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Sample records for surface runoff electronic

  1. A method of determining surface runoff by

    Science.gov (United States)

    Donald E. Whelan; Lemuel E. Miller; John B. Cavallero

    1952-01-01

    To determine the effects of watershed management on flood runoff, one must make a reliable estimate of how much the surface runoff can be reduced by a land-use program. Since surface runoff is the difference between precipitation and the amount of water that soaks into the soil, such an estimate must be based on the infiltration capacity of the soil.

  2. Total pollution effect of urban surface runoff.

    Science.gov (United States)

    Luo, Hongbing; Luo, Lin; Huang, Gu; Liu, Ping; Li, Jingxian; Hu, Sheng; Wang, Fuxiang; Xu, Rui; Huang, Xiaoxue

    2009-01-01

    For pollution research with regard to urban surface runoff, most sampling strategies to date have focused on differences in land usage. With single land-use sampling, total surface runoff pollution effect cannot be evaluated unless every land usage spot is monitored. Through a new sampling strategy known as mixed stormwater sampling for a street community at discharge outlet adjacent to river, this study assessed the total urban surface runoff pollution effect caused by a variety of land uses and the pollutants washed off from the rain pipe system in the Futian River watershed in Shenzhen City of China. The water quality monitoring indices were COD (chemical oxygen demand), TSS (total suspend solid), TP (total phosphorus), TN (total nitrogen) and BOD (biochemical oxygen demand). The sums of total pollution loads discharged into the river for the four indices of COD, TSS, TN, and TP over all seven rainfall events were very different. The mathematical model for simulating total pollution loads was established from discharge outlet mixed stormwater sampling of total pollution loads on the basis of four parameters: rainfall intensity, total land area, impervious land area, and pervious land area. In order to treat surface runoff pollution, the values of MFF30 (mass first flush ratio) and FF30 (first 30% of runoff volume) can be considered as split-flow control criteria to obtain more effective and economical design of structural BMPs (best management practices) facilities.

  3. Surface runoff in the Itaim Watershed

    Directory of Open Access Journals (Sweden)

    Getulio Teixeira Batista

    2007-06-01

    Full Text Available This paper describes a work done in the Itaim watershed at Taubaté, SP, and had the objective of estimating the surface runoff based on the Curve-Number (CN method in area with vegetation cover of grassland (Brachiaria Decumbens, that prevails in this watershed. The surface runoff was estimated using three different methods: 1st values of accumulated Infiltration (IAc obtained in the field were used, considered as the Potential Infiltration (S, which varied from 15.37 mm to 51.88 mm with an average value of 23.46 mm. With those measured infiltration rates and using the maximum precipitation values for Taubaté, SP, with duration time of 3 hours: P = 54.4; 70.3; 80.8; 86.7; 90.9; 94.1 and 103.9 mm, respectively, for the return times, Tr = 2, 5, 10, 15, 25, 50 and 100 years, the following values of surface runoff were generated: 34.83; 49.33; 59.14; 64.71; 68.69; 71.73 and 81.10 mm, respectively; In the 2nd method it was considered that the prevailing vegetation cover of the watershed was Dirty Pasture (Pasture with regrowth of natural vegetation and therefore, a value of CN = 75 was used and generated a potential infiltration, S = 84,7 mm and resulted in surface runoff values that varied from 11 to 44 mm; In the 3rd method, the value of CN was considered equal to 66.57. This value was calculated weighting the contribution of all land use cover classes of the watershed, and as a result a higher value of potential infiltration, S = 127 mm, was obtained. Consequently, the surface runoff values were 5.33; 11.64; 16.72; 19.83; 22.16; 23.98 and 29.83 mm, respectively. Therefore, the comparison with the results obtained by the two Curve-Number methods (conventional and weighted allowed to be concluded that the Curve-Number method applied in a conventional way underestimated the surface runoff in the studied area. However, results indicate that it is possible to use this method for surface runoff estimates as long as adjustments based on potential

  4. Surface runoff and phosphorus (P) loss from bamboo (Phyllostachys ...

    African Journals Online (AJOL)

    Jane

    2011-08-24

    Aug 24, 2011 ... The average bioavailable phosphorus (BAP) concentration of the runoff was 0.23 mg/l and the various phosphorus ... Key words: Phyllostachys pubescens, ecosystem, surface runoff, phosphorus (P) loss. INTRODUCTION .... runoff samples were used for total P (TP) determination following perchloric acid ...

  5. Mathematical modeling of rainwater runoff over catchment surface ...

    African Journals Online (AJOL)

    Mathematical modeling of rainwater runoff over catchment surface and mass transfer of contaminant incoming to water stream from soil. ... rainwater runoff along the surface catchment taking account the transport of pollution which permeates into the water flow from a porous media of soil at the certain areas of this surface.

  6. Joint variability of global runoff and global sea surface temperatures

    Science.gov (United States)

    McCabe, G.J.; Wolock, D.M.

    2008-01-01

    Global land surface runoff and sea surface temperatures (SST) are analyzed to identify the primary modes of variability of these hydroclimatic data for the period 1905-2002. A monthly water-balance model first is used with global monthly temperature and precipitation data to compute time series of annual gridded runoff for the analysis period. The annual runoff time series data are combined with gridded annual sea surface temperature data, and the combined dataset is subjected to a principal components analysis (PCA) to identify the primary modes of variability. The first three components from the PCA explain 29% of the total variability in the combined runoff/SST dataset. The first component explains 15% of the total variance and primarily represents long-term trends in the data. The long-term trends in SSTs are evident as warming in all of the oceans. The associated long-term trends in runoff suggest increasing flows for parts of North America, South America, Eurasia, and Australia; decreasing runoff is most notable in western Africa. The second principal component explains 9% of the total variance and reflects variability of the El Ni??o-Southern Oscillation (ENSO) and its associated influence on global annual runoff patterns. The third component explains 5% of the total variance and indicates a response of global annual runoff to variability in North Aflantic SSTs. The association between runoff and North Atlantic SSTs may explain an apparent steplike change in runoff that occurred around 1970 for a number of continental regions.

  7. Predicting Surface Runoff from Catchment to Large Region

    Directory of Open Access Journals (Sweden)

    Hongxia Li

    2015-01-01

    Full Text Available Predicting surface runoff from catchment to large region is a fundamental and challenging task in hydrology. This paper presents a comprehensive review for various studies conducted for improving runoff predictions from catchment to large region in the last several decades. This review summarizes the well-established methods and discusses some promising approaches from the following four research fields: (1 modeling catchment, regional and global runoff using lumped conceptual rainfall-runoff models, distributed hydrological models, and land surface models, (2 parameterizing hydrological models in ungauged catchments, (3 improving hydrological model structure, and (4 using new remote sensing precipitation data.

  8. Flood damage claims reveal insights about surface runoff in Switzerland

    Science.gov (United States)

    Bernet, D. B.; Prasuhn, V.; Weingartner, R.

    2015-12-01

    A few case studies in Switzerland exemplify that not only overtopping water bodies frequently cause damages to buildings. Reportedly, a large share of the total loss due to flooding in Switzerland goes back to surface runoff that is formed and is propagating outside of regular watercourses. Nevertheless, little is known about when, where and why such surface runoff occurs. The described process encompasses surface runoff formation, followed by unchannelised overland flow until a water body is reached. It is understood as a type of flash flood, has short response times and occurs diffusely in the landscape. Thus, the process is difficult to observe and study directly. A promising source indicating surface runoff indirectly are houseowners' damage claims recorded by Swiss Public Insurance Companies for Buildings (PICB). In most of Switzerland, PICB hold a monopoly position and insure (almost) every building. Consequently, PICB generally register all damages to buildings caused by an insured natural hazard (including surface runoff) within the respective zones. We have gathered gapless flood related claim records of most of all Swiss PICB covering more than the last two decades on average. Based on a subset, we have developed a methodology to differentiate claims related to surface runoff from other causes. This allows us to assess the number of claims as well as total loss related to surface runoff and compare these to the numbers of overtopping watercourses. Furthermore, with the good data coverage, we are able to analyze surface runoff related claims in space and time, from which we can infer spatial and temporal characteristics of surface runoff. Although the delivered data of PICB are heterogeneous and, consequently, time-consuming to harmonize, our first results show that exploiting these damage claim records is feasible and worthwhile to learn more about surface runoff in Switzerland.

  9. Modelling surface run-off and trends analysis over India

    Indian Academy of Sciences (India)

    responsible for run-off generation plays a major role in run-off modelling at region scales. Remote sensing, GIS and advancement of the computer technology based evaluation of land surface prop- erties at spatial and temporal scales are very useful input data for hydrological models. Using remote sensing data is not only ...

  10. Numerical model of rainwater runoff over the catchment surface and ...

    African Journals Online (AJOL)

    ... runoff along the surface catchment and transport of impurity which permeates into the water flow from soil at the certain areas of this surface. This system consists of two types of equations: the first of them describes the changes of water layer thickness over the slope surface given the precipitation and evaporation, and the ...

  11. Surface runoff in flat terrain: How field topography and runoff generating processes control hydrological connectivity

    NARCIS (Netherlands)

    Appels, W.M.; Bogaart, P.W.; Bogaart, P.W.; Zee, van der S.E.A.T.M.

    2016-01-01

    In flat lowland agricultural catchments in temperate climate zones with highly permeable sandy soils, surface runoff is a rare process with a large impact on the redistribution of sediments and solutes and stream water quality. We examine hydrological data obtained on two field sites in the

  12. Interception of rainfall and surface runoff in the Brazilian Cerrado

    Science.gov (United States)

    Tarso Oliveira, Paulo; Wendland, Edson; Nearing, Mark; Perea Martins, João

    2014-05-01

    The Brazilian Cerrado plays a fundamental role in water resources dynamics because it distributes fresh water to the largest basins in Brazil and South America. In recent decades, the native Cerrado vegetation has increasingly been replaced by agricultural crops and pasture. These land cover and land use changes have altered the hydrological processes. Meanwhile, little is known about the components of the water balance in the Brazilian Cerrado, mainly because the experimental field studies in this region are scarce or nonexistent. The objective of this study was to evaluate two hydrological processes under native Cerrado vegetation, the canopy interception (CI) and the surface runoff (R). The Cerrado physiognomy was classified as "cerrado sensu stricto denso" with an absolute density of 15,278 trees ha-1, and a basal area of 11.44 m2 ha-1. We measured the gross rainfall (P) from an automated tipping bucket rain gauge (model TB4) located in a tower with 11 m of height on the Cerrado. Throughfall (TF) was obtained from 15 automated tipping bucket rain gauges (model Davis) spread below the Cerrado vegetation and randomly relocated every month during the wet season. Stemflow (SF) was measured on 12 trees using a plastic hose wrapped around the trees trunks, sealed with neutral silicone sealant, and a bucket to store the water. The canopy interception was computed by the difference between P and the sum of TF and SF. Surface runoff under undisturbed Cerrado was collected in three plots of 100 m2(5 x 20 m) in size and slope steepness of approximately 0.09 m m-1. The experimental study was conducted between January 2012 and November 2013. We found TF of 81.0% of P and SF of 1.6% of P, i.e. the canopy interception was calculated at 17.4% of P. There was a statistically significant correlation (p 0.8. Our results suggest that the rainfall intensity, the characteristics of the trees trunks (crooked and twisted) and stand structure are the main factors that have influenced

  13. Modelling monthly runoff generation processes following land use changes: groundwater-surface runoff interactions

    Science.gov (United States)

    Bari, M.; Smettem, K. R. J.

    A conceptual water balance model is presented to represent changes in monthly water balance following land use changes. Monthly rainfall-runoff, groundwater and soil moisture data from four experimental catchments in Western Australia have been analysed. Two of these catchments, "Ernies" (control, fully forested) and "Lemon" (54% cleared) are in a zone of mean annual rainfall of 725 mm, while "Salmon" (control, fully forested) and "Wights" (100% cleared) are in a zone with mean annual rainfall of 1125 mm. At the Salmon forested control catchment, streamflow comprises surface runoff, base flow and interflow components. In the Wights catchment, cleared of native forest for pasture development, all three components increased, groundwater levels rose significantly and stream zone saturated area increased from 1% to 15% of the catchment area. It took seven years after clearing for the rainfall-runoff generation process to stabilise in 1984. At the Ernies forested control catchment, the permanent groundwater system is 20 m below the stream bed and so does not contribute to streamflow. Following partial clearing of forest in the Lemon catchment, groundwater rose steadily and reached the stream bed by 1987. The streamflow increased in two phases: (i) immediately after clearing due to reduced evapotranspiration, and (ii) through an increase in the groundwater-induced stream zone saturated area after 1987. After analysing all the data available, a conceptual monthly model was created, comprising four inter-connecting stores: (i) an upper zone unsaturated store, (ii) a transient stream zone store, (ii) a lower zone unsaturated store and (iv) a saturated groundwater store. Data such as rooting depth, Leaf Area Index, soil porosity, profile thickness, depth to groundwater, stream length and surface slope were incorporated into the model as a priori defined attributes. The catchment average values for different stores were determined through matching observed and predicted

  14. Modelling monthly runoff generation processes following land use changes: groundwater–surface runoff interactions

    Directory of Open Access Journals (Sweden)

    M. Bari

    2004-01-01

    Full Text Available A conceptual water balance model is presented to represent changes in monthly water balance following land use changes. Monthly rainfall–runoff, groundwater and soil moisture data from four experimental catchments in Western Australia have been analysed. Two of these catchments, 'Ernies' (control, fully forested and 'Lemon' (54% cleared are in a zone of mean annual rainfall of 725 mm, while 'Salmon' (control, fully forested and 'Wights' (100% cleared are in a zone with mean annual rainfall of 1125 mm. At the Salmon forested control catchment, streamflow comprises surface runoff, base flow and interflow components. In the Wights catchment, cleared of native forest for pasture development, all three components increased, groundwater levels rose significantly and stream zone saturated area increased from 1% to 15% of the catchment area. It took seven years after clearing for the rainfall–runoff generation process to stabilise in 1984. At the Ernies forested control catchment, the permanent groundwater system is 20 m below the stream bed and so does not contribute to streamflow. Following partial clearing of forest in the Lemon catchment, groundwater rose steadily and reached the stream bed by 1987. The streamflow increased in two phases: (i immediately after clearing due to reduced evapotranspiration, and (ii through an increase in the groundwater-induced stream zone saturated area after 1987. After analysing all the data available, a conceptual monthly model was created, comprising four inter-connecting stores: (i an upper zone unsaturated store, (ii a transient stream zone store, (ii a lower zone unsaturated store and (iv a saturated groundwater store. Data such as rooting depth, Leaf Area Index, soil porosity, profile thickness, depth to groundwater, stream length and surface slope were incorporated into the model as a priori defined attributes. The catchment average values for different stores were determined through matching observed and

  15. Water erosion in surface soil conditions: runoff velocity, concentration and D50 index of sediments in runoff

    Directory of Open Access Journals (Sweden)

    Júlio César Ramos

    2016-06-01

    Full Text Available ABSTRACT Water erosion and contamination of water resources are influenced by concentration and diameter of sediments in runoff. This study aimed to quantify runoff velocity and concentration and the D50 index of sediments in runoff under different soil surface managements, in the following treatments: i cropped systems: no-tilled soil covered by ryegrass (Lolium multiflorum Lam. residue, with high soil cover and minimal roughness (HCR; no tilled soil covered by vetch (Vicia sativa L. residue, with high soil cover and minimal roughness (HCV; chiseled soil after ryegrass crop removing the above-ground residues and keeping only the root system, with high roughness (HRR; chiseled soil after vetch crop removing the above-ground residues and keeping only the root system, with high roughness (HRV; ii bare and chiseled soil, with high roughness (BHR. The research was conducted on a Humic Dystrupept under simulated rainfall. The design was completely randomized and each treatment was replicated twice. Eight rainfall events of controlled intensity (65 mm h−1 were applied to each treatment for 90 minutes. The D50 index, runoff velocity and sediment concentration were influenced by crop and soil management. Runoff velocity was more intensely reduced by cover crop residues than by surface roughness. Regardless of surface condition, the D50 index and concentration of sediment in runoff were lower under ryegrass than vetch crop. Runoff velocity and the D50 index were exponentially and inversely correlated with soil cover by residues and with surface roughness, while the D50 index was positively and exponentially correlated with runoff velocity.

  16. Surface runoff generation in a small watershed covered by sugarcane and riparian forest

    Directory of Open Access Journals (Sweden)

    Rafael Pires Fernandes

    2013-12-01

    Full Text Available Since an understanding of how runoff is generated is of great importance to soil conservation, to water availability and to the management of a watershed, the objective of this study was to understand the generation of surface runoff in a watershed covered by sugarcane and riparian forest. Nine surface runoff plots were set up, evenly distributed on the lower, middle and upper slopes. The lower portion was covered by riparian forest. We showed that the average surface runoff coefficient along the slope in the present study was higher than in other studies under different land uses. Furthermore, the surface runoff was higher under sugarcane compared to the riparian forest, especially after sugarcane harvesting. Besides land cover, other factors such as the characteristics of rainfall events, relief and physical soil characteristics such as soil bulk density and saturated hydraulic conductivity influenced the surface runoff generation.

  17. Surface Roughness effects on Runoff and Soil Erosion Rates Under Simulated Rainfall

    Science.gov (United States)

    Soil surface roughness is identified as one of the controlling factors governing runoff and soil loss yet, most studies pay little attention to soil surface roughness. In this study, we analyzed the influence of random soil surface roughness on runoff and soil erosion rates. Bulk samples of a silt l...

  18. The development and evaluation of new runoff parameterization representations coupled with Noah Land Surface Model

    Science.gov (United States)

    Zheng, Z.; Zhang, W.; Xu, J.

    2011-12-01

    As a key component of the global water cycle, runoff plays an important role in earth climate system by affecting the land surface water and energy balance. Realistic runoff parameterization within land surface model (LSM) is significant for accurate land surface modeling and numerical weather and climate prediction. Hence, optimization and refinement of runoff formulation in LSM can further improve model predictive capability of surface-to-atmosphere fluxes which influences the complex interactions between the land surface and atmosphere. Moreover, the performance of runoff simulation in LSM would essential to drought and flood prediction and warning. In this study, a new runoff parameterization named XXT (Xin'anjiang x TOPMODEL) was developed by introducing the water table depth into the soil moisture storage capacity distribution curve (SMSCC) from Xin'anjiang model for surface runoff calculation improvement and then integrating with a TOPMODEL-based groundwater scheme. Several studies had already found a strong correlation between the water table depth and land surface processes. In this runoff parameterization, the dynamic variation of surface and subsurface runoff calculation is connected in a systematic way through the change of water table depth. The XXT runoff parameterization was calibrated and validated with datasets both from observation and Weather Research & Forecasting model (WRF) outputs, the results with high Nash-efficiency coefficient indicated that it has reliable capability of runoff simulation in different climate regions. After model test, the XXT runoff parameterization is coupled with the unified Noah LSM 3.2 instead of simple water balance model (SWB) in order to alleviate the runoff simulating bias which may lead to poor energy partition and evaporation. The impact of XXT is investigated through application of a whole year (1998) simulation at surface flux site of Champaign, Illinois (40.01°N, 88.37°W). The results show that Noah

  19. Experimental study on soluble chemical transfer to surface runoff from soil.

    Science.gov (United States)

    Tong, Juxiu; Yang, Jinzhong; Hu, Bill X; Sun, Huaiwei

    2016-10-01

    Prevention of chemical transfer from soil to surface runoff, under condition of irrigation and subsurface drainage, would improve surface water quality. In this paper, a series of laboratory experiments were conducted to assess the effects of various soil and hydraulic factors on chemical transfer from soil to surface runoff. The factors include maximum depth of ponding water on soil surface, initial volumetric water content of soil, depth of soil with low porosity, type or texture of soil and condition of drainage. In the experiments, two soils, sand and loam, mixed with different quantities of soluble KCl were filled in the sandboxes and prepared under different initial saturated conditions. Simulated rainfall induced surface runoff are operated in the soils, and various ponding water depths on soil surface are simulated. Flow rates and KCl concentration of surface runoff are measured during the experiments. The following conclusions are made from the study results: (1) KCl concentration in surface runoff water would decrease with the increase of the maximum depth of ponding water on soil surface; (2) KCl concentration in surface runoff water would increase with the increase of initial volumetric water content in the soil; (3) smaller depth of soil with less porosity or deeper depth of soil with larger porosity leads to less KCl transfer to surface runoff; (4) the soil with finer texture, such as loam, could keep more fertilizer in soil, which will result in more KCl concentration in surface runoff; and (5) good subsurface drainage condition will increase the infiltration and drainage rates during rainfall event and will decrease KCl concentration in surface runoff. Therefore, it is necessary to reuse drained fertile water effectively during rainfall, without polluting groundwater. These study results should be considered in agriculture management to reduce soluble chemical transfer from soil to surface runoff for reducing non-point sources pollution.

  20. Testing the Runoff Tool in Sicilian vineyards: adopting best management practices to prevent agricultural surface runoff

    Science.gov (United States)

    Singh, Manpriet; Dyson, Jeremy; Capri, Ettore

    2016-04-01

    Over the last decades rainfall has become more intense in Sicily, making large proportions of steeply sloping agricultural land more vulnerable to soil erosion, mainly orchards and vineyards (Diodato and Bellocchi 2010). The prevention of soil degradation is indirectly addressed in the European Union's Water Framework Directive (2000/60/EC) and Sustainable Use Directive (2009/128/EC). As a consequence, new EU compliance conditions for food producers requires them to have tools and solutions for on-farm implementation of sustainable practices (Singh et al. 2014). The Agricultural Runoff and Best Management Practice Tool has been developed by Syngenta to help farm advisers and managers diagnose the runoff potential from fields with visible signs of soil erosion. The tool consists of 4 steps including the assessment of three key landscape factors (slope, topsoil permeability and depth to restrictive horizon) and 9 mainly soil and crop management factors influencing the runoff potential. Based on the runoff potential score (ranging from 0 to 10), which is linked to a runoff potential class, the Runoff Tool uses in-field and edge-of-the-field Best Management Practices (BMPs) to mitigate runoff (aligned with advice from ECPA's TOPPS-prowadis project). The Runoff tool needs testing in different regions and crops to create a number of use scenarios with regional/crop specific advice on BMPs. For this purpose the Tool has been tested in vineyards of the Tasca d'Almerita and Planeta wineries, which are large family-owned estates with long-standing tradition in viticulture in Sicily. In addition to runoff potential scores, Visual Soil Assessment (VSA) scores have been calculated to allow for a comparison between different diagnostic tools. VSA allows for immediate diagnosis of soil quality (a higher score means a better soil quality) including many indicators of runoff (Shepherd 2008). Runoff potentials were moderate to high in all tested fields. Slopes were classified as

  1. Evaluation of alternative surface runoff accounting procedures using the SWAT model

    Science.gov (United States)

    For surface runoff estimation in the Soil and Water Assessment Tool (SWAT) model, the curve number (CN) procedure is commonly adopted to calculate surface runoff by utilizing antecedent soil moisture condition (SCSI) in field. In the recent version of SWAT (SWAT2005), an alternative approach is ava...

  2. Sensitivity-Based Modeling of Evaluating Surface Runoff and Sediment Load using Digital and Analog Mechanisms

    Directory of Open Access Journals (Sweden)

    Olotu Yahaya

    2014-07-01

    Full Text Available Analyses of runoff- sediment measurement and evaluation using automated and convectional runoff-meters was carried out at Meteorological and Hydrological Station of Auchi Polytechnic, Auchi using two runoff plots (ABCDa and EFGHm of area 2m 2 each, depth 0.26 m and driven into the soil to the depth of 0.13m. Runoff depths and intensities were measured from each of the positioned runoff plot. Automated runoff-meter has a measuring accuracy of ±0.001l/±0.025 mm and rainfall depth-intensity was measured using tipping-bucket rainguage during the period of 14-month of experimentation. Minimum and maximum rainfall depths of 1.2 and 190.3 mm correspond to measured runoff depths (MRo of 0.0 mm for both measurement approaches and 60.4 mm and 48.9 mm respectively. Automated runoffmeter provides precise, accurate and instantaneous result over the convectional measurement of surface runoff. Runoff measuring accuracy for automated runoff-meter from the plot (ABCDa produces R 2 = 0.99; while R 2 = 0.96 for manual evaluation in plot (EFGHm. WEPP and SWAT models were used to simulate the obtained hydrological variables from the applied measurement mechanisms. The outputs of sensitivity simulation analysis indicate that data from automated measuring systems gives a better modelling index and such could be used for running robust runoff-sediment predictive modelling technique under different reservoir sedimentation and water management scenarios.

  3. Electron microscopy of surfaces

    International Nuclear Information System (INIS)

    Venables, J.A.

    1981-01-01

    Electron beam techniques used to study clean surfaces and surface processes on a microscopic scale are reviewed. Recent experimental examples and possible future developments are discussed. Special emphasis is given to (i) transmission diffraction and microscopy techniques, including atomic imaging; (ii) Auger microscopy on bulk and thin film samples; (iii) secondary electron microscopy, especially low energy secondaries for work-function imaging and photoelectron imaging; and (iv) reflection electron microscopy and diffraction. (orig.)

  4. Erosivity, surface runoff, and soil erosion estimation using GIS-coupled runoff-erosion model in the Mamuaba catchment, Brazil.

    Science.gov (United States)

    Marques da Silva, Richarde; Guimarães Santos, Celso Augusto; Carneiro de Lima Silva, Valeriano; Pereira e Silva, Leonardo

    2013-11-01

    This study evaluates erosivity, surface runoff generation, and soil erosion rates for Mamuaba catchment, sub-catchment of Gramame River basin (Brazil) by using the ArcView Soil and Water Assessment Tool (AvSWAT) model. Calibration and validation of the model was performed on monthly basis, and it could simulate surface runoff and soil erosion to a good level of accuracy. Daily rainfall data between 1969 and 1989 from six rain gauges were used, and the monthly rainfall erosivity of each station was computed for all the studied years. In order to evaluate the calibration and validation of the model, monthly runoff data between January 1978 and April 1982 from one runoff gauge were used as well. The estimated soil loss rates were also realistic when compared to what can be observed in the field and to results from previous studies around of catchment. The long-term average soil loss was estimated at 9.4 t ha(-1) year(-1); most of the area of the catchment (60%) was predicted to suffer from a low- to moderate-erosion risk (soil erosion was estimated to exceed > 12 t ha(-1) year(-1). Expectedly, estimated soil loss was significantly correlated with measured rainfall and simulated surface runoff. Based on the estimated soil loss rates, the catchment was divided into four priority categories (low, moderate, high and very high) for conservation intervention. The study demonstrates that the AvSWAT model provides a useful tool for soil erosion assessment from catchments and facilitates the planning for a sustainable land management in northeastern Brazil.

  5. Prairie and turf buffer strips for controlling runoff from paved surfaces.

    Science.gov (United States)

    Steinke, K; Stier, J C; Kussow, W R; Thompson, A

    2007-01-01

    Eutrophication of surface waters due to nonpoint source pollution from urban environments has raised awareness of the need to decrease runoff from roads and other impervious surfaces. These concerns have led to precautionary P application restrictions on turf and requirements for vegetative buffer strips. The impacts of two plant communities and three impervious/pervious surface ratios were assessed on runoff water quality and quantity. A mixed forb/grass prairie and a Kentucky bluegrass (Poa pratensis L.) blend were seeded and runoff was monitored and analyzed for total volume, total P, soluble P, soluble organic P, bioavailable P, total suspended solids, and total organic suspended solids. Mean annual runoff volumes, all types of mean annual P nutrient losses, and sediment loads were not significantly affected by treatments because over 80% of runoff occurred during frozen soil conditions. Total P losses from prairie and turf were similar, averaging 1.96 and 2.12 kg ha(-1) yr(-1), respectively. Vegetation appeared to be a likely contributor of nutrients, particularly from prairie during winter dormancy. When runoff occurred during non-frozen soil conditions turf allowed significantly (P runoff volumes compared with prairie vegetation and the 1:2 and 1:4 impervious/pervious surface ratios had less runoff than the 1:1 ratio (P runoff occurs during frozen ground conditions, vegetative buffers strips alone are unlikely to dramatically reduce runoff and nutrient loading into surface waters. Regardless of vegetation type or size, natural nutrient biogeochemical cycling will cause nutrient loss in surface runoff waters, and these values may represent baseline thresholds below which values cannot be obtained.

  6. Weather Radar Adjustment Using Runoff from Urban Surfaces

    DEFF Research Database (Denmark)

    Ahm, Malte; Rasmussen, Michael Robdrup

    2017-01-01

    Weather radar data used for urban drainage applications are traditionally adjusted to point ground references, e.g., rain gauges. However, the available rain gauge density for the adjustment is often low, which may lead to significant representativeness errors. Yet, in many urban catchments......, rainfall is often measured indirectly through runoff sensors. This paper presents a method for weather radar adjustment on the basis of runoff observations (Z-Q adjustment) as an alternative to the traditional Z-R adjustment on the basis of rain gauges. Data from a new monitoring station in Aalborg......, Denmark, were used to evaluate the flow-based weather radar adjustment method against the traditional rain-gauge adjustment. The evaluation was performed by comparing radar-modeled runoff to observed runoff. The methodology was both tested on an events basis and multiple events combined. The results...

  7. Automated Measurement for Sensitivity Analysis of Runoff-Sediment Load at Varying Surface Gradients

    Directory of Open Access Journals (Sweden)

    Imanogor P.A.

    2015-07-01

    Full Text Available Direct measurement of surface runoff is often associated with errors and inaccuracies which results to unreliable hydrological data. An automatic Runoff-meter using tipping buckets arrangement calibrated to tip 0.14 liter of runoff water per tip with an accuracy of ± 0.001 litre was used to measure surface runoff from a steel bounded soil tray of dimension (1200 mm X 900 mm X 260 mm filled with sand loamy to the depth of 130 mm and inclined at angle (0 0 , 5 0 ,12 0 and 15 0 horizontal to the instrument. The effect of varying angles of inclination on runoff intensity, sediment loss rate and sediment loss is significant at 5 % confidence level, while surface runoff is not significant at 5 % confidence level. Total highest sediment loss of 458.2 g and 313.4 g were observed at angle 15 0 and 12 0 respectively. Total surface runoff of 361.5 mm and 445.8 mm were generated at inclined angle of 0 0 and 5 0 , while at angle 12 0 and 15 0 , 564.3 mm and 590.0 mm of surface runoff were generated. In addition, runoff intensity and sediment loss rate were highest at angle 15 0 , while the lowest values of 1.5mm/min and 5.43 g/min were obtained at angle of inclination 5 0 . The results showed that strong relationship existed among the hydrological variables as a result of subjecting the steel bounded soil tray to different angles of inclination. Such results would provide useful data for the running of physics-based deterministic model of surface runoff and erosion which will be useful for the design of hydrological structures, land use planning and management.

  8. Runoff of pyrethroid insecticides from concrete surfaces following simulated and natural rainfalls.

    Science.gov (United States)

    Jiang, Weiying; Haver, Darren; Rust, Michael; Gan, Jay

    2012-03-01

    Intensive residential use of insecticides has resulted in their ubiquitous presence as contaminants in urban surface streams. For pest eradication, urban hard surfaces such as concrete are often directly treated with pesticides, and wind/water can also carry pesticides onto hard surfaces from surrounding areas. This study expanded on previous bench-scale studies by considering pesticide runoff caused by irrigation under dry weather conditions and rain during the wet season, and evaluated the effects of pesticide residence time on concrete, single versus recurring precipitations, precipitation intensity, and concrete surface conditions, on pesticide transferability to runoff water. Runoff from concrete 1 d after pesticide treatment contained high levels of bifenthrin (82 μg/L) and permethrin (5143 μg/L for cis and 5518 μg/L for trans), indicating the importance of preventing water contact on concrete after pesticide treatments. Although the runoff transferability quickly decreased as the pesticide residence time on concrete increased, detectable residues were still found in runoff water after 3 months (89 d) exposure to hot and dry summer conditions. ANOVA analysis showed that precipitation intensities and concrete surface conditions (i.e., acid wash, silicone seal, stamping, and addition of microsilica) did not significantly affect the pesticide transferability to runoff. For concrete slabs subjected to natural rainfalls during the winter wet season, pesticide levels in the runoff decreased as the time interval between pesticide application and the rain event increased. However, bifenthrin and permethrin were still detected at 0.15-0.17 and 0.75-1.15 μg/L in the rain runoff after 7 months (221 d) from the initial treatment. In addition, pesticide concentrations showed no decrease between the two rainfall events, suggesting that concrete surfaces contaminated by pesticides may act as a reservoir for pesticide residues, leading to sustained urban runoff

  9. Feedbacks Between Shallow Groundwater Dynamics and Surface Topography on Runoff Generation in Flat Fields

    Science.gov (United States)

    Appels, Willemijn M.; Bogaart, Patrick W.; van der Zee, Sjoerd E. A. T. M.

    2017-12-01

    In winter, saturation excess (SE) ponding is observed regularly in temperate lowland regions. Surface runoff dynamics are controlled by small topographical features that are unaccounted for in hydrological models. To better understand storage and routing effects of small-scale topography and their interaction with shallow groundwater under SE conditions, we developed a model of reduced complexity to investigate SE runoff generation, emphasizing feedbacks between shallow groundwater dynamics and mesotopography. The dynamic specific yield affected unsaturated zone water storage, causing rapid switches between negative and positive head and a flatter groundwater mound than predicted by analytical agrohydrological models. Accordingly, saturated areas were larger and local groundwater fluxes smaller than predicted, leading to surface runoff generation. Mesotopographic features routed water over larger distances, providing a feedback mechanism that amplified changes to the shape of the groundwater mound. This in turn enhanced runoff generation, but whether it also resulted in runoff events depended on the geometry and location of the depressions. Whereas conditions favorable to runoff generation may abound during winter, these feedbacks profoundly reduce the predictability of SE runoff: statistically identical rainfall series may result in completely different runoff generation. The model results indicate that waterlogged areas in any given rainfall event are larger than those predicted by current analytical groundwater models used for drainage design. This change in the groundwater mound extent has implications for crop growth and damage assessments.

  10. Importance of fine particles in pesticide runoff from concrete surfaces and its prediction.

    Science.gov (United States)

    Jiang, Weiying; Gan, Jay

    2012-06-05

    Pesticides such as pyrethroids have been frequently found in runoff water from urban areas and the offsite movement is a significant cause for aquatic toxicities in urban streams and estuaries. To better understand the origination of pesticide residues in urban runoff, we investigated the association of pyrethroid residues with loose particles in runoff water from concrete surfaces after treatment with commercial products of bifenthrin and permethrin. In runoff water generated from simulated precipitations after 1 to 89 d exposure under dry outdoor conditions, over 80% of the pesticides was found on particles >0.7 μm for most treatments. The solid-water partitioning coefficient (K(d)) on day 1 was estimated to be 2.4 × 10(3) to 1.1 × 10(5) L/kg for permethrin and bifenthrin on these solids. Except for solid formulations, the pesticide-laden particles likely originated from dust particles preexisting on the concrete before treatment and the disintegration of the surficial concrete matter through weathering. We consequently tested a simple sponge-wipe method to collect and analyze the loose particles on concrete. Concurrent analyses (n = 30) showed an excellent linear correlation between the amount of pesticides transferrable to runoff water and that on the wipe (R(2) = 0.78, slope = 1.13 ± 0.11, P contaminating runoff water before runoff actually occurs. The importance of loose particles should be considered when developing practices to mitigate pesticide runoff contamination from urban residential areas.

  11. Direct measurements of meltwater runoff on the Greenland ice sheet surface

    Science.gov (United States)

    Smith, Laurence C.; Yang, Kang; Pitcher, Lincoln H.; Overstreet, Brandon T.; Chu, Vena W.; Rennermalm, Åsa K.; Ryan, Jonathan C.; Cooper, Matthew G.; Gleason, Colin J.; Tedesco, Marco; Jeyaratnam, Jeyavinoth; van As, Dirk; van den Broeke, Michiel R.; van de Berg, Willem Jan; Noël, Brice; Langen, Peter L.; Cullather, Richard I.; Zhao, Bin; Willis, Michael J.; Hubbard, Alun; Box, Jason E.; Jenner, Brittany A.; Behar, Alberto E.

    2017-12-01

    Meltwater runoff from the Greenland ice sheet surface influences surface mass balance (SMB), ice dynamics, and global sea level rise, but is estimated with climate models and thus difficult to validate. We present a way to measure ice surface runoff directly, from hourly in situ supraglacial river discharge measurements and simultaneous high-resolution satellite/drone remote sensing of upstream fluvial catchment area. A first 72-h trial for a 63.1-km2 moulin-terminating internally drained catchment (IDC) on Greenland's midelevation (1,207–1,381 m above sea level) ablation zone is compared with melt and runoff simulations from HIRHAM5, MAR3.6, RACMO2.3, MERRA-2, and SEB climate/SMB models. Current models cannot reproduce peak discharges or timing of runoff entering moulins but are improved using synthetic unit hydrograph (SUH) theory. Retroactive SUH applications to two older field studies reproduce their findings, signifying that remotely sensed IDC area, shape, and supraglacial river length are useful for predicting delays in peak runoff delivery to moulins. Applying SUH to HIRHAM5, MAR3.6, and RACMO2.3 gridded melt products for 799 surrounding IDCs suggests their terminal moulins receive lower peak discharges, less diurnal variability, and asynchronous runoff timing relative to climate/SMB model output alone. Conversely, large IDCs produce high moulin discharges, even at high elevations where melt rates are low. During this particular field experiment, models overestimated runoff by +21 to +58%, linked to overestimated surface ablation and possible meltwater retention in bare, porous, low-density ice. Direct measurements of ice surface runoff will improve climate/SMB models, and incorporating remotely sensed IDCs will aid coupling of SMB with ice dynamics and subglacial systems.

  12. Vegetated Treatment Systems for Removing Contaminants Associated with Surface Water Toxicity in Agriculture and Urban Runoff.

    Science.gov (United States)

    Anderson, Brian S; Phillips, Bryn M; Voorhees, Jennifer P; Cahn, Michael

    2017-05-15

    Urban stormwater and agriculture irrigation runoff contain a complex mixture of contaminants that are often toxic to adjacent receiving waters. Runoff may be treated with simple systems designed to promote sorption of contaminants to vegetation and soils and promote infiltration. Two example systems are described: a bioswale treatment system for urban stormwater treatment, and a vegetated drainage ditch for treating agriculture irrigation runoff. Both have similar attributes that reduce contaminant loading in runoff: vegetation that results in sorption of the contaminants to the soil and plant surfaces, and water infiltration. These systems may also include the integration of granulated activated carbon as a polishing step to remove residual contaminants. Implementation of these systems in agriculture and urban watersheds requires system monitoring to verify treatment efficacy. This includes chemical monitoring for specific contaminants responsible for toxicity. The current paper emphasizes monitoring of current use pesticides since these are responsible for surface water toxicity to aquatic invertebrates.

  13. Grass mulching effect on infiltration, surface runoff and soil loss of three agricultural soils in Nigeria.

    Science.gov (United States)

    Adekalu, K O; Olorunfemi, I A; Osunbitan, J A

    2007-03-01

    Mulching the soil surface with a layer of plant residue is an effective method of conserving water and soil because it reduces surface runoff, increases infiltration of water into the soil and retard soil erosion. The effectiveness of using elephant grass (Pennisetum purpureum) as mulching material was evaluated in the laboratory using a rainfall simulator set at rainfall intensities typical of the tropics. Six soil samples, two from each of the three major soil series representing the main agricultural soils in South Western Nigeria were collected, placed on three different slopes, and mulched with different rates of the grass. The surface runoff, soil loss, and apparent cumulative infiltration were then measured under each condition. The results with elephant grass compared favorably with results from previous experiments using rice straw. Runoff and soil loss decreased with the amount of mulch used and increased with slope. Surface runoff, infiltration and soil loss had high correlations (R = 0.90, 0.89, and 0.86, respectively) with slope and mulch cover using surface response analysis. The mean surface runoff was correlated negatively with sand content, while mean soil loss was correlated positively with colloidal content (clay and organic matter) of the soil. Infiltration was increased and soil loss was reduced greatly with the highest cover. Mulching the soils with elephant grass residue may benefit late cropping (second cropping) by increasing stored soil water for use during dry weather and help to reduce erosion on sloping land.

  14. Glacier surface mass balance and freshwater runoff modeling for the entire Andes Cordillera

    Science.gov (United States)

    Mernild, Sebastian H.; Liston, Glen E.; Yde, Jacob C.

    2017-04-01

    Glacier surface mass balance (SMB) observations for the Andes Cordillera are limited and, therefore, estimates of the SMB contribution from South America to sea-level rise are highly uncertain. Here, we simulate meteorological, snow, glacier surface, and hydrological runoff conditions and trends for the Andes Cordillera (1979/80-2013/14), covering the tropical latitudes in the north down to the sub-polar latitudes in the far south, including the Northern Patagonia Ice Field (NPI) and Southern Patagonia Ice Field (SPI). SnowModel - a fully integrated energy balance, blowing-snow distribution, multi-layer snowpack, and runoff routing model - was used to simulate glacier SMBs for the Andes Cordillera. The Randolph Glacier Inventory and NASA Modern-Era Retrospective Analysis for Research and Applications products, downscaled in SnowModel, allowed us to conduct relatively high-resolution simulations. The simulated glacier SMBs were verified against independent directly-observed and satellite gravimetry and altimetry-derived SMB, indicating a good statistical agreement. For glaciers in the Andes Cordillera, the 35-year mean annual SMB was found to be -1.13 m water equivalent. For both NPI and SPI, the mean SMB was positive (where calving is the likely reason for explaining why geodetic estimates are negative). Further, the spatio-temporal freshwater river runoff patterns from individual basins, including their runoff magnitude and change, were simulated. For the Andes Cordillera rivers draining to the Pacific Ocean, 86% of the simulated runoff originated from rain, 12% from snowmelt, and 2% from ice melt, whereas, for example, for Chile, the water-source distribution was 69, 24, and 7%, respectively. Along the Andes Cordillera, the 35-year mean basin outlet-specific runoff (L s-1 km-2) showed a characteristic regional hourglass shape pattern with highest runoff in both Colombia and Ecuador and in Patagonia, and lowest runoff in the Atacama Desert area.

  15. Critical review: Copper runoff from outdoor copper surfaces at atmospheric conditions.

    Science.gov (United States)

    Hedberg, Yolanda S; Hedberg, Jonas F; Herting, Gunilla; Goidanich, Sara; Odnevall Wallinder, Inger

    2014-01-01

    This review on copper runoff dispersed from unsheltered naturally patinated copper used for roofing and facades summarizes and discusses influencing factors, available literature, and predictive models, and the importance of fate and speciation for environmental risk assessment. Copper runoff from outdoor surfaces is predominantly governed by electrochemical and chemical reactions and is highly dependent on given exposure conditions (size, inclination, geometry, degree of sheltering, and orientation), surface parameters (age, patina composition, and thickness), and site-specific environmental conditions (gaseous pollutants, chlorides, rainfall characteristics (amount, intensity, pH), wind direction, temperature, time of wetness, season). The corrosion rate cannot be used to assess the runoff rate. The extent of released copper varies largely between different rain events and is related to dry and wet periods, dry deposition prior to the rain event and prevailing rain and patina characteristics. Interpretation and use of copper runoff data for environmental risk assessment and management need therefore to consider site-specific factors and focus on average data of long-term studies (several years). Risk assessments require furthermore that changes in copper speciation, bioavailability aspects, and potential irreversible retention on solid surfaces are considered, factors that determine the environmental fate of copper runoff from outdoor surfaces.

  16. Effect of soil surface conditions on runoff velocity and sediment mean aggregate diameter

    Science.gov (United States)

    César Ramos, Júlio; Bertol, Ildegardis; Paz González, Antonio; de Souza Werner, Romeu; Marioti, Juliana; Henrique Bandeira, Douglas; Andrighetti Leolatto, Lidiane

    2013-04-01

    Soil cover and soil management are the factors that most influence soil erosion by water, because they directly affect soil surface roughness and surface cover. The main effect of soil cover by crop residues consists in dissipation of kinetic energy of raindrops and also partly kinetic energy of runoff, so that the soil disaggregation is considerably reduced but, in addition, soil cover captures detached soil particles, retains water on its surface and decreases runoff volume and velocity. In turn, soil surface roughness, influences soil surface water storage and infiltration and also runoff volume and velocity, sediment retention and subsequently water and sediment losses. Based on the above rationale, we performed a field experiment to assess the influence of soil cover and soil surface roughness on decay of runoff velocity as well as on mean diameter of transported sediments (D50 index). The following treatments were evaluated: SRR) residues of Italian ryegrass (Lolium multiflorum) on a smooth soil surfcace, SRV) residues of common vetch (Vicia sativa) on a smooth soil surface, SSR) scarification after cultivation of Italian ryegrass resulting in a rough surface, SSV) scarification after cultivation of common vetch resulting in a rough surface, and SBS) scarified bare soil with high roughness as a control. The field experiments was performed on an Inceptisol in South Brazil under simulated rainfall conditions during 2012. Experimental plots were 11 m long and 3.5 m wide with an area of 38.5 m2. Six successive simulated rainfall tests were applied using a rotating-boom rain simulator. During each test, rain intensity was 60 mmhr-1, whereas rain duration was 90 minutes. Runoff velocity showed no significant differences between cultivated treatments. However, when compared to bare soil treatment, SBS (0.178 m s-1) and irrespective of the presence of surface crop residues or scarification operations, cultivated soil treatments significantly reduced runoff velocity

  17. Urban Land: Study of Surface Run-off Composition and Its Dynamics

    Science.gov (United States)

    Palagin, E. D.; Gridneva, M. A.; Bykova, P. G.

    2017-11-01

    The qualitative composition of urban land surface run-off is liable to significant variations. To study surface run-off dynamics, to examine its behaviour and to discover reasons of these variations, it is relevant to use the mathematical apparatus technique of time series analysis. A seasonal decomposition procedure was applied to a temporary series of monthly dynamics with the annual frequency of seasonal variations in connection with a multiplicative model. The results of the quantitative chemical analysis of surface wastewater of the 22nd Partsjezd outlet in Samara for the period of 2004-2016 were used as basic data. As a result of the analysis, a seasonal pattern of variations in the composition of surface run-off in Samara was identified. Seasonal indices upon 15 waste-water quality indicators were defined. BOD (full), suspended materials, mineralization, chlorides, sulphates, ammonium-ion, nitrite-anion, nitrate-anion, phosphates (phosphorus), iron general, copper, zinc, aluminium, petroleum products, synthetic surfactants (anion-active). Based on the seasonal decomposition of the time series data, the contribution of trends, seasonal and accidental components of the variability of the surface run-off indicators was estimated.

  18. Heavy metal contamination in surface runoff sediments of the urban area of Vilnius, Lithuania

    Directory of Open Access Journals (Sweden)

    Gytautas Ignatavičius

    2017-02-01

    Full Text Available Surface runoff from urbanized territories carries a wide range of pollutants. Sediments in untreated runoff from direct discharge stormwater systems significantly contribute to urban waterway pollution. In this study, heavy metal (Pb, Zn, Cu, Cr, Ba, As and Fe contamination in surface runoff sediments of the urban area of the city of Vilnius was investigated. The surface runoff sediment samples were collected from seven dischargers with the highest volume rate of water flow and concentrations of suspended solids. The geospatial analysis of the distribution of heavy metals shows that there are several active pollution sources supplying the dischargers with contaminated sediments. Most of these areas are located in the central part of the city and in old town with intense traffic. Principal components analysis and t-test results clearly depicted the significantly different chemical compositions of winter and autumn surface sediment samples. The sampling approach and assessment of results provide a useful tool to examine the contamination that is generated in urban areas, distinguish pollution sources and give a better understanding of the importance of permeable surfaces and green areas.

  19. TANK FARM INTERIM SURFACE BARRIER MATERIALS AND RUNOFF ALTERNATIVES STUDY

    Energy Technology Data Exchange (ETDEWEB)

    HOLM MJ

    2009-06-25

    This report identifies candidate materials and concepts for interim surface barriers in the single-shell tank farms. An analysis of these materials for application to the TY tank farm is also provided.

  20. Tank Farm Interim Surface Barrier Materials And Runoff Alternatives Study

    International Nuclear Information System (INIS)

    Holm, M.J.

    2009-01-01

    This report identifies candidate materials and concepts for interim surface barriers in the single-shell tank farms. An analysis of these materials for application to the TY tank farm is also provided.

  1. Aluminum-contaminant transport by surface runoff and bypass flow from an acid sulphate soil

    NARCIS (Netherlands)

    Minh, L.Q.; Tuong, T.P.; Mensvoort, van M.E.F.; Bouma, J.

    2002-01-01

    Quantifying the process and the amount of acid-contaminant released to the surroundings is important in assessing the environmental hazards associated with reclaiming acid sulphate soils (ASS). The roles of surface runoff and bypass flow (i.e. the rapid downward flow of free water along macropores

  2. Water quality of surface runoff and lint yield in cotton under furrow irrigation in Northeast Arkansas

    Science.gov (United States)

    Use of furrow irrigation in row crop production is a common practice through much of the Midsouth US. Problems with these systems arise when nutrients are transported off-site through surface runoff. A field study with cotton (Gossypium hirsutum, L.) was conducted to understand the impact of tillage...

  3. Effect of sugarcane cropping systems on herbicide losses in surface runoff.

    Science.gov (United States)

    Nachimuthu, Gunasekhar; Halpin, Neil V; Bell, Michael J

    2016-07-01

    Herbicide runoff from cropping fields has been identified as a threat to the Great Barrier Reef ecosystem. A field investigation was carried out to monitor the changes in runoff water quality resulting from four different sugarcane cropping systems that included different herbicides and contrasting tillage and trash management practices. These include (i) Conventional - Tillage (beds and inter-rows) with residual herbicides used; (ii) Improved - only the beds were tilled (zonal) with reduced residual herbicides used; (iii) Aspirational - minimum tillage (one pass of a single tine ripper before planting) with trash mulch, no residual herbicides and a legume intercrop after cane establishment; and (iv) New Farming System (NFS) - minimum tillage as in Aspirational practice with a grain legume rotation and a combination of residual and knockdown herbicides. Results suggest soil and trash management had a larger effect on the herbicide losses in runoff than the physico-chemical properties of herbicides. Improved practices with 30% lower atrazine application rates than used in conventional systems produced reduced runoff volumes by 40% and atrazine loss by 62%. There were a 2-fold variation in atrazine and >10-fold variation in metribuzin loads in runoff water between reduced tillage systems differing in soil disturbance and surface residue cover from the previous rotation crops, despite the same herbicide application rates. The elevated risk of offsite losses from herbicides was illustrated by the high concentrations of diuron (14μgL(-1)) recorded in runoff that occurred >2.5months after herbicide application in a 1(st) ratoon crop. A cropping system employing less persistent non-selective herbicides and an inter-row soybean mulch resulted in no residual herbicide contamination in runoff water, but recorded 12.3% lower yield compared to Conventional practice. These findings reveal a trade-off between achieving good water quality with minimal herbicide contamination and

  4. Evaluation of Surface Runoff Generation Processes Using a Rainfall Simulator: A Small Scale Laboratory Experiment

    Science.gov (United States)

    Danáčová, Michaela; Valent, Peter; Výleta, Roman

    2017-12-01

    Nowadays, rainfall simulators are being used by many researchers in field or laboratory experiments. The main objective of most of these experiments is to better understand the underlying runoff generation processes, and to use the results in the process of calibration and validation of hydrological models. Many research groups have assembled their own rainfall simulators, which comply with their understanding of rainfall processes, and the requirements of their experiments. Most often, the existing rainfall simulators differ mainly in the size of the irrigated area, and the way they generate rain drops. They can be characterized by the accuracy, with which they produce a rainfall of a given intensity, the size of the irrigated area, and the rain drop generating mechanism. Rainfall simulation experiments can provide valuable information about the genesis of surface runoff, infiltration of water into soil and rainfall erodibility. Apart from the impact of physical properties of soil, its moisture and compaction on the generation of surface runoff and the amount of eroded particles, some studies also investigate the impact of vegetation cover of the whole area of interest. In this study, the rainfall simulator was used to simulate the impact of the slope gradient of the irrigated area on the amount of generated runoff and sediment yield. In order to eliminate the impact of external factors and to improve the reproducibility of the initial conditions, the experiments were conducted in laboratory conditions. The laboratory experiments were carried out using a commercial rainfall simulator, which was connected to an external peristaltic pump. The pump maintained a constant and adjustable inflow of water, which enabled to overcome the maximum volume of simulated precipitation of 2.3 l, given by the construction of the rainfall simulator, while maintaining constant characteristics of the simulated precipitation. In this study a 12-minute rainfall with a constant intensity

  5. Assessment of the relation between atmospheric precipitation and rainwater runoff for various urban surfaces

    Directory of Open Access Journals (Sweden)

    Romaniak Alicja

    2017-03-01

    Full Text Available The relation between the diurnal sum of atmospheric precipitation and the diurnal volume of rainwater runoff from four experimental hardened surfaces was the subject of a pilot study conducted within the area of the Departmental Agro- and Hydrometeorology Observatory in Wrocław. The selection and the structure of the experimental surfaces were preceded with an inventory-taking of the coverage of hardened surfaces within a Wrocław housing estate with high-rise multifamily buildings. That estate was the second location, next to the area of the Observatory, at which the study presented here was conducted. The surfaces included in the experiment were roof surfaces P1 and P2 covered with heat-sealable roll roofing, surface APB made of gravel-filled openwork concrete plates, and tarmac surface AS. The pilot study was conducted during the period from April to November, 2014. During that period, depending on the type of experimental surface, from 81 to 87 days with atmospheric precipitation were analysed. The mean values of the rainwater runoff coefficients for the eightmonth period were 0.77, 0.77, 0.33 and 0.67 for surfaces P1, P2, APB and AS, respectively. The range of variability of mean values of the coefficients of rainwater runoff from the experimental surfaces in a month is presented by the following relation: APB > P1 > AS > P2. The study did not reveal any direct effect of the number of rainfall days in a month on the value of the coefficient of determination describing the correlation between the diurnal sums of precipitation and the diurnal volumes of rainwater runoff.

  6. Effect of soil surface roughness on infiltration water, ponding and runoff on tilled soils under rainfall simulation experiments

    NARCIS (Netherlands)

    Zhao, Longshan; Hou, Rui; Wu, Faqi; Keesstra, Saskia

    2018-01-01

    Agriculture has a large effect on the properties of the soil and with that on soil hydrology. The partitioning of rainfall into infiltration and runoff is relevant to understand runoff generation, infiltration and soil erosion. Tillage manages soil surface properties and generates soil surface

  7. Inorganic constituents in surface runoff from urbanised areas in winter: the case study of the city of Brest, Belarus

    Directory of Open Access Journals (Sweden)

    Ina Bulskaya

    2014-03-01

    Full Text Available The aim of this paper was to study the inorganic constituents of snow and snowmelt surface runoff in a case study of the city of Brest and to indicate components that could pose a threat to the environment. Samples of snow and snowmelt runoff were analysed for the following parameters: total suspended solids, pH, the contents of nitrate, phosphate and ammonium ions, and of heavy metals. The concentrations of most of these pollutants were higher in the snowmelt runoff than in snow. The concentrations of pollutants in the snowmelt surface runoff exceeded the levels established by national regulations (maximum permissible concentrations.

  8. The measurement of dry deposition and surface runoff to quantify urban road pollution in Taipei, Taiwan.

    Science.gov (United States)

    Wang, Yunn-Jinn; Chen, Chi-Feng; Lin, Jen-Yang

    2013-10-16

    Pollutants deposited on road surfaces and distributed in the environment are a source of nonpoint pollution. Field data are traditionally hard to collect from roads because of constant traffic. In this study, in cooperation with the traffic administration, the dry deposition on and road runoff from urban roads was measured in Taipei City and New Taipei City, Taiwan. The results showed that the dry deposition is 2.01-5.14 g/m(2) · day and 78-87% of these solids are in the 75-300 µm size range. The heavy metals in the dry deposited particles are mainly Fe, Zn, and Na, with average concentrations of 34,978, 1,519 and 1,502 ppm, respectively. Elevated express roads show the highest heavy metal concentrations. Not only the number of vehicles, but also the speed of the traffic should be considered as factors that influence road pollution, as high speeds may accelerate vehicle wear and deposit more heavy metals on road surfaces. In addition to dry deposition, the runoff and water quality was analyzed every five minutes during the first two hours of storm events to capture the properties of the first flush road runoff. The sample mean concentration (SMC) from three roads demonstrated that the first flush runoff had a high pollution content, notably for suspended solid (SS), chemical oxygen demand (COD), oil and grease, Pb, and Zn. Regular sweeping and onsite water treatment facilities are suggested to minimize the pollution from urban roads.

  9. Introduction of inclined open channels for the control of surface runoff of slopes in road structures

    Directory of Open Access Journals (Sweden)

    Hniad O.

    2018-01-01

    Full Text Available The phenomenon of water erosion induced by runoff speeds at the surface of the embankments causes their instability. Particularly in road environments, gullying on the slope's surface due to runoffs causes landslides, which in turn cause considerable damage and consequent disorders to the road network. The aim of this research is to put in place a new technology for superficial water drainage on slope surfaces. Our study has developed a methodology involving the change of the geometric configuration of the water flow, aiming at velocity control of the flows by choosing slanting waterways with small slopes coupled to vertical drains. A modelling of the proposed solution will evaluate its effectiveness as to prevent the erosive factor and to identify other factors that are responsible for slope disorders.

  10. Contamination by urban superficial runoff: accumulated heavy metals on a road surface

    Directory of Open Access Journals (Sweden)

    Carlos Alfonso Zafra Mejía

    2007-01-01

    Full Text Available Studying the behaviour of accumulated contamination on urban surfaces is important in designing control methods minimising the impacts of surface runoff on the environment. This paper presents data regarding the sediment collected on the surface of an urban road in the city of Torrelavega in northern Spain during a period of 65 days during which 132 samples were collected. Two types of sediment collection samples were obtained: vacuumed dry samples (free load and those swept up following vacuuming (fixed load. The results showed that heavy metal concentration in the collected sediment (Pb, Zn, Cu and Cd was inversely proportional to particle diameter. High heavy metal concentrations were found in the smaller fraction (63 pm. Regression equations were calculated for heavy metal concentration regarding particle diameter. Large heavy metal loads were found in the larger fraction (125 pm. The results provide information for analysing runoff water quality in urban areas and designing treatment strategies.

  11. Inverse modeling of hydrologic parameters using surface flux and runoff observations in the Community Land Model

    Science.gov (United States)

    Sun, Y.; Hou, Z.; Huang, M.; Tian, F.; Leung, L. Ruby

    2013-12-01

    This study demonstrates the possibility of inverting hydrologic parameters using surface flux and runoff observations in version 4 of the Community Land Model (CLM4). Previous studies showed that surface flux and runoff calculations are sensitive to major hydrologic parameters in CLM4 over different watersheds, and illustrated the necessity and possibility of parameter calibration. Both deterministic least-square fitting and stochastic Markov-chain Monte Carlo (MCMC)-Bayesian inversion approaches are evaluated by applying them to CLM4 at selected sites with different climate and soil conditions. The unknowns to be estimated include surface and subsurface runoff generation parameters and vadose zone soil water parameters. We find that using model parameters calibrated by the sampling-based stochastic inversion approaches provides significant improvements in the model simulations compared to using default CLM4 parameter values, and that as more information comes in, the predictive intervals (ranges of posterior distributions) of the calibrated parameters become narrower. In general, parameters that are identified to be significant through sensitivity analyses and statistical tests are better calibrated than those with weak or nonlinear impacts on flux or runoff observations. Temporal resolution of observations has larger impacts on the results of inverse modeling using heat flux data than runoff data. Soil and vegetation cover have important impacts on parameter sensitivities, leading to different patterns of posterior distributions of parameters at different sites. Overall, the MCMC-Bayesian inversion approach effectively and reliably improves the simulation of CLM under different climates and environmental conditions. Bayesian model averaging of the posterior estimates with different reference acceptance probabilities can smooth the posterior distribution and provide more reliable parameter estimates, but at the expense of wider uncertainty bounds.

  12. [Pollution Characteristics of Surface Runoff of Typical Town in Chongqing City].

    Science.gov (United States)

    Wang, Long-tao; Duan, Bing-zheng; Zhao, Jian-wei; Hua, Yu-mei; Zhu, Duan-wei

    2015-08-01

    Six kinds of impermeable underlying surface, cement tile roof, asbestos roof, cement flat roof, residential concrete pavement, asphalt pavement of restaurants, asphalt pavement of oil depot, and a combined sewer overflow canal in the Jiansheng town of Dadukou district in Chongqing city were chosen as sample plots to study the characteristics of nutritional pollutants and heavy metals in town runoff. The research showed that the average mass concentrations of TSS, COD, TN, TP in road runoff were (1681.2 +/- 677.2), (1154.7 +/- 415.5), (12.07 +/- 2.72), (3.32 +/- 1.15) mgL(-1), respectively. These pollutants were higher than those in roof runoff which were (13.3 +/- 6.5), (100.4 +/- 24.8), (3.58 +/- 0.70), (0.10 +/- 0.02) mg x L(-1), respectively. TDN accounted for 62.60% +/- 34.38% of TN, and TDP accounted for 42.22% +/- 33.94% of TP in the runoff of impermeable underlying surface. Compared with the central urban runoff, town runoff in our study had higher mass concentrations of these pollutants. The mass concentrations of TSS, COD, TDN, TN, TDP and TP in the combined sewer overflow were (281.57 +/- 308.38), (231.21 +/- 42.95), (8.16 +/- 2.78), (10.60 +/- 3.94), (0.38 +/- 0.23) and (1.51 +/- 0.75) mg x L(-1), respectively. The average levels of heavy metals in this kind of runoff did not exceed the class VI level of the surface water environmental quality standard. Most pollutants in the combined sewer overflow had first flush. However, this phenomenon was very rare for TSS. There was a significant positive correlation between TSS and COD, TP in the combined sewer overflow. And this correlation was significant between NH4+ -N and TP, TDP, TN, TDP. However, a negative correlation existed between NO3- -N and all other indicators.

  13. Retrospective Analysis of Recent Flood Events With Persistent High Surface Runoff From Hydrological Modelling

    Science.gov (United States)

    Joshi, S.; Hakeem, K. Abdul; Raju, P. V.; Rao, V. V.; Yadav, A.; Diwakar, P. G.; Dadhwal, V. K.

    2014-11-01

    Floods are one of the most common and widespread disasters in India, with an estimated 40Mha of land prone to this natural disaster (National Flood Commission, India). Significant loss of property, infrastructure, livestock, public utilities resulting in large economic losses due to floods are recurrent every year in many parts of India. Flood forecasting and early warning is widely recognized and adopted as non-structural measure to lower the damages caused by the flood events. Estimating the rainfall excess that results into excessive river flow is preliminary effort in riverine flood estimation. Flood forecasting models are in general, are event based and do not fully account for successive and persistent excessive surface runoff conditions. Successive high rainfall events result in saturated soil moisture conditions, favourable for high surface runoff conditions. The present study is to explore the usefulness of hydrological model derived surface runoff, running on continuous times-step, to relate to the occurrence of flood inundation due to persistent and successive high surface runoff conditions. Variable Infiltration Capacity (VIC), a macro-scale hydrological model, was used to simulate daily runoff at systematic grid level incorporating daily meteorological data and land cover data. VIC is a physically based, semi-distributed macroscale hydrological model that represents surface and subsurface hydrologic process on spatially distributed grid cell. It explicitly represents sub-grid heterogeneity in land cover classes, taking their phenological changes into account. In this study, the model was setup for entire India using geo-spatial data available from multiple sources (NRSC, NBSS&LUP, NOAA, and IMD) and was calibrated with river discharge data from CWC at selected river basins. Using the grid-wise surface runoff estimates from the model, an algorithm was developed through a set of thresholds of successive high runoff values in order to identify grids

  14. The effect of different surface materials on runoff quality in permeable pavement systems.

    Science.gov (United States)

    Li, Haiyan; Li, Zhifei; Zhang, Xiaoran; Li, Zhuorong; Liu, Dongqing; Li, Tanghu; Zhang, Ziyang

    2017-09-01

    To investigate the effect of different permeable pavement surface materials on the removal of pollutants from urban storm-runoff, six commonly surface materials (porous asphalt, porous concrete, cement brick, ceramic brick, sand base brick, and shale brick) were selected in this study and the research was carried out by column experiments. Except the concentrations of total suspended solids (TSS), chemical oxygen demand (COD), ammonia nitrogen (NH 4 -N), nitrate nitrogen (NO 3 -N), total nitrogen (TN), and total phosphorus (TP) in the influent and effluent that were measured, the removal mechanism of pollutants was discussed further. The results indicate that the surface materials influence the removal efficiency of pollutants greatly and have different effects on certain pollutant. Furthermore, the physical interception and adsorption would be the main mechanism for the removal of pollutants from runoff. For example, for all surface materials, the average removal efficiency of TSS is nearly about 90.0% because of physical interception. Due to the amount of iron oxide, the removal efficiency of COD, NO 3 -N, and TN of shale brick was 88.2, 35.1, and 17.5%, respectively. NH 4 -N and TN can be easily removed by porous asphalt due to the high content of organic matter. By lacking of useful adsorption sites, all the surface materials had little effect on the removal of TP from runoff. This research could offer useful guidelines for the better design of permeable pavement system and promote the insight into the removal mechanism of pollutants in permeable pavement system. Graphical abstract Different types of materials for the different types of pollutants in the runoff purification capacity were significantly different, overall, shale brick and porous asphalt Shale bricks and porous asphalt have a better purification effect according to the six kinds of materials.

  15. Patterns and signatures characterizing the partitioning of precipitation into evapotranspiration and runoff in land surface parameterizations

    Science.gov (United States)

    Yang, Z. L.; Zheng, H.; Lin, P.; Wei, J.; Li, L.; Wu, W. Y.; Zhao, L.; Wang, S.

    2017-12-01

    Quantifying how climate and land surface processes drive the partitioning of precipitation into evapotranspiration (ET) and runoff (R) is important for improving our predictive capability of climate-land interactions. To this end, this study focuses on quantifying the sensitivity of parameterizations for runoff, β-factor, turbulence, and stomatal conductance by employing the North American Land Data Assimilation System (NLDAS) and a 48-member ensemble from the Noah LSM with multi-parameterization (Noah-MP). All 48 Noah-MP simulations systematically overestimate ET and underestimate R in Florida, eastern Texas, and Nebraska, which precisely coincide with the sand distribution from NLDAS, suggesting a need to augment Noah-MP's sand parameters. The impacts of the selected parameterizations on the precipitation partitioning are climate-dependent. The stomatal conductance parameterizations are dominant in humid regions, while the runoff parameterizations are dominant in arid and semi-arid regions. Under snow conditions, incorporating a groundwater module significantly damps the modeled runoff peak and delays the timing. These parameterizations have a direct and seasonal influence on ET, but their influences on R are indirect and cross-seasonal.

  16. Atmospheric deposition and storm induced runoff of heavy metals from different impermeable urban surfaces.

    Science.gov (United States)

    Wicke, Daniel; Cochrane, Thomas A; O'Sullivan, Aisling D

    2012-01-01

    Contaminants deposited on impermeable surfaces migrate to stormwater following rainfall events, but accurately quantifying their spatial and temporal yields useful for mitigation purposes is challenging. To overcome limitations in current sampling methods, a system was developed for rapid quantification of contaminant build-up and wash-off dynamics from different impervious surfaces. Thin boards constructed of concrete and two types of asphalt were deployed at different locations of a large carpark to capture spatially distributed contaminants from dry atmospheric deposition over specified periods of time. Following experimental exposure time, the boards were then placed under a rainfall simulator in the laboratory to generate contaminant runoff under controlled conditions. Single parameter effects including surface roughness and material composition, number of antecedent dry days, rain intensity, and water quality on contaminant build-up and wash-off yields could be investigated. The method was applied to quantify spatial differences in deposition rates of contaminants (TSS, zinc, copper and lead) at two locations varying in their distance to vehicle traffic. Results showed that boards exposed at an unused part of the carpark >50 m from vehicular traffic captured similar amounts of contaminants compared with boards that were exposed directly adjacent to the access route, indicating substantial atmospheric contaminant transport. Furthermore, differences in contaminant accumulation as a function of surface composition were observed. Runoff from asphalt boards yielded higher zinc loads compared with concrete surfaces, whereas runoff from concrete surfaces resulted in higher TSS concentrations attributed to its smoother surfaces. The application of this method enables relationships between individual contaminant behaviour and specific catchment characteristics to be investigated and provides a technique to derive site-specific build-up and wash-off functions required

  17. The effect of GCM biases on global runoff simulations of a land surface model

    Science.gov (United States)

    Papadimitriou, Lamprini V.; Koutroulis, Aristeidis G.; Grillakis, Manolis G.; Tsanis, Ioannis K.

