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Sample records for surface reflectance spectra

  1. A climatology of visible surface reflectance spectra

    International Nuclear Information System (INIS)

    Zoogman, Peter; Liu, Xiong; Chance, Kelly; Sun, Qingsong; Schaaf, Crystal; Mahr, Tobias; Wagner, Thomas

    2016-01-01

    We present a high spectral resolution climatology of visible surface reflectance as a function of wavelength for use in satellite measurements of ozone and other atmospheric species. The Tropospheric Emissions: Monitoring of Pollution (TEMPO) instrument is planned to measure backscattered solar radiation in the 290–740 nm range, including the ultraviolet and visible Chappuis ozone bands. Observation in the weak Chappuis band takes advantage of the relative transparency of the atmosphere in the visible to achieve sensitivity to near-surface ozone. However, due to the weakness of the ozone absorption features this measurement is more sensitive to errors in visible surface reflectance, which is highly variable. We utilize reflectance measurements of individual plant, man-made, and other surface types to calculate the primary modes of variability of visible surface reflectance at a high spectral resolution, comparable to that of TEMPO (0.6 nm). Using the Moderate-resolution Imaging Spectroradiometer (MODIS) Bidirection Reflectance Distribution Function (BRDF)/albedo product and our derived primary modes we construct a high spatial resolution climatology of wavelength-dependent surface reflectance over all viewing scenes and geometries. The Global Ozone Monitoring Experiment–2 (GOME-2) Lambertian Equivalent Reflectance (LER) product provides complementary information over water and snow scenes. Preliminary results using this approach in multispectral ultraviolet+visible ozone retrievals from the GOME-2 instrument show significant improvement to the fitting residuals over vegetated scenes. - Highlights: • Our goals was visible surface reflectance for satellite trace gas measurements. • Captured the range of surface reflectance spectra through EOF analysis. • Used satellite surface reflectance products for each given scene to anchor EOFs. • Generated a climatology of time/geometry dependent surface reflectance spectra. • Demonstrated potential to

  2. A climatology of visible surface reflectance spectra

    Science.gov (United States)

    Zoogman, Peter; Liu, Xiong; Chance, Kelly; Sun, Qingsong; Schaaf, Crystal; Mahr, Tobias; Wagner, Thomas

    2016-09-01

    We present a high spectral resolution climatology of visible surface reflectance as a function of wavelength for use in satellite measurements of ozone and other atmospheric species. The Tropospheric Emissions: Monitoring of Pollution (TEMPO) instrument is planned to measure backscattered solar radiation in the 290-740 nm range, including the ultraviolet and visible Chappuis ozone bands. Observation in the weak Chappuis band takes advantage of the relative transparency of the atmosphere in the visible to achieve sensitivity to near-surface ozone. However, due to the weakness of the ozone absorption features this measurement is more sensitive to errors in visible surface reflectance, which is highly variable. We utilize reflectance measurements of individual plant, man-made, and other surface types to calculate the primary modes of variability of visible surface reflectance at a high spectral resolution, comparable to that of TEMPO (0.6 nm). Using the Moderate-resolution Imaging Spectroradiometer (MODIS) Bidirection Reflectance Distribution Function (BRDF)/albedo product and our derived primary modes we construct a high spatial resolution climatology of wavelength-dependent surface reflectance over all viewing scenes and geometries. The Global Ozone Monitoring Experiment-2 (GOME-2) Lambertian Equivalent Reflectance (LER) product provides complementary information over water and snow scenes. Preliminary results using this approach in multispectral ultraviolet+visible ozone retrievals from the GOME-2 instrument show significant improvement to the fitting residuals over vegetated scenes.

  3. Reflectance variability of surface coatings reveals characteristic eigenvalue spectra

    Science.gov (United States)

    Medina, José M.; Díaz, José A.; Barros, Rui

    2012-10-01

    We have examined the trial-to-trial variability of the reflectance spectra of surface coatings containing effect pigments. Principal component analysis of reflectances was done at each detection angle separately. A method for classification of principal components is applied based on the eigenvalue spectra. It was found that the eigenvalue spectra follow characteristic power laws and depend on the detection angle. Three different subsets of principal components were examined to separate the relevant spectral features related to the pigments from other noise sources. Reconstruction of the reflectance spectra by taking only the first subset indicated that reflectance variability was higher at near-specular reflection, suggesting a correlation with the trial-to-trial deposition of effect pigments. Reconstruction by using the second subset indicates that variability was higher at short wavelengths. Finally, reconstruction by using only the third subset indicates that reflectance variability was not totally random as a function of the wavelength. The methods employed can be useful in the evaluation of color variability in industrial paint application processes.

  4. Asteroid surface materials: mineralogical characterizations from reflectance spectra

    International Nuclear Information System (INIS)

    Gaffey, M.J.; McCord, T.B.

    1978-01-01

    The interpretation of diagnostic parameters in the spectral reflectance data for asteroids provides a means of characterizing the mineralogy and petrology of asteroid surface materials. An interpretive technique based on a quantitative understanding of the functional relationship between the optical properties of a mineral assemblage and its mineralogy, petrology and chemistry can provide a considerably more sophisticated characterization of a single material than any matching or classification technique for those objects bright enough to allow spectral reflectance measurements. Albedos derived from radiometry and polarization data for individual asteroids can be used with spectral data to establish the spectral albedo, to define the optical density of the surface material and, in general to constrain mineralogical interpretations. (Auth.)

  5. Observations of discrete energy loss effects in spectra of positrons reflected from solid surfaces

    International Nuclear Information System (INIS)

    Dale, J.M.; Hulett, L.D.; Pendyala, S.

    1980-01-01

    Surfaces of tungsten and silicon have been bombarded with monoenergetic beams of positrons and electrons. Spectra of reflected particles show energy loss tails with discrete peaks at kinetic energies about 15 eV lower than that of the elastic peaks. In the higher energy loss range for tungsten, positron spectra show fine structure that is not apparent in the electron spectra. This suggests that the positrons are losing energy through mechanisms different from that of the electrons

  6. Measurements of reflectance spectra of ion-bombarded ice and application to surfaces in the outer Solar System

    International Nuclear Information System (INIS)

    O'Shaughnessy, D.J.; Boring, J.W.; Johnson, R.E.

    1988-01-01

    A number of the icy satellites of the outer planets exhibit interesting hemispherical differences in brightness which have been attributed to enhanced bombardment by the local plasma of one hemisphere. The plasma bombardment is thought to erode the icy surfaces and implant species, thereby altering the surface reflectance spectra, as well as producing fresh plasma. Here we present the first results of laboratory measurements of the wavelength dependence of the alteration of the visible reflectance spectra of H 2 O ice irradiated by keV ions. When the implanted species is chemically neutral, absorption is slightly enhanced below 0.55 μm. For an incident species containing sulphur, a strong absorption feature is produced at 0.4 μm corresponding (probably) to S 3 . This occurs at too large a wavelength to account for the absorption feature observed at Europa by Voyager and therefore casts doubt on the recent interpretations of the reflectance data of Europa. (author)

  7. Reflectance spectra of subarctic lichens

    International Nuclear Information System (INIS)

    Petzold, D.E.; Goward, S.N.

    1988-01-01

    Lichens constitute a major portion of the ground cover of high latitude environments, but little has been reported concerning their in situ solar spectral reflectance properties. Knowledge of these properties is important for the interpretation of remotely sensed observations from high latitude regions, as well as in studies of high latitude ecology and energy balance climatology. The spectral reflectance of common boreal vascular plants is similar to that of vascular plants of the mid latitudes. The dominant lichens, in contrast, display variable reflectance patterns in visible wavelengths. The relative reflectance peak at 0.55 μm, common to green vegetation, is absent or indistinct in spectra of pervasive boreal forest and tundra lichens, despite the presence of chlorophyll in the inner algal cells. Lichens of the dominant genus, Cladina, display strong absorption of ultraviolet energy and short-wavelength blue light relative to their absorption in other visible wavelengths. Since the Cladinae dominate both the surface vegetation in open woodlands of the boreal forest and the low arctic tundra, their unusual spectral reflectance patterns will enable accurate monitoring of the boreal forest-tundra ecotone and detection of its vigor and movement in the future. (author)

  8. Reflectance spectra of subarctic lichens

    Science.gov (United States)

    Petzold, Donald E.; Goward, Samuel N.

    1988-01-01

    Lichens constitute a major portion of the ground cover of high latitude environments, but little has been reported concerning their in situ solar spectral reflectance properties. Knowledge of these properties is important for the interpretation of remotely sensed observations from high latitude regions, as well as in studies of high latitude ecology and energy balance climatology. The spectral reflectance of common boreal vascular plants is similar to that of vascular plants of the midlatitudes. The dominant lichens, in contrast, display variable reflectance patterns in visible wavelengths. The relative reflectance peak at 0.55 microns, common to green vegetation, is absent or indistinct in spectra of pervasive boreal forest and tundra lichens, despite the presence of chlorophyll in the inner algal cells. Lichens of the dominant genus, Cladina, display strong absorption of ultraviolet energy and short-wavelength blue light relative to their absorption in other visible wavelengths. Since the Cladinae dominate both the surface vegetation in open woodlands of the boreal forest and the low arctic tundra, their unusual spectral reflectance patterns will enable accurate monitoring of the boreal forest-tundra ecotone and detection of its vigor and movement in the future.

  9. Online Monitoring of Laser-Generated XUV Radiation Spectra by Surface Reflectivity Measurements with Particle Detectors

    Directory of Open Access Journals (Sweden)

    Andreas Hoffmann

    2017-01-01

    Full Text Available In this contribution, we present a wavelength-sensitive method for the detection of extreme ultraviolet (XUV photon energies between 30 eV and 120 eV. The method is based on 45° reflectivity from either a cesium iodide-coated or an uncoated metal surface, which directs the XUV beam onto an electron or ion detector and its signal is used to monitor the XUV beam. The benefits of our approach are a spectrally sensitive diagnosis of the XUV radiation at the interaction place of time-resolved XUV experiments and the detection of infrared leak light though metal filters in high-harmonic generation (HHG experiments. Both features were tested using spectrally shaped XUV pulses from HHG in a capillary, and we have achieved excellent agreement with XUV spectrometer measurements and reflectivity calculations. Our obtained results are of interest for time-resolved XUV experiments presenting an additional diagnostic directly in the interaction region and for small footprint XUV beamline diagnostics.

  10. Reflections on Conformal Spectra

    CERN Multimedia

    CERN. Geneva

    2015-01-01

    We use modular invariance and crossing symmetry of conformal field theory to reveal approximate reflection symmetries in the spectral decompositions of the partition function in two dimensions in the limit of large central charge and of the four-point function in any dimension in the limit of large scaling dimensions Δ0 of external operators. We use these symmetries to motivate universal upper bounds on the spectrum and the operator product expansion coefficients, which we then derive by independent techniques. Some of the bounds for four-point functions are valid for finite Δ0 as well as for large Δ0. We discuss a similar symmetry in a large spacetime dimension limit. Finally, we comment on the analogue of the Cardy formula and sparse light spectrum condition for the four-point function. (based on 1510.08772 with Kim & Ooguri). This seminar will be given via videolink

  11. RESEARCH OF THE ENTRANCE ANGLE EFFECT ON THE REFLECTANCE SPECTRA OF THE STAINLESS STEEL SURFACE OXIDIZED BY PULSED LASER RADIATION

    Directory of Open Access Journals (Sweden)

    V. P. Veiko

    2016-05-01

    Full Text Available Subject of Research.Oxide films on the metal surfaces can be obtained both by surface-uniform infrared heating and local laser treatment e.g. by sequence of nanosecond laser pulses. Due to interference in created films the coloration of treated area is observed. The present work shows the results of spectrophotometric measurements for various light entrance angles in the range of 10-60°. Method. AISI 304 stainless steel plates were oxidized by two methods: in muffle furnace FM - 10 (Т= 500-600° С, t = 5-7 min. and at line-by-line scanning by sequence of nanosecond laser pulses (λ = 1.06 μm, τ =100 ns, r = 25 μm,q=2.91∙107 W/cm2, Nx = 30, Ny = 1. Surface research in optical resolution was realized by Carl Zeiss Axio Imager A1M. Reflectance spectra were obtained with spectrophotometer Lambda Perkin 1050 with integrating sphere at different fixed light incidence angles. Topographic features were detected by scanning probe microscopy investigation with NanoEducator equipment. Main Results. The quantitative surface geometry characteristics of AISI 304 stainless steel patterns treated by different methods are obtained. It was found that the increase of light entrance angle has no influence on the form of reflection coefficient dependence from a wavelength, but a blue-shift occurs especially for the case of laser treatment. This difference can be caused by surface topology formed by laser heating and variety of oxide film thickness. This effect results in more significant change in observed sample color for laser treatment then for infrared heating. Practical Relevance. The results obtained in the present work can be used to implement a new element of product protection against forgery with the product marking.

  12. Rapid, nondestructive estimation of surface polymer layer thickness using attenuated total reflection fourier transform infrared (ATR FT-IR) spectroscopy and synthetic spectra derived from optical principles.

    Science.gov (United States)

    Weinstock, B André; Guiney, Linda M; Loose, Christopher

    2012-11-01

    We have developed a rapid, nondestructive analytical method that estimates the thickness of a surface polymer layer with high precision but unknown accuracy using a single attenuated total reflection Fourier transform infrared (ATR FT-IR) measurement. Because the method is rapid, nondestructive, and requires no sample preparation, it is ideal as a process analytical technique. Prior to implementation, the ATR FT-IR spectrum of the substrate layer pure component and the ATR FT-IR and real refractive index spectra of the surface layer pure component must be known. From these three input spectra a synthetic mid-infrared spectral matrix of surface layers 0 nm to 10,000 nm thick on substrate is created de novo. A minimum statistical distance match between a process sample's ATR FT-IR spectrum and the synthetic spectral matrix provides the thickness of that sample. We show that this method can be used to successfully estimate the thickness of polysulfobetaine surface modification, a hydrated polymeric surface layer covalently bonded onto a polyetherurethane substrate. A database of 1850 sample spectra was examined. Spectrochemical matrix-effect unknowns, such as the nonuniform and molecularly novel polysulfobetaine-polyetherurethane interface, were found to be minimal. A partial least squares regression analysis of the database spectra versus their thicknesses as calculated by the method described yielded an estimate of precision of ±52 nm.

  13. Surface states and spectra

    International Nuclear Information System (INIS)

    Jaksic, V.; Last, Y.; California Inst. of Tech., Pasadena, CA

    2001-01-01

    Let Z + d+1 =Z d x Z + , let H 0 be the discrete Laplacian on the Hilbert space l 2 (Z + d+1 ) with a Dirichlet boundary condition, and let V be a potential supported on the boundary ∂Z + d+1 . We introduce the notions of surface states and surface spectrum of the operator H=H 0 +V and explore their properties. Our main result is that if the potential V is random and if the disorder is either large or small enough, then in dimension two H has no surface spectrum on σ(H 0 ) with probability one. To prove this result we combine Aizenman-Molchanov theory with techniques of scattering theory. (orig.)

  14. In-out asymmetry of surface excitations in reflection-electron-energy-loss spectra of polycrystalline Al

    Czech Academy of Sciences Publication Activity Database

    Salvat-Pujol, F.; Werner, W. S. M.; Novák, M.; Jiříček, Petr; Zemek, Josef

    2014-01-01

    Roč. 89, č. 20 (2014), "205435-1"-"205435-7" ISSN 1098-0121 Grant - others:AV ČR(CZ) M100101202 Institutional support: RVO:68378271 Keywords : surface excitation * in-out asymmetry * REELS * Al Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.736, year: 2014

  15. Soil emissivity and reflectance spectra measurements

    International Nuclear Information System (INIS)

    Sobrino, Jose A.; Mattar, Cristian; Pardo, Pablo; Jimenez-Munoz, Juan C.; Hook, Simon J.; Baldridge, Alice; Ibanez, Rafael

    2009-01-01

    We present an analysis of the laboratory reflectance and emissivity spectra of 11 soil samples collected on different field campaigns carried out over a diverse suite of test sites in Europe, North Africa, and South America from 2002 to 2008. Hemispherical reflectance spectra were measured from 2.0 to 14 μm with a Fourier transform infrared spectrometer, and x-ray diffraction analysis (XRD) was used to determine the mineralogical phases of the soil samples. Emissivity spectra were obtained from the hemispherical reflectance measurements using Kirchhoff's law and compared with in situ radiance measurements obtained with a CIMEL Electronique CE312-2 thermal radiometer and converted to emissivity using the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) temperature and emissivity separation algorithm. The CIMEL has five narrow bands at approximately the same positions as the ASTER. Results show a root mean square error typically below 0.015 between laboratory emissivity measurements and emissivity measurements derived from the field radiometer.

  16. Infrared reflectance spectra: effects of particle size, provenance and preparation

    Science.gov (United States)

    Su, Yin-Fong; Myers, Tanya L.; Brauer, Carolyn S.; Blake, Thomas A.; Forland, Brenda M.; Szecsody, J. E.; Johnson, Timothy J.

    2014-10-01

    We have recently developed methods for making more accurate infrared total and diffuse directional - hemispherical reflectance measurements using an integrating sphere. We have found that reflectance spectra of solids, especially powders, are influenced by a number of factors including the sample preparation method, the particle size and morphology, as well as the sample origin. On a quantitative basis we have investigated some of these parameters and the effects they have on reflectance spectra, particularly in the longwave infrared. In the IR the spectral features may be observed as either maxima or minima: In general, upward-going peaks in the reflectance spectrum result from strong surface scattering, i.e. rays that are reflected from the surface without bulk penetration, whereas downward-going peaks are due to either absorption or volume scattering, i.e. rays that have penetrated or refracted into the sample interior and are not reflected. The light signals reflected from solids usually encompass all such effects, but with strong dependencies on particle size and preparation. This paper measures the reflectance spectra in the 1.3 - 16 micron range for various bulk materials that have a combination of strong and weak absorption bands in order to observe the effects on the spectral features: Bulk materials were ground with a mortar and pestle and sieved to separate the samples into various size fractions between 5 and 500 microns. The median particle size is demonstrated to have large effects on the reflectance spectra. For certain minerals we also observe significant spectral change depending on the geologic origin of the sample. All three such effects (particle size, preparation and provenance) result in substantial change in the reflectance spectra for solid materials; successful identification algorithms will require sufficient flexibility to account for these parameters.

  17. The influence of particle size on infrared reflectance spectra

    Science.gov (United States)

    Myers, Tanya L.; Brauer, Carolyn S.; Su, Yin-Fong; Blake, Thomas A.; Johnson, Timothy J.; Richardson, Robert L.

    2014-06-01

    Reflectance spectra of solids are influenced by the absorption coefficient and index of refraction as well as particle size and morphology. In the infrared, spectral features may be observed as either maxima or minima: in general, the upwardgoing peaks in the reflectance spectrum result from surface scattering, which are rays that have reflected from the surface without penetration, whereas downward-going peaks result from either absorption or volume scattering, i.e. rays that have penetrated into the sample to be absorbed or refracted into the sample interior and are not reflected. The light signal reflected from solids usually encompasses all these effects which include dependencies on particle size, morphology and sample density. This paper measures the reflectance spectra in the 1.3 - 16 micron range for various bulk materials that have a combination of strong and weak absorption bands in order to understand the effects on the spectral features as a function of the mean grain size of the sample. The bulk materials were ground and sieved to separate the samples into various size fractions: 0-45, 45-90, 90-180, 180-250, 250-500, and >500 microns. The directional-hemispherical spectra were recorded using a Fourier transform infrared spectrometer equipped with an integrating sphere to measure the reflectance for all of the particle-size fractions. We have studied both organic and inorganic materials, but this paper focuses on inorganic salts, NaNO3, in particular. Our studies clearly show that particle size has an enormous influence on the measured reflectance spectra for bulk materials and that successful identification requires sufficient representative reflectance data so as to include the particle size(s) of interest. Origins of the effects are discussed.

  18. The effect of radiation-thermal treatment on the physicochemical properties of the Ni-Mo/Al2O3 hydrotreatment catalyst. II. UV-Vis diffuse reflectance spectra of surface compounds after irradiation

    International Nuclear Information System (INIS)

    Solovetskii, Yu.I.; Miroshinichenko, I.I.; Lunin, V.V.

    1993-01-01

    Radiation-thermal damage of the surface and the active metal phases of hydrodesulfurization Ni-Mo/Al 2 O 3 catalysts by a fast electron beam of up to 2.0 MeV energy was studied. UV-Vis diffuse reflectance spectra of the industrial and model coked systems after radiation-thermal treatment were measured. 14 refs., 2 figs

  19. REFLECTION SPECTRA OF SKIN IN VITILIGO

    Directory of Open Access Journals (Sweden)

    V. V. Zhulmina

    2013-01-01

    Full Text Available Vitiligo is a disease with unknown etiology, which is characterized by skin depigmentation areas due to melanocyte death. Lack of clear understanding of pathogenic disease processes justifies the difficulty of choosing efficient treatment methods. Repigmentation is slow and not always complete. One of the key indicators in practical dermatology is objective assessment of skin cover condition for further diagnostics, definition of therapy and dynamics of the disease.The purpose of this study is to assess skin reflection spectrum in depigmentation areas, marginal layer and visible healthy skin before and after treatment of patients with vitiligo.21 patients having vitiligo were under observation; the patients were treated in the hospital of skin and venereal diseases of the Siberian State Medical University. The authors applied noninvasive method of spectrophotometry for the first time in order to study skin reflection spectrum of patients with vitiligo. Noninvasive medical spectrophotometry is based on dependence factor of integral optical properties of biological tissues and fluids in the conditions of homeostasis and in case of pathology. In order to assess the efficiency of skin disease treatment the patients were exposed to skin spectrophotometry before the beginning of the treatment and after the treatment itself with further measurements of the reflection spectrum integral criteria. The measurements were made in depigmentation area, on the boundary with healthy skin and in remote from depigmentation area of healthy skin.Obtained results indicate the difference of skin reflection spectra in the areas under investigation. Moreover, positive dynamics of the treatment associated with the decrease in the value of reflection spectrum integral criteria in the diseased area. There were no statistically important differences of the integral criteria, calculated based on measurement results of reflection spectra on the boundary of depigmentation area

  20. THEORETICAL SPECTRA OF TERRESTRIAL EXOPLANET SURFACES

    Energy Technology Data Exchange (ETDEWEB)

    Hu Renyu; Seager, Sara [Department of Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Ehlmann, Bethany L., E-mail: hury@mit.edu [Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125 (United States)

    2012-06-10

    We investigate spectra of airless rocky exoplanets with a theoretical framework that self-consistently treats reflection and thermal emission. We find that a silicate surface on an exoplanet is spectroscopically detectable via prominent Si-O features in the thermal emission bands of 7-13 {mu}m and 15-25 {mu}m. The variation of brightness temperature due to the silicate features can be up to 20 K for an airless Earth analog, and the silicate features are wide enough to be distinguished from atmospheric features with relatively high resolution spectra. The surface characterization thus provides a method to unambiguously identify a rocky exoplanet. Furthermore, identification of specific rocky surface types is possible with the planet's reflectance spectrum in near-infrared broad bands. A key parameter to observe is the difference between K-band and J-band geometric albedos (A{sub g}(K) - A{sub g}(J)): A{sub g}(K) - A{sub g}(J) > 0.2 indicates that more than half of the planet's surface has abundant mafic minerals, such as olivine and pyroxene, in other words primary crust from a magma ocean or high-temperature lavas; A{sub g}(K) - A{sub g}(J) < -0.09 indicates that more than half of the planet's surface is covered or partially covered by water ice or hydrated silicates, implying extant or past water on its surface. Also, surface water ice can be specifically distinguished by an H-band geometric albedo lower than the J-band geometric albedo. The surface features can be distinguished from possible atmospheric features with molecule identification of atmospheric species by transmission spectroscopy. We therefore propose that mid-infrared spectroscopy of exoplanets may detect rocky surfaces, and near-infrared spectrophotometry may identify ultramafic surfaces, hydrated surfaces, and water ice.

  1. Classification of specialty seed meals from NIR reflectance spectra

    Science.gov (United States)

    Near infrared reflectance spectroscopy was used to identify alternative seed meals proposed for food and feed formulations. Spectra were collected from cold pressed Camelina (Camelina sativa), Coriander (Coriandrum sativum), and Pennycress (Thlaspi arvense) meals. Additional spectra were collected ...

  2. Surface composition of Mercury from reflectance spectrophotometry

    Science.gov (United States)

    Vilas, Faith

    1988-01-01

    The controversies surrounding the existing spectra of Mercury are discussed together with the various implications for interpretations of Mercury's surface composition. Special attention is given to the basic procedure used for reducing reflectance spectrophotometry data, the factors that must be accounted for in the reduction of these data, and the methodology for defining the portion of the surface contributing the greatest amount of light to an individual spectrum. The application of these methodologies to Mercury's spectra is presented.

  3. Seedling Canopy Reflectance Spectra, 1992-1993 (ACCP)

    Data.gov (United States)

    National Aeronautics and Space Administration — ABSTRACT: The reflectance spectra of Douglas-fir and bigleaf maple seedling canopies were measured. Canopies varied in fertilizer treatment and leaf area density...

  4. HARDERSEN IRTF ASTEROID NIR REFLECTANCE SPECTRA V1.0

    Data.gov (United States)

    National Aeronautics and Space Administration — This dataset includes average near-infrared (NIR) reflectance spectra for 68 main-belt asteroids that were observed at the NASA Infrared Telescope Facility (IRTF),...

  5. Spectra of resonance surface photoionization

    Energy Technology Data Exchange (ETDEWEB)

    Antsiferov, V.V.; Smirnov, G.I.; Telegin, G.G. [Budker Nuclear Physics Institute, Novosibirsk (Russian Federation)

    1995-09-01

    The theory of nonactivated electron transfer between atoms interacting reasonantly with coherent radiation and a metal surface is developed. The spectral resonances in photoabsorption and surface photoionization are found to be related to nonlinear interference effects in the interaction between discrete atomic levels and the continuum formed by the quasi-continuous electron spectrum of a normal metal. The asymmetry in the resonance surface photoionization spectrum is shown to have a shape typical of the Fano autoionization resonances. 18 refs.

  6. Influence of fluctuating strain on exciton reflection spectra

    DEFF Research Database (Denmark)

    Skettrup, Torben

    1982-01-01

    , for example, between crossed polarizers or from ellipsometric measurements. Assuming the phase fluctuations to obey a Gaussian distribution, σ can be expressed in a simple way in terms of the degree of polarization or the depolarization of the reflected light. σ is then derived in terms of the standard......The influence of an internal distribution of strain on the exciton reflection spectra is investigated. The resulting fluctuating optical constants give rise to a fluctuating phase of reflectivity. The standard deviation σ of these phase fluctuations is the quantity which can be observed...... to derive the dependence of the phase of reflectivity on the direction of the fluctuating optical axis. The results obtained for σ are compared with the experimental depolarization spectra of ZnO. The only fitting parameter is the common standard deviation of the strain components. It is found...

  7. Prediction of pork quality attributes from near infrared reflectance spectra

    NARCIS (Netherlands)

    Geesink, G.H.; Schreutelkamp, F.H.; Frankhuizen, R.; Vedder, H.W.; Faber, N.M.; Kranen, R.W.; Gerritzen, M.A.

    2003-01-01

    Near infrared spectroscopy (NIRS) is one of the most promising techniques for large-scale meat quality evaluation. We investigated the potential of NIRS-based models to predict drip loss and shear force of pork samples. Near infrared reflectance spectra (1000¿2500 nm), water-holding capacity, shear

  8. Quantitative analysis of planetary reflectance spectra with principal components analysis

    Science.gov (United States)

    Johnson, P. E.; Smith, M. O.; Adams, J. B.

    1985-01-01

    A technique is presented for quantitative analysis of planetary reflectance spectra as mixtures of particles on microscopic and macroscopic scales using principal components analysis. This technique allows for determination of the endmembers being mixed, their abundance, and the scale of mixing, as well as other physical parameters. Eighteen lunar telescopic reflectance spectra of the Copernicus crater region, from 600 nm to 1800 nm in wavelength, are modeled in terms of five likely endmembers: mare basalt, mature mare soil, anorthosite, mature highland soil, and clinopyroxene. These endmembers were chosen from a similar analysis of 92 lunar soil and rock samples. The models fit the data to within 2 percent rms. It is found that the goodness of fit is marginally better for intimate mixing over macroscopic mixing.

  9. Subsurface electric field effect on excitonic reflection spectra of CdSe monocrystals

    International Nuclear Information System (INIS)

    Batyrev, A.S.; Novikov, B.V.; Cherednichenko, A.E.

    1981-01-01

    Changes in exciton reflection spectra of CdSe monocrystals under bombardment with 2-3.5 keV electrons at T=4.2 K have been experimentally investigated. Under the same conditions measured was a relative value of surface photo e.m.f. depending on a dose of electron bombardment. A structure, resulted from the Stark well for excitons near surface and bound state in it - mechanical surface exciton, has been detected in nonirradiated crystals. Correlation between changes in the value of photo e.m.f. and the exciton reflection spectrum contour in the process of irradiation has been traced. It is shown that a number of peculiarities in experimental exciton reflection spectra is not explained with the model of the Thomas and Hopfield ''dead layer''. The Kiselev model is used to explain the results [ru

  10. Simulation of attenuated total reflection infrared absorbance spectra: applications to automotive clear coat forensic analysis.

    Science.gov (United States)

    Lavine, Barry K; Fasasi, Ayuba; Mirjankar, Nikhil; Nishikida, Koichi; Campbell, Jay

    2014-01-01

    Attenuated total reflection (ATR) is a widely used sampling technique in infrared (IR) spectroscopy because minimal sample preparation is required. Since the penetration depth of the ATR analysis beam is quite shallow, the outer layers of a laminate or multilayered paint sample can be preferentially analyzed with the entire sample intact. For this reason, forensic laboratories are taking advantage of ATR to collect IR spectra of automotive paint systems that may consist of three or more layers. However, the IR spectrum of a paint sample obtained by ATR will exhibit distortions, e.g., band broadening and lower relative intensities at higher wavenumbers, compared with its transmission counterpart. This hinders library searching because most library spectra are measured in transmission mode. Furthermore, the angle of incidence for the internal reflection element, the refractive index of the clear coat, and surface contamination due to inorganic contaminants can profoundly influence the quality of the ATR spectrum obtained for automotive paints. A correction algorithm to allow ATR spectra to be searched using IR transmission spectra of the paint data query (PDQ) automotive database is presented. The proposed correction algorithm to convert transmission spectra from the PDQ library to ATR spectra is able to address distortion issues such as the relative intensities and broadening of the bands, and the introduction of wavelength shifts at lower frequencies, which prevent library searching of ATR spectra using archived IR transmission data.

  11. Analyzing reflectance spectra of human skin in legal medicine

    Science.gov (United States)

    Belenki, Liudmila; Sterzik, Vera; Schulz, Katharina; Bohnert, Michael

    2013-01-01

    Our current research in the framework of an interdisciplinary project focuses on modelling the dynamics of the hemoglobin reoxygenation process in post-mortem human skin by reflectance spectrometry. The observations of reoxygenation of hemoglobin in livores after postmortem exposure to a cold environment relate the reoxygenation to the commonly known phenomenon that the color impression of livores changes from livid to pink under low ambient temperatures. We analyze the spectra with respect to a physical model describing the optical properties of human skin, discuss the dynamics of the reoxygenation, and propose a phenomenological model for reoxygenation. For additional characterization of the reflectance spectra, the curvature of the local minimum and maximum in the investigated spectral range is considered. There is a strong correlation between the curvature of specra at a wavelength of 560 nm and the concentration of O2-Hb. The analysis is carried out via C programs, as well as MySQL database queries in Java EE, JDBC, Matlab, and Python.

  12. The Effects of Accretion Disk Geometry on AGN Reflection Spectra

    Science.gov (United States)

    Taylor, Corbin James; Reynolds, Christopher S.

    2017-08-01

    Despite being the gravitational engines that power galactic-scale winds and mega parsec-scale jets in active galaxies, black holes are remarkably simple objects, typically being fully described by their angular momenta (spin) and masses. The modelling of AGN X-ray reflection spectra has proven fruitful in estimating the spin of AGN, as well as giving insight into their accretion histories and the properties of plasmas in the strong gravity regime. However, current models make simplifying assumptions about the geometry of the reflecting material in the accretion disk and the irradiating X-ray corona, approximating the disk as an optically thick, infinitely thin disk of material in the orbital plane. We present results from the new relativistic raytracing suite, Fenrir, that explore the effects that disk thickness may have on the reflection spectrum and the accompanying reverberation signatures. Approximating the accretion disk as an optically thick, geometrically thin, radiation pressure dominated disk (Shakura & Sunyaev 1973), one finds that the disk geometry is non-negligible in many cases, with significant changes in the broad Fe K line profile. Finally, we explore the systematic errors inherent in approximating the disk as being infinitely thin when modeling reflection spectrum, potentially biasing determinations of black hole and corona properties.

  13. X-ray Reflected Spectra from Accretion Disk Models. III. A Complete Grid of Ionized Reflection Calculations

    Science.gov (United States)

    Garcia, J.; Dauser, T.; Reynolds, C. S.; Kallman, T. R.; McClintock, J. E.; Wilms, J.; Ekmann, W.

    2013-01-01

    We present a new and complete library of synthetic spectra for modeling the component of emission that is reflected from an illuminated accretion disk. The spectra were computed using an updated version of our code xillver that incorporates new routines and a richer atomic data base. We offer in the form of a table model an extensive grid of reflection models that cover a wide range of parameters. Each individual model is characterized by the photon index Gamma of the illuminating radiation, the ionization parameter zeta at the surface of the disk (i.e., the ratio of the X-ray flux to the gas density), and the iron abundance A(sub Fe) relative to the solar value. The ranges of the parameters covered are: 1.2 total of 720 reflection spectra are provided in a single FITS file suitable for the analysis of X-ray observations via the atable model in xspec. Detailed comparisons with previous reflection models illustrate the improvements incorporated in this version of xillver.

  14. Multivariate Data Analysis on Tissue Diffuse Reflectance Spectra for Diagnostic Applications

    Science.gov (United States)

    Prince, Shanthi; Malarvizhi, S.

    2011-10-01

    Currently, clinical diagnosis of skin disease is generally accomplished by visual inspection under white light illumination. Aside from physical examination, the diagnosis of most of these lesions is invasive, time-consuming, and costly, often requiring surgical excision or biopsy followed by pathological investigations. Several approaches have been tried to improve dermatological diagnosis. Optical means of characterizing tissues have gained importance due to its noninvasive nature. Diffuse reflectance spectra are unique for normal and diseased tissues. Spectral characteristics of the tissue spectra provide useful information to identify various chromophores present in them, because different chromophores have different spectroscopic responses to electromagnetic waves of certain energy bands. An optical fiber spectrometer is set up for collection of diffuse reflectance data from different skin conditions. The method involves exposure of skin surface to white light produced by an incandescent source. These back scattered photons emerging from various layers of tissue are detected by spectrometer resulting in diffuse reflectance data. PCA can be considered as "the mother of all methods in multivariate data analysis". PCA is performed for data reduction and to obtain specific signature from the spectra to differentiate normal and the diseased skin. The proposed principal component analysis method is able to enhance the peculiar characteristics of the diseased diffuse reflectance spectra. Principal component analysis shows that the spectra from normal and diseased tissues are distinct from each other. PCA is recommended as an exploratory tool to uncover unknown trends in the data. A preliminary study, using PCA on the reparability of the spectra of normal and diseased tissue within each patient shows promise that this method is sensitive to changes in tissue brought upon by the onset of disease.

  15. Program for the surface muon spectra calculation

    International Nuclear Information System (INIS)

    Arkatov, Yu.M.; Voloshchuk, V.I.; Zolenko, V.A.; Prokhorets, I.M.; Soldatov, S.A.

    1987-01-01

    Program for the ''surface'' muon spectrum calculation is described. The algorithm is based on simulation of coordinates of π-meson birth point and direction of its escape from meson-forming target (MFT) according to angular distribution with the use of Monte Carlo method. Ionization losses of π-(μ)-mesons in the target are taken into account in the program. Calculation of ''surface'' muon spectrum is performed in the range of electron energies from 150 MeV up to 1000 MeV. Spectra of π-mesons are calculated with account of ionization losses in the target and without it. Distributions over lengths of π-meson paths in MFT and contribution of separate sections of the target to pion flux at the outlet of meson channel are calculated as well. Meson-forming target for calculation can be made of any material. The program provides for the use of the MFT itself in the form of photon converter or photon converter is located in front of the target. The program is composed of 13 subprograms; 2 of them represent generators of pseudorandom numbers, distributed uniformly in the range from 0 up to 1, and numbers with Gauss distribution. Example of calculation for copper target of 3 cm length, electron beam current-1 μA, energy-300 MeV is presented

  16. Attenuated total reflection angular spectra of a system of alternating plasma-dielectric layers.

    Science.gov (United States)

    Kovacs, G J; Scott, G D

    1978-11-15

    The attenuated total reflection (ATR) angular spectra of a five-film system have been observed. Successive layers of Ag-LiF-Ag-LiF-Ag are evaporated onto the base of a glass prism. Surface plasma wave resonances corresponding to coupled oscillations at the plasma-dielectric interfaces were found for p-polarization. Guided light modes coupled between the two dielectric layers were observed in both p- and s-polarized spectra. If guided mode reflectance resonances occur at less than the critical angle they have associated with them resonance transmissions. In general the ATR resonances of the five-film system occur as doublets, which form a splitting of the resonances of a single dielectric slab bounded by Ag layers. The resonant oscillations are demonstrated by detailed calculations of the Poynting vector field and electric field oscillations, which also help in understanding the source of discrepancies between experimental and calculated ATR spectra. These discrepancies are thought to be due largely to the surface roughness of evaporated LiF films. The roughness is modeled as thin cermet layers at the LiF-Ag interfaces, and the optical constants of the cermets are calculated by the Maxwell Garnett theory. When the ATR spectra are then computed with the pseudolayers inserted, much improved agreement with experiment can be obtained.

  17. The effects of atmospheric pressure on infrared reflectance spectra of Martian analogs

    Science.gov (United States)

    Bishop, Janice L.; Pieters, Carle M.; Pratt, Stephen F.; Patterson, William

    1993-01-01

    The use of terrestrial samples as analogs of Mars soils are complicated by the Martian atmosphere. Spectral features due to the Martian atmosphere can be removed from telescopic spectra of Mars and ISM spectra of Mars, but this does not account for any spectral differences resulting from atmospheric pressure or any interactions between the atmosphere and the surface. We are examining the effects of atmospheric pressure on reflectance spectra of powdered samples in the laboratory. Contrary to a previous experiment with granite, no significant changes in albedo or the Christiansen feature were observed from 1 bar pressure down to a pressure of 8 micrometers Hg. However, reducing the atmospheric pressure does have a pronounced affect on the hydration features, even for samples retained in a dry environment for years.

  18. Near-infrared Reflectance Spectra Of 135 Hertha, 224 Oceana, 516 Amherstia, And 872 Holda

    Science.gov (United States)

    Hardersen, Paul S.; Gaffey, M. J.; Abell, P. A.

    2006-09-01

    Near-infrared reflectance spectra of M-asteroids 135 Hertha, 224 Oceana, 516 Amherstia, and 872 Holda display spectral and mineralogical diversity that is becoming the norm for the M-asteroid taxonomic group. 224 Oceana exhibits a traditionally featureless M-asteroid spectrum, moderately reddish slope, and an IRAS albedo of 17%. Canonical interpretations include a NiFe metal-rich surface or a surface similar to that of the enstatite chondrites. 516 Amherstia, with an IRAS albedo of 16%, displays absorption features centered at 0.93- and 1.92-microns superimposed on an overall reddish slope. This suggests a surface with a single mafic silicate (i.e., pyroxene, Wo10±4Fs31±5) and NiFe metal. The Band I and II absorptions are 5% and 2% deep, respectively. Amherstia's features are similar to, but somewhat more intense and Fe-rich than, other M-asteroid spectra as discussed in Hardersen et al. (2005). 872 Holda displays a generally featureless NIR reflectance spectrum with the exception of a very broad and weak ( 2% depth) absorption that ranges from 0.5 to 1.2-microns. 872 Holda's overall spectrum is similar to that of synthetic troilite, but differs from spectra of meteoritic troilite as discussed in Cloutis and Burbine (1999). If troilite is present on Holda's surface, then a potential interpretation is a mixture of NiFe metal and troilite as seen in iron meteorites. The NIR reflectance spectrum for 135 Hertha will also be discussed and compared to this asteroid's 52-color survey spectrum, which indicates the presence of a weak 0.9-micron absorption feature. Of the 20 M-asteroid spectra that have been examined by this team thus far, 10 M-asteroids display the presence of low-Fe pyroxene absorption features at 0.9 microns, 3 suggest the presence of spinel, 2 indicate the presence of olivine, one suggests the possible presence of troilite, and 4 display featureless spectra that suggest a variety of potential interpretations.

  19. Simulations of Effects of Nanophase Iron Space Weather Products on Lunar Regolith Reflectance Spectra

    Science.gov (United States)

    Escobar-Cerezo, J.; Penttilä, A.; Kohout, T.; Muñoz, O.; Moreno, F.; Muinonen, K.

    2018-01-01

    Lunar soil spectra differ from pulverized lunar rocks spectra by reddening and darkening effects, and shallower absorption bands. These effects have been described in the past as a consequence of space weathering. In this work, we focus on the effects of nanophase iron (npFe0) inclusions on the experimental reflectance spectra of lunar regolith particles. The reflectance spectra are computed using SIRIS3, a code that combines ray optics with radiative-transfer modeling to simulate light scattering by different types of scatterers. The imaginary part of the refractive index as a function of wavelength of immature lunar soil is derived by comparison with the measured spectra of the corresponding material. Furthermore, the effect of adding nanophase iron inclusions on the reflectance spectra is studied. The computed spectra qualitatively reproduce the observed effects of space weathered lunar regolith.

  20. Rydberg and π-π* transitions in film surfaces of various kinds of nylons studied by attenuated total reflection far-ultraviolet spectroscopy and quantum chemical calculations: peak shifts in the spectra and their relation to nylon structure and hydrogen bondings.

    Science.gov (United States)

    Morisawa, Yusuke; Yasunaga, Manaka; Sato, Harumi; Fukuda, Ryoichi; Ehara, Masahiro; Ozaki, Yukihiro

    2014-10-09

    Attenuated total reflection far-ultraviolet (ATR-FUV) spectra in the 145-260 nm region were measured for surfaces (thickness 50-200 nm) of various kinds of nylons in cast films to explore their electronic transitions in the FUV region. ATR-FUV spectra show two major bands near 150 and 200 nm in the surface condensed phase of nylons. Transmittance (Tr) spectra were also observed in particular for the analysis of valence excitations. Time-dependent density functional theory (TD-DFT/CAM-B3LYP) calculations were carried out using the model systems to provide the definitive assignments of their absorption spectra and to elucidate their peak shifts in several nylons, in particular, focusing on their crystal alignment structures and intermolecular hydrogen bondings. Two major bands of nylon films near 150 and 200 nm are characterized as σ-Rydberg 3p and π-π* transitions of nylons, respectively. These assignments are also coherent with those of liquid n-alkanes (n = 5-14) and liquid amides observed previously. The Rydberg transitions are delocalized over the hydrocarbon chains, while the π-π* transitions are relatively localized at the amide group. Differences in the peak positions and intensity were found in both ATR- and Tr-FUV spectra for different nylons. A red-shift of the π-π* amide band in the FUV spectra of nylon-6 and nylon-6/6 models in α-form is attributed to the crystal structure pattern and the intermolecular hydrogen bondings, which result in the different delocalization character of the π-π* transitions and transition dipole coupling.

  1. A Bayesian Reflection on Surfaces

    Directory of Open Access Journals (Sweden)

    David R. Wolf

    1999-10-01

    Full Text Available Abstract: The topic of this paper is a novel Bayesian continuous-basis field representation and inference framework. Within this paper several problems are solved: The maximally informative inference of continuous-basis fields, that is where the basis for the field is itself a continuous object and not representable in a finite manner; the tradeoff between accuracy of representation in terms of information learned, and memory or storage capacity in bits; the approximation of probability distributions so that a maximal amount of information about the object being inferred is preserved; an information theoretic justification for multigrid methodology. The maximally informative field inference framework is described in full generality and denoted the Generalized Kalman Filter. The Generalized Kalman Filter allows the update of field knowledge from previous knowledge at any scale, and new data, to new knowledge at any other scale. An application example instance, the inference of continuous surfaces from measurements (for example, camera image data, is presented.

  2. Reflection of Slow Electrons from Solid Surface

    Science.gov (United States)

    Mustafaev, Alexander; Ainov, Matsak; Kaganovich, Igor; Demidov, Vladimir

    2013-09-01

    Given that progress of future plasma technologies depends on control of electron coefficient reflection r0, the development of methods of measurement and control of r0 is of great importance. Published experimental data on r0 for slow electrons are inconsistent and sometime give large values up to r0 ~ 0 , 8 and even higher. This talk presents a technique for r0 measurements in low pressure plasmas in the presence of transverse magnetic field. It is found that for poly-crystal surface, effective reflection coefficient can really reach value of 0.8. It is demonstrated that it is connected to additional reflection from potential barrier near the surfaces. The contribution of electron reflection from the barrier and the surface has been divided and studied. The data have been confirmed at different mono-crystal surfaces. This work was supported by DoE Fusion Energy Sciences contract DE-SC0001939 and Education Ministry of the RF.

  3. Cluster analysis of near-infrared reflectance spectra of asteroid Itokawa

    Science.gov (United States)

    Inasawa, Tomoki; Kitazato, Kohei; Hirata, Naru; Demura, Hirohide

    2017-10-01

    The data from the analysis of samples returned by Hayabusa spacecraft have provided conclusive evidence regarding mineral composition and space weathering of near-Earth S-type asteroid Itokawa. To apply these information to the Hayabusa remote sensing data towards revealing the formation history of Itokawa, we made a more precise near-infrared spectral map of Itokawa than the previous ones from the Hayabusa NIRS data and performed its cluster analysis. The NIRS instrument had acquired more than 80,000 spatially resolved 0.75 to 2.20 microns reflectance spectra from the surface of Itokawa. We used PCA and k-means clustering for cluster analysis and found that at least three different types of surface areas would exist on Itokawa.

  4. Specular Reflection from Rough Surfaces Revisited

    Science.gov (United States)

    Yasuda, Kensei; Kim, Alvin; Cho, Hayley; Timofejev, Timofej; Walecki, Wojciech J.; Klep, James; Edelson, Amy S.; Walecki, Abigail S.; Walecki, Eve S.; Walecki, Peter S.

    2016-01-01

    In his beautiful paper, Hasan Fakhruddin reported observations of mirror-like reflections in the rough surface of a ground glass plate. Similar effects have been recently employed for metrology of the roughness of optical diffusers used in modern light emitting device illumination systems. We report the observations of specular reflection in…

  5. Simulation Tool for GNSS Ocean Surface Reflections

    OpenAIRE

    Høeg, Per; von Benzon, Hans-Henrik; Durgonics, Tibor

    2015-01-01

    GNSS coherent and incoherent reflected signals have the potential of deriving large scale parameters of ocean surfaces, as barotropic variability, eddy currents and fronts, Rossby waves, coastal upwelling, mean ocean surfaceheights, and patterns of the general ocean circulation. In the reflection zone the measurements may deriveparameters as sea surface roughness, winds, waves, heights and tilts from the spectral measurements. Previous measurements from the top of mountains and airplanes have...

  6. On automatic visual inspection of reflective surfaces

    DEFF Research Database (Denmark)

    Kulmann, Lionel

    1995-01-01

    lighting methods in a framework, general usable for inspecting reflective surfaces. Special attention has been given to the design of illumination techniques to enhance defects of highly reflective aluminum sheets. The chosen optical system setup has been used to enhance surface defects of other reflective......This thesis descrbes different methods to perform automatic visual inspection of reflective manufactured products, with the aim of increasing productivity, reduce cost and improve the quality level of the production. We investigate two different systems performing automatic visual inspection....... The first is the inspection of highly reflective aluminum sheets, used by the Danish company Bang & Olufsen, as a part of the exterior design and general appearance of their audio and video products. The second is the inspection of IBM hard disk read/write heads for defects during manufacturing. We have...

  7. Infrared spectral reflectances of asteroid surfaces

    Science.gov (United States)

    Larson, H. P.; Veeder, G. J.

    1979-01-01

    This review compares the types of compositional information produced by three complementary techniques used in infrared observations of asteroid surfaces: broadband JHKL photometry, narrow band photometry, and multiplex spectroscopy. The high information content of these infrared observations permits definitive interpretations of asteroid surface compositions in terms of the major meteoritic minerals (olivine, pyroxene, plagioclase feldspar, hydrous silicates, and metallic Ni-Fe). These studies emphasize the individuality of asteroid surface compositions, the inadequacy of simple comparisons with spectra of meteorites, and the need to coordinate spectral measurements of all types to optimize diagnostic capabilities.

  8. CCD reflectance spectra of selected asteroids. I - Presentation and data analysis considerations

    Science.gov (United States)

    Vilas, Faith; Mcfadden, Lucy A.

    1992-01-01

    Narrowband reflectance spectra have been acquired which contribute to the library of asteroid data in the visible and near-IR spectral regions. The spectra support the existence of aqueous alteration products on asteroids located in the outer part of the main asteroid belt out to at least 4 AU. No evidence for features similar to the spectral features of ordinary chondrite meteorites was found in the spectra of asteroids located near the 3:1 Kirkwood Gap chaotic zone.

  9. Visible and Near-Infrared Leaf Reflectance Spectra, 1992-1993 (ACCP)

    Data.gov (United States)

    National Aeronautics and Space Administration — Visible/NIR reflectance spectra data for both fresh and dry leaf samples were collected to determine the relationship of foliar chemical concentrations with...

  10. LBA-ECO LC-07 Reflectance Spectra and Water Quality of Amazon Basin Floodplain Lakes

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set includes bidirectional reflectance (BDR) spectra and water-quality data of floodplain lakes of the Solimoes and Negro Rivers in the central Amazon...

  11. LBA-ECO LC-07 Reflectance Spectra and Water Quality of Amazon Basin Floodplain Lakes

    Data.gov (United States)

    National Aeronautics and Space Administration — ABSTRACT: This data set includes bidirectional reflectance (BDR) spectra and water-quality data of floodplain lakes of the Solimoes and Negro Rivers in the central...

  12. Anisotropic reflectance characteristics of natural Earth surfaces.

    Science.gov (United States)

    Brennan, B; Bandeen, W R

    1970-02-01

    The patterns of reflection of solar radiation from cloud, water, and land surfaces were measured with an aircraft-borne medium resolution radiometer. Reflectances in the 0.2-4.0-micro and 0.55-0.85-micro portions of the electromagnetic spectrum were investigated. Results indicate that the reflectance characteristics of most of the surface types measured are anisotropic. The anisotropy is dependent on the type of surface and the angles of incidence and reflection. In general, the anisotropy increases with increasing solar zenith angle. Clouds and forests show similar reflectance patterns, with forward and backward scattering peaks. Ocean surfaces yield a pattern similar to those of the clouds and forests but with an additional peak which is associated with sun glitter. Reflectances measured in the 0.2-4.0-micro band are generally lower than those in the 0.55-0.85-micro band under cloudy conditions. Anisotropy and spectral bandwidth should be accounted for when computing the albedo of the earth from narrow field-of-view measurements from satellites; otherwise, large errors may be expected to occur.

  13. Diffuse reflectance infrared Fourier-Transform spectra of selected organic compounds

    Energy Technology Data Exchange (ETDEWEB)

    Harmon, S.H.; Caton, J.E.

    1982-05-01

    Diffuse reflectance infrared spectra of a variety of different organic compounds have been determined. Profiles of the spectra along with the location and relative intensity of the principal bands have been included for each compound studied. In addition both diffuse reflectance and transmittance infrared spectra were obtained for the same samples, and the spectral results were compared. Although some minor variations are observed between a diffuse reflectance spectrum and the corresponding transmittance spectrum, the diffuse reflectance is quite useful and may be a superior technique for the study of many samples because it possesses an inherently higher signal-to-noise response, requires less sample preparation and allows a very wide range of samples (solids, liquids of low volatility, neat sample, or sample diluted in a reflecting medium) to be studied under very similar conditions.

  14. Lunar surface reflectance by LALT aboard KAGUYA

    Science.gov (United States)

    Noda, H.; Araki, H.; Ishihara, Y.; Tazawa, S.; Sasaki, S.; Kawano, N.

    2009-12-01

    The Laser Altimeter (LALT) aboard Japanese lunar explorer KAGUYA (SELENE) is a ranging instrument which measures the distance between the satellite and the lunar surface with accuracy of 1 m by detecting the timing delay of the reflected laser light. The main science goal of the LALT is to obtain the lunar global topographic data including polar regions for the study of the origin and the evolution of the Moon [1]. Besides, the LALT is equipped with an intensity monitor of the returned pulses. The intensity of the returned pulses contains information concerning surface roughness and reflectance of the footprints, which will contribute to the study of the lunar surface maturity and age. The reflectance at LALT wavelength (1064nm) is sensitive to the surface maturity and composition. The data should be particularly important at lunar polar regions where camera instruments should suffer from phase angle effects in the surface reflectance and moreover cannot obtain reflectance data at the permanently shadowed area. The normal operation of the LALT began on 30th, December 2007 after two months’ commissioning phase. Before the end of the normal operation phase in October 2008, the LALT measured more than 10 million range data. Unfortunately, due to the laser power decrease and also possible smaller surface reflectance than the expected value before launch (15 % at 1 micro meter), the return pulse intensity during the nominal mission phase is so small that they are not reliable enough to discuss the surface property. During the extended mission phase, which started November 2008, the satellite altitude decreased to 50 km. Due to the malfunction of the reaction wheel and high-voltage instruments were shutdown, the observation was suspended until 11th of February, 2009. LALT successfully resumed observation on 12th February and continued observation until the controlled crash of KAGUYA onto the Moon on 10th of June, 2009. Thanks to the lower orbit during this phase, the

  15. Surface spectra of Weyl semimetals through self-adjoint extensions

    Science.gov (United States)

    Seradjeh, Babak; Vennettilli, Michael

    2018-02-01

    We apply the method of self-adjoint extensions of Hermitian operators to the low-energy, continuum Hamiltonians of Weyl semimetals in bounded geometries and derive the spectrum of the surface states on the boundary. This allows for the full characterization of boundary conditions and the surface spectra on surfaces both normal to the Weyl node separation as well as parallel to it. We show that the boundary conditions for quadratic bulk dispersions are, in general, specified by a U (2 ) matrix relating the wave function and its derivatives normal to the surface. We give a general procedure to obtain the surface spectra from these boundary conditions and derive them in specific cases of bulk dispersion. We consider the role of global symmetries in the boundary conditions and their effect on the surface spectrum. We point out several interesting features of the surface spectra for different choices of boundary conditions, such as a Mexican-hat shaped dispersion on the surface normal to Weyl node separation. We find that the existence of bound states, Fermi arcs, and the shape of their dispersion, depend on the choice of boundary conditions. This illustrates the importance of the physics at and near the boundaries in the general statement of bulk-boundary correspondence.

  16. Baseline Correction of Diffuse Reflection Near-Infrared Spectra Using Searching Region Standard Normal Variate (SRSNV).

    Science.gov (United States)

    Genkawa, Takuma; Shinzawa, Hideyuki; Kato, Hideaki; Ishikawa, Daitaro; Murayama, Kodai; Komiyama, Makoto; Ozaki, Yukihiro

    2015-12-01

    An alternative baseline correction method for diffuse reflection near-infrared (NIR) spectra, searching region standard normal variate (SRSNV), was proposed. Standard normal variate (SNV) is an effective pretreatment method for baseline correction of diffuse reflection NIR spectra of powder and granular samples; however, its baseline correction performance depends on the NIR region used for SNV calculation. To search for an optimal NIR region for baseline correction using SNV, SRSNV employs moving window partial least squares regression (MWPLSR), and an optimal NIR region is identified based on the root mean square error (RMSE) of cross-validation of the partial least squares regression (PLSR) models with the first latent variable (LV). The performance of SRSNV was evaluated using diffuse reflection NIR spectra of mixture samples consisting of wheat flour and granular glucose (0-100% glucose at 5% intervals). From the obtained NIR spectra of the mixture in the 10 000-4000 cm(-1) region at 4 cm intervals (1501 spectral channels), a series of spectral windows consisting of 80 spectral channels was constructed, and then SNV spectra were calculated for each spectral window. Using these SNV spectra, a series of PLSR models with the first LV for glucose concentration was built. A plot of RMSE versus the spectral window position obtained using the PLSR models revealed that the 8680–8364 cm(-1) region was optimal for baseline correction using SNV. In the SNV spectra calculated using the 8680–8364 cm(-1) region (SRSNV spectra), a remarkable relative intensity change between a band due to wheat flour at 8500 cm(-1) and that due to glucose at 8364 cm(-1) was observed owing to successful baseline correction using SNV. A PLSR model with the first LV based on the SRSNV spectra yielded a determination coefficient (R2) of 0.999 and an RMSE of 0.70%, while a PLSR model with three LVs based on SNV spectra calculated in the full spectral region gave an R2 of 0.995 and an RMSE of

  17. Reflectance spectroscopy and asteroid surface mineralogy

    International Nuclear Information System (INIS)

    Gaffey, M.J.; Bell, J.F.; Cruikshank, D.P.

    1989-01-01

    Information available from reflectance spectroscopy on the surface mineralogy of asteroids is discussed. Current spectral interpretive procedures used in the investigations of asteroid mineralogy are described. Present understanding of the nature and history of asteroids is discussed together with some still unresolved issues such as the source of ordinary chondrites. 100 refs

  18. Use of reflective surfaces on roadway embankment

    DEFF Research Database (Denmark)

    Jørgensen, Anders Stuhr; Doré, Guy

    2007-01-01

    Temperature measurements have been used to study the effect of two reflective surfaces on a roadway embankment in Forêt Montmorency, Québec, Canada. Both tested materials, Mapelastic (from MAPEI) and Colored Slurry (from Tech-Mix), have lead to a reduction in n-factor and proved to have very good...

  19. On the impact of particle size on the characteristics of specular and diffuse reflectance spectra

    Science.gov (United States)

    Mall, U.; Schmidt, B.; Dabrowski, B.; Hoenicke, L.; Kloskowski, D.

    2017-09-01

    The remote identification of minerals or rocks by reflectance measurements uses the fact that reflectance spectra in the UV-VIS-NIR and thermal infrared (TIR) wavelength regions contain a number of diagnostic features. Among these features particle size play an important role. We report on the characteristics of NIR measurements of pure minerals of well-defined grain sizes relevant for remote sensing studies of soils in specular and diffuse reflectance.

  20. Conversion from surface wave to surface wave on reflection

    DEFF Research Database (Denmark)

    Novitsky, Andrey

    2010-01-01

    can be transmitted without changing its direction (nevertheless the amplitude varies). For other media parameters, only normally incident surface waves can be converted to surface waves. We propose applications of the predicted conversion as a beam splitter and polarization filter for surface waves.......We discuss the reflection and transmission of an incident surface wave to a pure surface wave state at another interface. This is allowed only for special media parameters: at least one of the media must be magnetic. We found such material characteristics that the obliquely incident surface wave...

  1. Reflectance Spectra of Peacock Feathers and the Turning Angles of Melanin Rods in Barbules.

    Science.gov (United States)

    Okazaki, Toshio

    2018-02-01

    I analyzed the association between the reflectance spectra and melanin rod arrangement in barbules of the eyespot of peacock feathers. The reflectance spectra from the yellow-green feather of the eyespot indicated double peaks of 430 and 540 nm. The maximum reflectance spectrum of the blue feather was 480 nm, and that of the dark blue feather was 420 nm. The reflectance spectra from brown feathers indicated double peaks of 490 and 610 nm. Transmission electron microscopic analysis confirmed that melanin rods were arranged fanwise in the outer layer toward the barbule tips. In addition, using polarized light microscope, I attempted to determine whether the turning angles of melanin rods in the barbules reflected different colors. The turning angle of the polarizing axis of the barbules was supported by that of the melanin rods, observed using transmission electron microscopic images. To compare the turning angle of melanin rods in the respective barbules, I calculated the opening width of the fanwise melanin rods by dividing the width of the barbules by the turning angle of the polarizing axis of barbules and obtained a positive correlation between the reflectance spectra and opening width of the fanwise melanin rods. Moreover, the widely spreading reflection from the barbules may occur because of the fanwise melanin rod arrangement.

  2. DFT calculations of vibrational spectra of oxidized (111) diamond surface

    Czech Academy of Sciences Publication Activity Database

    Jirásek, Vít; Kozak, Halyna; Remeš, Zdeněk

    2015-01-01

    Roč. 7, č. 4 (2015), s. 275-278 ISSN 2164-6627 R&D Projects: GA ČR GPP205/12/P331; GA MŠk LH12186 Institutional support: RVO:68378271 Keywords : density functional theory * vibrational spectra * FTIR * diamond nanoparticles * functionalized diamond surface Subject RIV: JJ - Other Materials

  3. Surface enhanced Raman spectra of the organic nonlinear optic ...

    Indian Academy of Sciences (India)

    Wintec

    Institute of Chemistry, University of Opole, Olesksa 48 45-052 Opole, Poland. 1. Present Address: Department of ... The surface geometry of methyl 3-(4-methoxy phenyl)prop-2-enoate molecule was studied by analysis of the SERS spectra .... Harmonic vibrational wave numbers were calculated using analytic second de-.

  4. Titan's surface spectra at the Huygens landing site and Shangri-La

    Science.gov (United States)

    Rannou, P.; Toledo, D.; Lavvas, P.; D'Aversa, E.; Moriconi, M. L.; Adriani, A.; Le Mouélic, S.; Sotin, C.; Brown, R.

    2016-05-01

    Titan is an icy satellite of Saturn with a dense atmosphere and covered by a global photochemical organic haze. Ground based observations and the Huygens descent probe allowed to retrieve the main spectral signature of the water ice (Griffith, C.A. et al. [2003]. Science 300(5619), 628-630; Coustenis, A. et al. [2005]. Icarus 177, 89-105) at the surface, possibly covered by a layer of sedimented organic material (Tomasko, M.G. et al. [2005]. Nature 438(7069), 765-778). However, the spectrum of the surface is not yet understood. In this study, we find that the surface reflectivity at the Huygens Landing Site (HLS) is well modeled by a layer of water ice grains overlaid by a moist layer of weakly compacted photochemical aggregated aerosols. Moist soils have spectra shifted toward short wavelengths relatively to spectra of dry soils. Cassini observations of Shangri-La region from orbit also show a very dark surface with a reflectivity peak shifted toward short wavelengths in respect to the reflectivity peak of bright surfaces, revealing a dichotomy between terrains based to their spectra in visible.

  5. Effects of Space Weathering on Reflectance Spectra of Ureilites: First Studies

    Science.gov (United States)

    Goodrich, C. A.; Gillis-Davis, J.; Cloutis, E.; Applin, D.; Takir, D.; Hibbitts, C.; Christoffersen, R.; Fries, M.; Klima, R.; Decker, S.

    2018-01-01

    Ureilites are differentiated meteorites (ultramafic rocks interpreted to be mantle residues) that contain as much carbon as the most carbon-rich carbonaceous chondrites (CCs). Reflectance spectra of ureilites are similar to those of some CCs. Hence, ureilitic asteroids may accidentally be categorized as primitive because their spectra could resemble those of C-complex asteroids, which are thought to be CC-like. We began spectral studies of progressively laser-weathered ureilites with the goals of predicting UV-VIS-IR spectra of ureilitic asteroids, and identifying features that could distinguish differentiated from primitive dark asteroids. Space weathering has not previously been studied for ureilites, and, based on space weathering studies of CCs and other C-rich materials, it could significantly alter their reflectance spectra.

  6. Interactions of light with rough dielectric surfaces - Spectral reflectance and polarimetric properties

    Science.gov (United States)

    Yon, S. A.; Pieters, C. M.

    1988-01-01

    The nature of the interactions of visible and NIR radiation with the surfaces of rock and mineral samples was investigated by measuring the reflectance and the polarization properties of scattered and reflected light for slab samples of obsidian and fine-grained basalt, prepared to controlled surface roughness. It is shown that the degree to which radiation can penetrate a surface and then scatter back out, an essential criterion for mineralogic determinations based on reflectance spectra, depends not only upon the composition of the material, but also on its physical condition such as sample grain size and surface roughness. Comparison of the experimentally measured reflectance and polarization from smooth and rough slab materials with the predicted models indicates that single Fresnel reflections are responsible for the largest part of the reflected intensity resulting from interactions with the surfaces of dielectric materials; multiple Fresnel reflections are much less important for such surfaces.

  7. Similarity analysis of spectra obtained via reflectance spectrometry in legal medicine.

    Science.gov (United States)

    Belenki, Liudmila; Sterzik, Vera; Bohnert, Michael

    2014-02-01

    In the present study, a series of reflectance spectra of postmortem lividity, pallor, and putrefaction-affected skin for 195 investigated cases in the course of cooling down the corpse has been collected. The reflectance spectrometric measurements were stored together with their respective metadata in a MySQL database. The latter has been managed via a scientific information repository. We propose similarity measures and a criterion of similarity that capture similar spectra recorded at corpse skin. We systematically clustered reflectance spectra from the database as well as their metadata, such as case number, age, sex, skin temperature, duration of cooling, and postmortem time, with respect to the given criterion of similarity. Altogether, more than 500 reflectance spectra have been pairwisely compared. The measures that have been used to compare a pair of reflectance curve samples include the Euclidean distance between curves and the Euclidean distance between derivatives of the functions represented by the reflectance curves at the same wavelengths in the spectral range of visible light between 380 and 750 nm. For each case, using the recorded reflectance curves and the similarity criterion, the postmortem time interval during which a characteristic change in the shape of reflectance spectrum takes place is estimated. The latter is carried out via a software package composed of Java, Python, and MatLab scripts that query the MySQL database. We show that in legal medicine, matching and clustering of reflectance curves obtained by means of reflectance spectrometry with respect to a given criterion of similarity can be used to estimate the postmortem interval.

  8. Simulation Tool for GNSS Ocean Surface Reflections

    DEFF Research Database (Denmark)

    Høeg, Per; von Benzon, Hans-Henrik; Durgonics, Tibor

    2015-01-01

    . This impedance concept gives an accurate lower boundary condition in the determination of the electromagnetic field, and makes itpossible to simulate reflections and the effects of transitions between different mediums. A semi-isotropic Philipsspectrum is used to represent the air-sea interaction.Simulated GPS...... on the solution of the parabolic equation. The parabolic equation in our simulator is solvedusing the split-step sine transformation. The Earth’s surface is modeled with the use of an impedance model. The value of the Earth impedance is given as a function of the range along the surface of the Earth...

  9. ASTER L2 Surface Reflectance SWIR and ASTER L2 Surface Reflectance VNIR V003

    Data.gov (United States)

    National Aeronautics and Space Administration — The ASTER L2 Surface Reflectance is a multi-file product that contains atmospherically corrected data for both the Visible Near-Infrared (VNIR) and Shortwave...

  10. Reduction of Glass Surface Reflectance by Ion Beam Surface Modification

    Energy Technology Data Exchange (ETDEWEB)

    Mark Spitzer

    2011-03-11

    This is the final report for DOE contract DE-EE0000590. The purpose of this work was to determine the feasibility of the reduction of the reflection from the front of solar photovoltaic modules. Reflection accounts for a power loss of approximately 4%. A solar module having an area of one square meter with an energy conversion efficiency of 18% generates approximately 180 watts. If reflection loss can be eliminated, the power output can be increased to 187 watts. Since conventional thin-film anti-reflection coatings do not have sufficient environmental stability, we investigated the feasibility of ion beam modification of the glass surface to obtain reduction of reflectance. Our findings are generally applicable to all solar modules that use glass encapsulation, as well as commercial float glass used in windows and other applications. Ion implantation of argon, fluorine, and xenon into commercial low-iron soda lime float glass, standard float glass, and borosilicate glass was studied by implantation, annealing, and measurement of reflectance. The three ions all affected reflectance. The most significant change was obtained by argon implantation into both low-iron and standard soda-lime glass. In this way samples were formed with reflectance lower than can be obtained with a single-layer coatings of magnesium fluoride. Integrated reflectance was reduced from 4% to 1% in low-iron soda lime glass typical of the glass used in solar modules. The reduction of reflectance of borosilicate glass was not as large; however borosilicate glass is not typically used in flat plate solar modules. Unlike conventional semiconductor ion implantation doping, glass reflectance reduction was found to be tolerant to large variations in implant dose, meaning that the process does not require high dopant uniformity. Additionally, glass implantation does not require mass analysis. Simple, high current ion implantation equipment can be developed for this process; however, before the process

  11. [Monitoring of Crack Propagation in Repaired Structures Based on Characteristics of FBG Sensors Reflecting Spectra].

    Science.gov (United States)

    Yuan, Shen-fang; Jin, Xin; Qiu, Lei; Huang, Hong-mei

    2015-03-01

    In order to improve the security of aircraft repaired structures, a method of crack propagation monitoring in repaired structures is put forward basing on characteristics of Fiber Bragg Grating (FBG) reflecting spectra in this article. With the cyclic loading effecting on repaired structure, cracks propagate, while non-uniform strain field appears nearby the tip of crack which leads to the FBG sensors' reflecting spectra deformations. The crack propagating can be monitored by extracting the characteristics of FBG sensors' reflecting spectral deformations. A finite element model (FEM) of the specimen is established. Meanwhile, the distributions of strains which are under the action of cracks of different angles and lengths are obtained. The characteristics, such as main peak wavelength shift, area of reflecting spectra, second and third peak value and so on, are extracted from the FBGs' reflecting spectral which are calculated by transfer matrix algorithm. An artificial neural network is built to act as the model between the characteristics of the reflecting spectral and the propagation of crack. As a result, the crack propagation of repaired structures is monitored accurately and the error of crack length is less than 0.5 mm, the error of crack angle is less than 5 degree. The accurately monitoring problem of crack propagation of repaired structures is solved by taking use of this method. It has important significance in aircrafts safety improvement and maintenance cost reducing.

  12. The reflective surface of the MAGIC telescope

    Science.gov (United States)

    Doro, M.; Bastieri, D.; Biland, A.; Dazzi, F.; Font, L.; Garczarczyk, M.; Ghigo, M.; Giro, E.; Goebel, F.; Kosyra, R.; Lorenz, E.; Mariotti, M.; Mirzoyan, R.; Peruzzo, L.; Pareschi, G.; Zapatero, J.

