occupational activities, workers have to handle objects or tools in cold environments. In other circumstances, contact between the hand and the cold surface might be accidental (e.g., when a worker touches a cold surface, a cooler, etc). In both cases, contact between the hands and the c

  5. High-Emissivity Coatings For High-Temperature Surfaces

    Science.gov (United States)

    Deininger, William D.; King, David Q.

    1988-01-01

    Plasma-sprayed coatings increase cooling by thermal radiation. Coating of zirconium diboride on tungsten or molybdenum increases emissivity of surface to more than 0.6 at 2,000 degree C. Applied by plasma-arc spraying after surface cleaned and roughened to ensure adhesion.

  6. FLOW VELOCITY AND SURFACE TEMPERATURE EFFECTS ON CONVECTIVE HEAT TRANSFER COEFFICIENT FROM URBAN CANOPY SURFACES BY NUMERICAL SIMULATION

    Directory of Open Access Journals (Sweden)

    Sivaraja Subramania Pillai

    2013-01-01

    Full Text Available This study investigates the effect of flow velocity and building surface temperature effects on Convective Heat Transfer Coefficient (CHTC from urban building surfaces by numerical simulation. The thermal effects produced by geometrical and physical properties of urban areas generate a relatively differential heating and uncomfortable environment compared to rural regions called as Urban Heat Island (UHI phenomena. The urban thermal comfort is directly related to the CHTC from the urban canopy surfaces. This CHTC from urban canopy surfaces expected to depend upon the wind velocity flowing over the urban canopy surfaces, urban canopy configurations, building surface temperature etc. But the most influential parameter on CHTC has not been clarified yet. Urban canopy type experiments in thermally stratified wind tunnel have normally been used to study the heat transfer issues. But, it is not an easy task in wind tunnel experiments to evaluate local CHTC, which vary on individual canyon surfaces such as building roof, walls and ground. Numerical simulation validated by wind tunnel experiments can be an alternative for the prediction of CHTC from building surfaces in an urban area. In our study, wind tunnel experiments were conducted to validate the low-Reynolds-number k- ε model which was used for the evaluation of CHTC from surfaces. The calculated CFD results showed good agreement with experimental results. After this validation, the effects of flow velocity and building surface temperature effects on CHTC from urban building surfaces were investigated. It has been found that the change in velocity remarkably affects the CHTC from urban canopy surfaces and change in surface temperature has almost no effect over the CHTC from urban canopy surfaces.

  7. FLOW VELOCITY AND SURFACE TEMPERATURE EFFECTS ON CONVECTIVE HEAT TRANSFER COEFFICIENT FROM URBAN CANOPY SURFACES BY NUMERICAL SIMULATION

    Directory of Open Access Journals (Sweden)

    Sivaraja Subramania Pillai

    2013-06-01

    Full Text Available This study investigates the effect of flow velocity and building surface temperature effects on Convective Heat Transfer Coefficient (CHTC from urban building surfaces by numerical simulation. The thermal effects produced by geometrical and physical properties of urban areas generate a relatively differential heating and uncomfortable environment compared to rural regions called as Urban Heat Island (UHI phenomena. The urban thermal comfort is directly related to the CHTC from the urban canopy surfaces. This CHTC from urban canopy surfaces expected to depend upon the wind velocity flowing over the urban canopy surfaces, urban canopy configurations, building surface temperature etc. But the most influential parameter on CHTC has not been clarified yet. Urban canopy type experiments in thermally stratified wind tunnel have normally been used to study the heat transfer issues. But, it is not an easy task in wind tunnel experiments to evaluate local CHTC, which vary on individual canyon surfaces such as building roof, walls and ground. Numerical simulation validated by wind tunnel experiments can be an alternative for the prediction of CHTC from building surfaces in an urban area. In our study, wind tunnel experiments were conducted to validate the low-Reynolds-number k-ε model which was used for the evaluation of CHTC from surfaces. The calculated CFD results showed good agreement with experimental results. After this validation, the effects of flow velocity and building surface temperature effects on CHTC from urban building surfaces were investigated. It has been found that the change in velocity remarkably affects the CHTC from urban canopy surfaces and change in surface temperature has almost no effect over the CHTC from urban canopy surfaces.

  8. Long-Term High-Latitude Sea and Ice Surface Temperature Record from AVHRR GAC Data

    Science.gov (United States)

    Luis, C. S.; Dybkjær, G.; Eastwood, S.; Tonboe, R. T.; Høyer, J. L.

    2014-12-01

    Surface temperature is among the most important variables in the surface energy balance equation and it significantly affects the atmospheric boundary layer structure, the turbulent heat exchange and, over ice, the ice growth rate. Here we measure the surface temperature using thermal infrared sensors from 10-12 μm wavelength, a method whose primary limitation over sea ice is the detection of clouds. However, in the Arctic and around Antarctica there are very few conventional observations of surface temperature from buoys, and it is sometimes difficult to determine if the temperature is measured at the surface or within the snowpack, the latter of which often results in a warm bias. To reduce this bias, much interest is being paid to alternative remote sensing methods for monitoring high latitude surface temperature. We used Advanced Very High Resolution Radiometer (AVHRR) global area coverage (GAC) data to produce a high latitude sea surface temperature (SST), ice surface temperature (IST) and ice cap skin temperature dataset spanning 27 years (1982-2009). This long-term climate record is the first of its kind for IST. In this project we used brightness temperatures from the infrared channels of AVHRR sensors aboard NOAA and Metop polar-orbiting satellites. Surface temperatures were calculated using separate split window algorithms for day SST, night SST, and IST. The snow surface emissivity across all angles of the swath were simulated specifically for all sensors using an emission model. Additionally, all algorithms were tuned to the Arctic using simulated brightness temperatures from a radiative transfer model with atmospheric profiles and skin temperatures from European Centre for Medium-Range Forecasts (ECMWF) re-analysis data (ERA-Interim). Here we present the results of product quality as compared to in situ measurements from buoys and infrared radiometers, as well as a preliminary analysis of climate trends revealed by the record.

  9. Surface Variability of Short-wavelength Radiation and Temperature on Exoplanets around M Dwarfs

    Science.gov (United States)

    Zhang, Xin; Tian, Feng; Wang, Yuwei; Dudhia, Jimy; Chen, Ming

    2017-03-01

    It is a common practice to use 3D General Circulation Models (GCM) with spatial resolution of a few hundred kilometers to simulate the climate of Earth-like exoplanets. The enhanced albedo effect of clouds is especially important for exoplanets in the habitable zones around M dwarfs that likely have fixed substellar regions and substantial cloud coverage. Here, we carry out mesoscale model simulations with 3 km spatial resolution driven by the initial and boundary conditions in a 3D GCM and find that it could significantly underestimate the spatial variability of both the incident short-wavelength radiation and the temperature at planet surface. Our findings suggest that mesoscale models with cloud-resolving capability be considered for future studies of exoplanet climate.

  10. Numerical Simulation for Thermal Shock Resistance of Ultra-High Temperature Ceramics Considering the Effects of Initial Stress Field

    Directory of Open Access Journals (Sweden)

    Weiguo Li

    2011-01-01

    Full Text Available Taking the hafnium diboride ceramic as an example, the effects of heating rate, cooling rate, thermal shock initial temperature, and external constraint on the thermal shock resistance (TSR of ultra-high temperature ceramics (UHTCs were studied through numerical simulation in this paper. The results show that the external constraint has an approximately linear influence on the critical rupture temperature difference of UHTCs. The external constraint prepares a compressive stress field in the structure because of the predefined temperature field, and this compressive stress field relieves the tension stress in the structure when it is cooled down and then it improves the TSR of UHTCs. As the thermal shock initial temperature, a danger heating rate (or cooling rate exists where the critical temperature difference is the lowest.

