WorldWideScience

Sample records for surface reflectance properties

  1. Reflection properties of road surfaces. Contribution to OECD Scientific Expert Group AC4 on Road Surface Characteristics.

    NARCIS (Netherlands)

    Schreuder, D.A.

    1983-01-01

    Photometric characteristics of road surfaces are dealt with. Representation of reflection properties in public lighting; quality criteria of road lighting installations; classification of road surfaces; the relation between reflection characteristics and other properties of road pavements in public

  2. Reflection properties of hydrogen ions at helium irradiated tungsten surfaces

    International Nuclear Information System (INIS)

    Doi, K; Tawada, Y; Kato, S; Sasao, M; Kenmotsu, T; Wada, M; Lee, H T; Ueda, Y; Tanaka, N; Kisaki, M; Nishiura, M; Matsumoto, Y; Yamaoka, H

    2016-01-01

    Nanostructured W surfaces prepared by He bombardment exhibit characteristic angular distributions of hydrogen ion reflection upon injection of 1 keV H + beam. A magnetic momentum analyzer that can move in the vacuum chamber has measured the angular dependence of the intensity and the energy of reflected ions. Broader angular distributions were observed for He-irradiated tungsten samples compared with that of the intrinsic polycrystalline W. Both intensity and energy of reflected ions decreased in the following order: the polycrystalline W, the He-bubble containing W, and the fuzz W. Classical trajectory Monte Carlo simulations based on Atomic Collision in Amorphous Target code suggests that lower atom density near the surface can make the reflection coefficients lower due to increasing number of collisions. (paper)

  3. An instrument for the measurement of road surface reflection properties

    DEFF Research Database (Denmark)

    Corell, Dennis Dan; Sørensen, K.

    2017-01-01

    Road surface reflection data in the form of standard r-tables serve as input for design calculations of road lighting installations on traffic roads. However, in several countries the use of the standard r-tables has not been verified by measurement in a long period of time, while the types of road...

  4. An instrument for the measurement of road surface reflection properties

    DEFF Research Database (Denmark)

    Corell, Dennis Dan; Sørensen, K.

    2017-01-01

    surfaces in use have changed - for instance to road surface types with less noise from wheel passages. Because of this, a co-operation between the road administrations of the Nordic countries (abbreviated NMF) decided to construct a portable instrument to be used on selections of traffic roads within......Road surface reflection data in the form of standard r-tables serve as input for design calculations of road lighting installations on traffic roads. However, in several countries the use of the standard r-tables has not been verified by measurement in a long period of time, while the types of road...

  5. Influence of surface roughness on the reflective properties of snow

    International Nuclear Information System (INIS)

    Zhuravleva, Tatiana B.; Kokhanovsky, Alexander A.

    2011-01-01

    In this paper the influence of 3D effect on snow reflection function (SRF) and albedo is studied in the framework of the stochastic radiative transfer theory. In particular, the corresponding equations for the averaged intensity of reflected light are solved for the ensemble of realizations of the stochastic field κ(r), describing the distribution of 3D elements on the flat semi-infinite snow layer (SISL). The reflection from the underlying SISL is modeled using the solution of the 1D radiative transfer equation. The corresponding look-up tables were compiled beforehand and used in the simulation process. In accordance with the previous studies, it was found that the albedo of snow layer is reduced (in particular, in the infrared region), if 3D effects are taken into account. There is no such a reduction, if light absorption in snow is absent. The 3D effects may increase or decrease SRF depending on the sastrugi fraction and illumination/observation conditions.

  6. A comparison of reflectance properties on polymer micro-structured functional surface

    DEFF Research Database (Denmark)

    Regi, Francesco; Li, Dongya; Nielsen, Jannik Boll

    In this study, a functional micro-structure surface [1] has been developed as a combination of arrays of micro ridges. The scope of the surface is to achieve specific directional optical properties: that is, under constrained lighting, maximizing the reflectance from a certain viewing direction, ...

  7. Retrieval and Validation of aerosol optical properties from AHI measurements: impact of surface reflectance assumption

    Science.gov (United States)

    Lim, H.; Choi, M.; Kim, J.; Go, S.; Chan, P.; Kasai, Y.

    2017-12-01

    This study attempts to retrieve the aerosol optical properties (AOPs) based on the spectral matching method, with using three visible and one near infrared channels (470, 510, 640, 860nm). This method requires the preparation of look-up table (LUT) approach based on the radiative transfer modeling. Cloud detection is one of the most important processes for guaranteed quality of AOPs. Since the AHI has several infrared channels, which are very advantageous for cloud detection, clouds can be removed by using brightness temperature difference (BTD) and spatial variability test. The Yonsei Aerosol Retrieval (YAER) algorithm is basically utilized on a dark surface, therefore a bright surface (e.g., desert, snow) should be removed first. Then we consider the characteristics of the reflectance of land and ocean surface using three visible channels. The known surface reflectivity problem in high latitude area can be solved in this algorithm by selecting appropriate channels through improving tests. On the other hand, we retrieved the AOPs by obtaining the visible surface reflectance using NIR to normalized difference vegetation index short wave infrared (NDVIswir) relationship. ESR tends to underestimate urban and cropland area, we improved the visible surface reflectance considering urban effect. In this version, ocean surface reflectance is using the new cox and munk method which considers ocean bidirectional reflectance distribution function (BRDF). Input of this method has wind speed, chlorophyll, salinity and so on. Based on validation results with the sun-photometer measurement in AErosol Robotic NETwork (AERONET), we confirm that the quality of Aerosol Optical Depth (AOD) from the YAER algorithm is comparable to the product from the Japan Aerospace Exploration Agency (JAXA) retrieval algorithm. Our future update includes a consideration of improvement land surface reflectance by hybrid approach, and non-spherical aerosols. This will improve the quality of YAER

  8. Automated sulcal depth measurement on cortical surface reflecting geometrical properties of sulci.

    Directory of Open Access Journals (Sweden)

    Hyuk Jin Yun

    Full Text Available Sulcal depth that is one of the quantitative measures of cerebral cortex has been widely used as an important marker for brain morphological studies. Several studies have employed Euclidean (EUD or geodesic (GED algorithms to measure sulcal depth, which have limitations that ignore sulcal geometry in highly convoluted regions and result in under or overestimated depth. In this study, we proposed an automated measurement for sulcal depth on cortical surface reflecting geometrical properties of sulci, which named the adaptive distance transform (ADT. We first defined the volume region of cerebrospinal fluid between the 3D convex hull and the cortical surface, and constructed local coordinates for that restricted region. Dijkstra's algorithm was then used to compute the shortest paths from the convex hull to the vertices of the cortical surface based on the local coordinates, which may be the most proper approach for defining sulcal depth. We applied our algorithm to both a clinical dataset including patients with mild Alzheimer's disease (AD and 25 normal controls and a simulated dataset whose shape was similar to a single sulcus. The mean sulcal depth in the mild AD group was significantly lower than controls (p = 0.007, normal [mean±SD]: 7.29±0.23 mm, AD: 7.11±0.29 and the area under the receiver operating characteristic curve was relatively high, showing the value of 0.818. Results from clinical dataset that were consistent with former studies using EUD or GED demonstrated that ADT was sensitive to cortical atrophy. The robustness against inter-individual variability of ADT was highlighted through simulation dataset. ADT showed a low and constant normalized difference between the depth of the simulated data and the calculated depth, whereas EUD and GED had high and variable differences. We suggest that ADT is more robust than EUD or GED and might be a useful alternative algorithm for measuring sulcal depth.

  9. Tunable natural nano-arrays : controlling surface properties and light reflectance

    International Nuclear Information System (INIS)

    Watson, J.A.; Myhra, S.; Cribb, B.W.; Hope, G.A.; Watson, G.S.

    2005-01-01

    A sudden transition or impedance mismatch from one optical medium to another can result in unwanted reflections from the surface plane. Modification of a surface by creation of a gradual change in refractive index over a significant portion of a wavelength range will result in a reduction in reflection. Multi-layered thin film coatings based on this phenomenon are widely used on a number of different surfaces (e.g. solar cells, lenses, display screens etc.) to suppress undesired reflections and/or increase light transmittance. An alternative surface modification to the multi-layered stack coating (gradient index coating) is to produce a surface with structures having a period and heights shorter than the light wavelength. These structures act like a pseudo-gradient index coating and can be described by the effective medium theory. In this study we report on nano-structures (a natural pseudo-gradient index coating) which we have found on certain species of cicada wings demonstrating their reflective effectiveness using manipulative atomic force microscopy. (author). 2 refs., 5 figs

  10. Virtual Relighting of a Virtualized Scene by Estimating Surface Reflectance Properties

    OpenAIRE

    福富, 弘敦; 町田, 貴史; 横矢, 直和

    2011-01-01

    In mixed reality that merges real and virtual worlds, it is required to interactively manipulate the illumination conditions in a virtualized space. In general, specular reflections in a scene make it difficult to interactively manipulate the illumination conditions. Our goal is to provide an opportunity to simulate the original scene, including diffuse and specular relfections, with novel viewpoints and illumination conditions. Thus, we propose a new method for estimating diffuse and specula...

  11. Measuring Light Reflectance of BGO Crystal Surfaces

    Science.gov (United States)

    Janecek, Martin; Moses, William W.

    2008-10-01

    A scintillating crystal's surface reflectance has to be well understood in order to accurately predict and optimize the crystal's light collection through Monte Carlo simulations. In this paper, we measure the inner surface reflectance properties for BGO. The measurements include BGO crystals with a mechanically polished surface, rough-cut surface, and chemically etched surface, and with various reflectors attached, both air-coupled and with coupling compound. The measurements are performed with a laser aimed at the center of a hemispherical shaped BGO crystal. The hemispherical shape eliminates any non-perpendicular angles for light entering and exiting the crystal. The reflected light is collected with an array of photodiodes. The laser can be set at an arbitrary angle, and the photodiode array is rotated to fully cover 2pi of solid angle. The current produced in the photodiodes is readout with a digital multimeter connected through a multiplexer. The two rows of photodiodes achieve 5-degree by 4-degree resolution, and the current measurement has a dynamic range of 105:1. The acquired data was not described by the commonly assumed linear combination of specular and diffuse (Lambertian) distributions, except for a very few surfaces. Surface roughness proved to be the most important parameter when choosing crystal setup. The reflector choice was of less importance and of almost no consequence for rough-cut surfaces. Pure specular reflection distribution for all incidence angles was measured for polished surfaces with VM2000 film, while the most Lambertian distribution for any surface finish was measured for titanium dioxide paint. The distributions acquired in this paper will be used to create more accurate Monte Carlo models for light reflection distribution within BGO crystals.

  12. Adsorption of benzyldimethylhexadecylammonium chloride at the hydrophobic silica-water interface studied by total internal reflection Raman spectroscopy: effects of silica surface properties and metal salt addition.

    Science.gov (United States)

    Grenoble, Zlata; Baldelli, Steven

    2013-08-29

    The adsorption of the cationic surfactant benzyldimethylhexadecylammonium (BDMHA(+)) chloride was studied at an octadecyltrichlorosilane (OTS)-monolayer-modified silica-water interface by Raman spectroscopy in total internal reflection (TIR) geometry. The present study demonstrates the capabilities of this spectroscopic technique to evaluate thermodynamic and kinetic BDMHA(+)Cl(-) adsorption properties at the hydrophobic silica surface. The surface coverage of BDMHA(+) decreased by 50% at the hydrophobic OTS-silica surface relative to the surface coverage on bare silica; the dominating driving mechanisms for surfactant adsorption were identified as hydrophobic effects and head group charge screening by the electrolyte counterions. Addition of magnesium metal salt (MgCl2) to the aqueous solution (∼ neutral pH) lowered the surface coverage and moderately increased the Langmuir adsorption constants relative to those of the pure surfactant. These trends were previously observed at the hydrophilic, negatively charged silica surface but with a smaller change in the Gibbs free energy of adsorption at the hydrophobic silica surface. The hydrophobic OTS-silica surface properties resulted in shorter times for the surfactant to reach steady-state adsorption conditions compared to the slow adsorption kinetics previously seen with the surfactant at the hydrophilic surface. Adsorption isotherms, based on Raman signal intensities from spectral analysis, were developed according to the Langmuir adsorption model for the pure surfactant at the OTS-silica-water interface; the modified Langmuir model was applied to the surfactant adsorption in the presence of 5, 10, 50, and 100 mM magnesium chloride. Spectral analysis of the Raman scattering intensities and geometric considerations suggests a hemimicelle-type surface aggregate as the most likely surfactant structure at the OTS-silica surface. The different kinetics observed at the hydrophilic versus the hydrophobic silica surface

  13. Preparation of composite micro/nano structure on the silicon surface by reactive ion etching: Enhanced anti-reflective and hydrophobic properties

    Science.gov (United States)

    Zeng, Yu; Fan, Xiaoli; Chen, Jiajia; He, Siyu; Yi, Zao; Ye, Xin; Yi, Yougen

    2018-05-01

    A silicon substrate with micro-pyramid structure (black silicon) is prepared by wet chemical etching and then subjected to reactive ion etching (RIE) in the mixed gas condition of SF6, CHF3 and He. We systematically study the impacts of flow rates of SF6, CHF3 and He, the etching pressure and the etching time on the surface morphology and reflectivity through various characterizations. Meanwhile, we explore and obtain the optimal combination of parameters for the preparation of composite structure that match the RIE process based on the basis of micro-pyramid silicon substrate. The composite sample prepared under the optimum parameters exhibits excellent anti-reflective performance, hydrophobic, self-cleaning and anti-corrosive properties. Based on the above characteristics, the composite micro/nano structure can be applied to solar cells, photodetectors, LEDs, outdoor devices and other important fields.

  14. Coupled Retrieval of Aerosol Properties and Surface Reflection Using the Airborne Multi-angle SpectroPolarimetric Imager (AirMSPI)

    Science.gov (United States)

    Xu, F.; van Harten, G.; Kalashnikova, O. V.; Diner, D. J.; Seidel, F. C.; Garay, M. J.; Dubovik, O.

    2016-12-01

    The Airborne Multi-angle SpectroPolarimetric Imager (AirMSPI) [1] has been flying aboard the NASA ER-2 high altitude aircraft since October 2010. In step-and-stare operation mode, AirMSPI acquires radiance and polarization data at 355, 380, 445, 470*, 555, 660*, 865*, and 935 nm (* denotes polarimetric bands). The imaged area covers about 10 km by 10 km and is observed from 9 view angles between ±67° off of nadir. We have developed an efficient and flexible code that uses the information content of AirMSPI data for a coupled retrieval of aerosol properties and surface reflection. The retrieval was built based on the multi-pixel optimization concept [2], with the use of a hybrid radiative transfer model [3] that combines the Markov Chain [4] and adding/doubling methods [5]. The convergence and robustness of our algorithm is ensured by applying constraints on (a) the spectral variation of the Bidirectional Polarization Distribution Function (BPDF) and angular shape of the Bidirectional Reflectance Distribution Function (BRDF); (b) the spectral variation of aerosol optical properties; and (c) the spatial variation of aerosol parameters across neighboring image pixels. Our retrieval approach has been tested using over 20 AirMSPI datasets having low to moderately high aerosol loadings ( 0.02550-nmSpace Sci. Rev. 16, 527 (1974).

  15. A climatology of visible surface reflectance spectra

    International Nuclear Information System (INIS)

    Zoogman, Peter; Liu, Xiong; Chance, Kelly; Sun, Qingsong; Schaaf, Crystal; Mahr, Tobias; Wagner, Thomas

    2016-01-01

    We present a high spectral resolution climatology of visible surface reflectance as a function of wavelength for use in satellite measurements of ozone and other atmospheric species. The Tropospheric Emissions: Monitoring of Pollution (TEMPO) instrument is planned to measure backscattered solar radiation in the 290–740 nm range, including the ultraviolet and visible Chappuis ozone bands. Observation in the weak Chappuis band takes advantage of the relative transparency of the atmosphere in the visible to achieve sensitivity to near-surface ozone. However, due to the weakness of the ozone absorption features this measurement is more sensitive to errors in visible surface reflectance, which is highly variable. We utilize reflectance measurements of individual plant, man-made, and other surface types to calculate the primary modes of variability of visible surface reflectance at a high spectral resolution, comparable to that of TEMPO (0.6 nm). Using the Moderate-resolution Imaging Spectroradiometer (MODIS) Bidirection Reflectance Distribution Function (BRDF)/albedo product and our derived primary modes we construct a high spatial resolution climatology of wavelength-dependent surface reflectance over all viewing scenes and geometries. The Global Ozone Monitoring Experiment–2 (GOME-2) Lambertian Equivalent Reflectance (LER) product provides complementary information over water and snow scenes. Preliminary results using this approach in multispectral ultraviolet+visible ozone retrievals from the GOME-2 instrument show significant improvement to the fitting residuals over vegetated scenes. - Highlights: • Our goals was visible surface reflectance for satellite trace gas measurements. • Captured the range of surface reflectance spectra through EOF analysis. • Used satellite surface reflectance products for each given scene to anchor EOFs. • Generated a climatology of time/geometry dependent surface reflectance spectra. • Demonstrated potential to

  16. Transmission and reflection properties of terahertz fractal metamaterials

    DEFF Research Database (Denmark)

    Malureanu, Radu; Lavrinenko, Andrei; Cooke, David

    2010-01-01

    We use THz time-domain spectroscopy to investigate transmission and reflection properties of metallic fractal metamaterial structures. We observe loss of free-space energy at certain resonance frequencies, indicating excitation of surface modes of the metamaterial.......We use THz time-domain spectroscopy to investigate transmission and reflection properties of metallic fractal metamaterial structures. We observe loss of free-space energy at certain resonance frequencies, indicating excitation of surface modes of the metamaterial....

  17. A Bayesian Reflection on Surfaces

    Directory of Open Access Journals (Sweden)

    David R. Wolf

    1999-10-01

    Full Text Available Abstract: The topic of this paper is a novel Bayesian continuous-basis field representation and inference framework. Within this paper several problems are solved: The maximally informative inference of continuous-basis fields, that is where the basis for the field is itself a continuous object and not representable in a finite manner; the tradeoff between accuracy of representation in terms of information learned, and memory or storage capacity in bits; the approximation of probability distributions so that a maximal amount of information about the object being inferred is preserved; an information theoretic justification for multigrid methodology. The maximally informative field inference framework is described in full generality and denoted the Generalized Kalman Filter. The Generalized Kalman Filter allows the update of field knowledge from previous knowledge at any scale, and new data, to new knowledge at any other scale. An application example instance, the inference of continuous surfaces from measurements (for example, camera image data, is presented.

  18. Simulation Tool for GNSS Ocean Surface Reflections

    DEFF Research Database (Denmark)

    Høeg, Per; von Benzon, Hans-Henrik; Durgonics, Tibor

    2015-01-01

    GNSS coherent and incoherent reflected signals have the potential of deriving large scale parameters of ocean surfaces, as barotropic variability, eddy currents and fronts, Rossby waves, coastal upwelling, mean ocean surfaceheights, and patterns of the general ocean circulation. In the reflection...... zone the measurements may deriveparameters as sea surface roughness, winds, waves, heights and tilts from the spectral measurements. Previous measurements from the top of mountains and airplanes have shown such results leading.The coming satellite missions, CYGNSS, COSMIC-2, and GEROS...

  19. The strong reflecting property and Harrington's Principle

    OpenAIRE

    Cheng, Yong

    2015-01-01

    In this paper we characterize the strong reflecting property for $L$-cardinals for all $\\omega_n$, characterize Harrington's Principle $HP(L)$ and its generalization and discuss the relationship between the strong reflecting property for $L$-cardinals and Harrington's Principle $HP(L)$.

  20. Use of reflective surfaces on roadway embankment

    DEFF Research Database (Denmark)

    Jørgensen, Anders Stuhr; Doré, Guy

    2007-01-01

    adherence characteristics for roadway use. In Kangerlussuaq Airport, western Greenland, ground-penetrating radar (GPR) has been used to compare the variation of the frost table underneath a normal black asphalt surface and a more reflective surface (white paint). The GPR results have shown a clear...

  1. X-ray reflectivity and surface roughness

    International Nuclear Information System (INIS)

    Ocko, B.M.

    1988-01-01

    Since the advent of high brightness synchrotron radiation sources there has been a phenomenal growth in the use of x-rays as a probe of surface structure. The technique of x-ray reflectivity is particularly relevant to electrochemists since it is capable of probing the structure normal to an electrode surface in situ. In this paper the theoretical framework for x-ray reflectivity is reviewed and the results from previous non-electrochemistry measurements are summarized. These measurements are from the liquid/air interface (CCl 4 ), the metal crystal vacuum interface (Au(100)), and from the liquid/solid interface(liquid crystal/silicon). 34 refs., 5 figs

  2. Surface composition of Mercury from reflectance spectrophotometry

    Science.gov (United States)

    Vilas, Faith

    1988-01-01

    The controversies surrounding the existing spectra of Mercury are discussed together with the various implications for interpretations of Mercury's surface composition. Special attention is given to the basic procedure used for reducing reflectance spectrophotometry data, the factors that must be accounted for in the reduction of these data, and the methodology for defining the portion of the surface contributing the greatest amount of light to an individual spectrum. The application of these methodologies to Mercury's spectra is presented.

  3. Reflectance spectroscopy and asteroid surface mineralogy

    International Nuclear Information System (INIS)

    Gaffey, M.J.; Bell, J.F.; Cruikshank, D.P.

    1989-01-01

    Information available from reflectance spectroscopy on the surface mineralogy of asteroids is discussed. Current spectral interpretive procedures used in the investigations of asteroid mineralogy are described. Present understanding of the nature and history of asteroids is discussed together with some still unresolved issues such as the source of ordinary chondrites. 100 refs

  4. On automatic visual inspection of reflective surfaces

    DEFF Research Database (Denmark)

    Kulmann, Lionel

    1995-01-01

    surfaces, providing new and exciting applications subject to automated visual inspection. Several contextual features have been surveyed along with introduction of novel methods to perform data-dependent enhancement of local surface appearance . Morphological methods have been described and utilized......This thesis descrbes different methods to perform automatic visual inspection of reflective manufactured products, with the aim of increasing productivity, reduce cost and improve the quality level of the production. We investigate two different systems performing automatic visual inspection....... The first is the inspection of highly reflective aluminum sheets, used by the Danish company Bang & Olufsen, as a part of the exterior design and general appearance of their audio and video products. The second is the inspection of IBM hard disk read/write heads for defects during manufacturing. We have...

  5. Average nuclear surface properties

    International Nuclear Information System (INIS)

    Groote, H. von.

    1979-01-01

    The definition of the nuclear surface energy is discussed for semi-infinite matter. This definition is extended also for the case that there is a neutron gas instead of vacuum on the one side of the plane surface. The calculations were performed with the Thomas-Fermi Model of Syler and Blanchard. The parameters of the interaction of this model were determined by a least squares fit to experimental masses. The quality of this fit is discussed with respect to nuclear masses and density distributions. The average surface properties were calculated for different particle asymmetry of the nucleon-matter ranging from symmetry beyond the neutron-drip line until the system no longer can maintain the surface boundary and becomes homogeneous. The results of the calculations are incorporated in the nuclear Droplet Model which then was fitted to experimental masses. (orig.)

  6. ASTER L2 Surface Reflectance SWIR and ASTER L2 Surface Reflectance VNIR V003

    Data.gov (United States)

    National Aeronautics and Space Administration — The ASTER L2 Surface Reflectance is a multi-file product that contains atmospherically corrected data for both the Visible Near-Infrared (VNIR) and Shortwave...

  7. Optical properties (bidirectional reflectance distribution function) of shot fabric

    NARCIS (Netherlands)

    Lu, Rong; Koenderink, Jan J.; Kappers, Astrid M L

    2000-01-01

    To study the optical properties of materials, one needs a complete set of the angular distribution functions of surface scattering from the materials. Here we present a convenient method for collecting a large set of bidirectional reflectance distribution function (BRDF) samples in the hemispherical

  8. Remote measurement of surface roughness, surface reflectance, and body reflectance with LiDAR.

    Science.gov (United States)

    Li, Xiaolu; Liang, Yu

    2015-10-20

    Light detection and ranging (LiDAR) intensity data are attracting increasing attention because of the great potential for use of such data in a variety of remote sensing applications. To fully investigate the data potential for target classification and identification, we carried out a series of experiments with typical urban building materials and employed our reconstructed built-in-lab LiDAR system. Received intensity data were analyzed on the basis of the derived bidirectional reflectance distribution function (BRDF) model and the established integration method. With an improved fitting algorithm, parameters involved in the BRDF model can be obtained to depict the surface characteristics. One of these parameters related to surface roughness was converted to a most used roughness parameter, the arithmetical mean deviation of the roughness profile (Ra), which can be used to validate the feasibility of the BRDF model in surface characterizations and performance evaluations.

  9. Degradation of Silicon Carbide Reflective Surfaces in the LEO Environment

    Science.gov (United States)

    Mileti, Sandro; Coluzzi, Plinio; Marchetti, Mario

    2009-01-01

    Space mirrors in Low Earth Orbit (LEO) encounter a degradation problem caused by the impact of atomic oxygen (ATOX) in the space environment. This paper presents an experiment of the atomic oxygen impact degradation and UV synergic effects on ground simulation. The experiment was carried out in a dedicated ATOX simulation vacuum chamber. As target materials, a polished CVD Beta-silicon carbide (SiC) coating was investigated. The selection of silicon carbide is due to its high potential candidate as a mirror layer substrate material for its good reflectance at UV wavelengths and excellent thermal diffusivity. It has highly desirable mechanical and thermal properties and can achieve an excellent surface finish. The deposition of the coatings were on carbon-based material substrate; i.e., silicon impregnated carbon fiber composite (C/SiC). Mechanical and thermal properties of the coatings such as hardness and Coefficient of Thermal Expansion (CTE) were achieved. Several atomic oxygen impact angles were studied tilting the target samples respect to the flux direction. The various impact angles permitted to analyze the different erosion rates and typologies which the mirrors would encounter in LEO environment. The degradation was analyzed in various aspects. Macroscopic mass loss per unit area, surface roughness and morphology change were basically analyzed. The exposed surfaces of the materials were observed through a Scanning Electron Microscope (SEM). Secondly, optical diagnostic of the surfaces were performed in order to investigate their variation in optical properties as the evaluation of reflectance degradation. The presence of micro-cracks caused by shrinkage, grinding, polishing or thermal cycling and the porosity in the coatings, could have led to the undercutting phenomenon. Observation of uprising of undercutting was also conducted. Remarks are given regarding capabilities in short-term mission exposures to the LEO environment of this coating.

  10. Surface properties of beached plastics.

    Science.gov (United States)

    Fotopoulou, Kalliopi N; Karapanagioti, Hrissi K

    2015-07-01

    Studying plastic characteristics in the marine environment is important to better understand interaction between plastics and the environment. In the present study, high-density polyethylene (HDPE), polyethylene terephalate (PET), and polyvinyl chloride (PVC) samples were collected from the coastal environment in order to study their surface properties. Surface properties such as surface functional groups, surface topography, point of zero charge, and color change are important factors that change during degradation. Eroded HDPE demonstrated an altered surface topography and color and new functional groups. Eroded PET surface was uneven, yellow, and occasionally, colonized by microbes. A decrease in Fourier transform infrared (FTIR) peaks was observed for eroded PET suggesting that degradation had occurred. For eroded PVC, its surface became more lamellar and a new FTIR peak was observed. These surface properties were obtained due to degradation and could be used to explain the interaction between plastics, microbes, and pollutants.

  11. Reflectivity reduction of retro-reflector installed in LHD due to plasma surface interaction

    International Nuclear Information System (INIS)

    Yoshida, N.; Ohtawa, Y.; Ebihara, A.; Akiyama, T.; Tokitani, M.; Ashikawa, N.; Kawahata, K.

    2008-10-01

    Optical reflectivity of the retro-reflector installed in LHD as the first mirror was reduced seriously by plasma wall interaction. In order to understand the mechanism of the reflectivity reduction, optical and material properties of the mirror surfaces have been examined extensively. It was found that the deposited impurity layers caused the serious reduction of the reflectivity. Formation of iron oxide, bulges structure and He bubbles are the major factors for the reflectivity reduction in the wide wave length range. (author)

  12. The differential equation of an arbitrary reflecting surface

    Science.gov (United States)

    Melka, Richard F.; Berrettini, Vincent D.; Yousif, Hashim A.

    2018-05-01

    A differential equation describing the reflection of a light ray incident upon an arbitrary reflecting surface is obtained using the law of reflection. The derived equation is written in terms of a parameter and the value of this parameter determines the nature of the reflecting surface. Under various parametric constraints, the solution of the differential equation leads to the various conic surfaces but is not generally solvable. In addition, the dynamics of the light reflections from the conic surfaces are executed in the Mathematica software. Our derivation is the converse of the traditional approach and our analysis assumes a relation between the object distance and the image distance. This leads to the differential equation of the reflecting surface.

  13. Effects of Rocket Exhaust on Lunar Soil Reflectance Properties

    Science.gov (United States)

    Clegg, R. N.; Jolliff, B. L.; Robinson, M. S.; Hapke, B. W.; Plescia, J. B.

    2012-12-01

    areas; this magnitude is the same, within uncertainty, for all sites, indicating a common process or combination of processes causing differences in reflectance properties of the regolith. Phase-ratio images and photometric data collected over a range of illumination geometries show that a greater separation in reflectance occurs between the HR-BZs and undisturbed areas with increasing phase angle and indicate that the HR-BZs are less backscattering than undisturbed areas. As working hypotheses, we consider the following possibilities to explain BZ reflectance phenomena: change in macroscopic roughness, microscopic modification of surface structure, redistribution of fines (excavation from LR-BZ and deposition in HR-BZ), change in compaction, contamination from fuel, and modification of maturity. The LR-BZ is affected by macroscopic disruption of the surface and increased shadowing. We infer that HR-BZ reflectance has been affected by scouring from particles entrained by exhaust gases with low-angle trajectories. Entrained particles with trajectories greater than a few degrees relative to horizontal travel well beyond the BZ boundary and do not contribute to BZ reflectance variations. Regolith particle interactions with surface soil within HR-BZs may destroy fine-scale surface structure (e.g., "fairy-castle") and decrease macroscopic roughness, contributing to a decrease in backscattering character within the HR-BZ.

  14. Structural properties of reflected Lévy processes

    DEFF Research Database (Denmark)

    Andersen, Lars Nørvang; Mandjes, Michel

    This paper considers a number of structural properties of reflected Lévy processes, where both one-sided reflection (at 0) and two-sided reflection (at both 0 and K > 0) are examined. With Vt being the position of the reflected process at time t, we focus on the analysis of ζ(t) := EVt and ξ(t) :...

  15. Mars analog minerals' spectral reflectance characteristics under Martian surface conditions

    Science.gov (United States)

    Poitras, J. T.; Cloutis, E. A.; Salvatore, M. R.; Mertzman, S. A.; Applin, D. M.; Mann, P.

    2018-05-01

    We investigated the spectral reflectance properties of minerals under a simulated Martian environment. Twenty-eight different hydrated or hydroxylated phases of carbonates, sulfates, and silica minerals were selected based on past detection on Mars through spectral remote sensing data. Samples were ground and dry sieved to <45 μm grain size and characterized by XRD before and after 133 days inside a simulated Martian surface environment (pressure 5 Torr and CO2 fed). Reflectance spectra from 0.35 to 4 μm were taken periodically through a sapphire (0.35-2.5 μm) and zinc selenide (2.5-4 μm) window over a 133-day period. Mineral stability on the Martian surface was assessed through changes in spectral characteristics. Results indicate that the hydrated carbonates studied would be stable on the surface of Mars, only losing adsorbed H2O while maintaining their diagnostic spectral features. Sulfates were less stable, often with shifts in the band position of the SO, Fe, and OH absorption features. Silicas displayed spectral shifts related to SiOH and hydration state of the mineral surface, while diagnostic bands for quartz were stable. Previous detection of carbonate minerals based on 2.3-2.5 μm and 3.4-3.9 μm features appears to be consistent with our results. Sulfate mineral detection is more questionable since there can be shifts in band position related to SO4. The loss of the 0.43 μm Fe3+ band in many of the sulfates indicate that there are fewer potential candidates for Fe3+ sulfates to permanently exist on the Martian surface based on this band. The gypsum sample changed phase to basanite during desiccation as demonstrated by both reflectance and XRD. Silica on Mars has been detected using band depth ratio at 1.91 and 1.96 μm and band minimum position of the 1.4 μm feature, and the properties are also used to determine their age. This technique continues to be useful for positive silica identifications, however, silica age appears to be less consistent

  16. Critical reflection activation analysis - a new near-surface probe

    International Nuclear Information System (INIS)

    Gunn, J.M.F.; Trohidou, K.N.

    1988-09-01

    We propose a new surface analytic technique, Critical Reflection Activation Analysis (CRAA). This technique allows accurate depth profiling of impurities ≤ 100A beneath a surface. The depth profile of the impurity is simply related to the induced activity as a function of the angle of reflection. We argue that the technique is practical and estimate its accuracy. (author)

  17. Infrared spectral reflectances of asteroid surfaces

    Science.gov (United States)

    Larson, H. P.; Veeder, G. J.

    1979-01-01

    This review compares the types of compositional information produced by three complementary techniques used in infrared observations of asteroid surfaces: broadband JHKL photometry, narrow band photometry, and multiplex spectroscopy. The high information content of these infrared observations permits definitive interpretations of asteroid surface compositions in terms of the major meteoritic minerals (olivine, pyroxene, plagioclase feldspar, hydrous silicates, and metallic Ni-Fe). These studies emphasize the individuality of asteroid surface compositions, the inadequacy of simple comparisons with spectra of meteorites, and the need to coordinate spectral measurements of all types to optimize diagnostic capabilities.

  18. Experimental method for testing diffraction properties of reflection waveguide holograms.

    Science.gov (United States)

    Xie, Yi; Kang, Ming-Wu; Wang, Bao-Ping

    2014-07-01

    Waveguide holograms' diffraction properties include peak wavelength and diffraction efficiency, which play an important role in determining their display performance. Based on the record and reconstruction theory of reflection waveguide holograms, a novel experimental method for testing diffraction properties is introduced and analyzed in this paper, which uses a plano-convex lens optically contacted to the surface of the substrate plate of the waveguide hologram, so that the diffracted light beam can be easily detected. Then an experiment is implemented. The designed reconstruction wavelength of the test sample is 530 nm, and its diffraction efficiency is 100%. The experimental results are a peak wavelength of 527.7 nm and a diffraction efficiency of 94.1%. It is shown that the tested value corresponds well with the designed value.

  19. Computation of Mach reflection from rigid and yielding surfaces

    International Nuclear Information System (INIS)

    Buckingham, A.C.; Wilson, S.S.

    1976-01-01

    The present discussion centers on a theoretical description of one aspect of the irregular or Mach reflection from solid surfaces. The discussion is restricted to analytical considerations and some preliminary results using model approximations to the surface interaction phenomena. Currently, full numerical simulations of the irregular reflection surface interaction dynamics have not been obtained since the method is still under development. Discussion of the numerical method is, therefore, restricted to some special procedures for the gas-solid surface boundary dynamics. The discussion is divided into an introductory section briefly describing a particular Mach reflection process. Subsequently, some of the considerations on boundary conditions are submitted for numerical treatment of the gas-solid interface. Analysis and discussion of a yielding solid surface subjected to impulsive loading from an intense gas shock wave follows. This is used as a guide for the development of the numerical procedure. Mach reflection processes are then briefly reviewed with special attention for similitude and singular perturbation features

  20. Properties of interstellar dust in reflection nebulae

    International Nuclear Information System (INIS)

    Sellgren, K.

    1988-01-01

    Observations of interstellar dust in reflection nebulae are the closest analog in the interstellar medium to studies of cometary dust in our solar system. The presence of a bright star near the reflection nebula dust provides the opportunity to study both the reflection and emission characteristics of interstellar dust. At 0.1 to 1 micrometer, the reflection nebula emission is due to starlight scattered by dust. The albedo and scattering phase function of the dust is determined from observations of the scattered light. At 50 to 200 micrometers, thermal emission from the dust in equilibrium with the stellar radiation field is observed. The derived dust temperature determines the relative values of the absorption coefficient of the dust at wavelengths where the stellar energy is absorbed and at far infrared wavelengths where the absorbed energy is reradiated. These emission mechanisms directly relate to those seen in the near and mid infrared spectra of comets. In a reflection nebula the dust is observed at much larger distances from the star than in our solar system, so that the equilibrium dust temperature is 50 K rather than 300 K. Thus, in reflection nebulae, thermal emission from dust is emitted at 50 to 200 micrometer

  1. A Method of Retrieving BRDF from Surface-Reflected Radiance Using Decoupling of Atmospheric Radiative Transfer and Surface Reflection

    Directory of Open Access Journals (Sweden)

    Alexander Radkevich

    2018-04-01

    Full Text Available Bi-directional reflection distribution function (BRDF defines anisotropy of the surface reflection. It is required to specify the boundary condition for radiative transfer (RT modeling used in aerosol retrievals, cloud retrievals, atmospheric modeling, and other applications. Ground based measurements of reflected radiance draw increasing attention as a source of information about anisotropy of surface reflection. Derivation of BRDF from surface radiance requires atmospheric correction. This study develops a new method of retrieving BRDF on its whole domain, making it immediately suitable for further atmospheric RT modeling applications. The method is based on the integral equation relating surface-reflected radiance, BRDF, and solutions of two auxiliary atmosphere-only RT problems. The method requires kernel-based BRDF. The weights of the kernels are obtained with a quickly converging iterative procedure. RT modeling has to be done only one time before the start of iterative process.

  2. Spectral reflectance properties of carbonaceous chondrites: 1. CI chondrites

    Science.gov (United States)

    Cloutis, E. A.; Hiroi, T.; Gaffey, M. J.; Alexander, C. M. O.'D.; Mann, P.

    2011-03-01

    Existing reflectance spectra of CI chondrites (18 spectra of 3 CIs) have been augmented with new (18 spectra of 2 CIs) reflectance spectra to ascertain the spectral variability of this meteorite class and provide insights into their spectral properties as a function of grain size, composition, particle packing, and viewing geometry. Particle packing and viewing geometry effects have not previously been examined for CI chondrites. The current analysis is focused on the 0.3-2.5 μm interval, as this region is available for the largest number of CI spectra. Reflectance spectra of powdered CI1 chondrites are uniformly dark (IOM), as no other CI opaque phase appears able to produce concurrent darkening and bluing. Magnetite can also explain the presence of an absorption feature near 1 μm in some CI spectra. The most blue-sloped spectra are generally associated with the larger grain size samples. For incidence and emission angles <60°, increasing phase angle results in darker and redder spectra, particularly below ∼1 μm. At high incidence angles (60°), increasing emission angle results in brighter and redder spectra. More densely packed samples and underdense (fluffed) samples show lower overall reflectance than normally packed and flat-surface powdered samples. Some B-class asteroids exhibit selected spectral properties consistent with CI chondrites, although perfect spectral matches have not been found. Because many CI chondrite spectra exhibit absorption features that can be related to specific mineral phases, the search for CI parent bodies can fruitfully be conducted using such parameters.

  3. Viscoelasticity evaluation of rubber by surface reflection of supersonic wave.

    Science.gov (United States)

    Omata, Nobuaki; Suga, Takahiro; Furusawa, Hirokazu; Urabe, Shinichi; Kondo, Takeru; Ni, Qing-Qing

    2006-12-22

    The main characteristic of rubber is a viscoelasticity. So it is important to research the characteristic of the viscoelasticity of the high frequency band for the friction between a rubber material and the hard one with roughness, for instance, the tire and the road. As for the measurement of the viscoelasticity of rubber, DMA (dynamic mechanical analysis) is general. However, some problems are pointed out to the measurement of the high frequency band by DMA. Then, we evaluated the viscoelasticity characteristic by the supersonic wave measurement. However, attenuation of rubber is large, and when the viscoelasticity is measured by the supersonic wave therefore, it is inconvenient and limited in a past method by means of bottom reflection. In this report, we tried the viscoelasticity evaluation by the method of using complex surface reflection coefficient and we compared with the friction coefficient under wide-range friction velocity. As a result, some relationships had been found for two properties. We report the result that character of viscoelasticity of rubber was comparable to friction coefficient.

  4. Preparation of surface conductive and highly reflective silvered polyimide films by surface modification and in situ self-metallization technique

    International Nuclear Information System (INIS)

    Wu Zhanpeng; Wu Dezhen; Qi Shengli; Zhang Teng; Jin Riguang

    2005-01-01

    Double surface conductive and reflective flexible silvered polyimide films have been prepared by alkali hydroxylation of polyimide film surface and incorporation of silver ions through subsequent ion exchange. Thermal curing of silver(I) polyamate precursor leads to re-cycloimidization of modified surface with concomitant silver reduction, yielding a reflective and conductive silver surface approaching that of native metal. The reflective and conductive surface evolves only when the cure temperature rises to 300 deg. C. The metallized films usually retain the essential mechanical properties of the parent films. Films were characterized by transmission electron microscopy (TEM), scanning electron microscopy and tapping mode atomic force microscopy (AFM). AFM demonstrates that the diameter of close-packed silver particles of the silver layers was about 50-150 nm. TEM shows that thickness of silver layer on the polyimide film surface is about 400-600 nm

  5. On the reflection point where light reflects to a known destination on quadratic surfaces.

    Science.gov (United States)

    Gonçalves, Nuno

    2010-01-15

    We address the problem of determining the reflection point on a specular surface where a light ray that travels from a source to a target is reflected. The specular surfaces considered are those expressed by a quadratic equation. So far, there is no closed form explicit equation for the general solution of this determination of the reflection point, and the usual approach is to use the Snell law or the Fermat principle whose equations are derived in multidimensional nonlinear minimizations. We prove in this Letter that one can impose a set of three restrictions to the reflection point that can impose a set of three restrictions that culminates in a very elegant formalism of searching the reflection point in a unidimensional curve in space. This curve is the intersection of two quadratic equations. Some applications of this framework are also discussed.

  6. Properties of backward electromagnetic waves and negative reflection in ferrite films

    International Nuclear Information System (INIS)

    Vashkovsky, Anatolii V; Lock, Edwin H

    2006-01-01

    For a backward electromagnetic wave (magnetostatic wave) in a ferrite film, reflection from a perfect mirror formed by the straight edge of the film is investigated experimentally and theoretically. It is found that when the incident wave is collinear (the group velocity vector and the wave vector have opposite directions), negative reflection occurs at any angle of incidence, i.e., the incident and reflected beams are on the same side of the normal to the boundary. It is discovered that a noncollinear backward wave is nonreciprocal in the sense that its energy can be localized both near the surface and in the middle of the film. This property, previously observed only for surface magnetostatic waves, provides both the efficiency of generating and receiving the wave and the possibility of observing the reflected beam. A situation is realized where wave reflection results in two reflected beams. The properties of backward electromagnetic waves propagating in ferrite films are briefly analyzed. (methodological notes)

  7. Effect of reflective surfaces on a greenhouse lettuce crop

    Energy Technology Data Exchange (ETDEWEB)

    Warman, P.R.; Mayhew, W.J.

    1979-01-01

    The Canadian greenhouse industry is an important segment of horticultural production, providing employment for thousands of people. Continuing increases in the costs of conventional fuel supplies, however, has placed the industry in some jeopardy since the cost of heating during the winter months is also escalating. In response to this problem the Brace Research Institute has developed a single roofed greenhouse designed to capture and store the sun's energy, and to increase the amount of downward solar radiation inside the greenhouse through the use of specularly-reflecting back and side walls. The research investigated the effect of a reflective surface on plant growth, development, and nutritional uptake during fall and the early months of winter. The inside walls of the greenhouse were lined with aluminized polyester to act as a reflective surface and flat black roofing felt paper to provide a non-reflecting surface. Grand Rapids Forcing lettuce was planted from seed into a peat-vermiculite bed and total solar radiation was monitored on the horizontal. Over the duration of the experiment, the reflective side of the greenhouse received more than twice as much solar radiation as the non-reflective side leading to significantly larger plant yields on the reflective side. There were no significant differences in the uptake of the plant macronutrients, N, P, K, Ca, and Mg.

  8. Internal reflection spectroscopic analysis of sulphide mineral surfaces

    International Nuclear Information System (INIS)

    Kaoma, J.

    1989-01-01

    To establish the reason for flotation of sulfide minerals in the absence of any conventional collector, internal reflection spectroscopic analysis (IRS) of their surfaces was conducted. sulfur, sulfates, thiosulfates, and hydrocarbonates have been detected on the surface of as-grand sulfide minerals. On sodium sulfide-treated surfaces, both sulfur and polysulfide have also been found to be present. From these findings, the flotation of sulfide minerals without collectors is discussed. (author). 26 refs

  9. The effect of radiation-thermal treatment on the physicochemical properties of the Ni-Mo/Al2O3 hydrotreatment catalyst. II. UV-Vis diffuse reflectance spectra of surface compounds after irradiation

    International Nuclear Information System (INIS)

    Solovetskii, Yu.I.; Miroshinichenko, I.I.; Lunin, V.V.

    1993-01-01

    Radiation-thermal damage of the surface and the active metal phases of hydrodesulfurization Ni-Mo/Al 2 O 3 catalysts by a fast electron beam of up to 2.0 MeV energy was studied. UV-Vis diffuse reflectance spectra of the industrial and model coked systems after radiation-thermal treatment were measured. 14 refs., 2 figs

  10. Remote sensing reflectance and inherent optical properties of oceanic waters derived from above-water measurements

    Science.gov (United States)

    Lee, Zhongping; Carder, Kendall L.; Steward, Robert G.; Peacock, Thomas G.; Davis, Curtiss O.; Mueller, James L.

    1997-02-01

    Remote-sensing reflectance and inherent optical properties of oceanic properties of oceanic waters are important parameters for ocean optics. Due to surface reflectance, Rrs or water-leaving radiance is difficult to measure from above the surface. It usually is derived by correcting for the reflected skylight in the measured above-water upwelling radiance using a theoretical Fresnel reflectance value. As it is difficult to determine the reflected skylight, there are errors in the Q and E derived Rrs, and the errors may get bigger for high chl_a coastal waters. For better correction of the reflected skylight,w e propose the following derivation procedure: partition the skylight into Rayleigh and aerosol contributions, remove the Rayleigh contribution using the Fresnel reflectance, and correct the aerosol contribution using an optimization algorithm. During the process, Rrs and in-water inherent optical properties are derived at the same time. For measurements of 45 sites made in the Gulf of Mexico and Arabian Sea with chl_a concentrations ranging from 0.07 to 49 mg/m3, the derived Rrs and inherent optical property values were compared with those from in-water measurements. These results indicate that for the waters studied, the proposed algorithm performs quite well in deriving Rrs and in- water inherent optical properties from above-surface measurements for clear and turbid waters.

  11. Optical properties (bidirectional reflectance distribution function) of shot fabric.

    Science.gov (United States)

    Lu, R; Koenderink, J J; Kappers, A M

    2000-11-01

    To study the optical properties of materials, one needs a complete set of the angular distribution functions of surface scattering from the materials. Here we present a convenient method for collecting a large set of bidirectional reflectance distribution function (BRDF) samples in the hemispherical scattering space. Material samples are wrapped around a right-circular cylinder and irradiated by a parallel light source, and the scattered radiance is collected by a digital camera. We tilted the cylinder around its center to collect the BRDF samples outside the plane of incidence. This method can be used with materials that have isotropic and anisotropic scattering properties. We demonstrate this method in a detailed investigation of shot fabrics. The warps and the fillings of shot fabrics are dyed different colors so that the fabric appears to change color at different viewing angles. These color-changing characteristics are found to be related to the physical and geometrical structure of shot fabric. Our study reveals that the color-changing property of shot fabrics is due mainly to an occlusion effect.

  12. Geometrical considerations in analyzing isotropic or anisotropic surface reflections.

    Science.gov (United States)

    Simonot, Lionel; Obein, Gael

    2007-05-10

    The bidirectional reflectance distribution function (BRDF) represents the evolution of the reflectance with the directions of incidence and observation. Today BRDF measurements are increasingly applied and have become important to the study of the appearance of surfaces. The representation and the analysis of BRDF data are discussed, and the distortions caused by the traditional representation of the BRDF in a Fourier plane are pointed out and illustrated for two theoretical cases: an isotropic surface and a brushed surface. These considerations will help characterize either the specular peak width of an isotropic rough surface or the main directions of the light scattered by an anisotropic rough surface without misinterpretations. Finally, what is believed to be a new space is suggested for the representation of the BRDF, which avoids the geometrical deformations and in numerous cases is more convenient for BRDF analysis.

  13. Reflection of slow hydrogen and helium ions from solid surfaces

    International Nuclear Information System (INIS)

    Akkerman, A.F.

    1978-01-01

    Some characteristics of the proton and helium ion flux (E < 10 keV), reflected from solid surfaces are presented. A 'condensed walk' scheme, previously used for electron transport calculations, was adapted. Results obtained either by the scheme or by a more detailed 'consequent' scheme agreed closely. The presented data permit calculations of the mean energy of reflected particles and other values for various energy and angular distributions of incident particles. (author)

  14. Quality Assessment of Landsat Surface Reflectance Products Using MODIS Data

    Science.gov (United States)

    Feng, Min; Huang, Chengquan; Channan, Saurabh; Vermote, Eric; Masek, Jeffrey G.; Townshend, John R.

    2012-01-01

    Surface reflectance adjusted for atmospheric effects is a primary input for land cover change detection and for developing many higher level surface geophysical parameters. With the development of automated atmospheric correction algorithms, it is now feasible to produce large quantities of surface reflectance products using Landsat images. Validation of these products requires in situ measurements, which either do not exist or are difficult to obtain for most Landsat images. The surface reflectance products derived using data acquired by the Moderate Resolution Imaging Spectroradiometer (MODIS), however, have been validated more comprehensively. Because the MODIS on the Terra platform and the Landsat 7 are only half an hour apart following the same orbit, and each of the 6 Landsat spectral bands overlaps with a MODIS band, good agreements between MODIS and Landsat surface reflectance values can be considered indicators of the reliability of the Landsat products, while disagreements may suggest potential quality problems that need to be further investigated. Here we develop a system called Landsat-MODIS Consistency Checking System (LMCCS). This system automatically matches Landsat data with MODIS observations acquired on the same date over the same locations and uses them to calculate a set of agreement metrics. To maximize its portability, Java and open-source libraries were used in developing this system, and object-oriented programming (OOP) principles were followed to make it more flexible for future expansion. As a highly automated system designed to run as a stand-alone package or as a component of other Landsat data processing systems, this system can be used to assess the quality of essentially every Landsat surface reflectance image where spatially and temporally matching MODIS data are available. The effectiveness of this system was demonstrated using it to assess preliminary surface reflectance products derived using the Global Land Survey (GLS) Landsat

  15. DETERMINING REFLECTANCE SPECTRA OF SURFACES AND CLOUDS ON EXOPLANETS

    Energy Technology Data Exchange (ETDEWEB)

    Cowan, Nicolas B.; Strait, Talia E., E-mail: n-cowan@northwestern.edu [Center for Interdisciplinary Exploration and Research in Astrophysics (CIERA), Northwestern University, 2131 Tech Dr., IL 60208 (United States)

    2013-03-01

    Planned missions will spatially resolve temperate terrestrial planets from their host star. Although reflected light from such a planet encodes information about its surface, it has not been shown how to establish surface characteristics of a planet without assuming known surfaces to begin with. We present a reanalysis of disk-integrated, time-resolved, multiband photometry of Earth obtained by the Deep Impact spacecraft as part of the EPOXI Mission of Opportunity. We extract reflectance spectra of clouds, ocean, and land without a priori knowledge of the numbers or colors of these surfaces. We show that the inverse problem of extracting surface spectra from such data is a novel and extreme instance of spectral unmixing, a well-studied problem in remote sensing. Principal component analysis is used to determine an appropriate number of model surfaces with which to interpret the data. Shrink-wrapping a simplex to the color excursions of the planet yields a conservative estimate of the planet's endmember spectra. The resulting surface maps are unphysical, however, requiring negative or larger-than-unity surface coverage at certain locations. Our ''rotational unmixing'' supersedes the endmember analysis by simultaneously solving for the surface spectra and their geographical distributions on the planet, under the assumption of diffuse reflection and known viewing geometry. We use a Markov Chain Monte Carlo to determine best-fit parameters and their uncertainties. The resulting albedo spectra are similar to clouds, ocean, and land seen through a Rayleigh-scattering atmosphere. This study suggests that future direct-imaging efforts could identify and map unknown surfaces and clouds on exoplanets.

  16. Calculation of Reflectance and Transmittance of Coating With Optically Rough Surfaces

    International Nuclear Information System (INIS)

    El-Depsy, A.; Shawky, A.M.

    2011-01-01

    For ideal surfaces, components of the reflected beam are related to the components of the incident beam by Fresnel reflection equation. The surfaces encountered in engineering applications deviate from ideal as a result of roughness, oxidization and contamination; hence the Radiative properties of these real surfaces differ greatly from those predicted by electromagnetic theory. In regard to problems of radiative heat transfer; the roughness of surfaces may be divided into two categories: (1) small surface irregularities such that the incident radiation cannot undergo more than a single reflection, (2) deep cavities in which the incident radiation undergoes multi-reflection. The normally incident radiation from rough surface having small irregularities is reflected partly specularly and partly diffusely [1]. Kubelka-Munk theory (K-M) [2] describes optical characteristics (e.g. reflectance, transmittance and absorbance) by a variety of light scattering media including paints, textiles and papers, and It is widely used in various industrial applications. Moder developments in radiative transfer theory (RTT) enable the derivation of (K-M) parameters from first principles [3]. Kubelka and Munk proposed a theory based on a model of two light fluxes travelling in the forward and backward directions. Subsequently a number of authors refined the theory and compared it with experimental data [4]. Several authors attempted to relate the Kubelka- Munk coefficients to the transport coefficients [5,6

  17. Earth surface reflectance climatology from 3 years of OMI data

    NARCIS (Netherlands)

    Kleipool, Q.L.; Dobber, M.R.; Haan, de J.F.; Levelt, P.F.

    2008-01-01

    Global maps of the Earth's surface Lambertian equivalent reflectance (LER) are constructed using 3 years of Ozone Monitoring Instrument (OMI) measurements obtained between October 2004 and October 2007 at 23 wavelengths between 328 and 500 nm. The maps are constructed on a 0.5° by 0.5°

  18. Nanoimprinted reflecting gratings for long-range surface plasmon polaritons

    DEFF Research Database (Denmark)

    Pedersen, Rasmus Haugstrup; Boltasseva, Alexandra; Johansen, Dan Mario

    2007-01-01

    We present a novel design, fabrication, and characterization of reflecting gratings for long-range surface plasmon polaritons (LR-SPPs) at telecom wavelengths. LR-SPP waveguides consisting of a thin (12 nm) gold film embedded in a thick (45 μm) layer of dielectric polymer cladding are structured...

  19. Copper-assisted, anti-reflection etching of silicon surfaces

    Science.gov (United States)

    Toor, Fatima; Branz, Howard

    2014-08-26

    A method (300) for etching a silicon surface (116) to reduce reflectivity. The method (300) includes electroless deposition of copper nanoparticles about 20 nanometers in size on the silicon surface (116), with a particle-to-particle spacing of 3 to 8 nanometers. The method (300) includes positioning (310) the substrate (112) with a silicon surface (116) into a vessel (122). The vessel (122) is filled (340) with a volume of an etching solution (124) so as to cover the silicon surface (116). The etching solution (124) includes an oxidant-etchant solution (146), e.g., an aqueous solution of hydrofluoric acid and hydrogen peroxide. The silicon surface (116) is etched (350) by agitating the etching solution (124) with, for example, ultrasonic agitation, and the etching may include heating (360) the etching solution (124) and directing light (365) onto the silicon surface (116). During the etching, copper nanoparticles enhance or drive the etching process.

  20. Mercury's Surface Magnetic Field Determined from Proton-Reflection Magnetometry

    Science.gov (United States)

    Winslow, Reka M.; Johnson, Catherine L.; Anderson, Brian J.; Gershman, Daniel J.; Raines, Jim M.; Lillis, Robert J.; Korth, Haje; Slavin, James A.; Solomon, Sean C.; Zurbuchen, Thomas H.; hide

    2014-01-01

    Solar wind protons observed by the MESSENGER spacecraft in orbit about Mercury exhibit signatures of precipitation loss to Mercury's surface. We apply proton-reflection magnetometry to sense Mercury's surface magnetic field intensity in the planet's northern and southern hemispheres. The results are consistent with a dipole field offset to the north and show that the technique may be used to resolve regional-scale fields at the surface. The proton loss cones indicate persistent ion precipitation to the surface in the northern magnetospheric cusp region and in the southern hemisphere at low nightside latitudes. The latter observation implies that most of the surface in Mercury's southern hemisphere is continuously bombarded by plasma, in contrast with the premise that the global magnetic field largely protects the planetary surface from the solar wind.

  1. Repulsive Casimir-Polder potential by a negative reflecting surface

    Science.gov (United States)

    Yuan, Qi-Zhang

    2015-07-01

    We present a scheme to generate an all-range long repulsive Casimir-Polder potential between a perfect negative reflecting surface and a ground-state atom. The repulsive potential is stable and does not decay with time. The Casimir-Polder potential is proportional to z-2 at short atom-surface distances and to z-4 at long atom-surface distances. Because of these advantages, this potential can help in building quantum reflectors, quantum levitating devices, and waveguides for matter waves.

  2. Excitations of surface plasmon polaritons by attenuated total reflection, revisited

    International Nuclear Information System (INIS)

    Barchesi, D.; Otto, A.

    2013-01-01

    Many textbooks and review papers are devoted to plasmonics based on a selection of the numerous bibliography. But none describes the details of the first culmination of plasmonics in 1968, when surface plasmons become a field of optics. The coupling of light with the surface plasmon leads to the surface plasmon polariton (SPP). Therefore, the authors chose to associate historical insight (not avoiding a personal touch), a modern mathematical formulation of the excitation of the SPP by attenuated total reflection (ATR), considered as well understood since decades, and experimental applications since 1969, including recent developments.

  3. Development of paints with infrared radiation reflective properties

    Directory of Open Access Journals (Sweden)

    Eliane Coser

    2015-06-01

    Full Text Available AbstractLarge buildings situated in hot regions of the Globe need to be agreeable to their residents. Air conditioning is extensively used to make these buildings comfortable, with consequent energy consumption. Absorption of solar visible and infrared radiations are responsible for heating objects on the surface of the Earth, including houses and buildings. To avoid excessive energy consumption, it is possible to use coatings formulated with special pigments that are able to reflect the radiation in the near- infrared, NIR, spectrum. To evaluate this phenomenon an experimental study about the reflectivity of paints containing infrared-reflective pigments has been made. By irradiating with an IR source and by measuring the surface temperatures of the samples we evaluated: color according to ASTM D 2244-14, UV/VIS/NIR reflectance according to ASTM E 903-12 and thermal performance. Additionally, the spectral reflectance and the IR emittance were measured and the solar reflectance of the samples were calculated. The results showed that plates coated with paints containing IR-reflecting pigments displayed lower air temperature on the opposite side as compared to conventional coatings, indicating that they can be effective to reflect NIR and decrease the temperature of buildings when used in roofs and walls.

  4. Spectral curves of surface reflectance in some Antarctic regions

    International Nuclear Information System (INIS)

    Lupi, A.; Tomasi, C.; Orsini, A.; Cacciari, A.; Vitale, V.; Georgiadis, T.; Casacchia, R.; Salvatori, R.; Salvi, S.

    2001-01-01

    Four surface reflectance models of solar radiation were determined by examining several sets of field measurements taken for clear-sky conditions at various sites in Antarctica. Each model consists of the mean spectral curve of surface reflectance in the 0.25-2.7 μm wavelength range and of the dependence curve of total abedo on the solar elevation angle h, within the range from 5 0 to 55 0 . The TNB (Terra Nova Bay) model refers to a rocky terrain where granites are predominant; the NIS (Nansen Ice Sheet) model to a glacier surface made uneven by sastrugi and streaked by irregular fractures; the HAP (High Altitude Plateau) model to a flat ice surface covered by fresh snow and scored by light sastrugi; and the RIS (Ross Ice Shelf) model to an area covered by the sea ice pack presenting many discontinuities in the reflectance features, due to melt water lakes, puddles, refrozen ice and snow pots. The reflectance curve obtained for the TNB model presents gradually increasing values as wavelength increases through the visible spectral range and almost constant values at infrared wavelengths, giving a total albedo value equal to 0.264 at = 30 0 , which increases by about 80% through the lower range of h and decreases by 12% through the upper range. The reflectance curves of the NIS, HAP and RIS models are all peaked at visible wavelengths and exhibit decreasing values throughout the infrared spectral range, giving values of total albedo equal to 0.464, 0.738 and 0.426 at h 30 0 , respectively. These values were estimated to increase by 8-14% as h decreases from 30 0 to 5 0 and to decrease by 2-4% only as h increases from 30 0 to 55 0

  5. Comparison of the bidirectional reflectance distribution function of various surfaces

    International Nuclear Information System (INIS)

    Fernandez, R.; Seasholtz, R.G.; Oberle, L.G.; Kadambi, J.R.

    1989-01-01

    This paper describes the development and use of a system to measure the bidirectional reflectance distribution function (BRDF) of various surfaces. The BRDF measurements are to be used in the analysis and design of optical measurement systems such as laser anemometers. An Ar-ion laser (514 nm) was the light source. Preliminary results are presented for eight samples: two glossy black paints, two flat black paints, black glass, sand-blasted Al, unworked Al, and a white paint. A BaSO4 white reflectance standard was used as the reference sample throughout the tests. 8 refs

  6. Reflectance variability of surface coatings reveals characteristic eigenvalue spectra

    Science.gov (United States)

    Medina, José M.; Díaz, José A.; Barros, Rui

    2012-10-01

    We have examined the trial-to-trial variability of the reflectance spectra of surface coatings containing effect pigments. Principal component analysis of reflectances was done at each detection angle separately. A method for classification of principal components is applied based on the eigenvalue spectra. It was found that the eigenvalue spectra follow characteristic power laws and depend on the detection angle. Three different subsets of principal components were examined to separate the relevant spectral features related to the pigments from other noise sources. Reconstruction of the reflectance spectra by taking only the first subset indicated that reflectance variability was higher at near-specular reflection, suggesting a correlation with the trial-to-trial deposition of effect pigments. Reconstruction by using the second subset indicates that variability was higher at short wavelengths. Finally, reconstruction by using only the third subset indicates that reflectance variability was not totally random as a function of the wavelength. The methods employed can be useful in the evaluation of color variability in industrial paint application processes.

  7. Measurement of integrated coefficients of ultracold neutron reflection from solid surfaces

    International Nuclear Information System (INIS)

    Golikov, V.V.; Kulagin, E.N.; Nikitenko, Yu.V.

    1985-01-01

    The method of measurement of the integrated coefficients of ultracold neutrons (UCN) reflection from solid surfaces is reported. A simple formula is suggested which expresses the integrated coefficients of UCN reflection from a given sample through the measured counting rate of the detector with and without strong absorber (polyethelene). The parameters are determined describing anisotropic and inhomogeneity properties of UCN reflection from Al, Mg, Pb, Zn, Mo, stainless steel, T and V are measured. The thickness of oxide layers is determined within the 5-10A accuracy limits from the experimental coefficients of UCN reflection from metals having on their surfaces the oxides with boundary velocity larger than that for the metal. It has been determined that the density of 5000 A layer of heavy ice freezed on aluminium is 0.83 +- 0.05 from the crystal ice density

  8. GLOBAL LAND COVER CLASSIFICATION USING MODIS SURFACE REFLECTANCE PROSUCTS

    Directory of Open Access Journals (Sweden)

    K. Fukue

    2016-06-01

    Full Text Available The objective of this study is to develop high accuracy land cover classification algorithm for Global scale by using multi-temporal MODIS land reflectance products. In this study, time-domain co-occurrence matrix was introduced as a classification feature which provides time-series signature of land covers. Further, the non-parametric minimum distance classifier was introduced for timedomain co-occurrence matrix, which performs multi-dimensional pattern matching for time-domain co-occurrence matrices of a classification target pixel and each classification classes. The global land cover classification experiments have been conducted by applying the proposed classification method using 46 multi-temporal(in one year SR(Surface Reflectance and NBAR(Nadir BRDF-Adjusted Reflectance products, respectively. IGBP 17 land cover categories were used in our classification experiments. As the results, SR and NBAR products showed similar classification accuracy of 99%.

  9. Unmanned aerial system nadir reflectance and MODIS nadir BRDF-adjusted surface reflectances intercompared over Greenland

    Science.gov (United States)

    Faulkner Burkhart, John; Kylling, Arve; Schaaf, Crystal B.; Wang, Zhuosen; Bogren, Wiley; Storvold, Rune; Solbø, Stian; Pedersen, Christina A.; Gerland, Sebastian

    2017-07-01

    Albedo is a fundamental parameter in earth sciences, and many analyses utilize the Moderate Resolution Imaging Spectroradiometer (MODIS) bidirectional reflectance distribution function (BRDF)/albedo (MCD43) algorithms. While derivative albedo products have been evaluated over Greenland, we present a novel, direct comparison with nadir surface reflectance collected from an unmanned aerial system (UAS). The UAS was flown from Summit, Greenland, on 210 km transects coincident with the MODIS sensor overpass on board the Aqua and Terra satellites on 5 and 6 August 2010. Clear-sky acquisitions were available from the overpasses within 2 h of the UAS flights. The UAS was equipped with upward- and downward-looking spectrometers (300-920 nm) with a spectral resolution of 10 nm, allowing for direct integration into the MODIS bands 1, 3, and 4. The data provide a unique opportunity to directly compare UAS nadir reflectance with the MODIS nadir BRDF-adjusted surface reflectance (NBAR) products. The data show UAS measurements are slightly higher than the MODIS NBARs for all bands but agree within their stated uncertainties. Differences in variability are observed as expected due to different footprints of the platforms. The UAS data demonstrate potentially large sub-pixel variability of MODIS reflectance products and the potential to explore this variability using the UAS as a platform. It is also found that, even at the low elevations flown typically by a UAS, reflectance measurements may be influenced by haze if present at and/or below the flight altitude of the UAS. This impact could explain some differences between data from the two platforms and should be considered in any use of airborne platforms.

  10. Implementation of solar-reflective surfaces: Materials and utility programs

    Energy Technology Data Exchange (ETDEWEB)

    Bretz, S.; Akbari, H.; Rosenfeld, A.; Taha, H.

    1992-06-01

    This report focuses on implementation issues for using solar-reflective surfaces to cool urban heat islands, with specific examples for Sacramento, California. Advantages of solar-reflective surfaces for reducing energy use are: (1) they are cost-effective if albedo is increased during routine maintenance; (2) the energy savings coincide with peak demand for power; (3) there are positive effects on environmental quality; and (4) the white materials have a long service life. Important considerations when choosing materials for mitigating heat islands are identified as albedo, emissivity, durability, cost, pollution and appearance. There is a potential for increasing urban albedo in Sacramento by an additional 18%. Of residential roofs, we estimate that asphalt shingle and modified bitumen cover the largest area, and that built-up roofing and modified bitumen cover the largest area of commercial buildings. For all of these roof types, albedo may be increased at the time of re-roofing without any additional cost. When a roof is repaired, a solar-reflective roof coating may be applied to significantly increase albedo and extend the life of the root Although a coating may be cost-effective if applied to a new roof following installation or to an older roof following repair, it is not cost-effective if the coating is applied only to save energy. Solar-reflective pavement may be cost-effective if the albedo change is included in the routine resurfacing schedule. Cost-effective options for producing light-colored pavement may include: (1) asphalt concrete, if white aggregate is locally available; (2) concrete overlays; and (3) newly developed white binders and aggregate. Another option may be hot-rolled asphalt, with white chippings. Utilities could promote solar-reflective surfaces through advertisement, educational programs and cost-sharing of road resurfacing.

  11. Real-time defect detection on highly reflective curved surfaces

    Science.gov (United States)

    Rosati, G.; Boschetti, G.; Biondi, A.; Rossi, A.

    2009-03-01

    This paper presents an automated defect detection system for coated plastic components for the automotive industry. This research activity came up as an evolution of a previous study which employed a non-flat mirror to illuminate and inspect high reflective curved surfaces. According to this method, the rays emitted from a light source are conveyed on the surface under investigation by means of a suitably curved mirror. After the reflection on the surface, the light rays are collected by a CCD camera, in which the coating defects appear as shadows of various shapes and dimensions. In this paper we present an evolution of the above-mentioned method, introducing a simplified mirror set-up in order to reduce the costs and the complexity of the defect detection system. In fact, a set of plane mirrors is employed instead of the curved one. Moreover, the inspection of multiple bend radius parts is investigated. A prototype of the machine vision system has been developed in order to test this simplified method. This device is made up of a light projector, a set of plane mirrors for light rays reflection, a conveyor belt for handling components, a CCD camera and a desktop PC which performs image acquisition and processing. Like in the previous system, the defects are identified as shadows inside a high brightness image. At the end of the paper, first experimental results are presented.

  12. Low cloud investigations for project FIRE: Island studies of cloud properties, surface radiation, and boundary layer dynamics. A simulation of the reflectivity over a stratocumulus cloud deck by the Monte Carlo method. M.S. Thesis Final Report

    Science.gov (United States)

    Ackerman, Thomas P.; Lin, Ruei-Fong

    1993-01-01

    The radiation field over a broken stratocumulus cloud deck is simulated by the Monte Carlo method. We conducted four experiments to investigate the main factor for the observed shortwave reflectively over the FIRE flight 2 leg 5, in which reflectivity decreases almost linearly from the cloud center to cloud edge while the cloud top height and the brightness temperature remain almost constant through out the clouds. From our results, the geometry effect, however, did not contribute significantly to what has been observed. We found that the variation of the volume extinction coefficient as a function of its relative position in the cloud affects the reflectivity efficiently. Additional check of the brightness temperature of each experiment also confirms this conclusion. The cloud microphysical data showed some interesting features. We found that the cloud droplet spectrum is nearly log-normal distributed when the clouds were solid. However, whether the shift of cloud droplet spectrum toward the larger end is not certain. The decrease of number density from cloud center to cloud edges seems to have more significant effects on the optical properties.

