Highly reflective polymeric substrates functionalized utilizing atomic layer deposition

International Nuclear Information System (INIS)

Zuzuarregui, Ana; Gregorczyk, Keith E.; Coto, Borja; Ruiz de Gopegui, Unai; Barriga, Javier; Rodríguez, Jorge; Knez, Mato

2015-01-01

Reflective surfaces are one of the key elements of solar plants to concentrate energy in the receivers of solar thermal electricity plants. Polymeric substrates are being considered as an alternative to the widely used glass mirrors due to their intrinsic and processing advantages, but optimizing both the reflectance and the physical stability of polymeric mirrors still poses technological difficulties. In this work, polymeric surfaces have been functionalized with ceramic thin-films by atomic layer deposition. The characterization and optimization of the parameters involved in the process resulted in surfaces with a reflection index of 97%, turning polymers into a real alternative to glass substrates. The solution we present here can be easily applied in further technological areas where seemingly incompatible combinations of polymeric substrates and ceramic coatings occur

Modeling the microstructure of surface by applying BRDF function

Science.gov (United States)

Plachta, Kamil

2017-06-01

The paper presents the modeling of surface microstructure using a bidirectional reflectance distribution function. This function contains full information about the reflectance properties of the flat surfaces - it is possible to determine the share of the specular, directional and diffuse components in the reflected luminous stream. The software is based on the authorial algorithm that uses selected elements of this function models, which allows to determine the share of each component. Basing on obtained data, the surface microstructure of each material can be modeled, which allows to determine the properties of this materials. The concentrator directs the reflected solar radiation onto the photovoltaic surface, increasing, at the same time, the value of the incident luminous stream. The paper presents an analysis of selected materials that can be used to construct the solar concentrator system. The use of concentrator increases the power output of the photovoltaic system by up to 17% as compared to the standard solution.

Optical properties (bidirectional reflectance distribution function) of shot fabric

NARCIS (Netherlands)

Lu, Rong; Koenderink, Jan J.; Kappers, Astrid M L

2000-01-01

To study the optical properties of materials, one needs a complete set of the angular distribution functions of surface scattering from the materials. Here we present a convenient method for collecting a large set of bidirectional reflectance distribution function (BRDF) samples in the hemispherical

The differential equation of an arbitrary reflecting surface

Science.gov (United States)

Melka, Richard F.; Berrettini, Vincent D.; Yousif, Hashim A.

2018-05-01

A differential equation describing the reflection of a light ray incident upon an arbitrary reflecting surface is obtained using the law of reflection. The derived equation is written in terms of a parameter and the value of this parameter determines the nature of the reflecting surface. Under various parametric constraints, the solution of the differential equation leads to the various conic surfaces but is not generally solvable. In addition, the dynamics of the light reflections from the conic surfaces are executed in the Mathematica software. Our derivation is the converse of the traditional approach and our analysis assumes a relation between the object distance and the image distance. This leads to the differential equation of the reflecting surface.

Seismic reflection imaging, accounting for primary and multiple reflections

Science.gov (United States)

Wapenaar, Kees; van der Neut, Joost; Thorbecke, Jan; Broggini, Filippo; Slob, Evert; Snieder, Roel

2015-04-01

Imaging of seismic reflection data is usually based on the assumption that the seismic response consists of primary reflections only. Multiple reflections, i.e. waves that have reflected more than once, are treated as primaries and are imaged at wrong positions. There are two classes of multiple reflections, which we will call surface-related multiples and internal multiples. Surface-related multiples are those multiples that contain at least one reflection at the earth's surface, whereas internal multiples consist of waves that have reflected only at subsurface interfaces. Surface-related multiples are the strongest, but also relatively easy to deal with because the reflecting boundary (the earth's surface) is known. Internal multiples constitute a much more difficult problem for seismic imaging, because the positions and properties of the reflecting interfaces are not known. We are developing reflection imaging methodology which deals with internal multiples. Starting with the Marchenko equation for 1D inverse scattering problems, we derived 3D Marchenko-type equations, which relate reflection data at the surface to Green's functions between virtual sources anywhere in the subsurface and receivers at the surface. Based on these equations, we derived an iterative scheme by which these Green's functions can be retrieved from the reflection data at the surface. This iterative scheme requires an estimate of the direct wave of the Green's functions in a background medium. Note that this is precisely the same information that is also required by standard reflection imaging schemes. However, unlike in standard imaging, our iterative Marchenko scheme retrieves the multiple reflections of the Green's functions from the reflection data at the surface. For this, no knowledge of the positions and properties of the reflecting interfaces is required. Once the full Green's functions are retrieved, reflection imaging can be carried out by which the primaries and multiples are

Sequential fitting-and-separating reflectance components for analytical bidirectional reflectance distribution function estimation.

Science.gov (United States)

Lee, Yu; Yu, Chanki; Lee, Sang Wook

2018-01-10

We present a sequential fitting-and-separating algorithm for surface reflectance components that separates individual dominant reflectance components and simultaneously estimates the corresponding bidirectional reflectance distribution function (BRDF) parameters from the separated reflectance values. We tackle the estimation of a Lafortune BRDF model, which combines a nonLambertian diffuse reflection and multiple specular reflectance components with a different specular lobe. Our proposed method infers the appropriate number of BRDF lobes and their parameters by separating and estimating each of the reflectance components using an interval analysis-based branch-and-bound method in conjunction with iterative K-ordered scale estimation. The focus of this paper is the estimation of the Lafortune BRDF model. Nevertheless, our proposed method can be applied to other analytical BRDF models such as the Cook-Torrance and Ward models. Experiments were carried out to validate the proposed method using isotropic materials from the Mitsubishi Electric Research Laboratories-Massachusetts Institute of Technology (MERL-MIT) BRDF database, and the results show that our method is superior to a conventional minimization algorithm.

Measuring Light Reflectance of BGO Crystal Surfaces

Science.gov (United States)

Janecek, Martin; Moses, William W.

2008-10-01

A scintillating crystal's surface reflectance has to be well understood in order to accurately predict and optimize the crystal's light collection through Monte Carlo simulations. In this paper, we measure the inner surface reflectance properties for BGO. The measurements include BGO crystals with a mechanically polished surface, rough-cut surface, and chemically etched surface, and with various reflectors attached, both air-coupled and with coupling compound. The measurements are performed with a laser aimed at the center of a hemispherical shaped BGO crystal. The hemispherical shape eliminates any non-perpendicular angles for light entering and exiting the crystal. The reflected light is collected with an array of photodiodes. The laser can be set at an arbitrary angle, and the photodiode array is rotated to fully cover 2pi of solid angle. The current produced in the photodiodes is readout with a digital multimeter connected through a multiplexer. The two rows of photodiodes achieve 5-degree by 4-degree resolution, and the current measurement has a dynamic range of 105:1. The acquired data was not described by the commonly assumed linear combination of specular and diffuse (Lambertian) distributions, except for a very few surfaces. Surface roughness proved to be the most important parameter when choosing crystal setup. The reflector choice was of less importance and of almost no consequence for rough-cut surfaces. Pure specular reflection distribution for all incidence angles was measured for polished surfaces with VM2000 film, while the most Lambertian distribution for any surface finish was measured for titanium dioxide paint. The distributions acquired in this paper will be used to create more accurate Monte Carlo models for light reflection distribution within BGO crystals.

Optical Estimation of the 3D Shape of a Solar Illuminated, Reflecting Satellite Surface

Science.gov (United States)

Antolin, J.; Yu, Z.; Prasad, S.

2016-09-01

The spatial distribution of the polarized component of the power reflected by a macroscopically smooth but microscopically roughened curved surface under highly directional illumination, as characterized by an appropriate bi-directional reflectance distribution function (BRDF), carries information about the three-dimensional (3D) shape of the surface. This information can be exploited to recover the surface shape locally under rather general conditions whenever power reflectance data for at least two different illumination or observation directions can be obtained. We present here two different parametric approaches for surface reconstruction, amounting to the recovery of the surface parameters that are either the global parameters of the family to which the surface is known a priori to belong or the coefficients of a low-order polynomial that can be employed to characterize a smoothly varying surface locally over the observed patch.

Evaluation of BRDF Archetypes for Representing Surface Reflectance Anisotropy Using MODIS BRDF Data

OpenAIRE

Zhang, Hu; Jiao, Ziti; Dong, Yadong; Li, Xiaowen

2015-01-01

Bidirectional reflectance distribution function (BRDF) archetypes extracted from the Moderate Resolution Imaging Spectroradiometer (MODIS) BRDF/Albedo product over the global Earth Observing System Land Validation Core Sites can be used to simplify BRDF models. The present study attempts to evaluate the representativeness of BRDF archetypes for surface reflectance anisotropy. Five-year forward-modeled MODIS multi-angular reflectance (MCD-ref) and aditional actual MODIS multi-angular observat...

Assessment of biases in MODIS surface reflectance due to Lambertian approximation

Energy Technology Data Exchange (ETDEWEB)

Cook, Robert B [ORNL; SanthanaVannan, Suresh K [ORNL

2010-08-01

Using MODIS data and the AERONET-based Surface Reflectance Validation Network (ASRVN), this work studies errors of MODIS atmospheric correction caused by the Lambertian approximation. On one hand, this approximation greatly simplifies the radiative transfer model, reduces the size of the look-up tables, and makes operational algorithm faster. On the other hand, uncompensated atmospheric scattering caused by Lambertian model systematically biases the results. For example, for a typical bowl-shaped bidirectional reflectance distribution function (BRDF), the derived reflectance is underestimated at high solar or view zenith angles, where BRDF is high, and is overestimated at low zenith angles where BRDF is low. The magnitude of biases grows with the amount of scattering in the atmosphere, i.e., at shorter wavelengths and at higher aerosol concentration. The slope of regression of Lambertian surface reflectance vs. ASRVN bidirectional reflectance factor (BRF) is about 0.85 in the red and 0.6 in the green bands. This error propagates into the MODIS BRDF/albedo algorithm, slightly reducing the magnitude of overall reflectance and anisotropy of BRDF. This results in a small negative bias of spectral surface albedo. An assessment for the GSFC (Greenbelt, USA) validation site shows the albedo reduction by 0.004 in the near infrared, 0.005 in the red, and 0.008 in the green MODIS bands.

Bi-directional reflectance distribution function of a tungsten block for ITER divertor

International Nuclear Information System (INIS)

Iwamae, Atsushi; Ogawa, Hiroaki; Sugie, Tatsuo; Kusama, Yoshinori

2012-02-01

In order to investigate reflection properties on plasma-facing material in ITER, the bi-directional reflectance distribution function (BRDF) of a tungsten block sample has been measured. On the machining surface of the block, one-directional machining lines are engraved. Two laser diodes λ652 nm and λ473 nm were used to simulate H α and H β emissions, respectively. The reflected light is affected by the machining surface. The reflected light traces an arc when the incident light is injected in the parallel direction to the engraved line. On the other hand the reflected light traces a line shape when the incident light is injected in the perpendicular direction to the engraved lines. Ray tracing simulation qualitatively explains the experimental results. (author)

Reflectance variability of surface coatings reveals characteristic eigenvalue spectra

Science.gov (United States)

Medina, José M.; Díaz, José A.; Barros, Rui

2012-10-01

We have examined the trial-to-trial variability of the reflectance spectra of surface coatings containing effect pigments. Principal component analysis of reflectances was done at each detection angle separately. A method for classification of principal components is applied based on the eigenvalue spectra. It was found that the eigenvalue spectra follow characteristic power laws and depend on the detection angle. Three different subsets of principal components were examined to separate the relevant spectral features related to the pigments from other noise sources. Reconstruction of the reflectance spectra by taking only the first subset indicated that reflectance variability was higher at near-specular reflection, suggesting a correlation with the trial-to-trial deposition of effect pigments. Reconstruction by using the second subset indicates that variability was higher at short wavelengths. Finally, reconstruction by using only the third subset indicates that reflectance variability was not totally random as a function of the wavelength. The methods employed can be useful in the evaluation of color variability in industrial paint application processes.

Solar flux incident on an orbiting surface after reflection from a planet

Science.gov (United States)

Modest, M. F.

1980-01-01

Algorithms describing the solar radiation impinging on an infinitesimal surface after reflection from a gray and diffuse planet are derived. The following conditions apply: only radiation from the sunny half of the planet is taken into account; the radiation must fall on the top of the orbiting surface, and radiation must come from that part of the planet that can be seen from the orbiting body. A simple approximate formula is presented which displays excellent accuracy for all significant situations, with an error which is always less than 5% of the maximum possible reflected flux. Attention is also given to solar albedo flux on a surface directly facing the planet, the influence of solar position on albedo flux, and to solar albedo flux as a function of the surface-planet tilt angle.

Bidirectional reflectance distribution function of Spectralon white reflectance standard illuminated by incoherent unpolarized and plane-polarized light.

Science.gov (United States)

Bhandari, Anak; Hamre, Børge; Frette, Øvynd; Zhao, Lu; Stamnes, Jakob J; Kildemo, Morten

2011-06-01

A Lambert surface would appear equally bright from all observation directions regardless of the illumination direction. However, the reflection from a randomly scattering object generally has directional variation, which can be described in terms of the bidirectional reflectance distribution function (BRDF). We measured the BRDF of a Spectralon white reflectance standard for incoherent illumination at 405 and 680 nm with unpolarized and plane-polarized light from different directions of incidence. Our measurements show deviations of the BRDF for the Spectralon white reflectance standard from that of a Lambertian reflector that depend both on the angle of incidence and the polarization states of the incident light and detected light. The non-Lambertian reflection characteristics were found to increase more toward the direction of specular reflection as the angle of incidence gets larger.

Unmanned aerial system nadir reflectance and MODIS nadir BRDF-adjusted surface reflectances intercompared over Greenland

Science.gov (United States)

Faulkner Burkhart, John; Kylling, Arve; Schaaf, Crystal B.; Wang, Zhuosen; Bogren, Wiley; Storvold, Rune; Solbø, Stian; Pedersen, Christina A.; Gerland, Sebastian

2017-07-01

Albedo is a fundamental parameter in earth sciences, and many analyses utilize the Moderate Resolution Imaging Spectroradiometer (MODIS) bidirectional reflectance distribution function (BRDF)/albedo (MCD43) algorithms. While derivative albedo products have been evaluated over Greenland, we present a novel, direct comparison with nadir surface reflectance collected from an unmanned aerial system (UAS). The UAS was flown from Summit, Greenland, on 210 km transects coincident with the MODIS sensor overpass on board the Aqua and Terra satellites on 5 and 6 August 2010. Clear-sky acquisitions were available from the overpasses within 2 h of the UAS flights. The UAS was equipped with upward- and downward-looking spectrometers (300-920 nm) with a spectral resolution of 10 nm, allowing for direct integration into the MODIS bands 1, 3, and 4. The data provide a unique opportunity to directly compare UAS nadir reflectance with the MODIS nadir BRDF-adjusted surface reflectance (NBAR) products. The data show UAS measurements are slightly higher than the MODIS NBARs for all bands but agree within their stated uncertainties. Differences in variability are observed as expected due to different footprints of the platforms. The UAS data demonstrate potentially large sub-pixel variability of MODIS reflectance products and the potential to explore this variability using the UAS as a platform. It is also found that, even at the low elevations flown typically by a UAS, reflectance measurements may be influenced by haze if present at and/or below the flight altitude of the UAS. This impact could explain some differences between data from the two platforms and should be considered in any use of airborne platforms.

ASTER L2 Surface Reflectance SWIR and ASTER L2 Surface Reflectance VNIR V003

Data.gov (United States)

National Aeronautics and Space Administration — The ASTER L2 Surface Reflectance is a multi-file product that contains atmospherically corrected data for both the Visible Near-Infrared (VNIR) and Shortwave...

Energy loss of MeV protons specularly reflected from metal surfaces

International Nuclear Information System (INIS)

Juaristi, J.I.; Garcia de Abajo, F.J.; Echenique, P.M.

1996-01-01

A parameter-free model is presented to study the energy loss of fast protons specularly reflected from metal surfaces. The contributions to the energy loss from excitation of valence-band electrons and ionization of localized target-atom electronic states are calculated separately. The former is calculated from the induced surface wake potential using linear response theory and the specular-reflection model, while the latter is calculated in the first Born approximation. The results obtained are in good agreement with available experimental data. However, the experimental qualitative trend of the energy loss as a function of the angle of incidence is obtained when the valence-band electron model is replaced by localized target atom electron states, though with a worse quantitative agreement. copyright 1996 The American Physical Society

Wavelength dependence of the bidirectional reflectance distribution function (BRDF) of beach sands.

Science.gov (United States)

Doctor, Katarina Z; Bachmann, Charles M; Gray, Deric J; Montes, Marcos J; Fusina, Robert A

2015-11-01

The wavelength dependence of the dominant directional reflective properties of beach sands was demonstrated using principal component analysis and the related correlation matrix. In general, we found that the hyperspectral bidirectional reflectance distribution function (BRDF) of beach sands has weak wavelength dependence. Its BRDF varies slightly in three broad wavelength regions. The variations are more evident in surfaces of greater visual roughness than in smooth surfaces. The weak wavelength dependence of the BRDF of beach sand can be captured using three broad wavelength regions instead of hundreds of individual wavelengths.

X-ray reflectivity and surface roughness

International Nuclear Information System (INIS)

Ocko, B.M.

1988-01-01

Since the advent of high brightness synchrotron radiation sources there has been a phenomenal growth in the use of x-rays as a probe of surface structure. The technique of x-ray reflectivity is particularly relevant to electrochemists since it is capable of probing the structure normal to an electrode surface in situ. In this paper the theoretical framework for x-ray reflectivity is reviewed and the results from previous non-electrochemistry measurements are summarized. These measurements are from the liquid/air interface (CCl 4 ), the metal crystal vacuum interface (Au(100)), and from the liquid/solid interface(liquid crystal/silicon). 34 refs., 5 figs

Modeling Bidirectional Reflectance Distribution Function of One-dimensional Random Rough Surfaces with the Finite Difference Time Domain Method

Directory of Open Access Journals (Sweden)

Min-Jhong Gu

2014-08-01

Full Text Available This article describes the development of a suite of programs that is capable of simulating the radiation properties of a random rough surface (RRS. The fundamental approach involves the generation, by fast Fourier transform (FFT built with rigorous finite difference time domain (FDTD, as the theoretical basis for the simulation of a bidirectional reflectance distribution function (BRDF of the RRS. The results are compared with the measurements and modeling of existing work to verify the feasibility of customized programming. It was found that the results of this study were a better match to the measurement data than those achieved in other modeling work.

Computation of Mach reflection from rigid and yielding surfaces

International Nuclear Information System (INIS)

Buckingham, A.C.; Wilson, S.S.

1976-01-01

The present discussion centers on a theoretical description of one aspect of the irregular or Mach reflection from solid surfaces. The discussion is restricted to analytical considerations and some preliminary results using model approximations to the surface interaction phenomena. Currently, full numerical simulations of the irregular reflection surface interaction dynamics have not been obtained since the method is still under development. Discussion of the numerical method is, therefore, restricted to some special procedures for the gas-solid surface boundary dynamics. The discussion is divided into an introductory section briefly describing a particular Mach reflection process. Subsequently, some of the considerations on boundary conditions are submitted for numerical treatment of the gas-solid interface. Analysis and discussion of a yielding solid surface subjected to impulsive loading from an intense gas shock wave follows. This is used as a guide for the development of the numerical procedure. Mach reflection processes are then briefly reviewed with special attention for similitude and singular perturbation features

Simulation Tool for GNSS Ocean Surface Reflections

DEFF Research Database (Denmark)

Høeg, Per; von Benzon, Hans-Henrik; Durgonics, Tibor

2015-01-01

GNSS coherent and incoherent reflected signals have the potential of deriving large scale parameters of ocean surfaces, as barotropic variability, eddy currents and fronts, Rossby waves, coastal upwelling, mean ocean surfaceheights, and patterns of the general ocean circulation. In the reflection...... zone the measurements may deriveparameters as sea surface roughness, winds, waves, heights and tilts from the spectral measurements. Previous measurements from the top of mountains and airplanes have shown such results leading.The coming satellite missions, CYGNSS, COSMIC-2, and GEROS...

On the reflection point where light reflects to a known destination on quadratic surfaces.

Science.gov (United States)

Gonçalves, Nuno

2010-01-15

We address the problem of determining the reflection point on a specular surface where a light ray that travels from a source to a target is reflected. The specular surfaces considered are those expressed by a quadratic equation. So far, there is no closed form explicit equation for the general solution of this determination of the reflection point, and the usual approach is to use the Snell law or the Fermat principle whose equations are derived in multidimensional nonlinear minimizations. We prove in this Letter that one can impose a set of three restrictions to the reflection point that can impose a set of three restrictions that culminates in a very elegant formalism of searching the reflection point in a unidimensional curve in space. This curve is the intersection of two quadratic equations. Some applications of this framework are also discussed.

Reflectance Modeling

Science.gov (United States)

Smith, J. A.; Cooper, K.; Randolph, M.

1984-01-01

A classical description of the one dimensional radiative transfer treatment of vegetation canopies was completed and the results were tested against measured prairie (blue grama) and agricultural canopies (soybean). Phase functions are calculated in terms of directly measurable biophysical characteristics of the canopy medium. While the phase functions tend to exhibit backscattering anisotropy, their exact behavior is somewhat more complex and wavelength dependent. A Monte Carlo model was developed that treats soil surfaces with large periodic variations in three dimensions. A photon-ray tracing technology is used. Currently, the rough soil surface is described by analytic functions and appropriate geometric calculations performed. A bidirectional reflectance distribution function is calculated and, hence, available for other atmospheric or canopy reflectance models as a lower boundary condition. This technique is used together with an adding model to calculate several cases where Lambertian leaves possessing anisotropic leaf angle distributions yield non-Lambertian reflectance; similar behavior is exhibited for simulated soil surfaces.

Use of reflective surfaces on roadway embankment

DEFF Research Database (Denmark)

Jørgensen, Anders Stuhr; Doré, Guy

2007-01-01

adherence characteristics for roadway use. In Kangerlussuaq Airport, western Greenland, ground-penetrating radar (GPR) has been used to compare the variation of the frost table underneath a normal black asphalt surface and a more reflective surface (white paint). The GPR results have shown a clear...

Plasmonic reflectance anisotropy spectroscopy of metal nanoparticles on a semiconductor surface

Science.gov (United States)

Kosobukin, V. A.; Korotchenkov, A. V.

2016-12-01

A theory of plasmonic differential anisotropic reflection of light from nanoparticles located near the interface between media is developed. The model of a monolayer consisting of identical ellipsoidal metal particles occupying sites of a rectangular lattice is investigated. Effective plasmonic polarizabilities of nanoparticles in the layer are calculated self-consistently using the Green's function technique in the quasipoint dipole approximation. The local-field effect caused by anisotropic dipole plasmons of particles in the layer and their image dipoles is taken into account. The lately observed resonant reflectance anisotropy spectra of indium nanoclusters on InAs surface are explained by the difference between frequencies of plasmons with the orthogonal polarizations in the surface plane. The difference between the plasmon frequencies is attributed to anisotropy of the particles shape or/and the layer structure; the signs of frequency difference for the two types of anisotropy being different.

Retrieval and Validation of aerosol optical properties from AHI measurements: impact of surface reflectance assumption

Science.gov (United States)

Lim, H.; Choi, M.; Kim, J.; Go, S.; Chan, P.; Kasai, Y.

2017-12-01

This study attempts to retrieve the aerosol optical properties (AOPs) based on the spectral matching method, with using three visible and one near infrared channels (470, 510, 640, 860nm). This method requires the preparation of look-up table (LUT) approach based on the radiative transfer modeling. Cloud detection is one of the most important processes for guaranteed quality of AOPs. Since the AHI has several infrared channels, which are very advantageous for cloud detection, clouds can be removed by using brightness temperature difference (BTD) and spatial variability test. The Yonsei Aerosol Retrieval (YAER) algorithm is basically utilized on a dark surface, therefore a bright surface (e.g., desert, snow) should be removed first. Then we consider the characteristics of the reflectance of land and ocean surface using three visible channels. The known surface reflectivity problem in high latitude area can be solved in this algorithm by selecting appropriate channels through improving tests. On the other hand, we retrieved the AOPs by obtaining the visible surface reflectance using NIR to normalized difference vegetation index short wave infrared (NDVIswir) relationship. ESR tends to underestimate urban and cropland area, we improved the visible surface reflectance considering urban effect. In this version, ocean surface reflectance is using the new cox and munk method which considers ocean bidirectional reflectance distribution function (BRDF). Input of this method has wind speed, chlorophyll, salinity and so on. Based on validation results with the sun-photometer measurement in AErosol Robotic NETwork (AERONET), we confirm that the quality of Aerosol Optical Depth (AOD) from the YAER algorithm is comparable to the product from the Japan Aerospace Exploration Agency (JAXA) retrieval algorithm. Our future update includes a consideration of improvement land surface reflectance by hybrid approach, and non-spherical aerosols. This will improve the quality of YAER

Influence of Aerosols And Surface Reflectance On NO2 Retrieval Over China From 2005 to 2015

Science.gov (United States)

Liu, M.; Lin, J.

2016-12-01

Satellite observation is a powerful way to analysis annual and seasonal variations of nitrogen dioxide (NO2). However, much retrieval of vertical column densities (VCDs) of normally do not explicitly account for aerosol optical effects and surface reflectance anisotropy that vary with space and time. In traditional retrieval, aerosols' effects are often considered as cloud. However, China has complicated aerosols type and aerosol loading. Their optical properties may be very different from the cloud. Furthermore, China has undergone big changes in land use type in recent 10 years. Traditional climatology surface reflectance data may not have representation. In order to study spatial-temporal variation of and influences of these two factors on variations and trends, we use an improved retrieval method of VCDs over China, called the POMINO, based on measurements from the Ozone Monitoring Instrument (OMI), and we compare the results of without aerosol, without surface reflectance treatments and without both to the original POMINO product from 2005 to 2015. Furthermore, we will study correspondent spatial-temporal variations of aerosols, represented by MODIS aerosol optical depth (AOD) data and CALIOP extinction data; surface reflectance, represented by MODIS bidirectional reflectance distribution function (BRDF) data.

Exploration of a Polarized Surface Bidirectional Reflectance Model Using the Ground-Based Multiangle SpectroPolarimetric Imager

Directory of Open Access Journals (Sweden)

David J. Diner

2012-12-01

Full Text Available Accurate characterization of surface reflection is essential for retrieval of aerosols using downward-looking remote sensors. In this paper, observations from the Ground-based Multiangle SpectroPolarimetric Imager (GroundMSPI are used to evaluate a surface polarized bidirectional reflectance distribution function (PBRDF model. GroundMSPI is an eight-band spectropolarimetric camera mounted on a rotating gimbal to acquire pushbroom imagery of outdoor landscapes. The camera uses a very accurate photoelastic-modulator-based polarimetric imaging technique to acquire Stokes vector measurements in three of the instrument’s bands (470, 660, and 865 nm. A description of the instrument is presented, and observations of selected targets within a scene acquired on 6 January 2010 are analyzed. Data collected during the course of the day as the Sun moved across the sky provided a range of illumination geometries that facilitated evaluation of the surface model, which is comprised of a volumetric reflection term represented by the modified Rahman-Pinty-Verstraete function plus a specular reflection term generated by a randomly oriented array of Fresnel-reflecting microfacets. While the model is fairly successful in predicting the polarized reflection from two grass targets in the scene, it does a poorer job for two manmade targets (a parking lot and a truck roof, possibly due to their greater degree of geometric organization. Several empirical adjustments to the model are explored and lead to improved fits to the data. For all targets, the data support the notion of spectral invariance in the angular shape of the unpolarized and polarized surface reflection. As noted by others, this behavior provides valuable constraints on the aerosol retrieval problem, and highlights the importance of multiangle observations.

Unmanned aerial system nadir reflectance and MODIS nadir BRDF-adjusted surface reflectances intercompared over Greenland

Directory of Open Access Journals (Sweden)

J. F. Burkhart

2017-07-01

Full Text Available Albedo is a fundamental parameter in earth sciences, and many analyses utilize the Moderate Resolution Imaging Spectroradiometer (MODIS bidirectional reflectance distribution function (BRDF/albedo (MCD43 algorithms. While derivative albedo products have been evaluated over Greenland, we present a novel, direct comparison with nadir surface reflectance collected from an unmanned aerial system (UAS. The UAS was flown from Summit, Greenland, on 210 km transects coincident with the MODIS sensor overpass on board the Aqua and Terra satellites on 5 and 6 August 2010. Clear-sky acquisitions were available from the overpasses within 2 h of the UAS flights. The UAS was equipped with upward- and downward-looking spectrometers (300–920 nm with a spectral resolution of 10 nm, allowing for direct integration into the MODIS bands 1, 3, and 4. The data provide a unique opportunity to directly compare UAS nadir reflectance with the MODIS nadir BRDF-adjusted surface reflectance (NBAR products. The data show UAS measurements are slightly higher than the MODIS NBARs for all bands but agree within their stated uncertainties. Differences in variability are observed as expected due to different footprints of the platforms. The UAS data demonstrate potentially large sub-pixel variability of MODIS reflectance products and the potential to explore this variability using the UAS as a platform. It is also found that, even at the low elevations flown typically by a UAS, reflectance measurements may be influenced by haze if present at and/or below the flight altitude of the UAS. This impact could explain some differences between data from the two platforms and should be considered in any use of airborne platforms.

X-ray Reflectivity Study of Ionic Liquids at Electrified Surfaces

Science.gov (United States)

Chu, Miaoqi

X-ray reflectivity (XRR) versatile technique that characterize the surface structures. However, due to the lack of phase information of X-ray data, the reconstruction of electron density profile (EDP) from XRR data is an ill-posed inverse problem that requires extra attention. In Chapter 1, several key concepts in XRR data analysis are reviewed. The typical XRR data acquisition procedure and methods of modeling electron density are introduced. The widely used logarithm form of merit function is justified with mathematical deduction and numerical experiment. A scheme that generates artificial reflectivity data with theoretical statistical error but not systematical error is proposed. With the methods and schemes described in Chapter 1, simulated reflectivity data of a simple one-slab model is generated and fitted to test the efficient of EDP reconstruction. By isolating the parameters, the effects of slab width, electron density contrast and maximal wave transfer are studied individually. It?s demonstrated that best-fit/global minima, result reported by most XRR studies, don?t necessary reflect the real EDP. By contrast, mapping the merit function in the parametric space can capture much more details. Additionally, the widely accepted concept about the XRR theoretical spatial resolution (pi/q_{max}) as well the using Patterson function are brought to test. In the perspective of XRR data analysis, this chapter puts forward general rules to design and optimize XRR experiments. It also demonstrates how susceptible the fitting result will be if it?s not done carefully. In Chapter 3, the interface between hydrophobic OTS film and several solvents is studied with XRR in a transmission-cell setup. The solvents, from water, acetone, to alcohol (methanol, ethanol, 1-propanol), to alkane (pentane, hexane and heptane), vary significantly in terms of polarity and hydrogen bonding. However, the XRR data from different solvents are subtle. The methods and principles elicited in

Quality Assessment of Landsat Surface Reflectance Products Using MODIS Data

Science.gov (United States)

Feng, Min; Huang, Chengquan; Channan, Saurabh; Vermote, Eric; Masek, Jeffrey G.; Townshend, John R.

2012-01-01

Surface reflectance adjusted for atmospheric effects is a primary input for land cover change detection and for developing many higher level surface geophysical parameters. With the development of automated atmospheric correction algorithms, it is now feasible to produce large quantities of surface reflectance products using Landsat images. Validation of these products requires in situ measurements, which either do not exist or are difficult to obtain for most Landsat images. The surface reflectance products derived using data acquired by the Moderate Resolution Imaging Spectroradiometer (MODIS), however, have been validated more comprehensively. Because the MODIS on the Terra platform and the Landsat 7 are only half an hour apart following the same orbit, and each of the 6 Landsat spectral bands overlaps with a MODIS band, good agreements between MODIS and Landsat surface reflectance values can be considered indicators of the reliability of the Landsat products, while disagreements may suggest potential quality problems that need to be further investigated. Here we develop a system called Landsat-MODIS Consistency Checking System (LMCCS). This system automatically matches Landsat data with MODIS observations acquired on the same date over the same locations and uses them to calculate a set of agreement metrics. To maximize its portability, Java and open-source libraries were used in developing this system, and object-oriented programming (OOP) principles were followed to make it more flexible for future expansion. As a highly automated system designed to run as a stand-alone package or as a component of other Landsat data processing systems, this system can be used to assess the quality of essentially every Landsat surface reflectance image where spatially and temporally matching MODIS data are available. The effectiveness of this system was demonstrated using it to assess preliminary surface reflectance products derived using the Global Land Survey (GLS) Landsat

Reflection of illumination laser from gas metal arc weld pool surface

International Nuclear Information System (INIS)

Ma, Xiaoji; Zhang, YuMing

2009-01-01

The weld pool is the core of the welding process where complex welding phenomena originate. Skilled welders acquire their process feedback primarily from the weld pool. Observation and measurement of the three-dimensional weld pool surface thus play a fundamental role in understanding and future control of complex welding processes. To this end, a laser line is projected onto the weld pool surface in pulsed gas metal arc welding (GMAW) and an imaging plane is used to intercept its reflection from the weld pool surface. Resultant images of the reflected laser are analyzed and it is found that the weld pool surface in GMAW does specularly reflect the projected laser as in gas tungsten arc welding (GTAW). Hence, the weld pool surface in GMAW is also specular and it is in principle possible that it may be observed and measured by projecting a laser pattern and then intercepting and imaging the reflection from it. Due to high frequencies of surface fluctuations, GMAW requires a relatively short time to image the reflected laser

Effect of reflective surfaces on a greenhouse lettuce crop

Energy Technology Data Exchange (ETDEWEB)

Warman, P.R.; Mayhew, W.J.

1979-01-01

The Canadian greenhouse industry is an important segment of horticultural production, providing employment for thousands of people. Continuing increases in the costs of conventional fuel supplies, however, has placed the industry in some jeopardy since the cost of heating during the winter months is also escalating. In response to this problem the Brace Research Institute has developed a single roofed greenhouse designed to capture and store the sun's energy, and to increase the amount of downward solar radiation inside the greenhouse through the use of specularly-reflecting back and side walls. The research investigated the effect of a reflective surface on plant growth, development, and nutritional uptake during fall and the early months of winter. The inside walls of the greenhouse were lined with aluminized polyester to act as a reflective surface and flat black roofing felt paper to provide a non-reflecting surface. Grand Rapids Forcing lettuce was planted from seed into a peat-vermiculite bed and total solar radiation was monitored on the horizontal. Over the duration of the experiment, the reflective side of the greenhouse received more than twice as much solar radiation as the non-reflective side leading to significantly larger plant yields on the reflective side. There were no significant differences in the uptake of the plant macronutrients, N, P, K, Ca, and Mg.

Tunable natural nano-arrays : controlling surface properties and light reflectance

International Nuclear Information System (INIS)

Watson, J.A.; Myhra, S.; Cribb, B.W.; Hope, G.A.; Watson, G.S.

2005-01-01

A sudden transition or impedance mismatch from one optical medium to another can result in unwanted reflections from the surface plane. Modification of a surface by creation of a gradual change in refractive index over a significant portion of a wavelength range will result in a reduction in reflection. Multi-layered thin film coatings based on this phenomenon are widely used on a number of different surfaces (e.g. solar cells, lenses, display screens etc.) to suppress undesired reflections and/or increase light transmittance. An alternative surface modification to the multi-layered stack coating (gradient index coating) is to produce a surface with structures having a period and heights shorter than the light wavelength. These structures act like a pseudo-gradient index coating and can be described by the effective medium theory. In this study we report on nano-structures (a natural pseudo-gradient index coating) which we have found on certain species of cicada wings demonstrating their reflective effectiveness using manipulative atomic force microscopy. (author). 2 refs., 5 figs

SO2 frost - UV-visible reflectivity and Io surface coverage

Science.gov (United States)

Nash, D. B.; Fanale, F. P.; Nelson, R. M.

1980-01-01

The reflectance spectrum in the range 0.24-0.85 microns of SO2 frost is measured in light of the discovery of SO2 gas in the atmosphere of Io and the possible discovery of the frost on its surface. Frost deposits up to 1.5 mm thick were grown in vacuum at 130 K and bi-directional reflectance spectra were obtained. Typical SO2 frost is found to exhibit very low reflectivity (2-5%) at 0.30 microns, rising steeply at 0.32 microns to attain a maximum reflectivity (75-80%) at 4.0 microns and uniformly high reflectivity throughout the visible and near infrared. Comparison with the full disk spectrum of Io reveals that no more than 20% of the surface can be covered with optically thick SO2 frost. Combinations of surface materials including SO2 frost which can produce the observed spectrum are indicated.

Characterizing Land Surface Anisotropic Reflectance over Rugged Terrain: A Review of Concepts and Recent Developments

Directory of Open Access Journals (Sweden)

Jianguang Wen

2018-02-01

Full Text Available Rugged terrain, including mountains, hills, and some high lands are typical land surfaces around the world. As a physical parameter for characterizing the anisotropic reflectance of the land surface, the importance of the bidirectional reflectance distribution function (BRDF has been gradually recognized in the remote sensing community, and great efforts have been dedicated to build BRDF models over various terrain types. However, on rugged terrain, the topography intensely affects the shape and magnitude of the BRDF and creates challenges in modeling the BRDF. In this paper, after a brief introduction of the theoretical background of the BRDF over rugged terrain, the status of estimating land surface BRDF properties over rugged terrain is comprehensively reviewed from a historical perspective and summarized in two categories: BRDFs describing solo slopes and those describing composite slopes. The discussion focuses on land surface reflectance retrieval over mountainous areas, the difference in solo slope and composite slope BRDF models, and suggested future research to improve the accuracy of BRDFs derived with remote sensing satellites.

Comparison of cloud optical depth and cloud mask applying BRDF model-based background surface reflectance

Science.gov (United States)

Kim, H. W.; Yeom, J. M.; Woo, S. H.

2017-12-01

Over the thin cloud region, satellite can simultaneously detect the reflectance from thin clouds and land surface. Since the mixed reflectance is not the exact cloud information, the background surface reflectance should be eliminated to accurately distinguish thin cloud such as cirrus. In the previous research, Kim et al (2017) was developed the cloud masking algorithm using the Geostationary Ocean Color Imager (GOCI), which is one of significant instruments for Communication, Ocean, and Meteorology Satellite (COMS). Although GOCI has 8 spectral channels including visible and near infra-red spectral ranges, the cloud masking has quantitatively reasonable result when comparing with MODIS cloud mask (Collection 6 MYD35). Especially, we noticed that this cloud masking algorithm is more specialized in thin cloud detections through the validation with Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) data. Because this cloud masking method was concentrated on eliminating background surface effects from the top-of-atmosphere (TOA) reflectance. Applying the difference between TOA reflectance and the bi-directional reflectance distribution function (BRDF) model-based background surface reflectance, cloud areas both thick cloud and thin cloud can be discriminated without infra-red channels which were mostly used for detecting clouds. Moreover, when the cloud mask result was utilized as the input data when simulating BRDF model and the optimized BRDF model-based surface reflectance was used for the optimized cloud masking, the probability of detection (POD) has higher value than POD of the original cloud mask. In this study, we examine the correlation between cloud optical depth (COD) and its cloud mask result. Cloud optical depths mostly depend on the cloud thickness, the characteristic of contents, and the size of cloud contents. COD ranges from less than 0.1 for thin clouds to over 1000 for the huge cumulus due to scattering by droplets. With

Noninvasive assessment of articular cartilage surface damage using reflected polarized light microscopy

Science.gov (United States)

Huynh, Ruby N.; Nehmetallah, George; Raub, Christopher B.

2017-06-01

Articular surface damage occurs to cartilage during normal aging, osteoarthritis, and in trauma. A noninvasive assessment of cartilage microstructural alterations is useful for studies involving cartilage explants. This study evaluates polarized reflectance microscopy as a tool to assess surface damage to cartilage explants caused by mechanical scraping and enzymatic degradation. Adult bovine articular cartilage explants were scraped, incubated in collagenase, or underwent scrape and collagenase treatments. In an additional experiment, cartilage explants were subject to scrapes at graduated levels of severity. Polarized reflectance parameters were compared with India ink surface staining, features of histological sections, changes in explant wet weight and thickness, and chondrocyte viability. The polarized reflectance signal was sensitive to surface scrape damage and revealed individual scrape features consistent with India ink marks. Following surface treatments, the reflectance contrast parameter was elevated and correlated with image area fraction of India ink. After extensive scraping, polarized reflectance contrast and chondrocyte viability were lower than that from untreated explants. As part of this work, a mathematical model was developed and confirmed the trend in the reflectance signal due to changes in surface scattering and subsurface birefringence. These results demonstrate the effectiveness of polarized reflectance microscopy to sensitively assess surface microstructural alterations in articular cartilage explants.

Antarctic Surface Reflectivity Measurements from the ANITA-3 and HiCal-1 Experiments

Science.gov (United States)

Gorham, P. W.; Allison, P.; Banerjee, O.; Beatty, J. J.; Belov, K.; Besson, D. Z.; Binns, W. R.; Bugaev, V.; Cao, P.; Chen, C.; Chen, P.; Clem, J. M.; Connolly, A.; Dailey, B.; Dasgupta, P.; Deaconu, C.; Cremonesi, L.; Dowkontt, P. F.; Fox, B. D.; Gordon, J.; Hill, B.; Hupe, R.; Israel, M. H.; Jain, P.; Kowalski, J.; Lam, J.; Learned, J. G.; Liewer, K. M.; Liu, T. C.; Matsuno, S.; Miki, C.; Mottram, M.; Mulrey, K.; Nam, J.; Nichol, R. J.; Novikov, A.; Oberla, E.; Prohira, S.; Rauch, B. F.; Romero-Wolf, A.; Rotter, B.; Ratzlaff, K.; Russell, J.; Saltzberg, D.; Seckel, D.; Schoorlemmer, H.; Stafford, S.; Stockham, J.; Stockham, M.; Strutt, B.; Tatem, K.; Varner, G. S.; Vieregg, A. G.; Wissel, S. A.; Wu, F.; Young, R.

The primary science goal of the NASA-sponsored ANITA project is measurement of ultra-high energy neutrinos and cosmic rays, observed via radio-frequency signals resulting from a neutrino or cosmic ray interaction with terrestrial matter (e.g. atmospheric or ice molecules). Accurate inference of the energies of these cosmic rays requires understanding the transmission/reflection of radio wave signals across the ice-air boundary. Satellite-based measurements of Antarctic surface reflectivity, using a co-located transmitter and receiver, have been performed more-or-less continuously for the last few decades. Our comparison of four different reflectivity surveys, at frequencies ranging from 2 to 45GHz and at near-normal incidence, yield generally consistent maps of high versus low reflectivity, as a function of location, across Antarctica. Using the Sun as an RF source, and the ANITA-3 balloon borne radio-frequency antenna array as the RF receiver, we have also measured the surface reflectivity over the interval 200-1000MHz, at elevation angles of 12-30∘. Consistent with our previous measurement using ANITA-2, we find good agreement, within systematic errors (dominated by antenna beam width uncertainties) and across Antarctica, with the expected reflectivity as prescribed by the Fresnel equations. To probe low incidence angles, inaccessible to the Antarctic Solar technique and not probed by previous satellite surveys, a novel experimental approach (“HiCal-1”) was devised. Unlike previous measurements, HiCal-ANITA constitute a bi-static transmitter-receiver pair separated by hundreds of kilometers. Data taken with HiCal, between 200 and 600MHz shows a significant departure from the Fresnel equations, constant with frequency over that band, with the deficit increasing with obliquity of incidence, which we attribute to the combined effects of possible surface roughness, surface grain effects, radar clutter and/or shadowing of the reflection zone due to Earth

Evaluation of BRDF Archetypes for Representing Surface Reflectance Anisotropy Using MODIS BRDF Data

Directory of Open Access Journals (Sweden)

Hu Zhang

2015-06-01

Full Text Available Bidirectional reflectance distribution function (BRDF archetypes extracted from the Moderate Resolution Imaging Spectroradiometer (MODIS BRDF/Albedo product over the global Earth Observing System Land Validation Core Sites can be used to simplify BRDF models. The present study attempts to evaluate the representativeness of BRDF archetypes for surface reflectance anisotropy. Five-year forward-modeled MODIS multi-angular reflectance (MCD-ref and aditional actual MODIS multi-angular observations (MCD-obs in four growing periods in 2008 over three tiles were taken as validation data. First, BRDF archetypes in the principal plane were qualitatively compared with the time-series MODIS BRDF product of randomly sampled pixels. Secondly, BRDF archetypes were used to fit MCD-ref, and the average root-mean-squared errors (RMSEs over each tile were examined for these five years. Finally, both BRDF archetypes and the MODIS BRDF were used to fit MCD-obs, and the histograms of the fit-RMSEs were compared. The consistency of the directional reflectance between the BRDF archetypes and MODIS BRDFs in nadir-view, hotspot and entire viewing hemisphere at 30° and 50° solar geometries were also examined. The results confirm that BRDF archetypes are representative of surface reflectance anisotropy for available snow-free MODIS data.

Calculation of Reflectance and Transmittance of Coating With Optically Rough Surfaces

International Nuclear Information System (INIS)

El-Depsy, A.; Shawky, A.M.

2011-01-01

For ideal surfaces, components of the reflected beam are related to the components of the incident beam by Fresnel reflection equation. The surfaces encountered in engineering applications deviate from ideal as a result of roughness, oxidization and contamination; hence the Radiative properties of these real surfaces differ greatly from those predicted by electromagnetic theory. In regard to problems of radiative heat transfer; the roughness of surfaces may be divided into two categories: (1) small surface irregularities such that the incident radiation cannot undergo more than a single reflection, (2) deep cavities in which the incident radiation undergoes multi-reflection. The normally incident radiation from rough surface having small irregularities is reflected partly specularly and partly diffusely [1]. Kubelka-Munk theory (K-M) [2] describes optical characteristics (e.g. reflectance, transmittance and absorbance) by a variety of light scattering media including paints, textiles and papers, and It is widely used in various industrial applications. Moder developments in radiative transfer theory (RTT) enable the derivation of (K-M) parameters from first principles [3]. Kubelka and Munk proposed a theory based on a model of two light fluxes travelling in the forward and backward directions. Subsequently a number of authors refined the theory and compared it with experimental data [4]. Several authors attempted to relate the Kubelka- Munk coefficients to the transport coefficients [5,6

Reflectance of Antarctic surfaces from multispectral radiometers: The correction of atmospheric effects

International Nuclear Information System (INIS)

Zibordi, G.; Maracci, G.

1993-01-01

Monitoring reflectance of polar icecaps has relevance in climate studies. In fact, climate changes produce variations in the morphology of ice and snow covers, which are detectable as surface reflectance change. Surface reflectance can be retrieved from remotely sensed data. However, absolute values independent of atmospheric turbidity and surface altitude can only be obtained after removing masking effects of the atmosphere. An atmospheric correction model, accounting for surface and sensor altitudes above sea level, is described and validated through data detected over Antarctic surfaces with a Barnes Modular Multispectral Radiometer having bands overlapping those of the Landsat Thematic Mapper. The model is also applied in a sensitivity analysis to investigate error induced in reflectance obtained from satellite data by indeterminacy in optical parameters of atmospheric constituents. Results show that indeterminacy in the atmospheric water vapor optical thickness is the main source of nonaccuracy in the retrieval of surface reflectance from data remotely sensed over Antarctic regions

Full four-dimensional and reciprocal Mueller matrix bidirectional reflectance distribution function of sintered polytetrafluoroethylene.

Science.gov (United States)

Germer, Thomas A

2017-11-20

We measured the Mueller matrix bidirectional reflectance distribution function (BRDF) of a sintered polytetrafluoroethylene (PTFE) sample over the scattering hemisphere for six incident angles (0°-75° in 15° steps) and for four wavelengths (351 nm, 532 nm, 633 nm, and 1064 nm). The data for each wavelength were fit to a phenomenological description for the Mueller matrix BRDF, which is an extension of the bidirectional surface scattering modes developed by Koenderink and van Doorn [J. Opt. Soc. Am. A.15, 2903 (1998)JOAOD60740-323210.1364/JOSAA.15.002903] for unpolarized BRDF. This description is designed to be complete, to obey the appropriate reciprocity conditions, and to provide a full description of the Mueller matrix BRDF as a function of incident and scattering directions for each wavelength. The description was further extended by linearizing the surface scattering mode coefficients with wavelength. This data set and its parameterization provides a comprehensive on-demand description of the reflectance properties for this commonly used diffuse reflectance reference material over a wide range of wavelengths.

On automatic visual inspection of reflective surfaces

DEFF Research Database (Denmark)

Kulmann, Lionel

1995-01-01

surfaces, providing new and exciting applications subject to automated visual inspection. Several contextual features have been surveyed along with introduction of novel methods to perform data-dependent enhancement of local surface appearance . Morphological methods have been described and utilized......This thesis descrbes different methods to perform automatic visual inspection of reflective manufactured products, with the aim of increasing productivity, reduce cost and improve the quality level of the production. We investigate two different systems performing automatic visual inspection....... The first is the inspection of highly reflective aluminum sheets, used by the Danish company Bang & Olufsen, as a part of the exterior design and general appearance of their audio and video products. The second is the inspection of IBM hard disk read/write heads for defects during manufacturing. We have...

Reflectance spectroscopy and asteroid surface mineralogy

International Nuclear Information System (INIS)

Gaffey, M.J.; Bell, J.F.; Cruikshank, D.P.

1989-01-01

Information available from reflectance spectroscopy on the surface mineralogy of asteroids is discussed. Current spectral interpretive procedures used in the investigations of asteroid mineralogy are described. Present understanding of the nature and history of asteroids is discussed together with some still unresolved issues such as the source of ordinary chondrites. 100 refs

DETERMINING REFLECTANCE SPECTRA OF SURFACES AND CLOUDS ON EXOPLANETS

Energy Technology Data Exchange (ETDEWEB)

Cowan, Nicolas B.; Strait, Talia E., E-mail: n-cowan@northwestern.edu [Center for Interdisciplinary Exploration and Research in Astrophysics (CIERA), Northwestern University, 2131 Tech Dr., IL 60208 (United States)

2013-03-01

Planned missions will spatially resolve temperate terrestrial planets from their host star. Although reflected light from such a planet encodes information about its surface, it has not been shown how to establish surface characteristics of a planet without assuming known surfaces to begin with. We present a reanalysis of disk-integrated, time-resolved, multiband photometry of Earth obtained by the Deep Impact spacecraft as part of the EPOXI Mission of Opportunity. We extract reflectance spectra of clouds, ocean, and land without a priori knowledge of the numbers or colors of these surfaces. We show that the inverse problem of extracting surface spectra from such data is a novel and extreme instance of spectral unmixing, a well-studied problem in remote sensing. Principal component analysis is used to determine an appropriate number of model surfaces with which to interpret the data. Shrink-wrapping a simplex to the color excursions of the planet yields a conservative estimate of the planet's endmember spectra. The resulting surface maps are unphysical, however, requiring negative or larger-than-unity surface coverage at certain locations. Our ''rotational unmixing'' supersedes the endmember analysis by simultaneously solving for the surface spectra and their geographical distributions on the planet, under the assumption of diffuse reflection and known viewing geometry. We use a Markov Chain Monte Carlo to determine best-fit parameters and their uncertainties. The resulting albedo spectra are similar to clouds, ocean, and land seen through a Rayleigh-scattering atmosphere. This study suggests that future direct-imaging efforts could identify and map unknown surfaces and clouds on exoplanets.

Reflection properties of road surfaces. Contribution to OECD Scientific Expert Group AC4 on Road Surface Characteristics.

NARCIS (Netherlands)

Schreuder, D.A.

1983-01-01

Photometric characteristics of road surfaces are dealt with. Representation of reflection properties in public lighting; quality criteria of road lighting installations; classification of road surfaces; the relation between reflection characteristics and other properties of road pavements in public

Principal Components Analysis on the spectral Bidirectional Reflectance Distribution Function of ceramic colour standards.

Science.gov (United States)

Ferrero, A; Campos, J; Rabal, A M; Pons, A; Hernanz, M L; Corróns, A

2011-09-26

The Bidirectional Reflectance Distribution Function (BRDF) is essential to characterize an object's reflectance properties. This function depends both on the various illumination-observation geometries as well as on the wavelength. As a result, the comprehensive interpretation of the data becomes rather complex. In this work we assess the use of the multivariable analysis technique of Principal Components Analysis (PCA) applied to the experimental BRDF data of a ceramic colour standard. It will be shown that the result may be linked to the various reflection processes occurring on the surface, assuming that the incoming spectral distribution is affected by each one of these processes in a specific manner. Moreover, this procedure facilitates the task of interpolating a series of BRDF measurements obtained for a particular sample. © 2011 Optical Society of America

Sunlight reflection off the spacecraft with a solar sail on the surface of mars

Science.gov (United States)

Starinova, O. L.; Rozhkov, M. A.; Gorbunova, I. V.

