WorldWideScience

Sample records for surface ocean ph

  1. Attributing seasonal pH variability in surface ocean waters to governing factors

    NARCIS (Netherlands)

    Hagens, M.; Middelburg, J.J.

    2016-01-01

    On-going ocean acidification and increasing availability of high-frequency pH data have stimulated interest to understand seasonal pH dynamics in surface waters. Here we show that it is possible to accurately reproduce observed pH values by combining seasonal changes in temperature (T), dissolved

  2. Ocean circulation and biogeochemistry moderate interannual and decadal surface water pH changes in the Sargasso Sea

    Science.gov (United States)

    Nathalie F. Goodkin,; Bo-Shian Wang,; Chen-Feng You,; Konrad Hughen,; Prouty, Nancy G.; Bates, Nicholas; Scott Doney,

    2015-01-01

    The oceans absorb anthropogenic CO2 from the atmosphere, lowering surface ocean pH, a concern for calcifying marine organisms. The impact of ocean acidification is challenging to predict as each species appears to respond differently and because our knowledge of natural changes to ocean pH is limited in both time and space. Here we reconstruct 222 years of biennial seawater pH variability in the Sargasso Sea from a brain coral, Diploria labyrinthiformis. Using hydrographic data from the Bermuda Atlantic Time-series Study and the coral-derived pH record, we are able to differentiate pH changes due to surface temperature versus those from ocean circulation and biogeochemical changes. We find that ocean pH does not simply reflect atmospheric CO2 trends but rather that circulation/biogeochemical changes account for >90% of pH variability in the Sargasso Sea and more variability in the last century than would be predicted from anthropogenic uptake of CO2 alone.

  3. Flow and coral morphology control coral surface pH: Implications for the effects of ocean acidification

    Directory of Open Access Journals (Sweden)

    Neil C. S. Chan

    2016-02-01

    Full Text Available The future impact of ocean acidification (OA on corals is disputed in part because mathematical models used to predict these impacts do not seem to capture, or offer a framework to adequately explain, the substantial variability in acidification effects observed in empirical studies. The build-up of a diffusive boundary layer (DBL, wherein solute transport is controlled by diffusion, can lead to pronounced differences between the bulk seawater pH, and the actual pH experienced by the organism, a factor rarely considered in mathematical modelling of ocean acidification effects on corals. In the present study, we developed a simple diffusion-reaction-uptake model that was experimentally parameterized based on direct microsensor measurements of coral tissue pH and O2 within the DBL of a branching and a massive coral. The model accurately predicts tissue surface pH for different coral morphologies and under different flow velocities as a function of ambient pH. We show that, for all cases, tissue surface pH is elevated at lower flows, and thus thicker DBLs. The relative effects of OA on coral surface pH was controlled by flow and we show that under low flow velocities tissue surface pH under OA conditions (pHSWS = 7.8 can be equal to the pH under normal conditions (pHSWS = 8.2. We conclude that OA effects on corals in nature will be complex as the degree to which they are controlled by flow appears to be species specific.

  4. Geoengineering impact of open ocean dissolution of olivine on atmospheric CO2, surface ocean pH and marine biology

    International Nuclear Information System (INIS)

    Köhler, Peter; Abrams, Jesse F; Völker, Christoph; Hauck, Judith; Wolf-Gladrow, Dieter A

    2013-01-01

    Ongoing global warming induced by anthropogenic emissions has opened the debate as to whether geoengineering is a ‘quick fix’ option. Here we analyse the intended and unintended effects of one specific geoengineering approach, which is enhanced weathering via the open ocean dissolution of the silicate-containing mineral olivine. This approach would not only reduce atmospheric CO 2 and oppose surface ocean acidification, but would also impact on marine biology. If dissolved in the surface ocean, olivine sequesters 0.28 g carbon per g of olivine dissolved, similar to land-based enhanced weathering. Silicic acid input, a byproduct of the olivine dissolution, alters marine biology because silicate is in certain areas the limiting nutrient for diatoms. As a consequence, our model predicts a shift in phytoplankton species composition towards diatoms, altering the biological carbon pumps. Enhanced olivine dissolution, both on land and in the ocean, therefore needs to be considered as ocean fertilization. From dissolution kinetics we calculate that only olivine particles with a grain size of the order of 1 μm sink slowly enough to enable a nearly complete dissolution. The energy consumption for grinding to this small size might reduce the carbon sequestration efficiency by ∼30%. (letter)

  5. The pH of Enceladus' ocean

    Science.gov (United States)

    Glein, Christopher R.; Baross, John A.; Waite, J. Hunter

    2015-08-01

    Saturn's moon, Enceladus, is a geologically active waterworld. The prevailing paradigm is that there is a subsurface ocean that erupts to the surface, which leads to the formation of a plume of vapor and ice above the south polar region. The chemistry of the ocean is just beginning to be understood, but is of profound geochemical and astrobiological interest. Here, we determine the pH of the ocean using a thermodynamic model of carbonate speciation. Observational data from the Cassini spacecraft are used to make a chemical model of ocean water on Enceladus. The model suggests that Enceladus' ocean is a Na-Cl-CO3 solution with an alkaline pH of ∼11-12. The dominance of aqueous NaCl is a feature that Enceladus' ocean shares with terrestrial seawater, but the ubiquity of dissolved Na2CO3 suggests that soda lakes are more analogous to the Enceladus ocean. The high pH implies that the hydroxide ion should be relatively abundant, while divalent metals should be present at low concentrations owing to buffering by carbonates and phyllosilicates on the ocean floor. Carboxyl groups in dissolved organic species would be negatively charged, while amino groups would exist predominately in the neutral form. Knowledge of the pH improves our understanding of geochemical processes in Enceladus' ocean. The high pH is interpreted to be a key consequence of serpentinization of chondritic rock, as predicted by prior geochemical reaction path models; although degassing of CO2 from the ocean may also play a role depending on the efficiency of mixing processes in the ocean. Serpentinization leads to the generation of H2, a geochemical fuel that can support both abiotic and biological synthesis of organic molecules such as those that have been detected in Enceladus' plume. Serpentinization and H2 generation should have occurred on Enceladus, like on the parent bodies of aqueously altered meteorites; but it is unknown whether these critical processes are still taking place, or if

  6. Dissolved inorganic carbon, pH, oxygen, and other variables collected from surface discrete and surface underway observations using flow-through pump from NOAA Ship Gordon Gunter off the U.S. East Coast during the East Coast Ocean Acidification (ECOA) Cruise from 2015-06-19 to 2015-07-24 (NCEI Accession 0157485)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This archival package contains dissolved inorganic carbon, pH, oxygen, and other variables collected from surface discrete and surface underway observations during...

  7. Dissolved inorganic carbon, total alkalinity, pH, and other variables collected from surface discrete observations using flow through pump and other instruments from Explorer of the Seas (ID: 33KF) in the Caribbean Sea and North Atlantic ocean during the Ocean Acidification Cruise EX1507 from 2015-02-14 to 2015-02-15 (NCEI Accession 0154385)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This archival package contains surface discrete measurements of dissolved inorganic carbon, total alkalinity, pH in the Caribbean Sea. Increasing amounts of...

  8. Climatological Distributions of pH, pCO2, Total CO2, Alkalinity, and CaCO3 Saturation in the Global Surface Ocean (NCEI accession 01645680) (NCEI Accession 0164568)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Climatological mean monthly distributions of pH in the total H+ scale, total CO2 concentration (TCO2), and the degree of CaCO3 saturation for the global surface...

  9. Ocean Acidification: Euphausia Pacifica's Response to Decreasing pH

    Science.gov (United States)

    Weber, H. N.; Cooper, H.

    2014-12-01

    The increasing rate of CO2 accumulating in Earth's oceans creates a threat to organisms that can lead to disturbances in their reproduction, survival and growth. Euphausia pacifica is the dominant species of krill in Monterey Bay, CA, and a keystone species in the bay's food web. Previous work on the effects of ocean acidification on the survival, growth and molting of E. pacifica have shown they are fairly tolerant to increased CO2 concentrations. However, less is known about energy costs associated with maintaining their internal pH levels which could affect food consumption, swimming behavior or growth activity. We hypothesized that krill exposed to high CO2 will increase their feeding rate on local species of phytoplankton to account for increased energy costs of pH buffering activity. We exposed experimental E. pacifica to waters of pH 7.6 (the expected pH surface waters in year 2100), and pH 8.0 (control) periods.test for acclimation or longer term stress. Feeding rates were calculated as changes in phytoplankton counts over 24 hours of feeding using Frost's equations (Frost 1972). Understanding the way E. pacifica is affected by ocean acidification is important because of the role they play as the primary food source for a variety of predators necessary to maintain the Pacific's ecology.

  10. OW CCMP Ocean Surface Wind

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Cross-Calibrated Multi-Platform (CCMP) Ocean Surface Wind Vector Analyses (Atlas et al., 2011) provide a consistent, gap-free long-term time-series of monthly...

  11. OW ASCAT Ocean Surface Winds

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Advanced Scatterometer (ASCAT) sensor onboard the EUMETSAT MetOp polar-orbiting satellite provides ocean surface wind observations by means of radar...

  12. Quantifying the flux of CaCO3 and organic carbon from the surface ocean using in situ measurements of O2, N2, pCO2, and pH

    Science.gov (United States)

    Emerson, Steven; Sabine, Christopher; Cronin, Meghan F.; Feely, Richard; Cullison Gray, Sarah E.; Degrandpre, Mike

    2011-09-01

    Ocean acidification from anthropogenic CO2 has focused our attention on the importance of understanding the rates and mechanisms of CaCO3 formation so that changes can be monitored and feedbacks predicted. We present a method for determining the rate of CaCO3 production using in situ measureme nts of fCO2 and pH in surface waters of the eastern subarctic Pacific Ocean. These quantities were determined on a surface mooring every 3 h for a period of about 9 months in 2007 at Ocean Station Papa (50°N, 145°W). We use the data in a simple surface ocean, mass balance model of dissolved inorganic carbon (DIC) and alkalinity (Alk) to constrain the CaCO3: organic carbon (OC) production ratio to be approximately 0.5. A CaCO3 production rate of 8 mmol CaCO3 m-2 d-1 in the summer of 2007 (1.2 mol m-2 yr-1) is derived by combining the CaCO3: OC ratio with the a net organic carbon production rate (2.5 mol C m-2 yr-1) determined from in situ measurements of oxygen and nitrogen gas concentrations measured on the same mooring (Emerson and Stump, 2010). Carbonate chemistry data from a meridional hydrographic section in this area in 2008 indicate that isopycnal surfaces that outcrop in the winter in the subarctic Pacific and deepen southward into the subtropics are a much stronger source for alkalinity than vertical mixing. This pathway has a high enough Alk:DIC ratio to support the CaCO3:OC production rate implied by the fCO2 and pH data.

  13. Dissolved inorganic carbon, total alkalinity, pH, nutrients and other variables collected from surface discrete sampling using flow through pump and other instruments from NOAA Ship Gordon Gunter in the U.S. East Coast during the East Coast Ocean Acidification (GU-15-04 ECOA1) from 2015-06-20 to 2015-07-23 (NCEI Accession 0157389)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This archival package contains dissolved inorganic carbon, total alkalinity, pH, nutrients and other variables collected from surface discrete sampling using flow...

  14. Dissolved inorganic carbon, total alkalinity, pH, and other variables collected from surface and discrete observations using flow-through pump and other instruments from M/V Equinox in the North Atlantic ocean (east coast of Miami, FL, Bahamas, and Turks and Caicos Islands) from 2015-03-07 to 2015-03-09 (NCEI Accession 0154382)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This archival package contains surface discrete measurements of dissolved inorganic carbon, total alkalinity, and pH from the east coast of Florida to Puerto Rico....

  15. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, temperature, salinity and SEA SURFACE TEMPERATURE collected from Surface underway observations using automated Multi-parameter Inorganic Carbon Analyzer (MICA) for autonomous measurement of pH, carbon dioxide (CO2) and dissolved inorganic carbon (DIC) and other instruments from THOMAS G. THOMPSON in the Gulf of Alaska, North Pacific Ocean and South Pacific Ocean from 2006-02-13 to 2006-03-30 (NCEI Accession 0157411)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157411 includes Surface underway, chemical and physical data collected from THOMAS G. THOMPSON in the Gulf of Alaska, North Pacific Ocean and South...

  16. A New Desalination Pump Helps Define the pH of Ocean Worlds

    Science.gov (United States)

    Levi, A.; Sasselov, D.

    2018-04-01

    We study ocean exoplanets, for which the global surface ocean is separated from the rocky interior by a high-pressure ice mantle. We describe a mechanism that can pump salts out of the ocean, resulting in oceans of very low salinity. Here we focus on the H2O–NaCl system, though we discuss the application of this pump to other salts as well. We find our ocean worlds to be acidic, with a pH in the range of 2–4. We discuss and compare between the conditions found within our studied oceans and the conditions in which polyextremophiles were discovered. This work focuses on exoplanets in the super-Earth mass range (∼2 M ⊕), with water composing at least a few percent of their mass. However, the principle of the desalination pump might extend beyond this mass range.

  17. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from Surface underway, discrete sample and profile observations using CTD, Carbon dioxide (CO2) gas analyzer and other instruments from MAURICE EWING in the North Atlantic Ocean and South Atlantic Ocean from 1994-01-04 to 1994-03-21 (NODC Accession 0115157)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0115157 includes Surface underway, discrete sample and profile data collected from MAURICE EWING in the North Atlantic Ocean and South Atlantic Ocean...

  18. Ocean Health X-Prize testing of a Simplified Spectrophotometric pH Sensor

    Science.gov (United States)

    Darlington, R. C.; DeGrandpre, M. D.; Spaulding, R. S.; Beck, J. C.

    2016-02-01

    Since the Industrial Revolution, the world's oceans have absorbed increasing amounts of CO2, resulting in a >0.1 reduction in the pH of surface waters. This acidification of the oceans has many far reaching impacts on marine life. There is, therefore, great need of quality instrumentation to assess and follow the changing carbonate system. To address this need, we have developed a simplified spectrophotometric pH sensor with accuracy and precision suitable for sea surface measurements with special emphasis on reduced size and cost. The reduced size will allow deployment of sensors on a much wider variety of platforms than are currently possible, and the reduced cost will make the instruments available to a broader research community. This prototype pH instrument was entered into the Wendy Schmidt Ocean Health X-Prize, an incentivized global competition to spur innovation in sensors to monitor ocean acidification's impact on marine ecosystems. Results from the three phases of competition which explored accuracy, precision, and stability culminating in a one month field trial are detailed. The prototype proved to be highly accurate (+/-0.009), with good precision (+/-0.004) and stability showing drift indistinguishable from that of the validation measurements. The innovations that enabled this sensor to succeed in the competition could allow for deployment of spectrophotometric sensors on new platforms such as NOAAs Global Drifter Program, a network of non-recovered surface drifting buoys, which would greatly extend the spatial and temporal resolution of ocean acidification measurements.

  19. Dissolved inorganic carbon, total alkalinity, pH, and other variables collected from surface discrete observations using Flow through pump and other instruments from M/V Skogafoss in the Northeastern U.S. continental shelf and off the southern coast of Greenland during the ocean acidification cruise SKO0313, SKO0406, SKO0410, SKO0414, SKO0510, SKO0604, SKO0611, SKO0721, SKO_1406, SKO_1501, SKO_1506, SKO_1509, SKO_1604 from 2003-12-06 to 2016-04-01 (NCEI Accession 0154380)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This archival package contains surface measurements of dissolved inorganic carbon, total alkalinity, pH in the North Atlantic Ocean. Increasing amounts of...

  20. Generalised expressions for the response of pH to changes in ocean chemistry

    Science.gov (United States)

    Hagens, Mathilde; Middelburg, Jack J.

    2016-08-01

    The extent to which oceans are capable of buffering chemical changes resulting from the uptake of carbon dioxide (CO2) or other acidifying processes can be quantified using buffer factors. Here, we present general expressions describing the sensitivity of pH and concentrations of CO2 and other acid-base species to a change in ocean chemistry. These expressions can include as many acid-base systems as desirable, making them suitable for application to, e.g., upwelling regions or nutrient-rich coastal waters. We show that these expressions are fully consistent with previously derived expressions for the Revelle factor and other buffer factors, which only included the carbonate and borate acid-base systems, and provide more accurate values. We apply our general expressions to contemporary global ocean surface water and possible changes therein by the end of the 21st century. These results show that most sensitivities describing a change in pH are of greater magnitude in a warmer, high-CO2 ocean, indicating a decreased seawater buffering capacity. This trend is driven by the increase in CO2 and slightly moderated by the warming. Respiration-derived carbon dioxide may amplify or attenuate ocean acidification due to rising atmospheric CO2, depending on their relative importance. Our work highlights that, to gain further insight into current and future pH dynamics, it is crucial to properly quantify the various concurrently acting buffering mechanisms.

  1. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from Surface underway, discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from MIRAI in the Bering Sea, North Pacific Ocean and South Pacific Ocean from 2007-10-08 to 2007-12-26 (NODC Accession 0108123)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108123 includes Surface underway, discrete sample and profile data collected from MIRAI in the Bering Sea, North Pacific Ocean and South Pacific...

  2. pH (on total scale) and other variables collected from surface undewray observations using Durafet pH electrode and Chloride Ion Selective Electrode and other instruments from NOAA Ship Ronald H. Brown in the North Atlantic Ocean and South Atnaltic Ocean from during the CLIVAR/GO-SHIP Repeat Section A13.5_2010 (EXPOCODE 33RO20100308) from 2010-03-08 to 2010-04-17 (NCEI Accession 0162231)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — An automated underway pH system was operated in the hydro lab of NOAA Ship Ronald H. Brown during the CLIVAR/GO-SHIP Repeat Section A13.5 cruise in 2010. pH was...

  3. Simulation Tool for GNSS Ocean Surface Reflections

    OpenAIRE

    Høeg, Per; von Benzon, Hans-Henrik; Durgonics, Tibor

    2015-01-01

    GNSS coherent and incoherent reflected signals have the potential of deriving large scale parameters of ocean surfaces, as barotropic variability, eddy currents and fronts, Rossby waves, coastal upwelling, mean ocean surfaceheights, and patterns of the general ocean circulation. In the reflection zone the measurements may deriveparameters as sea surface roughness, winds, waves, heights and tilts from the spectral measurements. Previous measurements from the top of mountains and airplanes have...

  4. An update to the Surface Ocean CO

    NARCIS (Netherlands)

    Bakker, D.C.E.; de Baar, H.J.W.; van heuven, S.

    2014-01-01

    The Surface Ocean CO2 Atlas (SOCAT), an activity of the international marine carbon research community, provides access to synthesis and gridded fCO2 (fugacity of carbon dioxide) products for the surface oceans. Version 2 of SOCAT is an update of the previous release (version

  5. Glacial--interglacial stability of ocean pH inferred from foraminifer dissolution rates.

    Science.gov (United States)

    Anderson, David M; Archer, David

    2002-03-07

    The pH of the ocean is controlled by the chemistry of calcium carbonate. This system in turn plays a large role in regulating the CO2 concentration of the atmosphere on timescales of thousands of years and longer. Reconstructions of ocean pH and carbonate-ion concentration are therefore needed to understand the ocean's role in the global carbon cycle. During the Last Glacial Maximum (LGM), the pH of the whole ocean is thought to have been significantly more basic, as inferred from the isotopic composition of boron incorporated into calcium carbonate shells, which would partially explain the lower atmospheric CO2 concentration at that time. Here we reconstruct carbonate-ion concentration--and hence pH--of the glacial oceans, using the extent of calcium carbonate dissolution observed in foraminifer faunal assemblages as compiled in the extensive global CLIMAP data set. We observe decreased carbonate-ion concentrations in the glacial Atlantic Ocean, by roughly 20 micromolkg-1, while little change occurred in the Indian and Pacific oceans relative to today. In the Pacific Ocean, a small (5 micromolkg-1) increase occurred below 3,000m. This rearrangement of ocean pH may be due to changing ocean circulation from glacial to present times, but overall we see no evidence for a shift in the whole-ocean pH as previously inferred from boron isotopes.

  6. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample, profile and underway - surface observations using Alkalinity titrator, CTD and other instruments from the MIRAI in the Bismarck Sea, North Pacific Ocean and South Pacific Ocean from 2005-05-25 to 2005-07-02 (NODC Accession 0108081)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0108081 includes chemical, discrete sample, physical, profile and underway - surface data collected from MIRAI in the Bismarck Sea, North Pacific...

  7. Turf algal epiphytes metabolically induce local pH increase, with implications for underlying coralline algae under ocean acidification

    DEFF Research Database (Denmark)

    Short, J.A.; Pedersen, Ole; Kendrick, G.A.

    2015-01-01

    The presence of epiphytic turf algae may modify the effects of ocean acidification on coralline algal calcification rates by altering seawater chemistry within the diffusive boundary layer (DBL) above coralline algal crusts. We used microelectrodes to measure the effects of turf algal epiphytes...... on seawater pH and the partial pressure of oxygen (pO2) within the DBL at the surface of Hydrolithoideae coralline algal crusts under ambient (36 Pa) CO2 and an ocean acidification scenario with elevated CO2 (200 Pa). Turf algae significantly increased the mean diel amplitude of pH and pO2, and this effect...... was more pronounced under elevated CO2. We suggest that increases in seawater CO2 under ocean acidification conditions may drive an increase in the abundance of epiphytic turf algae, consequently modifying the chemistry within the DBL. Thus, the effect of epiphytic turf algae on microscale pH is striking...

  8. Natural variability in the surface ocean carbonate ion concentration

    Directory of Open Access Journals (Sweden)

    N. S. Lovenduski

    2015-11-01

    Full Text Available We investigate variability in the surface ocean carbonate ion concentration ([CO32−] on the basis of a~long control simulation with an Earth System Model. The simulation is run with a prescribed, pre-industrial atmospheric CO2 concentration for 1000 years, permitting investigation of natural [CO32−] variability on interannual to multi-decadal timescales. We find high interannual variability in surface [CO32−] in the tropical Pacific and at the boundaries between the subtropical and subpolar gyres in the Northern Hemisphere, and relatively low interannual variability in the centers of the subtropical gyres and in the Southern Ocean. Statistical analysis of modeled [CO32−] variance and autocorrelation suggests that significant anthropogenic trends in the saturation state of aragonite (Ωaragonite are already or nearly detectable at the sustained, open-ocean time series sites, whereas several decades of observations are required to detect anthropogenic trends in Ωaragonite in the tropical Pacific, North Pacific, and North Atlantic. The detection timescale for anthropogenic trends in pH is shorter than that for Ωaragonite, due to smaller noise-to-signal ratios and lower autocorrelation in pH. In the tropical Pacific, the leading mode of surface [CO32−] variability is primarily driven by variations in the vertical advection of dissolved inorganic carbon (DIC in association with El Niño–Southern Oscillation. In the North Pacific, surface [CO32−] variability is caused by circulation-driven variations in surface DIC and strongly correlated with the Pacific Decadal Oscillation, with peak spectral power at 20–30-year periods. North Atlantic [CO32−] variability is also driven by variations in surface DIC, and exhibits weak correlations with both the North Atlantic Oscillation and the Atlantic Multidecadal Oscillation. As the scientific community seeks to detect the anthropogenic influence on ocean carbonate chemistry, these results

  9. Natural variability in the surface ocean carbonate ion concentration

    Science.gov (United States)

    Lovenduski, N. S.; Long, M. C.; Lindsay, K.

    2015-11-01

    We investigate variability in the surface ocean carbonate ion concentration ([CO32-]) on the basis of a~long control simulation with an Earth System Model. The simulation is run with a prescribed, pre-industrial atmospheric CO2 concentration for 1000 years, permitting investigation of natural [CO32-] variability on interannual to multi-decadal timescales. We find high interannual variability in surface [CO32-] in the tropical Pacific and at the boundaries between the subtropical and subpolar gyres in the Northern Hemisphere, and relatively low interannual variability in the centers of the subtropical gyres and in the Southern Ocean. Statistical analysis of modeled [CO32-] variance and autocorrelation suggests that significant anthropogenic trends in the saturation state of aragonite (Ωaragonite) are already or nearly detectable at the sustained, open-ocean time series sites, whereas several decades of observations are required to detect anthropogenic trends in Ωaragonite in the tropical Pacific, North Pacific, and North Atlantic. The detection timescale for anthropogenic trends in pH is shorter than that for Ωaragonite, due to smaller noise-to-signal ratios and lower autocorrelation in pH. In the tropical Pacific, the leading mode of surface [CO32-] variability is primarily driven by variations in the vertical advection of dissolved inorganic carbon (DIC) in association with El Niño-Southern Oscillation. In the North Pacific, surface [CO32-] variability is caused by circulation-driven variations in surface DIC and strongly correlated with the Pacific Decadal Oscillation, with peak spectral power at 20-30-year periods. North Atlantic [CO32-] variability is also driven by variations in surface DIC, and exhibits weak correlations with both the North Atlantic Oscillation and the Atlantic Multidecadal Oscillation. As the scientific community seeks to detect the anthropogenic influence on ocean carbonate chemistry, these results will aid the interpretation of trends

  10. Field Performance of ISFET based Deep Ocean pH Sensors

    Science.gov (United States)

    Branham, C. W.; Murphy, D. J.

    2017-12-01

    Historically, ocean pH time series data was acquired from infrequent shipboard grab samples and measured using labor intensive spectrophotometry methods. However, with the introduction of robust and stable ISFET pH sensors for use in ocean applications a paradigm shift in the methods used to acquire long-term pH time series data has occurred. Sea-Bird Scientific played a critical role in the adoption this new technology by commercializing the SeaFET pH sensor and float pH Sensor developed by the MBARI chemical sensor group. Sea-Bird Scientific continues to advance this technology through a concerted effort to improve pH sensor accuracy and reliability by characterizing their performance in the laboratory and field. This presentation will focus on calibration of the ISFET pH sensor, evaluate its analytical performance, and validate performance using recent field data.

  11. Sunglitter Imagery Of The Ocean Surface Phenomena

    Science.gov (United States)

    Myasoedov, Alexander; Kudryavtsev, Vladimir; Chapron, Bertrand; Johannessen, Johnny

    2010-04-01

    An algorithm for retrieval of spatial variations of the mean square slope (MSS) of the sea surface from sunglint imagery is proposed. The retrieval algorithm is free on a prior suggestion on PDF model. The transfer function, relating the brightness contrast to the MSS contrasts, is found from observed sunglint brightness, where “real” PDF of the sea slopes has built-in. Developed approach was applied for analysis of the sunglint signature of the mesoscale ocean dynamics and internal waves. We found that the ocean currents (eddies, meanders, frontal lines) and internal waves are well visible on the sea surface as the MSS anomalies. Results of this study is further adopted by Kudryavtsev et al. (2010) for development of advanced approach for synergetic use of SAR and optical imagery in studies of meso-scale ocean dynamics.

  12. Surface ocean carbon dioxide during the Atlantic Meridional Transect (1995-2013); evidence of ocean acidification

    Science.gov (United States)

    Kitidis, Vassilis; Brown, Ian; Hardman-Mountford, Nicholas; Lefèvre, Nathalie

    2017-11-01

    Here we present more than 21,000 observations of carbon dioxide fugacity in air and seawater (fCO2) along the Atlantic Meridional Transect (AMT) programme for the period 1995-2013. Our dataset consists of 11 southbound and 2 northbound cruises in boreal autumn and spring respectively. Our paper is primarily focused on change in the surface-ocean carbonate system during southbound cruises. We used observed fCO2 and total alkalinity (TA), derived from salinity and temperature, to estimate dissolved inorganic carbon (DIC) and pH (total scale). Using this approach, estimated pH was consistent with spectrophotometric measurements carried out on 3 of our cruises. The AMT cruises transect a range of biogeographic provinces where surface Chlorophyll-α spans two orders of magnitude (mesotrophic high latitudes to oligotrophic subtropical gyres). We found that surface Chlorophyll-α was negatively correlated with fCO2, but that the deep chlorophyll maximum was not a controlling variable for fCO2. Our data show clear evidence of ocean acidification across 100° of latitude in the Atlantic Ocean. Over the period 1995-2013 we estimated annual rates of change in: (a) sea surface temperature of 0.01 ± 0.05 °C, (b) seawater fCO2 of 1.44 ± 0.84 μatm, (c) DIC of 0.87 ± 1.02 μmol per kg and (d) pH of -0.0013 ± 0.0009 units. Monte Carlo simulations propagating the respective analytical uncertainties showed that the latter were < 5% of the observed trends. Seawater fCO2 increased at the same rate as atmospheric CO2.

  13. High-resolution ocean pH dynamics in four subtropical Atlantic benthic habitats

    Science.gov (United States)

    Hernández, C. A.; Clemente, S.; Sangil, C.; Hernández, J. C.

    2015-12-01

    Oscillations of ocean pH are largely unknown in coastal environments and ocean acidification studies often do not account for natural variability yet most of what is known about marine species and populations is found out via studies conducted in near shore environments. Most experiments designed to make predictions about future climate change scenarios are carried out in coastal environments with no research that takes into account the natural pH variability. In order to fill this knowledge gap and to provide reliable measures of pH oscillation, seawater pH was measured over time using moored pH sensors in four contrasting phytocenoses typical of the north Atlantic subtropical region. Each phytocenosis was characterized by its predominant engineer species: (1) Cystoseira abies-marina, (2) a mix of gelidiales and geniculate corallines, (3) Lobophora variegata, and (4) encrusting corallines. The autonomous pH measuring systems consisted of a pH sensor; a data logger and a battery encased in a waterproof container and allowed the acquisition of high-resolution continuous pH data at each of the study sites. The pH variation observed ranged by between 0.09 and 0.24 pHNBS units. A clear daily variation in seawater pH was detected at all the studied sites (0.04-0.12 pHNBS units). Significant differences in daily pH oscillations were also observed between phytocenoses, which shows that macroalgal communities influence the seawater pH in benthic habitats. Natural oscillations in pH must be taken into account in future ocean acidification studies to put findings in perspective and for any ecological recommendations to be realistic.

  14. Merged Land and Ocean Surface Temperature, Version 3.5

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The historical Merged Land-Ocean Surface Temperature Analysis (MLOST) is derived from two independent analyses, an Extended Reconstructed Sea Surface Temperature...

  15. Atmosphere-surface interactions over polar oceans and heterogeneous surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Vihma, T.

