WorldWideScience

Sample records for surface phonon spectral

  1. Surface phonons

    CERN Document Server

    Wette, Frederik

    1991-01-01

    In recent years substantial progress has been made in the detection of surface phonons owing to considerable improvements in inelastic rare gas scattering tech­ niques and electron energy loss spectroscopy. With these methods it has become possible to measure surface vibrations in a wide energy range for all wave vectors in the two-dimensional Brillouin zone and thus to deduce the complete surface phonon dispersion curves. Inelastic atomic beam scattering and electron energy loss spectroscopy have started to play a role in the study of surface phonons similar to the one played by inelastic neutron scattering in the investigation of bulk phonons in the last thirty years. Detailed comparison between experimen­ tal results and theoretical studies of inelastic surface scattering and of surface phonons has now become feasible. It is therefore possible to test and to improve the details of interaction models which have been worked out theoretically in the last few decades. At this point we felt that a concise, co...

  2. Phonon lineshapes in atom-surface scattering

    Energy Technology Data Exchange (ETDEWEB)

    MartInez-Casado, R [Department of Chemistry, Imperial College London, South Kensington, London SW7 2AZ (United Kingdom); Sanz, A S; Miret-Artes, S [Instituto de Fisica Fundamental, Consejo Superior de Investigaciones CientIficas, Serrano 123, E-28006 Madrid (Spain)

    2010-08-04

    Phonon lineshapes in atom-surface scattering are obtained from a simple stochastic model based on the so-called Caldeira-Leggett Hamiltonian. In this single-bath model, the excited phonon resulting from a creation or annihilation event is coupled to a thermal bath consisting of an infinite number of harmonic oscillators, namely the bath phonons. The diagonalization of the corresponding Hamiltonian leads to a renormalization of the phonon frequencies in terms of the phonon friction or damping coefficient. Moreover, when there are adsorbates on the surface, this single-bath model can be extended to a two-bath model accounting for the effect induced by the adsorbates on the phonon lineshapes as well as their corresponding lineshapes.

  3. Infrared surface phonon polariton waveguides on SiC Substrate

    Science.gov (United States)

    Yang, Yuchen; Manene, Franklin M.; Lail, Brian A.

    2015-08-01

    Surface plasmon polariton (SPP) waveguides harbor many potential applications at visible and near-infrared (NIR) wavelengths. However, dispersive properties of the metal in the waveguide yields weakly coupled and lossy plasmonic modes in the mid and long wave infrared range. This is one of the major reasons for the rise in popularity of surface phonon polariton (SPhP) waveguides in recent research and micro-fabrication pursuit. Silicon carbide (SiC) is a good candidate in SPhP waveguides since it has negative dielectric permittivity in the long-wave infrared (LWIR) spectral region, indicative that coupling to surface phonon polaritons is realizable. Introducing surface phonon polaritons for waveguiding provides good modal confinement and enhanced propagation length. A hybrid waveguide structure at long-wave infrared (LWIR) is demonstrated in which an eigenmode solver approach in Ansys HFSS was applied. The effect of a three layer configuration i.e., silicon wire on a benzocyclobutene (BCB) dielectric slab on SiC, and the effects of varying their dimensions on the modal field distribution and on the propagation length, is presented.

  4. Relaxation between electrons and surface phonons of a ...

    Indian Academy of Sciences (India)

    Abstract. The energy relaxation between the hot degenerate electrons of a homoge- neously photoexcited metal film and the surface phonons (phonon wave vectors in two dimensions) is considered under Debye approximation. The state of electrons and phonons is described by equilibrium Fermi and Bose functions with ...

  5. Relaxation between electrons and surface phonons of a ...

    Indian Academy of Sciences (India)

    The energy relaxation between the hot degenerate electrons of a homogeneously photoexcited metal film and the surface phonons (phonon wave vectors in two dimensions) is considered under Debye approximation. The state of electrons and phonons is described by equilibrium Fermi and Bose functions with different ...

  6. Subwavelength waveguiding of surface phonons in pillars-based phononic crystal

    Directory of Open Access Journals (Sweden)

    Mahmoud Addouche

    2014-12-01

    Full Text Available In this study, we theoretically analyze the guiding of surface phonons through locally resonant defects in pillars-based phononic crystal. Using finite element method, we simulate the propagation of surface phonons through a periodic array of cylindrical pillars deposited on a semi-infinite substrate. This structure displays several band gaps, some of which are due to local resonances of the pillar. By introducing pillar defects inside the phononic structure, we show the possibility to perform a waveguiding of surface phonons based on two mechanisms that spatially confine the elastic energy in very small waveguide apertures. A careful choice of the height of the defect pillars, allows to shift the frequency position of the defect modes inside or outside the locally resonant band gaps and create two subwavelenght waveguiding mechanisms. The first is a classical mechanism that corresponds to the presence of the defect modes inside the locally resonant band gap. The seconde is due to the hybridation between the phonon resonances of defect modes and the surface phonons of the semi-infinite homogenous medium. We discuss the nature and the difference between both waveguiding phenomena.

  7. Molecular-dynamics theory of the temperature-dependent surface phonons of W(001)

    International Nuclear Information System (INIS)

    Wang, C.Z.; Fasolino, A.; Tosatti, E.

    1987-04-01

    We study the temperature-dependent zone-boundary surface phonons across the c(2x2)→1x1 reconstruction phase transition of the clean W(001) surface. Velocity-velocity correlations and hence the phonon spectral densities are calculated by molecular dynamics for the surface atoms of a finite thickness (001) slab, with interatomic potentials established in a previous study of the surface statics. Our calculated k = (1/2,1/2)(2π/a) surface phonon are dominated by three main low-frequency modes. Of these, the longitudinal and the shear horizontal are reconstruction-related and display critical broadening and softening at the phase transition, while the third, the shear vertical, is basically unaffected. The reconstruction phase mode, shear horizontal, appears to be responsible for the phase fluctuations which destroy long-range order at the transition. (author). 30 refs, 12 figs

  8. Interface nano-confined acoustic waves in polymeric surface phononic crystals

    Energy Technology Data Exchange (ETDEWEB)

    Travagliati, Marco, E-mail: marco.travagliati@iit.it [Center for Nanotechnology Innovation@NEST, Istituto Italiano di Tecnologia, Piazza San Silvestro 12, 56127 Pisa (Italy); NEST, Scuola Normale Superiore and Istituto Nanoscienze-CNR, Piazza San Silvestro 12, 56127 Pisa (Italy); Nardi, Damiano [JILA and Department of Physics, University of Colorado, 440 UCB, Boulder, Colorado 80309 (United States); Giannetti, Claudio; Ferrini, Gabriele; Banfi, Francesco, E-mail: francesco.banfi@unicatt.it [i-LAMP and Dipartimento di Matematica e Fisica, Università Cattolica del Sacro Cuore, Via Musei 41, 25121 Brescia (Italy); Gusev, Vitalyi [LAUM, UMR-CNRS 6613, Université du Maine, av. O. Messiaen, 72085 Le Mans (France); Pingue, Pasqualantonio [NEST, Scuola Normale Superiore and Istituto Nanoscienze-CNR, Piazza San Silvestro 12, 56127 Pisa (Italy); Piazza, Vincenzo [Center for Nanotechnology Innovation@NEST, Istituto Italiano di Tecnologia, Piazza San Silvestro 12, 56127 Pisa (Italy)

    2015-01-12

    The impulsive acoustic dynamics of soft polymeric surface phononic crystals is investigated here in the hypersonic frequency range by near-IR time-resolved optical diffraction. The acoustic response is analysed by means of wavelet spectral methods and finite element modeling. An unprecedented class of acoustic modes propagating within the polymer surface phononic crystal and confined within 100 nm of the nano-patterned interface is revealed. The present finding opens the path to an alternative paradigm for characterizing the mechanical properties of soft polymers at interfaces and for sensing schemes exploiting polymers as embedding materials.

  9. Electromagnetic excitation of phonons at C(001) surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Perez-Sanchez, F L [Escuela de Ciencias, Universidad Autonoma ' Benito Juarez' de Oaxaca, Avenida Universidad S/N, Ex-Hacienda de Cinco Senores, Ciudad Universitaria, Oaxaca de Juarez, Oaxaca, 68120 (Mexico); Perez-Rodriguez, F, E-mail: fperez@sirio.ifuap.buap.m [Instituto de Fisica, Benemerita Universidad Autonoma de Puebla, Apartado Post. J-48, Puebla 72570 (Mexico)

    2009-09-02

    The photon-phonon coupling at C(001)-(2 x 1) surfaces and its manifestation in far-infrared reflectance anisotropy spectra (FIR-RAS) are theoretically investigated. We solve the coupled system of equations for the electromagnetic field and lattice vibrations, described within the adiabatic bond charge model (ABCM), with the method of expansion into bulk phonon and photon modes. The calculated FIR-RAS exhibit resonances associated with zone-center surface phonons in good agreement with available HREELS experiments and predictions of vibrational modes for diamond (001)-(2 x 1) surfaces from ABCM and ab initio calculations. Interestingly, the reflectance anisotropy spectra for a C(001)-(2 x 1) surface turn out to be qualitatively different from the spectra for a Si(001)-(2 x 1) surface, reported previously.

  10. Electromagnetic excitation of phonons at C(001) surfaces

    International Nuclear Information System (INIS)

    Perez-Sanchez, F L; Perez-Rodriguez, F

    2009-01-01

    The photon-phonon coupling at C(001)-(2 x 1) surfaces and its manifestation in far-infrared reflectance anisotropy spectra (FIR-RAS) are theoretically investigated. We solve the coupled system of equations for the electromagnetic field and lattice vibrations, described within the adiabatic bond charge model (ABCM), with the method of expansion into bulk phonon and photon modes. The calculated FIR-RAS exhibit resonances associated with zone-center surface phonons in good agreement with available HREELS experiments and predictions of vibrational modes for diamond (001)-(2 x 1) surfaces from ABCM and ab initio calculations. Interestingly, the reflectance anisotropy spectra for a C(001)-(2 x 1) surface turn out to be qualitatively different from the spectra for a Si(001)-(2 x 1) surface, reported previously.

  11. Direct measurements of surface scattering in Si nanosheets using a microscale phonon spectrometer: implications for Casimir-limit predicted by Ziman theory.

    Science.gov (United States)

    Hertzberg, Jared B; Aksit, Mahmut; Otelaja, Obafemi O; Stewart, Derek A; Robinson, Richard D

    2014-02-12

    Thermal transport in nanostructures is strongly affected by phonon-surface interactions, which are expected to depend on the phonon's wavelength and the surface roughness. Here we fabricate silicon nanosheets, measure their surface roughness (∼ 1 nm) using atomic force microscopy (AFM), and assess the phonon scattering rate in the sheets with a novel technique: a microscale phonon spectrometer. The spectrometer employs superconducting tunnel junctions (STJs) to produce and detect controllable nonthermal distributions of phonons from ∼ 90 to ∼ 870 GHz. This technique offers spectral resolution nearly 10 times better than a thermal conductance measurement. We compare measured phonon transmission rates to rates predicted by a Monte Carlo model of phonon trajectories, assuming that these trajectories are dominated by phonon-surface interactions and using the Ziman theory to predict phonon-surface scattering rates based on surface topology. Whereas theory predicts a diffuse surface scattering probability of less than 40%, our measurements are consistent with a 100% probability. Our nanosheets therefore exhibit the so-called "Casimir limit" at a much lower frequency than expected if the phonon scattering rates follow the Ziman theory for a 1 nm surface roughness. Such a result holds implications for thermal management in nanoscale electronics and the design of nanostructured thermoelectrics.

  12. Enhanced Electron-Phonon Coupling at Metal Surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Plummer, Ward E.

    2010-08-04

    The Born-Oppenheimer approximation (BOA) decouples electronic from nuclear motion, providing a focal point for most quantum mechanics textbooks. However, a multitude of important chemical, physical and biological phenomena are driven by violations of this approximation. Vibronic interactions are a necessary ingredient in any process that makes or breaks a covalent bond, for example, conventional catalysis or enzymatically delivered biological reactions. Metastable phenomena associated with defects and dopants in semiconductors, oxides, and glasses entail violation of the BOA. Charge exchange in inorganic polymers, organic slats and biological systems involves charge- induced distortions of the local structure. A classic example is conventional superconductivity, which is driven by the electron-lattice interaction. High-resolution angle-resolved photoemission experiments are yielding new insight into the microscopic origin of electron-phonon coupling (EPC) in anisotropic two-dimensional systems. Our recent surface phonon measurement on the surface of a high-Tc material clearly indicates an important momentum dependent EPC in these materials. In the last few years we have shifted our research focus from solely looking at electron phonon coupling to examining the structure/functionality relationship at the surface of complex transition metal compounds. The investigation on electron phonon coupling has allowed us to move to systems where there is coupling between the lattice, the electrons and the spin.

  13. Phonon Surface Scattering and Thermal Energy Distribution in Superlattices.

    Science.gov (United States)

    Kothari, Kartik; Maldovan, Martin

    2017-07-17

    Thermal transport at small length scales has attracted significant attention in recent years and various experimental and theoretical methods have been developed to establish the reduced thermal conductivity. The fundamental understanding of how phonons move and the physical mechanisms behind nanoscale thermal transport, however, remains poorly understood. Here we move beyond thermal conductivity calculations and provide a rigorous and comprehensive physical description of thermal phonon transport in superlattices by solving the Boltzmann transport equation and using the Beckman-Kirchhoff surface scattering theory with shadowing to precisely describe phonon-surface interactions. We show that thermal transport in superlattices can be divided in two different heat transport modes having different physical properties at small length scales: layer-restricted and extended heat modes. We study how interface conditions, periodicity, and composition can be used to manipulate the distribution of thermal energy flow among such layer-restricted and extended heat modes. From predicted frequency and mean free path spectra of superlattices, we also investigate the existence of wave effects. The results and insights in this paper advance the fundamental understanding of heat transport in superlattices and the prospects of rationally designing thermal systems with tailored phonon transport properties.

  14. Thermal Properties and Phonon Spectral Characterization of Synthetic Boron Phosphide for High Thermal Conductivity Applications.

    Science.gov (United States)

    Kang, Joon Sang; Wu, Huan; Hu, Yongjie

    2017-12-13

    Heat dissipation is an increasingly critical technological challenge in modern electronics and photonics as devices continue to shrink to the nanoscale. To address this challenge, high thermal conductivity materials that can efficiently dissipate heat from hot spots and improve device performance are urgently needed. Boron phosphide is a unique high thermal conductivity and refractory material with exceptional chemical inertness, hardness, and high thermal stability, which holds high promises for many practical applications. So far, however, challenges with boron phosphide synthesis and characterization have hampered the understanding of its fundamental properties and potential applications. Here, we describe a systematic thermal transport study based on a synergistic synthesis-experimental-modeling approach: we have chemically synthesized high-quality boron phosphide single crystals and measured their thermal conductivity as a record-high 460 W/mK at room temperature. Through nanoscale ballistic transport, we have, for the first time, mapped the phonon spectra of boron phosphide and experimentally measured its phonon mean free-path spectra with consideration of both natural and isotope-pure abundances. We have also measured the temperature- and size-dependent thermal conductivity and performed corresponding calculations by solving the three-dimensional and spectral-dependent phonon Boltzmann transport equation using the variance-reduced Monte Carlo method. The experimental results are in good agreement with that predicted by multiscale simulations and density functional theory, which together quantify the heat conduction through the phonon mode dependent scattering process. Our finding underscores the promise of boron phosphide as a high thermal conductivity material for a wide range of applications, including thermal management and energy regulation, and provides a detailed, microscopic-level understanding of the phonon spectra and thermal transport mechanisms of

  15. Vibrational Surface Electron-Energy-Loss Spectroscopy Probes Confined Surface-Phonon Modes

    Directory of Open Access Journals (Sweden)

    Hugo Lourenço-Martins

    2017-12-01

    Full Text Available Recently, two reports [Krivanek et al. Nature (London 514, 209 (2014NATUAS0028-083610.1038/nature13870, Lagos et al. Nature (London 543, 529 (2017NATUAS0028-083610.1038/nature21699] have demonstrated the amazing possibility to probe vibrational excitations from nanoparticles with a spatial resolution much smaller than the corresponding free-space phonon wavelength using electron-energy-loss spectroscopy (EELS. While Lagos et al. evidenced a strong spatial and spectral modulation of the EELS signal over a nanoparticle, Krivanek et al. did not. Here, we show that discrepancies among different EELS experiments as well as their relation to optical near- and far-field optical experiments [Dai et al. Science 343, 1125 (2014SCIEAS0036-807510.1126/science.1246833] can be understood by introducing the concept of confined bright and dark surface phonon modes, whose density of states is probed by EELS. Such a concise formalism is the vibrational counterpart of the broadly used formalism for localized surface plasmons [Ouyang and Isaacson Philos. Mag. B 60, 481 (1989PMABDJ1364-281210.1080/13642818908205921, García de Abajo and Aizpurua Phys. Rev. B 56, 15873 (1997PRBMDO0163-182910.1103/PhysRevB.56.15873, García de Abajo and Kociak Phys. Rev. Lett. 100, 106804 (2008PRLTAO0031-900710.1103/PhysRevLett.100.106804, Boudarham and Kociak Phys. Rev. B 85, 245447 (2012PRBMDO1098-012110.1103/PhysRevB.85.245447]; it makes it straightforward to predict or interpret phenomena already known for localized surface plasmons such as environment-related energy shifts or the possibility of 3D mapping of the related surface charge densities [Collins et al. ACS Photonics 2, 1628 (2015APCHD52330-402210.1021/acsphotonics.5b00421].

  16. Vibrational Surface Electron-Energy-Loss Spectroscopy Probes Confined Surface-Phonon Modes

    Science.gov (United States)

    Lourenço-Martins, Hugo; Kociak, Mathieu

    2017-10-01

    Recently, two reports [Krivanek et al. Nature (London) 514, 209 (2014), 10.1038/nature13870, Lagos et al. Nature (London) 543, 529 (2017), 10.1038/nature21699] have demonstrated the amazing possibility to probe vibrational excitations from nanoparticles with a spatial resolution much smaller than the corresponding free-space phonon wavelength using electron-energy-loss spectroscopy (EELS). While Lagos et al. evidenced a strong spatial and spectral modulation of the EELS signal over a nanoparticle, Krivanek et al. did not. Here, we show that discrepancies among different EELS experiments as well as their relation to optical near- and far-field optical experiments [Dai et al. Science 343, 1125 (2014), 10.1126/science.1246833] can be understood by introducing the concept of confined bright and dark surface phonon modes, whose density of states is probed by EELS. Such a concise formalism is the vibrational counterpart of the broadly used formalism for localized surface plasmons [Ouyang and Isaacson Philos. Mag. B 60, 481 (1989), 10.1080/13642818908205921, García de Abajo and Aizpurua Phys. Rev. B 56, 15873 (1997), 10.1103/PhysRevB.56.15873, García de Abajo and Kociak Phys. Rev. Lett. 100, 106804 (2008), 10.1103/PhysRevLett.100.106804, Boudarham and Kociak Phys. Rev. B 85, 245447 (2012), 10.1103/PhysRevB.85.245447]; it makes it straightforward to predict or interpret phenomena already known for localized surface plasmons such as environment-related energy shifts or the possibility of 3D mapping of the related surface charge densities [Collins et al. ACS Photonics 2, 1628 (2015), 10.1021/acsphotonics.5b00421].

  17. Rayleigh waves, surface disorder, and phonon localization in nanostructures

    Science.gov (United States)

    Maurer, L. N.; Mei, S.; Knezevic, I.

    2016-07-01

    We introduce a technique to calculate thermal conductivity in disordered nanostructures: a finite-difference time-domain solution of the elastic-wave equation combined with the Green-Kubo formula. The technique captures phonon wave behavior and scales well to nanostructures that are too large or too surface disordered to simulate with many other techniques. We investigate the role of Rayleigh waves and surface disorder on thermal transport by studying graphenelike nanoribbons with free edges (allowing Rayleigh waves) and fixed edges (prohibiting Rayleigh waves). We find that free edges result in a significantly lower thermal conductivity than fixed ones. Free edges both introduce Rayleigh waves and cause all low-frequency modes (bulk and surface) to become more localized. Increasing surface disorder on free edges draws energy away from the center of the ribbon and toward the disordered edges, where it gets trapped in localized surface modes. These effects are not seen in ribbons with fixed boundary conditions and illustrate the importance of phonon-surface modes in nanostructures.

  18. Spectral tuning via multi-phonon-assisted stokes and anti-stokes excitations in LaF{sub 3}: Tm{sup 3+} nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Gao, Dangli, E-mail: gaodangli@163.com [School of Materials & Mineral Resources, Xi' an University of Architecture and Technology, Xi' an, Shaanxi 710055 (China); College of Science, Xi' an University of Architecture and Technology, Xi' an, Shaanxi 710055 (China); Shaanxi Key Laboratory of Nano Materials and Technology, Xi' an, Shaanxi 710055 (China); Tian, Dongping, E-mail: dptian@xauat.edu.cn [School of Materials & Mineral Resources, Xi' an University of Architecture and Technology, Xi' an, Shaanxi 710055 (China); College of Science, Xi' an University of Architecture and Technology, Xi' an, Shaanxi 710055 (China); Chong, Bo; Li, Long [College of Science, Xi' an University of Architecture and Technology, Xi' an, Shaanxi 710055 (China); Zhang, Xiangyu [College of Science, Chang' an University, Xi' an, Shaanxi 710064 (China)

    2016-09-05

    We present a facile and highly effective method to tailor upconversion (UC) emission from LaF{sub 3}: Tm{sup 3+} nanoparticles (NPs) by adjusting ambient temperature from 20 K to 400 K accompanied with the pulse laser excitation. Spectral tuning mechanism controlled by ambient temperature at pulse laser excitation is revealed, and a mechanism based on the modification on multi-phonon relaxation rates for the rapid population of intermediate level {sup 3}H{sub 4} and multi-phonon-assisted excited state absorption is proposed. Based on multi-phonon relaxation theory and time-resolved photoluminescence studies, it is reasonable that UC luminescence under short-pulse laser excitation mainly originates from the ions at/near the surface of NPs. These exciting findings in ambient temperature accompanied with the short-pulse excitation dependent UC selectivity offer a general approach to tailoring lanthanide related UC emissions, which will benefit multicolor displays and imaging. - Graphical abstract: An effective method to tailor upconversion from LaF{sub 3}: Tm{sup 3+} nanoparticles by adjusting ambient temperature accompanied with the short-pulse laser excitation is presented and the spectral tuning mechanism based the modification on multi-phonon relaxation rate and multi-phonon-assisted excited state absorption is also revealed. - Highlights: • The luminescence switching is controlled by temperature and pulse duration. • The mechanism based on the multi-phonon-assisted excitations is proposed. • Blue luminescence under short-pulse excitation originates from the surface ions. • Temperature has a big effect on luminescence color output.

  19. Metals: Phonon states, electron states and Fermi surfaces. Subvolume a

    International Nuclear Information System (INIS)

    Dederichs, P.H.; Schober, H.; Sellmyer, D.J.

    1981-01-01

    This collection of tables and diagrams is the first contribution to a larger programme aiming at a complete and critical tabulation of reliable data relevant to metal physics. No such complete collection exists at present, and these tables should fill a long felt need of both experimentalists and theoreticians. Group III in the New Series of the Landolt-Boernstein tables deals with Crystal and Solid State Physics. Volume III/13 to which this subvolume 13a belongs will cover all data published up to 1980 on phonon and electron states and Fermi surfaces in metals. Both experimental and theoretical results are included. (orig./WL)

  20. Raman selection rule of surface optical phonon in ZnS nanobelts

    KAUST Repository

    Ho, Chih-Hsiang

    2016-02-18

    We report Raman scattering results of high-quality wurtzite ZnS nanobelts (NBs) grown by chemical vapor deposition. In Raman spectrum, the ensembles of ZnS NBs exhibit first order phonon modes at 274 cm-1 and 350 cm-1, corresponding to A1/E1 transverse optical and A1/E1 longitudinal optical phonons, in addition with strong surface optical (SO) phonon mode at 329 cm-1. The existence of SO band is confirmed by its shift with different surrounding dielectric media. Polarization dependent Raman spectrum was performed on a single ZnS NB and for the first time SO phonon band has been detected on a single nanobelt. Different selection rules of SO phonon modeshown from their corresponding E1/A1 phonon modeswere attributed to the anisotropic translational symmetry breaking on the NB surface.

  1. Phonon anomalies and electron-phonon coupling of metal surfaces and thin films; Phononenanomalien und Elektron-Phonon-Kopplung an Metalloberflaechen und duennen Schichten

    Energy Technology Data Exchange (ETDEWEB)

    Flach, B.

    2000-01-01

    This thesis has two topics: One is the investigation of an adsorbate induced phonon anomaly on W(110) and Mo{sub 1-x}Re{sub x}(110) (x = 5, 15, 25%) with inelastic helium atom scattering (HAS). The other one is the study of the growth, morphology and dynamics of ultra-thin lithium films deposited on W(110). In 1992 a giant phonon anomaly was found by J. Luedecke on the hydrogen saturated W(110) and Mo(110) surfaces. The anomaly consists of a deep and sharp indentation in the phonon dispersion curves in which the phonon energy nearly drops to zero ({omega}{sub 1}). In addition, a small and broad dip in the surface Rayleigh mode is observed ({omega}{sub 2}). The anomaly appears in the anti {gamma}-H- as well as in the anti {gamma}-S-direction of the surface Brillouin zone (SBZ). Since its first discovery, numerous other experimental and theoretical studies have followed. In the present work the effects is reinvestigated and experimental parameters, such as the crystal temperature and the incident energy, were changed in order to study their influence on the anomalous phonon behavior. In the case of H/Mo(110) the substrate was changed as well by alloying with small amounts of rhenium. In the present experiments a strong crystal temperature dependence of the {omega}{sub 2}-branch was found which leads to lower energies at the 'dip' for smaller temperatures, while the {omega}{sub 1}-anomaly remains unchanged. Such behavior agrees well with the picture that the {omega}{sub 2}-branch is due to a Kohn anomaly. (orig.)

  2. INTRODUCTION: Surface Dynamics, Phonons, Adsorbate Vibrations and Diffusion

    Science.gov (United States)

    Bruch, L. W.

    2004-07-01

    understanding of the underlying factors determining the optical quality of GaInNAs, such as composition, growth and annealing conditions. We are still far from establishing an understanding of the band structure and its dependence on composition. Fundamental electronic interactions such as electron-electron and electron-phonon scattering, dependence of effective mass on composition, strain and orientation, quantum confinement effects, effects of localized nitrogen states on high field transport and on galvanometric properties, and mechanisms for light emission in these materials, are yet to be fully understood. Nature and formation mechanisms of grown-in and processing-induced defects that are important for material quality and device performance are still unknown. Such knowledge is required in order to design strategies to efficiently control and eliminate harmful defects. For many potential applications (such as solar cells, HBTs) it is essential to get more information on the transport properties of dilute nitride materials. The mobility of minority carriers is known to be low in GaInNAs and related material. The experimental values are far from reaching the theoretical ones, due to defects and impurities introduced in the material during the growth. The role of the material inhomogeneities on the lateral carrier transport also needs further investigation. From the device's point of view most attention to date has been focused on the GaInNAs/GaAs system, mainly because of its potential for optoelectronic devices covering the 1.3-1.55 µm data and telecommunications wavelength bands. As is now widely appreciated, these GaAs-compatible structures allow monolithic integration of AlGaAs-based distributed Bragg reflector mirrors (DBRs) for vertical cavity surface-emitting lasers with low temperature sensitivity and compatibility with AlOx-based confinement techniques. In terms of conventional edge-emitting lasers (EELs), the next step is to extend the wavelength range for cw room

  3. The influence of the surface parameter changes onto the phonon states in ultrathin crystalline films

    Science.gov (United States)

    Šetrajčić, Jovan P.; Ilić, Dušan I.; Jaćimovski, Stevo K.

    2018-04-01

    In this paper, we have analytically investigated how the changes in boundary surface parameters influence the phonon dispersion law in ultrathin films of the simple cubic crystalline structure. Spectra of possible phonon states are analyzed using the method of two-time dependent Green's functions and for the diverse combination of boundary surface parameters, this problem was presented numerically and graphically. It turns out that for certain values and combinations of parameters, displacement of dispersion branches outside of bulk zone occurs, leading to the creation of localized phonon states. This fact is of great importance for the heat removal, electrical conductivity and superconducting properties of ultrathin films.

  4. Continuous multispectral imaging of surface phonon polaritons on silicon carbide with an external cavity quantum cascade laser

    Science.gov (United States)

    Dougakiuchi, Tatsuo; Kawada, Yoichi; Takebe, Gen

    2018-03-01

    We demonstrate the continuous multispectral imaging of surface phonon polaritons (SPhPs) on silicon carbide excited by an external cavity quantum cascade laser using scattering-type scanning near-field optical microscopy. The launched SPhPs were well characterized via the confirmation that the theoretical dispersion relation and measured in-plane wave vectors are in excellent agreement in the entire measurement range. The proposed scheme, which can excite and observe SPhPs with an arbitrary wavelength that effectively covers the spectral gap of CO2 lasers, is expected to be applicable for studies of near-field optics and for various applications based on SPhPs.

  5. Investigation of the full spectrum phonon lifetime in thin silicon films from the bulk spectral phonon mean-free-path distribution by using kinetic theory

    Science.gov (United States)

    Jin, Jae Sik

    2017-03-01

    Phonon dynamics in nanostructures is critically important to thermoelectric and optoelectronic devices because it determines the transport and other crucial properties. However, accurately evaluating the phonon lifetimes is extremely difficult. This study reports on the development of a new semi-empirical method to estimate the full-spectrum phonon lifetimes in thin silicon films at room temperature based on the experimental data on the phonon mean-free-path spectrum in bulk silicon and a phenomenological consideration of phonon transport in thin films. The bulk of this work describes the theory and the validation; then, we discuss the trend of the phonon lifetimes in thin silicon films when their thicknesses decrease.

  6. Semiclassical multi-phonon theory for atom-surface scattering: Application to the Cu(111) system.

    Science.gov (United States)

    Daon, Shauli; Pollak, Eli

    2015-05-07

    The semiclassical perturbation theory of Hubbard and Miller [J. Chem. Phys. 80, 5827 (1984)] is further developed to include the full multi-phonon transitions in atom-surface scattering. A practically applicable expression is developed for the angular scattering distribution by utilising a discretized bath of oscillators, instead of the continuum limit. At sufficiently low surface temperature good agreement is found between the present multi-phonon theory and the previous one-, and two-phonon theory derived in the continuum limit in our previous study [Daon, Pollak, and Miret-Artés, J. Chem. Phys. 137, 201103 (2012)]. The theory is applied to the measured angular distributions of Ne, Ar, and Kr scattered from a Cu(111) surface. We find that the present multi-phonon theory substantially improves the agreement between experiment and theory, especially at the higher surface temperatures. This provides evidence for the importance of multi-phonon transitions in determining the angular distribution as the surface temperature is increased.

  7. Correlation between phonon anomaly along [211] and the Fermi surface nesting features with associated electron-phonon interactions in Ni2FeGa: A first principles study

    International Nuclear Information System (INIS)

    Chabungbam, Satyananda; Sahariah, Munima B.

    2015-01-01

    First principles calculation reaffirms the presence of phonon anomaly along [211] direction in Ni 2 FeGa shape memory alloy supporting the experimental findings of J. Q. Li et al. Fermi surface scans have been performed in both austenite and martensite phase to see the possible Fermi nesting features in this alloy. The magnitude of observed Fermi surface nesting vectors in (211) plane exactly match the phonon anomaly wavevectors along [211] direction. Electron-phonon calculation in the austenite phase shows that there is significant electron-phonon coupling in this alloy which might arise out of the lattice coupling between lower acoustic modes and higher optical modes combined with the observed strong Fermi nesting features in the system. - Highlights: • Transverse acoustic (TA 2 ) modes show anomaly along [211] direction in Ni 2 FeGa. • The phonon anomaly wavevector has been correlated with the Fermi nesting vectors. • Electron-phonon coupling calculation shows significant coupling in this system. • Max. el-ph coupling occurs in transition frequencies from acoustic to optical modes

  8. Phonon dynamics of the Sn/Ge(111)-(3 x 3) surface

    International Nuclear Information System (INIS)

    Farias, D.; Kaminski, W.; Lobo, J.; Ortega, J.; Hulpke, E.; Perez, R.; Flores, F.; Michel, E.G.

    2004-01-01

    We present a theoretical and experimental study on the phonon dynamics of the low-temperature Sn/Ge(111)-(3 x 3) structure. High-resolution helium atom scattering (HAS) data show that, besides the Rayleigh wave, there are three surface phonon branches with low dispersion related to the (3 x 3) surface phase. Their energies are approximately 6.5, 4, and 3meV at the Γ-bar point. In addition, we detect phonon peaks in the Q range 0.4-0.5A -1 at ∼2meV, which correspond to (3 x 3) folding of the Rayleigh wave. Ab initio DFT-GGA total energy calculations have been performed to determine the frequencies associated with the vertical displacements of the three Sn atoms in the unit cell. The values obtained are in good agreement with the experiment

  9. Surface dependent behaviour of CdS LO-phonon mode

    International Nuclear Information System (INIS)

    Molina-Contreras, J R; Medina-Gutierrez, C; Frausto-Reyes, C; Trejo-Vazquez, R; Villalobos-Pina, F J; Romo-Luevano, G; Calixto, S

    2007-01-01

    In this paper, we develop a sensitive optical method to monitor the surface roughness in the investigation of surfaces. By applying this method to measure the RMS surface roughness of various surfaces, we found RMS values which are comparable to those obtained by atomic force microscopy measurements. In addition, we present a simple empirical model to calculate the RMS surface roughness which shows very good agreement with the surface roughness measurements taken by the method reported in this paper. Finally, the application of our method to the study of the LO-phonon mode of CdS suggests that its intensity is dominated by the surface roughness. This roughness dependent behaviour of the CdS LO-phonon mode is experimentally confirmed by using an excitation wavelength near its E 0 transition

  10. Surface dependent behaviour of CdS LO-phonon mode

    Energy Technology Data Exchange (ETDEWEB)

    Molina-Contreras, J R [Departamento de IngenierIa Electrica y Electronica, Instituto Tecnologico de Aguascalientes, Av. Lopez Mateos 1081 Oriente, Fracc. Bonna Gens, CP 20256. Aguascalientes, Ags. (Mexico); Medina-Gutierrez, C [Universidad de Guadalajara, Centro Universitario de los Lagos, Av. Enrique DIaz de Leon s/n, Fracc. Paseos de la Montana, CP 47460, Lagos de Moreno, Jal. (Mexico); Frausto-Reyes, C [Centro de Investigaciones en Optica AC, Unidad Aguascalientes, Prolong., Constitucion 607, Fracc. Reserva Loma Bonita, CP 20200, Apartado Postal 507, Ags. (Mexico); Trejo-Vazquez, R [Departamento de IngenierIa Electrica y Electronica, Instituto Tecnologico de Aguascalientes, Av. Lopez Mateos 1081 Oriente, Fracc. Bonna Gens, CP 20256. Aguascalientes, Ags. (Mexico); Villalobos-Pina, F J [Departamento de IngenierIa Electrica y Electronica, Instituto Tecnologico de Aguascalientes, Av. Lopez Mateos 1081 Oriente, Fracc. Bonna Gens, CP 20256. Aguascalientes, Ags. (Mexico); Romo-Luevano, G [Intel TecnologIa de Mexico, SA de CV, Systems Research Center-Mexico, Parque Industrial Tecnologico II, Periferico Sur 7980, edificio 4-E, 45600 Tlaquepaque, Jalisco (Mexico); Calixto, S [Centro de Investigaciones en Optica, AC, Loma del Bosque 115, Colonia Lomas del Campestre, CP 37150 Leon, Guanajuato (Mexico)

    2007-08-21

    In this paper, we develop a sensitive optical method to monitor the surface roughness in the investigation of surfaces. By applying this method to measure the RMS surface roughness of various surfaces, we found RMS values which are comparable to those obtained by atomic force microscopy measurements. In addition, we present a simple empirical model to calculate the RMS surface roughness which shows very good agreement with the surface roughness measurements taken by the method reported in this paper. Finally, the application of our method to the study of the LO-phonon mode of CdS suggests that its intensity is dominated by the surface roughness. This roughness dependent behaviour of the CdS LO-phonon mode is experimentally confirmed by using an excitation wavelength near its E{sub 0} transition.

  11. Stress Induced Phononic Properties and Surface Waves in 2D Model of Auxetic Crystal

    International Nuclear Information System (INIS)

    Trzupek, D.; Twarog, D.; Zielinski, P.

    2009-01-01

    Elastic stiffness parameters are determined in a 2D model system of rigid rods interacting by harmonic force constants. Any positive ('' normal '' crystal) or negative (auxetic crystal) Poisson ratio can be obtained in this model as a function of the external stress. Conditions for opening an absolute stop band (phononic crystal) and for various kinds of surface waves are obtained. (authors)

  12. Orbital dependent Rashba splitting and electron-phonon coupling of 2D Bi phase on Cu(100) surface

    Energy Technology Data Exchange (ETDEWEB)

    Gargiani, Pierluigi; Lisi, Simone; Betti, Maria Grazia [Dipartimento di Fisica, Università di Roma “La Sapienza,” Piazzale A. Moro 5, I-00185 Roma (Italy); Ibrahimi, Amina Taleb; Bertran, François; Le Fèvre, Patrick [Synchrotron SOLEIL, Saint-Aubin-BP 48, F-91192 Gif sur Yvette (France); Chiodo, Letizia [Center for Life Nano Science - Sapienza, Istituto Italiano di Tecnologia and European Theoretical Spectroscopy Facility (ETSF), Viale Regina Elena 291, I-00161, Roma (Italy)

    2013-11-14

    A monolayer of bismuth deposited on the Cu(100) surface forms a highly ordered c(2×2) reconstructed phase. The low energy single particle excitations of the c(2×2) Bi/Cu(100) present Bi-induced states with a parabolic dispersion in the energy region close to the Fermi level, as observed by angle-resolved photoemission spectroscopy. The electronic state dispersion, the charge density localization, and the spin-orbit coupling have been investigated combining photoemission spectroscopy and density functional theory, unraveling a two-dimensional Bi phase with charge density well localized at the interface. The Bi-induced states present a Rashba splitting, when the charge density is strongly localized in the Bi plane. Furthermore, the temperature dependence of the spectral density close to the Fermi level has been evaluated. Dispersive electronic states offer a large number of decay channels for transitions coupled to phonons and the strength of the electron-phonon coupling for the Bi/Cu(100) system is shown to be stronger than for Bi surfaces and to depend on the electronic state symmetry and localization.

  13. Spectral Trends of Titan's Tropical Surface

    Science.gov (United States)

    Griffith, Caitlin Ann; Penteado, Paulo F.; Turner, Jake; Montiel, Nicholas; Schoenfeld, Ashley; Lopes, Rosaly M. C.; Soderblom, Laurence A.; Neish, Catherine; Radebaugh, Jani

    2016-10-01

    Titan's surface can be observed most clearly at 8 spectral regions that lie in between the strong methane bands in Titan's spectrum. Within these "windows", between 0.9 to 5 microns, the surface is nonetheless obscured by methane and haze, the latter of which is optically thick at lower wavelengths. Thus studies of Titan's surface must eliminate the effects of atmospheric extinction and extract the subtle spectral features that underlie the dominant spectral trends.To determine the subtle spectral features of Titan's tropical surface (30S--30N) we conducted a Principal Components Analysis (PCA) of the I/F at the 1.1, 1.3, 1.6 and 2.0 um wavelength windows, recorded by Cassini/VIMS. The PCA analysis identifies the spectral trend that defines the highest variance in the data (the principal component), as well as successively weaker orthogonal trends, without a priori assumptions about the surface composition, e.g. as needed in radiative transfer analyses.Our analysis derives the spectral features at the four wavelengths that describe Titan's tropical surface. We detect a large almost contiguous region that extends roughly 160 degrees in longitude and which exhibits absorption features at 1.6 and 2.0, as well as 2.8 um (characteristic of water ice). This vast and perhaps tectonic feature is, in part, associated with terrain that is hypothesized to be some of the oldest surfaces on Titan. In addition, the PCA analysis indicates at least 2 separate organic spectra signatures, potentially due to the separation of liquid and refractory sediments or to their chemically alteration over time. Here we discuss the PCA analysis and compare our derived compositional maps of Titan's surface with Radar maps of the topography and morphology, to entertain questions regarding the geology of Titan's surface the age of its atmosphere.

  14. Terahertz instability of surface optical-phonon polaritons that interact with surface plasmon polaritons in the presence of electron drift

    International Nuclear Information System (INIS)

    Sydoruk, O.; Solymar, L.; Shamonina, E.; Kalinin, V.

    2010-01-01

    Traveling-wave interaction between optical phonons and electrons drifting in diatomic semiconductors has potential for amplification and generation of terahertz radiation. Existing models of this interaction were developed for infinite materials. As a more practically relevant configuration, we studied theoretically a finite semiconductor slab surrounded by a dielectric. This paper analyzes the optical-phonon instability in the slab including the Lorentz force and compares it to the instability in an infinite material. As the analysis shows, the slab instability occurs because of the interaction of surface optical-phonon polaritons with surface plasmon polaritons in the presence of electron drift. The properties of the instability depend on the slab thickness when the thickness is comparable to the wavelength. For large slab thicknesses, however, the dispersion relation of the slab is similar to that of an infinite material, although the coupling is weaker. The results could be used for the design of practical terahertz traveling-wave oscillators and amplifiers.

  15. A Numerical Study on Phonon Spectral Contributions to Thermal Conduction in Silicon-on-Insulator Transistor Using Electron-Phonon Interaction Model

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Hyung-sun; Koh, Young Ha; Jin, Jae Sik [Chosun College of Science and Technology, Gwangju (Korea, Republic of)

    2017-06-15

    The aim of this study is to understand the phonon transfer characteristics of a silicon thin film transistor. For this purpose, the Joule heating mechanism was considered through the electron-phonon interaction model whose validation has been done. The phonon transport characteristics were investigated in terms of phonon mean free path for the variations in the device power and silicon layer thickness from 41 nm to 177 nm. The results may be used for developing the thermal design strategy for achieving reliability and efficiency of the silicon-on-insulator (SOI) transistor, further, they will increase the understanding of heat conduction in SOI systems, which are very important in the semiconductor industry and the nano-fabrication technology.

  16. Spectral emissivity of surface blackbody calibrators

    DEFF Research Database (Denmark)

    Clausen, Sønnik

    2007-01-01

    in emissivity using similar materials can be reduced to 0.5-1% by optimizing the coating process and the surface geometry. Results are discussed and an equation for calculation of the equivalent blackbody surface temperature from FTIR spectra is presented, including reflected ambient radiation. It is in most......The normal spectral emissivity of commercial infrared calibrators is compared with measurements of anodized aluminum samples and grooved aluminum surfaces coated with Pyromark. Measurements performed by FTIR spectroscopy in the wavelength interval from 2 to 20 mu m and at temperatures between 5...... and 550 degrees C are presented with absolute uncertainties from 0.25% to 1% in spectral regions with sufficient signal and no significant atmospheric gas absorption. A large variation in emissivity with wavelength is observed for some surfaces, i.e., from 1% to 3% to more than 10%. The variation...

  17. Surface acoustic waves in finite slabs of three-dimensional phononic crystals

    OpenAIRE

    Sainidou, R.; Djafari-Rouhani, B.; Vasseur, J. O.

    2008-01-01

    We study theoretically, by means of layer-multiple-scattering techniques, the propagation of elastic waves through finite slabs of phononic crystals consisting of metallic spheres in a polyester matrix, embedded in air. In particular, we focus on the study of modes localized on the surfaces of the structure. Their origin and behavior, as well as the physical parameters that influence and determine their appearance, are investigated in detail. Our results reveal the existence of absolute phono...

  18. Observation of surface-guided waves in holey hypersonic phononic crystal

    Science.gov (United States)

    Benchabane, Sarah; Gaiffe, Olivier; Ulliac, Gwenn; Salut, Roland; Achaoui, Younes; Laude, Vincent

    2011-04-01

    We observe experimentally the propagation of surface-guided waves in a hypersonic phononic crystal, both in the radiative and nonradiative regions of the spectrum. Combining electrical measurements in reflection and transmission as well as optical maps of the surface displacement, a band gap extending from 0.6 to 0.95 GHz is identified in a square lattice array of 1 μm radius air holes milled in lithium niobate. The optical measurements reveal the transmission of surface-guided waves above the band gap, well inside the sound cone.

  19. Optimizing phonon scattering by tuning surface-interdiffusion-driven intermixing to break the random-alloy limit of thermal conductivity

    Science.gov (United States)

    Yang, Xiaolong; Li, Wu

    2018-01-01

    We investigate the evolution of the cross-plane thermal conductivity κ of superlattices (SLs) as interfaces change from perfectly abrupt to totally intermixed, by using nonequilibrium molecular dynamics simulations in combination with the spectral heat current calculations. We highlight the role of surface-interdiffusion-driven intermixing by calculating the κ of SLs with changing interface roughness, whose tuning allows for κ values much lower than the "alloy limit" and the abrupt interface limit in same cases. The interplay between alloy and interface scattering in different frequency ranges provides a physical basis to predict a minimum of thermal conductivity. More specifically, we also explore how the interface roughness affects the thermal conductivities for SL materials with a broad span of atomic mass and bond strength. In particular, we find that (i) only when the "spacer" thickness of SLs increases up to a critical value, κ of rough SLs can break the corresponding "alloy limit," since SLs with different "spacer" thickness have different characteristic length of phonon transport, which is influenced by surface-interdiffusion-driven intermixing to different extend. (ii) Whether κ changes monotonically with interface roughness strongly depends on the period length and intrinsic behavior of phonon transport for SL materials. Especially, for the SL with large period length, there exists an optimal interface roughness that can minimize the thermal conductivity. (iii) Surface-interdiffusion-driven intermixing is more effective in achieving a low κ below the alloy limit for SL materials with large mass mismatch than with small one. (iv) It is possible for SL materials with large lattice mismatch (i.e., bond strength) to design an ideally abrupt interface structure with κ much below the alloy limit. These results have clear implications for optimization of thermal transport for heat management and for the development of thermoelectric materials.

  20. Infrared spectral reflectances of asteroid surfaces

    Science.gov (United States)

    Larson, H. P.; Veeder, G. J.

    1979-01-01

    This review compares the types of compositional information produced by three complementary techniques used in infrared observations of asteroid surfaces: broadband JHKL photometry, narrow band photometry, and multiplex spectroscopy. The high information content of these infrared observations permits definitive interpretations of asteroid surface compositions in terms of the major meteoritic minerals (olivine, pyroxene, plagioclase feldspar, hydrous silicates, and metallic Ni-Fe). These studies emphasize the individuality of asteroid surface compositions, the inadequacy of simple comparisons with spectra of meteorites, and the need to coordinate spectral measurements of all types to optimize diagnostic capabilities.

  1. Surface optical phonons in GaAs nanowires grown by Ga-assisted chemical beam epitaxy

    Energy Technology Data Exchange (ETDEWEB)

    García Núñez, C., E-mail: carlos.garcia@uam.es; Braña, A. F.; Pau, J. L.; Ghita, D.; García, B. J. [Grupo de Electrónica y Semiconductores, Departamento de Física Aplicada, Universidad Autónoma de Madrid, 28049 Madrid (Spain); Shen, G.; Wilbert, D. S.; Kim, S. M.; Kung, P. [Department of Electrical and Computer Engineering, The University of Alabama, Tuscaloosa, Alabama 35487 (United States)

    2014-01-21

    Surface optical (SO) phonons were studied by Raman spectroscopy in GaAs nanowires (NWs) grown by Ga-assisted chemical beam epitaxy on oxidized Si(111) substrates. NW diameters and lengths ranging between 40 and 65 nm and between 0.3 and 1.3 μm, respectively, were observed under different growth conditions. The analysis of the Raman peak shape associated to either longitudinal or surface optical modes gave important information about the crystal quality of grown NWs. Phonon confinement model was used to calculate the density of defects as a function of the NW diameter resulting in values between 0.02 and 0.03 defects/nm, indicating the high uniformity obtained on NWs cross section size during growth. SO mode shows frequency downshifting as NW diameter decreases, this shift being sensitive to NW sidewall oxidation. The wavevector necessary to activate SO phonon was used to estimate the NW facet roughness responsible for SO shift.

  2. Surface acoustic waves in two dimensional phononic crystal with anisotropic inclusions

    Directory of Open Access Journals (Sweden)

    Ketata H.

    2012-06-01

    Full Text Available An analysis is given to the band structure of the two dimensional solid phononic crystal considered as a semi infinite medium. The lattice includes an array of elastic anisotropic materials with different shapes embedded in a uniform matrix. For illustration two kinds of phononic materials are assumed. A particular attention is devoted to the computational procedure which is mainly based on the plane wave expansion (PWE method. It has been adapted to Matlab environment. Numerical calculations of the dispersion curves have been achieved by introducing particular functions which transform motion equations into an Eigen value problem. Significant improvements are obtained by increasing reasonably the number of Fourier components even when a large elastic mismatch is assumed. Such approach can be generalized to different types of symmetry and permit new physical properties as piezoelectricity to be added. The actual semi infinite phononic structure with a free surface has been shown to support surface acoustic waves (SAW. The obtained dispersion curves reveal band gaps in the SAW branches. It has been found that the influence, of the filling factor and anisotropy on their band gaps, is different from that of bulk waves.

  3. Evanescent coupling between surface and linear-defect guided modes in phononic crystals

    Science.gov (United States)

    Cicek, Ahmet; Salman, Aysevil; Adem Kaya, Olgun; Ulug, Bulent

    2016-01-01

    Evanescent coupling between surface and linear-defect waveguide modes in a two-dimensional phononic crystal of steel cylinders in air is numerically demonstrated. When the ratio of scatterer radii to the lattice constant is set to 0.47 in the square phononic crystal, the two types of modes start interacting if there is one-row separation between the surface and waveguide. Supercell band structure computations through the Finite Element Method suggest that the waveguide band is displaced significantly, whereas the surface band remains almost intact when the waveguide and surface are in close proximity. The two resultant hybrid bands are such that the coupling length, which varies between 8 and 22 periods, initially changes linearly with frequency, while a much sharper variation is observed towards the top of the lower hybrid band. Such small values facilitate the design of compact devices based on heterogeneous coupling. Finite-element simulations demonstrate bilateral coupling behaviour, where waves incident from either the surface or waveguide can efficiently couple to the other side. The coupling lengths calculated from simulation results are in agreement with the values predicted from the supercell band structure. The possible utilisation of the coupling scheme in sensing applications, especially in acoustic Doppler velocimetry, is discussed.

  4. SURFACE ALBEDO AND SPECTRAL VARIABILITY OF CERES

    Energy Technology Data Exchange (ETDEWEB)

    Li, Jian-Yang; Reddy, Vishnu; Corre, Lucille Le; Sykes, Mark V.; Prettyman, Thomas H. [Planetary Science Institute, 1700 E. Ft. Lowell Road, Suite 106, Tucson, AZ 85719 (United States); Nathues, Andreas; Hoffmann, Martin; Schaefer, Michael [Max Planck Institute for Solar System Research, Göttingen (Germany); Izawa, Matthew R. M.; Cloutis, Edward A. [University of Winnipeg, Winnipeg, Manitoba (Canada); Carsenty, Uri; Jaumann, Ralf; Krohn, Katrin; Mottola, Stefano; Schröder, Stefan E. [German Aerospace Center (DLR), Institute of Planetary Research, Berlin (Germany); Castillo-Rogez, Julie C. [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States); Schenk, Paul [Lunar and Planetary Institute, Houston, TX 77058 (United States); Williams, David A. [School of Earth and Space Exploration, Arizona State University, Tempe, AZ 85287 (United States); Smith, David E. [Solar System Exploration Division, NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Zuber, Maria T. [Department of Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); and others

    2016-02-01

    Previous observations suggested that Ceres has active, but possibly sporadic, water outgassing as well as possibly varying spectral characteristics over a timescale of months. We used all available data of Ceres collected in the past three decades from the ground and the Hubble Space Telescope, as well as the newly acquired images by the Dawn  Framing Camera, to search for spectral and albedo variability on Ceres, on both a global scale and in local regions, particularly the bright spots inside the Occator crater, over timescales of a few months to decades. Our analysis has placed an upper limit on the possible temporal albedo variation on Ceres. Sporadic water vapor venting, or any possibly ongoing activity on Ceres, is not significant enough to change the albedo or the area of the bright features in the Occator crater by >15%, or the global albedo by >3% over the various timescales that we searched. Recently reported spectral slope variations can be explained by changing Sun–Ceres–Earth geometry. The active area on Ceres is less than 1 km{sup 2}, too small to cause global albedo and spectral variations detectable in our data. Impact ejecta due to impacting projectiles of tens of meters in size like those known to cause observable changes to the surface albedo on Asteroid Scheila cannot cause detectable albedo change on Ceres due to its relatively large size and strong gravity. The water vapor activity on Ceres is independent of Ceres’ heliocentric distance, ruling out the possibility of the comet-like sublimation process as a possible mechanism driving the activity.

  5. Measurement of surface phonon dispersion relations for LiF, NaF, and KCl through energy-analysed inelastic scattering of a helium atomic beam

    International Nuclear Information System (INIS)

    Doak, R.B.

    1981-01-01

    A crystal surface terminates abruptly one dimension of lattice periodicity, constituting a lattice defect with concomitant localized modes of vibration, termed surface phonons. Such surface phonons have previously been investigated in the long wavelength, non-dispersive regime. The present work reports the first observation of surface phonons in the short wavelength, dispersive range. The data allow for the first time a surface phonon dispersion curve to be plotted completely from origin to edge of the surface Brillouin zone. Measurements were made of phonons along the (anti GAMMA anti M) and (anti GAMMA anti X) azimuths of the LiF(001) surface and along the azimuth of NaF(001) and KC1(001) surfaces. The results are in substantial agreement with theoretical predictions, although for LiF the measured Rayleigh dispersion curve at M lies appreciably below the theoretical value, possibly reflecting the effects of surface relaxation. (orig.)

  6. Phonon-mediated decay of an atom in a surface-induced potential

    International Nuclear Information System (INIS)

    Kien, Fam Le; Hakuta, K.; Dutta Gupta, S.

    2007-01-01

    We study phonon-mediated transitions between translational levels of an atom in a surface-induced potential. We present a general master equation governing the dynamics of the translational states of the atom. In the framework of the Debye model, we derive compact expressions for the rates for both upward and downward transitions. Numerical calculations for the transition rates are performed for a deep silica-induced potential allowing for a large number of bound levels as well as free states of a cesium atom. The total absorption rate is shown to be determined mainly by the bound-to-bound transitions for deep bound levels and by bound-to-free transitions for shallow bound levels. Moreover, the phonon emission and absorption processes can be orders of magnitude larger for deep bound levels as compared to the shallow bound ones. We also study various types of transitions from free states. We show that, for thermal atomic cesium with a temperature in the range from 100 μK to 400 μK in the vicinity of a silica surface with a temperature of 300 K, the adsorption (free-to-bound decay) rate is about two times larger than the heating (free-to-free upward decay) rate, while the cooling (free-to-free downward decay) rate is negligible

  7. Emission Spectral Control of a Silicon Light Emitting Diode Fabricated by Dressed-Photon-Phonon Assisted Annealing Using a Short Pulse Pair

    Directory of Open Access Journals (Sweden)

    Tadashi Kawazoe

    2014-01-01

    Full Text Available We fabricated a high-efficiency infrared light emitting diode (LED via dressed-photon-phonon (DPP assisted annealing of a p-n homojunctioned bulk Si crystal. The center wavelength in the electroluminescence (EL spectrum of this LED was determined by the wavelength of a CW laser used in the DPP-assisted annealing. We have proposed a novel method of controlling the EL spectral shape by additionally using a pulsed light source in order to control the number of phonons for the DPP-assisted annealing. In this method, the Si crystal is irradiated with a pair of pulses having an arrival time difference between them. The number of coherent phonons created is increased (reduced by tuning (detuning this time difference. A Si-LED was subjected to DPP-assisted annealing using a 1.3 μm (hν=0.94 eV CW laser and a mode-locked pulsed laser with a pulse width of 17 fs. When the number of phonons was increased, the EL emission spectrum broadened toward the high-energy side by 200 meV or more. The broadening towards the low-energy side was reduced to 120 meV.

  8. Size and environment dependence of surface phonon modes of gallium arsenide nanowires as measured by Raman spectroscopy.

    Science.gov (United States)

    Spirkoska, D; Abstreiter, G; Fontcuberta I Morral, A

    2008-10-29

    Gallium arsenide nanowires were synthesized by gallium-assisted molecular beam epitaxy. By varying the growth time, nanowires with diameters ranging from 30 to 160 nm were obtained. Raman spectra of the nanowire ensembles were measured. The small linewidth of the optical phonon modes agree with an excellent crystalline quality. A surface phonon mode was also revealed, as a shoulder at lower frequencies of the longitudinal optical mode. In agreement with the theory, the surface mode shifts to lower wavenumbers when the diameter of the nanowires is decreased or the environment dielectric constant increased.

  9. Nano-imaging and nano-spectroscopy of tunable surface phonon polaritons in hexagonal boron nitride

    Science.gov (United States)

    Dai, Siyuan; Fei, Zhe; Ma, Qiong; Rodin, Aleksandr; Wagner, Martin; McLeod, Alexander; Liu, Mengkun; Gannett, Will; Regan, William; Thiemens, Mark; Dominguez, Gerardo; Castro Neto, Antonio; Zettl, Alex; Keilmann, Fritz; Jarillo-Herrero, Pablo; Fogler, Michael; Basov, Dimitri

    2014-03-01

    Van der Waals crystals such as graphene, topological insulators, cuprate high-temperature superconductors, and many other layered structures reveal a rich variety of enigmatic electronic, photonic and magnetic properties. We report infrared (IR) nano-imaging of surface phonon polaritons in a prototypical van-der-Waals crystal: hexagonal boron nitride (hBN). In the setting of an antenna-based IR spectroscopic nanoscope, we accomplished launching, detecting, and real space imaging of the polaritonic waves. We were able to alter both the wavelength and the amplitude of such waves by varying the number of crystal layers in our specimens. We demonstrated a new nano-photonics method for mapping the polariton dispersion. The dispersion is shown to be governed by the crystal thickness according to a scaling law that persists down to a few monolayers. Our results point to novel functionalities of van-der-Waals crystals as reconfigurable nano-photonic materials.

  10. Surface effect on band structure of flexural wave propagating in magneto-elastic phononic crystal nanobeam

    International Nuclear Information System (INIS)

    Zhang, Shunzu; Gao, Yuanwen

    2017-01-01

    A theoretical model is established to study the size-dependent performance of flexural wave propagation in magneto-elastic phononic crystal (PC) nanobeam with surface effect based on Euler–Bernoulli beam theory and Gurtin–Murdoch theory. Considering the magneto-mechanical coupling constitutive relation of magnetostrictive material, the influence of surface effect on band structure is calculated by the plane wave expansion method for PC nanobeam subjected to pre-stress and magnetic field loadings. Through the example of an epoxy/Terfenol-D PC nanobeam, it can be observed that the characteristics of flexural wave band structures are size-dependent, and remarkably affected by surface effect when the dimension of the PC beam reduces to the nanoscale. The edges and width of the band gap with surface effect are higher than those without surface effect, especially for high frequency region. And surface effect gradually reduces with the increasing of bulk layer-to-surface layer thickness ratio until the band gap descends to a constant for the conventional one in the absence of surface effect. The effects of surface elasticity and piezomagneticity on band gap are more prominent than the residual surface stress. In addition, a distinctly nonlinear variation of band gap appears under the combined effects of pre-stress and magnetic field. Moreover, with the varying of filling fraction, multi-peaks of the width of the band gap are obtained and discussed. These results could be helpful for the intelligent regulation of magneto-elastic PC nanobeam and the design of nanobeam-based devices. (paper)

  11. Surface effect on band structure of flexural wave propagating in magneto-elastic phononic crystal nanobeam

    Science.gov (United States)

    Zhang, Shunzu; Gao, Yuanwen

    2017-11-01

    A theoretical model is established to study the size-dependent performance of flexural wave propagation in magneto-elastic phononic crystal (PC) nanobeam with surface effect based on Euler-Bernoulli beam theory and Gurtin-Murdoch theory. Considering the magneto-mechanical coupling constitutive relation of magnetostrictive material, the influence of surface effect on band structure is calculated by the plane wave expansion method for PC nanobeam subjected to pre-stress and magnetic field loadings. Through the example of an epoxy/Terfenol-D PC nanobeam, it can be observed that the characteristics of flexural wave band structures are size-dependent, and remarkably affected by surface effect when the dimension of the PC beam reduces to the nanoscale. The edges and width of the band gap with surface effect are higher than those without surface effect, especially for high frequency region. And surface effect gradually reduces with the increasing of bulk layer-to-surface layer thickness ratio until the band gap descends to a constant for the conventional one in the absence of surface effect. The effects of surface elasticity and piezomagneticity on band gap are more prominent than the residual surface stress. In addition, a distinctly nonlinear variation of band gap appears under the combined effects of pre-stress and magnetic field. Moreover, with the varying of filling fraction, multi-peaks of the width of the band gap are obtained and discussed. These results could be helpful for the intelligent regulation of magneto-elastic PC nanobeam and the design of nanobeam-based devices.

  12. Anisotropic surface acoustic waves in tungsten/lithium niobate phononic crystals

    Science.gov (United States)

    Sun, Jia-Hong; Yu, Yuan-Hai

    2018-02-01

    Phononic crystals (PnC) were known for acoustic band gaps for different acoustic waves. PnCs were already applied in surface acoustic wave (SAW) devices as reflective gratings based on the band gaps. In this paper, another important property of PnCs, the anisotropic propagation, was studied. PnCs made of circular tungsten films on a lithium niobate substrate were analyzed by finite element method. Dispersion curves and equal frequency contours of surface acoustic waves in PnCs of various dimensions were calculated to study the anisotropy. The non-circular equal frequency contours and negative refraction of group velocity were observed. Then PnC was applied as an acoustic lens based on the anisotropic propagation. Trajectory of SAW passing PnC lens was calculated and transmission of SAW was optimized by selecting proper layers of lens and applying tapered PnC. The result showed that PnC lens can suppress diffraction of surface waves effectively and improve the performance of SAW devices.

  13. The Effects of Different Electron-Phonon Couplings on the Spectral and Transport Properties of Small Molecule Single-Crystal Organic Semiconductors

    Directory of Open Access Journals (Sweden)

    Carmine Antonio Perroni

    2014-03-01

    Full Text Available Spectral and transport properties of small molecule single-crystal organic semiconductors have been theoretically analyzed focusing on oligoacenes, in particular on the series from naphthalene to rubrene and pentacene, aiming to show that the inclusion of different electron-phonon couplings is of paramount importance to interpret accurately the properties of prototype organic semiconductors. While in the case of rubrene, the coupling between charge carriers and low frequency inter-molecular modes is sufficient for a satisfactory description of spectral and transport properties, the inclusion of electron coupling to both low-frequency inter-molecular and high-frequency intra-molecular vibrational modes is needed to account for the temperature dependence of transport properties in smaller oligoacenes. For rubrene, a very accurate analysis in the relevant experimental configuration has allowed for the clarification of the origin of the temperature-dependent mobility observed in these organic semiconductors. With increasing temperature, the chemical potential moves into the tail of the density of states corresponding to localized states, but this is not enough to drive the system into an insulating state. The mobility along different crystallographic directions has been calculated, including vertex corrections that give rise to a transport lifetime one order of magnitude smaller than the spectral lifetime of the states involved in the transport mechanism. The mobility always exhibits a power-law behavior as a function of temperature, in agreement with experiments in rubrene. In systems gated with polarizable dielectrics, the electron coupling to interface vibrational modes of the gate has to be included in addition to the intrinsic electron-phonon interaction. While the intrinsic bulk electron-phonon interaction affects the behavior of mobility in the coherent regime below room temperature, the coupling with interface modes is dominant for the

  14. Surface defects characterization in a quantum wire by coherent phonons scattering

    Energy Technology Data Exchange (ETDEWEB)

    Rabia, M. S. [Laboratoire de Mécanique des Structures et Energétique, Faculté du Génie de la Construction, Université. Mammeri de Tizi-Ouzou, BP 17 RP Hasnaoua II, Tizi-Ouzou 15000, Algérie m2msr@yahoo.fr (Algeria)

    2015-03-30

    The influence of surface defects on the scattering properties of elastic waves in a quasi-planar crystallographic waveguide is studied in the harmonic approximation using the matching method formalism. The structural model is based on three infinite atomic chains forming a perfect lattice surmounted by an atomic surface defect. Following the Landauer approach, we solve directly the Newton dynamical equation with scattering boundary conditions and taking into account the next nearest neighbour’s interaction. A detailed study of the defect-induced fluctuations in the transmission spectra is presented for different adatom masses. As in the electronic case, the presence of localized defect-induced states leads to Fano-like resonances. In the language of mechanical vibrations, these are called continuum resonances. Numerical results reveal the intimate relation between transmission spectra and localized defect states and provide a basis for the understanding of conductance spectroscopy experiments in disordered mesoscopic systems. The results could be useful for the design of phononic devices.

  15. Surface defects characterization in a quantum wire by coherent phonons scattering

    International Nuclear Information System (INIS)

    Rabia, M. S.