  11. Changes in Temperature and Fate of Soil Organic Matter in an Andisol due to Soil Surface Burning

    Science.gov (United States)

    Obuchi, Atsuko; Nishimura, Taku; Mizoguchi, Masaru; Imoto, Hiromi; Miyazaki, Tsuyoshi

    This is a print of a camera-ready Japanese manuscript for the Transactions of JSIDRE. This will provide an example and directions for the layout and font size/style to be used. Please refer to this when preparing the headings, figures/table and text of your manuscript. The manuscript should be submitted on A4 size. Changes in temperature, soil moisture, and carbon and nitrogen contents were measured in Andisol under soil surface burning. Soil samples were packed into an unglazed cylinder of 15 cm inner diameter and 30 cm high. Charcoal was burned for 6 hours on the surface of the soil column. During the burning soil surface temperature rose to between 600-700°C. In initially wet soil, rise in soil temperature was retarded for a while at around 95-100°C. On the other hand, in initially dry Toyoura sand showed more rapid temperature increase without retardation. The temperature retardation in the wet soil could be caused by consumption of latent heat by vaporization of soil water. Rate of proceeding of the 100°C front was proportional to square root of the burning time. This indicates that higher the initial volumetric water content, shallower the depth affected by burning. Soil samples suffered temperature above 500°C still had total carbon and nitrogen contents of over 20 and 1 g kg-1, respectively, whereas the soil that was heated up to over 500°C by muffle furnace contained less than 0.4 and 0.1 g kg-1 of the carbon and nitrogen.

  12. Impact of high resolution land surface initialization in Indian summer monsoon simulation using a regional climate model

    Indian Academy of Sciences (India)

    C K Unnikrishnan; M Rajeevan; S Vijaya Bhaskara Rao

    2016-06-01

    The direct impact of high resolution land surface initialization on the forecast bias in a regional climatemodel in recent years over Indian summer monsoon region is investigated. Two sets of regional climatemodel simulations are performed, one with a coarse resolution land surface initial conditions and secondone used a high resolution land surface data for initial condition. The results show that all monsoonyears respond differently to the high resolution land surface initialization. The drought monsoon year2009 and extended break periods were more sensitive to the high resolution land surface initialization.These results suggest that the drought monsoon year predictions can be improved with high resolutionland surface initialization. Result also shows that there are differences in the response to the land surfaceinitialization within the monsoon season. Case studies of heat wave and a monsoon depression simulationshow that, the model biases were also improved with high resolution land surface initialization. Theseresults show the need for a better land surface initialization strategy in high resolution regional modelsfor monsoon forecasting.

  13. Influence of surface defects on the fatigue crack initiation in pearlitic steel

    Directory of Open Access Journals (Sweden)

    Toribio Jesús

    2014-06-01

    Full Text Available Tensile fatigue tests were performed under load control, with constant stress range Δσ on pearlitic steel wires, from the hot rolled bar to the commercial prestressing steel wire (which has undergone seven cold drawing steps. Results show that fatigue cracks in pearlitic steels initiate at the wire surface starting from small defects, whose size decreases with the drawing process. Fatigue cracks created from defects (initiation phase exhibit a fractographic appearance consisting of ductile microtearing events which can be classified as tearing topography surface or TTS, and exhibit a remarkably lower spacing in the prestressing steel wire than in the hot rolled bar. In addition, some S-N tests were performed in both material forms under a stress range of about half the yield strength. In these tests, the main part of the fatigue life corresponds to the propagation stage in the hot rolled bar whereas such a main part of the life is associated with the initiation stage in the case of the prestressing steel wire.

  14. A comparison of Argo nominal surface and near-surface temperature for validation of AMSR-E SST

    Science.gov (United States)

    Liu, Zenghong; Chen, Xingrong; Sun, Chaohui; Wu, Xiaofen; Lu, Shaolei

    2017-05-01

    Satellite SST (sea surface temperature) from the Advanced Microwave Scanning Radiometer for the Earth Observing System (AMSR-E) is compared with in situ temperature observations from Argo profiling floats over the global oceans to evaluate the advantages of Argo NST (near-surface temperature: water temperature less than 1 m from the surface). By comparing Argo nominal surface temperature ( 5 m) with its NST, a diurnal cycle caused by daytime warming and nighttime cooling was found, along with a maximum warming of 0.08±0.36°C during 14:00-15:00 local time. Further comparisons between Argo 5-m temperature/Argo NST and AMSR-E SST retrievals related to wind speed, columnar water vapor, and columnar cloud water indicate warming biases at low wind speed (28 mm during daytime. The warming tendency is more remarkable for AMSR-E SST/Argo 5-m temperature compared with AMSR-E SST/Argo NST, owing to the effect of diurnal warming. This effect of diurnal warming events should be excluded before validation for microwave SST retrievals. Both AMSR-E nighttime SST/Argo 5-m temperature and nighttime SST/Argo NST show generally good agreement, independent of wind speed and columnar water vapor. From our analysis, Argo NST data demonstrated their advantages for validation of satellite-retrieved SST.

  15. HYDROPHILIC MODIFICATION OF PPESK POROUS MEMBRANES VIA AQUEOUS SURFACE-INITIATED ATOM TRANSFER RADICAL POLYMERIZATION

    Institute of Scientific and Technical Information of China (English)

    Zhuan Yi; You-yi Xu; Li-ping Zhu; Han-bang Dong; Bao-ku Zhu

    2009-01-01

    Hydrophilic surface modification of poly(phthalazinone ether sulfone ketone)(PPESK)porous membranes was achieved via surface-initiated atom transfer radical polymerization(ATRP)in aqueous medium.Prior to ATRP,chloromethyl groups were introduced onto PPESK main chains by chloromethylation.Chloromethylated PPESK(CMPPESK)was fabricated into porous membrane through phase inversion technique.Hydrophilic poly(poly(ethylene glycol)methyl ether methacrylate)(P(PEGMA))brushes were grafted from CMPPESK membrane under the initiation of benzyl chloride groups on membrane surface.The results of Fourier transform infrared(FT-IR)spectroscopy and X-ray photoelectron spectroscopy (XPS)confirmed the grafting of P(PEGMA)chains.Water contact angle measurements and protein adsorption experiments suggested that the hydrophilicity and anti-fouling ability of PPESK membrane were remarkably improved after the grafting of P(PEGMA)brushes.The addition of small amount of water in the reaction solvent apparently accelerated the progress of the grafting reaction.The use of CuCl2 in the catalyst system promoted the controllability of the ATRP reaction.

  16. Quartz crystal microbalance study of the kinetics of surface initiated polymerization

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Surface initiated polymerization (SIP) is a valuable tool in synthesizing functional polymer brushes,yet the kinetic understanding of SIP lags behind the development of its application. We apply quartz crystal microbalance (QCM) to address two issues that are not fully addressed yet play a central role in the rational design of functional polymer brushes,namely quantitative determination of the kinetics and the initiator efficiency (IE) of SIP. SIP are monitored online using QCM. Two quantitative frequencythickness (f-T) relations make the direct determination and comparison of the rate of polymerization possible even for different monomers. Based on the bi-termination model,the kinetics of SIP is simply described by two variables,which are related to two polymerization constants,namely a = 1/(kp,s,app-[M][R·]0) and b = kt,s,app/(kp,s,app[M]). Factors that could alter the kinetics of SIP are studied,including (i) the molecular weight of monomers,(ii) the solvent used,(iii) the initial density of the initiator,(iv) the concentration of monomer,[M],and (v) the catalyst system (ratio among the ingredients,metal,ligands,and additives). The dynamic nature of IE is also described by these two variables,IE = a/(a + bt). Instead of the molecular weight and the polydispersity,we suggest that film thickness,the two kinetic parameters (a and b),and the initial density of the initiator and IE be the parameters that characterize ultrathin polymer brushes. Besides the kinetics study of SIP,the reported method has many other applications,for example,in the fast screening of catalyst system for SIP and other polymerization systems.