    1995-12-31

    Processes of interaction between the atmospheric boundary layer and the planetary surface have been studied with special emphasis on polar ocean surfaces: the open ocean, leads, polynyas and sea ice. The local exchange of momentum, heat and moisture has been studied experimentally both in the Weddell Sea and in the Greenland Sea. Exchange processes over heterogeneous surfaces are addressed by modelling studies. Over a homogeneous surface, the local turbulent fluxes can be reasonably well estimated using an iterative flux-profile scheme based on the Monin-Obukhov similarity theory. In the Greenland Sea, the near-surface air temperature and the generally small turbulent fluxes over the open ocean were affected by the sea surface temperature fronts. Over the sea ice cover in the Weddell Sea, the turbulent sensible heat flux was generally downwards, and together with an upward oceanic heat flux through the ice it compensated the heat loss from the surface via long-wave radiation. The wind dominated on time scales of days, while the current became important on longer time scales. The drift dynamics showed apparent spatial differences between the eastern and western regions, as well as between the Antarctic Circumpolar Current and the rest of the Weddell Sea. Inertial motion was present in regions of low ice concentration. The surface heterogeneity, arising e.g. from roughness or temperature distribution, poses a problem for the parameterization of surface exchange processes in large-scale models. In the case of neutral flow over a heterogeneous terrain, an effective roughness length can be used to parameterize the roughness effects

  16. Coralline algae elevate pH at the site of calcification under ocean acidification.

    Science.gov (United States)

    Cornwall, Christopher E; Comeau, Steeve; McCulloch, Malcolm T

    2017-10-01

    Coralline algae provide important ecosystem services but are susceptible to the impacts of ocean acidification. However, the mechanisms are uncertain, and the magnitude is species specific. Here, we assess whether species-specific responses to ocean acidification of coralline algae are related to differences in pH at the site of calcification within the calcifying fluid/medium (pH cf ) using δ 11 B as a proxy. Declines in δ 11 B for all three species are consistent with shifts in δ 11 B expected if B(OH) 4 - was incorporated during precipitation. In particular, the δ 11 B ratio in Amphiroa anceps was too low to allow for reasonable pH cf values if B(OH) 3 rather than B(OH) 4 - was directly incorporated from the calcifying fluid. This points towards δ 11 B being a reliable proxy for pH cf for coralline algal calcite and that if B(OH) 3 is present in detectable proportions, it can be attributed to secondary postincorporation transformation of B(OH) 4 - . We thus show that pH cf is elevated during calcification and that the extent is species specific. The net calcification of two species of coralline algae (Sporolithon durum, and Amphiroa anceps) declined under elevated CO 2 , as did their pH cf . Neogoniolithon sp. had the highest pH cf , and most constant calcification rates, with the decrease in pH cf being ¼ that of seawater pH in the treatments, demonstrating a control of coralline algae on carbonate chemistry at their site of calcification. The discovery that coralline algae upregulate pH cf under ocean acidification is physiologically important and should be included in future models involving calcification. © 2017 John Wiley & Sons Ltd.

  17. High-frequency dynamics of ocean pH: a multi-ecosystem comparison.

    Directory of Open Access Journals (Sweden)

    Gretchen E Hofmann

    Full Text Available The effect of Ocean Acidification (OA on marine biota is quasi-predictable at best. While perturbation studies, in the form of incubations under elevated pCO(2, reveal sensitivities and responses of individual species, one missing link in the OA story results from a chronic lack of pH data specific to a given species' natural habitat. Here, we present a compilation of continuous, high-resolution time series of upper ocean pH, collected using autonomous sensors, over a variety of ecosystems ranging from polar to tropical, open-ocean to coastal, kelp forest to coral reef. These observations reveal a continuum of month-long pH variability with standard deviations from 0.004 to 0.277 and ranges spanning 0.024 to 1.430 pH units. The nature of the observed variability was also highly site-dependent, with characteristic diel, semi-diurnal, and stochastic patterns of varying amplitudes. These biome-specific pH signatures disclose current levels of exposure to both high and low dissolved CO(2, often demonstrating that resident organisms are already experiencing pH regimes that are not predicted until 2100. Our data provide a first step toward crystallizing the biophysical link between environmental history of pH exposure and physiological resilience of marine organisms to fluctuations in seawater CO(2. Knowledge of this spatial and temporal variation in seawater chemistry allows us to improve the design of OA experiments: we can test organisms with a priori expectations of their tolerance guardrails, based on their natural range of exposure. Such hypothesis-testing will provide a deeper understanding of the effects of OA. Both intuitively simple to understand and powerfully informative, these and similar comparative time series can help guide management efforts to identify areas of marine habitat that can serve as refugia to acidification as well as areas that are particularly vulnerable to future ocean change.

  18. Late Archean Surface Ocean Oxygenation (Invited)

    Science.gov (United States)

    Kendall, B.; Reinhard, C.; Lyons, T. W.; Kaufman, A. J.; Anbar, A. D.

    2009-12-01

    Oxygenic photosynthesis must have evolved by 2.45-2.32 Ga, when atmospheric oxygen abundances first rose above 0.001% present atmospheric level (Great Oxidation Event; GOE). Biomarker evidence for a time lag between the evolution of cyanobacterial oxygenic photosynthesis and the GOE continues to be debated. Geochemical signatures from sedimentary rocks (redox-sensitive trace metal abundances, sedimentary Fe geochemistry, and S isotopes) represent an alternative tool for tracing the history of Earth surface oxygenation. Integrated high-resolution chemostratigraphic profiles through the 2.5 Ga Mt. McRae Shale (Pilbara Craton, Western Australia) suggest a ‘whiff’ of oxygen in the surface environment at least 50 M.y. prior to the GOE. However, the geochemical data from the Mt. McRae Shale does not uniquely constrain the presence or extent of Late Archean ocean oxygenation. Here, we present high-resolution chemostratigraphic profiles from 2.6-2.5 Ga black shales (upper Campbellrand Subgroup, Kaapvaal Craton, South Africa) that provide the earliest direct evidence for an oxygenated ocean water column. On the slope beneath the Campbellrand - Malmani carbonate platform (Nauga Formation), a mildly oxygenated water column (highly reactive iron to total iron ratios [FeHR/FeT] ≤ 0.4) was underlain by oxidizing sediments (low Re and Mo abundances) or mildly reducing sediments (high Re but low Mo abundances). After drowning of the carbonate platform (Klein Naute Formation), the local bottom waters became anoxic (FeHR/FeT > 0.4) and intermittently sulphidic (pyrite iron to highly reactive iron ratios [FePY/FeHR] > 0.8), conducive to enrichment of both Re and Mo in sediments, followed by anoxic and Fe2+-rich (ferruginous) conditions (high FeT, FePY/FeHR near 0). Widespread surface ocean oxygenation is suggested by Re enrichment in the broadly correlative Klein Naute Formation and Mt. McRae Shale, deposited ~1000 km apart in the Griqualand West and Hamersley basins

  19. Generalised expressions for the response of pH to changes in ocean chemistry

    NARCIS (Netherlands)

    Hagens, M.; Middelburg, J.B.M.

    2016-01-01

    The extent to which oceans are capable of buffering chemical changes resulting from the uptake of carbon dioxide (CO2) or other acidifying processes can be quantified using buffer factors. Here, we present general expressions describing the sensitivity of pH and concentrations of CO2 and other

  20. Slow and Steady: Ocean Circulation. The Influence of Sea Surface Height on Ocean Currents

    Science.gov (United States)

    Haekkinen, Sirpa

    2000-01-01

    The study of ocean circulation is vital to understanding how our climate works. The movement of the ocean is closely linked to the progression of atmospheric motion. Winds close to sea level add momentum to ocean surface currents. At the same time, heat that is stored and transported by the ocean warms the atmosphere above and alters air pressure distribution. Therefore, any attempt to model climate variation accurately must include reliable calculations of ocean circulation. Unlike movement of the atmosphere, movement of the ocean's waters takes place mostly near the surface. The major patterns of surface circulation form gigantic circular cells known as gyres. They are categorized according to their general location-equatorial, subtropical, subpolar, and polar-and may run across an entire ocean. The smaller-scale cell of ocean circulation is known' as an eddy. Eddies are much more common than gyres and much more difficult to track in computer simulations of ocean currents.

  1. Mouthguard and sports drinks on tooth surface pH.

    Science.gov (United States)

    Maeda, Y; Yang, T-C; Miyanaga, H; Tanaka, Y; Ikebe, K; Akimoto, N

    2014-09-01

    The influence of sports drinks and mouthguards on the pH level of tooth surface was examined. A custom-made mouthguard was fabricated for each subject. The pH level was measured by electric pH meter with sensitivity of 0.01 up to 30 min. Sports drinks (pH=3.75) containing 9.4% sugar were used in this study. Measurements were performed on a cohort of 23 female subjects without a mouthguard (control), wearing a mouthguard only (MG), wearing a mouthguard after 30 ml sports drink intake (SD+MG), wearing a mouthguard during a 5-min jogging exercise (MG+EX) and wearing a mouthguard during jogging after sports drink intake (SD+MG+EX). For 7 male subjects, the same measurements were performed while a sports drink was taken over the mouthguard (MG+SD, MD+EX+SD). MG showed statistically higher pH level than control (psports drinks were taken over the mouthguard, no significant differences in pH level were observed among the different conditions.Within the limitations of this study, it was suggested that wearing a mouthguard during exercise is in itself not a possible risk factor for dental caries, while wearing a mouthguard after consuming sports drinks is. © Georg Thieme Verlag KG Stuttgart · New York.

  2. Ka-band Doppler Scatterometer for Measurements of Ocean Vector Winds and Surface Currents

    Data.gov (United States)

    National Aeronautics and Space Administration — Ocean surface currents impact heat transport, surface momentum and gas fluxes, ocean productivity and marine biological communities. Ocean currents also have social...

  3. Empirical Algorithms to Predict pH and Aragonite Saturation State on SOCCOM Biogeochemical Argo Floats in the Pacific Sector of the Southern Ocean

    Science.gov (United States)

    Williams, N. L.; Juranek, L. W.; Feely, R. A.; Johnson, K. S.; Russell, J. L.

    2016-02-01

    The Southern Ocean plays a major role in the global uptake, transport, and storage of both heat and carbon, yet it remains one of the least-sampled regions of the ocean. The Southern Ocean Carbon and Climate Observations and Modeling (SOCCOM) project aims to fill the observational gaps by deploying over 200 autonomous profiling floats in the Southern Ocean over the next several years. Initial float deployments have greatly expanded our observational capability to include wintertime measurements as well as under-ice measurements, and many of these floats include novel biogeochemical sensors (pH, nitrate, oxygen). Here we present empirical algorithms that can be used to predict pH and ΩAragonite from other float-measured parameters (temperature, salinity, pressure, nitrate, oxygen). These algorithms were trained using bottle measurements from high-quality repeat hydrographic GO-SHIP cruises. We obtained R2 values of 0.98 (pH) and 0.99 (ΩAragonite) and RMS errors of 0.007 (pH) and 0.052 (ΩAragonite) for data between 100-1500 m. These algorithms will allow us to both validate pH data from these sensors, as well as predict ΩAragonite and pH on floats that do not have pH sensors. Here we present estimated pH and ΩAragonite over 20 months of deployment for several SOCCOM floats in the Pacific Sector of the Southern Ocean. The results show seasonal ranges in surface pH and ΩAragonite of 0.05 and 0.1, respectively.

  4. Comparison of two pH meters used for skin surface pH measurement: the pH meter 'pH900' from Courage & Khazaka versus the pH meter '1140' from Mettler Toledo.

    Science.gov (United States)

    Ehlers, C; Ivens, U I; Møller, M L; Senderovitz, T; Serup, J

    2001-05-01

    Measurement of skin surface pH is used in clinical research to evaluate hazardous shifts in pH following external exposures and to evaluate the state of diseased skin with acute or chronic changes. It is therefore important to measure skin surface pH as precisely as possible. The aim of this study was to compare two commercially available pH meters used for skin surface pH measurement, to reveal differences between them in measured skin pH on the forearm. The first pH meter (pH900) had a pointed electrode and a stabilisation period of 3 s. The second pH meter (pH meter 1140) had a circular electrode and no fixed stabilisation period. Twelve healthy subjects (6 male and 6 female Caucasians) entered the study. The pH measurements were performed once an hour from 8 a.m. to 3 p.m. on both forearms in five areas from the elbow to the "wristwatch" zone. In each area, three measurements were performed next to each other with both pH meters (15 measurements per arm per hour per pH meter). The pH900 has a higher measuring level and a higher variation than the pH meter 1140. A skin surface pH meter with a circular electrode and with no fixed stabilisation period is preferable. It is recommended that the pH meter be allowed to stabilise for at least 7 s before the result is read.

  5. Evaluation of OSCAR ocean surface current product in the tropical ...

    Indian Academy of Sciences (India)

    (Johnson et al. 2007). The OSCAR product is, however, a global product. Thus there is a pressing need to validate this product in the other basins of the world ocean, e.g., in the Indian Ocean. The present study is motivated by this need. In the present study, monthly climatology of OSCAR ocean surface currents in the TIO ...

  6. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample, profile and underway - surface observations using Alkalinity titrator, CTD and other instruments from the MIRAI in the Coral Sea, North Pacific Ocean and others from 2009-04-10 to 2009-07-03 (NODC Accession 0108084)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0108084 includes chemical, discrete sample, meteorological, physical, profile and underway - surface data collected from MIRAI in the Coral Sea, North...

  7. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer and other instruments from Benguela Stream in the Caribbean Sea, English Channel and North Atlantic Ocean from 2012-01-07 to 2012-09-03 (NCEI Accession 0157312)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157312 includes Surface underway, biological, chemical, meteorological, optical and physical data collected from Benguela Stream in the Caribbean...

  8. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer and other instruments from Benguela Stream in the Caribbean Sea, English Channel and North Atlantic Ocean from 2011-01-08 to 2011-12-29 (NCEI Accession 0157237)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157237 includes Surface underway, biological, chemical, meteorological, optical and physical data collected from Benguela Stream in the Caribbean...

  9. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer and other instruments from Benguela Stream in the Caribbean Sea, English Channel and North Atlantic Ocean from 2013-09-18 to 2014-01-05 (NCEI Accession 0157352)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157352 includes Surface underway, biological, chemical, meteorological, optical and physical data collected from Benguela Stream in the Caribbean...

  10. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample, profile and underway - surface observations using CTD, Carbon dioxide (CO2) gas analyzer and other instruments from the METEOR in the South Atlantic Ocean from 1992-12-27 to 1993-01-31 (NODC Accession 0115173)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115173 includes chemical, discrete sample, meteorological, physical, profile and underway - surface data collected from METEOR in the South Atlantic...

  11. Retrieval and assimilation of velocities at the ocean surface

    OpenAIRE

    Isern-Fontanet, Jordi; Ballabrera-Poy, Joaquim; Turiel, Antonio; García-Ladona, Emilio

    2017-01-01

    Ocean currents play a key role in Earth’s climate, they are of major importance for navigation and human activities at sea, and impact almost all processes that take place in the ocean. Nevertheless, their observation and forecasting are still difficult. First, direct measurements of ocean currents are difficult to obtain synoptically at global scale. Consequently, it has been necessary to use Sea Surface Height and Sea Surface Temperature measurements and refer to dynamical frameworks to der...

  12. Near-shore Antarctic pH variability has implications for the design of ocean acidification experiments

    Science.gov (United States)

    Kapsenberg, Lydia; Kelley, Amanda L.; Shaw, Emily C.; Martz, Todd R.; Hofmann, Gretchen E.

    2015-01-01

    Understanding how declining seawater pH caused by anthropogenic carbon emissions, or ocean acidification, impacts Southern Ocean biota is limited by a paucity of pH time-series. Here, we present the first high-frequency in-situ pH time-series in near-shore Antarctica from spring to winter under annual sea ice. Observations from autonomous pH sensors revealed a seasonal increase of 0.3 pH units. The summer season was marked by an increase in temporal pH variability relative to spring and early winter, matching coastal pH variability observed at lower latitudes. Using our data, simulations of ocean acidification show a future period of deleterious wintertime pH levels potentially expanding to 7–11 months annually by 2100. Given the presence of (sub)seasonal pH variability, Antarctica marine species have an existing physiological tolerance of temporal pH change that may influence adaptation to future acidification. Yet, pH-induced ecosystem changes remain difficult to characterize in the absence of sufficient physiological data on present-day tolerances. It is therefore essential to incorporate natural and projected temporal pH variability in the design of experiments intended to study ocean acidification biology.

  13. The physical structure of the oceanic surface-layer

    Energy Technology Data Exchange (ETDEWEB)

    Fedorov, K.N.

    1981-01-01

    A study is presented of the structure of the near-surface layer of the ocean under various hydrometeorological conditions. Such a study allows the isolation of border measures for a four characteristic regime for the top ocean layer: 1) intensive wind-wave mixing; 2) Langmuir circulation; 3) intense solar heating during still and calm weather (with and without internal wave modulations); 4) a pressing-out of surface sediment. It is demonstrated that the spatial temperature change in the ocean surface, the thermal structure, and the heat attainment in the top layer have various characteristics during different regimes and this must be considered during the measuring of the ocean surface temperature with the contact method as well as during the comparison of contact and satallite data on the ocean surface temperature. The necessity for more research in this area is underscored.

  14. Warming and surface ocean acidification over the last deglaciation: implications for foraminiferal assemblages

    Science.gov (United States)

    Dyez, K. A.; Hoenisch, B.; deMenocal, P. B.

    2017-12-01

    Although plankton drift with ocean currents, their presence and relative abundance varies across latitudes and environmental seawater conditions (e.g. temperature, pH, salinity). While earlier studies have focused on temperature as the primary factor for determining the regional species composition of planktic foraminiferal communities, evidence has recently been presented that foraminiferal shell thickness varies with ocean pH, and it remains unclear whether ongoing ocean acidification will cause ecological shifts within this plankton group. The transition from the last glacial maximum (LGM; 19,000-23,000 years B.P.) to the late Holocene (0-5,000 years B.P.) was characterized by both warming and acidification of the surface ocean, and thus provides an opportunity to study ecosystem shifts in response to these environmental changes. Here we provide new δ11B, Mg/Ca, and δ18O measurements from a suite of global sediment cores spanning this time range. We use these geochemical data to reconstruct ocean temperature, pH and salinity and pair the new data with previously published analyses of planktic foraminifera assemblages to study the respective effects of ocean warming and acidification on the foraminiferal habitat. At most open-ocean sample locations, our proxies indicate warming and acidification similar to previously published estimates, but in some marginal seas and coastal locations pH changes little between over the glacial termination. At face value, these observations suggest that warming is generally more important for ecosystem changes than acidification, at least over the slow rates of warming and ocean acidification in this time period. While geochemical data collection is being completed, we aim to include these data in an ecological model of foraminiferal habitat preferences.

  15. Evaluation of OSCAR ocean surface current product in the tropical ...

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Earth System Science; Volume 122; Issue 1. Evaluation of OSCAR ocean surface current product in the tropical Indian Ocean using in situ data. Rajesh Sikhakolli Rashmi Sharma Sujit Basu B S Gohil Abhijit Sarkar K V S R Prasad. Volume 122 Issue 1 February 2013 pp 187-199 ...

  16. Indian Ocean surface winds from NCMRWF analysis as compared to ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    Indian Ocean surface winds from NCMRWF analysis as compared to QuikSCAT and moored buoy winds. B N Goswami1 and E N Rajagopal2. 1Centre for Atmospheric and Oceanic Sciences, Indian Institute of Science, Bangalore 560 012, India. 2National Centre for Medium Range Weather Forecasting, Department of ...

  17. Transcriptomic responses to ocean acidification in larval sea urchins from a naturally variable pH environment.

    Science.gov (United States)

    Evans, Tyler G; Chan, Francis; Menge, Bruce A; Hofmann, Gretchen E

    2013-03-01

    Some marine ecosystems already experience natural declines in pH approximating those predicted with future anthropogenic ocean acidification (OA), the decline in seawater pH caused by the absorption of atmospheric CO2 . The molecular mechanisms that allow organisms to inhabit these low pH environments, particularly those building calcium carbonate skeletons, are unknown. Also uncertain is whether an enhanced capacity to cope with present day pH variation will confer resistance to future OA. To address these issues, we monitored natural pH dynamics within an intertidal habitat in the Northeast Pacific, demonstrating that upwelling exposes resident species to pH regimes not predicted to occur elsewhere until 2100. Next, we cultured the progeny of adult purple sea urchins (Strongylocentrotus purpuratus) collected from this region in CO2 -acidified seawater representing present day and near future ocean scenarios and monitored gene expression using transcriptomics. We hypothesized that persistent exposure to upwelling during evolutionary history will have selected for increased pH tolerance in this population and that their transcriptomic response to low pH seawater would provide insight into mechanisms underlying pH tolerance in a calcifying species. Resulting expression patterns revealed two important trends. Firstly, S. purpuratus larvae may alter the bioavailability of calcium and adjust skeletogenic pathways to sustain calcification in a low pH ocean. Secondly, larvae use different strategies for coping with different magnitudes of pH stress: initiating a robust transcriptional response to present day pH regimes but a muted response to near future conditions. Thus, an enhanced capacity to cope with present day pH variation may not translate into success in future oceans. © 2013 Blackwell Publishing Ltd.

  18. Ocean Surface Waves and Turbulence: Air-Sea Fluxes and Climate Variability

    Science.gov (United States)

    Melville, W. Kendall

    2009-11-01

    Apart from heating of the atmosphere, two of the most important consequences of current climate variability are changes in sea level, and acidification of the oceans. Over decadal time scales, changes in sea level are caused by changes in heat content and salinity of the ocean, and by changes in mass resulting from exchanges between the ocean, glaciers and other land-based reservoirs. The oceans have absorbed about one third of the anthropogenic CO2 due to fossil fuel burning. This reduces the green house effect in the atmosphere, but the CO2 reacts in the surface waters of the ocean to lower pH. Conservative projections of sea level rise over the next century are O(0.1 - 1) m, while ocean acidification is already having an impact on marine ecosystems. Both these processes depend on air-sea fluxes: heat flux for sea level rise, and gas flux for ocean acidification. These fluxes are among the most poorly constrained in current climate models, but both ultimately depend on fluid dynamics at the ocean surface and in the adjacent boundary layers. Traditional boundary layer models of the marine boundary layer and the marine atmospheric boundary layer were based on classical theories of boundary layers over rigid surfaces, but there is increasing evidence that these models must now include surface wave effects. In this talk the motivating climate data and modeling will be briefly reviewed, and then recent work on surface wave dynamics, air-sea fluxes and the adjacent boundary layers will be presented. The roles of surface wave breaking, Langmuir circulations, wave-turbulence interactions and gravity-capillary waves will be discussed.

  19. Surface temperature pattern of the Indian Ocean before summer monsoon

    Digital Repository Service at National Institute of Oceanography (India)

    Gopinathan, C.K.; Rao, D.P.

    The surface meteorological data collected during 1963 and 1964 indicate that the northward migration of the ITCZ is associated with a shift of the warm waters to the northern Indian Ocean. The warmer waters, found in the equatorial regions during...

  20. The timescales of global surface-ocean connectivity.

    Science.gov (United States)

    Jönsson, Bror F; Watson, James R

    2016-04-19

    Planktonic communities are shaped through a balance of local evolutionary adaptation and ecological succession driven in large part by migration. The timescales over which these processes operate are still largely unresolved. Here we use Lagrangian particle tracking and network theory to quantify the timescale over which surface currents connect different regions of the global ocean. We find that the fastest path between two patches--each randomly located anywhere in the surface ocean--is, on average, less than a decade. These results suggest that marine planktonic communities may keep pace with climate change--increasing temperatures, ocean acidification and changes in stratification over decadal timescales--through the advection of resilient types.

  1. Lidar equation for ocean surface and subsurface.

    Science.gov (United States)

    Josset, Damien; Zhai, Peng-Wang; Hu, Yongxiang; Pelon, Jacques; Lucker, Patricia L

    2010-09-27

    The lidar equation for ocean at optical wavelengths including subsurface signals is revisited using the recent work of the radiative transfer and ocean color community for passive measurements. The previous form of the specular and subsurface echo term are corrected from their heritage, which originated from passive remote sensing of whitecaps, and is improved for more accurate use in future lidar research. A corrected expression for specular and subsurface lidar return is presented. The previous formalism does not correctly address angular dependency of specular lidar return and overestimates the subsurface term by a factor ranging from 89% to 194% for a nadir pointing lidar. Suggestions for future improvements to the lidar equation are also presented.

  2. Variability in larval gut pH regulation defines sensitivity to ocean acidification in six species of the Ambulacraria superphylum.

    Science.gov (United States)

    Hu, Marian; Tseng, Yung-Che; Su, Yi-Hsien; Lein, Etienne; Lee, Hae-Gyeong; Lee, Jay-Ron; Dupont, Sam; Stumpp, Meike

    2017-10-11

    The unusual rate and extent of environmental changes due to human activities may exceed the capacity of marine organisms to deal with this phenomenon. The identification of physiological systems that set the tolerance limits and their potential for phenotypic buffering in the most vulnerable ontogenetic stages become increasingly important to make large-scale projections. Here, we demonstrate that the differential sensitivity of non-calcifying Ambulacraria (echinoderms and hemichordates) larvae towards simulated ocean acidification is dictated by the physiology of their digestive systems. Gastric pH regulation upon experimental ocean acidification was compared in six species of the superphylum Ambulacraria. We observed a strong correlation between sensitivity to ocean acidification and the ability to regulate gut pH. Surprisingly, species with tightly regulated gastric pH were more sensitive to ocean acidification. This study provides evidence that strict maintenance of highly alkaline conditions in the larval gut of Ambulacraria early life stages may dictate their sensitivity to decreases in seawater pH. These findings highlight the importance of identifying and understanding pH regulatory systems in marine larval stages that may contribute to substantial energetic challenges under near-future ocean acidification scenarios. © 2017 The Author(s).

  3. Indian Ocean surface winds from NCMRWF analysis as compared to ...

    Indian Academy of Sciences (India)

    The quality of the surface wind analysis at the National Centre for Medium Range Weather Forecasts (NCMRWF), New Delhi over the tropical Indian Ocean and its improvement in 2001 are examined by comparing it with in situ buoy measurements and satellite derived surface winds from NASA QuikSCAT satellite (QSCT) ...

  4. Auto-correlation analysis of ocean surface wind vectors

    Indian Academy of Sciences (India)

    The nature of the inherent temporal variability of surface winds is analyzed by comparison of winds obtained through different measurement methods. In this work, an auto-correlation analysis of a time series data of surface winds measured in situ by a deep water buoy in the Indian Ocean has been carried out. Hourly time ...

  5. Ocean Surface Current Vectors from MODIS Terra/Aqua Sea Surface Temperature Image Pairs, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Satellites that record imagery of the same sea surface area, at times separated by a few hours, can be used to estimate ocean surface velocity fields based on the...

  6. The influence of Southern Ocean surface buoyancy forcing on glacial-interglacial changes in the global deep ocean stratification

    OpenAIRE

    Sun, S; Eisenman, I; Stewart, AL

    2016-01-01

    ©2016. American Geophysical Union. All Rights Reserved. Previous studies have suggested that the global ocean density stratification below ∼3000 m is approximately set by its direct connection to the Southern Ocean surface density, which in turn is constrained by the atmosphere. Here the role of Southern Ocean surface forcing in glacial-interglacial stratification changes is investigated using a comprehensive climate model and an idealized conceptual model. Southern Ocean surface forcing is f...

  7. Surface wind mixing in the Regional Ocean Modeling System (ROMS)

    Science.gov (United States)

    Robertson, Robin; Hartlipp, Paul

    2017-12-01

    Mixing at the ocean surface is key for atmosphere-ocean interactions and the distribution of heat, energy, and gases in the upper ocean. Winds are the primary force for surface mixing. To properly simulate upper ocean dynamics and the flux of these quantities within the upper ocean, models must reproduce mixing in the upper ocean. To evaluate the performance of the Regional Ocean Modeling System (ROMS) in replicating the surface mixing, the results of four different vertical mixing parameterizations were compared against observations, using the surface mixed layer depth, the temperature fields, and observed diffusivities for comparisons. The vertical mixing parameterizations investigated were Mellor- Yamada 2.5 level turbulent closure (MY), Large- McWilliams- Doney Kpp (LMD), Nakanishi- Niino (NN), and the generic length scale (GLS) schemes. This was done for one temperate site in deep water in the Eastern Pacific and three shallow water sites in the Baltic Sea. The model reproduced the surface mixed layer depth reasonably well for all sites; however, the temperature fields were reproduced well for the deep site, but not for the shallow Baltic Sea sites. In the Baltic Sea, the models overmixed the water column after a few days. Vertical temperature diffusivities were higher than those observed and did not show the temporal fluctuations present in the observations. The best performance was by NN and MY; however, MY became unstable in two of the shallow simulations with high winds. The performance of GLS nearly as good as NN and MY. LMD had the poorest performance as it generated temperature diffusivities that were too high and induced too much mixing. Further observational comparisons are needed to evaluate the effects of different stratification and wind conditions and the limitations on the vertical mixing parameterizations.

  8. Iridium Oxide pH Sensor Based on Stainless Steel Wire for pH Mapping on Metal Surface

    Science.gov (United States)

    Shahrestani, S.; Ismail, M. C.; Kakooei, S.; Beheshti, M.; Zabihiazadboni, M.; Zavareh, M. A.

    2018-03-01

    A simple technique to fabricate the iridium oxide pH sensor is useful in several applications such as medical, food processing and engineering material where it is able to detect the changes of pH. Generally, the fabrication technique can be classified into three types: electro-deposition iridium oxide film (EIrOF), activated iridium oxide film (AIROF) and sputtering iridium oxide film (SIROF). This study focuses on fabricating electrode, calibration and test. Electro-deposition iridium oxide film is a simple and effective method of fabricating this kind of sensor via cyclic voltammetry process. The iridium oxide thick film was successfully electrodeposited on the surface of stainless steel wire with 500 cycles of sweep potential. A further analysis under FESEM shows detailed image of iridium oxide film which has cauliflower-liked microstructure. EDX analysis shows the highest element present are iridium and oxygen which concluded that the process is successful. The iridium oxide based pH sensor has shown a good performance in comparison to conventional glass pH sensor when it is being calibrated in buffer solutions with 2, 4, 7 and 9 pH values. The iridium oxide pH sensor is specifically designed to measure the pH on the surface of metal plate.

  9. About New Maps of Surface Currents of the World Ocean

    Science.gov (United States)

    Nikitin, O. P.; Kasyanov, S. Yu.

    2018-01-01

    Using the example of the surface currents map constructed for the Northern Atlantic on the basis of data of modern observations by means of drifting buoys, it is shown that the previously published maps of ocean surface currents, based on ship drift data, have become outdated and require an update. The influence of the bottom relief on the directions of surface layer currents is shown.