    2017-09-01

    Global climate model (GCM) outputs feature systematic biases that render them unsuitable for direct use by impact models, especially for hydrological studies. To deal with this issue, many bias correction techniques have been developed to adjust the modelled variables against observations, focusing mainly on precipitation and temperature. However, most state-of-the-art hydrological models require more forcing variables, in addition to precipitation and temperature, such as radiation, humidity, air pressure, and wind speed. The biases in these additional variables can hinder hydrological simulations, but the effect of the bias of each variable is unexplored. Here we examine the effect of GCM biases on historical runoff simulations for each forcing variable individually, using the JULES land surface model set up at the global scale. Based on the quantified effect, we assess which variables should be included in bias correction procedures. To this end, a partial correction bias assessment experiment is conducted, to test the effect of the biases of six climate variables from a set of three GCMs. The effect of the bias of each climate variable individually is quantified by comparing the changes in simulated runoff that correspond to the bias of each tested variable. A methodology for the classification of the effect of biases in four effect categories (ECs), based on the magnitude and sensitivity of runoff changes, is developed and applied. Our results show that, while globally the largest changes in modelled runoff are caused by precipitation and temperature biases, there are regions where runoff is substantially affected by and/or more sensitive to radiation and humidity. Global maps of bias ECs reveal the regions mostly affected by the bias of each variable. Based on our findings, for global-scale applications, bias correction of radiation and humidity, in addition to that of precipitation and temperature, is advised. Finer spatial-scale information is also provided

  18. [Inelastic electron scattering from surfaces

    International Nuclear Information System (INIS)

    1993-01-01

    This program uses ab-initio and multiple scattering to study surface dynamical processes; high-resolution electron-energy loss spectroscopy is used in particular. Off-specular excitation cross sections are much larger if electron energies are in the LEED range (50--300 eV). The analyses have been extended to surfaces of ordered alloys. Phonon eigenvectors and eigenfrequencies were used as inputs to electron-energy-loss multiple scattering cross section calculations. Work on low-energy electron and positron holography is mentioned

  19. Surface runoff and retention of transported pollutants in strips of riparian vegetation with and without trees

    Science.gov (United States)

    Giaccio, Gustavo; Laterra, Pedro; Aparicio, Virginia; Costa, Jose Luis

    2017-04-01

    In this study, some aspects related to the effect of the crack willow (Salix fragilis L.) invasion on the reduction of runoff and sediment retention, glyphosate, nitrogen and phosphorus in riparian environments with herbaceous vegetation of the Austral Pampa of Argentina were analysed. In order to evaluate the influence of the willows on the filtering mechanisms, surface runoff simulation experiments were carried out in plots of 1.5 m x 2.5 m in environments characterized by the presence vs. the absence of willows. In spite of the small length of the experimental plots, glyphosate retention in the tree-less plots reached 73.6%, a higher value than that recorded in tree stands (43.8%). However, sediment, nitrogen and phosphorus retention did not vary significantly between treatments. On the other hand, the reduction of the volume of runoff in the sites with trees reached 63%, a superior value to the one registered in strips without trees (31%). The presence of trees only significantly modified the biophysical properties of hydraulic conductivity, surface roughness, aerial biomass and soil moisture, compared to areas with no trees. Partial correlation analysis for both tree and no-tree environments showed that the reduction in runoff volume increased significantly with hydraulic conductivity, soil sand content and depth at the water table, and decreased with apparent density, soil moisture and the slope of the riverbank. However, sediment retention increased significantly with aerial, mulch and root biomass and decreased with the slope of the riparian strip. Glyphosate retention increased significantly with sediment retention and decreased with the slope of the riparian strip and the mulch biomass. Nitrogen retention increased with the reduction of runoff flow, soil hydraulic conductivity and depth to the water table and decreased with slope and sediment retention. While, phosphorus retention increased with sediment retention and decreased with slope and soil content

  20. Multifactor analysis and simulation of the surface runoff and soil infiltration at different slope gradients

    Science.gov (United States)

    Huang, J.; Kang, Q.; Yang, J. X.; Jin, P. W.

    2017-08-01

    The surface runoff and soil infiltration exert significant influence on soil erosion. The effects of slope gradient/length (SG/SL), individual rainfall amount/intensity (IRA/IRI), vegetation cover (VC) and antecedent soil moisture (ASM) on the runoff depth (RD) and soil infiltration (INF) were evaluated in a series of natural rainfall experiments in the South of China. RD is found to correlate positively with IRA, IRI, and ASM factors and negatively with SG and VC. RD decreased followed by its increase with SG and ASM, it increased with a further decrease with SL, exhibited a linear growth with IRA and IRI, and exponential drop with VC. Meanwhile, INF exhibits a positive correlation with SL, IRA and IRI and VC, and a negative one with SG and ASM. INF was going up and then down with SG, linearly rising with SL, IRA and IRI, increasing by a logit function with VC, and linearly falling with ASM. The VC level above 60% can effectively lower the surface runoff and significantly enhance soil infiltration. Two RD and INF prediction models, accounting for the above six factors, were constructed using the multiple nonlinear regression method. The verification of those models disclosed a high Nash-Sutcliffe coefficient and low root-mean-square error, demonstrating good predictability of both models.

  1. Transfer of spatio-temporal multifractal properties of rainfall to simulated surface runoff

    Science.gov (United States)

    Gires, Auguste; Giangola-Murzyn, Agathe; Richard, Julien; Abbes, Jean-Baptiste; Tchiguirinskaia, Ioulia; Schertzer, Daniel; Willinger, Bernard; Cardinal, Hervé; Thouvenot, Thomas

    2014-05-01

    In this paper we suggest to use scaling laws and more specifically Universal Multifractals (UM) to analyse in a spatio-temporal framework both the radar rainfall and the simulated surface runoff. Such tools have been extensively used to analyse and simulate geophysical fields extremely variable over wide range of spatio-temporal scales such as rainfall, but have not often if ever been applied to surface runoff. Such novel combined analysis helps to improve the understanding of the rainfall-runoff relationship. Two catchments of the chair "Hydrology for resilient cities" sponsored by Véolia, and of the European Interreg IV RainGain project are used. They are both located in the Paris area: a 144 ha flat urban area in the Seine-Saint-Denis County, and a 250 ha urban area with a significant portion of forest located on a steep hillside of the Bièvre River. A fully distributed urban hydrological model currently under development called Multi-Hydro is implemented to represent the catchments response. It consists in an interacting core between open source software packages, each of them representing a portion of the water cycle in urban environment. The fully distributed model is tested with pixels of size 5, 10 and 20 m. In a first step the model is validated for three rainfall events that occurred in 2010 and 2011, for which the Météo-France radar mosaic with a resolution of 1 km in space and 5 min in time is available. These events generated significant surface runoff and some local flooding. The sensitivity of the model to the rainfall resolution is briefly checked by stochastically generating an ensemble of realistic downscaled rainfall fields (obtained by continuing the underlying cascade process which is observed on the available range of scales) and inputting them into the model. The impact is significant on both the simulated sewer flow and surface runoff. Then rainfall fields are generated with the help of discrete multifractal cascades and inputted in the

  2. The Measurement of Dry Deposition and Surface Runoff to Quantify Urban Road Pollution in Taipei, Taiwan

    Directory of Open Access Journals (Sweden)

    Jen-Yang Lin

    2013-10-01

    Full Text Available Pollutants deposited on road surfaces and distributed in the environment are a source of nonpoint pollution. Field data are traditionally hard to collect from roads because of constant traffic. In this study, in cooperation with the traffic administration, the dry deposition on and road runoff from urban roads was measured in Taipei City and New Taipei City, Taiwan. The results showed that the dry deposition is 2.01–5.14 g/m2·day and 78–87% of these solids are in the 75–300 µm size range. The heavy metals in the dry deposited particles are mainly Fe, Zn, and Na, with average concentrations of 34,978, 1,519 and 1,502 ppm, respectively. Elevated express roads show the highest heavy metal concentrations. Not only the number of vehicles, but also the speed of the traffic should be considered as factors that influence road pollution, as high speeds may accelerate vehicle wear and deposit more heavy metals on road surfaces. In addition to dry deposition, the runoff and water quality was analyzed every five minutes during the first two hours of storm events to capture the properties of the first flush road runoff. The sample mean concentration (SMC from three roads demonstrated that the first flush runoff had a high pollution content, notably for suspended solid (SS, chemical oxygen demand (COD, oil and grease, Pb, and Zn. Regular sweeping and onsite water treatment facilities are suggested to minimize the pollution from urban roads.

  3. Atrazine, deethylatrazine, and deisopropylatrazine in surface runoff from conservation tilled watersheds.

    Science.gov (United States)

    Shipitalo, Martin J; Owens, Lloyd B

    2003-03-01

    Atrazine and two of its metabolites, deethylatrazine (DEA) and deisopropylatrazine (DIA), are frequently detected in surface runoff. Although their health and environmental effects may be similar to that of atrazine and ratios of their concentrations are useful in delineating sources of contamination, there have been few long-term studies of the factors affecting their losses in runoff. Therefore, losses of atrazine, DEA, and DIA were monitored for six years in runoff from seven small (0.45-0.79 ha) watersheds under three tillage practices. Weather year and the timing of runoff-producing rainfall had a greater effect on atrazine, DEA, and DIA concentrations and losses than did tillage practice. DEA was the most frequently detected metabolite with an average concentration in the year of atrazine application, of 2.5 microg L(-1) compared to 0.7 microg L(-1) for DIA. Atrazine exceeded its 3 /g L(-1) maximum contaminant level (MCL) up to 100 days after application. DEA and DIA exceeded the atrazine MCL up to 50 days after atrazine application; thus, failure to monitor their presence may result in underestimation of the environmental impact of atrazine usage. The molar concentration ratio of DEA to atrazine (DAR) was affected by tillage treatment, weather year, and possibly soil type. These factors may need to be taken into account when DAR is used as an index of atrazine movement. The ratio of DIA to DEA (D2R) was fairly constant and should be useful in determining the parent compounds contributing DIA to surface waters.

  4. Surface runoff and tile drainage transport of phosphorus in the midwestern United States.

    Science.gov (United States)

    Smith, Douglas R; King, Kevin W; Johnson, Laura; Francesconi, Wendy; Richards, Pete; Baker, Dave; Sharpley, Andrew N

    2015-03-01

    The midwestern United States offers some of the most productive agricultural soils in the world. Given the cool humid climate, much of the region would not be able to support agriculture without subsurface (tile) drainage because high water tables may damage crops and prevent machinery usage in fields at critical times. Although drainage is designed to remove excess soil water as quickly as possible, it can also rapidly transport agrochemicals, including phosphorus (P). This paper illustrates the potential importance of tile drainage for P transport throughout the midwestern United States. Surface runoff and tile drainage from fields in the St. Joseph River Watershed in northeastern Indiana have been monitored since 2008. Although the traditional concept of tile drainage has been that it slowly removes soil matrix flow, peak tile discharge occurred at the same time as peak surface runoff, which demonstrates a strong surface connection through macropore flow. On our research fields, 49% of soluble P and 48% of total P losses occurred via tile discharge. Edge-of-field soluble P and total P areal loads often exceeded watershed-scale areal loadings from the Maumee River, the primary source of nutrients to the western basin of Lake Erie, where algal blooms have been a pervasive problem for the last 10 yr. As farmers, researchers, and policymakers search for treatments to reduce P loading to surface waters, the present work demonstrates that treating only surface runoff may not be sufficient to reach the goal of 41% reduction in P loading for the Lake Erie Basin. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  5. Future Changes in Surface Runoff over Korea Projected by a Regional Climate Model under A1B Scenario

    Directory of Open Access Journals (Sweden)

    Ji-Woo Lee

    2014-01-01

    Full Text Available This study assesses future change of surface runoff due to climate change over Korea using a regional climate model (RCM, namely, the Global/Regional Integrated Model System (GRIMs, Regional Model Program (RMP. The RMP is forced by future climate scenario, namely, A1B of Intergovernmental Panel on Climate Change (IPCC Fourth Assessment Report (AR4. The RMP satisfactorily reproduces the observed seasonal mean and variation of surface runoff for the current climate simulation. The distribution of monsoonal precipitation-related runoff is adequately captured by the RMP. In the future (2040–2070 simulation, it is shown that the increasing trend of temperature has significant impacts on the intra-annual runoff variation. The variability of runoff is increased in summer; moreover, the strengthened possibility of extreme occurrence is detected in the future climate. This study indicates that future climate projection, including surface runoff and its variability over Korea, can be adequately addressed on the RMP testbed. Furthermore, this study reflects that global warming affects local hydrological cycle by changing major water budget components. This study adduces that the importance of runoff should not be overlooked in regional climate studies, and more elaborate presentation of fresh-water cycle is needed to close hydrological circulation in RCMs.

  6. A simple model for farmland nitrogen loss to surface runoff with raindrop driven process

    Science.gov (United States)

    Tong, J.; Li, J.

    2016-12-01

    It has been widely recognized that surface runoff from the agricultural fields is an important source of non-point source pollution (NPSP). Moreover, as the agricultural country with the largest nitrogen fertilizer production, import and consumption in the world, our nation should pay greater attention to the over-application and inefficient use of nitrogen (N) fertilizer, which may cause severe pollution both in surface water and groundwater. To figure out the transfer mechanism between the soil solution and surface runoff, lots of laboratory test were conducted and related models were established in this study. But little of them was carried out in field scale since a part of variables are hard to control and some uncontrollable natural factors including rainfall intensity, temperature, wind speeds, soil spatial heterogeneity etc., may affect the field experimental results. Despite that, field tests can better reflect the mechanism of soil chemical loss to surface runoff than laboratory experiments, and the latter tend to oversimplify the environmental conditions. Therefore, a physically based, nitrogen transport model was developed and tested with so called semi-field experiments (i.e., artificial rainfall instead of natural rainfall was applied in the test). Our model integrated both raindrop driven process and diffusion effect along with the simplified nitrogen chain reactions. The established model was solved numerically through the modified Hydrus-1d source code, and the model simulations closely agree with the experimental data. Furthermore, our model indicates that the depth of the exchange layer and raindrop induced water transfer rate are two important parameters, and they have different impacts on the simulation results. The study results can provide references for preventing and controlling agricultural NPSP.

  7. Integrated assessment of climate change impact on surface runoff contamination by pesticides.

    Science.gov (United States)

    Gagnon, Patrick; Sheedy, Claudia; Rousseau, Alain N; Bourgeois, Gaétan; Chouinard, Gérald

    2016-07-01

    Pesticide transport by surface runoff depends on climate, agricultural practices, topography, soil characteristics, crop type, and pest phenology. To accurately assess the impact of climate change, these factors must be accounted for in a single framework by integrating their interaction and uncertainty. This article presents the development and application of a framework to assess the impact of climate change on pesticide transport by surface runoff in southern Québec (Canada) for the 1981-2040 period. The crop enemies investigated were: weeds for corn (Zea mays); and for apple orchard (Malus pumila), 3 insect pests (codling moth [Cydia pomonella], plum curculio [Conotrachelus nenuphar], and apple maggot [Rhagoletis pomonella]), 2 diseases (apple scab [Venturia inaequalis], and fire blight [Erwinia amylovora]). A total of 23 climate simulations, 19 sites, and 11 active ingredients were considered. The relationship between climate and phenology was accounted for by bioclimatic models of the Computer Centre for Agricultural Pest Forecasting (CIPRA) software. Exported loads of pesticides were evaluated at the edge-of-field scale using the Pesticide Root Zone Model (PRZM), simulating both hydrology and chemical transport. A stochastic model was developed to account for PRZM parameter uncertainty. Results of this study indicate that for the 2011-2040 period, application dates would be advanced from 3 to 7 days on average with respect to the 1981-2010 period. However, the impact of climate change on maximum daily rainfall during the application window is not statistically significant, mainly due to the high variability of extreme rainfall events. Hence, for the studied sites and crop enemies considered, climate change impact on pesticide transported in surface runoff is not statistically significant throughout the 2011-2040 period. Integr Environ Assess Managem 2016;12:559-571. © Her Majesty the Queen in Right of Canada 2015; Published 2015 SETAC. © Her Majesty the

  8. Surface freshwater from Bay of Bengal runoff and Indonesian throughflow in the tropical Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Sengupta, D.; Raj, B.; Shenoi, S.S.C.

    haloclines in the BoB. If a shallow halocline resists diapycnal mixing, BoB surface water should continue to stay relatively fresh as it travels to remote regions of the tropical IO. Thus it is likely that most present day models underestimate the true reach...]), to examine BoB freshwater balance. 2. Bay of Bengal Freshwater In addition to several major rivers, numerous smaller streams discharge into the Bay of Bengal. The total an- nual continental runoff into the Bay is 2950 km3, obtained by integrating the Dai...

  9. The Interplay Between Transpiration and Runoff Formulations in Land Surface Schemes Used with Atmospheric Models

    Science.gov (United States)

    Koster, Rindal D.; Milly, P. C. D.

    1997-01-01

    The Project for Intercomparison of Land-surface Parameterization Schemes (PILPS) has shown that different land surface models (LSMS) driven by the same meteorological forcing can produce markedly different surface energy and water budgets, even when certain critical aspects of the LSMs (vegetation cover, albedo, turbulent drag coefficient, and snow cover) are carefully controlled. To help explain these differences, the authors devised a monthly water balance model that successfully reproduces the annual and seasonal water balances of the different PILPS schemes. Analysis of this model leads to the identification of two quantities that characterize an LSM's formulation of soil water balance dynamics: (1) the efficiency of the soil's evaporation sink integrated over the active soil moisture range, and (2) the fraction of this range over which runoff is generated. Regardless of the LSM's complexity, the combination of these two derived parameters with rates of interception loss, potential evaporation, and precipitation provides a reasonable estimate for the LSM's simulated annual water balance. The two derived parameters shed light on how evaporation and runoff formulations interact in an LSM, and the analysis as a whole underscores the need for compatibility in these formulations.

  10. Effect of Saturated Near Surface on Nitrate and Ammonia Nitrogen Losses in Surface Runoff at the Loess Soil Hillslope

    Directory of Open Access Journals (Sweden)

    Yu-bin Zhang

    2010-01-01

    Full Text Available Water pollution from agricultural fields is a global problem and cause of eutrophication of surface waters. A laboratory study was designed to evaluate the effects of near-surface hydraulic gradients on NO3–N and NH4–N losses in surface runoff from soil boxes at 27% slope undersimulated rainfall of a loess soil hillslope. Experimental treatments included two near-surface hydraulic gradients (free drainage, FD; saturation, SA, three fertilizer application rates (control, no fertilizer input; low, 120 kg N ha-1; high, 240 kg N ha-1, and simulated rainfall of 100 mm h-1 was applied for 70 min. The results showed that saturated near-surface soil moisture had dramatic effects on NO3–N and NH4–N losses and water quality. Under the low fertilizer treatment, average NO3–N concentrations in runoff water of SA averaged 2.2 times greater than that of FD, 1.6 times greater for NH4–N. Under the high fertilizer treatment, NO3–N concentrations in runoff water from SA averaged 5.7 times greater than that of FD, 4.3 times greater for NH4–N. Nitrogen loss formed with NO3–N is dominant during the event, but not NH4–N. Under the SA condition, the total loss of NO3–N from low fertilizer treatment was 34.2 to 42.3% of applied nitrogen, while under the FD treatment that was 3.9 to 6.9%. However, the total loss of NH4–N was less than 1% of applied nitrogen. These results showed that saturated condition could make significant contribution to water quality problems.

  11. Regulating urban surface runoff through nature-based solutions - An assessment at the micro-scale.

    Science.gov (United States)

    Zölch, Teresa; Henze, Lisa; Keilholz, Patrick; Pauleit, Stephan

    2017-08-01

    Urban development leads to changes of surface cover that disrupt the hydrological cycle in cities. In particular, impermeable surfaces and the removal of vegetation reduce the ability to intercept, store and infiltrate rainwater. Consequently, the volume of stormwater runoff and the risk of local flooding rises. This is further amplified by the anticipated effects of climate change leading to an increased frequency and intensity of heavy rain events. Hence, urban adaptation strategies are required to mitigate those impacts. A nature-based solution, more and more promoted in politics and academia, is urban green infrastructure as it contributes to the resilience of urban ecosystems by providing services to maintain or restore hydrological functions. However, this poses a challenge to urban planners in deciding upon effective adaptation measures as they often lack information on the performance of green infrastructure to moderate surface runoff. It remains unclear what type of green infrastructure (e.g. trees, green roofs), offers the highest potential to reduce discharge volumes and to what extent. Against this background, this study provides an approach to gather quantitative evidence on green infrastructure's regulation potential. We use a micro-scale scenario modelling approach of different variations of green cover under current and future climatic conditions. The scenarios are modelled with MIKE SHE, an integrated hydrological simulation tool, and applied to a high density residential area of perimeter blocks in Munich, Germany. The results reveal that both trees and green roofs increase water storage capacities and hence reduce surface runoff, although the main contribution of trees lies in increasing interception and evapotranspiration, whereas green roofs allow for more retention through water storage in their substrate. With increasing precipitation intensities as projected under climate change their regulating potential decreases due to limited water

  12. Surface runoff water quality in a managed three zone riparian buffer.

    Science.gov (United States)

    Lowrance, Richard; Sheridan, Joseph M

    2005-01-01

    Managed riparian forest buffers are an important conservation practice but there are little data on the water quality effects of buffer management. We measured surface runoff volumes and nutrient concentrations and loads in a riparian buffer system consisting of (moving down slope from the field) a grass strip, a managed forest, and an unmanaged forest. The managed forest consisted of sections of clear-cut, thinned, and mature forest. The mature forest had significantly lower flow-weighted concentrations of nitrate, ammonium, total Kjeldahl N (TKN), sediment TKN, total N (nitrate + TKN), dissolved molybdate reactive P (DMRP), total P, and chloride. The average buffer represented the conditions along a stream reach with a buffer system in different stages of growth. Compared with the field output, flow-weighted concentrations of nitrate, ammonium, DMRP, and total P decreased significantly within the buffer and flow-weighted concentrations of TKN, total N, and chloride increased significantly within the buffer. All loads decreased significantly from the field to the middle of the buffer, but most loads increased from the middle of the buffer to the sampling point nearest the stream because surface runoff volume increased near the stream. The largest percentage reduction of the incoming nutrient load (at least 65% for all nutrient forms) took place in the grass buffer zone because of the large decrease (68%) in flow. The average buffer reduced loadings for all nutrient species, from 27% for TKN to 63% for sediment P. The managed forest and grass buffer combined was an effective buffer system.

  13. Free and conjugated estrogen exports in surface-runoff from poultry litter-amended soil.

    Science.gov (United States)

    Dutta, Sudarshan; Inamdar, Shreeram; Tso, Jerry; Aga, Diana S; Sims, J Tom

    2010-01-01

    Land application of animal manures such as poultry litter is a common practice, especially in states with surplus manure. Past studies have shown that animal manure may contain estrogens, which are classified as endocrine-disrupting chemicals and may pose a threat to aquatic and wildlife species. We evaluated the concentrations of estrogens in surface runoff from experimental plots (5 x 12 m each) receiving raw and pelletized poultry litter. We evaluated the free (estrone, E1; 17beta-estradiol, E2beta; estriol, E3) and conjugate forms (glucuronides and sulfates) of estrogens, which differ in their toxicity. Sampling was performed for 10 natural storm events over a 4-mo period (April-July 2008). Estrogen concentrations were screened using enzyme-linked immunosorbent assay (ELISA), followed by quantification using liquid chromatography with tandem mass spectrometry (LC/MS/MS). Concentrations of estrogens from ELISA were much higher than the LC/MS/MS values, indicating crossreactivity with organic compounds. Exports of estrogens were much lower from soils amended with pelletized poultry litter than the raw form of the litter. No-tillage management practice also resulted in a lower export of estrogens with surface runoff compared with reduced tillage. The concentrations and exports of conjugate forms of estrogens were much higher than the free forms for some treatments, indicating that the conjugate forms should be considered for a comprehensive assessment of the threat posed by estrogens.

  14. A characterization of Greenland Ice Sheet surface melt and runoff in contemporary reanalyses and a regional climate model

    Science.gov (United States)

    Cullather, Richard; Nowicki, Sophie; Zhao, Bin; Koenig, Lora

    2016-02-01

    For the Greenland Ice Sheet (GrIS), large-scale melt area has increased in recent years and is detectable via remote sensing, but its relation to runoff is not known. Historical, modeled melt area and runoff from Modern-Era Retrospective Analysis for Research and Applications (MERRA-Replay), the Interim Re-Analysis of the European Centre for Medium Range Weather Forecasts (ERA-I), the Climate Forecast System Reanalysis (CFSR), the Modèle Atmosphérique Régional (MAR), and the Arctic System Reanalysis (ASR) are examined. These sources compare favorably with satellite-derived estimates of surface melt area for the period 2000-2012. Spatially, the models markedly disagree on the number of melt days in the interior of the southern part of the ice sheet, and on the extent of persistent melt areas in the northeastern GrIS. Temporally, the models agree on the mean seasonality of daily surface melt and on the timing of large-scale melt events in 2012. In contrast, the models disagree on the amount, seasonality, spatial distribution, and temporal variability of runoff. As compared to global reanalyses, time series from MAR indicate a lower correlation between runoff and melt area (r2 = 0.805). Runoff in MAR is much larger in the second half of the melt season for all drainage basins, while the ASR indicates larger runoff in the first half of the year. This difference in seasonality for the MAR and to an extent for the ASR provide a hysteresis in the relation between runoff and melt area, which is not found in the other models. The comparison points to a need for reliable observations of surface runoff.

  15. Reducing dissolved inorganic nitrogen in surface runoff water from sugarcane production systems.

    Science.gov (United States)

    Webster, A J; Bartley, R; Armour, J D; Brodie, J E; Thorburn, P J

    2012-01-01

    Nitrogen (N) lost from farms, especially as the highly bioavailable dissolved inorganic form, may be damaging Australia's Great Barrier Reef (GBR). As sugarcane is the dominant cropping system in GBR catchments, its N management practises are coming under increasing scrutiny. This study measured dissolved inorganic N lost in surface runoff water and sugarcane productivity over 3 years. The experiment compared the conventional fertiliser N application rate to sugarcane (average 180kg N/ha/year) and a rate based on replacing N exported in the previous crop (average 94kg N/ha/year). Dissolved inorganic N losses in surface water were 72%, 48% and 66% lower in the three monitored years in the reduced N fertiliser treatment. There was no significant difference in sugarcane yield between the two fertiliser N treatments, nor any treatment difference in soil mineral N - both of these results are indicators of the sustainability of the lower fertiliser N applications. Copyright © 2012 Elsevier Ltd. All rights reserved.

  16. Evaluating the Hydrologic Sensitivities of Three Land Surface Models to Bound Uncertainties in Runoff Projections

    Science.gov (United States)

    Chiao, T.; Nijssen, B.; Stickel, L.; Lettenmaier, D. P.

    2013-12-01

    Hydrologic modeling is often used to assess the potential impacts of climate change on water availability and quality. A common approach in these studies is to calibrate the selected model(s) to reproduce historic stream flows prior to the application of future climate projections. This approach relies on the implicit assumptions that the sensitivities of these models to meteorological fluctuations will remain relatively constant under climate change and that these sensitivities are similar among models if all models are calibrated to the same historic record. However, even if the models are able to capture the historic variability in hydrological variables, differences in model structure and parameter estimation contribute to the uncertainties in projected runoff, which confounds the incorporation of these results into water resource management decision-making. A better understanding of the variability in hydrologic sensitivities between different models can aid in bounding this uncertainty. In this research, we characterized the hydrologic sensitivities of three watershed-scale land surface models through a case study of the Bull Run watershed in Northern Oregon. The Distributed Hydrology Soil Vegetation Model (DHSVM), Precipitation-Runoff Modeling System (PRMS), and Variable Infiltration Capacity model (VIC) were implemented and calibrated individually to historic streamflow using a common set of long-term, gridded forcings. In addition to analyzing model performances for a historic period, we quantified the temperature sensitivity (defined as change in runoff in response to change in temperature) and precipitation elasticity (defined as change in runoff in response to change in precipitation) of these three models via perturbation of the historic climate record using synthetic experiments. By comparing how these three models respond to changes in climate forcings, this research aims to test the assumption of constant and similar hydrologic sensitivities. Our

  17. International approaches to the hydraulic control of surface water runoff in mitigating flood and environmental risks

    Directory of Open Access Journals (Sweden)

    Ballard Bridget Woods

    2016-01-01

    Full Text Available This paper compares and contrasts a number of international approaches to the hydraulic control of surface water runoff from new development and redevelopment, known as sustainable drainage systems (SuDS or low impact development (LID. The paper provides a commentary on the progress and current status of national standards for SuDS in the UK to control the frequency, flow rate and volume of runoff from both frequent and extreme rainfall events, and the best practice design criteria presented in the revised UK CIRIA SuDS Manual, published in November 2015. The paper then compares these design criteria and standards with those developed and applied in China, USA, France and Germany and also looks at the drivers behind their development. The benefits of these different approaches are assessed in the context of flood risk mitigation, climate resilience and wider environmental protection objectives, including water quality, morphology and ecology. The paper also reviews the design approaches promoted by the new SuDS Manual and internationally for delivering additional benefits for urban spaces (such as recreation, visual character, education and economic growth through multi-functional urban design.

  18. Design and Season Influence Nitrogen Dynamics in Two Surface Flow Constructed Wetlands Treating Nursery Irrigation Runoff

    Directory of Open Access Journals (Sweden)

    Sarah A. White

    2017-12-01

    Full Text Available Constructed wetlands (CWs are used to remediate runoff from a variety of agricultural, industrial, and urban sources. CW remediation performance is often evaluated at the laboratory scale over durations less than one year. The purpose of this study was to characterize the effect of CW design (cell depth and residence time on nitrogen (N speciation and fate across season and years in two free water surface wetlands receiving runoff from irrigated plant production areas at an ornamental plant nursery. Water quality (mg·L−1 of nitrate, nitrite, and ammonium, dissolved oxygen and oxidation reduction potential was monitored at five sites within each of two CWs each month over four years. Nitrate-N was the dominant form of ionic N present in both CWs. Within CW1, a deep cell to shallow cell design, nitrate comprised 86% of ionic N in effluent. Within CW2, designed with three sequential deep cells, nitrate comprised only 66% of total N and ammonium comprised 27% of total N in CW2 effluent. Differences in ionic N removal efficacies and shifts in N speciation in CW1 and CW2 were controlled by constructed wetland design (depth and hydraulic retention time, the concentration of nutrients entering the CW, and plant species richness.

  19. The effect of leaf litter cover on surface runoff and soil erosion in Northern China.

    Directory of Open Access Journals (Sweden)

    Xiang Li

    Full Text Available The role of leaf litter in hydrological processes and soil erosion of forest ecosystems is poorly understood. A field experiment was conducted under simulated rainfall in runoff plots with a slope of 10%. Two common types of litter in North China (from Quercus variabilis, representing broadleaf litter, and Pinus tabulaeformis, representing needle leaf litter, four amounts of litter, and five rainfall intensities were tested. Results revealed that the litter reduced runoff and delayed the beginning of runoff, but significantly reduced soil loss (p<0.05. Average runoff yield was 29.5% and 31.3% less than bare-soil plot, and for Q. variabilis and P. tabulaeformis, respectively, and average sediment yield was 85.1% and 79.9% lower. Rainfall intensity significantly affected runoff (R = 0.99, p<0.05, and the efficiency in runoff reduction by litter decreased considerably. Runoff yield and the runoff coefficient increased dramatically by 72.9 and 5.4 times, respectively. The period of time before runoff appeared decreased approximately 96.7% when rainfall intensity increased from 5.7 to 75.6 mm h-1. Broadleaf and needle leaf litter showed similarly relevant effects on runoff and soil erosion control, since no significant differences (p≤0.05 were observed in runoff and sediment variables between two litter-covered plots. In contrast, litter mass was probably not a main factor in determining runoff and sediment because a significant correlation was found only with sediment in Q. variabilis litter plot. Finally, runoff yield was significantly correlated (p<0.05 with sediment yield. These results suggest that the protective role of leaf litter in runoff and erosion processes was crucial, and both rainfall intensity and litter characteristics had an impact on these processes.

  20. High spatial-temporal resolution and integrated surface and subsurface precipitation-runoff modelling for a small stormwater catchment

    Science.gov (United States)

    Hailegeorgis, Teklu T.; Alfredsen, Knut

    2018-02-01

    Reliable runoff estimation is important for design of water infrastructure and flood risk management in urban catchments. We developed a spatially distributed Precipitation-Runoff (P-R) model that explicitly represents the land cover information, performs integrated modelling of surface and subsurface components of the urban precipitation water cycle and flow routing. We conducted parameter calibration and validation for a small (21.255 ha) stormwater catchment in Trondheim City during Summer-Autumn events and season, and snow-influenced Winter-Spring seasons at high spatial and temporal resolutions of respectively 5 m × 5 m grid size and 2 min. The calibration resulted in good performance measures (Nash-Sutcliffe efficiency, NSE = 0.65-0.94) and acceptable validation NSE for the seasonal and snow-influenced periods. The infiltration excess surface runoff dominates the peak flows while the contribution of subsurface flow to the sewer pipes also augments the peak flows. Based on the total volumes of simulated flow in sewer pipes (Qsim) and precipitation (P) during the calibration periods, the Qsim/P ranges from 21.44% for an event to 56.50% for the Winter-Spring season, which are in close agreement with the observed volumes (Qobs/P). The lowest percentage of precipitation volume that is transformed to the total simulated runoff in the catchment (QT) is 79.77%. Computation of evapotranspiration (ET) indicated that the ET/P is less than 3% for the events and snow-influenced seasons while it is about 18% for the Summer-Autumn season. The subsurface flow contribution to the sewer pipes are markedly higher than the total surface runoff volume for some events and the Summer-Autumn season. The peakiest flow rates correspond to the Winter-Spring season. Therefore, urban runoff simulation for design and management purposes should include two-way interactions between the subsurface runoff and flow in sewer pipes, and snow-influenced seasons. The developed urban P-R model is

  1. Surface runoff and subsurface tile drain losses of neonicotinoids and companion herbicides at edge-of-field.

    Science.gov (United States)

    Chrétien, François; Giroux, Isabelle; Thériault, Georges; Gagnon, Patrick; Corriveau, Julie

    2017-05-01

    With their application as seed coatings, the use of neonicotinoid insecticides increased dramatically during the last decade. They are now frequently detected in aquatic ecosystems at concentrations susceptible to harm aquatic invertebrates at individual and population levels. This study intent was to document surface runoff and subsurface tile drain losses of two common neonicotinoids (thiamethoxam and clothianidin) compared to those of companion herbicides (atrazine, glyphosate, S-metolachlor and mesotrione) at the edge of a 22.5-ha field under a corn-soybean rotation. A total of 14 surface runoff and tile drain discharge events were sampled over two years. Events and annual unit mass losses were computed using flow-weighted concentrations and total surface runoff and tile drain flow volumes. Detection frequencies close to 100% in edge-of-field surface runoff and tile drain water samples were observed for thiamethoxam and clothianidin even though only thiamethoxam had been applied in the first year. In 2014, thiamethoxam median concentrations in surface runoff and tile drain samples were respectively 0.46 and 0.16 μg/L, while respective maximum concentrations of 2.20 and 0.44 μg/L were measured in surface runoff and tile drain samples during the first post-seeding storm event. For clothianidin, median concentrations in surface runoff and tile drain samples were 0.02 and 0.01, μg/L, and respective maximum concentrations were 0.07 μg/L and 0.05 μg/L. Surface runoff and tile drain discharge were key transport mechanisms with similar contributions of 53 and 47% of measured mass losses, respectively. Even if thiamethoxam was applied at a relatively low rate and had a low mass exportation value (0.3%), the relative toxicity was one to two orders of magnitude higher than those of the other chemicals applied in 2014 and 2015. Companion herbicides, except glyphosate in tile drains, exceeded their water quality guideline during one sampling campaign after

  2. The Impact Of Snow Melt On Surface Runoff Of Sava River In Slovenia

    Science.gov (United States)

    Horvat, A.; Brilly, M.; Vidmar, A.; Kobold, M.

    2009-04-01

    Snow is a type of precipitation in the form of crystalline water ice, consisting of a multitude of snowflakes that fall from clouds. Snow remains on the ground until it melts or sublimates. Spring snow melt is a major source of water supply to areas in temperate zones near mountains that catch and hold winter snow, especially those with a prolonged dry summer. In such places, water equivalent is of great interest to water managers wishing to predict spring runoff and the water supply of cities downstream. In temperate zone like in Slovenia the snow melts in the spring and contributes certain amount of water to surface flow. This amount of water can be great and can cause serious floods in case of fast snow melt. For this reason we tried to determine the influence of snow melt on the largest river basin in Slovenia - Sava River basin, on surface runoff. We would like to find out if snow melt in Slovenian Alps can cause spring floods and how serious it can be. First of all we studied the caracteristics of Sava River basin - geology, hydrology, clima, relief and snow conditions in details for each subbasin. Furtermore we focused on snow and described the snow phenomenom in Slovenia, detailed on Sava River basin. We collected all available data on snow - snow water equivalent and snow depth. Snow water equivalent is a much more useful measurement to hydrologists than snow depth, as the density of cool freshly fallen snow widely varies. New snow commonly has a density of between 5% and 15% of water. But unfortunately there is not a lot of available data of SWE available for Slovenia. Later on we compared the data of snow depth and river runoff for some of the 40 winter seasons. Finally we analyzed the use of satellite images for Slovenia to determine the snow cover for hydrology reason. We concluded that snow melt in Slovenia does not have a greater influence on Sava River flow. The snow cover in Alps can melt fast due to higher temperatures but the water distributes

  3. Groundwater Recharge Rates and Surface Runoff Response to Land Use and Land Cover Changes in Semi-arid Environments

    Science.gov (United States)

    Owuor, Steven; Butterbach-Bahl, Klaus; Guzha, Alphonce; Rufino, Mariana; Pelster, David; Díaz-Pinés, Eugenio; Breuer, Lutz; Merbold, Lutz

    2017-04-01

    Conclusive evidence and understanding of the effects of land use and land cover (LULC) on both groundwater recharge and surface runoff is critical for effective management of water resources in semi-arid region as those heavily depend on groundwater resources. However, there is limited quantitative evidence on how changes to LULC in semi-arid tropical and subtropical regions affect the subsurface components of the hydrologic cycle, particularly groundwater recharge. In this study, we reviewed a total of 27 studies (2 modelling and 25 experimental), which reported on pre- and post-land use change groundwater recharge or surface runoff magnitude, and thus allowed to quantify the response of groundwater recharge rates and runoff to LULC. Restoration of bare land induces a decrease in groundwater recharge from 42 % of precipitation to between 6 and 12 % depending on the final LULC. If forests are cleared for rangelands, groundwater recharge increases by 7.8 ± 12.6 %, while conversion to cropland or grassland results in increases of 3.4 ± 2.5 and 4.4 ± 3.3 %, respectively. Rehabilitation of bare land to cropland results in surface runoff reductions of between 5.2 and 7.3 %. The conversion of forest vegetation to managed LULC shows an increase in surface runoff from 1 to 14.1 % depending on the final LULC. Surface runoff is reduced from 2.5 to 1.1 % when grassland is converted to forest vegetation. While there is general consistency in the results from the selected case studies, we conclude that there are few experimental studies that have been conducted in tropical and subtropical semi-arid regions, despite that many people rely heavily on groundwater for their livelihoods. Therefore, there is an urgent need to increase the body of quantitative evidence given the pressure of growing human population and climate change on water resources in the region.

  4. [Inelastic electron scattering from surfaces

    International Nuclear Information System (INIS)

    1993-01-01

    This program is aimed at the quantitative study of surface dynamical processes (vibrational, magnetic excitations) in crystalline slabs, ultrathin-layered materials, and chemisorbed systems on substrates, and of the geometric structure connected to these dynamical excitations. High-resolution electron-energy loss spectroscopy (HREELS) is a powerful probe. Off-specular excitation cross sections are much larger if electron energies are in the LEED range (50-300 eV). The analyses has been used to study surfaces of ordered alloys (NiAl). Ab-initio surface lattice dynamical results were combined with phonon-loss cross sections to achieve a more accurate microscopic description. First-principles phonon eigenvectors and eigenfrequencies were used as inputs to electron-energy-loss multiple scattering cross-section calculations. The combined microscopic approach was used to analyze EELS data of Cu(0001) and Ag(001) at two points. Positron diffraction is discussed as a structural and imaging tool. The relation between geometric structure of a film and its local magnetic properties will be studied in the future, along with other things

  5. Influence of the Precision of LIDAR Data in Surface Water Runoff Estimation for Road Maintenance

    Science.gov (United States)

    González-Jorge, H.; Díaz-Vilariño, L.; Lagüela, S.; Martínez-Sánchez, J.; Arias, P.

    2015-08-01

    Roads affect the natural surface and subsurface drainage pattern of a hill or a watershed. Road drainage systems are designed with the objective of reducing the energy generated by the flowing water and the presence of excess water or moisture within the road. A poorly designed drainage may affect to road maintenance causing cut or fill failures, road surface erosion and degrading the engineering properties of the materials with which it was constructed. Surface drainage pattern can be evaluated from Digital Elevation Models typically calculated from point clouds acquired with aerial LiDAR platforms. However, these systems provide low resolution point clouds especially in cases where slopes with steep grades exist. In this work, Mobile LiDAR systems (aerial and terrestrial) are combined for surveying roads and their surroundings in order to provide complete point cloud. As the precision of the point clouds obtained from these mobile systems is influenced by GNSS outages, Gaussian noise with different standard deviation values is introduced in the point cloud in order to determine its influence in the evaluation of water runoff direction. Results depict an increase in the differences of flow direction with the decrease of cell size of the raster dataset and with the increase of Gaussian noise. The last relation fits to a second-order polynomial Differences in flow direction up to 42º are achieved for a cell size of 0.5 m with a standard deviation of 0.15 m.

  6. INFLUENCE OF THE PRECISION OF LIDAR DATA IN SURFACE WATER RUNOFF ESTIMATION FOR ROAD MAINTENANCE

    Directory of Open Access Journals (Sweden)

    H. González-Jorge

    2015-08-01

    Full Text Available Roads affect the natural surface and subsurface drainage pattern of a hill or a watershed. Road drainage systems are designed with the objective of reducing the energy generated by the flowing water and the presence of excess water or moisture within the road. A poorly designed drainage may affect to road maintenance causing cut or fill failures, road surface erosion and degrading the engineering properties of the materials with which it was constructed. Surface drainage pattern can be evaluated from Digital Elevation Models typically calculated from point clouds acquired with aerial LiDAR platforms. However, these systems provide low resolution point clouds especially in cases where slopes with steep grades exist. In this work, Mobile LiDAR systems (aerial and terrestrial are combined for surveying roads and their surroundings in order to provide complete point cloud. As the precision of the point clouds obtained from these mobile systems is influenced by GNSS outages, Gaussian noise with different standard deviation values is introduced in the point cloud in order to determine its influence in the evaluation of water runoff direction. Results depict an increase in the differences of flow direction with the decrease of cell size of the raster dataset and with the increase of Gaussian noise. The last relation fits to a second-order polynomial Differences in flow direction up to 42º are achieved for a cell size of 0.5 m with a standard deviation of 0.15 m.

  7. Granulometric characterization of sediments transported by surface runoff generated by moving storms

    Directory of Open Access Journals (Sweden)

    J. L. M. P. de Lima

    2008-12-01

    Full Text Available Due to the combined effect of wind and rain, the importance of storm movement to surface flow has long been recognized, at scales ranging from headwater scales to large basins. This study presents the results of laboratory experiments designed to investigate the influence of moving rainfall storms on the dynamics of sediment transport by surface runoff. Experiments were carried out, using a rain simulator and a soil flume. The movement of rainfall was generated by moving the rain simulator at a constant speed in the upstream and downstream directions along the flume. The main objective of the study was to characterize, in laboratory conditions, the distribution of sediment grain-size transported by rainfall-induced overland flow and its temporal evolution. Grain-size distribution of the eroded material is governed by the capacity of flow that transports sediments. Granulometric curves were constructed using conventional hand sieving and a laser diffraction particle size analyser (material below 0.250 mm for overland flow and sediment deliveries collected at the flume outlet. Surface slope was set at 2%, 7% and 14%. Rainstorms were moved with a constant speed, upslope and downslope, along the flume or were kept static. The results of laboratory experiments show that storm movement, affecting the spatial and temporal distribution of rainfall, has a marked influence on the grain-size characteristics of sediments transported by overland flow. The downstream-moving rainfall storms have higher stream power than do other storm types.

  8. The Effect of Leaf Litter Cover on Surface Runoff and Soil Erosion in Northern China

    Science.gov (United States)

    Li, Xiang; Niu, Jianzhi; Xie, Baoyuan

    2014-01-01

    The role of leaf litter in hydrological processes and soil erosion of forest ecosystems is poorly understood. A field experiment was conducted under simulated rainfall in runoff plots with a slope of 10%. Two common types of litter in North China (from Quercus variabilis, representing broadleaf litter, and Pinus tabulaeformis, representing needle leaf litter), four amounts of litter, and five rainfall intensities were tested. Results revealed that the litter reduced runoff and delayed the beginning of runoff, but significantly reduced soil loss (prunoff yield was 29.5% and 31.3% less than bare-soil plot, and for Q. variabilis and P. tabulaeformis, respectively, and average sediment yield was 85.1% and 79.9% lower. Rainfall intensity significantly affected runoff (R = 0.99, prunoff reduction by litter decreased considerably. Runoff yield and the runoff coefficient increased dramatically by 72.9 and 5.4 times, respectively. The period of time before runoff appeared decreased approximately 96.7% when rainfall intensity increased from 5.7 to 75.6 mm h−1. Broadleaf and needle leaf litter showed similarly relevant effects on runoff and soil erosion control, since no significant differences (p≤0.05) were observed in runoff and sediment variables between two litter-covered plots. In contrast, litter mass was probably not a main factor in determining runoff and sediment because a significant correlation was found only with sediment in Q. variabilis litter plot. Finally, runoff yield was significantly correlated (prunoff and erosion processes was crucial, and both rainfall intensity and litter characteristics had an impact on these processes. PMID:25232858

  9. Effect of Rock Fragment Cover on Hydraulics Properties of Surface Flows and Rill Initiation with Simulating Runoff under Natural Conditions

    Directory of Open Access Journals (Sweden)

    sara kalbali

    2017-06-01

    Full Text Available Introduction: Rock fragments on soil surfaces can also have several contrasting effects on the hydraulics of overland flow and soil erosion processes. Many investigators have found that a cover of rock fragments on a soil surface can decrease its erosion potential compared to bare soil surface (1, 12 and 18. This has mainly been attributed to the protection of the soil surface by rock fragments against the beating action of rain. This leads to a decrease in the intensity of surface sealing, an increase in the infiltration rate, a decrease in the runoff volume and rate, and, hence, a decrease in sediment generation and production for soils covered by rock fragments. Parameters that have been reported to be important for explaining the degree of runoff or soil loss from soils containing rock fragments include the position and size (15, geometry (18, and percentage cover (11 and 12 of rock fragments and the structure of fine earth (16. Surface rock fragment cover is a more important factor for hydroulic properties of surface flows such as flow depth, flow velocity, Manning’s roughness coefficient (n parameter and flow shear stress and geometrics properties of formed rill such as time, location, number, length, width and depth of rill. Surface rock fragment cover is directly affected soil erosion processes in dry area specially in areas that plant can not grow because of sever dryness and salinity. Also, Surface rock fragment prevent the contact of rain drops to aggregates, decreasing physical degradation by decreasing flow velocity. The objective of this study was to investigate the effect of different surface rock fragment cover on hydraulic properties of surface flows and geometrics properties of formed rill. Materials and Methods: For this purpose, 36 field plots of 20 meter length and 0.5 meter width with 3% slope were established in research field of agricultural faculty, Shahrekord University. Before each erosion event, topsoil was tilled

  10. Assessing climate change impacts on runoff from karstic watersheds: NASA/GISS land-surface model improvement

    Science.gov (United States)

    Blake, Reginald Alexander

    The off-line version of the Goddard Institute for Space Studies (GISS) land-surface hydrological model over- predicted run-off from the karstic Rio Cobre watershed in Jamaica. To assess possible climate change impacts on runoff from the watershed, the model's simulation of observed runoff was improved by adding to it a karst component that has pipe flow features. The improved model was tested on two other karstic watersheds (Yangtze - China and Rio Grande - USA) and the results were encouraging. The impacts that possible climate change may have on the three karstic watersheds were then assessed. The assessment indicates that in a doubled carbon dioxide climate, the Rio Cobre and the Rio Grande may experience decreases in runoff, especially in low flow periods. The Yangtze, on the other hand, may not experience decreases in total runoff, but its peak flow which now occurs in July may be attenuated and shifted to September. The results of the study also show that climate feedbacks convolute climate change assessments and that different results can be obtained from the same climate change scenario depending on the choice of the modeling methodology-that is, on whether the models are coupled or uncoupled.

  11. Broiler Litter × Industrial By-Products Reduce Nutrients and Microbial Losses in Surface Runoff When Applied to Forages.

    Science.gov (United States)

    Adeli, Ardeshir; Read, John J; Brooks, John P; Miles, Dana; Feng, Gary; Jenkins, Johnie N

    2017-03-01

    The inability to incorporate broiler litter (BL) into permanent hayfields and pastures leads to nutrient accumulation near the soil surface and increases the potential transport of nutrients in runoff. This study was conducted on Marietta silt loam soil to determine the effect of flue gas desulfurization (FGD) gypsum and lignite on P, N, C, and microbial concentrations in runoff. Treatments were (i) control (unfertilized) and (ii) BL at 13.4 Mg ha alone or (iii) treated with either FGD gypsum or lignite applied at 20% (w/w) (2.68 Mg ha). Rainfall simulators were used to produce a 5.6 cm h storm event sufficient in duration to cause 15 min of continuous runoff. Repeated rains were applied at 3-d intervals to determine how long FGD gypsum and lignite are effective in reducing loss of litter-derived N, P, and C from soil. Application of BL increased N, P, and C concentrations in runoff as compared to the control. Addition of FGD gypsum reduced ( 20%. Thus, BL treated with FGD and lignite can be considered as cost-effective management practices in the mitigation of P, N, and C and possibly microbial concentration in runoff. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  12. Sustainable Stormwater Management: Examining the Role of Local Planning Capacity in Mitigating Peak Surface Runoff

    Directory of Open Access Journals (Sweden)

    Hyun Woo Kim

    2016-08-01

    Full Text Available The Chesapeake Bay, the largest estuary in the United States, is rich in natural resources. Its watershed has been impacted by excessive and degraded stormwater runoff from rapid urbanization. We used an empirical approach to investigate how local planning capacity in the Chesapeake Bay watershed affected stream flow. A multiple regression analysis was employed to examine to what extent that the planning factors and other contextual variables were associated with peak runoff. Counterintuitively, we found that sub-basins included in the sample jurisdictions with a relatively high plan quality score tend to generate higher volumes of peak runoff. Results further indicate that specific geographical, basin characteristic, and biophysical factors affected mean annual peak runoff significantly. Overall, our findings highlight the importance of local planning capacity and sustainable stormwater management concepts in mitigating excessive runoff.

  13. Modelling surface runoff and water fluxes over contrasted soils in pastoral Sahel: evaluation of the ALMIP2 land surface models over the Gourma region in Mali

    Science.gov (United States)

    Land surface processes play an important role in West African monsoon variability and land –atmosphere coupling has been shown to be particularly important in the Sahel. In addition, the evolution of hydrological systems in this region, and particularly the increase of surface water and runoff coeff...

  14. Soil aggregate stability and size-selective sediment transport with surface runoff as affected by organic residue amendment.

    Science.gov (United States)

    Shi, Pu; Arter, Christian; Liu, Xingyu; Keller, Martin; Schulin, Rainer

    2017-12-31

    Aggregate breakdown influences the availability of soil particles for size-selective sediment transport with surface runoff during erosive rainfall events. Organic matter management is known to affect aggregate stability against breakdown, but little is known about how this translates into rainfall-induced aggregate fragmentation and sediment transport under field conditions. In this study, we performed field experiments in which artificial rainfall was applied after pre-wetting on three pairs of arable soil plots (1.5×0.75m) six weeks after incorporating a mixture of grass and wheat straw into the topsoil of one plot in each pair (OI treatment) but not on the other plot (NI treatment). Artificial rainfall was applied for approximately 2h on each pair at an intensity of 49.1mmh -1 . In both treatments, discharge and sediment concentration in the discharge were correlated and followed a similar temporal pattern after the onset of surface runoff: After a sharp increase at the beginning both approached a steady state. But the onset of runoff was more delayed on the OI plots, and the discharge and sediment concentration were in average only roughly half as high on the OI as on the NI plots. With increasing discharge the fraction of coarse sediment increased. This relationship did not differ between the two treatments. Thus, due to the lower discharge, the fraction of fine particles in the exported sediment was larger in the runoff from the OI plots than from the NI plots. The later runoff onset and lower discharge rate was related to a higher initial aggregate stability on the OI plots. Terrestrial laser scanning proved to be a very valuable method to map changes in the micro-topography of the soil surfaces. It revealed a much less profound decrease in surface roughness on the OI than on the NI plots. Copyright © 2017 Elsevier B.V. All rights reserved.

  15. The effect of leaf litter cover on surface runoff and soil erosion in Northern China.

    Science.gov (United States)

    Li, Xiang; Niu, Jianzhi; Xie, Baoyuan

    2014-01-01

    The role of leaf litter in hydrological processes and soil erosion of forest ecosystems is poorly understood. A field experiment was conducted under simulated rainfall in runoff plots with a slope of 10%. Two common types of litter in North China (from Quercus variabilis, representing broadleaf litter, and Pinus tabulaeformis, representing needle leaf litter), four amounts of litter, and five rainfall intensities were tested. Results revealed that the litter reduced runoff and delayed the beginning of runoff, but significantly reduced soil loss (psoil plot, and for Q. variabilis and P. tabulaeformis, respectively, and average sediment yield was 85.1% and 79.9% lower. Rainfall intensity significantly affected runoff (R = 0.99, psoil erosion control, since no significant differences (p≤0.05) were observed in runoff and sediment variables between two litter-covered plots. In contrast, litter mass was probably not a main factor in determining runoff and sediment because a significant correlation was found only with sediment in Q. variabilis litter plot. Finally, runoff yield was significantly correlated (perosion processes was crucial, and both rainfall intensity and litter characteristics had an impact on these processes.

  16. Prediction of hydrological reduction factor and initial loss in urban surface runoff from small ungauged catchments

    DEFF Research Database (Denmark)

    Arnbjerg-Nielsen, K.; Harremoës, P.

    1996-01-01

    An advanced runoff model is compared to a simple one employing only a runoff coefficient and a regression parameter allowing for initial loss. The present study shows that the more detailed description of the runoff processes cannot be justified due to the uncertainty from using only one gauge...... in a catchment for the description of the rain input. A significant variation of the two parameters from one catchment to another has been found and the uncertainty of the two variables are evaluated. The uncertainty of the hydrological reduction factor and the initial loss should be taken into account...

  17. Recharging infiltration of precipitation water through the light soil, in the absence of surface runoff

    Directory of Open Access Journals (Sweden)

    Czyżyk Franciszek

    2017-03-01

    Full Text Available The article presents the value of recharging infiltration of precipitation through the light soil and its distribution over time, based on five-year of lysimetric research. The effect of organic and mineral fertilization on the infiltration was studied. In lysimeters does not occur the phenomenon of surface runoff, and thus, by analogy, the results of the research can be applied to agriculturally used lowland areas with sandy soils. The results showed that the infiltration is very changeable in time. On its value, in addition to precipitation, the greatest influence has evapotranspiration. The largest infiltration occurs in March after the spring thaws (IE = 70-81% monthly precipitation and the smallest in August (IE = 1.2-15.0% precipitation, depending on the type of fertilizer used and the level of fertilization. The soil fertilization, especially by using organic fertilizer (compost, is a factor, which has significantly influence on reduction of the recharging infiltration. The soil fertilization with compost reduced the infiltration of 7.4-9.0%, and with mineral fertilization of 5.4-7.0% of annual precipitation totals, compared with the infiltration through the soil not fertilized. The average annual index of infiltration was 21.8-25.3% of annual precipitation totals in variant of soil fertilized and 30.7% in case of the soil not fertilized.

  18. Surface Runoff Threshold Responses to Rainfall Intensity, Scale, and Land Use Type, Change and Disturbance

    Science.gov (United States)

    Bhaskar, A.; Kampf, S. K.; Green, T. R.; Wilson, C.; Wagenbrenner, J.; Erksine, R. H.

    2017-12-01

    The dominance of infiltration-excess (Hortonian) overland flow can be determined by how well a rainfall intensity threshold predicts streamflow response. Areas in which we would expect infiltration-excess overland flow to dominate include urban, bedrock, desert pavement, and lands disturbed by vegetation removal (e.g., after a fire burn or fallow agricultural lands). Using a transferable method of identifying the existence of thresholds, we compare the following sites to investigate their hydrologic responses to 60-minute rainfall intensities: desert pavement sites in Arizona (Walnut Gulch and Yuma Proving Ground), post-fire sites in a forested, mountainous burn area in north-central Colorado (High Park Fire), an area of northeastern Colorado Plains that has transitioned from dryland agriculture to conservation reserve (Drake Farm), and watersheds in suburban Baltimore, Maryland which range from less than 5% to over 50% impervious surface cover. We observed that at desert sites, the necessary threshold of rainfall intensity to produce flow increased with watershed size. In burned watersheds, watershed size did not have a clear effect on rainfall thresholds, but thresholds increased with time after burning, with streamflow no longer exhibiting clear threshold responses after the third year post-fire. At the agricultural site, the frequency of runoff events decreased during the transition from cultivated crops to mixed perennial native grasses. In an area where the natural land cover (forested) would be not dominated by infiltration-excess overland flow, urbanization greatly lowered the rainfall thresholds needed for hydrologic response. This work contributes to building a predictive framework for identifying what naturally-occurring landscapes are dominated by infiltration-excess overland flow, and how land use change could shift the dominance of infiltration-excess overland flow. Characterizing the driving mechanism for streamflow generation will allow better

  19. Modeling detailed hydro-meteorological surfaces and runoff response in large diverse watersheds

    International Nuclear Information System (INIS)

    Byrne, J.; Kienzle, S.W.; MacDonald, R.J.

    2008-01-01

    An understanding of local variability in climatic conditions over complex terrain is imperative to making accurate assessments of impacts from climate change on fresh water ecosystems (Daly, 2006). The derivation of representative spatial data in diverse environments poses a significant challenge to the modelling community. This presentation describes the current status of a long term ongoing hydro-climate model development program. We are developing a gridded hydroclimate dataset for diverse watersheds using SimGrid (Larson, 2008; Lapp et al., 2005; Sheppard, 1996), a model that applies the Mountain Climate Model (MTCLIM; Hungerford et al., 1989) to simulate hydro-climatic conditions over diverse terrain. The model uses GIS based terrain categories (TC) classified by slope, aspect, elevation, and soil water storage. SimGrid provides daily estimates of solar radiation, air temperature, relative humidity, precipitation, snowpack and soil water storage over space. Earlier versions of the model have been applied in the St. Mary (Larson, 2008) and upper Oldman basins (Lapp et al., 2005), giving realistic estimates of hydro-climatic variables. The current study demonstrates improvements to the estimation of temperature, precipitation, snowpack, soil water storage and runoff from the basin. Soil water storage data for the upper drainage were derived with GIS and included in SimGrid to estimate soil water flux over the time period. These changes help improve the estimation of spatial climatic variability over the basin while accounting for topographical influence. In further work we will apply spatial hydro-climatic surfaces from the SimGrid model to assess the hydrologic response to environmental change for watersheds in Canada and beyond. (author)

  20. Sensitivity Analysis of the Surface Runoff Coefficient of HiPIMS in Simulating Flood Processes in a Large Basin

    Directory of Open Access Journals (Sweden)

    Yueling Wang

    2018-03-01

    Full Text Available To simulate flood processes at the basin level, the GPU-based High-Performance Integrated Hydrodynamic Modelling System (HiPIMS is gaining interest as computational capability increases. However, the difficulty of coping with rainfall input to HiPIMS reduces the possibility of acquiring a satisfactory simulation accuracy. The objective of this study is to test the sensitivity of the surface runoff coefficient in the HiPIMS source term in the Misai basin with an area of 797 km2 in south China. To achieve this, the basin was divided into 909,824 grid cells, to each of which a Manning coefficient was assigned based on its land use type interpreted from remote sensing data. A sensitivity analysis was conducted for three typical flood processes under four types of surface runoff coefficients, assumed a priori, upon three error functions. The results demonstrate the crucial role of the surface runoff coefficient in achieving better simulation accuracy and reveal that this coefficient varies with flood scale and is unevenly distributed over the basin.

  1. Efficiency assessment of runoff harvesting techniques using a 3D coupled surface-subsurface hydrological model

    International Nuclear Information System (INIS)

    Verbist, K.; Cronelis, W. M.; McLaren, R.; Gabriels, D.; Soto, G.

    2009-01-01

    In arid and semi-arid zones runoff harvesting techniques are often applied to increase the water retention and infiltration on steep slopes. Additionally, they act as an erosion control measure to reduce land degradation hazards. Both in literature and in the field, a large variety of runoff collecting systems are found, as well as large variations in design and dimensions. Therefore, detailed measurements were performed on a semi-arid slope in central Chile to allow identification of the effect of a simple water harvesting technique on soil water availability. For this purpose, twenty two TDR-probes were installed and were monitored continuously during and after a simulated rainfall event. These data were used to calibrate the 3D distributed flow model HydroGeoSphere, to assess the runoff components and soil water retention as influenced by the water harvesting technique, both under simulated and natural rainfall conditions. (Author) 6 refs.

  2. Identification of soil P fractions that are associated with P loss from surface runoff under various cropping systems and fertilizer rates on sloped farmland.

    Directory of Open Access Journals (Sweden)

    Xinghua Li

    Full Text Available Soil phosphorus (P fractions and runoff P concentration were measured to understand the fate of soil P entering surface runoff water during summer cropping season of different double cropping systems under two fertilizer regimes. The dominant form of runoff P was particulate P (PP. Runoff total P (TP was higher at the vegetative growth stage and lower at the crop reproductive stage. TP and PP were derived mainly from soil Olsen-P, Al-P and Fe-P and amounts increased with sediment content in runoff water. Runoff P discharge was closely related to the changes in soil P forms. Soil Olsen-P, mainly consisting of some Ca2-P and Al-P, was increased by elevating fertilizer rate. Along with crop growth, there were active interconversions among Olsen-P, Org-P, Fe-P and O-Al-P in the soil, and some available P converted into Ca10-P, with O-Fe-P possibly being a transitional form for this conversion. The oilseed rape/corn system had less runoff TP at the early stage, and wheat/sweet potato system had a lower runoff P at the late stage. Intercropping corn with sweet potato in the field with oilseed rape as a previous crop may be helpful for alleviating runoff P load during the summer in this region.

  3. Identification of soil P fractions that are associated with P loss from surface runoff under various cropping systems and fertilizer rates on sloped farmland

    Science.gov (United States)

    Li, Xinghua; Wang, Baona; Yang, Tewu; Zhu, Duanwei; Nie, Zhongnan; Xu, Junchi

    2017-01-01

    Soil phosphorus (P) fractions and runoff P concentration were measured to understand the fate of soil P entering surface runoff water during summer cropping season of different double cropping systems under two fertilizer regimes. The dominant form of runoff P was particulate P (PP). Runoff total P (TP) was higher at the vegetative growth stage and lower at the crop reproductive stage. TP and PP were derived mainly from soil Olsen-P, Al-P and Fe-P and amounts increased with sediment content in runoff water. Runoff P discharge was closely related to the changes in soil P forms. Soil Olsen-P, mainly consisting of some Ca2-P and Al-P, was increased by elevating fertilizer rate. Along with crop growth, there were active interconversions among Olsen-P, Org-P, Fe-P and O-Al-P in the soil, and some available P converted into Ca10-P, with O-Fe-P possibly being a transitional form for this conversion. The oilseed rape/corn system had less runoff TP at the early stage, and wheat/sweet potato system had a lower runoff P at the late stage. Intercropping corn with sweet potato in the field with oilseed rape as a previous crop may be helpful for alleviating runoff P load during the summer in this region. PMID:28650990

  4. Method for surface treatment by electron beams

    International Nuclear Information System (INIS)

    Panzer, S.; Doehler, H.; Bartel, R.; Ardenne, T. von.

    1985-01-01

    The invention has been aimed at simplifying the technology and saving energy in modifying surfaces with the aid of electron beams. The described beam-object geometry allows to abandon additional heat treatments. It can be used for surface hardening

  5. Comparison of Surface Runoff Generation, and Soil and Nutrient Loss in Kakhk Treated and Representative Watersheds, Khorasan Razavi Province

    Directory of Open Access Journals (Sweden)

    Davood Davoodi Moghadam

    2017-02-01

    Full Text Available Introduction: It is vital to control land degradation, for conserving precious natural treasures. Quantification of runoff production and soil and nutrient loss from wild lands under different managerial systems is one of the scientific and optimal management in agriculture and natural resources, as a major component of sustainable development. Many researches have been conducted to assess the effects of different land uses on soil erosion and runoff generation throughout the globe. Most of which, mainly verified the detrimental effects of human intervention on land degradation. However, limited comprehensive and comparative studies have been conducted to consider the amount of surface runoff generation, and soil and nutrient loss from watersheds with different management patterns viz. untreated and treated small watersheds. Materials and Methods: The present study aimed to compare surface runoff generation,soil and nutrient loss in Kakhk treated and untreated watersheds with an area ca. 222 ha and precipitation of some 243 mm per annum. Other physical and geological characteristics of the paired watersheds were also similar to allow assessing the effects of study measures on soil, water and nutrient losses. The area under consideration has been located in Khorasan Razavi Province in northeastern Iran. The present study was performed in plots with standard size of 22.1 × 1.8 m in treating and representative areas, with three replicates and on the storm basis occurred during early 2011 and mid-2014. The treated plots were covered by biological measures viz. seeding, bunching and exclusre. The study plots have been situated on eastern,western and northern aspects with respective slope of 55, 40 and 40 %. The entire runoff from study plots were collected in a container in 0.5×1×1 m. The sediment concentration was also measured in 2-liter samples taken from the container after a complete mixing of the entire collected runoff. The sample was

  6. Quantification of turfgrass buffer performance in reducing transport of pesticides in surface runoff

    Science.gov (United States)

    Pesticides are used to control pests in managed biological system such as agricultural crops and golf course turf. Off-site transport of pesticides with runoff and their potential to adversely affect non-target aquatic organisms has inspired the evaluation of management practices to minimize pestic...

  7. Upscaling Surface and Subsurface Runoff Process Using a Travel Time Matching Strategy: Application to the Ohio River Basin

    Science.gov (United States)

    Zhao, Y.; Beighley, E.

    2017-12-01

    While hydrologic understanding gained from model assessment and sensitivity analyses continues to grow, computational efficiency is still a challenge for the hydrologic and hydraulic modeling community, especially at continental and global scales. This research presents a runoff flowpath travel-time matching method to upscale hydrologic response characteristics of surface and subsurface runoff from fine to coarse model resolutions. Five model resolutions are investigated in this study: 10, 32, 100, 320, 1000 km2, where model resolution represents the threshold areas used to define the underlying river network and catchment boundaries. Here, the 1 km2 mode resolution is set as the reference model. A case study in the Ohio River Basin (roughly 500,000 km2) is presented using a synthetic SCS 2-year flood event. The velocities of surface and subsurface runoff from Hillslope River Routing (HRR) model operating at 1 km2 resolution is determined on a high-performance computing cluster. Using these simulated velocities and 90-m Digital Elevation Model (DEM), pixel level velocities are determined separately for hillslopes (surface and subsurface) and channels. Cumulative Probability Distributions (CDFs) for surface and subsurface travel times based on the gridded 90-m velocities and conceptualized model units representing individual catchments in the HRR model are matched by adjusting surface roughness and subsurface hydraulic conductivity along HRR hillslopes in the courser model resolutions. The beta distribution is applied to approximate the CDF travel time to reduce pixel-level processing time for large model units. Simulated hydrographs at the outlet of the Ohio River Basin for the five coarser model resolutions are shown to have nearly identical peak discharge and time-to-peak discharge values as compared to the reference model. The proposed upscaling method can reduce the computation time by transferring the hydrologic characteristics captured at fine scales to

  8. Secondary electron emission from textured surfaces

    Science.gov (United States)

    Huerta, C. E.; Patino, M. I.; Wirz, R. E.

    2018-04-01

    In this work, a Monte Carlo model is used to investigate electron induced secondary electron emission for varying effects of complex surfaces by using simple geometric constructs. Geometries used in the model include: vertical fibers for velvet-like surfaces, tapered pillars for carpet-like surfaces, and a cage-like configuration of interlaced horizontal and vertical fibers for nano-structured fuzz. The model accurately captures the secondary electron emission yield dependence on incidence angle. The model shows that unlike other structured surfaces previously studied, tungsten fuzz exhibits secondary electron emission yield that is independent of primary electron incidence angle, due to the prevalence of horizontally-oriented fibers in the fuzz geometry. This is confirmed with new data presented herein of the secondary electron emission yield of tungsten fuzz at incidence angles from 0-60°.

  9. Surfaces and interfaces of electronic materials

    CERN Document Server

    Brillson, Leonard J

    2012-01-01

    An advanced level textbook covering geometric, chemical, and electronic structure of electronic materials, and their applications to devices based on semiconductor surfaces, metal-semiconductor interfaces, and semiconductor heterojunctions. Starting with the fundamentals of electrical measurements on semiconductor interfaces, it then describes the importance of controlling macroscopic electrical properties by atomic-scale techniques. Subsequent chapters present the wide range of surface and interface techniques available to characterize electronic, optical, chemical, and structural propertie

  10. The study of contamination of discharged runoff from surface water disposal channels of Bushehr city in 2012-2013

    Directory of Open Access Journals (Sweden)

    Vaheid Noroozi-Karbasdehi

    2016-09-01

    Full Text Available Background: In coastal cities, wastewater discharge into the sea is one of the options for sewage disposal that in case of non-compliance with health standards  in wastewater disposal will be led to the spread of infection and disease. On the other hand, water resources preservation and using them efficiently are the principles of sustainable development of each country. This study was aimed to investigate the contamination of discharged runoff from the surface water disposal channels of Bushehr city in 2012 - 13. Materials and Methods: In this study, Sampling was conducted by composite sampling method from output of the five main surface water disposal channels leading to the Persian Gulf located in the coastal region of Bushehr city during two seasons including wet (winter and dry (summer in 2012- 13. Then, experimental tests of BOD5, total coliform and fecal coliform were done on any of the 96 samples according to the standard method. Results: Analysis of the data showed that the BOD5, total coliform and fecal coliform of effluent runoff of the channels were more than the national standard output of disposal wastewaters into the surface waters, and the highest and lowest amount of BOD5 which obtained were 160 mg/L and 28 mg/L, respectively. Conclusion: considering the fact that discharged runoff from surface water disposal channels link from shoreline to sea in close distance and they often are as natural swimming sites and even fishing sites of Bushehr city, and also according to high level of organic and bacterial load of these channels, it is urgently required to be considered by the authorities.