    2008-09-01

    The atmospheric Cherenkov telescope MAGIC for ground-based gamma-ray astronomy is operating since late 2003 on the Canary island of La Palma. Its 17 m diameter mirror is composed of 964 square all-aluminum mirrors of ˜0.5m side, making up a parabola of 236 m2 area. Each mirror is composed of a sandwich of two thin aluminum layers interspaced by a honeycomb structure that ensures rigidity, high temperature conductivity and low weight. The surface of each raw blank is diamond milled to provide high reflectivity and a slightly different focal length to fit the overall parabolic shape of the reflector. We report about the stability and performance of the surface exposed to the atmosphere for over 3 years. For the construction of the clone of the first telescope, dubbed MAGIC II, major improvements of the design and performance of the reflective surface were required. Given the good experience with aluminum mirrors, a similar assembly was tested, but the area was increased to 1 m2, which allowed to skip the inter-alignment of four mirrors within a panel and to reduce substantially the weight. The increased rigidity of the mirror unit resulted in an improved focussing quality. In addition, a second class of mirrors will be installed in the outermost part of the reflector, namely glass mirrors obtained by cold-slumping replica technique. Details on the construction of both type MAGIC II new mirrors and the 17 m reflector will be presented.

  13. Micro reflectance difference techniques: Optical probes for surface exploration

    Energy Technology Data Exchange (ETDEWEB)

    Lastras-Martinez, L.F.; Del Pozo-Zamudio, O.; Herrera-Jasso, R.; Ulloa-Castillo, N.A.; Balderas-Navarro, R.E.; Ortega-Gallegos, J.; Lastras-Martinez, A. [Instituto de Investigacion en Comunicacion Optica, Universidad Autonoma de San Luis Potosi, Alvaro Obregon 64, 78000 San Luis Potosi, S.L.P. (Mexico)

    2012-06-15

    Micro reflectance difference spectroscopy ({mu}-RDS) is a promising tool for the in-situ and ex-situ characterization of semiconductors surfaces and interfaces. We discuss and compare two different approaches used to measure {mu}-RD spectra. One is based on a charge-coupled device (CCD) camera, while the other uses a laser and a XY translation stage. To show the performance of these systems, we have measured surface optical anisotropies of GaSb(001) sample on which anisotropic strains have been generated by preferential mechanical polishing along [110] and [1 anti 10] directions. The spectrometers are complementary and the selection of one of them depends on the sample to be investigated and on experimental conditions. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  14. Reconstruction of fiber grating refractive-index profiles from complex bragg reflection spectra.

    Science.gov (United States)

    Huang, D W; Yang, C C

    1999-07-20

    Reconstruction of the refractive-index profiles of fiber gratings from their complex Bragg reflection spectra is experimentally demonstrated. The amplitude and phase of the complex reflection spectrum were measured with a balanced Michelson interferometer. By integrating the coupled-mode equations, we built the relationship between the complex coupling coefficient and the complex reflection spectrum as an iterative algorithm for reconstructing the index profile. This method is expected to be useful for reconstructing the index profiles of fiber gratings with any apodization, chirp, or dc structures. An apodized chirped grating and a uniform grating with a depression of index modulation were used to demonstrate the technique.

  15. A system for the obtention and analysis of diffuse reflection spectra from biological tissue

    International Nuclear Information System (INIS)

    La Cadena, A. de; La Rosa, J. de; Stolik, S.

    2012-01-01

    The diffuse reflection spectroscopy is a technique with is possible to study biological tissue. In the field of the biomedical applications is useful for diagnostic purposes, since is possible to analyze biological tissue in a non invasive way. also, can be used with therapeutical purposes, for example in photodynamic therapy or laser surgery because with this technique it can be determined the biological effects produced by these treatments. In this paper is shown the development of a system to obtain and analyze diffuse reflection spectra of biological tissues, using a LED as a light source, that emits light between 400-700nm. The system has an interface for the regulation of the emittance of the LED. For diffuse reflectance spectra analysis, we use an HR4000CG-UV-NIR spectrometer. (Author)

  16. Estimation of Phytoplankton Accessory Pigments From Hyperspectral Reflectance Spectra: Toward a Global Algorithm

    Science.gov (United States)

    Chase, A. P.; Boss, E.; Cetinić, I.; Slade, W.

    2017-12-01

    Phytoplankton community composition in the ocean is complex and highly variable over a wide range of space and time scales. Able to cover these scales, remote-sensing reflectance spectra can be measured both by satellite and by in situ radiometers. The spectral shape of reflectance in the open ocean is influenced by the particles in the water, mainly phytoplankton and covarying nonalgal particles. We investigate the utility of in situ hyperspectral remote-sensing reflectance measurements to detect phytoplankton pigments by using an inversion algorithm that defines phytoplankton pigment absorption as a sum of Gaussian functions. The inverted amplitudes of the Gaussian functions representing pigment absorption are compared to coincident High Performance Liquid Chromatography measurements of pigment concentration. We determined strong predictive capability for chlorophylls a, b, c1+c2, and the photoprotective carotenoids. We also tested the estimation of pigment concentrations from reflectance-derived chlorophyll a using global relationships of covariation between chlorophyll a and the accessory pigments. We found similar errors in pigment estimation based on the relationships of covariation versus the inversion algorithm. An investigation of spectral residuals in reflectance data after removal of chlorophyll-based average absorption spectra showed no strong relationship between spectral residuals and pigments. Ultimately, we are able to estimate concentrations of three chlorophylls and the photoprotective carotenoid pigments, noting that further work is necessary to address the challenge of extracting information from hyperspectral reflectance beyond the information that can be determined from chlorophyll a and its covariation with other pigments.

  17. Formation of Reflecting Surfaces Based on Spline Methods

    Science.gov (United States)

    Zamyatin, A. V.; Zamyatina, E. A.

    2017-11-01

    The article deals with problem of reflecting barriers surfaces generation by spline methods. The cases of reflection when a geometric model is applied are considered. The surfaces of reflecting barriers are formed in such a way that they contain given points and the rays reflected at these points and hit at the defined points of specified surface. The reflecting barrier surface is formed by cubic splines. It enables a comparatively simple implementation of proposed algorithms in the form of software applications. The algorithms developed in the article can be applied in architecture and construction design for reflecting surface generation in optics and acoustics providing the geometrical model of reflex processes is used correctly.

  18. Manifestation of Crystal Lattice Distortions in the IR Reflection Spectra of Abrasion-Treated ZnSe Ceramics

    Science.gov (United States)

    Sitnikova, V. E.; Dunaev, A. A.; Mamalimov, R. I.; Pakhomov, P. M.; Khizhnyak, S. D.; Chmel, A. E.

    2017-07-01

    The Fourier IR reflection spectra of ZnSe ceramics prepared by hot pressing (HP), physical vapor deposition (PVD), and PVD combined with hot isostatic pressing (HIP) are presented. The optical constants of polished and dry-ground specimens were used for comparison. The grinding treatment simulated the erosion of the outer surface of optical elements made of zinc selenide under the influence of solid dust particles and deposits. In the polished specimens residual stresses showed up in the IR reflection spectra of the ZnSePVD and ZnSeHIP ceramics, which had well-defined orientation of grains, but were not present in the spectra of the ZnSeHIP ceramics as a result of mutual compensation of the stresses in the randomly oriented grains of the material. The stresses, which appeared as a shift of the absorption bands calculated by the Kramers-Kronig method, increased significantly after abrasive treatment of the specimens. For all the treated ceramics the intensity of the absorption bands resulting from the anharmonicity of the vibrations in the distorted crystal lattice increased by several times. The last effect also depends on the production prehistory of the ceramics.

  19. Effect of reflection and refraction on NEXAFS spectra measured in TEY mode.

    Science.gov (United States)

    Filatova, Elena; Sokolov, Andrey

    2018-01-01

    The evolution of near-edge X-ray absorption fine structure in the vicinity of the K-absorption edge of oxygen for HfO 2 over a wide range of incidence angles is analyzed by simultaneous implementation of the total-electron-yield (TEY) method and X-ray reflection spectroscopy. It is established that the effect of refraction on the TEY spectrum is greater than that of reflection and extends into the angular region up to angles 2θ c . Within angles that are less than the critical angle, both the reflection and refraction strongly distort the shape of the TEY spectrum. Limitations of the technique for the calculation of optical constants from the reflection spectra using the Kramers-Kronig relation in the limited energy region in the vicinity of thresholds are discussed in detail.

  20. [The evaluation of hydrocarbon potential generation for source rocks by near-infrared diffuse reflection spectra].

    Science.gov (United States)

    Zhang, Yu-Jia; Xu, Xiao-Xuan; Song, Ning; Wu, Zhong-Chen; Zhou, Xiang; Chen, Jin; Cao, Xue-Wei; Wang, Bin

    2011-04-01

    Near-infrared (NIR) and mid-infrared (MIR) diffuse reflection spectra were compared and evaluated for hydrocarbon potential generation of source rocks. Near-infrared diffuse reflectance often exhibits significant differences in the spectra due to the non-homogeneous distribution of the particles, so the signal-to-noise ratio of NIR is much lower than MIR It is too difficult to get accurate results by NIR without using a strong spectral preprocessing method to remove systematic noise such as base-line variation and multiplicative scatter effects. In the present paper, orthogonal signal correction (OSC) and an improved algorithm of it, i.e. direct orthogonal signal correction (DOSC), are used as different methods to preprocess both the NIR and MIR spectra of the hydrocarbon source rocks. Another algorithm, wavelet multi-scale direct orthogonal signal correction (WMDOSC), which is a combination of discrete wavelet transform (DWT) and DOSC, is also used as a preprocessing method. Then, the calibration model of hydrocarbon source rocks before and after pretreatment was established by interval partial least square (iPLS). The experimental results show that WMDOSC is more successfully applied to preprocess the NIR spectra data of the hydrocarbon source rocks than other two algorithms, and NIR performed as good as MIR in the analysis of hydrocarbon potential generation of source rocks with WMDOSC-iPLS pretreatment calibration model.

  1. [Maize Hybrid Seed Purity Identification Based on Near Infrared Reflectance (NIR) and Transmittance (NIT) Spectra].

    Science.gov (United States)

    Li, Tian-xin; Jia, Shi-qiang; Liu, Xu; Zhao, Sheng-yi; Ran, Hang; Yan, Yan-lu; An, Dong

    2015-12-01

    This article explore the feasibility of using Near Infrared Reflectance (NIR) and Transmittance (NIT) Spectroscopy (908.1-1677.2 nm wavelength range) to identify maize hybrid purity, and compare the performance of NIR and NIT spectroscopy. Principle Component Analysis (PCA) and Orthogonal Linear Discriminant Analysis (OLDA) were used to reduce the dimension of spectra which have been pretreated by first derivative and vector normalization. The hybrid purity identification model of Nonghua101 and Jingyu16 were built by SVM. Models based on NIR spectra obtained correct identification rate as 100% and 90% for Nonghua101 and Jingyu16 respectively. But NIR spectra were greatly influenced by the placement of seeds, and there existed significant difference between NIR spectra of embryo and non-embryo side. Models based on NIT spectroscopy yielded correct identification rate as 98% both for Nonghua101 and Jingyu16. NIT spectra of embryo and non-embryo side were highly similar. The results indicate that it is feasible to identify maize hybrid purity based on NIR and NIT spectroscopy, and NIT spectroscopy is more suitable to analyze single seed kernel than NIR spectroscopy.

  2. New vegetation indices for remote measurement of chlorophylls based on leaf directional reflectance spectra.

    Science.gov (United States)

    Maccioni, A; Agati, G; Mazzinghi, P

    2001-08-15

    Directional reflectance (R) spectra from 380 to 780 nm for nadir illuminated leaves of four different plants (croton, Codiaeum variegatum; spotted eleagnus, Eleagnus pungens Maculata; Japanese pittosporum, Pittosporum tobira and Benjamin fig, Ficus benjamina Starlight) were acquired at a viewing angle of 30 degrees from the nadir direction. Chlorophyll-a and -b content of leaves covered a range of 1-60 and 0.5-21 microg/cm(2), respectively. In contrast with previous results from hemispherical reflectance measurements, directional reflectance data does not correlate well with chlorophyll concentration. This is mainly due to the external reflectance (R(E)) at the leaf epidermis, caused by the mismatch of the refractive index at the air-epidermis and epidermis-inner layer boundary. The external reflectance can be identified with the blue flat reflectance between 380 and 480 nm. The inner reflectance (R(I)), obtained by subtracting the external reflectance from the measured spectra, was found to be linearly related to the logarithm of the chlorophyll content. Good fitting of the log (Chl) versus R(I)(lambda) curves were obtained for R(I) in the green band (around 550 nm) and close to the inflection point in the red edge (around 700 nm). The coefficient of determination, r(2), of curve fitting improved (up to 0.97) when the normalised inner reflectance NR(I)(lambda)=R(I)(lambda)/R(I)(lambda(0)), with lambda(0)>or=750 nm, was used instead of the absolute reflectance. The best indices for Chl, Chl-a and Chl-b determination were R(I)(542)/R(I)(750), R(I)(706)/R(I)(750) and R(I)(556)/R(I)(750), respectively. However, since the content of Chl-a relative to Chl-b was almost constant for the plants investigated, the two last indices must be further validated on leaves with a high variability in the Chl-a:Chl-b ratio. The error in the determination of chlorophyll content was found to be of the order of 10%. This value was lower than those obtained by applying the vegetation

  3. Correcting attenuated total reflection-fourier transform infrared spectra for water vapor and carbon dioxide

    DEFF Research Database (Denmark)

    Bruun, Susanne Wrang; Kohler, Achim; Adt, Isabelle

    2006-01-01

    Fourier transform infrared (FT-IR) spectroscopy is a valuable technique for characterization of biological samples, providing a detailed fingerprint of the major chemical constituents. However, water vapor and CO(2) in the beam path often cause interferences in the spectra, which can hamper...... the data analysis and interpretation of results. In this paper we present a new method for removal of the spectral contributions due to atmospheric water and CO(2) from attenuated total reflection (ATR)-FT-IR spectra. In the IR spectrum, four separate wavenumber regions were defined, each containing...... of the growing yeast biofilm, the gas correction revealed otherwise hidden variations of relevance for modeling the growth dynamics. As the presented method improved the interpretation of the principle component analysis (PCA) models, it has proven to be a valuable tool for filtering atmospheric variation in ATR...

  4. Chlorophyll Fluorescence Emissions of Vegetation Canopies From High Resolution Field Reflectance Spectra

    Science.gov (United States)

    Middleton, E. M.; Corp, L. A.; Daughtry, C. S. T.; Campbell, P. K. Entcheva

    2006-01-01

    A two-year experiment was performed on corn (Zea mays L.) crops under nitrogen (N) fertilization regimes to examine the use of hyperspectral canopy reflectance information for estimating chlorophyll fluorescence (ChlF) and vegetation production. Fluorescence of foliage in the laboratory has proven more rigorous than reflectance for correlation to plant physiology. Especially useful are emissions produced from two stable red and far-red chlorophyll ChlF peaks centered at 685V10 nm and 735V5 nm. Methods have been developed elsewhere to extract steady state solar induced fluorescence (SF) from apparent reflectance of vegetation canopies/landscapes using the Fraunhofer Line Depth (FLD) principal. Our study utilized these methods in conjunction with field-acquired high spectral resolution canopy reflectance spectra obtained in 2004 and 2005 over corn crops, as part of an ongoing multi-year experiment at the USDA/Agriculture Research Service in Beltsville, MD. A spectroradiometer (ASD-FR Fieldspec Pro, Analytical Spectral Devices, Inc., Boulder, CO) was used to measure canopy radiances 1 m above plant canopies with a 22deg field of view and a 0deg nadir view zenith angle. Canopy and plant measurements were made at the R3 grain fill reproductive stage on 3-4 replicate N application plots provided seasonal inputs of 280, 140, 70, and 28 kg N/ha. Leaf level measurements were also made which included ChlF, photosynthesis, and leaf constituents (photosynthetic pigment, carbon (C), and N contents). Crop yields were determined at harvest. SIF intensities for ChlF were derived directly from canopy reflectance spectra in specific narrowband regions associated with atmospheric oxygen absorption features centered at 688 and 760 nm. The red/far-red S F ratio derived from these field reflectance spectra successfully discriminated foliar pigment levels (e.g., total chlorophyll, Chl) associated with N application rates in both corn crops. This canopy-level spectral ratio was also

  5. Plant phenolics and absorption features in vegetation reflectance spectra near 1.66 μm

    Science.gov (United States)

    Kokaly, Raymond F.; Skidmore, Andrew K.

    2015-12-01

    Past laboratory and field studies have quantified phenolic substances in vegetative matter from reflectance measurements for understanding plant response to herbivores and insect predation. Past remote sensing studies on phenolics have evaluated crop quality and vegetation patterns caused by bedrock geology and associated variations in soil geochemistry. We examined spectra of pure phenolic compounds, common plant biochemical constituents, dry leaves, fresh leaves, and plant canopies for direct evidence of absorption features attributable to plant phenolics. Using spectral feature analysis with continuum removal, we observed that a narrow feature at 1.66 μm is persistent in spectra of manzanita, sumac, red maple, sugar maple, tea, and other species. This feature was consistent with absorption caused by aromatic Csbnd H bonds in the chemical structure of phenolic compounds and non-hydroxylated aromatics. Because of overlapping absorption by water, the feature was weaker in fresh leaf and canopy spectra compared to dry leaf measurements. Simple linear regressions of feature depth and feature area with polyphenol concentration in tea resulted in high correlations and low errors (% phenol by dry weight) at the dry leaf (r2 = 0.95, RMSE = 1.0%, n = 56), fresh leaf (r2 = 0.79, RMSE = 2.1%, n = 56), and canopy (r2 = 0.78, RMSE = 1.0%, n = 13) levels of measurement. Spectra of leaves, needles, and canopies of big sagebrush and evergreens exhibited a weak absorption feature centered near 1.63 μm, short ward of the phenolic compounds, possibly consistent with terpenes. This study demonstrates that subtle variation in vegetation spectra in the shortwave infrared can directly indicate biochemical constituents and be used to quantify them. Phenolics are of lesser abundance compared to the major plant constituents but, nonetheless, have important plant functions and ecological significance. Additional research is needed to advance our understanding of the spectral influences

  6. Rapid assessment of soluble solids content in navel orange by near-infrared diffuse reflectance spectra

    Science.gov (United States)

    Liu, Yande; Luo, Ji; Chen, Xingmiao; Ying, Yibin

    2006-10-01

    The potential of using Near Infrared diffuse reflectance spectroscopy to assess soluble solids content (SSC) of intact navel orange was examined. A total 40 samples were used to develop the calibration and prediction models. NIR spectral data were collected in the spectral region between 350 nm and 2500 nm and its second derivative spectra was used for this study. Different scattering correction algorithms (no preprocessing and multiplicative scattering correction (MSC) were compared. Calibration models based on different spectral ranges, different derivatives and different kinds of statistical models including partial least square (PLS) and principle component regression (PCR) were also compared in this research. The best results of PLS models with the second derivative spectra are r=0.929, RMSEC=0.517 and RMSEP=0.592, in the wavelength range of 361-2488 nm. The segment length used to derivate the spectra influences the calibration model and the results are better when the segment lengths and gap sizes are lower in Norris derivate filter. The results show that this method is feasible for rapid assessing SSC of the navel orange.

  7. Predicting ambient aerosol thermal-optical reflectance measurements from infrared spectra: elemental carbon

    Science.gov (United States)

    Dillner, A. M.; Takahama, S.

    2015-10-01

    Elemental carbon (EC) is an important constituent of atmospheric particulate matter because it absorbs solar radiation influencing climate and visibility and it adversely affects human health. The EC measured by thermal methods such as thermal-optical reflectance (TOR) is operationally defined as the carbon that volatilizes from quartz filter samples at elevated temperatures in the presence of oxygen. Here, methods are presented to accurately predict TOR EC using Fourier transform infrared (FT-IR) absorbance spectra from atmospheric particulate matter collected on polytetrafluoroethylene (PTFE or Teflon) filters. This method is similar to the procedure developed for OC in prior work (Dillner and Takahama, 2015). Transmittance FT-IR analysis is rapid, inexpensive and nondestructive to the PTFE filter samples which are routinely collected for mass and elemental analysis in monitoring networks. FT-IR absorbance spectra are obtained from 794 filter samples from seven Interagency Monitoring of PROtected Visual Environment (IMPROVE) sites collected during 2011. Partial least squares regression is used to calibrate sample FT-IR absorbance spectra to collocated TOR EC measurements. The FT-IR spectra are divided into calibration and test sets. Two calibrations are developed: one developed from uniform distribution of samples across the EC mass range (Uniform EC) and one developed from a uniform distribution of Low EC mass samples (EC normalized error (21 %). These performance metrics can be achieved with various degrees of spectral pretreatment (e.g., including or excluding substrate contributions to the absorbances) and are comparable in precision and accuracy to collocated TOR measurements. Only the normalized error is higher for the FT-IR EC measurements than for collocated TOR. FT-IR spectra are also divided into calibration and test sets by the ratios OC/EC and ammonium/EC to determine the impact of OC and ammonium on EC prediction. We conclude that FT-IR analysis with

  8. Plant phenolics and absorption features in vegetation reflectance spectra near 1.66 μm

    Science.gov (United States)

    Kokaly, Raymond F.; Skidmore, Andrew K

    2015-01-01

    Past laboratory and field studies have quantified phenolic substances in vegetative matter from reflectance measurements for understanding plant response to herbivores and insect predation. Past remote sensing studies on phenolics have evaluated crop quality and vegetation patterns caused by bedrock geology and associated variations in soil geochemistry. We examined spectra of pure phenolic compounds, common plant biochemical constituents, dry leaves, fresh leaves, and plant canopies for direct evidence of absorption features attributable to plant phenolics. Using spectral feature analysis with continuum removal, we observed that a narrow feature at 1.66 μm is persistent in spectra of manzanita, sumac, red maple, sugar maple, tea, and other species. This feature was consistent with absorption caused by aromatic C-H bonds in the chemical structure of phenolic compounds and non-hydroxylated aromatics. Because of overlapping absorption by water, the feature was weaker in fresh leaf and canopy spectra compared to dry leaf measurements. Simple linear regressions of feature depth and feature area with polyphenol concentration in tea resulted in high correlations and low errors (% phenol by dry weight) at the dry leaf (r2 = 0.95, RMSE = 1.0%, n = 56), fresh leaf (r2 = 0.79, RMSE = 2.1%, n = 56), and canopy (r2 = 0.78, RMSE = 1.0%, n = 13) levels of measurement. Spectra of leaves, needles, and canopies of big sagebrush and evergreens exhibited a weak absorption feature centered near 1.63 μm, short ward of the phenolic compounds, possibly consistent with terpenes. This study demonstrates that subtle variation in vegetation spectra in the shortwave infrared can directly indicate biochemical constituents and be used to quantify them. Phenolics are of lesser abundance compared to the major plant constituents but, nonetheless, have important plant functions and ecological significance. Additional research is needed to advance our understanding of the

  9. Predicting ambient aerosol thermal-optical reflectance (TOR) measurements from infrared spectra: organic carbon

    Science.gov (United States)

    Dillner, A. M.; Takahama, S.

    2015-03-01

    Organic carbon (OC) can constitute 50% or more of the mass of atmospheric particulate matter. Typically, organic carbon is measured from a quartz fiber filter that has been exposed to a volume of ambient air and analyzed using thermal methods such as thermal-optical reflectance (TOR). Here, methods are presented that show the feasibility of using Fourier transform infrared (FT-IR) absorbance spectra from polytetrafluoroethylene (PTFE or Teflon) filters to accurately predict TOR OC. This work marks an initial step in proposing a method that can reduce the operating costs of large air quality monitoring networks with an inexpensive, non-destructive analysis technique using routinely collected PTFE filter samples which, in addition to OC concentrations, can concurrently provide information regarding the composition of organic aerosol. This feasibility study suggests that the minimum detection limit and errors (or uncertainty) of FT-IR predictions are on par with TOR OC such that evaluation of long-term trends and epidemiological studies would not be significantly impacted. To develop and test the method, FT-IR absorbance spectra are obtained from 794 samples from seven Interagency Monitoring of PROtected Visual Environment (IMPROVE) sites collected during 2011. Partial least-squares regression is used to calibrate sample FT-IR absorbance spectra to TOR OC. The FTIR spectra are divided into calibration and test sets by sampling site and date. The calibration produces precise and accurate TOR OC predictions of the test set samples by FT-IR as indicated by high coefficient of variation (R2; 0.96), low bias (0.02 μg m-3, the nominal IMPROVE sample volume is 32.8 m3), low error (0.08 μg m-3) and low normalized error (11%). These performance metrics can be achieved with various degrees of spectral pretreatment (e.g., including or excluding substrate contributions to the absorbances) and are comparable in precision to collocated TOR measurements. FT-IR spectra are also

  10. Study on the effect of blood content on diffuse reflectance spectra of basal cell carcinoma skin tissue.

    Science.gov (United States)

    Nan, Miaoqing; He, Qingli

    2013-01-01

    Diffuse reflectance spectrum as a noninvasive method has been widely used to study the optical properties of cutaneous skin tissue. In this work, we optimized an eight-layered optical model of basal cell carcinoma skin tissue to study its optical properties. Based on the model, the diffuse reflectance spectra were reconstructed in visible wavelength range by Monte Carlo methods. After different blood contents were added to the optical model, the contribution of blood to diffuese reflectance spectra was investigated theoretically. The ratios of basal cell carcinoma skin and normal skin tissue were also calculated for both experimental result and rebuilt results to testify the theoretical reasonability of the model and methods.

  11. Total reflection X-ray fluorescence polymer spectra: classification by taxonomy statistic tools.

    Science.gov (United States)

    Vázquez, Cristina; Boeykens, Susana; Bonadeo, H

    2002-07-19

    The aim of this work is to explore the use of chemometric tools for the classification of synthetic and natural polymers with a mean molecular weight greater than 10(6). Total Reflection X-Ray Fluorescence (TXRF) spectra were obtained and analyzed in order to retrieve matrix information and to illustrate the calibration procedure. The intensities of the coherent and incoherent scattered peaks were specially selected for this purpose. The polymers studied were aqueous solutions of scleroglucan, polyacrilamide, polyoxyethylene oxide, glucomannan, 2,3,6-tri-o-ethylamylose and xhantan, in concentrations upto 1% (m/m). matlab software was used for numerical calculations. Using a combination of principal component analysis and cluster analysis, the differences in composition of various analyzed polymers can be visualized.

  12. Hyperspectral optical imaging of human iris in vivo: characteristics of reflectance spectra

    Science.gov (United States)

    Medina, José M.; Pereira, Luís M.; Correia, Hélder T.; Nascimento, Sérgio M. C.

    2011-07-01

    We report a hyperspectral imaging system to measure the reflectance spectra of real human irises with high spatial resolution. A set of ocular prosthesis was used as the control condition. Reflectance data were decorrelated by the principal-component analysis. The main conclusion is that spectral complexity of the human iris is considerable: between 9 and 11 principal components are necessary to account for 99% of the cumulative variance in human irises. Correcting image misalignments associated with spontaneous ocular movements did not influence this result. The data also suggests a correlation between the first principal component and different levels of melanin present in the irises. It was also found that although the spectral characteristics of the first five principal components were not affected by the radial and angular position of the selected iridal areas, they affect the higher-order ones, suggesting a possible influence of the iris texture. The results show that hyperspectral imaging in the iris, together with adequate spectroscopic analyses provide more information than conventional colorimetric methods, making hyperspectral imaging suitable for the characterization of melanin and the noninvasive diagnosis of ocular diseases and iris color.

  13. Predicting ambient aerosol Thermal Optical Reflectance (TOR) measurements from infrared spectra: elemental carbon

    Science.gov (United States)

    Dillner, A. M.; Takahama, S.

    2015-06-01

    Elemental carbon (EC) is an important constituent of atmospheric particulate matter because it absorbs solar radiation influencing climate and visibility and it adversely affects human health. The EC measured by thermal methods such as Thermal-Optical Reflectance (TOR) is operationally defined as the carbon that volatilizes from quartz filter samples at elevated temperatures in the presence of oxygen. Here, methods are presented to accurately predict TOR EC using Fourier Transform Infrared (FT-IR) absorbance spectra from atmospheric particulate matter collected on polytetrafluoroethylene (PTFE or Teflon) filters. This method is similar to the procedure tested and developed for OC in prior work (Dillner and Takahama, 2015). Transmittance FT-IR analysis is rapid, inexpensive, and non-destructive to the PTFE filter samples which are routinely collected for mass and elemental analysis in monitoring networks. FT-IR absorbance spectra are obtained from 794 filter samples from seven Interagency Monitoring of PROtected Visual Environment (IMPROVE) sites collected during 2011. Partial least squares regression is used to calibrate sample FT-IR absorbance spectra to collocated TOR EC measurements. The FTIR spectra are divided into calibration and test sets. Two calibrations are developed, one which is developed from uniform distribution of samples across the EC mass range (Uniform EC) and one developed from a~uniform distribution of low EC mass samples (EC TOR EC samples in the same mass range and an estimate of the minimum detection limit (MDL) that is on par with TOR EC MDL. For all samples, this hybrid approach leads to precise and accurate TOR EC predictions by FT-IR as indicated by high coefficient of variation (R2; 0.96), no bias (0.00 μg m-3, concentration value based on the nominal IMPROVE sample volume of 32.8 m-3), low error (0.03 μg m-3) and reasonable normalized error (21 %). These performance metrics can be achieved with various degrees of spectral pretreatment

  14. Method and apparatus for aligning laser reflective surfaces

    International Nuclear Information System (INIS)

    Caruolo, A.B.; Davis, J.W.; Walch, A.P.

    1975-01-01

    Methods and apparatus used in the alignment of high power laser systems to obtain optimum performance are disclosed. An external source of visible radiation provides an alignment beam which is reflected along the axis of a resonator. Reflecting surfaces of the resonator are aligned with respect to the axis located by the visible beam

  15. Effects of Space Weathering on Reflectance Spectra of Ureilites: A Proof-of-Concept Study

    Science.gov (United States)

    Goodrich, C. A.; Gillis-Davis, J.; Cloutis, E.; Applin, D.; Hibbits, C.; Klima, R.; Christoffersen, R.; Fries, M.; Decker, S.

    2017-07-01

    Space weathering and spectral studies of three ureilitic samples show that space weathering causes significant changes in UV-VIS-IR spectra and Raman spectra. Changes due to amorphization of carbon could disguise ureilitic asteroids as CC-like.

  16. Estimating surface reflectance from Himawari-8/AHI reflectance channels Using 6SV

    Science.gov (United States)

    Lee, Kyeong-sang; Choi, Sungwon; Seo, Minji; Seong, Noh-hun; Han, Kyung-soo

    2017-04-01

    TOA (Top Of Atmospheric) reflectance observed by satellite is modified by the influence of atmosphere such as absorbing and scattering by molecular and gasses. Removing TOA reflectance attenuation which is caused by the atmospheric is essential. surface reflectance with compensated atmospheric effects used as important input data for land product such as Normalized Difference Vegetation Index (NDVI), Land Surface Albedo (LSA) and etc. In this study, we Second Simulation of a Satellite Signal in the Solar Spectrum Vector (6SV) Radiative Transfer Model (RTM) for atmospheric correction and estimating surface reflectance from Himawari-8/Advanced Himawari Imager (AHI) reflectance channels. 6SV has the advantage that it has high accuracy by performing the atmospheric correction by dividing the width of the satellite channel by 2.5 nm, but it is slow to use in the operation. So, we use LUT approach to reduce the computation time and avoid the intensive calculation required for retrieving surface reflectance. Estimated surface reflectance data were compared with PROBA-V S1 data to evaluate the accuracy. As a result Root Mean Square Error (RMSE) and bias were about 0.05 and -0.02. It is considered that this error is due to the difference of angle component and Spectral Response Function (SRF) of each channel.

  17. 100% reflectivity from a monolithic dielectric microstructured surface

    OpenAIRE

    Brückner, F.; Clausnitzer, T.; Burmeister, O.; Friedrich, D.; Kley, E.; Danzmann, K.; Tünnermann, A.; Schnabel, R.

    2008-01-01

    Here, we propose a new mirror architecture which is solely based upon a monolithic dielectric micro-structured surface. Hence, the mirror device, which consists of a possibly mono-crystalline bulk material, can in principle simultaneously provide perfect reflectivity and lowest mechanical loss. By specifically structuring the monolithic surface, resulting in T-shaped ridges of a subwavelength grating, a resonant behavior of light coupling can be realized, leading to theoretically 100% reflect...

  18. Surface Compositional Units on Mercury from Spectral Reflectance at Ultraviolet to Near-infrared Wavelengths

    Science.gov (United States)

    Izenberg, N. R.; Holsclaw, G. M.; Domingue, D. L.; McClintock, W. E.; Klima, R. L.; Blewett, D. T.; Helbert, J.; Head, J. W.; Sprague, A. L.; Vilas, F.; Solomon, S. C.

    2012-12-01

    The Mercury Atmospheric and Surface Composition Spectrometer (MASCS) on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft has been acquiring reflectance spectra of Mercury's surface for over 16 months. The Visible and Infrared Spectrograph (VIRS) component of MASCS has accumulated a global data set of more than 2 million spectra over the wavelength range 300-1450 nm. We have derived a set of VIRS spectral units (VSUs) from the following spectral parameters: visible brightness (R575: reflectance at 575 nm); visible/near-infrared reflectance ratio (VISr: reflectance at 415 nm to that at 750 nm); and ultraviolet reflectance ratio (UVr: reflectance at 310 nm to that at 390 nm). Five broad, slightly overlapping VSUs may be distinguished from these parameters. "Average VSU" areas have spectral parameters close to mean global values. "Dark blue VSU" areas have spectra with low R575 and high UVr. "Red VSU" areas have spectra with low UVr and higher VISr and R575 than average. "Intermediate VSU" areas have spectra with higher VISr than VSU red, generally higher R575, and a wide range of UVr. "Bright VSU" areas have high R575 and VISr and intermediate UVr. Several units defined by morphological or multispectral criteria correspond to specific VSUs, including low-reflectance material (dark blue VSU), pyroclastic deposits (red VSU), and hollows (intermediate VSU), but these VSUs generally include other types of areas as well. VSU definitions are complementary to those obtained by unsupervised clustering analysis. The global distribution of VIRS spectral units provides new information on Mercury's geological evolution. Much of Mercury's northern volcanic plains show spectral properties ranging from those of average VSU to those of red VSU, as does a large region in the southern hemisphere centered near 50°S, 245°E. Dark blue VSU material is widely distributed, with concentrations south of the northern plains, around the Rembrandt and

  19. Diffuse reflection of ultracold neutrons from low-roughness surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Atchison, F.; Daum, M.; Henneck, R.; Horisberger, M.; Kirch, K.; Lauss, B.; Mtchedlishvili, A.; Meier, M.; Petzoldt, G.; Schelldorfer, R.; Zsigmond, G. [Paul Scherrer Institut, PSI, Villigen (Switzerland); Heule, S.; Knecht, A. [Paul Scherrer Institut, PSI, Villigen (Switzerland); University Zuerich, Zuerich (Switzerland); Kasprzak, M. [Paul Scherrer Institut, PSI, Villigen (Switzerland); Stefan Meyer Institut, Vienna (Austria); Kuzniak, M. [Paul Scherrer Institut, PSI, Villigen (Switzerland); Jagiellonian University, Smoluchowski Institute of Physics, Cracow (Poland); Plonka-Spehr, C. [Institut Laue Langevin, ILL, Grenoble (France); Straumann, U. [University Zuerich, Zuerich (Switzerland)

    2010-04-15

    We report a measurement of the reflection of ultracold neutrons from flat, large-area plates of different Fermi potential materials with low surface roughness. The results were used to test two diffuse reflection models, the well-known Lambert model and the micro-roughness model which is based on wave scattering. The Lambert model fails to reproduce the diffuse reflection data. The surface roughness b and correlation length w, obtained by fitting the micro-roughness model to the data are in the range 1{<=}b{<=}3 nm and 10{<=}w{<=}120 nm, in qualitative agreement with independent measurements using atomic force microscopy. (orig.)

  20. Diffuse reflection of ultracold neutrons from low-roughness surfaces

    International Nuclear Information System (INIS)

    Atchison, F.; Daum, M.; Henneck, R.; Horisberger, M.; Kirch, K.; Lauss, B.; Mtchedlishvili, A.; Meier, M.; Petzoldt, G.; Schelldorfer, R.; Zsigmond, G.; Heule, S.; Knecht, A.; Kasprzak, M.; Kuzniak, M.; Plonka-Spehr, C.; Straumann, U.

    2010-01-01

    We report a measurement of the reflection of ultracold neutrons from flat, large-area plates of different Fermi potential materials with low surface roughness. The results were used to test two diffuse reflection models, the well-known Lambert model and the micro-roughness model which is based on wave scattering. The Lambert model fails to reproduce the diffuse reflection data. The surface roughness b and correlation length w, obtained by fitting the micro-roughness model to the data are in the range 1≤b≤3 nm and 10≤w≤120 nm, in qualitative agreement with independent measurements using atomic force microscopy. (orig.)

  1. On the reflection point where light reflects to a known destination on quadratic surfaces.

    Science.gov (United States)

    Gonçalves, Nuno

    2010-01-15

    We address the problem of determining the reflection point on a specular surface where a light ray that travels from a source to a target is reflected. The specular surfaces considered are those expressed by a quadratic equation. So far, there is no closed form explicit equation for the general solution of this determination of the reflection point, and the usual approach is to use the Snell law or the Fermat principle whose equations are derived in multidimensional nonlinear minimizations. We prove in this Letter that one can impose a set of three restrictions to the reflection point that can impose a set of three restrictions that culminates in a very elegant formalism of searching the reflection point in a unidimensional curve in space. This curve is the intersection of two quadratic equations. Some applications of this framework are also discussed.

  2. A light reflecting apparatus including a multi-aberration light reflecting surface

    Science.gov (United States)

    Sawicki, R.H.; Sweatt, W.

    1985-11-21

    A light reflecting apparatus including a multi-aberration bendable light reflecting surface is disclosed herein. This apparatus includes a structural assembly comprised of a rectangular plate which is resiliently bendable, to a limited extent, and which has a front side defining the multi-aberration light reflecting surface and an opposite back side, and a plurality of straight leg members rigidly connected with the back side of the plate and extending rearwardly therefrom. The apparatus also includes a number of different adjustment mechanisms, each of which is connected with specific ones of the leg members. These mechanisms are adjustably movable in different ways for applying corresponding forces to the leg members in order to bend the rectangular plate and light reflecting surface into different predetermined curvatures and which specifically include quadratic and cubic curvatures corresponding to different optical aberrations.

  3. Thermal Infrared Spectra of Microcrystalline Sedimentary Phases: Effects of Natural Surface Roughness on Spectral Feature Shape

    Science.gov (United States)

    Hardgrove, C.; Rogers, A. D.

    2012-03-01

    Thermal infrared spectral features of common microcrystalline phases (chert, alabaster, micrite) are presented. Spectra are sensitive to mineralogy and micron-scale (~1-25 µm) surface roughness. Roughness is on the scale of the average crystal size.

  4. The effect of grain size and phosphorous-doping of polycrystalline 3C-SiC on infrared reflectance spectra

    Energy Technology Data Exchange (ETDEWEB)

    Rooyen, I.J. van, E-mail: Isabella.vanRooyen@inl.gov [Fuel Performance and Design Department, Idaho National Laboratory, Idaho Falls, ID 83415-6188 (United States); Department of Physics, Nelson Mandela Metropolitan University, Port Elizabeth (South Africa); Engelbrecht, J.A.A. [Department of Physics, Nelson Mandela Metropolitan University, Port Elizabeth (South Africa); Henry, A.; Janzen, E. [Department of Physics, Chemistry and Biology, Semiconductor Materials, Linkoeping University, Linkoeping 58183 (Sweden); Neethling, J.H. [Department of Physics, Nelson Mandela Metropolitan University, Port Elizabeth (South Africa); Rooyen, P.M. van [Philip M van Rooyen Network Consultants, Midlands Estates (South Africa)

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer IR is investigated as a technique to measure grain size and P-doping of polycrystalline SiC. Black-Right-Pointing-Pointer Infrared plasma minima can be used to determine doping levels in 3C-SiC for doping levels greater than 5 Multiplication-Sign 10{sup 17} cm{sup -3}. Black-Right-Pointing-Pointer A linear relationship is found between FWHM and the inverse of grain size of 3C-SiC irrespective of P-doping level. Black-Right-Pointing-Pointer It is further found that {omega}{sub p} is not influenced by the grain size. Black-Right-Pointing-Pointer P-doping level has no significant effect on the linear relationship between grain size and surface roughness. - Abstract: The effect of P-doping and grain size of polycrystalline 3C-SiC on the infrared reflectance spectra is reported. The relationship between grain size and full width at half maximum (FWHM) suggest that the behavior of the 3C-SiC with the highest phosphorous doping level (of 1.2 Multiplication-Sign 10{sup 19} at. cm{sup -3}) is different from those with lower doping levels (<6.6 Multiplication-Sign 10{sup 18} at. cm{sup -3}). It is also further demonstrated that the plasma resonance frequency ({omega}{sub p}) is not influenced by the grain size.

  5. The effect of grain size and phosphorous-doping of polycrystalline 3C–SiC on infrared reflectance spectra

    International Nuclear Information System (INIS)

    Rooyen, I.J. van; Engelbrecht, J.A.A.; Henry, A.; Janzén, E.; Neethling, J.H.; Rooyen, P.M. van

    2012-01-01

    Highlights: ► IR is investigated as a technique to measure grain size and P-doping of polycrystalline SiC. ► Infrared plasma minima can be used to determine doping levels in 3C–SiC for doping levels greater than 5 × 10 17 cm −3 . ► A linear relationship is found between FWHM and the inverse of grain size of 3C–SiC irrespective of P-doping level. ► It is further found that ω p is not influenced by the grain size. ► P-doping level has no significant effect on the linear relationship between grain size and surface roughness. - Abstract: The effect of P-doping and grain size of polycrystalline 3C–SiC on the infrared reflectance spectra is reported. The relationship between grain size and full width at half maximum (FWHM) suggest that the behavior of the 3C–SiC with the highest phosphorous doping level (of 1.2 × 10 19 at. cm −3 ) is different from those with lower doping levels ( 18 at. cm −3 ). It is also further demonstrated that the plasma resonance frequency (ω p ) is not influenced by the grain size.

  6. A whole image approach using field measurements for transforming EO1 Hyperion hyperspectral data into canopy reflectance spectra

    Science.gov (United States)

    Ramsey, Elijah W.; Nelson, G.

    2005-01-01

    To maximize the spectral distinctiveness (information) of the canopy reflectance, an atmospheric correction strategy was implemented to provide accurate estimates of the intrinsic reflectance from the Earth Observing 1 (EO1) satellite Hyperion sensor signal. In rendering the canopy reflectance, an estimate of optical depth derived from a measurement of downwelling irradiance was used to drive a radiative transfer simulation of atmospheric scattering and attenuation. During the atmospheric model simulation, the input whole-terrain background reflectance estimate was changed to minimize the differences between the model predicted and the observed canopy reflectance spectra at 34 sites. Lacking appropriate spectrally invariant scene targets, inclusion of the field and predicted comparison maximized the model accuracy and, thereby, the detail and precision in the canopy reflectance necessary to detect low percentage occurrences of invasive plants. After accounting for artifacts surrounding prominent absorption features from about 400nm to 1000nm, the atmospheric adjustment strategy correctly explained 99% of the observed canopy reflectance spectra variance. Separately, model simulation explained an average of 88%??9% of the observed variance in the visible and 98% ?? 1% in the near-infrared wavelengths. In the 34 model simulations, maximum differences between the observed and predicted reflectances were typically less than ?? 1% in the visible; however, maximum reflectance differences higher than ?? 1.6% (reflectance differences remained less than ??3% for 68% of the comparisons (??1 standard deviation) and less than ??6% for 95% of the comparisons (??2 standard deviation). Higher reflectance differences in the visible and near-infrared wavelengths were most likely associated with problems in the comparison, not in the model generation. ?? 2005 US Government.

  7. Reflection properties of hydrogen ions at helium irradiated tungsten surfaces

    International Nuclear Information System (INIS)

    Doi, K; Tawada, Y; Kato, S; Sasao, M; Kenmotsu, T; Wada, M; Lee, H T; Ueda, Y; Tanaka, N; Kisaki, M; Nishiura, M; Matsumoto, Y; Yamaoka, H

    2016-01-01

    Nanostructured W surfaces prepared by He bombardment exhibit characteristic angular distributions of hydrogen ion reflection upon injection of 1 keV H + beam. A magnetic momentum analyzer that can move in the vacuum chamber has measured the angular dependence of the intensity and the energy of reflected ions. Broader angular distributions were observed for He-irradiated tungsten samples compared with that of the intrinsic polycrystalline W. Both intensity and energy of reflected ions decreased in the following order: the polycrystalline W, the He-bubble containing W, and the fuzz W. Classical trajectory Monte Carlo simulations based on Atomic Collision in Amorphous Target code suggests that lower atom density near the surface can make the reflection coefficients lower due to increasing number of collisions. (paper)

  8. FT-IR reflection spectra of single crystals: resolving phonons of different symmetry without using polarised radiation

    Directory of Open Access Journals (Sweden)

    METODIJA NAJDOSKI

    2000-07-01

    Full Text Available Fourier-transform infrared (FT-IR reflection spectra, asquired at nearnormal incidence, were recorded from single crystals belonging to six crystal systems: CsCr(SO42.12H2O (alum, cubic, K2CuCl2·2H2O (Mitscherlichite, tetragonal, CaCO3 (calcite, hexagonal, KHSO4 (mercallite, orthorhombic, CaSO4·2H2O (gypsum, monoclinic and CuSO4·5H2O (chalcantite, triclinic. The acquired IR reflection spectra were further transformed into absorption spectra, employing the Kramers-Kronig transformation. Except for the cubic alums, the spectra strongly depend on the crystal face from which they were recorded; this is a consequence of anisotropy. Phonons of a given symmetry (E-species, in tetragonal/hexagonal and B-species, in monoclinic crystals may be resolved without using a polariser. The spectrum may be simplified in the case of an orthorhombic crystal, as well. The longitudinal-optical (LO and transversal-optical (TO mode frequencies were calculated in the case of optically isotropic and the simplified spectra of optically uniaxial crystals.

  9. Surface enhanced Raman spectra of the organic nonlinear optic ...

    Indian Academy of Sciences (India)

    Wintec

    Institute of Chemistry, University of Opole, Olesksa 48 45-052 Opole, Poland. 1. Present Address: Department of Physics, V.P.S.H.S.S. for ... co-ordination chemistry. Surface-enhanced Raman scattering (SERS), using .... numbers were calculated using analytic second de- rivatives to confirm the convergence to minima on.

  10. Field verification of ADCP surface gravity wave elevation spectra

    NARCIS (Netherlands)

    Hoitink, A.J.F.; Peters, H.C.; Schroevers, M.

    2007-01-01

    Acoustic Doppler current profilers (ADCPs) can measure orbital velocities induced by surface gravity waves, yet the ADCP estimates of these velocities are subject to a relatively high noise level. The present paper introduces a linear filtration technique to significantly reduce the influence of

  11. Reflection characteristics of a composite planar AMC surface

    Directory of Open Access Journals (Sweden)

    Ruey-Bing Hwang

    2012-03-01

    Full Text Available This study investigates the reflection characteristics of a composite Artificial Magnetic Conductor (AMC surface consisting of multiple orthogonal gradient AMC surfaces arranged in a two-dimensional periodic pattern. The gradient AMC surface in this study consists of square metal patches of variable size printed on a grounded dielectric substrate. Due to the orthogonal placement of the gradient AMC surface, the incident energy of a plane wave normally incident on the composite AMC surface will be reflected into four major lobes away from the impinging direction. To achieve a systematical design, a simple formula based on array antenna theory was developed to determine the reflection pattern of the gradient AMC surface illuminated by a normal incident plane wave. A time-domain full-wave simulation was also carried out to calculate the electromagnetic fields in the structure and the far-field patterns. The scattering patterns of the structure were measured in an electromagnetic anechoic chamber. Results confirm the design principle and procedures in this research. Since such a composite AMC surface can be easily fabricated using the standard printed circuit board technique without via-hole process, it may have potential applications in beam-steering and radar cross section reduction.

  12. Relationship between microstructure of the skin surface and surface reflection based on geometric optics.

    Science.gov (United States)

    Yoshida, Kenichiro; Miyaki, Masahiro; Ojima, Nobutoshi; Iwata, Kayoko

    2012-06-01

    The behavior of reflected light in skin affects skin appearance and provides clues as to the internal condition of the skin. Surface topography is one of the central physical factors contributing to surface reflection. We tried to clarify the relationship between microstructure of the skin surface and surface reflection based on geometric optics. Microstructures and surface reflections in the left cheeks of adult females were evaluated. Skin topography was acquired measuring replicas using confocal laser microscopy. Surface topography was used to calculate arithmetical mean deviation of the surface (S(a)), and geometric index from gradient of the surface (S(grad)), which is expected to correlate with the directionality of surface reflection (DoSR) based on geometric optics. A surface reflection image was acquired from differently polarized pictures of a face, and the index of surface reflection (I(obs)) was calculated as the average pixel value of the area of shine. Correlations between indices were then evaluated. S(grad) and S(a) showed significant correlation (preflection from the reflection model than S(a). In addition, S(grad) can explain differences in DoSR for some panelists even in the case of an identical S(a). The topographic element involved in DoSR was extracted from height mapping. S(grad) reflects the ratio of flat area, offering a more effective indicator than S(a) for distinguishing topographic characteristics with respect to surface reflection. Copyright © 2012 Japanese Society for Investigative Dermatology. Published by Elsevier Ireland Ltd. All rights reserved.

  13. Separation of Atmospheric and Surface Spectral Features in Mars Global Surveyor Thermal Emission Spectrometer (TES) Spectra

    Science.gov (United States)

    Smith, Michael D.; Bandfield, Joshua L.; Christensen, Philip R.

    2000-01-01

    We present two algorithms for the separation of spectral features caused by atmospheric and surface components in Thermal Emission Spectrometer (TES) data. One algorithm uses radiative transfer and successive least squares fitting to find spectral shapes first for atmospheric dust, then for water-ice aerosols, and then, finally, for surface emissivity. A second independent algorithm uses a combination of factor analysis, target transformation, and deconvolution to simultaneously find dust, water ice, and surface emissivity spectral shapes. Both algorithms have been applied to TES spectra, and both find very similar atmospheric and surface spectral shapes. For TES spectra taken during aerobraking and science phasing periods in nadir-geometry these two algorithms give meaningful and usable surface emissivity spectra that can be used for mineralogical identification.

  14. Computer simulation of RBS spectra from samples with surface roughness

    Czech Academy of Sciences Publication Activity Database

    Malinský, Petr; Hnatowicz, Vladimír; Macková, Anna

    2016-01-01

    Roč. 371, MAR (2016), s. 101-105 ISSN 0168-583X. [22nd International conference on Ion Beam Analysis (IBA). Opatija, 14.06.2015-19.06.2015] R&D Projects: GA MŠk(CZ) LM2011019; GA ČR GA15-01602S Institutional support: RVO:61389005 Keywords : computer simulation * Rutherford backscattering * surface roughness Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 1.109, year: 2016

  15. Quality Assessment of Landsat Surface Reflectance Products Using MODIS Data

    Science.gov (United States)

    Feng, Min; Huang, Chengquan; Channan, Saurabh; Vermote, Eric; Masek, Jeffrey G.; Townshend, John R.

    2012-01-01

    Surface reflectance adjusted for atmospheric effects is a primary input for land cover change detection and for developing many higher level surface geophysical parameters. With the development of automated atmospheric correction algorithms, it is now feasible to produce large quantities of surface reflectance products using Landsat images. Validation of these products requires in situ measurements, which either do not exist or are difficult to obtain for most Landsat images. The surface reflectance products derived using data acquired by the Moderate Resolution Imaging Spectroradiometer (MODIS), however, have been validated more comprehensively. Because the MODIS on the Terra platform and the Landsat 7 are only half an hour apart following the same orbit, and each of the 6 Landsat spectral bands overlaps with a MODIS band, good agreements between MODIS and Landsat surface reflectance values can be considered indicators of the reliability of the Landsat products, while disagreements may suggest potential quality problems that need to be further investigated. Here we develop a system called Landsat-MODIS Consistency Checking System (LMCCS). This system automatically matches Landsat data with MODIS observations acquired on the same date over the same locations and uses them to calculate a set of agreement metrics. To maximize its portability, Java and open-source libraries were used in developing this system, and object-oriented programming (OOP) principles were followed to make it more flexible for future expansion. As a highly automated system designed to run as a stand-alone package or as a component of other Landsat data processing systems, this system can be used to assess the quality of essentially every Landsat surface reflectance image where spatially and temporally matching MODIS data are available. The effectiveness of this system was demonstrated using it to assess preliminary surface reflectance products derived using the Global Land Survey (GLS) Landsat

  16. An instrument for the measurement of road surface reflection properties

    DEFF Research Database (Denmark)

    Corell, Dennis Dan; Sørensen, K.

    2017-01-01

    Road surface reflection data in the form of standard r-tables serve as input for design calculations of road lighting installations on traffic roads. However, in several countries the use of the standard r-tables has not been verified by measurement in a long period of time, while the types of road...

  17. Quality-factor and reflection-coefficient estimation using reflected surface waves

    NARCIS (Netherlands)

    Draganov, D.S.; Ruigrok, E.N.; Ghose, R.; Mikesell, D.; Van Wijk, K.

    2014-01-01

    We propose a method for estimating the reflection coefficient of a subvertical boundary and the the quality factor of the medium between a receiver and the subvertical boundary. The method uses surface waves from transient deterministic sources and is inspired by the occurrence of non-physical

  18. Copper-assisted, anti-reflection etching of silicon surfaces

    Science.gov (United States)

    Toor, Fatima; Branz, Howard

    2014-08-26

    A method (300) for etching a silicon surface (116) to reduce reflectivity. The method (300) includes electroless deposition of copper nanoparticles about 20 nanometers in size on the silicon surface (116), with a particle-to-particle spacing of 3 to 8 nanometers. The method (300) includes positioning (310) the substrate (112) with a silicon surface (116) into a vessel (122). The vessel (122) is filled (340) with a volume of an etching solution (124) so as to cover the silicon surface (116). The etching solution (124) includes an oxidant-etchant solution (146), e.g., an aqueous solution of hydrofluoric acid and hydrogen peroxide. The silicon surface (116) is etched (350) by agitating the etching solution (124) with, for example, ultrasonic agitation, and the etching may include heating (360) the etching solution (124) and directing light (365) onto the silicon surface (116). During the etching, copper nanoparticles enhance or drive the etching process.

  19. Mercury's Surface Magnetic Field Determined from Proton-Reflection Magnetometry

    Science.gov (United States)

    Winslow, Reka M.; Johnson, Catherine L.; Anderson, Brian J.; Gershman, Daniel J.; Raines, Jim M.; Lillis, Robert J.; Korth, Haje; Slavin, James A.; Solomon, Sean C.; Zurbuchen, Thomas H.; hide

    2014-01-01

    Solar wind protons observed by the MESSENGER spacecraft in orbit about Mercury exhibit signatures of precipitation loss to Mercury's surface. We apply proton-reflection magnetometry to sense Mercury's surface magnetic field intensity in the planet's northern and southern hemispheres. The results are consistent with a dipole field offset to the north and show that the technique may be used to resolve regional-scale fields at the surface. The proton loss cones indicate persistent ion precipitation to the surface in the northern magnetospheric cusp region and in the southern hemisphere at low nightside latitudes. The latter observation implies that most of the surface in Mercury's southern hemisphere is continuously bombarded by plasma, in contrast with the premise that the global magnetic field largely protects the planetary surface from the solar wind.

  20. Link functions and Matérn kernel in the estimation of reflectance spectra from RGB responses.

    Science.gov (United States)

    Heikkinen, Ville; Mirhashemi, Arash; Alho, Juha

    2013-11-01

    We evaluate three link functions (square root, logit, and copula) and Matérn kernel in the kernel-based estimation of reflectance spectra of the Munsell Matte collection in the 400-700 nm region. We estimate reflectance spectra from RGB camera responses in case of real and simulated responses and show that a combination of link function and a kernel regression model with a Matérn kernel decreases spectral errors when compared to a Gaussian mixture model or kernel regression with the Gaussian kernel. Matérn kernel produces performance similar to the thin plate spline model, but does not require a parametric polynomial part in the model.

  1. Stair-Step Particle Flux Spectra on the Lunar Surface: Evidence for Nonmonotonic Potentials?

    Science.gov (United States)

    Collier, Michael R.; Newheart, Anastasia; Poppe, Andrew R.; Hills, H. Kent; Farrell, William M.

    2016-01-01

    We present examples of unusual "stair-step" differential flux spectra observed by the Apollo 14 Suprathermal Ion Detector Experiment on the lunar dayside surface in Earth's magnetotail. These spectra exhibit a relatively constant differential flux below some cutoff energy and then drop off precipitously, by about an order of magnitude or more, at higher energies. We propose that these spectra result from photoions accelerated on the lunar dayside by nonmonotonic potentials (i.e.,potentials that do not decay to zero monotonically) and present a model for the expected differential flux. The energy of the cutoff and the magnitude of the differential flux are related to the properties of the local space environment and are consistent with the observed flux spectra. If this interpretation is correct, these surface-based ion observations provide a unique perspective that both complements and enhances the conclusions obtained by remote-sensing orbiter observations on the Moon's exospheric and electrostatic properties.

  2. Excitations of surface plasmon polaritons by attenuated total reflection, revisited

    International Nuclear Information System (INIS)

    Barchesi, D.; Otto, A.

    2013-01-01

    Many textbooks and review papers are devoted to plasmonics based on a selection of the numerous bibliography. But none describes the details of the first culmination of plasmonics in 1968, when surface plasmons become a field of optics. The coupling of light with the surface plasmon leads to the surface plasmon polariton (SPP). Therefore, the authors chose to associate historical insight (not avoiding a personal touch), a modern mathematical formulation of the excitation of the SPP by attenuated total reflection (ATR), considered as well understood since decades, and experimental applications since 1969, including recent developments.

  3. An instrument for the measurement of road surface reflection properties

    DEFF Research Database (Denmark)

    Corell, Dennis Dan; Sørensen, K.

    2017-01-01

    Road surface reflection data in the form of standard r-tables serve as input for design calculations of road lighting installations on traffic roads. However, in several countries the use of the standard r-tables has not been verified by measurement in a long period of time, while the types of road...... surfaces in use have changed - for instance to road surface types with less noise from wheel passages. Because of this, a co-operation between the road administrations of the Nordic countries (abbreviated NMF) decided to construct a portable instrument to be used on selections of traffic roads within...

  4. The influence of surface reflectance anisotropy on estimation of soil properties

    Science.gov (United States)

    Bartholomeus, Harm; Roosjen, Peter; Clevers, Jan

    2014-05-01

    The spatial variation in soil properties is an important factor for agricultural management. Unmanned airborne vehicles (UAV's) equipped with a hyperspectral mapping system may provide these data, but anisotropic reflectance effects may have an influence on the derived soil properties. Besides influencing the reflectance, angular observations may deliver added information about soil properties. We investigated the anisotropic behavior of 59 soil samples with a large variation in soil composition, by measuring their reflectance (350-2500 nm) over 92 different angles using a robot-based laboratory goniometer system. The results show that the anisotropic behavior of the soils influences the measured reflectance significantly, which limits the accurate prediction of soil properties (OM and clay especially). However, prediction accuracies of OM increase when spectra are measured under specific angles. Prediction accuracies further increase when a combination of observation angles is being used. Apart from that, using UAV's the wavelength range is limited to about 1000 nm. In general, this will decrease the model performance, but our results show that this effect can largely be compensated by combining multiple observation angles. Altogether, we demonstrate that surface anisotropy influences the prediction of soil properties negatively. This effect can be reduced by combining spectra acquired under different angles. Moreover, predictions can be improved if combinations of different observation angles are used.

  5. Reflectance Spectra of Synthetic Ortho- and Clinoenstatite in the UV, VIS, and IR for Comparison with Fe-poor Asteroids

    Science.gov (United States)

    Markus, Kathrin; Arnold, Gabriele; Hiesinger, Harald; Rohrbach, Arno

    2016-04-01

    Major rock forming minerals like pyroxenes are very common in the solar system and show characteristic absorption bands due to Fe2+ in the VIS and NIR [e.g., 1, 2]. The Fe-free endmember enstatite is also a common mineral on planetary surfaces like asteroids and probably Mercury [3] and a major constituent of meteorites like aubrites [4] and enstatite chondrites [5]. Reflectance spectra of these meteorites as well as the enstatite-rich or generally Fe-poor asteroids like the asteroidal targets of the Esa Rosetta mission (2867) Steins [6] and (21) Lutetia [7] are often featureless in the VIS and NIR lacking the absorption features associated with iron incorporated into the crystal structure of silicates. Fe-bearing orthopyroxenes show diagnostic absorption bands at ˜1 μm and ˜2 μm. While systematic changes in positions and depths of these bands with changes in Fe- and Ca-content of orthopyroxenes have been extensively studied [e.g., 2, 8], almost Fe-free enstatite is so far only spectroscopically investigated by [2]. For a better understanding of these Fe-poor bodies the availability of laboratory spectra of Fe-free silicates as analog materials are crucial but terrestrial samples of enstatite usually contain several mol% of FeO with pure enstatite being extremely rare. For easy availability of larger amounts of pure enstatite we developed a technique for synthesis of enstatite. These enstatite samples can be used as analog materials for laboratory studies for e.g. producing mixtures with other mineral samples. Enstatite has 3 stable polymorphs with clinoenstatite, orthoenstatite, and protoenstatite being stable at low (600° C), and high (>1000° C) temperatures [9]. Orthoenstatite and protoenstatite are orthorhombic, while clinoenstatite is monoclinic. Orthoenstatite is abundant in terrestrial rocks and in meteorites. Clinoenstatite is known from meteorites [5, 9]. Both polymorphs of enstatite therefore exist on the parent bodies of aubrites and enstatite

  6. Attenuated total reflectance Fourier-transform infrared spectroscopy of carboxylic acids adsorbed onto mineral surfaces

    Science.gov (United States)

    Kubicki, J. D.; Schroeter, L. M.; Itoh, M. J.; Nguyen, B. N.; Apitz, S. E.

    1999-09-01

    A suite of naturally-occurring carboxylic acids (acetic, oxalic, citric, benzoic, salicylic and phthalic) and their corresponding sodium salts were adsorbed onto a set of common mineral substrates (quartz, albite, illite, kaolinite and montmorillonite) in batch slurry experiments. Solution pH's of approximately 3 and 6 were used to examine the effects of pH on sorption mechanisms. Attenuated total reflectance Fourier-transform infrared (ATR FTIR) spectroscopy was employed to obtain vibrational frequencies of the organic ligands on the mineral surfaces and in solution. UV/visible spectroscopy on supernatant solutions was also employed to confirm that adsorption from solution had taken place for benzoic, salicylic and phthalic acids. Molecular orbital calculations were used to model possible surface complexes and interpret the experimental spectra. In general, the tectosilicates, quartz and albite feldspar, did not chemisorb (i.e., strong, inner-sphere adsorption) the carboxylate anions in sufficient amounts to produce infrared spectra of the organics after rinsing in distilled water. The clays (illite, kaolinite and montmorillonite) each exhibited similar ATR FTIR spectra. However, the illite sample used in this study reacted to form strong surface and aqueous complexes with salicylic acid before being treated to remove free Fe-hydroxides. Chemisorption of carboxylic acids onto clays is shown to be limited without the presence of Fe-hydroxides within the clay matrix.

  7. Diffuse Reflectance Spectroscopy of Hidden Objects, Part I: Interpretation of the Reflection-Absorption-Scattering Fractions in Near-Infrared (NIR) Spectra of Polyethylene Films.

    Science.gov (United States)

    Pomerantsev, Alexey L; Rodionova, Oxana Ye; Skvortsov, Alexej N

    2017-08-01

    Investigation of a sample covered by an interfering layer is required in many fields, e.g., for process control, biochemical analysis, and many other applications. This study is based on the analysis of spectra collected by near-infrared (NIR) diffuse reflectance spectroscopy. Each spectrum is a composition of a useful, target spectrum and a spectrum of an interfering layer. To recover the target spectrum, we suggest using a new phenomenological approach, which employs the multivariate curve resolution (MCR) method. In general terms, the problem is very complex. We start with a specific problem of analyzing a system, which consists of several layers of polyethylene (PE) film and underlayer samples with known spectral properties. To separate information originating from PE layers and the target, we modify the system versus both the number of the PE layers as well as the reflectance properties of the target sample. We consider that the interfering spectrum of the layer can be modeled using three components, which can be tentatively called transmission, absorption, and scattering contributions. The novelty of our approach is that we do not remove the reflectance and scattering effects from the spectra, but study them in detail aiming to use this information to recover the target spectrum.

  8. Reflection of slow ions: effect of anisotropy of scattering on energy spectra

    International Nuclear Information System (INIS)

    Vukanic, J.; Simovic, R.

    1997-01-01

    Transport calculations based on linear Boltzmann equation have been carried out analytically for the reflection of low energy light ions from heavy targets. The collision integral of the ion transport equation is replaced by P3 approximation in angle. For power potentials the influence of the anisotropy of scattering on universal path length distribution of reflected particles is investigated. (author)

  9. Application of anti-reflection structures on curved surfaces

    Science.gov (United States)

    Yamamoto, Kazuya; Yamamoto, Takeshi; Takaoka, Toshimitsu; Seigo, Masafumi; Kitagawa, Seiichiro

    2012-02-01

    Conventional lens manufacturing is accomplished by injection molding followed by application of a thin film anti-reflection coating. This requires several production steps, each with the associated constraints. Here we report a technique for production of injection molded lenses with conical sub-wavelength grating anti-reflection structures. While similar structures have been made in the past, our technique allows the sub-wavelength structure to be created on curved surfaces during the injection molding process, reducing the number of steps in the manufacturing process. The advantage of this new technology is that anti-reflection function is created without any additional process(es) conventionally required but by a single injection molding process to make lens normally, through which substantial cost saving will be achieved.

  10. Implementation of solar-reflective surfaces: Materials and utility programs

    Energy Technology Data Exchange (ETDEWEB)

    Bretz, S.; Akbari, H.; Rosenfeld, A.; Taha, H.

    1992-06-01

    This report focuses on implementation issues for using solar-reflective surfaces to cool urban heat islands, with specific examples for Sacramento, California. Advantages of solar-reflective surfaces for reducing energy use are: (1) they are cost-effective if albedo is increased during routine maintenance; (2) the energy savings coincide with peak demand for power; (3) there are positive effects on environmental quality; and (4) the white materials have a long service life. Important considerations when choosing materials for mitigating heat islands are identified as albedo, emissivity, durability, cost, pollution and appearance. There is a potential for increasing urban albedo in Sacramento by an additional 18%. Of residential roofs, we estimate that asphalt shingle and modified bitumen cover the largest area, and that built-up roofing and modified bitumen cover the largest area of commercial buildings. For all of these roof types, albedo may be increased at the time of re-roofing without any additional cost. When a roof is repaired, a solar-reflective roof coating may be applied to significantly increase albedo and extend the life of the root Although a coating may be cost-effective if applied to a new roof following installation or to an older roof following repair, it is not cost-effective if the coating is applied only to save energy. Solar-reflective pavement may be cost-effective if the albedo change is included in the routine resurfacing schedule. Cost-effective options for producing light-colored pavement may include: (1) asphalt concrete, if white aggregate is locally available; (2) concrete overlays; and (3) newly developed white binders and aggregate. Another option may be hot-rolled asphalt, with white chippings. Utilities could promote solar-reflective surfaces through advertisement, educational programs and cost-sharing of road resurfacing.

  11. Near-surface thermal gradients and their effects on mid-infrared emission spectra of planetary surfaces

    Science.gov (United States)

    Henderson, B. G.; Jakosky, B. M.

    1994-01-01

    We model the heat transfer by radiation and conduction in the top few millimeters of a planetary surface to determine the magnitude of near-surface (approximately 100 micrometers) thermal gradients and their effects on mid-infrared emission spectra for a number of planetary environments. The model is one-dimensional and uses a finite difference scheme for approximately 10 micrometers layers. Calculations are peformed for samples heated at the base and from above by sunlight. Our results indicate that near-surface radiative cooling creates significant thermal gradients in the top few hundred microns of surfaces in which radiation is an importamnt heat transfer mechanism. The effect is maximized in evacuated, underdense particulate media with sufficiently high temperatures. Near-surface thermal gradients will be significant in fine-grained particulate surfaces on the Moon (40-60 K/100 micrometers) and Mercury (approximately 80 K/100 micrometers), increasing spectral contrast and creating emission maxima in the transparent regions of the spectra. They will be of lesser importance on the surface of Mars, with a maximum value of around 5 k/100 micrometers in areas of low thermal inertia, and will be negligible on planets with more substantial atmospheres (less than 1 K/100 micrometers). We conclude that the effects that thermal gradients have on mid-IR emission spectra are predictable and do not negate the utility of emission spectroscopy for remote determination of planetary surface composition.

  12. Can a one-layer optical skin model including melanin and inhomogeneously distributed blood explain spatially resolved diffuse reflectance spectra?

    Science.gov (United States)

    Karlsson, Hanna; Pettersson, Anders; Larsson, Marcus; Strömberg, Tomas

    2011-02-01

    Model based analysis of calibrated diffuse reflectance spectroscopy can be used for determining oxygenation and concentration of skin chromophores. This study aimed at assessing the effect of including melanin in addition to hemoglobin (Hb) as chromophores and compensating for inhomogeneously distributed blood (vessel packaging), in a single-layer skin model. Spectra from four humans were collected during different provocations using a twochannel fiber optic probe with source-detector separations 0.4 and 1.2 mm. Absolute calibrated spectra using data from either a single distance or both distances were analyzed using inverse Monte Carlo for light transport and Levenberg-Marquardt for non-linear fitting. The model fitting was excellent using a single distance. However, the estimated model failed to explain spectra from the other distance. The two-distance model did not fit the data well at either distance. Model fitting was significantly improved including melanin and vessel packaging. The most prominent effect when fitting data from the larger separation compared to the smaller separation was a different light scattering decay with wavelength, while the tissue fraction of Hb and saturation were similar. For modeling spectra at both distances, we propose using either a multi-layer skin model or a more advanced model for the scattering phase function.

  13. Microcavity-coupled fiber Bragg grating with tunable reflection spectra and speed of light.

    Science.gov (United States)

    Chen, Lei; Han, Ya; Liu, Qian; Liu, Yan-Ge; Zhang, Weigang; Chou, Keng C

    2018-04-15

    After a fiber Bragg grating (FBG) is fabricated, the reflection spectrum of the FBG is generally not tunable without mechanical deformation or temperature adjustment. Here we present a microcavity-coupled FBG with both a tunable reflection lineshape and dispersion using electromagnetically induced transparency. The Fano interference of light in the FBG and the microcavity allows for dramatic modification of the reflection spectrum. The phase of the reflected spectrum is continuously tunable between 0 and 2π to produce various Fano lineshapes. The dispersion of the output light is adjustable from normal dispersion to abnormal dispersion, consequently providing an adjustable speed of light. Additionally, it allows the FBG to switch from a notch filter to a bandpass filter at the resonant wavelength, which is not possible in a conventional uniform FBG.

  14. Non-invasive identification of metal-oxalate complexes on polychrome artwork surfaces by reflection mid-infrared spectroscopy.