  17. Relationship between ocular surface temperature and peripheral vasoconstriction in healthy subjects: A thermographic study

    DEFF Research Database (Denmark)

    Matteoli, Sara; Vannetti, Federica; Finocchio, Lucia

    2014-01-01

    vasoconstriction might be detected by measuring the ocular surface temperature. The ocular surface temperature was evaluated in a group of 38 healthy young subjects (28 males and 10 females; mean age: 25.4 6 4.1 years) by infrared thermography. For each subject, the experimental procedure consisted of two...

  18. LUBRICATION BASIS THEORY OF WORM PAIR AND TEMPERATURE DISTRIBUTION ON WORM GEAR SURFACE

    Institute of Scientific and Technical Information of China (English)

    1998-01-01

    The lubrication basis theory of worm pair is given. The lubrication state of worm gear is analyzed. It is found that the temperature distribution on the tooth surface of worm gear is closely related with the lubrication state and that the temperature on the tooth surface of worm gear is consistent with the characteristic term of mesh and motion of worm pair.

  19. Low-temperature gaseous surface hardening of stainless steel: the current status

    DEFF Research Database (Denmark)

    Christiansen, Thomas; Somers, Marcel A. J.

    2009-01-01

    The present review addresses the state of the art of low-temperature gaseous surface engineering of (austenitic) stainless steel and is largely based on the authors' own work in the last 10 years. The main purpose of low temperature gaseous surface engineering of stainless steel is to develop a h...

  20. Effect of initial stress on reflection at the free surface of anisotropic elastic medium

    Indian Academy of Sciences (India)

    M D Sharma

    2007-12-01

    The propagation of plane waves is considered in a general anisotropic elastic medium in the presence of initial stress. The Christoffel equations are solved into a polynomial of degree six. The roots of this polynomial represent the vertical slowness values for the six quasi-waves resulting from the presence of a discontinuity in the medium. Three of these six values are identified with the three quasi-waves traveling in the medium but away from its boundary. Reflection at the free plane surface is studied for partition of energy among the three reflected waves. For post-critical incidence, the reflected waves are inhomogeneous (evanescent) waves. Numerical examples are considered to exhibit the effects of initial stress on the phase direction, attenuation and reflection coefficients of the reflected waves. The phase velocities and energy shares of the reflected waves change significantly with initial stress as well as anisotropic symmetry. The presence of initial stress, however, has a negligible effect on the phase directions of reflected waves.

  1. Recent surface temperature trends in the interior of East Antarctica from borehole firn temperature measurements and geophysical inverse methods

    Science.gov (United States)

    Muto, A.; Scambos, T.A.; Steffen, K.; Slater, A.G.; Clow, G.D.

    2011-01-01

    We use measured firn temperatures down to depths of 80 to 90 m at four locations in the interior of Dronning Maud Land, East Antarctica to derive surface temperature histories spanning the past few decades using two different inverse methods. We find that the mean surface temperatures near the ice divide (the highest-elevation ridge of East Antarctic Ice Sheet) have increased approximately 1 to 1.5 K within the past ???50 years, although the onset and rate of this warming vary by site. Histories at two locations, NUS07-5 (78.65S, 35.64E) and NUS07-7 (82.07S, 54.89E), suggest that the majority of this warming took place in the past one or two decades. Slight cooling to no change was indicated at one location, NUS08-5 (82.63S, 17.87E), off the divide near the Recovery Lakes region. In the most recent decade, inversion results indicate both cooler and warmer periods at different sites due to high interannual variability and relatively high resolution of the inverted surface temperature histories. The overall results of our analysis fit a pattern of recent climate trends emerging from several sources of the Antarctic temperature reconstructions: there is a contrast in surface temperature trends possibly related to altitude in this part of East Antarctica. Copyright 2011 by the American Geophysical Union.

  2. Initial position estimation strategy for a surface permanent magnet synchronous motor used in hybrid electric vehicles

    Institute of Scientific and Technical Information of China (English)

    Bing TIAN; Qun-tao AN; Li SUN‡; Dong-yang SUN; Jian-dong DUAN

    2016-01-01

    A novel nonlinear model for surface permanent magnet synchronous motors (SPMSMs) is adopted to estimate the initial rotor position for hybrid electric vehicles (HEVs). Usually, the accuracy of initial rotor position estimation for SPMSMs relies on magnetic saturation. To verify the saturation effect, the transient finite element analysis (FEA) model is presented first. Hybrid injection of a static voltage vector (SVV) superimposed with a high-frequency rotating voltage is proposed. The magnetic polarity is roughly identified with the aid of the saturation evaluation function, based on which an estimation of the position is performed. During this procedure, a special demodulation is suggested to extract signals of iron core saturation and rotor position. A Simulink/MATLAB platform for SPMSMs at standstill is constituted, and the effectiveness of the proposed strategy is verified. The proposed method is also validated by experimental results of an SPMSM drive.

  3. In situ monitoring of internal surface temperature of the historic building envelope

    Science.gov (United States)

    Labovská, Veronika; Katunský, Dušan

    2016-06-01

    Historical building envelope is characterized by a large accumulation that impact is mainly by changing the inner surface temperature over time. The minimum value of the inner surface temperature is set Code requirements. In the case of thermal technology assessment of building envelope contemplates a steady state external temperature and internal environment, thereby neglecting the heat accumulation capacity of building envelopes. Monitoring surface temperature in real terms in situ shows the real behavior of the building envelope close to reality. The recorded data can be used to create a numerical model for the simulation.

  4. Comparison of satellite and airborne sensor data on sea surface temperature and suspended solid distribution

    Science.gov (United States)

    Nishimura, Y.; Saito, K.; Hayakawa, S.; Narigasawa, K.

    1992-07-01

    Sea surface temperature and suspended solid were observed simultaneously by LANDSAT TM, NOAA AVHRR and airborne MSS. The authors compared the following items through the data, i.e., 1) Sea surface temperature, 2) Suspended solid in the sea water, 3) Monitoring ability on ocean environment. It was found that distribution patterns of sea surface temperature and suspended solid in the Ariake Sea obtained from LANDSAT TM are similar with those from airborne MSS in a scale of 1:300,000. Sea surface temperature estimated from NOAA AVHRR data indicates a fact of an ocean environment of the Ariake Sea and the around sea area. It is concluded that the TM data can be used for the monitoring of sea environment. The NOAA AVHRR data is useful for the estimation of sea surface temperature with the airborne MSS data.

  5. The Land Surface Temperature Synergistic Processor in BEAM: A Prototype towards Sentinel-3

    OpenAIRE

    Ruescas, Ana Belen; Danne, Olaf; Fomferra, Norman; Brockmann, Carsten

    2016-01-01

    Land Surface Temperature (LST) is one of the key parameters in the physics of land-surface processes on regional and global scales, combining the results of all surface-atmosphere interactions and energy fluxes between the surface and the atmosphere. With the advent of the European Space Agency (ESA) Sentinel 3 (S3) satellite, accurate LST retrieval methodologies are being developed by exploiting the synergy between the Ocean and Land Colour Instrument (OLCI) and the Sea and Land Surface Temp...

  6. Evaluation of the ground surface Enthalpy balance from bedrock temperatures (Livingston Island, Maritime Antarctic)

    Science.gov (United States)

    Ramos, M.; Vieira, G.