  11. Numerical simulation and experimental study on farmland nitrogen loss to surface runoff in a raindrop driven process

    Science.gov (United States)

    Li, Jiayun; Tong, Juxiu; Xia, Chuanan; Hu, Bill X.; Zhu, Hao; Yang, Rui; Wei, Wenshuo

    2017-06-01

    It has been widely recognized that surface runoff from agricultural field is an important non-point pollution source, which however, the chemical transfer amount in the process is very difficult to be quantified in field since some variables and natural factors are hard to control, such as rainfall intensity, temperature, wind speeds and soil spatial heterogeneity, which may significantly affect the field experimental results. Therefore, a physically based nitrogen transport model was developed and tested with the so called semi-field experiments (i.e., artificial rainfall was used instead of natural rainfall, but other conditions were natural) in this paper. Our model integrated the raindrop driven process and diffusion effect with the simplified nitrogen chain reactions. In this model, chemicals in the soil surface layer, or the 'exchange layer', were transformed into the surface runoff layer due to raindrop impact. The raindrops also have a significant role on the diffusion process between the exchange layer and the underlying soil. The established mathematical model was solved numerically through the modified Hydrus-1d source code, and the model simulations agreed well with the experimental data. The modeling results indicate that the depth of the exchange layer and raindrop induced water transfer rate are two important parameters for the simulation results. Variation of the water transfer rate, er, can strongly influence the peak values of the NO-3-N and NH+4-N concentration breakthrough curves. The concentration of NO-3-N is more sensitive to the exchange layer depth, de, than NH+4-N. In general, the developed model well describes the nitrogen loss into surface runoff in a raindrop driven process. Since the raindrop splash erosion process may aggravate the loss of chemical fertilizer, choosing an appropriate fertilization time and application method is very important to prevent the pollution.

  12. An approximate analytical solution for describing surface runoff and sediment transport over hillslope

    Science.gov (United States)

    Tao, Wanghai; Wang, Quanjiu; Lin, Henry

    2018-03-01

    Soil and water loss from farmland causes land degradation and water pollution, thus continued efforts are needed to establish mathematical model for quantitative analysis of relevant processes and mechanisms. In this study, an approximate analytical solution has been developed for overland flow model and sediment transport model, offering a simple and effective means to predict overland flow and erosion under natural rainfall conditions. In the overland flow model, the flow regime was considered to be transitional with the value of parameter β (in the kinematic wave model) approximately two. The change rate of unit discharge with distance was assumed to be constant and equal to the runoff rate at the outlet of the plane. The excess rainfall was considered to be constant under uniform rainfall conditions. The overland flow model developed can be further applied to natural rainfall conditions by treating excess rainfall intensity as constant over a small time interval. For the sediment model, the recommended values of the runoff erosion calibration constant (cr) and the splash erosion calibration constant (cf) have been given in this study so that it is easier to use the model. These recommended values are 0.15 and 0.12, respectively. Comparisons with observed results were carried out to validate the proposed analytical solution. The results showed that the approximate analytical solution developed in this paper closely matches the observed data, thus providing an alternative method of predicting runoff generation and sediment yield, and offering a more convenient method of analyzing the quantitative relationships between variables. Furthermore, the model developed in this study can be used as a theoretical basis for developing runoff and erosion control methods.

  13. Potential Groundwater Recharge from the Infiltration of Surface Runoff in Cold and Dry Creeks, Phase 2

    International Nuclear Information System (INIS)

    Waichler, Scott R.

    2005-01-01

    Runoff from Cold and Dry Creeks may provide an important source of groundwater recharge on the Hanford Site. This report presents estimates of total volume and distribution of such recharge from extreme precipitation events. Estimates were derived using a simple approach that combined the Soil Conservation Service curve number runoff method and an exponential-decay channel infiltration model. Fifteen-minute streamflow data from four gaging stations, and hourly precipitation data from one climate station, were used to compute curve numbers and calibrate the infiltration model. All data were from several storms occurring during January 1995. Design storm precipitation depths ranging from 1.6 to 2.7 inches were applied with computed curve numbers to produce total runoff/recharge of 7,700 to 15,900 ac-ft, or approximately 10 times the average annual rate from this recharge source as determined in a previous study. Approximately two-thirds of the simulated recharge occurred in the lower stream reaches contained in the broad alluvial valley that parallels State Highway 240 near the Hanford 200 Area

  14. Potential Groundwater Recharge from the Infiltration of Surface Runoff in Cold and Dry Creeks, Phase 2

    Energy Technology Data Exchange (ETDEWEB)

    Waichler, Scott R.

    2005-12-13

    Runoff from Cold and Dry Creeks may provide an important source of groundwater recharge on the Hanford Site. This report presents estimates of total volume and distribution of such recharge from extreme precipitation events. Estimates were derived using a simple approach that combined the Soil Conservation Service curve number runoff method and an exponential-decay channel infiltration model. Fifteen-minute streamflow data from four gaging stations, and hourly precipitation data from one climate station, were used to compute curve numbers and calibrate the infiltration model. All data were from several storms occurring during January 1995. Design storm precipitation depths ranging from 1.6 to 2.7 inches were applied with computed curve numbers to produce total runoff/recharge of 7,700 to 15,900 ac-ft, or approximately 10 times the average annual rate from this recharge source as determined in a previous study. Approximately two-thirds of the simulated recharge occurred in the lower stream reaches contained in the broad alluvial valley that parallels State Highway 240 near the Hanford 200 Area.

  15. Electron spectroscopy of nanodiamond surface states

    Energy Technology Data Exchange (ETDEWEB)

    Belobrov, P.I.; Bursill, L.A.; Maslakov, K.I.; Dementjev, A.P

    2003-06-15

    Electronic states of nanodiamond (ND) were investigated by PEELS, XPS and CKVV Auger spectra. Parallel electron energy loss spectra (PEELS) show that the electrons inside of ND particles are sp{sup 3} hybridized but there is a surface layer containing distinct hybridized states. The CKVV Auger spectra imply that the HOMO of the ND surface has a shift of 2.5 eV from natural diamond levels of {sigma}{sub p} up to the Fermi level. Hydrogen (H) treatment of natural diamond surface produces a chemical state indistinguishable from that of ND surfaces using CKVV. The ND electronic structure forms {sigma}{sub s}{sup 1}{sigma}{sub p}{sup 2}{pi}{sup 1} surface states without overlapping of {pi}-levels. Surface electronic states, including surface plasmons, as well as phonon-related electronic states of the ND surface are also interesting and may also be important for field emission mechanisms from the nanostructured diamond surface.

  16. Available content, surface runoff and leaching of phosphorus forms in a typic hapludalf treated with organic and mineral nutrient sources

    Directory of Open Access Journals (Sweden)

    Cledimar Rogério Lourenzi

    2014-04-01

    Full Text Available The application of animal manure to soil can increase phosphorus availability to plants and enhance transfer of the nutrient solution drained from the soil surface or leached into the soil profile. The aim of this study was to evaluate the effect of successive applications of organic and mineral nutrient sources on the available content, surface runoff and leaching of P forms in a Typic Hapludalf in no-tillage systems. Experiment 1 was set up in 2004 in the experimental area of UFSM, in Santa Maria (RS, Brazil. The treatments consisted of: control (without nutrient application and application of pig slurry (PS, pig deep-litter (PL, cattle slurry (CS, and mineral fertilizers (NPK. The rates were determined to meet the N crop requirements of no-tillage black oat and maize, grown in the 2010/2011 growing season. The soil solution was collected after each event (rain + runoff or leaching and the soluble, particulate and total P contents were measured. In November 2008, soil was collected in 2 cm intervals to a depth of 20 cm, in 5 cm intervals to a depth of 40 cm, and in 10 cm intervals to a depth of 70 cm. The soil was dried and ground, and P determined after extraction by anion exchange resin (AER. In experiment 2, samples collected from the Typic Hapludalf near experiment 1 were incubated for 20, 35, 58, 73 and 123 days after applying the following treatments: soil, soil + PS, soil + PL, soil + CS and soil + NPK. Thereafter, the soil was sampled and P was analyzed by AER. The applications of nutrient sources over the years led to an increase in available P and its migration in the soil profile. This led to P transfer via surface runoff and leaching, with the largest transfer being observed in PS and PL treatments, in which most P was applied. The soil available P and P transfer via surface runoff were correlated with the amounts applied, regardless of the P source. However, P transfer by leaching was not correlated with the applied nutrient

  17. Simulation of torrential rain as a means for assessment of surface runoff coefficients and calculation of recurrent design events in alpine catchments

    Science.gov (United States)

    Markart, Gerhard; Kohl, Bernhard; Sotier, Bernadette; Klebinder, Klaus; Schauer, Thomas; Bunza, Günther

    2010-05-01

    Simulation of heavy rain is an established method for studying infiltration characteristics, runoff and erosion behaviour in alpine catchments. Accordingly for characterization and differentiation of various runoff producing areas in alpine catchments transportable spray irrigation installations for large plots have been developed at the BFW, Department of Natural Hazards and Alpine Timberline, in Innsbruck, Austria. One installation has been designed for assessment of surface runoff coefficients under convective torrential rain with applicable precipitation intensities between 30 and 120 mm*h-1 and a plot size between 50 and 100 m2. The second device is used for simulation of persistent rain events (rain intensity about 10 mm*h-1, plot size: 400-1200 m2). Very reasonable results have been achieved during the comparison with spray irrigations from other institutions (e.g. Bavarian Environmental Agency in Munich) in the field. Rain simulations at BFW are mostly combined with comprehensive additional investigations on land-use, vegetation cover, soil physical characteristics, soil humidity, hydrogeology and other features of the test-sites. This allows proper interpretation of the achieved runoff data. At the moment results from more than 280 rain simulations are available from about 25 catchments / regions of the Eastern Alps at the BFW. Results show that the surface runoff coefficient, when runoff is constant at the test site (φconst) increases only slightly between rain intensities from 30 to 120 mm*h-1 (increment is 6%). Therefore φconst shall be used for assessment of runoff behaviour of runoff contributing areas, because it is less dependent form system conditions than φtot. BFW-data have been consolidated with results of the LfU (Bavarian Environmental Agency in Munich) in a data base and formed the basis for the development of a simple code of practice for assessment of surface runoff coefficients in torrential rain. The manual is freely available under

  18. USE OF MICRO-DAMS IN POTATO FURROWS TO REDUCE EROSION AND RUNOFF AND MINIMISE SURFACE WATER CONTAMINATION THROUGH PESTICIDES.

    Science.gov (United States)

    Olivier, C; Goffart, J P; Baets, D; Xanthoulis, D; Fonder, N; Lognay, G; Barthélemy, J P; Lebrun, P

    2014-01-01

    The use of micro-dams in potato furrows is an interesting technology to reduce erosion and runoff in hilly areas. These phenomena are major sources of surface water contamination by nutrients and plant protection products (Gillijns et al., 2005). In 2011 Bayer CropScience set up a trial in collaboration with the Walloon Agricultural Research Centre (CRA-W) and ULg-Gembloux Agro-Bio Tech in Huldenberg (Belgium) to demonstrate this technique in potatoes. Micro-dams create barriers between furrows in order to encourage rainwater to infiltrate in the soil rather than to run off. The results from the trial over this year confirm that the application of micro-dams is effective in reducing erosion and runoff significantly. The total loss of plant protection products (PPP) to surface water is dramatically reduced and also strongly depends on the physic-chemical characteristics of the active ingredients. In addition, the technique tends to produce a higher yield of potato tubers as an effect of an optimised utilisation of the available rainwater and nutrients.

  19. Oxides Surfaces and Novel Electronic Properties

    Science.gov (United States)

    Koirala, Pratik

    The scope of this thesis extends to the study of surface structures and electronic properties in a number of complex oxides. The c(6x2) surface reconstruction on SrTiO3 (001) was solved using a combination of plan view transmission electron microscopy imaging, atomic resolution secondary electron imaging, and density functional theory calculations. This work provided fundamental insights on the effects of dielectric screening in secondary electron generation. A thorough analysis on the limitation and functionality of transmission plan view imaging showed that the kinematical approximations used in the separation of top and bottom surfaces is only valid in thin samples (˜5 nm or less for SrTiO3). The presence of an inversion center in the surface structure also made separation of the top and bottom surfaces more robust. Surface studies of two other oxides, KTaO3 and NdGaO3, provided understanding on the mechanism of surface heterogeneity and segregation. In the case of KTaO3, selective ion sputtering and the loss of K resulted in large stoichiometric variations at the surface. Annealing of such samples led to the formation of a potassium deficient tetragonal phase (K 6Ta10.8O30) on the surface. A similar phenomenon was also observed in NdGaO3. Exploratory surface studies of the rare earth scandates (ReScO3 , Re = Gd, Tb, Dy) led to the observation of large flexoelectric bending inside an electron microscope. Thin rods of these scandates bent by up to 90 degree under a focused electron beam; the bending was fully reversible. Ex-situ measurements of flexoelectric coe cient performed by an- other graduate student, Christopher Mizzi, confirmed that the scandates have a large flexocoupling voltage (˜42 V). Electronic structure of the lanthanide scandates was studied using temperature depen- dent X-ray photoelectron spectroscopy and hybrid density functional theory calculations. The amount of charging under X-ray illumination was greatly reduced with increasing

  20. Unoccupied surface electronic structure of Gd(0001)

    International Nuclear Information System (INIS)

    Li, D.; Dowben, P.A.; Ortega, J.E.; Himpsel, F.J.

    1994-01-01

    The unoccupied surface electronic structure of Gd(0001) was investigated with high-resolution inverse-photoemission spectroscopy. An empty surface state near E F is observed at bar Γ. Two other surface-sensitive features are also revealed at 1.2 and 3.1 eV above the Fermi level. Hydrogen adsorption on Gd surfaces was used to distinguish the surface-sensitive features from the bulk features. The unoccupied bulk-band critical points are determined to be Γ 3 + at 1.9 eV and A 1 at 0.8 eV

  1. Surface-Plasmon-Driven Hot Electron Photochemistry.

    Science.gov (United States)

    Zhang, Yuchao; He, Shuai; Guo, Wenxiao; Hu, Yue; Huang, Jiawei; Mulcahy, Justin R; Wei, Wei David

    2017-11-30

    Visible-light-driven photochemistry has continued to attract heightened interest due to its capacity to efficiently harvest solar energy and its potential to solve the global energy crisis. Plasmonic nanostructures boast broadly tunable optical properties coupled with catalytically active surfaces that offer a unique opportunity for solar photochemistry. Resonant optical excitation of surface plasmons produces energetic hot electrons that can be collected to facilitate chemical reactions. This review sums up recent theoretical and experimental approaches for understanding the underlying photophysical processes in hot electron generation and discusses various electron-transfer models on both plasmonic metal nanostructures and plasmonic metal/semiconductor heterostructures. Following that are highlights of recent examples of plasmon-driven hot electron photochemical reactions within the context of both cases. The review concludes with a discussion about the remaining challenges in the field and future opportunities for addressing the low reaction efficiencies in hot-electron-induced photochemistry.

  2. County-Level Climate Uncertainty for Risk Assessments: Volume 14 Appendix M - Historical Surface Runoff.

    Energy Technology Data Exchange (ETDEWEB)

    Backus, George A.; Lowry, Thomas Stephen; Jones, Shannon M; Walker, La Tonya Nicole; Roberts, Barry L; Malczynski, Leonard A.

    2017-06-01

    This report uses the CMIP5 series of climate model simulations to produce country- level uncertainty distributions for use in socioeconomic risk assessments of climate change impacts. It provides appropriate probability distributions, by month, for 169 countries and autonomous-areas on temperature, precipitation, maximum temperature, maximum wind speed, humidity, runoff, soil moisture and evaporation for the historical period (1976-2005), and for decadal time periods to 2100. It also provides historical and future distributions for the Arctic region on ice concentration, ice thickness, age of ice, and ice ridging in 15-degree longitude arc segments from the Arctic Circle to 80 degrees latitude, plus two polar semicircular regions from 80 to 90 degrees latitude. The uncertainty is meant to describe the lack of knowledge rather than imprecision in the physical simulation because the emphasis is on unfalsified risk and its use to determine potential socioeconomic impacts. The full report is contained in 27 volumes.

  3. County-Level Climate Uncertainty for Risk Assessments: Volume 15 Appendix N - Forecast Surface Runoff.

    Energy Technology Data Exchange (ETDEWEB)

    Backus, George A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Lowry, Thomas Stephen [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Jones, Shannon M. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Walker, La Tonya Nicole [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Roberts, Barry L. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Malczynski, Leonard A. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-05-01

    This report uses the CMIP5 series of climate model simulations to produce country- level uncertainty distributions for use in socioeconomic risk assessments of climate change impacts. It provides appropriate probability distributions, by month, for 169 countries and autonomous-areas on temperature, precipitation, maximum temperature, maximum wind speed, humidity, runoff, soil moisture and evaporation for the historical period (1976-2005), and for decadal time periods to 2100. It also provides historical and future distributions for the Arctic region on ice concentration, ice thickness, age of ice, and ice ridging in 15-degree longitude arc segments from the Arctic Circle to 80 degrees latitude, plus two polar semicircular regions from 80 to 90 degrees latitude. The uncertainty is meant to describe the lack of knowledge rather than imprecision in the physical simulation because the emphasis is on unfalsified risk and its use to determine potential socioeconomic impacts. The full report is contained in 27 volumes.

  4. Importance of moisture determination in studies of infiltration and surface runoff for long periods

    Directory of Open Access Journals (Sweden)

    Fabian Fulginiti

    2011-08-01

    Full Text Available The determination of the natural soil moisture is essential to solve problems related to irrigation water requirements, environmental considerations, and determination of surplus water. For the determination of runoff one can adopt models that consider exclusively the infiltration as a loss or one could use computational models of infiltration to model the infiltrated water. Models based on the infiltration calculation consider well the interaction between infiltration - runoff processes and provide additional information on the phenomenon of infiltration which establishes the existing conditions of moisture in the soil before the occurrence of a new event (simulation for long periods. These models require solving Richards’s equation and for this purpose it is necessary to determine the relation between the soil moisture - suction and hydraulic conductivity - suction which require the determination of the hydraulic properties that can be obtained by measuring the water content by moisture profiles. The aim of this study was the verification of these moisture curves in loessic soils in the south of the city of Cordoba, Argentina. To do this, measurements were done and compared with results of infiltration models based on the determined hydraulic functions. The measurements were done using three probes installed at different depths. The results showed that the values obtained with NETRAIN adequately represent the behavior of wetting and drying conditions of the studied soil.The determination of these curves provided a basis for future studies that include the advancement of agricultural chemicals in the soil and its potential capacity to pollute groundwater, fundamental issue to define environmental management policies.

  5. Reflection of Slow Electrons from Solid Surface

    Science.gov (United States)

    Mustafaev, Alexander; Ainov, Matsak; Kaganovich, Igor; Demidov, Vladimir

    2013-09-01

    Given that progress of future plasma technologies depends on control of electron coefficient reflection r0, the development of methods of measurement and control of r0 is of great importance. Published experimental data on r0 for slow electrons are inconsistent and sometime give large values up to r0 ~ 0 , 8 and even higher. This talk presents a technique for r0 measurements in low pressure plasmas in the presence of transverse magnetic field. It is found that for poly-crystal surface, effective reflection coefficient can really reach value of 0.8. It is demonstrated that it is connected to additional reflection from potential barrier near the surfaces. The contribution of electron reflection from the barrier and the surface has been divided and studied. The data have been confirmed at different mono-crystal surfaces. This work was supported by DoE Fusion Energy Sciences contract DE-SC0001939 and Education Ministry of the RF.

  6. Electron emission at the rail surface

    International Nuclear Information System (INIS)

    Thornhill, L.; Battech, J.

    1991-01-01

    In this paper the authors examine the processes by which current is transferred from the cathode rail to the plasma armature in an arc-driven railgun. Three electron emission mechanisms are considered, namely thermionic emission, field-enhanced thermionic emission (or Schottky emission), and photoemission. The author's calculations show that the dominant electron emission mechanism depends, to a great extent, on the work function of the rail surface, the rail surface temperature, the electric field at the rail surface, and the effective radiation temperature of the plasma. For conditions that are considered to be typical of a railgun armature, Schottky emission is the dominant electron emission mechanism, providing current densities on the order of 10 9 A/m 2

  7. Metamodeling as a tool to size vegetative filter strips for surface runoff pollution control in European watersheds.

    Science.gov (United States)

    Lauvernet, Claire; Muñoz-Carpena, Rafael; Carluer, Nadia

    2015-04-01

    In Europe, a significant presence of contaminants is found in surface water, partly due to pesticide applications. Vegetative filter strips or buffer zones (VFS), often located along rivers, are a common best management practice (BMP) to reduce non point source pollution of water by reducing surface runoff. However, they need to be adapted to the agro-ecological and climatic conditions, both in terms of position and size, in order to be efficient. The TOPPS-PROWADIS project involves European experts and stakeholders to develop and recommend BMPs to reduce pesticide transfer by drift or runoff in several European countries. In this context, IRSTEA developed a guide accompanying the use of different tools, which allows designing site-specific VFS by simulating their efficiency to limit transfers using the mechanistic model VFSMOD. This method which is very complete assumes that the user provides detailed field knowledge and data, which are not always easily available. The aim of this study is to assist the buffer sizing by using a unique tool with a reduced set of parameters, adapted to the available information from the end-users. In order to fill in the lack of real data in many practical applications, a set of virtual scenarios was selected to encompass a large range of agro-pedo-climatic conditions in Europe, considering both the upslope agricultural field and the VFS characteristics. As a first step first, in this work we present scenarios based on North-West of France climate consisting of different rainfall intensities and durations, hillslope lengths and slopes, humidity conditions, a large set of field rainfall/runoff characteristics for the contributing area, and several shallow water table depths and soil types for the VFS. The sizing method based on the mechanistic model VFSMOD was applied for all these scenarios, and a global sensitivity analysis (GSA) of the VFS optimal length was performed for all the input parameters in order to understand their

  8. Cadmium removal from urban stormwater runoff via bioretention technology and effluent risk assessment for discharge to surface water

    Science.gov (United States)

    Wang, Jianlong; Zhang, Pingping; Yang, Liqiong; Huang, Tao

    2016-02-01

    Bioretention technology, a low-impact development stormwater management measure, was evaluated for its ability to remove heavy metals (specifically cadmium, Cd) from urban stormwater runoff. Fine sand, zeolite, sand and quartz sand were selected as composite bioretention media. The effects of these materials on the removal efficiency, chemical forms, and accumulation and migration characteristics of Cd were examined in laboratory scale bioretention columns. Heretofore, few studies have examined the removal of Cd by bioretention. A five-step sequential extraction method, a single-contamination index method, and an empirical migration equation were used in the experiments. The average Cd removal efficiency of quartz sand approached 99%, and removal by the other media all exceeded 90%. The media types markedly affected the forms of Cd found in the columns as well as its vertical migration rate. The Cd accumulated in the four media was mainly in residual form; moreover, accumulation of Cd occurred mainly in the surface layer of the bioretention column. The migration depth of Cd in the four media increased with elapsed time, in the following sequence: zeolite > quartz sand > fine sand > sand. In contrast, the migration rate decreased with elapsed time, and the migration rate of Cd was lowest in sand (0.015 m per annum over the first ten years). The comprehensive risk index analysis indicated that the risk arising from Cd discharge to surface water was "intermediate", and that the degree of risk was lowest in sand, then quartz sand, zeolite, and fine sand in sequence. These results indicate that the adsorption and accumulation of Cd in the four media are more significant than the migration of Cd. In addition, the results of Cd risk assessment for the effluent indicate that each of the four media can serve as long-term adsorption material in a bioretention facility for purifying stormwater runoff.

  9. Cadmium removal from urban stormwater runoff via bioretention technology and effluent risk assessment for discharge to surface water.

    Science.gov (United States)

    Wang, Jianlong; Zhang, Pingping; Yang, Liqiong; Huang, Tao

    2016-01-01

    Bioretention technology, a low-impact development stormwater management measure, was evaluated for its ability to remove heavy metals (specifically cadmium, Cd) from urban stormwater runoff. Fine sand, zeolite, sand and quartz sand were selected as composite bioretention media. The effects of these materials on the removal efficiency, chemical forms, and accumulation and migration characteristics of Cd were examined in laboratory scale bioretention columns. Heretofore, few studies have examined the removal of Cd by bioretention. A five-step sequential extraction method, a single-contamination index method, and an empirical migration equation were used in the experiments. The average Cd removal efficiency of quartz sand approached 99%, and removal by the other media all exceeded 90%. The media types markedly affected the forms of Cd found in the columns as well as its vertical migration rate. The Cd accumulated in the four media was mainly in residual form; moreover, accumulation of Cd occurred mainly in the surface layer of the bioretention column. The migration depth of Cd in the four media increased with elapsed time, in the following sequence: zeolite>quartz sand>fine sand>sand. In contrast, the migration rate decreased with elapsed time, and the migration rate of Cd was lowest in sand (0.015 m per annum over the first ten years). The comprehensive risk index analysis indicated that the risk arising from Cd discharge to surface water was "intermediate", and that the degree of risk was lowest in sand, then quartz sand, zeolite, and fine sand in sequence. These results indicate that the adsorption and accumulation of Cd in the four media are more significant than the migration of Cd. In addition, the results of Cd risk assessment for the effluent indicate that each of the four media can serve as long-term adsorption material in a bioretention facility for purifying stormwater runoff. Copyright © 2016 Elsevier B.V. All rights reserved.

  10. Surface study of liquid 3He using surface state electrons

    International Nuclear Information System (INIS)

    Shirahama, K.; Ito, S.; Suto, H.; Kono, K.

    1995-01-01

    We have measured the mobility of surface state electrons (SSE) on liquid 3 He, μ 3 , aiming to study the elementary surface excitations of the Fermi liquid. A gradual increase of μ 3 below 300 mK is attributed to the scattering of electrons by ripplons. Ripplons do exist in 3 He down to 100 mK. We observe an abrupt decrease of μ 3 , due to the transition to the Wigner solid (WS). The dependences of the WS conductivity and mobility on temperature and magnetic field differ from the SSE behavior on liquid 4 He

  11. Estimation of surface runoff for calculating recharge in the karstic massif of Ports of Beseit (Tarragona, Spain) combining water balance in the soil and analysis of flow hydrographs

    International Nuclear Information System (INIS)

    Espinosa Martinez, S.; Custodio, E.

    2016-01-01

    For the right estimation of aquifer recharge by precipitation surface taking into account runoff is particularly relevant. Non considering it in the estimation of the groundwater resources can overestimate them. In the Baix Ebre aquifer system, in southern Catalonia, the surface and vadose zone runoff produced in the karstified carbonate formations in the Ports de Beseit massif has to be evaluated in order to achieve a better estimation of the resources transferred from this massif to the Plana de La Galera plain. Starting from the conceptual hydrogeological model, the average annual runoff is estimated. It includes the discharge from temporal perched aquifers in the Ports de Beseit massif, in the Matarraña river basin, and in the SE watershed to the Plana de La Galera plain. This is performed by analyzing the river and tributaries hydrographs, the filling and emptying hydrographs of the Ulldecona reservoir, and the soil water balance using the Visual Balan code applied to obtain the runoff in the Ulldecona reservoir watershed. The runoff has been estimated about 105±20 mm·yr−1, which represents 20–30% of average annual recharge in the Ports, estimated with soil water balance and atmospheric chloride deposition balance, about 350–500 mm·yr−1, which is mostly transferred laterally to the Plana de La Galera plain. (Author)

  12. Runoff and windblown vehicle spray from road surfaces, risks and measures for soil and water.

    NARCIS (Netherlands)

    Schipper, P.N.M.; Comans, R.N.J.; Dijkstra, J.J.; Vergouwen, L.

    2007-01-01

    Soil and surface water along roads are exposed to pollution from motorways. The main pollutants are polycyclic aromatic hydrocarbons (PAH), mineral oil, heavy metals and salt. These pollutants originate from vehicles (fuel, wires, leakage), wear and degradation of road surfaces and road furniture

  13. Computer modeling of pesticide fate at the hillslope scale. Influence of vegetated filter strips on surface runoff pesticides transfer and partitioning between surface and subsurface fluxes

    Science.gov (United States)

    Djabelkhir, K.; Carluer, N.; Lauvernet, C.

    2012-04-01

    In France, agriculture uses large quantities of fertilizer and pesticides. Water contamination by pesticides is highlighted by monitoring networks, at local and national levels. Control and reduction of contamination are major issues, for the protection of drinking water resources and aquatic ecosystems. Thus, understanding and quantifying the mechanisms involved in mobilization, transfer and dissipation of these substances can help to perform risk of water contamination diagnosis, and to estimate the effectiveness of corrective solutions. In this context, landscape elements, like buffer zones, can be an effective way to reduce diffuse contamination of pesticides carried by surface runoff. They protect the water ressources of the drift of the products applied to crops and contribute to the reduction of the transfer of pesticides in surface runoff from the plots to the river. We are interested in our study to the vegetative filter strips. The main objective of this thesis is to develop a model simulating the processes governing the transfer and dissipation of pesticides from plots to surface water, on surface and subsurface, along a slope. This will be done by taking into account the influence of vegetative filter strips between plots and rivers on the transfer, by changing the flow paths and retention time of these products via several mechanisms (infiltration, filtration of runoff -sedimentation of MES-, adsorption and degradation of products on the surface of the vegetative filter strips or infiltrated). Several models describing the mechanisms of transfer of water and solutes (sometimes) at a hillslope scale exist, in particular : POLA (Pinheiro and al., 1995), Openfluid (LISAH), J2000-JAMS (Krause and al., 2006), CatFlow (Zehe and al., 2000), tRIBS (Ivanov and al., 2004), Cathy 3D (Bixio and al., 2000) and CMF (Kraft and al., 2011). It was decided to choose a spatially distributed and object-oriented model, allowing to couple hydrological processes occuring

  14. Linking crop structure, throughfall, soil surface conditions, runoff and soil detachment: 10 land uses analyzed in Northern Laos.

    Science.gov (United States)

    Lacombe, Guillaume; Valentin, Christian; Sounyafong, Phabvilay; de Rouw, Anneke; Soulileuth, Bounsamai; Silvera, Norbert; Pierret, Alain; Sengtaheuanghoung, Oloth; Ribolzi, Olivier

    2018-03-01

    In Montane Southeast Asia, deforestation and unsuitable combinations of crops and agricultural practices degrade soils at an unprecedented rate. Typically, smallholder farmers gain income from "available" land by replacing fallow or secondary forest by perennial crops. We aimed to understand how these practices increase or reduce soil erosion. Ten land uses were monitored in Northern Laos during the 2015 monsoon, using local farmers' fields. Experiments included plots of the conventional system (food crops and fallow), and land uses corresponding to new market opportunities (e.g. commercial tree plantations). Land uses were characterized by measuring plant cover and plant mean height per vegetation layer. Recorded meteorological variables included rainfall intensity, throughfall amount, throughfall kinetic energy (TKE), and raindrop size. Runoff coefficient, soil loss, and the percentage areas of soil surface types (free aggregates and gravel; crusts; macro-faunal, vegetal and pedestal features; plant litter) were derived from observations and measurements in 1-m 2 micro-plots. Relationships between these variables were explored with multiple regression analyses. Our results indicate that TKE induces soil crusting and soil loss. By reducing rainfall infiltration, crusted area enhances runoff, which removes and transports soil particles detached by splash over non-crusted areas. TKE is lower under land uses reducing the velocity of raindrops and/or preventing an increase in their size. Optimal vegetation structures combine minimum height of the lowest layer (to reduce drop velocity at ground level) and maximum coverage (to intercept the largest amount of rainfall), as exemplified by broom grass (Thysanolaena latifolia). In contrast, high canopies with large leaves will increase TKE by enlarging raindrops, as exemplified by teak trees (Tectona grandis), unless a protective understorey exists under the trees. Policies that ban the burning of multi-layered vegetation

  15. Rough surface mitigates electron and gas emission

    International Nuclear Information System (INIS)

    Molvik, A.

    2004-01-01

    Heavy-ion beams impinging on surfaces near grazing incidence (to simulate the loss of halo ions) generate copious amounts of electrons and gas that can degrade the beam. We measured emission coefficients of η e (le) 130 and η 0 ∼ 10 4 respectively, with 1 MeV K + incident on stainless steel. Electron emission scales as η e ∝ 1/cos(θ), where θ is the ion angle of incidence relative to normal. If we were to roughen a surface by blasting it with glass beads, then ions that were near grazing incidence (90 o ) on smooth surface would strike the rims of the micro-craters at angles closer to normal incidence. This should reduce the electron emission: the factor of 10 reduction, Fig. 1(a), implies an average angle of incidence of 62 o . Gas desorption varies more slowly with θ (Fig. 1(b)) decreasing a factor of ∼2, and along with the electron emission is independent of the angle of incidence on a rough surface. In a quadrupole magnet, electrons emitted by lost primary ions are trapped near the wall by the magnetic field, but grazing incidence ions can backscatter and strike the wall a second time at an azimuth where magnetic field lines intercept the beam. Then, electrons can exist throughout the beam (see the simulations of Cohen, HIF News 1-2/04). The SRIM (TRIM) Monte Carlo code predicts that 60-70% of 1 MeV K + ions backscatter when incident at 88-89 o from normal on a smooth surface. The scattered ions are mostly within ∼10 o of the initial direction but a few scatter by up to 90 o . Ion scattering decreases rapidly away from grazing incidence, Fig. 1(c ). At 62 deg. the predicted ion backscattering (from a rough surface) is 3%, down a factor of 20 from the peak, which should significantly reduce electrons in the beam from lost halo ions. These results are published in Phys. Rev. ST - Accelerators and Beams

  16. Contact lens surface by electron beam

    International Nuclear Information System (INIS)

    Shin, Jung Hyuck; Lee, Suk Ju; Hwang, Kwang Ha; Jeon Jin

    2011-01-01

    Contact lens materials needs good biocompatibility, high refractive index, high optical transparency, high water content etc. Surface treat method by using plasma and radiation can modify the physical and/or chemical properties of the contact lens surface. Radiation technology such as electron beam irradiation can apply to polymerization reaction and enhance the functionality of the polymer.The purpose of this study is to modify of contact lens surface by using Eb irradiation technology. Electron beam was irradiated to the contact lens surface which was synthesized thermal polymerization method and commercial contact lens to modify physical and chemical properties. Ft-IR, XP, UV-vis spectrophotometer, water content, oxygen trans-metastability were used to characterize the surface state, physicochemical, and optical property of the contact lens treated with Eb. The water content and oxygen transmissibility of the contact lens treated with Eb were increased due to increase in the hydrophilic group such as O-C=O and OH group on the contact lens surface which could be produced by possible reaction between carbon and oxygen during the Eb irradiation. All of the lenses showed the high optical transmittance above 90%. In this case of B/Es, TES, Ti contact lens, the optical transmittance decreased about 5% with increasing Eb dose in the wavelength of UV-B region. The contact lens modified by Eb irradiation could improve the physical properties of the contact lens such as water content and oxygen transmissibility

  17. Electronically controllable spoof localized surface plasmons

    Science.gov (United States)

    Zhou, Yong Jin; Zhang, Chao; Yang, Liu; Xun Xiao, Qian

    2017-10-01

    Electronically controllable multipolar spoof localized surface plasmons (LSPs) are experimentally demonstrated in the microwave frequencies. It has been shown that half integer order LSPs modes exist on the corrugated ring loaded with a slit, which actually arise from the Fabry-Perot-like resonances. By mounting active components across the slit in the corrugated rings, electronic switchability and tunability of spoof LSPs modes have been accomplished. Both simulated and measured results demonstrate efficient dynamic control of the spoof LSPs. These elements may form the basis of highly integrated programmable plasmonic circuits in microwave and terahertz regimes.

  18. Electron transfer in gas surface collisions

    International Nuclear Information System (INIS)

    Wunnik, J.N.M. van.

    1983-01-01

    In this thesis electron transfer between atoms and metal surfaces in general is discussed and the negative ionization of hydrogen by scattering protons at a cesiated crystalline tungsten (110) surface in particular. Experimental results and a novel theoretical analysis are presented. In Chapter I a theoretical overview of resonant electron transitions between atoms and metals is given. In the first part of chapter II atom-metal electron transitions at a fixed atom-metal distance are described on the basis of a model developed by Gadzuk. In the second part the influence of the motion of the atom on the atomic charge state is incorporated. Measurements presented in chapter III show a strong dependence of the fraction of negatively charged H atoms scattered at cesiated tungsten, on the normal as well as the parallel velocity component. In chapter IV the proposed mechanism for the parallel velocity effect is incorporated in the amplitude method. The scattering process of protons incident under grazing angles on a cesium covered surface is studied in chapter V. (Auth.)

  19. Surface mass balance and runoff modeling using HIRHAM4 RCM at Kangerlussuaq (Søndre Strømfjord), West Greenland, 1950-2080

    DEFF Research Database (Denmark)

    Mernild, Sebastian H.; Liston, Glen E.; Hiemstra, Christopher A.

    2011-01-01

    Greenland's Kangerlussuaq drainage. Projected changes in the Greenland Ice Sheet (GrIS) surface mass balance (SMB) and runoff are relevant for potential hydropower production and prediction of ecosystem changes in sensitive Kangerlussuaq Fjord systems. Mean annual surface air temperatures and precipitation...... in the Kangerlussuaq area were simulated to increase by 3.4°C and 95 mm water equivalent (w.eq.), respectively, between 1950 and 2080. The local Kangerlussuaq warming was less than the average warming of 4.8°C simulated for the entire GrIS. The Kangerlussuaq SMB loss increased by an average of 0.3 km3 because of a 0.......4 km3 rise in precipitation, 0.1 km3 rise in evaporation and sublimation, and 0.6 km3 gain in runoff (1950-2080). By 2080, the spring runoff season begins approximately three weeks earlier. The average modeled SMB and runoff is approximately -0.1 and 1.2 km3 yr-1, respectively, indicating that ~10...

  20. Analysing surface runoff and erosion responses to different land uses from the NE of Iberian Peninsula through rainfall simulation

    Science.gov (United States)

    Regüés, David; Arnáez, José; Badía, David; Cerdà, Artemi; Echeverría, María Teresa; Gispert, María; Lana-Renault, Noemí; Lasanta, Teodoro; León, Javier; Nadal-Romero, Estela; Pardini, Giovanni

    2014-05-01

    Rainfall simulation experiments are being used by soil scientists, geomorphologists, and hydrologist to study runoff generation and erosion processes. The use of different apparatus with different rainfall intensities and size of the wetted area contribute to determine the most vulnerable soils and land uses (Cerdá, 1998; Cerdà et al., 2009; Nadal-Romero et al., 2011; Martínez-Murillo et al., 2013; León et al., 2014). This research aims to determine the land uses that yield more sediments and water and to know the factors that control the differences. The information from 152 experiments of rainfall simulation was jointly analysed. Experiments were done in 17 land uses (natural forest, tree plantation, burned forest, scrub, meadows, crops and badlands), with contrasted exposition (north-south), and vegetation cover variety and/or density. These situations were selected from four geographic contexts (NE of Catalonia, high and medium lands from the Ebro valley and Southern range of central Pyrenees) with significant altitude variations, between 90 and 1000 meters above sea level, which represent the heterogeneity of the Mediterranean climate. The use of similar rainfall simulation apparatus, with the same spray nozzle, spraying components and plot size, favours the comparison of the results. A wide spectrum of precipitation intensities was applied, in order to reach surface runoff generation in all cases. Results showed significant differences in runoff amounts and erosion rates, which were mainly associated with land uses, even more than precipitation differences. Runoff coefficient shows an inversed exponential relationship with rainfall intensity, which is the opposite what could be previously expected (Ziadat and Taimeh, 2013). This may be only justified by land use characteristics because a direct effect between runoff generation intensity and soil degradation conditions, with respect vegetation covers features and density, was observed. In fact, even though

  1. Hydro engineering Feasibility Study of Surface Runoff Water Harvesting in Al-Ajeej Basin, North West Iraq

    Directory of Open Access Journals (Sweden)

    Thair M. Al-Taiee

    2013-04-01

    Full Text Available The hydro engineering  characteristics of Al-Ajeej basin which was located within south Sinjar plain north west Iraq was analyzed to predict the possibility of surface runoff harvesting during rainfall season in the upstream sites in this basin using watershed modeling system (WMS. The hydrological feasibility of constructing small dam on Al-Ajeej valley with some preliminary design calculations were presented. The best optimum dam site was selected to be located (3.95 km downstream the confluence of Al-Badee branch with Al-Ajeej valley (35° 46¢ 6² Latitude and Longitude 41° 36¢ 11² having a catchment's area of (3043km2. The proposed dam  height was (12.5 meter with a dam length of (1277m, while the normal storage volume of the reservoir is (38.8 million m3. Construction a dams in such sites characterized by water shortage during all  around the year will give an aid in the sustainable development of such area by increasing  the cultivation lands, the agricultural products and also modify the income of the villagers living  in this area leading to prevent them leaving their lands to other places

  2. Surface dynamics using pulsed electron beams

    Science.gov (United States)

    Chan, Ally S. Y.; Jones, Robert G.

    2000-04-01

    Line of sight time of flight has been used to measure the translational energy of ethene formed by dissociative electron attachment of adsorbed dihalocarbons (XCH 2CH 2Y) on Cu(111) at 100 K. A pulsed electron beam was used to generate low energy secondary electrons at the surface, which were the active agents in initiating the decomposition, XCH 2CH 2Y(ads)+e -→XCH 2CH 2rad (ads)+Y(chem)+e -, XCH 2CH 2rad (ads)→C 2H 4(g)+X(chem). For 1,2-dichloroethane (DCE) adsorbed with a spacer layer of chemisorbed chlorine between it and the Cu(111)surface, the TOF data could be fitted using three Maxwell distributions with fast (960 K), slow (180 K) and diffusion ('20 K') components. For a single monolayer of DCE adsorbed directly on the clean Cu(111) surface the fast (1230 K) and slow (225 K) components increased in temperature, indicating that the copper surface was affecting the reaction. For 1-bromo-2-chloroethane the results were the same, consistent with both molecules dissociating via a common intermediate, ClC 2H 4rad (ads). For 1,2-dibromoethane the intermediate is different, BrC 2H 4rad , and decomposition of a monolayer of this molecule on clean Cu(111) exhibited fast (1850 K) and slow (270 K) components, both higher than the corresponding temperatures for DCE. The dynamics of these reactions and the origin of the two Maxwell distributions are discussed in terms of the energy available within the radical, and from the formation of the chemisorbed halogen when the radical dissociates.

  3. Seasonal surface layer dynamics and sensitivity to runoff in a high Arctic fjord (Young Sound/Tyrolerfjord, 74°N)

    Science.gov (United States)

    Bendtsen, Jørgen; Mortensen, John; Rysgaard, Søren

    2014-09-01

    Runoff from the Greenland Ice Sheet, local glaciers, and snowmelt along the northeastern Greenland coastline has a significant impact on coastal water masses flowing south toward Denmark Strait. Very few direct measurements of runoff currently exist in this large area, and the water masses near the coast are also difficult to measure due to the presence of icebergs and sea ice. Measurements from the Zackenberg Research station, located in Young Sound/Tyrolerfjord in northeast Greenland (74°N), provide some of the few observations of hydrographic, hydrologic, and atmospheric parameters from this remote area. Here we analyze measurements from the fjord and also measurements in the ambient water masses, which are found in the outer fjord and between the fjord and the East Greenland Current and validate and apply a numerical model of the fjord. A model sensitivity study allows us to constrain runoff estimates for the area. We also show that a total runoff between 0.9 and 1.4 km3 in 2006 is in accordance with observed surface salinities and calculated freshwater content in the fjord. This indicates that earlier reported runoff to the area is significantly underestimated and that melt from glaciers and the Greenland Ice Sheet in this region may be up to 50% larger than the current estimate. Model simulations indicate the presence of a cold low-saline coastal water mass formed by runoff from fjords north of the Young Sound/Tyrolerfjord system. Simulations of passive and age tracers show that residence time of river water during the summer period is about 1 month in the inner part of the fjord. This article was corrected on 10 OCT 2014. See the end of the full text for details.

  4. Using Historical Precipitation, Temperature, and Runoff Observations to Evaluate Evaporation Formulations in Land Surface Models

    Science.gov (United States)

    Koster, Randal D.; Mahanama, P. P.

    2012-01-01

    Key to translating soil moisture memory into subseasonal precipitation and air temperature forecast skill is a realistic treatment of evaporation in the forecast system used - in particular, a realistic treatment of how evaporation responds to variations in soil moisture. The inherent soil moisture-evaporation relationships used in today's land surface models (LSMs), however, arguably reflect little more than guesswork given the lack of evaporation and soil moisture data at the spatial scales represented by regional and global models. Here we present a new approach for evaluating this critical aspect of LSMs. Seasonally averaged precipitation is used as a proxy for seasonally-averaged soil moisture, and seasonally-averaged air temperature is used as a proxy for seasonally-averaged evaporation (e.g., more evaporative cooling leads to cooler temperatures) the relationship between historical precipitation and temperature measurements accordingly mimics in certain important ways nature's relationship between soil moisture and evaporation. Additional information on the relationship is gleaned from joint analysis of precipitation and streamflow measurements. An experimental framework that utilizes these ideas to guide the development of an improved soil moisture-evaporation relationship is described and demonstrated.

  5. Quantifying the Impact of Seasonal and Short-term Manure Application Decisions on Phosphorus Loss in Surface Runoff.

    Science.gov (United States)

    Vadas, Peter A; Good, Laura W; Jokela, William E; Karthikeyan, K G; Arriaga, Francisco J; Stock, Melanie

    2017-11-01

    Agricultural phosphorus (P) management is a research and policy issue due to P loss from fields and water quality degradation. Better information is needed on the risk of P loss from dairy manure applied in winter or when runoff is imminent. We used the SurPhos computer model and 108 site-years of weather and runoff data to assess the impact of these two practices on dissolved P loss. Model results showed that winter manure application can increase P loss by 2.5 to 3.6 times compared with non-winter applications, with the amount increasing as the average runoff from a field increases. Increased P loss is true for manure applied any time from late November through early March, with a maximum P loss from application in late January and early February. Shifting manure application to fields with less runoff can reduce P loss by 3.4 to 7.5 times. Delaying manure application when runoff is imminent can reduce P loss any time of the year, and sometimes quite significantly, but the number of times that application delays will reduce P loss is limited to only 3 to 9% of possible spreading days, and average P loss may be reduced by only 15% for winter-applied manure and 6% for non-winter-applied manure. Overall, long-term strategies of shifting manure applications to low runoff seasons and fields can potentially reduce dissolved P loss in runoff much more compared with near-term, tactical application decisions of avoiding manure application when runoff is imminent. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  6. Photoelectron spectroscopy bulk and surface electronic structures

    CERN Document Server

    Suga, Shigemasa

    2014-01-01

    Photoelectron spectroscopy is now becoming more and more required to investigate electronic structures of various solid materials in the bulk, on surfaces as well as at buried interfaces. The energy resolution was much improved in the last decade down to 1 meV in the low photon energy region. Now this technique is available from a few eV up to 10 keV by use of lasers, electron cyclotron resonance lamps in addition to synchrotron radiation and X-ray tubes. High resolution angle resolved photoelectron spectroscopy (ARPES) is now widely applied to band mapping of materials. It attracts a wide attention from both fundamental science and material engineering. Studies of the dynamics of excited states are feasible by time of flight spectroscopy with fully utilizing the pulse structures of synchrotron radiation as well as lasers including the free electron lasers (FEL). Spin resolved studies also made dramatic progress by using higher efficiency spin detectors and two dimensional spin detectors. Polarization depend...

  7. The power of runoff

    Science.gov (United States)

    Wörman, A.; Lindström, G.; Riml, J.

    2017-05-01

    Although the potential energy of surface water is a small part of Earth's energy budget, this highly variable physical property is a key component in the terrestrial hydrologic cycle empowering geomorphological and hydrological processes throughout the hydrosphere. By downscaling of the daily hydrometeorological data acquired in Sweden over the last half-century this study quantifies the spatial and temporal distribution of the dominating energy components in terrestrial hydrology, including the frictional resistance in surface water and groundwater as well as hydropower. The energy consumed in groundwater circulation was found to be 34.6 TWh/y or a heat production of approximately 13% of the geothermal heat flux. Significant climate driven, periodic fluctuations in the power of runoff, stream flows and groundwater circulation were revealed that have not previously been documented. We found that the runoff power ranged from 173 to 260 TWh/y even when averaged over the entire surface of Sweden in a five-year moving window. We separated short-term fluctuations in runoff due to precipitation filtered through the watershed from longer-term seasonal and climate driven modes. Strong climate driven correlations between the power of runoff and climate indices, wind and solar intensity were found over periods of 3.6 and 8 years. The high covariance that we found between the potential energy of surface water and wind energy implies significant challenges for the combination of these renewable energy sources.

  8. Highway deicing salt dynamic runoff to surface water and subsequent infiltration to groundwater during severe UK winters.

    Science.gov (United States)

    Rivett, Michael O; Cuthbert, Mark O; Gamble, Richard; Connon, Lucy E; Pearson, Andrew; Shepley, Martin G; Davis, John

    2016-09-15

    Dynamic impact to the water environment of deicing salt application at a major highway (motorway) interchange in the UK is quantitatively evaluated for two recent severe UK winters. The contaminant transport pathway studied allowed controls on dynamic highway runoff and storm-sewer discharge to a receiving stream and its subsequent leakage to an underlying sandstone aquifer, including possible contribution to long-term chloride increases in supply wells, to be evaluated. Logged stream electrical-conductivity (EC) to estimate chloride concentrations, stream flow, climate and motorway salt application data were used to assess salt fate. Stream loading was responsive to salt applications and climate variability influencing salt release. Chloride (via EC) was predicted to exceed the stream Environmental Quality Standard (250mg/l) for 33% and 18% of the two winters. Maximum stream concentrations (3500mg/l, 15% sea water salinity) were ascribed to salt-induced melting and drainage of highway snowfall without dilution from, still frozen, catchment water. Salt persistance on the highway under dry-cold conditions was inferred from stream observations of delayed salt removal. Streambed and stream-loss data demonstrated chloride infiltration could occur to the underlying aquifer with mild and severe winter stream leakage estimated to account for 21 to 54% respectively of the 70t of increased chloride (over baseline) annually abstracted by supply wells. Deicing salt infiltration lateral to the highway alongside other urban/natural sources were inferred to contribute the shortfall. Challenges in quantifying chloride mass/fluxes (flow gauge accuracy at high flows, salt loading from other roads, weaker chloride-EC correlation at low concentrations), may be largely overcome by modest investment in enhanced data acquisition or minor approach modification. The increased understanding of deicing salt dynamic loading to the water environment obtained is relevant to improved

  9. Integrated Landsat Image Analysis and Hydrologic Modeling to Detect Impacts of 25-Year Land-Cover Change on Surface Runoff in a Philippine Watershed

    Directory of Open Access Journals (Sweden)

    Enrico Paringit

    2011-05-01

    Full Text Available Landsat MSS and ETM+ images were analyzed to detect 25-year land-cover change (1976–2001 in the critical Taguibo Watershed in Mindanao Island, Southern Philippines. This watershed has experienced historical modifications of its land-cover due to the presence of logging industries in the 1950s, and continuous deforestation due to illegal logging and slash-and-burn agriculture in the present time. To estimate the impacts of land-cover change on watershed runoff, land-cover information derived from the Landsat images was utilized to parameterize a GIS-based hydrologic model. The model was then calibrated with field-measured discharge data and used to simulate the responses of the watershed in its year 2001 and year 1976 land-cover conditions. The availability of land-cover information on the most recent state of the watershed from the Landsat ETM+ image made it possible to locate areas for rehabilitation such as barren and logged-over areas. We then created a “rehabilitated” land-cover condition map of the watershed (re-forestation of logged-over areas and agro-forestation of barren areas and used it to parameterize the model and predict the runoff responses of the watershed. Model results showed that changes in land-cover from 1976 to 2001 were directly related to the significant increase in surface runoff. Runoff predictions showed that a full rehabilitation of the watershed, especially in barren and logged-over areas, will be likely to reduce the generation of a huge volume of runoff during rainfall events. The results of this study have demonstrated the usefulness of multi-temporal Landsat images in detecting land-cover change, in identifying areas for rehabilitation, and in evaluating rehabilitation strategies for management of tropical watersheds through its use in hydrologic modeling.

  10. A Future Estimation of the Surface Runoff in the Greek Region: A Case Study of one of the Main Catchments Areas (Aravissos - Central Macedonia)

    Science.gov (United States)

    Anagnostopoulou, C.; Tolika, K.; Vafiadis, M.

    2010-09-01

    According to the IPCC latest report (IPCC, 2007) many semi-arid and arid areas, as the Mediterranean basin, are particularly exposed to the impacts of climate change and may suffer a decrease of water resources in the future. By the middle of the 21st century it is estimated that the annual average river runoff and water availability will decrease over these dry regions at mid-latitudes. So, it is of great importance the study of the future changes in the hydrological cycle, due to the increasing freshwater demands. The main scope of the present study is to estimate the future changes of the surface runoff in the Aravissos area (central Macedonia - Greece) due to the enhanced greenhouse effect until the end of the 21st century. The selection of Aravissos was based to the fact that the water needs of the second largest in population city in Greece (Thessaloniki) are covered mainly by the selected catchments area. Daily precipitation, temperature, relative humidity, wind speed and sunlight duration data derived from updated regional climate models, are used for selected grid points covering the domain of study. The main two climatological parameters (precipitation -temperature) are on a first step evaluated in comparison to re-analysis data (E-Obs -Ensembles project) for the same grid points. On a second step, utilizing several different evapotranspiration methods we calculated the surface runoff for two different time periods: the first in the middle and the second at the end of the 21st century. The first results of the study showed that the surface runoff depends on the methodology used for the calculation of the evapotranspiration but also from the regional model. Acknowledgements: This study has been supported by the CC-WaterS project (Contract number SEE/A/022/2.1/X)

  11. Electron work function of stepped tungsten surfaces

    International Nuclear Information System (INIS)

    Krahl-Urban, B.

    1976-03-01

    The electron work function of tungsten (110) vicinal faces was measured with the aid of thermionic emission, and its dependence on the crystallographic orientation and the surface structure was investigated. The thermionic measurements were evaluated with the aid of the Richardson plot. The real temperature of the emitting tungsten faces was determined with an accuracy of +- 0.5% in the range between 2,200 and 2,800 K. The vicinal faces under investigation have been prepared with an orientation exactness of +- 15'. In the tungsten (110) vicinal faces under investigation, a strong dependence of the temperature coefficient d PHI/dT of the work function on the crystallographic orientation was found. A strong influence of the edge structure as well as of the step density on the temperature coefficient was observed. (orig./HPOE) [de

  12. Surface Runoff and Snowmelt Infiltration into the Soil on Plowlands in the Forest-Steppe and Steppe Zones of the East European Plain

    Science.gov (United States)

    Barabanov, A. T.; Dolgov, S. V.; Koronkevich, N. I.; Panov, V. I.; Petel'ko, A. I.

    2018-01-01

    Long-term series of observations over the spring water balance elements on fields with hydrologically contrasting agricultural backgrounds―a loose soil after fall moldboard plowing and a plowland compacted by 12-16% compared to the former soil (perennial grasses, winter crops, stubble)―have been analyzed. The values of surface runoff and water infiltration into the soil in the steppe and forest-steppe zones of European Russia have been calculated for the spring (flooding) period and the entire cold season. The hydrological role of fall plowing has been shown, and water balance elements for the current (1981-2016) and preceding (1957-1980) periods have been compared. A significant decrease in runoff and an increase of water reserve in the soil have been revealed on all plowland types. Consequences of changes in the spring water balance on plowland have been analyzed.

  13. Effects of native perennial vegetation buffer strips on dissolved organic carbon in surface runoff from an agricultural landscape

    Science.gov (United States)

    Tomorra E. Smith; Randall K. Kolka; Xiaobo Zhou; Matthew J. Helmers; Richard M. Cruse; Mark D. Tomer

    2014-01-01

    Dissolved organic carbon (DOC) constitutes a small yet important part of a watershed's carbon budget because it is mobile and biologically active. Agricultural conservation practices such as native perennial vegetation (NPV) strips will influence carbon cycling of an upland agroecosystem, and could affect how much DOC enters streams in runoff, potentially...

  14. An AES Study of the Room Temperature Surface Conditioning of Technological Metal Surfaces by Electron Irradiation

    CERN Document Server

    Scheuerlein, C; Taborelli, M; Brown, A; Baker, M A

    2002-01-01

    The modifications to technological copper and niobium surfaces induced by 2.5 keV electron irradiation have been investigated in the context of the conditioning process occurring in particle accelerator ultra high vacuum systems. Changes in the elemental surface composition have been found using Scanning Auger Microscopy (SAM) by monitoring the carbon, oxygen and metal Auger peak intensities as a function of electron irradiation in the dose range 10-6 to 10-2 C mm-2. The surface analysis results are compared with electron dose dependent secondary electron and electron stimulated desorption yield measurements. Initially the electron irradiation causes a surface cleaning through electron stimulated desorption, in particular of hydrogen. During this period both the electron stimulated desorption and secondary electron yield decrease as a function of electron dose. When the electron dose exceeds 10-4 C mm-2 electron stimulated desorption yields are reduced by several orders of magnitude and the electron beam indu...

  15. Theoretical model of fast electron emission from surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Reinhold, C.; Burgdoerfer, J. [Univ. of Tennessee, Knoxville, TN (United States)]|[Oak Ridge National Laboratory, TN (United States)

    1993-05-01

    Electron emission in glancing-angle ion-surface collisions has become a focus of ion-surface interactions. Electron spectra can provide detailed information on the above surface neutralization dynamics of multiply charged ions, the electronic structure of the surface (surface density of states), and the long-ranged image interactions near the surface. Recent experiments have found that the convoy peak, well known from ion-atom and ion-solid collisions, is dramatically altered. The peak is broadened and shifted in energy which has been attributed to dynamical image interactions. We present a microscopic model for the emission of fast electrons in glancing-angle surface collisions. A classical trajectory Monte Carlo approach is utilized to calculate the evolution of electrons in the presence of their self image, the projectile Coulomb field and the image potential induced by the projectile. The excitation of collective surface modes is also incorporated.

  16. Effects of Fertilization on Surface Runoff Loss of Nitrogen and Phosphorus from Mulberry in the Northern Zhejiang Plain, China

    Directory of Open Access Journals (Sweden)

    SHI Yan-ping

    2016-11-01

    Full Text Available In 2012 and 2013, the situ experimental plots in mulberry under two different kinds of treatment(control fertilization and farmer's conventional fertilization were conducted, and the runoff water in each plot were collected and tested in a period of two years to investigate the law of runoff, the regular pattern and the influential factors of nitrogen and phosphorus losses, and to study the coefficient of fertilizer losses from mulberry in northern Zhejiang plain. The results showed that the annual rainfall runoff coefficient was about 0.253 in mulberry field in northern Zhejiang plain. In those two years, TN and TP cumulative loss load in the conventional fertilization area reached 36.13 kg·hm-2 and 3.49 kg·hm-2, of which the N, P nutrient losses of fertilizer reached 6.415 kg·hm-2 and 1.090 kg·hm-2, respectively. N, P loss coefficients of fertilizer (the difference of nitrogen or phosphorus loss in the conventional fertilization area and the control area was divided by the total amount of fertilizer application were 0.744% and 3.047%. Nitrogen loss were mainly in soluble form, in which the NO3-N and NH4-N, accounting for about 38.3% and 14.4% respectively; while the phosphorus loss were in particulate form, accounting for about 68.9%. The larger amount of nitrogen and phosphorus nutrient loss, were within the first year of the fertilization period, and the P loss was more serious than N. Within a period of fertilization, the cumulative loss of nitrogen and phosphorus caused by rainfall and the occurrence times of runoff increased with power function(R2>0.95.

  17. Runoff of particle bound pollutants from urban impervious surfaces studied by analysis of sediments from stormwater traps

    International Nuclear Information System (INIS)

    Jartun, Morten; Ottesen, Rolf Tore; Steinnes, Eiliv; Volden, Tore

    2008-01-01

    Runoff sediments from 68 small stormwater traps around the harbor of urban Bergen, Norway, were sampled and the concentrations of polychlorinated biphenyls (PCBs), polycyclic aromatic hydrocarbons (PAHs), heavy metals, and total organic carbon (TOC) were determined in addition to grain size. Our study provides empirical data from a large area in the interface between the urban and marine environment, studying the active transport of pollutants from land-based sources. The results of the analyses clearly demonstrate the importance of the urban environment representing a variety of contamination sources, and that stormwater runoff is an important dispersion mechanism of toxic pollutants. The concentrations of different pollutants in urban runoff sediments show that there are several active pollution sources supplying the sewage systems with PCBs, PAHs and heavy metals such as lead (Pb), zinc (Zn) and cadmium (Cd). The concentration of PCB 7 in the urban runoff sediments ranged between 16 , the concentration range was < 0.2-80 mg/kg, whereas the concentration ranges of Pb, Zn and Cd were 9-675, 51.3-4670 and 0.02-11.1 mg/kg respectively. Grain size distribution in 21 selected samples varied from a median particle diameter of 13 to 646 μm. However, several samples had very fine-grained particles even up to the 90 percentile of the samples, making them available for stormwater dispersion in suspended form. The sampling approach proposed in this paper will provide environmental authorities with a useful tool to examine ongoing urban contamination of harbors and similar recipients

  18. Simulation of secondary electron emission from rough surfaces

    International Nuclear Information System (INIS)

    Kawata, J.; Ohya, K.; Nishimura, K.

    1995-01-01

    The effect of surface roughness on the secondary electron emission from a beryllium surface under low-energy (≤1 keV) electron bombardment is investigated using a Monte Carlo simulation combined with the model of bowl-structured surface. With increasing aspect ratio H/W of the bowl structure, the secondary electron yield becomes greater than that for a flat surface, whereas for large H/W the yield is smaller; where H and W are the depth and width of the bowl structure, respectively. The former is due to emission of electrons, which cannot escape from the flat surface, from an inclined plane; it increases the low-energy component in the energy distribution. The latter is due to re-entrance of once-emitted electrons into the next part of the topographic surface; it decreases the number of electrons emitted with oblique angles. ((orig.))

  19. Escoamento superficial em diferentes sistemas de manejo em um Nitossolo Háplico típico Surface runoff in different soil management systems on Typic Hapudox soil

    Directory of Open Access Journals (Sweden)

    Ildegardis Bertol

    2008-06-01

    Full Text Available O preparo mecânico do solo influencia o seu manejo e danifica a estrutura, diminui a porosidade e a infiltração de água e aumenta o escoamento superficial. Utilizando-se simulador de chuvas, estudaram-se os tratamentos, preparo convencional (PC; semeadura direta em resíduo queimado (SQ; semeadura direta em resíduo dessecado (SD; e semeadura direta tradicional em resíduo dessecado (ST, cultivados, além de um preparo convencional sem cultivo do solo (SC - testemunha e de um campo nativo (CN, em um Nitossolo Háplico no Planalto Sul Catarinense, entre março de 2001 e fevereiro de 2004, com o objetivo de quantificar o escoamento superficial. Ao milho e feijão se aplicaram três testes de chuva em cada um e à soja cinco testes. Quantificaram-se os tempos de início (TI e pico (TP de enxurrada, a taxa constante (TE e o volume de enxurrada (VE e o coeficiente C da Equação Racional. Os TI, TP e TE, coeficiente C e VE, foram influenciados pelo preparo e cultivo do solo. O TI e o TP foram menores nos tratamentos PC e SC, enquanto a TE, o coeficiente C e o VE, também foram menores, mas nos tratamentos SD e ST. A TE variou de 18 mm h-1 na ST a 44 mm h-1 no SC, enquanto o coeficiente C variou de 0,29 na ST a 0,71 no SC. A variação do VE foi de 106 m³ ha-1 na ST a 434 m³ ha-1 no SC, na média dos cultivos.Soil tillage influences soil management and damages structure, reduces the porosity and water infiltration and increases surface runoff. A rotating-boom rainfall simulator was used to investigate the treatments: conventional tillage (CT, no-tillage in burn residue (NB, no-tillage in desiccated residue (ND, and traditional no-tillage in desiccated residue (NT, both cropped, as well as conventional tillage without crop (bare soil - BS, and native pasture treatment (NP, in a Typic Hapludox soil, in the Southern Plateau of Santa Catarina State, Brazil, from March, 2001 to February, 2004, with the objective of quantifying surface runoff. Three

  20. Electron Conditioning of Technical Aluminium Surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Le Pimpec, F

    2004-09-02

    The effect of electron conditioning on commercially aluminium alloys 1100 and 6063 were investigated. Contrary to the assumption that electron conditioning, if performed long enough, can reduce and stabilize the SEY to low values (= 1.3, value of many pure elements [1]), the SEY of aluminium did not go lower than 1.8. In fact, it reincreases with continued electron exposure dose.

  1. Surface excitations in electron backscattering from silicon surfaces

    Czech Academy of Sciences Publication Activity Database

    Zemek, Josef; Jiříček, Petr; Lesiak, B.; Jablonski, A.

    2004-01-01

    Roč. 562, - (2004), s. 92-100 ISSN 0039-6028 R&D Projects: GA ČR GA202/02/0237 Institutional research plan: CEZ:AV0Z1010914 Keywords : electron-solid interactions * electron-solid scattering and transmission-elastic * electron-solid scattering and transmission-inelastic * Monte Carlo simulation * electron bombardment * silicon Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.168, year: 2004

  2. Electron emission during multicharged ion-metal surface interactions

    International Nuclear Information System (INIS)

    Zeijlmans van Emmichoven, P.A.; Havener, C.C.; Hughes, I.G.; Overbury, S.H.; Robinson, M.T.; Zehner, D.M.; Meyer, F.W.

    1992-01-01

    The electron emission during multicharged ion-metal surface interactions will be discussed. The interactions lead to the emission of a significant number of electrons. Most of these electrons have energies below 30 eV. For incident ions with innershell vacancies the emission of Auger electrons that fill these vacancies has been found to occur mainly below the surface. We will present recently measured electron energy distributions which will be used to discuss the mechanisms that lead to the emission of Auger and of low-energy electrons

  3. Atomic and electronic structures of novel silicon surface structures

    Energy Technology Data Exchange (ETDEWEB)

    Terry, J.H. Jr.

    1997-03-01

    The modification of silicon surfaces is presently of great interest to the semiconductor device community. Three distinct areas are the subject of inquiry: first, modification of the silicon electronic structure; second, passivation of the silicon surface; and third, functionalization of the silicon surface. It is believed that surface modification of these types will lead to useful electronic devices by pairing these modified surfaces with traditional silicon device technology. Therefore, silicon wafers with modified electronic structure (light-emitting porous silicon), passivated surfaces (H-Si(111), Cl-Si(111), Alkyl-Si(111)), and functionalized surfaces (Alkyl-Si(111)) have been studied in order to determine the fundamental properties of surface geometry and electronic structure using synchrotron radiation-based techniques.

  4. Surface and volume photoemission of hot electrons from plasmonic nanoantennas

    DEFF Research Database (Denmark)

    Uskov, Alexander V.; Protsenko, Igor E.; Ikhsanov, Renat S.

    2014-01-01

    We theoretically compare surface- and volume-based photoelectron emission from spherical nanoparticles, obtaining analytical expressions for the emission rate in both mechanisms. We show that the surface mechanism prevails, being unaffected by detrimental hot electron collisions....

  5. Multiscale soil moisture measurement for mapping surface runoff generation on torrential headwater catchments (Draix-Bléone field observatory, South Alps, France)

    Science.gov (United States)

    Florian, Mallet; Vincent, Marc; Johnny, Douvinet; Philippe, Rossello; Bouteiller Caroline, Le; Jean-Philippe, Malet; Julien, Gance

    2015-04-01

    soilwater flow of from the surface to - 30 cm. Another distributed approach will be carried out from a measurement of cosmic neutrons mitigation (Cosmic ray sensor) to estimate a soil moisture averaged value over 40 ha (Zreda et al., 2012). Finally, the smallest scale (slope and catchment) will be approached using remote sensing with a drone and/or satellite imagery (IR, passive and active microwave). This concatenation of scales with different combinations of time steps should enable us to better understand the hydrological dynamics in torrential environments. It aims at mapping the stormflow generation on a catchment at the flood scale and defining the main determinants of surface runoff. These results may contribute to the improvement of runoff simulation and flood prediction. References : Uhlenbrook S., J.J. McDonnell and C. Leibundgut, 2003. Preface: Runoff generation implications for river basin modelling. Hydrological Processes, Special Issue, 17: 197-198. Andrew W. Western, Sen-Lin Zhou, Rodger B. Grayson, Thomas A. MacMahon, Günter Blöshl, David J. Wilson, 2004. Spatial correlation of soil moisture in small catchments and its relationship to dominant spatial hydrological processes. Journal of Hydrology 286. Zreda, M., Shuttleworth WJ., Zeng X., Zweck C., Desilets D., Franz TE. et al., 2012. COSMOS: the COsmic-ray Soil Moisture Observing System. Hydrology and Earth System Sciences, 16(11): 4079-4099.

  6. Electron stimulated desorption of gases at technological surfaces of aluminium

    International Nuclear Information System (INIS)

    Ding, M.Q.; Williams, E.M.

    1989-01-01

    The release of gas by electron bombardment at aluminium alloy surfaces in vacuum -9 torr has been investigated for a range of treatments including bakeout and glow discharge cleaning. Particular attention has been given to the role of continuous electron bombardment, with current densities and electron energies of up to 1.5 mA cm -2 and 2.0 keV, respectively, over the 10 cm 2 of surface area under irradiation. The observations of desorption efficiency, defined as the number of desorbed molecules per incident electron, conform to a model involving a dynamic balance between adsorption and desorption, with contributions to adsorption from both surface and sub-surface gas. Continuous electron bombardment promotes a surface with low desorption efficiency, -5 mol/electron, however, the conditioning cycle is accelerated significantly by glow discharge treatment. There is evidence of some short-term memory when the samples are exposed to air. (author)

  7. Surface influence on convoy electron emission at low energies

    International Nuclear Information System (INIS)

    Sanchez, E.A.

    1988-01-01

    It is studied the dependence of the production of convoy electrons induced by H + - 60 KeV with surface conditions of Al targets by in situ deposition of Na and O. The conclusion is that convoy electron production increases with the work function of the surface. (A.C.A.S.) [pt

  8. Using Data Assimilation Method Via an Ensemble Kalman Filter to Predict Adsorptive Solute Cr(Ⅵ) Transfer from Soil into Surface Runoff

    Science.gov (United States)

    Tong, J.