    Science.gov (United States)

    Monico, Letizia; Rosi, Francesca; Miliani, Costanza; Daveri, Alessia; Brunetti, Brunetto G

    2013-12-01

    In this work a reflection mid-infrared spectroscopy study of twelve metal-oxalate complexes, of interest in art conservation science as alteration compounds, was performed. Spectra of the reference materials highlighted the presence of derivative-like and/or inverted features for the fundamental vibrational modes as result of the main contribution from the surface component of the reflected light. In order to provide insights in the interpretation of theses spectral distortions, reflection spectra were compared with conventional transmission ones. The Kramers-Kronig (KK) algorithm, employed to correct for the surface reflection distortions, worked properly only for the derivative-like bands. Therefore, to pay attention to the use of this algorithm when interpreting the reflection spectra is recommended. The outcome of this investigation was exploited to discriminate among different oxalates on thirteen polychrome artworks analyzed in situ by reflection mid-infrared spectroscopy. The visualization of the νs(CO) modes (1400-1200 cm(-1)) and low wavenumber bands (below 900 cm(-1)) in the raw reflection profiles allowed Ca, Cu and Zn oxalates to be identified. Further information about the speciation of different hydration forms of calcium oxalates were obtained by using the KK transform. The work proves reflection mid-infrared spectroscopy to be a reliable and sensitive spectro-analytical method for identifying and mapping different metal-oxalate alteration compounds on the surface of artworks, thus providing conservation scientists with a non-invasive tool to obtain information on the state of conservation and causes of alteration of artworks. Copyright © 2013 Elsevier B.V. All rights reserved.

  15. Collection and corrections of oblique multiangle hyperspectral bidirectional reflectance imagery of the water surface

    Science.gov (United States)

    Bostater, Charles R.; Oney, Taylor S.

    2017-10-01

    Hyperspectral images of coastal waters in urbanized regions were collected from fixed platform locations. Surf zone imagery, images of shallow bays, lagoons and coastal waters are processed to produce bidirectional reflectance factor (BRF) signatures corrected for changing viewing angles. Angular changes as a function of pixel location within a scene are used to estimate changes in pixel size and ground sampling areas. Diffuse calibration targets collected simultaneously from within the image scene provides the necessary information for calculating BRF signatures of the water surface and shorelines. Automated scanning using a pushbroom hyperspectral sensor allows imagery to be collected on the order of one minute or less for different regions of interest. Imagery is then rectified and georeferenced using ground control points within nadir viewing multispectral imagery via image to image registration techniques. This paper demonstrates the above as well as presenting how spectra can be extracted along different directions in the imagery. The extraction of BRF spectra along track lines allows the application of derivative reflectance spectroscopy for estimating chlorophyll-a, dissolved organic matter and suspended matter concentrations at or near the water surface. Imagery is presented demonstrating the techniques to identify subsurface features and targets within the littoral and surf zones.

  16. Saturn's icy satellites investigated by Cassini-VIMS. I. Full-disk properties: 350-5100 nm reflectance spectra and phase curves

    Science.gov (United States)

    Filacchione, G.; Capaccioni, F.; McCord, T.B.; Coradini, A.; Cerroni, P.; Bellucci, G.; Tosi, F.; D'Aversa, E.; Formisano, V.; Brown, R.H.; Baines, K.H.; Bibring, J.-P.; Buratti, B.J.; Clark, R.N.; Combes, M.; Cruikshank, D.P.; Drossart, P.; Jaumann, R.; Langevin, Y.; Matson, D.L.; Mennella, V.; Nelson, R.M.; Nicholson, P.D.; Sicardy, B.; Sotin, Christophe; Hansen, G.; Hibbitts, K.; Showalter, M.; Newman, S.

    2007-01-01

    Saturn's icy satellites are among the main scientific objectives of the Cassini-VIMS (Visual and Infrared Mapping Spectrometer) experiment. This paper contains a first systematic and comparative analysis of the full-disk spectral properties of Dione, Enceladus, Epimetheus, Hyperion, Iapetus, Mimas, Phoebe, Rhea and Tethys as observed by VIMS from July 2004 to June 2005. The disk integrated properties (350-5100 nm reflectance spectra and phase curves at 550-2232 nm) and images of satellites are reported and discussed in detail together with the observed geometry. In general, the spectra in the visible spectral range are almost featureless and can be classified according to the spectral slopes: from the bluish Enceladus and Phoebe to the redder Iapetus, Hyperion and Epimetheus. In the 1000-1300 nm range the spectra of Enceladus, Tethys, Mimas and Rhea are characterized by a negative slope, consistent with a surface largely dominated by water ice, while the spectra of Iapetus, Hyperion and Phoebe show a considerable reddening pointing out the relevant role played by darkening materials present on the surface. In between these two classes are Dione and Epimetheus, which have a flat spectrum in this range. The main absorption bands identified in the infrared are the 1520, 2020, 3000 nm H2O/OH bands (for all satellites), although Iapetus dark terrains show mostly a deep 3000 nm band while the 1520 and 2020 nm bands are very faint. In this spectral range, the Iapetus spectrum is characterized by a strong reddening. The CO2 band at 4260 nm and the Fresnel ice peak around 3100 nm are evident only on Hyperion, Phoebe and Iapetus. The phase curves at 550 and at 2232 nm are reported for all the available observations in the 0??-144?? range; Rhea shows an opposition surge at visible wavelengths in the 0.5??-1.17?? interval. The improvement on the retrieval of the full-disk reflectance spectra can be appreciated by a direct comparison with ground-based telescopic data available

  17. First Derivative UV Spectra of Surface Water as a Monitor of Chlorination in Drinking Water Treatment

    Directory of Open Access Journals (Sweden)

    V. Zitko

    2001-01-01

    Full Text Available Many countries require the presence of free chlorine at about 0.1 mg/l in their drinking water supplies. For various reasons, such as cast-iron pipes or long residence times in the distribution system, free chlorine may decrease below detection limits. In such cases it is important to know whether or not the water was chlorinated or if nonchlorinated water entered the system by accident. Changes in UV spectra of natural organic matter in lakewater were used to assess qualitatively the degree of chlorination in the treatment to produce drinking water. The changes were more obvious in the first derivative spectra. In lakewater, the derivative spectra have a maximum at about 280 nm. This maximum shifts to longer wavelengths by up to 10 nm, decreases, and eventually disappears with an increasing dose of chlorine. The water treatment system was monitored by this technique for over 1 year and changes in the UV spectra of water samples were compared with experimental samples treated with known amounts of chlorine. The changes of the UV spectra with the concentration of added chlorine are presented. On several occasions, water, which received very little or no chlorination, may have entered the drinking water system. The results show that first derivative spectra are potentially a tool to determine, in the absence of residual chlorine, whether or not surface water was chlorinated during the treatment to produce potable water.

  18. Infrared reflection spectra of multilayer epitaxial heterostructures with embedded InAs and GaAs layers

    International Nuclear Information System (INIS)

    Seredin, P. V.; Domashevskaya, E. P.; Lukin, A. N.; Arsent'ev, I. N.; Vinokurov, D. A.; Tarasov, I. S.

    2008-01-01

    The effect of the thickness of embedded InAs and GaAs layers on the infrared reflection spectra of lattice vibrations for AlInAs/InAs/AlInAs, InGaAs/GaAs/InGaAs, and AlInAs/InGaAs/GaAs/InGaAs/AlInAs multilayer epitaxial heterostructures grown by MOC hydride epitaxy on InP (100) substrates is studied. Relative stresses emerging in the layers surrounding the embedded layers with variation in the number of monolayers from which the quantum dots are formed and with variation the thickness of the layers themselves surrounding the embedded layers are evaluated.

  19. Subsurface irradiance reflectance spectra of inland waters differing in morphometry and hydrology

    NARCIS (Netherlands)

    Rijkeboer, M.; Dekker, A.; Gons, H.J.

    1998-01-01

    A database has been established for relating subsurface irradiance reflectance, i.e. water ’colour‘, to the optical properties and water quality parameters of more than 120 Dutch inland water bodies. The concentrations of total chlorophyll-a (TChl-a = chlorophyll-a plus phaeopigment), total

  20. Interaction of mineral surfaces with simple organic molecules by diffuse reflectance IR spectroscopy (DRIFT)

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, Joan E.; Kelley, Michael J.

    2008-06-01

    Diffuse reflectance Fourier-transform infrared spectroscopy (DRIFTS) was used to characterize multi-layers of lysine, glutamic acid and salicylic acid on -alumina and kaolinite surfaces. The results agreed well with those previously obtained by ATR-IR in aqueous media where available, indicating that DRIFT may be regarded as effectively an in-situ spectroscopy for these materials. In the case of salicylic acid adsorption onto γ-alumina, DRIFTS was used to identify monolayer coverage and to detect molecules down to coverage of 3% of a monolayer. The spectroscopic results as to coverage were confirmed by analysis of the solutions used for treatment. The spectra obtained allowed identification of changes in the bonding environment with increasing surface coverage. DRIFTS, offers several advantages in terms of materials, experimental technique and data treatment, motivating further investigations.

  1. Near Surface Seismic Reflection Imaging: Great Potential Under Critical Eye

    Science.gov (United States)

    Miller, R. D.; Peterie, S.; Judy, B. E.

    2014-12-01

    Seismic-reflection imaging has long been a mainstay in the oil and gas exploration community with mind boggling advancements in just the last decade, but its application to engineering, environmental, and groundwater problems has not seen the same level of utilization. A great deal of the problem lies in the many assumptions that are valid for deep exploration that are violated in the very complex near surface. Large channel systems with acquisition geometries conducive for both deep and shallow targets are many times assumed to be capable of extending the imaging depth window. In reality, constraints of the source and sensor/recording systems must be considered, where large powerful sources are needed to image exploration depths while low-energy, high-frequency sources are required for the shallow and thin targets in the near surface. Attempts to make one size fit all will result in artifacts that result in bogus images and characterizations in the shallow subsurface.Narrow optimum offsets, highly attenuative materials, extreme velocity variability, wavefield interference, and low signal-to-noise ratios provide an ideal breeding ground for the generation of artifacts on near-surface seismic-reflection data. With the cost of shallow reflection data being so high relative to other geophysical methods and invasive sampling, sometimes a single failure can hinder the growth in the use of the method. The method is extremely powerful and has the potential to provide vast quantities of information critical to understand the distributed hydrogeological and biogeochemical processes that elude borehole investigations. It is imperative that data be acquired in its rawest possible form and be processed with an eye to each operation. Cost savings sometimes result in one-size-fits-all acquisition and automated processing flows. Attention to detail and following signal from origination to characterization is essential.

  2. Study on the Reflection Spectra of One Dimensional Plasma Photonic Crystals Having Exponentially Graded Materials

    International Nuclear Information System (INIS)

    Prasad, S.; Singh, Vivek; Singh, A. K.

    2013-01-01

    The transfer matrix method is used to study the effect of the permittivity profile on the reflectivity of a one dimensional plasma photonic crystal having exponentially graded material. The analysis shows that the proposed structure works as a perfect mirror within a certain frequency range. These frequency ranges can be completely controlled by the permittivity profile of a graded dielectric layer. As expected we observed that these frequency ranges are also controlled by plasma parameters. (plasma technology)

  3. First-Order Parametric Model of Reflectance Spectra for Dyed Fabrics

    Science.gov (United States)

    2016-02-19

    diffuse reflectance for the purpose of simulating the spectral response of military textiles containing different types and concentrations of near...which provides for both their inverse and direct modeling1. The dyes considered contain spectral features that are of interest to the U.S. Navy for...can be in terms of formulations based on the Beer -Lambert Law or its approximation, which is adopted for the parametric model considered here [8,9

  4. Clinical system model for monitoring the physiological status of jaundice by extracting bilirubin components from skin diffuse reflectance spectra

    Science.gov (United States)

    Kumar, Alla S.; Clark, Joseph; Beyette, Fred R., Jr.

    2009-02-01

    Neonatal jaundice is a medical condition which occurs in newborns as a result of an imbalance between the production and elimination of bilirubin. The excess bilirubin in the blood stream diffuses into the surrounding tissue leading to a yellowing of the skin. As the bilirubin levels rise in the blood stream, there is a continuous exchange between the extra vascular bilirubin and bilirubin in the blood stream. Exposure to phototherapy alters the concentration of bilirubin in the vascular and extra vascular regions by causing bilirubin in the skin layers to be broken down. Thus, the relative concentration of extra vascular bilirubin is reduced leading to a diffusion of bilirubin out of the vascular region. Diffuse reflectance spectra from human skin contains physiological and structural information of the skin and nearby tissue. A diffuse reflectance spectrum must be captured before and after blanching in order to isolate the intravascular and extra vascular bilirubin. A new mathematical model is proposed with extra vascular bilirubin concentration taken into consideration along with other optical parameters in defining the diffuse reflectance spectrum from human skin. A nonlinear optimization algorithm has been adopted to extract the optical properties (including bilirubin concentration) from the skin reflectance spectrum. The new system model and nonlinear algorithm have been combined to enable extraction of Bilirubin concentrations within an average error of 10%.

  5. Method for determining the optical constants of thin dielectric films with variable thickness using only their shrunk reflection spectra

    International Nuclear Information System (INIS)

    Ruiz-Perez, J.J.; Gonzalez-Leal, J.M.; Marquez, E.; Minkov, D.A.

    2001-01-01

    Thickness inhomogeneities in thin films have a large influence on their optical transmission and reflection spectra. If not taken into account, this may lead to rather large calculated values for the absorption coefficient or the erroneous presence of an absorption-band tail, as well as to significant errors in the calculated values of the refractive index and the film thickness. The effect of thickness variation on the optical reflection spectrum of a thin dielectric film covering a thick non-absorbing substrate, is analysed in detail in this paper, and analytical expressions are presented for such a reflection spectrum and its upper and lower envelopes. A method is suggested for determining the refractive index n(λ) and the extinction coefficient k(λ), as well as the average thickness and the thickness variation, of a thin dielectric film with variable thickness, by using only the two envelopes of the corresponding shrunk reflection spectrum. This method is used for the geometrical and optical characterization of thermally-evaporated amorphous chalcogenide films, deposited on glass substrates. (author)

  6. Mineralogy and chemistry of Ti-bearing lunar soils: Effects on reflectance spectra and remote sensing observations

    Science.gov (United States)

    Coman, Ecaterina O.; Jolliff, Bradley L.; Carpenter, Paul

    2018-05-01

    This paper presents results of coordinated ultraviolet and visible wavelength reflectance measurements, X-ray diffraction analyses of mineral components, and micro X-ray fluorescence analyses of Ti concentrations of 13 lunar soil samples (remote sensing observations of the Moon and other airless bodies. We find that measured ilmenite weight percent correlates highly with measured TiO2 concentrations. Thus, the ilmenite content is a good predictor of TiO2 concentration. Ilmenite is the main contributor of TiO2 for soils with greater than about 2 wt.% TiO2, so we take the effects of TiO2 on reflectance spectra to be essentially those of ilmenite. Constraining the data set to eight mature Apollo soils, we find that among the UV/VIS ratios from laboratory-measured spectra, the 321/415 nm ratio shows the best correlation with TiO2 and ilmenite. Moreover, for soils with similar maturity in the submature to mature range, those with higher TiO2 have higher 321/415 UV/VIS ratios. Finally, the correlation between TiO2 content and 321/415 ratio in samples measured in the lab appears weaker than for the same relationship using the Lunar Reconnaissance Orbiter (LRO) Wide Angle Camera (WAC) spectral data for the 321/415 ratio of Apollo ground-truth sites. The correlation between lab-derived 321/415 ratios and TiO2 content for measured samples improves when low-maturity samples are excluded from the dataset, implying that the LROC WAC spectra at 400 m/pix spatial resolution senses mostly mature soil.

  7. Integrating in situ reef-top reflectance spectra with Landsat TM imagery to aid shallow-tropical benthic habitat mapping

    NARCIS (Netherlands)

    Purkis, S.J.; Pasterkamp, R.

    2004-01-01

    This manuscript presents the use of hyperspectral in situ reflectance measurements evaluated above the water surface to train a supervised classification of a simultaneously acquired Landsat 5 TM image. The optical signature of a submerged reef substrate is both attenuated and augmented by the

  8. Numerical simulation of the forbidden Bragg reflection spectra observed in ZnO

    Science.gov (United States)

    Ovchinnikova, E. N.; Dmitrienko, V. E.; Oreshko, A. P.; Beutier, G.; Collins, S. P.

    2010-09-01

    Thermal motion induced (TMI) scattering is a unique probe of changes in electronic states with atomic displacements in crystals. We show that it provides a novel approach to extract atomic correlation functions. Using numerical calculations, we are able to reproduce the temperature-dependent energy spectrum of the 115 'forbidden' Bragg reflection in ZnO. Our previous experimental studies showed that the intensity growth of such reflections over a wide range of temperatures is accompanied by a dramatic change in the resonant spectral lineshape. This is the result of the interplay between the temperature-independent (TI) and temperature-dependent TMI contributions. Here, we confirm that the TI part of the resonant structure factor can be associated with the dipole-quadrupole contribution to the structure factor and show that the temperature-dependent part arises from the zinc and oxygen vibrations, which provide additional temperature-dependent dipole-dipole tensor components to the structure factor. By fitting the experimental data at various temperatures we have determined the temperature dependences of autocorrelation langux2(Zn)rang and correlation langux(O)ux(Zn)rang functions.

  9. Defects in UV-vis-NIR reflectance spectra as method for forgery detections in writing documents

    Energy Technology Data Exchange (ETDEWEB)

    Somma, F; Aloe, P; Schirripa Spagnolo, G

    2010-11-01

    Documents have taken up a very important place in our society. Frauds committed in connection with documents are not at all uncommon, and, in fact, represent a very large domain of the forensic science called 'questioned documents'. In the field of forensic examination of questioned documents, the legitimacy of an ink entry is often an essential question. A common type of forgery consists in materially altering an existing writing or adding a new writing. These changes can be characterized by means of optical spectroscopy. The aim of this work is to perform the UV-vis-NIR reflectance spectrophotometry to analyze a range of blue and black commercial ballpoint pens, in order to investigate the discriminating abilities of the different inks found on the same document.

  10. Scaling of turbulence spectra measured in strong shear flow near the Earth’s surface

    Science.gov (United States)

    Mikkelsen, T.; Larsen, S. E.; Jørgensen, H. E.; Astrup, P.; Larsén, X. G.

    2017-12-01

    Within the lowest kilometer of the Earth’s atmosphere, in the so-called atmospheric boundary layer, winds are often gusty and turbulent. Nearest to the ground, the turbulence is predominately generated by mechanical wall-bounded wind shear, whereas at higher altitudes turbulent mixing of heat and moisture also play a role. The variance (square of the standard deviation) of the fluctuation around the mean wind speed is a measure of the kinetic energy content of the turbulence. This kinetic energy can be resolved into the spectral distributions, or spectra, as functions of eddy size, wavenumber, or frequency. Spectra are derived from Fourier transforms of wind records as functions of space or time corresponding to wavenumber and frequency spectra, respectively. Atmospheric spectra often exhibit different subranges that can be distinguished and scaled by the physical parameters responsible for: (1) their generation; (2) the cascade of energy across the spectrum from large- to small-scale; and (3) the eventual decay of turbulence into heat owing to viscosity effects on the Kolmogorov microscale, in which the eddy size is only a fraction of a millimeter. This paper addresses atmospheric turbulence spectra in the lowest part of the atmospheric boundary layer—the so-called surface layer—where the wind shear is strong owing to the nonslip condition at the ground. Theoretical results dating back to Tchen’s early work in 1953 ‘on the spectrum of energy in turbulent shear flow’ led Tchen to predict a shear production subrange with a distinct inverse-linear power law for turbulence in a strongly sheared high-Reynolds number wall-bounded flow, as is encountered in the lowest sheared part of the atmospheric boundary layer, also known as the eddy surface layer. This paper presents observations of spectra measured in a meteorological mast at Høvsøre, Denmark, that support Tchen’s prediction of a shear production subrange following a distinct power law of degree

  11. Monte Carlo simulation of light reflection from cosmetic powder particles near the human skin surface.

    Science.gov (United States)

    Okamoto, Takashi; Kumagawa, Tatsuya; Motoda, Masafumi; Igarashi, Takanori; Nakao, Keisuke

    2013-06-01

    The reflection and scattering properties of light incident on human skin covered with powder particles have been investigated. A three-layer skin structure with a pigmented area is modeled, and the propagation of light in the skin's layers and in a layer of particles near the skin's surface is simulated using the Monte Carlo method. Assuming that only single scattering of light occurs in the powder layer, the simulation results show that the reflection spectra of light from the skin change with the size of powder particles. The color difference between normal and discolored skin is found to decrease considerably when powder particles with a diameter of approximately 0.25 μm are present near the skin's surface. The effects of the medium surrounding the particles, and the influence of the distribution of particle size (polydispersity), are also examined. It is shown that a surrounding medium with a refractive index close to that of the skin substantially suppresses the extreme spectral changes caused by the powder particles covering the skin surface.

  12. An algorithm for hyperspectral remote sensing of aerosols: 2. Information content analysis for aerosol parameters and principal components of surface spectra

    Science.gov (United States)

    Hou, Weizhen; Wang, Jun; Xu, Xiaoguang; Reid, Jeffrey S.

    2017-05-01

    This paper describes the second part of a series of investigation to develop algorithms for simultaneous retrieval of aerosol parameters and surface reflectance from the future hyperspectral and geostationary satellite sensors such as Tropospheric Emissions: Monitoring of POllution (TEMPO). The information content in these hyperspectral measurements is analyzed for 6 principal components (PCs) of surface spectra and a total of 14 aerosol parameters that describe the columnar aerosol volume Vtotal, fine-mode aerosol volume fraction, and the size distribution and wavelength-dependent index of refraction in both coarse and fine mode aerosols. Forward simulations of atmospheric radiative transfer are conducted for 5 surface types (green vegetation, bare soil, rangeland, concrete and mixed surface case) and a wide range of aerosol mixtures. It is shown that the PCs of surface spectra in the atmospheric window channel could be derived from the top-of-the-atmosphere reflectance in the conditions of low aerosol optical depth (AOD ≤ 0.2 at 550 nm), with a relative error of 1%. With degree freedom for signal analysis and the sequential forward selection method, the common bands for different aerosol mixture types and surface types can be selected for aerosol retrieval. The first 20% of our selected bands accounts for more than 90% of information content for aerosols, and only 4 PCs are needed to reconstruct surface reflectance. However, the information content in these common bands from each TEMPO individual observation is insufficient for the simultaneous retrieval of surface's PC weight coefficients and multiple aerosol parameters (other than Vtotal). In contrast, with multiple observations for the same location from TEMPO in multiple consecutive days, 1-3 additional aerosol parameters could be retrieved. Consequently, a self-adjustable aerosol retrieval algorithm to account for surface types, AOD conditions, and multiple-consecutive observations is recommended to derive

  13. LO-TO splittings, effective charges and interactions in electro-optic meta-nitroaniline crystal as studied by polarized IR reflection and transmission spectra

    Science.gov (United States)

    Szostak, M. M.; Le Calvé, N.; Romain, F.; Pasquier, B.

    1994-10-01

    The polarized IR reflection spectra of the meta-nitroaniline ( m-NA) single crystal along the a, b and c crystallographic axes as well as the b and c polarized transmission spectra have been measured in the 100-400 cm -1 region. The LO-TO splitting values have been calculated from the reflection spectra by fitting them with the four parameter dielectric function. The dipole moment derivatives, relevant to dynamic effective charges, of the vibrations have also been calculated and used to check the applicability of the oriented gas model (OGM) to reflection spectra. The discrepancies from the OGM have been discussed in terms of vibronic couplings, weak hydrogen bondings (HB) and intramolecular charge transfer.

  14. Calcium pyroxenes at Mercurian surface temperatures: investigation of in-situ emissivity spectra and thermal expansion

    Science.gov (United States)

    Ferrari, S.; Nestola, F.; Helbert, J.; Maturilli, A.; D'Amore, M.; Alvaro, M.; Domeneghetti, M.; Massironi, M.; Hiesinger, H.

    2013-12-01

    The European Space Agency and Japan Aerospace Agency mission to Mercury, named BepiColombo, will carry on board the Mercury Radiometer and Thermal Infrared Spectrometer (MERTIS) that will be able to provide surface Thermal Infra-Red (TIR) emissivity spectra from 7 to 14 μm. This range of wavelengths is very useful to identify the fine-scale structural properties of several silicates. For mineral families as pyroxenes, the emissivity peak positions are good indicators of the composition. A complication in the interpretation of MERTIS data could arise from the extreme daily surface temperature range of Mercury (70 to 725 K) that significantly affects the crystal structure and density of minerals and consequently should affect the TIR spectral signature of each single mineral present on the surface of the planet. In preparation for the MERTIS data analysis, we are extensively investigating at high temperatures conditions several mineral phases potentially detectable on the surface of Mercury. Two C2/c augitic pyroxenes, with constant calcium content and very different magnesium to iron ratio, were studied by in situ high-temperature thermal infrared spectroscopy (up to 750 K) and in situ high-temperature single-crystal X-ray diffraction (up to 770 K). The emissivity spectra of the two samples show similar band center shifts of the main three bands toward lower wavenumbers with increasing temperature. Our results indicate that the center position of bands 1 and 2 is strictly dependent on temperature, whereas the center position of band 3 is a strong function of the composition regardless the temperature. These data suggest that MERTIS spectra will be able to provide indications of C2/c augitic pyroxene with different magnesium contents and will allow a correct interpretation independently on the spectra acquisition temperature.

  15. Drop entrainment from the surface of oil mist filters: mechanisms, kinetics, and drop spectra

    OpenAIRE

    Wurster, S.; Kolb, H.; Meyer, J.; Kasper, G.

    2016-01-01

    Oil entrainment from coalescence filters has been characterized by different techniques. Drop spectra and entrainment rates were measured by a combination of techniques from 1 mm over long periods of time. Dominant entrainment mechanism(s) are identified on the basis of comparisons of entrainment rates measured in different regions of the filter surface with rates of air bubble formation, measurements of oil film thickness, as well as visual observations. Experiments are supported by force es...

  16. Energy spectra and charge states of light atoms scattered by solid surface

    International Nuclear Information System (INIS)

    Parilis, E.S.; Verleger, V.K.

    1980-01-01

    The theories of backscattering and charge state formation of light atoms (H, D, and He) for the energy range 1 keV 0 0 and theta. The dependence of epsilonsub(max) on theta determines the mean effective range for the scattering at the angle theta. The appearance of surface peaks in the energy spectra of neutrals below energy E 0 + , Hsup(*), and H - . (orig.)

  17. Determination of stress glut moments of total degree 2 from teleseismic surface wave amplitude spectra

    Science.gov (United States)

    Bukchin, B. G.

    1995-08-01

    A special case of the seismic source, where the stress glut tensor can be expressed as a product of a uniform moment tensor and a scalar function of spatial coordinates and time, is considered. For such a source, a technique of determining stress glut moments of total degree 2 from surface wave amplitude spectra is described. The results of application of this technique for the estimation of spatio-temporal characteristics of the Georgian earthquake, 29.04.91 are presented.

  18. Volume and surface photoemission from tungsten. I. Calculation of band structure and emission spectra

    DEFF Research Database (Denmark)

    Christensen, N. Egede; Feuerbacher, B.

    1974-01-01

    of photoemission spectra from W single crystals. The nondirect as well as the direct models for bulk photoemission processes are investigated. The emission from the three low-index surfaces (100), (110), and (111) exhibits strong dependence on direction and acceptance cone. According to the present band model...... there should essentially be no emission normal to the (110) face for photon energies between 9.4 and 10.6 eV. Experimental observation of emission in this gap, however, implies effects not included in the simple bulk models. In particular, effects arising from surface emission have been considered, i.......e., emission of those electrons which are excited in a single-step process from initial states near the surface to final states outside the crystal. The electrons that are emitted from the surface in directions perpendicular to the crystal planes carry information on the one-dimensional surface density...

  19. Attenuated total reflectance spectroscopy of coumarin organosilane molecules adsorbed on a fused silica surface

    International Nuclear Information System (INIS)

    Bratescu, Maria Antoaneta; Saito, Nagahiro; Takai, Osamu

    2010-01-01

    Attenuated total reflectance (ATR) spectroscopy was used to investigate the adsorption of coumarin organosilane molecules onto a fused silica surface. The difference between the absorption spectra of the molecules on the surface and in solution was explained by the interaction of the adsorbed coumarin organosilane molecules with the hydroxyl groups on the fused silica surface. This interaction produces a perturbation of the π electron distribution and the electronic transitions of the coumarin chromophore of the organosilane molecules adsorbed on the surface. From the kinetics adsorption curves, the calculated enthalpy values of 74.8 ± 5.2 kJ mol -1 and free energy of -38.22 ± 0.70 kJ mol -1 at 23 deg. C indicates a chemisorption process. The high sensitivity of ATR spectroscopy allows the detection of a monolayer formed by a 10 nM concentration of coumarin organosilane molecules, which covers more than half of the maximum surface coverage at 60 deg. C.

  20. Interferometry of a reflective axicon surface with a small cone angle using an optical inner surface

    Science.gov (United States)

    Gao, Huimin; Zhang, Xiaodong; Fang, Fengzhou

    2017-09-01

    Reflective axicons, widely used in optical alignment and Bessel-Gauss beam generation, require a highly accurate cone angle and surface metrology. However, current methods focus on the cone angle measurement and it is still difficult to measure the surface of a reflective axicon with a small cone angle. An interferometer measurement method using an optical inner surface is proposed to obtain the surface and cone angle simultaneously. The optical axis of the axicon and the optical inner surface should align together and be parallel to the beam light from the interferometer. The interference fringe would be obtained by the optical system consisting of the axicon and the optical inner surface. The theoretical model is established and analyzed through ray tracing theory, and is verified by optical simulation software. Fabrication errors in the axicon and the inner surface, and misalignment of the measurement setup are investigated systematically and separated in the measurement process. In the experiments, the reflective axicon with a cone angle of about 90° was measured by the proposed method, the results of which show good agreement with a stylus profiler (Taylor-Hobson PGI 3D) in cone angle trend and generatrix error. Experimental results prove the feasibility of the proposed method. This economical and effective method can be widely used with all types of reflective axicons, and it can obtain the surface error map of the axicon as well as the inner cylinder at the same time. The uncertainty and resolution of the proposed method is based on the performance of the interferometer. The uncertainty of alignment angle errors is less than 10-10 rad; the lateral resolution is 53.8 µm.

  1. Interferometry of a reflective axicon surface with a small cone angle using an optical inner surface

    International Nuclear Information System (INIS)

    Gao, Huimin; Zhang, Xiaodong; Fang, Fengzhou

    2017-01-01

    Reflective axicons, widely used in optical alignment and Bessel–Gauss beam generation, require a highly accurate cone angle and surface metrology. However, current methods focus on the cone angle measurement and it is still difficult to measure the surface of a reflective axicon with a small cone angle. An interferometer measurement method using an optical inner surface is proposed to obtain the surface and cone angle simultaneously. The optical axis of the axicon and the optical inner surface should align together and be parallel to the beam light from the interferometer. The interference fringe would be obtained by the optical system consisting of the axicon and the optical inner surface. The theoretical model is established and analyzed through ray tracing theory, and is verified by optical simulation software. Fabrication errors in the axicon and the inner surface, and misalignment of the measurement setup are investigated systematically and separated in the measurement process. In the experiments, the reflective axicon with a cone angle of about 90° was measured by the proposed method, the results of which show good agreement with a stylus profiler (Taylor-Hobson PGI 3D) in cone angle trend and generatrix error. Experimental results prove the feasibility of the proposed method. This economical and effective method can be widely used with all types of reflective axicons, and it can obtain the surface error map of the axicon as well as the inner cylinder at the same time. The uncertainty and resolution of the proposed method is based on the performance of the interferometer. The uncertainty of alignment angle errors is less than 10 −10 rad; the lateral resolution is 53.8 µ m. (paper)

  2. MODIS/Terra Surface Reflectance 8-Day L3 Global 250m SIN Grid V005

    Data.gov (United States)

    National Aeronautics and Space Administration — The MODIS Surface Reflectance products provide an estimate of the surface spectral reflectance as it would be measured at ground level in the absence of atmospheric...

  3. MODIS/Terra Surface Reflectance 8-Day L3 Global 500m SIN Grid V005

    Data.gov (United States)

    National Aeronautics and Space Administration — The MODIS Surface Reflectance products provide an estimate of the surface spectral reflectance as it would be measured at ground level in the absence of atmospheric...

  4. MODIS/Terra Surface Reflectance Daily L2G Global 250m SIN Grid V005

    Data.gov (United States)

    National Aeronautics and Space Administration — The MODIS Surface Reflectance products provide an estimate of the surface spectral reflectance as it would be measured at ground level in the absence of atmospheric...

  5. Changes in Attenuated Total Reflection Fourier Transform Infrared Spectra as Blood Dries Out.

    Science.gov (United States)

    Zhang, Yinming; Wang, Qi; Li, Bing; Wang, Zhijun; Li, Chengzhi; Yao, Yao; Huang, Ping; Wang, Zhenyuan

    2017-05-01

    The time since deposition (TSD) of a bloodstain is a valuable piece of evidence for forensic scientists to determine the time at which a crime took place. The objective of this study was to determine whether attenuated total reflection (ATR) Fourier transform infrared (FTIR) spectroscopy could be used to estimate the TSD of a bloodstain in a relatively early period (from 0 min to the time required for the bloodstain to dry out). For this purpose, we used ATR-FTIR to study the variation in absorbance at certain wavelengths as rat and human blood sample dried out. The absorbance at 3308/cm (A3308) was found to have a close correlation with the TSD during this time period, and the changes in A3308 during the drying of rat and human blood drops under the same controlled conditions showed similar results. The current study indicates that ATR-FTIR spectroscopy has potential as a tool for estimating TSD at early time periods of blood deposition. © 2016 American Academy of Forensic Sciences.

  6. Influence of the projectile charge state on electron emission spectra from a Cu(111) surface

    Science.gov (United States)

    Archubi, C. D.; Silkin, V. M.; Gravielle, M. S.

    2015-09-01

    Double differential electron emission distributions produced by grazing impact of fast dressed ions on a Cu(111) surface are investigated focusing on the effects of the electronic band structure. The process is described within the Band-Structure-Based approximation, which is a perturbative method that includes an accurate representation of the electron-surface interaction, incorporating information of the electronic band structure of the solid. Differences in the behavior of the emission spectra for He+ q, Li+ q, Be+ q and C+ q projectiles with different charge states q are explained by the combined effect of the projectile trajectory and the projectile charge distribution.

  7. Viscoelasticity evaluation of rubber by surface reflection of supersonic wave.

    Science.gov (United States)

    Omata, Nobuaki; Suga, Takahiro; Furusawa, Hirokazu; Urabe, Shinichi; Kondo, Takeru; Ni, Qing-Qing

    2006-12-22

    The main characteristic of rubber is a viscoelasticity. So it is important to research the characteristic of the viscoelasticity of the high frequency band for the friction between a rubber material and the hard one with roughness, for instance, the tire and the road. As for the measurement of the viscoelasticity of rubber, DMA (dynamic mechanical analysis) is general. However, some problems are pointed out to the measurement of the high frequency band by DMA. Then, we evaluated the viscoelasticity characteristic by the supersonic wave measurement. However, attenuation of rubber is large, and when the viscoelasticity is measured by the supersonic wave therefore, it is inconvenient and limited in a past method by means of bottom reflection. In this report, we tried the viscoelasticity evaluation by the method of using complex surface reflection coefficient and we compared with the friction coefficient under wide-range friction velocity. As a result, some relationships had been found for two properties. We report the result that character of viscoelasticity of rubber was comparable to friction coefficient.

  8. Mars analog minerals' spectral reflectance characteristics under Martian surface conditions

    Science.gov (United States)

    Poitras, J. T.; Cloutis, E. A.; Salvatore, M. R.; Mertzman, S. A.; Applin, D. M.; Mann, P.

    2018-05-01

    We investigated the spectral reflectance properties of minerals under a simulated Martian environment. Twenty-eight different hydrated or hydroxylated phases of carbonates, sulfates, and silica minerals were selected based on past detection on Mars through spectral remote sensing data. Samples were ground and dry sieved to Mars, only losing adsorbed H2O while maintaining their diagnostic spectral features. Sulfates were less stable, often with shifts in the band position of the SO, Fe, and OH absorption features. Silicas displayed spectral shifts related to SiOH and hydration state of the mineral surface, while diagnostic bands for quartz were stable. Previous detection of carbonate minerals based on 2.3-2.5 μm and 3.4-3.9 μm features appears to be consistent with our results. Sulfate mineral detection is more questionable since there can be shifts in band position related to SO4. The loss of the 0.43 μm Fe3+ band in many of the sulfates indicate that there are fewer potential candidates for Fe3+ sulfates to permanently exist on the Martian surface based on this band. The gypsum sample changed phase to basanite during desiccation as demonstrated by both reflectance and XRD. Silica on Mars has been detected using band depth ratio at 1.91 and 1.96 μm and band minimum position of the 1.4 μm feature, and the properties are also used to determine their age. This technique continues to be useful for positive silica identifications, however, silica age appears to be less consistent with our laboratory data. These results will be useful in spectral libraries for characterizing Martian remote sensed data.

  9. X-Ray Reflectivity from the Surface of a Liquid Crystal:

    DEFF Research Database (Denmark)

    Pershan, P.S.; Als-Nielsen, Jens Aage

    1984-01-01

    X-ray reflectivity from the surface of a nematic liquid crystal is interpreted as the coherent superposition of Fresnel reflection from the surface and Bragg reflection from smectic order induced by the surface. Angular dependence of the Fresnel effect yields information on surface structure....... Measurement of the intensity of diffuse critical scattering relative to the Fresnel reflection yields the absolute value of the critical part of the density-density correlation function....

  10. Impact of Sulfur Hazes on the Reflected Light Spectra of Giant Exoplanets

    Science.gov (United States)

    Gao, Peter; Marley, Mark S.; Zahnle, Kevin; Robinson, Tyler D.; Lewis, Nikole K.

    2017-01-01

    Recent work has shown that photochemical hazes composed of elemental sulfur and its allotropes may arise in the atmospheres of warm and temperate giant exoplanets due to the photolysis of H2S. We investigate the impact such a haze would have on an exoplanet's geometric albedo spectrum using a suite of established radiative-convective, cloud, and albedo models, and how this may impact future direct imaging missions, such as WFIRST. For Jupiter-massed planets, photochemical destruction of H2S results in the production of ~1 ppmv of S8 between 100 and 0.1 mbar. The S8 mixing ratio is largely independent of the stellar UV flux, vertical mixing rates, and atmospheric temperature for expected ranges of those values, such that the S8 haze mass is dependent only on the S8 supersaturation, controlled by the local temperature. Nominal haze masses are found to drastically alter a planet's geometric albedo spectrum: whereas a clear atmosphere is dark at wavelengths between 0.5 and 1 μm due to molecular absorption, the addition of a sulfur haze boosts the albedo there to ~0.7 due to its purely scattering nature. Strong absorption by the haze shortward of 0.4 μm results in albedos Jupiter-like planets. For this reason colors are unlikely to provide definitive identification of warm Jupiter-like planets. The albedo change due to a sulfur haze is largely independent of the location of the haze in the atmosphere, but is a strong function of the haze optical depth as controlled by its column number density and mean particle size, though the absorption feature at short wavelengths remains robust. Detection of such a haze by future direct imaging missions like WFIRST is possible, though discriminating between a sulfur haze and any other reflective material, such as water ice, will require observations shortward of 0.4 μm, which is currently beyond WFIRST's grasp.

  11. Sulfur Hazes in Giant Exoplanet Atmospheres: Impacts on Reflected Light Spectra

    Energy Technology Data Exchange (ETDEWEB)

    Gao, Peter; Marley, Mark S.; Zahnle, Kevin [NASA Ames Research Center, Moffett Field, CA 94035 (United States); Robinson, Tyler D. [Department of Astronomy and Astrophysics, University of California, Santa Cruz, Santa Cruz, CA 95064 (United States); Lewis, Nikole K., E-mail: pgao@caltech.edu [Space Telescope Science Institute, Baltimore, MD 21218 (United States)

    2017-03-01

    Recent work has shown that sulfur hazes may arise in the atmospheres of some giant exoplanets, due to the photolysis of H{sub 2}S. We investigate the impact such a haze would have on an exoplanet’s geometric albedo spectrum and how it may affect the direct imaging results of the Wide Field Infrared Survey Telescope ( WFIRST ), a planned NASA space telescope. For temperate (250 K <  T {sub eq} < 700 K) Jupiter-mass planets, photochemical destruction of H{sub 2}S results in the production of ∼1 ppmv of S{sub 8} between 100 and 0.1 mbar, which, if cool enough, will condense to form a haze. Nominal haze masses are found to drastically alter a planet’s geometric albedo spectrum: whereas a clear atmosphere is dark at wavelengths between 0.5 and 1 μ m, due to molecular absorption, the addition of a sulfur haze boosts the albedo there to ∼0.7, due to scattering. Strong absorption by the haze shortward of 0.4 μ m results in albedos <0.1, in contrast to the high albedos produced by Rayleigh scattering in a clear atmosphere. As a result, the color of the planet shifts from blue to orange. The existence of a sulfur haze masks the molecular signatures of methane and water, thereby complicating the characterization of atmospheric composition. Detection of such a haze by WFIRST is possible, though discriminating between a sulfur haze and any other highly reflective, high-altitude scatterer will require observations shortward of 0.4 μ m, which is currently beyond WFIRST ’s design.

  12. X-RAY REFLECTED SPECTRA FROM ACCRETION DISK MODELS. I. CONSTANT DENSITY ATMOSPHERES

    International Nuclear Information System (INIS)

    Garcia, J.; Kallman, T. R.

    2010-01-01

    We present new models for illuminated accretion disks, their structure, and reprocessed emission. We consider the effects of incident X-rays on the surface of an accretion disk by simultaneously solving the equations of radiative transfer, energy balance, and ionization equilibrium over a large range of column densities. We assume plane-parallel geometry and azimuthal symmetry, such that each calculation corresponds to a ring at a given distance from the central object. Our models include recent and complete atomic data for K-shell processes of the iron and oxygen isonuclear sequences. We examine the effect on the spectrum of fluorescent Kα line emission and absorption in the emitted spectrum. We also explore the dependence of the spectrum on the strength of the incident X-rays and other input parameters, and discuss the importance of Comptonization on the emitted spectrum.

  13. X-ray Reflected Spectra from Accretion Disk Models. I. Constant Density Atmospheres

    Science.gov (United States)

    Garcia, Javier; Kallman, Timothy R.

    2009-01-01

    We present new models for illuminated accretion disks, their structure and reprocessed emission. We consider the effects of incident X-rays on the surface of an accretion disk by solving simultaneously the equations of radiative transfer, energy balance and ionization equilibrium over a large range of column densities. We assume plane-parallel geometry and azimuthal symmetry, such that each calculation corresponds to a ring at a given distance from the central object. Our models include recent and complete atomic data for K-shell of the iron and oxygen isonuclear sequences. We examine the effect on the spectrum of fluorescent Ka line emission and absorption in the emitted spectrum. We also explore the dependence of the spectrum on the strength of the incident X-rays and other input parameters, and discuss the importance of Comptonization on the emitted spectrum.

  14. Principal component analysis for the forensic discrimination of black inkjet inks based on the Vis-NIR fibre optics reflection spectra.

    Science.gov (United States)

    Gál, Lukáš; Oravec, Michal; Gemeiner, Pavol; Čeppan, Michal

    2015-12-01

    Nineteen black inkjet inks of six different brands were examined by fibre optics reflection spectroscopy in Visible and Near Infrared Region (Vis-NIR FORS) directly on paper with a view to achieving good resolution between them. These different inks were tested on nineteen different inkjet printers from three brands. Samples were obtained from prints by reflection probe. Processed reflection spectra in the range 500-1000 nm were used as samples in principal component analysis. Variability between spectra of the same ink obtained from different prints, as well as between spectra of square areas and lines was examined. For both spectra obtained from square areas and lines reference, Principal Component Analysis (PCA) models were created. According to these models, the inkjet inks were divided into clusters. PCA method is able to separate inks containing carbon black as main colorant from the other inks using other colorants. Some spectra were recorded from another piece of printer and used as validation samples. Spectra of validation samples were projected onto reference PCA models. According to position of validation samples in score plots it can be concluded that PCA based on Vis-NIR FORS can reliably differentiate inkjet inks which are included in the reference database. The presented method appears to be a suitable tool for forensic examination of questioned documents containing inkjet inks. Inkjet inks spectra were obtained without extraction or cutting sample with possibility to measure out of the laboratory. Copyright © 2015 Elsevier Ireland Ltd. All rights reserved.

  15. Simulation of reflectance from white-anodised aluminium surfaces using polyurethane–TiO2 composite coatings

    DEFF Research Database (Denmark)

    Gudla, Visweswara Chakravarthy; Johansen, Villads Egede; Ambat, Rajan

    2015-01-01

    Theoretical calculations and experimental studies were carried out on polyurethane (PU)–TiO2 composite coatings on bright and matte aluminium surfaces with an aim to understand and tailor the light scattering from particles incorporated into an anodised layer for designing the optical appearance...... of anodised surfaces. PU matrix was selected for its matching refractive-index (n = 1.7) with anodic alumina layer. Three different TiO2 particle size distributions were dispersed in PU and spin coated onto bright high-gloss and matte caustic-etched aluminium substrates. The reflectance spectra of coated...

  16. Ground-Based VIS/NIR Reflectance Spectra of 25143 Itokawa: What Hayabusa will See and How Ground-Based Data can Augment Analyses

    Science.gov (United States)

    Vilas, Faith; Abell, P. A.; Jarvis, K. S.

    2004-01-01

    Planning for the arrival of the Hayabusa spacecraft at asteroid 25143 Itokawa includes consideration of the expected spectral information to be obtained using the AMICA and NIRS instruments. The rotationally-resolved spatial coverage the asteroid we have obtained with ground-based telescopic spectrophotometry in the visible and near-infrared can be utilized here to address expected spacecraft data. We use spectrophotometry to simulate the types of data that Hayabusa will receive with the NIRS and AMICA instruments, and will demonstrate them here. The NIRS will cover a wavelength range from 0.85 m, and have a dispersion per element of 250 Angstroms. Thus, we are limited in coverage of the 1.0 micrometer and 2.0 micrometer mafic silicate absorption features. The ground-based reflectance spectra of Itokawa show a large component of olivine in its surface material, and the 2.0 micrometer feature is shallow. Determining the olivine to pyroxene abundance ratio is critically dependent on the attributes of the 1.0- and 2.0 micrometer features. With a cut-off near 2,1 micrometer the longer edge of the 2.0- feature will not be obtained by NIRS. Reflectance spectra obtained using ground-based telescopes can be used to determine the regional composition around space-based spectral observations, and possibly augment the longer wavelength spectral attributes. Similarly, the shorter wavelength end of the 1.0 micrometer absorption feature will be partially lost to the NIRS. The AMICA filters mimic the ECAS filters, and have wavelength coverage overlapping with the NIRS spectral range. We demonstrate how merging photometry from AMICA will extend the spectral coverage of the NIRS. Lessons learned from earlier spacecraft to asteroids should be considered.

  17. An attenuated total reflectance IR study of silicic acid adsorbed onto a ferric oxyhydroxide surface

    Science.gov (United States)

    Swedlund, Peter J.; Miskelly, Gordon M.; McQuillan, A. James

    2009-07-01

    Silicic acid (H 4SiO 4) can have significant effects on the properties of iron oxide surfaces in both natural and engineered aquatic systems. Understanding the reactions of H 4SiO 4 on these surfaces is therefore necessary to describe the aquatic chemistry of iron oxides and the elements that associate with them. This investigation uses attenuated total reflectance infrared spectroscopy (ATR-IR) to study silicic acid in aqueous solution and the products formed when silicic acid adsorbs onto the surface of a ferrihydrite film in 0.01 M NaCl at pH 4. A spectrum of 1.66 mM H 4SiO 4 at pH 4 (0.01 M NaCl) has an asymmetric Si-O stretch at 939 cm -1 and a weak Si-O-H deformation at 1090 cm -1. ATR-IR spectra were measured over time (for up to 7 days) for a ferrihydrite film (≈1 mg) approaching equilibrium with H 4SiO 4 at concentrations between 0.044 and 0.91 mM. Adsorbed H 4SiO 4 had a broad spectral feature between 750 and 1200 cm -1 but the shape of the spectra changed as the amount of H 4SiO 4 adsorbed on the ferrihydrite increased. When the solid phase Si/Fe mole ratio was less than ≈0.01 the ATR-IR spectra had a maximum intensity at 943 cm -1 and the spectral shape suggests that a monomeric silicate species was formed via a bidentate linkage. As the solid phase Si/Fe mole ratio increased to higher values a discrete oligomeric silicate species was formed which had maximum intensity in the ATR-IR spectra at 1001 cm -1. The spectrum of this species suggests that it is larger than a dimer and it was tentatively identified as a cyclic tetramer. A small amount of a polymeric silica phase with a broad spectral feature centered at ≈1110 cm -1 was also observed at high surface coverage. The surface composition was estimated from the relative contribution of each species to the area of the ATR-IR spectra using multivariate curve resolution with alternating least squares. For a ferrihydrite film approaching equilibrium with 0.044, 0.14, 0.40 and 0.91 mM H 4SiO 4 the

  18. A framework for modeling connections between hydraulics, water surface roughness, and surface reflectance in open channel flows

    Science.gov (United States)

    Legleiter, Carl; Mobley, Curtis D.; Overstreet, Brandon

    2017-01-01

    This paper introduces a framework for examining connections between the flow field, the texture of the air-water interface, and the reflectance of the water surface and thus evaluating the potential to infer hydraulic information from remotely sensed observations of surface reflectance. We used a spatial correlation model describing water surface topography to illustrate the application of our framework. Nondimensional relations between model parameters and flow intensity were established based on a prior flume study. Expressing the model in the spatial frequency domain allowed us to use an efficient Fourier transform-based algorithm for simulating water surfaces. Realizations for both flume and field settings had water surface slope distributions positively correlated with velocity and water surface roughness. However, most surface facets were gently sloped and thus unlikely to yield strong specular reflections; the model exaggerated the extent of water surface features, leading to underestimation of facet slopes. A ray tracing algorithm indicated that reflectance was greatest when solar and view zenith angles were equal and the sensor scanned toward the Sun to capture specular reflections of the solar beam. Reflected energy was concentrated in a small portion of the sky, but rougher water surfaces reflected rays into a broader range of directions. Our framework facilitates flight planning to avoid surface-reflected radiance while mapping other river attributes, or to maximize this component to exploit relationships between hydraulics and surface reflectance. This initial analysis also highlighted the need for improved models of water surface topography in natural rivers.

  19. A framework for modeling connections between hydraulics, water surface roughness, and surface reflectance in open channel flows

    Science.gov (United States)

    Legleiter, Carl J.; Mobley, Curtis D.; Overstreet, Brandon T.

    2017-09-01

    This paper introduces a framework for examining connections between the flow field, the texture of the air-water interface, and the reflectance of the water surface and thus evaluating the potential to infer hydraulic information from remotely sensed observations of surface reflectance. We used a spatial correlation model describing water surface topography to illustrate the application of our framework. Nondimensional relations between model parameters and flow intensity were established based on a prior flume study. Expressing the model in the spatial frequency domain allowed us to use an efficient Fourier transform-based algorithm for simulating water surfaces. Realizations for both flume and field settings had water surface slope distributions positively correlated with velocity and water surface roughness. However, most surface facets were gently sloped and thus unlikely to yield strong specular reflections; the model exaggerated the extent of water surface features, leading to underestimation of facet slopes. A ray tracing algorithm indicated that reflectance was greatest when solar and view zenith angles were equal and the sensor scanned toward the Sun to capture specular reflections of the solar beam. Reflected energy was concentrated in a small portion of the sky, but rougher water surfaces reflected rays into a broader range of directions. Our framework facilitates flight planning to avoid surface-reflected radiance while mapping other river attributes, or to maximize this component to exploit relationships between hydraulics and surface reflectance. This initial analysis also highlighted the need for improved models of water surface topography in natural rivers.

  20. Optical properties of nucleobase thin films as studied by attenuated total reflection and surface-enhanced Raman spectroscopy

    Science.gov (United States)

    Kim, MinSuk; Ham, Won Kyu; Kim, Wonyoung; Hwangbo, Chang Kwon; Choi, Eun Ha; Lee, Geon Joon

    2018-04-01

    Optical properties of nucleobase thin films were studied by attenuated total reflection (ATR) and surface-enhanced Raman spectroscopy (SERS). Adenine and guanine films were deposited on fused silica and silver at room temperature by thermal evaporation, and the normal dispersion of refractive indices of transparent adenine and guanine films in the visible and near-infrared regions were analyzed. The measured ATR spectra of adenine (guanine) films and numerical simulations by optical transfer matrix formalism demonstrate that the shift of surface plasmon resonance (SPR) wavelength is approximately linearly proportional to the adenine (guanine) film thickness, indicating that SPR can be used for quantitative measurements of biomaterials. The Raman spectra indicated that the adenine (guanine) films can be deposited by thermal evaporation. The adenine (guanine) films on silver exhibited Raman intensity enhancement as compared to those on glass, which was attributed to the SPR effect of silver platform and might play a role as a hot plate for SERS detection of biomaterials.

  1. Continuity of Reflectance Data between Landsat-7 ETM+ and Landsat-8 OLI, for Both Top-of-Atmosphere and Surface Reflectance: A Study in the Australian Landscape

    Directory of Open Access Journals (Sweden)

    Neil Flood

    2014-08-01

    Full Text Available The new Landsat-8 Operational Land Imager (OLI is intended to be broadly compatible with the previous Landsat-7 Enhanced Thematic Mapper Plus (ETM+. The spectral response of the OLI is slightly different to the ETM+, and so there may be slight differences in the reflectance measurements. Since the differences are a function not just of spectral responses, but also of the target pixels, there is a need to assess these differences in practice, using imagery from the area of interest. This paper presents a large scale study of the differences between ETM+ and OLI in the Australian landscape. The analysis is carried out in terms of both top-of-atmosphere and surface reflectance, and also in terms of biophysical parameters modelled from those respective reflectance spectra. The results show small differences between the sensors, which can be magnified by modelling to a biophysical parameter. It is also shown that a part of this difference appears to be systematic, and can be reliably removed by regression equations to predict ETM+ reflectance from OLI reflectance, before applying biophysical models. This is important when models have been fitted to historical field data coincident with ETM+ imagery. However, there will remain a small per-pixel difference which could be an unwanted source of variability.

  2. Reflectance spectroscopy of natural organic solids, iron sulfides and their mixtures as refractory analogues for Rosetta/VIRTIS' surface composition analysis of 67P/CG

    Science.gov (United States)

    Moroz, Lyuba V.; Markus, Kathrin; Arnold, Gabriele; Henckel, Daniela; Kappel, David; Schade, Ulrich; Rousseau, Batiste; Quirico, Eric; Schmitt, Bernard; Capaccioni, Fabrizio; Bockelee-Morvan, Dominique; Filacchione, Gianrico; Érard, Stéphane; Leyrat, Cedric; VIRTIS Team

    2016-10-01

    Analysis of 0.25-5 µm reflectance spectra provided by the Visible and InfraRed Thermal Imaging Spectrometer (VIRTIS) onboard Rosetta orbiter revealed that the surface of 67P/CG is dark from the near-UV to the IR and is enriched in refractory phases such as organic and opaque components. The broadness and complexity of the ubiquitous absorption feature around 3.2 µm suggest a variety of cometary organic constituents. For example, complex hydrocarbons (aliphatic and polycyclic aromatic) can contribute to the feature between 3.3 and 3.5 µm and to the low reflectance of the surface in the visible. Here we present the 0.25-5 µm reflectance spectra of well-characterized terrestrial hydrocarbon materials (solid oil bitumens, coals) and discuss their relevance as spectral analogues for a hydrocarbon part of 67P/CG's complex organics. However, the expected low degree of thermal processing of cometary hydrocarbons (high (H+O+N+S)/C ratios and low carbon aromaticities) suggests high IR reflectance, intense 3.3-3.5 µm absorption bands and steep red IR slopes that are not observed in the VIRTIS spectra. Fine-grained opaque refractory phases (e.g., iron sulfides, Fe-Ni alloys) intimately mixed with other surface components are likely responsible for the low IR reflectance and low intensities of absorption bands in the VIRTIS spectra of the 67P/CG surface. In particular, iron sulfides are common constituents of cometary dust, "cometary" chondritic IDPs, and efficient darkening agents in primitive carbonaceous chondrites. Their effect on reflectance spectra of an intimate mixture is strongly affected by grain size. We report and discuss the 0.25-5 µm reflectance spectra of iron sulfides (meteoritic troilite and several terrestrial pyrrhotites) ground and sieved to various particle sizes. In addition, we present reflectance spectra of several intimate mixtures of powdered iron sulfides and solid oil bitumens. Based on the reported laboratory data, we discuss the ability of

  3. Impact of dielectric parameters on the reflectivity of 3C–SiC wafers with a rough surface morphology in the reststrahlen region

    Energy Technology Data Exchange (ETDEWEB)

    Engelbrecht, J.A.A., E-mail: Japie.Engelbrecht@nmmu.ac.za [Physics Department, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa); Janzén, E.; Henry, A. [Department of Physics, Chemistry and Biology, Linköping University, SE-581 83 Linköping (Sweden); Rooyen, I.J. van [Fuel Performance and Design Department, Idaho National Laboratory, PO Box 1625, Idaho Falls, ID 83415-6188 (United States)

    2014-04-15

    A layer-on-substrate model is used to obtain the infrared reflectance for 3C–SiC with a rough surface morphology. The effect of varying dielectric parameters of the “damaged layer” on the observed reflectivity of the 3C–SiC in the reststrahlen region is assessed. Different simulated reflectance spectra are obtained to those if the dielectric parameters of the “substrate” were varied. Most notable changes in the shape of the simulated reststrahlen peak are observed for changes in the high frequency dielectric constant, the phonon damping constant, the phonon frequencies and “thickness” of damaged surface layer.

  4. Impact of dielectric parameters on the reflectivity of 3C–SiC wafers with a rough surface morphology in the reststrahlen region

    International Nuclear Information System (INIS)

    Engelbrecht, J.A.A.; Janzén, E.; Henry, A.; Rooyen, I.J. van

    2014-01-01

    A layer-on-substrate model is used to obtain the infrared reflectance for 3C–SiC with a rough surface morphology. The effect of varying dielectric parameters of the “damaged layer” on the observed reflectivity of the 3C–SiC in the reststrahlen region is assessed. Different simulated reflectance spectra are obtained to those if the dielectric parameters of the “substrate” were varied. Most notable changes in the shape of the simulated reststrahlen peak are observed for changes in the high frequency dielectric constant, the phonon damping constant, the phonon frequencies and “thickness” of damaged surface layer.

  5. Variability of Surface Reflection Amplitudes of GPR Horn Antenna Depending on Distance between Antenna and Surface

    Directory of Open Access Journals (Sweden)

    Komačka Jozef

    2016-05-01

    Full Text Available The study focused on variability of surface reflections amplitudes of GPR horn antenna in relation to distance between an antenna and a surface is presented in the paper. The air-coupled antenna with the central frequency of 1 GHz was used in the investigation. Four types of surfaces (dry pavement, wet pavement, metal plate and composite layer from gypsum and wood were tested. The distance of antenna above the surfaces was changed in the range from 37.5 cm to 53.5 cm. The amplitudes of negative and positive peaks and their variability were analysed in relation to the distance of antenna above the surfaces. Moreover, the influence of changes in the peaks of negative and positive amplitudes on the total amplitudes was assessed. It was found out the amplitudes of negative peaks for all investigated surfaces were relatively consistent in the range from 40.5 cm to 48.5 cm and the moderate decline was identified in the case of amplitudes of positive peaks in the range of distances from 37.5 cm to 51.5 cm. This decline influences the tendency of total amplitudes. Based on the results of analysis it can be stated the distance of air-coupled antenna above the surface can influence the value of total amplitude and the differences depend on the type of surface.

  6. Different size biomolecules anchoring on porous silicon surface: fluorescence and reflectivity pores infiltration comparative studies

    Energy Technology Data Exchange (ETDEWEB)

    Giovannozzi, Andrea M.; Rossi, Andrea M. [National Institute for Metrological Research, Thermodynamic Division, Strada delle Cacce 91, 10135 Torino (Italy); Renacco, Chiara; Farano, Alessandro [Ribes Ricecrhe Srl, Via Lavoratori Vittime del Col du Mont 24, 11100 Aosta (Italy); Derosas, Manuela [Biodiversity Srl, Via Corfu 71, 25124 Brescia (Italy); Enrico, Emanuele [National Institute for Metrological Research, Electromagnetism Division, Strada delle Cacce 91, 10135 Torino (Italy)

    2011-06-15

    The performance of porous silicon optical based biosensors strongly depends on material nanomorphology, on biomolecules distribution inside the pores and on the ability to link sensing species to the pore walls. In this paper we studied the immobilization of biomolecules with different size, such as antibody anti aflatoxin (anti Aflatox Ab, {proportional_to}150 KDa), malate dehydrogenase (MDH, {proportional_to}36KDa) and metallothionein (MT, {proportional_to}6KDa) at different concentrations on mesoporous silicon samples ({proportional_to}15 nm pores diameter). Fluorescence measurements using FITC- labeled biomolecules and refractive index analysis based on reflectivity spectra have been employed together to detect the amount of proteins bound to the surface and to evaluate their diffusion inside the pores. Here we suggest that these two techniques should be used together to have a better understanding of what happens at the porous silicon surface. In fact, when pores dimensions are not perfectly tuned to the protein size a higher fluorescence signal doesn't often correspond to a higher biomolecules distribution inside the pores. When a too much higher concentration of biomolecule is anchored on the surface, steric crowd effects and repulsive interactions probably take over and hinder pores infiltration, inducing a small or absent shift in the fringe pattern even if a higher fluorescence signal is registered. (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  7. Surface Plasmons and Surface Enhanced Raman Spectra of Aggregated and Alloyed Gold-Silver Nanoparticles

    Directory of Open Access Journals (Sweden)

    Y. Fleger

    2009-01-01

    Full Text Available Effects of size, morphology, and composition of gold and silver nanoparticles on surface plasmon resonance (SPR and surface enhanced Raman spectroscopy (SERS are studied with the purpose of optimizing SERS substrates. Various gold and silver films made by evaporation and subsequent annealing give different morphologies and compositions of nanoparticles and thus different position of the SPR peak. SERS measurements of 4-mercaptobenzoic acid obtained from these films reveal that the proximity of the SPR peak to the exciting laser wavelength is not the only factor leading to the highest Raman enhancement. Silver nanoparticles evaporated on top of larger gold nanoparticles show higher SERS than gold-silver alloyed nanoparticles, in spite of the fact that the SPR peak of alloyed nanoparticles is narrower and closer to the excitation wavelength. The highest Raman enhancement was obtained for substrates with a two-peak particle size distribution for excitation wavelengths close to the SPR.

  8. Improved Aerosol Optical Thickness, Columnar Water Vapor, and Surface Reflectance Retrieval from Combined CASI and SASI Airborne Hyperspectral Sensors

    Directory of Open Access Journals (Sweden)

    Hang Yang

    2017-02-01

    Full Text Available An increasingly common requirement in remote sensing is the integration of hyperspectral data collected simultaneously from different sensors (and fore-optics operating across different wavelength ranges. Data from one module are often relied on to correct information in the other, such as aerosol optical thickness (AOT and columnar water vapor (CWV. This paper describes problems associated with this process and recommends an improved strategy for processing remote sensing data, collected from both visible to near-infrared and shortwave infrared modules, to retrieve accurate AOT, CWV, and surface reflectance values. This strategy includes a workflow for radiometric and spatial cross-calibration and a method to retrieve atmospheric parameters and surface reflectance based on a radiative transfer function. This method was tested using data collected with the Compact Airborne Spectrographic Imager (CASI and SWIR Airborne Spectrographic Imager (SASI from a site in Huailai County, Hebei Province, China. Various methods for retrieving AOT and CWV specific to this region were assessed. The results showed that retrieving AOT from the remote sensing data required establishing empirical relationships between 465.6 nm/659 nm and 2105 nm, augmented by ground-based reflectance validation data, and minimizing the merit function based on AOT@550 nm optimization. The paper also extends the second-order difference algorithm (SODA method using Powell’s methods to optimize CWV retrieval. The resulting CWV image has fewer residual surface features compared with the standard methods. The derived remote sensing surface reflectance correlated significantly with the ground spectra of comparable vegetation, cement road and soil targets. Therefore, the method proposed in this paper is reliable enough for integrated atmospheric correction and surface reflectance retrieval from hyperspectral remote sensing data. This study provides a good reference for surface

  9. RTM-based Teleseismic Reflection Tomography with Free Surface Multiples

    Science.gov (United States)

    Burdick, S. A.; De Hoop, M. V.; van der Hilst, R. D.

    2013-12-01

    Receiver function analysis of teleseismic converted and free surface reflected phases has long been a cornerstone of lithospheric studies. Discontinuities in elastic properties are revealed by deconvolving the incident wavefield from scattered phases and projecting the time differences to depth to form an image. The accuracy of the image is determined to a large extent by the accuracy of the method and background velocity model used, but popular approaches for projecting receiver functions to depth commonly rely on simplifying assumptions of a 1D velocity and planar discontinuities. In tectonically complex regions like subduction zones and rift systems, strong heterogeneity can create an ambiguous tradeoff between the background velocity and the depth of the discontinuities. Furthermore, such structures are apt to create caustics at high frequencies, rendering ray-based methods inadequate. In order to better constrain the background velocity and correctly place the discontinuities at depth, we employ a novel reverse-time migration (RTM) based reflection tomography method. We adapt our reflection tomography from exploration seismology for use with teleseismic phases. Active source methods for exploration have focused on the annihilation of extended images - image gathers formed with different subsurface angle or offset information - as a means of judging the accuracy of the model. Applying these approaches to teleseismic data is untenable because 1) the sparse and uneven distribution of earthquake sources leads to the incomplete construction of extended image, 2) the imperfect separation and source deconvolution of the scattered wavefield render previous error measurements unreliable, and 3) the planar geometry of incoming arrivals makes measures of subsurface offset insensitive to perturbations in the model. To overcome these obstacles, we have developed a flexible approach based on pairwise single-source image correlations. We determine the success of the RTM and

  10. Highly reproducible surface-enhanced Raman spectra on semiconductor SnO2 octahedral nanoparticles.

    Science.gov (United States)

    Jiang, Li; Yin, Penggang; You, Tingting; Wang, Hua; Lang, Xiufeng; Guo, Lin; Yang, Shihe

    2012-12-07

    Highly reproducible surface-enhanced Raman scattering (SERS) spectra are obtained on the surface of SnO(2) octahedral nanoparticles. The spot-to-spot SERS signals show a relative standard deviation (RSD) consistently below 20 % in the intensity of the main Raman peaks of 4-mercaptobenzoic acid (4-MBA) and 4-nitrobenzenethiol (4-NBT), indicating good spatial uniformity and reproducibility. The SERS signals are believed to mainly originate from a charge-transfer (CT) mechanism. Time-dependent density functional theory (TD-DFT) is used to simulate the SERS spectrum and interpret the chemical enhancement mechanism in the experiment. The research extends the application of SERS and also establishes a new uniform SERS substrate. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Plasma surface reflectance spectroscopy for non-invasive and continuous monitoring of extracellular component of blood

    Science.gov (United States)

    Sakota, Daisuke; Takatani, Setsuo

    2012-04-01

    To achieve the quantitative optical non-invasive diagnosis of blood during extracorporeal circulation therapies, the instrumental technique to extract extracellular spectra from whole blood was developed. In the circuit, the continuous blood flow was generated by a centrifugal blood pump. The oxygen saturation was maintained 100% by an oxygenator. The developed glass optical flow cell was attached to the outlet tubing of the oxygenator. The halogen lamp including the light from 400 to 900 nm wavelength was used for the light source. The light was guided into an optical fiber. The light emitted by the fiber was collimated and emitted to the flow cell flat surface at the incident angle of 45 degrees. The light just reflected on the boundary between inner surface of the flow cell and plasma at 45 degrees was detected by the detection fiber. The detected light was analyzed by a spectral photometer. The obtained spectrum from 400 to 600nm wavelength was not changed with respect to the hematocrit. In contrast, the signal in the spectral range was changed when the plasma free hemoglobin increased. By using two spectral range, 505+/-5 nm and 542.5+/-2.5 nm, the differential spectrum was correlated with the free hemoglobin at R2=0.99. On the other hand, as for the hematocrit, the differential spectrum was not correlated at R2=0.01. Finally, the plasma free hemoglobin was quantified with the accuracy of 22+/-19mg/dL. The result shows that the developed plasma surface reflectance spectroscopy (PSRS) can extract the plasma spectrum from flowing whole blood.

  12. Effects of mercury on visible/near-infrared reflectance spectra of mustard spinach plants (Brassica rapa P.)

    Energy Technology Data Exchange (ETDEWEB)

    Dunagan, Sarah C. [Department of Earth and Environmental Sciences, Wesleyan University, 265 Church Street, Middletown, CT 06459 (United States)]. E-mail: sdunagan@wesleyan.edu; Gilmore, Martha S. [Department of Earth and Environmental Sciences, Wesleyan University, 265 Church Street, Middletown, CT 06459 (United States)]. E-mail: mgilmore@wesleyan.edu; Varekamp, Johan C. [Department of Earth and Environmental Sciences, Wesleyan University, 265 Church Street, Middletown, CT 06459 (United States)]. E-mail: jvarekamp@wesleyan.edu

    2007-07-15

    Mustard spinach plants were grown in mercury-spiked and contaminated soils collected in the field under controlled laboratory conditions over a full growth cycle to test if vegetation grown in these soils has discernible characteristics in visible/near-infrared (VNIR) spectra. Foliar Hg concentrations (0.174-3.993 ppm) of the Mustard spinach plants were positively correlated with Hg concentration of soils and varied throughout the growing season. Equations relating foliar Hg concentration to spectral reflectance, its first derivative, and selected vegetation indices were generated using stepwise multiple linear regression. Significant correlations are found for limited wavelengths for specific treatments and dates. Ratio Vegetation Index (RVI) and Red Edge Position (REP) values of plants in Hg-spiked and field-contaminated soils are significantly lower relative to control plants during the early and middle portions of the growth cycle which may be related to lower chlorophyll abundance or functioning in Hg-contaminated plants. - Some spectral characteristics of leaves of Brassica rapa P. may be associated with foliar mercury content.

  13. Surface Stokes drift in the Baltic Sea based on modelled wave spectra

    Science.gov (United States)

    Tuomi, Laura; Vähä-Piikkiö, Olga; Alenius, Pekka; Björkqvist, Jan-Victor; Kahma, Kimmo K.