  10. The Proposed Surface Water and Ocean Topography (SWOT) Mission

    Science.gov (United States)

    Fu, Lee-Lueng; Alsdorf, Douglas; Rodriguez, Ernesto; Morrow, Rosemary; Mognard, Nelly; Vaze, Parag; Lafon, Thierry

    2012-01-01

    A new space mission concept called Surface Water and Ocean Topography (SWOT) is being developed jointly by a collaborative effort of the international oceanographic and hydrological communities for making high-resolution measurement of the water elevation of both the ocean and land surface water to answer the questions about the oceanic submesoscale processes and the storage and discharge of land surface water. The key instrument payload would be a Ka-band radar interferometer capable of making high-resolution wide-swath altimetry measurement. This paper describes the proposed science objectives and requirements as well as the measurement approach of SWOT, which is baselined to be launched in 2019. SWOT would demonstrate this new approach to advancing both oceanography and land hydrology and set a standard for future altimetry missions.

  11. Simulation Tool for GNSS Ocean Surface Reflections

    DEFF Research Database (Denmark)

    Høeg, Per; von Benzon, Hans-Henrik; Durgonics, Tibor

    2015-01-01

    . This impedance concept gives an accurate lower boundary condition in the determination of the electromagnetic field, and makes itpossible to simulate reflections and the effects of transitions between different mediums. A semi-isotropic Philipsspectrum is used to represent the air-sea interaction.Simulated GPS...... on the solution of the parabolic equation. The parabolic equation in our simulator is solvedusing the split-step sine transformation. The Earth’s surface is modeled with the use of an impedance model. The value of the Earth impedance is given as a function of the range along the surface of the Earth...

  12. CARBON-USE STRATEGIES IN MACROALGAE: DIFFERENTIAL RESPONSES TO LOWERED PH AND IMPLICATIONS FOR OCEAN ACIDIFICATION(1).

    Science.gov (United States)

    Cornwall, Christopher E; Hepburn, Christopher D; Pritchard, Daniel; Currie, Kim I; McGraw, Christina M; Hunter, Keith A; Hurd, Catriona L

    2012-02-01

    Ocean acidification (OA) is a reduction in oceanic pH due to increased absorption of anthropogenically produced CO2 . This change alters the seawater concentrations of inorganic carbon species that are utilized by macroalgae for photosynthesis and calcification: CO2 and HCO3 (-) increase; CO3 (2-) decreases. Two common methods of experimentally reducing seawater pH differentially alter other aspects of carbonate chemistry: the addition of CO2 gas mimics changes predicted due to OA, while the addition of HCl results in a comparatively lower [HCO3 (-) ]. We measured the short-term photosynthetic responses of five macroalgal species with various carbon-use strategies in one of three seawater pH treatments: pH 7.5 lowered by bubbling CO2 gas, pH 7.5 lowered by HCl, and ambient pH 7.9. There was no difference in photosynthetic rates between the CO2 , HCl, or pH 7.9 treatments for any of the species examined. However, the ability of macroalgae to raise the pH of the surrounding seawater through carbon uptake was greatest in the pH 7.5 treatments. Modeling of pH change due to carbon assimilation indicated that macroalgal species that could utilize HCO3 (-) increased their use of CO2 in the pH 7.5 treatments compared to pH 7.9 treatments. Species only capable of using CO2 did so exclusively in all treatments. Although CO2 is not likely to be limiting for photosynthesis for the macroalgal species examined, the diffusive uptake of CO2 is less energetically expensive than active HCO3 (-) uptake, and so HCO3 (-) -using macroalgae may benefit in future seawater with elevated CO2 . © 2011 Phycological Society of America.

  13. View-Dependent Tessellation and Simulation of Ocean Surfaces

    Directory of Open Access Journals (Sweden)

    Anna Puig-Centelles

    2014-01-01

    Full Text Available Modeling and rendering realistic ocean scenes have been thoroughly investigated for many years. Its appearance has been studied and it is possible to find very detailed simulations where a high degree of realism is achieved. Nevertheless, among the solutions to ocean rendering, real-time management of the huge heightmaps that are necessary for rendering an ocean scene is still not solved. We propose a new technique for simulating the ocean surface on GPU. This technique is capable of offering view-dependent approximations of the mesh while maintaining coherence among the extracted approximations. This feature is very important as most solutions previously presented must retessellate from the initial mesh. Our solution is able to use the latest extracted approximation when refining or coarsening the mesh.

  14. Ocean Surface Wind Speed of Hurricane Helene Observed by SAR

    DEFF Research Database (Denmark)

    Xu, Qing; Cheng, Yongcun; Li, Xiaofeng

    2011-01-01

    The hurricanes can be detected by many remote sensors, but synthetic aperture radar (SAR) can yield high-resolution (sub-kilometer) and low-level wind information that cannot be seen below the cloud by other sensors. In this paper, an assessment of SAR capability of monitoring high......-resolution hurricane was conducted. A case study was carried out to retrieve ocean surface wind field from C-band RADARSAT-1 SAR image which captured the structure of hurricane Helene over the Atlantic Ocean on 20 September, 2006. With wind direction from the outputs of U.S. Navy Operational Global Atmospheric...... CIWRAP models have been tested to extract wind speed from SAR data. The SAR retrieved ocean surface winds were compared to the aircraft wind speed observations from stepped frequency microwave radiometer (SFMR). The results show the capability of hurricane wind monitoring by SAR....

  15. Ocean Surface Carbon Dioxide Fugacity Observed from Space

    Science.gov (United States)

    Liu, W. Timothy; Xie, Xiaosu

    2014-01-01

    We have developed and validated a statistical model to estimate the fugacity (or partial pressure) of carbon dioxide (CO2) at sea surface (pCO2sea) from space-based observations of sea surface temperature (SST), chlorophyll, and salinity. More than a quarter million in situ measurements coincident with satellite data were compiled to train and validate the model. We have produced and made accessible 9 years (2002-2010) of the pCO2sea at 0.5 degree resolutions daily over the global ocean. The results help to identify uncertainties in current JPL Carbon Monitoring System (CMS) model-based and bottom-up estimates over the ocean. The utility of the data to reveal multi-year and regional variability of the fugacity in relation to prevalent oceanic parameters is demonstrated.

  16. Reduction in Surface Ocean Carbon Storage across the Middle Miocene

    Science.gov (United States)

    Babila, T. L.; Sosdian, S. M.; Foster, G. L.; Lear, C. H.

    2017-12-01

    During the Middle Miocene, Earth underwent a profound climate shift from the warmth of the Miocene Climatic Optimum (MCO; 14-17 Ma) to the stable icehouse of today during the Middle Miocene Climate transition (MMCT). Elevated atmospheric carbon dioxide concentrations (pCO2) revealed by boron isotope records (δ11B) link massive volcanic outputs of Columbia River Flood Basalts to the general warmth of MCO. Superimposed on the long-term cooling trend (MMCT) is a gradual pCO2 decline and numerous positive carbon isotope (δ13C) excursions that indicate dynamic variations in the global carbon cycle. Enhanced organic carbon burial via marine productivity, increased silicate weathering and volcanic emission cessation are each invoked to explain the drawdown of pCO2. To better constrain the oceanic role in carbon sequestration over the Middle Miocene detailed records of carbonate chemistry are needed. We present high resolution Boron/Calcium (B/Ca) and δ13C records in planktonic foraminifer T.trilobus spanning 12-17 Ma at ODP 761 (tropical eastern Indian Ocean) to document changes in surface ocean carbonate chemistry. An overall 30% increase in B/Ca ratios is expressed as two stepwise phases occurring at 14.7 and 13 Ma. Cyclic B/Ca variations are coherent with complimentary δ13C records suggesting a tight coupling between ocean carbonate chemistry parameters. Lower resolution B/Ca data at DSDP 588 (Pacific) and ODP 926 (Atlantic) corroborate the trends observed at ODP 761. We employ a paired approach that combines B/Ca (this study) to δ11B (Foster et al., 2012) and an ad hoc calibration to estimate changes in surface ocean dissolved inorganic carbon (DIC). We estimate a substantial decrease in surface ocean DIC spanning the Middle Miocene that culminates with modern day like values. This gradual decline in surface ocean DIC is coeval with existing deep-ocean records which together suggests a whole ocean reduction in carbon storage. We speculate that enhanced weathering

  17. Circulation of the surface waters in the north Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Varadachari, V.V.R.; Sharma, G.S.

    The circulation pattern of the surface waters in the North Indian Ocean for different months of the year is discussed. In order to arrive at a reliable and detailed picture of the circulation pattern, streamlines are drawn using the isogon technique...

  18. A uniform, quality controlled Surface Ocean CO2 Atlas (SOCAT

    Directory of Open Access Journals (Sweden)

    B. Pfeil

    2013-04-01

    Full Text Available A well-documented, publicly available, global data set of surface ocean carbon dioxide (CO2 parameters has been called for by international groups for nearly two decades. The Surface Ocean CO2 Atlas (SOCAT project was initiated by the international marine carbon science community in 2007 with the aim of providing a comprehensive, publicly available, regularly updated, global data set of marine surface CO2, which had been subject to quality control (QC. Many additional CO2 data, not yet made public via the Carbon Dioxide Information Analysis Center (CDIAC, were retrieved from data originators, public websites and other data centres. All data were put in a uniform format following a strict protocol. Quality control was carried out according to clearly defined criteria. Regional specialists performed the quality control, using state-of-the-art web-based tools, specially developed for accomplishing this global team effort. SOCAT version 1.5 was made public in September 2011 and holds 6.3 million quality controlled surface CO2 data points from the global oceans and coastal seas, spanning four decades (1968–2007. Three types of data products are available: individual cruise files, a merged complete data set and gridded products. With the rapid expansion of marine CO2 data collection and the importance of quantifying net global oceanic CO2 uptake and its changes, sustained data synthesis and data access are priorities.

  19. Evaluation of OSCAR ocean surface current product in the tropical ...

    Indian Academy of Sciences (India)

    combined fashion, have contributed to the superior performance of the present algorithm for generat- ing ocean surface current. Validation and error analysis of the OSCAR pro- ..... EC (figure 4) through the appearance of strong semiannual periodicity. The SEC peaks in July, the peak being smoother in OSCAR climatology.

  20. Phase spectral composition of wind generated ocean surface waves

    Digital Repository Service at National Institute of Oceanography (India)

    Varkey, M.J.

    A study of the composition of the phase spectra of wind generated ocean surface waves is carried out using wave records collected employing a ship borne wave recorder. It is found that the raw phase spectral estimates could be fitted by the Uniform...

  1. Interpretation of nonlinearity in wind generated ocean surface waves

    Digital Repository Service at National Institute of Oceanography (India)

    Varkey, M.J.

    This study attempts to resolve a mix-up between a physical process and its mathematical interpretation in the context of wind waves on ocean surface. Wind generated wave systems, are conventionally interpreted as a result of interaction of a number...

  2. Auto-correlation analysis of ocean surface wind vectors

    Indian Academy of Sciences (India)

    M. Senthilkumar (Newgen Imaging) 1461 1996 Oct 15 13:05:22

    In this work, an auto-correlation analysis of a time series data of surface winds measured in situ by a deep water buoy in the Indian Ocean has been carried out. Hourly time series data available for 240 hours in the month of May, 1999 were subjected to an auto-correlation analysis. The analysis indicates an exponential fall ...

  3. NOAA Climate Data Record (CDR) of Ocean Near Surface Atmospheric Properties, Version 2

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The NOAA Ocean Surface Bundle (OSB) Climate Data Record (CDR) consist of three parts: sea surface temperature; near-surface wind speed, air temperature, and specific...

  4. Natural variability in the surface ocean carbonate ion concentration

    OpenAIRE

    N. S. Lovenduski; M. C. Long; K. Lindsay

    2015-01-01

    We investigate variability in the surface ocean carbonate ion concentration ([CO32−]) on the basis of a long control simulation with a fully-coupled Earth System Model. The simulation is run with a prescribed, pre-industrial atmospheric CO2 concentration for 1000 years, permitting investigation of natural [CO32−] variability on interannual to multi-decadal timescales. We find high interannual variability in surface [CO32−] in the tropical...

  5. Natural variability in the surface ocean carbonate ion concentration

    OpenAIRE

    Lovenduski, N. S.; Long, M. C.; Lindsay, K.

    2015-01-01

    We investigate variability in the surface ocean carbonate ion concentration ([CO32−]) on the basis of a~long control simulation with an Earth System Model. The simulation is run with a prescribed, pre-industrial atmospheric CO2 concentration for 1000 years, permitting investigation of natural [CO32−] variability on interannual to multi-decadal timescales. We find high interannual variability in surface [CO32−] in the tropical Pacific and ...

  6. Local pH at the surface of hen egg white lysozyme

    Science.gov (United States)

    Otosu, Takuhiro; Kobayashi, Kaito; Yamaguchi, Shoichi

    2018-02-01

    The microenvironment at the surface of hen-egg-white lysozyme (HEWL) was examined by analyzing the change in pKa of fluorescein isothiocyanate (FITC) upon binding to the N-terminus of HEWL. The result showed that the local pH at the HEWL surface is higher than the bulk pH. Furthermore, the data showed that the difference between the local and bulk pH becomes larger with decreasing pH, suggesting HEWL repels more protons at lower pH. Because the local pH affects the protonation states of functional amino-acids at the protein surface, the results provide the fundamental insight into the microenvironment at the protein surface.

  7. The Relationship between Gastric Juice Nitrate/Nitrite Concentrations and Gastric Mucosal Surface pH

    OpenAIRE

    Lee, Hae Kyung; Kim, Hyunjung; Kim, Hyung-Keun; Cho, Young-Seok; Kim, Byung-Wook; Han, Sok-Won; Maeng, Lee So; Chae, Hiun-Suk; Kim, Hee Na

    2012-01-01

    Purpose To investigate gastric juice nitrate/nitrite concentration according to mucosal surface pH extent (area) of gastric corpus intimately contacting the gastric juice. Materials and Methods We included ninety-nine patients with dyspepsia. To evaluate gastric mucosal surface pH and its extent, gastric chromosocpy was performed by spraying phenol red dye on the corpus mucosa and estimating the extent of area with color changed. Nitrate/nitrite concentrations and pH of gastric juice were mea...

  8. Surface Ocean CO2 Atlas (SOCAT) gridded data products

    Energy Technology Data Exchange (ETDEWEB)

    Sabine, Christopher [NOAA Pacific Marine Environmental Laboratory; Hankin, S. [Pacific Northwest National Laboratory (PNNL); Koyuk, H [Joint Institute for the Study of the Atmosphere and Ocean, University of Washington; Bakker, D C E [School of Environmental Sciences, University of East Anglia, Norwich, UK; Pfeil, B [Geophysical Institute, University of Bergen; Uni Research AS, Bergen, Norway; Olsen, A [Bjerknes Centre for Climate Research, UNIFOB AS, Bergen, Norway; Metzl, N [Universite Pierre et Marie Curie, LOCEAN/IPSL, Paris, France; Kozyr, Alexander [ORNL; Fassbender, A [School of Oceanography, University of Washington, Seattle, WA; Manke, A [Pacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration; Malczyk, J [Jetz Laboratory, Department of Ecology and Evolutionary Biology, Yale University; Akl, J [CSIRO Wealth from Oceans Flagship, Hobart, Tasmania, Australia; Alin, S R [Pacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration; Bellerby, R G J [Geophysical Institute, University of Bergen, Bergen, Norway; Borges, A [University of Liege, Chemical Oceanography Unit, Institut de Physique, Liege, Belgium; Boutin, J [Universite Pierre et Marie Curie, LOCEAN/IPSL, Paris, France; Brown, P J [School of Environmental Sciences, University of East Anglia, Norwich, UK; Cai, W-J [Department of Marine Sciences, University of Georgia; Chavez, F P [Monterey Bay Aquarium Research Institute, Moss Landing, CA; Chen, A [Institute of Marine Geology and Chemistry, National Sun Yat-sen University, Kaohsiung, Taiwan; Cosa, C [Pacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration; Feely, R A [Pacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration; Gonzalez-Davila, M [Universidad de Las Palmas de Gran Canaria, Facultad de Ciencias del Mar, Las Palmas de Gran Canaria,; Goyet, C [Institut de Modélisation et d' Analyse en Géo-Environnement et Santé, Université de Perpignan; Hardman-Mountford, N [CSIRO, Marine and Atmospheric Research, Wembley, Western Australia, Australia; Heinze, C [Geophysical Institute, University of Bergen, Bergen, Norway; Hoppema, M [Alfred Wegener Institute for Polar and Marine Research, Bremerhaven, Germany; Hunt, C W [Ocean Process Analysis Lab, University of New Hampshire, Durham, New Hampshire; Hydes, D [National Oceanography Centre, Southampton, UK; Ishii, M [Japan Meteorological Agency, Meteorological Research Institute, Tsukuba, Japan; Johannessen, T [Geophysical Institute, University of Bergen, Bergen, Norway; Key, R M [Atmospheric and Oceanic Sciences, Princeton University, Princeton, New Jersey; Kortzinger, A [GEOMAR, Helmholtz Centre for Ocean Research, Kiel, Germany; Landschutzer, P [School of Environmental Sciences, University of East Anglia, Norwich, UK; Lauvset, S K [Geophysical Institute, University of Bergen, Bergen, Norway; Lefevre, N [Université Pierre et Marie Curie, LOCEAN/IPSL, Paris, France; Lenton, A [Centre for Australian Weather and Climate Research, Hobart, Tasmania, Australia; Lourantou, A [Université Pierre et Marie Curie, LOCEAN/IPSL, Paris, France; Merlivat, L [Université Pierre et Marie Curie, LOCEAN/IPSL, Paris, France; Midorikawa, T [Nagasaki Marine Observatory, Nagasaki, Japan; Mintrop, L [MARIANDA, Kiel, Germany; Miyazaki, C [Faculty of Environmental Earth Science, Hokkaido University, Hokkaido, Japan; Murata, A [Japan Agency for Marine-Earth Science and Technology, Yokosuka, Japan; Nakadate, A [Marine Division, Global Environment and Marine Department, Japan Meteorological Agency, Tokyo, Japan; Nakano, Y [Japan Agency for Marine-Earth Science and Technology, Yokosuka, Japan; Nakaoka, S [National Institute for Environmental Studies (NIES), Tsukuba, Japan; Nojiri, Y [National Institute for Environmental Studies, Tsukuba, Japan; et al.

    2013-01-01

    A well documented, publicly available, global data set for surface ocean carbon dioxide (CO2) parameters has been called for by international groups for nearly two decades. The Surface Ocean CO2 Atlas (SOCAT) project was initiated by the international marine carbon science community in 2007 with the aim of providing a comprehensive, publicly available, regularly updated, global data set of marine surface CO2, which had been subject to quality control (QC). SOCAT version 1.5 was made public in September 2011 and holds 6.3 million quality controlled surface CO2 data from the global oceans and coastal seas, spanning four decades (1968 2007). The SOCAT gridded data is the second data product to come from the SOCAT project. Recognizing that some groups may have trouble working with millions of measurements, the SOCAT gridded product was generated to provide a robust regularly spaced fCO2 product with minimal spatial and temporal interpolation which should be easier to work with for many applications. Gridded SOCAT is rich with information that has not been fully explored yet, but also contains biases and limitations that the user needs to recognize and address.

  9. Microwave Remote Sensing Modeling of Ocean Surface Salinity and Winds Using an Empirical Sea Surface Spectrum

    Science.gov (United States)

    Yueh, Simon H.

    2004-01-01

    Active and passive microwave remote sensing techniques have been investigated for the remote sensing of ocean surface wind and salinity. We revised an ocean surface spectrum using the CMOD-5 geophysical model function (GMF) for the European Remote Sensing (ERS) C-band scatterometer and the Ku-band GMF for the NASA SeaWinds scatterometer. The predictions of microwave brightness temperatures from this model agree well with satellite, aircraft and tower-based microwave radiometer data. This suggests that the impact of surface roughness on microwave brightness temperatures and radar scattering coefficients of sea surfaces can be consistently characterized by a roughness spectrum, providing physical basis for using combined active and passive remote sensing techniques for ocean surface wind and salinity remote sensing.

  10. Surface Ocean CO2 Atlas (SOCAT gridded data products

    Directory of Open Access Journals (Sweden)

    C. L. Sabine

    2013-04-01

    Full Text Available As a response to public demand for a well-documented, quality controlled, publically available, global surface ocean carbon dioxide (CO2 data set, the international marine carbon science community developed the Surface Ocean CO2 Atlas (SOCAT. The first SOCAT product is a collection of 6.3 million quality controlled surface CO2 data from the global oceans and coastal seas, spanning four decades (1968–2007. The SOCAT gridded data presented here is the second data product to come from the SOCAT project. Recognizing that some groups may have trouble working with millions of measurements, the SOCAT gridded product was generated to provide a robust, regularly spaced CO2 fugacity (fCO2 product with minimal spatial and temporal interpolation, which should be easier to work with for many applications. Gridded SOCAT is rich with information that has not been fully explored yet (e.g., regional differences in the seasonal cycles, but also contains biases and limitations that the user needs to recognize and address (e.g., local influences on values in some coastal regions.

  11. Constraining the climate and ocean pH of the early Earth with a geological carbon cycle model.

    Science.gov (United States)

    Krissansen-Totton, Joshua; Arney, Giada N; Catling, David C

    2018-04-02

    The early Earth's environment is controversial. Climatic estimates range from hot to glacial, and inferred marine pH spans strongly alkaline to acidic. Better understanding of early climate and ocean chemistry would improve our knowledge of the origin of life and its coevolution with the environment. Here, we use a geological carbon cycle model with ocean chemistry to calculate self-consistent histories of climate and ocean pH. Our carbon cycle model includes an empirically justified temperature and pH dependence of seafloor weathering, allowing the relative importance of continental and seafloor weathering to be evaluated. We find that the Archean climate was likely temperate (0-50 °C) due to the combined negative feedbacks of continental and seafloor weathering. Ocean pH evolves monotonically from [Formula: see text] (2σ) at 4.0 Ga to [Formula: see text] (2σ) at the Archean-Proterozoic boundary, and to [Formula: see text] (2σ) at the Proterozoic-Phanerozoic boundary. This evolution is driven by the secular decline of pCO 2 , which in turn is a consequence of increasing solar luminosity, but is moderated by carbonate alkalinity delivered from continental and seafloor weathering. Archean seafloor weathering may have been a comparable carbon sink to continental weathering, but is less dominant than previously assumed, and would not have induced global glaciation. We show how these conclusions are robust to a wide range of scenarios for continental growth, internal heat flow evolution and outgassing history, greenhouse gas abundances, and changes in the biotic enhancement of weathering. Copyright © 2018 the Author(s). Published by PNAS.

  12. Macroalgae may mitigate ocean acidification effects on mussel calcification by increasing pH and its fluctuations

    KAUST Repository

    Wahl, M.

    2017-06-26

    Ocean acidification (OA) is generally assumed to negatively impact calcification rates of marine organisms. At a local scale however, biological activity of macrophytes may generate pH fluctuations with rates of change that are orders of magnitude larger than the long-term trend predicted for the open ocean. These fluctuations may in turn impact benthic calcifiers in the vicinity. Combining laboratory, mesocosm and field studies, such interactions between OA, the brown alga Fucus vesiculosus, the sea grass Zostera marina and the blue mussel Mytilus edulis were investigated at spatial scales from decimetres to 100s of meters in the western Baltic. Macrophytes increased the overall mean pH of the habitat by up to 0.3 units relative to macrophyte-free, but otherwise similar, habitats and imposed diurnal pH fluctuations with amplitudes ranging from 0.3 to more than 1 pH unit. These amplitudes and their impact on mussel calcification tended to increase with increasing macrophyte biomass to bulk water ratio. At the laboratory and mesocosm scales, biogenic pH fluctuations allowed mussels to maintain calcification even under acidified conditions by shifting most of their calcification activity into the daytime when biogenic fluctuations caused by macrophyte activity offered temporal refuge from OA stress. In natural habitats with a low biomass to water body ratio, the impact of biogenic pH fluctuations on mean calcification rates of M. edulis was less pronounced. Thus, in dense algae or seagrass habitats, macrophytes may mitigate OA impact on mussel calcification by raising mean pH and providing temporal refuge from acidification stress.

  13. Surface pH controls purple-to-blue transition of bacteriorhodopsin. A theoretical model of purple membrane surface

    OpenAIRE

    Szundi, I.; Stoeckenius, W.

    1989-01-01

    We have developed a surface model of purple membrane and applied it in an analysis of the purple-to-blue color change of bacteriorhodopsin which is induced by acidification or deionization. The model is based on dissociation and double layer theory and the known membrane structure. We calculated surface pH, ion concentrations, charge density, and potential as a function of bulk pH and concentration of mono- and divalent cations. At low salt concentrations, the surface pH is significantly lowe...

  14. Evaluation of Scaling Approaches for the Oceanic Dissipation Rate of Turbulent Kinetic Energy in the Surface Ocean

    Science.gov (United States)

    Esters, L. T.; Ward, B.; Sutherland, G.; Ten Doeschate, A.; Landwehr, S.; Bell, T. G.; Christensen, K. H.

    2016-02-01

    The air-sea exchange of heat, gas and momentum plays an important role for the Earth's weather and global climate. The exchange processes between ocean and atmosphere are influenced by the prevailing surface ocean dynamics. This surface ocean is a highly turbulent region where there is enhanced production of turbulent kinetic energy (TKE). The dissipation rate of TKE (ɛ) in the surface ocean is an important process for governing the depth of both the mixing and mixed layers, which are important length-scales for many aspects of ocean research. However, there exist very limited observations of ɛ under open ocean conditions and consequently our understanding of how to model the dissipation profile is very limited. The approaches to model profiles of ɛ that exist, differ by orders of magnitude depending on their underlying theoretical assumption and included physical processes. Therefore, scaling ɛ is not straight forward and requires open ocean measurements of ɛ to validate the respective scaling laws. This validated scaling of ɛ, is for example required to produce accurate mixed layer depths in global climate models. Errors in the depth of the ocean surface boundary layer can lead to biases in sea surface temperature. Here, we present open ocean measurements of ɛ from the Air-Sea Interaction Profiler (ASIP) collected during several cruises in different ocean basins. ASIP is an autonomous upwardly rising microstructure profiler allowing undisturbed profiling up to the ocean surface. These direct measurements of ɛ under various types of atmospheric and oceanic conditions along with measurements of atmospheric fluxes and wave conditions allow us to make a unique assessment of several scaling approaches based on wind, wave and buoyancy forcing. This will allow us to best assess the most appropriate ɛ-based parameterisation for air-sea exchange.

  15. Arctic Ocean surface geostrophic circulation 2003–2014

    Directory of Open Access Journals (Sweden)

    T. W. K. Armitage

    2017-07-01

    Full Text Available Monitoring the surface circulation of the ice-covered Arctic Ocean is generally limited in space, time or both. We present a new 12-year record of geostrophic currents at monthly resolution in the ice-covered and ice-free Arctic Ocean derived from satellite radar altimetry and characterise their seasonal to decadal variability from 2003 to 2014, a period of rapid environmental change in the Arctic. Geostrophic currents around the Arctic basin increased in the late 2000s, with the largest increases observed in summer. Currents in the southeastern Beaufort Gyre accelerated in late 2007 with higher current speeds sustained until 2011, after which they decreased to speeds representative of the period 2003–2006. The strength of the northwestward current in the southwest Beaufort Gyre more than doubled between 2003 and 2014. This pattern of changing currents is linked to shifting of the gyre circulation to the northwest during the time period. The Beaufort Gyre circulation and Fram Strait current are strongest in winter, modulated by the seasonal strength of the atmospheric circulation. We find high eddy kinetic energy (EKE congruent with features of the seafloor bathymetry that are greater in winter than summer, and estimates of EKE and eddy diffusivity in the Beaufort Sea are consistent with those predicted from theoretical considerations. The variability of Arctic Ocean geostrophic circulation highlights the interplay between seasonally variable atmospheric forcing and ice conditions, on a backdrop of long-term changes to the Arctic sea ice–ocean system. Studies point to various mechanisms influencing the observed increase in Arctic Ocean surface stress, and hence geostrophic currents, in the 2000s – e.g. decreased ice concentration/thickness, changing atmospheric forcing, changing ice pack morphology; however, more work is needed to refine the representation of atmosphere–ice–ocean coupling in models before we can fully

  16. Surface pH controls purple-to-blue transition of bacteriorhodopsin. A theoretical model of purple membrane surface.

    Science.gov (United States)

    Szundi, I; Stoeckenius, W

    1989-08-01

    We have developed a surface model of purple membrane and applied it in an analysis of the purple-to-blue color change of bacteriorhodopsin which is induced by acidification or deionization. The model is based on dissociation and double layer theory and the known membrane structure. We calculated surface pH, ion concentrations, charge density, and potential as a function of bulk pH and concentration of mono- and divalent cations. At low salt concentrations, the surface pH is significantly lower than the bulk pH and it becomes independent of bulk pH in the deionized membrane suspension. Using an experimental acid titration curve for neutral, lipid-depleted membrane, we converted surface pH into absorption values. The calculated bacteriohodopsin color changes for acidification of purple, and titrations of deionized blue membrane with cations or base agree well with experimental results. No chemical binding is required to reproduce the experimental curves. Surface charge and potential changes in acid, base and cation titrations are calculated and their relation to the color change is discussed. Consistent with structural data, 10 primary phosphate and two basic surface groups per bacteriorhodopsin are sufficient to obtain good agreement between all calculated and experimental curves. The results provide a theoretical basis for our earlier conclusion that the purple-to-blue transition must be attributed to surface phenomena and not to cation binding at specific sites in the protein.

  17. Visible-infrared remote-sensing model and applications for ocean waters. Ph.D. Thesis

    Science.gov (United States)

    Lee, Zhongping

    1994-01-01

    Remote sensing has become important in the ocean sciences, especially for research involving large spatial scales. To estimate the in-water constituents through remote sensing, whether carried out by satellite or airplane, the signal emitted from beneath the sea surface, the so called water-leaving radiance (L(w)), is of prime importance. The magnitude of L(w) depends on two terms: one is the intensity of the solar input, and the other is the reflectance of the in-water constituents. The ratio of the water-leaving radiance to the downwelling irradiance (E(d)) above the sear surface (remote-sensing reflectance, R(sub rs)) is independent of the intensity of the irradiance input, and is largely a function of the optical properties of the in-water constituents. In this work, a model is developed to interpret r(sub rs) for ocean water in the visible-infrared range. In addition to terms for the radiance scattered from molecules and particles, the model includes terms that describe contributions from bottom reflectance, fluorescence of gelbstoff or colored dissolved organic matter (CDOM), and water Raman scattering. By using this model, the measured R(sub rs) of waters from the West Florida Shelf to the Mississippi River plume, which covered a (concentration of chlorophyll a) range of 0.07 - 50 mg/cu m, were well interpreted. The average percentage difference (a.p.d.) between the measured and modeled R(sub rs) is 3.4%, and, for the shallow waters, the model-required water depth is within 10% of the chart depth. Simple mathematical simulations for the phytoplankton pigment absorption coefficient (a(sub theta)) are suggested for using the R(sub rs) model. The inverse problem of R(sub rs), which is to analytically derive the in-water constituents from R(sub rs) data alone, can be solved using the a(sub theta) functions without prior knowledge of the in-water optical properties. More importantly, this method avoids problems associated with a need for knowledge of the shape

  18. Sea surface temperature and salinity from the Global Ocean Surface Underway Data (GOSUD) from 1980-01-03 to present

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This collection contains the Global Ocean Surface Underway Data (GOSUD) from 1980-01-03 to present as submitted to NOAA/NCEI. The data includes information about sea...