  13. ultrasound reflecting the morphological properties in soft tissue

    DEFF Research Database (Denmark)

    Lorentzen, Torben; Larsen, Torben; Court-Payen, Michel

    2014-01-01

    Ultrasound (US) is an image modality providing the examiner with real-time images which reflect the morphological properties in soft tissue. Different types of transducers are used for different kind of exams. US is cheap, fast, and safe. US is widely used in abdominal imaging including obstetrics...

  14. A method for the characterization of the reflectance of anisotropic functional surfaces

    DEFF Research Database (Denmark)

    Regi, Francesco; Nielsen, J B; Li, Dongya

    2018-01-01

    The functional properties of micro-structured surfaces have gained increasing interest thanks to many applications such as wetting, adhesion, thermal and/or electrical conductivity. In this study, directional optical properties, i.e. contrast between two regions of a surface, were achieved...... reflectance of the surface for a range of design-specific view-illumination configurations was determined using a method that involves a Hirox RH-2000 digital microscope, used as a gonioreflectometer. This method allows the empirical determination of the optimum surface microstructure for maximizing contrast...... between two horizontally orthogonal views. The results show that even if the uncertainty related to the instrumentation is up to 20% in some cases, this procedure is suitable for the characterization of the surface of both metal and plastic counterpart....

  15. Surface and conductivity properties of imidazoles solutions

    International Nuclear Information System (INIS)

    Rogalski, Marek; Domanska, Urszula; Czyrny, Dagmara; Dyczko, Dagmara

    2002-01-01

    The surface tension, σ, of the solutions of benzimidazole, 2-phenylimidazole and 2,4,5-triphenylimidazole in water, or water + 10 mol% of acetonitrile, or in other solvents as well as the solubilities and conductivity of benzimidazole and 2-phenylimidazole in water in function of concentration at 298.15 K were measured. The enthalpy of fusion, or solid-solid phase transition and the melting temperatures were determined for the substances under study by the scanning calorimetry (DSC). These solutions exhibit, in a wide range of concentrations, the normal linear, or parabolic decreasing dependencies and the maximum of surface tension at very low concentrations and show the S-shaped dependencies, being in function of the initial sample, never reported before. The results were confirmed by the conductivity measurements. The results were interpreted in terms of the changing structure of the interface. It was concluded that the observed phenomena were caused by an induced nucleation of benzimidazole, 2-phenylimidazole and especially by 2,4,5-triphenylimidazole by columnar discotic structures due to the initial concentration. The surface properties of these solutions reflect the interactions of hydrophobic parts of the guest molecules adsorbed at the interface, as a result of the hydrogen bonded structure of the solution

  16. Influence of Aerosols And Surface Reflectance On NO2 Retrieval Over China From 2005 to 2015

    Science.gov (United States)

    Liu, M.; Lin, J.

    2016-12-01

    Satellite observation is a powerful way to analysis annual and seasonal variations of nitrogen dioxide (NO2). However, much retrieval of vertical column densities (VCDs) of normally do not explicitly account for aerosol optical effects and surface reflectance anisotropy that vary with space and time. In traditional retrieval, aerosols' effects are often considered as cloud. However, China has complicated aerosols type and aerosol loading. Their optical properties may be very different from the cloud. Furthermore, China has undergone big changes in land use type in recent 10 years. Traditional climatology surface reflectance data may not have representation. In order to study spatial-temporal variation of and influences of these two factors on variations and trends, we use an improved retrieval method of VCDs over China, called the POMINO, based on measurements from the Ozone Monitoring Instrument (OMI), and we compare the results of without aerosol, without surface reflectance treatments and without both to the original POMINO product from 2005 to 2015. Furthermore, we will study correspondent spatial-temporal variations of aerosols, represented by MODIS aerosol optical depth (AOD) data and CALIOP extinction data; surface reflectance, represented by MODIS bidirectional reflectance distribution function (BRDF) data.

  17. Ocean color remote sensing using polarization properties of reflected sunlight

    Science.gov (United States)

    Frouin, R.; Pouliquen, E.; Breon, F.-M.

    1994-01-01

    The effects of the atmosphere and surface on sunlight backscattered to space by the ocean may be substantially reduced by using the unpolarized component of reflectance instead of total reflectance. At 450 nm, a wavelength of interest in ocean color remote sensing, and for typical conditions, 45% of the unpolarized reflectance may originate from the water body instead of 20% of the total reflectance, which represents a gain of a factor 2.2 in useful signal for water composition retrieval. The best viewing geometries are adjacent to the glitter region; they correspond to scattering angles around 100 deg, but they may change slightly depending on the polarization characteristics of the aerosols. As aerosol optical thickness increases, the atmosphere becomes less efficient at polarizing sunlight, and the enhancement of the water body contribution to unpolarized reflectance is reduced. Since the perturbing effects are smaller on unpolarized reflectance, at least for some viewing geometries, they may be more easily corrected, leading to a more accurate water-leaving signal and, therefore, more accurate estimates of phytoplankton pigment concentration.

  18. Gain-Enhanced On-Chip Antenna Utilizing Artificial Magnetic Conductor Reflecting Surface at 94 GHz

    KAUST Repository

    Nafe, Mahmoud

    2015-01-01

    In this work, the use of specially patterned reflecting surfaces for improving on- chip antenna performance is investigated. By using a periodic metallic surface on top of a grounded substrate, the structure can mimic the behavior of a perfect mag- netic conductor, hence called Artificial Magnetic Conductor (AMC) surface. Unlike conventional ground plane reflecting surfaces, AMC surfaces generally enhance the radiation and impedance characteristics of close-by antennas. Based on this property, a ring-based AMC reflecting surface has been designed in the oxide layer for on-chip antennas operating at 94 GHz. Furthermore, a folded dipole antenna with its associ- ated planar feeding structures has been optimized and integrated with the developed ring-based AMC surface. The proposed design is then fabricated at KAUST clean- room facilities. Prototype characterization showed very promising results with good correlation to simulations, with the antenna exhibiting an impedance bandwidth of 10% (90-100 GHz) and peak gain of -1.4 dBi, which is the highest gain reported for on-chip antennas at this frequency band without the use of any external o↵-chip components or post-fabrication steps.

  19. Surface reflectance of Antarctic bryophytes and protection from UV and visible light

    International Nuclear Information System (INIS)

    Robinson, S.A.; Wasley, J.; Turnbull, J.

    2000-01-01

    Full text: As well as determining the amount of solar radiation available for photosynthesis, the surface reflectance and absorptance characteristics of plants are their first defence against damaging effects of solar radiation. The solar spectrum can be damaging to plants in many ways. At shorter wavelengths, UV-B (280-320 nm) radiation can cause lesions in nucleic acid and proteins. Excess levels of visible radiation (400-750) can cause photoinhibition whilst high absorbtance of longer wavelengths (>750) leads to increases in temperature that can be detrimental in some environments. The adaptation of surface reflectance properties of vascular plants to particular environments are well known in some ecosystems. For example in desert ecosystems pubescent leaf surfaces that increase reflectance are common and have been demonstrated to be important to protection from photoinhibition. The epidermal characteristics of some plants are also known to change in absorptance, due to the accumulation of specific compounds. For example flavonoids which are effective screens against UV-B radiation, increase upon exposure to UV-B radiation. In this study we surveyed the natural variability in surface reflectance in mosses growing in continental Antarctica. Antarctica is experiencing large increases in incident UV-B radiation due to reductions in concentrations of stratospheric ozone. Additionally over the summer months (November January), when moss is exposed to direct sunlight, levels of visible solar radiation are also high, increasing the likelihood of photoinhibitory damage in moss. Our aim in this study is to describe the natural variability in the surface reflectance characteristics of moss, such that we have a baseline with which to assess future changes in response to changes in global climate, and imposed experimental treatments, and also to develop hypotheses with respect to how mosses have adapted to the cold and arid antarctic environment. Variability in surface

  20. Micro reflectance difference techniques: Optical probes for surface exploration

    Energy Technology Data Exchange (ETDEWEB)

    Lastras-Martinez, L.F.; Del Pozo-Zamudio, O.; Herrera-Jasso, R.; Ulloa-Castillo, N.A.; Balderas-Navarro, R.E.; Ortega-Gallegos, J.; Lastras-Martinez, A. [Instituto de Investigacion en Comunicacion Optica, Universidad Autonoma de San Luis Potosi, Alvaro Obregon 64, 78000 San Luis Potosi, S.L.P. (Mexico)

    2012-06-15

    Micro reflectance difference spectroscopy ({mu}-RDS) is a promising tool for the in-situ and ex-situ characterization of semiconductors surfaces and interfaces. We discuss and compare two different approaches used to measure {mu}-RD spectra. One is based on a charge-coupled device (CCD) camera, while the other uses a laser and a XY translation stage. To show the performance of these systems, we have measured surface optical anisotropies of GaSb(001) sample on which anisotropic strains have been generated by preferential mechanical polishing along [110] and [1 anti 10] directions. The spectrometers are complementary and the selection of one of them depends on the sample to be investigated and on experimental conditions. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  1. Scaling properties of optical reflectance from quasi-periodic superlattices

    International Nuclear Information System (INIS)

    Wu Xiang; Yao Hesheng; Feng Weiguo

    1991-08-01

    The scaling properties of the optical reflectance from two types of quasi-periodic metal-insulator superlattices, one with the structure of Cantor bars and the other with the structure of Cantorian-Fibonaccian train, have been studied for the region of s-polarized soft x-rays and extreme ultraviolet. By using the hydrodynamic model of electron dynamics and transfer-matrix method, and be taking into account retardation effects, we have presented the formalism of the reflectivity for the superlattices. From our numerical results, we found that the reflection spectra of the quasi-superlattices have a rich structure of self-similarity. The interesting scaling indices, which are related to the fractal dimensions, of the spectra are also discussed for the two kinds of the quasi-superlattices. (author). 10 refs, 7 figs

  2. Improved broadband and quasi-omnidirectional anti-reflection properties with biomimetic silicon nanostructures.

    Science.gov (United States)

    Huang, Yi-Fan; Chattopadhyay, Surojit; Jen, Yi-Jun; Peng, Cheng-Yu; Liu, Tze-An; Hsu, Yu-Kuei; Pan, Ci-Ling; Lo, Hung-Chun; Hsu, Chih-Hsun; Chang, Yuan-Huei; Lee, Chih-Shan; Chen, Kuei-Hsien; Chen, Li-Chyong

    2007-12-01

    Nature routinely produces nanostructured surfaces with useful properties, such as the self-cleaning lotus leaf, the colour of the butterfly wing, the photoreceptor in brittlestar and the anti-reflection observed in the moth eye. Scientists and engineers have been able to mimic some of these natural structures in the laboratory and in real-world applications. Here, we report a simple aperiodic array of silicon nanotips on a 6-inch wafer with a sub-wavelength structure that can suppress the reflection of light at a range of wavelengths from the ultraviolet, through the visible part of the spectrum, to the terahertz region. Reflection is suppressed for a wide range of angles of incidence and for both s- and p-polarized light. The antireflection properties of the silicon result from changes in the refractive index caused by variations in the height of the silicon nanotips, and can be simulated with models that have been used to explain the low reflection from moth eyes. The improved anti-reflection properties of the surfaces could have applications in renewable energy and electro-optical devices for the military.

  3. Surface 3-D reflection seismics - implementation at the Olkiluoto site

    Energy Technology Data Exchange (ETDEWEB)

    Saksa, P.; Lehtimaeki, T.; Heikkinen, E. [Poeyry Environment Oy, Vantaa (Finland)

    2007-03-15

    Posiva Oy takes care of the final disposal of spent nuclear fuel in Finland. In year 2001 Olkiluoto was selected for the site of final disposal. Construction of the underground research facility, ONKALO, is going on at the Olkiluoto site. The aim of this work was to study the possibilities for surface 3-D seismics and to review experiences for design before field work. The physical parameters and geometric properties of the site, as well as efficient survey layout and source arrangements, were considered in this work. Reflection seismics is most used geophysical investigation method in oil exploration and earth studies in sedimentary environment. Recently method has also been applied in crystalline bedrock for ore exploration and nuclear waste disposal site investigations. The advantage of the method is high accuracy combined with large depth of investigation. The principles of seismic 2-D and 3-D soundings are well known and advanced. 3-D sounding is a straightforward expansion of 2-D line based surveying. In investigation of crystalline bedrock, the high frequency wave sources and receivers, their right use in measurements and careful processing procedure (refraction static corrections in particular) are important. Using the site parameters in 2-D numerical modeling, two cases of faulted thin layer at depths of 200, 400 and 600 meters were studied. The first case was a layer with vertical dislocation (a ramp) and the other a layer having limited width of dislocated part. Central frequencies were 100, 200, 400 and 700 Hz. Results indicate that 10 - 20 m dislocation is recognizable, but for depths greater than 600 m, over 20 meters is required. Width of the dislocated part will affect the detectability of vertical displacement. At depths of 200 m and 400 m 10 - 50 m wide parts appear as point-like scatterers, wider areas have more continuity. Dislocations larger than 20 m can be seen. From depth of 600 m over 100 m wide parts are discernible, narrower are visible

  4. Surface 3-D reflection seismics - implementation at the Olkiluoto site

    International Nuclear Information System (INIS)

    Saksa, P.; Lehtimaeki, T.; Heikkinen, E.

    2007-03-01

    Posiva Oy takes care of the final disposal of spent nuclear fuel in Finland. In year 2001 Olkiluoto was selected for the site of final disposal. Construction of the underground research facility, ONKALO, is going on at the Olkiluoto site. The aim of this work was to study the possibilities for surface 3-D seismics and to review experiences for design before field work. The physical parameters and geometric properties of the site, as well as efficient survey layout and source arrangements, were considered in this work. Reflection seismics is most used geophysical investigation method in oil exploration and earth studies in sedimentary environment. Recently method has also been applied in crystalline bedrock for ore exploration and nuclear waste disposal site investigations. The advantage of the method is high accuracy combined with large depth of investigation. The principles of seismic 2-D and 3-D soundings are well known and advanced. 3-D sounding is a straightforward expansion of 2-D line based surveying. In investigation of crystalline bedrock, the high frequency wave sources and receivers, their right use in measurements and careful processing procedure (refraction static corrections in particular) are important. Using the site parameters in 2-D numerical modeling, two cases of faulted thin layer at depths of 200, 400 and 600 meters were studied. The first case was a layer with vertical dislocation (a ramp) and the other a layer having limited width of dislocated part. Central frequencies were 100, 200, 400 and 700 Hz. Results indicate that 10 - 20 m dislocation is recognizable, but for depths greater than 600 m, over 20 meters is required. Width of the dislocated part will affect the detectability of vertical displacement. At depths of 200 m and 400 m 10 - 50 m wide parts appear as point-like scatterers, wider areas have more continuity. Dislocations larger than 20 m can be seen. From depth of 600 m over 100 m wide parts are discernible, narrower are visible

  5. Temperature dependence of nuclear surface properties

    International Nuclear Information System (INIS)

    Campi, X.; Stringari, S.

    1982-01-01

    Thermal properties of nuclear surface are investigated in a semi-infinite medium. Explicit analytical expression are given for the temperature dependence of surface thickness, surface energy and surface free energy. In this model the temperature effects depend critically on the nuclear incompressibility and on the shape of the effective mass at the surface. To illustrate the relevance of these effects we made an estimate of the temperature dependence of the fission barrier height. (orig.)

  6. Modeling and analysis of surface roughness effects on sputtering, reflection, and sputtered particle transport

    International Nuclear Information System (INIS)

    Brooks, J.N.; Ruzic, D.N.

    1990-01-01

    The microstructure of the redeposited surface in tokamaks may affect sputtering and reflection properties and subsequent particle transport. This subject has been studied numerically using coupled models/codes for near-surface plasma particle kinetic transport (WBC code) and rough surface sputtering (fractal-TRIM). The coupled codes provide an overall Monte Carlo calculation of the sputtering cascade resulting from an initial flux of hydrogen ions. Beryllium, carbon, and tungsten surfaces are analyzed for typical high recycling, oblique magnetic field, divertor conditions. Significant variations in computed sputtering rates are found with surface roughness. Beryllium exhibits high D-T and self-sputtering coefficients for the plasma regime studied (T e = 30-75 eV). Carbon and tungsten sputtering is significantly lower. 9 refs., 6 figs., 1 tab

  7. Diffuse Reflectance Spectroscopy for Surface Measurement of Liver Pathology.

    Science.gov (United States)

    Nilsson, Jan H; Reistad, Nina; Brange, Hannes; Öberg, Carl-Fredrik; Sturesson, Christian

    2017-01-01

    Liver parenchymal injuries such as steatosis, steatohepatitis, fibrosis, and sinusoidal obstruction syndrome can lead to increased morbidity and liver failure after liver resection. Diffuse reflectance spectroscopy (DRS) is an optical measuring method that is fast, convenient, and established. DRS has previously been used on the liver with an invasive technique consisting of a needle that is inserted into the parenchyma. We developed a DRS system with a hand-held probe that is applied to the liver surface. In this study, we investigated the impact of the liver capsule on DRS measurements and whether liver surface measurements are representative of the whole liver. We also wanted to confirm that we could discriminate between tumor and liver parenchyma by DRS. The instrumentation setup consisted of a light source, a fiber-optic contact probe, and two spectrometers connected to a computer. Patients scheduled for liver resection due to hepatic malignancy were included, and DRS measurements were performed on the excised liver part with and without the liver capsule and alongside a newly cut surface. To estimate the scattering parameters and tissue chromophore volume fractions, including blood, bile, and fat, the measured diffuse reflectance spectra were applied to an analytical model. In total, 960 DRS spectra from the excised liver tissue of 18 patients were analyzed. All factors analyzed regarding tumor versus liver tissue were significantly different. When measuring through the capsule, the blood volume fraction was found to be 8.4 ± 3.5%, the lipid volume fraction was 9.9 ± 4.7%, and the bile volume fraction was 8.2 ± 4.6%. No differences could be found between surface measurements and cross-sectional measurements. In measurements with/without the liver capsule, the differences in volume fraction were 1.63% (0.75-2.77), -0.54% (-2.97 to 0.32), and -0.15% (-1.06 to 1.24) for blood, lipid, and bile, respectively. This study shows that it is possible to manage DRS

  8. Absorption and reflectivity of the lithium niobate surface masked with a graphene layer

    Directory of Open Access Journals (Sweden)

    O. Salas

    2017-01-01

    Full Text Available We performed simulations of the interaction of a graphene layer with the surface of lithium niobate utilizing density functional theory and molecular dynamics at 300K and atmospheric pressure. We found that the graphene layer is physisorbed on the lithium niobate surface with an adsorption energy of -0.8205 eV/(carbon-atom. Subsequently, the energy band structure, the optical absorption and reflectivity of the new system were calculated. We found important changes in these physical properties with respect to the corresponding ones of a graphene layer and of a lithium niobate crystal.

  9. Studies of dust grain properties in infrared reflection nebulae.

    Science.gov (United States)

    Pendleton, Y J; Tielens, A G; Werner, M W

    1990-01-20

    We have developed a model for reflection nebulae around luminous infrared sources embedded in dense dust clouds. The aim of this study is to determine the sizes of the scattering grains. In our analysis, we have adopted an MRN-like power-law size distribution (Mathis, Rumpl, and Nordsieck) of graphite and silicate grains, but other current dust models would give results which were substantially the same. In the optically thin limit, the intensity of the scattered light is proportional to the dust column density, while in the optically thick limit, it reflects the grain albedo. The results show that the shape of the infrared spectrum is the result of a combination of the scattering properties of the dust, the spectrum of the illuminating source, and foreground extinction, while geometry plays a minor role. Comparison of our model results with infrared observations of the reflection nebula surrounding OMC-2/IRS 1 shows that either a grain size distribution like that found in the diffuse interstellar medium, or one consisting of larger grains, can explain the observed shape of the spectrum. However, the absolute intensity level of the scattered light, as well as the observed polarization, requires large grains (approximately 5000 angstroms). By adding water ice mantles to the silicate and graphite cores, we have modeled the 3.08 micrometers ice band feature, which has been observed in the spectra of several infrared reflection nebulae. We show that this ice band arises naturally in optically thick reflection nebulae containing ice-coated grains. We show that the shape of the ice band is diagnostic of the presence of large grains, as previously suggested by Knacke and McCorkle. Comparison with observations of the BN/KL reflection nebula in the OMC-1 cloud shows that large ice grains (approximately 5000 angstroms) contribute substantially to the scattered light.

  10. Lunar surface engineering properties experiment definition

    Science.gov (United States)

    Mitchell, J. K.; Goodman, R. E.; Hurlbut, F. C.; Houston, W. N.; Willis, D. R.; Witherspoon, P. A.; Hovland, H. J.

    1971-01-01

    Research on the mechanics of lunar soils and on developing probes to determine the properties of lunar surface materials is summarized. The areas of investigation include the following: soil simulation, soil property determination using an impact penetrometer, soil stabilization using urethane foam or phenolic resin, effects of rolling boulders down lunar slopes, design of borehole jack and its use in determining failure mechanisms and properties of rocks, and development of a permeability probe for measuring fluid flow through porous lunar surface materials.

  11. IRAS surface brightness maps of reflection nebulae in the Pleiades

    Science.gov (United States)

    Castelaz, Michael W.; Werner, M. W.; Sellgren, K.

    1987-01-01

    Surface brightness maps at 12, 25, 60, and 100 microns were made of a 2.5 deg x 2.5 deg area of the reflection nebulae in the Pleiades by coadding IRAS scans of this region. Emission is seen surrounding 17 Tau, 20 Tau, 23 Tau, and 25 Tau in all four bands, coextensive with the visible reflection nebulosity, and extending as far as 30 arcminutes from the illuminating stars. The infrared energy distributions of the nebulae peak in the 100 micron band, but up to 40 percent of the total infrared power lies in the 12 and 25 micron bands. The brightness of the 12 and 25 micron emission and the absence of temperature gradients at these wavelengths are inconsistent with the predictions of equilibrium thermal emission models. The emission at these wavelengths appears to be the result of micron nonequilibrium emission from very small grains, or from molecules consisting of 10-100 carbon atoms, which have been excited by ultraviolet radiation from the illuminating stars.

  12. X-Ray Reflectivity from the Surface of a Liquid Crystal:

    DEFF Research Database (Denmark)

    Pershan, P.S.; Als-Nielsen, Jens Aage

    1984-01-01

    X-ray reflectivity from the surface of a nematic liquid crystal is interpreted as the coherent superposition of Fresnel reflection from the surface and Bragg reflection from smectic order induced by the surface. Angular dependence of the Fresnel effect yields information on surface structure....... Measurement of the intensity of diffuse critical scattering relative to the Fresnel reflection yields the absolute value of the critical part of the density-density correlation function....

  13. Properties Of Reflection Holograms Recorded In Polaroid's DMP-128 Photopolymer

    Science.gov (United States)

    Ingwall, R. T.; Troll, M.; Vetterling, W. T.

    1987-06-01

    Optical and microstructural properties of reflection holograms recorded in DMP-128 are reported. The optical properties are determined from transmission spectra of the holograms by ignoring the relatively small effects of light scattering and absorption. Microstructure is revealed by light and electron microscopic examination of hologram sections prepared either by diamond grit abrasion or by freeze fracture. Fringe planes are clearly seen with both sectioning procedures. The spacing between adjacent planes is strongly affected by processing conditions. Standard processing produces reflection holograms with fringe plane spacing that decreases continuously from the film:substrate interface to the film:air interface. These holograms have wide spectral bandwidths (100-200nm) and irregular band shapes. Narrow bandwidth holograms are produced from slightly more complicated processing steps. The optical properties of both types of holograms are compared to a theoretical model developed to account for nonuniform fringe plane spacing. Important experimental features such as spectral bandwidth and diffraction efficiency are readily explained by the theory and the observed microstructure.

  14. Improving Image Matching by Reducing Surface Reflections Using Polarising Filter Techniques

    Science.gov (United States)

    Conen, N.; Hastedt, H.; Kahmen, O.; Luhmann, T.

    2018-05-01

    In dense stereo matching applications surface reflections may lead to incorrect measurements and blunders in the resulting point cloud. To overcome the problem of disturbing reflexions polarising filters can be mounted on the camera lens and light source. Reflections in the images can be suppressed by crossing the polarising direction of the filters leading to homogeneous illuminated images and better matching results. However, the filter may influence the camera's orientation parameters as well as the measuring accuracy. To quantify these effects, a calibration and an accuracy analysis is conducted within a spatial test arrangement according to the German guideline VDI/VDE 2634.1 (2002) using a DSLR with and without polarising filter. In a second test, the interior orientation is analysed in more detail. The results do not show significant changes of the measuring accuracy in object space and only very small changes of the interior orientation (Δc ≤ 4 μm) with the polarising filter in use. Since in medical applications many tiny reflections are present and impede robust surface measurements, a prototypic trinocular endoscope is equipped with polarising technique. The interior and relative orientation is determined and analysed. The advantage of the polarising technique for medical image matching is shown in an experiment with a moistened pig kidney. The accuracy and completeness of the resulting point cloud can be improved clearly when using polarising filters. Furthermore, an accuracy analysis using a laser triangulation system is performed and the special reflection properties of metallic surfaces are presented.

  15. Directional radiative properties of anisotropic rough silicon and gold surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Lee, H.J.; Chen, Y.B.; Zhang, Z.M. [George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, GA 30332 (United States)

    2006-11-15

    Recent studies have shown that the topography of some chemically etched microrough silicon surfaces is non-Gaussian and may be strongly anisotropic. However, the bidirectional reflectance distribution function (BRDF) of anisotropic surfaces has not been fully understood. The present study uses the Monte Carlo method to investigate the out-of-plane BRDF, multiple scattering, and the change of the polarization state upon reflection. Two ray-tracing algorithms are developed that incorporate the surface topography or slope distribution of the samples obtained by the use of an atomic force microscope. The predicted BRDFs for silicon surfaces with or without a gold coating are in reasonable agreement with the results measured using a laser scatterometer at a wavelength of 635nm. The employment of surface topographic data is indispensable to the BRDF modeling of anisotropic surfaces. While first-order scattering makes the dominant contribution to reflections from the studied surfaces, it is critical to consider the polarization state change in order to correctly predict the out-of-plane BRDF. The versatile Monte Carlo modeling tools developed through the present study help gain a better understanding of the directional radiative properties of microrough surfaces and, furthermore, will have an impact on thermal metrology in the semiconductor industry. (author)

  16. Surface active monomers synthesis, properties, and application

    CERN Document Server

    Borzenkov, Mykola

    2014-01-01

    This brief includes information on the background?of and development of synthesis of various types of surface active monomers. The authors explain the importance of utilization of surface active monomers for creation of surface active polymers? and the various biomedical applications of such compounds . This brief introduces techniques for the synthesis of novel types of surface active monomers, their colloidal and polymerizable properties and application for needs of medicine and biology.

  17. Quantification of the optical surface reflection and surface roughness of articular cartilage using optical coherence tomography

    Energy Technology Data Exchange (ETDEWEB)

    Saarakkala, Simo; Wang Shuzhe; Huang Yanping; Zheng Yongping [Department of Health Technology and Informatics, Hong Kong Polytechnic University, Hong Kong (China)], E-mail: simo.saarakkala@uku.fi, E-mail: ypzheng@ieee.org

    2009-11-21

    Optical coherence tomography (OCT) is a promising new technique for characterizing the structural changes of articular cartilage in osteoarthritis (OA). The calculation of quantitative parameters from the OCT signal is an important step to develop OCT as an effective diagnostic technique. In this study, two novel parameters for the quantification of optical surface reflection and surface roughness from OCT measurements are introduced: optical surface reflection coefficient (ORC), describing the amount of a ratio of the optical reflection from cartilage surface with respect to that from a reference material, and OCT roughness index (ORI) indicating the smoothness of the cartilage surface. The sensitivity of ORC and ORI to detect changes in bovine articular cartilage samples after enzymatic degradations of collagen and proteoglycans using collagenase and trypsin enzymes, respectively, was tested in vitro. A significant decrease (p < 0.001) in ORC as well as a significant increase (p < 0.001) in ORI was observed after collagenase digestion. After trypsin digestion, no significant changes in ORC or ORI were observed. To conclude, the new parameters introduced were demonstrated to be feasible and sensitive to detect typical OA-like degenerative changes in the collagen network. From the clinical point of view, the quantification of OCT measurements is of great interest since OCT probes have been already miniaturized and applied in patient studies during arthroscopy or open knee surgery in vivo. Further studies are still necessary to demonstrate the clinical capability of the introduced parameters for naturally occurring early OA changes in the cartilage.

  18. Bi-directional Reflectance of Icy Surface Analogs: A Dual Approach

    Science.gov (United States)

    Quinones, Juan Manuel; Vides, Christina; Nelson, Robert M.; Boryta, Mark; Mannat, Ken s.

    2018-01-01

    Bi-directional reflectance measurements of analogs for planetary regolith have provided insight into the surface properties of planetary satellites and small bodies. Because Aluminum Oxide (Al2O3) and water ice share a similar hexagonal crystalline structure, the former has been used in laboratory experiments to simulate the regolith of both icy and dusty planetary bodies. By measuring various sizes of well sorted size fractions of Al2O3, the reflectance phase curve and porosity of a planetary regolith can be determined. We have designed an experiment to test the laboratory measurements produced by Nelson et al. (2000). Additionally, we made reflectance measurements for other alkali-halide compounds that could be used for applications beyond astronomy and planetary science.In order to provide an independent check on the Nelson et al. data, we designed an instrument with a different configuration. While both instruments take bidirectional reflectance measurements, our instrument, the Rigid Photometric Goniometer (RPG), is fixed at a phase angle of 5° and detects the scattered light with a photomultiplier tube (PMT). The PMT current is then measured with an electrometer. Following the example of Nelson et al., we measured the bidirectional reflectance of Al2O3 particulate size fractions between 0.1sizes from 20size that provided optimal, or maximum, reflectance for each compound. Our conclusions bring confirmation and clarity to photometric sciences.

  19. Surface composition and surface properties of water hyacinth ...

    African Journals Online (AJOL)

    Surface composition and surface properties of water hyacinth ( Eichhornia ... (2/1, v/v) followed by ethanol, using Fourier Transform Infra-red (FT-IR) spectroscopy, ... polar organic solvents and non-polar n-alkane hydrocarbons is discussed.

  20. The unusual properties of beryllium surfaces

    International Nuclear Information System (INIS)

    Stumpf, R.; Hannon, J.B.

    1994-01-01

    Be is a ''marginal metal.'' The stable phase, hcp-Be, has a low Fermi-level density of states and very anisotropic structural and elastic properties, similar to a semiconductor's. At the Be(0001) surface, surface states drastically increase the Fermi-level density of states. The different nature of bonding in bulk-Be and at the Be(0001) surface explains the large outward relaxation. The presence of surface states causes large surface core-level shifts by inducing a higher electrostatic potential in the surface layers and by improving the screening at the surface. The authors experimental and theoretical investigations of atomic vibrations at the Be(0001) surface demonstrate clearly that Be screening of atomic motion by the surface states makes the surface phonon dispersion fundamentally different from that of the bulk. Properties of Be(0001) are so different from those of the bulk that the surface can be considered a new ''phase'' of beryllium with unique electronic and structural characteristics. For comparison they also study Be(11 bar 20), a very open surface without important surface states. Be(11 bar 20) is the only clean s-p metal surface known to reconstruct (1 x 3 missing row reconstruction)

  1. Characterizing Land Surface Anisotropic Reflectance over Rugged Terrain: A Review of Concepts and Recent Developments

    Directory of Open Access Journals (Sweden)

    Jianguang Wen

    2018-02-01

    Full Text Available Rugged terrain, including mountains, hills, and some high lands are typical land surfaces around the world. As a physical parameter for characterizing the anisotropic reflectance of the land surface, the importance of the bidirectional reflectance distribution function (BRDF has been gradually recognized in the remote sensing community, and great efforts have been dedicated to build BRDF models over various terrain types. However, on rugged terrain, the topography intensely affects the shape and magnitude of the BRDF and creates challenges in modeling the BRDF. In this paper, after a brief introduction of the theoretical background of the BRDF over rugged terrain, the status of estimating land surface BRDF properties over rugged terrain is comprehensively reviewed from a historical perspective and summarized in two categories: BRDFs describing solo slopes and those describing composite slopes. The discussion focuses on land surface reflectance retrieval over mountainous areas, the difference in solo slope and composite slope BRDF models, and suggested future research to improve the accuracy of BRDFs derived with remote sensing satellites.

  2. Dielectric properties of lunar surface

    Science.gov (United States)

    Yushkova, O. V.; Kibardina, I. N.

    2017-03-01

    Measurements of the dielectric characteristics of lunar soil samples are analyzed in the context of dielectric theory. It has been shown that the real component of the dielectric permittivity and the loss tangent of rocks greatly depend on the frequency of the interacting electromagnetic field and the soil temperature. It follows from the analysis that one should take into account diurnal variations in the lunar surface temperature when interpreting the radar-sounding results, especially for the gigahertz radio range.

  3. Defined wetting properties of optical surfaces

    Science.gov (United States)

    Felde, Nadja; Coriand, Luisa; Schröder, Sven; Duparré, Angela; Tünnermann, Andreas

    2017-10-01

    Optical surfaces equipped with specific functional properties have attracted increasing importance over the last decades. In the light of cost reduction, hydrophobic self-cleaning behavior is aspired. On the other side, hydrophilic properties are interesting due to their anti-fog effect. It has become well known that such wetting states are significantly affected by the surface morphology. For optical surfaces, however, this fact poses a problem, as surface roughness can induce light scattering. The generation of optical surfaces with specific wetting properties, hence, requires a profound understanding of the relation between the wetting and the structural surface properties. Thus, our work concentrates on a reliable acquisition of roughness data over a wide spatial frequency range as well as on the comprehensive description of the wetting states, which is needed for the establishment of such correlations. We will present our advanced wetting analysis for nanorough optical surfaces, extended by a vibration-based procedure, which is mainly for understanding and tailoring the wetting behavior of various solid-liquid systems in research and industry. Utilizing the relationships between surface roughness and wetting, it will be demonstrated how different wetting states for hydrophobicity and hydrophilicity can be realized on optical surfaces with minimized scatter losses.

  4. Metrology and properties of engineering surfaces

    CERN Document Server

    Greenwood, J; Chetwynd, D

    2001-01-01

    Metrology and Properties of Engineering Surfaces provides in a single volume a comprehensive and authoritative treatment of the crucial topics involved in the metrology and properties of engineering surfaces. The subject matter is a central issue in manufacturing technology, since the quality and reliability of manufactured components depend greatly upon the selection and qualities of the appropriate materials as ascertained through measurement. The book can in broad terms be split into two parts; the first deals with the metrology of engineering surfaces and covers the important issues relating to the measurement and characterization of surfaces in both two and three dimensions. This covers topics such as filtering, power spectral densities, autocorrelation functions and the use of Fractals in topography. A significant proportion is dedicated to the calibration of scanning probe microscopes using the latest techniques. The remainder of the book deals with the properties of engineering surfaces and covers a w...

  5. Landsat surface reflectance quality assurance extraction (version 1.7)

    Science.gov (United States)

    Jones, J.W.; Starbuck, M.J.; Jenkerson, Calli B.

    2013-01-01

    The U.S. Geological Survey (USGS) Land Remote Sensing Program is developing an operational capability to produce Climate Data Records (CDRs) and Essential Climate Variables (ECVs) from the Landsat Archive to support a wide variety of science and resource management activities from regional to global scale. The USGS Earth Resources Observation and Science (EROS) Center is charged with prototyping systems and software to generate these high-level data products. Various USGS Geographic Science Centers are charged with particular ECV algorithm development and (or) selection as well as the evaluation and application demonstration of various USGS CDRs and ECVs. Because it is a foundation for many other ECVs, the first CDR in development is the Landsat Surface Reflectance Product (LSRP). The LSRP incorporates data quality information in a bit-packed structure that is not readily accessible without postprocessing services performed by the user. This document describes two general methods of LSRP quality-data extraction for use in image processing systems. Helpful hints for the installation and use of software originally developed for manipulation of Hierarchical Data Format (HDF) produced through the National Aeronautics and Space Administration (NASA) Earth Observing System are first provided for users who wish to extract quality data into separate HDF files. Next, steps follow to incorporate these extracted data into an image processing system. Finally, an alternative example is illustrated in which the data are extracted within a particular image processing system.

  6. Variability of Surface Reflection Amplitudes of GPR Horn Antenna Depending on Distance between Antenna and Surface

    Directory of Open Access Journals (Sweden)

    Komačka Jozef

    2016-05-01

    Full Text Available The study focused on variability of surface reflections amplitudes of GPR horn antenna in relation to distance between an antenna and a surface is presented in the paper. The air-coupled antenna with the central frequency of 1 GHz was used in the investigation. Four types of surfaces (dry pavement, wet pavement, metal plate and composite layer from gypsum and wood were tested. The distance of antenna above the surfaces was changed in the range from 37.5 cm to 53.5 cm. The amplitudes of negative and positive peaks and their variability were analysed in relation to the distance of antenna above the surfaces. Moreover, the influence of changes in the peaks of negative and positive amplitudes on the total amplitudes was assessed. It was found out the amplitudes of negative peaks for all investigated surfaces were relatively consistent in the range from 40.5 cm to 48.5 cm and the moderate decline was identified in the case of amplitudes of positive peaks in the range of distances from 37.5 cm to 51.5 cm. This decline influences the tendency of total amplitudes. Based on the results of analysis it can be stated the distance of air-coupled antenna above the surface can influence the value of total amplitude and the differences depend on the type of surface.

  7. The Effect of Non-Lambertian Surface Reflectance on Aerosol Radiative Forcing

    Energy Technology Data Exchange (ETDEWEB)

    Ricchiazzi, P.; O' Hirok, W.; Gautier, C.

    2005-03-18

    Surface reflectance is an important factor in determining the strength of aerosol radiative forcing. Previous studies of radiative forcing assumed that the reflected surface radiance is isotropic and does not depend on incident illumination angle. This Lambertian reflection model is not a very good descriptor of reflectance from real land and ocean surfaces. In this study we present computational results for the seasonal average of short and long wave aerosol radiative forcing at the top of the atmosphere and at the surface. The effect of the Lambertian assumption is found through comparison with calculations using a more detailed bi-direction reflectance distribution function (BRDF).

  8. Spectral reflectance properties of iridescent pierid butterfly wings.

    Science.gov (United States)

    Wilts, Bodo D; Pirih, Primož; Stavenga, Doekele G

    2011-06-01

    The wings of most pierid butterflies exhibit a main, pigmentary colouration: white, yellow or orange. The males of many species have in restricted areas of the wing upper sides a distinct structural colouration, which is created by stacks of lamellae in the ridges of the wing scales, resulting in iridescence. The amplitude of the reflectance is proportional to the number of lamellae in the ridge stacks. The angle-dependent peak wavelength of the observed iridescence is in agreement with classical multilayer theory. The iridescence is virtually always in the ultraviolet wavelength range, but some species have a blue-peaking iridescence. The spectral properties of the pigmentary and structural colourations are presumably tuned to the spectral sensitivities of the butterflies' photoreceptors.

  9. GPS Multipath Fade Measurements to Determine L-Band Ground Reflectivity Properties

    Science.gov (United States)

    Kavak, Adnan; Xu, Guang-Han; Vogel, Wolfhard J.

    1996-01-01

    In personal satellite communications, especially when the line-of-sight is clear, ground specular reflected signals along with direct signals are received by low gain, almost omni-directional subscriber antennas. A six-channel, C/A code processing, GPS receiver with an almost omni-directional patch antenna was used to take measurements over three types of ground to characterize 1.575 GHz specular ground reflections and ground dielectric properties. Fade measurements were taken over grass, asphalt, and lake water surfaces by placing the antenna in a vertical position at a fixed height from the ground. Electrical characteristics (conductivity and dielectric constant) of these surfaces (grass, asphalt, lake water) were obtained by matching computer simulations to the experimental results.

  10. Excimer laser surface modification: Process and properties

    Energy Technology Data Exchange (ETDEWEB)

    Jervis, T.R.; Nastasi, M. [Los Alamos National Lab., NM (United States); Hirvonen, J.P. [Technical Research Institute, Espoo (Finland). Metallurgy Lab.

    1992-12-01

    Surface modification can improve materials for structural, tribological, and corrosion applications. Excimer laser light has been shown to provide a rapid means of modifying surfaces through heat treating, surface zone refining, and mixing. Laser pulses at modest power levels can easily melt the surfaces of many materials. Mixing within the molten layer or with the gas ambient may occur, if thermodynamically allowed, followed by rapid solidification. The high temperatures allow the system to overcome kinetic barriers found in some ion mixing experiments. Alternatively, surface zone refinement may result from repeated melting-solidification cycles. Ultraviolet laser light couples energy efficiently to the surface of metallic and ceramic materials. The nature of the modification that follows depends on the properties of the surface and substrate materials. Alloying from both gas and predeposited layer sources has been observed in metals, semiconductors, and ceramics as has surface enrichment of Cr by zone refinement of stainless steel. Rapid solidification after melting often results in the formation of nonequilibrium phases, including amorphous materials. Improved surface properties, including tribology and corrosion resistance, are observed in these materials.

  11. IMPROVING IMAGE MATCHING BY REDUCING SURFACE REFLECTIONS USING POLARISING FILTER TECHNIQUES

    Directory of Open Access Journals (Sweden)

    N. Conen

    2018-05-01

    Full Text Available In dense stereo matching applications surface reflections may lead to incorrect measurements and blunders in the resulting point cloud. To overcome the problem of disturbing reflexions polarising filters can be mounted on the camera lens and light source. Reflections in the images can be suppressed by crossing the polarising direction of the filters leading to homogeneous illuminated images and better matching results. However, the filter may influence the camera’s orientation parameters as well as the measuring accuracy. To quantify these effects, a calibration and an accuracy analysis is conducted within a spatial test arrangement according to the German guideline VDI/VDE 2634.1 (2002 using a DSLR with and without polarising filter. In a second test, the interior orientation is analysed in more detail. The results do not show significant changes of the measuring accuracy in object space and only very small changes of the interior orientation (Δc ≤ 4 μm with the polarising filter in use. Since in medical applications many tiny reflections are present and impede robust surface measurements, a prototypic trinocular endoscope is equipped with polarising technique. The interior and relative orientation is determined and analysed. The advantage of the polarising technique for medical image matching is shown in an experiment with a moistened pig kidney. The accuracy and completeness of the resulting point cloud can be improved clearly when using polarising filters. Furthermore, an accuracy analysis using a laser triangulation system is performed and the special reflection properties of metallic surfaces are presented.

  12. Surface Compositional Units on Mercury from Spectral Reflectance at Ultraviolet to Near-infrared Wavelengths

    Science.gov (United States)

    Izenberg, N. R.; Holsclaw, G. M.; Domingue, D. L.; McClintock, W. E.; Klima, R. L.; Blewett, D. T.; Helbert, J.; Head, J. W.; Sprague, A. L.; Vilas, F.; Solomon, S. C.

    2012-12-01

    The Mercury Atmospheric and Surface Composition Spectrometer (MASCS) on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft has been acquiring reflectance spectra of Mercury's surface for over 16 months. The Visible and Infrared Spectrograph (VIRS) component of MASCS has accumulated a global data set of more than 2 million spectra over the wavelength range 300-1450 nm. We have derived a set of VIRS spectral units (VSUs) from the following spectral parameters: visible brightness (R575: reflectance at 575 nm); visible/near-infrared reflectance ratio (VISr: reflectance at 415 nm to that at 750 nm); and ultraviolet reflectance ratio (UVr: reflectance at 310 nm to that at 390 nm). Five broad, slightly overlapping VSUs may be distinguished from these parameters. "Average VSU" areas have spectral parameters close to mean global values. "Dark blue VSU" areas have spectra with low R575 and high UVr. "Red VSU" areas have spectra with low UVr and higher VISr and R575 than average. "Intermediate VSU" areas have spectra with higher VISr than VSU red, generally higher R575, and a wide range of UVr. "Bright VSU" areas have high R575 and VISr and intermediate UVr. Several units defined by morphological or multispectral criteria correspond to specific VSUs, including low-reflectance material (dark blue VSU), pyroclastic deposits (red VSU), and hollows (intermediate VSU), but these VSUs generally include other types of areas as well. VSU definitions are complementary to those obtained by unsupervised clustering analysis. The global distribution of VIRS spectral units provides new information on Mercury's geological evolution. Much of Mercury's northern volcanic plains show spectral properties ranging from those of average VSU to those of red VSU, as does a large region in the southern hemisphere centered near 50°S, 245°E. Dark blue VSU material is widely distributed, with concentrations south of the northern plains, around the Rembrandt and

  13. Rapid comparison of properties on protein surface.

    Science.gov (United States)

    Sael, Lee; La, David; Li, Bin; Rustamov, Raif; Kihara, Daisuke

    2008-10-01

    The mapping of physicochemical characteristics onto the surface of a protein provides crucial insights into its function and evolution. This information can be further used in the characterization and identification of similarities within protein surface regions. We propose a novel method which quantitatively compares global and local properties on the protein surface. We have tested the method on comparison of electrostatic potentials and hydrophobicity. The method is based on 3D Zernike descriptors, which provides a compact representation of a given property defined on a protein surface. Compactness and rotational invariance of this descriptor enable fast comparison suitable for database searches. The usefulness of this method is exemplified by studying several protein families including globins, thermophilic and mesophilic proteins, and active sites of TIM beta/alpha barrel proteins. In all the cases studied, the descriptor is able to cluster proteins into functionally relevant groups. The proposed approach can also be easily extended to other surface properties. This protein surface-based approach will add a new way of viewing and comparing proteins to conventional methods, which compare proteins in terms of their primary sequence or tertiary structure.

  14. Surface reflectance drives nest box temperature profiles and thermal suitability for target wildlife.

    Directory of Open Access Journals (Sweden)

    Stephen R Griffiths

    Full Text Available Thermal properties of tree hollows play a major role in survival and reproduction of hollow-dependent fauna. Artificial hollows (nest boxes are increasingly being used to supplement the loss of natural hollows; however, the factors that drive nest box thermal profiles have received surprisingly little attention. We investigated how differences in surface reflectance influenced temperature profiles of nest boxes painted three different colors (dark-green, light-green, and white: total solar reflectance 5.9%, 64.4%, and 90.3% respectively using boxes designed for three groups of mammals: insectivorous bats, marsupial gliders and brushtail possums. Across the three different box designs, dark-green (low reflectance boxes experienced the highest average and maximum daytime temperatures, had the greatest magnitude of variation in daytime temperatures within the box, and were consistently substantially warmer than light-green boxes (medium reflectance, white boxes (high reflectance, and ambient air temperatures. Results from biophysical model simulations demonstrated that variation in diurnal temperature profiles generated by painting boxes either high or low reflectance colors could have significant ecophysiological consequences for animals occupying boxes, with animals in dark-green boxes at high risk of acute heat-stress and dehydration during extreme heat events. Conversely in cold weather, our modelling indicated that there are higher cumulative energy costs for mammals, particularly smaller animals, occupying light-green boxes. Given their widespread use as a conservation tool, we suggest that before boxes are installed, consideration should be given to the effect of color on nest box temperature profiles, and the resultant thermal suitability of boxes for wildlife, particularly during extremes in weather. Managers of nest box programs should consider using several different colors and installing boxes across a range of both orientations and

  15. Surface Properties of TNOs: Preliminary Statistical Analysis

    Science.gov (United States)

    Antonieta Barucci, Maria; Fornasier, S.; Alvarez-Cantal, A.; de Bergh, C.; Merlin, F.; DeMeo, F.; Dumas, C.

    2009-09-01

    An overview of the surface properties based on the last results obtained during the Large Program performed at ESO-VLT (2007-2008) will be presented. Simultaneous high quality visible and near-infrared spectroscopy and photometry have been carried out on 40 objects with various dynamical properties, using FORS1 (V), ISAAC (J) and SINFONI (H+K bands) mounted respectively at UT2, UT1 and UT4 VLT-ESO telescopes (Cerro Paranal, Chile). For spectroscopy we computed the spectral slope for each object and searched for possible rotational inhomogeneities. A few objects show features in their visible spectra such as Eris, whose spectral bands are displaced with respect to pure methane-ice. We identify new faint absorption features on 10199 Chariklo and 42355 Typhon, possibly due to the presence of aqueous altered materials. The H+K band spectroscopy was performed with the new instrument SINFONI which is a 3D integral field spectrometer. While some objects show no diagnostic spectral bands, others reveal surface deposits of ices of H2O, CH3OH, CH4, and N2. To investigate the surface properties of these bodies, a radiative transfer model has been applied to interpret the entire 0.4-2.4 micron spectral region. The diversity of the spectra suggests that these objects represent a substantial range of bulk compositions. These different surface compositions can be diagnostic of original compositional diversity, interior source and/or different evolution with different physical processes affecting the surfaces. A statistical analysis is in progress to investigate the correlation of the TNOs’ surface properties with size and dynamical properties.

  16. Gain-Enhanced On-Chip Antenna Utilizing Artificial Magnetic Conductor Reflecting Surface at 94 GHz

    KAUST Repository

    Nafe, Mahmoud

    2015-08-04

    . Unlike conventional ground plane reflecting surfaces, AMC surfaces generally enhance the radiation and impedance characteristics of close-by antennas. Based on this property, a ring-based AMC reflecting surface has been designed in the oxide layer for on-chip antennas operating at 94 GHz. Furthermore, a folded dipole antenna with its associ- ated planar feeding structures has been optimized and integrated with the developed ring-based AMC surface. The proposed design is then fabricated at KAUST clean- room facilities. Prototype characterization showed very promising results with good correlation to simulations, with the antenna exhibiting an impedance bandwidth of 10% (90-100 GHz) and peak gain of -1.4 dBi, which is the highest gain reported for on-chip antennas at this frequency band without the use of any external o↵-chip components or post-fabrication steps.

  17. Thermoluminescence, infrared reflectivity and electron paramagnetic resonance properties of hemimorphite

    Energy Technology Data Exchange (ETDEWEB)

    Gallegos, E.A. [Institute of Physics, University of Sao Paulo, Rua do Matao, Travessa R, 187, CEP 05508-900, Sao Paulo, SP (Brazil); Cano, N.F. [Institute of Physics, University of Sao Paulo, Rua do Matao, Travessa R, 187, CEP 05508-900, Sao Paulo, SP (Brazil)], E-mail: nilocano@dfn.if.usp.br; Watanabe, S.; Chubaci, J.F.D. [Institute of Physics, University of Sao Paulo, Rua do Matao, Travessa R, 187, CEP 05508-900, Sao Paulo, SP (Brazil)

    2009-01-15

    Silicate mineral hemimorphite has been investigated concerning its TL, IR and EPR properties. A broad TL peak around 180 deg. C and a weaker and narrower peak around 360 deg. C were found in a sample annealed at 600 deg. C for 1 h and then irradiated. The deconvolution using the CGCD method revealed peaks around 132, 169, 222 and 367 deg. C. The reflectivity measurements showed several bands in the NIR region due to H{sub 2}O, OH and Al-OH complexes. No band was observed in the visible region. The thermal treatments were carried out from {approx}110 to 940 deg. C and dehydration was observed, first causing a diminishing optical absorption in general and the disappearance of water and hydroxyl absorption bands. The EPR spectrum of natural hemimorphite, presented Cu{sup 2+} signals at g = 2.4 and g = 2.1 plus E{sub 1}' signal superposed to Fe{sup 3+} signal around g = 2.0.

  18. Seismic data enhancement with Common Reflection Surface (CRS) stack method

    Energy Technology Data Exchange (ETDEWEB)

    Baykulov, M.; Brink, H.J.; Gajewski, D.; Yoon, Mi-Kyung [Hamburg Univ. (Germany). Inst. fuer Geophysik

    2008-10-23

    We present the results of partial stacking of prestack seismic reflection data based on the kinematic wavefield attributes computed during the automatic CRS stack. The resulting CRS supergathers are more regularised and have better signal to noise ratio compared to original CMP gathers. The improved data can be used in any conventional processing tool instead of the original data, providing enhanced images of better quality. The CRS supergather method is especially suited for low fold seismic reflection data. Application of the new method to synthetic and real low fold data shows a clear improvement of seismograms as well as time and depth-migrated sections. (orig.)

  19. Reflectance of Antarctic surfaces from multispectral radiometers: The correction of atmospheric effects

    International Nuclear Information System (INIS)

    Zibordi, G.; Maracci, G.

    1993-01-01

    Monitoring reflectance of polar icecaps has relevance in climate studies. In fact, climate changes produce variations in the morphology of ice and snow covers, which are detectable as surface reflectance change. Surface reflectance can be retrieved from remotely sensed data. However, absolute values independent of atmospheric turbidity and surface altitude can only be obtained after removing masking effects of the atmosphere. An atmospheric correction model, accounting for surface and sensor altitudes above sea level, is described and validated through data detected over Antarctic surfaces with a Barnes Modular Multispectral Radiometer having bands overlapping those of the Landsat Thematic Mapper. The model is also applied in a sensitivity analysis to investigate error induced in reflectance obtained from satellite data by indeterminacy in optical parameters of atmospheric constituents. Results show that indeterminacy in the atmospheric water vapor optical thickness is the main source of nonaccuracy in the retrieval of surface reflectance from data remotely sensed over Antarctic regions

  20. Quantum reflection of fast atoms from insulator surfaces: Eikonal description

    Energy Technology Data Exchange (ETDEWEB)

    Gravielle, M S; Miraglia, J E, E-mail: msilvia@iafe.uba.a, E-mail: miraglia@iafe.uba.a [Instituto de Astronomia y Fisica del Espacio, CONICET, Casilla de Correo 67, Sucursal 28, 1428 Buenos Aires (Argentina) and Dpto. de Fisica, FCEN, Universidad de Buenos Aires (Argentina)

    2009-11-01

    Interference effects recently observed in grazing scattering of swift atoms from insulator surfaces are studied within a distorted-wave method - the surface eikonal approximation. This approach makes use of the eikonal wave function, involving axial channeled trajectories. The theory is applied to helium atoms colliding with a LiF(001) surface along low-index crystallographic directions. The roles played by the projectile polarization and the surface rumpling are investigated, finding that both effects are important for the description of the experimental projectile distributions.

  1. Surface properties of functional polymer systems

    Science.gov (United States)

    Wong, Derek

    Polymer surface modification typically involves blending with other polymers or chemical modification of the parent polymer. Such strategies inevitably result in polymer systems that are spatially and chemically heterogeneous, and which exhibit the phenomenon of surface segregation. This work investigates the effects of chain architecture on the surface segregation behavior of such functionally modified polymers using a series of end- and center-fluorinated poly(D,L-lactide). Surface segregation of the fluorinated functional groups was observed in both chain architectures via AMPS and water contact angle. Higher surface segregation was noted for functional groups located at the chain end as opposed to those in the middle of the chain. A self-consistent mean-field lattice theory was used to model the composition depth profiles of functional groups and excellent agreement was found between the model predictions and the experimental AMPS data in both chain architectures. Polymer properties are also in general dependent on both time and temperature, and exhibit a range of relaxation times in response to environmental stimuli. This behavior arises from the characteristic frequencies of molecular motions of the polymer chain and the interrelationship between time and temperature has been widely established for polymer bulk properties. There is evidence that surface properties also respond in a manner that is time and temperature dependent and that this dependence may not be the same as that observed for bulk properties. AMPS and water contact angle experiments were used to investigate the surface reorganization behavior of functional groups using a series of anionically synthesized end-fluorinated and end-carboxylated poly(styrene). It was found that both types of functional end-groups reorganized upon a change in the polarity of the surface environment in order to minimize the surface free energy. ADXPS and contact angle results suggest that the reorganization depth was

  2. Correlation between surface microstructure and optical properties of porous silicon

    Directory of Open Access Journals (Sweden)

    Saeideh Rhramezani Sani

    2007-12-01

    Full Text Available   We have studied the effect of increasing porosity and its microstructure surface variation on the optical and dielectric properties of porous silicon. It seems that porosity, as the surface roughness within the range of a few microns, shows quantum effect in the absorption and reflection process of porous silicon. Optical constants of porous silicon at normal incidence of light with wavelength in the range of 250-3000 nm have been calculated by Kramers-Kroning method. Our experimental analysis shows that electronic structure and dielectric properties of porous silicon are totally different from silicon. Also, it shows that porous silicon has optical response in the visible region. This difference was also verified by effective media approximation (EMA.

  3. Impacts of dust aerosol and adjacency effects on the accuracy of Landsat 8 and RapidEye surface reflectances

    KAUST Repository

    Houborg, Rasmus; McCabe, Matthew

    2017-01-01

    The atmospheric correction of satellite data is challenging over desert agricultural systems, due to the relatively high aerosol optical thicknesses (τ550), bright soils, and a heterogeneous surface reflectance field. Indeed, the contribution of reflected radiation from adjacent pixels scattered into the field of view of a target pixel is considerable and can significantly affect the fidelity of retrieved reflectances. In this study, uncertainties and quantitative errors associated with the atmospheric correction of multi-spectral Landsat 8 and RapidEye data were characterized over a desert agricultural landscape in Saudi Arabia. Surface reflectances were retrieved using an implementation of the 6SV atmospheric correction code, and validated against field collected spectroradiometer measurements over desert, cultivated soil, and vegetated surface targets. A combination of satellite and Aerosol Robotic Network (AERONET) data were used to parameterize aerosol properties and atmospheric state parameters. With optimal specification of τ550 and aerosol optical properties and correction for adjacency effects, the relative Mean Absolute Deviation (MAD) for all bands combined was 5.4% for RapidEye and 6.8% for Landsat 8. However uncertainties associated with satellite-based τ550 retrievals were shown to introduce significant error into the reflectance estimates. With respect to deriving common vegetation indices from corrected reflectance data, the Normalized Difference Vegetation Index (NDVI) was associated with the smallest errors (3–8% MAD). Surface reflectance errors were highest for bands in the visible part of the spectrum, particularly the blue band (5–16%), while there was more consistency within the red-edge (~ 5%) and near-infrared (5–7%). Results were generally better constrained when a τ550-dependent aerosol model for desert dust particles, parameterized on the basis of nearby AERONET site data, was used in place of a generic rural or background

  4. Impacts of dust aerosol and adjacency effects on the accuracy of Landsat 8 and RapidEye surface reflectances

    KAUST Repository

    Houborg, Rasmus

    2017-03-29

    The atmospheric correction of satellite data is challenging over desert agricultural systems, due to the relatively high aerosol optical thicknesses (τ550), bright soils, and a heterogeneous surface reflectance field. Indeed, the contribution of reflected radiation from adjacent pixels scattered into the field of view of a target pixel is considerable and can significantly affect the fidelity of retrieved reflectances. In this study, uncertainties and quantitative errors associated with the atmospheric correction of multi-spectral Landsat 8 and RapidEye data were characterized over a desert agricultural landscape in Saudi Arabia. Surface reflectances were retrieved using an implementation of the 6SV atmospheric correction code, and validated against field collected spectroradiometer measurements over desert, cultivated soil, and vegetated surface targets. A combination of satellite and Aerosol Robotic Network (AERONET) data were used to parameterize aerosol properties and atmospheric state parameters. With optimal specification of τ550 and aerosol optical properties and correction for adjacency effects, the relative Mean Absolute Deviation (MAD) for all bands combined was 5.4% for RapidEye and 6.8% for Landsat 8. However uncertainties associated with satellite-based τ550 retrievals were shown to introduce significant error into the reflectance estimates. With respect to deriving common vegetation indices from corrected reflectance data, the Normalized Difference Vegetation Index (NDVI) was associated with the smallest errors (3–8% MAD). Surface reflectance errors were highest for bands in the visible part of the spectrum, particularly the blue band (5–16%), while there was more consistency within the red-edge (~ 5%) and near-infrared (5–7%). Results were generally better constrained when a τ550-dependent aerosol model for desert dust particles, parameterized on the basis of nearby AERONET site data, was used in place of a generic rural or background

  5. Multifunctional high-reflective and antireflective layer systems with easy-to-clean properties

    International Nuclear Information System (INIS)

    Gloess, D.; Frach, P.; Gottfried, C.; Klinkenberg, S.; Liebig, J.-S.; Hentsch, W.; Liepack, H.; Krug, M.

    2008-01-01

    High-reflective (HR) and even more antireflective (AR) layer systems are in use for widespread applications. Multifunctional layer systems providing high optical functionality with an easy-to-clean or a self-cleaning behaviour would be preferable for many applications to avoid soiling of the surface. In this paper, the feasibility of fabrication by highly productive pulse magnetron sputtering in an in-line coating plant is investigated. Easy-to-clean properties are achieved by a top layer of photocatalytic and photoinduced hydrophilic TiO 2 . Multifunctional HR layer systems were successfully deposited on glass and polyethylene terephthalate (PET) substrates at a low deposition temperature of 150 deg. C, demonstrating the possibility of coating certain polymer materials. Double-sided multifunctional AR layer systems with a single-sided photoinduced hydrophilic TiO 2 top coating have a resulting reflectivity of about 3% and transmittance of about 97% in the visible range of light

  6. Interference effects in plasom excitation by particles reflected near a metal surface

    International Nuclear Information System (INIS)

    Denton, C.D.; Gervasoni, J.L.; Barrachina, R.O.; Arista, N.R.; Universidad Nacional de Cuyo, Mendoza

    1993-01-01

    Using the dielectric formalism and the specular reflection model, we evaluate the probability of surface and bulk plasmon excitation by particles reflected in the proximity of a metal surface. We obtain a strong oscillatory behaviour as a function of the penetration distance. (author)

  7. Surface active properties of lipid nanocapsules.

    Directory of Open Access Journals (Sweden)

    Celia R A Mouzouvi

    Full Text Available Lipid nanocapsules (LNCs are biomimetic nanocarriers used for the encapsulation of a broad variety of active ingredients. Similar to surface active compounds, LNCs contain both hydrophilic and hydrophobic parts in their structure. Moreover, the components of LNCs, macrogol 15 hydroxystearate (MHS and lecithin, are known for their surface active properties. Therefore, the aim of this paper was to investigate the capability of the LNCs to decrease surface tension using two techniques: drop tensiometry and the Wilhelmy plate method. LNCs with diameters ranging from 30 to 100 nm were successfully obtained using a phase inversion technique. The LNCs' properties, such as size and zeta potential, depend on the composition. LNCs exhibit a lower limiting surface tension compared to MHS (34.8-35.0 mN/m and 37.7-38.8 mN/m, respectively, as confirmed by both drop tensiometry and the Wilhelmy plate method. LNCs have exhibited a saturated interfacial concentration (SIC that was 10-fold higher than the critical micellar concentration (CMC of MHS or the SIC of binary and ternary mixtures of LNC ingredients. The SIC of the LNC formulations depended on the mass mixing ratio of the MHS/triglycerides but not on the presence of lecithin. The CMC/SIC values measured by the Wilhelmy plate method were higher than those obtained using drop tensiometry because of the longer duration of the tensiometry measurement. In conclusion, the surfactant-like properties of the LNCs offer new possibilities for medical and pharmaceutical applications.

  8. Liquid Atomization Induced by Pulse Laser Reflection underneath Liquid Surface

    Science.gov (United States)

    Utsunomiya, Yuji; Kajiwara, Takashi; Nishiyama, Takashi; Nagayama, Kunihito; Kubota, Shiro; Nakahara, Motonao

    2009-05-01

    We observed a novel effect of pulse laser reflection at the interface between transparent materials with different refractive indices. The electric field intensity doubles when a laser beam is completely reflected from a material with a higher refractive index to a material with a lower index. This effect appreciably reduces pulse laser ablation threshold of transparent materials. We performed experiments to observe the entire ablation process for laser incidence on the water-air interface using pulse laser shadowgraphy with high-resolution film; the minimum laser fluence for laser ablation at the water-air interface was approximately 12-16 J/cm2. We confirmed that this laser ablation occurs only when the laser beam is incident on the water-air interface from water. Many slender liquid ligaments extend like a milk crown and seem to be atomized at the tip. Their detailed structures can be resolved only by pulse laser photography using high-resolution film.

  9. A Monte Carlo reflectance model for soil surfaces with three-dimensional structure

    Science.gov (United States)

    Cooper, K. D.; Smith, J. A.

    1985-01-01

    A Monte Carlo soil reflectance model has been developed to study the effect of macroscopic surface irregularities larger than the wavelength of incident flux. The model treats incoherent multiple scattering from Lambertian facets distributed on a periodic surface. Resulting bidirectional reflectance distribution functions are non-Lambertian and compare well with experimental trends reported in the literature. Examples showing the coupling of the Monte Carlo soil model to an adding bidirectional canopy of reflectance model are also given.

  10. Characterizing the statistical properties of protein surfaces

    Science.gov (United States)

    Bak, Ji Hyun; Bitbol, Anne-Florence; Bialek, William

    Proteins and their interactions form the body of the signaling transduction pathway in many living systems. In order to ensure the accuracy as well as the specificity of signaling, it is crucial that proteins recognize their correct interaction partners. How difficult, then, is it for a protein to discriminate its correct interaction partner(s) from the possibly large set of other proteins it may encounter in the cell? An important ingredient of recognition is shape complementarity. The ensemble of protein shapes should be constrained by the need for maintaining functional interactions while avoiding spurious ones. To address this aspect of protein recognition, we consider the ensemble of proteins in terms of the shapes of their surfaces. We take into account the high-resolution structures of E.coli non-DNA-binding cytoplasmic proteins, retrieved from the Protein Data Bank. We aim to characterize the statistical properties of the protein surfaces at two levels: First, we study the intrinsic dimensionality at the level of the ensemble of the surface objects. Second, at the level of the individual surfaces, we determine the scale of shape variation. We further discuss how the dimensionality of the shape space is linked to the statistical properties of individual protein surfaces. Jhb and WB acknowledge support from National Science Foundation Grants PHY-1305525 and PHY-1521553. AFB acknowledges support from the Human Frontier Science Program.

  11. Mechanical properties of ion implanted ceramic surfaces

    International Nuclear Information System (INIS)

    Burnett, P.J.

    1985-01-01

    This thesis investigates the mechanisms by which ion implantation can affect those surface mechanical properties of ceramics relevant to their tribological behaviour, specifically hardness and indentation fracture. A range of model materials (including single crystal Si, SiC, A1 2 0 3 , Mg0 and soda-lime-silica glass) have been implanted with a variety of ion species and at a range of ion energies. Significant changes have been found in both low-load microhardness and indentation fracture behaviour. The changes in hardness have been correlated with the evolution of an increasingly damaged and eventually amorphous thin surface layer together with the operation of radiation-, solid-solution- and precipitation-hardening mechanisms. Compressive surface stresses have been shown to be responsible for the observed changes in identation fracture behaviour. In addition, the levels of surface stress present have been correlated with the structure of the surface layer and a simple quantitative model proposed to explain the observed stress-relief upon amorphisation. Finally, the effects of ion implantation upon a range of polycrystalline ceramic materials has been investigated and the observed properties modifications compared and contrasted to those found for the model single crystal materials. (author)

  12. Welcome to Surface Topography: Metrology and Properties

    Science.gov (United States)

    Leach, Richard

    2013-11-01

    I am delighted to welcome readers to this inaugural issue of Surface Topography: Metrology and Properties (STMP). In these days of citation indexes and academic reviews, it is a tough, and maybe a brave, job to start a new journal. But the subject area has never been more active and we are seeing genuine breakthroughs in the use of surfaces to control functional performance. Most manufactured parts rely on some form of control of their surface characteristics. The surface is usually defined as that feature on a component or device, which interacts with either the environment in which it is housed (or in which the device operates), or with another surface. The surface topography and material characteristics of a part can affect how fluids interact with it, how the part looks and feels and how two bearing parts will slide together. The need to control, and hence measure, surface features is becoming increasingly important as we move into a miniaturized world. Surface features can become the dominant functional features of a part and may become large in comparison to the overall size of an object. Research into surface texture measurement and characterization has been carried out for over a century and is now more active than ever, especially as new areal surface texture specification standards begin to be introduced. The range of disciplines for which the function of a surface relates to its topography is very diverse; from metal sheet manufacturing to art restoration, from plastic electronics to forensics. Until now, there has been no obvious publishing venue to bring together all these applications with the underlying research and theory, or to unite those working in academia with engineering and industry. Hence the creation of Surface Topography: Metrology and Properties . STMP will publish the best work being done across this broad discipline in one journal, helping researchers to share common themes and highlighting and promoting the extraordinary benefits this

  13. Infrared reflection properties and modelling of in situ reflection measurements on plasma-facing materials in Tore Supra

    International Nuclear Information System (INIS)

    Reichle, R; Desgranges, C; Faisse, F; Pocheau, C; Lasserre, J-P; Oelhoffen, F; Eupherte, L; Todeschini, M

    2009-01-01

    Tore Supra has-like ITER-reflecting internal surfaces, which can perturb the machine protection systems based on infrared (IR) thermography. To ameliorate this situation, we have measured and modelled in the 3-5 μm wavelength range the bi-directional reflection distribution function (BRDF) of wall material samples from Tore Supra and conducted in situ reflection measurements and simulated them with the CEA COSMOS code. BRDF results are presented for B 4 C and carbon fibre composite (CFC) tiles. The hemispherical integrated reflection ranges from 0.12 for the B 4 C sample to 0.39 for a CFC tile from the limiter erosion zone. In situ measurements of the IR reflection of a blackbody source off an ICRH and an LHCD antenna of Tore Supra are well reproduced by the simulation.