    2018-01-01

    The Stokes drift is an important component in the surface drift. We used the wave model WAM to evaluate the mean values and exceedance probabilities of the surface Stokes drift in the Baltic Sea. As there is no direct way to verify the accuracy of the modelled Stokes drift, we compared the bulk parameters calculated by the wave model against buoy measurements to ensure the quality of the wave hindcast. Furthermore, we evaluated the surface Stokes drift from measured wave spectra to assess the accuracy of the modelled surface Stokes drift. The importance of the Stokes drift as a component of the total surface drift was evaluated by calculating the hindcast mean values and percentiles of the surface Stokes drift. The mean values were between 0.08 and 0.10 ms-1 in the open sea areas, thus being of the same order of magnitude as the mean wind shear currents. The highest values of the surface Stokes drift were slightly larger than 0.6 ms-1. The comparison of modelled Stokes drift values to estimates obtained from measured spectra suggests that the mean values are well represented by the model. However, the higher modelled values are most likely slightly too large because the wave energy was overestimated during high wind situations in some of the sub-basins, such as the Gulf of Finland. A comparison to a drifter experiment showed that use of the Stokes drift improves the estimate of both the drift speed and the direction in the Gulf of Finland. Parameterised methods to evaluate the Stokes drift that are used, e.g. in currently available Baltic Sea drift models, overestimate the smaller values (under 0.3 ms-1) and underestimate the larger values of the Stokes drift compared to the values calculated by the wave model. The modelled surface Stokes drift direction mostly followed the forcing wind direction. This was the case even in the Gulf of Finland, where the direction of the wind and the waves can differ considerably.

  14. Mercapto-based coupling agent for improved thermophotovoltaic device back surface reflector adhesion and reflectance

    Energy Technology Data Exchange (ETDEWEB)

    Wernsman, Bernard; Fiedor, Joseph N.; Irr, Lawrence G.; Palmisiano, Marc N.

    2016-10-04

    A back surface reflector (BSR) is described. The BSR includes a reflecting layer, a substrate and an adhesion layer between the reflecting layer and the substrate. The adhesion layer includes 3-mercaptopropyl (trimethoxy) silane (a.k.a. Merc).

  15. Gemini NorthNIRI Spectra of Pluto and Charon: Simultaneous Analysis of the Surface and Atmosphere

    Science.gov (United States)

    Cook, Jason C.; Cruikshank, Dale P.; Young, Leslie A.

    2014-01-01

    94035We report on our analysis of blended Pluto and Charon spectra over the wavelength range 1.4 to 2.5 m as obtained by the NIRI instrument on Gemini North on June 25-28, 2004. The data have a resolving power () around 1500 and a SNR around 200 per pixel. The observed blended spectra are compared to models that combine absorption from the solid ice on the surface using Hapke theory, and absorption from the gaseous atmosphere. We assume the spectrum is a combination of several spatially separate spectral units: a CH4-rich ice unit, a volatile unit (an intimate mixture of N2, CH4 and CO), and a Charon unit (H2O, ammonia hydrate and kaolinite). We test for the presence of hydrocarbons (i.e. C2H6) and nitriles (i.e. HCN) and examine cases where additional ices are present as either pure separate spatial units, mixed with the CH4-rich unit or part of the volatile unit. We conclude that 2-4 of Plutos surface is covered with pure-C2H6 and our identification of C2H6 is significantly strengthened when absorption due to gaseous CH4 is included. The inclusion of Plutos atmosphere demonstrates that low-resolution, high-SNR observations are capable of detecting Plutos atmosphere during a time when Plutos atmosphere may have been undergoing rapid changes (1988-2002) and no high-resolution spectra were obtained. In particular, we identify features at 1.665 and 2.317 m as the Q-branch of the 23 and 3+4 bands of gaseous CH4, respectively. The later band is also evident in many previously published spectra of Pluto. Our analysis finds it is unnecessary to include 13CO to explain the depth of the 2.405 m, which has been previously suggested to be a spectral blended with C2H6, but we cannot definitively rule out its presence. Funding for this work (Cook) has been provided by a NASA-PATM grant.

  16. Reconstruction of Satellite-Retrieved Land-Surface Reflectance Based on Temporally-Continuous Vegetation Indices

    Directory of Open Access Journals (Sweden)

    Zhiqiang Xiao

    2015-07-01

    Full Text Available Land-surface reflectance, estimated from satellite observations through atmospheric corrections, is an essential parameter for further retrieval of various high level land-surface parameters, such as leaf area index (LAI, fraction of absorbed photosynthetically active radiation (FAPAR, and surface albedo. Although great efforts have been made, land-surface reflectance products still contain considerable noise caused by, e.g., cloud or mixed-cloud pixels, which results in temporal and spatial inconsistencies in subsequent downstream products. In this study, a new method is developed to remove the residual clouds in the Moderate Resolution Imaging Spectroradiometer (MODIS land-surface reflectance product and reconstruct time series of surface reflectance for the red, near infrared (NIR, and shortwave infrared (SWIR bands. A smoothing method is introduced to calculate upper envelopes of vegetation indices (VIs from the surface reflectance data and the cloud contaminated reflectance data are identified using the time series VIs and the upper envelopes of the time series VIs. Surface reflectance was then reconstructed according to cloud-free surface reflectance by incorporating the upper envelopes of the time series VIs as constraint conditions. The method was applied to reconstruct time series of surface reflectance from MODIS/TERRA surface reflectance product (MOD09A1. Temporal consistency analysis indicates that the new method can reconstruct temporally-continuous time series of land-surface reflectance. Comparisons with cloud-free MODIS/AQUA surface reflectance product (MYD09A1 over the BELMANIP (Benchmark Land Multisite Analysis and Intercomparison of Products sites in 2003 demonstrate that the new method provides better performance for the red band (R2 = 0.8606 and RMSE = 0.0366 and NIR band (R2 = 0.6934 and RMSE = 0.0519, than the time series cloud detection (TSCD algorithm (R2 = 0.5811 and RMSE = 0.0649; and R2 = 0.5005 and RMSE = 0

  17. Native SrTiO3 (001) surface layer from resonant Ti L2,3 reflectance spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Valvidares, Manuel; Huijben, Mark; Yu, Pu; Ramesh, Ramamoorthy; Kortright, Jeffrey

    2010-11-03

    We quantitatively model resonant Ti L2,3 reflectivity Rs,p(q, hn) from several SrTiO3 (001) single crystals having different initial surface preparations and stored in ambient conditions before and between measurements. All samples exhibit unexpected 300 K Rs(hn) - Rp(hn) anisotropy corresponding to weak linear dichroism and tetragonal distortion of the TiO6 octahedra indicating a surface layer with properties different from cubic SrTiO3. Oscillations in Rs(q) confirm a ubiquitous surface layer 2-3 nm thick that evolves over a range of time scales. Resonant optical constant spectra derived from Rs,p(hn) assuming a uniform sample are refined using a single surface layer to fit measured Rs(q). Differences in surface layer and bulk optical properties indicate that the surface is significantly depleted in Sr and enriched in Ti and O. While consistent with the tendency of SrTiO3 surfaces toward non-stoichiometry, this layer does not conform simply to existing models for the near surface region and apparently forms via room temperature surface reactions with the ambient. This new quantitative spectral modeling approach is generally applicable and has potential to study near-surface properties of a variety of systems with unique chemical and electronic sensitivities.

  18. Detection of natural and stress-induced variability in reflectance spectra of apple trees using hyperspectral analysis

    Science.gov (United States)

    Delalieux, Stephanie; Keulemans, Wannes; van Aardt, Jan; Schrevens, Eddie; Coppin, Pol

    2005-10-01

    Early detection of biotic and abiotic stresses and subsequent steering of agricultural systems using hyperspectral sensors potentially could contribute to the pro-active treatment of production-limiting factors. Venturia inaequalis (apple scab) is an important biotic factor that can reduce yield in apple orchards. Previous hyperspectral research focused on (i) determining if Venturia inaequalis leaf infections could be differentiated from healthy leaves and (ii) investigating at which developmental stage Venturia inaequalis infection could be detected. Logistical regression and partial least squares discriminant analysis were used to select the hyperspectral bands that best define differences among treatments. It was clear that hyperspectral data provide the contiguous, high spectral resolution data that are needed to detect subtle changes in reflectance values between healthy and stressed vegetation. The research was extended to include tree-based modeling as an alternative classification method. Results suggested that good predictability could be achieved when classifying infected plants based on this supervised classification technique. It was concluded that the spectral domain around 1600 nm was best suited to discriminate between infected and non-infected leaves immediately after infection, while the visible spectral region became more important at a well-developed infection stage. Research was focused on young leaves, because of the decreased incidence of infection in older leaves, the so-called 'ontogenic resistance'. Additional research was performed to gain a better understanding of the processes occurring during the first days after leaf unfolding and to evaluate the natural spectral variability among leaves. An undisturbed 20-day growth profile was examined to assess variations in the reflectance spectra due to physiological changes at the different growth stages of the leaves. Results suggested that an accurate distinction could be made between

  19. Predicting foliar biochemistry of tea (Camellia sinensis) using reflectance spectra measured at powder, leaf and canopy levels

    Science.gov (United States)

    Bian, Meng; Skidmore, Andrew K.; Schlerf, Martin; Wang, Tiejun; Liu, Yanfang; Zeng, Rong; Fei, Teng

    2013-04-01

    Some biochemical compounds are closely related with the quality of tea (Camellia sinensis (L.)). In this study, the concentration of these compounds including total tea polyphenols, free amino acids and soluble sugars were estimated using reflectance spectroscopy at three different levels: powder, leaf and canopy, with partial least squares regression. The focus of this study is to systematically compare the accuracy of tea quality estimations based on spectroscopy at three different levels. At the powder level, the average r2 between predictions and observations was 0.89 for polyphenols, 0.81 for amino acids and 0.78 for sugars, with relative root mean square errors (RMSE/mean) of 5.47%, 5.50% and 2.75%, respectively; at the leaf level, the average r2 decreased to 0.46-0.81 and the relative RMSE increased to 4.46-7.09%. Compared to the results yielded at the leaf level, the results from canopy spectra were slightly more accurate, yielding average r2 values of 0.83, 0.77 and 0.56 and relative RMSE of 6.79%, 5.73% and 4.03% for polyphenols, amino acids and sugars, respectively. We further identified wavelength channels that influenced the prediction model. For powder and leaves, some bands identified can be linked to the absorption features of chemicals of interest (1648 nm for phenolic, 1510 nm for amino acids, 2080 nm and 2270 nm for sugars), while more indirectly related wavelengths were found to be important at the canopy level for predictions of chemical compounds. Overall, the prediction accuracies achieved at canopy level in this study are encouraging for future study on tea quality estimated at the landscape scale using airborne and space-borne sensors.

  20. Scaling of turbulence spectra measured in strong shear flow near the Earth’s surface

    DEFF Research Database (Denmark)

    Mikkelsen, Torben Krogh; Larsen, Søren Ejling; Ejsing Jørgensen, Hans

    2017-01-01

    Within the lowest kilometer of the Earth's atmosphere, in the so-called atmospheric boundary layer, winds are often gusty and turbulent. Nearest to the ground, the turbulence is predominately generated by mechanical wall-bounded wind shear, whereas at higher altitudes turbulent mixing of heat......) their generation; (2) the cascade of energy across the spectrum from large- to small-scale; and (3) the eventual decay of turbulence into heat owing to viscosity effects on the Kolmogorov microscale, in which the eddy size is only a fraction of a millimeter. This paper addresses atmospheric turbulence spectra...... in the lowest part of the atmospheric boundary layer—the so-called surface layer—where the wind shear is strong owing to the nonslip condition at the ground. Theoretical results dating back to Tchen's early work in 1953 'on the spectrum of energy in turbulent shear flow' led Tchen to predict a shear production...

  1. The Analyses of Turbulence Characteristics in the Atmospheric Surface Layer Using Arbitrary-Order Hilbert Spectra

    Science.gov (United States)

    Wei, W.; Schmitt, F. G.; Huang, Y. X.; Zhang, H. S.

    2016-05-01

    Turbulent characteristics in the atmospheric surface layer are investigated using a data-driven method, Hilbert spectral analysis. The results from empirical mode decomposition display a set of intrinsic mode functions whose characteristic scales suggest a dyadic filter-bank property. It can be concluded from the joint probability density function of the intrinsic mode functions that the turbulent properties are totally different under different stratifications: the amplitudes (or energies) are arranged according to the stability parameter [InlineEquation not available: see fulltext.] for stable conditions, but tend to cluster randomly for unstable cases. The intermittency analyses reveal that second-order Hilbert marginal spectra display a power-law behaviour in the inertial subrange, and that the scaling exponent functions deviate from the theoretical values due to the strong intermittency in the stable boundary layer.

  2. VIIRS/NPP Surface Reflectance 8-Day L3 Global 500m SIN Grid V001

    Data.gov (United States)

    National Aeronautics and Space Administration — The 8-day Visible Infrared Imaging Radiometer Suite (VIIRS) Surface Reflectance (VNP09H1) Version 1 composite product provides an estimate of land surface...

  3. Light Reflection from Water Surfaces Perturbed by Falling Rain Droplets

    Science.gov (United States)

    Molesini, Giuseppe; Vannoni, Maurizio

    2009-01-01

    An account of peculiar light patterns produced by reflection in a pool under falling rain droplets was recently reported by Molesini and Vannoni (2008 Eur. J. Phys. 29 403-11). The mathematical approach, however, only covered the case of a symmetrical location of a light source and the observer's eyes with respect to the vertical of the falling…

  4. A Generalized Approach to Model the Spectra and Radiation Dose Rate of Solar Particle Events on the Surface of Mars

    Science.gov (United States)

    Guo, Jingnan; Zeitlin, Cary; Wimmer-Schweingruber, Robert F.; McDole, Thoren; Kühl, Patrick; Appel, Jan C.; Matthiä, Daniel; Krauss, Johannes; Köhler, Jan

    2018-01-01

    For future human missions to Mars, it is important to study the surface radiation environment during extreme and elevated conditions. In the long term, it is mainly galactic cosmic rays (GCRs) modulated by solar activity that contribute to the radiation on the surface of Mars, but intense solar energetic particle (SEP) events may induce acute health effects. Such events may enhance the radiation level significantly and should be detected as immediately as possible to prevent severe damage to humans and equipment. However, the energetic particle environment on the Martian surface is significantly different from that in deep space due to the influence of the Martian atmosphere. Depending on the intensity and shape of the original solar particle spectra, as well as particle types, the surface spectra may induce entirely different radiation effects. In order to give immediate and accurate alerts while avoiding unnecessary ones, it is important to model and well understand the atmospheric effect on the incoming SEPs, including both protons and helium ions. In this paper, we have developed a generalized approach to quickly model the surface response of any given incoming proton/helium ion spectra and have applied it to a set of historical large solar events, thus providing insights into the possible variety of surface radiation environments that may be induced during SEP events. Based on the statistical study of more than 30 significant solar events, we have obtained an empirical model for estimating the surface dose rate directly from the intensities of a power-law SEP spectra.

  5. An instrument for the measurement of road surface reflection properties

    DEFF Research Database (Denmark)

    Corell, Dennis Dan; Sørensen, K.

    2017-01-01

    surfaces in use have changed - for instance to road surface types with less noise from wheel passages. Because of this, a co-operation between the road administrations of the Nordic countries (abbreviated NMF) decided to construct a portable instrument to be used on selections of traffic roads within...

  6. Orientation effect of ion flux splitting reflected from Wehner cone on solid surface

    CERN Document Server

    Bratchenko, M I; Rozhkov, V V

    2001-01-01

    It is shown that simple geometrical model of specular reflection of particles from the surface of Wehner cone (frequently observed feature of solid surface macroscopic topography developed under ion bombardment) can describe qualitatively the essential characteristics of the reflected particles flux splitting effect predicted earlier by means of computer simulation methods.

  7. Collimated light reflection and transmission of a surface partially covered by large and tenuous particles.

    Science.gov (United States)

    Vázquez-Estrada, Omar; García-Valenzuela, Augusto

    2016-11-01

    We derive simple approximate expressions for the reflectivity and transmissivity of light from disordered monolayers of tenuous particles of dimensions larger than the wavelength and supported by a flat interface. The expressions derived can be used for different particle shapes and for moderate angles of incidence. We then investigate the effects of particle shape and orientation on reflectivity and transmissivity spectra of a monolayer of tenuous particles containing an optical chromophore in a solution in their interior. We also simulate the effects of a particle's shape and orientation on the angle dependence of the optical reflectivity and transmissivity. In our examples, we consider disordered monolayers of particles analogous to some biological cells.

  8. Analysis of bacteria on steel surfaces using reflectance micro-Fourier transform infrared spectroscopy.

    Science.gov (United States)

    Ojeda, Jesús J; Romero-González, María E; Banwart, Steven A

    2009-08-01

    Reflectance micro-Fourier transform infrared (FT-IR) analysis has been applied to characterize biofilm formation of Aquabacterium commune, a common microorganism present on drinking water distribution systems, onto the increasingly popular pipe material stainless steel EN1.4307. The applicability of the reflectance micro-FT-IR technique for analyzing the bacterial functional groups is discussed, and the results are compared to spectra obtained using more conventional FT-IR techniques: transmission micro-FT-IR, attenuated transmitted reflectance (ATR), and KBr pellets. The differences between the infrared spectra of wet and dried bacteria, as well as free versus attached bacteria, are also discussed. The spectra obtained using reflectance micro-FT-IR spectroscopy were comparable to those obtained using other FT-IR techniques. The absence of sample preparation, the potential to analyze intact samples, and the ability to characterize opaque and thick samples without the need to transfer the bacterial samples to an infrared transparent medium or produce a pure culture were the main advantages of reflectance micro-FT-IR spectroscopy.

  9. A Monte Carlo reflectance model for soil surfaces with three-dimensional structure

    Science.gov (United States)

    Cooper, K. D.; Smith, J. A.

    1985-01-01

    A Monte Carlo soil reflectance model has been developed to study the effect of macroscopic surface irregularities larger than the wavelength of incident flux. The model treats incoherent multiple scattering from Lambertian facets distributed on a periodic surface. Resulting bidirectional reflectance distribution functions are non-Lambertian and compare well with experimental trends reported in the literature. Examples showing the coupling of the Monte Carlo soil model to an adding bidirectional canopy of reflectance model are also given.

  10. Liquid Atomization Induced by Pulse Laser Reflection underneath Liquid Surface

    Science.gov (United States)

    Utsunomiya, Yuji; Kajiwara, Takashi; Nishiyama, Takashi; Nagayama, Kunihito; Kubota, Shiro; Nakahara, Motonao

    2009-05-01

    We observed a novel effect of pulse laser reflection at the interface between transparent materials with different refractive indices. The electric field intensity doubles when a laser beam is completely reflected from a material with a higher refractive index to a material with a lower index. This effect appreciably reduces pulse laser ablation threshold of transparent materials. We performed experiments to observe the entire ablation process for laser incidence on the water-air interface using pulse laser shadowgraphy with high-resolution film; the minimum laser fluence for laser ablation at the water-air interface was approximately 12-16 J/cm2. We confirmed that this laser ablation occurs only when the laser beam is incident on the water-air interface from water. Many slender liquid ligaments extend like a milk crown and seem to be atomized at the tip. Their detailed structures can be resolved only by pulse laser photography using high-resolution film.

  11. Reflectivity reduction of retro-reflector installed in LHD due to plasma surface interaction

    International Nuclear Information System (INIS)

    Yoshida, N.; Ohtawa, Y.; Ebihara, A.; Akiyama, T.; Tokitani, M.; Ashikawa, N.; Kawahata, K.

    2008-10-01

    Optical reflectivity of the retro-reflector installed in LHD as the first mirror was reduced seriously by plasma wall interaction. In order to understand the mechanism of the reflectivity reduction, optical and material properties of the mirror surfaces have been examined extensively. It was found that the deposited impurity layers caused the serious reduction of the reflectivity. Formation of iron oxide, bulges structure and He bubbles are the major factors for the reflectivity reduction in the wide wave length range. (author)

  12. Patterns of change in the size spectra of numbers and diversity of the North Sea fish assemblage, as reflected in surveys and models

    DEFF Research Database (Denmark)

    Rice, J.; Gislason, Henrik

    1996-01-01

    Trends were analysed over two decades in the size spectra of numbers and diversity of the North Sea fish assemblage. Tn trawl survey data, the abundance spectrum was smoothly linear each year. Bath slopes and intercepts increased significantly over the period, reflecting the effects of fishing...... with the abundance spectrum suggests that the fish community structure has remained Fairly stable over the period, despite significant increases in harvesting on component populations. To explore the hypothesis that the regulation of the community structure arises from trophic interactions, the same community...... were very similar. Annual abundance spectra were linear and slopes increased significantly and fairly smoothly over the 20 years? indicating significant effects of fishing on the size composition of the exploited fish assemblage. The annual diversity spectra were more dome-shaped than in the survey...

  13. Fluorescence and Raman spectra on surface of K9 glass by high fluence ultraviolet laser irradiation at 355 nm

    Science.gov (United States)

    Zhang, Zhen; Huang, Jin; Geng, Feng; Zhou, Xiaoyan; Feng, Shiquan; Ren, Dahua; Cheng, Xinlu; Jiang, Xiaodong; Wu, Weidong; Zheng, Wanguo; Tang, Yongjian

    2013-11-01

    In order to explore the damage mechanisms of K9 glass irradiated by high energy density ultraviolet laser, laser-induced fluorescence and Raman spectra were investigated. Compared the fluorescence spectra of damaged area, undamaged area and sub-damaged area, it can be conclude that the fluorescence spectrum of sub-damaged area is different from the structure of the other two areas. Especially, the main peak of the spectra at 415 nm reveals the unique characteristics of K9 glass. The structure at the sub-damaged area enhances intensity of the Raman scattering spectra. Three peaks of the spectra at about 500 nm and two characteristic peaks at about 550 nm exhibit the characterization of damaged area. A peak of the Raman scattering spectra at 350 nm which related to water can be observed. The relationship between intensity of Raman scattering and laser intensity at 355 nm is investigated by confocal Raman microscopy. At sub-damage area, signal of Raman scattering is rather high and decreased dramatically with respect to energy density. The major band at about 1470 cm-1 sharpened and moved to higher frequency with densification. These phenomena demonstrate that the structure of sub-damaged area has some characterization compared with the damaged area. The investigation of defect induced fluorescence and Raman spectra on surface of K9 glass is important to explore the damage mechanisms of optical materials irradiated by ultraviolet laser irradiation at 355 nm.

  14. Removal of Surface-Reflected Light for the Measurement of Remote-Sensing Reflectance from an Above-Surface Platform

    Science.gov (United States)

    2010-12-06

    REPORT DATE IDD-MM- YYYY) 14-02-2011 2. REPORT TYPE Journal Article 3. DATES COVERED (From - To) 4. TITLE AND SUBTITLE Removal of Surface...impossible to obtain Rr, from measurements of vertical profiles of Lu and Elt [6]. During the experiment, the surface was calm [see Fig. 8(a)] and

  15. Preparation of surface conductive and highly reflective silvered polyimide films by surface modification and in situ self-metallization technique

    International Nuclear Information System (INIS)

    Wu Zhanpeng; Wu Dezhen; Qi Shengli; Zhang Teng; Jin Riguang

    2005-01-01

    Double surface conductive and reflective flexible silvered polyimide films have been prepared by alkali hydroxylation of polyimide film surface and incorporation of silver ions through subsequent ion exchange. Thermal curing of silver(I) polyamate precursor leads to re-cycloimidization of modified surface with concomitant silver reduction, yielding a reflective and conductive silver surface approaching that of native metal. The reflective and conductive surface evolves only when the cure temperature rises to 300 deg. C. The metallized films usually retain the essential mechanical properties of the parent films. Films were characterized by transmission electron microscopy (TEM), scanning electron microscopy and tapping mode atomic force microscopy (AFM). AFM demonstrates that the diameter of close-packed silver particles of the silver layers was about 50-150 nm. TEM shows that thickness of silver layer on the polyimide film surface is about 400-600 nm

  16. High quality broadband spatial reflections of slow Rayleigh surface acoustic waves modulated by a graded grooved surface

    KAUST Repository

    Xu, Yanlong

    2015-01-21

    We report high quality broadband spatial reflections of Rayleigh surface acoustic waves (SAWs) through a graded grooved surface. High quality means that no wave is allowed to transmit and the incident wave is nearly all reflected to the input side. The graded grooved surface is structured by drilling one dimensional array of graded grooves with increased depths on a flat surface. We investigate SAW dispersion relations, wave field distribution at several typical SAW wavelengths, and time evolution of a Gaussian pulse through the graded grooved surface. Results show that the input broadband Rayleigh SAWs can be slowed, spatially enhanced and stopped, and finally reflected to the input side. The study suggests that engraving the flat surface can be used as an efficient and economical way to manipulate Rayleigh SAWs, which has potential application in novel SAW devices such as filters, reflectors, sensors, energy harvesters, and diodes.

  17. Spectral reflectance of surface soils: Relationships with some soil properties

    Science.gov (United States)

    Kiesewetter, C. H.

    1983-01-01

    Using a published atlas of reflectance curves and physicochemical properties of soils, a statistical analysis was carried out. Reflectance bands which correspond to five of the wavebands used by NASA's Thematic Mapper were examined for relationships to specific soil properties. The properties considered in this study include: Sand Content, Silt Content, Clay Content, Organic Matter Content, Cation Exchange Capacity, Iron Oxide Content and Moisture Content. Regression of these seven properties on the mean values of five TM bands produced results that indicate that the predictability of the properties can be increased by stratifying the data. The data was stratified by parent material, taxonomic order, temperature zone, moisture zone and climate (combined temperature and moisture). The best results were obtained when the sample was examined by climatic classes. The middle Infra-red bands, 5 and 7, as well as the visible bands, 2 and 3, are significant in the model. The near Infra-red band, band 4, is almost as useful and should be included in any studies. General linear modeling procedures examined relationships of the seven properties with certain wavebands in the stratified samples.

  18. Estimating aerodynamic resistance of rough surfaces from angular reflectance

    Science.gov (United States)

    Current wind erosion and dust emission models neglect the heterogeneous nature of surface roughness and its geometric anisotropic effect on aerodynamic resistance, and over-estimate the erodible area by assuming it is not covered by roughness elements. We address these shortfalls with a new model wh...

  19. STACKING ON COMMON REFLECTION SURFACE WITH MULTIPARAMETER TRAVELTIME

    Directory of Open Access Journals (Sweden)

    Montes V. Luis A.

    2006-12-01

    Full Text Available Commonly seismic images are displayed in time domain because the model in depth can be known only in well logs. To produce seismic sections, pre and post stack processing approaches use time or depth velocity models whereas the common reflection method does not, instead it requires a set of parameters established for the first layer. A set of synthetic data of an anticline model, with sources and receivers placed on a flat topography, was used to observe the performance of this method. As result, a better reflector recovering compared against conventional processing sequence was observed.
    The procedure was extended to real data, using a dataset acquired on a zone characterized by mild topography and quiet environment reflectors in the Eastern Colombia planes, observing an enhanced and a better continuity of the reflectors in the CRS stacked section.

  20. Surface Bubbles in the Bathtub and Reflections on Ripple Tanks

    Science.gov (United States)

    Greenslade, Thomas B.

    2012-01-01

    Bathtubs are splendid places for studying physics! Recently I was happily splashing about and noticed that the light from the lamp above me was being focused as bright spots on the bottom of the tub. Closer inspection showed that the spots were surrounded by dark rings. This pattern turned out to be due to the lensing effect of bubbles floating on the surface of the water.

  1. Unmanned aerial system nadir reflectance and MODIS nadir BRDF-adjusted surface reflectances intercompared over Greenland

    Directory of Open Access Journals (Sweden)

    J. F. Burkhart

    2017-07-01

    Full Text Available Albedo is a fundamental parameter in earth sciences, and many analyses utilize the Moderate Resolution Imaging Spectroradiometer (MODIS bidirectional reflectance distribution function (BRDF/albedo (MCD43 algorithms. While derivative albedo products have been evaluated over Greenland, we present a novel, direct comparison with nadir surface reflectance collected from an unmanned aerial system (UAS. The UAS was flown from Summit, Greenland, on 210 km transects coincident with the MODIS sensor overpass on board the Aqua and Terra satellites on 5 and 6 August 2010. Clear-sky acquisitions were available from the overpasses within 2 h of the UAS flights. The UAS was equipped with upward- and downward-looking spectrometers (300–920 nm with a spectral resolution of 10 nm, allowing for direct integration into the MODIS bands 1, 3, and 4. The data provide a unique opportunity to directly compare UAS nadir reflectance with the MODIS nadir BRDF-adjusted surface reflectance (NBAR products. The data show UAS measurements are slightly higher than the MODIS NBARs for all bands but agree within their stated uncertainties. Differences in variability are observed as expected due to different footprints of the platforms. The UAS data demonstrate potentially large sub-pixel variability of MODIS reflectance products and the potential to explore this variability using the UAS as a platform. It is also found that, even at the low elevations flown typically by a UAS, reflectance measurements may be influenced by haze if present at and/or below the flight altitude of the UAS. This impact could explain some differences between data from the two platforms and should be considered in any use of airborne platforms.

  2. Investigation of cavity mode and excitonic transition in an InGaAs/GaAs/AlGaAs vertical-cavity surface emitting laser structure by variable-temperature micro-photoluminescence, reflectance and photomodulated reflectance

    International Nuclear Information System (INIS)

    Yu, J L; Chen, Y H; Jiang, C Y; Zhang, H Y

    2012-01-01

    Variable-temperature micro-photoluminescence (μ-PL), reflectance (R) and photomodulated reflectance (PR) have been used to study an InGaAs/GaAs/AlGaAs vertical-cavity surface emitting laser (VCSEL) structure. μ-PL and R spectra have been recorded at different temperatures between 80 K and 300 K By comparing μ-PL with R spectra, both the excitonic transition and cavity mode are clearly identified. The Variable-temperature μ-PL and PR results of the etched sample with the top distributed Bragg reflectors (DBR) being removed further confirmed our identification. Our results demonstrate that variable-temperature μ-PL is a powerful noninvasive tool to measure accurate the quantum well transition and the cavity mode alignment.

  3. Laboratory and field measurements of upwelled radiance and reflectance spectra of suspended James River sediments near Hopewell, Virginia

    Science.gov (United States)

    Whilock, C. H.; Witte, W. G.; Gurganus, E. A.; Usry, J. W.

    1978-01-01

    Spectral reflectance characteristics of suspended Bermuda Hundred and Bailey Bay bottom sediments taken from the Hopewell, Va., area were measured in the laboratory for water mixture total suspended solids concentrations between 4 and 173 parts per million. Field spectral reflectance measurements were made of the James River waters near Bermuda Hundred on two occasions. The results of these tests indicate that both Bermuda Hundred and Bailey Bay suspended sediments produce their strongest reflectance in the green and red regions of the spectrum.

  4. Highly reflective liquid mirrors: exploring the effects of localized surface plasmon resonance and the arrangement of nanoparticles on metal liquid-like films.

    Science.gov (United States)

    Yen, Yu-Ting; Lu, Tai-Yen; Lee, Yang-Chun; Yu, Chen-Chieh; Tsai, Yin-Chih; Tseng, Yi-Chuan; Chen, Hsuen-Li

    2014-03-26

    In this paper, we describe a high-reflectance liquid mirror prepared from densely packed silver nanoparticles (AgNPs) of two different sizes. We controlled the particle size during the synthetic process by controlling the temperature. Varying the concentration of the ligand also allowed us to optimize the arrangement of the AgNPs to achieve liquid mirrors exhibiting high specular reflectance. Scanning electron microscopy and atomic force microscopy confirmed that the particles of the liquid mirror were well-packed with an interparticle distance of merely 2 nm; thus, the interstices and surface roughness of the NPs were effectively minimized. As a result of decreased scattering loss, the reflectance in the shorter wavelength regime was increased effectively. The AgNP film was also sufficiently thick to reflect the light in the longer wavelength regime. In addition, we used three-dimensional finite-difference time domain simulations and experimental measurements to investigate the relationship between the localized surface plasmon resonance (LSPR) and the specular reflection of the liquid mirrors. By changing the packing density of the AgNPs, we found that the LSPR effect could yield either a specular reflection peak or dip at the LSPR wavelengths in the reflection spectra of the liquid mirrors. Relative to previously reported liquid mirrors, the reflectance of our system is obviously much greater, especially in the shorter wavelength regime. The average reflectance in the range from 400 to 1000 nm could reach 77%, comparable with that of mercury-based liquid mirrors.

  5. Spectral reflectance characteristics of different snow and snow-covered land surface objects and mixed spectrum fitting

    Science.gov (United States)

    Zhang, J.-H.; Zhou, Z.-M.; Wang, P.-J.; Yao, F.-M.; Yang, L.

    2011-01-01

    The field spectroradiometer was used to measure spectra of different snow and snow-covered land surface objects in Beijing area. The result showed that for a pure snow spectrum, the snow reflectance peaks appeared from visible to 800 nm band locations; there was an obvious absorption valley of snow spectrum near 1030 nm wavelength. Compared with fresh snow, the reflection peaks of the old snow and melting snow showed different degrees of decline in the ranges of 300~1300, 1700~1800 and 2200~2300 nm, the lowest was from the compacted snow and frozen ice. For the vegetation and snow mixed spectral characteristics, it was indicated that the spectral reflectance increased for the snow-covered land types(including pine leaf with snow and pine leaf on snow background), due to the influence of snow background in the range of 350~1300 nm. However, the spectrum reflectance of mixed pixel remained a vegetation spectral characteristic. In the end, based on the spectrum analysis of snow, vegetation, and mixed snow/vegetation pixels, the mixed spectral fitting equations were established, and the results showed that there was good correlation between spectral curves by simulation fitting and observed ones(correlation coefficient R2=0.9509).

  6. LBA-ECO CD-34 Hyperion 30-m Surface Reflectance, Amazon Basin: 2002-2005

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set contains 20 multispectral surface reflectance images collected by the EO-1 satellite Hyperion sensor at 30-m resolution and covering the entire Amazon...

  7. MODIS/Terra Surface Reflectance Daily L2G Global 250m SIN Grid V006

    Data.gov (United States)

    National Aeronautics and Space Administration — The MOD09GQ Version 6 product provides an estimate of the surface spectral reflectance of Terra MODIS 250 m bands 1-2 corrected for atmospheric conditions such as...

  8. LiDAR Relative Reflectivity Surface (2011) for the St. Thomas East End Reserve, St. Thomas

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This image represents a LiDAR (Light Detection & Ranging) 0.3x0.3 meter resolution relative seafloor reflectivity surface for the St. Thomas East End Reserve...

  9. CLPX-Satellite: EO-1 Hyperion Surface Reflectance, Snow-Covered Area, and Grain Size

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set consists of apparent surface reflectance, subpixel snow-covered area and grain size collected from the Hyperion hyperspectral imager. The Hyperion...

  10. NOAA Climate Data Record (CDR) of AVHRR Surface Reflectance, Version 4

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This dataset contains gridded daily surface reflectance and brightness temperatures derived from the Advanced Very High Resolution Radiometer (AVHRR) sensors onboard...

  11. ASTER L2 Surface Reflectance VNIR and Crosstalk Corrected SWIR V003

    Data.gov (United States)

    National Aeronautics and Space Administration — The ASTER L2 Surface Reflectance is a multi-file product that contains atmospherically corrected data for both the Visible Near-Infrared (VNIR) and Shortwave...

  12. MODIS/Aqua Surface Reflectance 8-Day L3 Global 250m SIN Grid V006

    Data.gov (United States)

    National Aeronautics and Space Administration — The MYD09Q1 Version 6 product provides an estimate of the surface spectral reflectance of AQUA MODIS Bands 1-2 corrected for atmospheric conditions such as gasses,...

  13. MODIS/Aqua Surface Reflectance Daily L3 Global 0.05Deg CMG V006

    Data.gov (United States)

    National Aeronautics and Space Administration — The MYD09CMG Version 6 product provides an estimate of the surface spectral reflectance of AQUA MODIS Bands 1-7 resampled to 5600 m pixel resolution and corrected...

  14. VIIRS/NPP Surface Reflectance Daily L3 Global 0.05 Deg CMG V001

    Data.gov (United States)

    National Aeronautics and Space Administration — The Visible Infrared Imaging Radiometer Suite (VIIRS) daily surface reflectance Climate Modeling Grid (VNP09CMG) Version 1 product provides an estimate of land...

  15. MODIS/Aqua Surface Reflectance 8-Day L3 Global 500m SIN Grid V006

    Data.gov (United States)

    National Aeronautics and Space Administration — The MYD09A1 Version 6 product provides an estimate of the surface spectral reflectance of AQUA MODIS Bands 1-7 corrected for atmospheric conditions such as gasses,...

  16. LBA-ECO LC-18 Hyperion 30-m Surface Reflectance, Mato Grosso, Brazil: July 2004

    Data.gov (United States)

    National Aeronautics and Space Administration — ABSTRACT: This image was collected by the Hyperion sensor on 10-July-2004 at 13:16:16 GMT. It was calibrated to apparent surface reflectance using the ACORN...

  17. LBA-ECO LC-18 Hyperion 30-m Surface Reflectance, Mato Grosso, Brazil: July 2004

    Data.gov (United States)

    National Aeronautics and Space Administration — This image was collected by the Hyperion sensor on 10-July-2004 at 13:16:16 GMT. It was calibrated to apparent surface reflectance using the ACORN atmospheric...

  18. Simulation and Measurement of Angle Resolved Reflectance from Black Si Surfaces

    DEFF Research Database (Denmark)

    Davidsen, Rasmus Schmidt; Wu, Kaiyu; Schmidt, Michael Stenbæk

    2015-01-01

    In this work angle-resolved reflectance from nanostructured Si surfaces realized by maskless RIE texturing has been simulated and measured. The simulation and experimental measurement data show the same trend. Experimentally a total reflectance below 1% for incident angles below 30o and specular...

  19. Backscattered EM-wave manipulation using low cost 1-bit reflective surface at W-band

    Science.gov (United States)

    Taher Al-Nuaimi, Mustafa K.; Hong, Wei; He, Yejun

    2018-04-01

    The design of low cost 1-bit reflective (non-absorptive) surfaces for manipulation of backscattered EM-waves and radar cross section (RCS) reduction at W-band is presented in this article. The presented surface is designed based on the reflection phase cancellation principle. The unit cell used to compose the proposed surface has an obelus (division symbol of short wire and two disks above and below) like shape printed on a grounded dielectric material. Using this unit cell, surfaces that can efficiently manipulate the backscattered RCS pattern by using the proposed obelus-shaped unit cell (as ‘0’ element) and its mirrored unit cell (as ‘1’ element) in one surface with a 180°  ±  35° reflection phase difference between their reflection phases are designed. The proposed surfaces can generate various kinds of backscattered RCS patterns, such as single, three, or four lobes or even a low-level (reduced RCS) diffused reflection pattern when those two unit cells are distributed randomly across the surface aperture. For experimental characterization purposes, a 50  ×  50 mm2 surface is fabricated and measured.

  20. Reflectance and Emissivity Spectra of Graphite as Potential Darkening Agent for Mercury from the UV to the TIR and its Comparison to Remote Sensing Measurements from MESSENGER and MERTIS on BepiColombo

    Science.gov (United States)

    Maturilli, A.; Helbert, J.; D'Amore, M.; Ferrari, S.; Hiesinger, H.

    2016-12-01

    For long time Mercury was considered a planet very similar to the Moon. Both are small rocky bodies in the inner solar system with thin exospheres and no large scale traces of recent geological activity. However Mercury's surface reflects much less sunlight than the Moon. Trying to explain the reasons for this difference, significant abundances of iron and titanium (and their oxides) were proposed for the Hermean surface. But the NASA MESSENGER instruments found only small abundances of iron, confirming earlier ground-based spectroscopy observations, and virtually no titanium. Therefore neither of the elements can account for this diversity. New analysis of MESSENGER data acquired for the darkest regions of Mercury's surface suggest that the unknown darkening material could be carbon, in particular as the mineral graphite (Peplowski et al., 2016) whose abundance in the darker regions is predicted to be 1 to 3 wt% higher than the surroundings. At the Planetary Spectroscopy Laboratory (PSL) of the Institute of Planetary Research (DLR, Berlin) we measured reflectance spectra for several phase angles of graphite, from UV to TIR spectral range (0.2 to 20 µm). Samples have been measured fresh and then after successive steps of heating at 400°C in vacuum for 8 hours. Following the same procedure, reflectance spectra of Komatiite (chosen as Mercury surface simulant, after Maturilli et al., 2014) was measured alone and mixed with few % of graphite to reproduce the results from Peplowski et al (2016). The results from this experiment can be compared to the data acquired from the MDIS and the MASCS instrument onboard the NASA MESSENGER mission. The same set of samples has been measured in emissivity, in vacuum (< 0.8 mbar) for successive cycles of several surface temperatures from 100°C to 400°C in the TIR spectral range (1 to 18 µm) in preparation for the emissivity spectra that will be collected by the Mercury Radiometer and Thermal Infrared Spectrometer (MERTIS), a

  1. Retrieval and Validation of aerosol optical properties from AHI measurements: impact of surface reflectance assumption

    Science.gov (United States)

    Lim, H.; Choi, M.; Kim, J.; Go, S.; Chan, P.; Kasai, Y.

    2017-12-01

    This study attempts to retrieve the aerosol optical properties (AOPs) based on the spectral matching method, with using three visible and one near infrared channels (470, 510, 640, 860nm). This method requires the preparation of look-up table (LUT) approach based on the radiative transfer modeling. Cloud detection is one of the most important processes for guaranteed quality of AOPs. Since the AHI has several infrared channels, which are very advantageous for cloud detection, clouds can be removed by using brightness temperature difference (BTD) and spatial variability test. The Yonsei Aerosol Retrieval (YAER) algorithm is basically utilized on a dark surface, therefore a bright surface (e.g., desert, snow) should be removed first. Then we consider the characteristics of the reflectance of land and ocean surface using three visible channels. The known surface reflectivity problem in high latitude area can be solved in this algorithm by selecting appropriate channels through improving tests. On the other hand, we retrieved the AOPs by obtaining the visible surface reflectance using NIR to normalized difference vegetation index short wave infrared (NDVIswir) relationship. ESR tends to underestimate urban and cropland area, we improved the visible surface reflectance considering urban effect. In this version, ocean surface reflectance is using the new cox and munk method which considers ocean bidirectional reflectance distribution function (BRDF). Input of this method has wind speed, chlorophyll, salinity and so on. Based on validation results with the sun-photometer measurement in AErosol Robotic NETwork (AERONET), we confirm that the quality of Aerosol Optical Depth (AOD) from the YAER algorithm is comparable to the product from the Japan Aerospace Exploration Agency (JAXA) retrieval algorithm. Our future update includes a consideration of improvement land surface reflectance by hybrid approach, and non-spherical aerosols. This will improve the quality of YAER

  2. Extracting Optical Fiber Background from Surface-Enhanced Raman Spectroscopy Spectra Based on Bi-Objective Optimization Modeling.

    Science.gov (United States)

    Huang, Jie; Shi, Tielin; Tang, Zirong; Zhu, Wei; Liao, Guanglan; Li, Xiaoping; Gong, Bo; Zhou, Tengyuan

    2017-08-01

    We propose a bi-objective optimization model for extracting optical fiber background from the measured surface-enhanced Raman spectroscopy (SERS) spectrum of the target sample in the application of fiber optic SERS. The model is built using curve fitting to resolve the SERS spectrum into several individual bands, and simultaneously matching some resolved bands with the measured background spectrum. The Pearson correlation coefficient is selected as the similarity index and its maximum value is pursued during the spectral matching process. An algorithm is proposed, programmed, and demonstrated successfully in extracting optical fiber background or fluorescence background from the measured SERS spectra of rhodamine 6G (R6G) and crystal violet (CV). The proposed model not only can be applied to remove optical fiber background or fluorescence background for SERS spectra, but also can be transferred to conventional Raman spectra recorded using fiber optic instrumentation.

  3. Simulated Fizeau ring fringes in transmission through spherical and plane reflected surfaces

    Science.gov (United States)

    Ramadan, W. A.; Wahba, H. H.

    2018-01-01

    In this paper, we present simulated Fizeau ring fringes. These fringes are constructed due to multiple reflection between highly reflected partially transmitted spherical and plane surfaces. The real paths of rays and consequently their amplitudes and phases have been determined when they reached the image plane. This plane is located at a certain distance above the interferometer. In these calculations, the impact of the image plane position, the radius of the spherical surface and the distance between the two surfaces on the fringe intensity distribution are investigated. A quite interesting result of our calculation is that the number of the interfered rays is varied and could be only two, even for a highly reflected surfaces. Three different estimated visualizations are included to give an overview imagination of the impact of the different parameter variation. These could be helpful for researchers for testing of spherical surfaces using interference-based methods.

  4. In Situ Nondestructive Analysis of Kalanchoe pinnata Leaf Surface Structure by Polarization-Modulation Infrared Reflection-Absorption Spectroscopy.

    Science.gov (United States)

    Hama, Tetsuya; Kouchi, Akira; Watanabe, Naoki; Enami, Shinichi; Shimoaka, Takafumi; Hasegawa, Takeshi

    2017-12-14

    The outermost surface of the leaves of land plants is covered with a lipid membrane called the cuticle that protects against various stress factors. Probing the molecular-level structure of the intact cuticle is highly desirable for understanding its multifunctional properties. We report the in situ characterization of the surface structure of Kalanchoe pinnata leaves using polarization-modulation infrared reflection-absorption spectroscopy (PM-IRRAS). Without sample pretreatment, PM-IRRAS measures the IR spectra of the leaf cuticle of a potted K. pinnata plant. The peak position of the CH 2 -related modes shows that the cuticular waxes on the leaf surface are mainly crystalline, and the alkyl chains are highly packed in an all-trans zigzag conformation. The surface selection rule of PM-IRRAS revealed the average orientation of the cuticular molecules, as indicated by the positive and negative signals of the IR peaks. This unique property of PM-IRRAS revealed that the alkyl chains of the waxes and the main chains of polysaccharides are oriented almost perpendicular to the leaf surface. The nondestructive, background-free, and environmental gas-free nature of PM-IRRAS allows the structure and chemistry of the leaf cuticle to be studied directly in its native environment.

  5. Reflection of diffuse light from dielectric one-dimensional rough surfaces.

    Science.gov (United States)

    González-Alcalde, Alma K; Méndez, Eugenio R; Terán, Emiliano; Cuppo, Fabio L S; Olivares, J A; García-Valenzuela, Augusto

    2016-03-01

    We study the reflection of diffuse light from 1D randomly rough dielectric interfaces. Results for the reflectance under diffuse illumination are obtained by rigorous numerical simulations and then contrasted with those obtained for flat surfaces. We also explore the possibility of using perturbation theories and conclude that they are limited for this type of study. Numerical techniques based on Kirchhoff approximation and reduced Rayleigh equations yield better results. We find that, depending on the refractive index contrast and nature of the irregularities, the roughness can increase or decrease the diffuse reflectance of the surface.

  6. NPP/VIIRS Atmospherically Corrected Surface Reflectance 6-Min L2 Swath 375m, 750m NRT

    Data.gov (United States)

    National Aeronautics and Space Administration — The VNP09_NRT is a Near Real Time (NRT) S-NPP/VIIRS 375 m, 750 m Atmospherically Corrected Surface Reflectance product. The NPP/VIIRS surface reflectance products...

  7. MODIS/Aqua Near Real Time (NRT) Surface Reflectance Daily L2G Global 250m SIN Grid

    Data.gov (United States)

    National Aeronautics and Space Administration — The MODIS Near Real Time (NRT) Surface Reflectance products are an estimate of the surface spectral reflectance as it would be measured at ground level in the...

  8. VIIRS/NPP Surface Reflectance Daily L2G Global 1km and 500m SIN Grid V001

    Data.gov (United States)

    National Aeronautics and Space Administration — The Visible Infrared Imaging Radiometer Suite (VIIRS) daily surface reflectance (VNP09GA) Version 1 product provides an estimate of land surface reflectance from the...

  9. Study on the surface density of surface-active substances through total-reflection X-ray absorption fine structure measurement.

    Science.gov (United States)

    Kashimoto, Kaoru; Takata, Youichi; Matsuda, Takashi; Ikeda, Norihiro; Matsubara, Hiroki; Takiue, Takanori; Aratono, Makoto; Tanida, Hajime; Watanabe, Iwao

    2006-09-26

    The total-reflection X-ray absorption fine structure (XAFS) method previously employed for the adsorption of dodecyltrimethylammonium bromide (DTAB) at the air/water interface was applied to that in the presence of NaBr. The surface concentration of the bromide ions Gamma(X)(B) of DTAB and NaBr was evaluated by using the Br K-edge absorption jump values of the total-reflection XAFS spectra and was compared to the corresponding value Gamma(H)(B) estimated from the dependence of surface tension on the bulk concentrations of DTAB m(1) and NaBr m(2). The Gamma(X)(B) values trace almost perfectly the Gamma(X)(B) versus m(1) curve up to a concentration near the critical micelle concentration (cmc) and deviate gradually above the concentration. This behavior is basically similar to that of the single DTAB system and ensures that the XAFS method is also applicable to the DTAB system, even in the presence of NaBr. In addition, this method was extended to the single nonionic amphiphile with covalently bonded bromine, and the surface concentrations of 6-bromo-1-hexanol (BrC6OH), Gamma(X)(1) and Gamma(H)(B), were evaluated and compared with each other. It was found that the Gamma(X)(1) value almost perfectly traces the Gamma(H)(1) versus m(1) curve, even at high surface concentrations. The excellent coincidence confirmed that the total-reflection XAFS method can be applied to the nonionic amphiphile system as well as a cationic surfactant with or without an added salt system. Finally, the difference between the Gamma(X)(B) and Gamma(H)(B) values observed in the DTAB with and without an added salt system is briefly described.

  10. The sparkle of the eye: the impact of ocular surface wetness on corneal light reflection.

    Science.gov (United States)

    Goto, Eiki; Dogru, Murat; Sato, Enrique Adan; Matsumoto, Yukihiro; Takano, Yoji; Tsubota, Kazuo

    2011-04-01

    To measure the sparkle of the human eye evaluated by the intensity of corneal light reflection in normal subjects and dry eye patients to investigate whether ocular surface wetness has an impact on the sparkle of the eye. Prospective case-control study. We examined a consecutive series of eight dry eye patients with Sjögren syndrome (SS, 15 eyes), as well as eight normal subjects (16 eyes). The specular corneal surface light reflection was quantitatively measured with an ophthalmic slit-lamp microscope and image capturing system under fixed conditions of light source, incident angle, and detector sensitivity. The intensity of images from subjects' corneal light reflection was quantified with image analysis software along with the measurement of grade of self-reported brilliancy of the eye, corneal fluorescein staining score, tear film break-up time, and Schirmer test value. The intensity of corneal light reflection was also compared before and after dry eye treatment. The mean intensity of corneal light reflection was significantly lower in dry eye patients (125.0 ± 40.1) than normal subjects (167.6 ± 36.6, P=.004). Grade of self-reported brilliancy of the eye, corneal fluorescein staining scores, tear film break-up time, and Schirmer test values showed good correlation to the intensity of corneal light reflection. After punctal plug treatment, the intensity of corneal light reflection significantly increased from 125.0 ± 40.1 to 167.2 ± 45.0 (Plight reflection representing the sparkle of the eye was significantly more intense in normal subjects compared to dry eye patients, and was increased after punctal plug treatment. The intensity of corneal light reflection appeared to correlate well with tear film stability, volume, and ocular surface desiccation. We showed that tears contributed not only to ocular surface wetness but also to the extent of the light reflection from the eye. Copyright © 2011 Elsevier Inc. All rights reserved.

  11. An investigation of the reflection of low energy electrons from the surfaces of layered transition metal dichalcogenides

    International Nuclear Information System (INIS)

    Smith, A.E.; Mohamed, M.H.; Wohlenberg, T.; Johnson, E.; Chadderton, L.T.; Moeller, P.J.

    1980-01-01

    Experimental measurements, using the total current spectroscopy (TCS) technique, on the energy dependence of the reflection of low energy electrons from clean surfaces of layered transition metal dichalcogenides are reported for the molybdenum semiconductor compounds 2H-MoS 2 and 2H-MoSe 2 . A simple model calculation involving both elastic and inelastic scattering is presented and correspondence established with the experimental spectra. In this picture information on the electronic band structure of the materials can then be extracted from the single particle component of the inelastic scattering. The model is extended to show that a feature in the 2H-MoS 2 experimental spectrum may be attributed to the excitation of an intermediate plasmon. (Auth.)

  12. Reflection of plane waves from free surface of a microstretch elastic ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    The problem of reflection of plane waves from free surface of a microstretch elastic solid half-space is studied. The energy ratios for ... axis is taken normal to free surface in downward direction. The region z > 0 is occupied by linear ... Superposed dots on the right hand side of above equations denote the second partial ...

  13. Temperature comparison of different reflective surfaces of a solar thermal collector

    Science.gov (United States)

    Koh, Yit Yan; Chua, Yaw Long; Chin, Kiat Keong

    2017-09-01

    With the rapid depletion of fossil fuels, the search for application of alternative energy sources becomes more important than ever before. Solar energy has been identified as one of the major renewable energy that will contribute to power generation is years to come. There are two major categories of solar energy applications. Solar thermal collector is one of it. This paper presents an investigation on the effect of different reflecting surfaces on solar thermal collector. Three different reflective surfaces were applied on the surface of the solar thermal collector. Data was collected and analyzed. From the results, the aluminum mirror sheet performed best.

  14. Reflections

    Directory of Open Access Journals (Sweden)

    Joanne Embree

    2001-01-01

    Full Text Available Ideally, editorials are written one to two months before publication in the Journal. It was my turn to write this one. I had planned to write the first draft the evening after my clinic on Tuesday, September 11. It didn't get done that night or during the next week. Somehow, the topic that I had originally chosen just didn't seem that important anymore as I, along my friends and colleagues, reflected on the changes that the events of that day were likely to have on our lives.

  15. A high-reflective surface measurement method based on conoscopic holography technology

    Science.gov (United States)

    Cheng, Xu; Li, ZhongWei; Shi, YuSheng; Zhao, HengShuang; Zhan, Guomin

    2014-11-01

    Measuring high-reflective surfaces using optical method is always a big challenging problem. This paper presents a high-reflective surface measurement method based on conoscopic holography technology using a 4D motion platform equipped with a conoscopic holography optical probe. There are two key problems needed to solve before the automate scan of the complex shape surface: the coordinate calibration and the path planning. To improve the calibration efficiency and accuracy, the coordinate calibration is divided into two parts: the rough calibration and the accurate registration. The path planning consists of two aspects including: the path points generation and the path points verification. In addition, by scanning the objects having high-reflective surfaces, such as the metal blades, coins and other work-pieces, the efficiency of the measurement method has been verified.

  16. Predicting foliar biochemistry of tea (Camellia sinensis) using reflectance spectra measured at powder, leaf and canopy levels

    NARCIS (Netherlands)

    Bian, B.M.; Skidmore, A.K.; Schlerf, M.; Wang, T.; Liu, X.; Zeng, R.; Fei, T.

    2013-01-01

    Some biochemical compounds are closely related with the quality of tea (Camellia sinensis (L.)). In this study, the concentration of these compounds including total tea polyphenols, free amino acids and soluble sugars were estimated using reflectance spectroscopy at three different levels: powder,

  17. Estimates of radiance reflected towards the zenith at the surface of the sea

    Directory of Open Access Journals (Sweden)

    E. Aas

    2010-10-01

    Full Text Available Remote sensing of water colour by ship-mounted sensors represents an important tool for the validation of satellite products and the monitoring of water quality. The recorded radiance from the sea has to be corrected for the surface-reflected radiance from sun and sky in order to obtain the water-leaving radiance. Here the simple case of radiance reflected towards the zenith is studied. A set of observed sky radiance and solar irradiance data from Oslo has been used together with a Gaussian slope distribution for the sea surface in order to estimate the reflected radiance. The spectral range studied is 405–650 nm, the solar zenith angles are in the range 37°–76°, and the wind speeds are up to 10 m s−1. The analysis of the results show that the reflected radiance has to be separated into three contributions: sky radiance and sun rays reflected at the foam-free surface and irradiance reflected by whitecaps and foam. It is then demonstrated that by using four input values, namely the downward irradiance, the sky radiance from the zenith, the solar zenith angle and the wind speed, it is possible to obtain by simple expressions estimates of the reflected radiance that only differ from the former calculated values by relative errors of less than 5%. The analysis also indicates that for the spectral range studied neither the water-leaving radiance nor the surface-reflected radiance can be disregarded relative to the other one in the Case 2 waters of the Oslofjord-Skagerrak area. The results form a first step towards the study of reflected radiance in viewing angles differing from the nadir direction.

  18. Suppressing light reflection from polycrystalline silicon thin films through surface texturing and silver nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Akhter, Perveen [Department of Physics, University at Albany-SUNY, Albany, New York 12222 (United States); Huang, Mengbing, E-mail: mhuang@albany.edu; Kadakia, Nirag; Spratt, William; Malladi, Girish; Bakhru, Hassarum [SUNY College of Nanoscale Science and Engineering, Albany, New York 12203 (United States)

    2014-09-21

    This work demonstrates a novel method combining ion implantation and silver nanostructures for suppressing light reflection from polycrystalline silicon thin films. Samples were implanted with 20-keV hydrogen ions to a dose of 10¹⁷/cm², and some of them received an additional argon ion implant to a dose of 5×10¹⁵ /cm² at an energy between 30 and 300 keV. Compared to the case with a single H implant, the processing involved both H and Ar implants and post-implantation annealing has created a much higher degree of surface texturing, leading to a more dramatic reduction of light reflection from polycrystalline Si films over a broadband range between 300 and 1200 nm, e.g., optical reflection from the air/Si interface in the AM1.5 sunlight condition decreasing from ~30% with an untextured surface to below 5% for a highly textured surface after post-implantation annealing at 1000°C. Formation of Ag nanostructures on these ion beam processed surfaces further reduces light reflection, and surface texturing is expected to have the benefit of diminishing light absorption losses within large-size (>100 nm) Ag nanoparticles, yielding an increased light trapping efficiency within Si as opposed to the case with Ag nanostructures on a smooth surface. A discussion of the effects of surface textures and Ag nanoparticles on light trapping within Si thin films is also presented with the aid of computer simulations.

  19. Methods of creating solar-reflective nonwhite surfaces and their application to residential roofing materials

    Energy Technology Data Exchange (ETDEWEB)

    Levinson, Ronnen; Berdahl, Paul; Akbari, Hashem [Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Miller, William [Oak Ridge National Laboratory, PO Box 2008, MS6070, Oak Ridge, TN 37831 (United States); Joedicke, Ingo [ISP Mineral Products, Inc., 34 Charles St., Hagerstown, MD 21740 (United States); Reilly, Joseph [American Rooftile Coatings, 250 Viking Avenue, Brea, CA 92821 (United States); Suzuki, Yoshi [MCA Clay Tile, 1985 Sampson Avenue, Corona, CA 92879 (United States); Vondran, Michelle [Steelscape Inc., 1200 Arrow Route, Rancho Cucamonga, CA 91730 (United States)

    2007-02-15

    We describe methods for creating solar-reflective nonwhite surfaces and their application to a wide variety of residential roofing materials, including metal, clay tile, concrete tile, wood, and asphalt shingle. Reflectance in the near-infrared (NIR) spectrum (0.7-2.5{mu}m) is maximized by coloring a topcoat with pigments that weakly absorb and (optionally) strongly backscatter NIR radiation, and by adding an NIR-reflective basecoat (e.g., one colored with titanium dioxide rutile white) if both the topcoat and the substrate weakly reflect NIR radiation. Coated steel and glazed clay-tile roofing products achieved NIR reflectances of up to 0.50 and 0.75, respectively, using only cool topcoats. Gray-cement concrete tiles achieved NIR reflectances as high as 0.60 with coatings colored by NIR-scattering pigments. Such tiles could attain NIR reflectances of up to 0.85 by overlaying a white basecoat with a topcoat colored by NIR-transparent organic pigments. Granule-surfaced asphalt shingles achieved NIR reflectances as high as 0.45 when the granules were covered with a white basecoat and a cool color topcoat. (author)

  20. Sensitivity analysis of 6S-based look-up table for surface reflectance retrieval

    Science.gov (United States)

    Lee, Chang Suk; Yeom, Jong Min; Lee, Han Lim; Kim, Jae-Jin; Han, Kyung-Soo

    2015-02-01

    We created a look-up table (LUT) based on the Second Simulation of the Satellite Signal in the Solar Spectrum (6S) radiative transfer model, which reduces large errors in the surface reflectance retrieval under high solar zenith angle (SZA) conditions. The LUT was calculated in 10° SZA intervals containing pre-computed atmospheric correction coefficients as a function of discretized pre-defined input parameters. In order to validate the performance of the LUT, we compared the retrieved surface reflectance using the LUT against a retrieval performed using the simplified method of atmospheric correction (SMAC). These results were validated against MODIS reflectance data (MOD09). The surface reflectance obtained using the LUT was highly correlated with the MOD09, with a coefficient of determination (R2) of 0.88 (red band) and 0.94 (NIR). The retrieved surface reflectance had a root mean-squared error of 0.0132 (red band) and 0.0191 (NIR). Accuracy of surface reflectance retrieved using our LUT with a 10° SZA interval was better than that of the obtained using SMAC. However, certain errors were still present particularly at high SZAs. In order to increase the accuracy at high SZAs, new LUT was computed with a finer SZA interval (5°) at high SZAs. In both red and NIR bands, the R2, fine SZA interval LUT (0.92) were compared to the coarse SZA interval LUT (0.74) of around 65°. Additionally, the run time for surface reflectance retrievals with our LUT was almost comparable to that of the SMAC, an operational model. This study demonstrates that proper SZAs interval for making LUT in high SZA range.

  1. A review on data and predictions of water dielectric spectra for calculations of van der Waals surface forces.

    Science.gov (United States)

    Wang, Jianlong; Nguyen, Anh V

    2017-12-01

    Van der Waals forces are one of the important components of intermolecular, colloidal and surface forces governing many phenomena and processes. The latest examples include the colloidal interactions between hydrophobic colloids and interfaces in ambient (non-degassed) water in which dissolved gases and nanobubbles are shown to affect the van der Waals attractions significantly. The advanced computation of van der Waals forces in aqueous systems by the Lifshitz theory requires reliable data for water dielectric spectra. In this paper we review the available predictions of water dielectric spectra for calculating colloidal and surface van der Waals forces. Specifically, the available experimental data for the real and imaginary parts of the complex dielectric function of liquid water in the microwave, IR and UV regions and various corresponding predictions of the water spectra are critically reviewed. The data in the UV region are critical, but the available predictions are still based on the outdated data obtained in 1974 (for frequency only up to 25.5eV). We also reviewed and analysed the experimental data obtained for the UV region in 2000 (for frequency up to 50eV) and 2015 (for frequency up to 100eV). The 1974 and 2000 data require extrapolations to higher frequencies needed for calculating the van der Waals forces but remain inaccurate. Our analysis shows that the latest data of 2015 do not require the extrapolation and can be used to reliably calculate van der Waals forces. The most recent water dielectric spectra gives the (non-retarded) Hamaker constant, A=5.20×10 -20 J, for foam films of liquid water. This review provides the most updated and reliable water dielectric spectra to compute van der Waals forces in aqueous systems. Copyright © 2017 Elsevier B.V. All rights reserved.

  2. Iterative discrete ordinates solution of the equation for surface-reflected radiance

    Science.gov (United States)

    Radkevich, Alexander

    2017-11-01

    This paper presents a new method of numerical solution of the integral equation for the radiance reflected from an anisotropic surface. The equation relates the radiance at the surface level with BRDF and solutions of the standard radiative transfer problems for a slab with no reflection on its surfaces. It is also shown that the kernel of the equation satisfies the condition of the existence of a unique solution and the convergence of the successive approximations to that solution. The developed method features two basic steps: discretization on a 2D quadrature, and solving the resulting system of algebraic equations with successive over-relaxation method based on the Gauss-Seidel iterative process. Presented numerical examples show good coincidence between the surface-reflected radiance obtained with DISORT and the proposed method. Analysis of contributions of the direct and diffuse (but not yet reflected) parts of the downward radiance to the total solution is performed. Together, they represent a very good initial guess for the iterative process. This fact ensures fast convergence. The numerical evidence is given that the fastest convergence occurs with the relaxation parameter of 1 (no relaxation). An integral equation for BRDF is derived as inversion of the original equation. The potential of this new equation for BRDF retrievals is analyzed. The approach is found not viable as the BRDF equation appears to be an ill-posed problem, and it requires knowledge the surface-reflected radiance on the entire domain of both Sun and viewing zenith angles.

  3. Using visible and near-infrared diffuse reflectance spectroscopy for predicting soil properties based on regression with peaks parameters as derived from continuum-removed spectra

    Science.gov (United States)

    Vasat, Radim; Klement, Ales; Jaksik, Ondrej; Kodesova, Radka; Drabek, Ondrej; Boruvka, Lubos

    2014-05-01

    Visible and near-infrared diffuse reflectance spectroscopy (VNIR-DRS) provides a rapid and inexpensive tool for simultaneous prediction of a variety of soil properties. Usually, some sophisticated multivariate mathematical or statistical methods are employed in order to extract the required information from the raw spectra measurement. For this purpose especially the Partial least squares regression (PLSR) and Support vector machines (SVM) are the most frequently used. These methods generally benefit from the complexity with which the soil spectra are treated. But it is interesting that also techniques that focus only on a single spectral feature, such as a simple linear regression with selected continuum-removed spectra (CRS) characteristic (e.g. peak depth), can often provide competitive results. Therefore, we decided to enhance the potential of CRS taking into account all possible CRS peak parameters (area, width and depth) and develop a comprehensive methodology based on multiple linear regression approach. The eight considered soil properties were oxidizable carbon content (Cox), exchangeable (pHex) and active soil pH (pHa), particle and bulk density, CaCO3 content, crystalline and amorphous (Fed) and amorphous Fe (Feox) forms. In four cases (pHa, bulk density, Fed and Feox), of which two (Fed and Feox) were predicted reliably accurately (0.50 0.80). Acknowledgment: Authors acknowledge the financial support of the Ministry of Agriculture of the Czech Republic (grant No. QJ1230319).

  4. Determination of the Ability to Measure Traces of Water in Dehydrated Residues of Waste Water by IR Diffuse Reflectance Spectra

    Science.gov (United States)

    Pratsenka, S. V.; Voropai, E. S.; Belkin, V. G.

    2018-01-01

    Rapid measurement of the moisture content of dehydrated residues is a critical problem, the solution of which will increase the efficiency of treatment facilities and optimize the process of applying flocculants. The ability to determine the moisture content of dehydrated residues using a meter operating on the IR reflectance principle was confirmed experimentally. The most suitable interference filters were selected based on an analysis of the obtained diffuse reflectance spectrum of the dehydrated residue in the range 1.0-2.7 μm. Calibration curves were constructed and compared for each filter set. A measuring filter with a transmittance maximum at 1.19 μm and a reference filter with a maximum at 1.3 μm gave the best agreement with the laboratory measurements.

  5. Processing of phase pure and dense bulk EuTiO.sub.3./sub. ceramics and their infrared reflectivity spectra

    Czech Academy of Sciences Publication Activity Database

    Kachlik, M.; Máca, K.; Goian, Veronica; Kamba, Stanislav

    2012-01-01

    Roč. 74, MAY (2012), s. 16-18 ISSN 0167-577X R&D Projects: GA ČR GD202/09/H041; GA ČR(CZ) GA202/09/0682 Grant - others:GAUK(CZ) SVV-2011-263303 Institutional research plan: CEZ:AV0Z10100520 Keywords : functional ceramics, * europium titanate * sintering * infrared reflectivity Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.224, year: 2012

  6. Scaling properties of velocity and temperature spectra above the surface friction layer in a convective atmospheric boundary layer

    Directory of Open Access Journals (Sweden)

    K. G. McNaughton

    2007-06-01

    Full Text Available We report velocity and temperature spectra measured at nine levels from 1.42 meters up to 25.7 m over a smooth playa in Western Utah. Data are from highly convective conditions when the magnitude of the Obukhov length (our proxy for the depth of the surface friction layer was less than 2 m. Our results are somewhat similar to the results reported from the Minnesota experiment of Kaimal et al. (1976, but show significant differences in detail. Our velocity spectra show no evidence of buoyant production of kinetic energy at at the scale of the thermal structures. We interpret our velocity spectra to be the result of outer eddies interacting with the ground, not "local free convection".

    We observe that velocity spectra represent the spectral distribution of the kinetic energy of the turbulence, so we use energy scales based on total turbulence energy in the convective boundary layer (CBL to collapse our spectra. For the horizontal velocity spectra this scale is (zi εo2/3, where zi is inversion height and εo is the dissipation rate in the bulk CBL. This scale functionally replaces the Deardorff convective velocity scale. Vertical motions are blocked by the ground, so the outer eddies most effective in creating vertical motions come from the inertial subrange of the outer turbulence. We deduce that the appropriate scale for the peak region of the vertical velocity spectra is (z εo2/3 where z is height above ground. Deviations from perfect spectral collapse under these scalings at large and small wavenumbers are explained in terms of the energy transport and the eddy structures of the flow.

    We find that the peaks of the temperature spectra collapse when wavenumbers are scaled using (z1/2 zi1/2. That is, the lengths of the thermal structures depend on both the lengths of the

  7. Combined quantum mechanics (TDDFT) and classical electrodynamics (Mie theory) methods for calculating surface enhanced Raman and hyper-Raman spectra.

    Science.gov (United States)

    Mullin, Jonathan; Valley, Nicholas; Blaber, Martin G; Schatz, George C

    2012-09-27

    Multiscale models that combine quantum mechanics and classical electrodynamics are presented, which allow for the evaluation of surface-enhanced Raman (SERS) and hyper-Raman scattering spectra (SEHRS) for both chemical (CHEM) and electrodynamic (EM) enhancement mechanisms. In these models, time-dependent density functional theory (TDDFT) for a system consisting of the adsorbed molecule and a metal cluster fragment of the metal particle is coupled to Mie theory for the metal particle, with the surface of the cluster being overlaid with the surface of the metal particle. In model A, the electromagnetic enhancement from plasmon-excitation of the metal particle is combined with the chemical enhancement associated with a static treatment of the molecule-metal structure to determine overall spectra. In model B, the frequency dependence of the Raman spectrum of the isolated molecule is combined with the enhancements determined in model A to refine the enhancement estimate. An equivalent theory at the level of model A is developed for hyper-Raman spectra calculations. Application to pyridine interacting with a 20 nm diameter silver sphere is presented, including comparisons with an earlier model (denoted G), which combines plasmon enhanced fields with gas-phase Raman (or hyper-Raman) spectra. The EM enhancement factor for spherical particles at 357 nm is found to be 10(4) and 10(6) for SERS and SEHRS, respectively. Including both chemical and electromagnetic mechanisms at the level of model A leads to enhancements on the order of 10(4) and 10(9) for SERS and SEHRS.