2018-05-01

Modern technologies make it possible to fulfill many projects in the field of space exploration. One such project is the colonization of Mars and providing favorable conditions for living on it. Authors propose principles of functioning of the spacecraft with a solar sail, intended to create a thermal and light spot in a predetermined area of the Martian surface. This additional illumination can maintain and support certain climatic conditions on a small area where a Mars base could be located. This paper investigate the possibility of the spacecraft continuously reflect the sunlight off the solar sail on the small area of the Mars surface. The mathematical motion model in such condition of the solar sail's orientation is considered and used for motion simulation session. Moreover, the analysis of this motion is performed. Thus, were obtained parameters of the synchronic non-Keplerian orbit and spacecraft construction. In addition, were given recommendations for further applying satellites to reflect the sunlight on a planet's surface.

Fitness function and nonunique solutions in x-ray reflectivity curve fitting: crosserror between surface roughness and mass density

International Nuclear Information System (INIS)

Tiilikainen, J; Bosund, V; Mattila, M; Hakkarainen, T; Sormunen, J; Lipsanen, H

2007-01-01

Nonunique solutions of the x-ray reflectivity (XRR) curve fitting problem were studied by modelling layer structures with neural networks and designing a fitness function to handle the nonidealities of measurements. Modelled atomic-layer-deposited aluminium oxide film structures were used in the simulations to calculate XRR curves based on Parratt's formalism. This approach reduced the dimensionality of the parameter space and allowed the use of fitness landscapes in the study of nonunique solutions. Fitness landscapes, where the height in a map represents the fitness value as a function of the process parameters, revealed tracks where the local fitness optima lie. The tracks were projected on the physical parameter space thus allowing the construction of the crosserror equation between weakly determined parameters, i.e. between the mass density and the surface roughness of a layer. The equation gives the minimum error for the other parameters which is a consequence of the nonuniqueness of the solution if noise is present. Furthermore, the existence of a possible unique solution in a certain parameter range was found to be dependent on the layer thickness and the signal-to-noise ratio

Reflection properties of hydrogen ions at helium irradiated tungsten surfaces

International Nuclear Information System (INIS)

Doi, K; Tawada, Y; Kato, S; Sasao, M; Kenmotsu, T; Wada, M; Lee, H T; Ueda, Y; Tanaka, N; Kisaki, M; Nishiura, M; Matsumoto, Y; Yamaoka, H

2016-01-01

Nanostructured W surfaces prepared by He bombardment exhibit characteristic angular distributions of hydrogen ion reflection upon injection of 1 keV H + beam. A magnetic momentum analyzer that can move in the vacuum chamber has measured the angular dependence of the intensity and the energy of reflected ions. Broader angular distributions were observed for He-irradiated tungsten samples compared with that of the intrinsic polycrystalline W. Both intensity and energy of reflected ions decreased in the following order: the polycrystalline W, the He-bubble containing W, and the fuzz W. Classical trajectory Monte Carlo simulations based on Atomic Collision in Amorphous Target code suggests that lower atom density near the surface can make the reflection coefficients lower due to increasing number of collisions. (paper)

Internal reflection spectroscopic analysis of sulphide mineral surfaces

International Nuclear Information System (INIS)

Kaoma, J.

1989-01-01

To establish the reason for flotation of sulfide minerals in the absence of any conventional collector, internal reflection spectroscopic analysis (IRS) of their surfaces was conducted. sulfur, sulfates, thiosulfates, and hydrocarbonates have been detected on the surface of as-grand sulfide minerals. On sodium sulfide-treated surfaces, both sulfur and polysulfide have also been found to be present. From these findings, the flotation of sulfide minerals without collectors is discussed. (author). 26 refs

High quality broadband spatial reflections of slow Rayleigh surface acoustic waves modulated by a graded grooved surface

KAUST Repository

Xu, Yanlong

2015-01-21

We report high quality broadband spatial reflections of Rayleigh surface acoustic waves (SAWs) through a graded grooved surface. High quality means that no wave is allowed to transmit and the incident wave is nearly all reflected to the input side. The graded grooved surface is structured by drilling one dimensional array of graded grooves with increased depths on a flat surface. We investigate SAW dispersion relations, wave field distribution at several typical SAW wavelengths, and time evolution of a Gaussian pulse through the graded grooved surface. Results show that the input broadband Rayleigh SAWs can be slowed, spatially enhanced and stopped, and finally reflected to the input side. The study suggests that engraving the flat surface can be used as an efficient and economical way to manipulate Rayleigh SAWs, which has potential application in novel SAW devices such as filters, reflectors, sensors, energy harvesters, and diodes.

Surface composition of Mercury from reflectance spectrophotometry

Science.gov (United States)

Vilas, Faith

1988-01-01

The controversies surrounding the existing spectra of Mercury are discussed together with the various implications for interpretations of Mercury's surface composition. Special attention is given to the basic procedure used for reducing reflectance spectrophotometry data, the factors that must be accounted for in the reduction of these data, and the methodology for defining the portion of the surface contributing the greatest amount of light to an individual spectrum. The application of these methodologies to Mercury's spectra is presented.

Spectral curves of surface reflectance in some Antarctic regions

International Nuclear Information System (INIS)

Lupi, A.; Tomasi, C.; Orsini, A.; Cacciari, A.; Vitale, V.; Georgiadis, T.; Casacchia, R.; Salvatori, R.; Salvi, S.

2001-01-01

Four surface reflectance models of solar radiation were determined by examining several sets of field measurements taken for clear-sky conditions at various sites in Antarctica. Each model consists of the mean spectral curve of surface reflectance in the 0.25-2.7 μm wavelength range and of the dependence curve of total abedo on the solar elevation angle h, within the range from 5 0 to 55 0 . The TNB (Terra Nova Bay) model refers to a rocky terrain where granites are predominant; the NIS (Nansen Ice Sheet) model to a glacier surface made uneven by sastrugi and streaked by irregular fractures; the HAP (High Altitude Plateau) model to a flat ice surface covered by fresh snow and scored by light sastrugi; and the RIS (Ross Ice Shelf) model to an area covered by the sea ice pack presenting many discontinuities in the reflectance features, due to melt water lakes, puddles, refrozen ice and snow pots. The reflectance curve obtained for the TNB model presents gradually increasing values as wavelength increases through the visible spectral range and almost constant values at infrared wavelengths, giving a total albedo value equal to 0.264 at = 30 0 , which increases by about 80% through the lower range of h and decreases by 12% through the upper range. The reflectance curves of the NIS, HAP and RIS models are all peaked at visible wavelengths and exhibit decreasing values throughout the infrared spectral range, giving values of total albedo equal to 0.464, 0.738 and 0.426 at h 30 0 , respectively. These values were estimated to increase by 8-14% as h decreases from 30 0 to 5 0 and to decrease by 2-4% only as h increases from 30 0 to 55 0

Absorption and reflectivity of the lithium niobate surface masked with a graphene layer

Directory of Open Access Journals (Sweden)

O. Salas

2017-01-01

Full Text Available We performed simulations of the interaction of a graphene layer with the surface of lithium niobate utilizing density functional theory and molecular dynamics at 300K and atmospheric pressure. We found that the graphene layer is physisorbed on the lithium niobate surface with an adsorption energy of -0.8205 eV/(carbon-atom. Subsequently, the energy band structure, the optical absorption and reflectivity of the new system were calculated. We found important changes in these physical properties with respect to the corresponding ones of a graphene layer and of a lithium niobate crystal.

Attachment patterns and Reflective Functioning in Traumatized Refugees

DEFF Research Database (Denmark)

Riber, Karin

, attachment systems, emotion-regulation, and personality. Attachment research on the consequences of organized violence and forced migration is sparse and research in PTSD-treatment for refugees is lacking behind. Cumulative pre-migration traumatic experiences and ongoing post-migration stressors might lead...... Psychiatry, Denmark. June 2011-March 2012 patients fulfilling inclusion criteria entered the trial. The present sample consisted of those of the 135 patients who were Arabic-speaking (N=67). Measures involved the Adult Attachment Interview, The Reflective Functioning Scale, Revised Adult Attachment Scale...... and reflective functioning will be described and implications for psychotherapy discussed. Keywords: Adult attachment, reflective functioning, refugee traumatisation....

Simulation of reflecting surface deviations of centimeter-band parabolic space radiotelescope (SRT) with the large-size mirror

Science.gov (United States)

Kotik, A.; Usyukin, V.; Vinogradov, I.; Arkhipov, M.

2017-11-01

he realization of astrophysical researches requires the development of high-sensitive centimeterband parabolic space radiotelescopes (SRT) with the large-size mirrors. Constructively such SRT with the mirror size more than 10 m can be realized as deployable rigid structures. Mesh-structures of such size do not provide the reflector reflecting surface accuracy which is necessary for the centimeter band observations. Now such telescope with the 10 m diameter mirror is developed in Russia in the frame of "SPECTR - R" program. External dimensions of the telescope is more than the size of existing thermo-vacuum chambers used to prove SRT reflecting surface accuracy parameters under the action of space environment factors. That's why the numerical simulation turns out to be the basis required to accept the taken designs. Such modeling should be based on experimental working of the basic constructive materials and elements of the future reflector. In the article computational modeling of reflecting surface deviations of a centimeter-band of a large-sized deployable space reflector at a stage of his orbital functioning is considered. The analysis of the factors that determines the deviations - both determined (temperatures fields) and not-determined (telescope manufacturing and installation faults; the deformations caused by features of composite materials behavior in space) is carried out. The finite-element model and complex of methods are developed. They allow to carry out computational modeling of reflecting surface deviations caused by influence of all factors and to take into account the deviations correction by space vehicle orientation system. The results of modeling for two modes of functioning (orientation at the Sun) SRT are presented.

Experimental analysis of bidirectional reflectance distribution function cross section conversion term in direction cosine space.

Science.gov (United States)

Butler, Samuel D; Nauyoks, Stephen E; Marciniak, Michael A

2015-06-01

Of the many classes of bidirectional reflectance distribution function (BRDF) models, two popular classes of models are the microfacet model and the linear systems diffraction model. The microfacet model has the benefit of speed and simplicity, as it uses geometric optics approximations, while linear systems theory uses a diffraction approach to compute the BRDF, at the expense of greater computational complexity. In this Letter, nongrazing BRDF measurements of rough and polished surface-reflecting materials at multiple incident angles are scaled by the microfacet cross section conversion term, but in the linear systems direction cosine space, resulting in great alignment of BRDF data at various incident angles in this space. This results in a predictive BRDF model for surface-reflecting materials at nongrazing angles, while avoiding some of the computational complexities in the linear systems diffraction model.

The normalization of surface anisotropy effects present in SEVIRI reflectances by using the MODIS BRDF method

DEFF Research Database (Denmark)

Proud, Simon Richard; Zhang, Qingling; Schaaf, Crystal

2014-01-01

A modified version of the MODerate resolution Imaging Spectroradiometer (MODIS) bidirectional reflectance distribution function (BRDF) algorithm is presented for use in the angular normalization of surface reflectance data gathered by the Spinning Enhanced Visible and InfraRed Imager (SEVIRI...... acquisition period than the comparable MODIS products while, at the same time, removing many of the angular perturbations present within the original MSG data. The NBAR data are validated against reflectance data from the MODIS instrument and in situ data gathered at a field location in Africa throughout 2008....... It is found that the MSG retrievals are stable and are of high-quality across much of the SEVIRI disk while maintaining a higher temporal resolution than the MODIS BRDF products. However, a number of circumstances are discovered whereby the BRDF model is unable to function correctly with the SEVIRI...

Using Neural Networks to Improve the Performance of Radiative Transfer Modeling Used for Geometry Dependent Surface Lambertian-Equivalent Reflectivity Calculations

Science.gov (United States)

Fasnacht, Zachary; Qin, Wenhan; Haffner, David P.; Loyola, Diego; Joiner, Joanna; Krotkov, Nickolay; Vasilkov, Alexander; Spurr, Robert

2017-01-01

Surface Lambertian-equivalent reflectivity (LER) is important for trace gas retrievals in the direct calculation of cloud fractions and indirect calculation of the air mass factor. Current trace gas retrievals use climatological surface LER's. Surface properties that impact the bidirectional reflectance distribution function (BRDF) as well as varying satellite viewing geometry can be important for retrieval of trace gases. Geometry Dependent LER (GLER) captures these effects with its calculation of sun normalized radiances (I/F) and can be used in current LER algorithms (Vasilkov et al. 2016). Pixel by pixel radiative transfer calculations are computationally expensive for large datasets. Modern satellite missions such as the Tropospheric Monitoring Instrument (TROPOMI) produce very large datasets as they take measurements at much higher spatial and spectral resolutions. Look up table (LUT) interpolation improves the speed of radiative transfer calculations but complexity increases for non-linear functions. Neural networks perform fast calculations and can accurately predict both non-linear and linear functions with little effort.

Iterative discrete ordinates solution of the equation for surface-reflected radiance

Science.gov (United States)

Radkevich, Alexander

2017-11-01

This paper presents a new method of numerical solution of the integral equation for the radiance reflected from an anisotropic surface. The equation relates the radiance at the surface level with BRDF and solutions of the standard radiative transfer problems for a slab with no reflection on its surfaces. It is also shown that the kernel of the equation satisfies the condition of the existence of a unique solution and the convergence of the successive approximations to that solution. The developed method features two basic steps: discretization on a 2D quadrature, and solving the resulting system of algebraic equations with successive over-relaxation method based on the Gauss-Seidel iterative process. Presented numerical examples show good coincidence between the surface-reflected radiance obtained with DISORT and the proposed method. Analysis of contributions of the direct and diffuse (but not yet reflected) parts of the downward radiance to the total solution is performed. Together, they represent a very good initial guess for the iterative process. This fact ensures fast convergence. The numerical evidence is given that the fastest convergence occurs with the relaxation parameter of 1 (no relaxation). An integral equation for BRDF is derived as inversion of the original equation. The potential of this new equation for BRDF retrievals is analyzed. The approach is found not viable as the BRDF equation appears to be an ill-posed problem, and it requires knowledge the surface-reflected radiance on the entire domain of both Sun and viewing zenith angles.

Improved analytical formulas for x-ray and neutron reflection from surface films

International Nuclear Information System (INIS)

Zhou, X.; Chen, S.; Felcher, G.P.

1992-01-01

A general and exact expression for x-ray and neutron reflectance and transmittance is given in terms of an integral of the real-space scattering-length-density profile fluctuation of the film, with respect to an arbitrary constant reference density level, over the wave function inside the film. Various special cases and approximations are then derived from this exact form by suitable approximations of the wave function. In particular, two practical approximate formulas are derived which are improvement over the corresponding distorted-wave Born approximations. One is for an arbitrary film deposited on a known substrate and the other for a free liquid surface. Numerical results are used to illustrate the accuracy of these formulas

Backscattered EM-wave manipulation using low cost 1-bit reflective surface at W-band

Science.gov (United States)

Taher Al-Nuaimi, Mustafa K.; Hong, Wei; He, Yejun

2018-04-01

The design of low cost 1-bit reflective (non-absorptive) surfaces for manipulation of backscattered EM-waves and radar cross section (RCS) reduction at W-band is presented in this article. The presented surface is designed based on the reflection phase cancellation principle. The unit cell used to compose the proposed surface has an obelus (division symbol of short wire and two disks above and below) like shape printed on a grounded dielectric material. Using this unit cell, surfaces that can efficiently manipulate the backscattered RCS pattern by using the proposed obelus-shaped unit cell (as ‘0’ element) and its mirrored unit cell (as ‘1’ element) in one surface with a 180°  ±  35° reflection phase difference between their reflection phases are designed. The proposed surfaces can generate various kinds of backscattered RCS patterns, such as single, three, or four lobes or even a low-level (reduced RCS) diffused reflection pattern when those two unit cells are distributed randomly across the surface aperture. For experimental characterization purposes, a 50  ×  50 mm2 surface is fabricated and measured.

Preparation of surface conductive and highly reflective silvered polyimide films by surface modification and in situ self-metallization technique

International Nuclear Information System (INIS)

Wu Zhanpeng; Wu Dezhen; Qi Shengli; Zhang Teng; Jin Riguang

2005-01-01

Double surface conductive and reflective flexible silvered polyimide films have been prepared by alkali hydroxylation of polyimide film surface and incorporation of silver ions through subsequent ion exchange. Thermal curing of silver(I) polyamate precursor leads to re-cycloimidization of modified surface with concomitant silver reduction, yielding a reflective and conductive silver surface approaching that of native metal. The reflective and conductive surface evolves only when the cure temperature rises to 300 deg. C. The metallized films usually retain the essential mechanical properties of the parent films. Films were characterized by transmission electron microscopy (TEM), scanning electron microscopy and tapping mode atomic force microscopy (AFM). AFM demonstrates that the diameter of close-packed silver particles of the silver layers was about 50-150 nm. TEM shows that thickness of silver layer on the polyimide film surface is about 400-600 nm

Implementation of solar-reflective surfaces: Materials and utility programs

Energy Technology Data Exchange (ETDEWEB)

Bretz, S.; Akbari, H.; Rosenfeld, A.; Taha, H.

1992-06-01

This report focuses on implementation issues for using solar-reflective surfaces to cool urban heat islands, with specific examples for Sacramento, California. Advantages of solar-reflective surfaces for reducing energy use are: (1) they are cost-effective if albedo is increased during routine maintenance; (2) the energy savings coincide with peak demand for power; (3) there are positive effects on environmental quality; and (4) the white materials have a long service life. Important considerations when choosing materials for mitigating heat islands are identified as albedo, emissivity, durability, cost, pollution and appearance. There is a potential for increasing urban albedo in Sacramento by an additional 18%. Of residential roofs, we estimate that asphalt shingle and modified bitumen cover the largest area, and that built-up roofing and modified bitumen cover the largest area of commercial buildings. For all of these roof types, albedo may be increased at the time of re-roofing without any additional cost. When a roof is repaired, a solar-reflective roof coating may be applied to significantly increase albedo and extend the life of the root Although a coating may be cost-effective if applied to a new roof following installation or to an older roof following repair, it is not cost-effective if the coating is applied only to save energy. Solar-reflective pavement may be cost-effective if the albedo change is included in the routine resurfacing schedule. Cost-effective options for producing light-colored pavement may include: (1) asphalt concrete, if white aggregate is locally available; (2) concrete overlays; and (3) newly developed white binders and aggregate. Another option may be hot-rolled asphalt, with white chippings. Utilities could promote solar-reflective surfaces through advertisement, educational programs and cost-sharing of road resurfacing.

Surface reflectance of Antarctic bryophytes and protection from UV and visible light

International Nuclear Information System (INIS)

Robinson, S.A.; Wasley, J.; Turnbull, J.

2000-01-01

Full text: As well as determining the amount of solar radiation available for photosynthesis, the surface reflectance and absorptance characteristics of plants are their first defence against damaging effects of solar radiation. The solar spectrum can be damaging to plants in many ways. At shorter wavelengths, UV-B (280-320 nm) radiation can cause lesions in nucleic acid and proteins. Excess levels of visible radiation (400-750) can cause photoinhibition whilst high absorbtance of longer wavelengths (>750) leads to increases in temperature that can be detrimental in some environments. The adaptation of surface reflectance properties of vascular plants to particular environments are well known in some ecosystems. For example in desert ecosystems pubescent leaf surfaces that increase reflectance are common and have been demonstrated to be important to protection from photoinhibition. The epidermal characteristics of some plants are also known to change in absorptance, due to the accumulation of specific compounds. For example flavonoids which are effective screens against UV-B radiation, increase upon exposure to UV-B radiation. In this study we surveyed the natural variability in surface reflectance in mosses growing in continental Antarctica. Antarctica is experiencing large increases in incident UV-B radiation due to reductions in concentrations of stratospheric ozone. Additionally over the summer months (November January), when moss is exposed to direct sunlight, levels of visible solar radiation are also high, increasing the likelihood of photoinhibitory damage in moss. Our aim in this study is to describe the natural variability in the surface reflectance characteristics of moss, such that we have a baseline with which to assess future changes in response to changes in global climate, and imposed experimental treatments, and also to develop hypotheses with respect to how mosses have adapted to the cold and arid antarctic environment. Variability in surface

Developmental prosopagnosia and super-recognition: no special role for surface reflectance processing.

Science.gov (United States)

Russell, Richard; Chatterjee, Garga; Nakayama, Ken

2012-01-01

Face recognition by normal subjects depends in roughly equal proportions on shape and surface reflectance cues, while object recognition depends predominantly on shape cues. It is possible that developmental prosopagnosics are deficient not in their ability to recognize faces per se, but rather in their ability to use reflectance cues. Similarly, super-recognizers' exceptional ability with face recognition may be a result of superior surface reflectance perception and memory. We tested this possibility by administering tests of face perception and face recognition in which only shape or reflectance cues are available to developmental prosopagnosics, super-recognizers, and control subjects. Face recognition ability and the relative use of shape and pigmentation were unrelated in all the tests. Subjects who were better at using shape or reflectance cues were also better at using the other type of cue. These results do not support the proposal that variation in surface reflectance perception ability is the underlying cause of variation in face recognition ability. Instead, these findings support the idea that face recognition ability is related to neural circuits using representations that integrate shape and pigmentation information. Copyright © 2011 Elsevier Ltd. All rights reserved.

Nanoscale silver-assisted wet etching of crystalline silicon for anti-reflection surface textures.

Science.gov (United States)

Li, Rui; Wang, Shuling; Chuwongin, Santhad; Zhou, Weidong

2013-01-01

We report here an electro-less metal-assisted chemical etching (MacEtch) process as light management surface-texturing technique for single crystalline Si photovoltaics. Random Silver nanostructures were formed on top of the Si surface based on the thin film evaporation and annealing process. Significant reflection reduction was obtained from the fabricated Si sample, with approximately 2% reflection over a wide spectra range (300 to 1050 nm). The work demonstrates the potential of MacEtch process for anti-reflection surface texture fabrication of large area, high efficiency, and low cost thin film solar cell.

Weighted least-square approach for simultaneous measurement of multiple reflective surfaces

Science.gov (United States)

Tang, Shouhong; Bills, Richard E.; Freischlad, Klaus

2007-09-01

Phase shifting interferometry (PSI) is a highly accurate method for measuring the nanometer-scale relative surface height of a semi-reflective test surface. PSI is effectively used in conjunction with Fizeau interferometers for optical testing, hard disk inspection, and semiconductor wafer flatness. However, commonly-used PSI algorithms are unable to produce an accurate phase measurement if more than one reflective surface is present in the Fizeau interferometer test cavity. Examples of test parts that fall into this category include lithography mask blanks and their protective pellicles, and plane parallel optical beam splitters. The plane parallel surfaces of these parts generate multiple interferograms that are superimposed in the recording plane of the Fizeau interferometer. When using wavelength shifting in PSI the phase shifting speed of each interferogram is proportional to the optical path difference (OPD) between the two reflective surfaces. The proposed method is able to differentiate each underlying interferogram from each other in an optimal manner. In this paper, we present a method for simultaneously measuring the multiple test surfaces of all underlying interferograms from these superimposed interferograms through the use of a weighted least-square fitting technique. The theoretical analysis of weighted least-square technique and the measurement results will be described in this paper.

Biomimetic approaches to create anti-reflection glass surfaces for solar cells using self-organizing techniques

International Nuclear Information System (INIS)

Achtelik, J.; Sievers, W.; Lindner, J.K.N.

2013-01-01

Highlights: ► Nanostructured glass surfaces with theoretically near-to-zero reflectivity in the UVNIR region. ► Simple fabrication process using self-organization during reactive ion etching proposed. ► Prediction of optical reflectivity from AFM measured surface morphology. -- Abstract: Aiming to diminish the reflection losses of glass covered light harvesting devices, the optical reflectivity of nanostructured glass surfaces is studied theoretically and experimentally. The work is inspired by the nanoscale roughness of insect eyes, which is tried to be replicated on a technical glass surface. To this end, the reflectivity of glass surfaces with topographies represented by linear, parabolic and Fermi-shaped glass/air fill factor profiles is calculated for normal incidence. It is shown that using the latter ones, an almost complete suppression of reflections can be achieved. A simple, self-organization technique to create such Fermi-shaped filling factor profiles in glass experimentally is also presented

Biomimetic approaches to create anti-reflection glass surfaces for solar cells using self-organizing techniques

Energy Technology Data Exchange (ETDEWEB)

Achtelik, J.; Sievers, W. [University of Paderborn, Department of Physics, 33098 Paderborn (Germany); Center of Optoelectronics and Photonics Paderborn CeOPP, 33098 Paderborn (Germany); Lindner, J.K.N., E-mail: lindner@physik.uni-paderborn.de [University of Paderborn, Department of Physics, 33098 Paderborn (Germany); Center of Optoelectronics and Photonics Paderborn CeOPP, 33098 Paderborn (Germany)

2013-05-15

Highlights: ► Nanostructured glass surfaces with theoretically near-to-zero reflectivity in the UVNIR region. ► Simple fabrication process using self-organization during reactive ion etching proposed. ► Prediction of optical reflectivity from AFM measured surface morphology. -- Abstract: Aiming to diminish the reflection losses of glass covered light harvesting devices, the optical reflectivity of nanostructured glass surfaces is studied theoretically and experimentally. The work is inspired by the nanoscale roughness of insect eyes, which is tried to be replicated on a technical glass surface. To this end, the reflectivity of glass surfaces with topographies represented by linear, parabolic and Fermi-shaped glass/air fill factor profiles is calculated for normal incidence. It is shown that using the latter ones, an almost complete suppression of reflections can be achieved. A simple, self-organization technique to create such Fermi-shaped filling factor profiles in glass experimentally is also presented.

Repulsive Casimir-Polder potential by a negative reflecting surface

Science.gov (United States)

Yuan, Qi-Zhang

2015-07-01

We present a scheme to generate an all-range long repulsive Casimir-Polder potential between a perfect negative reflecting surface and a ground-state atom. The repulsive potential is stable and does not decay with time. The Casimir-Polder potential is proportional to z-2 at short atom-surface distances and to z-4 at long atom-surface distances. Because of these advantages, this potential can help in building quantum reflectors, quantum levitating devices, and waveguides for matter waves.

The Value of Reflective: Functioning within an Academic Therapeutic Nursery.

Science.gov (United States)

LaLonde, Mary M; Dreier, Mona; Aaronson, Gayle; O'Brien, John

2015-01-01

The self begins as a social self and is dependent on the other and the self-other relationship. Furthermore, shortly after birth, the intersubjective self is nurtured and sustained by the reciprocal interactions with the significant other. Recent research suggests that the significant other's reciprocity depends on his or her capacity for mentalization, and this reflective functioning capacity influences not only the child's developing sense of I, other, and we, but also his or her developing attachment pattern. Several studies have demonstrated that parental reflective functioning can be improved with intervention, and enhancing parental reflective functioning can lead to a more secure attachment pattern and better outcomes for the child and parent. Therefore, intervention with toddlers and their families requires us to consider this dynamic two-person psychology. In this paper, we describe an academic parent-child nursery program aimed at enhancing parental reflective functioning. A clinical example from the collaborative treatment of a mother and her two-year-old will demonstrate how reflective functioning can be enhanced in the parent-child dyad and lead to a more secure parent-child relationship. We will also discuss the value of reflective functioning to the interdisciplinary team and how we dealt with countertransference issues that arose during the treatment.

Measurement of integrated coefficients of ultracold neutron reflection from solid surfaces

International Nuclear Information System (INIS)

Golikov, V.V.; Kulagin, E.N.; Nikitenko, Yu.V.

1985-01-01

The method of measurement of the integrated coefficients of ultracold neutrons (UCN) reflection from solid surfaces is reported. A simple formula is suggested which expresses the integrated coefficients of UCN reflection from a given sample through the measured counting rate of the detector with and without strong absorber (polyethelene). The parameters are determined describing anisotropic and inhomogeneity properties of UCN reflection from Al, Mg, Pb, Zn, Mo, stainless steel, T and V are measured. The thickness of oxide layers is determined within the 5-10A accuracy limits from the experimental coefficients of UCN reflection from metals having on their surfaces the oxides with boundary velocity larger than that for the metal. It has been determined that the density of 5000 A layer of heavy ice freezed on aluminium is 0.83 +- 0.05 from the crystal ice density

An investigation of the functional groups on the surface of activated carbons

Directory of Open Access Journals (Sweden)

MARYTE DERVINYTE

2004-05-01

Full Text Available Activated carbons were produced in the laboratory from wood using a 20-run Plackett–Burman experimental design for 19 factors. The obtained batches of activated carbon were analysed by potentiometric titration and FTIR spectroscopy to determine the surface functional groups. The results obtained by potentiometric titration displayed the distribution of individual acidity constants of those groups in the pK range. Considering this parameter, the surface functional groups were divided into carboxyl, lactone and phenol. The linear regression equations reflecting the influence of each operation used for the synthesis on the amount of these functional groups in the obtained activated carbons were generated. The FTIR spectra were used in parallel for the evaluation of the amount and the type of the surface functional groups. Relationships between the two data sets obtained by potentiometric titration and FTIR spectroscopy were evaluated by correlation analysis. It was established that the amount of surface functional groups determined by potentiometric titration positively correlates with the intensity of the peaks of hydrophilic functional groups in the FTIR spectra. At the same time, the negative correlation between potentiometrically determined amount of surface functional groups and the intensity of peaks of hydrophobic functional groups was observed. Most probably, these non-polar formations can take part in the interaction of carbon surface with H+/OH- ions and diminish the strength of existent functional groups.

Model of bidirectional reflectance distribution function for metallic materials

International Nuclear Information System (INIS)

Wang Kai; Zhu Jing-Ping; Liu Hong; Hou Xun

2016-01-01

Based on the three-component assumption that the reflection is divided into specular reflection, directional diffuse reflection, and ideal diffuse reflection, a bidirectional reflectance distribution function (BRDF) model of metallic materials is presented. Compared with the two-component assumption that the reflection is composed of specular reflection and diffuse reflection, the three-component assumption divides the diffuse reflection into directional diffuse and ideal diffuse reflection. This model effectively resolves the problem that constant diffuse reflection leads to considerable error for metallic materials. Simulation and measurement results validate that this three-component BRDF model can improve the modeling accuracy significantly and describe the reflection properties in the hemisphere space precisely for the metallic materials. (paper)

Model of bidirectional reflectance distribution function for metallic materials

Science.gov (United States)

Wang, Kai; Zhu, Jing-Ping; Liu, Hong; Hou, Xun

2016-09-01

Based on the three-component assumption that the reflection is divided into specular reflection, directional diffuse reflection, and ideal diffuse reflection, a bidirectional reflectance distribution function (BRDF) model of metallic materials is presented. Compared with the two-component assumption that the reflection is composed of specular reflection and diffuse reflection, the three-component assumption divides the diffuse reflection into directional diffuse and ideal diffuse reflection. This model effectively resolves the problem that constant diffuse reflection leads to considerable error for metallic materials. Simulation and measurement results validate that this three-component BRDF model can improve the modeling accuracy significantly and describe the reflection properties in the hemisphere space precisely for the metallic materials.

Photo-induced surface functionalization of carbon surfaces: The role of photoelectron ejection

International Nuclear Information System (INIS)

Colavita, Paula E.; Sun Bin; Tse, K.-Y.; Hamers, Robert J.

2008-01-01

Carbon-based materials are attractive for a wide range of applications, from biomaterials to fuel cells; however, their effective use often requires controlling the surface chemistry to incorporate recognition moieties or reactive centers. The high stability of carbon also makes it a challenging material to functionalize; recently, the use of ultraviolet light (254 nm) to initiate functionalization of carbon surfaces has emerged as a way to obtain carbon/organic interfaces with tailored properties. The authors have investigated the mechanism of covalent grafting of amorphous carbon surfaces with functional organic molecules using the photochemical reaction of terminal alkenes. Measurements comparing the reactivity of different n-alkenes bearing different terminal groups at the terminus opposite the olefin showed pronounced differences in reactivity. They characterized the rate and final coverage of the resulting organic layers using x-ray photoelectron spectroscopy and infrared reflection-absorption spectroscopy. Ultraviolet photoelectron spectroscopy and photocurrent measurements suggested that the reaction involves photoelectron emission from the carbon surface into the liquid phase. Density functional calculations show a strong correlation between the electron affinity of the alkenes and the observed reactivity. The specific terminal group opposite to the olefin was found to play an important role in the stabilization of excess negative charges on the molecule, thus explaining the strong dependence of reactivity on the particular terminal group. These findings suggest that the reaction involves injection of photoelectrons into the alkene acceptor levels, leading to the formation of radical anions in the liquid phase. Finally, the authors demonstrate that the grafting of marginally reactive alkenes can be enhanced by seeding the surface with a small amount of good electron accepting groups. These results provide fundamental new insights into the role of

Gelatin Functionalization of Biomaterial Surfaces: Strategies for Immobilization and Visualization

Directory of Open Access Journals (Sweden)

Peter Dubruel

2011-01-01

Full Text Available In the present work, the immobilization of gelatin as biopolymer on two types of implantable biomaterials, polyimide and titanium, was compared. Both materials are known for their biocompatibility while lacking cell-interactive behavior. For both materials, a pre-functionalization step was required to enable gelatin immobilization. For the polyimide foils, a reactive succinimidyl ester was introduced first on the surface, followed by covalent grafting of gelatin. For the titanium material, methacrylate groups were first introduced on the Ti surface through a silanization reaction. The applied functionalities enabled the subsequent immobilization of methacrylamide modified gelatin. Both surface modified materials were characterized in depth using atomic force microscopy, static contact angle measurements, confocal fluorescence microscopy, attenuated total reflection infrared spectroscopy and X-ray photo-electron spectroscopy. The results indicated that the strategies elaborated for both material classes are suitable to apply stable gelatin coatings. Interestingly, depending on the material class studied, not all surface analysis techniques are applicable.

Critical coupling of surface plasmons in graphene attenuated total reflection geometry

Energy Technology Data Exchange (ETDEWEB)

Cuevas, Mauro, E-mail: cuevas@df.uba.ar [Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) and Facultad de Ingeniería y Tecnología Informática, Universidad de Belgrano, Villanueva 1324, C1426BMJ, Buenos Aires (Argentina); Grupo de Electromagnetismo Aplicado, Departamento de Física, FCEN, Universidad de Buenos Aires and IFIBA, Ciudad Universitaria, Pabellón I, C1428EHA, Buenos Aires (Argentina)

2016-12-09

We study the optical response of an attenuated total reflection (ATR) structure in Otto configuration with graphene sheet, paying especial attention to the occurrence of total absorption. Our results show that due to excitation of surface plasmons on the graphene sheet, two different conditions of total absorption may occur. At these conditions, the energy loss of the surface plasmon by radiation is equal to its energy loss by absorption into the graphene sheet. We give necessary conditions on ATR parameters for the existence of total absorption. - Highlights: • Attenuated total reflection (ATR) structure with graphene sheet. • Surface plasmons and power matched condition. • Necessary conditions on ATR parameters for the existence of total absorption.

Critical coupling of surface plasmons in graphene attenuated total reflection geometry

International Nuclear Information System (INIS)

Cuevas, Mauro

2016-01-01

We study the optical response of an attenuated total reflection (ATR) structure in Otto configuration with graphene sheet, paying especial attention to the occurrence of total absorption. Our results show that due to excitation of surface plasmons on the graphene sheet, two different conditions of total absorption may occur. At these conditions, the energy loss of the surface plasmon by radiation is equal to its energy loss by absorption into the graphene sheet. We give necessary conditions on ATR parameters for the existence of total absorption. - Highlights: • Attenuated total reflection (ATR) structure with graphene sheet. • Surface plasmons and power matched condition. • Necessary conditions on ATR parameters for the existence of total absorption.

Manifestation of surface phonons in far infrared reflectivity of diamond-type semiconductors

Energy Technology Data Exchange (ETDEWEB)

Perez-Sanchez, F.L.; Perez-Rodriguez, F. [Instituto de Fisica, Universidad Autonoma de Puebla, Apdo. Post. J-48, Puebla, Pue. 72570 (Mexico)

2004-11-01

The coupling of surface phonons with light at (001) surfaces of diamond-structure crystals and its manifestation in far-infrared anisotropy spectra are theoretically studied. We apply the adiabatic bond charge model to describe short-range mechanical interactions together with long-range Coulomb forces and radiation fields, and we solve the corresponding system of coupled equations for the electromagnetic field and the lattice vibrations. We calculate far-infrared normal reflectance spectra of (001) surfaces of semi-infinite diamond-type crystals. In particular, we analyse reflectance spectra for the Si(001) (2 x 1) surface, which exhibit a resonance structure associated with the excitation of surface phonon modes. (copyright 2004 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Copper-assisted, anti-reflection etching of silicon surfaces

Science.gov (United States)

Toor, Fatima; Branz, Howard

2014-08-26

A method (300) for etching a silicon surface (116) to reduce reflectivity. The method (300) includes electroless deposition of copper nanoparticles about 20 nanometers in size on the silicon surface (116), with a particle-to-particle spacing of 3 to 8 nanometers. The method (300) includes positioning (310) the substrate (112) with a silicon surface (116) into a vessel (122). The vessel (122) is filled (340) with a volume of an etching solution (124) so as to cover the silicon surface (116). The etching solution (124) includes an oxidant-etchant solution (146), e.g., an aqueous solution of hydrofluoric acid and hydrogen peroxide. The silicon surface (116) is etched (350) by agitating the etching solution (124) with, for example, ultrasonic agitation, and the etching may include heating (360) the etching solution (124) and directing light (365) onto the silicon surface (116). During the etching, copper nanoparticles enhance or drive the etching process.

Anti-reflection textured structures by wet etching and island lithography for surface-enhanced Raman spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Chao, Bo-Kai [Department of Materials Science and Engineering, National Taiwan University, Taipei 10617, Taiwan (China); Cheng, Hsin-Hung [Department of Marine Engineering, Taipei College of Maritime Technology, Taipei 11174, Taiwan (China); Nien, Li-Wei; Chen, Miin-Jang [Department of Materials Science and Engineering, National Taiwan University, Taipei 10617, Taiwan (China); Nagao, Tadaaki [Center for Materials Nanoarchitectonics, National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Li, Jia-Han [Department of Engineering Science and Ocean Engineering, National Taiwan University, Taipei 10617, Taiwan (China); Hsueh, Chun-Hway, E-mail: hsuehc@ntu.edu.tw [Department of Materials Science and Engineering, National Taiwan University, Taipei 10617, Taiwan (China)

2015-12-01

Graphical abstract: - Highlights: • We fabricated textured SERS substrate with a high surface area and low reflectance. • Large surface area of substrate contains more gold nanodroplets to absorb analytes. • Low reflectance of textured SERS substrate enabled multiple reflections of incident laser light. • We obtained strong SERS enhancement from nanopillar-on-pyramid SERS substrate. - Abstract: A high surface area and low reflection textured surface-enhanced Raman scattering (SERS) substrate with plasmonic gold nanodroplets fabricated by wet etching and island lithography was reported in the present study. Specifically, four textured substrates, planar, pyramid, nanopillar, and nanopillar-on-pyramid, were fabricated. The fabricated structures were simulated using the finite-difference time-domain method and the results agreed with the reflection and dark-field scattering measurements. Although the SERS signals varied in different measured regions because of the random nanostructure, the SERS substrates with nanopillar-on-pyramid structure always have the stronger enhancement factor than the SERS substrates with only pyramids or nanopillars. Based on the atomic force microscope and reflection measurements, the nanopillar-on-pyramid structure provided a large surface area and multiple reflections for SERS enhancement, which was about 3 orders of magnitude larger than that of the planar substrate. Our results can be applied to fabricate the inexpensive, large surface area, and high SERS enhancement substrates.

Accounting for surface reflectance anisotropy in satellite retrievals of tropospheric NO₂

NARCIS (Netherlands)

Zhou, Yipin; Brunner, D.; Spurr, R.J.D.; Boersma, K.F.; Sneep, M.; Popp, C.; Buchmann, B.

2010-01-01

Surface reflectance is a key parameter in satellite trace gas retrievals in the UV/visible range and in particular for the retrieval of nitrogen dioxide (NO2) vertical tropospheric columns (VTCs). Current operational retrievals rely on coarse-resolution reflectance data and do not account for the

Functional Reflective Polarizer for Augmented Reality and Color Vision Deficiency

Science.gov (United States)

2016-03-03

augment reality system is relatively high as compared to a polarizing beam splitter or a conventional reflective polarizer. Such a functional reflective...brightness of the display [7]. A key component for polarization management is polarizing beam splitter (PBS). Even though the PBS has exceptional...polarizer that can be incorporated into a compact augmented reality system. The design principle of the functional reflective polarizer is explained and

Estimates of radiance reflected towards the zenith at the surface of the sea

Directory of Open Access Journals (Sweden)

E. Aas

2010-10-01

Full Text Available Remote sensing of water colour by ship-mounted sensors represents an important tool for the validation of satellite products and the monitoring of water quality. The recorded radiance from the sea has to be corrected for the surface-reflected radiance from sun and sky in order to obtain the water-leaving radiance. Here the simple case of radiance reflected towards the zenith is studied. A set of observed sky radiance and solar irradiance data from Oslo has been used together with a Gaussian slope distribution for the sea surface in order to estimate the reflected radiance. The spectral range studied is 405–650 nm, the solar zenith angles are in the range 37°–76°, and the wind speeds are up to 10 m s⁻¹. The analysis of the results show that the reflected radiance has to be separated into three contributions: sky radiance and sun rays reflected at the foam-free surface and irradiance reflected by whitecaps and foam. It is then demonstrated that by using four input values, namely the downward irradiance, the sky radiance from the zenith, the solar zenith angle and the wind speed, it is possible to obtain by simple expressions estimates of the reflected radiance that only differ from the former calculated values by relative errors of less than 5%. The analysis also indicates that for the spectral range studied neither the water-leaving radiance nor the surface-reflected radiance can be disregarded relative to the other one in the Case 2 waters of the Oslofjord-Skagerrak area. The results form a first step towards the study of reflected radiance in viewing angles differing from the nadir direction.

Real-time defect detection on highly reflective curved surfaces

Science.gov (United States)

Rosati, G.; Boschetti, G.; Biondi, A.; Rossi, A.

2009-03-01

This paper presents an automated defect detection system for coated plastic components for the automotive industry. This research activity came up as an evolution of a previous study which employed a non-flat mirror to illuminate and inspect high reflective curved surfaces. According to this method, the rays emitted from a light source are conveyed on the surface under investigation by means of a suitably curved mirror. After the reflection on the surface, the light rays are collected by a CCD camera, in which the coating defects appear as shadows of various shapes and dimensions. In this paper we present an evolution of the above-mentioned method, introducing a simplified mirror set-up in order to reduce the costs and the complexity of the defect detection system. In fact, a set of plane mirrors is employed instead of the curved one. Moreover, the inspection of multiple bend radius parts is investigated. A prototype of the machine vision system has been developed in order to test this simplified method. This device is made up of a light projector, a set of plane mirrors for light rays reflection, a conveyor belt for handling components, a CCD camera and a desktop PC which performs image acquisition and processing. Like in the previous system, the defects are identified as shadows inside a high brightness image. At the end of the paper, first experimental results are presented.

Smart biomaterials: Surfaces functionalized with proteolytically stable osteoblast-adhesive peptides

Directory of Open Access Journals (Sweden)

Annj Zamuner

2017-09-01

Full Text Available Engineered scaffolds for bone tissue regeneration are designed to promote cell adhesion, growth, proliferation and differentiation. Recently, covalent and selective functionalization of glass and titanium surfaces with an adhesive peptide (HVP mapped on [351–359] sequence of human Vitronectin allowed to selectively increase osteoblast attachment and adhesion strength in in vitro assays, and to promote osseointegration in in vivo studies. For the first time to our knowledge, in this study we investigated the resistance of adhesion sequences to proteolytic digestion: HVP was completely cleaved after 5 h. In order to overcome the enzymatic degradation of the native peptide under physiological conditions we synthetized three analogues of HVP sequence. A retro-inverted peptide D-2HVP, composed of D amino acids, was completely stable in serum-containing medium. In addition, glass surfaces functionalized with D-2HVP increased human osteoblast adhesion as compared to the native peptide and maintained deposition of calcium. Interestingly, D-2HVP increased expression of IBSP, VTN and SPP1 genes as compared to HVP functionalized surfaces. Total internal reflection fluorescence microscope analysis showed cells with numerous filopodia spread on D-2HVP-functionalized surfaces. Therefore, the D-2HVP sequence is proposed as new osteoblast adhesive peptide with increased bioactivity and high proteolytic resistance.

Smart biomaterials: Surfaces functionalized with proteolytically stable osteoblast-adhesive peptides.

Science.gov (United States)

Zamuner, Annj; Brun, Paola; Scorzeto, Michele; Sica, Giuseppe; Castagliuolo, Ignazio; Dettin, Monica

2017-09-01

Engineered scaffolds for bone tissue regeneration are designed to promote cell adhesion, growth, proliferation and differentiation. Recently, covalent and selective functionalization of glass and titanium surfaces with an adhesive peptide (HVP) mapped on [351-359] sequence of human Vitronectin allowed to selectively increase osteoblast attachment and adhesion strength in in vitro assays, and to promote osseointegration in in vivo studies. For the first time to our knowledge, in this study we investigated the resistance of adhesion sequences to proteolytic digestion: HVP was completely cleaved after 5 h. In order to overcome the enzymatic degradation of the native peptide under physiological conditions we synthetized three analogues of HVP sequence. A retro-inverted peptide D-2HVP, composed of D amino acids, was completely stable in serum-containing medium. In addition, glass surfaces functionalized with D-2HVP increased human osteoblast adhesion as compared to the native peptide and maintained deposition of calcium. Interestingly, D-2HVP increased expression of IBSP, VTN and SPP1 genes as compared to HVP functionalized surfaces. Total internal reflection fluorescence microscope analysis showed cells with numerous filopodia spread on D-2HVP-functionalized surfaces. Therefore, the D-2HVP sequence is proposed as new osteoblast adhesive peptide with increased bioactivity and high proteolytic resistance.

The effect of surface texture on total reflection of neutrons and X-rays from modified interfaces

DEFF Research Database (Denmark)

Goldar, A.; Roser, S.J.; Hughes, A.

2002-01-01

X-ray and neutron scattering from macroscopically rough surfaces and interfaces is considered and a new method of analysis based on the variation of the shape of the total reflection edge in the reflectivity profile is proposed. It was shown that in the limit that the correlation length and the h......X-ray and neutron scattering from macroscopically rough surfaces and interfaces is considered and a new method of analysis based on the variation of the shape of the total reflection edge in the reflectivity profile is proposed. It was shown that in the limit that the correlation length...... and the height of the surface roughness are larger than the wavelength (at least 100 times bigger) of the incoming beam, the total reflection edge in the reflection profile becomes rounded. This technique allows direct analysis of the variation of the reflectivity pro le in terms of the structure of the surface...

Mercury's Surface Magnetic Field Determined from Proton-Reflection Magnetometry

Science.gov (United States)

Winslow, Reka M.; Johnson, Catherine L.; Anderson, Brian J.; Gershman, Daniel J.; Raines, Jim M.; Lillis, Robert J.; Korth, Haje; Slavin, James A.; Solomon, Sean C.; Zurbuchen, Thomas H.;

Engineering design of sub-micron topographies for simultaneously adherent and reflective metal-polymer interfaces

Science.gov (United States)

Brown, Christopher A.

1993-01-01

The approach of the project is to base the design of multi-function, reflective topographies on the theory that topographically dependent phenomena react with surfaces and interfaces at certain scales. The first phase of the project emphasizes the development of methods for understanding the sizes of topographic features which influence reflectivity. Subsequent phases, if necessary, will address the scales of interaction for adhesion and manufacturing processes. A simulation of the interaction of electromagnetic radiation, or light, with a reflective surface is performed using specialized software. Reflectivity of the surface as a function of scale is evaluated and the results from the simulation are compared with reflectivity measurements made on multi-function, reflective surfaces.

Reflection of slow hydrogen and helium ions from solid surfaces

International Nuclear Information System (INIS)

Akkerman, A.F.

1978-01-01

Some characteristics of the proton and helium ion flux (E < 10 keV), reflected from solid surfaces are presented. A 'condensed walk' scheme, previously used for electron transport calculations, was adapted. Results obtained either by the scheme or by a more detailed 'consequent' scheme agreed closely. The presented data permit calculations of the mean energy of reflected particles and other values for various energy and angular distributions of incident particles. (author)

Surface roughness and gloss study of prints: application of specular reflection at near infrared

International Nuclear Information System (INIS)

Silfsten, P; Dutta, R; Pääkkönen, P; Peiponen, K-E; Tåg, C-M; Gane, P A C

2012-01-01

Absolute reflectance data were measured with a spectrophotometer in the visible and near infrared (NIR) spectral range. The specular reflectance data in the NIR were used for the assessment of the surface roughness of magenta, yellow, cyan and black prints on paper. In addition, surface roughness data obtained from the prints with a mechanical diamond stylus, an optical profiling system and the spectrophotometer are compared with each other. The surface roughness obtained with the aid of the spectrophotometer data suggests a smoother surface than when measured with the diamond stylus and the optical profiling system. The gloss of the prints can be obtained from the absolute specular reflectance spectra in the spectral region of visible light. It is shown that specular reflection data at a fixed wavelength in the NIR are useful also in the interpretation of gloss in the visible spectral range, but using an unconventional grazing angle of incidence. (paper)

Bio-Inspired Functional Surfaces Based on Laser-Induced Periodic Surface Structures.

Science.gov (United States)

Müller, Frank A; Kunz, Clemens; Gräf, Stephan

2016-06-15

Nature developed numerous solutions to solve various technical problems related to material surfaces by combining the physico-chemical properties of a material with periodically aligned micro/nanostructures in a sophisticated manner. The utilization of ultra-short pulsed lasers allows mimicking numerous of these features by generating laser-induced periodic surface structures (LIPSS). In this review paper, we describe the physical background of LIPSS generation as well as the physical principles of surface related phenomena like wettability, reflectivity, and friction. Then we introduce several biological examples including e.g., lotus leafs, springtails, dessert beetles, moth eyes, butterfly wings, weevils, sharks, pangolins, and snakes to illustrate how nature solves technical problems, and we give a comprehensive overview of recent achievements related to the utilization of LIPSS to generate superhydrophobic, anti-reflective, colored, and drag resistant surfaces. Finally, we conclude with some future developments and perspectives related to forthcoming applications of LIPSS-based surfaces.

The Normalization of Surface Anisotropy Effects Present in SEVIRI Reflectances by Using the MODIS BRDF Method

Science.gov (United States)

Proud, Simon Richard; Zhang, Qingling; Schaaf, Crystal; Fensholt, Rasmus; Rasmussen, Mads Olander; Shisanya, Chris; Mutero, Wycliffe; Mbow, Cheikh; Anyamba, Assaf; Pak, Ed;

Quantification of the optical surface reflection and surface roughness of articular cartilage using optical coherence tomography

Energy Technology Data Exchange (ETDEWEB)

Saarakkala, Simo; Wang Shuzhe; Huang Yanping; Zheng Yongping [Department of Health Technology and Informatics, Hong Kong Polytechnic University, Hong Kong (China)], E-mail: simo.saarakkala@uku.fi, E-mail: ypzheng@ieee.org

2009-11-21

Optical coherence tomography (OCT) is a promising new technique for characterizing the structural changes of articular cartilage in osteoarthritis (OA). The calculation of quantitative parameters from the OCT signal is an important step to develop OCT as an effective diagnostic technique. In this study, two novel parameters for the quantification of optical surface reflection and surface roughness from OCT measurements are introduced: optical surface reflection coefficient (ORC), describing the amount of a ratio of the optical reflection from cartilage surface with respect to that from a reference material, and OCT roughness index (ORI) indicating the smoothness of the cartilage surface. The sensitivity of ORC and ORI to detect changes in bovine articular cartilage samples after enzymatic degradations of collagen and proteoglycans using collagenase and trypsin enzymes, respectively, was tested in vitro. A significant decrease (p < 0.001) in ORC as well as a significant increase (p < 0.001) in ORI was observed after collagenase digestion. After trypsin digestion, no significant changes in ORC or ORI were observed. To conclude, the new parameters introduced were demonstrated to be feasible and sensitive to detect typical OA-like degenerative changes in the collagen network. From the clinical point of view, the quantification of OCT measurements is of great interest since OCT probes have been already miniaturized and applied in patient studies during arthroscopy or open knee surgery in vivo. Further studies are still necessary to demonstrate the clinical capability of the introduced parameters for naturally occurring early OA changes in the cartilage.

Red-Edge Spectral Reflectance as an Indicator of Surface Moisture Content in an Alaskan Peatland Ecosystem

Science.gov (United States)

McPartland, M.; Kane, E. S.; Turetsky, M. R.; Douglass, T.; Falkowski, M. J.; Montgomery, R.; Edwards, J.