  14. Infrared reflection properties and modelling of in situ reflection measurements on plasma-facing materials in Tore Supra

    Energy Technology Data Exchange (ETDEWEB)

    Reichle, R; Desgranges, C; Faisse, F; Pocheau, C [CEA, IRFM, F-13108 Saint-Paul-lez-Durance (France); Lasserre, J-P; Oelhoffen, F; Eupherte, L; Todeschini, M [CEA, DAM, CESTA, F-33114 Le Barp (France)

    2009-12-15

    Tore Supra has-like ITER-reflecting internal surfaces, which can perturb the machine protection systems based on infrared (IR) thermography. To ameliorate this situation, we have measured and modelled in the 3-5 {mu}m wavelength range the bi-directional reflection distribution function (BRDF) of wall material samples from Tore Supra and conducted in situ reflection measurements and simulated them with the CEA COSMOS code. BRDF results are presented for B{sub 4}C and carbon fibre composite (CFC) tiles. The hemispherical integrated reflection ranges from 0.12 for the B{sub 4}C sample to 0.39 for a CFC tile from the limiter erosion zone. In situ measurements of the IR reflection of a blackbody source off an ICRH and an LHCD antenna of Tore Supra are well reproduced by the simulation.

  15. Native SrTiO3 (001) surface layer from resonant Ti L2,3 reflectance spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Valvidares, Manuel; Huijben, Mark; Yu, Pu; Ramesh, Ramamoorthy; Kortright, Jeffrey

    2010-11-03

    We quantitatively model resonant Ti L2,3 reflectivity Rs,p(q, hn) from several SrTiO3 (001) single crystals having different initial surface preparations and stored in ambient conditions before and between measurements. All samples exhibit unexpected 300 K Rs(hn) - Rp(hn) anisotropy corresponding to weak linear dichroism and tetragonal distortion of the TiO6 octahedra indicating a surface layer with properties different from cubic SrTiO3. Oscillations in Rs(q) confirm a ubiquitous surface layer 2-3 nm thick that evolves over a range of time scales. Resonant optical constant spectra derived from Rs,p(hn) assuming a uniform sample are refined using a single surface layer to fit measured Rs(q). Differences in surface layer and bulk optical properties indicate that the surface is significantly depleted in Sr and enriched in Ti and O. While consistent with the tendency of SrTiO3 surfaces toward non-stoichiometry, this layer does not conform simply to existing models for the near surface region and apparently forms via room temperature surface reactions with the ambient. This new quantitative spectral modeling approach is generally applicable and has potential to study near-surface properties of a variety of systems with unique chemical and electronic sensitivities.

  16. From Intensity Profile to Surface Normal: Photometric Stereo for Unknown Light Sources and Isotropic Reflectances.

    Science.gov (United States)

    Lu, Feng; Matsushita, Yasuyuki; Sato, Imari; Okabe, Takahiro; Sato, Yoichi

    2015-10-01

    We propose an uncalibrated photometric stereo method that works with general and unknown isotropic reflectances. Our method uses a pixel intensity profile, which is a sequence of radiance intensities recorded at a pixel under unknown varying directional illumination. We show that for general isotropic materials and uniformly distributed light directions, the geodesic distance between intensity profiles is linearly related to the angular difference of their corresponding surface normals, and that the intensity distribution of the intensity profile reveals reflectance properties. Based on these observations, we develop two methods for surface normal estimation; one for a general setting that uses only the recorded intensity profiles, the other for the case where a BRDF database is available while the exact BRDF of the target scene is still unknown. Quantitative and qualitative evaluations are conducted using both synthetic and real-world scenes, which show the state-of-the-art accuracy of smaller than 10 degree without using reference data and 5 degree with reference data for all 100 materials in MERL database.

  17. High quality broadband spatial reflections of slow Rayleigh surface acoustic waves modulated by a graded grooved surface

    KAUST Repository

    Xu, Yanlong

    2015-01-21

    We report high quality broadband spatial reflections of Rayleigh surface acoustic waves (SAWs) through a graded grooved surface. High quality means that no wave is allowed to transmit and the incident wave is nearly all reflected to the input side. The graded grooved surface is structured by drilling one dimensional array of graded grooves with increased depths on a flat surface. We investigate SAW dispersion relations, wave field distribution at several typical SAW wavelengths, and time evolution of a Gaussian pulse through the graded grooved surface. Results show that the input broadband Rayleigh SAWs can be slowed, spatially enhanced and stopped, and finally reflected to the input side. The study suggests that engraving the flat surface can be used as an efficient and economical way to manipulate Rayleigh SAWs, which has potential application in novel SAW devices such as filters, reflectors, sensors, energy harvesters, and diodes.

  18. Retrieving background surface reflectance of Himawari-8/AHI using BRDF modeling

    Science.gov (United States)

    Choi, Sungwon; Seo, Minji; Lee, Kyeong-sang; Han, Kyung-soo

    2017-04-01

    In these days, remote sensing is more important than past. And retrieving surface reflectance in remote sensing is also important. So there are many ways to retrieve surface reflectance by my countries with polar orbit and geostationary satellite. We studied Bidirectional Reflectance Distribution Function (BRDF) which is used to retrieve surface reflectance. In BRDF equation, we calculate surface reflectance using BRD components and angular data. BRD components are to calculate 3 of scatterings, isotropic geometric and volumetric scattering. To make Background Surface Reflectance (BSR) of Himawari-8/AHI. We used 5 bands (band1, band2, band3, band4, band5) with BRDF. And we made 5 BSR for 5 channels. For validation, we compare BSR with Top of canopy (TOC) reflectance of AHI. As a result, bias are from -0.00223 to 0.008328 and Root Mean Square Error (RMSE) are from 0.045 to 0.049. We think BSR can be used to replace TOC reflectance in remote sensing to improve weakness of TOC reflectance.

  19. Anisotropic surface chemistry properties and adsorption behavior of silicate mineral crystals.

    Science.gov (United States)

    Xu, Longhua; Tian, Jia; Wu, Houqin; Fang, Shuai; Lu, Zhongyuan; Ma, Caifeng; Sun, Wei; Hu, Yuehua

    2018-03-07

    Anisotropic surface properties of minerals play an important role in a variety of fields. With a focus on the two most intensively investigated silicate minerals (i.e., phyllosilicate minerals and pegmatite aluminosilicate minerals), this review highlights the research on their anisotropic surface properties based on their crystal structures. Four surface features comprise the anisotropic surface chemistry of minerals: broken bonds, energy, wettability, and charge. Analysis of surface broken bond and energy anisotropy helps to explain the cleavage and growth properties of mineral crystals, and understanding surface wettability and charge anisotropy is critical to the analysis of minerals' solution behavior, such as their flotation performance and rheological properties. In a specific reaction, the anisotropic surface properties of minerals are reflected in the adsorption strengths of reagents on different mineral surfaces. Combined with the knowledge of mineral crushing and grinding, a thorough understanding of the anisotropic surface chemistry properties and the anisotropic adsorption behavior of minerals will lead to the development of effective relational models comprising their crystal structure, surface chemistry properties, and targeted reagent adsorption. Overall, such a comprehensive approach is expected to firmly establish the connection between selective cleavage of mineral crystals for desired surfaces and designing novel reagents selectively adsorbed on the mineral surfaces. As tools to characterize the anisotropic surface chemistry properties of minerals, DLVO theory, atomic force microscopy (AFM), and molecular dynamics (MD) simulations are also reviewed. Copyright © 2017 Elsevier B.V. All rights reserved.

  20. STACKING ON COMMON REFLECTION SURFACE WITH MULTIPARAMETER TRAVELTIME

    Directory of Open Access Journals (Sweden)

    Montes V. Luis A.

    2006-12-01

    Full Text Available Commonly seismic images are displayed in time domain because the model in depth can be known only in well logs. To produce seismic sections, pre and post stack processing approaches use time or depth velocity models whereas the common reflection method does not, instead it requires a set of parameters established for the first layer. A set of synthetic data of an anticline model, with sources and receivers placed on a flat topography, was used to observe the performance of this method. As result, a better reflector recovering compared against conventional processing sequence was observed.
    The procedure was extended to real data, using a dataset acquired on a zone characterized by mild topography and quiet environment reflectors in the Eastern Colombia planes, observing an enhanced and a better continuity of the reflectors in the CRS stacked section.

  1. Noninvasive assessment of articular cartilage surface damage using reflected polarized light microscopy

    Science.gov (United States)

    Huynh, Ruby N.; Nehmetallah, George; Raub, Christopher B.

    2017-06-01

    Articular surface damage occurs to cartilage during normal aging, osteoarthritis, and in trauma. A noninvasive assessment of cartilage microstructural alterations is useful for studies involving cartilage explants. This study evaluates polarized reflectance microscopy as a tool to assess surface damage to cartilage explants caused by mechanical scraping and enzymatic degradation. Adult bovine articular cartilage explants were scraped, incubated in collagenase, or underwent scrape and collagenase treatments. In an additional experiment, cartilage explants were subject to scrapes at graduated levels of severity. Polarized reflectance parameters were compared with India ink surface staining, features of histological sections, changes in explant wet weight and thickness, and chondrocyte viability. The polarized reflectance signal was sensitive to surface scrape damage and revealed individual scrape features consistent with India ink marks. Following surface treatments, the reflectance contrast parameter was elevated and correlated with image area fraction of India ink. After extensive scraping, polarized reflectance contrast and chondrocyte viability were lower than that from untreated explants. As part of this work, a mathematical model was developed and confirmed the trend in the reflectance signal due to changes in surface scattering and subsurface birefringence. These results demonstrate the effectiveness of polarized reflectance microscopy to sensitively assess surface microstructural alterations in articular cartilage explants.

  2. Patellar Skin Surface Temperature by Thermography Reflects Knee Osteoarthritis Severity

    OpenAIRE

    Anna E. Denoble; Norine Hall; Carl F. Pieper; Virginia B. Kraus

    2010-01-01

    Background: Digital infrared thermal imaging is a means of measuring the heat radiated from the skin surface. Our goal was to develop and assess the reproducibility of serial infrared measurements of the knee and to assess the association of knee temperature by region of interest with radiographic severity of knee Osteoarthritis (rOA). Methods: A total of 30 women (15 Cases with symptomatic knee OA and 15 age-matched Controls without knee pain or knee OA) participated in this study. Infrared ...

  3. Unmanned aerial system nadir reflectance and MODIS nadir BRDF-adjusted surface reflectances intercompared over Greenland

    Directory of Open Access Journals (Sweden)

    J. F. Burkhart

    2017-07-01

    Full Text Available Albedo is a fundamental parameter in earth sciences, and many analyses utilize the Moderate Resolution Imaging Spectroradiometer (MODIS bidirectional reflectance distribution function (BRDF/albedo (MCD43 algorithms. While derivative albedo products have been evaluated over Greenland, we present a novel, direct comparison with nadir surface reflectance collected from an unmanned aerial system (UAS. The UAS was flown from Summit, Greenland, on 210 km transects coincident with the MODIS sensor overpass on board the Aqua and Terra satellites on 5 and 6 August 2010. Clear-sky acquisitions were available from the overpasses within 2 h of the UAS flights. The UAS was equipped with upward- and downward-looking spectrometers (300–920 nm with a spectral resolution of 10 nm, allowing for direct integration into the MODIS bands 1, 3, and 4. The data provide a unique opportunity to directly compare UAS nadir reflectance with the MODIS nadir BRDF-adjusted surface reflectance (NBAR products. The data show UAS measurements are slightly higher than the MODIS NBARs for all bands but agree within their stated uncertainties. Differences in variability are observed as expected due to different footprints of the platforms. The UAS data demonstrate potentially large sub-pixel variability of MODIS reflectance products and the potential to explore this variability using the UAS as a platform. It is also found that, even at the low elevations flown typically by a UAS, reflectance measurements may be influenced by haze if present at and/or below the flight altitude of the UAS. This impact could explain some differences between data from the two platforms and should be considered in any use of airborne platforms.

  4. Optical Estimation of the 3D Shape of a Solar Illuminated, Reflecting Satellite Surface

    Science.gov (United States)

    Antolin, J.; Yu, Z.; Prasad, S.

    2016-09-01

    The spatial distribution of the polarized component of the power reflected by a macroscopically smooth but microscopically roughened curved surface under highly directional illumination, as characterized by an appropriate bi-directional reflectance distribution function (BRDF), carries information about the three-dimensional (3D) shape of the surface. This information can be exploited to recover the surface shape locally under rather general conditions whenever power reflectance data for at least two different illumination or observation directions can be obtained. We present here two different parametric approaches for surface reconstruction, amounting to the recovery of the surface parameters that are either the global parameters of the family to which the surface is known a priori to belong or the coefficients of a low-order polynomial that can be employed to characterize a smoothly varying surface locally over the observed patch.

  5. How Can Polarization States of Reflected Light from Snow Surfaces Inform Us on Surface Normals and Ultimately Snow Grain Size Measurements?

    Science.gov (United States)

    Schneider, A. M.; Flanner, M.; Yang, P.; Yi, B.; Huang, X.; Feldman, D.

    2016-12-01

    The Snow Grain Size and Pollution (SGSP) algorithm is a method applied to Moderate Resolution Imaging Spectroradiometer data to estimate snow grain size from space-borne measurements. Previous studies validate and quantify potential sources of error in this method, but because it assumes flat snow surfaces, however, large scale variations in surface normals can cause biases in its estimates due to its dependence on solar and observation zenith angles. To address these variations, we apply the Monte Carlo method for photon transport using data containing the single scattering properties of different ice crystals to calculate polarization states of reflected monochromatic light at 1500nm from modeled snow surfaces. We evaluate the dependence of these polarization states on solar and observation geometry at 1500nm because multiple scattering is generally a mechanism for depolarization and the ice crystals are relatively absorptive at this wavelength. Using 1500nm thus results in a higher number of reflected photons undergoing fewer scattering events, increasing the likelihood of reflected light having higher degrees of polarization. In evaluating the validity of the model, we find agreement with previous studies pertaining to near-infrared spectral directional hemispherical reflectance (i.e. black-sky albedo) and similarities in measured bidirectional reflectance factors, but few studies exist modeling polarization states of reflected light from snow surfaces. Here, we present novel results pertaining to calculated polarization states and compare dependences on solar and observation geometry for different idealized snow surfaces. If these dependencies are consistent across different ice particle shapes and sizes, then these findings could inform the SGSP algorithm by providing useful relationships between measurable physical quantities and solar and observation geometry to better understand variations in snow surface normals from remote sensing observations.

  6. Nanoscale silver-assisted wet etching of crystalline silicon for anti-reflection surface textures.

    Science.gov (United States)

    Li, Rui; Wang, Shuling; Chuwongin, Santhad; Zhou, Weidong

    2013-01-01

    We report here an electro-less metal-assisted chemical etching (MacEtch) process as light management surface-texturing technique for single crystalline Si photovoltaics. Random Silver nanostructures were formed on top of the Si surface based on the thin film evaporation and annealing process. Significant reflection reduction was obtained from the fabricated Si sample, with approximately 2% reflection over a wide spectra range (300 to 1050 nm). The work demonstrates the potential of MacEtch process for anti-reflection surface texture fabrication of large area, high efficiency, and low cost thin film solar cell.

  7. Thermodynamic properties of water solvating biomolecular surfaces

    Science.gov (United States)

    Heyden, Matthias

    Changes in the potential energy and entropy of water molecules hydrating biomolecular interfaces play a significant role for biomolecular solubility and association. Free energy perturbation and thermodynamic integration methods allow calculations of free energy differences between two states from simulations. However, these methods are computationally demanding and do not provide insights into individual thermodynamic contributions, i.e. changes in the solvent energy or entropy. Here, we employ methods to spatially resolve distributions of hydration water thermodynamic properties in the vicinity of biomolecular surfaces. This allows direct insights into thermodynamic signatures of the hydration of hydrophobic and hydrophilic solvent accessible sites of proteins and small molecules and comparisons to ideal model surfaces. We correlate dynamic properties of hydration water molecules, i.e. translational and rotational mobility, to their thermodynamics. The latter can be used as a guide to extract thermodynamic information from experimental measurements of site-resolved water dynamics. Further, we study energy-entropy compensations of water at different hydration sites of biomolecular surfaces. This work is supported by the Cluster of Excellence RESOLV (EXC 1069) funded by the Deutsche Forschungsgemeinschaft.

  8. Hydrodynamic slip length as a surface property

    Science.gov (United States)

    Ramos-Alvarado, Bladimir; Kumar, Satish; Peterson, G. P.

    2016-02-01

    Equilibrium and nonequilibrium molecular dynamics simulations were conducted in order to evaluate the hypothesis that the hydrodynamic slip length is a surface property. The system under investigation was water confined between two graphite layers to form nanochannels of different sizes (3-8 nm). The water-carbon interaction potential was calibrated by matching wettability experiments of graphitic-carbon surfaces free of airborne hydrocarbon contamination. Three equilibrium theories were used to calculate the hydrodynamic slip length. It was found that one of the recently reported equilibrium theories for the calculation of the slip length featured confinement effects, while the others resulted in calculations significantly hindered by the large margin of error observed between independent simulations. The hydrodynamic slip length was found to be channel-size independent using equilibrium calculations, i.e., suggesting a consistency with the definition of a surface property, for 5-nm channels and larger. The analysis of the individual trajectories of liquid particles revealed that the reason for observing confinement effects in 3-nm nanochannels is the high mobility of the bulk particles. Nonequilibrium calculations were not consistently affected by size but by noisiness in the smallest systems.

  9. Neutron reflectivity study of substrate surface chemistry effects on supported phospholipid bilayer formation on (1120) sapphire.

    Energy Technology Data Exchange (ETDEWEB)

    Oleson, Timothy A. [University of Wisconsin, Madison; Sahai, Nita [University of Akron; Wesolowski, David J [ORNL; Dura, Joseph A [ORNL; Majkrzak, Charles F [ORNL; Giuffre, Anthony J. [University of Wisconsin, Madison

    2012-01-01

    Oxide-supported phospholipid bilayers (SPBs) used as biomimetric membranes are significant for a broad range of applications including improvement of biomedical devices and biosensors, and in understanding biomineralization processes and the possible role of mineral surfaces in the evolution of pre-biotic membranes. Continuous-coverage and/or stacjed SPBs retain properties (e.,g. fluidity) more similar to native biological membranes, which is desirable for most applications. Using neutron reflectivity, we examined face coverage and potential stacking of dipalmitoylphosphatidylcholine (DPPC) bilayers on the (1120) face of sapphire (a-Al2O3). Nearly full bilayers were formed at low to neutral pH, when the sapphire surface is positively charged, and at low ionic strength (l=15 mM NaCl). Coverage decreased at higher pH, close to the isoelectric point of sapphire, and also at high I>210mM, or with addition of 2mM Ca2+. The latter two effects are additive, suggesting that Ca2+ mitigates the effect of higher I. These trends agree with previous results for phospholipid adsorption on a-Al2O3 particles determined by adsorption isotherms and on single-crystal (1010) sapphire by atomic force microscopy, suggesting consistency of oxide surface chemistry-dependent effects across experimental techniques.

  10. SO2 frost - UV-visible reflectivity and Io surface coverage

    Science.gov (United States)

    Nash, D. B.; Fanale, F. P.; Nelson, R. M.

    1980-01-01

    The reflectance spectrum in the range 0.24-0.85 microns of SO2 frost is measured in light of the discovery of SO2 gas in the atmosphere of Io and the possible discovery of the frost on its surface. Frost deposits up to 1.5 mm thick were grown in vacuum at 130 K and bi-directional reflectance spectra were obtained. Typical SO2 frost is found to exhibit very low reflectivity (2-5%) at 0.30 microns, rising steeply at 0.32 microns to attain a maximum reflectivity (75-80%) at 4.0 microns and uniformly high reflectivity throughout the visible and near infrared. Comparison with the full disk spectrum of Io reveals that no more than 20% of the surface can be covered with optically thick SO2 frost. Combinations of surface materials including SO2 frost which can produce the observed spectrum are indicated.

  11. Perceived Average Orientation Reflects Effective Gist of the Surface.

    Science.gov (United States)

    Cha, Oakyoon; Chong, Sang Chul

    2018-03-01

    The human ability to represent ensemble visual information, such as average orientation and size, has been suggested as the foundation of gist perception. To effectively summarize different groups of objects into the gist of a scene, observers should form ensembles separately for different groups, even when objects have similar visual features across groups. We hypothesized that the visual system utilizes perceptual groups characterized by spatial configuration and represents separate ensembles for different groups. Therefore, participants could not integrate ensembles of different perceptual groups on a task basis. We asked participants to determine the average orientation of visual elements comprising a surface with a contour situated inside. Although participants were asked to estimate the average orientation of all the elements, they ignored orientation signals embedded in the contour. This constraint may help the visual system to keep the visual features of occluding objects separate from those of the occluded objects.

  12. Extreme Ultraviolet Bragg mirrors with suppressed infrared reflectivity properties

    NARCIS (Netherlands)

    Medvedev, Viacheslav; Yakshin, Andrey; Louis, Eric; van de Kruijs, Robbert Wilhelmus Elisabeth; van den Boogaard, Toine; Krivtsun, V.M.; Yakinun, A.M.; Bijkerk, Frederik

    2013-01-01

    Many optical applications demand high reflectivity in a particular wavelength range while simultaneously requiring suppression of radiation outside this range. Such parasitic radiation can for instance lead to image distortions in imaging applications or poor signal-noise ratios in spectroscopy. The

  13. Extreme Ultraviolet Bragg mirrors with suppressed infrared reflectivity properties

    NARCIS (Netherlands)

    Medvedev, Viacheslav; Yakshin, Andrey; Louis, Eric; van de Kruijs, Robbert Wilhelmus Elisabeth; van den Boogaard, Toine; Krivtsun, V.M.; Yakunin, A.M.; Bijkerk, Frederik

    2012-01-01

    Many optical applications demand high reflectivity in a particular wavelength range while simultaneously requiring suppression of radiation outside this range. Such parasitic radiation can for instance lead to image distortions in imaging applications or poor signal-noise ratios in spectroscopy. The

  14. Surface properties of copper based cermet materials

    International Nuclear Information System (INIS)

    Voinea, M.; Vladuta, C.; Bogatu, C.; Duta, A.

    2008-01-01

    The paper presents the characterization of the surface properties of copper based cermets obtained by two different techniques: spray pyrolysis deposition (SPD) and electrodeposition. Copper acetate was used as precursor of Cu/CuO x cermet. The surface morphology was tailored by adding copolymers of maleic anhydride with controlled hydrophobia. The films morphology of Cu/CuO x was assessed using contact angle measurements and AFM analysis. The porous structures obtained via SPD lead to higher liquid adsorption rate than the electrodeposited films. A highly polar liquid - water is recommended as testing liquid in contact angle measurements, for estimating the porosity of copper based cermets, while glycerol can be used to distinguish among ionic and metal predominant structures. Thus, contact angle measurements can be used for a primary evaluation of the films morphology and, on the other hand, of the ratio between the cermet components

  15. Evaluation of BRDF Archetypes for Representing Surface Reflectance Anisotropy Using MODIS BRDF Data

    OpenAIRE

    Zhang, Hu; Jiao, Ziti; Dong, Yadong; Li, Xiaowen

    2015-01-01

    Bidirectional reflectance distribution function (BRDF) archetypes extracted from the Moderate Resolution Imaging Spectroradiometer (MODIS) BRDF/Albedo product over the global Earth Observing System Land Validation Core Sites can be used to simplify BRDF models. The present study attempts to evaluate the representativeness of BRDF archetypes for surface reflectance anisotropy. Five-year forward-modeled MODIS multi-angular reflectance (MCD-ref) and aditional actual MODIS multi-angular observat...

  16. Surface roughness and gloss study of prints: application of specular reflection at near infrared

    International Nuclear Information System (INIS)

    Silfsten, P; Dutta, R; Pääkkönen, P; Peiponen, K-E; Tåg, C-M; Gane, P A C

    2012-01-01

    Absolute reflectance data were measured with a spectrophotometer in the visible and near infrared (NIR) spectral range. The specular reflectance data in the NIR were used for the assessment of the surface roughness of magenta, yellow, cyan and black prints on paper. In addition, surface roughness data obtained from the prints with a mechanical diamond stylus, an optical profiling system and the spectrophotometer are compared with each other. The surface roughness obtained with the aid of the spectrophotometer data suggests a smoother surface than when measured with the diamond stylus and the optical profiling system. The gloss of the prints can be obtained from the absolute specular reflectance spectra in the spectral region of visible light. It is shown that specular reflection data at a fixed wavelength in the NIR are useful also in the interpretation of gloss in the visible spectral range, but using an unconventional grazing angle of incidence. (paper)

  17. NOAA Climate Data Record (CDR) of AVHRR Surface Reflectance, Version 4

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This dataset contains gridded daily surface reflectance and brightness temperatures derived from the Advanced Very High Resolution Radiometer (AVHRR) sensors onboard...

  18. LiDAR Relative Reflectivity Surface (2011) for the St. Thomas East End Reserve, St. Thomas

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This image represents a LiDAR (Light Detection & Ranging) 0.3x0.3 meter resolution relative seafloor reflectivity surface for the St. Thomas East End Reserve...

  19. A new approach to the retrieval of surface properties from earthshine measurements

    Energy Technology Data Exchange (ETDEWEB)

    Spurr, R.J.D. E-mail: rspurr@cfa.harvard.edu

    2004-01-01

    Instruments such as the MODIS and MISR radiometers on EOS AM-1, and POLDER on ADEOS have been deployed for the remote sensing retrieval of surface properties. Typically, retrieval algorithms use linear combinations of semi-empirical bidirectional reflectance distribution function (BRDF) kernels to model surface reflectance. The retrieval proceeds in two steps; first, an atmospheric correction relates surface BRDF to top-of-atmosphere (TOA) reflectances, then regression is used to establish the linear coefficients used in the kernel combination. BRDF kernels may also depend on a number of physical or empirical non-linear parameters (e.g. ocean wind speed for a specular BRDF); such parameters are usually assumed known. A major source of error in this retrieval comes from lack of knowledge of planetary boundary layer (PBL) aerosol properties. In this paper, we present a different approach to surface property retrieval. For the radiative transfer simulations, we use the discrete ordinate LIDORT model, which has the capability to generate simultaneous fields of radiances and weighting functions in a multiply scattering multi-layer atmosphere. Surface-atmosphere coupling due to multiple scattering and reflection effects is treated in full; the use of an atmospheric correction is not required. Further, it is shown that sensitivities of TOA reflectances to both linear and non-linear surface BRDF parameters may be established directly by explicit analytic differentiation of the discrete ordinate radiative transfer equations. Surface properties may thus be retrieved directly and conveniently from satellite measurements using standard non-linear fitting methods. In the fitting for BRDF parameters, lower-boundary aerosol properties can either be retrieved as auxiliary parameters, or they can be regarded as forward model parameter errors. We present examples of simulated radiances and surface/aerosol weighting functions for combinations of multi-angle measurements at several

  20. A new approach to the retrieval of surface properties from earthshine measurements

    International Nuclear Information System (INIS)

    Spurr, R.J.D.

    2004-01-01

    Instruments such as the MODIS and MISR radiometers on EOS AM-1, and POLDER on ADEOS have been deployed for the remote sensing retrieval of surface properties. Typically, retrieval algorithms use linear combinations of semi-empirical bidirectional reflectance distribution function (BRDF) kernels to model surface reflectance. The retrieval proceeds in two steps; first, an atmospheric correction relates surface BRDF to top-of-atmosphere (TOA) reflectances, then regression is used to establish the linear coefficients used in the kernel combination. BRDF kernels may also depend on a number of physical or empirical non-linear parameters (e.g. ocean wind speed for a specular BRDF); such parameters are usually assumed known. A major source of error in this retrieval comes from lack of knowledge of planetary boundary layer (PBL) aerosol properties. In this paper, we present a different approach to surface property retrieval. For the radiative transfer simulations, we use the discrete ordinate LIDORT model, which has the capability to generate simultaneous fields of radiances and weighting functions in a multiply scattering multi-layer atmosphere. Surface-atmosphere coupling due to multiple scattering and reflection effects is treated in full; the use of an atmospheric correction is not required. Further, it is shown that sensitivities of TOA reflectances to both linear and non-linear surface BRDF parameters may be established directly by explicit analytic differentiation of the discrete ordinate radiative transfer equations. Surface properties may thus be retrieved directly and conveniently from satellite measurements using standard non-linear fitting methods. In the fitting for BRDF parameters, lower-boundary aerosol properties can either be retrieved as auxiliary parameters, or they can be regarded as forward model parameter errors. We present examples of simulated radiances and surface/aerosol weighting functions for combinations of multi-angle measurements at several

  1. Accounting for surface reflectance anisotropy in satellite retrievals of tropospheric NO₂

    NARCIS (Netherlands)

    Zhou, Yipin; Brunner, D.; Spurr, R.J.D.; Boersma, K.F.; Sneep, M.; Popp, C.; Buchmann, B.

    2010-01-01

    Surface reflectance is a key parameter in satellite trace gas retrievals in the UV/visible range and in particular for the retrieval of nitrogen dioxide (NO2) vertical tropospheric columns (VTCs). Current operational retrievals rely on coarse-resolution reflectance data and do not account for the

  2. Backscattered EM-wave manipulation using low cost 1-bit reflective surface at W-band

    Science.gov (United States)

    Taher Al-Nuaimi, Mustafa K.; Hong, Wei; He, Yejun

    2018-04-01

    The design of low cost 1-bit reflective (non-absorptive) surfaces for manipulation of backscattered EM-waves and radar cross section (RCS) reduction at W-band is presented in this article. The presented surface is designed based on the reflection phase cancellation principle. The unit cell used to compose the proposed surface has an obelus (division symbol of short wire and two disks above and below) like shape printed on a grounded dielectric material. Using this unit cell, surfaces that can efficiently manipulate the backscattered RCS pattern by using the proposed obelus-shaped unit cell (as ‘0’ element) and its mirrored unit cell (as ‘1’ element) in one surface with a 180°  ±  35° reflection phase difference between their reflection phases are designed. The proposed surfaces can generate various kinds of backscattered RCS patterns, such as single, three, or four lobes or even a low-level (reduced RCS) diffused reflection pattern when those two unit cells are distributed randomly across the surface aperture. For experimental characterization purposes, a 50  ×  50 mm2 surface is fabricated and measured.

  3. Patellar Skin Surface Temperature by Thermography Reflects Knee Osteoarthritis Severity

    Directory of Open Access Journals (Sweden)

    Anna E. Denoble

    2010-01-01

    Full Text Available Background Digital infrared thermal imaging is a means of measuring the heat radiated from the skin surface. Our goal was to develop and assess the reproducibility of serial infrared measurements of the knee and to assess the association of knee temperature by region of interest with radiographic severity of knee Osteoarthritis (rOA. Methods A total of 30 women (15 Cases with symptomatic knee OA and 15 age-matched Controls without knee pain or knee OA participated in this study. Infrared imaging was performed with a Meditherm Med2000™ Pro infrared camera. The reproducibility of infrared imaging of the knee was evaluated through determination of intraclass correlation coefficients (ICCs for temperature measurements from two images performed 6 months apart in Controls whose knee status was not expected to change. The average cutaneous temperature for each of five knee regions of interest was extracted using WinTes software. Knee x-rays were scored for severity of rOA based on the global Kellgren-Lawrence grading scale. Results The knee infrared thermal imaging procedure used here demonstrated long-term reproducibility with high ICCs (0.50–0.72 for the various regions of interest in Controls. Cutaneous temperature of the patella (knee cap yielded a significant correlation with severity of knee rOA (R = 0.594, P = 0.02. Conclusion The skin temperature of the patellar region correlated with x-ray severity of knee OA. This method of infrared knee imaging is reliable and as an objective measure of a sign of inflammation, temperature, indicates an interrelationship of inflammation and structural knee rOA damage.

  4. Patellar skin surface temperature by thermography reflects knee osteoarthritis severity.

    Science.gov (United States)

    Denoble, Anna E; Hall, Norine; Pieper, Carl F; Kraus, Virginia B

    2010-10-15

    Digital infrared thermal imaging is a means of measuring the heat radiated from the skin surface. Our goal was to develop and assess the reproducibility of serial infrared measurements of the knee and to assess the association of knee temperature by region of interest with radiographic severity of knee Osteoarthritis (rOA). A total of 30 women (15 Cases with symptomatic knee OA and 15 age-matched Controls without knee pain or knee OA) participated in this study. Infrared imaging was performed with a Meditherm Med2000™ Pro infrared camera. The reproducibility of infrared imaging of the knee was evaluated through determination of intraclass correlation coefficients (ICCs) for temperature measurements from two images performed 6 months apart in Controls whose knee status was not expected to change. The average cutaneous temperature for each of five knee regions of interest was extracted using WinTes software. Knee x-rays were scored for severity of rOA based on the global Kellgren-Lawrence grading scale. The knee infrared thermal imaging procedure used here demonstrated long-term reproducibility with high ICCs (0.50-0.72 for the various regions of interest) in Controls. Cutaneous temperature of the patella (knee cap) yielded a significant correlation with severity of knee rOA (R = 0.594, P = 0.02). The skin temperature of the patellar region correlated with x-ray severity of knee OA. This method of infrared knee imaging is reliable and as an objective measure of a sign of inflammation, temperature, indicates an interrelationship of inflammation and structural knee rOA damage.

  5. MODIS/Aqua Near Real Time (NRT) Surface Reflectance Daily L2G Global 250m SIN Grid

    Data.gov (United States)

    National Aeronautics and Space Administration — The MODIS Near Real Time (NRT) Surface Reflectance products are an estimate of the surface spectral reflectance as it would be measured at ground level in the...

  6. [Experimental Methods and Result Analysis of a Variety of Spectral Reflectance Properties of the Thin Oil Film].

    Science.gov (United States)

    Ye, Zhou; Liu, Li; Wei, Chuan-xin; Gu, Qun; An, Ping-ao; Zhao, Yue-jiao; Yin, Da-yi

    2015-06-01

    In order to analysis the oil spill situation based on the obtained data in airborne aerial work, it's needed to get the spectral reflectance characteristics of the oil film of different oils and thickness as support and to select the appropriate operating band. An experiment is set up to measure the reflectance spectroscopy from ultraviolet to near-infrared for the film of five target samples, which means petrol, diesel, lubricating oil, kerosene and fossil, using spectral measurement device. The result is compared with the reflectance spectra of water in the same experimental environment, which shows that the spectral reflection characteristics of the oil film are related to the thickness and the type of the oil film. In case of the same thickness, the spectral reflectance curve of different types of film is far different, and for the same type of film, the spectral reflectance curve changes accordingly with the change of film thickness, therefore in terms of the single film, different film thickness can be distinguished by reflectance curves. It also shows that in terms of the same film thickness, the reflectance of diesel, kerosene, lubricants reaches peak around 380 nm wavelength, obviously different from the reflectance of water, and that the reflectance of crude oil is far less than that of water in more than 340 nm wavelength, and the obtained reflection spectrum can be used to distinguish between different types of oil film to some extent. The experiment covers main types of spilled oil, with data comprehensively covering commonly used detect spectral bands, and quantitative description of the spectral reflectance properties of film. It provides comprehensive theoretical and data support for the selection of airborne oil spill detection working band and the detection and analysis of water-surface oil spill.

  7. Effects of a Chitosan Coating Layer on the Surface Properties and Barrier Properties of Kraft Paper

    Directory of Open Access Journals (Sweden)

    Shanhui Wang

    2016-01-01

    Full Text Available Biodegradable chitosan can be applied as a coating on the surface of kraft paper in order to improve its barrier properties against water vapor and air. The food packaging industry can benefit from the addition of chitosan to its current packaging, and in turn reduce pollution from plastic packaging plants. This paper discusses the film formation of chitosan, the permeability of paper coated with a chitosan layer, and the influence on the paper’s surface and barrier properties under different process conditions. SEM (scanning electron microscope, AFM (atomic force microscope, ATR-FTIR (Fourier transmission infrared spectroscope with attenuated total reflection, and PDA (penetration dynamics analysis were used to analyze the properties of chitosan’s film formation and permeability. A controlled experiment showed that the chitosan layer was smoother than the surface of the uncoated kraft paper, had better film formation, and that there was no chitosan penetration through the kraft paper. The barrier properties against water vapor were strongest when there was a higher concentration of chitosan solution at the optimum pH, stirring speed, and those with a thicker coating on the kraft paper.

  8. A new theory and its application to remove the effect of surface-reflected light in above-surface radiance data from clear and turbid waters

    International Nuclear Information System (INIS)

    Dev, Pravin Jeba; Shanmugam, Palanisamy

    2014-01-01

    Water-leaving radiances (L w ) measured from the deck of a ship or boat in oceanic and lake waters are widely and operationally used for satellite sensor vicarious calibration and validation and development of remote-sensing algorithms to understand interdisciplinary coastal ocean properties and processes. However, accurate determination of L w remains to be a challenging issue because of the limitations of the existing methods to accurately remove the undesired signal (surface-reflected light of the sky and sun) from above-surface measurements of the total upwelling radiance leaving the water surface. In this study, a new theory is developed and applied to the above-surface radiometric data measured from clear, turbid and eutrophic waters. The new method effectively removes surface-reflected contributions from the total upwelling radiance signal under different sky (clear sky to overcast sky) and sun glint conditions. The L w spectra obtained from the above-surface radiance data using the new method are found to match well with those extrapolated from the upwelling radiances (L u ) measured with another set of underwater radiometers (used just below the sea surface). The new method proves to be a viable alternative, especially in circumstances when the above-surface measurements of radiances are severally contaminated by the surface-reflected light fields. Since spectral radiance measurements are also sensitive to the observation angles, and to the magnitude of the radiometer's solid angle field of view, above-surface radiances are also measured for different viewing angles in highly eutrophic waters. Such measurements show large deviations in L w spectra except at lower viewing angles (30°). When applied to these data, the new method eliminates the undesired signal encountered at higher viewing angles and delivers accurate water-leaving radiance data. These results suggest that the new method is capable of removing the surface-reflected light fields from both

  9. Study of optical and electronic properties of nickel from reflection electron energy loss spectra

    Science.gov (United States)

    Xu, H.; Yang, L. H.; Da, B.; Tóth, J.; Tőkési, K.; Ding, Z. J.

    2017-09-01

    We use the classical Monte Carlo transport model of electrons moving near the surface and inside solids to reproduce the measured reflection electron energy-loss spectroscopy (REELS) spectra. With the combination of the classical transport model and the Markov chain Monte Carlo (MCMC) sampling of oscillator parameters the so-called reverse Monte Carlo (RMC) method was developed, and used to obtain optical constants of Ni in this work. A systematic study of the electronic and optical properties of Ni has been performed in an energy loss range of 0-200 eV from the measured REELS spectra at primary energies of 1000 eV, 2000 eV and 3000 eV. The reliability of our method was tested by comparing our results with the previous data. Moreover, the accuracy of our optical data has been confirmed by applying oscillator strength-sum rule and perfect-screening-sum rule.

  10. X-ray Reflectivity Study of Ionic Liquids at Electrified Surfaces

    Science.gov (United States)

    Chu, Miaoqi

    X-ray reflectivity (XRR) versatile technique that characterize the surface structures. However, due to the lack of phase information of X-ray data, the reconstruction of electron density profile (EDP) from XRR data is an ill-posed inverse problem that requires extra attention. In Chapter 1, several key concepts in XRR data analysis are reviewed. The typical XRR data acquisition procedure and methods of modeling electron density are introduced. The widely used logarithm form of merit function is justified with mathematical deduction and numerical experiment. A scheme that generates artificial reflectivity data with theoretical statistical error but not systematical error is proposed. With the methods and schemes described in Chapter 1, simulated reflectivity data of a simple one-slab model is generated and fitted to test the efficient of EDP reconstruction. By isolating the parameters, the effects of slab width, electron density contrast and maximal wave transfer are studied individually. It?s demonstrated that best-fit/global minima, result reported by most XRR studies, don?t necessary reflect the real EDP. By contrast, mapping the merit function in the parametric space can capture much more details. Additionally, the widely accepted concept about the XRR theoretical spatial resolution (pi/q_{max}) as well the using Patterson function are brought to test. In the perspective of XRR data analysis, this chapter puts forward general rules to design and optimize XRR experiments. It also demonstrates how susceptible the fitting result will be if it?s not done carefully. In Chapter 3, the interface between hydrophobic OTS film and several solvents is studied with XRR in a transmission-cell setup. The solvents, from water, acetone, to alcohol (methanol, ethanol, 1-propanol), to alkane (pentane, hexane and heptane), vary significantly in terms of polarity and hydrogen bonding. However, the XRR data from different solvents are subtle. The methods and principles elicited in

  11. Reflections

    Directory of Open Access Journals (Sweden)

    Joanne Embree

    2001-01-01

    Full Text Available Ideally, editorials are written one to two months before publication in the Journal. It was my turn to write this one. I had planned to write the first draft the evening after my clinic on Tuesday, September 11. It didn't get done that night or during the next week. Somehow, the topic that I had originally chosen just didn't seem that important anymore as I, along my friends and colleagues, reflected on the changes that the events of that day were likely to have on our lives.

  12. Reflection of illumination laser from gas metal arc weld pool surface

    International Nuclear Information System (INIS)

    Ma, Xiaoji; Zhang, YuMing

    2009-01-01

    The weld pool is the core of the welding process where complex welding phenomena originate. Skilled welders acquire their process feedback primarily from the weld pool. Observation and measurement of the three-dimensional weld pool surface thus play a fundamental role in understanding and future control of complex welding processes. To this end, a laser line is projected onto the weld pool surface in pulsed gas metal arc welding (GMAW) and an imaging plane is used to intercept its reflection from the weld pool surface. Resultant images of the reflected laser are analyzed and it is found that the weld pool surface in GMAW does specularly reflect the projected laser as in gas tungsten arc welding (GTAW). Hence, the weld pool surface in GMAW is also specular and it is in principle possible that it may be observed and measured by projecting a laser pattern and then intercepting and imaging the reflection from it. Due to high frequencies of surface fluctuations, GMAW requires a relatively short time to image the reflected laser

  13. Study on the effect of ambient gas on nanostructure formation on metal surfaces during femtosecond laser ablation for fabrication of low-reflective surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Smausz, Tomi, E-mail: tomi@physx.u-szeged.hu [MTA-SZTE Research Group on Photoacoustic Spectroscopy, University of Szeged, 6720 Szeged, Dóm tér 9 (Hungary); Department of Optics and Quantum Electronics, University of Szeged, H-6720 Szeged, Dóm tér 9 (Hungary); Csizmadia, Tamás [Department of Optics and Quantum Electronics, University of Szeged, H-6720 Szeged, Dóm tér 9 (Hungary); Attosecond Light Pulse Source, ELI-Hu Nkft, H-6720 Szeged, Dugonics ter 13 (Hungary); Tápai, Csaba; Kopniczky, Judit [Department of Optics and Quantum Electronics, University of Szeged, H-6720 Szeged, Dóm tér 9 (Hungary); Oszkó, Albert [Department of Physical Chemistry and Material Science, University of Szeged, H-6720 Szeged, Aradi vértanuk tere 1 (Hungary); Ehrhardt, Martin; Lorenz, Pierre; Zimmer, Klaus; Prager, Andrea [Leibniz-Institut für Oberflächenmodifizierung e.V., Permoserstr. 15, 04318 Leipzig (Germany); Hopp, Béla [Department of Optics and Quantum Electronics, University of Szeged, H-6720 Szeged, Dóm tér 9 (Hungary)

    2016-12-15

    Highlights: • Metal surfaces were irradiated with femtosecond laser in different gas environments. • The reflectivity, morphology and chemical composition of the surfaces were studied. • Darkening was influenced by chemical and physical interaction of the plume and gas. • Molecular mass of the applied gas had an impact on the nanostructure formation. • For some of the used metals the oxide formation affected the reflective properties. - Abstract: Nanostructure formation on bulk metals (silver, gold, copper and titanium) by femtosecond Ti-sapphire laser irradiation (775 nm, 150 fs) is studied aiming the production of low-reflectivity surfaces and the better understanding of the development process. The experiments were performed in nitrogen, air, oxygen and helium environments at atmospheric pressure. The samples were irradiated with fluences in the 0.1–2 J/cm{sup 2} range and an average pulse number of 100 falling over a given area. The reflectivity of the treated surfaces was determined by a microspectrometer in the 450–800 nm range and their morphology was studied by scanning electron microscopy. The gas ambience influenced the results via two effects: formation processes and the chemically-induced modifications of the nanostructures. In case of He the nanoparticle aggregates–otherwise generally present–are predominantly missing, which leads to a lower darkening efficiency. The presence of oxygen enhances the darkening effect for copper mostly at lower fluences, while causes a slow increase in reflectivity in the case of titanium (in case of pure oxygen) in the high fluence range. The surface morphology in case of nitrogen and air were quite similar probably due to their close molecular mass values.

  14. Surface properties correlate to the digestibility of hydrothermally pretreated lignocellulosic Poaceae biomass feedstocks

    DEFF Research Database (Denmark)

    Tristan Djajadi, Demi; Hansen, Aleksander R.; Jensen, Anders

    2017-01-01

    physical and chemical features of the biomass surfaces, specifically contact angle measurements (wettability) and attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectroscopy (surfacebiopolymer composition) produced data correlating pretreatment severity and enzymatic digestibility......, and they also revealed differences that correlated to enzymatic glucose yield responses among the three different biomass types. Conclusion: The study revealed that to a large extent, factors related to physico-chemical surface properties, namely surface wettability as assessed by contact angle measurements...

  15. Bio-inspired, subwavelength surface structures to control reflectivity, transmission, and scattering in the infrared

    Science.gov (United States)

    Lora Gonzalez, Federico

    Controlling the reflection of visible and infrared (IR) light at interfaces is extremely important to increase the power efficiency and performance of optics, electro-optical and (thermo)photovoltaic systems. The eye of the moth has evolved subwavelength protuberances that increase light transmission into the eye tissue and prevent reflection. The subwavelength protuberances effectively grade the refractive index from that of air (n=1) to that of the tissue (n=1.4), making the interface gradual, suppressing reflection. In theory, the moth-eye (ME) structures can be implemented with any material platform to achieve an antireflectance effect by scaling the pitch and size of protuberances for the wavelength range of interest. In this work, a bio-inspired, scalable and substrate-independent surface modification protocol was developed to realize broadband antireflective structures based on the moth-eye principle. Quasi-ordered ME arrays were fabricated in IR relevant materials using a colloidal lithography method to achieve highly efficient, omni-directional transmission of mid and far infrared (IR) radiation. The effect of structure height and aspect ratio on transmittance and scattering is explored, with discussion on experimental techniques and effective medium theory (EMT). The highest aspect ratio structures (AR = 9.4) achieved peak single-side transmittance of 98%, with >85% transmission for lambda = 7--30 microns. A detailed photon balance constructed by transmission, forward scattering, specular reflection and diffuse reflection measurements to quantify optical losses due to near-field effects will be discussed. In addition, angle-dependent transmission measurements showed that moth-eye structures provide superior antireflective properties compared to unstructured interfaces over a wide angular range (0--60° incidence). Finally, subwavelength ME structures are incorporated on a Si substrate to enhance the absorption of near infrared (NIR) light in PtSi films to

  16. Inherent optical properties and remote sensing reflectance of Pomeranian lakes (Poland

    Directory of Open Access Journals (Sweden)

    Dariusz Ficek

    2012-11-01

    Full Text Available This paper describes the results of comprehensive empirical studies of theinherent optical properties (IOPs, the remote sensing reflectance Rrs(λ andthe contents of the principal optically active components (OAC i.e. coloureddissolved organic matter (CDOM, suspended particulate matter (SPM andchlorophyll a, in the waters of 15 lakes in Polish Pomerania in 2007-2010.It presents numerous spectra of the total absorption a(λ andscattering b(λ ≈ bp(λ of light in the visibleband (400-700 nm for surface waters, and separately, spectra of absorptionby CDOM aCDOM(λ and spectra of the mass-specificcoefficients of absorption ap*(SPM(λ and scatteringbp*(SPM(λ by SPM. The properties of these lake waters are highly diverse, but all of them can beclassified as Case 2 waters (according to the optical classification by Morel& Prieur 1977 and they all have a relatively high OAC content. The lakeswere conventionally divided into three types: Type I lakes have the lowestOAC concentrations (chlorophyll concentration Ca = (8.76 ± 7.4 mg m-3 and CDOM absorption coefficientsaCDOM(440 = (0.57 ± 0.22 m-1 (i.e. mean and standarddeviation, and optical properties (including spectra of Rrs(λresembling those of Baltic waters. Type II waters have exceptionally highcontents of CDOM (aCDOM(440 = (15.37 ± 1.54 m-1,and hence appear brown in daylight and have very low reflectancesRrs(λ (of the order of 0.001 sr-1. Type III waters arehighly eutrophic and contain large amounts of suspended matter, includingphytoplankton ((CSPM = (47.0 ± 39.4 g m-3,Ca = (86.6 ± 61.5 mg m-3; aCDOM(440 = (2.77 ± 0.86 m-1. Hence the reflectances Rrs(λof these type of waters are on average one order of magnitude higher thanthose of the other natural waters, reaching maximum values of 0.03 sr-1in λ bands 560-580 nm and 690-720 nm (see Ficek et al. 2011. Thearticle provides a number of empirical formulas approximating therelationships between the properties of these lake waters.

  17. Estimates of radiance reflected towards the zenith at the surface of the sea

    Directory of Open Access Journals (Sweden)

    E. Aas

    2010-10-01

    Full Text Available Remote sensing of water colour by ship-mounted sensors represents an important tool for the validation of satellite products and the monitoring of water quality. The recorded radiance from the sea has to be corrected for the surface-reflected radiance from sun and sky in order to obtain the water-leaving radiance. Here the simple case of radiance reflected towards the zenith is studied. A set of observed sky radiance and solar irradiance data from Oslo has been used together with a Gaussian slope distribution for the sea surface in order to estimate the reflected radiance. The spectral range studied is 405–650 nm, the solar zenith angles are in the range 37°–76°, and the wind speeds are up to 10 m s−1. The analysis of the results show that the reflected radiance has to be separated into three contributions: sky radiance and sun rays reflected at the foam-free surface and irradiance reflected by whitecaps and foam. It is then demonstrated that by using four input values, namely the downward irradiance, the sky radiance from the zenith, the solar zenith angle and the wind speed, it is possible to obtain by simple expressions estimates of the reflected radiance that only differ from the former calculated values by relative errors of less than 5%. The analysis also indicates that for the spectral range studied neither the water-leaving radiance nor the surface-reflected radiance can be disregarded relative to the other one in the Case 2 waters of the Oslofjord-Skagerrak area. The results form a first step towards the study of reflected radiance in viewing angles differing from the nadir direction.

  18. Size- and shape-dependent surface thermodynamic properties of nanocrystals

    Science.gov (United States)

    Fu, Qingshan; Xue, Yongqiang; Cui, Zixiang

    2018-05-01

    As the fundamental properties, the surface thermodynamic properties of nanocrystals play a key role in the physical and chemical changes. However, it remains ambiguous about the quantitative influence regularities of size and shape on the surface thermodynamic properties of nanocrystals. Thus by introducing interface variables into the Gibbs energy and combining Young-Laplace equation, relations between the surface thermodynamic properties (surface Gibbs energy, surface enthalpy, surface entropy, surface energy and surface heat capacity), respectively, and size of nanocrystals with different shapes were derived. Theoretical estimations of the orders of the surface thermodynamic properties of nanocrystals agree with available experimental values. Calculated results of the surface thermodynamic properties of Au, Bi and Al nanocrystals suggest that when r > 10 nm, the surface thermodynamic properties linearly vary with the reciprocal of particle size, and when r < 10 nm, the effect of particle size on the surface thermodynamic properties becomes greater and deviates from linear variation. For nanocrystals with identical equivalent diameter, the more the shape deviates from sphere, the larger the surface thermodynamic properties (absolute value) are.

  19. Microwave reflection measurements of the dielectric properties of concrete : final report.

    Science.gov (United States)

    1983-01-01

    The use of microwave reflection measurements to continuously and nondestructively monitor the hydration of concrete is described. The method relies upon the influence of the free-water content on the dielectric properties of the concrete. Use of the ...

  20. Iterative discrete ordinates solution of the equation for surface-reflected radiance

    Science.gov (United States)

    Radkevich, Alexander

    2017-11-01

    This paper presents a new method of numerical solution of the integral equation for the radiance reflected from an anisotropic surface. The equation relates the radiance at the surface level with BRDF and solutions of the standard radiative transfer problems for a slab with no reflection on its surfaces. It is also shown that the kernel of the equation satisfies the condition of the existence of a unique solution and the convergence of the successive approximations to that solution. The developed method features two basic steps: discretization on a 2D quadrature, and solving the resulting system of algebraic equations with successive over-relaxation method based on the Gauss-Seidel iterative process. Presented numerical examples show good coincidence between the surface-reflected radiance obtained with DISORT and the proposed method. Analysis of contributions of the direct and diffuse (but not yet reflected) parts of the downward radiance to the total solution is performed. Together, they represent a very good initial guess for the iterative process. This fact ensures fast convergence. The numerical evidence is given that the fastest convergence occurs with the relaxation parameter of 1 (no relaxation). An integral equation for BRDF is derived as inversion of the original equation. The potential of this new equation for BRDF retrievals is analyzed. The approach is found not viable as the BRDF equation appears to be an ill-posed problem, and it requires knowledge the surface-reflected radiance on the entire domain of both Sun and viewing zenith angles.

  1. Spectral and spatial properties of polarized light reflections from the arms of squid (Loligo pealeii) and cuttlefish (Sepia officinalis L.).

    Science.gov (United States)

    Chiou, Tsyr-Huei; Mäthger, Lydia M; Hanlon, Roger T; Cronin, Thomas W

    2007-10-01

    On every arm of cuttlefish and squid there is a stripe of high-reflectance iridophores that reflects highly polarized light. Since cephalopods possess polarization vision, it has been hypothesized that these polarized stripes could serve an intraspecific communication function. We determined how polarization changes when these boneless arms move. By measuring the spectral and polarizing properties of the reflected light from samples at various angles of tilt and rotation, we found that the actual posture of the arm has little or no effect on partial polarization or the e-vector angle of the reflected light. However, when the illumination angle changed, the partial polarization of the reflected light also changed. The spectral reflections of the signals were also affected by the angle of illumination but not by the orientation of the sample. Electron microscope samples showed that these stripes are composed of several groups of multilayer platelets within the iridophores. The surface normal to each group is oriented at a different angle, which produces essentially constant reflection of polarized light over a range of viewing angles. These results demonstrate that cuttlefish and squid could send out reliable polarization signals to a receiver regardless of arm orientation.

  2. Manifestation of surface phonons in far infrared reflectivity of diamond-type semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    Perez-Sanchez, F.L.; Perez-Rodriguez, F. [Instituto de Fisica, Universidad Autonoma de Puebla, Apdo. Post. J-48, Puebla, Pue. 72570 (Mexico)

    2004-11-01

    The coupling of surface phonons with light at (001) surfaces of diamond-structure crystals and its manifestation in far-infrared anisotropy spectra are theoretically studied. We apply the adiabatic bond charge model to describe short-range mechanical interactions together with long-range Coulomb forces and radiation fields, and we solve the corresponding system of coupled equations for the electromagnetic field and the lattice vibrations. We calculate far-infrared normal reflectance spectra of (001) surfaces of semi-infinite diamond-type crystals. In particular, we analyse reflectance spectra for the Si(001) (2 x 1) surface, which exhibit a resonance structure associated with the excitation of surface phonon modes. (copyright 2004 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  3. Developmental prosopagnosia and super-recognition: no special role for surface reflectance processing.

    Science.gov (United States)

    Russell, Richard; Chatterjee, Garga; Nakayama, Ken

    2012-01-01

    Face recognition by normal subjects depends in roughly equal proportions on shape and surface reflectance cues, while object recognition depends predominantly on shape cues. It is possible that developmental prosopagnosics are deficient not in their ability to recognize faces per se, but rather in their ability to use reflectance cues. Similarly, super-recognizers' exceptional ability with face recognition may be a result of superior surface reflectance perception and memory. We tested this possibility by administering tests of face perception and face recognition in which only shape or reflectance cues are available to developmental prosopagnosics, super-recognizers, and control subjects. Face recognition ability and the relative use of shape and pigmentation were unrelated in all the tests. Subjects who were better at using shape or reflectance cues were also better at using the other type of cue. These results do not support the proposal that variation in surface reflectance perception ability is the underlying cause of variation in face recognition ability. Instead, these findings support the idea that face recognition ability is related to neural circuits using representations that integrate shape and pigmentation information. Copyright © 2011 Elsevier Ltd. All rights reserved.

  4. Assessment of biases in MODIS surface reflectance due to Lambertian approximation

    Energy Technology Data Exchange (ETDEWEB)

    Cook, Robert B [ORNL; SanthanaVannan, Suresh K [ORNL

    2010-08-01

    Using MODIS data and the AERONET-based Surface Reflectance Validation Network (ASRVN), this work studies errors of MODIS atmospheric correction caused by the Lambertian approximation. On one hand, this approximation greatly simplifies the radiative transfer model, reduces the size of the look-up tables, and makes operational algorithm faster. On the other hand, uncompensated atmospheric scattering caused by Lambertian model systematically biases the results. For example, for a typical bowl-shaped bidirectional reflectance distribution function (BRDF), the derived reflectance is underestimated at high solar or view zenith angles, where BRDF is high, and is overestimated at low zenith angles where BRDF is low. The magnitude of biases grows with the amount of scattering in the atmosphere, i.e., at shorter wavelengths and at higher aerosol concentration. The slope of regression of Lambertian surface reflectance vs. ASRVN bidirectional reflectance factor (BRF) is about 0.85 in the red and 0.6 in the green bands. This error propagates into the MODIS BRDF/albedo algorithm, slightly reducing the magnitude of overall reflectance and anisotropy of BRDF. This results in a small negative bias of spectral surface albedo. An assessment for the GSFC (Greenbelt, USA) validation site shows the albedo reduction by 0.004 in the near infrared, 0.005 in the red, and 0.008 in the green MODIS bands.

  5. Comparison of cloud optical depth and cloud mask applying BRDF model-based background surface reflectance

    Science.gov (United States)

    Kim, H. W.; Yeom, J. M.; Woo, S. H.

    2017-12-01

    Over the thin cloud region, satellite can simultaneously detect the reflectance from thin clouds and land surface. Since the mixed reflectance is not the exact cloud information, the background surface reflectance should be eliminated to accurately distinguish thin cloud such as cirrus. In the previous research, Kim et al (2017) was developed the cloud masking algorithm using the Geostationary Ocean Color Imager (GOCI), which is one of significant instruments for Communication, Ocean, and Meteorology Satellite (COMS). Although GOCI has 8 spectral channels including visible and near infra-red spectral ranges, the cloud masking has quantitatively reasonable result when comparing with MODIS cloud mask (Collection 6 MYD35). Especially, we noticed that this cloud masking algorithm is more specialized in thin cloud detections through the validation with Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) data. Because this cloud masking method was concentrated on eliminating background surface effects from the top-of-atmosphere (TOA) reflectance. Applying the difference between TOA reflectance and the bi-directional reflectance distribution function (BRDF) model-based background surface reflectance, cloud areas both thick cloud and thin cloud can be discriminated without infra-red channels which were mostly used for detecting clouds. Moreover, when the cloud mask result was utilized as the input data when simulating BRDF model and the optimized BRDF model-based surface reflectance was used for the optimized cloud masking, the probability of detection (POD) has higher value than POD of the original cloud mask. In this study, we examine the correlation between cloud optical depth (COD) and its cloud mask result. Cloud optical depths mostly depend on the cloud thickness, the characteristic of contents, and the size of cloud contents. COD ranges from less than 0.1 for thin clouds to over 1000 for the huge cumulus due to scattering by droplets. With

  6. The role of random nanostructures for the omnidirectional anti-reflection properties of the glasswing butterfly

    Science.gov (United States)

    Siddique, Radwanul Hasan; Gomard, Guillaume; Hölscher, Hendrik

    2015-04-01

    The glasswing butterfly (Greta oto) has, as its name suggests, transparent wings with remarkable low haze and reflectance over the whole visible spectral range even for large view angles of 80°. This omnidirectional anti-reflection behaviour is caused by small nanopillars covering the transparent regions of its wings. In difference to other anti-reflection coatings found in nature, these pillars are irregularly arranged and feature a random height and width distribution. Here we simulate the optical properties with the effective medium theory and transfer matrix method and show that the random height distribution of pillars significantly reduces the reflection not only for normal incidence but also for high view angles.

  7. Determining the properties of dense matter: Superconductivity, bulk viscosity, and light reflection in compact stars

    Science.gov (United States)

    Good, Gerald J.

    In this dissertation, we investigate the properties of matter, denser than nuclei, that exists inside compact stars. First, we examine a mixed superfluid/superconductor system, which likely occurs in neutron star cores. We derive an effective theory of Cooper pair quasiparticles from a microscopic theory of nucleons, and calculate the coupling strengths between quasiparticles. We then calculate the structure of magnetic flux tubes, taking into consideration interactions between neutron and proton Cooper pairs. We find that interactions between the condensates can lead to interesting phenomena and new phases at the border between type-I and type-II behavior. Next, we examine the response of nuclear matter to vibrational modes by calculating the bulk viscosity from purely leptonic processes. We find that for hot neutron stars, the bulk viscosity due to leptons is very small compared to the bulk viscosity due to nucleons, but for cold neutron stars, the leptonic component is dominant. Finally, we derive the reflection and transmission properties of light at boundaries between phases of matter that have two independent U(1) generators, which may exist at the surface of "strange stars" or at boundaries between different phases of matter in a neutron star.

  8. Surface segregation of InGaAs films by the evolution of reflection high-energy electron diffraction patterns

    International Nuclear Information System (INIS)

    Zhou Xun; Luo Zi-Jiang; Guo Xiang; Zhang Bi-Chan; Shang Lin-Tao; Zhou Qing; Deng Chao-Yong; Ding Zhao

    2012-01-01

    Surface segregation is studied via the evolution of reflection high-energy electron diffraction (RHEED) patterns under different values of As 4 BEP for InGaAs films. When the As 4 BEP is set to be zero, the RHEED pattern keeps a 4×3/(n × 3) structure with increasing temperature, and surface segregation takes place until 470 °C. The RHEED pattern develops into a metal-rich (4 × 2) structure as temperature increases to 495 °C. The reason for this is that surface segregation makes the In inside the InGaAs film climb to its surface. With the temperature increasing up to 515 °C, the RHEED pattern turns into a GaAs(2 × 4) structure due to In desorption. While the As 4 BEP comes up to a specific value (1.33 × 10 -4 Pa−1.33 × 10 -3 Pa), the surface temperature can delay the segregation and desorption. We find that As 4 BEP has a big influence on surface desorption, while surface segregation is more strongly dependent on temperature than surface desorption. (condensed matter: structural, mechanical, and thermal properties)

  9. Early Evaluation of the VIIRS Calibration, Cloud Mask and Surface Reflectance Earth Data Records

    Science.gov (United States)

    Vermote, Eric; Justice, Chris; Csiszar, Ivan

    2014-01-01

    Surface reflectance is one of the key products fromVIIRS and as withMODIS, is used in developing several higherorder land products. The VIIRS Surface Reflectance (SR) Intermediate Product (IP) is based on the heritageMODIS Collection 5 product (Vermote, El Saleous, & Justice, 2002). The quality and character of surface reflectance depend on the accuracy of the VIIRS Cloud Mask (VCM), the aerosol algorithms and the adequate calibration of the sensor. The focus of this paper is the early evaluation of the VIIRS SR product in the context of the maturity of the operational processing system, the Interface Data Processing System (IDPS). After a brief introduction, the paper presents the calibration performance and the role of the surface reflectance in calibration monitoring. The analysis of the performance of the cloud mask with a focus on vegetation monitoring (no snow conditions) shows typical problems over bright surfaces and high elevation sites. Also discussed is the performance of the aerosol input used in the atmospheric correction and in particular the artifacts generated by the use of the Navy Aerosol Analysis and Prediction System. Early quantitative results of the performance of the SR product over the AERONET sites showthatwith the fewadjustments recommended, the accuracy iswithin the threshold specifications. The analysis of the adequacy of the SR product (Land PEATE adjusted version) in applications of societal benefits is then presented. We conclude with a set of recommendations to ensure consistency and continuity of the JPSS mission with the MODIS Land Climate Data Record.

  10. Observation on Surface Change of Fragile Glass: Temperature - Time Dependence Studied by X-Ray Reflectivity

    International Nuclear Information System (INIS)

    Kikkawa, Hiroyuki; Kitahara, Amane; Takahashi, Isao

    2004-01-01

    The structural change of a fragile glass surface close to the glass transition temperature Tg is studied by using X-ray reflectivity. Measurements were performed on surfaces of maltitol, which is a typical polyalcohol fragile glass with Tg = 320K. Upon both heating and cooling, we find the following features which are also noticed in silicate glass surfaces: (i) On heating, the surface morphology indicates a variation at temperatures below Tg; (ii) A drastic increase in surface roughness occurs at a temperature about 333K on heating, which is 13K higher than Tg; (iii) During the cooling of the sample, formation of a low-density surface layer (3nm at 293K) is observed. Prior to the crystallization, nm - μm sized domains were grown at the surface, which might not be reported for other glasses

  11. Effect of sol aging time on the anti-reflective properties of silica coatings templated with phosphoric acid

    Directory of Open Access Journals (Sweden)

    Wen Wen

    Full Text Available Silica anti-reflective coatings have been prepared by a sol–gel dip-coating process using the sol containing phosphoric acid as a pore-forming template. The effect of the aging time of the sol on the anti-reflective properties has been investigated. The surface topography of the silica AR coatings has been characterized. With increasing sol aging time, more over-sized pores larger than 100 nm are formed in the silica coatings. These could act as scattering centers, scattering visible light and thereby lowering transmittance. The optimal aging time was identified as 1 day, and the corresponding silica coatings showed a maximum transmittance of 99.2%, representing an 8% increase compared to the bare glass substrate. Keywords: Thin films, Anti-reflective coatings, Aging, Dip-coating, Sol–gel preparation

  12. Solar flux incident on an orbiting surface after reflection from a planet

    Science.gov (United States)

    Modest, M. F.

    1980-01-01

    Algorithms describing the solar radiation impinging on an infinitesimal surface after reflection from a gray and diffuse planet are derived. The following conditions apply: only radiation from the sunny half of the planet is taken into account; the radiation must fall on the top of the orbiting surface, and radiation must come from that part of the planet that can be seen from the orbiting body. A simple approximate formula is presented which displays excellent accuracy for all significant situations, with an error which is always less than 5% of the maximum possible reflected flux. Attention is also given to solar albedo flux on a surface directly facing the planet, the influence of solar position on albedo flux, and to solar albedo flux as a function of the surface-planet tilt angle.

  13. Effect of surface characteristics on diffuse reflection radiation at lambda=0. 40. mu. m

    Energy Technology Data Exchange (ETDEWEB)

    Takashima, T [Atmospheric Environment Service, Downsview, Ontario (Canada)

    1976-08-01

    The diffuse radiation in the upward direction at the top and at an internal level of an inhomogeneous atmosphere is computed at lambda=0.40 ..mu..m. The surface is assumed to reflect light in accordance with a hybrid mode of a diffuse and specular reflector. The objective is to estimate the effect of underlying surface characteristics in terms of the diffuse radiation field. By making use of these results, accuracy in monitoring the atmospheric aerosols would be increased for the use of remote sensing satellite techniques. Junge power law (..gamma..*=3) is adopted for the size distribution of aerosols (1963), while the data given by McClatchy et al. (1971) is used for the number density of aerosols with height distribution. It is noted from the computations that the diffuse reflection radiation is affected by the surface characteristics, even if the albedo of the surface is a fixed constant and very small.

  14. Properties of light reflected from road signs in active imaging for driving safety

    Science.gov (United States)

    Halstuch, Aviran; Yitzhaky, Yitzhak

    2007-10-01

    Night-vision systems in vehicles are a new emerging technology. A crucial problem in active (illumination-based) systems is distortion of images by saturation and blooming, due to strong retro-reflections from road signs. In this work we quantified this phenomenon. We measured the Mueller matrices and the polarization state of the reflected light from three different types of road signs commonly used. Measurements of the reflected intensity were taken also with respect to the angle of reflection. We found that different types of signs have different reflection properties. It is concluded from our measurements that the optimal solution for attenuating the retro-reflected intensity is using a linear horizontal polarized light source and a linear vertical polarizer. Unfortunately, while the performance of this solution is good for two types of road signs, it is less efficient for the third sign type.

  15. Optical and electrical properties of porous silicon layer formed on the textured surface by electrochemical etching

    Science.gov (United States)

    Weiying, Ou; Lei, Zhao; Hongwei, Diao; Jun, Zhang; Wenjing, Wang

    2011-05-01

    Porous silicon (PS) layers were formed on textured crystalline silicon by electrochemical etching in HF-based electrolyte. Optical and electrical properties of the TMAH textured surfaces with PS formation are studied. Moreover, the influences of the initial structures and the anodizing time on the optical and electrical properties of the surfaces after PS formation are investigated. The results show that the TMAH textured surfaces with PS formation present a dramatic decrease in reflectance. The longer the anodizing time is, the lower the reflectance. Moreover, an initial surface with bigger pyramids achieved lower reflectance in a short wavelength range. A minimum reflectance of 3.86% at 460 nm is achieved for a short anodizing time of 2 min. Furthermore, the reflectance spectrum of the sample, which was etched in 3 vol.% TMAH for 25 min and then anodized for 20 min, is extremely flat and lies between 3.67% and 6.15% in the wavelength range from 400 to 1040 nm. In addition, for a short anodizing time, a slight increase in the effective carrier lifetime is observed. Our results indicate that PS layers formed on a TMAH textured surface for a short anodization treatment can be used as both broadband antireflection coatings and passivation layers for the application in solar cells.