  19. SWOT, The Surface Water and Ocean Topography Satellite Mission (Invited)

    Science.gov (United States)

    Alsdorf, D.; Andreadis, K.; Bates, P. D.; Biancamaria, S.; Clark, E.; Durand, M. T.; Fu, L.; Lee, H.; Lettenmaier, D. P.; Mognard, N. M.; Moller, D.; Morrow, R. A.; Rodriguez, E.; Shum, C.

    2009-12-01

    Surface fresh water is essential for life, yet we have surprisingly poor knowledge of its variability in space and time. Similarly, ocean circulation fundamentally drives global climate variability, yet the ocean current and eddy field that affects ocean circulation and heat transport at the sub-mesoscale resolution and particularly near coastal and estuary regions, is poorly known. About 50% of the vertical exchange of water properties (nutrients, dissovled CO2, heat, etc) in the upper ocean is taking place at the sub-mesoscale. Measurements from the Surface Water and Ocean Topography satellite mission (SWOT) will make strides in understanding these processes and improving global ocean models for studying climate change. SWOT is a swath-based interferometric-altimeter designed to acquire elevations of ocean and terrestrial water surfaces at unprecedented spatial and temporal resolutions. The mission will provide measurements of storage changes in lakes, reservoirs, and wetlands as well as estimates of discharge in rivers. These measurements are important for global water and energy budgets, constraining hydrodynamic models of floods, carbon evasion through wetlands, and water management, especially in developing nations. Perhaps most importantly, SWOT measurements will provide a fundamental understanding of the spatial and temporal variations in global surface waters, which for many countries are the primary source of water. An on-going effort, the “virtual mission” (VM) is designed to help constrain the required height and slope accuracies, the spatial sampling (both pixels and orbital coverage), and the trade-offs in various temporal revisits. Example results include the following: (1) Ensemble Kalman filtering of VM simulations recover water depth and discharge, reducing the discharge RMSE from 23.2% to 10.0% over an 84-day simulation period, relative to a simulation without assimilation. (2) Ensemble-based data assimilation of SWOT like measurements yields

  20. Abiotic versus biotic drivers of ocean pH variation under fast sea ice in McMurdo Sound, Antarctica.

    Science.gov (United States)

    Matson, Paul G; Washburn, Libe; Martz, Todd R; Hofmann, Gretchen E

    2014-01-01

    Ocean acidification is expected to have a major effect on the marine carbonate system over the next century, particularly in high latitude seas. Less appreciated is natural environmental variation within these systems, particularly in terms of pH, and how this natural variation may inform laboratory experiments. In this study, we deployed sensor-equipped moorings at 20 m depths at three locations in McMurdo Sound, comprising deep (bottom depth>200 m: Hut Point Peninsula) and shallow environments (bottom depth ∼25 m: Cape Evans and New Harbor). Our sensors recorded high-frequency variation in pH (Hut Point and Cape Evans only), tide (Cape Evans and New Harbor), and water mass properties (temperature and salinity) during spring and early summer 2011. These collective observations showed that (1) pH differed spatially both in terms of mean pH (Cape Evans: 8.009±0.015; Hut Point: 8.020±0.007) and range of pH (Cape Evans: 0.090; Hut Point: 0.036), and (2) pH was not related to the mixing of two water masses, suggesting that the observed pH variation is likely not driven by this abiotic process. Given the large daily fluctuation in pH at Cape Evans, we developed a simple mechanistic model to explore the potential for biotic processes--in this case algal photosynthesis--to increase pH by fixing carbon from the water column. For this model, we incorporated published photosynthetic parameters for the three dominant algal functional groups found at Cape Evans (benthic fleshy red macroalgae, crustose coralline algae, and sea ice algal communities) to estimate oxygen produced/carbon fixed from the water column underneath fast sea ice and the resulting pH change. These results suggest that biotic processes may be a primary driver of pH variation observed under fast sea ice at Cape Evans and potentially at other shallow sites in McMurdo Sound.

  1. Abiotic versus biotic drivers of ocean pH variation under fast sea ice in McMurdo Sound, Antarctica.

    Directory of Open Access Journals (Sweden)

    Paul G Matson

    Full Text Available Ocean acidification is expected to have a major effect on the marine carbonate system over the next century, particularly in high latitude seas. Less appreciated is natural environmental variation within these systems, particularly in terms of pH, and how this natural variation may inform laboratory experiments. In this study, we deployed sensor-equipped moorings at 20 m depths at three locations in McMurdo Sound, comprising deep (bottom depth>200 m: Hut Point Peninsula and shallow environments (bottom depth ∼25 m: Cape Evans and New Harbor. Our sensors recorded high-frequency variation in pH (Hut Point and Cape Evans only, tide (Cape Evans and New Harbor, and water mass properties (temperature and salinity during spring and early summer 2011. These collective observations showed that (1 pH differed spatially both in terms of mean pH (Cape Evans: 8.009±0.015; Hut Point: 8.020±0.007 and range of pH (Cape Evans: 0.090; Hut Point: 0.036, and (2 pH was not related to the mixing of two water masses, suggesting that the observed pH variation is likely not driven by this abiotic process. Given the large daily fluctuation in pH at Cape Evans, we developed a simple mechanistic model to explore the potential for biotic processes--in this case algal photosynthesis--to increase pH by fixing carbon from the water column. For this model, we incorporated published photosynthetic parameters for the three dominant algal functional groups found at Cape Evans (benthic fleshy red macroalgae, crustose coralline algae, and sea ice algal communities to estimate oxygen produced/carbon fixed from the water column underneath fast sea ice and the resulting pH change. These results suggest that biotic processes may be a primary driver of pH variation observed under fast sea ice at Cape Evans and potentially at other shallow sites in McMurdo Sound.

  2. Sea surface salinity variability in the tropical Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Subrahmanyam, B.; Murty, V.S.N.; Heffner, D.M.

    . Thompson et al. (2006) reported the Indian Ocean circulation and SSS variability during IODZM events, using different OGCM (Ocean General Circulation Model) simulations and assimilated data sets of SODA (Simple Ocean Data Assimilation) and ECCO...

  3. Instrument development and field application of the in situ pH Calibrator at the Ocean Observatory

    Science.gov (United States)

    Tan, C.; Ding, K.; Seyfried, W. E.

    2012-12-01

    A novel, self-calibrating instrument for in-situ measurement of pH in deep sea environments up to 4000 m has recently been developed. The device utilizes a compact fluid delivery system to perform measurement and two-point calibration of the solid state pH sensor array (Ir|IrOx| Ag|AgCl), which is sealed in a flow cell to enhance response time. The fluid delivery system is composed of a metering pump and valves, which periodically deliver seawater samples into the flow cell to perform measurements. Similarly, pH buffer solutions can be delivered into the flow cell to calibrate the electrodes under operational conditions. Sensor signals are acquired and processed by a high resolution (0.25 mV) datalogger circuit with a size of 114 mm×31 mm×25 mm. Eight input channels are available: two high impedance sensor input channels, two low impedance sensor input channel, two thermocouple input channels and two thermistor input channels. These eight channels provide adequate measurement flexibility to enhance applications in deep sea environments. The two high impedance channels of the datalogger are especially designed with the input impedance of 1016 Ω for YSZ (yittria-stabilized zirconia) ceramic electrodes characterized by the extremely low input bias current and high resistance. Field tests have been performed in 2008 by ROV at the depth up to 3200 m. Using the continuous power supply and TCP/IP network capability of the Monterey Accelerated Research System (MARS) ocean observatory, the so-called "pH Calibrator" has the capability of long term operation up to six months. In the observatory mode, the electronics are configured with DC-DC power converter modules and Ethernet to serial module to gain access to the science port of seafloor junction box. The pH Calibrator will be deployed at the ocean observatory in October and the in situ data will be on line on the internet. The pH Calibrator presents real time pH data at high pressures and variable temperatures, while

  4. Physical Retracking of Cryosat-2 Low Resolution Mode data for ocean surface height and gravity field estimation in open ocean

    Science.gov (United States)

    Jain, Maulik; Baltazar Andersen, Ole; Dall, Jorgen; Stenseng, Lars

    2014-05-01

    Cryosat-2 Low Resolution Mode (LRM) altimetric data is processed to determine precise ocean surface heights and gravity fields in open ocean. These ocean surface heights are corrected using various geophysical corrections available. The along track variation of the ocean surface height anomaly is used to determine the gravity field. The quality of this gravity field estimation is dependent on the precision in the ocean surface height anomaly. Thus a three/two parameter based physical model based on an error function is used, and the Cryosat-2 LRM waveforms are fit to this model. The fitting routines which employ the Levenberg Marquadt technique generate estimated values of retracked epochs which are used to compute the ocean surface heights. A two step processing system made up of sequential 3 parameter (amplitude, rise time, retracked epoch) and 2 parameter (amplitude, retracked epoch) fitting models are used to determine precise ocean surface heights. The quality of the processing system is judged by evaluating the standard deviation of the ocean surface height anomaly obtained after all corrections and the mean sea surface/geoid are removed. The lower the value of the standard deviation of the ocean surface height anomaly, the better the quality of processing is. Hence, different processing schemes are considered and evaluated in order to conclude towards the best retracking procedure which would eventually result in high accuracy gravity field estimations. Also, the quality on the precision is judged by analyzing the standard deviation in the gravity field anomaly. The gravity field anomaly is obtained by subtracting the retracked gravity field with the marine gravity field available. A lower value of the standard deviation in the gravity field anomaly indicates a more precise retracking algorithm. Using the two retracker performance evaluation strategies, namely the ocean surface height anomaly and the gravity field anomaly, it was concluded that the three

  5. Error estimates for CCMP ocean surface wind data sets

    Science.gov (United States)

    Atlas, R. M.; Hoffman, R. N.; Ardizzone, J.; Leidner, S.; Jusem, J.; Smith, D. K.; Gombos, D.

    2011-12-01

    The cross-calibrated, multi-platform (CCMP) ocean surface wind data sets are now available at the Physical Oceanography Distributed Active Archive Center from July 1987 through December 2010. These data support wide-ranging air-sea research and applications. The main Level 3.0 data set has global ocean coverage (within 78S-78N) with 25-kilometer resolution every 6 hours. An enhanced variational analysis method (VAM) quality controls and optimally combines multiple input data sources to create the Level 3.0 data set. Data included are all available RSS DISCOVER wind observations, in situ buoys and ships, and ECMWF analyses. The VAM is set up to use the ECMWF analyses to fill in areas of no data and to provide an initial estimate of wind direction. As described in an article in the Feb. 2011 BAMS, when compared to conventional analyses and reanalyses, the CCMP winds are significantly different in some synoptic cases, result in different storm statistics, and provide enhanced high-spatial resolution time averages of ocean surface wind. We plan enhancements to produce estimated uncertainties for the CCMP data. We will apply the method of Desroziers et al. for the diagnosis of error statistics in observation space to the VAM O-B, O-A, and B-A increments. To isolate particular error statistics we will stratify the results by which individual instruments were used to create the increments. Then we will use cross-validation studies to estimate other error statistics. For example, comparisons in regions of overlap for VAM analyses based on SSMI and QuikSCAT separately and together will enable estimating the VAM directional error when using SSMI alone. Level 3.0 error estimates will enable construction of error estimates for the time averaged data sets.

  6. Sea level: measuring the bounding surfaces of the ocean.

    Science.gov (United States)

    Tamisiea, Mark E; Hughes, Chris W; Williams, Simon D P; Bingley, Richard M

    2014-09-28

    The practical need to understand sea level along the coasts, such as for safe navigation given the spatially variable tides, has resulted in tide gauge observations having the distinction of being some of the longest instrumental ocean records. Archives of these records, along with geological constraints, have allowed us to identify the century-scale rise in global sea level. Additional data sources, particularly satellite altimetry missions, have helped us to better identify the rates and causes of sea-level rise and the mechanisms leading to spatial variability in the observed rates. Analysis of all of the data reveals the need for long-term and stable observation systems to assess accurately the regional changes as well as to improve our ability to estimate future changes in sea level. While information from many scientific disciplines is needed to understand sea-level change, this review focuses on contributions from geodesy and the role of the ocean's bounding surfaces: the sea surface and the Earth's crust. © 2014 The Author(s) Published by the Royal Society. All rights reserved.

  7. Sea level: measuring the bounding surfaces of the ocean

    Science.gov (United States)

    Tamisiea, Mark E.; Hughes, Chris W.; Williams, Simon D. P.; Bingley, Richard M.

    2014-01-01

    The practical need to understand sea level along the coasts, such as for safe navigation given the spatially variable tides, has resulted in tide gauge observations having the distinction of being some of the longest instrumental ocean records. Archives of these records, along with geological constraints, have allowed us to identify the century-scale rise in global sea level. Additional data sources, particularly satellite altimetry missions, have helped us to better identify the rates and causes of sea-level rise and the mechanisms leading to spatial variability in the observed rates. Analysis of all of the data reveals the need for long-term and stable observation systems to assess accurately the regional changes as well as to improve our ability to estimate future changes in sea level. While information from many scientific disciplines is needed to understand sea-level change, this review focuses on contributions from geodesy and the role of the ocean's bounding surfaces: the sea surface and the Earth's crust. PMID:25157196

  8. Climate change feedbacks on future oceanic acidification

    International Nuclear Information System (INIS)

    McNeil, Ben I.; Matear, Richard J.

    2007-01-01

    Oceanic anthropogenic CO 2 uptake will decrease both the pH and the aragonite saturation state (Oarag) of seawater leading to an oceanic acidification. However, the factors controlling future changes in pH and Oarag are independent and will respond differently to oceanic climate change feedbacks such as ocean warming, circulation and biological changes. We examine the sensitivity of these two CO 2 -related parameters to climate change feedbacks within a coupled atmosphere-ocean model. The ocean warming feedback was found to dominate the climate change responses in the surface ocean. Although surface pH is projected to decrease relatively uniformly by about 0.3 by the year 2100, we find pH to be insensitive to climate change feedbacks, whereas Oarag is buffered by ∼15%. Ocean carbonate chemistry creates a situation whereby the direct pH changes due to ocean warming are almost cancelled by the pH changes associated with dissolved inorganic carbon concentrations changes via a reduction in CO 2 solubility from ocean warming. We show that the small climate change feedback on future surface ocean pH is independent to the amount of ocean warming. Our analysis therefore implies that future projections of surface ocean acidification only need to consider future atmospheric CO 2 levels, not climate change induced modifications in the ocean

  9. Surface Ocean CO2 Atlas Database Version 5 (SOCATv5) (NCEI Accession 0163180)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Surface Ocean CO2 Atlas (SOCAT, www.socat.info) is a synthesis activity by the international marine carbon research community and has more than 100 contributors...

  10. Ocean Surface Topography Mission (OSTM) /Jason-3: Auxiliary Files, 2015- (NODC Accession 0122597)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Jason-3 is the fourth mission in U.S.-European series of satellite missions that measure the height of the ocean surface. Scheduled to launch in 2015, the mission...

  11. Ocean Surface Topography Mission (OSTM) /Jason-3: Orbital Information, 2015- (NODC Accession 0122598)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Jason-3 is the fourth mission in U.S.-European series of satellite missions that measure the height of the ocean surface. Scheduled to launch in 2015, the mission...

  12. Ocean Surface Topography Mission (OSTM) /Jason-3: Ancillary Files, 2015- (NCEI Accession 0122596)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Jason-3 is the fourth mission in U.S.-European series of satellite missions that measure the height of the ocean surface. Scheduled to launch in 2015, the mission...

  13. Ocean Surface Topography Mission (OSTM) /Jason-3: Telemetry, 2015- (NODC Accession 0122599)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Jason-3 is the fourth mission in U.S.-European series of satellite missions that measure the height of the ocean surface. Scheduled to launch in 2015, the mission...

  14. Baseline monitoring of the western Arctic Ocean estimates 20% of Canadian basin surface waters are undersaturated with respect to aragonite.

    Directory of Open Access Journals (Sweden)

    Lisa L Robbins

    Full Text Available Marine surface waters are being acidified due to uptake of anthropogenic carbon dioxide, resulting in surface ocean areas of undersaturation with respect to carbonate minerals, including aragonite. In the Arctic Ocean, acidification is expected to occur at an accelerated rate with respect to the global oceans, but a paucity of baseline data has limited our understanding of the extent of Arctic undersaturation and of regional variations in rates and causes. The lack of data has also hindered refinement of models aimed at projecting future trends of ocean acidification. Here, based on more than 34,000 data records collected in 2010 and 2011, we establish a baseline of inorganic carbon data (pH, total alkalinity, dissolved inorganic carbon, partial pressure of carbon dioxide, and aragonite saturation index for the western Arctic Ocean. This data set documents aragonite undersaturation in ≈ 20% of the surface waters of the combined Canada and Makarov basins, an area characterized by recent acceleration of sea ice loss. Conservative tracer studies using stable oxygen isotopic data from 307 sites show that while the entire surface of this area receives abundant freshwater from meteoric sources, freshwater from sea ice melt is most closely linked to the areas of carbonate mineral undersaturation. These data link the Arctic Ocean's largest area of aragonite undersaturation to sea ice melt and atmospheric CO2 absorption in areas of low buffering capacity. Some relatively supersaturated areas can be linked to localized biological activity. Collectively, these observations can be used to project trends of ocean acidification in higher latitude marine surface waters where inorganic carbon chemistry is largely influenced by sea ice meltwater.

  15. Molecular biogeochemical provinces in the Atlantic Surface Ocean

    Science.gov (United States)

    Koch, B. P.; Flerus, R.; Schmitt-Kopplin, P.; Lechtenfeld, O. J.; Bracher, A.; Cooper, W.; Frka, S.; Gašparović, B.; Gonsior, M.; Hertkorn, N.; Jaffe, R.; Jenkins, A.; Kuss, J.; Lara, R. J.; Lucio, M.; McCallister, S. L.; Neogi, S. B.; Pohl, C.; Roettgers, R.; Rohardt, G.; Schmitt, B. B.; Stuart, A.; Theis, A.; Ying, W.; Witt, M.; Xie, Z.; Yamashita, Y.; Zhang, L.; Zhu, Z. Y.; Kattner, G.

    2010-12-01

    One of the most important aspects to understand marine organic carbon fluxes is to resolve the molecular mechanisms which convert fresh, labile biomolecules into semi-labile and refractory dissolved and particulate organic compounds in the ocean. In this interdisciplinary project, which was performed on a cruise with RV Polarstern, we carried out a detailed molecular characterisation of dissolved organic matter (DOM) on a North-South transect in the Atlantic surface ocean in order to relate the data to different biological, climatic, oceanographic, and meteorological regimes as well as to terrestrial input from riverine and atmospheric sources. Our goal was to achieve a high resolution data set for the biogeochemical characterisation of the sources and reactivity of DOM. We applied ultrahigh resolution Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR-MS), nutrient, trace element, amino acid, and lipid analyses and other biogeochemical measurements for 220 samples from the upper water column (0-200m) and eight deep profiles. Various spectroscopic techniques were applied continuously in a constant sample water flow supplied by a fish system and the moon pool. Radiocarbon dating enabled assessing DOC residence time. Bacterial abundance and production provided a metabolic context for the DOM characterization work and pCO2 concentrations. Combining molecular organic techniques and inductively coupled plasma mass spectrometry (ICP-MS) established an important link between organic and inorganic biogeochemical studies. Multivariate statistics, primarily based on FT-ICR-MS data for 220 samples, allowed identifying geographical clusters which matched ecological provinces proposed previously by Longhurst (2007). Our study demonstrated that marine DOM carries molecular information reflecting the “history” of ocean water masses. This information can be used to define molecular biogeochemical provinces and to improve our understanding of element fluxes in

  16. Closing the Seasonal Ocean Surface Temperature Balance in the Eastern Tropical Oceans from Remote Sensing and Model Reanalyses

    Science.gov (United States)

    Roberts, J. Brent; Clayson, C. A.

    2012-01-01

    Residual forcing necessary to close the MLTB on seasonal time scales are largest in regions of strongest surface heat flux forcing. Identifying the dominant source of error - surface heat flux error, mixed layer depth estimation, ocean dynamical forcing - remains a challenge in the eastern tropical oceans where ocean processes are very active. Improved sub-surface observations are necessary to better constrain errors. 1. Mixed layer depth evolution is critical to the seasonal evolution of mixed layer temperatures. It determines the inertia of the mixed layer, and scales the sensitivity of the MLTB to errors in surface heat flux and ocean dynamical forcing. This role produces timing impacts for errors in SST prediction. 2. Errors in the MLTB are larger than the historical 10Wm-2 target accuracy. In some regions, a larger accuracy can be tolerated if the goal is to resolve the seasonal SST cycle.

  17. Application of SMAP Data for Ocean Surface Remote Sensing

    Science.gov (United States)

    Fore, A.; Yueh, S. H.; Tang, W.; Stiles, B. W.; Hayashi, A.

    2017-12-01

    The Soil Moisture Active Passive (SMAP) mission was launched January 31st, 2015. It is designed to measure the soil moisture over land using a combined active / passive L-band system. Due to the Aquarius mission, L-band model functions for ocean winds and salinity are mature and are directly applicable to the SMAP mission. In contrast to Aquarius, the higher resolution and scanning geometry of SMAP allow for wide-swath ocean winds and salinities to be retrieved. In this talk we present the SMAP Sea Surface Salinity (SSS) and extreme winds dataset and its performance. First we discuss the heritage of SMAP SSS algorithms, showing that SMAP and Aquarius show excellent agreement in the ocean surface roughness correction. Then, we give an overview of some newly developed algorithms that are only relevant to the SMAP system; a new galaxy correction and land correction enabling SSS retrievals up to 40 km from coast. We discuss recent improvements to the SMAP data processing for version 4.0. Next we compare the performance of the SMAP SSS to in-situ salinity measurements obtained from ARGO floats, tropical moored buoys, and ship-based data. SMAP SSS has accuracy of 0.2 PSU on a monthly basis compared to ARGO gridded data in tropics and mid-latitudes. In tropical oceans, time series comparison of salinity measured at 1 m depth by moored buoys indicates SMAP can track large salinity changes within a month. Synergetic analysis of SMAP, SMOS, and Argo data allows us to identify and exclude erroneous buoy data from assessment of SMAP SSS. The resulting SMAP-buoy matchup analysis gives a mean standard deviation (STD) of 0.22 PSU and correlation of 0.73 on weekly scale; at monthly scale the mean STD decreased to 0.17 PSU and the correlation increased to 0.8. In addition to SSS, SMAP provides a view into tropical cyclones having much higher sensitivity than traditional scatterometers. We validate the high-winds using collocations with SFMR during tropical cyclones as well as

  18. The surface pH of glass ionomer cavity lining agents.

    Science.gov (United States)

    Woolford, M J

    1989-12-01

    It is considered that acid release from the surface of glass ionomer (polyalkenoate) cements may be associated with early pulpal sensitivity following the use of these materials. This study was carried out to examine the surface pH of different types of glass ionomer lining cements using a flat-ended pH electrode. It was found that the surface pH remains low for this group of materials during the first hour of setting. Different types of glass ionomer lining cement were also shown to behave differently when considering acid release from the surface. Conclusions regarding the behaviour of glass ionomers should only be made with reference to the specific material tested.

  19. Impacts of Ocean Waves on the Atmospheric Surface Layer: Simulations and Observations

    National Research Council Canada - National Science Library

    Sullivan, Peter P; McWilliams, James C; Melville, W. K

    2008-01-01

    ... planetary boundary layers (PBL). Efforts were focused on the effects of surface gravity waves on the near-surface dynamics, surface fluxes, and coupling between the atmospheric and oceanic PBLs...

  20. On the interaction between ocean surface waves and seamounts

    Science.gov (United States)

    Sosa, Jeison; Cavaleri, Luigi; Portilla-Yandún, Jesús

    2017-12-01

    Of the many topographic features, more specifically seamounts, that are ubiquitous in the ocean floor, we focus our attention on those with relatively shallow summits that can interact with wind-generated surface waves. Among these, especially relatively long waves crossing the oceans (swells) and stormy seas are able to affect the water column up to a considerable depth and therefore interact with these deep-sea features. We quantify this interaction through numerical experiments using a numerical wave model (SWAN), in which a simply shaped seamount is exposed to waves of different length. The results show a strong interaction that leads to significant changes in the wave field, creating wake zones and regions of large wave amplification. This is then exemplified in a practical case where we analyze the interaction of more realistic sea conditions with a very shallow rock in the Yellow Sea. Potentially important for navigation and erosion processes, mutatis mutandis, these results are also indicative of possible interactions with emerged islands and sand banks in shelf seas.

  1. National Coral Reef Monitoring Program: Dissolved inorganic carbon, total alkalinity, pH and other variables collected from surface discrete observations using infrared dissolved inorganic carbon analyzer, alkalinity titrator and other instruments from the North Atlantic Ocean near Key West, Florida (Class III climate monitoring sites) from 2012-03-23 to 2014-12-11 (NCEI Accession 0132022)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This archival package contains data collected to monitor changes to coral reef carbonate chemistry over time, at US affiliated coral reef sites, through quantifying...

  2. Volcanic ash as fertiliser for the surface ocean

    Directory of Open Access Journals (Sweden)

    B. Langmann

    2010-04-01

    Full Text Available Iron is a key limiting micro-nutrient for marine primary productivity. It can be supplied to the ocean by atmospheric dust deposition. Volcanic ash deposition into the ocean represents another external and so far largely neglected source of iron. This study demonstrates strong evidence for natural fertilisation in the iron-limited oceanic area of the NE Pacific, induced by volcanic ash from the eruption of Kasatochi volcano in August 2008. Atmospheric and oceanic conditions were favourable to generate a massive phytoplankton bloom in the NE Pacific Ocean which for the first time strongly suggests a connection between oceanic iron-fertilisation and volcanic ash supply.

  3. Metrological challenges for measurements of key climatological observables: oceanic salinity and pH, and atmospheric humidity. Part 1: overview

    Science.gov (United States)

    Feistel, R.; Wielgosz, R.; Bell, S. A.; Camões, M. F.; Cooper, J. R.; Dexter, P.; Dickson, A. G.; Fisicaro, P.; Harvey, A. H.; Heinonen, M.; Hellmuth, O.; Kretzschmar, H.-J.; Lovell-Smith, J. W.; McDougall, T. J.; Pawlowicz, R.; Ridout, P.; Seitz, S.; Spitzer, P.; Stoica, D.; Wolf, H.

    2016-02-01

    Water in its three ambient phases plays the central thermodynamic role in the terrestrial climate system. Clouds control Earth’s radiation balance, atmospheric water vapour is the strongest ‘greenhouse’ gas, and non-equilibrium relative humidity at the air-sea interface drives evaporation and latent heat export from the ocean. On climatic time scales, melting ice caps and regional deviations of the hydrological cycle result in changes of seawater salinity, which in turn may modify the global circulation of the oceans and their ability to store heat and to buffer anthropogenically produced carbon dioxide. In this paper, together with three companion articles, we examine the climatologically relevant quantities ocean salinity, seawater pH and atmospheric relative humidity, noting fundamental deficiencies in the definitions of those key observables, and their lack of secure foundation on the International System of Units, the SI. The metrological histories of those three quantities are reviewed, problems with their current definitions and measurement practices are analysed, and options for future improvements are discussed in conjunction with the recent seawater standard TEOS-10. It is concluded that the International Bureau of Weights and Measures, BIPM, in cooperation with the International Association for the Properties of Water and Steam, IAPWS, along with other international organizations and institutions, can make significant contributions by developing and recommending state-of-the-art solutions for these long standing metrological problems in climatology.

  4. Application of Satellite-Derived Ocean Surface Winds to the Detection of Weather Systems and the Prediction of Near-Ocean Surface Winds around Hawaii

    Directory of Open Access Journals (Sweden)

    Hsi-Chyi Yeh

    2010-01-01

    Full Text Available The Hawaiian Island chain is surrounded by the open ocean and is an ideal place to conduct the application of QuikSCAT satellite-derived ocean surface winds to the detection of weather systems. With the help of QuikSCAT winds, the associated circulation of the weather systems over the open ocean around Hawaii can be identified. In this study, the obvious cyclonic circulation associated with a Kona storm, the significant wind shift and wind confluence related to the surface cold front, and the anticyclonic circulation related to high-pressure systems for both a strong-wind event and a trade-wind condition are revealed over the open ocean through QuikSCAT winds. The propagation of a cold frontal boundary, defined by the wind shift and wind confluence, also can be clearly detected using the reanalyzed ocean-surface winds.

  5. Baseline Monitoring of the Western Arctic Ocean Estimates 20% of Canadian Basin Surface Waters Are Undersaturated with Respect to Aragonite

    Science.gov (United States)

    Robbins, Lisa L.; Wynn, Jonathan G.; Lisle, John T.; Yates, Kimberly K.; Knorr, Paul O.; Byrne, Robert H.; Liu, Xuewu; Patsavas, Mark C.; Azetsu-Scott, Kumiko; Takahashi, Taro

    2013-01-01

    Marine surface waters are being acidified due to uptake of anthropogenic carbon dioxide, resulting in surface ocean areas of undersaturation with respect to carbonate minerals, including aragonite. In the Arctic Ocean, acidification is expected to occur at an accelerated rate with respect to the global oceans, but a paucity of baseline data has limited our understanding of the extent of Arctic undersaturation and of regional variations in rates and causes. The lack of data has also hindered refinement of models aimed at projecting future trends of ocean acidification. Here, based on more than 34,000 data records collected in 2010 and 2011, we establish a baseline of inorganic carbon data (pH, total alkalinity, dissolved inorganic carbon, partial pressure of carbon dioxide, and aragonite saturation index) for the western Arctic Ocean. This data set documents aragonite undersaturation in ∼20% of the surface waters of the combined Canada and Makarov basins, an area characterized by recent acceleration of sea ice loss. Conservative tracer studies using stable oxygen isotopic data from 307 sites show that while the entire surface of this area receives abundant freshwater from meteoric sources, freshwater from sea ice melt is most closely linked to the areas of carbonate mineral undersaturation. These data link the Arctic Ocean’s largest area of aragonite undersaturation to sea ice melt and atmospheric CO2 absorption in areas of low buffering capacity. Some relatively supersaturated areas can be linked to localized biological activity. Collectively, these observations can be used to project trends of ocean acidification in higher latitude marine surface waters where inorganic carbon chemistry is largely influenced by sea ice meltwater. PMID:24040074

  6. The causes of alkalinity variations in the global surface ocean

    OpenAIRE

    Fry, Claudia Helen

    2016-01-01

    Human activities have caused the atmospheric concentration of carbon dioxide (CO2) to increase by 120 ppmv from pre-industrial times to 2014. The ocean takes up approximately a quarter of the anthropogenic CO2, causing ocean acidification (OA). Therefore it is necessary to study the ocean carbonate system, including alkalinity, to quantify the flux of CO2 into the ocean and understand OA. Since the 1970s, carbonate system measurements have been undertaken which can be analyzed to quantify the...