2015-12-01

Arctic and boreal peatlands serve as major reservoirs of terrestrial organic carbon (C) because Net Primary Productivity (NPP) outstrips C loss from decomposition over long periods of time. Peatland productivity varies as a function of water table position and surface moisture content, making C storage in these systems particularly vulnerable to the climate warming and drying predicted for high latitudes. Detailed spatial knowledge of how aboveground vegetation communities respond to changes in hydrology would allow for ecosystem response to environmental change to be measured at the landscape scale. This study leverages remotely sensed data along with field measurements taken at the Alaska Peatland Experiment (APEX) at the Bonanza Creek Long Term Ecological Research site to examine relationships between plant solar reflectance and surface moisture. APEX is a decade-long experiment investigating the effects of hydrologic change on peatland ecosystems using water table manipulation treatments (raised, lowered, and control). Water table levels were manipulated throughout the 2015 growing season, resulting in a maximum separation of 35 cm between raised and lowered treatment plots. Water table position, soil moisture content, depth to seasonal ice, soil temperature, photosynthetically active radiation (PAR), CO2 and CH4 fluxes were measured as predictors of C loss through decomposition and NPP. Vegetation was surveyed for percent cover of plant functional types. Remote sensing data was collected during peak growing season, when the separation between treatment plots was at maximum difference. Imagery was acquired via a SenseFly eBee airborne platform equipped with a Canon S110 red-edge camera capable of detecting spectral reflectance from plant tissue at 715 nm band center to within centimeters of spatial resolution. Here, we investigate empirical relationships between spectral reflectance, water table position, and surface moisture in relation to peat carbon balance.

Mechanisms for the reflection of light atoms from crystal surfaces at kilovolt energies

International Nuclear Information System (INIS)

Hou, M.; Robinson, M.T.

1978-01-01

The computer program MARLOWE was used to investigate the backscattering of protons from the (110) surface of a nickel crystal. Grazing incidence was considered so that anisotropic effects originated mainly from the surface region. The contribution of aligned scattering was studied by comparing the results with similar calculations for an amorphous target. Energy distributions of backscattered particles were investigated for incident energies ranging from 0.1 to 5 keV. The structure of these distributions was explained by making calculations for several target thickness. Specular reflection was found to depend on the structure of the first few atomic planes only. The (110) rows in the surface plane were responsible for focusing into surface semichannels. Focusing in these semichannels was found to be the strongest under total reflection conditions (below about 1.3 keV) while the scattering intensity from surface rows increased with increasing incident energy. The orientation of the plane of incidence was found to have large influence on the relative contributions of the reflection mechanisms involved. (orig.) [de

Optical properties (bidirectional reflectance distribution function) of shot fabric.

Science.gov (United States)

Lu, R; Koenderink, J J; Kappers, A M

2000-11-01

To study the optical properties of materials, one needs a complete set of the angular distribution functions of surface scattering from the materials. Here we present a convenient method for collecting a large set of bidirectional reflectance distribution function (BRDF) samples in the hemispherical scattering space. Material samples are wrapped around a right-circular cylinder and irradiated by a parallel light source, and the scattered radiance is collected by a digital camera. We tilted the cylinder around its center to collect the BRDF samples outside the plane of incidence. This method can be used with materials that have isotropic and anisotropic scattering properties. We demonstrate this method in a detailed investigation of shot fabrics. The warps and the fillings of shot fabrics are dyed different colors so that the fabric appears to change color at different viewing angles. These color-changing characteristics are found to be related to the physical and geometrical structure of shot fabric. Our study reveals that the color-changing property of shot fabrics is due mainly to an occlusion effect.

Measurement and application of bidirectional reflectance distribution function

Science.gov (United States)

Liao, Fei; Li, Lin; Lu, Chengwen

2016-10-01

When a beam of light with certain intensity and distribution reaches the surface of a material, the distribution of the diffused light is related to the incident angle, the receiving angle, the wavelength of the light and the types of the material. Bidirectional Reflectance Distribution Function (BRDF) is a method to describe this distribution. For an optical system, the optical and mechanical materials' BRDF are unique, and if we want to calculate stray light of the system we should know the correct BRDF data of the whole materials. There are fundamental significances in the area of space remote sensor where BRDF is needed in the precise radiation calibration. It is also important in the military field where BRDF can be used in the object identification and target tracking, etc. In this paper, 11 kinds of aerospace materials' BRDF are measured and more than 310,000 groups of BRDF data are achieved , and also a BRDF database is established in China for the first time. With the BRDF data of the database, we can create the detector model, build the stray light radiation surface model in the stray light analysis software. In this way, the stray radiation on the detector can be calculated correctly.

Nanoimprinted reflecting gratings for long-range surface plasmon polaritons

DEFF Research Database (Denmark)

Pedersen, Rasmus Haugstrup; Boltasseva, Alexandra; Johansen, Dan Mario

2007-01-01

We present a novel design, fabrication, and characterization of reflecting gratings for long-range surface plasmon polaritons (LR-SPPs) at telecom wavelengths. LR-SPP waveguides consisting of a thin (12 nm) gold film embedded in a thick (45 μm) layer of dielectric polymer cladding are structured...

Bio-Inspired Functional Surfaces Based on Laser-Induced Periodic Surface Structures

Directory of Open Access Journals (Sweden)

Frank A. Müller

2016-06-01

Full Text Available Nature developed numerous solutions to solve various technical problems related to material surfaces by combining the physico-chemical properties of a material with periodically aligned micro/nanostructures in a sophisticated manner. The utilization of ultra-short pulsed lasers allows mimicking numerous of these features by generating laser-induced periodic surface structures (LIPSS. In this review paper, we describe the physical background of LIPSS generation as well as the physical principles of surface related phenomena like wettability, reflectivity, and friction. Then we introduce several biological examples including e.g., lotus leafs, springtails, dessert beetles, moth eyes, butterfly wings, weevils, sharks, pangolins, and snakes to illustrate how nature solves technical problems, and we give a comprehensive overview of recent achievements related to the utilization of LIPSS to generate superhydrophobic, anti-reflective, colored, and drag resistant surfaces. Finally, we conclude with some future developments and perspectives related to forthcoming applications of LIPSS-based surfaces.

Model for the ultrasound reflection from micro-beads and cells distributed in layers on a uniform surface

Energy Technology Data Exchange (ETDEWEB)

Couture, O; Cherin, E; Foster, F S [Imaging Research, Sunnybrook Health Sciences Centre/University of Toronto, Toronto (Canada)

2007-07-21

A model predicting the reflection of ultrasound from multiple layers of small scattering spheres is developed. Predictions of the reflection coefficient, which takes into account the interferences between the different sphere layers, are compared to measurements performed in the 10-80 MHz and 15-35 MHz frequency range with layers of glass beads and spherical acute myeloid leukemia (AML) cells, respectively. For both types of scatterers, the reflection coefficient increases as a function of their density on the surface for less than three superimposed layers, at which point it saturates at 0.38 for glass beads and 0.02 for AML cells. Above three layers, oscillations of the reflection coefficient due to constructive or destructive interference between layers are observed experimentally and are accurately predicted by the model. The use of such a model could lead to a better understanding of the structures observed in layered tissue images.

Fabrication of multi-functional silicon surface by direct laser writing

Science.gov (United States)

Verma, Ashwani Kumar; Soni, R. K.

2018-05-01

We present a simple, quick and one-step methodology based on nano-second laser direct writing for the fabrication of micro-nanostructures on silicon surface. The fabricated surfaces suppress the optical reflection by multiple reflection due to light trapping effect to a much lower value than polished silicon surface. These textured surfaces offer high enhancement ability after gold nanoparticle deposition and then explored for Surface Enhanced Raman Scattering (SERS) for specific molecular detection. The effect of laser scanning line interval on optical reflection and SERS signal enhancement ability was also investigated. Our results indicate that low optical reflection substrates exhibit uniform SERS enhancement with enhancement factor of the order of 106. Furthermore, this methodology provide an alternative approach for cost-effective large area fabrication with good control over feature size.

Reflective Functioning, Physiological Reactivity, and Overcontrol in Mothers: Links with School-Aged Children's Reflective Functioning

Science.gov (United States)

Borelli, Jessica L.; Hong, Kajung; Rasmussen, Hannah F.; Smiley, Patricia A.

2017-01-01

Theorists argue that parental reflective functioning (PRF) is activated in response to emotions, potentially supporting parenting sensitivity even when arousal is high. That is, when parents become emotionally reactive when interacting with their children, those who can use PRF to understand their children's mental states should be able to parent…

Plasma functionalized surface of commodity polymers for dopamine detection

Energy Technology Data Exchange (ETDEWEB)

Fabregat, Georgina [Departament d’Enginyeria Química, E.T.S. d’Enginyeria Industrial de Barcelona, Universitat Politècnica de Catalunya, Diagonal 647, 08028, Barcelona (Spain); Center for Research in Nano-Engineering, Universitat Politècnica de Catalunya, Campus Sud, Edifici C’, C/Pasqual i Vila s/n, Barcelona, E-08028 (Spain); Osorio, Joaquin [Departament d’Enginyeria Química, E.T.S. d’Enginyeria Industrial de Barcelona, Universitat Politècnica de Catalunya, Diagonal 647, 08028, Barcelona (Spain); Castedo, Alejandra [Center for Research in Nano-Engineering, Universitat Politècnica de Catalunya, Campus Sud, Edifici C’, C/Pasqual i Vila s/n, Barcelona, E-08028 (Spain); Institut de Tècniques Energètiques, E.T.S. d’Enginyeria Industrial de Barcelona, Universitat Politècnica de Catalunya, Diagonal 647, 08028, Barcelona (Spain); Armelin, Elaine [Departament d’Enginyeria Química, E.T.S. d’Enginyeria Industrial de Barcelona, Universitat Politècnica de Catalunya, Diagonal 647, 08028, Barcelona (Spain); Center for Research in Nano-Engineering, Universitat Politècnica de Catalunya, Campus Sud, Edifici C’, C/Pasqual i Vila s/n, Barcelona, E-08028 (Spain); and others

2017-03-31

Highlights: • Electrochemically inert polymers become electroactive after plasma functionalization. • Selective dopamine detection has been achieved functionalizing polymers with plasma. • Plasma-functionalized polymers are sensitive dopamine detectors. • XPS analyses reflect the transformation of inert polymers into electrosensors. - Abstract: We have fabricated potentially generalizable sensors based on polymeric-modified electrodes for the electrochemical detection of dopamine. Sensitive and selective sensors have been successfully obtained by applying a cold-plasma treatment during 1–2 min not only to conducting polymers but also to electrochemically inert polymers, such as polyethylene, polypropylene, polyvinylpyrrolidone, polycaprolactone and polystyrene. The effects of the plasma in the electrode surface activation, which is an essential requirement for the dopamine detection when inert polymers are used, have been investigated using X-ray photoelectron spectroscopy. Results indicate that exposure of polymer-modified electrodes to cold-plasma produces the formation of a large variety of reactive species adsorbed on the electrode surface, which catalyse the dopamine oxidation. With this technology, which is based on the application of a very simple physical functionalization, we have defined a paradox-based paradigm for the fabrication of electrochemical sensors by using inert and cheap plastics.

How Can Polarization States of Reflected Light from Snow Surfaces Inform Us on Surface Normals and Ultimately Snow Grain Size Measurements?

Science.gov (United States)

Schneider, A. M.; Flanner, M.; Yang, P.; Yi, B.; Huang, X.; Feldman, D.

2016-12-01

The Snow Grain Size and Pollution (SGSP) algorithm is a method applied to Moderate Resolution Imaging Spectroradiometer data to estimate snow grain size from space-borne measurements. Previous studies validate and quantify potential sources of error in this method, but because it assumes flat snow surfaces, however, large scale variations in surface normals can cause biases in its estimates due to its dependence on solar and observation zenith angles. To address these variations, we apply the Monte Carlo method for photon transport using data containing the single scattering properties of different ice crystals to calculate polarization states of reflected monochromatic light at 1500nm from modeled snow surfaces. We evaluate the dependence of these polarization states on solar and observation geometry at 1500nm because multiple scattering is generally a mechanism for depolarization and the ice crystals are relatively absorptive at this wavelength. Using 1500nm thus results in a higher number of reflected photons undergoing fewer scattering events, increasing the likelihood of reflected light having higher degrees of polarization. In evaluating the validity of the model, we find agreement with previous studies pertaining to near-infrared spectral directional hemispherical reflectance (i.e. black-sky albedo) and similarities in measured bidirectional reflectance factors, but few studies exist modeling polarization states of reflected light from snow surfaces. Here, we present novel results pertaining to calculated polarization states and compare dependences on solar and observation geometry for different idealized snow surfaces. If these dependencies are consistent across different ice particle shapes and sizes, then these findings could inform the SGSP algorithm by providing useful relationships between measurable physical quantities and solar and observation geometry to better understand variations in snow surface normals from remote sensing observations.

Surface functionalization of dopamine coated iron oxide nanoparticles for various surface functionalities

Energy Technology Data Exchange (ETDEWEB)

Sherwood, Jennifer; Xu, Yaolin; Lovas, Kira [Chemical and Biological Engineering, The University of Alabama, Tuscaloosa , AL 35487 (United States); Qin, Ying [Alabama Innovation and Mentoring of Entrepreneurs, The University of Alabama, Tuscaloosa, AL 35487 (United States); Bao, Yuping, E-mail: ybao@eng.ua.edu [Chemical and Biological Engineering, The University of Alabama, Tuscaloosa , AL 35487 (United States)

2017-04-01

We present effective conjugation of four small molecules (glutathione, cysteine, lysine, and Tris(hydroxymethyl)aminomethane) onto dopamine-coated iron oxide nanoparticles. Conjugation of these molecules could improve the surface functionality of nanoparticles for more neutral surface charge at physiological pH and potentially reduce non-specific adsorption of proteins to nanoparticles surfaces. The success of conjugation was evaluated with dynamic light scattering by measuring the surface charge changes and Fourier transform infrared spectroscopy for surface chemistry analysis. The stability of dopamine-coated nanoparticles and the ability of conjugated nanoparticles to reduce the formation of protein corona were evaluated by measuring the size and charge of the nanoparticles in biological medium. This facile conjugation method opens up possibilities for attaching various surface functionalities onto iron oxide nanoparticle surfaces for biomedical applications.

Surface functionalization of dopamine coated iron oxide nanoparticles for various surface functionalities

International Nuclear Information System (INIS)

Sherwood, Jennifer; Xu, Yaolin; Lovas, Kira; Qin, Ying; Bao, Yuping

2017-01-01

We present effective conjugation of four small molecules (glutathione, cysteine, lysine, and Tris(hydroxymethyl)aminomethane) onto dopamine-coated iron oxide nanoparticles. Conjugation of these molecules could improve the surface functionality of nanoparticles for more neutral surface charge at physiological pH and potentially reduce non-specific adsorption of proteins to nanoparticles surfaces. The success of conjugation was evaluated with dynamic light scattering by measuring the surface charge changes and Fourier transform infrared spectroscopy for surface chemistry analysis. The stability of dopamine-coated nanoparticles and the ability of conjugated nanoparticles to reduce the formation of protein corona were evaluated by measuring the size and charge of the nanoparticles in biological medium. This facile conjugation method opens up possibilities for attaching various surface functionalities onto iron oxide nanoparticle surfaces for biomedical applications.

Excitations of surface plasmon polaritons by attenuated total reflection, revisited

International Nuclear Information System (INIS)

Barchesi, D.; Otto, A.

2013-01-01

Many textbooks and review papers are devoted to plasmonics based on a selection of the numerous bibliography. But none describes the details of the first culmination of plasmonics in 1968, when surface plasmons become a field of optics. The coupling of light with the surface plasmon leads to the surface plasmon polariton (SPP). Therefore, the authors chose to associate historical insight (not avoiding a personal touch), a modern mathematical formulation of the excitation of the SPP by attenuated total reflection (ATR), considered as well understood since decades, and experimental applications since 1969, including recent developments.

GLOBAL LAND COVER CLASSIFICATION USING MODIS SURFACE REFLECTANCE PROSUCTS

Directory of Open Access Journals (Sweden)

K. Fukue

2016-06-01

Full Text Available The objective of this study is to develop high accuracy land cover classification algorithm for Global scale by using multi-temporal MODIS land reflectance products. In this study, time-domain co-occurrence matrix was introduced as a classification feature which provides time-series signature of land covers. Further, the non-parametric minimum distance classifier was introduced for timedomain co-occurrence matrix, which performs multi-dimensional pattern matching for time-domain co-occurrence matrices of a classification target pixel and each classification classes. The global land cover classification experiments have been conducted by applying the proposed classification method using 46 multi-temporal(in one year SR(Surface Reflectance and NBAR(Nadir BRDF-Adjusted Reflectance products, respectively. IGBP 17 land cover categories were used in our classification experiments. As the results, SR and NBAR products showed similar classification accuracy of 99%.

Gain-Enhanced On-Chip Antenna Utilizing Artificial Magnetic Conductor Reflecting Surface at 94 GHz

KAUST Repository

Nafe, Mahmoud

2015-01-01

In this work, the use of specially patterned reflecting surfaces for improving on- chip antenna performance is investigated. By using a periodic metallic surface on top of a grounded substrate, the structure can mimic the behavior of a perfect mag- netic conductor, hence called Artificial Magnetic Conductor (AMC) surface. Unlike conventional ground plane reflecting surfaces, AMC surfaces generally enhance the radiation and impedance characteristics of close-by antennas. Based on this property, a ring-based AMC reflecting surface has been designed in the oxide layer for on-chip antennas operating at 94 GHz. Furthermore, a folded dipole antenna with its associ- ated planar feeding structures has been optimized and integrated with the developed ring-based AMC surface. The proposed design is then fabricated at KAUST clean- room facilities. Prototype characterization showed very promising results with good correlation to simulations, with the antenna exhibiting an impedance bandwidth of 10% (90-100 GHz) and peak gain of -1.4 dBi, which is the highest gain reported for on-chip antennas at this frequency band without the use of any external o↵-chip components or post-fabrication steps.

A functional-dynamic reflection on participatory processes in modeling projects.

Science.gov (United States)

Seidl, Roman

2015-12-01

The participation of nonscientists in modeling projects/studies is increasingly employed to fulfill different functions. However, it is not well investigated if and how explicitly these functions and the dynamics of a participatory process are reflected by modeling projects in particular. In this review study, I explore participatory modeling projects from a functional-dynamic process perspective. The main differences among projects relate to the functions of participation-most often, more than one per project can be identified, along with the degree of explicit reflection (i.e., awareness and anticipation) on the dynamic process perspective. Moreover, two main approaches are revealed: participatory modeling covering diverse approaches and companion modeling. It becomes apparent that the degree of reflection on the participatory process itself is not always explicit and perfectly visible in the descriptions of the modeling projects. Thus, the use of common protocols or templates is discussed to facilitate project planning, as well as the publication of project results. A generic template may help, not in providing details of a project or model development, but in explicitly reflecting on the participatory process. It can serve to systematize the particular project's approach to stakeholder collaboration, and thus quality management.

Improving Image Matching by Reducing Surface Reflections Using Polarising Filter Techniques

Science.gov (United States)

Conen, N.; Hastedt, H.; Kahmen, O.; Luhmann, T.

2018-05-01

In dense stereo matching applications surface reflections may lead to incorrect measurements and blunders in the resulting point cloud. To overcome the problem of disturbing reflexions polarising filters can be mounted on the camera lens and light source. Reflections in the images can be suppressed by crossing the polarising direction of the filters leading to homogeneous illuminated images and better matching results. However, the filter may influence the camera's orientation parameters as well as the measuring accuracy. To quantify these effects, a calibration and an accuracy analysis is conducted within a spatial test arrangement according to the German guideline VDI/VDE 2634.1 (2002) using a DSLR with and without polarising filter. In a second test, the interior orientation is analysed in more detail. The results do not show significant changes of the measuring accuracy in object space and only very small changes of the interior orientation (Δc ≤ 4 μm) with the polarising filter in use. Since in medical applications many tiny reflections are present and impede robust surface measurements, a prototypic trinocular endoscope is equipped with polarising technique. The interior and relative orientation is determined and analysed. The advantage of the polarising technique for medical image matching is shown in an experiment with a moistened pig kidney. The accuracy and completeness of the resulting point cloud can be improved clearly when using polarising filters. Furthermore, an accuracy analysis using a laser triangulation system is performed and the special reflection properties of metallic surfaces are presented.

IMPROVING IMAGE MATCHING BY REDUCING SURFACE REFLECTIONS USING POLARISING FILTER TECHNIQUES

Directory of Open Access Journals (Sweden)

N. Conen

2018-05-01

Full Text Available In dense stereo matching applications surface reflections may lead to incorrect measurements and blunders in the resulting point cloud. To overcome the problem of disturbing reflexions polarising filters can be mounted on the camera lens and light source. Reflections in the images can be suppressed by crossing the polarising direction of the filters leading to homogeneous illuminated images and better matching results. However, the filter may influence the camera’s orientation parameters as well as the measuring accuracy. To quantify these effects, a calibration and an accuracy analysis is conducted within a spatial test arrangement according to the German guideline VDI/VDE 2634.1 (2002 using a DSLR with and without polarising filter. In a second test, the interior orientation is analysed in more detail. The results do not show significant changes of the measuring accuracy in object space and only very small changes of the interior orientation (Δc ≤ 4 μm with the polarising filter in use. Since in medical applications many tiny reflections are present and impede robust surface measurements, a prototypic trinocular endoscope is equipped with polarising technique. The interior and relative orientation is determined and analysed. The advantage of the polarising technique for medical image matching is shown in an experiment with a moistened pig kidney. The accuracy and completeness of the resulting point cloud can be improved clearly when using polarising filters. Furthermore, an accuracy analysis using a laser triangulation system is performed and the special reflection properties of metallic surfaces are presented.

Verifying the functional ability of microstructured surfaces by model-based testing

Science.gov (United States)

Hartmann, Wito; Weckenmann, Albert

2014-09-01

Micro- and nanotechnology enables the use of new product features such as improved light absorption, self-cleaning or protection, which are based, on the one hand, on the size of functional nanostructures and the other hand, on material-specific properties. With the need to reliably measure progressively smaller geometric features, coordinate and surface-measuring instruments have been refined and now allow high-resolution topography and structure measurements down to the sub-nanometre range. Nevertheless, in many cases it is not possible to make a clear statement about the functional ability of the workpiece or its topography because conventional concepts of dimensioning and tolerancing are solely geometry oriented and standardized surface parameters are not sufficient to consider interaction with non-geometric parameters, which are dominant for functions such as sliding, wetting, sealing and optical reflection. To verify the functional ability of microstructured surfaces, a method was developed based on a parameterized mathematical-physical model of the function. From this model, function-related properties can be identified and geometric parameters can be derived, which may be different for the manufacturing and verification processes. With this method it is possible to optimize the definition of the shape of the workpiece regarding the intended function by applying theoretical and experimental knowledge, as well as modelling and simulation. Advantages of this approach will be discussed and demonstrated by the example of a microstructured inking roll.

Capabilities of using white x-rays for the reconstruction of surface morphology from coherent reflectivity

Energy Technology Data Exchange (ETDEWEB)

Sant, Tushar, E-mail: tushar@physik.uni-siegen.de [Solid State Physics Group, University of Siegen, 57068 Siegen (Germany); Panzner, Tobias [Paul Scherrer Institute (Switzerland); Pietsch, Ullrich [Solid State Physics Group, University of Siegen, 57068 Siegen (Germany)

2010-10-15

We present a new method to reconstruct the surface profile of a sample from coherent reflectivity data of a white x-ray beam experiment. As an example the surface profile of a laterally confined silicon wafer has been reconstructed quantitatively from static speckle measurements using white coherent x-rays from a bending magnet in the energy range between 5 < E < 20 keV. As a consequence of using white radiation, speckles appear in addition to the Airy pattern caused by scattering at the entrance pinhole. Nevertheless, the surface profile of a triangularly shaped specimen was reconstructed considering sufficient oversampling between the beam-footprint and the effective sample width. For the profile reconstruction the Error-Reduction phase retrieval algorithm was modified by including the spectral illumination function and a Fresnel propagator term. The simultaneous use of different x-ray energies having different penetration depth provides information on the evolution of the surface profile from the near-surface towards the bulk. The limitations of present experiment can be overcome using white or pink radiation from a source with higher photon flux.

An instrument for the measurement of road surface reflection properties

DEFF Research Database (Denmark)

Corell, Dennis Dan; Sørensen, K.

2017-01-01

surfaces in use have changed - for instance to road surface types with less noise from wheel passages. Because of this, a co-operation between the road administrations of the Nordic countries (abbreviated NMF) decided to construct a portable instrument to be used on selections of traffic roads within......Road surface reflection data in the form of standard r-tables serve as input for design calculations of road lighting installations on traffic roads. However, in several countries the use of the standard r-tables has not been verified by measurement in a long period of time, while the types of road...

Lunar surface remanent magnetic fields detected by the electron reflection method

Science.gov (United States)

Lin, R. P.; Anderson, K. A.; Bush, R.; Mcguire, R. E.; Mccoy, J. E.

1976-01-01

We present maps of the lunar surface remanent magnetic fields detected by the electron reflection method. These maps provide substantial coverage of the latitude band from 30 N southward to 30 S with a resolution of about 40 km and a sensitivity of about 0.2 gamma at the lunar surface. Regions of remanent magnetization are observed ranging in size from the resolution limit of 1.25 deg to above approximately 60 deg. The largest contiguous region fills the Big Backside Basin where it is intersected by the spacecraft orbital tracks. Preliminary analyses of the maps show that the source regions of lunar limb compressions correspond to regions of strong surface magnetism, and that there does not appear to be sharply discontinuous magnetization at the edges of maria. We also analyze the electron reflection observations to obtain information on the direction and distribution of magnetization in the Van de Graaff anomaly region.

NOAA Climate Data Record (CDR) of AVHRR Surface Reflectance, Version 4

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — This dataset contains gridded daily surface reflectance and brightness temperatures derived from the Advanced Very High Resolution Radiometer (AVHRR) sensors onboard...

Self-consistent approach to x-ray reflection from rough surfaces

International Nuclear Information System (INIS)

Feranchuk, I. D.; Feranchuk, S. I.; Ulyanenkov, A. P.

2007-01-01

A self-consistent analytical approach for specular x-ray reflection from interfaces with transition layers [I. D. Feranchuk et al., Phys. Rev. B 67, 235417 (2003)] based on the distorted-wave Born approximation (DWBA) is used for the description of coherent and incoherent x-ray scattering from rough surfaces and interfaces. This approach takes into account the transformation of the modeling transition layer profile at the interface, which is caused by roughness correlations. The reflection coefficients for each DWBA order are directly calculated without phenomenological assumptions on their exponential decay at large scattering angles. Various regions of scattering angles are discussed, which show qualitatively different dependence of the reflection coefficient on the scattering angle. The experimental data are analyzed using the method developed

Derivation of Land Surface Albedo at High Resolution by Combining HJ-1A/B Reflectance Observations with MODIS BRDF Products

Directory of Open Access Journals (Sweden)

Bo Gao

2014-09-01

Full Text Available Land surface albedo is an essential parameter for monitoring global/regional climate and land surface energy balance. Although many studies have been conducted on global or regional land surface albedo using various remote sensing data over the past few decades, land surface albedo product with a high spatio–temporal resolution is currently very scarce. This paper proposes a method for deriving land surface albedo with a high spatio–temporal resolution (space: 30 m and time: 2–4 days. The proposed method works by combining the land surface reflectance data at 30 m spatial resolution obtained from the charge-coupled devices in the Huanjing-1A and -1B (HJ-1A/B satellites with the Moderate Resolution Imaging Spectroradiometer (MODIS land surface bidirectional reflectance distribution function (BRDF parameters product (MCD43A1, which is at a spatial resolution of 500 m. First, the land surface BRDF parameters for HJ-1A/B land surface reflectance with a spatial–temporal resolutions of 30 m and 2–4 day are calculated on the basis of the prior knowledge from the MODIS BRDF product; then, the calculated high resolution BRDF parameters are integrated over the illuminating/viewing hemisphere to produce the white- and black-sky albedos at 30 m resolution. These results form the basis for the final land surface albedo derivation by accounting for the proportion of direct and diffuse solar radiation arriving at the ground. The albedo retrieved by this novel method is compared with MODIS land surface albedo products, as well as with ground measurements. The results show that the derived land surface albedo during the growing season of 2012 generally achieved a mean absolute accuracy of ±0.044, and a root mean square error of 0.039, confirming the effectiveness of the newly proposed method.

Spectral and geometrical variation of the bidirectional reflectance distribution function of diffuse reflectance standards.

Science.gov (United States)

Ferrero, Alejandro; Rabal, Ana María; Campos, Joaquín; Pons, Alicia; Hernanz, María Luisa

2012-12-20

A study on the variation of the spectral bidirectional reflectance distribution function (BRDF) of four diffuse reflectance standards (matte ceramic, BaSO(4), Spectralon, and white Russian opal glass) is accomplished through this work. Spectral BRDF measurements were carried out and, using principal components analysis, its spectral and geometrical variation respect to a reference geometry was assessed from the experimental data. Several descriptors were defined in order to compare the spectral BRDF variation of the four materials.

Collection and corrections of oblique multiangle hyperspectral bidirectional reflectance imagery of the water surface

Science.gov (United States)

Bostater, Charles R.; Oney, Taylor S.

2017-10-01

Hyperspectral images of coastal waters in urbanized regions were collected from fixed platform locations. Surf zone imagery, images of shallow bays, lagoons and coastal waters are processed to produce bidirectional reflectance factor (BRF) signatures corrected for changing viewing angles. Angular changes as a function of pixel location within a scene are used to estimate changes in pixel size and ground sampling areas. Diffuse calibration targets collected simultaneously from within the image scene provides the necessary information for calculating BRF signatures of the water surface and shorelines. Automated scanning using a pushbroom hyperspectral sensor allows imagery to be collected on the order of one minute or less for different regions of interest. Imagery is then rectified and georeferenced using ground control points within nadir viewing multispectral imagery via image to image registration techniques. This paper demonstrates the above as well as presenting how spectra can be extracted along different directions in the imagery. The extraction of BRF spectra along track lines allows the application of derivative reflectance spectroscopy for estimating chlorophyll-a, dissolved organic matter and suspended matter concentrations at or near the water surface. Imagery is presented demonstrating the techniques to identify subsurface features and targets within the littoral and surf zones.

Low reflectance radio frequency load

Science.gov (United States)

Ives, R. Lawrence; Mizuhara, Yosuke M

2014-04-01

A load for traveling microwave energy has an absorptive volume defined by cylindrical body enclosed by a first end cap and a second end cap. The first end cap has an aperture for the passage of an input waveguide with a rotating part that is coupled to a reflective mirror. The inner surfaces of the absorptive volume consist of a resistive material or are coated with a coating which absorbs a fraction of incident RF energy, and the remainder of the RF energy reflects. The angle of the reflector and end caps is selected such that reflected RF energy dissipates an increasing percentage of the remaining RF energy at each reflection, and the reflected RF energy which returns to the rotating mirror is directed to the back surface of the rotating reflector, and is not coupled to the input waveguide. Additionally, the reflector may have a surface which generates a more uniform power distribution function axially and laterally, to increase the power handling capability of the RF load. The input waveguide may be corrugated for HE11 mode input energy.

Reflectivity reduction of retro-reflector installed in LHD due to plasma surface interaction

International Nuclear Information System (INIS)

Yoshida, N.; Ohtawa, Y.; Ebihara, A.; Akiyama, T.; Tokitani, M.; Ashikawa, N.; Kawahata, K.

2008-10-01

Optical reflectivity of the retro-reflector installed in LHD as the first mirror was reduced seriously by plasma wall interaction. In order to understand the mechanism of the reflectivity reduction, optical and material properties of the mirror surfaces have been examined extensively. It was found that the deposited impurity layers caused the serious reduction of the reflectivity. Formation of iron oxide, bulges structure and He bubbles are the major factors for the reflectivity reduction in the wide wave length range. (author)

Thermal consequences of colour and near-infrared reflectance.

Science.gov (United States)

Stuart-Fox, Devi; Newton, Elizabeth; Clusella-Trullas, Susana

2017-07-05

The importance of colour for temperature regulation in animals remains controversial. Colour can affect an animal's temperature because all else being equal, dark surfaces absorb more solar energy than do light surfaces, and that energy is converted into heat. However, in reality, the relationship between colour and thermoregulation is complex and varied because it depends on environmental conditions and the physical properties, behaviour and physiology of the animal. Furthermore, the thermal effects of colour depend as much on absorptance of near-infrared ((NIR), 700-2500 nm) as visible (300-700 nm) wavelengths of direct sunlight; yet the NIR is very rarely considered or measured. The few available data on NIR reflectance in animals indicate that the visible reflectance is often a poor predictor of NIR reflectance. Adaptive variation in animal coloration (visible reflectance) reflects a compromise between multiple competing functions such as camouflage, signalling and thermoregulation. By contrast, adaptive variation in NIR reflectance should primarily reflect thermoregulatory requirements because animal visual systems are generally insensitive to NIR wavelengths. Here, we assess evidence and identify key research questions regarding the thermoregulatory function of animal coloration, and specifically consider evidence for adaptive variation in NIR reflectance.This article is part of the themed issue 'Animal coloration: production, perception, function and application'. © 2017 The Author(s).

Near-surface 3D reflections seismic survey; Sanjigen senso hanshaho jishin tansa

Energy Technology Data Exchange (ETDEWEB)

Nakahigashi, H; Mitsui, H; Nakano, O; Kobayashi, T [DIA Consultants Co. Ltd., Tokyo (Japan)

1997-05-27

Faults are being actively investigated across Japan since the Great Hanshin-Awaji Earthquake. Discussed in this report is the application of the 3D near-surface reflection seismic survey in big cities. Data from trenching and drilling is used for the geological interpretation of the surroundings of a fault, and the reflection seismic survey is used to identify the position, etc., of the fault. In this article, when the results obtained from the experimental field are examined, it is found that the conventional 2D imaging reflection survey betrays the limit of its capability when the geological structure is complicated, that the 3D reflection seismic survey, on the contrary, is capable of high-precision imaging and, when augmented by drilling, etc., becomes capable of a more detailed interpretation, and that it also contributes effectively to the improvement of local disaster prevention in big cities. Using as the model the Tachikawa fault that runs near JR Tachikawa Station, embodiment of the 3D reflection seismic survey is reviewed. For the acquisition of data excellent in quality in a 3D reflection seismic survey conducted utilizing the roads in the sector chosen for experiment in the urban area, the shock generating points and receiving points should be positioned by taking into account the parameters in the bin arranging process so that the mid-points will be regularly distributed on the surface. 3 refs., 11 figs., 1 tab.

MODIS/Aqua Near Real Time (NRT) Surface Reflectance Daily L2G Global 250m SIN Grid

Data.gov (United States)

National Aeronautics and Space Administration — The MODIS Near Real Time (NRT) Surface Reflectance products are an estimate of the surface spectral reflectance as it would be measured at ground level in the...

Potential Long-Term Records of Surface Albedo at Fine Spatiotemporal Resolution from Landsat/Sentinle-2A Surface Reflectance and MODIS/VIIRS BRDF

Science.gov (United States)

Li, Z.; Schaaf, C.; Shuai, Y.; Liu, Y.; Sun, Q.; Erb, A.; Wang, Z.

2016-12-01

The land surface albedo products at fine spatial resolutions are generated by coupling surface reflectance (SR) from Landsat (30 m) or Sentinel-2A (20 m) with concurrent surface anisotropy information (the Bidirectional Reflectance Distribution Function - BRDF) at coarser spatial resolutions from sequential multi-angular observations by the Moderate Resolution Imaging Spectroradiometer (MODIS) or its successor, the Visible Infrared Imaging Radiometer Suite (VIIRS). We assess the comparability of four types of fine-resolution albedo products (black-sky and white-sky albedos over the shortwave broad band) generated by coupling, (1) Landsat-8 Optical Land Imager (OLI) SR with MODIS BRDF; (2) OLI SR with VIIRS BRDF; (3) Sentinel-2A MultiSpectral Instrument (MSI) SR with MODIS BRDF; and (4) MSI SR with VIIRS BRDF. We evaluate the accuracy of these four types of fine-resolution albedo products using ground tower measurements of surface albedo over six SURFace RADiation Network (SURFRAD) sites in the United States. For comparison with the ground measurements, we estimate the actual (blue-sky) albedo values at the six sites by using the satellite-based retrievals of black-sky and white-sky albedos and taking into account the proportion of direct and diffuse solar radiation from the ground measurements at the sites. The coupling of the OLI and MSI SR with MODIS BRDF has already been shown to provide accurate fine-resolution albedo values. With demonstration of a high agreement in BRDF products from MODIS and VIIRS, we expect to see consistency between all four types of fine-resolution albedo products. This assurance of consistency between the couplings of both OLI and MSI with both MODIS and VIIRS guarantees the production of long-term records of surface albedo at fine spatial resolutions and an increased temporal resolution. Such products will be critical in studying land surface changes and associated surface energy balance over the dynamic and heterogeneous landscapes

Earth surface reflectance climatology from 3 years of OMI data

NARCIS (Netherlands)

Kleipool, Q.L.; Dobber, M.R.; Haan, de J.F.; Levelt, P.F.

2008-01-01

Global maps of the Earth's surface Lambertian equivalent reflectance (LER) are constructed using 3 years of Ozone Monitoring Instrument (OMI) measurements obtained between October 2004 and October 2007 at 23 wavelengths between 328 and 500 nm. The maps are constructed on a 0.5° by 0.5°

Bioinspired Functional Surfaces for Technological Applications

Science.gov (United States)

Sharma, Vipul; Kumar, Suneel; Reddy, Kumbam Lingeshwar; Bahuguna, Ashish; Krishnan, Venkata

2016-08-01

Biological matters have been in continuous encounter with extreme environmental conditions leading to their evolution over millions of years. The fittest have survived through continuous evolution, an ongoing process. Biological surfaces are the important active interfaces between biological matters and the environment, and have been evolving over time to a higher state of intelligent functionality. Bioinspired surfaces with special functionalities have grabbed attention in materials research in the recent times. The microstructures and mechanisms behind these functional biological surfaces with interesting properties have inspired scientists to create artificial materials and surfaces which possess the properties equivalent to their counterparts. In this review, we have described the interplay between unique multiscale (micro- and nano-scale) structures of biological surfaces with intrinsic material properties which have inspired researchers to achieve the desired wettability and functionalities. Inspired by naturally occurring surfaces, researchers have designed and fabricated novel interfacial materials with versatile functionalities and wettability, such as superantiwetting surfaces (superhydrophobic and superoleophobic), omniphobic, switching wettability and water collecting surfaces. These strategies collectively enable functional surfaces to be utilized in different applications such as fog harvesting, surface-enhanced Raman spectroscopy (SERS), catalysis, sensing and biological applications. This paper delivers a critical review of such inspiring biological surfaces and artificial bioinspired surfaces utilized in different applications, where material science and engineering have merged by taking inspiration from the natural systems.

Mars analog minerals' spectral reflectance characteristics under Martian surface conditions

Science.gov (United States)

Poitras, J. T.; Cloutis, E. A.; Salvatore, M. R.; Mertzman, S. A.; Applin, D. M.; Mann, P.

2018-05-01

We investigated the spectral reflectance properties of minerals under a simulated Martian environment. Twenty-eight different hydrated or hydroxylated phases of carbonates, sulfates, and silica minerals were selected based on past detection on Mars through spectral remote sensing data. Samples were ground and dry sieved to <45 μm grain size and characterized by XRD before and after 133 days inside a simulated Martian surface environment (pressure 5 Torr and CO2 fed). Reflectance spectra from 0.35 to 4 μm were taken periodically through a sapphire (0.35-2.5 μm) and zinc selenide (2.5-4 μm) window over a 133-day period. Mineral stability on the Martian surface was assessed through changes in spectral characteristics. Results indicate that the hydrated carbonates studied would be stable on the surface of Mars, only losing adsorbed H2O while maintaining their diagnostic spectral features. Sulfates were less stable, often with shifts in the band position of the SO, Fe, and OH absorption features. Silicas displayed spectral shifts related to SiOH and hydration state of the mineral surface, while diagnostic bands for quartz were stable. Previous detection of carbonate minerals based on 2.3-2.5 μm and 3.4-3.9 μm features appears to be consistent with our results. Sulfate mineral detection is more questionable since there can be shifts in band position related to SO4. The loss of the 0.43 μm Fe3+ band in many of the sulfates indicate that there are fewer potential candidates for Fe3+ sulfates to permanently exist on the Martian surface based on this band. The gypsum sample changed phase to basanite during desiccation as demonstrated by both reflectance and XRD. Silica on Mars has been detected using band depth ratio at 1.91 and 1.96 μm and band minimum position of the 1.4 μm feature, and the properties are also used to determine their age. This technique continues to be useful for positive silica identifications, however, silica age appears to be less consistent

Surface correlation function analysis of high resolution scattering data from mirrored surfaces obtained using a triple-axis X-ray diffractometer

DEFF Research Database (Denmark)

Christensen, Finn Erland; Hornstrup, Allan; Schnopper, H. W.

1988-01-01

methods is that they are bandwidth-limited. A crucial point in the analysis of data is, therefore, to specify accurately the wavelength bandwidth limitation and to determine the surface autocorrelation function within this bandwidth. The authors present a number of scattering measurements obtained using...... a triple-axis perfect-crystal X-ray diffractometer and the results of an autocorrelation function analysis. Furthermore, they present some measurements of integrated reflectivity, which they believe provide evidence for microroughness in the range from a few angstroms to tens of microns...

Gain-Enhanced On-Chip Antenna Utilizing Artificial Magnetic Conductor Reflecting Surface at 94 GHz

KAUST Repository

Nafe, Mahmoud

2015-08-04

Nowadays, there is a growing demand for high frequency-bandwidth mm-wave (30-300 GHz) electronic wireless transceiver systems to support applications such as high data-rate wireless communication and high resolution imaging. Such mm-wave systems are becoming more feasible due to the extreme transistor downscaling in silicon-based integrated circuits, which enabled densely-integrated high-speed elec- tronics operating up to more than 100 GHz with low fabrication cost. To further enhance system integrability, it is required to implement all wireless system compo- nents on the chip. Presently, the last major barrier to true System-on-Chip (SoC) realization is the antenna implementation on the silicon chip. Although at mm-wave frequencies the antenna size becomes small enough to fit on chip, the antenna performance is greatly deteriorated due the high conductivity and high relative permittivity of the silicon substrate. The negative e↵ects of the silicon substrate could be avoided by using a metallic reflecting surface on top of silicon, which e↵ectively isolates the antenna from the silicon. However, this approach has the shortcoming of having to implement the antenna on the usually very thin silicon oxide layer of a typical CMOS fabrication process (10’s of μm). This forces the antenna to be in a very close proximity (less than one hundredth of a wavelength) to the reflecting surface. In this regime, the use of conventional metallic reflecting surface for silicon shielding has severe e↵ects on the antenna performance as it tends to reduce the antenna radiation resistance resulting in most of the energy being absorbed rather than radiated. In this work, the use of specially patterned reflecting surfaces for improving on- chip antenna performance is investigated. By using a periodic metallic surface on top of a grounded substrate, the structure can mimic the behavior of a perfect mag- netic conductor, hence called Artificial Magnetic Conductor (AMC) surface

LiDAR Relative Reflectivity Surface (2011) for Coral Bay, St. John

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — This image represents a LiDAR (Light Detection & Ranging) 0.3x0.3 meter resolution relative seafloor reflectivity surface for Coral Bay, St. John in the U.S....

LiDAR Relative Reflectivity Surface (2011) for Fish Bay, St. John

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — This image represents a LiDAR (Light Detection & Ranging) 0.3x0.3 meter resolution relative seafloor reflectivity surface for Fish Bay, St. John in the U.S....

Directional statistics-based reflectance model for isotropic bidirectional reflectance distribution functions.

Science.gov (United States)

Nishino, Ko; Lombardi, Stephen

2011-01-01

We introduce a novel parametric bidirectional reflectance distribution function (BRDF) model that can accurately encode a wide variety of real-world isotropic BRDFs with a small number of parameters. The key observation we make is that a BRDF may be viewed as a statistical distribution on a unit hemisphere. We derive a novel directional statistics distribution, which we refer to as the hemispherical exponential power distribution, and model real-world isotropic BRDFs as mixtures of it. We derive a canonical probabilistic method for estimating the parameters, including the number of components, of this novel directional statistics BRDF model. We show that the model captures the full spectrum of real-world isotropic BRDFs with high accuracy, but a small footprint. We also demonstrate the advantages of the novel BRDF model by showing its use for reflection component separation and for exploring the space of isotropic BRDFs.

An instrument for the measurement of road surface reflection properties

DEFF Research Database (Denmark)

Corell, Dennis Dan; Sørensen, K.

2017-01-01

Road surface reflection data in the form of standard r-tables serve as input for design calculations of road lighting installations on traffic roads. However, in several countries the use of the standard r-tables has not been verified by measurement in a long period of time, while the types of road...

Bi-directional Reflectance of Icy Surface Analogs: A Dual Approach

Science.gov (United States)

Quinones, Juan Manuel; Vides, Christina; Nelson, Robert M.; Boryta, Mark; Mannat, Ken s.

2018-01-01

Bi-directional reflectance measurements of analogs for planetary regolith have provided insight into the surface properties of planetary satellites and small bodies. Because Aluminum Oxide (Al2O3) and water ice share a similar hexagonal crystalline structure, the former has been used in laboratory experiments to simulate the regolith of both icy and dusty planetary bodies. By measuring various sizes of well sorted size fractions of Al2O3, the reflectance phase curve and porosity of a planetary regolith can be determined. We have designed an experiment to test the laboratory measurements produced by Nelson et al. (2000). Additionally, we made reflectance measurements for other alkali-halide compounds that could be used for applications beyond astronomy and planetary science.In order to provide an independent check on the Nelson et al. data, we designed an instrument with a different configuration. While both instruments take bidirectional reflectance measurements, our instrument, the Rigid Photometric Goniometer (RPG), is fixed at a phase angle of 5° and detects the scattered light with a photomultiplier tube (PMT). The PMT current is then measured with an electrometer. Following the example of Nelson et al., we measured the bidirectional reflectance of Al2O3 particulate size fractions between 0.1sizes from 20size that provided optimal, or maximum, reflectance for each compound. Our conclusions bring confirmation and clarity to photometric sciences.

Early Evaluation of the VIIRS Calibration, Cloud Mask and Surface Reflectance Earth Data Records

Science.gov (United States)

Vermote, Eric; Justice, Chris; Csiszar, Ivan

2014-01-01

Surface reflectance is one of the key products fromVIIRS and as withMODIS, is used in developing several higherorder land products. The VIIRS Surface Reflectance (SR) Intermediate Product (IP) is based on the heritageMODIS Collection 5 product (Vermote, El Saleous, & Justice, 2002). The quality and character of surface reflectance depend on the accuracy of the VIIRS Cloud Mask (VCM), the aerosol algorithms and the adequate calibration of the sensor. The focus of this paper is the early evaluation of the VIIRS SR product in the context of the maturity of the operational processing system, the Interface Data Processing System (IDPS). After a brief introduction, the paper presents the calibration performance and the role of the surface reflectance in calibration monitoring. The analysis of the performance of the cloud mask with a focus on vegetation monitoring (no snow conditions) shows typical problems over bright surfaces and high elevation sites. Also discussed is the performance of the aerosol input used in the atmospheric correction and in particular the artifacts generated by the use of the Navy Aerosol Analysis and Prediction System. Early quantitative results of the performance of the SR product over the AERONET sites showthatwith the fewadjustments recommended, the accuracy iswithin the threshold specifications. The analysis of the adequacy of the SR product (Land PEATE adjusted version) in applications of societal benefits is then presented. We conclude with a set of recommendations to ensure consistency and continuity of the JPSS mission with the MODIS Land Climate Data Record.

Glazed ceramic roof tiles: influence of surface features in the solar reflectance index

International Nuclear Information System (INIS)

Bortoli, Leitcia Silva de; Stapait, Camila Cristina; Marinoski, Deivis Luis; Fredel, Marcio Celso; Schabbach, Luciana M.

2016-01-01

In this study the influence of surface features of ceramic roof tiles in the solar reflectance index were evaluated. Two glazed ceramic roof tiles (type stoneware) with the same color (ivory) but with different appearance (matte and brilliant) were the focus of the analysis. The Solar Reflectance Index (SRI) of the roofs tiles were determined by the solar reflectance values (UV-VIS-NIR) and emittance, measured in laboratory. The samples showed SRI> 39 in accordance with LEED certification criteria (Leadership in Energy and Environmental Design), contributing to minimizing the Heat Island Effects. Although the matte roof tile shows a slightly higher SRI value (82) than the brilliant one (78), the results for the variables that composes the SRI value (reflectance and emittance) were very similar. Analysis of XRD, SEM and EDS performed on the surfaces of the two roofs indicated for the matte glaze the presence of microcrystals (with barium and zinc) that can contribute to the slightly highest value of SRI. The roughness (optical interferometer white light) and the brightness (brightness meter) of the samples were also measured. (author)

Low reflectance high power RF load

Science.gov (United States)

Ives, R. Lawrence; Mizuhara, Yosuke M.

2016-02-02

A load for traveling microwave energy has an absorptive volume defined by cylindrical body enclosed by a first end cap and a second end cap. The first end cap has an aperture for the passage of an input waveguide with a rotating part that is coupled to a reflective mirror. The inner surfaces of the absorptive volume consist of a resistive material or are coated with a coating which absorbs a fraction of incident RF energy, and the remainder of the RF energy reflects. The angle of the reflector and end caps is selected such that reflected RF energy dissipates an increasing percentage of the remaining RF energy at each reflection, and the reflected RF energy which returns to the rotating mirror is directed to the back surface of the rotating reflector, and is not coupled to the input waveguide. Additionally, the reflector may have a surface which generates a more uniform power distribution function axially and laterally, to increase the power handling capability of the RF load. The input waveguide may be corrugated for HE11 mode input energy.

Manipulating Acoustic Wavefront by Inhomogeneous Impedance and Steerable Extraordinary Reflection

Science.gov (United States)

Zhao, Jiajun; Li, Baowen; Chen, Zhining; Qiu, Cheng-Wei

2013-08-01

We unveil the connection between the acoustic impedance along a flat surface and the reflected acoustic wavefront, in order to empower a wide wariety of novel applications in acoustic community. Our designed flat surface can generate double reflections: the ordinary reflection and the extraordinary one whose wavefront is manipulated by the proposed impedance-governed generalized Snell's law of reflection (IGSL). IGSL is based on Green's function and integral equation, instead of Fermat's principle for optical wavefront manipulation. Remarkably, via the adjustment of the designed specific acoustic impedance, extraordinary reflection can be steered for unprecedented acoustic wavefront while that ordinary reflection can be surprisingly switched on or off. The realization of the complex discontinuity of the impedance surface has been proposed using Helmholtz resonators.

Recent Developments in the X-Ray Reflectivity Analysis for Rough Surfaces and Interfaces of Multilayered Thin Film Materials

Directory of Open Access Journals (Sweden)

Yoshikazu Fujii

2013-01-01

Full Text Available X-ray reflectometry is a powerful tool for investigations on rough surface and interface structures of multilayered thin film materials. The X-ray reflectivity has been calculated based on the Parratt formalism, accounting for the effect of roughness by the theory of Nevot-Croce conventionally. However, in previous studies, the calculations of the X-ray reflectivity often show a strange effect where interference effects would increase at a rough surface. And estimated surface and interface roughnesses from the X-ray reflectivity measurements did not correspond to the TEM image observation results. The strange result had its origin in a used equation due to a serious mistake in which the Fresnel transmission coefficient in the reflectivity equation is increased at a rough interface because of a lack of consideration of diffuse scattering. In this review, a new accurate formalism that corrects this mistake is presented. The new accurate formalism derives an accurate analysis of the X-ray reflectivity from a multilayer surface of thin film materials, taking into account the effect of roughness-induced diffuse scattering. The calculated reflectivity by this accurate reflectivity equation should enable the structure of buried interfaces to be analyzed more accurately.

Radiative transfer in shrub savanna sites in Niger: preliminary results from HAPEX-Sahel. 1. Modelling surface reflectance using a geometric-optical approach

International Nuclear Information System (INIS)

Franklin, J.; Duncan, J.; Huete, A.R.; Leeuwen, W.J.D. van; Li, X.; Bégué, A.

1994-01-01

To use optical remote sensing to monitor land surface-climate interactions over large areas, algorithms must be developed to relate multispectral measurements to key variables controlling the exchange of matter (water, carbon dioxide) and energy between the land surface and the atmosphere. The proportion of the ground covered by vegetation and the interception of photosynthetically active radiation (PAR) by vegetation are examples of two variables related to evapotranspiration and primary production, respectively. An areal-proportion model of the multispectral reflectance of shrub savanna, composed of scattered shrubs with a grass, forb or soil understory, predicted the reflectance of two 0.5 km 2 sites as the area-weighted average of the shrub and understory or ‘background’ reflectances. Although the shaded crown and shaded background have darker reflectances, ignoring them in the area-weighted model is not serious when shrub cover is low and solar zenith angle is small. A submodel predicted the reflectance of the shrub crown as a function of the foliage reflectance and amount of plant material within the crown, and the background reflectance scattered or transmitted through canopy gaps (referred to as a soil—plant ‘spectral interaction’ term). One may be able to combine these two models to estimate both the fraction of vegetation cover and interception of PAR by green vegetation in a shrub savanna. (author)

Ellipsometry of functional organic surfaces and films

CERN Document Server

Eichhorn, Klaus-Jochen

2018-01-01

This new edition provides a state-of-the-art survey of ellipsometric methods used to study organic films and surfaces, from laboratory to synchrotron applications, with a special focus on in-situ use in processing environments and at solid-liquid interfaces. Thanks to the development of functional organic, meta- and hybrid materials for new optical, electronic, sensing and biotechnological devices, the ellipsometric analysis of optical and material properties has made tremendous strides over the past few years. The second edition has been updated to reflect the latest advances in ellipsometric methods. The new content focuses on the study of anisotropic materials, conjugated polymers, polarons, self-assembled monolayers, industrial membranes, adsorption of proteins, enzymes and RGD-peptides, as well as the correlation of ellipsometric spectra to structure and molecular interactions.