    2014-12-01

    With the development of modern agriculture, large amount of fertilizer and pesticide outflow from farming land causes great wastes and contributes to serious pollution of surface water and groundwater, which threatens ecological environment and human life. In this paper, laboratory experiments are conducted to simulate adsorbed Cr(VI) transfer from soil into runoff. A two-layer in-mixing analytical model is developed to to analyze laboratory experimental results. A data assimilation (DA) method via the ensemble Kalman filter (EnKF) is used to update parameters and improve predictions. In comparison with the observed data, DA results are much better than forward model predictions. Based on the used rainfall and relevant physical principles, the updated value of the incomplete mixing coefficient is about 7.4 times of the value of the incomplete mixing coefficient in experiment 1 and about 14.0 times in experiment 2, which indicates the loss of Cr(VI) in soil solute is mainly due to infiltration, rather than surface runoff. With the increase of soil adsorption ability and the mixing layer depth, the loss of soil solute will decrease. These results provide information for preventing and reducing the agricultural nonpoint source pollution.

  9. Surface properties and microporosity of polyhydroxybutyrate under scanning electron microscopy

    International Nuclear Information System (INIS)

    Raouf, A.A.; Samsudin, A.R.; Samian, R.; Akool, K.; Abdullah, N.

    2004-01-01

    This study was designed to investigate the surface properties especially surface porosity of polyhydroxybutyrate (PHB) using scanning electron microscopy. PHB granules were sprinkled on the double-sided sticky tape attached on a SEM aluminium stub and sputtered with gold (10nm thickness) in a Polaron SC515 Coater, following which the samples were placed into the SEM specimen chamber for viewing and recording. Scanning electron micrographs with different magnification of PHB surface revealed multiple pores with different sizes. (Author)

  10. Nutrient, metal and microbial loss in surface runoff following treated sludge and dairy cattle slurry application to an Irish grassland soil

    Energy Technology Data Exchange (ETDEWEB)

    Peyton, D.P. [Teagasc, Environment Research Centre, Johnstown Castle, Co. Wexford (Ireland); Civil Engineering, National University of Ireland, Galway, Co. Galway (Ireland); Healy, M.G. [Civil Engineering, National University of Ireland, Galway, Co. Galway (Ireland); Fleming, G.T.A. [Microbiology, National University of Ireland, Galway, Co. Galway (Ireland); Grant, J. [Teagasc, Ashtown, Co. Dublin (Ireland); Wall, D. [Teagasc, Environment Research Centre, Johnstown Castle, Co. Wexford (Ireland); Morrison, L. [Earth and Ocean Sciences and Ryan Institute, National University of Ireland, Galway, Co. Galway (Ireland); Cormican, M. [School of Medicine, National University of Ireland, Galway, Co. Galway (Ireland); Fenton, O., E-mail: owen.fenton@teagasc.ie [Teagasc, Environment Research Centre, Johnstown Castle, Co. Wexford (Ireland)

    2016-01-15

    Treated municipal sewage sludge (“biosolids”) and dairy cattle slurry (DCS) may be applied to agricultural land as an organic fertiliser. This study investigates losses of nutrients in runoff water (nitrogen (N) and phosphorus (P)), metals (copper (Cu), nickel (Ni), lead (Pb), zinc (Zn), cadmium (Cd), chromium (Cr)), and microbial indicators of pollution (total and faecal coliforms) arising from the land application of four types of treated biosolids and DCS to field micro-plots at three time intervals (24, 48, 360 h) after application. Losses from biosolids-amended plots or DCS-amended plots followed a general trend of highest losses occurring during the first rainfall event and reduced losses in the subsequent events. However, with the exception of total and faecal coliforms and some metals (Ni, Cu), the greatest losses were from the DCS-amended plots. For example, average losses over the three rainfall events for dissolved reactive phosphorus and ammonium-nitrogen from DCS-amended plots were 5 and 11.2 mg L{sup −1}, respectively, which were in excess of the losses from the biosolids plots. When compared with slurry treatments, for the parameters monitored biosolids generally do not pose a greater risk in terms of losses along the runoff pathway. This finding has important policy implications, as it shows that concern related to the reuse of biosolids as a soil fertiliser, mainly related to contaminant losses upon land application, may be unfounded. - Highlights: • This study investigated surface runoff of contaminants from biosolids in field plots. • Contaminants investigated were nutrients, metals, microbes and trace elements. • Compared to slurry, biosolids do not pose a greater risk of contaminant losses. • Fears concerning contaminant losses from land applied biosolids may be unfounded.

  11. A 3-step framework for understanding the added value of surface soil moisture measurements for large-scale runoff prediction via data assimilation - a synthetic study in the Arkansas-Red River basin

    Science.gov (United States)

    Mao, Y.; Crow, W. T.; Nijssen, B.

    2017-12-01

    Soil moisture (SM) plays an important role in runoff generation both by partitioning infiltration and surface runoff during rainfall events and by controlling the rate of subsurface flow during inter-storm periods. Therefore, more accurate SM state estimation in hydrologic models is potentially beneficial for streamflow prediction. Various previous studies have explored the potential of assimilating SM data into hydrologic models for streamflow improvement. These studies have drawn inconsistent conclusions, ranging from significantly improved runoff via SM data assimilation (DA) to limited or degraded runoff. These studies commonly treat the whole assimilation procedure as a black box without separating the contribution of each step in the procedure, making it difficult to attribute the underlying causes of runoff improvement (or the lack thereof). In this study, we decompose the overall DA process into three steps by answering the following questions (3-step framework): 1) how much can assimilation of surface SM measurements improve surface SM state in a hydrologic model? 2) how much does surface SM improvement propagate to deeper layers? 3) How much does (surface and deeper-layer) SM improvement propagate into runoff improvement? A synthetic twin experiment is carried out in the Arkansas-Red River basin ( 600,000 km2) where a synthetic "truth" run, an open-loop run (without DA) and a DA run (where synthetic surface SM measurements are assimilated) are generated. All model runs are performed at 1/8 degree resolution and over a 10-year period using the Variable Infiltration Capacity (VIC) hydrologic model at a 3-hourly time step. For the DA run, the ensemble Kalman filter (EnKF) method is applied. The updated surface and deeper-layer SM states with DA are compared to the open-loop SM to quantitatively evaluate the first two steps in the framework. To quantify the third step, a set of perfect-state runs are generated where the "true" SM states are directly inserted

  12. Tantalum surface oxidation: Bond relaxation, energy entrapment, and electron polarization

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Yongling [Key Laboratory of Low-Dimensional Materials and Application Technologies (Ministry of Education), Hunan Provincial Key Laboratory of Thin Film Materials and Devices, Faculty of Materials Science and Engineering, Xiangtan University, Hunan 411105 (China); Bo, Maolin [Yangtze Normal University, College of Mechanical and Electrical Engineering, Chongqing 408100 (China); Wang, Yan [School of Information and Electronic Engineering, Hunan University of Science and Technology, Hunan 411201 (China); Liu, Yonghui [Key Laboratory of Low-Dimensional Materials and Application Technologies (Ministry of Education), Hunan Provincial Key Laboratory of Thin Film Materials and Devices, Faculty of Materials Science and Engineering, Xiangtan University, Hunan 411105 (China); Sun, Chang Q. [NOVITAS, School of Electrical and Electronic Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Huang, Yongli, E-mail: huangyongli@xtu.edu.cn [Key Laboratory of Low-Dimensional Materials and Application Technologies (Ministry of Education), Hunan Provincial Key Laboratory of Thin Film Materials and Devices, Faculty of Materials Science and Engineering, Xiangtan University, Hunan 411105 (China)

    2017-02-28

    Graphical abstract: The bond, electron and energy relaxation result in core level energy shift, local densification, quantum entrapment and electron polarization of bonding electrons. - Highlights: • Increasing the oxygen coverage lowers the adsorption energy associated with lattice reconstruction. • Electrons transfer from Ta surface atoms to sp-hydrated oxygen, creating dipole moment that decreases the work function. • Oxygen chemisorption modified valence density-of-state (DOS) for Ta with four excessive DOS features: O−Ta bonding, O{sup 2−} lone pairs, Ta+ electron holes, and the lone-pair polarized Ta dipoles. • The bond, electron and energy relaxation between surface undercoordinated atoms are responsible for core level energy shift, local densification, quantum entrapment and electron polarization of bonding electrons. - Abstract: A combination of photoelectron spectrometric analysis and density functional theory calculations has enabled reconciliation of the bond-energy-electron relaxation for the Ta(100, 110, 111) surfaces chemisorbed with oxygen at different coverages. Results show that increasing oxygen coverage lowers the adsorption energy associated with lattice reconstruction. Valence electrons transfer from Ta surface atoms to oxygen to create four excessive DOS features in terms of O−Ta bonding, lone pairs of oxygen, Ta{sup +} electron holes, and polarized Ta dipoles. Oxidation proceeds in the following dynamics: oxygen gets electrons from two neighboring Ta atoms left behind Ta{sup +}; the sp{sup 3}-orbital hybridization takes place with additional two electron lone pairs, the lone pairs polarize the other two Ta neighbors becoming dipoles. X-ray photoelectron spectral analysis results in the 4f binding energy of an isolated Ta atom and its shift upon bond formation and oxidation. Exercises provide not only a promising numerical approach for the quantitative information about the bond and electronic behavior but also consistent

  13. Some unusual electronic patterns on graphite surface

    Indian Academy of Sciences (India)

    gives rise to one-dimensional fringe-like pattern as seen with the STM. We are also reporting here observation of such large-scale linear fringes near defects. 2. Experimental details. Experiments were done with a home-built compact STM similar to the one de- scribed in [10]. This STM uses commercial electronics and ...

  14. Phosphogypsum surface characterisation using scanning electron microscopy

    Directory of Open Access Journals (Sweden)

    Rajković Miloš B.

    2003-01-01

    Full Text Available This paper presents the results of application of Scanning Electron Microscopy (SEM to examinations of the samples of natural gypsum and phosphogypsum. Phosphogypsum has a well developed crystalline structure, and appear in two polymorphous forms, of rombic and hexagonal shape crystals. Natural gypsum has a poorly crystalline structure. The differences in crystalline structure influence the chemical behavior of these row materials.

  15. Electron bombardment of water adsorbed on Zr(0001) surfaces

    CERN Document Server

    Ankrah, S; Ramsier, R D

    2003-01-01

    A study of the effects of electron bombardment on water adsorbed on Zr(0001) is reported. Zirconium surfaces are dosed with isotopic water mixtures at 160 K followed by electron bombardment (485 eV). The system is then probed by low energy electron diffraction, temperature programmed desorption (TPD) and Auger electron spectroscopy (AES). No evidence is found that would indicate preferential mixing of hydrogen from the bulk with isotopic water dissociation products during TPD. However, electron bombardment results in the sharpening of a hydrogen/deuterium desorption peak near 320 K and the production of water near 730 K at low water exposures. In addition, although water does not oxidize Zr(0001) thermally, electron bombardment of adsorbed water induces a shift of about 2 eV in the Zr AES features indicating that the surface is partially oxidized by electron bombardment.

  16. A quantitative microbial risk assessment model for total coliforms and E. coli in surface runoff following application of biosolids to grassland.

    Science.gov (United States)

    Clarke, Rachel; Peyton, Dara; Healy, Mark G; Fenton, Owen; Cummins, Enda

    2017-05-01

    In Ireland, the land application of biosolids is the preferred option of disposing of municipal sewage waste. Biosolids provide nutrients in the form of nitrogen, phosphorus, potassium and increases organic matter. It is also an economic way for a country to dispose of its municipal waste. However, biosolids may potentially contain a wide range of pathogens, and following rainfall events, may be transported in surface runoff and pose a potential risk to human health. Thus, a quantitative risk assessment model was developed to estimate potential pathogens in surface water and the environmental fate of the pathogens following dilution, residence time in a stream, die-off rate, drinking water treatment and human exposure. Surface runoff water quality data was provided by project partners. Three types of biosolids, anaerobically digested (AD), lime stabilised (LS), and thermally dried (TD)) were applied on micro plots. Rainfall was simulated at three time intervals (24, 48 and 360 h) following land application. It was assumed that this water entered a nearby stream and was directly abstracted for drinking water. Consumption data for drinking water and body weight was obtained from an Irish study and assigned distributions. Two dose response models for probability of illness were considered for total and faecal coliform exposure incorporating two different exposure scenarios (healthy populations and immuno-compromised populations). The simulated annual risk of illness for healthy populations was below the US EPA and World Health Organisation tolerable level of risk (10 -4 and 10 -6 , respectively). However, immuno-compromised populations may still be at risk as levels were greater than the tolerable level of risk for that subpopulation. The sensitivity analysis highlighted the importance of residence time in a stream on the bacterial die-off rate. Copyright © 2016 Elsevier Ltd. All rights reserved.

  17. The role of electron scattering in electron-induced surface chemistry

    NARCIS (Netherlands)

    van Dorp, Willem F.

    2012-01-01

    Electron-induced chemistry on surfaces plays a key role in focused electron beam induced processing (FEBIP), a single-step lithography technique that has increasingly gained interest in the past decade. It is crucial for the understanding and modelling of this process to know the role of the surface

  18. Structural and electronic properties of hydrosilylated silicon surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Baumer, A.

    2005-11-15

    The structural and electronic properties of alkyl-terminated Si surfaces prepared by thermallyinduced hydrosilylation have been studied in detail in the preceding chapters. Various surfaces have been used for the functionalization ranging from crystalline Si over amorphous hydrogenated Si to nanoscaled materials such as Si nanowires and nanoparticles. In each case, the alkyl-terminated surfaces have been compared to the native oxidized and H-terminated surfaces. (orig.)

  19. Hot-electron nanoscopy using adiabatic compression of surface plasmons

    KAUST Repository

    Giugni, Andrea

    2013-10-20

    Surface plasmon polaritons are a central concept in nanoplasmonics and have been exploited to develop ultrasensitive chemical detection platforms, as well as imaging and spectroscopic techniques at the nanoscale. Surface plasmons can decay to form highly energetic (or hot) electrons in a process that is usually thought to be parasitic for applications, because it limits the lifetime and propagation length of surface plasmons and therefore has an adverse influence on the functionality of nanoplasmonic devices. Recently, however, it has been shown that hot electrons produced by surface plasmon decay can be harnessed to produce useful work in photodetection, catalysis and solar energy conversion. Nevertheless, the surface-plasmon-to-hot-electron conversion efficiency has been below 1% in all cases. Here we show that adiabatic focusing of surface plasmons on a Schottky diode-terminated tapered tip of nanoscale dimensions allows for a plasmon-to-hot-electron conversion efficiency of ∼30%. We further demonstrate that, with such high efficiency, hot electrons can be used for a new nanoscopy technique based on an atomic force microscopy set-up. We show that this hot-electron nanoscopy preserves the chemical sensitivity of the scanned surface and has a spatial resolution below 50 nm, with margins for improvement.

  20. The surface electronic structure of Y(0001)

    International Nuclear Information System (INIS)

    Searle, C.

    1998-12-01

    Yttrium has been grown epitaxially on W(110). The growth was monitored by using photoemission spectroscopy with a synchrotron radiation source. The film thickness has been gauged by the attenuation of the W 4f 7/2 bulk component. The films have been grown reproducibly and show a prominent surface state which is indicative of good order and low contamination. Angle-Resolved Ultra-Violet Photoemission Spectroscopy has been used to examine the valence band of these ultra-thin films. The films show a very different structure to the valence band of a bulk crystal of yttrium. The differences have been investigated by a series of model calculations using the LMASA-46 tight-binding LMTO program. The calculations suggest that the ultra-thin film surface state may be hybridised with a tungsten orbital having (x 2 - y 2 ) character. (author)

  1. EVOLUTION OF IONS AFTER MULTIPLE ELECTRON-CAPTURE FROM SURFACES

    NARCIS (Netherlands)

    MORGENSTERN, R; DAS, J

    1993-01-01

    A comparison is made of the electronic processes which occur when a multiply charged ion is approaching an atomic target on the one hand or a metal surface on the other hand. In both caws three collision phases can be identified: those of attraction, of electron capture and of decay in the vacuum;

  2. Relaxation between electrons and surface phonons of a ...

    Indian Academy of Sciences (India)

    Abstract. The energy relaxation between the hot degenerate electrons of a homoge- neously photoexcited metal film and the surface phonons (phonon wave vectors in two dimensions) is considered under Debye approximation. The state of electrons and phonons is described by equilibrium Fermi and Bose functions with ...

  3. Relaxation between electrons and surface phonons of a ...

    Indian Academy of Sciences (India)

    The energy relaxation between the hot degenerate electrons of a homogeneously photoexcited metal film and the surface phonons (phonon wave vectors in two dimensions) is considered under Debye approximation. The state of electrons and phonons is described by equilibrium Fermi and Bose functions with different ...

  4. Analytical Chemistry of Surfaces: Part II. Electron Spectroscopy.

    Science.gov (United States)

    Hercules, David M.; Hercules, Shirley H.

    1984-01-01

    Discusses two surface techniques: X-ray photoelectron spectroscopy (ESCA) and Auger electron spectroscopy (AES). Focuses on fundamental aspects of each technique, important features of instrumentation, and some examples of how ESCA and AES have been applied to analytical surface problems. (JN)

  5. A surface-electrode quadrupole guide for electrons

    Energy Technology Data Exchange (ETDEWEB)

    Hoffrogge, Johannes Philipp

    2012-12-19

    This thesis reports on the design and first experimental realization of a surface-electrode quadrupole guide for free electrons. The guide is based on a miniaturized, planar electrode layout and is driven at microwave frequencies. It confines electrons in the near-field of the microwave excitation, where strong electric field gradients can be generated without resorting to resonating structures or exceptionally high drive powers. The use of chip-based electrode geometries allows the realization of versatile, microstructured potentials with the perspective of novel quantum experiments with guided electrons. I present the design, construction and operation of an experiment that demonstrates electron confinement in a planar quadrupole guide for the first time. To this end, electrons with kinetic energies from one to ten electron-volts are guided along a curved electrode geometry. The stability of electron guiding as a function of drive parameters and electron energy has been studied. A comparison with numerical particle tracking simulations yields good qualitative agreement and provides a deeper understanding of the electron dynamics in the guiding potential. Furthermore, this thesis gives a detailed description of the design of the surface-electrode layout. This includes the development of an optimized coupling structure to inject electrons into the guide with minimum transverse excitation. I also discuss the extension of the current setup to longitudinal guide dimensions that are comparable to or larger than the wavelength of the drive signal. This is possible with a modified electrode layout featuring elevated signal conductors. Electron guiding in the field of a planar, microfabricated electrode layout allows the generation of versatile and finely structured guiding potentials. One example would be the realization of junctions that split and recombine a guided electron beam. Furthermore, it should be possible to prepare electrons in low-lying quantum mechanical

  6. A surface-electrode quadrupole guide for electrons

    International Nuclear Information System (INIS)

    Hoffrogge, Johannes Philipp

    2012-01-01

    This thesis reports on the design and first experimental realization of a surface-electrode quadrupole guide for free electrons. The guide is based on a miniaturized, planar electrode layout and is driven at microwave frequencies. It confines electrons in the near-field of the microwave excitation, where strong electric field gradients can be generated without resorting to resonating structures or exceptionally high drive powers. The use of chip-based electrode geometries allows the realization of versatile, microstructured potentials with the perspective of novel quantum experiments with guided electrons. I present the design, construction and operation of an experiment that demonstrates electron confinement in a planar quadrupole guide for the first time. To this end, electrons with kinetic energies from one to ten electron-volts are guided along a curved electrode geometry. The stability of electron guiding as a function of drive parameters and electron energy has been studied. A comparison with numerical particle tracking simulations yields good qualitative agreement and provides a deeper understanding of the electron dynamics in the guiding potential. Furthermore, this thesis gives a detailed description of the design of the surface-electrode layout. This includes the development of an optimized coupling structure to inject electrons into the guide with minimum transverse excitation. I also discuss the extension of the current setup to longitudinal guide dimensions that are comparable to or larger than the wavelength of the drive signal. This is possible with a modified electrode layout featuring elevated signal conductors. Electron guiding in the field of a planar, microfabricated electrode layout allows the generation of versatile and finely structured guiding potentials. One example would be the realization of junctions that split and recombine a guided electron beam. Furthermore, it should be possible to prepare electrons in low-lying quantum mechanical

  7. Measures to reduce glyphosate runoff from hard surfaces, 2: effect of time interval between application and first precipitation event

    NARCIS (Netherlands)

    Luijendijk, C.D.; Beltman, W.H.J.; Smidt, R.A.; Pas, van der L.J.T.; Kempenaar, C.

    2005-01-01

    In this research the effect of moisture conditions of hard surfaces on emission of herbicides from hard surfaces was quantified. In addition the dissipation of glyphosate applied on brick-pavement is determined in time. The outdoor experiment was carried out on 3 and 17 June 2003. In previous

  8. ESCORRENTÍA SUPERFICIAL EN BOSQUES MONTANOS NATURALES Y PLANTADOS DE PIEDRAS BLANCAS, ANTIOQUIA (COLOMBIA SURFACE RUNOFF IN NATURAL MONTANE FORESTS AND FOREST PLANTATIONS IN ANTIOQUIA, COLOMBIA

    Directory of Open Access Journals (Sweden)

    Oscar Andrés Ruiz Suescún

    2005-06-01

    Full Text Available En bosques montanos naturales de roble (Quercus humboldtii Bonpl. y plantados de pino pátula (Pinus patula Schltdl. & Cham. y ciprés (Cupressus lusitanica Mill. de la región de Piedras Blancas, Antioquia (Colombia, fueron medidos los flujos de escorrentía superficial (ES por un periodo de tiempo de 16 meses. Se implementaron parcelas cerradas de escorrentía superficial de 10 m de largo x 2 m de ancho, tanques colectores y sistemas de registro volumétrico. Los flujos fueron de 23,19 mm año-1 (1,07 % de la precipitación para la cobertura de roble; 35,13 mm año-1 (1,61 % de la precipitación para la cobertura de pino pátula y 230,64 mm año-1 (11,05 % de la precipitación para la cobertura de ciprés. Mediante análisis de componentes principales (ACP se identificaron las relaciones existentes entre las variables hidrológicas y los flujos de ES, y por medio de análisis de regresión lineal múltiple se ajustaron modelos para los flujos de ES por cobertura en función de la precipitación, la precipitación en el bosque y la intensidad de lluvia promedio, variables que mostraron alta relación con la ES según el ACP.In natural montane oak forests (Quercus humboldtii Bonpl., in pine (Pinus patula Schltdl. & Cham. and cypress (Cupressus lusitanica Mill. plantations in Piedras Blancas, Antioquia (Colombia, surface runoff flows (SRF were measured over 16 months. Runoff was measured using 10 m long x 2 m wide runoff bounded plots, collector tanks and a volumetric counter system. SRF were 23,19 mm year -1 (1,07 % of rainfall for oak forest; 35,13 mm year -1 (1,61 % of rainfall for pine and 230,64 mm year-1 (11,05 % of rainfall for cypress plantations. Relationships between hydrological variables and SRF were identified by a principal components analysis (PCA. For each one of the stands, multiple regression analysis was used to fit models of SRF on rainfall, throughfall and mean intensity of rainfall, variables that, according to the PCA

  9. Electronic collective modes and instabilities on semiconductor surfaces. I

    International Nuclear Information System (INIS)

    Muramatsu, A.; Hanke, W.

    1984-01-01

    A Green's-function theory of electronic collective modes is presented which leads to a practical scheme for a microscopic determination of surface elementary excitations in conducting as well as nonconducting solids. Particular emphasis is placed on semiconductor surfaces where the jellium approximation is not valid, due to the importance of density fluctuations on a microscopic scale (reflected in the local-field effects). Starting from the Bethe-Salpeter equation for the two-particle Green's function of the surface system, an equation of motion for the electron-hole pair is obtained. Its solutions determine the energy spectra, lifetimes, and amplitudes of the surface elementary excitations, i.e., surface plasmons, excitons, polaritons, and magnons. Exchange and correlation effects are taken into account through the random-phase and time-dependent Hartree-Fock (screened electron-hole attraction) approximations. The formalism is applied to the study of electronic (charge- and spin-density) instabilities at covalent semiconductor surfaces. Quantitative calculations for an eight-layer Si(111) slab display an instability of the ideal paramagnetic surface with respect to spin-density waves with wavelength nearly corresponding to (2 x 1) and (7 x 7) superstructures

  10. Assessment of Runoff Contributing Catchment Areas in Rainfall Runoff Modelling

    DEFF Research Database (Denmark)

    Thorndahl, Søren Liedtke; Johansen, C.; Schaarup-Jensen, Kjeld

    2005-01-01

    recommended literary values for residential areas. It is proven by comparing rainfall-runoff measurements from four different residential catchments that the literary values of the hydrological reduction factor are over-estimated for this type of catchments. In addition, different catchment descriptions......In numerical modelling of rainfall caused runoff in urban sewer systems an essential parameter is the hydrological reduction factor which defines the percentage of the impervious area contributing to the surface flow towards the sewer. As the hydrological processes during a rainfall are difficult...... to determine with significant precision the hydrological reduction factor is implemented to account all hydrological losses except the initial loss. This paper presents an inconsistency between calculations of the hydrological reduction factor, based on measurements of rainfall and runoff, and till now...

  11. Assessment of runoff contributing catchment areas in rainfall runoff modelling

    DEFF Research Database (Denmark)

    Thorndahl, Søren; Johansen, C.; Schaarup-Jensen, Kjeld

    2006-01-01

    recommended literature values for residential areas. It is proven by comparing rainfall-runoff measurements from four different residential catchments that the literature values of the hydrological reduction factor are over-estimated for this type of catchment. In addition, different catchment descriptions......In numerical modelling of rainfall caused runoff in urban sewer systems an essential parameter is the hydrological reduction factor which defines the percentage of the impervious area contributing to the surface flow towards the sewer. As the hydrological processes during a rainfall are difficult...... to determine with significant precision the hydrological reduction factor is implemented to account all hydrological losses except the initial loss. This paper presents an inconsistency between calculations of the hydrological reduction factor, based on measurements of rainfall and runoff, and till now...

  12. Treatment of surfaces with low-energy electrons

    Energy Technology Data Exchange (ETDEWEB)

    Frank, L., E-mail: ludek@isibrno.cz [Institute of Scientific Instruments of the CAS, v.v.i., Královopolská 147, 61264 Brno (Czech Republic); Mikmeková, E. [Institute of Scientific Instruments of the CAS, v.v.i., Královopolská 147, 61264 Brno (Czech Republic); FEI Company, Achtseweg Noord 5, 5651 GG Eindhoven (Netherlands); Lejeune, M. [LPMC – Faculte des Sciences d’Amiens, Universite de Picardie Jules Verne, 33 rue Saint Leu, 80039 Amiens Cedex 2 (France)

    2017-06-15

    Highlights: • Using proper irradiation parameters, adsorbed hydrocarbons are released from surfaces. • Slow electrons remove hydrocarbons instead of depositing carbon. • Prolonged irradiation with very slow electrons does not create defects in graphene. - Abstract: Electron-beam-induced deposition of various materials from suitable precursors has represented an established branch of nanotechnology for more than a decade. A specific alternative is carbon deposition on the basis of hydrocarbons as precursors that has been applied to grow various nanostructures including masks for subsequent technological steps. Our area of study was unintentional electron-beam-induced carbon deposition from spontaneously adsorbed hydrocarbon molecules. This process traditionally constitutes a challenge for scanning electron microscopy practice preventing one from performing any true surface studies outside an ultrahigh vacuum and without in-situ cleaning of samples, and also jeopardising other electron-optical devices such as electron beam lithographs. Here we show that when reducing the energy of irradiating electrons sufficiently, the e-beam-induced deposition can be converted to e-beam-induced release causing desorption of hydrocarbons and ultimate cleaning of surfaces in both an ultrahigh and a standard high vacuum. Using series of experiments with graphene samples, we demonstrate fundamental features of e-beam-induced desorption and present results of checks for possible radiation damage using Raman spectroscopy that led to optimisation of the electron energy for damage-free cleaning. The method of preventing carbon contamination described here paves the way for greatly enhanced surface sensitivity of imaging and substantially reduced demands on vacuum systems for nanotechnological applications.

  13. A surface diffuse scattering model for the mobility of electrons in surface charge coupled devices

    International Nuclear Information System (INIS)

    Ionescu, M.

    1977-01-01

    An analytical model for the mobility of electrons in surface charge coupled devices is studied on the basis of the results previously obtained, considering a surface diffuse scattering; the importance of the results obtained for a better understanding of the influence of the fringing field in surface charge coupled devices is discussed. (author)

  14. Quality of surface-water runoff in selected streams in the San Antonio segment of the Edwards aquifer recharge zone, Bexar County, Texas, 1997-2012

    Science.gov (United States)

    Opsahl, Stephen P.

    2012-01-01

    During 1997–2012, the U.S. Geological Survey, in cooperation with the San Antonio Water System, collected and analyzed water-quality constituents in surface-water runoff from five ephemeral stream sites near San Antonio in northern Bexar County, Texas. The data were collected to assess the quality of surface water that recharges the Edwards aquifer. Samples were collected from four stream basins that had small amounts of developed land at the onset of the study but were predicted to undergo substantial development over a period of several decades. Water-quality samples also were collected from a fifth stream basin located on land protected from development to provide reference data by representing undeveloped land cover. Water-quality data included pH, specific conductance, chemical oxygen demand, dissolved solids (filtered residue on evaporation in milligrams per liter, dried at 180 degrees Celsius), suspended solids, major ions, nutrients, trace metals, and pesticides. Trace metal concentration data were compared to the Texas Commission on Environmental Quality established surface water quality standards for human health protection (water and fish). Among all constituents in all samples for which criteria were available for comparison, only one sample had one constituent which exceeded the surface water criteria on one occasion. A single lead concentration (2.76 micrograms per liter) measured in a filtered water sample exceeded the surface water criteria of 1.15 micrograms per liter. The average number of pesticide detections per sample in stream basins undergoing development ranged from 1.8 to 6.0. In contrast, the average number of pesticide detections per sample in the reference stream basin was 0.6. Among all constituents examined in this study, pesticides, dissolved orthophosphate phosphorus, and dissolved total phosphorus demonstrated the largest differences between the four stream basins undergoing development and the reference stream basin with

  15. Surface and Core Electronic Structure of Oxidized Silicon Nanocrystals

    Directory of Open Access Journals (Sweden)

    Noor A. Nama

    2010-01-01

    Full Text Available Ab initio restricted Hartree-Fock method within the framework of large unit cell formalism is used to simulate silicon nanocrystals between 216 and 1000 atoms (1.6–2.65 nm in diameter that include Bravais and primitive cell multiples. The investigated properties include core and oxidized surface properties. Results revealed that electronic properties converge to some limit as the size of the nanocrystal increases. Increasing the size of the core of a nanocrystal resulted in an increase of the energy gap, valence band width, and cohesive energy. The lattice constant of the core and oxidized surface parts shows a decreasing trend as the nanocrystal increases in a size that converges to 5.28 Ǻ in a good agreement with the experiment. Surface and core convergence to the same lattice constant reflects good adherence of oxide layer at the surface. The core density of states shows highly degenerate states that split at the oxygenated (001-(1×1 surface due to symmetry breaking. The nanocrystal surface shows smaller gap and higher valence and conduction bands when compared to the core part, due to oxygen surface atoms and reduced structural symmetry. The smaller surface energy gap shows that energy gap of the nanocrystal is controlled by the surface part. Unlike the core part, the surface part shows a descending energy gap that proves its obedience to quantum confinement effects. Nanocrystal geometry proved to have some influence on all electronic properties including the energy gap.

  16. Soils - Potential Runoff

    Data.gov (United States)

    Kansas Data Access and Support Center — This digital spatial data set provides information on the spatial distribution of potential runoff-contributing areas in Kansas. Potential runoff-contributing areas...

  17. Surface and Interface Physics of Correlated Electron Materials

    Energy Technology Data Exchange (ETDEWEB)

    Millis, Andrew [Columbia Univ., New York, NY (United States)

    2004-09-01

    The {\\it Surface and Interface Physics of Correlated Electron Materials} research program provided conceptual understanding of and theoretical methodologies for understanding the properties of surfaces and interfaces involving materials exhibiting strong electronic correlations. The issues addressed in this research program are important for basic science, because the behavior of correlated electron superlattices is a crucial challenge to and crucial test of our understanding of the grand-challenge problem of correlated electron physics and are important for our nation's energy future because correlated interfaces offer opportunities for the control of phenomena needed for energy and device applications. Results include new physics insights, development of new methods, and new predictions for materials properties.

  18. Enhanced Electron-Phonon Coupling at Metal Surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Plummer, Ward E.

    2010-08-04

    The Born-Oppenheimer approximation (BOA) decouples electronic from nuclear motion, providing a focal point for most quantum mechanics textbooks. However, a multitude of important chemical, physical and biological phenomena are driven by violations of this approximation. Vibronic interactions are a necessary ingredient in any process that makes or breaks a covalent bond, for example, conventional catalysis or enzymatically delivered biological reactions. Metastable phenomena associated with defects and dopants in semiconductors, oxides, and glasses entail violation of the BOA. Charge exchange in inorganic polymers, organic slats and biological systems involves charge- induced distortions of the local structure. A classic example is conventional superconductivity, which is driven by the electron-lattice interaction. High-resolution angle-resolved photoemission experiments are yielding new insight into the microscopic origin of electron-phonon coupling (EPC) in anisotropic two-dimensional systems. Our recent surface phonon measurement on the surface of a high-Tc material clearly indicates an important momentum dependent EPC in these materials. In the last few years we have shifted our research focus from solely looking at electron phonon coupling to examining the structure/functionality relationship at the surface of complex transition metal compounds. The investigation on electron phonon coupling has allowed us to move to systems where there is coupling between the lattice, the electrons and the spin.

  19. ELECTRON AVALANCHE MODEL OF DIELECTRIC-VACUUM SURFACE BREAKDOWN

    Energy Technology Data Exchange (ETDEWEB)

    Lauer, E J

    2007-02-21

    The model assumes that an 'initiating event' results in positive ions on the surface near the anode and reverses the direction of the normal component of electric field so that electrons in vacuum are attracted to the dielectric locally. A sequence of surface electron avalanches progresses in steps from the anode to the cathode. For 200 kV across 1 cm, the spacing of avalanches is predicted to be about 13 microns. The time for avalanches to step from the anode to the cathode is predicted to be about a ns.

  20. Electron Stimulated Desorption of Condensed Gases on Cryogenic Surfaces

    CERN Document Server

    Tratnik, H; Hilleret, Noël

    2005-01-01

    In ultra-high vacuum systems outgassing from vacuum chamber walls and desorption from surface adsorbates are usually the factors which in°uence pressure and residual gas composition. In particular in beam vacuum systems of accelerators like the LHC, where surfaces are exposed to intense synchro- tron radiation and bombardment by energetic ions and electrons, properties like the molecular desorption yield or secondary electron yield can strongly in°uence the performance of the accelerator. In high-energy particle accelerators operating at liquid helium temperature, cold surfaces are exposed to the bombardment of energetic photons, electrons and ions. The gases released by the subsequent desorption are re-condensed on the cold surfaces and can be re-desorbed by the impinging electrons and ions. The equilibrium coverage reached on the surfaces exposed to the impact of energetic particles depends on the desorption yield of the condensed gases and can a®ect the operation of the accelerator by modifying th...

  1. Treatment of surfaces with low-energy electrons

    Czech Academy of Sciences Publication Activity Database

    Frank, Luděk; Mikmeková, Eliška; Lejeune, M.

    2017-01-01

    Roč. 407, JUN 15 (2017), s. 105-108 ISSN 0169-4332 R&D Projects: GA TA ČR(CZ) TE01020118; GA MŠk(CZ) LO1212; GA MŠk ED0017/01/01 Institutional support: RVO:68081731 Keywords : Low-energy electrons * Electron beam induced release * Graphene * Ultimate cleaning of surfaces Subject RIV: JA - Electronics ; Optoelectronics, Electrical Engineering OBOR OECD: Nano-processes (applications on nano-scale) Impact factor: 3.387, year: 2016

  2. Project test plan for runoff and erosion on fine-soil barrier surfaces and rock-covered side slopes

    Energy Technology Data Exchange (ETDEWEB)

    Walters, W.H.; Hoover, K.A.; Cadwell, L.L.

    1990-06-01

    Pacific Northwest Laboratory (PNL) and Westinghouse Hanford Company are working together to develop protective barriers to isolate near-surface radioactive waste. The purpose of the barriers is to protect defense wastes at the US Department of Energy's (DOE) Hanford Site from infiltration of precipitation, biointrusion, and surficial erosion for up to 10,000 years without the need for long-term monitoring, maintenance, or institutional control. The barriers will be constructed of layered earth and rock material designed to direct surface and groundwater pathways away from the buried waste. To address soil erosion as it applies to barrier design and long-term stability, a task designed to study this problem has been included in the Protective Barriers Program at PNL. The barrier soil-erosion task will investigate the ability of the soil cover and side slopes to resist the erosional and destabilizing processes from externally applied water. The study will include identification and field testing of the dominant processes contributing to erosion and barrier failure. The effects of rock mulches, vegetation cover on the top fine-grained soil surface, as well as the stability of rock armoring on the side slopes, will be evaluated. Some of the testing will include the effects of animal intrusion on barrier erosion, and these will be coordinated with other animal intrusion studies. 6 refs., 4 figs., 1 tab.

  3. The powerful pulsed electron beam effect on the metallic surfaces

    International Nuclear Information System (INIS)

    Neklyudov, I.M.; Yuferov, V.B.; Kosik, N.A.; Druj, O.S.; Skibenko, E.I.

    2001-01-01

    Experimental results of the influence of powerful pulsed electron beams on the surface structure,hardness and corrosion resistance of the Cr18ni10ti steel are presented. The experiments were carried out in the powerful electron accelerators of directional effect VGIK-1 and DIN-2K with an energy up to approx 300 KeV and a power density of 10 9 - 10 11 W/cm 2 for micro- and nanosecond range. The essential influence of the irradiation power density on the material structure was established. Pulsed powerful beam action on metallic surface leads to surface melting,modification of the structure and structure-dependent material properties. The gas emission and mass-spectrometer analysis of the beam-surface interaction were defined

  4. Electronic structure of disordered alloys, surfaces and interfaces

    CERN Document Server

    Turek, Ilja; Kudrnovský, Josef; Šob, Mojmír; Weinberger, Peter

    1997-01-01

    At present, there is an increasing interest in the prediction of properties of classical and new materials such as substitutional alloys, their surfaces, and metallic or semiconductor multilayers. A detailed understanding based on a thus of the utmost importance for fu­ microscopic, parameter-free approach is ture developments in solid state physics and materials science. The interrela­ tion between electronic and structural properties at surfaces plays a key role for a microscopic understanding of phenomena as diverse as catalysis, corrosion, chemisorption and crystal growth. Remarkable progress has been made in the past 10-15 years in the understand­ ing of behavior of ideal crystals and their surfaces by relating their properties to the underlying electronic structure as determined from the first principles. Similar studies of complex systems like imperfect surfaces, interfaces, and mul­ tilayered structures seem to be accessible by now. Conventional band-structure methods, however, are of limited use ...

  5. Surface Relaxation and Electronic States of Pt(111) Surface with Varying Slab Thickness

    International Nuclear Information System (INIS)

    Kaushal, Ashok K.; Mullick, Shanta; Ahluwalia, P. K.

    2011-01-01

    Surface relaxation and electronic DOS's of Pt(111) surface have been studied with varying slab thickness using ab-initio SIESTA method. We found the expansion in the top layer and contraction in the subsurface layers of Pt(111) surface. Our results match with the experimental results. Also observing electronic density of states we found that as we increase the thickness of slab, the PDOS of Pt(111) surface goes towards the bulk density of states and Fermi energy shifts towards the bulk fermi energy.

  6. Observation of melt surface depressions during electron beam evaporation

    International Nuclear Information System (INIS)

    Ohba, Hironori; Shibata, Takemasa

    2000-08-01

    Depths of depressed surface of liquid gadolinium, cerium and copper during electron beam evaporation were measured by triangulation method using a CCD camera. The depression depths estimated from the balance of the vapor pressure and the hydrostatic pressure at the evaporation surface agreed with the measured values. The periodic fluctuation of atomic beam was observed when the depression of 3∼4 mm in depth was formed at the evaporation spot. (author)

  7. Temperature profiles on the gadolinium surface during electron beam evaporation

    International Nuclear Information System (INIS)

    Ohba, Hironori; Shibata, Takemasa

    1995-01-01

    The distributions of surface temperature of gadolinium in a water-cooled copper crucible during electron beam evaporation were measured by optical pyrometry. The surface temperatures were obtained from the radiation intensity ratio of the evaporating surface and a reference light source using Planck's law of radiation. The emitted radiation from the evaporating surface and a reference source was detected by a CCD sensor through a band pass filter of 650 nm. The measured surface temperature generally agreed with those estimated from the deposition rate and the data of the saturated vapor pressure. At high input powers, it was found that the measured value had small difference with the estimated one due to variation of the surface condition. (author)

  8. The Influence of Surface Coal Mining on Runoff Processes and Stream Chemistry in the Elk Valley, British Colubmbia, Canada

    Science.gov (United States)

    Carey, S. K.; Wellen, C. C.; Shatilla, N. J.

    2015-12-01

    Surface mining is a common method of accessing coal. In high-elevation environments, vegetation and soils are typically removed prior to the blasting of overburden rock, thereby allowing access to mineable ore. Following this, the removed overburden rock is deposited in adjacent valleys as waste rock spoils. Previous research has identified that areas downstream of surface coal mining have impaired water quality, yet there is limited information about the interaction of hydrology and geochemistry across a range of mining conditions, particularly at the headwater scale. Here, we provide an analysis of an extensive long-term data set of geochemistry and flows across a gradient of coal mining in the Elk Valley, British Columbia, Canada. This work is part of a broader R&D program examining the influence of surface coal mining on hydrological and water quality responses in the Elk Valley aimed at informing effective management responses. Results indicate that water from waste rock piles has an ionic profile distinct from unimpacted catchments. While the concentration of geochemicals increased with the degree of mine impact, the control of hydrological transport capacity over geochemical export did not vary with degree of mine impact. Geochemical export in mine-influenced catchments was limited more strongly by transport capacity than supply, implying that more water moving through the waste rock mobilized more geochemicals. Placement of waste rock within the catchment (headwaters or outlet) did not affect chemical concentrations but did alter the timing with which chemically distinct water mixed. This work advances on results reported earlier using empirical models of selenium loading and further highlights the importance of limiting water inputs into waste rock piles.

  9. Electron at the Surface of Water: Dehydrated or Not?

    Czech Academy of Sciences Publication Activity Database

    Uhlig, Frank; Maršálek, Ondřej; Jungwirth, Pavel

    2013-01-01

    Roč. 4, č. 2 (2013), s. 338-343 ISSN 1948-7185 R&D Projects: GA ČR GBP208/12/G016 Institutional support: RVO:61388963 Keywords : hydrated electron * surface solvation * ab initio molecular dynamics Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 6.687, year: 2013

  10. Assessment of root surfaces of apicected teeth: A scanning electron ...

    African Journals Online (AJOL)

    Objectives: The aim of this study was to determine the apical surface characteristics and presence of dental cracks in single‑rooted premolars, resected 3.0 mm from the root apex, using the Er: YAG laser, tungsten carbide bur, and diamond‑coated tip, by scanning electron microscopy (SEM). Experimental design: Thirty ...

  11. Electron capture by highly charged ions from surfaces and gases

    Energy Technology Data Exchange (ETDEWEB)

    Allen, F.

    2008-01-11

    In this study highly charged ions produced in Electron Beam Ion Traps are used to investigate electron capture from surfaces and gases. The experiments with gas targets focus on spectroscopic measurements of the K-shell x-rays emitted at the end of radiative cascades following electron capture into Rydberg states of Ar{sup 17+} and Ar{sup 18+} ions as a function of collision energy. The ions are extracted from an Electron Beam Ion Trap at an energy of 2 keVu{sup -1}, charge-selected and then decelerated down to 5 eVu{sup -1} for interaction with an argon gas target. For decreasing collision energies a shift to electron capture into low orbital angular momentum capture states is observed. Comparative measurements of the K-shell x-ray emission following electron capture by Ar{sup 17+} and Ar{sup 18+} ions from background gas in the trap are made and a discrepancy in the results compared with those from the extraction experiments is found. Possible explanations are discussed. For the investigation of electron capture from surfaces, highly charged ions are extracted from an Electron Beam Ion Trap at energies of 2 to 3 keVu{sup -1}, charge-selected and directed onto targets comprising arrays of nanoscale apertures in silicon nitride membranes. The highly charged ions implemented are Ar{sup 16+} and Xe{sup 44+} and the aperture targets are formed by focused ion beam drilling in combination with ion beam assisted thin film deposition, achieving hole diameters of 50 to 300 nm and aspect ratios of 1:5 to 3:2. After transport through the nanoscale apertures the ions pass through an electrostatic charge state analyzer and are detected. The percentage of electron capture from the aperture walls is found to be much lower than model predictions and the results are discussed in terms of a capillary guiding mechanism. (orig.)

  12. Studies on electronic structure of GaN(0001) surface

    CERN Document Server

    Xie Chang Kun; Xu Fa Qiang; Deng Rui; Liu Feng; Yibulaxin, K

    2002-01-01

    An electronic structure investigation on GaN(0001) is reported. The authors employ a full-potential linearized augmented plane-wave (FPLAPW) approach to calculate the partial density of state, which is in agreement with previous experimental results. The effects of the Ga3d semi-core levels on the electronic structure of GaN are discussed. The valence-electronic structure of the wurtzite GaN(0001) surface is investigated using synchrotron radiation excited angle-resolved photoemission spectroscopy. The bulk bands dispersion along GAMMA A direction in the Brillouin zones is measured using normal-emission spectra by changing photon-energy. The band structure derived from authors' experimental data is compared well with the results of authors' FPLAPW calculation. Furthermore, off-normal emission spectra are also measured along the GAMMA K and GAMMA M directions. Two surface states are identified, and their dispersions are characterized

  13. The identification of suitable areas for afforestation in order to reduce the potential for surface runoff in the upper and middle sectors of Buzãu catchment

    Directory of Open Access Journals (Sweden)

    ROMULUS COSTACHE

    2015-07-01

    Full Text Available Deforestations, besides the global climate change, are the main cause of the intensification of f loods and flash - floods in the latest years. Since surface runoff is the main phenomenon leading to floods or flash - floods, afforestation is necessary, forest coverage being the element that retains most of the water from precipitation. The study area, repr esented by the upper and middle sectors of Buzau River basin, is one of the most affected regions of Romania by torrential phenomena. Also, the study area was chosen due to its considerable deforestation. This paper proposes a methodology created exclusive ly by GIS techniques in order to identify the areas suitable for afforestation. Thus, land cover and slope relief were taken into account when running the GIS model. Database processing and obtaining the final results were possible by implementing a workfl ow in Model Builder from ArcGIS 10.3, which can be later used as a tool for other study areas. The results of the study highlight Balaneasa, Bâsca Chiojdului and Sărăţel river basins, which record the highest shares of areas suitable for afforestation.

  14. Surface hardening of AISI 4340 steel by electron beam treatment

    International Nuclear Information System (INIS)

    Wang Chienchun; Hwang Jiunren

    1994-01-01

    This paper investigates the effect of electron beam (EB) surface hardening on the abrasive wear property of AISI 4340 steel. The heat treatment conditions were varied so that the influence of microstructures on the wear resistance could be evaluated. A dry sand/rubber wheel abrasion test was selected to evaluate the high stress wear properties. The results show that the weight loss decreases with increasing hardness of surface layer or base material. The EB surface hardening can improve the abrasive wear resistance by about 10%. The best heat treatment process for AISI 4340 steel against abrasive wear is oil quenching from 840 C, tempering at 370 C, the EB surface hardening under heat input of 135-150 J mm -1 . The width and depth of the wear tracks are reduced after the EB surface hardening treatment. (orig.)

  15. An AES Study of the Room Temperature Surface Conditioning of Technological Metal Surfaces by Electron Irradiation

    OpenAIRE

    Scheuerlein, C; Hilleret, Noël; Taborelli, M; Brown, A; Baker, M A

    2002-01-01

    The modifications to technological copper and niobium surfaces induced by 2.5 keV electron irradiation have been investigated in the context of the conditioning process occurring in particle accelerator ultra high vacuum systems. Changes in the elemental surface composition have been found using Scanning Auger Microscopy (SAM) by monitoring the carbon, oxygen and metal Auger peak intensities as a function of electron irradiation in the dose range 10-6 to 10-2 C mm-2. The surface analysis resu...

  16. Assessment of climate and land use change impacts on surface water runoff and connectivity in a continuous permafrost catchment on the Arctic Coastal Plain, Alaska

    Science.gov (United States)

    Gaedeke, A.; Arp, C. D.; Liljedahl, A. K.; Daanen, R. P.; Whitman, M. S.

    2016-12-01

    A changing climate is leading to rapid transformations of hydrological processes in low-gradient Arctic terrestrial ecosystems which are dominated by lakes and ponds, wetlands, polygonised tundra, and connecting stream and river networks. The aim of this study is to gain a deeper understanding of the impacts of climate and land use change on surface water availability and connectivity by utilizing the process-based, spatially distributed hydrological model WaSiM. Crea Creek Watershed (30 km2), which is located in the National Petroleum Reserve-Alaska (NPR-A) was chosen as study area because of its permafrost landforms (bedfast and floating ice lakes, high and low centered polygons), existing observational data (discharge, snow depth, and meteorological variables since 2009), and resource management issues related to permafrost degradation and aquatic habitat dynamics. Foremost of concern is oil development scheduled to begin starting in 2017 with the construction of a permanent road and drilling pad directly within the Crea Watershed. An interdisciplinary team consisting of scientists and regional stakeholders defined the following scenarios to be simulated using WaSiM: (1) industrial development (impact of water removal from lakes (winter) for ice road construction on downstream (summer) runoff), (2) permanent road construction to allow oil companies access to develop and extract petroleum, and (3) potential modes of climate change including warmer, snowier winters and prolonged drought during summers. Downscaled meteorological output from the Weather Research & Forecasting Model (WRF) will be used as the forcing for analysis of climate scenarios alone and for assessment of land-use responses under varying climate scenarios. Our results will provide regional stakeholders with information on the impacts of climate and land use change on surface water connectivity that affects aquatic habitat, as well as lake hydrologic interactions with permafrost. These finding

  17. Dissociative electron attachment on surfaces and in bulk media

    International Nuclear Information System (INIS)

    Fabrikant, Ilya I.

    2007-01-01

    A theory of dissociative electron attachment to molecules condensed at surfaces and embedded within bulk media is developed. The theory of low-energy electron diffraction is used to obtain the width for electron-molecule resonance scattering in the condensed phase from the width for the gas phase. It is then employed for the calculation of dissociative attachment in the framework of the nonlocal complex potential theory. Specific calculations using the effective mass approximation are carried out for electron attachment to CH 3 Cl and CF 3 Cl molecules physisorbed on the surface of a Kr film. The role of image states and image-potential resonances is analyzed. The results show an increase by several orders of magnitude in the cross section for physisorbed molecules as compared with gas-phase molecules. This is in general agreement with the measured cross sections. However, the position of the peak in the cross section for CH 3 Cl is significantly shifted towards higher energies as compared to experiment [K. Nagesha et al., J. Chem. Phys. 114, 4934 (2001)], and the magnitude of the calculated cross section for CF 3 Cl at the surface is significantly higher than the measured value. Possible reasons for disagreements are analyzed

  18. Improved Analyses and Forecasts of Snowpack, Runoff and Drought through Remote Sensing and Land Surface Modeling in Southeastern Europe

    Science.gov (United States)

    Matthews, D.; Brilly, M.; Gregoric, G.; Polajnar, J.; Kobold, M.; Zagar, M.; Knoblauch, H.; Staudinger, M.; Mecklenburg, S.; Lehning, M.; Schweizer, J.; Balint, G.; Cacic, I.; Houser, P.; Pozzi, W.

    2008-12-01

    European hydrometeorological services and research centers are faced with increasing challenges from extremes of weather and climate that require significant investments in new technology and better utilization of existing human and natural resources to provide improved forecasts. Major advances in remote sensing, observation networks, data assimilation, numerical modeling, and communications continue to improve our ability to disseminate information to decision-makers and stake holders. This paper identifies gaps in current technologies, key research and decision-maker teams, and recommends means for moving forward through focused applied research and integration of results into decision support tools. This paper reports on the WaterNet - NASA Water Cycle Solutions Network contacts in Europe and summarizes progress in improving water cycle related decision-making using NASA research results. Products from the Hydrologic Sciences Branch, Goddard Space Flight Center, NASA, Land Information System's (LIS) Land Surface Models (LSM), the SPoRT, CREW , and European Space Agency (ESA), and Joint Research Center's (JRC) natural hazards products, and Swiss Federal Institute for Snow and Avalanche Research's (SLF), and others are discussed. They will be used in collaboration with the ESA and the European Commission to provide solutions for improved prediction of water supplies and stream flow, and droughts and floods, and snow avalanches in the major river basins serviced by EARS, ZAMG, SLF, Vituki Consult, and other European forecast centers. This region of Europe includes the Alps and Carpathian Mountains and is an area of extreme topography with abrupt 2000 m mountains adjacent to the Adriatic Sea. These extremes result in the highest precipitation ( > 5000 mm) in Europe in Montenegro and low precipitation of 300-400 mm at the mouth of the Danube during droughts. The current flood and drought forecasting systems have a spatial resolution of 9 km, which is currently being

  19. Low-energy electron scattering from molecules, biomolecules and surfaces

    CERN Document Server

    Carsky, Petr

    2011-01-01

    Since the turn of the 21st century, the field of electron molecule collisions has undergone a renaissance. The importance of such collisions in applications from radiation chemistry to astrochemistry has flowered, and their role in industrial processes such as plasma technology and lighting are vital to the advancement of next generation devices. Furthermore, the development of the scanning tunneling microscope highlights the role of such collisions in the condensed phase, in surface processing, and in the development of nanotechnology.Low-Energy Electron Scattering from Molecules, Biomolecule

  20. Surface Relaxations, Surface Energies and Electronic Structures of BaSnO3 (001) Surfaces: Ab Initio Calculations

    Science.gov (United States)

    Slassi, A.; Hammi, M.; El Rhazouani, O.

    2017-07-01

    The surface relaxations, surface energies and electronic structures of BaO- and SnO2-terminated BaSnO3 (001) surfaces have been studied by employing the first-principles density functional theory. For both terminations, we find that the upper-layer Ba and Sn atoms move inward, whereas upper-layer O atoms move outward from the surface. Moreover, the largest relaxations are occurred on the first-layer atoms of both terminations. The surface rumpling of BaO-terminated BaSnO3 (001) is slightly less than that of the SnO2-terminated BaSnO3 (001) surface. The surface energies show that both terminated surfaces are energetically stable and favorable. Finally, the surface band gap is slightly decreased for the BaO termination, while it is dramatically decreased for the SnO2 termination.

  1. Exchange energy of inhomogenous electron gas near a metal surface

    International Nuclear Information System (INIS)

    Miglio, L.; Tosi, M.P.; March, N.H.

    1980-12-01

    Using the first-order density matrix of an infinite-barrier model of a metal surface, the exchange energy density can be evaluated exactly as a function of distance z from the barrier. This result is compared with the local approximation -3/4e 2 (3/π)sup(1/3) rhosup(4/3)(z) where rho is the electron density in the model. The local approximation is demonstrated to be quantitatively accurate at all z. The integrated surface exchange energy is given to within 3% by the local theory. (author)

  2. Radiative capture of slow electrons by tungsten surface

    International Nuclear Information System (INIS)

    Artamonov, O.M.; Belkina, G.M.; Samarin, S.N.; Yakovlev, I.I.

    1987-01-01

    Isochromatic spectra of radiation capture of slow electrons by the surface of mono- and polycrystal tungsten recorded on 322 and 405 nm wave lengths are presented. The effect of oxygen adsorption on isochromates of the (110) face of tungsten monocrystal is investigated. The obtained isochromatic spectra are compared with energy band structure of tungsten. Based on the analysis of the obtained experimental results it is assumed that optical transition to the final state at the energy of 7.3 eV relatively to Fermi level is conditioned by surface states of the tungsten face (110)

  3. Electronic structure of epitaxial chalcopyrite surfaces and interfaces for photovoltaics

    International Nuclear Information System (INIS)

    Hofmann, Andreas

    2012-01-01

    This thesis constitutes a comprehensive study of the surface physics of epitaxial CuInSe 2 films. It comprises analyses of the surface morphology and reconstruction, electronic band structure as well as hetero-junctions relevant to photovoltaic applications. Therefore, especially the aspect of stoichiometry variation from the CuInSe 2 to the copper-deficient defect phases was considered. Preparation and analysis was completely performed under ultra-high vacuum conditions in order to ensure the investigation of well-defined samples free of contaminants. For some of the analysis techniques, single-crystalline samples are indispensable: They allow for the determination of surface periodicity by low-energy electron diffraction (LEED). In combination with concentration depth profiling by angle-resolved x-ray photoemission, to types of surface reconstructions could be distinguished for the near-stoichiometric CuInSe 2 (112) surface. In the copper-rich case, it is stabilized by Cu In anti-site defects and on the indium-rich side by 2 V Cu defects, as predicted by surface total energy calculations by Jaffe and Zunger. Both configurations correspond to a c(4 x 2) reconstruction of the zinc blende type (111) surface. For the defect compound CuIn 3 Se 5 , a sphalerite order of the surface was found, which points at a weakening or absence of the chalcopyrite order in the bulk of the material. The unusual stability of the (112) surface could also be proven by comparison with the reconstruction and surface order of (001) and (220) surfaces. The results from surface analysis were used to measure the valence band structure of the epitaxial samples by synchrotron-based angle-resolved photoelectron spectroscopy. The CuInSe 2 (001) surface gives access to the high symmetry directions Γ-T and Γ-N of momentum space. By contrasting the data obtained for the stoichiometric surface with the copper-poor defect compound, a reduction of the valence band dispersion and a broadening of

  4. Electron emission from MOS electron emitters with clean and cesium covered gold surface

    International Nuclear Information System (INIS)

    Nielsen, Gunver; Thomsen, Lasse Bjorchmar; Johansson, Martin; Hansen, Ole; Chorkendorff, Ib

    2009-01-01

    MOS (metal-oxide-semiconductor) electron emitters consisting of a Si substrate, a SiO 2 tunnel barrier and a Ti (1 nm)/Au(7 nm) top-electrode, with an active area of 1 cm 2 have been produced and studied with surface science techniques under UHV (ultra high vacuum) conditions and their emission characteristics have been investigated. It is known, that deposition of an alkali metal on the emitting surface lowers the work function and increases the emission efficiency. For increasing Cs coverages the surface has been characterized by X-ray Photoelectron Spectroscopy (XPS), Ion Scattering Spectroscopy (ISS) and work function measurements. Energy spectra of electron emission from the devices under an applied bias voltage have been recorded for the clean Au surface and for two Cs coverages and simultaneous work function curves have been obtained. The electron emission onset is seen to appear at the surface work function. A method for cleaning the ex situ deposited Au top electrodes to a degree satisfactory to surface science studies has been developed, and a threshold for oxide damage by low-energy ion exposure between 0.5 and 1 keV has been determined.

  5. Electronic structure of graphene on Ni surfaces with different orientation

    International Nuclear Information System (INIS)

    Pudikov, D.A.; Zhizhin, E.V.; Rybkin, A.G.; Rybkina, A.A.; Zhukov, Y.M.; Vilkov, O. Yu.; Shikin, A.M.

    2016-01-01

    An experimental study of the graphene, synthesized by propylene cracking on Ni surfaces with different orientation: (100) and (111), using angle-resolved photoemission, has been performed. It has been shown that graphene on Ni(111) had a perfect lateral structure due to consistency of their lattices, whereas graphene/Ni(100) consisted of a lot of domains. For both systems electronic structure was quite similar and demonstrated a strong bonding of graphene to the underlying Ni surface. After Au intercalation the electronic structure of graphene in both systems was shifted to the Fermi level and became linear in the vicinity of the K point of the Brillouin zone. - Highlights: • Graphene on Ni(111) is well-ordered, whereas on Ni(100) – multi-domain. • Graphene on Ni(111) and Ni(100) is strongly bonded with substrate. • Intercalation of Au atoms restores the linearity in dispersion and makes graphene quasi-free on both Ni(100) and Ni(111).

  6. Mass balance, meteorology, area altitude distribution, glacier-surface altitude, ice motion, terminus position, and runoff at Gulkana Glacier, Alaska, 1996 balance year

    Science.gov (United States)

    March, Rod S.

    2003-01-01

    The 1996 measured winter snow, maximum winter snow, net, and annual balances in the Gulkana Glacier Basin were evaluated on the basis of meteorological, hydrological, and glaciological data. Averaged over the glacier, the measured winter snow balance was 0.87 meter on April 18, 1996, 1.1 standard deviation below the long-term average; the maximum winter snow balance, 1.06 meters, was reached on May 28, 1996; and the net balance (from August 30, 1995, to August 24, 1996) was -0.53 meter, 0.53 standard deviation below the long-term average. The annual balance (October 1, 1995, to September 30, 1996) was -0.37 meter. Area-averaged balances were reported using both the 1967 and 1993 area altitude distributions (the numbers previously given in this abstract use the 1993 area altitude distribution). Net balance was about 25 percent less negative using the 1993 area altitude distribution than the 1967 distribution. Annual average air temperature was 0.9 degree Celsius warmer than that recorded with the analog sensor used since 1966. Total precipitation catch for the year was 0.78 meter, 0.8 standard deviations below normal. The annual average wind speed was 3.5 meters per second in the first year of measuring wind speed. Annual runoff averaged 1.50 meters over the basin, 1.0 standard deviation below the long-term average. Glacier-surface altitude and ice-motion changes measured at three index sites document seasonal ice-speed and glacier-thickness changes. Both showed a continuation of a slowing and thinning trend present in the 1990s. The glacier terminus and lower ablation area were defined for 1996 with a handheld Global Positioning System survey of 126 locations spread out over about 4 kilometers on the lower glacier margin. From 1949 to 1996, the terminus retreated about 1,650 meters for an average retreat rate of 35 meters per year.

  7. Morphology and electronic properties of silicon carbide surfaces

    Science.gov (United States)

    Nie, Shu

    2007-12-01

    Several issues related to SiC surfaces are studied in the thesis using scanning tunneling microscopy/spectroscopy (STM/S) and atomic force microscopy (AFM). Specific surfaces examined include electropolished SiC, epitaxial graphene on SiC, and vicinal (i.e. slightly miscut from a low-index direction) SiC that have been subjected to high temperature hydrogen-etching. The electropolished surfaces are meant to mimic electrochemically etched SiC, which forms a porous network. The chemical treatment of the surface is similar between electropolishing and electrochemical etching, but the etching conditions are slightly different such that the former produces a flat surface (that is amenable to STM study) whereas the latter produces a complex 3-dimensional porous network. We have used these porous SiC layers as semi-permeable membranes in a biosensor, and we find that the material is quite biocompatible. The purpose of the STM/STS study is to investigate the surface properties of the SiC on the atomic scale in an effort to explain this biocompatibility. The observed tunneling spectra are found to be very asymmetric, with a usual amount of current at positive voltages but no observable current at negative voltages. We propose that this behavior is due to surface charge accumulating on an incompletely passivated surface. Measurements on SiC surfaces prepared by various amounts of hydrogen-etching are used to support this interpretation. Comparison with tunneling computations reveals a density of about 10 13 cm-2 fixed charges on both the electro-polished and the H-etched surfaces. The relatively insulating nature observed on the electro-polished SiC surface may provide an explanation for the biocompatibility of the surface. Graphene, a monolayer of carbon, is a new material for electronic devices. Epitaxial graphene on SiC is fabricated by the Si sublimation method in which a substrate is heated up to about 1350°C in ultra-high vacuum (UHV). The formation of the graphene is

  8. Electron emission from MOS electron emitters with clean and cesium covered gold surface

    DEFF Research Database (Denmark)

    Nielsen, Gunver; Thomsen, Lasse Bjørchmar; Johansson, Martin

    2009-01-01

    MOS (metal-oxide-semiconductor) electron emitters consisting of a Si substrate, a SiO2 tunnel barrier and a Ti (1 nm)/Au(7 nm) top-electrode, with an active area of 1 cm(2) have been produced and studied with surface science techniques under UHV (ultra high vacuum) conditions and their emission...... characteristics have been investigated. It is known, that deposition of an alkali metal on the emitting surface lowers the work function and increases the emission efficiency. For increasing Cs coverages the surface has been characterized by X-ray Photoelectron Spectroscopy (XPS), Ion Scattering Spectroscopy (ISS...

  9. Atomic and electronic structure of surfaces theoretical foundations

    CERN Document Server

    Lannoo, Michel

    1991-01-01

    Surfaces and interfaces play an increasingly important role in today's solid state devices. In this book the reader is introduced, in a didactic manner, to the essential theoretical aspects of the atomic and electronic structure of surfaces and interfaces. The book does not pretend to give a complete overview of contemporary problems and methods. Instead, the authors strive to provide simple but qualitatively useful arguments that apply to a wide variety of cases. The emphasis of the book is on semiconductor surfaces and interfaces but it also includes a thorough treatment of transition metals, a general discussion of phonon dispersion curves, and examples of large computational calculations. The exercises accompanying every chapter will be of great benefit to the student.

  10. Electronic properties of semiconductor surfaces and metal/semiconductor interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Tallarida, M.

    2005-05-15

    This thesis reports investigations of the electronic properties of a semiconductor surface (silicon carbide), a reactive metal/semiconductor interface (manganese/silicon) and a non-reactive metal/semiconductor interface (aluminum-magnesium alloy/silicon). The (2 x 1) reconstruction of the 6H-SiC(0001) surface has been obtained by cleaving the sample along the (0001) direction. This reconstruction has not been observed up to now for this compound, and has been compared with those of similar elemental semiconductors of the fourth group of the periodic table. This comparison has been carried out by making use of photoemission spectroscopy, analyzing the core level shifts of both Si 2p and C 1s core levels in terms of charge transfer between atoms of both elements and in different chemical environments. From this comparison, a difference between the reconstruction on the Si-terminated and the C-terminated surface was established, due to the ionic nature of the Si-C bond. The growth of manganese films on Si(111) in the 1-5 ML thickness range has been studied by means of LEED, STM and photoemission spectroscopy. By the complementary use of these surface science techniques, two different phases have been observed for two thickness regimes (<1 ML and >1 ML), which exhibit a different electronic character. The two reconstructions, the (1 x 1)-phase and the ({radical}3 x {radical}3)R30 -phase, are due to silicide formation, as observed in core level spectroscopy. The growth proceeds via island formation in the monolayer regime, while the thicker films show flat layers interrupted by deep holes. On the basis of STM investigations, this growth mode has been attributed to strain due to lattice mismatch between the substrate and the silicide. Co-deposition of Al and Mg onto a Si(111) substrate at low temperature (100K) resulted in the formation of thin alloy films. By varying the relative content of both elements, the thin films exhibited different electronic properties

  11. Hydrogen collisions with transition metal surfaces: Universal electronically nonadiabatic adsorption

    Science.gov (United States)

    Dorenkamp, Yvonne; Jiang, Hongyan; Köckert, Hansjochen; Hertl, Nils; Kammler, Marvin; Janke, Svenja M.; Kandratsenka, Alexander; Wodtke, Alec M.; Bünermann, Oliver

    2018-01-01

    Inelastic scattering of H and D atoms from the (111) surfaces of six fcc transition metals (Au, Pt, Ag, Pd, Cu, and Ni) was investigated, and in each case, excitation of electron-hole pairs dominates the inelasticity. The results are very similar for all six metals. Differences in the average kinetic energy losses between metals can mainly be attributed to different efficiencies in the coupling to phonons due to the different masses of the metal atoms. The experimental observations can be reproduced by molecular dynamics simulations based on full-dimensional potential energy surfaces and including electronic excitations by using electronic friction in the local density friction approximation. The determining factors for the energy loss are the electron density at the surface, which is similar for all six metals, and the mass ratio between the impinging atoms and the surface atoms. Details of the electronic structure of the metal do not play a significant role. The experimentally validated simulations are used to explore sticking over a wide range of incidence conditions. We find that the sticking probability increases for H and D collisions near normal incidence—consistent with a previously reported penetration-resurfacing mechanism. The sticking probability for H or D on any of these metals may be represented as a simple function of the incidence energy, Ein, metal atom mass, M, and incidence angle, 𝜗i n. S =(S0+a ṡEi n+b ṡM ) *(1 -h (𝜗i n-c ) (1 -cos(𝜗 i n-c ) d ṡh (Ei n-e ) (Ei n-e ) ) ) , where h is the Heaviside step function and for H, S0 = 1.081, a = -0.125 eV-1, b =-8.40 ṡ1 0-4 u-1, c = 28.88°, d = 1.166 eV-1, and e = 0.442 eV; whereas for D, S0 = 1.120, a = -0.124 eV-1, b =-1.20 ṡ1 0-3 u-1, c = 28.62°, d = 1.196 eV-1, and e = 0.474 eV.

  12. Relation between surface crystallography and surface electron structure of the superlattice

    Czech Academy of Sciences Publication Activity Database

    Bartoš, Igor; Strasser, T.; Schattke, W.

    2003-01-01

    Roč. 10, 2&3 (2003), s. 195-199 ISSN 0218-625X R&D Projects: GA AV ČR IAA1010108 Institutional research plan: CEZ:AV0Z1010914 Keywords : surface electron structure * superlattices * one-step photoemission Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 0.586, year: 2003

  13. Stereoscopic and photometric surface reconstruction in scanning electron microscopy

    International Nuclear Information System (INIS)

    Scherer, S.