    2015-01-01

    The influence of surface defects on the scattering properties of elastic waves in a quasi-planar crystallographic waveguide is studied in the harmonic approximation using the matching method formalism. The structural model is based on three infinite atomic chains forming a perfect lattice surmounted by an atomic surface defect. Following the Landauer approach, we solve directly the Newton dynamical equation with scattering boundary conditions and taking into account the next nearest neighbour’s interaction. A detailed study of the defect-induced fluctuations in the transmission spectra is presented for different adatom masses. As in the electronic case, the presence of localized defect-induced states leads to Fano-like resonances. In the language of mechanical vibrations, these are called continuum resonances. Numerical results reveal the intimate relation between transmission spectra and localized defect states and provide a basis for the understanding of conductance spectroscopy experiments in disordered mesoscopic systems. The results could be useful for the design of phononic devices

  16. Unsupervised Classification of Mercury's Surface Spectral and Chemical Characteristics

    Science.gov (United States)

    D'Amore, M.; Helbert, J.; Ferrari, S.; Maturilli, A.; Nittler, L. R.; Domingue, D. L.; Vilas, F.; Weider, S. Z.; Starr, R. D.; Crapster-Pregont, E. J.; Ebel, D. S.; Solomon, S. C.

    2014-12-01

    The spectral reflectance of Mercury's surface has been mapped in the 400-1145 nm wavelength range by the Mercury Atmospheric and Surface Composition Spectrometer (MASCS) instrument during orbital observations by the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft. Under the hypothesis that surface compositional information can be efficiently derived from such spectral measurements with the use of statistical techniques, we have conducted unsupervised hierarchical clustering analyses to identify and characterize spectral units from MASCS observations. The results display a large-scale dichotomy, with two spectrally distinct units: polar and equatorial, possibly linked to differences in surface environment or composition. The spatial extent of the polar unit in the northern hemisphere correlates approximately with that of the northern volcanic plains. To explore possible relations between composition and spectral behavior, we have compared the spectral units with elemental abundance maps derived from MESSENGER's X-Ray Spectrometer (XRS). It is important to note that the mapping coverage for XRS differs from that of MASCS, particularly for the heavy elements. Nonetheless, by comparing the visible and near-infrared MASCS and XRS datasets and investigating the links between them, we seek further clues to the formation and evolution of Mercury's crust. Moreover, the methodology will permit automation of the production of new maps of the spectral and chemical signature of the surface.

  17. Phonon engineering for nanostructures.

    Energy Technology Data Exchange (ETDEWEB)

    Aubry, Sylvie (Stanford University); Friedmann, Thomas Aquinas; Sullivan, John Patrick; Peebles, Diane Elaine; Hurley, David H. (Idaho National Laboratory); Shinde, Subhash L.; Piekos, Edward Stanley; Emerson, John Allen

    2010-01-01

    Understanding the physics of phonon transport at small length scales is increasingly important for basic research in nanoelectronics, optoelectronics, nanomechanics, and thermoelectrics. We conducted several studies to develop an understanding of phonon behavior in very small structures. This report describes the modeling, experimental, and fabrication activities used to explore phonon transport across and along material interfaces and through nanopatterned structures. Toward the understanding of phonon transport across interfaces, we computed the Kapitza conductance for {Sigma}29(001) and {Sigma}3(111) interfaces in silicon, fabricated the interfaces in single-crystal silicon substrates, and used picosecond laser pulses to image the thermal waves crossing the interfaces. Toward the understanding of phonon transport along interfaces, we designed and fabricated a unique differential test structure that can measure the proportion of specular to diffuse thermal phonon scattering from silicon surfaces. Phonon-scale simulation of the test ligaments, as well as continuum scale modeling of the complete experiment, confirmed its sensitivity to surface scattering. To further our understanding of phonon transport through nanostructures, we fabricated microscale-patterned structures in diamond thin films.

  18. Plasmon-enhanced electron-phonon coupling in Dirac surface states of the thin-film topological insulator Bi{sub 2}Se{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Glinka, Yuri D., E-mail: ydglinka@mail.wvu.edu [Department of Physics and Astronomy, West Virginia University, Morgantown, West Virginia 26506-6315 (United States); Institute of Physics, National Academy of Sciences of Ukraine, Kiev 03028 (Ukraine); Babakiray, Sercan; Lederman, David [Department of Physics and Astronomy, West Virginia University, Morgantown, West Virginia 26506-6315 (United States)

    2015-10-07

    Raman measurements of a Fano-type surface phonon mode associated with Dirac surface states (SS) in Bi{sub 2}Se{sub 3} topological insulator thin films allowed an unambiguous determination of the electron-phonon coupling strength in Dirac SS as a function of film thickness ranging from 2 to 40 nm. A non-monotonic enhancement of the electron-phonon coupling strength with maximum for the 8–10 nm thick films was observed. The non-monotonicity is suggested to originate from plasmon-phonon coupling which enhances electron-phonon coupling when free carrier density in Dirac SS increases with decreasing film thickness and becomes suppressed for thinnest films when anharmonic coupling between in-plane and out-of-plane phonon modes occurs. The observed about four-fold enhancement of electron-phonon coupling in Dirac SS of the 8–10 nm thick Bi{sub 2}Se{sub 3} films with respect to the bulk samples may provide new insights into the origin of superconductivity in this-type materials and their applications.

  19. Theoretical study on photon-phonon coupling at (001)-(2 x 1) surfaces of Ge and {alpha}-Sn

    Energy Technology Data Exchange (ETDEWEB)

    Perez-Sanchez, F.L. [Escuela de Ciencias, Universidad Autonoma ' ' Benito Juarez' ' de Oaxaca, Av. Universidad S/N, Ex-Hacienda de Cinco Senores, Ciudad Universitaria, Oaxaca de Juarez, Oax., 68120 (Mexico); Perez-Rodriguez, F. [Instituto de Fisica, Benemerita Universidad Autonoma de Puebla, Apdo. Post. J-48, Puebla, Pue. 72570 (Mexico)

    2011-06-15

    We present a study of the far-infrared reflectance anisotropy spectra for (001) surfaces of Ge and {alpha}-Sn in the (2 x 1) asymmetric dimer geometry, which exhibit a resonance structure associated with the excitation of surface phonon modes. We have employed a theoretical formalism, based on the adiabatic bond-charge model (ABCM), for computing the far-infrared reflectance anisotropy spectra. In comparison with previous theoretical results for silicon and diamond surfaces, the resonance structure in the reflectance anisotropy spectrum for Ge(001)-(2 x 1) turns out to be similar to that observed in the spectrum for the Si(001)-(2 x 1) surface, whereas the spectrum for {alpha}-Sn(001)-(2 x 1) surface is noticeably different from the others. We have established a trend of far-infrared reflectance anisotropy spectra for IV(001) surfaces: the weaker dimer strength, the stronger resonances of low-frequency surface phonons. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  20. Phonon-eigenspectrum-based formulation of the atomistic Green's function method

    Science.gov (United States)

    Sadasivam, Sridhar; Waghmare, Umesh V.; Fisher, Timothy S.

    2017-11-01

    While the atomistic Green's function (AGF) method has the potential to compute spectrally resolved phonon transport across interfaces, most prior formulations of the AGF method provide only the total phonon transmission function that includes contributions from all phonon branches or channels. In this work, we present a formulation of the conventional AGF technique in terms of phonon eigenspectra that provides a natural decomposition of the total transmission function into contributions from various phonon modes. The method involves the use of Dyson and Lippmann-Schwinger equations to determine surface Green's functions from the phonon eigenspectrum of the bulk, and establishes a direct connection between the transmission function and the bulk phonon spectra of the materials forming the interface. We elucidate our formulation of the AGF technique through its application to a microscopic picture of phonon mode conversion at Si-Ge interfaces with atomic intermixing. Intermixing of atoms near the interface is shown to increase the phase space available for phonon mode conversion and to enhance thermal interface conductance at moderate levels of atomic mixing. The eigenspectrum-based AGF method should be useful in determination of microscopic mechanisms of phonon scattering and identification of the specific modes that dominate thermal transport across an interface.

  1. The spectral function for Mott insulating surfaces

    CERN Document Server

    Manuel, L O; Feiguin, A E; Trumper, A E

    2003-01-01

    We show theoretically the fingerprints of short-range spiral magnetic correlations in the photoemission spectra of the Mott insulating ground states realized in the sq root 3 x sq root 3 triangular silicon surfaces K/Si(111)-B and SiC(0001). The calculated spectra present low-energy features of magnetic origin with a reduced dispersion approx 10-40 meV compared with the centre-of-mass spectra bandwidth approx 0.2-0.3 eV. Remarkably, we find that the quasiparticle (QP) signal survives only around the magnetic Goldstone modes. Our findings position these silicon surfaces as new candidates for investigation in the search for non-conventional QP excitations.

  2. The spectral function for Mott insulating surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Manuel, L O [Instituto de Fisica Rosario (CONICET) and Universidad Nacional de Rosario, Boulevard 27 de Febrero 210 bis (2000) Rosario (Argentina); Gazza, C J [Instituto de Fisica Rosario (CONICET) and Universidad Nacional de Rosario, Boulevard 27 de Febrero 210 bis (2000) Rosario (Argentina); Feiguin, A E [Department of Physics and Astronomy, University of California, Irvine, CA 92697, USA (United States); Trumper, A E [Instituto de Fisica Rosario (CONICET) and Universidad Nacional de Rosario, Boulevard 27 de Febrero 210 bis (2000) Rosario (Argentina)

    2003-05-07

    We show theoretically the fingerprints of short-range spiral magnetic correlations in the photoemission spectra of the Mott insulating ground states realized in the {radical}3 x{radical} 3 triangular silicon surfaces K/Si(111)-B and SiC(0001). The calculated spectra present low-energy features of magnetic origin with a reduced dispersion {approx}10-40 meV compared with the centre-of-mass spectra bandwidth {approx}0.2-0.3 eV. Remarkably, we find that the quasiparticle (QP) signal survives only around the magnetic Goldstone modes. Our findings position these silicon surfaces as new candidates for investigation in the search for non-conventional QP excitations.

  3. The spectral function for Mott insulating surfaces

    International Nuclear Information System (INIS)

    Manuel, L O; Gazza, C J; Feiguin, A E; Trumper, A E

    2003-01-01

    We show theoretically the fingerprints of short-range spiral magnetic correlations in the photoemission spectra of the Mott insulating ground states realized in the √3 x√ 3 triangular silicon surfaces K/Si(111)-B and SiC(0001). The calculated spectra present low-energy features of magnetic origin with a reduced dispersion ∼10-40 meV compared with the centre-of-mass spectra bandwidth ∼0.2-0.3 eV. Remarkably, we find that the quasiparticle (QP) signal survives only around the magnetic Goldstone modes. Our findings position these silicon surfaces as new candidates for investigation in the search for non-conventional QP excitations

  4. Spectral theory of infinite-area hyperbolic surfaces

    CERN Document Server

    Borthwick, David

    2016-01-01

    This text introduces geometric spectral theory in the context of infinite-area Riemann surfaces, providing a comprehensive account of the most recent developments in the field. For the second edition the context has been extended to general surfaces with hyperbolic ends, which provides a natural setting for development of the spectral theory while still keeping technical difficulties to a minimum. All of the material from the first edition is included and updated, and new sections have been added. Topics covered include an introduction to the geometry of hyperbolic surfaces, analysis of the resolvent of the Laplacian, scattering theory, resonances and scattering poles, the Selberg zeta function, the Poisson formula, distribution of resonances, the inverse scattering problem, Patterson-Sullivan theory, and the dynamical approach to the zeta function. The new sections cover the latest developments in the field, including the spectral gap, resonance asymptotics near the critical line, and sharp geometric constan...

  5. Extracting sea ice surface characteristics using spectral unmixing

    Science.gov (United States)

    Barrett, A.; Stroeve, J.

    2016-12-01

    The surface of the Arctic Ocean is a mixture of bare sea ice, snow covered sea ice, melt ponds, leads and open ocean. The composition of this mixture changes throughout the summer melt season. The mixture of surface types influences albedo at a range of scales, from local to global. The spatial variability of surface types often occurs at a scale smaller than the spatial resolution of remotely sensed imagery, resulting in a "mixed-pixel" problem. Therefore, it is important to quantify the fractions of surface types in each pixel. Multiple endmember spectral mixture analysis (MESMA) allows fractional area of surface types to be estimated. In this paper we explore classifying RS imagery collected over the Arctic Ocean into surface types using a spectral mixture analysis. MESMA is only as good as the endmembers. We use a library of spectra collected in-situ at Barrow, Resolute and the Surface Heat Budget of the Arctic Ocean over bare and snow covered sea ice, melt ponds, and leads as our endmembers. The separability of spectra is first examined. For the spectral unmixing, we follow a similar approach to the MEM/MODSCAG algorithm for snow covered area. Endmember spectra for each of the four surface types are selected to find the best linear combination of spectra. The algorithm is tested on MODIS imagery for selected dates throughout the 2007 melt season. The approach is validated using high-resolution Quickbird imagery collected at the same time as the MODIS images.

  6. Phase spectral composition of wind generated ocean surface waves

    Digital Repository Service at National Institute of Oceanography (India)

    Varkey, M.J.

    A study of the composition of the phase spectra of wind generated ocean surface waves is carried out using wave records collected employing a ship borne wave recorder. It is found that the raw phase spectral estimates could be fitted by the Uniform...

  7. An experimental method for making spectral emittance and surface temperature measurements of opaque surfaces

    International Nuclear Information System (INIS)

    Moore, Travis J.; Jones, Matthew R.; Tree, Dale R.; Daniel Maynes, R.; Baxter, Larry L.

    2011-01-01

    An experimental procedure has been developed to make spectral emittance and temperature measurements. The spectral emittance of an object is calculated using measurements of the spectral emissive power and of the surface temperature of the object obtained using a Fourier transform infrared (FTIR) spectrometer. A calibration procedure is described in detail which accounts for the temperature dependence of the detector. The methods used to extract the spectral emissive power and surface temperature from measured infrared spectra were validated using a blackbody radiator at known temperatures. The average error in the measured spectral emittance was 2.1% and the average difference between the temperature inferred from the recorded spectra and the temperature indicated on the blackbody radiator was 1.2%. The method was used to measure the spectral emittance of oxidized copper at various temperatures.

  8. Power Spectral Density Evaluation of Laser Milled Surfaces

    Directory of Open Access Journals (Sweden)

    Raoul-Amadeus Lorbeer

    2017-12-01

    Full Text Available Ablating surfaces with a pulsed laser system in milling processes often leads to surface changes depending on the milling depth. Especially if a constant surface roughness and evenness is essential to the process, structural degradation may advance until the process fails. The process investigated is the generation of precise thrust by laser ablation. Here, it is essential to predict or rather control the evolution of the surfaces roughness. Laser ablative milling with a short pulse laser system in vacuum (≈1 Pa were performed over depths of several 10 µm documenting the evolution of surface roughness and unevenness with a white light interference microscope. Power spectral density analysis of the generated surface data reveals a strong influence of the crystalline structure of the solid. Furthermore, it was possible to demonstrate that this effect could be suppressed for gold.

  9. Mars analog minerals' spectral reflectance characteristics under Martian surface conditions

    Science.gov (United States)

    Poitras, J. T.; Cloutis, E. A.; Salvatore, M. R.; Mertzman, S. A.; Applin, D. M.; Mann, P.

    2018-05-01

    We investigated the spectral reflectance properties of minerals under a simulated Martian environment. Twenty-eight different hydrated or hydroxylated phases of carbonates, sulfates, and silica minerals were selected based on past detection on Mars through spectral remote sensing data. Samples were ground and dry sieved to Mars, only losing adsorbed H2O while maintaining their diagnostic spectral features. Sulfates were less stable, often with shifts in the band position of the SO, Fe, and OH absorption features. Silicas displayed spectral shifts related to SiOH and hydration state of the mineral surface, while diagnostic bands for quartz were stable. Previous detection of carbonate minerals based on 2.3-2.5 μm and 3.4-3.9 μm features appears to be consistent with our results. Sulfate mineral detection is more questionable since there can be shifts in band position related to SO4. The loss of the 0.43 μm Fe3+ band in many of the sulfates indicate that there are fewer potential candidates for Fe3+ sulfates to permanently exist on the Martian surface based on this band. The gypsum sample changed phase to basanite during desiccation as demonstrated by both reflectance and XRD. Silica on Mars has been detected using band depth ratio at 1.91 and 1.96 μm and band minimum position of the 1.4 μm feature, and the properties are also used to determine their age. This technique continues to be useful for positive silica identifications, however, silica age appears to be less consistent with our laboratory data. These results will be useful in spectral libraries for characterizing Martian remote sensed data.

  10. Interaction of non-equilibrium phonons with electron-hole plasmas in germanium

    International Nuclear Information System (INIS)

    Kirch, S.J.

    1985-01-01

    This thesis presents results of experiments on the interaction of phonons and photo-excited electron-hole plasmas in Ge at low temperature. The first two studies involved the low-temperature fluid phase known as the electron-hole liquid (EHL). The third study involved a wider range of temperatures and includes the higher temperature electron-hole plasma (EHP). In the first experiment, superconducting tunnel junctions are used to produce quasi-monochromatic phonons, which propagate through the EHL. The magnitude of the absorption of these non-equilibrium phonons gives a direct measure of the coupling constant, the deformation potential. In the second experiment, the nonequilibrium phonons are generated by laser excitation of a metal film. An unusual sample geometry allows examination of the EHL-phonon interaction near the EHL excitation surface. This coupling is examined for both cw and pulsed EHL excitation. In the third experiment, the phonons are byproducts of the photo-excited carrier thermalization. The spatial, spectral and temporal dependence of the recombination luminescence is examined. A phonon wind force is observed to dominate the transport properties of the EHL and the EHP. These carriers are never observed to move faster than the phonon velocity even during the laser pulse

  11. Tunable infrared reflectance by phonon modulation

    Energy Technology Data Exchange (ETDEWEB)

    Ihlefeld, Jon F.; Sinclair, Michael B.; Beechem, III, Thomas E.

    2018-03-06

    The present invention pertains to the use of mobile coherent interfaces in a ferroelectric material to interact with optical phonons and, ultimately, to affect the material's optical properties. In altering the optical phonon properties, the optical properties of the ferroelectric material in the spectral range near-to the phonon mode frequency can dramatically change. This can result in a facile means to change to the optical response of the ferroelectric material in the infrared.

  12. Tunable infrared reflectance by phonon modulation

    Science.gov (United States)

    Ihlefeld, Jon F.; Sinclair, Michael B.; Beechem, III, Thomas E.

    2018-03-06

    The present invention pertains to the use of mobile coherent interfaces in a ferroelectric material to interact with optical phonons and, ultimately, to affect the material's optical properties. In altering the optical phonon properties, the optical properties of the ferroelectric material in the spectral range near-to the phonon mode frequency can dramatically change. This can result in a facile means to change to the optical response of the ferroelectric material in the infrared.

  13. ADE spectral networks and decoupling limits of surface defects

    Energy Technology Data Exchange (ETDEWEB)

    Longhi, Pietro [Department of Physics and Astronomy, Uppsala university,Uppsala (Sweden); Park, Chan Y. [NHETC and Department of Physics and Astronomy, Rutgers University,New Brunswick, NJ (United States)

    2017-02-03

    We study vacua and BPS spectra of canonical surface defects of class S theories in different decoupling limits using ADE spectral networks. In some regions of the IR moduli spaces of these 2d-4d systems, the mixing between 2d and 4d BPS states is suppressed, and the spectrum of 2d-4d BPS states becomes that of a 2d N=(2,2) theory. For some decoupling limits, we identify the 2d theories describing the surface defects with nonlinear sigma models and coset models that have been previously studied. We also study certain cases where the decoupling limit of a surface defect exhibits a set of vacua and a BPS spectrum that appear to be entirely new. A detailed analysis of these spectra and their wall-crossing behavior is performed.

  14. Ag Nanorod Arrays for SERS: Aspects of Spectral Reproducibility, Surface Contamination, and Spectral Sensitivity

    Directory of Open Access Journals (Sweden)

    Martin Šubr

    2015-01-01

    Full Text Available Ag nanorod arrays prepared by oblique angle vapor deposition (OAD represent regular, large area substrates for surface-enhanced Raman scattering (SERS spectroscopy. We studied uniformity and spectral reproducibility of silver OAD-fabricated substrates (AgOADs by spectral mapping of methylene blue. The results demonstrate good reproducibility apart from occasional “hot-spot” sites where the intensity is higher. The number of “hot-spots” represents 2%–6% of SERS-active sites of mapping substrate area. We were able to obtain good SERS spectra of testing amino acid tryptophan at 1 × 10−5 M concentration and three different free-base porphyrins down to ∼10−7 M concentration. We found out that keeping the AgOADs in a vacuum chamber overnight prevents the surface from binding any contaminants from the ambient atmosphere, without significant reduction in the SERS enhancement. Such substrates provide stable SERS enhancement even when stored for 1 year after preparation.

  15. Power Spectral Density Specification and Analysis of Large Optical Surfaces

    Science.gov (United States)

    Sidick, Erkin

    2009-01-01

    The 2-dimensional Power Spectral Density (PSD) can be used to characterize the mid- and the high-spatial frequency components of the surface height errors of an optical surface. We found it necessary to have a complete, easy-to-use approach for specifying and evaluating the PSD characteristics of large optical surfaces, an approach that allows one to specify the surface quality of a large optical surface based on simulated results using a PSD function and to evaluate the measured surface profile data of the same optic in comparison with those predicted by the simulations during the specification-derivation process. This paper provides a complete mathematical description of PSD error, and proposes a new approach in which a 2-dimentional (2D) PSD is converted into a 1-dimentional (1D) one by azimuthally averaging the 2D-PSD. The 1D-PSD calculated this way has the same unit and the same profile as the original PSD function, thus allows one to compare the two with each other directly.

  16. Resonant tunneling in a pulsed phonon field

    DEFF Research Database (Denmark)

    Kral, P.; Jauho, Antti-Pekka

    1999-01-01

    , The nonequilibrium spectral function for the resonance displays the formation and decay of the phonon sidebands on ultrashort time scales. The time-dependent tunneling current through the individual phonon satellites reflects this quasiparticle formation by oscillations, whose time scale is set by the frequency...

  17. New aspects of electronic excitations at the bismuth surface: Topology, thermalization and coupling to coherent phonons

    Energy Technology Data Exchange (ETDEWEB)

    Perfetti, L., E-mail: luca.perfetti@polytechnique.edu [Laboratoire des Solides Irradiés, Ecole Polytechnique – CEA/DSM – CNRS UMR 7642, 91128 Palaiseau (France); Faure, J. [Laboratoire d’Optique Appliquée, Ecole Polytechnique – ENSTA – CNRS UMR 7639, 91761 Palaiseau (France); Papalazarou, E.; Mauchain, J.; Marsi, M.; Goerbig, M.O. [Laboratoire de Physique des Solides, CNRS UMR 8502, Université Paris-Sud, F-91405 Orsay (France); Taleb-Ibrahimi, A.; Ohtsubo, Y. [Synchrotron SOLEIL, Saint-Aubin-BP 48, F-91192 Gif sur Yvette (France)

    2015-05-15

    We review measurements of angle and time resolved photoelectron spectroscopy on the surface states of the Bi(1 1 1) surface. The work covers several aspects of these surface states, discussing the topological properties, the strong anisotropy of the spin–orbit splitting and the dynamical relaxation of photoexcited electrons. Since time resolved experiments disentagle interaction processes in real time, the reported data offer a novel perspective on the motion of charge carriers in surface states and will serve as an unuseful reference for other systems with strong spin–orbit coupling.

  18. Rode's iterative calculation of surface optical phonon scattering limited electron mobility in N-polar GaN devices

    International Nuclear Information System (INIS)

    Ghosh, Krishnendu; Singisetti, Uttam

    2015-01-01

    N-polar GaN channel mobility is important for high frequency device applications. Here, we report theoretical calculations on the surface optical (SO) phonon scattering rate of two-dimensional electron gas (2DEG) in N-polar GaN quantum well channels with high-k dielectrics. Rode's iterative calculation is used to predict the scattering rate and mobility. Coupling of the GaN plasmon modes with the SO modes is taken into account and dynamic screening is employed under linear polarization response. The effect of SO phonons on 2DEG mobility was found to be small at >5 nm channel thickness. However, the SO mobility in 3 nm N-polar GaN channels with HfO 2 and ZrO 2 high-k dielectrics is low and limits the total mobility. The SO scattering for SiN dielectric on GaN was found to be negligible due to its high SO phonon energy. Using Al 2 O 3 , the SO phonon scattering does not affect mobility significantly only except the case when the channel is too thin with a low 2DEG density

  19. Phonon frequency shift and effect of correlation on the electron ...

    Indian Academy of Sciences (India)

    Abstract. The electron–phonon interaction in the periodic Anderson model (PAM) is considered. The PAM incorporates the effect of onsite Coulomb interaction (U) between /-electrons. The in- fluence of Coulomb correlation U on the phonon response of the system is studied by evaluating the phonon spectral function for ...

  20. Effect of phonon transport on the Seebeck coefficient and thermal conductivity of silicon nanowire arrays

    Science.gov (United States)

    Sadhu, Jyothi Swaroop

    annihilation of phonon drag in nanowires due to phonon boundary scattering. By exploring the effect of surface roughness and employing lattice non-equilibrium theories, the measurements are able to distinguish between long wavelength phonons that contribute to phonon drag and shorter wavelengths that contribute to heat conduction near room temperature. Phonon drag quenching in nanostructures has implications beyond silicon and this thesis paves the way toward spectrally selective phonon scattering for improving nanoscale thermoelectrics.

  1. Analysis of the phonon surface specific heat using Green function techniques

    International Nuclear Information System (INIS)

    Silva Carrico, A. da; Albuquerque, E.L. de

    1981-01-01

    Green functions are derived for the displacement associated with acoustic vibrations in isotropic elastic media and used to evaluate the surface specific heat in the harmonic approximation. Only the low-temperature limit case is considered since, provided K sub(B) T/h is very small, the dispersion relation for the three acoustic branches can be replaced by its long-wavelenght form. The contributions of surface elastic waves of the Rayleigh and Love types are pointed out and their features discussed. The nature of the result and their relations to previous work in this field is also presented and discussed. (Author) [pt

  2. Analysis of the phonon surface specific heat using Green function techniques

    International Nuclear Information System (INIS)

    Carrico, A.S.; Albuquerque, E.L.

    1980-01-01

    Green functions are derived for the displacement associated with acoustic vibrations in isotropic elastic media and used to evaluate the surface specific heat in the harmonic approximation. We consider only the low-temperature limit case since, provided K B 1/h is very samll, we can replace the dispersion relation for the three acoustic branches by its long-wavelenghts form. The contributions of surface elastic waves ot the Rayleigh and Love types are pointed out and their features discussed. The nature of the result and their relations to previous work in this field is also presented and discussed. (author) [pt

  3. Spectral studies of Lanthanide interactions with membrane surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Karukstis, K.K.; Kao, M.Y.; Savin, D.A.; Bittker, R.A.; Kaphengst, K.J.; Emetarom, C.M.; Naito, N.R.; Takamoto, D.Y. [Harvey Mudd College, Claremont, CA (United States)

    1995-03-23

    We have monitored the interactions of the series of trivalent lanthanide cations with the thylakoid membrane surface of spinach chloroplasts using two complementary spectral techniques. Measurements of the fluorescence emission of the extrinsic probe 2-p-toluidinonaphthalene-6-sulfonate (TNS) and the absorbance of the intrinsic chromophore chlorophyll provide two sensitive means of characterizing the dependence of the cation-membrane interaction on the nature of the cation. In these systems, added lanthanide cations adsorb onto the membrane surface to neutralize exposed segments of membrane-embedded protein complexes. The lanthanide-induced charge neutralization increases the proximity of added TNS anion to the membrane surface as evidenced by variations in the TNS fluorescence level and wavelength of maximum emission. Our results reveal a strong dependence of TNS fluorescence parameters on both lanthanide size and total orbital angular momentum L value. Lanthanides with greater charge density (small size and/or low L value) enhance the TNS fluorescence level to a greater extent. A possible origin for the lanthanide-dependent TNS fluorescence levels is suggested in terms of a heterogeneity in the number and type of TNS binding sites. The data are consistent with the proposal that larger lanthanides with smaller enthalpies of hydration induce more significant membrane appression. 59 refs., 9 figs., 2 tabs.

  4. Phonon manipulation with phononic crystals.

    Energy Technology Data Exchange (ETDEWEB)

    Kim Bongsang; Hopkins, Patrick Edward; Leseman, Zayd C.; Goettler, Drew F.; Su, Mehmet F. (University of New Mexico, Albuquerque, NM); El-Kady, Ihab Fathy; Reinke, Charles M.; Olsson, Roy H., III

    2012-01-01

    In this work, we demonstrated engineered modification of propagation of thermal phonons, i.e. at THz frequencies, using phononic crystals. This work combined theoretical work at Sandia National Laboratories, the University of New Mexico, the University of Colorado Boulder, and Carnegie Mellon University; the MESA fabrication facilities at Sandia; and the microfabrication facilities at UNM to produce world-leading control of phonon propagation in silicon at frequencies up to 3 THz. These efforts culminated in a dramatic reduction in the thermal conductivity of silicon using phononic crystals by a factor of almost 30 as compared with the bulk value, and about 6 as compared with an unpatterned slab of the same thickness. This work represents a revolutionary advance in the engineering of thermoelectric materials for optimal, high-ZT performance. We have demonstrated the significant reduction of the thermal conductivity of silicon using phononic crystal structuring using MEMS-compatible fabrication techniques and in a planar platform that is amenable to integration with typical microelectronic systems. The measured reduction in thermal conductivity as compared to bulk silicon was about a factor of 20 in the cross-plane direction [26], and a factor of 6 in the in-plane direction. Since the electrical conductivity was only reduced by a corresponding factor of about 3 due to the removal of conductive material (i.e., porosity), and the Seebeck coefficient should remain constant as an intrinsic material property, this corresponds to an effective enhancement in ZT by a factor of 2. Given the number of papers in literature devoted to only a small, incremental change in ZT, the ability to boost the ZT of a material by a factor of 2 simply by reducing thermal conductivity is groundbreaking. The results in this work were obtained using silicon, a material that has benefitted from enormous interest in the microelectronics industry and that has a fairly large thermoelectric power

  5. Evaluation of abrasive waterjet produced titan surfaces topography by spectral analysis techniques

    Directory of Open Access Journals (Sweden)

    D. Kozak

    2012-01-01

    Full Text Available Experimental study of a titan grade 2 surface topography prepared by abrasive waterjet cutting is performed using methods of the spectral analysis. Topographic data are acquired by means of the optical profilometr MicroProf®FRT. Estimation of the areal power spectral density of the studied surface is carried out using the periodogram method combined with the Welch´s method. Attention is paid to a structure of the areal power spectral density, which is characterized by means of the angular power spectral density. This structure of the areal spectral density is linked to the fine texture of the surface studied.

  6. Resonant surface-enhanced Raman scattering by optical phonons in a monolayer of CdSe nanocrystals on Au nanocluster arrays

    Energy Technology Data Exchange (ETDEWEB)

    Milekhin, Alexander G., E-mail: milekhin@isp.nsc.ru [A.V. Rzhanov Institute of Semiconductor Physics, pr. Lavrentjeva, 13, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, Pirogov str. 2, 630090 Novosibirsk (Russian Federation); Sveshnikova, Larisa L.; Duda, Tatyana A. [A.V. Rzhanov Institute of Semiconductor Physics, pr. Lavrentjeva, 13, 630090 Novosibirsk (Russian Federation); Rodyakina, Ekaterina E. [A.V. Rzhanov Institute of Semiconductor Physics, pr. Lavrentjeva, 13, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, Pirogov str. 2, 630090 Novosibirsk (Russian Federation); Dzhagan, Volodymyr M. [Semiconductor Physics, Technische Universität Chemnitz, D-09107 Chemnitz (Germany); Sheremet, Evgeniya [Solid Surfaces Analysis, Technische Universität Chemnitz, D-09107 Chemnitz (Germany); Gordan, Ovidiu D. [Semiconductor Physics, Technische Universität Chemnitz, D-09107 Chemnitz (Germany); Himcinschi, Cameliu [Institut für Theoretische Physik, TU Bergakademie Freiberg, 09596 Freiberg (Germany); Latyshev, Alexander V. [A.V. Rzhanov Institute of Semiconductor Physics, pr. Lavrentjeva, 13, 630090 Novosibirsk (Russian Federation); Novosibirsk State University, Pirogov str. 2, 630090 Novosibirsk (Russian Federation); Zahn, Dietrich R.T. [Semiconductor Physics, Technische Universität Chemnitz, D-09107 Chemnitz (Germany)

    2016-05-01

    Highlights: • Regular Au nanocluster and dimer arrays as well as single Au dimers are fabricated. • Resonant SERS by monolayers of CdSe nanocrystals deposited on the Au nanostructures is observed. • LO energy change for CdSe NCs on different single Au dimers indicates SERS by single or a few NCs. - Abstract: Here we present the results on an investigation of resonant Stokes and anti- Stokes surface-enhanced Raman scattering (SERS) by optical phonons in colloidal CdSe nanocrystals (NCs) homogeneously deposited on arrays of Au nanoclusters using the Langmuir–Blodgett technology. The thickness of deposited NCs, determined by transmission and scanning electron microscopy, amounts to approximately 1 monolayer. Special attention is paid to the determination of the localized surface plasmon resonance (LSPR) energy in the arrays of Au nanoclusters as a function of the nanocluster size by means of micro-ellipsometry. SERS by optical phonons in CdSe NCs shows a significant enhancement factor with a maximal value of 2 × 10{sup 3} which depends resonantly on the Au nanocluster size and thus on the LSPR energy. The deposition of CdSe NCs on the arrays of Au nanocluster dimers enabled us to study the polarization dependence of SERS. It was found that a maximal SERS signal is observed for the light polarization along the dimer axis. Finally, SERS by optical phonons was observed for CdSe NCs deposited on the structures with a single Au dimer. A difference of the LO phonon energy is observed for CdSe NCs on different single dimers. This effect is explained as the confinement-induced shift which depends on the CdSe nanocrystal size and indicates quasi-single NC Raman spectra being obtained.

  7. Terahertz acoustic phonon detection from a compact surface layer of spherical nanoparticles powder mixture of aluminum, alumina and multi-walled carbon nanotube

    Science.gov (United States)

    Abouelsayed, A.; Ebrahim, M. R.; El hotaby, W.; Hassan, S. A.; Al-Ashkar, Emad

    2017-10-01

    We present terahertz spectroscopy study on spherical nanoparticles powder mixture of aluminum, alumina, and MWCNTs induced by surface mechanical attrition treatment (SMAT) of aluminum substrates. Surface alloying of AL, Al2O3 0.95% and MWCNTs 0.05% powder mixture was produced during SMAT process, where a compact surface layer of about 200 μm due to ball bombardment was produced from the mixture. Al2O3 alumina powder played a significant role in MWCNTs distribution on surface, those were held in deformation surface cites of micro-cavities due to SMAT process of Al. The benefits are the effects on resulted optical properties of the surface studied at the terahertz frequency range due to electrical isolation confinement effects and electronic resonance disturbances exerted on Al electronic resonance at the same range of frequencies. THz acoustic phonon around 0.53-0.6 THz (17-20 cm-1) were observed at ambient conditions for the spherical nanoparticles powder mixture of Al, Al2O3 and MWCNTs. These results suggested that the presence of Al2O3 and MWCNTs during SMAT process leads to the optically detection of such acoustic phonon in the THz frequency range.

  8. Clenbuterol Assay by Spectral Imaging Surface Plasmon Resonance Biosensor System.

    Science.gov (United States)

    Wu, Yichuan; Yao, Manwen; Fang, Xiangyi; Yang, Yucong; Cheng, Xiaoli

    2015-11-01

    To prevent illegal use of clenbuterol and for quality control in the food industry, more efficient and reliable methods for clenbuterol detection are needed. In this study, clenbuterol was detected using a spectral imaging surface plasmon resonance sensor system via two inhibition methods: (1) the target site compensation method, in which anti-clenbuterol antibody was immobilized on the sensor chip as a bioprobe and (2) the solution competition method in which a clenbuterol-BSA conjugate was immobilized on the sensor chip as the bioprobe. The detectable clenbuterol concentration ranged between 6.25 and 100 μg/mL for both methods. The clenbuterol limit of detection for the target site compensation method and solution competition method are estimated to be 6.7 and 4.5 μg/mL, respectively. The proposed methods were successfully applied to the detection of clenbuterol molecules and were found to have high specificity and high-throughput and were label free and operationally convenient.

  9. Airborne Spectral Measurements of Surface-Atmosphere Anisotropy for Several Surfaces and Ecosystem over Southern Africa

    Science.gov (United States)

    Gatebe, C. K.; King, M. D.; Tsay, S.; Arnold, G. T.; Li, J. Y.

    2001-12-01

    The Cloud Absorption Radiometer (CAR) was flown aboard the University of Washington Convair CV-580 research aircraft and took measurements on 23 flights between August 15 and September 16. On 12 of those flights, BRF measurements were obtained over different natural surfaces and ecosystem in southern Africa. The BRF measurements were done to characterize surface anisotropy in support of SAFARI 2000 science objectives principally to validate products from NASA's EOS satellites, and to parameterize and validate BRF models. In this paper we present results of BRFs taken over two EOS validation sites: Skukuza tower, South Africa (25.0 oS, 31.5 oE) and Mongu tower, Zambia (15.4 oS, 23.3 oE). Additional sites are also considered and include, Maun tower, Botswana (20.0 oS, 23.5 oE), Sowa Pan, Botswana (20.6 oS, 26.2 oE) and Etosha Pan, Namibia (19.0 oS, 16.0 oE). The CAR is capable of measuring scattered light in fourteen spectral bands. The scan mirror, rotating at 100 rpm, directs the light into a Dall-Kirkham telescope where the beam is split into nine paths. Eight light beams pass through beam splitters, dichroics, and lenses to individual detectors (0.34-1.27 μ m), and finally are registered by eight data channels. They are sampled simultaneously and continuously. The ninth beam passes through a spinning filter wheel to an InSb detector cooled by a Stirling cycle cooler. Signals registered by the ninth data channel are selected from among six spectral channels (1.55-2.30 μ m). The filter wheel can either cycle through all six spectral bands at a prescribed interval (usually changing filter every fifth scan line), or lock onto any one of the six spectral bands and sample it continuously. To measure the BRF of the surface-atmosphere system, the University of Washington CV-580 had to bank at a comfortable roll angle of ~20 o and fly in a circle about 3 km in diameter above the surface for roughly two minutes. Replicated observations (multiple circular orbits) were

  10. The structure of spectral problems and geometry: hyperbolic surfaces in E sup 3

    CERN Document Server

    Cieslinski, J L

    2003-01-01

    Working in the framework of Sym's soliton surfaces approach we point out that some simple assumptions about the structure of linear (spectral) problems of the theory of solitons lead uniquely to the geometry of some special immersions. In this paper we consider general su(2) spectral problems. Under some very weak assumptions they turn out to be associated with hyperbolic surfaces (surfaces of negative Gaussian curvature) immersed in three-dimensional Euclidean space, and especially with the so-called Bianchi surfaces.

  11. ARM Climate Research Facility Spectral Surface Albedo Value-Added Product (VAP) Report

    Energy Technology Data Exchange (ETDEWEB)

    McFarlane, S; Gaustad, K; Long, C; Mlawer, E

    2011-07-15

    This document describes the input requirements, output data products, and methodology for the Spectral Surface Albedo (SURFSPECALB) value-added product (VAP). The SURFSPECALB VAP produces a best-estimate near-continuous high spectral resolution albedo data product using measurements from multifilter radiometers (MFRs). The VAP first identifies best estimates for the MFR downwelling and upwelling shortwave irradiance values, and then calculates narrowband spectral albedo from these best-estimate irradiance values. The methodology for finding the best-estimate values is based on a simple process of screening suspect data and backfilling screened and missing data with estimated values when possible. The resulting best-estimate MFR narrowband spectral albedos are used to determine a daily surface type (snow, 100% vegetation, partial vegetation, or 0% vegetation). For non-snow surfaces, a piecewise continuous function is used to estimate a high spectral resolution albedo at 1 min temporal and 10 cm-1 spectral resolution.

  12. Study of land surface temperature and spectral emissivity using multi ...

    Indian Academy of Sciences (India)

    LST) and spectral emissivities over a hard rock terrain using multi-sensor satellite data. The study area, of about 6000 km2, is a part of Singhbhum–Orissa craton situated in the eastern part of India. TIR data from ASTER, MODIS and Landsat ...

  13. Separation of Atmospheric and Surface Spectral Features in Mars Global Surveyor Thermal Emission Spectrometer (TES) Spectra

    Science.gov (United States)

    Smith, Michael D.; Bandfield, Joshua L.; Christensen, Philip R.

    2000-01-01

    We present two algorithms for the separation of spectral features caused by atmospheric and surface components in Thermal Emission Spectrometer (TES) data. One algorithm uses radiative transfer and successive least squares fitting to find spectral shapes first for atmospheric dust, then for water-ice aerosols, and then, finally, for surface emissivity. A second independent algorithm uses a combination of factor analysis, target transformation, and deconvolution to simultaneously find dust, water ice, and surface emissivity spectral shapes. Both algorithms have been applied to TES spectra, and both find very similar atmospheric and surface spectral shapes. For TES spectra taken during aerobraking and science phasing periods in nadir-geometry these two algorithms give meaningful and usable surface emissivity spectra that can be used for mineralogical identification.

  14. Manipulation of Phonons with Phononic Crystals

    Energy Technology Data Exchange (ETDEWEB)

    Leseman, Zayd Chad [Univ. of New Mexico, Albuquerque, NM (United States)

    2015-07-09

    There were three research goals associated with this project. First, was to experimentally demonstrate phonon spectrum control at THz frequencies using Phononic Crystals (PnCs), i.e. demonstrate coherent phonon scattering with PnCs. Second, was to experimentally demonstrate analog PnC circuitry components at GHz frequencies. The final research goal was to gain a fundamental understanding of phonon interaction using computational methods. As a result of this work, 7 journal papers have been published, 1 patent awarded, 14 conference presentations given, 4 conference publications, and 2 poster presentations given.

  15. Asteroid Spectral Imaging Mission (ASPECT) CubeSat to characterize resources on asteroid surfaces

    Science.gov (United States)

    Kohout, T.; Näsilä, A.; Tikka, T.; Granvik, M.; Kestilä, A.; Penttilä, A.; Kuhno, J.; Muinonen, K.; Viherkanto, K.

    2017-09-01

    ASPECT is a 3U CubeSat with a VIS-NIR spectral imager. It can characterize composition of asteroid surfaces and identify areas and objects with desired properties for sample return or in-space resource utilization.

  16. Thermal Infrared Spectra of Microcrystalline Sedimentary Phases: Effects of Natural Surface Roughness on Spectral Feature Shape

    Science.gov (United States)

    Hardgrove, C.; Rogers, A. D.

    2012-03-01

    Thermal infrared spectral features of common microcrystalline phases (chert, alabaster, micrite) are presented. Spectra are sensitive to mineralogy and micron-scale (~1-25 µm) surface roughness. Roughness is on the scale of the average crystal size.

  17. Airborne spectral measurements of surface-atmosphere anisotropy for several surfaces and ecosystems over southern Africa

    Science.gov (United States)

    Gatebe, Charles K.; King, Michael D.; Platnick, Steve; Arnold, G. Thomas; Vermote, Eric F.; Schmid, Beat

    2003-07-01

    The Cloud Absorption Radiometer (CAR) was flown aboard the University of Washington Convair CV-580 research aircraft during the Southern Africa Regional Science Initiative 2000 (SAFARI 2000) dry season campaign and obtained measurements of bidirectional reflectance distribution function (BRDF) for a variety of natural surfaces and ecosystems in southern Africa. To measure the BRDF of the surface-atmosphere system, the University of Washington CV-580 banked at a roll angle of ˜20° and flew circles about 3 km in diameter above the surface, taking approximately 2 min. Multiple circular orbits were acquired over selected surfaces so that average BRDFs could be acquired, smoothing out small-scale surface and atmospheric inhomogeneities. In this paper, we present results of BRDFs taken over two Earth Observing System (EOS) validation sites: Skukuza tower, South Africa (25.0°S, 31.5°E) and Mongu tower, Zambia (15.4°S, 23.3°E). Additional sites are discussed and include the Maun tower, Botswana (20.0°S, 23.6°E), Sua Pan, Botswana (20.6°S, 25.9°E), Etosha Pan, Namibia (19.0°S, 16.0°E), and marine stratocumulus clouds off the west coast of Namibia (20.5°S, 13.1°E). Results clearly show anisotropy in reflected solar radiation over the various surfaces types: savanna, salt pans, and cloud. The greatest anisotropy is observed over marine stratus clouds, which exhibit strong forward scattering as well as important water cloud scattering features such as the rainbow and glory. The BRDF over savanna is characterized by a distinct backscattering peak in the principal plane and shows directional and spectral variations. Over the pans, the BRDF is more enhanced in the backscattering plane than forward scattering plane and shows little directional variation.

  18. Surface kinetic temperature mapping using satellite spectral data in ...

    African Journals Online (AJOL)

    The result revealed that despite the limited topographic differences of the rift lakes and their proximity, the surface kinetic temperature difference is high, mainly due to groundwater and surface water fluxes. From thermal signature analysis two hot springs below the lake bed of Ziway were discovered. The various hot springs ...

  19. Temporal and Spectral Coherence From Rough Surface Scattering

    National Research Council Canada - National Science Library

    Gu, Zu-Han

    2006-01-01

    .... The enhanced backscattering is manifested by the presence of a well-defined peak in the retro-reflection direction in the angular distribution of the intensity of the diffusely scattered light from a rough surface...

  20. Observation of chiral phonons

    KAUST Repository

    Zhu, Hanyu

    2018-02-01

    Chirality reveals symmetry breaking of the fundamental interaction of elementary particles. In condensed matter, for example, the chirality of electrons governs many unconventional transport phenomena such as the quantum Hall effect. Here we show that phonons can exhibit intrinsic chirality in monolayer tungsten diselenide. The broken inversion symmetry of the lattice lifts the degeneracy of clockwise and counterclockwise phonon modes at the corners of the Brillouin zone. We identified the phonons by the intervalley transfer of holes through hole-phonon interactions during the indirect infrared absorption, and we confirmed their chirality by the infrared circular dichroism arising from pseudoangular momentum conservation. The chiral phonons are important for electron-phonon coupling in solids, phonon-driven topological states, and energy-efficient information processing.

  1. Spectrally enhanced image resolution of tooth enamel surfaces

    Science.gov (United States)

    Zhang, Liang; Nelson, Leonard Y.; Berg, Joel H.; Seibel, Eric J.

    2012-01-01

    Short-wavelength 405 nm laser illumination of surface dental enamel using an ultrathin scanning fiber endoscope (SFE) produced enhanced detail of dental topography. The surfaces of human extracted teeth and artificial erosions were imaged with 405 nm, 444 nm, 532 nm, or 635 nm illumination lasers. The obtained images were then processed offline to compensate for any differences in the illumination beam diameters between the different lasers. Scattering and absorption coefficients for a Monte Carlo model of light propagation in dental enamel for 405 nm were scaled from published data at 532 nm and 633 nm. The value of the scattering coefficient used in the model was scaled from the coefficients at 532 nm and 633 nm by the inverse third power of wavelength. Simulations showed that the penetration depth of short-wavelength illumination is localized close to the enamel surface, while long-wavelength illumination travels much further and is backscattered from greater depths. Therefore, images obtained using short wavelength laser are not contaminated by the superposition of light reflected from enamel tissue at greater depths. Hence, the SFE with short-wavelength illumination may make it possible to visualize surface manifestations of phenomena such as demineralization, thus better aiding the clinician in the detection of early caries.

  2. Location of Bare Soil Surface and Soil Line on the RED-NIR Spectral Plane

    Science.gov (United States)

    Koroleva, P. V.; Rukhovich, D. I.; Rukhovich, A. D.; Rukhovich, D. D.; Kulyanitsa, A. L.; Trubnikov, A. V.; Kalinina, N. V.; Simakova, M. S.

    2017-12-01

    Soil as a separate natural body occupies certain area with its own set of spectral characteristics within the RED-NIR spectral space. This is an ellipse-shaped area, and its semi-major axis is the soil line for a satellite image. The spectral area for a bare soil surface is neighboring to the areas of black carbon, straw, vegetating plants, and missing RED-NIR values. A reliable separation of the bare soil surface within the spectral space is possible with the technology of spectral neighborhood of soil line. The accuracy of this method is 90%. The determination of the bare soil surface using vegetation indices, both relative (NDVI), and perpendicular (PVI), is incorrect; the accuracy of these methods does not exceed 65%, and for most of the survey seasons it may be lower than 50%. The flat part of the "tasseled cap" described as the soil line, is not a synonym for the area of the bare soil surface. The bare soil surface on the RED-NIR plots occupies significantly smaller areas than the area of soil line according to Kauth and Thomas.

  3. Novel spectral fiber optic sensor based on surface plasmon resonance

    Czech Academy of Sciences Publication Activity Database

    Slavík, Radan; Homola, Jiří; Čtyroký, Jiří; Brynda, Eduard

    B74, 1/3 (2001), s. 106-111 ISSN 0925-4005. [European Conference on Optical Chemical Sensors and Biosensors EUROPT(R)ODE /5./. Lyon-Villeurbanne, 16.04.2000-19.04.2000] R&D Projects: GA ČR GA102/99/M057; GA ČR GA102/99/0549; GA ČR GA102/00/1536 Institutional research plan: CEZ:AV0Z2067918 Keywords : fibre optic sensors * surface plasmons Subject RIV: JB - Sensors, Measurment, Regulation Impact factor: 1.440, year: 2001

  4. Laser pulse transient method for measuring the normal spectral emissivity of samples with arbitrary surface quality

    Science.gov (United States)

    Jeromen, A.; Grabec, I.; Govekar, E.

    2008-09-01

    A laser pulse transient method for measuring normal spectral emissivity is described. In this method, a laser pulse ( λ=1064 nm) irradiates the top surface of a flat specimen. A two-dimensional temperature response of the bottom surface is measured with a calibrated thermographic camera. By solving an axisymmetric boundary value heat conduction problem, the normal spectral emissivity at 1064 nm is determined by using an iterative nonlinear least-squares estimation procedure. The method can be applied to arbitrary sample surface quality. The method is tested on a nickel specimen and used to determine the normal spectral emissivity of AISI 304 stainless steel. The expanded combined uncertainty of the method has been estimated to be 18%.

  5. Spectrally adjusted surface reflectance and its dependence with NDVI for Landsat and Sentinel 2

    Science.gov (United States)

    Villaescusa, J. L.; Franch, B.; Roger, J. C.; Vermote, E.; Justice, C. O.

    2017-12-01

    Cross-calibration between sensors is necessary to bring measurements to a common radiometric scale; it allows a more complete monitoring of land surface processes and enhances data continuity and harmonization. However, differences in the Relative Spectral Response (RSR) of sensors generate uncertainties in the process (Teillet et al., 2004). For this reason, compensating for these differences is of great importance and can be achieved by using a spectral band adjustment factor (SBAF), which establishes a relationship between two spectrally adjusted bands. Nonetheless, this relationship has been shown to depend greatly on the surface's NDVI (Trishchenko et al., 2002) and therefore needs to be corrected. In this work, we use the Sentinel 2 and Landsat sensor's RSRs for both the Red and NIR bands to find the most accurate metric towards performing said relationship, and use surface reflectance spectral libraries with a wide variety of classes that include NDVI values ranging from -0.1 to 1 to analyze its dependence. We compute a quadratic fit of the metric used vs the surface's NDVI and propose an adjusted correction equation dependent on the NDVI value for both bands of all Landsat and Sentinel 2 sensors. Key words: Radiometric calibration, RSR, Spectral Adjustment, Landsat, Sentinel 2.

  6. Phonon broadening in high entropy alloys

    Science.gov (United States)

    Körmann, Fritz; Ikeda, Yuji; Grabowski, Blazej; Sluiter, Marcel H. F.

    2017-09-01

    Refractory high entropy alloys feature outstanding properties making them a promising materials class for next-generation high-temperature applications. At high temperatures, materials properties are strongly affected by lattice vibrations (phonons). Phonons critically influence thermal stability, thermodynamic and elastic properties, as well as thermal conductivity. In contrast to perfect crystals and ordered alloys, the inherently present mass and force constant fluctuations in multi-component random alloys (high entropy alloys) can induce significant phonon scattering and broadening. Despite their importance, phonon scattering and broadening have so far only scarcely been investigated for high entropy alloys. We tackle this challenge from a theoretical perspective and employ ab initio calculations to systematically study the impact of force constant and mass fluctuations on the phonon spectral functions of 12 body-centered cubic random alloys, from binaries up to 5-component high entropy alloys, addressing the key question of how chemical complexity impacts phonons. We find that it is crucial to include both mass and force constant fluctuations. If one or the other is neglected, qualitatively wrong results can be obtained such as artificial phonon band gaps. We analyze how the results obtained for the phonons translate into thermodynamically integrated quantities, specifically the vibrational entropy. Changes in the vibrational entropy with increasing the number of elements can be as large as changes in the configurational entropy and are thus important for phase stability considerations. The set of studied alloys includes MoTa, MoTaNb, MoTaNbW, MoTaNbWV, VW, VWNb, VWTa, VWNbTa, VTaNbTi, VWNbTaTi, HfZrNb, HfMoTaTiZr.

  7. Probing the spectral density of the surface electromagnetic fields through scattering of waveguide photons.

    Science.gov (United States)

    Chen, Guang-Yin

    2016-02-10

    The spectral density of the metal-surface electromagnetic fields will be strongly modified in the presence of a closely-spaced quantum emitter. In this work, we propose a feasible way to probe the changes of the spectral density through the scattering of the waveguide photon incident on the quantum emitter. The variances of the lineshape in the transmission spectra indicate the coherent interaction between the emitter and the pseudomode resulting from all the surface electromagnetic modes. We further investigate the quantum coherence between the emitter and the pseudomode of the metal-dielectric interface.

  8. Global spectral graph wavelet signature for surface analysis of carpal bones

    Science.gov (United States)

    Masoumi, Majid; Rezaei, Mahsa; Ben Hamza, A.

    2018-02-01

    Quantitative shape comparison is a fundamental problem in computer vision, geometry processing and medical imaging. In this paper, we present a spectral graph wavelet approach for shape analysis of carpal bones of the human wrist. We employ spectral graph wavelets to represent the cortical surface of a carpal bone via the spectral geometric analysis of the Laplace-Beltrami operator in the discrete domain. We propose global spectral graph wavelet (GSGW) descriptor that is isometric invariant, efficient to compute, and combines the advantages of both low-pass and band-pass filters. We perform experiments on shapes of the carpal bones of ten women and ten men from a publicly-available database of wrist bones. Using one-way multivariate analysis of variance (MANOVA) and permutation testing, we show through extensive experiments that the proposed GSGW framework gives a much better performance compared to the global point signature embedding approach for comparing shapes of the carpal bones across populations.

  9. Hypersonic phononic crystals.

    Science.gov (United States)

    Gorishnyy, T; Ullal, C K; Maldovan, M; Fytas, G; Thomas, E L

    2005-03-25

    In this Letter we propose the use of hypersonic phononic crystals to control the emission and propagation of high frequency phonons. We report the fabrication of high quality, single crystalline hypersonic crystals using interference lithography and show that direct measurement of their phononic band structure is possible with Brillouin light scattering. Numerical calculations are employed to explain the nature of the observed propagation modes. This work lays the foundation for experimental studies of hypersonic crystals and, more generally, phonon-dependent processes in nanostructures.

  10. Phonon limited electronic transport in Pb

    DEFF Research Database (Denmark)

    Rittweger, Florian; Hinsche, Nicki Frank; Mertig, Ingrid

    2017-01-01

    We present a fully ab initio based scheme to compute electronic transport properties, i.e. the electrical conductivity σ and thermopower S, in the presence of electron-phonon interaction. We explicitly investigate the k-dependent structure of the Éliashberg spectral function, the coupling strength......, the linewidth and the relaxation time τ. We obtain a state-dependent τ and show its necessity to reproduce the increased thermopower for temperatures below the Debye temperature, without accounting for the phonon-drag effect. Despite the detailed investigations of various k- and q-dependencies, the presented...

  11. Surface of Maximums of AR(2 Process Spectral Densities and its Application in Time Series Statistics

    Directory of Open Access Journals (Sweden)

    Alexander V. Ivanov

    2017-09-01

    Conclusions. The obtained formula of surface of maximums of noise spectral densities gives an opportunity to realize for which values of AR(2 process characteristic polynomial coefficients it is possible to look for greater rate of convergence to zero of the probabilities of large deviations of the considered estimates.

  12. Probing surface plasmons in individual Ag nanoparticles in the ultra-violet spectral regime.

    Science.gov (United States)

    Chu, Ming-Wen; Sharma, Pradeep; Chang, Ching-Pin; Liou, Sz Chian; Tsai, Kun-Tong; Wang, Juen-Kai; Wang, Yuh-Lin; Chen, Cheng Hsuan

    2009-06-10

    Previous investigations of surface plasmons in Ag largely focused on their excitations in the visible spectral regime. Using scanning transmission electron microscopy with an electron beam of 0.2 nm in conjunction with electron energy-loss spectroscopy, we spectrally and spatially probe the surface plasmons in individual Ag nanoparticles (approximately 30 nm), grown on Si, in the ultra-violet spectral regime. The nanomaterials show respective sharp and broad surface-plasmon resonances at approximately 3.5 eV (approximately 355 nm) and approximately 7.0 eV (approximately 177 nm), and the correlated spectral calculations established their multipolar characteristics. The near-field distributions of the surface plasmons on the nanoparticles were also mapped out, revealing the predominant dipolar nature of the 3.5 eV excitation with obvious near-field enhancements at one end of the nano-object. The unveiled near-field enhancements have potential applications in plasmonics and molecular sensing.

  13. Probing surface plasmons in individual Ag nanoparticles in the ultra-violet spectral regime

    International Nuclear Information System (INIS)

    Chu, M-W; Chang, C-P; Liou, S C; Wang, J-K; Chen, C H; Sharma, Pradeep; Tsai, K-T; Wang, Y-L

    2009-01-01

    Previous investigations of surface plasmons in Ag largely focused on their excitations in the visible spectral regime. Using scanning transmission electron microscopy with an electron beam of 0.2 nm in conjunction with electron energy-loss spectroscopy, we spectrally and spatially probe the surface plasmons in individual Ag nanoparticles (∼30 nm), grown on Si, in the ultra-violet spectral regime. The nanomaterials show respective sharp and broad surface-plasmon resonances at ∼3.5 eV (∼355 nm) and ∼7.0 eV (∼177 nm), and the correlated spectral calculations established their multipolar characteristics. The near-field distributions of the surface plasmons on the nanoparticles were also mapped out, revealing the predominant dipolar nature of the 3.5 eV excitation with obvious near-field enhancements at one end of the nano-object. The unveiled near-field enhancements have potential applications in plasmonics and molecular sensing.

  14. Development of a low-cost, 11 µm spectral domain optical coherence tomography surface profilometry prototype

    Science.gov (United States)

    Suliali, Nyasha J.; Baricholo, Peter; Neethling, Pieter H.; Rohwer, Erich G.

    2017-06-01

    A spectral-domain Optical Coherence Tomography (OCT) surface profilometry prototype has been developed for the purpose of surface metrology of optical elements. The prototype consists of a light source, spectral interferometer, sample fixture and software currently running on Microsoft® Windows platforms. In this system, a broadband light emitting diode beam is focused into a Michelson interferometer with a plane mirror as its sample fixture. At the interferometer output, spectral interferograms of broadband sources were measured using a Czerny-Turner mount monochromator with a 2048-element complementary metal oxide semiconductor linear array as the detector. The software performs importation and interpolation of interferometer spectra to pre-condition the data for image computation. One dimensional axial OCT images were computed by Fourier transformation of the measured spectra. A first reflection surface profilometry (FRSP) algorithm was then formulated to perform imaging of step-function-surfaced samples. The algorithm re-constructs two dimensional colour-scaled slice images by concatenation of 21 and 13 axial scans to form a 10 mm and 3.0 mm slice respectively. Measured spectral interferograms, computed interference fringe signals and depth reflectivity profiles were comparable to simulations and correlated to displacements of a single reflector linearly translated about the arm null-mismatch point. Surface profile images of a double-step-function-surfaced sample, embedded with inclination and crack detail were plotted with an axial resolution of 11 μm. The surface shape, defects and misalignment relative to the incident beam were detected to the order of a micron, confirming high resolution of the developed system as compared to electro-mechanical surface profilometry techniques.

  15. The spectral curve theory for (k, l)-symmetric CMC surfaces

    Science.gov (United States)

    Heller, Lynn; Heller, Sebastian; Schmitt, Nicholas

    2015-12-01

    Constant mean curvature surfaces in S3 can be studied via their associated family of flat connections. In the case of tori this approach has led to a deep understanding of the moduli space of all CMC tori. For compact CMC surfaces of higher genus the theory is far more involved due to the non abelian nature of their fundamental group. In this paper we extend the spectral curve theory for tori developed in Hitchin (1990), Pinkall and Sterling (1989) and for genus 2 surfaces (Heller, 2014) to CMC surfaces in S3 of genus g = k ṡ l with commuting Zk+1 and Zl+1 symmetries. We determine their associated family of flat connections via certain flat line bundle connections parametrized by the spectral curve. We generalize the flow on spectral data introduced in Heller (2015) and prove the short time existence of this flow for certain families of initial surfaces. In this way we obtain countably many 1 -parameter families of new CMC surfaces of higher genus with prescribed branch points and prescribed umbilics.

  16. Near infrared imager for spectral and polarization analysis of planetary surfaces

    Science.gov (United States)

    Belyaev, D. A.; Yushkov, K. B.; Anikin, S. P.; Evdokimova, N. A.; Potanin, S. A.; Dobrolenskiy, Y. S.; Korablev, O. I.; Molchanov, V. Ya; Mantsevich, S. N.

    2017-09-01

    We propose a concept of an imaging near-IR spectrometer for sensing of planetary surfaces. This instrument is intended to analyze mineralogical and, in some cases, petrographic composition of the upper surface layer in the planetary regolith; to identify and monitor OH/H2O bearing minerals and water adsorption in this layer. The scheme of the spectrometer was designed on a basis of an acousto-optic tunable filter (AOTF) that allows imaging of samples in two orthogonal polarization planes simultaneously. Images are registered as a light (e.g. solar one) reflected and scattered from an observed target in the near infrared spectral range. The AOTF's electrical tuning provides fast and flexible spectral scanning of an image through whole the range analyzed - potentially, ten microseconds per a spectral point. Thus, it is possible to explore reflectance spectra of specified areas on a sample and to detect its minerals composition and microstructure variations. In parallel, one can estimate polarization contrast at different wavelengths thanks to the AOTF's birefringence properties. In this paper we report design and performance of a laboratory prototype for the near-IR spectro-polarimeteric imaging AOTF system operating in the spectral range from 0.8 to 1.75 μm. Reflectance spectra of some minerals were measured with the spectral resolution of 100 cm-1 (passband 10 nm at 1 μm). When imaging samples the spatial resolution as high as 0.5 mm was reached at the target distance of one meter. It corresponds to 100 by 100 resolving elements on the CCD matrix for each of two polarizations of the reflected light. Such a concept is also being designed for the spectral range from 1.7 to 3.5 μm.

  17. Spectral asymptotics of a strong δ′ interaction supported by a surface

    International Nuclear Information System (INIS)

    Exner, Pavel; Jex, Michal

    2014-01-01

    Highlights: • Attractive δ ′ interactions supported by a smooth surface are considered. • Surfaces can be either infinite and asymptotically planar, or compact and closed. • Spectral asymptotics is determined by the geometry of the interaction support. - Abstract: We derive asymptotic expansion for the spectrum of Hamiltonians with a strong attractive δ ′ interaction supported by a smooth surface in R 3 , either infinite and asymptotically planar, or compact and closed. Its second term is found to be determined by a Schrödinger type operator with an effective potential expressed in terms of the interaction support curvatures

  18. Development of a high spectral resolution surface albedo product for the ARM Southern Great Plains Central Facility

    Energy Technology Data Exchange (ETDEWEB)

    McFarlane, Sally A.; Gaustad, Krista L.; Mlawer, Eli J.; Long, Charles N.; Delamere, Jennifer

    2011-09-01

    We present a method for identifying dominant surface type and estimating high spectral resolution surface albedo at the Atmospheric Radiation Measurement (ARM) facility at the Southern Great Plains (SGP) site in Oklahoma for use in radiative transfer calculations. Given a set of 6-channel narrowband visible and near-infrared irradiance measurements from upward and downward looking multi-filter radiometers (MFRs), four different surface types (snow-covered, green vegetation, partial vegetation, non-vegetated) can be identified. A normalized difference vegetation index (NDVI) is used to distinguish between vegetated and non-vegetated surfaces, and a scaled NDVI index is used to estimate the percentage of green vegetation in partially vegetated surfaces. Based on libraries of spectral albedo measurements, a piecewise continuous function is developed to estimate the high spectral resolution surface albedo for each surface type given the MFR albedo values as input. For partially vegetated surfaces, the albedo is estimated as a linear combination of the green vegetation and non-vegetated surface albedo values. The estimated albedo values are evaluated through comparison to high spectral resolution albedo measurements taken during several Intensive Observational Periods (IOPs) and through comparison of the integrated spectral albedo values to observed broadband albedo measurements. The estimated spectral albedo values agree well with observations for the visible wavelengths constrained by the MFR measurements, but have larger biases and variability at longer wavelengths. Additional MFR channels at 1100 nm and/or 1600 nm would help constrain the high resolution spectral albedo in the near infrared region.

  19. Development of a high spectral resolution surface albedo product for the ARM Southern Great Plains central facility

    Science.gov (United States)

    McFarlane, S. A.; Gaustad, K. L.; Mlawer, E. J.; Long, C. N.; Delamere, J.