A functional equation for the specular reflection of rays.

Science.gov (United States)

Le Bot, A

2002-10-01

This paper aims to generalize the "radiosity method" when applied to specular reflection. Within the field of thermics, the radiosity method is also called the "standard procedure." The integral equation for incident energy, which is usually derived for diffuse reflection, is replaced by a more appropriate functional equation. The latter is used to solve some specific problems and it is shown that all the classical features of specular reflection, for example, the existence of image sources, are embodied within this equation. This equation can be solved with the ray-tracing technique, despite the implemented mathematics being quite different. Several interesting features of the energy field are presented.

Ray splitting in the reflection and refraction of surface acoustic waves in anisotropic solids.

Science.gov (United States)

Every, A G; Maznev, A A

2010-05-01

This paper examines the conditions for, and provides examples of, ray splitting in the reflection and refraction of surface acoustic waves (SAW) in elastically anisotropic solids at straight obstacles such as edges, surface breaking cracks, and interfaces between different solids. The concern here is not with the partial scattering of an incident SAW's energy into bulk waves, but with the occurrence of more than one SAW ray in the reflected and/or transmitted wave fields, by analogy with birefringence in optics and mode conversion of bulk elastic waves at interfaces. SAW ray splitting is dependent on the SAW slowness curve possessing concave regions, which within the constraint of wave vector conservation parallel to the obstacle allows multiple outgoing SAW modes for certain directions of incidence and orientation of obstacle. The existence of pseudo-SAW for a given surface provides a further channel for ray splitting. This paper discusses some typical material configurations for which SAW ray splitting occurs. An example is provided of mode conversion entailing backward reflection or negative refraction. Experimental demonstration of ray splitting in the reflection of a laser generated SAW in GaAs(111) is provided. The calculation of SAW mode conversion amplitudes lies outside the scope of this paper.

Bioinspired surface functionalization of metallic biomaterials.

Science.gov (United States)

Su, Yingchao; Luo, Cheng; Zhang, Zhihui; Hermawan, Hendra; Zhu, Donghui; Huang, Jubin; Liang, Yunhong; Li, Guangyu; Ren, Luquan

2018-01-01

Metallic biomaterials are widely used for clinical applications because of their excellent mechanical properties and good durability. In order to provide essential biofunctionalities, surface functionalization is of particular interest and requirement in the development of high-performance metallic implants. Inspired by the functional surface of natural biological systems, many new designs and conceptions have recently emerged to create multifunctional surfaces with great potential for biomedical applications. This review firstly introduces the metallic biomaterials, important surface properties, and then elaborates some strategies on achieving the bioinspired surface functionalization for metallic biomaterials. Copyright © 2017 Elsevier Ltd. All rights reserved.

Airborne hyperspectral observations of surface and cloud directional reflectivity using a commercial digital camera

Directory of Open Access Journals (Sweden)

A. Ehrlich

2012-04-01

Full Text Available Spectral radiance measurements by a digital single-lens reflex camera were used to derive the directional reflectivity of clouds and different surfaces in the Arctic. The camera has been calibrated radiometrically and spectrally to provide accurate radiance measurements with high angular resolution. A comparison with spectral radiance measurements with the Spectral Modular Airborne Radiation measurement sysTem (SMART-Albedometer showed an agreement within the uncertainties of both instruments (6% for both. The directional reflectivity in terms of the hemispherical directional reflectance factor (HDRF was obtained for sea ice, ice-free ocean and clouds. The sea ice, with an albedo of ρ = 0.96 (at 530 nm wavelength, showed an almost isotropic HDRF, while sun glint was observed for the ocean HDRF (ρ = 0.12. For the cloud observations with ρ = 0.62, the cloudbow – a backscatter feature typically for scattering by liquid water droplets – was covered by the camera. For measurements above heterogeneous stratocumulus clouds, the required number of images to obtain a mean HDRF that clearly exhibits the cloudbow has been estimated at about 50 images (10 min flight time. A representation of the HDRF as a function of the scattering angle only reduces the image number to about 10 (2 min flight time.

The measured cloud and ocean HDRF have been compared to radiative transfer simulations. The ocean HDRF simulated with the observed surface wind speed of 9 m s⁻¹ agreed best with the measurements. For the cloud HDRF, the best agreement was obtained by a broad and weak cloudbow simulated with a cloud droplet effective radius of R_eff = 4 μm. This value agrees with the particle sizes derived from in situ measurements and retrieved from the spectral radiance of the SMART-Albedometer.

Does reflective functioning mediate the relationship between attachment and personality?

Science.gov (United States)

Nazzaro, Maria Paola; Boldrini, Tommaso; Tanzilli, Annalisa; Muzi, Laura; Giovanardi, Guido; Lingiardi, Vittorio

2017-10-01

Mentalization, operationalized as reflective functioning (RF), can play a crucial role in the psychological mechanisms underlying personality functioning. This study aimed to: (a) study the association between RF, personality disorders (cluster level) and functioning; (b) investigate whether RF and personality functioning are influenced by (secure vs. insecure) attachment; and (c) explore the potential mediating effect of RF on the relationship between attachment and personality functioning. The Shedler-Westen Assessment Procedure (SWAP-200) was used to assess personality disorders and levels of psychological functioning in a clinical sample (N = 88). Attachment and RF were evaluated with the Adult Attachment Interview (AAI) and Reflective Functioning Scale (RFS). Findings showed that RF had significant negative associations with cluster A and B personality disorders, and a significant positive association with psychological functioning. Moreover, levels of RF and personality functioning were influenced by attachment patterns. Finally, RF completely mediated the relationship between (secure/insecure) attachment and adaptive psychological features, and thus accounted for differences in overall personality functioning. Lack of mentalization seemed strongly associated with vulnerabilities in personality functioning, especially in patients with cluster A and B personality disorders. These findings provide support for the development of therapeutic interventions to improve patients' RF. Copyright © 2017 Elsevier B.V. All rights reserved.

Decadal changes of surface elevation over permafrost area estimated using reflected GPS signals

Science.gov (United States)

Liu, Lin; Larson, Kristine M.

2018-02-01

Conventional benchmark-based survey and Global Positioning System (GPS) have been used to measure surface elevation changes over permafrost areas, usually once or a few times a year. Here we use reflected GPS signals to measure temporal changes of ground surface elevation due to dynamics of the active layer and near-surface permafrost. Applying the GPS interferometric reflectometry technique to the multipath signal-to-noise ratio data collected by a continuously operating GPS receiver mounted deep in permafrost in Barrow, Alaska, we can retrieve the vertical distance between the antenna and reflecting surface. Using this unique kind of observables, we obtain daily changes of surface elevation during July and August from 2004 to 2015. Our results show distinct temporal variations at three timescales: regular thaw settlement within each summer, strong interannual variability that is characterized by a sub-decadal subsidence trend followed by a brief uplift trend, and a secular subsidence trend of 0.26 ± 0.02 cm year-1 during 2004 and 2015. This method provides a new way to fully utilize data from continuously operating GPS sites in cold regions for studying dynamics of the frozen ground consistently and sustainably over a long time.

Scanning tunnel microscopic image of tungsten (100) and (110) real surfaces and nature of conduction electron reflection

International Nuclear Information System (INIS)

Pryadkin, S.L.; Tsoj, V.S.

1988-01-01

The electrically polished (100) and (110) surfaces of tungsten are studied with the aid of a scanning tunnel microscope at atmospheric pressure. The (110) surface consists of a large number of atomically plane terraces whereas the (100) surface is faceted. The scanning tunnel microscope data can explain such results of experiments on transverse electron focussing as the strong dependence of the probability for specular reflection of conduction electrons scattered by the (100) surface on the electron de Broglie wavelength and the absence of a dependence of the probability for specular reflection on the wavelength for the (110) surface

Ultraviolet (UV)-reflective paint with ultraviolet germicidal irradiation (UVGI) improves decontamination of nosocomial bacteria on hospital room surfaces.

Science.gov (United States)

Jelden, Katelyn C; Gibbs, Shawn G; Smith, Philip W; Hewlett, Angela L; Iwen, Peter C; Schmid, Kendra K; Lowe, John J

2017-06-01

An ultraviolet germicidal irradiation (UVGI) generator (the TORCH, ClorDiSys Solutions, Inc.) was used to compare the disinfection of surface coupons (plastic from a bedrail, stainless steel, and chrome-plated light switch cover) in a hospital room with walls coated with ultraviolet (UV)-reflective paint (Lumacept) or standard paint. Each surface coupon was inoculated with methicillin-resistant Staphylococcus aureus (MRSA) or vancomycin-resistant Enterococcus faecalis (VRE), placed at 6 different sites within a hospital room coated with UV-reflective paint or standard paint, and treated by 10 min UVC exposure (UVC dose of 0-688 mJ/cm 2 between sites with standard paint and 0-553 mJ/cm 2 with UV-reflective paint) in 8 total trials. Aggregated MRSA concentrations on plastic bedrail surface coupons were reduced on average by 3.0 log 10 (1.8 log 10 Geometric Standard Deviation [GSD]) with standard paint and 4.3 log 10 (1.3 log 10 GSD) with UV-reflective paint (p = 0.0005) with no significant reduction differences between paints on stainless steel and chrome. Average VRE concentrations were reduced by ≥4.9 log 10 (surface types with UV-reflective paint and ≤4.1 log 10 (hospital bed from the UVGI generator, MRSA concentrations on average were reduced by 1.3 log 10 (1.7 log 10 GSD) with standard paint and 4.7 log 10 (1.3 log 10 GSD) with UV-reflective paint (p hospital room walls with UV-reflective paint enhanced UVGI disinfection of nosocomial bacteria on various surfaces compared to standard paint, particularly at a surface placement site indirectly exposed to UVC light.

An efficient approach for computing the geometrical optics field reflected from a numerically specified surface

Science.gov (United States)

Mittra, R.; Rushdi, A.

1979-01-01

An approach for computing the geometrical optic fields reflected from a numerically specified surface is presented. The approach includes the step of deriving a specular point and begins with computing the reflected rays off the surface at the points where their coordinates, as well as the partial derivatives (or equivalently, the direction of the normal), are numerically specified. Then, a cluster of three adjacent rays are chosen to define a 'mean ray' and the divergence factor associated with this mean ray. Finally, the ampilitude, phase, and vector direction of the reflected field at a given observation point are derived by associating this point with the nearest mean ray and determining its position relative to such a ray.

Recognition processes at a functionalized lipid surface observed with molecular resolution

DEFF Research Database (Denmark)

Vaknin, D.; Als-Nielsen, J.; Piepenstock, M.

1991-01-01

The specific binding of proteins to functionalized lipid monolayers on aqueous subphases was characterized by neutron reflectivity and fluorescence microscopy measurements. Due to the high affinity and high specificity of their noncovalent interaction, streptavidin (SA) and biotin (vitamin H) were...... with each protein molecule. Quantitative binding was found to occur at biotin surface concentrations as low as 1 molecule/1,250 angstrom 2 (compared with approximately 1 molecule/40 angstrom 2 for dense packing). This study demonstrates the application of a promising new tool for the systematic...

Study on the effect of ambient gas on nanostructure formation on metal surfaces during femtosecond laser ablation for fabrication of low-reflective surfaces

Energy Technology Data Exchange (ETDEWEB)

Smausz, Tomi, E-mail: tomi@physx.u-szeged.hu [MTA-SZTE Research Group on Photoacoustic Spectroscopy, University of Szeged, 6720 Szeged, Dóm tér 9 (Hungary); Department of Optics and Quantum Electronics, University of Szeged, H-6720 Szeged, Dóm tér 9 (Hungary); Csizmadia, Tamás [Department of Optics and Quantum Electronics, University of Szeged, H-6720 Szeged, Dóm tér 9 (Hungary); Attosecond Light Pulse Source, ELI-Hu Nkft, H-6720 Szeged, Dugonics ter 13 (Hungary); Tápai, Csaba; Kopniczky, Judit [Department of Optics and Quantum Electronics, University of Szeged, H-6720 Szeged, Dóm tér 9 (Hungary); Oszkó, Albert [Department of Physical Chemistry and Material Science, University of Szeged, H-6720 Szeged, Aradi vértanuk tere 1 (Hungary); Ehrhardt, Martin; Lorenz, Pierre; Zimmer, Klaus; Prager, Andrea [Leibniz-Institut für Oberflächenmodifizierung e.V., Permoserstr. 15, 04318 Leipzig (Germany); Hopp, Béla [Department of Optics and Quantum Electronics, University of Szeged, H-6720 Szeged, Dóm tér 9 (Hungary)

2016-12-15

Highlights: • Metal surfaces were irradiated with femtosecond laser in different gas environments. • The reflectivity, morphology and chemical composition of the surfaces were studied. • Darkening was influenced by chemical and physical interaction of the plume and gas. • Molecular mass of the applied gas had an impact on the nanostructure formation. • For some of the used metals the oxide formation affected the reflective properties. - Abstract: Nanostructure formation on bulk metals (silver, gold, copper and titanium) by femtosecond Ti-sapphire laser irradiation (775 nm, 150 fs) is studied aiming the production of low-reflectivity surfaces and the better understanding of the development process. The experiments were performed in nitrogen, air, oxygen and helium environments at atmospheric pressure. The samples were irradiated with fluences in the 0.1–2 J/cm{sup 2} range and an average pulse number of 100 falling over a given area. The reflectivity of the treated surfaces was determined by a microspectrometer in the 450–800 nm range and their morphology was studied by scanning electron microscopy. The gas ambience influenced the results via two effects: formation processes and the chemically-induced modifications of the nanostructures. In case of He the nanoparticle aggregates–otherwise generally present–are predominantly missing, which leads to a lower darkening efficiency. The presence of oxygen enhances the darkening effect for copper mostly at lower fluences, while causes a slow increase in reflectivity in the case of titanium (in case of pure oxygen) in the high fluence range. The surface morphology in case of nitrogen and air were quite similar probably due to their close molecular mass values.

Probing Ultrafast Electron Dynamics at Surfaces Using Soft X-Ray Transient Reflectivity Spectroscopy

Science.gov (United States)

Baker, L. Robert; Husek, Jakub; Biswas, Somnath; Cirri, Anthony

The ability to probe electron dynamics with surface sensitivity on the ultrafast time scale is critical for understanding processes such as charge separation, injection, and surface trapping that mediate efficiency in catalytic and energy conversion materials. Toward this goal, we have developed a high harmonic generation (HHG) light source for femtosecond soft x-ray reflectivity. Using this light source we investigated the ultrafast carrier dynamics at the surface of single crystalline α-Fe2O3, polycrystalline α-Fe2O3, and the mixed metal oxide, CuFeO2. We have recently demonstrated that CuFeO2 in particular is a selective catalyst for photo-electrochemical CO2 reduction to acetate; however, the role of electronic structure and charge carrier dynamics in mediating catalytic selectivity has not been well understood. Soft x-ray reflectivity measurements probe the M2,3, edges of the 3d transition metals, which provide oxidation and spin state resolution with element specificity. In addition to chemical state specificity, these measurements are also surface sensitive, and by independently simulating the contributions of the real and imaginary components of the complex refractive index, we can differentiate between surface and sub-surface contributions to the excited state spectrum. Accordingly, this work demonstrates the ability to probe ultrafast carrier dynamics in catalytic materials with element and chemical state specificity and with surface sensitivity.

Retrieval of the Land Surface Reflectance for Landsat-8 and Sentinel-2 and its validation.

Science.gov (United States)

Roger, J. C.; Vermote, E.; Skakun, S.; Franch, B.; Holben, B. N.; Justice, C. O.

2017-12-01

The land surface reflectance is a fundamental climate data record at the basis of the derivation of other climate data records (Albedo, LAI/Fpar, Vegetation indices) and a key parameter in the understanding of the land-surface-climate processes. For 25 years, Vermote and al. develop atmospheric corrections methods to define a land surface reflectance product for various satellites (AVHRR, MODIS, VIIRS…). This presentation highlights the algorithms developed both for Landsant-8 and Sentinel-2. We also emphasize the validation of the "Land surface reflectance" satellite products, which is a very important step to be done. For that purpose, we compared the surface reflectance products to a reference determined by using the accurate radiative transfer code 6S and very detailed measurements of the atmosphere obtained over the AERONET network (which allows to test for a large range of aerosol characteristics); formers being important inputs for atmospheric corrections. However, the application of this method necessitates the definition of a very detailed protocol for the use of AERONET data especially as far as size distribution and absorption are concerned, so that alternative validation methods or protocols could be compared. We describe here the protocol we have been working on based on our experience with the AERONET data and its application to Landsat-8 and Sentinel-2). We also derive a detailed error budget in relation to this approach. For a mean loaded atmosphere, t550 less than 0.25, the maximum uncertainty is 0.0025 corresponding to a relative uncertainty (in the RED channels): U 0.10, and 1% rsurf > 0.04.

Non-invasive identification of metal-oxalate complexes on polychrome artwork surfaces by reflection mid-infrared spectroscopy.

Science.gov (United States)

Monico, Letizia; Rosi, Francesca; Miliani, Costanza; Daveri, Alessia; Brunetti, Brunetto G

2013-12-01

In this work a reflection mid-infrared spectroscopy study of twelve metal-oxalate complexes, of interest in art conservation science as alteration compounds, was performed. Spectra of the reference materials highlighted the presence of derivative-like and/or inverted features for the fundamental vibrational modes as result of the main contribution from the surface component of the reflected light. In order to provide insights in the interpretation of theses spectral distortions, reflection spectra were compared with conventional transmission ones. The Kramers-Kronig (KK) algorithm, employed to correct for the surface reflection distortions, worked properly only for the derivative-like bands. Therefore, to pay attention to the use of this algorithm when interpreting the reflection spectra is recommended. The outcome of this investigation was exploited to discriminate among different oxalates on thirteen polychrome artworks analyzed in situ by reflection mid-infrared spectroscopy. The visualization of the νs(CO) modes (1400-1200 cm(-1)) and low wavenumber bands (below 900 cm(-1)) in the raw reflection profiles allowed Ca, Cu and Zn oxalates to be identified. Further information about the speciation of different hydration forms of calcium oxalates were obtained by using the KK transform. The work proves reflection mid-infrared spectroscopy to be a reliable and sensitive spectro-analytical method for identifying and mapping different metal-oxalate alteration compounds on the surface of artworks, thus providing conservation scientists with a non-invasive tool to obtain information on the state of conservation and causes of alteration of artworks. Copyright © 2013 Elsevier B.V. All rights reserved.

Modelling the bidirectional reflectance distribution functions (BRDF of sea areas polluted by oil

Directory of Open Access Journals (Sweden)

Zbigniew Otremba

2004-12-01

Full Text Available The paper discusses the possibilities of modelling the bi-directional reflectance distribution function (BRDF in sea areas polluted by oil. Three sea basin models are considered: a coastal one free of oil, one polluted by an oil film and one polluted by an oil emulsion. The following concentrations of oil were compared: for the film, 1 cm3 of oil per 1 m2 water surface, for the emulsion 1 cm3 of oil in 1 m3 of water. The optical properties of Romashkino crude oil were taken into consideration, as were various angles of incident solar light. The conversion of BRDFs into a directional distribution of the optical contrast of polluted areas is demonstrated.

Classification of Clean and Dirty Pighouse Surfaces Based on Spectral Reflectance

DEFF Research Database (Denmark)

Blanke, Mogens; Braithwaite, Ian David; Zhang, Guo-Qiang

2004-01-01

of designing a vision based system to locate dirty areas and subsequently direct a cleaning robot to remove dirt. Novel results include the characterisation of the spectral reflectance of real surfaces and dirt in a pig house and the design of illumination to obtain discrimination of clean from dirty areas...

Total reflection coefficients of low-energy photons presented as universal functions

Directory of Open Access Journals (Sweden)

Ljubenov Vladan

2010-01-01

Full Text Available The possibility of expressing the total particle and energy reflection coefficients of low-energy photons in the form of universal functions valid for different shielding materials is investigated in this paper. The analysis is based on the results of Monte Carlo simulations of photon reflection by using MCNP, FOTELP, and PENELOPE codes. The normal incidence of the narrow monoenergetic photon beam of the unit intensity and of initial energies from 20 keV up to 100 keV is considered, and particle and energy reflection coefficients from the plane homogenous targets of water, aluminum, and iron are determined and compared. The representations of albedo coefficients on the initial photon energy, on the probability of large-angle photon scattering, and on the mean number of photon scatterings are examined. It is found out that only the rescaled albedo coefficients dependent on the mean number of photon scatterings have the form of universal functions and these functions are determined by applying the least square method.

Micro reflectance difference techniques: Optical probes for surface exploration

Energy Technology Data Exchange (ETDEWEB)

Lastras-Martinez, L.F.; Del Pozo-Zamudio, O.; Herrera-Jasso, R.; Ulloa-Castillo, N.A.; Balderas-Navarro, R.E.; Ortega-Gallegos, J.; Lastras-Martinez, A. [Instituto de Investigacion en Comunicacion Optica, Universidad Autonoma de San Luis Potosi, Alvaro Obregon 64, 78000 San Luis Potosi, S.L.P. (Mexico)

2012-06-15

Micro reflectance difference spectroscopy ({mu}-RDS) is a promising tool for the in-situ and ex-situ characterization of semiconductors surfaces and interfaces. We discuss and compare two different approaches used to measure {mu}-RD spectra. One is based on a charge-coupled device (CCD) camera, while the other uses a laser and a XY translation stage. To show the performance of these systems, we have measured surface optical anisotropies of GaSb(001) sample on which anisotropic strains have been generated by preferential mechanical polishing along [110] and [1 anti 10] directions. The spectrometers are complementary and the selection of one of them depends on the sample to be investigated and on experimental conditions. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Orthogonal functionalization of nanoporous substrates: control of 3D surface functionality.

Science.gov (United States)

Lazzara, Thomas D; Kliesch, Torben-Tobias; Janshoff, Andreas; Steinem, Claudia

2011-04-01

Anodic aluminum oxide (AAO) membranes with aligned, cylindrical, nonintersecting pores were selectively functionalized in order to create dual-functionality substrates with different pore-rim and pore-interior surface functionalities, using silane chemistry. We used a two-step process involving an evaporated thin gold film to protect the underlying surface functionality of the pore rims. Subsequent treatment with oxygen plasma of the modified AAO membrane removed the unprotected organic functional groups, i.e., the pore-interior surface. After gold removal, the substrate became optically transparent, and displayed two distinct surface functionalities, one at the pore-rim surface and another at the pore-interior surface. We achieved a selective hydrophobic functionalization with dodecyl-trichlorosilane of either the pore rims or the pore interiors. The deposition of planar lipid membranes on the functionalized areas by addition of small unilamellar vesicles occurred in a predetermined fashion. Small unilamellar vesicles only ruptured upon contact with the hydrophobic substrate regions forming solid supported hybrid bilayers. In addition, pore-rim functionalization with dodecyl-trichlorosilane allowed the formation of pore-spanning hybrid lipid membranes as a result of giant unilamellar vesicle rupture. Confocal laser scanning microscopy was employed to identify the selective spatial localization of the adsorbed fluorescently labeled lipids. The corresponding increase in the AAO refractive index due to lipid adsorption on the hydrophobic regions was monitored by optical waveguide spectroscopy. This simple orthogonal functionalization route is a promising method to control the three-dimensional surface functionality of nanoporous films. © 2011 American Chemical Society

Surface functionalization of epitaxial graphene on SiC by ion irradiation for gas sensing application

Energy Technology Data Exchange (ETDEWEB)

Kaushik, Priya Darshni, E-mail: kaushik.priyadarshni@gmail.com [Department of Physics, Chemistry and Biology, Linköping University, SE-58183 Linköping (Sweden); Department of Physics, Jamia Millia Islamia, New Delhi, 110025 (India); Ivanov, Ivan G.; Lin, Pin-Cheng [Department of Physics, Chemistry and Biology, Linköping University, SE-58183 Linköping (Sweden); Kaur, Gurpreet [Department of Physics and Astrophysics, University of Delhi, Delhi, 110007 (India); Eriksson, Jens [Department of Physics, Chemistry and Biology, Linköping University, SE-58183 Linköping (Sweden); Lakshmi, G.B.V.S. [Inter-University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi, 110067 (India); Avasthi, D.K. [Inter-University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi, 110067 (India); Amity Institute of Nanotechnology, Noida 201313 (India); Gupta, Vinay [Department of Physics and Astrophysics, University of Delhi, Delhi, 110007 (India); Aziz, Anver; Siddiqui, Azher M. [Department of Physics, Jamia Millia Islamia, New Delhi, 110025 (India); Syväjärvi, Mikael [Department of Physics, Chemistry and Biology, Linköping University, SE-58183 Linköping (Sweden); Yazdi, G. Reza, E-mail: yazdi@ifm.liu.se [Department of Physics, Chemistry and Biology, Linköping University, SE-58183 Linköping (Sweden)

2017-05-01

Highlights: • For the first time the gas sensing application of SHI irradiated epitaxial graphene on SiC is explored. • Surface morphology of irradiated graphene layers showed graphene folding, hillocks, and formation of wrinkles. • Existence of an optimal fluence which maximize the gas sensing response towards NO{sub 2} and NH{sub 3} gases. - Abstract: In this work, surface functionalization of epitaxial graphene grown on silicon carbide was performed by ion irradiation to investigate their gas sensing capabilities. Swift heavy ion irradiation using 100 MeV silver ions at four varying fluences was implemented on epitaxial graphene to investigate morphological and structural changes and their effects on the gas sensing capabilities of graphene. Sensing devices are expected as one of the first electronic applications using graphene and most of them use functionalized surfaces to tailor a certain function. In our case, we have studied irradiation as a tool to achieve functionalization. Morphological and structural changes on epitaxial graphene layers were investigated by atomic force microscopy, Raman spectroscopy, Raman mapping and reflectance mapping. The surface morphology of irradiated graphene layers showed graphene folding, hillocks, and formation of wrinkles at highest fluence (2 × 10{sup 13} ions/cm{sup 2}). Raman spectra analysis shows that the graphene defect density is increased with increasing fluence, while Raman mapping and reflectance mapping show that there is also a reduction of monolayer graphene coverage. The samples were investigated for ammonia and nitrogen dioxide gas sensing applications. Sensors fabricated on pristine and irradiated samples showed highest gas sensing response at an optimal fluence. Our work provides new pathways for introducing defects in controlled manner in epitaxial graphene, which can be used not only for gas sensing application but also for other applications, such as electrochemical, biosensing, magnetosensing and

Surface functionalization of epitaxial graphene on SiC by ion irradiation for gas sensing application

International Nuclear Information System (INIS)

Kaushik, Priya Darshni; Ivanov, Ivan G.; Lin, Pin-Cheng; Kaur, Gurpreet; Eriksson, Jens; Lakshmi, G.B.V.S.; Avasthi, D.K.; Gupta, Vinay; Aziz, Anver; Siddiqui, Azher M.; Syväjärvi, Mikael; Yazdi, G. Reza

2017-01-01

Highlights: • For the first time the gas sensing application of SHI irradiated epitaxial graphene on SiC is explored. • Surface morphology of irradiated graphene layers showed graphene folding, hillocks, and formation of wrinkles. • Existence of an optimal fluence which maximize the gas sensing response towards NO_2 and NH_3 gases. - Abstract: In this work, surface functionalization of epitaxial graphene grown on silicon carbide was performed by ion irradiation to investigate their gas sensing capabilities. Swift heavy ion irradiation using 100 MeV silver ions at four varying fluences was implemented on epitaxial graphene to investigate morphological and structural changes and their effects on the gas sensing capabilities of graphene. Sensing devices are expected as one of the first electronic applications using graphene and most of them use functionalized surfaces to tailor a certain function. In our case, we have studied irradiation as a tool to achieve functionalization. Morphological and structural changes on epitaxial graphene layers were investigated by atomic force microscopy, Raman spectroscopy, Raman mapping and reflectance mapping. The surface morphology of irradiated graphene layers showed graphene folding, hillocks, and formation of wrinkles at highest fluence (2 × 10"1"3 ions/cm"2). Raman spectra analysis shows that the graphene defect density is increased with increasing fluence, while Raman mapping and reflectance mapping show that there is also a reduction of monolayer graphene coverage. The samples were investigated for ammonia and nitrogen dioxide gas sensing applications. Sensors fabricated on pristine and irradiated samples showed highest gas sensing response at an optimal fluence. Our work provides new pathways for introducing defects in controlled manner in epitaxial graphene, which can be used not only for gas sensing application but also for other applications, such as electrochemical, biosensing, magnetosensing and spintronic

Objective and Subjective Evaluation of Reflecting and Diffusing Surfaces in Auditoria

Science.gov (United States)

Cox, Trevor John

Available from UMI in association with The British Library. Requires signed TDF. The performance of reflectors and diffusers used in auditoria have been evaluated both objectively and subjectively. Two accurate systems have been developed to measure the scattering from surfaces via the cross correlation function. These have been used to measure the scattering from plane panels, curved panels and quadratic residue diffusers (QRDs). The scattering measurements have been used to test theoretical prediction methods based on the Helmholtz-Kirchhoff integral equation. Accurate prediction methods were found for all surfaces tested. The limitations of the more approximate methods have been defined. The assumptions behind Schroeder's design of the QRD have been tested and the local reacting admittance assumption found to be valid over a wide frequency range. It was found that the QRD only produces uniform scattering at low frequencies. For an on-axis source the scattering from a curved panel was as good as from a QRD. For an oblique source the QRD produced much more uniform scattering than the curved panel. The subjective measurements evaluated the smallest perceivable change in the early sound field, the part most influenced by reflectors and diffusers. A natural sounding simulation of a concert hall field within an anechoic chamber was used. Standard objective parameters were reasonable values when compared to values found in real halls and subjective preference measurements. A difference limen was measured for early lateral energy fraction (.048 +/-.005); inter aural cross correlation (.075 +/-.008); clarity index (.67 +/-.13 dB); and centre time (8.6 +/- 1.6 ms). It was found that: (i) when changes are made to diffusers and reflectors, changes in spatial impression will usually be larger than those in clarity; and (ii) acousticians can gain most by paying attention to lateral sound in auditoria. It was also found that: (i) diffuse reflections in the early sound field

Maternal reflective functioning among mothers with childhood maltreatment histories: links to sensitive parenting and infant attachment security.

Science.gov (United States)

Stacks, Ann M; Muzik, Maria; Wong, Kristyn; Beeghly, Marjorie; Huth-Bocks, Alissa; Irwin, Jessica L; Rosenblum, Katherine L

2014-01-01

This study examined relationships among maternal reflective functioning, parenting, infant attachment, and demographic risk in a relatively large (N = 83) socioeconomically diverse sample of women with and without a history of childhood maltreatment and their infants. Most prior research on parental reflective functioning has utilized small homogenous samples. Reflective functioning was assessed with the Parent Development Interview, parenting was coded from videotaped mother-child interactions, and infant attachment was evaluated in Ainsworth's Strange Situation by independent teams of reliable coders masked to maternal history. Reflective functioning was associated with parenting sensitivity and secure attachment, and inversely associated with demographic risk and parenting negativity; however, it was not associated with maternal maltreatment history or PTSD. Parenting sensitivity mediated the relationship between reflective functioning and infant attachment, controlling for demographic risk. Findings are discussed in the context of prior research on reflective functioning and the importance of targeting reflective functioning in interventions.

A new theory and its application to remove the effect of surface-reflected light in above-surface radiance data from clear and turbid waters

International Nuclear Information System (INIS)

Dev, Pravin Jeba; Shanmugam, Palanisamy

2014-01-01

Water-leaving radiances (L w ) measured from the deck of a ship or boat in oceanic and lake waters are widely and operationally used for satellite sensor vicarious calibration and validation and development of remote-sensing algorithms to understand interdisciplinary coastal ocean properties and processes. However, accurate determination of L w remains to be a challenging issue because of the limitations of the existing methods to accurately remove the undesired signal (surface-reflected light of the sky and sun) from above-surface measurements of the total upwelling radiance leaving the water surface. In this study, a new theory is developed and applied to the above-surface radiometric data measured from clear, turbid and eutrophic waters. The new method effectively removes surface-reflected contributions from the total upwelling radiance signal under different sky (clear sky to overcast sky) and sun glint conditions. The L w spectra obtained from the above-surface radiance data using the new method are found to match well with those extrapolated from the upwelling radiances (L u ) measured with another set of underwater radiometers (used just below the sea surface). The new method proves to be a viable alternative, especially in circumstances when the above-surface measurements of radiances are severally contaminated by the surface-reflected light fields. Since spectral radiance measurements are also sensitive to the observation angles, and to the magnitude of the radiometer's solid angle field of view, above-surface radiances are also measured for different viewing angles in highly eutrophic waters. Such measurements show large deviations in L w spectra except at lower viewing angles (30°). When applied to these data, the new method eliminates the undesired signal encountered at higher viewing angles and delivers accurate water-leaving radiance data. These results suggest that the new method is capable of removing the surface-reflected light fields from both

Effect of surface characteristics on diffuse reflection radiation at lambda=0. 40. mu. m

Energy Technology Data Exchange (ETDEWEB)

Takashima, T [Atmospheric Environment Service, Downsview, Ontario (Canada)

1976-08-01

The diffuse radiation in the upward direction at the top and at an internal level of an inhomogeneous atmosphere is computed at lambda=0.40 ..mu..m. The surface is assumed to reflect light in accordance with a hybrid mode of a diffuse and specular reflector. The objective is to estimate the effect of underlying surface characteristics in terms of the diffuse radiation field. By making use of these results, accuracy in monitoring the atmospheric aerosols would be increased for the use of remote sensing satellite techniques. Junge power law (..gamma..*=3) is adopted for the size distribution of aerosols (1963), while the data given by McClatchy et al. (1971) is used for the number density of aerosols with height distribution. It is noted from the computations that the diffuse reflection radiation is affected by the surface characteristics, even if the albedo of the surface is a fixed constant and very small.

Development and applications of retro-reflective surfaces for ultrasound in LBE

Energy Technology Data Exchange (ETDEWEB)

NONE

2015-07-01

pulse or a complete absence of a reflection like a shadow. In that way, it suffices to align the sensor with the diaphragm instead of the fuel assembly which is much easier to achieve as the robotics on which the sensor is mounted move parallel with the diaphragm. The alignment requirement in the latter approach can be further relaxed by using a tiling of retro-reflectors on the lower surface of the diaphragm. In that way, alignment becomes less vital and the main source of acoustic energy loss - geometric spread of the beam - is almost completely removed, leaving only absorption losses. In this paper, we present the first results in developing a retro reflectance surface for ultrasound in LBE. We present experimental results for different designs of retro-reflectors in both water and LBE. We discuss both linear and array retro-reflectors of different sizes and investigate the influence of the main relevant ultrasonic parameters such as wavelength and spot size on the strength of the received reflection under different alignment angles. We also demonstrate how retro-reflective surfaces can be exploited when localizing objects using linear and rotating scanning methods. (authors)

Combined analysis of surface reflection imaging and vertical seismic profiling at Yucca Mountain, Nevada

International Nuclear Information System (INIS)

Daley, T.M.; Majer, E.L.; Karageorgi, E.

1994-08-01

This report presents results from surface and borehole seismic profiling performed by the Lawrence Berkeley Laboratory (LBL) on Yucca Mountain. This work was performed as part of the site characterization effort for the potential high-level nuclear waste repository. Their objective was to provide seismic imaging from the near surface (200 to 300 ft. depth) to the repository horizon and below, if possible. Among the issues addressed by this seismic imaging work are location and depth of fracturing and faulting, geologic identification of reflecting horizons, and spatial continuity of reflecting horizons. The authors believe their results are generally positive, with tome specific successes. This was the first attempt at this scale using modem seismic imaging techniques to determine geologic features on Yucca Mountain. The principle purpose of this report is to present the interpretation of the seismic reflection section in a geologic context. Three surface reflection profiles were acquired and processed as part of this study. Because of environmental concerns, all three lines were on preexisting roads. Line 1 crossed the mapped surface trace of the Ghost Dance fault and it was intended to study the dip and depth extent of the fault system. Line 2 was acquired along Drill Hole wash and was intended to help the ESF north ramp design activities. Line 3 was acquired along Yucca Crest and was designed to image geologic horizons which were thought to be less faulted along the ridge. Unfortunately, line 3 proved to have poor data quality, in part because of winds, poor field conditions and limited time. Their processing and interpretation efforts were focused on lines 1 and 2 and their associated VSP studies

Degradation of Silicon Carbide Reflective Surfaces in the LEO Environment

Science.gov (United States)

Mileti, Sandro; Coluzzi, Plinio; Marchetti, Mario

2009-01-01

Space mirrors in Low Earth Orbit (LEO) encounter a degradation problem caused by the impact of atomic oxygen (ATOX) in the space environment. This paper presents an experiment of the atomic oxygen impact degradation and UV synergic effects on ground simulation. The experiment was carried out in a dedicated ATOX simulation vacuum chamber. As target materials, a polished CVD Beta-silicon carbide (SiC) coating was investigated. The selection of silicon carbide is due to its high potential candidate as a mirror layer substrate material for its good reflectance at UV wavelengths and excellent thermal diffusivity. It has highly desirable mechanical and thermal properties and can achieve an excellent surface finish. The deposition of the coatings were on carbon-based material substrate; i.e., silicon impregnated carbon fiber composite (C/SiC). Mechanical and thermal properties of the coatings such as hardness and Coefficient of Thermal Expansion (CTE) were achieved. Several atomic oxygen impact angles were studied tilting the target samples respect to the flux direction. The various impact angles permitted to analyze the different erosion rates and typologies which the mirrors would encounter in LEO environment. The degradation was analyzed in various aspects. Macroscopic mass loss per unit area, surface roughness and morphology change were basically analyzed. The exposed surfaces of the materials were observed through a Scanning Electron Microscope (SEM). Secondly, optical diagnostic of the surfaces were performed in order to investigate their variation in optical properties as the evaluation of reflectance degradation. The presence of micro-cracks caused by shrinkage, grinding, polishing or thermal cycling and the porosity in the coatings, could have led to the undercutting phenomenon. Observation of uprising of undercutting was also conducted. Remarks are given regarding capabilities in short-term mission exposures to the LEO environment of this coating.

Functionalized polymer film surfaces via surface-initiated atom transfer radical polymerization

International Nuclear Information System (INIS)

Hu, Y.; Li, J.S.; Yang, W.T.; Xu, F.J.

2013-01-01

The ability to manipulate and control the surface properties of polymer films, without altering the substrate properties, is crucial to their wide-spread applications. In this work, a simple one-step method for the direct immobilization of benzyl chloride groups (as the effective atom transfer radical polymerization (ATRP) initiators) on the polymer films was developed via benzophenone-induced coupling of 4-vinylbenzyl chloride (VBC). Polyethylene (PE) and nylon films were selected as examples of polymer films to illustrate the functionalization of film surfaces via surface-initiated ATRP. Functional polymer brushes of (2-dimethylamino)ethyl methacrylate, sodium 4-styrenesulfonate, 2-hydroxyethyl methacrylate and glycidyl methacrylate, as well as their block copolymer brushes, have been prepared via surface-initiated ATRP from the VBC-coupled PE or nylon film surfaces. With the development of a simple approach to the covalent immobilization of ATRP initiators on polymer film surfaces and the inherent versatility of surface-initiated ATRP, the surface functionality of polymer films can be precisely tailored. - Highlights: ► Atom transfer radical polymerization initiators were simply immobilized. ► Different functional polymer brushes were readily prepared. ► Their block copolymer brushes were also readily prepared

Dynamic Bidirectional Reflectance Distribution Functions: Measurement and Representation

Science.gov (United States)

2008-02-01

be included in the harmonic fits. Other sets of orthogonal functions such as Zernike polynomials have also been used to characterize BRDF and could...reflectance spectra of 3D objects,” Proc. SPIE 4663, 370–378 2001. 13J. R. Shell II, C. Salvagio, and J. R. Schott, “A novel BRDF measurement technique

Determining surface coverage of ultra-thin gold films from X-ray reflectivity measurements

International Nuclear Information System (INIS)

Kossoy, A.; Simakov, D.; Olafsson, S.; Leosson, K.

2013-01-01

The paper describes usage of X-ray reflectivity for characterization of surface coverage (i.e. film continuity) of ultra-thin gold films which are widely studied for optical, plasmonic and electronic applications. The demonstrated method is very sensitive and can be applied for layers below 1 nm. It has several advantages over other techniques which are often employed in characterization of ultra-thin metal films, such as optical absorption, Atomic Force Microscopy, Transmission Electron Microscopy or Scanning Electron Microscopy. In contrast to those techniques our method does not require specialized sample preparation and measurement process is insensitive to electrostatic charge and/or presence of surface absorbed water. We validate our results with image processing of Scanning Electron Microscopy images. To ensure precise quantitative analysis of the images we developed a generic local thresholding algorithm which allowed us to treat series of images with various values of surface coverage with similar image processing parameters. - Highlights: • Surface coverage/continuity of ultra-thin Au films (up to 7 nm) was determined. • Results from X-ray reflectivity were verified by scanning electron microscopy. • We developed local thresholding algorithm to treat non-homogeneous image contrast

Variability of the reflectance coefficient of skylight from the ocean surface and its implications to ocean color.

Science.gov (United States)

Gilerson, Alexander; Carrizo, Carlos; Foster, Robert; Harmel, Tristan

2018-04-16

The value and spectral dependence of the reflectance coefficient (ρ) of skylight from wind-roughened ocean surfaces is critical for determining accurate water leaving radiance and remote sensing reflectances from shipborne, AERONET-Ocean Color and satellite observations. Using a vector radiative transfer code, spectra of the reflectance coefficient and corresponding radiances near the ocean surface and at the top of the atmosphere (TOA) are simulated for a broad range of parameters including flat and windy ocean surfaces with wind speeds up to 15 m/s, aerosol optical thicknesses of 0-1 at 440nm, wavelengths of 400-900 nm, and variable Sun and viewing zenith angles. Results revealed a profound impact of the aerosol load and type on the spectral values of ρ. Such impacts, not included yet in standard processing, may produce significant inaccuracies in the reflectance spectra retrieved from above-water radiometry and satellite observations. Implications for satellite cal/val activities as well as potential changes in measurement and data processing schemes are discussed.

Effects of Surface BRDF on the OMI Cloud and NO2 Retrievals: A New Approach Based on Geometry-Dependent Lambertian Equivalent Reflectivity (GLER) Derived from MODIS

Science.gov (United States)

Vasilkov, Alexander; Qin, Wenhan; Krotkov, Nickolay; Lamsal, Lok; Spurr, Robert; Haffner, David; Joiner, Joanna; Yang, Eun-Su; Marchenko, Sergey

2017-01-01

The Ozone Monitoring Instrument (OMI) cloud and NO2 algorithms use a monthly gridded surface reflectivity climatology that does not depend upon the observation geometry. In reality, reflection of incoming direct and diffuse solar light from land or ocean surfaces is sensitive to the sun sensor geometry. This dependence is described by the bidirectional reflectance distribution function (BRDF). To account for the BRDF, we propose to use a new concept of geometry-dependent Lambertian equivalent reflectivity (GLER). Implementation within the existing OMI cloud and NO2 retrieval infrastructure requires changes only to the input surface reflectivity database. GLER is calculated using a vector radiative transfer model with high spatial resolution BRDF information from MODIS over land and the Cox Munk slope distribution over ocean with a contribution from water-leaving radiance. We compare GLER and climatological LER at 466 nm, which is used in the OMI O2-O2cloud algorithm to derive effective cloud fractions. A detailed comparison of the cloud fractions and pressures derived with climatological and GLERs is carried out. GLER and corresponding retrieved cloud products are then used as input to the OMI NO2 algorithm. We find that replacing the climatological OMI-based LERs with GLERs can increase NO2 vertical columns by up to 50 % in highly polluted areas; the differences include both BRDF effects and biases between the MODIS and OMI-based surface reflectance data sets. Only minor changes to NO2 columns (within 5 %) are found over unpolluted and overcast areas.

Analysing the impact of reflectance distributions and well geometries on vertical surface daylight levels in atria for overcast skies

Energy Technology Data Exchange (ETDEWEB)

Du, Jiangtao; Sharples, Steve [School of Architecture, University of Sheffield, Crookesmoor Building, Conduit Road, Sheffield S10 1FL (United Kingdom)

2010-07-15

This study investigated the impacts of different diffuse reflectance distributions and well geometries on vertical daylight factors and vertical internally reflected components in atria. Two forms of reflectance distribution patterns of wall surface were examined: horizontal and vertical reflectance band variation. The square atrium models studied have a broader WI range of 0.25-2.0, which represent shallow, medium and high atria. Radiance, a powerful package based on backward ray tracing technique, was used for the simulations of vertical daylight levels. The results show that different reflectance distributions of square atrium walls do have an impact on the vertical daylight factors and vertical internally reflected components under overcast sky condition. The impact relates to the orientation of the band with different reflectance distributions on the wall. Compared with the vertical band surface, the horizontal band surface has a much more complicated effect. The horizontal distributions of the reflectances significantly affects the vertical daylight levels at the locations more than 30% atrium height on the wall. For an atrium with a height more than 1/2 the width, the effect tends to increase with the increasing well index. The vertical distributions of the reflectance, nevertheless, do not substantially take effect on the vertical daylight levels in atria except for some special reflectance distribution patterns. (author)

Surface properties of functional polymer systems

Science.gov (United States)

Wong, Derek

Polymer surface modification typically involves blending with other polymers or chemical modification of the parent polymer. Such strategies inevitably result in polymer systems that are spatially and chemically heterogeneous, and which exhibit the phenomenon of surface segregation. This work investigates the effects of chain architecture on the surface segregation behavior of such functionally modified polymers using a series of end- and center-fluorinated poly(D,L-lactide). Surface segregation of the fluorinated functional groups was observed in both chain architectures via AMPS and water contact angle. Higher surface segregation was noted for functional groups located at the chain end as opposed to those in the middle of the chain. A self-consistent mean-field lattice theory was used to model the composition depth profiles of functional groups and excellent agreement was found between the model predictions and the experimental AMPS data in both chain architectures. Polymer properties are also in general dependent on both time and temperature, and exhibit a range of relaxation times in response to environmental stimuli. This behavior arises from the characteristic frequencies of molecular motions of the polymer chain and the interrelationship between time and temperature has been widely established for polymer bulk properties. There is evidence that surface properties also respond in a manner that is time and temperature dependent and that this dependence may not be the same as that observed for bulk properties. AMPS and water contact angle experiments were used to investigate the surface reorganization behavior of functional groups using a series of anionically synthesized end-fluorinated and end-carboxylated poly(styrene). It was found that both types of functional end-groups reorganized upon a change in the polarity of the surface environment in order to minimize the surface free energy. ADXPS and contact angle results suggest that the reorganization depth was

Impacts of dust aerosol and adjacency effects on the accuracy of Landsat 8 and RapidEye surface reflectances

KAUST Repository

Houborg, Rasmus; McCabe, Matthew

2017-01-01

The atmospheric correction of satellite data is challenging over desert agricultural systems, due to the relatively high aerosol optical thicknesses (τ550), bright soils, and a heterogeneous surface reflectance field. Indeed, the contribution of reflected radiation from adjacent pixels scattered into the field of view of a target pixel is considerable and can significantly affect the fidelity of retrieved reflectances. In this study, uncertainties and quantitative errors associated with the atmospheric correction of multi-spectral Landsat 8 and RapidEye data were characterized over a desert agricultural landscape in Saudi Arabia. Surface reflectances were retrieved using an implementation of the 6SV atmospheric correction code, and validated against field collected spectroradiometer measurements over desert, cultivated soil, and vegetated surface targets. A combination of satellite and Aerosol Robotic Network (AERONET) data were used to parameterize aerosol properties and atmospheric state parameters. With optimal specification of τ550 and aerosol optical properties and correction for adjacency effects, the relative Mean Absolute Deviation (MAD) for all bands combined was 5.4% for RapidEye and 6.8% for Landsat 8. However uncertainties associated with satellite-based τ550 retrievals were shown to introduce significant error into the reflectance estimates. With respect to deriving common vegetation indices from corrected reflectance data, the Normalized Difference Vegetation Index (NDVI) was associated with the smallest errors (3–8% MAD). Surface reflectance errors were highest for bands in the visible part of the spectrum, particularly the blue band (5–16%), while there was more consistency within the red-edge (~ 5%) and near-infrared (5–7%). Results were generally better constrained when a τ550-dependent aerosol model for desert dust particles, parameterized on the basis of nearby AERONET site data, was used in place of a generic rural or background

Impacts of dust aerosol and adjacency effects on the accuracy of Landsat 8 and RapidEye surface reflectances

KAUST Repository

Houborg, Rasmus

2017-03-29

The atmospheric correction of satellite data is challenging over desert agricultural systems, due to the relatively high aerosol optical thicknesses (τ550), bright soils, and a heterogeneous surface reflectance field. Indeed, the contribution of reflected radiation from adjacent pixels scattered into the field of view of a target pixel is considerable and can significantly affect the fidelity of retrieved reflectances. In this study, uncertainties and quantitative errors associated with the atmospheric correction of multi-spectral Landsat 8 and RapidEye data were characterized over a desert agricultural landscape in Saudi Arabia. Surface reflectances were retrieved using an implementation of the 6SV atmospheric correction code, and validated against field collected spectroradiometer measurements over desert, cultivated soil, and vegetated surface targets. A combination of satellite and Aerosol Robotic Network (AERONET) data were used to parameterize aerosol properties and atmospheric state parameters. With optimal specification of τ550 and aerosol optical properties and correction for adjacency effects, the relative Mean Absolute Deviation (MAD) for all bands combined was 5.4% for RapidEye and 6.8% for Landsat 8. However uncertainties associated with satellite-based τ550 retrievals were shown to introduce significant error into the reflectance estimates. With respect to deriving common vegetation indices from corrected reflectance data, the Normalized Difference Vegetation Index (NDVI) was associated with the smallest errors (3–8% MAD). Surface reflectance errors were highest for bands in the visible part of the spectrum, particularly the blue band (5–16%), while there was more consistency within the red-edge (~ 5%) and near-infrared (5–7%). Results were generally better constrained when a τ550-dependent aerosol model for desert dust particles, parameterized on the basis of nearby AERONET site data, was used in place of a generic rural or background

[A Method to Reconstruct Surface Reflectance Spectrum from Multispectral Image Based on Canopy Radiation Transfer Model].

Science.gov (United States)

Zhao, Yong-guang; Ma, Ling-ling; Li, Chuan-rong; Zhu, Xiao-hua; Tang, Ling-li

2015-07-01

Due to the lack of enough spectral bands for multi-spectral sensor, it is difficult to reconstruct surface retlectance spectrum from finite spectral information acquired by multi-spectral instrument. Here, taking into full account of the heterogeneity of pixel from remote sensing image, a method is proposed to simulate hyperspectral data from multispectral data based on canopy radiation transfer model. This method first assumes the mixed pixels contain two types of land cover, i.e., vegetation and soil. The sensitive parameters of Soil-Leaf-Canopy (SLC) model and a soil ratio factor were retrieved from multi-spectral data based on Look-Up Table (LUT) technology. Then, by combined with a soil ratio factor, all the parameters were input into the SLC model to simulate the surface reflectance spectrum from 400 to 2 400 nm. Taking Landsat Enhanced Thematic Mapper Plus (ETM+) image as reference image, the surface reflectance spectrum was simulated. The simulated reflectance spectrum revealed different feature information of different surface types. To test the performance of this method, the simulated reflectance spectrum was convolved with the Landsat ETM + spectral response curves and Moderate Resolution Imaging Spectrometer (MODIS) spectral response curves to obtain the simulated Landsat ETM+ and MODIS image. Finally, the simulated Landsat ETM+ and MODIS images were compared with the observed Landsat ETM+ and MODIS images. The results generally showed high correction coefficients (Landsat: 0.90-0.99, MODIS: 0.74-0.85) between most simulated bands and observed bands and indicated that the simulated reflectance spectrum was well simulated and reliable.