  7. Surface pH of resin-modified glass polyalkenoate (ionomer) cements.

    Science.gov (United States)

    Woolford, M J; Chadwick, R G

    1992-12-01

    The recently developed group of materials known as light-activated, or resin-modified, glass polyalkenoate (ionomer) cements have been produced in response to clinical demands for a command set cavity base material. This study monitored the surface pH of three commercially available resin-modified glass ionomer cements over a 60-min period following either mixing alone or mixing followed by a 30-s exposure to a curing lamp. The results indicate that each material behaves in a unique manner. For all materials and conditions the pH reached after a 60-min period was significantly (P pH of two of the materials (Baseline VLC and Vitrebond) as compared to the same materials in the uncured state. In the case of XR-Ionomer, however, no significant (P > 0.05) effect of light curing upon the surface pH was apparent. The precise clinical consequences of a low surface pH are unclear but may be an aetiological factor in postoperative pulpal sensitivity. It is therefore recommended that a sublining of a proprietary calcium hydroxide lining material should be placed routinely beneath these materials and every effort made to ensure effective light curing.

  8. Dissolved inorganic carbon, total alkalinity, pH, nutrients, and other variables collected from surface discrete observations using Niskin bottle and other instruments from R/V F. G. Walton Smith in the west coast of Florida within Gulf of Mexico from 2015-09-23 to 2015-09-24 (NCEI Accession 0157025)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This archival package contains the surface discrete measurements of dissolved inorganic carbon, total alkalinity, pH and nutrients in the west coast of Florida near...

  9. Dissolved inorganic carbon, total alkalinity, pH, and other variables collected from surface and discrete observations using Niskin bottle, flow-through pump and other instruments from F.G. Walton Smith in the Gulf of Mexico (east coast of Florida near the Keys) from 2014-12-03 to 2014-12-04 (NCEI Accession 0154383)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This archival package contains surface discrete measurement of dissolved inorganic carbon, total alkalinity, pH, dissolved oxygen and nutrients from a transect off...

  10. Dissolved inorganic carbon, total alkalinity, pH, and other variables collected from surface discrete observations using spectrophotometer and other instruments from NOAA Ship Henry B. Bigelow off the Northeastern coast of the United States from 2014-09-10 to 2014-11-05 (NCEI Accession 0138983)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This archival package contains surface measurements of dissolved inorganic, total alkalinity, pH measurements off the Northeastern coast of the United States....

  11. Dissolved inorganic carbon, total alkalinity, pH, nutrients, and other variables collected from surface discrete observations using flow-through pump and other instruments from NOAA Ship Henry B. Bigelow on the Northeast U.S. Shelf (Gulf of Maine and Mid-Atlantic Bight) from 2013-03-17 to 2013-05-09 (NCEI Accession 0154386)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This archival package contains surface discrete measurements of dissolved inorganic carbon, total alkalinity, pH and nutrients in the Mid-Atlantic Bight and Gulf of...

  12. Spiraling pathways of global deep waters to the surface of the Southern Ocean

    OpenAIRE

    Tamsitt, Veronica; Drake, Henri F.; Morrison, Adele K.; Talley, Lynne D.; Dufour, Carolina O.; Gray, Alison R.; Griffies, Stephen M.; Mazloff, Matthew R.; Sarmiento, Jorge L.; Wang, Jinbo; Weijer, Wilbert

    2017-01-01

    Upwelling of global deep waters to the sea surface in the Southern Ocean closes the global overturning circulation and is fundamentally important for oceanic uptake of carbon and heat, nutrient resupply for sustaining oceanic biological production, and the melt rate of ice shelves. However, the exact pathways and role of topography in Southern Ocean upwelling remain largely unknown. Here we show detailed upwelling pathways in three dimensions, using hydrographic observations and particle trac...

  13. Impact of Surface Waves on SWOT’s Projected Ocean Accuracy

    OpenAIRE

    Peral, Eva; Rodríguez, Ernesto; Esteban-Fernández, Daniel

    2015-01-01

    The Surface Water and Ocean Topography (SWOT) mission being considered by NASA has, as one of its main objectives, to measure ocean topography with centimeter scale accuracy over kilometer scale spatial resolution. This paper investigates the impact of ocean waves on SWOT’s projected performance. Several effects will be examined: volumetric decorrelation, aliasing of ocean waves, backscattering modulation, and the so-called surfboard sampling.

  14. Adhesion of Pathogenic Bacteria to Food Contact Surfaces: Influence of pH of Culture

    Directory of Open Access Journals (Sweden)

    Akier Assanta Mafu

    2011-01-01

    Full Text Available The adhesion of Aeromonas hydrophila, Escherichia coli O157:H7, Salmonella Enteritidis, and Staphylococcus aureus to hydrophobic and hydrophilic surfaces in cultures with different pHs (6, 7, and 8 was studied. The results indicated that the type of material had no effect on the attachment capacity of microorganisms, while environmental pH influenced the adhesion of A. hydrophila, E. coli, and S. aureus to both solid substrates. The attachment of S. Enteritidis (P>.05 was not affected by the type of substrate or the culture pH, whereas E. coli displayed the weakest affinity for both polystyrene and glass surfaces. No correlation was established between the physicochemical properties of the materials, or the bacterial and the rate of bacterial adhesion, except for S. aureus. Photomicrographs have shown that surfaces were contaminated by small clusters of S. Enteritidis while S. aureus invaded the food contact surfaces in the form of small chains or cell aggregates.

  15. [Measurements of surface ocean carbon dioxide partial pressure during WOCE

    Energy Technology Data Exchange (ETDEWEB)

    1992-01-01

    This paper discusses the research progress of the second year of research under Measurement of Surface Ocean Carbon Dioxide Partial Pressure During WOCE'' and proposes to continue measurements of underway pCO[sub 2]. During most of the first year of this grant, our efforts to measure pCO[sub 2] on WOCE WHP legs were frustrated by ship problems. The R/V Knorr, which was originally scheduled to carry out the first work on WHP lines P19 and P16 in the southeastem Pacific during the 1990-91 austral summer, was delayed in the shipyard during her mid-life refit for more than a year. In the interim, the smaller R/V Thomas Washington, was pressed into service to carry out lower-latitude portions of WHP lines P16 and P17 during mid-1991 (TUNES Expedition). We installed and operated our underway chromatographic system on this expedition, even though space and manpower on this smaller vessel were limited and no one from our group would be aboard any of the 3 WHP expedition legs. The results for carbon dioxide and nitrous oxide are shown. A map of the cruise track is shown for each leg, marked with cumulative distance. Following each track is a figure showing the carbon dioxide and nitrous oxide results as a function of distance along this track. The results are plotted as dry-gas mole fractions (in ppm and ppb, respectively) in air and in gas equilibrated with surface seawater at a total pressure equal to the barometric pressure. The air data are plotted as a 10-point running mean, and appear as a roughly horizontal line. The seawater data are plotted as individual points, using a 5-point Gaussian smoother. Equal values Of xCO[sub 2] in air and surface seawater indicate air-sea equilibrium.

  16. The Ocean Surface Topography Sentinel-6/Jason-CS Mission

    Science.gov (United States)

    Giulicchi, L.; Cullen, R.; Donlon, C.; Vuilleumier@esa int, P.

    2016-12-01

    The Sentinel-6/Jason-CS mission consists of two identical satellites flying in sequence and designed to provide operational measurements of sea surface height significant wave high and wind speed to support operational oceanography and climate monitoring. The mission will be the latest in a series of ocean surface topography missions that will span nearly three decades. They follow the altimeters on- board TOPEX/Poseidon through to Jason-3 (launched in January 2016). Jason-CS will continue to fulfil objectives of the reference series whilst introducing a major enhancement in capability providing the operational and science oceanographic community with the state of the art in terms of spacecraft, measurement instrumentation design thus securing optimal operational and science data return. As a secondary objective the mission will also include Radio Occultation user services. Each satellite will be launched sequentially into the Jason orbit (up to 66 latitude) respectively in 2020 and 2025. The principle payload instrument is a high precision Ku/C band radar altimeter with retrieval of geophysical parameters (surface elevation, wind speed and SWH) from the altimeter data require supporting measurements: a DORIS receiver for Precise Orbit Determination; The Climate Quality Advanced Microwave Radiometer (AMR-C) for high stability path delay correction. Orbit tracking data are also provided by GPS & LRA. An additional GPS receiver will be dedicated to radio-occultation measurements. The programme is a part of the European Community Copernicus initiative, whose objective is to support Europe's goals regarding sustainable development and global governance of the environment by providing timely and quality data, information, services and knowledge. The Sentinel-6/Jason-CS in particular is a cooperative mission with contributions from NASA, NOAA, EUMETSAT, ESA, CNES and the European Union.

  17. Formation and maintenance of high-nitrate, low pH layers in the eastern Indian Ocean and the role of nitrogen fixation

    Directory of Open Access Journals (Sweden)

    A. M. Waite

    2013-08-01

    Full Text Available We investigated the biogeochemistry of low dissolved oxygen high-nitrate (LDOHN layers forming against the backdrop of several interleaving regional water masses in the eastern Indian Ocean, off northwest Australia adjacent to Ningaloo Reef. These water masses, including the forming Leeuwin Current, have been shown directly to impact the ecological function of Ningaloo Reef and other iconic coastal habitats downstream. Our results indicate that LDOHN layers are formed from multiple subduction events of the Eastern Gyral Current beneath the Leeuwin Current (LC; the LC originates from both the Indonesian Throughflow and tropical Indian Ocean. Density differences of up to 0.025 kg m−3 between the Eastern Gyral Current and the Leeuwin Current produce sharp gradients that can trap high concentrations of particles (measured as low transmission along the density interfaces. The oxidation of the trapped particulate matter results in local depletion of dissolved oxygen and regeneration of dissolved nitrate (nitrification. We document an associated increase in total dissolved carbon dioxide, which lowers the seawater pH by 0.04 units. Based on isotopic measurements (δ15N and δ18O of dissolved nitrate, we determine that ~ 40–100% of the nitrate found in LDOHN layers is likely to originate from nitrogen fixation, and that, regionally, the importance of N-fixation in contributing to LDOHN layers is likely to be highest at the surface and offshore.

  18. Three Dimensional Dynamics of Freshwater Lenses in the Oceans Near Surface Layer

    Science.gov (United States)

    2016-09-14

    the potential impact of these fluxes on the barrier layer and Aquarius and Soil Moisture and Ocean Salinity (SMOS) satellite image formations. By...contributing to the salinity field detected in the Aquarius and Soil Moisture and Ocean Salinity (SMOS) sat- ellite footprints. The barrier layer (Lukas...operational algorithms for sea surface salinity satellites. Oceanic advection and mixing funda- mentally affect the sea surface salinity sig - nal

  19. Near field impacts of reduced pH from ocean CO{sub 2} disposal

    Energy Technology Data Exchange (ETDEWEB)

    Caulfield, J.A.; Auerbach, D.I.; Adams, E.E.; Herzog, H.J. [Massachusetts Inst. of Tech., Cambridge, MA (United States)

    1997-12-31

    A methodology has been developed to quantify mortality suffered by marine zooplankton passing through a CO{sub 2}-enriched sea water plume. Predicted impact depends on the mode of injection with scenarios which disperse the CO{sub 2} showing least impact. Benthic impacts also depend on injection mode, with localized effects expected for any scenario in which the plume contacts the bottom. Effects of scale were found whereby the predicted impact from 10 power plants is greater than 10 times the impact of one plant at the same site. Based on available data, our modeling suggests that mortality associated with exposure to low pH can be avoided by properly dispersing the CO{sub 2} and keeping the plume off of the seabed. (Author)

  20. 3-D Surface Visualization of pH Titration "Topos": Equivalence Point Cliffs, Dilution Ramps, and Buffer Plateaus

    Science.gov (United States)

    Smith, Garon C.; Hossain, Md Mainul; MacCarthy, Patrick

    2014-01-01

    3-D topographic surfaces ("topos") can be generated to visualize how pH behaves during titration and dilution procedures. The surfaces are constructed by plotting computed pH values above a composition grid with volume of base added in one direction and overall system dilution on the other. What emerge are surface features that…

  1. Surface Ocean CO2 Atlas (SOCAT) gridded data products

    Digital Repository Service at National Institute of Oceanography (India)

    Sabine, C.L.; Hankin, S.; Koyuk, H.; Bakker, D.C.E.; Pfeil, B.; Olsen, A; Metzl, N.; Kozyr, A; Fassbender, A; Manke, A; Malczyk, J.; Akl, J.; Alin, S.R.; Bellerby, R.G.J.; Borges, A; Boutin, J.; Brown, P.J.; Cai, W.-J.; Chavez, F.P.; Chen, A.; Cosca, C.; Feely, R.A.; Gonzalez-Davila, M.; Goyet, C.; Hardman-Mountford, N.; Heinze, C.; Hoppema, M.; Hunt, C.W.; Hydes, D.; Ishii, M.; Johannessen, T.; Key, R.M.; Kortzinger, A.; Landschutzer, P.; Lauvset, S.K.; Lefevre, N.; Lenton, A.; Lourantou, A.; Merlivat, L.; Midorikawa, T.; Mintrop, L.; Miyazaki, C.; Murata, A.; Nakadate, A.; Nakano, Y.; Nakaoka, S.; Nojiri, Y.; Omar, A.M.; Padin, X.A.; Park, G.-H.; Paterson, K.; Perez, F.F.; Pierrot, D.; Poisson, A.; Rios, A.F.; Salisbury, J.; Santana-Casiano, J.M.; Sarma, V.V.S.S.; et al.

    As a response to public demand for a well-documented, quality controlled, publically available, global surface ocean carbon dioxide (CO2) data set, the international marine carbon science community developed the Surface Ocean CO2...

  2. Response and Recovery of Surface Ocean Carbonate Chemistry in the Mid-latitude North Atlantic During the PETM

    Science.gov (United States)

    Gutjahr, M.; Sexton, P. F.; Ridgwell, A. J.; Anagnostou, E.; Pearson, P. N.; Palike, H.; Norris, R. D.; Thomas, E.; Foster, G. L.

    2014-12-01

    With more than 3,000 Gt of carbon released over ≤10 ka [1-3], the Paleocene-Eocene Thermal Maximum (PETM) arguably represents our closest geologic analogue for the long-term effects of present-day and future fossil fuel carbon combustion. The PETM carbon isotopic excursion (CIE) was initiated at ~55.9 Ma [4] and lasted for ~170 ka [5]. This event was associated with pronounced ocean acidification, recently reported to amount to a drop in oceanic mixed-layer pH on the order of 0.3 pH units at the central North Pacific Shatsky Rise [6]. Here, a new boron isotope record (expressed in δ11B) will be presented from mixed-layer dwelling foraminiferal species Morozovella subbotinae across the PETM from DSDP Site 401 in the North Atlantic. We convert the δ11B data into mixed layer pH, complemented by elemental records and new carbon and oxygen isotope data generated from the same samples. Our records cover the time interval from about 300 ka prior to the CIE to more than 400 ka after the CIE. The bulk carbonate content decreased from 80 to 30 wt% at the onset of the CIE, but calcareous microfossils in the interval show no signs of carbonate dissolution [7, and this study]. We find significantly lowered pH for almost 100 ka following the CIE onset and furthermore, no complete post-PETM recovery of surface ocean pH to pre-PETM values, likely tracing the longer-term climatic trajectories leading to the subsequent Eocene Thermal Maximum 2 (ETM 2) [8]. Based on this surface ocean pH record, atmospheric CO2 concentrations over the PETM are estimated using the GENIE Earth System Model [9, 10]. References[1] McInerney, F.A. & Wing, S.L. (2011). Ann. Rev. Earth Planet. Sci. 39, 489-516. [2] Zeebe, R. et al., (2009). Nat. Geosc. 2, 576-580. [3] Cui, Y. et al. (2011). Nat. Geosc. 4, 481-485. [4] Charles, A.J. et al. (2011). G Cubed 12, 19 pp. [5] Röhl, U. et al. (2007). G Cubed 8, 13 pp. [6] Penman, D.E. et al. (2014) Paleoceanography 29, 357-369. [7] Bornemann, A. et al. (2014

  3. Surface Ocean Circulation and Dynamics in the Philippine Archipelago Region

    Science.gov (United States)

    Han, W.; Moore, A. M.; Levin, J.; Zhang, B.; Arango, H. G.; Curchitser, E.; di Lorenzo, E.; Gordon, A. L.; Lin, J.

    2008-12-01

    The dynamics of the seasonal surface circulation in the Philippine Archipelago (117E-128E, 0N-14N) are investigated using a high-resolution Regional Ocean Modeling System (ROMS) for the period of 2004 - March 2008. Three experiments are performed to estimate the relative importance of local, remote and tidal forcing. On annual mean, circulation in the Sulu Sea is dominated by the inflow from the South China Sea at the Mindoro and Balabac Straits, outflow into the Sulawesi Sea at the Sibutu Passage, and cyclonic circulation in the Sulu basin. A strong jet forms in the northeast Sulu Sea when currents from the Mindoro and Tablas Straits converge. Within the Archipelago, strong westward currents in the Bohol Sea carry the western Pacific (WP) Water from the Surigao Strait into the Sulu Sea via the Dipolog Strait. In the Sibuyan Sea, currents flow westward, which carry part of the WP water from the San Bernardino Strait into the Sulu Sea via the Tablas Strait. The surface circulations exhibit strong seasonal variations or reversals from winter to summer. The variations of volume transports above 40m at the Mindoro Strait, Balabac Strait and Sibutu Passage of the Sulu Sea and at the Verde Island Passage are dominated by remote forcing, although local forcing can be large sometimes. At the Tablas and Dipolog Straits, variations of transports result from both remote and local forcing. The cyclonic (anticyclonic) gyres during winter (summer) in the Sulu Sea and seasonally reversing currents in the Archipelago result mainly from local forcing. Nonlinear rectification of tides acts to reduce the mean transports at the Surigao, San Bernardino and Dipolog Straits, and it also affects the Sulu Sea circulation perhaps by tidal mixing and shifting the locations of jets and eddies.

  4. Improving NOAA's NWLON Through Enhanced Data Inputs from NASA's Ocean Surface Topography

    Science.gov (United States)

    Guest, DeNeice C.

    2010-01-01

    This report assesses the benefit of incorporating NASA's OSTM (Ocean Surface Topography Mission) altimeter data (C- and Ku-band) into NOAA's (National Oceanic and Atmospheric Administration) NWLON (National Water Level Observation Network) DSS (Decision Support System). This data will enhance the NWLON DSS by providing additional inforrnation because not all stations collect all meteorological parameters (sea-surface height, ocean tides, wave height, and wind speed over waves). OSTM will also provide data where NWLON stations are not present. OSTM will provide data on seasurface heights for determining sea-level rise and ocean circulation. Researchers and operational users currently use satellite altimeter data products with the GSFCOO NASA data model to obtain sea-surface height and ocean circulation inforrnation. Accurate and tirnely inforrnation concerning sea-level height, tide, and ocean currents is needed to irnprove coastal tidal predictions, tsunarni and storm surge warnings, and wetland restoration.

  5. Partial pressure (or fugacity) of carbon dioxide, salinity and SEA SURFACE TEMPERATURE collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from ODEN in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2006-12-14 to 2006-12-26 (NODC Accession 0108159)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108159 includes Surface underway data collected from ODEN in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60 degrees...

  6. Auto-correlation analysis of ocean surface wind vectors

    Indian Academy of Sciences (India)

    M. Senthilkumar (Newgen Imaging) 1461 1996 Oct 15 13:05:22

    satellite and in situ measurements. A case study using the TRMM Microwave Imager (TMI) and. Indian Ocean buoy wind speed data resulted in an improvement of about 10%. 1. Introduction. The need for studying temporal variability of oceanic winds has been pointed out by many authors (for example, Ezraty R S 1989).

  7. Investigating the Potential Impact of the Surface Water and Ocean Topography (SWOT) Altimeter on Ocean Mesoscale Prediction

    Science.gov (United States)

    Carrier, M.; Ngodock, H.; Smith, S. R.; Souopgui, I.

    2016-02-01

    NASA's Surface Water and Ocean Topography (SWOT) satellite, scheduled for launch in 2020, will provide sea surface height anomaly (SSHA) observations with a wider swath width and higher spatial resolution than current satellite altimeters. It is expected that this will help to further constrain ocean models in terms of the mesoscale circulation. In this work, this expectation is investigated by way of twin data assimilation experiments using the Navy Coastal Ocean Model Four Dimensional Variational (NCOM-4DVAR) data assimilation system using a weak constraint formulation. Here, a nature run is created from which SWOT observations are sampled, as well as along-track SSHA observations from simulated Jason-2 tracks. The simulated SWOT data has appropriate spatial coverage, resolution, and noise characteristics based on an observation-simulator program provided by the SWOT science team. The experiment is run for a three-month period during which the analysis is updated every 24 hours and each analysis is used to initialize a 96 hour forecast. The forecasts in each experiment are compared to the available nature run to determine the impact of the assimilated data. It is demonstrated here that the SWOT observations help to constrain the model mesoscale in a more consistent manner than traditional altimeter observations. The findings of this study suggest that data from SWOT may have a substantial impact on improving the ocean model analysis and forecast of mesoscale features and surface ocean transport.

  8. A computational analysis of sonic booms penetrating a realistic ocean surface.

    Science.gov (United States)

    Rochat, J L; Sparrow, V W

    2001-03-01

    The last decade has seen a revival of sonic boom research, a direct result of the projected market for a new breed of supersonic passenger aircraft, its design, and its operation. One area of the research involves sonic boom penetration into the ocean, one concern being the possible disturbance of marine mammals from the noise generated by proposed high-speed civil transport (HSCT) flyovers. Although theory is available to predict underwater sound levels due to a sonic boom hitting a homogeneous ocean with a flat surface, theory for a realistic ocean, one with a wavy surface and bubbles near the surface, is missing and will be presented in this paper. First, reviews are given of a computational method to calculate the underwater pressure field and the effects of a simple wavy ocean surface on the impinging sonic boom. Second, effects are described for the implementation of three additional conditions: a sonic boom/ocean "wavelength" comparison, complex ocean surfaces, and bubbles near the ocean surface. Overall, results from the model suggest that the realistic ocean features affect the penetrating proposed HSCT sonic booms by modifying the underwater sound-pressure levels only about 1 decibel or less.

  9. Transgenerational exposure of North Atlantic bivalves to ocean acidification renders offspring more vulnerable to low pH and additional stressors.

    Science.gov (United States)

    Griffith, Andrew W; Gobler, Christopher J

    2017-09-12

    While early life-stage marine bivalves are vulnerable to ocean acidification, effects over successive generations are poorly characterized. The objective of this work was to assess the transgenerational effects of ocean acidification on two species of North Atlantic bivalve shellfish, Mercenaria mercenaria and Argopecten irradians. Adults of both species were subjected to high and low pCO 2 conditions during gametogenesis. Resultant larvae were exposed to low and ambient pH conditions in addition to multiple, additional stressors including thermal stress, food-limitation, and exposure to a harmful alga. There were no indications of transgenerational acclimation to ocean acidification during experiments. Offspring of elevated pCO 2 -treatment adults were significantly more vulnerable to acidification as well as the additional stressors. Our results suggest that clams and scallops are unlikely to acclimate to ocean acidification over short time scales and that as coastal oceans continue to acidify, negative effects on these populations may become compounded and more severe.

  10. Evaluation of Oceanic Surface Observation for Reproducing the Upper Ocean Structure in ECHAM5/MPI-OM

    Science.gov (United States)

    Luo, Hao; Zheng, Fei; Zhu, Jiang

    2017-12-01

    Better constraints of initial conditions from data assimilation are necessary for climate simulations and predictions, and they are particularly important for the ocean due to its long climate memory; as such, ocean data assimilation (ODA) is regarded as an effective tool for seasonal to decadal predictions. In this work, an ODA system is established for a coupled climate model (ECHAM5/MPI-OM), which can assimilate all available oceanic observations using an ensemble optimal interpolation approach. To validate and isolate the performance of different surface observations in reproducing air-sea climate variations in the model, a set of observing system simulation experiments (OSSEs) was performed over 150 model years. Generally, assimilating sea surface temperature, sea surface salinity, and sea surface height (SSH) can reasonably reproduce the climate variability and vertical structure of the upper ocean, and assimilating SSH achieves the best results compared to the true states. For the El Niño-Southern Oscillation (ENSO), assimilating different surface observations captures true aspects of ENSO well, but assimilating SSH can further enhance the accuracy of ENSO-related feedback processes in the coupled model, leading to a more reasonable ENSO evolution and air-sea interaction over the tropical Pacific. For ocean heat content, there are still limitations in reproducing the long time-scale variability in the North Atlantic, even if SSH has been taken into consideration. These results demonstrate the effectiveness of assimilating surface observations in capturing the interannual signal and, to some extent, the decadal signal but still highlight the necessity of assimilating profile data to reproduce specific decadal variability.

  11. A cold and fresh ocean surface in the Nordic Seas during MIS 11: Significance for the future ocean

    NARCIS (Netherlands)

    Kandiano, E.S.; Van der Meer, M.T.J.; Bauch, H.A.; Helmke, J.; Sinninghe Damsté, J.S.; Schouten, S.

    2016-01-01

    Paleoceanographical studies of Marine Isotope Stage (MIS) 11 have revealed higher-than-presentsea surface temperatures (SSTs) in the North Atlantic and in parts of the Arctic but lower-than-present SSTsin the Nordic Seas, the main throughflow area of warm water into the Arctic Ocean. We resolve

  12. A cold and fresh ocean surface in the Nordic Seas during MIS 11 : Significance for the future ocean

    NARCIS (Netherlands)

    Kandiano, Evgenia S.; van der Meer, M.T.J.; Bauch, H.A.; Helmke, Jan; Sinninghe Damsté, J.S.; Schouten, S.

    2016-01-01

    Paleoceanographical studies of Marine Isotope Stage (MIS) 11 have revealed higher-than-present sea surface temperatures (SSTs) in the North Atlantic and in parts of the Arctic but lower-than-present SSTs in the Nordic Seas, the main throughflow area of warm water into the Arctic Ocean. We resolve

  13. Wear and surface roughness of silorane composites after pH cycling and toothbrushing abrasion.

    Science.gov (United States)

    Ishikiriama, Sérgio Kiyoshi; De Oliveira, Gabriela Ulian; Maenosono, Rafael Massunari; Wang, Linda; Duarte, Marco Antonio Húngaro; Mondelli, Rafael Francisco Lia

    2014-08-01

    To evaluate the effects of toothbrushing abrasion associated with pH cycling on the surface roughness and wear of methacrylate- and silorane-based resin composites. Microhybrid methacrylate-based (Filtek Z250), nanofilled methacrylate-based (Filtek Supreme Ultra) and microhybrid silorane-based (Filtek LS) composites were selected for this investigation. For each composite, two groups (n = 10) of rectangular specimens were made. The initial roughness (Ra) of all of the groups was evaluated based on the average of three random tracings with a profilometer, and each specimen had half of its surface protected with two layers of nail varnish to serve as controls. Half of the specimens of each resin were submitted to pH cycling, while the other half were stored in deionized water for 14 days. Subsequently, 100,000 strokes of simulated toothbrushing were performed. Final roughness and wear were measured with the same profilometer, and the values were submitted to ANOVA, Student's t-test and Tukey's test (P toothbrushing, while Filtek LS showed the opposite behavior. Methacrylate-based composites presented lower wear values [Z250 (4.19 ± 1.73 μm); Supreme Ultra (4.16 ± 0.95 μm)], while the silorane-based composite presented increased surface roughness (11.51 ± 5.69 μm), particularly when submitted to pH cycling (15.31 ± 5.41 μm). Despite the good properties of silorane-based composites, particularly its smooth surface roughness even after pH cycling and toothbrushing abrasion, this composite still presented increased wear, which is an important issue for the development of new resin compositions.

  14. Marine isoprene production and consumption in the mixed layer of the surface ocean - a field study over two oceanic regions

    Science.gov (United States)

    Booge, Dennis; Schlundt, Cathleen; Bracher, Astrid; Endres, Sonja; Zäncker, Birthe; Marandino, Christa A.

    2018-02-01

    Parameterizations of surface ocean isoprene concentrations are numerous, despite the lack of source/sink process understanding. Here we present isoprene and related field measurements in the mixed layer from the Indian Ocean and the eastern Pacific Ocean to investigate the production and consumption rates in two contrasting regions, namely oligotrophic open ocean and the coastal upwelling region. Our data show that the ability of different phytoplankton functional types (PFTs) to produce isoprene seems to be mainly influenced by light, ocean temperature, and salinity. Our field measurements also demonstrate that nutrient availability seems to have a direct influence on the isoprene production. With the help of pigment data, we calculate in-field isoprene production rates for different PFTs under varying biogeochemical and physical conditions. Using these new calculated production rates, we demonstrate that an additional significant and variable loss, besides a known chemical loss and a loss due to air-sea gas exchange, is needed to explain the measured isoprene concentration. We hypothesize that this loss, with a lifetime for isoprene between 10 and 100 days depending on the ocean region, is potentially due to degradation or consumption by bacteria.

  15. On-chip surface modified nanostructured ZnO as functional pH sensors

    Science.gov (United States)

    Zhang, Qing; Liu, Wenpeng; Sun, Chongling; Zhang, Hao; Pang, Wei; Zhang, Daihua; Duan, Xuexin

    2015-09-01

    Zinc oxide (ZnO) nanostructures are promising candidates as electronic components for biological and chemical applications. In this study, ZnO ultra-fine nanowire (NW) and nanoflake (NF) hybrid structures have been prepared by Au-assisted chemical vapor deposition (CVD) under ambient pressure. Their surface morphology, lattice structures, and crystal orientation were investigated by scanning electron microscopy (SEM), x-ray diffraction (XRD), and transmission electron microscopy (TEM). Two types of ZnO nanostructures were successfully integrated as gate electrodes in extended-gate field-effect transistors (EGFETs). Due to the amphoteric properties of ZnO, such devices function as pH sensors. We found that the ultra-fine NWs, which were more than 50 μm in length and less than 100 nm in diameter, performed better in the pH sensing process than NW-NF hybrid structures because of their higher surface-to-volume ratio, considering the Nernst equation and the Gouy-Chapman-Stern model. Furthermore, the surface coating of (3-Aminopropyl)triethoxysilane (APTES) protects ZnO nanostructures in both acidic and alkaline environments, thus enhancing the device stability and extending its pH sensing dynamic range.