  8. WREP: A wavelet-based technique for extracting the red edge position from reflectance spectra for estimating leaf and canopy chlorophyll contents of cereal crops

    Science.gov (United States)

    Li, Dong; Cheng, Tao; Zhou, Kai; Zheng, Hengbiao; Yao, Xia; Tian, Yongchao; Zhu, Yan; Cao, Weixing

    2017-07-01

    Red edge position (REP), defined as the wavelength of the inflexion point in the red edge region (680-760 nm) of the reflectance spectrum, has been widely used to estimate foliar chlorophyll content from reflectance spectra. A number of techniques have been developed for REP extraction in the past three decades, but most of them require data-specific parameterization and the consistence of their performance from leaf to canopy levels remains poorly understood. In this study, we propose a new technique (WREP) to extract REPs based on the application of continuous wavelet transform to reflectance spectra. The REP is determined by the zero-crossing wavelength in the red edge region of a wavelet transformed spectrum for a number of scales of wavelet decomposition. The new technique is simple to implement and requires no parameterization from the user as long as continuous wavelet transforms are applied to reflectance spectra. Its performance was evaluated for estimating leaf chlorophyll content (LCC) and canopy chlorophyll content (CCC) of cereal crops (i.e. rice and wheat) and compared with traditional techniques including linear interpolation, linear extrapolation, polynomial fitting and inverted Gaussian. Our results demonstrated that WREP obtained the best estimation accuracy for both LCC and CCC as compared to traditional techniques. High scales of wavelet decomposition were favorable for the estimation of CCC and low scales for the estimation of LCC. The difference in optimal scale reveals the underlying mechanism of signature transfer from leaf to canopy levels. In addition, crop-specific models were required for the estimation of CCC over the full range. However, a common model could be built with the REPs extracted with Scale 5 of the WREP technique for wheat and rice crops when CCC was less than 2 g/m2 (R2 = 0.73, RMSE = 0.26 g/m2). This insensitivity of WREP to crop type indicates the potential for aerial mapping of chlorophyll content between growth seasons

  9. Surface reflectance of Antarctic bryophytes and protection from UV and visible light

    International Nuclear Information System (INIS)

    Robinson, S.A.; Wasley, J.; Turnbull, J.

    2000-01-01

    Full text: As well as determining the amount of solar radiation available for photosynthesis, the surface reflectance and absorptance characteristics of plants are their first defence against damaging effects of solar radiation. The solar spectrum can be damaging to plants in many ways. At shorter wavelengths, UV-B (280-320 nm) radiation can cause lesions in nucleic acid and proteins. Excess levels of visible radiation (400-750) can cause photoinhibition whilst high absorbtance of longer wavelengths (>750) leads to increases in temperature that can be detrimental in some environments. The adaptation of surface reflectance properties of vascular plants to particular environments are well known in some ecosystems. For example in desert ecosystems pubescent leaf surfaces that increase reflectance are common and have been demonstrated to be important to protection from photoinhibition. The epidermal characteristics of some plants are also known to change in absorptance, due to the accumulation of specific compounds. For example flavonoids which are effective screens against UV-B radiation, increase upon exposure to UV-B radiation. In this study we surveyed the natural variability in surface reflectance in mosses growing in continental Antarctica. Antarctica is experiencing large increases in incident UV-B radiation due to reductions in concentrations of stratospheric ozone. Additionally over the summer months (November January), when moss is exposed to direct sunlight, levels of visible solar radiation are also high, increasing the likelihood of photoinhibitory damage in moss. Our aim in this study is to describe the natural variability in the surface reflectance characteristics of moss, such that we have a baseline with which to assess future changes in response to changes in global climate, and imposed experimental treatments, and also to develop hypotheses with respect to how mosses have adapted to the cold and arid antarctic environment. Variability in surface

  10. Application of the complex cepstrum to the location of acoustic sources near reflective surfaces

    Science.gov (United States)

    Fuller, C. R.; Tavakkoli, S.; Elliott, K. B.; Hurst, C. J.; Obrien, W. F.

    1987-01-01

    The complex cepstrum is used to correct bearing estimations of acoustic sources in the presence of a reflective surface. An automated liftering procedure is used which zeros out a block portion of the cepstrum including the echo information. The problem of the resulting distortion is alleviated by applying a coherence criterion to the recovered direct signals at each microphone. Thus to a large degree the interactive nature of cepstral processing is overcome for this application. For the test signals and geometries considered the cepstrum is shown to accurately correct for bearing errors in acoustic signals contaminated with reflections from nearby surfaces.

  11. Argon and krypton Auger spectra induced by ion bombardment of aluminium and silicon surfaces

    International Nuclear Information System (INIS)

    Nixon, A.P.; Gallon, T.E.; Yousif, F.; Matthew, J.A.D.

    1994-01-01

    Measurements are reported of Auger (autoionization) spectra of Ar and Kr produced by bombarding Al and Si substrates with Ar + and Kr + ions in the 110 eV-5 keV energy range. These are shown to be consistent with the simple Doppler model suggested, for Ne and Al and Si, in a previous paper. Once corrected using the model, the observed Auger energies are shown to correspond to theoretical predictions produced using Dirac-Fock calculations. (Author)

  12. Numerical study of three-dimensional sound reflection from corrugated surface waves.

    Science.gov (United States)

    Choo, Youngmin; Song, H C; Seong, Woojae

    2016-10-01

    When a sound wave propagates in a water medium bounded by a smooth surface wave, reflection from a wave crest can lead to focusing and result in rapid variation of the received waveform as the surface wave moves [Tindle, Deane, and Preisig, J. Acoust. Soc. Am. 125, 66-72 (2009)]. In prior work, propagation paths have been constrained to be in a plane parallel to the direction of corrugated surface waves, i.e., a two-dimensional (2-D) propagation problem. In this paper, the azimuthal dependence of sound propagation as a three-dimensional (3-D) problem is investigated using an efficient, time-domain Helmholtz-Kirchhoff integral formulation. When the source and receiver are in the plane orthogonal to the surface wave direction, the surface wave curvature vanishes in conventional 2-D treatments and the flat surface simply moves up and down, resulting in minimal temporal variation of the reflected signal intensity. On the other hand, the 3-D propagation analysis reveals that a focusing phenomenon occurs in the reflected signal due to the surface wave curvature formed along the orthogonal plane, i.e., out-of-plane scattering.

  13. Early Evaluation of the VIIRS Calibration, Cloud Mask and Surface Reflectance Earth Data Records

    Science.gov (United States)

    Vermote, Eric; Justice, Chris; Csiszar, Ivan

    2014-01-01

    Surface reflectance is one of the key products fromVIIRS and as withMODIS, is used in developing several higherorder land products. The VIIRS Surface Reflectance (SR) Intermediate Product (IP) is based on the heritageMODIS Collection 5 product (Vermote, El Saleous, & Justice, 2002). The quality and character of surface reflectance depend on the accuracy of the VIIRS Cloud Mask (VCM), the aerosol algorithms and the adequate calibration of the sensor. The focus of this paper is the early evaluation of the VIIRS SR product in the context of the maturity of the operational processing system, the Interface Data Processing System (IDPS). After a brief introduction, the paper presents the calibration performance and the role of the surface reflectance in calibration monitoring. The analysis of the performance of the cloud mask with a focus on vegetation monitoring (no snow conditions) shows typical problems over bright surfaces and high elevation sites. Also discussed is the performance of the aerosol input used in the atmospheric correction and in particular the artifacts generated by the use of the Navy Aerosol Analysis and Prediction System. Early quantitative results of the performance of the SR product over the AERONET sites showthatwith the fewadjustments recommended, the accuracy iswithin the threshold specifications. The analysis of the adequacy of the SR product (Land PEATE adjusted version) in applications of societal benefits is then presented. We conclude with a set of recommendations to ensure consistency and continuity of the JPSS mission with the MODIS Land Climate Data Record.

  14. Homogeneity of Surface Sites in Supported Single-Site Metal Catalysts: Assessment with Band Widths of Metal Carbonyl Infrared Spectra.

    Science.gov (United States)

    Hoffman, Adam S; Fang, Chia-Yu; Gates, Bruce C

    2016-10-06

    Determining and controlling the uniformity of isolated metal sites on surfaces of supports are central goals in investigations of single-site catalysts because well-defined species provide opportunities for fundamental understanding of the surface sites. CO is a useful probe of surface metal sites, often reacting with them to form metal carbonyls, the infrared spectra of which provide insights into the nature of the sites and the metal-support interface. Metals bonded to various support surface sites give broad bands in the spectra, and when narrow bands are observed, they indicate a high degree of uniformity of the metal sites. Much recent work on single-site catalysts has been done with supports that are inherently nonuniform, giving supported metal species that are therefore nonuniform. Herein we summarize values of ν CO data characterizing supported iridium gem-dicarbonyls, showing that the most nearly uniform of them are those supported on zeolites and the least uniform are those supported on metal oxides. Guided by ν CO data of supported iridium gem-dicarbonyls, we have determined new, general synthesis methods to maximize the degree of uniformity of iridium species on zeolites and on MgO. We report results for a zeolite HY-supported iridium gem-dicarbonyl with full width at half-maximum values of only 4.6 and 5.2 cm -1 characterizing the symmetric and asymmetric CO stretches and implying that this is the most nearly uniform supported single-site metal catalyst.

  15. In situ probing of surface hydrides on hydrogenated amorphous silicon using attenuated total reflection infrared spectroscopy

    CERN Document Server

    Kessels, W M M; Sanden, M C M; Aydil, E S

    2002-01-01

    An in situ method based on attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR) is presented for detecting surface silicon hydrides on plasma deposited hydrogenated amorphous silicon (a-Si:H) films and for determining their surface concentrations. Surface silicon hydrides are desorbed by exposing the a-Si:H films to low energy ions from a low density Ar plasma and by comparing the infrared spectrum before and after this low energy ion bombardment, the absorptions by surface hydrides can sensitively be separated from absorptions by bulk hydrides incorporated into the film. An experimental comparison with other methods that utilize isotope exchange of the surface hydrogen with deuterium showed good agreement and the advantages and disadvantages of the different methods are discussed. Furthermore, the determination of the composition of the surface hydrogen bondings on the basis of the literature data on hydrogenated crystalline silicon surfaces is presented, and quantification of the h...

  16. Observation on Surface Change of Fragile Glass: Temperature - Time Dependence Studied by X-Ray Reflectivity

    International Nuclear Information System (INIS)

    Kikkawa, Hiroyuki; Kitahara, Amane; Takahashi, Isao

    2004-01-01

    The structural change of a fragile glass surface close to the glass transition temperature Tg is studied by using X-ray reflectivity. Measurements were performed on surfaces of maltitol, which is a typical polyalcohol fragile glass with Tg = 320K. Upon both heating and cooling, we find the following features which are also noticed in silicate glass surfaces: (i) On heating, the surface morphology indicates a variation at temperatures below Tg; (ii) A drastic increase in surface roughness occurs at a temperature about 333K on heating, which is 13K higher than Tg; (iii) During the cooling of the sample, formation of a low-density surface layer (3nm at 293K) is observed. Prior to the crystallization, nm - μm sized domains were grown at the surface, which might not be reported for other glasses

  17. Orientation and Optical Polarized Spectra (380–900 nm of Methylene Blue Crystals on a Glass Surface

    Directory of Open Access Journals (Sweden)

    Maja D. Milošević

    2013-01-01

    Full Text Available The crystallographic directions of the crystal toward the vector of polarized light can accurately be positioned, so the information that we gain from polarized spectra can be consistently interpreted according to known crystal structure. The orientation and optical properties of the methylene blue (MB crystals were analyzed by XRD, XRPD, and polarized VIS-NIR spectroscopy. Cationic dye, MB, was polymerized into crystals on a glass slate. The blue color crystals showed pronounced dichroism, twin lamellar structure and bladed to fibrous habit. According to XRD data, [010] direction lies perpendicular to the crystal surface, so we recognized it as (0k0 face, while [100] and [001] directions coincide with crystal elongation and crystal thickness respectively. In this paper, the polarized spectra of MB crystal are presented, measured with the aim of acquisition of referent values, which could be helpful for the identification of MB molecular aggregation.

  18. METHODS OF ANALYSIS AND CLASSIFICATION OF THE COMPONENTS OF GRAIN MIXTURES BASED ON MEASURING THE REFLECTION AND TRANSMISSION SPECTRA

    Directory of Open Access Journals (Sweden)

    Artem O. Donskikh*

    2017-10-01

    Full Text Available The paper considers methods of classification of grain mixture components based on spectral analysis in visible and near-infrared wavelength ranges using various measurement approaches - reflection, transmission and combined spectrum methods. It also describes the experimental measuring units used and suggests the prototype of a multispectral grain mixture analyzer. The results of the spectral measurement were processed using neural network based classification algorithms. The probabilities of incorrect recognition for various numbers of spectral parts and combinations of spectral methods were estimated. The paper demonstrates that combined usage of two spectral analysis methods leads to higher classification accuracy and allows for reducing the number of the analyzed spectral parts. A detailed description of the proposed measurement device for high-performance real-time multispectral analysis of the components of grain mixtures is given.

  19. Exceptionally slow rise in differential reflectivity spectra of excitons in GaN: effect of excitation-induced dephasing

    International Nuclear Information System (INIS)

    Stanton, C.J.; Kenrow, J.; El Sayed, K.; Jho, Y.D.; Kim, D.S.; Song, J.J.; Fischer, Arthur Joseph

    2004-01-01

    Femtosecond differential reflectivity spectroscopy (DRS) and four-wave mixing (FWM) experiments were performed simultaneously to study the initial temporal dynamics of the exciton line-shapes in GaN epilayers. Beats between the A-B excitons were found only for positive time delay in both DRS and FWM experiments. The rise time at negative time delay for the DRS was much slower than the FWM signal or differential transmission spectroscopy at the exciton resonance. A numerical solution of a six band semiconductor Bloch equation model including nonlinearities at the Hartree-Fock level shows that this slow rise in the DRS results from excitation induced dephasing, that is, the strong density dependence of the dephasing time which changes with the laser excitation energy.

  20. Negligible water surface charge determined using Kelvin probe and total reflection X-ray fluorescence techniques.

    Science.gov (United States)

    Shapovalov, Vladimir L; Möhwald, Helmuth; Konovalov, Oleg V; Knecht, Volker

    2013-09-07

    The water surface charge has been extensively debated in recent decades. Electrophoretic mobilities of air bubbles in water and disjoining pressures between the surfaces of aqueous films suggest that the surface of water exhibits a significant negative charge. This is commonly attributed to a strong adsorption of hydroxide ions at the interface, though spectroscopic measurements and simulation studies suggest surface depletion of hydroxide ions. Alternatively, the negative surface charge could arise from surface contamination with trace charged surfactants. We have probed the variation in the surface charge of water with pH by measuring surface potentials using the Kelvin probe technique. Independently, the abundance in the interfacial layer of "reporter ions" (Rb(+) and Br(-)), which must be affected by a charged surface, has been monitored using the total reflection X-ray fluorescence (TRXF) technique. Special care was taken to prove the high sensitivity of this technique as well as to avoid surface contaminants. The magnitude of the surface charge was found to be below 1 e per 500 nm(2) (TRXF). No evidence of variations in the surface potential between pH 2-3 and pH 9-12 was detected within the accuracies of the methods (5 mV for Kelvin probe and 2 mV for TRXF). Hence, our findings suggest that the clean water surface exhibits negligible charge in a wide pH range.

  1. High-resolution x-ray scatter and reflectivity study of sputtered IR surfaces

    DEFF Research Database (Denmark)

    Christensen, Finn Erland; Abdali, S.; Hornstrup, Allan

    1993-01-01

    In recent years there has been an increased interest in the possible use of Ir as the reflecting surface in X-ray telescope programs. An X-ray study of such surfaces produced by sputtering of Ir on highly polished Zerodur flats is presented here. The study was performed using Fe K(alpha) 1 (6...... result shows that an Ir coating can be produced with nominal bulk density....

  2. Impact of MODIS Sensor Calibration Updates on Greenland Ice Sheet Surface Reflectance and Albedo Trends

    Science.gov (United States)

    Casey, Kimberly A.; Polashenski, Chris M.; Chen, Justin; Tedesco, Marco

    2017-01-01

    We evaluate Greenland Ice Sheet (GrIS) surface reflectance and albedo trends using the newly released Collection 6 (C6) MODIS (Moderate Resolution Imaging Spectroradiometer) products over the period 2001-2016. We find that the correction of MODIS sensor degradation provided in the new C6 data products reduces the magnitude of the surface reflectance and albedo decline trends obtained from previous MODIS data (i.e., Collection 5, C5). Collection 5 and 6 data product analysis over GrIS is characterized by surface (i.e., wet vs. dry) and elevation (i.e., 500-2000 m, 2000 m and greater) conditions over the summer season from 1 June to 31 August. Notably, the visible-wavelength declining reflectance trends identified in several bands of MODIS C5 data from previous studies are only slightly detected at reduced magnitude in the C6 versions over the dry snow area. Declining albedo in the wet snow and ice area remains over the MODIS record in the C6 product, albeit at a lower magnitude than obtained using C5 data. Further analyses of C6 spectral reflectance trends show both reflectance increases and decreases in select bands and regions, suggesting that several competing processes are contributing to Greenland Ice Sheet albedo change. Investigators using MODIS data for other ocean, atmosphere and/or land analyses are urged to consider similar re-examinations of trends previously established using C5 data.

  3. Impact of MODIS sensor calibration updates on Greenland Ice Sheet surface reflectance and albedo trends

    Science.gov (United States)

    Casey, Kimberly A.; Polashenski, Chris M.; Chen, Justin; Tedesco, Marco

    2017-08-01

    We evaluate Greenland Ice Sheet (GrIS) surface reflectance and albedo trends using the newly released Collection 6 (C6) MODIS (Moderate Resolution Imaging Spectroradiometer) products over the period 2001-2016. We find that the correction of MODIS sensor degradation provided in the new C6 data products reduces the magnitude of the surface reflectance and albedo decline trends obtained from previous MODIS data (i.e., Collection 5, C5). Collection 5 and 6 data product analysis over GrIS is characterized by surface (i.e., wet vs. dry) and elevation (i.e., 500-2000 m, 2000 m and greater) conditions over the summer season from 1 June to 31 August. Notably, the visible-wavelength declining reflectance trends identified in several bands of MODIS C5 data from previous studies are only slightly detected at reduced magnitude in the C6 versions over the dry snow area. Declining albedo in the wet snow and ice area remains over the MODIS record in the C6 product, albeit at a lower magnitude than obtained using C5 data. Further analyses of C6 spectral reflectance trends show both reflectance increases and decreases in select bands and regions, suggesting that several competing processes are contributing to Greenland Ice Sheet albedo change. Investigators using MODIS data for other ocean, atmosphere and/or land analyses are urged to consider similar re-examinations of trends previously established using C5 data.

  4. Impact of MODIS sensor calibration updates on Greenland Ice Sheet surface reflectance and albedo trends

    Directory of Open Access Journals (Sweden)

    K. A. Casey

    2017-08-01

    Full Text Available We evaluate Greenland Ice Sheet (GrIS surface reflectance and albedo trends using the newly released Collection 6 (C6 MODIS (Moderate Resolution Imaging Spectroradiometer products over the period 2001–2016. We find that the correction of MODIS sensor degradation provided in the new C6 data products reduces the magnitude of the surface reflectance and albedo decline trends obtained from previous MODIS data (i.e., Collection 5, C5. Collection 5 and 6 data product analysis over GrIS is characterized by surface (i.e., wet vs. dry and elevation (i.e., 500–2000 m, 2000 m and greater conditions over the summer season from 1 June to 31 August. Notably, the visible-wavelength declining reflectance trends identified in several bands of MODIS C5 data from previous studies are only slightly detected at reduced magnitude in the C6 versions over the dry snow area. Declining albedo in the wet snow and ice area remains over the MODIS record in the C6 product, albeit at a lower magnitude than obtained using C5 data. Further analyses of C6 spectral reflectance trends show both reflectance increases and decreases in select bands and regions, suggesting that several competing processes are contributing to Greenland Ice Sheet albedo change. Investigators using MODIS data for other ocean, atmosphere and/or land analyses are urged to consider similar re-examinations of trends previously established using C5 data.

  5. Near-surface 3D reflections seismic survey; Sanjigen senso hanshaho jishin tansa

    Energy Technology Data Exchange (ETDEWEB)

    Nakahigashi, H.; Mitsui, H.; Nakano, O.; Kobayashi, T. [DIA Consultants Co. Ltd., Tokyo (Japan)

    1997-05-27

    Faults are being actively investigated across Japan since the Great Hanshin-Awaji Earthquake. Discussed in this report is the application of the 3D near-surface reflection seismic survey in big cities. Data from trenching and drilling is used for the geological interpretation of the surroundings of a fault, and the reflection seismic survey is used to identify the position, etc., of the fault. In this article, when the results obtained from the experimental field are examined, it is found that the conventional 2D imaging reflection survey betrays the limit of its capability when the geological structure is complicated, that the 3D reflection seismic survey, on the contrary, is capable of high-precision imaging and, when augmented by drilling, etc., becomes capable of a more detailed interpretation, and that it also contributes effectively to the improvement of local disaster prevention in big cities. Using as the model the Tachikawa fault that runs near JR Tachikawa Station, embodiment of the 3D reflection seismic survey is reviewed. For the acquisition of data excellent in quality in a 3D reflection seismic survey conducted utilizing the roads in the sector chosen for experiment in the urban area, the shock generating points and receiving points should be positioned by taking into account the parameters in the bin arranging process so that the mid-points will be regularly distributed on the surface. 3 refs., 11 figs., 1 tab.

  6. LiDAR Relative Reflectivity Surface (2011) for Fish Bay, St. John

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This image represents a LiDAR (Light Detection & Ranging) 0.3x0.3 meter resolution relative seafloor reflectivity surface for Fish Bay, St. John in the U.S....

  7. LiDAR Relative Reflectivity Surface (2011) for Coral Bay, St. John

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This image represents a LiDAR (Light Detection & Ranging) 0.3x0.3 meter resolution relative seafloor reflectivity surface for Coral Bay, St. John in the U.S....

  8. Introducing a mini-catamaran to perform reflectance measurements above and below the water surface

    Science.gov (United States)

    Froidefond, Jean-Marie; Ouillon, Sylvain

    2005-02-01

    An innovative platform is tested to perform reflectance measurements at sea. This platform is a mini-catamaran with two hulls 1m long and set 0.7m apart, fitted with optical sensors. It can be used far away from an oceanographic ship to avoid its hull influencing the measurement. Reflectance measurements were performed with a TriOS radiance sensor placed +2cm or -2cm from the water surface and a TriOS irradiance sensor. Tests were carried out in calm seas and with cloud cover. The processing to derive marine radiances from raw measurements is detailed. When the radiance sensor is above the interface, it limits the sky reflections on the targeted surface and the radiance is identical to that deduced from measurements below the surface. When the sensor is placed at +3cm abovewater or higher, glint affects the measurements. The mini-catamaran shows a good ability to measure marine reflectance with an adapted measurement protocol. Except for very turbid waters, it seems preferable to perform upwelling radiance measurements below the surface.

  9. Total reflection PIXE (TPIXE) and RBS for surface and trace element analysis.

    NARCIS (Netherlands)

    van Kan, J.A.; Vis, R.D.

    1996-01-01

    MeV proton and α beams at small incident angles (0-35 mrad) were used to analyse flat surfaces such as Si wafers and coated quartz substrates. X-rays and backscattered particles were detected in a total reflection geometry. Using TPIXE a quick and simultaneous detection of different trace elements

  10. On the determination of the spin of the black hole in Cyg X-1 from X-ray reflection spectra

    Science.gov (United States)

    Fabian, A. C.; Wilkins, D. R.; Miller, J. M.; Reis, R. C.; Reynolds, C. S.; Cackett, E. M.; Nowak, M. A.; Pooley, G. G.; Pottschmidt, K.; Sanders, J. S.; Ross, R. R.; Wilms, J.

    2012-07-01

    The spin of Cygnus X-1 is measured by fitting reflection models to Suzaku data covering the energy band 0.9-400 keV. The inner radius of the accretion disc is found to lie within 2 gravitational radii (rg=GM/c2), and a value of ? is obtained for the dimensionless black hole spin. This agrees with recent measurements using the continuum fitting method by Gou et al. and of the broad iron line by Duro et al. The disc inclination is measured at ?, which is consistent with the recent optical measurement of the binary system inclination by Orosz et al. of 27°± 0?8. We pay special attention to the emissivity profile caused by irradiation of the inner disc by the hard power-law source. The X-ray observations and simulations show that the index q of that profile deviates from the commonly used, Newtonian, value of 3 within 3rg, steepening considerably within 2rg, as expected in the strong gravity regime.

  11. On the Determination of the Spin of the Black Hole in Cyg X-1 from X-Ray Reflection Spectra

    Science.gov (United States)

    Fabian, A. C.; Wilkins, D.; Miller, J. M.; Reis, R. C.; Reynolds, C. S.; Cackett, E. M.; Nowak, M. A.; Pooley, G.; Pottschmidt, K.; Sanders, J. S.; hide

    2012-01-01

    The spin of Cygnus X-I is measured by fitting reflection models to Suzaku data covering the energy band 0.9-400 keY. The inner radius of the accretion disc is found to lie within 2 gravitational radii (rg = GM/c(exp 2)) and a value for the dimensionless black hole spin is obtained of 0.97(sup .0.14) (sup -0.02). This agrees with recent measurements using the continuum fitting method by Gou et al. and of the broad iron line by Duro et al. The disc inclination is measured at 23.7(sup +6.7) (sup -5.4) deg. which is consistent with the recent optical measurement of the binary system inclination by Orosz et al of 27+/- 0.8 deg. We pay special attention to the emissivity profile caused by irradiation of the inner disc by the hard power-law source. 1be X-ray observations and simulations show that the index q of that profile deviates from the commonly used, Newtonian, value of 3 within 3r(sub g), steepening considerably within 2r(sub g). as expected in the strong gravity regime.

  12. The normalization of surface anisotropy effects present in SEVIRI reflectances by using the MODIS BRDF method

    DEFF Research Database (Denmark)

    Proud, Simon Richard; Zhang, Qingling; Schaaf, Crystal

    2014-01-01

    A modified version of the MODerate resolution Imaging Spectroradiometer (MODIS) bidirectional reflectance distribution function (BRDF) algorithm is presented for use in the angular normalization of surface reflectance data gathered by the Spinning Enhanced Visible and InfraRed Imager (SEVIRI......) aboard the geostationary Meteosat Second Generation (MSG) satellites. We present early and provisional daily nadir BRDF-adjusted reflectance (NBAR) data in the visible and near-infrared MSG channels. These utilize the high temporal resolution of MSG to produce BRDF retrievals with a greatly reduced...... acquisition period than the comparable MODIS products while, at the same time, removing many of the angular perturbations present within the original MSG data. The NBAR data are validated against reflectance data from the MODIS instrument and in situ data gathered at a field location in Africa throughout 2008...

  13. Suppressing light reflection from polycrystalline silicon thin films through surface texturing and silver nanostructures

    International Nuclear Information System (INIS)

    Akhter, Perveen; Huang, Mengbing; Kadakia, Nirag; Spratt, William; Malladi, Girish; Bakhru, Hassarum

    2014-01-01

    This work demonstrates a novel method combining ion implantation and silver nanostructures for suppressing light reflection from polycrystalline silicon thin films. Samples were implanted with 20-keV hydrogen ions to a dose of 10 17 /cm 2 , and some of them received an additional argon ion implant to a dose of 5 × 10 15 /cm 2 at an energy between 30 and 300 keV. Compared to the case with a single H implant, the processing involved both H and Ar implants and post-implantation annealing has created a much higher degree of surface texturing, leading to a more dramatic reduction of light reflection from polycrystalline Si films over a broadband range between 300 and 1200 nm, e.g., optical reflection from the air/Si interface in the AM1.5 sunlight condition decreasing from ∼30% with an untextured surface to below 5% for a highly textured surface after post-implantation annealing at 1000 °C. Formation of Ag nanostructures on these ion beam processed surfaces further reduces light reflection, and surface texturing is expected to have the benefit of diminishing light absorption losses within large-size (>100 nm) Ag nanoparticles, yielding an increased light trapping efficiency within Si as opposed to the case with Ag nanostructures on a smooth surface. A discussion of the effects of surface textures and Ag nanoparticles on light trapping within Si thin films is also presented with the aid of computer simulations.

  14. Methods of Creating Solar-Reflective Nonwhite Surfaces and theirApplication to Residential Roofing Materials

    Energy Technology Data Exchange (ETDEWEB)

    Levinson, Ronnen; Berdahl, Paul; Akbari, Hashem; Miller, William; Joedicke, Ingo; Reilly, Joseph; Suzuki, Yoshi; Vondran, Michelle

    2005-05-24

    We describe methods for creating solar-reflective nonwhitesurfaces and their application to a wide variety of residential roofingmaterials, including metal, clay tile, concrete tile, wood, and asphaltshingle. Reflectance in the near-infrared (NIR) spectrum (0.7 2.5mu m) ismaximized by coloring a topcoatwith pigments that weakly absorb and(optionally) strongly backscatter NIR radiation, and adding anNIR-reflective basecoat (e.g., titanium dioxide white) if both thetopcoat and substrate weakly reflect NIR radiation. Coated steel andglazed clay tile roofing products achieved NIRreflectances of up to 0.50and 0.75, respectively, using only cool topcoats. Gray concrete tilesachieve NIR reflectances as high as 0.60 when thickly coated withNIR-scattering pigments, and could attain an NIR reflectances as high as0.85 by overlaying a titanium-dioxide basecoat with a topcoat colored byNIR-transparent organic pigments. Granule-surfaced asphalt shinglesachieved NIR reflectances as high as 0.45 when a cool color topcoat wasapplied over a thick white basecoat.

  15. Directional short wind wave spectra derived from the sea surface photography

    Science.gov (United States)

    Dulov, Vladimir; Yurovskaya, Maria; Chapron, Bertrand; Kudryavtsev, Vladimir

    2014-05-01

    New field measurements of 2-D wave number short wind wave spectra in the wavelength range from few millimeters to few decimeters are reported and discussed. The measurement method proposed by [Kosnik and Dulov, 2011] is based on stereophotography and image brightness contrast processing. The method strongly builds on the brightness cross-spectral analysis to reduce the noise within this short wave gravity and capillary range. Field measurements of wind wave spectra are still rare, and the reported data thus provide valuable information to bring new evidences on the 2-D spectral distribution of short wind waves in the wavelength range from decimeters to millimeters. As found, the folded spectra of decimeter waves are very weakly dependent on the wind speed and its direction. Wind speed and direction sensitivity only starts to appear in the short wavelength range, more precisely in the vicinity of the wave number 100 rad/m, where the wind exponent grows from 0.5 to 1.5-2.5 at 800 rad/m, and angular anisotropy parameter introduced by [Elfouhaily et al., 1997] amounts the value of 0.5. These aspects are consistent with other previously reported optical and radar data. For the latter, we solely extracted the polarization sensitivity to best isolate the contribution associated to the wave saturation spectrum around the Bragg resonant wave number. For the former, mean-squared slope statistics were used to assess the integrated shortscale directional spectral properties. As revealed, observed direction spectral distributions are significantly different from those previously suggested [Elfouhaily et al., 1997; Kudryavtsev et al., 2003, 2005]. On the basis of these new in situ measurements, we then propose to revise the semiempirical analytical model of short wind wave spectra developed by [Kudryavtsev et al., 2003, 2005]. In this model the key parameter is exponent n governing the nonlinear dissipation rate as D ~ Bn+1, where B is saturation spectrum. Accordingly, new

  16. Absorption and Reflectance Spectra of Microwave Radiation by an Epoxy Resin Composite with Multi-Walled Carbon Nanotubes

    Science.gov (United States)

    Komarov, F. F.; Milchanin, O. V.; Parfimovich, I. D.; Grinchenko, M. V.; Parhomenko, I. N.; Tkachev, A. G.; Bychanok, D. S.

    2017-09-01

    A procedure for dispersing multi-walled carbon nanotubes in the two-component polymer SpeciFix-20 (epoxy resin + hardener) using combined hydromechanical and ultrasonic mixing was developed. New composites with carbon nanotubes were produced. Their structures and optical and electrophysical characteristics were studied. The propagation of microwave radiation (26-38 GHz) in experimental composite samples was investigated. It was shown that the strong absorption of the composites appeared only with significant additions of multi-walled carbon nanotubes and was caused by the resulting electrical conductivity of the composites. A size effect of the additive on the optical characteristics of the produced composites was established. Equal absorption coefficients for microwave radiation could be achieved by using a smaller amount of carbon nanotubes with smaller diameters and greater specific surface areas in the composite.

  17. The use of IR, magnetism, reflectance, and mass spectra together with thermal analyses in structure investigation of codeine phosphate complexes of d-block elements

    Science.gov (United States)

    Zayed, M. A.; El-shahat, M. F.; Abdullah, S. M.

    2005-06-01

    Codeine is an analgesic with uses similar to morphines, but it is of much less effect, i.e., it had a mild sedative effect; codeine is usually used as the phosphate form (Cod.P) and is often administrated by mouth with aspirin of paracetamol. Due to its serious use, if it is in large dose, attention is paid in this research to the synthesis and stereochemistry of new iron, cobalt, nickel, copper, and zinc complexes of this drug in both solution and the solid states. The spectra of these complexes in solution and the study of their stoichiometry refer to the formation of 1:1 ratio of metal (M) to ligand (L). The steriochemical structures of the solid complexes were studied on the basis of their analytical, spectroscopic, magnetic, and thermal data. Infrared spectra proved the presence of M sbnd O bonds. Magnetic susceptibility and solid reflectance spectral measurements were used to infer the structures. The prepared complexes were found to have the general formulae [ML(OH) x(H 2O) y](H 2O) zH 3PO 4, M: Co(II), Ni(II), and Cu(II), x = 1, y = 0, z = 0; M: Fe(II), x = 1, y = 2, z = 1; Fe(III), x = 2, y = 1, z = 0; Co(III), x = 0, y = 2, z = 1; Zn(II), x = 1, y = 0, z = 3; and L: (Cod.P) of the general formula C 18H 24NO 7P (anhydrate). Octahedral, tetrahedral, and square planer structures were proposed for these complexes depending upon the magnetic and reflectance data and were confirmed by detailed mass and thermal analyses comparative studies.

  18. On the spectra and coherence of some surface meteorological parameters in the Arabian Sea

    Digital Repository Service at National Institute of Oceanography (India)

    RameshKumar, M.R.; Fernandes, A.A.

    . In addition to peaks in the annual, semiannual and four-month periodicities, the various surface parameters exhibited some energy at 2, 3 and 4 year cycles. It was also found that most of the surface meteorological parameters were coherent (at 95% confidence...

  19. Lactoperoxidase catalyzed radioiodination of cell surface immunoglobulin: incorporated radioactivity may not reflect relative cell surface Ig density

    International Nuclear Information System (INIS)

    Wilder, R.L.; Yuen, C.C.; Mage, R.G.

    1979-01-01

    Rabbit and mouse splenic lymphocytes were radioiodinated by the lactoperoxidase technique, extracted with non-ionic detergent, immunoprecipitated with high titered rabbit anti-kappa antisera, and compared by SDS-PAGE. Mouse sIg peaks were reproducibly larger in size than rabbit sIg peaks (often greater than 10 times). Neither differences in incorporation of label into the rabbit cell surface, nor differences in average sIg density explain this result. Total TCA-precipitable radioactivity was similar in each species. Estimation of the relative amounts of sIg in the mouse and rabbit showed similar average sIg densities. Differences in detergent solubility, proteolytic lability, or antisera used also do not adequately account for this difference. Thus, these data indicate that radioactivity incorporated after lactoperoxidase catalyzed cell surface radioiodination may not reflect cell surface Ig density. Conclusions about cell surface density based upon relative incorporation of radioactivity should be confirmed by other approaches

  20. Critical coupling of surface plasmons in graphene attenuated total reflection geometry

    Energy Technology Data Exchange (ETDEWEB)

    Cuevas, Mauro, E-mail: cuevas@df.uba.ar [Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) and Facultad de Ingeniería y Tecnología Informática, Universidad de Belgrano, Villanueva 1324, C1426BMJ, Buenos Aires (Argentina); Grupo de Electromagnetismo Aplicado, Departamento de Física, FCEN, Universidad de Buenos Aires and IFIBA, Ciudad Universitaria, Pabellón I, C1428EHA, Buenos Aires (Argentina)

    2016-12-09

    We study the optical response of an attenuated total reflection (ATR) structure in Otto configuration with graphene sheet, paying especial attention to the occurrence of total absorption. Our results show that due to excitation of surface plasmons on the graphene sheet, two different conditions of total absorption may occur. At these conditions, the energy loss of the surface plasmon by radiation is equal to its energy loss by absorption into the graphene sheet. We give necessary conditions on ATR parameters for the existence of total absorption. - Highlights: • Attenuated total reflection (ATR) structure with graphene sheet. • Surface plasmons and power matched condition. • Necessary conditions on ATR parameters for the existence of total absorption.

  1. A compact ESPI system for displacement measurements of specular reflecting or optical rough surfaces

    DEFF Research Database (Denmark)

    Hansen, R.S.

    2004-01-01

    A stable and compact speckle interferometer for doing out-of-plane displacement measurements on reflective as well as diffusely scattering object surfaces is demonstrated. The set-up is based on a nearly path length compensated interferometer of the Fizeau type and uses diffuse illumination...... of the object combined with a speckled reference wave. This combination eliminates the need for special optical components, and the interferometer can be built of commonly available components. The diffuse illumination wave is obtained by scattering coherent light from a diffusely scattering surface....... The speckled reference wave is established by reflecting a part of the diffuse illumination wave from a glass plate placed in front of the object. Besides relaxing the alignment tolerances of the set-up, the diffuse illumination eliminates the need for any preparation of the surface under test, which turns...

  2. Intensity distributions of reflected surface channeling protons scattered on surfaces of electron-bombarded alkali halide crystals

    Science.gov (United States)

    Fukazawa, Y.; Kihara, K.; Iwamoto, K.; Susuki, Y.

    2013-11-01

    We have examined the surface-channeling of 550 keV protons on electron-bombarded KBr(0 0 1) surfaces at grazing incidence. On the surface, electron-stimulated desorption (ESD) resulting from the irradiation of 5 keV electrons changes the surface morphology. In order to investigate the change of the surface morphology, the luminous intensity distributions observed on a fluorescent screen (scattering patterns) of the reflected protons under the surface-channeling conditions are measured. Normalized specular intensity of the protons oscillates, and the results of computer simulations show that the period of the intensity oscillation agrees with the period of layer-by-layer desorption. The measured period of the oscillation is comparable to the simulated one, i.e., the period of the desorption, however, the measured amplitude of the oscillation is weak. This shows that the layer-by-layer desorption of the experimental surface is observed but is not as remarkable as that of the perfect surface introduced in the simulation.

  3. Intensity distributions of reflected surface channeling protons scattered on surfaces of electron-bombarded alkali halide crystals

    Energy Technology Data Exchange (ETDEWEB)

    Fukazawa, Y., E-mail: yukofu@cc.osaka-kyoiku.ac.jp; Kihara, K.; Iwamoto, K.; Susuki, Y.

    2013-11-15

    We have examined the surface-channeling of 550 keV protons on electron-bombarded KBr(0 0 1) surfaces at grazing incidence. On the surface, electron-stimulated desorption (ESD) resulting from the irradiation of 5 keV electrons changes the surface morphology. In order to investigate the change of the surface morphology, the luminous intensity distributions observed on a fluorescent screen (scattering patterns) of the reflected protons under the surface-channeling conditions are measured. Normalized specular intensity of the protons oscillates, and the results of computer simulations show that the period of the intensity oscillation agrees with the period of layer-by-layer desorption. The measured period of the oscillation is comparable to the simulated one, i.e., the period of the desorption, however, the measured amplitude of the oscillation is weak. This shows that the layer-by-layer desorption of the experimental surface is observed but is not as remarkable as that of the perfect surface introduced in the simulation.

  4. Probing Ultrafast Electron Dynamics at Surfaces Using Soft X-Ray Transient Reflectivity Spectroscopy

    Science.gov (United States)

    Baker, L. Robert; Husek, Jakub; Biswas, Somnath; Cirri, Anthony

    The ability to probe electron dynamics with surface sensitivity on the ultrafast time scale is critical for understanding processes such as charge separation, injection, and surface trapping that mediate efficiency in catalytic and energy conversion materials. Toward this goal, we have developed a high harmonic generation (HHG) light source for femtosecond soft x-ray reflectivity. Using this light source we investigated the ultrafast carrier dynamics at the surface of single crystalline α-Fe2O3, polycrystalline α-Fe2O3, and the mixed metal oxide, CuFeO2. We have recently demonstrated that CuFeO2 in particular is a selective catalyst for photo-electrochemical CO2 reduction to acetate; however, the role of electronic structure and charge carrier dynamics in mediating catalytic selectivity has not been well understood. Soft x-ray reflectivity measurements probe the M2,3, edges of the 3d transition metals, which provide oxidation and spin state resolution with element specificity. In addition to chemical state specificity, these measurements are also surface sensitive, and by independently simulating the contributions of the real and imaginary components of the complex refractive index, we can differentiate between surface and sub-surface contributions to the excited state spectrum. Accordingly, this work demonstrates the ability to probe ultrafast carrier dynamics in catalytic materials with element and chemical state specificity and with surface sensitivity.

  5. The effect of surface texture on total reflection of neutrons and X-rays from modified interfaces

    DEFF Research Database (Denmark)

    Goldar, A.; Roser, S.J.; Hughes, A.

    2002-01-01

    X-ray and neutron scattering from macroscopically rough surfaces and interfaces is considered and a new method of analysis based on the variation of the shape of the total reflection edge in the reflectivity profile is proposed. It was shown that in the limit that the correlation length...... and the height of the surface roughness are larger than the wavelength (at least 100 times bigger) of the incoming beam, the total reflection edge in the reflection profile becomes rounded. This technique allows direct analysis of the variation of the reflectivity pro le in terms of the structure of the surface...

  6. Evaluation of BRDF Archetypes for Representing Surface Reflectance Anisotropy Using MODIS BRDF Data

    Directory of Open Access Journals (Sweden)

    Hu Zhang

    2015-06-01

    Full Text Available Bidirectional reflectance distribution function (BRDF archetypes extracted from the Moderate Resolution Imaging Spectroradiometer (MODIS BRDF/Albedo product over the global Earth Observing System Land Validation Core Sites can be used to simplify BRDF models. The present study attempts to evaluate the representativeness of BRDF archetypes for surface reflectance anisotropy. Five-year forward-modeled MODIS multi-angular reflectance (MCD-ref and aditional actual MODIS multi-angular observations (MCD-obs in four growing periods in 2008 over three tiles were taken as validation data. First, BRDF archetypes in the principal plane were qualitatively compared with the time-series MODIS BRDF product of randomly sampled pixels. Secondly, BRDF archetypes were used to fit MCD-ref, and the average root-mean-squared errors (RMSEs over each tile were examined for these five years. Finally, both BRDF archetypes and the MODIS BRDF were used to fit MCD-obs, and the histograms of the fit-RMSEs were compared. The consistency of the directional reflectance between the BRDF archetypes and MODIS BRDFs in nadir-view, hotspot and entire viewing hemisphere at 30° and 50° solar geometries were also examined. The results confirm that BRDF archetypes are representative of surface reflectance anisotropy for available snow-free MODIS data.

  7. Correlation characteristics of signals reflected by the wavy surface of ocean in mirror direction

    Science.gov (United States)

    Zhitkovskiy, Y. Y.; Nosov, A. V.; Savelyev, V. V.

    1985-06-01

    An experimental study was carried out to determine the correlation characteristics of pseudonoise signals reflected from a wave-covered surface in the mirror direction. The major measured quantity was the reciprocal correlation coefficient between the transmitted signal and the reflected signal. The transmitter was lowered from a ship on a 150 m cable. The receiver and preamplifier were lowered to the same depth from a buoy which was allowed to drift from the ship to a distance of 100-500 m, the changing distance changing the angle of the beam reflected from the surface of the ocean back down to the hydrophone. The radiator transmitted a pulsed signal with a pseudonoise carrier. The results were interpreted within the framework of ordinary correlation theory by processing several recordings, calculating the sign and ordinary correlation coefficients to determine the variation in sign correlation coefficient as a function of the ordinary correlation coefficient. Graphs of the average variation are presented. It was found that the medium did not distort the signal as it propagated through the water mass (within the limits of experimental accuracy). The correlation coefficient between the transmitted and reflected signals is thus determined entirely by the characteristics of reradiation of the sound by the wavecovered surface.

  8. Aerosol Optical Retrieval and Surface Reflectance from Airborne Remote Sensing Data over Land

    Directory of Open Access Journals (Sweden)

    Cristiana Bassani

    2010-06-01

    Full Text Available Quantitative analysis of atmospheric optical properties and surface reflectance can be performed by applying radiative transfer theory in the Atmosphere-Earth coupled system, for the atmospheric correction of hyperspectral remote sensing data. This paper describes a new physically-based algorithm to retrieve the aerosol optical thickness at 550nm (τ550 and the surface reflectance (ρ from airborne acquired data in the atmospheric window of the Visible and Near-Infrared (VNIR range. The algorithm is realized in two modules. Module A retrieves τ550 with a minimization algorithm, then Module B retrieves the surface reflectance ρ for each pixel of the image. The method was tested on five remote sensing images acquired by an airborne sensor under different geometric conditions to evaluate the reliability of the method. The results, τ550 and ρ, retrieved from each image were validated with field data contemporaneously acquired by a sun-sky radiometer and a spectroradiometer, respectively. Good correlation index, r, and low root mean square deviations, RMSD, were obtained for the τ550 retrieved by Module A (r2 = 0.75, RMSD = 0.08 and the ρ retrieved by Module B (r2 ≤ 0.9, RMSD ≤ 0.003. Overall, the results are encouraging, indicating that the method is reliable for optical atmospheric studies and the atmospheric correction of airborne hyperspectral images. The method does not require additional at-ground measurements about at-ground reflectance of the reference pixel and aerosol optical thickness.

  9. Predicting ambient aerosol thermal-optical reflectance (TOR) measurements from infrared spectra: extending the predictions to different years and different sites

    Science.gov (United States)

    Reggente, Matteo; Dillner, Ann M.; Takahama, Satoshi

    2016-02-01

    Organic carbon (OC) and elemental carbon (EC) are major components of atmospheric particulate matter (PM), which has been associated with increased morbidity and mortality, climate change, and reduced visibility. Typically OC and EC concentrations are measured using thermal-optical methods such as thermal-optical reflectance (TOR) from samples collected on quartz filters. In this work, we estimate TOR OC and EC using Fourier transform infrared (FT-IR) absorbance spectra from polytetrafluoroethylene (PTFE Teflon) filters using partial least square regression (PLSR) calibrated to TOR OC and EC measurements for a wide range of samples. The proposed method can be integrated with analysis of routinely collected PTFE filter samples that, in addition to OC and EC concentrations, can concurrently provide information regarding the functional group composition of the organic aerosol. We have used the FT-IR absorbance spectra and TOR OC and EC concentrations collected in the Interagency Monitoring of PROtected Visual Environments (IMPROVE) network (USA). We used 526 samples collected in 2011 at seven sites to calibrate the models, and more than 2000 samples collected in 2013 at 17 sites to test the models. Samples from six sites are present both in the calibration and test sets. The calibrations produce accurate predictions both for samples collected at the same six sites present in the calibration set (R2 = 0.97 and R2 = 0.95 for OC and EC respectively), and for samples from 9 of the 11 sites not included in the calibration set (R2 = 0.96 and R2 = 0.91 for OC and EC respectively). Samples collected at the other two sites require a different calibration model to achieve accurate predictions. We also propose a method to anticipate the prediction error; we calculate the squared Mahalanobis distance in the feature space (scores determined by PLSR) between new spectra and spectra in the calibration set. The squared Mahalanobis distance provides a crude method for assessing the

  10. Near-surface temperature gradients and their effects on thermal-infrared emission spectra of particulate planetary surfaces

    Science.gov (United States)

    Henderson, B. G.; Jakosky, B. M.

    1993-01-01

    The infrared energy emitted from a planetary surface is generated within a finite depth determined by the material's absorption skin depth. This parameter varies significantly with wavelength in the infrared but has an average value of around 50 microns for most geologic materials. In solid rock, heat transfer is efficient enough so that this 50 micron zone of the near surface from which the radiation emanates will be more or less isothermal. In particulate materials, however, heat transfer is more complicated and occurs via a combination of mechanisms, including solid conduction within grains and across grain contacts, conduction through the interstitial gas, and thermal radiation within individual particles and across the void spaces in between grains. On planets with substantial atmospheres, the gas component dominates the heat transfer and tends to mitigate near-surface thermal gradients. However, on airless bodies, the gas component is absent and heat transfer occurs via solid conductions and radiation. If the particles are small relative to the average absorption skin depth, then the top 50-100 microns or so of the surface will be cooled by radiation to space allowing the creation of significant near-surface thermal gradients. In those regions of the spectrum where the absorption coefficient is low, the emission will come from the deeper, warmer parts of the medium, whereas in regions of high absorption, the emission will emanate from shallower, cooler parts of the medium. The resulting emission spectrum will show non-compositional features as a result of the thermal structure in the material. We have modeled the heat transfer in a particulate medium in order to determine the magnitude of near-surface thermal gradients for surfaces on airless bodies and on Mars. We use the calculated thermal structure to determine the effects it has on the infrared emission spectrum of the surface.

  11. Characterizing the surface heterogeneity of fire effects using multi-temporal reflective wavelength data

    CSIR Research Space (South Africa)

    Roy, DP

    2005-10-10

    Full Text Available of fire effects using multi-temporal reflective wavelength data D. P. Roy a; T. Landmann ba Department of Geography, College Park, and NASA Goddard, Space Flight Center, University of Maryland. Code 614.5 (B32), Greenbelt, MD 20771. USAb CSIR Environmentek... Characterizing the surface heterogeneity of fire effects using multi-temporal reflective wavelength data D. P. ROY*{ and T. LANDMANN{ {Department of Geography, University of Maryland, College Park, and NASA Goddard, Space Flight Center, Code 614.5 (B32...

  12. Microscopic surface wettability electrochemical characterization of tight sandstone with infrared spectra testing

    Science.gov (United States)

    Song, L.; Ning, Z. F.; Li, N.; Zhang, B.; Ding, G. Y.

    2017-08-01

    The distribution of charge density on the surface of microscopic tight oil is studied by using Stern double electric layer theory, and the mathematical flow model of polar fluid with micro powers in tight oil reservoir is established. The Fourier transform infrared (FTIR) were used to investigate the interaction of rock surface functional groups with fluids. The results show that: (1) When the external fluid of the polar group passes through the dense micro-nano pore, it will form an electric double layer on the surface of the rock, there will be a certain thickness of the liquid membrane, the fluid migration has a certain Of the electrical viscosity effect, will have a certain flow resistance. (2) The Fourier transform infrared spectroscopy of the Chang 7 tight reservoir rock samples exists and distributes different kinds of peaks. The left peak trend determines the presence of hydroxyl groups. The four fronts and types of the right side can be used to obtain that calcium carbonate CO3 2- exists. (3) There are CO3 2- and hydroxyl functional minerals in the Chang 7 tight sandstone samples. It is consistent with the basic mineral analysis measured by X-ray diffraction. When the external fluid affects the rock surface, the surface will occur in the physical van der Waals force and chemical bond interaction, so it will affect the flow of water on the surface.

  13. Studies of float glass surfaces by neutron and x-ray reflection

    International Nuclear Information System (INIS)

    Dalgliesh, R.

    2001-09-01

    The surface of glass and glass coatings have been studied using x-ray and neutron scattering techniques. In particular, the effect of aqueous solutions and humid atmospheres on both the fire polished and the tin rich side of float glass have been investigated using neutron and x-ray reflection. Isotopic substitution has enabled the number density of water molecules within the float glass surface to be monitored with respect to immersion time, temperature and impurity content. A thin gel-like water-rich layer of thickness ∼30A is observed at the surface accompanied by a more deeply penetrating layer which increases in depth with time reaching ∼500A after 6 months. The rate of water ingression is higher than predicted from previous work carried out at elevated temperatures. Small decreases in the depth of penetration have been observed for glass containing alumina and tin. Water penetration into thin films made by a sol-gel process have also been studied. The hydrophobicity of these films had been varied by the addition of fluoroalkylsilane. Neutron and X-ray reflection revealed that water entered the highly hydrophobic films readily from the vapour phase. This suggests a method of film destabilisation by which water enters the film and freezes, causing the film to crack. Changes in fluoroalkylsilane content and annealing have little effect on the penetration of water into the coatings. Etched float glass surfaces have been used as a system for testing the applicability of current off-specular scattering models. A rich surface structure has been found which results in reflection effects that cannot be explained by these models. Model systems have also been developed in an attempt to combine x-ray fluorescence techniques with reflectivity. (author)

  14. Bi-directional Reflectance of Icy Surface Analogs: A Dual Approach

    Science.gov (United States)

    Quinones, Juan Manuel; Vides, Christina; Nelson, Robert M.; Boryta, Mark; Mannat, Ken s.

    2018-01-01

    Bi-directional reflectance measurements of analogs for planetary regolith have provided insight into the surface properties of planetary satellites and small bodies. Because Aluminum Oxide (Al2O3) and water ice share a similar hexagonal crystalline structure, the former has been used in laboratory experiments to simulate the regolith of both icy and dusty planetary bodies. By measuring various sizes of well sorted size fractions of Al2O3, the reflectance phase curve and porosity of a planetary regolith can be determined. We have designed an experiment to test the laboratory measurements produced by Nelson et al. (2000). Additionally, we made reflectance measurements for other alkali-halide compounds that could be used for applications beyond astronomy and planetary science.In order to provide an independent check on the Nelson et al. data, we designed an instrument with a different configuration. While both instruments take bidirectional reflectance measurements, our instrument, the Rigid Photometric Goniometer (RPG), is fixed at a phase angle of 5° and detects the scattered light with a photomultiplier tube (PMT). The PMT current is then measured with an electrometer. Following the example of Nelson et al., we measured the bidirectional reflectance of Al2O3 particulate size fractions between 0.1reflectance measurements for NaCl and KCl of sizes from 20reflectance applications beyond astronomy and planetary science. The objective of the experiment was to determine the particle size that provided optimal, or maximum, reflectance for each compound. Our conclusions bring confirmation and clarity to photometric sciences.

  15. Thermal emission from particulate surfaces: A comparison of scattering models with measured spectra

    Science.gov (United States)

    Moersch, J. E.; Christensen, P. R.

    1995-01-01

    Emissivity spectra of particulate mineral samples are highly dependent on particle size when that size is comparable to the wavelength of light emitted (5-50 micrometers for the midinfrared). Proper geologic interpretation of data from planetary infrared spectrometers will require that these particle size effects be well understood. To address this issue, samples of quartz powders were produced with narrow, well-characterized particle size distributions. Mean particle diameters in these samples ranged from 15 to 227 micrometers. Emission spectra of these powders allow the first detailed comparison of the complex spectral variations with particle size observed in laboratory data with the predictions of radiative transfer models. Four such models are considered here. Hapke's relectance theory (converted to emissivity via Kirchoff's law) is the first model tested. Hapke's more recently published emission theory is also employed. The third model, the 'Mie/Conel' model, uses Mie single scattering with a two-stream approximation for multiple scattering. This model, like the first, is a converted reflec- tance model. Mie scattering assumes particles are both spherical and well separated, which is not true for the quartz powders, but includes diffraction effects. The fourth model uses the Mie solution for single scattering by spheres and inputs those results into the multiple scattering formalism of Hapke's emission theory. The results of the four models are considered in relation to the values of the optical constants n and k. We have grouped these as class 1 (k large), class 2 (k moderate, n is approximately 2), class 3 (k small, n is approximately 2), and class 4 (k small, n is approximately 1). In general, the Mie/Hapke hybrid model does best at predicting variations with grain size. In particular, it predicts changes of the correct pattern, although incorrect magnitude, for class 1 bands, where large increases in emissivity with decreasing grain size are observed

  16. Biomimetic approaches to create anti-reflection glass surfaces for solar cells using self-organizing techniques

    Energy Technology Data Exchange (ETDEWEB)

    Achtelik, J.; Sievers, W. [University of Paderborn, Department of Physics, 33098 Paderborn (Germany); Center of Optoelectronics and Photonics Paderborn CeOPP, 33098 Paderborn (Germany); Lindner, J.K.N., E-mail: lindner@physik.uni-paderborn.de [University of Paderborn, Department of Physics, 33098 Paderborn (Germany); Center of Optoelectronics and Photonics Paderborn CeOPP, 33098 Paderborn (Germany)

    2013-05-15

    Highlights: ► Nanostructured glass surfaces with theoretically near-to-zero reflectivity in the UVNIR region. ► Simple fabrication process using self-organization during reactive ion etching proposed. ► Prediction of optical reflectivity from AFM measured surface morphology. -- Abstract: Aiming to diminish the reflection losses of glass covered light harvesting devices, the optical reflectivity of nanostructured glass surfaces is studied theoretically and experimentally. The work is inspired by the nanoscale roughness of insect eyes, which is tried to be replicated on a technical glass surface. To this end, the reflectivity of glass surfaces with topographies represented by linear, parabolic and Fermi-shaped glass/air fill factor profiles is calculated for normal incidence. It is shown that using the latter ones, an almost complete suppression of reflections can be achieved. A simple, self-organization technique to create such Fermi-shaped filling factor profiles in glass experimentally is also presented.

  17. Surface defect assisted broad spectra emission from CdSe quantum dots for white LED application

    Science.gov (United States)

    Samuel, Boni; Mathew, S.; Anand, V. R.; Correya, Adrine Antony; Nampoori, V. P. N.; Mujeeb, A.

    2018-02-01

    This paper reports, broadband photoluminescence from CdSe quantum dots (QDs) under the excitation of 403 nm using fluorimeter and 403 nm CW laser excitation. The broad spectrum obtained from the colloidal quantum dots was ranges from 450 nm to 800 nm. The broadness of the spectra was attributed to the merging of band edge and defect driven emissions from the QDs. Six different sizes of particles were prepared via kinetic growth method by using CdO and elemental Se as sources of Cd and Se respectively. The particle sizes were measured from TEM images. The size dependent effect on broad emission was also studied and the defect state emission was found to be predominant in very small QDs. The defect driven emission was also observed to be redshifted, similar to the band edge emission, due to quantum confinement effect. The emission corresponding to different laser power was also studied and a linear relation was obtained. In order to study the colour characteristics of the emission, CIE chromaticity coordinate, CRI and CCT of the prepared samples were measured. It is observed that, these values were tunable by the addition of suitable intensity of blue light from the excitation source to yield white light of various colour temperatures. The broad photoluminescence spectrum of the QDs, were compared with that of a commercially available white LED. It was found that the prepared QDs are good alternatives for the phosphor in phosphor converted white LEDs, to provide good spectral tunability.

  18. Transmission/reflection behaviors of surface plasmons at an interface between two plasmonic systems

    Science.gov (United States)

    Guan, Fuxin; Sun, Shulin; Ma, Shaojie; Fang, Zhening; Zhu, Baocheng; Li, Xin; He, Qiong; Xiao, Shiyi; Zhou, Lei

    2018-03-01

    Although surface plasmon polaritons (SPPs) have been intensively studied in past years, the transmission/reflection properties of SPPs at an interface between two plasmonic media are still not fully understood. In this article, we employ a mode expansion method (MEM) to systematically study such a problem based on a model system jointing two superlattices, each consisting of a periodic stacking of dielectric and plasmonic slabs with different material properties. Such a generic model can represent two widely used plasmonic structures (i.e. interfaces between two single dielectric/metal systems or between two metal–insulator–metal waveguides) under certain conditions. Our MEM calculations, in excellent agreement with full-wave simulations, uncover the rich physics behind the SPP reflections at generic plasmonic interfaces. In particular, we successfully derive from the MEM several analytical formulas that can quantitatively describe the SPP reflections at different plasmonic interfaces, and show that our formulas exhibit wider applicable regions than previously proposed empirical ones.

  19. Antarctic Surface Reflectivity Measurements from the ANITA-3 and HiCal-1 Experiments

    Science.gov (United States)

    Gorham, P. W.; Allison, P.; Banerjee, O.; Beatty, J. J.; Belov, K.; Besson, D. Z.; Binns, W. R.; Bugaev, V.; Cao, P.; Chen, C.; Chen, P.; Clem, J. M.; Connolly, A.; Dailey, B.; Dasgupta, P.; Deaconu, C.; Cremonesi, L.; Dowkontt, P. F.; Fox, B. D.; Gordon, J.; Hill, B.; Hupe, R.; Israel, M. H.; Jain, P.; Kowalski, J.; Lam, J.; Learned, J. G.; Liewer, K. M.; Liu, T. C.; Matsuno, S.; Miki, C.; Mottram, M.; Mulrey, K.; Nam, J.; Nichol, R. J.; Novikov, A.; Oberla, E.; Prohira, S.; Rauch, B. F.; Romero-Wolf, A.; Rotter, B.; Ratzlaff, K.; Russell, J.; Saltzberg, D.; Seckel, D.; Schoorlemmer, H.; Stafford, S.; Stockham, J.; Stockham, M.; Strutt, B.; Tatem, K.; Varner, G. S.; Vieregg, A. G.; Wissel, S. A.; Wu, F.; Young, R.

    The primary science goal of the NASA-sponsored ANITA project is measurement of ultra-high energy neutrinos and cosmic rays, observed via radio-frequency signals resulting from a neutrino or cosmic ray interaction with terrestrial matter (e.g. atmospheric or ice molecules). Accurate inference of the energies of these cosmic rays requires understanding the transmission/reflection of radio wave signals across the ice-air boundary. Satellite-based measurements of Antarctic surface reflectivity, using a co-located transmitter and receiver, have been performed more-or-less continuously for the last few decades. Our comparison of four different reflectivity surveys, at frequencies ranging from 2 to 45GHz and at near-normal incidence, yield generally consistent maps of high versus low reflectivity, as a function of location, across Antarctica. Using the Sun as an RF source, and the ANITA-3 balloon borne radio-frequency antenna array as the RF receiver, we have also measured the surface reflectivity over the interval 200-1000MHz, at elevation angles of 12-30∘. Consistent with our previous measurement using ANITA-2, we find good agreement, within systematic errors (dominated by antenna beam width uncertainties) and across Antarctica, with the expected reflectivity as prescribed by the Fresnel equations. To probe low incidence angles, inaccessible to the Antarctic Solar technique and not probed by previous satellite surveys, a novel experimental approach (“HiCal-1”) was devised. Unlike previous measurements, HiCal-ANITA constitute a bi-static transmitter-receiver pair separated by hundreds of kilometers. Data taken with HiCal, between 200 and 600MHz shows a significant departure from the Fresnel equations, constant with frequency over that band, with the deficit increasing with obliquity of incidence, which we attribute to the combined effects of possible surface roughness, surface grain effects, radar clutter and/or shadowing of the reflection zone due to Earth

  20. Measuring and modeling near-surface reflected and emitted radiation fluxes at the FIFE site

    Science.gov (United States)

    Blad, Blaine L.; Walter-Shea, Elizabeth A.; Starks, Patrick J.; Vining, Roel C.; Hays, Cynthia J.; Mesarch, Mark A.

    1990-01-01

    Information is presented pertaining to the measurement and estimation of reflected and emitted components of the radiation balance. Information is included about reflectance and transmittance of solar radiation from and through the leaves of some grass and forb prairie species, bidirectional reflectance from a prairie canopy is discussed and measured and estimated fluxes are described of incoming and outgoing longwave and shortwave radiation. Results of the study showed only very small differences in reflectances and transmittances for the adaxial and abaxial surfaces of grass species in the visible and infrared wavebands, but some differences in the infrared wavebands were noted for the forbs. Reflectance from the prairie canopy changed as a function of solar and view zenith angles in the solar principal plane with definite asymmetry about nadir. The surface temperature of prairie canopies was found to vary by as much as 5 C depending on view zenith and azimuth position and on the solar azimuth. Aerodynamic temperature calculated from measured sensible heat fluxes ranged from 0 to 3 C higher than nadir-viewed temperatures. Models were developed to estimate incoming and reflected shortwave radiation from data collected with a Barnes Modular Multiband Radiometer. Several algorithms for estimating incoming longwave radiation were evaluated and compared to actual measures of that parameter. Net radiation was calculated using the estimated components of the shortwave radiation streams, determined from the algorithms developed, and from the longwave radiation streams provided by the Brunt, modified Deacon, and the Stefan-Boltzmann models. Estimates of net radiation were compared to measured values and found to be within the measurement error of the net radiometers used in the study.

  1. Energy loss of MeV protons specularly reflected from metal surfaces

    International Nuclear Information System (INIS)

    Juaristi, J.I.; Garcia de Abajo, F.J.; Echenique, P.M.

    1996-01-01

    A parameter-free model is presented to study the energy loss of fast protons specularly reflected from metal surfaces. The contributions to the energy loss from excitation of valence-band electrons and ionization of localized target-atom electronic states are calculated separately. The former is calculated from the induced surface wake potential using linear response theory and the specular-reflection model, while the latter is calculated in the first Born approximation. The results obtained are in good agreement with available experimental data. However, the experimental qualitative trend of the energy loss as a function of the angle of incidence is obtained when the valence-band electron model is replaced by localized target atom electron states, though with a worse quantitative agreement. copyright 1996 The American Physical Society

  2. Surface plasmon resonance sensors based on uniform-waist tapered fibers in a reflective configuration

    Science.gov (United States)

    Esteban, Óscar; Díaz-Herrera, Natalia; Navarrete, María-Cruz; González-Cano, Agustín

    2006-10-01

    We present a configuration for surface plasmon resonance sensors based on uniform-waist tapered optical fibers and reflective elements. Once the fiber is tapered fulfilling the adiabatic criterion, a multilayer including a metallic medium is asymmetrically deposited on the uniform waist of the fiber. This feature provides the resonant excitation of multiple surface plasma waves. In addition, a mirror is produced at the fiber tip by a chemical Tollens reaction. In this way, the sensor operates in a reflective mode, more convenient for dip probes. When these sensors are spectrally interrogated, a high sensitivity of 10-4 refractive index units per nanometer is attained. These devices can be advantageously used for any kind of chemical sensing and biosensing.

  3. Glazed ceramic roof tiles: influence of surface features in the solar reflectance index

    International Nuclear Information System (INIS)

    Bortoli, Leitcia Silva de; Stapait, Camila Cristina; Marinoski, Deivis Luis; Fredel, Marcio Celso; Schabbach, Luciana M.

    2016-01-01

    In this study the influence of surface features of ceramic roof tiles in the solar reflectance index were evaluated. Two glazed ceramic roof tiles (type stoneware) with the same color (ivory) but with different appearance (matte and brilliant) were the focus of the analysis. The Solar Reflectance Index (SRI) of the roofs tiles were determined by the solar reflectance values (UV-VIS-NIR) and emittance, measured in laboratory. The samples showed SRI> 39 in accordance with LEED certification criteria (Leadership in Energy and Environmental Design), contributing to minimizing the Heat Island Effects. Although the matte roof tile shows a slightly higher SRI value (82) than the brilliant one (78), the results for the variables that composes the SRI value (reflectance and emittance) were very similar. Analysis of XRD, SEM and EDS performed on the surfaces of the two roofs indicated for the matte glaze the presence of microcrystals (with barium and zinc) that can contribute to the slightly highest value of SRI. The roughness (optical interferometer white light) and the brightness (brightness meter) of the samples were also measured. (author)

  4. Absorption and reflectivity of the lithium niobate surface masked with a graphene layer

    Directory of Open Access Journals (Sweden)

    O. Salas

    2017-01-01

    Full Text Available We performed simulations of the interaction of a graphene layer with the surface of lithium niobate utilizing density functional theory and molecular dynamics at 300K and atmospheric pressure. We found that the graphene layer is physisorbed on the lithium niobate surface with an adsorption energy of -0.8205 eV/(carbon-atom. Subsequently, the energy band structure, the optical absorption and reflectivity of the new system were calculated. We found important changes in these physical properties with respect to the corresponding ones of a graphene layer and of a lithium niobate crystal.

  5. Transitioning MODIS to VIIRS observations for Land: Surface Reflectance results, Status and Long-term Prospective

    Science.gov (United States)

    Vermote, E.

    2015-12-01

    Surface reflectance is one of the key products from VIIRS and as with MODIS, is used in developing several higher-order land products. The VIIRS Surface Reflectance (SR) IP is based on the heritage MODIS Collection 5 product (Vermote et al. 2002). The quality and character of surface reflectance depends on the accuracy of the VIIRS Cloud Mask (VCM) and aerosol algorithms and of course on the adequate calibration of the sensor. Early evaluation of the VIIRS SR product in the context of the maturity of the operational processing system known as the Interface Data Processing System (IDPS), has been a major focus of work to-date, but is now evolving into the development of a VIIRS suite of Climate Data Records produced by the NASA Land Science Investigator Processing System (SIPS). We will present the calibration performance and the role of the surface reflectance in calibration monitoring, the performance of the cloud mask with a focus on vegetation monitoring (no snow conditions), the performance of the aerosol input used in the atmospheric correction with quantitative results of the performance of the SR product over AERONET sites. Based on those elements and further assessment, we will address the readiness of the SR product for the production of higher-order land products such as Vegetation Indices, Albedo and LAI/FPAR, the its application to agricultural monitoring and in particular the integration of VIIRS data into the global agricultural monitoring (GLAM) system developed at UMd. Finally from the lessons learned, we will articulate a set of critical recommendations to ensure consistency and continuity of the JPSS mission with the MODIS data record.

  6. Combined analysis of surface reflection imaging and vertical seismic profiling at Yucca Mountain, Nevada

    International Nuclear Information System (INIS)

    Daley, T.M.; Majer, E.L.; Karageorgi, E.

    1994-08-01

    This report presents results from surface and borehole seismic profiling performed by the Lawrence Berkeley Laboratory (LBL) on Yucca Mountain. This work was performed as part of the site characterization effort for the potential high-level nuclear waste repository. Their objective was to provide seismic imaging from the near surface (200 to 300 ft. depth) to the repository horizon and below, if possible. Among the issues addressed by this seismic imaging work are location and depth of fracturing and faulting, geologic identification of reflecting horizons, and spatial continuity of reflecting horizons. The authors believe their results are generally positive, with tome specific successes. This was the first attempt at this scale using modem seismic imaging techniques to determine geologic features on Yucca Mountain. The principle purpose of this report is to present the interpretation of the seismic reflection section in a geologic context. Three surface reflection profiles were acquired and processed as part of this study. Because of environmental concerns, all three lines were on preexisting roads. Line 1 crossed the mapped surface trace of the Ghost Dance fault and it was intended to study the dip and depth extent of the fault system. Line 2 was acquired along Drill Hole wash and was intended to help the ESF north ramp design activities. Line 3 was acquired along Yucca Crest and was designed to image geologic horizons which were thought to be less faulted along the ridge. Unfortunately, line 3 proved to have poor data quality, in part because of winds, poor field conditions and limited time. Their processing and interpretation efforts were focused on lines 1 and 2 and their associated VSP studies

  7. Fluctuations of noiselike signals reflected from a rough surface at the output of a correlation receiver

    Science.gov (United States)

    Gulin, E. P.