    2011-09-01

    We present a method for identifying dominant surface type and estimating high spectral resolution surface albedo at the Atmospheric Radiation Measurement (ARM) facility at the Southern Great Plains (SGP) site in Oklahoma for use in radiative transfer calculations. Given a set of 6-channel narrowband visible and near-infrared irradiance measurements from upward and downward looking multi-filter radiometers (MFRs), four different surface types (snow-covered, green vegetation, partial vegetation, non-vegetated) can be identified. A normalized difference vegetation index (NDVI) is used to distinguish between vegetated and non-vegetated surfaces, and a scaled NDVI index is used to estimate the percentage of green vegetation in partially vegetated surfaces. Based on libraries of spectral albedo measurements, a piecewise continuous function is developed to estimate the high spectral resolution surface albedo for each surface type given the MFR albedo values as input. For partially vegetated surfaces, the albedo is estimated as a linear combination of the green vegetation and non-vegetated surface albedo values. The estimated albedo values are evaluated through comparison to high spectral resolution albedo measurements taken during several Intensive Observational Periods (IOPs) and through comparison of the integrated spectral albedo values to observed broadband albedo measurements. The estimated spectral albedo values agree well with observations for the visible wavelengths constrained by the MFR measurements, but have larger biases and variability at longer wavelengths. Additional MFR channels at 1100 nm and/or 1600 nm would help constrain the high resolution spectral albedo in the near infrared region.

  20. Polarization dependent behavior of CdS around the first and second LO-phonon modes

    Energy Technology Data Exchange (ETDEWEB)

    Frausto-Reyes, C., E-mail: cfraus@cio.mx [Centro de Investigaciones en Optica AC, Unidad Aguascalientes, Prolong., Constitucion 607, Fracc. Reserva Loma Bonita, CP 20200, Apartado Postal 507, Ags. (Mexico); Molina-Contreras, J.R., E-mail: rmolina@correo.ita.mx [Departamento de Ingenieria Electrica y Electronica, Instituto Tecnologico de Aguascalientes, Av. Lopez Mateos 1081 Oriente, Fracc. Bonna Gens, CP 20256, Aguascalientes, Ags. (Mexico); Lopez-Alvarez, Y.F. [Departamento de Ingenieria Electrica y Electronica, Instituto Tecnologico de Aguascalientes, Av. Lopez Mateos 1081 Oriente, Fracc. Bonna Gens, CP 20256, Aguascalientes, Ags. (Mexico); Medel-Ruiz, C.I.; Perez Ladron de Guevara, H. [Universidad de Guadalajara, Centro Universitario de los Lagos, Av. Enrique Diaz de Leon s/n, Fracc. Paseos de la Montana, CP 47460, Lagos de Moreno, Jal. (Mexico); Ortiz-Morales, M. [Centro de Investigaciones en Optica AC, Unidad Aguascalientes, Prolong., Constitucion 607, Fracc. Reserva Loma Bonita, CP 20200, Apartado Postal 507, Ags. (Mexico)

    2010-10-25

    The present work report studies on resonant Raman experimental line shape for CdS around the first and second LO-phonon modes. The application of our method to the study of LO-phonon modes of CdS suggests that the scattered intensity is dominated by the surface and dependent on polarization. Results showed that the Raman spectra for CdS, roughly fall into three groups: a broad line-wing with apparent maxima around 194 cm{sup -1} in the range of 140 and 240 cm{sup -1} which can be ascribed to overtone scattering from acoustic phonons; a band near the 1LO phonon mode which can be attributed to a combination of one-phonon scattering and peak acoustic phonon and finally, a band near the 2LO phonon mode which can be attributed to a combination of two-phonon scattering and peak acoustic phonon.

  1. Coherent generation of acoustic phonons in an optical microcavity

    International Nuclear Information System (INIS)

    Lanzillotti-Kimura, N D; Fainstein, A; Huynh, A; Perrin, B; Jusserand, B; Miard, A; LemaItre, A

    2007-01-01

    Coherent acoustic phonons confined in a nanocavity are generated in an optical microcavity. The confinement of the femtosecond light pulse in the optical resonator amplifies both processes, generation and detection of the acoustic phonons. In addition, due to the standing wave character of the photon field, phonons of wavevector q = 0 and q = 2k (k is the light wavenumber) contribute to both the generation and detection in time resolved reflectivity measurements, further optimizing the pump and probe experiments. Time resolved differential reflectivity experiments are reported as a function of laser energy. The optical cavity resonance is apparent in the amplitude and spectral features of the Fourier transformed signals

  2. Properties of nanocones formed on a surface of semiconductors by laser radiation: quantum confinement effect of electrons, phonons, and excitons

    Directory of Open Access Journals (Sweden)

    Medvid Artur

    2011-01-01

    Full Text Available Abstract On the basis of the analysis of experimental results, a two-stage mechanism of nanocones formation on the irradiated surface of semiconductors by Nd:YAG laser is proposed for elementary semiconductors and solid solutions, such as Si, Ge, SiGe, and CdZnTe. Properties observed are explained in the frame of quantum confinement effect. The first stage of the mechanism is characterized by the formation of a thin strained top layer, due to redistribution of point defects in temperature-gradient field induced by laser radiation. The second stage is characterized by mechanical plastic deformation of the stained top layer leading to arising of nanocones, due to selective laser absorption of the top layer. The nanocones formed on the irradiated surface of semiconductors by Nd:YAG laser possessing the properties of 1D graded bandgap have been found for Si, Ge, and SiGe as well, however QD structure in CdTe was observed. The model is confirmed by "blue shift" of bands in photoluminescence spectrum, "red shift" of longitudinal optical line in Raman back scattering spectrum of Ge crystal, appearance of Ge phase in SiGe solid solution after irradiation by the laser at intensity 20 MW/cm2, and non-monotonous dependence of Si crystal micro-hardness as function of the laser intensity.

  3. Birefringent phononic structures

    Directory of Open Access Journals (Sweden)

    I. E. Psarobas

    2014-12-01

    Full Text Available Within the framework of elastic anisotropy, caused in a phononic crystal due to low crystallographic symmetry, we adopt a model structure, already introduced in the case of photonic metamaterials, and by analogy, we study the effect of birefringence and acoustical activity in a phononic crystal. In particular, we investigate its low-frequency behavior and comment on the factors which determine chirality by reference to this model.

  4. Electron-phonon coupling in graphene placed between magnetic Li and Si layers on cobalt

    Science.gov (United States)

    Usachov, Dmitry Yu.; Fedorov, Alexander V.; Vilkov, Oleg Yu.; Ogorodnikov, Ilya I.; Kuznetsov, Mikhail V.; Grüneis, Alexander; Laubschat, Clemens; Vyalikh, Denis V.

    2018-02-01

    Using angle-resolved photoemission spectroscopy (ARPES), we study the electronic structure and electron-phonon coupling in a Li-doped graphene monolayer decoupled from the Co(0001) substrate by intercalation of silicon. Based on the photoelectron diffraction measurements, we disclose the structural properties of the Si/Co interface. Our density functional theory calculations demonstrate that in the studied Li/graphene/Si/Co system the magnetism of Co substrate induces notable magnetic moments on Li and Si atoms. At the same time graphene remains almost nonmagnetic and clamped between two magnetically active atomic layers with antiparallel magnetizations. ARPES maps of the graphene Fermi surface reveal strong electron doping, which may lead to superconductivity mediated by electron-phonon coupling (EPC). Analysis of the spectral function of photoelectrons reveals apparent anisotropy of EPC in the k space. These properties make the studied system tempting for studying the relation between superconductivity and magnetism in two-dimensional materials.

  5. Phonon interference control of atomic-scale metamirrors, meta-absorbers, and heat transfer through crystal interfaces

    Science.gov (United States)

    Kosevich, Yu. A.; Potyomina, L. G.; Darinskii, A. N.; Strelnikov, I. A.

    2018-03-01

    The paper theoretically studies the possibility of using the effects of phonon interference between paths through different interatomic bonds for the control of phonon heat transfer through internal crystal interfaces and for the design of phonon metamirrors and meta-absorbers. These metamirrors and meta-absorbers are considered to be defect nanolayers of atomic-scale thicknesses embedded in a crystal. Several analytically solvable three-dimensional lattice-dynamics models of the phonon metamirrors and meta-absorbers at the internal crystal planes are described. It is shown that due to destructive interference in the two or more phonon paths, the internal crystal planes, fully or partially filled with weakly bound or heavy-isotope defect atoms, can completely reflect or completely absorb phonons at the transmission antiresonances, whose wavelengths are larger than the effective thickness of the metamirror or meta-absorber. Due to cooperative superradiant effect, the spectral widths of the two-path interference antiresonances for the plane waves are given by the square of partial filling fraction in the defect crystal plane. Our analysis reveals that the presence of two or more phonon paths plays the dominant role in the emergence of the transmission antiresonances in phonon scattering at the defect crystal planes and in reduction of the thermal interface conductance in comparison with the Fano-resonance concept. We study analytically phonon transmission through internal crystal plane in a model cubic lattice of Si-like atoms, partially filled with Ge-like defect atoms. Such a plane can serve as interference phonon metamirror with the transmission antiresonances in the vicinities of eigenmode frequencies of Ge-like defect atoms in the terahertz frequency range. We predict the extraordinary phonon transmission induced by the two-path constructive interference of the lattice waves in resonance with the vibrations of rare host atoms, periodically distributed in the

  6. The Spectral Nature of Titan's Major Geomorphological Units: Constraints on Surface Composition

    Science.gov (United States)

    Solomonidou, A.; Coustenis, A.; Lopes, R. M. C.; Malaska, M. J.; Rodriguez, S.; Drossart, P.; Elachi, C.; Schmitt, B.; Philippe, S.; Janssen, M.; Hirtzig, M.; Wall, S.; Sotin, C.; Lawrence, K.; Altobelli, N.; Bratsolis, E.; Radebaugh, J.; Stephan, K.; Brown, R. H.; Le Mouélic, S.; Le Gall, A.; Villanueva, E. V.; Brossier, J. F.; Bloom, A. A.; Witasse, O.; Matsoukas, C.; Schoenfeld, A.

    2018-02-01

    We investigate Titan's low-latitude and midlatitude surface using spectro-imaging near-infrared data from Cassini/Visual and Infrared Mapping Spectrometer. We use a radiative transfer code to first evaluate atmospheric contributions and then extract the haze and the surface albedo values of major geomorphological units identified in Cassini Synthetic Aperture Radar data, which exhibit quite similar spectral response to the Visual and Infrared Mapping Spectrometer data. We have identified three main categories of albedo values and spectral shapes, indicating significant differences in the composition among the various areas. We compare with linear mixtures of three components (water ice, tholin-like, and a dark material) at different grain sizes. Due to the limited spectral information available, we use a simplified model, with which we find that each albedo category of regions of interest can be approximately fitted with simulations composed essentially by one of the three surface candidates. Our fits of the data are overall successful, except in some cases at 0.94, 2.03, and 2.79 μm, indicative of the limitations of our simplistic compositional model and the need for additional components to reproduce Titan's complex surface. Our results show a latitudinal dependence of Titan's surface composition, with water ice being the major constituent at latitudes beyond 30°N and 30°S, while Titan's equatorial region appears to be dominated partly by a tholin-like or by a very dark unknown material. The albedo differences and similarities among the various geomorphological units give insights on the geological processes affecting Titan's surface and, by implication, its interior. We discuss our results in terms of origin and evolution theories.

  7. Supra-ballistic phonons

    International Nuclear Information System (INIS)

    Russell, F.M.

    1989-05-01

    Energetic particles moving with a solid, either from nuclear reactions or externally injected, deposit energy by inelastic scattering processes which eventually appears as thermal energy. If the transfer of energy occurs in a crystalline solid then it is possible to couple some of the energy directly to the nuclei forming the lattice by generating phonons. In this paper the transfer of energy from a compound excited nucleus to the lattice is examined by introducing a virtual particle Π. It is shown that by including a Π in the nuclear reaction a substantial amount of energy can be coupled directly to the lattice. In the lattice this particle behaves as a spatially localized phonon of high energy, the so-called supra-ballistic phonon. By multiple inelastic scattering the supra-ballistic phonon eventually thermalizes. Because both the virtual particle Π and the equivalent supra-ballistic phonon have no charge or spin and can only exist within a lattice it is difficult to detect other than by its decay into thermal phonons. The possibility of a Π removing excess energy from a compound nucleus formed by the cold fusion of deuterium is examined. (Author)

  8. Wet-etched phononic crystal waveguiding on GaAs

    Science.gov (United States)

    Muzar, Edward; Azodi Aval, Golnaz; Stotz, James A. H.

    2018-01-01

    A wet-etched phononic crystal waveguide in GaAs with approximately two micron deep inclusions is studied both numerically and experimentally for controlled surface acoustic wave propagation. Numerically, the phononic crystal was modelled using the finite element method (FEM) with COMSOL Multiphysics, and the surface displacement of the acoustic waves was measured using optical interferometry. The computed filter response of the phononic crystal confirmed that the phononic crystal was an effective stop band filter in the interval of 400 MHz and 450 MHz. An L1 linear defect waveguide with a stepped funnel entrance design is shown to perform well at a surface acoustic wave frequency of 410.344 MHz and in agreement to simulated results. The phononic crystal waveguide system shows promise for use in acoustic control of GaAs-based quantum nanostructures.

  9. Phonon frequency shift and effect of correlation on the electron ...

    Indian Academy of Sciences (India)

    P.G. Department of Physics, Sambalpur University, Jyoti Vihar, Burla 768 019, India. *. Institute of Physics ... observed magneto-elastic effect (coupling of phonon to thef-electrons), anisotropic Fermi surface, Kondo ... Considering the importance of the lanthanide contraction in these systems, the phonons are assumed to ...

  10. Upwelling UV spectral irradiances and surface albedo measurements at Lauder, New Zealand

    Science.gov (United States)

    McKenzie, R. L.; Kotkamp, M.; Ireland, W.

    Simultaneous measurements of upwelling and downwelling ultraviolet (UV) spectral irradiance were used to deduce the wavelength dependence and the solar zenith angle dependence of the albedo of the ground surface (long grass) at Lauder, New Zealand (45.05°S, 169.68°E). In the UVB region the deduced albedos are approximately 1%. At longer wavelengths the albedo increases to approximately 2% at 400 nm, and 4.5% at 450 nm. These albedos are significantly smaller than those generally quoted for the visible region. The deduced albedos tend to increase at larger solar zenith angles, demonstrating that the surface is not strictly Lambertian.

  11. High-Resolution Faraday Rotation and Electron-Phonon Coupling in Surface States of the Bulk-Insulating Topological Insulator Cu_{0.02}Bi_{2}Se_{3}.

    Science.gov (United States)

    Wu, Liang; Tse, Wang-Kong; Brahlek, M; Morris, C M; Aguilar, R Valdés; Koirala, N; Oh, S; Armitage, N P

    2015-11-20

    We have utilized time-domain magnetoterahertz spectroscopy to investigate the low-frequency optical response of the topological insulator Cu_{0.02}Bi_{2}Se_{3} and Bi_{2}Se_{3} films. With both field and frequency dependence, such experiments give sufficient information to measure the mobility and carrier density of multiple conduction channels simultaneously. We observe sharp cyclotron resonances (CRs) in both materials. The small amount of Cu incorporated into the Cu_{0.02}Bi_{2}Se_{3} induces a true bulk insulator with only a single type of conduction with a total sheet carrier density of ~4.9×10^{12}/cm^{2} and mobility as high as 4000 cm^{2}/V·s. This is consistent with conduction from two virtually identical topological surface states (TSSs) on the top and bottom of the film with a chemical potential ~145 meV above the Dirac point and in the bulk gap. The CR broadens at high fields, an effect that we attribute to an electron-phonon interaction. This assignment is supported by an extended Drude model analysis of the zero-field Drude conductance. In contrast, in normal Bi_{2}Se_{3} films, two conduction channels were observed, and we developed a self-consistent analysis method to distinguish the dominant TSSs and coexisting trivial bulk or two-dimensional electron gas states. Our high-resolution Faraday rotation spectroscopy on Cu_{0.02}Bi_{2}Se_{3} paves the way for the observation of quantized Faraday rotation under experimentally achievable conditions to push the chemical potential in the lowest Landau level.

  12. Effect of surface cleaning on spectral response for InGaAs photocathodes.

    Science.gov (United States)

    Jin, Muchun; Zhang, Yijun; Chen, Xinlong; Hao, Guanghui; Chang, Benkang; Shi, Feng

    2015-12-20

    Photocathode surface treatment aims to obtain high sensitivity, where the key point is to acquire an atomically clean surface. Various surface cleaning methods for removing contamination from InGaAs photocathode surfaces were investigated. The atomic compositions of InGaAs photocathode structures and surfaces were measured by x-ray photoelectron spectroscopy and Ar ion sputtering. After surface cleaning, the InGaAs surface is arsenoxide-free, however, a small amount of Ga2O3 and In2O3 still can be found. The 1:1 mixed solution of hydrochloric acid to deionized water followed by thermal annealing at 525°C has been demonstrated to be the best choice in dealing with the surface oxides. After the Cs/O activation, a surface model was proposed where the oxides on the surface will lead to a positive electron affinity, adversely affecting low-energy electrons escaping to the vacuum, which is reflected by the photocurrent curves and the spectral response curves.

  13. Spectrally resolved surface plasmon resonance dispersion using half-ball optics

    Science.gov (United States)

    Dehmel, Raphael; Baumberg, Jeremy J.; Steiner, Ullrich; Wilts, Bodo D.

    2017-11-01

    In this work, a variant of a Kretschmann-type surface plasmon resonance (SPR) sensor is introduced. k-space imaging is combined with half-ball glass optics to facilitate the measurement of SPRs across the visible spectral range. In contrast to current state-of-the-art techniques, which are widely utilized in commercially available systems, the presented method allows single-shot-acquisition of the full angular reflection without any moving parts, as well as mapping of the surface plasmon dispersion by scanning across the entire visible wavelength range. Measurements on various thin metallic films demonstrate the sensitivity of the system towards minute changes of the metal surface and its close vicinity. The fast and precise measurement of surface plasmon resonances paves the way for improved detection in applications such as immunoassays or gas-sensors, especially for real-time in situ measurements.

  14. Electron-phonon interactions and the phonon anomaly in β-phase NiTi

    International Nuclear Information System (INIS)

    Zhao, G.L.; Harmon, B.N.

    1993-01-01

    The electronic structure of β-phase NiTi has been calculated using a first-principles linear-combination-of-atomic-orbitals method. The resulting band structure was fitted with a nonorthogonal tight-binding Hamiltonian from which electron-phonon matrix elements were evaluated. The soft phonon near Q 0 =(2/3, 2) / (3 ,0)π/a, which is responsible for the premartensitic phase transition in β-phase NiTi, is found to arise from the strong electron-phonon coupling of nested electronic states on the Fermi surface. Thermal vibrations and changes in electronic occupation cause a smearing of the nested features, which in turn cause a hardening of the phonon anomaly

  15. Spectral decomposition of internal gravity wave sea surface height in global models

    Science.gov (United States)

    Savage, Anna C.; Arbic, Brian K.; Alford, Matthew H.; Ansong, Joseph K.; Farrar, J. Thomas; Menemenlis, Dimitris; O'Rourke, Amanda K.; Richman, James G.; Shriver, Jay F.; Voet, Gunnar; Wallcraft, Alan J.; Zamudio, Luis

    2017-10-01

    Two global ocean models ranging in horizontal resolution from 1/12° to 1/48° are used to study the space and time scales of sea surface height (SSH) signals associated with internal gravity waves (IGWs). Frequency-horizontal wavenumber SSH spectral densities are computed over seven regions of the world ocean from two simulations of the HYbrid Coordinate Ocean Model (HYCOM) and three simulations of the Massachusetts Institute of Technology general circulation model (MITgcm). High wavenumber, high-frequency SSH variance follows the predicted IGW linear dispersion curves. The realism of high-frequency motions (>0.87 cpd) in the models is tested through comparison of the frequency spectral density of dynamic height variance computed from the highest-resolution runs of each model (1/25° HYCOM and 1/48° MITgcm) with dynamic height variance frequency spectral density computed from nine in situ profiling instruments. These high-frequency motions are of particular interest because of their contributions to the small-scale SSH variability that will be observed on a global scale in the upcoming Surface Water and Ocean Topography (SWOT) satellite altimetry mission. The variance at supertidal frequencies can be comparable to the tidal and low-frequency variance for high wavenumbers (length scales smaller than ˜50 km), especially in the higher-resolution simulations. In the highest-resolution simulations, the high-frequency variance can be greater than the low-frequency variance at these scales.

  16. Phonon dispersion in vanadium

    International Nuclear Information System (INIS)

    Ivanov, A.S.; Rumiantsev, A.Yu.

    1999-01-01

    Complete text of publication follows. Phonon dispersion curves in Vanadium metal are investigated by neutron inelastic scattering using three-axis spectrometers. Due to extremely low coherent scattering amplitude of neutrons in natural isotope mixture of vanadium the phonon frequencies could be determined in the energy range below about 15 meV. Several phonon groups were measured with the polarised neutron scattering set-up. It is demonstrated that the intensity of coherent inelastic scattering observed in the non-spin-flip channel vanishes in the spin-flip channel. The phonon density of states is measured on a single crystal keeping the momentum transfer equal to a vector of reciprocal lattice where the coherent inelastic scattering is suppressed. Phonon dispersion curves in vanadium, as measured by neutron and earlier by X-ray scattering, are described in frames of a charge-fluctuation model involving monopolar and dipolar degrees of freedom. The model parameters are compared for different transition metals with body-centred cubic-structure. (author)

  17. Surface Compositional Units on Mercury from Spectral Reflectance at Ultraviolet to Near-infrared Wavelengths

    Science.gov (United States)

    Izenberg, N. R.; Holsclaw, G. M.; Domingue, D. L.; McClintock, W. E.; Klima, R. L.; Blewett, D. T.; Helbert, J.; Head, J. W.; Sprague, A. L.; Vilas, F.; Solomon, S. C.

    2012-12-01

    The Mercury Atmospheric and Surface Composition Spectrometer (MASCS) on the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft has been acquiring reflectance spectra of Mercury's surface for over 16 months. The Visible and Infrared Spectrograph (VIRS) component of MASCS has accumulated a global data set of more than 2 million spectra over the wavelength range 300-1450 nm. We have derived a set of VIRS spectral units (VSUs) from the following spectral parameters: visible brightness (R575: reflectance at 575 nm); visible/near-infrared reflectance ratio (VISr: reflectance at 415 nm to that at 750 nm); and ultraviolet reflectance ratio (UVr: reflectance at 310 nm to that at 390 nm). Five broad, slightly overlapping VSUs may be distinguished from these parameters. "Average VSU" areas have spectral parameters close to mean global values. "Dark blue VSU" areas have spectra with low R575 and high UVr. "Red VSU" areas have spectra with low UVr and higher VISr and R575 than average. "Intermediate VSU" areas have spectra with higher VISr than VSU red, generally higher R575, and a wide range of UVr. "Bright VSU" areas have high R575 and VISr and intermediate UVr. Several units defined by morphological or multispectral criteria correspond to specific VSUs, including low-reflectance material (dark blue VSU), pyroclastic deposits (red VSU), and hollows (intermediate VSU), but these VSUs generally include other types of areas as well. VSU definitions are complementary to those obtained by unsupervised clustering analysis. The global distribution of VIRS spectral units provides new information on Mercury's geological evolution. Much of Mercury's northern volcanic plains show spectral properties ranging from those of average VSU to those of red VSU, as does a large region in the southern hemisphere centered near 50°S, 245°E. Dark blue VSU material is widely distributed, with concentrations south of the northern plains, around the Rembrandt and

  18. Phonon superradiance and phonon laser effect in nanomagnets.

    Science.gov (United States)

    Chudnovsky, E M; Garanin, D A

    2004-12-17

    We show that the theory of spin-phonon processes in paramagnetic solids must take into account the coherent generation of phonons by the magnetic centers. This effect should drastically enhance spin-phonon rates in nanoscale paramagnets and in crystals of molecular nanomagnets.

  19. Phonon density of states in nanocrystalline Fe

    Indian Academy of Sciences (India)

    Kara and Rahman [10] did the cluster calculations using the interaction potential based on the embedded ... It is found that in the interior of the clusters large capillary pressure is built up and the surface tension derived .... results due to flatness of phonon dispersion relations in the transverse branch in the [111] direction at ζ ...

  20. Classification of Clean and Dirty Pighouse Surfaces Based on Spectral Reflectance

    DEFF Research Database (Denmark)

    Blanke, Mogens; Braithwaite, Ian David; Zhang, Guo-Qiang

    2004-01-01

    Current pig house cleaning procedures are hazardous to the health of farm workers, and yet necessary if the spread of disease between batches of animals is to be satisfactorily controlled. Autonomous cleaning using robot technology offers salient benefits. This report addresses the feasibility...... of designing a vision based system to locate dirty areas and subsequently direct a cleaning robot to remove dirt. Novel results include the characterisation of the spectral reflectance of real surfaces and dirt in a pig house and the design of illumination to obtain discrimination of clean from dirty areas...

  1. Spectral-Modulation Characteristics of Vertical-Cavity Surface-Emitting Lasers

    Science.gov (United States)

    Vas'kovskaya, M. I.; Vasil'ev, V. V.; Zibrov, S. A.; Yakovlev, V. P.; Velichanskii, V. L.

    2018-01-01

    The requirements imposed on vertical-cavity surface-emitting lasers in a number of metrological problems in which optical pumping of alkali atoms is used are considered. For lasers produced by different manufacturers, these requirements are compared with the experimentally observed spectral characteristics at a constant pump current and in the microwave modulation mode. It is shown that a comparatively small number of lasers in the microwave modulation mode make it possible to obtain the spectrum required for atomic clocks based on the coherent population-trapping effect.

  2. Asteroid surface archaeology: Identification of eroded impact structures by spectral properties on (4) Vesta

    Science.gov (United States)

    Hoffmann, M.; Nathues, A.; Schäfer, M.; Schmedemann, N.; Vincent, J.; Russell, C.

    2014-07-01

    Introduction: Vesta's surface material is characterized as a deep regolith [1,2], mobilized by countless impacts. The almost catastrophic impact near Vesta's south pole, which has created the Rheasilvia basin, and the partly overlapping older impact of similar size, Veneneia, have not only reshaped the areas of their interior (roughly 50 % of the Vesta surface), but also emplaced each time a huge ejecta blanket of similar size, thus covering the whole remaining surface. In this context, pristine and even younger morphologic features have been erased. However, the spectral signatures of the early differentiation and alteration products by impacts have partially remained in situ. While near the north pole several large old eroded impact features are visible, the equatorial zone close to the basin rims seems to be void of those. Since it is unlikely, that this zone has been entirely avoided by large projectiles, in this area the results of such impacts may have left morphologically not detectable remnants: Individual distribution of particle sizes and altered photometric properties, excavated layers, shock metamorphism, melt generation inside particles and on macroscopic scales, and emplacement of exogenous projectile material. An analysis by color ratio images and spatial profiles of diagnostic spectral parameters reveals such features. Results: Based on local spectroscopic evidence we have detected eroded impact features of three categories: 1) Small craters with diameters of a few kilometers, 2) Large craters or, if even larger, incipient impact basins, 3) Sub-global ejecta blankets. The eastern part of Feralia Planitia, diameter 140 km, has little evidence of a round outline in the shape model, but it features spectral gradients towards its center. A feature of similar size, centered north of Lucaria Tholus becomes only visible by a similar spectra gradient and a circular outline in specific spectral ratio mosaics. These features seem to be related to the

  3. Preface: Phonons 2007

    Science.gov (United States)

    Perrin, Bernard

    2007-06-01

    logo.jpg" ALT="Conference logo"/> The conference PHONONS 2007 was held 15-20 July 2007 in the Conservatoire National des Arts et Métiers (CNAM) Paris, France. CNAM is a college of higher technology for training students in the application of science to industry, founded by Henri Grégoire in 1794. This was the 12th International Conference on Phonon Scattering in Condensed Matter. This international conference series, held every 3 years, started in France at Sainte-Maxime in 1972. It was then followed by meetings at Nottingham (1975), Providence (1979), Stuttgart (1983), Urbana-Champaign (1986), Heidelberg (1989), Ithaca (1992), Sapporo (1995), Lancaster (1998), Dartmouth (2001) and St Petersburg (2004). PHONONS 2007 was attended by 346 delegates from 37 different countries as follows: France 120, Japan 45, Germany 25, USA 25, Russia 21, Italy 13, Poland 9, UK 9, Canada 7, The Netherlands 7, Finland 6, Spain 6, Taiwan 6, Greece 4, India 4, Israel 4, Ukraine 4, Serbia 3, South Africa 3, Argentina 2, Belgium 2, China 2, Iran 2, Korea 2, Romania 2, Switzerland 2, and one each from Belarus, Bosnia-Herzegovina, Brazil, Bulgaria, Egypt, Estonia, Mexico, Moldova, Morocco, Saudi Arabia, Turkey. There were 5 plenary lectures, 14 invited talks and 84 oral contributions; 225 posters were presented during three poster sessions. The first plenary lecture was given by H J Maris who presented fascinating movies featuring the motion of a single electron in liquid helium. Robert Blick gave us a review on the new possibilities afforded by nanotechnology to design nano-electomechanical systems (NEMS) and the way to use them to study elementary and fundamental processes. The growing interest for phonon transport studies in nanostructured materials was demonstrated by Arun Majumdar. Andrey Akimov described how ultrafast acoustic solitons can monitor the optical properties of quantum wells. Finally, Maurice Chapellier told us how phonons can help tracking dark matter. These 328

  4. Impact of soil moisture and winter wheat height from the Loess Plateau in Northwest China on surface spectral albedo

    Science.gov (United States)

    Li, Zhenchao; Yang, Jiaxi; Gao, Xiaoqing; Zheng, Zhiyuan; Yu, Ye; Hou, Xuhong; Wei, Zhigang

    2018-02-01

    The understanding of surface spectral radiation and reflected radiation characteristics of different surfaces in different climate zones aids in the interpretation of regional surface energy transfers and the development of land surface models. This study analysed surface spectral radiation variations and corresponding surface albedo characteristics at different wavelengths as well as the relationship between 5-cm soil moisture and surface albedo on typical sunny days during the winter wheat growth period. The analysis was conducted using observational Loess Plateau winter wheat data from 2015. The results show that the ratio of atmospheric downward radiation to global radiation on typical sunny days is highest for near-infrared wavelengths, followed by visible wavelengths and ultraviolet wavelengths, with values of 57.3, 38.7 and 4.0%, respectively. The ratio of reflected spectral radiation to global radiation varies based on land surface type. The visible radiation reflected by vegetated surfaces is far less than that reflected by bare ground, with surface albedos of 0.045 and 0.27, respectively. Thus, vegetated surfaces absorb more visible radiation than bare ground. The atmospheric downward spectral radiation to global radiation diurnal variation ratios vary for near-infrared wavelengths versus visible and ultraviolet wavelengths on typical sunny days. The near-infrared wavelengths ratio is higher in the morning and evening and lower at noon. The visible and ultraviolet wavelengths ratios are lower in the morning and evening and higher at noon. Visible and ultraviolet wavelength surface albedo is affected by 5-cm soil moisture, demonstrating a significant negative correlation. Excluding near-infrared wavelengths, correlations between surface albedo and 5-cm soil moisture pass the 99% confidence test at each wavelength. The correlation with 5-cm soil moisture is more significant at shorter wavelengths. However, this study obtained surface spectral radiation

  5. Development of a high spectral resolution surface albedo product for the ARM Southern Great Plains central facility

    Directory of Open Access Journals (Sweden)

    J. Delamere

    2011-09-01

    Full Text Available We present a method for identifying dominant surface type and estimating high spectral resolution surface albedo at the Atmospheric Radiation Measurement (ARM facility at the Southern Great Plains (SGP site in Oklahoma for use in radiative transfer calculations. Given a set of 6-channel narrowband visible and near-infrared irradiance measurements from upward and downward looking multi-filter radiometers (MFRs, four different surface types (snow-covered, green vegetation, partial vegetation, non-vegetated can be identified. A normalized difference vegetation index (NDVI is used to distinguish between vegetated and non-vegetated surfaces, and a scaled NDVI index is used to estimate the percentage of green vegetation in partially vegetated surfaces. Based on libraries of spectral albedo measurements, a piecewise continuous function is developed to estimate the high spectral resolution surface albedo for each surface type given the MFR albedo values as input. For partially vegetated surfaces, the albedo is estimated as a linear combination of the green vegetation and non-vegetated surface albedo values. The estimated albedo values are evaluated through comparison to high spectral resolution albedo measurements taken during several Intensive Observational Periods (IOPs and through comparison of the integrated spectral albedo values to observed broadband albedo measurements. The estimated spectral albedo values agree well with observations for the visible wavelengths constrained by the MFR measurements, but have larger biases and variability at longer wavelengths. Additional MFR channels at 1100 nm and/or 1600 nm would help constrain the high resolution spectral albedo in the near infrared region.

  6. Confined and interface phonons in combined cylindrical nanoheterosystem

    Directory of Open Access Journals (Sweden)

    O.M.Makhanets

    2006-01-01

    Full Text Available The spectra of all types of phonons existing in a complicated combined nanoheterosystem consisting of three cylindrical quantum dots embedded into the cylindrical quantum wire placed into vacuum are studied within the dielectric continuum model. It is shown that there are confined optical (LO and interface phonons of two types: top surface optical (TSO and side surface optical (SSO modes of vibration in such a nanosystem. The dependences of phonon energies on the quasiwave numbers and geometrical parameters of quantum dots are investigated and analysed.

  7. ThermoPhonon

    Energy Technology Data Exchange (ETDEWEB)

    2014-11-24

    ThermoPhonon is a stand-alone code, which can be integrated into other software packages. Typically, it is used together with a density functional theory (DFT) code (such as VASP, Wien2k, AbInit, SIESTA) and a phonon code (such as Phonopy or Phon). The workflow is the following. Molecular dynamics (MD) in a supercell at a given temperature T is performed using another code. After sufficient equilibration, the output in the form of atomic positions and forces for a large number of selected MD steps is recorded into a file. If needed, one can modify this file by applying additional constraints, such as enforced crystal symmetry or subtracted motion of the center of mass. ThermoPhonon reads the file with atomic positions and forces and writes a new file with the force constants. Force constants can be used by another code (such as Phonopy or Phon) to produce phonon spectrum for plotting, in the assumption of known equilibrium atomic positions provided in a separate file.

  8. Rotational Spectral Unmixing of Exoplanets: Degeneracies between Surface Colors and Geography

    Energy Technology Data Exchange (ETDEWEB)

    Fujii, Yuka [NASA Goddard Institute for Space Studies, New York, NY 10025 (United States); Lustig-Yaeger, Jacob [Astronomy Department, University of Washington, Box 951580, Seattle, WA 98195 (United States); Cowan, Nicolas B., E-mail: yuka.fujii.ebihara@gmail.com [Department of Earth and Planetary Sciences, McGill University, Montreal, Quebec, H3A 0E8 (Canada)

    2017-11-01

    Unmixing the disk-integrated spectra of exoplanets provides hints about heterogeneous surfaces that we cannot directly resolve in the foreseeable future. It is particularly important for terrestrial planets with diverse surface compositions like Earth. Although previous work on unmixing the spectra of Earth from disk-integrated multi-band light curves appeared successful, we point out a mathematical degeneracy between the surface colors and their spatial distributions. Nevertheless, useful constraints on the spectral shape of individual surface types may be obtained from the premise that albedo is everywhere between 0 and 1. We demonstrate the degeneracy and the possible constraints using both mock data based on a toy model of Earth, as well as real observations of Earth. Despite the severe degeneracy, we are still able to recover an approximate albedo spectrum for an ocean. In general, we find that surfaces are easier to identify when they cover a large fraction of the planet and when their spectra approach zero or unity in certain bands.

  9. Rotational Spectral Unmixing of Exoplanets: Degeneracies Between Surface Colors and Geography

    Science.gov (United States)

    Fujii, Yuka; Lustig-Yaeger, Jacob; Cowan, Nicolas B.

    2017-01-01

    Unmixing the disk-integrated spectra of exoplanets provides hints about heterogeneous surfaces that we cannot directly resolve in the foreseeable future. It is particularly important for terrestrial planets with diverse surface compositions like Earth. Although previous work on unmixing the spectra of Earth from disk-integrated multi-band light curves appeared successful, we point out a mathematical degeneracy between the surface colors and their spatial distributions. Nevertheless, useful constraints on the spectral shape of individual surface types may be obtained from the premise that albedo is everywhere between 0 and 1. We demonstrate the degeneracy and the possible constraints using both mock data based on a toy model of Earth, as well as real observations of Earth. Despite the severe degeneracy, we are still able to recover an approximate albedo spectrum for an ocean. In general, we find that surfaces are easier to identify when they cover a large fraction of the planet and when their spectra approach zero or unity in certain bands.

  10. Probing thermomechanics at the nanoscale: impulsively excited pseudosurface acoustic waves in hypersonic phononic crystals.

    Science.gov (United States)

    Nardi, Damiano; Travagliati, Marco; Siemens, Mark E; Li, Qing; Murnane, Margaret M; Kapteyn, Henry C; Ferrini, Gabriele; Parmigiani, Fulvio; Banfi, Francesco

    2011-10-12

    High-frequency surface acoustic waves can be generated by ultrafast laser excitation of nanoscale patterned surfaces. Here we study this phenomenon in the hypersonic frequency limit. By modeling the thermomechanics from first-principles, we calculate the system's initial heat-driven impulsive response and follow its time evolution. A scheme is introduced to quantitatively access frequencies and lifetimes of the composite system's excited eigenmodes. A spectral decomposition of the calculated response on the eigemodes of the system reveals asymmetric resonances that result from the coupling between surface and bulk acoustic modes. This finding allows evaluation of impulsively excited pseudosurface acoustic wave frequencies and lifetimes and expands our understanding of the scattering of surface waves in mesoscale metamaterials. The model is successfully benchmarked against time-resolved optical diffraction measurements performed on one-dimensional and two-dimensional surface phononic crystals, probed using light at extreme ultraviolet and near-infrared wavelengths.

  11. M3 spectral analysis of lunar swirls and the link between optical maturation and surface hydroxyl formation at magnetic anomalies

    Science.gov (United States)

    Kramer, G.Y.; Besse, S.; Dhingra, D.; Nettles, J.; Klima, R.; Garrick-Bethell, I.; Clark, Roger N.; Combe, J.-P.; Head, J. W.; Taylor, L.A.; Pieters, C.M.; Boardman, J.; McCord, T.B.

    2011-01-01

    We examined the lunar swirls using data from the Moon Mineralogy Mapper (M3). The improved spectral and spatial resolution of M3 over previous spectral imaging data facilitates distinction of subtle spectral differences, and provides new information about the nature of these enigmatic features. We characterized spectral features of the swirls, interswirl regions (dark lanes), and surrounding terrain for each of three focus regions: Reiner Gamma, Gerasimovich, and Mare Ingenii. We used Principle Component Analysis to identify spectrally distinct surfaces at each focus region, and characterize the spectral features that distinguish them. We compared spectra from small, recent impact craters with the mature soils into which they penetrated to examine differences in maturation trends on- and off-swirl. Fresh, on-swirl crater spectra are higher albedo, exhibit a wider range in albedos and have well-preserved mafic absorption features compared with fresh off-swirl craters. Albedoand mafic absorptions are still evident in undisturbed, on-swirl surface soils, suggesting the maturation process is retarded. The spectral continuum is more concave compared with off-swirl spectra; a result of the limited spectral reddening being mostly constrained to wavelengths less than ∼1500 nm. Off-swirl spectra show very little reddening or change in continuum shape across the entire M3 spectral range. Off-swirl spectra are dark, have attenuated absorption features, and the narrow range in off-swirl albedos suggests off-swirl regions mature rapidly. Spectral parameter maps depicting the relative OH surface abundance for each of our three swirl focus regions were created using the depth of the hydroxyl absorption feature at 2.82 μm. For each of the studied regions, the 2.82 μm absorption feature is significantly weaker on-swirl than off-swirl, indicating the swirls are depleted in OH relative to their surroundings. The spectral characteristics of the swirls and adjacent terrains

  12. Generation, detection and spectroscopic studies of high-frequency nonequilibrium phonons in crystals

    International Nuclear Information System (INIS)

    Dennis, W.M.; Yen, W.M.

    2007-01-01

    In this article we will review studies conducted in the past two decades on the dynamic properties of high-frequency (THz) phonons generated monochromatically with high power far infrared (FIR) laser pulses using defect-induced phonon absorption and detected using a vibronic sideband spectrometer fashioned after that devised by Kaplyanskii, the honoree of this special issue. The temporal and spectral evolution of the phonon signature provides information on the mechanisms that dominate the relaxation of high-frequency phonons in real crystals

  13. Phononic crystals fundamentals and applications

    CERN Document Server

    Adibi, Ali

    2016-01-01

    This book provides an in-depth analysis as well as an overview of phononic crystals. This book discusses numerous techniques for the analysis of phononic crystals and covers, among other material, sonic and ultrasonic structures, hypersonic planar structures and their characterization, and novel applications of phononic crystals. This is an ideal book for those working with micro and nanotechnology, MEMS (microelectromechanical systems), and acoustic devices. This book also: Presents an introduction to the fundamentals and properties of phononic crystals Covers simulation techniques for the analysis of phononic crystals Discusses sonic and ultrasonic, hypersonic and planar, and three-dimensional phononic crystal structures Illustrates how phononic crystal structures are being deployed in communication systems and sensing systems.

  14. Toward accurate prediction of potential energy surfaces and the spectral density of hydrogen bonded systems

    International Nuclear Information System (INIS)

    Rekik, Najeh

    2014-01-01

    Despite the considerable progress made in quantum theory and computational methods, detailed descriptions of the potential energy surfaces of hydrogen-bonded systems have not yet been achieved. In addition, the hydrogen bond (H-bond) itself is still so poorly understood at the fundamental level that it remains unclear exactly what geometry constitutes a “real” H-bond. Therefore, in order to investigate features essential for hydrogen bonded complexes, a simple, efficient, and general method for calculating matrix elements of vibrational operators capable of describing the stretching modes and the H-bond bridges of hydrogen-bonded systems is proposed. The derived matrix elements are simple and computationally easy to evaluate, which makes the method suitable for vibrational studies of multiple-well potentials. The method is illustrated by obtaining potential energy surfaces for a number of two-dimensional systems with repulsive potentials chosen to be in Gaussian form for the stretching mode and of the Morse-type for the H-bond bridge dynamics. The forms of potential energy surfaces of weak and strong hydrogen bonds are analyzed by varying the asymmetry of the Gaussian potential. Moreover, the choice and applicability of the selected potential for the stretching mode and comparison with other potentials used in the area of hydrogen bond research are discussed. The approach for the determination of spectral density has been constructed in the framework of the linear response theory for which spectral density is obtained by Fourier transform of the autocorrelation function of the dipole moment operator of the fast mode. The approach involves anharmonic coupling between the high frequency stretching vibration (double well potential) and low-frequency donor-acceptor stretching mode (Morse potential) as well as the electrical anharmonicity of the dipole moment operator of the fast mode. A direct relaxation mechanism is incorporated through a time decaying exponential

  15. Phononic fluidics: acoustically activated droplet manipulations

    Science.gov (United States)

    Reboud, Julien; Wilson, Rab; Bourquin, Yannyk; Zhang, Yi; Neale, Steven L.; Cooper, Jonathan M.

    2011-02-01

    Microfluidic systems have faced challenges in handling real samples and the chip interconnection to other instruments. Here we present a simple interface, where surface acoustic waves (SAWs) from a piezoelectric device are coupled into a disposable acoustically responsive microfluidic chip. By manipulating droplets, SAW technologies have already shown their potential in microfluidics, but it has been limited by the need to rely upon mixed signal generation at multiple interdigitated electrode transducers (IDTs) and the problematic resulting reflections, to allow complex fluid operations. Here, a silicon chip was patterned with phononic structures, engineering the acoustic field by using a full band-gap. It was simply coupled to a piezoelectric LiNbO3 wafer, propagating the SAW, via a thin film of water. Contrary to the use of unstructured superstrates, phononic metamaterials allowed precise spatial control of the acoustic energy and hence its interaction with the liquids placed on the surface of the chip, as demonstrated by simulations. We further show that the acoustic frequency influences the interaction between the SAW and the phononic lattice, providing a route to programme complex fluidic manipulation onto the disposable chip. The centrifugation of cells from a blood sample is presented as a more practical demonstration of the potential of phononic crystals to realize diagnostic systems.

  16. The role of the roughness spectral breadth in elastic contact of rough surfaces

    Science.gov (United States)

    Yastrebov, Vladislav A.; Anciaux, Guillaume; Molinari, Jean-François

    2017-10-01

    We study frictionless and non-adhesive contact between elastic half-spaces with self-affine surfaces. Using a recently suggested corrective technique, we ensure an unprecedented accuracy in computation of the true contact area evolution under increasing pressure. This accuracy enables us to draw conclusions on the role of the surface's spectrum breadth (Nayak parameter) in the contact area evolution. We show that for a given normalized pressure, the contact area decreases logarithmically with the Nayak parameter. By linking the Nayak parameter with the Hurst exponent (or fractal dimension), we show the effect of the latter on the true contact area. This effect, undetectable for surfaces with poor spectral content, is quite strong for surfaces with rich spectra. Numerical results are compared with analytical models and other available numerical results. A phenomenological equation for the contact area growth is suggested with coefficients depending on the Nayak parameter. Using this equation, the pressure-dependent friction coefficient is deduced based on the adhesive theory of friction. Some observations on Persson's model of rough contact, whose prediction does not depend on Nayak parameter, are reported. Overall, the paper provides a unifying picture of rough elastic contact and clarifies discrepancies between preceding results.

  17. Widespread distribution of OH/H2O on the lunar surface inferred from spectral data

    Science.gov (United States)

    Bandfield, Joshua L.; Poston, Michael J.; Klima, Rachel L.; Edwards, Christopher S.

    2018-02-01

    Remote-sensing data from lunar orbiters have revealed spectral features consistent with the presence of OH or H2O on the lunar surface. Analyses of data from the Moon Mineralogy Mapper spectrometer onboard the Chandrayaan-1 spacecraft have suggested that OH/H2O is recycled on diurnal timescales and persists only at high latitudes. However, the spatial distribution and temporal variability of the OH/H2O, as well as its source, remain uncertain. Here we incorporate a physics-based thermal correction into analysis of reflectance spectra from the Moon Mineralogy Mapper and find that prominent absorption features consistent with OH/H2O can be present at all latitudes, local times and surface types examined. This suggests the widespread presence of OH/H2O on the lunar surface without significant diurnal migration. We suggest that the spectra are consistent with the production of OH in space-weathered materials by the solar wind implantation of H+ and formation of OH at crystal defect sites, as opposed to H2O sourced from the lunar interior. Regardless of the specific composition or formation mechanism, we conclude that OH/H2O can be present on the Moon under thermal conditions more wide-ranging than previously recognized.

  18. Phonon dispersion in Be

    International Nuclear Information System (INIS)

    Sharma, R.P.; Sharma, A.K.; Sharma, S.; Sinha, H.P.

    1979-01-01

    In a study of the lattice dynamics of Be a simple scheme has been developed in which the pairwise and long range forces are accounted on the lines of nonlocal theory and the short range three-body forces are included. This procedure of calculations has been applied to compute the phonon dispersion in Be and the results of investigation have been compared with the experimental data. (author)

  19. Comparisons Between Model Predictions and Spectral Measurements of Charged and Neutral Particles on the Martian Surface

    Science.gov (United States)

    Kim, Myung-Hee Y.; Cucinotta, Francis A.; Zeitlin, Cary; Hassler, Donald M.; Ehresmann, Bent; Rafkin, Scot C. R.; Wimmer-Schweingruber, Robert F.; Boettcher, Stephan; Boehm, Eckart; Guo, Jingnan; hide

    2014-01-01

    Detailed measurements of the energetic particle radiation environment on the surface of Mars have been made by the Radiation Assessment Detector (RAD) on the Curiosity rover since August 2012. RAD is a particle detector that measures the energy spectrum of charged particles (10 to approx. 200 MeV/u) and high energy neutrons (approx 8 to 200 MeV). The data obtained on the surface of Mars for 300 sols are compared to the simulation results using the Badhwar-O'Neill galactic cosmic ray (GCR) environment model and the high-charge and energy transport (HZETRN) code. For the nuclear interactions of primary GCR through Mars atmosphere and Curiosity rover, the quantum multiple scattering theory of nuclear fragmentation (QMSFRG) is used. For describing the daily column depth of atmosphere, daily atmospheric pressure measurements at Gale Crater by the MSL Rover Environmental Monitoring Station (REMS) are implemented into transport calculations. Particle flux at RAD after traversing varying depths of atmosphere depends on the slant angles, and the model accounts for shielding of the RAD "E" dosimetry detector by the rest of the instrument. Detailed comparisons between model predictions and spectral data of various particle types provide the validation of radiation transport models, and suggest that future radiation environments on Mars can be predicted accurately. These contributions lend support to the understanding of radiation health risks to astronauts for the planning of various mission scenarios

  20. Comparison of TOMS retrievals and UVMRP measurements of surface spectral UV radiation in the United States

    Directory of Open Access Journals (Sweden)

    M. Xu

    2010-09-01

    Full Text Available Surface noontime spectral ultraviolet (UV irradiances during May-September of 2000–2004 from the total ozone mapping spectrometer (TOMS satellite retrievals are systematically compared with the ground measurements at 27 climatological sites maintained by the USDA UV-B Monitoring and Research Program. The TOMS retrievals are evaluated by two cloud screening methods and local air quality conditions to determine their bias dependencies on spectral bands, cloudiness, aerosol loadings, and air pollution. Under clear-sky conditions, TOMS retrieval biases vary from −3.4% (underestimation to 23.6% (overestimation. Averaged over all sites, the relative mean biases for 305, 311, 325, and 368 nm are respectively 15.4, 7.9, 7.6, and 7.0% (overestimation. The bias enhancement for 305 nm by approximately twice that of other bands likely results from absorption by gaseous pollutants (SO2, O3, and aerosols that are not included in the TOMS algorithm. For all bands, strong positive correlations of the TOMS biases are identified with aerosol optical depth, which explains nearly 50% of the variances of TOMS biases. The more restrictive in-situ cloud screening method reduces the biases by 3.4–3.9% averaged over all sites. This suggests that the TOMS biases from the in-situ cloud contamination may account for approximately 25% for 305 nm and 50% for other bands of the total bias. The correlation coefficients between total-sky and clear-sky biases across 27 sites are 0.92, 0.89, 0.83, and 0.78 for 305, 311, 325, and 368 nm, respectively. The results show that the spatial characteristics of the TOMS retrieval biases are systematic, representative of both clear and total-sky conditions.

  1. The impact of grid and spectral nudging on the variance of the near-surface wind speed

    DEFF Research Database (Denmark)

    Vincent, Claire Louise; Hahmann, Andrea N.

    2015-01-01

    nudging at and above 1150 m above ground level (AGL). Nested 5 km simulations are not nudged directly, but inherit boundary conditions from the 15 km experiments. Spatial and temporal spectra show that grid nudging causes smoothing of the wind in the 15 km domain at all wavenumbers, both at 1150 m AGL...... and near the surface where nudging is not applied directly, while spectral nudging mainly affects longer wavenumbers. Maps of mesoscale variance show spatial smoothing for both grid and spectral nudging, although the effect is less pronounced for spectral nudging. On the inner, 5 km domain, an indirect...... smoothing impact of nudging is seen up to 200 km inward from the dominant in flow boundary at 1150 m AGL, but there is minimal smoothing from the nudging near the surface, indicating that nudging an outer domain is an appropriate configuration for wind resource modelling....

  2. Derivation of the canopy conductance from surface temperature and spectral indices for estimating evapotranspiration in semiarid vegetation

    International Nuclear Information System (INIS)

    Morillas, L.; Garcia, M.; Zarco-Tejada, P.; Ladron de Guevara, M.; Villagarcia, L.; Were, A.; Domingo, F.

    2009-01-01

    This work evaluates the possibilities for estimating stomata conductance (C) and leaf transpiration (Trf) at the ecosystem scale from radiometric indices and surface temperature. The relationships found between indices and the transpiration component of the water balance in a semiarid tussock ecosystem in SE Spain are discussed. Field data were collected from spring 2008 until winter 2009 in order to observe the annual variability of the relationships and the behaviour of spectral indices and surface temperature. (Author) 11 refs.

  3. Phonon-induced optical superlattice.

    Science.gov (United States)

    de Lima, M M; Hey, R; Santos, P V; Cantarero, A

    2005-04-01

    We demonstrate the formation of a dynamic optical superlattice through the modulation of a semiconductor microcavity by stimulated acoustic phonons. The high coherent phonon population produces a folded optical dispersion relation with well-defined energy gaps and renormalized energy levels, which are accessed using reflection and diffraction experiments.

  4. Electrical switch to the resonant magneto-phonon effect in graphene.

    Science.gov (United States)

    Leszczynski, Przemyslaw; Han, Zheng; Nicolet, Aurelien A L; Piot, Benjamin A; Kossacki, Piotr; Orlita, Milan; Bouchiat, Vincent; Basko, Denis M; Potemski, Marek; Faugeras, Clement

    2014-03-12

    We report a comprehensive study of the tuning with electric fields of the resonant magneto-exciton optical phonon coupling in gated graphene. For magnetic fields around B ∼ 25 T that correspond to the range of the fundamental magneto-phonon resonance, the electron-phonon coupling can be switched on and off by tuning the position of the Fermi level in order to Pauli block the two fundamental inter-Landau level excitations. The effects of such a profound change in the electronic excitation spectrum are traced through investigations of the optical phonon response in polarization resolved magneto-Raman scattering experiments. We report on the observation of a splitting of the phonon feature with satellite peaks developing at particular values of the Landau level filling factor on the low or on the high energy side of the phonon, depending on the relative energy of the discrete electronic excitation and of the optical phonon. Shifts of the phonon energy as large as ±60 cm(-1) are observed close to the resonance. The intraband electronic excitation, the cyclotron resonance, is shown to play a relevant role in the observed spectral evolution of the phonon response.

  5. The directional propagation characteristics of elastic wave in two-dimensional thin plate phononic crystals

    International Nuclear Information System (INIS)

    Wen Jihong; Yu, Dianlong; Wang Gang; Zhao Honggang; Liu Yaozong; Wen Xisen

    2007-01-01

    The directional propagation characteristics of elastic wave during pass bands in two-dimensional thin plate phononic crystals are analyzed by using the lumped-mass method to yield the phase constant surface. The directions and regions of wave propagation in phononic crystals for certain frequencies during pass bands are predicted with the iso-frequency contour lines of the phase constant surface, which are then validated with the harmonic responses of a finite two-dimensional thin plate phononic crystals with 16x16 unit cells. These results are useful for controlling the wave propagation in the pass bands of phononic crystals

  6. Weyl points and Fermi arcs in a chiral phononic crystal

    Science.gov (United States)

    Li, Feng; Huang, Xueqin; Lu, Jiuyang; Ma, Jiahong; Liu, Zhengyou

    2018-01-01

    Topological semimetals are materials whose band structure contains touching points that are topologically nontrivial and can host quasiparticle excitations that behave as Dirac or Weyl fermions. These so-called Weyl points not only exist in electronic systems, but can also be found in artificial periodic structures with classical waves, such as electromagnetic waves in photonic crystals and acoustic waves in phononic crystals. Due to the lack of spin and a difficulty in breaking time-reversal symmetry for sound, however, topological acoustic materials cannot be achieved in the same way as electronic or optical systems. And despite many theoretical predictions, experimentally realizing Weyl points in phononic crystals remains challenging. Here, we experimentally realize Weyl points in a chiral phononic crystal system, and demonstrate surface states associated with the Weyl points that are topological in nature, and can host modes that propagate only in one direction. As with their photonic counterparts, chiral phononic crystals bring topological physics to the macroscopic scale.

  7. Tunable Topological Phononic Crystals

    KAUST Repository

    Chen, Zeguo

    2016-05-27

    Topological insulators first observed in electronic systems have inspired many analogues in photonic and phononic crystals in which remarkable one-way propagation edge states are supported by topologically nontrivial band gaps. Such band gaps can be achieved by breaking the time-reversal symmetry to lift the degeneracy associated with Dirac cones at the corners of the Brillouin zone. Here, we report on our construction of a phononic crystal exhibiting a Dirac-like cone in the Brillouin zone center. We demonstrate that simultaneously breaking the time-reversal symmetry and altering the geometric size of the unit cell result in a topological transition that we verify by the Chern number calculation and edge-mode analysis. We develop a complete model based on the tight binding to uncover the physical mechanisms of the topological transition. Both the model and numerical simulations show that the topology of the band gap is tunable by varying both the velocity field and the geometric size; such tunability may dramatically enrich the design and use of acoustic topological insulators.

  8. Quasiparticle-phonon nuclear model

    International Nuclear Information System (INIS)

    Soloviev, V.G.

    1977-01-01

    The general assumptions of the quasiparticle-phonon model of complex nuclei are given. The choice of the model hamiltonian as an average field and residual forces is discussed. The phonon description and quasiparticle-phonon interaction are presented. The system of basic equations and their approximate solutions are obtained. The approximation is chosen so as to obtain the most correct description of few-quasiparticle components rather than of the whole wave function. The method of strenght functions is presented, which plays a decisive role in practical realization of the quasiparticle-phonon model for the description of some properties of complex nuclei. The range of applicability of the quasiparticle-phonon nuclear model is determined as few-quasiparticle components of the wave functions at low, intermediate and high excitation energies averaged in a certain energy interval

  9. Phonon Transport in Semiconductor interface: An atomistic approach

    Science.gov (United States)

    Chalopin, Yann

    2010-03-01

    Thermal dissipation and thermal insulation are among crucial issues encountered in high speed electronics devices and thermoelectrics systems. Both applications rely on controlling the transport properties of the heat carriers at semiconductor interfaces. From microscopic perspective, it is of fundamental interest to understand how the transport of phonons is impacted by an interface formed by two semiconductor layers. In a typical junction, the mechanism of reflection/transmission of vibrational energy causes strong modifications in the conductance regime. Thus, it is important to address the thermal transport at a contact junction in the framework of phonon wave propagation. Our approach is based on the fluctuation/dissipation theorem in order to calculate the thermal conductance of an interface. Using molecular dynamics simulations, we address the problems associated to using Si/Ge Si/SiGe junctions. We propose a methodology that enables the recovery of the transmission of the phonon modes by correlating the atomic motions of the phonon modes. Furthermore, we conclude that the phonon transmission function can be reconstructed such that it is integrated in the spectral expression of the conductance.

  10. Spectral reflectance characteristics of different snow and snow-covered land surface objects and mixed spectrum fitting

    Science.gov (United States)

    Zhang, J.-H.; Zhou, Z.-M.; Wang, P.-J.; Yao, F.-M.; Yang, L.

    2011-01-01

    The field spectroradiometer was used to measure spectra of different snow and snow-covered land surface objects in Beijing area. The result showed that for a pure snow spectrum, the snow reflectance peaks appeared from visible to 800 nm band locations; there was an obvious absorption valley of snow spectrum near 1030 nm wavelength. Compared with fresh snow, the reflection peaks of the old snow and melting snow showed different degrees of decline in the ranges of 300~1300, 1700~1800 and 2200~2300 nm, the lowest was from the compacted snow and frozen ice. For the vegetation and snow mixed spectral characteristics, it was indicated that the spectral reflectance increased for the snow-covered land types(including pine leaf with snow and pine leaf on snow background), due to the influence of snow background in the range of 350~1300 nm. However, the spectrum reflectance of mixed pixel remained a vegetation spectral characteristic. In the end, based on the spectrum analysis of snow, vegetation, and mixed snow/vegetation pixels, the mixed spectral fitting equations were established, and the results showed that there was good correlation between spectral curves by simulation fitting and observed ones(correlation coefficient R2=0.9509).

  11. The Ultimate Pile Bearing Capacity from Conventional and Spectral Analysis of Surface Wave (SASW) Measurements

    Science.gov (United States)

    Faizah Bawadi, Nor; Anuar, Shamilah; Rahim, Mustaqqim A.; Mansor, A. Faizal

    2018-03-01

    A conventional and seismic method for determining the ultimate pile bearing capacity was proposed and compared. The Spectral Analysis of Surface Wave (SASW) method is one of the non-destructive seismic techniques that do not require drilling and sampling of soils, was used in the determination of shear wave velocity (Vs) and damping (D) profile of soil. The soil strength was found to be directly proportional to the Vs and its value has been successfully applied to obtain shallow bearing capacity empirically. A method is proposed in this study to determine the pile bearing capacity using Vs and D measurements for the design of pile and also as an alternative method to verify the bearing capacity from the other conventional methods of evaluation. The objectives of this study are to determine Vs and D profile through frequency response data from SASW measurements and to compare pile bearing capacities obtained from the method carried out and conventional methods. All SASW test arrays were conducted near the borehole and location of conventional pile load tests. In obtaining skin and end bearing pile resistance, the Hardin and Drnevich equation has been used with reference strains obtained from the method proposed by Abbiss. Back analysis results of pile bearing capacities from SASW were found to be 18981 kN and 4947 kN compared to 18014 kN and 4633 kN of IPLT with differences of 5% and 6% for Damansara and Kuala Lumpur test sites, respectively. The results of this study indicate that the seismic method proposed in this study has the potential to be used in estimating the pile bearing capacity.

  12. The A1g mode in the Hg-1201 phonon spectrum as an indicator of N→S transition

    International Nuclear Information System (INIS)

    Dovgij, Ya.

    2011-01-01

    By analyzing the structure of and the temperature changes in HgBa 2 CuO 4+y phonon spectra, the electron-phonon coupling constant g has been determined for the first time. It is shown that this compound is a superconductor with strong coupling. A frequency interval around 60.4 MeV in the HgBa 2 CuO 4+y phonon spectrum, which may be classed as a 'soft mode', is revealed. The dominant partial contribution to the density of phonon states in that spectral range is found to be given by O(2) atomic vibrations.

  13. Phonon anomalies in trilayer high-Tc cuprate superconductors

    International Nuclear Information System (INIS)

    Dubroka, Adam; Munzar, Dominik

    2004-01-01

    We present an extension of the model proposed recently to account for dramatic chAes below T c (anomalies) of some c-axis polarized infrared-active phonons in bilayer cuprate superconductors, that applies to trilayer high-T c compounds. We discuss several types of phonon anomalies that can occur in these systems and demonstrate that our model is capable of explaining the spectral chAes occurring upon entering the superconducting state in the trilayer compound Tl 2 Ba 2 Ca 2 Cu 3 O 10 . The low-temperature spectra of this compound obtained by Zetterer and coworkers display an additional broad absorption band, similar to the one observed in underdoped YBa 2 Cu 3 O 7-δ and Bi 2 Sr 2 CaCu 2 O 8 . In addition, three phonon modes are strongly anomalous. We attribute the absorption band to the transverse Josephson plasma resonance, similar to that of the bilayer compounds. The phonon anomalies are shown to result from a modification of the local fields induced by the formation of the resonance. The spectral chAes in Tl 2 Ba 2 Ca 2 Cu 3 O 10 are compared with those occurring in Bi 2 Sr 2 Ca 2 Cu 3 O 10 , reported recently by Boris and coworkers

  14. Classification of topological phonons in linear mechanical metamaterials.

    Science.gov (United States)

    Süsstrunk, Roman; Huber, Sebastian D

    2016-08-16

    Topological phononic crystals, alike their electronic counterparts, are characterized by a bulk-edge correspondence where the interior of a material dictates the existence of stable surface or boundary modes. In the mechanical setup, such surface modes can be used for various applications such as wave guiding, vibration isolation, or the design of static properties such as stable floppy modes where parts of a system move freely. Here, we provide a classification scheme of topological phonons based on local symmetries. We import and adapt the classification of noninteracting electron systems and embed it into the mechanical setup. Moreover, we provide an extensive set of examples that illustrate our scheme and can be used to generate models in unexplored symmetry classes. Our work unifies the vast recent literature on topological phonons and paves the way to future applications of topological surface modes in mechanical metamaterials.

  15. Classification of topological phonons in linear mechanical metamaterials

    Science.gov (United States)

    Süsstrunk, Roman

    2016-01-01

    Topological phononic crystals, alike their electronic counterparts, are characterized by a bulk–edge correspondence where the interior of a material dictates the existence of stable surface or boundary modes. In the mechanical setup, such surface modes can be used for various applications such as wave guiding, vibration isolation, or the design of static properties such as stable floppy modes where parts of a system move freely. Here, we provide a classification scheme of topological phonons based on local symmetries. We import and adapt the classification of noninteracting electron systems and embed it into the mechanical setup. Moreover, we provide an extensive set of examples that illustrate our scheme and can be used to generate models in unexplored symmetry classes. Our work unifies the vast recent literature on topological phonons and paves the way to future applications of topological surface modes in mechanical metamaterials. PMID:27482105

  16. Phonons: Theory and experiments II. Volume 2

    International Nuclear Information System (INIS)

    Bruesch, P.

    1986-01-01

    The present second volume titled as ''Phonons: Theory and Experiments II'', contains, a thorough study of experimental techniques and the interpretation of experimental results. This three-volume set tries to bridge the gap between theory and experiment, and is addressed to those working in both camps in the vast field of dynamical properties of solids. Topics presented in the second volume include; infrared-, Raman and Brillouin spectroscopy, interaction of X-rays with phonons, and inelastic neutron scattering. In addition an account is given of some other techniques, including ultrasonic methods, inelastic electron tunneling spectroscopy, point contact spectroscopy, and spectroscopy of surface phonons, thin films and adsorbates. Both experimental aspects and theoretical concepts necessary for the interpretation of experimental data are discussed. An attempt is made to present the descriptive as well as the analytical aspects of the topics. Simple models are often used to illustrate the basic concepts and more than 100 figures are included to illustrate both theoretical and experimental results. Many chapters contain a number of problems with hints and results giving additional information

  17. Automated mapping of impervious surfaces in urban and suburban areas: Linear spectral unmixing of high spatial resolution imagery

    Science.gov (United States)

    Yang, Jian; He, Yuhong

    2017-02-01

    Quantifying impervious surfaces in urban and suburban areas is a key step toward a sustainable urban planning and management strategy. With the availability of fine-scale remote sensing imagery, automated mapping of impervious surfaces has attracted growing attention. However, the vast majority of existing studies have selected pixel-based and object-based methods for impervious surface mapping, with few adopting sub-pixel analysis of high spatial resolution imagery. This research makes use of a vegetation-bright impervious-dark impervious linear spectral mixture model to characterize urban and suburban surface components. A WorldView-3 image acquired on May 9th, 2015 is analyzed for its potential in automated unmixing of meaningful surface materials for two urban subsets and one suburban subset in Toronto, ON, Canada. Given the wide distribution of shadows in urban areas, the linear spectral unmixing is implemented in non-shadowed and shadowed areas separately for the two urban subsets. The results indicate that the accuracy of impervious surface mapping in suburban areas reaches up to 86.99%, much higher than the accuracies in urban areas (80.03% and 79.67%). Despite its merits in mapping accuracy and automation, the application of our proposed vegetation-bright impervious-dark impervious model to map impervious surfaces is limited due to the absence of soil component. To further extend the operational transferability of our proposed method, especially for the areas where plenty of bare soils exist during urbanization or reclamation, it is still of great necessity to mask out bare soils by automated classification prior to the implementation of linear spectral unmixing.