  16. Optical and electrical properties of porous silicon layer formed on the textured surface by electrochemical etching

    Energy Technology Data Exchange (ETDEWEB)

    Ou Weiying; Zhao Lei; Diao Hongwei; Zhang Jun; Wang Wenjing, E-mail: wjwangwj@126.com [Key Laboratory of Solar Thermal Energy and Photovoltaic System, Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190 (China)

    2011-05-15

    Porous silicon (PS) layers were formed on textured crystalline silicon by electrochemical etching in HF-based electrolyte. Optical and electrical properties of the TMAH textured surfaces with PS formation are studied. Moreover, the influences of the initial structures and the anodizing time on the optical and electrical properties of the surfaces after PS formation are investigated. The results show that the TMAH textured surfaces with PS formation present a dramatic decrease in reflectance. The longer the anodizing time is, the lower the reflectance. Moreover, an initial surface with bigger pyramids achieved lower reflectance in a short wavelength range. A minimum reflectance of 3.86% at 460 nm is achieved for a short anodizing time of 2 min. Furthermore, the reflectance spectrum of the sample, which was etched in 3 vol.% TMAH for 25 min and then anodized for 20 min, is extremely flat and lies between 3.67% and 6.15% in the wavelength range from 400 to 1040 nm. In addition, for a short anodizing time, a slight increase in the effective carrier lifetime is observed. Our results indicate that PS layers formed on a TMAH textured surface for a short anodization treatment can be used as both broadband antireflection coatings and passivation layers for the application in solar cells. (semiconductor technology)

  17. Modeling Bidirectional Reflectance Distribution Function of One-dimensional Random Rough Surfaces with the Finite Difference Time Domain Method

    Directory of Open Access Journals (Sweden)

    Min-Jhong Gu

    2014-08-01

    Full Text Available This article describes the development of a suite of programs that is capable of simulating the radiation properties of a random rough surface (RRS. The fundamental approach involves the generation, by fast Fourier transform (FFT built with rigorous finite difference time domain (FDTD, as the theoretical basis for the simulation of a bidirectional reflectance distribution function (BRDF of the RRS. The results are compared with the measurements and modeling of existing work to verify the feasibility of customized programming. It was found that the results of this study were a better match to the measurement data than those achieved in other modeling work.

  18. Development of Surfaces Optically Suitable for Flat Solar Panels. [using a reflectometer which separately evaluates spectral and diffuse reflectivities of surfaces

    Science.gov (United States)

    1979-01-01

    A reflectometer which can separately evaluate the spectral and diffuse reflectivities of surfaces is described. A phase locked detection system for the reflectometer is also described. A selective coating on aluminum potentially useful for flat plate solar collector applications is presented. The coating is composed of strongly bound copper oxide (divalent) and is formed by an etching process performed on an aluminum alloy with high copper content. Fabrication costs are expected to be small due to the one stop fabrication process. A number of conclusions gathered from the literature as to the required optical properties of flat plate solar collectors are discussed.

  19. Near-surface 3D reflections seismic survey; Sanjigen senso hanshaho jishin tansa

    Energy Technology Data Exchange (ETDEWEB)

    Nakahigashi, H; Mitsui, H; Nakano, O; Kobayashi, T [DIA Consultants Co. Ltd., Tokyo (Japan)

    1997-05-27

    Faults are being actively investigated across Japan since the Great Hanshin-Awaji Earthquake. Discussed in this report is the application of the 3D near-surface reflection seismic survey in big cities. Data from trenching and drilling is used for the geological interpretation of the surroundings of a fault, and the reflection seismic survey is used to identify the position, etc., of the fault. In this article, when the results obtained from the experimental field are examined, it is found that the conventional 2D imaging reflection survey betrays the limit of its capability when the geological structure is complicated, that the 3D reflection seismic survey, on the contrary, is capable of high-precision imaging and, when augmented by drilling, etc., becomes capable of a more detailed interpretation, and that it also contributes effectively to the improvement of local disaster prevention in big cities. Using as the model the Tachikawa fault that runs near JR Tachikawa Station, embodiment of the 3D reflection seismic survey is reviewed. For the acquisition of data excellent in quality in a 3D reflection seismic survey conducted utilizing the roads in the sector chosen for experiment in the urban area, the shock generating points and receiving points should be positioned by taking into account the parameters in the bin arranging process so that the mid-points will be regularly distributed on the surface. 3 refs., 11 figs., 1 tab.

  20. Weighted least-square approach for simultaneous measurement of multiple reflective surfaces

    Science.gov (United States)

    Tang, Shouhong; Bills, Richard E.; Freischlad, Klaus

    2007-09-01

    Phase shifting interferometry (PSI) is a highly accurate method for measuring the nanometer-scale relative surface height of a semi-reflective test surface. PSI is effectively used in conjunction with Fizeau interferometers for optical testing, hard disk inspection, and semiconductor wafer flatness. However, commonly-used PSI algorithms are unable to produce an accurate phase measurement if more than one reflective surface is present in the Fizeau interferometer test cavity. Examples of test parts that fall into this category include lithography mask blanks and their protective pellicles, and plane parallel optical beam splitters. The plane parallel surfaces of these parts generate multiple interferograms that are superimposed in the recording plane of the Fizeau interferometer. When using wavelength shifting in PSI the phase shifting speed of each interferogram is proportional to the optical path difference (OPD) between the two reflective surfaces. The proposed method is able to differentiate each underlying interferogram from each other in an optimal manner. In this paper, we present a method for simultaneously measuring the multiple test surfaces of all underlying interferograms from these superimposed interferograms through the use of a weighted least-square fitting technique. The theoretical analysis of weighted least-square technique and the measurement results will be described in this paper.

  1. Plasma treatment of porous GaAs surface formed by electrochemical etching method: Characterization and properties

    International Nuclear Information System (INIS)

    Naddaf, M.; Saloum, S.

    2008-12-01

    Porous GaAs samples were formed by electrochemical anodic etching of Zn doped p-type GaAs (100) wafers at different etching parameters (time, mode of applied voltage or current and electrolyte). The effect of etching parameters and plasma surface treatment on the optical properties of the prepared sample has been investigated by using room temperature photoluminescence (PL), Raman spectroscopy and reflectance spectroscopic measurements in the range (400-800 nm). The surface morphological changes were studied by using atomic force microscope. It has been found that etching parameters can be controlled to produce a considerably low optical reflectivity porous GaAs layer, attractive for use in solar cells. In addition, it has been observed that the deposition of plasma polymerized HMDSO thin film on porous GaAs surface can be utilized to produce a surface with novel optical properties interesting for solar cells and optoelectronic devices. (author)

  2. An efficient approach for computing the geometrical optics field reflected from a numerically specified surface

    Science.gov (United States)

    Mittra, R.; Rushdi, A.

    1979-01-01

    An approach for computing the geometrical optic fields reflected from a numerically specified surface is presented. The approach includes the step of deriving a specular point and begins with computing the reflected rays off the surface at the points where their coordinates, as well as the partial derivatives (or equivalently, the direction of the normal), are numerically specified. Then, a cluster of three adjacent rays are chosen to define a 'mean ray' and the divergence factor associated with this mean ray. Finally, the ampilitude, phase, and vector direction of the reflected field at a given observation point are derived by associating this point with the nearest mean ray and determining its position relative to such a ray.

  3. A geometrical optics polarimetric bidirectional reflectance distribution function for dielectric and metallic surfaces.

    Science.gov (United States)

    Hyde, M W; Schmidt, J D; Havrilla, M J

    2009-11-23

    A polarimetric bidirectional reflectance distribution function (pBRDF), based on geometrical optics, is presented. The pBRDF incorporates a visibility (shadowing/masking) function and a Lambertian (diffuse) component which distinguishes it from other geometrical optics pBRDFs in literature. It is shown that these additions keep the pBRDF bounded (and thus a more realistic physical model) as the angle of incidence or observation approaches grazing and better able to model the behavior of light scattered from rough, reflective surfaces. In this paper, the theoretical development of the pBRDF is shown and discussed. Simulation results of a rough, perfect reflecting surface obtained using an exact, electromagnetic solution and experimental Mueller matrix results of two, rough metallic samples are presented to validate the pBRDF.

  4. Surface elastic properties in silicon nanoparticles

    Science.gov (United States)

    Melis, Claudio; Giordano, Stefano; Colombo, Luciano

    2017-09-01

    The elastic behavior of the external surface of a solid body plays a key role in nanomechanical phenomena. While bulk elasticity enjoys the benefits of a robust theoretical understanding, many surface elasticity features remain unexplored: some of them are here addressed by blending together continuum elasticity and atomistic simulations. A suitable readdressing of the surface elasticity theory allows to write the balance equations in arbitrary curvilinear coordinates and to investigate the dependence of the surface elastic parameters on the mean and Gaussian curvatures of the surface. In particular, we predict the radial strain induced by surface effects in spherical and cylindrical silicon nanoparticles and provide evidence that the surface parameters are nearly independent of curvatures and, therefore, of the surface conformation.

  5. LiDAR Relative Reflectivity Surface (2011) for Coral Bay, St. John

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This image represents a LiDAR (Light Detection & Ranging) 0.3x0.3 meter resolution relative seafloor reflectivity surface for Coral Bay, St. John in the U.S....

  6. Vertical-cavity surface-emitting laser vapor sensor using swelling polymer reflection modulation

    DEFF Research Database (Denmark)

    Ansbæk, Thor; Nielsen, Claus Højgård; Dohn, Søren

    2012-01-01

    Vapor detection using a low-refractive index polymer for reflection modulation of the top mirror in a vertical-cavity surface-emitting laser (VCSEL) is demonstrated. The VCSEL sensor concept presents a simple method to detect the response of a sensor polymer in the presence of volatile organic...

  7. Classification of Clean and Dirty Pighouse Surfaces Based on Spectral Reflectance

    DEFF Research Database (Denmark)

    Blanke, Mogens; Braithwaite, Ian David; Zhang, Guo-Qiang

    2004-01-01

    of designing a vision based system to locate dirty areas and subsequently direct a cleaning robot to remove dirt. Novel results include the characterisation of the spectral reflectance of real surfaces and dirt in a pig house and the design of illumination to obtain discrimination of clean from dirty areas...

  8. LiDAR Relative Reflectivity Surface (2011) for Fish Bay, St. John

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This image represents a LiDAR (Light Detection & Ranging) 0.3x0.3 meter resolution relative seafloor reflectivity surface for Fish Bay, St. John in the U.S....

  9. In Situ Nondestructive Analysis of Kalanchoe pinnata Leaf Surface Structure by Polarization-Modulation Infrared Reflection-Absorption Spectroscopy.

    Science.gov (United States)

    Hama, Tetsuya; Kouchi, Akira; Watanabe, Naoki; Enami, Shinichi; Shimoaka, Takafumi; Hasegawa, Takeshi

    2017-12-14

    The outermost surface of the leaves of land plants is covered with a lipid membrane called the cuticle that protects against various stress factors. Probing the molecular-level structure of the intact cuticle is highly desirable for understanding its multifunctional properties. We report the in situ characterization of the surface structure of Kalanchoe pinnata leaves using polarization-modulation infrared reflection-absorption spectroscopy (PM-IRRAS). Without sample pretreatment, PM-IRRAS measures the IR spectra of the leaf cuticle of a potted K. pinnata plant. The peak position of the CH 2 -related modes shows that the cuticular waxes on the leaf surface are mainly crystalline, and the alkyl chains are highly packed in an all-trans zigzag conformation. The surface selection rule of PM-IRRAS revealed the average orientation of the cuticular molecules, as indicated by the positive and negative signals of the IR peaks. This unique property of PM-IRRAS revealed that the alkyl chains of the waxes and the main chains of polysaccharides are oriented almost perpendicular to the leaf surface. The nondestructive, background-free, and environmental gas-free nature of PM-IRRAS allows the structure and chemistry of the leaf cuticle to be studied directly in its native environment.

  10. Bidirectional reflectance distribution function modeling of one-dimensional rough surface in the microwave band

    International Nuclear Information System (INIS)

    Guo Li-Xin; Gou Xue-Yin; Zhang Lian-Bo

    2014-01-01

    In this study, the bidirectional reflectance distribution function (BRDF) of a one-dimensional conducting rough surface and a dielectric rough surface are calculated with different frequencies and roughness values in the microwave band by using the method of moments, and the relationship between the bistatic scattering coefficient and the BRDF of a rough surface is expressed. From the theory of the parameters of the rough surface BRDF, the parameters of the BRDF are obtained using a genetic algorithm. The BRDF of a rough surface is calculated using the obtained parameter values. Further, the fitting values and theoretical calculations of the BRDF are compared, and the optimization results are in agreement with the theoretical calculation results. Finally, a reference for BRDF modeling of a Gaussian rough surface in the microwave band is provided by the proposed method. (electromagnetism, optics, acoustics, heat transfer, classical mechanics, and fluid dynamics)

  11. Dynamical properties of tertiarybutylarsine on GaAs(0 0 1) surface

    CERN Document Server

    Ozeki, M; Tanaka, Y

    2002-01-01

    The dynamical properties of tertiarybutylarsine (TBA) was studied on GaAs(0 0 1) surface using a supersonic molecular beam. The temperature and incident energy dependence of the reflected beam revealed a reaction channel of TBA on GaAs surface with a large decrease in the activation energy from 2.7 to 1.8 eV as the incident energy increases from 0.04 to 2.5 eV.

  12. Radius of curvature measurement of spherical smooth surfaces by multiple-beam interferometry in reflection

    Science.gov (United States)

    Abdelsalam, D. G.; Shaalan, M. S.; Eloker, M. M.; Kim, Daesuk

    2010-06-01

    In this paper a method is presented to accurately measure the radius of curvature of different types of curved surfaces of different radii of curvatures of 38 000,18 000 and 8000 mm using multiple-beam interference fringes in reflection. The images captured by the digital detector were corrected by flat fielding method. The corrected images were analyzed and the form of the surfaces was obtained. A 3D profile for the three types of surfaces was obtained using Zernike polynomial fitting. Some sources of uncertainty in measurement were calculated by means of ray tracing simulations and the uncertainty budget was estimated within λ/40.

  13. Mechanisms for the reflection of light atoms from crystal surfaces at kilovolt energies

    International Nuclear Information System (INIS)

    Hou, M.; Robinson, M.T.

    1978-01-01

    The computer program MARLOWE was used to investigate the backscattering of protons from the (110) surface of a nickel crystal. Grazing incidence was considered so that anisotropic effects originated mainly from the surface region. The contribution of aligned scattering was studied by comparing the results with similar calculations for an amorphous target. Energy distributions of backscattered particles were investigated for incident energies ranging from 0.1 to 5 keV. The structure of these distributions was explained by making calculations for several target thickness. Specular reflection was found to depend on the structure of the first few atomic planes only. The (110) rows in the surface plane were responsible for focusing into surface semichannels. Focusing in these semichannels was found to be the strongest under total reflection conditions (below about 1.3 keV) while the scattering intensity from surface rows increased with increasing incident energy. The orientation of the plane of incidence was found to have large influence on the relative contributions of the reflection mechanisms involved. (orig.) [de

  14. One-step Maskless Fabrication and Optical Characterization of Silicon Surfaces with Antireflective Properties and a White Color Appearance

    DEFF Research Database (Denmark)

    Sun, Ling; Feidenhans'l, Nikolaj Agentoft; Telecka, Agnieszka

    2016-01-01

    We report a simple one-step maskless fabrication of inverted pyramids on silicon wafers by reactive ion etching. The fabricated surface structures exhibit excellent anti-reflective properties: The total reflectance of the nano inverted pyramids fabricated by our method can be as low as 12% withou...... milky white color....

  15. Critical coupling of surface plasmons in graphene attenuated total reflection geometry

    Energy Technology Data Exchange (ETDEWEB)

    Cuevas, Mauro, E-mail: cuevas@df.uba.ar [Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) and Facultad de Ingeniería y Tecnología Informática, Universidad de Belgrano, Villanueva 1324, C1426BMJ, Buenos Aires (Argentina); Grupo de Electromagnetismo Aplicado, Departamento de Física, FCEN, Universidad de Buenos Aires and IFIBA, Ciudad Universitaria, Pabellón I, C1428EHA, Buenos Aires (Argentina)

    2016-12-09

    We study the optical response of an attenuated total reflection (ATR) structure in Otto configuration with graphene sheet, paying especial attention to the occurrence of total absorption. Our results show that due to excitation of surface plasmons on the graphene sheet, two different conditions of total absorption may occur. At these conditions, the energy loss of the surface plasmon by radiation is equal to its energy loss by absorption into the graphene sheet. We give necessary conditions on ATR parameters for the existence of total absorption. - Highlights: • Attenuated total reflection (ATR) structure with graphene sheet. • Surface plasmons and power matched condition. • Necessary conditions on ATR parameters for the existence of total absorption.

  16. Critical coupling of surface plasmons in graphene attenuated total reflection geometry

    International Nuclear Information System (INIS)

    Cuevas, Mauro

    2016-01-01

    We study the optical response of an attenuated total reflection (ATR) structure in Otto configuration with graphene sheet, paying especial attention to the occurrence of total absorption. Our results show that due to excitation of surface plasmons on the graphene sheet, two different conditions of total absorption may occur. At these conditions, the energy loss of the surface plasmon by radiation is equal to its energy loss by absorption into the graphene sheet. We give necessary conditions on ATR parameters for the existence of total absorption. - Highlights: • Attenuated total reflection (ATR) structure with graphene sheet. • Surface plasmons and power matched condition. • Necessary conditions on ATR parameters for the existence of total absorption.

  17. Sunlight reflection off the spacecraft with a solar sail on the surface of mars

    Science.gov (United States)

    Starinova, O. L.; Rozhkov, M. A.; Gorbunova, I. V.

    2018-05-01

    Modern technologies make it possible to fulfill many projects in the field of space exploration. One such project is the colonization of Mars and providing favorable conditions for living on it. Authors propose principles of functioning of the spacecraft with a solar sail, intended to create a thermal and light spot in a predetermined area of the Martian surface. This additional illumination can maintain and support certain climatic conditions on a small area where a Mars base could be located. This paper investigate the possibility of the spacecraft continuously reflect the sunlight off the solar sail on the small area of the Mars surface. The mathematical motion model in such condition of the solar sail's orientation is considered and used for motion simulation session. Moreover, the analysis of this motion is performed. Thus, were obtained parameters of the synchronic non-Keplerian orbit and spacecraft construction. In addition, were given recommendations for further applying satellites to reflect the sunlight on a planet's surface.

  18. Lunar surface remanent magnetic fields detected by the electron reflection method

    Science.gov (United States)

    Lin, R. P.; Anderson, K. A.; Bush, R.; Mcguire, R. E.; Mccoy, J. E.

    1976-01-01

    We present maps of the lunar surface remanent magnetic fields detected by the electron reflection method. These maps provide substantial coverage of the latitude band from 30 N southward to 30 S with a resolution of about 40 km and a sensitivity of about 0.2 gamma at the lunar surface. Regions of remanent magnetization are observed ranging in size from the resolution limit of 1.25 deg to above approximately 60 deg. The largest contiguous region fills the Big Backside Basin where it is intersected by the spacecraft orbital tracks. Preliminary analyses of the maps show that the source regions of lunar limb compressions correspond to regions of strong surface magnetism, and that there does not appear to be sharply discontinuous magnetization at the edges of maria. We also analyze the electron reflection observations to obtain information on the direction and distribution of magnetization in the Van de Graaff anomaly region.

  19. Lactoperoxidase catalyzed radioiodination of cell surface immunoglobulin: incorporated radioactivity may not reflect relative cell surface Ig density

    International Nuclear Information System (INIS)

    Wilder, R.L.; Yuen, C.C.; Mage, R.G.

    1979-01-01

    Rabbit and mouse splenic lymphocytes were radioiodinated by the lactoperoxidase technique, extracted with non-ionic detergent, immunoprecipitated with high titered rabbit anti-kappa antisera, and compared by SDS-PAGE. Mouse sIg peaks were reproducibly larger in size than rabbit sIg peaks (often greater than 10 times). Neither differences in incorporation of label into the rabbit cell surface, nor differences in average sIg density explain this result. Total TCA-precipitable radioactivity was similar in each species. Estimation of the relative amounts of sIg in the mouse and rabbit showed similar average sIg densities. Differences in detergent solubility, proteolytic lability, or antisera used also do not adequately account for this difference. Thus, these data indicate that radioactivity incorporated after lactoperoxidase catalyzed cell surface radioiodination may not reflect cell surface Ig density. Conclusions about cell surface density based upon relative incorporation of radioactivity should be confirmed by other approaches

  20. Probing Ultrafast Electron Dynamics at Surfaces Using Soft X-Ray Transient Reflectivity Spectroscopy

    Science.gov (United States)

    Baker, L. Robert; Husek, Jakub; Biswas, Somnath; Cirri, Anthony

    The ability to probe electron dynamics with surface sensitivity on the ultrafast time scale is critical for understanding processes such as charge separation, injection, and surface trapping that mediate efficiency in catalytic and energy conversion materials. Toward this goal, we have developed a high harmonic generation (HHG) light source for femtosecond soft x-ray reflectivity. Using this light source we investigated the ultrafast carrier dynamics at the surface of single crystalline α-Fe2O3, polycrystalline α-Fe2O3, and the mixed metal oxide, CuFeO2. We have recently demonstrated that CuFeO2 in particular is a selective catalyst for photo-electrochemical CO2 reduction to acetate; however, the role of electronic structure and charge carrier dynamics in mediating catalytic selectivity has not been well understood. Soft x-ray reflectivity measurements probe the M2,3, edges of the 3d transition metals, which provide oxidation and spin state resolution with element specificity. In addition to chemical state specificity, these measurements are also surface sensitive, and by independently simulating the contributions of the real and imaginary components of the complex refractive index, we can differentiate between surface and sub-surface contributions to the excited state spectrum. Accordingly, this work demonstrates the ability to probe ultrafast carrier dynamics in catalytic materials with element and chemical state specificity and with surface sensitivity.

  1. Evaluation of BRDF Archetypes for Representing Surface Reflectance Anisotropy Using MODIS BRDF Data

    Directory of Open Access Journals (Sweden)

    Hu Zhang

    2015-06-01

    Full Text Available Bidirectional reflectance distribution function (BRDF archetypes extracted from the Moderate Resolution Imaging Spectroradiometer (MODIS BRDF/Albedo product over the global Earth Observing System Land Validation Core Sites can be used to simplify BRDF models. The present study attempts to evaluate the representativeness of BRDF archetypes for surface reflectance anisotropy. Five-year forward-modeled MODIS multi-angular reflectance (MCD-ref and aditional actual MODIS multi-angular observations (MCD-obs in four growing periods in 2008 over three tiles were taken as validation data. First, BRDF archetypes in the principal plane were qualitatively compared with the time-series MODIS BRDF product of randomly sampled pixels. Secondly, BRDF archetypes were used to fit MCD-ref, and the average root-mean-squared errors (RMSEs over each tile were examined for these five years. Finally, both BRDF archetypes and the MODIS BRDF were used to fit MCD-obs, and the histograms of the fit-RMSEs were compared. The consistency of the directional reflectance between the BRDF archetypes and MODIS BRDFs in nadir-view, hotspot and entire viewing hemisphere at 30° and 50° solar geometries were also examined. The results confirm that BRDF archetypes are representative of surface reflectance anisotropy for available snow-free MODIS data.

  2. Effects of atomic oxygen irradiation on the surface properties of phenolphthalein poly(ether sulfone)

    International Nuclear Information System (INIS)

    Pei Xianqiang; Li Yan; Wang Qihua; Sun Xiaojun

    2009-01-01

    To study the effects of low earth orbit environment on the surface properties of polymers, phenolphthalein poly(ether sulfone) (PES-C) blocks were irradiated by atomic oxygen in a ground-based simulation system. The surface properties of the pristine and irradiated blocks were studied by attenuated total-reflection FTIR (FTIR-ATR), X-ray photoelectron spectroscopy (XPS), scanning electron microscope (SEM). It was found that atomic oxygen irradiation induced the destruction of PES-C molecular chains, including the scission and oxidation of PES-C molecular chains, as evidenced by FTIR and XPS results. The scission of PES-C molecular chains decreased the relative concentration of C in the surface, while the oxidation increased the relative concentration of O in the surface. The changes in surface chemical structure and composition also changed the surface morphology of the block, which shifted from smooth structure before irradiation to 'carpet-like' structure after irradiation

  3. Ray splitting in the reflection and refraction of surface acoustic waves in anisotropic solids.

    Science.gov (United States)

    Every, A G; Maznev, A A

    2010-05-01

    This paper examines the conditions for, and provides examples of, ray splitting in the reflection and refraction of surface acoustic waves (SAW) in elastically anisotropic solids at straight obstacles such as edges, surface breaking cracks, and interfaces between different solids. The concern here is not with the partial scattering of an incident SAW's energy into bulk waves, but with the occurrence of more than one SAW ray in the reflected and/or transmitted wave fields, by analogy with birefringence in optics and mode conversion of bulk elastic waves at interfaces. SAW ray splitting is dependent on the SAW slowness curve possessing concave regions, which within the constraint of wave vector conservation parallel to the obstacle allows multiple outgoing SAW modes for certain directions of incidence and orientation of obstacle. The existence of pseudo-SAW for a given surface provides a further channel for ray splitting. This paper discusses some typical material configurations for which SAW ray splitting occurs. An example is provided of mode conversion entailing backward reflection or negative refraction. Experimental demonstration of ray splitting in the reflection of a laser generated SAW in GaAs(111) is provided. The calculation of SAW mode conversion amplitudes lies outside the scope of this paper.

  4. Andreev reflection properties in a parallel mesoscopic circuit with Majorana bound states

    Energy Technology Data Exchange (ETDEWEB)

    Mu, Jin-Tao; Han, Yu [Physics Department, Liaoning University, Shenyang 110036 (China); Gong, Wei-Jiang, E-mail: gwj@mail.neu.edu.cn [College of Sciences, Northeastern University, Shenyang 110819 (China)

    2017-03-15

    We investigate the Andreev reflection in a parallel mesoscopic circuit with Majorana bound states (MBSs). It is found that in such a structure, the Andreev current can be manipulated in a highly efficient way, by the adjustment of bias voltage, dot levels, inter-MBS coupling, and the applied magnetic flux. Besides, the dot-MBS coupling manner is an important factor to modulate the Andreev current, because it influences the period of the conductance oscillation. By discussing the underlying quantum interference mechanism, the Andreev-reflection property is explained in detail. We believe that all the results can assist to understand the nontrivial role of the MBSs in driving the Andreev reflection.

  5. Application of Sol-Gel Method as a Protective Layer on a Specular Reflective Surface for Secondary Reflector in a Solar Receiver

    Energy Technology Data Exchange (ETDEWEB)

    Afrin, Samia; Dagdelen, John; Ma, Zhiwen; Kumar, Vinod

    2017-01-01

    Highly-specular reflective surfaces that can withstand elevated-temperatures are desirable for many applications including reflective heat shielding in solar receivers and secondary reflectors, which can be used between primary concentrators and heat collectors. A high-efficiency, high-temperature solar receiver design based on arrays of cavities needs a highly-specular reflective surface on its front section to help sunlight penetrate into the absorber tubes for effective flux spreading. Since this application is for high-temperature solar receivers, this surface needs to be durable and to maintain its optical properties through the usable life. Degradation mechanisms associated with elevated temperatures and thermal cycling, which include cracking, delamination, corrosion/oxidation, and environmental effects, could cause the optical properties of surfaces to degrade rapidly in these conditions. Protected mirror surfaces for these applications have been tested by depositing a thin layer of SiO2 on top of electrodeposited silver by means of the sol-gel method. To obtain an effective thin film structure, this sol-gel procedure has been investigated extensively by varying process parameters that affect film porosity and thickness. Endurance tests have been performed in a furnace at 150 degrees C for thousands of hours. This paper presents the sol-gel process for intermediate-temperature specular reflective coatings and provides the long-term reliability test results of sol-gel protected silver-coated surfaces.

  6. [A Method to Reconstruct Surface Reflectance Spectrum from Multispectral Image Based on Canopy Radiation Transfer Model].

    Science.gov (United States)

    Zhao, Yong-guang; Ma, Ling-ling; Li, Chuan-rong; Zhu, Xiao-hua; Tang, Ling-li

    2015-07-01

    Due to the lack of enough spectral bands for multi-spectral sensor, it is difficult to reconstruct surface retlectance spectrum from finite spectral information acquired by multi-spectral instrument. Here, taking into full account of the heterogeneity of pixel from remote sensing image, a method is proposed to simulate hyperspectral data from multispectral data based on canopy radiation transfer model. This method first assumes the mixed pixels contain two types of land cover, i.e., vegetation and soil. The sensitive parameters of Soil-Leaf-Canopy (SLC) model and a soil ratio factor were retrieved from multi-spectral data based on Look-Up Table (LUT) technology. Then, by combined with a soil ratio factor, all the parameters were input into the SLC model to simulate the surface reflectance spectrum from 400 to 2 400 nm. Taking Landsat Enhanced Thematic Mapper Plus (ETM+) image as reference image, the surface reflectance spectrum was simulated. The simulated reflectance spectrum revealed different feature information of different surface types. To test the performance of this method, the simulated reflectance spectrum was convolved with the Landsat ETM + spectral response curves and Moderate Resolution Imaging Spectrometer (MODIS) spectral response curves to obtain the simulated Landsat ETM+ and MODIS image. Finally, the simulated Landsat ETM+ and MODIS images were compared with the observed Landsat ETM+ and MODIS images. The results generally showed high correction coefficients (Landsat: 0.90-0.99, MODIS: 0.74-0.85) between most simulated bands and observed bands and indicated that the simulated reflectance spectrum was well simulated and reliable.

  7. Simulation of an oil film at the sea surface and its radiometric properties in the SWIR

    Science.gov (United States)

    Schwenger, Frédéric; Van Eijk, Alexander M. J.

    2017-10-01

    The knowledge of the optical contrast of an oil layer on the sea under various surface roughness conditions is of great interest for oil slick monitoring techniques. This paper presents a 3D simulation of a dynamic sea surface contaminated by a floating oil film. The simulation considers the damping influence of oil on the ocean waves and its physical properties. It calculates the radiance contrast of the sea surface polluted by the oil film in relation to a clean sea surface for the SWIR spectral band. Our computer simulation combines the 3D simulation of a maritime scene (open clear sea/clear sky) with an oil film at the sea surface. The basic geometry of a clean sea surface is modeled by a composition of smooth wind driven gravity waves. Oil on the sea surface attenuates the capillary and short gravity waves modulating the wave power density spectrum of these waves. The radiance of the maritime scene is calculated in the SWIR spectral band with the emitted sea surface radiance and the specularly reflected sky radiance as components. Wave hiding and shadowing, especially occurring at low viewing angles, are considered. The specular reflection of the sky radiance at the clean sea surface is modeled by an analytical statistical bidirectional reflectance distribution function (BRDF) of the sea surface. For oil at the sea surface, a specific BRDF is used influenced by the reduced surface roughness, i.e., the modulated wave density spectrum. The radiance contrast of an oil film in relation to the clean sea surface is calculated for different viewing angles, wind speeds, and oil types characterized by their specific physical properties.

  8. Fluorinated cellular polypropylene films with time-invariant excellent surface electret properties by post-treatments

    International Nuclear Information System (INIS)

    An Zhenlian; Mao Mingjun; Yao Junlan; Zhang Yewen; Xia Zhongfu

    2010-01-01

    In this work, to improve the electret properties of cellular polypropylene films, they were fluorinated and post-treated with nitrous oxide and by isothermal crystallization. Surface electret properties of the samples were investigated by thermally stimulated discharge current measurements, and their compositions and structures were analysed by attenuated total reflection infrared spectroscopy and wide angle x-ray diffraction, respectively. Time-dependent deterioration of surface electret properties was observed for the fluorinated samples without the nitrous oxide post-treatment. However, deterioration did not occur for the fluorinated samples post-treated with nitrous oxide, and time-invariant excellent surface electret properties or deep surface charge traps were obtained by the combined post-treatments of the fluorinated samples with nitrous oxide and by isothermal crystallization. Based on the analyses of composition and structure of the treated samples, the deterioration was clarified to be due to a trace of oxygen in the reactive mixture, which led to the formation of peroxy RO 2 . radicals in the fluorinated surface layer. The time invariability of surface electret properties was owing to the rapid termination of the peroxy RO 2 . radicals by nitrous oxide. And the deep surface charge traps resulted from the isothermal crystallization treatment which led to an increase in the efficient charging interface between the crystallite and amorphous region and its property change.

  9. The effect of surface texture on total reflection of neutrons and X-rays from modified interfaces

    DEFF Research Database (Denmark)

    Goldar, A.; Roser, S.J.; Hughes, A.

    2002-01-01

    X-ray and neutron scattering from macroscopically rough surfaces and interfaces is considered and a new method of analysis based on the variation of the shape of the total reflection edge in the reflectivity profile is proposed. It was shown that in the limit that the correlation length and the h......X-ray and neutron scattering from macroscopically rough surfaces and interfaces is considered and a new method of analysis based on the variation of the shape of the total reflection edge in the reflectivity profile is proposed. It was shown that in the limit that the correlation length...... and the height of the surface roughness are larger than the wavelength (at least 100 times bigger) of the incoming beam, the total reflection edge in the reflection profile becomes rounded. This technique allows direct analysis of the variation of the reflectivity pro le in terms of the structure of the surface...

  10. Retrieval of the Land Surface Reflectance for Landsat-8 and Sentinel-2 and its validation.

    Science.gov (United States)

    Roger, J. C.; Vermote, E.; Skakun, S.; Franch, B.; Holben, B. N.; Justice, C. O.

    2017-12-01

    The land surface reflectance is a fundamental climate data record at the basis of the derivation of other climate data records (Albedo, LAI/Fpar, Vegetation indices) and a key parameter in the understanding of the land-surface-climate processes. For 25 years, Vermote and al. develop atmospheric corrections methods to define a land surface reflectance product for various satellites (AVHRR, MODIS, VIIRS…). This presentation highlights the algorithms developed both for Landsant-8 and Sentinel-2. We also emphasize the validation of the "Land surface reflectance" satellite products, which is a very important step to be done. For that purpose, we compared the surface reflectance products to a reference determined by using the accurate radiative transfer code 6S and very detailed measurements of the atmosphere obtained over the AERONET network (which allows to test for a large range of aerosol characteristics); formers being important inputs for atmospheric corrections. However, the application of this method necessitates the definition of a very detailed protocol for the use of AERONET data especially as far as size distribution and absorption are concerned, so that alternative validation methods or protocols could be compared. We describe here the protocol we have been working on based on our experience with the AERONET data and its application to Landsat-8 and Sentinel-2). We also derive a detailed error budget in relation to this approach. For a mean loaded atmosphere, t550 less than 0.25, the maximum uncertainty is 0.0025 corresponding to a relative uncertainty (in the RED channels): U 0.10, and 1% rsurf > 0.04.

  11. Light reflection from a rough liquid surface including wind-wave effects in a scattering atmosphere

    International Nuclear Information System (INIS)

    Salinas, Santo V.; Liew, S.C.

    2007-01-01

    Visible and near-IR images of the ocean surface, taken from remote satellites, often contain important information of near-surface or sub-surface processes, which occur on, or over the ocean. Remote measurements of near surface winds, sea surface temperature and salinity, ocean color and underwater bathymetry, all, one way or another, depend on how well we understand sea surface roughness. However, in order to extract useful information from our remote measurements, we need to construct accurate models of the transfer of solar radiation inside the atmosphere as well as, its reflection from the sea surface. To approach this problem, we numerically solve the radiative transfer equation (RTE) by implementing a model for the atmosphere-ocean system. A one-dimensional atmospheric radiation model is solved via the widely known doubling and adding method and the ocean body is treated as a boundary condition to the problem. The ocean surface is modeled as a rough liquid surface which includes wind interaction and wave states, such as wave age. The model can have possible applications to the retrieval of wind and wave states, such as wave age, near a Sun glint region

  12. Biomimetic approaches to create anti-reflection glass surfaces for solar cells using self-organizing techniques

    International Nuclear Information System (INIS)

    Achtelik, J.; Sievers, W.; Lindner, J.K.N.

    2013-01-01

    Highlights: ► Nanostructured glass surfaces with theoretically near-to-zero reflectivity in the UVNIR region. ► Simple fabrication process using self-organization during reactive ion etching proposed. ► Prediction of optical reflectivity from AFM measured surface morphology. -- Abstract: Aiming to diminish the reflection losses of glass covered light harvesting devices, the optical reflectivity of nanostructured glass surfaces is studied theoretically and experimentally. The work is inspired by the nanoscale roughness of insect eyes, which is tried to be replicated on a technical glass surface. To this end, the reflectivity of glass surfaces with topographies represented by linear, parabolic and Fermi-shaped glass/air fill factor profiles is calculated for normal incidence. It is shown that using the latter ones, an almost complete suppression of reflections can be achieved. A simple, self-organization technique to create such Fermi-shaped filling factor profiles in glass experimentally is also presented

  13. Biomimetic approaches to create anti-reflection glass surfaces for solar cells using self-organizing techniques

    Energy Technology Data Exchange (ETDEWEB)

    Achtelik, J.; Sievers, W. [University of Paderborn, Department of Physics, 33098 Paderborn (Germany); Center of Optoelectronics and Photonics Paderborn CeOPP, 33098 Paderborn (Germany); Lindner, J.K.N., E-mail: lindner@physik.uni-paderborn.de [University of Paderborn, Department of Physics, 33098 Paderborn (Germany); Center of Optoelectronics and Photonics Paderborn CeOPP, 33098 Paderborn (Germany)

    2013-05-15

    Highlights: ► Nanostructured glass surfaces with theoretically near-to-zero reflectivity in the UVNIR region. ► Simple fabrication process using self-organization during reactive ion etching proposed. ► Prediction of optical reflectivity from AFM measured surface morphology. -- Abstract: Aiming to diminish the reflection losses of glass covered light harvesting devices, the optical reflectivity of nanostructured glass surfaces is studied theoretically and experimentally. The work is inspired by the nanoscale roughness of insect eyes, which is tried to be replicated on a technical glass surface. To this end, the reflectivity of glass surfaces with topographies represented by linear, parabolic and Fermi-shaped glass/air fill factor profiles is calculated for normal incidence. It is shown that using the latter ones, an almost complete suppression of reflections can be achieved. A simple, self-organization technique to create such Fermi-shaped filling factor profiles in glass experimentally is also presented.

  14. Laser modification of macroscopic properties of metal surface layer

    Science.gov (United States)

    Kostrubiec, Franciszek

    1995-03-01

    Surface laser treatment of metals comprises a number of diversified technological operations out of which the following can be considered the most common: oxidation and rendering surfaces amorphous, surface hardening of steel, modification of selected physical properties of metal surface layers. In the paper basic results of laser treatment of a group of metals used as base materials for electric contacts have been presented. The aim of the study was to test the usability of laser treatment from the viewpoint of requirements imposed on materials for electric contacts. The results presented in the paper refer to two different surface treatment technologies: (1) modification of infusible metal surface layer: tungsten and molybdenum through laser fusing of their surface layer and its crystallization, and (2) modification of surface layer properties of other metals through laser doping of their surface layer with foreign elements. In the paper a number of results of experimental investigations obtained by the team under the author's supervision are presented.

  15. Probing Anisotropic Surface Properties of Molybdenite by Direct Force Measurements.

    Science.gov (United States)

    Lu, Zhenzhen; Liu, Qingxia; Xu, Zhenghe; Zeng, Hongbo

    2015-10-27

    Probing anisotropic surface properties of layer-type mineral is fundamentally important in understanding its surface charge and wettability for a variety of applications. In this study, the surface properties of the face and the edge surfaces of natural molybdenite (MoS2) were investigated by direct surface force measurements using atomic force microscope (AFM). The interaction forces between the AFM tip (Si3N4) and face or edge surface of molybdenite were measured in 10 mM NaCl solutions at various pHs. The force profiles were well-fitted with classical DLVO (Derjaguin-Landau-Verwey-Overbeek) theory to determine the surface potentials of the face and the edge surfaces of molybdenite. The surface potentials of both the face and edge surfaces become more negative with increasing pH. At neutral and alkaline conditions, the edge surface exhibits more negative surface potential than the face surface, which is possibly due to molybdate and hydromolybdate ions on the edge surface. The point of zero charge (PZC) of the edge surface was determined around pH 3 while PZC of the face surface was not observed in the range of pH 3-11. The interaction forces between octadecyltrichlorosilane-treated AFM tip (OTS-tip) and face or edge surface of molybdenite were also measured at various pHs to study the wettability of molybdenite surfaces. An attractive force between the OTS-tip and the face surface was detected. The force profiles were well-fitted by considering DLVO forces and additional hydrophobic force. Our results suggest the hydrophobic feature of the face surface of molybdenite. In contrast, no attractive force between the OTS-tip and the edge surface was detected. This is the first study in directly measuring surface charge and wettability of the pristine face and edge surfaces of molybdenite through surface force measurements.

  16. Structure and optical properties of water covered Cu(110) surfaces

    International Nuclear Information System (INIS)

    Baghbanpourasl, A.

    2014-01-01

    In this thesis structural and optical properties of the water covered Cu(110) surface is studied using density functional theory within independent particle approximation. Several stable adsorption structures are studied such as water clusters (monomer, dimer, trimer, tetramer and pentamer), different hexagonal monolayers, partially dissociated water monolayers and three different types of chains among them a chain that consists of pentagon rings. For a copper surface in contact with water vapor, the energetically stable H 2 O/OH adsorbed structures are compared thermodynamically using adsorption free energy (change of free energy due to adsorption). Several phase diagrams with respect to temperature and pressure are calculated. It is found that among the large number of energetically stable structures (i.e. structures with positive adsorption energy ) only limited number of them are thermodynamically stable. These thermodynamically stable structures are the class of almost energetically degenerate hexagonal overlayers, one type of partially dissociated water structure that contains Bjerrum defect in the hydrogen bond network and pentagon chain. Since hydrogen atoms are light weight their vibrational effects can be considerable. Zero point vibration decreases the adsorption energy up to 0.1 eV and free energy of adsorbed molecules arising from vibrational degree of freedom can go up to -0.2 eV per adsorbed molecule at 500 Kelvin. However zero point energy and vibrational free energy of adsorbed molecules do not alter relative stability of the adsorbed structures. To account for the long range van der Waals interactions, a semi-empirical scheme is applied. Reflectance Anisotropy Spectroscopy (RAS) is a fast and non destructive optical method that can be used to prob the surface in different conditions such as vacuum and electro-chemical environment. Elasto-optic coeficients of bulk are calculated from first principles and the change of the RA spectrum of the bare Cu

  17. Characterizing Optical Properties of Disturbed Surface Signatures

    Science.gov (United States)

    2013-01-01

    object, the holes were approximately 21-25” in diameter, with loosened soil and unearthed clasts spread nearby due to the digging and movements of the...pixel, bracketing the telluric CO2 absorption with bands at ~ 3.8 – 4.2 m and ~ 4.5 – 5 m. The shorter band is sensitive to both reflected sunlight

  18. The normalization of surface anisotropy effects present in SEVIRI reflectances by using the MODIS BRDF method

    DEFF Research Database (Denmark)

    Proud, Simon Richard; Zhang, Qingling; Schaaf, Crystal

    2014-01-01

    A modified version of the MODerate resolution Imaging Spectroradiometer (MODIS) bidirectional reflectance distribution function (BRDF) algorithm is presented for use in the angular normalization of surface reflectance data gathered by the Spinning Enhanced Visible and InfraRed Imager (SEVIRI...... acquisition period than the comparable MODIS products while, at the same time, removing many of the angular perturbations present within the original MSG data. The NBAR data are validated against reflectance data from the MODIS instrument and in situ data gathered at a field location in Africa throughout 2008....... It is found that the MSG retrievals are stable and are of high-quality across much of the SEVIRI disk while maintaining a higher temporal resolution than the MODIS BRDF products. However, a number of circumstances are discovered whereby the BRDF model is unable to function correctly with the SEVIRI...

  19. Self-consistent approach to x-ray reflection from rough surfaces

    International Nuclear Information System (INIS)

    Feranchuk, I. D.; Feranchuk, S. I.; Ulyanenkov, A. P.

    2007-01-01

    A self-consistent analytical approach for specular x-ray reflection from interfaces with transition layers [I. D. Feranchuk et al., Phys. Rev. B 67, 235417 (2003)] based on the distorted-wave Born approximation (DWBA) is used for the description of coherent and incoherent x-ray scattering from rough surfaces and interfaces. This approach takes into account the transformation of the modeling transition layer profile at the interface, which is caused by roughness correlations. The reflection coefficients for each DWBA order are directly calculated without phenomenological assumptions on their exponential decay at large scattering angles. Various regions of scattering angles are discussed, which show qualitatively different dependence of the reflection coefficient on the scattering angle. The experimental data are analyzed using the method developed

  20. SURFACE PROPERTIES AND CATALYTIC PERFORMANCE OF Pt ...

    African Journals Online (AJOL)

    various temperatures of precipitates obtained from aqueous solutions in the ... The oxidation reactivity of VOCs is in the following order: alcohols > aldheydes > aromatics ... Specific surface areas (SSA) were calculated by the BET method from ...

  1. Electrochemical Properties of Alkanethiol Monolayers Adsorbed on Nanoporous Au Surfaces

    International Nuclear Information System (INIS)

    Chu, Yeon Yi; Seo, Bora; Kim, Jong Won

    2010-01-01

    We investigated the electrochemical properties of alkanethiol monolayers adsorbed on NPG surfaces by cyclic voltammetry and electrochemical impedance spectroscopy, and the results are compared to those on flat Au surfaces. The reductive desorption of alkanethiols on NPG surfaces is observed in more negative potential regions than that on flat Au surfaces due the stronger S-Au interaction on NPG surfaces. While the electron transfer through alkanethiol monolayers on flat Au surfaces occurs via a tunneling process through the monolayer films, the redox species can permeate through the monolayers on NPG surfaces to transfer the electrons to the Au surfaces. The results presented here will help to elucidate the intrinsic electrochemical properties of alkanethiol monolayers adsorbed on curved Au surfaces, particularly on the surface of AuNPs. Self-assembled monolayers (SAMs) of thiolate molecules on Au surfaces have been the subject of intensive research for the last few decades due to their unique physical and chemical properties. The well-organized surface structures of thiolate SAMs with various end-group functionalities can be further utilized for many applications in biology and nanotechnology. In addition to the practical applications, SAMs of thiolate molecules on Au surfaces also provide unique opportunities to address fundamental issues in surface chemistry such as self-organized surface structures, electron transfer behaviors, and moleculesubstrate interactions. Although there have been numerous reports on the fundamental physical and chemical properties of thiolate SAMs on Au surfaces, most of them were investigated on flat Au surfaces, typically on well-defined Au(111) surfaces

  2. Antarctic Surface Reflectivity Measurements from the ANITA-3 and HiCal-1 Experiments

    Science.gov (United States)

    Gorham, P. W.; Allison, P.; Banerjee, O.; Beatty, J. J.; Belov, K.; Besson, D. Z.; Binns, W. R.; Bugaev, V.; Cao, P.; Chen, C.; Chen, P.; Clem, J. M.; Connolly, A.; Dailey, B.; Dasgupta, P.; Deaconu, C.; Cremonesi, L.; Dowkontt, P. F.; Fox, B. D.; Gordon, J.; Hill, B.; Hupe, R.; Israel, M. H.; Jain, P.; Kowalski, J.; Lam, J.; Learned, J. G.; Liewer, K. M.; Liu, T. C.; Matsuno, S.; Miki, C.; Mottram, M.; Mulrey, K.; Nam, J.; Nichol, R. J.; Novikov, A.; Oberla, E.; Prohira, S.; Rauch, B. F.; Romero-Wolf, A.; Rotter, B.; Ratzlaff, K.; Russell, J.; Saltzberg, D.; Seckel, D.; Schoorlemmer, H.; Stafford, S.; Stockham, J.; Stockham, M.; Strutt, B.; Tatem, K.; Varner, G. S.; Vieregg, A. G.; Wissel, S. A.; Wu, F.; Young, R.

    The primary science goal of the NASA-sponsored ANITA project is measurement of ultra-high energy neutrinos and cosmic rays, observed via radio-frequency signals resulting from a neutrino or cosmic ray interaction with terrestrial matter (e.g. atmospheric or ice molecules). Accurate inference of the energies of these cosmic rays requires understanding the transmission/reflection of radio wave signals across the ice-air boundary. Satellite-based measurements of Antarctic surface reflectivity, using a co-located transmitter and receiver, have been performed more-or-less continuously for the last few decades. Our comparison of four different reflectivity surveys, at frequencies ranging from 2 to 45GHz and at near-normal incidence, yield generally consistent maps of high versus low reflectivity, as a function of location, across Antarctica. Using the Sun as an RF source, and the ANITA-3 balloon borne radio-frequency antenna array as the RF receiver, we have also measured the surface reflectivity over the interval 200-1000MHz, at elevation angles of 12-30∘. Consistent with our previous measurement using ANITA-2, we find good agreement, within systematic errors (dominated by antenna beam width uncertainties) and across Antarctica, with the expected reflectivity as prescribed by the Fresnel equations. To probe low incidence angles, inaccessible to the Antarctic Solar technique and not probed by previous satellite surveys, a novel experimental approach (“HiCal-1”) was devised. Unlike previous measurements, HiCal-ANITA constitute a bi-static transmitter-receiver pair separated by hundreds of kilometers. Data taken with HiCal, between 200 and 600MHz shows a significant departure from the Fresnel equations, constant with frequency over that band, with the deficit increasing with obliquity of incidence, which we attribute to the combined effects of possible surface roughness, surface grain effects, radar clutter and/or shadowing of the reflection zone due to Earth

  3. Antifouling polymer brushes displaying antithrombogenic surface properties

    Czech Academy of Sciences Publication Activity Database

    de los Santos Pereira, Andres; Sheikh, S.; Blaszykowski, C.; Pop-Georgievski, Ognen; Fedorov, K.; Thompson, M.; Rodriguez-Emmenegger, Cesar

    2016-01-01

    Roč. 17, č. 3 (2016), s. 1179-1185 ISSN 1525-7797 R&D Projects: GA ČR(CZ) GJ15-09368Y; GA MŠk(CZ) ED1.1.00/02.0109 Grant - others:OPPK(XE) CZ.2.16/3.1.00/21545 Program:OPPK Institutional support: RVO:61389013 Keywords : polymer brushes * surface characterization * antifouling surfaces Subject RIV: BO - Biophysics Impact factor: 5.246, year: 2016

  4. Energy loss of MeV protons specularly reflected from metal surfaces

    International Nuclear Information System (INIS)

    Juaristi, J.I.; Garcia de Abajo, F.J.; Echenique, P.M.

    1996-01-01

    A parameter-free model is presented to study the energy loss of fast protons specularly reflected from metal surfaces. The contributions to the energy loss from excitation of valence-band electrons and ionization of localized target-atom electronic states are calculated separately. The former is calculated from the induced surface wake potential using linear response theory and the specular-reflection model, while the latter is calculated in the first Born approximation. The results obtained are in good agreement with available experimental data. However, the experimental qualitative trend of the energy loss as a function of the angle of incidence is obtained when the valence-band electron model is replaced by localized target atom electron states, though with a worse quantitative agreement. copyright 1996 The American Physical Society

  5. Plasmonic reflectance anisotropy spectroscopy of metal nanoparticles on a semiconductor surface

    Science.gov (United States)

    Kosobukin, V. A.; Korotchenkov, A. V.

    2016-12-01

    A theory of plasmonic differential anisotropic reflection of light from nanoparticles located near the interface between media is developed. The model of a monolayer consisting of identical ellipsoidal metal particles occupying sites of a rectangular lattice is investigated. Effective plasmonic polarizabilities of nanoparticles in the layer are calculated self-consistently using the Green's function technique in the quasipoint dipole approximation. The local-field effect caused by anisotropic dipole plasmons of particles in the layer and their image dipoles is taken into account. The lately observed resonant reflectance anisotropy spectra of indium nanoclusters on InAs surface are explained by the difference between frequencies of plasmons with the orthogonal polarizations in the surface plane. The difference between the plasmon frequencies is attributed to anisotropy of the particles shape or/and the layer structure; the signs of frequency difference for the two types of anisotropy being different.

  6. Glazed ceramic roof tiles: influence of surface features in the solar reflectance index

    International Nuclear Information System (INIS)

    Bortoli, Leitcia Silva de; Stapait, Camila Cristina; Marinoski, Deivis Luis; Fredel, Marcio Celso; Schabbach, Luciana M.

    2016-01-01

    In this study the influence of surface features of ceramic roof tiles in the solar reflectance index were evaluated. Two glazed ceramic roof tiles (type stoneware) with the same color (ivory) but with different appearance (matte and brilliant) were the focus of the analysis. The Solar Reflectance Index (SRI) of the roofs tiles were determined by the solar reflectance values (UV-VIS-NIR) and emittance, measured in laboratory. The samples showed SRI> 39 in accordance with LEED certification criteria (Leadership in Energy and Environmental Design), contributing to minimizing the Heat Island Effects. Although the matte roof tile shows a slightly higher SRI value (82) than the brilliant one (78), the results for the variables that composes the SRI value (reflectance and emittance) were very similar. Analysis of XRD, SEM and EDS performed on the surfaces of the two roofs indicated for the matte glaze the presence of microcrystals (with barium and zinc) that can contribute to the slightly highest value of SRI. The roughness (optical interferometer white light) and the brightness (brightness meter) of the samples were also measured. (author)

  7. Anomalous Quasiparticle Reflection from the Surface of a ^{3}He-^{4}He Dilute Solution.

    Science.gov (United States)

    Ikegami, Hiroki; Kim, Kitak; Sato, Daisuke; Kono, Kimitoshi; Choi, Hyoungsoon; Monarkha, Yuriy P

    2017-11-10

    A free surface of a dilute ^{3}He-^{4}He liquid mixture is a unique system where two Fermi liquids with distinct dimensions coexist: a three-dimensional (3D) ^{3}He Fermi liquid in the bulk and a two-dimensional (2D) ^{3}He Fermi liquid at the surface. To investigate a novel effect generated by the interaction between the two Fermi liquids, the mobility of a Wigner crystal of electrons formed on the free surface of the mixture is studied. An anomalous enhancement of the mobility, compared with the case where the 3D and 2D systems do not interact with each other, is observed. The enhancement is explained by the nontrivial reflection of 3D quasiparticles from the surface covered with the 2D ^{3}He system.

  8. Observations of discrete energy loss effects in spectra of positrons reflected from solid surfaces

    International Nuclear Information System (INIS)

    Dale, J.M.; Hulett, L.D.; Pendyala, S.

    1980-01-01

    Surfaces of tungsten and silicon have been bombarded with monoenergetic beams of positrons and electrons. Spectra of reflected particles show energy loss tails with discrete peaks at kinetic energies about 15 eV lower than that of the elastic peaks. In the higher energy loss range for tungsten, positron spectra show fine structure that is not apparent in the electron spectra. This suggests that the positrons are losing energy through mechanisms different from that of the electrons

  9. Combined analysis of surface reflection imaging and vertical seismic profiling at Yucca Mountain, Nevada

    International Nuclear Information System (INIS)

    Daley, T.M.; Majer, E.L.; Karageorgi, E.

    1994-08-01

    This report presents results from surface and borehole seismic profiling performed by the Lawrence Berkeley Laboratory (LBL) on Yucca Mountain. This work was performed as part of the site characterization effort for the potential high-level nuclear waste repository. Their objective was to provide seismic imaging from the near surface (200 to 300 ft. depth) to the repository horizon and below, if possible. Among the issues addressed by this seismic imaging work are location and depth of fracturing and faulting, geologic identification of reflecting horizons, and spatial continuity of reflecting horizons. The authors believe their results are generally positive, with tome specific successes. This was the first attempt at this scale using modem seismic imaging techniques to determine geologic features on Yucca Mountain. The principle purpose of this report is to present the interpretation of the seismic reflection section in a geologic context. Three surface reflection profiles were acquired and processed as part of this study. Because of environmental concerns, all three lines were on preexisting roads. Line 1 crossed the mapped surface trace of the Ghost Dance fault and it was intended to study the dip and depth extent of the fault system. Line 2 was acquired along Drill Hole wash and was intended to help the ESF north ramp design activities. Line 3 was acquired along Yucca Crest and was designed to image geologic horizons which were thought to be less faulted along the ridge. Unfortunately, line 3 proved to have poor data quality, in part because of winds, poor field conditions and limited time. Their processing and interpretation efforts were focused on lines 1 and 2 and their associated VSP studies

  10. Decadal changes of surface elevation over permafrost area estimated using reflected GPS signals

    Science.gov (United States)

    Liu, Lin; Larson, Kristine M.

    2018-02-01

    Conventional benchmark-based survey and Global Positioning System (GPS) have been used to measure surface elevation changes over permafrost areas, usually once or a few times a year. Here we use reflected GPS signals to measure temporal changes of ground surface elevation due to dynamics of the active layer and near-surface permafrost. Applying the GPS interferometric reflectometry technique to the multipath signal-to-noise ratio data collected by a continuously operating GPS receiver mounted deep in permafrost in Barrow, Alaska, we can retrieve the vertical distance between the antenna and reflecting surface. Using this unique kind of observables, we obtain daily changes of surface elevation during July and August from 2004 to 2015. Our results show distinct temporal variations at three timescales: regular thaw settlement within each summer, strong interannual variability that is characterized by a sub-decadal subsidence trend followed by a brief uplift trend, and a secular subsidence trend of 0.26 ± 0.02 cm year-1 during 2004 and 2015. This method provides a new way to fully utilize data from continuously operating GPS sites in cold regions for studying dynamics of the frozen ground consistently and sustainably over a long time.

  11. Evidence for Surface Water Ice in the Lunar Polar Regions Using Reflectance Measurements from the Lunar Orbiter Laser Altimeter and Temperature Measurements from the Diviner Lunar Radiometer Experiment

    Science.gov (United States)

    Fisher, Elizabeth A.; Lucey, Paul G.; Lemelin, Myriam; Greenhagen, Benjamin T.; Siegler, Matthew A.; Mazarico, Erwan; Aharonson, Oded; Williams, Jean-Pierre; Hayne, Paul O.; Neumann, Gregory A.; hide

    2017-01-01

    We find that the reflectance of the lunar surface within 5 deg of latitude of theSouth Pole increases rapidly with decreasing temperature, near approximately 110K, behavior consistent with the presence of surface water ice. The North polar region does not show this behavior, nor do South polar surfaces at latitudes more than 5 deg from the pole. This South pole reflectance anomaly persists when analysis is limited to surfaces with slopes less than 10 deg to eliminate false detection due to the brightening effect of mass wasting, and also when the very bright south polar crater Shackleton is excluded from the analysis. We also find that south polar regions of permanent shadow that have been reported to be generally brighter at 1064 nm do not show anomalous reflectance when their annual maximum surface temperatures are too high to preserve water ice. This distinction is not observed at the North Pole. The reflectance excursion on surfaces with maximum temperatures below 110K is superimposed on a general trend of increasing reflectance with decreasing maximum temperature that is present throughout the polar regions in the north and south; we attribute this trend to a temperature or illumination-dependent space weathering effect (e.g. Hemingway et al. 2015). We also find a sudden increase in reflectance with decreasing temperature superimposed on the general trend at 200K and possibly at 300K. This may indicate the presence of other volatiles such as sulfur or organics. We identified and mapped surfaces with reflectances so high as to be unlikely to be part of an ice-free population. In this south we find a similar distribution found by Hayne et al. 2015 based on UV properties. In the north a cluster of pixels near that pole may represent a limited frost exposure.

  12. Evidence for surface water ice in the lunar polar regions using reflectance measurements from the Lunar Orbiter Laser Altimeter and temperature measurements from the Diviner Lunar Radiometer Experiment

    Science.gov (United States)

    Fisher, Elizabeth A.; Lucey, Paul G.; Lemelin, Myriam; Greenhagen, Benjamin T.; Siegler, Matthew A.; Mazarico, Erwan; Aharonson, Oded; Williams, Jean-Pierre; Hayne, Paul O.; Neumann, Gregory A.; Paige, David A.; Smith, David E.; Zuber, Maria T.

    2017-08-01

    We find that the reflectance of the lunar surface within 5° of latitude of the South Pole increases rapidly with decreasing temperature, near ∼110 K, behavior consistent with the presence of surface water ice. The North polar region does not show this behavior, nor do South polar surfaces at latitudes more than 5° from the pole. This South pole reflectance anomaly persists when analysis is limited to surfaces with slopes less than 10° to eliminate false detection due to the brightening effect of mass wasting, and also when the very bright south polar crater Shackleton is excluded from the analysis. We also find that south polar regions of permanent shadow that have been reported to be generally brighter at 1064 nm do not show anomalous reflectance when their annual maximum surface temperatures are too high to preserve water ice. This distinction is not observed at the North Pole. The reflectance excursion on surfaces with maximum temperatures below 110 K is superimposed on a general trend of increasing reflectance with decreasing maximum temperature that is present throughout the polar regions in the north and south; we attribute this trend to a temperature or illumination-dependent space weathering effect (e.g. Hemingway et al., 2015). We also find a sudden increase in reflectance with decreasing temperature superimposed on the general trend at 200 K and possibly at 300 K. This may indicate the presence of other volatiles such as sulfur or organics. We identified and mapped surfaces with reflectances so high as to be unlikely to be part of an ice-free population. In this south we find a similar distribution found by Hayne et al. (2015) based on UV properties. In the north a cluster of pixels near that pole may represent a limited frost exposure.

  13. IRAS surface brightness maps of visible reflection nebulae: evidence for non-equilibrium infrared emission

    International Nuclear Information System (INIS)

    Castelaz, M.W.; Werner, M.W.; Sellgren, K.

    1986-01-01

    Surface brightness maps at 12, 25, 60, and 100 microns of 16 visible reflection nebulae were extracted from the Infrared Astronomy Satellite (IRAS) database. The maps were produced by coadding IRAS survey scans over areas centered on the illuminating stars, and have spatial resolutions of 0.9' x 4' at 12 and 25 microns, 1.8' x 4.5' at 60 microns, and 3.6' x 5' at 100 microns. Extended emission in the four IRAS bandpasses was detected in fourteen of the reflection nebulae. The IRAS data were used to measure the flux of the infrared emission associated with each source. The energy distributions show that the 12 micron flux is greater than the 25 micron flux in 11 of the nebulae, and the peak flux occurs in the 60 or 100 micron bandpass in all 16 nebular. The 60 and 100 micron flux can be approximated by blackbodies with temperatures between 30 and 50 K, consistent with temperatures expected from extrapolation of greybody fits to the 60 and 100 micron data. The excess 12 and 25 micron emission is attributed to a nonequilibrium process such as emission from thermal fluctuations of very small grains excited by single ultraviolet photons, or emission from polycyclic aromatic hydrocarbons (PAHs) excited by ultraviolet radiation. The common features of the energy distributions of the 16 reflection nebulae, also seen in the reflection nebulae associated with the Pleiades, suggest that PAHs or very small grains may be found in most reflection nebulae

  14. A fiber-coupled displacement measuring interferometer for determination of the posture of a reflective surface

    International Nuclear Information System (INIS)

    Mao, Shuai; Hu, Peng-Cheng; Ding, Xue-Mei; Tan, Jiu-Bin

    2016-01-01

    A fiber-coupled displacement measuring interferometer capable of determining of the posture of a reflective surface of a measuring mirror is proposed. The newly constructed instrument combines fiber-coupled displacement and angular measurement technologies. The proposed interferometer has advantages of both the fiber-coupled and the spatially beam-separated interferometer. A portable dual-position sensitive detector (PSD)-based unit within this proposed interferometer measures the parallelism of the two source beams to guide the fiber-coupling adjustment. The portable dual PSD-based unit measures not only the pitch and yaw of the retro-reflector but also measures the posture of the reflective surface. The experimental results of displacement calibration show that the deviations between the proposed interferometer and a reference one, Agilent 5530, at two different common beam directions are both less than ±35 nm, thus verifying the effectiveness of the beam parallelism measurement. The experimental results of angular calibration show that deviations of pitch and yaw with the auto-collimator (as a reference) are less than ±2 arc sec, thus proving the proposed interferometer’s effectiveness for determination of the posture of a reflective surface.

  15. Formation of reflective and conductive silver film on ABS surface via covalent grafting and solution spray

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Dexin; Zhang, Yan [School of Mechanical and Automotive Engineering, South China University of Technology, 381 Wushan, Guangzhou 510640 (China); Bessho, Takeshi [Higashifuji Technical Center, Toyota Motor Corporation, 1200 Mishuku, Susono, Shizuoka 410-1193 (Japan); Kudo, Takahiro; Sang, Jing; Hirahara, Hidetoshi; Mori, Kunio [Faculty of Engineering, Iwate University, 4-3-5 Ueda, Morioka 020-8551 (Japan); Kang, Zhixin, E-mail: zxkang@scut.edu.cn [School of Mechanical and Automotive Engineering, South China University of Technology, 381 Wushan, Guangzhou 510640 (China)

    2015-09-15

    Highlights: • A pure and homogenous silver film was deposited by spray-style plating technique. • The mechanism of covalent bonding between coating and substrate was studied. • The silver coating is highly reflective and conductive. • UV light was used to activate the ABS surface with triazine azide derivative. - Abstract: Conductive and reflective silver layers on acrylonitrile butadiene styrene (ABS) plastics have been prepared by photo grafting of triazine azides upon ultraviolet activation, self-assembling of triazine dithiols and silver electroless plating by solution spray based on silver mirror reaction. The as-prepared silver film exhibited excellent adhesion with ABS owing to covalent bonds between coating and substrate, and the detailed bonding mechanism have been investigated by X-ray photoelectron spectroscopy (XPS). X-ray diffraction (XRD) result revealed that silver film on ABS was pure and with a nanocrystalline structure. Atomic force microscope (AFM) analysis demonstrated that massive silver particles with sizes varying from 80 to 120 nm were deposited on ABS and formed a homogenous and smooth coating, resulting in highly reflective surface. Furthermore, silver maintained its unique conductivity even as film on ABS surface in term of four-point probe method.

  16. Formation of reflective and conductive silver film on ABS surface via covalent grafting and solution spray

    International Nuclear Information System (INIS)

    Chen, Dexin; Zhang, Yan; Bessho, Takeshi; Kudo, Takahiro; Sang, Jing; Hirahara, Hidetoshi; Mori, Kunio; Kang, Zhixin

    2015-01-01

    Highlights: • A pure and homogenous silver film was deposited by spray-style plating technique. • The mechanism of covalent bonding between coating and substrate was studied. • The silver coating is highly reflective and conductive. • UV light was used to activate the ABS surface with triazine azide derivative. - Abstract: Conductive and reflective silver layers on acrylonitrile butadiene styrene (ABS) plastics have been prepared by photo grafting of triazine azides upon ultraviolet activation, self-assembling of triazine dithiols and silver electroless plating by solution spray based on silver mirror reaction. The as-prepared silver film exhibited excellent adhesion with ABS owing to covalent bonds between coating and substrate, and the detailed bonding mechanism have been investigated by X-ray photoelectron spectroscopy (XPS). X-ray diffraction (XRD) result revealed that silver film on ABS was pure and with a nanocrystalline structure. Atomic force microscope (AFM) analysis demonstrated that massive silver particles with sizes varying from 80 to 120 nm were deposited on ABS and formed a homogenous and smooth coating, resulting in highly reflective surface. Furthermore, silver maintained its unique conductivity even as film on ABS surface in term of four-point probe method

  17. The infrared properties of reusable surface insulations.

    Science.gov (United States)

    Schmitt, R. J.; Linford, R. M. F.; Dillow, C. F.; Hughes, T. A.

    1973-01-01

    The total infrared scattering and absorption cross sections of both flexible and rigidized high temperature fibrous insulations have been measured. The methods for accomplishing these measurements are described. Infrared reflection and transmission spectra were obtained to study the dependence of the total cross sections on the spectral characteristics of the transported radiation. These results are applied to steady-state effective thermal conductivity measurements via a four-flux model of radiative heat transfer to separate the radiative component and to calculate the effective thermal conductivity under transient heating conditions. Data for both silica and mullite fibers are presented.

  18. Measurement and modelization of silica opal reflection properties: Optical determination of the silica index

    Science.gov (United States)

    Avoine, Amaury; Hong, Phan Ngoc; Frederich, Hugo; Frigerio, Jean-Marc; Coolen, Laurent; Schwob, Catherine; Nga, Pham Thu; Gallas, Bruno; Maître, Agnès

    2012-10-01

    Self-assembled artificial opals (in particular silica opals) constitute a model system to study the optical properties of three-dimensional photonic crystals. The silica optical index is a key parameter to correctly describe an opal but is difficult to measure at the submicrometer scale and usually treated as a free parameter. Here, we propose a method to extract the silica index from the opal reflection spectra and we validate it by comparison with two independent methods based on infrared measurements. We show that this index gives a correct description of the opal reflection spectra, either by a band structure or by a Bragg approximation. In particular, we are able to provide explanations in quantitative agreement with the measurements for two features : the observation of a second reflection peak in specular direction, and the quasicollapse of the p-polarized main reflection peak at a typical angle of 54∘.

  19. Tuning antimicrobial properties of biomimetic nanopatterned surfaces.

    Science.gov (United States)

    Michalska, Martyna; Gambacorta, Francesca; Divan, Ralu; Aranson, Igor S; Sokolov, Andrey; Noirot, Philippe; Laible, Philip D

    2018-04-05

    Nature has amassed an impressive array of structures that afford protection from microbial colonization/infection when displayed on the exterior surfaces of organisms. Here, controlled variation of the features of mimetics derived from etched silicon allows for tuning of their antimicrobial efficacy. Materials with nanopillars up to 7 μm in length are extremely effective against a wide range of microbial species and exceed the performance of natural surfaces; in contrast, materials with shorter/blunter nanopillars (<2 μm) selectively killed specific species. Using a combination of microscopies, the mechanisms by which bacteria are killed are demonstrated, emphasizing the dependence upon pillar density and tip geometry. Additionally, real-time imaging reveals how cells are immobilized and killed rapidly. Generic or selective protection from microbial colonization could be conferred to surfaces [for, e.g., internal medicine, implants (joint, dental, and cosmetic), food preparation, and the agricultural industry] patterned with these materials as coatings.