    2005-11-01

    The frequency and time averaging of the fluctuations that occur in the cross-correlation function of a radiated noiselike acoustic signal with the signal received after its reflection from a rough water surface is considered. The variance and temporal correlation function are calculated for the output effect of a correlation receiver for different ratios between the averaging time and the time correlation interval of fluctuations, the band width of the radiated signal, and the frequency correlation interval of the transfer function fluctuations.

  8. Decadal changes of surface elevation over permafrost area estimated using reflected GPS signals

    Science.gov (United States)

    Liu, Lin; Larson, Kristine M.

    2018-02-01

    Conventional benchmark-based survey and Global Positioning System (GPS) have been used to measure surface elevation changes over permafrost areas, usually once or a few times a year. Here we use reflected GPS signals to measure temporal changes of ground surface elevation due to dynamics of the active layer and near-surface permafrost. Applying the GPS interferometric reflectometry technique to the multipath signal-to-noise ratio data collected by a continuously operating GPS receiver mounted deep in permafrost in Barrow, Alaska, we can retrieve the vertical distance between the antenna and reflecting surface. Using this unique kind of observables, we obtain daily changes of surface elevation during July and August from 2004 to 2015. Our results show distinct temporal variations at three timescales: regular thaw settlement within each summer, strong interannual variability that is characterized by a sub-decadal subsidence trend followed by a brief uplift trend, and a secular subsidence trend of 0.26 ± 0.02 cm year-1 during 2004 and 2015. This method provides a new way to fully utilize data from continuously operating GPS sites in cold regions for studying dynamics of the frozen ground consistently and sustainably over a long time.

  9. A Study on Infrared Emissivity Measurement of Material Surface by Reflection Method

    International Nuclear Information System (INIS)

    Kang, Byung Chul; Kim, Sang Myoung; Choi, Joung Yoon; Kim, Gun Ok

    2010-01-01

    Infrared emissivity is one of the most important factors for the temperature measurement by infrared thermography. Although the infrared emissivity of an object can be measured from the ratio of blackbody and the object, at room temperature it is practically difficult to measure the value due to the background effects. Hence, quantitative reflectance of bare steel plate and the surface of coating was measured by FT-IR spectroscopy and emissivity was calculated from this. The emissivity of polished bare steel surface was from 0.06 to 0.10 and the value for the unpolished bare steel can not be achieved because optical characteristics changes of surface roughness induces erroneous results. Emissivity of transparent paint coated steel was from 0.50 to 0.84. Depends on the IR absorption regions, which is a characteristic value of the coating, emissivity changes. This study suggests surface condition of material, thickness, roughness etcetra are important factor for IR optical characteristics. Emissivity measurement by reflection method is useful technique to be applied for metal and it with coating applied on the surface. The range of experimental errors of temperature can be narrowed by the application of infrared thermography from the measured thermal emissivity

  10. A fiber-coupled displacement measuring interferometer for determination of the posture of a reflective surface

    Energy Technology Data Exchange (ETDEWEB)

    Mao, Shuai; Hu, Peng-Cheng, E-mail: hupc@hit.edu.cn; Ding, Xue-Mei, E-mail: X.M.Ding@outlook.com; Tan, Jiu-Bin [Harbin Institute of Technology, D-403 Science Park, 2 Yikuang Street, Harbin 150080 (China)

    2016-08-15

    A fiber-coupled displacement measuring interferometer capable of determining of the posture of a reflective surface of a measuring mirror is proposed. The newly constructed instrument combines fiber-coupled displacement and angular measurement technologies. The proposed interferometer has advantages of both the fiber-coupled and the spatially beam-separated interferometer. A portable dual-position sensitive detector (PSD)-based unit within this proposed interferometer measures the parallelism of the two source beams to guide the fiber-coupling adjustment. The portable dual PSD-based unit measures not only the pitch and yaw of the retro-reflector but also measures the posture of the reflective surface. The experimental results of displacement calibration show that the deviations between the proposed interferometer and a reference one, Agilent 5530, at two different common beam directions are both less than ±35 nm, thus verifying the effectiveness of the beam parallelism measurement. The experimental results of angular calibration show that deviations of pitch and yaw with the auto-collimator (as a reference) are less than ±2 arc sec, thus proving the proposed interferometer’s effectiveness for determination of the posture of a reflective surface.

  11. A fiber-coupled displacement measuring interferometer for determination of the posture of a reflective surface

    Science.gov (United States)

    Mao, Shuai; Hu, Peng-Cheng; Ding, Xue-Mei; Tan, Jiu-Bin

    2016-08-01

    A fiber-coupled displacement measuring interferometer capable of determining of the posture of a reflective surface of a measuring mirror is proposed. The newly constructed instrument combines fiber-coupled displacement and angular measurement technologies. The proposed interferometer has advantages of both the fiber-coupled and the spatially beam-separated interferometer. A portable dual-position sensitive detector (PSD)-based unit within this proposed interferometer measures the parallelism of the two source beams to guide the fiber-coupling adjustment. The portable dual PSD-based unit measures not only the pitch and yaw of the retro-reflector but also measures the posture of the reflective surface. The experimental results of displacement calibration show that the deviations between the proposed interferometer and a reference one, Agilent 5530, at two different common beam directions are both less than ±35 nm, thus verifying the effectiveness of the beam parallelism measurement. The experimental results of angular calibration show that deviations of pitch and yaw with the auto-collimator (as a reference) are less than ±2 arc sec, thus proving the proposed interferometer's effectiveness for determination of the posture of a reflective surface.

  12. A rendering method of background reflections on a specular surface for CGH

    International Nuclear Information System (INIS)

    Ichikawa, T; Sakamoto, Y

    2013-01-01

    Computer-generated holograms (CGHs) are remarked as ideal three-dimensional displays. There are a lot of problems have to be overcome, and we focused on the rendering techniques to reconstruct realistic images. In particular, there is almost no calculation method that correctly expresses depth information. Reflected images are necessary to express complex realistic scenes. In this paper, we introduce a calculation method that generates reconstructed images with background reflections. Proposed method calculates intersections between virtual objects and rays by the ray tracing method. Then intersections are assumed as a point light source group, and light waves on a hologram plane are calculated. In the ray tracing process, when a ray hits the specular object, a ray is additionally casted to the specular direction from the intersection. If the ray hits other diffuse objects or background, the length of light path from a viewpoint to the diffuse object is calculated. By calculating light waves from a point light source on the diffuse surface distant from the light path, reflected images are expressed in the CGH. To express the quality of materials, we adopted the Cook-Torrance reflection model. In the experiment, we conducted the computer simulation to confirm that the depth of reflected images is correctly calculated. And results of optical reconstructions show that our proposed method is able to make CGHs of various qualities of material.

  13. IRAS surface brightness maps of visible reflection nebulae: evidence for non-equilibrium infrared emission

    International Nuclear Information System (INIS)

    Castelaz, M.W.; Werner, M.W.; Sellgren, K.

    1986-01-01

    Surface brightness maps at 12, 25, 60, and 100 microns of 16 visible reflection nebulae were extracted from the Infrared Astronomy Satellite (IRAS) database. The maps were produced by coadding IRAS survey scans over areas centered on the illuminating stars, and have spatial resolutions of 0.9' x 4' at 12 and 25 microns, 1.8' x 4.5' at 60 microns, and 3.6' x 5' at 100 microns. Extended emission in the four IRAS bandpasses was detected in fourteen of the reflection nebulae. The IRAS data were used to measure the flux of the infrared emission associated with each source. The energy distributions show that the 12 micron flux is greater than the 25 micron flux in 11 of the nebulae, and the peak flux occurs in the 60 or 100 micron bandpass in all 16 nebular. The 60 and 100 micron flux can be approximated by blackbodies with temperatures between 30 and 50 K, consistent with temperatures expected from extrapolation of greybody fits to the 60 and 100 micron data. The excess 12 and 25 micron emission is attributed to a nonequilibrium process such as emission from thermal fluctuations of very small grains excited by single ultraviolet photons, or emission from polycyclic aromatic hydrocarbons (PAHs) excited by ultraviolet radiation. The common features of the energy distributions of the 16 reflection nebulae, also seen in the reflection nebulae associated with the Pleiades, suggest that PAHs or very small grains may be found in most reflection nebulae

  14. Quantitative determination of the intensities of known components in spectra obtained from surface analytical techniques

    International Nuclear Information System (INIS)

    Nelson, G.C.

    1984-01-01

    Linear least-squares methods have been used to quantitatively decompose experimental data obtained from surface analytical techniques into its separate components. The mathematical procedure for accomplishing this is described and examples are given of the use of this method with data obtained from Auger electron spectroscopy [both N(E) and derivative], x-ray photoelectron spectroscopy, and low energy ion scattering spectroscopy. The requirements on the quality of the data are discussed

  15. Simulation of RBS spectra with known 3D sample surface roughness

    Czech Academy of Sciences Publication Activity Database

    Malinský, Petr; Siegel, J.; Hnatowicz, Vladimír; Macková, Anna; Švorčík, V.

    2017-01-01

    Roč. 406, SEP (2017), s. 99-103 ISSN 0168-583X R&D Projects: GA MŠk LM2015056; GA ČR(CZ) GBP108/12/G108 Institutional support: RVO:61389005 Keywords : computer simulation * surface roughness * AFM Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders OBOR OECD: Nuclear physics Impact factor: 1.109, year: 2016

  16. EPR Studies of Spin Labels Bound to Ceramic Surfaces, and Simulation of Magnetic Resonance Spectra by Molecular Trajectory.

    Science.gov (United States)

    Auteri, Francesco Paul

    Electron paramagnetic resonance (EPR) spectroscopy is sensitive to molecular rotational correlation times in the range of 10^{-6} to 10^{-11} seconds. EPR spin labels are often attached or incorporated into molecular structures as probes of local viscosities and dynamics. In part I of this work, methods of covalently attaching a variety of spin labels to silica and alumina ceramic surfaces are developed in an attempt to study local viscosities at varying distances from about 5 A^circ to 25 A^circ from the ceramic/liquid interface. Three solvents, diethyl ether, benzene, and cyclohexane, are chosen for detailed study in combination with the spin labels, TEMPOL, 5-DOXYL, and 12-DOXYL. EPR spectra of each system are taken over the range of temperatures from -140 ^circC to 50^circ C (or just below the solvent boiling point). Spectra show good sensitivity to solvent, temperature, and probe. The effect of adding 3% (w/o) poly-(octadecyl-methacrylate) (PODM) to benzene and cyclohexane on spin label mobility is also studied in this work. Rotational correlation times from lineshapes are analyzed assuming isotropic rotation using spectral splitting, line width, and simulation methods. These approaches are often inadequate for the more complex spectral line shapes observed for tethered spin labels, especially in the intermediate motional regime where sensitivity to anisotropic dynamics is greatest. In part II of this work, a novel approach to the prediction of spectral line shapes is developed. It is shown that EPR spectra may be computed directly from molecular trajectories using classical approximations to describe the time evolution of the magnetization vector under fluctuating effective interaction tensor values. Line shape simulations using molecular trajectories generated by Brownian dynamics theory are less time intensive than existing methods. Simulation of magnetic resonance line shapes by molecular trajectories as generated by programs such as CHARMM promises to be

  17. Gain-Enhanced On-Chip Antenna Utilizing Artificial Magnetic Conductor Reflecting Surface at 94 GHz

    KAUST Repository

    Nafe, Mahmoud

    2015-08-04

    Nowadays, there is a growing demand for high frequency-bandwidth mm-wave (30-300 GHz) electronic wireless transceiver systems to support applications such as high data-rate wireless communication and high resolution imaging. Such mm-wave systems are becoming more feasible due to the extreme transistor downscaling in silicon-based integrated circuits, which enabled densely-integrated high-speed elec- tronics operating up to more than 100 GHz with low fabrication cost. To further enhance system integrability, it is required to implement all wireless system compo- nents on the chip. Presently, the last major barrier to true System-on-Chip (SoC) realization is the antenna implementation on the silicon chip. Although at mm-wave frequencies the antenna size becomes small enough to fit on chip, the antenna performance is greatly deteriorated due the high conductivity and high relative permittivity of the silicon substrate. The negative e↵ects of the silicon substrate could be avoided by using a metallic reflecting surface on top of silicon, which e↵ectively isolates the antenna from the silicon. However, this approach has the shortcoming of having to implement the antenna on the usually very thin silicon oxide layer of a typical CMOS fabrication process (10’s of μm). This forces the antenna to be in a very close proximity (less than one hundredth of a wavelength) to the reflecting surface. In this regime, the use of conventional metallic reflecting surface for silicon shielding has severe e↵ects on the antenna performance as it tends to reduce the antenna radiation resistance resulting in most of the energy being absorbed rather than radiated. In this work, the use of specially patterned reflecting surfaces for improving on- chip antenna performance is investigated. By using a periodic metallic surface on top of a grounded substrate, the structure can mimic the behavior of a perfect mag- netic conductor, hence called Artificial Magnetic Conductor (AMC) surface

  18. Measurements of long-range interactions between protein-functionalized surfaces by total internal reflection microscopy.

    Science.gov (United States)

    Wang, Zhaohui; Gong, Xiangjun; Ngai, To

    2015-03-17

    Understanding the interaction between protein-functionalized surfaces is an important subject in a variety of protein-related processes, ranging from coatings for biomedical implants to targeted drug carriers and biosensors. In this work, utilizing a total internal reflection microscope (TIRM), we have directly measured the interactions between micron-sized particles decorated with three types of common proteins concanavalin A (ConA), bovine serum albumin (BSA), lysozyme (LYZ), and glass surface coated with soy proteins (SP). Our results show that the protein adsorption greatly affects the charge property of the surfaces, and the interactions between those protein-functionalized surfaces depend on solution pH values. At pH 7.5-10.0, all these three protein-functionalized particles are highly negatively charged, and they move freely above the negatively charged SP-functionalized surface. The net interaction between protein-functionalized surfaces captured by TIRM was found as a long-range, nonspecific double-layer repulsion. When pH was decreased to 5.0, both protein-functionalized surfaces became neutral and double-layer repulsion was greatly reduced, resulting in adhesion of all three protein-functionalized particles to the SP-functionalized surface due to the hydrophobic attraction. The situation is very different at pH = 4.0: BSA-decorated particles, which are highly charged, can move freely above the SP-functionalized surfaces, while ConA- and LYZ-decorated particles can only move restrictively in a limited range. Our results quantify these nonspecific kT-scale interactions between protein-functionalized surfaces, which will enable the design of surfaces for use in biomedical applications and study of biomolecular interactions.

  19. NPP/VIIRS Surface Reflectance Daily L2G Global 1km and 500m SIN Grid NRT

    Data.gov (United States)

    National Aeronautics and Space Administration — The VNP09GA_NRT is a Near Real Time (NRT) S-NPP/VIIRS 500m and 1km Daily Level 2G Surface Reflectance product. The NPP/ VIIRS surface reflectance products are...

  20. [Study on Square Super-Lattice Pattern with Surface Discharge in Dielectric Barrier Discharge by Optical Emission Spectra].

    Science.gov (United States)

    Niu, Xue-jiao; Dong, Li-fang; Liu, Ying; Wang, Qian; Feng, Jian-yu

    2016-02-01

    Square super-lattice pattern with surface discharge consisting of central spots and dim spots is firstly observed in the mixture of argon and air by using a dielectric barrier discharge device with water electrodes. By observing the image, it is found that the central spot is located at the centriod of its surrounding four dim spots. The short-exposure image recorded by a high speed video camera shows that the dim spot results from the surface discharges (SDs). The brightness of the central spot and is quite different from that of the dim spot, which indicates that the plasma states of the central spot and the dim spot may be differentiated. The optical emission spectrum method is used to further study the several plasma parameters of the central spot and the dim spot in different argon content. The emission spectra of the N₂ second positive band (C³IIu --> B³ IIg) are measured, from which the molecule vibration temperatures of the central spot and the dim spot are calculated respectively. The broadening of spectral line 696.57 nm (2P₂-->1S₅) is used to study the electron densities of the central spot and the dim spot. It is found that the molecule vibration temperature and electron density of the dim spot are higher than those of the central spot in the same argon content The molecule vibration temperature and electron density of the central spot and the dim spot increase with the argon content increasing from 90% to 99.9%. The surface discharge induced by the volume discharge (VD) has the determinative effect on the formation of the dim spot The experimental results above play an important role in studying the formation mechanism of surface discharg&of square super-lattice pattern with surface discharge. In addition, the studies exert an influence on the application of surface discharge and volume discharge in different fields.

  1. High-accuracy water potential energy surface for the calculation of infrared spectra

    Science.gov (United States)

    Mizus, Irina I.; Kyuberis, Aleksandra A.; Zobov, Nikolai F.; Makhnev, Vladimir Yu.; Polyansky, Oleg L.; Tennyson, Jonathan

    2018-03-01

    Transition intensities for small molecules such as water and CO2 can now be computed with such high accuracy that they are being used to systematically replace measurements in standard databases. These calculations use high-accuracy ab initio dipole moment surfaces and wave functions from spectroscopically determined potential energy surfaces (PESs). Here, an extra high-accuracy PES of the water molecule (H216O) is produced starting from an ab initio PES which is then refined to empirical rovibrational energy levels. Variational nuclear motion calculations using this PES reproduce the fitted energy levels with a standard deviation of 0.011 cm-1, approximately three times their stated uncertainty. The use of wave functions computed with this refined PES is found to improve the predicted transition intensities for selected (problematic) transitions. A new room temperature line list for H216O is presented. It is suggested that the associated set of line intensities is the most accurate available to date for this species. This article is part of the theme issue `Modern theoretical chemistry'.

  2. High-accuracy water potential energy surface for the calculation of infrared spectra.

    Science.gov (United States)

    Mizus, Irina I; Kyuberis, Aleksandra A; Zobov, Nikolai F; Makhnev, Vladimir Yu; Polyansky, Oleg L; Tennyson, Jonathan

    2018-03-13

    Transition intensities for small molecules such as water and CO 2 can now be computed with such high accuracy that they are being used to systematically replace measurements in standard databases. These calculations use high-accuracy ab initio dipole moment surfaces and wave functions from spectroscopically determined potential energy surfaces (PESs). Here, an extra high-accuracy PES of the water molecule (H 2 16 O) is produced starting from an ab initio PES which is then refined to empirical rovibrational energy levels. Variational nuclear motion calculations using this PES reproduce the fitted energy levels with a standard deviation of 0.011 cm -1 , approximately three times their stated uncertainty. The use of wave functions computed with this refined PES is found to improve the predicted transition intensities for selected (problematic) transitions. A new room temperature line list for H 2 16 O is presented. It is suggested that the associated set of line intensities is the most accurate available to date for this species.This article is part of the theme issue 'Modern theoretical chemistry'. © 2018 The Author(s).

  3. Incisor inclination determined by the light reflection zone on the tooth's surface.

    Science.gov (United States)

    Brezniak, Naphtali; Turgeman, Ronit; Redlich, Meir

    2010-01-01

    Maxillary incisors are the most prominent teeth, and their inclination plays an important role in esthetics. In orthodontics, the inclination of central incisors is usually determined by cephalometric analysis. This publication suggests an adjunctive clinical measure to determine this inclination. The objective of the study was to examine the correlation between the inclinations of maxillary incisors measured on a cephalometric lateral headfilm and the light reflection zone appearing on the buccal surface of the teeth on anterior intraoral photographs. Maxillary incisor inclination, divided into three levels-proclination, normal inclination, and retroclination-of 65 patients was determined by means of cephalometric analysis, using three angular measurements (maxillary incisor to sella-nasion, maxillary incisor to Frankfort horizontal, and maxillary incisor to nasion-point A). The anterior intraoral photographs of the 65 patients were divided into 3 groups according to the reflection zone on the maxillary central incisors as determined from the photographs: incisal, middle, and gingival. The correlation and agreement between the two parameters were evaluated by chi-square and kappa statistics. The light reflection zone on the tooth surface as it appears on intraoral photographs-incisal, middle, or gingival-correlated with statistical significance to the angular inclination of the teeth-proclination, normal inclination, and retroclination, respectively-as determined by means of cephalometric analysis (P light reflection zone viewed on the buccal surface of intraoral photographs. This method might be used as a new screening tool and further as an additional clinical tool for assessing treatment plans in orthodontics and other fields of dentistry.

  4. Determining surface coverage of ultra-thin gold films from X-ray reflectivity measurements

    International Nuclear Information System (INIS)

    Kossoy, A.; Simakov, D.; Olafsson, S.; Leosson, K.

    2013-01-01

    The paper describes usage of X-ray reflectivity for characterization of surface coverage (i.e. film continuity) of ultra-thin gold films which are widely studied for optical, plasmonic and electronic applications. The demonstrated method is very sensitive and can be applied for layers below 1 nm. It has several advantages over other techniques which are often employed in characterization of ultra-thin metal films, such as optical absorption, Atomic Force Microscopy, Transmission Electron Microscopy or Scanning Electron Microscopy. In contrast to those techniques our method does not require specialized sample preparation and measurement process is insensitive to electrostatic charge and/or presence of surface absorbed water. We validate our results with image processing of Scanning Electron Microscopy images. To ensure precise quantitative analysis of the images we developed a generic local thresholding algorithm which allowed us to treat series of images with various values of surface coverage with similar image processing parameters. - Highlights: • Surface coverage/continuity of ultra-thin Au films (up to 7 nm) was determined. • Results from X-ray reflectivity were verified by scanning electron microscopy. • We developed local thresholding algorithm to treat non-homogeneous image contrast

  5. Inverse modelling of Köhler theory – Part 1: A response surface analysis of CCN spectra with respect to surface-active organic species

    Directory of Open Access Journals (Sweden)

    S. Lowe

    2016-09-01

    Full Text Available In this study a novel framework for inverse modelling of cloud condensation nuclei (CCN spectra is developed using Köhler theory. The framework is established by using model-generated synthetic measurements as calibration data for a parametric sensitivity analysis. Assessment of the relative importance of aerosol physicochemical parameters, while accounting for bulk–surface partitioning of surface-active organic species, is carried out over a range of atmospherically relevant supersaturations. By introducing an objective function that provides a scalar metric for diagnosing the deviation of modelled CCN concentrations from synthetic observations, objective function response surfaces are presented as a function of model input parameters. Crucially, for the chosen calibration data, aerosol–CCN spectrum closure is confirmed as a well-posed inverse modelling exercise for a subset of the parameters explored herein. The response surface analysis indicates that the appointment of appropriate calibration data is particularly important. To perform an inverse aerosol–CCN closure analysis and constrain parametric uncertainties, it is shown that a high-resolution CCN spectrum definition of the calibration data is required where single-valued definitions may be expected to fail. Using Köhler theory to model CCN concentrations requires knowledge of many physicochemical parameters, some of which are difficult to measure in situ on the scale of interest and introduce a considerable amount of parametric uncertainty to model predictions. For all partitioning schemes and environments modelled, model output showed significant sensitivity to perturbations in aerosol log-normal parameters describing the accumulation mode, surface tension, organic : inorganic mass ratio, insoluble fraction, and solution ideality. Many response surfaces pertaining to these parameters contain well-defined minima and are therefore good candidates for calibration using a Monte

  6. Measurement of Near-Surface Salinity, Temperature and Directional Wave Spectra using a Novel Wave-Following, Lagrangian Surface Contact Buoy

    Science.gov (United States)

    Boyle, J. P.

    2016-02-01

    Results from a surface contact drifter buoy which measures near-surface conductivity ( 10 cm depth), sea state characteristics and near-surface water temperature ( 2 cm depth) are described. This light (autonomous, with low power requirements and solar panel battery recharging. Onboard sensors include an inductive toroidal conductivity probe for salinity measurement, a nine-degrees-of-freedom motion package for derivation of directional wave spectra and a thermocouple for water temperature measurement. Data retrieval for expendable, ocean-going operation uses an onboard Argos transmitter. Scientific results as well as data processing algorithms are presented from laboratory and field experiments which support qualification of buoy platform measurements. These include sensor calibration experiments, longer-term dock-side biofouling experiments during 2013-2014 and a series of short-duration ocean deployments in the Gulf Stream in 2014. In addition, a treatment method will be described which appears to minimize the effects of biofouling on the inductive conductivity probe when in coastal surface waters. Due to its low cost and ease of deployment, scores, perhaps hundreds of these novel instruments could be deployed from ships or aircraft during process studies or to provide surface validation for satellite-based measurements, particularly in high precipitation regions.

  7. Surface-enhanced Raman scattering spectra of adsorbates on Cu₂O nanospheres: charge-transfer and electromagnetic enhancement.

    Science.gov (United States)

    Jiang, Li; You, Tingting; Yin, Penggang; Shang, Yang; Zhang, Dongfeng; Guo, Lin; Yang, Shihe

    2013-04-07

    Surface-enhanced Raman scattering (SERS) spectra of 4-mercaptobenzoic acid (4-MBA) have been investigated on the surface of Cu2O nanospheres. The SERS signals were believed to originate from the static chemical enhancement, resonant chemical enhancement and electromagnetic enhancement. The coupling between the adsorbates and the semiconductor, evidenced by the shift in absorption spectrum of modified Cu2O and the enhancement of non-totally symmetric modes of the 4-MBA and 4-mercaptopyridine (4-MPY) molecules, were invoked to explain the experimental results. Furthermore, simulations were employed to investigate the nature of the enhancement mechanisms operative between the molecules and the semiconductor. Density functional theory (DFT) calculations suggested a charge transfer (CT) transition process between the molecules and the Cu2O nanospheres. Three-dimensional finite-difference time domain (3D-FDTD) simulations were conducted to map out the electromagnetic field around the Cu2O nanospheres. The experimental and simulation results have revealed the promise of the Cu2O nanospheres as a good SERS substrate and the prospect of using the SERS substrate as a valuable tool for in situ investigation and assay of the adsorption behavior on semiconductor surfaces.

  8. Surface reflectance drives nest box temperature profiles and thermal suitability for target wildlife.

    Directory of Open Access Journals (Sweden)

    Stephen R Griffiths

    Full Text Available Thermal properties of tree hollows play a major role in survival and reproduction of hollow-dependent fauna. Artificial hollows (nest boxes are increasingly being used to supplement the loss of natural hollows; however, the factors that drive nest box thermal profiles have received surprisingly little attention. We investigated how differences in surface reflectance influenced temperature profiles of nest boxes painted three different colors (dark-green, light-green, and white: total solar reflectance 5.9%, 64.4%, and 90.3% respectively using boxes designed for three groups of mammals: insectivorous bats, marsupial gliders and brushtail possums. Across the three different box designs, dark-green (low reflectance boxes experienced the highest average and maximum daytime temperatures, had the greatest magnitude of variation in daytime temperatures within the box, and were consistently substantially warmer than light-green boxes (medium reflectance, white boxes (high reflectance, and ambient air temperatures. Results from biophysical model simulations demonstrated that variation in diurnal temperature profiles generated by painting boxes either high or low reflectance colors could have significant ecophysiological consequences for animals occupying boxes, with animals in dark-green boxes at high risk of acute heat-stress and dehydration during extreme heat events. Conversely in cold weather, our modelling indicated that there are higher cumulative energy costs for mammals, particularly smaller animals, occupying light-green boxes. Given their widespread use as a conservation tool, we suggest that before boxes are installed, consideration should be given to the effect of color on nest box temperature profiles, and the resultant thermal suitability of boxes for wildlife, particularly during extremes in weather. Managers of nest box programs should consider using several different colors and installing boxes across a range of both orientations and

  9. [The research of the relationship between snow properties and the bidirectional polarized reflectance from snow surface].

    Science.gov (United States)

    Sun, Zhong-Qiu; Wu, Zheng-Fang; Zhao, Yun-Sheng

    2014-10-01

    In the context of remote sensing, the reflectance of snow is a key factor for accurate inversion for snow properties, such as snow grain size, albedo, because of it is influenced by the change of snow properties. The polarized reflectance is a general phenomenon during the reflected progress in natural incident light In this paper, based on the correct measurements for the multiple-angle reflected property of snow field in visible and near infrared wavelength (from 350 to 2,500 nm), the influence of snow grain size and wet snow on the bidirectional polarized property of snow was measured and analyzed. Combining the results measured in the field and previous conclusions confirms that the relation between polarization and snow grain size is obvious in infrared wavelength (at about 1,500 nm), which means the degree of polarization increasing with an increase of snow grain size in the forward scattering direction, it is because the strong absorption of ice near 1,500 nm leads to the single scattering light contributes to the reflection information obtained by the sensor; in other word, the larger grain size, the more absorption accompanying the larger polarization in forward scattering direction; we can illustrate that the change from dry snow to wet snow also influences the polarization property of snow, because of the water on the surface of snow particle adheres the adjacent particles, that means the wet snow grain size is larger than the dry snow grain size. Therefore, combining the multiple-angle polarization with reflectance will provide solid method and theoretical basis for inversion of snow properties.

  10. Surface reflectance drives nest box temperature profiles and thermal suitability for target wildlife.

    Science.gov (United States)

    Griffiths, Stephen R; Rowland, Jessica A; Briscoe, Natalie J; Lentini, Pia E; Handasyde, Kathrine A; Lumsden, Linda F; Robert, Kylie A

    2017-01-01

    Thermal properties of tree hollows play a major role in survival and reproduction of hollow-dependent fauna. Artificial hollows (nest boxes) are increasingly being used to supplement the loss of natural hollows; however, the factors that drive nest box thermal profiles have received surprisingly little attention. We investigated how differences in surface reflectance influenced temperature profiles of nest boxes painted three different colors (dark-green, light-green, and white: total solar reflectance 5.9%, 64.4%, and 90.3% respectively) using boxes designed for three groups of mammals: insectivorous bats, marsupial gliders and brushtail possums. Across the three different box designs, dark-green (low reflectance) boxes experienced the highest average and maximum daytime temperatures, had the greatest magnitude of variation in daytime temperatures within the box, and were consistently substantially warmer than light-green boxes (medium reflectance), white boxes (high reflectance), and ambient air temperatures. Results from biophysical model simulations demonstrated that variation in diurnal temperature profiles generated by painting boxes either high or low reflectance colors could have significant ecophysiological consequences for animals occupying boxes, with animals in dark-green boxes at high risk of acute heat-stress and dehydration during extreme heat events. Conversely in cold weather, our modelling indicated that there are higher cumulative energy costs for mammals, particularly smaller animals, occupying light-green boxes. Given their widespread use as a conservation tool, we suggest that before boxes are installed, consideration should be given to the effect of color on nest box temperature profiles, and the resultant thermal suitability of boxes for wildlife, particularly during extremes in weather. Managers of nest box programs should consider using several different colors and installing boxes across a range of both orientations and shade profiles (i

  11. Identifying the structure of 4-chlorophenyl isocyanide adsorbed on Au(111) and Pt(111) surfaces by first-principles simulations of Raman spectra.

    Science.gov (United States)

    Hu, Wei; Duan, Sai; Zhang, Yujin; Ren, Hao; Jiang, Jun; Luo, Yi

    2017-12-13

    Surface Raman spectroscopy has become one of the most powerful analytical tools for interfacial structures. However, theoretical modeling for the Raman spectra of molecular adsorbate on metallic surfaces is a long-standing challenge because accurate descriptions of the electronic structure for both the metallic substrates and adsorbates are required. Here we present a quasi-analytical method for high-precision surface Raman spectra at the first principle level. Using this method, we correlate both geometrical and electronic structures of a single 4-chlorophenyl isocyanide (CPI) molecule adsorbed on a Au(111) or Pt(111) surface with its Raman spectra. The "finger-print" frequency shift of the CN stretching mode reveals the in situ configuration of CPI is vertical adsorption on the top site of the Au(111) surface, but a bent configuration when it adsorbs on the hollow site of the Pt(111) surface. Electronic structure calculations reveal that a π-back donation mechanism often causes a red shift to the Raman response of CN stretching mode. In contrast, σ donation as well as a wall effect introduces a blue shift to the CN stretching mode. A clear relationship for the dependence of Raman spectra on the surface electronic and geometrical information is built up, which largely benefits the understanding of chemical and physical changes during the adsorption. Our results highlight that high-precision theoretical simulations are essential for identifying in situ geometrical and electronic surface structures.

  12. Simulation calculations of physical sputtering and reflection coefficient of plasma-irradiated carbon surface

    International Nuclear Information System (INIS)

    Kawamura, T.; Ono, T.; Yamamura, Y.

    1994-08-01

    Physical sputtering yields from the carbon surface irradiated by the boundary plasma are obtained with the use of a Monte Carlo simulation code ACAT. The yields are calculated for many random initial energy and angle values of incident protons or deuterons with a Maxwellian velocity distribution, and then averaged. Here the temperature of the boundary plasma, the sheath potential and the angle δ between the magnetic field line and the surface normal are taken into account. A new fitting formula for an arrangement of the numerical data of sputtering yield is introduced, in which six fitting parameters are determined from the numerical results and listed. These results provide a way to estimate the erosion of carbon materials irradiated by boundary plasma. The particle reflection coefficients for deuterons and their neutrals from a carbon surface are also calculated by the same code and presented together with, for comparison, that for the case of monoenergetic normal incidence. (author)

  13. Automatic and improved radiometric correction of Landsat imagery using reference values from MODIS surface reflectance images

    Science.gov (United States)

    Pons, X.; Pesquer, L.; Cristóbal, J.; González-Guerrero, O.

    2014-12-01

    Radiometric correction is a prerequisite for generating high-quality scientific data, making it possible to discriminate between product artefacts and real changes in Earth processes as well as accurately produce land cover maps and detect changes. This work contributes to the automatic generation of surface reflectance products for Landsat satellite series. Surface reflectances are generated by a new approach developed from a previous simplified radiometric (atmospheric + topographic) correction model. The proposed model keeps the core of the old model (incidence angles and cast-shadows through a digital elevation model [DEM], Earth-Sun distance, etc.) and adds new characteristics to enhance and automatize ground reflectance retrieval. The new model includes the following new features: (1) A fitting model based on reference values from pseudoinvariant areas that have been automatically extracted from existing reflectance products (Terra MODIS MOD09GA) that were selected also automatically by applying quality criteria that include a geostatistical pattern model. This guarantees the consistency of the internal and external series, making it unnecessary to provide extra atmospheric data for the acquisition date and time, dark objects or dense vegetation. (2) A spatial model for atmospheric optical depth that uses detailed DEM and MODTRAN simulations. (3) It is designed so that large time-series of images can be processed automatically to produce consistent Landsat surface reflectance time-series. (4) The approach can handle most images, acquired now or in the past, regardless of the processing system, with the exception of those with extremely high cloud coverage. The new methodology has been successfully applied to a series of near 300 images of the same area including MSS, TM and ETM+ imagery as well as to different formats and processing systems (LPGS and NLAPS from the USGS; CEOS from ESA) for different degrees of cloud coverage (up to 60%) and SLC

  14. Application of the Polynomial-Based Least Squares and Total Least Squares Models for the Attenuated Total Reflection Fourier Transform Infrared Spectra of Binary Mixtures of Hydroxyl Compounds.

    Science.gov (United States)

    Shan, Peng; Peng, Silong; Zhao, Yuhui; Tang, Liang

    2016-03-01

    An analysis of binary mixtures of hydroxyl compound by Attenuated Total Reflection Fourier transform infrared spectroscopy (ATR FT-IR) and classical least squares (CLS) yield large model error due to the presence of unmodeled components such as H-bonded components. To accommodate these spectral variations, polynomial-based least squares (LSP) and polynomial-based total least squares (TLSP) are proposed to capture the nonlinear absorbance-concentration relationship. LSP is based on assuming that only absorbance noise exists; while TLSP takes both absorbance noise and concentration noise into consideration. In addition, based on different solving strategy, two optimization algorithms (limited-memory Broyden-Fletcher-Goldfarb-Shanno (LBFGS) algorithm and Levenberg-Marquardt (LM) algorithm) are combined with TLSP and then two different TLSP versions (termed as TLSP-LBFGS and TLSP-LM) are formed. The optimum order of each nonlinear model is determined by cross-validation. Comparison and analyses of the four models are made from two aspects: absorbance prediction and concentration prediction. The results for water-ethanol solution and ethanol-ethyl lactate solution show that LSP, TLSP-LBFGS, and TLSP-LM can, for both absorbance prediction and concentration prediction, obtain smaller root mean square error of prediction than CLS. Additionally, they can also greatly enhance the accuracy of estimated pure component spectra. However, from the view of concentration prediction, the Wilcoxon signed rank test shows that there is no statistically significant difference between each nonlinear model and CLS. © The Author(s) 2016.

  15. Selecting the optimum number of partial least squares components for the calibration of attenuated total reflectance-mid-infrared spectra of undesigned kerosene samples.

    Science.gov (United States)

    Gómez-Carracedo, M P; Andrade, J M; Rutledge, D N; Faber, N M

    2007-03-07

    Selecting the correct dimensionality is critical for obtaining partial least squares (PLS) regression models with good predictive ability. Although calibration and validation sets are best established using experimental designs, industrial laboratories cannot afford such an approach. Typically, samples are collected in an (formally) undesigned way, spread over time and their measurements are included in routine measurement processes. This makes it hard to evaluate PLS model dimensionality. In this paper, classical criteria (leave-one-out cross-validation and adjusted Wold's criterion) are compared to recently proposed alternatives (smoothed PLS-PoLiSh and a randomization test) to seek out the optimum dimensionality of PLS models. Kerosene (jet fuel) samples were measured by attenuated total reflectance-mid-IR spectrometry and their spectra where used to predict eight important properties determined using reference methods that are time-consuming and prone to analytical errors. The alternative methods were shown to give reliable dimensionality predictions when compared to external validation. By contrast, the simpler methods seemed to be largely affected by the largest changes in the modeling capabilities of the first components.

  16. Antibody adsorption on the surface of water studied by neutron reflection.

    Science.gov (United States)

    Smith, Charles; Li, Zongyi; Holman, Robert; Pan, Fang; Campbell, Richard A; Campana, Mario; Li, Peixun; Webster, John R P; Bishop, Steven; Narwal, Rojaramani; Uddin, Shahid; van der Walle, Christopher F; Lu, Jian R

    2017-04-01

    Surface and interfacial adsorption of antibody molecules could cause structural unfolding and desorbed molecules could trigger solution aggregation, resulting in the compromise of physical stability. Although antibody adsorption is important and its relevance to many mechanistic processes has been proposed, few techniques can offer direct structural information about antibody adsorption under different conditions. The main aim of this study was to demonstrate the power of neutron reflection to unravel the amount and structural conformation of the adsorbed antibody layers at the air/water interface with and without surfactant, using a monoclonal antibody 'COE-3' as the model. By selecting isotopic contrasts from different ratios of H 2 O and D 2 O, the adsorbed amount, thickness and extent of the immersion of the antibody layer could be determined unambiguously. Upon mixing with the commonly-used non-ionic surfactant Polysorbate 80 (Tween 80), the surfactant in the mixed layer could be distinguished from antibody by using both hydrogenated and deuterated surfactants. Neutron reflection measurements from the co-adsorbed layers in null reflecting water revealed that, although the surfactant started to remove antibody from the surface at 1/100 critical micelle concentration (CMC) of the surfactant, complete removal was not achieved until above 1/10 CMC. The neutron study also revealed that antibody molecules retained their globular structure when either adsorbed by themselves or co-adsorbed with the surfactant under the conditions studied.

  17. Collisional Processing Of Comet And Asteroid Surfaces: Velocity Effects On Absorption Spectra

    Science.gov (United States)

    Jensen, Elizabeth; Lederer, S. M.; Wooden, D. H.; Lindsay, S. S.; Nakamura-Messenger, K.; Keller, L. P.; Cintala, M. J.; Zolensky, M. E.

    2012-10-01

    A new paradigm has emerged where 3.9 Gyr ago, a violent reshuffling reshaped the placement of small bodies in the solar system (the Nice model). Surface properties of these objects may have been affected by collisions caused by this event, and by collisions with other small bodies since their emplacement. These impacts affect the spectroscopic observations of these bodies today. Shock effects (e.g., planar dislocations) manifest in minerals allowing astronomers to better understand geophysical impact processing that has occurred on small bodies. At the Experimental Impact Laboratory at NASA Johnson Space Center, we have impacted forsterite and enstatite across a range of velocities. We find that the amount of spectral variation, absorption wavelength, and full width half maximum of the absorbance peaks vary non-linearly with the velocity of the impact. We also find that the spectral variation increases with decreasing crystal size (single solid rock versus granular). Future analyses include quantification of the spectral changes with different impactor densities, temperature, and additional impact velocities. Results on diopside, fayalite, and magnesite can be found in Lederer et al., this meeting. Funding was provided by the NASA PG&G grant 09-PGG09-0115, NSF grant AST-1010012, and a Cottrell College Scholarship through the Research Corporation.

  18. Characterizing LEDAPS surface reflectance products by comparisons with AERONET, field spectrometer, and MODIS data

    Science.gov (United States)

    Maiersperger, Tom; Scaramuzza, Pat; Leigh, Larry; Shrestha, S.; Gallo, Kevin; Jenkerson, Calli B.; Dwyer, John L.

    2013-01-01

    This study provides a baseline quality check on provisional Landsat Surface Reflectance (SR) products as generated by the U.S. Geological Survey (USGS) Earth Resources Observation and Science (EROS) Center using Landsat Ecosystem Disturbance Adaptive Processing System (LEDAPS) software. Characterization of the Landsat SR products leveraged comparisons between aerosol optical thickness derived from LEDAPS and measured by Aerosol Robotic Network (AERONET), as well as reflectance correlations with field spectrometer and Moderate Resolution Imaging Spectroradiometer (MODIS) data. Results consistently indicated similarity between LEDAPS and alternative data products in longer wavelengths over vegetated areas with no adjacent water, while less reliable performance was observed in shorter wavelengths and sparsely vegetated areas. This study demonstrates the strengths and weaknesses of the atmospheric correction methodology used in LEDAPS, confirming its successful implementation to generate Landsat SR products.

  19. Reflection of X-rays from a rough surface at extremely small grazing angles.

    Science.gov (United States)

    Wen, Mingwu; Kozhevnikov, Igor V; Wang, Zhanshan

    2015-09-21

    Peculiarities of X-ray diffraction from a rough surface at an extremely small grazing angle of an incident beam are theoretically studied. The interrelation of four diffraction channels (coherent reflectance, coherent transmittance, diffuse scattering in vacuum, and scattering into the matter depth) is analyzed for different limiting cases (large and small correlation length of roughness and large and extremely small grazing angle of incident radiation). Both the Debye-Waller and the Nevot-Croce factors are demonstrated to describe improperly the features of X-ray diffraction at extremely small grazing angles. More appropriate simple analytic expressions for the specular reflectivity and total integrated scattering in vacuum are obtained instead. Transformation of one limiting diffraction regime into another one with variation in the correlation length of roughness is discussed.

  20. Mathematical Modeling of Radiant Heat Transfer in Mirror Systems Considering Deep Reflecting Surface Defects

    Directory of Open Access Journals (Sweden)

    V. V. Leonov

    2014-01-01

    Full Text Available When designing large-sized mirror concentrating systems (MCS for high-temperature solar power plants, one must have at disposal reasonably reliable and economical methods and tools, making it possible to analyze its characteristics, to predict them depending on the operation conditions and accordingly to choose the most suitable system for the solution of particular task.Experimental determination of MCS characteristics requires complicated and expensive experimentation, having significant limitations on interpretation of the results, as well as limitations imposed due to the size of the structure. Therefore it is of particular interest to develop a mathematical model capable of estimating power characteristics of MCS considering the influence of operating conditions, design features, roughness and other surface defects.For efficient solution of the tasks the model must ensure simulation of solar radiant flux as well as simulation of geometrical and optical characteristics of reflection surface and their interaction. In this connection a statistical mathematical model of radiation heat exchange based on use of Monte Carlo methods and Finite Element Method was developed and realized in the software complex, making it possible to determine main characteristics of the MCS.In this paper the main attention is given to definition of MCS radiation characteristics with account for deep reflecting surface defects (cavities, craters. Deep cavities are not typical for MCS, but their occurrence is possible during operation as a result of erosion or any physical damage. For example, for space technology it is primarily micrometeorite erosion.

  1. Influence of coffee on reflectance and chemistry of resin composite protected by surface sealant.

    Science.gov (United States)

    Soares, Luís Eduardo Silva; Cesar, Ilene Cristine Rosia; Santos, Carla Gabriela Couto; De Cardoso, Ana Luiza Merigo Oliveira; Liporoni, Priscila Christiane Suzy; Munin, Egberto; Martin, Airton Abrahão

    2007-10-01

    To assess the influence of the light-curing unit type and whether or not it was worth using surface sealant protection on resin composite restorative materials stained by coffee. Another objective was to propose the monitoring of coffee staining by FT-Raman spectroscopy using carbon-hydrogen (C-H) bonds as reference to the composite matrix degradation. Sixty cylindrical specimens of resin composite were prepared and divided into six groups: HC (control)--cured with a halogen light; LC (control) cured with a LED; HF--cured with a halogen light + Fortify Plus; LF--cured with a LED + Fortify Plus; HP--cured with a halogen light + PermaSeal; LP--cured with a LED + PermaSeal. After storage for 24 hours at 37% and 100% of relative humidity, the top surface was protected, and the other surfaces isolated. Polishing with paper discs was performed after 24 hours of curing and prior to FT-Raman spectroscopy and reflectance measurements. All specimens were submitted to coffee staining for 14 days and evaluated by both systems. Results were statistically analyzed by ANOVA and Tukey tests. FT-Raman spectrum only showed significant changes in groups LC and LP (P< 0.05). Reflectance demonstrated that staining was present in all specimens protected by sealants. Sealant staining was larger in the HF (P < 0.001) group.

  2. High laser damage threshold surface relief micro-structures for anti-reflection applications

    Science.gov (United States)

    Hobbs, Douglas S.; MacLeod, Bruce D.

    2008-01-01

    Microstructures built into the surfaces of an optic or window, are an effective replacement for thin-film coatings in anti-reflection (AR) and narrow-band filter applications. AR microstructures exhibit particularly noteworthy performance where an average reflection loss of less than 0.2% over a four-octave range (400-1800nm) has been demonstrated, and a loss of less than 0.03% is routinely achieved for narrow-band applications. Because AR micro-textures provide a gradual change in the refractive index at a material boundary, it is expected that light can propagate through the boundary without material damage at energy levels that are much higher than that found with thin-film interference coatings. Recently, it was shown that the laser induced damage threshold (LIDT) of an inexpensive borosilicate glass window containing AR microstructures was nearly 57 J/cm2 at 1064nm (20ns pulse). This LIDT is two to three times greater than the damage threshold of single-layer sol-gel AR coatings on fused silica often reported in the literature. The development of surface relief AR textures for use in high-energy laser applications is presented. Data from scanning electron microscope (SEM) analysis, reflection measurements, and LIDT testing, is shown for high performance AR microstructures fabricated in fused silica, and borosilicate glass. Results of LIDT testing at wavelengths ranging from the near ultraviolet through the near infrared confirm the initial result that AR microstructures can operate at pulsed laser power levels at least two times higher than thin-film coatings. For near infrared applications such as laser weapons and fiber optic communications requiring high performance AR, LIDT levels for AR microstructures in fused silica are found to be at least five times greater than conventional multi-layer thin film coatings. An initial surface absorption test at 1064nm shows that AR microstructures may also exhibit improved lifetimes within continuous wave laser systems.

  3. A Conceptual Model of Surface Reflectance Estimation for Satellite Remote Sensing Images Using in situ Reference Data

    Directory of Open Access Journals (Sweden)

    Ke-Sheng Cheng

    2012-03-01

    Full Text Available For satellite remote sensing, radiances received at the sensor are not only affected by the atmosphere but also by the topographic properties of the terrain surface. As a result, atmospheric correction alone does not yield output images that truly reflect terrain surface properties, namely surface reflectance (bidirectional reflectance factor, BRF of objects on the earth surface. Following the concept of the radiometric control area (RCA-based path radiance estimation method, we herein propose a statistical approach for surface reflectance estimation utilizing DEM data and surface reflectance of selected radiometric control areas. An algorithm for identification of shaded samples and a shape factor model were also developed in this study. The proposed RCA-based surface reflectance estimation method is capable of achieving good reflectance estimates in a region where elevation varies from 0 to approximately 600 m above the mean sea level. However, further study is recommended in order to extend the application of the proposed method to areas with substantial terrain variation.

  4. Multipitched Diffraction Gratings for Surface Plasmon Resonance-Enhanced Infrared Reflection Absorption Spectroscopy.

    Science.gov (United States)

    Petefish, Joseph W; Hillier, Andrew C

    2015-11-03

    We demonstrate the application of metal-coated diffraction gratings possessing multiple simultaneous pitch values for surface enhanced infrared absorption (SEIRA) spectroscopy. SEIRA increases the magnitude of vibrational signals in infrared measurements by one of several mechanisms, most frequently involving the enhanced electric field associated with surface plasmon resonance (SPR). While the majority of SEIRA applications to date have employed nanoparticle-based plasmonic systems, recent advances have shown how various metals and structures lead to similar signal enhancement. Recently, diffraction grating couplers have been demonstrated as a highly tunable platform for SEIRA. Indeed, gratings are an experimentally advantageous platform due to the inherently tunable nature of surface plasmon excitation at these surfaces since both the grating pitch and incident angle can be used to modify the spectral location of the plasmon resonance. In this work, we use laser interference lithography (LIL) to fabricate gratings possessing multiple pitch values by subjecting photoresist-coated glass slides to repetitive exposures at varying orientations. After metal coating, these gratings produced multiple, simultaneous plasmon peaks associated with the multipitched surface, as identified by infrared reflectance measurements. These plasmon peaks could then be coupled to vibrational modes in thin films to provide localized enhancement of infrared signals. We demonstrate the flexibility and tunability of this platform for signal enhancement. It is anticipated that, with further refinement, this approach might be used as a general platform for broadband enhancement of infrared spectroscopy.

  5. Classification of Clean and Dirty Pighouse Surfaces Based on Spectral Reflectance

    DEFF Research Database (Denmark)

    Blanke, Mogens; Braithwaite, Ian David; Zhang, Guo-Qiang

    2004-01-01

    Current pig house cleaning procedures are hazardous to the health of farm workers, and yet necessary if the spread of disease between batches of animals is to be satisfactorily controlled. Autonomous cleaning using robot technology offers salient benefits. This report addresses the feasibility...... of designing a vision based system to locate dirty areas and subsequently direct a cleaning robot to remove dirt. Novel results include the characterisation of the spectral reflectance of real surfaces and dirt in a pig house and the design of illumination to obtain discrimination of clean from dirty areas...

  6. Vertical-cavity surface-emitting laser vapor sensor using swelling polymer reflection modulation

    DEFF Research Database (Denmark)

    Ansbæk, Thor; Nielsen, Claus Højgård; Dohn, Søren

    2012-01-01

    Vapor detection using a low-refractive index polymer for reflection modulation of the top mirror in a vertical-cavity surface-emitting laser (VCSEL) is demonstrated. The VCSEL sensor concept presents a simple method to detect the response of a sensor polymer in the presence of volatile organic co...... compounds. We model the physics as a change in the top mirror loss caused by swelling of the polymer upon absorbing the target volatile organic compound. Further we show how acetone vapors at 82 000 ppm concentration can change the polymer coated VCSEL output power by 20 mu W....

  7. Development and applications of retro-reflective surfaces for ultrasound in LBE

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2015-07-01

    pulse or a complete absence of a reflection like a shadow. In that way, it suffices to align the sensor with the diaphragm instead of the fuel assembly which is much easier to achieve as the robotics on which the sensor is mounted move parallel with the diaphragm. The alignment requirement in the latter approach can be further relaxed by using a tiling of retro-reflectors on the lower surface of the diaphragm. In that way, alignment becomes less vital and the main source of acoustic energy loss - geometric spread of the beam - is almost completely removed, leaving only absorption losses. In this paper, we present the first results in developing a retro reflectance surface for ultrasound in LBE. We present experimental results for different designs of retro-reflectors in both water and LBE. We discuss both linear and array retro-reflectors of different sizes and investigate the influence of the main relevant ultrasonic parameters such as wavelength and spot size on the strength of the received reflection under different alignment angles. We also demonstrate how retro-reflective surfaces can be exploited when localizing objects using linear and rotating scanning methods. (authors)

  8. A poly-epoxy surface explored by Hartree-Fock ΔSCF simulations of C1s XPS spectra.

    Science.gov (United States)

    Gavrielides, A; Duguet, T; Esvan, J; Lacaze-Dufaure, C; Bagus, P S

    2016-08-21

    Whereas poly-epoxy polymers represent a class of materials with a wide range of applications, the structural disorder makes them difficult to model. In the present work, we use good experimental model samples in the sense that they are pure, fully polymerized, flat and smooth, defect-free, and suitable for ultrahigh vacuum x-ray photoelectron spectroscopy, XPS, experiments. In parallel, we perform Hartree-Fock, HF, calculations of the binding energies, BEs, of the C1s electrons in a model molecule composed of the two constituents of the poly-epoxy sample. These C1s BEs were determined using the HF ΔSCF method, which is known to yield accurate values, especially for the shifts of the BEs, ΔBEs. We demonstrate the benefits of combining rigorous theory with careful XPS measurements in order to obtain correct assignments of the C1s XPS spectra of the polymer sample. Both the relative binding energies-by the ΔSCF method-and relative intensities-in the sudden approximation, SA, are calculated. It results in an excellent match with the experimental spectra. We are able to identify 9 different chemical environments under the C1s peak, where an exclusively experimental work would have found only 3 contributions. In addition, we observe that some contributions are localized at discrete binding energies, whereas others allow a much wider range because of the variation of their second neighbor bound polarization. Therefore, HF-ΔSCF simulations significantly increase the spectral resolution of XPS and thus offer a new avenue for the exploration of the surface of polymers.

  9. Modified polarimetric bidirectional reflectance distribution function with diffuse scattering: surface parameter estimation

    Science.gov (United States)

    Zhan, Hanyu; Voelz, David G.

    2016-12-01

    The polarimetric bidirectional reflectance distribution function (pBRDF) describes the relationships between incident and scattered Stokes parameters, but the familiar surface-only microfacet pBRDF cannot capture diffuse scattering contributions and depolarization phenomena. We propose a modified pBRDF model with a diffuse scattering component developed from the Kubelka-Munk and Le Hors et al. theories, and apply it in the development of a method to jointly estimate refractive index, slope variance, and diffuse scattering parameters from a series of Stokes parameter measurements of a surface. An application of the model and estimation approach to experimental data published by Priest and Meier shows improved correspondence with measurements of normalized Mueller matrix elements. By converting the Stokes/Mueller calculus formulation of the model to a degree of polarization (DOP) description, the estimation results of the parameters from measured DOP values are found to be consistent with a previous DOP model and results.

  10. Barium fluoride surface preparation, analysis and UV reflective coatings at Lawrence Livermore National Laboratory

    International Nuclear Information System (INIS)

    Wuest, C.R.

    1992-01-01

    Lawrence Livermore National Laboratory (LLNL) has begun a program of study on barium fluoride scintillating crystals for the Barium Fluoride Electromagnetic Calorimeter Collaboration. This program has resulted in a number of significant improvements in the mechanical processing, polishing and coating of barium fluoride crystals. Techniques have been developed using diamond-loaded pitch lapping that can produce 15 angstrom RMS surface finishes over large areas. These lapped surfaces have been shown to be crystalline using Rutherford Back-scattering (RBS). Also, special polishing fixtures have been designed based on mounting technology developed for the 1.1 m diameter optics used in LLNL's Nova Laser. These fixtures allow as many as five 25--50 cm long barium fluoride crystals to be polished and lapped at a time with the necessary tolerances for the 16,000 crystal Barium Fluoride Calorimeter. In addition, results will be presented on coating barium fluoride with UV reflective layers of magnesium fluoride and aluminum

  11. Enhanced Group Delay of the Pulse Reflection with Graphene Surface Plasmon via Modified Otto Configuration

    Directory of Open Access Journals (Sweden)

    Guimei Li

    2017-01-01

    Full Text Available In this paper, the group delay of the transverse magnetic (TM polarized wave reflected from a modified Otto configuration with graphene surface plasmon is investigated theoretically. The findings show that the optical group delay in this structure can be enhanced negatively and can be switched from negative to positive due to the excitation of surface plasmon by graphene. It is clear that the negative group delay can be actively tuned through the Fermi energy of the graphene. Furthermore, the delay properties can also be manipulated by changing either the relaxation time of graphene or the distance between the coupling prism and the graphene. These tunable delay characteristics are promising for fabricating grapheme-based optical delay devices and other applications in the terahertz regime.

  12. Improved Near-surface Velocity Models from Waveform Tomography Applied to Vibroseis MCS Reflection Data

    Science.gov (United States)

    Smithyman, B.; Clowes, R. M.

    2009-12-01

    Multichannel vibroseis reflection surveys are prevalent in the land exploration seismic industry because of benefits in speed and cost, along with reduced environmental impact when compared to explosive sources. Since the downgoing energy must travel through the shallow subsurface, an improved model of near-surface velocity can in theory substantially improve the resolution of deeper reflections. We describe techniques aimed at allowing the use of vibroseis data for long-offset refraction processing of first-arrival traveltimes and waveforms. Refraction processing of surface vibroseis data is typically limited to near-offset refraction statics. Velocity models of the shallow subsurface can be built to facilitate CDP stacking and migration, but these models are typically coarse and of limited use for interpretation. Waveform tomography combines inversion of first-arrival traveltime data with full waveform inversion of densely-sampled refracted arrivals. Since inversion of the waveform amplitude and phase is not limited by the ray-theory approximation, identification of low-velocity zones and small scattering targets is possible. Incorporating a wide range of offsets is critical for a more complete characterization of the near-surface. Because of the use of a non-linear frequency-domain approach to the solution of this inverse problem, low data frequencies are important in comparison with conventional reflection processing. Through the use of waveform tomography, we plan to build useful, detailed near-surface velocity models for both the reflection work flow and direct interpretation. Several difficulties exist in first-arrival analysis and waveform inversion of vibroseis data. The mixed-phase vibroseis source signature exhibits variations in phase with offset that are difficult to quantify without detailed a priori knowledge of the near-surface. This causes difficulties with picking and initial model building, which is critical for non-linear waveform inversion. A

  13. Estimation of Melt Ponds over Arctic Sea Ice using MODIS Surface Reflectance Data

    Science.gov (United States)

    Ding, Y.; Cheng, X.; Liu, J.

    2017-12-01

    Melt ponds over Arctic sea ice is one of the main factors affecting variability of surface albedo, increasing absorption of solar radiation and further melting of snow and ice. In recent years, a large number of melt ponds have been observed during the melt season in Arctic. Moreover, some studies have suggested that late spring to mid summer melt ponds information promises to improve the prediction skill of seasonal Arctic sea ice minimum. In the study, we extract the melt pond fraction over Arctic sea ice since 2000 using three bands MODIS weekly surface reflectance data by considering the difference of spectral reflectance in ponds, ice and open water. The preliminary comparison shows our derived Arctic-wide melt ponds are in good agreement with that derived by the University of Hamburg, especially at the pond distribution. We analyze seasonal evolution, interannual variability and trend of the melt ponds, as well as the changes of onset and re-freezing. The melt pond fraction shows an asymmetrical growth and decay pattern. The observed melt ponds fraction is almost within 25% in early May and increases rapidly in June and July with a high fraction of more than 40% in the east of Greenland and Beaufort Sea. A significant increasing trend in the melt pond fraction is observed for the period of 2000-2017. The relationship between melt pond fraction and sea ice extent will be also discussed. Key Words: melt ponds, sea ice, Arctic

  14. Spectrally adjusted surface reflectance and its dependence with NDVI for Landsat and Sentinel 2

    Science.gov (United States)

    Villaescusa, J. L.; Franch, B.; Roger, J. C.; Vermote, E.; Justice, C. O.

    2017-12-01

    Cross-calibration between sensors is necessary to bring measurements to a common radiometric scale; it allows a more complete monitoring of land surface processes and enhances data continuity and harmonization. However, differences in the Relative Spectral Response (RSR) of sensors generate uncertainties in the process (Teillet et al., 2004). For this reason, compensating for these differences is of great importance and can be achieved by using a spectral band adjustment factor (SBAF), which establishes a relationship between two spectrally adjusted bands. Nonetheless, this relationship has been shown to depend greatly on the surface's NDVI (Trishchenko et al., 2002) and therefore needs to be corrected. In this work, we use the Sentinel 2 and Landsat sensor's RSRs for both the Red and NIR bands to find the most accurate metric towards performing said relationship, and use surface reflectance spectral libraries with a wide variety of classes that include NDVI values ranging from -0.1 to 1 to analyze its dependence. We compute a quadratic fit of the metric used vs the surface's NDVI and propose an adjusted correction equation dependent on the NDVI value for both bands of all Landsat and Sentinel 2 sensors. Key words: Radiometric calibration, RSR, Spectral Adjustment, Landsat, Sentinel 2.

  15. Airborne hyperspectral observations of surface and cloud directional reflectivity using a commercial digital camera

    Directory of Open Access Journals (Sweden)

    A. Ehrlich

    2012-04-01

    Full Text Available Spectral radiance measurements by a digital single-lens reflex camera were used to derive the directional reflectivity of clouds and different surfaces in the Arctic. The camera has been calibrated radiometrically and spectrally to provide accurate radiance measurements with high angular resolution. A comparison with spectral radiance measurements with the Spectral Modular Airborne Radiation measurement sysTem (SMART-Albedometer showed an agreement within the uncertainties of both instruments (6% for both. The directional reflectivity in terms of the hemispherical directional reflectance factor (HDRF was obtained for sea ice, ice-free ocean and clouds. The sea ice, with an albedo of ρ = 0.96 (at 530 nm wavelength, showed an almost isotropic HDRF, while sun glint was observed for the ocean HDRF (ρ = 0.12. For the cloud observations with ρ = 0.62, the cloudbow – a backscatter feature typically for scattering by liquid water droplets – was covered by the camera. For measurements above heterogeneous stratocumulus clouds, the required number of images to obtain a mean HDRF that clearly exhibits the cloudbow has been estimated at about 50 images (10 min flight time. A representation of the HDRF as a function of the scattering angle only reduces the image number to about 10 (2 min flight time.

    The measured cloud and ocean HDRF have been compared to radiative transfer simulations. The ocean HDRF simulated with the observed surface wind speed of 9 m s−1 agreed best with the measurements. For the cloud HDRF, the best agreement was obtained by a broad and weak cloudbow simulated with a cloud droplet effective radius of Reff = 4 μm. This value agrees with the particle sizes derived from in situ measurements and retrieved from the spectral radiance of the SMART-Albedometer.

  16. Reference-free total reflection X-ray fluorescence analysis of semiconductor surfaces with synchrotron radiation.

    Science.gov (United States)

    Beckhoff, Burkhard; Fliegauf, Rolf; Kolbe, Michael; Müller, Matthias; Weser, Jan; Ulm, Gerhard

    2007-10-15

    Total reflection X-ray fluorescence (TXRF) analysis is a well-established method to monitor lowest level contamination on semiconductor surfaces. Even light elements on a wafer surface can be excited effectively when using high-flux synchrotron radiation in the soft X-ray range. To meet current industrial requirements in nondestructive semiconductor analysis, the Physikalisch-Technische Bundesanstalt (PTB) operates dedicated instrumentation for analyzing light element contamination on wafer pieces as well as on 200- and 300-mm silicon wafer surfaces. This instrumentation is also suited for grazing incidence X-ray fluorescence analysis and conventional energy-dispersive X-ray fluorescence analysis of buried and surface nanolayered structures, respectively. The most prominent features are a high-vacuum load-lock combined with an equipment front end module and a UHV irradiation chamber with an electrostatic chuck mounted on an eight-axis manipulator. Here, the entire surface of a 200- or a 300-mm wafer can be scanned by monochromatized radiation provided by the plane grating monochromator beamline for undulator radiation in the PTB laboratory at the electron storage ring BESSY II. This beamline provides high spectral purity and high photon flux in the range of 0.078-1.86 keV. In addition, absolutely calibrated photodiodes and Si(Li) detectors are used to monitor the exciting radiant power respectively the fluorescence radiation. Furthermore, the footprint of the excitation radiation at the wafer surface is well-known due to beam profile recordings by a CCD during special operation conditions at BESSY II that allow for drastically reduced electron beam currents. Thus, all the requirements of completely reference-free quantitation of TXRF analysis are fulfilled and are to be presented in the present work. The perspectives to arrange for reference-free quantitation using X-ray tube-based, table-top TXRF analysis are also addressed.

  17. LBA-ECO CD-34 Hyperion 30-m Surface Reflectance, Amazon Basin: 2002-2005

    Data.gov (United States)

    National Aeronautics and Space Administration — ABSTRACT: This data set contains 20 multispectral surface reflectance images collected by the EO-1 satellite Hyperion sensor at 30-m resolution and covering the...

  18. OMI/Aura Surface Reflectance Climatology Level 3 Global 0.5deg Lat/Lon Grid V003

    Data.gov (United States)

    National Aeronautics and Space Administration — The OMI Earth Surface Reflectance Climatology product, OMLER (Global 0.5deg Lat/Lon grid) which is based on Version 003 Level-1B top of atmosphere upwelling radiance...

  19. CLPX-Satellite: EO-1 Hyperion Surface Reflectance, Snow-Covered Area, and Grain Size, Version 1

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set consists of apparent surface reflectance, subpixel snow-covered area, and grain size collected from the Hyperion hyperspectral imager. The Hyperion...

  20. MODIS/Aqua Surface Reflectance Daily L2G Global 1km and 500m SIN Grid V006

    Data.gov (United States)

    National Aeronautics and Space Administration — The MYD09GA Version 6 product provides an estimate of the surface spectral reflectance of AQUA MODIS Bands 1-7 corrected for atmospheric conditions such as gasses,...

  1. MODIS/Terra Surface Reflectance Daily L2G Global 1km and 500m SIN Grid V006

    Data.gov (United States)

    National Aeronautics and Space Administration — The MOD09GA Version 6 product provides an estimate of the surface spectral reflectance of Terra MODIS Bands 1-7 corrected for atmospheric conditions such as gasses,...

  2. A prototype for automation of land-cover products from Landsat Surface Reflectance Data Records

    Science.gov (United States)

    Rover, J.; Goldhaber, M. B.; Steinwand, D.; Nelson, K.; Coan, M.; Wylie, B. K.; Dahal, D.; Wika, S.; Quenzer, R.

    2014-12-01

    Landsat data records of surface reflectance provide a three-decade history of land surface processes. Due to the vast number of these archived records, development of innovative approaches for automated data mining and information retrieval were necessary. Recently, we created a prototype utilizing open source software libraries for automatically generating annual Anderson Level 1 land cover maps and information products from data acquired by the Landsat Mission for the years 1984 to 2013. The automated prototype was applied to two target areas in northwestern and east-central North Dakota, USA. The approach required the National Land Cover Database (NLCD) and two user-input target acquisition year-days. The Landsat archive was mined for scenes acquired within a 100-day window surrounding these target dates, and then cloud-free pixels where chosen closest to the specified target acquisition dates. The selected pixels were then composited before completing an unsupervised classification using the NLCD. Pixels unchanged in pairs of the NLCD were used for training decision tree models in an iterative process refined with model confidence measures. The decision tree models were applied to the Landsat composites to generate a yearly land cover map and related information products. Results for the target areas captured changes associated with the recent expansion of oil shale production and agriculture driven by economics and policy, such as the increase in biofuel production and reduction in Conservation Reserve Program. Changes in agriculture, grasslands, and surface water reflect the local hydrological conditions that occurred during the 29-year span. Future enhancements considered for this prototype include a web-based client, ancillary spatial datasets, trends and clustering algorithms, and the forecasting of future land cover.

  3. Quantification of phosphorus metabolites in human calf muscle and soft-tissue tumours from localized MR spectra acquired using surface coils

    Science.gov (United States)

    Doyle, V. L.; Payne, G. S.; Collins, D. J.; Verrill, M. W.; Leach, M. O.

    1997-04-01

    Metabolite concentrations determined from MR spectra provide more specific information than peak area ratios. This paper presents a method of quantification that allows metabolite concentrations to be determined from in vivo MR spectra acquired using a surface coil and ISIS localization. Corrections for the effects of field inhomogeneity produced by surface coils are based on a measured and calibrated spatial sensitivity field map for the coil. Account is taken of imperfections in pulse performance, coil loading effects and relaxation effects, the latter making use of published metabolite relaxation times. The technique is demonstrated on model solutions. The concentrations of the main metabolites in normal human calf muscle measured using this method are [PCr] = ; [Pi] = ; [NTP] = . Quantification of spectra acquired from soft-tissue tumours in patients both pre- and post-treatment showed that changes in metabolite concentrations are more sensitive to metabolic changes than changes in peak area ratios.

  4. 30-m Land Surface Albedo by Integrating Landsat directional reflectance and MODIS anisotropic information

    Science.gov (United States)

    Shuai, Y.; Masek, J. G.; Gao, F.; Schaaf, C.; Williams, C. A.; Wang, Z.

    2012-12-01

    Land surface albedo as a key physical variable determining the solar energy absorbed by the land surface, and can affect climate through ecosystem feedback processes. Some studies have highlighted that positive radiative forcing (warming) induced by increased forest cover and decreased albedo in temperate and boreal forest regions could offset the negative forcing expected from carbon sequestration (Betts 2000). However, these studies have not used data at the spatial resolution of human land dynamics (e.g. 30m Landsat resolution). Therefore, there is a need for improved estimates of land surface albedo at high resolution to fully understand the role of land cover change in climate forcing and carbon cycle. Following our initial "concurrent" approach applied to Landsat data acquired during the post-2000 MODIS era (Shuai et al.2011), we have developed a "pre-MODIS era" approach to generate 30-meter albedos using Landsat surface directional reflectance (1970s-2000) and Look-Up-Tables (LUT) of anisotropy information extracted from MODIS BRDF data. We use a NLCD (National Land Cover Dataset)-class-based LUT for non-disturbed land cover. Disturbed forest patches are identified from the Monitoring Trends in Burn Severity (MTBS) and North American Forest Dynamics (NAFD) datasets. For each category, high quality MODIS BRDF parameters (MCD43A1 product) are retrieved and used to populate the LUT. Each entry in the LUT reflects a unique combination of land cover type, disturbance age and type, season/month, and sensor bands. The initial BRDF LUT generated for the Pacific Northwest of the United States exhibits various BRDF evolution trajectories for disturbed classes, including different recovery trajectories for fire and non-fire disturbance. The albedo-to-nadir-ratio method (Shuai et al., 2011) is applied to the BRDF LUT to calculate spectral albedos, followed by a narrow-to-broadband conversion (Liang 2000) to generate broad-band shortwave albedo. Our preliminary

  5. X-ray Reflectivity Study of Ionic Liquids at Electrified Surfaces

    Science.gov (United States)

    Chu, Miaoqi

    X-ray reflectivity (XRR) versatile technique that characterize the surface structures. However, due to the lack of phase information of X-ray data, the reconstruction of electron density profile (EDP) from XRR data is an ill-posed inverse problem that requires extra attention. In Chapter 1, several key concepts in XRR data analysis are reviewed. The typical XRR data acquisition procedure and methods of modeling electron density are introduced. The widely used logarithm form of merit function is justified with mathematical deduction and numerical experiment. A scheme that generates artificial reflectivity data with theoretical statistical error but not systematical error is proposed. With the methods and schemes described in Chapter 1, simulated reflectivity data of a simple one-slab model is generated and fitted to test the efficient of EDP reconstruction. By isolating the parameters, the effects of slab width, electron density contrast and maximal wave transfer are studied individually. It?s demonstrated that best-fit/global minima, result reported by most XRR studies, don?t necessary reflect the real EDP. By contrast, mapping the merit function in the parametric space can capture much more details. Additionally, the widely accepted concept about the XRR theoretical spatial resolution (pi/q_{max}) as well the using Patterson function are brought to test. In the perspective of XRR data analysis, this chapter puts forward general rules to design and optimize XRR experiments. It also demonstrates how susceptible the fitting result will be if it?s not done carefully. In Chapter 3, the interface between hydrophobic OTS film and several solvents is studied with XRR in a transmission-cell setup. The solvents, from water, acetone, to alcohol (methanol, ethanol, 1-propanol), to alkane (pentane, hexane and heptane), vary significantly in terms of polarity and hydrogen bonding. However, the XRR data from different solvents are subtle. The methods and principles elicited in

  6. Neutron reflectivity study of substrate surface chemistry effects on supported phospholipid bilayer formation on (1120) sapphire.