  18. Computational studies of first-Born scattering cross sections. I - Spectral properties of Bethe surfaces. II - Moment-theory approach

    Science.gov (United States)

    Margoliash, D. J.; Langhoff, P. W.

    1983-01-01

    The present investigation is concerned with the spectral properties of Bethe surfaces to establish a basis for the formulation of alternatives to the conventional computational approach. The relevant scattering cross sections and closely related Van Hove autocorrelation functions are identified as spectral (Riemann-Stieltjes) integral properties of the corresponding atomic and molecular Bethe surfaces. Evaluation of these properties for hydrogenic targets provides a basis for clarifying the ranges of validity of the static, binary-encounter, and sum-rule approximations to differential and total inelastic cross sections generally employed in place of the correct Born results. A description is provided of moment-theory methods for calculations of the high-energy electron impact-excitation and -ionization cross sections and closely related Van Hove correlation functions of atomic and molecular targets. Attention is given to aspects of the Chebyshev-Stieltjes-Markoff moment theory and the Stieltjes and Chebyshev derivatives.

  19. Elastic LO-phonon scattering as an efficient mechanism of dephasing and homogeneous broadening in quantum dots

    DEFF Research Database (Denmark)

    Uskov, Alexander V.; Tromborg, Bjarne; Jauho, Antti-Pekka

    2000-01-01

    The spectral linewidth of optical transitions in quantum dots is shown to be strongly broadened by elastic scattering of LO phonons on the confined carriers. The scattering does not excite the carriers but results in a large dephasing rate.......The spectral linewidth of optical transitions in quantum dots is shown to be strongly broadened by elastic scattering of LO phonons on the confined carriers. The scattering does not excite the carriers but results in a large dephasing rate....

  20. Effect of Spectrally Varying Albedo of Vegetation Surfaces on Shortwave Radiation Fluxes and Aerosol Direct Radiative Forcing

    Science.gov (United States)

    Zhu, L.; Martins, J. V.; Yu, H.

    2012-01-01

    This study develops an algorithm for representing detailed spectral features of vegetation albedo based on Moderate Resolution Imaging Spectrometer (MODIS) observations at 7 discrete channels, referred to as the MODIS Enhanced Vegetation Albedo (MEVA) algorithm. The MEVA algorithm empirically fills spectral gaps around the vegetation red edge near 0.7 micrometers and vegetation water absorption features at 1.48 and 1.92 micrometers which cannot be adequately captured by the MODIS 7 channels. We then assess the effects of applying MEVA in comparison to four other traditional approaches to calculate solar fluxes and aerosol direct radiative forcing (DRF) at the top of atmosphere (TOA) based on the MODIS discrete reflectance bands. By comparing the DRF results obtained through the MEVA method with the results obtained through the other four traditional approaches, we show that filling the spectral gap of the MODIS measurements around 0.7 micrometers based on the general spectral behavior of healthy green vegetation leads to significant improvement in the instantaneous aerosol DRF at TOA (up to 3.02Wm(exp -2) difference or 48% fraction of the aerosol DRF, .6.28Wm(exp -2), calculated for high spectral resolution surface reflectance from 0.3 to 2.5 micrometers for deciduous vegetation surface). The corrections of the spectral gaps in the vegetation spectrum in the near infrared, again missed by the MODIS reflectances, also contributes to improving TOA DRF calculations but to a much lower extent (less than 0.27Wm(exp -2), or about 4% of the instantaneous DRF). Compared to traditional approaches, MEVA also improves the accuracy of the outgoing solar flux between 0.3 to 2.5 micrometers at TOA by over 60Wm(exp -2) (for aspen 3 surface) and aerosol DRF by over 10Wm(exp -2) (for dry grass). Specifically, for Amazon vegetation types, MEVA can improve the accuracy of daily averaged aerosol radiative forcing in the spectral range of 0.3 to 2.5 micrometers at equator at the

  1. Generation of coherent optical phonons in ZnO using femtosecond lasers

    Energy Technology Data Exchange (ETDEWEB)

    Lim, Y. S. [Dept. of Applied Physics, Konkuk University, Chungju (Korea, Republic of); Lee, I. H.; Yee, K. J.; Lee, K. G.; Oh, E.; Kim, D. S. [School of Physics, Seoul National University, Seoul (Korea, Republic of)

    2002-07-01

    We report on coherent optical phonon oscillations in wuzite ZnO. The high- and low-frequency E{sub 2} modes are excited by the impulsive stimulated Raman scattering (ISRS), and detected through the electric sampling. The dephasing times at room temperature are measured to be 1.75 ps, 29.2 ps for high- and low-E{sub 2} mode, respectively. The relation of the coherent phonon amplitude with the spectral wide of femtosecond pump pulse is demonstrated.

  2. Reduction of thermal conductivity in phononic nanomesh structures

    KAUST Repository

    Yu, Jen-Kan

    2010-07-25

    Controlling the thermal conductivity of a material independently of its electrical conductivity continues to be a goal for researchers working on thermoelectric materials for use in energy applications1,2 and in the cooling of integrated circuits3. In principle, the thermal conductivity κ and the electrical conductivity σ may be independently optimized in semiconducting nanostructures because different length scales are associated with phonons (which carry heat) and electric charges (which carry current). Phonons are scattered at surfaces and interfaces, so κ generally decreases as the surface-to-volume ratio increases. In contrast, σ is less sensitive to a decrease in nanostructure size, although at sufficiently small sizes it will degrade through the scattering of charge carriers at interfaces. Here, we demonstrate an approach to independently controlling κ based on altering the phonon band structure of a semiconductor thin film through the formation of a phononic nanomesh film. These films are patterned with periodic spacings that are comparable to, or shorter than, the phonon mean free path. The nanomesh structure exhibits a substantially lower thermal conductivity than an equivalently prepared array of silicon nanowires, even though this array has a significantly higher surface-to-volume ratio. Bulk-like electrical conductivity is preserved. We suggest that this development is a step towards a coherent mechanism for lowering thermal conductivity. © 2010 Macmillan Publishers Limited. All rights reserved.

  3. Probing phonons in plutonium

    International Nuclear Information System (INIS)

    Wong, Joe; Krisch, M.; Farber, D.; Occelli, F.; Schwartz, A.; Chiang, T.C.; Wall, M.; Boro, C.; Xu, Ruqing

    2010-01-01

    Plutonium (Pu) is well known to have complex and unique physico-chemical properties. Notably, the pure metal exhibits six solid-state phase transformations with large volume expansions and contractions along the way to the liquid state: α → β → γ → (delta) → (delta)(prime) → (var e psilon) → liquid. Unalloyed Pu melts at a relatively low temperature ∼640 C to yield a higher density liquid than that of the solid from which it melts, (Figure 1). Detailed understanding of the properties of plutonium and plutonium-based alloys is critical for the safe handling, utilization, and long-term storage of these important, but highly toxic materials. However, both technical and and safety issues have made experimental observations extremely difficult. Phonon dispersion curves (PDCs) are key experimenta l data to the understanding of the basic properties of Pu materials such as: force constants, sound velocities, elastic constants, thermodynamics, phase stability, electron-phonon coupling, structural relaxation, etc. However, phonon dispersion curves (PDCs) in plutonium (Pu) and its alloys have defied measurement for the past few decades since the discovery of this element in 1941. This is due to a combination of the high thermal-neutron absorption cross section of plutonium and the inability to grow the large single crystals (with dimensions of a few millimeters) necessary for inelastic neutron scattering. Theoretical simulations of the Pu PDC continue to be hampered by the lack of suitable inter -atomic potentials. Thus, until recently the PDCs for Pu and its alloys have remained unknown experimentally and theoretically. The experimental limitations have recently been overcome by using a tightly focused undulator x-ray micro-beam scattered from single -grain domains in polycrystalline specimens. This experimental approach has been applied successfully to map the complete PDCs of an fcc d-Pu-Ga alloy using the high resolution inelastic x-ray scattering (HRIXS

  4. Probing phonons in plutonium

    Energy Technology Data Exchange (ETDEWEB)

    Wong, Joe; Krisch, M.; Farber, D.; Occelli, F.; Schwartz, A.; Chiang, T.C.; Wall, M.; Boro, C.; Xu, Ruqing (UIUC); (LLNL); (ESRF); (LANL)

    2010-11-16

    Plutonium (Pu) is well known to have complex and unique physico-chemical properties. Notably, the pure metal exhibits six solid-state phase transformations with large volume expansions and contractions along the way to the liquid state: {alpha} {yields} {beta} {yields} {gamma} {yields} {delta} {yields} {delta}{prime} {yields} {var_epsilon} {yields} liquid. Unalloyed Pu melts at a relatively low temperature {approx}640 C to yield a higher density liquid than that of the solid from which it melts, (Figure 1). Detailed understanding of the properties of plutonium and plutonium-based alloys is critical for the safe handling, utilization, and long-term storage of these important, but highly toxic materials. However, both technical and and safety issues have made experimental observations extremely difficult. Phonon dispersion curves (PDCs) are key experimenta l data to the understanding of the basic properties of Pu materials such as: force constants, sound velocities, elastic constants, thermodynamics, phase stability, electron-phonon coupling, structural relaxation, etc. However, phonon dispersion curves (PDCs) in plutonium (Pu) and its alloys have defied measurement for the past few decades since the discovery of this element in 1941. This is due to a combination of the high thermal-neutron absorption cross section of plutonium and the inability to grow the large single crystals (with dimensions of a few millimeters) necessary for inelastic neutron scattering. Theoretical simulations of the Pu PDC continue to be hampered by the lack of suitable inter -atomic potentials. Thus, until recently the PDCs for Pu and its alloys have remained unknown experimentally and theoretically. The experimental limitations have recently been overcome by using a tightly focused undulator x-ray micro-beam scattered from single -grain domains in polycrystalline specimens. This experimental approach has been applied successfully to map the complete PDCs of an fcc d-Pu-Ga alloy using the

  5. Phonons with orbital angular momentum

    International Nuclear Information System (INIS)

    Ayub, M. K.; Ali, S.; Mendonca, J. T.

    2011-01-01

    Ion accoustic waves or phonon modes are studied with orbital angular momentum (OAM) in an unmagnetized collissionless uniform plasma, whose constituents are the Boltzmann electrons and inertial ions. For this purpose, we have employed the fluid equations to obtain a paraxial equation in terms of ion density perturbations and discussed its Gaussian beam and Laguerre-Gauss (LG) beam solutions. Furthermore, an approximate solution for the electrostatic potential problem is presented, allowing to express the components of the electric field in terms of LG potential perturbations. The energy flux due to phonons is also calculated and the corresponding OAM is derived. Numerically, it is shown that the parameters such as azimuthal angle, radial and angular mode numbers, and beam waist, strongly modify the profiles of the phonon LG potential. The present results should be helpful in understanding the phonon mode excitations produced by Brillouin backscattering of laser beams in a uniform plasma.

  6. Local Environment and Interactions of Liquid and Solid Interfaces Revealed by Spectral Line Shape of Surface Selective Nonlinear Vibrational Probe

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Shun-Li; Fu, Li; Chase, Zizwe A.; Gan, Wei; Wang, Hong-Fei

    2016-11-10

    Vibrational spectral lineshape contains important detailed information of molecular vibration and reports its specific interactions and couplings to its local environment. In this work, recently developed sub-1 cm-1 high-resolution broadband sum frequency generation vibrational spectroscopy (HR-BB-SFG-VS) was used to measure the -C≡N stretch vibration in the 4-n-octyl-4’-cyanobiphenyl (8CB) Langmuir or Langmuir-Blodgett (LB) monolayer as a unique vibrational probe, and the spectral lineshape analysis revealed the local environment and interactions at the air/water, air/glass, air/calcium fluoride and air/-quartz interfaces for the first time. The 8CB Langmuir or LB film is uniform and the vibrational spectral lineshape of its -C≡N group has been well characterized, making it a good choice as the surface vibrational probe. Lineshape analysis of the 8CB -C≡N stretch SFG vibrational spectra suggests the coherent vibrational dynamics and the structural and dynamic inhomogeneity of the -C≡N group at each interface are uniquely different. In addition, it is also found that there are significantly different roles for water molecules in the LB films on different substrate surfaces. These results demonstrated the novel capabilities of the surface nonlinear spectroscopy in characterization and in understanding the specific structures and chemical interactions at the liquid and solid interfaces in general.

  7. Spectral Feature Analysis of Minerals and Planetary Surfaces in an Introductory Planetary Science Course

    Science.gov (United States)

    Urban, Michael J.

    2013-01-01

    Using an ALTA II reflectance spectrometer, the USGS digital spectral library, graphs of planetary spectra, and a few mineral hand samples, one can teach how light can be used to study planets and moons. The author created the hands-on, inquiry-based activity for an undergraduate planetary science course consisting of freshman to senior level…

  8. Initial analyses of surface spectral radiance between observations and Line-By-Line calculations

    Energy Technology Data Exchange (ETDEWEB)

    Brown, P.D.; Clough, S.A. [Atmospheric and Environmental Research, Inc., Cambridge, MA (United States); Miller, N.E.; Shippert, T.R.; Turner, D.D. [Pacific Northwest Lab., Richland, WA (United States)] [and others

    1996-04-01

    The evaluation an improvement of radiative transfer calculations are essential to attain improved performance of general circulation models (GCMs) for climate change applications. A Quality Measurement Experiment (QME) is being conducted to analyze the spectral residuals between the downwelling longwave radiance measured by the University of Wisconsin Atmospheric Emitted Radiance Interferometer (AERI) and spectral radiance calculated by the Line-By-Line Radiative Transfer Model (LBLRTM). The three critical components of this study are (1) the assessment of the quality of the high resolution AERI measurements, (2) the assessment of the ability to define the atmospheric state in the radiating column, and (3) the evaluation of the capability of LBLRTM. Validations have been performed on spectral radiance data, obtained from April 1994 through July 1994, through the analysis of the spectral interval and physical process. The results are archived as a function of time, enabling the retrieval of specific data and facilitating investigations and diurnal effects, seasonal effects, and longer-term trends. While the initial focus is restricted to clear-sky analyses, efforts are under way to include the effects of clouds and aerosols. Plans are well formulated for the extension of the current approach to the shortwave. An overview of the concept of the QME is described by Miller et al. (1994), and a detailed description of this study is provided by Clough et al. (1994).

  9. Relationship of intertidal surface sediment chlorophyll concentration to hyper-spectral reflectance and chlorophyll fluorescence

    NARCIS (Netherlands)

    Kromkamp, J.C.; Morris, E.P.; Forster, R.M.; Honeywill, C.; Hagerthey, S.; Paterson, D.M.

    2006-01-01

    Estimating biomass of microphytobenthos (MPB) on intertidal mud flats is extremely difficult due to their patchy occurrence, especially at the scale of an entire mud flat. We tested two optical approaches that can be applied in situ: spectral reflectance and chlorophyll fluorescence. These two

  10. Red-Shift Effects in Surface Enhanced Raman Spectroscopy: Spectral or Intensity Dependence of the Near-Field?

    KAUST Repository

    Colas, Florent

    2016-06-06

    Optimum amplification in Surface Enhanced Raman Scattering (SERS) from individual nanoantennas is expected when the excitation is slightly blue-shifted with respect to the Localized Surface Plasmon Resonance (LSPR), so that the LSPR peak falls in the middle between the laser and the Stokes Raman emission. Recent experiments have shown when moving the excitation from the visible to the near-infrared that this rule of thumb is no more valid. The excitation has to be red-shifted with respect to the LSPR peak, up to 80nm, to obtain highest SERS. Such discrepancy is usually attributed to a Near-Field (NF) to Far-Field (FF) spectral shift. Here we critically discuss this hypothesis for the case of gold nanocylinders. By combining multi-wavelength excitation SERS experiments with numerical calculations, we show that the red-shift of the excitation energy does not originate from a spectral shift between the extinction (FF) and the near-field distribution (NF), which is found to be not larger than 10nm. Rather, it can be accounted for by looking at the peculiar spectral dependence of the near-field intensity on the cylinders diameter, characterized by an initial increase, up to 180nm diameter, followed by a decrease and a pronounced skewness.

  11. Four-phonon scattering significantly reduces intrinsic thermal conductivity of solids

    Science.gov (United States)

    Feng, Tianli; Lindsay, Lucas; Ruan, Xiulin

    2017-10-01

    For decades, the three-phonon scattering process has been considered to govern thermal transport in solids, while the role of higher-order four-phonon scattering has been persistently unclear and so ignored. However, recent quantitative calculations of three-phonon scattering have often shown a significant overestimation of thermal conductivity as compared to experimental values. In this Rapid Communication we show that four-phonon scattering is generally important in solids and can remedy such discrepancies. For silicon and diamond, the predicted thermal conductivity is reduced by 30% at 1000 K after including four-phonon scattering, bringing predictions in excellent agreement with measurements. For the projected ultrahigh-thermal conductivity material, zinc-blende BAs, a competitor of diamond as a heat sink material, four-phonon scattering is found to be strikingly strong as three-phonon processes have an extremely limited phase space for scattering. The four-phonon scattering reduces the predicted thermal conductivity from 2200 to 1400 W/m K at room temperature. The reduction at 1000 K is 60%. We also find that optical phonon scattering rates are largely affected, being important in applications such as phonon bottlenecks in equilibrating electronic excitations. Recognizing that four-phonon scattering is expensive to calculate, in the end we provide some guidelines on how to quickly assess the significance of four-phonon scattering, based on energy surface anharmonicity and the scattering phase space. Our work clears the decades-long fundamental question of the significance of higher-order scattering, and points out ways to improve thermoelectrics, thermal barrier coatings, nuclear materials, and radiative heat transfer.

  12. THE HUBBLE WIDE FIELD CAMERA 3 TEST OF SURFACES IN THE OUTER SOLAR SYSTEM: SPECTRAL VARIATION ON KUIPER BELT OBJECTS

    International Nuclear Information System (INIS)

    Fraser, Wesley C.; Brown, Michael E.; Glass, Florian

    2015-01-01

    Here, we present additional photometry of targets observed as part of the Hubble Wide Field Camera 3 (WFC3) Test of Surfaces in the Outer Solar System. Twelve targets were re-observed with the WFC3 in the optical and NIR wavebands designed to complement those used during the first visit. Additionally, all of the observations originally presented by Fraser and Brown were reanalyzed through the same updated photometry pipeline. A re-analysis of the optical and NIR color distribution reveals a bifurcated optical color distribution and only two identifiable spectral classes, each of which occupies a broad range of colors and has correlated optical and NIR colors, in agreement with our previous findings. We report the detection of significant spectral variations on five targets which cannot be attributed to photometry errors, cosmic rays, point-spread function or sensitivity variations, or other image artifacts capable of explaining the magnitude of the variation. The spectrally variable objects are found to have a broad range of dynamical classes and absolute magnitudes, exhibit a broad range of apparent magnitude variations, and are found in both compositional classes. The spectrally variable objects with sufficiently accurate colors for spectral classification maintain their membership, belonging to the same class at both epochs. 2005 TV189 exhibits a sufficiently broad difference in color at the two epochs that span the full range of colors of the neutral class. This strongly argues that the neutral class is one single class with a broad range of colors, rather than the combination of multiple overlapping classes

  13. Enhancing of optic phonon contribution in hydrodynamic phonon transport

    Science.gov (United States)

    de Tomas, C.; Cantarero, A.; Lopeandia, A. F.; Alvarez, F. X.

    2015-10-01

    In the framework of the kinetic-collective model of phonon heat transport, we analyze how each range of the phonon frequency spectrum contributes to the total thermal conductivity both in the macro and the nanoscale. For this purpose, we use two case study samples: naturally occurring bulk silicon and a 115 nm of diameter silicon nanowire. We show that the contribution of high-energy phonons (optic branches) is non-negligible only when N-collisions are strongly present. This contribution increases when the effective size of the sample decreases, and it is found to be up to a 10% at room temperature for the 115 nm nanowire, corroborating preliminar ab-initio predictions.

  14. The Impact of the Spectral Band Number and Width on the Oil Pollution Diagnostics on Earth Surface by Laser Fluorescence Method

    Directory of Open Access Journals (Sweden)

    Yu. V. Fedotov

    2017-01-01

    Full Text Available Using the remote sensing methods is the most promising for day-to-day control of oil pollution. The laser-induced fluorescence method provides efficient detection and classification of oil pollutions. To monitor oil pollutions on the earth surface is more complicated than on the water one because of lower fluorescence intensity and interfering fluorescence of natural objects available on the earth surface.Properties of oil pollution classifiers depend largely on the number and positions of spectral bands of fluorescence registration. Reducing the number of spectral bands allows us to diminish computation complexity and cost of equipment. In some cases the reduction increases classification accuracy. The number of spectral bands can be reduced through increasing their width.The paper presents mathematical modeling of oil pollution detection and classification. The experimentally obtained fluorescence spectra of oil pollutions on different substrates were used as input data. The k-nearest neighbors algorithm was used to detect and classify oil pollutions. Cross validation was applied in mathematical modeling.The mathematical modeling results have shown that for oil pollutions detection using over 8 spectral bands (band width less than 50 nm a classification error rate does not depend on the further increasing number of the spectral bands.As to the type classification of oil pollutions (4 classes, an increasing width of the spectral bands up to 60 nm (the number of spectral bands reduced up 7 does not lead to a significantly decreasing overall classification accuracy.In the case of the sort classification of oil pollutions (8 classes a local maximum of the overall accuracy has been observed at 25-30 nm width of the spectral band (14-16 spectral bands. The spectral resolution improvement (increasing the number of bands does give an essentially increasing accuracy.The paper has shown that to detect and classify oil pollutions on the earth surface

  15. Fresnel lens solar concentrator design and spectral distribution on focus surface

    Science.gov (United States)

    Shen, Zuo Chun; Lu, Yu; Lu, Jian Ye

    2011-09-01

    It is necessary to analysize the spectral distribution of sun light on focal spot as well as its condenser ratio, both in the study of the different quantum efficiency of photoelectric materials and the different spectral absorption coefficient for the laser medium. Based on the absorption spectrum of Cr/Nd:YAG ceramic, this paper addresses itself to the study of convex Fresnel lens focus solar light and choose spectrum. Set Parameters which are used for the design of Fresnel lens such as the ring width, height the focal length as well as the design of spectrum can be changed and the spectral ditribution on focal plane can be controlled. By way of simulation, a method through which is the best optical design for matching Cr/Nd:YAG ceramic absorption spectrum can be found. The maximum absorb power density in six optimum design is 288.5 W/cm2, which is 3.2-18.5% higher than absorb power density in six initial design based on purpose of obtaining the maximum power density.

  16. Phonons from neutron powder diffraction

    Science.gov (United States)

    Dimitrov, D. A.; Louca, D.; Röder, H.

    1999-09-01

    The spherically averaged structure function S(\\|q\\|) obtained from pulsed neutron powder diffraction contains both elastic and inelastic scattering via an integral over energy. The Fourier transformation of S(\\|q\\|) to real space, as is done in the pair density function (PDF) analysis, regularizes the data, i.e., it accentuates the diffuse scattering. We present a technique which enables the extraction of off-center (\\|q\\|≠0) phonon information from powder diffraction experiments by comparing the experimental PDF with theoretical calculations based on standard interatomic potentials and the crystal symmetry. This procedure [dynamics from powder diffraction] has been successfully implemented as demonstrated here for two systems, a simple metal fcc Ni and an ionic crystal CaF2. Although computationally intensive, this data analysis allows for a phonon based modeling of the PDF, and additionally provides off-center phonon information from neutron powder diffraction.

  17. Spectral surface plasmon resonance imaging for the detection of clenbuterol via three-dimensional immobilization of bioprobes.

    Science.gov (United States)

    Yao, Manwen; Wu, Yichuan; Fang, Xiangyi; Yang, Yucong; Liu, Hongjun

    2015-04-15

    A method of immobilizing clenbuterol (CLEN) on the sensor chip for spectral surface plasmon resonance imaging (SPRi) was experimentally investigated. The bioprobes on the sensor chip were prepared by immobilizing bovine serum albumin (BSA) protein and conjugating CLEN molecules to BSA, which provides more active points and free orientations for specific binding. The calibration curve showed that the wavelength resonance shift decreased as the concentration of CLEN analyte increased, consistent with the inhibition principle. The limit of detection (LOD) was estimated to be 6.32 μg/ml. This method proved to be highly specific, high throughput, label free, and operationally convenient. Copyright © 2015 Elsevier Inc. All rights reserved.

  18. Electron-phonon coupling of the actinide metals

    DEFF Research Database (Denmark)

    Skriver, H. L.; Mertig, I.

    1985-01-01

    The authors have estimated the strength of the electron-phonon coupling in Fr and Ra plus the light actinides Ac through Pu. The underlying self-consistent band-structure calculations were performed by the scalar relativistic linear-muffin-tin-orbital method including l quantum numbers s through g......, and the electron-phonon parameters were obtained within the rigid-atomic-sphere approximation. The electron-phonon coupling in Fr through Th is found to be dominated by pd and df scattering and in Pa through Pu by pd and fg scattering. At the equilibrium volumes and as a function of atomic number, the electron...... be related to the changeover from an s-to- d to an s-to-f electronic transition and a related change in the topology of the Fermi surface...

  19. Dynamical Fano-Like Interference between Rabi Oscillations and Coherent Phonons in a Semiconductor Microcavity System.

    Science.gov (United States)

    Yoshino, S; Oohata, G; Mizoguchi, K

    2015-10-09

    We report on dynamical interference between short-lived Rabi oscillations and long-lived coherent phonons in CuCl semiconductor microcavities resulting from the coupling between the two oscillations. The Fourier-transformed spectra of the time-domain signals obtained from semiconductor microcavities by using a pump-probe technique show that the intensity of the coherent longitudinal optical phonon of CuCl is enhanced by increasing that of the Rabi oscillation, which indicates that the coherent phonon is driven by the Rabi oscillation through the Fröhlich interaction. Moreover, as the Rabi oscillation frequency decreases upon crossing the phonon frequency, the spectral profile of the coherent phonon changes from a peak to a dip with an asymmetric structure. The continuous wavelet transformation reveals that these peak and dip structures originate from constructive and destructive interference between Rabi oscillations and coherent phonons, respectively. We demonstrate that the asymmetric spectral structures in relation to the frequency detuning are well reproduced by using a classical coupled oscillator model on the basis of dynamical Fano-like interference.

  20. Ab initio optimization of phonon drag effect for lower-temperature thermoelectric energy conversion

    Science.gov (United States)

    Zhou, Jiawei; Liao, Bolin; Qiu, Bo; Huberman, Samuel; Esfarjani, Keivan; Dresselhaus, Mildred S.; Chen, Gang

    2015-01-01

    Although the thermoelectric figure of merit zT above 300 K has seen significant improvement recently, the progress at lower temperatures has been slow, mainly limited by the relatively low Seebeck coefficient and high thermal conductivity. Here we report, for the first time to our knowledge, success in first-principles computation of the phonon drag effect—a coupling phenomenon between electrons and nonequilibrium phonons—in heavily doped region and its optimization to enhance the Seebeck coefficient while reducing the phonon thermal conductivity by nanostructuring. Our simulation quantitatively identifies the major phonons contributing to the phonon drag, which are spectrally distinct from those carrying heat, and further reveals that although the phonon drag is reduced in heavily doped samples, a significant contribution to Seebeck coefficient still exists. An ideal phonon filter is proposed to enhance zT of silicon at room temperature by a factor of 20 to ∼0.25, and the enhancement can reach 70 times at 100 K. This work opens up a new venue toward better thermoelectrics by harnessing nonequilibrium phonons. PMID:26627231

  1. First principles phonon calculations in materials science

    OpenAIRE

    Togo, Atsushi; Tanaka, Isao

    2015-01-01

    Phonon plays essential roles in dynamical behaviors and thermal properties, which are central topics in fundamental issues of materials science. The importance of first principles phonon calculations cannot be overly emphasized. Phonopy is an open source code for such calculations launched by the present authors, which has been world-widely used. Here we demonstrate phonon properties with fundamental equations and show examples how the phonon calculations are applied in materials science.

  2. Spectral analysis of atmospheric composition: application to surface ozone model–measurement comparisons

    Directory of Open Access Journals (Sweden)

    D. R. Bowdalo

    2016-07-01

    Full Text Available Models of atmospheric composition play an essential role in our scientific understanding of atmospheric processes and in providing policy strategies to deal with societally relevant problems such as climate change, air quality, and ecosystem degradation. The fidelity of these models needs to be assessed against observations to ensure that errors in model formulations are found and that model limitations are understood. A range of approaches are necessary for these comparisons. Here, we apply a spectral analysis methodology for this comparison. We use the Lomb–Scargle periodogram, a method similar to a Fourier transform, but better suited to deal with the gapped data sets typical of observational data. We apply this methodology to long-term hourly ozone observations and the equivalent model (GEOS-Chem output. We show that the spectrally transformed observational data show a distinct power spectrum with regimes indicative of meteorological processes (weather, macroweather and specific peaks observed at the daily and annual timescales together with corresponding harmonic peaks at one-half, one-third, etc., of these frequencies. Model output shows corresponding features. A comparison between the amplitude and phase of these peaks introduces a new comparison methodology between model and measurements. We focus on the amplitude and phase of diurnal and seasonal cycles and present observational/model comparisons and discuss model performance. We find large biases notably for the seasonal cycle in the mid-latitude Northern Hemisphere where the amplitudes are generally overestimated by up to 16 ppbv, and phases are too late on the order of 1–5 months. This spectral methodology can be applied to a range of model–measurement applications and is highly suitable for Multimodel Intercomparison Projects (MIPs.

  3. Evidence of differentiated near-surface plutons on Vesta in integrated Dawn color images and spectral datasets

    Science.gov (United States)

    Cheek, L.; Sunshine, J.

    2014-07-01

    Introduction: Recent analyses of Visible and Infrared Mapping Spectrometer (VIR) data from the Dawn mission [1] revealed isolated areas on the asteroid (4) Vesta that contain enhanced abundances of olivine [2,3]. However, this olivine component is only subtly expressed in the VIR data, superimposed on spectrally dominant pyroxene absorptions. The highly ''mixed'' nature of these spectra is likely due, in part, to the relatively coarse spatial resolution of VIR (˜190 m/pixel in HAMO-2) [4], which averages the spectral characteristics of potentially heterogeneous meter-scale outcrops. The capability to resolve the olivine-enhanced regions at a finer scale may reveal a spectrally-dominant olivine component that would facilitate characterization of 1) the distribution and context of the olivine-enhanced exposures, and 2) the spectral properties of the olivine component, providing clues to mineral composition. In order to access finer spatial scales while preserving the detailed mineralogic information offered by the hyperspectral VIR instrument, we use an approach developed for the Moon by [5] that is based on an inversion of the Spectral Mixture Analysis (SMA) framework [6]. Here, we project the VIR data onto co-located, multispectral Framing Camera (FC) data with a spatial resolution of ˜50 m/pixel (HAMO-2) [7]. The analysis was carried out using georeferenced VIR and FC calibrated mosaics for the olivine-enhanced region containing Bellicia and Arruntia craters in the northern hemisphere of Vesta. The approach produces a set of four calculated VIR end members, as well as a projected image cube that contains a calculated VIR spectrum for each FC pixel in the scene. An important advantage of this approach is that it can be applied to co-located multi- and hyperspectral datasets on other planetary bodies. Initial Results: We find that VIR observations for diverse areas across the scene are well described by the following hyperspectral end members: two spectra

  4. Estimation of spectral solar radiation based on global insolation and characteristics of spectral solar radiation on a tilt surface; Zenten nissharyo ni motozuku zenten nissha supekutoru no suitei to keishamen bunko tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Baba, H.; Kanayama, K.; Endo, N.; Koromohara, K.; Takayama, H. [Kitami Institute of Technology, Hokkaido (Japan)

    1996-10-27

    Use of global insolation for estimating the corresponding spectral distribution is proposed. Measurements of global insolation spectrum throughout a year were compiled for clear days and cloudy days, ranked by 100W/m{sup 2}, for the clarification of spectral distribution. Global insolation quantity for a clear day was subject mainly to sun elevation. The global insolation spectral distribution with the sun elevation not lower than 15{degree} was similar to Bird`s model. Under the cloudy sky, energy density was lower in the region of wavelengths longer than the peak wavelength of 0.46{mu}m, and the distribution curve was sharper than that under the clear sky. Values given by Bird`s model were larger than measured values in the wavelength range of 0.6-1.8{mu}m, which was attributed to absorption by vapor. From the standard spectral distribution charts for the clear sky and cloudy sky, and from the dimensionless spectral distributions obtained by dividing them by the peak values, spectral distributions could be estimated of insolation quantities for the clear sky, cloudy sky, etc. As for the characteristics of spectral solar radiation on a tilt surface obtained from Bird`s model, they agreed with actually measured values at an angle of inclination of 60{degree} or smaller. 6 refs., 10 figs., 1 tab.

  5. Interactions of light with rough dielectric surfaces - Spectral reflectance and polarimetric properties

    Science.gov (United States)

    Yon, S. A.; Pieters, C. M.

    1988-01-01

    The nature of the interactions of visible and NIR radiation with the surfaces of rock and mineral samples was investigated by measuring the reflectance and the polarization properties of scattered and reflected light for slab samples of obsidian and fine-grained basalt, prepared to controlled surface roughness. It is shown that the degree to which radiation can penetrate a surface and then scatter back out, an essential criterion for mineralogic determinations based on reflectance spectra, depends not only upon the composition of the material, but also on its physical condition such as sample grain size and surface roughness. Comparison of the experimentally measured reflectance and polarization from smooth and rough slab materials with the predicted models indicates that single Fresnel reflections are responsible for the largest part of the reflected intensity resulting from interactions with the surfaces of dielectric materials; multiple Fresnel reflections are much less important for such surfaces.

  6. Heat flux induced blueshift of dominant phonon wavelength and its impact on thermal conductivity

    Directory of Open Access Journals (Sweden)

    Aymeric Ramiere

    2017-01-01

    Full Text Available The concept of dominant phonon wavelength is investigated in systems submitted to a heat flux at low temperatures. Using spectral energy distributions, a treatment of two-dimensional and three-dimensional structures is conducted in parallel. We demonstrate a significant reduction of the dominant phonon wavelength, up to 62%, due to a displacement of the phonon spectrum towards higher frequencies in presence of a heat flux. We name this phenomenon blueshift effect. A formula is provided to directly calculate the corrected dominant phonon wavelength. We illustrate the impact of the blueshift effect by showing that a temperature gradient of 10% at 4K yields a 20% reduction in the thermal conductivity. Therefore, ignoring the blueshift effect in a thermal model can notably alter the physical interpretation of measurements. The results suggest that an appropriate heat flux environment can improve thermoelectric device performances.

  7. The mid-IR spectral effects of darkening agents and porosity on the silicate surface features of airless bodies

    Science.gov (United States)

    Young, C. L.; Wray, J. J.; Poston, M.; Hand, K. P.; Carlson, R. W.

    2017-12-01

    The surfaces of airless bodies present opportunities to investigate the physical processes acting on planetary systems over time, without the need to account for surface-atmosphere interactions. Silicate surfaces mixed with fine-grained optically dark material with varying degrees of porosity are ubiquitous on many airless bodies (e.g., Earth's Moon, Deimos, Phobos, asteroids, meteorites, and moons of the outer solar system). Although the mid-IR is rich in emissivity features of important minerals and molecular groups, including organics [e.g., 1], it is less studied for airless conditions and presents challenges in signal-to-noise ratio, especially for the colder outer solar system bodies with fined-grained surfaces [2, 3]. We systematically measured the mid-IR spectra of different mixtures of three silicates (antigorite, lizardite, and pure silica) with varying porosities and amounts of darkening agent (iron oxide and carbon). Serpentines, such as antigorite and lizardite, are common to airless surfaces, and their mid-IR spectra in the presence of darkening agents and different surface porosities would be typical for those measured by spacecraft. Although pure silica has only been measured in the plumes of Enceladus, it presents exciting possibilities for other Saturn-system surfaces due to long range transport [4], and it is therefore important to investigate how its spectral signature would be manifested in the mid-IR. Overall, this work provides a library of mineral mixtures to facilitate dealing with current and future mid-IR datasets of airless bodies. These results are also applicable to the development of future missions to airless bodies, and our continuing efforts will help determine if mid-IR spectrometry is worthwhile for surface compositional studies of icy bodies. The mixtures presented here could be useful for testing future mid-IR instruments by confirming detectability of spectral features for typical materials on the surfaces of interest. [1

  8. Measuring and modeling the effect of surface moisture on the spectral reflectance of coastal beach sand

    NARCIS (Netherlands)

    Nolet, Corjan; Poortinga, Ate; Roosjen, Peter; Bartholomeus, Harm; Ruessink, Gerben|info:eu-repo/dai/nl/169093360

    2014-01-01

    Surface moisture is an important supply limiting factor for aeolian sand transport, which is the primary driver of coastal dune development. As such, it is critical to account for the control of surface moisture on available sand for dune building. Optical remote sensing has the potential to measure

  9. Development of Surfaces Optically Suitable for Flat Solar Panels. [using a reflectometer which separately evaluates spectral and diffuse reflectivities of surfaces

    Science.gov (United States)

    1979-01-01

    A reflectometer which can separately evaluate the spectral and diffuse reflectivities of surfaces is described. A phase locked detection system for the reflectometer is also described. A selective coating on aluminum potentially useful for flat plate solar collector applications is presented. The coating is composed of strongly bound copper oxide (divalent) and is formed by an etching process performed on an aluminum alloy with high copper content. Fabrication costs are expected to be small due to the one stop fabrication process. A number of conclusions gathered from the literature as to the required optical properties of flat plate solar collectors are discussed.

  10. Spectral Dependent Degradation of the Solar Diffuser on Suomi-NPP VIIRS Due to Surface Roughness-Induced Rayleigh Scattering

    Directory of Open Access Journals (Sweden)

    Xi Shao

    2016-03-01

    Full Text Available The Visible Infrared Imaging Radiometer Suite (VIIRS onboard Suomi National Polar Orbiting Partnership (SNPP uses a solar diffuser (SD as its radiometric calibrator for the reflective solar band calibration. The SD is made of Spectralon™ (one type of fluoropolymer and was chosen because of its controlled reflectance in the Visible/Near-Infrared/Shortwave-Infrared region and its near-Lambertian reflectance property. On-orbit changes in VIIRS SD reflectance as monitored by the Solar Diffuser Stability Monitor showed faster degradation of SD reflectance for 0.4 to 0.6 µm channels than the longer wavelength channels. Analysis of VIIRS SD reflectance data show that the spectral dependent degradation of SD reflectance in short wavelength can be explained with a SD Surface Roughness (length scale << wavelength based Rayleigh Scattering (SRRS model due to exposure to solar UV radiation and energetic particles. The characteristic length parameter of the SD surface roughness is derived from the long term reflectance data of the VIIRS SD and it changes at approximately the tens of nanometers level over the operational period of VIIRS. This estimated roughness length scale is consistent with the experimental result from radiation exposure of a fluoropolymer sample and validates the applicability of the Rayleigh scattering-based model. The model is also applicable to explaining the spectral dependent degradation of the SDs on other satellites. This novel approach allows us to better understand the physical processes of the SD degradation, and is complementary to previous mathematics based models.

  11. Theory of generation of angular momentum of phonons by heat current and its conversion to spins

    Science.gov (United States)

    Hamada, Masato; Murakami, Shuichi

    Spin-rotation coupling in crystals will enable us to convert between spin current and mechanical rotations, as has been studied in surface acoustic waves, in liquid metals, and in carbon nanotubes. In this presentation we focus on angular momentum of phonons. In nonmagnetic crystals without inversion symmetry, we theoretically demonstrate that phonon modes generally have angular momenta depending on their wave vectors. In equilibrium the sum of the angular momenta is zero. On the other hand, if a heat current flows in the crystal, nonequilibrium phonon distribution leads to nonzero total angular momentum of phonons. It can be observed as a rotation of crystal itself, and as a spin current induced by these phonons via the spin-rotation coupling.

  12. Assessment of Surface Soil Moisture Using High-Resolution Multi-Spectral Imagery and Artificial Neural Networks

    Directory of Open Access Journals (Sweden)

    Leila Hassan-Esfahani

    2015-03-01

    Full Text Available Many crop production management decisions can be informed using data from high-resolution aerial images that provide information about crop health as influenced by soil fertility and moisture. Surface soil moisture is a key component of soil water balance, which addresses water and energy exchanges at the surface/atmosphere interface; however, high-resolution remotely sensed data is rarely used to acquire soil moisture values. In this study, an artificial neural network (ANN model was developed to quantify the effectiveness of using spectral images to estimate surface soil moisture. The model produces acceptable estimations of surface soil moisture (root mean square error (RMSE = 2.0, mean absolute error (MAE = 1.8, coefficient of correlation (r = 0.88, coefficient of performance (e = 0.75 and coefficient of determination (R2 = 0.77 by combining field measurements with inexpensive and readily available remotely sensed inputs. The spatial data (visual spectrum, near infrared, infrared/thermal are produced by the AggieAir™ platform, which includes an unmanned aerial vehicle (UAV that enables users to gather aerial imagery at a low price and high spatial and temporal resolutions. This study reports the development of an ANN model that translates AggieAir™ imagery into estimates of surface soil moisture for a large field irrigated by a center pivot sprinkler system.

  13. Semi-Dirac points in phononic crystals

    KAUST Repository

    Zhang, Xiujuan

    2014-01-01

    A semi-Dirac cone refers to a peculiar type of dispersion relation that is linear along the symmetry line but quadratic in the perpendicular direction. It was originally discovered in electron systems, in which the associated quasi-particles are massless along one direction, like those in graphene, but effective-mass-like along the other. It was reported that a semi-Dirac point is associated with the topological phase transition between a semi-metallic phase and a band insulator. Very recently, the classical analogy of a semi-Dirac cone has been reported in an electromagnetic system. Here, we demonstrate that, by accidental degeneracy, two-dimensional phononic crystals consisting of square arrays of elliptical cylinders embedded in water are also able to produce the particular dispersion relation of a semi-Dirac cone in the center of the Brillouin zone. A perturbation method is used to evaluate the linear slope and to affirm that the dispersion relation is a semi-Dirac type. If the scatterers are made of rubber, in which the acoustic wave velocity is lower than that in water, the semi-Dirac dispersion can be characterized by an effective medium theory. The effective medium parameters link the semi-Dirac point to a topological transition in the iso-frequency surface of the phononic crystal, in which an open hyperbola is changed into a closed ellipse. This topological transition results in drastic change in wave manipulation. On the other hand, the theory also reveals that the phononic crystal is a double-zero-index material along the x-direction and photonic-band-edge material along the perpendicular direction (y-direction). If the scatterers are made of steel, in which the acoustic wave velocity is higher than that in water, the effective medium description fails, even though the semi-Dirac dispersion relation looks similar to that in the previous case. Therefore different wave transport behavior is expected. The semi-Dirac points in phononic crystals described in

  14. Ultraviolet Raman Spectral Signatures in Support of Lisa (Laser Interrogation of Surface Agents)

    National Research Council Canada - National Science Library

    Sedlacek, III, Arthur J; Finfrock, Charles C; Christesen, Steve; Chyba, Tom; Higdon, Scott

    2003-01-01

    ... (Laser Interrogation of Surface Agents). This engineering, testing and evaluation effort uses a novel mini-Raman lidar technique for on-the-move, short-range, non-contact detection and identification of chemical agents on the battlefield...

  15. Combined retrieval of Arctic liquid water cloud and surface snow properties using airborne spectral solar remote sensing

    Science.gov (United States)

    Ehrlich, André; Bierwirth, Eike; Istomina, Larysa; Wendisch, Manfred

    2017-09-01

    The passive solar remote sensing of cloud properties over highly reflecting ground is challenging, mostly due to the low contrast between the cloud reflectivity and that of the underlying surfaces (sea ice and snow). Uncertainties in the retrieved cloud optical thickness τ and cloud droplet effective radius reff, C may arise from uncertainties in the assumed spectral surface albedo, which is mainly determined by the generally unknown effective snow grain size reff, S. Therefore, in a first step the effects of the assumed snow grain size are systematically quantified for the conventional bispectral retrieval technique of τ and reff, C for liquid water clouds. In general, the impact of uncertainties of reff, S is largest for small snow grain sizes. While the uncertainties of retrieved τ are independent of the cloud optical thickness and solar zenith angle, the bias of retrieved reff, C increases for optically thin clouds and high Sun. The largest deviations between the retrieved and true original values are found with 83 % for τ and 62 % for reff, C. In the second part of the paper a retrieval method is presented that simultaneously derives all three parameters (τ, reff, C, reff, S) and therefore accounts for changes in the snow grain size. Ratios of spectral cloud reflectivity measurements at the three wavelengths λ1 = 1040 nm (sensitive to reff, S), λ2 = 1650 nm (sensitive to τ), and λ3 = 2100 nm (sensitive to reff, C) are combined in a trispectral retrieval algorithm. In a feasibility study, spectral cloud reflectivity measurements collected by the Spectral Modular Airborne Radiation measurement sysTem (SMART) during the research campaign Vertical Distribution of Ice in Arctic Mixed-Phase Clouds (VERDI, April/May 2012) were used to test the retrieval procedure. Two cases of observations above the Canadian Beaufort Sea, one with dense snow-covered sea ice and another with a distinct snow-covered sea ice edge are analysed. The retrieved values of τ, reff

  16. Combined retrieval of Arctic liquid water cloud and surface snow properties using airborne spectral solar remote sensing

    Directory of Open Access Journals (Sweden)

    A. Ehrlich

    2017-09-01

    Full Text Available The passive solar remote sensing of cloud properties over highly reflecting ground is challenging, mostly due to the low contrast between the cloud reflectivity and that of the underlying surfaces (sea ice and snow. Uncertainties in the retrieved cloud optical thickness τ and cloud droplet effective radius reff, C may arise from uncertainties in the assumed spectral surface albedo, which is mainly determined by the generally unknown effective snow grain size reff, S. Therefore, in a first step the effects of the assumed snow grain size are systematically quantified for the conventional bispectral retrieval technique of τ and reff, C for liquid water clouds. In general, the impact of uncertainties of reff, S is largest for small snow grain sizes. While the uncertainties of retrieved τ are independent of the cloud optical thickness and solar zenith angle, the bias of retrieved reff, C increases for optically thin clouds and high Sun. The largest deviations between the retrieved and true original values are found with 83 % for τ and 62 % for reff, C.In the second part of the paper a retrieval method is presented that simultaneously derives all three parameters (τ, reff, C, reff, S and therefore accounts for changes in the snow grain size. Ratios of spectral cloud reflectivity measurements at the three wavelengths λ1 = 1040 nm (sensitive to reff, S, λ2 = 1650 nm (sensitive to τ, and λ3 = 2100 nm (sensitive to reff, C are combined in a trispectral retrieval algorithm. In a feasibility study, spectral cloud reflectivity measurements collected by the Spectral Modular Airborne Radiation measurement sysTem (SMART during the research campaign Vertical Distribution of Ice in Arctic Mixed-Phase Clouds (VERDI, April/May 2012 were used to test the retrieval procedure. Two cases of observations above the Canadian Beaufort Sea, one with dense snow-covered sea ice and another with a distinct snow-covered sea ice

  17. Observation of cyclotron resonance and electron-phonon coupling in surface states of the bulk-insulating topological insulator Cu0.02Bi2Se3

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Liang [Johns Hopkins Univ., Baltimore, MD (United States). The Inst. of Quantum Matter; Tse, Wang-Kong [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Morris, C. M. [Johns Hopkins Univ., Baltimore, MD (United States). The Inst. of Quantum Matter; Brahlek, M. [Rutgers Univ., Piscataway, NJ (United States). Dept. of Physics and Astronomy; Koirala, N. [Rutgers Univ., Piscataway, NJ (United States). Dept. of Physics and Astronomy; Oh, S. [Rutgers Univ., Piscataway, NJ (United States). Dept. of Physics and Astronomy; Armitage, N. P. [Johns Hopkins Univ., Baltimore, MD (United States). The Inst. of Quantum Matter

    2015-02-05

    We have utilized magneto-optical time-domain spectroscopy to investigate the low frequency optical response of topological insulator Cu0.02Bi2Se3 and Bi2Se3 films. With both field and frequency depedence, such experiments give sufficient information to measure the mobility and carrier density of multiple conduction channels simultaneously. We observe sharp cyclotron resonances (CRs) in both samples. The small amount of Cu substitution into the Cu0.02Bi2Se3 induces a true bulk insulator with only a single conduction channel with total sheet carrier density 4.9 x 1012/cm2 and mobility as large as 4000 cm2/V s. This is consistent with pure topological surface state (TSSs) conduction with a chemical potential 150 meV above the Dirac point. Hence, a true topological insulator with an insulating bulk is realized. The CR broadens at high fields, an e ect that we attribute to an electron-phonon interaction. This assignment is supported by an extended Drude model analysis on the zero field data. In contrast to Cu0.02Bi2Se3, two charge channels were observed in normal Bi2Se3 films. We demonstrate a method to distinguish between the dominant TSSs and trivial bulk/2DEG states. The dominant channel exhibits a CR with a carrier density of ~2.0 x 1013/cm2 and mobility ~3200 cm2/V s, consistent with TSSs with a chemical potential ~350meV above the Dirac point.

  18. Phonon-Driven Oscillatory Plasmonic Excitonic Nanomaterials

    Energy Technology Data Exchange (ETDEWEB)

    Kirschner, Matthew S. [Department; Ding, Wendu [Department; Li, Yuxiu [Center; College; Chapman, Craig T. [Department; Lei, Aiwen [College; Lin, Xiao-Min [Center; Chen, Lin X. [Department; Chemical; Schatz, George C. [Department; Schaller, Richard D. [Department; Center

    2017-12-08

    We demonstrate that coherent acoustic phonons derived from plasmonic nanoparticles can modulate electronic interactions with proximal excitonic molecular species. A series of gold bipyramids with systematically varied aspect ratios and corresponding localized surface plasmon resonance energies, functionalized with a J-aggregated thiacarbocyanine dye molecule, produce two hybridized states that exhibit clear anti-crossing behavior with a Rabi splitting energy of 120 meV. In metal nanoparticles, photoexcitation generates coherent acoustic phonons that cause oscillations in the plasmon resonance energy. In the coupled system, these photo-generated oscillations alter the metal nanoparticle’s energetic contribution to the hybridized system and, as a result, change the coupling between the plasmon and exciton. We demonstrate that such modulations in the hybridization is consistent across a wide range of bipyramid ensembles. We also use Finite-Difference Time Domain calculations to develop a simple model describing this behavior. Such oscillatory plasmonic-excitonic nanomaterials (OPENs) offer a route to manipulate and dynamically-tune the interactions of plasmonic/excitonic systems and unlock a range of potential applications.

  19. Satellite estimation of surface spectral ultraviolet irradiance using OMI data in East Asia

    Science.gov (United States)

    Lee, H.; Kim, J.; Jeong, U.

    2017-12-01

    Due to a strong influence to the human health and ecosystem environment, continuous monitoring of the surface ultraviolet (UV) irradiance is important nowadays. The amount of UVA (320-400 nm) and UVB (290-320 nm) radiation at the Earth surface depends on the extent of Rayleigh scattering by atmospheric gas molecules, the radiative absorption by ozone, radiative scattering by clouds, and both absorption and scattering by airborne aerosols. Thus advanced consideration of these factors is the essential part to establish the process of UV irradiance estimation. Also UV index (UVI) is a simple parameter to show the strength of surface UV irradiance, therefore UVI has been widely utilized for the purpose of UV monitoring. In this study, we estimate surface UV irradiance at East Asia using realistic input based on OMI Total Ozone and reflectivity, and then validate this estimated comparing to UV irradiance from World Ozone and Ultraviolet Radiation Data Centre (WOUDC) data. In this work, we also try to develop our own retrieval algorithm for better estimation of surface irradiance. We use the Vector Linearized Discrete Ordinate Radiative Transfer (VLIDORT) model version 2.6 for our UV irradiance calculation. The input to the VLIDORT radiative transfer calculations are the total ozone column (TOMS V7 climatology), the surface albedo (Herman and Celarier, 1997) and the cloud optical depth. Based on these, the UV irradiance is calculated based on look-up table (LUT) approach. To correct absorbing aerosol, UV irradiance algorithm added climatological aerosol information (Arola et al., 2009). The further study, we analyze the comprehensive uncertainty analysis based on LUT and all input parameters.

  20. Experimental CC stretching phonon dispersion curves and electron phonon coupling in polyene derivatives

    Science.gov (United States)

    Bianco, A.; Del Zoppo, M.; Zerbi, G.

    2004-01-01

    We analyze the infrared and Raman spectra (both experimentally and with the aid of quantum chemical calculations) of a series of polyenals which provide us with the fortunate case of a set of polyene chains with one of the end groups consisting of a C=O group which not only does take part in the conjugation but also pulls electrons from the chain making the whole system highly polar, thus affecting the vibrational transition moments. In the following we show, for the first time, that it is possible to derive experimental phonon dispersion curves and these prove to be different for each chain length. We support our experimental findings with Density Functional Theory quantum chemical calculations which reproduce with sufficient accuracy the IR and Raman spectral pattern and at the same time help in disentangling the assignment of the fine structure observed in the experimental spectra.

  1. Spectral measurements of returned spacecraft surfaces and the implications for space debris material measurements

    Science.gov (United States)

    Jorgensen, K.; Culp, R. D.; Clark, R. N.

    2001-10-01

    Knowledge of the physical properties of orbital debris is necessary for modeling the debris environment. Current methods determine the size and mass of orbital debris based on knowledge or assumption of the material type of the piece. By using spectroscopy, one can determine the material type of the piece by comparing the absorption features of its spectra to that of lab spectra for given materials. The goal of this research is not to improve the models themselves, but to improve the information others use to make the models. In order to determine the effects of the space environment on the reflectance spectra of spacecraft materials, researchers measured materials from returned spacecraft. Measurements of material degradation for returned missions from the Long Duration Exposure Facility (LDEF) are documented herein. When the spectra of returned spacecraft materials were compared with the pre-flight laboratory spectra degradation in the samples were seen mostly in the visible wavelengths, while the samples showed similar features in the near-infrared. Overall, the results displayed less degradation on the spaceflight samples than anticipated. The spectral measurements of returned spacecraft materials lent credence to continuing the study of determining the material type of orbital debris using spectroscopy.

  2. Spectral asymptotics of a strong delta ' interaction supported by a surface

    Czech Academy of Sciences Publication Activity Database

    Exner, Pavel; Jex, M.

    2014-01-01

    Roč. 378, 30-31 (2014), s. 2091-2095 ISSN 0375-9601 R&D Projects: GA ČR(CZ) GA14-06818S Institutional support: RVO:61389005 Keywords : delta ' surface interaction * strong coupling expansion Subject RIV: BE - Theoretical Physics Impact factor: 1.683, year: 2014

  3. Free-surface Multiples and full-waveform inversion spectral resolution

    NARCIS (Netherlands)

    Kazei, V.V.; Kashtan, B.M.; Troyan, V.N.; Mulder, W.A.

    2015-01-01

    Low frequencies play a crucial role in the convergence of full-waveform inversion to the correct model in most of its current implementations. However, the lower the frequencies, the bigger are the amplitudes of the surface waves, causing the inversion to be driven by the latter. If they are not

  4. Comparison of the surface ion density of silica gel evaluated via spectral induced polarization versus acid-base titration

    Science.gov (United States)

    Hao, Na; Moysey, Stephen M. J.; Powell, Brian A.; Ntarlagiannis, Dimitrios

    2016-12-01

    Surface complexation models are widely used with batch adsorption experiments to characterize and predict surface geochemical processes in porous media. In contrast, the spectral induced polarization (SIP) method has recently been used to non-invasively monitor in situ subsurface chemical reactions in porous media, such as ion adsorption processes on mineral surfaces. Here we compare these tools for investigating surface site density changes during pH-dependent sodium adsorption on a silica gel. Continuous SIP measurements were conducted using a lab scale column packed with silica gel. A constant inflow of 0.05 M NaCl solution was introduced to the column while the influent pH was changed from 7.0 to 10.0 over the course of the experiment. The SIP measurements indicate that the pH change caused a 38.49 ± 0.30 μS cm- 1 increase in the imaginary conductivity of the silica gel. This increase is thought to result from deprotonation of silanol groups on the silica gel surface caused by the rise in pH, followed by sorption of Na+ cations. Fitting the SIP data using the mechanistic model of Leroy et al. (Leroyet al., 2008), which is based on the triple layer model of a mineral surface, we estimated an increase in the silica gel surface site density of 26.9 × 1016 sites m- 2. We independently used a potentiometric acid-base titration data for the silica gel to calibrate the triple layer model using the software FITEQL and observed a total increase in the surface site density for sodium sorption of 11.2 × 1016 sites m- 2, which is approximately 2.4 times smaller than the value estimated using the SIP model. By simulating the SIP response based on the calibrated surface complexation model, we found a moderate association between the measured and estimated imaginary conductivity (R2 = 0.65). These results suggest that the surface complexation model used here does not capture all mechanisms contributing to polarization of the silica gel captured by the SIP data.

  5. Spectral surface plasmon resonance biosensor for detection of staphylococal enterotoxin B /SEB/ in milk

    Czech Academy of Sciences Publication Activity Database

    Homola, Jiří; Dostálek, Jakub; Chen, S.; Rasooly, A.; Jiang, S.; Yee, S. S.

    2002-01-01

    Roč. 75, 1/2 (2002), s. 61-69 ISSN 0168-1605 R&D Projects: GA ČR GA102/99/0549; GA ČR GA102/00/1536 Institutional research plan: CEZ:AV0Z2067918 Keywords : biosensors * surface plasmon resonance Subject RIV: JB - Sensors, Measurment, Regulation Impact factor: 1.719, year: 2002

  6. Phonons in fcc binary alloys

    International Nuclear Information System (INIS)

    Sharma, Amita; Rathore, R.P.S.

    1992-01-01

    Born-Mayer potential has been modified to account for the unpaired (three body) forces among the common nearest neighbours of the ordered binary fcc alloys i.e. Ni 3 Fe 7 , Ni 5 Fe 5 and Ni 75 Fe 25 . The three body potential is added to the two body form of Morse to formalize the total interaction potential. Measured inverse ionic compressibility, cohesive energy, lattice constant and one measured phonon frequency are used to evaluate the defining parameters of the potential. The potential seeks to bring about the binding among 140 and 132 atoms though pair wise (two body) and non-pair wise (three body) forces respectively. The phonon-dispersion relations obtained by solving the secular equation are compared with the experimental findings on the aforesaid alloys. (author). 19 refs., 3 figs

  7. Fast Inversion of Air-Coupled Spectral Analysis of Surface Wave (SASW Using in situ Particle Displacement

    Directory of Open Access Journals (Sweden)

    Yifeng Lu

    2015-11-01

    Full Text Available Spectral Analysis of Surface Wave (SASW is widely used in nondestructive subsurface profiling for geological sites. The air-coupled SASW is an extension from conventional SASW methods by replacing ground-mounted accelerometers with non-contact microphones, which acquire a leaky surface wave instead of ground vibration. The air-coupled SASW is a good candidate for fast inspection in shallow geological studies. Especially for pavement maintenance, minimum traffic interference might be induced. One issue that restrains SASW from fast inspection is the traditional slow inversion which relies on guess-and-check iteration techniques including a forward analysis. In this article, a fast inversion analysis algorithm is proposed to estimate the shear velocity profile without performing conventional forward simulation. By investigating the attenuation of particle displacement along penetrating depths, a weighted combination relationship is derived to connect the dispersion curve with the shear velocity profile directly. Using this relationship, the shear velocity profile could be estimated from a given/measured dispersion curve. The proposed procedure allows the surface wave-based method to be fully automatic and even operated in real-time for geological site and pavement assessment. The method is verified by the forward analysis with stiffness matrix method. It is also proved by comparing with other published results using various inversion methods.

  8. Phonon impact on optical control schemes of quantum dots: Role of quantum dot geometry and symmetry

    Science.gov (United States)

    Lüker, S.; Kuhn, T.; Reiter, D. E.

    2017-12-01

    Phonons strongly influence the optical control of semiconductor quantum dots. When modeling the electron-phonon interaction in several theoretical approaches, the quantum dot geometry is approximated by a spherical structure, though typical self-assembled quantum dots are strongly lens-shaped. By explicitly comparing simulations of a spherical and a lens-shaped dot using a well-established correlation expansion approach, we show that, indeed, lens-shaped dots can be exactly mapped to a spherical geometry when studying the phonon influence on the electronic system. We also give a recipe to reproduce spectral densities from more involved dots by rather simple spherical models. On the other hand, breaking the spherical symmetry has a pronounced impact on the spatiotemporal properties of the phonon dynamics. As an example we show that for a lens-shaped quantum dot, the phonon emission is strongly concentrated along the direction of the smallest axis of the dot, which is important for the use of phonons for the communication between different dots.

  9. Effects of quantum statistics of phonons on the thermal conductivity of silicon and germanium nanoribbons

    Science.gov (United States)

    Kosevich, Yuriy A.; Savin, Alexander V.; Cantarero, Andrés

    2013-01-01

    We present molecular dynamics simulation of phonon thermal conductivity of semiconductor nanoribbons with an account for phonon quantum statistics. In our semiquantum molecular dynamics simulation, dynamics of the system is described with the use of classical Newtonian equations of motion where the effect of phonon quantum statistics is introduced through random Langevin-like forces with a specific power spectral density (color noise). The color noise describes interaction of the molecular system with the thermostat. The thermal transport of silicon and germanium nanoribbons with atomically smooth (perfect) and rough (porous) edges are studied. We show that the existence of rough (porous) edges and the quantum statistics of phonon change drastically the low-temperature thermal conductivity of the nanoribbon in comparison with that of the perfect nanoribbon with atomically smooth edges and classical phonon dynamics and statistics. The rough-edge phonon scattering and weak anharmonicity of the considered lattice produce a weakly pronounced maximum of thermal conductivity of the nanoribbon at low temperature.

  10. High-Resolution Mapping of Urban Surface Water Using ZY-3 Multi-Spectral Imagery

    Directory of Open Access Journals (Sweden)

    Fangfang Yao

    2015-09-01

    Full Text Available Accurate information of urban surface water is important for assessing the role it plays in urban ecosystem services under the content of urbanization and climate change. However, high-resolution monitoring of urban water bodies using remote sensing remains a challenge because of the limitation of previous water indices and the dark building shadow effect. To address this problem, we proposed an automated urban water extraction method (UWEM which combines a new water index, together with a building shadow detection method. Firstly, we trained the parameters of UWEM using ZY-3 imagery of Qingdao, China. Then we verified the algorithm using five other sub-scenes (Aksu, Fuzhou, Hanyang, Huangpo and Huainan ZY-3 imagery. The performance was compared with that of the Normalized Difference Water Index (NDWI. Results indicated that UWEM performed significantly better at the sub-scenes with kappa coefficients improved by 7.87%, 32.35%, 12.64%, 29.72%, 14.29%, respectively, and total omission and commission error reduced by 61.53%, 65.74%, 83.51%, 82.44%, and 74.40%, respectively. Furthermore, UWEM has more stable performances than NDWI’s in a range of thresholds near zero. It reduces the over- and under-estimation issues which often accompany previous water indices when mapping urban surface water under complex environmental conditions.

  11. On application of ion-photon emission method in spectral analysis of surface of different materials

    International Nuclear Information System (INIS)

    Bazhin, A.I.; Buravlev, Yu.M.; Ryzhov, V.N.

    1983-01-01

    Possibilities of application of ion-photom emission (IPE) method for determining element composition of the aluminium bronzes surface and profiles of distribution of hydrogen and helium implanted in metals (Mon Wn Cun Aln OKh18N10T steel) by ion bombardment have been studied. As ion source duoplasmatron which permits to obtain ions of inert (helium, argon) and active (hydrogenn oxygen) gases with current density 0.1-1 mA/cm 2 in the beam and energy from 5 to 25 keV has been applied. The photomultiplier PEM-79 has been used as a detector of optical radiation arising in the course of ion bombardment of the sample. For spectra recording the two-coordinate recorder has been used. Calibration charts which permit to determine the concentration of the investigated elements with 3-5% accuracy are obtained. The method sensitivity depends on excitation energy of transition observed in the spectrum. By known volumetric element concentration in the sample one can determine its concentration on a sUrface without resorting to a calibration chart in the coUrse of target sputtering. It has been found that the target impurity sputtering coefficient becomes nonselective to their relatiVe content. At wide incidence angles of ion beam. In contrast to other excitation methods (arc, spark) the IPE method possesses locality which constitutes 1 μm at a quite simple method of ion beam focussing (single lens)

  12. Coherent Phonon Rabi Oscillations with a High-Frequency Carbon Nanotube Phonon Cavity.

    Science.gov (United States)

    Zhu, Dong; Wang, Xin-He; Kong, Wei-Cheng; Deng, Guang-Wei; Wang, Jiang-Tao; Li, Hai-Ou; Cao, Gang; Xiao, Ming; Jiang, Kai-Li; Dai, Xing-Can; Guo, Guang-Can; Nori, Franco; Guo, Guo-Ping

    2017-02-08

    Phonon-cavity electromechanics allows the manipulation of mechanical oscillations similar to photon-cavity systems. Many advances on this subject have been achieved in various materials. In addition, the coherent phonon transfer (phonon Rabi oscillations) between the phonon cavity mode and another oscillation mode has attracted many interest in nanoscience. Here, we demonstrate coherent phonon transfer in a carbon nanotube phonon-cavity system with two mechanical modes exhibiting strong dynamical coupling. The gate-tunable phonon oscillation modes are manipulated and detected by extending the red-detuned pump idea of photonic cavity electromechanics. The first- and second-order coherent phonon transfers are observed with Rabi frequencies 591 and 125 kHz, respectively. The frequency quality factor product fQ m ∼ 2 × 10 12 Hz achieved here is larger than k B T base /h, which may enable the future realization of Rabi oscillations in the quantum regime.