    2000-01-01

    The scanning electron microscope (SEM) is one of the most important devices to examine microscopic structures as it offers images of a high contrast range with a large depth of focus. Nevertheless, three-dimensional measurements, as desired in fracture mechanics, have previously not been accomplished. This work presents a system for automatic, robust and dense surface reconstruction in scanning electron microscopy combining new approaches in shape from stereo and shape from photometric stereo. The basic theoretical assumption for a known adaptive window algorithm is shown not to hold in scanning electron microscopy. A constraint derived from this observation yields a new, simplified, hence faster calculation of the adaptive window. The correlation measure itself is obtained by a new ordinal measure coefficient. Shape from photometric stereo in the SEM is formulated by relating the image formation process with conventional photography. An iterative photometric ratio reconstruction is invented based on photometric ratios of backscatter electron images. The performance of the proposed system is evaluated using ground truth data obtained by three alternative shape recovery devices. Most experiments showed relative height accuracy within the tolerances of the alternative devices. (author)

  14. Risk assessment of pesticide runoff from turf.

    Science.gov (United States)

    Haith, Douglas A; Rossi, Frank S

    2003-01-01

    The TurfPQ model was used to simulate the runoff of 15 pesticides commonly applied to creeping bentgrass (Agrostis stolonifera L.) fairways and greens on golf courses in the northeastern USA. Simulations produced 100-yr daily records of water runoff, pesticide runoff, and pesticide concentration in runoff for three locations: Boston, MA, Philadelphia, PA, and Rochester, NY. Results were summarized as annual and monthly means and annual maximum daily loads (AMDLs) corresponding to 10- and 20-yr return periods. Mean annual pesticide runoff loads did not exceed 3% of annual applications for any pesticide or site, and most losses were substantially less than 1% of application. However, annual or monthly mean concentrations of chlorothalonil, iprodione, and PCNB in fairway runoff often exceeded concentrations that result in 50% mortality of the affected species (LC50) for aquatic organisms. Concentrations of azoxystrobin, bensulide, cyfluthrin, and trichlorfon in extreme (1 in 10 yr or 1 in 20 yr) events often approached or exceeded LC50 levels. Concentrations of halofenozide, mancozeb, MCPP, oxadiazon, propiconazole, thiophanate-methyl, triadimefon, and trinexapac-ethyl were well below LC50 levels, and turf runoff of these chemicals does not appear to be hazardous to aquatic life in surface waters.

  15. Electronic structure of benzene adsorbed on Ni and Cu surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Weinelt, M.; Nilsson, A.; Wassdahl, N. [Uppsala Univ. (Sweden)] [and others

    1997-04-01

    Benzene has for a long time served as a prototype adsorption system of large molecules. It adsorbs with the molecular plane parallel to the surface. The bonding of benzene to a transition metal is typically viewed to involve the {pi} system. Benzene adsorbs weakly on Cu and strongly on Ni. It is interesting to study how the adsorption strength is reflected in the electronic structure of the adsorbate-substrate complex. The authors have used X-ray Emission (XE) and X-ray Absorption (XA) spectroscopies to selectively study the electronic states localized on the adsorbed benzene molecule. Using XES the occupied states can be studies and with XAS the unoccupied states. The authors have used beamline 8.0 and the Swedish endstation equipped with a grazing incidence x-ray spectrometer and a partial yield absorption detector. The resolution in the XES and XAS were 0.5 eV and 0.05 eV, respectively.

  16. Electron Scattering at Surfaces of Epitaxial Metal Layers

    Science.gov (United States)

    Chawla, Jasmeet Singh

    In the field of electron transport in metal films and wires, the 'size effect' refers to the increase in the resistivity of the films and wires as their critical dimensions (thickness of film, width and height of wires) approach or become less than the electron mean free path lambda, which is, for example, 39 nm for bulk copper at room temperature. This size-effect is currently of great concern to the semiconductor industry because the continued downscaling of feature sizes has already lead to Cu interconnect wires in this size effect regime, with a reported 2.5 times higher resistivity for 40 nm wide Cu wires than for bulk Cu. Silver is a possible alternate material for interconnect wires and titanium nitride is proposed as a gate metal in novel field-effect-transistors. Therefore, it is important to develop an understanding of how the growth, the surface morphology, and the microstructure of ultrathin (few nanometers) Cu, Ag and TiN layers affect their electrical properties. This dissertation aims to advance the scientific knowledge of electron scattering at surfaces (external surfaces and grain boundaries), that are, the primary reasons for the size-effect in metal conductors. The effect of surface and grain boundary scattering on the resistivity of Cu thin films and nanowires is separately quantified using (i) in situ transport measurements on single-crystal, atomically smooth Cu(001) layers, (ii) textured polycrystalline Cu(111) layers and patterned wires with independently varying grain size, thickness and line width, and (iii) in situ grown interfaces including Cu-Ta, Cu-MgO, Cu-vacuum and Cu-oxygen. In addition, the electron surface scattering is also measured in situ for single-crystal Ag(001), (111) twinned epitaxial Ag(001), and single-crystal TiN(001) layers. Cu(001), Ag(001), and TiN(001) layers with a minimum continuous thickness of 4, 3.5 and 1.8 nm, respectively, are grown by ultra-high vacuum magnetron sputter deposition on MgO(001) substrates with

  17. Extremely confined gap surface-plasmon modes excited by electrons

    DEFF Research Database (Denmark)

    Raza, Søren; Stenger, Nicolas; Pors, Anders Lambertus

    2014-01-01

    EELS to ultra-sharp convex grooves in gold, we directly probe extremely confined gap surface-plasmon (GSP) modes excited by swift electrons in nanometre-wide gaps. We reveal the resonance behaviour associated with the excitation of the antisymmetric GSP mode for extremely small gap widths, down to ~5...... nm. We argue that excitation of this mode, featuring very strong absorption, has a crucial role in experimental realizations of non-resonant light absorption by ultra-sharp convex grooves with fabrication-induced asymmetry. The occurrence of the antisymmetric GSP mode along with the fundamental GSP...

  18. Metals: Phonon states, electron states and Fermi surfaces. Subvolume a

    International Nuclear Information System (INIS)

    Dederichs, P.H.; Schober, H.; Sellmyer, D.J.

    1981-01-01

    This collection of tables and diagrams is the first contribution to a larger programme aiming at a complete and critical tabulation of reliable data relevant to metal physics. No such complete collection exists at present, and these tables should fill a long felt need of both experimentalists and theoreticians. Group III in the New Series of the Landolt-Boernstein tables deals with Crystal and Solid State Physics. Volume III/13 to which this subvolume 13a belongs will cover all data published up to 1980 on phonon and electron states and Fermi surfaces in metals. Both experimental and theoretical results are included. (orig./WL)

  19. Electronic-state control of amino acids on semiconductor surfaces

    International Nuclear Information System (INIS)

    Oda, Masato; Nakayama, Takashi

    2005-01-01

    Electronic structures of amino acids on the Si(1 1 1) surfaces are investigated by using ab initio Hartree-Fock calculations. It is shown that among various polar amino acids, a histidine is the only one that can be positively ionized when hole carriers are supplied in the Si substrate, by transferring the hole charge from Si substrate to an amino acid. This result indicates that the ionization of a histidine, which will activate the protein functions, can be controlled electrically by producing amino acid/Si junctions

  20. Electromagnetic surface waves at the interface of a relativistic electron beam with vacuum

    International Nuclear Information System (INIS)

    Shoucri, M.M.; Gagne, R.R.J.

    1977-01-01

    The dispersion relation for electromagnetic surface waves propagating at the interface between a relativistic electron beam and vacuum is derived. The excitation of surface modes in a plasma at rest by a relativistic electron beam is discussed

  1. Coupling Modified Linear Spectral Mixture Analysis and Soil Conservation Service Curve Number (SCS-CN Models to Simulate Surface Runoff: Application to the Main Urban Area of Guangzhou, China

    Directory of Open Access Journals (Sweden)

    Jianhui Xu

    2016-11-01

    Full Text Available Land surface characteristics, including soil type, terrain slope, and antecedent soil moisture, have significant impacts on surface runoff during heavy precipitation in highly urbanized areas. In this study, a Linear Spectral Mixture Analysis (LSMA method is modified to extract high-precision impervious surface, vegetation, and soil fractions. In the modified LSMA method, the representative endmembers are first selected by combining a high-resolution image from Google Earth; the unmixing results of the LSMA are then post-processed to reduce errors of misclassification with Normalized Difference Built-up Index (NDBI and Normalized Difference Vegetation Index (NDVI. The modified LSMA is applied to the Landsat 8 Operational Land Imager (OLI image from 18 October 2015 of the main urban area of Guangzhou city. The experimental result indicates that the modified LSMA shows improved extraction performance compared with the conventional LSMA, as it can significantly reduce the bias and root-mean-square error (RMSE. The improved impervious surface, vegetation, and soil fractions are used to calculate the composite curve number (CN for each pixel according to the Soil Conservation Service curve number (SCS-CN model. The composite CN is then adjusted with regional data of the terrain slope and total 5-day antecedent precipitation. Finally, the surface runoff is simulated with the SCS-CN model by combining the adjusted CN and real precipitation data at 1 p.m., 4 May 2015.

  2. The secondary electron yield of noble metal surfaces

    Science.gov (United States)

    Gonzalez, L. A.; Angelucci, M.; Larciprete, R.; Cimino, R.

    2017-11-01

    Secondary electron yield (SEY) curves in the 0-1000 eV range were measured on polycrystalline Ag, Au and Cu samples. The metals were examined as introduced in the ultra-high vacuum chamber and after having been cleaned by Ar+ ion sputtering. The comparison between the curves measured on the clean samples and in the presence of contaminants, due to the permanence in atmosphere, confirmed that the SEY behavior is strongly influenced by the chemical state of the metal surface. We show that when using very slow primary electrons the sample work function can be determined with high accuracy from the SEY curves. Moreover we prove that SEY is highly sensitive to the presence of adsorbates even at submonolayer coverage. Results showing the effect of small quantities of CO adsorbed on copper are presented. Our findings demonstrate that SEY, besides being an indispensable mean to qualify technical materials in many technological fields, can be also used as a flexible and advantageous diagnostics to probe surfaces and interfaces.

  3. The secondary electron yield of noble metal surfaces

    Directory of Open Access Journals (Sweden)

    L. A. Gonzalez

    2017-11-01

    Full Text Available Secondary electron yield (SEY curves in the 0-1000 eV range were measured on polycrystalline Ag, Au and Cu samples. The metals were examined as introduced in the ultra-high vacuum chamber and after having been cleaned by Ar+ ion sputtering. The comparison between the curves measured on the clean samples and in the presence of contaminants, due to the permanence in atmosphere, confirmed that the SEY behavior is strongly influenced by the chemical state of the metal surface. We show that when using very slow primary electrons the sample work function can be determined with high accuracy from the SEY curves. Moreover we prove that SEY is highly sensitive to the presence of adsorbates even at submonolayer coverage. Results showing the effect of small quantities of CO adsorbed on copper are presented. Our findings demonstrate that SEY, besides being an indispensable mean to qualify technical materials in many technological fields, can be also used as a flexible and advantageous diagnostics to probe surfaces and interfaces.

  4. Recent advances in ion and electron spectroscopy of polymer surfaces

    Science.gov (United States)

    Gardella, Joseph A.

    1988-01-01

    The structure of microdomains and bonding at multicomponent polymer material interfaces has been studied using a variety of surface sensitive spectroscopic techniques. In our laboratory, low energy ion scattering spectroscopy (ISS) and static secondary ion mass spectrometry (SIMS) serve to complement results from angular dependent X-ray photoelectron spectroscopy (XPS or ESCA), Fourier transform infrared (FTIR) with attenuated total reflectance (ATR) sampling and SEM techniques to provide a quantitative picture of the relationships between structure, bonding, morphology and microdomain formation in near surface regions of polymeric systems. The added surface sensitivity of ISS can yield quantitative information at a sampling depth of 3-5 Å, which, with ESCA and FTIR analysis yields a "non-destructive" depth profile of domain formation in copolymer and blend systems. These studies will be illustrated with results from siloxane and siloxane/polycarbonate copolymer systems, where a complete picture of surface domain formation and morphology as a function of composition and polymer crystallinity has been developed. ISS can also yield information regarding the orientation of surface functional groups which ESCA and FTIR do not have either sensitivity and/or sufficient detection limits to analyze. These studies will be illustrated by the analysis of plasma hydrolysis/oxidation of stereoregular poly(methyl-methacrylate). The effects of functional group orientation on reactivity will be explored using results from ISS, ESCA and FTIR for stereoregular (isotatic, syndiotactic) and random (atactic) PMMA. Electron energy loss spectroscopy at high resolution (HREELS) has recently been extended to the examination of polymer and organic surfaces. Vibrational information from this experiment can yield very precise results about surface functional groups (1-20 Å) but at much lower resolution than is typical from IR and Raman techniques. However, the promise of evaluating surface

  5. Effects of earthworms on slopewash, surface runoff, and fine-litter transport on a humid-tropical forested hillslope in eastern Puerto Rico: Chapter G in Water quality and landscape processes of four watersheds in eastern Puerto Rico

    Science.gov (United States)

    Larsen, Matthew C.; Liu, Zhigang Liu; Zou, Xiaoming; Murphy, Sheila F.; Stallard, Robert F.

    2012-01-01

    Rainfall, slopewash (the erosion of soil particles), surface runoff, and fine-litter transport were measured in tropical wet forest on a hillslope in the Luquillo Experimental Forest, Puerto Rico, from February 1998 until April 2000. Slopewash data were collected using Gerlach troughs at eight plots, each 2 square meters in area. Earthworms were excluded by electroshocking from four randomly selected plots. The other four (control) plots were undisturbed. During the experiment, earthworm population in the electroshocked plots was reduced by 91 percent. At the end of the experiment, the electroshocked plots had 13 percent of earthworms by count and 6 percent by biomass as compared with the control plots. Rainfall during the sampling period (793 days) was 9,143 millimeters. Mean and maximum rainfall by sampling period (mean of 16 days) were 189 and 563 millimeters, respectively. Surface runoff averaged 0.6 millimeters and 1.2 millimeters by sampling period for the control and experimental plots, equal to 0.25 and 0.48 percent of mean rainfall, respectively. Disturbance of the soil environment by removal of earthworms doubled runoff and increased the transport (erosion) of soil and organic material by a factor of 4.4. When earthworms were removed, the erosion of mineral soil (soil mass left after ashing) and the transport of fine litter were increased by a factor of 5.3 and 3.4, respectively. It is assumed that increased runoff is a function of reduced soil porosity, resulting from decreased burrowing and reworking of the soil in the absence of earthworms. The background, or undisturbed, downslope transport of soil, as determined from the control plots, was 51 kilograms per hectare and the "disturbance" rate, determined from the experimental plots, was 261 kilograms per hectare. The background rate for downslope transport of fine litter was 71 kilograms per hectare and the disturbance rate was 246 kilograms per hectare. Data from this study indicate that the reduction

  6. Mobility and bioavailability of Cd, Co, Cr, Cu, Mn and Zn in surface runoff sediments in the urban catchment area of Guwahati, India

    Science.gov (United States)

    Devi, Upama; Bhattacharyya, Krishna G.

    2018-03-01

    The sediments in stormwater runoff are recognised as the major sink of the heavy metals and affect the soil quality in the catchment. The runoff sediments are also important in the management of contaminant transport to receiving water bodies. In the present work, stormwater during several major rain events was collected from nine principal locations of Guwahati, India. The solid phase was separated from the liquid phase and was investigated for the total contents of Cd, Co, Cr, Cu, Mn and Zn as well as their distribution among the prominent chemical phases. Sequential extraction procedure was used for the chemical fractionation of the metals that contains five steps. The total metal concentration showed the trend, Cd mobile and high-risk fractions. Co with medium mobility was also found to be in the high-risk category. On the other hand, the mobilities of Cu and Zn were relatively low and these were, therefore, the least bioavailable metals in the runoff sediments falling in medium-risk category.

  7. Optimization of Land Use Pattern Reduces Surface Runoff and Sediment Loss in a Hilly-Gully Watershed at the Loess Plateau, China

    Directory of Open Access Journals (Sweden)

    Han Yini

    2016-04-01

    Full Text Available Aim of study: The aim is to find a way increasing gain yield and lessen area of farmland, and then increasing vegetation cover, improving environment and alleviating soil erosion.Area of study: The Hilly-Gully region at the loess plateau of China.Material and methods: In this study, an adjusted and optimized land use pattern was developed in Luoyugou watershed in the Yellow River valley based on the gradient distribution of land use types, and its effect on water and sediment transport was simulated using the SWAT model and GIS, with remote sensing images, land use maps and hydrologic data.Main results: The results indicate: average simulated runoff and sediment for the period 1986-2000 under conditions of the three land use pattern (2011, 2008 and optimized land use reduced by 0.002-0.013 m3/s (2.7-17.6% and 0.66 million tons, respectively. The runoff and sediment data obtained were compared with observed data from 2008, which showed that runoff and sediment production would be reduced by 467625 m3 and 22754 tons, respectively.Research highlights: The adjustment of the land use pattern in comprehensive consideration of vegetation and geography have a positive effect on water and sediment transport which will be important for decision making and water resources management, and provides a reference for future environmental management and ecological construction in the loess plateau Hilly-Gully region. 

  8. Optimization of Land Use Pattern Reduces Surface Runoff and Sediment Loss in a Hilly-Gully Watershed at the Loess Plateau, China

    Energy Technology Data Exchange (ETDEWEB)

    Yini, H.; Jianzhi, N.; Zhongbao, X.; Wei, Z.; Tielin, Z.; Xilin, W.; Yousong, Z.

    2016-07-01

    Aim of study: The aim is to find a way increasing gain yield and lessen area of farmland, and then increasing vegetation cover, improving environment and alleviating soil erosion. Area of study: The Hilly-Gully region at the loess plateau of China. Material and methods: In this study, an adjusted and optimized land use pattern was developed in Luoyugou watershed in the Yellow River valley based on the gradient distribution of land use types, and its effect on water and sediment transport was simulated using the SWAT model and GIS, with remote sensing images, land use maps and hydrologic data. Main results: The results indicate: average simulated runoff and sediment for the period 1986-2000 under conditions of the three land use pattern (2011, 2008 and optimized land use) reduced by 0.002-0.013 m3/s (2.7-17.6%) and 0.66 million tons, respectively. The runoff and sediment data obtained were compared with observed data from 2008, which showed that runoff and sediment production would be reduced by 467625 m3 and 22754 tons, respectively. Research highlights: The adjustment of the land use pattern in comprehensive consideration of vegetation and geography have a positive effect on water and sediment transport which will be important for decision making and water resources management, and provides a reference for future environmental management and ecological construction in the loess plateau Hilly-Gully region. (Author)

  9. Interactions between surface runoff, hydro sediments and radionuclides (210Pb, 226Ra, 228Ra, Th e U) at Alto Ribeirão das Antas, Poços de Caldas, MG, Brazil

    International Nuclear Information System (INIS)

    Moreira, Flavio Henrique de Souza

    2017-01-01

    Knowledge about hydrological and sedimentological dynamics of a river basin is fundamental to the adequate management of water resources, and it can support the identification of contaminants in the water, the estimation of water erosion, the estimation of reservoir siltation, and even the reduction of water treatment costs. The study carried out in Alto Ribeirão das Antas River Basin assessed, throughout seasons, all interactions between the surface runoff and the transport of suspended and underwater hydro-sediments, through direct monitoring of two sites at the Ribeirão das Antas channel. Concurrently, the potential of the indirect monitoring of suspended solids concentration was evaluated using an optical turbidity sensor. The hydrological results point to a high precipitation in the region, however with a well balanced distribution among the humid months, allowing the basin’s high capacity to transform precipitation into surface runoff. Sediment transport rates characterize the studied area as a low sediment production region. The sedimentological regime was found to be in accordance with the surface runoff regime, reflected by the seasonality of the transported masses. The estimation of transport of sediment in suspension through optical turbidity sensor presented promising results. Most of the results of radionuclides 210 Pb, 226 Ra, 228 Ra, Th and U observed in water and in suspended hydro-sediment were below the detection limit of the methodology, whereas in the riverbed hydro-sediments quantification of radionuclides was possible. The radiometric results indicate absence of radionuclide carriage from the Águas Claras Dam at INB Caldas to Ribeirão das Antas. The low concentration values of radioactive elements observed in the study may be of natural origin, once the Poços de Caldas Plateau region presents a geological constitution endowed with anomalies associated to radionuclides. (author)

  10. Fine Structure in the Secondary Electron Emission Peak for Diamond Crystal with (100) Negative Electron Affinity Surface

    Science.gov (United States)

    Asnin, V. M.; Krainsky, I. L.

    1998-01-01

    A fine structure was discovered in the low-energy peak of the secondary electron emission spectra of the diamond surface with negative electron affinity. We studied this structure for the (100) surface of the natural type-IIb diamond crystal. We have found that the low-energy peak consists of a total of four maxima. The relative energy positions of three of them could be related to the electron energy minima near the bottom of the conduction band. The fourth peak, having the lowest energy, was attributed to the breakup of the bulk exciton at the surface during the process of secondary electron emission.

  11. Holey buckets! Monitoring plot-scale runoff

    Science.gov (United States)

    Rupp, D. E.; Stewart, R. D.; Abou Najm, M. R.; Selker, J. S.; Selker, F.; Van De Giesen, N.

    2011-12-01

    Measurement of plot-scale surface runoff is commonly achieved by diverting flow through a flume or tipping bucket system, or into a storage tank, such as bucket. The principle advantages of the "bucket method" are relative simplicity and low cost. The principle drawback is that the bucket requires frequent emptying during heavy runoff, unless the bucket volume is very large. As a solution to the problem of emptying the bucket while still retaining the properties of simplicity and economy, we used a holey bucket. Our "bucket" is vertical 4"-diameter ABS pipe, sealed at the bottom, and with holes along the side of the pipe. A screen in the pipe catches debris that could block the holes. The holes' diameters and locations were chosen to capture both low (100 L min-1) flows. Runoff is diverted into the top of the pipe. The runoff rate is determined from the water level and the rate of change in water level: the water level gives the flow rate out of the submerged holes (using Torricelli's Law) and the change in water level gives the rate of change in storage in the pipe. The runoff is calculated as the sum of the hole discharge and the rate of change in storage. A calibration parameter is applied to account for departures from assumptions of the theory. The design is currently being utilized to monitor runoff from experimental plots on a rural hillslope in Chile.

  12. Rivers, runoff, and reefs

    Science.gov (United States)

    McLaughlin, C.J.; Smith, C.A.; Buddemeier, R.W.; Bartley, J.D.; Maxwell, B.A.

    2003-01-01

    The role of terrigenous sediment in controlling the occurrence of coral reef ecosystems is qualitatively understood and has been studied at local scales, but has not been systematically evaluated on a global-to-regional scale. Current concerns about degradation of reef environments and alteration of the hydrologic and sediment cycles place the issue at a focal point of multiple environmental concerns. We use a geospatial clustering of a coastal zone database of river and local runoff identified with 0.5?? grid cells to identify areas of high potential runoff effects, and combine this with a database of reported coral reef locations. Coastal cells with high runoff values are much less likely to contain reefs than low runoff cells and GIS buffer analysis demonstrates that this inhibition extends to offshore ocean cells as well. This analysis does not uniquely define the effects of sediment, since salinity, nutrients, and contaminants are potentially confounding variables also associated with runoff. However, sediment effects are likely to be a major factor and a basis is provided for extending the study to higher resolution with more specific variables. ?? 2003 Elsevier B.V. All rights reserved.

  13. Electronic Noses for Composites Surface Contamination Detection in Aerospace Industry.

    Science.gov (United States)

    Vito, Saverio De; Miglietta, Maria Lucia; Massera, Ettore; Fattoruso, Grazia; Formisano, Fabrizio; Polichetti, Tiziana; Salvato, Maria; Alfano, Brigida; Esposito, Elena; Francia, Girolamo Di

    2017-04-02

    The full exploitation of Composite Fiber Reinforced Polymers (CFRP) in so-called green aircrafts design is still limited by the lack of adequate quality assurance procedures for checking the adhesive bonding assembly, especially in load-critical primary structures. In this respect, contamination of the CFRP panel surface is of significant concern since it may severely affect the bonding and the mechanical properties of the joint. During the last years, the authors have developed and tested an electronic nose as a non-destructive tool for pre-bonding surface inspection for contaminants detection, identification and quantification. Several sensors and sampling architectures have been screened in view of the high Technology Readiness Level (TRL) scenarios requirements. Ad-hoc pattern recognition systems have also been devised to ensure a fast and reliable assessment of the contamination status, by combining real time classifiers and the implementation of a suitable rejection option. Results show that e-noses could be used as first line low cost Non Destructive Test (NDT) tool in aerospace CFRP assembly and maintenance scenarios.

  14. Target surface area effects on hot electron dynamics from high intensity laser-plasma interactions

    Science.gov (United States)

    Zulick, C.; Raymond, A.; McKelvey, A.; Chvykov, V.; Maksimchuk, A.; Thomas, A. G. R.; Willingale, L.; Yanovsky, V.; Krushelnick, K.

    2016-06-01

    Reduced surface area targets were studied using an ultra-high intensity femtosecond laser in order to determine the effect of electron sheath field confinement on electron dynamics. X-ray emission due to energetic electrons was imaged using a {K}α imaging crystal. Electrons were observed to travel along the surface of wire targets, and were slowed mainly by the induced fields. Targets with reduced surface areas were correlated with increased hot electron densities and proton energies. Hybrid Vlasov-Fokker-Planck simulations demonstrated increased electric sheath field strength in reduced surface area targets.

  15. Possible correlation effects of surface state electrons on a solid hydrogen film

    NARCIS (Netherlands)

    Mugele, Friedrich Gunther; Albrecht, Uwe; Leiderer, Paul; Kono, Kimitoshi

    1992-01-01

    We have investigated the transport properties of surface state electrons on thin quench-condensed hydrogen films for various electron densities. The surface state electron mobility showed a continuous dependence on the plasma parameter Gamma in the range from 20 to 130, indicating a strong influence

  16. Climatic Models Ensemble-based Mid-21st Century Runoff Projections: A Bayesian Framework

    Science.gov (United States)

    Achieng, K. O.; Zhu, J.

    2017-12-01

    There are a number of North American Regional Climate Change Assessment Program (NARCCAP) climatic models that have been used to project surface runoff in the mid-21st century. Statistical model selection techniques are often used to select the model that best fits data. However, model selection techniques often lead to different conclusions. In this study, ten models are averaged in Bayesian paradigm to project runoff. Bayesian Model Averaging (BMA) is used to project and identify effect of model uncertainty on future runoff projections. Baseflow separation - a two-digital filter which is also called Eckhardt filter - is used to separate USGS streamflow (total runoff) into two components: baseflow and surface runoff. We use this surface runoff as the a priori runoff when conducting BMA of runoff simulated from the ten RCM models. The primary objective of this study is to evaluate how well RCM multi-model ensembles simulate surface runoff, in a Bayesian framework. Specifically, we investigate and discuss the following questions: How well do ten RCM models ensemble jointly simulate surface runoff by averaging over all the models using BMA, given a priori surface runoff? What are the effects of model uncertainty on surface runoff simulation?

  17. Phosphorus loss by surface runoff in no-till system under mineral and organic fertilization Perda de fósforo via escoamento superficial no sistema plantio direto sob adubação mineral e orgânica

    Directory of Open Access Journals (Sweden)

    Oromar João Bertol

    2010-02-01

    Full Text Available The no-till system has been intensively used in the state of Paraná, Brazil, and it has increased the nutrients level at the soil surface. This has contributed for nutrient losses via runoff and consequently, off-site water pollution. The objective of this study was to evaluate phosphorus loss in surface runoff by simulated rainfall on an Oxisol, under no-till system following application of mineral fertilizer and liquid swine manure. Nitrogen, soil and water losses from the same study are reported in a separated paper. The application of liquid swine manure, compared with mineral fertilization, increased runoff concentration of total P, particulate P and dissolved reactive P by 193%, 111% and 506%, respectively, averaged for all rainfall intensities. Independently on the fertilizer source, the highest rainfall intensity provided the greatest concentration and loads of P in runoff.O sistema plantio direto tem sito intensivamente utilizado no Estado do Paraná Brasil o qual tem aumentado os níveis de nutrientes na superfície do solo. Isto tem contribuído para a perda de nutrientes via escoamento superficial e consequentemente com a poluição não pontual das águas. Avaliou-se a perda de fósforo via escoamento superficial ocasionado por chuva simulada sobre um Latossolo originário de basalto, em sistema plantio direto submetido à aplicação de fertilizante mineral e dejeto líquido de suíno. As perdas de nitrogênio, solo e água deste mesmo estudo foram publicadas em outro artigo. A aplicação de dejeto líquido suíno, comparado com o fertilizante mineral, aumentou a concentração de P total, P particulado e P dissolvido reativo em 193%, 111% e 506%, respectivamente, na média das chuvas. Independentemente da fonte de fertilizante, a chuva de maior intensidade proporcionou maior concentração e quantidade perdida de P no escoamento superficial.

  18. Electronic Structure of the Perylene / Zinc Oxide Interface: A Computational Study of Photoinduced Electron Transfer and Impact of Surface Defects

    KAUST Repository

    Li, Jingrui

    2015-07-29

    The electronic properties of dye-sensitized semiconductor surfaces consisting of pery- lene chromophores chemisorbed on zinc oxide via different spacer-anchor groups, have been studied at the density-functional-theory level. The energy distributions of the donor states and the rates of photoinduced electron transfer from dye to surface are predicted. We evaluate in particular the impact of saturated versus unsaturated aliphatic spacer groups inserted between the perylene chromophore and the semiconductor as well as the influence of surface defects on the electron-injection rates.

  19. Influence of surface topography on elastically backscattered electrons

    International Nuclear Information System (INIS)

    Ding, X; Da, B; Gong, J B; Ding, Z J; Mao, S F

    2014-01-01

    A Monte Carlo simulation, taking into account of the detailed surface roughness of a realistic solid sample, has been performed to study the surface topography influence on elastic peak intensity. To describe quantitatively the surface topography effect, here we introduce surface roughness parameter (SRP) according to the ratio of elastic peak intensities between a rough surface and an ideal planar surface. Simulation results for Al sample have shown that SRP varies with surface roughness particularly at large incidence/emission angles

  20. Runoff modeling of the Mara River using satellite observed soil ...

    African Journals Online (AJOL)

    The model is developed based on the relationships found between satellite observed soil moisture and rainfall and the measured runoff. It uses the satellite observed rainfall as the prime forcing, and the soil moisture to separate the fast surface runoff and slow base flow contributions. The soil moisture and rainfall products ...

  1. Herbicide volatilization trumps runoff losses, a multi-year investigation

    Science.gov (United States)

    Surface runoff and volatilization are two processes critical to herbicide off-site transport. To determine the relevance of these off-site transport mechanisms, runoff and turbulent vapor fluxes were simultaneously monitored on the same site for eight years. Site location, herbicide formulations, ...

  2. Surface and interface electronic structure: Three year activity report

    International Nuclear Information System (INIS)

    Kevan, S.D.

    1992-01-01

    The 3-year activity report covers surface structure and phonon anomalies (surface reconstruction on W(001) and Mo(001), adsorbate lateral ordering, surface Fermi contours and phonon anomalies on Pt(111) and Pd(001)), adsorbate vibrational damping, charge transfer in momentum space: W(011)-K, surface states and resonances (relativistic effects ampersand computations, surface resonances)

  3. Low-energy electron irradiation induced top-surface nanocrystallization of amorphous carbon film

    Science.gov (United States)

    Chen, Cheng; Fan, Xue; Diao, Dongfeng

    2016-10-01

    We report a low-energy electron irradiation method to nanocrystallize the top-surface of amorphous carbon film in electron cyclotron resonance plasma system. The nanostructure evolution of the carbon film as a function of electron irradiation density and time was examined by transmission electron microscope (TEM) and Raman spectroscopy. The results showed that the electron irradiation gave rise to the formation of sp2 nanocrystallites in the film top-surface within 4 nm thickness. The formation of sp2 nanocrystallite was ascribed to the inelastic electron scattering in the top-surface of carbon film. The frictional property of low-energy electron irradiated film was measured by a pin-on-disk tribometer. The sp2 nanocrystallized top-surface induced a lower friction coefficient than that of the original pure amorphous film. This method enables a convenient nanocrystallization of amorphous surface.

  4. Effect of transverse electron drift on absorption of surface acoustic waves in CdS

    International Nuclear Information System (INIS)

    Kmita, A.M.; Medved', A.V.; Fedorets, V.N.

    1976-01-01

    The effect of the transverse electron drift on acousto-electron interaction in CdS has been studied. It has been revealed that the free electron drift only in the direction normal to the plane of propagation of surface acoustic waves may change the sound electron absorption coefficient in a wide range. In the case of metallization of the active part of a crystal surface a decrease in sound absorption has been observed both on the electron drift to a working crystal surface and on the opposite direction. Whereas in the case of a free crystal surface the transverse electron drift directed to the working plate surface causes an increase in sound absorption, and with the opposite drift electron absorption of the Rayleigh ultrasound waves is almost not observed. An explanation of the effects observed is proposed

  5. Estimating the tritium input to groundwater from wine samples: Groundwater and direct run-off contribution to Central European surface waters

    International Nuclear Information System (INIS)

    Roether, W.

    1967-01-01

    yearly average of precipitation. This is reflected also by river measurements, which in the absence of a direct run-off contribution, show a surprisingly low tritium content. The Weser river, which has its catchment area in the hilly districts and the lowlands of Northern Germany, is an example of dependence on large groundwater bodies and shows large fluctuations in tritium concentration correlated with rainfall. These fluctuations originate from the varying ratio of direct run-off to groundwater contribution, the direct run-off being much higher in tritium than the groundwater during the period of investigation (1963-65). The minimum tritium values for the Weser show that the groundwater contributions in 1964 had an average level as low as, or lower than 150 T.U. Fluctuations in the tritium concentration of the Alpenrhein, the main inflow of Lake Constance, are relatively small. This is obviously due to the fact that in this case the groundwater draining to the river is replaced fast enough to keep the concentrations of direct run-off and groundwater closely similar. Lake Constance, which is layered in summer and mixed in winter, was followed up in its response to the increased atmospheric tritium levels of recent years. The information on internal mixing of the lake thus obtained is compared to the mixing parameters obtained by other methods. The deep-water activity increased from 150 to 450 T.U. between 1963 and 1965. (author)

  6. First Principle Calculation of Electronic, Optical Properties and Photocatalytic Potential of CuO Surfaces

    OpenAIRE

    Ahmad, Faozan

    2016-01-01

    We have performed DFT calculations of electronic structure, optical properties and photocatalytic potential of the low-index surfaces of CuO. Photocatalytic reaction on the surface of semiconductor requires the appropriate band edge of the semiconductor surface to drive redox reactions. The calculation begins with the electronic structure of bulk system; it aims to determine realistic input parameters and band gap prediction. CuO is an antiferromagnetic material with strong electronic correla...

  7. Surface water quality in a water run-off canal system: A case study in Jubail Industrial City, Kingdom of Saudi Arabia

    Directory of Open Access Journals (Sweden)

    Zia Mahmood Siddiqi

    2016-06-01

    Full Text Available Water quality in a run-off canal system in an industrial area was evaluated for a range of physical and chemical properties comprising trace metals (including mercury (Hg, chromium (Cr, iron (Fe, manganese (Mn, salinity, pH, turbidity, total dissolved solids, total suspended solids, chemical oxygen demand (COD, and dissolved oxygen. High concentrations of potassium (K (1.260–2.345 mg/l and calcium (Ca (19.170–35510 mg/l demonstrated that the salinity in the water was high, which indicates that industrial effluents from fertilizer manufacturing and Chlor-alkali units are being discharged into the canal system. Almost all the metal concentrations in water and sediment were within the thresholds established by the local regulatory body. Concentrations of Cr (0.0154–0.0184 mg/l, Mn (0.0608–0.199 mg/l, Fe (0.023–0.035 mg/l, COD (807–916 mg/l, and turbidity (633 ± 15–783 ± 22 NTU were high where the canal discharges into the Persian Gulf; these discharges may compromise the health of the aquatic ecosystem. There is concern about the levels of Hg in water (0.00135–0.0084 mg/l, suspended sediment (0.00308–0.0096 mg/l, and bed sediment (0.00172–0.00442 mg/l because of the bio-accumulative nature of Hg. We also compared the total Hg concentrations in fish from Jubail, and two nearby cities. Hg contents were highest in fish tissues from Jubail. This is the first time that heavy metal pollution has been assessed in this water run-off canal system; information about Hg is of particular interest and will form the basis of an Hg database for the area that will be useful for future investigations.

  8. Extracellular Electron Uptake: Among Autotrophs and Mediated by Surfaces

    DEFF Research Database (Denmark)

    Tremblay, Pier-Luc; Angenent, Largus T.; Zhang, Tian

    2017-01-01

    Autotrophic microbes can acquire electrons from solid donors such as steel, other microbial cells, or electrodes. Based on this feature, bioprocesses are being developed for the microbial electrosynthesis (MES) of useful products from the greenhouse gas CO2. Extracellular electron-transfer mechan......Autotrophic microbes can acquire electrons from solid donors such as steel, other microbial cells, or electrodes. Based on this feature, bioprocesses are being developed for the microbial electrosynthesis (MES) of useful products from the greenhouse gas CO2. Extracellular electron......; or (iii) mediator-generating enzymes detached from cells. This review explores the interactions of autotrophs with solid electron donors and their importance in nature and for biosustainable technologies....

  9. Electron mobility on the surface of liquid Helium: influence of surface level atoms and depopulation of lowest subbands

    International Nuclear Information System (INIS)

    Grigoriev, P. D.; Dyugaev, A. M.; Lebedeva, E. V.

    2008-01-01

    The temperature dependence of electron mobility is examined. We calculate the contribution to the electron scattering rate from the surface level atoms (SLAs), proposed in [10]. This contribution is substantial at low temperatures T < 0.5, when the He vapor concentration is exponentially small. We also study the effect of depopulation of the lowest energy subband, which leads to an increase in the electron mobility at high temperature. The results explain certain long-standing discrepancies between the existing theory and experiment on electron mobility on the surface of liquid helium

  10. Estimativa do escoamento superficial em uma bacia hidrográfica com base em modelagem dinâmica e distribuída Surface runoff in a watershed estimated by dynamic and distributed modeling

    Directory of Open Access Journals (Sweden)

    Samuel Beskow

    2009-02-01

    escoamento superficial, visto que propicia estruturação de rotinas computacionais considerando os problemas associados à variabilidade espacial dos dados de entrada dos modelos.Knowledge on the surface runoff in watersheds is very important for a good conservation of natural resources. However, surface runoff is a complex and dynamic process, especially in the context of spatial variability. An application of the Geographical Information System (GIS tools in small grid cells is therefore adequate. This way, it is possible to consider the spatial behavior of variables associated to the origin of surface runoff. This study aimed to program the Hydrological Models SCS-CN (SCS-Curve Number and CN - MMS (CN - Modified based on the PC Raster Programming Language and a reduced dataset, in distributed and dynamic approaches, to estimate the direct surface runoff in a watershed of Oxissols, in the county of Nazareno, region of Campos das Vertentes, Minas Gerais State. SCS-CN model was applied structuring a CN-map linked to the soil infiltration capacity in the PCRaster GIS format. For the CN - MMS model, we used other maps: saturated volumetric soil moisture content, initial volumetric soil moisture content and soil depth. For the simulation and evaluation of both models, 18 rainfall events that produced surface runoff in the hydrologic year 2004-2005 were used, and their respective surface runoff depths observed. The model performance was evaluated by sensitivity analyses, based on the mean error and Root Square Error. Based on these accuracy statistics, the calibration of the CN - MMS model was better than in the original SCS-CN model, since the initial soil moisture was taken into account. Nevertheless, the adjustment of the models in the SIG PCRaster allowed the development of an effective and useful computer tool to simulate surface runoff, due to the possibility of establishing computer routines considering the problems elated to the spatial variability of data entries of

  11. Electron beam processed plasticized epoxy coatings for surface protection

    International Nuclear Information System (INIS)

    Ibrahim, Mervat S.; Mohamed, Heba A.; Kandile, Nadia G.; Said, Hossam M.; Mohamed, Issa M.

    2011-01-01

    Highlights: · Coating formulations with EA 70%, HD 20%, and castor oil 10% under 1 Mrad pass -1 irradiation dose showed the best adhesion and passed bending tests. · The prepared EP-SF-An adduct improve anti-corrosion properties of coatings without any significant effect on physical, mechanical and chemical properties of the cured film. The optimum amount of aniline adduct as corrosion inhibitor was found to be 0.4 g for 100 g of coating formulation. · The corrosion inhibition efficiency of the prepared adduct competed the commercial efficiency. - Abstract: Epoxy acrylate oligomer (EA) was plasticized by adding different plasticizers such as epoxidized soybean oil, glycerol and castor oil and cured by electron beam (EB). Different irradiation doses (1, 2.5 and 5 Mrad pass -1 ) were used in the curing process. The effect of both different irradiation doses and plasticizers on the end use performance properties of epoxy acrylate coating namely, pencil hardness, bending test, adhesion test, acid and alkali resistance test were studied. It was observed that incorporation of castor oil in epoxy acrylate diluted by 1,6-hexanediol diacrylate (HD) monomer with a ratio (EA 70%, HD 20%, castor oil 10%) under 1 Mrad pass -1 irradiation dose improved the physical, chemical and mechanical properties of cured films than the other plasticizer. Sunflower free fatty acid was epoxidized in situ under well established conditions. The epoxidized sunflower free fatty acids (ESFA) were subjected to react with aniline in sealed ampoules under inert atmosphere at 140 deg. C. The produced adducts were added at different concentrations to epoxy acrylate coatings under certain EB irradiation dose and then evaluated as corrosion inhibitors for carbon steel surfaces in terms of weight loss measurements and corrosion resistance tests. It was found that, addition of 0.4 g of aniline adduct to 100 g epoxy acrylate formula may give the best corrosion protection for carbon steel and compete the

  12. Vibrational Surface Electron-Energy-Loss Spectroscopy Probes Confined Surface-Phonon Modes

    Directory of Open Access Journals (Sweden)

    Hugo Lourenço-Martins

    2017-12-01

    Full Text Available Recently, two reports [Krivanek et al. Nature (London 514, 209 (2014NATUAS0028-083610.1038/nature13870, Lagos et al. Nature (London 543, 529 (2017NATUAS0028-083610.1038/nature21699] have demonstrated the amazing possibility to probe vibrational excitations from nanoparticles with a spatial resolution much smaller than the corresponding free-space phonon wavelength using electron-energy-loss spectroscopy (EELS. While Lagos et al. evidenced a strong spatial and spectral modulation of the EELS signal over a nanoparticle, Krivanek et al. did not. Here, we show that discrepancies among different EELS experiments as well as their relation to optical near- and far-field optical experiments [Dai et al. Science 343, 1125 (2014SCIEAS0036-807510.1126/science.1246833] can be understood by introducing the concept of confined bright and dark surface phonon modes, whose density of states is probed by EELS. Such a concise formalism is the vibrational counterpart of the broadly used formalism for localized surface plasmons [Ouyang and Isaacson Philos. Mag. B 60, 481 (1989PMABDJ1364-281210.1080/13642818908205921, García de Abajo and Aizpurua Phys. Rev. B 56, 15873 (1997PRBMDO0163-182910.1103/PhysRevB.56.15873, García de Abajo and Kociak Phys. Rev. Lett. 100, 106804 (2008PRLTAO0031-900710.1103/PhysRevLett.100.106804, Boudarham and Kociak Phys. Rev. B 85, 245447 (2012PRBMDO1098-012110.1103/PhysRevB.85.245447]; it makes it straightforward to predict or interpret phenomena already known for localized surface plasmons such as environment-related energy shifts or the possibility of 3D mapping of the related surface charge densities [Collins et al. ACS Photonics 2, 1628 (2015APCHD52330-402210.1021/acsphotonics.5b00421].

  13. Vibrational Surface Electron-Energy-Loss Spectroscopy Probes Confined Surface-Phonon Modes

    Science.gov (United States)

    Lourenço-Martins, Hugo; Kociak, Mathieu

    2017-10-01

    Recently, two reports [Krivanek et al. Nature (London) 514, 209 (2014), 10.1038/nature13870, Lagos et al. Nature (London) 543, 529 (2017), 10.1038/nature21699] have demonstrated the amazing possibility to probe vibrational excitations from nanoparticles with a spatial resolution much smaller than the corresponding free-space phonon wavelength using electron-energy-loss spectroscopy (EELS). While Lagos et al. evidenced a strong spatial and spectral modulation of the EELS signal over a nanoparticle, Krivanek et al. did not. Here, we show that discrepancies among different EELS experiments as well as their relation to optical near- and far-field optical experiments [Dai et al. Science 343, 1125 (2014), 10.1126/science.1246833] can be understood by introducing the concept of confined bright and dark surface phonon modes, whose density of states is probed by EELS. Such a concise formalism is the vibrational counterpart of the broadly used formalism for localized surface plasmons [Ouyang and Isaacson Philos. Mag. B 60, 481 (1989), 10.1080/13642818908205921, García de Abajo and Aizpurua Phys. Rev. B 56, 15873 (1997), 10.1103/PhysRevB.56.15873, García de Abajo and Kociak Phys. Rev. Lett. 100, 106804 (2008), 10.1103/PhysRevLett.100.106804, Boudarham and Kociak Phys. Rev. B 85, 245447 (2012), 10.1103/PhysRevB.85.245447]; it makes it straightforward to predict or interpret phenomena already known for localized surface plasmons such as environment-related energy shifts or the possibility of 3D mapping of the related surface charge densities [Collins et al. ACS Photonics 2, 1628 (2015), 10.1021/acsphotonics.5b00421].

  14. Surface structure determinations of crystalline ionic thin films grown on transition metal single crystal surfaces by low energy electron diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Roberts, Joel Glenn [Univ. of California, Berkeley, CA (United States)

    2000-05-01

    The surface structures of NaCl(100), LiF(100) and alpha-MgCl2(0001) adsorbed on various metal single crystals have been determined by low energy electron diffraction (LEED). Thin films of these salts were grown on metal substrates by exposing the heated metal surface to a molecular flux of salt emitted from a Knudsen cell. This method of investigating thin films of insulators (ionic salts) on a conducting substrate (metal) circumvents surface charging problems that plagued bulk studies, thereby allowing the use of electron-based techniques to characterize the surface.

  15. Urban Runoff and Nutrients Loading Control from Sustainable BMPs (Invited)

    Science.gov (United States)

    Xiao, Q.

    2009-12-01

    Climate change alters hydrodynamic and nutrient dynamic in both large and small geographic scales. These changes in our freshwater system directly affect drinking water, food production, business, and all aspects of our life. Along with climate change is increasing urbanization which alters natural landscape. Urban runoff has been identified as one of many potential drivers of the decline of pelagic fishes in san Francisco Bay-Delta region. Recent found of Pyrethroids in American River has increased scientists, public, and policy makers’ concern about our fresh water system. Increasing our understanding about the fundamental hydrodynamic, nutrient dynamics, and the transport mechanics of runoff and nutrients are important for future water resource and ecosystem management. Urbanization has resulted in significantly increasing the amount of impervious land cover. Most impervious land covers are hydrophobic that alters surface runoff because of the effects on surface retention storage, rainfall interception, and infiltration. Large volumes of excess storm runoff from urbanized areas cause flooding, water pollution, groundwater recharge deficits, destroyed habitat, beach closures, and toxicity to aquatic organisms. Parking lot alone accounts for more than 11% of these impervious surfaces. Contrast to impervious parking lot, turfgrass can accouter for 12% of urban land in California. Irrigated urban landscapes create considerable benefits to our daily living. However, the use of fertilizers and pesticides has caused environmental problems. Preventing fertilizers and pesticides from entering storm drains is an important goal for both landscape and storm runoff managers. Studies of urban runoff have found that the most fertilizers and pesticides are from dry weather runoff which conveys pollutants to sidewalks, streets, and storm drains. Controlling surface runoff is critical to preventing these pollutants from entering storm drains and water bodies. Large scale

  16. Surface electron states on the quasi-two-dimensional excess-electron compounds Ca2N and Y2C

    Science.gov (United States)

    Inoshita, Takeshi; Takemoto, Seiji; Tada, Tomofumi; Hosono, Hideo

    2017-04-01

    Compounds having excess electrons from the formal valence viewpoint (electrides) are a new class of materials, which often take low-dimensional structures. We studied the (001) surface electronic structures of quasi-two-dimensional electrides Ca2N and Y2C by density functional theory using a slab model. Both materials were found to have a clean surface state well separated in energy from the bulk states. Furthermore, this state virtually floats above the surface and may be considered to be a hallmark of two-dimensional electrides. For Ca2N , a tight-binding model in the Wannier representation was derived and analyzed, from which we concluded that the surface state, described by extra-surface s -like orbitals, is a Tamm state originating from an abrupt increase in potential energy at the surface.

  17. Homogenization mechanism of the residual surface potential of insulating specimens under electron beam irradiation

    International Nuclear Information System (INIS)

    Li Jingjing; Zhang Haibo; Feng Renjian

    2007-01-01

    A homogenized surface potential is desirable for the observation of a pre-irradiated insulating specimen using a scanning electron microscope because the residual surface potential may affect the imaging properties of the specimen. To homogenize the residual surface potential, the specimen should be subjected to the irradiation of an electron beam with the total electron yield greater than one. The expression of the equilibrium potential is derived based on the charge balance condition in the equilibrium state and the potential value is found to increase mainly with the secondary electron (SE) yield and the most probable emission energy of SEs. Further numerical calculations of SE trajectories show that affected by different surface potentials, SEs leave or return to the specimen surface to change the net charge flux into the specimen. This thereby increases the surface potential below the equilibrium potential and decreases that above the equilibrium potential, homogenizing the surface potential

  18. Surface flashover performance of epoxy resin microcomposites improved by electron beam irradiation

    International Nuclear Information System (INIS)

    Huang, Yin; Min, Daomin; Li, Shengtao; Li, Zhen; Xie, Dongri; Wang, Xuan; Lin, Shengjun

    2017-01-01

    Highlights: • Epoxy resin microcomposites were irradiated by electron beam with energies of 10 and 20 keV. • Surface flashover voltage increase with the increase of electron beam energy. • Both the untreated and irradiated samples have two trap centers, which are labeled as shallow and deep traps. • Deposition energy in epoxy resin microcomposites increases with electron beam energy, and surface trap properties are determined by deposition energy. • The influence of surface conductivity and trap distribution on flashover voltage is discussed. - Abstract: The influencing mechanism of electron beam irradiation on surface flashover of epoxy resin/Al 2 O 3 microcomposite was investigated. Epoxy resin/Al 2 O 3 microcomposite samples with a diameter of 50 mm and a thickness of 1 mm were prepared. The samples were irradiated by electron beam with energies of 10 and 20 keV and a beam current of 5 μA for 5 min. Surface potential decay, surface conduction, and surface flashover properties of untreated and irradiated samples were measured. Both the decay rate of surface potential and surface conductivity decrease with an increase in the energy of electron beam. Meanwhile, surface flashover voltage increase. It was found that both the untreated and irradiated samples have two trap centers, which are labeled as shallow and deep traps. The increase in the energy and density of deep surface traps enhance the ability to capture primary emitted electrons. In addition, the decrease in surface conductivity blocks electron emission at the cathode triple junction. Therefore, electron avalanche at the interface between gas and an insulating material would be suppressed, eventually improving surface flashover voltage of epoxy resin microcomposites.

  19. Surface flashover performance of epoxy resin microcomposites improved by electron beam irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Yin; Min, Daomin [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Li, Shengtao, E-mail: stli@mail.xjtu.edu.cn [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Li, Zhen; Xie, Dongri [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Wang, Xuan [Key Laboratory of Engineering Dielectric and its Application, Ministry of Education, Harbin University of Science and Technology, Harbin 150040 (China); Lin, Shengjun [State Key Laboratory of Electrical Insulation and Power Equipment, Xi' an Jiaotong University, Xi' an 710049 (China); Pinggao Group Company Ltd., State Grid High Voltage Switchgear Insulation Materials Laboratory, Pingdingshan 467001 (China)

    2017-06-01

    Highlights: • Epoxy resin microcomposites were irradiated by electron beam with energies of 10 and 20 keV. • Surface flashover voltage increase with the increase of electron beam energy. • Both the untreated and irradiated samples have two trap centers, which are labeled as shallow and deep traps. • Deposition energy in epoxy resin microcomposites increases with electron beam energy, and surface trap properties are determined by deposition energy. • The influence of surface conductivity and trap distribution on flashover voltage is discussed. - Abstract: The influencing mechanism of electron beam irradiation on surface flashover of epoxy resin/Al{sub 2}O{sub 3} microcomposite was investigated. Epoxy resin/Al{sub 2}O{sub 3} microcomposite samples with a diameter of 50 mm and a thickness of 1 mm were prepared. The samples were irradiated by electron beam with energies of 10 and 20 keV and a beam current of 5 μA for 5 min. Surface potential decay, surface conduction, and surface flashover properties of untreated and irradiated samples were measured. Both the decay rate of surface potential and surface conductivity decrease with an increase in the energy of electron beam. Meanwhile, surface flashover voltage increase. It was found that both the untreated and irradiated samples have two trap centers, which are labeled as shallow and deep traps. The increase in the energy and density of deep surface traps enhance the ability to capture primary emitted electrons. In addition, the decrease in surface conductivity blocks electron emission at the cathode triple junction. Therefore, electron avalanche at the interface between gas and an insulating material would be suppressed, eventually improving surface flashover voltage of epoxy resin microcomposites.

  20. Electron beam processed plasticized epoxy coatings for surface protection

    Energy Technology Data Exchange (ETDEWEB)

    Ibrahim, Mervat S. [National Center for Radiation Research and Technology, Nasr City (Egypt); Mohamed, Heba A., E-mail: hebaamohamed@gmail.com [National Research Center, Dokki (Egypt); Kandile, Nadia G. [University College for Girls, Ain Shams University (Egypt); Said, Hossam M.; Mohamed, Issa M. [National Center for Radiation Research and Technology, Nasr City (Egypt)

    2011-10-17

    Highlights: {center_dot} Coating formulations with EA 70%, HD 20%, and castor oil 10% under 1 Mrad pass{sup -1} irradiation dose showed the best adhesion and passed bending tests. {center_dot} The prepared EP-SF-An adduct improve anti-corrosion properties of coatings without any significant effect on physical, mechanical and chemical properties of the cured film. The optimum amount of aniline adduct as corrosion inhibitor was found to be 0.4 g for 100 g of coating formulation. {center_dot} The corrosion inhibition efficiency of the prepared adduct competed the commercial efficiency. - Abstract: Epoxy acrylate oligomer (EA) was plasticized by adding different plasticizers such as epoxidized soybean oil, glycerol and castor oil and cured by electron beam (EB). Different irradiation doses (1, 2.5 and 5 Mrad pass{sup -1}) were used in the curing process. The effect of both different irradiation doses and plasticizers on the end use performance properties of epoxy acrylate coating namely, pencil hardness, bending test, adhesion test, acid and alkali resistance test were studied. It was observed that incorporation of castor oil in epoxy acrylate diluted by 1,6-hexanediol diacrylate (HD) monomer with a ratio (EA 70%, HD 20%, castor oil 10%) under 1 Mrad pass{sup -1} irradiation dose improved the physical, chemical and mechanical properties of cured films than the other plasticizer. Sunflower free fatty acid was epoxidized in situ under well established conditions. The epoxidized sunflower free fatty acids (ESFA) were subjected to react with aniline in sealed ampoules under inert atmosphere at 140 deg. C. The produced adducts were added at different concentrations to epoxy acrylate coatings under certain EB irradiation dose and then evaluated as corrosion inhibitors for carbon steel surfaces in terms of weight loss measurements and corrosion resistance tests. It was found that, addition of 0.4 g of aniline adduct to 100 g epoxy acrylate formula may give the best corrosion

  1. Documentation of the dynamic parameter, water-use, stream and lake flow routing, and two summary output modules and updates to surface-depression storage simulation and initial conditions specification options with the Precipitation-Runoff Modeling System (PRMS)

    Science.gov (United States)

    Regan, R. Steve; LaFontaine, Jacob H.

    2017-10-05

    This report documents seven enhancements to the U.S. Geological Survey (USGS) Precipitation-Runoff Modeling System (PRMS) hydrologic simulation code: two time-series input options, two new output options, and three updates of existing capabilities. The enhancements are (1) new dynamic parameter module, (2) new water-use module, (3) new Hydrologic Response Unit (HRU) summary output module, (4) new basin variables summary output module, (5) new stream and lake flow routing module, (6) update to surface-depression storage and flow simulation, and (7) update to the initial-conditions specification. This report relies heavily upon U.S. Geological Survey Techniques and Methods, book 6, chapter B7, which documents PRMS version 4 (PRMS-IV). A brief description of PRMS is included in this report.

  2. Guide on the use of low energy electron beams for microbiological decontamination of surfaces

    DEFF Research Database (Denmark)

    Miller, Arne; Helt-Hansen, Jakob; Gondim, Ondina

    This Guide describes the validation and routine monitoring of microbiological decontamination of surfaces by low energy electron beams (100-200 keV). The Guide is mainly based on experience gained in connection with installation of electron beam systems for surface decontamination of pre-steriliz...

  3. Evaluation of Livestock Runoff as a Source of Water Polution in Northern Utah

    OpenAIRE

    Wieneke, Stephen T.; George, Dennis B.; Filip, Daniel S.; Finney, Brad

    1980-01-01

    A mathematical model was developed to predict the impact of dairy and beef cattle feedlot runoff on receiving streams. The mathematical expressions used in the model describing runoff quantity and quality were not only a function of single rain or snow precipitation events but also consecutive events prior to the runoff occurrence. The runoff quantity and quality were also a function of feedlot surface. Computer s...

  4. The role of substrate electrons in the wetting of a metal surface

    DEFF Research Database (Denmark)

    Schiros, T.; Takahashi, O.; Andersson, Klas Jerker

    2010-01-01

    We address how the electronic and geometric structures of metal surfaces determine water-metal bonding by affecting the balance between Pauli repulsion and electrostatic attraction. We show how the rigid d-electrons and the softer s-electrons utilize different mechanisms for the redistribution...... of charge that enables surface wetting. On open d-shell Pt(111), the ligand field of water alters the distribution of metal d-electrons to reduce the repulsion. The closed-shell Cu d(10) configuration of isostructural Cu(111), however, does not afford this mechanism, resulting in a hydrophobic surface...

  5. Simple scalings for various regimes of electron acceleration in surface plasma waves

    Energy Technology Data Exchange (ETDEWEB)

    Riconda, C.; Vialis, T. [LULI, Sorbonne Université, Université Pierre et Marie Curie, Ecole Polytechnique, CNRS UMR 7605, CEA, Paris 75005 (France); Raynaud, M. [Laboratoire des Solides Irradiés, CNRS UMR 7642, CEA-DSM-IRAMIS, Ecole Polytechnique, Université Paris-Saclay, 91128 Palaiseau (France); Grech, M. [LULI, CNRS UMR 7605, Université Pierre et Marie Curie, Ecole Polytechnique, CEA, 91128 Palaiseau (France)

    2015-07-15

    Different electron acceleration regimes in the evanescent field of a surface plasma wave are studied by considering the interaction of a test electron with the high-frequency electromagnetic field of a surface wave. The non-relativistic and relativistic limits are investigated. Simple scalings are found demonstrating the possibility to achieve an efficient conversion of the surface wave field energy into electron kinetic energy. This mechanism of electron acceleration can provide a high-frequency pulsed source of relativistic electrons with a well defined energy. In the relativistic limit, the most energetic electrons are obtained in the so-called electromagnetic regime for surface waves. In this regime, the particles are accelerated to velocities larger than the wave phase velocity, mainly in the direction parallel to the plasma-vacuum interface.

  6. Electron attenuation anisotropy at crystal surfaces from LEED

    Czech Academy of Sciences Publication Activity Database

    Romanyuk, Olexandr; Bartoš, Igor

    2009-01-01

    Roč. 603, č. 17 (2009), s. 2789-2792 ISSN 0039-6028 R&D Projects: GA ČR GA202/07/0601; GA AV ČR IAA100100628 Institutional research plan: CEZ:AV0Z10100521 Keywords : electron attenuation length, low energy electron diffraction, photoelectron diffraction, electron–solid scattering and transmission, copper * low energy electron diffraction * photoelectron diffraction * electron–solid scattering and transmission * copper Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.798, year: 2009 http://dx.doi.org/10.1016/j.susc.2009.07.024

  7. Neutralizing trapped electrons on the hydrogenated surface of a diamond amplifier

    Directory of Open Access Journals (Sweden)

    Xiangyun Chang

    2012-01-01

    Full Text Available We discuss our investigation of electron trapping in a diamond amplifier (DA. Our previous work demonstrated that some electrons reaching the DA’s hydrogenated surface are not emitted. The state and the removal of these electrons is important for DA applications. We found that these stopped electrons are trapped, and cannot be removed by a strong reversed-polarity electric field; to neutralize this surface charge, holes must be sent to the hydrogenated surface to recombine with the trapped electrons through the Shockley-Read-Hall surface-recombination mechanism. We measured the time taken for such recombination on the hydrogenated surface, viz. the recombination time, as less than 5 ns, limited by the resolution of our test system. With this measurement, we demonstrated that DA could be operated in an rf cavity with frequency of a few hundred megahertz.

  8. The effect of hot electrons and surface plasmons on heterogeneous catalysis

    International Nuclear Information System (INIS)

    Kim, Sun Mi; Lee, Si Woo; Moon, Song Yi; Park, Jeong Young

    2016-01-01

    Hot electrons and surface-plasmon-driven chemistry are amongst the most actively studied research subjects because they are deeply associated with energy dissipation and the conversion processes at the surface and interfaces, which are still open questions and key issues in the surface science community. In this topical review, we give an overview of the concept of hot electrons or surface-plasmon-mediated hot electrons generated under various structural schemes (i.e. metals, metal–semiconductor, and metal–insulator–metal) and their role affecting catalytic activity in chemical reactions. We highlight recent studies on the relation between hot electrons and catalytic activity on metallic surfaces. We discuss possible mechanisms for how hot electrons participate in chemical reactions. We also introduce controlled chemistry to describe specific pathways for selectivity control in catalysis on metal nanoparticles. (topical review)

  9. Surface morphological, mechanical and thermal characterization of electron beam irradiated fibers

    International Nuclear Information System (INIS)

    Choi, Hae Young; Han, Seong Ok; Lee, Jung Soon

    2008-01-01

    The surface morphology of henequen irradiated by electron beam has been investigated by atomic force microscopy (AFM). Also, the extents to which electron beam irradiation affected the tensile and thermal properties of henequen fiber were investigated with Instron tensile tests and thermogravimetric analysis (TGA). The AFM studies showed that the pectin, waxy and primary layers (P) of henequen fiber, which have heterogeneous structures, were removed from the fiber surface by electron beam irradiation. The tensile strength and thermal stability of henequen fiber decreased with increasing dose of electron beam. At the irradiation of 10 kGy, the surface roughness increased because of the removal of the pectin, waxy and P layer, but the tensile strength of henequen irradiated with 10 kGy were maintained. It has been suggested that the use of a 10 kGy dose of electron beam to modify the henequen fiber surface can improve the surface properties and preserve the fibers' mechanical and thermal properties.

  10. Collaborative Research: Fundamental studies of plasma control using surface embedded electronic devices

    Energy Technology Data Exchange (ETDEWEB)

    Raja, Laxminarayan L. [Univ. of Texas, Austin, TX (United States); PanneerChelvam, PremKumar [Univ. of Texas, Austin, TX (United States); Levko, Dimtry [Univ. of Texas, Austin, TX (United States)

    2016-02-26

    The proposed study will investigate the effect of active electron injection of from electrode surfaces To the best of our knowledge, no such a study has ever been attempted even though it could lead to the formation of whole new classes of plasma based devices and systems. We are motivated by recent articles and simple theory which gives strong reason to believe that embedded electronic devices can be used to exert control over the SEE coefficient of semiconductor surfaces (and maybe other surface types as well). Furthermore, the research will explore how such sub-surface electronic devices can best be used to exert control over an associated plasma.

  11. Hot-electron-assisted femtochemistry at surfaces: A time-dependent density functional theory approach

    DEFF Research Database (Denmark)

    Gavnholt, Jeppe; Rubio, Angel; Olsen, Thomas

    2009-01-01

    Using time-evolution time-dependent density functional theory (TDDFT) within the adiabatic local-density approximation, we study the interactions between single electrons and molecular resonances at surfaces. Our system is a nitrogen molecule adsorbed on a ruthenium surface. The surface is modeled...... at two levels of approximation, first as a simple external potential and later as a 20-atom cluster. We perform a number of calculations on an electron hitting the adsorbed molecule from inside the surface and establish a picture, where the resonance is being probed by the hot electron. This enables us...

  12. Electronic state of europium atoms on surface of oxidized tungsten

    CERN Document Server

    Davydov, S Y

    2001-01-01

    The energy scheme of the europium atoms adsorption system on the tungsten surface, coated with the oxygen monolayer, is considered. The evaluations of the europium adatoms charged state on the oxidized tungsten surface are performed. It is established, that europium, adsorbed at the oxidized tungsten surface, is a positive ion with the charge close to the unit. The zonal scheme of the Eu-O/W adsorption system for the europium low and high concentrations is proposed

  13. Electron Conditioning of Technical Aluminium Surfaces: Effect on the Secondary Electron Yield

    Energy Technology Data Exchange (ETDEWEB)

    Le Pimpec, F.

    2004-12-13

    The effect of electron conditioning on commercially aluminium alloys 1100 and 6063 were investigated. Contrary to the assumption that electron conditioning, if performed long enough, can reduce and stabilize the SEY to low values (< 1.3, value of many pure elements [1] ), the SEY of aluminium did not go lower than 1.8. In fact, it reincreases with continued electron exposure dose.

  14. Magnetoresistance of tungsten thin wafer at the multichannel surface scattering of conduction electrons

    International Nuclear Information System (INIS)

    Lutsishin, P.P.; Nakhodkin, T.N.

    1982-01-01

    The magnetoresistance of tungsten thin wafer with the (110) surface was studied at the adsorption of tungsten dioxide. The method of low-energy electron diffraction was used to study the symmetry of ordered surface structures. Using the method of the magnetoresistance measurement the character of the scattering of conduction electrons was investigated. THe dependence of magnetoresistance on the surface concentration of tungsten dioxide correlated w1th the structure of the surface layer of atoms, what was explained with allowance for diffraction of conduction electrons at the metal boundary. The magnetoresistance maximum for the (2x2) structure, which characterised decrease in surface conduction under the conditions of static skin effect, was explained by multichannel mirror reflection with the recombinations of electron and ho.le sections of Fermi Surface

  15. Low-energy electron irradiation induced top-surface nanocrystallization of amorphous carbon film

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Cheng [Institute of Nanosurface Science and Engineering (INSE), Shenzhen University, Shenzhen 518060 (China); Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060 (China); Fan, Xue, E-mail: fanx@szu.edu.cn [Institute of Nanosurface Science and Engineering (INSE), Shenzhen University, Shenzhen 518060 (China); Diao, Dongfeng, E-mail: dfdiao@szu.edu.cn [Institute of Nanosurface Science and Engineering (INSE), Shenzhen University, Shenzhen 518060 (China)

    2016-10-30

    Graphical abstract: Low-energy electron irradiation was proposed to nanocrystallize the top-surface of the as-deposited amorphous carbon film, and sp{sup 2} nanocrystallites formed in the film top-surface within 4 nm thickness. Display Omitted - Abstract: We report a low-energy electron irradiation method to nanocrystallize the top-surface of amorphous carbon film in electron cyclotron resonance plasma system. The nanostructure evolution of the carbon film as a function of electron irradiation density and time was examined by transmission electron microscope (TEM) and Raman spectroscopy. The results showed that the electron irradiation gave rise to the formation of sp{sup 2} nanocrystallites in the film top-surface within 4 nm thickness. The formation of sp{sup 2} nanocrystallite was ascribed to the inelastic electron scattering in the top-surface of carbon film. The frictional property of low-energy electron irradiated film was measured by a pin-on-disk tribometer. The sp{sup 2} nanocrystallized top-surface induced a lower friction coefficient than that of the original pure amorphous film. This method enables a convenient nanocrystallization of amorphous surface.

  16. Surface and interface electronic structure: Sixth year activity report

    International Nuclear Information System (INIS)

    Kevan, S.D.

    1992-01-01

    Several productive runs were made on beamline U4A at NSLS. An upgrade of angle-resolved photoemission spectrometer was largely completed on the beamline. Progress was made on studies of surface states and reconstruction on Mo(001) and W(001), and of surface states and resonances on Pt(111)

  17. Study on surface structures with the aid of slow electron diffraction

    International Nuclear Information System (INIS)

    Fedyanin, V.K.; Mozol'kov, A.E.

    1976-01-01

    A short review is presented on experimental and theoretical data published on slow electron diffraction. The theory of slow electron diffraction on two-dimensional surface structures caused by the presence of an absorbed gas on the surface which has been earlier proposed by the authors is discussed. The model is based on a quantum-statistical model of adsorption on a homogeneous surface. Its application allows one to explain most important aspects of this problem

  18. Runoff generation in a Mediterranean semi-arid landscape: Thresholds, scale, rainfall and catchment characteristics

    Science.gov (United States)

    Ries, Fabian; Schmidt, Sebastian; Sauter, Martin; Lange, Jens

    2016-04-01

    Surface runoff acts as an integrated response of catchment characteristics and hydrological processes. In the Eastern Mediterranean region, a lack of runoff data has hindered a better understanding of runoff generation processes on the catchment scale, despite the importance of surface runoff as a water resource or flood hazard. Our main aim was to identify and explain differences in catchment runoff reactions across a variety of scales. Over a period of five years, we observed runoff in ephemeral streams of seven watersheds with sizes between 3 and 129 km2. Landuse and surface cover types (share of vegetation, bare soil and rock outcrops) were derived from aerial images by objective classification techniques. Using data from a dense rainfall network we analysed the effects of scale, catchment properties and aridity on runoff generation. Thereby we extracted rainfall and corresponding runoff events from our time-series to calculate event based rainfall characteristics and catchment runoff coefficients. Soil moisture observations provided additional information on antecedent moisture conditions, infiltration characteristics and the evolution of saturated areas. In contrast to the prevailing opinion that the proportion of Hortonian overland flow increases with aridity, we found that in our area the largest share (> 95 %) of runoff is generated by saturation excess overland flow in response to long lasting, rainfall events of high amount. This was supported by a strong correlation between event runoff and precipitation totals. Similar rainfall thresholds (50 mm) for runoff generation were observed in all investigated catchments. No scale effects on runoff coefficients were found; instead we identified up to three-fold runoff coefficients in catchments with larger extension of arid areas, higher percentage of rock outcrops and urbanization. Comparing two headwater catchments with noticeable differences in extent of olive orchards, no difference in runoff generation was

  19. Electron-beam induced current characterization of back-surface field solar cells using a chopped scanning electron microscope beam

    Science.gov (United States)

    Luke, K. L.; Cheng, L.-J.