Functionalization of Block Copolymer Vesicle Surfaces

Directory of Open Access Journals (Sweden)

Wolfgang Meier

2011-01-01

Full Text Available In dilute aqueous solutions certain amphiphilic block copolymers self-assemble into vesicles that enclose a small pool of water with a membrane. Such polymersomes have promising applications ranging from targeted drug-delivery devices, to biosensors, and nanoreactors. Interactions between block copolymer membranes and their surroundings are important factors that determine their potential biomedical applications. Such interactions are influenced predominantly by the membrane surface. We review methods to functionalize block copolymer vesicle surfaces by chemical means with ligands such as antibodies, adhesion moieties, enzymes, carbohydrates and fluorophores. Furthermore, surface-functionalization can be achieved by self-assembly of polymers that carry ligands at their chain ends or in their hydrophilic blocks. While this review focuses on the strategies to functionalize vesicle surfaces, the applications realized by, and envisioned for, such functional polymersomes are also highlighted.

Bio-inspired functional surfaces for advanced applications

DEFF Research Database (Denmark)

Malshe, Ajay; Rajurkar, Kamlakar; Samant, Anoop

2013-01-01

, are being evolved to a higher state of intelligent functionality. These surfaces became more efficient by using combinations of available materials, along with unique physical and chemical strategies. Noteworthy physical strategies include features such as texturing and structure, and chemical strategies...... such as sensing and actuation. These strategies collectively enable functional surfaces to deliver extraordinary adhesion, hydrophobicity, multispectral response, energy scavenging, thermal regulation, antibiofouling, and other advanced functions. Production industries have been intrigued with such biological...... surface strategies in order to learn clever surface architectures and implement those architectures to impart advanced functionalities into manufactured consumer products. This keynote paper delivers a critical review of such inspiring biological surfaces and their nonbiological product analogs, where...

Diffuse Reflectance Spectroscopy for Surface Measurement of Liver Pathology.

Science.gov (United States)

Nilsson, Jan H; Reistad, Nina; Brange, Hannes; Öberg, Carl-Fredrik; Sturesson, Christian

2017-01-01

Liver parenchymal injuries such as steatosis, steatohepatitis, fibrosis, and sinusoidal obstruction syndrome can lead to increased morbidity and liver failure after liver resection. Diffuse reflectance spectroscopy (DRS) is an optical measuring method that is fast, convenient, and established. DRS has previously been used on the liver with an invasive technique consisting of a needle that is inserted into the parenchyma. We developed a DRS system with a hand-held probe that is applied to the liver surface. In this study, we investigated the impact of the liver capsule on DRS measurements and whether liver surface measurements are representative of the whole liver. We also wanted to confirm that we could discriminate between tumor and liver parenchyma by DRS. The instrumentation setup consisted of a light source, a fiber-optic contact probe, and two spectrometers connected to a computer. Patients scheduled for liver resection due to hepatic malignancy were included, and DRS measurements were performed on the excised liver part with and without the liver capsule and alongside a newly cut surface. To estimate the scattering parameters and tissue chromophore volume fractions, including blood, bile, and fat, the measured diffuse reflectance spectra were applied to an analytical model. In total, 960 DRS spectra from the excised liver tissue of 18 patients were analyzed. All factors analyzed regarding tumor versus liver tissue were significantly different. When measuring through the capsule, the blood volume fraction was found to be 8.4 ± 3.5%, the lipid volume fraction was 9.9 ± 4.7%, and the bile volume fraction was 8.2 ± 4.6%. No differences could be found between surface measurements and cross-sectional measurements. In measurements with/without the liver capsule, the differences in volume fraction were 1.63% (0.75-2.77), -0.54% (-2.97 to 0.32), and -0.15% (-1.06 to 1.24) for blood, lipid, and bile, respectively. This study shows that it is possible to manage DRS

Vertical-cavity surface-emitting laser vapor sensor using swelling polymer reflection modulation

DEFF Research Database (Denmark)

Ansbæk, Thor; Nielsen, Claus Højgård; Dohn, Søren

2012-01-01

Vapor detection using a low-refractive index polymer for reflection modulation of the top mirror in a vertical-cavity surface-emitting laser (VCSEL) is demonstrated. The VCSEL sensor concept presents a simple method to detect the response of a sensor polymer in the presence of volatile organic...

A new setup to measure bidirectional reflectance distribution functions

NARCIS (Netherlands)

Roosjen, P.P.J.; Clevers, J.G.P.W.; Bartholomeus, H.

2012-01-01

The Plant Facility, a new laboratory goniometer system, built by the Wageningen University has been tested in order to take bidirectional reflectance distribution function (BRDF) measurements. An ASD FieldSpec 3 spectroradiometer mounted on an industrial robot arm is able to measure small targets

Surface Compositional Units on Mercury from Spectral Reflectance at Ultraviolet to Near-infrared Wavelengths

Science.gov (United States)

Izenberg, N. R.; Holsclaw, G. M.; Domingue, D. L.; McClintock, W. E.; Klima, R. L.; Blewett, D. T.; Helbert, J.; Head, J. W.; Sprague, A. L.; Vilas, F.; Solomon, S. C.

2012-12-01

The Mercury Atmospheric and Surface Composition Spectrometer (MASCS) on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft has been acquiring reflectance spectra of Mercury's surface for over 16 months. The Visible and Infrared Spectrograph (VIRS) component of MASCS has accumulated a global data set of more than 2 million spectra over the wavelength range 300-1450 nm. We have derived a set of VIRS spectral units (VSUs) from the following spectral parameters: visible brightness (R575: reflectance at 575 nm); visible/near-infrared reflectance ratio (VISr: reflectance at 415 nm to that at 750 nm); and ultraviolet reflectance ratio (UVr: reflectance at 310 nm to that at 390 nm). Five broad, slightly overlapping VSUs may be distinguished from these parameters. "Average VSU" areas have spectral parameters close to mean global values. "Dark blue VSU" areas have spectra with low R575 and high UVr. "Red VSU" areas have spectra with low UVr and higher VISr and R575 than average. "Intermediate VSU" areas have spectra with higher VISr than VSU red, generally higher R575, and a wide range of UVr. "Bright VSU" areas have high R575 and VISr and intermediate UVr. Several units defined by morphological or multispectral criteria correspond to specific VSUs, including low-reflectance material (dark blue VSU), pyroclastic deposits (red VSU), and hollows (intermediate VSU), but these VSUs generally include other types of areas as well. VSU definitions are complementary to those obtained by unsupervised clustering analysis. The global distribution of VIRS spectral units provides new information on Mercury's geological evolution. Much of Mercury's northern volcanic plains show spectral properties ranging from those of average VSU to those of red VSU, as does a large region in the southern hemisphere centered near 50°S, 245°E. Dark blue VSU material is widely distributed, with concentrations south of the northern plains, around the Rembrandt and

Reflective functioning and attachment in adolescent eating disorders

OpenAIRE

Siddell, Laurette

2017-01-01

Introduction: A systematic review was undertaken to identify any psychological predictors of treatment dropout for individuals diagnosed with an eating disorder, to help inform psychological therapy and reduce attrition. An empirical study was conducted to understand developmental psychological mechanisms at play in the aetiology and maintenance of eating disordered symptomology by assessing reflective functioning and attachment from a trans-diagnostic perspective. Method...

Tunable band gap and optical properties of surface functionalized Sc2C monolayer

International Nuclear Information System (INIS)

Wang Shun; Du Yu-Lei; Liao Wen-He

2017-01-01

Using the density functional theory, we have investigated the electronic and optical properties of two-dimensional Sc 2 C monolayer with OH, F, or O chemical groups. The electronic structures reveal that the functionalized Sc 2 C monolayers are semiconductors with a band gap of 0.44–1.55 eV. The band gap dependent optical parameters, like dielectric function, absorption coefficients, reflectivity, loss function, and refraction index were also calculated for photon energy up to 20 eV. At the low-energy region, each optical parameter shifts to red, and the peak increases obviously with the increase of the energy gap. Consequently, Sc 2 C monolayer with a tunable band gap by changing the type of surface chemical groups is a promising 2D material for optoelectronic devices. (paper)

A sea surface reflectance model for (AATSR, and application to aerosol retrievals

Directory of Open Access Journals (Sweden)

A. M. Sayer

2010-07-01

Full Text Available A model of the sea surface bidirectional reflectance distribution function (BRDF is presented for the visible and near-IR channels (over the spectral range 550 nm to 1.6 μm of the dual-viewing Along-Track Scanning Radiometers (ATSRs. The intended application is as part of the Oxford-RAL Aerosols and Clouds (ORAC retrieval scheme. The model accounts for contributions to the observed reflectance from whitecaps, sun-glint and underlight. Uncertainties in the parametrisations used in the BRDF model are propagated through into the forward model and retrieved state. The new BRDF model offers improved coverage over previous methods, as retrievals are possible into the sun-glint region, through the ATSR dual-viewing system. The new model has been applied in the ORAC aerosol retrieval algorithm to process Advanced ATSR (AATSR data from September 2004 over the south-eastern Pacific. The assumed error budget is shown to be generally appropriate, meaning the retrieved states are consistent with the measurements and a priori assumptions. The resulting field of aerosol optical depth (AOD is compared with colocated MODIS-Terra observations, AERONET observations at Tahiti, and cruises over the oceanic region. MODIS and AATSR show similar spatial distributions of AOD, although MODIS reports values which are larger and more variable. It is suggested that assumptions in the MODIS aerosol retrieval algorithm may lead to a positive bias in MODIS AOD of order 0.01 at 550 nm over ocean regions where the wind speed is high.

An Operational Scheme for Deriving Standardised Surface Reflectance from Landsat TM/ETM+ and SPOT HRG Imagery for Eastern Australia

Directory of Open Access Journals (Sweden)

Neil Flood

2013-01-01

Full Text Available Operational monitoring of vegetation and land surface change over large areas can make good use of satellite sensors that measure radiance reflected from the Earth’s surface. Monitoring programs use multiple images for complete spatial coverage over time. Accurate retrievals of vegetation cover and vegetation change estimates can be hampered by variation, in both space and time, in the measured radiance, caused by atmospheric conditions, topography, sensor location, and sun elevation. In order to obtain estimates of cover that are comparable between images, and to retrieve accurate estimates of change, these sources of variation must be removed. In this paper we present a preprocessing scheme for minimising atmospheric, topographic and bi-directional reflectance effects on Landsat-5 TM, Landsat-7 ETM+ and SPOT-5 HRG imagery. The approach involves atmospheric correction to compute surface-leaving radiance, and bi-directional reflectance modelling to remove the effects of topography and angular variation in reflectance. The bi-directional reflectance model has been parameterised for eastern Australia, but the general approach is more widely applicable. The result is surface reflectance standardised to a fixed viewing and illumination geometry. The method can be applied to the entire record for these instruments, without intervention, which is of increasing importance with the increased availability of long term image archives. Validation shows that the corrections improve the estimation of reflectance at any given angular configuration, thus allowing the removal from the reflectance signal of much variation due to factors independent of the land surface. The method has been used to process over 45,000 Landsat-5 TM and Landsat-7 ETM+ scenes and 2,500 SPOT-5 scenes, over eastern Australia, and is now in use in operational monitoring programs.

Variability of Surface Reflection Amplitudes of GPR Horn Antenna Depending on Distance between Antenna and Surface

Directory of Open Access Journals (Sweden)

Komačka Jozef

2016-05-01

Full Text Available The study focused on variability of surface reflections amplitudes of GPR horn antenna in relation to distance between an antenna and a surface is presented in the paper. The air-coupled antenna with the central frequency of 1 GHz was used in the investigation. Four types of surfaces (dry pavement, wet pavement, metal plate and composite layer from gypsum and wood were tested. The distance of antenna above the surfaces was changed in the range from 37.5 cm to 53.5 cm. The amplitudes of negative and positive peaks and their variability were analysed in relation to the distance of antenna above the surfaces. Moreover, the influence of changes in the peaks of negative and positive amplitudes on the total amplitudes was assessed. It was found out the amplitudes of negative peaks for all investigated surfaces were relatively consistent in the range from 40.5 cm to 48.5 cm and the moderate decline was identified in the case of amplitudes of positive peaks in the range of distances from 37.5 cm to 51.5 cm. This decline influences the tendency of total amplitudes. Based on the results of analysis it can be stated the distance of air-coupled antenna above the surface can influence the value of total amplitude and the differences depend on the type of surface.

Analysis of Selected Photovoltaic Panels Operating Parameters as a Function of Partial Shading and Intensity of Reflected Radiation

Directory of Open Access Journals (Sweden)

Bilčík Matúš

2018-03-01

Full Text Available Due to expansion of utilisation of photovoltaics in ordinary households, the question arises how this phenomenon affects the electric power of photovoltaic modules. The article deals with the electric power analysis of photovoltaic modules as a function of two very important factors. The first examined factor was partial shading, and the second factor was the intensity of reflected radiation. In order to determine the dependence of module power on the aforementioned parameters, a measurement system under laboratory conditions has been prepared. For identification of the reflected radiation effect on the power of the photovoltaic module, a series of measurements was performed on 7 different surfaces with the same radiation source. It is evident from obtained experimental result that the ratio of reflected irradiation on the solar module power is 1.29%. By simulation of partial shading of photovoltaic module, the decrease of 86.15% in its output power was identified.

Bone-like apatite coating on functionalized poly(etheretherketone) surface via tailored silanization layers technique.

Science.gov (United States)

Zheng, Yanyan; Xiong, Chengdong; Zhang, Shenglan; Li, Xiaoyu; Zhang, Lifang

2015-10-01

Poly(etheretherketone) (PEEK) is a rigid semi-crystalline polymer with outstanding mechanical properties, bone-like stiffness and suitable biocompatibility that has attracted much interest as a biomaterial for orthopedic and dental implants. However, the bio-inert surface of PEEK limits its biomedical applications when direct osteointegration between the implants and the host tissue is desired. In this work, -PO4H2, -COOH and -OH groups were introduced on the PEEK surface by further chemical treatments of the vinyl-terminated silanization layers formed on the hydroxylation-pretreated PEEK surface. Both the surface-functionalized and pristine specimens were characterized by X-ray photoelectron spectroscopy (XPS), attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy and water contact angle measurements. When placed in 1.5 strength simulated body fluid (SBF) solution, apatite was observed to form uniformly on the functionalized PEEK surface and firmly attach to the substrate. The characterized results demonstrated that the coating was constituted by poorly crystallized bone-like apatite and the effect of surface functional groups on coating formation was also discussed in detail. In addition, in vitro biocompatibility of PEEK, in terms of pre-osteoblast cell (MC3T3-E1) attachment, spreading and proliferation, was remarkably enhanced by the bone-like apatite coating. Thus, this study provides a method to enhance the bioactivity of PEEK and expand its applications in orthopedic and dental implants. Copyright © 2015 Elsevier B.V. All rights reserved.

Overview on the Surface Functionalization Mechanism and Determination of Surface Functional Groups of Plasma Treated Carbon Nanotubes.

Science.gov (United States)

Saka, Cafer

2018-01-02

The use of carbon materials for many applications is due to the unique diversity of structures and properties ranging from chemical bonds between the carbon atoms of the materials to nanostructures, crystallite alignment, and microstructures. Carbon nanotubes and other nanoscale carbonaceous materials draw much attention due to their physical and chemical properties, such as high strength, high resistance to corrosion, electrical and thermal conductivity, stability and a qualified adsorbent. Carbon-based nanomaterials, which have a relatively large specific area and layered structure, can be used as an adsorbent for efficient removal of organic and inorganic contaminants. However, one of the biggest obstacles to the development of carbon-based nanomaterials adsorbents is insolubility and the lack of functional groups on the surface. There are several approaches to introduce functional groups on carbon nanotubes. One of these approaches, plasma applications, now has an important place in the creation of surface functional groups as a flexible, fast, and environmentally friendly method. This review focuses on recent information concerning the surface functionalization and modification of plasma treated carbon nanotube. This review considers the surface properties, advantages, and disadvantages of plasma-applied carbon nanotubes. It also examines the reaction mechanisms involved in the functional groups on the surface.

Bone-like apatite coating on functionalized poly(etheretherketone) surface via tailored silanization layers technique

International Nuclear Information System (INIS)

Zheng, Yanyan; Xiong, Chengdong; Zhang, Shenglan; Li, Xiaoyu; Zhang, Lifang

2015-01-01

Poly(etheretherketone) (PEEK) is a rigid semi-crystalline polymer with outstanding mechanical properties, bone-like stiffness and suitable biocompatibility that has attracted much interest as a biomaterial for orthopedic and dental implants. However, the bio-inert surface of PEEK limits its biomedical applications when direct osteointegration between the implants and the host tissue is desired. In this work, –PO 4 H 2 , –COOH and –OH groups were introduced on the PEEK surface by further chemical treatments of the vinyl-terminated silanization layers formed on the hydroxylation-pretreated PEEK surface. Both the surface-functionalized and pristine specimens were characterized by X-ray photoelectron spectroscopy (XPS), attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy and water contact angle measurements. When placed in 1.5 strength simulated body fluid (SBF) solution, apatite was observed to form uniformly on the functionalized PEEK surface and firmly attach to the substrate. The characterized results demonstrated that the coating was constituted by poorly crystallized bone-like apatite and the effect of surface functional groups on coating formation was also discussed in detail. In addition, in vitro biocompatibility of PEEK, in terms of pre-osteoblast cell (MC3T3-E1) attachment, spreading and proliferation, was remarkably enhanced by the bone-like apatite coating. Thus, this study provides a method to enhance the bioactivity of PEEK and expand its applications in orthopedic and dental implants. - Highlights: • –PO 4 H 2 , –COOH and –OH groups were successfully introduced onto PEEK surface via tailored silanization layer technique. • Bone-like apatite formed uniformly on surface-functionalized PEEK after immersion in SBF, and tightly adhered to the PEEK. • SEM, EDS, FTIR, XPS and XRD results showed that apatite layer is composed of low-crystalline bone-like apatite. • Bone-like apatite coating remarkably enhanced pre

Lactoperoxidase catalyzed radioiodination of cell surface immunoglobulin: incorporated radioactivity may not reflect relative cell surface Ig density

International Nuclear Information System (INIS)

Wilder, R.L.; Yuen, C.C.; Mage, R.G.

1979-01-01

Rabbit and mouse splenic lymphocytes were radioiodinated by the lactoperoxidase technique, extracted with non-ionic detergent, immunoprecipitated with high titered rabbit anti-kappa antisera, and compared by SDS-PAGE. Mouse sIg peaks were reproducibly larger in size than rabbit sIg peaks (often greater than 10 times). Neither differences in incorporation of label into the rabbit cell surface, nor differences in average sIg density explain this result. Total TCA-precipitable radioactivity was similar in each species. Estimation of the relative amounts of sIg in the mouse and rabbit showed similar average sIg densities. Differences in detergent solubility, proteolytic lability, or antisera used also do not adequately account for this difference. Thus, these data indicate that radioactivity incorporated after lactoperoxidase catalyzed cell surface radioiodination may not reflect cell surface Ig density. Conclusions about cell surface density based upon relative incorporation of radioactivity should be confirmed by other approaches

Accounting for the Effects of Surface BRDF on Satellite Cloud and Trace-Gas Retrievals: A New Approach Based on Geometry-Dependent Lambertian-Equivalent Reflectivity Applied to OMI Algorithms

Science.gov (United States)

Vasilkov, Alexander; Qin, Wenhan; Krotkov, Nickolay; Lamsal, Lok; Spurr, Robert; Haffner, David; Joiner, Joanna; Yang, Eun-Su; Marchenko, Sergey

2017-01-01

Most satellite nadir ultraviolet and visible cloud, aerosol, and trace-gas algorithms make use of climatological surface reflectivity databases. For example, cloud and NO2 retrievals for the Ozone Monitoring Instrument (OMI) use monthly gridded surface reflectivity climatologies that do not depend upon the observation geometry. In reality, reflection of incoming direct and diffuse solar light from land or ocean surfaces is sensitive to the sun-sensor geometry. This dependence is described by the bidirectional reflectance distribution function (BRDF). To account for the BRDF, we propose to use a new concept of geometry-dependent Lambertian equivalent reflectivity (LER). Implementation within the existing OMI cloud and NO2 retrieval infrastructure requires changes only to the input surface reflectivity database. The geometry-dependent LER is calculated using a vector radiative transfer model with high spatial resolution BRDF information from the Moderate Resolution Imaging Spectroradiometer (MODIS) over land and the Cox-Munk slope distribution over ocean with a contribution from water-leaving radiance. We compare the geometry-dependent and climatological LERs for two wavelengths, 354 and 466 nm, that are used in OMI cloud algorithms to derive cloud fractions. A detailed comparison of the cloud fractions and pressures derived with climatological and geometry-dependent LERs is carried out. Geometry-dependent LER and corresponding retrieved cloud products are then used as inputs to our OMI NO2 algorithm. We find that replacing the climatological OMI-based LERs with geometry-dependent LERs can increase NO2 vertical columns by up to 50% in highly polluted areas; the differences include both BRDF effects and biases between the MODIS and OMI-based surface reflectance data sets. Only minor changes to NO2 columns (within 5 %) are found over unpolluted and overcast areas.

Accounting for the effects of surface BRDF on satellite cloud and trace-gas retrievals: a new approach based on geometry-dependent Lambertian equivalent reflectivity applied to OMI algorithms

Science.gov (United States)

Vasilkov, Alexander; Qin, Wenhan; Krotkov, Nickolay; Lamsal, Lok; Spurr, Robert; Haffner, David; Joiner, Joanna; Yang, Eun-Su; Marchenko, Sergey

2017-01-01

Most satellite nadir ultraviolet and visible cloud, aerosol, and trace-gas algorithms make use of climatological surface reflectivity databases. For example, cloud and NO2 retrievals for the Ozone Monitoring Instrument (OMI) use monthly gridded surface reflectivity climatologies that do not depend upon the observation geometry. In reality, reflection of incoming direct and diffuse solar light from land or ocean surfaces is sensitive to the sun-sensor geometry. This dependence is described by the bidirectional reflectance distribution function (BRDF). To account for the BRDF, we propose to use a new concept of geometry-dependent Lambertian equivalent reflectivity (LER). Implementation within the existing OMI cloud and NO2 retrieval infrastructure requires changes only to the input surface reflectivity database. The geometry-dependent LER is calculated using a vector radiative transfer model with high spatial resolution BRDF information from the Moderate Resolution Imaging Spectroradiometer (MODIS) over land and the Cox-Munk slope distribution over ocean with a contribution from water-leaving radiance. We compare the geometry-dependent and climatological LERs for two wavelengths, 354 and 466 nm, that are used in OMI cloud algorithms to derive cloud fractions. A detailed comparison of the cloud fractions and pressures derived with climatological and geometry-dependent LERs is carried out. Geometry-dependent LER and corresponding retrieved cloud products are then used as inputs to our OMI NO2 algorithm. We find that replacing the climatological OMI-based LERs with geometry-dependent LERs can increase NO2 vertical columns by up to 50 % in highly polluted areas; the differences include both BRDF effects and biases between the MODIS and OMI-based surface reflectance data sets. Only minor changes to NO2 columns (within 5 %) are found over unpolluted and overcast areas.

Response functions for crystals and surfaces, with applications to surface scattering

International Nuclear Information System (INIS)

Barker, J.A.; Steele, W.A.

1978-01-01

A general solution of the equations of forced motion of a harmonic crystal or other vibrating system with arbitrary time-dependent forces acting on the atoms is given. The solution is given in terms of dynamical 'response functions', for which expressions in terms of the normal mode frequencies and eigenvectors (polarization vectors) are given. Numerical calculations of the response functions are described for (111) and (100) surfaces of face-centered cubic crystals interacting with Lennard-Jones 6-12 potentials, and the qualitative features of the surface and bulk response functions are discussed. The use of these functions in problems of atomic scattering from surface is outlined, and convenient parametrized forms for this application are given. (Auth.)

Influence of surface roughness on the reflective properties of snow

International Nuclear Information System (INIS)

Zhuravleva, Tatiana B.; Kokhanovsky, Alexander A.

2011-01-01

In this paper the influence of 3D effect on snow reflection function (SRF) and albedo is studied in the framework of the stochastic radiative transfer theory. In particular, the corresponding equations for the averaged intensity of reflected light are solved for the ensemble of realizations of the stochastic field κ(r), describing the distribution of 3D elements on the flat semi-infinite snow layer (SISL). The reflection from the underlying SISL is modeled using the solution of the 1D radiative transfer equation. The corresponding look-up tables were compiled beforehand and used in the simulation process. In accordance with the previous studies, it was found that the albedo of snow layer is reduced (in particular, in the infrared region), if 3D effects are taken into account. There is no such a reduction, if light absorption in snow is absent. The 3D effects may increase or decrease SRF depending on the sastrugi fraction and illumination/observation conditions.

PREFACE: Exploring surfaces and buried interfaces of functional materials by advanced x-ray and neutron techniques Exploring surfaces and buried interfaces of functional materials by advanced x-ray and neutron techniques

Science.gov (United States)

Sakurai, Kenji

2010-12-01

measurement. Advances in such technologies are bringing with them new opportunities in surface and buried interface science. In the not too distant future, we will publish a special issue or a book detailing such progress. Exploring surfaces and buried interfaces of functional materials by advanced x-ray and neutron techniques contents Lateral uniformity in chemical composition along a buried reaction front in polymers using off-specular reflectivity Kristopher A Lavery, Vivek M Prabhu, Sushil Satija and Wen-li Wu Orientation dependence of Pd growth on Au electrode surfaces M Takahasi, K Tamura, J Mizuki, T Kondo and K Uosaki A grazing incidence small-angle x-ray scattering analysis on capped Ge nanodots in layer structures Hiroshi Okuda, Masayuki Kato, Keiji Kuno, Shojiro Ochiai, Noritaka Usami, Kazuo Nakajima and Osami Sakata High resolution grazing-incidence in-plane x-ray diffraction for measuring the strain of a Si thin layer Kazuhiko Omote X-ray analysis of mesoporous silica thin films templated by Brij58 surfactant S Fall, M Kulij and A Gibaud Review of the applications of x-ray refraction and the x-ray waveguide phenomenon to estimation of film structures Kouichi Hayashi Epitaxial growth of largely mismatched crystals on H-terminated Si(111) surfaces Hidehito Asaoka Novel TiO2/ZnO multilayer mirrors at 'water-window' wavelengths fabricated by atomic layer epitaxy H Kumagai, Y Tanaka, M Murata, Y Masuda and T Shinagawa Depth-selective structural analysis of thin films using total-external-reflection x-ray diffraction Tomoaki Kawamura and Hiroo Omi Structures of Yb nanoparticle thin films grown by deposition in He and N2 gas atmospheres: AFM and x-ray reflectivity studies Martin Jerab and Kenji Sakurai Ga and As composition profiles in InP/GaInAs/InP heterostructures—x-ray CTR scattering and cross-sectional STM measurements Yoshikazu Takeda, Masao Tabuchi and Arao Nakamura Polarized neutron reflectivity study of a thermally treated MnIr/CoFe exchange bias system Naoki

A fiber-coupled displacement measuring interferometer for determination of the posture of a reflective surface

International Nuclear Information System (INIS)

Mao, Shuai; Hu, Peng-Cheng; Ding, Xue-Mei; Tan, Jiu-Bin

2016-01-01

A fiber-coupled displacement measuring interferometer capable of determining of the posture of a reflective surface of a measuring mirror is proposed. The newly constructed instrument combines fiber-coupled displacement and angular measurement technologies. The proposed interferometer has advantages of both the fiber-coupled and the spatially beam-separated interferometer. A portable dual-position sensitive detector (PSD)-based unit within this proposed interferometer measures the parallelism of the two source beams to guide the fiber-coupling adjustment. The portable dual PSD-based unit measures not only the pitch and yaw of the retro-reflector but also measures the posture of the reflective surface. The experimental results of displacement calibration show that the deviations between the proposed interferometer and a reference one, Agilent 5530, at two different common beam directions are both less than ±35 nm, thus verifying the effectiveness of the beam parallelism measurement. The experimental results of angular calibration show that deviations of pitch and yaw with the auto-collimator (as a reference) are less than ±2 arc sec, thus proving the proposed interferometer’s effectiveness for determination of the posture of a reflective surface.

Determining the influential depth for surface reflectance of sediment by BRDF measurements.

Science.gov (United States)

Zhang, H; Voss, K; Reid, R

2003-10-20

We measure the Bi-directional reflectance distribution function (BRDF) of ooid sand layers with three particle size distributions (0.5-1mm, 0.25-0.5mm and 0.125-0.25mm) and layer thicknesses on a reflecting mirror to determine the influential depth in the optical region at wavelengths of 658 nm (red), 570 nm (green) and 457 nm (blue). The hemispherical reflectance (albedo) was used as an indicator of BRDF changes between different layers. Measurements are carried out on both dry and water wetted grains. The results indicate that for both dry and wet and all size distributions, the influential depth is at most 2mm.

Quantum reflection of fast atoms from insulator surfaces: Eikonal description

Energy Technology Data Exchange (ETDEWEB)

Gravielle, M S; Miraglia, J E, E-mail: msilvia@iafe.uba.a, E-mail: miraglia@iafe.uba.a [Instituto de Astronomia y Fisica del Espacio, CONICET, Casilla de Correo 67, Sucursal 28, 1428 Buenos Aires (Argentina) and Dpto. de Fisica, FCEN, Universidad de Buenos Aires (Argentina)

2009-11-01

Interference effects recently observed in grazing scattering of swift atoms from insulator surfaces are studied within a distorted-wave method - the surface eikonal approximation. This approach makes use of the eikonal wave function, involving axial channeled trajectories. The theory is applied to helium atoms colliding with a LiF(001) surface along low-index crystallographic directions. The roles played by the projectile polarization and the surface rumpling are investigated, finding that both effects are important for the description of the experimental projectile distributions.

Chromatic X-ray magnifying method and apparatus by Bragg reflective planes on the surface of Abbe sphere

Science.gov (United States)

Thoe, Robert S.

1991-01-01

Method and apparatus for producing sharp, chromatic, magnified images of X-ray emitting objects, are provided. The apparatus, which constitutes an X-ray microscope or telescope, comprises a connected collection of Bragg reflecting planes, comprised of either a bent crystal or a synthetic multilayer structure, disposed on and adjacent to a locus determined by a spherical surface. The individual Bragg planes are spatially oriented to Bragg reflect radiation from the object location toward the image location. This is accomplished by making the Bragg planes spatially coincident with the surfaces of either a nested series of prolate ellipsoids of revolution, or a nested series of spheres. The spacing between the Bragg reflecting planes can be tailored to control the wavelengths and the amount of the X-radiation that is Bragg reflected to form the X-ray image.

Vicinal surfaces for functional nanostructures.

Science.gov (United States)

Tegenkamp, Christoph

2009-01-07

Vicinal surfaces are currently the focus of research. The regular arrangements of atomic steps on a mesoscopic scale reveal the possibility to functionalize these surfaces for technical applications, e.g. nanowires, catalysts, etc. The steps of the vicinal surface are well-defined defect structures of atomic size for nucleation of low-dimensional nanostructures. The concentration and therefore the coupling between the nanostructures can be tuned over a wide range by simply changing the inclination angle of the substrate. However, the coupling of these nano-objects to the substrate is just as important in controlling their electronic or chemical properties and making a functionality useable. On the basis of stepped insulating films, these aspects are fulfilled and will be considered in the first part of this review. Recent results for the epitaxial growth of wide bandgap insulating films (CaF(2), MgO, NaCl, BaSrO) on metallic and semiconducting vicinal substrates (Si(100), Ge(100), Ag(100)) will be presented. The change of the electronic structure, the adsorption behavior as well as the kinetics and energetics of color centers in the presence of steps is discussed. The successful bridging of the gap between the atomic and mesoscopic world, i.e. the functionalization of vicinal surfaces by nanostructures, is demonstrated in the second part by metal adsorption on semiconducting surfaces. For (sub)monolayer coverage these systems have in common that the surface states do not hybridize with the support, i.e. the semiconducting surfaces are insulating. Here I will focus on the latest results of macroscopic transport measurements on Pb quantum wires grown on vicinal Si(111) showing indeed a one-dimensional transport behavior.

Vicinal surfaces for functional nanostructures

Energy Technology Data Exchange (ETDEWEB)

Tegenkamp, Christoph [Institut fuer Festkoerperphysik, Gottfried Wilhelm Leibniz Universitaet Hannover, Appelstrasse 2, D-30167 Hannover (Germany)], E-mail: tegenkamp@fkp.uni-hannover.de

2009-01-07

Vicinal surfaces are currently the focus of research. The regular arrangements of atomic steps on a mesoscopic scale reveal the possibility to functionalize these surfaces for technical applications, e.g. nanowires, catalysts, etc. The steps of the vicinal surface are well-defined defect structures of atomic size for nucleation of low-dimensional nanostructures. The concentration and therefore the coupling between the nanostructures can be tuned over a wide range by simply changing the inclination angle of the substrate. However, the coupling of these nano-objects to the substrate is just as important in controlling their electronic or chemical properties and making a functionality useable. On the basis of stepped insulating films, these aspects are fulfilled and will be considered in the first part of this review. Recent results for the epitaxial growth of wide bandgap insulating films (CaF{sub 2}, MgO, NaCl, BaSrO) on metallic and semiconducting vicinal substrates (Si(100), Ge(100), Ag(100)) will be presented. The change of the electronic structure, the adsorption behavior as well as the kinetics and energetics of color centers in the presence of steps is discussed. The successful bridging of the gap between the atomic and mesoscopic world, i.e. the functionalization of vicinal surfaces by nanostructures, is demonstrated in the second part by metal adsorption on semiconducting surfaces. For (sub)monolayer coverage these systems have in common that the surface states do not hybridize with the support, i.e. the semiconducting surfaces are insulating. Here I will focus on the latest results of macroscopic transport measurements on Pb quantum wires grown on vicinal Si(111) showing indeed a one-dimensional transport behavior. (topical review)

Vicinal surfaces for functional nanostructures

International Nuclear Information System (INIS)

Tegenkamp, Christoph

2009-01-01

Vicinal surfaces are currently the focus of research. The regular arrangements of atomic steps on a mesoscopic scale reveal the possibility to functionalize these surfaces for technical applications, e.g. nanowires, catalysts, etc. The steps of the vicinal surface are well-defined defect structures of atomic size for nucleation of low-dimensional nanostructures. The concentration and therefore the coupling between the nanostructures can be tuned over a wide range by simply changing the inclination angle of the substrate. However, the coupling of these nano-objects to the substrate is just as important in controlling their electronic or chemical properties and making a functionality useable. On the basis of stepped insulating films, these aspects are fulfilled and will be considered in the first part of this review. Recent results for the epitaxial growth of wide bandgap insulating films (CaF 2 , MgO, NaCl, BaSrO) on metallic and semiconducting vicinal substrates (Si(100), Ge(100), Ag(100)) will be presented. The change of the electronic structure, the adsorption behavior as well as the kinetics and energetics of color centers in the presence of steps is discussed. The successful bridging of the gap between the atomic and mesoscopic world, i.e. the functionalization of vicinal surfaces by nanostructures, is demonstrated in the second part by metal adsorption on semiconducting surfaces. For (sub)monolayer coverage these systems have in common that the surface states do not hybridize with the support, i.e. the semiconducting surfaces are insulating. Here I will focus on the latest results of macroscopic transport measurements on Pb quantum wires grown on vicinal Si(111) showing indeed a one-dimensional transport behavior. (topical review)

Bovine serum albumin adsorption on functionalized porous silicon surfaces

Science.gov (United States)

Tay, Li-Lin; Rowell, Nelson L.; Lockwood, David J.; Boukherroub, Rabah

2004-10-01

The large surface area within porous Si (pSi) and its strong room temperature photoluminescence (PL) make it an ideal host for biological sensors. In particular, the development of pSi-based optical sensors for DNA, enzyme and other biochemical molecules have become of great interest. Here, we demonstrate that the in-situ monitoring of the pSi PL behaviour can be used as a positive identification of bovine serum albumin (BSA) protein adsorption inside the porous matrix. Electrochemically prepared pSi films were first functionalized with undecylenic acid to produce an organic monolayer covalently attached to the porous silicon surfaces. The acid terminal group also provided favourable BSA binding sites on the pSi matrix sidewalls. In-situ PL spectra showed a gradual red shift (up to 12 meV) in the PL peak energy due to the protein incorporation into the porous matrix. The PL then exhibited a continuous blue shift after saturation of the protein molecules in the pores. This blue shift of the PL peak frequency and a steady increase in the PL intensity is evidence of surface oxidation. Comparing the specular reflectance obtained by Fourier transform infrared spectroscopy (FTIR) before and after BSA incubation confirmed the adsorption of protein in the pSi matrix.

Transient reflection and transmission of E polarized electromagnetic waves at boundary surface between air and moving isotropic plasma

International Nuclear Information System (INIS)

Saito, Yukimasa

1977-01-01

The transient reflection and transmission waves of E polarized electromagnetic waves coming into the boundary surface between air and moving isotropic plasma were theoretically investigated. By using the Laplace transformation in the moving system, the formulae of Lorentz and inverse Lorentz transformations concerning electromagnetic field were transformed, thus the transient reflection and transmission waves were obtained. These waves were normalized with the angular frequency of the incident waves, and the variation of the wave form was obtained. Examples of the numerical calculation of reflected waves are shown for the plasma moving in parallel to the boundary surface. (Kato, T.)

Seismic interferometry : Reconstructing the earth's reflection response

NARCIS (Netherlands)

Draganov, D.S.; Wapenaar, C.P.A.; Thorbecke, J.W.

2006-01-01

In 1968, Jon Claerbout showed that the reflection response of a 1D acoustic medium can be reconstructed by autocorrelating the transmission response. Since then, several authors have derived relationships for reconstructing Green's functions at the surface, using crosscorrelations of (noise)

An analytical two-flow model to simulate the distribution of irradiance in coastal waters with a wind-roughed surface and bottom reflectance

Science.gov (United States)

Ma, Wei-Ming

1997-06-01

An analytical two-flow model is derived from the radiative transfer equation to simulate the distribution of irradiance in coastal waters with a wind-roughed surface and bottom reflectance. The model utilizes unique boundary conditions, including the surface slope of the downwelling and upwelling irradiance as well as the influence of wind and bottom reflectance on simulated surface reflectance. The developed model provides a simple mathematical concept for understanding the irradiant light flux and associated processes in coastal or fresh water as well as turbid estuarine waters. The model is applied to data from the Banana River and coastal Atlantic Ocean water off the east coast of central Florida, USA. The two-flow irradiance model is capable of simulating realistic above-surface reflectance signatures under wind-roughened air-water surface given realistic input parameters including a specular flux conversion coefficient, absorption coefficient, backscattering coefficient, atmospheric visibility, bottom reflectance, and water depth. The root-mean-squared error of the calculated above-surface reflectances is approximately 3% in the Banana River and is less than 15% in coastal Atlantic Ocean off the east of Florida. Result of the subsurface reflectance sensitivity analysis indicates that the specular conversion coefficient is the most sensitive parameter in the model, followed by the beam attenuation coefficient, absorption coefficient, water depth, backscattering coefficient, specular irradiance, diffuse irradiance, bottom reflectance, and wind speed. On the other hand, result of the above-surface reflectance sensitivity analysis indicates that the wind speed is the most important parameter, followed by bottom reflectance, attenuation coefficient, water depth, conversion coefficient, specular irradiance, downwelling irradiance, absorption coefficient, and backscattering coefficient. Model results depend on the accuracy of these parameters to a large degree and

On the X-ray reflectivity by poly allyl diglycol carbonate (PADC)

International Nuclear Information System (INIS)

Ghazaly, M. El

2011-01-01

X-ray reflectivity via the poly allyl diglycol carbonate (CR-39 polymer sheet) was investigated. X-ray reflectivity was measured for a pristine and a chemically etched CR-39 detector in 6.25N NaOH at (70 ± 0.5) .deg. C for different durations. Far from the spectral peak, the reflectivity of the CR-39 polymer sheet has a wide peak at 2θ = 20.1 .deg. , and its intensity is decreased by increasing the etching time. Moreover, the integrated counts under the peaks, C(t e ), vary linearly as a function of the etching time t e . Data are fitted using a linear function C(t e ) = A+Bt e , with fitting parameters A = (3271 ± 170) and B = (- 960 ± 84). The reflectivity deterioration is attributed to the increase of CR-39 surface's roughness due to the chemical etching. The rocking curves of X-ray reflectivity were measured for a pristine and an etched CR-39 polymer sheet. Specular reflections are observed, as well as Yoneda wings, which broaden and move away from the specular reflections due to the increase in the CR-39 surface's roughness.

IRAS surface brightness maps of reflection nebulae in the Pleiades

Science.gov (United States)

Castelaz, Michael W.; Werner, M. W.; Sellgren, K.

1987-01-01

Surface brightness maps at 12, 25, 60, and 100 microns were made of a 2.5 deg x 2.5 deg area of the reflection nebulae in the Pleiades by coadding IRAS scans of this region. Emission is seen surrounding 17 Tau, 20 Tau, 23 Tau, and 25 Tau in all four bands, coextensive with the visible reflection nebulosity, and extending as far as 30 arcminutes from the illuminating stars. The infrared energy distributions of the nebulae peak in the 100 micron band, but up to 40 percent of the total infrared power lies in the 12 and 25 micron bands. The brightness of the 12 and 25 micron emission and the absence of temperature gradients at these wavelengths are inconsistent with the predictions of equilibrium thermal emission models. The emission at these wavelengths appears to be the result of micron nonequilibrium emission from very small grains, or from molecules consisting of 10-100 carbon atoms, which have been excited by ultraviolet radiation from the illuminating stars.

Quantum field theory near surfaces of discontinuity

International Nuclear Information System (INIS)

Onishi, H.T.

1981-01-01

This work deals with the problem of a quantized scalar field propagating near a surface of discontinuity. The proper time formalism is employed to express the Green's function and stress tensor as proper time integrals of a transformation function. The transformation function is calculated by a WKB approximation which exhibits the essential singularities generated by the high frequency behavior of waves propagating near the surface. Two singularities are present, the usual direct singularity and an additional reflected singularity generated by the high frequency behavior of waves reflected by the discontinuity. The stress tensor is calculated by dimensional continuation. The results are employed to analyze energy generated by the surface

Giant enhancement of reflectance due to the interplay between surface confined wave modes and nonlinear gain in dielectric media.

Science.gov (United States)

Kim, Sangbum; Kim, Kihong

2017-12-11

We study theoretically the interplay between the surface confined wave modes and the linear and nonlinear gain of the dielectric layer in the Otto configuration. The surface confined wave modes, such as surface plasmons or waveguide modes, are excited in the dielectric-metal bilayer by obliquely incident p waves. In the purely linear case, we find that the interplay between linear gain and surface confined wave modes can generate a large reflectance peak with its value much greater than 1. As the linear gain parameter increases, the peak appears at smaller incident angles, and the associated modes also change from surface plasmons to waveguide modes. When the nonlinear gain is turned on, the reflectance shows very strong multistability near the incident angles associated with surface confined wave modes. As the nonlinear gain parameter is varied, the reflectance curve undergoes complicated topological changes and sometimes displays separated closed curves. When the nonlinear gain parameter takes an optimally small value, a giant amplification of the reflectance by three orders of magnitude occurs near the incident angle associated with a waveguide mode. We also find that there exists a range of the incident angle where the wave is dissipated rather than amplified even in the presence of gain. We suggest that this can provide the basis for a possible new technology for thermal control in the subwavelength scale.

Functions and generality of logic reflections on Dedekind's and Frege's logicisms

CERN Document Server

Benis-Sinaceur, Hourya; Sandu, Gabriel

2015-01-01

This book examines three connected aspects of Frege's logicism: the differences between Dedekind's and Frege's interpretation of the term 'logic' and related terms and reflects on Frege's notion of function, comparing its understanding and the role it played in Frege's and Lagrange's foundational programs. It concludes with an examination of the notion of arbitrary function, taking into account Frege's, Ramsey's and Russell's view on the subject. Composed of three chapters, this book sheds light on important aspects of Dedekind's and Frege's logicisms. The first chapter explains how, although he shares Frege's aim at substituting logical standards of rigor to intuitive imports from spatio-temporal experience into the deductive presentation of arithmetic, Dedekind had a different goal and used or invented different tools. The chapter highlights basic dissimilarities between Dedekind's and Frege's actual ways of doing and thinking. The second chapter reflects on Frege's notion of a function, in comparison with ...

Reflection-type hologram for atoms

International Nuclear Information System (INIS)

Shimizu, Fujio; Fujita, Jun-ichi

2002-01-01

A cold metastable neon atomic beam was manipulated with a reflective amplitude hologram that was encoded on a silicon surface. A black-and-white pattern of atoms was reconstructed on a microchannel plate detector. The hologram used the enhanced quantum reflection developed by authors and was made of a two-dimensional array of rectangular low and high reflective cells. The surface of the high reflective cell was composed of regularly spaced roof-shaped ridges, while the low reflective cell was simply a flat surface. The hologram was the first demonstration of reflective atom-optical elements that used universal interaction between a neutral atom and solid surface

Infrared reflection properties and modelling of in situ reflection measurements on plasma-facing materials in Tore Supra

International Nuclear Information System (INIS)

Reichle, R; Desgranges, C; Faisse, F; Pocheau, C; Lasserre, J-P; Oelhoffen, F; Eupherte, L; Todeschini, M

2009-01-01

Tore Supra has-like ITER-reflecting internal surfaces, which can perturb the machine protection systems based on infrared (IR) thermography. To ameliorate this situation, we have measured and modelled in the 3-5 μm wavelength range the bi-directional reflection distribution function (BRDF) of wall material samples from Tore Supra and conducted in situ reflection measurements and simulated them with the CEA COSMOS code. BRDF results are presented for B 4 C and carbon fibre composite (CFC) tiles. The hemispherical integrated reflection ranges from 0.12 for the B 4 C sample to 0.39 for a CFC tile from the limiter erosion zone. In situ measurements of the IR reflection of a blackbody source off an ICRH and an LHCD antenna of Tore Supra are well reproduced by the simulation.

Infrared reflection properties and modelling of in situ reflection measurements on plasma-facing materials in Tore Supra

Energy Technology Data Exchange (ETDEWEB)

Reichle, R; Desgranges, C; Faisse, F; Pocheau, C [CEA, IRFM, F-13108 Saint-Paul-lez-Durance (France); Lasserre, J-P; Oelhoffen, F; Eupherte, L; Todeschini, M [CEA, DAM, CESTA, F-33114 Le Barp (France)

2009-12-15

Tore Supra has-like ITER-reflecting internal surfaces, which can perturb the machine protection systems based on infrared (IR) thermography. To ameliorate this situation, we have measured and modelled in the 3-5 {mu}m wavelength range the bi-directional reflection distribution function (BRDF) of wall material samples from Tore Supra and conducted in situ reflection measurements and simulated them with the CEA COSMOS code. BRDF results are presented for B{sub 4}C and carbon fibre composite (CFC) tiles. The hemispherical integrated reflection ranges from 0.12 for the B{sub 4}C sample to 0.39 for a CFC tile from the limiter erosion zone. In situ measurements of the IR reflection of a blackbody source off an ICRH and an LHCD antenna of Tore Supra are well reproduced by the simulation.

Morphology and phase structures of CW laser-induced oxide layers on iron surface with evolving reflectivity and colors

Energy Technology Data Exchange (ETDEWEB)

Wu, Taotao, E-mail: wutaotao@nint.ac.cn; Wang, Lijun; Wei, Chenghua; Zhou, Menglian; He, Minbo; Wu, Lixiong

2016-11-30

Highlights: • Firstly, iron samples with different color features were obtained by continuous wave laser irradiation depending on progressive durations. The real-time reflectivity and temperature of samples were measured. The color and the reflectivity evolution were related. They were both caused by the forming oxide films. • Secondly, laser-induced oxidation process of iron was studied by microscope, X-ray diffraction and Raman spectrum. The first formed magnetite made the surface reflectivity decline rapidly and caused the “positive feedback” effect because of molecular absorption. The later formed hematite oscillated the reflectivity by interference effect. • Lastly, the laser-induced oxide films were thin, orientated and badly crystallized. The Wagner oxidation theory was incapable of describing the non-isothermal and early stage oxidation process. So we emphasized that a precise oxidation model depending on the experiment and the optical constants of the laser-induced oxides must be studied. - Abstract: Laser-induced oxidation will change the laser reflectivity and color features of metal surface. Both changes can be theoretically calculated based on the oxidation kinetics and the optical constants of oxides. For the purpose of calculation, the laser-induced oxidation process of pure polycrystalline iron was studied. Samples with various color features were obtained by continuous wave Nd:YAG fiber laser (1.06 μm) irradiation depending on progressive durations in the intensity of 1.90 W/cm{sup 2}. The real-time reflectivity and temperature were measured with integral sphere and thermocouples. The irradiated surface morphology and phase structures were characterized by microscope, X-ray diffraction and Raman spectrum. It was found that the first formed magnetite made the surface reflectivity decline rapidly and caused the “positive feedback” effect because of molecular absorption. The later formed hematite oscillated the reflectivity by

Kramers-Kronig transform for the surface energy loss function

International Nuclear Information System (INIS)

Tan, G.L.; DeNoyer, L.K.; French, R.H.; Guittet, M.J.; Gautier-Soyer, M.

2005-01-01

A new pair of Kramers-Kronig (KK) dispersion relationships for the transformation of surface energy loss function Im[-1/(ε + 1)] has been proposed. The validity of the new surface KK transform is confirmed, using both a Lorentz oscillator model and the surface energy loss functions determined from the experimental complex dielectric function of SrTiO 3 and tungsten metal. The interband transition strength spectra (J cv ) have been derived either directly from the original complex dielectric function or from the derived dielectric function obtained from the KK transform of the surface energy loss function. The original J cv trace and post-J cv trace overlapped together for the three modes, indicating that the new surface Kramers-Kronig dispersion relationship is valid for the surface energy loss function

Land Surface Reflectance Retrieval from Hyperspectral Data Collected by an Unmanned Aerial Vehicle over the Baotou Test Site

Science.gov (United States)

Duan, Si-Bo; Li, Zhao-Liang; Tang, Bo-Hui; Wu, Hua; Ma, Lingling; Zhao, Enyu; Li, Chuanrong

2013-01-01

To evaluate the in-flight performance of a new hyperspectral sensor onboard an unmanned aerial vehicle (UAV-HYPER), a comprehensive field campaign was conducted over the Baotou test site in China on 3 September 2011. Several portable reference reflectance targets were deployed across the test site. The radiometric performance of the UAV-HYPER sensor was assessed in terms of signal-to-noise ratio (SNR) and the calibration accuracy. The SNR of the different bands of the UAV-HYPER sensor was estimated to be between approximately 5 and 120 over the homogeneous targets, and the linear response of the apparent reflectance ranged from approximately 0.05 to 0.45. The uniform and non-uniform Lambertian land surface reflectance was retrieved and validated using in situ measurements, with root mean square error (RMSE) of approximately 0.01–0.07 and relative RMSE of approximately 5%–12%. There were small discrepancies between the retrieved uniform and non-uniform Lambertian land surface reflectance over the homogeneous targets and under low aerosol optical depth (AOD) conditions (AOD = 0.18). However, these discrepancies must be taken into account when adjacent pixels had large land surface reflectance contrast and under high AOD conditions (e.g. AOD = 1.0). PMID:23785513

Calculus on Surfaces with General Closest Point Functions

KAUST Repository

Mä rz, Thomas; Macdonald, Colin B.

2012-01-01

The closest point method for solving partial differential equations (PDEs) posed on surfaces was recently introduced by Ruuth and Merriman [J. Comput. Phys., 227 (2008), pp. 1943- 1961] and successfully applied to a variety of surface PDEs. In this paper we study the theoretical foundations of this method. The main idea is that surface differentials of a surface function can be replaced with Cartesian differentials of its closest point extension, i.e., its composition with a closest point function. We introduce a general class of these closest point functions (a subset of differentiable retractions), show that these are exactly the functions necessary to satisfy the above idea, and give a geometric characterization of this class. Finally, we construct some closest point functions and demonstrate their effectiveness numerically on surface PDEs. © 2012 Society for Industrial and Applied Mathematics.

Quantifying the Uncertainty in High Spatial and Temporal Resolution Synthetic Land Surface Reflectance at Pixel Level Using Ground-Based Measurements

Science.gov (United States)

Kong, J.; Ryu, Y.

2017-12-01

Algorithms for fusing high temporal frequency and high spatial resolution satellite images are widely used to develop dense time-series land surface observations. While many studies have revealed that the synthesized frequent high spatial resolution images could be successfully applied in vegetation mapping and monitoring, validation and correction of fused images have not been focused than its importance. To evaluate the precision of fused image in pixel level, in-situ reflectance measurements which could account for the pixel-level heterogeneity are necessary. In this study, the synthetic images of land surface reflectance were predicted by the coarse high-frequency images acquired from MODIS and high spatial resolution images from Landsat-8 OLI using the Flexible Spatiotemporal Data Fusion (FSDAF). Ground-based reflectance was measured by JAZ Spectrometer (Ocean Optics, Dunedin, FL, USA) on rice paddy during five main growth stages in Cheorwon-gun, Republic of Korea, where the landscape heterogeneity changes through the growing season. After analyzing the spatial heterogeneity and seasonal variation of land surface reflectance based on the ground measurements, the uncertainties of the fused images were quantified at pixel level. Finally, this relationship was applied to correct the fused reflectance images and build the seasonal time series of rice paddy surface reflectance. This dataset could be significant for rice planting area extraction, phenological stages detection, and variables estimation.