    2009-05-01

    The annual evolution of the ground temperatures from Incinerador borehole in Livingston Island (South Shetlands, Antarctic) is studied. The borehole is 2.4 m deep and is located in a massive quartzite outcrop with negligible water content, in the proximity of the Spanish Antarctic Station Juan Carlos I. In order to model the movement of the 0°C isotherm (velocity and maximum depth) hourly temperature profiles from: (i) the cooling periods of the frost season of 2000 to 2005, and (ii) the warming periods of the thaw season of 2002-2003, 2003-2004 and 2004-2005, were studied. In this modelling approach, heat gains and losses across the ground surface are assumed to be the causes for the 0°C isotherm movement. A methodological approach to calculate the ground Enthalpy change based on the thermodynamic analysis of the ground during the cooling and warming periods is proposed. The Enthalpy change into the rock is equivalent to the heat exchange through the ground surface during each season, thus enabling to describe the interaction ground-atmosphere and providing valuable data for studies on permafrost and periglacial processes. The bedrock density and thermal conductivity are considered to be constant and initial isothermal conditions at 0°C are assumed (based in collected data and local meteorological conditions in this area) to run the model in the beginning of each season. The final stages correspond to the temperatures at the end of the cooling and warming periods (annual minima and maxima). The application of this method avoids error propagation induced by the heat exchange calculations from multiple sensors using the Fourier method.

  7. Evaluation of the ground surface Enthalpy balance from bedrock temperatures (Livingston Island, Maritime Antarctic

    Directory of Open Access Journals (Sweden)

    M. Ramos

    2009-05-01

    Full Text Available The annual evolution of the ground temperatures from Incinerador borehole in Livingston Island (South Shetlands, Antarctic is studied. The borehole is 2.4 m deep and is located in a massive quartzite outcrop with negligible water content, in the proximity of the Spanish Antarctic Station Juan Carlos I. In order to model the movement of the 0°C isotherm (velocity and maximum depth hourly temperature profiles from: (i the cooling periods of the frost season of 2000 to 2005, and (ii the warming periods of the thaw season of 2002–2003, 2003–2004 and 2004–2005, were studied. In this modelling approach, heat gains and losses across the ground surface are assumed to be the causes for the 0°C isotherm movement. A methodological approach to calculate the ground Enthalpy change based on the thermodynamic analysis of the ground during the cooling and warming periods is proposed. The Enthalpy change into the rock is equivalent to the heat exchange through the ground surface during each season, thus enabling to describe the interaction ground-atmosphere and providing valuable data for studies on permafrost and periglacial processes. The bedrock density and thermal conductivity are considered to be constant and initial isothermal conditions at 0°C are assumed (based in collected data and local meteorological conditions in this area to run the model in the beginning of each season. The final stages correspond to the temperatures at the end of the cooling and warming periods (annual minima and maxima. The application of this method avoids error propagation induced by the heat exchange calculations from multiple sensors using the Fourier method.

  8. Heterogeneity of soil surface temperature induced by xerophytic shrub in a revegetated desert ecosystem, northwestern China

    Indian Academy of Sciences (India)

    Ya-Feng Zhang; Xin-Ping Wang; Yan-Xia PAN; Rui Hu; Hao Zhang

    2013-06-01

    Variation characteristics of the soil surface temperature induced by shrub canopy greatly affects the nearsurface biological and biochemical processes in desert ecosystems. However, information regarding the effects of shrub upon the heterogeneity of soil surface temperature is scarce. Here we aimed to characterize the effects of shrub (Caragana korshinskii) canopy on the soil surface temperature heterogeneity at areas under shrub canopy and the neighbouring bare ground. Diurnal variations of soil surface temperature were measured at areas adjacent to the shrub base (ASB), beneath the midcanopy (BMC), and in the bare intershrub spaces (BIS) at the eastern, southern, western and northern aspects of shrub, respectively. Results indicated that diurnal mean soil surface temperature under the C. korshinskii canopy (ASB and BMC) was significantly lower than in the BIS, with the highest in the BIS, followed by the BMC and ASB. The diurnal maximum and diurnal variations of soil surface temperatures under canopy vary strongly with different aspects of shrub with the diurnal variation in solar altitude, which could be used as cues to detect safe sites for under-canopy biota. A significant empirical linear relationship was found between soil surface temperature and solar altitude, suggesting an empirical predicator that solar altitude can serve for soil surface temperature. Lower soil surface temperatures under the canopy than in the bare intershrub spaces imply that shrubs canopy play a role of ‘cool islands’ in the daytime in terms of soil surface temperature during hot summer months in the desert ecosystems characterized by a mosaic of sparse vegetation and bare ground.

  9. Investigat ing the effect of surface water – groundwater interactions on stream temperature using D istributed Temperature Sensing and instream temperature model

    DEFF Research Database (Denmark)

    Matheswaran, K.; Blemmer, M.; Mortensen, J.

    2011-01-01

    Surface water–groundwater interactions at the stream interface influences, and at times controls the stream temperature, a critical water property driving biogeochemical processes. This study investigates the effects of these interactions on temperature of Stream Elverdamsåen in Denmark using the...

  10. Investigat ing the effect of surface water – groundwater interactions on stream temperature using D istributed Temperature Sensing and instream temperature model

    DEFF Research Database (Denmark)

    Matheswaran, K.; Blemmer, M.; Mortensen, J.;

    2011-01-01

    Surface water–groundwater interactions at the stream interface influences, and at times controls the stream temperature, a critical water property driving biogeochemical processes. This study investigates the effects of these interactions on temperature of Stream Elverdamsåen in Denmark using the...

  11. A Method to Determine the Mean Temperature at the Planet Surface

    Institute of Scientific and Technical Information of China (English)

    GAOChong-Yi

    2003-01-01

    The escape time of a given species of partlcles in the planetary atmosphere is related to atmospheric temperature. The mean temperature at the planet surface may be inferred from the escape of a given kind of particles in the planetary atmosphere. For example, CH4 escaping from the Pluto atmosphere results in the variation of its partial pressure and escape time, then the mean temperature at the Pluto surface, 42.2 K, is got on the barns of it.

  12. A statistical method to get surface level air-temperature from satellite observations of precipitable water

    Digital Repository Service at National Institute of Oceanography (India)

    Pankajakshan, T.; Shikauchi, A.; Sugimori, Y.; Kubota, M.

    Vol. 49, pp. 551 to 558. 1993 A Statistical Method to Get Surface Level Air-Temperature from Satellite Observations of Precipitable Water PANKAJAKSHAN THADATHIL*, AKIRA SHIKAUCHI, YASUHIRO SUGIMORI and MASAHISA KUBOTA School of Marine Science... observations for getting the estimates of heat flux across the air-sea boundary (Miller, 1981; Liu, 1988). Bulk method has widely been used for this purpose and the parameters required are: sea surface temperature, and wind speed, air-temperature and specific...

  13. Surface characterization of dental ceramics and initial streptococcal adhesion in vitro.

    Science.gov (United States)

    Hahnel, Sebastian; Rosentritt, Martin; Handel, Gerhard; Bürgers, Ralf

    2009-08-01

    The aim of this in vitro study was to investigate the surface properties of dental ceramic materials belonging to different ceramic classes, and to correlate the findings to the initial adherence of three oral streptococcal strains. Rectangular specimens were prepared from different ceramic materials (glass/lithium disilicate glass/glass-infiltrated zirconia/partially sintered zirconia/hipped zirconia ceramic) and polished; surface roughness (Ra) was determined. Glass plates were used as a control. Specimens were incubated with phosphate-buffered saline or an artificial saliva (protein mixture; 2h, 37 degrees C). Surface free energy (gamma(t)) and its polar (gamma(p)) and disperse (gamma(d)) contribution were determined prior to and after artificial saliva exposure. Uncoated and protein-coated specimens were incubated with Streptococcus gordonii DSMZ 6777, Streptococcus oralis DSMZ 20068 or Streptococcus sanguinis DSMZ 20068 suspension for 2.5h at 37 degrees C (n=15 for each treatment and strain). Adherent streptococci were quantified fluorometrically. The lithium disilicate glass ceramic showed the highest values for Ra; the lowest values were found for the glass ceramic, the partially sintered zirconia and the hipped zirconia ceramic. Protein coating caused a significant increase in gamma(t) and gamma(p), but not in the control material. The control material showed higher values for streptococcal adhesion than all ceramic materials. After protein coating, only slight and random differences in streptococcal adhesion were found between the various ceramic materials. Dental ceramic materials show differences in terms of Ra, gamma(t) and initial streptococcal adhesion; however, correlations between surface properties and streptococcal adhesion were poor.