  16. Iodine isotopes species fingerprinting environmental conditions in surface water along the northeastern Atlantic Ocean

    DEFF Research Database (Denmark)

    He, Peng; Hou, Xiaolin; Aldahan, Ala

    2013-01-01

    Concentrations and species of iodine isotopes (127I and 129I) provide vital information about iodine geochemistry, environmental conditions and water masses exchange in oceans. Despite extensive investigations of anthropogenic 129I in the Arctic Ocean and the Nordic Seas, concentrations of the is...... 129I in ocean environments and impact on climate at the ocean boundary layer.......Concentrations and species of iodine isotopes (127I and 129I) provide vital information about iodine geochemistry, environmental conditions and water masses exchange in oceans. Despite extensive investigations of anthropogenic 129I in the Arctic Ocean and the Nordic Seas, concentrations...... of the isotope in the Atlantic Ocean are, however, still unknown. We here present first data on 129I and 127I, and their species (iodide and iodate) in surface water transect along the northeastern Atlantic between 30° and 50°N. The results show iodate as the predominant species in the analyzed marine waters...

  17. Respiration of new and old carbon in the surface ocean: Implications for estimates of global oceanic gross primary productivity

    Science.gov (United States)

    Carvalho, Matheus C.; Schulz, Kai G.; Eyre, Bradley D.

    2017-06-01

    New respiration (Rnew, of freshly fixated carbon) and old respiration (Rold, of storage carbon) were estimated for different regions of the global surface ocean using published data on simultaneous measurements of the following: (1) primary productivity using 14C (14PP); (2) gross primary productivity (GPP) based on 18O or O2; and (3) net community productivity (NCP) using O2. The ratio Rnew/GPP in 24 h incubations was typically between 0.1 and 0.3 regardless of depth and geographical area, demonstrating that values were almost constant regardless of large variations in temperature (0 to 27°C), irradiance (surface to 100 m deep), nutrients (nutrient-rich and nutrient-poor waters), and community composition (diatoms, flagellates, etc,). As such, between 10 and 30% of primary production in the surface ocean is respired in less than 24 h, and most respiration (between 55 and 75%) was of older carbon. Rnew was most likely associated with autotrophs, with minor contribution from heterotrophic bacteria. Patterns were less clear for Rold. Short 14C incubations are less affected by respiratory losses. Global oceanic GPP is estimated to be between 70 and 145 Gt C yr-1.Plain Language SummaryHere we present a comprehensive coverage of ocean new and old respiration. Our results show that nearly 20% of oceanic gross primary production is consumed in the first 24 h. However, most (about 60%) respiration is of older carbon fixed at least 24 h before its consumption. Rates of new respiration relative to gross primary production were remarkably constant for the entire ocean, which allowed a preliminary estimation of global primary productivity as between 70 and 145 gt C yr-1.

  18. Influence of pH, bleaching agents, and acid etching on surface wear of bovine enamel

    Science.gov (United States)

    Soares, Ana Flávia; Bombonatti, Juliana Fraga Soares; Alencar, Marina Studart; Consolmagno, Elaine Cristina; Honório, Heitor Marques; Mondelli, Rafael Francisco Lia

    2016-01-01

    ABSTRACT Development of new materials for tooth bleaching justifies the need for studies to evaluate the changes in the enamel surface caused by different bleaching protocols. Objective The aim of this study was to evaluate the bovine dental enamel wear in function of different bleaching gel protocols, acid etching and pH variation. Material and Methods Sixty fragments of bovine teeth were cut, obtaining a control and test areas. In the test area, one half received etching followed by a bleaching gel application, and the other half, only the bleaching gel. The fragments were randomly divided into six groups (n=10), each one received one bleaching session with five hydrogen peroxide gel applications of 8 min, activated with hybrid light, diode laser/blue LED (HL) or diode laser/violet LED (VHL) (experimental): Control (C); 35% Total Blanc Office (TBO35HL); 35% Lase Peroxide Sensy (LPS35HL); 25% Lase Peroxide Sensy II (LPS25HL); 15% Lase Peroxide Lite (LPL15HL); and 10% hydrogen peroxide (experimental) (EXP10VHL). pH values were determined by a pHmeter at the initial and final time periods. Specimens were stored, subjected to simulated brushing cycles, and the superficial wear was determined (μm). ANOVA and Tukey´s tests were applied (α=0.05). Results The pH showed a slight decrease, except for Group LPL15HL. Group LPS25HL showed the highest degree of wear, with and without etching. Conclusion There was a decrease from the initial to the final pH. Different bleaching gels were able to increase the surface wear values after simulated brushing. Acid etching before bleaching increased surface wear values in all groups. PMID:27008254

  19. Fine-Scale Variability in Temperature, Salinity, and pH in the Upper-Ocean and the Effects on Acoustic Transmission Loss in the Western Arctic Ocean.

    Science.gov (United States)

    2010-03-01

    ocean (Bates et al. 2006) by entrainment in the sinking denser water. 4. Ocean Acidification The equilibrium equation for carbon dioxide in water is...significantly increases air- ocean interactions. As atmospheric carbon dioxide (CO2) levels rise (Bindoff et al. 2007 and Denman et al. 2007), there is...atmospheric nitrogen and sulfur decomposition on ocean acidification and the inorganic carbon system." Edited by M. L. Bender. Proceedings of the

  20. Acidic pH increases airway surface liquid viscosity in cystic fibrosis

    Science.gov (United States)

    Tang, Xiao Xiao; Ostedgaard, Lynda S.; Hoegger, Mark J.; Moninger, Thomas O.; Karp, Philip H.; McMenimen, James D.; Choudhury, Biswa; Varki, Ajit; Stoltz, David A.; Welsh, Michael J.

    2016-01-01

    Cystic fibrosis (CF) disrupts respiratory host defenses, allowing bacterial infection, inflammation, and mucus accumulation to progressively destroy the lungs. Our previous studies revealed that mucus with abnormal behavior impaired mucociliary transport in newborn CF piglets prior to the onset of secondary manifestations. To further investigate mucus abnormalities, here we studied airway surface liquid (ASL) collected from newborn piglets and ASL on cultured airway epithelia. Fluorescence recovery after photobleaching revealed that the viscosity of CF ASL was increased relative to that of non-CF ASL. CF ASL had a reduced pH, which was necessary and sufficient for genotype-dependent viscosity differences. The increased viscosity of CF ASL was not explained by pH-independent changes in HCO3– concentration, altered glycosylation, additional pH-induced disulfide bond formation, increased percentage of nonvolatile material, or increased sulfation. Treating acidic ASL with hypertonic saline or heparin largely reversed the increased viscosity, suggesting that acidic pH influences mucin electrostatic interactions. These findings link loss of cystic fibrosis transmembrane conductance regulator–dependent alkalinization to abnormal CF ASL. In addition, we found that increasing Ca2+ concentrations elevated ASL viscosity, in part, independently of pH. The results suggest that increasing pH, reducing Ca2+ concentration, and/or altering electrostatic interactions in ASL might benefit early CF. PMID:26808501

  1. Transport and scavenging of Pu in surface waters of the Southern Hemisphere Oceans

    DEFF Research Database (Denmark)

    Gastaud, J.; Povinec, P.P.; Aoyama, M.

    2011-01-01

    of the conservative 137Cs tracer are in all three oceanic basins comparable. The primary productivity reflected by the chlorophyll content in surface waters has similar longitudinal distribution as 239Pu. Radioactive and chlorophyll tracers revealed that the most important current system in each southern oceanic...

  2. Evolving research directions in Surface Ocean-Lower Atmosphere (SOLAS) science

    NARCIS (Netherlands)

    Law, Cliff S.; Breviere, Emilie; de Leeuw, Gerrit; Garcon, Veronique; Guieu, Cecile; Kieber, David J.; Kontradowitz, Stefan; Paulmier, Aurelien; Quinn, Patricia K.; Saltzman, Eric S.; Stefels, Jacqueline; von Glasow, Roland

    2013-01-01

    This review focuses on critical issues in ocean-atmosphere exchange that will be addressed by new research strategies developed by the international Surface Ocean-Lower Atmosphere Study (SOLAS) research community. Eastern boundary upwelling systems are important sites for CO2 and trace gas emission

  3. The Surface Water and Ocean Topography Mission: a mission concept to study the world's oceans and fresh water

    Science.gov (United States)

    Vaze, Parag; Albuys, Vincent; Esteban-Fernandez, Daniel; Lafon, Thierry; Lambin, Juliette; Mallet, Alain; Rodriguez, Ernesto

    2010-10-01

    The Surface Water and Ocean Topography (SWOT) is a planned satellite mission to study the world's oceans and terrestrial surface water bodies. The SWOT mission concept has been proposed jointly by the global Hydrology and Oceanography science communities to make the first global survey of the Earth's surface water, observe the fine details of the ocean's surface topography, and measure how water bodies change over time. SWOT was one of 15 missions listed in the 2007 National Research Council's Decadal Survey for Earth science as a mission that NASA should implement in the incoming decade. This mission concept builds upon the heritage of prior missions and technologies such as Topex/Poseidon, Jason-1/ 2, the Shuttle Radar Topography Mission (SRTM), and the initial development of the Wide Swatch Ocean Altimeter intended for the Ocean Surface Topography Mission/Jason-2. The key measurement capability for SWOT is provided by a Ka-band synthetic aperture radar interferometer (KaRIn). With an orbit altitude of 970 km, the KaRIn instrument provides a high-resolution swath width of 120 km enabling global coverage (~90%) of the world's ocean's and fresh water bodies. The KaRIn measurement is being designed to provide a spatial resolution of 1 km for the oceans (after on-board processing), and 100 m for land water, both at centimetric accuracy. An additional instrument suite similar to the Jason series will complement KaRIn: a Ku-band nadir altimeter, a Microwave Radiometer and Precision Orbit Determination (POD) systems. To enable this challenging measurement performance, the SWOT mission concept is designed to overcome several challenges, such as very high raw data rate (320 Mbps), large on-board data volumes, high power demand, stringent pointing and stability requirements, and ground data processing systems, to produce meaningful science data products to our user community. The SWOT mission concept is being developed as a cooperative effort between NASA and CNES. This

  4. Geochemistry of the Congo and Amazon river systems. Boron isotopic geochemistry in corals. Continental erosion and ocean pH

    International Nuclear Information System (INIS)

    Gaillardet, J.

    1995-01-01

    Two main geological processes control the CO 2 concentration in the atmosphere at a geological time scale: CO 2 outgasing from the interior of the Earth and CO 2 consumption by continental weathering. In the thesis, we initiate two different directions that can be useful to constraint the past climate evolution models. The first one is the extensive study of the largest rivers of the world using the classical geochemical analyses (major and trace elements, Sr-Nd-Pb isotopes) and modelling approaches. The study case of this thesis are the Congo and Amazon Basin. In particular, the coupling between chemical and physical erosion is examined and related to the hydrologic and tectonic parameters. Relief, thus tectonics appear to best control CO 2 consumption by rock weathering. The second part of the work is devoted to the measurement of boron isotopic ratio in corals because it may be used as a proxy for paleo-ocean pH. It could thus bring important pieces of information on the global C cycle and climate evolution. The technical part is extensively described and the method applied to the corals from the last interglacial period. Our conclusion is that corals are likely to be influence by early diagenetic changes that modify the boron isotopic composition of corals. We thus propose a test to select the samples. (author)

  5. Photoheterotrophy of bacterioplankton is ubiquitous in the surface oligotrophic ocean

    Science.gov (United States)

    Evans, Claire; Gómez-Pereira, Paola R.; Martin, Adrian P.; Scanlan, David J.; Zubkov, Mikhail V.

    2015-06-01

    Accurate measurements in the Southern Hemisphere were obtained to test a hypothesis of the ubiquity of photoheterotrophy in the oligotrophic ocean. We present experimental results of light-enhanced uptake of methionine, leucine and ATP by bacterioplankton during two large-scale transects of the South Atlantic. Light increased the uptake of substrates by both dominant bacterioplankton groups, Prochlorococcus and SAR11, as well as for the bulk microbial community. Our consistent experimental evidence strongly indicates that photoheterotrophy is characteristic of dominant bacterioplankton populations in the global oligotrophic ocean.

  6. Using the Regional Ocean Modelling System (ROMS to improve the sea surface temperature predictions of the MERCATOR Ocean System

    Directory of Open Access Journals (Sweden)

    Pedro Costa

    2012-09-01

    Full Text Available Global models are generally capable of reproducing the observed trends in the globally averaged sea surface temperature (SST. However, the global models do not perform as well on regional scales. Here, we present an ocean forecast system based on the Regional Ocean Modelling System (ROMS, the boundary conditions come from the MERCATOR ocean system for the North Atlantic (1/6° horizontal resolution. The system covers the region of the northwestern Iberian Peninsula with a horizontal resolution of 1/36°, forced with the Weather Research and Forecasting Model (WRF and the Soil Water Assessment Tool (SWAT. The ocean model results from the regional ocean model are validated using real-time SST and observations from the MeteoGalicia, INTECMAR and Puertos Del Estado real-time observational networks. The validation results reveal that over a one-year period the mean absolute error of the SST is less than 1°C, and several sources of measured data reveal that the errors decrease near the coast. This improvement is related to the inclusion of local forcing not present in the boundary condition model.

  7. Near-surface circulation and kinetic energy in the tropical Indian Ocean derived from lagrangian drifters

    Digital Repository Service at National Institute of Oceanography (India)

    Shenoi, S.S.C.; Saji, P.K.; Almeida, A.M.

    Trajectories of 412 satellite-tracked drifting buoys deployed in the tropical Indian Ocean have been analyzed to document the surface circulation and kinetic energy field. Only drifters drogued at 15 m depth and having drag area ratio greater than...

  8. Calibration and Validation of High Frequency Radar for Ocean Surface Current Mapping

    National Research Council Canada - National Science Library

    Kim, Kyung

    2004-01-01

    High Frequency (HF) radar backscatter instruments are being developed and tested in the marine science and defense science communities for their abilities to sense surface parameters remotely in the coastal ocean over large areas...

  9. Retrieval of sea surface air temperature from satellite data over Indian Ocean: An empirical approach

    Digital Repository Service at National Institute of Oceanography (India)

    Sathe, P.V.; Muraleedharan, P.M.

    The sea surface air temperature is an important parameter required for computation of air-sea fluxes over oceans which at present cannot be directly measured from remote sensing. In the present article, an empirical approach is proposed to determine...

  10. Trends of pH decrease in the Mediterranean Sea through high frequency observational data: indication of ocean acidification in the basin.

    Science.gov (United States)

    Flecha, Susana; Pérez, Fiz F; García-Lafuente, Jesús; Sammartino, Simone; Ríos, Aida F; Huertas, I Emma

    2015-11-26

    A significant fraction of anthropogenic carbon dioxide (CO2) released to the atmosphere is absorbed by the oceans, leading to a range of chemical changes and causing ocean acidification (OA). Assessing the impact of OA on marine ecosystems requires the accurate detection of the rate of seawater pH change. This work reports the results of nearly 3 years of continuous pH measurements in the Mediterranean Sea at the Strait of Gibraltar GIFT time series station. We document a remarkable decreasing annual trend of -0.0044 ± 0.00006 in the Mediterranean pH, which can be interpreted as an indicator of acidification in the basin based on high frequency records. Modeling pH data of the Mediterranean outflow allowed to discriminate between the pH values of its two main constituent water masses, the Levantine Intermediate Water (LIW) and the Western Mediterranean Deep Water (WMDW). Both water masses also exhibited a decline in pH with time, particularly the WMDW, which can be related to their different biogeochemical nature and processes occurring during transit time from formation sites to the Strait of Gibraltar.

  11. Pathways of upwelling deep waters to the surface of the Southern Ocean

    Science.gov (United States)

    Tamsitt, Veronica; Drake, Henri; Morrison, Adele; Talley, Lynne; Dufour, Carolina; Gray, Alison; Griffies, Stephen; Mazloff, Matthew; Sarmiento, Jorge; Wang, Jinbo; Weijer, Wilbert

    2017-04-01

    Upwelling of Atlantic, Indian and Pacific deep waters to the sea surface in the Southern Ocean closes the global overturning circulation and is fundamentally important for oceanic uptake of anthropogenic carbon and heat, nutrient resupply for sustaining oceanic biological production, and the melt rate of ice shelves. Here we go beyond the two-dimensional view of Southern Ocean upwelling, to show detailed Southern Ocean upwelling pathways in three dimensions, using hydrographic observations and particle tracking in high-resolution ocean and climate models. The northern deep waters enter the Antarctic Circumpolar Current (ACC) via narrow southward currents along the boundaries of the three ocean basins, before spiraling southeastward and upward through the ACC. Upwelling is greatly enhanced at five major topographic features, associated with vigorous mesoscale eddy activity. Deep water reaches the upper ocean predominantly south of the southern ACC boundary, with a spatially nonuniform distribution, regionalizing warm water supply to Antarctic ice shelves and the delivery of nutrient and carbon-rich water to the sea surface. The timescale for half of the deep water to upwell from 30°S to the mixed layer is on the order of 60-90 years, which has important implications for the timescale for signals to propagate through the deep ocean. In addition, we quantify the diabatic transformation along particle trajectories, to identify where diabatic processes are important along the upwelling pathways.

  12. Retrieval of sea surface velocities using sequential Ocean Colour ...

    Indian Academy of Sciences (India)

    The Indian remote sensing satellite, IRS-P4 (Oceansat-I) launched on May 26th, 1999 carried two sensors on board, i.e., the Ocean Colour Monitor (OCM) and the Multi-frequency Scanning Microwave Radiometer (MSMR) dedicated for oceanographic research. Sequential data of IRS-P4 OCM has been analysed over parts ...

  13. Retrieval of sea surface velocities using sequential Ocean Colour ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    The Indian remote sensing satellite, IRS-P4 (Oceansat-I) launched on May 26th, 1999 carried two sensors on board, i.e., the Ocean Colour Monitor (OCM) and the Multi-frequency Scanning. Microwave Radiometer (MSMR) dedicated for oceanographic research. Sequential data of IRS-P4. OCM has been analysed over ...

  14. pH and redox responsive polymer for antifouling surface coating

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Kang Seok [Department of Chemical and Biological Engineering, Korea National University of Transportation, Chungju, 380-702 (Korea, Republic of); In, Insik, E-mail: in1@ut.ac.kr [Department of Polymer Science and Engineering, Korea National University of Transportation, Chungju, 380-702 (Korea, Republic of); Department of IT Convergence, Korea National University of Transportation, Chungju, 380-702 (Korea, Republic of); Park, Sung Young, E-mail: parkchem@ut.ac.kr [Department of Chemical and Biological Engineering, Korea National University of Transportation, Chungju, 380-702 (Korea, Republic of); Department of IT Convergence, Korea National University of Transportation, Chungju, 380-702 (Korea, Republic of)

    2014-09-15

    Graphical abstract: Dual responsive surface with highly fouling resistance with the formation of a pH-dependent benzoic imine and redox-sensitive disulfide bond has been developed using a catechol/benzoic acid conjugated polymer and disulfide containing amine end-capped Pluronic. - Highlights: • Stimuli-responsive antifouling surface was prepared by layer-by-layer method. • The surface contact angle showed responsive behavior via pH and redox environments. • Simply coated polymer completely prevented cell adhesion onto surfaces. - Abstract: A dual environmentally responsive polymer with a highly fouling-resistant surface has been developed using poly[(hydroxyethyl methacrylate-g-benzoic acid)-co-(dimethylaminoethyl methacrylate-g-2-chloro-3′, 4′-dihydroxyacetophenone)] [poly[(HEMA-BA)-co-(DMAEMA-CCDP)], P1] as a coating material. The redox-sensitive disulfide containing amine end-capped Pluronic [(Plu-S-S-NH{sub 2}), P2] was then introduced over the P1 surface via the formation of a pH-dependent benzoic imine bond, where the polyethylene glycol (PEG) acts as an antifouling agent. The successful adhesion of P1 and the deposition of P2 onto the P1-coated substrate were ascertained with X-ray photoelectron spectroscopy (XPS). In vitro cell adhesion followed by scanning electron microscopy (SEM) indicated an excellent antifouling nature of the P2 layer. Consequently, the reattachment of Hela cells was strongly observed when P2 layered on P1-coated substrates (P1–P2) was pretreated at lower pH and high redox conditions. The P1–P2 bilayer-coated substrate has exhibited a great advantage in its effective antifouling behaviors with well-tuned cell attachment and detachment.

  15. Extensional terrain formation on Europa and Ganymede: Implications for ocean-surface interaction

    Science.gov (United States)

    Howell, S. M.; Pappalardo, R. T.

    2017-12-01

    Europa and Ganymede, Galilean satellites of Jupiter, exhibit geologic activity in their outer H2O ice shells that might convey material from water oceans within the satellites to their surfaces. Imagery from the Voyager and Galileo spacecraft reveal surfaces rich with tectonic deformation, including dilational bands on Europa and groove lanes on Ganymede. These features are generally attributed to the extension of a brittle ice lithosphere overlaying a possibly convecting ice asthenosphere. To explore band formation and interaction with interior oceans, we employ fully visco-elasto-plastic 2-D models of faulting and convection with complex, realistic pure ice rheologies. In these models, material entering from below is tracked and considered to be "fossilized ocean," ocean material that has frozen into the ice shell and evolves through geologic time. We track the volume fraction of fossil ocean material in the ice shell as a function of depth, and the exposure of both fresh ice and fossil ocean material at the ice shell surface. We vary ice shell thickness, fault localization, melting-temperature ice viscosity, and the presence of pre-existing weaknesses. Mechanisms which act to weaken the ice shell and thin the lithosphere (e.g. vigorous convection, thinner shells, pre-existing weaknesses) tend to plastically yield to form smooth bands at high strains, and are more likely to incorporate fossil ocean material in the ice shell and expose it at the surface. In contrast, lithosphere strengthened by rapid fault annealing or increased viscosity, for example, exhibits large-scale tectonic rifting at low strains superimposed over pre-existing terrains, and inhibits the incorporation and delivery of fossil ocean material to the surface. Thus, our results identify a spectrum of extensional terrain formation mechanisms as linked to lithospheric strength, rather than any specific mechanism being unique to each type of band, and where in this spectrum ocean material

  16. The Wave Glider°: A New Autonomous Surface Vehicle to Augment MBARI's Growing Fleet of Ocean Observing Systems

    Science.gov (United States)

    Tougher, B. B.

    2011-12-01

    Monterey Bay Aquarium Research Institute's (MBARI) evolving fleet of ocean observing systems has made it possible to collect information and data about a wide variety of ocean parameters, enabling researchers to better understand marine ecosystems. In collaboration with Liquid Robotics Inc, the designer of the Wave Glider autonomous surface vehicle (ASV), MBARI is adding a new capability to its suite of ocean observing tools. This new technology will augment MBARI research programs that use satellites, ships, moorings, drifters, autonomous underwater vehicles (AUVs) and remotely operated vehicles (ROVs) to improve data collection of temporally and spatially variable oceanographic features. The Wave Glider ASV derives its propulsion from wave energy, while sensors and communications are powered through the use of two solar panels and batteries, enabling it to remain at sea indefinitely. Wave Gliders are remotely controlled via real-time Iridium burst communications, which also permit real-time data telemetry. MBARI has developed Ocean Acidification (OA) moorings to continuously monitor the chemical and physical changes occurring in the ocean as a result of increased levels of atmospheric carbon dioxide (CO2). The moorings are spatially restricted by being anchored to the seafloor, so during the summer of 2011 the ocean acidification sensor suite designed for moorings was integrated into a Wave Glider ASV to increase both temporal and spatial ocean observation capabilities. The OA sensor package enables the measurement of parameters essential to better understanding the changing acidity of the ocean, specifically pCO2, pH, oxygen, salinity and temperature. The Wave Glider will also be equipped with a meteorological sensor suite that will measure air temperature, air pressure, and wind speed and direction. The OA sensor integration into a Wave Glider was part of MBARI's 2011 summer internship program. This project involved designing a new layout for the OA sensors

  17. Latitudinal and seasonal capacity of the surface oceans as a reservoir of polychlorinated biphenyls

    International Nuclear Information System (INIS)

    Jurado, Elena; Lohmann, Rainer; Meijer, Sandra; Jones, Kevin C.; Dachs, Jordi

    2004-01-01

    The oceans play an important role as a global reservoir and ultimate sink of persistent organic pollutants (POPs) such as polychlorinated biphenyls congeners (PCBs). However, the physical and biogeochemical variables that affect the oceanic capacity to retain PCBs show an important spatial and temporal variability which have not been studied in detail, so far. The objective of this paper is to assess the seasonal and spatial variability of the ocean's maximum capacity to act as a reservoir of atmospherically transported and deposited PCBs. A level I fugacity model is used which incorporates the environmental variables of temperature, phytoplankton biomass, and mixed layer depth, as determined from remote sensing and from climatological datasets. It is shown that temperature, phytoplankton biomass and mixed layer depth influence the potential PCB reservoir of the oceans, being phytoplankton biomass specially important in the oceanic productive regions. The ocean's maximum capacities to hold PCBs are estimated. They are compared to a budget of PCBs in the surface oceans derived using a level III model that assumes steady state and which incorporates water column settling fluxes as a loss process. Results suggest that settling fluxes will keep the surface oceanic reservoir of PCBs well below its maximum capacity, especially for the more hydrophobic compounds. The strong seasonal and latitudinal variability of the surface ocean's storage capacity needs further research, because it plays an important role in the global biogeochemical cycles controlling the ultimate sink of PCBs. Because this modeling exercise incorporates variations in downward fluxes driven by phytoplankton and the extent of the water column mixing, it predicts more complex latitudinal variations in PCBs concentrations than those previously suggested. - Model calculations estimate the latitudinal and seasonal storage capacity of the surface oceans for PCBs

  18. Trans-life cycle acclimation to experimental ocean acidification affects gastric pH homeostasis and larval recruitment in the sea star Asterias rubens.

    Science.gov (United States)

    Hu, Marian Y; Lein, Etienne; Bleich, Markus; Melzner, Frank; Stumpp, Meike

    2018-04-16

    Experimental simulation of near-future ocean acidification (OA) has been demonstrated to affect growth and development of echinoderm larval stages through energy allocation towards ion and pH compensatory processes. To date, it remains largely unknown how major pH regulatory systems and their energetics are affected by trans-generational exposure to near-future acidification levels. Here we used the common sea star Asterias rubens in a reciprocal transplant experiment comprising different combinations of OA scenarios, in order to study trans-generational plasticity using morphological and physiological endpoints. Acclimation of adults to pH T 7.2 (pCO 2 3500μatm) led to reductions in feeding rates, gonad weight, and fecundity. No effects were evident at moderate acidification levels (pH T 7.4; pCO 2 2000μatm). Parental pre-acclimation to pH T 7.2 for 85 days reduced developmental rates even when larvae were raised under moderate and high pH conditions, whereas pre-acclimation to pH T 7.4 did not alter offspring performance. Microelectrode measurements and pharmacological inhibitor studies carried out on larval stages demonstrated that maintenance of alkaline gastric pH represents a substantial energy sink under acidified conditions that may contribute up to 30% to the total energy budget. Parental pre-acclimation to acidification levels that are beyond the pH that is encountered by this population in its natural habitat (e.g. pH T 7.2) negatively affected larval size and development, potentially through reduced energy transfer. Maintenance of alkaline gastric pH and reductions in maternal energy reserves probably constitute the main factors for a reduced juvenile recruitment of this marine keystone species under simulated OA. This article is protected by copyright. All rights reserved. This article is protected by copyright. All rights reserved.

  19. Quantifying the Dynamic Ocean Surface Using Underwater Radiometric Measurements

    Science.gov (United States)

    2013-09-30

    PUBLICATIONS 1. Xu, Z. and D. K. P. Yue (2013a), Mixture model for probability of inherent shortwave radiation intensity in strong scattering mediums...reflections for various solar incidence conditions, particularly the shadowing effect for large zenith solar incidence case. With the numerical tool, we...We provided direct and empirical derivations of parameters needed for the model using priori information of ocean wave spectra, solar incidence and

  20. An overview of ENSO signature on the surface parameters of the tropical Pacific ocean

    Directory of Open Access Journals (Sweden)

    1998-01-01

    Full Text Available ÉTUDE DE LA SIGNATURE DE L’ENSO SUR LES PARAMETRES DE SURFACE DE L’OCEAN PACIFIQUE TROPICAL. A l’échelle interannuelle, le phénomène climatique El Niño Oscillation Australe (ENSO constitue le signal climatique le plus puissant de la Planète. Cette note décrit et analyse la variabilité associée à ce phénomène dans le Pacifique tropical au cours de la période 1961-1995. L’accent est mis sur cinq paramètres considérés comme essentiels, à savoir: la température et la salinité de surface, l’anomalie de hauteur dynamique 0/450 dbar (un alias du niveau de la mer, le vent de surface et les précipitations. Le signal ENSO est décrit à partir d’une analyse en fonctions empiriques orthogonales des séries temporelles filtrées de manière à ne retenir que les variations de période supérieure à un an. Cette analyse précise de manière concise l’amplitude, la position géographique et la date d’apparition des anomalies associées à chaque paramètre. UN ESTUDIO DE LA FIRMA ENSO DE LOS PARÁMETROS SUPERFICIALES DEL OCÉANO PACÍFICO TROPICAL. El fenómeno ENSO (El Niño Oscilación del Sur es el fenómeno climático más poderoso del planeta a una escala interanual. En esta nota, la variabilidad relacionada al ENSO, se describe y analiza para los parámetros claves oceánicos y atmosféricos del Pacífico tropical. Estos parámetros consisten en la temperatura superficial del mar y la salinidad, la anomalía de altura dinámica 0/450 dbar (esto es, un alias para el nivel del mar, viento superficial y la precipitación recolectada durante el período de 1961 a 1995. Se extraen las señales relacionadas al ENSO a partir del análisis de una Función Ortogonal Empírica (FOE realizada en las series de tiempo filtradas de paso bajo. Para cada parámetro, el análisis FOE precisa las localizaciones y tiempos de las variaciones notables relacionadas al ENSO en una forma concisa. The ENSO (El Niño Southern Oscillation phenomenon

  1. Statistical fluctuations of an ocean surface inferred from shoes and ships

    Science.gov (United States)

    Lerche, Ian; Maubeuge, Frédéric

    1995-12-01

    This paper shows that it is possible to roughly estimate some ocean properties using simple time-dependent statistical models of ocean fluctuations. Based on a real incident, the loss by a vessel of a Nike shoes container in the North Pacific Ocean, a statistical model was tested on data sets consisting of the Nike shoes found by beachcombers a few months later. This statistical treatment of the shoes' motion allows one to infer velocity trends of the Pacific Ocean, together with their fluctuation strengths. The idea is to suppose that there is a mean bulk flow speed that can depend on location on the ocean surface and time. The fluctuations of the surface flow speed are then treated as statistically random. The distribution of shoes is described in space and time using Markov probability processes related to the mean and fluctuating ocean properties. The aim of the exercise is to provide some of the properties of the Pacific Ocean that are otherwise calculated using a sophisticated numerical model, OSCURS, where numerous data are needed. Relevant quantities are sharply estimated, which can be useful to (1) constrain output results from OSCURS computations, and (2) elucidate the behavior patterns of ocean flow characteristics on long time scales.