    1984-01-01

    A chopped electron beam induced current (EBIC) technique for the chacterization of back-surface field (BSF) solar cells is presented. It is shown that the effective recombination velocity of the low-high junction forming the back-surface field of BSF cells, in addition to the diffusion length and the surface recombination velocity of the surface perpendicular to both the p-n and low-high junctions, can be determined from the data provided by a single EBIC scan. The method for doing so is described and illustrated. Certain experimental considerations taken to enhance the quality of the EBIC data are also discussed.

  20. An ultrafast nanotip electron gun triggered by grating-coupled surface plasmons

    Energy Technology Data Exchange (ETDEWEB)

    Schröder, Benjamin; Sivis, Murat; Bormann, Reiner; Schäfer, Sascha; Ropers, Claus, E-mail: cropers@gwdg.de [4th Physical Institute - Solids and Nanostructures, University of Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen (Germany)

    2015-12-07

    We demonstrate multiphoton photoelectron emission from gold nanotips induced by nanofocusing surface plasmons, resonantly excited on the tip shaft by a grating coupler. The tip is integrated into an electron gun assembly, which facilitates control over the spatial emission sites and allows us to disentangle direct grating emission from plasmon-triggered apex emission. The nanoscale source size of this electron gun concept enables highly coherent electron pulses with applications in ultrafast electron imaging and diffraction.

  1. Nuclear Dynamics and Electronic Effects of Hydrogen on Solid Surfaces.

    Science.gov (United States)

    Fukutani, K; Wilde, M; Ogura, S

    2017-02-01

    Hydrogen is involved in a variety of chemical processes on surfaces. While hydrogen exhibits vibrational and rotational dynamics in its adsorption state, it in some cases undergoes diffusion into the substrate as well as on the surface, and participates in chemical reactions. Furthermore, hydrogen exchanges an electron with surfaces having a significant effect on the surface electronic structure. In this personal account, we review our recent studies on surface nuclear dynamics of hydrogen, hydrogen transport across surfaces, catalytic hydrogenation/isotope exchange reactions, and charge transfer between the surface and hydrogen by using a depth-resolved technique of nuclear reaction analysis and a quantum-state-selective detection of resonance enhanced multiphoton ionization in combination with surface science techniques. As a future prospect, we refer to ultraslow μ spin rotation spectroscopy for a direct probe of the hydrogen charge state at surfaces. © 2017 The Chemical Society of Japan & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. X-ray free electron laser as a real-time probe of chemistry on surfaces

    International Nuclear Information System (INIS)

    Katayama, Tetsuo; Ogasawara, Hirohito

    2015-01-01

    X-ray free electron laser has opened up new possibilities for the study of surface chemical reactions on ultrafast time scale. This article reviews the recent work on the desorption of a molecule from a surface, which is one of the most fundamental surface chemical process. (author)

  3. Pollen grain surface in Vaccinium myrtillus as seen in scanning electron microscopy

    Directory of Open Access Journals (Sweden)

    Józef Kocoń

    2014-01-01

    Full Text Available Pollen grain surface of Vaccinium myrtillus L. was analyzed by scanning electron microscopy. Pollen grains remain in tetrahedral tetrads. Grain surface is verrucose, consisting of thick, irregularly shaped muri, surrounding small, round or oval lumina. The surface of the muri is fissured, and minute papillae can also be noted.

  4. Surface plasmon enhanced interfacial electron transfer and resonance Raman, surface-enhanced resonance Raman studies of cytochrome C mutants

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Junwei [Iowa State Univ., Ames, IA (United States)

    1999-11-08

    Surface plasmon resonance was utilized to enhance the electron transfer at silver/solution interfaces. Photoelectrochemical reductions of nitrite, nitrate, and CO2 were studied on electrochemically roughened silver electrode surfaces. The dependence of the photocurrent on photon energy, applied potential and concentration of nitrite demonstrates that the photoelectrochemical reduction proceeds via photoemission process followed by the capture of hydrated electrons. The excitation of plasmon resonances in nanosized metal structures resulted in the enhancement of the photoemission process. In the case of photoelectrocatalytic reduction of CO2, large photoelectrocatalytic effect for the reduction of CO2 was observed in the presence of surface adsorbed methylviologen, which functions as a mediator for the photoexcited electron transfer from silver metal to CO2 in solution. Photoinduced reduction of microperoxidase-11 adsorbed on roughened silver electrode was also observed and attributed to the direct photoejection of free electrons of silver metal. Surface plasmon assisted electron transfer at nanostructured silver particle surfaces was further determined by EPR method.

  5. Theory of coherent molecule to surface electron injection: An ...

    Indian Academy of Sciences (India)

    Administrator

    erogeneous electron transfer from a molecule to a semiconductor occurs before full vibrational relaxa- tion of the excited molecule is achieved. 5,6. Accor- dingly, theoretical description of the decay of the initial state has been formulated to include vibra- tional coherence in the transfer process. 4. 2. Analytical model.

  6. The interaction of swift electrons with surface excitations

    International Nuclear Information System (INIS)

    Ritchie, R.H.; Tennessee Univ., Knoxville, TN

    1992-01-01

    For many decades swift electrons have comprised a powerful tool for the study of the dynamical properties of condensed matter. The development of this technique has involved much important physics. Here we sketch the historical background of the field and some important developments in theory and experiment. Possible directions for future research are indicated

  7. Photoelectron spectroscopy and Auger electron spectroscopy of solids and surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Kowalczyk, S.P.

    1976-01-01

    The use of photoelectron spectroscopy, primarily x-ray photoelectron spectroscopy, to obtain information on the electronic structure of a wide variety of solids (especially the bulk electronic structure of solids) is covered. Both valence band and core-level spectra, as well as a few cases of photon excited Auger electron spectroscopy, are employed in the investigations to derive information on N(E). The effect of several modulations inherent in the measured I(E)'s, such as final state band structure, cross section, and relaxation, is discussed. Examples of many-electron interactions in PES are given. Some experimental aspects of PES and AES studies are given with emphasis on sample preparation techniques. Multiple splitting of core levels is examined using the Mn levels in MnF/sub 2/ as a detailed case study. Core level splittings in transition metals, rare earth metals, transition metal halides and several alloys are also reported. The application of PES to the study of the chemical bond in some crystalline semiconductors and insulators, A/sup N/B/sup 8-N/ and A/sup N/B/sup 10-N/ compounds is treated, and a spectroscopic scale of ionicity for these compounds is developed from the measured ''s-band'' splitting in the valence band density of states. (GHT)

  8. Photoelectron spectroscopy and Auger electron spectroscopy of solids and surfaces

    International Nuclear Information System (INIS)

    Kowalczyk, S.P.

    1976-01-01

    The use of photoelectron spectroscopy, primarily x-ray photoelectron spectroscopy, to obtain information on the electronic structure of a wide variety of solids (especially the bulk electronic structure of solids) is covered. Both valence band and core-level spectra, as well as a few cases of photon excited Auger electron spectroscopy, are employed in the investigations to derive information on N(E). The effect of several modulations inherent in the measured I(E)'s, such as final state band structure, cross section, and relaxation, is discussed. Examples of many-electron interactions in PES are given. Some experimental aspects of PES and AES studies are given with emphasis on sample preparation techniques. Multiple splitting of core levels is examined using the Mn levels in MnF 2 as a detailed case study. Core level splittings in transition metals, rare earth metals, transition metal halides and several alloys are also reported. The application of PES to the study of the chemical bond in some crystalline semiconductors and insulators, A/sup N/B/sup 8-N/ and A/sup N/B/sup 10-N/ compounds is treated, and a spectroscopic scale of ionicity for these compounds is developed from the measured ''s-band'' splitting in the valence band density of states

  9. Diffuse Surface Scattering in the Plasmonic Resonances of Ultralow Electron Density Nanospheres.

    Science.gov (United States)

    Monreal, R Carmina; Antosiewicz, Tomasz J; Apell, S Peter

    2015-05-21

    Localized surface plasmon resonances (LSPRs) have recently been identified in extremely diluted electron systems obtained by doping semiconductor quantum dots. Here, we investigate the role that different surface effects, namely, electronic spill-out and diffuse surface scattering, play in the optical properties of these ultralow electron density nanosystems. Diffuse scattering originates from imperfections or roughness at a microscopic scale on the surface. Using an electromagnetic theory that describes this mechanism in conjunction with a dielectric function including the quantum size effect, we find that the LSPRs show an oscillatory behavior in both position and width for large particles and a strong blue shift in energy and an increased width for smaller radii, consistent with recent experimental results for photodoped ZnO nanocrystals. We thus show that the commonly ignored process of diffuse surface scattering is a more important mechanism affecting the plasmonic properties of ultralow electron density nanoparticles than the spill-out effect.

  10. Intensity distributions of reflected surface channeling protons scattered on surfaces of electron-bombarded alkali halide crystals

    Science.gov (United States)

    Fukazawa, Y.; Kihara, K.; Iwamoto, K.; Susuki, Y.

    2013-11-01

    We have examined the surface-channeling of 550 keV protons on electron-bombarded KBr(0 0 1) surfaces at grazing incidence. On the surface, electron-stimulated desorption (ESD) resulting from the irradiation of 5 keV electrons changes the surface morphology. In order to investigate the change of the surface morphology, the luminous intensity distributions observed on a fluorescent screen (scattering patterns) of the reflected protons under the surface-channeling conditions are measured. Normalized specular intensity of the protons oscillates, and the results of computer simulations show that the period of the intensity oscillation agrees with the period of layer-by-layer desorption. The measured period of the oscillation is comparable to the simulated one, i.e., the period of the desorption, however, the measured amplitude of the oscillation is weak. This shows that the layer-by-layer desorption of the experimental surface is observed but is not as remarkable as that of the perfect surface introduced in the simulation.

  11. Intensity distributions of reflected surface channeling protons scattered on surfaces of electron-bombarded alkali halide crystals

    Energy Technology Data Exchange (ETDEWEB)

    Fukazawa, Y., E-mail: yukofu@cc.osaka-kyoiku.ac.jp; Kihara, K.; Iwamoto, K.; Susuki, Y.

    2013-11-15

    We have examined the surface-channeling of 550 keV protons on electron-bombarded KBr(0 0 1) surfaces at grazing incidence. On the surface, electron-stimulated desorption (ESD) resulting from the irradiation of 5 keV electrons changes the surface morphology. In order to investigate the change of the surface morphology, the luminous intensity distributions observed on a fluorescent screen (scattering patterns) of the reflected protons under the surface-channeling conditions are measured. Normalized specular intensity of the protons oscillates, and the results of computer simulations show that the period of the intensity oscillation agrees with the period of layer-by-layer desorption. The measured period of the oscillation is comparable to the simulated one, i.e., the period of the desorption, however, the measured amplitude of the oscillation is weak. This shows that the layer-by-layer desorption of the experimental surface is observed but is not as remarkable as that of the perfect surface introduced in the simulation.

  12. Clouds enhance Greenland ice sheet meltwater runoff.

    Science.gov (United States)

    Van Tricht, K; Lhermitte, S; Lenaerts, J T M; Gorodetskaya, I V; L'Ecuyer, T S; Noël, B; van den Broeke, M R; Turner, D D; van Lipzig, N P M

    2016-01-12

    The Greenland ice sheet has become one of the main contributors to global sea level rise, predominantly through increased meltwater runoff. The main drivers of Greenland ice sheet runoff, however, remain poorly understood. Here we show that clouds enhance meltwater runoff by about one-third relative to clear skies, using a unique combination of active satellite observations, climate model data and snow model simulations. This impact results from a cloud radiative effect of 29.5 (±5.2) W m(-2). Contrary to conventional wisdom, however, the Greenland ice sheet responds to this energy through a new pathway by which clouds reduce meltwater refreezing as opposed to increasing surface melt directly, thereby accelerating bare-ice exposure and enhancing meltwater runoff. The high sensitivity of the Greenland ice sheet to both ice-only and liquid-bearing clouds highlights the need for accurate cloud representations in climate models, to better predict future contributions of the Greenland ice sheet to global sea level rise.

  13. Crop Residue Biomass Effects on Agricultural Runoff

    Directory of Open Access Journals (Sweden)

    Damodhara R. Mailapalli

    2013-01-01

    Full Text Available High residue loads associated with conservation tillage and cover cropping may impede water flow in furrow irrigation and thus decrease the efficiency of water delivery and runoff water quality. In this study, the biomass residue effects on infiltration, runoff, and export of total suspended solids (TSS, dissolved organic carbon (DOC, sediment-associated carbon (TSS-C, and other undesirable constituents such as phosphate (soluble P, nitrate (, and ammonium ( in runoff water from a furrow-irrigated field were studied. Furrow irrigation experiments were conducted in 91 and 274 m long fields, in which the amount of residue in the furrows varied among four treatments. The biomass residue in the furrows increased infiltration, and this affected total load of DOC, TSS, and TSS-C. Net storage of DOC took place in the long but not in the short field because most of the applied water ran off in the short field. Increasing field length decreased TSS and TSS-C losses. Total load of , , and soluble P decreased with increasing distance from the inflow due to infiltration. The concentration and load of P increased with increasing residue biomass in furrows, but no particular trend was observed for and . Overall, the constituents in the runoff decreased with increasing surface cover and field length.

  14. Secondary Electron Yield on Cryogenic Surfaces as a Function of Physisorbed Gases

    CERN Document Server

    Kuzucan, Asena; Taborelli, Mauro

    2011-01-01

    In LHC the electron cloud induced by photoelectrons, gas ionization and secondary electrons emitted from the beam pipe walls could be a limitation of the performance. The electron cloud induce heat load on the cryogenic system, cause pressure rise, emittance growth and beam instabilities, which in the end will limit the beam’s lifetime. Beam- induced multipacting, which can arise through oscillatory motion of photoelectrons and low-energy secondary electrons bouncing back and forth between opposite walls of the vacuum chamber during successive passage of proton bunches, represent therefore a potential problem for the machine. The secondary electron yield (SEY) is one of the key parameters for the electron cloud build up and multipacting phenomenon. An electron cloud occurs if the metal surface secondary electron yield is high enough for electron multiplication. This parameter has been extensively studied on room temperature samples but uncertainties remain for samples at cryogenic temperature. Indeed, at l...

  15. Near-Surface Circulation and Fate of Upper Layer Fresh Water from Rivers Runoff and Rain in the Bay of Bengal near Sri Lanka

    Science.gov (United States)

    2015-09-30

    and variability over the experiment area and to infer the surface freshwater export pathways from direct measurements. The salinity drifters were...GOALS Improve the knowledge of the near-surface circulation in the BoB and of the pathways through which the freshwater fluxes occur. OBJECTIVES...drifters was deployed 2015 when an additional fleet of 36 salinity drifters was used in conjunction of other IOP activities to map the SSS distribution

  16. Influence of the projectile charge state on electron emission spectra from a Cu(111) surface

    Science.gov (United States)

    Archubi, C. D.; Silkin, V. M.; Gravielle, M. S.

    2015-09-01

    Double differential electron emission distributions produced by grazing impact of fast dressed ions on a Cu(111) surface are investigated focusing on the effects of the electronic band structure. The process is described within the Band-Structure-Based approximation, which is a perturbative method that includes an accurate representation of the electron-surface interaction, incorporating information of the electronic band structure of the solid. Differences in the behavior of the emission spectra for He+ q, Li+ q, Be+ q and C+ q projectiles with different charge states q are explained by the combined effect of the projectile trajectory and the projectile charge distribution.

  17. Electron emission induced by resonant coherent ion-surface interaction at grazing incidence

    International Nuclear Information System (INIS)

    Garcia de Abajo, F.J.; Ponce, V.H.; Echenique, P.M.

    1992-01-01

    A new spectroscopy based on the resonant coherently induced electron loss to the continuum in ion-surface scattering under grazing incidence is proposed. A series of peaks, corresponding to the energy differences determined by the resonant interaction with the rows of atoms in the surface, is predicted to appear in the energy distribution of electrons emitted from electronic states bound to the probe. Calculations for MeV He + ions scattered at a W(001) surface along the left-angle 100 right-angle direction with a glancing angle of 0--2 mrad show a total yield close to 1

  18. A glacier runoff extension to the Precipitation Runoff Modeling System

    Science.gov (United States)

    A. E. Van Beusekom; R. J. Viger

    2016-01-01

    A module to simulate glacier runoff, PRMSglacier, was added to PRMS (Precipitation Runoff Modeling System), a distributed-parameter, physical-process hydrological simulation code. The extension does not require extensive on-glacier measurements or computational expense but still relies on physical principles over empirical relations as much as is feasible while...

  19. Surface electronic properties of discontinuous Pd films during hydrogen exposure

    International Nuclear Information System (INIS)

    Zhao, Ming; Nagata, Shinji; Shikama, Tatsuo; Inouye, Aichi; Yamamoto, Shunya; Yoshikawa, Masahito

    2011-01-01

    This paper explored the change in the surface resistance of the discontinuous palladium (Pd) films during hydrogen exposure. In our experiments, we observed a remarkable rise in the electrical resistance of the discontinuous film which consists of nano-sized particles, when it was exposed to thin hydrogen. By studying the resistance change ratio before and after hydrogen exposure, we have found that it demonstrates an inverse exponential relationship with the ratio of on-film particle radius to the inter island separation. This suggests that the change in the film resistance under hydrogen exposure is primarily associated with the variation of surface work function which is caused by the hydrogen absorption on the Pd surface. (author)

  20. Magnetite Fe3O4 (111) Surfaces: Impact of Defects on Structure, Stability, and Electronic Properties

    KAUST Repository

    Noh, Jung Hyun

    2015-08-04

    We present a comprehensive investigation, via first-principles density functional theory (DFT) calculations, of various surface terminations of magnetite, Fe3O4 (111), a major iron oxide which has also a number of applications in electronics and spintronics. We compare the thermodynamic stability and electronic structure among the different surfaces terminations. Interestingly, we find that surfaces modified with point defects and adatoms can be more stable than bulk-like terminations. These surfaces show different surface chemistry, electronic structures and distinctive spin polarization features near the Fermi level from those previously considered in the literature. Our studies provide an atomic level insight for magnetite surfaces, which is a necessary step to understanding their interfaces with organic layers in OLED and spintronic devices.

  1. A scanning electron microscope study of olivine crystal surfaces

    Science.gov (United States)

    Olsen, E. J.; Grossman, L.

    1974-01-01

    SEM photographs were taken of euhedral olivine grains from the Murchison C2 chondrite and several terrestrial and lunar occurrences. In general, the crystal faces of the meteorite grains are rough and uneven, with irregular growth patterns. They are very similar to crystal faces on terrestrial olivine grains that formed by sublimation from a vapor phase. They are very different from the relatively smooth and featureless surfaces of magmatic olivine crystals that precipitated from igneous melts. Qualitatively, the surface morphology of the crystal supports the contention that many euhedral crystals of olivine in C2 meteorites condensed from a gas phase.

  2. Electronic dissipation processes during chemical reactions on surfaces

    CERN Document Server

    Stella, Kevin

    2012-01-01

    Hauptbeschreibung Every day in our life is larded with a huge number of chemical reactions on surfaces. Some reactions occur immediately, for others an activation energy has to be supplied. Thus it happens that though a reaction should thermodynamically run off, it is kinetically hindered. Meaning the partners react only to the thermodynamically more stable product state within a mentionable time if the activation energy of the reaction is supplied. With the help of catalysts the activation energy of a reaction can be lowered. Such catalytic processes on surfaces are widely used in industry. A

  3. Electronic Structure of Solids and Their Surfaces and Interfaces.

    Science.gov (United States)

    1981-06-30

    I!*l.7* ser~iccrd--otors and the more iconic I-VII ~nslatT’. Tey servo! yis %_test of calculationp.1 mothods previo-usly ,j s I o n t h c! i1, pr I1I...upper bon -.s, since electrons and holes are not as localized as this mo4el potrays them. The Hartree-Fock calculation and the following correlation

  4. Modelo hidrológico para estimativa do escoamento superficial em áreas agrícolas A hydrologic model to estimate the surface runoff in agricultural lands

    Directory of Open Access Journals (Sweden)

    Fernando F. Pruski

    2001-05-01

    Full Text Available Desenvolveu-se um modelo hidrológico para estimar o escoamento superficial em áreas sob condições agrícolas. O modelo é baseado na análise dos diversos processos associados ao balanço hídrico e nele se usa a equação de intensidade, duração e freqüência da precipitação para estimar a intensidade de precipitação e a equação de Green-Ampt modificada por Mein-Larson, para estimar a velocidade de infiltração permitindo, também, a consideração da interceptação pela cobertura vegetal e do armazenamento de água sobre a superfície do solo por meio de diferentes metodologias. O escoamento superficial começa após a capacidade de armazenamento sobre a superfície do solo ter sido preenchida, e é calculado subtraindo-se a velocidade de infiltração da água no solo da intensidade de precipitação durante o intervalo de tempo em que a intensidade da chuva é maior que a velocidade de infiltração. Resultados de um experimento de validação do modelo e duas aplicações práticas são apresentados, sendo que os resultados obtidos com o modelo foram muito próximos daqueles observados no campo.A hydrologic model was developed to estimate the surface runoff under agricultural conditions. The model is process-based and uses the intensity-duration-frequency equation to calculate the rainfall intensity and the Green-Ampt-Mein-Larson equation to estimate the infiltration rate. The runoff begins after the maximum surface storage on the soil surface has been reached. It is calculated by subtracting the infiltration rate from the rainfall intensity during the interval of time that the rainfall intensity is greater than the infiltration rate. The model also allows the calculation of the deep percolation and the actual soil-water content. Results from a validation experiment and two practical applications of the model are also presented. The results obtained with the model were approximately the same as those observed in the field.

  5. Suppression secondary electrons from target surface under pulsed ion beams bombardment

    International Nuclear Information System (INIS)

    Yang Zhen; Peng Yufei; Long Jidong; Lan Chaohui; Dong Pan; Shi Jinshui

    2012-01-01

    The producing mechanism of secondary electrons from target surface under ion beams bombardment is discussed. Several methods to suppress the secondary electrons in special vacuum devices and their advantages and disadvantages are introduced. The ways of using self-bias and curved surface target are proposed and verified in the experiment. The results show that the secondary electrons can be effectively suppressed when the self-bias is larger than 80 V. The secondary electron yield decreases by using curved surface target instead of flat target. The secondary electron yield calculated from the experimental data is about 0.67, which is slightly larger than the value (0.58) from the literature due to the impurities of the ion beam and target surface. The effect of suppressing the electron countercurrent by the self-bias method is analyzed. The result shows that the self-bias method can not only suppress the secondary electrons from target surface under ion beams bombardment, but also suppress the electron countercurrent resulting from the instability of the pulsed power source. (authors)

  6. The electronic structure of anodized and etched aluminum alloy surfaces

    Science.gov (United States)

    Mullins, W. M.; Averbach, B. L.

    1988-11-01

    Specimens of 6061 and 5052 aluminum alloys which had been anodized and etched by several commonly used procedures were examined by means of bias-reference X-ray photoelectron spectroscopy (XPS). The spectra were compared with those obtained from single crystals of pure aluminum oxides. The chemical shifts observed from the A12p surface oxide lines were interpreted as differences in the Fermi energy levels relative to those in the bulk oxide crystals, and the Fermi energy levels of the surface oxides were thus determined. Using an earlier experimental correlation obtained for values of the point of zero charge (pzc) with Fermi energy levels in aluminum oxide powders, a value of the pzc of the surface oxide was then determined. The surface exhibited the maximum alkalinity, pzc = 8.9, after a caustic etch, and the maximum acidity, pzc = 3.6, after a phosphoric acid anodizing treatment. The significance of these pzc values in the adhesive bonding of aluminum alloys is discussed.

  7. GSFLOW - Coupled Ground-Water and Surface-Water Flow Model Based on the Integration of the Precipitation-Runoff Modeling System (PRMS) and the Modular Ground-Water Flow Model (MODFLOW-2005)

    Science.gov (United States)

    Markstrom, Steven L.; Niswonger, Richard G.; Regan, R. Steven; Prudic, David E.; Barlow, Paul M.

    2008-01-01

    The need to assess the effects of variability in climate, biota, geology, and human activities on water availability and flow requires the development of models that couple two or more components of the hydrologic cycle. An integrated hydrologic model called GSFLOW (Ground-water and Surface-water FLOW) was developed to simulate coupled ground-water and surface-water resources. The new model is based on the integration of the U.S. Geological Survey Precipitation-Runoff Modeling System (PRMS) and the U.S. Geological Survey Modular Ground-Water Flow Model (MODFLOW). Additional model components were developed, and existing components were modified, to facilitate integration of the models. Methods were developed to route flow among the PRMS Hydrologic Response Units (HRUs) and between the HRUs and the MODFLOW finite-difference cells. This report describes the organization, concepts, design, and mathematical formulation of all GSFLOW model components. An important aspect of the integrated model design is its ability to conserve water mass and to provide comprehensive water budgets for a location of interest. This report includes descriptions of how water budgets are calculated for the integrated model and for individual model components. GSFLOW provides a robust modeling system for simulating flow through the hydrologic cycle, while allowing for future enhancements to incorporate other simulation techniques.

  8. Influence of the Electron-Electron Interaction in the Surface Valence Band on Low Energy Ion Scattering

    Science.gov (United States)

    Fomin, Vladimir M.; Devreese, Jozef T.

    1996-03-01

    The influence of the electron-electron interaction in the surface valence band on the low-energy ion scattering (LEIS) is investigated in the framework of the modified Muda---Newns approach. With this aim the Anderson-type electron-electron interaction term is taken into account in the Hamiltonian of the system and a resulting nonlinear set of equations of motion for the occupation number matrix is solved for various values of the effective electron-electron coupling constant U. It is demonstrated that for increasing U the steady-state value of the atomic level occupation number after the scattering increases. As a result, the ion survival probability is found, e. g., for the scattering of ^4He^+ ions from Cu to be a decreasing function of U. These results allow a consistent interpretation of the recent experimental data on low-energy He^+ ion scattering from metals. The work is supported by the C.E.C. Human Capital and Mobility Project "Quantification of Surface Analysis by Low Energy Ion Scattering". Also at the Technical University of Eindhoven, The Netherlands.

  9. Microstructure evolution during surface alloying of ductile iron and austempered ductile iron by electron beam melting

    Energy Technology Data Exchange (ETDEWEB)

    Gulzar, A. [Materials Division, Pakistan Institute of Nuclear Science and Technology, Nilore, Islamabad (Pakistan); Akhter, J.I. [Physics Division, Pakistan Institute of Nuclear Science and Technology, Nilore, Islamabad (Pakistan); Ahmad, M., E-mail: maqomer@yahoo.com [Physics Division, Pakistan Institute of Nuclear Science and Technology, Nilore, Islamabad (Pakistan); Ali, G. [Physics Division, Pakistan Institute of Nuclear Science and Technology, Nilore, Islamabad (Pakistan); Mahmood, M. [Department of Chemical and Materials Engineering, Pakistan Institute of Engineering and Applied Sciences, Islamabad (Pakistan); Ajmal, M. [Department of Metallurgical and Materials Engineering, University of Engineering and Technology, Lahore (Pakistan)

    2009-07-30

    Alloying and microstructural modification of surfaces by electron beam has become popular to tailor the surface properties of materials. Surface modification of as-received ductile iron, Ni-plated ductile iron and Ni-plated austempered ductile iron was carried out by electron beam melting to improve the surface properties. Martensitic structure evolved in the heat affected zone and ledeburite structure was produced in the molten zone of the ductile iron. Microhardness of the melted specimens enhanced considerably as compared to the as-received samples. However the microhardness of melted Ni-plated samples is lower than that of the unplated specimens. X-ray diffraction clearly revealed the formation of an austenite and Fe{sub 3}C phases in the electron beam molten zone. The broadening of peaks suggests refinement of the microstructure as well as internal stresses generated during electron beam melting.

  10. Quantum Nuclear Extension of Electron Nuclear Dynamics on Folded Effective-Potential Surfaces

    DEFF Research Database (Denmark)

    Hall, B.; Deumens, E.; Ohrn, Y.

    2014-01-01

    A perennial problem in quantum scattering calculations is accurate theoretical treatment of low energy collisions. We propose a method of extracting a folded, nonadiabatic, effective potential energy surface from electron nuclear dynamics (END) trajectories; we then perform nuclear wave packet...

  11. Probing the electronic transport on the reconstructed Au/Ge(001 surface

    Directory of Open Access Journals (Sweden)

    Franciszek Krok

    2014-09-01

    Full Text Available By using scanning tunnelling potentiometry we characterized the lateral variation of the electrochemical potential µec on the gold-induced Ge(001-c(8 × 2-Au surface reconstruction while a lateral current flows through the sample. On the reconstruction and across domain boundaries we find that µec shows a constant gradient as a function of the position between the contacts. In addition, nanoscale Au clusters on the surface do not show an electronic coupling to the gold-induced surface reconstruction. In combination with high resolution scanning electron microscopy and transmission electron microscopy, we conclude that an additional transport channel buried about 2 nm underneath the surface represents a major transport channel for electrons.

  12. Relation between bulk compressibility and surface energy of electron-hole liquids

    International Nuclear Information System (INIS)

    Singwi, K.S.; Tosi, M.P.

    1979-08-01

    Attention is drawn to the existence of an empirical relation chiσ/asup(*)sub(B) approximately 1 between the compressibility, the surface energy and the excitonic radius in electron-hole liquids. (author)

  13. Simulação do deflúvio e vazão de pico em microbacia hidrográfica com escoamento efêmero Surface runoff and peak discharge simulation in ephemeral watershed

    Directory of Open Access Journals (Sweden)

    Carlos R. Mello

    2007-08-01

    Full Text Available A predição da resposta hidrológica em microbacias hidrográficas a partir de diferentes usos do solo é de fundamental importância para nortear ações de manejo ambiental, razão por que se objetivou, neste trabalho, desenvolver, em primeira mão, uma modelagem hidrológica para predizer o deflúvio total e a vazão de pico em uma microbacia hidrográfica experimental, de escoamento efêmero, ocupada por eucalipto e pastagem, e após esta etapa, aplicá-la a diferentes cenários de ocupação da microbacia por ambas as coberturas vegetais, estimando-se as respostas hidrológicas das situações simuladas. O monitoramento hidrológico foi realizado entre novembro/02 e abril/03, por meio de estação meteorológica e calha Parshall, conjugada a linígrafo automático. A umidade do solo foi monitorada a cada 2 dias, em 3 profundidades (20, 50 e 80 cm, em 8 pontos na área ocupada por pastagem e 4 na área com eucalipto. A modelagem mostrou-se precisa e eficaz aos objetivos propostos de predição em diferentes cenários de uso e ocupação do solo. Verificou-se que, se a microbacia for ocupada por 80% de eucalipto, haverá redução do deflúvio em 29%, constatando-se ainda, redução substancial da vazão de pico; verificou-se também que a umidade do solo é fundamental no processo, especialmente para pequenas vazões, no início e no final do período chuvoso e após veranicos e que, para vazões mais elevadas, as características da precipitação são determinantes.The prediction of hydrological responses in a microbasin from different soil uses is of fundamental importance to develop actions to minimize environmental impacts. This work aimed to develop and to apply hydrological modeling for predicting surface runoff and peak discharge in experimental tropical ephemeral watershed occupied by eucalyptus and grasses, creating different soil use scenarios. Hydrological monitoring was performed between November/2002 and April/2003, using

  14. Auger electron spectroscopy of the surface of a pipe-like solid C60+18n

    International Nuclear Information System (INIS)

    Khvostov, V.V.; Chernozatonskij, L.A.; Kosakovskaya, Z.Ya.; Babaev, V.V.; Guseva, M.B.

    1992-01-01

    Auger and electron energy loss spectra obtained when probing the surface of nanofiber carbon material by an electron beam point out to C 60 football-type of covers with the outlet to the surface of nanopipe carbon molecules

  15. Self-consistent electronic structure of the contracted tungsten (001) surface

    International Nuclear Information System (INIS)

    Posternak, M.; Krakauer, H.; Freeman, A.J.

    1982-01-01

    Self-consistent linearized-augmented-plane-wave energy-band studies using the warped muffin-tin approximation for a seven-layer W(001) single slab with the surface-layer separation contracted by 6% of the bulk interlayer spacing are reported. Surface electronic structure, local densities of states, generalized susceptibility for the surface, work function, and core-level shifts are found to have insignificant differences with corresponding results for the unrelaxed surface. Several differences in surface states between theory and recent angle-resolved photoemission experiments are discussed in the light of new proposed models of the actual unreconstructed surface structure at high temperatures

  16. Metal substrates with nanometer scale surface roughness for flexible electronics

    Science.gov (United States)

    Lee, Jong-Lam; Kim, Kisoo

    2012-09-01

    In this work, we present a novel way in fabricating a metal substrate with nanometer scale in surface roughness (Ra INVAR (Invariable alloy) one (20 cm × 20 cm, Ra = 1.40 nm) were demonstrated. The INVAR film was used as a substrate for fabricating organic light emitting diodes (OLED) and organic photovoltaic (OPV). The optical and electrical characteristics of OLEDs and OPVs using the INVAR were comparable to those using a conventional ITO glass substrate.

  17. Electronic structure, molecular bonding and potential energy surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Ruedenberg, K. [Ames Laboratory, IA (United States)

    1993-12-01

    By virtue of the universal validity of the generalized Born-Oppenheimer separation, potential energy surfaces (PES`) represent the central conceptual as well as quantitative entities of chemical physics and provide the basis for the understanding of most physicochemical phenomena in many diverse fields. The research in this group deals with the elucidation of general properties of PES` as well as with the quantitative determination of PES` for concrete systems, in particular pertaining to reactions involving carbon, oxygen, nitrogen and hydrogen molecules.

  18. Two-dimensional simulation research of secondary electron emission avalanche discharge on vacuum insulator surface

    Science.gov (United States)

    Cai, Libing; Wang, Jianguo; Zhu, Xiangqin; Wang, Yue; Zhang, Dianhui

    2015-01-01

    Based on the secondary electron emission avalanche (SEEA) model, the SEEA discharge on the vacuum insulator surface is simulated by using a 2D PIC-MCC code developed by ourselves. The evolutions of the number of discharge electrons, insulator surface charge, current, and 2D particle distribution are obtained. The effects of the strength of the applied electric field, secondary electron yield coefficient, rise time of the pulse, length of the insulator on the discharge are investigated. The results show that the number of the SEEA electrons presents a quadratic dependence upon the applied field strength. The SEEA current, which is on the order of Ampere, is directly proportional to the field strength and secondary electron yield coefficient. Finally, the electron-stimulated outgassing is included in the simulation code, and a three-phase discharge curve is presented by the simulation, which agrees with the experimental data.

  19. Two-dimensional simulation research of secondary electron emission avalanche discharge on vacuum insulator surface

    International Nuclear Information System (INIS)

    Cai, Libing; Wang, Jianguo; Zhu, Xiangqin; Wang, Yue; Zhang, Dianhui

    2015-01-01

    Based on the secondary electron emission avalanche (SEEA) model, the SEEA discharge on the vacuum insulator surface is simulated by using a 2D PIC-MCC code developed by ourselves. The evolutions of the number of discharge electrons, insulator surface charge, current, and 2D particle distribution are obtained. The effects of the strength of the applied electric field, secondary electron yield coefficient, rise time of the pulse, length of the insulator on the discharge are investigated. The results show that the number of the SEEA electrons presents a quadratic dependence upon the applied field strength. The SEEA current, which is on the order of Ampere, is directly proportional to the field strength and secondary electron yield coefficient. Finally, the electron-stimulated outgassing is included in the simulation code, and a three-phase discharge curve is presented by the simulation, which agrees with the experimental data

  20. Electron work function and composition of gallium-indium alloy surface

    International Nuclear Information System (INIS)

    Egorova, E.M.

    1979-01-01

    The dependences of electron work functions on the composition for gallium-indium alloy obtained under different conditions are compared. An attempt is made to estimate a change in the alloy surface composition caused by a change in temperature and in the boundary phase nature. For the case under consideration it has been shown to be reasonable to compare the dependences of the electron work functions not on the alloy volumetric composition but on the composition of its surface

  1. Application of GIS in Modeling Zilberchai Basin Runoff

    Science.gov (United States)

    Malekani, L.; Khaleghi, S.; Mahmoodi, M.

    2014-10-01

    Runoff is one of most important hydrological variables that are used in many civil works, planning for optimal use of reservoirs, organizing rivers and warning flood. The runoff curve number (CN) is a key factor in determining runoff in the SCS (Soil Conservation Service) based hydrologic modeling method. The traditional SCS-CN method for calculating the composite curve number consumes a major portion of the hydrologic modeling time. Therefore, geographic information systems (GIS) are now being used in combination with the SCS-CN method. This work uses a methodology of determining surface runoff by Geographic Information System model and applying SCS-CN method that needs the necessary parameters such as land use map, hydrologic soil groups, rainfall data, DEM, physiographic characteristic of the basin. The model is built by implementing some well known hydrologic methods in GIS like as ArcHydro, ArcCN-Runoff for modeling of Zilberchai basin runoff. The results show that the high average weighted of curve number indicate that permeability of the basin is low and therefore likelihood of flooding is high. So the fundamental works is essential in order to increase water infiltration in Zilberchai basin and to avoid wasting surface water resources. Also comparing the results of the computed and observed runoff value show that use of GIS tools in addition to accelerate the calculation of the runoff also increase the accuracy of the results. This paper clearly demonstrates that the integration of GIS with the SCS-CN method provides a powerful tool for estimating runoff volumes in large basins.

  2. Effects of electronic correlation, physical structure, and surface termination on the electronic structure of V2O3 nanowires

    Science.gov (United States)

    Tiano, Amanda L.; Li, Jing-bin; Sutter, Eli; Wong, Stanislaus S.; Fernández-Serra, M.-V.

    2012-09-01

    We report on a density functional theory (DFT) study of the electronic structure of vanadium sesquioxide (V2O3) in both bulk and nanowire form. In particular, our study focuses on the role of spin polarization and electronic correlations, as computed within the local (spin) density approximation (L(S)DA) and the LDA+U formalism. As expected for a mean-field approach such as DFT, our optimized bulk V2O3 structure is shown to be metallic in nature, while an adequate choice of the Hubbard U parameter (U = 4 eV) is enough to open the band gap, making the system insulating. However, this formalism predicts a nonmagnetic insulator, as opposed to the experimentally observed antiferromagnetic structure, to be the ground state. The electronic structure of the V2O3 nanowire system is more complex, and it strongly depends on the surface termination of the structures. Our results show that non-spin-polarized LDA calculations of 001-grown nanowires are metallic in nature. However, LSDA predicts that some surface terminations are half-metals, with a large band gap opening for one of the spins. When LSDA+U was used to study the nanowire model with a closed-shell oxygen surface termination, we observe insulating behavior with no net magnetic moment, with a 104 meV band gap. This is consistent with the experimentally observed gap recently reported in the literature for similar wires. To experimentally address the surface structure of these nanowires, we perform surface specific nano-Auger electron spectroscopy on as-synthesized V2O3 nanowires. Our experimental results show a higher O:V peak ratio (1.93:1) than expected for pure V2O3, thereby suggesting higher oxygen content at the surface of the nanowires. From our results, we conclude that oxygen termination is likely the termination for our as-synthesized V2O3 nanowires.

  3. Influence on rod-pinch diode performance of suppressing electron emission from different cathode surfaces

    International Nuclear Information System (INIS)

    Gao Yi; Lv Min; Qiu Aici; Yang Hailiang; Liang Tianxue; Zhang Zhong

    2010-01-01

    The electron pinching process of a rod-pinch diode is simulated with UNIPIC. It indicates that the pinching characteristics of the electrons emitted from different cathode surfaces differ significantly. The electrons emitted from the downstream surface pinch worst, with large amount of electrons hitting upstream of the rod, which increases the axial bremsstrahlung X-ray spot size. The simulation results show that suppressing electron emission from the downstream surface will reduce the axial X-ray spot size and improve the pinching quality. Composite cathodes are designed to investigate the influence of suppressing electron emission from the upstream or downstream surface. Experiments are performed on the new-built IVA (Inductive Voltage Adder) device at the peak voltage of ∼1.5 MV, and the peak current of ∼44 kA. It is shown that the composite cathode is effective in suppressing electron emission from the specific surface, the axial X-ray spot size in the case of downstream suppression is about 14.5% less than the case of upstream suppression and in both cases, the axis-on X-ray dose at 1 meter from the rod tip is ∼1.9rads, validating the simulation results. (authors)

  4. Surface sensitization mechanism on negative electron affinity p-GaN nanowires

    Science.gov (United States)

    Diao, Yu; Liu, Lei; Xia, Sihao; Feng, Shu; Lu, Feifei

    2018-03-01

    The surface sensitization is the key to prepare negative electron affinity photocathode. The thesis emphasizes on the study of surface sensitization mechanism of p-type doping GaN nanowires utilizing first principles based on density function theory. The adsorption energy, work function, dipole moment, geometry structure, electronic structure and optical properties of Mg-doped GaN nanowires surfaces with various coverages of Cs atoms are investigated. The GaN nanowire with Mg doped in core position is taken as the sensitization base. At the initial stage of sensitization, the best adsorption site for Cs atom on GaN nanowire surface is BN, the bridge site of two adjacent N atoms. Surface sensitization generates a p-type internal surface with an n-type surface state, introducing a band bending region which can help reduce surface barrier and work function. With increasing Cs coverage, work functions decrease monotonously and the "Cs-kill" phenomenon disappears. For Cs coverage of 0.75 ML and 1 ML, the corresponding sensitization systems reach negative electron affinity state. Through surface sensitization, the absorption curves are red shifted and the absorption coefficient is cut down. All theoretical calculations can guide the design of negative electron affinity Mg doped GaN nanowires photocathode.

  5. Calculating the SnS(010) surface electronic structure using the green function method

    Science.gov (United States)

    Jahangirli, Z. A.

    2011-08-01

    The electronic structure of the (010) surface in a layered SnS semiconductor terminating with Sn and S atomic planes is calculated by the Green function method. The electronic structure of a perfect crystal is calculated according to the linear combination of atomic orbitals (LCAO) using Slater s-, p-, and d-orbitals. Defect-induced changes in the density of states and the origin and orbital composition of electronic states in the band gap are discussed.

  6. Electronic transport at semiconductor surfaces - from point-contact transistor to micro-four-point probes

    DEFF Research Database (Denmark)

    Hasegawa, S.; Grey, Francois

    2002-01-01

    show that this type of conduction is measurable using new types of experimental probes, such as the multi-tip scanning tunnelling microscope and the micro-four-point probe. The resulting electronic transport properties are intriguing, and suggest that semiconductor surfaces should be considered......The electrical properties of semiconductor surfaces have played a decisive role in one of the most important discoveries of the last century, transistors. In the 1940s, the concept of surface states-new electron energy levels characteristic of the surface atoms-was instrumental in the fabrication...... of the first point-contact transistors, and led to the successful fabrication of field-effect transistors. However, to this day, one property of semiconductor surface states remains poorly understood, both theoretically and experimentally. That is the conduction of electrons or holes directly through...

  7. Ionic liquids influence on the surface properties of electron beam irradiated wood

    International Nuclear Information System (INIS)

    Croitoru, Catalin; Patachia, Silvia; Doroftei, Florica; Parparita, Elena; Vasile, Cornelia

    2014-01-01

    Highlights: • Wood veneers impregnated with three imidazolium-based ionic liquids and irradiated with electron beam were studied by FTIR-ATR, SEM/EDX, AFM, contact angle and image analysis. • ILs preserve the surface properties of the wood (surface energy, roughness, color) upon irradiation, in comparison with the reference wood, but the surface composition is changed by treatment with IL-s, mainly with 1-butyl-3-methylimidazolium tetrafluoroborate. • Under electron beam irradiation covalent bonding of the imidazolium moiety to wood determines a higher resistance to water penetration and spreading on the surface. - Abstract: In this paper, the influence of three imidazolium-based ionic liquids (1-butyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium hexafluorophosphate and 1-hexyl-3-methylimidazolium chloride) on the structure and surface properties of sycamore maple (Acer pseudoplatanus) veneers submitted to electron beam irradiation with a dose of 50 kGy has been studied by using Fourier transform infrared spectroscopy, as well as image, scanning electron microscopy/SEM/EDX, atomic force microscopy and contact angle analysis. The experimental results have proven that the studied ionic liquids determine a better preservation of the structural features of wood (cellulose crystallinity index and lignin concentration on the surface) as well as some of surface properties such as surface energy, roughness, color upon irradiation with electron beam, in comparison with the reference wood, but surface composition is changed by treatment with imidazolium-based ionic liquids mainly with 1-butyl-3-methylimidazolium tetrafluoroborate. Also, under electron beam irradiation covalent bonding of the imidazolium moiety to wood determines a higher resistance to water penetration and spreading on the surface

  8. Snowmelt Runoff: A New Focus of Urban Nonpoint Source Pollution

    Science.gov (United States)

    Zhu, Hui; Xu, Yingying; Yan, Baixing; Guan, Jiunian

    2012-01-01

    Irregular precipitation associated with global climate change had been causing various problems in urban regions. Besides the runoff due to rainfall in summer, the snowmelt runoff in early spring could also play an important role in deteriorating the water quality of the receiving waters. Due to global climate change, the snowfall has increased gradually in individual regions, and snowstorms occur more frequently, which leads to an enhancement of snowmelt runoff flow during the melting seasons. What is more, rivers just awaking from freezing cosntitute a frail ecosystem, with poor self-purification capacity, however, the urban snowmelt runoff could carry diverse pollutants accumulated during the winter, such as coal and/or gas combustion products, snowmelting agents, automotive exhaust and so on, which seriously threaten the receiving water quality. Nevertheless, most of the research focused on the rainfall runoff in rainy seasons, and the study on snowmelt runoff is still a neglected field in many countries and regions. In conclusion, due to the considerable water quantity and the worrisome water quality, snowmelt runoff in urban regions with large impervious surface areas should be listed among the important targets in urban nonpoint source pollution management and control. PMID:23202881

  9. MIS hot electron devices for enhancement of surface reactivity by hot electrons

    DEFF Research Database (Denmark)

    Thomsen, Lasse Bjørchmar

    is monitored using the calibrated resistance of the metal layer. The MIS hot electron emitters are cleaned in-situ in a background pressure of 3 £ 10¡7 mbar O2. Thermal desorption experiments with labeled CO are carried out with a reproducibility of 7%. The detection limit of labeled CO for the mass...... spectrometer setup is estimated to 3 £ 109 s¡1 from the desorption experiments. The theoretical hot electron induced desorption rate is estimated to 2£104 s¡1....

  10. Modeling the process of interaction of 10 keV electrons with a plane dielectric surface

    Science.gov (United States)

    Vokhmyanina, Kristina; Sotnikova, Valentina; Sotnikov, Alexey; Kaplii, Anna; Nikulicheva, Tatyana; Kubankin, Alexandr; Kishin, Ivan

    2018-05-01

    The effect of guiding of charged particles by dielectric channels is of noticeable interest at the present time. The phenomenon is widely studied experimentally and theoretically but some points still need to be clarified. A previously developed model of interaction of fast electrons with dielectric surface at grazing incidence is used to study the independence of electron deflection on the value of electron beam current. The calculations were performed assuming a smooth dependence of the surface conductivity on the beam current in the 40-3000 nA range.

  11. Electronic and structural characterizations of unreconstructed {0001} surfaces and the growth of graphene overlayers

    International Nuclear Information System (INIS)

    Emtsev, Konstantin

    2009-01-01

    The present work is focused on the characterization of the clean unreconstructed SiC{0001} surfaces and the growth of graphene overlayers thereon. Electronic properties of SiC surfaces and their interfaces with graphene and few layer graphene films were investigated by means of angle resolved photoelectron spectroscopy, X-ray photoelectron spectroscopy and low energy electron diffraction. Structural characterizations of the epitaxial graphene films grown on SiC were carried out by atomic force microscopy and low energy electron microscopy. Supplementary data was obtained by scanning tunneling microscopy. (orig.)

  12. Lateral propagation of fast electrons at the laser-irradiated target surfaces

    International Nuclear Information System (INIS)

    Li, Y T; Lin, X X; Liu, B C; Du, F; Wang, S J; Li, C; Zhou, M L; Zhang, L; Liu, X; Wang, J; Liu, X L; Chen, L M; Wang, Z H; Ma, J L; Wei, Z Y; Zhang, J; Liu, F; Liu, F

    2010-01-01

    Lateral propagation of fast electrons at the target surfaces irradiated by femtosecond intense laser pulses is measured by k α x-ray imaging technique when a preplasma is presented. An annular halo surrounding a bright spot is observed in the x-ray images when the scale length of the electron density is large. For an incidence angle of 70 0 the x-ray images show a non-symmetrical distribution peaked to the laser propagation direction. The x-ray photons in the halo are mainly excited by the fast electrons that flow in the preplasma when their paths intersect the high density regions near the target surface.

  13. New electron-ion-plasma equipment for modification of materials and products surface

    International Nuclear Information System (INIS)

    Koval', N.N.

    2013-01-01

    Electron-ion-plasma treatment of materials and products, including surface clearing and activation, formation surface layers with changed chemical and phase structure, increased hardness and corrosion resistance; deposition of various functional coatings, has received a wide distribution in a science and industry. Widespread methods of ion-plasma modification of material and product surfaces are ion etching and activation, ion-plasma nitriding, arc or magnetron deposition of functional coatings, including nanostructured. The combination of above methods of surface modification allows essentially to improve exploitation properties of treated products and to optimize the characteristics of modified surfaces for concrete final requirements. For the purpose of a combination of various methods of ion-plasma treatment in a single work cycle at Institute of High Current Electronics of SB RAS (IHCE SB RAS) specialized technological equipment 'DUET', 'TRIO' and 'QUADRO' and 'KVINTA' have been developed. This equipment allow generating uniform low-temperature gas plasma at pressures of (0.1-1) Pa with concentration of (10 9 -10 11 ) cm -3 in volume of (0.1-1) m 3 . In the installations consistent realization of several various operations of materials and products treatment in a single work cycle is possible. The operations are preliminary heating and degassing, ion clearing, etching and activation of materials and products surface by plasma of arc discharges; chemicothermal treatment (nitriding) for formation of diffusion layer on a surface of treated sample using plasma of nonself-sustained low-pressure arc discharge; deposition of single- or multilayered superhard (≥40 GPa) nanocrystalline coatings on the basis of pure metals or their compounds (nitrides, carbides, carbonitrides) by the arc plasma-assisted method. For realization of the modes all installations are equipped by original sources of gas and metal plasma. Besides, in

  14. Functional nanostructured materials for stormwater runoff treatment

    DEFF Research Database (Denmark)

    Ko, Dongah

    metal sorption behaviour. Although COP-63 has a moderate surface area, it demonstrated cadmium removal efficiency equivalent to highly porous activated carbon (AC), while it also exhibited 16 times faster sorption kinetics compared to AC, owing to high affinity towards disulphide and thiol functionality......Numerous heavy metal removal practices for stormwater runoff have been studied and applied; however, there is still room for improvement. Among these practices, adsorption has proven to be the most efficient way of removing heavy metals. Commonly used adsorbents have an innate sorption capacity...... in relation to high concentrations of heavy metal ions, but if they are to be used for stormwater runoff, high affinity with rapid sorption kinetics for low concentrations of heavy metals is necessary. Therefore, in this study, new types of functional nanostructured polymer sorbents for effective heavy metal...

  15. Applications of low-energy electron diffraction to ordering at crystal and quasicrystal surfaces

    International Nuclear Information System (INIS)

    McRae, E.G.; Malic, R.A.

    1990-01-01

    The ability to measure low-energy electron diffraction (LEED) intensity profiles has been enhanced by use of low-current well-defined primary electron beams in conjunction with position-sensitive detection (PSD) of the diffracted electrons. The following are examples of applications of LEED-PSD. Compositional ordering at ordering alloy Cu 3 Au (100) and (110) surfaces - the ordering of the (100) surface is believed to conform to a conventional picture in which the already-ordered bulk acts as a template, but the profiles measured in the course of ordering of the (110) surface are of the shapes expected if the ordering occurred first at the surface. Disordering of Ge(111) surface 150 K below the bulk melting temperature - the intensities and profiles are inconsistent with surface melting or roughening, but a model based on molecular dynamics simulations is not ruled out. Order and disordering at decagonal quasicrystal Al 65 Cu 15 Co 20 surfaces - at room temperature the quasicrystalline order is well developed at both the 'ten-fold' surface (perpendicular to the ten-fold surface (perpendicular to the ten-fold periodic axis) and a 'two-fold' one (parallel to the ten-fold axis) as evidenced by narrow beam profiles. The ten-fold surface undergoes a disordering transition at 700 K, but the temperature dependence of the profiles is unlike that expected for the roughening transition anticipated theoretically. 57 refs., 15 figs

  16. Electron density in reasonably real metallic surfaces, including interchange and correlation effects

    International Nuclear Information System (INIS)

    Moraga, L.A.; Martinez, G.

    1981-01-01

    By means of a new method, the electron density in a jellium surface is calculated taking in account interchange and correlation effects; reproducing, in this way, the Lang and Kohn results. The new method is self-consistent but not iterative and hence is possible extend it to the solution of the same problem in more reasonably real metallic surfaces. (L.C.) [pt

  17. Reduction of secondary electron yield for E-cloud mitigation by laser ablation surface engineering

    Energy Technology Data Exchange (ETDEWEB)

    Valizadeh, R., E-mail: reza.valizadeh@stfc.ac.uk [ASTeC, STFC Daresbury Laboratory, Warrington WA4 4AD (United Kingdom); Malyshev, O.B. [ASTeC, STFC Daresbury Laboratory, Warrington WA4 4AD (United Kingdom); Wang, S. [ASTeC, STFC Daresbury Laboratory, Warrington WA4 4AD (United Kingdom); Department of Physics, Loughborough University, Loughborough LE11 3TU (United Kingdom); Sian, T. [ASTeC, STFC Daresbury Laboratory, Warrington WA4 4AD (United Kingdom); The Photon Science Institute, The University of Manchester, Manchester M13 9PL (United Kingdom); Cropper, M.D. [Department of Physics, Loughborough University, Loughborough LE11 3TU (United Kingdom); Sykes, N. [Micronanics Ltd., Didcot, Oxon OX11 0QX (United Kingdom)

    2017-05-15

    Highlights: • SEY below 1 can be achieved with Laser ablation surface engineering. • SEY <1 surface can be produced with different types of nanosecond lasers. • Both microstructure (groves) and nano-structures are playing a role in reducing SEY. - Abstract: Developing a surface with low Secondary Electron Yield (SEY) is one of the main ways of mitigating electron cloud and beam-induced electron multipacting in high-energy charged particle accelerators. In our previous publications, a low SEY < 0.9 for as-received metal surfaces modified by a nanosecond pulsed laser was reported. In this paper, the SEY of laser-treated blackened copper has been investigated as a function of different laser irradiation parameters. We explore and study the influence of micro- and nano-structures induced by laser surface treatment in air of copper samples as a function of various laser irradiation parameters such as peak power, laser wavelength (λ = 355 nm and 1064 nm), number of pulses per point (scan speed and repetition rate) and fluence, on the SEY. The surface chemical composition was determined by x-ray photoelectron spectroscopy (XPS) which revealed that heating resulted in diffusion of oxygen into the bulk and induced the transformation of CuO to sub-stoichiometric oxide. The surface topography was examined with high resolution scanning electron microscopy (HRSEM) which showed that the laser-treated surfaces are dominated by microstructure grooves and nanostructure features.

  18. Direct observation of surface reconstruction and termination on a complex metal oxide catalyst by electron microscopy

    KAUST Repository

    Zhu, Yihan

    2012-03-19

    On the surface: The surface reconstruction of an MoVTeO complex metal oxide catalyst was observed directly by various electron microscopic techniques and the results explain the puzzling catalytic behavior. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Electronic interconnects and devices with topological surface states and methods for fabricating same

    Energy Technology Data Exchange (ETDEWEB)

    Yazdani, Ali; Ong, N. Phuan; Cava, Robert J.

    2016-05-03

    An interconnect is disclosed with enhanced immunity of electrical conductivity to defects. The interconnect includes a material with charge carriers having topological surface states. Also disclosed is a method for fabricating such interconnects. Also disclosed is an integrated circuit including such interconnects. Also disclosed is a gated electronic device including a material with charge carriers having topological surface states.

  20. Electronic interconnects and devices with topological surface states and methods for fabricating same

    Energy Technology Data Exchange (ETDEWEB)

    Yazdani, Ali; Ong, N. Phuan; Cava, Robert J.

    2017-04-04

    An interconnect is disclosed with enhanced immunity of electrical conductivity to defects. The interconnect includes a material with charge carriers having topological surface states. Also disclosed is a method for fabricating such interconnects. Also disclosed is an integrated circuit including such interconnects. Also disclosed is a gated electronic device including a material with charge carriers having topological surface states.

  1. Variability of Measured Runoff and Soil Loss from Field Plots

    Directory of Open Access Journals (Sweden)

    F. Asadzadeh

    2016-02-01

    Full Text Available Introduction: Field plots are widely used in studies related to the measurements of soil loss and modeling of erosion processes. Research efforts are needed to investigate factors affecting the data quality of plots. Spatial scale or size of plots is one of these factors which directly affects measuring runoff and soil loss by means of field plots. The effect of plot size on measured runoff or soil loss from natural plots is known as plot scale effect. On the other hand, variability of runoff and sediment yield from replicated filed plots is a main source of uncertainty in measurement of erosion from plots which should be considered in plot data interpretation processes. Therefore, there is a demand for knowledge of soil erosion processes occurring in plots of different sizes and of factors that determine natural variability, as a basis for obtaining soil loss data of good quality. This study was carried out to investigate the combined effects of these two factors by measurement of runoff and soil loss from replicated plots with different sizes. Materials and Methods: In order to evaluate the variability of runoff and soil loss data seven plots, differing in width and length, were constructed in a uniform slope of 9% at three replicates at Koohin Research Station in Qazvin province. The plots were ploughed up to down slope in September 2011. Each plot was isolated using soil beds with a height of 30 cm, to direct generated surface runoff to the lower part of the plots. Runoff collecting systems composed of gutters, pipes and tankswere installed at the end of each plot. During the two-year study period of 2011-2012, plots were maintained in bare conditions and runoff and soil loss were measured for each single event. Precipitation amounts and characteristics were directly measured by an automatic recording tipping-bucket rain gauge located about 200 m from the experimental plots. The entire runoff volume including eroded sediment was measured on

  2. Micro-Shaping of Nanopatterned Surfaces by Electron Beam Irradiation

    Directory of Open Access Journals (Sweden)

    Carlos Angulo Barrios

    2016-04-01

    Full Text Available We show that planar nanopatterned thin films on standard polycarbonate (PC compact discs (CD can be micro-shaped in a non-contact manner via direct e-beam exposure. The shape of the film can be controlled by proper selection of the e-beam parameters. As an example of application, we demonstrate a two-dimensional (2D array of micro-lenses/reservoirs conformally covered by an Al 2D nanohole array (NHA film on a PC CD substrate. It is also shown that such a curvilinear Al NHA layer can be easily transferred onto a flexible polymeric support. The presented technique provides a new tool for creating lab-on-CD architectures and developing multifunctional (flexible non-planar nanostructured films and surfaces.

  3. Surface buckling of black phosphorus: Determination, origin, and influence on electronic structure

    Science.gov (United States)

    Dai, Zhongwei; Jin, Wencan; Yu, Jie-Xiang; Grady, Maxwell; Sadowski, Jerzy T.; Kim, Young Duck; Hone, James; Dadap, Jerry I.; Zang, Jiadong; Osgood, Richard M.; Pohl, Karsten

    2017-12-01

    The surface structure of black phosphorus materials is determined using surface-sensitive dynamical microspot low energy electron diffraction (μ LEED ) analysis using a high spatial resolution low energy electron microscopy (LEEM) system. Samples of (i) crystalline cleaved black phosphorus (BP) at 300 K and (ii) exfoliated few-layer phosphorene (FLP) of about 10 nm thickness which were annealed at 573 K in vacuum were studied. In both samples, a significant surface buckling of 0.22 Å and 0.30 Å, respectively, is measured, which is one order of magnitude larger than previously reported. As direct evidence for large buckling, we observe a set of (for the flat surface forbidden) diffraction spots. Using first-principles calculations, we find that the presence of surface vacancies is responsible for the surface buckling in both BP and FLP, and is related to the intrinsic hole doping of phosphoresce materials previously reported.

  4. Highly collimated monoenergetic target-surface electron acceleration in near-critical-density plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Mao, J. Y. [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, CAS, Beijing 100190 (China); Department of Physics and Research Center OPTIMAS, University of Kaiserslautern, Kaiserslautern 67663 (Germany); Chen, L. M., E-mail: lmchen@iphy.ac.cn [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, CAS, Beijing 100190 (China); IFSA Collaborative Innovation Center, Shanghai Jiao Tong University, Shanghai 200240 (China); Huang, K.; Ma, Y.; Zhao, J. R.; Yan, W. C.; Ma, J. L.; Wei, Z. Y. [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, CAS, Beijing 100190 (China); Li, D. Z. [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, CAS, Beijing 100190 (China); Institute of High Energy Physics, CAS, Beijing 100049 (China); Aeschlimann, M. [Department of Physics and Research Center OPTIMAS, University of Kaiserslautern, Kaiserslautern 67663 (Germany); Zhang, J. [Laboratory for Laser Plasmas (Ministry of Education) and Department of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240 (China)

    2015-03-30

    Optimized-quality monoenergetic target surface electron beams at MeV level with low normalized emittance (0.03π mm mrad) and high charge (30 pC) per shot have been obtained from 3 TW laser-solid interactions at a grazing incidence. The 2-Dimension particle-in-cell simulations suggest that electrons are wake-field accelerated in a large-scale, near-critical-density preplasma. It reveals that a bubble-like structure as an accelerating cavity appears in the near-critical-density plasma region and travels along the target surface. A bunch of electrons are pinched transversely and accelerated longitudinally by the wake field in the bubble. The outstanding normalized emittance and monochromaticity of such highly collimated surface electron beams could make it an ideal beam for fast ignition or may serve as an injector in traditional accelerators.

  5. Electronic structure and band alignment of 9,10-phenanthrenequinone passivated silicon surfaces

    Science.gov (United States)

    Avasthi, Sushobhan; Qi, Yabing; Vertelov, Grigory K.; Schwartz, Jeffrey; Kahn, Antoine; Sturm, James C.

    2011-07-01

    In this work we demonstrate that the room-temperature deposition of the organic molecule 9,10-phenanthrenequinone (PQ) reduces the surface defect density of the silicon (100) surface by chemically bonding to the surface dangling bonds. Using various spectroscopic measurements we have investigated the electronic structure and band alignment properties of the PQ/Si interface. The band-bending at the PQ-passivated silicon surface is negligible for both n- and p-type substrates, demonstrating a low density of surface defects. Finally we show that PQ forms a semiconducting wide-bandgap type-I heterojunction with silicon.

  6. Scanning electron microscopy study of protein immobilized on SIO2 Sol-gel surfaces

    Directory of Open Access Journals (Sweden)

    Assis O.B.G.

    2003-01-01

    Full Text Available Uniform attachment of enzymes to solid surfaces is essential in the development of bio and optical sensor devices. Immobilization by adsorption according to hydrophilic or hydrophobic nature is dependent on the charges and defects of the support surfaces. Sol-gel SiO2 densified glass surfaces, frequently used as supports for protein immobilization, are evaluated via scanning electron microscopy. The model protein is globular enzyme lysozyme, deposited by adsorption on functionalized surfaces. Formation of a protein layer is confirmed by FTIR spectroscopy, and the SEM images suggest discontinuous adsorption in areas where cracks predominate on the glass surface.

  7. Chemical, electronic, and magnetic structure of LaFeCoSi alloy: Surface and bulk properties

    Energy Technology Data Exchange (ETDEWEB)

    Lollobrigida, V. [Dipartimento di Scienze, Università Roma Tre, I-00146 Rome (Italy); Dipartimento di Matematica e Fisica, Università Roma Tre, I-00146 Rome (Italy); Basso, V.; Kuepferling, M.; Coïsson, M.; Olivetti, E. S.; Celegato, F. [Istituto Nazionale di Ricerca Metrologica (INRIM), I-10135 Torino (Italy); Borgatti, F. [CNR, Istituto per lo Studio dei Materiali Nanostrutturati (ISMN), I-40129 Bologna (Italy); Torelli, P.; Panaccione, G. [CNR, Istituto Officina dei Materiali (IOM), Lab. TASC, I-34149 Trieste (Italy); Tortora, L. [Laboratorio di Analisi di Superficie, Dipartimento di Matematica e Fisica, Università Roma Tre, I-00146 Rome (Italy); Dipartimento di Ingegneria Meccanica, Università Tor Vergata, I-00133 Rome (Italy); Stefani, G.; Offi, F. [Dipartimento di Scienze, Università Roma Tre, I-00146 Rome (Italy)

    2014-05-28

    We investigate the chemical, electronic, and magnetic structure of the magnetocaloric LaFeCoSi compound with bulk and surface sensitive techniques. We put in evidence that the surface retains a soft ferromagnetic behavior at temperatures higher than the Curie temperature of the bulk due to the presence of Fe clusters at the surface only. This peculiar magnetic surface effect is attributed to the exchange interaction between the ferromagnetic Fe clusters located at the surface and the bulk magnetocaloric alloy, and it is used here to monitor the magnetic properties of the alloy itself.

  8. Chemical, electronic, and magnetic structure of LaFeCoSi alloy: Surface and bulk properties

    International Nuclear Information System (INIS)

    Lollobrigida, V.; Basso, V.; Kuepferling, M.; Coïsson, M.; Olivetti, E. S.; Celegato, F.; Borgatti, F.; Torelli, P.; Panaccione, G.; Tortora, L.; Stefani, G.; Offi, F.

    2014-01-01

    We investigate the chemical, electronic, and magnetic structure of the magnetocaloric LaFeCoSi compound with bulk and surface sensitive techniques. We put in evidence that the surface retains a soft ferromagnetic behavior at temperatures higher than the Curie temperature of the bulk due to the presence of Fe clusters at the surface only. This peculiar magnetic surface effect is attributed to the exchange interaction between the ferromagnetic Fe clusters located at the surface and the bulk magnetocaloric alloy, and it is used here to monitor the magnetic properties of the alloy itself.

  9. Primary role of electron work function for evaluation of nanostructured titania implant surface against bacterial infection

    Energy Technology Data Exchange (ETDEWEB)

    Golda-Cepa, M., E-mail: golda@chemia.uj.edu.pl [Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Krakow (Poland); Syrek, K. [Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Krakow (Poland); Brzychczy-Wloch, M. [Department of Bacteriology, Microbial Ecology and Parasitology, Jagiellonian University Medical College, Czysta 18, 31-121 Krakow (Poland); Sulka, G.D. [Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Krakow (Poland); Kotarba, A., E-mail: kotarba@chemia.uj.edu.pl [Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Krakow (Poland)

    2016-09-01

    The electron work function as an essential descriptor for the evaluation of metal implant surfaces against bacterial infection is identified for the first time. Its validity is demonstrated on Staphylococcus aureus adhesion to nanostructured titania surfaces. The established correlation: work function–bacteria adhesion is of general importance since it can be used for direct evaluation of any electrically conductive implant surfaces. - Highlights: • The correlation between work function and bacteria adhesion was discovered. • The discovered correlation is rationalized in terms of electrostatic bacteria–surface repulsion. • The results provide basis for the simple evaluation of implant surfaces against infection.

  10. Electron energy-loss spectroscopic study of the surface of ceria abrasives

    International Nuclear Information System (INIS)

    Gilliss, Shelley R.; Bentley, James; Carter, C. Barry

    2005-01-01

    Surfaces of ceria (CeO 2 ) particles have been studied by electron energy-loss spectroscopy in a field-emission gun scanning transmission electron microscope. All the ceria particles analyzed contained Ce 3+ at the surface. Rare-earth impurities such as La were enriched at the surface and were observed for particles ranging from tens to hundreds of nanometers in size. Fluorine in the abrasives corresponded to a lower average cerium valence. Time series investigations indicate that fluorine substitutes on the oxygen sub-lattice and is charge-balanced by some cerium changing from Ce 4+ to Ce 3+

  11. Electron energy-loss spectroscopic study of the surface of ceria abrasives

    Energy Technology Data Exchange (ETDEWEB)

    Gilliss, Shelley R. [Department of Chemical Engineering and Materials Science, University of Minnesota, 421 Washington Avenue S.E., 151 Amundson Hall, Minneapolis, MN 55455 0132 (United States); Bentley, James [Oak Ridge National Laboratory, Metals and Ceramics Division, P.O. Box 2008, Oak Ridge, TN 37831 6024 (United States); Carter, C. Barry [Department of Chemical Engineering and Materials Science, University of Minnesota, 421 Washington Avenue S.E., 151 Amundson Hall, Minneapolis, MN 55455 0132 (United States)]. E-mail: carter@cems.umn.edu

    2005-02-28

    Surfaces of ceria (CeO{sub 2}) particles have been studied by electron energy-loss spectroscopy in a field-emission gun scanning transmission electron microscope. All the ceria particles analyzed contained Ce{sup 3+} at the surface. Rare-earth impurities such as La were enriched at the surface and were observed for particles ranging from tens to hundreds of nanometers in size. Fluorine in the abrasives corresponded to a lower average cerium valence. Time series investigations indicate that fluorine substitutes on the oxygen sub-lattice and is charge-balanced by some cerium changing from Ce{sup 4+} to Ce{sup 3+}.