  14. Emperor penguin body surfaces cool below air temperature.

    Science.gov (United States)

    McCafferty, D J; Gilbert, C; Thierry, A-M; Currie, J; Le Maho, Y; Ancel, A

    2013-06-23

    Emperor penguins Aptenodytes forsteri are able to survive the harsh Antarctic climate because of specialized anatomical, physiological and behavioural adaptations for minimizing heat loss. Heat transfer theory predicts that metabolic heat loss in this species will mostly depend on radiative and convective cooling. To examine this, thermal imaging of emperor penguins was undertaken at the breeding colony of Pointe Géologie in Terre Adélie (66°40' S 140° 01' E), Antarctica in June 2008. During clear sky conditions, most outer surfaces of the body were colder than surrounding sub-zero air owing to radiative cooling. In these conditions, the feather surface will paradoxically gain heat by convection from surrounding air. However, owing to the low thermal conductivity of plumage any heat transfer to the skin surface will be negligible. Future thermal imaging studies are likely to yield further insights into the adaptations of this species to the Antarctic climate.

  15. Polarization switching in vertical-cavity surface emitting lasers observed at constant active region temperature

    Science.gov (United States)

    Martín-Regalado, J.; Chilla, J. L. A.; Rocca, J. J.; Brusenbach, P.

    1997-06-01

    Polarization switching in gain-guided, vertical-cavity, surface-emitting lasers was studied as a function of the active region temperature. We show that polarization switching occurs even when the active region temperature is kept constant during fast pulse low duty cycle operation. This temperature independent polarization switching phenomenon is explained in terms of a recently developed model.

  16. 30 CFR 7.101 - Surface temperature tests.

    Science.gov (United States)

    2010-07-01

    ... in the application, § 7.97(a)(3). (iii) If a wet exhaust conditioner is used to cool the exhaust gas... temperature tests. The test for determination of exhaust gas cooling efficiency described in § 7.102 may be..., by volume, of methane in the intake air mixture until all parts of the engine, exhaust coolant...

  17. Anti-biofouling property of vanillin on Aeromonas hydrophila initial biofilm on various membrane surfaces.

    Science.gov (United States)

    Ponnusamy, K; Kappachery, S; Thekeettle, M; Song, J H; Kweon, J H

    2013-09-01

    Biofouling is a serious problem on filter membranes of water purification systems due to formation of bacterial biofilms, which can be detrimental to the membrane performance. Biofouling occurs on membrane surface and therefore greatly influences the physical and chemical aspects of the surface. Several membranes including microfiltration, ultrafiltration, and reverse osmosis (RO) membranes were used to learn about the anti-biofouling properties of vanillin affecting the membrane performances. Vanillin has been recognized as a potential quorum quenching compound for Aeromonas hydrophila biofilms. The initial attachment and dynamics of biofilm growth were monitored using scanning electron microscopy and confocal laser scanning microscopy. Biofilm quantities were measured using a plate count method and total protein determinations. Vanillin addition was effective in the prevention of biofilm formation on the tested membrane surfaces. Among the membranes, RO membranes made with cellulose acetate showed the most substantial reduction of biofilm formation by addition of vanillin. The biofilm reduction was confirmed by the results of surface coverage, biomass and protein accumulation. The HPLC spectrum of the spent culture with vanillin addition showed that vanillin may interfere with quorum sensing molecules and thus prevent the formation of the biofilms.

  18. Anti-fouling surfaces by combined molecular self-assembly and surface-initiated ATRP for micropatterning active proteins.

    Science.gov (United States)

    Xiu, K M; Cai, Q; Li, J S; Yang, X P; Yang, W T; Xu, F J

    2012-02-01

    A simple method by combined molecular self assembly and surface-initiated atom transfer radical polymerization (SI-ATRP) was proposed to prepare a biologically inert surface for micropatterning active proteins. The MPEG microdomains having a short terminal poly(ethylene glycol) (PEG) unit were prepared by self assembly of 2-(methyoxy(polyethylenoxy) propyl)trimethoxy silane (MPEG-silane). The remaining local regions or poly(poly(ethylene glycol)methyl ether methacrylate-co-glycidyl methacrylate) (P(PEGMEMA-co-GMA)) microdomains were produced via SI-ATRP of PEGMEMA and GMA comonomers. The epoxy groups of the P(PEGMEMA-co-GMA) microdomains were used directly for covalent coupling of an active protein (human immunoglobulin or IgG) via the ring-opening reaction to produce the IgG-coupled microdomains. The IgG-coupled microdomains interact only and specifically with target anti-IgG, while the other antifouling microregions from self-assembled monolayers with short terminal PEG units effectively prevent specific and non-specific protein fouling. When extended to other active biomolecules, microarrays for specific and non-specific analyte interactions with a high signal-to-noise ratio could be readily tailored.

  19. Validation of AIRS V6 Surface Temperature over Greenland with GCN and NOAA Stations

    Science.gov (United States)

    Lee, Jae N.; Hearty, Thomas; Cullather, Richard; Nowicki, Sophie; Susskind, Joel

    2016-01-01

    This work compares the temporal and spatial characteristics of the AIRSAMSU (Atmospheric Infrared Sounder Advanced Microwave Sounding Unit A) Version 6 and MODIS (Moderate resolution Imaging Spectroradiometer) Collection 5 derived surface temperatures over Greenland. To estimate uncertainties in space-based surface temperature measurements, we re-projected the MODIS Ice Surface Temperature (IST) to 0.5 by 0.5 degree spatial resolution. We also re-gridded AIRS Skin Temperature (Ts) into the same grid but classified with different cloud conditions and surface types. These co-located data sets make intercomparison between the two instruments relatively straightforward. Using this approach, the spatial comparison between the monthly mean AIRS Ts and MODIS IST is in good agreement with RMS 2K for May 2012. This approach also allows the detection of any long-term calibration drift and the careful examination of calibration consistency in the MODIS and AIRS temperature data record. The temporal correlations between temperature data are also compared with those from in-situ measurements from GC-Net (GCN) and NOAA stations. The coherent time series of surface temperature evident in the correlation between AIRS Ts and GCN temperatures suggest that at monthly time scales both observations capture the same climate signal over Greenland. It is also suggested that AIRS surface air temperature (Ta) can be used to estimate the boundary layer inversion.

  20. Seasonal variability of diurnal temperature range in Egypt with links to atmospheric circulations and sea surface temperature

    Science.gov (United States)

    El Kenawy, A.; Lopez Moreno, J. I.; Vicente-Serrano, S.

    2010-09-01

    The diurnal temperature range (DTR) is an important climate-change variable. Seasonal and annual variability of DTR in Egypt was investigated based on a monthly dataset of 40 observatories distributing across the country. The trends were calculated using the Rho spearman rank test at the 95 % level of significance. The trends at the independent individual scale were compared with a regional series created for the whole country following the Thiessen polygon approach. A cross-tabulation analysis was performed between the trends of the DTR and the trends of maximum and minimum temperatures to account for directional causes of variability of the DTR at seasonal and annual scales. The physical processes controlling the DTR variability were also assessed in terms of large atmospheric circulations representing in the indices of the North Atlantic Oscillation (NAO), the East Atlantic (EA) pattern, El Niño Southern Oscillation (ENSO) index and the EAWR (East Atlantic/West Russia) Pattern. Also, the variability of the DTR was linked with anomaly of Sea Surface Temperature (SST). A cooling trend was observed in Egypt with strong behavior in winter and summer rather than fall and spring. The upwarding trend of the mean minimum temperature was mainly responsible for variability of the DTR rather than the mean maximum temperature. Also, the EA and the EAWR indices were the main indices accounted for most of variation in the DTR in Egypt, particularly in summer. Key words: trend analysis, temperature variability, Diurnal temperature range, atmospheric circulation, sea surface temperature, Egypt.