  2. Ocean Acidification in the Surface Waters of the Pacific-Arctic Boundary Regions

    Science.gov (United States)

    Mathis, J. T.; Cross, J. N.; Evans, W.; Doney, S. C.

    2016-02-01

    The continental shelves of the Pacific-Arctic Region (PAR) are especially vulnerable to the effects of ocean acidification (OA) because the intrusion of anthropogenic CO2 is not the only process that can reduce pH and carbonate mineral saturation states for aragonite (ΩArag). Enhanced sea-ice melt, respiration of organic matter, upwelling and riverine inputs have been shown to exacerbate CO2-driven ocean acidification in high-latitude regions. Additionally, the indirect effect of changing sea-ice coverage is providing a positive feedback to OA as more open water will allow for greater uptake of atmospheric CO2. Here, we compare model-based outputs from the Community Earth System Model with a subset of recent ship-based observations, and take an initial look at future model projections of surface water ΩArag in the Bering, Chukchi and Beaufort Seas. We then use the model outputs to define benchmark years when biological impacts are likely to result from reduced ΩArag. Each of the three continental shelf seas in the PAR will become undersaturated with respect to aragonite at approximately 30-year intervals, indicating that aragonite undersaturations gradually progress upstream along the flow path of the waters as they move north from the Pacific Ocean. However, naturally high variability in ΩArag may indicate higher resilience of the Bering Sea ecosystem to these low-ΩArag conditions than the Chukchi and the Beaufort Seas. Based on our initial results, we have determined that the annual mean for ΩArag will pass below the current range of natural variability in 2025 for the Beaufort Sea and 2027 for the Chukchi Sea. Because of the higher range of natural variability, the annual mean for ΩArag for the Bering Sea does not pass out of the natural variability range until 2044. As ΩArag in these shelf seas slips below the present-day range of large seasonal variability by midcentury, it could put tremendous pressure on the diverse ecosystems that support some of

  3. Ocean acidification affects parameters of immune response and extracellular pH in tropical sea urchins Lytechinus variegatus and Echinometra luccunter.

    Science.gov (United States)

    Leite Figueiredo, Débora Alvares; Branco, Paola Cristina; Dos Santos, Douglas Amaral; Emerenciano, Andrews Krupinski; Iunes, Renata Stecca; Shimada Borges, João Carlos; Machado Cunha da Silva, José Roberto

    2016-11-01

    The rising concentration of atmospheric CO 2 by anthropogenic activities is changing the chemistry of the oceans, resulting in a decreased pH. Several studies have shown that the decrease in pH can affect calcification rates and reproduction of marine invertebrates, but little attention has been drawn to their immune response. Thus this study evaluated in two adult tropical sea urchin species, Lytechinus variegatus and Echinometra lucunter, the effects of ocean acidification over a period of 24h and 5days, on parameters of the immune response, the extracellular acid base balance, and the ability to recover these parameters. For this reason, the phagocytic capacity (PC), the phagocytic index (PI), the capacity of cell adhesion, cell spreading, cell spreading area of phagocytic amebocytes in vitro, and the coelomic fluid pH were analyzed in animals exposed to a pH of 8.0 (control group), 7.6 and 7.3. Experimental pH's were predicted by IPCC for the future of the two species. Furthermore, a recovery test was conducted to verify whether animals have the ability to restore these physiological parameters after being re-exposed to control conditions. Both species presented a significant decrease in PC, in the pH of coelomic fluid and in the cell spreading area. Besides that, Echinometra lucunter showed a significant decrease in cell spreading and significant differences in coelomocyte proportions. The recovery test showed that the PC of both species increased, also being below the control values. Even so, they were still significantly higher than those exposed to acidified seawater, indicating that with the re-establishment of the pH value the phagocytic capacity of cells tends to restore control conditions. These results demonstrate that the immune system and the coelomic fluid pH of these animals can be affected by ocean acidification. However, the effects of a short-term exposure can be reversible if the natural values ​​are re-established. Thus, the effects of

  4. How do uncertainties in NCEP R2 and CFSR surface fluxes impact tropical ocean simulations?

    Science.gov (United States)

    Wen, Caihong; Xue, Yan; Kumar, Arun; Behringer, David; Yu, Lisan

    2017-11-01

    NCEP/DOE reanalysis (R2) and Climate Forecast System Reanalysis (CFSR) surface fluxes are widely used by the research community to understand surface flux climate variability, and to drive ocean models as surface forcings. However, large discrepancies exist between these two products, including (1) stronger trade winds in CFSR than in R2 over the tropical Pacific prior 2000; (2) excessive net surface heat fluxes into ocean in CFSR than in R2 with an increase in difference after 2000. The goals of this study are to examine the sensitivity of ocean simulations to discrepancies between CFSR and R2 surface fluxes, and to assess the fidelity of the two products. A set of experiments, where an ocean model was driven by a combination of surface flux components from R2 and CFSR, were carried out. The model simulations were contrasted to identify sensitivity to different component of the surface fluxes in R2 and CFSR. The accuracy of the model simulations was validated against the tropical moorings data, altimetry SSH and SST reanalysis products. Sensitivity of ocean simulations showed that temperature bias difference in the upper 100 m is mostly sensitive to the differences in surface heat fluxes, while depth of 20 °C (D20) bias difference is mainly determined by the discrepancies in momentum fluxes. D20 simulations with CFSR winds agree with observation well in the western equatorial Pacific prior 2000, but have large negative bias similar to those with R2 winds after 2000, partly because easterly winds over the central Pacific were underestimated in both CFSR and R2. On the other hand, the observed temperature variability is well reproduced in the tropical Pacific by simulations with both R2 and CFSR fluxes. Relative to the R2 fluxes, the CFSR fluxes improve simulation of interannual variability in all three tropical oceans to a varying degree. The improvement in the tropical Atlantic is most significant and is largely attributed to differences in surface winds.

  5. System for Monitoring, Determining, and Reporting Directional Spectra of Ocean Surface Waves in Near Realtime from a Moored Buoy

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A moored buoy floating at the ocean surface and anchored to the seafloor precisely measures acceleration, pitch, roll, and Earth's magnetic flux field of the buoy...

  6. Enhanced Decadal Warming of the Southeast Indian Ocean During the Recent Global Surface Warming Slowdown

    Science.gov (United States)

    Li, Yuanlong; Han, Weiqing; Zhang, Lei

    2017-10-01

    The rapid Indian Ocean warming during the early-21th century was a major heat sink for the recent global surface warming slowdown. Analysis of observational data and ocean model experiments reveals that during 2003-2012 more than half of the increased upper Indian Ocean heat content was concentrated in the southeast Indian Ocean (SEIO), causing a warming "hot spot" of 0.8-1.2 K decade-1 near the west coast of Australia. This SEIO warming was primarily induced by the enhancements of the Pacific trade winds and Indonesian throughflow associated with the Interdecadal Pacific Oscillation's (IPO) transition to its negative phase, and to a lesser degree by local atmospheric forcing within the Indian Ocean. Large-ensemble climate model simulations suggest that this warming event was likely also exacerbated by anthropogenic forcing and thus unprecedentedly strong as compared to previous IPO transition periods. Climate model projections suggest an increasing possibility of such strong decadal warming in future.

  7. Macrofauna under sea ice and in the open surface layer of the Lazarev Sea, Southern Ocean

    NARCIS (Netherlands)

    Flores, Hauke; van Franeker, Jan-Andries; Cisewski, Boris; Leach, Harry; Van de Putte, Anton P.; Meesters, Erik (H. W. G.); Bathmann, Ulrich; Wolff, Wirn J.

    2011-01-01

    A new fishing gear was used to sample the macrozooplankton and micronekton community in the surface layer (0-2 m) under ice and in open water, the Surface and Under Ice Trawl (SUIT). In total, 57 quantitative hauls were conducted in the Lazarev Sea (Southern Ocean) during 3 different seasons (autumn

  8. Macrofauna under sea ice and in the open surface layer of the Lazarev Sea, Southern Ocean

    NARCIS (Netherlands)

    Florentino De Souza Silva, A.P.; Franeker, van J.A.; Cisewski, B.; Leach, H.; Putte, van de A.P.; Meesters, H.W.G.; Bathmann, U.; Wolff, W.J.

    2011-01-01

    A new fishing gear was used to sample the macrozooplankton and micronekton community in the surface layer (0–2 m) under ice and in open water, the Surface and Under Ice Trawl (SUIT). In total, 57 quantitative hauls were conducted in the Lazarev Sea (Southern Ocean) during 3 different seasons (autumn

  9. Ocean sunfish rewarm at the surface after deep excursions to forage for siphonophores.

    Science.gov (United States)

    Nakamura, Itsumi; Goto, Yusuke; Sato, Katsufumi

    2015-05-01

    Ocean sunfish (Mola mola) were believed to be inactive jellyfish feeders because they are often observed lying motionless at the sea surface. Recent tracking studies revealed that they are actually deep divers, but there has been no evidence of foraging in deep water. Furthermore, the surfacing behaviour of ocean sunfish was thought to be related to behavioural thermoregulation, but there was no record of sunfish body temperature. Evidence of ocean sunfish feeding in deep water was obtained using a combination of an animal-borne accelerometer and camera with a light source. Siphonophores were the most abundant prey items captured by ocean sunfish and were typically located at a depth of 50-200 m where the water temperature was Ocean sunfish were diurnally active, made frequently deep excursions and foraged mainly at 100-200 m depths during the day. Ocean sunfish body temperatures were measured under natural conditions. The body temperatures decreased during deep excursions and recovered during subsequent surfacing periods. Heat-budget models indicated that the whole-body heat-transfer coefficient between sunfish and the surrounding water during warming was 3-7 times greater than that during cooling. These results suggest that the main function of surfacing is the recovery of body temperature, and the fish might be able to increase heat gain from the warm surface water by physiological regulation. The thermal environment of ocean sunfish foraging depths was lower than their thermal preference (c. 16-17 °C). The behavioural and physiological thermoregulation enables the fish to increase foraging time in deep, cold water. Feeding rate during deep excursions was not related to duration or depth of the deep excursions. Cycles of deep foraging and surface warming were explained by a foraging strategy, to maximize foraging time with maintaining body temperature by vertical temperature environment. © 2015 The Authors. Journal of Animal Ecology © 2015 British

  10. Impacts of reduced pH from ocean CO{sub 2} disposal: Sensitivity of zooplankton mortality to model parameters

    Energy Technology Data Exchange (ETDEWEB)

    Adams, E.E.; Caulfield, J.A.; Herzog, H.J.; Auerbach, D.I. [Massachusetts Inst. of Tech., Cambridge, MA (United States)

    1998-07-01

    The authors have developed a methodology to quantify mortality suffered by marine zooplankton passing through a CO{sub 2}-enriched sea water plume. Here the authors explore model sensitivity to some of the more important biological, physical and engineering design parameters, with particular reference to CO{sub 2} injection as a buoyant droplet plume. Uncertainty in the dose-response relationship, e.g. caused by the use of data for surface organisms, will affect predicted values of total mortality by less than a factor of two for a single point discharge from 10 standard (500 MWe) coal-fired values of total mortality by less than a factor of two for a single point discharge from 10 standard 500 MWe coal-fired electric power plants and a factor of five for a single point discharge from one standard plant. The most important design variable is the number of physically separated discharge points (diffuser ports or groups of ports) used to disperse the CO{sub 2}. Predicted mortality drops to zero as the number of discharge points per standard plants exceeds two. Finally the most important physical parameters are ambient current speed and turbulent diffusivity. As with the dose-response data, most physical oceanographic measurements have been conducted near the ocean surface. Model sensitivity suggests that a factor of 2.5 reduction in current speed or a factor of 3 reduction in ambient diffusivity, relative to the base case, would require that the number of discharge points per standard plant increase from 2 to 12 in order to avoid mortality. Thus, impacts can be strongly site-specific, and additional oceanographic measurements are needed at depths appropriate for CO{sub 2} sequestration. Nonetheless, it should be easy to design an environmentally conservative multi-point discharge system that can disperse CO{sub 2} as a droplet plume without significant mortality, even under adverse environmental conditions.

  11. Sea surface temperature predictions using a multi-ocean analysis ensemble scheme

    Science.gov (United States)

    Zhang, Ying; Zhu, Jieshun; Li, Zhongxian; Chen, Haishan; Zeng, Gang

    2017-08-01

    This study examined the global sea surface temperature (SST) predictions by a so-called multiple-ocean analysis ensemble (MAE) initialization method which was applied in the National Centers for Environmental Prediction (NCEP) Climate Forecast System Version 2 (CFSv2). Different from most operational climate prediction practices which are initialized by a specific ocean analysis system, the MAE method is based on multiple ocean analyses. In the paper, the MAE method was first justified by analyzing the ocean temperature variability in four ocean analyses which all are/were applied for operational climate predictions either at the European Centre for Medium-range Weather Forecasts or at NCEP. It was found that these systems exhibit substantial uncertainties in estimating the ocean states, especially at the deep layers. Further, a set of MAE hindcasts was conducted based on the four ocean analyses with CFSv2, starting from each April during 1982-2007. The MAE hindcasts were verified against a subset of hindcasts from the NCEP CFS Reanalysis and Reforecast (CFSRR) Project. Comparisons suggested that MAE shows better SST predictions than CFSRR over most regions where ocean dynamics plays a vital role in SST evolutions, such as the El Niño and Atlantic Niño regions. Furthermore, significant improvements were also found in summer precipitation predictions over the equatorial eastern Pacific and Atlantic oceans, for which the local SST prediction improvements should be responsible. The prediction improvements by MAE imply a problem for most current climate predictions which are based on a specific ocean analysis system. That is, their predictions would drift towards states biased by errors inherent in their ocean initialization system, and thus have large prediction errors. In contrast, MAE arguably has an advantage by sampling such structural uncertainties, and could efficiently cancel these errors out in their predictions.

  12. Evolving research directions in Surface Ocean-Lower Atmosphere (SOLAS) science

    OpenAIRE

    Law, CS; Brévière, E; De Leeuw, G; Garçon, V; Guieu, C; Kieber, DJ; Kontradowitz, S; Paulmier, A; Quinn, PK; Saltzman, ES; Stefels, J; Von Glasow, R

    2013-01-01

    This review focuses on critical issues in ocean-atmosphere exchange that will be addressed by new research strategies developed by the international Surface Ocean-Lower Atmosphere Study (SOLAS) research community. Eastern boundary upwelling systems are important sites for CO 2 and trace gas emission to the atmosphere, and the proposed research will examine how heterotrophic processes in the underlying oxygen-deficient waters interact with the climate system. The second regional research focu...

  13. Artificial ocean upwelling utilizing the energy of surface waves

    Science.gov (United States)

    Soloviev, Alexander

    2016-04-01

    Artificial upwelling can bring cold water from below the thermocline to the sea surface. Vershinsky, Pshenichnyy, and Soloviev (1987) developed a prototype device, utilizing the energy of surface waves to create an upward flow of water in the tube. This is a wave-inertia pump consisting of a vertical tube, a valve, and a buoy to keep the device afloat. An outlet valve at the top of the unit synchronizes the operation of the device with surface waves and prevents back-splashing. A single device with a 100 m long and 1.2 m diameter tube is able to produce up to 1 m3s-1 flow of deep water to the surface. With a 10 oC temperature difference over 100 m depth, the negative heat supply rate to the sea surface is 42 MW, which is equivalent to a 42 Wm-2 heat flux, if distributed over 1 km2 area. Such flux is comparable to the average net air-sea flux. A system of artificial upwelling devices can cool down the sea surface, modify climate on a regional scale and possibly help mitigate hurricanes. The cold water brought from a deeper layer, however, has a larger density than the surface water and therefore has a tendency to sink back down. In this work, the efficiency of wave-inertia pumps and climatic consequences are estimated for different environmental conditions using a computational fluid dynamics model.

  14. Late Holocene diatom-based sea-surface temperature reconstruction from the Conrad Rise, Southern Ocean

    Science.gov (United States)

    Orme, Lisa; Mietinnen, Arto; Crosta, Xavier; Mohan, Rahul

    2017-04-01

    The Southern Ocean plays an important role in the global climate system. The temperature and sea ice extent alter the latitudinal temperature gradient of the Southern Ocean, which can be transferred to the atmosphere resulting in changes in the southern westerly winds. The temperature, sea ice and wind variations are also factors influencing Antarctic Bottom Water formation, which is a control on the strength of the Atlantic Meridional Overturning Circulation. Therefore conditions in the Southern Ocean may influence the climate in the northern and southern hemispheres. The Southern Ocean and North Atlantic were connected during the Last Glacial during Dansgaard-Oeschger events, when variations in ocean circulation caused a bipolar seesaw of temperatures. For the Holocene there is less evidence for a bipolar seesaw, although recent research shows concurrent, opposite trends in ocean circulation in the North Atlantic and in the Southern Ocean. Further reconstructions are required from the Southern Ocean in particular to enable greater understanding of how the temperature and sea ice varied during the Holocene. The OCTEL project (Ocean-sea-ice-atmosphere teleconnections between the Southern Ocean and North Atlantic during the Holocene) aims to investigate the ocean, atmosphere and sea-ice teleconnections for the Holocene using new, high resolution records from both the Southern Ocean and North Atlantic. We here present initial results from diatom analysis conducted on a sediment core from the Southern Ocean, sampled from the Conrad Rise (54˚ 16.04'S, 39˚ 45.98'W). The preliminary results highlight a dominance of diatom species Fragilariopsis kerguelensis and Thalassiosira lentiginosa, with lower abundances of Thalassiothrix antarctica and Thalassiosira gracilis among others, which suggests an open ocean setting close to the polar front. The diatom data will be converted to quantitative reconstructions of summer sea surface temperature and sea ice presence using the

  15. Mechanisms for SAR imaging of ocean surface phenomena: Theory and experiment

    Science.gov (United States)

    Vesecky, J. F.

    1983-01-01

    Understanding the SAR response to surface wave is a central issue in the analysis of SAR ocean images. The imaging mechanism for gravity waves and the practical question of just which characteristics of the ocean wave field can be measured remotely using SAR were examined. Assessments of wave imaging theory are based primarily on comparisons of the directional wave height variance spectrum psi (K) measured by in situ buoys with estimates from SAR images. Other criteria are also recommended, e.g., the effects of focus adjustments. It is assumed that fluctuations in SAR image intensity are proportional to fluctuations in ocean surface height. If this were true, the Fourier power spectrum of a SAR image and corresponding surface measurements of psi would coincide. Differences between SAR estimates based on this hypothesis and buoy measurements of psi are then used to begin the assessment of rival wave imaging theories.

  16. Out of Thin Air: Microbial Utilization of Atmospheric Gaseous Organics in the Surface Ocean

    KAUST Repository

    Arrieta, Jesus

    2016-01-20

    Volatile and semi-volatile gas-phase organic carbon (GOC) is a largely neglected component of the global carbon cycle, with poorly resolved pools and fluxes of natural and anthropogenic GOC in the biosphere. Substantial amounts of atmospheric GOC are exchanged with the surface ocean, and subsequent utilization of specific GOC compounds by surface ocean microbial communities has been demonstrated. Yet, the final fate of the bulk of the atmospheric GOC entering the surface ocean is unknown. Our data show experimental evidence of efficient use of atmospheric GOC by marine prokaryotes at different locations in the NE Subtropical Atlantic, the Arctic Ocean and the Mediterranean Sea. We estimate that between 2 and 27% of the prokaryotic carbon demand was supported by GOC with a major fraction of GOC inputs being consumed within the mixed layer. The role of the atmosphere as a key vector of organic carbon subsidizing marine microbial metabolism is a novel link yet to be incorporated into the microbial ecology of the surface ocean as well as into the global carbon budget.

  17. Spatial distributions of Southern Ocean mesozooplankton communities have been resilient to long-term surface warming.

    Science.gov (United States)

    Tarling, Geraint A; Ward, Peter; Thorpe, Sally E

    2018-01-01

    The biogeographic response of oceanic planktonic communities to climatic change has a large influence on the future stability of marine food webs and the functioning of global biogeochemical cycles. Temperature plays a pivotal role in determining the distribution of these communities and ocean warming has the potential to cause major distributional shifts, particularly in polar regions where the thermal envelope is narrow. We considered the impact of long-term ocean warming on the spatial distribution of Southern Ocean mesozooplankton communities through examining plankton abundance in relation to sea surface temperature between two distinct periods, separated by around 60 years. Analyses considered 16 dominant mesozooplankton taxa (in terms of biomass and abundance) in the southwest Atlantic sector of the Southern Ocean, from net samples and in situ temperature records collected during the Discovery Investigations (1926-1938) and contemporary campaigns (1996-2013). Sea surface temperature was found to have increased significantly by 0.74°C between the two eras. The corresponding sea surface temperature at which community abundance peaked was also significantly higher in contemporary times, by 0.98°C. Spatial projections indicated that the geographical location of community peak abundance had remained the same between the two eras despite the poleward advance of sea surface isotherms. If the community had remained within the same thermal envelope as in the 1920s-1930s, community peak abundance would be 500 km further south in the contemporary era. Studies in the northern hemisphere have found that dominant taxa, such as calanoid copepods, have conserved their thermal niches and tracked surface isotherms polewards. The fact that this has not occurred in the Southern Ocean suggests that other selective pressures, particularly food availability and the properties of underlying water masses, place greater constraints on spatial distributions in this region. It

  18. Multi-mission mean sea surface and geoid models for ocean monitoring within the GOCINA project

    Science.gov (United States)

    Andersen, O. B.; Knudsen, P.; Anne, V. L.

    2004-05-01

    A major goal of the EU project GOCINA (Geoid and Ocean Circulation In the North Atlantic) is to develop tools for ocean monitoring using satellite altimetry combined with satellite gravimetry. Furthermore, the project will determine an accurate geoid in the region between Greenland and the UK and, hereby, create a platform for validation of future GOCE Level 2 data and higher order scientific products. The central quantity bridging the geoid and the ocean circulation is the mean dynamic topography, which is the difference between the mean sea surface and the geoid. The mean dynamic topography provides the absolute reference surface for the ocean circulation. The improved determination of the mean circulation will advance the understanding of the role of the ocean mass and heat transport in climate change. To calculate the best possible synthetic mean dynamic topographies a new mean sea surface (KMS03) has been derived from nine years of altimetric data (1993-2001). The regional geoid has furthermore being updated using GRACE and gravimetric data from a recent airborne survey. New synthetic mean dynamic topography models have been computed from the best available geoid models (EGM96, GRACE, GOCINA) and the present mean sea surface models (i.e. CLS01, GSFC00, KMS03). These models will be compared with state of the art hydrodynamic mean dynamic topography models in the North Atlantic GOCINA area. An extended comparison in the Artic Ocean will also be presented to demonstrate the impact of improved geoid and mean sea surface modeling. Particularly using the GRACE derived geoid models, and the KMS03 mean sea surface.

  19. Soliton turbulence in shallow water ocean surface waves.

    Science.gov (United States)

    Costa, Andrea; Osborne, Alfred R; Resio, Donald T; Alessio, Silvia; Chrivì, Elisabetta; Saggese, Enrica; Bellomo, Katinka; Long, Chuck E

    2014-09-05

    We analyze shallow water wind waves in Currituck Sound, North Carolina and experimentally confirm, for the first time, the presence of soliton turbulence in ocean waves. Soliton turbulence is an exotic form of nonlinear wave motion where low frequency energy may also be viewed as a dense soliton gas, described theoretically by the soliton limit of the Korteweg-deVries equation, a completely integrable soliton system: Hence the phrase "soliton turbulence" is synonymous with "integrable soliton turbulence." For periodic-quasiperiodic boundary conditions the ergodic solutions of Korteweg-deVries are exactly solvable by finite gap theory (FGT), the basis of our data analysis. We find that large amplitude measured wave trains near the energetic peak of a storm have low frequency power spectra that behave as ∼ω-1. We use the linear Fourier transform to estimate this power law from the power spectrum and to filter densely packed soliton wave trains from the data. We apply FGT to determine the soliton spectrum and find that the low frequency ∼ω-1 region is soliton dominated. The solitons have random FGT phases, a soliton random phase approximation, which supports our interpretation of the data as soliton turbulence. From the probability density of the solitons we are able to demonstrate that the solitons are dense in time and highly non-Gaussian.

  20. Oceanic whitecaps: Sea surface features detectable via satellite that ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    Andreas et al (1995), and figure 1 of Monahan and Spillane (1984). et al (1995) made detailed measurements in a large wave basin of the increases in brightness tempera- ture associated with measured increases in stage A whitecap coverage. It follows that the fraction of the sea surface covered by stage A whitecaps can ...

  1. A role of the Atlantic Ocean in predicting summer surface air temperature over North East Asia?

    Science.gov (United States)

    Monerie, Paul-Arthur; Robson, Jon; Dong, Buwen; Dunstone, Nick

    2017-10-01

    We assess the ability of the DePreSys3 prediction system to predict the summer (JJAS) surface-air temperature over North East Asia. DePreSys3 is based on a high resolution ocean-atmosphere coupled climate prediction system ( 60 km in the atmosphere and 25 km in the ocean), which is full-field initialized from 1960 to 2014 (26 start-dates). We find skill in predicting surface-air temperature, relative to a long-term trend, for 1 and 2-5 year lead-times over North East Asia, the North Atlantic Ocean and Eastern Europe. DePreSys3 also reproduces the interdecadal evolution of surface-air temperature over the North Atlantic subpolar gyre and North East Asia for both lead times, along with the strong warming that occurred in the mid-1990s over both areas. Composite analysis reveals that the skill at capturing interdecadal changes in North East Asia is associated with the propagation of an atmospheric Rossby wave, which follows the subtropical jet and modulates surface-air temperature from Europe to Eastern Asia. We hypothesise that this `circumglobal teleconnection' pattern is excited over the Atlantic Ocean and is related to Atlantic multi-decadal variability and the associated changes in precipitation over the Sahel and the subtropical Atlantic Ocean. This mechanism is robust for the 2-5 year lead-time. For the 1 year lead-time the Pacific Ocean also plays an important role in leading to skill in predicting SAT over Northeast Asia. Increased temperatures and precipitation over the western Pacific Ocean was found to be associated with a Pacific-Japan like-pattern, which can affect East Asia's climate.

  2. Ocean acidification impact on growth and the pH dependence of trace elements in skeleton of juvenile corals (Acropora digitifera)

    Science.gov (United States)

    Inoue, M.; Suwa, R.; Iguchi, A.; Suzuki, A.; Sakai, K.; Kawahata, H.

    2010-12-01

    The impact of ocean acidification caused by the increasing global concentration of atmospheric CO2 has been studied in marine calcifiers, including hermatypic corals, in which calcification is expected to decrease significantly. However, the effect of elevated pCO2 on the early developmental stage of the coral life cycle has been little studied, even though corals at this stage seem to be susceptible to stresses including ocean acidification. In this study, we reared polyps of Acropora digitifera, one of the dominant species around the Ryukyu Islands, Japan, in seawater of various pH (6.55, 7.31, 7.64, 7.77, 8.03), controlled by CO2 bubbling. We measured the dry weight of the polyp skeletons after the 40 days experiment to investigate the relationship between the aragonite saturation state and polyp growth. In addition, we measured the Mg/Ca, Sr/Ca, Ba/Ca, and U/Ca ratios of their skeletons to estimate the pH dependence of these ratios. Although skeletons of polyps reared at pH 6.55 dissolved during the experiment after settlement, the other skeletal weight of coral polyps increased with the aragonite saturation state. Then, skeletal weight apparently reached a saturation plateau above pH 7.77, a finding in agreement with previous results for adult corals. Ba/Ca and U/Ca were significantly related to pH, whereas Sr/Ca showed a moderate positive correlation with pH. On the other hand, there was no clear relationship between Mg/Ca and pH. Although both the Ba/Ca and U/Ca ratios showed a strong dependency on pH, coral Ba/Ca is reported to be affected by multiple factors such as terrestrial runoff and upwelling. But, U/Ca ratios have been reported a relatively simple dependency on temperature. Therefore, coral U/Ca may have a potential for pH proxy.

  3. Influence of Soft Drinks with Low pH on Different Ni-Ti Orthodontic Archwire Surface Patterns

    Science.gov (United States)

    Abalos, C.; Paul, A.; Mendoza, A.; Solano, E.; Palazon, C.; Gil, F. J.

    2013-03-01

    The aim of this study was to determine the influence of soft drinks on the surface of Ni-Ti archwires and their corrosion behavior. Archwires with different patterns (smooth, scratch, dimple, and crack) were selected and characterized by scanning electron microscopy and laser confocal microscopy. Immersion tests were performed in artificial saliva (pH 6.7) with a soft drink with a pH of 2.5 for 28 days. The results showed an increase in the surface defects and/or roughness of the dimple, crack and scratch patterns with the immersion times, and a decrease in corrosion resistance. A relationship between the surface pattern and the extent of the corrosion in Ni-Ti archwires with soft drinks at low pH has been demonstrated. Pattern should be taken into account in future studies, and manufacturing processes that produce surface defects (especially cracks) should be avoided.