  20. Manganese phospate physical chemistry and surface properties

    International Nuclear Information System (INIS)

    Najera R, N.; Romero G, E. T.

    2008-01-01

    This paper presents the methodology for the manganese phosphate (III) synthesis (MnP0 4 H 2 0) from manganese chloride. The physicochemical characterization was carried out by: X-ray diffraction, scanning electron microscopy, infrared analysis and thermal gravimetric analysis. The surface characterization is obtained through the determination of surface area, point of zero charge and kinetics of moisture. As a phosphate compound of a metal with low oxidation state is a promising compound for removal pollutants from water and soil, can be used for the potential construction of containment barriers for radioactive wastes. (Author)

  1. Composition and physical properties of Enceladus' surface

    Science.gov (United States)

    Brown, R.H.; Clark, R.N.; Buratti, B.J.; Cruikshank, D.P.; Barnes, J.W.; Mastrapa, R.M.E.; Bauer, J.; Newman, S.; Momary, T.; Baines, K.H.; Bellucci, G.; Capaccioni, F.; Cerroni, P.; Combes, M.; Coradini, A.; Drossart, P.; Formisano, V.; Jaumann, R.; Langavin, Y.; Matson, D.L.; McCord, T.B.; Nelson, R.M.; Nicholson, P.D.; Sicardy, B.; Sotin, Christophe

    2006-01-01

    Observations of Saturn's satellite Enceladus using Cassini's Visual and Infrared Mapping Spectrometer instrument were obtained during three flybys of Enceladus in 2005. Enceladus' surface is composed mostly of nearly pure water ice except near its south pole, where there are light organics, CO2, and amorphous and crystalline water ice, particularly in the region dubbed the "tiger stripes." An upper limit of 5 precipitable nanometers is derived for CO in the atmospheric column above Enceladus, and 2% for NH 3 in global surface deposits. Upper limits of 140 kelvin (for a filled pixel) are derived for the temperatures in the tiger stripes.

  2. Structural and electronic properties of hydrosilylated silicon surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Baumer, A.

    2005-11-15

    The structural and electronic properties of alkyl-terminated Si surfaces prepared by thermallyinduced hydrosilylation have been studied in detail in the preceding chapters. Various surfaces have been used for the functionalization ranging from crystalline Si over amorphous hydrogenated Si to nanoscaled materials such as Si nanowires and nanoparticles. In each case, the alkyl-terminated surfaces have been compared to the native oxidized and H-terminated surfaces. (orig.)

  3. Surface properties of semi-infinite Fermi systems

    International Nuclear Information System (INIS)

    Campi, X.; Stringari, S.

    1979-10-01

    A functional relation between the kinetic energy density and the total density is used to analyse the surface properties of semi-infinite Fermi systems. One find an explicit expression for the surface thickness in which the role of the infinite matter compressibility, binding energy and non-locality effects is clearly shown. The method, which holds both for nuclear and electronic systems (liquid metals), yields a very simple relation between the surface thickness and the surface energy

  4. Adsorption Properties of the Cu(115) Surface

    DEFF Research Database (Denmark)

    Godowski, P. J.; Groso, A.; Hoffmann, S. V.

    2010-01-01

    The interfaces: K/Cu(115) and CO/Cu(115) have been characterized using surface sensitive techniques, including low energy electron diffraction and photoelectron spectroscopy. K adatoms show tendency to occupy the sites close to the step edges. At low temperature (near 125 K), after completion of ...

  5. Wetting Properties of Molecularly Rough Surfaces

    Czech Academy of Sciences Publication Activity Database

    Svoboda, Martin; Malijevský, Alexandr; Lísal, Martin

    2015-01-01

    Roč. 143, č. 10 (2015), s. 104701 ISSN 0021-9606 R&D Projects: GA ČR GA13-09914S; GA MŠk LH12020 Institutional support: RVO:67985858 Keywords : contant-angle * solid-surface * dynamics Subject RIV: BJ - Thermodynamics Impact factor: 2.894, year: 2015

  6. Characterization of the Vajont landslide (North-Eastern Italy) by means of reflection and surface wave seismics

    Science.gov (United States)

    Petronio, Lorenzo; Boaga, Jacopo; Cassiani, Giorgio

    2016-05-01

    The mechanisms of the disastrous Vajont rockslide (North-Eastern Italy, October 9, 1963) have been studied in great detail over the past five decades. Nevertheless, the reconstruction of the rockslide dynamics still presents several uncertainties, including those related to the accurate estimation of the actual landslide mass. This work presents the results of a geophysical characterization of the Vajont landslide body in terms of material properties and buried geometry. Both aspects add new information to the existing dataset and will help a better understanding of the rockslide failure mechanisms and dynamics. In addition, some general considerations concerning the intricacies of landslide characterization can be drawn, with due attention to potential pitfalls. The employed techniques are: (i) high resolution P-wave reflection, (ii) high resolution SH-wave reflection, (iii) controlled source surface wave analysis. We adopted as a seismic source a vibrator both for P waves and SH waves, using vertical and horizontal geophones respectively. For the surface wave seismic survey we used a heavy drop-weight source and low frequency receivers. Despite the high noise level caused by the fractured conditions of the large rock body, a common situation in landslide studies, we managed to achieve a satisfying imaging quality of the landslide structure thanks to the large number of active channels, the short receiver interval and the test of appropriate seismic sources. The joint use of different seismic techniques help focus the investigation on the rock mass mechanical properties. Results are in good agreement with the available borehole data, the geological sections and the mechanical properties of the rockmass estimated by other studies. In general the proposed approach is likely to be applicable successfully to similar situations where scattering and other noise sources are a typical bottleneck to geophysical data acquisition on landslide bodies.

  7. Determining surface coverage of ultra-thin gold films from X-ray reflectivity measurements

    International Nuclear Information System (INIS)

    Kossoy, A.; Simakov, D.; Olafsson, S.; Leosson, K.

    2013-01-01

    The paper describes usage of X-ray reflectivity for characterization of surface coverage (i.e. film continuity) of ultra-thin gold films which are widely studied for optical, plasmonic and electronic applications. The demonstrated method is very sensitive and can be applied for layers below 1 nm. It has several advantages over other techniques which are often employed in characterization of ultra-thin metal films, such as optical absorption, Atomic Force Microscopy, Transmission Electron Microscopy or Scanning Electron Microscopy. In contrast to those techniques our method does not require specialized sample preparation and measurement process is insensitive to electrostatic charge and/or presence of surface absorbed water. We validate our results with image processing of Scanning Electron Microscopy images. To ensure precise quantitative analysis of the images we developed a generic local thresholding algorithm which allowed us to treat series of images with various values of surface coverage with similar image processing parameters. - Highlights: • Surface coverage/continuity of ultra-thin Au films (up to 7 nm) was determined. • Results from X-ray reflectivity were verified by scanning electron microscopy. • We developed local thresholding algorithm to treat non-homogeneous image contrast

  8. Retrieval of optical properties of skin from measurement and modeling the diffuse reflectance

    Science.gov (United States)

    Douven, Lucien F. A.; Lucassen, Gerald W.

    2000-06-01

    We present results on the retrieval of skin optical properties obtained by fitting of measurements of the diffuse reflectance of human skin. Reflectance spectra are simulated using an analytical model based on the diffusion approximation. This model is implemented in a simplex fit routine. The skin optical model used consists of five layers representing epidermis, capillary blood plexus, dermis, deep blood plexus and hypodermis. The optical properties of each layer are assumed homogeneously distributed. The main optical absorbers included are melanin in epidermis and blood. The experimental setup consists of a HP photospectrometer equipped with a remote fiber head. Total reflectance spectra were measured in the 400 - 820 nm wavelength range on the volar underarm of 19 volunteers under various conditions influencing the blood content and oxygenation degree. Changes in the reflectance spectra were observed. Using the fit routine changes in blood content in the capillary blood plexus and in the deep blood plexus could be quantified. These showed different influences on the total reflectance. The method can be helpful to quantitatively assess changes in skin color appearance such as occurs in the treatment of port wine stains, blanching, skin irritation and tanning.

  9. Sputtering properties of tungsten 'fuzzy' surfaces

    International Nuclear Information System (INIS)

    Nishijima, D.; Baldwin, M.J.; Doerner, R.P.; Yu, J.H.

    2011-01-01

    Sputtering yields of He-induced W 'fuzzy' surfaces bombarded by Ar have been measured in the linear divertor plasma simulator PISCES-B. It is found that the sputtering yield of a fuzzy surface, Y fuzzy , decreases with increasing fuzzy layer thickness, L, and saturates at ∼10% of that of a smooth surface, Y smooth , at L > 1 μm. The reduction in the sputtering yield is suspected to be due mainly to the porous structure of fuzz, since the ratio, Y fuzzy /Y smooth follows (1 - p fuzz ), where p fuzz is the fuzz porosity. Further, Y fuzzy /Y smooth is observed to increase with incident ion energy, E i . This may be explained by an energy dependent change in the angular distribution of sputtered W atoms, since at lower E i , the angular distribution is observed to become more butterfly-shaped. That is, a larger fraction of sputtered W atoms can line-of-sight deposit/stick onto neighboring fuzz nanostructures for lower E i butterfly distributions, resulting in lower ratio of Y fuzzy /Y smooth .

  10. Simulation calculations of physical sputtering and reflection coefficient of plasma-irradiated carbon surface

    International Nuclear Information System (INIS)

    Kawamura, T.; Ono, T.; Yamamura, Y.

    1994-08-01

    Physical sputtering yields from the carbon surface irradiated by the boundary plasma are obtained with the use of a Monte Carlo simulation code ACAT. The yields are calculated for many random initial energy and angle values of incident protons or deuterons with a Maxwellian velocity distribution, and then averaged. Here the temperature of the boundary plasma, the sheath potential and the angle δ between the magnetic field line and the surface normal are taken into account. A new fitting formula for an arrangement of the numerical data of sputtering yield is introduced, in which six fitting parameters are determined from the numerical results and listed. These results provide a way to estimate the erosion of carbon materials irradiated by boundary plasma. The particle reflection coefficients for deuterons and their neutrals from a carbon surface are also calculated by the same code and presented together with, for comparison, that for the case of monoenergetic normal incidence. (author)

  11. Low temperature self-cleaning properties of superhydrophobic surfaces

    Science.gov (United States)

    Wang, Fajun; Shen, Taohua; Li, Changquan; Li, Wen; Yan, Guilong

    2014-10-01

    Outdoor surfaces are usually dirty surfaces. Ice accretion on outdoor surfaces could lead to serious accidents. In the present work, the superhydrophobic surface based on 1H, 1H, 2H, 2H-Perfluorodecanethiol (PFDT) modified Ag/PDMS composite was prepared to investigate the anti-icing property and self-cleaning property at temperatures below freezing point. The superhydrophobic surface was deliberately polluted with activated carbon before testing. It was observed that water droplet picked up dusts on the cold superhydrophobic surface and took it away without freezing at a measuring temperature of -10 °C. While on a smooth PFDT surface and a rough surface base on Ag/PDMS composite without PFDT modification, water droplets accumulated and then froze quickly at the same temperature. However, at even lower temperature of -12 °C, the superhydrophobic surface could not prevent the surface water from icing. In addition, it was observed that the frost layer condensed from the moisture pay an important role in determining the low temperature self-cleaning properties of a superhydrophobic surface.

  12. Automatic and improved radiometric correction of Landsat imagery using reference values from MODIS surface reflectance images

    Science.gov (United States)

    Pons, X.; Pesquer, L.; Cristóbal, J.; González-Guerrero, O.

    2014-12-01

    Radiometric correction is a prerequisite for generating high-quality scientific data, making it possible to discriminate between product artefacts and real changes in Earth processes as well as accurately produce land cover maps and detect changes. This work contributes to the automatic generation of surface reflectance products for Landsat satellite series. Surface reflectances are generated by a new approach developed from a previous simplified radiometric (atmospheric + topographic) correction model. The proposed model keeps the core of the old model (incidence angles and cast-shadows through a digital elevation model [DEM], Earth-Sun distance, etc.) and adds new characteristics to enhance and automatize ground reflectance retrieval. The new model includes the following new features: (1) A fitting model based on reference values from pseudoinvariant areas that have been automatically extracted from existing reflectance products (Terra MODIS MOD09GA) that were selected also automatically by applying quality criteria that include a geostatistical pattern model. This guarantees the consistency of the internal and external series, making it unnecessary to provide extra atmospheric data for the acquisition date and time, dark objects or dense vegetation. (2) A spatial model for atmospheric optical depth that uses detailed DEM and MODTRAN simulations. (3) It is designed so that large time-series of images can be processed automatically to produce consistent Landsat surface reflectance time-series. (4) The approach can handle most images, acquired now or in the past, regardless of the processing system, with the exception of those with extremely high cloud coverage. The new methodology has been successfully applied to a series of near 300 images of the same area including MSS, TM and ETM+ imagery as well as to different formats and processing systems (LPGS and NLAPS from the USGS; CEOS from ESA) for different degrees of cloud coverage (up to 60%) and SLC

  13. A fundamental approach to adhesion: Synthesis, surface analysis, thermodynamics and mechanics. [acid-base properties of titanium 6-4 surfaces

    Science.gov (United States)

    Siriwardane, R.; Wightman, J. P.

    1980-01-01

    The acid-base properties of titanium 6-4 plates (low surface area) were investigated after three different pretreatments, namely Turco, phosphate-fluoride and Pasa-Jell. A series of indicators was used and color changes were detected using diffuse reflectance visible spectroscopy. Electron spectroscopy for chemical analysis was used to examine the indicator on the Ti 6-4 surface. Specular reflectance infra-red spectroscopy was used to study the adsorption of stearic acid from cyclohexane solutions on the Ti 6-4 surface.

  14. Surface morphology, structural and electrical properties of RF ...

    Indian Academy of Sciences (India)

    5

    electrical properties of RF sputtered ITO thin films deposited onto Si(100). .... scanning electron microscopy (SEM) surface images are shown along with the cross- ..... annealing effect”, J. of Alloys and Compounds 509, (2011) 6072-6076.

  15. Pseudopotentials for calculating the bulk and surface properties of solids

    International Nuclear Information System (INIS)

    Cohen, M.L.

    1983-01-01

    A survey is presented describing research in condensed matter physics using pseudopotentials to calculate electronic, structural, and vibrational properties of solids. Semiconductors are emphasized, and both bulk and surface calculations are discussed. (author) [pt

  16. Effect of retardation on the reflectance properties of the metallic Fibonacci quasi-superlattice

    International Nuclear Information System (INIS)

    Feng Weiguo; Yao Hesheng; Xu Xiang

    1989-12-01

    Based on the hydrodynamic model theory and the transfer matrix method, we have re-examined the reflection properties by taking account of the retardation effect to the system of the metallic Fibonacci quasi-superlattice. For the normal incident S-polarized Soft X-rays and extreme ultraviolet, we find that the self-similar reflecting spectrum will be restrained with the increasing of the retardation, but for the higher frequency region or at the smaller grazing angle, the self similarity will still exist for the lower generation quasi-superlattice. (author). 19 refs, 2 figs, 1 tab

  17. Accounting for surface reflectance in the derivation of vertical column densities of NO2 from airborne imaging DOAS

    Science.gov (United States)

    Meier, Andreas Carlos; Schönhardt, Anja; Richter, Andreas; Bösch, Tim; Seyler, André; Constantin, Daniel Eduard; Shaiganfar, Reza; Merlaud, Alexis; Ruhtz, Thomas; Wagner, Thomas; van Roozendael, Michel; Burrows, John. P.

    2016-04-01

    Nitrogen oxides, NOx (NOx = NO + NO2) play a key role in tropospheric chemistry. In addition to their directly harmful effects on the respiratory system of living organisms, they influence the levels of tropospheric ozone and contribute to acid rain and eutrophication of ecosystems. As they are produced in combustion processes, they can serve as an indicator for anthropogenic air pollution. In the late summers of 2014 and 2015, two extensive measurement campaigns were conducted in Romania by several European research institutes, with financial support from ESA. The AROMAT / AROMAT-2 campaigns (Airborne ROmanian Measurements of Aerosols and Trace gases) were dedicated to measurements of air quality parameters utilizing newly developed instrumentation at state-of-the-art. The experiences gained will help to calibrate and validate the measurements taken by the upcoming Sentinel-S5p mission scheduled for launch in 2016. The IUP Bremen contributed to these campaigns with its airborne imaging DOAS (Differential Optical Absorption Spectroscopy) instrument AirMAP (Airborne imaging DOAS instrument for Measurements of Atmospheric Pollution). AirMAP allows retrieving spatial distributions of trace gas columns densities in a stripe below the aircraft. The measurements have a high spatial resolution of approximately 30 x 80 m2 (along x across track) at a typical flight altitude of 3000 m. Supported by the instrumental setup and the large swath, gapless maps of trace gas distributions above a large city, like Bucharest or Berlin, can be acquired within a time window of approximately two hours. These properties make AirMAP a valuable tool for the validation of trace gas measurements from space. DOAS retrievals yield the density of absorbers integrated along the light path of the measurement. The light path is altered with a changing surface reflectance, leading to enhanced / reduced slant column densities of NO2 depending on surface properties. This effect must be considered in

  18. The Normalization of Surface Anisotropy Effects Present in SEVIRI Reflectances by Using the MODIS BRDF Method

    Science.gov (United States)

    Proud, Simon Richard; Zhang, Qingling; Schaaf, Crystal; Fensholt, Rasmus; Rasmussen, Mads Olander; Shisanya, Chris; Mutero, Wycliffe; Mbow, Cheikh; Anyamba, Assaf; Pak, Ed; hide

    2014-01-01

    A modified version of the MODerate resolution Imaging Spectroradiometer (MODIS) bidirectional reflectance distribution function (BRDF) algorithm is presented for use in the angular normalization of surface reflectance data gathered by the Spinning Enhanced Visible and InfraRed Imager (SEVIRI) aboard the geostationary Meteosat Second Generation (MSG) satellites. We present early and provisional daily nadir BRDFadjusted reflectance (NBAR) data in the visible and near-infrared MSG channels. These utilize the high temporal resolution of MSG to produce BRDF retrievals with a greatly reduced acquisition period than the comparable MODIS products while, at the same time, removing many of the angular perturbations present within the original MSG data. The NBAR data are validated against reflectance data from the MODIS instrument and in situ data gathered at a field location in Africa throughout 2008. It is found that the MSG retrievals are stable and are of high-quality across much of the SEVIRI disk while maintaining a higher temporal resolution than the MODIS BRDF products. However, a number of circumstances are discovered whereby the BRDF model is unable to function correctly with the SEVIRI observations-primarily because of an insufficient spread of angular data due to the fixed sensor location or localized cloud contamination.

  19. Effects of high-temperature gas dealkalization on surface mechanical properties of float glass

    Science.gov (United States)

    Senturk, Ufuk

    The surface topography, and the near-surface structure and mechanical property changes on float glass, that was treated in atmospheres containing SOsb2, HCl, and 1,1 difluoroethane (DFE) gases, at temperatures in the glass transition region, were studied. Structure was investigated using surface sensitive infrared spectroscopy techniques (attenuated total reflectance (ATR) and diffuse reflectance (DRIFT)) and the topography was evaluated using atomic force microscopy (AFM). The results obtained from the two FTIR methods were in agreement with each other. Mechanical property characteristics of the surface were determined by measuring microhardness using a recording microindentation set-up. A simple analysis performed on the three hardness calculation methods-LVH, LVHsb2, and Lsb2VH-indicated that LVH and LVHsb2 are less effected by measurement errors and are better suited for the calculation of hardness. Contact damage characteristics of the treated glass was also studied by monitoring the crack initiation behavior during indentation, using acoustic emission. The results of the studies, aiming for the understanding of the structure, topography, and hardness property changes indicate that the treatment parameters-temperature, time, and treatment atmosphere conditions-are significant factors influencing these properties. The analysis of these results suggest a relation to exist between the three properties. This relation is used in understanding the surface mechanical properties of the treated float glasses. The difference in the thermal expansion coefficients between the dealkalized surface and bulk, the nature of surface structure changes, structural relaxation, surface water content, and glass transformation temperature are identified as the major factors having an influence on the properties. A model connecting these features is suggested. A difference in the structure, hardness, and topography on the air and tin sides of float glass is also shown to exist. The

  20. Reflecting and Polarizing Properties of Conductive Fabrics in Ultra-High Frequency Range

    Directory of Open Access Journals (Sweden)

    Oleg Kiprijanovič

    2015-09-01

    Full Text Available The system based on ultra-wide band (UWB signals was employed for qualitative estimation of attenuating, reflecting and polarizing properties of conductive fabrics, capable to prevent local static charge accumulation. Pulsed excitation of triangle monopole antenna of 6.5 cm height by rectangular electric pulses induced radiation of UWB signals with spectral density of power having maximum in ultra-high frequency (UHF range. The same antenna was used for the radiated signal receiving. Filters and amplifiers of different passband were employed to divide UHF range into subranges of 0.3-0.55 GHz, 0.55-1 GHz, 1-2 GHz and 2-4 GHz bands. The free space method, when conductive fabric samples of 50x50 cm2 were placed between transmitting and receiving antennas, was used to imitate a practical application. Received wideband signals corresponding to the defined range were detected by unbiased detectors. The fabrics made of two types of warps, containing different threads with conductive yarns, were investigated. It was estimated attenuation and reflective properties of the fabrics when electric field is collinear or perpendicular to thread direction. In the UHF range it was revealed good reflecting properties of the fabrics containing metallic component in the threads. The system has advantages but not without a certain shortcoming. Adapting it for specific tasks should lead to more effective usage, including yet unused properties of the UWB signals.

  1. Mathematical Modeling of Radiant Heat Transfer in Mirror Systems Considering Deep Reflecting Surface Defects

    Directory of Open Access Journals (Sweden)

    V. V. Leonov

    2014-01-01

    Full Text Available When designing large-sized mirror concentrating systems (MCS for high-temperature solar power plants, one must have at disposal reasonably reliable and economical methods and tools, making it possible to analyze its characteristics, to predict them depending on the operation conditions and accordingly to choose the most suitable system for the solution of particular task.Experimental determination of MCS characteristics requires complicated and expensive experimentation, having significant limitations on interpretation of the results, as well as limitations imposed due to the size of the structure. Therefore it is of particular interest to develop a mathematical model capable of estimating power characteristics of MCS considering the influence of operating conditions, design features, roughness and other surface defects.For efficient solution of the tasks the model must ensure simulation of solar radiant flux as well as simulation of geometrical and optical characteristics of reflection surface and their interaction. In this connection a statistical mathematical model of radiation heat exchange based on use of Monte Carlo methods and Finite Element Method was developed and realized in the software complex, making it possible to determine main characteristics of the MCS.In this paper the main attention is given to definition of MCS radiation characteristics with account for deep reflecting surface defects (cavities, craters. Deep cavities are not typical for MCS, but their occurrence is possible during operation as a result of erosion or any physical damage. For example, for space technology it is primarily micrometeorite erosion.

  2. Tailoring Silica Surface Properties by Plasma Polymerization for Elastomer Applications

    NARCIS (Netherlands)

    Tiwari, M.; Dierkes, Wilma K.; Datta, Rabin; Talma, Auke; Noordermeer, Jacobus W.M.; van Ooij, W.J.

    2009-01-01

    The surface properties of reinforcing fillers are a crucial factor for dispersion and filler–polymer interaction in rubber compounds, as they strongly influence the final vulcanized properties of the rubber article. Silica is gaining more and more importance as reinforcing filler for rubbers, as it

  3. Tailoring Silica Surface Properties by Plasma Polymerization for Elastomer Applications

    NARCIS (Netherlands)

    Tiwari, M.; Dierkes, W.K.; Datta, R.N.; Talma, A.G.; Noordermeer, J.W.M.; van Ooij, W.J.

    2011-01-01

    The surface properties of reinforcing fillers are a crucial factor for dispersion and filler–polymer interaction in rubber compounds, as they strongly influence the final vulcanized properties of the rubber article. Silica is gaining more and more importance as reinforcing filler for rubbers, as it

  4. Laser alloying of aluminium to improve surface properties - MSSA 2010

    CSIR Research Space (South Africa)

    Mabhali, Luyolo AB

    2010-07-01

    Full Text Available and microstructure of the surface without affecting the bulk properties of the material. The process involves melting the substrate surface and injecting the powder of the alloying material into the melt pool. Process parameters such as laser power, beam spot size...

  5. A validation study of the psychometric properties of the Groningen Reflection Ability Scale

    DEFF Research Database (Denmark)

    Andersen, Nina Bjerre; O'Neill, Lotte; Gormsen, Lise Kirstine

    2014-01-01

    Background Reflection, the ability to examine critically one’s own learning and functioning, is considered important for ‘the good doctor’. The Groningen Reflection Ability Scale (GRAS) is an instrument measuring student reflection, which has not yet been validated beyond the original Dutch study....... The aim of this study was to adapt GRAS for use in a Danish setting and to investigate the psychometric properties of GRAS-DK. Methods We performed a cross-cultural adaptation of GRAS from Dutch to Danish. Next, we collected primary data online, performed a retest, analysed data descriptively, estimated...... measurement error, performed an exploratory and a confirmatory factor analysis to test the proposed three-factor structure. Results 361 (69%) of 523 invited students completed GRAS-DK. Their mean score was 88 (SD = 11.42; scale maximum 115). Scores were approximately normally distributed. Measurement error...

  6. Estimating the Augmented Reflectance Ratio of the Ocean Surface When Whitecaps Appear

    Directory of Open Access Journals (Sweden)

    Zhantang Xu

    2015-10-01

    Full Text Available The presence of foam influences the accuracy of satellite-derived water-leaving radiance. A model has been developed to estimate the augmented reflectance ratio (A(λ,U due to differences in the fraction of whitecap coverage (w on the ocean surface. A(λ,U can be calculated from the product of w and ρ(λ,U, where ρ(λ,U is the augmented ratio of the reflectance of background water (Rb(λ caused by the presence of whitecaps. Our results showed that the average A(400~700,U in the visible region was approximately 1.3% at U = 9 m∙s−1, 2.2% at U = 10 m∙s−1, 4.4% at U = 12 m∙s−1, 7.4% at U = 14 m∙s−1, 19% at U = 19 m∙s−1 and 37.9% at U = 24 m∙s−1, making it is necessary to consider the augmented reflectance ratio for remote sensing applications. By estimating remote sensing augmented reflectance using A(λ,U, it was found that the result was in good agreement with previous studies conducted in other areas with U from 9 to 12 m∙s−1. Since Rb(λ is temporally and spatially variable, our model considered the variation of Rb(λ, whereas existing models have assumed that Rb(λ is constant. Therefore, the proposed model is more suitable for estimating the augmented reflectance ratio due to whitecaps.

  7. Surface properties and microporosity of polyhydroxybutyrate under scanning electron microscopy

    International Nuclear Information System (INIS)

    Raouf, A.A.; Samsudin, A.R.; Samian, R.; Akool, K.; Abdullah, N.

    2004-01-01

    This study was designed to investigate the surface properties especially surface porosity of polyhydroxybutyrate (PHB) using scanning electron microscopy. PHB granules were sprinkled on the double-sided sticky tape attached on a SEM aluminium stub and sputtered with gold (10nm thickness) in a Polaron SC515 Coater, following which the samples were placed into the SEM specimen chamber for viewing and recording. Scanning electron micrographs with different magnification of PHB surface revealed multiple pores with different sizes. (Author)

  8. Microwave reflection properties of planar anisotropy Fe50Ni50 powder/paraffin composites

    International Nuclear Information System (INIS)

    Wei Jian-Qiang; Zhang Zhao-Qi; Han Rui; Wang Tao; Li Fa-Shen

    2012-01-01

    The reflection properties of planar anisotropy Fe 50 Ni 50 powder/paraffin composites have been studied in the microwave frequency range. The permeability of Fe 50 Ni 50 powder/paraffin composites is greatly enhanced by introducing the planar anisotropy, and can be further enhanced by using a rotational orientation method. The complex permeability can be considered as the superposition of two types of magnetic resonance. The resonance peak at high frequency is attributed to the natural resonance, while the peak at low frequency is attributed to the domain-wall resonance. The simulated results of the microwave reflectivity show that the matching thickness, peak frequency, permeability, and permittivity are closely related to the quarter wavelength matching condition. The Fe 50 Ni 50 powder/paraffin composites can be attractive candidates for thinner microwave absorbers in the L-band (1–2 GHz). (condensed matter: electronic structure, electrical, magnetic, and optical properties)

  9. Quantum state-resolved gas/surface reaction dynamics probed by reflection absorption infrared spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Chen Li [Department of Dynamics at Surfaces, Max Planck Institute for Biophysical Chemistry, Am Fassberg 11, Goettingen (Germany); Ueta, Hirokazu; Beck, Rainer D. [Laboratoire de Chimie Physique Moleculaire, Ecole Polytechnique Federale de Lausanne (Switzerland); Bisson, Regis [Aix-Marseille Universite, PIIM, CNRS, UMR 7345, 13397 Marseille (France)

    2013-05-15

    We report the design and characterization of a new molecular-beam/surface-science apparatus for quantum state-resolved studies of gas/surface reaction dynamics combining optical state-specific reactant preparation in a molecular beam by rapid adiabatic passage with detection of surface-bound reaction products by reflection absorption infrared spectroscopy (RAIRS). RAIRS is a non-invasive infrared spectroscopic detection technique that enables online monitoring of the buildup of reaction products on the target surface during reactant deposition by a molecular beam. The product uptake rate obtained by calibrated RAIRS detection yields the coverage dependent state-resolved reaction probability S({theta}). Furthermore, the infrared absorption spectra of the adsorbed products obtained by the RAIRS technique provide structural information, which help to identify nascent reaction products, investigate reaction pathways, and determine branching ratios for different pathways of a chemisorption reaction. Measurements of the dissociative chemisorption of methane on Pt(111) with this new apparatus are presented to illustrate the utility of RAIRS detection for highly detailed studies of chemical reactions at the gas/surface interface.

  10. Capabilities of using white x-rays for the reconstruction of surface morphology from coherent reflectivity

    Energy Technology Data Exchange (ETDEWEB)

    Sant, Tushar, E-mail: tushar@physik.uni-siegen.de [Solid State Physics Group, University of Siegen, 57068 Siegen (Germany); Panzner, Tobias [Paul Scherrer Institute (Switzerland); Pietsch, Ullrich [Solid State Physics Group, University of Siegen, 57068 Siegen (Germany)

    2010-10-15

    We present a new method to reconstruct the surface profile of a sample from coherent reflectivity data of a white x-ray beam experiment. As an example the surface profile of a laterally confined silicon wafer has been reconstructed quantitatively from static speckle measurements using white coherent x-rays from a bending magnet in the energy range between 5 < E < 20 keV. As a consequence of using white radiation, speckles appear in addition to the Airy pattern caused by scattering at the entrance pinhole. Nevertheless, the surface profile of a triangularly shaped specimen was reconstructed considering sufficient oversampling between the beam-footprint and the effective sample width. For the profile reconstruction the Error-Reduction phase retrieval algorithm was modified by including the spectral illumination function and a Fresnel propagator term. The simultaneous use of different x-ray energies having different penetration depth provides information on the evolution of the surface profile from the near-surface towards the bulk. The limitations of present experiment can be overcome using white or pink radiation from a source with higher photon flux.

  11. The conditions for total reflection of low-energy atoms from crystal surfaces

    International Nuclear Information System (INIS)

    Hou, M.; Robinson, M.T.

    1978-01-01

    The critical angles for the total reflection of low-energy particles from Cu rows and (001) planes have been investigated, using the binary collision approximation computer simulation code MARLOWE Breakthrough angles were evaluated for H, N, Ne, Ar, Cu, Xe, and Au in the energy range from 0.1 to 7.5 keV. In both the axial and the planar cases, recoiling of the target atoms lowers the energy barrier which the target surface presents to the heavy projectiles. Consequently, the breakthrough angles are reduced for heavy projectiles below the values expected either from observations on light projectiles or from analytical channeling theory. (orig.) [de

  12. Assessment of Satellite-Derived Surface Reflectances by NASA's CAR Airborne Radiometer over Railroad Valley, Nevada

    Science.gov (United States)

    Kharbouche, Said; Muller, Jan-Peter; Gatebe, Charles K.; Scanlon, Tracy; Banks, Andrew C.

    2017-01-01

    CAR (Cloud Absorption Radiometer) is a multi-angular and multi-spectral airborne radiometer instrument, whose radiometric and geometric characteristics are well calibrated and adjusted before and after each flight campaign. CAR was built by NASA (National Aeronautics and Space Administration) in 1984. On 16 May 2008, a CAR flight campaign took place over the well-known calibration and validation site of Railroad Valley in Nevada (38.504 deg N, 115.692 deg W).The campaign coincided with the overpasses of several key EO (Earth Observation) satellites such as Landsat-7, Envisat and Terra. Thus, there are nearly simultaneous measurements from these satellites and the CAR airborne sensor over the same calibration site. The CAR spectral bands are close to those of most EO satellites. CAR has the ability to cover the whole range of azimuth view angles and a variety of zenith angles depending on altitude and, as a consequence, the biases seen between satellite and CAR measurements due to both unmatched spectral bands and unmatched angles can be significantly reduced. A comparison is presented here between CARs land surface reflectance (BRF or Bidirectional Reflectance Factor) with those derived from Terra/MODIS (MOD09 and MAIAC), Terra/MISR, Envisat/MERIS and Landsat-7. In this study, we utilized CAR data from low altitude flights (approx. 180 m above the surface) in order to minimize the effects of the atmosphere on these measurements and then obtain a valuable ground-truth data set of surface reflectance. Furthermore, this study shows that differences between measurements caused by surface heterogeneity can be tolerated, thanks to the high homogeneity of the study site on the one hand, and on the other hand, to the spatial sampling and the large number of CAR samples. These results demonstrate that satellite BRF measurements over this site are in good agreement with CAR with variable biases across different spectral bands. This is most likely due to residual aerosol

  13. Highly directive Fabry-Perot leaky-wave nanoantennas based on optical partially reflective surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Lorente-Crespo, M.; Mateo-Segura, C., E-mail: C.Mateo-Segura@hw.ac.uk [Institute of Sensors, Signals and Systems, Heriot-Watt University, EH14 4AS Edinburgh (United Kingdom)

    2015-05-04

    Nanoantennas enhance the conversion between highly localized electromagnetic fields and far-field radiation. Here, we investigate the response of a nano-patch partially reflective surface backed with a silver mirror to an optical source embedded at the centre of the structure. Using full wave simulations, we demonstrate a two orders of magnitude increased directivity compared to the isotropic radiator, 50% power confinement to a 13.8° width beam and a ±16 nm bandwidth. Our antenna does not rely on plasmonic phenomena thus reducing non-radiative losses and conserving source coherence.

  14. Hyperspectral diffuse reflectance for determination of the optical properties of milk and fruit and vegetable juices

    Science.gov (United States)

    Qin, Jianwei; Lu, Renfu

    2005-11-01

    Absorption and reduced scattering coefficients are two fundamental optical properties for turbid biological materials. This paper presents the technique and method of using hyperspectral diffuse reflectance for fast determination of the optical properties of fruit and vegetable juices and milks. A hyperspectral imaging system was used to acquire spatially resolved steady-state diffuse reflectance over the spectral region between 530 and 900 nm from a variety of fruit and vegetable juices (citrus, grapefruit, orange, and vegetable) and milks with different fat levels (full, skim and mixed). The system collected diffuse reflectance in the source-detector separation range from 1.1 to 10.0 mm. The hyperspectral reflectance data were analyzed by using a diffusion theory model for semi-infinite homogeneous media. The absorption and reduced scattering coefficients of the fruit and vegetable juices and milks were extracted by inverse algorithms from the scattering profiles for wavelengths of 530-900 nm. Values of the absorption and reduced scattering coefficient at 650 nm were highly correlated to the fat content of the milk samples with the correlation coefficient of 0.990 and 0.989, respectively. The hyperspectral imaging technique can be extended to the measurement of other liquid and solid foods in which light scattering is dominant.

  15. Development and applications of retro-reflective surfaces for ultrasound in LBE

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2015-07-01

    pulse or a complete absence of a reflection like a shadow. In that way, it suffices to align the sensor with the diaphragm instead of the fuel assembly which is much easier to achieve as the robotics on which the sensor is mounted move parallel with the diaphragm. The alignment requirement in the latter approach can be further relaxed by using a tiling of retro-reflectors on the lower surface of the diaphragm. In that way, alignment becomes less vital and the main source of acoustic energy loss - geometric spread of the beam - is almost completely removed, leaving only absorption losses. In this paper, we present the first results in developing a retro reflectance surface for ultrasound in LBE. We present experimental results for different designs of retro-reflectors in both water and LBE. We discuss both linear and array retro-reflectors of different sizes and investigate the influence of the main relevant ultrasonic parameters such as wavelength and spot size on the strength of the received reflection under different alignment angles. We also demonstrate how retro-reflective surfaces can be exploited when localizing objects using linear and rotating scanning methods. (authors)

  16. Scanning tunnel microscopic image of tungsten (100) and (110) real surfaces and nature of conduction electron reflection

    International Nuclear Information System (INIS)

    Pryadkin, S.L.; Tsoj, V.S.

    1988-01-01

    The electrically polished (100) and (110) surfaces of tungsten are studied with the aid of a scanning tunnel microscope at atmospheric pressure. The (110) surface consists of a large number of atomically plane terraces whereas the (100) surface is faceted. The scanning tunnel microscope data can explain such results of experiments on transverse electron focussing as the strong dependence of the probability for specular reflection of conduction electrons scattered by the (100) surface on the electron de Broglie wavelength and the absence of a dependence of the probability for specular reflection on the wavelength for the (110) surface

  17. Regional-Scale Surface Magnetic Fields and Proton Fluxes to Mercury's Surface from Proton-Reflection Magnetometry

    Science.gov (United States)

    Winslow, R. M.; Johnson, C. L.; Anderson, B. J.; Gershman, D. J.; Raines, J. M.; Lillis, R. J.; Korth, H.; Slavin, J. A.; Solomon, S. C.; Zurbuchen, T.

    2014-12-01

    The application of a recently developed proton-reflection magnetometry technique to MESSENGER spacecraft observations at Mercury has yielded two significant findings. First, loss-cone observations directly confirm particle precipitation to Mercury's surface and indicate that solar wind plasma persistently bombards the planet not only in the magnetic cusp regions but over a large fraction of the southern hemisphere. Second, the inferred surface field strengths independently confirm the north-south asymmetry in Mercury's global magnetic field structure first documented from observations of magnetic equator crossings. Here we extend this work with 1.5 additional years of observations (i.e., to 2.5 years in all) to further probe Mercury's surface magnetic field and better resolve proton flux precipitation to the planet's surface. We map regions where proton loss cones are observed; these maps indicate regions where protons precipitate directly onto the surface. The augmentation of our data set over that used in our original study allows us to examine the proton loss cones in cells of dimension 10° latitude by 20° longitude in Mercury body-fixed coordinates. We observe a transition from double-sided to single-sided loss cones in the pitch-angle distributions; this transition marks the boundary between open and closed field lines. At the surface this boundary lies between 60° and 70°N. Our observations allow the estimation of surface magnetic field strengths in the northern cusp region and the calculation of incident proton fluxes to both hemispheres. In the northern cusp, our regional-scale observations are consistent with an offset dipole field and a dipole moment of 190 nT RM3, where RM is Mercury's radius, implying that any regional-scale variations in surface magnetic field strengths are either weak relative to the dipole field or occur at length scales smaller than the resolution of our observations (~300 km). From the global proton flux map (north of 40° S

  18. Algorithm of extraction optics properties from the measurement of spatially resolved diffuse reflectance

    International Nuclear Information System (INIS)

    Cunill Rodriguez, Margarita; Delgado Atencio, Jose Alberto; Castro Ramos, Jorge; Vazquez y Montiel, Sergio

    2009-01-01

    There are several methods to obtain the optical parameters of biological tissues from the measurement of spatially resolved diffuse reflectance. One of them is well-known as Video Reflectometry in which a camera CCD is used as detection and recording system of the lateral distribution of diffuse reflectance Rd(r) when an infinitely narrow light beam impinges on the tissue. In this paper, we present an algorithm that we have developed for the calibration and application of an experimental set-up of Video Reflectometry destined to extract the optical properties of models of biological tissues with optical properties similar to the human skin. The results of evaluation of the accuracy of the algorithm for optical parameters extraction is shown for a set of proofs reflectance curves with known values of these parameters. In the generation of these curves the simulation of measurement errors was also considered. The results show that it is possible to extract the optical properties with an accuracy error of less than 1% for all the proofs curves. (Author)

  19. Portable, Fiber-Based, Diffuse Reflection Spectroscopy (DRS) Systems for Estimating Tissue Optical Properties.

    Science.gov (United States)

    Vishwanath, Karthik; Chang, Kevin; Klein, Daniel; Deng, Yu Feng; Chang, Vivide; Phelps, Janelle E; Ramanujam, Nimmi

    2011-02-01

    Steady-state diffuse reflection spectroscopy is a well-studied optical technique that can provide a noninvasive and quantitative method for characterizing the absorption and scattering properties of biological tissues. Here, we compare three fiber-based diffuse reflection spectroscopy systems that were assembled to create a light-weight, portable, and robust optical spectrometer that could be easily translated for repeated and reliable use in mobile settings. The three systems were built using a broadband light source and a compact, commercially available spectrograph. We tested two different light sources and two spectrographs (manufactured by two different vendors). The assembled systems were characterized by their signal-to-noise ratios, the source-intensity drifts, and detector linearity. We quantified the performance of these instruments in extracting optical properties from diffuse reflectance spectra in tissue-mimicking liquid phantoms with well-controlled optical absorption and scattering coefficients. We show that all assembled systems were able to extract the optical absorption and scattering properties with errors less than 10%, while providing greater than ten-fold decrease in footprint and cost (relative to a previously well-characterized and widely used commercial system). Finally, we demonstrate the use of these small systems to measure optical biomarkers in vivo in a small-animal model cancer therapy study. We show that optical measurements from the simple portable system provide estimates of tumor oxygen saturation similar to those detected using the commercial system in murine tumor models of head and neck cancer.

  20. Using surfaces, ligands, and dimensionality to obtain desired nanostructure properties

    Science.gov (United States)

    Nagpal, Prashant; Singh, Vivek; Ding, Yuchen

    2014-03-01

    Nanostructured materials are intensively investigated to obtain material properties different from their bulk counterparts. It has been demonstrated that nanoscaled semiconductor can have interesting size, shape and morphology dependent optoelectronic properties. But the effect of surfaces, ligands and dimensionality (0D quantum dots to 2D nanosheets) has been largely unexplored. Here, we will show how tuning the surface and dimensionality can affect the electronic states of the semiconductor, and how these states can play an important role in their fundamental photophysical properties or thermal transport. Using the specific case for silicon, we will show how ``new'' surface states in small uniform can lead to light absorption/emission without phonon assistance, while hindering the phonon-drag of charge carriers leading to low Seebeck coefficient for thermoelectric applications. These measurements will shed light on designing appropriate surface, size, and dimensionality for desired applications of nanostructured films.

  1. Oleophobic properties of the step-and-terrace sapphire surface

    Energy Technology Data Exchange (ETDEWEB)

    Muslimov, A. E., E-mail: amuslimov@mail.ru; Butashin, A. V.; Kanevsky, V. M. [Russian Academy of Sciences, Shubnikov Institute of Crystallography, Federal Research Center “Crystallography and Photonics” (Russian Federation)

    2017-03-15

    Sapphire is widely used in production of optical windows for various devices due to its mechanical and optical properties. However, during operation the surface can be affected by fats, oils, and other organic contaminations. Therefore, it is important to improve the oleophobic properties of sapphire windows. In this study, we investigate the interaction of a supersmooth sapphire surface with oleic acid droplets, which imitate human finger printing. It is established that chemical–mechanical polishing with additional annealing in air, which leads to the formation of an atomically smooth sapphire surface, makes it possible to significantly improve the oleophobic properties of the surface. The results are analyzed using the Ventsel–Deryagin homogeneous wetting model.

  2. Barium fluoride surface preparation, analysis and UV reflective coatings at Lawrence Livermore National Laboratory

    International Nuclear Information System (INIS)

    Wuest, C.R.

    1992-01-01

    Lawrence Livermore National Laboratory (LLNL) has begun a program of study on barium fluoride scintillating crystals for the Barium Fluoride Electromagnetic Calorimeter Collaboration. This program has resulted in a number of significant improvements in the mechanical processing, polishing and coating of barium fluoride crystals. Techniques have been developed using diamond-loaded pitch lapping that can produce 15 angstrom RMS surface finishes over large areas. These lapped surfaces have been shown to be crystalline using Rutherford Back-scattering (RBS). Also, special polishing fixtures have been designed based on mounting technology developed for the 1.1 m diameter optics used in LLNL's Nova Laser. These fixtures allow as many as five 25--50 cm long barium fluoride crystals to be polished and lapped at a time with the necessary tolerances for the 16,000 crystal Barium Fluoride Calorimeter. In addition, results will be presented on coating barium fluoride with UV reflective layers of magnesium fluoride and aluminum

  3. Modified polarimetric bidirectional reflectance distribution function with diffuse scattering: surface parameter estimation

    Science.gov (United States)

    Zhan, Hanyu; Voelz, David G.

    2016-12-01

    The polarimetric bidirectional reflectance distribution function (pBRDF) describes the relationships between incident and scattered Stokes parameters, but the familiar surface-only microfacet pBRDF cannot capture diffuse scattering contributions and depolarization phenomena. We propose a modified pBRDF model with a diffuse scattering component developed from the Kubelka-Munk and Le Hors et al. theories, and apply it in the development of a method to jointly estimate refractive index, slope variance, and diffuse scattering parameters from a series of Stokes parameter measurements of a surface. An application of the model and estimation approach to experimental data published by Priest and Meier shows improved correspondence with measurements of normalized Mueller matrix elements. By converting the Stokes/Mueller calculus formulation of the model to a degree of polarization (DOP) description, the estimation results of the parameters from measured DOP values are found to be consistent with a previous DOP model and results.

  4. Generating Land Surface Reflectance for the New Generation of Geostationary Satellite Sensors with the MAIAC Algorithm

    Science.gov (United States)

    Wang, W.; Wang, Y.; Hashimoto, H.; Li, S.; Takenaka, H.; Higuchi, A.; Lyapustin, A.; Nemani, R. R.

    2017-12-01

    The latest generation of geostationary satellite sensors, including the GOES-16/ABI and the Himawari 8/AHI, provide exciting capability to monitor land surface at very high temporal resolutions (5-15 minute intervals) and with spatial and spectral characteristics that mimic the Earth Observing System flagship MODIS. However, geostationary data feature changing sun angles at constant view geometry, which is almost reciprocal to sun-synchronous observations. Such a challenge needs to be carefully addressed before one can exploit the full potential of the new sources of data. Here we take on this challenge with Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm, recently developed for accurate and globally robust applications like the MODIS Collection 6 re-processing. MAIAC first grids the top-of-atmosphere measurements to a fixed grid so that the spectral and physical signatures of each grid cell are stacked ("remembered") over time and used to dramatically improve cloud/shadow/snow detection, which is by far the dominant error source in the remote sensing. It also exploits the changing sun-view geometry of the geostationary sensor to characterize surface BRDF with augmented angular resolution for accurate aerosol retrievals and atmospheric correction. The high temporal resolutions of the geostationary data indeed make the BRDF retrieval much simpler and more robust as compared with sun-synchronous sensors such as MODIS. As a prototype test for the geostationary-data processing pipeline on NASA Earth Exchange (GEONEX), we apply MAIAC to process 18 months of data from Himawari 8/AHI over Australia. We generate a suite of test results, including the input TOA reflectance and the output cloud mask, aerosol optical depth (AOD), and the atmospherically-corrected surface reflectance for a variety of geographic locations, terrain, and land cover types. Comparison with MODIS data indicates a general agreement between the retrieved surface reflectance

  5. Plasmonic properties of gold nanoparticles on silicon substrates: Understanding Fano-like spectra observed in reflection

    Science.gov (United States)

    Bossard-Giannesini, Léo; Cruguel, Hervé; Lacaze, Emmanuelle; Pluchery, Olivier

    2016-09-01

    Gold nanoparticles (AuNPs) are known for their localized surface plasmon resonance (LSPR) that can be measured with UV-visible spectroscopy. AuNPs are often deposited on silicon substrates for various applications, and the LSPR is measured in reflection. In this case, optical spectra are measured by surface differential reflectance spectroscopy (SDRS) and the absorbance exhibits a negative peak. This article studies both experimentally and theoretically on the single layers of 16 nm diameter spherical gold nanoparticles (AuNPs) grafted on silicon. The morphology and surface density of AuNPs were investigated by atomic force microscopy (AFM). The plasmon response in transmission on the glass substrate and in reflection on the silicon substrate is described by an analytical model based on the Fresnel equations and the Maxwell-Garnett effective medium theory (FMG). The FMG model shows a strong dependence to the incidence angle of the light. At low incident angles, the peak appears negatively with a shallow intensity, and at angles above 30°, the usual positive shape of the plasmon is retrieved. The relevance of the FMG model is compared to the Mie theory within the dipolar approximation. We conclude that no Fano effect is responsible for this derivative shape. An easy-to-use formula is derived that agrees with our experimental data.

  6. Analysing the impact of reflectance distributions and well geometries on vertical surface daylight levels in atria for overcast skies

    Energy Technology Data Exchange (ETDEWEB)

    Du, Jiangtao; Sharples, Steve [School of Architecture, University of Sheffield, Crookesmoor Building, Conduit Road, Sheffield S10 1FL (United Kingdom)

    2010-07-15

    This study investigated the impacts of different diffuse reflectance distributions and well geometries on vertical daylight factors and vertical internally reflected components in atria. Two forms of reflectance distribution patterns of wall surface were examined: horizontal and vertical reflectance band variation. The square atrium models studied have a broader WI range of 0.25-2.0, which represent shallow, medium and high atria. Radiance, a powerful package based on backward ray tracing technique, was used for the simulations of vertical daylight levels. The results show that different reflectance distributions of square atrium walls do have an impact on the vertical daylight factors and vertical internally reflected components under overcast sky condition. The impact relates to the orientation of the band with different reflectance distributions on the wall. Compared with the vertical band surface, the horizontal band surface has a much more complicated effect. The horizontal distributions of the reflectances significantly affects the vertical daylight levels at the locations more than 30% atrium height on the wall. For an atrium with a height more than 1/2 the width, the effect tends to increase with the increasing well index. The vertical distributions of the reflectance, nevertheless, do not substantially take effect on the vertical daylight levels in atria except for some special reflectance distribution patterns. (author)

  7. Seismic reflection imaging, accounting for primary and multiple reflections

    Science.gov (United States)

    Wapenaar, Kees; van der Neut, Joost; Thorbecke, Jan; Broggini, Filippo; Slob, Evert; Snieder, Roel

    2015-04-01

    Imaging of seismic reflection data is usually based on the assumption that the seismic response consists of primary reflections only. Multiple reflections, i.e. waves that have reflected more than once, are treated as primaries and are imaged at wrong positions. There are two classes of multiple reflections, which we will call surface-related multiples and internal multiples. Surface-related multiples are those multiples that contain at least one reflection at the earth's surface, whereas internal multiples consist of waves that have reflected only at subsurface interfaces. Surface-related multiples are the strongest, but also relatively easy to deal with because the reflecting boundary (the earth's surface) is known. Internal multiples constitute a much more difficult problem for seismic imaging, because the positions and properties of the reflecting interfaces are not known. We are developing reflection imaging methodology which deals with internal multiples. Starting with the Marchenko equation for 1D inverse scattering problems, we derived 3D Marchenko-type equations, which relate reflection data at the surface to Green's functions between virtual sources anywhere in the subsurface and receivers at the surface. Based on these equations, we derived an iterative scheme by which these Green's functions can be retrieved from the reflection data at the surface. This iterative scheme requires an estimate of the direct wave of the Green's functions in a background medium. Note that this is precisely the same information that is also required by standard reflection imaging schemes. However, unlike in standard imaging, our iterative Marchenko scheme retrieves the multiple reflections of the Green's functions from the reflection data at the surface. For this, no knowledge of the positions and properties of the reflecting interfaces is required. Once the full Green's functions are retrieved, reflection imaging can be carried out by which the primaries and multiples are

  8. Anti-reflection textured structures by wet etching and island lithography for surface-enhanced Raman spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Chao, Bo-Kai [Department of Materials Science and Engineering, National Taiwan University, Taipei 10617, Taiwan (China); Cheng, Hsin-Hung [Department of Marine Engineering, Taipei College of Maritime Technology, Taipei 11174, Taiwan (China); Nien, Li-Wei; Chen, Miin-Jang [Department of Materials Science and Engineering, National Taiwan University, Taipei 10617, Taiwan (China); Nagao, Tadaaki [Center for Materials Nanoarchitectonics, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Li, Jia-Han [Department of Engineering Science and Ocean Engineering, National Taiwan University, Taipei 10617, Taiwan (China); Hsueh, Chun-Hway, E-mail: hsuehc@ntu.edu.tw [Department of Materials Science and Engineering, National Taiwan University, Taipei 10617, Taiwan (China)

    2015-12-01

    Graphical abstract: - Highlights: • We fabricated textured SERS substrate with a high surface area and low reflectance. • Large surface area of substrate contains more gold nanodroplets to absorb analytes. • Low reflectance of textured SERS substrate enabled multiple reflections of incident laser light. • We obtained strong SERS enhancement from nanopillar-on-pyramid SERS substrate. - Abstract: A high surface area and low reflection textured surface-enhanced Raman scattering (SERS) substrate with plasmonic gold nanodroplets fabricated by wet etching and island lithography was reported in the present study. Specifically, four textured substrates, planar, pyramid, nanopillar, and nanopillar-on-pyramid, were fabricated. The fabricated structures were simulated using the finite-difference time-domain method and the results agreed with the reflection and dark-field scattering measurements. Although the SERS signals varied in different measured regions because of the random nanostructure, the SERS substrates with nanopillar-on-pyramid structure always have the stronger enhancement factor than the SERS substrates with only pyramids or nanopillars. Based on the atomic force microscope and reflection measurements, the nanopillar-on-pyramid structure provided a large surface area and multiple reflections for SERS enhancement, which was about 3 orders of magnitude larger than that of the planar substrate. Our results can be applied to fabricate the inexpensive, large surface area, and high SERS enhancement substrates.

  9. Estimation of Melt Ponds over Arctic Sea Ice using MODIS Surface Reflectance Data

    Science.gov (United States)

    Ding, Y.; Cheng, X.; Liu, J.

    2017-12-01

    Melt ponds over Arctic sea ice is one of the main factors affecting variability of surface albedo, increasing absorption of solar radiation and further melting of snow and ice. In recent years, a large number of melt ponds have been observed during the melt season in Arctic. Moreover, some studies have suggested that late spring to mid summer melt ponds information promises to improve the prediction skill of seasonal Arctic sea ice minimum. In the study, we extract the melt pond fraction over Arctic sea ice since 2000 using three bands MODIS weekly surface reflectance data by considering the difference of spectral reflectance in ponds, ice and open water. The preliminary comparison shows our derived Arctic-wide melt ponds are in good agreement with that derived by the University of Hamburg, especially at the pond distribution. We analyze seasonal evolution, interannual variability and trend of the melt ponds, as well as the changes of onset and re-freezing. The melt pond fraction shows an asymmetrical growth and decay pattern. The observed melt ponds fraction is almost within 25% in early May and increases rapidly in June and July with a high fraction of more than 40% in the east of Greenland and Beaufort Sea. A significant increasing trend in the melt pond fraction is observed for the period of 2000-2017. The relationship between melt pond fraction and sea ice extent will be also discussed. Key Words: melt ponds, sea ice, Arctic

  10. Collection and corrections of oblique multiangle hyperspectral bidirectional reflectance imagery of the water surface

    Science.gov (United States)

    Bostater, Charles R.; Oney, Taylor S.

    2017-10-01

    Hyperspectral images of coastal waters in urbanized regions were collected from fixed platform locations. Surf zone imagery, images of shallow bays, lagoons and coastal waters are processed to produce bidirectional reflectance factor (BRF) signatures corrected for changing viewing angles. Angular changes as a function of pixel location within a scene are used to estimate changes in pixel size and ground sampling areas. Diffuse calibration targets collected simultaneously from within the image scene provides the necessary information for calculating BRF signatures of the water surface and shorelines. Automated scanning using a pushbroom hyperspectral sensor allows imagery to be collected on the order of one minute or less for different regions of interest. Imagery is then rectified and georeferenced using ground control points within nadir viewing multispectral imagery via image to image registration techniques. This paper demonstrates the above as well as presenting how spectra can be extracted along different directions in the imagery. The extraction of BRF spectra along track lines allows the application of derivative reflectance spectroscopy for estimating chlorophyll-a, dissolved organic matter and suspended matter concentrations at or near the water surface. Imagery is presented demonstrating the techniques to identify subsurface features and targets within the littoral and surf zones.

  11. Airborne hyperspectral observations of surface and cloud directional reflectivity using a commercial digital camera

    Directory of Open Access Journals (Sweden)

    A. Ehrlich

    2012-04-01

    Full Text Available Spectral radiance measurements by a digital single-lens reflex camera were used to derive the directional reflectivity of clouds and different surfaces in the Arctic. The camera has been calibrated radiometrically and spectrally to provide accurate radiance measurements with high angular resolution. A comparison with spectral radiance measurements with the Spectral Modular Airborne Radiation measurement sysTem (SMART-Albedometer showed an agreement within the uncertainties of both instruments (6% for both. The directional reflectivity in terms of the hemispherical directional reflectance factor (HDRF was obtained for sea ice, ice-free ocean and clouds. The sea ice, with an albedo of ρ = 0.96 (at 530 nm wavelength, showed an almost isotropic HDRF, while sun glint was observed for the ocean HDRF (ρ = 0.12. For the cloud observations with ρ = 0.62, the cloudbow – a backscatter feature typically for scattering by liquid water droplets – was covered by the camera. For measurements above heterogeneous stratocumulus clouds, the required number of images to obtain a mean HDRF that clearly exhibits the cloudbow has been estimated at about 50 images (10 min flight time. A representation of the HDRF as a function of the scattering angle only reduces the image number to about 10 (2 min flight time.

    The measured cloud and ocean HDRF have been compared to radiative transfer simulations. The ocean HDRF simulated with the observed surface wind speed of 9 m s−1 agreed best with the measurements. For the cloud HDRF, the best agreement was obtained by a broad and weak cloudbow simulated with a cloud droplet effective radius of Reff = 4 μm. This value agrees with the particle sizes derived from in situ measurements and retrieved from the spectral radiance of the SMART-Albedometer.

  12. Reconciling Electrical Properties of Titan's Surface Derived from Cassini RADAR Scatterometer and Radiometer Measurements

    Science.gov (United States)

    Zebker, H. A.; Wye, L. C.; Janssen, M.; Paganelli, F.; Cassini RADAR Team

    2006-12-01

    We observe Titan, Saturn's largest moon, using active and passive microwave instruments carried on board the Cassini spacecraft. The 2.2-cm wavelength penetrates the thick atmosphere and provides surface measurements at resolutions from 10-200 km over much of the satellite's surface. The emissivity and reflectivity of surface features are generally anticorrelated, and both values are fairly high. Inversion of either set of data alone yields dielectric constants ranging from 1.5 to 3 or 4, consistent with an icy hydrocarbon or water ice composition. However, the dielectric constants retrieved from radiometric data alone are usually less than those inferred from backscatter measurements, a discrepancy consistent with similar analyses dating back to lunar observations in the 1960's. Here we seek to reconcile Titan's reflectivity and emissivity observations using a single physical model of the surface. Our approach is to calculate the energy scattered by Titan's surface and near subsurface, with the remainder absorbed. In equilibrium the absorption equals the emission, so that both the reflectivity and emissivity are described by the model. We use a form of the Kirchhoff model for modeling surface scatter, and a model based on weak localization of light for the volume scatter. With this model we present dielectric constant and surface roughness parameters that match both sets of Cassini RADAR observations over limited regions on Titan's surface, helping to constrain the composition and roughness of the surface. Most regions display electrical properties consistent with solid surfaces, however some of the darker "lake-like" features at higher latitudes can be modeled as either solid or liquid materials. The ambiguity arises from the limited set of observational angles available.

  13. ChemCam passive reflectance spectroscopy of surface materials at the Curiosity landing site, Mars

    Science.gov (United States)

    Johnson, Jeffrey R.; Bell, J. F.; Bender, S.; Blaney, D.; Cloutis, E.; DeFlores, L.; Ehlmann, B.; Gasnault, O.; Gondet, B.; Kinch, K.; Lemmon, M.; Le Mouélic, S.; Maurice, S.; Rice, M.; Wiens, R. C.

    2015-03-01

    The spectrometers on the Mars Science Laboratory (MSL) ChemCam instrument were used in passive mode to record visible/near-infrared (400-840 nm) radiance from the martian surface. Using the onboard ChemCam calibration targets' housing as a reflectance standard, we developed methods to collect, calibrate, and reduce radiance observations to relative reflectance. Such measurements accurately reproduce the known reflectance spectra of other calibration targets on the rover, and represent the highest spatial resolution (0.65 mrad) and spectral sampling (rocks and soils match those from orbital observations and multispectral data from the MSL Mastcam camera. Preliminary analyses of the band depths, spectral slopes, and reflectance ratios of the more than 2000 spectra taken during the first year of MSL operations demonstrate at least six spectral classes of materials distinguished by variations in ferrous and ferric components. Initial comparisons of ChemCam spectra to laboratory spectra of minerals and Mars analog materials demonstrate similarities with palagonitic soils and indications of orthopyroxene in some dark rocks. Magnesium-rich "raised ridges" tend to exhibit distinct near-infrared slopes. The ferric absorption downturn typically found for martian materials at rocks and drill tailings, consistent with their more ferrous nature. Calcium-sulfate veins exhibit the highest relative reflectances observed, but are still relatively red owing to the effects of residual dust. Such dust is overall less prominent on rocks sampled within the "blast zone" immediately surrounding the landing site. These samples were likely affected by the landing thrusters, which partially removed the ubiquitous dust coatings. Increased dust coatings on the calibration targets during the first year of the mission were documented by the ChemCam passive measurements as well. Ongoing efforts to model and correct for this dust component should improve calibration of the relative reflectance

  14. Plasma treatment of porous GaAs surface formed by electrochemical etching method: Characterization and properties

    International Nuclear Information System (INIS)

    Saloum, S.; Naddaf, M.

    2010-01-01

    Porous GaAs samples were formed by electrochemical anodic etching of Zn doped p-type GaAs (100) wafers at different etching parameters (time, mode of applied voltage or current and electrolyte). The effect of etching parameters and plasma surface treatment on the optical properties of the prepared sample has been investigated by using room temperature photoluminescence (PL), Raman spectroscopy and reflectance spectroscopic measurements in the range (400-800 nm). The surface morphological changes were studied by using atomic force microscope. (author)

  15. OMI/Aura Surface Reflectance Climatology Level 3 Global 0.5deg Lat/Lon Grid V003

    Data.gov (United States)

    National Aeronautics and Space Administration — The OMI Earth Surface Reflectance Climatology product, OMLER (Global 0.5deg Lat/Lon grid) which is based on Version 003 Level-1B top of atmosphere upwelling radiance...

  16. Spectral and physical properties of metal in meteorite assemblages - implications of asteroid surface materials

    International Nuclear Information System (INIS)

    Gaffey, M.J.

    1986-01-01

    One of the objectives of the present paper is related to a definition of the spectral contribution of the nickel-iron metal component in meteoritic assemblages. Another objective is the elucidation of the chemical, physical, and petrographic properties of the metal grains which affect the spectral signature in asteroid surface materials. It is pointed out that an improved understanding of the spectral and physical properties of metal in asteroid regoliths should permit an improved characterization of these objects, and, in particular, a better evaluation of the differentiated or undifferentiated nature of the S-type and M-type asteroids. Attention is given to the spectra of iron and nickel-iron metals, the spectral effects of metal in chondritic assemblages, the spectral reflectance of metal grains in ordinary chondrites, the nature of the surfaces of chondritic metal grains, the origin of coats on chondritic metal grains, and the fragmentation of metal on asteroid surfaces. 57 references

  17. Plasma surface reflectance spectroscopy for non-invasive and continuous monitoring of extracellular component of blood

    Science.gov (United States)

    Sakota, Daisuke; Takatani, Setsuo

    2012-04-01

    To achieve the quantitative optical non-invasive diagnosis of blood during extracorporeal circulation therapies, the instrumental technique to extract extracellular spectra from whole blood was developed. In the circuit, the continuous blood flow was generated by a centrifugal blood pump. The oxygen saturation was maintained 100% by an oxygenator. The developed glass optical flow cell was attached to the outlet tubing of the oxygenator. The halogen lamp including the light from 400 to 900 nm wavelength was used for the light source. The light was guided into an optical fiber. The light emitted by the fiber was collimated and emitted to the flow cell flat surface at the incident angle of 45 degrees. The light just reflected on the boundary between inner surface of the flow cell and plasma at 45 degrees was detected by the detection fiber. The detected light was analyzed by a spectral photometer. The obtained spectrum from 400 to 600nm wavelength was not changed with respect to the hematocrit. In contrast, the signal in the spectral range was changed when the plasma free hemoglobin increased. By using two spectral range, 505+/-5 nm and 542.5+/-2.5 nm, the differential spectrum was correlated with the free hemoglobin at R2=0.99. On the other hand, as for the hematocrit, the differential spectrum was not correlated at R2=0.01. Finally, the plasma free hemoglobin was quantified with the accuracy of 22+/-19mg/dL. The result shows that the developed plasma surface reflectance spectroscopy (PSRS) can extract the plasma spectrum from flowing whole blood.

  18. A prototype for automation of land-cover products from Landsat Surface Reflectance Data Records

    Science.gov (United States)

    Rover, J.; Goldhaber, M. B.; Steinwand, D.; Nelson, K.; Coan, M.; Wylie, B. K.; Dahal, D.; Wika, S.; Quenzer, R.

    2014-12-01

    Landsat data records of surface reflectance provide a three-decade history of land surface processes. Due to the vast number of these archived records, development of innovative approaches for automated data mining and information retrieval were necessary. Recently, we created a prototype utilizing open source software libraries for automatically generating annual Anderson Level 1 land cover maps and information products from data acquired by the Landsat Mission for the years 1984 to 2013. The automated prototype was applied to two target areas in northwestern and east-central North Dakota, USA. The approach required the National Land Cover Database (NLCD) and two user-input target acquisition year-days. The Landsat archive was mined for scenes acquired within a 100-day window surrounding these target dates, and then cloud-free pixels where chosen closest to the specified target acquisition dates. The selected pixels were then composited before completing an unsupervised classification using the NLCD. Pixels unchanged in pairs of the NLCD were used for training decision tree models in an iterative process refined with model confidence measures. The decision tree models were applied to the Landsat composites to generate a yearly land cover map and related information products. Results for the target areas captured changes associated with the recent expansion of oil shale production and agriculture driven by economics and policy, such as the increase in biofuel production and reduction in Conservation Reserve Program. Changes in agriculture, grasslands, and surface water reflect the local hydrological conditions that occurred during the 29-year span. Future enhancements considered for this prototype include a web-based client, ancillary spatial datasets, trends and clustering algorithms, and the forecasting of future land cover.

  19. Surface properties of activated carbon treated by cold plasma heating

    Energy Technology Data Exchange (ETDEWEB)

    Norikazu, Kurano [Shigematsu works Co. Ltd., 267 Yashita, Iwatsuki 3390046 (Japan); Yamada, Hiroshi [Shigematsu works Co. Ltd., 267 Yashita, Iwatsuki 3390046 (Japan); Yajima, Tatsuhiko [Faculty of Engineering, Saitama Institute of Technology, 1690 Fusoiji, Okabe 3690293 (Japan); Sugiyama, Kazuo [Faculty of Engineering, Saitama University, 255 Shimo-okubo, Sakura-Ku, Saitama 3388570 (Japan)]. E-mail: sugi@apc.saitama-u.ac.jp

    2007-03-12

    To modify the surface properties of activated carbon powders, we have applied the cold plasma treatment method. The cold plasma was used to be generated in the evacuated reactor vessel by 2.45 GHz microwave irradiation. In this paper, changes of surface properties such as distribution of acidic functional groups and roughness morphology were examined. By the cold plasma treatment, activated carbons with large specific surface area of ca. 2000 m{sup 2}/g or more could be prepared in a minute. The amount of every gaseous organic compound adsorbed on the unit gram of treated activated carbons was more increased that on the unit gram of untreated carbons. Especially, the adsorbed amount of carbon disulfide was remarkably increased even if it was compared by the amount per unit surface area. These results suggest that the surface property of the sample was modified by the plasma treatment. It became apparent by observing SEM photographs that dust and impure particles in macropores of activated carbons were far more reduced by the plasma treatment than by the conventional heating in an electric furnace under vacuum. In addition, a bubble-like surface morphology of the sample was observed by AEM measurement. The amount of acidic functional groups at the surface was determined by using the Boehm's titration method. Consequently, the increase of lactone groups and the decrease of carboxyl groups were also observed.