  1. The Impact of Sea-Surface Winds on Meteorological Conditions in Israel: An Initial Study

    Science.gov (United States)

    Otterman, J.; Saaroni, H.; Atlas, R.; Ardizzone, J.; Ben-Dor, E.; Druyan, L.; Jusem, C. J.; Karnieli, A.; Terry, J.

    2000-01-01

    The SSM/I (Spectral Sensor Microwave Imager) dataset is used to monitor surface wind speed and direction at four locations over the Eastern Mediterranean during December 1998 - January 1999. Time series of these data are compared to concurrent series of precipitation, surface temperature, humidity and winds at selected Israeli stations: Sde Dov (coastal), Bet Dagan (5 km. inland), Jerusalem (Judean Hills), Hafetz Haim (3 km. inland) and Sde Boker (central Negev). December 1998 and the beginning of January 1999 were dry in Israel, but significant precipitation was recorded at many stations during the second half of January (1999). SSM/I data show a surge in westerly surface winds west of Israel (32 N, 32.5 E) on 15 January, coinciding with the renewal of precipitation. We discuss the relevant circulation and pressure patterns during this transition in the context of the evolving meteorological conditions at the selected Israeli locations. The SSM/I dataset of near ocean surface winds, available for the last 12 years, is described. We analyze lagged correlation between these data and the Israeli station data and investigate possibility of predictive skill. Application of such relationships to short-term weather prediction would require real-time access to the SSM/I observations.

  2. Sea surface temperature mapping using a thermal infrared scanner

    Digital Repository Service at National Institute of Oceanography (India)

    RameshKumar, M.R.; Pandya, R.M.; Mathur, K.M.; Charyulu, R.J.K.; Rao, L.V.G.

    1 metre water column below the sea surface. A thermal infrared scanner developed by the Space Applications Centre (ISRO), Ahmedabad was operated on board R.V. Gaveshani in April/May 1984 for mapping SST over the eastern Arabian Sea. SST values...

  3. Levitation of Liquid Microdroplets Above A Solid Surface Subcooled to the Leidenfrost Temperature

    Directory of Open Access Journals (Sweden)

    Kirichenko D. P.

    2016-01-01

    Full Text Available Evaporation of liquid microdroplets that fall on a solid surface with the temperature of below the Leidenfrost temperature is studied. It has been found out that sufficiently small liquid droplets of about 10 microns can suspend at some distance from the surface (levitate and do not reach the surface; at that, the rate of droplet evaporation is reduced by an order as compared to microdroplets, which touch the surface. It is determined that in contrast to microdroplets, which touch the surface, the specific evaporation rate of levitating droplets is constant in time.

  4. Regional change in snow water equivalent-surface air temperature relationship over Eurasia during boreal spring

    Science.gov (United States)

    Wu, Renguang; Chen, Shangfeng

    2016-10-01

    Present study investigates local relationship between surface air temperature and snow water equivalent (SWE) change over mid- and high-latitudes of Eurasia during boreal spring. Positive correlation is generally observed around the periphery of snow covered region, indicative of an effect of snow on surface temperature change. In contrast, negative correlation is usually found over large snow amount area, implying a response of snow change to wind-induced surface temperature anomalies. With the seasonal retreat of snow covered region, region of positive correlation between SWE and surface air temperature shifts northeastward from March to May. A diagnosis of surface heat flux anomalies in April suggests that the snow impact on surface air temperature is dominant in east Europe and west Siberia through modulating surface shortwave radiation. In contrast, atmospheric effect on SWE is important in Siberia and Russia Far East through wind-induced surface sensible heat flux change. Further analysis reveals that atmospheric circulation anomalies in association with snowmelt over east Siberia may be partly attributed to sea surface temperature anomalies in the North Atlantic and the atmospheric circulation anomaly pattern associated with snowmelt over Russia Far East has a close association with the Arctic Oscillation.

  5. Urban surface temperature behaviour and heat island effect in a tropical planned city

    Science.gov (United States)

    Ahmed, Adeb Qaid; Ossen, Dilshan Remaz; Jamei, Elmira; Manaf, Norhashima Abd; Said, Ismail; Ahmad, Mohd Hamdan

    2015-02-01

    Putrajaya is a model city planned with concepts of a "city in the garden" and an "intelligent city" in the tropics. This study presents the behaviour of the surface temperature and the heat island effect of Putrajaya. Findings show that heat island intensity is 2 °C on average at nighttime and negligible at daytime. But high surface temperature values were recorded at the main boulevard due to direct solar radiation incident, street orientation in the direction of northeast and southwest and low building height-to-street width ratio. Buildings facing each other had cooling effect on surfaces during the morning and evening hours; conversely, they had a warming effect at noon. Clustered trees along the street are effective in reducing the surface temperature compared to scattered and isolated trees. Surface temperature of built up areas was highest at noon, while walls and sidewalks facing northwest were hottest later in the day. Walls and sidewalks that face northwest were warmer than those that face southeast. The surface temperatures of the horizontal street surfaces and of vertical façades are at acceptable levels relative to the surface temperature of similar surfaces in mature cities in subtropical, temperate and Mediterranean climates.

  6. The Effect of Composition on the Surface Finish of PS400: A New High Temperature Solid Lubricant Coating

    Science.gov (United States)

    DellaCorte, Christopher; Stanford, malcolm K.; Thomas, Fransua; Edmonds, Brian J.

    2010-01-01

    A new composite, multi-constituent, solid lubricant coating, NASA PS400, developed for high temperature tribological applications, exhibits a smoother surface finish after grinding and polishing than its predecessors PS200 and PS300. In this paper, the baseline composition of PS400 is modified to investigate each individual constituent s role on the achievable surface finish through a series of coating deposition, grinding, and polishing experiments. Furthermore, to explore the limits of compositional tailoring for improved tribological performance, several PS400 coatings were doped with additional solid lubricants (graphite, MoS2 and BN) and tribologically tested. The test results clearly showed that, compared to PS300 coatings, PS400 achieves a smoother surface finish via a reduced lubricant content. Coatings prepared with higher than the baseline level (10 wt%) of lubricants exhibited higher final surface roughness than the earlier generation PS300 coatings. Reducing or eliminating the one or both lubricants (fluorides or silver) did not further improve the surface finish suggesting that the current composition of PS400 is near optimal with respect to surface finish. Lastly, attempts to improve the poor initial room temperature tribological behavior of PS400 via the addition of traditional solid lubricants were unsuccessful. Based upon this work and earlier results it is expected that future research will concentrate on developing methods to produce a lubricious glaze on the rubbing surface during break in to ensure that low friction and wear are rapidly achieved.

  7. Force Restore Technique for Ground Surface Temperature and Moisture Content in a Dry Desert System

    NARCIS (Netherlands)

    Jacobs, A.F.G.; Heusinkveld, B.G.; Berkowicz, S.

    2000-01-01

    The level of the surface temperature as well as surface moisture content is important for the turbulent transports of sensible and latent heat, respectively, but this level is also crucial for the survival of shrubs, plants, insects, and small animals in a desert environment. To estimate the surface

  8. Room-Temperature Growth of Al Films on Si(111)-7×7 Surface

    Institute of Scientific and Technical Information of China (English)

    LIU Hong; ZHANG Yan-Feng; WANG De-Yong; JIA Jin-Feng; XUE Qi-Kun

    2004-01-01

    @@ Reflection high energy electron diffraction and scanning tunnelling microscopy (STM) are used to investigate the structure and morphology of Al films deposited on Si(111)-7 × 7 surface at room temperature. The films are polycrystalline, made up of (100) and (111) oriented islands, which primarily result from the interface elastic effect and free surface energies of the Al (100) and (111) surfaces.