Surface functionalization of solid state ultra-high molecular weight polyethylene through chemical grafting

Science.gov (United States)

Sherazi, Tauqir A.; Rehman, Tayyiba; Naqvi, Syed Ali Raza; Shaikh, Ahson Jabbar; Shahzad, Sohail Anjum; Abbas, Ghazanfar; Raza, Rizwan; Waseem, Amir

2015-12-01

The surface of ultra-high molecular weight polyethylene (UHMWPE) powder was functionalized with styrene using chemical grafting technique. The grafting process was initiated through radical generation on base polymer matrix in the solid state by sodium thiosulfate, while peroxides formed at radical sites during this process were dissociated by ceric ammonium nitrate. Various factors were optimized and reasonably high level of monomer grafting was achieved, i.e., 15.6%. The effect of different acids as additive and divinyl benzene (DVB) as a cross-linking agent was also studied. Post-grafting sulfonation was conducted to introduce the ionic moieties to the grafted polymer. Ion-exchange capacity (IEC) was measured experimentally and is found to be 1.04 meq g-1, which is in close agreement with the theoretical IEC values. The chemical structure of grafted and functionalized polymer was characterized by attenuated total reflection infrared spectroscopy (ATR-FTIR) and thermal properties were investigated by thermo gravimetric analysis (TGA) and differential scanning calorimetry (DSC). Thermal analysis depicts that the presence of radicals on the polymer chain accelerates the thermal decomposition process. The results signify that the chemical grafting is an effective tool for substantial surface modification and subsequent functionalization of polyethylene.

Synchronous scattering and diffraction from gold nanotextured surfaces with structure factors

Science.gov (United States)

Gu, Min-Jhong; Lee, Ming-Tsang; Huang, Chien-Hsun; Wu, Chi-Chun; Chen, Yu-Bin

2018-05-01

Synchronous scattering and diffraction were demonstrated using reflectance from gold nanotextured surfaces at oblique (θi = 15° and 60°) incidence of wavelength λ = 405 nm. Two samples of unique auto-correlation functions were cost-effectively fabricated. Multiple structure factors of their profiles were confirmed with Fourier expansions. Bi-directional reflectance function (BRDF) from these samples provided experimental proofs. On the other hand, standard deviation of height and unique auto-correlation function of each sample were used to generate surfaces numerically. Comparing their BRDF with those of totally random rough surfaces further suggested that structure factors in profile could reduce specular reflection more than totally random roughness.

Formation of reflective and conductive silver film on ABS surface via covalent grafting and solution spray

Energy Technology Data Exchange (ETDEWEB)

Chen, Dexin; Zhang, Yan [School of Mechanical and Automotive Engineering, South China University of Technology, 381 Wushan, Guangzhou 510640 (China); Bessho, Takeshi [Higashifuji Technical Center, Toyota Motor Corporation, 1200 Mishuku, Susono, Shizuoka 410-1193 (Japan); Kudo, Takahiro; Sang, Jing; Hirahara, Hidetoshi; Mori, Kunio [Faculty of Engineering, Iwate University, 4-3-5 Ueda, Morioka 020-8551 (Japan); Kang, Zhixin, E-mail: zxkang@scut.edu.cn [School of Mechanical and Automotive Engineering, South China University of Technology, 381 Wushan, Guangzhou 510640 (China)

2015-09-15

Highlights: • A pure and homogenous silver film was deposited by spray-style plating technique. • The mechanism of covalent bonding between coating and substrate was studied. • The silver coating is highly reflective and conductive. • UV light was used to activate the ABS surface with triazine azide derivative. - Abstract: Conductive and reflective silver layers on acrylonitrile butadiene styrene (ABS) plastics have been prepared by photo grafting of triazine azides upon ultraviolet activation, self-assembling of triazine dithiols and silver electroless plating by solution spray based on silver mirror reaction. The as-prepared silver film exhibited excellent adhesion with ABS owing to covalent bonds between coating and substrate, and the detailed bonding mechanism have been investigated by X-ray photoelectron spectroscopy (XPS). X-ray diffraction (XRD) result revealed that silver film on ABS was pure and with a nanocrystalline structure. Atomic force microscope (AFM) analysis demonstrated that massive silver particles with sizes varying from 80 to 120 nm were deposited on ABS and formed a homogenous and smooth coating, resulting in highly reflective surface. Furthermore, silver maintained its unique conductivity even as film on ABS surface in term of four-point probe method.

Formation of reflective and conductive silver film on ABS surface via covalent grafting and solution spray

International Nuclear Information System (INIS)

Chen, Dexin; Zhang, Yan; Bessho, Takeshi; Kudo, Takahiro; Sang, Jing; Hirahara, Hidetoshi; Mori, Kunio; Kang, Zhixin

2015-01-01

Highlights: • A pure and homogenous silver film was deposited by spray-style plating technique. • The mechanism of covalent bonding between coating and substrate was studied. • The silver coating is highly reflective and conductive. • UV light was used to activate the ABS surface with triazine azide derivative. - Abstract: Conductive and reflective silver layers on acrylonitrile butadiene styrene (ABS) plastics have been prepared by photo grafting of triazine azides upon ultraviolet activation, self-assembling of triazine dithiols and silver electroless plating by solution spray based on silver mirror reaction. The as-prepared silver film exhibited excellent adhesion with ABS owing to covalent bonds between coating and substrate, and the detailed bonding mechanism have been investigated by X-ray photoelectron spectroscopy (XPS). X-ray diffraction (XRD) result revealed that silver film on ABS was pure and with a nanocrystalline structure. Atomic force microscope (AFM) analysis demonstrated that massive silver particles with sizes varying from 80 to 120 nm were deposited on ABS and formed a homogenous and smooth coating, resulting in highly reflective surface. Furthermore, silver maintained its unique conductivity even as film on ABS surface in term of four-point probe method

Detection of Lettuce Discoloration Using Hyperspectral Reflectance Imaging.

Science.gov (United States)

Mo, Changyeun; Kim, Giyoung; Lim, Jongguk; Kim, Moon S; Cho, Hyunjeong; Cho, Byoung-Kwan

2015-11-20

Rapid visible/near-infrared (VNIR) hyperspectral imaging methods, employing both a single waveband algorithm and multi-spectral algorithms, were developed in order to discrimination between sound and discolored lettuce. Reflectance spectra for sound and discolored lettuce surfaces were extracted from hyperspectral reflectance images obtained in the 400-1000 nm wavelength range. The optimal wavebands for discriminating between discolored and sound lettuce surfaces were determined using one-way analysis of variance. Multi-spectral imaging algorithms developed using ratio and subtraction functions resulted in enhanced classification accuracy of above 99.9% for discolored and sound areas on both adaxial and abaxial lettuce surfaces. Ratio imaging (RI) and subtraction imaging (SI) algorithms at wavelengths of 552/701 nm and 557-701 nm, respectively, exhibited better classification performances compared to results obtained for all possible two-waveband combinations. These results suggest that hyperspectral reflectance imaging techniques can potentially be used to discriminate between discolored and sound fresh-cut lettuce.

Surface energy and work function of elemental metals

DEFF Research Database (Denmark)

Skriver, Hans Lomholt; Rosengaard, N. M.

1992-01-01

and noble metals, as derived from the surface tension of liquid metals. In addition, they give work functions which agree with the limited experimental data obtained from single crystals to within 15%, and explain the smooth behavior of the experimental work functions of polycrystalline samples......We have performed an ab initio study of the surface energy and the work function for six close-packed surfaces of 40 elemental metals by means of a Green’s-function technique, based on the linear-muffin-tin-orbitals method within the tight-binding and atomic-sphere approximations. The results...... are in excellent agreement with a recent full-potential, all-electron, slab-supercell calculation of surface energies and work functions for the 4d metals. The present calculations explain the trend exhibited by the surface energies of the alkali, alkaline earth, divalent rare-earth, 3d, 4d, and 5d transition...

Modeling and analysis of surface roughness effects on sputtering, reflection, and sputtered particle transport

International Nuclear Information System (INIS)

Brooks, J.N.; Ruzic, D.N.

1990-01-01

The microstructure of the redeposited surface in tokamaks may affect sputtering and reflection properties and subsequent particle transport. This subject has been studied numerically using coupled models/codes for near-surface plasma particle kinetic transport (WBC code) and rough surface sputtering (fractal-TRIM). The coupled codes provide an overall Monte Carlo calculation of the sputtering cascade resulting from an initial flux of hydrogen ions. Beryllium, carbon, and tungsten surfaces are analyzed for typical high recycling, oblique magnetic field, divertor conditions. Significant variations in computed sputtering rates are found with surface roughness. Beryllium exhibits high D-T and self-sputtering coefficients for the plasma regime studied (T e = 30-75 eV). Carbon and tungsten sputtering is significantly lower. 9 refs., 6 figs., 1 tab

Bone-like apatite coating on functionalized poly(etheretherketone) surface via tailored silanization layers technique

Energy Technology Data Exchange (ETDEWEB)

Zheng, Yanyan [Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Xiong, Chengdong; Zhang, Shenglan [Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041 (China); Li, Xiaoyu [State Key Laboratory of Oral Diseases, West China Hospital of Stomatology, Sichuan University, Chengdu 610041 (China); Zhang, Lifang, E-mail: zhanglfcioc@163.com [Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041 (China)

2015-10-01

Poly(etheretherketone) (PEEK) is a rigid semi-crystalline polymer with outstanding mechanical properties, bone-like stiffness and suitable biocompatibility that has attracted much interest as a biomaterial for orthopedic and dental implants. However, the bio-inert surface of PEEK limits its biomedical applications when direct osteointegration between the implants and the host tissue is desired. In this work, –PO{sub 4}H{sub 2}, –COOH and –OH groups were introduced on the PEEK surface by further chemical treatments of the vinyl-terminated silanization layers formed on the hydroxylation-pretreated PEEK surface. Both the surface-functionalized and pristine specimens were characterized by X-ray photoelectron spectroscopy (XPS), attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectroscopy and water contact angle measurements. When placed in 1.5 strength simulated body fluid (SBF) solution, apatite was observed to form uniformly on the functionalized PEEK surface and firmly attach to the substrate. The characterized results demonstrated that the coating was constituted by poorly crystallized bone-like apatite and the effect of surface functional groups on coating formation was also discussed in detail. In addition, in vitro biocompatibility of PEEK, in terms of pre-osteoblast cell (MC3T3-E1) attachment, spreading and proliferation, was remarkably enhanced by the bone-like apatite coating. Thus, this study provides a method to enhance the bioactivity of PEEK and expand its applications in orthopedic and dental implants. - Highlights: • –PO{sub 4}H{sub 2}, –COOH and –OH groups were successfully introduced onto PEEK surface via tailored silanization layer technique. • Bone-like apatite formed uniformly on surface-functionalized PEEK after immersion in SBF, and tightly adhered to the PEEK. • SEM, EDS, FTIR, XPS and XRD results showed that apatite layer is composed of low-crystalline bone-like apatite. • Bone-like apatite coating

Beam line optics technologies series (7). Orthopedic treatment of sharp of light (reflecting mirror)

International Nuclear Information System (INIS)

Uruga, Tomoya; Nomura, Masaharu

2006-01-01

A reflecting mirror (mirror) is the most popular light device for orthopedic treatment of the shape of light. The paper explains the kinds of mirror for hard X-ray field and its applications in order to think the objects of mirror and how to adjust it when user experiment on the beam-line. The basic knowledge of reflection of X-ray, a use of mirror, the kinds of condenser mirror, the influence factors on the condenser size, arrangement of mirror in the hard X-ray beam-line, what kinds of mirror are necessary, evaluation of performance of mirror and adjustment, and troubles and measures are described. Layout in optics hutch at BL01B1 at SPring-8, refraction and total reflection of X-rays at surface, reflectivity of Rh and Pt with ideal surface as a function of photon energy, effects of surface roughness on reflectivity of Rh, calculated beam sizes for typical SPring-8 mirror as a function of magnification, schematic drawing of mirror, standard mirror system for vertical deflection in bending magnet beam-line, and observed and calculated reflectivity of Rh double mirror at BL01B1 at SPring-8 are illustrated. (S.Y)

Image potential effect on the specular reflection coefficient of alkali ions scattered from a nickel surface at low energy

International Nuclear Information System (INIS)

Zemih, R.; Boudjema, M.; Benazeth, C.; Boudouma, Y.; Chami, A.C.

2002-01-01

The resonant charge exchange in the incoming path of alkali ions scattered at low energy from a polycrystalline nickel surface is studied by using the image effect occurring at glancing incidence (2-10 deg. from the surface plane) and for specular reflection. The part of the experimental artefacts (geometrical factor, surface roughness ...) is extracted from the reflection coefficient of almost completely neutralised projectiles (He + or Ne + ) compared with the coefficient obtained from numerical simulations (TRIM and MARLOWE codes). The present model explains very well the lowering of the reflection coefficient measured at grazing incidence (below 4 deg.). Furthermore, the optimised values of the charge fraction in the incoming path and the image potential are in agreement with the theoretical calculations in the case of Na + /Ni at 4 keV

Viscoelasticity evaluation of rubber by surface reflection of supersonic wave.

Science.gov (United States)

Omata, Nobuaki; Suga, Takahiro; Furusawa, Hirokazu; Urabe, Shinichi; Kondo, Takeru; Ni, Qing-Qing

2006-12-22

The main characteristic of rubber is a viscoelasticity. So it is important to research the characteristic of the viscoelasticity of the high frequency band for the friction between a rubber material and the hard one with roughness, for instance, the tire and the road. As for the measurement of the viscoelasticity of rubber, DMA (dynamic mechanical analysis) is general. However, some problems are pointed out to the measurement of the high frequency band by DMA. Then, we evaluated the viscoelasticity characteristic by the supersonic wave measurement. However, attenuation of rubber is large, and when the viscoelasticity is measured by the supersonic wave therefore, it is inconvenient and limited in a past method by means of bottom reflection. In this report, we tried the viscoelasticity evaluation by the method of using complex surface reflection coefficient and we compared with the friction coefficient under wide-range friction velocity. As a result, some relationships had been found for two properties. We report the result that character of viscoelasticity of rubber was comparable to friction coefficient.

Assessment of Satellite-Derived Surface Reflectances by NASA's CAR Airborne Radiometer over Railroad Valley, Nevada

Science.gov (United States)

Kharbouche, Said; Muller, Jan-Peter; Gatebe, Charles K.; Scanlon, Tracy; Banks, Andrew C.

2017-01-01

CAR (Cloud Absorption Radiometer) is a multi-angular and multi-spectral airborne radiometer instrument, whose radiometric and geometric characteristics are well calibrated and adjusted before and after each flight campaign. CAR was built by NASA (National Aeronautics and Space Administration) in 1984. On 16 May 2008, a CAR flight campaign took place over the well-known calibration and validation site of Railroad Valley in Nevada (38.504 deg N, 115.692 deg W).The campaign coincided with the overpasses of several key EO (Earth Observation) satellites such as Landsat-7, Envisat and Terra. Thus, there are nearly simultaneous measurements from these satellites and the CAR airborne sensor over the same calibration site. The CAR spectral bands are close to those of most EO satellites. CAR has the ability to cover the whole range of azimuth view angles and a variety of zenith angles depending on altitude and, as a consequence, the biases seen between satellite and CAR measurements due to both unmatched spectral bands and unmatched angles can be significantly reduced. A comparison is presented here between CARs land surface reflectance (BRF or Bidirectional Reflectance Factor) with those derived from Terra/MODIS (MOD09 and MAIAC), Terra/MISR, Envisat/MERIS and Landsat-7. In this study, we utilized CAR data from low altitude flights (approx. 180 m above the surface) in order to minimize the effects of the atmosphere on these measurements and then obtain a valuable ground-truth data set of surface reflectance. Furthermore, this study shows that differences between measurements caused by surface heterogeneity can be tolerated, thanks to the high homogeneity of the study site on the one hand, and on the other hand, to the spatial sampling and the large number of CAR samples. These results demonstrate that satellite BRF measurements over this site are in good agreement with CAR with variable biases across different spectral bands. This is most likely due to residual aerosol

Estimating the Augmented Reflectance Ratio of the Ocean Surface When Whitecaps Appear

Directory of Open Access Journals (Sweden)

Zhantang Xu

2015-10-01

Full Text Available The presence of foam influences the accuracy of satellite-derived water-leaving radiance. A model has been developed to estimate the augmented reflectance ratio (A(λ,U due to differences in the fraction of whitecap coverage (w on the ocean surface. A(λ,U can be calculated from the product of w and ρ(λ,U, where ρ(λ,U is the augmented ratio of the reflectance of background water (Rb(λ caused by the presence of whitecaps. Our results showed that the average A(400~700,U in the visible region was approximately 1.3% at U = 9 m∙s−1, 2.2% at U = 10 m∙s−1, 4.4% at U = 12 m∙s−1, 7.4% at U = 14 m∙s−1, 19% at U = 19 m∙s−1 and 37.9% at U = 24 m∙s−1, making it is necessary to consider the augmented reflectance ratio for remote sensing applications. By estimating remote sensing augmented reflectance using A(λ,U, it was found that the result was in good agreement with previous studies conducted in other areas with U from 9 to 12 m∙s−1. Since Rb(λ is temporally and spatially variable, our model considered the variation of Rb(λ, whereas existing models have assumed that Rb(λ is constant. Therefore, the proposed model is more suitable for estimating the augmented reflectance ratio due to whitecaps.

Reflectance analysis of porosity gradient in nanostructured silicon layers

Science.gov (United States)

Jurečka, Stanislav; Imamura, Kentaro; Matsumoto, Taketoshi; Kobayashi, Hikaru

2017-12-01

In this work we study optical properties of nanostructured layers formed on silicon surface. Nanostructured layers on Si are formed in order to reach high suppression of the light reflectance. Low spectral reflectance is important for improvement of the conversion efficiency of solar cells and for other optoelectronic applications. Effective method of forming nanostructured layers with ultralow reflectance in a broad interval of wavelengths is in our approach based on metal assisted etching of Si. Si surface immersed in HF and H2O2 solution is etched in contact with the Pt mesh roller and the structure of the mesh is transferred on the etched surface. During this etching procedure the layer density evolves gradually and the spectral reflectance decreases exponentially with the depth in porous layer. We analyzed properties of the layer porosity by incorporating the porosity gradient into construction of the layer spectral reflectance theoretical model. Analyzed layer is splitted into 20 sublayers in our approach. Complex dielectric function in each sublayer is computed by using Bruggeman effective media theory and the theoretical spectral reflectance of modelled multilayer system is computed by using Abeles matrix formalism. Porosity gradient is extracted from the theoretical reflectance model optimized in comparison to the experimental values. Resulting values of the structure porosity development provide important information for optimization of the technological treatment operations.

Glints from particulate media and wavy surfaces

International Nuclear Information System (INIS)

Borovoi, Anatoli; Konoshonkin, Alexander; Kolokolova, Ludmilla

2012-01-01

Glints are bright light spots created by particulate media like cirrus clouds, glaciers, and wavy water surfaces. They are seen around the specular reflection angle. In this paper, the glints from such scattering/reflecting media are described in a unified manner through the probability density for facet tilts. Various kinds of these probability densities for wavy surfaces are defined and classified. The concept of the differential scattering cross section (DSCS) for rough surfaces instead of the conventional bidirectional reflectance distribution function (BRDF) is introduced for characterization of the glints. The simple equations connecting the DSCS and the probability densities for facet tilts are derived. It is shown that the glints from particulate media and wavy surface are very similar at small incidence angles and they are significantly different at slant incidence. -- Highlights: ► Differential scattering cross section unifies particulate media and wavy surfaces. ► The glint pattern is a mapping of the probability density function for facet tilts. ► Shadowing is a crucial aspect of glint pattern formation. ► Glint patterns discriminate between the particulate media and wavy surfaces.

Roughness-reflectance relationship of bare desert terrain: An empirical study

International Nuclear Information System (INIS)

Shoshany, M.

1993-01-01

A study of the bidirectional reflectance distribution function (BRDF) in relation to surface roughness properties was conducted in arid land near Fowlers Gap Research Station, New South Wales, Australia. Such empirical study is necessary for investigating the possibility of determining terrain geomorphological parameters from bidirectional reflectance data. A new apparatus was developed to take accurate hemispherical directions radiance measurements (HDRM). A digitizer for three-dimensional in situ roughness measurements was also developed. More than 70 hemispherical data sets were collected for various illumination conditions and surface types of desert stony pavements and rocky terrain slopes. In general, it was found that most of the surfaces exhibited an anisotropic reflection, combining a major component of backscattering. The BRDF of different surface types in relation to their roughness properties as determined by the field digitizer were then examined. Results showed that sites that are considered to differ significantly from a geomorphological point of view would not necessarily form a different BRDF

Characterization of technical surfaces by structure function analysis

Science.gov (United States)

Kalms, Michael; Kreis, Thomas; Bergmann, Ralf B.

2018-03-01

The structure function is a tool for characterizing technical surfaces that exhibits a number of advantages over Fourierbased analysis methods. So it is optimally suited for analyzing the height distributions of surfaces measured by full-field non-contacting methods. The structure function is thus a useful method to extract global or local criteria like e. g. periodicities, waviness, lay, or roughness to analyze and evaluate technical surfaces. After the definition of line- and area-structure function and offering effective procedures for their calculation this paper presents examples using simulated and measured data of technical surfaces including aircraft parts.

Temperature-reflection I

DEFF Research Database (Denmark)

McGady, David A.

2017-01-01

-temperature path integrals for quantum field theories (QFTs) should be T-reflection invariant. Because multi-particle partition functions are equal to Euclidean path integrals for QFTs, we expect them to be T-reflection invariant. Single-particle partition functions though are often not invariant under T......In this paper, we revisit the claim that many partition functions are invariant under reflecting temperatures to negative values (T-reflection). The goal of this paper is to demarcate which partition functions should be invariant under T-reflection, and why. Our main claim is that finite...... that T-reflection is unrelated to time-reversal. Finally, we study the interplay between T-reflection and perturbation theory in the anharmonic harmonic oscillator in quantum mechanics and in Yang-Mills in four-dimensions. This is the first in a series of papers on temperature-reflections....

Development of Biomimetic and Functionally Responsive Surfaces

Science.gov (United States)

Anastasiadis, Spiros H.

2010-03-01

Controlling the surface morphology of solids and manufacturing of functional surfaces with special responsive properties has been the subject of intense research. We report a methodology for creating multifunctionally responsive surfaces by irradiating silicon wafers with femtosecond laser pulses and subsequently coating them with different types of functional conformal coatings. Such surfaces exhibit controlled dual-scale roughness at the micro- and the nano-scale, which mimics the hierarchical morphology of water repellent natural surfaces. When a simple alkylsilane coating is utilized, highly water repellent surfaces are produced that quantitatively compare to those of the Lotus leaf. When a polymer brush is ``grafted from" these surfaces based on a pH-sensitive polymer, the surfaces can alter their behavior from super-hydrophilic (after immersion in a low pH buffer) to super-hydrophobic and water-repellent (following immersion to a high pH buffer). We quantify the water repellency of such responsive systems by drop elasticity measurements whereas we demonstrate that the water repellent state of such surface requires appropriate hydrophobicity of the functionalizing polymer. When a photo-responsive azobenzene-type polymer is deposited, a dynamic optical control of the wetting properties is obtained and the surface can be switched from super-hydrophilic (following UV irradiation) to hydrophobic (following green irradiation). In all the above cases we show that the principal effect of roughness is to cause amplification of the response to the different external stimuli.

Attachment Patterns and Reflective Functioning in traumatised refugees

DEFF Research Database (Denmark)

Riber, Karin

2013-01-01

psychotherapy research has shown is central to change and effect. Aims: 1) To examine attachment patterns and reflective functioning in traumatised refugees with PTSD, and 2) shed light on their significance to therapeutic alliance and treatment effect. Methods: All Arabic speaking patients in the study......Traumatized refugees have often suffered severe, prolonged, repeated traumas and pose a challenge to treatment. Attachment patterns and level of mentalizing seem to work as protection mechanisms in traumatizing events and to be important for positively utilizing the therapeutic alliance which...

Arterial stiffness and wave reflection: sex differences and relationship with left ventricular diastolic function.

Science.gov (United States)

Russo, Cesare; Jin, Zhezhen; Palmieri, Vittorio; Homma, Shunichi; Rundek, Tatjana; Elkind, Mitchell S V; Sacco, Ralph L; Di Tullio, Marco R

2012-08-01

Increased arterial stiffness and wave reflection have been reported in heart failure with normal ejection fraction (HFNEF) and in asymptomatic left ventricular (LV) diastolic dysfunction, a precursor of HFNEF. It is unclear whether women, who have higher frequency of HFNEF, are more vulnerable than men to the deleterious effects of arterial stiffness on LV diastolic function. We investigated, in a large community-based cohort, whether sex differences exist in the relationship among arterial stiffness, wave reflection, and LV diastolic function. Arterial stiffness and wave reflection were assessed in 983 participants from the Cardiovascular Abnormalities and Brain Lesions study using applanation tonometry. The central pulse pressure/stroke volume index, total arterial compliance, pulse pressure amplification, and augmentation index were used as parameters of arterial stiffness and wave reflection. LV diastolic function was evaluated by 2-dimensional echocardiography and tissue-Doppler imaging. Arterial stiffness and wave reflection were greater in women compared with men, independent of body size and heart rate (all Pfunction in both sexes. Further adjustment for cardiovascular risk factors attenuated these relationships; however, a higher central pulse pressure/stroke volume index predicted LV diastolic dysfunction in women (odds ratio, 1.54; 95% confidence intervals, 1.03 to 2.30) and men (odds ratio, 2.09; 95% confidence interval, 1.30 to 3.39), independent of other risk factors. In conclusion, in our community-based cohort study, higher arterial stiffness was associated with worse LV diastolic function in men and women. Women's higher arterial stiffness, independent of body size, may contribute to their greater susceptibility to develop HFNEF.

Diamond surface functionalization with biomimicry – Amine surface tether and thiol moiety for electrochemical sensors

Energy Technology Data Exchange (ETDEWEB)

Sund, James B., E-mail: jim@jamessund.com [Department of Electrical and Computer Engineering, Duke University, Durham, NC (United States); Causey, Corey P. [Departments of Chemistry and Biochemistry, Duke University, Durham, NC (United States); Wolter, Scott D. [Department of Physics, Elon University, Elon, NC 27244 (United States); Parker, Charles B., E-mail: charles.parker@duke.edu [Department of Electrical and Computer Engineering, Duke University, Durham, NC (United States); Stoner, Brian R. [Department of Electrical and Computer Engineering, Duke University, Durham, NC (United States); Research Triangle Institute (RTI) International, Research Triangle Park, NC (United States); Toone, Eric J. [Departments of Chemistry and Biochemistry, Duke University, Durham, NC (United States); Glass, Jeffrey T. [Department of Electrical and Computer Engineering, Duke University, Durham, NC (United States)

2014-05-01

Highlights: • Diamond surfaces were functionalized with organic molecules using a novel approach. • Used biomimicry to select a molecule to bind NO, similar to the human body. • Molecular orbital theory predicted the molecule-analyte oxidation behavior. • A thiol moiety was attached to an amine surface tether on the diamond surface. • XPS analysis verified each surface functionalization step. - Abstract: The surface of conducting diamond was functionalized with a terminal thiol group that is capable of binding and detecting nitrogen–oxygen species. The functionalization process employed multiple steps starting with doped diamond films grown by plasma enhanced chemical vapor deposition followed by hydrogen termination and photochemical attachment of a chemically protected amine alkene. The surface tether was deprotected to reveal the amine functionality, which enabled the tether to be extended with surface chemistry to add a terminal thiol moiety for electrochemical sensing applications. Each step of the process was validated using X-ray photoelectron spectroscopy analysis.

Diamond surface functionalization with biomimicry – Amine surface tether and thiol moiety for electrochemical sensors

International Nuclear Information System (INIS)

Sund, James B.; Causey, Corey P.; Wolter, Scott D.; Parker, Charles B.; Stoner, Brian R.; Toone, Eric J.; Glass, Jeffrey T.

2014-01-01

Highlights: • Diamond surfaces were functionalized with organic molecules using a novel approach. • Used biomimicry to select a molecule to bind NO, similar to the human body. • Molecular orbital theory predicted the molecule-analyte oxidation behavior. • A thiol moiety was attached to an amine surface tether on the diamond surface. • XPS analysis verified each surface functionalization step. - Abstract: The surface of conducting diamond was functionalized with a terminal thiol group that is capable of binding and detecting nitrogen–oxygen species. The functionalization process employed multiple steps starting with doped diamond films grown by plasma enhanced chemical vapor deposition followed by hydrogen termination and photochemical attachment of a chemically protected amine alkene. The surface tether was deprotected to reveal the amine functionality, which enabled the tether to be extended with surface chemistry to add a terminal thiol moiety for electrochemical sensing applications. Each step of the process was validated using X-ray photoelectron spectroscopy analysis

Nanoparticle Surface Functionality Dictates Cellular and Systemic Toxicity

DEFF Research Database (Denmark)

Saei, Amir Ata; Yazdani, Mahdieh; Lohse, Samuel E.

2017-01-01

can greatly enhance subsequent therapeutic effects of NPs while diminishing their adverse side effects. In this review, we will focus on the effect of surface functionality on the cellular uptake and the transport of NPs by various subcellular processes.......Engineered nanoparticles (NPs) have opened new frontiers in therapeutics and diagnostics in recent years. The surface functionality of these nanoparticles often predominates their interactions with various biological components of human body, and proper selection or control of surface functionality...

Effect of surface plasmon polaritons on the sensitivity of refractive index measurement using total internal reflection method

International Nuclear Information System (INIS)

Roshan Entezar, S.

2015-01-01

The phase difference between two p-polarized and s-polarized plane waves which are reflected under total internal reflection from the base of a prism with a thin metal coating is studied. Typically such a quantity can be used to measure the refractive index of a test material using the total internal reflection method. It is shown that due to the excitation of surface plasmon polaritons at the interface between the tested dielectric material and the thin metal layer, the p-polarized light experiences a large phase shift which enlarges the phase difference between the p-polarized and the s-polarized waves. As a result, the sensitivity of refractive index measurement increases and the error in determining the refractive index decreases. - Highlights: • Phase difference of totally internally reflected p and s polarized beams is studied. • Excitation of the surface wave increases the phase shift of the p-polarized light. • The sensitivity of refractive index measurement increases by using a coated prism. • The error in determining the refractive index decreases using the coated prism

Mindfulness Plus Reflection Training: Effects on Executive Function in Early Childhood

Directory of Open Access Journals (Sweden)

Philip David Zelazo

2018-02-01

Full Text Available Executive function (EF skills are essential for academic achievement, and poverty-related stress interferes with their development. This pre-test, post-test, follow-up randomized-control trial assessed the impact of an intervention targeting reflection and stress reduction on children's EF skills. Preschool children (N = 218 from schools serving low-income families in two U.S. cities were randomly assigned to one of three options delivered in 30 small-group sessions over 6 weeks: Mindfulness + Reflection training; Literacy training; or Business as Usual (BAU. Sessions were conducted by local teachers trained in a literacy curriculum or Mindfulness + Reflection intervention, which involved calming activities and games that provided opportunities to practice reflection in the context of goal-directed problem solving. EF improved in all groups, but planned contrasts indicated that the Mindfulness + Reflection group significantly outperformed the BAU group at Follow-up (4 weeks post-test. No differences in EF were observed between the BAU and Literacy training groups. Results suggest that a brief, small-group, school-based intervention teaching mindfulness and reflection did not improve EF skills more than literacy training but is promising compared to BAU for improving EF in low-income preschool children several weeks following the intervention.

LiDAR Relative Reflectivity Surface (2011) for the St. Thomas East End Reserve, St. Thomas

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — This image represents a LiDAR (Light Detection & Ranging) 0.3x0.3 meter resolution relative seafloor reflectivity surface for the St. Thomas East End Reserve...

Domain wall partition function of the eight-vertex model with a non-diagonal reflecting end

International Nuclear Information System (INIS)

Yang Wenli; Chen Xi; Feng Jun; Hao Kun; Shi Kangjie; Sun Chengyi; Yang Zhanying; Zhang Yaozhong

2011-01-01

With the help of the Drinfeld twist or factorizing F-matrix for the eight-vertex SOS model, we derive the recursion relations of the partition function for the eight-vertex model with a generic non-diagonal reflecting end and domain wall boundary condition. Solving the recursion relations, we obtain the explicit determinant expression of the partition function. Our result shows that, contrary to the eight-vertex model without a reflecting end, the partition function can be expressed as a single determinant.

Radius of curvature measurement of spherical smooth surfaces by multiple-beam interferometry in reflection

Science.gov (United States)

Abdelsalam, D. G.; Shaalan, M. S.; Eloker, M. M.; Kim, Daesuk

2010-06-01

In this paper a method is presented to accurately measure the radius of curvature of different types of curved surfaces of different radii of curvatures of 38 000,18 000 and 8000 mm using multiple-beam interference fringes in reflection. The images captured by the digital detector were corrected by flat fielding method. The corrected images were analyzed and the form of the surfaces was obtained. A 3D profile for the three types of surfaces was obtained using Zernike polynomial fitting. Some sources of uncertainty in measurement were calculated by means of ray tracing simulations and the uncertainty budget was estimated within λ/40.

Rumination and self-reflection in stress narratives and relations to psychological functioning.

Science.gov (United States)

Marin, Kelly A; Rotondo, Elena K

2017-01-01

The longitudinal study aims to expand what is known about the costs and benefits of narrating stressful experiences by exploring changes in rumination within the narrative process and comparing it to changes in self-reflection. Rumination (e.g., brooding, self-criticism, and negative emotions) and self-reflection were measured in stress narratives of 56 college students. There were several goals: (1) examine changes in narrative rumination and narrative self-reflection over 3 days of writing, (2) examine the relations among the changes in narrative rumination variables and narrative self-reflection and (3) examine how changes in narrative rumination and narrative self-reflection relate to multiple measures of psychological functioning. Overall, individuals increased self-reflection over the 3-day writing task. Individuals who increased ruminative brooding across the 3 days of writing showed lower ego identity development (short term and long term) and self-esteem (short term), while increased self-criticism was positively correlated with identity distress (short term). Implications of the different aspects of narrative rumination, specifically in the context of stressful experiences, are discussed.

Kaguya observations of the lunar wake in the terrestrial foreshock: Surface potential change by bow-shock reflected ions

Science.gov (United States)

Nishino, Masaki N.; Harada, Yuki; Saito, Yoshifumi; Tsunakawa, Hideo; Takahashi, Futoshi; Yokota, Shoichiro; Matsushima, Masaki; Shibuya, Hidetoshi; Shimizu, Hisayoshi

2017-09-01

There forms a tenuous region called the wake behind the Moon in the solar wind, and plasma entry/refilling into the wake is a fundamental problem of the lunar plasma science. High-energy ions and electrons in the foreshock of the Earth's magnetosphere were detected at the lunar surface in the Apollo era, but their effects on the lunar night-side environment have never been studied. Here we show the first observation of bow-shock reflected protons by Kaguya (SELENE) spacecraft in orbit around the Moon, confirming that solar wind plasma reflected at the terrestrial bow shock can easily access the deepest lunar wake when the Moon stays in the foreshock (We name this mechanism 'type-3 entry'). In a continuous type-3 event, low-energy electron beams from the lunar night-side surface are not obvious even though the spacecraft location is magnetically connected to the lunar surface. On the other hand, in an intermittent type-3 entry event, the kinetic energy of upward-going field-aligned electron beams decreases from ∼ 80 eV to ∼ 20 eV or electron beams disappear as the bow-shock reflected ions come accompanied by enhanced downward electrons. According to theoretical treatment based on electric current balance at the lunar surface including secondary electron emission by incident electron and ion impact, we deduce that incident ions would be accompanied by a few to several times higher flux of an incident electron flux, which well fits observed downward fluxes. We conclude that impact by the bow-shock reflected ions and electrons raises the electrostatic potential of the lunar night-side surface.

Development and Validation of a Self-Report Measure of Mentalizing: The Reflective Functioning Questionnaire.

Directory of Open Access Journals (Sweden)

Peter Fonagy

Full Text Available Reflective functioning or mentalizing is the capacity to interpret both the self and others in terms of internal mental states such as feelings, wishes, goals, desires, and attitudes. This paper is part of a series of papers outlining the development and psychometric features of a new self-report measure, the Reflective Functioning Questionnaire (RFQ, designed to provide an easy to administer self-report measure of mentalizing. We describe the development and initial validation of the RFQ in three studies. Study 1 focuses on the development of the RFQ, its factor structure and construct validity in a sample of patients with Borderline Personality Disorder (BPD and Eating Disorder (ED (n = 108 and normal controls (n = 295. Study 2 aims to replicate these findings in a fresh sample of 129 patients with personality disorder and 281 normal controls. Study 3 addresses the relationship between the RFQ, parental reflective functioning and infant attachment status as assessed with the Strange Situation Procedure (SSP in a sample of 136 community mothers and their infants. In both Study 1 and 2, confirmatory factor analyses yielded two factors assessing Certainty (RFQ_C and Uncertainty (RFQ_U about the mental states of self and others. These two factors were relatively distinct, invariant across clinical and non-clinical samples, had satisfactory internal consistency and test-retest stability, and were largely unrelated to demographic features. The scales discriminated between patients and controls, and were significantly and in theoretically predicted ways correlated with measures of empathy, mindfulness and perspective-taking, and with both self-reported and clinician-reported measures of borderline personality features and other indices of maladaptive personality functioning. Furthermore, the RFQ scales were associated with levels of parental reflective functioning, which in turn predicted infant attachment status in the SSP. Overall, this study lends

Far-infrared /FIR/ optical black bidirectional reflectance distribution function /BRDF/

Science.gov (United States)

Smith, S. M.

1981-01-01

A nonspecular reflectometer and its operation at far-infrared wavelengths are described. Large differences in nonspecular reflectance were found to exist between different optically black coatings. Normal incidence bidirectional reflectance distribution function /BRDF) measurements at wavelengths between 12 and 316 microns of three black coatings show that their mean BRDFs increase with wavelength. The specularity of two of these coatings also showed a strong wavelength dependence, while the specularity of one coating seemed independent of wavelength. The BRDF of one coating depended on the angle of incidence at 12 and 38 microns, but not at 316 microns. Beyond 200 microns, it was found necessary to correct the measurements for the beam spread of the instrument.

SURFACE TEXTURE ANALYSIS FOR FUNCTIONALITY CONTROL

DEFF Research Database (Denmark)

De Chiffre, Leonardo; Andreasen, Jan Lasson; Tosello, Guido

This document is used in connection with three exercises of 3 hours duration as a part of the course VISION ONLINE – One week course on Precision & Nanometrology. The exercises concern surface texture analysis for functionality control, in connection with three different case stories. This docume...... contains a short description of each case story, 3-D roughness parameters analysis and relation with the product’s functionality.......This document is used in connection with three exercises of 3 hours duration as a part of the course VISION ONLINE – One week course on Precision & Nanometrology. The exercises concern surface texture analysis for functionality control, in connection with three different case stories. This document...

Analysis of bacteria on steel surfaces using reflectance micro-Fourier transform infrared spectroscopy.

Science.gov (United States)

Ojeda, Jesús J; Romero-González, María E; Banwart, Steven A

2009-08-01

Reflectance micro-Fourier transform infrared (FT-IR) analysis has been applied to characterize biofilm formation of Aquabacterium commune, a common microorganism present on drinking water distribution systems, onto the increasingly popular pipe material stainless steel EN1.4307. The applicability of the reflectance micro-FT-IR technique for analyzing the bacterial functional groups is discussed, and the results are compared to spectra obtained using more conventional FT-IR techniques: transmission micro-FT-IR, attenuated transmitted reflectance (ATR), and KBr pellets. The differences between the infrared spectra of wet and dried bacteria, as well as free versus attached bacteria, are also discussed. The spectra obtained using reflectance micro-FT-IR spectroscopy were comparable to those obtained using other FT-IR techniques. The absence of sample preparation, the potential to analyze intact samples, and the ability to characterize opaque and thick samples without the need to transfer the bacterial samples to an infrared transparent medium or produce a pure culture were the main advantages of reflectance micro-FT-IR spectroscopy.

Intercomparison of 30+ years of AVHRR and Landsat-5 TM Surface Reflectance using Multiple Pseudo-Invariant Calibration Sites

Science.gov (United States)

Santamaría-Artigas, A. E.; Franch, B.; Vermote, E.; Roger, J. C.; Justice, C. O.

2017-12-01

The 30+ years daily surface reflectance long term data record (LTDR) from the Advanced Very High Resolution Radiometer (AVHRR) is a valuable source of information for long-term studies of the Earth surface. This LTDR was generated by combining observations from multiple AVHRR sensors aboard different NOAA satellites starting from the early 1980s, and due to the lack of on-board calibration its quality should be evaluated. Previous studies have used observations from the Moderate Resolution Imaging Spectroradiometer (MODIS) over pseudo-invariant calibration sites (PICS) as a calibrated reference to assess the performance of AVHRR products. However, this limits the evaluation to the period after MODIS launch. In this work, the AVHRR surface reflectance LTDR was evaluated against Landsat-5 Thematic Mapper (TM) data using observations from 4 well known pseudo-invariant calibration sites (i.e. Sonoran, Saharan, Sudan1, and Libya4) over an extended time period (1984-2011). For the intercomparison, AVHRR and TM observations of each site were extracted and averaged over a 20 km x 20 km area and aggregated to monthly mean values. In order to account for the spectral differences between sensors, Hyperion hyperspectral data from the Sonoran and Libya4 sites were convolved with sensor-specific relative spectral responses, and used to compute spectral band adjustment factors (SBAFs). Results of the intercomparison are reported in terms of the root mean square difference (RMSD) and determination coefficient (r2). In general, there is good agreement between the surface reflectance products from both sensors. The overall RMSD and r2 for all the sites and AVHRR/TM combinations were 0.03 and 0.85 for the red band, and 0.04 and 0.81 for the near-infrared band. These results show the strong performance of the AVHRR surface reflectance LTDR through all of the considered period. Thus, remarking its usefulness and value for long term Earth studies. Figure 1 shows the red (filled markers

Coupled Retrieval of Aerosol Properties and Surface Reflection Using the Airborne Multi-angle SpectroPolarimetric Imager (AirMSPI)

Science.gov (United States)

Xu, F.; van Harten, G.; Kalashnikova, O. V.; Diner, D. J.; Seidel, F. C.; Garay, M. J.; Dubovik, O.

2016-12-01

The Airborne Multi-angle SpectroPolarimetric Imager (AirMSPI) [1] has been flying aboard the NASA ER-2 high altitude aircraft since October 2010. In step-and-stare operation mode, AirMSPI acquires radiance and polarization data at 355, 380, 445, 470*, 555, 660*, 865*, and 935 nm (* denotes polarimetric bands). The imaged area covers about 10 km by 10 km and is observed from 9 view angles between ±67° off of nadir. We have developed an efficient and flexible code that uses the information content of AirMSPI data for a coupled retrieval of aerosol properties and surface reflection. The retrieval was built based on the multi-pixel optimization concept [2], with the use of a hybrid radiative transfer model [3] that combines the Markov Chain [4] and adding/doubling methods [5]. The convergence and robustness of our algorithm is ensured by applying constraints on (a) the spectral variation of the Bidirectional Polarization Distribution Function (BPDF) and angular shape of the Bidirectional Reflectance Distribution Function (BRDF); (b) the spectral variation of aerosol optical properties; and (c) the spatial variation of aerosol parameters across neighboring image pixels. Our retrieval approach has been tested using over 20 AirMSPI datasets having low to moderately high aerosol loadings ( 0.02550-nmSpace Sci. Rev. 16, 527 (1974).

The trapping of potassium atoms by a polycrystalline tungsten surface as a function of energy and angle of incidence. ch. 1

International Nuclear Information System (INIS)

Hurkmans, A.; Overbosch, E.G.; Olander, D.R.; Los, J.

1976-01-01

The trapping probability of potassium atoms on a polycrystalline tungsten surface has been measured as a function of the angle of incidence and as a function of the energy of the incoming atoms. Below an energy of 1 eV the trapping was complete; above 20 eV only reflection occurred. The trapping probability increased with increasing angle of incidence. The measurements are compared with a simple model of the fraction of atoms initially trapped. The model, a one-dimensional cube model including a Boltzmann distribution of the velocities of oscillating surface atoms, partially explains the data. The trapping probability as a function of incoming energy is well described for normal incidence, justifying the inclusion of thermal motion of the surface atoms in the model. The angular dependence can be explained in a qualitative way, although there is a substantial discrepancy for large angles of incidence, showing the presence of surface structure. (Auth.)

Observation on Surface Change of Fragile Glass: Temperature - Time Dependence Studied by X-Ray Reflectivity

International Nuclear Information System (INIS)

Kikkawa, Hiroyuki; Kitahara, Amane; Takahashi, Isao

2004-01-01

The structural change of a fragile glass surface close to the glass transition temperature Tg is studied by using X-ray reflectivity. Measurements were performed on surfaces of maltitol, which is a typical polyalcohol fragile glass with Tg = 320K. Upon both heating and cooling, we find the following features which are also noticed in silicate glass surfaces: (i) On heating, the surface morphology indicates a variation at temperatures below Tg; (ii) A drastic increase in surface roughness occurs at a temperature about 333K on heating, which is 13K higher than Tg; (iii) During the cooling of the sample, formation of a low-density surface layer (3nm at 293K) is observed. Prior to the crystallization, nm - μm sized domains were grown at the surface, which might not be reported for other glasses

Comparison between reflectivity statistics at heights of 3 and 6 km and rain rate statistics at ground level

Science.gov (United States)

Crane, R. K.

1975-01-01

An experiment was conducted to study the relations between the empirical distribution functions of reflectivity at specified locations above the surface and the corresponding functions at the surface. A bistatic radar system was used to measure continuously the scattering cross section per unit volume at heights of 3 and 6 km. A frequency of 3.7 GHz was used in the tests. It was found that the distribution functions for reflectivity may significantly change with height at heights below the level of the melting layer.

Surface Functionalization of Thin-Film Composite Membranes with Copper Nanoparticles for Antimicrobial Surface Properties

KAUST Repository

Ben-Sasson, Moshe

2014-01-07

Biofouling is a major operational challenge in reverse osmosis (RO) desalination, motivating a search for improved biofouling control strategies. Copper, long known for its antibacterial activity and relatively low cost, is an attractive potential biocidal agent. In this paper, we present a method for loading copper nanoparticles (Cu-NPs) on the surface of a thin-film composite (TFC) polyamide RO membrane. Cu-NPs were synthesized using polyethyleneimine (PEI) as a capping agent, resulting in particles with an average radius of 34 nm and a copper content between 39 and 49 wt.%. The positive charge of the Cu-NPs imparted by the PEI allowed a simple electrostatic functionalization of the negatively charged RO membrane. We confirmed functionalization and irreversible binding of the Cu-NPs to the membrane surface with SEM and XPS after exposing the membrane to bath sonication. We also demonstrated that Cu-NP functionalization can be repeated after the Cu-NPs dissolve from the membrane surface. The Cu-NP functionalization had minimal impact on the intrinsic membrane transport parameters. Surface hydrophilicity and surface roughness were also maintained, and the membrane surface charge became positive after functionalization. The functionalized membrane exhibited significant antibacterial activity, leading to an 80-95% reduction in the number of attached live bacteria for three different model bacterial strains. Challenges associated with this functionalization method and its implementation in RO desalination are discussed. © 2013 American Chemical Society.

Surface Functionalization of Thin-Film Composite Membranes with Copper Nanoparticles for Antimicrobial Surface Properties

KAUST Repository

Ben-Sasson, Moshe; Zodrow, Katherine R.; Genggeng, Qi; Kang, Yan; Giannelis, Emmanuel P.; Elimelech, Menachem

2014-01-01

Biofouling is a major operational challenge in reverse osmosis (RO) desalination, motivating a search for improved biofouling control strategies. Copper, long known for its antibacterial activity and relatively low cost, is an attractive potential biocidal agent. In this paper, we present a method for loading copper nanoparticles (Cu-NPs) on the surface of a thin-film composite (TFC) polyamide RO membrane. Cu-NPs were synthesized using polyethyleneimine (PEI) as a capping agent, resulting in particles with an average radius of 34 nm and a copper content between 39 and 49 wt.%. The positive charge of the Cu-NPs imparted by the PEI allowed a simple electrostatic functionalization of the negatively charged RO membrane. We confirmed functionalization and irreversible binding of the Cu-NPs to the membrane surface with SEM and XPS after exposing the membrane to bath sonication. We also demonstrated that Cu-NP functionalization can be repeated after the Cu-NPs dissolve from the membrane surface. The Cu-NP functionalization had minimal impact on the intrinsic membrane transport parameters. Surface hydrophilicity and surface roughness were also maintained, and the membrane surface charge became positive after functionalization. The functionalized membrane exhibited significant antibacterial activity, leading to an 80-95% reduction in the number of attached live bacteria for three different model bacterial strains. Challenges associated with this functionalization method and its implementation in RO desalination are discussed. © 2013 American Chemical Society.

Application of Sol-Gel Method as a Protective Layer on a Specular Reflective Surface for Secondary Reflector in a Solar Receiver

Energy Technology Data Exchange (ETDEWEB)

Afrin, Samia; Dagdelen, John; Ma, Zhiwen; Kumar, Vinod

2017-01-01

Highly-specular reflective surfaces that can withstand elevated-temperatures are desirable for many applications including reflective heat shielding in solar receivers and secondary reflectors, which can be used between primary concentrators and heat collectors. A high-efficiency, high-temperature solar receiver design based on arrays of cavities needs a highly-specular reflective surface on its front section to help sunlight penetrate into the absorber tubes for effective flux spreading. Since this application is for high-temperature solar receivers, this surface needs to be durable and to maintain its optical properties through the usable life. Degradation mechanisms associated with elevated temperatures and thermal cycling, which include cracking, delamination, corrosion/oxidation, and environmental effects, could cause the optical properties of surfaces to degrade rapidly in these conditions. Protected mirror surfaces for these applications have been tested by depositing a thin layer of SiO2 on top of electrodeposited silver by means of the sol-gel method. To obtain an effective thin film structure, this sol-gel procedure has been investigated extensively by varying process parameters that affect film porosity and thickness. Endurance tests have been performed in a furnace at 150 degrees C for thousands of hours. This paper presents the sol-gel process for intermediate-temperature specular reflective coatings and provides the long-term reliability test results of sol-gel protected silver-coated surfaces.

Near zero reflection by nanostructured anti-reflection coating design for Si substrates

Science.gov (United States)

Al-Fandi, Mohamed; Makableh, Yahia F.; Khasawneh, Mohammad; Rabady, Rabi

2018-05-01

The nanostructure design of near zero reflection coating for Si substrates by using ZnO Nanoneedles (ZnONN) is performed and optimized for the visible spectral range. The design investigates the ZnONN tip to body ratio effect on the anti-reflection coating properties. Different tip to body ratios are used on Si substrates. Around zero reflection is achieved by the Nanoneedles structure design presented in this work, leading to minimal reflection losses from the Si surface. The current design evolves a solution to optical losses and surface contamination effects associated with Si solar cells.

Toward tuning the surface functionalization of small ceria nanoparticles

International Nuclear Information System (INIS)

Huang, Xing; Wang, Binghui; Grulke, Eric A.; Beck, Matthew J.

2014-01-01

Understanding and controlling the performance of ceria nanoparticle (CNP) catalysts requires knowledge of the detailed structure and property of CNP surfaces and any attached functional groups. Here we report thermogravimetric analysis results showing that hydrothermally synthesized ∼30 nm CNPs are decorated with 12.9 hydroxyl groups per nm 2 of CNP surface. Quantum mechanical calculations of the density and distribution of bound surface groups imply a scaling relationship for surface group density that balances formal charges in the functionalized CNP system. Computational results for CNPs with only hydroxyl surface groups yield a predicted density of bound hydroxyl groups for ∼30 nm CNPs that is ∼33% higher than measured densities. Quantitative agreement between predicted and measured hydroxyl surface densities is achieved when calculations consider CNPs with both –OH and –O x surface groups. For this more general treatment of CNP surface functionalizations, quantum mechanical calculations predict a range of stable surface group configurations that depend on the chemical potentials of O and H, and demonstrate the potential to tune CNP surface functionalizations by varying temperature and/or partial pressures of O 2 and H 2 O

Anomalous Quasiparticle Reflection from the Surface of a ^{3}He-^{4}He Dilute Solution.