    Energy Technology Data Exchange (ETDEWEB)

    Oleson, Timothy A. [University of Wisconsin, Madison; Sahai, Nita [University of Akron; Wesolowski, David J [ORNL; Dura, Joseph A [ORNL; Majkrzak, Charles F [ORNL; Giuffre, Anthony J. [University of Wisconsin, Madison

    2012-01-01

    Oxide-supported phospholipid bilayers (SPBs) used as biomimetric membranes are significant for a broad range of applications including improvement of biomedical devices and biosensors, and in understanding biomineralization processes and the possible role of mineral surfaces in the evolution of pre-biotic membranes. Continuous-coverage and/or stacjed SPBs retain properties (e.,g. fluidity) more similar to native biological membranes, which is desirable for most applications. Using neutron reflectivity, we examined face coverage and potential stacking of dipalmitoylphosphatidylcholine (DPPC) bilayers on the (1120) face of sapphire (a-Al2O3). Nearly full bilayers were formed at low to neutral pH, when the sapphire surface is positively charged, and at low ionic strength (l=15 mM NaCl). Coverage decreased at higher pH, close to the isoelectric point of sapphire, and also at high I>210mM, or with addition of 2mM Ca2+. The latter two effects are additive, suggesting that Ca2+ mitigates the effect of higher I. These trends agree with previous results for phospholipid adsorption on a-Al2O3 particles determined by adsorption isotherms and on single-crystal (1010) sapphire by atomic force microscopy, suggesting consistency of oxide surface chemistry-dependent effects across experimental techniques.

  7. Sn-L3 EDGE and Fe K edge XANES spectra of the surface layer of ancient Chinese black mirror Heiqigu

    International Nuclear Information System (INIS)

    Gaowei Mengjia; Liu Yuzhen; Chu Wangsheng; Wu Ziyu; Wang Changsui

    2009-01-01

    The Chinese ancient black mirror known as Heiqigu was studied by x-ray-absorption near-edge structure spectroscopy and results were reported. The Sn-L 3 edge and Fe K edge spectra further confirmed the Schottky-type defect model in the Heiqigu surface system. And it was suggested that the surface layer of the mirror was a combined structure of oxidation of Sn(IV) and Sn(II). (authors)

  8. Recent Developments in the X-Ray Reflectivity Analysis for Rough Surfaces and Interfaces of Multilayered Thin Film Materials

    Directory of Open Access Journals (Sweden)

    Yoshikazu Fujii

    2013-01-01

    Full Text Available X-ray reflectometry is a powerful tool for investigations on rough surface and interface structures of multilayered thin film materials. The X-ray reflectivity has been calculated based on the Parratt formalism, accounting for the effect of roughness by the theory of Nevot-Croce conventionally. However, in previous studies, the calculations of the X-ray reflectivity often show a strange effect where interference effects would increase at a rough surface. And estimated surface and interface roughnesses from the X-ray reflectivity measurements did not correspond to the TEM image observation results. The strange result had its origin in a used equation due to a serious mistake in which the Fresnel transmission coefficient in the reflectivity equation is increased at a rough interface because of a lack of consideration of diffuse scattering. In this review, a new accurate formalism that corrects this mistake is presented. The new accurate formalism derives an accurate analysis of the X-ray reflectivity from a multilayer surface of thin film materials, taking into account the effect of roughness-induced diffuse scattering. The calculated reflectivity by this accurate reflectivity equation should enable the structure of buried interfaces to be analyzed more accurately.

  9. A sea surface reflectance model for (A)ATSR, and application to aerosol retrievals

    Science.gov (United States)

    Sayer, A. M.; Thomas, G. E.; Grainger, R. G.

    2010-07-01

    A model of the sea surface bidirectional reflectance distribution function (BRDF) is presented for the visible and near-IR channels (over the spectral range 550 nm to 1.6 μm) of the dual-viewing Along-Track Scanning Radiometers (ATSRs). The intended application is as part of the Oxford-RAL Aerosols and Clouds (ORAC) retrieval scheme. The model accounts for contributions to the observed reflectance from whitecaps, sun-glint and underlight. Uncertainties in the parametrisations used in the BRDF model are propagated through into the forward model and retrieved state. The new BRDF model offers improved coverage over previous methods, as retrievals are possible into the sun-glint region, through the ATSR dual-viewing system. The new model has been applied in the ORAC aerosol retrieval algorithm to process Advanced ATSR (AATSR) data from September 2004 over the south-eastern Pacific. The assumed error budget is shown to be generally appropriate, meaning the retrieved states are consistent with the measurements and a priori assumptions. The resulting field of aerosol optical depth (AOD) is compared with colocated MODIS-Terra observations, AERONET observations at Tahiti, and cruises over the oceanic region. MODIS and AATSR show similar spatial distributions of AOD, although MODIS reports values which are larger and more variable. It is suggested that assumptions in the MODIS aerosol retrieval algorithm may lead to a positive bias in MODIS AOD of order 0.01 at 550 nm over ocean regions where the wind speed is high.

  10. Mixed polymer conductors for control of microwave reflectivity surfaces. Volume I

    International Nuclear Information System (INIS)

    Despotakis, A.

    1998-06-01

    The preparation and characterisation of polyaniline-silver-polymer electrolyte composite materials are described and their potential application as large area surfaces with microwave reflection/transmission controlled by application of an electric field ('microwave shutters') is investigated. The component polymer electrolyte (largely polyether-silver salt) and the polyaniline-silver salt mixtures have been separately investigated using a range of spectroscopic, microscopic and electrical impedance techniques. The redox behaviour of polyaniline versus silver in various cells incorporating polymer electrolytes have been studied in both ambient and 'dry' nitrogen environments using cyclic voltammetry and square wave potentiometry. It is proposed that the redox behaviour in dry nitrogen conditions involves the formation of leucoemeraldine-Ag + complex. This promotes the spontaneous reduction of emeraldine salt to leucoemeraldine by silver metal in contrast to the equilibrium status of the system in ambient conditions. In ambient conditions, the emeraldine undergoes an acid-base transition in the presence of silver salt (with(out) elemental silver). Furthermore, X-ray analysis has revealed that it is possible to chemically generate elemental silver after mixing its silver salt with the emeraldine (either salt or base form) in ambient conditions. Discs of various polyaniline-silver-polymer electrolyte compositions have been reported. Significant and rapid changes in microwave reflectivities have been observed. The mechanisms of electrochemical changes within the composites have been discussed and a 'cascade' process for the propagation of the switching effect across the areas of the discs has been proposed. (author)

  11. Relationship between the velvet-like texture of flower petals and light reflection from epidermal cell surfaces.

    Science.gov (United States)

    Zhang, Yang; Sun, Tianxun; Xie, Linan; Hayashi, Takahiro; Kawabata, Saneyuki; Li, Yuhua

    2015-07-01

    Texture such as velvet lustre contributes to the ornamental character of a flower, along with shape and colour. This study aims to clarify the relationship between the formation of the velvet lustre texture and the optical characteristics of light reflection from irradiated surfaces of velvety and non-velvety petals from 30 cultivars or varieties of ornamental plants representing 19 species from various families. The angle of incident light from the petal surface was set at 90°, 60° or 30°, then light reflection from the petal surfaces was observed using a digital microscope. The observed reflected light was composed of "exterior" reflected light (ERL), which is observed as sparkling white spots on the surface of the epidermal cells, and "interior" reflected light (IRL), which is reflected from inside the petal and determines the base colour of the petals. Velvety petals had two common characteristics: conical-papillate or domed epidermal cells and a dark colour. As the angle between the petal and the incident light decreased, the ERL spots took on a belt-like shape, and total ERL intensity became stronger. We concluded that the velvety texture is derived from characteristic ERL rays coupled with dark IRL. The long sloping surface of the epidermal cells contributes to the higher ERL intensity as petals are observed from more horizontal angles, causing characteristic reverse shading effects on velvety petals.

  12. A Harmonized Landsat-Sentinel-2 Surface Reflectance product: a resource for Agricultural Monitoring

    Science.gov (United States)

    Masek, J. G.; Claverie, M.; Ju, J.; Vermote, E.; Justice, C. O.

    2015-12-01

    The combination of Landsat and Sentinel-2 data offers a unique opportunity to observe globally the land every 2-3 days at medium (reflectance data from Landsat and Sentinel-2 missions and to deliver them to the community in a combined, seamless form. The HLS will be beneficial for global agricultural monitoring applications that require medium spatial resolution and weekly or more frequent observations. In particular, the provided opportunity to track crop phenology at the scale of individual fields will support detailed mapping of crop type and type-specific vegetation conditions. To create a compatible set of radiometric measurements, the HLS product relies on rigorous pre- and post-launch cross-calibration (Landsat-8 OLI and Sentinel-2 MSI) activities. The processing chain includes the following components: atmospheric correction, cloud/shadow masking, nadir BRDF-adjustment, spectral-adjustment, regridding, and temporal composite. The atmospheric correction and cloud masking is based on the OLI atmospheric correction developed at NASA-GSFC and has been adapted to the MSI data. The BRDF-adjustment is based on a disaggregation technique using MODIS-based BRDF coefficients. The technique has been evaluated using the multi-angular acquisition from the SPOT 4 and 5 (Take5) experiments. The spectral-adjustment relies on a linear regression that has been calibrated and evaluated using synthetic data and surface reflectance processed from a large number of hyperspectral EO-1 Hyperion scenes. Finally, significant effort is placed on product validation and evaluation. The delivered data set will include surface reflectance products at different levels: Using the native gridding, i.e. UTM, 30m for Landsat-8, and UTM, 10-20m for Sentinel-2 Using a common global gridding (Sinusoidal, 30m) Temporal composite (Sinusoidal, 30m, 5-day) During the first year of operation of Sentinel-2A, the HLS will be prototyped over a selection of 30 sites that includes some of the JECAM sites

  13. Influence of aerosol and surface reflectance variability on hyperspectral observed radiance

    Directory of Open Access Journals (Sweden)

    C. Bassani

    2012-06-01

    Full Text Available Current aerosol retrievals based on visible and near infrared remote-sensing, are prone to loss of accuracy, where the assumptions of the applied algorithm are violated. This happens mostly over land and it is related to misrepresentation of specific aerosol conditions or surface properties. New satellite missions, based on high spectral resolution instruments, such as PRISMA (Hyperspectral Precursor of the Application Mission, represent a valuable opportunity to improve the accuracy of τa550 retrievable from a remote-sensing system developing new atmospheric measurement techniques. This paper aims to address the potential of these new observing systems in more accurate retrieving τa550, specifically over land in heterogeneous and/or homogeneous areas composed by dark and bright targets. The study shows how the variation of the hyperspectral observed radiance can be addressed to recognise a variation of Δτa550 = 0.02. The goal has been achieved by using simulated radiances by combining two aerosol models (urban and continental and two reflecting surfaces: dark (represented by water and bright (represented by sand for the PRISMA instrument, considering the environmental contribution of the observed radiance, i.e., the adjacency effect. Results showed that, in the continental regime, the expected instrument sensitivity would allow for retrieval accuracy of the aerosol optical thickness at 550 nm of 0.02 or better, with a dark surface surrounded by dark areas. The study also showed that for the urban regime, the surface plays a more significant role, with a bright surface surrounded by dark areas providing favourable conditions for the aerosol load retrievals, and dark surfaces representing less suitable situations for inversion independently of the surroundings. However, over all, the results obtained provide evidence that high resolution observations of Earth spectrum between

  14. Correlation of tunneling spectra with surface nano-morphology and doping in thin YBa2Cu3O7-delta films

    OpenAIRE

    Sharoni, A.; Koren, G.; Millo, O.

    2001-01-01

    Tunneling spectra measured on thin epitaxial YBa2Cu3O7-delta films are found to exhibit strong spatial variations, showing U and V-shaped gaps as well as zero bias conductance peaks typical of a d-wave superconductor. A full correspondence is found between the tunneling spectra and the surface morphology down to a level of a unit-cell step. Splitting of the zero bias conductance peak is seen in optimally-doped and overdoped films, but not in the underdoped ones, suggesting that there is no tr...

  15. Phase analysis for three-dimensional surface reconstruction of apples using structured-illumination reflectance imaging

    Science.gov (United States)

    Lu, Yuzhen; Lu, Renfu

    2017-05-01

    Three-dimensional (3-D) shape information is valuable for fruit quality evaluation. This study was aimed at developing phase analysis techniques for reconstruction of the 3-D surface of fruit from the pattern images acquired by a structuredillumination reflectance imaging (SIRI) system. Phase-shifted sinusoidal patterns, distorted by the fruit geometry, were acquired and processed through phase demodulation, phase unwrapping and other post-processing procedures to obtain phase difference maps relative to the phase of a reference plane. The phase maps were then transformed into height profiles and 3-D shapes in a world coordinate system based on phase-to-height and in-plane calibrations. A reference plane-based approach, coupled with the curve fitting technique using polynomials of order 3 or higher, was utilized for phase-to-height calibrations, which achieved superior accuracies with the root-mean-squared errors (RMSEs) of 0.027- 0.033 mm for a height measurement range of 0-91 mm. The 3rd-order polynomial curve fitting technique was further tested on two reference blocks with known heights, resulting in relative errors of 3.75% and 4.16%. In-plane calibrations were performed by solving a linear system formed by a number of control points in a calibration object, which yielded a RMSE of 0.311 mm. Tests of the calibrated system for reconstructing the surface of apple samples showed that surface concavities (i.e., stem/calyx regions) could be easily discriminated from bruises from the phase difference maps, reconstructed height profiles and the 3-D shape of apples. This study has laid a foundation for using SIRI for 3-D shape measurement, and thus expanded the capability of the technique for quality evaluation of horticultural products. Further research is needed to utilize the phase analysis techniques for stem/calyx detection of apples, and optimize the phase demodulation and unwrapping algorithms for faster and more reliable detection.

  16. Automated sulcal depth measurement on cortical surface reflecting geometrical properties of sulci.

    Directory of Open Access Journals (Sweden)

    Hyuk Jin Yun

    Full Text Available Sulcal depth that is one of the quantitative measures of cerebral cortex has been widely used as an important marker for brain morphological studies. Several studies have employed Euclidean (EUD or geodesic (GED algorithms to measure sulcal depth, which have limitations that ignore sulcal geometry in highly convoluted regions and result in under or overestimated depth. In this study, we proposed an automated measurement for sulcal depth on cortical surface reflecting geometrical properties of sulci, which named the adaptive distance transform (ADT. We first defined the volume region of cerebrospinal fluid between the 3D convex hull and the cortical surface, and constructed local coordinates for that restricted region. Dijkstra's algorithm was then used to compute the shortest paths from the convex hull to the vertices of the cortical surface based on the local coordinates, which may be the most proper approach for defining sulcal depth. We applied our algorithm to both a clinical dataset including patients with mild Alzheimer's disease (AD and 25 normal controls and a simulated dataset whose shape was similar to a single sulcus. The mean sulcal depth in the mild AD group was significantly lower than controls (p = 0.007, normal [mean±SD]: 7.29±0.23 mm, AD: 7.11±0.29 and the area under the receiver operating characteristic curve was relatively high, showing the value of 0.818. Results from clinical dataset that were consistent with former studies using EUD or GED demonstrated that ADT was sensitive to cortical atrophy. The robustness against inter-individual variability of ADT was highlighted through simulation dataset. ADT showed a low and constant normalized difference between the depth of the simulated data and the calculated depth, whereas EUD and GED had high and variable differences. We suggest that ADT is more robust than EUD or GED and might be a useful alternative algorithm for measuring sulcal depth.

  17. Impacts of dust aerosol and adjacency effects on the accuracy of Landsat 8 and RapidEye surface reflectances

    KAUST Repository

    Houborg, Rasmus

    2017-03-29

    The atmospheric correction of satellite data is challenging over desert agricultural systems, due to the relatively high aerosol optical thicknesses (τ550), bright soils, and a heterogeneous surface reflectance field. Indeed, the contribution of reflected radiation from adjacent pixels scattered into the field of view of a target pixel is considerable and can significantly affect the fidelity of retrieved reflectances. In this study, uncertainties and quantitative errors associated with the atmospheric correction of multi-spectral Landsat 8 and RapidEye data were characterized over a desert agricultural landscape in Saudi Arabia. Surface reflectances were retrieved using an implementation of the 6SV atmospheric correction code, and validated against field collected spectroradiometer measurements over desert, cultivated soil, and vegetated surface targets. A combination of satellite and Aerosol Robotic Network (AERONET) data were used to parameterize aerosol properties and atmospheric state parameters. With optimal specification of τ550 and aerosol optical properties and correction for adjacency effects, the relative Mean Absolute Deviation (MAD) for all bands combined was 5.4% for RapidEye and 6.8% for Landsat 8. However uncertainties associated with satellite-based τ550 retrievals were shown to introduce significant error into the reflectance estimates. With respect to deriving common vegetation indices from corrected reflectance data, the Normalized Difference Vegetation Index (NDVI) was associated with the smallest errors (3–8% MAD). Surface reflectance errors were highest for bands in the visible part of the spectrum, particularly the blue band (5–16%), while there was more consistency within the red-edge (~ 5%) and near-infrared (5–7%). Results were generally better constrained when a τ550-dependent aerosol model for desert dust particles, parameterized on the basis of nearby AERONET site data, was used in place of a generic rural or background

  18. Updating Landsat time series of surface-reflectance composites and forest change products with new observations

    Science.gov (United States)

    Hermosilla, Txomin; Wulder, Michael A.; White, Joanne C.; Coops, Nicholas C.; Hobart, Geordie W.

    2017-12-01

    The use of time series satellite data allows for the temporally dense, systematic, transparent, and synoptic capture of land dynamics over time. Subsequent to the opening of the Landsat archive, several time series approaches for characterizing landscape change have been developed, often representing a particular analytical time window. The information richness and widespread utility of these time series data have created a need to maintain the currency of time series information via the addition of new data, as it becomes available. When an existing time series is temporally extended, it is critical that previously generated change information remains consistent, thereby not altering reported change statistics or science outcomes based on that change information. In this research, we investigate the impacts and implications of adding additional years to an existing 29-year annual Landsat time series for forest change. To do so, we undertook a spatially explicit comparison of the 29 overlapping years of a time series representing 1984-2012, with a time series representing 1984-2016. Surface reflectance values, and presence, year, and type of change were compared. We found that the addition of years to extend the time series had minimal effect on the annual surface reflectance composites, with slight band-specific differences (r ≥ 0.1) in the final years of the original time series being updated. The area of stand replacing disturbances and determination of change year are virtually unchanged for the overlapping period between the two time-series products. Over the overlapping temporal period (1984-2012), the total area of change differs by 0.53%, equating to an annual difference in change area of 0.019%. Overall, the spatial and temporal agreement of the changes detected by both time series was 96%. Further, our findings suggest that the entire pre-existing historic time series does not need to be re-processed during the update process. Critically, given the time

  19. Objective and Subjective Evaluation of Reflecting and Diffusing Surfaces in Auditoria

    Science.gov (United States)

    Cox, Trevor John

    Available from UMI in association with The British Library. Requires signed TDF. The performance of reflectors and diffusers used in auditoria have been evaluated both objectively and subjectively. Two accurate systems have been developed to measure the scattering from surfaces via the cross correlation function. These have been used to measure the scattering from plane panels, curved panels and quadratic residue diffusers (QRDs). The scattering measurements have been used to test theoretical prediction methods based on the Helmholtz-Kirchhoff integral equation. Accurate prediction methods were found for all surfaces tested. The limitations of the more approximate methods have been defined. The assumptions behind Schroeder's design of the QRD have been tested and the local reacting admittance assumption found to be valid over a wide frequency range. It was found that the QRD only produces uniform scattering at low frequencies. For an on-axis source the scattering from a curved panel was as good as from a QRD. For an oblique source the QRD produced much more uniform scattering than the curved panel. The subjective measurements evaluated the smallest perceivable change in the early sound field, the part most influenced by reflectors and diffusers. A natural sounding simulation of a concert hall field within an anechoic chamber was used. Standard objective parameters were reasonable values when compared to values found in real halls and subjective preference measurements. A difference limen was measured for early lateral energy fraction (.048 +/-.005); inter aural cross correlation (.075 +/-.008); clarity index (.67 +/-.13 dB); and centre time (8.6 +/- 1.6 ms). It was found that: (i) when changes are made to diffusers and reflectors, changes in spatial impression will usually be larger than those in clarity; and (ii) acousticians can gain most by paying attention to lateral sound in auditoria. It was also found that: (i) diffuse reflections in the early sound field

  20. Chemometric evaluation of temperature-dependent surface-enhanced Raman spectra of riboflavin: What is the best multivariate approach to describe the effect of temperature?

    Science.gov (United States)

    Kokaislová, Alžběta; Kalhousová, Milena; Gráfová, Michaela; Matějka, Pavel

    2014-10-01

    Riboflavin is an essential nutrient involved in energetic metabolism. It is used as a pharmacologically active substance in treatment of several diseases. From analytical point of view, riboflavin can be used as an active part of sensors for substances with affinity to riboflavin molecules. In biological environment, metal substrates coated with riboflavin are exposed to temperatures that are different from room temperature. Hence, it is important to describe the influence of temperature on adsorbed molecules of riboflavin, especially on orientation of molecules towards the metal surface and on stability of adsorbed molecular layer. Surface-enhanced Raman scattering (SERS) spectroscopy is a useful tool for investigation of architecture of molecular layers adsorbed on metal surfaces because the spectral features in SERS spectra change with varying orientation of molecules towards the metal surface, as well as with changes in mutual interactions among adsorbed molecules. In this study, riboflavin was adsorbed on electrochemically prepared massive silver substrates that were exposed to temperature changes according to four different temperature programs. Raman spectra measured at different temperatures were compared considering positions of spectral bands, their intensities, bandwidths and variability of all these parameters. It was found out that increase of substrate temperature up to 50 °C does not lead to any observable decomposition of riboflavin molecules, but the changes of band intensity ratios within individual spectra are apparent. To distinguish sources of variability beside changes in band intensities and widths, Principal Component Analysis (PCA) was applied. Discriminant Analysis (DA) was used to explore if the SERS spectra can be separated according to temperature. The results of Partial Least Squares (PLS) regression demonstrate the possibility to predict the sample temperature using SERS spectral features. Results of all performed experiments and

  1. Specular and non-specular X-ray reflection from a single-crystal molybdenum mirror surface

    CERN Document Server

    Mizusawa, M

    2003-01-01

    The surface morphology of a super-polished mirror of single-crystal molybdenum has been studied by grazing-incidence X-ray reflection. It yields a rather high specular reflectivity (82.0%) for 16.0 keV X-rays below the critical angle. The data suggest that the mirror has a small roughness (0.7 nm rms) unlike other metal mirrors, but, on the other hand, strongly damaged layers (6.35 nm in total) exist at the near surface. It has been also found that the surface has a large correlation length (>3 mu m) and a small Hurst parameter (0.2-0.3) from the non-specular reflection.

  2. [Light reflection zone on the incisors' surface--a new parameter for smile esthetics evaluation].

    Science.gov (United States)

    Brezniak, N; Wasserstein, A; Shmuli, T

    2012-07-01

    The light reflection zone (LRZ) is a bright white dot or area that appears on the surface of the maxillary central incisors and/or the gingiva of the front teeth, visible in intra-oral and smile extra-oral photographs. Previously, a positive correlation between the location of the LRZ as observed in intra-oral frontal photographs and the inclination of the upper central incisors as measured on lateral headfims was found. The purpose of this study was to find whether this LRZ location can serve as a new parameter influencing the level of smile esthetics. Twelve pairs of facial photographs, including 10 of ordinary smiling persons and 2 of smiling models, were presented to 138 participants. The only difference between each pair was the location of the LRZ that was moved, compared to the original photograph, gingivally or incisally respectively, using Photoshop (Adobe). Each participant was asked to mark whether he/she noticed a difference between the 2 pictures, and if so, to score the nicer smile. Data analysis was carried out using Chi square test and Fisher's exact test (SPSS v17). The results showed that most of the participants did not recognize the differences between the pairs however, when differences were recognized, most of the participants pointed on the smile where the LRZ was located gingivally as the nicer one. This result was with statistical significance for the 2 models (p < 0.05), In conclusion, the LRZ is a new, yet unrecognized, parameter that can serve as a tool for the diagnosis of esthetic smile. The general population defines a nicer smile when the LRZ is located in the gingival area of the upper central incisors' surface rather than the incisal third. The LRZ should probably be studied not only in Orthodontics but also in other branches of dentistry.

  3. Classification of sugar beet and volunteer potato reflection spectra with a neural network and statistical discriminant analysis to select discriminative wavelengths

    NARCIS (Netherlands)

    Nieuwenhuizen, A.T.; Hofstee, J.W.; Zande, van de J.C.; Meuleman, J.; Henten, van E.J.

    2010-01-01

    The objectives of this study were to determine the reflectance properties of volunteer potato and sugar beet and to assess the potential of separating sugar beet and volunteer potato at different fields and in different years, using spectral reflectance characteristics. With the ImspectorMobile,

  4. How Can Polarization States of Reflected Light from Snow Surfaces Inform Us on Surface Normals and Ultimately Snow Grain Size Measurements?

    Science.gov (United States)

    Schneider, A. M.; Flanner, M.; Yang, P.; Yi, B.; Huang, X.; Feldman, D.

    2016-12-01

    The Snow Grain Size and Pollution (SGSP) algorithm is a method applied to Moderate Resolution Imaging Spectroradiometer data to estimate snow grain size from space-borne measurements. Previous studies validate and quantify potential sources of error in this method, but because it assumes flat snow surfaces, however, large scale variations in surface normals can cause biases in its estimates due to its dependence on solar and observation zenith angles. To address these variations, we apply the Monte Carlo method for photon transport using data containing the single scattering properties of different ice crystals to calculate polarization states of reflected monochromatic light at 1500nm from modeled snow surfaces. We evaluate the dependence of these polarization states on solar and observation geometry at 1500nm because multiple scattering is generally a mechanism for depolarization and the ice crystals are relatively absorptive at this wavelength. Using 1500nm thus results in a higher number of reflected photons undergoing fewer scattering events, increasing the likelihood of reflected light having higher degrees of polarization. In evaluating the validity of the model, we find agreement with previous studies pertaining to near-infrared spectral directional hemispherical reflectance (i.e. black-sky albedo) and similarities in measured bidirectional reflectance factors, but few studies exist modeling polarization states of reflected light from snow surfaces. Here, we present novel results pertaining to calculated polarization states and compare dependences on solar and observation geometry for different idealized snow surfaces. If these dependencies are consistent across different ice particle shapes and sizes, then these findings could inform the SGSP algorithm by providing useful relationships between measurable physical quantities and solar and observation geometry to better understand variations in snow surface normals from remote sensing observations.

  5. Comparability of red/near-infrared reflectance and NDVI based on the spectral response function between MODIS and 30 other satellite sensors using rice canopy spectra.

    Science.gov (United States)

    Huang, Weijiao; Huang, Jingfeng; Wang, Xiuzhen; Wang, Fumin; Shi, Jingjing

    2013-11-26

    Long-term monitoring of regional and global environment changes often depends on the combined use of multi-source sensor data. The most widely used vegetation index is the normalized difference vegetation index (NDVI), which is a function of the red and near-infrared (NIR) spectral bands. The reflectance and NDVI data sets derived from different satellite sensor systems will not be directly comparable due to different spectral response functions (SRF), which has been recognized as one of the most important sources of uncertainty in the multi-sensor data analysis. This study quantified the influence of SRFs on the red and NIR reflectances and NDVI derived from 31 Earth observation satellite sensors. For this purpose, spectroradiometric measurements were performed for paddy rice grown under varied nitrogen levels and at different growth stages. The rice canopy reflectances were convoluted with the spectral response functions of various satellite instruments to simulate sensor-specific reflectances in the red and NIR channels. NDVI values were then calculated using the simulated red and NIR reflectances. The results showed that as compared to the Terra MODIS, the mean relative percentage difference (RPD) ranged from -12.67% to 36.30% for the red reflectance, -8.52% to -0.23% for the NIR reflectance, and -9.32% to 3.10% for the NDVI. The mean absolute percentage difference (APD) compared to the Terra MODIS ranged from 1.28% to 36.30% for the red reflectance, 0.84% to 8.71% for the NIR reflectance, and 0.59% to 9.32% for the NDVI. The lowest APD between MODIS and the other 30 satellite sensors was observed for Landsat5 TM for the red reflectance, CBERS02B CCD for the NIR reflectance and Landsat4 TM for the NDVI. In addition, the largest APD between MODIS and the other 30 satellite sensors was observed for IKONOS for the red reflectance, AVHRR1 onboard NOAA8 for the NIR reflectance and IKONOS for the NDVI. The results also indicated that AVHRRs onboard NOAA7-17 showed

  6. Exploration of a Polarized Surface Bidirectional Reflectance Model Using the Ground-Based Multiangle SpectroPolarimetric Imager

    Directory of Open Access Journals (Sweden)

    David J. Diner

    2012-12-01

    Full Text Available Accurate characterization of surface reflection is essential for retrieval of aerosols using downward-looking remote sensors. In this paper, observations from the Ground-based Multiangle SpectroPolarimetric Imager (GroundMSPI are used to evaluate a surface polarized bidirectional reflectance distribution function (PBRDF model. GroundMSPI is an eight-band spectropolarimetric camera mounted on a rotating gimbal to acquire pushbroom imagery of outdoor landscapes. The camera uses a very accurate photoelastic-modulator-based polarimetric imaging technique to acquire Stokes vector measurements in three of the instrument’s bands (470, 660, and 865 nm. A description of the instrument is presented, and observations of selected targets within a scene acquired on 6 January 2010 are analyzed. Data collected during the course of the day as the Sun moved across the sky provided a range of illumination geometries that facilitated evaluation of the surface model, which is comprised of a volumetric reflection term represented by the modified Rahman-Pinty-Verstraete function plus a specular reflection term generated by a randomly oriented array of Fresnel-reflecting microfacets. While the model is fairly successful in predicting the polarized reflection from two grass targets in the scene, it does a poorer job for two manmade targets (a parking lot and a truck roof, possibly due to their greater degree of geometric organization. Several empirical adjustments to the model are explored and lead to improved fits to the data. For all targets, the data support the notion of spectral invariance in the angular shape of the unpolarized and polarized surface reflection. As noted by others, this behavior provides valuable constraints on the aerosol retrieval problem, and highlights the importance of multiangle observations.

  7. Ultraviolet (UV)-reflective paint with ultraviolet germicidal irradiation (UVGI) improves decontamination of nosocomial bacteria on hospital room surfaces.

    Science.gov (United States)

    Jelden, Katelyn C; Gibbs, Shawn G; Smith, Philip W; Hewlett, Angela L; Iwen, Peter C; Schmid, Kendra K; Lowe, John J

    2017-06-01

    An ultraviolet germicidal irradiation (UVGI) generator (the TORCH, ClorDiSys Solutions, Inc.) was used to compare the disinfection of surface coupons (plastic from a bedrail, stainless steel, and chrome-plated light switch cover) in a hospital room with walls coated with ultraviolet (UV)-reflective paint (Lumacept) or standard paint. Each surface coupon was inoculated with methicillin-resistant Staphylococcus aureus (MRSA) or vancomycin-resistant Enterococcus faecalis (VRE), placed at 6 different sites within a hospital room coated with UV-reflective paint or standard paint, and treated by 10 min UVC exposure (UVC dose of 0-688 mJ/cm 2 between sites with standard paint and 0-553 mJ/cm 2 with UV-reflective paint) in 8 total trials. Aggregated MRSA concentrations on plastic bedrail surface coupons were reduced on average by 3.0 log 10 (1.8 log 10 Geometric Standard Deviation [GSD]) with standard paint and 4.3 log 10 (1.3 log 10 GSD) with UV-reflective paint (p = 0.0005) with no significant reduction differences between paints on stainless steel and chrome. Average VRE concentrations were reduced by ≥4.9 log 10 (light, MRSA concentrations on average were reduced by 5.2 log 10 (1.4 log 10 GSD) with standard paint and 5.1 log 10 (1.2 log 10 GSD) with UV-reflective paint (p = 0.017) and VRE by 4.4 log 10 (1.4 log 10 GSD) with standard paint and 5.3 log 10 (1.1 log 10 GSD) with UV-reflective paint (p bacteria on various surfaces compared to standard paint, particularly at a surface placement site indirectly exposed to UVC light.

  8. FIRST ULTRAVIOLET REFLECTANCE SPECTRA OF PLUTO AND CHARON BY THE HUBBLE SPACE TELESCOPE COSMIC ORIGINS SPECTROGRAPH: DETECTION OF ABSORPTION FEATURES AND EVIDENCE FOR TEMPORAL CHANGE

    Energy Technology Data Exchange (ETDEWEB)

    Stern, S. A.; Spencer, J. R.; Shinn, A. [Southwest Research Institute, 1050 Walnut Street, Boulder, CO 80302 (United States); Cunningham, N. J.; Hain, M. J., E-mail: astern@swri.edu [Nebraska Wesleyan University, 5000 Saint Paul Avenue, Lincoln, NE 68504 (United States)

    2012-01-15

    We have observed the mid-UV spectra of both Pluto and its large satellite, Charon, at two rotational epochs using the Hubble Space Telescope (HST) Cosmic Origins Spectrograph (COS) in 2010. These are the first HST/COS measurements of Pluto and Charon. Here we describe the observations and our reduction of them, and present the albedo spectra, average mid-UV albedos, and albedo slopes we derive from these data. These data reveal evidence for a strong absorption feature in the mid-UV spectrum of Pluto; evidence for temporal change in Pluto's spectrum since the 1990s is reported, and indirect evidence for a near-UV spectral absorption on Charon is also reported.

  9. Improving interpretation of infrared spectra for OM characterization by subtraction of spectra from incinerated samples

    Science.gov (United States)

    Ellerbrock, Ruth H.; Gerke, Horst H.; Leue, Martin

    2017-04-01

    Non-destructive methods such as diffuse reflectance infrared Fourier transform spectroscopy (DRIFT) have been applied to characterize organic matter (OM) at intact structural surfaces among others. However, it is often difficult to distinguish effects of organic components on DRIFT signal intensities from those of mineral components. The objective of this study was to re-evaluate DRIFT spectra from intact earthworm burrow walls and coated cracks to improve the interpretation of C-H and C=O bands. We compared DRIFT and transmission Fourier transform infrared (FTIR) spectra of entire samples that were from the same pedogenetic soil horizon, but different in mineral composition and texture (i.e., glacial till versus loess). Spectra of incinerated samples were subtracted from the original spectra. Transmission FTIR and DRIFT spectra were almost identical for entire soil samples. However, the DRIFT spectra were affected by the bulk mode bands (i.e., wavenumbers 2000 to 1700 cm-1) that affected spectral resolution and reproducibility. The ratios between C-H and C=O band intensities as indicator for OM quality obtained with DRIFT were smaller than those obtained from transmission FTIR. A spectral subtraction procedure was found to reduce effects of mineral absorption bands on DRIFT spectra allowing an improved interpretation. DRIFT spectroscopy as a non-destructive method for analyzing OM composition at intact surfaces in structured soils could be calibrated with information obtained with the more detailed transmission FTIR and complementary methods.

  10. Land Surface Reflectance Retrieval from Hyperspectral Data Collected by an Unmanned Aerial Vehicle over the Baotou Test Site

    Science.gov (United States)

    Duan, Si-Bo; Li, Zhao-Liang; Tang, Bo-Hui; Wu, Hua; Ma, Lingling; Zhao, Enyu; Li, Chuanrong

    2013-01-01

    To evaluate the in-flight performance of a new hyperspectral sensor onboard an unmanned aerial vehicle (UAV-HYPER), a comprehensive field campaign was conducted over the Baotou test site in China on 3 September 2011. Several portable reference reflectance targets were deployed across the test site. The radiometric performance of the UAV-HYPER sensor was assessed in terms of signal-to-noise ratio (SNR) and the calibration accuracy. The SNR of the different bands of the UAV-HYPER sensor was estimated to be between approximately 5 and 120 over the homogeneous targets, and the linear response of the apparent reflectance ranged from approximately 0.05 to 0.45. The uniform and non-uniform Lambertian land surface reflectance was retrieved and validated using in situ measurements, with root mean square error (RMSE) of approximately 0.01–0.07 and relative RMSE of approximately 5%–12%. There were small discrepancies between the retrieved uniform and non-uniform Lambertian land surface reflectance over the homogeneous targets and under low aerosol optical depth (AOD) conditions (AOD = 0.18). However, these discrepancies must be taken into account when adjacent pixels had large land surface reflectance contrast and under high AOD conditions (e.g. AOD = 1.0). PMID:23785513

  11. Land surface reflectance retrieval from hyperspectral data collected by an unmanned aerial vehicle over the Baotou test site.

    Science.gov (United States)

    Duan, Si-Bo; Li, Zhao-Liang; Tang, Bo-Hui; Wu, Hua; Ma, Lingling; Zhao, Enyu; Li, Chuanrong

    2013-01-01

    To evaluate the in-flight performance of a new hyperspectral sensor onboard an unmanned aerial vehicle (UAV-HYPER), a comprehensive field campaign was conducted over the Baotou test site in China on 3 September 2011. Several portable reference reflectance targets were deployed across the test site. The radiometric performance of the UAV-HYPER sensor was assessed in terms of signal-to-noise ratio (SNR) and the calibration accuracy. The SNR of the different bands of the UAV-HYPER sensor was estimated to be between approximately 5 and 120 over the homogeneous targets, and the linear response of the apparent reflectance ranged from approximately 0.05 to 0.45. The uniform and non-uniform Lambertian land surface reflectance was retrieved and validated using in situ measurements, with root mean square error (RMSE) of approximately 0.01-0.07 and relative RMSE of approximately 5%-12%. There were small discrepancies between the retrieved uniform and non-uniform Lambertian land surface reflectance over the homogeneous targets and under low aerosol optical depth (AOD) conditions (AOD = 0.18). However, these discrepancies must be taken into account when adjacent pixels had large land surface reflectance contrast and under high AOD conditions (e.g. AOD = 1.0).

  12. Synchrotron Radiation Total Reflection X-ray Fluorescence Spectroscopy for Microcontamination Analysis on Silicon Wafer Surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Takaura, Norikatsu

    1997-10-01

    As dimensions in state-of-the-art CMOS devices shrink to less than 0.1 pm, even low levels of impurities on wafer surfaces can cause device degradation. Conventionally, metal contamination on wafer surfaces is measured using Total Reflection X-Ray Fluorescence Spectroscopy (TXRF). However, commercially available TXRF systems do not have the necessary sensitivity for measuring the lower levels of contamination required to develop new CMOS technologies. In an attempt to improve the sensitivity of TXRF, this research investigates Synchrotron Radiation TXRF (SR TXRF). The advantages of SR TXRF over conventional TXRF are higher incident photon flux, energy tunability, and linear polarization. We made use of these advantages to develop an optimized SR TXRF system at the Stanford Synchrotron Radiation Laboratory (SSRL). The results of measurements show that the Minimum Detection Limits (MDLs) of SR TXRF for 3-d transition metals are typically at a level-of 3x10{sup 8} atoms/cm{sup 2}, which is better than conventional TXRF by about a factor of 20. However, to use our SR TXRF system for practical applications, it was necessary to modify a commercially available Si (Li) detector which generates parasitic fluorescence signals. With the modified detector, we could achieve true MDLs of 3x10{sup 8} atoms/cm{sup 2} for 3-d transition metals. In addition, the analysis of Al on Si wafers is described. Al analysis is difficult because strong Si signals overlap the Al signals. In this work, the Si signals are greatly reduced by tuning the incident beam energy below the Si K edge. The results of our measurements show that the sensitivity for Al is limited by x-ray Raman scattering. Furthermore, we show the results of theoretical modeling of SR TXRF backgrounds consisting of the bremsstrahlung generated by photoelectrons, Compton scattering, and Raman scattering. To model these backgrounds, we extended conventional theoretical models by taking into account several aspects particular

  13. MODIS/Aqua L2 Surface Reflectance, 5-Min Swath 250m, 500m, and 1km

    Data.gov (United States)

    National Aeronautics and Space Administration — MODIS/Aqua L2 Surface Reflectance, 5-Min Swath 250m, 500m, and 1km (MYD09). This product is computed from the MODIS Level 1B land bands 1, 2, 3, 4, 5, 6, and 7...

  14. MODIS/Aqua Near Real Time (NRT) Surface Reflectance Daily L2G Global 500m SIN Grid

    Data.gov (United States)

    National Aeronautics and Space Administration — The MODIS Near Real Time (NRT) Surface Reflectance Daily L2G Global 500m SIN Grid product, MYD09GHK, is a seven-band product computed from the MODIS Level 1B land...

  15. Fluorine-containing composition for forming anti-reflection film on resist surface and pattern formation method

    Science.gov (United States)

    Nishi, Mineo; Makishima, Hideo

    1996-01-01

    A composition for forming anti-reflection film on resist surface which comprises an aqueous solution of a water soluble fluorine compound, and a pattern formation method which comprises the steps of coating a photoresist composition on a substrate; coating the above-mentioned composition for forming anti-reflection film; exposing the coated film to form a specific pattern; and developing the photoresist, are provided. Since the composition for forming anti-reflection film can be coated on the photoresist in the form of an aqueous solution, not only the anti-reflection film can be formed easily, but also, the film can be removed easily by rinsing with water or alkali development. Therefore, by the pattern formation method according to the present invention, it is possible to form a pattern easily with a high dimensional accuracy.

  16. 3D spectrum imaging of multi-wall carbon nanotube coupled π-surface modes utilising electron energy-loss spectra acquired using a STEM/Enfina system

    International Nuclear Information System (INIS)

    Seepujak, A.; Bangert, U.; Gutierrez-Sosa, A.; Harvey, A.J.; Blank, V.D.; Kulnitskiy, B.A.; Batov, D.V.

    2005-01-01

    Numerous studies have utilised electron energy-loss (EEL) spectra acquired in the plasmon (2-10 eV) regime in order to probe delocalised π-electronic states of multi-wall carbon nanotubes (MWCNTs). Interpretation of electron energy loss (EEL) spectra of MWCNTs in the 2-10 eV regime. Carbon (accepted for publication); Blank et al. J. Appl. Phys. 91 (2002) 1657). In the present contribution, EEL spectra were acquired from a 2D raster defined on a bottle-shaped MWCNT, using a Gatan UHV Enfina system attached to a dedicated scanning transmission electron microscope (STEM). The technique utilised to isolate and sequentially filter each of the volume and surface resonances is described in detail. Utilising a scale for the intensity of a filtered mode enables one to 'see' the distribution of each resonance in the raster. This enables striking 3D resonance-filtered spectrum images (SIs) of π-collective modes to be observed. Red-shift of the lower energy split π-surface resonance provides explicit evidence of π-surface mode coupling predicted for thin graphitic films (Lucas et al. Phys. Rev. B 49 (1994) 2888). Resonance-filtered SIs are also compared to non-filtered SIs with suppressed surface contributions, acquired utilising a displaced collector aperture. The present filtering technique is seen to isolate surface contributions more effectively, and without the significant loss of statistics, associated with the displaced collector aperture mode. Isolation of collective modes utilising 3D resonance-filtered spectrum imaging, demonstrates a valuable method for 'pinpointing' the location of discrete modes in irregularly shaped nanostructures

  17. A Framework for Estimating the 30 m Thermal-Infrared Broadband Emissivity From Landsat Surface Reflectance Data

    Science.gov (United States)

    Cheng, Jie; Liu, Hao; Liang, Shunlin; Nie, Aixiu; Liu, Qiang; Guo, Yamin

    2017-11-01

    The land surface thermal-infrared broadband emissivity (BBE) is a vital variable for estimating land surface radiation budgets (SRBs). We develop a framework for retrieving the 30 m BBE from Landsat surface reflectance data to estimate SRBs at finer scales and validate coarse resolution data. In the developed framework, the land surface is classified as bare soils and vegetated surfaces to allow different algorithms to be used for the BBE estimation. We propose a downscaling algorithm that uses the empirical relationship between the Advanced Spaceborne Thermal Emission and Reflectance Radiometer (ASTER) BBE and Landsat surface reflectance at 90 m to retrieve the 30 m BBE over bare soils. A look-up table (LUT)-based algorithm is proposed for vegetated surfaces. The BBE is interpolated from a LUT that is constructed from the 4SAIL radiative transfer model with inputs of the leaf BBE, the soil background BBE, and the leaf area index (LAI). Ground measurements that were collected at 11 relatively homogeneous sandy sites during three independent field campaigns are used to validate the proposed algorithm over bare soils. The average difference between the retrieved and field-measured BBEs is 0.012. We produce the land surface BBE of China in 2008 by using the developed framework and composited winter and summer seasonal BBE maps. The composited seasonal BBE maps are compared to the seasonal BBE maps derived from the ASTER emissivity product. The bias is within ±0.005 over bare soils and ranges from 0.012 to 0.019 over vegetated surfaces. Combined with the validated results in this study and published references, the comparison results demonstrate the good performance of the developed framework. This study provides a new perspective on estimating BBEs from sensors with only a thermal-infrared channel.

  18. Broadband infrared reflective surfaces using doped and stacked polar dielectric layers

    Science.gov (United States)

    Janipour, Mohsen; Sendur, Kursat

    2018-02-01

    Polar dielectrics, such as SiC, are excellent candidates for operation in extreme environments due to their excellent mechanical and thermal properties. In addition, they can achieve good IR reflection in the Reststrahlen band. However, these materials have relatively narrow spectral bandwidth for reflection, especially considering that the broadband illumination sources in extreme environments. In this study, we investigated the broadband reflection properties of polar dielectrics by engineering the Reststrahlen band through doping and stacked layers. Our results indicate that by doping polar dielectrics, spectral reflection bandwidth can be significantly broadened. In addition, we demonstrate that by stacking different polar dielectric layers, the reflection spectrum of different materials can be overlapped, and thereby, significantly broader spectrum is obtained.

  19. Study on the effect of ambient gas on nanostructure formation on metal surfaces during femtosecond laser ablation for fabrication of low-reflective surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Smausz, Tomi, E-mail: tomi@physx.u-szeged.hu [MTA-SZTE Research Group on Photoacoustic Spectroscopy, University of Szeged, 6720 Szeged, Dóm tér 9 (Hungary); Department of Optics and Quantum Electronics, University of Szeged, H-6720 Szeged, Dóm tér 9 (Hungary); Csizmadia, Tamás [Department of Optics and Quantum Electronics, University of Szeged, H-6720 Szeged, Dóm tér 9 (Hungary); Attosecond Light Pulse Source, ELI-Hu Nkft, H-6720 Szeged, Dugonics ter 13 (Hungary); Tápai, Csaba; Kopniczky, Judit [Department of Optics and Quantum Electronics, University of Szeged, H-6720 Szeged, Dóm tér 9 (Hungary); Oszkó, Albert [Department of Physical Chemistry and Material Science, University of Szeged, H-6720 Szeged, Aradi vértanuk tere 1 (Hungary); Ehrhardt, Martin; Lorenz, Pierre; Zimmer, Klaus; Prager, Andrea [Leibniz-Institut für Oberflächenmodifizierung e.V., Permoserstr. 15, 04318 Leipzig (Germany); Hopp, Béla [Department of Optics and Quantum Electronics, University of Szeged, H-6720 Szeged, Dóm tér 9 (Hungary)

    2016-12-15

    Highlights: • Metal surfaces were irradiated with femtosecond laser in different gas environments. • The reflectivity, morphology and chemical composition of the surfaces were studied. • Darkening was influenced by chemical and physical interaction of the plume and gas. • Molecular mass of the applied gas had an impact on the nanostructure formation. • For some of the used metals the oxide formation affected the reflective properties. - Abstract: Nanostructure formation on bulk metals (silver, gold, copper and titanium) by femtosecond Ti-sapphire laser irradiation (775 nm, 150 fs) is studied aiming the production of low-reflectivity surfaces and the better understanding of the development process. The experiments were performed in nitrogen, air, oxygen and helium environments at atmospheric pressure. The samples were irradiated with fluences in the 0.1–2 J/cm{sup 2} range and an average pulse number of 100 falling over a given area. The reflectivity of the treated surfaces was determined by a microspectrometer in the 450–800 nm range and their morphology was studied by scanning electron microscopy. The gas ambience influenced the results via two effects: formation processes and the chemically-induced modifications of the nanostructures. In case of He the nanoparticle aggregates–otherwise generally present–are predominantly missing, which leads to a lower darkening efficiency. The presence of oxygen enhances the darkening effect for copper mostly at lower fluences, while causes a slow increase in reflectivity in the case of titanium (in case of pure oxygen) in the high fluence range. The surface morphology in case of nitrogen and air were quite similar probably due to their close molecular mass values.

  20. Principal component analysis for surface reflection components and structure in facial images and synthesis of facial images for various ages

    Science.gov (United States)

    Hirose, Misa; Toyota, Saori; Ojima, Nobutoshi; Ogawa-Ochiai, Keiko; Tsumura, Norimichi

    2017-08-01

    In this paper, principal component analysis is applied to the distribution of pigmentation, surface reflectance, and landmarks in whole facial images to obtain feature values. The relationship between the obtained feature vectors and the age of the face is then estimated by multiple regression analysis so that facial images can be modulated for woman aged 10-70. In a previous study, we analyzed only the distribution of pigmentation, and the reproduced images appeared to be younger than the apparent age of the initial images. We believe that this happened because we did not modulate the facial structures and detailed surfaces, such as wrinkles. By considering landmarks and surface reflectance over the entire face, we were able to analyze the variation in the distributions of facial structures and fine asperity, and pigmentation. As a result, our method is able to appropriately modulate the appearance of a face so that it appears to be the correct age.

  1. Correlation of tunneling spectra with surface nanomorphology and doping in thin YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} films

    Energy Technology Data Exchange (ETDEWEB)

    Sharoni, A.; Millo, O. [Hebrew Univ., Jerusalem (Israel). Racah Inst. of Physics; Koren, G. [Technion-Israel Inst. of Tech., Haifa (Israel). Dept. of Physics

    2001-06-01

    Tunneling spectra measured on thin epitaxial YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} films are found to exhibit strong spatial variations, showing U- and V-shaped gaps as well as zero-bias conductance peaks typical of a d-wave superconductor. A full correspondence is found between the tunneling spectra and the surface morphology down to a level of a unit-cell step. Splitting of the zero-bias conductance peak is seen in optimally-doped and overdoped films, but not in the underdoped ones, suggesting that there is no transition to a state of broken time-reversal symmetry in the underdoped regime. (orig.)

  2. Surface-atmosphere interactions with coupled within-canopy aerodynamic resistance and canopy reflection.

    Science.gov (United States)

    Timmermans, J.; van der Tol, C.; Verhoef, W.; Su, Z.

    2009-04-01

    Models that describe the exchange of CO2 and H2O between the surface and atmosphere use bulk-parametrization of the within-canopy aerodynamic resistance and leaf area density (eq. LAI). This bulk parametrization is based on the Monin-Obukhov Similarity (MOS) theory. The MOS theory however breaks down for sparse canopies and it cannot couple profiles in the leaf density to profiles in the within-canopy aerodynamic resistance. The objective of this research is to create a simple model that is able to couple the within-canopy aerodynamic resistance and canopy reflection for different levels in the canopy. This model should be able to represent the canopy using as fewer parameters as possible, in order to facilitate inversion of remote sensing imagery. A virtual canopy was simulated using an L-systems approach, Lindenmayer 1968. The L-system approach was chosen because it describes the canopy with fractals. It therefore needs very little inputs to simulate a virtual canopy. A vertical profile of leaf density was calculated for 60 levels from this virtual canopy. The within-canopy aerodynamic resistance was modeled from the vertical leaf density profile using foliage drag coefficient, Massman 1997. A modified version of the SCOPE (Soil Canopy Observations and Photosynthesis) model was used to calculate the H2O and CO2 fluxes using the vertical profiles of leaf density and within-canopy aerodynamic resistance. The simulated fluxes are compared with field measurements over a vineyard and a forested area. The field measurements in both areas are acquired using the same setup: a basic flux tower in addition with an eddy-covariance setup. We present in this article the methodology and the results, as a proof of concept. references Massman, W.J., An Analytical One-Dimensional Model of Momentum Transfer by vegetation of arbitrary structure, Boundary-Layer Meteorology, 1997, 83, 407-421 Lindenmayer, A., Mathematical Models for Cellular Interactions in Development, Journal of

  3. Kaguya observations of the lunar wake in the terrestrial foreshock: Surface potential change by bow-shock reflected ions

    Science.gov (United States)

    Nishino, Masaki N.; Harada, Yuki; Saito, Yoshifumi; Tsunakawa, Hideo; Takahashi, Futoshi; Yokota, Shoichiro; Matsushima, Masaki; Shibuya, Hidetoshi; Shimizu, Hisayoshi

    2017-09-01

    There forms a tenuous region called the wake behind the Moon in the solar wind, and plasma entry/refilling into the wake is a fundamental problem of the lunar plasma science. High-energy ions and electrons in the foreshock of the Earth's magnetosphere were detected at the lunar surface in the Apollo era, but their effects on the lunar night-side environment have never been studied. Here we show the first observation of bow-shock reflected protons by Kaguya (SELENE) spacecraft in orbit around the Moon, confirming that solar wind plasma reflected at the terrestrial bow shock can easily access the deepest lunar wake when the Moon stays in the foreshock (We name this mechanism 'type-3 entry'). In a continuous type-3 event, low-energy electron beams from the lunar night-side surface are not obvious even though the spacecraft location is magnetically connected to the lunar surface. On the other hand, in an intermittent type-3 entry event, the kinetic energy of upward-going field-aligned electron beams decreases from ∼ 80 eV to ∼ 20 eV or electron beams disappear as the bow-shock reflected ions come accompanied by enhanced downward electrons. According to theoretical treatment based on electric current balance at the lunar surface including secondary electron emission by incident electron and ion impact, we deduce that incident ions would be accompanied by a few to several times higher flux of an incident electron flux, which well fits observed downward fluxes. We conclude that impact by the bow-shock reflected ions and electrons raises the electrostatic potential of the lunar night-side surface.

  4. Reflection Spectra of the Black Hole Binary Candidate MAXI J1535-571 in the Hard State Observed by NuSTAR

    Science.gov (United States)

    Xu, Yanjun; Harrison, Fiona A.; García, Javier A.; Fabian, Andrew C.; Fürst, Felix; Gandhi, Poshak; Grefenstette, Brian W.; Madsen, Kristin K.; Miller, Jon M.; Parker, Michael L.; Tomsick, John A.; Walton, Dominic J.

    2018-01-01

    We report on a Nuclear Spectroscopic Telescope Array (NuSTAR) observation of the recently discovered bright black hole candidate MAXI J1535-571. NuSTAR observed the source on MJD 58003 (five days after the outburst was reported). The spectrum is characteristic of a black hole binary in the hard state. We observe clear disk reflection features, including a broad Fe Kα line and a Compton hump peaking around 30 keV. Detailed spectral modeling reveals a narrow Fe Kα line complex centered around 6.5 keV on top of the strong relativistically broadened Fe Kα line. The narrow component is consistent with distant reflection from moderately ionized material. The spectral continuum is well described by a combination of cool thermal disk photons and a Comptonized plasma with the electron temperature {{kT}}{{e}}=19.7+/- 0.4 keV. An adequate fit can be achieved for the disk reflection features with a self-consistent relativistic reflection model that assumes a lamp-post geometry for the coronal illuminating source. The spectral fitting measures a black hole spin a> 0.84, inner disk radius {R}{in}r}{ISCO}, and a lamp-post height h={7.2}-2.0+0.8 {r}{{g}} (statistical errors, 90% confidence), indicating no significant disk truncation and a compact corona. Although the distance and mass of this source are not currently known, this suggests the source was likely in the brighter phases of the hard state during this NuSTAR observation.

  5. Stretched membrane heliostats: design and structural analysis of reflectance module and support of a heliostats of 9 m. diaform and 60 m''3 of reflectance surface

    International Nuclear Information System (INIS)

    Figarola Torres, J. M.

    1993-01-01

    After having designed and built at CIEMAT a first prototype of a Btretched membrane heliostats of 3 m. diameter, the design and the structural analysis of the different components included in the reflectance module and support of another heliostats, this one of 9 m. diameter and 60 m2. of reflectance surface, are shown In this report. This last heliostats will be mounted on a pedestal and its driving device at the Solar Platform of Almeria. In order to optimize design and performance, the structural analysis of its basic components has been analyzed with the finite elements program ANSYS. The following elements have been subject to analysis: the membrane and their ring supports, stretching system and the structural support. A similar scheme to the one applied to the previous prototype has been used on the focus control system. That includes a linear transducer, a variable frequency and a fan. Finally it has to be pointed out that substantial improvements have been achieved with respect to the first prototype concerning design and cost. (Author) 5 refs

  6. Tailoring surface plasmon resonance and dipole cavity plasmon modes of scattering cross section spectra on the single solid-gold/gold-shell nanorod

    International Nuclear Information System (INIS)

    Chou Chau, Yuan-Fong; Lim, Chee Ming; Kumara, N. T. R. N.; Yoong, Voo Nyuk; Lee, Chuanyo; Huang, Hung Ji; Lin, Chun-Ting; Chiang, Hai-Pang

    2016-01-01

    Tunable surface plasmon resonance (SPR) and dipole cavity plasmon modes of the scattering cross section (SCS) spectra on the single solid-gold/gold-shell nanorod have been numerically investigated by using the finite element method. Various effects, such as the influence of SCS spectra under x- and y-polarizations on the surface of the single solid-gold/gold-shell nanorod, are discussed in detail. With the single gold-shell nanorod, one can independently tune the relative SCS spectrum width by controlling the rod length and rod diameter, and the surface scattering by varying the shell thickness and polarization direction, as well as the dipole peak energy. These behaviors are consistent with the properties of localized SPRs and offer a way to optically control and produce selected emission wavelengths from the single solid-gold/gold-shell nanorod. The electric field and magnetic distributions provide us a qualitative idea of the geometrical properties of the single solid-gold/gold-shell nanorod on plasmon resonance.

  7. Investigation of surface and sub-surface damage in high quality synthetic diamonds by X-ray reflectivity and grazing incidence in-plane diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Bussone, Genziana; Lafford, Tamzin A.; Masiello, Fabio; Carbone, Gerardina; Schuelli, Tobias U.; Rommeveaux, Amparo Vivo; Haertwig, Juergen [European Synchrotron Radiation Facility, 6, Rue Jules Horowitz, BP 220, 38043 Grenoble Cedex 9 (France); Gibaud, Alain [Laboratoire PEC, Universite du Maine le Mans, Avenue Olivier Messiaen, 72 085 Le Mans (France); Connell, Simon H. [University of Johannesburg, cnr Kingsway Ave and University Rd, Auckland Park, 2006, Johannesburg (South Africa); Wormington, Matthew [Jordan Valley Semiconductors Inc., 8601 Cross Park Drive, Suite 200, Austin, TX 78754-4578 (United States)

    2011-11-15

    High quality single-crystal synthetic diamond is the most suitable material for selected X-ray optical applications in the latest generation X-ray light sources. Excellent heat handling properties, as well as low absorption, coupled with high perfection in the crystal bulk and very good surface quality, are crucial for such applications. In recent years, some progress has been made in the fields of surface treatments and growth techniques. Conventional scaife polishing is largely ineffective on the diamond (111) surface. To overcome this disadvantage, one possibility is to use the Hot Metal polishing technique. An investigation of surface and sub-surface damage of Hot Metal polished and cleaved surfaces, has been carried out using depth-sensitive non-destructive X-ray techniques. The near surface crystalline quality was studied as a function of depth using in-plane grazing incidence X-ray diffraction. Additionally, X-ray reflectivity was used to investigate the density, thickness and roughness of near-surface layers. The measurements enable us to estimate the thickness of the affected sub-surface layer. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  8. Reflection of sound from finite-size plane and curved surfaces

    DEFF Research Database (Denmark)

    Rindel, Jens Holger

    2005-01-01

    The author’s research on reflectors over nearly 25 years is summarized. The influence of curvature was analyzed by a geometrical model in order to quantify the attenuation by a simple expression. Reflection from a finite size plate was studied using the Kirchhoff-Fresnel approximation and the des......The author’s research on reflectors over nearly 25 years is summarized. The influence of curvature was analyzed by a geometrical model in order to quantify the attenuation by a simple expression. Reflection from a finite size plate was studied using the Kirchhoff-Fresnel approximation...... in the refurbishment of the concert hall of the Danish Radio in Copenhagen 1989, and later in many other halls. In order to describe the scattering due to edge diffraction the directional characteristic of reflections from a finite-size plate has been studied and a simple approximation valid for octave bands has been...

  9. Surface segregation of InGaAs films by the evolution of reflection high-energy electron diffraction patterns

    International Nuclear Information System (INIS)

    Zhou Xun; Luo Zi-Jiang; Guo Xiang; Zhang Bi-Chan; Shang Lin-Tao; Zhou Qing; Deng Chao-Yong; Ding Zhao

    2012-01-01

    Surface segregation is studied via the evolution of reflection high-energy electron diffraction (RHEED) patterns under different values of As 4 BEP for InGaAs films. When the As 4 BEP is set to be zero, the RHEED pattern keeps a 4×3/(n × 3) structure with increasing temperature, and surface segregation takes place until 470 °C. The RHEED pattern develops into a metal-rich (4 × 2) structure as temperature increases to 495 °C. The reason for this is that surface segregation makes the In inside the InGaAs film climb to its surface. With the temperature increasing up to 515 °C, the RHEED pattern turns into a GaAs(2 × 4) structure due to In desorption. While the As 4 BEP comes up to a specific value (1.33 × 10 -4 Pa−1.33 × 10 -3 Pa), the surface temperature can delay the segregation and desorption. We find that As 4 BEP has a big influence on surface desorption, while surface segregation is more strongly dependent on temperature than surface desorption. (condensed matter: structural, mechanical, and thermal properties)

  10. Interactions of satellite-speed helium atoms with satellite-surfaces. 1. Spatial distributions of reflected helium atoms

    International Nuclear Information System (INIS)

    Liu, S.M.; Rodgers, W.E.; Knuth, E.L.

    1975-06-01

    Interactions of satellite-speed helium atoms with practical satellite surfaces were investigated experimentally, and spatial distributions of satellite-speed helium beams scattered from four different engineering surfaces were measured. The 7000-m/s helium beams were produced using an arc-heated supersonic molecular beam source. The test surfaces included cleaned 6061-T6 aluminum plate, anodized aluminum foil, white paint, and quartz surfaces. Both in-plane (in the plane containing the incident beam and the surface normal) and out-of-plane spatial distributions of reflected helium atoms were measured for six different incidence angles (0, 15, 30, 45, 60, and 75 deg from the surface normal). It was found that a large fraction of the incident helium atoms were scattered back in the vicinity of the incoming beam, particularly in the case of glancing incidence angles. This unexpected scattering feature results perhaps from the gross roughness of these test surfaces. This prominent backscattering could yield drag coefficients which are higher than for surfaces with either forward-lobed or diffusive (cosine) scattering patterns

  11. Analysis of human perception of facial skin radiance by means of image histogram parameters of surface and subsurface reflections from the skin.

    Science.gov (United States)

    Matsubara, Akira; Liang, Zhiwu; Sato, Yuji; Uchikawa, Keiji

    2012-08-01

    The appearance of the skin is the result of complicated light-skin interactions involving surface and subsurface reflections. Radiant skin is a complicated attribute but is important for skin beauty. The aim of the present study was to achieve an understanding of the association between human perceptions of skin radiance and image histogram parameters from technically recorded images of surface and subsurface reflections. Facial images of 45 subjects were evaluated visually by 30 respondents and were also computer analyzed in terms of their image histogram parameters. A partial least squares regression model was created to explain visual perceptions in terms of the image histogram parameters. Visual perceptions of subsurface reflections can be explained in terms of the mean from the subsurface reflection image histogram, and visual perceptions of surface reflections can be explained in terms of the standard deviation (SD) and skewness from the surface reflection image histogram. Skin radiance can be explained in terms of the mean from the subsurface reflection and the SD from the surface reflection. To acquire skin radiance, a surface reflection component that makes the skin look shiny and a subsurface reflection component that is in line with skin fairness are both needed. A balance of these features provides the origin of skin radiance. © 2011 John Wiley & Sons A/S.

  12. BETA SPECTRA. I. Negatrons spectra

    International Nuclear Information System (INIS)

    Grau Malonda, A.; Garcia-Torano, E.

    1978-01-01

    Using the Fermi theory of beta decay, the beta spectra for 62 negatrons emitters have been computed introducing a correction factor for unique forbidden transitions. These spectra are plotted vs. energy, once normal i sed, and tabulated with the related Fermi functions. The average and median energies are calculated. (Author)

  13. Nonlinear reflection of a spherically divergent N-wave from a plane surface: Optical interferometry measurements in air

    Energy Technology Data Exchange (ETDEWEB)

    Karzova, M., E-mail: masha@acs366.phys.msu.ru [Laboratoire de Mécanique des Fluides et d’Acoustique, Ecole Centrale de Lyon, 36 Avenue Guy de Collongue, 69134 Ecully (France); Physics Faculty, Moscow State University, Leninskie Gory, 119991 Moscow (Russian Federation); Yuldashev, P.; Khokhlova, V. [Physics Faculty, Moscow State University, Leninskie Gory, 119991 Moscow (Russian Federation); Ollivier, S.; Blanc-Benon, Ph. [Laboratoire de Mécanique des Fluides et d’Acoustique, Ecole Centrale de Lyon, 36 Avenue Guy de Collongue, 69134 Ecully (France)

    2015-10-28

    Mach stem is a well-known structure typically observed in the process of strong (acoustic Mach numbers greater than 0.4) step-shock waves reflection from a rigid boundary. However, this phenomenon has been much less studied for weak shocks in nonlinear acoustic fields where Mach numbers are in the range from 0.001 to 0.01 and pressure waveforms have more complicated waveforms than step shocks. The goal of this work was to demonstrate experimentally how nonlinear reflection occurs in air for very weak spherically divergent acoustic spark-generated pulses resembling an N-wave. Measurements of reflection patterns were performed using a Mach-Zehnder interferometer. A thin laser beam with sub-millimeter cross-section was used to obtain the time resolution of 0.4 µs, which is 6 times higher than the time resolution of the condenser microphones. Pressure waveforms were reconstructed using the inverse Abel transform applied to the phase of the signal measured by the interferometer. The Mach stem formation was observed experimentally as a result of collision of the incident and reflected shock pulses. It was shown that irregular reflection of the pulse occurred in a dynamic way and the length of the Mach stem increased linearly while the pulse propagated along the surface. Since the front shock of the spark-generated pulse was steeper than the rear shock, irregular type of reflection was observed only for the front shock of the pulse while the rear shock reflection occurred in a regular regime.

  14. Critical and creative reflective inquiry: surfacing narratives to enable learning and inform action

    NARCIS (Netherlands)

    Rn, MscN Shaun Cardiff

    2012-01-01

    Narratives are being increasingly used in nursing and action research. In this participatory action research study, nurse leaders of an acute care of the older person unit collectively, critically and creatively reflected on lived experiences in order to explore the concept of person-centred

  15. Relationship of intertidal surface sediment chlorophyll concentration to hyper-spectral reflectance and chlorophyll fluorescence

    NARCIS (Netherlands)

    Kromkamp, J.C.; Morris, E.P.; Forster, R.M.; Honeywill, C.; Hagerthey, S.; Paterson, D.M.

    2006-01-01

    Estimating biomass of microphytobenthos (MPB) on intertidal mud flats is extremely difficult due to their patchy occurrence, especially at the scale of an entire mud flat. We tested two optical approaches that can be applied in situ: spectral reflectance and chlorophyll fluorescence. These two

  16. Modeling the Anisotropic Reflectance of a Surface with Microstructure Engineered to Obtain Visible Contrast after Rotation

    DEFF Research Database (Denmark)

    Luongo, Andrea; Falster, Viggo; Doest, Mads Emil Brix

    2017-01-01

    rotating it 90 degrees around its normal axis. We build an analytic anisotropic reflectance model based on the microstructure engineered to obtain such contrast. Using our model to render synthetic images, we predict the above mentioned contrasts and compare our predictions with the measurements reported...

  17. Reflection of P and SV waves at the free surface of a monoclinic ...

    Indian Academy of Sciences (India)

    R.Narasimhan(krishtel emaging)1461 1996 Oct 15 13:05:22

    a monoclinic elastic half-space. Numerical results presented indicate that the anisotropy might affect the reflection coefficients significantly. 2. Basic equations. Consider a homogeneous anisotropic elastic medium of monoclinic type. It has one plane of elastic symmetry and its elastic properties are defined by thirteen elastic ...

  18. A bi-layer model for nondestructive prediction of soluble solids content in apple based on reflectance spectra and peel pigments.

    Science.gov (United States)

    Tian, Xi; Li, Jiangbo; Wang, Qingyan; Fan, Shuxiang; Huang, Wenqian

    2018-01-15

    Hyperspectral imaging technology was used to investigate the effect of various peel colors on soluble solids content (SSC) prediction model and build a SSC model insensitive to the color distribution of apple peel. The SSC and peel pigments were measured, effective wavelengths (EWs) of SSC and pigments were selected from the acquired hyperspectral images of the intact and peeled apple samples, respectively. The effect of pigments on the SSC prediction was studied and optimal SSC EWs were selected from the peel-flesh layers spectra after removing the chlorophyll and anthocyanin EWs. Then, the optimal bi-layer model for SSC prediction was built based on the finally selected optimal SSC EWs. Results showed that the correlation coefficient of prediction, root mean square error of prediction and selected bands of the bi-layer model were 0.9560, 0.2528 and 41, respectively, which will be more acceptable for future online SSC prediction of various colors of apple. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. Measuring and modeling the effect of surface moisture on the spectral reflectance of coastal beach sand

    NARCIS (Netherlands)

    Nolet, Corjan; Poortinga, Ate; Roosjen, Peter; Bartholomeus, Harm; Ruessink, Gerben|info:eu-repo/dai/nl/169093360

    2014-01-01

    Surface moisture is an important supply limiting factor for aeolian sand transport, which is the primary driver of coastal dune development. As such, it is critical to account for the control of surface moisture on available sand for dune building. Optical remote sensing has the potential to measure

  20. System for Monitoring, Determining, and Reporting Directional Spectra of Ocean Surface Waves in Near Realtime from a Moored Buoy

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A moored buoy floating at the ocean surface and anchored to the seafloor precisely measures acceleration, pitch, roll, and Earth's magnetic flux field of the buoy...