  20. Modification of Textile Materials' Surface Properties Using Chemical Softener

    Directory of Open Access Journals (Sweden)

    Jurgita KOŽENIAUSKIENĖ

    2011-03-01

    Full Text Available In the present study the effect of technological treatment involving the processes of washing or washing and softening with chemical cationic softener "Surcase" produced in Great Britain on the surface properties of cellulosic textile materials manufactured from cotton, bamboo and viscose spun yarns was investigated. The changes in textile materials surface properties were evaluated using KTU-Griff-Tester device and FEI Quanta 200 FEG scanning electron microscope (SEM. It was observed that the worst hand properties and the higher surface roughness are observed of cotton materials if compared with those of bamboo and viscose materials. Also, it was shown that depending on the material structure the handle parameters of knitted materials are the better than the ones of woven fabrics.http://dx.doi.org/10.5755/j01.ms.17.1.249

  1. Investigation of the surface adsorption and biotribological properties of mucins

    DEFF Research Database (Denmark)

    Madsen, Jan Busk

    to a surface. However, in other instances the inverse properties are desirable. Mucins are found on epithelial surfaces throughout the body and are a key component of the mucus barrier. Here, they facilitate friction reduction, thus lowering the impact of physical abrasions, but they also act as a physical...... charge due to the oligosaccharides being capped by negatively charged species such as sialic acid or sulphate groups. Mucins display phenotypic diversion according to their expression site. This is most pronounced in the oligosaccharide composition of the central domains. The amphiphilic nature of mucins...... and their aqueous lubrication properties have led to them being proposed as possible biocompatible lubricants. In this thesis, we investigate the biotribological properties of two commercially available mucins on the soft, elastomeric and hydrophobic surface of PDMS under different conditions. Due to the presence...

  2. Effective modification of particle surface properties using ultrasonic water mist

    DEFF Research Database (Denmark)

    Genina, Natalja; Räikkönen, Heikki; Heinämäki, Jyrki

    2009-01-01

    The goal of the present study was to design a new technique to modify particle surface properties and, through that, to improve flowability of poorly flowing drug thiamine hydrochloride and pharmaceutical sugar lactose monohydrate of two different grades. The powdered particles were supplied...... properties. It was found that rapid exposition of pharmaceutical materials by water mist resulted in the improvement of powder technical properties. The evident changes in flowability of coarser lactose were obviously due to smoothing of particle surface and decreasing in the level of fines with very slight...... increment in particle size. The changes in thiamine powder flow were mainly due to narrowing in particle size distribution where the tendency for better flow of finer lactose was related to surface and size modifications. The aqueous mist application did not cause any alteration of the crystal structures...

  3. Determination of Surface Properties of Liquid Transition Metals

    International Nuclear Information System (INIS)

    Korkmaz, S. D.

    2008-01-01

    Certain surface properties of liquid simple metals are reported. Using the expression derived by Gosh and coworkers we investigated the surface entropy of liquid transition metals namely Fe, Co and Ni. We have also computed surface tensions of the metals concerned. The pair distribution functions are calculated from the solution of Ornstein-Zernike integral equation with Rogers-Young closure using the individual version of the electron-ion potential proposed by Fioalhais and coworkers which was originally developed for solid state. The predicted values of surface tension and surface entropy are in very good agreement with available experimental data. The present study results show that the expression derived by Gosh and coworkers is very useful for the surface entropy by using Fioalhais pseudopotential and Rogers-Young closure

  4. VNIR Reflectance and MIR Emissivity Spectra of Ordinary Chondrite Meteorites Under Simulated Asteroid Surface Conditions

    Science.gov (United States)

    Gemma, M.; Shirley, K.; Glotch, T. D.; Ebel, D. S. S.

    2017-12-01

    Recent missions have revealed much about the nature of many Near-Earth asteroids, including the NEAR-Shoemaker target 433 Eros and Hayabusa target 25142 Itokawa. Both asteroids appear to have mineralogy consistent with ordinary chondrite meteorites. Laboratory spectral analysis of well-constrained meteorite samples can be employed as a reference tool to characterize and constrain data from current and future asteroid studies. A sample set of ordinary chondrite meteorites was chosen from the collection at the American Museum of Natural History. Six meteorites, spanning groups H, L, and LL, were prepared at four different size fractions (25-63 μm, 63-90 μm, 90-125 μm, 125-250 μm) in an attempt to mimic regolith known to exist on asteroids such as 433 Eros and 25142 Itokawa. At the Center for Planetary Exploration at Stony Brook University, spectra of the ordinary chondrite material were measured under simulated asteroid surface conditions ( 10-6 mbar, 150 K chamber temperature, low intensity illumination). The samples were used in two experiments: one measuring visible and near-infrared (VNIR) reflectance spectra at a series of temperatures, and the other measuring mid-infrared (MIR) emissivity spectra. The emissivity measurements require accurate simulation of the thermal environment within asteroid regolith, achieved by inducing a thermal gradient within the sample that results in a surface brightness temperature around 323 K (similar to the surface of 25142 Itokawa). Mid-IR emissivity spectra were collected for each sample at a surface temperature of 323 K, and reflectance spectra were collected in increments of 10 K, over the range 283 K to 373 K. Preliminary VNIR spectra show spreads similar to those seen in Hinrichs and Lucey (2002). Preliminary MIR emissivity spectra suggest that under asteroid surface conditions, the position of the Christiansen feature shifts to shorter wavelengths and emissivity is lower in the Reststrahlen bands when compared to

  5. Different size biomolecules anchoring on porous silicon surface: fluorescence and reflectivity pores infiltration comparative studies

    Energy Technology Data Exchange (ETDEWEB)

    Giovannozzi, Andrea M.; Rossi, Andrea M. [National Institute for Metrological Research, Thermodynamic Division, Strada delle Cacce 91, 10135 Torino (Italy); Renacco, Chiara; Farano, Alessandro [Ribes Ricecrhe Srl, Via Lavoratori Vittime del Col du Mont 24, 11100 Aosta (Italy); Derosas, Manuela [Biodiversity Srl, Via Corfu 71, 25124 Brescia (Italy); Enrico, Emanuele [National Institute for Metrological Research, Electromagnetism Division, Strada delle Cacce 91, 10135 Torino (Italy)

    2011-06-15

    The performance of porous silicon optical based biosensors strongly depends on material nanomorphology, on biomolecules distribution inside the pores and on the ability to link sensing species to the pore walls. In this paper we studied the immobilization of biomolecules with different size, such as antibody anti aflatoxin (anti Aflatox Ab, {proportional_to}150 KDa), malate dehydrogenase (MDH, {proportional_to}36KDa) and metallothionein (MT, {proportional_to}6KDa) at different concentrations on mesoporous silicon samples ({proportional_to}15 nm pores diameter). Fluorescence measurements using FITC- labeled biomolecules and refractive index analysis based on reflectivity spectra have been employed together to detect the amount of proteins bound to the surface and to evaluate their diffusion inside the pores. Here we suggest that these two techniques should be used together to have a better understanding of what happens at the porous silicon surface. In fact, when pores dimensions are not perfectly tuned to the protein size a higher fluorescence signal doesn't often correspond to a higher biomolecules distribution inside the pores. When a too much higher concentration of biomolecule is anchored on the surface, steric crowd effects and repulsive interactions probably take over and hinder pores infiltration, inducing a small or absent shift in the fringe pattern even if a higher fluorescence signal is registered. (copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  6. Virtual-stereo fringe reflection technique for specular free-form surface testing

    Science.gov (United States)

    Ma, Suodong; Li, Bo

    2016-11-01

    Due to their excellent ability to improve the performance of optical systems, free-form optics have attracted extensive interest in many fields, e.g. optical design of astronomical telescopes, laser beam expanders, spectral imagers, etc. However, compared with traditional simple ones, testing for such kind of optics is usually more complex and difficult which has been being a big barrier for the manufacture and the application of these optics. Fortunately, owing to the rapid development of electronic devices and computer vision technology, fringe reflection technique (FRT) with advantages of simple system structure, high measurement accuracy and large dynamic range is becoming a powerful tool for specular free-form surface testing. In order to obtain absolute surface shape distributions of test objects, two or more cameras are often required in the conventional FRT which makes the system structure more complex and the measurement cost much higher. Furthermore, high precision synchronization between each camera is also a troublesome issue. To overcome the aforementioned drawback, a virtual-stereo FRT for specular free-form surface testing is put forward in this paper. It is able to achieve absolute profiles with the help of only one single biprism and a camera meanwhile avoiding the problems of stereo FRT based on binocular or multi-ocular cameras. Preliminary experimental results demonstrate the feasibility of the proposed technique.

  7. Surface energy loss processes in XPS studied by absolute reflection electron energy loss spectroscopy

    International Nuclear Information System (INIS)

    Nagatomi, T.; Goto, K.

    2010-01-01

    The results of the investigation of the inelastic interaction of 300-3000 eV electrons with the Ni and Au surfaces by the analysis of absolute reflection electron energy loss spectroscopy (REELS) spectra were described. The present analysis enables the inelastic mean free path (IMFP), surface excitation parameter (SEP) and differential SEP (DSEP) to be obtained simultaneously from an absolute REELS spectrum. The obtained IMFPs for Ni and Au showed a good agreement with those calculated using the TPP-2M predictive equation. The present SEPs determined for Ni and Au were fitted to the Chen's formula describing the dependence of the SEP on the electron energy, and material parameters for Ni and Au in Chen's formula were proposed. The present DESPs were compared with the theoretical results, and a reasonable agreement between the experimentally determined DSEPs and theoretical results was confirmed. The MC modeling of calculating the REELS spectrum, in which energy loss processes due to surface excitations are taken into account, was also described. The IMFP, SEP and DSEP determined by the present absolute REELS analysis were employed to describe energy loss processes by inelastic scattering in the proposed MC simulation. The simulated REELS spectra were found to be in a good agreement with the experimental spectra for both Ni and Au.

  8. The surface properties of biopolymer-coated fruit: A review

    Directory of Open Access Journals (Sweden)

    Diana Cristina Moncayo Martinez

    2013-09-01

    Full Text Available Environmental conservation concerns have led to research and development regarding biodegradable materials from biopolymers, leading to new formulations for edible films and coatings for preserving the quality of fresh fruit and vegetables. Determining fruit skin surface properties for a given coating solution has led to predicting coating efficiency. Wetting was studied by considering spreading, adhesion and cohesion and measuring the contact angle, thus optimising the coating formulation in terms of biopolymer, plasticiser, surfactant, antimicrobial and antioxidant concentration. This work reviews the equations for determining fruit surface properties by using polar and dispersive interaction calculations and by determining the contact angle.

  9. Parametric surface and properties defined on parallelogrammic domain

    OpenAIRE

    Shuqian Fan; Jinsong Zou; Mingquan Shi

    2014-01-01

    Similar to the essential components of many mechanical systems, the geometrical properties of the teeth of spiral bevel gears greatly influence the kinematic and dynamic behaviors of mechanical systems. Logarithmic spiral bevel gears show a unique advantage in transmission due to their constant spiral angle property. However, a mathematical model suitable for accurate digital modeling, differential geometrical characteristics, and related contact analysis methods for tooth surfaces have not b...

  10. Properties of water surface discharge at different pulse repetition rates

    International Nuclear Information System (INIS)

    Ruma,; Yoshihara, K.; Hosseini, S. H. R.; Sakugawa, T.; Akiyama, H.; Akiyama, M.; Lukeš, P.

    2014-01-01

    The properties of water surface discharge plasma for variety of pulse repetition rates are investigated. A magnetic pulse compression (MPC) pulsed power modulator able to deliver pulse repetition rates up to 1000 Hz, with 0.5 J per pulse energy output at 25 kV, was used as the pulsed power source. Positive pulse with a point-to-plane electrode configuration was used for the experiments. The concentration and production yield of hydrogen peroxide (H 2 O 2 ) were quantitatively measured and orange II organic dye was treated, to evaluate the chemical properties of the discharge reactor. Experimental results show that the physical and chemical properties of water surface discharge are not influenced by pulse repetition rate, very different from those observed for under water discharge. The production yield of H 2 O 2 and degradation rate per pulse of the dye did not significantly vary at different pulse repetition rates under a constant discharge mode on water surface. In addition, the solution temperature, pH, and conductivity for both water surface and underwater discharge reactors were measured to compare their plasma properties for different pulse repetition rates. The results confirm that surface discharge can be employed at high pulse repetition rates as a reliable and advantageous method for industrial and environmental decontamination applications.

  11. Statistical inference for classification of RRIM clone series using near IR reflectance properties

    Science.gov (United States)

    Ismail, Faridatul Aima; Madzhi, Nina Korlina; Hashim, Hadzli; Abdullah, Noor Ezan; Khairuzzaman, Noor Aishah; Azmi, Azrie Faris Mohd; Sampian, Ahmad Faiz Mohd; Harun, Muhammad Hafiz

    2015-08-01

    RRIM clone is a rubber breeding series produced by RRIM (Rubber Research Institute of Malaysia) through "rubber breeding program" to improve latex yield and producing clones attractive to farmers. The objective of this work is to analyse measurement of optical sensing device on latex of selected clone series. The device using transmitting NIR properties and its reflectance is converted in terms of voltage. The obtained reflectance index value via voltage was analyzed using statistical technique in order to find out the discrimination among the clones. From the statistical results using error plots and one-way ANOVA test, there is an overwhelming evidence showing discrimination of RRIM 2002, RRIM 2007 and RRIM 3001 clone series with p value = 0.000. RRIM 2008 cannot be discriminated with RRIM 2014; however both of these groups are distinct from the other clones.

  12. Influence of surface roughness on the friction property of textured surface

    OpenAIRE

    Yuankai Zhou; Hua Zhu; Wenqian Zhang; Xue Zuo; Yan Li; Jianhua Yang

    2015-01-01

    In contrast with dimple textures, surface roughness is a texture at the micro-scale, essentially which will influence the load-bearing capacity of lubricant film. The numerical simulation was carried out to investigate the influence of surface roughness on friction property of textured surface. The lubricant film pressure was obtained using the method of computational fluid dynamics according to geometric model of round dimple, and the renormalization-group k–ε turbulent model was adopted in ...

  13. Detecting moisture status of pecan orchards and the potential of remotely-sensed surface reflectance data

    Science.gov (United States)

    Othman, Yahia Abdelrahman

    Demand for New Mexico's limited water resources coupled with periodic drought has increased the need to schedule irrigation of pecan orchards based on tree water status. The overall goal of this research was to develop advanced tree water status sensing techniques to optimize irrigation scheduling of pecan orchards. To achieve this goal, I conducted three studies in the La Mancha and Leyendecker orchards, both mature pecan orchards located in the Mesilla Valley, New Mexico. In the first study, I screened leaf-level physiological changes that occurred during cyclic irrigation to determine parameters that best represented changes in plant moisture status. Then, I linked plant physiological changes to remotely-sensed surface reflectance data derived from Landsat Thematic Mapper (TM) and Enhanced Thematic Mapper (ETM+). In the second study, I assessed the impact of water deficits that developed during the flood irrigation dry-down cycles on photosynthesis (A) and gas exchange and established preliminary water deficit thresholds of midday stem water potential (Psi smd) critical to A and gas exchange of pecans. In a third study, I investigated whether hyperspectral data obtained from a handheld spectroradiometer and multispectral remotely-sensed data derived from Landsat 7 ETM+ and Landsat 8 Operational Land Imager (OLI) could detect moisture status in pecans during cyclic flood irrigations. I conducted the first study simultaneously in both orchards. Leaf-level physiological responses and remotely-sensed surface reflectance data were collected from trees that were either well watered or in water deficit. Midday stem water potential was the best leaf-level physiological response to detect moisture status in pecans. Multiple linear regression between Psismd and vegetation indices revealed a significant relationship (R 2 = 0.54) in both orchards. Accordingly, I concluded that remotely-sensed multispectral data form Landsat TMETM+ holds promise for detecting the moisture

  14. Transient reflection and transmission of E polarized electromagnetic waves at boundary surface between air and moving isotropic plasma

    International Nuclear Information System (INIS)

    Saito, Yukimasa

    1977-01-01

    The transient reflection and transmission waves of E polarized electromagnetic waves coming into the boundary surface between air and moving isotropic plasma were theoretically investigated. By using the Laplace transformation in the moving system, the formulae of Lorentz and inverse Lorentz transformations concerning electromagnetic field were transformed, thus the transient reflection and transmission waves were obtained. These waves were normalized with the angular frequency of the incident waves, and the variation of the wave form was obtained. Examples of the numerical calculation of reflected waves are shown for the plasma moving in parallel to the boundary surface. (Kato, T.)

  15. Modification of kaolinite surfaces through mechanochemical activation with quartz: A diffuse reflectance infrared fourier transform and chemometrics study.

    Science.gov (United States)

    Carmody, Onuma; Frost, Ray L; Kristóf, János; Kokot, Serge; Kloprogge, J Theo; Makó, Eva

    2006-12-01

    Studies of kaolinite surfaces are of industrial importance. One useful method for studying the changes in kaolinite surface properties is to apply chemometric analyses to the kaolinite surface infrared spectra. A comparison is made between the mechanochemical activation of Kiralyhegy kaolinites with significant amounts of natural quartz and the mechanochemical activation of Zettlitz kaolinite with added quartz. Diffuse reflectance infrared Fourier transform (DRIFT) spectra were analyzed using principal component analysis (PCA) and multi-criteria decision making (MCDM) methods, the preference ranking organization method for enrichment evaluations (PROMETHEE) and geometrical analysis for interactive assistance (GAIA). The clear discrimination of the Kiralyhegy spectral objects on the two PC scores plots (400-800 and 800-2030 cm(-1)) indicated the dominance of quartz. Importantly, no ordering of any spectral objects appeared to be related to grinding time in the PC plots of these spectral regions. Thus, neither the kaolinite nor the quartz are systematically responsive to grinding time according to the spectral criteria investigated. The third spectral region (2600-3800 cm(-1), OH vibrations), showed apparent systematic ordering of the Kiralyhegy and, to a lesser extent, Zettlitz spectral objects with grinding time. This was attributed to the effect of the natural quartz on the delamination of kaolinite and the accompanying phenomena (i.e., formation of kaolinite spheres and water). The mechanochemical activation of kaolinite and quartz, through dry grinding, results in changes to the surface structure. Different grinding times were adopted to study the rate of destruction of the kaolinite and quartz structures. This relationship (i.e., grinding time) was classified using PROMETHEE and GAIA methodology.

  16. Improved analytical formulas for x-ray and neutron reflection from surface films

    International Nuclear Information System (INIS)

    Zhou, X.; Chen, S.; Felcher, G.P.

    1992-01-01

    A general and exact expression for x-ray and neutron reflectance and transmittance is given in terms of an integral of the real-space scattering-length-density profile fluctuation of the film, with respect to an arbitrary constant reference density level, over the wave function inside the film. Various special cases and approximations are then derived from this exact form by suitable approximations of the wave function. In particular, two practical approximate formulas are derived which are improvement over the corresponding distorted-wave Born approximations. One is for an arbitrary film deposited on a known substrate and the other for a free liquid surface. Numerical results are used to illustrate the accuracy of these formulas

  17. Modified polarized geometrical attenuation model for bidirectional reflection distribution function based on random surface microfacet theory.

    Science.gov (United States)

    Liu, Hong; Zhu, Jingping; Wang, Kai

    2015-08-24

    The geometrical attenuation model given by Blinn was widely used in the geometrical optics bidirectional reflectance distribution function (BRDF) models. Blinn's geometrical attenuation model based on symmetrical V-groove assumption and ray scalar theory causes obvious inaccuracies in BRDF curves and negatives the effects of polarization. Aiming at these questions, a modified polarized geometrical attenuation model based on random surface microfacet theory is presented by combining of masking and shadowing effects and polarized effect. The p-polarized, s-polarized and unpolarized geometrical attenuation functions are given in their separate expressions and are validated with experimental data of two samples. It shows that the modified polarized geometrical attenuation function reaches better physical rationality, improves the precision of BRDF model, and widens the applications for different polarization.

  18. Raman scattering and attenuated-total-reflection studies of surface-plasmon polaritons

    International Nuclear Information System (INIS)

    Kurosawa, K.; Pierce, R.M.; Ushioda, S.; Hemminger, J.C.

    1986-01-01

    We have made in situ measurements of attenuated total reflection (ATR) and Raman scattering from a layered structure consisting of a glass prism, a thin silver film, an MgF 2 spacer, and a liquid mixture whose refractive index is matched to that of MgF 2 . When the incident angle of the laser beam coincides with the ATR angle, the surface-plasmon polariton (SPP) of the silver film is excited resonantly and the Raman scattering intensity of the liquid shows a maximum. The same effect is observed at the frequency of the Stokes scattered light. By measuring the decrease of the Raman scattering intensity of the liquid with increase of the thickness of the MgF 2 spacer layer, we have determined the decay length (l/sub d/) of the SPP field into the liquid. The measured value of l/sub d/ = 1539 A agrees with the calculated value, 1534 A

  19. Recent Developments in the X-Ray Reflectivity Analysis for Rough Surfaces and Interfaces of Multilayered Thin Film Materials

    Directory of Open Access Journals (Sweden)

    Yoshikazu Fujii

    2013-01-01

    Full Text Available X-ray reflectometry is a powerful tool for investigations on rough surface and interface structures of multilayered thin film materials. The X-ray reflectivity has been calculated based on the Parratt formalism, accounting for the effect of roughness by the theory of Nevot-Croce conventionally. However, in previous studies, the calculations of the X-ray reflectivity often show a strange effect where interference effects would increase at a rough surface. And estimated surface and interface roughnesses from the X-ray reflectivity measurements did not correspond to the TEM image observation results. The strange result had its origin in a used equation due to a serious mistake in which the Fresnel transmission coefficient in the reflectivity equation is increased at a rough interface because of a lack of consideration of diffuse scattering. In this review, a new accurate formalism that corrects this mistake is presented. The new accurate formalism derives an accurate analysis of the X-ray reflectivity from a multilayer surface of thin film materials, taking into account the effect of roughness-induced diffuse scattering. The calculated reflectivity by this accurate reflectivity equation should enable the structure of buried interfaces to be analyzed more accurately.

  20. [Studies on a sequential injection renewable surface reflectance spectrophotometric system using a microchip flow cell].

    Science.gov (United States)

    Wang, Jian-ya; Fang, Zhao-lun

    2002-02-01

    A microchip flow cell was developed for flow injection renewable surface assay by reflectance spectrophotometry. The flow cell was coupled to a sequential injection system and optical fiber photometric detection system. The flow cell featured a three-layer structure. The flow channel was cut into a silicone rubber membrance which formed the middle layer, and a porous filter was inlayed across a widened section of the channel to trap microbeads introduced into the flow cell. The area of the detection window of the flow cell was approximately 3.6 mm2, the volume of the bead trapped in the flow cell was 2.2 microL, the depth of the bead layer was 600 microns. A multistrand bifurcated optical fiber was coupled with incident light, detector and flow cell. The chromogenic reaction of Cr(VI) with 1,5-diphenylcarbohydrazide (DPC) which was adsorbed on trapped Polysorb C-18 beads was used as a model reaction to optimize the flow cell design and the experimental system. The reflectance of the renewable reaction surface was monitored at 540 nm. With 100 microL sample loaded and 1.0 mL.min-1 carrier flow rate, the linear response range was 0-0.6 microgram.mL-1 Cr(VI). A detection limit (3 sigma) of 6 ng.mL-1, precision of 1.5% RSD(n = 11), and a throughput of 64 samples per hour were achieved. Considerations in system and flow cell design, the influence of depth of the bead layer, weight of beads used, and the flow rates of carrier stream on the performance were discussed.

  1. Final report for the project "Improving the understanding of surface-atmosphere radiative interactions by mapping surface reflectance over the ARM CART site" (award DE-FG02-02ER63351)

    Energy Technology Data Exchange (ETDEWEB)

    Alexander P. Trishchenko; Yi Luo; Konstantin V. Khlopenkov, William M. Park; Zhanqing Li; Maureen Cribb

    2008-11-28

    Surface spectral reflectance (albedo) is a fundamental variable affecting the transfer of solar radiation and the Earth’s climate. It determines the proportion of solar energy absorbed by the surface and reflected back to the atmosphere. The International Panel on Climate Change (IPCC) identified surface albedo among key factors influencing climate radiative forcing. Accurate knowledge of surface reflective properties is important for advancing weather forecasting and climate change impact studies. It is also important for determining radiative impact and acceptable levels of greenhouse gases in the atmosphere, which makes this work strongly linked to major scientific objectives of the Climate Change Research Division (CCRD) and Atmospheric Radiation Measurement (ARM) Program. Most significant accomplishments of eth project are listed below. I) Surface albedo/BRDF datasets from 1995 to the end of 2004 have been produced. They were made available to the ARM community and other interested users through the CCRS public ftp site ftp://ftp.ccrs.nrcan.gc.ca/ad/CCRS_ARM/ and ARM IOP data archive under “PI data Trishchenko”. II) Surface albedo properties over the ARM SGP area have been described for 10-year period. Comparison with ECMWF data product showed some deficiencies in the ECMWF surface scheme, such as missing some seasonal variability and no dependence on sky-conditions which biases surface energy budget and has some influence of the diurnal cycle of upward radiation and atmospheric absorption. III) Four surface albedo Intensive Observation Period (IOP) Field Campaigns have been conducted for every season (August, 2002, May 2003, February 2004 and October 2004). Data have been prepared, documented and transferred to ARM IOP archive. Nine peer-reviewed journal papers and 26 conference papers have been published.

  2. Reversible Surface Properties of Polybenzoxazine/Silica Nanocomposites Thin Films

    Directory of Open Access Journals (Sweden)

    Wei-Chen Su

    2013-01-01

    Full Text Available We report the reversible surface properties (hydrophilicity, hydrophobicity of a polybenzoxazine (PBZ thin film through simple application of alternating UV illumination and thermal treatment. The fraction of intermolecularly hydrogen bonded O–H⋯O=C units in the PBZ film increased after UV exposure, inducing a hydrophilic surface; the surface recovered its hydrophobicity after heating, due to greater O–H⋯N intramolecular hydrogen bonding. Taking advantage of these phenomena, we prepared a PBZ/silica nanocomposite coating through two simple steps; this material exhibited reversible transitions from superhydrophobicity to superhydrophilicity upon sequential UV irradiation and thermal treatment.

  3. Surface effects on the mechanical properties of nanoporous materials

    International Nuclear Information System (INIS)

    Lu Zixing; Zhang Cungang; Liu Qiang; Yang Zhenyu

    2011-01-01

    In this paper, surface effects on the mechanical behaviour of nanoporous materials are investigated using the theory of surface elasticity and Timoshenko beam theory based on the tetrakaidecahedron (or Kelvin) open-cell foam model. Meanwhile, the influence of surface elasticity and residual surface stress on the mechanical properties of nanoporous materials is discussed. In addition, the results derived from the theory of Euler-Bernoulli beam model are also provided for comparison. Theoretical results show that the effective Young's modulus of the nanoporous materials increases as the diameter of the strut decreases, but in contrast Poisson's ratio and the brittle collapse strength decrease with the diameter of the strut. The contribution of shear deformation to surface effects on elastic properties is more significant, while the surface effects on brittle collapse strength are not sensitive to shear deformation, and it can even be neglected. As the strut size increases, the present results can be reduced to the cases without considering surface effects, which verifies the efficiency of the present model to a certain extent.

  4. The practice of reflection in the russian goodwill when buying enterprises as a property complex

    Directory of Open Access Journals (Sweden)

    O. A. Ovchinnikova

    2016-01-01

    Full Text Available When buying enterprises as a property complex, firm-the buyer can pay for it as excess cost of the acquired entity on its balance sheet, and an amount less than the value of the assets on the balance sheet of the acquiree. Based on the requirements of the Russian legislation, in the account of the buyer acquires an intangible asset that distinguishes the Russian from the international practice. International financial reporting standards do not recognize goodwill an intangible asset of the buyer enterprise. Therefore, it is necessary to specify the Russian practice of accounting transactions in the purchase of enterprises as property complex. The article presents a definition of the property complex, based on the requirements of the Civil Code of the Russian Federation, highlighted the stages of transfer of the property complex of the specified accounting documents that must be decorated, the analysis of the approaches of domestic and foreign authors to the recognition and measurement of goodwill, studied the specificity of the requirements of the Russian normative-legislative acts to the category “goodwill”, “intangible asset”. Based on the requirements of the Russian legislation, a positive goodwill is recognized in intangible asset (goodwill, in contrast to the negative goodwill (badwill, which immediately applies on other income of the organisation – the buyer of the enterprise – a property complex. On the positive business reputation, then the requirements of the Russian legislation, a positive goodwill is recognized intangible asset. In this paper, the authors proposed a model accounting for the purchase of enterprise as property complex as a result of which the acquisition price of an enterprise as a property complex exceeds its carrying amount of the assessment, therefore, in accounting, the buyer acquires an intangible asset in the form of a positive business reputation, compiled and substantiated recommended to reflect this

  5. A Harmonized Landsat-Sentinel-2 Surface Reflectance product: a resource for Agricultural Monitoring

    Science.gov (United States)

    Masek, J. G.; Claverie, M.; Ju, J.; Vermote, E.; Justice, C. O.

    2015-12-01

    The combination of Landsat and Sentinel-2 data offers a unique opportunity to observe globally the land every 2-3 days at medium (reflectance data from Landsat and Sentinel-2 missions and to deliver them to the community in a combined, seamless form. The HLS will be beneficial for global agricultural monitoring applications that require medium spatial resolution and weekly or more frequent observations. In particular, the provided opportunity to track crop phenology at the scale of individual fields will support detailed mapping of crop type and type-specific vegetation conditions. To create a compatible set of radiometric measurements, the HLS product relies on rigorous pre- and post-launch cross-calibration (Landsat-8 OLI and Sentinel-2 MSI) activities. The processing chain includes the following components: atmospheric correction, cloud/shadow masking, nadir BRDF-adjustment, spectral-adjustment, regridding, and temporal composite. The atmospheric correction and cloud masking is based on the OLI atmospheric correction developed at NASA-GSFC and has been adapted to the MSI data. The BRDF-adjustment is based on a disaggregation technique using MODIS-based BRDF coefficients. The technique has been evaluated using the multi-angular acquisition from the SPOT 4 and 5 (Take5) experiments. The spectral-adjustment relies on a linear regression that has been calibrated and evaluated using synthetic data and surface reflectance processed from a large number of hyperspectral EO-1 Hyperion scenes. Finally, significant effort is placed on product validation and evaluation. The delivered data set will include surface reflectance products at different levels: Using the native gridding, i.e. UTM, 30m for Landsat-8, and UTM, 10-20m for Sentinel-2 Using a common global gridding (Sinusoidal, 30m) Temporal composite (Sinusoidal, 30m, 5-day) During the first year of operation of Sentinel-2A, the HLS will be prototyped over a selection of 30 sites that includes some of the JECAM sites

  6. Seasonal lake surface water temperature trends reflected by heterocyst glycolipid-based molecular thermometers

    Science.gov (United States)

    Bauersachs, T.; Rochelmeier, J.; Schwark, L.

    2015-06-01

    preserved in the sediment record of Lake Schreventeich reflect summer surface water temperatures. As N2-fixing heterocystous cyanobacteria are widespread in present-day freshwater and brackish environments, we conclude that the distribution of HGs in sediments may allow for the reconstruction of surface water temperatures of modern and potentially ancient lacustrine settings.

  7. Surface properties of CNTs and their interaction with silica.

    Science.gov (United States)

    Sobolkina, Anastasia; Mechtcherine, Viktor; Bellmann, Cornelia; Khavrus, Vyacheslav; Oswald, Steffen; Hampel, Silke; Leonhardt, Albrecht

    2014-01-01

    In order to improve the embedding of carbon nanotubes (CNTs) in cement-based matrices, silica was deposited on the sidewall of CNTs by a sol-gel method. Knowledge of the conditions of CNTs' surfaces is a key issue in understanding the corresponding interaction mechanisms. In this study various types of CNTs synthesized using acetonitrile, cyclohexane, and methane were investigated with regard to their physicochemical surface properties. Significant differences in surface polarity as well as in the wetting properties of the CNTs, depending on the precursors used, were revealed by combining electro-kinetic potential and contact angle measurements. The hydrophobicity of CNTs decreases by utilising the carbon sources in the following order: cyclohexane, methane, and finally acetonitrile. The XPS analysis, applied to estimate the chemical composition at the CNT surface, showed nitrogen atoms incorporated into the tube structure by using acetonitrile as a carbon source. It was found that the simultaneous presence of nitrogen- and/or oxygen-containing sites with different acid-base properties increased the surface polarity of the CNTs, imparting amphoteric characteristics to them and improving their wetting behaviour. Regarding the silica deposition, strong differences in adsorption capacity of the CNTs were observed. The mechanism of silica adsorption through interfacial bond formation was discussed. Copyright © 2013 Elsevier Inc. All rights reserved.

  8. Reflectance properties of one-dimensional metal-dielectric ternary photonic crystal

    Energy Technology Data Exchange (ETDEWEB)

    Pandey, G. N., E-mail: gnpandey2009@gmail.com [Department of Physics, Amity Institute of Applied Sciences, AmityUniversity, Noida (U.P.) (India); Kumar, Narendra [Department of Physics (CASH), Modi University of Science and Technology, Lakshmangarh, Sikar, Rajsthan (India); Thapa, Khem B. [Department of Physics, U I E T, ChhatrapatiShahu Ji Maharaj University, Kanpur- (UP) (India); Ojha, S. P. [Department of Physics IIT, Banaras Hindu University (India)

    2016-05-06

    Metallic photonic crystal has a very important application in absorption enhancement in solar cells. It has been found that an ultra-thin metallic layer becomes transparent due to internal scattering of light through the each interface of the dielectric and metal surfaces. The metal has absorption due to their surface plasmon and the plasmon has important parameters for changing optical properties of the metal. We consider ternary metallic-dielectric photonic crystal (MDPC) for having large probabilities to change the optical properties of the MDPC and the photonic crystals may be changed by changing dimensionality, symmetry, lattice parameters, Filling fraction and effective refractive index refractive index contrast. In this present communication, we try to show that the photonic band gap in ternary metal-dielectric photonic crystal can be significantly enlarged when air dielectric constant is considered. All the theoretical analyses are made based on the transfer matrix method together with the Drude model of metal.

  9. Membranes with Surface-Enhanced Antifouling Properties for Water Purification

    Science.gov (United States)

    Shahkaramipour, Nima; Tran, Thien N.; Ramanan, Sankara; Lin, Haiqing

    2017-01-01

    Membrane technology has emerged as an attractive approach for water purification, while mitigation of fouling is key to lower membrane operating costs. This article reviews various materials with antifouling properties that can be coated or grafted onto the membrane surface to improve the antifouling properties of the membranes and thus, retain high water permeance. These materials can be separated into three categories, hydrophilic materials, such as poly(ethylene glycol), polydopamine and zwitterions, hydrophobic materials, such as fluoropolymers, and amphiphilic materials. The states of water in these materials and the mechanisms for the antifouling properties are discussed. The corresponding approaches to coat or graft these materials on the membrane surface are reviewed, and the materials with promising performance are highlighted. PMID:28273869

  10. Improvement of carbon fiber surface properties using electron beam irradiation

    International Nuclear Information System (INIS)

    Pino, E.S.; Machado, L.D.B.; Giovedi, C.

    2007-01-01

    Carbon fiber-reinforced advance composites have been used for structural applications, mainly on account of their mechanical properties. The main factor for a good mechanical performance of carbon fiber-reinforced composite is the interfacial interaction between its components, which are carbon fiber and polymeric matrix. The aim of this study is to improve the surface properties of the carbon fiber using ionizing radiation from an electron beam to obtain better adhesion properties in the resultant composite. EB radiation was applied on the carbon fiber itself before preparing test specimens for the mechanical tests. Experimental results showed that EB irradiation improved the tensile strength of carbon fiber samples. The maximum value in tensile strength was reached using doses of about 250 kGy. After breakage, the morphology aspect of the tensile specimens prepared with irradiated and non-irradiated car- bon fibers were evaluated. SEM micrographs showed modifications on the carbon fiber surface. (authors)

  11. An analytical and numerical study of the nonlinear reflection at a stress-free surface

    Energy Technology Data Exchange (ETDEWEB)

    Romer, Anne, E-mail: anne.romer@gmx.net; Kim, Jin-Yeon, E-mail: anne.romer@gmx.net [School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta, GA 30332 (United States); Jacobs, Laurence J. [School of Civil and Environmental Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA and G.W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, GA 30332 (United States)

    2015-03-31

    Implementation of the ultrasonic second harmonic generation has typically been restricted to simple setups such as through-transmission or Rayleigh surface waves. Recent research has evaluated the second harmonic waves generation in P- and SV- waves reflected from a stress-free surface to enable the single-sided interrogation of a specimen. This research considers the second harmonic generation in an aluminum specimen, which is analytically evaluated using an approach based on a perturbation method. Here, the model is chosen to mimic an experimental setup where the longitudinal wave is generated at oblique angle using a wedge transducer. Due to the mode conversion at the interface of the wedge and the specimen, it is necessary to evaluate longitudinal and shear waves, determining all second harmonic waves generated in the bulk and at the stress-free boundary. The theoretically developed model is then implemented in a commercial finite element code, COMSOL, using increasing fundamental wave amplitudes for different values of third order elastic constants. The results of this computational model verify the analytical approach and the proposed measurement setup, taking into account assumptions and approximations of the solution procedure. Furthermore, the computational model is used to draw important conclusions relevant to the experimental setup, including the need to avoid interaction with diffracted waves.

  12. Spontaneous acoustic emission of a corrugated shock wave in the presence of a reflecting surface

    International Nuclear Information System (INIS)

    Wouchuk, J.G.; Lopez Cavada, J.

    2004-01-01

    An analytic model to study perturbation evolution in the space between a corrugated shock and a piston surface is presented. The conditions for stable oscillation patterns are obtained by looking at the poles of the exact Laplace transform. It is seen that besides the standard D'yakov-Kontorovich (DK) mode of oscillation, the shock surface can exhibit an additional finite set of discrete frequencies, due to the interaction with the piston which reflects sound waves from behind. The additional eigenmodes are excited when the shock is launched at t=0 + . The first eigenmode (the DK mode) is always present, if the Hugoniot curve has the correct slope in the V-p plane. However, the additional frequencies could be excited for strong enough shocks. The predictions of the model are verified for particular cases by studying a van der Waals gas, as in the work of Bates and Montgomery [Phys. Fluids 11, 462 (1999); Phys. Rev. Lett. 84, 1180 (2000)]. Only acoustic emission modes are considered

  13. Mechanical and tribological properties of ion beam-processed surfaces

    International Nuclear Information System (INIS)

    Kodali, P.

    1998-01-01

    The intent of this work was to broaden the applications of well-established surface modification techniques and to elucidate the various wear mechanisms that occur in sliding contact of ion-beam processed surfaces. The investigation included characterization and evaluation of coatings and modified surfaces synthesized by three surface engineering methods; namely, beam-line ion implantation, plasma-source ion implantation, and DC magnetron sputtering. Correlation among measured properties such as surface hardness, fracture toughness, and wear behavior was also examined. This dissertation focused on the following areas of research: (1) investigating the mechanical and tribological properties of mixed implantation of carbon and nitrogen into single crystal silicon by beam-line implantation; (2) characterizing the mechanical and tribological properties of diamond-like carbon (DLC) coatings processed by plasma source ion implantation; and (3) developing and evaluating metastable boron-carbon-nitrogen (BCN) compound coatings for mechanical and tribological properties. The surface hardness of a mixed carbon-nitrogen implant sample improved significantly compared to the unimplanted sample. However, the enhancement in the wear factor of this sample was found to be less significant than carbon-implanted samples. The presence of nitrogen might be responsible for the degraded wear behavior since nitrogen-implantation alone resulted in no improvement in the wear factor. DLC coatings have low friction, low wear factor, and high hardness. The fracture toughness of DLC coatings has been estimated for the first time. The wear mechanism in DLC coatings investigated with a ruby slider under a contact stress of 1 GPa was determined to be plastic deformation. The preliminary data on metastable BCN compound coatings indicated high friction, low wear factor, and high hardness

  14. The laboratory investigation of surface envelope solitons: reflection from a vertical wall and collisions of solitons

    Science.gov (United States)

    Slunyaev, Alexey; Klein, Marco; Clauss, Günther F.

    2016-04-01

    Envelope soliton solutions are key elements governing the nonlinear wave dynamics within a simplified theory for unidirectional weakly modulated weakly nonlinear wave groups on the water surface. Within integrable models the solitons preserve their structure in collisions with other waves; they do not disperse and can carry energy infinitively long. Steep and short soliton-like wave groups have been shown to exist in laboratory tests [1] and, even earlier, in numerical simulations [2, 3]. Thus, long-living wave groups may play important role in the dynamics of intense sea waves and wave-structure interactions. The solitary wave groups may change the wave statistics and can be taken into account when developing approaches for the deterministic forecasting of dangerous waves, including so-called rogue waves. An experimental campaign has been conducted in the wave basin of the Technical University of Berlin on simulations of intense solitary wave groups. The first successful experimental observation of intense envelope solitons took place in this facility [1]. The new experiments aimed at following main goals: 1) to reproduce intense envelope solitons with different carrier wave lengths; 2) to estimate the rate of envelope soliton dissipation; 3) to consider the reflection of envelope solitons on a vertical wall; 4) to consider head-on collisions of envelope solitons, and 5) to consider overtaking interactions of envelope solitons. Up to 9 wave gauges were used in each experimental run, which enabled registration of the surface movement at different distances from the wavemaker, at different locations across the wave flume and near the wall. Besides surface displacements, the group envelope shapes were directly recorded, with use of phase shifts applied to the modulated waves generated by the wavemaker. [1] A. Slunyaev, G.F. Clauss, M. Klein, M. Onorato, Simulations and experiments of short intense envelope solitons of surface water waves. Phys. Fluids 25, 067105

  15. Improved algorithm for estimating optical properties of food and biological materials using spatially-resolved diffuse reflectance

    Science.gov (United States)

    In this research, the inverse algorithm for estimating optical properties of food and biological materials from spatially-resolved diffuse reflectance was optimized in terms of data smoothing, normalization and spatial region of reflectance profile for curve fitting. Monte Carlo simulation was used ...

  16. Shear-wave seismic reflection imaging and impedance inversion for a near-surface point-bar

    Science.gov (United States)

    Benton, N. W.; Morrison, M.; Lorenzo, J. M.; Odom, B.; Clift, P. D.; Olson, E.; Gostic, A.

    2017-12-01

    Imaging and inversion of SH-waves are useful to detect, map, and quantitatively characterize near-surface point-bar strata. We conduct a horizontally-polarized (SH) reflection survey across and along a near-surface (9 - 40 m) downstream point-bar. We invert for shear-impedance profiles and correlate our interpretation to electrical conductivity (EC) logs in adjacent wells to study the internal architecture and lithology of point-bars. We acquire two common-midpoint (CMP) SH-wave seismic reflection lines at False River (Point Coupee Parish, Louisiana). A 104 m long seismic line (L1) is oriented orthogonal (NW - SE) to point-bar strike. A second line (L2) is 48 m long and set parallel to point-bar strike (NE - SW). Two EC wells lie 33 m apart. Both wells are parallel with respect to the L1 survey and offset from it by 15 m. EC log measurements range from 1 - 25 m depth. Interference of Love-waves prevents seismic imaging at depths less than 9 m. The L1 and L2 data sets are inverted for shear-impedance using a model-based band-limited impedance (BLIMP) algorithm that incorporates a low-frequency velocity model. This model is also used for the depthing processing. The L1 cross-section shows coherent dipping reflection events ( 4 - 7º) from 0.15 - 0.35 s (10 - 40 m). The corresponding shear-impedance profile also reveals coherent and dipping impedance contrasts that grow in magnitude with increasing depth. The L2 cross-section shows comparatively less dip ( 1º) as well as sharper and shallower continuity of reflection events (0.1 - 0.28 s TWT or 9 - 25 m). Depth-converted (TVD) seismic amplitudes and impedance values correlate to near-surface point-bar geology via superposition of log data. The first well (W5) shows distinct EC local maxima (+50 - 70 mS/m) at 14.5 and 15.5 m depth that correlate well with the seismic amplitudes and impedance values from both L1 and L2 data sets. The second well (W7) shows comparatively lower local maxima (+40 - 60 mS/m) but at greater

  17. Surface-defect induced modifications in the optical properties of α-MnO_2 nanorods

    International Nuclear Information System (INIS)

    John, Reenu Elizabeth; Chandran, Anoop; Thomas, Marykutty; Jose, Joshy; George, K.C.

    2016-01-01

    Graphical abstract: - Highlights: • Alpha-MnO_2 nanorods are prepared by chemical method. • Difference in surface defect density is achieved. • Characterized using XRD, Rietveld, XPS, EDS, HR-TEM, BET, UV–vis absorption spectroscopy and PL spectroscopy. • Explains the bandstructure modification due to Jahn–Teller distortions using crystal field theory. • Modification in the intensity of optical emissions related to defect levels validates the concept of surface defect induced tuning of optical properties. - Abstract: The science of defect engineering via surface tuning opens a new route to modify the inherent properties of nanomaterials for advanced functional and practical applications. In this work, two independent synthesis methods (hydrothermal and co-precipitation) are adopted to fabricate α-MnO_2 nanorods with different defect structures so as to understand the effect of surface modifications on their optical properties. The crystal structure and morphology of samples are investigated with the aid of X-ray diffraction (XRD) and high resolution transmission electron microscopy (HRTEM). Atomic composition calculated from energy dispersive spectroscopy (EDS) confirms non-stoichiometry of the samples. The surface properties and chemical environment are thoroughly studied using X-ray photoelectron spectroscopy (XPS) and Brunauer–Emmett–Teller (BET) analysis. Bond angle variance and bond valence sum are determined to validate distortions in the basic MnO_6 octahedron. The surface studies indicate that the concentration of Jahn–Teller manganese (III) (Mn"3"+) ion in the samples differ from each other which results in their distinct properties. Band structure modifications due to Jahn–Teller distortion are examined with the aid of ultraviolet–visible (UV) reflectance and photoluminescence (PL) studies. The dual peaks obtained in derivative spectrum conflict the current concept on the bandgap energy of MnO_2. These studies suggest that

  18. An Operational Scheme for Deriving Standardised Surface Reflectance from Landsat TM/ETM+ and SPOT HRG Imagery for Eastern Australia

    Directory of Open Access Journals (Sweden)

    Neil Flood

    2013-01-01

    Full Text Available Operational monitoring of vegetation and land surface change over large areas can make good use of satellite sensors that measure radiance reflected from the Earth’s surface. Monitoring programs use multiple images for complete spatial coverage over time. Accurate retrievals of vegetation cover and vegetation change estimates can be hampered by variation, in both space and time, in the measured radiance, caused by atmospheric conditions, topography, sensor location, and sun elevation. In order to obtain estimates of cover that are comparable between images, and to retrieve accurate estimates of change, these sources of variation must be removed. In this paper we present a preprocessing scheme for minimising atmospheric, topographic and bi-directional reflectance effects on Landsat-5 TM, Landsat-7 ETM+ and SPOT-5 HRG imagery. The approach involves atmospheric correction to compute surface-leaving radiance, and bi-directional reflectance modelling to remove the effects of topography and angular variation in reflectance. The bi-directional reflectance model has been parameterised for eastern Australia, but the general approach is more widely applicable. The result is surface reflectance standardised to a fixed viewing and illumination geometry. The method can be applied to the entire record for these instruments, without intervention, which is of increasing importance with the increased availability of long term image archives. Validation shows that the corrections improve the estimation of reflectance at any given angular configuration, thus allowing the removal from the reflectance signal of much variation due to factors independent of the land surface. The method has been used to process over 45,000 Landsat-5 TM and Landsat-7 ETM+ scenes and 2,500 SPOT-5 scenes, over eastern Australia, and is now in use in operational monitoring programs.

  19. Parametric surface and properties defined on parallelogrammic domain

    Directory of Open Access Journals (Sweden)

    Shuqian Fan

    2014-01-01

    Full Text Available Similar to the essential components of many mechanical systems, the geometrical properties of the teeth of spiral bevel gears greatly influence the kinematic and dynamic behaviors of mechanical systems. Logarithmic spiral bevel gears show a unique advantage in transmission due to their constant spiral angle property. However, a mathematical model suitable for accurate digital modeling, differential geometrical characteristics, and related contact analysis methods for tooth surfaces have not been deeply investigated, since such gears are not convenient in traditional cutting manufacturing in the gear industry. Accurate mathematical modeling of the tooth surface geometry for logarithmic spiral bevel gears is developed in this study, based on the basic gearing kinematics and spherical involute geometry along with the tangent planes geometry; actually, the tooth surface is a parametric surface defined on a parallelogrammic domain. Equivalence proof of the tooth surface geometry is then given in order to greatly simplify the mathematical model. As major factors affecting the lubrication, surface fatigue, contact stress, wear, and manufacturability of gear teeth, the differential geometrical characteristics of the tooth surface are summarized using classical fundamental forms. By using the geometrical properties mentioned, manufactura-bility (and its limitation in logarithmic spiral bevel gears is analyzed using precision forging and multi-axis freeform milling, rather than classical cradle-type machine tool based milling or hobbing. Geometry and manufacturability analysis results show that logarithmic spiral gears have many application advantages, but many urgent issues such as contact tooth analysis for precision plastic forming and multi-axis freeform milling also need to be solved in a further study.

  20. [Corrosion resistant properties of different anodized microtopographies on titanium surfaces].

    Science.gov (United States)

    Fangjun, Huo; Li, Xie; Xingye, Tong; Yueting, Wang; Weihua, Guo; Weidong, Tian

    2015-12-01

    To investigate the corrosion resistant properties of titanium samples prepared by anodic oxidation with different surface morphologies. Pure titanium substrates were treated by anodic oxidation to obtain porous titanium films in micron, submicron, and micron-submicron scales. The surface morphologies, coating cross-sectional morphologies, crystalline structures, and surface roughness of these samples were characterized. Electrochemical technique was used to measure the corrosion potential (Ecorr), current density of corrosion (Icorr), and polarization resistance (Rp) of these samples in a simulated body fluid. Pure titanium could be modified to exhibit different surface morphologies by the anodic oxidation technique. The Tafel curve results showed that the technique can improve the corrosion resistance of pure titanium. Furthermore, the corrosion resistance varied with different surface morphologies. The submicron porous surface sample demonstrated the best corrosion resistance, with maximal Ecorr and Rp and minimal Icorr. Anodic oxidation technology can improve the corrosion resistance of pure titanium in a simulated body fluid. The submicron porous surface sample exhibited the best corrosion resistance because of its small surface area and thick barrier layer.

  1. Analysis of Static and Dynamic Properties of Micromirror with the Application of Response Surface Method

    Directory of Open Access Journals (Sweden)

    A Martowicz

    2016-09-01

    Full Text Available The paper presents the results of an application of response surface method to aid the analysis of variation of static and dynamic properties of micromirror. The multiphysics approach was taken into account to elaborate finite element model of electrostatically actuated microdevice and coupled analyses were carried out to yield the results. Used procedure of metamodel fitting is described and its quality is discussed. Elaborated approximations were used to perform the sensitivity analysis as well as to study the propagation of variation introduced by uncertain and control parameters. The input parameters deal with geometry, material properties and control voltage. As studied output characteristics there were chosen the resultant static vertical displacement of reflecting surfaces and the resonance frequency related to the first normal mode of vibration.

  2. Ultraviolet (UV)-reflective paint with ultraviolet germicidal irradiation (UVGI) improves decontamination of nosocomial bacteria on hospital room surfaces.

    Science.gov (United States)

    Jelden, Katelyn C; Gibbs, Shawn G; Smith, Philip W; Hewlett, Angela L; Iwen, Peter C; Schmid, Kendra K; Lowe, John J

    2017-06-01

    An ultraviolet germicidal irradiation (UVGI) generator (the TORCH, ClorDiSys Solutions, Inc.) was used to compare the disinfection of surface coupons (plastic from a bedrail, stainless steel, and chrome-plated light switch cover) in a hospital room with walls coated with ultraviolet (UV)-reflective paint (Lumacept) or standard paint. Each surface coupon was inoculated with methicillin-resistant Staphylococcus aureus (MRSA) or vancomycin-resistant Enterococcus faecalis (VRE), placed at 6 different sites within a hospital room coated with UV-reflective paint or standard paint, and treated by 10 min UVC exposure (UVC dose of 0-688 mJ/cm 2 between sites with standard paint and 0-553 mJ/cm 2 with UV-reflective paint) in 8 total trials. Aggregated MRSA concentrations on plastic bedrail surface coupons were reduced on average by 3.0 log 10 (1.8 log 10 Geometric Standard Deviation [GSD]) with standard paint and 4.3 log 10 (1.3 log 10 GSD) with UV-reflective paint (p = 0.0005) with no significant reduction differences between paints on stainless steel and chrome. Average VRE concentrations were reduced by ≥4.9 log 10 (surface types with UV-reflective paint and ≤4.1 log 10 (hospital bed from the UVGI generator, MRSA concentrations on average were reduced by 1.3 log 10 (1.7 log 10 GSD) with standard paint and 4.7 log 10 (1.3 log 10 GSD) with UV-reflective paint (p hospital room walls with UV-reflective paint enhanced UVGI disinfection of nosocomial bacteria on various surfaces compared to standard paint, particularly at a surface placement site indirectly exposed to UVC light.

  3. A sea surface reflectance model for (AATSR, and application to aerosol retrievals

    Directory of Open Access Journals (Sweden)

    A. M. Sayer

    2010-07-01

    Full Text Available A model of the sea surface bidirectional reflectance distribution function (BRDF is presented for the visible and near-IR channels (over the spectral range 550 nm to 1.6 μm of the dual-viewing Along-Track Scanning Radiometers (ATSRs. The intended application is as part of the Oxford-RAL Aerosols and Clouds (ORAC retrieval scheme. The model accounts for contributions to the observed reflectance from whitecaps, sun-glint and underlight. Uncertainties in the parametrisations used in the BRDF model are propagated through into the forward model and retrieved state. The new BRDF model offers improved coverage over previous methods, as retrievals are possible into the sun-glint region, through the ATSR dual-viewing system. The new model has been applied in the ORAC aerosol retrieval algorithm to process Advanced ATSR (AATSR data from September 2004 over the south-eastern Pacific. The assumed error budget is shown to be generally appropriate, meaning the retrieved states are consistent with the measurements and a priori assumptions. The resulting field of aerosol optical depth (AOD is compared with colocated MODIS-Terra observations, AERONET observations at Tahiti, and cruises over the oceanic region. MODIS and AATSR show similar spatial distributions of AOD, although MODIS reports values which are larger and more variable. It is suggested that assumptions in the MODIS aerosol retrieval algorithm may lead to a positive bias in MODIS AOD of order 0.01 at 550 nm over ocean regions where the wind speed is high.

  4. Thermal repellent properties of surface coating using silica

    Science.gov (United States)

    Lee, Y. Y.; Halim, M. S.; Aminudin, E.; Guntor, N. A.

    2017-11-01

    Extensive land development in urban areas is completely altering the surface profile of human living environment. As cities growing rapidly, impervious building and paved surfaces are replacing the natural landscape. In the developing countries with tropical climate, large masses of building elements, such as brick wall and concrete members, absorb and store large amount of heat, which in turn radiate back to the surrounding air during the night time. This bubble of heat is known as urban heat island (UHI). The use of high albedo urban surfaces is an inexpensive measure that can reduce surrounded temperature. Thus, the main focus of this study is to investigate the ability of silica, SiO2, with high albedo value, to be used as a thermal-repelled surface coating for brick wall. Three different silica coatings were used, namely silicone resin, silicone wax and rain repellent and one exterior commercial paint (jota shield paint) that commercially available in the market were applied on small-scale brick wall models. An uncoated sample also had been fabricated as a control sample for comparison. These models were placed at the outdoor space for solar exposure. Outdoor environment measurement was carried out where the ambient temperature, surface temperature, relative humidity and UV reflectance were recorded. The effect of different type of surface coating on temperature variation of the surface brick wall and the thermal performance of coatings as potential of heat reduction for brick wall have been studied. Based on the results, model with silicone resin achieved the lowest surface temperature which indicated that SiO2 can be potentially used to reduce heat absorption on the brick wall and further retains indoor passive thermal comfortability.

  5. Chromatic X-ray magnifying method and apparatus by Bragg reflective planes on the surface of Abbe sphere

    Science.gov (United States)

    Thoe, Robert S.

    1991-01-01

    Method and apparatus for producing sharp, chromatic, magnified images of X-ray emitting objects, are provided. The apparatus, which constitutes an X-ray microscope or telescope, comprises a connected collection of Bragg reflecting planes, comprised of either a bent crystal or a synthetic multilayer structure, disposed on and adjacent to a locus determined by a spherical surface. The individual Bragg planes are spatially oriented to Bragg reflect radiation from the object location toward the image location. This is accomplished by making the Bragg planes spatially coincident with the surfaces of either a nested series of prolate ellipsoids of revolution, or a nested series of spheres. The spacing between the Bragg reflecting planes can be tailored to control the wavelengths and the amount of the X-radiation that is Bragg reflected to form the X-ray image.

  6. Updating Landsat time series of surface-reflectance composites and forest change products with new observations

    Science.gov (United States)

    Hermosilla, Txomin; Wulder, Michael A.; White, Joanne C.; Coops, Nicholas C.; Hobart, Geordie W.

    2017-12-01

    The use of time series satellite data allows for the temporally dense, systematic, transparent, and synoptic capture of land dynamics over time. Subsequent to the opening of the Landsat archive, several time series approaches for characterizing landscape change have been developed, often representing a particular analytical time window. The information richness and widespread utility of these time series data have created a need to maintain the currency of time series information via the addition of new data, as it becomes available. When an existing time series is temporally extended, it is critical that previously generated change information remains consistent, thereby not altering reported change statistics or science outcomes based on that change information. In this research, we investigate the impacts and implications of adding additional years to an existing 29-year annual Landsat time series for forest change. To do so, we undertook a spatially explicit comparison of the 29 overlapping years of a time series representing 1984-2012, with a time series representing 1984-2016. Surface reflectance values, and presence, year, and type of change were compared. We found that the addition of years to extend the time series had minimal effect on the annual surface reflectance composites, with slight band-specific differences (r ≥ 0.1) in the final years of the original time series being updated. The area of stand replacing disturbances and determination of change year are virtually unchanged for the overlapping period between the two time-series products. Over the overlapping temporal period (1984-2012), the total area of change differs by 0.53%, equating to an annual difference in change area of 0.019%. Overall, the spatial and temporal agreement of the changes detected by both time series was 96%. Further, our findings suggest that the entire pre-existing historic time series does not need to be re-processed during the update process. Critically, given the time

  7. Objective and Subjective Evaluation of Reflecting and Diffusing Surfaces in Auditoria

    Science.gov (United States)

    Cox, Trevor John

    Available from UMI in association with The British Library. Requires signed TDF. The performance of reflectors and diffusers used in auditoria have been evaluated both objectively and subjectively. Two accurate systems have been developed to measure the scattering from surfaces via the cross correlation function. These have been used to measure the scattering from plane panels, curved panels and quadratic residue diffusers (QRDs). The scattering measurements have been used to test theoretical prediction methods based on the Helmholtz-Kirchhoff integral equation. Accurate prediction methods were found for all surfaces tested. The limitations of the more approximate methods have been defined. The assumptions behind Schroeder's design of the QRD have been tested and the local reacting admittance assumption found to be valid over a wide frequency range. It was found that the QRD only produces uniform scattering at low frequencies. For an on-axis source the scattering from a curved panel was as good as from a QRD. For an oblique source the QRD produced much more uniform scattering than the curved panel. The subjective measurements evaluated the smallest perceivable change in the early sound field, the part most influenced by reflectors and diffusers. A natural sounding simulation of a concert hall field within an anechoic chamber was used. Standard objective parameters were reasonable values when compared to values found in real halls and subjective preference measurements. A difference limen was measured for early lateral energy fraction (.048 +/-.005); inter aural cross correlation (.075 +/-.008); clarity index (.67 +/-.13 dB); and centre time (8.6 +/- 1.6 ms). It was found that: (i) when changes are made to diffusers and reflectors, changes in spatial impression will usually be larger than those in clarity; and (ii) acousticians can gain most by paying attention to lateral sound in auditoria. It was also found that: (i) diffuse reflections in the early sound field

  8. Microphase separated structure and surface properties of fluorinated polyurethane resin

    International Nuclear Information System (INIS)

    Sudaryanto; Nishino, T.; Hori, Y.; Nakamae, K.

    2000-01-01

    The effect of fluorination on microphase separation and surface properties of segmented polyurethane (PU) resin were investigated. A series of fluorinated polyurethane resin (FPU) was synthesized by reacting a fluorinated diol with aromatic diisocyanate. The microphase separated structure of FPU was studied by thermal analysis, and small angle X-ray scattering (SAXS) as well as wide angle X-ray diffraction (WAXD). The surface structure and properties were characterized by X-ray photoelectron spectroscopy (XPS) and dynamic contact angle measurement. The incorporation of fluorine into hard segment brings the FPU to have a higher hard domain cohesion and increase the phase separation, however localization of fluorine on the surface could not be observed. On the other hands, localization of fluorine on the surface could be achieved for soft segment fluorinated PU without any significant change in microphase separated structure. The result from this study give an important basic information for designing PU coating material with a low surface energy and strong adhesion as well as for development of release film on pressure sensitive adhesive tape. (author)

  9. Giant enhancement of reflectance due to the interplay between surface confined wave modes and nonlinear gain in dielectric media.

    Science.gov (United States)

    Kim, Sangbum; Kim, Kihong

    2017-12-11

    We study theoretically the interplay between the surface confined wave modes and the linear and nonlinear gain of the dielectric layer in the Otto configuration. The surface confined wave modes, such as surface plasmons or waveguide modes, are excited in the dielectric-metal bilayer by obliquely incident p waves. In the purely linear case, we find that the interplay between linear gain and surface confined wave modes can generate a large reflectance peak with its value much greater than 1. As the linear gain parameter increases, the peak appears at smaller incident angles, and the associated modes also change from surface plasmons to waveguide modes. When the nonlinear gain is turned on, the reflectance shows very strong multistability near the incident angles associated with surface confined wave modes. As the nonlinear gain parameter is varied, the reflectance curve undergoes complicated topological changes and sometimes displays separated closed curves. When the nonlinear gain parameter takes an optimally small value, a giant amplification of the reflectance by three orders of magnitude occurs near the incident angle associated with a waveguide mode. We also find that there exists a range of the incident angle where the wave is dissipated rather than amplified even in the presence of gain. We suggest that this can provide the basis for a possible new technology for thermal control in the subwavelength scale.

  10. Oxidative nanopatterning of titanium generates mesoporous surfaces with antimicrobial properties

    Directory of Open Access Journals (Sweden)

    Variola F

    2014-05-01

    Full Text Available Fabio Variola,1,2 Sylvia Francis Zalzal,3 Annie Leduc,3 Jean Barbeau,3 Antonio Nanci31Faculty of Engineering, Department of Mechanical Engineering, 2Faculty of Science, Department of Physics, University of Ottawa, Ottawa, ON, 3Faculty of Dental Medicine, Université de Montréal, Montreal, QC, CanadaAbstract: Mesoporous surfaces generated by oxidative nanopatterning have the capacity to selectively regulate cell behavior, but their impact on microorganisms has not yet been explored. The main objective of this study was to test the effects of such surfaces on the adherence of two common bacteria and one yeast strain that are responsible for nosocomial infections in clinical settings and biomedical applications. In addition, because surface characteristics are known to affect bacterial adhesion, we further characterized the physicochemical properties of the mesoporous surfaces. Focused ion beam (FIB was used to generate ultrathin sections for elemental analysis by energy-dispersive X-ray spectroscopy (EDS, nanobeam electron diffraction (NBED, and high-angle annular dark field (HAADF scanning transmission electron microscopy (STEM imaging. The adherence of Staphylococcus aureus, Escherichia coli and Candida albicans onto titanium disks with mesoporous and polished surfaces was compared. Disks with the two surfaces side-by-side were also used for direct visual comparison. Qualitative and quantitative results from this study indicate that bacterial adhesion is significantly hindered by the mesoporous surface. In addition, we provide evidence that it alters structural parameters of C. albicans that determine its invasiveness potential, suggesting that microorganisms can sense and respond to the mesoporous surface. Our findings demonstrate the efficiency of a simple chemical oxidative treatment in generating nanotextured surfaces with antimicrobial capacity with potential applications in the implant manufacturing industry and hospital setting

  11. Microstructure and properties of cast iron after laser surface hardening

    Directory of Open Access Journals (Sweden)

    Stanislav

    2013-12-01

    Full Text Available Laser surface hardening of cast iron is not trivial due to the material’s heterogeneity and coarse-grained microstructure, particularly in massive castings. Despite that, hardening of heavy moulds for automotive industry is in high demand. The present paper summarises the findings collected over several years of study of materials structure and surface properties. Phase transformations in the vicinity of graphite are described using examples from production of body parts in automotive industry. The description relates to formation of martensite and carbide-based phases, which leads to hardness values above 65 HRC and to excellent abrasion resistance.

  12. Image potential effect on the specular reflection coefficient of alkali ions scattered from a nickel surface at low energy

    International Nuclear Information System (INIS)

    Zemih, R.; Boudjema, M.; Benazeth, C.; Boudouma, Y.; Chami, A.C.

    2002-01-01

    The resonant charge exchange in the incoming path of alkali ions scattered at low energy from a polycrystalline nickel surface is studied by using the image effect occurring at glancing incidence (2-10 deg. from the surface plane) and for specular reflection. The part of the experimental artefacts (geometrical factor, surface roughness ...) is extracted from the reflection coefficient of almost completely neutralised projectiles (He + or Ne + ) compared with the coefficient obtained from numerical simulations (TRIM and MARLOWE codes). The present model explains very well the lowering of the reflection coefficient measured at grazing incidence (below 4 deg.). Furthermore, the optimised values of the charge fraction in the incoming path and the image potential are in agreement with the theoretical calculations in the case of Na + /Ni at 4 keV

  13. A far ultraviolet spectroscopic study of the reflectance, luminescence and electronic properties of SrMgF4 single crystals

    International Nuclear Information System (INIS)

    Ogorodnikov, I.N.; Pustovarov, V.A.; Omelkov, S.I.; Isaenko, L.I.; Yelisseyev, A.P.; Goloshumova, A.A.; Lobanov, S.I.

    2014-01-01

    The electronic properties of single crystals of SrMgF 4 have been determined using low-temperature (10–293 K) time-resolved vacuum ultraviolet synchrotron radiation spectroscopy, far ultraviolet (3.7–36 eV) reflectance spectra and calculations for the spectra of optical functions. The bandgap of investigated compound was found at E g =12.55eV, the energy threshold for creation of the unrelaxed excitons at E n=1 =11.37eV, and the low-energy fundamental absorption edge at 10.3 eV. Two groups of photoluminescence (PL) bands have been identified: the exciton-type emissions at 2.6–3.3 and 3.3–4.2 eV and defect-related emissions at 1.8–2.6 and 4.2–5.5 eV. It was shown that PL excitation (PLE) for the exciton-type emission bands occurs mainly at the low-energy tail of the fundamental absorption of the crystal with a maximum at 10.7 eV. At excitation energies above E g the energy transfer from the host lattice to the PL emission centers is inefficient. The paper discusses the origin of the excitonic-type PLE spectra taking into account the results of modeling the PLE spectra shape in the framework of a simple diffusion theory and surface energy losses. -- Highlights: • Far-ultraviolet reflection spectra of SrMgF 4 were studied. • Photoluminescence (PL) emission and PL excitation spectra were studied. • Optical function spectra were calculated on the basis of experimental data. • Electronic structure properties of undoped SrMgF 4 crystals were determined

  14. Neutron Reflection Study of Surface Adsorption of Fc, Fab, and the Whole mAb.

    Science.gov (United States)

    Li, Zongyi; Li, Ruiheng; Smith, Charles; Pan, Fang; Campana, Mario; Webster, John R P; van der Walle, Christopher F; Uddin, Shahid; Bishop, Steve M; Narwal, Rojaramani; Warwicker, Jim; Lu, Jian Ren

    2017-07-12

    Characterizing the influence of fragment crystallization (Fc) and antigen-binding fragment (Fab) on monoclonal antibody (mAb) adsorption at the air/water interface is an important step to understanding liquid mAb drug product stability during manufacture, shipping, and storage. Here, neutron reflection is used to study the air/water adsorption of a mAb and its Fc and Fab fragments. By varying the isotopic contrast, the adsorbed amount, thickness, orientation, and immersion of the adsorbed layers could be determined unambiguously. While Fc adsorption reached saturation within the hour, its surface adsorbed amount showed little variation with bulk concentration. In contrast, Fab adsorption was slower and the adsorbed amount was concentration dependent. The much higher Fc adsorption, as compared to Fab, was linked to its lower surface charge. Time and concentration dependence of mAb adsorption was dominated by Fab behavior, although both Fab and Fc behaviors contributed to the amount of mAb adsorbed. Changing the pH from 5.5 to 8.8 did not much perturb the adsorbed amount of Fc, Fab, or mAb. However, a small decrease in adsorption was observed for the Fc over pH 8-8.8 and vice versa for the Fab and mAb, consistent with a dominant Fab behavior. As bulk concentration increased from 5 to 50 ppm, the thicknesses of the Fc layers were almost constant at 40 Å, while Fab and mAb layers increased from 45 to 50 Å. These results imply that the adsorbed mAb, Fc, and Fab all retained their globular structures and were oriented with their short axial lengths perpendicular to the interface.