Science.gov (United States)

Ikegami, Hiroki; Kim, Kitak; Sato, Daisuke; Kono, Kimitoshi; Choi, Hyoungsoon; Monarkha, Yuriy P

2017-11-10

A free surface of a dilute ^{3}He-^{4}He liquid mixture is a unique system where two Fermi liquids with distinct dimensions coexist: a three-dimensional (3D) ^{3}He Fermi liquid in the bulk and a two-dimensional (2D) ^{3}He Fermi liquid at the surface. To investigate a novel effect generated by the interaction between the two Fermi liquids, the mobility of a Wigner crystal of electrons formed on the free surface of the mixture is studied. An anomalous enhancement of the mobility, compared with the case where the 3D and 2D systems do not interact with each other, is observed. The enhancement is explained by the nontrivial reflection of 3D quasiparticles from the surface covered with the 2D ^{3}He system.

Reflective functioning, physiological reactivity, and overcontrol in mothers: Links with school-aged children's reflective functioning.

Science.gov (United States)

Borelli, Jessica L; Hong, Kajung; Rasmussen, Hannah F; Smiley, Patricia A

2017-09-01

Theorists argue that parental reflective functioning (PRF) is activated in response to emotions, potentially supporting parenting sensitivity even when arousal is high. That is, when parents become emotionally reactive when interacting with their children, those who can use PRF to understand their children's mental states should be able to parent sensitively, which, in turn, should promote children's ability to understand their own mental states. We test this theory by examining whether, in the face of physiological reactivity, mothers' PRF inhibits one form of parenting insensitivity, overcontrol (OC), and whether this process in turn predicts children's RF. A diverse sample of school-age children (N = 106, Mage = 10.27 years) completed a standardized failure paradigm while their mothers were asked to passively observe. Following the stressor, mothers and children independently completed interviews regarding the task, which were later coded for RF with respect to children's mental states. Mothers provided saliva samples before and after the stressor, and after the interview, which were later assayed for cortisol reactivity; maternal behavior during the stressor task was coded for OC. Among mothers with low levels of RF, greater increases in cortisol were associated with more displays of OC, whereas among mothers with high PRF, greater cortisol reactivity was associated with fewer OC behaviors. For low PRF mothers, higher reactivity and OC predicted lower children's PRF for their own experiences. The findings provide initial evidence for a protective function of PRF, and may point toward the importance of promoting PRF in intervention programs to reduce parental OC. (PsycINFO Database Record (c) 2017 APA, all rights reserved).

Quantum state-resolved gas/surface reaction dynamics probed by reflection absorption infrared spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Chen Li [Department of Dynamics at Surfaces, Max Planck Institute for Biophysical Chemistry, Am Fassberg 11, Goettingen (Germany); Ueta, Hirokazu; Beck, Rainer D. [Laboratoire de Chimie Physique Moleculaire, Ecole Polytechnique Federale de Lausanne (Switzerland); Bisson, Regis [Aix-Marseille Universite, PIIM, CNRS, UMR 7345, 13397 Marseille (France)

2013-05-15

We report the design and characterization of a new molecular-beam/surface-science apparatus for quantum state-resolved studies of gas/surface reaction dynamics combining optical state-specific reactant preparation in a molecular beam by rapid adiabatic passage with detection of surface-bound reaction products by reflection absorption infrared spectroscopy (RAIRS). RAIRS is a non-invasive infrared spectroscopic detection technique that enables online monitoring of the buildup of reaction products on the target surface during reactant deposition by a molecular beam. The product uptake rate obtained by calibrated RAIRS detection yields the coverage dependent state-resolved reaction probability S({theta}). Furthermore, the infrared absorption spectra of the adsorbed products obtained by the RAIRS technique provide structural information, which help to identify nascent reaction products, investigate reaction pathways, and determine branching ratios for different pathways of a chemisorption reaction. Measurements of the dissociative chemisorption of methane on Pt(111) with this new apparatus are presented to illustrate the utility of RAIRS detection for highly detailed studies of chemical reactions at the gas/surface interface.

Attachment and parental reflective functioning features in ADHD: Enhancing the knowledge on parenting characteristics

Directory of Open Access Journals (Sweden)

Clarissa eCavallina

2015-09-01

Full Text Available Attention-deficit/hyperactivity disorder (ADHD is a disorder characterized by a chronic, pervasive, and developmentally inappropriate level of impulsivity, attention and concentration. It is associated with adverse academic and social functions and stress to families. Studies provide evidence that family variables are correlated with this disorder and that parenting styles play an important role in its complexity. However, a thorough investigation of the impact of parental affective and relational aspects on the ADHD child’s areas of functioning is still needed. We suggest investigating parenting characteristics to a greater extent by adopting an attachment perspective with a focus on parental reflective functioning as it pertains to the child’s ADHD clinical condition. In future research, parents’ attachment and the parental reflective functioning should be taken into account.

Selective functionalization of patterned glass surfaces

NARCIS (Netherlands)

Ploetz, E.; Visser, B.; Slingenbergh, W.; Evers, K.; Martinez-Martinez, D.; Pei, Y. T.; Feringa, B. L.; De Hosson, J. Th. M.; Cordes, T.; van Dorp, W. F.

2014-01-01

Tailored writing and specific positioning of molecules on nanostructures is a key step for creating functional materials and nano-optical devices, or interfaces for synthetic machines in various applications. We present a novel approach for the selective functionalization of patterned glass surfaces

Bidirectional reflectance distribution function measurements and analysis of retroreflective materials.

Science.gov (United States)

Belcour, Laurent; Pacanowski, Romain; Delahaie, Marion; Laville-Geay, Aude; Eupherte, Laure

2014-12-01

We compare the performance of various analytical retroreflecting bidirectional reflectance distribution function (BRDF) models to assess how they reproduce accurately measured data of retroreflecting materials. We introduce a new parametrization, the back vector parametrization, to analyze retroreflecting data, and we show that this parametrization better preserves the isotropy of data. Furthermore, we update existing BRDF models to improve the representation of retroreflective data.

Macromolecular surface design: photopatterning of functional stable nitrile oxides.

Science.gov (United States)

Altintas, Ozcan; Glassner, Mathias; Rodriguez-Emmenegger, Cesar; Welle, Alexander; Trouillet, Vanessa; Barner-Kowollik, Christopher

2015-05-04

The efficient trapping of photogenerated thioaldehydes with functional shelf-stable nitrile oxides in a 1,3-dipolar cycloaddition is a novel and versatile photochemical strategy for polymer end-group functionalization and surface modification under mild and equimolar conditions. The modular ligation in solution was followed in detail by electrospray ionization mass spectrometry (ESI-MS). X-ray photoelectron spectroscopy (XPS) was employed to analyze the functionalized surfaces, whereas time-of-flight secondary-ion mass spectrometry (ToF-SIMS) confirmed the spatial control of the surface functionalization using a micropatterned shadow mask. Polymer brushes were grown from the surface in a spatially confined regime by surface-initiated atom transfer radical polymerization (SI-ATRP) as confirmed by TOF-SIMS, XPS as well as ellipsometry. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

OMI/Aura Surface Reflectance Climatology Level 3 Global 0.5deg Lat/Lon Grid V003

Data.gov (United States)

National Aeronautics and Space Administration — The OMI Earth Surface Reflectance Climatology product, OMLER (Global 0.5deg Lat/Lon grid) which is based on Version 003 Level-1B top of atmosphere upwelling radiance...

The parental reflective functioning questionnaire: Development and preliminary validation

Science.gov (United States)

Luyten, Patrick; Mayes, Linda C.; Nijssens, Liesbet; Fonagy, Peter

2017-01-01

This paper reports on three studies on the development and validation of the Parental Reflective Functioning Questionnaire (PRFQ), a brief, multidimensional self-report measure that assesses parental reflective functioning or mentalizing, that is, the capacity to treat the infant as a psychological agent. Study 1 investigated the factor structure, reliability, and relationships of the PRFQ with demographic features, symptomatic distress, attachment dimensions, and emotional availability in a socially diverse sample of 299 mothers of a child aged 0–3. In Study 2, the factorial invariance of the PRFQ in mothers and fathers was investigated in a sample of 153 first-time parents, and relationships with demographic features, symptomatic distress, attachment dimensions, and parenting stress were investigated. Study 3 investigated the relationship between the PRFQ and infant attachment classification as assessed with the Strange Situation Procedure (SSP) in a sample of 136 community mothers and their infants. Exploratory and confirmatory factor analyses suggested three theoretically consistent factors assessing pre-mentalizing modes, certainty about the mental states of the infant, and interest and curiosity in the mental states of the infant. These factors were generally related in theoretically expected ways to parental attachment dimensions, emotional availability, parenting stress, and infant attachment status in the SSP. Yet, at the same time, more research on the PRFQ is needed to further establish its reliability and validity. PMID:28472162

Probing Surface-Adlayer Conjugation on Organic-Modified Si(111) Surfaces with Microscopy, Scattering, Spectroscopy, and Density Functional Theory

International Nuclear Information System (INIS)

Kellar, Joshua A.; Lin, Jui-Ching; Kim, Jun-Hyun; Yoder, Nathan L.; Bevan, Kirk H.; Stokes, Grace Y.; Geiger, Franz M.; Nguyen, SonBinh T.; Bedzyk, Michael J.; Hersam, Mark C.

2009-01-01

Highly conjugated molecules bound to silicon are promising candidates for organosilicon electronic devices and sensors. In this study, 1-bromo-4-ethynylbenzene was synthesized and reacted with a hydrogen-passivated Si(111) surface via ultraviolet irradiation. Through an array of characterization and modeling tools, the binding configuration and morphology of the reacted molecule were thoroughly analyzed. Atomic force microscopy confirmed an atomically flat surface morphology following reaction, while X-ray photoelectron spectroscopy verified reaction to the surface via the terminal alkyne moiety. In addition, synchrotron X-ray characterization, including X-ray reflectivity, X-ray fluorescence, and X-ray standing wave measurements, enabled sub-angstrom determination of the position of the bromine atom with respect to the silicon lattice. This structural characterization was quantitatively compared with density functional theory (DFT) calculations, thus enabling the π-conjugation of the terminal carbon atoms to be deduced. The X-ray and DFT results were additionally corroborated with the vibrational spectrum of the organic adlayer, which was measured with sum frequency generation. Overall, these results illustrate that the terminal carbon atoms in 1-bromo-4-ethynylbenzene adlayers on Si(111) retain π-conjugation, thus revealing alkyne molecules as promising candidates for organosilicon electronics and sensing.

Interpolation of magnetic surface functions for an axi-symmetric plasma

International Nuclear Information System (INIS)

Yamaguchi, Taiki; Maeyama, Mitsuaki

2000-01-01

Informations of the magnetic surface functions of magnetically confined plasma are indispensable for equilibrium, stability and transport analyses. In this paper, in order to identify a realistic surface functions and compare those with ones which are introduced from Taylor's relaxation theory, we propose a code to interpolate these surface functions for an axi-symmetric plasma from experimentally measured data. To confirm our code, we used the date which were analyzed from known functions given as a measured data. As a result, we have developed a code which can derive surface functions I and P. Effects of measurement error on those functions are also examined. (author)

Simulated BRDF based on measured surface topography of metal

Science.gov (United States)

Yang, Haiyue; Haist, Tobias; Gronle, Marc; Osten, Wolfgang

2017-06-01

The radiative reflective properties of a calibration standard rough surface were simulated by ray tracing and the Finite-difference time-domain (FDTD) method. The simulation results have been used to compute the reflectance distribution functions (BRDF) of metal surfaces and have been compared with experimental measurements. The experimental and simulated results are in good agreement.

A LAI inversion algorithm based on the unified model of canopy bidirectional reflectance distribution function for the Heihe River Basin

Science.gov (United States)

Ma, B.; Li, J.; Fan, W.; Ren, H.; Xu, X.

2017-12-01

Leaf area index (LAI) is one of the important parameters of vegetation canopy structure, which can represent the growth condition of vegetation effectively. The accuracy, availability and timeliness of LAI data can be improved greatly, which is of great importance to vegetation-related research, such as the study of atmospheric, land surface and hydrological processes to obtain LAI by remote sensing method. Heihe River Basin is the inland river basin in northwest China. There are various types of vegetation and all kinds of terrain conditions in the basin, so it is helpful for testing the accuracy of the model under the complex surface and evaluating the correctness of the model to study LAI in this area. On the other hand, located in west arid area of China, the ecological environment of Heihe Basin is fragile, LAI is an important parameter to represent the vegetation growth condition, and can help us understand the status of vegetation in the Heihe River Basin. Different from the previous LAI inversion models, the BRDF (bidirectional reflectance distribution function) unified model can be applied for both continuous vegetation and discrete vegetation, it is appropriate to the complex vegetation distribution. LAI is the key input parameter of the model. We establish the inversion algorithm that can exactly retrieve LAI using remote sensing image based on the unified model. First, we determine the vegetation type through the vegetation classification map to obtain the corresponding G function, leaf and surface reflectivity. Then, we need to determine the leaf area index (LAI), the aggregation index (ζ) and the sky scattered light ratio (β) range and the value of the interval, entering all the parameters into the model to calculate the corresponding reflectivity ρ and establish the lookup table of different vegetation. Finally, we can invert LAI on the basis of the established lookup table. The principle of inversion is least squares method. We have produced 1 km

Surface plasma functionalization influences macrophage behavior on carbon nanowalls

Energy Technology Data Exchange (ETDEWEB)

Ion, Raluca [University of Bucharest, Department of Biochemistry and Molecular Biology, 91-95 Spl. Independentei, 050095 Bucharest (Romania); Vizireanu, Sorin [National Institute for Laser, Plasma and Radiation Physics, 409 Atomistilor, PO Box MG-36, 077125, Magurele, Bucharest (Romania); Stancu, Claudia Elena [National Institute for Laser, Plasma and Radiation Physics, 409 Atomistilor, PO Box MG-36, 077125, Magurele, Bucharest (Romania); Leibniz Institute for Plasma Science and Technology (INP Greifswald), Felix-Hausdorff-Str. 2, 17489 Greifswald (Germany); Luculescu, Catalin [National Institute for Laser, Plasma and Radiation Physics, 409 Atomistilor, PO Box MG-36, 077125, Magurele, Bucharest (Romania); Cimpean, Anisoara, E-mail: anisoara.cimpean@bio.unibuc.ro [University of Bucharest, Department of Biochemistry and Molecular Biology, 91-95 Spl. Independentei, 050095 Bucharest (Romania); Dinescu, Gheorghe [National Institute for Laser, Plasma and Radiation Physics, 409 Atomistilor, PO Box MG-36, 077125, Magurele, Bucharest (Romania)

2015-03-01

The surfaces of carbon nanowall samples as scaffolds for tissue engineering applications were treated with oxygen or nitrogen plasma to improve their wettability and to functionalize their surfaces with different functional groups. X-ray photoelectron spectroscopy and water contact angle results illustrated the effective conversion of the carbon nanowall surfaces from hydrophobic to hydrophilic and the incorporation of various amounts of carbon, oxygen and nitrogen functional groups during the treatments. The early inflammatory responses elicited by un-treated and modified carbon nanowall surfaces were investigated by quantifying tumor necrosis factor-alpha and macrophage inflammatory protein-1 alpha released by attached RAW 264.7 macrophage cells. Scanning electron microscopy and fluorescence studies were employed to investigate the changes in macrophage morphology and adhesive properties, while MTT assay was used to quantify cell proliferation. All samples sustained macrophage adhesion and growth. In addition, nitrogen plasma treatment was more beneficial for cell adhesion in comparison with un-modified carbon nanowall surfaces. Instead, oxygen plasma functionalization led to increased macrophage adhesion and spreading suggesting a more activated phenotype, confirmed by elevated cytokine release. Thus, our findings showed that the chemical surface alterations which occur as a result of plasma treatment, independent of surface wettability, affect macrophage response in vitro. - Highlights: • N{sub 2} and O{sub 2} plasma treatments alter the CNW surface chemistry and wettability. • Cells seeded on CNW scaffolds are viable and metabolically active. • Surface functional groups, independent of surface wettability, affect cell response. • O{sub 2} plasma treatment of CNW leads to a more activated macrophage phenotype.

Shear-wave seismic reflection imaging and impedance inversion for a near-surface point-bar

Science.gov (United States)

Benton, N. W.; Morrison, M.; Lorenzo, J. M.; Odom, B.; Clift, P. D.; Olson, E.; Gostic, A.

2017-12-01

Imaging and inversion of SH-waves are useful to detect, map, and quantitatively characterize near-surface point-bar strata. We conduct a horizontally-polarized (SH) reflection survey across and along a near-surface (9 - 40 m) downstream point-bar. We invert for shear-impedance profiles and correlate our interpretation to electrical conductivity (EC) logs in adjacent wells to study the internal architecture and lithology of point-bars. We acquire two common-midpoint (CMP) SH-wave seismic reflection lines at False River (Point Coupee Parish, Louisiana). A 104 m long seismic line (L1) is oriented orthogonal (NW - SE) to point-bar strike. A second line (L2) is 48 m long and set parallel to point-bar strike (NE - SW). Two EC wells lie 33 m apart. Both wells are parallel with respect to the L1 survey and offset from it by 15 m. EC log measurements range from 1 - 25 m depth. Interference of Love-waves prevents seismic imaging at depths less than 9 m. The L1 and L2 data sets are inverted for shear-impedance using a model-based band-limited impedance (BLIMP) algorithm that incorporates a low-frequency velocity model. This model is also used for the depthing processing. The L1 cross-section shows coherent dipping reflection events ( 4 - 7º) from 0.15 - 0.35 s (10 - 40 m). The corresponding shear-impedance profile also reveals coherent and dipping impedance contrasts that grow in magnitude with increasing depth. The L2 cross-section shows comparatively less dip ( 1º) as well as sharper and shallower continuity of reflection events (0.1 - 0.28 s TWT or 9 - 25 m). Depth-converted (TVD) seismic amplitudes and impedance values correlate to near-surface point-bar geology via superposition of log data. The first well (W5) shows distinct EC local maxima (+50 - 70 mS/m) at 14.5 and 15.5 m depth that correlate well with the seismic amplitudes and impedance values from both L1 and L2 data sets. The second well (W7) shows comparatively lower local maxima (+40 - 60 mS/m) but at greater

Diamond surface functionalization with biomimicry - Amine surface tether and thiol moiety for electrochemical sensors

Science.gov (United States)

Sund, James B.; Causey, Corey P.; Wolter, Scott D.; Parker, Charles B.; Stoner, Brian R.; Toone, Eric J.; Glass, Jeffrey T.

2014-05-01

The surface of conducting diamond was functionalized with a terminal thiol group that is capable of binding and detecting nitrogen-oxygen species. The functionalization process employed multiple steps starting with doped diamond films grown by plasma enhanced chemical vapor deposition followed by hydrogen termination and photochemical attachment of a chemically protected amine alkene. The surface tether was deprotected to reveal the amine functionality, which enabled the tether to be extended with surface chemistry to add a terminal thiol moiety for electrochemical sensing applications. Each step of the process was validated using X-ray photoelectron spectroscopy analysis.

Simulation of reflectance from white-anodised aluminium surfaces using polyurethane–TiO2 composite coatings

DEFF Research Database (Denmark)

Gudla, Visweswara Chakravarthy; Johansen, Villads Egede; Ambat, Rajan

2015-01-01

of anodised surfaces. PU matrix was selected for its matching refractive-index (n = 1.7) with anodic alumina layer. Three different TiO2 particle size distributions were dispersed in PU and spin coated onto bright high-gloss and matte caustic-etched aluminium substrates. The reflectance spectra of coated...

Optimization of plasma mirror reflectivity and optical quality using double laser pulses

International Nuclear Information System (INIS)

Scott, G G; Clarke, R J; Green, J S; Heathcote, R I; Neely, D; Bagnoud, V; Brabetz, C; Zielbauer, B; Powell, H W; McKenna, P; Arber, T D

2015-01-01

We measure a record 96 ±2.5% specularly reflected energy fraction from an interaction with a plasma mirror (PM) surface preionized by a controlled prepulse and find that the optical quality is dependent on the inter pulse time delay. Simulations show that the main pulse reflected energy is a strong function of plasma density scale length, which increases with the time delay and reaches a peak reflectivity for a scale length of 0.3 μm, which is achieved here for a pulse separation time of 3 ps. It is found that the incident laser quasi near field intensity distribution leads to nonuniformities in this plasma expansion and consequent critical surface position distribution. The PM optical quality is found to be governed by the resultant perturbations in the critical surface position, which become larger with inter pulse time delay. (paper)

Reflected Sunlight Reduction and Characterization for a Deep-Space Optical Receiver Antenna (DSORA)

Science.gov (United States)

Clymer, B. D.

1990-01-01

A baffle system for the elimination of first-order specular and diffuse reflection of sunlight from the sunshade of a deep-space optical receiver telescope is presented. This baffle system consists of rings of 0.5cm blades spaced 2.5 cm apart on the walls of GO hexagonal sunshade tubes that combine to form the telescope sunshade. The shadow cast by the blades, walls, and rims of the tubes prevent all first-order reflections of direct sunlight from reaching the primary mirror of the telescope. A reflection model of the sunshade without baffles is also presented for comparison. Since manufacturers of absorbing surfaces do not measure data near grazing incidence, the reflection properties at anticipated angles of incidence must be characterized. A description of reflection from matte surfaces in term of bidirectional reflection distribution function (BRDF) is presented along with a discussion of measuring BRDF near grazing incidence.

Efective infrared reflectivity and dielectric function of polycrystalline alumina ceramics

Czech Academy of Sciences Publication Activity Database

Nuzhnyy, Dmitry; Petzelt, Jan; Borodavka, Fedir; Vaněk, Přemysl; Šimek, Daniel; Trunec, D.; Maca, K.

2017-01-01

Roč. 254, č. 5 (2017), s. 1-8, č. článku 1600607. ISSN 0370-1972 R&D Projects: GA ČR GA15-08389S Institutional support: RVO:68378271 Keywords : alumina * ceramics * effective dielectric function * effective medium approximation * geometrical resonances * infrared reflectivity Subject RIV: BM - Solid Matter Physics ; Magnetism OBOR OECD: Condensed matter physics (including formerly solid state physics, supercond.) Impact factor: 1.674, year: 2016

Final report for the project "Improving the understanding of surface-atmosphere radiative interactions by mapping surface reflectance over the ARM CART site" (award DE-FG02-02ER63351)

Energy Technology Data Exchange (ETDEWEB)

Alexander P. Trishchenko; Yi Luo; Konstantin V. Khlopenkov, William M. Park; Zhanqing Li; Maureen Cribb

2008-11-28

Surface spectral reflectance (albedo) is a fundamental variable affecting the transfer of solar radiation and the Earth’s climate. It determines the proportion of solar energy absorbed by the surface and reflected back to the atmosphere. The International Panel on Climate Change (IPCC) identified surface albedo among key factors influencing climate radiative forcing. Accurate knowledge of surface reflective properties is important for advancing weather forecasting and climate change impact studies. It is also important for determining radiative impact and acceptable levels of greenhouse gases in the atmosphere, which makes this work strongly linked to major scientific objectives of the Climate Change Research Division (CCRD) and Atmospheric Radiation Measurement (ARM) Program. Most significant accomplishments of eth project are listed below. I) Surface albedo/BRDF datasets from 1995 to the end of 2004 have been produced. They were made available to the ARM community and other interested users through the CCRS public ftp site ftp://ftp.ccrs.nrcan.gc.ca/ad/CCRS_ARM/ and ARM IOP data archive under “PI data Trishchenko”. II) Surface albedo properties over the ARM SGP area have been described for 10-year period. Comparison with ECMWF data product showed some deficiencies in the ECMWF surface scheme, such as missing some seasonal variability and no dependence on sky-conditions which biases surface energy budget and has some influence of the diurnal cycle of upward radiation and atmospheric absorption. III) Four surface albedo Intensive Observation Period (IOP) Field Campaigns have been conducted for every season (August, 2002, May 2003, February 2004 and October 2004). Data have been prepared, documented and transferred to ARM IOP archive. Nine peer-reviewed journal papers and 26 conference papers have been published.

Regional-Scale Surface Magnetic Fields and Proton Fluxes to Mercury's Surface from Proton-Reflection Magnetometry

Science.gov (United States)

Winslow, R. M.; Johnson, C. L.; Anderson, B. J.; Gershman, D. J.; Raines, J. M.; Lillis, R. J.; Korth, H.; Slavin, J. A.; Solomon, S. C.; Zurbuchen, T.

2014-12-01

The application of a recently developed proton-reflection magnetometry technique to MESSENGER spacecraft observations at Mercury has yielded two significant findings. First, loss-cone observations directly confirm particle precipitation to Mercury's surface and indicate that solar wind plasma persistently bombards the planet not only in the magnetic cusp regions but over a large fraction of the southern hemisphere. Second, the inferred surface field strengths independently confirm the north-south asymmetry in Mercury's global magnetic field structure first documented from observations of magnetic equator crossings. Here we extend this work with 1.5 additional years of observations (i.e., to 2.5 years in all) to further probe Mercury's surface magnetic field and better resolve proton flux precipitation to the planet's surface. We map regions where proton loss cones are observed; these maps indicate regions where protons precipitate directly onto the surface. The augmentation of our data set over that used in our original study allows us to examine the proton loss cones in cells of dimension 10° latitude by 20° longitude in Mercury body-fixed coordinates. We observe a transition from double-sided to single-sided loss cones in the pitch-angle distributions; this transition marks the boundary between open and closed field lines. At the surface this boundary lies between 60° and 70°N. Our observations allow the estimation of surface magnetic field strengths in the northern cusp region and the calculation of incident proton fluxes to both hemispheres. In the northern cusp, our regional-scale observations are consistent with an offset dipole field and a dipole moment of 190 nT RM3, where RM is Mercury's radius, implying that any regional-scale variations in surface magnetic field strengths are either weak relative to the dipole field or occur at length scales smaller than the resolution of our observations (~300 km). From the global proton flux map (north of 40° S

Generating Land Surface Reflectance for the New Generation of Geostationary Satellite Sensors with the MAIAC Algorithm

Science.gov (United States)

Wang, W.; Wang, Y.; Hashimoto, H.; Li, S.; Takenaka, H.; Higuchi, A.; Lyapustin, A.; Nemani, R. R.

2017-12-01

The latest generation of geostationary satellite sensors, including the GOES-16/ABI and the Himawari 8/AHI, provide exciting capability to monitor land surface at very high temporal resolutions (5-15 minute intervals) and with spatial and spectral characteristics that mimic the Earth Observing System flagship MODIS. However, geostationary data feature changing sun angles at constant view geometry, which is almost reciprocal to sun-synchronous observations. Such a challenge needs to be carefully addressed before one can exploit the full potential of the new sources of data. Here we take on this challenge with Multi-Angle Implementation of Atmospheric Correction (MAIAC) algorithm, recently developed for accurate and globally robust applications like the MODIS Collection 6 re-processing. MAIAC first grids the top-of-atmosphere measurements to a fixed grid so that the spectral and physical signatures of each grid cell are stacked ("remembered") over time and used to dramatically improve cloud/shadow/snow detection, which is by far the dominant error source in the remote sensing. It also exploits the changing sun-view geometry of the geostationary sensor to characterize surface BRDF with augmented angular resolution for accurate aerosol retrievals and atmospheric correction. The high temporal resolutions of the geostationary data indeed make the BRDF retrieval much simpler and more robust as compared with sun-synchronous sensors such as MODIS. As a prototype test for the geostationary-data processing pipeline on NASA Earth Exchange (GEONEX), we apply MAIAC to process 18 months of data from Himawari 8/AHI over Australia. We generate a suite of test results, including the input TOA reflectance and the output cloud mask, aerosol optical depth (AOD), and the atmospherically-corrected surface reflectance for a variety of geographic locations, terrain, and land cover types. Comparison with MODIS data indicates a general agreement between the retrieved surface reflectance

Automatic and improved radiometric correction of Landsat imagery using reference values from MODIS surface reflectance images

Science.gov (United States)

Pons, X.; Pesquer, L.; Cristóbal, J.; González-Guerrero, O.

2014-12-01

Radiometric correction is a prerequisite for generating high-quality scientific data, making it possible to discriminate between product artefacts and real changes in Earth processes as well as accurately produce land cover maps and detect changes. This work contributes to the automatic generation of surface reflectance products for Landsat satellite series. Surface reflectances are generated by a new approach developed from a previous simplified radiometric (atmospheric + topographic) correction model. The proposed model keeps the core of the old model (incidence angles and cast-shadows through a digital elevation model [DEM], Earth-Sun distance, etc.) and adds new characteristics to enhance and automatize ground reflectance retrieval. The new model includes the following new features: (1) A fitting model based on reference values from pseudoinvariant areas that have been automatically extracted from existing reflectance products (Terra MODIS MOD09GA) that were selected also automatically by applying quality criteria that include a geostatistical pattern model. This guarantees the consistency of the internal and external series, making it unnecessary to provide extra atmospheric data for the acquisition date and time, dark objects or dense vegetation. (2) A spatial model for atmospheric optical depth that uses detailed DEM and MODTRAN simulations. (3) It is designed so that large time-series of images can be processed automatically to produce consistent Landsat surface reflectance time-series. (4) The approach can handle most images, acquired now or in the past, regardless of the processing system, with the exception of those with extremely high cloud coverage. The new methodology has been successfully applied to a series of near 300 images of the same area including MSS, TM and ETM+ imagery as well as to different formats and processing systems (LPGS and NLAPS from the USGS; CEOS from ESA) for different degrees of cloud coverage (up to 60%) and SLC

A Methodology to Assess the Accuracy with which Remote Data Characterize a Specific Surface, as a Function of Full Width at Half Maximum (FWHM: Application to Three Italian Coastal Waters

Directory of Open Access Journals (Sweden)

Rosa Maria Cavalli

2014-01-01

Full Text Available This methodology assesses the accuracy with which remote data characterizes a surface, as a function of Full Width at Half Maximum (FWHM. The purpose is to identify the best remote data that improves the characterization of a surface, evaluating the number of bands in the spectral range. The first step creates an accurate dataset of remote simulated data, using in situ hyperspectral reflectances. The second step evaluates the capability of remote simulated data to characterize this surface. The spectral similarity measurements, which are obtained using classifiers, provide this capability. The third step examines the precision of this capability. The assumption is that in situ hyperspectral reflectances are considered the “real” reflectances. They are resized with the same spectral range of the remote data. The spectral similarity measurements which are obtained from “real” resized reflectances, are considered “real” measurements. Therefore, the quantity and magnitude of “errors” (i.e., differences between spectral similarity measurements obtained from “real” resized reflectances and from remote data provide the accuracy as a function of FWHM. This methodology was applied to evaluate the accuracy with which CHRIS-mode1, CHRIS-mode2, Landsat5-TM, MIVIS and PRISMA data characterize three coastal waters. Their mean values of uncertainty are 1.59%, 3.79%, 7.75%, 3.15% and 1.18%, respectively.

Application of the three-component bidirectional reflectance distribution function model to Monte Carlo calculation of spectral effective emissivities of nonisothermal blackbody cavities.

Science.gov (United States)

Prokhorov, Alexander; Prokhorova, Nina I

2012-11-20

We applied the bidirectional reflectance distribution function (BRDF) model consisting of diffuse, quasi-specular, and glossy components to the Monte Carlo modeling of spectral effective emissivities for nonisothermal cavities. A method for extension of a monochromatic three-component (3C) BRDF model to a continuous spectral range is proposed. The initial data for this method are the BRDFs measured in the plane of incidence at a single wavelength and several incidence angles and directional-hemispherical reflectance measured at one incidence angle within a finite spectral range. We proposed the Monte Carlo algorithm for calculation of spectral effective emissivities for nonisothermal cavities whose internal surface is described by the wavelength-dependent 3C BRDF model. The results obtained for a cylindroconical nonisothermal cavity are discussed and compared with results obtained using the conventional specular-diffuse model.

Determination of point of incidence for the case of reflection or refraction at spherical surface knowing two points lying on the ray.

Science.gov (United States)

Mikš, Antonín; Novák, Pavel

2017-09-01

The paper is focused on the problem of determination of the point of incidence of a light ray for the case of reflection or refraction at the spherical optical surface, assuming that two fixed points in space that the sought light ray should go through are given. The requirement is that one of these points lies on the incident ray and the other point on the reflected/refracted ray. Although at first glance it seems to be a simple problem, it will be shown that it has no simple analytical solution. The basic idea of the solution is given, and it is shown that the problem leads to a nonlinear equation in one variable. The roots of the resulting nonlinear equation can be found by numerical methods of mathematical optimization. The proposed methods were implemented in MATLAB, and the proper function of these algorithms was verified on several examples.

TOPICAL REVIEW: Vicinal surfaces for functional nanostructures

Science.gov (United States)

Tegenkamp, Christoph

2009-01-01

Vicinal surfaces are currently the focus of research. The regular arrangements of atomic steps on a mesoscopic scale reveal the possibility to functionalize these surfaces for technical applications, e.g. nanowires, catalysts, etc. The steps of the vicinal surface are well-defined defect structures of atomic size for nucleation of low-dimensional nanostructures. The concentration and therefore the coupling between the nanostructures can be tuned over a wide range by simply changing the inclination angle of the substrate. However, the coupling of these nano-objects to the substrate is just as important in controlling their electronic or chemical properties and making a functionality useable. On the basis of stepped insulating films, these aspects are fulfilled and will be considered in the first part of this review. Recent results for the epitaxial growth of wide bandgap insulating films (CaF2, MgO, NaCl, BaSrO) on metallic and semiconducting vicinal substrates (Si(100), Ge(100), Ag(100)) will be presented. The change of the electronic structure, the adsorption behavior as well as the kinetics and energetics of color centers in the presence of steps is discussed. The successful bridging of the gap between the atomic and mesoscopic world, i.e. the functionalization of vicinal surfaces by nanostructures, is demonstrated in the second part by metal adsorption on semiconducting surfaces. For (sub)monolayer coverage these systems have in common that the surface states do not hybridize with the support, i.e. the semiconducting surfaces are insulating. Here I will focus on the latest results of macroscopic transport measurements on Pb quantum wires grown on vicinal Si(111) showing indeed a one-dimensional transport behavior.

Altered functional connectivity during self- and close other-reflection in patients with bipolar disorder with past psychosis and patients with schizophrenia.

Science.gov (United States)

Zhang, Liwen; Vander Meer, Lisette; Opmeer, Esther M; Marsman, Jan-Bernard C; Ruhé, Henricus G; Aleman, André

2016-12-01

Disturbances in implicit self-processing have been reported both in psychotic patients with bipolar disorder (BD) and schizophrenia. It remains unclear whether these two psychotic disorders show disturbed functional connectivity during explicit self-reflection, which is associated with social functioning and illness symptoms. Therefore, we investigated functional connectivity during explicit self-reflection in BD with past psychosis and schizophrenia. Twenty-three BD-patients, 17 schizophrenia-patients and 21 health controls (HC) performed a self-reflection task, including the conditions self-reflection, close other-reflection and semantic control. Functional connectivity was investigated with generalized psycho-physiological interaction (gPPI). During self-reflection compared to semantic, BD-patients had decreased connectivity between several cortical-midline structures (CMS) nodes (i.e., anterior cingulate cortex, ventromedial prefrontal cortex), the insula and the head of the caudate while HC showed increased connectivities. Schizophrenia-patients, during close other-reflection compared to semantic, demonstrated reduced ventral-anterior insula-precuneus/posterior cingulate cortex (PCC) functional connectivity, whereas this was increased in HC. There were no differences between BD and schizophrenia during self- and close other-reflection. We propose that decreased functional connectivity between the CMS nodes/insula and head of the caudate in BD-patients may imply a reduced involvement of the motivational system during self-reflection; and the reduced functional connectivity between the ventral-anterior insula and precuneus/PCC during close other-reflection in schizophrenia-patients may subserve difficulties in information integration of autobiographical memory and emotional awareness in relation to close others. These distinctive impaired patterns of functional connectivity in BD and schizophrenia (compared to HC) deserve further investigation to determine their

Personality Is Reflected in the Brain's Intrinsic Functional Architecture

Science.gov (United States)

Adelstein, Jonathan S.; Shehzad, Zarrar; Mennes, Maarten; DeYoung, Colin G.; Zuo, Xi-Nian; Kelly, Clare; Margulies, Daniel S.; Bloomfield, Aaron; Gray, Jeremy R.; Castellanos, F. Xavier; Milham, Michael P.

2011-01-01

Personality describes persistent human behavioral responses to broad classes of environmental stimuli. Investigating how personality traits are reflected in the brain's functional architecture is challenging, in part due to the difficulty of designing appropriate task probes. Resting-state functional connectivity (RSFC) can detect intrinsic activation patterns without relying on any specific task. Here we use RSFC to investigate the neural correlates of the five-factor personality domains. Based on seed regions placed within two cognitive and affective ‘hubs’ in the brain—the anterior cingulate and precuneus—each domain of personality predicted RSFC with a unique pattern of brain regions. These patterns corresponded with functional subdivisions responsible for cognitive and affective processing such as motivation, empathy and future-oriented thinking. Neuroticism and Extraversion, the two most widely studied of the five constructs, predicted connectivity between seed regions and the dorsomedial prefrontal cortex and lateral paralimbic regions, respectively. These areas are associated with emotional regulation, self-evaluation and reward, consistent with the trait qualities. Personality traits were mostly associated with functional connections that were inconsistently present across participants. This suggests that although a fundamental, core functional architecture is preserved across individuals, variable connections outside of that core encompass the inter-individual differences in personality that motivate diverse responses. PMID:22140453

Personality is reflected in the brain's intrinsic functional architecture.

Directory of Open Access Journals (Sweden)

Jonathan S Adelstein

Full Text Available Personality describes persistent human behavioral responses to broad classes of environmental stimuli. Investigating how personality traits are reflected in the brain's functional architecture is challenging, in part due to the difficulty of designing appropriate task probes. Resting-state functional connectivity (RSFC can detect intrinsic activation patterns without relying on any specific task. Here we use RSFC to investigate the neural correlates of the five-factor personality domains. Based on seed regions placed within two cognitive and affective 'hubs' in the brain--the anterior cingulate and precuneus--each domain of personality predicted RSFC with a unique pattern of brain regions. These patterns corresponded with functional subdivisions responsible for cognitive and affective processing such as motivation, empathy and future-oriented thinking. Neuroticism and Extraversion, the two most widely studied of the five constructs, predicted connectivity between seed regions and the dorsomedial prefrontal cortex and lateral paralimbic regions, respectively. These areas are associated with emotional regulation, self-evaluation and reward, consistent with the trait qualities. Personality traits were mostly associated with functional connections that were inconsistently present across participants. This suggests that although a fundamental, core functional architecture is preserved across individuals, variable connections outside of that core encompass the inter-individual differences in personality that motivate diverse responses.

STUDY OF REFLECTION COEFFICIENT DISTRIBUTION FOR ANTI-REFLECTION COATINGS ON SMALL-RADIUS OPTICAL PARTS

Directory of Open Access Journals (Sweden)

L. A. Gubanova

2015-03-01

Full Text Available The paper deals with findings for the energy reflection coefficient distribution of anti- reflection coating along the surface of optical elements with a very small radius (2-12 mm. The factors influencing the magnitude of the surface area of the optical element, in which the energy reflection coefficient is constant, were detected. The main principles for theoretical models that describe the spectral characteristics of the multilayer interference coatings were used to achieve these objectives. The relative size of the enlightenment area is defined as the ratio of the radius for the optical element surface, where the reflection is less than a certain value, to its radius (ρ/r. The result of research is the following: this size is constant for a different value of the curvature radius for the optical element made of the same material. Its value is determined by the refractive index of material (nm, from which the optical element was made, and the design of antireflection coatings. For single-layer coatings this value is ρ/r = 0.5 when nm = 1.51; and ρ/r = 0.73 when nm = 1.75; for two-layer coatings ρ/r = 0.35 when nm = 1.51 and ρ/r = 0.41 when nm = 1.75. It is shown that with increasing of the material refractive index for the substrate size, the area of minimum reflection coefficient is increased. The paper considers a single-layer, two-layer, three-layer and five-layer structures of antireflection coatings. The findings give the possibility to conclude that equal thickness coverings formed on the optical element surface with a small radius make no equal reflection from the entire surface, and distribution of the layer thickness needs to be looked for, providing a uniform radiation reflection at all points of the spherical surface.

Simulation calculations of physical sputtering and reflection coefficient of plasma-irradiated carbon surface

International Nuclear Information System (INIS)

Kawamura, T.; Ono, T.; Yamamura, Y.

1994-08-01

Physical sputtering yields from the carbon surface irradiated by the boundary plasma are obtained with the use of a Monte Carlo simulation code ACAT. The yields are calculated for many random initial energy and angle values of incident protons or deuterons with a Maxwellian velocity distribution, and then averaged. Here the temperature of the boundary plasma, the sheath potential and the angle δ between the magnetic field line and the surface normal are taken into account. A new fitting formula for an arrangement of the numerical data of sputtering yield is introduced, in which six fitting parameters are determined from the numerical results and listed. These results provide a way to estimate the erosion of carbon materials irradiated by boundary plasma. The particle reflection coefficients for deuterons and their neutrals from a carbon surface are also calculated by the same code and presented together with, for comparison, that for the case of monoenergetic normal incidence. (author)

Mathematical Modeling of Radiant Heat Transfer in Mirror Systems Considering Deep Reflecting Surface Defects

Directory of Open Access Journals (Sweden)

V. V. Leonov

2014-01-01

Full Text Available When designing large-sized mirror concentrating systems (MCS for high-temperature solar power plants, one must have at disposal reasonably reliable and economical methods and tools, making it possible to analyze its characteristics, to predict them depending on the operation conditions and accordingly to choose the most suitable system for the solution of particular task.Experimental determination of MCS characteristics requires complicated and expensive experimentation, having significant limitations on interpretation of the results, as well as limitations imposed due to the size of the structure. Therefore it is of particular interest to develop a mathematical model capable of estimating power characteristics of MCS considering the influence of operating conditions, design features, roughness and other surface defects.For efficient solution of the tasks the model must ensure simulation of solar radiant flux as well as simulation of geometrical and optical characteristics of reflection surface and their interaction. In this connection a statistical mathematical model of radiation heat exchange based on use of Monte Carlo methods and Finite Element Method was developed and realized in the software complex, making it possible to determine main characteristics of the MCS.In this paper the main attention is given to definition of MCS radiation characteristics with account for deep reflecting surface defects (cavities, craters. Deep cavities are not typical for MCS, but their occurrence is possible during operation as a result of erosion or any physical damage. For example, for space technology it is primarily micrometeorite erosion.

Impact of dielectric parameters on the reflectivity of 3C–SiC wafers with a rough surface morphology in the reststrahlen region

International Nuclear Information System (INIS)

Engelbrecht, J.A.A.; Janzén, E.; Henry, A.; Rooyen, I.J. van

2014-01-01

A layer-on-substrate model is used to obtain the infrared reflectance for 3C–SiC with a rough surface morphology. The effect of varying dielectric parameters of the “damaged layer” on the observed reflectivity of the 3C–SiC in the reststrahlen region is assessed. Different simulated reflectance spectra are obtained to those if the dielectric parameters of the “substrate” were varied. Most notable changes in the shape of the simulated reststrahlen peak are observed for changes in the high frequency dielectric constant, the phonon damping constant, the phonon frequencies and “thickness” of damaged surface layer.

Impact of dielectric parameters on the reflectivity of 3C–SiC wafers with a rough surface morphology in the reststrahlen region

Energy Technology Data Exchange (ETDEWEB)

Engelbrecht, J.A.A., E-mail: Japie.Engelbrecht@nmmu.ac.za [Physics Department, Nelson Mandela Metropolitan University, PO Box 77000, Port Elizabeth 6031 (South Africa); Janzén, E.; Henry, A. [Department of Physics, Chemistry and Biology, Linköping University, SE-581 83 Linköping (Sweden); Rooyen, I.J. van [Fuel Performance and Design Department, Idaho National Laboratory, PO Box 1625, Idaho Falls, ID 83415-6188 (United States)

2014-04-15

A layer-on-substrate model is used to obtain the infrared reflectance for 3C–SiC with a rough surface morphology. The effect of varying dielectric parameters of the “damaged layer” on the observed reflectivity of the 3C–SiC in the reststrahlen region is assessed. Different simulated reflectance spectra are obtained to those if the dielectric parameters of the “substrate” were varied. Most notable changes in the shape of the simulated reststrahlen peak are observed for changes in the high frequency dielectric constant, the phonon damping constant, the phonon frequencies and “thickness” of damaged surface layer.

Identification of hydrogen and deuterium at the surface of water ice by reflection electron energy loss spectroscopy

International Nuclear Information System (INIS)

Yubero, F.; Toekesi, K.

2009-01-01

Complete text of publication follows. The study of elastically backscattered electrons from surfaces by reflection electron energy loss spectroscopy (REELS) has been recently recommended as an alternative technique to quantify the H content at the surface of a-C:H and polymer samples. This analysis is based on the fact that the energy loss of the incident electrons due to the recoil effect depends on the atomic mass of the particular atom present at the surface. The observed difference in recoil energies between H and O atoms (about 2 eV for 1.5 keV primary electrons) can be easily measured with standard electron spectrometers used in surface analysis. In this paper we go one step forward to explore if, with the same experimental approach, it is possible to differentiate between hydrogen and deuterium (D) in the surface region of a sample. This capability could be important for technological fields such as surface functionalization, where it is desired to distinguish between H and D at surfaces after interaction with labeled compounds. We have chosen normal and deuterated water as test labeled compounds because this polar molecule is of key importance in numerous surface reactions. It has been shown that H and D can be easily distinguished at the surface of water ice [4] using standard REELS measurements with 1000 - 1650 eV primary-electron energies, i.e., a surface analytical technique. Differences in recoil energies of the O - H and O - D atom pairs present in H 2 O and D 2 O have been found to agree with MC simulations (see Fig.1). There are many possible applications of H and D detection by REELS. Among many others, this study opens the possibility of nondestructive studies of deuterium-labeled atoms present or adsorbed on surfaces. For example, studies of H incorporation into a polymer or carbonbased surface after plasma activation with gas mixtures with several labeled molecules containing H atoms. Acknowledgements F.Y. thanks the Spanish Ministry of Science

Light reflection from a rough liquid surface including wind-wave effects in a scattering atmosphere

International Nuclear Information System (INIS)

Salinas, Santo V.; Liew, S.C.

2007-01-01

Visible and near-IR images of the ocean surface, taken from remote satellites, often contain important information of near-surface or sub-surface processes, which occur on, or over the ocean. Remote measurements of near surface winds, sea surface temperature and salinity, ocean color and underwater bathymetry, all, one way or another, depend on how well we understand sea surface roughness. However, in order to extract useful information from our remote measurements, we need to construct accurate models of the transfer of solar radiation inside the atmosphere as well as, its reflection from the sea surface. To approach this problem, we numerically solve the radiative transfer equation (RTE) by implementing a model for the atmosphere-ocean system. A one-dimensional atmospheric radiation model is solved via the widely known doubling and adding method and the ocean body is treated as a boundary condition to the problem. The ocean surface is modeled as a rough liquid surface which includes wind interaction and wave states, such as wave age. The model can have possible applications to the retrieval of wind and wave states, such as wave age, near a Sun glint region

Electrochemical characterization of organosilane-functionalized nanostructured ITO surfaces

Energy Technology Data Exchange (ETDEWEB)

Pruna, R., E-mail: rpruna@el.ub.edu; Palacio, F.; López, M. [SIC, Departament d' Enginyeries: Electrònica, Universitat de Barcelona, C/ Martí i Franquès 1, E-08028 Barcelona (Spain); Pérez, J. [Nanobioengineering Group, Institute for Bioengineering of Catalonia (IBEC), Baldiri Reixac 15-21, E-08028 Barcelona (Spain); Mir, M. [Nanobioengineering Group, Institute for Bioengineering of Catalonia (IBEC), Baldiri Reixac 15-21, E-08028 Barcelona (Spain); Centro de Investigación Biomédica en Red en Bioingeniería, Biomateriales y Nanomedicina (CIBER-BBN), Monforte de Lemos 3-5 Pabellón 11, E-28029 Madrid (Spain); Blázquez, O.; Hernández, S.; Garrido, B. [MIND-IN" 2UB, Departament d' Enginyeries: Electrònica, Universitat de Barcelona, C/ Martí i Franquès 1, E-08028 Barcelona (Spain)

2016-08-08

The electroactivity of nanostructured indium tin oxide (ITO) has been investigated for its further use in applications such as sensing biological compounds by the analysis of redox active molecules. ITO films were fabricated by using electron beam evaporation at different substrate temperatures and subsequently annealed for promoting their crystallization. The morphology of the deposited material was monitored by scanning electron microscopy, confirming the deposition of either thin films or nanowires, depending on the substrate temperature. Electrochemical surface characterization revealed a 45 % increase in the electroactive surface area of nanostructured ITO with respect to thin films, one third lower than the geometrical surface area variation determined by atomic force microscopy. ITO surfaces were functionalized with a model organic molecule known as 6-(ferrocenyl)hexanethiol. The chemical attachment was done by means of a glycidoxy compound containing a reactive epoxy group, the so-called 3-glycidoxypropyltrimethoxy-silane. ITO functionalization was useful for determining the benefits of nanostructuration on the surface coverage of active molecules. Compared to ITO thin films, an increase in the total peak height of 140 % was observed for as-deposited nanostructured electrodes, whereas the same measurement for annealed electrodes resulted in an increase of more than 400 %. These preliminary results demonstrate the ability of nanostructured ITO to increase the surface-to-volume ratio, conductivity and surface area functionalization, features that highly benefit the performance of biosensors.

Electrochemical characterization of organosilane-functionalized nanostructured ITO surfaces

International Nuclear Information System (INIS)

Pruna, R.; Palacio, F.; López, M.; Pérez, J.; Mir, M.; 2UB, Departament d'Enginyeries: Electrònica, Universitat de Barcelona, C/ Martí i Franquès 1, E-08028 Barcelona (Spain))" data-affiliation=" (MIND-IN2UB, Departament d'Enginyeries: Electrònica, Universitat de Barcelona, C/ Martí i Franquès 1, E-08028 Barcelona (Spain))" >Blázquez, O.; 2UB, Departament d'Enginyeries: Electrònica, Universitat de Barcelona, C/ Martí i Franquès 1, E-08028 Barcelona (Spain))" data-affiliation=" (MIND-IN2UB, Departament d'Enginyeries: Electrònica, Universitat de Barcelona, C/ Martí i Franquès 1, E-08028 Barcelona (Spain))" >Hernández, S.; 2UB, Departament d'Enginyeries: Electrònica, Universitat de Barcelona, C/ Martí i Franquès 1, E-08028 Barcelona (Spain))" data-affiliation=" (MIND-IN2UB, Departament d'Enginyeries: Electrònica, Universitat de Barcelona, C/ Martí i Franquès 1, E-08028 Barcelona (Spain))" >Garrido, B.

2016-01-01

The electroactivity of nanostructured indium tin oxide (ITO) has been investigated for its further use in applications such as sensing biological compounds by the analysis of redox active molecules. ITO films were fabricated by using electron beam evaporation at different substrate temperatures and subsequently annealed for promoting their crystallization. The morphology of the deposited material was monitored by scanning electron microscopy, confirming the deposition of either thin films or nanowires, depending on the substrate temperature. Electrochemical surface characterization revealed a 45 % increase in the electroactive surface area of nanostructured ITO with respect to thin films, one third lower than the geometrical surface area variation determined by atomic force microscopy. ITO surfaces were functionalized with a model organic molecule known as 6-(ferrocenyl)hexanethiol. The chemical attachment was done by means of a glycidoxy compound containing a reactive epoxy group, the so-called 3-glycidoxypropyltrimethoxy-silane. ITO functionalization was useful for determining the benefits of nanostructuration on the surface coverage of active molecules. Compared to ITO thin films, an increase in the total peak height of 140 % was observed for as-deposited nanostructured electrodes, whereas the same measurement for annealed electrodes resulted in an increase of more than 400 %. These preliminary results demonstrate the ability of nanostructured ITO to increase the surface-to-volume ratio, conductivity and surface area functionalization, features that highly benefit the performance of biosensors.

REX - a program for the analysis of X-ray reflectivity data: user guide and programmer manual

International Nuclear Information System (INIS)

Crabb, T.A.; Gibson, P.N.

1992-12-01

A FORTRAN program REX, which has been developed to facilitate the interpretation of X-ray reflectivity data, is described. The program allows the simulation of reflectivity profiles as a function of either incident angle or of energy. Factors such as anomalous dispersion, and surface and interface roughness are taken into account in the model. In addition, experimental data of reflectivity as a function of incident angle can be matched to user-supplied theoretical parameters by a least-squares refinement procedure. Experimental reflectivity data recorded at several X-ray wavelengths can be analysed simultaneously, thus eliminating certain experimental errors. (author)

Retrieval of reflections from ambient noise using illumination diagnosis

Science.gov (United States)

Vidal, C. Almagro; Draganov, D.; van der Neut, J.; Drijkoningen, G.; Wapenaar, K.