  13. Light-induced nonthermal population of optical phonons in nanocrystals

    Science.gov (United States)

    Falcão, Bruno P.; Leitão, Joaquim P.; Correia, Maria R.; Soares, Maria R.; Wiggers, Hartmut; Cantarero, Andrés; Pereira, Rui N.

    2017-03-01

    Raman spectroscopy is widely used to study bulk and nanomaterials, where information is frequently obtained from spectral line positions and intensities. In this study, we monitored the Raman spectrum of ensembles of semiconductor nanocrystals (NCs) as a function of optical excitation intensity (optical excitation experiments). We observe that in NCs the red-shift of the Raman peak position with increasing light power density is much steeper than that recorded for the corresponding bulk material. The increase in optical excitation intensity results also in an increasingly higher temperature of the NCs as obtained with Raman thermometry through the commonly used Stokes/anti-Stokes intensity ratio. More significantly, the obtained dependence of the Raman peak position on temperature in optical excitation experiments is markedly different from that observed when the same NCs are excited only thermally (thermal excitation experiments). This difference is not observed for the control bulk material. The inefficient diffusion of photogenerated charges in nanoparticulate systems, due to their inherently low electrical conductivity, results in a higher steady-state density of photoexcited charges and, consequently, also in a stronger excitation of optical phonons that cannot decay quickly enough into acoustic phonons. This results in a nonthermal population of optical phonons and thus the Raman spectrum deviates from that expected for the temperature of the system. Our study has major consequences to the general application of Raman spectroscopy to nanomaterials.

  14. Infrared spectral investigations of UV irradiated nucleobases adsorbed on mineral surfaces

    Science.gov (United States)

    Fornaro, Teresa; Brucato, John Robert; Pace, Emanuele; Guidi, Mariangela Cestelli; Branciamore, Sergio; Pucci, Amaranta

    2013-09-01

    The interaction between electromagnetic radiation and bio-molecules in heterogeneous environments is a prebiotically relevant process. Minerals may have a pivotal role in the prebiotic evolution of complex chemical systems, mediating the effects of electromagnetic radiation, influencing the photostability of bio-molecules, catalyzing important chemical reactions and/or protecting molecules against degradation. In particular, nucleobases are relevant bio-molecules to investigate both in the prebiotic context, because they are coding components of nucleic acids, and from the standpoint of the survival of biological systems in space conditions. Several studies on the photodynamics of nucleobases suggest that their structure could have been naturally selected for the ability to dissipate electronic energy through ultrafast photophysical decay. Considering the putative involvement of minerals in the prebiotic chemistry, it is necessary to study the photostability of nucleobases under space conditions in the presence of mineral matrices, to investigate both the prebiotic processes that might have had a role in the development of the first living entities on Earth and the physical and chemical processes occurring in extraterrestrial environments. We focused our study on the characterization of the nature of the interaction between nucleobases and the surface of the minerals magnesium oxide and forsterite by infrared vibrational spectroscopy. We observed that most of the characteristic bands of pure nucleobases vanished when adsorbed on magnesium oxide. On the contrary, in the case of adenine and uracil adsorbed on forsterite, very intense nucleobase absorption peaks appeared. This phenomenon pertains to the surface selection rules changes related to molecular orientation. Moreover, based on the vibrational shifts, we deduced the molecular interaction sites with the mineral surfaces. Furthermore, we investigated the photostability of nucleobases adsorbed on such minerals

  15. Temperature dependence of phonons in pyrolitic graphite

    International Nuclear Information System (INIS)

    Brockhouse, B.N.; Shirane, G.

    1977-01-01

    Dispersion curves for longitudinal and transverse phonons propagating along and near the c-axis in pyrolitic graphite at temperatures between 4 0 K and 1500 0 C have been measured by neutron spectroscopy. The observed frequencies decrease markedly with increasing temperature (except for the transverse optical ''rippling'' modes in the hexagonal planes). The neutron groups show interesting asymmetrical broadening ascribed to interference between one phonon and many phonon processes

  16. Electron-phonon coupling in one dimension

    International Nuclear Information System (INIS)

    Apostol, M.; Baldea, I.

    1981-08-01

    The Ward identity is derived for the electron-phonon coupling in one dimension and the spectrum of elementary excitations is calculated by assuming that the Fermi distribution is not strongly distorted by interaction. The electron-phonon vertex is renormalized in the case of the forward scattering and Migdal's theorem is discussed. A model is proposed for the giant Kohn anomaly. The dip in the phonon spectrum is obtained and found to be in agreement with the experimental data for KCP. (author)

  17. Spectral and morphological properties of various geological types of Titan’s surface with Cassini VIMS and RADAR

    Science.gov (United States)

    Solomonidou, Anezina; Coustenis, Athena; Lopes, Rosaly M.; Hirtzig, Mathieu; Rodriguez, Sebastien; Malaska, Michael; Drossart, Pierre; Sotin, Christophe; Bratsolis, Emmanuel; Matsoukas, Chris; Brown, Robert; Maltagliati, Luca

    2015-08-01

    Cassini’s VIMS and the RADAR have been investigating Titan’s surface since 2004. Both instruments unveiled the dynamic and complex surface expressions of this Saturnian moon, suggesting exogenic and endogenic processes [1;2;3]. In order to evaluate the atmospheric contribution and thereafter extract surface information, a Radiative transfer code is used to analyse different regions and to monitor their spectral behaviour over time [4;5;7]. We furthermore use RADAR despeckled SAR images to infer information on the morphology [6]. We find that temporal variations of surface albedo occur for some areas, but that their origin may differ from one region to the other. Tui Regio and Sotra Patera change with time becoming darker and brighter respectively in terms of surface albedo. In contrast, we find that the undifferentiated plains and the suggested evaporitic areas in the equatorial regions do not present any significant change [5]. This observation supports the hypothesis that Titan is surface brightening of Sotra supports a possible internal rather than an exogenic origin. This observation supports the hypothesis that Titan is a cryovolcanic world due to the presence of local complex volcanic-like geomorphology [1] and indications of surface albedo changes [4,5]. Potential sources of the energy for cryovolcanism include tidal heating, possible internal convection, and ice tectonics, is believed to be a pre-requisite of a habitable planetary body as it allows the recycling of minerals and potential nutrients and provides localized energy sources. A recent study has shown that tidal forces are a constant and significant source of internal deformation on Titan and the interior liquid water ocean can be relatively warm for reasonable amounts of ammonia concentrations [8].[1] Lopes, R.M.C., et al. JGR, 118, 2013 [2] Solomonidou, A., et al. PSS, 70, 2013 [3] Moore, J.M. GRL, 37, 2010 [4] Solomonidou, A., et al. JGR, 119, 2014 [5] Solomonidou, A., et al. submitted [6

  18. Carbon nanowires: Phonon and π -electron confinement

    Science.gov (United States)

    Milani, Alberto; Tommasini, Matteo; Del Zoppo, Mirella; Castiglioni, Chiara; Zerbi, Giuseppe

    2006-10-01

    The phonon dispersion of an isolated linear chain of carbon atoms is studied by density functional theory. It is shown that the longitudinal optical phonon at the Γ point is affected by Kohn anomaly. Moreover the slope of this phonon branch is modulated by the degree of bond length alternation of the chain and reaches its maximum value in the case of the cumulenic structure (equalized bonds). Phonon dispersion curves of the infinite system computed for different values of the bond length alternation can be put in correspondence with the Raman active modes of finite carbon chains.

  19. Electron-phonon interactions from first principles

    Science.gov (United States)

    Giustino, Feliciano

    2017-01-01

    This article reviews the theory of electron-phonon interactions in solids from the point of view of ab initio calculations. While the electron-phonon interaction has been studied for almost a century, predictive nonempirical calculations have become feasible only during the past two decades. Today it is possible to calculate from first principles many materials properties related to the electron-phonon interaction, including the critical temperature of conventional superconductors, the carrier mobility in semiconductors, the temperature dependence of optical spectra in direct and indirect-gap semiconductors, the relaxation rates of photoexcited carriers, the electron mass renormalization in angle-resolved photoelectron spectra, and the nonadiabatic corrections to phonon dispersion relations. In this article a review of the theoretical and computational framework underlying modern electron-phonon calculations from first principles as well as landmark investigations of the electron-phonon interaction in real materials is given. The first part of the article summarizes the elementary theory of electron-phonon interactions and their calculations based on density-functional theory. The second part discusses a general field-theoretic formulation of the electron-phonon problem and establishes the connection with practical first-principles calculations. The third part reviews a number of recent investigations of electron-phonon interactions in the areas of vibrational spectroscopy, photoelectron spectroscopy, optical spectroscopy, transport, and superconductivity.

  20. Realization of phonon laser with femtosecond technology

    Science.gov (United States)

    Sun, Chi-Kuang; Huang, Yue-Kai; Chern, Gia-Wei

    2002-06-01

    One of the most desirable properties of phonon system is sound amplification by stimulated emission of phonon radiation, coined as SASER or called phonon laser or acoustic laser, which is the acoustic counterpart of LASER. Phonon stimulated emission, or sound amplification, has been previously observed fro several occasions in extremely low temperatures, however a lasing behavior of the phonon oscillators has never been established. It is also desirable to build a phonon laser operating at room temperature. Here we present an optically pumped nano-sized phonon laser with an output acoustic wavelength of 9.3 nm, operating at room temperature. The nano phonon laser is composed by InGaN/GaN multiple-quantum-wells (MQWs). By using femtosecond ultraviolet pulses as pumping sources, coherent acoustic phonon amplification with large acoustic gain was observed. When the induced acoustic gain is higher than the acoustic loss due to its traveling nature, a clear laser-like threshold behavior was observed, which resembles a pulsed optical laser. This demonstration will open a new way toward nano-ultrasonics.

  1. Assessment of the accuracy of snow surface direct beam spectral albedo under a variety of overcast skies derived by a reciprocal approach through radiative transfer simulation.

    Science.gov (United States)

    Li, Shusun; Zhou, Xiaobing

    2003-09-20

    With radiative transfer simulations it is suggested that stable estimates of the highly anisotropic direct beam spectral albedo of snow surface can be derived reciprocally under a variety of overcast skies. An accuracy of +/- 0.008 is achieved over a solar zenith angle range of theta0 snow surface albedo for the polar regions where direct measurement of clear-sky surface albedo is limited to large theta0's only. The enhancement will assist in the validation of snow surface albedo models and improve the representation of polar surface albedo in global circulation models.

  2. Influence of the electron-phonon iinteraction on phonon heat conduction in a molecular nanowire

    Directory of Open Access Journals (Sweden)

    Galović Slobodanka P.

    2006-01-01

    Full Text Available A model for phonon heat conduction in a molecular nanowire is developed. The calculation takes into account modification of the acoustic phonon dispersion relation due to the electron-phonon interaction. The results obtained are compared with models based upon a simpler, Callaway formula.

  3. Anharmonic vibrational properties in periodic systems: energy, electron-phonon coupling, and stress

    OpenAIRE

    Monserrat, Bartomeu; Drummond, N. D.; Needs, R. J.

    2013-01-01

    A unified approach is used to study vibrational properties of periodic systems with first-principles methods and including anharmonic effects. Our approach provides a theoretical basis for the determination of phonon-dependent quantities at finite temperatures. The low-energy portion of the Born-Oppenheimer energy surface is mapped and used to calculate the total vibrational energy including anharmonic effects, electron-phonon coupling, and the vibrational contribution to the stress tensor. W...

  4. Surface enhanced Raman spectroscopy as a new spectral technique for quantitative detection of metal ions.

    Science.gov (United States)

    Temiz, Havva Tumay; Boyaci, Ismail Hakki; Grabchev, Ivo; Tamer, Ugur

    2013-12-01

    Four newly synthesized poly (propylene amine) dendrimers from first and second generation modified with 1,8-naphthalimide units in the dendrimer periphery have been investigated as ligands for the detection of heavy metal ions (Al(3+), Sb(2+), As(2+), Cd(2+) and Pb(2+)) by surface-enhanced Raman spectroscopy. Calibration curves were established for all metal ions between the concentration ranges of 1 x 10(-6) to 5 x 10(-4) M. It has been shown that these dendrimers can be coordinated, especially with different metal ions. Using dendrimer molecules and silver colloids at the same time allowed us to obtain an SERS signal from the abovementioned metal ions at very low concentrations. Principle component analysis (PCA) analysis was also applied to the collected SERS data. Four different PCA models were developed to accomplish the discrimination of five metal ions, which interacted with each of the four dendrimer molecules, separately. A detailed investigation was performed in the present study to provide the basis of a new approach for heavy metal detection. Copyright © 2013 Elsevier B.V. All rights reserved.

  5. Low temperature phonon boundary scattering in slightly rough Silicon nanowires

    Science.gov (United States)

    Ghossoub, Marc; Valavala, Krishna; Seong, Myunghoon; Azeredo, Bruno; Sadhu, Jyothi S.; Sinha, Sanjiv

    2013-03-01

    Nanostructured materials have lower thermal conductivities than the bulk and are promising candidates for thermoelectric applications. In particular, measurements on single silicon nanowires show a reduction in thermal conductivity below the Casimir limit. This reduction increases with surface roughness but the trend and its connection to phonon boundary scattering are still elusive. Here, we measure the thermal conductivity of single silicon nanowires fabricated using metal-assisted chemical etching. High resolution TEM imaging shows crystalline wires with slightly rough surfaces. Their statistical correlation lengths (5-15 nm) and RMS heights (0.8-1.5 nm) are in a range where perturbation-based wave scattering theory is still applicable. We use the thermal conductivity data to extract the frequency dependence of phonon boundary scattering at low temperatures (10-40 K) and show agreement with multiple scattering theory. This work provides insight into enhancing the thermoelectric performance of nanostructures.

  6. Muscle fatigue in women with primary biliary cirrhosis: Spectral analysis of surface electromyography

    Science.gov (United States)

    Biagini, Maria Rosa; Tozzi, Alessandro; Grippo, Antonello; Galli, Andrea; Milani, Stefano; Amantini, Aldo

    2006-01-01

    AIM: To evaluate the myoelectric manifestations of peripheral fatigability in patients with primary biliary cirrhosis in comparison to healthy subjects. METHODS: Sixteen women with primary biliary cirrhosis without comorbidity and 13 healthy women matched for age and body mass index (BMI) completed the self-reported questionnaire fatigue impact scale. All subjects underwent surface electromyography assessment of peripheral fatigability. Anterior tibial muscle isometric voluntary contraction was executed for 20 s at 80% of maximal voluntary isometric contraction. During the exercise electromyographic signal series were recorded and root mean square (expression of central drive) as well as mean and median of electromyographic signal frequency spectrum (estimates of muscle fatigability) were computed. Each subject executed the trial two times. EMG parameters were normalized, then linear regression was applied and slopes were calculated. RESULTS: Seven patients were fatigued (median fatigue impact scale score: 38, range: 26-66) and 9 were not fatigued (median fatigue impact scale score: 7, range: 0-17). The maximal voluntary isometric contraction was similar in patients (82, 54-115 N) and controls (87, 74-101 N), and in patients with high (81, 54-115 N) and low fatigue impact scale scores (86, 65-106 N). Root mean square as well as mean and median of frequency spectrum slopes were compared with the Mann-Whitney U test, and no significant difference was found between fatigued and non-fatigued patients and controls. CONCLUSION: No instrumental evidence of peripheral fatigability can be found in women with primary biliary cirrhosis but no comorbidity, suggesting that fatigue in such patients may be of central origin. PMID:16937530

  7. Uncertainty in the inelastic resonant scattering assisted by phonons

    International Nuclear Information System (INIS)

    Garcia, N.; Garcia-Sanz, J.; Solana, J.

    1977-01-01

    We have analyzed the inelastic minima observed in new results of He atoms scattered from LiF(001) surfaces. This is done considering bound state resonance processes assisted by phonons. The analysis presents large uncertainties. In the range of uncertainty, we find two ''possible'' bands associated with the vibrations of F - and Li + , respectively. Many more experimental data are necessary to confirm the existence of these processes

  8. Non-spherical surface wave amplitude radiation patterns identified from spectral ratios of the 2016 and 2013 DPRK nuclear tests

    Science.gov (United States)

    Ichinose, G. A.; Ford, S. R.; Myers, S.; Pasyanos, M.; Walter, W. R.

    2016-12-01

    The 6 January 2016, 12 February 2013 and 25 May 2009 declared nuclear explosions at the Punggye-ri test site in the Democratic People's Republic of Korea (DPRK) were all closely located providing an opportunity to perform differential analysis. We used spectral ratios of surface waves between 50 and 10 sec period between the co-located events to isolate relative explosion amplitude radiation patterns by the cancelation of propagation and site effects. We calculated the spectral ratios using a dense array of 72 NIED F-NET stations across Japan and all available IMS, IC and IU network stations. Analyses of Rayleigh waves indicated non-spherical radiation for the 2016 and 2013 tests relative to 2009. The 2016/2009 and 2013/2009 event pairs had ellipsoidal radiation patterns. The 2016/2009 pair had an ellipse major axis oriented 123 degrees from north and the 2013/2009 pair was oriented 33 degrees from north. This suggests that both 2016 and 2013 explosions have non-spherical radiation and also that the radiation between 2016 and 2013 were rotated by 90 degrees. This radiation pattern was strongest in the 20 and 33 sec period band but was also observed in the 10 and 50 sec band with higher scatter. We did not discern any Love wave radiation patterns but there is high scatter possibly due to a lower long-period signal to noise ratio on the horizontal relative to the vertical components. There are several possible source models that can theoretically cause non-spherical radiation, for example topography, spall damage, or tectonic release. One implication we have identified is that the radiation pattern makes it problematic for the use of surface waves in relative relocations, typically more robust for earthquakes. The amount of departure from purely spherical radiation is consistent with the 20-30% CLVD and 60-70% isotropic components estimated from regional long-period moment tensor solutions for the two explosions. This work performed under the auspices of the US

  9. Phonon dispersion models for MgB{sub 2} with application of pressure

    Energy Technology Data Exchange (ETDEWEB)

    Alarco, Jose A., E-mail: jose.alarco@qut.edu.au; Talbot, Peter C., E-mail: p.talbot@qut.edu.au; Mackinnon, Ian D.R., E-mail: ian.mackinnon@qut.edu.au

    2017-05-15

    Highlights: • Ab initio DFT MgB{sub 2} phonon dispersion for pressures up to 20 GPa are presented. • Extent of E{sub 2g} phonon anomaly and thermal energy, T{sub δ,} are pressure dependent. • Phonon anomaly thermal energy equivalent to experimental T{sub c} values for MgB{sub 2}. • Computational method to measure T{sub δ} is an effective predictor of T{sub c}. - Abstract: We evaluate, via the Local Density and the Generalised Gradient Approximations to the Density Functional Theory (DFT), the change in form and extent of the E{sub 2g} phonon anomaly of MgB{sub 2} with increase in applied pressure up to 20 GPa. Ab initio DFT calculations on the phonon dispersion (PD) for MgB{sub 2} show a phonon anomaly symmetrically displaced around Γ, the reciprocal lattice origin. This anomaly is related to nesting between diametrically opposite sides of tubular elements of Fermi surfaces, which correspond to sigma bonding and run approximately parallel to the Γ–A reciprocal space direction. The anomaly is parallel to Γ–A and along Γ–M and Γ–K. The extent of the E{sub 2g} phonon anomaly, δ, along Γ–M and Γ–K is a measure of the thermal energy, T{sub δ}, that matches within error the experimental onset superconducting transition temperature, T{sub c}. Ab initio DFT calculations with pressure for −5 GPa < P < 20 GPa show a linear reduction in T{sub δ} that closely matches experimental T{sub c} values for MgB{sub 2}. For phonon-mediated superconductors with AlB{sub 2}–type structures, the thermal energy of the phonon anomaly, T{sub δ}, is a reliable predictor of T{sub c}.

  10. Experimental Study of Electron and Phonon Dynamics in Nanoscale Materials by Ultrafast Laser Time-Domain Spectroscopy

    Science.gov (United States)

    Shen, Xiaohan

    less than 100 nm was observed. The longitudinal acoustic phonon transport in silicon (Si) nanorod with confined diameter and length was investigated. The guided phonon modes in Si nanorod with different frequencies and wave vectors were observed. The mean-free-path of the guided phonons in Si nanorod was found to be larger than the effective phonon mean-free-path in Si film, because of the limited phonon scattering channels in Si nanorod. The phonon density of states and dispersion relation strongly depend on the size and boundary conditions of nanorod. Our work demonstrates the possibility of modifying the phonon transport properties in nanoscale materials by designing the size and boundary conditions, hence the control of thermal conductivity. In addition, the periodicity effect of nanostructures on acoustic phonon transport was investigated in silicon dioxide (SiO2) nanorod arrays. The lattice modes and mechanical eigenmodes were observed, and the pitch effect on lattice modes was discussed. A narrowband acoustic phonon spectroscopic technique with tunable frequency and spectral width throughout GHz frequency range has been developed to investigate the frequency-dependent acoustic phonon transport in nanoscale materials. The quadratic frequency dependence of acoustic attenuation of SiO2 and indium tin oxide (ITO) thin films was observed, and the acoustic attenuation of ITO was found to be larger than SiO2. Moreover, the acoustic control on mechanical resonance of nanoscale materials using the narrowband acoustic phonon source was demonstrated in tungsten thin film.

  11. Splash, pop, sizzle: Information processing with phononic computing

    International Nuclear Information System (INIS)

    Sklan, Sophia R.

    2015-01-01

    Phonons, the quanta of mechanical vibration, are important to the transport of heat and sound in solid materials. Recent advances in the fundamental control of phonons (phononics) have brought into prominence the potential role of phonons in information processing. In this review, the many directions of realizing phononic computing and information processing are examined. Given the relative similarity of vibrational transport at different length scales, the related fields of acoustic, phononic, and thermal information processing are all included, as are quantum and classical computer implementations. Connections are made between the fundamental questions in phonon transport and phononic control and the device level approach to diodes, transistors, memory, and logic. 

  12. Structure factors and phonon dispersion in liquid

    Indian Academy of Sciences (India)

    2Electronics Department, Narmada College of Science and Commerce, Bharuch 392 011,. India. E-mail: apratapmsu@yahoo.com. Abstract. The phonon spectra for .... Structure factors and phonon dispersion in liquid Li0.61Na0.39 alloy. [5] U Balucani and M Zoppi, Dynamics of the liquid state (Clarendon, Oxford, 1994).

  13. Phononic crystals and elastodynamics: Some relevant points

    Energy Technology Data Exchange (ETDEWEB)

    Aravantinos-Zafiris, N. [Dept. of Materials Science, University of Patras, Patras 26504 (Greece); Department of Sound and Musical Instruments Technology, Ionian Islands Technological Educational Institute, Lixouri, 28200 (Greece); Sigalas, M. M. [Dept. of Materials Science, University of Patras, Patras 26504 (Greece); Kafesaki, M. [Institute of Electronic Structure and Laser (IESL), Foundation for Research and Technology, Hellas (FORTH), P.O. Box 1387, 70013 Heraklion, Crete (Greece); Dept. of Materials Science and Technology, Univ. of Crete (Greece); Economou, E. N. [Institute of Electronic Structure and Laser (IESL), Foundation for Research and Technology, Hellas (FORTH), P.O. Box 1387, 70013 Heraklion, Crete (Greece); Dept. of Physics, Univ. of Crete (Greece)

    2014-12-15

    In the present paper we review briefly some of the first works on wave propagation in phononic crystals emphasizing the conditions for the creation of acoustic band-gaps and the role of resonances to the band-gap creation. We show that useful conclusions in the analysis of phononic band gap structures can be drawn by considering the mathematical similarities of the basic classical wave equation (Helmholtz equation) with Schrödinger equation and by employing basic solid state physics concepts and conclusions regarding electronic waves. In the second part of the paper we demonstrate the potential of phononic systems to be used as elastic metamaterials. This is done by demonstrating negative refraction in phononic crystals and subwavelength waveguiding in a linear chain of elastic inclusions, and by proposing a novel structure with close to pentamode behavior. Finally the potential of phononic structures to be used in liquid sensor applications is discussed and demonstrated.

  14. Phononic crystals and elastodynamics: Some relevant points

    International Nuclear Information System (INIS)

    Aravantinos-Zafiris, N.; Sigalas, M. M.; Kafesaki, M.; Economou, E. N.

    2014-01-01

    In the present paper we review briefly some of the first works on wave propagation in phononic crystals emphasizing the conditions for the creation of acoustic band-gaps and the role of resonances to the band-gap creation. We show that useful conclusions in the analysis of phononic band gap structures can be drawn by considering the mathematical similarities of the basic classical wave equation (Helmholtz equation) with Schrödinger equation and by employing basic solid state physics concepts and conclusions regarding electronic waves. In the second part of the paper we demonstrate the potential of phononic systems to be used as elastic metamaterials. This is done by demonstrating negative refraction in phononic crystals and subwavelength waveguiding in a linear chain of elastic inclusions, and by proposing a novel structure with close to pentamode behavior. Finally the potential of phononic structures to be used in liquid sensor applications is discussed and demonstrated

  15. What Can Spectral Properties of Martian Surface and Snc Can Tell Us about the Martian Crust Composition and Evolution

    Science.gov (United States)

    Ody, A.; Poulet, F.; Baratoux, D.; Quantin, C.; Bibring, J. P.

    2014-12-01

    While the study of Martian meteorites can provide detailed information about the crust and mantle composition and evolution, remote-sensing observations, through the merging of compositional and geological data, allow highlighting planetary-scale trends of the Martian crustal evolution [1,2]. Recently, the analysis of the global distribution of mafic minerals [3] has put new constraints on the Martian crust formation and evolution. One of the major results is a past global event of olivine-bearing fissural volcanism that has filled craters and low depressions in the southern highlands and a large part of the Northern plains during the late Noachian/early Hesperian. Petrologic models show that this sudden increase of the olivine content at the Noachian-Hesperian boundary could be the result of a rapid thickening of the lithosphere at the end of the Noachian era [4]. A recent study based on the OMEGA/MEx data has shown that the spectral properties of the shergottites are similar to those of some Noachian and Hesperian terrains [5]. To contrary, the Nakhla spectral properties are very different from those of the observable surface and could be representative of Amazonian terrains buried under dust. These results are best explained with an old age of the shergottites [6] and with the present understanding of the evolution of magma composition at a planetary scale [7]. On the other hand, if shergottites are young [8], the similarities between the shergottites and ancient terrains implies that exceptional conditions of melting with respect to the ambient mantle (e.g., hot spots or water-rich mantle source) were responsible for the formation of these samples [9]. References: [1] McSween et al., 2009, Science, 324. [2] Ehlmann & Edwards 2014, AREPS, vol. 42. [3] Ody et al., 2013, JGR,117,E00J14. [4] Ody et al., 2014, 8th Inter. Conf. on Mars,#1190. [5] Ody et al., 2013, 44th LPSC, #1719. [6] Bouvier et al., 2009, EPSL, 280. [7] Baratoux et al., 2013, JGR, 118. [8] Nyquist

  16. Cross-spectral study of the spatial relationships in the North Pacific sea-surface temperature anomaly field. Report No. 23

    Energy Technology Data Exchange (ETDEWEB)

    Middleton, J.W.

    1980-03-01

    Cross-spectral analysis is used to examine the dependence of the temporal covariation of sea-surface temperature (SST) anomalies at pairs of spatially separated points in the North Pacific on (1) the time scale of the variations, (2) the relative displacement of the points and (3) their location within the North Pacific basin. Spatial scales considered here range from 1000 kilometers up to the width of the basin. The study focuses on cross-spectral estimates for the interannual frequency band, 0.125-0.75 yr/sup -1/ although estimates for three other bands spanning higher frequencies are also examined.

  17. Three-dimensional phonon population anisotropy in silicon nanomembranes

    Energy Technology Data Exchange (ETDEWEB)

    McElhinny, Kyle M.; Gopalakrishnan, Gokul; Holt, Martin V.; Czaplewski, David A.; Evans, Paul G.

    2017-07-01

    Nanoscale single crystals possess modified phonon dispersions due to the truncation of the crystal. The introduction of surfaces alters the population of phonons relative to the bulk and introduces anisotropy arising from the breaking of translational symmetry. Such modifications exist throughout the Brillouin zone, even in structures with dimensions of several nanometers, posing a challenge to the characterization of vibrational properties and leading to uncertainty in predicting the thermal, optical, and electronic properties of nanomaterials. Synchrotron x-ray thermal diffuse scattering studies find that freestanding Si nanomembranes with thicknesses as large as 21 nm exhibit a higher scattering intensity per unit thickness than bulk silicon. In addition, the anisotropy arising from the finite thickness of these membranes produces particularly intense scattering along reciprocal-space directions normal to the membrane surface compared to corresponding in-plane directions. These results reveal the dimensions at which calculations of materials properties and device characteristics based on bulk phonon dispersions require consideration of the nanoscale size of the crystal.

  18. Assessment of performances of sun zenith angle and altitude parameterisations of atmospheric radiative transfer for spectral surface downwelling solar irradiance

    Science.gov (United States)

    Wald, L.; Blanc, Ph.

    2010-09-01

    Satellite-derived assessments of surface downwelling solar irradiance are more and more used by engineering companies in solar energy. Performances are judged satisfactory for the time being. Nevertheless, requests for more accuracy are increasing, in particular in the spectral definition and in the decomposition of the global radiation into direct and diffuse radiations. One approach to reach this goal is to improve both the modelling of the radiative transfer and the quality of the inputs describing the optical state. Within their joint project Heliosat-4, DLR and MINES ParisTech have adopted this approach to create advanced databases of solar irradiance succeeding to the current ones HelioClim and SolEMi. Regarding the model, we have opted for libRadtran, a well-known model of proven quality. As many similar models, running libRadtran is very time-consuming when it comes to process millions or more pixels or grid cells. This is incompatible with real-time operational process. One may adopt the abacus approach, or look-up tables, to overcome the problem. The model is run for a limited number of cases, covering the whole range of values taken by the various inputs of the model. Abaci are such constructed. For each real case, the irradiance value is computed by interpolating within the abaci. In this way, real-time can be envisioned. Nevertheless, the computation of the abaci themselves requires large computing capabilities. In addition, searching the abaci to find the values to interpolate can be time-consuming as the abaci are very large: several millions of values in total. Moreover, it raises the extrapolation problem of parameter out-of-range during the utilisation of the abaci. Parameterisation, when possible, is a means to reduce the amount of computations to be made and subsequently, the computation effort to create the abaci, the size of the abaci, the extrapolation and the searching time. It describes in analytical manner and with a few parameters the

  19. Electron-phonon coupling of light-actinides. Effect of spin-orbit coupling

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez-Castelazo, Paola; Pena-Seaman, Omar de la [Benemerita Universidad Autonoma de Puebla (BUAP), Institute of Physics (IFUAP) (Mexico); Heid, Rolf; Bohnen, Klaus-Peter [Karlsruher Institut fuer Technologie (KIT), Institut fuer Festkoerperphysik (IFP) (Germany)

    2014-07-01

    The physics of actinide metals is quite complex and rich due to the behavior of 5f electrons in the valence region: it goes from itinerant on the early stages of the actinide series to highly localized for the elements with a higher number of 5f electrons involved. In addition, in this systems should be mandatory the inclusion of spin-orbit coupling (SOC). However, only in few cases on electronic and lattice dynamical properties the SOC has been taking into account, while for the electron-phonon (e-ph) coupling such analysis has not been performed so far. Thus, as a first approach we have systematically studied the SOC influence on the full-phonon dispersion and the e-ph coupling for the simplest light-actinide metals: Ac and Th. These elements have been studied within the framework of density functional perturbation theory, using a mixed-basis pseudopotential method. The full-phonon dispersion as well as the Eliashberg spectral function and the electron-phonon coupling parameter have been calculated with and without SOC. The observed effects of SOC in the full-phonon dispersion and Eliashberg function are discussed in detail, together with an analysis of the differences on the electronic properties due to the SOC inclusion in the calculations.

  20. Magnon and phonon dispersion, lifetime, and thermal conductivity of iron from spin-lattice dynamics simulations

    Science.gov (United States)

    Wu, Xufei; Liu, Zeyu; Luo, Tengfei

    2018-02-01

    In recent years, the fundamental physics of spin-lattice (e.g., magnon-phonon) interaction has attracted significant experimental and theoretical interests given its potential paradigm-shifting impacts in areas like spin-thermoelectrics, spin-caloritronics, and spintronics. Modelling studies of the transport of magnons and phonons in magnetic crystals are very rare. In this paper, we use spin-lattice dynamics (SLD) simulations to model ferromagnetic crystalline iron, where the spin and lattice systems are coupled through the atomic position-dependent exchange function, and thus the interaction between magnons and phonons is naturally considered. We then present a method combining SLD simulations with spectral energy analysis to calculate the magnon and phonon harmonic (e.g., dispersion, specific heat, and group velocity) and anharmonic (e.g., scattering rate) properties, based on which their thermal conductivity values are calculated. This work represents an example of using SLD simulations to understand the transport properties involving coupled magnon and phonon dynamics.

  1. Four-phonon scattering reduces intrinsic thermal conductivity of graphene and the contributions from flexural phonons

    Science.gov (United States)

    Feng, Tianli; Ruan, Xiulin

    2018-01-01

    We have developed a formalism of the exact solution to linearized phonon Boltzmann transport equation (BTE) for thermal conductivity calculation including three- and four-phonon scattering. We find strikingly high four-phonon scattering rates in single-layer graphene (SLG) based on the optimized Tersoff potential. The reflection symmetry in graphene, which forbids the three-ZA (out-of-plane acoustic) scattering, allows the four-ZA processes ZA +ZA ⇌ZA +ZA and ZA ⇌ZA +ZA + ZA. As a result, the large phonon population of the low-energy ZA branch originated from the quadratic phonon dispersion leads to high four-phonon scattering rates, even much higher than the three-phonon scattering rates at room temperature. These four-phonon processes are dominated by the normal processes, which lead to a failure of the single mode relaxation time approximation. Therefore, we have solved the exact phonon BTE using an iterative scheme and then calculated the length- and temperature-dependent thermal conductivities. We find that the predicted thermal conductivity of SLG is lower than the previously predicted value from the three-phonon scattering only. The relative contribution of the ZA branch is reduced from 70% to 30% when four-phonon scattering is included. Furthermore, we have demonstrated that the four-phonon scattering in multilayer graphene and graphite is not strong due to the ZA splitting by interlayer van der Waals interaction. We also demonstrate that the five-phonon process in SLG is not strong due to the restriction of reflection symmetry.

  2. A spectral method for retrieving cloud optical thickness and effective radius from surface-based transmittance measurements

    Directory of Open Access Journals (Sweden)

    P. J. McBride

    2011-07-01

    Full Text Available We introduce a new spectral method for the retrieval of optical thickness and effective radius from cloud transmittance that relies on the spectral slope of the normalized transmittance between 1565 nm and 1634 nm, and on cloud transmittance at a visible wavelength. The standard dual-wavelength technique, which is traditionally used in reflectance-based retrievals, is ill-suited for transmittance because it lacks sensitivity to effective radius, especially for optically thin clouds. Using the spectral slope rather than the transmittance itself enhances the sensitivity of transmittance observations with respect to the effective radius. This is demonstrated by applying it to the moderate spectral resolution observations from the Solar Spectral Flux Radiometer (SSFR and Shortwave Spectroradiometer (SWS, and by examining the retrieval uncertainties of the standard and the spectral method for data from the DOE ARM Southern Great Plains (SGP site and a NOAA ship cruise (ICEALOT. The liquid water path (LWP is derived from the retrieved optical thickness and effective radius, based on two different assumptions about the cloud vertical profile, and compared to the simultaneous observations from a microwave radiometer. Optical thickness and effective radius is also compared to MODIS retrievals. In general, the effective radius uncertainties were much larger for the standard retrieval than for the spectral retrieval, particularly for thin clouds. When defining 2 μm as upper limit for the tolerable uncertainty of the effective radius, the standard method returned only very few valid retrievals for clouds with an optical thickness below 25. For the analyzed ICEALOT data (mean optical thickness 23, the spectral method provided valid retrievals for 84 % of the data (24 % for the standard method. For the SGP data (mean optical thickness 44, both methods provided a high return of 90 % for the spectral method and 78 % for the standard method.

  3. Phonon scattering in metallic glasses

    International Nuclear Information System (INIS)

    Black, J.L.

    1979-01-01

    The purpose of this article is to review some recent theoretical and experimental developments in the study of metallic glasses at temperatures near or below 1K. In this temperature regime, it appears that practically all glasses, whether metallic or insulating, behave in a similar fashion. The fact that such similarities occur, despite substantial structural differences between metallic and insulating glasses, constitutes a major theoretical challenge. This challenge, however, is not directly addressed in what follows. Instead, the evidence for universal behavior and the theory which is necessary to understand this evidence are emphasized. It turns out that most of this evidence involves a comparison of phonon scattering in metallic glasses with its counterpart in insulating glasses

  4. Electron–phonon coupling from finite differences

    Science.gov (United States)

    Monserrat, Bartomeu

    2018-02-01

    The interaction between electrons and phonons underlies multiple phenomena in physics, chemistry, and materials science. Examples include superconductivity, electronic transport, and the temperature dependence of optical spectra. A first-principles description of electron–phonon coupling enables the study of the above phenomena with accuracy and material specificity, which can be used to understand experiments and to predict novel effects and functionality. In this topical review, we describe the first-principles calculation of electron–phonon coupling from finite differences. The finite differences approach provides several advantages compared to alternative methods, in particular (i) any underlying electronic structure method can be used, and (ii) terms beyond the lowest order in the electron–phonon interaction can be readily incorporated. But these advantages are associated with a large computational cost that has until recently prevented the widespread adoption of this method. We describe some recent advances, including nondiagonal supercells and thermal lines, that resolve these difficulties, and make the calculation of electron–phonon coupling from finite differences a powerful tool. We review multiple applications of the calculation of electron–phonon coupling from finite differences, including the temperature dependence of optical spectra, superconductivity, charge transport, and the role of defects in semiconductors. These examples illustrate the advantages of finite differences, with cases where semilocal density functional theory is not appropriate for the calculation of electron–phonon coupling and many-body methods such as the GW approximation are required, as well as examples in which higher-order terms in the electron–phonon interaction are essential for an accurate description of the relevant phenomena. We expect that the finite difference approach will play a central role in future studies of the electron–phonon interaction.

  5. Phonon linewidths in YNi2B2C

    Indian Academy of Sciences (India)

    Abstract. Phonons in a metal interact with conduction electrons which give rise to a finite linewidth. In the normal state, this leads to a Lorentzian shape of the phonon line. Density functional theory is able to predict the phonon linewidths as a function of wave vector for each branch of the phonon dispersion. An experimental ...

  6. Integrated phononic crystal resonators based on adiabatically-terminated phononic crystal waveguides

    Directory of Open Access Journals (Sweden)

    Razi Dehghannasiri

    2016-12-01

    Full Text Available In this letter, we demonstrate a new design for integrated phononic crystal (PnC resonators based on confining acoustic waves in a heterogeneous waveguide-based PnC structure. In this architecture, a PnC waveguide that supports a single mode at the desired resonance frequencies is terminated by two waveguide sections with no propagating mode at those frequencies (i.e., have mode gap. The proposed PnC resonators are designed through combining the spatial-domain and the spatial-frequency domain (i.e., the k-domain analysis to achieve a smooth mode envelope. This design approach can benefit both membrane-based and surface-acoustic-wave-based architectures by confining the mode spreading in k-domain that leads to improved electromechanical excitation/detection coupling and reduced loss through propagating bulk modes.

  7. One-dimensional hypersonic phononic crystals.

    Science.gov (United States)

    Gomopoulos, N; Maschke, D; Koh, C Y; Thomas, E L; Tremel, W; Butt, H-J; Fytas, G

    2010-03-10

    We report experimental observation of a normal incidence phononic band gap in one-dimensional periodic (SiO(2)/poly(methyl methacrylate)) multilayer film at gigahertz frequencies using Brillouin spectroscopy. The band gap to midgap ratio of 0.30 occurs for elastic wave propagation along the periodicity direction, whereas for inplane propagation the system displays an effective medium behavior. The phononic properties are well captured by numerical simulations. The porosity in the silica layers presents a structural scaffold for the introduction of secondary active media for potential coupling between phonons and other excitations, such as photons and electrons.

  8. Electron–phonon superconductivity in YIn3

    International Nuclear Information System (INIS)

    Billington, D; Llewellyn-Jones, T M; Maroso, G; Dugdale, S B

    2013-01-01

    First-principles calculations of the electron–phonon coupling were performed on the cubic intermetallic compound YIn 3 . The electron–phonon coupling constant was found to be λ ep = 0.42. Using the Allen–Dynes formula with a Coulomb pseudopotential of μ* = 0.10, a T c of approximately 0.77 K is obtained which is reasonably consistent with the experimentally observed temperature (between 0.8 and 1.1 K). The results indicate that conventional electron–phonon coupling is capable of producing the superconductivity in this compound. (paper)

  9. Current & Heat Transport in Graphene Nanoribbons: Role of Non-Equilibrium Phonons

    Science.gov (United States)

    Pennington, Gary; Finkenstadt, Daniel

    2010-03-01

    The conducting channel of a graphitic nanoscale device is expected to experience a larger degree of thermal isolation when compared to traditional inversion channels of electronic devices. This leads to enhanced non-equilibrium phonon populations which are likely to adversely affect the mobility of graphene-based nanoribbons due to enhanced phonon scattering. Recent reports indicating the importance of carrier scattering with substrate surface polar optical phonons in carbon nanotubes^1 and graphene^2,3 show that this mechanism may allow enhanced heat removal from the nanoribbon channel. To investigate the effects of hot phonon populations on current and heat conduction, we solve the graphene nanoribbon multiband Boltzmann transport equation. Monte Carlo transport techniques are used since phonon populations may be tracked and updated temporally.^4 The electronic structure is solved using the NRL Tight-Binding method,^5 where carriers are scattered by confined acoustic, optical, edge and substrate polar optical phonons. [1] S. V. Rotkin et al., Nano Lett. 9, 1850 (2009). [2] J. H. Chen, C. Jang, S. Xiao, M. Ishigami and M. S. Fuhrer, Nature Nanotech. 3, 206 (2008). [3] V. Perebeinos and P. Avouris, arXiv:0910.4665v1 [cond-mat.mes-hall] (2009). [4] P. Lugli et al., Appl. Phys. Lett. 50, 1251 (1987). [5] D. Finkenstadt, G. Pennington & M.J. Mehl, Phys. Rev. B 76, 121405(R) (2007).

  10. Normal processes of phonon-phonon scattering and thermal conductivity of germanium crystals with isotopic disorder

    CERN Document Server

    Kuleev, I G

    2001-01-01

    The effect of normal processes of the phonon-phonon scattering on the thermal conductivity of the germanium crystals with various isotopic disorder degrees is considered. The phonon pulse redistribution in the normal scattering processes both inside each oscillatory branch (the Simons mechanism) and between various phonon oscillatory branches (the Herring mechanism) is accounted for. The contributions of the longitudinal and cross-sectional phonons drift motion into the thermal conductivity are analyzed. It is shown that the pulse redistribution in the Herring relaxation mechanism leads to essential suppression of the longitudinal phonons drift motion in the isotopically pure germanium crystals. The calculations results of thermal conductivity for the Herring relaxation mechanism agree well with experimental data on the germanium crystals with various isotopic disorder degrees

  11. Controlling competing electronic orders via non-equilibrium acoustic phonons

    Science.gov (United States)

    Schuett, Michael; Orth, Peter; Levchenko, Alex; Fernandes, Rafael

    The interplay between multiple electronic orders is a hallmark of strongly correlated systems displaying unconventional superconductivity. While doping, pressure, and magnetic field are the standard knobs employed to assess these different phases, ultrafast pump-and-probe techniques opened a new window to probe these systems. Recent examples include the ultrafast excitation of coherent optical phonons coupling to electronic states in cuprates and iron pnictides. In this work, we demonstrate theoretically that non-equilibrium acoustic phonons provide a promising framework to manipulate competing electronic phases and favor unconventional superconductivity over other states. In particular, we show that electrons coupled to out-of-equilibrium anisotropic acoustic phonons enter a steady state in which the effective electronic temperature varies around the Fermi surface. Such a momentum-dependent temperature can then be used to selectively heat electronic states that contribute primarily to density-wave instabilities, reducing their competition with superconductivity. We illustrate this phenomenon by computing the microscopic steady-state phase diagram of the iron pnictides, showing that superconductivity is enhanced with respect to the competing antiferromagnetic phase.

  12. AUTOMATED CLASSIFICATION OF LAND COVER USING LANDSAT 8 OLI SURFACE REFLECTANCE PRODUCT AND SPECTRAL PATTERN ANALYSIS CONCEPT - CASE STUDY IN HANOI, VIETNAM

    Directory of Open Access Journals (Sweden)

    D. Nguyen Dinh

    2016-06-01

    Full Text Available Recently USGS released provisional Landsat 8 Surface Reflectance product, which allows conducting land cover mapping over large composed of number of image scenes without necessity of atmospheric correction. In this study, the authors present a new concept for automated classification of land cover. This concept is based on spectral patterns analysis of reflected bands and can be automated using predefined classification rule set constituted of spectral pattern shape, total reflected radiance index (TRRI and ratios of spectral bands. Given a pixel vector B6 = {b1,b2,b3,b4,b5,b6} where b1, b2,...,b6 denote bands 2, 3, ...,7 of OLI sensor respectively. By using the pixel vector B6 we can construct spectral reflectance curve. Each spectral curve is featured by a shape, which can be described in simplified form of an analogue pattern, which is consisted of 15 digits of 0, 1 and 2 showing mutual relative position of spectral vertices. Value of comparison between band i and j is 2 if bj > bi, 1 if bj = bi and 0 if bj i. Simplified spectral pattern is defined by 15 digits as m1,2m1,3m1,4m1,5m1,6m2,3m2,4m2,5m2,6m3,4m3,5m3,6m4,5m4,6m5,6 where mi,j is result of comparison of reflectance between bi and bj and has values of 0, 1 and 2. After construction of SSP for each pixel in the input image, the original image will be decomposed to component images, which contain pixels with the same SRCS pattern. The decomposition can be written analytically by equation A = Σnk=1Ck where A stands for original image with 6 spectral bands, n is number of component images decomposed from A and Ck is component image. For this study, we use Landsat 8 OLI reflectance image LC81270452013352LGN00 and LC81270452015182LGN00. For the decomposition, we use only six reflective bands. Each land cover class is defined by SSP code, threshold values for TRRI and band ratios. Automated classification of land cover was realized with 8 classes: forest, shrub, grass, water, wetland

  13. Non-markovian model of photon-assisted dephasing by electron-phonon interactions in a coupled quantum-dot-cavity system

    DEFF Research Database (Denmark)

    Nielsen, Per Kær; Nielsen, Torben Roland; Lodahl, Peter

    2010-01-01

    treatments. A pronounced consequence is the emergence of a phonon induced spectral asymmetry when detuning the cavity from the quantum-dot resonance. The asymmetry can only be explained when considering the polaritonic quasiparticle nature of the quantum-dot-cavity system. Furthermore, a temperature induced......We investigate the influence of electron-phonon interactions on the dynamical properties of a quantum-dot-cavity QED system. We show that non-Markovian effects in the phonon reservoir lead to strong changes in the dynamics, arising from photon-assisted dephasing processes, not present in Markovian...

  14. Length-scale dependent phonon interactions

    CERN Document Server

    Srivastava, Gyaneshwar

    2014-01-01

    This book presents  a comprehensive description of phonons and their interactions in systems with different dimensions and length scales. Internationally-recognized leaders describe theories and measurements of phonon interactions  in relation to the design of materials with exotic properties such as metamaterials, nano-mechanical systems, next-generation electronic, photonic, and acoustic devices, energy harvesting, optical information storage, and applications of phonon lasers in a variety of fields. The emergence of techniques for control of semiconductor properties and geometry has enabled engineers to design structures in which functionality is derived from controlling electron behavior. As manufacturing techniques have greatly expanded the list of available materials and the range of attainable length scales, similar opportunities now exist for designing devices whose functionality is derived from controlling phonon behavior. However, progress in this area is hampered by gaps in our knowledge of phono...

  15. Electromagnetic decay of two-phonon states

    International Nuclear Information System (INIS)

    Catara, F.; Chomaz, Ph.; Van Giai, N.; Paris-11 Univ., 91 - Orsay

    1991-01-01

    The electromagnetic decay of two-phonon states corresponding to the multi-excitation of giant resonances is studied. The calculations are performed within a boson expansion approach and the elementary modes are constructed in random phase approximation (RPA). The rates for direct transition of two-phonon states to the ground state turn out to be not negligibly smaller than those from the (single) giant resonances. The former transitions are accompanied by a γ-ray whose energy is equal to the sum of the two phonon energies. Thus the detection of such high energy γ-rays could provide a signature of the excitation of two-phonon states. (author) 9 refs., 3 tabs

  16. Characterizing phonon dynamics using stochastic sampling

    International Nuclear Information System (INIS)

    Kunal, K.; Aluru, N. R.

    2016-01-01

    Predicting phonon relaxation time from molecular dynamics (MD) requires a long simulation time to compute the mode energy auto-correlation function. Here, we present an alternative approach to infer the phonon life-time from an approximate form of the energy auto-correlation function. The method requires as an input a set of sampled equilibrium configurations. A stochastic sampling method is used to generate the equilibrium configurations. We consider a truncated Taylor series expansion of the phonon energy auto-correlation function. The different terms in the truncated correlation function are obtained using the stochastic sampling approach. The expansion terms, thus, obtained are in good agreement with the corresponding values obtained using MD. We then use the approximate function to compute the phonon relaxation time. The relaxation time computed using this method is compared with that obtained from the exact correlation function. The two values are in agreement with each other.

  17. Influence of phonons on semiconductor quantum emission

    Energy Technology Data Exchange (ETDEWEB)

    Feldtmann, Thomas

    2009-07-06

    A microscopic theory of interacting charge carriers, lattice vibrations, and light modes in semiconductor systems is presented. The theory is applied to study quantum dots and phonon-assisted luminescence in bulk semiconductors and heterostructures. (orig.)

  18. Phonon limited electronic transport in Pb

    Science.gov (United States)

    Rittweger, F.; Hinsche, N. F.; Mertig, I.

    2017-09-01

    We present a fully ab initio based scheme to compute electronic transport properties, i.e. the electrical conductivity σ and thermopower S, in the presence of electron-phonon interaction. We explicitly investigate the \

  19. Mapping impervious surfaces in the Xiangjiang River basin based on remote sensing spectral indices: a case study in Chang-Zhu-Tan region

    Science.gov (United States)

    Zhang, Xiaoping; Lyu, Ying; Zhang, Huaguo; Gong, Fang; Zhang, Yongxin; Li, Chaokui

    2017-10-01

    Increased impervious surfaces pose significant threats to the hydrologic cycle of the Xiangjiang River basin as a consequence of urbanization. Quantifying the percentage of imperviousness within the Xiangjiang River basin is important to pollution control and watershed management. Per-pixel and sub-pixel methods have been widely used for analyzing impervious surface changes, but these methods are considered as complicated, computationally intensive, and sometimes subjective, especially when applied to a large geographic area. In this paper, normalized difference built-up index (NDBI), normalized difference impervious surface index (NDISI), normalized difference vegetation index (NDVI) and enhanced built-up and bareness index (EBBI) were respectively used to estimate impervious surfaces in Chang-ZhuTan region (CZT) of the Xiangjiang River basin, and a comparative analyses was conducted. Then the optimum spectral index was chosen to map the percentage of impervious surfaces for the study area. The results show that the spectral index of NDBI has the optimum estimation of large-scale impervious surfaces, and the percentage of imperviousness in CZT was 13.87%. The water quality in CZT was characterized as "protected", indicating that water quality protection in the plain areas of CZT is imperative.

  20. Cooling of photoexcited carriers in graphene by internal and substrate phonons

    Science.gov (United States)

    Low, Tony; Perebeinos, Vasili; Kim, Raseong; Freitag, Marcus; Avouris, Phaedon

    2012-07-01

    We investigate the energy relaxation of hot carriers produced by photoexcitation of graphene through coupling to both intrinsic and remote (substrate) surface polar phonons using the Boltzmann equation approach. We find that the energy relaxation of hot photocarriers in graphene on commonly used polar substrates, under most conditions, is dominated by remote surface polar phonons. We also calculate key characteristics of the energy relaxation process, such as the transient cooling time and steady-state carrier temperatures and photocarrier densities, which determine the thermoelectric and photovoltaic photoresponse, respectively. Substrate engineering can be a promising route to efficient optoelectronic devices driven by hot carrier dynamics.

  1. Surface-sensitive FTIR spectral measurements of nanogram samples using 30-100-μm-thick planar Ge waveguides

    Science.gov (United States)

    Braiman, Mark S.; Plunkett, Susan E.; Stone, James J.

    1998-06-01

    We have developed techniques for fabricating supported planar Ge waveguides that are useful for measuring broadband mid-IR evanescent-wave absorption spectra from small numbers of molecules. The waveguides are ground and polished as thin as 30 μm, starting from larger pieces of commercially-available single-crystal Ge. Such waveguides are useful as extremely sensitive multiple-internal-reflection elements, when used in conjunction with an FTIR spectrometer with microscope accessory and a small-area detector. With careful polishing and alignment, optical losses can be reduced to those predicted as resulting from ray spreading within the waveguide and from reflection at the air-Ge interface. For example, by using a Spectra-Tech Research IR-Plan™ microscope with a (100 μm)2 detector element, we have been able to demonstrate broadband IR power transmission through a 30-μm-thick, 3-mm-wide waveguide that is 4% of the open-beam throughput focused through a 30 μm×3 mm slit at the sample focal plane. Supported planar Ge waveguides between 30 and 100 μm in thickness function as internal reflection elements with 10-20 reflections per mm of length. Using such waveguides, we have been able to make surface-sensitive spectral measurements of tiny samples. For example, we can easily observe the FTIR absorption spectrum selectively from the adhesive layer on 3M Scotch™ tape, without interfering absorption from the tape backing. A 0.07 mm2 piece of tape, carrying only several μg of adhesive, still produces distinct bands with absorbance values as large as 0.18. The great sensitivity to monolayer samples covering small contact areas has allowed us to measure useful FTIR spectra of the plasma membranes of intact cells, e.g. individual 1-mm-diameter frog oocytes, submerged in aqueous media. The protein and lipid components in a patch of such a single-bilayer membrane give absorbances on the order of 0.01.

  2. Vibrational properties of the Au-(√{3 }×√{3 } )/Si(111) surface reconstruction

    Science.gov (United States)

    Halbig, B.; Liebhaber, M.; Bass, U.; Geurts, J.; Speiser, E.; Räthel, J.; Chandola, S.; Esser, N.; Krenz, M.; Neufeld, S.; Schmidt, W. G.; Sanna, S.

    2018-01-01

    The vibrational properties of the Au-induced (√{3 }×√{3 })R 30∘ reconstruction of the Si(111) surface are investigated by polarized surface Raman spectroscopy and density-functional theory. The Raman measurements are performed in situ at room temperature as well as 20 K, and they reveal the presence of vibrational eigenmodes in the spectral range from 20 to 450 cm-1. In particular, two peaks of E symmetry at 75 and 183 cm-1 dominate the spectra. No substantial difference between room- and low-temperature spectra is observed, suggesting that the system does not undergo a phase transition down to 20 K. First-principles calculations are performed based on the structural models discussed in the literature. The thermodynamically stable conjugate honeycomb-chained-trimer model (CHCT) [Surf. Sci. 275, L691 (1992), 10.1016/0039-6028(92)90785-5] leads to phonon eigenvalues compatible with the experimental observations in the investigated spectral range. On the basis of the phonon eigenfrequencies, symmetries, and Raman intensities, we assign the measured spectral features to the calculated phonon modes. The good agreement between measured and calculated modes provides a strong argument in favor of the CHCT model.

  3. Squeezed Phonons: Modulating Quantum Fluctuations of Atomic Displacements.

    Science.gov (United States)

    Hu, Xuedong; Nori, Franco

    1997-03-01

    We have studied phonon squeezed states and also put forward several proposals for their generation(On phonon parametric process, X. Hu and F. Nori, Phys. Rev. Lett. 76), 2294 (1996); on polariton mechanism, X. Hu and F. Nori, Phys. Rev. B 53, 2419 (1996); on second-order Raman scattering, X. Hu and F. Nori, preprint.. Here, we compare the relative merits and limitations of these approaches, including several factors that will limit the amount of phonon squeezing. In particular, we investigate the effect of the initial thermal states on the phonon modes. Using a model for the phonon density matrix, we also study the mixing of the phonon squeezed states with thermal states, which describes the decay of the phonon coherence. Finally, we calculate the maximum possible squeezing from a phonon parametric process limited by phonon decay.

  4. Phonon Routing in Integrated Optomechanical Cavity-waveguide Systems

    Science.gov (United States)

    2015-08-20

    k ~ωk b̂†k b̂k + ∑ k ~(gLk b̂†Lb̂k + g ? Lk b̂Lb̂ † k) + ∑ k ~(gRk b̂†Rb̂k + g ? Rk b̂Rb̂ † k), (E1) where b†k(bk) is the creation ( annihilation ...together to form optomechanical circuits. Using a pair of optomechanical cavities coupled together via a phonon waveguide we demonstrate a tunable delay and...period is set by the free spectral range of the waveguide modes. V. DISCUSSION The devices presented in this work, involving pairs of optomechanical

  5. Phonon Sensor Dynamics for Cryogenic Dark Matter Search Experiment

    Energy Technology Data Exchange (ETDEWEB)

    Yen, Jeffrey [Stanford Univ., CA (United States)

    2015-01-01

    Understanding the quasiparticle diffusion process inside sputtered aluminum (Al thin films (~ 0.1-1 μm is critical for the Cryogenic Dark Matter Search (CDMS experiment to further optimize its detectors to directly search for dark matter. An initial study with Al films was undertaken by our group ~ 20 years ago, but some important questions were not answered at the time. This thesis can be considered a continuation of that critical study. The CDMS experiment utilizes high purity silicon and germanium crystals to simultaneously measure ionization and phonons created by particle interactions. In addition to describing some of the rich physics involved in simultaneously detecting ionization and phonons with a CDMS detector, this thesis focuses on the detailed physics of the phonon sensors themselves, which are patterned onto CDMS detector surfaces. CDMS detectors use thin sputtered Al films to collect phonon energy when it propagates to the surfaces of the detector crystals. The phonon energy breaks Cooper pairs and creates quasiparticles (qps). These qps diffuse until they get trapped in an proximitized “overlap” region where lower-Tc tungsten films connect to the Al film. These tungsten films are the transition edge sensors (W-TESs CDMS uses to readout phonon signals. We performed a wide range of experiments using several sets of test devices designed and fabricated specifically for this work. The devices were used mostly to study quasiparticle (qp transport in Al films and qp transmission through Al/W interfaces. The results of this work are being used to optimize the design of detectors for SuperCDMS SNOLAB. This thesis is intended for CDMS collaborators who are interested in knowing more about the detailed fundamentals of how our phonon sensors work so they can take full advantage of their benefits. However, this work can also be read by general readers who are interested in particle detection using TES technology. This thesis contains eight chapters. The

  6. Phonon optimized interatomic potential for aluminum

    Science.gov (United States)

    Muraleedharan, Murali Gopal; Rohskopf, Andrew; Yang, Vigor; Henry, Asegun

    2017-12-01

    We address the problem of generating a phonon optimized interatomic potential (POP) for aluminum. The POP methodology, which has already been shown to work for semiconductors such as silicon and germanium, uses an evolutionary strategy based on a genetic algorithm (GA) to optimize the free parameters in an empirical interatomic potential (EIP). For aluminum, we used the Vashishta functional form. The training data set was generated ab initio, consisting of forces, energy vs. volume, stresses, and harmonic and cubic force constants obtained from density functional theory (DFT) calculations. Existing potentials for aluminum, such as the embedded atom method (EAM) and charge-optimized many-body (COMB3) potential, show larger errors when the EIP forces are compared with those predicted by DFT, and thus they are not particularly well suited for reproducing phonon properties. Using a comprehensive Vashishta functional form, which involves short and long-ranged interactions, as well as three-body terms, we were able to better capture interactions that reproduce phonon properties accurately. Furthermore, the Vashishta potential is flexible enough to be extended to Al2O3 and the interface between Al-Al2O3, which is technologically important for combustion of solid Al nano powders. The POP developed here is tested for accuracy by comparing phonon thermal conductivity accumulation plots, density of states, and dispersion relations with DFT results. It is shown to perform well in molecular dynamics (MD) simulations as well, where the phonon thermal conductivity is calculated via the Green-Kubo relation. The results are within 10% of the values obtained by solving the Boltzmann transport equation (BTE), employing Fermi's Golden Rule to predict the phonon-phonon relaxation times.

  7. Phonon optimized interatomic potential for aluminum

    Directory of Open Access Journals (Sweden)

    Murali Gopal Muraleedharan

    2017-12-01

    Full Text Available We address the problem of generating a phonon optimized interatomic potential (POP for aluminum. The POP methodology, which has already been shown to work for semiconductors such as silicon and germanium, uses an evolutionary strategy based on a genetic algorithm (GA to optimize the free parameters in an empirical interatomic potential (EIP. For aluminum, we used the Vashishta functional form. The training data set was generated ab initio, consisting of forces, energy vs. volume, stresses, and harmonic and cubic force constants obtained from density functional theory (DFT calculations. Existing potentials for aluminum, such as the embedded atom method (EAM and charge-optimized many-body (COMB3 potential, show larger errors when the EIP forces are compared with those predicted by DFT, and thus they are not particularly well suited for reproducing phonon properties. Using a comprehensive Vashishta functional form, which involves short and long-ranged interactions, as well as three-body terms, we were able to better capture interactions that reproduce phonon properties accurately. Furthermore, the Vashishta potential is flexible enough to be extended to Al2O3 and the interface between Al-Al2O3, which is technologically important for combustion of solid Al nano powders. The POP developed here is tested for accuracy by comparing phonon thermal conductivity accumulation plots, density of states, and dispersion relations with DFT results. It is shown to perform well in molecular dynamics (MD simulations as well, where the phonon thermal conductivity is calculated via the Green-Kubo relation. The results are within 10% of the values obtained by solving the Boltzmann transport equation (BTE, employing Fermi’s Golden Rule to predict the phonon-phonon relaxation times.

  8. Renormalized Phonon Microstructures at High Temperatures from First-Principles Calculations: Methodologies and Applications in Studying Strong Anharmonic Vibrations of Solids

    Directory of Open Access Journals (Sweden)

    Tian Lan

    2016-01-01

    Full Text Available While the vibrational thermodynamics of materials with small anharmonicity at low temperatures has been understood well based on the harmonic phonons approximation, at high temperatures, this understanding must accommodate how phonons interact with other phonons or with other excitations. To date the anharmonic lattice dynamics is poorly understood despite its great importance, and most studies still rely on the quasiharmonic approximations. We shall see that the phonon-phonon interactions give rise to interesting coupling problems and essentially modify the equilibrium and nonequilibrium properties of materials, for example, thermal expansion, thermodynamic stability, heat capacity, optical properties, thermal transport, and other nonlinear properties of materials. The review aims to introduce some recent developements of computational methodologies that are able to efficiently model the strong phonon anharmonicity based on quantum perturbation theory of many-body interactions and first-principles molecular dynamics simulations. The effective potential energy surface of renormalized phonons and structures of the phonon-phonon interaction channels can be derived from these interdependent methods, which provide both macroscopic and microscopic perspectives in analyzing the strong anharmonic phenomena while the traditional harmonic models fail dramatically. These models have been successfully performed in the studies on the temperature-dependent broadenings of Raman and neutron scattering spectra, high temperature phase stability, and negative thermal expansion of rutile and cuprite structures, for example.

  9. Cross-calibration of Medium Resolution Earth Observing Satellites by Using EO-1 Hyperion-derived Spectral Surface Reflectance from "Lunar Cal Sites"

    Science.gov (United States)

    Ungar, S.