  9. A Process-Based Assessment of Decadal-Scale Surface Temperature Evolutions in the NCAR CCSM4's 25-Year Hindcast Experiments

    Science.gov (United States)

    Deng, Yi; Chen, Junwen

    2017-04-01

    This study represents an initial effort in the context of the coupled atmosphere-surface climate feedback-response analysis method (CFRAM) to partition the temporal evolution of the global surface temperature from 1981 to 2005 into components associated with individual radiative and non-radiative (dynamical) processes in the NCAR CCSM4's decadal hindcasts. When compared with the observation (ERA-Interim), the CCSM4 is able to predict an overall warming trend as well as the transient cooling occurring during the period 1989-1994. However, while the model captures fairly well the positive contributions of the CO2 and surface albedo change to the temperature evolution, it has an overly strong water vapor effect that dictates the temperature evolution in the hindcast. This is in contrast with the observation where changes in surface dynamics (mainly ocean circulation and heat content change) dominates the actual temperature evolution. Atmospheric dynamics in both the observation and model works against the surface temperature tendency through turbulent and convective heat transport, leading to an overall negative contribution to the evolution of the surface temperature. Impacts of solar forcing and ozone change on the surface temperature change are relatively weak during this period. The magnitude of cloud effect is considerably smaller compared to that in the observation and the spatial distribution of the cloud effect is also significantly different between the two especially over the equatorial Pacific. The value and limitations of this process-based temperature decomposition are discussed.

  10. Influence of initial temperature and heating method in the temperature profile during alkaline dissolution of Al for the production of Mo-99

    Energy Technology Data Exchange (ETDEWEB)

    Camilo, Ruth L.; Araujo, Izilda C.; Mindrisz, Ana C.; Forbicini, Christina A.L.G. de O., E-mail: rcamilo@ipen.br, E-mail: cruzaraujo22@gmail.com, E-mail: acmindri@ipen.br, E-mail: cforbici@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2013-07-01

    Radionuclides in nuclear medicine can be used for diagnosis and therapy. The {sup 99m}Tc, son of {sup 99}Mo, is most often used in nuclear medicine as tracer element because of its favorable nuclear properties, accounting for about 80% of all diagnostic procedures in vivo. Aiming to resolve the dependency of Brazil with respect to the supply of {sup 99}Mo was created the Brazilian Multipurpose Reactor project (BMR), started in 2008, having as main objective to produce about 1000 Ci/week of {sup 99}Mo. This study is part of the project to obtain {sup 9}'9Mo by alkaline dissolution of UAl{sub x}-Al targets. The initial reaction temperature is an important parameter, since it has great influence on the value of the maximum temperature and dissolution time. According to literature, for security reasons the dissolution process must have its temperature controlled so that the maximum temperature has to be around 90 deg C. The behavior of the temperature during dissolution using three different methods of heating in order to minimize the fluctuation of temperature during dissolution, keeping its maximum value at around 90 deg C was studied. The three methods of heating chosen were: a) initial temperature of 85 deg C with continuous heating, b) heating water bath until it reaches the initial temperature (70 to 95 deg C), turning off after that, and c) external heating until it reached the starting temperature (60-95 deg C). The alkaline solution used was 3 mol.L{sup -1} NaOH{sub 3} and 2 mol.L{sup -1} NaNO{sub 3}. In the first study it was observed that after 1 minute of dissolution the solution temperature reached 100 deg C on average, up to a maximum of 109 deg C, ending with values around 95 deg C. In the second study after 3 minutes of dissolution the maximum temperature was 106 deg C and the minimum 100 deg C. In the third study the temperature rise during dissolution increased with increasing initial temperature which practically remains constant until the end

  11. Temperature-driven switching of water adhesion on organogel surface.

    Science.gov (United States)

    Yao, Xi; Ju, Jie; Yang, Shuai; Wang, Jianjun; Jiang, Lei

    2014-03-26

    Temperature-driven switching of water adhesion is realized on a novel n-paraffinswollen organogel by thermally controlling the transition of air/liquid/solid (ALS/ALLS) systems via the phasechange process of n-paraffin. The thermal control of both the water-drop sliding motion and the switching of the optical transparency shows potential applications in scientific research and daily life.

  12. Preparation of polystyrene/SiO2 nanocomposites by surface-initiated nitroxide-mediated radical polymerization

    Institute of Scientific and Technical Information of China (English)

    NI Gang; YANG Wu; BO Lili; GUO Hao; ZHANG Wenhao; GAO Jinzhang

    2006-01-01

    Polystyrene/SiO2 composite nanoparticles (PS-g-Silica) were prepared by an in-situ surface-initiated nitroxide-mediated radical polymerization. After SiO2 nanoparticles were treated by thionyl chloride (SOCl2), peroxide initiation groups were immobilized on their surfaces through a reaction with tertiary butyl hydroperoxide (TBHP). Then surface nitroxide-mediated radical polymerization was initiated and polystyrene was grafted on the surface of SiO2 particles. Composite nanoparticles were characterized by IR spectra, transmission electron microscopy (TEM), atomic force microscopy (AFM) and thermogravimetry (TGA) and the results indicated that the surface-initiated nitroxide-mediated radical polymerization could be successfully used to synthesize well-dispersive PS/SiO2 nanocomposites.

  13. Comparing Geophysical Methods for Determining the Thickness of Arctic Sea Ice: Is There a Correlation Between Thickness and Surface Temperature?

    Science.gov (United States)

    Robertson, R.; Bowman, T.; Eagle, J. L.; Fisher, L.; Mankowski, K.; McGrady, N.; Schrecongost, N.; Voll, H.; Zulfiqar, A.; Herman, R. B.

    2016-12-01

    Several small geophysical surveys were conducted on the Chukchi Sea ice just offshore from the Naval Arctic Research Laboratory near Barrow, Alaska, in March, 2016. The goal was to investigate a possible correlation between the surface temperature and the thickness of the sea ice, as well as to test a potential new method for more accurately determining ice thickness. Surveys were conducted using a capacitively coupled resistivity array, a custom built thermal sensor array sled, ground penetrating radar (GPR), and an ice drill. The thermal sensor array was based on an Arduino microcontroller. It used an infrared (IR) sensor to determine surface temperature, and thermistor-based sensors to determine vertical air temperatures at 6 evenly spaced heights up to a maximum of 1.5 meters. Surface temperature (IR) data show possible correlations with ice drill, resistivity, and GPR data. The vertical air sensors showed almost no variation for any survey line which we postulate is due to the constant wind during each survey. Ice drill data show ice thickness along one 200 meter line varied from 79-95 cm, with an average of 87 cm. The thickness appears to be inversely correlated to surface temperatures. Resistivity and IR data both showed abrupt changes when crossing from the shore to the sea ice along a 400 meter line. GPR and IR data showed similar changes along a separate 900 meter line, suggesting that surface temperature and subsurface composition are related. Resistivity data were obtained in two locations by using the array in an expanding dipole-dipole configuration with 2.5 meter dipoles. The depth to the ice/water boundary was calculated using a "cumulative resistivity" plot and matched the depths obtained via the ice drill to within 2%. This has initiated work to develop a microcontroller-based resistivity array specialized for thickness measurements of thin ice.

  14. Contact and directional radiative temperature measurements of sunlit and shaded land surface components during the SEN2FLEX 2005 campaign

    NARCIS (Netherlands)

    Timmermans, J.; Tol, van der C.; Verhoef, W.; Su, Z.