  15. Surface properties of Ti-6Al-4V alloy part I: Surface roughness and apparent surface free energy.

    Science.gov (United States)

    Yan, Yingdi; Chibowski, Emil; Szcześ, Aleksandra

    2017-01-01

    Titanium (Ti) and its alloys are the most often used implants material in dental treatment and orthopedics. Topography and wettability of its surface play important role in film formation, protein adhesion, following osseointegration and even duration of inserted implant. In this paper, we prepared Ti-6Al-4V alloy samples using different smoothing and polishing materials as well the air plasma treatment, on which contact angles of water, formamide and diiodomethane were measured. Then the apparent surface free energy was calculated using four different approaches (CAH, LWAB, O-W and Neumann's Equation of State). From LWAB approach the components of surface free energy were obtained, which shed more light on the wetting properties of samples surface. The surface roughness of the prepared samples was investigated with the help of optical profilometer and AFM. It was interesting whether the surface roughness affects the apparent surface free energy. It was found that both polar interactions the electron donor parameter of the energy and the work of water adhesion increased with decreasing roughness of the surfaces. Moreover, short time plasma treatment (1min) caused decrease in the surface hydrophilic character, while longer time (10min) treatment caused significant increase in the polar interactions and the work of water adhesion. Although Ti-6Al-4V alloy has been investigated many times, to our knowledge, so far no paper has been published in which surface roughness and changes in the surface free energy of the alloy were compared in the quantitative way in such large extent. This novel approach deliver better knowledge about the surface properties of differently smoothed and polished samples which may be helpful to facilitate cell adhesion, proliferation and mineralization. Therefore the results obtained present also potentially practical meaning. Copyright © 2016 Elsevier B.V. All rights reserved.

  16. Friction Properties of Surface-Fluorinated Carbon Nanotubes

    Science.gov (United States)

    Wal, R. L. Vander; Miyoshi, K.; Street, K. W.; Tomasek, A. J.; Peng, H.; Liu, Y.; Margrave, J. L.; Khabashesku, V. N.

    2005-01-01

    Surface modification of the tubular or sphere-shaped carbon nanoparticles through chemical treatment, e.g., fluorination, is expected to significantly affect their friction properties. In this study, a direct fluorination of the graphene-built tubular (single-walled carbon nanotubes) structures has been carried out to obtain a series of fluorinated nanotubes (fluoronanotubes) with variable C(n)F (n =2-20) stoichiometries. The friction coefficients for fluoronanotubes, as well as pristine and chemically cut nanotubes, were found to reach values as low as 0.002-0.07, according to evaluation tests run in contact with sapphire in air of about 40% relative humidity on a ball-on-disk tribometer which provided an unidirectional sliding friction motion. These preliminary results demonstrate ultra-low friction properties and show a promise in applications of surface modified nanocarbons as a solid lubricant.

  17. Surface properties of hydrogenated nanodiamonds: a chemical investigation.

    Science.gov (United States)

    Girard, H A; Petit, T; Perruchas, S; Gacoin, T; Gesset, C; Arnault, J C; Bergonzo, P

    2011-06-28

    Hydrogen terminations (C-H) confer to diamond layers specific surface properties such as a negative electron affinity and a superficial conductive layer, opening the way to specific functionalization routes. For example, efficient covalent bonding of diazonium salts or of alkene moieties can be performed on hydrogenated diamond thin films, owing to electronic exchanges at the interface. Here, we report on the chemical reactivity of fully hydrogenated High Pressure High Temperature (HPHT) nanodiamonds (H-NDs) towards such grafting, with respect to the reactivity of as-received NDs. Chemical characterizations such as FTIR, XPS analysis and Zeta potential measurements reveal a clear selectivity of such couplings on H-NDs, suggesting that C-H related surface properties remain dominant even on particles at the nanoscale. These results on hydrogenated NDs open up the route to a broad range of new functionalizations for innovative NDs applications development. This journal is © the Owner Societies 2011

  18. Using the Surface Reflectance MODIS Terra Product to Estimate Turbidity in Tampa Bay, Florida

    Directory of Open Access Journals (Sweden)

    Douglas L. Rickman

    2010-12-01

    Full Text Available Turbidity is a commonly-used index of the factors that determine light penetration in the water column. Consistent estimation of turbidity is crucial to design environmental and restoration management plans, to predict fate of possible pollutants, and to estimate sedimentary fluxes into the ocean. Traditional methods monitoring fixed geographical locations at fixed intervals may not be representative of the mean water turbidity in estuaries between intervals, and can be expensive and time consuming. Although remote sensing offers a good solution to this limitation, it is still not widely used due in part to required complex processing of imagery. There are satellite-derived products, including the Moderate Resolution Imaging Spectroradiometer (MODIS Terra surface reflectance daily product (MOD09GQ Band 1 (620–670 nm which are now routinely available at 250 m spatial resolution and corrected for atmospheric effect. This study shows this product to be useful to estimate turbidity in Tampa Bay, Florida, after rainfall events (R2 = 0.76, n = 34. Within Tampa Bay, Hillsborough Bay (HB and Old Tampa Bay (OTB presented higher turbidity compared to Middle Tampa Bay (MTB and Lower Tampa Bay (LTB.

  19. Magnetic Nanoparticles: Surface Effects and Properties Related to Biomedicine Applications

    OpenAIRE

    Issa, Bashar; Obaidat, Ihab M.; Albiss, Borhan A.; Haik, Yousef

    2013-01-01

    Due to finite size effects, such as the high surface-to-volume ratio and different crystal structures, magnetic nanoparticles are found to exhibit interesting and considerably different magnetic properties than those found in their corresponding bulk materials. These nanoparticles can be synthesized in several ways (e.g., chemical and physical) with controllable sizes enabling their comparison to biological organisms from cells (10–100 μm), viruses, genes, down to proteins (3–50 nm). The opti...

  20. Correlation properties of surface and percolation transfer of electrons

    International Nuclear Information System (INIS)

    Bakunin, O.G.

    2002-01-01

    In this work was received equation, connecting correlatively properties of surface with electrons distribution function. Usually for equilibrium is necessary a large number of collisions. Collisions are 'destroying' correlations. In case rare collisions large importance have correlations and 'memory' effects. Non-Markov's character of emitting particles by surface lead to strongly nonequilibrium condition of 'gas'. Here kinetic equation of diffusive form does not apply. Classical kinetic equation are described only conditions near to equilibrium. This work offers to use ideas anomal diffusion in phase-space. The correlation properties of surface describe by correlations of velocities of emitting electrons: B(t). We offer to use functional equation for probability collision instead of kinetic equation: ∫ 0 ν 0 W noncoll F(ν) dv = 1 - B(t). This functional allow to consider 'memory' effects. It is important for consideration of electrons and clusters near surfaces. Distribution function become direct connected with correlations. In classical Kubo-Mory theory of transfer is necessary to get nondivergences integral: D ∝ ∫ 0 ∞ B(t). In considering case we can use even 'power function'. It was used 'slow' correlation function as Kohlraush in calculations. The information about kinetics and correlations properties are containing in one functional equation. It was received solution of this equation in form Levy function: F(ν) ∝ 1/ν α exp(-1/ν). The solution of this form can not be get with help asymptotic methods of kinetic theory. Asymptotics of solution have scale-invariant character F(V) ∝ 1/V α . This indicate on fractal properties phase-space. (author)

  1. Imaging the spectral reflectance properties of bipolar radiofrequency-fused bowel tissue

    Science.gov (United States)

    Clancy, Neil T.; Arya, Shobhit; Stoyanov, Danail; Du, Xiaofei; Hanna, George B.; Elson, Daniel S.

    2015-07-01

    Delivery of radiofrequency (RF) electrical energy is used during surgery to heat and seal tissue, such as vessels, allowing resection without blood loss. Recent work has suggested that this approach may be extended to allow surgical attachment of larger tissue segments for applications such as bowel anastomosis. In a large series of porcine surgical procedures bipolar RF energy was used to resect and re-seal the small bowel in vivo with a commercial tissue fusion device (Ligasure; Covidien PLC, USA). The tissue was then imaged with a multispectral imaging laparoscope to obtain a spectral datacube comprising both fused and healthy tissue. Maps of blood volume, oxygen saturation and scattering power were derived from the measured reflectance spectra using an optimised light-tissue interaction model. A 60% increase in reflectance of visible light (460-700 nm) was observed after fusion, with the tissue taking on a white appearance. Despite this the distinctive shape of the haemoglobin absorption spectrum was still noticeable in the 460-600 nm wavelength range. Scattering power increased in the fused region in comparison to normal serosa, while blood volume and oxygen saturation decreased. Observed fusion-induced changes in the reflectance spectrum are consistent with the biophysical changes induced through tissue denaturation and increased collagen cross-linking. The multispectral imager allows mapping of the spatial extent of these changes and classification of the zone of damaged tissue. Further analysis of the spectral data in parallel with histopathological examination of excised specimens will allow correlation of the optical property changes with microscopic alterations in tissue structure.

  2. The multispectral reflectance of shortwave radiation by agricultural crops in relation with their morphological and optical properties

    NARCIS (Netherlands)

    Bunnik, N.J.J.

    1978-01-01

    Relations between morphological properties of uniform canopies. optical properties of the leaves and reflection of shortwave radiation, in the visible light region and the near infrared, by crops are the subject of this thesis.

    The aim of the study was a further investigation of

  3. Correlation between reflectance and photoluminescent properties of al-rich ZnO nano-structures

    Science.gov (United States)

    Khan, Firoz; Baek, Seong-Ho; Ahmad, Nafis; Lee, Gun Hee; Seo, Tae Hoon; Suh, Eun-kyung; Kim, Jae Hyun

    2015-05-01

    Al rich zinc oxide nano-structured films were synthesized using spin coating sol-gel technique. The films were annealed in oxygen ambient in the temperature range of 200-700 °C. The structural, optical, and photoluminescence (PL) properties of the films were studied at various annealing temperatures using X-ray diffraction spectroscopy, field emission scanning electron microscopy, photoluminescence emission spectra measurement, and Raman and UV-Vis spectroscopy. The optical band gap was found to decrease with the increase of the annealing temperature following the Gauss Amp function due to the confinement of the exciton. The PL peak intensity in the near band region (INBE) was found to increase with the increase of the annealing temperature up to 600 °C, then to decrease fast to a lower value for the annealing temperature of 700 °C due to crystalline quality. The Raman peak of E2 (low) was red shifted from 118 cm-1 to 126 cm-1 with the increase of the annealing temperature. The intensity of the second order phonon (TA+LO) at 674 cm-1 was found to decrease with the increase of the annealing temperature. The normalized values of the reflectance and the PL intensity in the NBE region were highest for the annealing temperature of 600 °C. A special correlation was found between the reflectance at λ = 1000 nm and the normalized PL intensity in the green region due to scattering due to presence of grains.

  4. Stable isotopes of Hawaiian spiders reflect substrate properties along a chronosequence

    Science.gov (United States)

    Dawson, Todd E.; Gillespie, Rosemary G.

    2018-01-01

    The Hawaiian Islands offer a unique opportunity to test how changes in the properties of an isolated ecosystem are propagated through the organisms that occur within that ecosystem. The age-structured arrangement of volcanic-derived substrates follows a regular progression over space and, by inference, time. We test how well documented successional changes in soil chemistry and associated vegetation are reflected in organisms at higher trophic levels—specifically, predatory arthropods (spiders)—across a range of functional groups. We focus on three separate spider lineages: one that builds capture webs, one that hunts actively, and one that specializes on eating other spiders. We analyze spiders from three sites across the Hawaiian chronosequence with substrate ages ranging from 200 to 20,000 years. To measure the extent to which chemical signatures of terrestrial substrates are propagated through higher trophic levels, we use standard stable isotope analyses of nitrogen and carbon, with plant leaves included as a baseline. The target taxa show the expected shift in isotope ratios of δ15N with trophic level, from plants to cursorial spiders to web-builders to spider eaters. Remarkably, organisms at all trophic levels also precisely reflect the successional changes in the soil stoichiometry of the island chronosequence, demonstrating how the biogeochemistry of the entire food web is determined by ecosystem succession of the substrates on which the organisms have evolved. PMID:29576984

  5. Surface, structural and tensile properties of proton beam irradiated zirconium

    Energy Technology Data Exchange (ETDEWEB)

    Rafique, Mohsin; Chae, San; Kim, Yong-Soo, E-mail: yongskim@hanyang.ac.kr

    2016-02-01

    This paper reports the surface, structural and tensile properties of proton beam irradiated pure zirconium (99.8%). The Zr samples were irradiated by 3.5 MeV protons using MC-50 cyclotron accelerator at different doses ranging from 1 × 10{sup 13} to 1 × 10{sup 16} protons/cm{sup 2}. Both un-irradiated and irradiated samples were characterized using Field Emission Scanning Electron Microscope (FESEM), X-ray Diffraction (XRD) and Universal Testing Machine (UTM). The average surface roughness of the specimens was determined by using Nanotech WSxM 5.0 develop 7.0 software. The FESEM results revealed the formation of bubbles, cracks and black spots on the samples’ surface at different doses whereas the XRD results indicated the presence of residual stresses in the irradiated specimens. Williamson–Hall analysis of the diffraction peaks was carried out to investigate changes in crystallite size and lattice strain in the irradiated specimens. The tensile properties such as the yield stress, ultimate tensile stress and percentage elongation exhibited a decreasing trend after irradiation in general, however, an inconsistent behavior was observed in their dependence on proton dose. The changes in tensile properties of Zr were associated with the production of radiation-induced defects including bubbles, cracks, precipitates and simultaneous recovery by the thermal energy generated with the increase of irradiation dose.

  6. Surface, structural and tensile properties of proton beam irradiated zirconium

    Science.gov (United States)

    Rafique, Mohsin; Chae, San; Kim, Yong-Soo

    2016-02-01

    This paper reports the surface, structural and tensile properties of proton beam irradiated pure zirconium (99.8%). The Zr samples were irradiated by 3.5 MeV protons using MC-50 cyclotron accelerator at different doses ranging from 1 × 1013 to 1 × 1016 protons/cm2. Both un-irradiated and irradiated samples were characterized using Field Emission Scanning Electron Microscope (FESEM), X-ray Diffraction (XRD) and Universal Testing Machine (UTM). The average surface roughness of the specimens was determined by using Nanotech WSxM 5.0 develop 7.0 software. The FESEM results revealed the formation of bubbles, cracks and black spots on the samples' surface at different doses whereas the XRD results indicated the presence of residual stresses in the irradiated specimens. Williamson-Hall analysis of the diffraction peaks was carried out to investigate changes in crystallite size and lattice strain in the irradiated specimens. The tensile properties such as the yield stress, ultimate tensile stress and percentage elongation exhibited a decreasing trend after irradiation in general, however, an inconsistent behavior was observed in their dependence on proton dose. The changes in tensile properties of Zr were associated with the production of radiation-induced defects including bubbles, cracks, precipitates and simultaneous recovery by the thermal energy generated with the increase of irradiation dose.

  7. Study on tribological properties of multi-layer surface texture on Babbitt alloys surface

    Science.gov (United States)

    Zhang, Dongya; Zhao, Feifei; Li, Yan; Li, Pengyang; Zeng, Qunfeng; Dong, Guangneng

    2016-12-01

    To improve tribological properties of Babbitt alloys, multi-layer surface texture consisted of the main grooves and secondary micro-dimples are fabricated on the Babbitt substrate through laser pulse ablation. The tribological behaviors of multi-layer surface texture are investigated using a rotating type pin-on-disc tribo-meter under variation sliding speeds, and the film pressure distributions on the textured surfaces are simulated using computational fluid dynamics (CFD) method for elucidating the possible mechanisms. The results suggest that: (i) the multi-layer surface texture can reduce friction coefficient of Babbitt alloy, which has lowest friction coefficient of 0.03, in case of the groove parameter of 300 μm width and 15% of area density; (ii) the improvement effect may be more sensitive to the groove area density and the siding speed, and the textured surface with lower area density has lower friction coefficient under high sliding speed. Based on the reasons of (i) the secondary micro-dimples on Babbitt alloy possesses a hydrophobicity surface and (ii) the CFD analysis indicates that main grooves enhancing hydrodynamic effect, thus the multi-layer surface texture is regarded as dramatically improve the lubricating properties of the Babbitt alloy.

  8. Receptor-mediated endocytosis generates nanomechanical force reflective of ligand identity and cellular property.

    Science.gov (United States)

    Zhang, Xiao; Ren, Juan; Wang, Jingren; Li, Shixie; Zou, Qingze; Gao, Nan

    2018-08-01

    Whether environmental (thermal, chemical, and nutrient) signals generate quantifiable, nanoscale, mechanophysical changes in the cellular plasma membrane has not been well elucidated. Assessment of such mechanophysical properties of plasma membrane may shed lights on fundamental cellular process. Atomic force microscopic (AFM) measurement of the mechanical properties of live cells was hampered by the difficulty in accounting for the effects of the cantilever motion and the associated hydrodynamic force on the mechanical measurement. These challenges have been addressed in our recently developed control-based AFM nanomechanical measurement protocol, which enables a fast, noninvasive, broadband measurement of the real-time changes in plasma membrane elasticity in live cells. Here we show using this newly developed AFM platform that the plasma membrane of live mammalian cells exhibits a constant and quantifiable nanomechanical property, the membrane elasticity. This mechanical property sensitively changes in response to environmental factors, such as the thermal, chemical, and growth factor stimuli. We demonstrate that different chemical inhibitors of endocytosis elicit distinct changes in plasma membrane elastic modulus reflecting their specific molecular actions on the lipid configuration or the endocytic machinery. Interestingly, two different growth factors, EGF and Wnt3a, elicited distinct elastic force profiles revealed by AFM at the plasma membrane during receptor-mediated endocytosis. By applying this platform to genetically modified cells, we uncovered a previously unknown contribution of Cdc42, a key component of the cellular trafficking network, to EGF-stimulated endocytosis at plasma membrane. Together, this nanomechanical AFM study establishes an important foundation that is expandable and adaptable for investigation of cellular membrane evolution in response to various key extracellular signals. © 2017 Wiley Periodicals, Inc.

  9. Effect of Surface Treatment on the Properties of Wool Fabric

    Science.gov (United States)

    Kan, C. W.; Yuen, C. W. M.; Chan, C. K.; Lau, M. P.

    Wool fiber is commonly used in textile industry, however, it has some technical problems which affect the quality and performance of the finished products such as felting shrinkage, handle, lustre, pilling, and dyeability. These problems may be attributed mainly in the presence of wool scales on the fiber surface. Recently, chemical treatments such as oxidation and reduction are the commonly used descaling methods in the industry. However, as a result of the pollution caused by various chemical treatments, physical treatment such as low temperature plasma (LTP) treatment has been introduced recently because it is similarly capable of achieving a comparable descaling effect. Most of the discussions on the applications of LTP treatment on wool fiber were focused on applying this technique for improving the surface wettability and shrink resistance. Meanwhile, little discussion has been made on the mechanical properties, thermal properties, and the air permeability. In this paper, wool fabric was treated with LTP treatment with the use of a non-polymerizing gas, namely oxygen. After the LTP treatment, the fabrics low-stress mechanical properties, air permeability, and thermal properties were evaluated and discussed.

  10. BIOPHYSICAL PROPERTIES OF NUCLEIC ACIDS AT SURFACES RELEVANT TO MICROARRAY PERFORMANCE.

    Science.gov (United States)

    Rao, Archana N; Grainger, David W

    2014-04-01

    Both clinical and analytical metrics produced by microarray-based assay technology have recognized problems in reproducibility, reliability and analytical sensitivity. These issues are often attributed to poor understanding and control of nucleic acid behaviors and properties at solid-liquid interfaces. Nucleic acid hybridization, central to DNA and RNA microarray formats, depends on the properties and behaviors of single strand (ss) nucleic acids (e.g., probe oligomeric DNA) bound to surfaces. ssDNA's persistence length, radius of gyration, electrostatics, conformations on different surfaces and under various assay conditions, its chain flexibility and curvature, charging effects in ionic solutions, and fluorescent labeling all influence its physical chemistry and hybridization under assay conditions. Nucleic acid (e.g., both RNA and DNA) target interactions with immobilized ssDNA strands are highly impacted by these biophysical states. Furthermore, the kinetics, thermodynamics, and enthalpic and entropic contributions to DNA hybridization reflect global probe/target structures and interaction dynamics. Here we review several biophysical issues relevant to oligomeric nucleic acid molecular behaviors at surfaces and their influences on duplex formation that influence microarray assay performance. Correlation of biophysical aspects of single and double-stranded nucleic acids with their complexes in bulk solution is common. Such analysis at surfaces is not commonly reported, despite its importance to microarray assays. We seek to provide further insight into nucleic acid-surface challenges facing microarray diagnostic formats that have hindered their clinical adoption and compromise their research quality and value as genomics tools.

  11. BIOPHYSICAL PROPERTIES OF NUCLEIC ACIDS AT SURFACES RELEVANT TO MICROARRAY PERFORMANCE

    Science.gov (United States)

    Rao, Archana N.; Grainger, David W.

    2014-01-01

    Both clinical and analytical metrics produced by microarray-based assay technology have recognized problems in reproducibility, reliability and analytical sensitivity. These issues are often attributed to poor understanding and control of nucleic acid behaviors and properties at solid-liquid interfaces. Nucleic acid hybridization, central to DNA and RNA microarray formats, depends on the properties and behaviors of single strand (ss) nucleic acids (e.g., probe oligomeric DNA) bound to surfaces. ssDNA’s persistence length, radius of gyration, electrostatics, conformations on different surfaces and under various assay conditions, its chain flexibility and curvature, charging effects in ionic solutions, and fluorescent labeling all influence its physical chemistry and hybridization under assay conditions. Nucleic acid (e.g., both RNA and DNA) target interactions with immobilized ssDNA strands are highly impacted by these biophysical states. Furthermore, the kinetics, thermodynamics, and enthalpic and entropic contributions to DNA hybridization reflect global probe/target structures and interaction dynamics. Here we review several biophysical issues relevant to oligomeric nucleic acid molecular behaviors at surfaces and their influences on duplex formation that influence microarray assay performance. Correlation of biophysical aspects of single and double-stranded nucleic acids with their complexes in bulk solution is common. Such analysis at surfaces is not commonly reported, despite its importance to microarray assays. We seek to provide further insight into nucleic acid-surface challenges facing microarray diagnostic formats that have hindered their clinical adoption and compromise their research quality and value as genomics tools. PMID:24765522

  12. Surface effects on the mechanical properties of nanoporous materials

    International Nuclear Information System (INIS)

    Xia Re; Li Xide; Feng Xiqiao; Qin Qinghua; Liu Jianlin

    2011-01-01

    Using the theory of surface elasticity, we investigate the mechanical properties of nanoporous materials. The classical theory of porous materials is modified to account for surface effects, which become increasingly important as the characteristic sizes of microstructures shrink to nanometers. First, a refined Timoshenko beam model is presented to predict the effective elastic modulus of nanoporous materials. Then the surface effects on the elastic microstructural buckling behavior of nanoporous materials are examined. In particular, nanoporous gold is taken as an example to illustrate the application of the proposed model. The results reveal that both the elastic modulus and the critical buckling behavior of nanoporous materials exhibit a distinct dependence on the characteristic sizes of microstructures, e.g. the average ligament width.

  13. Surface effects on the mechanical properties of nanoporous materials

    Energy Technology Data Exchange (ETDEWEB)

    Xia Re [School of Power and Mechanical Engineering, Wuhan University, Wuhan 430072 (China); Li Xide; Feng Xiqiao [AML, Department of Engineering Mechanics, Tsinghua University, Beijing 100084 (China); Qin Qinghua [School of Engineering, Australian National University, Canberra, ACT 0200 (Australia); Liu Jianlin, E-mail: fengxq@tsinghua.edu.cn [Department of Engineering Mechanics, China University of Petroleum, Qingdao 266555 (China)

    2011-07-01

    Using the theory of surface elasticity, we investigate the mechanical properties of nanoporous materials. The classical theory of porous materials is modified to account for surface effects, which become increasingly important as the characteristic sizes of microstructures shrink to nanometers. First, a refined Timoshenko beam model is presented to predict the effective elastic modulus of nanoporous materials. Then the surface effects on the elastic microstructural buckling behavior of nanoporous materials are examined. In particular, nanoporous gold is taken as an example to illustrate the application of the proposed model. The results reveal that both the elastic modulus and the critical buckling behavior of nanoporous materials exhibit a distinct dependence on the characteristic sizes of microstructures, e.g. the average ligament width.

  14. Exploration of a Polarized Surface Bidirectional Reflectance Model Using the Ground-Based Multiangle SpectroPolarimetric Imager

    Directory of Open Access Journals (Sweden)

    David J. Diner

    2012-12-01

    Full Text Available Accurate characterization of surface reflection is essential for retrieval of aerosols using downward-looking remote sensors. In this paper, observations from the Ground-based Multiangle SpectroPolarimetric Imager (GroundMSPI are used to evaluate a surface polarized bidirectional reflectance distribution function (PBRDF model. GroundMSPI is an eight-band spectropolarimetric camera mounted on a rotating gimbal to acquire pushbroom imagery of outdoor landscapes. The camera uses a very accurate photoelastic-modulator-based polarimetric imaging technique to acquire Stokes vector measurements in three of the instrument’s bands (470, 660, and 865 nm. A description of the instrument is presented, and observations of selected targets within a scene acquired on 6 January 2010 are analyzed. Data collected during the course of the day as the Sun moved across the sky provided a range of illumination geometries that facilitated evaluation of the surface model, which is comprised of a volumetric reflection term represented by the modified Rahman-Pinty-Verstraete function plus a specular reflection term generated by a randomly oriented array of Fresnel-reflecting microfacets. While the model is fairly successful in predicting the polarized reflection from two grass targets in the scene, it does a poorer job for two manmade targets (a parking lot and a truck roof, possibly due to their greater degree of geometric organization. Several empirical adjustments to the model are explored and lead to improved fits to the data. For all targets, the data support the notion of spectral invariance in the angular shape of the unpolarized and polarized surface reflection. As noted by others, this behavior provides valuable constraints on the aerosol retrieval problem, and highlights the importance of multiangle observations.

  15. Non-invasive identification of metal-oxalate complexes on polychrome artwork surfaces by reflection mid-infrared spectroscopy.

    Science.gov (United States)

    Monico, Letizia; Rosi, Francesca; Miliani, Costanza; Daveri, Alessia; Brunetti, Brunetto G

    2013-12-01

    In this work a reflection mid-infrared spectroscopy study of twelve metal-oxalate complexes, of interest in art conservation science as alteration compounds, was performed. Spectra of the reference materials highlighted the presence of derivative-like and/or inverted features for the fundamental vibrational modes as result of the main contribution from the surface component of the reflected light. In order to provide insights in the interpretation of theses spectral distortions, reflection spectra were compared with conventional transmission ones. The Kramers-Kronig (KK) algorithm, employed to correct for the surface reflection distortions, worked properly only for the derivative-like bands. Therefore, to pay attention to the use of this algorithm when interpreting the reflection spectra is recommended. The outcome of this investigation was exploited to discriminate among different oxalates on thirteen polychrome artworks analyzed in situ by reflection mid-infrared spectroscopy. The visualization of the νs(CO) modes (1400-1200 cm(-1)) and low wavenumber bands (below 900 cm(-1)) in the raw reflection profiles allowed Ca, Cu and Zn oxalates to be identified. Further information about the speciation of different hydration forms of calcium oxalates were obtained by using the KK transform. The work proves reflection mid-infrared spectroscopy to be a reliable and sensitive spectro-analytical method for identifying and mapping different metal-oxalate alteration compounds on the surface of artworks, thus providing conservation scientists with a non-invasive tool to obtain information on the state of conservation and causes of alteration of artworks. Copyright © 2013 Elsevier B.V. All rights reserved.

  16. Plasma immersion ion implantation of polyurethane shape memory polymer: Surface properties and protein immobilization

    Science.gov (United States)

    Cheng, Xinying; Kondyurin, Alexey; Bao, Shisan; Bilek, Marcela M. M.; Ye, Lin

    2017-09-01

    Polyurethane-type shape memory polymers (SMPU) are promising biomedical implant materials due to their ability to recover to a predetermined shape from a temporary shape induced by thermal activation close to human body temperature and their advantageous mechanical properties including large recovery strains and low recovery stresses. Plasma Immersion Ion Implantation (PIII) is a surface modification process using energetic ions that generates radicals in polymer surfaces leading to carbonisation and oxidation and the ability to covalently immobilise proteins without the need for wet chemistry. Here we show that PIII treatment of SMPU significantly enhances its bioactivity making SMPU suitable for applications in permanent implantable biomedical devices. Scanning Electron Microscopy (SEM), contact angle measurements, surface energy measurements, attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS) were used to characterise the PIII modified surface, including its after treatment aging kinetics and its capability to covalently immobilise protein directly from solution. The results show a substantial improvement in wettability and dramatic changes of surface chemical composition dependent on treatment duration, due to the generation of radicals and subsequent oxidation. The SMPU surface, PIII treated for 200s, achieved a saturated level of covalently immobilized protein indicating that a full monolayer coverage was achieved. We conclude that PIII is a promising and efficient surface modification method to enhance the biocompatibility of SMPU for use in medical applications that demand bioactivity for tissue integration and stability in vivo.

  17. Electronic and Optical Properties of Aluminum Oxide Before and After Surface Reduction by Ar+ Bombardment

    Directory of Open Access Journals (Sweden)

    D. Tahir

    2014-08-01

    Full Text Available The electronic and optical properties of a-Al2O3 after induced by 3-keV Ar+ sputtering have been studied quantitatively by use of reflection electron energy loss spectroscopy (REELS spectra. The band gap values of a-Al2O3 was determined from the onset values of the energy loss spectrum to the background level of REELS spectra as a function of time Ar+ bombardment. The bandgap changes from 8.4 eV before sputtering to 6.2 eV after 4 minutes of sputtering.The optical properties of α-Al2O3 thin films have been determined by comparing the experimental cross section obtained from reflection electron energy loss spectroscopy with the theoretical inelastic scattering cross section, deduced from the simulated energy loss function (ELF by using QUEELS-ε(k-REELS software. The peak assignments are based on ELF and compared with reported data on the electronic structure of α-Al2O3 obtained using different techniques. The results demonstrate that the electronic and optical properties before and after surface reduction will provide further understanding in the fundamental properties of α-Al2O3 which will be useful in the design, modeling and analysis of devices applications performance.

  18. Bulk Fermi surface and electronic properties of Cu0.07Bi2Se3

    Science.gov (United States)

    Martin, C.; Craciun, V.; Miller, K. H.; Uzakbaiuly, B.; Buvaev, S.; Berger, H.; Hebard, A. F.; Tanner, D. B.

    2013-05-01

    The electronic properties of Cu0.07Bi2Se3 have been investigated using Shubnikov-de Haas and optical reflectance measurements. Quantum oscillations reveal a bulk, three-dimensional Fermi surface with anisotropy kFc/kFab≈ 2 and a modest increase in free-carrier concentration and in scattering rate with respect to the undoped Bi2Se3, also confirmed by reflectivity data. The effective mass is almost identical to that of Bi2Se3. Optical conductivity reveals a strong enhancement of the bound impurity bands with Cu addition, suggesting that a significant number of Cu atoms enter the interstitial sites between Bi and Se layers or may even substitute for Bi. This conclusion is also supported by x-ray diffraction measurements, where a significant increase of microstrain was found in Cu0.07Bi2Se3, compared to Bi2Se3.

  19. Surface properties of Ti-6Al-4V alloy part I: Surface roughness and apparent surface free energy

    Energy Technology Data Exchange (ETDEWEB)

    Yan, Yingdi; Chibowski, Emil; Szcześ, Aleksandra, E-mail: aszczes@poczta.umcs.lublin.pl

    2017-01-01

    Titanium (Ti) and its alloys are the most often used implants material in dental treatment and orthopedics. Topography and wettability of its surface play important role in film formation, protein adhesion, following osseointegration and even duration of inserted implant. In this paper, we prepared Ti-6Al-4V alloy samples using different smoothing and polishing materials as well the air plasma treatment, on which contact angles of water, formamide and diiodomethane were measured. Then the apparent surface free energy was calculated using four different approaches (CAH, LWAB, O-W and Neumann's Equation of State). From LWAB approach the components of surface free energy were obtained, which shed more light on the wetting properties of samples surface. The surface roughness of the prepared samples was investigated with the help of optical profilometer and AFM. It was interesting whether the surface roughness affects the apparent surface free energy. It was found that both polar interactions the electron donor parameter of the energy and the work of water adhesion increased with decreasing roughness of the surfaces. Moreover, short time plasma treatment (1 min) caused decrease in the surface hydrophilic character, while longer time (10 min) treatment caused significant increase in the polar interactions and the work of water adhesion. Although Ti-6Al-4V alloy has been investigated many times, to our knowledge, so far no paper has been published in which surface roughness and changes in the surface free energy of the alloy were compared in the quantitative way in such large extent. This novel approach deliver better knowledge about the surface properties of differently smoothed and polished samples which may be helpful to facilitate cell adhesion, proliferation and mineralization. Therefore the results obtained present also potentially practical meaning. - Highlights: • Surface of five Ti-6Al-4V alloy samples were smoothed and polished successively. • The

  20. Constraining the surface properties of effective Skyrme interactions

    Science.gov (United States)

    Jodon, R.; Bender, M.; Bennaceur, K.; Meyer, J.

    2016-08-01

    Background: Deformation energy surfaces map how the total binding energy of a nuclear system depends on the geometrical properties of intrinsic configurations, thereby providing a powerful tool to interpret nuclear spectroscopy and large-amplitude collective-motion phenomena such as fission. The global behavior of the deformation energy is known to be directly connected to the surface properties of the effective interaction used for its calculation. Purpose: The precise control of surface properties during the parameter adjustment of an effective interaction is key to obtain a reliable and predictive description of nuclear properties. The most relevant indicator is the surface-energy coefficient asurf. There are several possibilities for its definition and estimation, which are not fully equivalent and require a computational effort that can differ by orders of magnitude. The purpose of this study is threefold: first, to identify a scheme for the determination of asurf that offers the best compromise between robustness, precision, and numerical efficiency; second, to analyze the correlation between values for asurf and the characteristic energies of the fission barrier of 240Pu; and third, to lay out an efficient and robust procedure for how the deformation properties of the Skyrme energy density functional (EDF) can be constrained during the parameter fit. Methods: There are several frequently used possibilities to define and calculate the surface energy coefficient asurf of effective interactions built for the purpose of self-consistent mean-field calculations. The most direct access is provided by the model system of semi-infinite nuclear matter, but asurf can also be extracted from the systematics of binding energies of finite nuclei. Calculations can be carried out either self-consistently [Hartree-Fock (HF)], which incorporates quantal shell effects, or in one of the semiclassical extended Thomas-Fermi (ETF) or modified Thomas-Fermi (MTF) approximations. The

  1. dsRNA binding properties of RDE-4 and TRBP reflect their distinct roles in RNAi.

    Science.gov (United States)

    Parker, Greg S; Maity, Tuhin Subhra; Bass, Brenda L

    2008-12-26

    Double-stranded RNA (dsRNA)-binding proteins facilitate Dicer functions in RNA interference. Caenorhabditis elegans RDE-4 facilitates cleavage of long dsRNA to small interfering RNA (siRNA), while human trans-activation response RNA-binding protein (TRBP) functions downstream to pass siRNA to the RNA-induced silencing complex. We show that these distinct in vivo roles are reflected in in vitro binding properties. RDE-4 preferentially binds long dsRNA, while TRBP binds siRNA with an affinity that is independent of dsRNA length. These properties are mechanistically based on the fact that RDE-4 binds cooperatively, via contributions from multiple domains, while TRBP binds noncooperatively. Our studies offer a paradigm for how dsRNA-binding proteins, which are not sequence specific, discern dsRNA length. Additionally, analyses of the ability of RDE-4 deletion constructs and RDE-4/TRBP chimeras to reconstitute Dicer activity suggest RDE-4 promotes activity using its dsRNA-binding motif 2 to bind dsRNA, its linker region to interact with Dicer, and its C-terminus for Dicer activation.

  2. Surface chemistry and bonding configuration of ultrananocrystalline diamond surfaces and their effects on nanotribological properties

    International Nuclear Information System (INIS)

    Sumant, A. V.; Grierson, D. S.; Carpick, R. W.; Gerbi, J. E.; Carlisle, J. A.; Auciello, O.

    2007-01-01

    We present a comprehensive study of surface composition and nanotribology for ultrananocrystalline diamond (UNCD) surfaces, including the influence of film nucleation on these properties. We describe a methodology to characterize the underside of the films as revealed by sacrificial etching of the underlying substrate. This enables the study of the morphology and composition resulting from the nucleation and initial growth of the films, as well as the characterization of nanotribological properties which are relevant for applications including micro-/nanoelectromechanical systems. We study the surface chemistry, bonding configuration, and nanotribological properties of both the topside and the underside of the film with synchrotron-based x-ray absorption near-edge structure spectroscopy to identify the bonding state of the carbon atoms, x-ray photoelectron spectroscopy to determine the surface chemical composition, Auger electron spectroscopy to further verify the composition and bonding configuration, and quantitative atomic force microscopy to study the nanoscale topography and nanotribological properties. The films were grown on SiO 2 after mechanically polishing the surface with detonation synthesized nanodiamond powder, followed by ultrasonication in a methanol solution containing additional nanodiamond powder. The sp 2 fraction, morphology, and chemistry of the as-etched underside are distinct from the topside, exhibiting a higher sp 2 fraction, some oxidized carbon, and a smoother morphology. The nanoscale single-asperity work of adhesion between a diamond nanotip and the as-etched UNCD underside is far lower than for a silicon-silicon interface (59.2±2 vs 826±186 mJ/m 2 , respectively). Exposure to atomic hydrogen dramatically reduces nanoscale adhesion to 10.2±0.4 mJ/m 2 , at the level of van der Waals' interactions and consistent with recent ab initio calculations. Friction is substantially reduced as well, demonstrating a direct link between the

  3. Land Surface Reflectance Retrieval from Hyperspectral Data Collected by an Unmanned Aerial Vehicle over the Baotou Test Site

    Science.gov (United States)

    Duan, Si-Bo; Li, Zhao-Liang; Tang, Bo-Hui; Wu, Hua; Ma, Lingling; Zhao, Enyu; Li, Chuanrong

    2013-01-01

    To evaluate the in-flight performance of a new hyperspectral sensor onboard an unmanned aerial vehicle (UAV-HYPER), a comprehensive field campaign was conducted over the Baotou test site in China on 3 September 2011. Several portable reference reflectance targets were deployed across the test site. The radiometric performance of the UAV-HYPER sensor was assessed in terms of signal-to-noise ratio (SNR) and the calibration accuracy. The SNR of the different bands of the UAV-HYPER sensor was estimated to be between approximately 5 and 120 over the homogeneous targets, and the linear response of the apparent reflectance ranged from approximately 0.05 to 0.45. The uniform and non-uniform Lambertian land surface reflectance was retrieved and validated using in situ measurements, with root mean square error (RMSE) of approximately 0.01–0.07 and relative RMSE of approximately 5%–12%. There were small discrepancies between the retrieved uniform and non-uniform Lambertian land surface reflectance over the homogeneous targets and under low aerosol optical depth (AOD) conditions (AOD = 0.18). However, these discrepancies must be taken into account when adjacent pixels had large land surface reflectance contrast and under high AOD conditions (e.g. AOD = 1.0). PMID:23785513

  4. High quality broadband spatial reflections of slow Rayleigh surface acoustic waves modulated by a graded grooved surface

    KAUST Repository

    Xu, Yanlong; Peng, Pai

    2015-01-01

    . The graded grooved surface is structured by drilling one dimensional array of graded grooves with increased depths on a flat surface. We investigate SAW dispersion relations, wave field distribution at several typical SAW wavelengths, and time evolution of a

  5. Synchrotron Radiation Total Reflection X-ray Fluorescence Spectroscopy for Microcontamination Analysis on Silicon Wafer Surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Takaura, Norikatsu

    1997-10-01

    As dimensions in state-of-the-art CMOS devices shrink to less than 0.1 pm, even low levels of impurities on wafer surfaces can cause device degradation. Conventionally, metal contamination on wafer surfaces is measured using Total Reflection X-Ray Fluorescence Spectroscopy (TXRF). However, commercially available TXRF systems do not have the necessary sensitivity for measuring the lower levels of contamination required to develop new CMOS technologies. In an attempt to improve the sensitivity of TXRF, this research investigates Synchrotron Radiation TXRF (SR TXRF). The advantages of SR TXRF over conventional TXRF are higher incident photon flux, energy tunability, and linear polarization. We made use of these advantages to develop an optimized SR TXRF system at the Stanford Synchrotron Radiation Laboratory (SSRL). The results of measurements show that the Minimum Detection Limits (MDLs) of SR TXRF for 3-d transition metals are typically at a level-of 3x10{sup 8} atoms/cm{sup 2}, which is better than conventional TXRF by about a factor of 20. However, to use our SR TXRF system for practical applications, it was necessary to modify a commercially available Si (Li) detector which generates parasitic fluorescence signals. With the modified detector, we could achieve true MDLs of 3x10{sup 8} atoms/cm{sup 2} for 3-d transition metals. In addition, the analysis of Al on Si wafers is described. Al analysis is difficult because strong Si signals overlap the Al signals. In this work, the Si signals are greatly reduced by tuning the incident beam energy below the Si K edge. The results of our measurements show that the sensitivity for Al is limited by x-ray Raman scattering. Furthermore, we show the results of theoretical modeling of SR TXRF backgrounds consisting of the bremsstrahlung generated by photoelectrons, Compton scattering, and Raman scattering. To model these backgrounds, we extended conventional theoretical models by taking into account several aspects particular

  6. Optical performance of random anti-reflection structured surfaces (rARSS) on spherical lenses

    Science.gov (United States)

    Taylor, Courtney D.

    Random anti-reflection structured surfaces (rARSS) have been reported to improve transmittance of optical-grade fused silica planar substrates to values greater than 99%. These textures are fabricated directly on the substrates using reactive-ion/inductively-coupled plasma etching (RIE/ICP) techniques, and often result in transmitted spectra with no measurable interference effects (fringes) for a wide range of wavelengths. The RIE/ICP processes used in the fabrication process to etch the rARSS is anisotropic and thus well suited for planar components. The improvement in spectral transmission has been found to be independent of optical incidence angles for values from 0° to +/-30°. Qualifying and quantifying the rARSS performance on curved substrates, such as convex lenses, is required to optimize the fabrication of the desired AR effect on optical-power elements. In this work, rARSS was fabricated on fused silica plano-convex (PCX) and plano-concave (PCV) lenses using a planar-substrate optimized RIE process to maximize optical transmission in the range from 500 to 1100 nm. An additional set of lenses were etched in a non-optimized ICP process to provide additional comparisons. Results are presented from optical transmission and beam propagation tests (optimized lenses only) of rARSS lenses for both TE and TM incident polarizations at a wavelength of 633 nm and over a 70° full field of view in both singlet and doublet configurations. These results suggest optimization of the fabrication process is not required, mainly due to the wide angle-of-incidence AR tolerance performance of the rARSS lenses. Non-optimized recipe lenses showed low transmission enhancement, and confirmed the need to optimized etch recipes prior to process transfer of PCX/PCV lenses. Beam propagation tests indicated no major beam degradation through the optimized lens elements. Scanning electron microscopy (SEM) images confirmed different structure between optimized and non-optimized samples

  7. Influence of surface roughness on the friction property of textured surface

    Directory of Open Access Journals (Sweden)

    Yuankai Zhou

    2015-02-01

    Full Text Available In contrast with dimple textures, surface roughness is a texture at the micro-scale, essentially which will influence the load-bearing capacity of lubricant film. The numerical simulation was carried out to investigate the influence of surface roughness on friction property of textured surface. The lubricant film pressure was obtained using the method of computational fluid dynamics according to geometric model of round dimple, and the renormalization-group k–ε turbulent model was adopted in the computation. The numerical simulation results suggest that there is an optimum dimensionless surface roughness, and near this value, the maximum load-bearing capacity can be achieved. The load-bearing capacity is determined by the surface texture, the surface roughness, and the interaction between them. To get information of friction coefficient, the experiments were conducted. This experiment was used to evaluate the simulation. The experimental results show that for the frequency of 4 and 6 Hz, friction coefficient decreases at first and then increases with decreasing surface roughness, which indicates that there exists the optimum region of surface roughness leading to the best friction reduction effect, and it becomes larger when area fractions increase from 2% to 10%. The experimental results agree well with the simulation results.

  8. Changes in surface properties caused by ion implantation

    International Nuclear Information System (INIS)

    Iwaki, Masaya

    1987-01-01

    This report outlines various aspects of ion implantation. Major features of ion implantation are described first, focusing on the structure of ion implantation equipment and some experimental results of ion implantation into semiconductors. Distribution of components in ion-implantated layers is then discussed. The two major features of ion implantation in relation to the distribution of implanted ions are: (1) high controllability of addition of ions to a surface layer and (2) formation of a large number of lattice defects in a short period of time. Application of ion implantation to metallic materials is expected to permit the following: (1) formation of a semi-stable alloy surface layer by metallic ion implantation, (2) formation of a semi-stable ceramic surface layer or buried layer by non-metallic ion implantation, and (3) formation of a buried layer by combined implementation of a different metallic ion and non-metallic ion. Ion implantation in carbon materials, polymers and ceramics is discussed next. The last part of the report is dedicated to macroscopic properties of an ion-implanted layer, centering on surface modification, formation of a conductive surface layer, and tribology. (Nogami, K.) 60 refs

  9. Influence of short chain organic acids and bases on the wetting properties and surface energy of submicrometer ceramic powders.

    Science.gov (United States)

    Neirinck, Bram; Soccol, Dimitri; Fransaer, Jan; Van der Biest, Omer; Vleugels, Jef

    2010-08-15

    The effect of short chained organic acids and bases on the surface energy and wetting properties of submicrometer alumina powder was assessed. The surface chemistry of treated powders was determined by means of Diffuse Reflectance Infrared Fourier Transform spectroscopy and compared to untreated powder. The wetting of powders was measured using a modified Washburn method, based on the use of precompacted powder samples. The geometric factor needed to calculate the contact angle was derived from measurements of the porous properties of the powder compacts. Contact angle measurements with several probe liquids before and after modification allowed a theoretical estimation of the surface energy based on the surface tension component theory. Trends in the surface energy components were linked to observations in infrared spectra. The results showed that the hydrophobic character of the precompacted powder depends on both the chain length and polar group of the modifying agent. Copyright 2010 Elsevier Inc. All rights reserved.

  10. Simulation of reflectance from white-anodised aluminium surfaces using polyurethane–TiO2 composite coatings

    DEFF Research Database (Denmark)

    Gudla, Visweswara Chakravarthy; Johansen, Villads Egede; Ambat, Rajan

    2015-01-01

    of anodised surfaces. PU matrix was selected for its matching refractive-index (n = 1.7) with anodic alumina layer. Three different TiO2 particle size distributions were dispersed in PU and spin coated onto bright high-gloss and matte caustic-etched aluminium substrates. The reflectance spectra of coated...

  11. Model for the ultrasound reflection from micro-beads and cells distributed in layers on a uniform surface

    Energy Technology Data Exchange (ETDEWEB)

    Couture, O; Cherin, E; Foster, F S [Imaging Research, Sunnybrook Health Sciences Centre/University of Toronto, Toronto (Canada)

    2007-07-21

    A model predicting the reflection of ultrasound from multiple layers of small scattering spheres is developed. Predictions of the reflection coefficient, which takes into account the interferences between the different sphere layers, are compared to measurements performed in the 10-80 MHz and 15-35 MHz frequency range with layers of glass beads and spherical acute myeloid leukemia (AML) cells, respectively. For both types of scatterers, the reflection coefficient increases as a function of their density on the surface for less than three superimposed layers, at which point it saturates at 0.38 for glass beads and 0.02 for AML cells. Above three layers, oscillations of the reflection coefficient due to constructive or destructive interference between layers are observed experimentally and are accurately predicted by the model. The use of such a model could lead to a better understanding of the structures observed in layered tissue images.

  12. Magnetic nanoparticles: surface effects and properties related to biomedicine applications.

    Science.gov (United States)

    Issa, Bashar; Obaidat, Ihab M; Albiss, Borhan A; Haik, Yousef

    2013-10-25

    Due to finite size effects, such as the high surface-to-volume ratio and different crystal structures, magnetic nanoparticles are found to exhibit interesting and considerably different magnetic properties than those found in their corresponding bulk materials. These nanoparticles can be synthesized in several ways (e.g., chemical and physical) with controllable sizes enabling their comparison to biological organisms from cells (10-100 μm), viruses, genes, down to proteins (3-50 nm). The optimization of the nanoparticles' size, size distribution, agglomeration, coating, and shapes along with their unique magnetic properties prompted the application of nanoparticles of this type in diverse fields. Biomedicine is one of these fields where intensive research is currently being conducted. In this review, we will discuss the magnetic properties of nanoparticles which are directly related to their applications in biomedicine. We will focus mainly on surface effects and ferrite nanoparticles, and on one diagnostic application of magnetic nanoparticles as magnetic resonance imaging contrast agents.

  13. Investigation of CVD graphene topography and surface electrical properties

    International Nuclear Information System (INIS)

    Wang, Rui; Pearce, Ruth; Gallop, John; Patel, Trupti; Pollard, Andrew; Hao, Ling; Zhao, Fang; Jackman, Richard; Klein, Norbert; Zurutuza, Amaia

    2016-01-01

    Combining scanning probe microscopy techniques to characterize samples of graphene, a selfsupporting, single atomic layer hexagonal lattice of carbon atoms, provides far more information than a single technique can. Here we focus on graphene grown by chemical vapour deposition (CVD), grown by passing carbon containing gas over heated copper, which catalyses single atomic layer growth of graphene on its surface. To be useful for applications the graphene must be transferred onto other substrates. Following transfer it is important to characterize the CVD graphene. We combine atomic force microscopy (AFM) and scanning Kelvin probe microscopy (SKPM) to reveal several properties of the transferred film. AFM alone provides topographic information, showing ‘wrinkles’ where the transfer provided incomplete substrate attachment. SKPM measures the surface potential indicating regions with different electronic properties for example graphene layer number. By combining AFM and SKPM local defects and impurities can also be observed. Finally, Raman spectroscopy can confirm the structural properties of the graphene films, such as the number of layers and level of disorder, by observing the peaks present. We report example data on a number of CVD samples from different sources. (paper)

  14. Application of the surface reflection seismic method to shallow coal exploration in the plains of Alberta

    Energy Technology Data Exchange (ETDEWEB)

    Lyatsky, H.V.; Lawton, D.C. (University of Victoria, Victoria, BC (Canada). Dept. of Physics and Astronomy)

    1988-12-01

    A study was done to make a quantitative interpretation of reflection seismic data from the Highvale-Whitewood shallow coal deposit in central Alberta. Results showed that the data is useful in demonstrating coal thickness and stratigraphy as well as structural formation. Reflection character is affected by nature of the strata surrounding the coal deposit. 22 refs., 1 tab., 23 figs.

  15. Determination of acoustic properties of thin polymer films utilizing the frequency dependence of the reflection coefficient of ultrasound.

    Science.gov (United States)

    Tohmyoh, Hironori; Sakamoto, Yuhei

    2015-11-01

    This paper reports on a technique to measure the acoustic properties of a thin polymer film utilizing the frequency dependence of the reflection coefficient of ultrasound reflected back from a system comprising a reflection plate, the film, and a material that covers the film. The frequency components of the echo reflected from the back of the plate, where the film is attached, take their minimum values at the resonant frequency, and from these frequency characteristics, the acoustic impedance, sound velocity, and the density of the film can be determined. We applied this technique to characterize an ion exchange membrane, which has high water absorbability, and successfully determined the acoustic properties of the membrane without getting it wet.

  16. Tribological properties of nanostripe surface structures-a design concept for improving tribological properties

    International Nuclear Information System (INIS)

    Miyake, K; Nakano, M; Korenaga, A; Mano, H; Ando, Y

    2010-01-01

    The tribological properties of nanostripe surface structures were investigated using a pin-on-plate tribometer in order to propose a design concept for improving the tribological properties. The authors used four kinds of nanostripe structures consisting of different combinations of materials (Fe-Au, C-SiC, Al-Al 2 O 3 and Al-Pt) fabricated by a process they had previously proposed. The frictional properties of the nanostripe structures depended on the materials that constituted the nanostripes. When the sliding direction in friction tests was parallel to the microgrooves, nanostripe structures remained on all surfaces even after friction tests. Based on the friction test results, the authors considered a design concept for nanostripe structures in tribological applications.

  17. Near surface mechanical properties of optical single crystals and surface response to deterministic microgrinding

    Science.gov (United States)

    Randi, Joseph A., III

    2005-12-01

    This thesis makes use of microindentation, nanoindentation and nanoscratching methods to better understand the mechanical properties of single crystalline silicon, calcium fluoride, and magnesium fluoride. These properties are measured and are used to predict the material's response to material removal, specifically by grinding and polishing, which is a combination of elastic, plastic and fracture processes. The hardness anisotropy during Knoop microindentation, hardness from nanoindentation, and scratch morphology from nanoscratching are reported. This information is related to the surface microroughness from grinding. We show that mechanical property relationships that predict the surface roughness from lapping and deterministic microgrinding of optical glasses are applicable to single crystals. We show the range of hardness from some of the more common crystallographic faces. Magnesium fluoride, having a tetragonal structure, has 2-fold hardness anisotropy. Nanoindentation, as expected provides higher hardness than microindentation, but anisotropy is not observed. Nanoscratching provides the scratch profile during loading, after the load has been removed, and the coefficient of friction during the loading. Ductile and brittle mode scratching is present with brittle mode cracking being orientation specific. Subsurface damage (SSD) measurements are made using a novel process known as the MRF technique. Magnetorheological finishing is used to polish spots into the ground surface where SSD can be viewed. SSD is measured using an optical microscope and knowledge of the spot profile. This technique is calibrated with a previous technique and implemented to accurately measure SSD in single crystals. The data collected are compared to the surface microroughness of the ground surface, resulting in an upper bound relationship. The results indicate that SSD is always less than 1.4 times the peak-to-valley surface microroughness for single crystals regardless of the

  18. Nonlinear mean field theory for nuclear matter and surface properties

    International Nuclear Information System (INIS)

    Boguta, J.; Moszkowski, S.A.

    1983-01-01

    Nuclear matter properties are studied in a nonlinear relativistic mean field theory. We determine the parameters of the model from bulk properties of symmetric nuclear matter and a reasonable value of the effective mass. In this work, we stress the nonrelativistic limit of the theory which is essentially equivalent to a Skyrme hamiltonian, and we show that most of the results can be obtained, to a good approximation, analytically. The strength of the required parameters is determined from the binding energy and density of nuclear matter and the effective nucleon mass. For realistic values of the parameters, the nonrelativistic approximation turns out to be quite satisfactory. Using reasonable values of the parameters, we can account for other key properties of nuclei, such as the spin-orbit coupling, surface energy, and diffuseness of the nuclear surface. Also the energy dependence of the nucleon-nucleus optical model is accounted for reasonably well except near the Fermi surface. It is found, in agreement with empirical results, that the Landau parameter F 0 is quite small in normal nuclear matter. Both density dependence and momentum dependence of the NN interaction, but especially the former, are important for nuclear saturation. The required scalar and vector coupling constants agree fairly well with those obtained from analyses of NN scattering phase shifts with one-boson-exchange models. The mean field theory provides a semiquantitative justification for the weak Skyrme interaction in odd states. The strength of the required nonlinear term is roughly consistent with that derived using a new version of the chiral mean field theory in which the vector mass as well as the nucleon mass is generated by the sigma-field. (orig.)

  19. Microstructure and surface mechanical properties of pulse electrodeposited nickel

    Energy Technology Data Exchange (ETDEWEB)

    Ul-Hamid, A., E-mail: anwar@kfupm.edu.sa [Center of Research Excellence in Corrosion (CoRE-C), Research Institute, King Fahd University of Petroleum and Minerals, P.O. Box 1073, Dhahran 31261 (Saudi Arabia); Dafalla, H.; Quddus, A.; Saricimen, H.; Al-Hadhrami, L.M. [Center of Research Excellence in Corrosion (CoRE-C), Research Institute, King Fahd University of Petroleum and Minerals, P.O. Box 1073, Dhahran 31261 (Saudi Arabia)

    2011-09-01

    The surface of carbon steel was modified by electrochemical deposition of Ni in a standard Watt's bath using dc and pulse plating electrodeposition. The aim was to compare the microstructure and surface mechanical properties of the deposit obtained by both techniques. Materials characterization was conducted using field emission scanning electron microscope fitted with scanning transmission electron detector, atomic force microscope and X-ray diffractometer. Nanoindentation hardness, elastic modulus, adhesion, coefficients of friction and wear rates were determined for both dc and pulse electrodeposits. Experimental results indicate that pulse electrodeposition produced finer Ni grains compared to dc plating. Size of Ni grains increased with deposition. Both dc and pulse deposition resulted in grain growth in preferred (2 0 0) orientation. However, presence of Ni (1 1 1) grains increased in deposits produced by pulse deposition. Pulse plated Ni exhibited higher hardness, creep and coefficient of friction and lower modulus of elasticity compared to dc plated Ni.

  20. Effect of nanofillers' size on surface properties after toothbrush abrasion.

    Science.gov (United States)

    Cavalcante, Larissa M; Masouras, Konstantinos; Watts, David C; Pimenta, Luiz A; Silikas, Nick

    2009-02-01

    To investigate the effect of filler-particle size of experimental and commercial resin composites, undergoing toothbrush abrasion, on three surface properties: surface roughness (SR), surface gloss (G) and color stability (CS). Four model (Ivoclar/Vivadent) and one commercial resin composite (Tokuyama) with varying filler-size from 100-1000 nm were examined. Six discs (10 mm x 2 mm) from each product were prepared and mechanically polished. The samples were then submitted to 20,000 brushing strokes in a toothbrush abrasion machine. SR parameters (Ra, Rt and RSm), G, and CS were measured before and after toothbrush abrasion. Changes in SR and G were analyzed by 2-way ANOVA, with Bonferroni post hoc test. CS values were submitted to one-way ANOVA and Bonferroni post hoc test (alpha=0.05). Initial G values ranged between 73-87 gloss units (GU) and were reduced after toothbrush abrasion to a range of 8-64 GU. Toothbrush abrasion resulted in significant modifications in SR and G amongst the materials tested, attributed to filler sizes. There was statistically significant difference in color (delta E* ranged from 0.38-0.88). Filler size did not affect color stability. Toothbrush abrasion resulted in rougher and matte surfaces for all materials tested. Although the individual differences in surface roughness among filler sizes were not always significant, the correlation showed a trend that larger filler sizes resulted in higher surface roughness after abrasion for the SR parameters Ra and Rt (r = 0.95; r = 0.93, respectively). RSm showed an increase after toothbrush abrasion for all resin composites, however no significant correlation was detected (r = 0.21).There was a significant correlation between G and Ra ratios (r = - 0.95).

  1. Modification of polyvinyl alcohol surface properties by ion implantation

    Energy Technology Data Exchange (ETDEWEB)

    Pukhova, I.V., E-mail: ivpuhova@mail.ru [National Research Tomsk State University, 36 Lenin Ave, Tomsk 634050 (Russian Federation); Institute of High Current Electronics, 2/3 Akademichesky Ave, Tomsk 634055 (Russian Federation); Kurzina, I.A. [National Research Tomsk State University, 36 Lenin Ave, Tomsk 634050 (Russian Federation); Savkin, K.P. [Institute of High Current Electronics, 2/3 Akademichesky Ave, Tomsk 634055 (Russian Federation); Laput, O.A. [National Research Tomsk Polytechnic University, 30 Lenin Ave, Tomsk 634050 (Russian Federation); Oks, E.M. [Institute of High Current Electronics, 2/3 Akademichesky Ave, Tomsk 634055 (Russian Federation)

    2017-05-15

    We describe our investigations of the surface physicochemical properties of polyvinyl alcohol modified by silver, argon and carbon ion implantation to doses of 1 × 10{sup 14}, 1 × 10{sup 15} and 1 × 10{sup 16} ion/cm{sup 2} and energies of 20 keV (for C and Ar) and 40 keV (for Ag). Infrared spectroscopy (IRS) indicates that destructive processes accompanied by chemical bond (−C=O) generation are induced by implantation, and X-ray photoelectron spectroscopy (XPS) analysis indicates that the implanted silver is in a metallic Ag3d state without stable chemical bond formation with polymer chains. Ion implantation is found to affect the surface energy: the polar component increases while the dispersion part decreases with increasing implantation dose. Surface roughness is greater after ion implantation and the hydrophobicity increases with increasing dose, for all ion species. We find that ion implantation of Ag, Ar and C leads to a reduction in the polymer microhardness by a factor of five, while the surface electrical resistivity declines modestly.

  2. Properties of bare strange stars associated with surface electric fields

    International Nuclear Information System (INIS)

    Picanco Negreiros, Rodrigo; Mishustin, Igor N.; Schramm, Stefan; Weber, Fridolin

    2010-01-01

    In this paper we investigate the electrodynamic surface properties of bare strange quark stars. The surfaces of such objects are characterized by the formation of ultrahigh electric surface fields which might be as high as ∼10 19 V/cm. These fields result from the formation of electric dipole layers at the stellar surfaces. We calculate the increase in gravitational mass associated with the energy stored in the electric dipole field, which turns out to be only significant if the star possesses a sufficiently strong net electric charge distribution. In the second part of the paper, we explore the intriguing possibility of what happens when the electron layer (sphere) rotates with respect to the stellar strange matter body. We find that in this event magnetic fields can be generated which, for moderate effective rotational frequencies between the electron layer and the stellar body, agree with the magnetic fields inferred for several central compact objects. These objects could thus be comfortably interpreted as strange stars whose electron atmospheres rotate at frequencies that are moderately different (∼10 Hz) from the rotational frequencies of the strange star itself.

  3. Engineered Surface Properties of Porous Tungsten from Cryogenic Machining

    Science.gov (United States)

    Schoop, Julius Malte

    Porous tungsten is used to manufacture dispenser cathodes due to it refractory properties. Surface porosity is critical to functional performance of dispenser cathodes because it allows for an impregnated ceramic compound to migrate to the emitting surface, lowering its work function. Likewise, surface roughness is important because it is necessary to ensure uniform wetting of the molten impregnate during high temperature service. Current industry practice to achieve surface roughness and surface porosity requirements involves the use of a plastic infiltrant during machining. After machining, the infiltrant is baked and the cathode pellet is impregnated. In this context, cryogenic machining is investigated as a substitutionary process for the current plastic infiltration process. Along with significant reductions in cycle time and resource use, surface quality of cryogenically machined un-infiltrated (as-sintered) porous tungsten has been shown to significantly outperform dry machining. The present study is focused on examining the relationship between machining parameters and cooling condition on the as-machined surface integrity of porous tungsten. The effects of cryogenic pre-cooling, rake angle, cutting speed, depth of cut and feed are all taken into consideration with respect to machining-induced surface morphology. Cermet and Polycrystalline diamond (PCD) cutting tools are used to develop high performance cryogenic machining of porous tungsten. Dry and pre-heated machining were investigated as a means to allow for ductile mode machining, yet severe tool-wear and undesirable smearing limited the feasibility of these approaches. By using modified PCD cutting tools, high speed machining of porous tungsten at cutting speeds up to 400 m/min is achieved for the first time. Beyond a critical speed, brittle fracture and built-up edge are eliminated as the result of a brittle to ductile transition. A model of critical chip thickness ( hc ) effects based on cutting

  4. Surface orientation effects on bending properties of surgical mesh are independent of tensile properties.

    Science.gov (United States)

    Simon, David D; Andrews, Sharon M; Robinson-Zeigler, Rebecca; Valdes, Thelma; Woods, Terry O

    2018-02-01

    Current mechanical testing of surgical mesh focuses primarily on tensile properties even though implanted devices are not subjected to pure tensile loads. Our objective was to determine the flexural (bending) properties of surgical mesh and determine if they correlate with mesh tensile properties. The flexural rigidity values of 11 different surgical mesh designs were determined along three textile directions (machine, cross-machine, and 45° to machine; n = 5 for each) using ASTM D1388-14 while tracking surface orientation. Tensile testing was also performed on the same specimens using ASTM D882-12. Linear regressions were performed to compare mesh flexural rigidity to mesh thickness, areal mass density, filament diameter, ultimate tensile strength, and maximum extension. Of 33 mesh specimen groups, 30 had significant differences in flexural rigidity values when comparing surface orientations (top and bottom). Flexural rigidity and mesh tensile properties also varied with textile direction (machine and cross-machine). There was no strong correlation between the flexural and tensile properties, with mesh thickness having the best overall correlation with flexural rigidity. Currently, surface orientation is not indicated on marketed surgical mesh, and a single mesh may behave differently depending on the direction of loading. The lack of correlation between flexural stiffness and tensile properties indicates the need to examine mesh bending stiffness to provide a more comprehensive understanding of surgical mesh mechanical behaviors. Further investigation is needed to determine if these flexural properties result in the surgical mesh behaving mechanically different depending on implantation direction. © 2017 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 106B: 854-862, 2018. © 2017 Wiley Periodicals, Inc.

  5. Determining the influential depth for surface reflectance of sediment by BRDF measurements.

    Science.gov (United States)

    Zhang, H; Voss, K; Reid, R

    2003-10-20

    We measure the Bi-directional reflectance distribution function (BRDF) of ooid sand layers with three particle size distributions (0.5-1mm, 0.25-0.5mm and 0.125-0.25mm) and layer thicknesses on a reflecting mirror to determine the influential depth in the optical region at wavelengths of 658 nm (red), 570 nm (green) and 457 nm (blue). The hemispherical reflectance (albedo) was used as an indicator of BRDF changes between different layers. Measurements are carried out on both dry and water wetted grains. The results indicate that for both dry and wet and all size distributions, the influential depth is at most 2mm.

  6. Electronic and optical properties of Fe, Pd, and Ti studied by reflection electron energy loss spectroscopy

    International Nuclear Information System (INIS)

    Tahir, Dahlang; Kraaer, Jens; Tougaard, Sven

    2014-01-01

    We have studied the electronic and optical properties of Fe, Pd, and Ti by reflection electron energy-loss spectroscopy (REELS). REELS spectra recorded for primary energies in the range from 300 eV to 10 keV were corrected for multiple inelastically scattered electrons to determine the effective inelastic-scattering cross section. The dielectric functions and optical properties were determined by comparing the experimental inelastic-electron scattering cross section with a simulated cross section calculated within the semi-classical dielectric response model in which the only input is Im(−1/ε) by using the QUEELS-ε(k,ω)-REELS software package. The complex dielectric functions ε(k,ω), in the 0–100 eV energy range, for Fe, Pd, and Ti were determined from the derived Im(−1/ε) by Kramers-Kronig transformation and then the refractive index n and extinction coefficient k. The validity of the applied model was previously tested and found to give consistent results when applied to REELS spectra at energies between 300 and 1000 eV taken at widely different experimental geometries. In the present paper, we provide, for the first time, a further test on its validity and find that the model also gives consistent results when applied to REELS spectra in the full range of primary electron energies from 300 eV to 10000 eV. This gives confidence in the validity of the applied method.

  7. Variability of the reflectance coefficient of skylight from the ocean surface and its implications to ocean color.

    Science.gov (United States)

    Gilerson, Alexander; Carrizo, Carlos; Foster, Robert; Harmel, Tristan

    2018-04-16

    The value and spectral dependence of the reflectance coefficient (ρ) of skylight from wind-roughened ocean surfaces is critical for determining accurate water leaving radiance and remote sensing reflectances from shipborne, AERONET-Ocean Color and satellite observations. Using a vector radiative transfer code, spectra of the reflectance coefficient and corresponding radiances near the ocean surface and at the top of the atmosphere (TOA) are simulated for a broad range of parameters including flat and windy ocean surfaces with wind speeds up to 15 m/s, aerosol optical thicknesses of 0-1 at 440nm, wavelengths of 400-900 nm, and variable Sun and viewing zenith angles. Results revealed a profound impact of the aerosol load and type on the spectral values of ρ. Such impacts, not included yet in standard processing, may produce significant inaccuracies in the reflectance spectra retrieved from above-water radiometry and satellite observations. Implications for satellite cal/val activities as well as potential changes in measurement and data processing schemes are discussed.

  8. Electronic properties of semiconductor surfaces and metal/semiconductor interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Tallarida, M.

    2005-05-15

    This thesis reports investigations of the electronic properties of a semiconductor surface (silicon carbide), a reactive metal/semiconductor interface (manganese/silicon) and a non-reactive metal/semiconductor interface (aluminum-magnesium alloy/silicon). The (2 x 1) reconstruction of the 6H-SiC(0001) surface has been obtained by cleaving the sample along the (0001) direction. This reconstruction has not been observed up to now for this compound, and has been compared with those of similar elemental semiconductors of the fourth group of the periodic table. This comparison has been carried out by making use of photoemission spectroscopy, analyzing the core level shifts of both Si 2p and C 1s core levels in terms of charge transfer between atoms of both elements and in different chemical environments. From this comparison, a difference between the reconstruction on the Si-terminated and the C-terminated surface was established, due to the ionic nature of the Si-C bond. The growth of manganese films on Si(111) in the 1-5 ML thickness range has been studied by means of LEED, STM and photoemission spectroscopy. By the complementary use of these surface science techniques, two different phases have been observed for two thickness regimes (<1 ML and >1 ML), which exhibit a different electronic character. The two reconstructions, the (1 x 1)-phase and the ({radical}3 x {radical}3)R30 -phase, are due to silicide formation, as observed in core level spectroscopy. The growth proceeds via island formation in the monolayer regime, while the thicker films show flat layers interrupted by deep holes. On the basis of STM investigations, this growth mode has been attributed to strain due to lattice mismatch between the substrate and the silicide. Co-deposition of Al and Mg onto a Si(111) substrate at low temperature (100K) resulted in the formation of thin alloy films. By varying the relative content of both elements, the thin films exhibited different electronic properties

  9. X-ray reflectivity study of thermal capillary waves on liquid surfaces

    International Nuclear Information System (INIS)

    Ocko, B.M.; Wu, X.Z.; Sirota, E.B.; Sinha, S.K.; Deutsch, M.