    2017-12-01

    Over the past 3 years, the Earth Observing-one (EO-1) Hyperion imaging spectrometer was used to slowly scan the lunar surface at a rate which results in up to 32X oversampling to effectively increase the SNR. Several strategies, including comparison against the USGS RObotic Lunar Observatory (ROLO) mode,l are being employed to estimate the absolute and relative accuracy of the measurement set. There is an existing need to resolve discrepancies as high as 10% between ROLO and solar based calibration of current NASA EOS assets. Although the EO-1 mission was decommissioned at the end of March 2017, the development of a well-characterized exoatmospheric spectral radiometric database, for a range of lunar phase angles surrounding the fully illuminated moon, continues. Initial studies include a comprehensive analysis of the existing 17-year collection of more than 200 monthly lunar acquisitions. Specific lunar surface areas, such as a lunar mare, are being characterized as potential "lunar calibration sites" in terms of their radiometric stability in the presence of lunar nutation and libration. Site specific Hyperion-derived lunar spectral reflectance are being compared against spectrographic measurements made during the Apollo program. Techniques developed through this activity can be employed by future high-quality orbiting imaging spectrometers (such as HyspIRI and EnMap) to further refine calibration accuracies. These techniques will enable the consistent cross calibration of existing and future earth observing systems (spectral and multi-spectral) including those that do not have lunar viewing capability. When direct lunar viewing is not an option for an earth observing asset, orbiting imaging spectrometers can serve as transfer radiometers relating that asset's sensor response to lunar values through near contemporaneous observations of well characterized stable CEOS test sites. Analysis of this dataset will lead to the development of strategies to ensure more

  10. Phonon Raman spectra of colloidal CdTe nanocrystals: effect of size, non-stoichiometry and ligand exchange

    Directory of Open Access Journals (Sweden)

    Lokteva Irina

    2011-01-01

    Full Text Available Abstract Resonant Raman study reveals the noticeable effect of the ligand exchange on the nanocrystal (NC surface onto the phonon spectra of colloidal CdTe NC of different size and composition. The oleic acid ligand exchange for pyridine ones was found to change noticeably the position and width of the longitudinal optical (LO phonon mode, as well as its intensity ratio to overtones. The broad shoulder above the LO peak frequency was enhanced and sharpened after pyridine treatment, as well as with decreasing NC size. The low-frequency mode around 100 cm-1 which is commonly related with the disorder-activated acoustical phonons appears in smaller NCs but is not enhanced after pyridine treatment. Surprisingly, the feature at low-frequency shoulder of the LO peak, commonly assigned to the surface optical phonon mode, was not sensitive to ligand exchange and concomitant close packing of the NCs. An increased structural disorder on the NC surface, strain and modified electron-phonon coupling is discussed as the possible reason of the observed changes in the phonon spectrum of ligand-exchanged CdTe NCs. PACS: 63.20.-e, 78.30.-j, 78.67.-n, 78.67.Bf

  11. Ionizing particle detection based on phononic crystals

    Energy Technology Data Exchange (ETDEWEB)

    Aly, Arafa H., E-mail: arafa16@yahoo.com, E-mail: arafa.hussien@science.bsu.edu.eg; Mehaney, Ahmed; Eissa, Mostafa F. [Physics Department, Faculty of Science, Beni-Suef University, Beni-Suef (Egypt)

    2015-08-14

    Most conventional radiation detectors are based on electronic or photon collections. In this work, we introduce a new and novel type of ionizing particle detector based on phonon collection. Helium ion radiation treats tumors with better precision. There are nine known isotopes of helium, but only helium-3 and helium-4 are stable. Helium-4 is formed in fusion reactor technology and in enormous quantities during Big Bang nucleo-synthesis. In this study, we introduce a technique for helium-4 ion detection (sensing) based on the innovative properties of the new composite materials known as phononic crystals (PnCs). PnCs can provide an easy and cheap technique for ion detection compared with conventional methods. PnC structures commonly consist of a periodic array of two or more materials with different elastic properties. The two materials are polymethyl-methacrylate and polyethylene polymers. The calculations showed that the energies lost to target phonons are maximized at 1 keV helium-4 ion energy. There is a correlation between the total phonon energies and the transmittance of PnC structures. The maximum transmission for phonons due to the passage of helium-4 ions was found in the case of making polyethylene as a first layer in the PnC structure. Therefore, the concept of ion detection based on PnC structure is achievable.

  12. Spectral Assessment of Soil Properties: Standoff Quantification of Soil Organic Matter Content in Surface Mineral Soils and Alaskan Peat

    Science.gov (United States)

    2017-08-01

    All product names and trademarks cited are the property of their respective owners . The findings of this report are not to be construed as an official...350°C to remove the organic component, and then reanalyzed. The resulting spectral subtraction, initial minus com- busted, in theory would exhibit an...determine the change in mass as a sample is heated, monitor this change over time, and obtain spectra of compounds as they are volatilized. In theory

  13. Effects of elastic anisotropy in phononic band-gap plates with two-dimensional lattices

    International Nuclear Information System (INIS)

    Hsu, Jin-Chen

    2013-01-01

    This study presents the effects of elastic anisotropy of constituent materials in square-lattice phononic-crystal plates. Using general elastodynamic calculations and the finite element (FE) method, this study analyses phononic-crystal plates constituted by (1) anisotropic scatterers embedded in an epoxy plate and (2) air holes etched on an anisotropic plate. The full band gaps can be modulated, opened and closed by changing the orientation of the square lattice relative to the crystallographic coordinate system of the anisotropic materials, and the elastic anisotropy varies the dispersion curves of the phononic-crystal plate waves with the rotation of the square lattice. Acoustic power transmission calculations show incident plate mode-dependent spectral gaps, the appearances of which in the frequency spectrum can also be modulated and shifted using elastic anisotropy. The effects of elastic anisotropy demonstrated here enable tailoring frequency band gaps and dispersion curves for functional control of acoustic-wave energy flows in phononic-crystal plates. Applications include acoustic waveguiding, confining, self-collimating and perfect acoustic focusing.

  14. Phonon focusing and electron–phonon drag in semiconductor crystals with degenerate charge-carrier statistics

    Energy Technology Data Exchange (ETDEWEB)

    Kuleyev, I. G., E-mail: kuleev@imp.uran.ru; Kuleyev, I. I.; Bakharev, S. M.; Ustinov, V. V. [Russian Academy of Sciences, Institute of Metal Physics, Ural Branch (Russian Federation)

    2016-09-15

    We study the effect of anisotropy in elastic properties on the electron–phonon drag and thermoelectric phenomena in gapless semiconductors with degenerate charge-carrier statistics. It is shown that phonon focusing leads to a number of new effects in the drag thermopower at low temperatures, when diffusive phonon scattering from the boundaries is the predominant relaxation mechanism. We analyze the effect of phonon focusing on the dependences of the thermoelectromotive force (thermopower) in HgSe:Fe crystals on geometric parameters and the heat-flow directions relative to the crystal axes in the Knudsen regime of the phonon gas flow. The crystallographic directions that ensure the maximum and minimum values of the thermopower are determined and the role of quasi-longitudinal and quasi-transverse phonons in the drag thermopower in HgSe:Fe crystals at low temperatures is analyzed. It is shown that the main contribution to the drag thermopower comes from slow quasi-transverse phonons in the directions of focusing in long samples.

  15. Ab initio phonon dispersions of face centered cubic Pb: effects of spin-orbit coupling

    International Nuclear Information System (INIS)

    Dal Corso, Andrea

    2008-01-01

    I present the ab initio phonon dispersions of face centered cubic Pb calculated within the framework of density functional perturbation theory, with plane waves and a fully relativistic ultrasoft pseudopotential which includes spin-orbit coupling effects. I find that, within the local density approximation, the theory gives phonon frequencies close to the experimental inelastic neutron scattering data. Many of the anomalies present in these dispersions are well reproduced by the fully relativistic pseudopotential theory and can be shown to appear only for small values of the smearing parameter that controls the sharpness of the Fermi surface.

  16. Electron and phonon transport in silicon nanowires: Atomistic approach to thermoelectric properties

    DEFF Research Database (Denmark)

    Markussen, Troels; Jauho, Antti-Pekka; Brandbyge, Mads

    2009-01-01

    vacancies. It is shown that the average phonon and electron transmissions through long SiNWs containing many vacancies can be accurately estimated from the scattering properties of the isolated vacancies using a recently proposed averaging method [Markussen et al., Phys. Rev. Lett. 99, 076803 (2007)]. We...... apply this averaging method to surface disordered SiNWs in the diameter range of 1–3 nm to compute the thermoelectric figure of merit ZT. It is found that the phonon transmission is affected more by the vacancies than the electronic transmission leading to an increased thermoelectric performance...

  17. The effect of n- and p-type doping on coherent phonons in GaN

    Science.gov (United States)

    Ishioka, Kunie; Kato, Keiko; Ohashi, Naoki; Haneda, Hajime; Kitajima, Masahiro; Petek, Hrvoje

    2013-05-01

    The effect of doping on the carrier-phonon interaction in wurtzite GaN is investigated by pump-probe reflectivity measurements using 3.1 eV light in near resonance with the fundamental band gap of 3.39 eV. Coherent modulations of the reflectivity due to the E2 and A1(LO) modes, as well as the 2A1(LO) overtone are observed. Doping of acceptor and donor atoms enhances the dephasing of the polar A1(LO) phonon via coupling with plasmons, with the effect of donors being stronger. Doping also enhances the relative amplitude of the coherent A1(LO) phonon with respect to that of the high-frequency E2 phonon, though it does not affect the relative intensity in Raman spectroscopic measurements. We attribute this enhanced coherent amplitude to the transient depletion field screening (TDFS) excitation mechanism, which, in addition to impulsive stimulated Raman scattering (ISRS), contributes to the generation of coherent polar phonons even for sub-band gap excitation. Because the TDFS mechanism requires photoexcitation of carriers, we argue that the interband transition is made possible at a surface with photon energies below the bulk band gap through the Franz-Keldysh effect.

  18. Phonon dispersion models for MgB2 with application of pressure

    Science.gov (United States)

    Alarco, Jose A.; Talbot, Peter C.; Mackinnon, Ian D. R.

    2017-05-01

    We evaluate, via the Local Density and the Generalised Gradient Approximations to the Density Functional Theory (DFT), the change in form and extent of the E2g phonon anomaly of MgB2 with increase in applied pressure up to 20 GPa. Ab initio DFT calculations on the phonon dispersion (PD) for MgB2 show a phonon anomaly symmetrically displaced around Γ, the reciprocal lattice origin. This anomaly is related to nesting between diametrically opposite sides of tubular elements of Fermi surfaces, which correspond to sigma bonding and run approximately parallel to the Γ-A reciprocal space direction. The anomaly is parallel to Γ-A and along Γ-M and Γ-K. The extent of the E2g phonon anomaly, δ, along Γ-M and Γ-K is a measure of the thermal energy, Tδ, that matches within error the experimental onset superconducting transition temperature, Tc. Ab initio DFT calculations with pressure for -5 GPa mediated superconductors with AlB2-type structures, the thermal energy of the phonon anomaly, Tδ, is a reliable predictor of Tc.

  19. Phonon tunneling through a double barrier system

    Energy Technology Data Exchange (ETDEWEB)

    Villegas, Diosdado [Departamento de Física, Universidad Central “Marta Abreu” de Las Villas, CP 54830, Santa Clara, Villa Clara (Cuba); Instituto de Física, Universidad Autónoma de Puebla, 18 Sur y San Claudio, Edif. 110A, Ciudad Universitaria, 72570 Puebla (Mexico); León-Pérez, Fernando de [Centro Universitario de la Defensa de Zaragoza, Ctra. de Huesca s/n, E-50090 Zaragoza (Spain); Pérez-Álvarez, R. [Universidad Autónoma del Estado de Morelos, Av. Universidad 1001, CP 62209 Cuernavaca (Mexico); Arriaga, J., E-mail: arriaga@ifuap.buap.mx [Instituto de Física, Universidad Autónoma de Puebla, 18 Sur y San Claudio, Edif. 110A, Ciudad Universitaria, 72570 Puebla (Mexico)

    2015-04-15

    The tunneling of optical and acoustic phonons at normal incidence on a double-barrier is studied in this paper. Transmission coefficients and resonance conditions are derived theoretically under the assumption that the long-wavelength approximation is valid. It is shown that the behavior of the transmission coefficients for the symmetric double barrier has a Lorentzian form close to resonant frequencies and that Breit–Wigner's formula have a general validity in one-dimensional phonon tunneling. Authors also study the so-called generalized Hartman effect in the tunneling of long-wavelength phonons and show that this effect is a numerical artifact resulting from taking the opaque limit before exploring the variation with a finite barrier width. This study could be useful for the design of acoustic devices.

  20. Phonon tunneling through a double barrier system

    International Nuclear Information System (INIS)

    Villegas, Diosdado; León-Pérez, Fernando de; Pérez-Álvarez, R.; Arriaga, J.

    2015-01-01

    The tunneling of optical and acoustic phonons at normal incidence on a double-barrier is studied in this paper. Transmission coefficients and resonance conditions are derived theoretically under the assumption that the long-wavelength approximation is valid. It is shown that the behavior of the transmission coefficients for the symmetric double barrier has a Lorentzian form close to resonant frequencies and that Breit–Wigner's formula have a general validity in one-dimensional phonon tunneling. Authors also study the so-called generalized Hartman effect in the tunneling of long-wavelength phonons and show that this effect is a numerical artifact resulting from taking the opaque limit before exploring the variation with a finite barrier width. This study could be useful for the design of acoustic devices

  1. Electrical resistivity due to electron-phonon scattering in thin gadolinium films

    International Nuclear Information System (INIS)

    Urbaniak-Kucharczyk, A.

    1988-01-01

    The contribution to the electrical resistivity due to the electron-phonon scattering for the special case of h.c.p. structure is derived. The numerical results obtained for the case of polycrystalline gadolinum films show the resistivity dependence on the film thickness and the surface properties. (author)

  2. Nonequilibrium phonon effects in midinfrared quantum cascade lasers

    Energy Technology Data Exchange (ETDEWEB)

    Shi, Y. B., E-mail: yshi9@wisc.edu; Knezevic, I., E-mail: knezevic@engr.wisc.edu [Department of Electrical and Computer Engineering, University of Wisconsin-Madison, Madison, Wisconsin 53706-1691 (United States)

    2014-09-28

    We investigate the effects of nonequilibrium phonon dynamics on the operation of a GaAs-based midinfrared quantum cascade laser over a range of temperatures (77–300 K) via a coupled ensemble Monte Carlo simulation of electron and optical-phonon systems. Nonequilibrium phonon effects are shown to be important below 200 K. At low temperatures, nonequilibrium phonons enhance injection selectivity and efficiency by drastically increasing the rate of interstage electron scattering from the lowest injector state to the next-stage upper lasing level via optical-phonon absorption. As a result, the current density and modal gain at a given field are higher and the threshold current density lower and considerably closer to experiment than results obtained with thermal phonons. By amplifying phonon absorption, nonequilibrium phonons also hinder electron energy relaxation and lead to elevated electronic temperatures.

  3. Toward quantitative modeling of silicon phononic thermocrystals

    Energy Technology Data Exchange (ETDEWEB)

    Lacatena, V. [STMicroelectronics, 850, rue Jean Monnet, F-38926 Crolles (France); IEMN UMR CNRS 8520, Institut d' Electronique, de Microélectronique et de Nanotechnologie, Avenue Poincaré, F-59652 Villeneuve d' Ascq (France); Haras, M.; Robillard, J.-F., E-mail: jean-francois.robillard@isen.iemn.univ-lille1.fr; Dubois, E. [IEMN UMR CNRS 8520, Institut d' Electronique, de Microélectronique et de Nanotechnologie, Avenue Poincaré, F-59652 Villeneuve d' Ascq (France); Monfray, S.; Skotnicki, T. [STMicroelectronics, 850, rue Jean Monnet, F-38926 Crolles (France)

    2015-03-16

    The wealth of technological patterning technologies of deca-nanometer resolution brings opportunities to artificially modulate thermal transport properties. A promising example is given by the recent concepts of 'thermocrystals' or 'nanophononic crystals' that introduce regular nano-scale inclusions using a pitch scale in between the thermal phonons mean free path and the electron mean free path. In such structures, the lattice thermal conductivity is reduced down to two orders of magnitude with respect to its bulk value. Beyond the promise held by these materials to overcome the well-known “electron crystal-phonon glass” dilemma faced in thermoelectrics, the quantitative prediction of their thermal conductivity poses a challenge. This work paves the way toward understanding and designing silicon nanophononic membranes by means of molecular dynamics simulation. Several systems are studied in order to distinguish the shape contribution from bulk, ultra-thin membranes (8 to 15 nm), 2D phononic crystals, and finally 2D phononic membranes. After having discussed the equilibrium properties of these structures from 300 K to 400 K, the Green-Kubo methodology is used to quantify the thermal conductivity. The results account for several experimental trends and models. It is confirmed that the thin-film geometry as well as the phononic structure act towards a reduction of the thermal conductivity. The further decrease in the phononic engineered membrane clearly demonstrates that both phenomena are cumulative. Finally, limitations of the model and further perspectives are discussed.

  4. Controlling competing orders via nonequilibrium acoustic phonons: Emergence of anisotropic effective electronic temperature

    Science.gov (United States)

    Schütt, Michael; Orth, Peter P.; Levchenko, Alex; Fernandes, Rafael M.

    2018-01-01

    Ultrafast perturbations offer a unique tool to manipulate correlated systems due to their ability to promote transient behaviors with no equilibrium counterpart. A widely employed strategy is the excitation of coherent optical phonons, as they can cause significant changes in the electronic structure and interactions on short time scales. One of the issues, however, is the inevitable heating that accompanies these resonant excitations. Here, we explore a promising alternative route: the nonequilibrium excitation of acoustic phonons, which, due to their low excitation energies, generally lead to less heating. We demonstrate that driving acoustic phonons leads to the remarkable phenomenon of a momentum-dependent effective temperature, by which electronic states at different regions of the Fermi surface are subject to distinct local temperatures. Such an anisotropic effective electronic temperature can have a profound effect on the delicate balance between competing ordered states in unconventional superconductors, opening a so far unexplored avenue to control correlated phases.

  5. Direct correlation of observed phonon anomalies and maxima in the generalized susceptibilities of transition metal carbides

    International Nuclear Information System (INIS)

    Gupta, M.J.; Freeman, A.B.

    1976-01-01

    The generalized susceptibility, chi(q), of both NbC and TaC determined from APW energy band calculations show large maxima to occur at precisely those q/sub max/ values at which soft phonon modes were observed by Smith. Maxima in chi(q) are predicted for other directions. The locus of these q/sub max/ values can be represented by a warped cube of dimension approximately 1.2(2π/a) in momentum space--in striking agreement with the soft mode surface proposed phenomenologically by Weber. In sharp contrast, the chi(q) calculated for both ZrC and HfC--for which no phonon anomalies have been observed--fall off in all symmetry directions away from the zone center. The phonon anomalies in the transition metal carbides are thus interpreted as due to an ''overscreening'' effect resulting from an anomalous increase of the response function of the conduction electrons

  6. Self-consistency in the phonon space of the particle-phonon coupling model

    Science.gov (United States)

    Tselyaev, V.; Lyutorovich, N.; Speth, J.; Reinhard, P.-G.

    2018-04-01

    In the paper the nonlinear generalization of the time blocking approximation (TBA) is presented. The TBA is one of the versions of the extended random-phase approximation (RPA) developed within the Green-function method and the particle-phonon coupling model. In the generalized version of the TBA the self-consistency principle is extended onto the phonon space of the model. The numerical examples show that this nonlinear version of the TBA leads to the convergence of results with respect to enlarging the phonon space of the model.

  7. Phonon dispersion curves for CsCN

    International Nuclear Information System (INIS)

    Gaur, N.K.; Singh, Preeti; Rini, E.G.; Galgale, Jyostna; Singh, R.K.

    2004-01-01

    The motivation for the present work was gained from the recent publication on phonon dispersion curves (PDCs) of CsCN from the neutron scattering technique. We have applied the extended three-body force shell model (ETSM) by incorporating the effect of coupling between the translation modes and the orientation of cyanide molecules for the description of phonon dispersion curves of CsCN between the temperatures 195 and 295 K. Our results on PDCs in symmetric direction are in good agreement with the experimental data measured with inelastic neutron scattering technique. (author)

  8. Microscopic model of a phononic refrigerator

    Science.gov (United States)

    Arrachea, Liliana; Mucciolo, Eduardo R.; Chamon, Claudio; Capaz, Rodrigo B.

    2012-09-01

    We analyze a simple microscopic model to pump heat from a cold to a hot reservoir in a nanomechanical system. The model consists of a one-dimensional chain of masses and springs coupled to a back gate through which a time-dependent perturbation is applied. The action of the gate creates a moving phononic barrier by locally pinning a mass. We solve the problem numerically using a nonequilibrium Green's function technique. For low driving frequencies and for sharp traveling barriers, we show that this microscopic model realizes a phonon refrigerator.

  9. Phonon emission in a degenerate semiconductor at low lattice temperatures

    International Nuclear Information System (INIS)

    Midday, S.; Nag, S.; Bhattacharya, D.P.

    2015-01-01

    The characteristics of phonon growth in a degenerate semiconductor at low lattice temperatures have been studied for inelastic interaction of non-equilibrium electrons with the intravalley acoustic phonons. The energy of the phonon and the full form of the phonon distribution are taken into account. The results reveal significant changes in the growth characteristics compared to the same for a non-degenerate material

  10. A step closer to visualizing the electron___phonon interplay

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Y.L.; Lee, W.S.; Shen, Z.X.; /Stanford U., Appl. Phys. Dept. /Stanford U., Phys. Dept. /SLAC, PULSE

    2011-01-04

    , Carbone et al. found that the c-axis phonons in the optimally-doped Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8} (Bi2212) are coupled to the electrons with different strength along different directions within the CuO{sub 2} plane. The coupling strength reaches its largest value along the 2 Cu-O bond directions and becomes the weakest along the bisector of the angle formed by the 2 Cu-O bonds. As pointed out by Carbone et al., these observations agree well with the calculated coupling strength between electrons and the buckling phonons. Furthermore, their observation of this anisotropic electron-phonon coupling also agrees with results from angle-resolved photoemission (ARPES), which measures the equilibrium-state properties of materials. In ARPES measurements, electron-phonon coupling manifests itself as a kink anomaly in the band dispersion and a corresponding sudden broadening in the spectral width.

  11. Goldstone-like phonon modes in a (111)-strained perovskite

    Science.gov (United States)

    Marthinsen, A.; Griffin, S. M.; Moreau, M.; Grande, T.; Tybell, T.; Selbach, S. M.

    2018-01-01

    Goldstone modes are massless particles resulting from spontaneous symmetry breaking. Although such modes are found in elementary particle physics as well as in condensed-matter systems like superfluid helium, superconductors, and magnons, structural Goldstone modes are rare. Epitaxial strain in thin films can induce structures and properties not accessible in bulk and has been intensively studied for (001)-oriented perovskite oxides. Here we predict Goldstone-like phonon modes in (111)-strained SrMn O3 by first-principles calculations. Under compressive strain the coupling between two in-plane rotational instabilities gives rise to a Mexican hat-shaped energy surface characteristic of a Goldstone mode. Conversely, large tensile strain induces in-plane polar instabilities with no directional preference, giving rise to a continuous polar ground state. Such phonon modes with U (1) symmetry could emulate structural condensed-matter Higgs modes. The mass of this Higgs boson, given by the shape of the Mexican hat energy surface, can be tuned by strain through proper choice of substrate.

  12. Numerical studies of backscattering enhancement of electromagnetic waves from two-dimensional random rough surfaces with the forward-backward/novel spectral acceleration method.

    Science.gov (United States)

    Torrungrueng, D; Johnson, J T

    2001-10-01

    The forward-backward method with a novel spectral acceleration algorithm (FB/NSA) has been shown to be a highly efficient O(Ntot) iterative method of moments, where Ntot is the total number of unknowns to be solved, for the computation of electromagnetic (EM) wave scattering from both one-dimensional and two-dimensional (2-D) rough surfaces. The efficiency of the method makes studies of backscattering enhancement from moderately rough impedance surfaces at large incident angles tractable. Variations in the characteristics of backscattering enhancement with incident angle, surface impedance, polarization, and surface statistics are investigated by use of the 2-D FB/NSA method combined with parallel computing techniques. The surfaces considered are Gaussian random processes with an isotropic Gaussian spectrum and root-mean-square surface heights and slopes ranging from 0.5 lambda to lambda and from 0.5 to 1.0, respectively, where lambda is the EM wavelength in free space. Incident angles ranging from normal incidence up to 70 degrees are considered in this study. It is found that backscattering enhancement depends strongly on all parameters of interest. America

  13. Electron-phonon heat exchange in quasi-two-dimensional nanolayers

    Science.gov (United States)

    Anghel, Dragos-Victor; Cojocaru, Sergiu

    2017-12-01

    We study the heat power P transferred between electrons and phonons in thin metallic films deposited on free-standing dielectric membranes. The temperature range is typically below 1 K, such that the wavelengths of the excited phonon modes in the system is large enough so that the picture of a quasi-two-dimensional phonon gas is applicable. Moreover, due to the quantization of the components of the electron wavevectors perpendicular to the metal film's surface, the electrons spectrum forms also quasi two-dimensional sub-bands, as in a quantum well (QW). We describe in detail the contribution to the electron-phonon energy exchange of different electron scattering channels, as well as of different types of phonon modes. We find that heat flux oscillates strongly with thickness of the film d while having a much smoother variation with temperature (Te for the electrons temperature and Tph for the phonons temperature), so that one obtains a ridge-like landscape in the two coordinates, (d, Te) or (d, Tph), with crests and valleys aligned roughly parallel to the temperature axis. For the valley regions we find P ∝ Te3.5 - Tph3.5. From valley to crest, P increases by more than one order of magnitude and on the crests P cannot be represented by a simple power law. The strong dependence of P on d is indicative of the formation of the QW state and can be useful in controlling the heat transfer between electrons and crystal lattice in nano-electronic devices. Nevertheless, due to the small value of the Fermi wavelength in metals, the surface imperfections of the metallic films can reduce the magnitude of the oscillations of P vs. d, so this effect might be easier to observe experimentally in doped semiconductors.

  14. Optical pumping of hot phonons in GaAs

    International Nuclear Information System (INIS)

    Collins, C.L.; Yu, P.Y.

    1982-01-01

    Optical pumping of hot LO phonons in GaAs has been studied as a function of the excitation photon frequency. The experimental results are in good agreement with a model calculation which includes both inter- and intra-valley electron-phonon scatterings. The GAMMA-L and GAMMA-X intervalley electron-phonon interactions in GaAs have been estimated

  15. Simulations of a spectral gamma-ray logging tool response to a surface source distribution on the borehole wall

    International Nuclear Information System (INIS)

    Wilson, R.D.; Conaway, J.G.

    1991-01-01

    We have developed Monte Carlo and discrete ordinates simulation models for the large-detector spectral gamma-ray (SGR) logging tool in use at the Nevada Test Site. Application of the simulation models produced spectra for source layers on the borehole wall, either from potassium-bearing mudcakes or from plate-out of radon daughter products. Simulations show that the shape and magnitude of gamma-ray spectra from sources distributed on the borehole wall depend on radial position with in the air-filled borehole as well as on hole diameter. No such dependence is observed for sources uniformly distributed in the formation. In addition, sources on the borehole wall produce anisotropic angular fluxes at the higher scattered energies and at the source energy. These differences in borehole effects and in angular flux are important to the process of correcting SGR logs for the presence of potassium mudcakes; they also suggest a technique for distinguishing between spectral contributions from formation sources and sources on the borehole wall. These results imply the existence of a standoff effect not present for spectra measured in air-filled boreholes from formation sources. 5 refs., 11 figs

  16. Spectral detection of near-surface moisture content and water-table position in northern peatland ecosystems

    Science.gov (United States)

    Karl M. Meingast; Michael J. Falkowski; Evan S. Kane; Lynette R. Potvin; Brian W. Benscoter; Alistair M.S. Smith; Laura L. Bourgeau-Chavez; Mary Ellen. Miller

    2014-01-01

    Wildland fire occurrence has been increasing in peatland ecosystems during recent decades. As such, there is a need for broadly applicable tools to detect and monitor controls on combustion such as surface peat moisture and water-table position. A field portable spectroradiometer was used to measure surface reflectance of two Sphagnum moss-dominated...

  17. Phonon dispersion curves of CsCN

    Indian Academy of Sciences (India)

    Abstract. The motivation for the present work was gained from the recent publication on phonon dispersion curves (PDCs) of CsCN from the neutron scattering technique. We have applied the extended three-body force shell model (ETSM) by incorporating the effect of coupling between the translation modes and the ...

  18. Hydrodynamic states of phonons in insulators

    Directory of Open Access Journals (Sweden)

    S.A. Sokolovsky

    2012-12-01

    Full Text Available The Chapman-Enskog method is generalized for accounting the effect of kinetic modes on hydrodynamic evolution. Hydrodynamic states of phonon system of insulators have been studied in a small drift velocity approximation. For simplicity, the investigation was carried out for crystals of the cubic class symmetry. It has been found that in phonon hydrodynamics, local equilibrium is violated even in the approximation linear in velocity. This is due to the absence of phonon momentum conservation law that leads to a drift velocity relaxation. Phonon hydrodynamic equations which take dissipative processes into account have been obtained. The results were compared with the standard theory based on the local equilibrium validity. Integral equations have been obtained for calculating the objects of the theory (including viscosity and heat conductivity. It has been shown that in low temperature limit, these equations are solvable by iterations. Steady states of the system have been considered and an expression for steady state heat conductivity has been obtained. It coincides with the famous result by Akhiezer in the leading low temperature approximation. It has been established that temperature distribution in the steady state of insulator satisfies a condition of heat source absence.

  19. Phonon dispersion relation of liquid metals

    Indian Academy of Sciences (India)

    Abstract. The phonon dispersion curves of some liquid metals, viz. Na (Z = 1), Mg. (Z = 2), Al (Z = 3) and Pb (Z = 4), have been computed using our model potential. The charged hard sphere (CHS) reference system is applied to describe the structural information. Our model potential along with CHS reference system is ...

  20. Time and momentum-resolved phonon decay

    Science.gov (United States)

    Reis, David

    2017-04-01

    The high brightness of x-ray free-electron lasers provides us a unique opportunity to measure lattice dynamics directly in the time domain and out of equilibrium. As a first step in this direction we demonstrate how ultrafast optical excitation creates temporal coherences in the mean-square phonon displacements spanning the Brillouin zone by a second-order squeezing process. This leads to broad-bandwidth high-resolution measurements of the phonon dispersion without the need for high-resolution monochromators or analyzers. We will also show how anharmonic phonon decay can be viewed as a parametric squeezing process, and present first momentum-resolved measurements of the downconversion of a coherent optical phonon into pairs of high-wavevector acoustic modes, information that cannot be obtained by spectroscopic measurements in the frequency domain. Supported by the Department of Energy, Office of Science, Basic Energy Sciences, Materials Sciences and Engineering Division, under Contract DE-AC02-76SF00515.

  1. Magnetic polarization and two-phonon states

    International Nuclear Information System (INIS)

    Tsoneva, N.; Stoyanov, Ch.; Grinberg, M.; Vdovin, A.

    1997-01-01

    Influence of magnetic core polarization on properties of 2 - member of two-phonon quintet of states 2 1 + x 3 1 - is analyzed. Like for recently identified lowest 1 - member of this quintet, an excitation probability of 2 - state is strongly affected by polarization of the nucleus

  2. Phonon density of states in nanocrystalline Fe

    Indian Academy of Sciences (India)

    Abstract. The Born–von Karman model is used to calculate phonon density of states (DOS) of nanocrystalline bcc Fe. It is found that there is an anisotropic stiffening in the interatomic force constants and hence there is shrinking in the nearest-neighbour distances in the nanophase. This leads to additional vibrational modes ...

  3. Phononic band gap structures as optimal designs

    DEFF Research Database (Denmark)

    Jensen, Jakob Søndergaard; Sigmund, Ole

    2003-01-01

    In this paper we use topology optimization to design phononic band gap structures. We consider 2D structures subjected to periodic loading and obtain the distribution of two materials with high contrast in material properties that gives the minimal vibrational response of the structure. Both in...

  4. Phonon affected transport through molecular quantum

    Czech Academy of Sciences Publication Activity Database

    Loos, Jan; Koch, T.; Alvermann, A.; Bishop, A. R.; Fehske, H.

    2009-01-01

    Roč. 21, č. 39 (2009), 395601/1-395601/18 ISSN 0953-8984 Institutional research plan: CEZ:AV0Z10100521 Keywords : quantum dots * electron - phonon interaction * polarons Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.964, year: 2009

  5. Phonon heat transport in gallium arsenide

    Indian Academy of Sciences (India)

    The energy linewidth is found to be an extremely sensitive quantity in the transport phenomena of crystalline solids as a collection of large number of scattering processes, namely, boundary scattering, impurity scattering, multiphonon scattering, interference scattering, electron–phonon processes and resonance scattering.

  6. Synthetic thermoelectric materials comprising phononic crystals

    Science.gov (United States)

    El-Kady, Ihab F; Olsson, Roy H; Hopkins, Patrick; Reinke, Charles; Kim, Bongsang

    2013-08-13

    Synthetic thermoelectric materials comprising phononic crystals can simultaneously have a large Seebeck coefficient, high electrical conductivity, and low thermal conductivity. Such synthetic thermoelectric materials can enable improved thermoelectric devices, such as thermoelectric generators and coolers, with improved performance. Such synthetic thermoelectric materials and devices can be fabricated using techniques that are compatible with standard microelectronics.

  7. Structure factors and phonon dispersion in liquid

    Indian Academy of Sciences (India)

    Technology and Engineering, M.S. University of Baroda, Vadodara 390 001, India. 2Electronics Department, Narmada College of Science and Commerce, Bharuch 392 011,. India. E-mail: apratapmsu@yahoo.com. Abstract. The phonon spectra for liquid Li and Na have been computed through the phenomenological model ...

  8. ``Forbidden'' phonon in the iron chalcogenide series

    Science.gov (United States)

    Fobes, David M.; Zaliznyak, Igor A.; Xu, Zhijun; Gu, Genda; Tranquada, John M.

    2015-03-01

    Recently, we uncovered evidence for the formation of a bond-order wave (BOW) leading to ferro-orbital order at low temperature, acting to stabilize the bicollinear AFM order, in the iron-rich parent compound, Fe1+yTe. Investigating the inelastic spectra centered near (100) in Fe1+yTe, a signature peak for the BOW formation in the monoclinic phase, we observed an acoustic phonon dispersion in both tetragonal and monoclinic phases. While a structural Bragg peak accompanies the mode in the monoclinic phase, in the tetragonal phase Bragg scattering at this Q is forbidden by symmetry, and we observed no elastic peak. This phonon mode was also observed in superconducting FeTe0.6Se0.4, where structural and magnetic transitions are suppressed. LDA frozen phonon calculations suggested that this mode could result from a spin imbalance between neighboring Fe atoms, but polarized neutron measurements revealed no additional magnetic scattering. We propose that this ``forbidden'' phonon mode may originate from dynamically broken symmetry, perhaps related to the strong dynamic spin correlations in these materials. Work at BNL was supported by BES, US DOE, under Contract No. DE-AC02-98CH10886. Research at ORNL's HFIR and SNS sponsored by Scientific User Facilities Division, BES, US DOE. We acknowledge the support of NIST, in providing neutron research facilities.

  9. Phonon scattering in graphene over substrate steps

    DEFF Research Database (Denmark)

    Sevincli, Haldun; Brandbyge, Mads

    2014-01-01

    We calculate the effect on phonon transport of substrate-induced bends in graphene. We consider bending induced by an abrupt kink in the substrate, and provide results for different step-heights and substrate interaction strengths. We find that individual substrate steps reduce thermal conductance...

  10. In situ determination of layer thickness and elastic moduli of asphalt pavement systems by spectral analysis of surface waves (SASW) method

    International Nuclear Information System (INIS)

    Mohd Azmi Ismail; Sri Atmaja Rosyidi; Abdul Rahim Samsudin; Abdul Ghani Rafek; Khairul Anuar Mohd Nayan

    2003-01-01

    Spectral analysis of surface waves (SASW) is a non-destructive and in situ method for determining the stiffness profile of soil and pavement sites. The method consists of generation, measurement, and processing of dispersive elastic waves in layered systems. The test is performed on the pavement surface at strain level below 0.001%, where the elastic properties are considered independent of strain amplitude. During an SASW test, the surface of the medium under investigation is subject to an impact to generate energy at various frequencies. Two vertical acceleration transducers are set up near the impact source to detect the energy transmitted through the testing media. By recording signals in digitised form using a data acquisition system and processing them, surface wave velocities can be determined by constructing a dispersion curve. Through forward modeling, the shear wave velocities can be obtained, which can be related to the variation of stiffness with depth. This paper presents the results of two case studies for near?surface profiling of two different asphalt pavement sites. (Author)

  11. Thermal transport across solid-solid interfaces enhanced by pre-interface isotope-phonon scattering

    Science.gov (United States)

    Lee, Eungkyu; Luo, Tengfei

    2018-01-01

    Thermal transport across solid interfaces can play critical roles in the thermal management of electronics. In this letter, we use non-equilibrium molecular dynamics simulations to investigate the isotope effect on the thermal transport across SiC/GaN interfaces. It is found that engineered isotopes (e.g., 10% 15N or 71Ga) in the GaN layer can increase the interfacial thermal conductance compared to the isotopically pure case by as much as 23%. Different isotope doping features, such as the isotope concentration, skin depth of the isotope region, and its distance from the interface, are investigated, and all of them lead to increases in thermal conductance. Studies of spectral temperatures of phonon modes indicate that interfacial thermal transport due to low-frequency phonons (transport. This work may provide insights into interfacial thermal transport and useful guidance to practical material design.

  12. Surface and interface electronic structure: Three year activity report

    International Nuclear Information System (INIS)

    Kevan, S.D.

    1992-01-01

    The 3-year activity report covers surface structure and phonon anomalies (surface reconstruction on W(001) and Mo(001), adsorbate lateral ordering, surface Fermi contours and phonon anomalies on Pt(111) and Pd(001)), adsorbate vibrational damping, charge transfer in momentum space: W(011)-K, surface states and resonances (relativistic effects ampersand computations, surface resonances)

  13. Strong Carrier–Phonon Coupling in Lead Halide Perovskite Nanocrystals

    Science.gov (United States)

    2017-01-01

    We highlight the importance of carrier–phonon coupling in inorganic lead halide perovskite nanocrystals. The low-temperature photoluminescence (PL) spectrum of CsPbBr3 has been investigated under a nonresonant and a nonstandard, quasi-resonant excitation scheme, and phonon replicas of the main PL band have been identified as due to the Fröhlich interaction. The energy of longitudinal optical (LO) phonons has been determined from the separation of the zero phonon band and phonon replicas. We reason that the observed LO phonon coupling can only be related to an orthorhombically distorted crystal structure of the perovskite nanocrystals. Additionally, the strength of carrier–phonon coupling has been characterized using the ratio between the intensities of the first phonon replica and the zero-phonon band. PL emission from localized versus delocalized carriers has been identified as the source of the observed discrepancies between the LO phonon energy and phonon coupling strength under quasi-resonant and nonresonant excitation conditions, respectively. PMID:29019652

  14. Phonon mechanism in the most dilute superconductor n-type SrTiO3.

    Science.gov (United States)

    Gor'kov, Lev P

    2016-04-26

    Superconductivity of n-doped SrTiO3, which remained enigmatic for half a century, is treated as a particular case of nonadiabatic phonon pairing. Motivated by experiment, we suggest the existence of the mobility edge at some dopant concentration. The itinerant part of the spectrum consists of three conduction bands filling by electrons successively. Each subband contributes to the superconducting instability and exhibits a gap in its energy spectrum at low temperatures. We argue that superconductivity of n-doped SrTiO3 results from the interaction of electrons with several longitudinal (LO) optical phonons with frequencies much larger than the Fermi energy. Immobile charges under the mobility edge threshold increase the "optical" dielectric constant far above that in clean SrTiO3 placing control on the electron-LO phonon interaction. TC initially grows as density of states at the Fermi surface increases with doping, but the accumulating charges reduce the electrons-polar-phonon interaction by screening the longitudinal electric fields. The theory predicts maxima in the TC-concentration dependence indeed observed experimentally. Having reached a maximum in the third band, the transition temperature finally decreases, rounding out the TC (n) dome, the three maxima with accompanying superconducting gaps emerging consecutively as electrons fill successive bands. This arises from attributes of the LO optical phonon pairing of electrons. The mechanism of LO phonons opens the path to increasing superconducting transition temperature in bulk transition-metal oxides and other polar crystals, and in charged 2D layers at the LaAaO3/SrTiO3 interfaces and on the SrTiO3 substrates.

  15. Effects of a piezoelectric substrate on phonon-drag thermopower in monolayer graphene

    Science.gov (United States)

    Bhargavi, K. S.; Kubakaddi, S. S.; Ford, C. J. B.

    2017-06-01

    The phonon-drag thermopower is studied in a monolayer graphene on a piezoelectric substrate. The phonon-drag contribution S\\text{PA}\\text{g} from the extrinsic potential of piezoelectric surface acoustic (PA) phonons of a piezoelectric substrate (GaAs) is calculated as a function of temperature T and electron concentration n s. At a very low temperature, S\\text{PA}\\text{g} is found to be much greater than S\\text{DA}\\text{g} of the intrinsic deformation potential of acoustic (DA) phonons of the graphene. There is a crossover of S\\text{PA}\\text{g} and S\\text{DA}\\text{g} at around ~5 K. In graphene samples of about  >10 µm size, we predict S g ~ 20 µV at 10 K, which is much greater than the diffusion component of the thermopower and can be experimentally observed. In the Bloch-Gruneisen (BG) regime T and n s dependence are, respectively, given by the power laws S\\text{PA}\\text{g} (S\\text{DA}\\text{g} ) ~ T 2(T 3) and S\\text{PA}\\text{g} , S\\text{DA}\\text{g} ~ n\\text{s}-1/2 . The T(n s) dependence is the manifestation of the 2D phonons (Dirac phase of the electrons). The effect of the screening is discussed. Analogous to Herring’s law (S g μ p ~ T -1), we predict a new relation S g μ p ~ n\\text{s}0 , where μ p is the phonon-limited mobility. We suggest that the n s dependent measurements will play a more significant role in identifying the Dirac phase and the effect of screening.

  16. Phonon Scattering and Confinement in Crystalline Films

    Science.gov (United States)

    Parrish, Kevin D.

    The operating temperature of energy conversion and electronic devices affects their efficiency and efficacy. In many devices, however, the reference values of the thermal properties of the materials used are no longer applicable due to processing techniques performed. This leads to challenges in thermal management and thermal engineering that demand accurate predictive tools and high fidelity measurements. The thermal conductivity of strained, nanostructured, and ultra-thin dielectrics are predicted computationally using solutions to the Boltzmann transport equation. Experimental measurements of thermal diffusivity are performed using transient grating spectroscopy. The thermal conductivities of argon, modeled using the Lennard-Jones potential, and silicon, modeled using density functional theory, are predicted under compressive and tensile strain from lattice dynamics calculations. The thermal conductivity of silicon is found to be invariant with compression, a result that is in disagreement with previous computational efforts. This difference is attributed to the more accurate force constants calculated from density functional theory. The invariance is found to be a result of competing effects of increased phonon group velocities and decreased phonon lifetimes, demonstrating how the anharmonic contribution of the atomic potential can scale differently than the harmonic contribution. Using three Monte Carlo techniques, the phonon-boundary scattering and the subsequent thermal conductivity reduction are predicted for nanoporous silicon thin films. The Monte Carlo techniques used are free path sampling, isotropic ray-tracing, and a new technique, modal ray-tracing. The thermal conductivity predictions from all three techniques are observed to be comparable to previous experimental measurements on nanoporous silicon films. The phonon mean free paths predicted from isotropic ray-tracing, however, are unphysical as compared to those predicted by free path sampling

  17. Retrieving aerosol height from the oxygen A band: a fast forward operator and sensitivity study concerning spectral resolution, instrumental noise, and surface inhomogeneity

    Science.gov (United States)

    Hollstein, A.; Fischer, J.

    2014-05-01

    Hyperspectral radiance measurements in the oxygen A band are sensitive to the vertical distribution of atmospheric scatterers, which in principle allows the retrieval of aerosol height from future instruments like TROPOMI, OCO2, FLEX, and CarbonSat. Discussed in this paper is a fast and flexible forward operator for the simulation of hyperspectral radiances in the oxygen A band and, based on this scheme, a sensitivity study about the inversion quality of aerosol optical thickness, aerosol mean height, and aerosol type. The forward operator is based on a lookup table with efficient data compression based on principal component analysis. Linear interpolation and computation of partial derivatives is performed in the much smaller space of expansion coefficients rather than wavelength. Thus, this approach is computationally fast and, at the same time, memory efficient. The sensitivity study explores the impact of instrument design on the retrieval of aerosol optical thickness and aerosol height. Considered are signal to noise ratio, spectral resolution, and spectral sampling. Also taken into account are surface inhomogeneities and variations of the aerosol type.

  18. Understanding photon sideband statistics and correlation for determining phonon coherence

    Science.gov (United States)

    Ding, Ding; Yin, Xiaobo; Li, Baowen

    2018-01-01

    Generating and detecting coherent high-frequency heat-carrying phonons have been topics of great interest in recent years. Although there have been successful attempts in generating and observing coherent phonons, rigorous techniques to characterize and detect phonon coherence in a crystalline material have been lagging compared to what has been achieved for photons. One main challenge is a lack of detailed understanding of how detection signals for phonons can be related to coherence. The quantum theory of photoelectric detection has greatly advanced the ability to characterize photon coherence in the past century, and a similar theory for phonon detection is necessary. Here, we reexamine the optical sideband fluorescence technique that has been used to detect high-frequency phonons in materials with optically active defects. We propose a quantum theory of phonon detection using the sideband technique and found that there are distinct differences in sideband counting statistics between thermal and coherent phonons. We further propose a second-order correlation function unique to sideband signals that allows for a rigorous distinction between thermal and coherent phonons. Our theory is relevant to a correlation measurement with nontrivial response functions at the quantum level and can potentially bridge the gap of experimentally determining phonon coherence to be on par with that of photons.

  19. Characterization and surface-enhanced Raman spectral probing of silver hydrosols prepared by two-wavelength laser ablation and fragmentation

    Czech Academy of Sciences Publication Activity Database

    Šmejkal, P.; Šišková, K.; Vlčková, B.; Pfleger, Jiří; Šloufová, Ivana; Šlouf, Miroslav; Mojzeš, P.

    2003-01-01

    Roč. 59, č. 10 (2003), s. 2321-2329 ISSN 1386-1425. [International Conference on Raman Spectroscopy Applied to the Earth Sciences /5./. Prague, 12.06.2002-15.06.2002] R&D Projects: GA ČR GA203/01/1013 Institutional research plan: CEZ:AV0Z4050913 Keywords : surface-enhanced Raman spectroscopy * silver hydrosols * two-wavelength laser ablation Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.315, year: 2003

  20. Scattering and Doppler Spectral Analysis for a Fast-Moving Target above Time-Varying Lossy Dielectric Sea Surface

    Directory of Open Access Journals (Sweden)

    Ke Li

    2016-01-01

    Full Text Available A numerical electromagnetic method based on the physical optics with physical optics method (PO-PO is employed to calculate backscattered returns from a missile-like target above sea surface. Surfaces are time-varying Monte Carlo simulations initialized as realizations of a Pierson–Moskowitz spectrum. The monostatic normalized radar cross section of composite model by the hybrid PO-PO method is calculated and compared with those by the conventional method of moments, as well as the runtime and memory requirements. The results are found to be in good agreement. The runtime shows that the hybrid PO-PO method enables large-scale time-varying Monte Carlo simulations. The numerical simulations of the Doppler spectrum from the fast-moving target above time-varying lossy dielectric sea surface are obtained, and the Doppler spectra of backscattered signals from this model are discussed for different incident angles, speed of flying target, wind speeds, incident frequencies, and target altitudes in detail. Finally, the coupling effects on Doppler spectra are analyzed. All the results are obtained at the incidence of horizontal polarization wave in this study.

  1. Structural Properties and Phonon dispertion of NACl

    Directory of Open Access Journals (Sweden)

    R. Khoda-Bakhsh

    2001-06-01

    Full Text Available   Although many phenomena in condensed matter Physics can be understood on the basis of a model, there are also considerable number of physical properties of solid which can not be explained except in the framework of lattice dynamics.   We have calculated the phonon frequencies of Na Cl, using an approach which is a combination of frozen phonon and force constants methods in the framework of density functional pseudopotential theory. The dispersion relation curves, were calculated along symmetry direction Δ,  Σ  and  Ù. We also calculated Grunesein parameters for all modes at X and L points in Brillion zone. The calcutions are made in the framework of density functional and pseudopotential theory, using super cell method, with the valence orbitals expanded in plane waves.

  2. Beryllium phonon spectrum from cold neutron measurements

    International Nuclear Information System (INIS)

    Bulat, I.A.

    1979-01-01

    The inelastic coherent scattering of neutrons with the initial energy E 0 =4.65 MeV on the spectrometer according to the time of flight is studied in polycrystalline beryllium. The measurements are made for the scattering angles THETA=15, 30, 45, 60, 75 and 90 deg at 293 K. The phonon spectrum of beryllium, i-e. g(w) is reestablished from the experimental data. The data obtained are compared with the data of model calculations. It is pointed out that the phonon spectrum of beryllium has a bit excessive state density in the energy range from 10 to 30 MeV. It is caused by the insufficient statistical accuracy of the experiment at low energy transfer

  3. Multiple topological phases in phononic crystals

    KAUST Repository

    Chen, Zeguo

    2017-11-20

    We report a new topological phononic crystal in a ring-waveguide acoustic system. In the previous reports on topological phononic crystals, there are two types of topological phases: quantum Hall phase and quantum spin Hall phase. A key point in achieving quantum Hall insulator is to break the time-reversal (TR) symmetry, and for quantum spin Hall insulator, the construction of pseudo-spin is necessary. We build such pseudo-spin states under particular crystalline symmetry (C-6v) and then break the degeneracy of the pseudo-spin states by introducing airflow to the ring. We study the topology evolution by changing both the geometric parameters of the unit cell and the strength of the applied airflow. We find that the system exhibits three phases: quantum spin Hall phase, conventional insulator phase and a new quantum anomalous Hall phase.

  4. Electron and Phonon Transport in Molecular Junctions

    DEFF Research Database (Denmark)

    Li, Qian

    transmission at the Fermi energy. We propose and analyze a way of using π   stacking to design molecular junctions to control heat transport. We develop a simple model system to identify optimal parameter regimes and then use density functional theory (DFT) to extract model parameters for a number of specific......Molecular electronics provide the possibility to investigate electron and phonon transport at the smallest imaginable scale, where quantum effects can be investigated and exploited directly in the design. In this thesis, we study both electron transport and phonon transport in molecular junctions....... The system we are interested in here are π-stacked molecules connected with two semi-infinite leads. π-stacked aromatic rings, connected via π-π electronic coupling, provides a rather soft mechanical bridge while maintaining high electronic conductivity. We investigate electron transport...

  5. On the theory of three types of polaritons (phonon, exciton and plasmon polaritons)

    International Nuclear Information System (INIS)

    Ha, Duong Thi; Thuy, Dinh Thi; Hoa, Vo Thi; Van, Tran Thi Thanh; Viet, Nguyen Ai

    2017-01-01

    We have investigated the similarities and difference between three well-known types of polaritons: phonon polariton, exciton polariton and surface plasmon polariton. For first two types (phonon polariton and exciton polariton) the interaction between photon and media can be expressed via a longitudinal-transversal splitting (LT-splitting), while for third type of polariton (surface plasmon polariton) via the boundary condition. Considering an analogy of these three types of polaritons, an effective LT-splitting was introduced for surface plasmon polariton. We discuss a possible existence of an evanescent state in the band gap of polaritons. Finally, the Nambu broken symmetry theory and Anderson-Higgs mechanism are discussed for lower branch of these polaritons. (paper)

  6. Phonon dispersion relations for caesium thiocyanate

    International Nuclear Information System (INIS)

    Irving, M.A.; Smith, T.F.; Elcombe, M.M.

    1984-01-01

    Room temperature phonon dispersion relations for frequencies below 2 THz have been measured, along the three orthorhombic axes and selected diagonal directions by neutron inelastic scattering, for caesium thiocyanate. These curves, which represent 13 acoustic modes and 11 optic modes of vibration, do not agree with the dispersion behaviour calculated from the rigid-ion model developed by Ti and Ra to describe their Raman scattering observations

  7. Quantum mode phonon forces between chainmolecules

    DEFF Research Database (Denmark)

    Bohr, Jakob

    2001-01-01

    A phenomenological description of the contributions of phonons to molecular force is developed. It uses an approximation to consider macromolecules as solid continua. The molecular modes of a molecule can then be characterized by a Debye-like description of the partition function. The resulting b....... For the later case, a significant change in zero-point energy is found. This may be the underlying cause for cold denaturation of proteins. (C) 2001 John Wiley & Sons, Inc....

  8. Linear and non-linear infrared response of one-dimensional vibrational Holstein polarons in the anti-adiabatic limit: Optical and acoustical phonon models

    Science.gov (United States)

    Falvo, Cyril

    2018-02-01

    The theory of linear and non-linear infrared response of vibrational Holstein polarons in one-dimensional lattices is presented in order to identify the spectral signatures of self-trapping phenomena. Using a canonical transformation, the optical response is computed from the small polaron point of view which is valid in the anti-adiabatic limit. Two types of phonon baths are considered: optical phonons and acoustical phonons, and simple expressions are derived for the infrared response. It is shown that for the case of optical phonons, the linear response can directly probe the polaron density of states. The model is used to interpret the experimental spectrum of crystalline acetanilide in the C=O range. For the case of acoustical phonons, it is shown that two bound states can be observed in the two-dimensional infrared spectrum at low temperature. At high temperature, analysis of the time-dependence of the two-dimensional infrared spectrum indicates that bath mediated correlations slow down spectral diffusion. The model is used to interpret the experimental linear-spectroscopy of model α-helix and β-sheet polypeptides. This work shows that the Davydov Hamiltonian cannot explain the observations in the NH stretching range.

  9. Thermal design studies in superconducting rf cavities: Phonon peak and Kapitza conductance

    Directory of Open Access Journals (Sweden)

    A. Aizaz

    2010-09-01

    Full Text Available Thermal design studies of superconducting radio frequency (SRF cavities involve two thermal parameters, namely the temperature dependent thermal conductivity of Nb at low temperatures and the heat transfer coefficient at the Nb-He II interface, commonly known as the Kapitza conductance. During the fabrication process of the SRF cavities, Nb sheet is plastically deformed through a deep drawing process to obtain the desired shape. The effect of plastic deformation on low temperature thermal conductivity as well as Kapitza conductance has been studied experimentally. Strain induced during the plastic deformation process reduces the thermal conductivity in its phonon transmission regime (disappearance of phonon peak by 80%, which may explain the performance limitations of the defect-free SRF cavities during their high field operations. Low temperature annealing of the deformed Nb sample could not recover the phonon peak. However, moderate temperature annealing during the titanification process recovered the phonon peak in the thermal conductivity curve. Kapitza conductance measurements for the Nb-He II interface for various surface topologies have also been carried out before and after the annealing. These measurements reveal consistently increased Kapitza conductance after the annealing process was carried out in the two temperature regimes.

  10. Comparison of three empirical force fields for phonon calculations in CdSe quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Kelley, Anne Myers [Chemistry and Chemical Biology, University of California, Merced, 5200 North Lake Road, Merced, California 95343 (United States)

    2016-06-07

    Three empirical interatomic force fields are parametrized using structural, elastic, and phonon dispersion data for bulk CdSe and their predictions are then compared for the structures and phonons of CdSe quantum dots having average diameters of ~2.8 and ~5.2 nm (~410 and ~2630 atoms, respectively). The three force fields include one that contains only two-body interactions (Lennard-Jones plus Coulomb), a Tersoff-type force field that contains both two-body and three-body interactions but no Coulombic terms, and a Stillinger-Weber type force field that contains Coulombic interactions plus two-body and three-body terms. While all three force fields predict nearly identical peak frequencies for the strongly Raman-active “longitudinal optical” phonon in the quantum dots, the predictions for the width of the Raman peak, the peak frequency and width of the infrared absorption peak, and the degree of disorder in the structure are very different. The three force fields also give very different predictions for the variation in phonon frequency with radial position (core versus surface). The Stillinger-Weber plus Coulomb type force field gives the best overall agreement with available experimental data.

  11. Surface spectroscopy using inelastic scattering of He atoms

    International Nuclear Information System (INIS)

    Doak, R.B.

    1986-01-01

    A low energy (∼0 meV) neutral helium atomic beam has been scattered from crystal surfaces. Energy gain and face phonons may be measured by time-of-flight analysis of single phonon scattering dominates, allowing the frequency and wave vector of individual surface phonons to be determined and their dispersion relations plotted. Resonant interaction with bound states of the helium in the surface potential well is found to greatly affect the inelastic scattering cross-sections. 23 references, 27 figures

  12. Ultrafast optical studies of phonon polaritons, squeezed modes and high frequency diamagnetism in metamaterials

    Science.gov (United States)

    Bianchini, Andrea

    The coupling of the electromagnetic field with polar lattice vibrations of a solid, which gives rise to what is traditionally known as phonon polaritons, is investigated both through spontaneous and stimulated Raman scattering. Experimental results relative to polariton modes excited in several semiconductors are presented to explore their dependence on the crystal symmetry, temperature, excitation wavelength and measuring techniques. In GaAs we find discrepancies between spontaneous and Impulsive Stimulated Raman Scattering (ISRS) which are attributed to the presence of free carriers interacting with the electric field of the longitudinal phonon mode. In CraSe, we successfully excite two distinct frequencies of the lower phonon polariton branch. In the transparent regime, this is accomplished combining in the same experiment backward and forward scattering, the latter one induced by the beam reflected at the back surface of the sample. Moreover, it is shown how the reduced value of the scattering cross section retrieved in the time domain experiments is attributable to the polariton field spatial distribution, estimated in accordance with the Cherenkov radiation theory. In CdSe we identify another polariton mode that is present whenever the dielectric constant of a medium becomes negative: the surface plasmon polariton. Besides coherent phonons, squeezed phonons are studied. discussing their generation and detection in regard to the ISRS theory. In particular we introduce a novel phenomenon, named "phonon echo", occurring whenever a squeezed phonon field is induced in a crystal through a double pump excitation. Simulations are shown to validate the theoretical predictions and pave the way to future experiments. Shifting to the metamaterial field, we consider a viable technique to achieve artificial diamagnetism (the magnetic permeability mu is < 1). The proposed approach is based on the well established sphere-in-a-host model that is thoroughly described with

  13. Analytical approach to phonons and electron-phonon interactions in single-walled zigzag carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Kandemir, B S; Keskin, M [Department of Physics, Faculty of Sciences, Ankara University, 06100 Tandogan, Ankara (Turkey)

    2008-08-13

    In this paper, exact analytical expressions for the entire phonon spectra in single-walled carbon nanotubes with zigzag geometry are presented by using a new approach, originally developed by Kandemir and Altanhan. This approach is based on the concept of construction of a classical lattice Hamiltonian of single-walled carbon nanotubes, wherein the nearest and next nearest neighbor and bond bending interactions are all included, then its quantization and finally diagonalization of the resulting second quantized Hamiltonian. Furthermore, within this context, explicit analytical expressions for the relevant electron-phonon interaction coefficients are also investigated for single-walled carbon nanotubes having this geometry, by the phonon modulation of the hopping interaction.

  14. Analytical approach to phonons and electron-phonon interactions in single-walled zigzag carbon nanotubes

    International Nuclear Information System (INIS)

    Kandemir, B S; Keskin, M

    2008-01-01

    In this paper, exact analytical expressions for the entire phonon spectra in single-walled carbon nanotubes with zigzag geometry are presented by using a new approach, originally developed by Kandemir and Altanhan. This approach is based on the concept of construction of a classical lattice Hamiltonian of single-walled carbon nanotubes, wherein the nearest and next nearest neighbor and bond bending interactions are all included, then its quantization and finally diagonalization of the resulting second quantized Hamiltonian. Furthermore, within this context, explicit analytical expressions for the relevant electron-phonon interaction coefficients are also investigated for single-walled carbon nanotubes having this geometry, by the phonon modulation of the hopping interaction

  15. NATO Advanced Study Institute on Nonequilibrium Phonon Dynamics

    CERN Document Server

    1985-01-01

    Phonons are always present in the solid state even at an absolute temperature of 0 K where zero point vibrations still abound. Moreover, phonons interact with all other excitations of the solid state and, thereby, influence most of its properties. Historically experimental information on phonon transport came from measurements of thermal conductivity. Over the past two decades much more, and much more detailed, information on phonon transport and on many of the inherent phonon interaction processes have come to light from experiments which use nonequilibrium phonons to study their dynamics. The resultant research field has most recently blossomed with the development of ever more sophisticated experimental and theoretical methods which can be applied to it. In fact, the field is moving so rapidly that new members of the research community have difficulties in keeping up to date. This NATO Advanced Study Institute (ASI) was organized with the objective of overcoming the information barrier between those expert...

  16. Phonon hydrodynamics for nanoscale heat transport at ordinary temperatures

    Science.gov (United States)

    Guo, Yangyu; Wang, Moran

    2018-01-01

    The classical Fourier's law fails in extremely small and ultrafast heat conduction even at ordinary temperatures due to strong thermodynamic nonequilibrium effects. In this work, a macroscopic phonon hydrodynamic equation beyond Fourier's law with a relaxation term and nonlocal terms is derived through a perturbation expansion to the phonon Boltzmann equation around a four-moment nonequilibrium solution. The temperature jump and heat flux tangential retardant boundary conditions are developed based on the Maxwell model of the phonon-boundary interaction. Extensive steady-state and transient nanoscale heat transport cases are modeled by the phonon hydrodynamic model, which produces quantitative predictions in good agreement with available phonon Boltzmann equation solutions and experimental results. The phonon hydrodynamic model provides a simple and elegant mathematical description of non-Fourier heat conduction with a clear and intuitive physical picture. The present work will promote deeper understanding and macroscopic modeling of heat transport in extreme states.

  17. Frictional drag between quantum wells mediated by phonon exchange

    DEFF Research Database (Denmark)

    Bønsager, M.C.; Flensberg, Karsten; Hu, Ben Yu-Kuang

    1998-01-01

    We use the Kubo formalism to evaluate the contribution of acoustic-phonon exchange to the frictional drag between nearby two-dimensional electron systems. In the case of free phonons, we find a divergent drag rate (tau(D)(-l)). However, tau(D)(-l) becomes finite when phonon scattering from either...... lattice imperfections or electronic excitations is accounted for. In the case of GaAs quantum wells, we find that for a phonon mean free path l(ph) smaller than a critical value, imperfection scattering dominates and the drag rate varies as ln(l(ph)/d) over many orders of magnitude of the layer separation...... d. When l(ph) exceeds the critical value, the drag rate is dominated by coupling through an electron-phonon collective mode localized in the vicinity of the electron layers. We argue that the coupled electron-phonon mode may be observable for realistic parameters. Our theory is in good agreement...

  18. Phonon contribution to RIXS spectra calculated with a cumulant expansion for the quasiparticle Green's function

    Science.gov (United States)

    Gilmore, Keith; Geondzhian, Andrey; Kas, Josh

    Much of the effort in many-body techniques for going beyond standard density functional theory seeks to improve the accuracy of quasiparticle energies, particularly for large or complex systems. A quantity that is sometimes overlooked is the quasiparticle spectral function. Accurately calculating satellite features due to boson excitations is essential for providing a meaningful interpretation of many experimental results, particularly for X-ray spectroscopies. Resonant inelastic x-ray scattering (RIXS) is a relatively new experimental probe of the coupling of electronic states to various excitations in a material such as plasmons, magnons and phonons. The localized nature of the core hole in X-ray spectroscopies allows one to use linked-cluster formulations, as in the seminal work of Nozieres, that express the electron Green's function as a cumulant expansion rather than via a Dyson equation. Kas et al. have recently used this approach for electron-plasmon coupling in X-ray photoemission and X-ray absorption. We perform analogous work for the case of coupling to phonons, with a particular focus on RIXS. RIXS is increasingly used to study electron-phonon coupling in unconventional superconductors and it is essential to improve our interpretation of these spectra. TiO2, for which high energy resolution RIXS data was recently reported, serves as our test case.

  19. Rayleigh Waves in Phononic Crystal Made of Multilayered Pillars: Confined Modes, Fano Resonances, and Acoustically Induced Transparency

    Science.gov (United States)

    Oudich, M.; Djafari-Rouhani, B.; Bonello, B.; Pennec, Y.; Hemaidia, S.; Sarry, F.; Beyssen, D.

    2018-03-01

    We present a design of phononic crystal based on pillars distributed on a substrate surface in which each pillar is constructed by a periodic stacking of PMMA and silicon layers. The pillar behaves like a one-dimensional phononic crystal which allows the creation of band gaps that prohibit wave propagation along the pillar. Thanks to this property, we show that confined modes are produced at the pillar-substrate interface which couples with surface acoustic waves (SAW) and causes their attenuation. Furthermore, by tailoring a defect inside the phononic pillar, we reveal the possibility to create confined cavity modes inside the band gap which can strongly couple with SAW. The cavity modes can be excited by SAW and the coupling produces sharp SAW transmissions. Additionally, we demonstrate that the coupling between the cavity modes and the confined modes at the pillar-substrate interface can give rise to a Fano-like resonance. We also evidence the possibility of generating an acoustic analogue of electromagnetically induced transparency for SAW with high transmission in a narrow bandwidth. The system presents perspectives for the design of high-quality-factor phononic excitation for optomechanic devices and phonon circuits based on SAW manipulation.

  20. Seismic velocity site characterization of 10 Arizona strong-motion recording stations by spectral analysis of surface wave dispersion

    Science.gov (United States)

    Kayen, Robert E.; Carkin, Brad A.; Corbett, Skye C.

    2017-10-19

    Vertical one-dimensional shear wave velocity (VS) profiles are presented for strong-motion sites in Arizona for a suite of stations surrounding the Palo Verde Nuclear Generating Station. The purpose of the study is to determine the detailed site velocity profile, the average velocity in the upper 30 meters of the profile (VS30), the average velocity for the entire profile (VSZ), and the National Earthquake Hazards Reduction Program (NEHRP) site classification. The VS profiles are estimated using a non-invasive continuous-sine-wave method for gathering the dispersion characteristics of surface waves. Shear wave velocity profiles were inverted from the averaged dispersion curves using three independent methods for comparison, and the root-mean-square combined coefficient of variation (COV) of the dispersion and inversion calculations are estimated for each site.