2014-09-01

Seismic interferometry (SI) enables the retrieval of virtual sources at the location of receivers. In the case of passive SI, no active sources are used for the retrieval of the reflection response of the subsurface, but ambient-noise recordings only. The resulting retrieved response is determined by the illumination characteristics of the recorded ambient noise. Characteristics like geometrical distribution and signature of the noise sources, together with the complexity of the medium and the length of the noise records, determine the quality of the retrieved virtual-shot events. To retrieve body wave reflections, one needs to correlate body-wave noise. A source of such noise might be regional seismicity. In regions with notable human presence, the dominant noise sources are generally located at or close to the surface. In the latter case, the noise will be dominated by surface waves and consequently also the retrieved virtual common-source panels will contain dominant retrieved surface waves, drowning out possible retrieved reflections. In order to retrieve reflection events, suppression of the surface waves becomes the most important pre-processing goal. Because of the reasons mentioned above, we propose a fast method to evaluate the illumination characteristics of ambient noise using the correlation results from ambient-noise records. The method is based on the analysis of the so-called source function of the retrieved virtual-shot panel, and evaluates the apparent slowness of arrivals in the correlation results that pass through the position of the virtual source and at zero time. The results of the diagnosis are used to suppress the retrieval of surface waves and therefore to improve the quality of the retrieved reflection response. We explain the approach using modelled data from transient and continuous noise sources and an example from a passive field data set recorded at Annerveen, Northern Netherlands.

Filtering Non-Linear Transfer Functions on Surfaces.

Science.gov (United States)

Heitz, Eric; Nowrouzezahrai, Derek; Poulin, Pierre; Neyret, Fabrice

2014-07-01

Applying non-linear transfer functions and look-up tables to procedural functions (such as noise), surface attributes, or even surface geometry are common strategies used to enhance visual detail. Their simplicity and ability to mimic a wide range of realistic appearances have led to their adoption in many rendering problems. As with any textured or geometric detail, proper filtering is needed to reduce aliasing when viewed across a range of distances, but accurate and efficient transfer function filtering remains an open problem for several reasons: transfer functions are complex and non-linear, especially when mapped through procedural noise and/or geometry-dependent functions, and the effects of perspective and masking further complicate the filtering over a pixel's footprint. We accurately solve this problem by computing and sampling from specialized filtering distributions on the fly, yielding very fast performance. We investigate the case where the transfer function to filter is a color map applied to (macroscale) surface textures (like noise), as well as color maps applied according to (microscale) geometric details. We introduce a novel representation of a (potentially modulated) color map's distribution over pixel footprints using Gaussian statistics and, in the more complex case of high-resolution color mapped microsurface details, our filtering is view- and light-dependent, and capable of correctly handling masking and occlusion effects. Our approach can be generalized to filter other physical-based rendering quantities. We propose an application to shading with irradiance environment maps over large terrains. Our framework is also compatible with the case of transfer functions used to warp surface geometry, as long as the transformations can be represented with Gaussian statistics, leading to proper view- and light-dependent filtering results. Our results match ground truth and our solution is well suited to real-time applications, requires only a few

Surface-functionalized nanoparticles for biosensing and imaging-guided therapeutics

Science.gov (United States)

Jiang, Shan; Win, Khin Yin; Liu, Shuhua; Teng, Choon Peng; Zheng, Yuangang; Han, Ming-Yong

2013-03-01

In this article, the very recent progress of various functional inorganic nanomaterials is reviewed including their unique properties, surface functionalization strategies, and applications in biosensing and imaging-guided therapeutics. The proper surface functionalization renders them with stability, biocompatibility and functionality in physiological environments, and further enables their targeted use in bioapplications after bioconjugation via selective and specific recognition. The surface-functionalized nanoprobes using the most actively studied nanoparticles (i.e., gold nanoparticles, quantum dots, upconversion nanoparticles, and magnetic nanoparticles) make them an excellent platform for a wide range of bioapplications. With more efforts in recent years, they have been widely developed as labeling probes to detect various biological species such as proteins, nucleic acids and ions, and extensively employed as imaging probes to guide therapeutics such as drug/gene delivery and photothermal/photodynamic therapy.

Kinetic-energy functionals studied by surface calculations

DEFF Research Database (Denmark)

Vitos, Levente; Skriver, Hans Lomholt; Kollár, J.

1998-01-01

The self-consistent jellium model of metal surfaces is used to study the accuracy of a number of semilocal kinetic-energy functionals for independent particles. It is shown that the poor accuracy exhibited by the gradient expansion approximation and most of the semiempirical functionals in the lo...... density, high gradient limit may be subtantially improved by including locally a von Weizsacker term. Based on this, we propose a simple one-parameter Pade's approximation, which reproduces the exact Kohn-Sham surface kinetic energy over the entire range of metallic densities....

From Intensity Profile to Surface Normal: Photometric Stereo for Unknown Light Sources and Isotropic Reflectances.

Science.gov (United States)

Lu, Feng; Matsushita, Yasuyuki; Sato, Imari; Okabe, Takahiro; Sato, Yoichi

2015-10-01

We propose an uncalibrated photometric stereo method that works with general and unknown isotropic reflectances. Our method uses a pixel intensity profile, which is a sequence of radiance intensities recorded at a pixel under unknown varying directional illumination. We show that for general isotropic materials and uniformly distributed light directions, the geodesic distance between intensity profiles is linearly related to the angular difference of their corresponding surface normals, and that the intensity distribution of the intensity profile reveals reflectance properties. Based on these observations, we develop two methods for surface normal estimation; one for a general setting that uses only the recorded intensity profiles, the other for the case where a BRDF database is available while the exact BRDF of the target scene is still unknown. Quantitative and qualitative evaluations are conducted using both synthetic and real-world scenes, which show the state-of-the-art accuracy of smaller than 10 degree without using reference data and 5 degree with reference data for all 100 materials in MERL database.

Influence of surface chemistry on the structural organization of monomolecular protein layers adsorbed to functionalized aqueous interfaces

DEFF Research Database (Denmark)

Lösche, M.; Piepenstock, M.; Diederich, A.

1993-01-01

The molecular organization of streptavidin (SA) bound to aqueous surface monolayers of biotin-functionalized lipids and binary lipid mixtures has been investigated with neutron reflectivity and electron and fluorescence microscopy. The substitution of deuterons (2H) for protons (1H), both...... in subphase water molecules and in the alkyl chains of the lipid surface monolayer, was utilized to determine the interface structure on the molecular length scale. In all cases studied, the protein forms monomolecular layers underneath the interface with thickness values of apprx 40 ANG . A systematic...... dependence of the structural properties of such self-assembled SA monolayers on the surface chemistry was observed: the lateral protein density depends on the length of the spacer connecting the biotin moiety and its hydrophobic anchor. The hydration of the lipid head groups in the protein-bound state...

Reconstruction of MODIS Spectral Reflectance under Cloudy-Sky Condition

Directory of Open Access Journals (Sweden)

Bo Gao

2016-09-01

Full Text Available Clouds usually cause invalid observations for sensors aboard satellites, which corrupts the spatio-temporal continuity of land surface parameters retrieved from remote sensing data (e.g., MODerate Resolution Imaging Spectroradiometer (MODIS data and prevents the fusing of multi-source remote sensing data in the field of quantitative remote sensing. Based on the requirements of spatio-temporal continuity and the necessity of methods to restore bad pixels, primarily resulting from image processing, this study developed a novel method to derive the spectral reflectance for MODIS band of cloudy pixels in the visual–near infrared (VIS–NIR spectral channel based on the Bidirectional Reflectance Distribution Function (BRDF and multi-spatio-temporal observations. The proposed method first constructs the spatial distribution of land surface reflectance based on the corresponding BRDF and the solar-viewing geometry; then, a geographically weighted regression (GWR is introduced to individually derive the spectral surface reflectance for MODIS band of cloudy pixels. A validation of the proposed method shows that a total root-mean-square error (RMSE of less than 6% and a total R2 of more than 90% are detected, which indicates considerably better precision than those exhibited by other existing methods. Further validation of the retrieved white-sky albedo based on the spectral reflectance for MODIS band of cloudy pixels confirms an RMSE of 3.6% and a bias of 2.2%, demonstrating very high accuracy of the proposed method.

Do seedling functional groups reflect ecological strategies of woody plant species in Caatinga?

Directory of Open Access Journals (Sweden)

Tatiane Gomes Calaça Menezes

2017-11-01

Full Text Available ABSTRACT It is assumed that morphological traits of seedlings reflect different strategies in response to environmental conditions. The ecological significance of this has been widely documented in rainforests, where habitat structure and species interactions play an important role in community assembly. However, in seasonally dry ecosystems, where environmental filtering is expected to strongly influence community structure, this relationship is poorly understood. We investigated this relationship between functional groups of seedlings and life history traits and tested whether functional group predicts the ecological strategies employed by woody species to deal with the stressful conditions in seasonally dry ecosystems. Seedling functional groups, life history traits and traits that reflect ecological strategies for occupying seasonally dry environments were described for twenty-six plant species. Seedlings of species from the Caatinga vegetation exhibited a functional profile different from that observed in rainforests ecosystems. Phanerocotylar-epigeal seedlings were the most frequently observed groups, and had the largest range of ecological strategies related to dealing with seasonally dry environments, while phanerocotylar-hypogeal-reserve seedlings exhibited an increase in frequency with seasonality. We discuss these results in relation to those observed in other tropical forests and their ecological significance in seasonally dry environments.

Surface structure and properties of functionalized nanodiamonds: a first-principles study

International Nuclear Information System (INIS)

Datta, Aditi; Kirca, Mesut; Fu Yao; To, Albert C

2011-01-01

The goal of this work is to gain fundamental understanding of the surface and internal structure of functionalized detonation nanodiamonds (NDs) using quantum mechanics based density functional theory (DFT) calculations. The unique structure of ND assists in the binding of different functional groups to its surface which in turn facilitates binding with drug molecules. The ability to comprehensively model the surface properties, as well as drug-ND interactions during functionalization, is a challenge and is the problem of our interest. First, the structure of NDs of technologically relevant size (∼5 nm) was optimized using classical mechanics based molecular mechanics simulations. Quantum mechanics based density functional theory (DFT) was then employed to analyse the properties of smaller relevant parts of the optimized cluster further to address the effect of functionalization on the stability of the cluster and reactivity at its surface. It is found that functionalization is preferred over reconstruction at the (100) surface and promotes graphitization in the (111) surface for NDs functionalized with the carbonyl oxygen (C = O) group. It is also seen that the edges of ND are the preferred sites for functionalization with the carboxyl group (-COOH) vis-a-vis the corners of ND.

Surface structure and properties of functionalized nanodiamonds: a first-principles study

Energy Technology Data Exchange (ETDEWEB)

Datta, Aditi; Kirca, Mesut; Fu Yao; To, Albert C, E-mail: albertto@pitt.edu [Department of Mechanical Engineering and Materials Science and Department of Civil and Environmental Engineering, University of Pittsburgh, Pittsburgh, PA 15261 (United States)

2011-02-11

The goal of this work is to gain fundamental understanding of the surface and internal structure of functionalized detonation nanodiamonds (NDs) using quantum mechanics based density functional theory (DFT) calculations. The unique structure of ND assists in the binding of different functional groups to its surface which in turn facilitates binding with drug molecules. The ability to comprehensively model the surface properties, as well as drug-ND interactions during functionalization, is a challenge and is the problem of our interest. First, the structure of NDs of technologically relevant size ({approx}5 nm) was optimized using classical mechanics based molecular mechanics simulations. Quantum mechanics based density functional theory (DFT) was then employed to analyse the properties of smaller relevant parts of the optimized cluster further to address the effect of functionalization on the stability of the cluster and reactivity at its surface. It is found that functionalization is preferred over reconstruction at the (100) surface and promotes graphitization in the (111) surface for NDs functionalized with the carbonyl oxygen (C = O) group. It is also seen that the edges of ND are the preferred sites for functionalization with the carboxyl group (-COOH) vis-a-vis the corners of ND.

Molecular recognition on a cavitand-functionalized silicon surface.

Science.gov (United States)

Biavardi, Elisa; Favazza, Maria; Motta, Alessandro; Fragalà, Ignazio L; Massera, Chiara; Prodi, Luca; Montalti, Marco; Melegari, Monica; Condorelli, Guglielmo G; Dalcanale, Enrico

2009-06-03

A Si(100) surface featuring molecular recognition properties was obtained by covalent functionalization with a tetraphosphonate cavitand (Tiiii), able to complex positively charged species. Tiiii cavitand was grafted onto the Si by photochemical hydrosilylation together with 1-octene as a spatial spectator. The recognition properties of the Si-Tiiii surface were demonstrated through two independent analytical techniques, namely XPS and fluorescence spectroscopy, during the course of reversible complexation-guest exchange-decomplexation cycles with specifically designed ammonium and pyridinium salts. Control experiments employing a Si(100) surface functionalized with a structurally similar, but complexation inactive, tetrathiophosphonate cavitand (TSiiii) demonstrated no recognition events. This provides evidence for the complexation properties of the Si-Tiiii surface, ruling out the possibility of nonspecific interactions between the substrate and the guests. The residual Si-O(-) terminations on the surface replace the guests' original counterions, thus stabilizing the complex ion pairs. These results represent a further step toward the control of self-assembly of complex supramolecular architectures on surfaces.

Recommended values of clean metal surface work functions

International Nuclear Information System (INIS)

Derry, Gregory N.; Kern, Megan E.; Worth, Eli H.

2015-01-01

A critical review of the experimental literature for measurements of the work functions of clean metal surfaces of single-crystals is presented. The tables presented include all results found for low-index crystal faces except cases that were known to be contaminated surfaces. These results are used to construct a recommended value of the work function for each surface examined, along with an uncertainty estimate for that value. The uncertainties are based in part on the error distribution for all measured work functions in the literature, which is included here. The metals included in this review are silver (Ag), aluminum (Al), gold (Au), copper (Cu), iron (Fe), iridium (Ir), molybdenum (Mo), niobium (Nb), nickel (Ni), palladium (Pd), platinum (Pt), rhodium (Rh), ruthenium (Ru), tantalum (Ta), and tungsten (W)

Recommended values of clean metal surface work functions

Energy Technology Data Exchange (ETDEWEB)

Derry, Gregory N., E-mail: gderry@loyola.edu; Kern, Megan E.; Worth, Eli H. [Department of Physics, Loyola University Maryland, 4501 N. Charles St., Baltimore, Maryland 21210 (United States)

2015-11-15

A critical review of the experimental literature for measurements of the work functions of clean metal surfaces of single-crystals is presented. The tables presented include all results found for low-index crystal faces except cases that were known to be contaminated surfaces. These results are used to construct a recommended value of the work function for each surface examined, along with an uncertainty estimate for that value. The uncertainties are based in part on the error distribution for all measured work functions in the literature, which is included here. The metals included in this review are silver (Ag), aluminum (Al), gold (Au), copper (Cu), iron (Fe), iridium (Ir), molybdenum (Mo), niobium (Nb), nickel (Ni), palladium (Pd), platinum (Pt), rhodium (Rh), ruthenium (Ru), tantalum (Ta), and tungsten (W)

Virtual-stereo fringe reflection technique for specular free-form surface testing

Science.gov (United States)

Ma, Suodong; Li, Bo

2016-11-01

Due to their excellent ability to improve the performance of optical systems, free-form optics have attracted extensive interest in many fields, e.g. optical design of astronomical telescopes, laser beam expanders, spectral imagers, etc. However, compared with traditional simple ones, testing for such kind of optics is usually more complex and difficult which has been being a big barrier for the manufacture and the application of these optics. Fortunately, owing to the rapid development of electronic devices and computer vision technology, fringe reflection technique (FRT) with advantages of simple system structure, high measurement accuracy and large dynamic range is becoming a powerful tool for specular free-form surface testing. In order to obtain absolute surface shape distributions of test objects, two or more cameras are often required in the conventional FRT which makes the system structure more complex and the measurement cost much higher. Furthermore, high precision synchronization between each camera is also a troublesome issue. To overcome the aforementioned drawback, a virtual-stereo FRT for specular free-form surface testing is put forward in this paper. It is able to achieve absolute profiles with the help of only one single biprism and a camera meanwhile avoiding the problems of stereo FRT based on binocular or multi-ocular cameras. Preliminary experimental results demonstrate the feasibility of the proposed technique.

Stable functionalization of germanium surface and its application in biomolecules immobilization

Energy Technology Data Exchange (ETDEWEB)

Cai, Qi [State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, No.865, Changning Road, Shanghai 200050 (China); University of Chinese Academy of Sciences, No.19A, Yuquan Road, Beijing 100049 (China); Xu, Baojian [State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, No.865, Changning Road, Shanghai 200050 (China); Ye, Lin [Sate Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, No.865, Changning Road, Shanghai 200050 (China); University of Chinese Academy of Sciences, No.19A, Yuquan Road, Beijing 100049 (China); Tang, Teng; Huang, Shanluo; Du, Xiaowei [State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, No.865, Changning Road, Shanghai 200050 (China); University of Chinese Academy of Sciences, No.19A, Yuquan Road, Beijing 100049 (China); Bian, Xiaojun; Zhang, Jishen [State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, No.865, Changning Road, Shanghai 200050 (China); Di, Zengfeng, E-mail: zfdi@mail.sim.ac.cn [Sate Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, No.865, Changning Road, Shanghai 200050 (China); Jin, Qinghui [State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, No.865, Changning Road, Shanghai 200050 (China); Zhao, Jianlong, E-mail: jlzhao@mail.sim.ac.cn [State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, No.865, Changning Road, Shanghai 200050 (China)

2014-10-15

Highlights: • An effective method to immobilize biomolecules on the functionalized Ge surface. • The surface of Ge was functionalized with 11-Mercaptoundecanoic acid (11-MUA). • Stable and uniform SAMs was obtained on Ge surface after 11-MUA treatment. • The functionalized Ge was employed as substrate for protein immobilization. • Paving the way of Ge for further applications in bioelectronics field. - Abstract: As a typical semiconductor material, germanium (Ge) has the potential to be utilized in microelectronics and bioelectronics. Herein, we present a simple and effective method to immobilize biomolecules on the surface of functionalized Ge. The surface oxide of Ge was removed with the pretreatment of hydrochloric acid and the Cl-terminated Ge reacted with 11-Mercaptoundecanoic acid (11-MUA). The surface of Ge was coated with 11-MUA self-assembled monolayers (SAMs) due to the bonding reaction between the sulfhydryl group of 11-MUA and Cl-terminated Ge. Furthermore, typical biomolecule, a green fluorescent protein was chosen to be immobilized on the surface of the functionalized Ge. Contact angle analysis, atomic force microscopy and X-ray photoelectron spectroscopy were used to study the characteristics including wettability, stability, roughness and component of the functionalized Ge, respectively. Fluorescence microscopy was utilized to indicate the efficiency of protein immobilization on the surface of the functionalized Ge. With these studies, stable and uniform functionalized monolayer was obtained on the surface of Ge after 11-MUA treatment and the functionalized Ge was effectively applied in protein immobilization. Furthermore, this study may pave the way for further applications such as the integration of bioelectronics and biosensors with the attractive semiconductor material-Ge in future work.

Surface functionalization of aluminosilicate nanotubes with organic molecules

Directory of Open Access Journals (Sweden)

Wei Ma

2012-02-01

Full Text Available The surface functionalization of inorganic nanostructures is an effective approach for enriching the potential applications of existing nanomaterials. Inorganic nanotubes attract great research interest due to their one-dimensional structure and reactive surfaces. In this review paper, recent developments in surface functionalization of an aluminosilicate nanotube, “imogolite”, are introduced. The functionalization processes are based on the robust affinity between phosphate groups of organic molecules and the aluminol (AlOH surface of imogolite nanotubes. An aqueous modification process employing a water soluble ammonium salt of alkyl phosphate led to chemisorption of molecules on imogolite at the nanotube level. Polymer-chain-grafted imogolite nanotubes were prepared through surface-initiated polymerization. In addition, the assembly of conjugated molecules, 2-(5’’-hexyl-2,2’:5’,2’’-terthiophen-5-ylethylphosphonic acid (HT3P and 2-(5’’-hexyl-2,2’:5’,2’’-terthiophen-5-ylethylphosphonic acid 1,1-dioxide (HT3OP, on the imogolite nanotube surface was achieved by introducing a phosphonic acid group to the corresponding molecules. The optical and photophysical properties of these conjugated-molecule-decorated imogolite nanotubes were characterized. Moreover, poly(3-hexylthiophene (P3HT chains were further hybridized with HT3P modified imogolite to form a nanofiber hybrid.

Minimal models on Riemann surfaces: The partition functions

International Nuclear Information System (INIS)

Foda, O.

1990-01-01

The Coulomb gas representation of the A n series of c=1-6/[m(m+1)], m≥3, minimal models is extended to compact Riemann surfaces of genus g>1. An integral representation of the partition functions, for any m and g is obtained as the difference of two gaussian correlation functions of a background charge, (background charge on sphere) x (1-g), and screening charges integrated over the surface. The coupling constant x (compacitification radius) 2 of the gaussian expressions are, as on the torus, m(m+1), and m/(m+1). The partition functions obtained are modular invariant, have the correct conformal anomaly and - restricting the propagation of states to a single handle - one can verify explicitly the decoupling of the null states. On the other hand, they are given in terms of coupled surface integrals, and it remains to show how they degenerate consistently to those on lower-genus surfaces. In this work, this is clear only at the lattice level, where no screening charges appear. (orig.)

Minimal models on Riemann surfaces: The partition functions

Energy Technology Data Exchange (ETDEWEB)

Foda, O. (Katholieke Univ. Nijmegen (Netherlands). Inst. voor Theoretische Fysica)

1990-06-04

The Coulomb gas representation of the A{sub n} series of c=1-6/(m(m+1)), m{ge}3, minimal models is extended to compact Riemann surfaces of genus g>1. An integral representation of the partition functions, for any m and g is obtained as the difference of two gaussian correlation functions of a background charge, (background charge on sphere) x (1-g), and screening charges integrated over the surface. The coupling constant x (compacitification radius){sup 2} of the gaussian expressions are, as on the torus, m(m+1), and m/(m+1). The partition functions obtained are modular invariant, have the correct conformal anomaly and - restricting the propagation of states to a single handle - one can verify explicitly the decoupling of the null states. On the other hand, they are given in terms of coupled surface integrals, and it remains to show how they degenerate consistently to those on lower-genus surfaces. In this work, this is clear only at the lattice level, where no screening charges appear. (orig.).

Study on the cloud detection of GOCI by using the simulated surface reflectance from BRDF-model for the land application and meteorological utilization

Science.gov (United States)

Kim, Hye-Won; Yeom, Jong-Min; Woo, Sun-Hee; Chae, Tae-Byeong

2016-04-01

COMS (Communication, Ocean, and Meteorological Satellite) was launched at French Guiana Kourou space center on 27 June 2010. Geostationary Ocean Color Imager (GOCI), which is the first ocean color geostationary satellite in the world for observing the ocean phenomena, is able to obtain the scientific data per an hour from 00UTC to 07UTC. Moreover, the spectral channels of GOCI would enable not only monitoring for the ocean, but for extracting the information of the land surface over the Korean Peninsula, Japan, and Eastern China. Since it is extremely important to utilize GOCI data accurately for the land application, cloud pixels over the surface have to be removed. Unfortunately, infra-red (IR) channels that can easily detect the water vapor with the cloud top temperature, are not included in the GOCI sensor. In this paper, the advanced cloud masking algorithm will be proposed with visible and near-IR (NIR) bands that are within GOCI bands. The main obstacle of cloud masking with GOCI is how to handle the high variable surface reflectance, which is mainly depending on the solar zenith angle. In this study, we use semi-empirical BRDF model to simulate the surface reflectance by using 16 day composite cloudy free image. When estimating the simulated surface reflectance, same geometry for GOCI observation was applied. The simulated surface reflectance is used to discriminate cloud areas especially for the thin cloud and shows more reasonable result than original threshold methods.

Adjustment of Sentinel-2 Multi-Spectral Instrument (MSI) Red-Edge Band Reflectance to Nadir BRDF Adjusted Reflectance (NBAR) and Quantification of Red-Edge Band BRDF Effects

OpenAIRE

David P. Roy; Zhongbin Li; Hankui K. Zhang

2017-01-01

Optical wavelength satellite data have directional reflectance effects over non-Lambertian surfaces, described by the bidirectional reflectance distribution function (BRDF). The Sentinel-2 multi-spectral instrument (MSI) acquires data over a 20.6° field of view that have been shown to have non-negligible BRDF effects in the visible, near-infrared, and short wave infrared bands. MSI red-edge BRDF effects have not been investigated. In this study, they are quantified by an examination of 6.6 mi...

Derivation of Coefficients for the Bidirectional Reflection Distribution Function from AVHRR-data over Europe, under Consideration of the Helmholtz Reciprocity Law

Science.gov (United States)

Billing, H.; Koslowsky, D.

In the AVHRR data of the polar orbiting NOAA Satellites, directional reflectance under a certain view from satellite and a certain illumination by the sun is measured. Due to the nearly sunsynchroneous orbit of the NOAA satellite, each area is seen under different viewing angles in successive days. Only after approximately 9 days, the conditions are again similar. Areas, seen in specular direction, may appear only half as bright, as if seen in antispecular direction. This deviation from a Lambertian reflector is a function of the surface roughness and the degree of coverage with vegetation. The NOAA afternoon satellites drift by half an hour from year to year. Thus even data from the same season, but different years, are seen under different illumination conditions. To derive the bidirectional reflection distribution function in dependence on satellite viewing angle and solar illumination becomes a very complicated procedure. Using the Helmholtz reciprocity principle (HRP), i.e. the symetrie in viewing and illumination, reduces the problem by one dimension. For different bidimensional reflection laws it will be tested, whether they can be formulated to fullfill the HRP. Via regression, the parameters will be deduced for time series of AVHRR data of 10 years from NOAA 11,14,16 and 17. Brdfunctions, suggested by Rao as well as a law, suggested by Ba seem to become unstable for low sun resp. large viewing zenit angles. Only brdfs with 4 coefficients can fit the observed distributions. A nonlinear temporal angular model (NTAM), suggested by Latifovic,Cihlar and Chen, seems to be suitable to describe even the hot spot and the dependence on plant growth. The coefficients of these brdf-function will be derived via regression for monthly series of cloud free data for the European area, where AVHRR data in full resolution are received in Berlin. Using these coefficients, monthly maps of surface roughness are produced for the above area for the time since 1985. Ba, M

A Kind of Nanofluid Consisting of Surface-Functionalized Nanoparticles

Directory of Open Access Journals (Sweden)

Yang Xuefei

2010-01-01

Full Text Available Abstract A method of surface functionalization of silica nanoparticles was used to prepare a kind of stable nanofluid. The functionalization was achieved by grafting silanes directly to the surface of silica nanoparticles in silica solutions (both a commercial solution and a self-made silica solution were used. The functionalized nanoparticles were used to make nanofluids, in which well-dispersed nanoparticles can keep good stability. One of the unique characteristics of the nanofluids is that no deposition layer forms on the heated surface after a pool boiling process. The nanofluids have applicable prospect in thermal engineering fields with the phase-change heat transfer.

Classification of reflected signals from cavitated tooth surfaces using an artificial intelligence technique incorporating a fiber optic displacement sensor

Science.gov (United States)

Rahman, Husna Abdul; Harun, Sulaiman Wadi; Arof, Hamzah; Irawati, Ninik; Musirin, Ismail; Ibrahim, Fatimah; Ahmad, Harith

2014-05-01

An enhanced dental cavity diameter measurement mechanism using an intensity-modulated fiber optic displacement sensor (FODS) scanning and imaging system, fuzzy logic as well as a single-layer perceptron (SLP) neural network, is presented. The SLP network was employed for the classification of the reflected signals, which were obtained from the surfaces of teeth samples and captured using FODS. Two features were used for the classification of the reflected signals with one of them being the output of a fuzzy logic. The test results showed that the combined fuzzy logic and SLP network methodology contributed to a 100% classification accuracy of the network. The high-classification accuracy significantly demonstrates the suitability of the proposed features and classification using SLP networks for classifying the reflected signals from teeth surfaces, enabling the sensor to accurately measure small diameters of tooth cavity of up to 0.6 mm. The method remains simple enough to allow its easy integration in existing dental restoration support systems.

Surface reflectance drives nest box temperature profiles and thermal suitability for target wildlife.

Directory of Open Access Journals (Sweden)

Stephen R Griffiths

Full Text Available Thermal properties of tree hollows play a major role in survival and reproduction of hollow-dependent fauna. Artificial hollows (nest boxes are increasingly being used to supplement the loss of natural hollows; however, the factors that drive nest box thermal profiles have received surprisingly little attention. We investigated how differences in surface reflectance influenced temperature profiles of nest boxes painted three different colors (dark-green, light-green, and white: total solar reflectance 5.9%, 64.4%, and 90.3% respectively using boxes designed for three groups of mammals: insectivorous bats, marsupial gliders and brushtail possums. Across the three different box designs, dark-green (low reflectance boxes experienced the highest average and maximum daytime temperatures, had the greatest magnitude of variation in daytime temperatures within the box, and were consistently substantially warmer than light-green boxes (medium reflectance, white boxes (high reflectance, and ambient air temperatures. Results from biophysical model simulations demonstrated that variation in diurnal temperature profiles generated by painting boxes either high or low reflectance colors could have significant ecophysiological consequences for animals occupying boxes, with animals in dark-green boxes at high risk of acute heat-stress and dehydration during extreme heat events. Conversely in cold weather, our modelling indicated that there are higher cumulative energy costs for mammals, particularly smaller animals, occupying light-green boxes. Given their widespread use as a conservation tool, we suggest that before boxes are installed, consideration should be given to the effect of color on nest box temperature profiles, and the resultant thermal suitability of boxes for wildlife, particularly during extremes in weather. Managers of nest box programs should consider using several different colors and installing boxes across a range of both orientations and

Modeling the bidirectional reflectance distribution function of mixed finite plant canopies and soil

Science.gov (United States)

Schluessel, G.; Dickinson, R. E.; Privette, J. L.; Emery, W. J.; Kokaly, R.

1994-01-01

An analytical model of the bidirectional reflectance for optically semi-infinite plant canopies has been extended to describe the reflectance of finite depth canopies contributions from the underlying soil. The model depends on 10 independent parameters describing vegetation and soil optical and structural properties. The model is inverted with a nonlinear minimization routine using directional reflectance data for lawn (leaf area index (LAI) is equal to 9.9), soybeans (LAI, 2.9) and simulated reflectance data (LAI, 1.0) from a numerical bidirectional reflectance distribution function (BRDF) model (Myneni et al., 1988). While the ten-parameter model results in relatively low rms differences for the BRDF, most of the retrieved parameters exhibit poor stability. The most stable parameter was the single-scattering albedo of the vegetation. Canopy albedo could be derived with an accuracy of less than 5% relative error in the visible and less than 1% in the near-infrared. Sensitivity were performed to determine which of the 10 parameters were most important and to assess the effects of Gaussian noise on the parameter retrievals. Out of the 10 parameters, three were identified which described most of the BRDF variability. At low LAI values the most influential parameters were the single-scattering albedos (both soil and vegetation) and LAI, while at higher LAI values (greater than 2.5) these shifted to the two scattering phase function parameters for vegetation and the single-scattering albedo of the vegetation. The three-parameter model, formed by fixing the seven least significant parameters, gave higher rms values but was less sensitive to noise in the BRDF than the full ten-parameter model. A full hemispherical reflectance data set for lawn was then interpolated to yield BRDF values corresponding to advanced very high resolution radiometer (AVHRR) scan geometries collected over a period of nine days. The resulting parameters and BRDFs are similar to those for the

The role of coherence of mind and reflective functioning in understanding binge-eating disorder and co-morbid overweight.

Science.gov (United States)

Maxwell, Hilary; Tasca, Giorgio A; Grenon, Renee; Faye, Megan; Ritchie, Kerri; Bissada, Hany; Balfour, Louise

2017-08-01

Coherence of mind and reflective functioning may impact negative affect and interpersonal functioning over and above the effects of symptoms of depression and interpersonal problems that contribute to symptoms of binge-eating disorder (BED) and overweight/obesity. Matched samples of overweight women with BED and overweight and normal weight women without BED completed the Adult Attachment Interview, a measure of depressive symptoms, and a measure of interpersonal problems. Greater symptoms of depression distinguished women with BED from the matched comparison samples. Greater interpersonal problems differentiated women with BED from overweight women without BED. Coherence of Mind scores did not differentiate the samples. However, lower Reflective Functioning scores did distinguish both women with BED and overweight women without BED from normal weight women. Lower reflective functioning may lead to binge eating independent of depressive symptoms and interpersonal problems.

Biodegradation improvement of poly(3-hydroxy-butyrate) films by entomopathogenic fungi and UV-assisted surface functionalization.

Science.gov (United States)

Kessler, Felipe; Marconatto, Leticia; Rodrigues, Roberta da Silva Bussamara; Lando, Gabriela Albara; Schrank, Augusto; Vainstein, Marilene Henning; Weibel, Daniel Eduardo

2014-01-05

Ultraviolet (UV)-assisted surface modification in the presence of oxygen was used as initial step to achieve controlled degradation of poly(3-hydroxy-butyrate), PHB, films by entomopathogenic fungi. Treated surfaces were investigated by surface analysis techniques (water contact angle, Fourier Transformed Infrared Spectroscopy in Attenuated Total Reflectance mode, X-ray Photoelectron Spectroscopy, Near-edge X-ray Absorption Fine Structure, Gel Permeation Chromatography, Optical Microscopy, Scanning Electron Microscopy, and weight loss). After the UV-assisted treatments, new carbonyl groups in new chemical environments were detected by XPS and NEXAFS spectroscopy. The oxidizing atmosphere did not allow the formation of CC bonds, indicating that Norrish Type II mechanism is suppressed during or by the treatments. The higher hydrophilicity and concentration of oxygenated functional groups at the surface of the treated films possibly improved the biodegradation of the films. It was observed a clear increase in the growth of this fungus when oxygenated groups were grafted on the polymers surfaces. This simple methodology can be used to improve and control the degradation rate of PHB films in applications that require a controllable degradation rate. Copyright © 2013 Elsevier B.V. All rights reserved.

Protective effects of flavanol-rich dark chocolate on endothelial function and wave reflection during acute hyperglycemia.

Science.gov (United States)

Grassi, Davide; Desideri, Giovambattista; Necozione, Stefano; Ruggieri, Fabrizio; Blumberg, Jeffrey B; Stornello, Michele; Ferri, Claudio

2012-09-01

Nitric oxide plays a pivotal role in regulating vascular tone. Different studies show endothelial function is impaired during hyperglycemia. Dark chocolate increases flow-mediated dilation in healthy and hypertensive subjects with and without glucose intolerance; however, the effect of pretreatment with dark chocolate on endothelial function and other vascular responses to hyperglycemia has not been examined. Therefore, we aimed to investigate the effects of flavanol-rich dark chocolate administration on (1) flow-mediated dilation and wave reflections; (2) blood pressure, endothelin-1 and oxidative stress, before and after oral glucose tolerance test (OGTT). Twelve healthy volunteers (5 males, 28.2±2.7 years) randomly received either 100 g/d dark chocolate or flavanol-free white chocolate for 3 days. After 7 days washout period, volunteers were switched to the other treatment. Flow-mediated dilation, stiffness index, reflection index, peak-to-peak time, blood pressure, endothelin-1 and 8-iso-PGF(2α) were evaluated after each treatment phase and OGTT. Compared with white chocolate, dark chocolate ingestion improved flow-mediated dilation (P=0.03), wave reflections, endothelin-1 and 8-iso-PGF(2α) (Pwave reflections, blood pressure, and endothelin-1 and 8-iso-PGF(2α) increased after OGTT. OGTT causes acute, transient impairment of endothelial function and oxidative stress, which is attenuated by flavanol-rich dark chocolate. These results suggest cocoa flavanols may contribute to vascular health by reducing the postprandial impairment of arterial function associated with the pathogenesis of atherosclerosis.

SURFACE SYMMETRY ENERGY OF NUCLEAR ENERGY DENSITY FUNCTIONALS

Energy Technology Data Exchange (ETDEWEB)

Nikolov, N; Schunck, N; Nazarewicz, W; Bender, M; Pei, J

2010-12-20

We study the bulk deformation properties of the Skyrme nuclear energy density functionals. Following simple arguments based on the leptodermous expansion and liquid drop model, we apply the nuclear density functional theory to assess the role of the surface symmetry energy in nuclei. To this end, we validate the commonly used functional parametrizations against the data on excitation energies of superdeformed band-heads in Hg and Pb isotopes, and fission isomers in actinide nuclei. After subtracting shell effects, the results of our self-consistent calculations are consistent with macroscopic arguments and indicate that experimental data on strongly deformed configurations in neutron-rich nuclei are essential for optimizing future nuclear energy density functionals. The resulting survey provides a useful benchmark for further theoretical improvements. Unlike in nuclei close to the stability valley, whose macroscopic deformability hangs on the balance of surface and Coulomb terms, the deformability of neutron-rich nuclei strongly depends on the surface-symmetry energy; hence, its proper determination is crucial for the stability of deformed phases of the neutron-rich matter and description of fission rates for r-process nucleosynthesis.

IRAS surface brightness maps of visible reflection nebulae: evidence for non-equilibrium infrared emission

International Nuclear Information System (INIS)

Castelaz, M.W.; Werner, M.W.; Sellgren, K.

1986-01-01

Surface brightness maps at 12, 25, 60, and 100 microns of 16 visible reflection nebulae were extracted from the Infrared Astronomy Satellite (IRAS) database. The maps were produced by coadding IRAS survey scans over areas centered on the illuminating stars, and have spatial resolutions of 0.9' x 4' at 12 and 25 microns, 1.8' x 4.5' at 60 microns, and 3.6' x 5' at 100 microns. Extended emission in the four IRAS bandpasses was detected in fourteen of the reflection nebulae. The IRAS data were used to measure the flux of the infrared emission associated with each source. The energy distributions show that the 12 micron flux is greater than the 25 micron flux in 11 of the nebulae, and the peak flux occurs in the 60 or 100 micron bandpass in all 16 nebular. The 60 and 100 micron flux can be approximated by blackbodies with temperatures between 30 and 50 K, consistent with temperatures expected from extrapolation of greybody fits to the 60 and 100 micron data. The excess 12 and 25 micron emission is attributed to a nonequilibrium process such as emission from thermal fluctuations of very small grains excited by single ultraviolet photons, or emission from polycyclic aromatic hydrocarbons (PAHs) excited by ultraviolet radiation. The common features of the energy distributions of the 16 reflection nebulae, also seen in the reflection nebulae associated with the Pleiades, suggest that PAHs or very small grains may be found in most reflection nebulae

Partitioning of functional and taxonomic diversity in surface-associated microbial communities.

Science.gov (United States)

Roth-Schulze, Alexandra J; Zozaya-Valdés, Enrique; Steinberg, Peter D; Thomas, Torsten

2016-12-01

Surfaces, including those submerged in the marine environment, are subjected to constant interactions and colonisation by surrounding microorganisms. The principles that determine the assembly of those epibiotic communities are however poorly understood. In this study, we employed a hierarchical design to assess the functionality and diversity of microbial communities on different types of host surfaces (e.g. macroalgae, seagrasses). We found that taxonomic diversity was unique to each type of host, but that the majority of functions (> 95%) could be found in any given surface community, suggesting a high degree of functional redundancy. However, some community functions were enriched on certain surfaces and were related to host-specific properties (e.g. the degradation of specific polysaccharides). Together these observations support a model, whereby communities on surfaces are assembled from guilds of microorganisms with a functionality that is partitioned into general properties for a surface-associated life-style, but also specific features that mediate host-specificity. © 2016 Society for Applied Microbiology and John Wiley & Sons Ltd.

Estimation of Melt Ponds over Arctic Sea Ice using MODIS Surface Reflectance Data

Science.gov (United States)

Ding, Y.; Cheng, X.; Liu, J.

2017-12-01

Melt ponds over Arctic sea ice is one of the main factors affecting variability of surface albedo, increasing absorption of solar radiation and further melting of snow and ice. In recent years, a large number of melt ponds have been observed during the melt season in Arctic. Moreover, some studies have suggested that late spring to mid summer melt ponds information promises to improve the prediction skill of seasonal Arctic sea ice minimum. In the study, we extract the melt pond fraction over Arctic sea ice since 2000 using three bands MODIS weekly surface reflectance data by considering the difference of spectral reflectance in ponds, ice and open water. The preliminary comparison shows our derived Arctic-wide melt ponds are in good agreement with that derived by the University of Hamburg, especially at the pond distribution. We analyze seasonal evolution, interannual variability and trend of the melt ponds, as well as the changes of onset and re-freezing. The melt pond fraction shows an asymmetrical growth and decay pattern. The observed melt ponds fraction is almost within 25% in early May and increases rapidly in June and July with a high fraction of more than 40% in the east of Greenland and Beaufort Sea. A significant increasing trend in the melt pond fraction is observed for the period of 2000-2017. The relationship between melt pond fraction and sea ice extent will be also discussed. Key Words: melt ponds, sea ice, Arctic

Work functions and surface charges at metallic facet edges

International Nuclear Information System (INIS)

Fall, C.J.; Binggeli, N.; Baldereschi, A.

2002-04-01

The electronic charge densities and work functions at sharp metallic facet edges are determined from ab initio calculations, combined with macroscopic averaging techniques. In particular, we examine how two different work functions coexist at close range near edges between inequivalent facets. The surface ionic relaxation at facet edges is shown to influence appreciably the local electrostatic potential in the vacuum. Various edges between Al(100) and Al(111) facets are studied, as well as between Na(110) facets. We also develop a model of electronic surface dipoles, which accounts for the surface charge transfer between inequivalent facets, and which allows us to predict the influence of the shape and size of a macroscopic crystal on its work functions. (author)

Automatic monitoring of ecosystem structure and functions using integrated low-cost near surface sensors

Science.gov (United States)

Kim, J.; Ryu, Y.; Jiang, C.; Hwang, Y.

2016-12-01

Near surface sensors are able to acquire more reliable and detailed information with higher temporal resolution than satellite observations. Conventional near surface sensors usually work individually, and thus they require considerable manpower from data collection through information extraction and sharing. Recent advances of Internet of Things (IoT) provides unprecedented opportunities to integrate various low-cost sensors as an intelligent near surface observation system for monitoring ecosystem structure and functions. In this study, we developed a Smart Surface Sensing System (4S), which can automatically collect, transfer, process and analyze data, and then publish time series results on public-available website. The system is composed of micro-computer Raspberry pi, micro-controller Arduino, multi-spectral spectrometers made from Light Emitting Diode (LED), visible and near infrared cameras, and Internet module. All components are connected with each other and Raspberry pi intelligently controls the automatic data production chain. We did intensive tests and calibrations in-lab. Then, we conducted in-situ observations at a rice paddy field and a deciduous broadleaf forest. During the whole growth season, 4S obtained landscape images, spectral reflectance in red, green, blue, and near infrared, normalized difference vegetation index (NDVI), fraction of photosynthetically active radiation (fPAR), and leaf area index (LAI) continuously. Also We compared 4S data with other independent measurements. NDVI obtained from 4S agreed well with Jaz hyperspectrometer at both diurnal and seasonal scales (R2 = 0.92, RMSE = 0.059), and 4S derived fPAR and LAI were comparable to LAI-2200 and destructive measurements in both magnitude and seasonal trajectory. We believe that the integrated low-cost near surface sensor could help research community monitoring ecosystem structure and functions closer and easier through a network system.

Design and simulation of reflect-array metasurfaces in the visible regime

KAUST Repository

Alrasheed, Salma

2017-04-07

Metasurfaces are new, promising ultrathin materials that can enable many novel optical devices due to their ability to act as a discontinuity interface that introduces an abrupt change in amplitude, phase, and sometimes the polarization of the incident light at the wavelength scale. Therefore they can function as flat optical elements. Here, we investigate the anomalous reflection of light for transverse-magnetic (TM) polarization for normal and oblique incidence in the visible regime. We propose gradient phase gap-surface plasmon metasurfaces that exhibit high conversion efficiency (up to ∼97% of total reflected light) to the anomalous reflection angle for blue, green, and red wavelengths at normal and oblique incidence, and where light polarization is unchanged after the reflection.

Insight and psychosis: Functional and anatomical brain connectivity and self-reflection in Schizophrenia.

Science.gov (United States)

Ćurčić-Blake, Branislava; van der Meer, Lisette; Pijnenborg, Gerdina H M; David, Anthony S; Aleman, André

2015-12-01

Impaired insight into illness, associated with worse treatment outcome, is common in schizophrenia. Insight has been related to the self-reflective processing, centred on the medial frontal cortex. We hypothesized that anatomical and functional routes to and from the ventromedial prefrontal cortex (vmPFC) would differ in patients according to their degree of impaired insight. Forty-five schizophrenia patients and 19 healthy subjects performed a self-reflection task during fMRI, and underwent diffusion tensor imaging. Using dynamic causal modelling we observed increased effective connectivity from the posterior cingulate cortex (PCC), inferior parietal lobule (IPL), and dorsal mPFC (dmPFC) towards the vmPFC with poorer insight and decrease from vmPFC to the IPL. Stronger connectivity from the PCC to vmPFC during judgment of traits related to self was associated with poorer insight. We found small-scale significant changes in white matter integrity associated with clinical insight. Self-reflection may be influenced by synaptic changes that lead to the observed alterations in functional connectivity accompanied by the small-scale but measurable alterations in anatomical connections. Our findings may point to a neural compensatory response to an impairment of connectivity between self-processing regions. Similarly, the observed hyper-connectivity might be a primary deficit linked to inefficiency in the component cognitive processes that lead to impaired insight. We suggest that the stronger cognitive demands placed on patients with poor insight is reflected in increased effective connectivity during the task in this study. © 2015 Wiley Periodicals, Inc.

Highly directive Fabry-Perot leaky-wave nanoantennas based on optical partially reflective surfaces

Energy Technology Data Exchange (ETDEWEB)

Lorente-Crespo, M.; Mateo-Segura, C., E-mail: C.Mateo-Segura@hw.ac.uk [Institute of Sensors, Signals and Systems, Heriot-Watt University, EH14 4AS Edinburgh (United Kingdom)

2015-05-04

Nanoantennas enhance the conversion between highly localized electromagnetic fields and far-field radiation. Here, we investigate the response of a nano-patch partially reflective surface backed with a silver mirror to an optical source embedded at the centre of the structure. Using full wave simulations, we demonstrate a two orders of magnitude increased directivity compared to the isotropic radiator, 50% power confinement to a 13.8° width beam and a ±16 nm bandwidth. Our antenna does not rely on plasmonic phenomena thus reducing non-radiative losses and conserving source coherence.

The simplest models of the reflection nebulae

International Nuclear Information System (INIS)

Voshchinnikov, N.V.

1977-01-01

Some models of the reflection nebulue have been considered. The (U-B), (B-V) and (V-R) colors and the U, B, V and R polarization have been calculated for a model of a reflection nebula associated with a large dust cloud. For the cases in which the illuminating star is far from the surface of the cloud, the form of the nebula has been considered to be spherical. If the star is close to the surface of the cloud, a part of the nebura boundary has been considered to be flat. Single scattering within the homogeneous nebula has been assumed. All the calculations use the scattering by spheres as given by the Mie's theory. The effect of variations of chemical composition and size distribution function of the grains and the position of the illuminating star has been examined. Comparison of the theoretical results with the observations of the Merope nebula shows that the dirty ice grains with the refraction index m=1.30-0.02i and size parameter asub(o)=0.5μ represent satisfactorily the observation if the star is embedded 0.7 pc behind the front surface of the nebula

The conditions for total reflection of low-energy atoms from crystal surfaces

International Nuclear Information System (INIS)

Hou, M.; Robinson, M.T.

1978-01-01

The critical angles for the total reflection of low-energy particles from Cu rows and (001) planes have been investigated, using the binary collision approximation computer simulation code MARLOWE Breakthrough angles were evaluated for H, N, Ne, Ar, Cu, Xe, and Au in the energy range from 0.1 to 7.5 keV. In both the axial and the planar cases, recoiling of the target atoms lowers the energy barrier which the target surface presents to the heavy projectiles. Consequently, the breakthrough angles are reduced for heavy projectiles below the values expected either from observations on light projectiles or from analytical channeling theory. (orig.) [de

A Harmonized Landsat-Sentinel-2 Surface Reflectance product: a resource for Agricultural Monitoring

Science.gov (United States)

Masek, J. G.; Claverie, M.; Ju, J.; Vermote, E.; Justice, C. O.

2015-12-01

The combination of Landsat and Sentinel-2 data offers a unique opportunity to observe globally the land every 2-3 days at medium (reflectance data from Landsat and Sentinel-2 missions and to deliver them to the community in a combined, seamless form. The HLS will be beneficial for global agricultural monitoring applications that require medium spatial resolution and weekly or more frequent observations. In particular, the provided opportunity to track crop phenology at the scale of individual fields will support detailed mapping of crop type and type-specific vegetation conditions. To create a compatible set of radiometric measurements, the HLS product relies on rigorous pre- and post-launch cross-calibration (Landsat-8 OLI and Sentinel-2 MSI) activities. The processing chain includes the following components: atmospheric correction, cloud/shadow masking, nadir BRDF-adjustment, spectral-adjustment, regridding, and temporal composite. The atmospheric correction and cloud masking is based on the OLI atmospheric correction developed at NASA-GSFC and has been adapted to the MSI data. The BRDF-adjustment is based on a disaggregation technique using MODIS-based BRDF coefficients. The technique has been evaluated using the multi-angular acquisition from the SPOT 4 and 5 (Take5) experiments. The spectral-adjustment relies on a linear regression that has been calibrated and evaluated using synthetic data and surface reflectance processed from a large number of hyperspectral EO-1 Hyperion scenes. Finally, significant effort is placed on product validation and evaluation. The delivered data set will include surface reflectance products at different levels: Using the native gridding, i.e. UTM, 30m for Landsat-8, and UTM, 10-20m for Sentinel-2 Using a common global gridding (Sinusoidal, 30m) Temporal composite (Sinusoidal, 30m, 5-day) During the first year of operation of Sentinel-2A, the HLS will be prototyped over a selection of 30 sites that includes some of the JECAM sites

Arc-textured metal surfaces for high thermal emittance space radiators

International Nuclear Information System (INIS)

Banks, B.A.; Rutledge, S.K.; Mirtich, M.J.; Behrend, T.; Hotes, D.; Kussmaul, M.; Barry, J.; Stidham, C.; Stueber, T.; DiFilippo, F.

1994-01-01

Carbon arc electrical discharges struck across the surfaces of metals such as Nb-1% Zr, alter the morphology to produce a high thermal emittance surface. Metal from the surface and carbon from the arc electrode vaporize during arcing, and then condense on the metal surface to produce a microscopically rough surface having a high thermal emittance. Quantitative spectral reflectance measurements from 0.33 to 15 μm were made on metal surfaces which were carbon arc treated in an inert gas environment. The resulting spectral reflectance data were then used to calculate thermal emittance as a function of temperature for various methods of arc treatment. The results of arc treatment on various metals are presented for both ac and dc arcs. Surface characterization data, including thermal emittance as a function of temperature, scanning electron microscopy, and atomic oxygen durability, are also presented. Ac arc texturing was found to increase the thermal emittance at 800 K from 0.05. to 0.70

Surface Acoustic Wave (SAW-Enhanced Chemical Functionalization of Gold Films

Directory of Open Access Journals (Sweden)

Gina Greco

2017-10-01

Full Text Available Surface chemical and biochemical functionalization is a fundamental process that is widely applied in many fields to add new functions, features, or capabilities to a material’s surface. Here, we demonstrate that surface acoustic waves (SAWs can enhance the chemical functionalization of gold films. This is shown by using an integrated biochip composed by a microfluidic channel coupled to a surface plasmon resonance (SPR readout system and by monitoring the adhesion of biotin-thiol on the gold SPR areas in different conditions. In the case of SAW-induced streaming, the functionalization efficiency is improved ≈ 5 times with respect to the case without SAWs. The technology here proposed can be easily applied to a wide variety of biological systems (e.g., proteins, nucleic acids and devices (e.g., sensors, devices for cell cultures.

Observations of discrete energy loss effects in spectra of positrons reflected from solid surfaces

International Nuclear Information System (INIS)

Dale, J.M.; Hulett, L.D.; Pendyala, S.

1980-01-01

Surfaces of tungsten and silicon have been bombarded with monoenergetic beams of positrons and electrons. Spectra of reflected particles show energy loss tails with discrete peaks at kinetic energies about 15 eV lower than that of the elastic peaks. In the higher energy loss range for tungsten, positron spectra show fine structure that is not apparent in the electron spectra. This suggests that the positrons are losing energy through mechanisms different from that of the electrons

Analytical fitting model for rough-surface BRDF.

Science.gov (United States)

Renhorn, Ingmar G E; Boreman, Glenn D

2008-08-18

A physics-based model is developed for rough surface BRDF, taking into account angles of incidence and scattering, effective index, surface autocovariance, and correlation length. Shadowing is introduced on surface correlation length and reflectance. Separate terms are included for surface scatter, bulk scatter and retroreflection. Using the FindFit function in Mathematica, the functional form is fitted to BRDF measurements over a wide range of incident angles. The model has fourteen fitting parameters; once these are fixed, the model accurately describes scattering data over two orders of magnitude in BRDF without further adjustment. The resulting analytical model is convenient for numerical computations.