  1. Light reflection by road surfaces : english edition of Communication 53 of the Study Centre for Road Construction (Mededeling 53 'lichtreflectie van wegdekken', 1984.

    NARCIS (Netherlands)

    SCW-Working Group E2; Schreuder, D.A. Schram, J. Burghout, F. Kreeft, S.G. van der Tan, T.H. & Gorkum, F. van

    1984-01-01

    This report deals with the relationship between the light reflecting properties and the composition of road surfaces. For this it is essential to be able to characterise, identify and classify surfaces with regard to their reflection properties. Identification is possible by means of two parameters

  2. Study of Surface Wettability Change of Unconsolidated Sand Using Diffuse Reflectance Infrared Fourier Transform Spectroscopy and Thermogravimetric Analysis.

    Science.gov (United States)

    Gómora-Herrera, Diana; Navarrete Bolaños, Juan; Lijanova, Irina V; Olivares-Xometl, Octavio; Likhanova, Natalya V

    2018-04-01

    The effects exerted by the adsorption of vapors of a non-polar compound (deuterated benzene) and a polar compound (water) on the surface of Ottawa sand and a sample of reservoir sand (Channel), which was previously impregnated with silicon oil or two kinds of surfactants, (2-hydroxyethyl) trimethylammonium oleate (HETAO) and (2-hydroxyethyl)trimethylammonium azelate (HETAA), were studied by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and thermogravimetric analysis (TGA). The surface chemistry of the sandstone rocks was elucidated by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDX). Terminal surface groups such as hydroxyls can strongly adsorb molecules that interact with these surface groups (surfactants), resulting in a wettability change. The wettability change effect suffered by the surface after treating it with surfactants was possible to be detected by the DRIFTS technique, wherein it was observed that the surface became more hydrophobic after being treated with silicon oil and HETAO; the surface became more hydrophilic after treating it with HETAA.

  3. Directional reflectance factors for monitoring spatial changes in soil surface structure and soil organic matter erosion in agricultural systems

    Science.gov (United States)

    Croft, H.; Anderson, K.

    2012-04-01

    Soils can experience rapid structural degradation in response to land cover changes, resulting in reduced soil productivity, increased erodibility and a loss of soil organic matter (SOM). The breakdown of soil aggregates through slaking and raindrop impact is linked to organic matter turnover, with subsequently eroded material often displaying proportionally more SOM. A reduction in aggregate stability is reflected in a decline in soil surface roughness (SSR), indicating that a soil structural change can be used to highlight soil vulnerability to SOM loss through mineralisation or erosion. Accurate, spatially-continuous measurements of SSR are therefore needed at a variety of spatial and temporal scales to understand the spatial nature of SOM erosion and deposition. Remotely-sensed data can provide a cost-effective means of monitoring changes in soil surface condition over broad spatial extents. Previous work has demonstrated the ability of directional reflectance factors to monitor soil crusting within a controlled laboratory experiment, due to changes in the levels of self-shadowing effects by soil aggregates. However, further research is needed to test this approach in situ, where other soil variables may affect measured reflectance factors and to investigate the use of directional reflectance factors for monitoring soil erosion processes. This experiment assesses the potential of using directional reflectance factors to monitor changes in SSR, aggregate stability and soil organic carbon (SOC) content for two agricultural conditions. Five soil plots representing tilled and seedbed soils were subjected to different durations of natural rainfall, producing a range of different levels of SSR. Directional reflectance factors were measured concomitantly with sampling for soil structural and biochemical tests at each soil plot. Soil samples were taken to measure aggregate stability (wet sieving), SOC (loss on ignition) and soil moisture (gravimetric method). SSM

  4. Three inorganic-organic hybrids of bismuth(III) iodide complexes containing substituted 1,2,4-triazole organic components with charaterizations of diffuse reflectance spectra

    International Nuclear Information System (INIS)

    Liu Bing; Xu Ling; Guo Guocong; Huang Jinshun

    2006-01-01

    The reactions of two kinds of substituted 1,2,4-triazoles with BiI 3 yielded three inorganic-organic hybrids: [HL1] 4 [Bi 6 I 22 ].[L1] 4 .4H 2 O (1) (L1=3-(1,2,4-triazole-4-yl)-1H-1,2,4-triazole); [HL2] 4 [Bi 6 I 22 ].6H 2 O (2); [HL2] 2 [Bi 2 I 8 ].[L2] 2 (3) (L2=(m-phenol)-1,2,4-triazole). Both 1 and 2 have polynuclear anions of [Bi 6 I 22 ] 4- to build up the inorganic layers and substituted 1,2,4-triazoles as the organic layers. Hybrid 3 consists of two BiI 5 square pyramids as inorganic layers. There exist hydrogen bondings and I...;I interactions in the structures of 1, 2 and 3. Optical absorption spectra of 1, 2 and 3 reveal the presence of sharp optical gaps of 1.77, 1.77 and 2.07 eV, respectively, suggesting that these materials behave as semiconductors. - Graphical abstract: The reactions of two kinds of the substituted 1,2,4-triazoles with BiI 3 yielded three layered inorganic-organic hybrids [HL1] 4 [Bi 6 I 22 ].[L1] 4 .4H 2 O (1), [HL2] 4 [Bi 6 I 22 ].6H 2 O (2), [HL2] 2 [Bi 2 I 8 ].[L2] 2 (3) with optical gaps of 1.77, 1.77 and 2.07 eV, respectively. The structures of 1-3 are constructed from inorganic layers of polynuclear anions of bismuth iodine and organic layers of the substituted 1,2,4-triazoles

  5. Porous Nanomaterials for Ultrabroadband Omnidirectional Anti-Reflection Surfaces with Applications in High Concentration Photovoltaics

    KAUST Repository

    Yao, Yuan

    2016-12-06

    Materials for nanoporous coatings that exploit optimized chemistries and self-assembly processes offer capabilities to reach ≈98% transmission efficiency and negligible scattering losses over the broad wavelength range of the solar spectrum from 350 nm to 1.5 μm, on both flat and curved glass substrates. These nanomaterial anti-reflection coatings also offer wide acceptance angles, up to ±40°, for both s- and p-polarization states of incident light. Carefully controlled bilayer films have allowed for the fabrication of dual-sided, gradient index profiles on plano-convex lens elements. In concentration photovoltaics platforms, the resultant enhancements in the photovoltaics efficiencies are ≈8%, as defined by experimental measurements on systems that use microscale triple-junction solar cells. These materials and their applications in technologies that require control over interface reflections have the potential for broad utility in imaging systems, photolithography, light-emitting diodes, and display technologies.

  6. Seasonal signatures in SFG vibrational spectra of the sea surface nanolayer at Boknis Eck Time Series Station (SW Baltic Sea)

    Science.gov (United States)

    Laß, K.; Bange, H. W.; Friedrichs, G.

    2013-08-01

    The very thin sea surface nanolayer on top of the sea surface microlayer, sometimes just one monomolecular layer thick, forms the interface between ocean and atmosphere. Due to the small dimension and tiny amount of substance, knowledge about the development of the layer in the course of the year is scarce. In this work, the sea surface nanolayer at Boknis Eck Time Series Station (BE), southwestern Baltic Sea, has been investigated over a period of three and a half years. Surface water samples were taken monthly by screen sampling and were analyzed in terms of organic content and composition by sum frequency generation spectroscopy, which is specifically sensitive to interfacial layers. A yearly periodicity has been observed with a pronounced abundance of sea surface nanolayer material (such as carbohydrate-rich material) during the summer months. On the basis of our results we conclude that the abundance of organic material in the nanolayer at Boknis Eck is not directly related to phytoplankton abundance alone. We speculate that indeed sloppy feeding of zooplankton together with photochemical and/or microbial processing of organic precursor compounds is responsible for the pronounced seasonality.

  7. Virtual Relighting of a Virtualized Scene by Estimating Surface Reflectance Properties

    OpenAIRE

    福富, 弘敦; 町田, 貴史; 横矢, 直和

    2011-01-01

    In mixed reality that merges real and virtual worlds, it is required to interactively manipulate the illumination conditions in a virtualized space. In general, specular reflections in a scene make it difficult to interactively manipulate the illumination conditions. Our goal is to provide an opportunity to simulate the original scene, including diffuse and specular relfections, with novel viewpoints and illumination conditions. Thus, we propose a new method for estimating diffuse and specula...

  8. Reflection of P and SV waves at the free surface of a monoclinic ...

    Indian Academy of Sciences (India)

    R.Narasimhan(krishtel emaging)1461 1996 Oct 15 13:05:22

    of elastic symmetry are obtained in terms of the direction cosines of the propagation vector. It is shown that ... In general, the particle motion is neither ... qP waves at the plane free boundary of a mon- oclinic half-space. In a subsequent paper, Chat- topadhyay et al (1996) studied the reflection of. qSV waves. Since, in both of ...

  9. Role of the substrate reflectance and surface-bulk treatments in CsI quantum efficiency

    CERN Document Server

    Singh, B K; Nitti, M A; Valentini, A

    2003-01-01

    We have experimentally investigated the following aspects related to the quantum efficiency of CsI photocathodes: the type of substrate, the film thickness and the effect of a 'bulk treatment' during the film growth. We discovered that, using a high reflectivity aluminium substrate, the photoemission of very thin CsI film is enhanced. Our study also revealed that photocathodes become less sensitive to moisture when a negative bias voltage is applied to the substrate during the film deposition process.

  10. Gravimetric and density profiling using the combination of surface acoustic waves and neutron reflectivity.

    Science.gov (United States)

    Toolan, Daniel T W; Barker, Robert; Gough, Tim; Topham, Paul D; Howse, Jonathan R; Glidle, Andrew

    2017-02-01

    A new approach is described herein, where neutron reflectivity measurements that probe changes in the density profile of thin films as they absorb material from the gas phase have been combined with a Love wave based gravimetric assay that measures the mass of absorbed material. This combination of techniques not only determines the spatial distribution of absorbed molecules, but also reveals the amount of void space within the thin film (a quantity that can be difficult to assess using neutron reflectivity measurements alone). The uptake of organic solvent vapours into spun cast films of polystyrene has been used as a model system with a view to this method having the potential for extension to the study of other systems. These could include, for example, humidity sensors, hydrogel swelling, biomolecule adsorption or transformations of electroactive and chemically reactive thin films. This is the first ever demonstration of combined neutron reflectivity and Love wave-based gravimetry and the experimental caveats, limitations and scope of the method are explored and discussed in detail. Copyright © 2016 The Authors. Published by Elsevier Inc. All rights reserved.

  11. Zn(II)-concentration dependent Raman spectra in the dithizone complex on gold nanoparticle surfaces in environmental water samples

    Science.gov (United States)

    Ly, Nguyen Hoang; Joo, Sang-Woo

    2015-11-01

    After the formation of dithizone with metal ion complexes, a selective Raman detection method for the Zn2+ ions in aqueous solutions was developed by observing the intensity change of the ring mode peaks at ∼1585 cm-1 on gold nanoparticles (AuNPs). At high concentrations of Zn2+ ions, the conformation of the dithizone complex may have different orientations on AuNPs to yield the spectral changes at ca. ∼510 and ∼1585 cm-1. The concentration dependent spectra changes indicated that a detection limit would be in the submicromolar region of Zn2+ ions. The other ions of Mg2+, K+, Fe3+, Hg2+, Co2+, Fe2+, Pb2+, Cu2+, Ni2+, Cr3+, NH4+, Cd2+, Na+, Ca2+, and Mn2+ at micromolar concentrations of 1 μM did not produce such spectral changes. The detection limit based on the Raman band intensities was estimated to be as low as 500 nM of Zn2+ ion in aqueous solutions. The three real samples of tap, river, and seawater were tested under the interference of the commonly existing interfering ions. Despite the presence of highly concentrated Na, Ca, Mg, and K, our interfacial spectroscopic methodology of Zn2+ determination could be applied in the environmental water samples.

  12. Classification of reflected signals from cavitated tooth surfaces using an artificial intelligence technique incorporating a fiber optic displacement sensor

    Science.gov (United States)

    Rahman, Husna Abdul; Harun, Sulaiman Wadi; Arof, Hamzah; Irawati, Ninik; Musirin, Ismail; Ibrahim, Fatimah; Ahmad, Harith

    2014-05-01

    An enhanced dental cavity diameter measurement mechanism using an intensity-modulated fiber optic displacement sensor (FODS) scanning and imaging system, fuzzy logic as well as a single-layer perceptron (SLP) neural network, is presented. The SLP network was employed for the classification of the reflected signals, which were obtained from the surfaces of teeth samples and captured using FODS. Two features were used for the classification of the reflected signals with one of them being the output of a fuzzy logic. The test results showed that the combined fuzzy logic and SLP network methodology contributed to a 100% classification accuracy of the network. The high-classification accuracy significantly demonstrates the suitability of the proposed features and classification using SLP networks for classifying the reflected signals from teeth surfaces, enabling the sensor to accurately measure small diameters of tooth cavity of up to 0.6 mm. The method remains simple enough to allow its easy integration in existing dental restoration support systems.

  13. Detection of egg yolk antibodies reflecting Salmonella enteritidis infections using a surface plasmon resonance biosensor

    NARCIS (Netherlands)

    Thomas, M.E.; Bouma, A.; Eerden, van E.; Landman, W.J.M.; Knapen, van F.; Stegeman, J.A.; Bergwerff, A.A.

    2006-01-01

    A surface plasmon resonance (SPR) biosensor assay was developed on the basis of a lipopolysaccharide antigen of Salmonella enterica serovar enteritidis (S. enterica serovar enteritidis) to detect egg yolk antibodies against S. enterica serovar enteritidis. This biosensor assay was compared to two

  14. Processing OMEGA/Mars Express hyperspectral imagery from radiance-at-sensor to surface reflectance

    NARCIS (Netherlands)

    Bakker, W.H.; Ruitenbeek, F.J.A. van; Werff, H.M.A. van der; Zegers, T.E.; Oosthoek, J.H.P.; Marsh, S.H.; Meer, F.D. van der

    2014-01-01

    OMEGA/Mars Express hyperspectral imagery is an excellent source of data for exploring the surface composition of the planet Mars. Compared to terrestrial hyperspectral imagery, the data are challenging to work with; scene-specific transmission models are lacking, spectral features are shallow making

  15. A comparison of reflectance properties on polymer micro-structured functional surface

    DEFF Research Database (Denmark)

    Regi, Francesco; Li, Dongya; Nielsen, Jannik Boll

    by their pitch distance and their angle in respect to the surface (Figure 2). The geometry was obtained by precision milling of a tool steel bar and replicated through silicone replica technology [2], and by hot embossing using Acrylonitrile Butadiene Styrene (ABS). A digital microscope has been used...

  16. Reflection-based fibre-optic refractive index sensor using surface plasmon resonance

    Czech Academy of Sciences Publication Activity Database

    Hlubina, P.; Kadulová, M.; Ciprian, D.; Sobota, Jaroslav

    2014-01-01

    Roč. 9, August 19 (2014), 14033:1-5 ISSN 1990-2573 R&D Projects: GA MŠk(CZ) LO1212 Keywords : surface plasmon resonance * fibre -optic sensor * spectral interrogation technique * aqueous solutions of ethanol * refractive index Subject RIV: BH - Optics, Masers, Lasers Impact factor: 1.231, year: 2014

  17. Neutron and X-ray reflection from surface monolayers of a lipopolyoxazoline

    DEFF Research Database (Denmark)

    Wurlitzer, A.; Politsch, E.; Cevc, G.

    2000-01-01

    were investigated as a function of surface pressure. The data are consistent with a fraction of the polyoxazoline moieties in brush-like conformations coexisting with a smaller fraction that is closely associated with the interface. Across the phase transition that is detected in the isotherm...

  18. Coupled retrieval of aerosol properties and land surface reflection using the Airborne Multiangle SpectroPolarimetric Imager

    Science.gov (United States)

    Xu, Feng; van Harten, Gerard; Diner, David J.; Kalashnikova, Olga V.; Seidel, Felix C.; Bruegge, Carol J.; Dubovik, Oleg

    2017-07-01

    The Airborne Multiangle SpectroPolarimetric Imager (AirMSPI) has been flying aboard the NASA ER-2 high-altitude aircraft since October 2010. In step-and-stare operation mode, AirMSPI acquires radiance and polarization data in bands centered at 355, 380, 445, 470*, 555, 660*, 865*, and 935 nm (* denotes polarimetric bands). The imaged area covers about 10 km by 11 km and is typically observed from nine viewing angles between ±66° off nadir. For a simultaneous retrieval of aerosol properties and surface reflection using AirMSPI, an efficient and flexible retrieval algorithm has been developed. It imposes multiple types of physical constraints on spectral and spatial variations of aerosol properties as well as spectral and temporal variations of surface reflection. Retrieval uncertainty is formulated by accounting for both instrumental errors and physical constraints. A hybrid Markov-chain/adding-doubling radiative transfer (RT) model is developed to combine the computational strengths of these two methods in modeling polarized RT in vertically inhomogeneous and homogeneous media, respectively. Our retrieval approach is tested using 27 AirMSPI data sets with low to moderately high aerosol loadings, acquired during four NASA field campaigns plus one AirMSPI preengineering test flight. The retrieval results including aerosol optical depth, single-scattering albedo, aerosol size and refractive index are compared with Aerosol Robotic Network reference data. We identify the best angular combinations for 2, 3, 5, and 7 angle observations from the retrieval quality assessment of various angular combinations. We also explore the benefits of polarimetric and multiangular measurements and target revisits in constraining aerosol property and surface reflection retrieval.

  19. Surface-enhanced Raman scattering spectra revealing the inter-cultivar differences for Chinese ornamental Flos Chrysanthemum: a new promising method for plant taxonomy

    Directory of Open Access Journals (Sweden)

    Heng Zhang

    2017-10-01

    Full Text Available Abstract Background Flos Chrysanthemi, as a part of Chinese culture for a long history, is valuable for not only environmental decoration but also the medicine and food additive. Due to their voluminously various breeds and extensive distributions worldwide, it is burdensome to make recognition and classification among numerous cultivars with conventional methods which still rest on the level of morphologic observation and description. As a fingerprint spectrum for parsing molecular information, surface-enhanced Raman scattering (SERS could be a suitable candidate technique to characterize and distinguish the inter-cultivar differences at molecular level. Results SERS spectra were used to analyze the inter-cultivar differences among 26 cultivars of Chinese ornamental Flos Chrysanthemum. The characteristic peaks distribution patterns were abstracted from SERS spectra and varied from cultivars to cultivars. For the bands distributed in the pattern map, the similarities in general showed their commonality while in the finer scales, the deviations and especially the particular bands owned by few cultivars revealed their individualities. Since the Raman peaks could characterize specific chemical components, those diversity of patterns could indicate the inter-cultivar differences at the chemical level in fact. Conclusion In this paper, SERS technique is feasible for distinguishing the inter-cultivar differences among Flos Chrysanthemum. The Raman spectral library was built with SERS characteristic peak distribution patterns. A new method was proposed for Flos Chrysanthemum recognition and taxonomy.

  20. Quantitative surface topography determination by Nomarski reflection microscopy. 2: Microscope modification, calibration, and planar sample experiments

    International Nuclear Information System (INIS)

    Hartman, J.S.; Gordon, R.L.; Lessor, D.L.

    1980-01-01

    The application of reflective Nomarski differential interference contrast microscopy for the determination of quantitative sample topography data is presented. The discussion includes a review of key theoretical results presented previously plus the experimental implementation of the concepts using a commercial Momarski microscope. The experimental work included the modification and characterization of a commercial microscope to allow its use for obtaining quantitative sample topography data. System usage for the measurement of slopes on flat planar samples is also discussed. The discussion has been designed to provide the theoretical basis, a physical insight, and a cookbook procedure for implementation to allow these results to be of value to both those interested in the microscope theory and its practical usage in the metallography laboratory

  1. Furan interaction with the Si(001)-(2 x 2) surface: structural, energetics, and vibrational spectra from first-principles

    International Nuclear Information System (INIS)

    Miotto, R; Ferraz, A C

    2009-01-01

    In this work we employ the state of the art pseudopotential method, within a generalized gradient approximation to the density functional theory, to investigate the adsorption process of furan on the silicon (001) surface. A direct comparison of different adsorption structures with x-ray photoelectron spectroscopy (XPS), ultra-violet photoelectron spectroscopy (UPS), high resolution electron energy loss spectroscopy (HREELS), near edge x-ray absorption fine structure (NEXAFS), and high resolution spectroscopy experimental data allows us to identify the [4+2 ] cycloaddition reaction as the most probable adsorbate. In addition, theoretical scanning tunnelling microscopy (STM) images are presented, with a view to contributing to further experimental investigations.

  2. Frequency averaging of fluctuations in the cross-correlation reception of noiselike signals reflected from a rough sea surface

    Science.gov (United States)

    Baranov, V. F.; Gerasimova, T. I.; Gulin, É. P.

    2007-04-01

    For noiselike signals reflected from a rough sea surface and received by a correlation receiver, the effect achieved at the receiver output as a result of frequency averaging of signal fluctuations is considered. Expressions characterizing the effect of frequency averaging are derived by using the generalized two-scale model describing the frequency correlation of strong fluctuations of the transfer function. Results of numerical calculations for the variance of fluctuations at the output of the correlation receiver are presented for different relative values of the frequency bandwidth of noiselike signals and the frequency correlation scales for the cases of both weak and strong fluctuations.

  3. Spatial and energy distributions of satellite-speed helium atoms reflected from satellite-type surfaces

    International Nuclear Information System (INIS)

    Liu, S.M.; Rodgers, W.E.; Knuth, E.L.

    1977-01-01

    Interactions of satellite-speed helium atoms (accelerated in an expansion from an arc-heated supersonic-molecular-beam source) with practical satellite surfaces have been investigated experimentally. The density and energy distributions of the scattered atoms were measured using a detection system developed for this study. This detection system includes (a) a target positioning mechanism, (b) a detector rotating mechanism, and (c) a mass spectrometer and/or a retarding-field energy analyzer. (Auth.)

  4. On fatigue crack growth mechanisms of MMC: Reflection on analysis of 'multi surface initiations'

    International Nuclear Information System (INIS)

    Mkaddem, A.; El Mansori, M.

    2009-01-01

    This work attempts to examine the mechanisms of fatigue when cracks synergetically initiate in more than one site at the specimen surface. The metal matrix composites (MMC) i.e. silicon carbide particles reinforced aluminium matrix composites (Al/SiC p -MMC), seem to be good candidates to accelerate fatigue failures following multi surface initiations (MSI). Closure effects of MSI mechanisms on the variation of fatigue behaviour are explored for various stress states. Experiments were carried out using non pre-treated and pre-treated specimens. Using an Equivalent Ellipse Method (EEM), it is shown that the aspect of surface finish of specimen plays an important role on crack growth. Scanning Electron Microscope (SEM) inspections have lead to distinguishing the initiation regions from propagation regions and final separation regions. It is also revealed that the total lifetime of specimens is sensitive to heat treatment. Moreover, it is found that the appearance of MSI in cycled materials is more probable at high level of fatigue loads.

  5. Deriving surface soil moisture from reflected GNSS signal observations from a grassland site in southwestern France

    Directory of Open Access Journals (Sweden)

    S. Zhang

    2018-03-01

    Full Text Available This work assesses the estimation of surface volumetric soil moisture (VSM using the global navigation satellite system interferometric reflectometry (GNSS-IR technique. Year-round observations were acquired from a grassland site in southwestern France using an antenna consecutively placed at two contrasting heights above the ground surface (3.3 and 29.4 m. The VSM retrievals are compared with two independent reference datasets: in situ observations of soil moisture, and numerical simulations of soil moisture and vegetation biomass from the ISBA (Interactions between Soil, Biosphere and Atmosphere land surface model. Scaled VSM estimates can be retrieved throughout the year removing vegetation effects by the separation of growth and senescence periods and by the filtering of the GNSS-IR observations that are most affected by vegetation. Antenna height has no significant impact on the quality of VSM estimates. Comparisons between the VSM GNSS-IR retrievals and the in situ VSM observations at a depth of 5 cm show good agreement (R2 =  0.86 and RMSE  =  0.04 m3 m−3. It is shown that the signal is sensitive to the grass litter water content and that this effect triggers differences between VSM retrievals and in situ VSM observations at depths of 1 and 5 cm, especially during light rainfall events.

  6. Proteome of conidial surface associated proteins of Aspergillus fumigatus reflecting potential vaccine candidates and allergens.

    Science.gov (United States)

    Asif, Abdul R; Oellerich, Michael; Amstrong, Victor W; Riemenschneider, Birgit; Monod, Michel; Reichard, Utz

    2006-04-01

    Aspergillus fumigatus is a mold causing most of the invasive fungal lung infections in the immunocompromised host. In addition, the species is the causative agent of certain allergic diseases. Both in invasive and in allergic diseases, the conidial surface mediates the first contact with the human immune system. Thus, conidial surface proteins may be reasonable vaccine candidates as well as important allergens. To broaden the list of those antigens, intact viable Aspergillus conidia were extracted with mild alkaline buffer at pH 8.5 in the presence of a 1,3-beta-glucanase. The proteome of this fraction was separated by two- dimensional gel electrophoresis (2-DE) and analyzed by liquid chromatography coupled with tandem mass spectrometry. Altogether 26 different A. fumigatus proteins were identified, twelve of which contain a signal for secretion. Among these were the known major conidial surface protein rodlet A, one acid protease PEP2, one lipase, a putative disulfide isomerase and a putative fructose-1,6-biphosphatase. The known allergen Aspf 3 was identified among the proteins without a signal for secretion. On the basis of the recently annotated A. fumigatus genome (Nature 2005, 438, 1151-1156), proteome analysis is now a powerful tool to confirm expression of hypothetical proteins and, thereby to identify additional vaccine candidates and possible new allergens of this important fungal pathogen.

  7. Deriving surface soil moisture from reflected GNSS signal observations from a grassland site in southwestern France

    Science.gov (United States)

    Zhang, Sibo; Calvet, Jean-Christophe; Darrozes, José; Roussel, Nicolas; Frappart, Frédéric; Bouhours, Gilles

    2018-03-01

    This work assesses the estimation of surface volumetric soil moisture (VSM) using the global navigation satellite system interferometric reflectometry (GNSS-IR) technique. Year-round observations were acquired from a grassland site in southwestern France using an antenna consecutively placed at two contrasting heights above the ground surface (3.3 and 29.4 m). The VSM retrievals are compared with two independent reference datasets: in situ observations of soil moisture, and numerical simulations of soil moisture and vegetation biomass from the ISBA (Interactions between Soil, Biosphere and Atmosphere) land surface model. Scaled VSM estimates can be retrieved throughout the year removing vegetation effects by the separation of growth and senescence periods and by the filtering of the GNSS-IR observations that are most affected by vegetation. Antenna height has no significant impact on the quality of VSM estimates. Comparisons between the VSM GNSS-IR retrievals and the in situ VSM observations at a depth of 5 cm show good agreement (R2 = 0.86 and RMSE = 0.04 m3 m-3). It is shown that the signal is sensitive to the grass litter water content and that this effect triggers differences between VSM retrievals and in situ VSM observations at depths of 1 and 5 cm, especially during light rainfall events.

  8. High-directional light source using photon recycling with a retro-reflective Dome incorporated with a textured LED die surface.

    Science.gov (United States)

    Sun, Ching-Cherng; Chung, Shuang-Chao; Yang, Shuang-Hao; Yu, Yeh-Wei; Chien, Wei-Ting; Chen, Huang-Kuen; Chen, Shih-Peng

    2013-07-29

    This paper demonstrates a novel retro-reflective dome that enhances the directionality of a light emitting diode (LED) by recycling photons reflected by a textured LED die surface. A simulation model is developed to describe both the photon recycling process within the dome and the role of specific pyramid patterns on the top surface of the LED die. Advanced simulations showed that a perfectly polished surface with 100% reflectivity potentially enhances the directionality of the dome by 340%, 250%, and 240% using reflective domes with 10°, 20°, and 30° light cones, respectively. In the experiment, the directionality of the domes exhibiting surface imperfections is enhanced by approximately 160%, 150%, and 130% using 10°, 20°, and 30° light cones, respectively. By incorporating a textured top surface on the LED die, the proposed dome effectively increases the directionality of the LED light source.

  9. Plasmon-less surface enhanced Raman spectra induced by self-organized networks of silica nanoparticles produced by femtosecond lasers.

    Science.gov (United States)

    Bellouard, Yves; Block, Erica; Squier, Jeff; Gobet, Jean

    2017-05-01

    Raman spectroscopy is the workhorse for label-free analysis of molecules. It relies on the inelastic scattering of incoming monochromatic light impinging molecules of interest. This effect leads to a very weak emission of light spectrum that provides a signature of the molecules being observed. Considerable efforts have been made over the last decades, in particular with the development of Surface Enhanced Raman Spectroscopy (SERS), to enhance the intensity of the emitted signal so that ultimately, traces of molecules can be detected. Here, we show that dense self-organized networks of quasi-monodisperse nanoparticles redepositing during femtosecond laser ablation of trenches in fused silica can lead to a significant field enhancement effect, enabling the Raman detection of a single-molecule layer deposited on the surface (so called monolayer). Unlike previously reported for SERS experiments, here, there is no metal layer promoting plasmonics effects causing localized field enhancement. The method for producing SERS substrates is therefore quite straightforward and low cost.

  10. Development of Surfaces Optically Suitable for Flat Solar Panels. [using a reflectometer which separately evaluates spectral and diffuse reflectivities of surfaces

    Science.gov (United States)

    1979-01-01

    A reflectometer which can separately evaluate the spectral and diffuse reflectivities of surfaces is described. A phase locked detection system for the reflectometer is also described. A selective coating on aluminum potentially useful for flat plate solar collector applications is presented. The coating is composed of strongly bound copper oxide (divalent) and is formed by an etching process performed on an aluminum alloy with high copper content. Fabrication costs are expected to be small due to the one stop fabrication process. A number of conclusions gathered from the literature as to the required optical properties of flat plate solar collectors are discussed.

  11. Fluorescence Spectra of Highlighter Inks

    Science.gov (United States)

    Birriel, Jennifer J.; King, Damon

    2018-01-01

    Fluorescence spectra excited by laser pointers have been the subject of several papers in TPT. These papers all describe a fluorescence phenomenon in which the reflected laser light undergoes a change in color: this color change results from the combination of some partially reflected laser light and additional colors generated by fluorescent emission. Here we examine the fluorescence spectra of highlighter inks using green and violet laser pointers. We use an RSpec Explorer spectrometer to obtain spectra and compare the emission spectra of blue, green, yellow, orange, pink, and purple highlighters. The website Compound Interest details the chemical composition of highlighter inks; in addition, the site discusses how some base dye colors can be combined to produce the variety commercially available colors. Spectra obtained in this study were qualitatively consistent with the Compound Interest site. We discuss similarities and differences between various highlighter colors and conclude with the relevance of such studies to physics students.

  12. Stochastic models and spectra of interannual variability of mean annual sea surface temperature in the North Atlantic

    Science.gov (United States)

    Privalsky, V. E.

    1988-10-01

    Estimates of one- and two-variate autoregressive models of mean annual sea surface temperature (SST) in five Smed squares in the North Atlantic are obtained by analysing time series of SST, 1881-1970. Year-to-year variations of SST are shown to follow the AR model of order one with a regression parameter of 0.5 so that their generalized spectrum decreases monotonically and relatively fast with frequency while the limits of statistical predictability amount up to two years. Two-variate models of SST reveal frequency-dependent time lags up to three years and possess slightly better statistical predictability. A feedback in the system of warm and cold currents is found with a characteristic time scale of about six years, which plays an important role in the system's energy budget.

  13. Modeling of Microwave Reflection from the Surface of Water Basins with Spills of Water-Cut Oil

    Science.gov (United States)

    Krotikov, V. D.; Pelushenko, S. A.; Rakut', I. V.; Savelyev, V. Yu.

    2015-06-01

    We consider specific features of reflection of microwaves from the surface of a water basin for the two-layer model of oil spills, which are determined by a water-cut-oil film. Within the spill model, the dielectric properties of water were allowed for in accordance with the Debye theory, and the dielectric properties of the water-cut oil, in accordance with the theory developed for binary systems. The data about variations in the values of reflection coefficients depending on the frequency, viewing angle, thickness of the oil film, and moisture content in the film are obtained. The dependences of reflection coefficients on the film thickness are determined for various values of volume content of the water fraction in oil. Complex values of the dielectric permittivity of oil-water emulsions with preset volume moisture content are found. Describing the obtained dependences of the complex dielectric permittivity of the emulsion on the volume moisture content requires application of asymmetrical formulas for the mixture of polar and nonpolar fluids.

  14. Fluorescence Spectra of Highlighter Inks

    Science.gov (United States)

    Birriel, Jennifer J.; King, Damon

    2018-01-01

    Fluorescence spectra excited by laser pointers have been the subject of several papers in "TPT". These papers all describe a fluorescence phenomenon in which the reflected laser light undergoes a change in color: this color change results from the combination of some partially reflected laser light and additional colors generated by…

  15. 1D Seismic reflection technique to increase depth information in surface seismic investigations

    Science.gov (United States)

    Camilletti, Stefano; Fiera, Francesco; Umberto Pacini, Lando; Perini, Massimiliano; Prosperi, Andrea

    2017-04-01

    1D seismic methods, such as MASW Re.Mi. and HVSR, have been extensively used in engineering investigations, bedrock research, Vs profile and to some extent for hydrologic applications, during the past 20 years. Recent advances in equipment, sound sources and computer interpretation techniques, make 1D seismic methods highly effective in shallow subsoil modeling. Classical 1D seismic surveys allows economical collection of subsurface data however they fail to return accurate information for depths greater than 50 meters. Using a particular acquisition technique it is possible to collect data that can be quickly processed through reflection technique in order to obtain more accurate velocity information in depth. Furthermore, data processing returns a narrow stratigraphic section, alongside the 1D velocity model, where lithological boundaries are represented. This work will show how collect a single-CMP to determine: (1) depth of bedrock; (2) gravel layers in clayey domains; (3) accurate Vs profile. Seismic traces was processed by means a new software developed in collaboration with SARA electronics instruments S.r.l company, Perugia - ITALY. This software has the great advantage of being able to be used directly in the field in order to reduce the times elapsing between acquisition and processing.

  16. Detection of aflatoxin and surface mould contaminated figs by using Fourier transform near-infrared reflectance spectroscopy.

    Science.gov (United States)

    Durmuş, Efkan; Güneş, Ali; Kalkan, Habil

    2017-01-01

    Aflatoxins are toxic metabolites that are mainly produced by members of the Aspergillus section Flavi on many agricultural products. Certain agricultural products such as figs are known to be high risk products for aflatoxin contamination. Aflatoxin contaminated figs may show a bright greenish yellow fluorescence (BGYF) under ultraviolet (UV) light at a wavelength of 365 nm. Traditionally, BGYF positive figs are manually selected by workers. However, manual selection depends on the expertise level of the workers and it may cause them skin-related health problems due to UV radiation. In this study, we propose a non-invasive approach to detect aflatoxin and surface mould contaminated figs by using Fourier transform near-infrared (FT-NIR) reflectance spectroscopy. A classification accuracy of 100% is achieved for classifying the figs into aflatoxin contaminated/uncontaminated and surface mould contaminated/uncontaminated categories. In addition, a strong correlation has been found between aflatoxin and surface mould. Combined with pattern classification methods, the NIR spectroscopy can be used to detect aflatoxin contaminated figs non-invasively. Furthermore, a positive correlation between surface mould and aflatoxin contamination leads to a promising alternative indicator for the detection of aflatoxin-contaminated figs. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

  17. Surface reflectance and conversion efficiency dependence of technologies for mitigating global warming

    Energy Technology Data Exchange (ETDEWEB)

    Edmonds, Ian [Solartran Pty Ltd., 12 Lentara St, Kenmore, Brisbane 4069 (Australia); Smith, Geoff [Physics and Advanced Materials, University of Technology, Sydney, PO Box 123, Broadway, New South Wales 2007 (Australia)

    2011-05-15

    A means of assessing the relative impact of different renewable energy technologies on global warming has been developed. All power plants emit thermal energy to the atmosphere. Fossil fuel power plants also emit CO{sub 2} which accumulates in the atmosphere and provides an indirect increase in global warming via the greenhouse effect. A fossil fuel power plant may operate for some time before the global warming due to its CO{sub 2} emission exceeds the warming due to its direct heat emission. When a renewable energy power plant is deployed instead of a fossil fuel power plant there may be a significant time delay before the direct global warming effect is less than the combined direct and indirect global warming effect from an equivalent output coal fired plant - the ''business as usual'' case. Simple expressions are derived to calculate global temperature change as a function of ground reflectance and conversion efficiency for various types of fossil fuelled and renewable energy power plants. These expressions are used to assess the global warming mitigation potential of some proposed Australian renewable energy projects. The application of the expressions is extended to evaluate the deployment in Australia of current and new geo-engineering and carbon sequestration solutions to mitigate global warming. Principal findings are that warming mitigation depends strongly on the solar to electric conversion efficiency of renewable technologies, geo-engineering projects may offer more economic mitigation than renewable energy projects and the mitigation potential of reforestation projects depends strongly on the location of the projects. (author)

  18. Light depolarization in off-specular reflection on submicro rough metal surfaces with imperfectly random roughness.

    Science.gov (United States)

    Liu, Linsheng; Li, Xuefeng; Nonaka, Kazuhiro

    2015-02-01

    Depolarization at a rough surface relates to its roughness and irregularity (e.g., sags and crests) besides the material property. However, there is still lack of general theory to clearly describe the relationship between depolarization ratios and surface conditions, and one important reason is that the mechanism of depolarization relates to geometric parameters such as microcosmic height/particle distributions of sub-micro to nm levels. To study the mechanism in more detail, a compact laser instrument is developed, and depolarization information of a linearly polarized incident light is used for analyzing the roughness, during which a He-Ne laser source (λ = 632.8 nm) is used. Three nickel specimens with RMS roughness (Rq) less than λ/4 are fabricated and tested. Six different areas in each specimen are characterized in detail using an AFM. Rq are in the range of 34.1-155.0 nm, and the heights are non-Gaussian distribution in the first specimen and near-Gaussian distribution in the others. Off-specular inspection is carried out exactly on these 18 characterized areas, and results show that the cross-polarization ratios match quite well with Rq values of the first sample that has Rq ≤ λ/10 (or Rt ≤ λ), while they match well with maximum height, Rt, values of the other two that have Rt > λ (the maximum derivation is 11%). In addition, since this instrument is simple, portable, stable, and low-cost, it has great potential for practical online roughness testing after a linear calibration.

  19. Near-infrared spectra and rovibrational dynamics on a four-dimensional ab initio potential energy surface of (HBr)2.

    Science.gov (United States)

    Castillo-Chará, J; McIntosh, A L; Wang, Z; Lucchese, R R; Bevan, J W

    2004-06-08

    Supersonic jet investigations of the (HBr)(2) dimer have been carried out using a tunable diode laser spectrometer to provide accurate data for comparison with results from a four-dimensional (4-D) ab initio potential energy surface (PES). The near-infrared nu(1) (+/-), nu(2) (+/-), and (nu(1)+nu(4))(-) bands of (H (79)Br)(2), (H (79)Br-H (81)Br), and (H (81)Br)(2) isotopomers have been recorded in the range 2500-2600 cm(-1) using a CW slit jet expansion with an upgraded near-infrared diode laser spectrometer. The 4-D PES has been calculated for (HBr)(2) using second-order Møller-Plesset perturbation theory with an augmented and polarized 6-311G basis set. The potential is characterized by a global minimum occurring at the H bond structure with the distance between the center of masses (CM) of the monomer being R(CM)=4.10 A with angles theta(A)=10 degrees, theta(B)=100 degrees and a well depth of 692.2 cm(-1), theta(A) is the angle the HBr bond of monomer A makes with the vector from the CM of A to the CM of B, and theta(B) is the corresponding angle monomer B makes with the same CM-CM vector. The barrier for the H interchange occurs at the closed C(2h) structure for which R(CM)=4.07 A, theta(A)=45 degrees, theta(B)=135 degrees, and the barrier height is 73.9 cm(-1). The PES was fitted using a linear-least squares method and the rovibrational energy levels of the complex were calculated by a split pseudospectral method. The spectroscopic data provide accurate molecular parameters for the dimer that are then compared with the results predicted on the basis of the 4-D ab initio PES. (c) 2004 American Institute of Physics.

  20. Analysis of Visible/SWIR surface reflectance ratios for aerosol retrievals from satellite in Mexico City urban area

    Directory of Open Access Journals (Sweden)

    A. D. de Almeida Castanho

    2007-10-01

    Full Text Available The surface reflectance ratio between the visible (VIS and shortwave infrared (SWIR radiation is an important quantity for the retrieval of the aerosol optical depth (τa from the MODIS sensor data. Based on empirically determined VIS/SWIR ratios, MODIS τa retrieval uses the surface reflectance in the SWIR band (2.1 µm, where the interaction between solar radiation and the aerosol layer is small, to predict the visible reflectances in the blue (0.47 µm and red (0.66 µm bands. Therefore, accurate knowledge of the VIS/SWIR ratio is essential for achieving accurate retrieval of aerosol optical depth from MODIS. We analyzed the surface reflectance over some distinct surface covers in and around the Mexico City metropolitan area (MCMA using MODIS radiances at 0.66 µm and 2.1 µm. The analysis was performed at 1.5 km×1.5 km spatial resolution. Also, ground-based AERONET sun-photometer data acquired in Mexico City from 2002 to 2005 were analyzed for aerosol depth and other aerosol optical properties. In addition, a network of hand-held sun-photometers deployed in Mexico City, as part of the MCMA-2006 Study during the MILAGRO Campaign, provided an unprecedented measurement of τa in 5 different sites well distributed in the city. We found that the average RED/SWIR ratio representative of the urbanized sites analyzed is 0.73±0.06 for scattering angles <140° and goes up to 0.77±0.06 for higher ones. The average ratio for non-urban sites was significantly lower (approximately 0.55. In fact, this ratio strongly depends on differences in urbanization levels (i.e. relative urban to vegetation proportions and types of surface materials. The aerosol optical depth retrieved from MODIS radiances at a spatial resolution of 1.5 km×1.5 km and averaged within 10×10 km boxes were compared with collocated 1-h τa averaged from sun-photometer measurements. The use of the new RED

  1. A Solar Reflectance Method for Retrieving Cloud Optical Thickness and Droplet Size Over Snow and Ice Surfaces

    Science.gov (United States)

    Platnick, S.; Li, J. Y.; King, M. D.; Gerber, H.; Hobbs, P. V.

    1999-01-01

    Cloud optical thickness and effective radius retrievals from solar reflectance measurements are traditionally implemented using a combination of spectral channels that are absorbing and non-absorbing for water particles. Reflectances in non-absorbing channels (e.g., 0.67, 0.86, 1.2 micron spectral window bands) are largely dependent on cloud optical thickness, while longer wavelength absorbing channels (1.6, 2. 1, and 3.7 micron window bands) provide cloud particle size information. Cloud retrievals over ice and snow surfaces present serious difficulties. At the shorter wavelengths, ice is bright and highly variable, both characteristics acting to significantly increase cloud retrieval uncertainty. In contrast, reflectances at the longer wavelengths are relatively small and may be comparable to that of dark open water. A modification to the traditional cloud retrieval technique is devised. The new algorithm uses only a combination of absorbing spectral channels for which the snow/ice albedo is relatively small. Using this approach, retrievals have been made with the MODIS Airborne Simulator (MAS) imager flown aboard the NASA ER-2 from May - June 1998 during the Arctic FIRE-ACE field deployment. Data from several coordinated ER-2 and University of Washington CV-580 in situ aircraft observations of liquid water stratus clouds are examined. MAS retrievals of optical thickness, droplet effective radius, and liquid water path are shown to be in good agreement with the in situ measurements. The initial success of the technique has implications for future operational satellite cloud retrieval algorithms in polar and wintertime regions.

  2. Shear-wave seismic reflection imaging and impedance inversion for a near-surface point-bar

    Science.gov (United States)

    Benton, N. W.; Morrison, M.; Lorenzo, J. M.; Odom, B.; Clift, P. D.; Olson, E.; Gostic, A.

    2017-12-01

    Imaging and inversion of SH-waves are useful to detect, map, and quantitatively characterize near-surface point-bar strata. We conduct a horizontally-polarized (SH) reflection survey across and along a near-surface (9 - 40 m) downstream point-bar. We invert for shear-impedance profiles and correlate our interpretation to electrical conductivity (EC) logs in adjacent wells to study the internal architecture and lithology of point-bars. We acquire two common-midpoint (CMP) SH-wave seismic reflection lines at False River (Point Coupee Parish, Louisiana). A 104 m long seismic line (L1) is oriented orthogonal (NW - SE) to point-bar strike. A second line (L2) is 48 m long and set parallel to point-bar strike (NE - SW). Two EC wells lie 33 m apart. Both wells are parallel with respect to the L1 survey and offset from it by 15 m. EC log measurements range from 1 - 25 m depth. Interference of Love-waves prevents seismic imaging at depths less than 9 m. The L1 and L2 data sets are inverted for shear-impedance using a model-based band-limited impedance (BLIMP) algorithm that incorporates a low-frequency velocity model. This model is also used for the depthing processing. The L1 cross-section shows coherent dipping reflection events ( 4 - 7º) from 0.15 - 0.35 s (10 - 40 m). The corresponding shear-impedance profile also reveals coherent and dipping impedance contrasts that grow in magnitude with increasing depth. The L2 cross-section shows comparatively less dip ( 1º) as well as sharper and shallower continuity of reflection events (0.1 - 0.28 s TWT or 9 - 25 m). Depth-converted (TVD) seismic amplitudes and impedance values correlate to near-surface point-bar geology via superposition of log data. The first well (W5) shows distinct EC local maxima (+50 - 70 mS/m) at 14.5 and 15.5 m depth that correlate well with the seismic amplitudes and impedance values from both L1 and L2 data sets. The second well (W7) shows comparatively lower local maxima (+40 - 60 mS/m) but at greater

  3. Characterization of the Vajont landslide (North-Eastern Italy) by means of reflection and surface wave seismics

    Science.gov (United States)

    Petronio, Lorenzo; Boaga, Jacopo; Cassiani, Giorgio

    2016-05-01

    The mechanisms of the disastrous Vajont rockslide (North-Eastern Italy, October 9, 1963) have been studied in great detail over the past five decades. Nevertheless, the reconstruction of the rockslide dynamics still presents several uncertainties, including those related to the accurate estimation of the actual landslide mass. This work presents the results of a geophysical characterization of the Vajont landslide body in terms of material properties and buried geometry. Both aspects add new information to the existing dataset and will help a better understanding of the rockslide failure mechanisms and dynamics. In addition, some general considerations concerning the intricacies of landslide characterization can be drawn, with due attention to potential pitfalls. The employed techniques are: (i) high resolution P-wave reflection, (ii) high resolution SH-wave reflection, (iii) controlled source surface wave analysis. We adopted as a seismic source a vibrator both for P waves and SH waves, using vertical and horizontal geophones respectively. For the surface wave seismic survey we used a heavy drop-weight source and low frequency receivers. Despite the high noise level caused by the fractured conditions of the large rock body, a common situation in landslide studies, we managed to achieve a satisfying imaging quality of the landslide structure thanks to the large number of active channels, the short receiver interval and the test of appropriate seismic sources. The joint use of different seismic techniques help focus the investigation on the rock mass mechanical properties. Results are in good agreement with the available borehole data, the geological sections and the mechanical properties of the rockmass estimated by other studies. In general the proposed approach is likely to be applicable successfully to similar situations where scattering and other noise sources are a typical bottleneck to geophysical data acquisition on landslide bodies.

  4. An Algorithm for the Retrieval of 30-m Snow-Free Albedo from Landsat Surface Reflectance and MODIS BRDF

    Science.gov (United States)

    Shuai, Yanmin; Masek, Jeffrey G.; Gao, Feng; Schaaf, Crystal B.

    2011-01-01

    We present a new methodology to generate 30-m resolution land surface albedo using Landsat surface reflectance and anisotropy information from concurrent MODIS 500-m observations. Albedo information at fine spatial resolution is particularly useful for quantifying climate impacts associated with land use change and ecosystem disturbance. The derived white-sky and black-sky spectral albedos maybe used to estimate actual spectral albedos by taking into account the proportion of direct and diffuse solar radiation arriving at the ground. A further spectral-to-broadband conversion based on extensive radiative transfer simulations is applied to produce the broadband albedos at visible, near infrared, and shortwave regimes. The accuracy of this approach has been evaluated using 270 Landsat scenes covering six field stations supported by the SURFace RADiation Budget Network (SURFRAD) and Atmospheric Radiation Measurement Southern Great Plains (ARM/SGP) network. Comparison with field measurements shows that Landsat 30-m snow-free shortwave albedos from all seasons generally achieve an absolute accuracy of +/-0.02 - 0.05 for these validation sites during available clear days in 2003-2005,with a root mean square error less than 0.03 and a bias less than 0.02. This level of accuracy has been regarded as sufficient for driving global and regional climate models. The Landsat-based retrievals have also been compared to the operational 16-day MODIS albedo produced every 8-days from MODIS on Terra and Aqua (MCD43A). The Landsat albedo provides more detailed landscape texture, and achieves better agreement (correlation and dynamic range) with in-situ data at the validation stations, particularly when the stations include a heterogeneous mix of surface covers.

  5. Enhancing the chroma of pigmented polymers using antireflective surface structures

    DEFF Research Database (Denmark)

    Clausen, Jeppe Sandvik; Christiansen, Alexander Bruun; Kristensen, Anders

    2013-01-01

    In this paper we investigate how the color of a pigmented polymer is affected by reduction of the reflectance at the air-polymer interface. Both theoretical and experimental investigations show modified diffuse-direct reflectance spectra when the reflectance of the surface is lowered. Specifically...

  6. Evidence for surface water ice in the lunar polar regions using reflectance measurements from the Lunar Orbiter Laser Altimeter and temperature measurements from the Diviner Lunar Radiometer Experiment

    Science.gov (United States)

    Fisher, Elizabeth A.; Lucey, Paul G.; Lemelin, Myriam; Greenhagen, Benjamin T.; Siegler, Matthew A.; Mazarico, Erwan; Aharonson, Oded; Williams, Jean-Pierre; Hayne, Paul O.; Neumann, Gregory A.; Paige, David A.; Smith, David E.; Zuber, Maria T.

    2017-08-01

    We find that the reflectance of the lunar surface within 5° of latitude of the South Pole increases rapidly with decreasing temperature, near ∼110 K, behavior consistent with the presence of surface water ice. The North polar region does not show this behavior, nor do South polar surfaces at latitudes more than 5° from the pole. This South pole reflectance anomaly persists when analysis is limited to surfaces with slopes less than 10° to eliminate false detection due to the brightening effect of mass wasting, and also when the very bright south polar crater Shackleton is excluded from the analysis. We also find that south polar regions of permanent shadow that have been reported to be generally brighter at 1064 nm do not show anomalous reflectance when their annual maximum surface temperatures are too high to preserve water ice. This distinction is not observed at the North Pole. The reflectance excursion on surfaces with maximum temperatures below 110 K is superimposed on a general trend of increasing reflectance with decreasing maximum temperature that is present throughout the polar regions in the north and south; we attribute this trend to a temperature or illumination-dependent space weathering effect (e.g. Hemingway et al., 2015). We also find a sudden increase in reflectance with decreasing temperature superimposed on the general trend at 200 K and possibly at 300 K. This may indicate the presence of other volatiles such as sulfur or organics. We identified and mapped surfaces with reflectances so high as to be unlikely to be part of an ice-free population. In this south we find a similar distribution found by Hayne et al. (2015) based on UV properties. In the north a cluster of pixels near that pole may represent a limited frost exposure.

  7. Specific behavior of the p-aminothiophenol--silver sol system in their Ultra-Violet-Visible (UV-Visible) and Surface Enhanced Raman (SERS) spectra.

    Science.gov (United States)

    Firkala, Tamás; Tálas, Emília; Mihály, Judith; Imre, Tímea; Kristyán, Sándor

    2013-11-15

    The UV-Visible and Surface Enhanced Raman Spectroscopy (SERS) behavior of silver sol (a typical SERS agent) were studied in the presence of different bifunctional thiols such as p-aminothiophenol, p-mercaptobenzoic acid, p-nitrothiophenol, p-aminothiophenol hydrochloride, and 2-mercaptoethylamine hydrochloride in diluted aqueous solution. Our results confirm that the p-aminothiophenol induced aggregation of citrate stabilized silver colloid originates from its electrostatic nature, as well as the azo-bridge formation cannot be the reason of the observed time dependent UV-Visible spectra. Based on our parallel SERS and electrospray ionization mass spectrometry measurements, we have concluded that certain amount of oxidized form of the probe molecule has to be present for the so-called b2-mode enhancement in the SERS spectrum of p-aminothiophenol. Our findings seem to support the idea that the azo-bridge formation is responsible for the b2-mode enhancement in the SERS spectrum of p-aminothiophenol. Copyright © 2013 Elsevier Inc. All rights reserved.

  8. Absorption spectra of localized surface plasmon resonance observed in an inline/picoliter spectrometer cell fabricated by a near ultraviolet femtosecond laser

    Science.gov (United States)

    Shiraishi, Masahiko; Nishiyama, Michiko; Watanabe, Kazuhiro; Kubodera, Shoichi

    2018-03-01

    Absorption spectra based on localized surface plasmon resonance (LSPR) were obtained with an inline/picoliter spectrometer cell. The spectrometer cell was fabricated into an optical glass fiber by focusing a near UV (NUV) femtosecond laser pulses at a wavelength of 400 nm with an energy of 30 μJ. The laser beam was focused from two directions opposite to each other to fabricate a through-hole spectrometer cell. A diameter of the cell was approximately 3 μm, and the length was approximately 62.5 μm, which was nearly equal to the core diameter of the optical fiber. Liquid solution of gold nanoparticles (GNPs) with a diameter of 5-10 nm was injected into the spectrometer cell with its volume of 0.4 pL. The absorption peak centered at 518 nm was observed. An increase of absorption associated with the increase of the number of nanoparticles was in agreement with the numerical calculation based on the Lambert-Beer law.

  9. Spectrophotometric evaluation of surface morphology dependent catalytic activity of biosynthesized silver and gold nanoparticles using UV–vis spectra: A comparative kinetic study

    International Nuclear Information System (INIS)

    Ankamwar, Balaprasad; Kamble, Vaishali; Sur, Ujjal Kumar; Santra, Chittaranjan

    2016-01-01

    Graphical abstract: - Highlights: • The biosynthesized silver nanoparticles were stable for 6 months and used as effective SERS active substrate. • They are effective catalyst in the chemical reduction of 4-nitrophenol to 4-aminophenol. • Comparative catalytic efficiency of both silver and gold nanoparticles was studied spectrophotometrically. • Our results demonstrate surface morphology dependent catalytic activity of both nanoparticles. - Abstract: The development of eco-friendly and cost-effective synthetic protocol for the preparation of nanomaterials, especially metal nanoparticles is an emerging area of research in nanotechnology. These metal nanoparticles, especially silver can play a crucial role in various catalytic reactions. The biosynthesized silver nanoparticles described here was very stable up to 6 months and can be further exploited as an effective catalyst in the chemical reduction of 4-nitrophenol to 4-aminophenol. The silver nanoparticles were utilized as an efficient surface-enhanced Raman scattering (SERS) active substrate using Rhodamine 6G as Raman probe molecule. We have also carried out systematic comparative studies on the catalytic efficiency of both silver and gold nanoparticles using UV–vis spectra to monitor the above reaction spectrophotometrically. We find that the reaction follows pseudo-first order kinetics and the catalytic activity can be explained by a simple model based on Langmuir–Hinshelwood mechanism for heterogeneous catalysis. We also find that silver nanoparticles are more efficient as a catalyst compare to gold nanoparticles in the reduction of 4-nitrophenol to 4-aminophenol, which can be explained by the morphology of the nanoparticles as determined by transmission electron microscopy.

  10. Reflectance model for densely packed media: Estimates of the surface properties of the high-albedo satellites of Saturn

    Science.gov (United States)

    Tishkovets, V. P.; Petrova, E. V.

    2017-07-01

    Interpretation of photometric and polarimetric observations of atmosphereless celestial bodies faces the problems connected with both the insufficient accuracy and level of details in groundbased observations and the current state of the theory of the multiple scattering of light. In application to sparse media, where the electromagnetic waves, propagating between the scatterers, can be considered as spherical (the socalled far-field approximation), this theory is rather well developed for both the diffuse and coherent components of the scattered radiation. In this paper, we show that this theory can be also successfully applied to the measurements of polarization of light scattered by densely packed, though nonabsorbing or weakly absorbing, media. For this purpose, we calculated the models for a semi-infinite layer of the medium composed of randomly oriented clusters of spherical particles and compared them with the data of laboratory and astronomical measurements. The potential of the present approach is illustrated by an example of the interpretation of the polarization measurements of the ice satellites of Saturn—Rhea and Enceladus—which allowed some properties of the surface of these celestial bodies to be estimated. In particular, the ratio of the surface area that makes no contribution to the negative polarization of light reflected at small phase angles to the area producing the negative polarization branch was found. Under the assumption of the same albedo of these areas, this ratio turned out to be 3.31-3.66 and 1.7-3.8 for Rhea and Enceladus, respectively. For Enceladus, it is difficult to obtain a sufficiently narrow range of the estimated parameters, since the number of measurement points in the phase dependence of polarization of this satellite is small. For the surface of Rhea, the estimated packing density of particles, participating in the opposition effects, is approximately 15%, while their smallest size is of the order of the wavelength of

  11. Development of new maskless manufacturing method for anti-reflection structure and application to large-area lens with curved surface

    Science.gov (United States)

    Yamamoto, Kazuya; Takaoka, Toshimitsu; Fukui, Hidetoshi; Haruta, Yasuyuki; Yamashita, Tomoya; Kitagawa, Seiichiro

    2016-03-01

    In general, thin-film coating process is widely applied on optical lens surface as anti-reflection function. In normal production process, at first lens is manufactured by molding, then anti-reflection is added by thin-film coating. In recent years, instead of thin-film coating, sub-wavelength structures adding on surface of molding die are widely studied and development to keep anti-reflection performance. As merits, applying sub-wavelength structure, coating process becomes unnecessary and it is possible to reduce man-hour costs. In addition to cost merit, these are some technical advantages on this study. Adhesion of coating depends on material of plastic, and it is impossible to apply anti-reflection function on arbitrary surface. Sub-wavelength structure can solve both problems. Manufacturing method of anti-reflection structure can be divided into two types mainly. One method is with the resist patterning, and the other is mask-less method that does not require patterning. What we have developed is new mask-less method which is no need for resist patterning and possible to impart an anti-reflection structure to large area and curved lens surface, and can be expected to apply to various market segments. We report developed technique and characteristics of production lens.

  12. Reflectance Modeling

    Science.gov (United States)

    Smith, J. A.; Cooper, K.; Randolph, M.

    1984-01-01

    A classical description of the one dimensional radiative transfer treatment of vegetation canopies was completed and the results were tested against measured prairie (blue grama) and agricultural canopies (soybean). Phase functions are calculated in terms of directly measurable biophysical characteristics of the canopy medium. While the phase functions tend to exhibit backscattering anisotropy, their exact behavior is somewhat more complex and wavelength dependent. A Monte Carlo model was developed that treats soil surfaces with large periodic variations in three dimensions. A photon-ray tracing technology is used. Currently, the rough soil surface is described by analytic functions and appropriate geometric calculations performed. A bidirectional reflectance distribution function is calculated and, hence, available for other atmospheric or canopy reflectance models as a lower boundary condition. This technique is used together with an adding model to calculate several cases where Lambertian leaves possessing anisotropic leaf angle distributions yield non-Lambertian reflectance; similar behavior is exhibited for simulated soil surfaces.

  13. Application of Sol-Gel Method as a Protective Layer on a Specular Reflective Surface for Secondary Reflector in a Solar Receiver

    Energy Technology Data Exchange (ETDEWEB)

    Afrin, Samia; Dagdelen, John; Ma, Zhiwen; Kumar, Vinod

    2017-01-01

    Highly-specular reflective surfaces that can withstand elevated-temperatures are desirable for many applications including reflective heat shielding in solar receivers and secondary reflectors, which can be used between primary concentrators and heat collectors. A high-efficiency, high-temperature solar receiver design based on arrays of cavities needs a highly-specular reflective surface on its front section to help sunlight penetrate into the absorber tubes for effective flux spreading. Since this application is for high-temperature solar receivers, this surface needs to be durable and to maintain its optical properties through the usable life. Degradation mechanisms associated with elevated temperatures and thermal cycling, which include cracking, delamination, corrosion/oxidation, and environmental effects, could cause the optical properties of surfaces to degrade rapidly in these conditions. Protected mirror surfaces for these applications have been tested by depositing a thin layer of SiO2 on top of electrodeposited silver by means of the sol-gel method. To obtain an effective thin film structure, this sol-gel procedure has been investigated extensively by varying process parameters that affect film porosity and thickness. Endurance tests have been performed in a furnace at 150 degrees C for thousands of hours. This paper presents the sol-gel process for intermediate-temperature specular reflective coatings and provides the long-term reliability test results of sol-gel protected silver-coated surfaces.

  14. Radiation reflection from star surface reveals the mystery of interpulse shift and appearance of high frequency components in the Crab pulsar

    Science.gov (United States)

    Kontorovich, V. M.; Trofymenko, S. V.

    2017-12-01

    A new mechanism of radiation emission in the polar gap of a pulsar is discussed. It is based on the curvature radiation which is emitted by positrons moving towards the surface of neutron star along field lines of the inclined magnetic field and reflects from the surface. This mechanism explains the mystery of the interpulse shift and appearance of additional components in the emission of Crab pulsar at high frequencies discovered by Moffett and Hankins twenty years ago. We discuss coherence, energy flux and spectrum of the reflected radiation, appearance and disappearance of the interpulse position shift with the frequency increase. It is also possible that a nonlinear reflection (stimulated scattering) from the star surface is observed in the form of HF components. The frequency drift of these components, discovered by Hankins, Jones and Eilek, is discussed. The nonlinear reflection is associated with “Wood’s anomaly” at the diffracted waves grazing along the star surface. Two components can arise due to slow and fast waves which are present in the magnetospheric plasma. The possible scheme of their appearance due to birefringence at the reflection is also proposed.

  15. Derivation of Land Surface Albedo at High Resolution by Combining HJ-1A/B Reflectance Observations with MODIS BRDF Products

    Directory of Open Access Journals (Sweden)

    Bo Gao

    2014-09-01

    Full Text Available Land surface albedo is an essential parameter for monitoring global/regional climate and land surface energy balance. Although many studies have been conducted on global or regional land surface albedo using various remote sensing data over the past few decades, land surface albedo product with a high spatio–temporal resolution is currently very scarce. This paper proposes a method for deriving land surface albedo with a high spatio–temporal resolution (space: 30 m and time: 2–4 days. The proposed method works by combining the land surface reflectance data at 30 m spatial resolution obtained from the charge-coupled devices in the Huanjing-1A and -1B (HJ-1A/B satellites with the Moderate Resolution Imaging Spectroradiometer (MODIS land surface bidirectional reflectance distribution function (BRDF parameters product (MCD43A1, which is at a spatial resolution of 500 m. First, the land surface BRDF parameters for HJ-1A/B land surface reflectance with a spatial–temporal resolutions of 30 m and 2–4 day are calculated on the basis of the prior knowledge from the MODIS BRDF product; then, the calculated high resolution BRDF parameters are integrated over the illuminating/viewing hemisphere to produce the white- and black-sky albedos at 30 m resolution. These results form the basis for the final land surface albedo derivation by accounting for the proportion of direct and diffuse solar radiation arriving at the ground. The albedo retrieved by this novel method is compared with MODIS land surface albedo products, as well as with ground measurements. The results show that the derived land surface albedo during the growing season of 2012 generally achieved a mean absolute accuracy of ±0.044, and a root mean square error of 0.039, confirming the effectiveness of the newly proposed method.

  16. Surface characterization of selected polymer thin films by total-reflection x-ray fluorescence spectroscopy and x-ray reflectivity

    International Nuclear Information System (INIS)

    Innis, Vallerie Ann A.

    2006-01-01

    Development of available x-ray characterizations tools for grazing incidence techniques was done to be able to probe nano-size thin films. Alignment of a Philips x-ray powder diffractometer was improved to let it perform as an x-ray reflectometer. X-ray reflectometry was coupled with total-reflection x-ray fluorescence spectroscopy. Evaluation of the performance of this grazing incidence techniques was done by preparing polymer thin films of carboxymethylcellulose, carrageenan and polyvinylpyrrolidone (PVP). The thickness of the films were varied by varying the process parameters such as concentration, spin speed and spin time. Angle-dispersive total-reflection x-ray fluorescence spectroscopy profiles of three films showed film formation only in carrageenan and PVP. For both carrageenan and PVP, an increase in concentration yielded a corresponding increase in intensity of the fluorescent or scattered peaks. XRR profiles of carrageenan thin films yielded a mean value for the critical angle close to quartz substrate. Thickness measurements of the prepared carrageenan thin films showed that concentration was the main determinant for final film thickness over the other process parameters. Sulfur fluorescent intensity derived from the TXRF measurement showed a linear relationship with the measured thickness by XRR. For PVP, measured critical angle is lower than quartz. Poor adhesion of the polymer onto the substrate yielded a limited number of thickness measurements made from the XRR profiles. (Author)

  17. Pattern recognition in spectra

    Science.gov (United States)

    Gebran, M.; Paletou, F.

    2017-06-01

    We present a new automated procedure that simultaneously derives the effective temperature Teff, surface gravity log g, metallicity [Fe/H], and equatorial projected rotational velocity ve sin i for stars. The procedure is inspired by the well-known PCA-based inversion of spectropolarimetric full-Stokes solar data, which was used both for Zeeman and Hanle effects. The efficiency and accuracy of this procedure have been proven for FGK, A, and late type dwarf stars of K and M spectral types. Learning databases are generated from the Elodie stellar spectra library using observed spectra for which fundamental parameters were already evaluated or with synthetic data. The synthetic spectra are calculated using ATLAS9 model atmospheres. This technique helped us to detect many peculiar stars such as Am, Ap, HgMn, SiEuCr and binaries. This fast and efficient technique could be used every time a pattern recognition is needed. One important application is the understanding of the physical properties of planetary surfaces by comparing aboard instrument data to synthetic ones.

  18. Pattern recognition in spectra

    International Nuclear Information System (INIS)

    Gebran, M; Paletou, F

    2017-01-01

    We present a new automated procedure that simultaneously derives the effective temperature T eff , surface gravity log g , metallicity [ Fe/H ], and equatorial projected rotational velocity v e sin i for stars. The procedure is inspired by the well-known PCA-based inversion of spectropolarimetric full-Stokes solar data, which was used both for Zeeman and Hanle effects. The efficiency and accuracy of this procedure have been proven for FGK, A, and late type dwarf stars of K and M spectral types. Learning databases are generated from the Elodie stellar spectra library using observed spectra for which fundamental parameters were already evaluated or with synthetic data. The synthetic spectra are calculated using ATLAS9 model atmospheres. This technique helped us to detect many peculiar stars such as Am, Ap, HgMn, SiEuCr and binaries. This fast and efficient technique could be used every time a pattern recognition is needed. One important application is the understanding of the physical properties of planetary surfaces by comparing aboard instrument data to synthetic ones. (paper)

  19. Far-infrared spectra of mesoporous ZnS nanoparticles

    Science.gov (United States)

    Trajić, J.; Romčević, M.; Romčević, N.; Babić, B.; Matović, B.; Baláž, P.

    2016-07-01

    ZnS nanoparticles were synthesized mechanochemically by high-energy milling, with three different milling times (5 min, 10 min and 20 min). Nitrogen adsorption method was used for examining specific surface area and texture of obtained powders. It was found that all samples are completely mesoporous. The optical properties were studied by far-infrared spectroscopy at room temperature in spectral region of 50-600 cm-1. The analysis of the far-infrared reflectivity spectra was made by the fitting procedure. The dielectric function of ZnS nanoparticles is modeled as a mixture of homogenous spherical inclusions in air by the Maxwell-Garnet formula. In the analysis of the far-infrared reflection spectra, appearance of combined plasmon-LO phonon modes (CPPMs) with high phonon damping are observed, which causes decrease of coupled plasmon-phonon frequencies.

  20. Remote compositional analysis of lunar olivine-rich lithologies with Moon Mineralogy Mapper (M3) spectra

    Science.gov (United States)

    Isaacson, P.J.; Pieters, C.M.; Besse, S.; Clark, R.N.; Head, J.W.; Klima, R.L.; Mustard, J.F.; Petro, N.E.; Staid, M.I.; Sunshine, J.M.; Taylor, L.A.; Thaisen, K.G.; Tompkins, S.

    2011-01-01

    A systematic approach for deconvolving remotely sensed lunar olivine-rich visible to near-infrared (VNIR) reflectance spectra with the Modified Gaussian Model (MGM) is evaluated with Chandrayaan-1 Moon Mineralogy Mapper (M 3) spectra. Whereas earlier studies of laboratory reflectance spectra focused only on complications due to chromite inclusions in lunar olivines, we develop a systematic approach for addressing (through continuum removal) the prominent continuum slopes common to remotely sensed reflectance spectra of planetary surfaces. We have validated our continuum removal on a suite of laboratory reflectance spectra. Suites of olivine-dominated reflectance spectra from a small crater near Mare Moscoviense, the Copernicus central peak, Aristarchus, and the crater Marius in the Marius Hills were analyzed. Spectral diversity was detected in visual evaluation of the spectra and was quantified using the MGM. The MGM-derived band positions are used to estimate the olivine's composition in a relative sense. Spectra of olivines from Moscoviense exhibit diversity in their absorption features, and this diversity suggests some variation in olivine Fe/Mg content. Olivines from Copernicus are observed to be spectrally homogeneous and thus are predicted to be more compositionally homogeneous than those at Moscoviense but are of broadly similar composition to the Moscoviense olivines. Olivines from Aristarchus and Marius exhibit clear spectral differences from those at Moscoviense and Copernicus but also exhibit features that suggest contributions from other phases. If the various precautions discussed here are weighed carefully, the methods presented here can be used to make general predictions of absolute olivine composition (Fe/Mg content). Copyright ?? 2011 by the American Geophysical Union.