  1. Potential energy and dipole moment surfaces for HF@C60: Prediction of spectral and electric response properties

    Science.gov (United States)

    Kalugina, Yulia N.; Roy, Pierre-Nicholas

    2017-12-01

    We present a five-dimensional potential energy surface (PES) for the HF@C60 system computed at the DF-LMP2/cc-pVTZ level of theory. We also calculated a five-dimensional dipole moment surface (DMS) based on DFT(PBE0)/cc-pVTZ calculations. The HF and C60 molecules are considered rigid with bond length rHF = 0.9255 Å (gas phase ground rovibrational state geometry). The C60 geometry is of Ih symmetry. The ab initio points were fitted to obtain a PES in terms of bipolar spherical harmonics. The minimum of the PES corresponds to a geometry where the center of mass of HF is located 0.11 Å away from the center of the cage with an interaction energy of -6.929 kcal/mol. The DMS was also represented in terms of bipolar spherical harmonics. The PES was used to calculate the rotation-translation bound states of HF@C60, and good agreement was found relative to the available experimental data [A. Krachmalnicoff et al., Nat. Chem. 8, 953 (2016)] except for the splitting of the first rotational excitation levels. We propose an empirical adjustment to the PES in order to account for the experimentally observed symmetry breaking. The form of that effective PES is additive. We also propose an effective Hamiltonian with an adjusted rotational constant in order to quantitatively reproduce the experimental results including the splitting of the first rotational state. We use our models to compute the molecular volume polarizability of HF confined by C60 and obtain good agreement with experiment.

  2. Decay of coherent acoustic phonons generated by femtosecond pulsed optical excitation and injected in a Wannier-Stark superlattice (Conference Presentation)

    Science.gov (United States)

    Kent, Anthony J.; Poyser, Caroline L.; Akimov, Andrey V.; York, William; Henini, Mohamed; Campion, Richard P.

    2017-02-01

    In the past decade, sound amplification by the stimulated emission of (acoustic phonon) radiation (saser) devices for generating coherent terahertz (THz) acoustic waves have been demonstrated [1 - 3]. The devices exploit the electron-phonon interactions in periodic semiconductor nanostructures known as superlattices (SLs) to amplify acoustic phonons. In addition, the particular acoustic properties of SLs can be exploited to make mirrors and cavities for THz phonons. Thus SLs can provide the two essential elements of a saser: the acoustic gain medium and the acoustic cavity. In this presentation I will describe experimental studies of the THz phonon dynamics in a weakly-coupled GaAs/AlAs saser SL, which is DC electrically biased into the Wannier-Stark regime. Picoseconds-duration pulses of coherent THz acoustic phonons were generated using pump light pulses from a femtosecond laser and injected into the SL device. These phonon pulses seeded the saser cavity modes at about 220 and 440 GHz, which were amplified within the device. The phonons were detected using two methods: reflection of femtosecond probe light pulses, in a conventional pump-probe arrangement, and through the transient electrical response of the device itself. When the DC bias conditions for saser were achieved in the device, the amplitude and lifetime of the seeded modes were both increased, analogous to the threshold and spectral line narrowing effects seen in laser devices. [1] R P Beardsley et al., Phys. Rev. Lett. 104, 085501 (2010). [2] W Maryam et al., Nature Communications 4:2184 (2013). [3] K Shinokita et al., Phys. Rev. Lett. 116, 075504 (2016).

  3. Isotopic effects on the phonon modes in boron carbide.

    Science.gov (United States)

    Werheit, H; Kuhlmann, U; Rotter, H W; Shalamberidze, S O

    2010-10-06

    The effect of isotopes ((10)B-(11)B; (12)C-(13)C) on the infrared- and Raman-active phonons of boron carbide has been investigated. For B isotopes, the contributions of the virtual crystal approximation, polarization vector and isotopical disorder are separated. Boron and carbon isotope effects are largely opposite to one another and indicate the share of the particular atoms in the atomic assemblies vibrating in specific phonon modes. Some infrared-active phonons behave as expected for monatomic boron crystals.

  4. Phonon-assisted tunneling and its dependence on pressure

    International Nuclear Information System (INIS)

    Roy, P.N.; Singh, A.P.; Thakur, B.N.

    1999-01-01

    First the mechanism of phonon-assisted tunneling has been investigated. The indirect tunnel current density has been computed after taking the amplitude of the time dependent perturbation as the energy of the lattice vibration. Later the pressure dependence of the phonon-assisted tunnel current has been computed using Payne's expression for the dependence of phonon frequency on pressure. Very good qualitative agreements are obtained between predicted and observed characteristics. (author)

  5. Acoustic phonon dispersion of CoSi2

    International Nuclear Information System (INIS)

    Weiss, L.; Rumyantsev, A.Yu.; Ivanov, A.S.

    1985-01-01

    The acoustical phonon dispersion curves of CoSi 2 are measured at room temperature along the main symmetry directions by means of coherent one-phonon scattering of thermal neutrons. The dispersion curves are compared with those of Ge, Si, and the fluorite structure types as CaF 2 and UO 2 . From the slope of the phonon dispersion curves at the GAMMA-point the elastic constants have been obtained

  6. Computational modeling of geometry dependent phonon transport in silicon nanostructures

    Science.gov (United States)

    Cheney, Drew A.

    Recent experiments have demonstrated that thermal properties of semiconductor nanostructures depend on nanostructure boundary geometry. Phonons are quantized mechanical vibrations that are the dominant carrier of heat in semiconductor materials and their aggregate behavior determine a nanostructure's thermal performance. Phonon-geometry scattering processes as well as waveguiding effects which result from coherent phonon interference are responsible for the shape dependence of thermal transport in these systems. Nanoscale phonon-geometry interactions provide a mechanism by which nanostructure geometry may be used to create materials with targeted thermal properties. However, the ability to manipulate material thermal properties via controlling nanostructure geometry is contingent upon first obtaining increased theoretical understanding of fundamental geometry induced phonon scattering processes and having robust analytical and computational models capable of exploring the nanostructure design space, simulating the phonon scattering events, and linking the behavior of individual phonon modes to overall thermal behavior. The overall goal of this research is to predict and analyze the effect of nanostructure geometry on thermal transport. To this end, a harmonic lattice-dynamics based atomistic computational modeling tool was created to calculate phonon spectra and modal phonon transmission coefficients in geometrically irregular nanostructures. The computational tool is used to evaluate the accuracy and regimes of applicability of alternative computational techniques based upon continuum elastic wave theory. The model is also used to investigate phonon transmission and thermal conductance in diameter modulated silicon nanowires. Motivated by the complexity of the transmission results, a simplified model based upon long wavelength beam theory was derived and helps explain geometry induced phonon scattering of low frequency nanowire phonon modes.

  7. Phonon excitation and instabilities in biased graphene nanoconstrictions

    DEFF Research Database (Denmark)

    Gunst, Tue; Lu, Jing Tao; Hedegård, Per

    2013-01-01

    We investigate how a high current density perturbs the phonons in a biased graphene nanoconstriction coupled to semi-infinite electrodes. The coupling to electrode phonons, electrode electrons under bias, Joule heating, and current-induced forces is evaluated using first principles density...... to the presence of negatively damped phonons driven by the current. The effects may limit the stability and capacity of graphene nanoconstrictions to carry high currents....

  8. Theoretical study of the phonon spectrum, phonon refraction and thermodynamic properties for explosive/additive interfaces

    Science.gov (United States)

    Long, Yao; Chen, Jun

    2018-01-01

    We develop a method to calculate the local vibrational mode and phonon refraction probability of a 1,3,5-triamino-2,4,6-trinitrobenzene/graphite interface, and use them to evaluate the interfacial free energy, heat capacity and thermal conductivity. We find that the heat exchange across the interface is sensitive with five incident phonon states. The frequencies, vibrational modes, refraction angles and refraction probabilities of the sensitive states are calculated. The relationship between vibrational modes and thermodynamic properties at the interface is obtained.

  9. Phonon-assisted decoherence and tunneling in quantum dot molecules

    DEFF Research Database (Denmark)

    Grodecka-Grad, Anna; Foerstner, Jens

    2011-01-01

    We study the influence of the phonon environment on the electron dynamics in a doped quantum dot molecule. A non-perturbative quantum kinetic theory based on correlation expansion is used in order to describe both diagonal and off-diagonal electron-phonon couplings representing real and virtual...... processes with relevant acoustic phonons. We show that the relaxation is dominated by phonon-assisted electron tunneling between constituent quantum dots and occurs on a picosecond time scale. The dependence of the time evolution of the quantum dot occupation probabilities on the energy mismatch between...

  10. Two-phonon bound states in imperfect crystals

    International Nuclear Information System (INIS)

    Behera, S.N.; Samsur, Sk.

    1980-01-01

    The question of the occurrence of two-phonon bound states in imperfect crystals is investigated. It is shown that the anharmonicity mediated two-phonon bound state which is present in perfect crystals gets modified due to the presence of impurities. Moreover, the possibility of the occurrence of a purely impurity mediated two-phonon bound state is demonstrated. The bound state frequencies are calculated using the simple Einstein oscillator model for the host phonons. The two-phonon density of states for the imperfect crystal thus obtained has peaks at the combination and difference frequencies of two host phonons besides the peaks at the bound state frequencies. For a perfect crystal the theory predicts a single peak at the two-phonon bound state frequency in conformity with experimental observations and other theoretical calculations. Experimental data on the two-phonon infrared absorption and Raman scattering from mixed crystals of Gasub(1-c)Alsub(c)P and Gesub(1-c)Sisub(c) are analysed to provide evidence in support of impurity-mediated two-phonon bound states. The relevance of the zero frequency (difference spectrum) peak to the central peak, observed in structural phase transitions, is conjectured. (author)

  11. Sensing coherent phonons with two-photon interference

    Science.gov (United States)

    Ding, Ding; Yin, Xiaobo; Li, Baowen

    2018-02-01

    Detecting coherent phonons pose different challenges compared to coherent photons due to the much stronger interaction between phonons and matter. This is especially true for high frequency heat carrying phonons, which are intrinsic lattice vibrations experiencing many decoherence events with the environment, and are thus generally assumed to be incoherent. Two photon interference techniques, especially coherent population trapping (CPT) and electromagnetically induced transparency (EIT), have led to extremely sensitive detection, spectroscopy and metrology. Here, we propose the use of two photon interference in a three-level system to sense coherent phonons. Unlike prior works which have treated phonon coupling as damping, we account for coherent phonon coupling using a full quantum-mechanical treatment. We observe strong asymmetry in absorption spectrum in CPT and negative dispersion in EIT susceptibility in the presence of coherent phonon coupling which cannot be accounted for if only pure phonon damping is considered. Our proposal has application in sensing heat carrying coherent phonons effects and understanding coherent bosonic multi-pathway interference effects in three coupled oscillator systems.

  12. Ballistic phonon and thermal radiation transport across a minute vacuum gap in between aluminum and silicon thin films: Effect of laser repetitive pulses on transport characteristics

    Science.gov (United States)

    Yilbas, B. S.; Ali, H.

    2016-08-01

    Short-pulse laser heating of aluminum and silicon thin films pair with presence of a minute vacuum gap in between them is considered and energy transfer across the thin films pair is predicted. The frequency dependent Boltzmann equation is used to predict the phonon intensity distribution along the films pair for three cycles of the repetitive short-pulse laser irradiation on the aluminum film surface. Since the gap size considered is within the Casimir limit, thermal radiation and ballistic phonon contributions to energy transfer across the vacuum gap is incorporated. The laser irradiated field is formulated in line with the Lambert's Beer law and it is considered as the volumetric source in the governing equations of energy transport. In order to assess the phonon intensity distribution in the films pair, equivalent equilibrium temperature is introduced. It is demonstrated that thermal separation of electron and lattice sub-systems in the aluminum film, due to the short-pulse laser irradiation, takes place and electron temperature remains high in the aluminum film while equivalent equilibrium temperature for phonons decays sharply in the close region of the aluminum film interface. This behavior is attributed to the phonon boundary scattering at the interface and the ballistic phonon transfer to the silicon film across the vacuum gap. Energy transfer due to the ballistic phonon contribution is significantly higher than that of the thermal radiation across the vacuum gap.

  13. Airborne Spectral BRDF of Various Surface Types (Ocean, Vegetation, Snow, Desert, Wetlands, Cloud Decks, Smoke Layers) for Remote Sensing Applications

    Science.gov (United States)

    Gatebe, Charles K.; King, Michael D.

    2016-01-01

    In this paper we describe measurements of the bidirectional reflectance-distribution function (BRDF) acquired over a 30-year period (1984-2014) by the National Aeronautics and Space Administration's (NASA's) Cloud Absorption Radiometer (CAR). Our BRDF database encompasses various natural surfaces that are representative of many land cover or ecosystem types found throughout the world. CAR's unique measurement geometry allows a comparison of measurements acquired from different satellite instruments with various geometrical configurations, none of which are capable of obtaining such a complete and nearly instantaneous BRDF. This database is therefore of great value in validating many satellite sensors and assessing corrections of reflectances for angular effects. These data can also be used to evaluate the ability of analytical models to reproduce the observed directional signatures, to develop BRDF models that are suitable for sub-kilometer-scale satellite observations over both homogeneous and heterogeneous landscape types, and to test future spaceborne sensors. All of these BRDF data are publicly available and accessible in hierarchical data format (http:car.gsfc.nasa.gov/).

  14. Cu-Fe-S Nanocrystals Exhibiting Tunable Localized Surface Plasmon Resonance in the Visible to NIR Spectral Ranges.

    Science.gov (United States)

    Gabka, Grzegorz; Bujak, Piotr; Ostrowski, Andrzej; Tomaszewski, Waldemar; Lisowski, Wojciech; Sobczak, Janusz W; Pron, Adam

    2016-07-05

    Cu-Fe-S nanocrystals exhibiting a strong localized surface plasmon resonance (LSPR) effect were synthesized for the first time. The elaborated reproducible preparation procedure involved copper(II) oleate, iron(III) stearate, and sulfur powder dissolved in oleylamine (OLA) as precursors. The wavelength of the plasmonic resonance maximum could be tuned by changing the Cu/Fe ratio in the resulting nanocrystals, being the most energetic for the 1:1 ratio (486 nm) and undergoing a bathochromic shift to ca. 1200 nm with an increase to 6:1. LSPR could also be observed in nanocrystals prepared from the same metal precursors and sulfur powder dissolved in 1-octadecene (ODE), provided that the sulfur precursor was taken in excess. Detailed analysis of the reaction mixture by chromatographic techniques, supplemented by mass spectrometry and (1)H NMR spectroscopy enabled the identification of the true chemical nature of the sulfur precursor in S/OLA, namely, (C18H35NH3(+))(C18H35NH-S8(-)), a reactive product of the reduction of elemental sulfur by the amine groups of OLA. In the case of the S/ODE precursor, the true precursors are much less reactive primary or secondary thioethers and dialkyl polysulfides.

  15. Ultrafast Spectral Photoresponse of Bilayer Graphene: Optical Pump-Terahertz Probe Spectroscopy.

    Science.gov (United States)

    Kar, Srabani; Nguyen, Van Luan; Mohapatra, Dipti R; Lee, Young Hee; Sood, A K

    2018-02-27

    Photoinduced terahertz conductivity Δσ(ω) of Bernal stacked bilayer graphene (BLG) with different dopings is measured by time-resolved optical pump terahertz probe spectroscopy. The real part of photoconductivity Δσ(ω) (Δσ Re (ω)) is positive throughout the spectral range 0.5-2.5 THz in low-doped BLG. This is in sharp contrast to Δσ(ω) for high-doped bilayer graphene where Δσ Re (ω) is negative at low frequency and positive on the high frequency side. We use Boltzmann transport theory to understand quantitatively the frequency dependence of Δσ(ω), demanding the energy dependence of different scattering rates such as short-range impurity scattering, Coulomb scattering, carrier-acoustic phonon scattering, and substrate surface optical phonon scattering. We find that the short-range disorder scattering dominates over other processes. The calculated photoconductivity captures very well the experimental conductivity spectra as a function of lattice temperature varying from 300 to 4 K, without any empirical fitting procedures adopted so far in the literature. This helps us to understand the intraband conductivity of photoexcited hot carriers in 2D materials.

  16. On Phonons in Simple Metals II. Calculated Dispersion Curves In Aluminium

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, R. [AB Atomenergi, Nykoeping (Sweden); Westin, A. [Dept. of Theore tical Physics, Univ. of Uppsala, Uppsala (Sweden)

    1969-07-15

    The real part of the dynamical matrix, derived earlier in a weak local potential ion-electron interaction model of the metal, is investigated in the case of aluminium. It is shown that the free electron, or Lindhard, dielectric function leads to a picture of the metal which is inconsistent with the dHvA observations of the Fermi surface. By adjusting one parameter, however, the experimental phonon frequencies are reproduced satisfactorily. Even some simple structure in the derivative d{omega}/dq can be reproduced in this way. Although corrections to the Lindhard dielectric matrix give no essential contributions to the dynamical matrix, the first order corrections, which are the most important, can explain the observed Fermi surface. Much of the observed structure in the phonon dispersion curves seems also to be due to these non-diagonal terms in the dielectric matrix.

  17. Negative refraction imaging of solid acoustic waves by two-dimensional three-component phononic crystal

    International Nuclear Information System (INIS)

    Li Jing; Liu Zhengyou; Qiu Chunyin

    2008-01-01

    By using of the multiple scattering methods, we study the negative refraction imaging effect of solid acoustic waves by two-dimensional three-component phononic crystals composed of coated solid inclusions placed in solid matrix. We show that localized resonance mechanism brings on a group of flat single-mode bands in low-frequency region, which provides two equivalent frequency surfaces (EFS) close to circular. The two constant frequency surfaces correspond to two Bloch modes, a right-handed and a left-handed, whose leading mode are respectively transverse (T) and longitudinal (L) modes. The negative refraction behaviors of the two kinds of modes have been demonstrated by simulation of a Gaussian beam through a finite system. High-quality far-field imaging by a planar lens for transverse or longitudinal waves has been realized separately. This three-component phononic crystal may thus serve as a mode selector in negative refraction imaging of solid acoustic waves

  18. Fuchs-Kliewer phonons of H-covered and clean GaN(1 1 bar 00)

    Science.gov (United States)

    Rink, M.; Himmerlich, M.; Krischok, S.; Kröger, J.

    2018-01-01

    Inelastic electron scattering is used to study surface phonon polaritons on H-covered and clean GaN(1 1 bar 00) surfaces. The Fuchs-Kliewer phonon of GaN(1 1 bar 00) -H gives rise to characteristic signatures of its single and multiple excitation in specular electron energy loss spectra. The loss intensities for multi-phonon scattering processes decrease according to a Poisson distribution. Vibrational spectra of this surface are invariant on the time scale of days reflecting its chemical passivation by the H layer. In contrast, vibrational spectra of pristine GaN(1 1 bar 00) are subject to a pronounced temporal evolution where spectroscopic weight is gradually shifted towards the multiple excitation of the Fuchs-Kliewer phonon. As a consequence, the monotonous decrease of the cross section for multiple quantum excitation as observed for the H-covered surface is not applicable. This remarkable effect is particularly strong in spectra acquired at low primary energies of incident electrons, which hints at processes occurring in the very surface region. Scenarios that may contribute to these observations are discussed.

  19. Coherent phonon optics in a chip with an electrically controlled active device.

    Science.gov (United States)

    Poyser, Caroline L; Akimov, Andrey V; Campion, Richard P; Kent, Anthony J

    2015-02-05

    Phonon optics concerns operations with high-frequency acoustic waves in solid media in a similar way to how traditional optics operates with the light beams (i.e. photons). Phonon optics experiments with coherent terahertz and sub-terahertz phonons promise a revolution in various technical applications related to high-frequency acoustics, imaging, and heat transport. Previously, phonon optics used passive methods for manipulations with propagating phonon beams that did not enable their external control. Here we fabricate a phononic chip, which includes a generator of coherent monochromatic phonons with frequency 378 GHz, a sensitive coherent phonon detector, and an active layer: a doped semiconductor superlattice, with electrical contacts, inserted into the phonon propagation path. In the experiments, we demonstrate the modulation of the coherent phonon flux by an external electrical bias applied to the active layer. Phonon optics using external control broadens the spectrum of prospective applications of phononics on the nanometer scale.

  20. Tight control of light trapping in surface addressable photonic crystal membranes: application to spectrally and spatially selective optical devices (Conference Presentation)

    Science.gov (United States)

    Letartre, Xavier; Blanchard, Cédric; Grillet, Christian; Jamois, Cécile; Leclercq, Jean-Louis; Viktorovitch, Pierre

    2016-04-01

    Surface addressable Photonic Crystal Membranes (PCM) are 1D or 2D photonic crystals formed in a slab waveguides where Bloch modes located above the light line are exploited. These modes are responsible for resonances in the reflection spectrum whose bandwidth can be adjusted at will. These resonances result from the coupling between a guided mode of the membrane and a free-space mode through the pattern of the photonic crystal. If broadband, these structures represent an ideal mirror to form compact vertical microcavity with 3D confinement of photons and polarization selectivity. Among numerous devices, low threshold VCSELs with remarkable and tunable modal properties have been demonstrated. Narrow band PCMs (or high Q resonators) have also been extensively used for surface addressable optoelectronic devices where an active material is embedded into the membrane, leading to the demonstration of low threshold surface emitting lasers, nonlinear bistables, optical traps... In this presentation, we will describe the main physical rules which govern the lifetime of photons in these resonant modes. More specifically, it will be emphasized that the Q factor of the PCM is determined, to the first order, by the integral overlap between the electromagnetic field distributions of the guided and free space modes and of the dielectric periodic perturbation which is applied to the homogeneous membrane to get the photonic crystal. It turns out that the symmetries of these distributions are of prime importance for the strength of the resonance. It will be shown that, by molding in-plane or vertical symmetries of Bloch modes, spectrally and spatially selective light absorbers or emitters can be designed. First proof of concept devices will be also presented.

  1. Interface optical phonons and their electron-phonon interactions in ZnS/CdS multi-shell spherical quantum dots

    Science.gov (United States)

    Huang, Wen Deng; Bao, Li Fu; Ren, Ya Jie; Yuan, Zhao Lin

    2018-04-01

    The properties of interface optical phonons and their electron-phonon interactions in ZnS/CdS multi-shell spherical quantum dots are studied by adopting dielectric continuum model. The dispersion curves and electron-phonon coupling strengths for interface optical phonons in ZnS/CdS multi-shell dots are calculated and analyzed in detail. It is shown that the number of interface optical phonon branches increase with the increase of layers of multi-shell quantum dots. The number of interface optical phonons increase two branches for increasing one layer material. The dispersions of interface optical phonon with low quantum number l are weak. The electron-interface optical phonon interactions are mainly localized at hetero-interfaces. The interface optical phonons with low quantum number l have important contribution to electron-interface optical phonon interactions.

  2. Phonon hydrodynamics and its applications in nanoscale heat transport

    Science.gov (United States)

    Guo, Yangyu; Wang, Moran

    2015-09-01

    Phonon hydrodynamics is an effective macroscopic method to study heat transport in dielectric solid and semiconductor. It has a clear and intuitive physical picture, transforming the abstract and ambiguous heat transport process into a concrete and evident process of phonon gas flow. Furthermore, with the aid of the abundant models and methods developed in classical hydrodynamics, phonon hydrodynamics becomes much easier to implement in comparison to the current popular approaches based on the first-principle method and kinetic theories involving complicated computations. Therefore, it is a promising tool for studying micro- and nanoscale heat transport in rapidly developing micro and nano science and technology. However, there still lacks a comprehensive account of the theoretical foundations, development and implementation of this approach. This work represents such an attempt in providing a full landscape, from physical fundamental and kinetic theory of phonons to phonon hydrodynamics in view of descriptions of phonon systems at microscopic, mesoscopic and macroscopic levels. Thus a systematical kinetic framework, summing up so far scattered theoretical models and methods in phonon hydrodynamics as individual cases, is established through a frame of a Chapman-Enskog solution to phonon Boltzmann equation. Then the basic tenets and procedures in implementing phonon hydrodynamics in nanoscale heat transport are presented through a review of its recent wide applications in modeling thermal transport properties of nanostructures. Finally, we discuss some pending questions and perspectives highlighted by a novel concept of generalized phonon hydrodynamics and possible applications in micro/nano phononics, which will shed more light on more profound understanding and credible applications of this new approach in micro- and nanoscale heat transport science.

  3. Relaxation of strongly coupled electron and phonon fields after photoemission and high-energy part of ARPES spectra of cuprates

    Science.gov (United States)

    Myasnikova, A. E.; Zhileeva, E. A.; Moseykin, D. V.

    2018-03-01

    An approach to considering systems with a high concentration of correlated carriers and strong long-range electron–phonon interaction and to calculating the high-energy part of the angle-resolved photoemission spectroscopy (ARPES) spectra of such systems is suggested. Joint relaxation of strongly coupled fields—a field of correlated electrons and phonon field—after photoemission is studied to clarify the nature of characteristic features observed in the high-energy part of the ARPES spectra of cuprate superconductors. Such relaxation occurs in systems with strong predominantly long-range electron–phonon interaction at sufficiently high carrier concentration due to the coexistence of autolocalized and delocalized carriers. A simple method to calculate analytically a high-energy part of the ARPES spectrum arising is proposed. It takes advantage of using the coherent states basis for the phonon field in the polaron and bipolaron states. The approach suggested yields all the high-energy spectral features like broad Gaussian band and regions of ‘vertical dispersion’ being in good quantitative agreement with the experiments on cuprates at any doping with both types of carriers. Demonstrated coexistence of autolocalized and delocalized carriers in superconducting cuprates changes the idea about their ground state above the superconducting transition temperature that is important for understanding transport and magnetic properties. High density of large-radius autolocalized carriers revealed may be a key to the explanation of charge ordering in doped cuprates.

  4. Large scale phononic metamaterials for seismic isolation

    Energy Technology Data Exchange (ETDEWEB)

    Aravantinos-Zafiris, N. [Department of Sound and Musical Instruments Technology, Ionian Islands Technological Educational Institute, Stylianou Typaldou ave., Lixouri 28200 (Greece); Sigalas, M. M. [Department of Materials Science, University of Patras, Patras 26504 (Greece)

    2015-08-14

    In this work, we numerically examine structures that could be characterized as large scale phononic metamaterials. These novel structures could have band gaps in the frequency spectrum of seismic waves when their dimensions are chosen appropriately, thus raising the belief that they could be serious candidates for seismic isolation structures. Different and easy to fabricate structures were examined made from construction materials such as concrete and steel. The well-known finite difference time domain method is used in our calculations in order to calculate the band structures of the proposed metamaterials.

  5. Parity-Time Synthetic Phononic Media

    DEFF Research Database (Denmark)

    Christensen, Johan; Willatzen, Morten; Velasco, V. R.

    2016-01-01

    media, have been devised in many optical systems with the ground breaking potential to create nonreciprocal structures and one-way cloaks of invisibility. Here we demonstrate a feasible approach for the case of sound where the most important ingredients within synthetic materials, loss and gain......, are achieved through electrically biased piezoelectric semiconductors. We study first how wave attenuation and amplification can be tuned, and when combined, can give rise to a phononic PT synthetic media with unidirectional suppressed reflectance, a feature directly applicable to evading sonar detection....

  6. Nonlinear Phononic Periodic Structures and Granular Crystals

    Science.gov (United States)

    2012-02-10

    in crystalline solids. Physical Review B, 2001. 64(6): p. 064302. 18. Maris, H.J. and S. Tamura, Propagation of acoustic phonon solitons in... mathematics . American Scientist, 2009. 97(6). 28. Duncan, D.B., et al., SOLITONS ON LATTICES. Physica D, 1993. 68(1): p. 1-11. 29. Kartashov, Y.V., B.A...Malomed, and L. Torner, Solitons in nonlinear lattices. Reviews of Modern Physics , 2011. 83(1): p. 247. 30. Kevrekidis, P.G., Non-linear waves in

  7. Large scale phononic metamaterials for seismic isolation

    International Nuclear Information System (INIS)

    Aravantinos-Zafiris, N.; Sigalas, M. M.

    2015-01-01

    In this work, we numerically examine structures that could be characterized as large scale phononic metamaterials. These novel structures could have band gaps in the frequency spectrum of seismic waves when their dimensions are chosen appropriately, thus raising the belief that they could be serious candidates for seismic isolation structures. Different and easy to fabricate structures were examined made from construction materials such as concrete and steel. The well-known finite difference time domain method is used in our calculations in order to calculate the band structures of the proposed metamaterials

  8. Phononic crystals bring sound to a focus

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez-Dehesa, Jose

    2004-09-01

    Three years ago researchers at the University of California at San Diego created a storm in the world of optics when they announced that they had made a material that exhibited negative refraction. Light rays entering such a 'negative index' material are not bent towards the normal -- as happens in all known materials in nature -- but beyond the normal. Now physicists in China and Canada have demonstrated the equivalent phenomenon with sound waves in a material known as a 'phononic crystal'. (U.K.)

  9. Phononic Crystal Made of Multilayered Ridges on a Substrate for Rayleigh Waves Manipulation

    Directory of Open Access Journals (Sweden)

    Mourad Oudich

    2017-12-01

    Full Text Available We present a phononic crystal to achieve efficient manipulation of surface acoustic waves (SAW. The structure is made of finite phononic micro-ridges arranged periodically in a substrate surface. Each ridge is constructed by staking silicon and tungsten layers so that it behaves as one-dimensional phononic crystal which exhibits band gaps for elastic waves. The band gap allows the existence of resonance modes where the elastic energy is either confined within units in the free end of the ridge or the ones in contact with the substrate. We show that SAW interaction with localized modes in the free surface of the ridge gives rise to sharp attenuation in the SAW transmission, while the modes confined within the ridge/substrate interface cause broad band attenuations of SAW. Furthermore, we demonstrate that the coupling between the two kinds of modes within the band gap gives high SAW transmission amplitude in the form of Fano-like peaks with high quality factor. The structure could provide an interesting solution for accurate SAW control for sensing applications, for instance.

  10. Blue and red shifted temperature dependence of implicit phonon shifts in graphene

    Science.gov (United States)

    Mann, Sarita; Jindal, V. K.

    2017-07-01

    We have calculated the implicit shift for various modes of frequency in a pure graphene sheet. Thermal expansion and Grüneisen parameter which are required for implicit shift calculation have already been studied and reported. For this calculation, phonon frequencies are obtained using force constants derived from dynamical matrix calculated using VASP code where the density functional perturbation theory (DFPT) is used in interface with phonopy software. The implicit phonon shift shows an unusual behavior as compared to the bulk materials. The frequency shift is large negative (red shift) for ZA and ZO modes and the value of negative shift increases with increase in temperature. On the other hand, blue shift arises for all other longitudinal and transverse modes with a similar trend of increase with increase in temperature. The q dependence of phonon shifts has also been studied. Such simultaneous red and blue shifts in transverse or out plane modes and surface modes, respectively leads to speculation of surface softening in out of plane direction in preference to surface melting.

  11. Derivation of the canopy conductance from surface temperature and spectral indices for estimating evapotranspiration in semiarid vegetation; Monitorizacion de conductancia en vegetacion semiarida a partir de indices espectrales y temperatura de supeficie

    Energy Technology Data Exchange (ETDEWEB)

    Morillas, L.; Garcia, M.; Zarco-Tejada, P.; Ladron de Guevara, M.; Villagarcia, L.; Were, A.; Domingo, F.

    2009-07-01

    This work evaluates the possibilities for estimating stomata conductance (C) and leaf transpiration (Trf) at the ecosystem scale from radiometric indices and surface temperature. The relationships found between indices and the transpiration component of the water balance in a semiarid tussock ecosystem in SE Spain are discussed. Field data were collected from spring 2008 until winter 2009 in order to observe the annual variability of the relationships and the behaviour of spectral indices and surface temperature. (Author) 11 refs.

  12. Confinement of acoustical modes due to the electron-phonon interaction within 2D-electron gas

    International Nuclear Information System (INIS)

    Kochelap, V.A.; Gulseren, O.

    1992-09-01

    We study the confinement of acoustical modes within 2DEG due only to the electron-phonon interaction. The confined modes split out from the bulk phonons even at uniform lattice parameters, when the 2DEG is created by means of modulation doping. The effect is more pronounced when the wave vector q of the modes increases and is maximum at q = 2 k F (k F is the Fermi wave vector). In the case of several electron sheets the additional features of the confinement effect appear. In the limit of the strong electron-phonon coupling and high surface concentration of the electrons the considered system can suffer Peierls-type phase transition. In this case periodical deformation of the lattice and charge density wave are confined within the electron sheet. (author). 18 refs, 2 figs

  13. One- and two-phonon capture processes in quantum dots

    DEFF Research Database (Denmark)

    Magnúsdóttir, Ingibjörg; Uskov, Alexander; Bischoff, Svend

    2002-01-01

    Multiphonon capture processes are investigated theoretically and found to contribute efficiently to the carrier injection into quantum dots. It is shown that two-phonon capture contributes where single-phonon capture is energetically inhibited and can lead to electron capture times of a few...

  14. Modelling exciton–phonon interactions in optically driven quantum dots

    DEFF Research Database (Denmark)

    Nazir, Ahsan; McCutcheon, Dara

    2016-01-01

    We provide a self-contained review of master equation approaches to modelling phonon effects in optically driven self-assembled quantum dots. Coupling of the (quasi) two-level excitonic system to phonons leads to dissipation and dephasing, the rates of which depend on the excitation conditions...

  15. Phonon thermal transport through tilt grain boundaries in strontium titanate

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Zexi; Chen, Xiang; Yang, Shengfeng; Xiong, Liming; Chen, Youping [Department of Mechanical and Aerospace Engineering, University of Florida, Gainesville, Florida 32611 (United States); Deng, Bowen; Chernatynskiy, Aleksandr [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States)

    2014-08-21

    In this work, we perform nonequilibrium molecular dynamics simulations to study phonon scattering at two tilt grain boundaries (GBs) in SrTiO{sub 3}. Mode-wise energy transmission coefficients are obtained based on phonon wave-packet dynamics simulations. The Kapitza conductance is then quantified using a lattice dynamics approach. The obtained results of the Kapitza conductance of both GBs compare well with those obtained by the direct method, except for the temperature dependence. Contrary to common belief, the results of this work show that the optical modes in SrTiO{sub 3} contribute significantly to phonon thermal transport, accounting for over 50% of the Kapitza conductance. To understand the effect of the GB structural disorder on phonon transport, we compare the local phonon density of states of the atoms in the GB region with that in the single crystalline grain region. Our results show that the excess vibrational modes introduced by the structural disorder do not have a significant effect on phonon scattering at the GBs, but the absence of certain modes in the GB region appears to be responsible for phonon reflections at GBs. This work has also demonstrated phonon mode conversion and simultaneous generation of new modes. Some of the new modes have the same frequency as the initial wave packet, while some have the same wave vector but lower frequencies.

  16. Phonons and charge-transfer excitations in HTS superconductors

    International Nuclear Information System (INIS)

    Bishop, A.R.

    1989-01-01

    Some of the experimental and theoretical evidence implicating phonons and charge-transfer excitations in HTS superconductors is reviewed. It is suggested that superconductivity may be driven by a synergistic interplay of (anharmonic) phonons and electronic degrees of freedom (e.g., charge fluctuations, excitons). 47 refs., 5 figs

  17. Phonon thermal transport through tilt grain boundaries in strontium titanate

    International Nuclear Information System (INIS)

    Zheng, Zexi; Chen, Xiang; Yang, Shengfeng; Xiong, Liming; Chen, Youping; Deng, Bowen; Chernatynskiy, Aleksandr

    2014-01-01

    In this work, we perform nonequilibrium molecular dynamics simulations to study phonon scattering at two tilt grain boundaries (GBs) in SrTiO 3 . Mode-wise energy transmission coefficients are obtained based on phonon wave-packet dynamics simulations. The Kapitza conductance is then quantified using a lattice dynamics approach. The obtained results of the Kapitza conductance of both GBs compare well with those obtained by the direct method, except for the temperature dependence. Contrary to common belief, the results of this work show that the optical modes in SrTiO 3 contribute significantly to phonon thermal transport, accounting for over 50% of the Kapitza conductance. To understand the effect of the GB structural disorder on phonon transport, we compare the local phonon density of states of the atoms in the GB region with that in the single crystalline grain region. Our results show that the excess vibrational modes introduced by the structural disorder do not have a significant effect on phonon scattering at the GBs, but the absence of certain modes in the GB region appears to be responsible for phonon reflections at GBs. This work has also demonstrated phonon mode conversion and simultaneous generation of new modes. Some of the new modes have the same frequency as the initial wave packet, while some have the same wave vector but lower frequencies

  18. Investigation of quasi-one-dimensional finite phononic crystal with ...

    Indian Academy of Sciences (India)

    the results analysed by the finite element software, ANSYS. We hope that the results will be helpful in practical applications of phononic crystals. Keywords. Finite phononic crystal; band gap; frequency-response functions. PACS Nos 43.20.+g; 43.40.+s; 63.20.−e. 1. Introduction. In recent years, the propagation of classical ...

  19. Stimulated emission of phonons in an acoustic cavity

    NARCIS (Netherlands)

    Tilstra, Lieuwe Gijsbert

    2001-01-01

    This thesis will present experiments on stimulated emission of phonons in dilute ruby following complete population inversion of the Zeeman-split E(2E) Kramers doublet by selective pulsed optical pumping into its upper component. The resulting phonon avalanches are detected by use of the R1

  20. Multiple interruption of optically generated acoustic phonons in ruby

    International Nuclear Information System (INIS)

    Dijkhuis, J.I.

    1979-01-01

    This thesis clarifies the rate-determining processes which tend to equilibrate the bottlenecked 29 cm -1 phonons with the temperature bath in stationary experiments. In addition, the direct relaxation between the Zeeman components of E is measured, revealing at high pumping, both continuous and time-resolved, a strong phonon bottleneck. (Auth.)

  1. Phonon localization transition in relaxor ferroelectric PZN-5%PT

    International Nuclear Information System (INIS)

    Manley, Michael E.; Christianson, Andrew D.; Abernathy, Douglas L.; Sahul, Raffi

    2017-01-01

    Relaxor ferroelectric behavior occurs in many disordered ferroelectric materials but is not well understood at the atomic level. Recent experiments and theoretical arguments indicate that Anderson localization of phonons instigates relaxor behavior by driving the formation of polar nanoregions (PNRs). Here, we use inelastic neutron scattering to observe phonon localization in relaxor ferroelectric PZN-5%PT (0.95[Pb(Zn 1/3 Nb 2/3 )O 3 ]–0.05PbTiO 3 ) and detect additional features of the localization process. In the lead, up to phonon localization on cooling, the local resonant modes that drive phonon localization increase in number. The increase in resonant scattering centers is attributed to a known increase in the number of locally off centered Pb atoms on cooling. The transition to phonon localization occurs when these random scattering centers increase to a concentration where the Ioffe-Regel criterion is satisfied for localizing the phonon. Finally, we also model the effects of damped mode coupling on the observed phonons and phonon localization structure.

  2. Remarkable reduction of thermal conductivity in phosphorene phononic crystal.

    Science.gov (United States)

    Xu, Wen; Zhang, Gang

    2016-05-05

    Phosphorene has received much attention due to its interesting physical and chemical properties, and its potential applications such as thermoelectricity. In thermoelectric applications, low thermal conductivity is essential for achieving a high figure of merit. In this work, we propose to reduce the thermal conductivity of phosphorene by adopting the phononic crystal structure, phosphorene nanomesh. With equilibrium molecular dynamics simulations, we find that the thermal conductivity is remarkably reduced in the phononic crystal. Our analysis shows that the reduction is due to the depressed phonon group velocities induced by Brillouin zone folding, and the reduced phonon lifetimes in the phononic crystal. Interestingly, it is found that the anisotropy ratio of thermal conductivity could be tuned by the 'non-square' pores in the phononic crystal, as the phonon group velocities in the direction with larger projection of pores is more severely suppressed, leading to greater reduction of thermal conductivity in this direction. Our work provides deep insight into thermal transport in phononic crystals and proposes a new strategy to reduce the thermal conductivity of monolayer phosphorene.

  3. Colloquium: Phononics: Manipulating heat flow with electronic analogs and beyond

    Science.gov (United States)

    Li, Nianbei; Ren, Jie; Wang, Lei; Zhang, Gang; Hänggi, Peter; Li, Baowen

    2012-07-01

    The form of energy termed heat that typically derives from lattice vibrations, i.e., phonons, is usually considered as waste energy and, moreover, deleterious to information processing. However, in this Colloquium, an attempt is made to rebut this common view: By use of tailored models it is demonstrated that phonons can be manipulated similarly to electrons and photons, thus enabling controlled heat transport. Moreover, it is explained that phonons can be put to beneficial use to carry and process information. In the first part ways are presented to control heat transport and to process information for physical systems which are driven by a temperature bias. In particular, a toolkit of familiar electronic analogs for use of phononics is put forward, i.e., phononic devices are described which act as thermal diodes, thermal transistors, thermal logic gates, and thermal memories. These concepts are then put to work to transport, control, and rectify heat in physically realistic nanosystems by devising practical designs of hybrid nanostructures that permit the operation of functional phononic devices; the first experimental realizations are also reported. Next, richer possibilities to manipulate heat flow by use of time-varying thermal bath temperatures or various other external fields are discussed. These give rise to many intriguing phononic nonequilibrium phenomena such as, for example, the directed shuttling of heat, geometrical phase-induced heat pumping, or the phonon Hall effect, which may all find their way into operation with electronic analogs.

  4. Strong Carrier-Phonon Coupling in Lead Halide Perovskite Nanocrystals

    NARCIS (Netherlands)

    Iaru, Claudiu M; Geuchies, Jaco J|info:eu-repo/dai/nl/370526090; Koenraad, Paul M; Vanmaekelbergh, Daniël|info:eu-repo/dai/nl/304829137; Silov, Andrei Yu

    2017-01-01

    We highlight the importance of carrier-phonon coupling in inorganic lead halide perovskite nanocrystals. The low-temperature photoluminescence (PL) spectrum of CsPbBr3 has been investigated under a nonresonant and a nonstandard, quasi-resonant excitation scheme, and phonon replicas of the main PL

  5. Phonon and thermal properties of achiral single wall carbon ...

    Indian Academy of Sciences (India)

    A detailed theoretical study of the phonon and thermal properties of achiral single wall carbon nanotubes has been carried out using force constant model considering up to third nearest-neighbor interactions. We have calculated the phonon dispersions, density of states, radial breathing modes (RBM) and the specific heats ...

  6. Time-resolved spectral characterization of ring cavity surface emitting and ridge-type distributed feedback quantum cascade lasers by step-scan FT-IR spectroscopy.

    Science.gov (United States)

    Brandstetter, Markus; Genner, Andreas; Schwarzer, Clemens; Mujagic, Elvis; Strasser, Gottfried; Lendl, Bernhard

    2014-02-10

    We present the time-resolved comparison of pulsed 2nd order ring cavity surface emitting (RCSE) quantum cascade lasers (QCLs) and pulsed 1st order ridge-type distributed feedback (DFB) QCLs using a step-scan Fourier transform infrared (FT-IR) spectrometer. Laser devices were part of QCL arrays and fabricated from the same laser material. Required grating periods were adjusted to account for the grating order. The step-scan technique provided a spectral resolution of 0.1 cm(-1) and a time resolution of 2 ns. As a result, it was possible to gain information about the tuning behavior and potential mode-hops of the investigated lasers. Different cavity-lengths were compared, including 0.9 mm and 3.2 mm long ridge-type and 0.97 mm (circumference) ring-type cavities. RCSE QCLs were found to have improved emission properties in terms of line-stability, tuning rate and maximum emission time compared to ridge-type lasers.

  7. Observation of a phononic quadrupole topological insulator

    Science.gov (United States)

    Serra-Garcia, Marc; Peri, Valerio; Süsstrunk, Roman; Bilal, Osama R.; Larsen, Tom; Villanueva, Luis Guillermo; Huber, Sebastian D.

    2018-03-01

    The modern theory of charge polarization in solids is based on a generalization of Berry’s phase. The possibility of the quantization of this phase arising from parallel transport in momentum space is essential to our understanding of systems with topological band structures. Although based on the concept of charge polarization, this same theory can also be used to characterize the Bloch bands of neutral bosonic systems such as photonic or phononic crystals. The theory of this quantized polarization has recently been extended from the dipole moment to higher multipole moments. In particular, a two-dimensional quantized quadrupole insulator is predicted to have gapped yet topological one-dimensional edge modes, which stabilize zero-dimensional in-gap corner states. However, such a state of matter has not previously been observed experimentally. Here we report measurements of a phononic quadrupole topological insulator. We experimentally characterize the bulk, edge and corner physics of a mechanical metamaterial (a material with tailored mechanical properties) and find the predicted gapped edge and in-gap corner states. We corroborate our findings by comparing the mechanical properties of a topologically non-trivial system to samples in other phases that are predicted by the quadrupole theory. These topological corner states are an important stepping stone to the experimental realization of topologically protected wave guides in higher dimensions, and thereby open up a new path for the design of metamaterials.

  8. Phonon bottleneck identification in disordered nanoporous materials

    Science.gov (United States)

    Romano, Giuseppe; Grossman, Jeffrey C.

    2017-09-01

    Nanoporous materials are a promising platform for thermoelectrics in that they offer high thermal conductivity tunability while preserving good electrical properties, a crucial requirement for high-efficiency thermal energy conversion. Understanding the impact of the pore arrangement on thermal transport is pivotal to engineering realistic materials, where pore disorder is unavoidable. Although there has been considerable progress in modeling thermal size effects in nanostructures, it has remained a challenge to screen such materials over a large phase space due to the slow simulation time required for accurate results. We use density functional theory in connection with the Boltzmann transport equation to perform calculations of thermal conductivity in disordered porous materials. By leveraging graph theory and regressive analysis, we identify the set of pores representing the phonon bottleneck and obtain a descriptor for thermal transport, based on the sum of the pore-pore distances between such pores. This approach provide a simple tool to estimate phonon suppression in realistic porous materials for thermoelectric applications and enhance our understanding of heat transport in disordered materials.

  9. Controllable photon and phonon localization in optomechanical Lieb lattices.

    Science.gov (United States)

    Wan, Liang-Liang; Lü, Xin-You; Gao, Jin-Hua; Wu, Ying

    2017-07-24

    The Lieb lattice featuring flat band is not only important in strongly-correlated many-body physics, but also can be utilized to inspire new quantum devices. Here we propose an optomechanical Lieb lattice, where the flat-band physics of photon-phonon polaritons is demonstrated. The tunability of the band structure of the optomechanical arrays allows one to obtain an approximate photon or phonon flat band as well as the transition between them. This ultimately leads to the result that the controllable photon or phonon localization could be realized by the path interference effects. This study offers an alternative approach to explore the exotic photon and phonon many-body effects, which has potential applications in the future hybrid-photon-phonon quantum network and engineering new type solid-state quantum devices.

  10. Thermal rectification based on phonon hydrodynamics and thermomass theory

    Directory of Open Access Journals (Sweden)

    Dong Yuan

    2016-06-01

    Full Text Available The thermal diode is the fundamental device for phononics. There are various mechanisms for thermal rectification, e.g. different temperature dependent thermal conductivity of two ends, asymmetric interfacial resistance, and nonlocal behavior of phonon transport in asymmetric structures. The phonon hydrodynamics and thermomass theory treat the heat conduction in a fluidic viewpoint. The phonon gas flowing through the media is characterized by the balance equation of momentum, like the Navier-Stokes equation for fluid mechanics. Generalized heat conduction law thereby contains the spatial acceleration (convection term and the viscous (Laplacian term. The viscous term predicts the size dependent thermal conductivity. Rectification appears due to the MFP supersession of phonons. The convection term also predicts rectification because of the inertia effect, like a gas passing through a nozzle or diffuser.

  11. Controlling elastic waves with small phononic crystals containing rigid inclusions

    KAUST Repository

    Peng, Pai

    2014-05-01

    We show that a two-dimensional elastic phononic crystal comprising rigid cylinders in a solid matrix possesses a large complete band gap below a cut-off frequency. A mechanical model reveals that the band gap is induced by negative effective mass density, which is affirmed by an effective medium theory based on field averaging. We demonstrate, by two examples, that such elastic phononic crystals can be utilized to design small devices to control low-frequency elastic waves. One example is a waveguide made of a two-layer anisotropic elastic phononic crystal, which can guide and bend elastic waves with wavelengths much larger than the size of the waveguide. The other example is the enhanced elastic transmission of a single-layer elastic phononic crystal loaded with solid inclusions. The effective mass density and reciprocal of the modulus of the single-layer elastic phononic crystal are simultaneously near zero. © CopyrightEPLA, 2014.

  12. Phonon squeezed states: quantum noise reduction in solids

    Science.gov (United States)

    Hu, Xuedong; Nori, Franco

    1999-03-01

    This article discusses quantum fluctuation properties of a crystal lattice, and in particular, phonon squeezed states. Squeezed states of phonons allow a reduction in the quantum fluctuations of the atomic displacements to below the zero-point quantum noise level of coherent phonon states. Here we discuss our studies of both continuous-wave and impulsive second-order Raman scattering mechanisms. The later approach was used to experimentally suppress (by one part in a million) fluctuations in phonons. We calculate the expectation values and fluctuations of both the atomic displacement and the lattice amplitude operators, as well as the effects of the phonon squeezed states on macroscopically measurable quantities, such as changes in the dielectric constant. These results are compared with recent experiments. Further information, including preprints and animations, are available in http://www-personal.engin.umich.edu/∼nori/squeezed.html.

  13. Search for the 3-phonon state of 40Ca

    International Nuclear Information System (INIS)

    Fallot, M.

    2002-09-01

    We study collective vibrational states of the nucleus: giant resonances and multiphonon states. It has been shown that multiphonon states, which are built with several superimposed giant resonances, can be excited in inelastic heavy ion scattering near the grazing angle. No three photon states have been observed until now. An experiment has been performed at GANIL, aiming at the observation of the 3-phonon state built with the giant quadrupole resonance (GQR) in 40 Ca, with the reaction 40 Ca + 40 Ca at 50 A.Me.V. The ejectile was identified in the SPEG spectrometer. Light charged particles were detected in 240 CsI scintillators of the INDRA 4π array. The analysis confirms the previous results about the GQR and the 2-phonon state in 40 Ca. For the first time, we have measured an important direct decay branch of the GQR by alpha particles. Applying the so-called 'missing energy method' to events containing three protons measured in coincidence with the ejectile, we observe a direct decay branch revealing the presence of a 3-phonon state in the excitation energy region expected for the triple GQR. Dynamical processes are also studied in the inelastic channel, emphasizing a recently discovered mechanism named towing-mode. We observe for the first time the towing-mode of alpha particles. The energies of multiphonon states in 40 Ca and 208 Pb have been computed microscopically including some anharmonicities via boson mapping methods. The basis of the calculation has been extended to the 3-phonon states. Our results show large anharmonicities (several MeV), due to the coupling of 3-phonon states to 2-phonon states. The extension of the basis to 4-phonon states has been performed for the first time. The inclusion of the 4 phonon states in the calculation did not affect the previous observations concerning the 2-phonon states. Preliminary results on the anharmonicities of the 3-phonon states are presented. (author)

  14. Analysis of Lattice Thermal Conductivity of Si Considering the Effect of Phonon Dispersion on Three-phonon Processes

    Science.gov (United States)

    He, Ping; Li, Zhijian

    2001-03-01

    In this work we present the new relaxation time expressions considering the detailed information of the phonon dispersion. For the three-phonon processes, it is found that only limited types of three-phonon processes are allowed to occur and the attenuation of phonon that conduct heat varies roughly with the fifth power of frequency. By using these expressions, the data of thermal conductivity of bulk silicon is well fitted. And further, the data for thin films of single crystal silicon which cannot be well fitted by the widely used model that proposed by Holland is also well fitted using the new expressions for three-phonon processes and parameters got at the previous step.

  15. Probing electronic phase transitions with phonons via inelastic neutron scattering: superconductivity in borocarbides, charge and magnetic order in manganites

    International Nuclear Information System (INIS)

    Weber, F.

    2007-01-01

    The present thesis concentrates on the signatures of strong electron-phonon coupling in phonon properties measured by inelastic neutron scattering. The inelastic neutron scattering experiments were performed on the triple-axis spectrometers 1T and DAS PUMA at the research reactors in Saclay (France) and Munich (Germany), respectively. The work is subdivided into two separate chapters: In the first part, we report measurements of the lattice dynamical properties, i.e. phonon frequency, linewidth and intensity, of the conventional, i.e. phonon-mediated, superconductor YNi 2 B 2 C of the rare-earth-borocarbide family. The detailed check of theoretical predictions for these properties, which were calculated in the theory group of our institute, was one major goal of this work. We measured phonons in the normal state, i.e. T>T c , for several high symmetry directions up to 70 meV. We were able to extract the full temperature dependence of the superconducting energy gap 2Δ(T) from our phonon scans with such accuracy that even deviations from the weak coupling BCS behaviour could be clearly observed. By measuring phonons at different wave vectors we demonstrated that phonons are sensitive to the gap anisotropy under the precondition, that different phonons get their coupling strength from different parts of the Fermi surface. In the second part, we investigated the properties of Mn-O bond-stretching phonons in the bilayer manganite La 2-2x Sr 1+2x Mn 2 O 7 . At the doping level x=0.38 this compound has an ferromagnetic groundstate and exhibits the so-called colossal magnetoresistance effect in the vicinity of the Curie temperature T C . The atomic displacement patterns of the investigated phonons closely resemble possible Jahn-Teller distortions of the MnO 6 octahedra, which are introduced in this compound by the Jahn-Teller active Mn 3+ ions. We observed strong renormalizations of the phonon frequencies and clear peaks of the intrinsic phonon linewidth near the order

  16. Probing electronic phase transitions with phonons via inelastic neutron scattering: superconductivity in borocarbides, charge and magnetic order in manganites

    Energy Technology Data Exchange (ETDEWEB)

    Weber, F.

    2007-11-02

    The present thesis concentrates on the signatures of strong electron-phonon coupling in phonon properties measured by inelastic neutron scattering. The inelastic neutron scattering experiments were performed on the triple-axis spectrometers 1T and DAS PUMA at the research reactors in Saclay (France) and Munich (Germany), respectively. The work is subdivided into two separate chapters: In the first part, we report measurements of the lattice dynamical properties, i.e. phonon frequency, linewidth and intensity, of the conventional, i.e. phonon-mediated, superconductor YNi{sub 2}B{sub 2}C of the rare-earth-borocarbide family. The detailed check of theoretical predictions for these properties, which were calculated in the theory group of our institute, was one major goal of this work. We measured phonons in the normal state, i.e. T>T{sub c}, for several high symmetry directions up to 70 meV. We were able to extract the full temperature dependence of the superconducting energy gap 2{delta}(T) from our phonon scans with such accuracy that even deviations from the weak coupling BCS behaviour could be clearly observed. By measuring phonons at different wave vectors we demonstrated that phonons are sensitive to the gap anisotropy under the precondition, that different phonons get their coupling strength from different parts of the Fermi surface. In the second part, we investigated the properties of Mn-O bond-stretching phonons in the bilayer manganite La{sub 2-2x}Sr{sub 1+2x}Mn{sub 2}O{sub 7}. At the doping level x=0.38 this compound has an ferromagnetic groundstate and exhibits the so-called colossal magnetoresistance effect in the vicinity of the Curie temperature T{sub C}. The atomic displacement patterns of the investigated phonons closely resemble possible Jahn-Teller distortions of the MnO{sub 6} octahedra, which are introduced in this compound by the Jahn-Teller active Mn{sup 3+} ions. We observed strong renormalizations of the phonon frequencies and clear peaks of

  17. Spectral Pollution

    OpenAIRE

    Davies, E B; Plum, M

    2003-01-01

    We discuss the problems arising when computing eigenvalues of self-adjoint operators which lie in a gap between two parts of the essential spectrum. Spectral pollution, i.e. the apparent existence of eigenvalues in numerical computations, when no such eigenvalues actually exist, is commonplace in problems arising in applied mathematics. We describe a geometrically inspired method which avoids this difficulty, and show that it yields the same results as an algorithm of Zimmermann and Mertins.

  18. Nonlocal Coulomb correlations in pure and electron-doped Sr2IrO4 : Spectral functions, Fermi surface, and pseudo-gap-like spectral weight distributions from oriented cluster dynamical mean-field theory

    Science.gov (United States)

    Martins, Cyril; Lenz, Benjamin; Perfetti, Luca; Brouet, Veronique; Bertran, François; Biermann, Silke

    2018-03-01

    We address the role of nonlocal Coulomb correlations and short-range magnetic fluctuations in the high-temperature phase of Sr2IrO4 within state-of-the-art spectroscopic and first-principles theoretical methods. Introducing an "oriented-cluster dynamical mean-field scheme", we compute momentum-resolved spectral functions, which we find to be in excellent agreement with angle-resolved photoemission spectra. We show that while short-range antiferromagnetic fluctuations are crucial to accounting for the electronic properties of Sr2IrO4 even in the high-temperature paramagnetic phase, long-range magnetic order is not a necessary ingredient of the insulating state. Upon doping, an exotic metallic state is generated, exhibiting cuprate-like pseudo-gap spectral properties, for which we propose a surprisingly simple theoretical mechanism.

  19. Phonon structures of GaN-based random semiconductor alloys

    Science.gov (United States)

    Zhou, Mei; Chen, Xiaobin; Li, Gang; Zheng, Fawei; Zhang, Ping

    2017-12-01

    Accurate modeling of thermal properties is strikingly important for developing next-generation electronics with high performance. Many thermal properties are closely related to phonon dispersions, such as sound velocity. However, random substituted semiconductor alloys AxB1-x usually lack translational symmetry, and simulation with periodic boundary conditions often requires large supercells, which makes phonon dispersion highly folded and hardly comparable with experimental results. Here, we adopt a large supercell with randomly distributed A and B atoms to investigate substitution effect on the phonon dispersions of semiconductor alloys systematically by using phonon unfolding method [F. Zheng, P. Zhang, Comput. Mater. Sci. 125, 218 (2016)]. The results reveal the extent to which phonon band characteristics in (In,Ga)N and Ga(N,P) are preserved or lost at different compositions and q points. Generally, most characteristics of phonon dispersions can be preserved with indium substitution of gallium in GaN, while substitution of nitrogen with phosphorus strongly perturbs the phonon dispersion of GaN, showing a rapid disintegration of the Bloch characteristics of optical modes and introducing localized impurity modes. In addition, the sound velocities of both (In,Ga)N and Ga(N,P) display a nearly linear behavior as a function of substitution compositions. Supplementary material in the form of one pdf file available from the Journal web page at http://https://doi.org/10.1140/epjb/e2017-80481-0.

  20. Cavity-type hypersonic phononic crystals

    International Nuclear Information System (INIS)

    Sato, A; Fytas, G; Pennec, Y; Djafari-Rouhani, B; Yanagishita, T; Masuda, H; Knoll, W

    2012-01-01

    We report on the engineering of the phonon dispersion diagram in monodomain anodic porous alumina (APA) films through the porosity and physical state of the material residing in the nanopores. Lattice symmetry and inclusion materials are theoretically identified to be the main factors which control the hypersonic acoustic wave propagation. This involves the interaction between the longitudinal and the transverse modes in the effective medium and a flat band characteristic of the material residing in the cavities. Air and filled nanopores, therefore, display markedly different dispersion relations and the inclusion materials lead to a locally resonant structural behavior uniquely determining their properties under confinement. APA films emerge as a new platform to investigate the rich acoustic phenomena of structured composite matter. (paper)

  1. Phonon modes in a disordered lattice

    International Nuclear Information System (INIS)

    Chakrabarti, B.K.; Roy, G.K.; Sinha, S.K.

    1979-01-01

    A simple cubic lattice, in which a small fraction of sites are replaced at random by atoms of a different kind and the resulting vibrational excitations are studied. Both the mass and force constant disorders are considered. The equation of motion of the Green function is developed following Matsubara and Yonezawa neglecting shear modes; the resulting expression for dispersion relation is summed up following Keneyashi and Jones to the lowest order in concentration. The results are obtained analytically and are found to be exact upto the linear term in concentration. Expressions have been obtained for the renormalised energies and the damping of the long wavelength phonon modes. In the special case of simple disorder, the results are compared with those of Langer. (K.B.)

  2. Double Dirac cones in phononic crystals

    KAUST Repository

    Li, Yan

    2014-07-07

    A double Dirac cone is realized at the center of the Brillouin zone of a two-dimensional phononic crystal (PC) consisting of a triangular array of core-shell-structure cylinders in water. The double Dirac cone is induced by the accidental degeneracy of two double-degenerate Bloch states. Using a perturbation method, we demonstrate that the double Dirac cone is composed of two identical and overlapping Dirac cones whose linear slopes can also be accurately predicted from the method. Because the double Dirac cone occurs at a relatively low frequency, a slab of the PC can be mapped onto a slab of zero refractive index material by using a standard retrieval method. Total transmission without phase change and energy tunneling at the double Dirac point frequency are unambiguously demonstrated by two examples. Potential applications can be expected in diverse fields such as acoustic wave manipulations and energy flow control.

  3. Phonon Screening in High-Temperature Superconductors

    International Nuclear Information System (INIS)

    Homes, C. C.; McConnell, A. W.; Clayman, B. P.; Bonn, D. A.; Liang, Ruixing; Hardy, W. N.; Inoue, M.; Negishi, H.; Fournier, P.; Greene, R. L.

    2000-01-01

    In good conductors optical phonons are usually screened, and therefore not observed. However, sharp features due to infrared-active modes in the copper-oxygen planes are observed in the optical conductivity of Pr 1.85 Ce 0.15 CuO 4 and YBa 2 Cu 3 O 6.95 . Oscillator strengths indicate that the screening of these modes is poor or totally absent. These materials are compared with η-Mo 4 O 11 , in which lattice modes appear suddenly below the charge-density wave transition. It is proposed that poor screening in the cuprates originates from fluctuating charge inhomogeneities in the copper-oxygen planes. (c) 2000 The American Physical Society

  4. Influence of pulse width and detuning on coherent phonon generation

    Science.gov (United States)

    Nakamura, Kazutaka G.; Shikano, Yutaka; Kayanuma, Yosuke

    2015-10-01

    We investigated the coherent phonon generation mechanism by irradiation of an ultrashort pulse with a simple two-level model. Our derived formulation shows that both impulsive stimulated Raman scattering (ISRS) and impulsive absorption (IA) simultaneously occur, and phonon wave packets are generated in the electronic ground and excited states by ISRS and IA, respectively. We identify the dominant process from the amplitude of the phonon oscillation. For short pulse widths, ISRS is very small and becomes larger as the pulse width increases. We also show that the initial phase is dependent on the pulse width and the detuning.

  5. Phononic frequency comb via three-mode parametric resonance

    Science.gov (United States)

    Ganesan, Adarsh; Do, Cuong; Seshia, Ashwin

    2018-01-01

    This paper is motivated by the recent demonstration of a phononic frequency comb. While previous experiments have shown the existence of a three-wave mixing pathway in a system of two-coupled phonon modes, this work demonstrates a similar pathway in a system of three-coupled phonon modes. This paper also presents a number of interesting experimental facts concomitant to the three-mode parametric resonance based frequency comb observed in a specific micromechanical device. The experimental validation of frequency combs via three-mode parametric resonance along with the previous demonstration of two-mode frequency combs points to the ultimate possibility of multimode frequency combs.

  6. Band structures in fractal grading porous phononic crystals

    Science.gov (United States)

    Wang, Kai; Liu, Ying; Liang, Tianshu; Wang, Bin

    2018-05-01

    In this paper, a new grading porous structure is introduced based on a Sierpinski triangle routine, and wave propagation in this fractal grading porous phononic crystal is investigated. The influences of fractal hierarchy and porosity on the band structures in fractal graidng porous phononic crystals are clarified. Vibration modes of unit cell at absolute band gap edges are given to manifest formation mechanism of absolute band gaps. The results show that absolute band gaps are easy to form in fractal structures comparatively to the normal ones with the same porosity. Structures with higher fractal hierarchies benefit multiple wider absolute band gaps. This work provides useful guidance in design of fractal porous phononic crystals.

  7. Resonant supercollisions and electron-phonon heat transfer in graphene

    Science.gov (United States)

    Tikhonov, K. S.; Gornyi, I. V.; Kachorovskii, V. Yu.; Mirlin, A. D.

    2018-02-01

    We study the effects of strong impurities on heat transfer in a coupled electron-phonon system in disordered graphene. A detailed analysis of the electron-phonon heat exchange assisted by such an impurity through the "resonant supercollision" mechanism is presented. We further explore the local modification of heat transfer in a weakly disordered graphene due to a resonant scatterer and determine spatial profiles of the phonon and electron temperature around the scatterer under electrical driving. Our results are consistent with recent experimental findings on imaging resonant dissipation from individual atomic defects.

  8. Flexural-Phonon Scattering Induced by Electrostatic Gating in Graphene

    DEFF Research Database (Denmark)

    Gunst, Tue; Kaasbjerg, Kristen; Brandbyge, Mads

    2017-01-01

    Graphene has an extremely high carrier mobility partly due to its planar mirror symmetry inhibiting scattering by the highly occupied acoustic flexural phonons. Electrostatic gating of a graphene device can break the planar mirror symmetry, yielding a coupling mechanism to the flexural phonons......-limiting factor, and show how the carrier density and temperature scaling of the mobility depends on the electrostatic environment. Our findings may explain the high deformation potential for in-plane acoustic phonons extracted from experiments and, furthermore, suggest a direct relation between device symmetry...

  9. Non-equilibrium phonon generation and detection in microstructure devices

    KAUST Repository

    Hertzberg, J. B.