  12. Influence of surface topography on the secondary electron yield of clean copper samples.

    Science.gov (United States)

    Hu, Xiao-Chuan; Cao, Meng; Cui, Wan-Zhao

    2016-11-01

    Secondary electron yield (SEY) due to electron impact depends strongly on surface topography. The SEY of copper samples after Ar-ion bombardment is measured in situ in a multifunctional ultrahigh vacuum system. Increasing the ion energy or duration of ion bombardment can even enlarge the SEY, though it is relatively low under moderate bombardment intensity. The results obtained with scanning electron microscopy and atomic force microscopy images demonstrate that many valley structures of original sample surfaces can be smoothed due to ion bombardment, but more hill structures are generated with stronger bombardment intensity. With increasing the surface roughness in the observed range, the maximum SEY decreases from 1.2 to 1.07 at a surface characterized by valleys, while it again increases to 1.33 at a surface spread with hills. This phenomenon indicates that hill and valley structures are respectively effective in increasing and decreasing the SEY. These obtained results thus provide a comprehensive insight into the surface topography influence on the secondary electron emission characteristics in scanning electron microscopy. Copyright © 2016 Elsevier Ltd. All rights reserved.

  13. Optical studies of MBE-grown InN nanocolumns: Evidence of surface electron accumulation

    Science.gov (United States)

    Segura-Ruiz, J.; Garro, N.; Cantarero, A.; Denker, C.; Malindretos, J.; Rizzi, A.

    2009-03-01

    Vertically self-aligned InN nanocolumns have been investigated by means of scanning electron microscopy, Raman scattering, and photoluminescence spectroscopy. Different nanocolumn morphologies corresponding to different molecular beam epitaxy growth conditions have been studied. Raman spectra revealed strain-free nanocolumns with high crystalline quality for the full set of samples studied. Longitudinal optical modes both uncoupled and coupled to an electron plasma coexist in the Raman spectra pointing to the existence of two distinctive regions in the nanocolumn: a surface layer of degenerated electrons and a nondegenerated inner core. The characteristics of the low-temperature photoluminescence and its dependence on temperature and excitation power can be explained by a model considering localized holes recombining with degenerated electrons close to the nonpolar surface. The differences observed in the optical response of different samples showing similar crystalline quality have been attributed to the variation in the electron accumulation layer with the growth conditions.

  14. Study of the local structure of binary surfaces by electron diffraction (XPS, LEED)

    OpenAIRE

    Gereová, Katarína

    2006-01-01

    Study of local structure of binary surface with usage of ultra-thin film of cerium deposited on a Pd (111) single-crystal surface is presented. X-ray photoelectron spectroscopy and diffraction (XPS, XPD), angle resolved UV photoemission spectroscopy (ARUPS) and low energy electron diffraction (LEED) was used for our investigations. LEED and X-ray excited photoemission intensities results represent a surface-geometrical structure. As well, mapping of ultra-violet photoelectron intensities as a...

  15. Effect of Autoclave Cycles on Surface Characteristics of S-File Evaluated by Scanning Electron Microscopy

    OpenAIRE

    Razavian, Hamid; Iranmanesh, Pedram; Mojtahedi, Hamid; Nazeri, Rahman

    2015-01-01

    Introduction: Presence of surface defects in endodontic instruments can lead to unwanted complications such as instrument fracture and incomplete preparation of the canal. The current study was conducted to evaluate the effect of autoclave cycles on surface characteristics of S-File by scanning electron microscopy (SEM). Methods and Materials: In this experimental study, 17 brand new S-Files (#30) were used. The surface characteristics of the files were examined in four steps (without autocla...

  16. Hot Electron Photoemission from Plasmonic Nanoparticles: Role of Transient Absorption in Surface Mechanism

    DEFF Research Database (Denmark)

    Uskov, Alexander V.; Protsenko, Igor E.; Ikhsanov, Renat S.

    2014-01-01

    We analyze and compare surface- and vol ume-based internal photoelectric effects from spherical nanoparticles, obtaining analytical expression s for the photoemission rate in both cases. Similar to results for a flat metal surface, one can show that the surface mechanism preva ils, since it is un...... it is unaffected by detrimental hot electron collisions. Transient ab sorption results from dielectric permittivity discontinuity at the nanoparticle boundary and leads to a substantial (by ~5 times) increase of the photoelectron emission rate....

  17. Surface-conduction electron-emitter characteristics and fabrication based on vertically aligned carbon nanotube arrays

    Energy Technology Data Exchange (ETDEWEB)

    Shih, Yi-Ting [Graduate Institute of Electro-Optical Engineering, National Taiwan University of Science and Technology, No. 43, Section 4, Keelung Road, Taipei 10607, Taiwan (China); Li, Kuan-Wei [Department of Electronic and Computer Engineering, National Taiwan University of Science and Technology, No. 43, Section 4, Keelung Road, Taipei 10607, Taiwan (China); Honda, Shin-ichi [Graduate School of Engineering, University of Hyogo, 2167 Shosha, Himeji, Hyogo 671-2280 (Japan); Lin, Pao-Hung; Huang, Ying-Sheng [Graduate Institute of Electro-Optical Engineering, National Taiwan University of Science and Technology, No. 43, Section 4, Keelung Road, Taipei 10607, Taiwan (China); Department of Electronic and Computer Engineering, National Taiwan University of Science and Technology, No. 43, Section 4, Keelung Road, Taipei 10607, Taiwan (China); Lee, Kuei-Yi, E-mail: kylee@mail.ntust.edu.tw [Graduate Institute of Electro-Optical Engineering, National Taiwan University of Science and Technology, No. 43, Section 4, Keelung Road, Taipei 10607, Taiwan (China); Department of Electronic and Computer Engineering, National Taiwan University of Science and Technology, No. 43, Section 4, Keelung Road, Taipei 10607, Taiwan (China)

    2017-06-01

    Graphical abstract: The pattern design provides a new structure of surface-conduction electron-emitter display (SED). Delta-star shaped vertically aligned CNT (VACNT) arrays with 20o tips can simultaneously provide three emitters to bombard the sides of equilateral triangles pattern of VACNT, which produces numerous secondary electrons and enhance the SED efficiency. - Highlights: • The carbon nanotube (CNT) has replaced palladium oxide (PdO) as the electrode material for surface-conduction electron-emitter (SCE) applications. • The vertically aligned CNT (VACNT) arrays with 20° tips of the delta-star arrangement are used as cathodes that easily emit electrons. The cathode pattern simultaneously provides three emitters to bombard the sides of equilateral triangles pattern of VACNT. • The VACNT arrays were covered with magnesium oxide (MgO) nanostructures to promote the surface-conduction electron-emitter display (SED) efficiency (η). • The η was stably maintained in the 75–85% range. The proposed design provides a facile new method for developing SED applications. - Abstract: The carbon nanotube (CNT) has replaced palladium oxide (PdO) as the electrode material for surface-conduction electron-emitter (SCE) applications. Vertically aligned CNT arrays with a delta-star arrangement were patterned and synthesized onto a quartz substrate using photolithography and thermal chemical vapor deposition. Delta-star shaped VACNT arrays with 20° tips are used as cathodes that easily emit electrons because of their high electrical field gradient. In order to improve the field emission and secondary electrons (SEs) in SCE applications, magnesium oxide (MgO) nanostructures were coated onto the VACNT arrays to promote the surface-conduction electron-emitter display (SED) efficiency (η). According to the definition of η in SCE applications, in this study, the η was stably maintained in the 75–85% range. The proposed design provides a facile new method for

  18. Surface electronic transport measurements: A micro multi-point probe approach

    DEFF Research Database (Denmark)

    Barreto, Lucas

    2014-01-01

    This work is mostly focused on the study of electronic transport properties of two-dimensional materials, in particular graphene and topological insulators. To study these, we have improved a unique micro multi-point probe instrument used to perform transport measurements. Not only the experimental...... quantities are extracted, such as conductivity, carrier density and carrier mobility. • A method to insulate electrically epitaxial graphene grown on metals, based on a stepwise intercalation methodology, is developed and transport measurements are performed in order to test the insulation. • We show...... a direct measurement of the surface electronic transport on a bulk topological insulator. The surface state conductivity and mobility are obtained. Apart from transport properties, we also investigate the atomic structure of the Bi2Se3(111) surface via surface x-ray diraction and low-energy electron...

  19. Chemical formation of palladium-free surface-nickelized polyimide film for flexible electronics

    International Nuclear Information System (INIS)

    Hsiao, Y.-S.; Whang, W.-T.; Wu, S.-C.; Chuang, Kuen-Ru

    2008-01-01

    Flexible polyimide (PI) films for flexible electronics were surface-nickelized using a fully solution-based process and excellent adhesion between the nickel and polyimide phases was observed. Polyimide substrates were modified by alkaline hydrolysis, ion exchange, reduction and nickel electroless deposition without palladium. Atomic force microscopy and field emission scanning electron microscopy were used to follow the growth of nickel nanoparticles (Ni-NPs) and nickel layers on the polyimide surface. The surface resistances of the Ni-NPs/PI films and Ni/PI films, measured using a four-point probe, were 1.6 x 10 7 and 0.83 Ω/cm 2 , respectively. The thicknesses of Ni-NPs and the Ni layer on the polyimide surface were 82 nm and 382 nm, respectively, as determined by transmission electron microscopy, and the Ni layer adhered well to PI, as determined by the adhesive tape testing method

  20. Surface hardening of 30CrMnSiA steel using continuous electron beam

    Science.gov (United States)

    Fu, Yulei; Hu, Jing; Shen, Xianfeng; Wang, Yingying; Zhao, Wansheng

    2017-11-01

    30CrMnSiA high strength low alloy (HSLA) carbon structural steel is typically applied in equipment manufacturing and aerospace industries. In this work, the effects of continuous electron beam treatment on the surface hardening and microstructure modifications of 30CrMnSiA are investigated experimentally via a multi-purpose electron beam machine Pro-beam system. Micro hardness value in the electron beam treated area shows a double to triple increase, from 208 HV0.2 on the base metal to 520 HV0.2 on the irradiated area, while the surface roughness is relatively unchanged. Surface hardening parameters and mechanisms are clarified by investigation of the microstructural modification and the phase transformation both pre and post irradiation. The base metal is composed of ferrite and troostite. After continuous electron beam irradiation, the micro structure of the electron beam hardened area is composed of acicular lower bainite, feathered upper bainite and part of lath martensite. The optimal input energy density for 30CrMnSiA steel in this study is of 2.5 kJ/cm2 to attain the proper hardened depth and peak hardness without the surface quality deterioration. When the input irradiation energy exceeds 2.5 kJ/cm2 the convective mixing of the melted zone will become dominant. In the area with convective mixing, the cooling rate is relatively lower, thus the micro hardness is lower. The surface quality will deteriorate. Chemical composition and surface roughness pre and post electron beam treatment are also compared. The technology discussed give a picture of the potential of electron beam surface treatment for improving service life and reliability of the 30CrMnSiA steel.

  1. Fill and spill drives runoff connectivity over frozen ground

    Science.gov (United States)

    Coles, A. E.; McDonnell, J. J.

    2018-03-01

    Snowmelt-runoff processes on frozen ground are poorly understood at the hillslope scale. This is especially true for hillslopes on the northern Great Plains of North America where long periods of snow-covered frozen ground with very shallow slopes mask any spatial patterns and process controls on connectivity and hillslope runoff generation. This study examines a 4.66 ha (46,600 m2) hillslope on the northern Great Plains during the 2014 spring snowmelt season to explore hillslope runoff processes. Specifically, we explore the spatial patterns of runoff production source areas and examine how surface topography and patterns of snow cover, snow water equivalent, soil water content, and thawed layer depth - which we measured on a 10 m grid across our 46,600 m2 hillslope - affect melt water partitioning and runoff connectivity. A key question was whether or not the controls on connectivity are consistent with the fill and spill mechanism found in rain-dominated and unfrozen soil domains. The contrast between the slow infiltration rates into frozen soil and the relatively fast rates of snowmelt delivery to the soil surface resulted in water accumulation in small depressions under the snowpack. Consequently, infiltration was minimal over the 12 day melt period. Instead, nested filling of micro- and meso-depressions was followed by macro-scale, whole-slope spilling. This spilling occurred when large patches of ponded water exceeded the storage capacity behind downslope micro barriers in the surface topography, and flows from them coalesced to drive a rapid increase in runoff at the hillslope outlet. These observations of ponded water and flowpaths followed mapable fill and spill locations based on 2 m resolution digital topographic analysis. Interestingly, while surface topography is relatively unimportant under unfrozen conditions at our site because of low relief and high infiltrability, surface topography shows episodically critical importance for connectivity and

  2. Surface structures from low energy electron diffraction: Atoms, small molecules and an ordered ice film on metal surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Materer, Nicholas F. [Univ. of California, Berkeley, CA (United States)

    1995-09-01

    We investigated the surface bonding of various adsorbates (0, S, C2H3 and NO) along with the resulting relaxation of the Pt(111) surface using low energy electron diffiraction (LEED). LEED experiments have been performed on these ordered overlayers along with theoretical structural analysis using automated tensor LEED (ATLEED). The resulting surface structures of these ordered overlayers exhibit similar adsorbate-induced relaxations. In all cases the adsorbate occupies the fcc hollow site and induces an approximately 0.1 A buckling of the metal surface. The three metal atoms directly bonded to the adsorbate are ``pulled`` out of the surface and the metal atom that is not bound to the adsorbate is `pushed`` inward. In order to understand the reliability of such details, we have carried out a comprehensive study of various non-structural parameters used in a LEED computation. We also studied the adsorption of water on the Pt(lll) surface. We ordered an ultra thin ice film on this surface. The film`s surface is found to be the (0001) face of hexagonal ice. This surface is apparently terminated by a full-bilayer, in which the uppermost water molecules have large vibrational amplitudes even at temperatures as low as 90 K. We examined two other metal surfaces besides Pt(111): Ni(111) and Fe(lll). On Ni(111), we have studied the surface under a high coverage of NO. On both Ni(111) and Pt(111) NO molecules occupy the hollow sites and the N-0 bond distances are practically identical. The challenging sample preparation of an Fe(111) surface has been investigated and a successful procedure has been obtained. The small interlayer spacing found on Fe(111) required special treatment in the LEED calculations. A new ATLEED program has been developed to handle this surface.

  3. Further insight into the mechanism of heavy metals partitioning in stormwater runoff.

    Science.gov (United States)

    Djukić, Aleksandar; Lekić, Branislava; Rajaković-Ognjanović, Vladana; Veljović, Djordje; Vulić, Tatjana; Djolić, Maja; Naunovic, Zorana; Despotović, Jovan; Prodanović, Dušan

    2016-03-01

    Various particles and materials, including pollutants, deposited on urban surfaces are washed off by stormwater runoff during rain events. The interactions between the solid and dissolved compounds in stormwater runoff are phenomena of importance for the selection and improvement of optimal stormwater management practices aimed at minimizing pollutant input to receiving waters. The objective of this research was to further investigate the mechanisms responsible for the partitioning of heavy metals (HM) between the solid and liquid phases in urban stormwater runoff. The research involved the collection of samples from urban asphalt surfaces, chemical characterization of the bulk liquid samples, solids separation, particle size distribution fractionation and chemical and physico-chemical characterization of the solid phase particles. The results revealed that a negligible fraction of HM was present in the liquid phase (less than 3% by weight), while there was a strong correlation between the total content of heavy metals and total suspended solids. Examinations of surface morphology and mineralogy revealed that the solid phase particles consist predominantly of natural macroporous materials: alpha quartz (80%), magnetite (11.4%) and silicon diphosphate (8.9%). These materials have a low surface area and do not have significant adsorptive capacity. These materials have a low surface area and do not have significant adsorptive capacity. The presence of HM on the surface of solid particles was not confirmed by scanning electron microscopy and energy dispersive X-ray microanalyses. These findings, along with the results of the liquid phase sample characterization, indicate that the partitioning of HM between the liquid and solid phases in the analyzed samples may be attributed to precipitation processes. Copyright © 2015 Elsevier Ltd. All rights reserved.

  4. Fabrication of surface micro- and nanostructures for superhydrophobic surfaces in electric and electronic applications

    Science.gov (United States)

    Xiu, Yonghao

    In our study, the superhydrophobic surface based on biomimetic lotus leave is explored to maintain the desired properties for self-cleaning. Parameters in controlling bead-up and roll-off characteristics of water droplets were investigated on different model surfaces. The governing equations were proposed. Heuristic study is performed. First, the fundamental understanding of the effect of roughness on superhydrophobicity is performed. The effect of hierarchical roughness, i.e., two scale roughness effect on roughness is investigated using systems of (1) monodisperse colloidal silica sphere (submicron) arrays and Au nanoparticle on top and (2) Si micrometer pyramids and Si nanostructures on top from KOH etching and metal assisted etching of Si. The relation between the contact area fraction and water droplet contact angles are derived based on Wenzel and Cassie-Baxter equation for the systems and the two scale effect is explained regarding the synergistic combination of two scales. Previously the microscopic three-phase-contact line is thought to be the key factor in determining contact angles and hystereses. In our study, Laplace pressure was brought up and related to the three-phase-contact line and taken as a key figure of merit in determining superhydrophobicity. In addition, we are one of the first to study the effect of tapered structures (wall inclination). Combining with a second scale roughness on the tapered structures, stable Cassie state for both water and low surface energy oil may be achieved. This is of great significance for designing both superhydrophobicity and superoleophobicity. Regarding the origin of contact angle hysteresis, study of superhydrophobicity on micrometer Si pillars was performed. The relation between the interface work of function and contact angle hysteresis was proposed and derived mathematically based on the Young-Dupre equation. The three-phase-contact line was further related to a secondary scale roughness induced. Based on

  5. Low-energy electron scattering at surfaces using STM tips as a field emission gun

    International Nuclear Information System (INIS)

    Mizuno, S.; Iwanaga, M.; Tochihara, H.

    2004-01-01

    Full text: The field emission from scanning tunnelling microscopy (STM) tips has the potential to probe small surface areas with electron beams. Several groups have demonstrated their capabilities. Intensity mapping of the secondary electrons and projection of the transmitted electrons have been shown to have high lateral resolution. Spin-polarized secondary electron microscopy, energy loss spectroscopy and scanning Auger electron microscopy have been also reported. We examined low-energy electron scattering at surfaces. Our final target is a development of a low-energy electron diffraction (LEED) technique using field emission from STM tips to determine structures of surface small regions. Our apparatus was designed based on a commercial STM system (UNISOKU USM-1100). The STM part was suspended by four springs to remove vibrations. The sample holder was mounted on a tube-type piezo scanner, while the tip was fixed rigidly on the holder. The bias voltages were applied to the sample up to +100 V. The tunnel current and the emission current were monitored on the tip. The emission current was fixed at 0.1 nA in the field emission mode. The apparatus was designed to detect backscattered electrons toward surface normal direction. The scattered electrons were guided by the electric field of the tip shield and an extractor, passed through a three-grid electron energy filter, and detected by a microchannel plate equipped with a phosphor screen. Tips were made of tungsten single crystal wire with a diameter of 0.25 mm. They have orientation of direction, and were sharpened by electrochemical etching with a NaOH solution of 2 N. The tips were welded on a tantalum wire for annealing in a preparation chamber. Field emission patterns and field ion microscopy images of them were obtained before and after experiments. The sensitivity and stability of the apparatus were sufficient to observe scattering patterns on the screen. We measured the kinetic energies of the scattered

  6. Surface decontamination of cheddar cheese by electron-beam irradiation

    International Nuclear Information System (INIS)

    Shamsuzzaman, K.

    1991-01-01

    Cheddar cheese samples inoculated with two different levels of Penicillium cyclopium or Aspergillus ochraceus spores were vacuum-packed and irradiated at various doses up to 3.5 kGy with electrons from a 10-MeV linear accelerator. Unirradiated cheese showed visible mold growth in 8-25 d at 10 degrees C, and 7-12 d at 15 degrees C, depending on species and spore concentration. Only marginal extension of shelf life at 15 degrees C was achieved with cheese inoculated with 10 2 cfu per sample of either of the mold spores, followed by irradiation at 0.21 or 0.52 kGy. However, at these doses the average shelf life at 10 degrees C was extended by 41.5 and 50.5 d respectively when the inoculum was A. ochraceus. When the inoculum level was increased tenfold, irradiation at 1.2 and 3.5 kGy extended the average shelf life of cheese containing P. cyclopium by 44.5 and >262 d respectively at 10 degrees C, and by 3 and >166 d respectively at 15 degrees C. The shelf life of samples containing A. ochraceus and irradiated at 1.2 or 3.5 kGy was extended by at least 255.5 d at 10 degrees C and at least 160 d at 15 degrees C. The results clearly showed that low radiation doses are effective in the mold decontamination of cheese. The results also suggest that P. cyclopium in Cheddar cheese is more radiation-resistant than A. ochraceus. This was supported by determination of radiation survival curves for the two species incorporated into Cheddar cheese: D 10 values for P. cyclopium and A. ochraceus were found to be 0.40 and 0.21 kGy respectively. The radiation sensitivity of the two organisms was found not to vary with pH in the pH range 5.0-6.2

  7. Impact of Surface Treatment on the Structural and Electronic Properties of Polished CdZnTe Surfaces for Radiation Detectors

    Science.gov (United States)

    Tari, Suleyman; Aqariden, F.; Chang, Y.; Grein, C.; Li, Jin; Kioussis, N.

    2013-11-01

    We present the effects of surface treatments on the structural and electronic properties of chemomechanically polished Cd0.9Zn0.1Te before contact deposition. Specifically, polished CdZnTe (CZT) samples were treated with four distinct chemical etchants: (1) bromine methanol (BM), (2) bromine in lactic acid, (3) bromine in methanol followed by bromine-20% lactic acid in ethylene glycol, and (4) hydrochloric acid (HCl). The surface structure and surface electronic properties were studied with atomic force microscopy (AFM) and x-ray photoelectron spectroscopy (XPS). AFM images showed that three of the four etchants significantly altered the surface morphology and structure of CZT. All etchants created smoother surfaces; however, all except HCl also introduced high densities of defects. HCl was found to not affect the surface structure. XPS measurements indicated that a thick, ˜3 nm to 4 nm, TeO2 layer formed about 1 h after etching; hence, it is very important to process devices immediately after etching to prevent oxide formation.

  8. Electronic structure of (001) semiconducting MTe surfaces (M = Zn, Cd, Hg)

    International Nuclear Information System (INIS)

    Rodriguez, F.; Camacho, A.; Quiroga, L.; Baquero, R.

    1990-01-01

    By using the tight-binding scheme with ten orbitals per atom (SP 3 s * and two spin orientations) the electronic projected bulk band structure, surface band structure (both anion- and cation-terminated surfaces), and the wave-vector-resolved density of states for these II-VI semiconductors are calculated. A quickly convergent iterative technique is employed for calculating the Green function of the actual semi-infinite crystal. This calculational method allows to precise very accurately, the energy of localized surface states. All the materials considered in this work present surface states with energies lying in the fundamental gap as well as surface states in the lenses opened in the projected bulk valence-band continuum. The atomic weight of each surface state is determined. The states in the fundamental gap turn out to be 'bridge-bond'-type states for anion-terminated surfaces and 'dangling-bond'-type states for cation-terminated surfaces. (author)

  9. Excess electrons at anatase TiO2 surfaces and interfaces: insights from first principles simulations

    Science.gov (United States)

    Selçuk, Sencer; Selloni, Annabella

    2017-07-01

    TiO2 is an important technological material with widespread applications in photocatalysis, photovoltaics and self-cleaning surfaces. Excess electrons from intrinsic defects, dopants and photoexcitation play a key role in the properties of TiO2 that are relevant to its energy-related applications. The picture of excess and photoexcited electrons in TiO2 is based on the polaron model, where the electron forms a localized state that is stabilized by an accompanying lattice distortion. Here, we focus on excess and photoexcited electrons in anatase, the TiO2 polymorph most relevant to photocatalysis and solar energy conversion. For anatase, evidence of both small and large electron polarons has been reported in the literature. In addition, several studies have revealed a remarkable dependence of the photocatalytic activity of anatase on the crystal surface. After an overview of experimental studies, we briefly discuss recent progress in the theoretical description of polaronic states in TiO2, and finally present a more detailed account of our computational studies on the trapping and dynamics of excess electrons near the most common anatase surfaces and aqueous interfaces. The results of these studies provide a bridge between surface science experiments under vacuum conditions and observations of crystal-face-dependent photocatalysis on anatase, and support the idea that optimization of the ratio between different anatase facets can help enhance the photocatalytic activity of this material.

  10. Diagnostics of microwave assisted electron cyclotron resonance plasma source for surface modification of nylon 6

    Science.gov (United States)

    More, Supriya E.; Das, Partha Sarathi; Bansode, Avinash; Dhamale, Gayatri; Ghorui, S.; Bhoraskar, S. V.; Sahasrabudhe, S. N.; Mathe, Vikas L.

    2018-01-01

    Looking at the increasing scope of plasma processing of materials surface, here we present the development and diagnostics of a microwave assisted Electron Cyclotron Resonance (ECR) plasma system suitable for surface modification of polymers. Prior to the surface-treatment, a detailed diagnostic mapping of the plasma parameters throughout the reactor chamber was carried out by using single and double Langmuir probe measurements in Ar plasma. Conventional analysis of I-V curves as well as the elucidation form of the Electron Energy Distribution Function (EEDF) has become the source of calibration of plasma parameters in the reaction chamber. The high energy tail in the EEDF of electron temperature is seen to extend beyond 60 eV, at much larger distances from the ECR zone. This proves the suitability of the rector for plasma processing, since the electron energy is much beyond the threshold energy of bond breaking in most of the polymers. Nylon 6 is used as a representative candidate for surface processing in the presence of Ar, H2 + N2, and O2 plasma, treated at different locations inside the plasma chamber. In a typical case, the work of adhesion is seen to almost get doubled when treated with oxygen plasma. Morphology of the plasma treated surface and its hydrophilicity are discussed in view of the variation in electron density and electron temperature at these locations. Nano-protrusions arising from plasma treatment are set to be responsible for the hydrophobicity. Chemical sputtering and physical sputtering are seen to influence the surface morphology on account of sufficient electron energies and increased plasma potential.

  11. Secondary electron emission from rough metal surfaces: a multi-generation model

    International Nuclear Information System (INIS)

    Cao, Meng; Zhang, Na; Wang, Fang; Hu, Tian-Cun; Cui, Wan-Zhao

    2015-01-01

    We develop a multi-generation model to examine secondary electron emission (SEE) from a rough metal surface. In this model, the traces of both primary electrons (PEs) and secondary electrons (SEs) are tracked by combining the electron scattering in the material and the multi-interaction with the rough surface. The effective secondary electron emission yield (SEY) is then obtained from the final states of the multi-generation SEs. Using this model, the SEE properties of the surfaces with rectangular and triangular grooves have been examined. We find that a rectangular groove can be used for effective SEE suppression. For a triangular groove, the criterion of SEY enhancement/suppression has been achieved, indicating that a small groove angle is required for effective SEE suppression, especially for a high PE energy. Furthermore, the SEE properties for some random rough surfaces are examined and some preliminary results are presented. Accordingly, our model and results could provide a powerful tool to give a comprehensive insight into the SEE of rough metal surfaces. (paper)

  12. InN/GaN quantum dot superlattices: Charge-carrier states and surface electronic structure

    Science.gov (United States)

    Kanouni, F.; Brezini, A.; Djenane, M.; Zou, Q.

    2018-03-01

    We have theoretically investigated the electron energy spectra and surface states energy in the three dimensionally ordered quantum dot superlattices (QDSLs) made of InN and GaN semiconductors. The QDSL is assumed in this model to be a matrix of GaN containing cubic dots of InN of the same size and uniformly distributed. For the miniband’s structure calculation, the resolution of the effective mass Schrödinger equation is done by decoupling it in the three directions within the framework of Kronig-Penney model. We found that the electrons minibands in infinite ODSLs are clearly different from those in the conventional quantum-well superlattices. The electrons localization and charge-carrier states are very dependent on the quasicrystallographic directions, the size and the shape of the dots which play a role of the artificial atoms in such QD supracrystal. The energy spectrum of the electron states localized at the surface of InN/GaN QDSL is represented by Kronig-Penney like-model, calculated via direct matching procedure. The calculation results show that the substrate breaks symmetrical shape of QDSL on which some localized electronic surface states can be produced in minigap regions. Furthermore, we have noticed that the surface states degeneracy is achieved in like very thin bands located in the minigaps, identified by different quantum numbers nx, ny, nz. Moreover, the surface energy bands split due to the reduction of the symmetry of the QDSL in z-direction.

  13. Tuning the electronic properties at the surface of BaBiO{sub 3} thin films

    Energy Technology Data Exchange (ETDEWEB)

    Ferreyra, C. [GIyA y INN, CNEA, Av.Gral Paz 1499, (1650), San Martín, Buenos Aires (Argentina); Departamento de Física, Facultad Ciencias Exactas y Naturales, Universidad de Buenos Aires (Argentina); Guller, F.; Llois, A. M.; Vildosola, V. [GIyA y INN, CNEA, Av.Gral Paz 1499, (1650), San Martín, Buenos Aires (Argentina); Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) (Argentina); Marchini, F.; Williams, F. J. [Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) (Argentina); Departamento de Química Inorgánica, Analítica y Química-Física, INQUIMAE-CONICET, Facultad Ciencias Exactas y Naturales, Universidad de Buenos Aires, Pabellón 2, Ciudad Universitaria, Buenos Aires (Argentina); Lüders, U. [CRISMAT, CNRS UMR 6508, ENSICAEN, 6 Boulevard Maréchal Juin, 14050 Caen Cedex 4 (France); Albornoz, C. [GIyA y INN, CNEA, Av.Gral Paz 1499, (1650), San Martín, Buenos Aires (Argentina); Leyva, A. G. [GIyA y INN, CNEA, Av.Gral Paz 1499, (1650), San Martín, Buenos Aires (Argentina); Escuela de Ciencia y Tecnología, UNSAM, Campus Miguelete, (1650), San Martín, Buenos Aires (Argentina); and others

    2016-06-15

    The presence of 2D electron gases at surfaces or interfaces in oxide thin films remains a hot topic in condensed matter physics. In particular, BaBiO{sub 3} appears as a very interesting system as it was theoretically proposed that its (001) surface should become metallic if a Bi-termination is achieved (Vildosola et al., PRL 110, 206805 (2013)). Here we report on the preparation by pulsed laser deposition and characterization of BaBiO{sub 3} thin films on silicon. We show that the texture of the films can be tuned by controlling the growth conditions, being possible to stabilize strongly (100)-textured films. We find significant differences on the spectroscopic and transport properties between (100)-textured and non-textured films. We rationalize these experimental results by performing first principles calculations, which indicate the existence of electron doping at the (100) surface. This stabilizes Bi ions in a 3+ state, shortens Bi-O bonds and reduces the electronic band gap, increasing the surface conductivity. Our results emphasize the importance of surface effects on the electronic properties of perovskites, and provide strategies to design novel oxide heterostructures with potential interface-related 2D electron gases.

  14. Hot-electron-mediated desorption rates calculated from excited-state potential energy surfaces

    DEFF Research Database (Denmark)

    Olsen, Thomas; Gavnholt, Jeppe; Schiøtz, Jakob

    2009-01-01

    We present a model for desorption induced by (multiple) electronic transitions [DIET (DIMET)] based on potential energy surfaces calculated with the delta self-consistent field extension of density-functional theory. We calculate potential energy surfaces of CO and NO molecules adsorbed on various...... transition-metal surfaces and show that classical nuclear dynamics does not suffice for propagation in the excited state. We present a simple Hamiltonian describing the system with parameters obtained from the excited-state potential energy surface and show that this model can describe desorption dynamics...... in both the DIET and DIMET regimes and reproduce the power-law behavior observed experimentally. We observe that the internal stretch degree of freedom in the molecules is crucial for the energy transfer between the hot electrons and the molecule when the coupling to the surface is strong....

  15. The effects of two counterpropagating surface acoustic wave beams on single electron acoustic charge transport

    International Nuclear Information System (INIS)

    He Jianhong; Guo Huazhong; Song Li; Zhang Wei; Gao Jie; Lu Chuan

    2010-01-01

    We present a comprehensive study of the effects of two counterpropagating surface acoustic waves on the acoustoelectric current of single electron transport devices. A significant improvement in the accuracy of current quantization is achieved as a result of an additional surface acoustic wave beam. The experiments reveal the sinusoidally periodical modulation in the acoustoelectric current characteristic as a function of the relative phase of the two surface acoustic wave beams. Besides, by using standing surface acoustic waves, the acoustoelectric current is detected which we consider as the so-called anomalous acoustoelectric current produced by acoustic wave mechanical deformations. This kind current is contributed to one component of the acoustoelectric current in surface acoustic wave device, which could enable us to establish a more adequate description of acoustoelectric effects on single-electron acoustic charge transport.

  16. Theoretical studies of inelastic molecule-surface and resonant electron-atom and electron-molecule scattering

    International Nuclear Information System (INIS)

    Mowrey, R.C. Jr.

    1985-01-01

    In part I, two problems in the inelastic scattering of molecules from nonvibrating surfaces are discussed. First, the close coupling (CC) method is used to study the orientational dependence of the transition probabilities for vibrationally and rotationally inelastic scattering of H 2 and N 2 from flat surfaces. The dependence of vibrational transition probabilities on the orientation of the molecule is strong but decreases as the energy increases. Second, a new approximation to the CC method for treating scattering of molecules from corrugated surfaces is discussed. The proposed local normal model of j/sub z/ conservation assumes that the component of the rotational angular momentum of the incident molecule which is parallel to the normal to the surface at the impact point is conserved during a collision. In part II, the use of the complex basis function method to study two shape resonances in electron scattering is discussed. The complex self-consistent-field (CSCF) method was used to obtain the position and width of the 2 D shape resonance in electron-calcium scattering. Comparison with experimental results shows that the lifetime is influenced by correlation effects. The CSCF and complex configuration interaction (CCI) methods were used to obtain the complex potential energy function for nuclear motion for the 2 Σ/sub u/ + resonance state of H 2 -

  17. Investigation of the electron emission properties of silver: From exposed to ambient atmosphere Ag surface to ion-cleaned Ag surface

    Energy Technology Data Exchange (ETDEWEB)

    Gineste, T., E-mail: Thomas.Gineste@onera.fr [ONERA The French Aerospace Lab, 31055 Toulouse (France); Belhaj, M. [ONERA The French Aerospace Lab, 31055 Toulouse (France); Teyssedre, G. [LAPLACE - Laboratoire Plasma et Conversion d’Energie -UMR 5213, Université Paul Sabatier - 118, route de Narbonne, 31062 Toulouse Cedex (France); Puech, J. [CNES, 18 Avenue Edouard Belin 31055 Toulouse Cédex 9 (France)

    2015-12-30

    Highlights: • We investigated the electron emission yield of an air exposed Ag to a cleaned Ag. • Air exposed Ag sample was cleaned by ion Ar etching. • Surface composition was determined by AES. • Electron emission yield was related to surface composition evolution. • Natural contamination hugely influence electron properties of Ag sample. - Abstract: Electron emission properties of materials are highly dependent to the surface and the first nanometres subsurface. Technical materials, i.e. used within applications are ordinarily exposed to atmosphere, which interacts with the surface. The contamination layer building up at the surface of materials and/or oxidation layer affects dramatically the electron emission proprieties. In this paper, starting from 99.99% pure silver sample, exposed 4 years to ambient atmosphere, we monitored the variations of the electron emission properties and the surface composition during step by step ion etching procedure.

  18. Atomic interactions at the (100) diamond surface and the impact of surface and interface changes on the electronic transport properties

    Science.gov (United States)

    Deferme, Wim

    Centuries and centuries already, diamond is a material that speaks to ones imagination. Till the 18th century it was only mined in India, after it was also found in Brazil and South-Africa. But along the fascinating properties of diamond, it is also a very interesting material for industry. After the discovery at the end of the 18th century that diamond consists of carbon, it took until the 50's of the previous century before research groups from Russia, Japan and the USA were able to reproduce the growth process of diamond. In 1989 it was discovered that the surface of intrinsic, insulation diamond can be made conductive by hydrogenating the surface. It was clear that not only hydrogen at the surface but also the so called "adsorbates" were responsible for this conductivity. It was still not completely clear what was the influence of other species (like oxygen) on the mechanism of surface conductivity and therefore in this thesis the influence of oxygen on the electronic transport properties of atomically flat diamond are researched. Besides the growth of atomically flat diamond with the use of CVD (chemical vapour deposition) en the study of the grown surfaces with characterising techniques such as AFM (atomic force microscopy) and STM (scanning tunnelling microscopy), the study of the surface treatment with plasma techniques is the main topic of this thesis. The influence of oxygen on the surface conductivity is studied and with the ToF (Time-of-Flight) technique the transport properties of the freestanding diamond are examined. With a short laserflash, electrons and holes are created at the diamond/aluminium interface and due to an electric field (up to 500V) the charge carriers are translated to the back contact. In this way the influence of the surface and the changes at the aluminum contacts is studied leading to very interesting results.

  19. Surface free energy of ultra-high molecular weight polyethylene modified by electron and gamma irradiation

    International Nuclear Information System (INIS)

    Abdul-Kader, A.M.; Turos, A.; Radwan, R.M.; Kelany, A.M.

    2009-01-01

    Surface free energy of biocompatible polymers is important factor which affects the surface properties such as wetting, adhesion and biocompatibility. In the present work, the change in the surface free energy of ultra-high molecular weight polyethylene (UHMWPE) samples, which is produced by electron beam and gamma ray irradiation were, investigated. Mechanism of the changes in surface free energy induced by irradiations of doses ranging from 25 to 500 kGy was studied. FTIR technique was applied for sample analysis. Contact angle measurements showed that wettability and surface free energy of samples have increased with increasing the irradiation dose, where the values of droplet contact angle of the samples decrease gradually with increasing the radiation dose. The increase in the wettability and surface free energy of the irradiated samples are attributed to formation of hydrophilic groups on the polymer surface by the oxidation, which apparently occurs by exposure of irradiated samples to the air.

  20. New aspects of electronic excitations at the bismuth surface: Topology, thermalization and coupling to coherent phonons

    Energy Technology Data Exchange (ETDEWEB)

    Perfetti, L., E-mail: luca.perfetti@polytechnique.edu [Laboratoire des Solides Irradiés, Ecole Polytechnique – CEA/DSM – CNRS UMR 7642, 91128 Palaiseau (France); Faure, J. [Laboratoire d’Optique Appliquée, Ecole Polytechnique – ENSTA – CNRS UMR 7639, 91761 Palaiseau (France); Papalazarou, E.; Mauchain, J.; Marsi, M.; Goerbig, M.O. [Laboratoire de Physique des Solides, CNRS UMR 8502, Université Paris-Sud, F-91405 Orsay (France); Taleb-Ibrahimi, A.; Ohtsubo, Y. [Synchrotron SOLEIL, Saint-Aubin-BP 48, F-91192 Gif sur Yvette (France)

    2015-05-15

    We review measurements of angle and time resolved photoelectron spectroscopy on the surface states of the Bi(1 1 1) surface. The work covers several aspects of these surface states, discussing the topological properties, the strong anisotropy of the spin–orbit splitting and the dynamical relaxation of photoexcited electrons. Since time resolved experiments disentagle interaction processes in real time, the reported data offer a novel perspective on the motion of charge carriers in surface states and will serve as an unuseful reference for other systems with strong spin–orbit coupling.

  1. Terahertz instability of surface optical-phonon polaritons that interact with surface plasmon polaritons in the presence of electron drift

    International Nuclear Information System (INIS)

    Sydoruk, O.; Solymar, L.; Shamonina, E.; Kalinin, V.

    2010-01-01

    Traveling-wave interaction between optical phonons and electrons drifting in diatomic semiconductors has potential for amplification and generation of terahertz radiation. Existing models of this interaction were developed for infinite materials. As a more practically relevant configuration, we studied theoretically a finite semiconductor slab surrounded by a dielectric. This paper analyzes the optical-phonon instability in the slab including the Lorentz force and compares it to the instability in an infinite material. As the analysis shows, the slab instability occurs because of the interaction of surface optical-phonon polaritons with surface plasmon polaritons in the presence of electron drift. The properties of the instability depend on the slab thickness when the thickness is comparable to the wavelength. For large slab thicknesses, however, the dispersion relation of the slab is similar to that of an infinite material, although the coupling is weaker. The results could be used for the design of practical terahertz traveling-wave oscillators and amplifiers.

  2. Note: Electron energy spectroscopy mapping of surface with scanning tunneling microscope.

    Science.gov (United States)

    Li, Meng; Xu, Chunkai; Zhang, Panke; Li, Zhean; Chen, Xiangjun

    2016-08-01

    We report a novel scanning probe electron energy spectrometer (SPEES) which combines a double toroidal analyzer with a scanning tunneling microscope to achieve both topography imaging and electron energy spectroscopy mapping of surface in situ. The spatial resolution of spectroscopy mapping is determined to be better than 0.7 ± 0.2 μm at a tip sample distance of 7 μm. Meanwhile, the size of the field emission electron beam spot on the surface is also measured, and is about 3.6 ± 0.8 μm in diameter. This unambiguously demonstrates that the spatial resolution of SPEES technique can be much better than the size of the incident electron beam.

  3. Chemical changes induced on a TiO2 surface by electron bombardment

    International Nuclear Information System (INIS)

    Vergara, L.I.; Passeggi, M.C.G.; Ferron, J.

    2007-01-01

    We study the TiO 2 (Ti 4+ ) chemical reduction induced by electron bombardment using Auger electron spectroscopy and factor analysis. We show that the electron irradiation of a TiO 2 sample is characterized by the appearance of a lower Ti oxidation state, Ti 2 O 3 (Ti 3+ ), followed by a further deposition of carbon, which is present inevitably in the environment even under ultra-high vacuum conditions. The appearance of C over the surface is found to be a complex mechanism which affects the reduction process through passivation of the electron-induced oxygen desorption and formation of titanium carbide. For very high irradiation doses, we also found that the chemical changes on the surface are stopped due to the deposition of carbon in a graphitic form

  4. Hot Electron Photoemission from Plasmonic Nanostructures: The Role of Surface Photoemission and Transition Absorption

    DEFF Research Database (Denmark)

    Babicheva, Viktoriia; Zhukovsky, Sergei; Ikhsanov, Renat Sh

    2015-01-01

    We study mechanisms of photoemission of hot electrons from plasmonic nanoparticles. We analyze the contribution of "transition absorption", i.e., loss of energy of electrons passing through the boundary between different materials, to the surface mechanism of photoemission. We calculate photoemis......We study mechanisms of photoemission of hot electrons from plasmonic nanoparticles. We analyze the contribution of "transition absorption", i.e., loss of energy of electrons passing through the boundary between different materials, to the surface mechanism of photoemission. We calculate...... photoemission rate and transition absorption for nanoparticles surrounded by various media with a broad range of permittivities and show that photoemission rate and transition absorption follow the same dependence on the permittivity. Thus, we conclude that transition absorption is responsible...

  5. Towards hot electron mediated charge exchange in hyperthermal energy ion-surface interactions

    DEFF Research Database (Denmark)

    Ray, M. P.; Lake, R. E.; Thomsen, Lasse Bjørchmar

    2010-01-01

    electrons useful for driving chemical reactions at surfaces. Using the binary collision approximation and a nonadiabatic model that takes into account the time-varying nature of the ion–surface interaction, the energy loss of the ions is reproduced. The energy loss for Na + ions incident on the devices......We have made Na + and He + ions incident on the surface of solid state tunnel junctions and measured the energy loss due to atomic displacement and electronic excitations. Each tunnel junction consists of an ultrathin film metal–oxide–semiconductor device which can be biased to create a band of hot...... shows that the primary energy loss mechanism is the atomic displacement of Au atoms in the thin film of the metal–oxide–semiconductor device. We propose that neutral particle detection of the scattered flux from a biased device could be a route to hot electron mediated charge exchange....

  6. Rainfall-induced runoff from exposed streambed sediments: an important source of water pollution.

    Science.gov (United States)

    Frey, S K; Gottschall, N; Wilkes, G; Grégoire, D S; Topp, E; Pintar, K D M; Sunohara, M; Marti, R; Lapen, D R

    2015-01-01

    When surface water levels decline, exposed streambed sediments can be mobilized and washed into the water course when subjected to erosive rainfall. In this study, rainfall simulations were conducted over exposed sediments along stream banks at four distinct locations in an agriculturally dominated river basin with the objective of quantifying the potential for contaminant loading from these often overlooked runoff source areas. At each location, simulations were performed at three different sites. Nitrogen, phosphorus, sediment, fecal indicator bacteria, pathogenic bacteria, and microbial source tracking (MST) markers were examined in both prerainfall sediments and rainfall-induced runoff water. Runoff generation and sediment mobilization occurred quickly (10-150 s) after rainfall initiation. Temporal trends in runoff concentrations were highly variable within and between locations. Total runoff event loads were considered large for many pollutants considered. For instance, the maximum observed total phosphorus runoff load was on the order of 1.5 kg ha. Results also demonstrate that runoff from exposed sediments can be a source of pathogenic bacteria. spp. and spp. were present in runoff from one and three locations, respectively. Ruminant MST markers were also present in runoff from two locations, one of which hosted pasturing cattle with stream access. Overall, this study demonstrated that rainfall-induced runoff from exposed streambed sediments can be an important source of surface water pollution. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  7. Micropollutants Identification Affecting the Nearby Environment from Highway Runoff: The Case Study of Cyprus Highway

    Directory of Open Access Journals (Sweden)

    Antonis A. Zorpas

    2015-01-01

    Full Text Available Road/highway surfaces accumulate significant quantities of pollutants including nutrients, heavy metals, and polycyclic hydrocarbon aromatic (PHAs. Traffic characteristics (vehicle speed, traffic load, etc., climate, long dry wet periods, and rainfall event intensity and duration are regarded as important factors in generating pollutants in high way runoff (HRO. Regarding rainfall control, most of the road is served by drainage ditches which collect the runoff and direct it to the nearest natural water courses. This paper focuses on the estimation of pollutant that is coming from two several highways (to the airport and to the biggest industrial area in Cyprus. Overall, more than 100 different samples were collected and analysed over a period of two years. Several parameters were determined like PHA, COD, electronic conductivity (EC, total suspended solid (TSS, total dissolved solid (TDS, pH, fats and oils (FOG, T. Coliforms, NO3, NO2, NH4, SO4, Cl, As, Ba, Bi, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, P, Pb, and Zn. The results indicated that the first flush consists of major pollution due to the fact that all parameters are in high levels. As the rainfall continues the pollution decreases but the influence to the nearby areas of the runoff is high.

  8. Electron emission induced by resonant coherent interaction in ion-surface scattering at grazing incidence

    International Nuclear Information System (INIS)

    Garcia de Abajo, F.J.; Ponce, V.H.; Echenique, P.M.

    1994-01-01

    The resonant coherent interaction of an ion with an oriented crystal surface, under grazing-incidence conditions with respect to a special direction of the crystal, gives rise to electron loss to the continuum from electronic bound states of the ion. The calculations presented below predict large probabilities for electron emission due to this mechanism. The electrons are emitted with well defined energies, expressed in terms of the condition of resonance. Furthermore, the emission takes place around certain preferential directions, which are determined by both the latter condition and the symmetry of the surface lattice. Our calculations for MeV He + ions scattered at a W(001) surface along the left-angle 100 right-angle direction with glancing angle of 0--2 mrad indicate a yield of emission close to 1. Using heavier projectiles, one obtains smaller yields, but still large enough to be measurable in some cases (e.g., ∼0.9 for 53 MeV B 4+ and an angle of incidence of 1 mrad). Besides, the initial bound state is energy shifted due to the interaction with both the crystal potential and the velocity-dependent image potential. This results in a slight shift of the peaks of emission, which suggests a possible spectroscopy for analyzing the dynamical interaction of electronic bound states with solid surfaces

  9. Secondary Electron Yield on Cryogenic Surfaces as a Function of Physisorbed Gases

    CERN Document Server

    Kuzucan, A; Taborelli, M; Störi, H

    2011-01-01

    Electron cloud is a serious limitation for the operation of particle accelerators with intense positively charged beams. It occurs if the secondary electron yield (SEY) of the beam-pipe surface is sufficiently high to induce an electron multiplication. At low surface temperatures, the SEY is strongly influenced by the nature of the physisorbed gases and by the corresponding surface coverage. These conditions occur in many accelerators operating with superconducting magnets and cold vacuum sections such as the LHC and RHIC. In this work, we investigated the variation of the SEY of copper, aluminium and electro-polished copper as a function of physisorbed N2, CO, CO2, CH4, Kr, C2H6 at cryogenic temperatures. The conditioning by electron bombardment of the surface after the physisorption of H2O on electro polished copper will also be presented. The results of the various gases are compared in order to find a rationale for the behaviour of the secondary electrons for the various adsorbates.

  10. Construction and characterization of a spin polarized helium ion beam for surface electronic structure studies

    International Nuclear Information System (INIS)

    Harrison, A.R.

    1982-01-01

    Ion neutralization and metastable de-excitation spectroscopy, INS and MDS, allow detailed analysis of the surface electronic configuration of metals. The orthodox application of these spectroscopies may be enhanced by electronic spin polarization of the probe beams. For this reason, a spin polarized helium ion beam has been constructed. The electronic spin of helium metastables created within an rf discharge may be spacially aligned by optically pumping the atoms. Subsequent collisions between metastables produce helium ions which retain the orientation of the electronic spin. Extracted ion polarization, although not directly measurable, may be estimated from extracted electron polarization, metastable polarization, pumping radiation absorption and current modulation measurements. Ions extracted from the optically pumped discharge exhibit an estimated polarization of about ten per cent at a beam current of a few tenths of a microampere. Extraction of helium ions from the discharge requires that the ions have a high kinetic energy. However, to avoid undesirable kinetic electron ejection from the target surface, the ions must be decelerated. Examination of various deceleration configurations, in paticular exponential and linear deceleration fields, and experimental observation indicate that a linear decelerating field produces the best low energy beam to the target surface

  11. Characterizing the geometric and electronic structure of defects in the "29" copper surface oxide

    Science.gov (United States)

    Therrien, Andrew J.; Hensley, Alyssa J. R.; Zhang, Renqin; Pronschinske, Alex; Marcinkowski, Matthew D.; McEwen, Jean-Sabin; Sykes, E. Charles H.

    2017-12-01

    The geometric and electronic structural characterization of thin film metal oxides is of fundamental importance to many fields such as catalysis, photovoltaics, and electrochemistry. Surface defects are also well known to impact a material's performance in any such applications. Here, we focus on the "29" oxide Cu2O/Cu(111) surface and we observe two common structural defects which we characterize using scanning tunneling microscopy/spectroscopy and density functional theory. The defects are proposed to be O vacancies and Cu adatoms, which both show unique topographic and spectroscopic signatures. The spatially resolved electronic and charge state effects of the defects are investigated, and implications for their reactivity are given.

  12. Direct observation of spin-resolved full and empty electron states in ferromagnetic surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Berti, G., E-mail: giulia.berti@polimi.it; Calloni, A.; Brambilla, A.; Bussetti, G.; Duò, L.; Ciccacci, F. [Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, I-20133, Milano (Italy)

    2014-07-15

    We present a versatile apparatus for the study of ferromagnetic surfaces, which combines spin-polarized photoemission and inverse photoemission spectroscopies. Samples can be grown by molecular beam epitaxy and analyzed in situ. Spin-resolved photoemission spectroscopy analysis is done with a hemispherical electron analyzer coupled to a 25 kV-Mott detector. Inverse photoemission spectroscopy experiments are performed with GaAs crystals as spin-polarized electron sources and a UV bandpass photon detector. As an example, measurements on the oxygen passivated Fe(100)-p(1×1)O surface are presented.

  13. Different quantization mechanisms in single-electron pumps driven by surface acoustic waves

    DEFF Research Database (Denmark)

    Utko, P.; Gloos, K.; Hansen, Jørn Bindslev

    2006-01-01

    We have studied the acoustoelectric current in single-electron pumps driven by surface acoustic waves. We have found that in certain parameter ranges two different sets of quantized steps dominate the acoustoelectric current versus gate-voltage characteristics. In some cases, both types of quanti......We have studied the acoustoelectric current in single-electron pumps driven by surface acoustic waves. We have found that in certain parameter ranges two different sets of quantized steps dominate the acoustoelectric current versus gate-voltage characteristics. In some cases, both types...

  14. Electronic transport at semiconductor surfaces - from point-contact transistor to micro-four-point probes

    DEFF Research Database (Denmark)

    Hasegawa, S.; Grey, Francois

    2002-01-01

    show that this type of conduction is measurable using new types of experimental probes, such as the multi-tip scanning tunnelling microscope and the micro-four-point probe. The resulting electronic transport properties are intriguing, and suggest that semiconductor surfaces should be considered...... of the first point-contact transistors, and led to the successful fabrication of field-effect transistors. However, to this day, one property of semiconductor surface states remains poorly understood, both theoretically and experimentally. That is the conduction of electrons or holes directly through...

  15. Positron study of electron momentum density and Fermi surface in titanium and zirconium

    International Nuclear Information System (INIS)

    Suzuki, Ryoichi; Osawa, Makoto; Tanigawa, Shoichiro; Matsumoto, Makoto; Shiotani, Nobuhiro.

    1989-01-01

    The three dimensional electron-positron momentum densities have been obtained on Ti and Zr from measurements of two dimensional angular correlation of positron annihilation radiation followed by an image reconstruction technique based on direct Fourier transformation. Augmented-plane wave band structure calculations have been carried out and the results are compared with the experiments. Agreement between the experiment and the theory leads to a conclusion that both Ti and Zr have electron surface sheets which are centered at H and hole surface sheets which are running along the Γ-A axis. (author)

  16. Asymptotic theory of dissipative trapped electron mode overlapping many rational surfaces

    International Nuclear Information System (INIS)

    Rogister, A.; Hasselberg, G.

    1978-01-01

    The two dimensional eigenvalue equation describing the dissipative trapped electron mode is solved exactly in the limit of the mode overlapping many rational surfaces using the Pogutse model for the magnetic field and the pitch angle collision operator. The trapped electron contribution to the growth rate decreases, with respect to the standard theory, by a factor of order Δ/chi sub(T) << 1 where chi sub(T) is the position of the turning point and Δ the distance between rational surfaces

  17. Surface characterization and surface electronic structure of organic quasi-one-dimensional charge transfer salts

    DEFF Research Database (Denmark)

    Sing, M.; Schwingenschlögl, U.; Claessen, R.

    2003-01-01

    We have thoroughly characterized the surfaces of the organic charge-transfer salts TTF-TCNQ and (TMTSF)(2)PF6 which are generally acknowledged as prototypical examples of one-dimensional conductors. In particular x-ray-induced photoemission spectroscopy turns out to be a valuable nondestructive d...

  18. Surface morphology of the endolymphatic duct in the rat. A scanning electron microscopy study

    DEFF Research Database (Denmark)

    Qvortrup, K; Rostgaard, Jørgen; Bretlau, P

    1995-01-01

    were identified with the scanning electron microscope. A polygonal and oblong epithelial cell was observed in the largest number throughout the duct, and in the juxtasaccular half of the duct, two additional types of epithelial cells were observed. The scanning electron microscopic observations...... microscopy was attained by coating of the specimens with osmium tetroxide and thiocarbohydrazide followed by a continuous dehydration procedure. This technique permitted, for the first time, an investigation of the surface morphology of the epithelial cells in the endolymphatic duct. Three types of cells...... are compared and discussed with reference to previous transmission electron microscopic studies of the endolymphatic duct....

  19. Towards an electronic dog nose: surface plasmon resonance immunosensor for security and safety.

    Science.gov (United States)

    Onodera, Takeshi; Toko, Kiyoshi

    2014-09-05

    This review describes an "electronic dog nose" based on a surface plasmon resonance (SPR) sensor and an antigen-antibody interaction for security and safety. We have concentrated on developing appropriate sensor surfaces for the SPR sensor for practical use. The review covers different surface fabrications, which all include variations of a self-assembled monolayer containing oligo(ethylene glycol), dendrimer, and hydrophilic polymer. We have carried out detection of explosives using the sensor surfaces. For the SPR sensor to detect explosives, the vapor or particles of the target substances have to be dissolved in a liquid. Therefore, we also review the development of sampling processes for explosives, and a protocol for the measurement of explosives on the SPR sensor in the field. Additionally, sensing elements, which have the potential to be applied for the electronic dog nose, are described.

  20. Towards an Electronic Dog Nose: Surface Plasmon Resonance Immunosensor for Security and Safety

    Directory of Open Access Journals (Sweden)

    Takeshi Onodera

    2014-09-01

    Full Text Available This review describes an “electronic dog nose” based on a surface plasmon resonance (SPR sensor and an antigen–antibody interaction for security and safety. We have concentrated on developing appropriate sensor surfaces for the SPR sensor for practical use. The review covers different surface fabrications, which all include variations of a self-assembled monolayer containing oligo(ethylene glycol, dendrimer, and hydrophilic polymer. We have carried out detection of explosives using the sensor surfaces. For the SPR sensor to detect explosives, the vapor or particles of the target substances have to be dissolved in a liquid. Therefore, we also review the development of sampling processes for explosives, and a protocol for the measurement of explosives on the SPR sensor in the field. Additionally, sensing elements, which have the potential to be applied for the electronic dog nose, are described.

  1. Surface potential measurement of negative-ion-implanted insulators by analysing secondary electron energy distribution

    International Nuclear Information System (INIS)

    Toyota, Yoshitaka; Tsuji, Hiroshi; Nagumo, Syoji; Gotoh, Yasuhito; Ishikawa, Junzo; Sakai, Shigeki.

    1994-01-01

    The negative ion implantation method we have proposed is a noble technique which can reduce surface charging of isolated electrodes by a large margin. In this paper, the way to specify the surface potential of negative-ion-implanted insulators by the secondary electron energy analysis is described. The secondary electron energy distribution is obtained by a retarding field type energy analyzer. The result shows that the surface potential of fused quartz by negative-ion implantation (C - with the energy of 10 keV to 40 keV) is negatively charged by only several volts. This surface potential is extremely low compared with that by positive-ion implantation. Therefore, the negative-ion implantation is a very effective method for charge-up free implantation without charge compensation. (author)

  2. Potential and Kinetic Electron Emissions from HOPG Surface Irradiated by Highly Charged Xenon and Neon Ions

    International Nuclear Information System (INIS)

    Yu-Yu, Wang; Yong-Tao, Zhao; Jian-Rong, Sun; De-Hui, Li; Jin-Yu, Li; Ping-Zhi, Wang; Guo-Qing, Xiao; Abdul, Qayyum

    2011-01-01

    Highly charged 129 Xe q+ (q = 10−30) and 40 Ne q+ (q = 4−8) ion-induced secondary electron emissions on the surface of highly oriented pyrolytic graphite (HOPG) are reported. The total secondary electron yield is measured as a function of the potential energy of incident ions. The experimental data are used to separate contributions of kinetic and potential electron yields. Our results show that about 4.5% and 13.2% of ion's potential energies are consumed in potential electron emission due to different Xe q+ -HOPG and Ne q+ -HOPG combinations. A simple formula is introduced to estimate the fraction of ion's potential energy for potential electron emission. (atomic and molecular physics)

  3. Localized electronic states at grain boundaries on the surface of graphene and graphite

    DEFF Research Database (Denmark)

    Luican-Mayer, Adina; Barrios-Vargas, Jose E.; Falkenberg, Jesper Toft

    2016-01-01

    morphology affects the electronic properties is crucial for the development of applications such as flexible electronics, energy harvesting devices or sensors. We here report on atomic scale characterization of several GBs and on the structural-dependence of the localized electronic states in their vicinity....... Using low temperature scanning tunneling microscopy and spectroscopy, together with tight binding and ab initio numerical simulations we explore GBs on the surface of graphite and elucidate the interconnection between the local density of states and their atomic structure. We show that the electronic......ecent advances in large-scale synthesis of graphene and other 2D materials have underscored the importance of local defects such as dislocations and grain boundaries (GBs), and especially their tendency to alter the electronic properties of the material. Understanding how the polycrystalline...

  4. Absorption and backscatter of internal conversion electrons in the measurements of surface contamination of 137Cs

    International Nuclear Information System (INIS)

    Yunoki, A.; Kawada, Y.; Yamada, T.; Unno, Y.; Sato, Y.; Hino, Y.

    2013-01-01

    We measured 4π and 2π counting efficiencies for internal conversion electrons (ICEs), gross β-particles and also β-rays alone with various source conditions regarding absorber and backing foil thickness using e-X coincidence technique. Dominant differences regarding the penetration, attenuation and backscattering properties among ICEs and β-rays were revealed. Although the abundance of internal conversion electrons of 137 Cs- 137 Ba is only 9.35%, 60% of gross counts may be attributed to ICEs in worse source conditions. This information will be useful for radionuclide metrology and for surface contamination monitoring. - Highlights: • Counting efficiencies for internal conversion electrons from 137 Cs were measured, and compared with those for β-rays. • Electron-X coincidence technique was employed. • A thin NaI(Tl) scintillation detector was used for X-ray detection. • Backscattering fractions of electrons and beta particles were studied by similar experiments

  5. Surface morphology and chemical composition of TiTa-based surface alloy formed on TiNi by electron beam additive technologies

    Science.gov (United States)

    Gudimova, E. Yu.; Meisner, L. L.; Meisner, S. N.; Yakovlev, E. V.; Shabalina, O. I.

    2017-12-01

    This paper presents research results on the physiochemical and topographic surface properties of a NiTi alloy and their changes after different surface treatments: mechanical polishing, electron beam cleaning, and TiTa-based surface alloying. The possibility of using electron beam treatment for surface preparation with no additional methods is shown. Experiments demonstrate that the TiTa-based alloy surface formed by multiple magnetron deposition of TiTa film and subsequent pulsed electron beam melting of the film/substrate system is chemically and morphologically homogeneous.

  6. Pollution loads in urban runoff and sanitary wastewater

    International Nuclear Information System (INIS)

    Taebi, Amir; Droste, Ronald L.

    2004-01-01

    While more attention has been paid in recent years to urban point source pollution control through the establishment of wastewater treatment plants in many developing countries, no considerable planning nor any serious measures have been taken to control urban non-point source pollution (urban stormwater runoff). The present study is a screening analysis to investigate the pollution loads in urban runoff compared to point source loads as a first prerequisite for planning and management of receiving water quality. To compare pollutant loads from point and non-point urban sources, the pollutant load is expressed as the weight of pollutant per hectare area per year (kg/ha·year). Unit loads were estimated in stormwater runoff, raw sanitary wastewater and secondary treatment effluents in Isfahan, Iran. Results indicate that the annual pollution load in urban runoff is lower than the annual pollution load in sanitary wastewater in areas with low precipitation but it is higher in areas with high precipitation. Two options, namely, advanced treatment (in lieu of secondary treatment) of sanitary wastewater and urban runoff quality control systems (such as detention ponds) were investigated as controlling systems for pollution discharges into receiving waters. The results revealed that for Isfahan, as a low precipitation urban area, advanced treatment is a more suitable option, but for high precipitation urban areas, urban surface runoff quality control installations were more effective for suspended solids and oxygen-demanding matter controls, and that advanced treatment is the more effective option for nutrient control

  7. Analyzing runoff processes through conceptual hydrological modeling in the Upper Blue Nile Basin, Ethiopia

    Science.gov (United States)

    Dessie, M.; Verhoest, N. E. C.; Pauwels, V. R. N.; Admasu, T.; Poesen, J.; Adgo, E.; Deckers, J.; Nyssen, J.

    2014-12-01

    Understanding runoff processes in a basin is of paramount importance for the effective planning and management of water resources, in particular in data-scarce regions such as the Upper Blue Nile. Hydrological models representing the underlying hydrological processes can predict river discharges from ungauged catchments and allow for an understanding of the rainfall-runoff processes in those catchments. In this paper, such a conceptual process-based hydrological model is developed and applied to the upper Gumara and Gilgel Abay catchments (both located within the Upper Blue Nile Basin, the Lake Tana sub-basin) to study the runoff mechanisms and rainfall-runoff processes in the basin. Topography is considered as a proxy for the variability of most of the catchment characteristics. We divided the catchments into different runoff production areas using topographic criteria. Impermeable surfaces (rock outcrops and hard soil pans, common in the Upper Blue Nile Basin) were considered separately in the conceptual model. Based on model results, it can be inferred that about 65% of the runoff appears in the form of interflow in the Gumara study catchment, and baseflow constitutes the larger proportion of runoff (44-48%) in the Gilgel Abay catchment. Direct runoff represents a smaller fraction of the runoff in both catchments (18-19% for the Gumara, and 20% for the Gilgel Abay) and most of this direct runoff is generated through infiltration excess runoff mechanism from the impermeable rocks or hard soil pans. The study reveals that the hillslopes are recharge areas (sources of interflow and deep percolation) and direct runoff as saturated excess flow prevails from the flat slope areas. Overall, the model study suggests that identifying the catchments into different runoff production areas based on topography and including the impermeable rocky areas separately in the modeling process mimics the rainfall-runoff process in the Upper Blue Nile Basin well and yields a useful

  8. Analyzing runoff processes through conceptual hydrological modelling in the Upper Blue Nile basin, Ethiopia

    Science.gov (United States)

    Dessie, M.; Verhoest, N. E. C.; Pauwels, V. R. N.; Admasu, T.; Poesen, J.; Adgo, E.; Deckers, J.; Nyssen, J.

    2014-05-01

    Understanding runoff processes in a basin is of paramount importance for the effective planning and management of water resources, in particular in data scarce regions of the Upper Blue Nile. Hydrological models representing the underlying hydrological processes can predict river discharges from ungauged catchments and allow for an understanding of the rainfall-runoff processes in those catchments. In this paper, such a conceptual process-based hydrological model is developed and applied to the upper Gumara and Gilgel Abay catchments (both located within the Upper Blue Nile basin, the Lake Tana sub-basin) to study the runoff mechanisms and rainfall-runoff processes in the basin. Topography is considered as a proxy for the variability of most of the catchment characteristics. We divided the catchments into different runoff production areas using topographic criteria. Impermeable surfaces (rock outcrops and hard soil pans, common in the Upper Blue Nile basin) were considered separately in the conceptual model. Based on model results, it can be inferred that about 65% of the runoff appears in the form of interflow in the Gumara study catchment, and baseflow constitutes the larger proportion of runoff (44-48%) in the Gilgel Abay catchment. Direct runoff represents a smaller fraction of the runoff in both catchments (18-19% for the Gumara, and 20% for the Gilgel Abay) and most of this direct runoff is generated through infiltration excess runoff mechanism from the impermeable rocks or hard soil pans. The study reveals that the hillslopes are recharge areas (sources of interflow and deep percolation) and direct runoff as saturated excess flow prevails from the flat slope areas. Overall, the model study suggests that identifying the catchments into different runoff production areas based on topography and including the impermeable rocky areas separately in the modeling process mimics well the rainfall-runoff process in the Upper Blue Nile basin and brings a useful result

  9. Ion and electron beam interaction on surfaces - a detection mechanism for obtaining visual ion beam images

    International Nuclear Information System (INIS)

    Fine, J.; Gorden, R. Jr.

    1978-01-01

    Two-dimensional images have been obtained of ion beam impact cross sections on solid surfaces by the coincident interaction of a rastered electron beam. This detection method is effective in producing images in real time on various insulator surfaces. The size of these images correlates well with ion beam current density profile measurements (at full width) and, therefore, can be very useful for ion beam diagnostics and alignment. (Auth.)

  10. [Scanning electron microscopy (S.E.M.) aspects of intestinal mucosal surface in childhood coeliac disease].

    Science.gov (United States)

    Patanè, R; Bottaro, G; Ricca, O; Galasso, S

    1982-01-01

    Intestinal mucosal surface in 5 children suffered with Coeliac Disease was observed at Scanning Electron Microscopy. The comparison between two techniques of dehydration demonstrated that the Alcool-Amile Acetate dehydration reduces the technical errors to the minimum. Therefore, a better visualization allows us to recognize the surface coat, the microvillous and some mucosal functional aspects (scale off), which were previously undistinguished. There are no differences between the mucosal aspects in adult coeliac disease and childhood coelia disease.

  11. Climate change and runoff in south-western Australia

    Science.gov (United States)

    Silberstein, R. P.; Aryal, S. K.; Durrant, J.; Pearcey, M.; Braccia, M.; Charles, S. P.; Boniecka, L.; Hodgson, G. A.; Bari, M. A.; Viney, N. R.; McFarlane, D. J.

    2012-12-01

    SummaryThis paper presents the results of computer simulations of runoff from 13 major fresh and brackish river basins in south-western Australia (SWA) under climate projections obtained from 15 GCMs with three future global warming scenarios equivalent to global temperature rises of 0.7 °C, 1.0 °C and 1.3 °C by 2030. The objective was to apply an efficient methodology, consistent across a large region, to examine the implications of the best available projections in climate trends for future surface water resources. An ensemble of rainfall-runoff models was calibrated on stream flow data from 1975 to 2007 from 106 gauged catchments distributed throughout the basins of the study area. The sensitivity of runoff to projected changes in mean annual rainfall is examined using the climate 'elasticity' concept. Averaged across the study area, all 15 GCMs project declines in rainfall under all global warming scenarios with a median decline of 8% resulting in a median decline in runoff of 25%. Such uniformity in projections from GCMs is unusual. Over SWA the average annual runoff under the 5th wettest and 5th driest of the 45 projections of the 2030 climate declines by 10 and 42%, respectively. Under the 5th driest projection the runoff decline ranges from 53% in the northern region to 40% in the southern region. Strong regional variations in climate sensitivity are found with the proportional decline in runoff greatest in the northern region and the greatest volumetric declines in the wetter basins in the south. Since the mid 1970s stream flows into the major water supply reservoirs in SWA have declined by more than 50% following a 16% rainfall reduction. This has already had major implications for water resources planning and for the preservation of aquatic and riparian ecosystems in the region. Our results indicate that this reduction in runoff is likely to continue if future climate projections eventuate.