    2008-01-01

    Evapotranspiration models require thermodynamic temperatures as a state variable characterizing the surface energy balance. The thermodynamic temperature is calculated using the brightness temperature and the emissivity because no effective method exists to measure thermodynamic temperatures in spac

  15. Contact and directional radiative temperature measurements of sunlit and shaded land surface components during the SEN2FLEX 2005 campaign

    NARCIS (Netherlands)

    Timmermans, J.; Tol, van der C.; Verhoef, W.; Su, Z.

    2008-01-01

    Evapotranspiration models require thermodynamic temperatures as a state variable characterizing the surface energy balance. The thermodynamic temperature is calculated using the brightness temperature and the emissivity because no effective method exists to measure thermodynamic temperatures in

  16. Low temperature heating and high temperature cooling embedded water based surface heating and cooling systems

    CERN Document Server

    Babiak, Jan; Petras, Dusan

    2009-01-01

    This Guidebook describes the systems that use water as heat-carrier and when the heat exchange within the conditioned space is more than 50% radiant. Embedded systems insulated from the main building structure (floor, wall and ceiling) are used in all types of buildings and work with heat carriers at low temperatures for heating and relatively high temperature for cooling.

  17. Initial adhesion of glass-fiber-reinforced composite to the surface of porcine calvarial bone.

    Science.gov (United States)

    Tuusa, S M R; Lassila, L V J; Matinlinna, J P; Peltola, M J; Vallittu, P K

    2005-11-01

    The aim of this preliminary study was to compare the initial bond strength of the glass-fiber-reinforced composite veil to the surface of the porcine calvarial compact bone using different adhesives. Fiber-reinforced composite (FRC) made of E-glass fiber veil with the BisGMA-PMMA resin system was used in the study. For the shear bond strength test, porcine calvarial bone cubes were mounted into resin matrix. FRC-veil discs were bonded to compact bone with different types of adhesives: (A) BisGMA-HEMA based (3M-ESPE Scotchbond Multi-Purpose Adhesive), (B) 4-META/UDMA/BisGMA based (Unifil Bond Bonding Agent) and MDP based (Clearfil Se Bond adhesive), (C) UDMA/BisGMA/PMMA-based experimental adhesive, and (D) silane-based (APS, ICS, MPS) experimental adhesives. The surface of the bone was mechanically roughened and was either used as such, treated with dental primers (Unifil Bond Self-etching Primer, Clearfil Se Bond Primer), or treated with an experimental silane mixture (APS, ICS, MPS), or with a mixture of the experimental silane liquid and Clearfil Se Bond Primer. The 3M-ESPE Scotchbond Multi-Purpose Adhesive and UDMA/BisGMA/PMMA experimental adhesive gave poor results in the shear bond test (0.58 and 0.40 MPa, respectively). Unifil Bond Bonding Agent and Clearfil Se Bond adhesive with respective primers markedly improved the shear bond strength; with Unifil the result was 3.40 MPa, and with Clearfil it was 6.19 MPa. When the bone surface was primed with a mixture of Clearfil Se Bond Primer and Clearfil Porcelain Bond Activator, the Clearfil Se Bond adhesive-impregnated FRC veil gave the best adhesion to the bone surface in this test: 9.50 MPa. The addition of bioactive glass granules between the veil and the bone lowered the shear bond strength in the test system described above to 6.72 MPa. The test systems with the silane mixture were also promising. In the SEM study, it was found that the mechanical treatment reveals the pores of the bone surface. Chemical

  18. Sea surface temperature and Ekman transport in the Persian Gulf

    Directory of Open Access Journals (Sweden)

    E. H.

    2002-12-01

    Full Text Available   The wind drift motion of the water which is produced by the stress of the wind exerted upon the surface of the ocean is described by Ekmans theory (1905. Using the mean monthly values for the wind stress and SST, seasonal Ekman transport for the Persian Gulf was computed and contoured. The geostrophic winds have combined with the SST to estimate the effect of cooling due to Ekman transport of colder northern waters and inflow from the Oman Sea. The monthly SST mainly obtained from the 10 10 grided data of Levitus atlas and Hormuz Cruis Experiment for 1997.   Analyses show a NW to SE Ekman transport due to wind stress and significant interannual variability of SST on sea surface in the Persian Gulf. The seasonal variation of SST shows a continental pattern due to severe interaction between the land and sea. But these variations somehow moderates because of Ekman transport in Persian Gulf.

  19. Functionalization of graphene and grafting of temperature-responsive surfaces from graphene by ATRP 'on water'

    Energy Technology Data Exchange (ETDEWEB)

    Ren Lulu; Huang Shu; Zhang Chao; Wang Ruiyu [Fudan University, State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science (China); Tjiu, Weng Weei [Institute of Materials Research and Engineering, Agency for Science, Technology and Research (A-STAR) (Singapore); Liu Tianxi, E-mail: txliu@fudan.edu.cn [Fudan University, State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science (China)

    2012-06-15

    Water-dispersible graphene with temperature-responsive surfaces has successfully been synthesized by grafting poly(N-isopropylacrylamide) (PNIPAM) from graphene via surface-initiated atom transfer radical polymerization (ATRP). First, graphene surfaces are functionalized with aminophenol groups by diazonium reaction on water. Subsequently, bromoisobutyrate groups are covalently attached to the phenol-functionalized graphene (G-OH) surface by esterification of 2-bromoisobutyrate with the hydroxyl groups, forming bromoisobutyrate-functionalized graphene (G-Br). Finally, PNIPAM is then grafted from G-Br via ATRP. Data from Raman spectroscopy, {sup 1}H NMR, and transmission electron microscopy (TEM) confirm that PNIPAM chains grow from graphene by ATRP. Thermogravimetric analysis shows that the amount of PNIPAM grown from the graphene increases with the increase of monomer ratios. TEM images also show that functionalized polymer structures (PNIPAM cluster or agglutination) on graphene sheets can be well tuned by controlled polymerization. The obtained graphene-PNIPAM (G-PNIPAM) composite has PNIPAM surface which is highly sensitive to the temperature change. This temperature-responsive and water-dispersible G-PNIPAM composite may find potential applications in environmental devices as well as controlled release drug delivery.

  20. Temperature and biological soil effects on the survival of selected foodborne pathogens on a mortar surface.

    Science.gov (United States)

    Allan, J T; Yan, Z; Genzlinger, L L; Kornacki, J L

    2004-12-01

    The survival of three foodborne pathogens (Listeria monocytogenes, Yersinia enterocolitica, and Salmonella) attached to mortar surfaces, with or without biological soil (porcine serum) and incubated at either 4 or 10 degrees C in the presence of condensate, was evaluated. Soiled and unsoiled coupons were inoculated by immersion into a five-strain cocktail (approximately 10(7) CFU/ml) of each organism type and evaluated. Coupons were incubated at 25 degrees C for 2 h to allow attachment of cells, rinsed to remove unattached cells, and incubated at either 4 or 10 degrees C at high humidity to create condensate on the surface. Sonication was used to remove the attached cells, and bacteria (CFU per coupon) was determined at 9 to 10 sampling periods over 120 h. Yersinia populations decreased more than 5 log units in the presence of serum in a 24-h period. Listeria and Salmonella had better survival on mortar in the presence of serum than Yersinia throughout the 120-h incubation period. Populations of L. monocytogenes declined more rapidly at 10 than at 4 degree C after 24 h. In general, differences in temperature did not affect the survival of Salmonella or Yersinia. Serum had a protective effect on the survival of all three organisms, sustaining populations at significantly (P 0.05) among the mean number (CFU per coupon) of L. monocytogenes, Y. enterocolitica, or Salmonella on initial attachment onto the mortar surfaces (unsoiled). The results indicate relatively rapid destruction of selected pathogenic bacteria on unsoiled mortar surfaces compared with those that contained biological soil, thus highlighting the need for effective cleaning to reduce harborage of these microbes in the food factory environment.