    2011-01-01

    We demonstrate a method to excite locally a controllable, non-thermal distribution of acoustic phonon modes ranging from 0 to ∼200 GHz in a silicon microstructure, by decay of excited quasiparticle states in an attached superconducting tunnel junction (STJ). The phonons transiting the structure ballistically are detected by a second STJ, allowing comparison of direct with indirect transport pathways. This method may be applied to study how different phonon modes contribute to the thermal conductivity of nanostructures. © 2011 American Institute of Physics.

  10. Resonant Magnon-Phonon Polaritons in a Ferrimagnet

    Science.gov (United States)

    2000-09-29

    UNCLASSIFIED Defense Technical Information Center Compilation Part Notice ADPO 11604 TITLE: Resonant Magnon -Phonon Polaritons in a Ferrimagnet...part numbers comprise the compilation report: ADP011588 thru ADP011680 UNCLASSIFIED 75 Resonant Magnon -Phonon Polaritons in a Ferrimagnet I. E...susceptibilities X"aa and X’m << X’m appear, where 77 xem - DPx igEo0 i_ Xxy - hy- C1 (0)2 _ 00t2) 4= -7• 4 3. Phonon and magnon polaritons We solve the

  11. Phonon properties of β-FeSi2 and photoluminescence

    Science.gov (United States)

    Maeda, Y.; Nakajima, T.; Matsukura, B.; Ikeda, T.; Hiraiwa, Y.

    We have investigated phonon properties of some β-FeSi2 crystals with characteristic light emission properties by using measurements of far-infrared absorption and photoluminescence in order to discuss a correlation between them. It has been found that there is a systematic correlation between phonon states and light emission efficiency and that the phonons above the energy of more than ∼44 meV may be effectively coupled to the optical indirect transition for the IR light emission from β-FeSi2 crystals.

  12. Electron-phonon coupling in the rare-earth metals

    DEFF Research Database (Denmark)

    Skriver, Hans Lomholt; Mertig, I.

    1990-01-01

    We have estimated the strength of the mass enhancement of the conduction electrons due to electron-phonon interaction in the rare metals Sc, Y, and La–Lu. The underlying self-consistent energy bands were obtained by means of the scalar relativistic linear-muffin-tin-orbital method, and the electron......-phonon parameters were calculated within the Gaspari-Gyorffy formulation. For the heavier rare earths Gd–Tm spin polarization was included both in the band-structure calculations and in the treatment of the electron-phonon coupling to take into account the spin splitting of the conduction electrons induced by the 4...

  13. Wave-vector-dependent electron-phonon coupling and the charge-density-wave transition in TbT e3

    Science.gov (United States)

    Maschek, M.; Rosenkranz, S.; Heid, R.; Said, A. H.; Giraldo-Gallo, P.; Fisher, I. R.; Weber, F.

    2015-06-01

    We present a high-energy-resolution inelastic x-ray scattering investigation of the soft phonon mode in the charge-density-wave (CDW) system TbT e3 . We analyze our data based on lattice dynamical calculations using density-functional-perturbation theory and find clear evidence that strongly momentum-dependent electron-phonon coupling defines the periodicity of the CDW superstructure: Our experiment reveals strong phonon softening and increased phonon linewidths over a large part in reciprocal space adjacent to the CDW ordering vector qCDW=(0 ,0 ,0.3 ) . Further, qCDW is clearly offset from the wave vector of (weak) Fermi surface nesting qFS=(0 ,0 ,0.25 ) , and our detailed analysis indicates that electron-phonon coupling is responsible for this shift. Hence, we can add TbT e3 , which was previously considered as a canonical CDW compound following the Peierls scenario, to the list of distinct charge-density-wave materials characterized by momentum-dependent electron-phonon coupling.

  14. Heat Exchange Between Electrons and Phonons in Nanosystems at Sub-Kelvin Temperatures

    Directory of Open Access Journals (Sweden)

    Anghel Dragoş-Victor

    2018-01-01

    Full Text Available Ultra-sensitive nanoscopic detectors for electromagnetic radiation consist of thin metallic films deposited on dielectric membranes. The metallic films, of thickness d of the order of 10 nm, form the thermal sensing element (TSE, which absorbs the incident radiation and measures its power flux or the energies of individual photons. To achieve the sensitivity required for astronomical observations, the TSE works at temperatures of the order of 0.1 K. The dielectric membranes are used as support and for thermal insulation of the TSE and are of thickness L − d of the order of 100 nm (L being the total thickness of the system. In such conditions, the phonon gas in the detector assumes a quasi-two-dimensional distribution, whereas quantization of the electrons wavenumbers in the direction perpendicular to the film surfaces leads to the formation of quasi two-dimensional electronic sub-bands. The heat exchange between electrons and phonons has an important contribution to the performance of the device and is dominated by the interaction between the electrons and the antisymmetric acoustic phonons.

  15. Heat Exchange Between Electrons and Phonons in Nanosystems at Sub-Kelvin Temperatures

    Science.gov (United States)

    Anghel, Dragoş-Victor; Cojocaru, Sergiu

    2018-02-01

    Ultra-sensitive nanoscopic detectors for electromagnetic radiation consist of thin metallic films deposited on dielectric membranes. The metallic films, of thickness d of the order of 10 nm, form the thermal sensing element (TSE), which absorbs the incident radiation and measures its power flux or the energies of individual photons. To achieve the sensitivity required for astronomical observations, the TSE works at temperatures of the order of 0.1 K. The dielectric membranes are used as support and for thermal insulation of the TSE and are of thickness L - d of the order of 100 nm (L being the total thickness of the system). In such conditions, the phonon gas in the detector assumes a quasi-two-dimensional distribution, whereas quantization of the electrons wavenumbers in the direction perpendicular to the film surfaces leads to the formation of quasi two-dimensional electronic sub-bands. The heat exchange between electrons and phonons has an important contribution to the performance of the device and is dominated by the interaction between the electrons and the antisymmetric acoustic phonons.

  16. Neutron-Phonon Interaction Studies in Copper, Zinc and Magnesium Single Crystals

    International Nuclear Information System (INIS)

    Maliszewski, E.; Sosnowski, J.; Blinowski, K.; Kozubowski, J.; Padlo, L.; Sledziewska, D.

    1963-01-01

    The phonon dispersion relations in copper single crystals has been studied by means of a triple-axis crystal neutron spectrometer. In the [100] direction the transversal branch, not reported in the papers of Cabie and Jacrot, has been found. This branch fits well to the recent data of sound velocity; however, it differs partly from the X-ray results of Jacobsen. For the longitudinal branch in the [100] direction the dispersion curve obtained by Cribier and Jacrot is lying well above the Jacobsen's curve, and the experimental points reported in the present paper support the results of Cribier and Jacrot. The phonon dispersion relations in zinc and magnesium single crystals has been studied using the cold neutron method and by means of a triple-axis crystal neutron spectrometer as well. The scattering surfaces in the [1010] plane were traced, the AT and AL branches found and the phonon dispersion relations in the [001] and [010] directions obtained. The results have been compared with those obtained by Johnson with X-rays. In the [001] direction the present results fit well lo Johnson's foe the AL branch. In the [010] direction for the AT branch a large discrepancy has been found between Johnson's and the present results. Some explanation of this discrepancy is given. Similar measurements in the same directions in magnesium single crystals are under way and will be reported. (author) [fr

  17. The Electron-Phonon Interaction as Studied by Photoelectron Spectroscopy

    International Nuclear Information System (INIS)

    Lynch, D.W.

    2004-01-01

    With recent advances in energy and angle resolution, the effects of electron-phonon interactions are manifest in many valence-band photoelectron spectra (PES) for states near the Fermi level in metals

  18. Phonon Modes and the Maintenance Condition of a Crystalline Beam

    CERN Document Server

    Wei, Jie; Li, Xiao-Ping; Okamoto, Hiromi; Sessler, Andrew M; Yuri, Yosuke

    2005-01-01

    Previously it has been shown that the maintenance condition for a crystalline beam requires that there not be a resonance between the crystal phonon frequencies and the frequency associated with a beam moving through a lattice of N periods. This resonance can be avoided provided the phonon frequencies are all below half of the lattice frequency. Here we make a detailed study of the phonon modes of a crystalline beam. Analytic results obtained in a “smooth approximation” using the ground-state crystalline beam structure is compared with numerical evaluation employing Fourier transform of Molecular Dynamic (MD) modes. The MD also determines when a crystalline beam is stable. The maintenance condition, when combined with either the simple analytic theory or the numerical evaluation of phonon modes, is shown to be in excellent agreement with the MD calculations of crystal stability.

  19. Phonon thermal conductance of disordered graphene strips with armchair edges

    International Nuclear Information System (INIS)

    Shi Lipeng; Xiong Shijie

    2009-01-01

    Based on the model of lattice dynamics together with the transfer matrix technique, we investigate the thermal conductances of phonons in quasi-one-dimensional disordered graphene strips with armchair edges using Landauer formalism for thermal transport. It is found that the contributions to thermal conductance from the phonon transport near von Hove singularities is significantly suppressed by the presence of disorder, on the contrary to the effect of disorder on phonon modes in other frequency regions. Besides the magnitude, for different widths of the strips, the thermal conductance also shows different temperature dependence. At low temperatures, the thermal conductance displays quantized features of both pure and disordered graphene strips implying that the transmission of phonon modes at low frequencies are almost unaffected by the disorder

  20. Phonons and Thermal Transport in Carbon Nanotube Systems

    National Research Council Canada - National Science Library

    Gartstein, Yuri

    2005-01-01

    "Due to the combination of a high speed of sound hard optical vibration modes and a large phonon mean free path carbon nanotubes prove to be the most efficient thermal conductors." (D Tornanek, 2005...

  1. Quantum decoherence of phonons in Bose–Einstein condensates

    Science.gov (United States)

    Howl, Richard; Sabín, Carlos; Hackermüller, Lucia; Fuentes, Ivette

    2018-01-01

    We apply modern techniques from quantum optics and quantum information science to Bose–Einstein condensates (BECs) in order to study, for the first time, the quantum decoherence of phonons of isolated BECs. In the last few years, major advances in the manipulation and control of phonons have highlighted their potential as carriers of quantum information in quantum technologies, particularly in quantum processing and quantum communication. Although most of these studies have focused on trapped ion and crystalline systems, another promising system that has remained relatively unexplored is BECs. The potential benefits in using this system have been emphasized recently with proposals of relativistic quantum devices that exploit quantum states of phonons in BECs to achieve, in principle, superior performance over standard non-relativistic devices. Quantum decoherence is often the limiting factor in the practical realization of quantum technologies, but here we show that quantum decoherence of phonons is not expected to heavily constrain the performance of these proposed relativistic quantum devices.

  2. Designing broad phononic band gaps for in-plane modes

    Science.gov (United States)

    Li, Yang Fan; Meng, Fei; Li, Shuo; Jia, Baohua; Zhou, Shiwei; Huang, Xiaodong

    2018-03-01

    Phononic crystals are known as artificial materials that can manipulate the propagation of elastic waves, and one essential feature of phononic crystals is the existence of forbidden frequency range of traveling waves called band gaps. In this paper, we have proposed an easy way to design phononic crystals with large in-plane band gaps. We demonstrated that the gap between two arbitrarily appointed bands of in-plane mode can be formed by employing a certain number of solid or hollow circular rods embedded in a matrix material. Topology optimization has been applied to find the best material distributions within the primitive unit cell with maximal band gap width. Our results reveal that the centroids of optimized rods coincide with the point positions generated by Lloyd's algorithm, which deepens our understandings on the formation mechanism of phononic in-plane band gaps.

  3. Phonon spectrum in a nanoparticle mechanically coupled to a substrate

    Science.gov (United States)

    Patton, K.

    2001-12-01

    We calculate the vibrational density-of-states in an insulating nanoparticle that is in weak mechanical contact with a semi-infinite substrate. The work is motivated by a recent experiment by Yang et al., where the low-energy phonon density-of-states of Y2O3 nanoparticles doped with Eu was measured. Preliminary results presented here, based on the conventional quasiparticle-pole approximation for the phonon propagator, are in reasonable agreement with experiment.

  4. On-chip photonic-phononic emitter-receiver apparatus

    Science.gov (United States)

    Cox, Jonathan Albert; Jarecki, Jr., Robert L.; Rakich, Peter Thomas; Wang, Zheng; Shin, Heedeuk; Siddiqui, Aleem; Starbuck, Andrew Lea

    2017-07-04

    A radio-frequency photonic devices employs photon-phonon coupling for information transfer. The device includes a membrane in which a two-dimensionally periodic phononic crystal (PnC) structure is patterned. The device also includes at least a first optical waveguide embedded in the membrane. At least a first line-defect region interrupts the PnC structure. The first optical waveguide is embedded within the line-defect region.

  5. Fabrication of phonon-based metamaterial structures using focused ion beam patterning

    Science.gov (United States)

    Bassim, Nabil D.; Giles, Alexander J.; Ocola, Leonidas E.; Caldwell, Joshua D.

    2018-02-01

    The focused ion beam (FIB) is a powerful tool for rapid prototyping and machining of functional nanodevices. It is employed regularly to fabricate test metamaterial structures but, to date, has been unsuccessful in fabricating metamaterial structures with features at the nanoscale that rely on surface phonons as opposed to surface plasmons because of the crystalline damage that occurs with the collision cascade associated with ion sputtering. In this study, we employ a simple technique of protecting the crystalline substrate in single-crystal 4H-SiC to design surface phonon polariton-based optical resonance structures. By coating the material surface with a thin film of chromium, we have placed a material of high sputter resistance on the surface, which essentially absorbs the energy in the beam tails. When the beam ultimately punches through the Cr film, the hard walls in the film have the effect of channeling the beam to create smooth sidewalls. This demonstration opens the possibility of further rapid-prototyping of metamaterials using FIB.

  6. Material and Phonon Engineering for Next Generation Acoustic Devices

    Science.gov (United States)

    Kuo, Nai-Kuei

    This thesis presents the theoretical and experimental work related to micromachining of low intrinsic loss sapphire and phononic crystals for engineering new classes of electroacoustic devices for frequency control applications. For the first time, a low loss sapphire suspended membrane was fabricated and utilized to form the main body of a piezoelectric lateral overtone bulk acoustic resonator (LOBAR). Since the metalized piezoelectric transducer area in a LOBAR is only a small fraction of the overall resonant cavity (made out of sapphire), high quality factor (Q) overtones are attained. The experiment confirms the low intrinsic mechanical loss of the transferred sapphire thin film, and the resonators exhibit the highest Q of 5,440 at 2.8 GHz ( f·Q of 1.53.1013 Hz). This is also the highest f·Q demonstrated for aluminum-nitride-(AIN)-based Lamb wave devices to date. Beyond demonstrating a low loss device, this experimental work has laid the foundation for the future development of new micromechanical devices based on a high Q, high hardness and chemically resilient material. The search for alternative ways to more efficiently perform frequency control functionalities lead to the exploration of Phononic Crystal (PnC) structures in AIN thin films. Four unit cell designs were theoretically and experimentally investigated to explore the behavior of phononic bandgaps (PBGs) in the ultra high frequency (UHF) range: (i) the conventional square lattice with circular air scatterer, (ii) the inverse acoustic bandgap (IABG) structure, (iii) the fractal PnC, and (iv) the X-shaped PnC. Each unit cell has its unique frequency characteristic that was exploited to synthesize either cavity resonators or improve the performance of acoustic delay lines. The PBGs operate in the range of 770 MHz to 1 GHz and exhibit a maximum acoustic rejection of 40 dB. AIN Lamb wave transducers (LWTs) were employed for the experimental demonstration of the PBGs and cavity resonances. Ultra

  7. Topological phononic insulator with robust pseudospin-dependent transport

    Science.gov (United States)

    Xia, Bai-Zhan; Liu, Ting-Ting; Huang, Guo-Liang; Dai, Hong-Qing; Jiao, Jun-Rui; Zang, Xian-Guo; Yu, De-Jie; Zheng, Sheng-Jie; Liu, Jian

    2017-09-01

    Topological phononic states, which facilitate unique acoustic transport around defects and disorders, have significantly revolutionized our scientific cognition of acoustic systems. Here, by introducing a zone folding mechanism, we realize the topological phase transition in a double Dirac cone of the rotatable triangular phononic crystal with C3 v symmetry. We then investigate the distinct topological edge states on two types of interfaces of our phononic insulators. The first one is a zigzag interface which simultaneously possesses a symmetric mode and an antisymmetric mode. Hybridization of the two modes leads to a robust pseudospin-dependent one-way propagation. The second one is a linear interface with a symmetric mode or an antisymmetric mode. The type of mode is dependent on the topological phase transition of the phononic insulators. Based on the rotatability of triangular phononic crystals, we consider several complicated contours defined by the topological zigzag interfaces. Along these contours, the acoustic waves can unimpededly transmit without backscattering. Our research develops a route for the exploration of the topological phenomena in experiments and provides an excellent framework for freely steering the acoustic backscattering-immune propagation within topological phononic structures.

  8. Phononic crystals with one-dimensional defect as sensor materials

    Science.gov (United States)

    Aly, Arafa H.; Mehaney, Ahmed

    2017-09-01

    Recently, sensor technology has attracted great attention in many fields due to its importance in many engineering applications. In the present work, we introduce a study using the innovative properties of phononic crystals in enhancing a new type of sensors based on the intensity of transmitted frequencies inside the phononic band gaps. Based on the transfer matrix method and Bloch theory, the expressions of the reflection coefficient and dispersion relation are presented. Firstly, the influences of filling fraction ratio and the angle of incidence on the band gap width are discussed. Secondly, the localization of waves inside band gaps is discussed by enhancing the properties of the defected phononic crystal. Compared to the periodic structure, localization modes involved within the band structure of phononic crystals with one and two defect layers are presented and compared. Trapped localized modes can be detected easily and provide more information about defected structures. Such method could increase the knowledge of manufacturing defects by measuring the intensity of propagated waves in the resonant cavities and waveguides. Moreover, several factors enhance the role of the defect layer on the transmission properties of defected phononic crystals are presented. The acoustic band gap can be used to detect or sense the type of liquids filling the defect layer. The liquids make specific resonant modes through the phononic band gaps that related to the properties of each liquid. The frequency where the maximum resonant modes occur is correlated to material properties and allows to determine several parameters such as the type of an unknown material.

  9. SAIL-Thermique: a model for land surface spectral emissivity in the thermal infrared. Evaluation and reassesment of the temperature - emissivity separation (TES) algorithm in presence of vegetation canopies.

    Science.gov (United States)

    Olioso, A.; Jacob, F.; Lesaignoux, A.

    2014-12-01

    The SAIL-Thermique model was developed to simulate thermal infrared (TIR) radiative transfers inside vegetation canopies and land surface emissivity. It is based on the SAIL model developed by Verhoef (1984) for simulating spectral reflectances in the solar domain. Due to the difficulty to measure land surface emissivity, no emissivity model was validated against ground measurements. In this study, several datasets extracted from the literature and from recent databases were used for evaluating emissivity simulations. Model simulations were performed from the knowledge of leaf area index, leaf inclination distribution, direction of viewing, and leaf and soil optical properties. As data on leaf inclination and leaf optical properties were usually not available, stochastic simulations were performed from a priori knowledges on their distribution (extracted from the literature and recent databases). Simulated 8-14 μm emissivities were favorably compared to measurements with a root mean square difference (RMSD) around 0.006 (0.004 when considering only herbaceous species). The model was then used for simulating emissivity spectra for providing information for the interpretation of TIR multispectral data from the ASTER sensor. We used the land surface emissivity simulations for re-assessing the TES algorithm used to separate emissivity and land surface temperature. We showed that the inclusion of vegetated land surfaces significantly modified the relationship between minimum emissivity and minimum maximum difference (ɛmin- MMD) which is at the heart of the TES algorithm. This relationship was originally established on the ASTER spectral library which did not include vegetated land surface (Schmugge et al. 1998). On a synthetic database, estimations of spectral emissivities and surface temperature were significantly improved when using the new ɛmin- MMD relationship in comparison to the classical one: RMSD dropped from ~0.012 to ~0.006 for spectral emissivity and from

  10. Angle-Resolved Photoemission Spectroscopy on Electronic Structure and Electron-Phonon Coupling in Cuprate Superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Zhou, X.J.

    2010-04-30

    thought possible only a decade ago. This revolution of the ARPES technique and its scientific impact result from dramatic advances in four essential components: instrumental resolution and efficiency, sample manipulation, high quality samples and well-matched scientific issues. The purpose of this treatise is to go through the prominent results obtained from ARPES on cuprate superconductors. Because there have been a number of recent reviews on the electronic structures of high-T{sub c} materials, we will mainly present the latest results not covered previously, with a special attention given on the electron-phonon interaction in cuprate superconductors. What has emerged is rich information about the anomalous electron-phonon interaction well beyond the traditional views of the subject. It exhibits strong doping, momentum and phonon symmetry dependence, and shows complex interplay with the strong electron-electron interaction in these materials. ARPES experiments have been instrumental in identifying the electronic structure, observing and detailing the electron-phonon mode coupling behavior, and mapping the doping evolution of the high-T{sub c} cuprates. The spectra evolve from the strongly coupled, polaronic spectra seen in underdoped cuprates to the Migdal-Eliashberg like spectra seen in the optimally and overdoped cuprates. In addition to the marked doping dependence, the cuprates exhibit pronounced anisotropy with direction in the Brillouin zone: sharp quasiparticles along the nodal direction that broaden significantly in the anti-nodal region of the underdoped cuprates, an anisotropic electron-phonon coupling vertex for particular modes identified in the optimal and overdoped compounds, and preferential scattering across the two parallel pieces of Fermi surface in the antinodal region for all doping levels. This also contributes to the pseudogap effect. To the extent that the Migdal-Eliashberg picture applies, the spectra of the cuprates bear resemblance to that

  11. Mesoscopic hydro-thermodynamics of phonons

    Directory of Open Access Journals (Sweden)

    Aurea R. Vasconcellos

    2013-07-01

    Full Text Available A generalized Hydrodynamics, referred to as Mesoscopic Hydro-Thermodynamics, of phonons in semiconductors is presented. It involves the descriptions of the motion of the quasi-particle density and of the energy density. The hydrodynamic equations, which couple both types of movement via thermo-elastic processes, are derived starting with a generalized Peierls-Boltzmann kinetic equation obtained in the framework of a Non-Equilibrium Statistical Ensemble Formalism, providing such Mesoscopic Hydro-Thermodynamics. The case of a contraction in first order is worked out in detail. The associated Maxwell times are derived and discussed. The densities of quasi-particles and of energy are found to satisfy coupled Maxwell-Cattaneo-like (hyperbolic equations. The analysis of thermo-elastic effects is done and applied to investigate thermal distortion in silicon mirrors under incidence of high intensity X-ray pulses in FEL facilities. The derivation of a generalized Guyer-Krumhansl equation governing the flux of heat and the associated thermal conductivity coefficient is also presented.

  12. The hydrogen-bond network of water supports propagating optical phonon-like modes.

    Science.gov (United States)

    Elton, Daniel C; Fernández-Serra, Marivi

    2016-01-04

    The local structure of liquid water as a function of temperature is a source of intense research. This structure is intimately linked to the dynamics of water molecules, which can be measured using Raman and infrared spectroscopies. The assignment of spectral peaks depends on whether they are collective modes or single-molecule motions. Vibrational modes in liquids are usually considered to be associated to the motions of single molecules or small clusters. Using molecular dynamics simulations, here we find dispersive optical phonon-like modes in the librational and OH-stretching bands. We argue that on subpicosecond time scales these modes propagate through water's hydrogen-bond network over distances of up to 2 nm. In the long wavelength limit these optical modes exhibit longitudinal-transverse splitting, indicating the presence of coherent long-range dipole-dipole interactions, as in ice. Our results indicate the dynamics of liquid water have more similarities to ice than previously thought.

  13. 3D basin-shape ratio effects on frequency content and spectral amplitudes of basin-generated surface waves and associated spatial ground motion amplification and differential ground motion

    Science.gov (United States)

    Kamal; Narayan, J. P.

    2015-04-01

    This paper presents the effects of basin-shape ratio (BSR) on the frequency content and spectral amplitudes of the basin-generated surface (BGS) waves and the associated spatial variation of ground motion amplification and differential ground motion (DGM) in a 3D semi-spherical (SS) basin. Seismic responses were computed using a recently developed 3D fourth-order spatial accurate time-domain finite-difference (FD) algorithm based on the parsimonious staggered-grid approximation of the 3D viscoelastic wave equations. The simulated results revealed the decrease of both the frequency content and the spectral amplitudes of the BGS waves and the duration of ground motion in the SS basin with the decrease of BSR. An increase of the average spectral amplification (ASA), DGM and the average aggravation factor (AAF) towards the centre of the SS basin was obtained due to the focusing of the surface waves. A decrease of ASA, DGM and AAF with the decrease of BSR was also obtained.

  14. Thermal characterization of nanoscale phononic crystals using supercell lattice dynamics

    Directory of Open Access Journals (Sweden)

    Bruce L. Davis

    2011-12-01

    Full Text Available The concept of a phononic crystal can in principle be realized at the nanoscale whenever the conditions for coherent phonon transport exist. Under such conditions, the dispersion characteristics of both the constitutive material lattice (defined by a primitive cell and the phononic crystal lattice (defined by a supercell contribute to the value of the thermal conductivity. It is therefore necessary in this emerging class of phononic materials to treat the lattice dynamics at both periodicity levels. Here we demonstrate the utility of using supercell lattice dynamics to investigate the thermal transport behavior of three-dimensional nanoscale phononic crystals formed from silicon and cubic voids of vacuum. The periodicity of the voids follows a simple cubic arrangement with a lattice constant that is around an order of magnitude larger than that of the bulk crystalline silicon primitive cell. We consider an atomic-scale supercell which incorporates all the details of the silicon atomic locations and the void geometry. For this supercell, we compute the phonon band structure and subsequently predict the thermal conductivity following the Callaway-Holland model. Our findings dictate that for an analysis based on supercell lattice dynamics to be representative of the properties of the underlying lattice model, a minimum supercell size is needed along with a minimum wave vector sampling resolution. Below these minimum values, a thermal conductivity prediction of a bulk material based on a supercell will not adequately recover the value obtained based on a primitive cell. Furthermore, our results show that for the relatively small voids and void spacings we consider (where boundary scattering is dominant, dispersion at the phononic crystal unit cell level plays a noticeable role in determining the thermal conductivity.

  15. Electromagnetic microwaves in metal films with electron-phonon interaction and a dc magnetic field

    DEFF Research Database (Denmark)

    Hasselberg, L.E.

    1976-01-01

    A quantum-mechanical treatment of electromagnetic microwaves is performed for a metal film. The directions of the exterior ac and dc fields are taken to be arbitrary and boundary conditions for the electrons are assumed to be specular. The relation between the current and the electromagnetic field...... in the transmission spectrum can perhaps be obtained by assuming a finite Debye temperature and specular reflections of the electrons at the boundary surfaces. A sharp peak entirely caused by the finite electron-phonon interaction is also discussed....

  16. Stability of the Bi2Se3(111) topological state: Electron-phonon and electron-defect scattering

    DEFF Research Database (Denmark)

    Hatch, Richard Cannon; Bianchi, Marco; Guan, Dandan

    2011-01-01

    by introducing a small concentration of surface defects via ion bombardment. It is found that, in contrast to the bulk states, the topological state can no longer be observed in the photoemission spectra, and this cannot merely be attributed to surface defect-induced momentum broadening....... is possible. The electron-phonon coupling constant is found to be λ = 0.25(5), more than an order of magnitude higher than the corresponding value for intraband scattering in the noble-metal surface states. The stability of the topological state with respect to surface irregularities was also tested...

  17. Coherent Phonons Spectroscopy in Si/SiGe superlattices

    Science.gov (United States)

    Michel, Helene; Ezzahri, Younes; Shakouri, Ali; Pernot, Gilles; Rampnoux, Jean-Michel; Dilhaire, Stefan

    2010-03-01

    Ultrafast pump-probe experiments have been extensively used for coherent zone-folded acoustic phonon spectroscopy in semiconductor superlattices (SL). Most of the spectroscopy studies have been realized via impulsive stimulated Raman scattering (ISRS). More recently some studies, focused on Si/SixGe1-x SL, have combined the spectroscopy via ISRS with the spectroscopy of phonons Bragg reflected via picosecond acoustic experiment. In the latter case, sample needs to be covered by a metallic film which serves as a transducer to convert the optical energy into an impulse heating and thermal expansion. This launches coherent acoustic phonons into the SL structure. Here we present a systematic study of coherent phonons in different Si/SixGe1-x SL structures with two different superlattice periods and transducer thicknesses. The measured acoustic spectrums show that the thickness of the transducer should be chosen as function as the SL period to be able to generate and detect both phonons Bragg reflected and excited by ISRS.

  18. Soft phononic crystals with deformation-independent band gaps

    Science.gov (United States)

    Zhang, Pu; Parnell, William J.

    2017-04-01

    Soft phononic crystals have the advantages over their stiff counterparts of being flexible and reconfigurable. Normally, the band gaps of soft phononic crystals will be modified after deformation due to both geometric and constitutive nonlinearity. Indeed these are important properties that can be exploited to tune the dynamic properties of the material. However, in some instances, it may be that one wishes to deform the medium while retaining the band gap structure. A special class of soft phononic crystals is described here with band gaps that are independent or almost-independent of the imposed mechanical deformation, which enables the design of phononic crystals with robust performance. This remarkable behaviour originates from transformation elasticity theory, which leaves the wave equation and the eigenfrequencies invariant after deformation. The necessary condition to achieve such a property is that the Lagrangian elasticity tensor of the hyperelastic material should be constant, i.e. independent of deformation. It is demonstrated that incompressible neo-Hookean materials exhibit such a unique property. Semilinear materials also possess this property under special loading conditions. Phononic crystals composed of these two materials are studied theoretically and the predictions of invariance, or the manner in which the response deviates from invariance, are confirmed via numerical simulation.

  19. Hole-phonon scattering in high magnetic fields

    International Nuclear Information System (INIS)

    Singh, Surendra; Verma, G.S.

    1980-01-01

    The relative importance of the elastic and inelastic phonon scatterings by shallow acceptors to the low temperature magneto-phonon conductivity of boron doped silicon has been investigated in the present work. It is shown that in the temoerature range 1-5deg K and for magnetic fields upto 55 KG the elastic scattering makes the major contribution towards phonon resistivity. Magnetic field removes the degenracy of the ground state and the phonon conductivity first falls as the level splittings become comparable to the dominant phonon energies (approximately 4 kBT) and then rises rapidly when the splittings become >> kBT. These features are reflected in the present computations with the new effective g values of the acceptor holes, which are given by gsub(3/2) = 2.33 and gsub(1/2) = 1.00. The discrepancy between theory and experiment regarding the absolute values of the ratio [K(H)/K(H=0)] still remains unresolved with the present magnetic level structure and g values. (author)

  20. Anisotropic strain and phonon deformation potentials in GaN

    International Nuclear Information System (INIS)

    Darakchieva, V.; Arwin, H.; Paskov, P. P.; Monemar, B.; Paskova, T.; Hommel, D.; Schubert, M.; Heuken, M.; Off, J.; Scholz, F.; Haskell, B. A.; Fini, P. T.; Speck, J. S.; Nakamura, S.

    2007-01-01

    We report optical phonon frequency studies in anisotropically strained c-plane- and a-plane-oriented GaN films by generalized infrared spectroscopic ellipsometry and Raman scattering spectroscopy. The anisotropic strain in the films is obtained from high-resolution x-ray diffraction measurements. Experimental evidence for splitting of the GaN E 1 (TO), E 1 (LO), and E 2 phonons under anisotropic strain in the basal plane is presented, and their phonon deformation potentials c E 1 (TO) , c E 1 (LO) , and c E 2 are determined. A distinct correlation between anisotropic strain and the A 1 (TO) and E 1 (LO) frequencies of a-plane GaN films reveals the a A 1 (TO) , b A 1 (TO) , a E 1 (LO) , and b E 1 (LO) phonon deformation potentials. The a A 1 (TO) and b A 1 (TO) are found to be in very good agreement with previous results from Raman experiments [V. Yu. Davydov et al., J. Appl. Phys. 82, 5097 (1997)]. Our a A 1 (TO) and a E 1 (LO) phonon deformation potentials agree well with recently reported theoretical estimations [J.-M. Wagner and F. Bechstedt, Phys. Rev. B 66, 115202 (2002)], while b A 1 (TO) and b E 1 (LO) are found to be significantly larger than the theoretical values. A discussion of the observed differences is presented

  1. Quantum Phonon Optics: Squeezing Quantum Noise in the Atomic Displacements.

    Science.gov (United States)

    Hu, X.; Nori, F.

    1996-03-01

    We have investigated(X. Hu and F. Nori, Physical Review B, in press; preprints.) coherent and squeezed quantum states of phonons. Squeezed states are interesting because they allow the possibility of modulating the quantum fluctuations of atomic displacements below the zero-point quantum noise level of phonon vacuum states. We have studiedfootnotemark[1] the possibility of squeezing quantum noise in the atomic displacement using a polariton-based approach and also a method based on the three-phonon anharmonic interaction. Our focus here is on the first approach. We have diagonalized the polariton Hamiltonian and calculated the corresponding expectation values and fluctuations of both the atomic displacement and the lattice amplitude operators (the later is the phonon analog of the electric field operator for photons). Our results shows that squeezing of quantum fluctuations in the atomic displacements can be achieved with appropriate initial states of both photon and phonon fields. The degree of squeezing is directly related to the crystal susceptibility, which is indicative of the interaction strength between the incident light and the crystal.

  2. Designing Phononic Crystals with Wide and Robust Band Gaps

    Science.gov (United States)

    Jia, Zian; Chen, Yanyu; Yang, Haoxiang; Wang, Lifeng

    2018-04-01

    Phononic crystals (PnCs) engineered to manipulate and control the propagation of mechanical waves have enabled the design of a range of novel devices, such as waveguides, frequency modulators, and acoustic cloaks, for which wide and robust phononic band gaps are highly preferable. While numerous PnCs have been designed in recent decades, to the best of our knowledge, PnCs that possess simultaneous wide and robust band gaps (to randomness and deformations) have not yet been reported. Here, we demonstrate that by combining the band-gap formation mechanisms of Bragg scattering and local resonances (the latter one is dominating), PnCs with wide and robust phononic band gaps can be established. The robustness of the phononic band gaps are then discussed from two aspects: robustness to geometric randomness (manufacture defects) and robustness to deformations (mechanical stimuli). Analytical formulations further predict the optimal design parameters, and an uncertainty analysis quantifies the randomness effect of each designing parameter. Moreover, we show that the deformation robustness originates from a local resonance-dominant mechanism together with the suppression of structural instability. Importantly, the proposed PnCs require only a small number of layers of elements (three unit cells) to obtain broad, robust, and strong attenuation bands, which offer great potential in designing flexible and deformable phononic devices.

  3. Designing Phononic Crystals with Wide and Robust Band Gaps

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Yanyu [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Jia, Zian [State University of New York at Stony Brook; Yang, Haoxiang [State University of New York at Stony Brook; Wang, Lifeng [State University of New York at Stony Brook

    2018-04-16

    Phononic crystals (PnCs) engineered to manipulate and control the propagation of mechanical waves have enabled the design of a range of novel devices, such as waveguides, frequency modulators, and acoustic cloaks, for which wide and robust phononic band gaps are highly preferable. While numerous PnCs have been designed in recent decades, to the best of our knowledge, PnCs that possess simultaneous wide and robust band gaps (to randomness and deformations) have not yet been reported. Here, we demonstrate that by combining the band-gap formation mechanisms of Bragg scattering and local resonances (the latter one is dominating), PnCs with wide and robust phononic band gaps can be established. The robustness of the phononic band gaps are then discussed from two aspects: robustness to geometric randomness (manufacture defects) and robustness to deformations (mechanical stimuli). Analytical formulations further predict the optimal design parameters, and an uncertainty analysis quantifies the randomness effect of each designing parameter. Moreover, we show that the deformation robustness originates from a local resonance-dominant mechanism together with the suppression of structural instability. Importantly, the proposed PnCs require only a small number of layers of elements (three unit cells) to obtain broad, robust, and strong attenuation bands, which offer great potential in designing flexible and deformable phononic devices.

  4. Theory and experimental evidence of phonon domains and their roles in pre-martensitic phenomena

    Science.gov (United States)

    Jin, Yongmei M.; Wang, Yu U.; Ren, Yang

    2015-12-01

    Pre-martensitic phenomena, also called martensite precursor effects, have been known for decades while yet remain outstanding issues. This paper addresses pre-martensitic phenomena from new theoretical and experimental perspectives. A statistical mechanics-based Grüneisen-type phonon theory is developed. On the basis of deformation-dependent incompletely softened low-energy phonons, the theory predicts a lattice instability and pre-martensitic transition into elastic-phonon domains via 'phonon spinodal decomposition.' The phase transition lifts phonon degeneracy in cubic crystal and has a nature of phonon pseudo-Jahn-Teller lattice instability. The theory and notion of phonon domains consistently explain the ubiquitous pre-martensitic anomalies as natural consequences of incomplete phonon softening. The phonon domains are characterised by broken dynamic symmetry of lattice vibrations and deform through internal phonon relaxation in response to stress (a particular case of Le Chatelier's principle), leading to previously unexplored new domain phenomenon. Experimental evidence of phonon domains is obtained by in situ three-dimensional phonon diffuse scattering and Bragg reflection using high-energy synchrotron X-ray single-crystal diffraction, which observes exotic domain phenomenon fundamentally different from usual ferroelastic domain switching phenomenon. In light of the theory and experimental evidence of phonon domains and their roles in pre-martensitic phenomena, currently existing alternative opinions on martensitic precursor phenomena are revisited.

  5. Thermal transport in phononic crystals: The role of zone folding effect

    Science.gov (United States)

    Dechaumphai, Edward; Chen, Renkun

    2012-04-01

    Recent experiments [Yu et al., Nature Nanotech 5, 718 (2010); Tang et al., Nano Lett. 10, 4279 (2010); Hopkins etal., Nano Lett. 11, 107(2011)] on silicon based nanoscale phononic crystals demonstrated substantially reduced thermal conductivity compared to bulk Si, which cannot be explained by incoherent phonon boundary scattering within the Boltzmann Transport Equation (BTE). In this paper, partial coherent treatment of phonons, where phonons are regarded as either wave or particles depending on their frequencies, was considered. Phonons with mean free path smaller than the characteristic size of phononic crystals are treated as particles and the transport in this regime is modeled by BTE with phonon boundary scattering taken into account. On the other hand, phonons with mean free path longer than the characteristic size are treated as waves. In this regime, phonon dispersion relations are computed using the Finite Difference Time Domain (FDTD) method and are found to be modified due to the zone folding effect. The new phonon spectra are then used to compute phonon group velocity and density of states for thermal conductivity modeling. Our partial coherent model agrees well with the recent experimental results on in-plane thermal conductivity of phononic crystals. Our study highlights the importance of zone folding effect on thermal transport in phononic crystals.

  6. First principles study of the electron-phonon coupling on the light-actinides Ac-Th alloy: effect of spin-orbit coupling

    Science.gov (United States)

    de La Peña Seaman, Omar; de Coss-Martinez, Romeo; Gonzalez-Castelazo, Paola; Heid, Rolf; Bohnen, Klaus-Peter

    We have studied the electronic, lattice dynamics, and electron-phonon (e-ph) properties of the Ac1-xThx actinide alloy. This system have been studied within the framework of density functional perturbation theory, using a mixed-basis pseudopotential method and the virtual crystal approximation (VCA) for modeling the alloy. The electronic density of states (DOS), the full-phonon dispersion as well as the Eliashberg spectral function (α2 F (ω)) and the electron-phonon coupling (λ) parameter have been calculated with and without the inclusion of spin-orbit coupling (SOC). For Ac the observed effects of SOC on α2 F (ω) are very minor. However, as Th-content increases on the alloy the SOC influence is more important. Such evolution has its roots on a continuous increase of density of states at the Fermi level (N (EF)) difference between schemes, as well as a steady hardening of the SOC full phonon dispersion. The evolution of λ as a function of Th-content for both schemes is presented and discussed on the light of SOC effects on the electronic and vibrational properties. This research was supported by Conacyt-México under Project No. 221807.

  7. Historic and ongoing buoy wave measurements, time series, spectral analysis, and other parameters (sea surface temperature, air temperature and pressure, wind speed and direction), worldwide, mostly US coastal, from November 1975 through present, from the Scripps Institution of Oceanography (SIO) Coastal Data Information Program (CDIP)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The data contain raw and processed values concerning wave size and direction, energy spectral data (both original and processed), and, where available, sea surface...

  8. Photon control of phonons in mixed crystal quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Ingale, Alka

    2003-12-15

    Coherent phonon oscillations in solids can be excited impulsively by a single femtosecond laser pulse whose duration is shorter than a phonon period. In the impulsive stimulated Raman scattering (ISRS) experiment, scattering of probe is monitored as a function of time with respect to pump to generate time domain spectra of coherent phonons. In this paper, we present one such study of CdSe{sub 0.68}Te{sub 0.32} (d{approx}80 A) quantum dots in glass matrix, i.e semiconductor-doped glass (SDG) RG780 from Schott, USA and the experiment was performed at Prof. Merlin's laboratory at the University of Michigan, USA. Here, we present first report of selectively driving only CdSe-like modes in these mixed crystal quantum dots using photon control with two pump beams.

  9. Research Update: Phonon engineering of nanocrystalline silicon thermoelectrics

    Directory of Open Access Journals (Sweden)

    Junichiro Shiomi

    2016-10-01

    Full Text Available Nanocrystalline silicon thermoelectrics can be a solution to improve the cost-effectiveness of thermoelectric technology from both material and integration viewpoints. While their figure-of-merit is still developing, recent advances in theoretical/numerical calculations, property measurements, and structural synthesis/fabrication have opened up possibilities to develop the materials based on fundamental physics of phonon transport. Here, this is demonstrated by reviewing a series of works on nanocrystalline silicon materials using calculations of multiscale phonon transport, measurements of interfacial heat conduction, and synthesis from nanoparticles. Integration of these approaches allows us to engineer phonon transport to improve the thermoelectric performance by introducing local silicon-oxide structures.

  10. Phonon band structures of the three dimensional latticed pentamode metamaterials

    Directory of Open Access Journals (Sweden)

    Guan Wang

    2017-02-01

    Full Text Available The artificially designed three-dimensional (3D pentamode metamaterials have such an extraordinary characteristic that the solid materials behave like liquids. Meanwhile, the ideal structure of the pentamode metamaterials arranges in the same way as that of the diamond crystals. In the present research, we regard three types of pentamode metamaterials derived from the 3D crystal lattices as research objects. The phonon band structures of the candidate pentamode structures are calculated by using the finite element method (FEM. We illustrate the relation between the ratio of the bulk modulus B and the shear modulus G of different combinations of D and d. Finally, we find out the relationship between the phonon band structure and the structure parameters. It is useful for generating the phonon band structure and controlling elastic wave propagation.

  11. Anharmonic phonons and magnons in BiFeO3

    Energy Technology Data Exchange (ETDEWEB)

    Delaire, Olivier A [ORNL; Ma, Jie [ORNL; Stone, Matthew B [ORNL; Huq, Ashfia [ORNL; Gout, Delphine J [ORNL; Brown, Craig [National Institute of Standards and Technology (NIST); Wang, Kefeng [Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing; Ren, Zhifeng [Boston College, Chestnut Hill

    2012-01-01

    The phonon density of states (DOS) and magnetic excitation spectrum of polycrystalline BiFeO3 were measured for temperatures 200 < T < 750K , using inelastic neutron scattering (INS). Our results indicate that the magnetic spectrum of BiFeO3 closely resembles that of similar Fe perovskites, such as LaFeO3, despite the cycloid modulation in BiFeO3. We do not find any evidence for a spin gap. A strong T-dependence of the phonon DOS was found, with a marked broadening of the whole spectrum, providing evidence of strong anharmonicity. This anharmonicity is corroborated by large amplitude motions of Bi and O ions observed with neutron diffraction. These results highlight the importance of spin-phonon coupling in this material.

  12. Interaction Between Electrons, Magnons and Phonons in Nickel. RCN Report

    International Nuclear Information System (INIS)

    Frikkee, E.

    1971-02-01

    By means of inelastic neutron scattering, a localized electron excitation was observed in Ni and (4% Fe). The excitation interacts with magnons and phonons, and is assumed to correspond with transitions between the nearly-degenerate electronstates Δ 6 ↑ and Δ 7 ↑ near X, which are situated just below the Fermi level.Selection rules for electron-phonon and electronmagnon scattering are determined by means of group theory. It is found that in particular the transverse (Δ 5 ) phonons in the [100] direction are perturbed. The observed neutron-electron scattering turns out to be an indirect process, which is only possible due to the interaction between the (Δ 6 , Δ 7 ) electrons and the lattice. The basic mechanism for the observed effects is the electron spin-orbit coupling, which establishes the interaction between the electron spin system and the lattice. (author)

  13. DFT study of phonon dispersion in pure graphene

    Science.gov (United States)

    Mann, Sarita; Rani, Pooja; Kumar, Ranjan; Jindal, V. K.

    2015-08-01

    Ab-initio density functional perturbation theory (DFPT) study of pure graphene has been performed to study the phonon dispersion curve. The Specific heat at constant volume has been calculated and has been compared with theoretical and experimental results. The dynamical matrix has been calculated using VASP software under both simple DFT and DFPT approximation. The phonon frequencies have been calculated using phonopy code under harmonic approximation. The phonon frequencies are then used in calculating dispersion curve and specific heat at constant volume which is in reasonable agreement with available theoretical and experimental results for pure graphene. The specific heat of pristine graphene at constant value has been found to be 1.3 J g-1K-1.

  14. Temperature Dependent Variations of Phonon Interactions in Nanocrystalline Cerium Oxide

    Directory of Open Access Journals (Sweden)

    Sugandha Dogra Pandey

    2015-01-01

    Full Text Available The temperature dependent anharmonic behavior of the phonon modes of nanocrystalline CeO2 was investigated in the temperature range of 80–440 K. The anharmonic constants have been derived from the shift in phonon modes fitted to account for the anharmonic contributions as well as the thermal expansion contribution using the high pressure parameters derived from our own high pressure experimental data reported previously. The total anharmonicity has also been estimated from the true anharmonicity as well as quasiharmonic component. In the line-width variation analysis, the cubic anharmonic term was found to dominate the quartic term. Finally, the phonon lifetime also reflected the trend so observed.

  15. Spectral Decomposition Algorithm (SDA)

    Data.gov (United States)

    National Aeronautics and Space Administration — Spectral Decomposition Algorithm (SDA) is an unsupervised feature extraction technique similar to PCA that was developed to better distinguish spectral features in...

  16. Phonon density of states and anharmonicity of UO2

    Science.gov (United States)

    Pang, Judy W. L.; Chernatynskiy, Aleksandr; Larson, Bennett C.; Buyers, William J. L.; Abernathy, Douglas L.; McClellan, Kenneth J.; Phillpot, Simon R.

    2014-03-01

    Phonon density of states (PDOS) measurements have been performed on polycrystalline UO2 at 295 and 1200 K using time-of-flight inelastic neutron scattering to investigate the impact of anharmonicity on the vibrational spectra and to benchmark ab initio PDOS simulations performed on this strongly correlated Mott insulator. Time-of-flight PDOS measurements include anharmonic linewidth broadening, inherently, and the factor of ˜7 enhancement of the oxygen spectrum relative to the uranium component by the increased neutron sensitivity to the oxygen-dominated optical phonon modes. The first-principles simulations of quasiharmonic PDOS spectra were neutron weighted and anharmonicity was introduced in an approximate way by convolution with wave-vector-weighted averages over our previously measured phonon linewidths for UO2, which are provided in numerical form. Comparisons between the PDOS measurements and the simulations show reasonable agreement overall, but they also reveal important areas of disagreement for both high and low temperatures. The discrepancies stem largely from a ˜10 meV compression in the overall bandwidth (energy range) of the oxygen-dominated optical phonons in the simulations. A similar linewidth-convoluted comparison performed with the PDOS spectrum of Dolling et al. obtained by shell-model fitting to their historical phonon dispersion measurements shows excellent agreement with the time-of-flight PDOS measurements reported here. In contrast, we show by comparisons of spectra in linewidth-convoluted form that recent first-principles simulations for UO2 fail to account for the PDOS spectrum determined from the measurements of Dolling et al. These results demonstrate PDOS measurements to be stringent tests for ab inito simulations of phonon physics in UO2 and they indicate further the need for advances in theory to address the lattice dynamics of UO2.

  17. Inelastic neutron studies of the low energy phonon excitations in the RENi2B2C superconductors (RE = Lu, Y, Ho, Er)

    International Nuclear Information System (INIS)

    Bullock, M.; Stassis, C.; Zarestky, J.; Goldman, A.; Canfield, P.

    1997-01-01

    The authors studied the low-energy phonon excitations for wavevectors close to the Fermi surface nesting vector rvec ξ m ≅ 0.55 rvec a. They find that above T c the frequencies of the Δ 4 [ζ00] lowest-lying optical and acoustic phonon modes decrease with decreasing temperature, for rvec ξ close to rvec ξ m , and there is a shift of intensity from the upper to the lower mode, an effect characteristic of coupled modes. From approximately 120K down to temperatures in the vicinity of T c , only a single unresolved peak is observed. Below T c the phonon spectra of the Y and Lu compounds change dramatically: they consist of a sharp peak at approximately 4.5 meV with a weak shoulder at the higher energy side. No such sharp peak was observed below T c in the Ho and Er compounds

  18. Electron-phonon coupling of the actinide metals

    DEFF Research Database (Denmark)

    Skriver, H. L.; Mertig, I.

    1985-01-01

    The authors have estimated the strength of the electron-phonon coupling in Fr and Ra plus the light actinides Ac through Pu. The underlying self-consistent band-structure calculations were performed by the scalar relativistic linear-muffin-tin-orbital method including l quantum numbers s through g......-phonon parameter λ is found to attain its maximum value in Ac, and they predict a transition temperature of 9K for this metal. In the light actinides Th through Pu, λ is found to be of order 0.4 and within a factor of 2 of experiments which is also the accuracy found in studies of the transition metals...

  19. Topology optimization of two-dimensional asymmetrical phononic crystals

    Energy Technology Data Exchange (ETDEWEB)

    Dong, Hao-Wen [Institute of Engineering Mechanics, Beijing Jiaotong University, Beijing 100044 (China); Su, Xiao-Xing [School of Electronic and Information Engineering, Beijing Jiaotong University, Beijing 100044 (China); Wang, Yue-Sheng, E-mail: yswang@bjtu.edu.cn [Institute of Engineering Mechanics, Beijing Jiaotong University, Beijing 100044 (China); Zhang, Chuanzeng [Department of Civil Engineering, University of Siegen, D-57068 Siegen (Germany)

    2014-01-17

    The multiple elitist genetic algorithm with the adaptive fuzzy fitness granulation (AFFG) is used to design the phononic crystals with large relative bandgap width (BGW) for combined out-of-plane and in-plane wave modes. Without assumption on the symmetry of the unit-cell, we obtain an asymmetrical phononic crystal with the relative BGW which is quite larger than that of the optimized symmetrical structure. With the help of AFFG, the number of the fitness function evaluations is reduced by over 50% and the procedure converges 5 times faster than the conventional evolutionary algorithm to reach the same final fitness values.

  20. Electron-phonon interaction in high temperature superconductors

    Directory of Open Access Journals (Sweden)

    H. Khosroabadi

    2006-09-01

    Full Text Available   We explore the important role of the strong electron-phonon interaction in high temperature superconductivity through the study of the results of some important experiments, such as inelastic neutron and X-ray scattering, angle resolved photoemission spectroscopy, and isotope effects. We also present our computational results of the eigenvalues and eigenvectors of the Ag Raman modes, and the ionic displacement dependence of the electronic band structure by density functional theory. It is clearly evident that the role of phonons in the mechanism behind the high-temperature superconducting state should be seriously considered.

  1. Band structures and localization properties of aperiodic layered phononic crystals

    Energy Technology Data Exchange (ETDEWEB)

    Yan Zhizhong, E-mail: zzyan@bit.edu.cn [Department of Applied Mathematics, Beijing Institute of Technology, Beijing 100081 (China); Zhang Chuanzeng [Department of Civil Engineering, University of Siegen, D-57078 Siegen (Germany)

    2012-03-15

    The band structures and localization properties of in-plane elastic waves with coupling of longitudinal and transverse modes oblique propagating in aperiodic phononic crystals based on Thue-Morse and Rudin-Shapiro sequences are studied. Using transfer matrix method, the concept of the localization factor is introduced and the correctness is testified through the Rytov dispersion relation. For comparison, the perfect periodic structure and the quasi-periodic Fibonacci system are also considered. In addition, the influences of the random disorder, local resonance, translational and/or mirror symmetries on the band structures of the aperiodic phononic crystals are analyzed in this paper.

  2. Unraveling the acoustic electron-phonon interaction in graphene

    DEFF Research Database (Denmark)

    Kaasbjerg, Kristen; Thygesen, Kristian S.; Jacobsen, Karsten W.

    2012-01-01

    Using a first-principles approach we calculate the electron-phonon couplings in graphene for the transverse and longitudinal acoustic phonons. Analytic forms of the coupling matrix elements valid in the long-wavelength limit are found to give an almost quantitative description of the first...... that the intrinsic effective acoustic deformation potential of graphene is Ξeff=6.8 eV and that the temperature dependence of the mobility μ~T-α in the Bloch-Gru¨neisen regime increases beyond an α=4 dependence even in the absence of screening when the true coupling matrix elements are considered. The α>4...

  3. Quantum non-demolition phonon counter with a hybrid optomechnical system

    Science.gov (United States)

    Song, Qiao; Zhang, KeYe; Dong, Ying; Zhang, WeiPing

    2018-05-01

    A phonon counting scheme based on the control of polaritons in an optomechanical system is proposed. This approach permits us to measure the number of phonons in a quantum non-demolition (QND) manner for arbitrary modes not limited by the frequency matching condition as in usual photon-phonon scattering detections. The performance on phonon number transfer and quantum state transfer of the counter are analyzed and simulated numerically by taking into account all relevant sources of noise.

  4. Spectral Imaging by Upconversion

    DEFF Research Database (Denmark)

    Dam, Jeppe Seidelin; Pedersen, Christian; Tidemand-Lichtenberg, Peter

    2011-01-01

    We present a method to obtain spectrally resolved images using upconversion. By this method an image is spectrally shifted from one spectral region to another wavelength. Since the process is spectrally sensitive it allows for a tailored spectral response. We believe this will allow standard sili...... silicon based cameras designed for visible/near infrared radiation to be used for spectral images in the mid infrared. This can lead to much lower costs for such imaging devices, and a better performance.......We present a method to obtain spectrally resolved images using upconversion. By this method an image is spectrally shifted from one spectral region to another wavelength. Since the process is spectrally sensitive it allows for a tailored spectral response. We believe this will allow standard...

  5. Two-phonon capture processes into quantum dots: The role of intermediate states

    DEFF Research Database (Denmark)

    Magnúsdóttir, Ingibjörg; Uskov, A. V.; Bischoff, Svend

    2003-01-01

    We present a study of carrier capture into quantum dots via emission of longitudinal optical phonons. Two-phonon capture times are found to be of the order of some picoseconds at carrier densities 10^1^7cm^-^3 in situations where single-phonon capture processes are energetically prohibited...

  6. A note on two-phonon coherent anti-stokes Raman scattering

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Y. R. [Univ. of California, Berkeley, CA (United States). Dept. of Physics; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials and Molecular Research Division

    1981-01-01

    Difference-frequency mixing of two pump waves can in principle excite two coherent phonon waves via the parametric process. Finally, only when the phonon excitation is small can the nonlinear susceptibility of two-phonon coherent anti-Stokes Raman scattering be described as proportional to the product of two Raman tensors.

  7. Phonons in high- Tc CaBi 2Sr 2Cu 2O 8

    Science.gov (United States)

    Gupta, H. C.

    1989-02-01

    The phonons have been investigated in CaBi 2Sr 2Cu 2O 8 using radial and tangential force constants. From the point of view of superconductivity, it is found that the phonons associated with the Bi-O layers will play an analogous role to the phonons due to Cu-O perovskite-like layers.

  8. Theoretical study of the transverse acoustic phonons of GaSb at ...

    Indian Academy of Sciences (India)

    Abstract. We have investigated the phonon dispersion curves and one-phonon density of states up to the pressure of 8 GPa using a theoretical model, namely the rigid ion model. The transverse acoustic phonons as a function of pressure have been compared with the recently measured inelastic neutron scattering data ...

  9. (In,Ga,Al)P-GaP laser diodes grown on high-index GaAs surfaces emitting in the green, yellow and bright red spectral range

    Science.gov (United States)

    Ledentsov, N. N.; Shchukin, V. A.; Shernyakov, Yu M.; Kulagina, M. M.; Payusov, A. S.; Gordeev, N. Yu; Maximov, M. V.; Cherkashin, N. A.

    2017-02-01

    We report on low threshold current density (<400 A cm-2) injection lasing in (Al x Ga1-x )0.5In0.5P-GaAs-based diodes down to the green spectral range (<570 nm). The epitaxial structures are grown on high-index (611)A and (211)A GaAs substrates by metal-organic vapor phase epitaxy and contain tensile-strained GaP-enriched insertions aimed at reflection of the injected nonequilibrium electrons preventing their escape from the active region. Extended waveguide concept results in a vertical beam divergence with a full width at half maximum of 15° for (611)A substrates. The lasing at the wavelength of 569 nm is realized at 85 K. In an orange-red laser diode structure low threshold current density (190 A cm-2) in the orange spectral range (598 nm) is realized at 85 K. The latter devices demonstrated room temperature lasing at 628 nm at ˜2 kA cm-2 and a total power above 3 W. The red laser diodes grown on (211)A substrates demonstrated a far field characteristic for vertically multimode lasing indicating a lower optical confinement factor for the fundamental mode as compared to the devices grown on (611)A. However, as expected from previous research, the temperature stability of the threshold current and the wavelength stability were significantly higher for (211)A-grown structures.

  10. Demonstration of suppressed phonon tunneling losses in phononic bandgap shielded membrane resonators for high-Q optomechanics

    DEFF Research Database (Denmark)

    Tsaturyan, Yeghishe; Barg, Andreas; Simonsen, Anders

    2014-01-01

    Dielectric membranes with exceptional mechanical and optical properties present one of the most promising platforms in quantum optomechanics. The performance of stressed silicon nitride nanomembranes as mechanical resonators notoriously depends on how their frame is clamped to the sample mount...... so that it assumes the form of a cm-sized bridge featuring a 1-dimensional periodic pattern, whose phononic density of states is tailored to exhibit one, or several, full band gaps around the membrane’s high-Q modes in the MHz-range. We quantify the effectiveness of this phononic bandgap shield...

  11. Active spectral imaging nondestructive evaluation (SINDE) camera

    Energy Technology Data Exchange (ETDEWEB)

    Simova, E.; Rochefort, P.A., E-mail: eli.simova@cnl.ca [Canadian Nuclear Laboratories, Chalk River, Ontario (Canada)

    2016-06-15

    A proof-of-concept video camera for active spectral imaging nondestructive evaluation has been demonstrated. An active multispectral imaging technique has been implemented in the visible and near infrared by using light emitting diodes with wavelengths spanning from 400 to 970 nm. This shows how the camera can be used in nondestructive evaluation to inspect surfaces and spectrally identify materials and corrosion. (author)

  12. The opposition effect in Saturn's main rings as seen by Cassini ISS: 4. Correlations of the surge morphology with surface albedos and VIMS spectral properties

    Science.gov (United States)

    Déau, Estelle; Dones, Luke; Mishchenko, Michael I.; West, Robert A.; Helfenstein, Paul; Hedman, Matt M.; Porco, Carolyn C.

    2018-05-01

    In this paper, we continue our analysis of the saturnian ring opposition effect seen by Cassini ISS. The ring opposition effect is a peak in the rings' reflectivity caused as the directions from a spot on the rings to the observer and to the light source, respectively, converge toward zero degrees. So far, the exact origin of the ring's opposition effect is still a matter of debate. In our previous work (Déau, et al., 2013, Icarus, 226, 591-603), we compared the opposition effect morphology with the rings' optical depth and found that only the slope of the linear part of the rings' phase curves was strongly correlated with the optical depth. We interpreted this as an indication of the predominant role of interparticle shadowing at moderate phase angles (α ∼ 10-40o). More recently (Déau, 2015, Icarus, 253, 311-345), we showed that interparticle shadowing cannot explain the behavior at low phase angles (α microscopic scale of the regolith, and there is a growing body of evidence that regolith grain size, porosity, roughness, and composition control the opposition surge behavior for α < 1o. To test this hypothesis, we compare the opposition surge morphology to the regolith albedo and other spectral properties related to the regolith, such as water ice band depths and spectral slopes derived from Cassini VIMS data (Hedman et al., 2013, Icarus, 223, 105-130). Indeed, it has been recently proven that coherent backscattering affects the water ice band depth variations with phase angle for icy saturnian regoliths (Kolokolova et al., 2010, The Astrophysical Journal Letters, 711, L71-L74). We find that the opposition surge morphology is strongly correlated with the water ice band depth and the regolith albedo. We interpret this finding as an indication that coherent backscattering plays a role in affecting both the water ice band depths and the opposition surge at low phase angles (α < 1o). As the regolith albedo and spectral properties are related to the grain size

  13. Calculation Of Phonon Dispersion Frequencies For Bcc Tantalum ...

    African Journals Online (AJOL)

    The phonon dispersion frequencies are calculated from first principles for bcc Tantalum using a resonance pseudopotential model. It was also possible, using this scheme, to account for the anomalous feature of the Ta dispersion curve observed experimentally in the (ε,o,o,) direction where the frequencies of the transverse ...

  14. Effects of electron–phonon interaction and impurity on optical ...

    Indian Academy of Sciences (India)

    ... Refresher Courses · Symposia · Live Streaming. Home; Journals; Pramana – Journal of Physics; Volume 88; Issue 3. Effects of electron–phonon interaction and impurity on optical properties of hexagonal-shaped quantum wires. R KHORDAD H BAHRAMIYAN. Research Article Volume 88 Issue 3 March 2017 Article ID 50 ...

  15. Theory of parametrically amplified electron-phonon superconductivity

    Science.gov (United States)

    Babadi, Mehrtash; Knap, Michael; Martin, Ivar; Refael, Gil; Demler, Eugene

    2017-07-01

    Ultrafast optical manipulation of ordered phases in strongly correlated materials is a topic of significant theoretical, experimental, and technological interest. Inspired by a recent experiment on light-induced superconductivity in fullerenes [M. Mitrano et al., Nature (London) 530, 461 (2016), 10.1038/nature16522], we develop a comprehensive theory of light-induced superconductivity in driven electron-phonon systems with lattice nonlinearities. In analogy with the operation of parametric amplifiers, we show how the interplay between the external drive and lattice nonlinearities lead to significantly enhanced effective electron-phonon couplings. We provide a detailed and unbiased study of the nonequilibrium dynamics of the driven system using the real-time Green's function technique. To this end, we develop a Floquet generalization of the Migdal-Eliashberg theory and derive a numerically tractable set of quantum Floquet-Boltzmann kinetic equations for the coupled electron-phonon system. We study the role of parametric phonon generation and electronic heating in destroying the transient superconducting state. Finally, we predict the transient formation of electronic Floquet bands in time- and angle-resolved photoemission spectroscopy experiments as a consequence of the proposed mechanism.

  16. Coalescence towards exceptional contours in synthetic phononic media

    DEFF Research Database (Denmark)

    Christensen, Johan

    2016-01-01

    are induced via the acousto-electric effect in electrically biased piezoelectric semiconductors. We study how wave attenuation and amplification can be tuned, and when combined, can give rise to phononic synthetic media with unidirectional suppressed reflectance, a feature directly applicable to evading sonar...

  17. The Electron-Phonon Interaction in Strongly Correlated Systems

    International Nuclear Information System (INIS)

    Castellani, C.; Grilli, M.

    1995-01-01

    We analyze the effect of strong electron-electron repulsion on the electron-phonon interaction from a Fermi-liquid point of view and show that the electron-electron interaction is responsible for vertex corrections, which generically lead to a strong suppression of the electron-phonon coupling in the v F q/ω >>1 region, while such effect is not present when v F q/ω F is the Fermi velocity and q and ω are the transferred momentum and frequency respectively. In particular the e-ph scattering is suppressed in transport properties which are dominated by low-energy-high-momentum processes. On the other hand, analyzing the stability criterion for the compressibility, which involves the effective interactions in the dynamical limit, we show that a sizable electron-phonon interaction can push the system towards a phase-separation instability. Finally a detailed analysis of these ideas is carried out using a slave-boson approach for the infinite-U three-band Hubbard model in the presence of a coupling between the local hole density and a dispersionless optical phonon. (author)

  18. The Effect of Phonon Relaxation Process on Absorption Spectra ...

    African Journals Online (AJOL)

    In this work we study the effect of phonon relaxation process on the absorption spectra using the Green's function technique. The Green's function technique which is widely used in many particle problems is used to solve the Kubo formula which describes the optical absorption process. Finally the configurational diagram is ...

  19. Phonon, magnon and electron contributions to low temperature ...

    Indian Academy of Sciences (India)

    immediate important meanings to reveal the phenomenon of colossal magnetoresistance. The present ... (O) is symbolized by M+(M−)], κ∗ = 2κ for each direc- tional oscillation mode to get the acoustic phonon frequency ... 2.1 Electronic specific heat. The internal energy of electron gas is expressed as. U = U0 +. (. 2π3mV.

  20. Long-Wavelength Phonon Scattering in Nonpolar Semiconductors

    DEFF Research Database (Denmark)

    Lawætz, Peter

    1969-01-01

    The long-wavelength acoustic- and optical-phonon scattering of carriers in nonpolar semiconductors is considered from a general point of view. The deformation-potential approximation is defined and it is shown that long-range electrostatic forces give a nontrivial correction to the scattering...... of the very-short-range nature of interactions in a covalent semiconductor....