  12. Trend and concentrations of legacy lead (Pb) in highway runoff

    International Nuclear Information System (INIS)

    Kayhanian, Masoud

    2012-01-01

    This study presents the results of lead (Pb) concentrations from both highway runoff and contaminated soil along 32 and 23 highway sites, respectively. In general, the Pb concentration on topsoil (0–15 cm) along highways was much higher than the Pb concentration in subsurface soil (15–60 cm). The Pb deposited on soil appears to be anthropogenic and a strong correlation was found between the Pb concentration in surface soil and highway runoff in urban areas. The concentration of Pb measured during 1980s from highways runoff throughout the world was up to 11 times higher than the measured values in mid 1990s and 2000s. The current Pb deposited on soil near highways appears to be a mixture of paint, tire weight balance and old leaded gasoline combustion. Overall, the Pb phase-out regulation reduced the Pb deposits in the environment and consequently lowered Pb loading into receiving waters. - Highlights: ► Pb concentrations in highway runoff ranged from 0.5 to 752 mg/L. ► 78% of total lead concentration in highway runoff was in particulate form. ► Pb deposited on highway sites was mostly within 0 to 15 cm of soil column. ► Pb concentration in highway runoff and top soil was strongly correlated. ► Current Pb concentration in highway runoff is up to 11 times lower than late 1980s. - Most Pb deposited on soil near highways is within the top 15 cm. This Pb is the major sources of Pb concentration in highway runoff that has substantially been reduced since lead phase-out era.

  13. Chemistry of SOFC Cathode Surfaces: Fundamental Investigation and Tailoring of Electronic Behavior

    Energy Technology Data Exchange (ETDEWEB)

    Yildiz, Bilge; Heski, Clemens

    2013-08-31

    1) Electron tunneling characteristics on La0.7Sr0.3MnO3 (LSM) thin-film surfaces were studied up to 580oC in 10-3mbar oxygen pressure, using scanning tunneling microscopy/ spectroscopy (STM/STS). A threshold-like drop in the tunneling current was observed at positive bias in STS, which is interpreted as a unique indicator for the activation polarization in cation oxygen bonding on LSM cathodes. Sr-enrichment was found on the surface at high temperature using Auger electron spectroscopy, and was accompanied by a decrease in tunneling conductance in STS. This suggests that Sr-terminated surfaces are less active for electron transfer in oxygen reduction compared to Mn-terminated surfaces on LSM. 2) Effects of strain on the surface cation chemistry and the electronic structure are important to understand and control for attaining fast oxygen reduction kinetics on transition metal oxides. Here, we demonstrate and mechanistically interpret the strain coupling to Sr segregation, oxygen vacancy formation, and electronic structure on the surface of La0.7Sr0.3MnO3 (LSM) thin films as a model system. Our experimental results from x-ray photoelectron spectroscopy and scanning tunneling spectroscopy are discussed in light of our first principles-based calculations. A stronger Sr enrichment tendency and a more facile oxygen vacancy formation prevail for the tensile strained LSM surface. The electronic structure of the tensile strained LSM surface exhibits a larger band gap at room temperature, however, a higher tunneling conductance near the Fermi level than the compressively strained LSM at elevated temperatures in oxygen. Our findings suggest lattice strain as a key parameter to tune the reactivity of perovskite transition metal oxides with oxygen in solid oxide fuel cell cathodes. 3) Cation segregation on perovskite oxide surfaces affects vastly the oxygen reduction activity and stability of solid oxide fuel cell (SOFC) cathodes. A unified theory that explains the physical

  14. Groundwater Recharge, Evapotranspiration and Surface Runoff ...

    African Journals Online (AJOL)

    Bheema

    possible climatic change on basin hydrology and water resources (Alemaw and Chaoka, 2003). Hence ... catchment is mainly controlled by the lithologies, geological structures and geomorphology. Geological ... 2007), which has different climatic and land conditions compared to the tropics, some input parameters ...

  15. Plasma Discharge Effect on Secondary Electron Yield of Various Surface Locations on SRF Cavities

    Science.gov (United States)

    Basovic, Milos; Samolov, Ana; Cuckov, Filip; Tomovic, Mileta; Popovic, Svetozar; Vuskovic, Leposava

    2015-09-01

    Electron activity (field emission and multipacting) has been identified as the main limiting factor of Superconducting Radiofrequency (SRF) cavity performance. Secondary Electron Yield (SEY) is highly dependent on the state of the cavity's surface, which is investigated before and after plasma exposure. Current methods for simulating the electron activity in SRF cavity consider it as a uniform surface. Due to fabricating procedure there are three distinct areas of the cavity's microstructure: weld zone, heat affected zone, and base metal zone. Each zone has a characteristic microstructure even after the treatments that are currently used to clean the surface of the cavities. Improvement of existing surface treatment techniques, or use of a new is required in order to increase the limit of Q factor towards the theoretical limit of Nb. RF discharge is a promising technique for this purpose. In order to test the effect of the plasma on the SEY of the various cavity surface zones we have developed the experimental setup to measure the energy distribution of the SEY from coupon-like samples. Samples are made in a way that all three zones of cavity surface will be included in the examination. We will present the SEY changes in these three zones before and after plasma treatment.

  16. Various categories of defects after surface alloying induced by high current pulsed electron beam irradiation

    International Nuclear Information System (INIS)

    Luo, Dian; Tang, Guangze; Ma, Xinxin; Gu, Le; Sun, Mingren; Wang, Liqin

    2015-01-01

    Highlights: • Four kinds of defects are found during surface alloying by high current electron beam. • Exploring the mechanism how these defects appear after irradiation. • Increasing pulsing cycles will help to get good surface quality. • Choosing proper energy density will increase surface quality. - Abstract: High current pulsed electron beam (HCPEB) is an attractive advanced materials processing method which could highly increase the mechanical properties and corrosion resistance. However, how to eliminate different kinds of defects during irradiation by HCPEB especially in condition of adding new elements is a challenging task. In the present research, the titanium and TaNb-TiW composite films was deposited on the carburizing steel (SAE9310 steel) by DC magnetron sputtering before irradiation. The process of surface alloying was induced by HCPEB with pulse duration of 2.5 μs and energy density ranging from 3 to 9 J/cm 2 . Investigation of the microstructure indicated that there were several forms of defects after irradiation, such as surface unwetting, surface eruption, micro-cracks and layering. How the defects formed was explained by the results of electron microscopy and energy dispersive spectroscopy. The results also revealed that proper energy density (∼6 J/cm 2 ) and multi-number of irradiation (≥50 times) contributed to high quality of alloyed layers after irradiation

  17. Surface morphology and electronic structure of halogen etched InAs (1 1 1)

    Energy Technology Data Exchange (ETDEWEB)

    Eassa, N., E-mail: nashwa.eassa@nmmu.ac.za [Department of Physics, Nelson Mandela Metropolitan University, P.O. Box 77000, Port Elizabeth 6031 (South Africa); Murape, D.M. [Department of Physics, Nelson Mandela Metropolitan University, P.O. Box 77000, Port Elizabeth 6031 (South Africa); Betz, R. [Department of Chemistry, Nelson Mandela Metropolitan University (South Africa); Neethling, J.H.; Venter, A.; Botha, J.R. [Department of Physics, Nelson Mandela Metropolitan University, P.O. Box 77000, Port Elizabeth 6031 (South Africa)

    2012-05-15

    The reaction of halogen-based etchants with n-InAs (1 1 1)A and the resulting surface morphology and surface electronic structure are investigated using field emission scanning electron microscopy and Raman spectroscopy. Using the intensity ratio of the unscreened longitudinal optical (LO) phonon to the transverse optical (TO) phonon in the Raman spectrum, a significant reduction in band bending is deduced after exposure of the InAs surface to HCl:H{sub 2}O, Br-methanol and I-ethanol for moderate times and concentrations. These procedures also lead to smooth and defect-free InAs surfaces. The improvements in surface properties are reversed, however, if the concentrations of the etchants are increased or the etch time is too long. In the worst cases, pit formation and inverted pyramids with {l_brace}1 1 1{r_brace} side facets are observed. The influence of the etchant concentration and etch time on the morphological and electronic properties of the etched surfaces is reported.

  18. Nano-diamonds surface modifications: understanding of electron exchange mechanisms and evidence of a therapeutic effect

    International Nuclear Information System (INIS)

    Petit, Tristan

    2013-01-01

    In this thesis, a therapeutic effect of nano-diamonds (NDs) has been evidenced by investigating the role of NDs surface chemistry on their electronic properties. More precisely, the generation of reactive oxygen species from detonation NDs under ionizing radiation, which could improve current radiotherapy treatments, has been demonstrated. To this end, surface treatments facilitating electron transfer from NDs to their environment, namely hydrogenation and surface graphitization, were developed. Experimental conditions ensuring an efficient hydrogenation by hydrogen plasma were determined under ultrahigh vacuum, before being used to prepare large quantities of NDs in powder phase. A similar procedure was applied to the surface graphitization of NDs, performed by annealing under vacuum at high temperature. The impact of such surface treatments on the electronic interaction properties of NDs has been investigated under ambient air and after dispersion in water. These surface treatments induce a positive Zeta potential to NDs in water, which origin has been discussed. Finally, their interactions with human tumor cells were observed. Radiosensitization of tumor cells using NDs under gamma irradiation was demonstrated, opening new perspectives for NDs in nano-medicine. (author) [fr

  19. Dynamics of a Rydberg hydrogen atom near a metal surface in the electron-extraction scheme

    Energy Technology Data Exchange (ETDEWEB)

    Iñarrea, Manuel [Área de Física Aplicada, Universidad de La Rioja, Logroño (Spain); Lanchares, Víctor [Departamento de Matemáticas y Computación, Universidad de La Rioja, Logroño, La Rioja (Spain); Palacián, Jesús [Departamento de Ingeniería Matemática e Informática, Universidad Pública de Navarra, Pamplona (Spain); Pascual, Ana I. [Departamento de Matemáticas y Computación, Universidad de La Rioja, Logroño, La Rioja (Spain); Salas, J. Pablo, E-mail: josepablo.salas@unirioja.es [Área de Física Aplicada, Universidad de La Rioja, Logroño (Spain); Yanguas, Patricia [Departamento de Ingeniería Matemática e Informática, Universidad Pública de Navarra, Pamplona (Spain)

    2015-01-23

    We study the classical dynamics of a Rydberg hydrogen atom near a metal surface in the presence of a constant electric field in the electron-extraction situation [1], e.g., when the field attracts the electron to the vacuum. From a dynamical point of view, this field configuration provides a dynamics richer than in the usual ion-extraction scheme, because, depending on the values of field and the atom–surface distance, the atom can be ionized only towards the metal surface, only to the vacuum or to the both sides. The evolution of the phase space structure as a function of the atom–surface distance is explored in the bound regime of the atom. In the high energy regime, the ionization mechanism is also investigated. We find that the classical results of this work are in good agreement with the results obtained in the wave-packet propagation study carried out by So et al. [1]. - Highlights: • We study a classical hydrogen atom near a metal surface plus a electric field. • We explore the phase space structure as a function of the field strength. • We find most of the electronic orbits are oriented along the field direction. • We study the ionization of the atom for several atom–surface distances. • This classical study is in good agreement with the quantum results.

  20. Mapping Carrier Dynamics on Material Surfaces in Space and Time using Scanning Ultrafast Electron Microscopy

    KAUST Repository

    Sun, Jingya

    2016-02-25

    Selectively capturing the ultrafast dynamics of charge carriers on materials surfaces and at interfaces is crucial to the design of solar cells and optoelectronic devices. Despite extensive research efforts over the past few decades, information and understanding about surface-dynamical processes, including carrier trapping and recombination remains extremely limited. A key challenge is to selectively map such dynamic processes, a capability that is hitherto impractical by time-resolved laser techniques, which are limited by the laser’s relatively large penetration depth and consequently they record mainly bulk information. Such surface dynamics can only be mapped in real space and time by applying four-dimensional (4D) scanning ultrafast electron microscopy (S-UEM), which records snapshots of materials surfaces with nanometer spatial and sub-picosecond temporal resolutions. In this method, the secondary electron (SE) signal emitted from the sample’s surface is extremely sensitive to the surface dynamics and is detected in real time. In several unique applications, we spatially and temporally visualize the SE energy gain and loss, the charge carrier dynamics on the surface of InGaN nanowires and CdSe single crystals and its powder film. We also provide the mechanisms for the observed dynamics, which will be the foundation for future potential applications of S-UEM to a wide range of studies on material surfaces and device interfaces.

  1. Rainfall-Runoff Parameters Uncertainity

    Science.gov (United States)

    Heidari, A.; Saghafian, B.; Maknoon, R.

    2003-04-01

    Karkheh river basin, located in southwest of Iran, drains an area of over 40000 km2 and is considered a flood active basin. A flood forecasting system is under development for the basin, which consists of a rainfall-runoff model, a river routing model, a reservior simulation model, and a real time data gathering and processing module. SCS, Clark synthetic unit hydrograph, and Modclark methods are the main subbasin rainfall-runoff transformation options included in the rainfall-runoff model. Infiltration schemes, such as exponentioal and SCS-CN methods, account for infiltration losses. Simulation of snow melt is based on degree day approach. River flood routing is performed by FLDWAV model based on one-dimensional full dynamic equation. Calibration and validation of the rainfall-runoff model on Karkheh subbasins are ongoing while the river routing model awaits cross section surveys.Real time hydrometeological data are collected by a telemetry network. The telemetry network is equipped with automatic sensors and INMARSAT-C comunication system. A geographic information system (GIS) stores and manages the spatial data while a database holds the hydroclimatological historical and updated time series. Rainfall runoff parameters uncertainty is analyzed by Monte Carlo and GLUE approaches.

  2. Surface science analysis of GaAs photocathodes following sustained electron beam delivery

    Directory of Open Access Journals (Sweden)

    V. Shutthanandan

    2012-06-01

    Full Text Available Degradation of the photocathode materials employed in photoinjectors represents a challenge for sustained operation of nuclear physics accelerators and high power free electron lasers (FEL. Photocathode quantum efficiency degradation is due to residual gases in the electron source vacuum system being ionized and accelerated back to the photocathode. These investigations are a first attempt to characterize the nature of the photocathode degradation, and employ multiple surface and bulk analysis techniques to investigate damage mechanisms including sputtering of the Cs-oxidant surface monolayer, other surface chemistry effects, and ion implantation. Surface and bulk analysis studies were conducted on two GaAs photocathodes, which were removed from the JLab FEL DC photoemission gun after delivering electron beam, and two control samples. The analysis techniques include helium ion microscopy, Rutherford backscattering spectrometry (RBS, atomic force microscopy, and secondary ion mass spectrometry (SIMS. In addition, two high-polarization strained superlattice GaAs photocathode samples, one removed from the continuous electron beam accelerator facility (CEBAF photoinjector and one unused, were also analyzed using transmission electron microscopy (TEM and SIMS. It was found that heat cleaning the FEL GaAs wafer introduces surface roughness, which seems to be reduced by prolonged use. The bulk GaAs samples retained a fairly well organized crystalline structure after delivering beam but show evidence of Cs depletion on the surface. Within the precision of the SIMS and RBS measurements, the data showed no indication of hydrogen implantation or lattice damage from ion back bombardment in the bulk GaAs wafers. In contrast, SIMS and TEM measurements of the strained superlattice photocathode show clear crystal damage in the wafer from ion back bombardment.

  3. Surface science analysis of GaAs photocathodes following sustained electron beam delivery

    Energy Technology Data Exchange (ETDEWEB)

    Carlos Hernandez-Garcia, Fay Hannon, Marcy Stutzman, V. Shutthanandan, Z. Zhu, M. Nandasri, S. V. Kuchibhatla, S. Thevuthasan, W. P. Hess

    2012-06-01

    Degradation of the photocathode materials employed in photoinjectors represents a challenge for sustained operation of nuclear physics accelerators and high power Free Electron Lasers (FEL). Photocathode quantum efficiency (QE) degradation is due to residual gasses in the electron source vacuum system being ionized and accelerated back to the photocathode. These investigations are a first attempt to characterize the nature of the photocathode degradation, and employ multiple surface and bulk analysis techniques to investigate damage mechanisms including sputtering of the Cs-oxidant surface monolayer, other surface chemistry effects, and ion implantation. Surface and bulk analysis studies were conducted on two GaAs photocathodes, which were removed from the JLab FEL DC photoemission gun after delivering electron beam, and two control samples. The analysis techniques include Helium Ion Microscopy (HIM), Rutherford Backscattering Spectrometry (RBS), Atomic Force Microscopy (AFM) and Secondary Ion Mass Spectrometry (SIMS). In addition, two high-polarization strained superlattice GaAs photocathode samples, one removed from the Continuous Electron Beam Accelerator Facility (CEBAF) photoinjector and one unused, were also analyzed using Transmission Electron Microscopy (TEM) and SIMS. It was found that heat cleaning the FEL GaAs wafer introduces surface roughness, which seems to be reduced by prolonged use. The bulk GaAs samples retained a fairly well organized crystalline structure after delivering beam but shows evidence of Cs depletion on the surface. Within the precision of the SIMS and RBS measurements the data showed no indication of hydrogen implantation or lattice damage from ion back bombardment in the bulk GaAs wafers. In contrast, SIMS and TEM measurements of the strained superlattice photocathode show clear crystal damage in the wafer from ion back bombardment.

  4. Calibration of Rainfall-Runoff Parameters in Peatlands

    Science.gov (United States)

    Walle Menberu, Meseret; Torabi Haghighi, Ali; Kløve, Bjørn

    2013-04-01

    Finland is a country where its possession of peatlands compared to the total surface area of the country puts in the leading categories globally in peatland possession having 33.5% of its total land area covered with peatlands. Recent interest has grown in using peatlands as temporary flood control barriers by taking advantage of the high water holding capacity of peat soils. Water holding capacity of peat soils enables to reduce high rate of runoff and peak flow which might endanger downstream of the flow and in the process of doing that, the rest of the water leaving the peatland areas is less polluted due to the wetlands' potential in purifying polluted water. Therefore, in order to understand how capable enough peatlands are in holding water by reducing the peak flow or slowing down the rate of runoff, this paper analyses the rainfall-runoff phenomena in peatland catchments through important runoff parameters. Among the most important runoff parameters; the initial abstraction, the curve number and lag time are selected for this paper due to their highest impact on rainfall-runoff process. For this study, two peatland catchments of drained and pristine are selected. Managing to explain the initial abstraction and curve number behaviour in the catchments will able to clearly understand and as well predict the rainfall-runoff process in the catchments. In the selected study sites, observed rainfall and runoff data are collected. The study sites are modelled with the help of Arc-GIS and Hec-GeoHMS and from that are exported to HEC-HMS (Hydrologic modelling software) for rainfall-runoff analysis. The two important parameters; the initial abstraction and curve number are used to calibrate the model. And finally, the parameters that have given the best fit between the modelled and observed rainfall-runoff process are suggested for the study sites. Having these parameters estimated eases to understand rainfall-runoff process in the catchments for whatsoever purpose

  5. Electron microscopy studies of zirconia-alumina nanolaminates and nickel oxide surfaces

    Science.gov (United States)

    Schofield, Marvin Allan

    Understanding the atomic scale properties and behavior of materials systems offers exciting potential for the development of fresh and innovative technological applications to impact the world in which we live. The basic materials physics problem addressed in this dissertation involves separate studies of the effects owing to the existence of surfaces present in two types of oxide systems: that of polycrystalline zirconia in zirconia-alumina multilayer films, and that of single-crystal NiO. The first surface science problem involved study of nanometer-sized zirconia crystallites. Due to the small crystallite size, energetics occurring at the surface of crystallites affected properties of the bulk material including its crystallographic phase. High resolution transmission electron microscopy was used to characterize zirconia crystallites within sputter-deposited films containing a range of zirconia layer thickness, i.e. zirconia crystallite size, and crystallographic phase identification of individual crystallites was made directly from digital high resolution images. Information about the growth behavior of zirconia crystallites was inferred from the observed phase and morphology of crystallites as a function of zirconia layer thickness, i.e. growth time. The capabilities for rapid phase identification of individual crystallites allowed for in situ experimentation into the crystallographic phase transformation behavior of the zirconia nanocrystallites, and for a comparison of that behavior to be made against reported behavior of systems containing much larger, micron-sized zirconia crystals. The second surface science problem involved study of surfaces of single-crystal NiO, specifically, the polar-(111) surface. The NiO(111) surface, when the surface atoms are in their bulk-terminated positions, has an infinite surface energy. Studies were carried out to examine by what mechanisms the polar surface of NiO overcomes this large surface energy. Transmission electron

  6. Ultrafast electron dynamics at alkali/ice structures adsorbed on a metal surface

    International Nuclear Information System (INIS)

    Meyer, Michael

    2011-01-01

    The goal of this work is to study the interaction between excess electrons in water ice structures adsorbed on metal surfaces and other charged or neutral species, like alkali ions, or chemically reactive molecules, like chlorofluorocarbons (CFC), respectively. The excess electrons in the ice can interact with the ions directly or indirectly via the hydrogen bonded water molecules. In both cases the presence of the alkali influences the population, localization, and lifetime of electronic states of excess electrons in the ice adlayer. These properties are of great relevance when considering the highly reactive character of the excess electrons, which can mediate chemical reactions by dissociative electron attachment (DEA). The influence of alkali adsorption on electron solvation and transfer dynamics in ice structures is investigated for two types of adsorption configurations using femtosecond time-resolved two-photon photoelectron spectroscopy. In the first system alkali atoms are coadsorbed on top of a wetting amorphous ice film adsorbed on Cu(111). At temperatures between 60 and 100 K alkali adsorption leads to the formation of positively charged alkali ions at the ice/vacuum interface. The interaction between the alkali ions at the surface and the dipole moments of the surrounding water molecules results in a reorientation of the water molecules. As a consequence new electron trapping sites, i.e. at local potential minima, are formed. Photoinjection of excess electrons into these alkali-ion covered amorphous ice layers, results in the trapping of a solvated electron at an alkali-ion/water complex. In contrast to solvation in pure amorphous ice films, where the electrons are located in the bulk of the ice layer, solvated electrons at alkali-ion/water complexes are located at the ice/vacuum interface. They exhibit lifetimes of several picoseconds and show a fast energetic stabilization. With ongoing solvation, i.e. pump-probe time delay, the electron transfer is

  7. Comparative investigation of surface transfer doping of hydrogen terminated diamond by high electron affinity insulators

    Energy Technology Data Exchange (ETDEWEB)

    Verona, C.; Marinelli, Marco; Verona-Rinati, G. [Dip. di Ingegneria Industriale, Università di Roma “Tor Vergata,” Via del Politecnico 1, I-00133 Roma (Italy); Ciccognani, W.; Colangeli, S.; Limiti, E. [Dip. di Ingegneria Elettronica, Università di Roma “Tor Vergata,” Via del Politecnico 1, I-00133 Roma (Italy)

    2016-07-14

    We report on a comparative study of transfer doping of hydrogenated single crystal diamond surface by insulators featured by high electron affinity, such as Nb{sub 2}O{sub 5}, WO{sub 3}, V{sub 2}O{sub 5}, and MoO{sub 3}. The low electron affinity Al{sub 2}O{sub 3} was also investigated for comparison. Hole transport properties were evaluated in the passivated hydrogenated diamond films by Hall effect measurements, and were compared to un-passivated diamond films (air-induced doping). A drastic improvement was observed in passivated samples in terms of conductivity, stability with time, and resistance to high temperatures. The efficiency of the investigated insulators, as electron accepting materials in hydrogenated diamond surface, is consistent with their electronic structure. These surface acceptor materials generate a higher hole sheet concentration, up to 6.5 × 10{sup 13} cm{sup −2}, and a lower sheet resistance, down to 2.6 kΩ/sq, in comparison to the atmosphere-induced values of about 1 × 10{sup 13} cm{sup −2} and 10 kΩ/sq, respectively. On the other hand, hole mobilities were reduced by using high electron affinity insulator dopants. Hole mobility as a function of hole concentration in a hydrogenated diamond layer was also investigated, showing a well-defined monotonically decreasing trend.

  8. Temperature-dependent electronic decay profiles in CZT: probe of bulk and surface properties

    Science.gov (United States)

    Kessick, Royal; Maupin, Hugh; Tepper, Gary C.; Szeles, Csaba

    2003-01-01

    The electronic performance of CZT-based gamma radiation spectrometers is governed by a synergism of bulk and surface properties. Compensation is used to increase the bulk resistivity of Cd1-xZnxTe (x~0.1), but the same electronic states that are introduced to increase the material resistivity can also trap charge and reduce the carrier lifetime. Electrical and mechanical surface defects introduced during or subsequent to crystal harvesting are also known to interfere with device performance. Using a contactless, pulsed laser microwave cavity perturbation technique, electronic decay profiles were studied in high pressure Bridgman CZT as a function of temperature. The electronic decay profile was found to depend very strongly on temperature and was modeled using a function consisting of two exponential terms with temperature-dependent amplitudes and time constants. The model was used to relate the observed temperature dependent decay kinetics in CZT to specific trap energies. It was found that, at low temperatures, the electronic decay process is dominated by a deep trap with an energy of approximately 0.69 +/- 0.1 eV from the band edge. As the temperature is increased, the charge trapping becomes dominated by a second trap with an energy of approximately 0.60 +/- 0.1 eV from the band edge. Surface damage introduces additional charge traps that significantly alter the decay kinetics particularly at low temperatures.

  9. Dose distribution considerations of medium energy electron beams at extended source-to-surface distance

    International Nuclear Information System (INIS)

    Saw, Cheng B.; Ayyangar, Komanduri M.; Pawlicki, Todd; Korb, Leroy J.

    1995-01-01

    Purpose: To determine the effects of extended source-to-surface distance (SSD) on dose distributions for a range of medium energy electron beams and cone sizes. Methods and Materials: The depth-dose curves and isodose distributions of 6 MeV, 10 MeV, and 14 MeV electron beams from a dual photon and multielectron energies linear accelerator were studied. To examine the influence of cone size, the smallest and the largest cone sizes available were used. Measurements were carried out in a water phantom with the water surface set at three different SSDs from 101 to 116 cm. Results: In the region between the phantom surface and the depth of maximum dose, the depth-dose decreases as the SSD increases for all electron beam energies. The effects of extended SSD in the region beyond the depth of maximum dose are unobservable and, hence, considered minimal. Extended SSD effects are apparent for higher electron beam energy with small cone size causing the depth of maximum dose and the rapid dose fall-off region to shift deeper into the phantom. However, the change in the depth-dose curve is small. On the other hand, the rapid dose fall-off region is essentially unaltered when the large cone is used. The penumbra enlarges and electron beam flatness deteriorates with increasing SSD

  10. Accuracy of surface strain measurements from transmission electron microscopy images of nanoparticles

    DEFF Research Database (Denmark)

    Madsen, Jacob; Liu, Pei; Wagner, Jakob Birkedal

    2017-01-01

    Strain analysis from high-resolution transmission electron microscopy (HRTEM) images offers a convenient tool for measuring strain in materials at the atomic scale. In this paper we present a theoretical study of the precision and accuracy of surface strain measurements directly from aberration...

  11. Electrical conductivity and electron cyclotron current drive efficiencies for non-circular flux surfaces in tokamaks

    International Nuclear Information System (INIS)

    O'Brien, M.R.

    1989-01-01

    As is well known, the presence of electron trapping can strongly reduce the electrical conductivity and rf current drive efficiencies of tokamak plasmas. For example, the conductivity (in the low collisionality limit) of a flux surface with inverse aspect ratio ε=0.1 is approximately one half of the Spitzer conductivity (σ sp )for uniform magnetic fields. Previous estimates of these effects have assumed that the variation of magnetic field strength around a flux surface is given by the standard form for circular flux surfaces. (author) 11 refs., 4 figs

  12. Escoamento superficial e desagregação do solo em entressulcos em solo franco-argilo-arenoso com resíduos vegetais Interrill surface runoff and soil detachment on a sandy clay loam soil with residue cover

    Directory of Open Access Journals (Sweden)

    Elemar Antonino Cassol

    2004-07-01

    depth and hydraulic roughness, and a decrease in the mean flow velocity, due to an increase in the viscous forces from the physical interference of residue on runoff, thus contributing to a reduction in interrill soil detachment rate (Di. The Di was 5.35x10-4 kg m-2 s-1 for bare soil and was reduced to 1.50x10-5 kg m-2 s-1 for soil with 100% of surface cover. The Laflen's and the potential models were adequate to estimate the coefficient of soil coverage by residue in direct contact with soil as a function of the soil surface cover.

  13. Surface nanostructuring of LiNbO3 by high-density electronic excitations

    International Nuclear Information System (INIS)

    El-Said, A.S.; Wilhelm, R.A.; Facsko, S.; Trautmann, C.

    2013-01-01

    Lithium niobate (LiNbO 3 ) single crystals were irradiated with high energy gold ions (0.5–2.2 GeV) at the UNILAC (GSI) and with 150-keV highly charged xenon ions from an EBIT (Electron Beam Ion Trap, HZDR). The surfaces of the irradiated crystals were analyzed by scanning force microscopy showing very similar topographic changes. Swift heavy ions and slow highly charged ions produce hillock-like nanostructures on the surface. In both cases, the energy deposition of the ions is characterized by dense localized electronic excitations and efficient transfer to the lattice. Furthermore, the irradiation results in a shift in the band gap energy as evidenced by UV–Vis absorption spectroscopy. Specific modifications (e.g. hillock size, energy loss threshold) induced by slow highly charged ions are discussed in comparison with effects due to the electronic energy loss by swift heavy ions

  14. Surface nanostructuring of LiNbO{sub 3} by high-density electronic excitations

    Energy Technology Data Exchange (ETDEWEB)

    El-Said, A.S., E-mail: elsaid@kfupm.edu.sa [Institute of Ion Beam Physics and Materials Research, Helmholtz-Zentrum Dresden-Rossendorf (HZDR), 01328 Dresden (Germany); Physics Department, King Fahd University of Petroleum and Minerals, Dhahran 31261 (Saudi Arabia); Nuclear and Radiation Physics Lab, Physics Department, Faculty of Science, Mansoura University, 35516 Mansoura (Egypt); Wilhelm, R.A. [Institute of Ion Beam Physics and Materials Research, Helmholtz-Zentrum Dresden-Rossendorf (HZDR), 01328 Dresden (Germany); Technische Universität Dresden, 01062 Dresden (Germany); Facsko, S. [Institute of Ion Beam Physics and Materials Research, Helmholtz-Zentrum Dresden-Rossendorf (HZDR), 01328 Dresden (Germany); Trautmann, C. [GSI Helmholtz Centre for Heavy Ion Research, 64291 Darmstadt (Germany); Technische Universität Darmstadt, 64289 Darmstadt (Germany)

    2013-11-15

    Lithium niobate (LiNbO{sub 3}) single crystals were irradiated with high energy gold ions (0.5–2.2 GeV) at the UNILAC (GSI) and with 150-keV highly charged xenon ions from an EBIT (Electron Beam Ion Trap, HZDR). The surfaces of the irradiated crystals were analyzed by scanning force microscopy showing very similar topographic changes. Swift heavy ions and slow highly charged ions produce hillock-like nanostructures on the surface. In both cases, the energy deposition of the ions is characterized by dense localized electronic excitations and efficient transfer to the lattice. Furthermore, the irradiation results in a shift in the band gap energy as evidenced by UV–Vis absorption spectroscopy. Specific modifications (e.g. hillock size, energy loss threshold) induced by slow highly charged ions are discussed in comparison with effects due to the electronic energy loss by swift heavy ions.

  15. Effects of surface functionalization on the electronic and structural properties of carbon nanotubes: A computational approach

    Science.gov (United States)

    Ribeiro, M. S.; Pascoini, A. L.; Knupp, W. G.; Camps, I.

    2017-12-01

    Carbon nanotubes (CNTs) have important electronic, mechanical and optical properties. These features may be different when comparing a pristine nanotube with other presenting its surface functionalized. These changes can be explored in areas of research and application, such as construction of nanodevices that act as sensors and filters. Following this idea, in the current work, we present the results from a systematic study of CNT's surface functionalized with hydroxyl and carboxyl groups. Using the entropy as selection criterion, we filtered a library of 10k stochastically generated complexes for each functional concentration (5, 10, 15, 20 and 25%). The structurally related parameters (root-mean-square deviation, entropy, and volume/area) have a monotonic relationship with functionalization concentration. Differently, the electronic parameters (frontier molecular orbital energies, electronic gap, molecular hardness, and electrophilicity index) present and oscillatory behavior. For a set of concentrations, the nanotubes present spin polarized properties that can be used in spintronics.

  16. Electron spectroscopy studies of surface In-Ag alloy formation on the tungsten surface

    International Nuclear Information System (INIS)

    Bukaluk, A.; Trzcinski, M.; Okulewicz, K.

    2008-01-01

    XPS and UPS investigations of ultrathin films of In/Ag and Ag/In, deposited onto the W(1 1 0) surface in the ultrahigh vacuum conditions have been performed. Indium and silver films were formed by 'in-situ' evaporation on W(1 1 0) substrate. XPS and UPS studies have been performed by means of SCIENTA ESCA200 instrument. The changes of In4d core-level and Ag4d valence band emissions with increasing Ag and In coverage were monitored to observe the energy shift and shape of the spin-orbit doublet of In4d and Ag4d lines in the Ag/In/W and In/Ag/W systems. UPS (HeI and HeII) measurements were supported by XPS AlK α measurements of In3d and W4p levels, as well as by investigations of Ag3d levels. XPS and UPS data allowed to evaluate the coverage and make conclusions concerning intermixing and surface alloying in the In/Ag/W and Ag/In/W systems. W(1 1 0) substrate can be cleaned after each deposition by thermal desorption and no alloying in the In/W and Ag/W systems is observed

  17. Probing Ultrafast Electron Dynamics at Surfaces Using Soft X-Ray Transient Reflectivity Spectroscopy

    Science.gov (United States)

    Baker, L. Robert; Husek, Jakub; Biswas, Somnath; Cirri, Anthony

    The ability to probe electron dynamics with surface sensitivity on the ultrafast time scale is critical for understanding processes such as charge separation, injection, and surface trapping that mediate efficiency in catalytic and energy conversion materials. Toward this goal, we have developed a high harmonic generation (HHG) light source for femtosecond soft x-ray reflectivity. Using this light source we investigated the ultrafast carrier dynamics at the surface of single crystalline α-Fe2O3, polycrystalline α-Fe2O3, and the mixed metal oxide, CuFeO2. We have recently demonstrated that CuFeO2 in particular is a selective catalyst for photo-electrochemical CO2 reduction to acetate; however, the role of electronic structure and charge carrier dynamics in mediating catalytic selectivity has not been well understood. Soft x-ray reflectivity measurements probe the M2,3, edges of the 3d transition metals, which provide oxidation and spin state resolution with element specificity. In addition to chemical state specificity, these measurements are also surface sensitive, and by independently simulating the contributions of the real and imaginary components of the complex refractive index, we can differentiate between surface and sub-surface contributions to the excited state spectrum. Accordingly, this work demonstrates the ability to probe ultrafast carrier dynamics in catalytic materials with element and chemical state specificity and with surface sensitivity.

  18. The near-surface electron radiation environment of Saturn's moon Mimas

    Science.gov (United States)

    Nordheim, T. A.; Hand, K. P.; Paranicas, C.; Howett, C. J. A.; Hendrix, A. R.; Jones, G. H.; Coates, A. J.

    2017-04-01

    Saturn's inner mid-size moons are exposed to a number of external weathering processes, including charged particle bombardment and UV photolysis, as well as deposition of E-ring grains and interplanetary dust. While optical remote sensing observations by several instruments onboard the Cassini spacecraft have revealed a number of weathering patterns across the surfaces of these moons, it is not entirely clear which external process is responsible for which observed weathering pattern. Here we focus on Saturn's moon Mimas and model the effect of energetic electron bombardment across its surface. By using a combination of a guiding center, bounce-averaged charged particle tracing approach and a particle physics code, we investigate how the radiation dose due to energetic electrons is deposited with depth at different locations. We predict a lens-shaped electron energy deposition pattern that extends down to ∼cm depths at low latitudes centered around the apex of the leading hemisphere (90° W). These results are consistent with previous remote sensing observations of a lens-shaped color anomaly observed by the Imaging Science Subsystem (ISS) instrument as well as a thermal inertia anomaly observed by the Visual and Infrared Mapping Spectrometer (VIMS) and the Composite Infrared Spectrometer (CIRS). Our results confirm that these features are produced by MeV electrons that have a penetration depth into the surface comparable to the effective sampling depths of these instruments. On the trailing hemisphere we predict a similar lens-shaped electron energy deposition pattern, whose effects have to date not been observed by the Cassini remote sensing instruments. We suggest that no corresponding lens-shaped weathering pattern has been observed on the trailing hemisphere because of the comparatively short range of lower energy (<1 MeV) electrons into surface ice, as well as competing effects from cold plasma, neutral, and dust bombardment.

  19. Low-energy electron diffraction experiment, theory and surface structure determination

    CERN Document Server

    Hove, Michel A; Chan, Chi-Ming

    1986-01-01

    Surface crystallography plays the same fundamental role in surface science which bulk crystallography has played so successfully in solid-state physics and chemistry. The atomic-scale structure is one of the most important aspects in the understanding of the behavior of surfaces in such widely diverse fields as heterogeneous catalysis, microelectronics, adhesion, lubrication, cor­ rosion, coatings, and solid-solid and solid-liquid interfaces. Low-Energy Electron Diffraction or LEED has become the prime tech­ nique used to determine atomic locations at surfaces. On one hand, LEED has yielded the most numerous and complete structural results to date (almost 200 structures), while on the other, LEED has been regarded as the "technique to beat" by a variety of other surface crystallographic methods, such as photoemission, SEXAFS, ion scattering and atomic diffraction. Although these other approaches have had impressive successes, LEED has remained the most productive technique and has shown the most versatility...

  20. Electronic structure of surface-supported bis(phthalocyaninato) terbium(III) single molecular magnets.

    Science.gov (United States)

    Vitali, Lucia; Fabris, Stefano; Conte, Adriano Mosca; Brink, Susan; Ruben, Mario; Baroni, Stefano; Kern, Klaus

    2008-10-01

    The electronic structure of isolated bis(phthalocyaninato) terbium(III) molecules, a novel single-molecular-magnet (SMM), supported on the Cu(111) surface has been characterized by density functional theory and scanning tunneling spectroscopy. These studies reveal that the interaction with the metal surface preserves both the molecular structure and the large spin magnetic moment of the metal center. The 4f electron states are not perturbed by the adsorption while a strong molecular/metal interaction can induce the suppression of the minor spin contribution delocalized over the molecular ligands. The calculations show that the inherent spin magnetic moment of the molecule is only weakly affected by the interaction with the surface and suggest that the SMM character might be preserved.

  1. Electron beam irradiation effects on the mechanical, thermal and surface properties of a fluoroelastomer

    International Nuclear Information System (INIS)

    Giovedi, Claudia; Pino, Eddy Segura; Rossi, Marcelo Rabello; Machado, Luci Diva Brocardo

    2007-01-01

    Fluoroelastomer can be used as a sealing material for different purposes. The aim of this work is the evaluation of the effects of the ionizing radiation of an electron beam (EB) on the mechanical, thermal and surface properties of a commercial fluoroelastomer containing carbon black and inorganic fillers. The material was irradiated with overall doses between 10 and 250 kGy. Tensile strength (stress and strain at break), hardness (Shore A) and compression set were evaluated. Thermal behavior was evaluated by thermogravimetric analysis and differential scanning calorimetry. Surface modifications were inspected using scanning electron microscopy (SEM) and optical microscopy. The experiments have shown that EB irradiation promotes beneficial changes in the fluoroelastomer tensile strength behavior while compression set remain constant and the glass transition temperature increases. The SEM micrographs have shown compactness in the irradiated samples, although optical observations showed no surface morphology changes

  2. Models for Surface Roughness Scattering of Electrons in a 2DEG

    International Nuclear Information System (INIS)

    Yarar, Z.

    2004-01-01

    In this work surface roughness scattering of electrons in a two dimensional electron gas (2DEG) formed at heterojunction interfaces is investigated for different auto-correlation tions and potential forms. Gaussian, exponentiaI and lorentsian auto-correlation tions are used to represent surface roughness. Both an infinitely deep triangular potential model and the potential that is found from the numerical solution of Poisson Shrodinger equations self consistently are used as the potential that holds 2DEG at the hetero Interface. Using the wave functions appropriate for the potentials just mentioned and the auto-correlation functions indicated above, the scattering rates due to surface roughness are calculated. The calculations were repeated when the effect of screening is also included for the case of triangular potential

  3. Near-surface electron acceleration during intense laser-solid interaction in the grazing incidence regime

    Science.gov (United States)

    Serebryakov, D. A.; Nerush, E. N.; Kostyukov, I. Yu.

    2017-12-01

    When a relativistically intense p-polarized laser pulse is grazingly incident onto a planar solid-state target, a slightly superluminal field structure is formed near the target surface due to the incident and reflected waves superposition. This field structure can both extract the electrons from the target and accelerate them. It is theoretically shown that the acceleration is possible and stable for a wide range of electron initial conditions. Particle-in-cell simulations confirm that this mechanism can actually take place for realistic parameters. As a result, the electron bunches with a charge of tens of nC and GeV-level energy can be produced using a laser intensity 1021-1022 W/cm2. It is also shown that the presence of a preplasma can improve acceleration, which becomes possible because of more efficient electron injection into the accelerating field structure.

  4. Propagation of a surface electromagnetic wave in a plasma with allowance for electron heating

    International Nuclear Information System (INIS)

    Boev, A.G.; Prokopov, A.V.

    1978-01-01

    Considered is propagation of a surface high-frequency wave in a semibounded plasma, which electron component is heated within the wave field. Dissipative effects are considered small, that is possible if wave frequency is much higher than the collision frequency and phase velocity of wave considerably exceeds electron heat velocity. Under conditions of anomalous skin-effect the distributions of electron temperature and wave damping have been found. It is established, that higher electron temperature on the boundary results in a higher decrease of temperature inside a plasma, far from the boundary temperature decreases exponentially; damping coefficient under anomalous skin-effect conditions is characterized by a stronger dependence not only on the wave amplitude, but as well as on gas pressure and wave frequency in comparison with normal conditions

  5. High resolution electron energy loss spectroscopy of clean and hydrogen covered Si(001) surfaces: first principles calculations.

    Science.gov (United States)

    Patterson, C H

    2012-09-07

    Surface phonons, conductivities, and loss functions are calculated for reconstructed (2×1), p(2×2) and c(4×2) clean Si(001) surfaces, and (2×1) H and D covered Si(001) surfaces. Surface conductivities perpendicular to the surface are significantly smaller than conductivities parallel to the surface. The surface loss function is compared to high resolution electron energy loss measurements. There is good agreement between calculated loss functions and experiment for H and D covered surfaces. However, agreement between experimental data from different groups and between theory and experiment is poor for clean Si(001) surfaces. Formalisms for calculating electron energy loss spectra are reviewed and the mechanism of electron energy losses to surface vibrations is discussed.

  6. Structural and electronic properties of low-index stoichiometric BiOI surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Dai, Wen-Wu; Zhao, Zong-Yan, E-mail: zzy@kmust.edu.cn

    2017-06-01

    As promising photocatalyst driven by visible-light, BiOI has attracted more and more attention in the past years. However, the surface structure and properties of BiOI that is the most important place for the photocatalytic have not been investigated in details. To this end, density functional theory was performed to calculate the structural and electronic properties of four low-index stoichiometric surfaces of BiOI. It is found that the relaxation of the low-index BiOI surfaces are relatively small, especially the (001) surface. Thus, the surface energies of BiOI are very relatively small. Moreover, there are a few surface states below the bottom of conduction band in the first layer except the (001) surface, which maybe capture the photo-excited carriers. In all of the most stable terminated planes, all the dangling bonds are cleaved from the broken Bi-O bonds. In the case of (001) surface, the dangling bond density of Bi atoms for the (001) surface is zero per square nano. Therefore, the (001) surface is thermodynamically lowest-energy surface of BiOI, and it is the predominant surface (51.4%). As a final remark, the dangling bonds density of bismuth atoms determines not only the surface energy, but also the surface relaxation. Finally, the equilibrium morphology of BiOI was also proposed and provided, which is determined through the Wulff construction. These results will help us to better understand the underlying photocatalytic mechanism that is related to BiOI surfaces, and provide theoretical support for some experimental studies about BiOI-based photocatalyst in future. - Highlights: • Four low-index BiOI surfaces have been calculated by DFT method. • The relaxations of the low-index BiOI surfaces are relatively small. • There are a few surface states below the bottom of conduction band in the first layer. • The dangling bonds density of bismuth atoms determines not only the surface energy, but also the surface relaxation. • The thermodynamic

  7. Electron beam induced Hg desorption and the electronic structure of the Hg depleted surface of Hg1/sub -//sub x/Cd/sub x/Te

    International Nuclear Information System (INIS)

    Shih, C.K.; Friedman, D.J.; Bertness, K.A.; Lindau, I.; Spicer, W.E.; Wilson, J.A.

    1986-01-01

    Auger electron spectroscopy (AES), x-ray photoemission spectroscopy (XPS), low energy electron diffraction (LEED), and angle-resolved ultraviolet photoemission spectroscopy (ARPES) were used to study the electron beam induced Hg desorption from a cleaved (110)Hg/sub 1-//sub x/Cd/sub x/Te surface and the electronic structure of the Hg depleted surface. Solid state recrystallized Hg/sub 1-//sub x/Cd/sub x/Te single crystals were used. It was found that the electron beam heating dominated the electron beam induced Hg desorption on Hg/sub 1-//sub x/Cd/sub x/Te. At the electron beam energy used, the electron beam heating extended several thousand angstroms deep. However, the Hg depletion saturated after a few monolayers were depleted of Hg atoms. At the initial stage of Hg loss (only 3%), the surface band bends upward (more p type). The ARPES spectrum showed the loss of some E vs k dispersion after 22% Hg atoms were removed from the surface region, and no dispersion was observed after 43% Hg atoms were removed. These results have important implications on the electronic structure of the surfaces and interfaces of which the stoichiometry is altered

  8. Electron Energy Loss Spectroscopy imaging of surface plasmons at the nanometer scale.

    Science.gov (United States)

    Colliex, Christian; Kociak, Mathieu; Stéphan, Odile

    2016-03-01

    Since their first realization, electron microscopes have demonstrated their unique ability to map with highest spatial resolution (sub-atomic in most recent instruments) the position of atoms as a consequence of the strong scattering of the incident high energy electrons by the nuclei of the material under investigation. When interacting with the electron clouds either on atomic orbitals or delocalized over the specimen, the associated energy transfer, measured and analyzed as an energy loss (Electron Energy Loss Spectroscopy) gives access to analytical properties (atom identification, electron states symmetry and localization). In the moderate energy-loss domain (corresponding to an optical spectral domain from the infrared (IR) to the rather far ultra violet (UV), EELS spectra exhibit characteristic collective excitations of the rather-free electron gas, known as plasmons. Boundary conditions, such as surfaces and/or interfaces between metallic and dielectric media, generate localized surface charge oscillations, surface plasmons (SP), which are associated with confined electric fields. This domain of research has been extraordinarily revived over the past few years as a consequence of the burst of interest for structures and devices guiding, enhancing and controlling light at the sub-wavelength scale. The present review focuses on the study of these surface plasmons with an electron microscopy-based approach which associates spectroscopy and mapping at the level of a single and well-defined nano-object, typically at the nanometer scale i.e. much improved with respect to standard, and even near-field, optical techniques. After calling to mind some early studies, we will briefly mention a few basic aspects of the required instrumentation and associated theoretical tools to interpret the very rich data sets recorded with the latest generation of (Scanning)TEM microscopes. The following paragraphs will review in more detail the results obtained on simple planar and

  9. Electron Energy Loss Spectroscopy imaging of surface plasmons at the nanometer scale

    International Nuclear Information System (INIS)

    Colliex, Christian; Kociak, Mathieu; Stéphan, Odile

    2016-01-01

    Since their first realization, electron microscopes have demonstrated their unique ability to map with highest spatial resolution (sub-atomic in most recent instruments) the position of atoms as a consequence of the strong scattering of the incident high energy electrons by the nuclei of the material under investigation. When interacting with the electron clouds either on atomic orbitals or delocalized over the specimen, the associated energy transfer, measured and analyzed as an energy loss (Electron Energy Loss Spectroscopy) gives access to analytical properties (atom identification, electron states symmetry and localization). In the moderate energy-loss domain (corresponding to an optical spectral domain from the infrared (IR) to the rather far ultra violet (UV), EELS spectra exhibit characteristic collective excitations of the rather-free electron gas, known as plasmons. Boundary conditions, such as surfaces and/or interfaces between metallic and dielectric media, generate localized surface charge oscillations, surface plasmons (SP), which are associated with confined electric fields. This domain of research has been extraordinarily revived over the past few years as a consequence of the burst of interest for structures and devices guiding, enhancing and controlling light at the sub-wavelength scale. The present review focuses on the study of these surface plasmons with an electron microscopy-based approach which associates spectroscopy and mapping at the level of a single and well-defined nano-object, typically at the nanometer scale i.e. much improved with respect to standard, and even near-field, optical techniques. After calling to mind some early studies, we will briefly mention a few basic aspects of the required instrumentation and associated theoretical tools to interpret the very rich data sets recorded with the latest generation of (Scanning)TEM microscopes. The following paragraphs will review in more detail the results obtained on simple planar and

  10. Pan-Arctic distributions of continental runoff in the Arctic Ocean.

    Science.gov (United States)

    Fichot, Cédric G; Kaiser, Karl; Hooker, Stanford B; Amon, Rainer M W; Babin, Marcel; Bélanger, Simon; Walker, Sally A; Benner, Ronald

    2013-01-01

    Continental runoff is a major source of freshwater, nutrients and terrigenous material to the Arctic Ocean. As such, it influences water column stratification, light attenuation, surface heating, gas exchange, biological productivity and carbon sequestration. Increasing river discharge and thawing permafrost suggest that the impacts of continental runoff on these processes are changing. Here, a new optical proxy was developed and implemented with remote sensing to determine the first pan-Arctic distribution of terrigenous dissolved organic matter (tDOM) and continental runoff in the surface Arctic Ocean. Retrospective analyses revealed connections between the routing of North American runoff and the recent freshening of the Canada Basin, and indicated a correspondence between climate-driven changes in river discharge and tDOM inventories in the Kara Sea. By facilitating the real-time, synoptic monitoring of tDOM and freshwater runoff in surface polar waters, this novel approach will help understand the manifestations of climate change in this remote region.

  11. Perceived agricultural runoff impact on drinking water.

    Science.gov (United States)

    Crampton, Andrea; Ragusa, Angela T

    2014-09-01

    Agricultural runoff into surface water is a problem in Australia, as it is in arguably all agriculturally active countries. While farm practices and resource management measures are employed to reduce downstream effects, they are often either technically insufficient or practically unsustainable. Therefore, consumers may still be exposed to agrichemicals whenever they turn on the tap. For rural residents surrounded by agriculture, the link between agriculture and water quality is easy to make and thus informed decisions about water consumption are possible. Urban residents, however, are removed from agricultural activity and indeed drinking water sources. Urban and rural residents were interviewed to identify perceptions of agriculture's impact on drinking water. Rural residents thought agriculture could impact their water quality and, in many cases, actively avoided it, often preferring tank to surface water sources. Urban residents generally did not perceive agriculture to pose health risks to their drinking water. Although there are more agricultural contaminants recognised in the latest Australian Drinking Water Guidelines than previously, we argue this is insufficient to enhance consumer protection. Health authorities may better serve the public by improving their proactivity and providing communities and water utilities with the capacity to effectively monitor and address agricultural runoff.

  12. Wettability modification of human tooth surface by water and UV and electron-beam radiation

    Energy Technology Data Exchange (ETDEWEB)

    Tiznado-Orozco, Gaby E., E-mail: gab0409@gmail.com [UMET, Bâtiment C6, Université de Lille 1, Sciences et Technologies, 59650 Villeneuve d' Ascq (France); Unidad Académica de Odontología, Universidad Autónoma de Nayarit, Edificio E7, Ciudad de la Cultura “Amado Nervo”, C.P. 63190 Tepic, Nayarit (Mexico); Reyes-Gasga, José, E-mail: jreyes@fisica.unam.mx [UMET, Bâtiment C6, Université de Lille 1, Sciences et Technologies, 59650 Villeneuve d' Ascq (France); Instituto de Física, UNAM, Circuito de la Investigación s/n, Ciudad Universitaria, 04510 Coyoacan, México, D.F. (Mexico); Elefterie, Florina, E-mail: elefterie_florina@yahoo.com [UMET, Bâtiment C6, Université de Lille 1, Sciences et Technologies, 59650 Villeneuve d' Ascq (France); Beyens, Christophe, E-mail: christophe.beyens@ed.univ-lille1.fr [UMET, Bâtiment C6, Université de Lille 1, Sciences et Technologies, 59650 Villeneuve d' Ascq (France); Maschke, Ulrich, E-mail: Ulrich.Maschke@univ-lille1.fr [UMET, Bâtiment C6, Université de Lille 1, Sciences et Technologies, 59650 Villeneuve d' Ascq (France); Brès, Etienne F., E-mail: etienne.bres@univ-lille1.fr [UMET, Bâtiment C6, Université de Lille 1, Sciences et Technologies, 59650 Villeneuve d' Ascq (France)

    2015-12-01

    The wettability of the human tooth enamel and dentin was analyzed by measuring the contact angles of a drop of distilled water deposited on the surface. The samples were cut along the transverse and longitudinal directions, and their surfaces were subjected to metallographic mirror-finish polishing. Some samples were also acid etched until their microstructure became exposed. Wettability measurements of the samples were done in dry and wet conditions and after ultraviolet (UV) and electron beam (EB) irradiations. The results indicate that water by itself was able to increase the hydrophobicity of these materials. The UV irradiation momentarily reduced the contact angle values, but they recovered after a short time. EB irradiation raised the contact angle and maintained it for a long time. Both enamel and dentin surfaces showed a wide range of contact angles, from approximately 10° (hydrophilic) to 90° (hydrophobic), although the contact angle showed more variability on enamel than on dentin surfaces. Whether the sample's surface had been polished or etched did not influence the contact angle value in wet conditions. - Highlights: • Human tooth surface wettability changes in dry/wet and UV/EB radiation conditions. • More variability in contact angle is observed on enamel than on dentin surfaces. • Water by itself increases the hydrophobicity of the human tooth surface. • UV irradiation reduces momentarily the human tooth surface hydrophobicity. • EB irradiation increases and maintains the hydrophobicity for a long time.

  13. Adhesion of and to soil in runoff as influenced by polyacrylamide.

    Science.gov (United States)

    Bech, Tina B; Sbodio, Adrian; Jacobsen, Carsten S; Suslow, Trevor

    2014-11-01

    Polyacrylamide (PAM) is used in agriculture to reduce soil erosion and has been reported to reduce turbidity, nutrients, and pollutants in surface runoff water. The objective of this work was to determine the effect of PAM on the concentration of enteric bacteria in surface runoff by comparing four enteric bacteria representing phenotypically different motility and hydrophobicity from three soils. Results demonstrated that bacterial surface runoff was differentially influenced by the PAM treatment. Polyacrylamide treatment increased surface runoff for adhered and planktonic cells from a clay soil; significantly decreased surface runoff of adhered bacteria, while no difference was observed for planktonic bacteria from the sandy loam; and significantly decreased the surface runoff of planktonic cells, while no difference was observed for adhered bacteria from the clay loam. Comparing strains from a final water sample collected after 48 h showed a greater loss of while serovar Poona was almost not detected. Thus, (i) the PAM efficiency in reducing the concentration of enteric bacteria in surface runoff was influenced by soil type and (ii) variation in the loss of enteric bacteria highlights the importance of strain-specific properties that may not be captured with general fecal indicator bacteria. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  14. Effect of MeV Electron Radiation on Europa’s Surface Ice Analogs

    Science.gov (United States)

    Gudipati, Murthy; Henderson, Bryana; Bateman, Fred

    2017-10-01

    MeV electrons that impact Europa’s trailing hemisphere and cause both physical and chemical alteration of the surface and near-surface. The trailing hemisphere receives far lower fluxes above 25 MeV as compared with lower energy particles, but can cause significant chemical and physical modifications at these energies. With NASA's planned Europa Clipper mission and a Europa Lander Concept on the horizon, it is critical to understand and quantify the effect of Europa’s radiation environment on the surface and near surface.Electrons penetrate through ice by far the deepest at any given energy compared to protons and ions, making the role of electrons very important to understand. In addition, secondary radiation - Bremsstrahlung, in X-ray wavelengths - is generated during high-energy particle penetration through solids. Secondary X-rays are equally lethal to life and penetrate even deeper than electrons, making the cumulative effect of radiation on damaging organic matter on the near surface of Europa a complex process that could have effects several meters below Europa’s surface. Other physical properties such as coloration could be caused by radiation.In order to quantify this effect under realistic Europa trailing hemisphere conditions, we devised, built, tested, and obtained preliminary results using our ICE-HEART instrument prototype totally funded by JPL’s internal competition funding for Research and Technology Development. Our Ice Chamber for Europa High-Energy Electron And Radiation-Environment Testing (ICE-HEART) operates at ~100 K. We have also implemented a magnet that is used to remove primary electrons subsequent to passing through an ice column, in order to determine the flux of secondary X-radiation and its penetration through ice.Some of the first results from these studies will be presented and their relevance to understand physical and chemical properties of Europa’s trailing hemisphere surface.This work has been carried out at Jet

  15. Electronic structure at metal-smiconductor surfaces and interfaces: effects of disorder

    International Nuclear Information System (INIS)

    Rodrigues, D.E.

    1988-01-01

    The main concern of this work is the study of the electronic structure at metal and semiconductor surfaces or interfaces, with special emphasis in the effects of disorder and local microstructure upon them. Various factors which determine this structure are presented and those of central importance are identified. A model that allows the efficient and exact calculation of the local density of states at disordered interfaces is described. This model is based on a tight-binding hamiltonian that has enough flexibility so as to allow an adequate description of real solids. The disorder is taken into account by including stochastic perturbations in the diagonal elements of the hamiltonian in a site orbital basis. These perturbations are taken at each layer from a lorentzian probability distribution. An exact expression for the calculation of the local density of states is derived and applied to a model surface built up from a type orbitals arranged in a simple cubic lattice. The effects of disorder on the local densities of states and on the existence of surface Tamm states are studied. The properties of the electronic states with this kind of model of disorder are considered. The self-consistent calculation of the electronic structure of the Si(111) - (1x1) surface is presented. The effects of disorder on the electronic properties such as the work function or the position of surface states within the gap are evaluated. The surface of the metallic compound NiSi 2 is also treated. The first self-consistent calculation of the electronic structure of its (111) surface is presented. The electronic structure of the Si/NiSi 2 (111) interfaces is calculated for the two types of junctions that can be grown experimentally. The origin of the difference between the Schottky barrier heights at both interfaces is discussed. The results are compared with available experimental data. The implications of this calculation on existing theories about the microscopic mechanism that causes

  16. Charge transfer dynamics from adsorbates to surfaces with single active electron and configuration interaction based approaches

    Energy Technology Data Exchange (ETDEWEB)

    Ramakrishnan, Raghunathan, E-mail: r.ramakrishnan@unibas.ch [Institute of Physical Chemistry, National Center for Computational Design and Discovery of Novel Materials (MARVEL), Department of Chemistry, University of Basel, Klingelbergstrasse 80, CH-4056 Basel (Switzerland); Nest, Mathias [Theoretische Chemie, Technische Universität München, Lichtenbergstr. 4, 85747 Garching (Germany)

    2015-01-13

    Highlights: • We model electron dynamics across cyano alkanethiolates attached to gold cluster. • We present electron transfer time scales from TD-DFT and TD-CI based simulations. • Both DFT and CI methods qualitatively predict the trend in time scales. • TD-CI predicts the experimental relative time scale very accurately. - Abstract: We employ wavepacket simulations based on many-body time-dependent configuration interaction (TD-CI), and single active electron theories, to predict the ultrafast molecule/metal electron transfer time scales, in cyano alkanethiolates bonded to model gold clusters. The initial states represent two excited states where a valence electron is promoted to one of the two virtual π{sup ∗} molecular orbitals localized on the cyanide fragment. The ratio of the two time scales indicate the efficiency of one charge transfer channel over the other. In both our one-and many-electron simulations, this ratio agree qualitatively with each other as well as with the previously reported experimental time scales (Blobner et al., 2012), measured for a macroscopic metal surface. We study the effect of cluster size and the description of electron correlation on the charge transfer process.

  17. Dairy heifer manure management, dietary phosphorus, and soil test P effects on runoff phosphorus.

    Science.gov (United States)

    Jokela, William E; Coblentz, Wayne K; Hoffman, Patrick C

    2012-01-01

    Manure application to cropland can contribute to runoff losses of P and eutrophication of surface waters. We conducted a series of three rainfall simulation experiments to assess the effects of dairy heifer dietary P, manure application method, application rate, and soil test P on runoff P losses from two successive simulated rainfall events. Bedded manure (18-21% solids) from dairy heifers fed diets with or without supplemental P was applied on a silt loam soil packed into 1- by 0.2-m sheet metal pans. Manure was either surface-applied or incorporated (Experiment 1) or surface-applied at two rates (Experiment 2) to supply 26 to 63 kg P ha. Experiment 3 evaluated runoff P from four similar nonmanured soils with average Bray P1-extractable P levels of 11, 29, 51, and 75 mg kg. We measured runoff quantity, total P (TP), dissolved reactive P (DRP), and total and volatile solids in runoff collected for 30 min after runoff initiation from two simulated rain events (70 mm h) 3 or 4 d apart. Manure incorporation reduced TP and DRP concentrations and load by 85 to 90% compared with surface application. Doubling the manure rate increased runoff DRP and TP concentrations an average of 36%. In the same experiment, P diet supplementation increased water-extractable P in manure by 100% and increased runoff DRP concentration threefold. Concentrations of solids, TP, and DRP in runoff from Rain 2 were 25 to 75% lower than from Rain 1 in Experiments 1 and 2. Runoff DRP from nonmanured soils increased quadratically with increasing soil test P. These results show that large reductions in P runoff losses can be achieved by incorporation of manure, avoiding unnecessary diet P supplementation, limiting manure application rate, and managing soils to prevent excessive soil test P levels. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  18. ESTfMATING RUNOFF AND SOfL MOfSTURE DEFICIT IN GUINEA ...

    African Journals Online (AJOL)

    hydrological parameters and consequently the estimation of soil moisture deficit, runoff, and evapotranspiration. This model is a single layer soil water balance model that incorporates the physical processes, such as: rainfall, surface runoff, soil evaporation, crop transpiration, root growth, and soil water distribution following ...

  19. Estrogenic activity, estrogens, and calcium in runoff post-layer litter application from rainfall simulated events

    Science.gov (United States)

    Estrogens in runoff from fields fertilized with animal wastes have been implicated as endocrine disruptors of fish in recipient surface waters. The goal of this study was to measure estrogenic activity in runoff post-application of animal waste with the greatest potential for estrogenic activity - ...

  20. Maximum Runoff of the Flood on Wadis of Northern Part of Algeria ...

    African Journals Online (AJOL)

    Wadis of Algeria are characterized by a very irregular hydrological regime. The question of estimating the maximum flow of wadis is relevant. We propose in this paper a method based on an interpretation of the transformation of surface runoff in streamflow. The technique of account the maximal runoff of flood for the rivers ...

  1. Prediction of sediment yield in runoff from agricultural land in the ...

    African Journals Online (AJOL)

    Records on 111 natural rainfall events covering 2 years (2001 and 2003) were used to estimate the sediment yield in runoff from a bare surface Alfisol, and a similar soil under straw mulch and natural grass in the southern Guinea savanna zone of Nigeria. Measurements of runoff amount and sediment load were made for ...

  2. The Role of Electronic Excitations on Chemical Reaction Dynamics at Metal, Semiconductor and Nanoparticle Surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Tully, John C. [Yale Univ., New Haven, CT (United States)

    2017-06-10

    Chemical reactions are often facilitated and steered when carried out on solid surfaces, essential for applications such as heterogeneous catalysis, solar energy conversion, corrosion, materials processing, and many others. A critical factor that can determine the rates and pathways of chemical reactions at surfaces is the efficiency and specificity of energy transfer; how fast does energy move around and where does it go? For reactions on insulator surfaces energy transfer generally moves in and out of vibrations of the adsorbed molecule and the underlying substrate. By contrast, on metal surfaces, metallic nanoparticles and semiconductors, another pathway for energy flow opens up, excitation and de-excitation of electrons. This so-called “nonadiabatic” mechanism often dominates the transfer of energy and can directly impact the course of a chemical reaction. Conventional computational methods such as molecular dynamics simulation do not account for this nonadiabatic behavior. The current DOE-BES funded project has focused on developing the underlying theoretical foundation and the computational methodology for the prediction of nonadiabatic chemical reaction dynamics at surfaces. The research has successfully opened up new methodology and new applications for molecular simulation. In particular, over the last three years, the “Electronic Friction” theory, pioneered by the PI, has now been developed into a stable and accurate computational method that is sufficiently practical to allow first principles “on-the-fly” simulation of chemical reaction dynamics at metal surfaces.

  3. Operation of a novel hot-electron vertical-cavity surface-emitting laser

    Science.gov (United States)

    Balkan, Naci; O'Brien-Davies, Angela; Thoms, A. B.; Potter, Richard J.; Poolton, Nigel; Adams, Michael J.; Masum, J.; Bek, Alpan; Serpenguzel, Ali; Aydinli, Atilla; Roberts, John S.

    1998-07-01

    The hot Electron Light Emission and Lasing in Semiconductor Heterostructures devices (HELLISH-1) is novel surface emitter consisting of a GaAs quantum well, within the depletion region, on the n side of Ga1-xAlxAs p- n junction. It utilizes hot electron transport parallel to the layers and injection of hot electron hole pairs into the quantum well through a combination of mechanisms including tunnelling, thermionic emission and diffusion of `lucky' carriers. Super Radiant HELLISH-1 is an advanced structure incorporating a lower distributed Bragg reflector (DBR). Combined with the finite reflectivity of the upper semiconductor-air interface reflectivity it defines a quasi- resonant cavity enabling emission output from the top surface with a higher spectral purity. The output power has increased by two orders of magnitude and reduced the full width at half maximum (FWHM) to 20 nm. An upper DBR added to the structure defines HELLISH-VCSEL which is currently the first operational hot electron surface emitting laser and lases at room temperature with a 1.5 nm FWHM. In this work we demonstrate and compare the operation of UB-HELLISH-1 and HELLISH-VCSEL using experimental and theoretical reflectivity spectra over an extensive temperature range.

  4. The clinical meaning of radiodermatitis considering the surface dose of supervoltage electron beam

    International Nuclear Information System (INIS)

    Hiraki, Tatsunosuke; Rikimaru, Shigeho; Kakishita, Masao; Kuranishi, Makoto.

    1975-01-01

    In our experience using supervoltage betatron electron beam, the skin surface dose of the electron decreased when the energy became either greater of less than 18 MeV. When we considered 18 MeV to be a 100% dose, the dose with 4 MeV, which was the least amount, corresponded to 81% of the dose. The skin surface dose of 10 MeV betatron electrons or more became greater than the 90% standard tumor dose. An external irradiation of more than 10 MeV should not be applied to neoplasms of which the curative ratio is less than 1.0. Therefore another methods such as intraoperative irradiation, should be used. The surface skin dose about 4-6 MeV betatron postoperative irradiation, particularly after resection of breast cancer, was less than the skin dose with 10 MeV. Close care should be taken to prevent hot lesions which are caused by duplication of irradiation fields. It should be kept in mind that the late effects of hot lesions caused by electron beam irradiation with an energy of 10 MeV or more are serious. (Kashu, E.)

  5. Urban runoff treatment using nano-sized iron oxide coated sand with and without magnetic field applying.

    Science.gov (United States)

    Khiadani Hajian, Mehdi; Zarrabi, Mansur; Foroughi, Maryam

    2013-12-20

    Increase of impervious surfaces in urban area followed with increases in runoff volume and peak flow, leads to increase in urban storm water pollution. The polluted runoff has many adverse impacts on human life and environment. For that reason, the aim of this study was to investigate the efficiency of nano iron oxide coated sand with and without magnetic field in treatment of urban runoff. In present work, synthetic urban runoff was treated in continuous separate columns system which was filled with nano iron oxide coated sand with and without magnetic field. Several experimental parameters such as heavy metals, turbidity, pH, nitrate and phosphate were controlled for investigate of system efficiency. The prepared column materials were characterized with Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray analysis (EDXA) instruments. SEM and EDXA analyses proved that the sand has been coated with nano iron oxide (Fe3O4) successfully. The results of SEM and EDXA instruments well demonstrate the formation of nano iron oxide (Fe3O4) on sand particle. Removal efficiency without magnetic field for turbidity; Pb, Zn, Cd and PO4 were observed to be 90.8%, 73.3%, 75.8%, 85.6% and 67.5%, respectively. When magnetic field was applied, the removal efficiency for turbidity, Pb, Zn, Cd and PO4 was increased to 95.7%, 89.5%, 79.9%, 91.5% and 75.6% respectively. In addition, it was observed that coated sand and magnetic field was not able to remove NO3 ions. Statistical analyses of data indicated that there was a significant difference between removals of pollutants in two tested columns. Results of this study well demonstrate the efficiency of nanosized iron oxide-coated sand in treatment of urban runoff quality; upon 75% of pollutants could be removed. In addition, in the case of magnetic field system efficiency can be improved significantly.

  6. Infiltration and runoff losses under fallowing and conservation ...

    African Journals Online (AJOL)

    2011-02-16

    Feb 16, 2011 ... erosion was not checked immediately by a dynamic policy based on reliable technical information, then ..... infiltration dynamics or changes in infiltration as affected by soil properties like aggregation, .... pores, surface sealing, reduced infiltration rates and increased runoff and soil erosion (Sumner, 1992).

  7. Assessing the response of runoff to climate change and human ...

    Indian Academy of Sciences (India)

    34

    In this study, a typical basin (the control basin of Fuping hydrological station) in the upper reaches of Baiyangdian basin, which is located in the Northern Taihang Mountain, was chosen as the study area. Since the 1960s, under the strong interference of climate change and human activities, the surface runoff constantly ...

  8. IrPd nanoalloys: simulations, from surface