    1994-01-01

    X-ray reflectivity measurements have been carried out at the liquid/vapor interface of normal alkanes. The reflectivities over a large temperature range of different chain lengths (C20 and C36) provide a critical test of the various capillary wave models. Our data are most consistent with the hybrid model which allows for a molecular size dependent cutoff q max for the capillary waves and an intrinsic interface width σ 0

  10. Theoretical study on the electronic and optical properties of bulk and surface (001) InxGa1-xAs

    Science.gov (United States)

    Liu, XueFei; Ding, Zhao; Luo, ZiJiang; Zhou, Xun; Wei, JieMin; Wang, Yi; Guo, Xiang; Lang, QiZhi

    2018-05-01

    The optical properties of surface and bulk InxGa1-xAs materials are compared systematically first time in this paper. The band structures, density of states and optical properties including dielectric function, reflectivity, absorption coefficient, loss function and refractive index of bulk and surface InxGa1-xAs materials are investigated by first-principles based on plane-wave pseudo-potentials method within the LDA approximation. The results agree well with the available theoretical and experimental studies and indicate that the electronic and optical properties of bulk and surface InxGa1-xAs materials are much different, and the results show that the considered optical properties of the both materials vary with increasing indium composition in an opposite way. The calculations show that the optical properties of surface In0.75Ga0.25As material are unexpected to be far from the other two indium compositions of surface InxGa1-xAs materials while the optical properties of bulk InxGa1-xAs materials vary with increasing indium composition in an expected regular way.

  11. Morphology and phase structures of CW laser-induced oxide layers on iron surface with evolving reflectivity and colors

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Taotao, E-mail: wutaotao@nint.ac.cn; Wang, Lijun; Wei, Chenghua; Zhou, Menglian; He, Minbo; Wu, Lixiong

    2016-11-30

    Highlights: • Firstly, iron samples with different color features were obtained by continuous wave laser irradiation depending on progressive durations. The real-time reflectivity and temperature of samples were measured. The color and the reflectivity evolution were related. They were both caused by the forming oxide films. • Secondly, laser-induced oxidation process of iron was studied by microscope, X-ray diffraction and Raman spectrum. The first formed magnetite made the surface reflectivity decline rapidly and caused the “positive feedback” effect because of molecular absorption. The later formed hematite oscillated the reflectivity by interference effect. • Lastly, the laser-induced oxide films were thin, orientated and badly crystallized. The Wagner oxidation theory was incapable of describing the non-isothermal and early stage oxidation process. So we emphasized that a precise oxidation model depending on the experiment and the optical constants of the laser-induced oxides must be studied. - Abstract: Laser-induced oxidation will change the laser reflectivity and color features of metal surface. Both changes can be theoretically calculated based on the oxidation kinetics and the optical constants of oxides. For the purpose of calculation, the laser-induced oxidation process of pure polycrystalline iron was studied. Samples with various color features were obtained by continuous wave Nd:YAG fiber laser (1.06 μm) irradiation depending on progressive durations in the intensity of 1.90 W/cm{sup 2}. The real-time reflectivity and temperature were measured with integral sphere and thermocouples. The irradiated surface morphology and phase structures were characterized by microscope, X-ray diffraction and Raman spectrum. It was found that the first formed magnetite made the surface reflectivity decline rapidly and caused the “positive feedback” effect because of molecular absorption. The later formed hematite oscillated the reflectivity by

  12. Electrical properties of Titan's surface from Cassini RADAR scatterometer measurements

    Science.gov (United States)

    Wye, Lauren C.; Zebker, Howard A.; Ostro, Steven J.; West, Richard D.; Gim, Yonggyu; Lorenz, Ralph D.; The Cassini Radar Team

    2007-06-01

    albedo feature Shangri-La is best fit by a Hagfors model with a dielectric constant close to 2.4 and an rms slope near 9.5°. From the modeled backscatter curves, we find the average radar albedo in the same linear (SL) polarization to be near 0.34. We constrain the total-power albedo in order to compare the measurements with available groundbased radar results, which are typically obtained in both senses of circular polarization. We estimate an upper limit of 0.4 on the total-power albedo, a value that is significantly higher than the 0.21 total albedo value measured at 13 cm [Campbell, D., Black, G., Carter, L., Ostro, S., 2003. Science 302, 431-434]. This is consistent with a surface that has more small-scale structure and is thus more reflective at 2-cm than 13-cm. We compare results across overlapping observations and observe that the reduction and analysis are repeatable and consistent. We also confirm the strong correlations between radar and near-infrared images.

  13. Surface ferromagnetism and superconducting properties of nanocrystalline niobium nitride

    International Nuclear Information System (INIS)

    Shipra, R.; Kumar, Nitesh; Sundaresan, A.

    2013-01-01

    Nanocrystalline δ-NbN x samples have been synthesized by reacting NbCl 5 and urea at three different temperatures. A comparison of their structural, magnetic, transport and thermal properties is reported in the present study. The size of the particles and their agglomeration extent increase with increasing reaction temperature. The sample prepared at 900 °C showed the highest superconducting transition temperature (T c ) of 16.2 K with a transition width, ∼1.8 K, as obtained from the resistivity measurement on cold-pressed bars. Above T c , magnetization measurements revealed the presence of surface ferromagnetism which coexists with superconductivity below T c . Heat capacity measurements confirm superconductivity with strong electron–phonon coupling constant. The sample prepared at 800 °C shows a lower T c (10 K) while that prepared at 700 °C exhibit no superconductivity down to the lowest temperature (3 K) measured. - Highlights: ► Synthesis of δ-NbN nanoparticles by urea nitridation of NbCl 5 . ► Superconducting transition temperature (T c ) is 16.2 K. ► Superconductivity and surface ferromagnetism coexist in the nanoparticles. ► Effect of size and agglomeration on the physical properties of nanoparticles

  14. Yttrium ion implantation on the surface properties of magnesium

    International Nuclear Information System (INIS)

    Wang, X.M.; Zeng, X.Q.; Wu, G.S.; Yao, S.S.

    2006-01-01

    Owing to their excellent physical and mechanical properties, magnesium and its alloys are receiving more attention. However, their application has been limited to the high reactivity and the poor corrosion resistance. The aim of the study was to investigate the beneficial effects of ion-implanted yttrium using a MEVVA ion implanter on the surface properties of pure magnesium. Isothermal oxidation tests in pure O 2 at 673 and 773 K up to 90 min indicated that the oxidation resistance of magnesium had been significantly improved. Surface morphology of the oxide scale was analyzed using scanning electron microscope (SEM). Auger electron spectroscopy (AES) and X-ray diffraction (XRD) analyses indicated that the implanted layer was mainly composed of MgO and Y 2 O 3 , and the implanted layer with a duplex structure could decrease the inward diffusion of oxygen and reduce the outward diffusion of Mg 2+ , which led to improving the oxidation resistance of magnesium. Potentiodynamic polarization curves were used to evaluate the corrosion resistance of the implanted magnesium. The results show yttrium implantation could enhance the corrosion resistance of implanted magnesium compared with that of pure magnesium

  15. Properties and cleanability of new and traditional agricultural surface materials

    Directory of Open Access Journals (Sweden)

    J. MÄÄTTÄ

    2008-12-01

    Full Text Available The aim of the present study was to evaluate new and traditional surface materials for use in cattle barns. The evaluated concrete materials had different compositions and included different additives and coatings. Contact angle meter, optical profilometry and scanning electron microscopy SEM were used for characterization of surface properties. Radiochemical methods and a biochemical adenosine triphosphate ATP method were used to determine cleanability. A specific methodological aim was to examine the correlations between these determination methods. A statistically significant difference was observed between contact angles of non-coated concretes, coated concretes and joint materials. In general, coatings smoothened surfaces and the joint materials were the roughest surfaces, as illustrated by profilometry and SEM. On the basis of the radiochemical determination methods, coatings improved the cleanability of concrete. An epoxy joint material was cleaned efficiently from the oil model soil and from the labelled feed soil when compared to the two cement-based joint materials. According to the results of the biochemical ATP method the manure test soil was cleaned better from a concrete including inorganic sealant than from the other materials examined. The cleanability results of oil model soil used in the radiochemical method correlated with the results of the test feed soil used in the biochemical ATP method. Both determination methods of cleanability appeared to be suitable for examining the cleanability of surfaces soiled with agricultural soils. Only the radiochemical determination gives detailed quantitative results, but it can be used only in laboratory studies. The results of this laboratory study will be used for selecting materials for a pilot study in a cattle barn.;

  16. Kaguya observations of the lunar wake in the terrestrial foreshock: Surface potential change by bow-shock reflected ions

    Science.gov (United States)

    Nishino, Masaki N.; Harada, Yuki; Saito, Yoshifumi; Tsunakawa, Hideo; Takahashi, Futoshi; Yokota, Shoichiro; Matsushima, Masaki; Shibuya, Hidetoshi; Shimizu, Hisayoshi

    2017-09-01

    There forms a tenuous region called the wake behind the Moon in the solar wind, and plasma entry/refilling into the wake is a fundamental problem of the lunar plasma science. High-energy ions and electrons in the foreshock of the Earth's magnetosphere were detected at the lunar surface in the Apollo era, but their effects on the lunar night-side environment have never been studied. Here we show the first observation of bow-shock reflected protons by Kaguya (SELENE) spacecraft in orbit around the Moon, confirming that solar wind plasma reflected at the terrestrial bow shock can easily access the deepest lunar wake when the Moon stays in the foreshock (We name this mechanism 'type-3 entry'). In a continuous type-3 event, low-energy electron beams from the lunar night-side surface are not obvious even though the spacecraft location is magnetically connected to the lunar surface. On the other hand, in an intermittent type-3 entry event, the kinetic energy of upward-going field-aligned electron beams decreases from ∼ 80 eV to ∼ 20 eV or electron beams disappear as the bow-shock reflected ions come accompanied by enhanced downward electrons. According to theoretical treatment based on electric current balance at the lunar surface including secondary electron emission by incident electron and ion impact, we deduce that incident ions would be accompanied by a few to several times higher flux of an incident electron flux, which well fits observed downward fluxes. We conclude that impact by the bow-shock reflected ions and electrons raises the electrostatic potential of the lunar night-side surface.

  17. Coherent reflection from surface gravity water waves during reciprocal acoustic transmissions.

    Science.gov (United States)

    Badiey, Mohsen; Song, Aijun; Smith, Kevin B

    2012-10-01

    During a recent experiment in Kauai, Hawaii, reciprocal transmissions were conducted between two acoustic transceivers mounted on the seafloor at a depth of 100 m. The passage of moving surface wave crests was shown to generate focused and intense coherent acoustic returns, which had increasing or decreasing delay depending on the direction of propagation relative to the direction of surface wave crests. It is shown that a rough surface two-dimensional parabolic equation model with an evolving sea surface can produce qualitative agreement with data for the dynamic surface returns.

  18. Stretched membrane heliostats: design and structural analysis of reflectance module and support of a heliostats of 9 m. diaform and 60 m''3 of reflectance surface

    International Nuclear Information System (INIS)

    Figarola Torres, J. M.

    1993-01-01

    After having designed and built at CIEMAT a first prototype of a Btretched membrane heliostats of 3 m. diameter, the design and the structural analysis of the different components included in the reflectance module and support of another heliostats, this one of 9 m. diameter and 60 m2. of reflectance surface, are shown In this report. This last heliostats will be mounted on a pedestal and its driving device at the Solar Platform of Almeria. In order to optimize design and performance, the structural analysis of its basic components has been analyzed with the finite elements program ANSYS. The following elements have been subject to analysis: the membrane and their ring supports, stretching system and the structural support. A similar scheme to the one applied to the previous prototype has been used on the focus control system. That includes a linear transducer, a variable frequency and a fan. Finally it has to be pointed out that substantial improvements have been achieved with respect to the first prototype concerning design and cost. (Author) 5 refs

  19. Surface Estimation, Variable Selection, and the Nonparametric Oracle Property.

    Science.gov (United States)

    Storlie, Curtis B; Bondell, Howard D; Reich, Brian J; Zhang, Hao Helen

    2011-04-01

    Variable selection for multivariate nonparametric regression is an important, yet challenging, problem due, in part, to the infinite dimensionality of the function space. An ideal selection procedure should be automatic, stable, easy to use, and have desirable asymptotic properties. In particular, we define a selection procedure to be nonparametric oracle (np-oracle) if it consistently selects the correct subset of predictors and at the same time estimates the smooth surface at the optimal nonparametric rate, as the sample size goes to infinity. In this paper, we propose a model selection procedure for nonparametric models, and explore the conditions under which the new method enjoys the aforementioned properties. Developed in the framework of smoothing spline ANOVA, our estimator is obtained via solving a regularization problem with a novel adaptive penalty on the sum of functional component norms. Theoretical properties of the new estimator are established. Additionally, numerous simulated and real examples further demonstrate that the new approach substantially outperforms other existing methods in the finite sample setting.

  20. Surface properties, solubility and dissolution kinetics of bamboo phytoliths

    Science.gov (United States)

    Fraysse, Fabrice; Pokrovsky, Oleg S.; Schott, Jacques; Meunier, Jean-Dominique

    2006-04-01

    Although phytoliths, constituted mainly by micrometric opal, exhibit an important control on silicon cycle in superficial continental environments, their thermodynamic properties and reactivity in aqueous solution are still poorly known. In this work, we determined the solubility and dissolution rates of bamboo phytoliths collected in the Réunion Island and characterized their surface properties via electrophoretic measurements and potentiometric titrations in a wide range of pH. The solubility product of "soil" phytoliths ( pKsp0=2.74 at 25 °C) is equal to that of vitreous silica and is 17 times higher than that of quartz. Similarly, the enthalpy of phytoliths dissolution reaction (ΔHr25-80°C=10.85kJ/mol) is close to that of amorphous silica but is significantly lower than the enthalpy of quartz dissolution. Electrophoretic measurements yield isoelectric point pH IEP = 1.2 ± 0.1 and 2.5 ± 0.2 for "soil" (native) and "heated" (450 °C heating to remove organic matter) phytoliths, respectively. Surface acid-base titrations allowed generation of a 2-p K surface complexation model. Phytoliths dissolution rates, measured in mixed-flow reactors at far from equilibrium conditions at 2 ⩽ pH ⩽ 12, were found to be intermediate between those of quartz and vitreous silica. The dissolution rate dependence on pH was modeled within the concept of surface coordination theory using the equation: R=k1·{>SiOH2+}n+k2·{>SiOH0}+k3·{>SiO-}m, where {> i} stands for the concentration of the surface species present at the SiO 2-H 2O interface, ki are the rate constants of the three parallel reactions and n and m represent the order of the proton- and hydroxy-promoted reactions, respectively. It follows from the results of this study that phytoliths dissolution rates exhibit a minimum at pH ˜ 3. This can explain their good preservation in the acidic soil horizons of Réunion Island. In terms of silicon biogeochemical cycle, phytoliths represent a large buffering reservoir

  1. Analysis of bacteria on steel surfaces using reflectance micro-Fourier transform infrared spectroscopy.

    Science.gov (United States)

    Ojeda, Jesús J; Romero-González, María E; Banwart, Steven A

    2009-08-01

    Reflectance micro-Fourier transform infrared (FT-IR) analysis has been applied to characterize biofilm formation of Aquabacterium commune, a common microorganism present on drinking water distribution systems, onto the increasingly popular pipe material stainless steel EN1.4307. The applicability of the reflectance micro-FT-IR technique for analyzing the bacterial functional groups is discussed, and the results are compared to spectra obtained using more conventional FT-IR techniques: transmission micro-FT-IR, attenuated transmitted reflectance (ATR), and KBr pellets. The differences between the infrared spectra of wet and dried bacteria, as well as free versus attached bacteria, are also discussed. The spectra obtained using reflectance micro-FT-IR spectroscopy were comparable to those obtained using other FT-IR techniques. The absence of sample preparation, the potential to analyze intact samples, and the ability to characterize opaque and thick samples without the need to transfer the bacterial samples to an infrared transparent medium or produce a pure culture were the main advantages of reflectance micro-FT-IR spectroscopy.

  2. Using Neural Networks to Improve the Performance of Radiative Transfer Modeling Used for Geometry Dependent Surface Lambertian-Equivalent Reflectivity Calculations

    Science.gov (United States)

    Fasnacht, Zachary; Qin, Wenhan; Haffner, David P.; Loyola, Diego; Joiner, Joanna; Krotkov, Nickolay; Vasilkov, Alexander; Spurr, Robert

    2017-01-01

    Surface Lambertian-equivalent reflectivity (LER) is important for trace gas retrievals in the direct calculation of cloud fractions and indirect calculation of the air mass factor. Current trace gas retrievals use climatological surface LER's. Surface properties that impact the bidirectional reflectance distribution function (BRDF) as well as varying satellite viewing geometry can be important for retrieval of trace gases. Geometry Dependent LER (GLER) captures these effects with its calculation of sun normalized radiances (I/F) and can be used in current LER algorithms (Vasilkov et al. 2016). Pixel by pixel radiative transfer calculations are computationally expensive for large datasets. Modern satellite missions such as the Tropospheric Monitoring Instrument (TROPOMI) produce very large datasets as they take measurements at much higher spatial and spectral resolutions. Look up table (LUT) interpolation improves the speed of radiative transfer calculations but complexity increases for non-linear functions. Neural networks perform fast calculations and can accurately predict both non-linear and linear functions with little effort.

  3. Optical properties of WO3 thin films using surface plasmon resonance technique

    International Nuclear Information System (INIS)

    Paliwal, Ayushi; Sharma, Anjali; Gupta, Vinay; Tomar, Monika

    2014-01-01

    Indigenously assembled surface plasmon resonance (SPR) technique has been exploited to study the thickness dependent dielectric properties of WO 3 thin films. WO 3 thin films (80 nm to 200 nm) have been deposited onto gold (Au) coated glass prism by sputtering technique. The structural, optical properties and surface morphology of the deposited WO 3 thin films were studied using X-ray diffraction, UV-visible spectrophotometer, Raman spectroscopy, and Scanning electron microscopy (SEM). XRD analysis shows that all the deposited WO 3 thin films are exhibiting preferred (020) orientation and Raman data indicates that the films possess single phase monoclinic structure. SEM images reveal the variation in grain size with increase in thickness. The SPR reflectance curves of the WO 3 /Au/prism structure were utilized to estimate the dielectric properties of WO 3 thin films at optical frequency (λ = 633 nm). As the thickness of WO 3 thin film increases from 80 nm to 200 nm, the dielectric constant is seen to be decreasing from 5.76 to 3.42, while the dielectric loss reduces from 0.098 to 0.01. The estimated value of refractive index of WO 3 film is in agreement to that obtained from UV-visible spectroscopy studies. The strong dispersion in refractive index is observed with wavelength of incident laser light

  4. Optical properties of WO{sub 3} thin films using surface plasmon resonance technique

    Energy Technology Data Exchange (ETDEWEB)

    Paliwal, Ayushi; Sharma, Anjali; Gupta, Vinay, E-mail: drguptavinay@gmail.com, E-mail: vgupta@physics.du.ac.in [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Tomar, Monika [Department of Physics, Miranda House, University of Delhi, Delhi 110007 (India)

    2014-01-28

    Indigenously assembled surface plasmon resonance (SPR) technique has been exploited to study the thickness dependent dielectric properties of WO{sub 3} thin films. WO{sub 3} thin films (80 nm to 200 nm) have been deposited onto gold (Au) coated glass prism by sputtering technique. The structural, optical properties and surface morphology of the deposited WO{sub 3} thin films were studied using X-ray diffraction, UV-visible spectrophotometer, Raman spectroscopy, and Scanning electron microscopy (SEM). XRD analysis shows that all the deposited WO{sub 3} thin films are exhibiting preferred (020) orientation and Raman data indicates that the films possess single phase monoclinic structure. SEM images reveal the variation in grain size with increase in thickness. The SPR reflectance curves of the WO{sub 3}/Au/prism structure were utilized to estimate the dielectric properties of WO{sub 3} thin films at optical frequency (λ = 633 nm). As the thickness of WO{sub 3} thin film increases from 80 nm to 200 nm, the dielectric constant is seen to be decreasing from 5.76 to 3.42, while the dielectric loss reduces from 0.098 to 0.01. The estimated value of refractive index of WO{sub 3} film is in agreement to that obtained from UV-visible spectroscopy studies. The strong dispersion in refractive index is observed with wavelength of incident laser light.

  5. In situ anodization of aluminum surfaces studied by x-ray reflectivity and electrochemical impedance spectroscopy

    International Nuclear Information System (INIS)

    Bertram, F.; Evertsson, J.; Messing, M. E.; Mikkelsen, A.; Lundgren, E.; Zhang, F.; Pan, J.; Carlà, F.; Nilsson, J.-O.

    2014-01-01

    We present results from the anodization of an aluminum single crystal [Al(111)] and an aluminum alloy [Al 6060] studied by in situ x-ray reflectivity, in situ electrochemical impedance spectroscopy and ex situ scanning electron microscopy. For both samples, a linear increase of oxide film thickness with increasing anodization voltage was found. However, the slope is much higher in the single crystal case, and the break-up of the oxide film grown on the alloy occurs at a lower anodization potential than on the single crystal. The reasons for these observations are discussed as are the measured differences observed for x-ray reflectivity and electrochemical impedance spectroscopy.

  6. Formation of plasmonic silver nanoparticles using rapid thermal annealing at low temperature and study in reflectance reduction of Si surface

    Science.gov (United States)

    Barman, Bidyut; Dhasmana, Hrishikesh; Verma, Abhishek; Kumar, Amit; Pratap Chaudhary, Shiv; Jain, V. K.

    2017-09-01

    This work presents studies of plasmonic silver nanoparticles (AgNPs) formation at low temperatures (200 °C-300 °C) onto Si surface by sputtering followed with rapid thermal processing (RTP) for different time durations(5-30 min). The study reveals that 20 min RTP at all temperatures show minimum average size of AgNPs (60.42 nm) with corresponding reduction in reflectance of Si surface from 40.12% to mere 1.15% only in wavelength region 300-800 nm for RTP at 200 °C. A detailed supporting growth mechanism is also discussed. This low temperature technique can be helpful in achieving efficiency improvement in solar cells via reflectance reduction with additional features such as reproducibility, minimal time and very good adhesion without damaging underlying layers device parameters.

  7. Effect of surface plasmon polaritons on the sensitivity of refractive index measurement using total internal reflection method

    International Nuclear Information System (INIS)

    Roshan Entezar, S.

    2015-01-01

    The phase difference between two p-polarized and s-polarized plane waves which are reflected under total internal reflection from the base of a prism with a thin metal coating is studied. Typically such a quantity can be used to measure the refractive index of a test material using the total internal reflection method. It is shown that due to the excitation of surface plasmon polaritons at the interface between the tested dielectric material and the thin metal layer, the p-polarized light experiences a large phase shift which enlarges the phase difference between the p-polarized and the s-polarized waves. As a result, the sensitivity of refractive index measurement increases and the error in determining the refractive index decreases. - Highlights: • Phase difference of totally internally reflected p and s polarized beams is studied. • Excitation of the surface wave increases the phase shift of the p-polarized light. • The sensitivity of refractive index measurement increases by using a coated prism. • The error in determining the refractive index decreases using the coated prism

  8. High-efficiency dual-modes vortex beam generator with polarization-dependent transmission and reflection properties.

    Science.gov (United States)

    Tang, Shiwei; Cai, Tong; Wang, Guang-Ming; Liang, Jian-Gang; Li, Xike; Yu, Jiancheng

    2018-04-23

    Vortex beam is believed to be an effective way to extend communication capacity, but available efforts suffer from the issues of complex configurations, fixed operation mode as well as low efficiency. Here, we propose a general strategy to design dual-modes vortex beam generator by using metasurfaces with polarization-dependent transmission and reflection properties. Combining the focusing and vortex functionalities, we design/fabricate a type of compact dual-modes vortex beam generator operating at both reflection/transmission sides of the system. Experimental results demonstrate that the designed metadevice can switch freely and independently between the reflective vortex with topological charge m 1  = 2 and transmissive vortex with m 2  = 1. Moreover, the metadevice exhibits very high efficiencies of 91% and 85% for the reflective and transmissive case respectively. Our findings open a door for multifunctional metadevices with high performances, which indicate wide applications in modern integration-optics and wireless communication systems.

  9. Micromechanical and surface adhesive properties of single saccharomyces cerevisiae cells

    Science.gov (United States)

    Farzi, Bahman; Cetinkaya, Cetin

    2017-09-01

    The adhesion and mechanical properties of a biological cell (e.g. cell membrane elasticity and adhesiveness) are often strong indicators for the state of its health. Many existing techniques for determining mechanical properties of cells require direct physical contact with a single cell or a group of cells. Physical contact with the cell can trigger complex mechanotransduction mechanisms, leading to cellular responses, and consequently interfering with measurement accuracy. In the current work, based on ultrasonic excitation and interferometric (optical) motion detection, a non-contact method for characterizing the adhesion and mechanical properties of single cells is presented. It is experimentally demonstrated that the rocking (rigid body) motion and internal vibrational resonance frequencies of a single saccharomyces cerevisiae (SC) (baker’s yeast) cell can be acquired with the current approach, and the Young’s modulus and surface tension of the cell membrane as well as surface adhesion energy can be extracted from the values of these acquired resonance frequencies. The detected resonance frequency ranges for single SC cells include a rocking (rigid body) frequency of 330  ±  70 kHz and two breathing resonance frequencies of 1.53  ±  0.12 and 2.02  ±  0.31 MHz. Based on these values, the average work-of-adhesion of SC cells on a silicon substrate in aqueous medium is extracted, for the first time, as WASC-Si=16.2+/- 3.8 mJ {{m}-2} . Similarly, the surface tension and the Young’s modulus of the SC cell wall are predicted as {{σ }SC}=0.16+/- 0.02 N {{m}-1} and {{E}SC}= 9.20  ±  2.80 MPa, respectively. These results are compared to those reported in the literature by utilizing various methods, and good agreements are found. The current approach eliminates the measurement inaccuracies associated with the physical contact. Exciting and detecting cell dynamics at micro-second time-scales is significantly faster than the

  10. Relation between seasonally detrended shortwave infrared reflectance data and land surface moisture in semi-arid Sahel

    DEFF Research Database (Denmark)

    Olsen, Jørgen Lundegaard; Ceccato, Pietro; Proud, Simon Richard

    2013-01-01

    in vegetation moisture status, and is compared to detrended time series of the Normalized Difference Vegetation Index (NDVI). It was found that when plant available water is low, the SIWSI anomalies increase over time, while the NDVI anomalies decrease over time, but less systematically. Therefore SIWSI may......In the Sudano-Sahelian areas of Africa droughts can have serious impacts on natural resources, and therefore land surface moisture is an important factor. Insufficient conventional sites for monitoring land surface moisture make the use of Earth Observation data for this purpose a key issue...... Second Generation (MSG) satellite. We focused on responses in surface reflectance to soil- and surface moisture for bare soil and early to mid- growing season. A method for implementing detrended time series of the Shortwave Infrared Water Stress Index (SIWSI) is examined for detecting variations...

  11. Determination of solid surface composition by the X-ray fluorescence method under total external reflection with angular scanning

    International Nuclear Information System (INIS)

    Krasnolutskij, V.P.

    2000-01-01

    Possibilities of determination of composition of surface layers by X-ray fluorescence analysis under total reflection of incident radiation with angular scanning of a target are investigated. For the case of the GaAs target it is shown that the sensibility of this method is sufficient for a control of element composition in layer of thickness 1 nm. A simple method for solution of inverse task of analysis of a two component medium is considered [ru

  12. Simulation of reflecting surface deviations of centimeter-band parabolic space radiotelescope (SRT) with the large-size mirror

    Science.gov (United States)

    Kotik, A.; Usyukin, V.; Vinogradov, I.; Arkhipov, M.

    2017-11-01

    he realization of astrophysical researches requires the development of high-sensitive centimeterband parabolic space radiotelescopes (SRT) with the large-size mirrors. Constructively such SRT with the mirror size more than 10 m can be realized as deployable rigid structures. Mesh-structures of such size do not provide the reflector reflecting surface accuracy which is necessary for the centimeter band observations. Now such telescope with the 10 m diameter mirror is developed in Russia in the frame of "SPECTR - R" program. External dimensions of the telescope is more than the size of existing thermo-vacuum chambers used to prove SRT reflecting surface accuracy parameters under the action of space environment factors. That's why the numerical simulation turns out to be the basis required to accept the taken designs. Such modeling should be based on experimental working of the basic constructive materials and elements of the future reflector. In the article computational modeling of reflecting surface deviations of a centimeter-band of a large-sized deployable space reflector at a stage of his orbital functioning is considered. The analysis of the factors that determines the deviations - both determined (temperatures fields) and not-determined (telescope manufacturing and installation faults; the deformations caused by features of composite materials behavior in space) is carried out. The finite-element model and complex of methods are developed. They allow to carry out computational modeling of reflecting surface deviations caused by influence of all factors and to take into account the deviations correction by space vehicle orientation system. The results of modeling for two modes of functioning (orientation at the Sun) SRT are presented.

  13. European spruce bark beetle (Ips typographus, L.) green attack affects foliar reflectance and biochemical properties

    Science.gov (United States)

    Abdullah, Haidi; Darvishzadeh, Roshanak; Skidmore, Andrew K.; Groen, Thomas A.; Heurich, Marco

    2018-02-01

    The European spruce bark beetle Ips typographus, L. (hereafter bark beetle), causes major economic loss to the forest industry in Europe, especially in Norway Spruce (Picea abies). To minimise economic loss and preclude a mass outbreak, early detection of bark beetle infestation (so-called ;green attack; stage - a period at which trees are yet to show visual signs of infestation stress) is, therefore, a crucial step in the management of Norway spruce stands. It is expected that a bark beetle infestation at the green attack stage affects a tree's physiological and chemical status. However, the concurrent effect on key foliar biochemical such as foliar nitrogen and chlorophyll as well as spectral responses are not well documented in the literature. Therefore, in this study, the early detection of bark beetle green attacks is investigated by examining foliar biochemical and spectral properties (400-2000 nm). We also assessed whether bark beetle infestation affects the estimation accuracy of foliar biochemicals. An extensive field survey was conducted in the Bavarian Forest National Park (BFNP), Germany, in the early summer of 2015 to collect leaf samples from 120 healthy and green attacked trees. The spectra of the leaf samples were measured using an ASD FieldSpec3 equipped with an integrating sphere. Significant differences (p < 0.05) between healthy and infested needle samples were found in the mean reflectance spectra, with the most pronounced differences being observed in the NIR and SWIR regions between 730 and 1370 nm. Furthermore, significant differences (p < 0.05) were found in the biochemical compositions (chlorophyll and nitrogen concentration) of healthy versus green attacked samples. Our results further demonstrate that the estimation accuracy of foliar chlorophyll and nitrogen concentrations, utilising partial least square regression model, was lower for the infested compared to the healthy trees. We show that early stage of infestation reduces not only

  14. Intercomparison of 30+ years of AVHRR and Landsat-5 TM Surface Reflectance using Multiple Pseudo-Invariant Calibration Sites

    Science.gov (United States)

    Santamaría-Artigas, A. E.; Franch, B.; Vermote, E.; Roger, J. C.; Justice, C. O.

    2017-12-01

    The 30+ years daily surface reflectance long term data record (LTDR) from the Advanced Very High Resolution Radiometer (AVHRR) is a valuable source of information for long-term studies of the Earth surface. This LTDR was generated by combining observations from multiple AVHRR sensors aboard different NOAA satellites starting from the early 1980s, and due to the lack of on-board calibration its quality should be evaluated. Previous studies have used observations from the Moderate Resolution Imaging Spectroradiometer (MODIS) over pseudo-invariant calibration sites (PICS) as a calibrated reference to assess the performance of AVHRR products. However, this limits the evaluation to the period after MODIS launch. In this work, the AVHRR surface reflectance LTDR was evaluated against Landsat-5 Thematic Mapper (TM) data using observations from 4 well known pseudo-invariant calibration sites (i.e. Sonoran, Saharan, Sudan1, and Libya4) over an extended time period (1984-2011). For the intercomparison, AVHRR and TM observations of each site were extracted and averaged over a 20 km x 20 km area and aggregated to monthly mean values. In order to account for the spectral differences between sensors, Hyperion hyperspectral data from the Sonoran and Libya4 sites were convolved with sensor-specific relative spectral responses, and used to compute spectral band adjustment factors (SBAFs). Results of the intercomparison are reported in terms of the root mean square difference (RMSD) and determination coefficient (r2). In general, there is good agreement between the surface reflectance products from both sensors. The overall RMSD and r2 for all the sites and AVHRR/TM combinations were 0.03 and 0.85 for the red band, and 0.04 and 0.81 for the near-infrared band. These results show the strong performance of the AVHRR surface reflectance LTDR through all of the considered period. Thus, remarking its usefulness and value for long term Earth studies. Figure 1 shows the red (filled markers

  15. Improvement of carbon fibre surface properties using electron beam irradiation

    International Nuclear Information System (INIS)

    Eddy Segura Pino; Luci Diva Brocardo Machado; Claudia Giovedi

    2006-01-01

    Carbon fiber-reinforced advance composites have been used for structural applications, mainly due to their mechanical properties, and additional features such as high strength-to-weight ratio, stiffness-to-weight ratio, corrosion resistance and wear properties. The main factor for a good mechanical performance of carbon fiber-reinforced composite is the interfacial interaction between the components that are fiber and polymeric matrix. The greatest challenge is to improve adhesion between components having elasticity modulus which differ by orders of magnitude and furthermore they are immiscible in each other. Another important factor is the sizing material on the carbon fiber, which protects the carbon fiber filaments and must be compatible with the matrix material in order to improve the adhesion process. The interaction of ionizing radiation from electron beam can induce in the irradiated material the formation of very active centers and free radicals. Further evolution of these active species can significantly modify structure and properties not only in the irradiated polymeric matrix but also on the fiber surface. So that, fiber and matrix play an important role in the production of chemical bonds, which promote better adhesion between both materials improving the composite mechanical performance. The aim of this work was to improve the surface properties of the carbon fiber surface using ionizing radiation from an electron beam in order to obtain improvement of the adhesion properties in the resulted composite. Commercial carbon fiber roving of high tensile strength with 12 000 filaments named 12 k, and sizing material of epoxy resin modified by ester groups was studied. EB irradiation has been carried out at the Institute for Nuclear and Energy Research (IPEN) facilities using a 1.5 MeV 37.5 kW Dynamitron electron accelerator model JOB-188. Rovings of carbon fibers with 1.78 g cm -3 density and 0.13 mm thickness were irradiated with 0.555 MeV, 6.43 mA and

  16. Reflection of sound from finite-size plane and curved surfaces

    DEFF Research Database (Denmark)

    Rindel, Jens Holger

    2005-01-01

    of a reflector array can improve if the size of the panels is decreased. The same design frequency applies to a single reflector and a reflector array, but with different meaning; in the latter case the design frequency is the upper limit for useful reflections. This design rule was first used...

  17. Critical and Creative Reflective Inquiry: Surfacing Narratives to Enable Learning and Inform Action

    Science.gov (United States)

    Cardiff, Shaun

    2012-01-01

    Narratives are being increasingly used in nursing and action research. In this participatory action research study, nurse leaders of an acute care of the older person unit collectively, critically and creatively reflected on lived experiences in order to explore the concept of person-centred leadership within their own practice. This paper…

  18. Relationship of intertidal surface sediment chlorophyll concentration to hyper-spectral reflectance and chlorophyll fluorescence

    NARCIS (Netherlands)

    Kromkamp, J.C.; Morris, E.P.; Forster, R.M.; Honeywill, C.; Hagerthey, S.; Paterson, D.M.

    2006-01-01

    Estimating biomass of microphytobenthos (MPB) on intertidal mud flats is extremely difficult due to their patchy occurrence, especially at the scale of an entire mud flat. We tested two optical approaches that can be applied in situ: spectral reflectance and chlorophyll fluorescence. These two

  19. Reflectivity and surface roughness of multilayer-coated substrate recovery layers for EUV lithographic optics

    NARCIS (Netherlands)

    Nedelcu, I.; van de Kruijs, R.W.E.; Yakshin, A. E.; von Blanckenhagen, G.; F. Bijkerk,

    2008-01-01

    We investigated the use of separation, or substrate recovery, layers (SRLs), to enable the reuse of optical substrates after the deposition of multilayer reflective coatings, in particular Mo/Si multilayers as used for EUV lithography. An organic material (polyimide), known from other work to reduce

  20. Reflection of P and SV waves at the free surface of a monoclinic ...

    Indian Academy of Sciences (India)

    R.Narasimhan(krishtel emaging)1461 1996 Oct 15 13:05:22

    The propagation of plane waves in an anisotropic elastic medium possessing monoclinic symmetry is discussed. The expressions for ... Keywords. Anisotropic medium; elastic waves; monoclinic half-space; reflection coefficients. Proc. Indian Acad. Sci. ...... In contrast, for C < 0, the angle of reflec- tion is less than the angle of ...

  1. Nonlinear reflection of a spherically divergent N-wave from a plane surface: Optical interferometry measurements in air

    International Nuclear Information System (INIS)

    Karzova, M.; Yuldashev, P.; Khokhlova, V.; Ollivier, S.; Blanc-Benon, Ph.

    2015-01-01

    Mach stem is a well-known structure typically observed in the process of strong (acoustic Mach numbers greater than 0.4) step-shock waves reflection from a rigid boundary. However, this phenomenon has been much less studied for weak shocks in nonlinear acoustic fields where Mach numbers are in the range from 0.001 to 0.01 and pressure waveforms have more complicated waveforms than step shocks. The goal of this work was to demonstrate experimentally how nonlinear reflection occurs in air for very weak spherically divergent acoustic spark-generated pulses resembling an N-wave. Measurements of reflection patterns were performed using a Mach-Zehnder interferometer. A thin laser beam with sub-millimeter cross-section was used to obtain the time resolution of 0.4 µs, which is 6 times higher than the time resolution of the condenser microphones. Pressure waveforms were reconstructed using the inverse Abel transform applied to the phase of the signal measured by the interferometer. The Mach stem formation was observed experimentally as a result of collision of the incident and reflected shock pulses. It was shown that irregular reflection of the pulse occurred in a dynamic way and the length of the Mach stem increased linearly while the pulse propagated along the surface. Since the front shock of the spark-generated pulse was steeper than the rear shock, irregular type of reflection was observed only for the front shock of the pulse while the rear shock reflection occurred in a regular regime

  2. Nonlinear reflection of a spherically divergent N-wave from a plane surface: Optical interferometry measurements in air

    Energy Technology Data Exchange (ETDEWEB)

    Karzova, M., E-mail: masha@acs366.phys.msu.ru [Laboratoire de Mécanique des Fluides et d’Acoustique, Ecole Centrale de Lyon, 36 Avenue Guy de Collongue, 69134 Ecully (France); Physics Faculty, Moscow State University, Leninskie Gory, 119991 Moscow (Russian Federation); Yuldashev, P.; Khokhlova, V. [Physics Faculty, Moscow State University, Leninskie Gory, 119991 Moscow (Russian Federation); Ollivier, S.; Blanc-Benon, Ph. [Laboratoire de Mécanique des Fluides et d’Acoustique, Ecole Centrale de Lyon, 36 Avenue Guy de Collongue, 69134 Ecully (France)

    2015-10-28

    Mach stem is a well-known structure typically observed in the process of strong (acoustic Mach numbers greater than 0.4) step-shock waves reflection from a rigid boundary. However, this phenomenon has been much less studied for weak shocks in nonlinear acoustic fields where Mach numbers are in the range from 0.001 to 0.01 and pressure waveforms have more complicated waveforms than step shocks. The goal of this work was to demonstrate experimentally how nonlinear reflection occurs in air for very weak spherically divergent acoustic spark-generated pulses resembling an N-wave. Measurements of reflection patterns were performed using a Mach-Zehnder interferometer. A thin laser beam with sub-millimeter cross-section was used to obtain the time resolution of 0.4 µs, which is 6 times higher than the time resolution of the condenser microphones. Pressure waveforms were reconstructed using the inverse Abel transform applied to the phase of the signal measured by the interferometer. The Mach stem formation was observed experimentally as a result of collision of the incident and reflected shock pulses. It was shown that irregular reflection of the pulse occurred in a dynamic way and the length of the Mach stem increased linearly while the pulse propagated along the surface. Since the front shock of the spark-generated pulse was steeper than the rear shock, irregular type of reflection was observed only for the front shock of the pulse while the rear shock reflection occurred in a regular regime.

  3. Intermolecular potential energy surface and thermophysical properties of propane.

    Science.gov (United States)

    Hellmann, Robert

    2017-03-21

    A six-dimensional potential energy surface (PES) for the interaction of two rigid propane molecules was determined from supermolecular ab initio calculations up to the coupled cluster with single, double, and perturbative triple excitations level of theory for 9452 configurations. An analytical site-site potential function with 14 sites per molecule was fitted to the calculated interaction energies. To validate the analytical PES, the second virial coefficient and the dilute gas shear viscosity and thermal conductivity of propane were computed. The dispersion part of the potential function was slightly adjusted such that quantitative agreement with the most accurate experimental data for the second virial coefficient at room temperature was achieved. The adjusted PES yields values for the three properties that are in very good agreement with the best experimental data at all temperatures.

  4. Computation of the optical properties of turbid media from slope and curvature of spatially resolved reflectance curves

    International Nuclear Information System (INIS)

    Jäger, Marion; Foschum, Florian; Kienle, Alwin

    2013-01-01

    The optical properties of turbid media were calculated from the curvature at the radial distance ρ O and the slope at the radial distance ρ* of simulated spatially resolved reflectance curves (ρ O (ρ*) denotes a decrease of the spatially resolved reflectance curve of 0.75 (2.4) orders of magnitude relative to the reflectance value at 1.2 mm). We found correlations between the curvature at ρ O and the reduced scattering coefficient as well as the slope at ρ* and the absorption coefficient. For the determination of the optical properties we used these two correlations. The calculation of the reduced scattering coefficient from the curvature at ρ O is practically independent from the absorption coefficient. Knowing the reduced scattering coefficient within a certain accuracy allows the determination of the absorption coefficient from the slope at ρ*. Additionally, we investigated the performance of an artificial neural network for the determination of the optical properties using the above explained correlations. This means we used the derivatives as input data. Our artificial neural network was capable to learn the mapping between the optical properties and the derivatives. In effect, the results for the determined optical properties improved in comparison to the above explained method. Finally, the procedure was compared to an artificial neural network that was trained without using the derivatives. (note)

  5. Impact of gastric acidic challenge on surface topography and optical properties of monolithic zirconia.

    Science.gov (United States)

    Sulaiman, Taiseer A; Abdulmajeed, Aous A; Shahramian, Khalil; Hupa, Leena; Donovan, Terrence E; Vallittu, Pekka; Närhi, Timo O

    2015-12-01

    To evaluate the surface topography and optical properties of monolithic zirconia after immersion in simulated gastric acid. Four partially stabilized (PSZ) and one fully stabilized (FSZ) zirconia materials were selected for the study: Prettau (PRT, Zirkonzahn), Zenostar (ZEN, Ivoclar), Bruxzir (BRX, Glidewell), Katana (KAT, Noritake) and FSZ Prettau Anterior (PRTA, Zirkonzahn). IPS e.max (Ivoclar) was used as a control. The specimens (10×10×1.2mm, n=5 per material) were cut, sintered, polished and cleaned before immersed in 5ml of simulated gastric acid solution (Hydrochloric acid (HCl) 0.06M, 0.113% solution in deionized distal water, pH 1.2) for 96h in a 37°C incubator. Specimens were weighed and examined for morphological changes under scanning electron microscope (SEM) coupled with energy dispersive X-ray spectroscopy (EDX). Surface roughness was evaluated by a confocal microscope. Surface gloss and translucency parameter (TP) values were determined by a reflection spectrophotometer before and after acid immersion. The data was analyzed by one-way ANOVA followed by Tukey's HSD post hoc test (pgloss of ZEN, PRTA and IPS e.max increased (p<0.05). Monolithic zirconia materials show some surface alterations in an acidic environment with minimum effect on their optical properties. Whether a smoother surface is in fact a sign of true corrosion resistance or is purely the result of an evenly progressive corrosive process is yet to be confirmed by further research. Copyright © 2015 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.

  6. An assessment of thin cloud detection by applying bidirectional reflectance distribution function model-based background surface reflectance using Geostationary Ocean Color Imager (GOCI): A case study for South Korea

    Science.gov (United States)

    Kim, Hye-Won; Yeom, Jong-Min; Shin, Daegeun; Choi, Sungwon; Han, Kyung-Soo; Roujean, Jean-Louis

    2017-08-01

    In this study, a new assessment of thin cloud detection with the application of bidirectional reflectance distribution function (BRDF) model-based background surface reflectance was undertaken by interpreting surface spectra characterized using the Geostationary Ocean Color Imager (GOCI) over a land surface area. Unlike cloud detection over the ocean, the detection of cloud over land surfaces is difficult due to the complicated surface scattering characteristics, which vary among land surface types. Furthermore, in the case of thin clouds, in which the surface and cloud radiation are mixed, it is difficult to detect the clouds in both land and atmospheric fields. Therefore, to interpret background surface reflectance, especially underneath cloud, the semiempirical BRDF model was used to simulate surface reflectance by reflecting solar angle-dependent geostationary sensor geometry. For quantitative validation, Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) data were used to make a comparison with the proposed cloud masking result. As a result, the new cloud masking scheme resulted in a high probability of detection (POD = 0.82) compared with the Moderate Resolution Imaging Spectroradiometer (MODIS) (POD = 0.808) for all cloud cases. In particular, the agreement between the CALIPSO cloud product and new GOCI cloud mask was over 94% when detecting thin cloud (e.g., altostratus and cirrus) from January 2014 to June 2015. This result is relatively high in comparison with the result from the MODIS Collection 6 cloud mask product (MYD35).

  7. Substrate texture properties induce triatomine probing on bitten warm surfaces

    Directory of Open Access Journals (Sweden)

    Lorenzo Marcelo G

    2011-06-01

    Full Text Available Abstract Background In this work we initially evaluated whether the biting process of Rhodnius prolixus relies on the detection of mechanical properties of the substrate. A linear thermal source was used to simulate the presence of a blood vessel under the skin of a host. This apparatus consisted of an aluminium plate and a nickel-chrome wire, both thermostatized and presented at 33 and 36°C, respectively. To evaluate whether mechanical properties of the substrate affect the biting behaviour of bugs, this apparatus was covered by a latex membrane. Additionally, we evaluated whether the expression of probing depends on the integration of bilateral thermal inputs from the antennae. Results The presence of a latex cover on a thermal source induced a change in the biting pattern shown by bugs. In fact, with latex covered sources it was possible to observe long bites that were never performed in response to warm metal surfaces. The total number of bites was higher in intact versus unilaterally antennectomized insects. These bites were significantly longer in intact than in unilaterally antennectomized insects. Conclusions Our results suggest that substrate recognition by simultaneous input through thermal and mechanical modalities is required for triggering maxillary probing activity.

  8. Atomistic simulations of bulk, surface and interfacial polymer properties

    Science.gov (United States)

    Natarajan, Upendra

    In chapter I, quasi-static molecular mechanics based simulations are used to estimate the activation energy of phenoxy rings flips in the amorphous region of a semicrystalline polyimide. Intra and intermolecular contributions to the flip activation energy, the torsional cooperativity accompanying the flip, and the effect of the flip on the motion in the glassy bulk state, are looked at. Also, comparison of the weighted mean activation energy is made with experimental data from solid state NMR measurements; the simulated value being 17.5 kcal/mol., while the experimental value was observed to be 10.5 kcal/mol. Chapter II deals with construction of random copolymer thin films of styrene-butadiene (SB) and styrene-butadiene-acrylonitrile (SBA). The structure and properties of the free surfaces presented by these thin films are analysed by, the atom mass density profiles, backbone bond orientation function, and the spatial distribution of acrylonitrile groups and styrene rings. The surface energies of SB and SBA are calculated using an atomistic equation and are compared with experimental data in the literature. In chapter III, simulations of polymer-polymer interfaces between like and unlike polymers, specifically cis-polybutadiene (PBD) and atatic polypropylene (PP), are presented. The structure of an incompatible polymer-polymer interface, and the estimation of the thermodynamic work of adhesion and interfacial energy between different incompatible polymers, form the focus here. The work of adhesion is calculated using an atomistic equation and is further used in a macroscopic equation to estimate the interfacial energy. The interfacial energy is compared with typical values for other immiscible systems in the literature. The interfacial energy compared very well with interfacial energy values for a few other immiscible hydrocarbon pairs. In chapter IV, the study proceeds to look at the interactions between nonpolar and polar small molecules with SB and SBA thin

  9. Mapping surface properties of sinusoidal roughness standards by TPM

    International Nuclear Information System (INIS)

    Liu, X; Rubert, P

    2005-01-01

    We report our investigation on the surface properties of sinusoidal roughness standards made from pure electroformed nickel. Two specimens having a sinusoidal profile with nominal R a of 0.36 μm and a peak spacing of 25 μm are chosen for this investigation. One specimen is further treated with a hard protective coating of nickel-boron. The surface topography, friction, hardness and Young's modulus of the specimens were measured by a novel instrument, the multi-function Tribological Probe Microscope (TPM). The results show that hardness of these two specimens is 14.1 GPa for uncoated specimen and 25.7 GPa for the coated one, while the Young's modulus is 188 GPa and 225 GPa, respectively. The ramping force was set to 3mN for both the specimens and the effect of the tip penetration was investigated by comparing the topography measurements before and after hardness mapping. It has been found out that there is no significant change in the averaged profiles over the scanned area, which indicates the topography distortion seen in the multi-function mapping, is recoverable. Cross correlation between topography and its corresponding hardness/Young's modulus has been carried out and the result will be discussed in the paper

  10. Surface molecular aggregation structure and surface physicochemical properties of poly(fluoroalkyl acrylate) thin films

    International Nuclear Information System (INIS)

    Honda, K; Yamaguchi, H; Takahara, A; Kobayashi, M; Morita, M

    2008-01-01

    Effect of side chain length on the molecular aggregation states and surface properties of poly(fluoroalkyl acrylate)s [PFA-C y , where y is fluoromethylene number in R f group] thin films were systematically investigated. Spin-coated PFA-C y thin films were characterized by static and dynamic contact angle measurements, X-ray photoelectron spectroscopy (XPS), and grazing- incidence X-ray diffraction (GIXD). The receding contact angles showed small values for PFA-C y with short side chain (y≤6) and increased above y≥8. GIXD revealed that fluoroalkyl side chain of PFA-C y with y≥8 was crystallized and formed ordered structures at the surface region as well as bulk one. These results suggest that water repellent mechanism of PFA-C y can be attributed to the presence of highly ordered fluoroalkyl side chains at the outermost surfaces. The results of XPS in the dry and hydrated states and contact angle measurement in water support the mechanism of lowering contact angle for water by exposure of carbonyl group to the water interface through reorientation of short fluoroalkyl chains. The surface nanotextured PFA-C 8 through imprinting of anodic aluminum oxide mold showed extremely high hydrophobicity as well as high oleophobicity

  11. Study of Surface Wettability Change of Unconsolidated Sand Using Diffuse Reflectance Infrared Fourier Transform Spectroscopy and Thermogravimetric Analysis.

    Science.gov (United States)

    Gómora-Herrera, Diana; Navarrete Bolaños, Juan; Lijanova, Irina V; Olivares-Xometl, Octavio; Likhanova, Natalya V

    2018-04-01

    The effects exerted by the adsorption of vapors of a non-polar compound (deuterated benzene) and a polar compound (water) on the surface of Ottawa sand and a sample of reservoir sand (Channel), which was previously impregnated with silicon oil or two kinds of surfactants, (2-hydroxyethyl) trimethylammonium oleate (HETAO) and (2-hydroxyethyl)trimethylammonium azelate (HETAA), were studied by diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and thermogravimetric analysis (TGA). The surface chemistry of the sandstone rocks was elucidated by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) with energy dispersive X-ray spectroscopy (EDX). Terminal surface groups such as hydroxyls can strongly adsorb molecules that interact with these surface groups (surfactants), resulting in a wettability change. The wettability change effect suffered by the surface after treating it with surfactants was possible to be detected by the DRIFTS technique, wherein it was observed that the surface became more hydrophobic after being treated with silicon oil and HETAO; the surface became more hydrophilic after treating it with HETAA.

  12. Porous Nanomaterials for Ultrabroadband Omnidirectional Anti-Reflection Surfaces with Applications in High Concentration Photovoltaics

    KAUST Repository

    Yao, Yuan

    2016-12-06

    Materials for nanoporous coatings that exploit optimized chemistries and self-assembly processes offer capabilities to reach ≈98% transmission efficiency and negligible scattering losses over the broad wavelength range of the solar spectrum from 350 nm to 1.5 μm, on both flat and curved glass substrates. These nanomaterial anti-reflection coatings also offer wide acceptance angles, up to ±40°, for both s- and p-polarization states of incident light. Carefully controlled bilayer films have allowed for the fabrication of dual-sided, gradient index profiles on plano-convex lens elements. In concentration photovoltaics platforms, the resultant enhancements in the photovoltaics efficiencies are ≈8%, as defined by experimental measurements on systems that use microscale triple-junction solar cells. These materials and their applications in technologies that require control over interface reflections have the potential for broad utility in imaging systems, photolithography, light-emitting diodes, and display technologies.

  13. Secondary electron/reflected particle coincidence studies during slow highly charged ion-surface interactions

    Energy Technology Data Exchange (ETDEWEB)

    McGrath, C.T.; Szilagyi, Z.; Shah, M.B.; McCullough, R.W. [Queen' s Univ., Belfast, Northern Ireland (United Kingdom); Woolsey, J.M. [Stirling Univ. (United Kingdom). DBMS; Trassl, R.; Salzborn, E. [Giessen Univ. (Germany). Inst. fuer Kernphysik

    2001-07-01

    We have measured the secondary electron emission statistics (ES) for 5 keV N{sup q+} (q = 1-4) ions incident at 10 on polycrystalline aluminium, in coincidence with specularly reflected N{sup 0}. In this arrangement the kinetic contribution to secondary electron emission is minimised. The experimental data shows that the coincident electron yield, {gamma}, increases linearly with incident ion charge state. The kinetic emission contribution has also been determined from this data. The ES due to 2 and 4 keV He{sup 2+} impact on polycrystalline aluminium in coincidence with specularly reflected He{sup +} and He{sup 0} have also been determined. The process He{sup 2+} {yields} He{sup 0} yields a larger {gamma} value than the process He{sup 2+} {yields} He{sup +}. (orig.)

  14. Adaptive Surface Modeling of Soil Properties in Complex Landforms

    Directory of Open Access Journals (Sweden)

    Wei Liu

    2017-06-01

    Full Text Available Abstract: Spatial discontinuity often causes poor accuracy when a single model is used for the surface modeling of soil properties in complex geomorphic areas. Here we present a method for adaptive surface modeling of combined secondary variables to improve prediction accuracy during the interpolation of soil properties (ASM-SP. Using various secondary variables and multiple base interpolation models, ASM-SP was used to interpolate soil K+ in a typical complex geomorphic area (Qinghai Lake Basin, China. Five methods, including inverse distance weighting (IDW, ordinary kriging (OK, and OK combined with different secondary variables (e.g., OK-Landuse, OK-Geology, and OK-Soil, were used to validate the proposed method. The mean error (ME, mean absolute error (MAE, root mean square error (RMSE, mean relative error (MRE, and accuracy (AC were used as evaluation indicators. Results showed that: (1 The OK interpolation result is spatially smooth and has a weak bull's-eye effect, and the IDW has a stronger ‘bull’s-eye’ effect, relatively. They both have obvious deficiencies in depicting spatial variability of soil K+. (2 The methods incorporating combinations of different secondary variables (e.g., ASM-SP, OK-Landuse, OK-Geology, and OK-Soil were associated with lower estimation bias. Compared with IDW, OK, OK-Landuse, OK-Geology, and OK-Soil, the accuracy of ASM-SP increased by 13.63%, 10.85%, 9.98%, 8.32%, and 7.66%, respectively. Furthermore, ASM-SP was more stable, with lower MEs, MAEs, RMSEs, and MREs. (3 ASM-SP presents more details than others in the abrupt boundary, which can render the result consistent with the true secondary variables. In conclusion, ASM-SP can not only consider the nonlinear relationship between secondary variables and soil properties, but can also adaptively combine the advantages of multiple models, which contributes to making the spatial interpolation of soil K+ more reasonable.

  15. Characterizing the surface heterogeneity of fire effects using multi-temporal reflective wavelength data

    CSIR Research Space (South Africa)

    Roy, DP

    2005-10-10

    Full Text Available fires lit in South Africa to substantiate and illustrate the model findings. We discuss the implications of our findings for algorithms that examine change in reflectance to map fire-affected areas and discuss the possibility of deriving cc and f from... measurements were taken in the laboratory to reduce field measurement errors and because we were concerned only with obtaining representative spectra for illustrative modelling. SAFARI 2000 4203 The measurements were made under diffuse illumination conditions...

  16. Role of the substrate reflectance and surface-bulk treatments in CsI quantum efficiency

    CERN Document Server

    Singh, B K; Nitti, M A; Valentini, A

    2003-01-01

    We have experimentally investigated the following aspects related to the quantum efficiency of CsI photocathodes: the type of substrate, the film thickness and the effect of a 'bulk treatment' during the film growth. We discovered that, using a high reflectivity aluminium substrate, the photoemission of very thin CsI film is enhanced. Our study also revealed that photocathodes become less sensitive to moisture when a negative bias voltage is applied to the substrate during the film deposition process.

  17. Neutron reflectivity

    Directory of Open Access Journals (Sweden)

    Cousin Fabrice

    2015-01-01

    Full Text Available The specular neutron reflectivity is a technique enabling the measurement of neutron scattering length density profile perpendicular to the plane of a surface or an interface, and thereby the profile of chemical composition. The characteristic sizes that are probed range from around 5 Å up 5000 Å. It is a scattering technique that averages information on the entire surface and it is therefore not possible to obtain information within the plane of the interface. The specific properties of neutrons (possibility of tuning the contrast by isotopic substitution, sensitivity to magnetism, negligible absorption, low energy of the incident neutrons makes it particularly interesting in the fields of soft matter, biophysics and magnetic thin films. This course is a basic introduction to the technique and does not address the magnetic reflectivity. It is composed of three parts describing respectively its principle and its formalism, the experimental aspects of the method (spectrometers, samples and two examples related to the materials for energy.

  18. On quantum motion of particle in linear potential bounded by perfectly reflecting plane and parabolic surfaces

    International Nuclear Information System (INIS)

    Pokotilovskij, Yu.N.

    1999-01-01

    The motion of a particle in the linear potential bounded by an inclined plane or parabolic surfaces is considered. The quantization of energy and wave functions is obtained numerically by the separation of the variables method

  19. Acrotelm pedogenesis of a Sphagnum bog is reflected in effective unsaturated hydraulic properties

    Science.gov (United States)

    Weber, Tobias K. D.; Iden, Sascha C.; Durner, Wolfgang

    2017-04-01

    In ombrotrophic peatlands, the moisture content of the vadose zone (acrotelm) controls oxygen diffusion rates, redox state, and the turnover of organic matter. Whether peatlands act as sinks or sources of atmospheric carbon thus relies on variably saturated flow processes. Modeling of these processes is crucial in assessing effects of changed environmental conditions on the future development of these ecosystems. The Richards equation (RE) is the standard model for water flow in soils, but it is not clear whether it can be applied to simulate water flow in live Sphagnum moss. To check the suitability of the RE to describe the water dynamics in drying moss and peat we conducted transient laboratory evaporation experiments on undisturbed samples from the entire acrotelm. The experimental data consisted of measured pressure heads in two depths and water fluxes, and were evaluated by inverse modelling using the RE as process model. The results showed that the measurements could be matched very well only if the soil hydraulic properties (SHPs) were represented by a suitable model. A successful parameterisation of the SHPs of the moss was based on pore-size distributions (PSD) which combine three distinct pore systems of the Sphagnum moss, reflecting an inter-, intra-, and inner-plant pore space. We had to extend the traditional van Genuchten-Mualem model to account for non-capillary water storage and flow to obtain consistent descriptions of the observations. For the deeper samples, the pedogenesis of the acrotelm, a process of compaction and biochemical degradation of the solid matrix, had considerably impact on the shape of the SHPs. The collapse of the inter-plant pores and their filling with smaller particles led gradually to bi-modal PSDs with increasing depth. This coincides with a homogenisation and a considerably reduction in horizontal variability of SHPs at greater depths. We conclude that the RE with adequate representation of SHPs is a valid process

  20. Tunable band gap and optical properties of surface functionalized Sc2C monolayer

    International Nuclear Information System (INIS)

    Wang Shun; Du Yu-Lei; Liao Wen-He

    2017-01-01

    Using the density functional theory, we have investigated the electronic and optical properties of two-dimensional Sc 2 C monolayer with OH, F, or O chemical groups. The electronic structures reveal that the functionalized Sc 2 C monolayers are semiconductors with a band gap of 0.44–1.55 eV. The band gap dependent optical parameters, like dielectric function, absorption coefficients, reflectivity, loss function, and refraction index were also calculated for photon energy up to 20 eV. At the low-energy region, each optical parameter shifts to red, and the peak increases obviously with the increase of the energy gap. Consequently, Sc 2 C monolayer with a tunable band gap by changing the type of surface chemical groups is a promising 2D material for optoelectronic devices. (paper)

  1. Reflection electron energy loss spectroscopy as efficient technique for the determination of optical properties of polystyrene intermixed with gold nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Deris, Jamileh [Department of Physics, Yasouj University, Yasouj 75918-74831 (Iran, Islamic Republic of); Hajati, Shaaker, E-mail: Hajati@mail.yu.ac.ir [Department of Physics, Yasouj University, Yasouj 75918-74831 (Iran, Islamic Republic of); Department of Semiconductors, Materials and Energy Research Center, Karaj 3177983634 (Iran, Islamic Republic of)

    2017-01-15

    Highlights: • Reflection Electron Energy Loss Spectroscopy of nano-metalized polymer. • Determination of real part of the dielectric function of nanostructured sample. • Determination of imaginary part of the dielectric function of nanostructured sample. • Determination of refractive index and coefficient of extinction of the sample. • Determination of reflection and absorption coefficients of nano-metalized Polymer. - Abstract: The electronic properties (electron inelastic cross section, energy loss function) of a nano-metalized polystyrene obtained by reflection electron energy loss spectroscopy (REELS) in a previous study [J. Deris, S. Hajati, S. Tougaard, V. Zaporojtchenko, Appl. Surf. Sci. 377 (2016) 44–47], which relies on the Yubero-Tougaard method, were used in the complementary application of Kramers-Kronig transformation to determine its optical properties such as the real part (ε{sub 1}) and imaginary part (ε{sub 2}) of the dielectric function (ε), refractive index (n), coefficients of extinction (k), reflection (R) and absorption (μ). The degree of intermixing of polystyrene thin film and gold nanoparticles of sizes 5.5 nm was controlled by annealing the sample to achieve a morphology in which the nanoparticles were homogeneously distributed within polystyrene. It is worth noting that no data are available on the optical properties of metalized polymers such as gold nanoparticles intermixed with polystyrene. Therefore, this work is of high importance in terms of both the sample studied here and the method applied. The advantage of the method applied here is that no information on the lateral distribution of the nanocomposite sample is required. This means that the REELS technique has been presented here to suitably, efficiently and easily obtain the optical properties of such nano-metalized polymer in which the metal nanoparticles have been vertically well distributed (homogeneous in depth). Therefore, for vertically homogeneous and

  2. Classification of reflected signals from cavitated tooth surfaces using an artificial intelligence technique incorporating a fiber optic displacement sensor

    Science.gov (United States)

    Rahman, Husna Abdul; Harun, Sulaiman Wadi; Arof, Hamzah; Irawati, Ninik; Musirin, Ismail; Ibrahim, Fatimah; Ahmad, Harith

    2014-05-01

    An enhanced dental cavity diameter measurement mechanism using an intensity-modulated fiber optic displacement sensor (FODS) scanning and imaging system, fuzzy logic as well as a single-layer perceptron (SLP) neural network, is presented. The SLP network was employed for the classification of the reflected signals, which were obtained from the surfaces of teeth samples and captured using FODS. Two features were used for the classification of the reflected signals with one of them being the output of a fuzzy logic. The test results showed that the combined fuzzy logic and SLP network methodology contributed to a 100% classification accuracy of the network. The high-classification accuracy significantly demonstrates the suitability of the proposed features and classification using SLP networks for classifying the reflected signals from teeth surfaces, enabling the sensor to accurately measure small diameters of tooth cavity of up to 0.6 mm. The method remains simple enough to allow its easy integration in existing dental restoration support systems.

  3. Polarization properties and microfacet-based modelling of white, grey and coloured matte diffuse reflection standards

    Science.gov (United States)

    Quast, T.; Schirmacher, A.; Hauer, K.-O.; Koo, A.

    2018-02-01

    To elucidate the influence of polarization in diffuse reflectometry, we performed a series of measurements in several bidirectional geometries and determined the Stokes parameters of the diffusely reflected radiation. Different types of matte reflection standards were used, including several common white standards and ceramic colour standards. The dependence of the polarization on the sample type, wavelength and geometry have been studied systematically, the main influence factors have been identified: The effect is largest at large angles of incidence or detection and at wavelengths where the magnitude of the reflectance is small. The results for the colour standards have been modelled using a microfacet-based reflection theory which is derived from the well-known model of Torrance and Sparrow. Although the theory is very simple and only has three free parameters, the agreement with the measured data is very good, all essential features of the data can be reproduced by the model.

  4. TiO2-coated Hollow Glass Microspheres with Superhydrophobic and High IR-reflective Properties Synthesized by a Soft-chemistry Method.

    Science.gov (United States)

    Wong, Yinting; Zhong, Dan; Song, Aotian; Hu, Yan

    2017-04-26

    This manuscript proposes a soft-chemistry method to develop superhydrophobic and highly IR-reflective hollow glass microspheres (HGM). The anatase TiO2 and a superhydrophobic agent were coated on the HGM surface in one step. TBT and PFOTES were selected as the Ti source and the superhydrophobic agent, respectively. They were both coated on the HGM, and after the hydrothermal process, the TBT turned to anatase TiO2. In this way, a PFOTES/TiO2-coated HGM (MCHGM) was prepared. For comparison, PFOTES single-coated HGM (F-SCHGM) and TiO2 single-coated HGM (Ti-SCHGM) were synthesized as well. The PFOTES and TiO2 coatings on the HGM surface were demonstrated through X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive detector (EDS) characterizations. The MCHGM showed a higher contact angle (153°) but a lower sliding angle (16°) than F-SCHGM, with a contact angle of 141.2° and a sliding angle of 67°. In addition, both Ti-SCHGM and MCHGM displayed similar IR reflectivity values, which were about 5.8% higher than the original HGM and F-SCHGM. Also, the PFOTES coating barely changed the thermal conductivity. Therefore, F-SCHGM, with a thermal conductivity of 0.0479 W/(m·K), was quite like the original HGM, which was 0.0475 W/(m·K). MCHGM and Ti-SCHGM were also similar. Their thermal conductivity values were 0.0543 W/(m·K) and 0.0543 W/(m·K), respectively. The TiO2 coating slightly increased the thermal conductivity, but with the increase in reflectivity, the overall heat-insulation property was enhanced. Finally, since the IR-reflecting property is provided by the HGM coating, if the coating is fouled, the reflectivity decreases. Therefore, with the superhydrophobic coating, the surface is protected from fouling, and its lifetime is also prolonged.

  5. Simultaneous Retrieval of Aerosol and Surface Optical Properties from Combined Airborne- and Ground-Based Direct and Diffuse Radiometric Measurements

    Science.gov (United States)

    Gatebe, C. K.; Dubovik, O.; King, M. D.; Sinyuk, A.

    2010-01-01

    This paper presents a new method for simultaneously retrieving aerosol and surface reflectance properties from combined airborne and ground-based direct and diffuse radiometric measurements. The method is based on the standard Aerosol Robotic Network (AERONET) method for retrieving aerosol size distribution, complex index of refraction, and single scattering albedo, but modified to retrieve aerosol properties in two layers, below and above the aircraft, and parameters on surface optical properties from combined datasets (Cloud Absorption Radiometer (CAR) and AERONET data). A key advantage of this method is the inversion of all available spectral and angular data at the same time, while accounting for the influence of noise in the inversion procedure using statistical optimization. The wide spectral (0.34-2.30 m) and angular range (180 ) of the CAR instrument, combined with observations from an AERONET sunphotometer, provide sufficient measurement constraints for characterizing aerosol and surface properties with minimal assumptions. The robustness of the method was tested on observations made during four different field campaigns: (a) the Southern African Regional Science Initiative 2000 over Mongu, Zambia, (b) the Intercontinental Transport Experiment-Phase B over Mexico City, Mexico (c) Cloud and Land Surface Interaction Campaign over the Atmospheric Radiation Measurement (ARM) Central Facility, Oklahoma, USA, and (d) the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) over Elson Lagoon in Barrow, Alaska, USA. The four areas are dominated by different surface characteristics and aerosol types, and therefore provide good test cases for the new inversion method.

  6. Designed cellulose nanocrystal surface properties for improving barrier properties in polylactide nanocomposites.

    Science.gov (United States)

    Espino-Pérez, Etzael; Bras, Julien; Almeida, Giana; Plessis, Cédric; Belgacem, Naceur; Perré, Patrick; Domenek, Sandra

    2018-03-01

    Nanocomposites are an opportunity to increase the performance of polymer membranes by fine-tuning their morphology. In particular, the understanding of the contribution of the polymer matrix/nanofiller interface to the overall transport properties is key to design membranes with tailored selective and adsorptive properties. In that aim, cellulose nanocrystals (CNC)/polylactide (PLA) nanocomposites were fabricated with chemically designed interfaces, which were ensuring the compatibility between the constituents and impacting the mass transport mechanism. A detailed analysis of the mass transport behaviour of different permeants in CNC/PLA nanocomposites was carried out as a function of their chemical affinity to grafted CNC surfaces. Penetrants (O 2 and cyclohexane), which were found to slightly interact with the constituents of the nanocomposites, provided information on the small