  4. Binding of chloroquine to ionic micelles: Effect of pH and micellar surface charge

    Energy Technology Data Exchange (ETDEWEB)

    Souza Santos, Marcela de, E-mail: marcelafarmausp77@gmail.com [Departamento de Física e Química, Faculdade de Ciências Farmacêuticas de Ribeirão Preto, Universidade de São Paulo, Avenida do Café, s/n, Ribeirão Preto, São Paulo 14040-903 (Brazil); Perpétua Freire de Morais Del Lama, Maria, E-mail: mpemdel@fcfrp.usp.br [Departamento de Física e Química, Faculdade de Ciências Farmacêuticas de Ribeirão Preto, Universidade de São Paulo, Avenida do Café, s/n, Ribeirão Preto, São Paulo 14040-903 (Brazil); Instituto Nacional de Ciência e Tecnologia de Bioanalítica, Departamento de Química Analítica, Universidade Estadual de Campinas, Cidade Universitária Zeferino Vaz, s/n, Campinas, São Paulo 13083-970 (Brazil); Siuiti Ito, Amando, E-mail: amandosi@ffclrp.usp.br [Departamento de Física, Faculdade de Filosofia, Ciências e Letras de Ribeirão Preto, Universidade de São Paulo, Avenida Bandeirantes, 3900, Ribeirão Preto, São Paulo 14040-901 (Brazil); and others

    2014-03-15

    The pharmacological action of chloroquine relies on its ability to cross biological membranes in order to accumulate inside lysosomes. The present work aimed at understanding the basis for the interaction between different chloroquine species and ionic micelles of opposite charges, the latter used as a simple membrane model. The sensitivity of absorbance and fluorescence of chloroquine to changes in its local environment was used to probe its interaction with cetyltrimethylammonium micelles presenting bromide (CTAB) and sulfate (CTAS) as counterions, in addition to dodecyl sulfate micelles bearing sodium (SDS) and tetramethylammonium (TMADS) counterions. Counterion exchange was shown to have little effect on drug–micelle interaction. Chloroquine first dissociation constant (pKa{sub 1}) shifted to opposite directions when anionic and cationic micelles were compared. Chloroquine binding constants (K{sub b}) revealed that electrostatic forces mediate charged drug–micelle association, whereas hydrophobic interactions allowed neutral chloroquine to associate with anionic and cationic micelles. Fluorescence quenching studies indicated that monoprotonated chloroquine is inserted deeper into the micelle surface of anionic micelles than its neutral form, the latter being less exposed to the aqueous phase when associated with cationic over anionic assemblies. The findings provide further evidence that chloroquine–micelle interaction is driven by a tight interplay between the drug form and the micellar surface charge, which can have a major effect on the drug biological activity. -- Highlights: • Chloroquine (CQ) pKa{sub 1} increased for SDS micelles and decreased for CTAB micelles. • CQ is solubilized to the surface of both CTAB and SDS micelles. • Monoprotonated CQ is buried deeper into SDS micelles than neutral CQ. • Neutral CQ is less exposed to aqueous phase in CTAB over SDS micelles. • Local pH and micellar surface charge mediate interaction of CQ with

  5. Baseline monitoring of the western Arctic Ocean estimates 20% of the Canadian Basin surface waters are undersaturated with respect to aragonite

    Science.gov (United States)

    Robbins, Lisa L.; Wynn, Jonathan G.; Lisle, John T.; Yates, Kimberly K.; Knorr, Paul O.; Byrne, Robert H.; Liu, Xuewu; Patsavas, Mark C.; Azetsu-Scott, Kumiko; Takahashi, Taro

    2013-01-01

    Marine surface waters are being acidified due to uptake of anthropogenic carbon dioxide, resulting in surface ocean areas of undersaturation with respect to carbonate minerals, including aragonite. In the Arctic Ocean, acidification is expected to occur at an accelerated rate with respect to the global oceans, but a paucity of baseline data has limited our understanding of the extent of Arctic undersaturation and of regional variations in rates and causes. The lack of data has also hindered refinement of models aimed at projecting future trends of ocean acidification. Here, based on more than 34,000 data records collected in 2010 and 2011, we establish a baseline of inorganic carbon data (pH, total alkalinity, dissolved inorganic carbon, partial pressure of carbon dioxide, and aragonite saturation index) for the western Arctic Ocean. This data set documents aragonite undersaturation in ~20% of the surface waters of the combined Canada and Makarov basins, an area characterized by recent acceleration of sea ice loss. Conservative tracer studies using stable oxygen isotopic data from 307 sites show that while the entire surface of this area receives abundant freshwater from meteoric sources, freshwater from sea ice melt is most closely linked to the areas of carbonate mineral undersaturation. These data link the Arctic Ocean’s largest area of aragonite undersaturation to sea ice melt and atmospheric CO2 absorption in areas of low buffering capacity. Some relatively supersaturated areas can be linked to localized biological activity. Collectively, these observations can be used to project trends of ocean acidification in higher latitude marine surface waters where inorganic carbon chemistry is largely influenced by sea ice meltwater.

  6. Distinct global warming rates tied to multiple ocean surface temperature changes

    Science.gov (United States)

    Yao, Shuai-Lei; Luo, Jing-Jia; Huang, Gang; Wang, Pengfei

    2017-07-01

    The globally averaged surface temperature has shown distinct multi-decadal fluctuations since 1900, characterized by two weak slowdowns in the mid-twentieth century and early twenty-first century and two strong accelerations in the early and late twentieth century. While the recent global warming (GW) hiatus has been particularly ascribed to the eastern Pacific cooling, causes of the cooling in the mid-twentieth century and distinct intensity differences between the slowdowns and accelerations remain unclear. Here, our model experiments with multiple ocean sea surface temperature (SST) forcing reveal that, although the Pacific SSTs play essential roles in the GW rates, SST changes in other basins also exert vital influences. The mid-twentieth-century cooling results from the SST cooling in the tropical Pacific and Atlantic, which is partly offset by the Southern Ocean warming. During the recent hiatus, the tropical Pacific-induced strong cooling is largely compensated by warming effects of other oceans. In contrast, during the acceleration periods, ubiquitous SST warming across all the oceans acts jointly to exaggerate the GW. Multi-model simulations with separated radiative forcing suggest diverse causes of the SST changes in multiple oceans during the GW acceleration and slowdown periods. Our results highlight the importance of multiple oceans on the multi-decadal GW rates.

  7. Spiraling pathways of global deep waters to the surface of the Southern Ocean.

    Science.gov (United States)

    Tamsitt, Veronica; Drake, Henri F; Morrison, Adele K; Talley, Lynne D; Dufour, Carolina O; Gray, Alison R; Griffies, Stephen M; Mazloff, Matthew R; Sarmiento, Jorge L; Wang, Jinbo; Weijer, Wilbert

    2017-08-02

    Upwelling of global deep waters to the sea surface in the Southern Ocean closes the global overturning circulation and is fundamentally important for oceanic uptake of carbon and heat, nutrient resupply for sustaining oceanic biological production, and the melt rate of ice shelves. However, the exact pathways and role of topography in Southern Ocean upwelling remain largely unknown. Here we show detailed upwelling pathways in three dimensions, using hydrographic observations and particle tracking in high-resolution models. The analysis reveals that the northern-sourced deep waters enter the Antarctic Circumpolar Current via southward flow along the boundaries of the three ocean basins, before spiraling southeastward and upward through the Antarctic Circumpolar Current. Upwelling is greatly enhanced at five major topographic features, associated with vigorous mesoscale eddy activity. Deep water reaches the upper ocean predominantly south of the Antarctic Circumpolar Current, with a spatially nonuniform distribution. The timescale for half of the deep water to upwell from 30° S to the mixed layer is ~60-90 years.Deep waters of the Atlantic, Pacific and Indian Oceans upwell in the Southern Oceanbut the exact pathways are not fully characterized. Here the authors present a three dimensional view showing a spiralling southward path, with enhanced upwelling by eddy-transport at topographic hotspots.

  8. Ocean surface waves and winds over the north Indian Ocean from satellite altimeter - preliminary results of SAC-NIO joint project

    Digital Repository Service at National Institute of Oceanography (India)

    Sarkar, A.; Rajkumar, R.; Gairola, R.M.; Gohil, B.S.; Vethamony, P.; Rao, L.V.G.

    With the aim of retrieving, validating and mapping ocean surface winds and waves in the north Indian Ocean, GEOSAT altimeter data for the period November 1986 to October 1987 and available sea truth data for the above period were processed in SAC...

  9. Determination of optimum pH and temperature for pasteurization of citrus juices by response surface methodology.

    Science.gov (United States)

    Ulgen, N; Ozilgen, M

    1993-01-01

    Optimization of microbial death, enzyme inactivation and vitamin C retention during pasteurization of pH-adjusted orange juice is discussed free of equipment-dependent parameters such as the heating lag. The pH-temperature optimum was determined by response surface methodology in the range of 65 degrees C-75 degrees C and pH 2.5-4.0. The results implied that there was no pectinesterase activity below pH 3.5. Leuconostoc mesenteroides had its maximum and minimum thermal resistance at pH 3.5 and pH 2.7, respectively. For an ideal theoretical process requiring four log cycles of microbial reduction the optimum pasteurization conditions were 12 min at 75 degrees C and pH 2.7.

  10. SWOT: The Surface Water and Ocean Topography Mission. Wide- Swath Altimetric Elevation on Earth

    Science.gov (United States)

    Fu, Lee-Lueng (Editor); Alsdorf, Douglas (Editor); Morrow, Rosemary; Rodriguez, Ernesto; Mognard, Nelly

    2012-01-01

    The elevation of the surface of the ocean and freshwater bodies on land holds key information on many important processes of the Earth System. The elevation of the ocean surface, called ocean surface topography, has been measured by conventional nadirlooking radar altimeter for the past two decades. The data collected have been used for the study of large-scale circulation and sea level change. However, the spatial resolution of the observations has limited the study to scales larger than about 200 km, leaving the smaller scales containing substantial kinetic energy of ocean circulation that is responsible for the flux of heat, dissolved gas and nutrients between the upper and the deep ocean. This flux is important to the understanding of the ocean's role in regulatingfuture climate change.The elevation of the water bodies on land is a key parameter required for the computation of storage and discharge of freshwater in rivers, lakes, and wetlands. Globally, the spatial and temporal variability of water storage and discharge is poorly known due to the lack of well-sampled observations. In situ networks measuring river flows are declining worldwide due to economic and political reasons. Conventional altimeter observations suffers from the complexity of multiple peaks caused by the reflections from water, vegetation canopy and rough topography, resulting in much less valid data over land than over the ocean. Another major limitation is the large inter track distance preventing good coverage of rivers and other water bodies.This document provides descriptions of a new measurement technique using radar interferometry to obtain wide-swath measurement of water elevation at high resolution over both the ocean and land. Making this type of measurement, which addresses the shortcomings of conventional altimetry in both oceanographic and hydrologic applications, is the objective of a mission concept called Surface Water and Ocean Topography (SWOT), which was recommended by

  11. Ocean surface waves in Hurricane Ike (2008) and Superstorm Sandy (2012): Coupled model predictions and observations

    Science.gov (United States)

    Chen, Shuyi S.; Curcic, Milan

    2016-07-01

    Forecasting hurricane impacts of extreme winds and flooding requires accurate prediction of hurricane structure and storm-induced ocean surface waves days in advance. The waves are complex, especially near landfall when the hurricane winds and water depth varies significantly and the surface waves refract, shoal and dissipate. In this study, we examine the spatial structure, magnitude, and directional spectrum of hurricane-induced ocean waves using a high resolution, fully coupled atmosphere-wave-ocean model and observations. The coupled model predictions of ocean surface waves in Hurricane Ike (2008) over the Gulf of Mexico and Superstorm Sandy (2012) in the northeastern Atlantic and coastal region are evaluated with the NDBC buoy and satellite altimeter observations. Although there are characteristics that are general to ocean waves in both hurricanes as documented in previous studies, wave fields in Ike and Sandy possess unique properties due mostly to the distinct wind fields and coastal bathymetry in the two storms. Several processes are found to significantly modulate hurricane surface waves near landfall. First, the phase speed and group velocities decrease as the waves become shorter and steeper in shallow water, effectively increasing surface roughness and wind stress. Second, the bottom-induced refraction acts to turn the waves toward the coast, increasing the misalignment between the wind and waves. Third, as the hurricane translates over land, the left side of the storm center is characterized by offshore winds over very short fetch, which opposes incoming swell. Landfalling hurricanes produce broader wave spectra overall than that of the open ocean. The front-left quadrant is most complex, where the combination of windsea, swell propagating against the wind, increasing wind-wave stress, and interaction with the coastal topography requires a fully coupled model to meet these challenges in hurricane wave and surge prediction.

  12. The Ocean's Vital Skin: Toward an Integrated Understanding of the Sea Surface Microlayer

    Energy Technology Data Exchange (ETDEWEB)

    Engel, Anja; Bange, Hermann W.; Cunliffe, Michael; Burrows, Susannah M.; Friedrichs, Gernot; Galgani, Luisa; Herrmann, Hartmut; Hertkorn, Norbert; Johnson, Martin; Liss, Peter S.; Quinn, Patricia K.; Schartau, Markus; Soloviev, Alexander; Stolle, Christian; Upstill-Goddard, Robert C.; van Pinxteren, Manuela; Zäncker, Birthe

    2017-05-30

    Despite the huge extent of the ocean’s surface, until now relatively little attention has been paid to the sea surface microlayer (SML) as the ultimate interface where heat, momentum and mass exchange between the ocean and the atmosphere takes place. Via the SML, large-scale environmental changes in the ocean such as warming, acidification, deoxygenation, and eutrophication potentially influence cloud formation, precipitation, and the global radiation balance. Due to the deep connectivity between biological, chemical, and physical processes, studies of the SML may reveal multiple sensitivities to global and regional changes. Understanding the processes at the ocean’s surface, in particular involving the SML as an important and determinant interface, could therefore provide an essential contribution to the reduction of uncertainties regarding ocean-climate feedbacks. This review identifies gaps in our current knowledge of the SML and highlights a need to develop a holistic and mechanistic understanding of the diverse biological, chemical, and physical processes occurring at the ocean-atmosphere interface. We advocate the development of strong interdisciplinary expertise and collaboration in order to bridge between ocean and atmospheric sciences. Although this will pose significant methodological challenges, such an initiative would represent a new role model for interdisciplinary research in Earth System sciences.

  13. Mechanisms for Seasonal and Interannual Sea Surface Salinity Variability in the Indian Ocean

    Science.gov (United States)

    Köhler, J.; Stammer, D.; Serra, N.; Bryan, F.

    2016-12-01

    Space-borne salinity data in the Indian Ocean are analyzed over the period 2000-2015 based on data from the European Space Agency's (ESA) "Soil Moisture and Ocean Salinity" (SMOS) and the National Aeronautical Space Agency's (NASA) "Aquarius/SAC-D" missions. The seasonal variability is the dominant mode of sea surface salinity (SSS) variability in the Indian Ocean, accounting for more than 50% of salinity variance. Through a combined analysis of the satellite and ARGO data, dominant forcing terms for seasonal salinity changes are identified. It is found, that E-P controls seasonal salinity tendency in the western Indian Ocean, where the ITCZ has a strong seasonal cycle. In contrast, Ekman advection is the dominant term in the northern and eastern equatorial Indian Ocean. The influence of vertical processes on the salinity tendency is enhanced in coastal upwelling regions and south of the equator due to mid-ocean upwelling. Jointly those processes can explain most of the observed seasonal cycle with a correlation of 0.85 and an RMS difference of 0.07/month. However, the detailed composition of driving terms depends on underlying data products. In general, our study confirms previous results from Lisan Yu (2011); however, in the eastern Indian Ocean contrasting results indicate the leading role of meridional Ekman advection to the seasonal salinity tendency instead of surface external forces due to precipitation. The inferred dominant salinity budget terms are confirmed by results obtained from a high resolution NCAR Core model run driven by NCEP forcing fields. From an EOF analysis of the salinity fields after substracting the annual and semiannual cycle we found that the first EOF mode explains more than 20% of salinity variance. The first principal component of SSS EOF is correlated with the Indian Ocean Dipole Mode Index. Nevertheless the EOF pattern shows a meridional tripole structure, while the IOD describes a zonal SST dipole (Saji et al, 1999).

  14. Impulse exchange at the surface of the ocean and the fractal dimension of drifter trajectories

    Directory of Open Access Journals (Sweden)

    D. M. Summers

    2002-01-01

    Full Text Available An impulse-based model is developed to represent a coupling between turbulent flow in the atmosphere and turbulent flow in the ocean. In particular, it is argued that the atmosphere flowing horizontally over the ocean surface generates a velocity fluctuation field in the latter's near-surface flow. The mechanism for this can be understood kinematically in terms of an exchange of tangentially-oriented fluid impulse at the air-sea interface. We represent this exchange numerically through the creation of Lagrangian elements of impulse density. An indication of the efficacy of such a model would lie in its ability to predict the observed fractal dimension of lateral trajectories of submerged floats set adrift in the ocean. To this end, we examine the geometry of lateral tracer-paths determined from the present model.

  15. Climate change in the sea: the implications of increasing the carbon dioxide inputs to the surface ocean

    Energy Technology Data Exchange (ETDEWEB)

    Pfister, Cathy [University of Chicago

    2012-12-23

    The oceans are estimated to be absorbing one-third of the fossil fuel carbon released into the atmosphere, a process that is expected to change ocean carbon chemistry. I will present data from the Washington coast showing ocean pH declines and changes to the shell chemistry of bivalves. I will discuss implications of carbon cycle changes for marine species, including insights from a coastal area where I have worked for more than 24 years. I will summarize what we know to date about this process of “ocean acidification”.

  16. Decadal variability of the Tropical Atlantic Ocean Surface Temperature in shipboard measurements and in a Global Ocean-Atmosphere model

    Science.gov (United States)

    Mehta, Vikram M.; Delworth, Thomas

    1995-01-01

    Sea surface temperature (SST) variability was investigated in a 200-yr integration of a global model of the coupled oceanic and atmospheric general circulations developed at the Geophysical Fluid Dynamics Laboratory (GFDL). The second 100 yr of SST in the coupled model's tropical Atlantic region were analyzed with a variety of techniques. Analyses of SST time series, averaged over approximately the same subregions as the Global Ocean Surface Temperature Atlas (GOSTA) time series, showed that the GFDL SST anomalies also undergo pronounced quasi-oscillatory decadal and multidecadal variability but at somewhat shorter timescales than the GOSTA SST anomalies. Further analyses of the horizontal structures of the decadal timescale variability in the GFDL coupled model showed the existence of two types of variability in general agreement with results of the GOSTA SST time series analyses. One type, characterized by timescales between 8 and 11 yr, has high spatial coherence within each hemisphere but not between the two hemispheres of the tropical Atlantic. A second type, characterized by timescales between 12 and 20 yr, has high spatial coherence between the two hemispheres. The second type of variability is considerably weaker than the first. As in the GOSTA time series, the multidecadal variability in the GFDL SST time series has approximately opposite phases between the tropical North and South Atlantic Oceans. Empirical orthogonal function analyses of the tropical Atlantic SST anomalies revealed a north-south bipolar pattern as the dominant pattern of decadal variability. It is suggested that the bipolar pattern can be interpreted as decadal variability of the interhemispheric gradient of SST anomalies. The decadal and multidecadal timescale variability of the tropical Atlantic SST, both in the actual and in the GFDL model, stands out significantly above the background 'red noise' and is coherent within each of the time series, suggesting that specific sets of

  17. Measurements of Surface Ocean Carbon Dioxide Partial Pressure During WOCE; FINAL

    International Nuclear Information System (INIS)

    Weiss, R.F.

    1998-01-01

    All of the technical goals of the World Ocean Circulation Experiment (WOCE) field program which were supported under the Department of Energy research grant ''Measurements of Surface Ocean Carbon Dioxide Partial Pressure During WOCE'' (DE-FG03-90ER60981) have been met. This has included the measurement of the partial pressures of carbon dioxide (C0(sub 2)) and nitrous oxide (N(sub 2)O) in both the surface ocean and the atmosphere on 24 separate shipboard expedition legs of the WOCE Hydrographic Programme. These measurements were made in the Pacific, Indian and Atlantic Oceans over a six-and-a-half year period, and over a distance of nearly 200,000 kilometers of ship track. The total number of measurements, including ocean measurements, air measurements and standard gas measurements, is about 136,000 for each gas, or about 34,000 measurements of each gas in the ocean and in the air. This global survey effort is directed at obtaining a better understanding of the role of the oceans in th e global atmospheric budgets of two important natural and anthropogenic modulators of climate through the ''greenhouse effect'', CO(sub 2) and N(sub 2)O, and an important natural and anthropogenic modulator of the Earth's protective ozone layer through catalytic processes in the stratosphere, N(sub 2)O. For both of these compounds, the oceans play a major role in their global budgets. In the case of CO(sub 2), roughly half of the anthropogenic production through the combustion of fossil fuels has been absorbed by the world's oceans. In the case of N(sub 2)O, roughly a third of the natural flux to the atmosphere originates in the oceans. As the interpretation of the variability in the oceanic distributions of these compounds improves, measurements such as those supported by this research project are playing an increasingly important role in improving our understanding of natural and anthropogenic influences on climate and ozone

  18. Satellite surface salinity maps to determine fresh water fluxes in the Arctic Ocean

    Science.gov (United States)

    Gabarro, Carolina; Estrella, Olmedo; Emelianov, Mikhail; Ballabrera, Joaquim; Turiel, Antonio

    2017-04-01

    Salinity and temperature gradients drive the thermohaline circulation of the oceans, and play a key role in the ocean-atmosphere coupling. The strong and direct interactions between the ocean and the cryosphere (primarily through sea ice and ice shelves) are also a key ingredient of the thermohaline circulation. Recent observational studies have documented changes in upper Arctic Ocean hydrography [1, 2]. The ESA's Soil Moisture and Ocean Salinity (SMOS) mission, launched in 2009, have the objective to measure soil moisture over the continents and sea surface salinity over the oceans [3]. However, SMOS is also making inroads in Cryospheric science, as the measurements of thin ice thickness and sea ice concentration. SMOS carries an innovative L-band (1.4 GHz, or 21-cm wavelength), passive interferometric radiometer (the so-called MIRAS) that measures the electromagnetic radiation emitted by the Earth's surface, at about 50 km spatial resolution wide swath (1200-km), and with a 3-day revisit time at the equator, but more frequently at the poles. Although the SMOS radiometer operating frequency offers almost the maximum sensitivity of the brightness temperature (TB) to sea surface salinity (SSS) variations, such sensitivity is rather low, even lower at cold waters [4]: 90% of ocean SSS values span a range of brightness temperatures of just 5K. This implies that the SMOS SSS retrieval requires a high performance of the MIRAS interferometric radiometer [5]. New algorithms, recently developed at the Barcelona Expert Center (BEC) to improve the quality of SMOS measurements [6], allow for the first time to derive cold-water SSS maps from SMOS data, and to observe the variability of the SSS in the higher north Atlantic and the Arctic Ocean. In this work, we will provide an assessment of the quality of these new SSS Arctic maps, and we will illustrate their potential to monitor the impact on ocean state of the discharges from the main rivers to the Arctic Ocean. Moreover

  19. Impacts of climate changes on ocean surface gravity waves over the eastern Canadian shelf

    Science.gov (United States)

    Guo, Lanli; Sheng, Jinyu

    2017-05-01

    A numerical study is conducted to investigate the impact of climate changes on ocean surface gravity waves over the eastern Canadian shelf (ECS). The "business-as-usual" climate scenario known as Representative Concentration Pathway RCP8.5 is considered in this study. Changes in the ocean surface gravity waves over the study region for the period 1979-2100 are examined based on 3 hourly ocean waves simulated by the third-generation ocean wave model known as WAVEWATCHIII. The wave model is driven by surface winds and ice conditions produced by the Canadian Regional Climate Model (CanRCM4). The whole study period is divided into the present (1979-2008), near future (2021-2050) and far future (2071-2100) periods to quantify possible future changes of ocean waves over the ECS. In comparison with the present ocean wave conditions, the time-mean significant wave heights ( H s ) are expected to increase over most of the ECS in the near future and decrease over this region in the far future period. The time-means of the annual 5% largest H s are projected to increase over the ECS in both near and far future periods due mainly to the changes in surface winds. The future changes in the time-means of the annual 5% largest H s and 10-m wind speeds are projected to be twice as strong as the changes in annual means. An analysis of inverse wave ages suggests that the occurrence of wind seas is projected to increase over the southern Labrador and central Newfoundland Shelves in the near future period, and occurrence of swells is projected to increase over other areas of the ECS in both the near and far future periods.

  20. Operational use of ocean surface drifters for tracking spilled oil

    International Nuclear Information System (INIS)

    Aamo, O. M.; Jensen, H.

    1997-01-01

    The use of Argos-positioned surface drifters by Norwegian engineers to monitor oil slicks in the North Sea was discussed. The system that was tested in June 1996 during the Norwegian Clean Seas Association oil-on-water exercise consisted of several GPS-positioned Argos drift trackers, an Argos receiver, a GPS navigator for the ship's position, and a PC with software for logging and displaying positions. Results of the field trial have been positive in that the system worked as expected. The range of direct transmission of signals from the buoys to the ship was about three nautical miles. The degree of accuracy of the relative positioning between the buoy GPS and the ship-borne GPS navigator was similar to the absolute positioning of single buoys. For best results, a minimum of two buoys and the use of lithium cells to increase battery capacity, were recommended. 3 refs., 5 figs

  1. Low reservoir ages for the surface ocean from mid-Holocene Florida corals

    Science.gov (United States)

    Druffel, E.R.M.; Robinson, L.F.; Griffin, S.; Halley, R.B.; Southon, J.R.; Adkins, J.F.

    2008-01-01

    The 14C reservoir age of the surface ocean was determined for two Holocene periods (4908-4955 and 3008-3066 calendar (cal) B.P.) using U/Th-dated corals from Biscayne National Park, Florida, United States. We found that the average reservoir ages for these two time periods (294 ?? 33 and 291 ?? 27 years, respectively) were lower than the average value between A.D. 1600 and 1900 (390 ?? 60 years) from corals. It appears that the surface ocean was closer to isotopic equilibrium with CO2 in the atmosphere during these two time periods than it was during recent times. Seasonal ??18O measurements from the younger coral are similar to modern values, suggesting that mixing with open ocean waters was indeed occurring during this coral's lifetime. Likely explanations for the lower reservoir age include increased stratification of the surface ocean or increased ??14C values of subsurface waters that mix into the surface. Our results imply that a more correct reservoir age correction for radiocarbon measurements of marine samples in this location from the time periods ???3040 and ???4930 cal years B.P. is ???292 ?? 30 years, less than the canonical value of 404 ?? 20 years. Copyright 2008 by the American Geophysical Union.

  2. Photo-oxidation : Major sink of oxygen in the ocean surface layer

    NARCIS (Netherlands)

    Gieskes, W. W. C.; Laane, R. W. P. M.; Ruardij, P.

    2015-01-01

    Evidence is presented that the oxygen demand associated with photochemical processes in the surface layer of oceans and seas worldwide is of the same order of magnitude as the amount of oxygen released by photosynthesis of the world's marine phytoplankton. Both estimates are of necessity quite rough

  3. Photo-oxidation: Major sink of oxygen in the ocean surface layer

    NARCIS (Netherlands)

    Gieskes, W.W.C.; Laane, R.W.P.M.; Ruardij, P.

    2015-01-01

    Evidence is presented that the oxygen demand associated with photochemical processes in the surface layer of oceans and seas worldwide is of the same order of magnitude as the amount of oxygen released by photosynthesis of the world's marine phytoplankton. Both estimates are of necessity quite rough

  4. The warmer the ocean surface, the shallower the mixed layer. How much of this is true?

    Science.gov (United States)

    Somavilla, R; González-Pola, C; Fernández-Diaz, J

    2017-09-01

    Ocean surface warming is commonly associated with a more stratified, less productive, and less oxygenated ocean. Such an assertion is mainly based on consistent projections of increased near-surface stratification and shallower mixed layers under global warming scenarios. However, while the observed sea surface temperature (SST) is rising at midlatitudes, the concurrent ocean record shows that stratification is not unequivocally increasing nor is MLD shoaling. We find that while SST increases at three study areas at midlatitudes, stratification both increases and decreases, and MLD deepens with enhanced deepening of winter MLDs at rates over 10 m  decade-1. These results rely on the estimation of several MLD and stratification indexes of different complexity on hydrographic profiles from long-term hydrographic time-series, ocean reanalysis, and Argo floats. Combining this information with estimated MLDs from buoyancy fluxes and the enhanced deepening/attenuation of the winter MLD trends due to changes in the Ekman pumping, MLD variability involves a subtle interplay between circulation and atmospheric forcing at midlatitudes. Besides, it is highlighted that the density difference between the surface and 200 m, the most widely used stratification index, should not be expected to reliably inform about changes in the vertical extent of mixing.

  5. Probing Earth’s conductivity structure beneath oceans by scalar geomagnetic data: autonomous surface vehicle solution

    DEFF Research Database (Denmark)

    Kuvshinov, Alexey; Matzka, Jürgen; Poedjono, Benny

    2016-01-01

    to the conductivity structure beneath the ocean. We conclude that the sensitivity, depending on the bathymetry gradient, is typically largest near the coast offshore. We show that such sea-surface marine induction surveys can be performed with the Wave Glider, an easy-to-deploy, autonomous, energy-harvesting floating...

  6. Surface temperature of the equatorial Pacific Ocean and the Indian rainfall

    Digital Repository Service at National Institute of Oceanography (India)

    Gopinathan, C.K.

    The time variation of the monthly mean surface temperature of the equatorial Pacific Ocean during 1982-1987 has been studied in relation to summer monsoon rainfall over India The ENSO events of 1982 and 1987 were related to a significant reduction...

  7. The warmer the ocean surface, the shallower the mixed layer. How much of this is true?

    Science.gov (United States)

    Somavilla, R.; González-Pola, C.; Fernández-Diaz, J.

    2017-09-01

    Ocean surface warming is commonly associated with a more stratified, less productive, and less oxygenated ocean. Such an assertion is mainly based on consistent projections of increased near-surface stratification and shallower mixed layers under global warming scenarios. However, while the observed sea surface temperature (SST) is rising at midlatitudes, the concurrent ocean record shows that stratification is not unequivocally increasing nor is MLD shoaling. We find that while SST increases at three study areas at midlatitudes, stratification both increases and decreases, and MLD deepens with enhanced deepening of winter MLDs at rates over 10 m decade-1. These results rely on the estimation of several MLD and stratification indexes of different complexity on hydrographic profiles from long-term hydrographic time-series, ocean reanalysis, and Argo floats. Combining this information with estimated MLDs from buoyancy fluxes and the enhanced deepening/attenuation of the winter MLD trends due to changes in the Ekman pumping, MLD variability involves a subtle interplay between circulation and atmospheric forcing at midlatitudes. Besides, it is highlighted that the density difference between the surface and 200 m, the most widely used stratification index, should not be expected to reliably inform about changes in the vertical extent of mixing.

  8. Occurrence, distribution and environmental risk of pharmaceutically active compounds (PhACs) in coastal and ocean waters from the Gulf of Cadiz (SW Spain).

    Science.gov (United States)

    Biel-Maeso, Miriam; Baena-Nogueras, Rosa María; Corada-Fernández, Carmen; Lara-Martín, Pablo A

    2018-01-15

    In this study, we have evaluated the occurrence and distribution of 78 pharmaceuticals in different aquatic marine environments from the Gulf of Cadiz (SW Spain) for the first time. The obtained results revealed that pharmaceuticals were present in seawater at total concentrations ranging 61-2133 and 16-189ngL -1 in coastal and oceanic transects, respectively. Potential marine pollution hotspots were observed in enclosed or semi-enclosed water bodies (Cadiz Bay), showing concentrations that were one or two orders of magnitude higher than in the open ocean. The presence of these chemicals in local sewage treatment plants (STPs), one of the main contamination sources, was also assessed, revealing total concentrations of up to 23μgL -1 in effluents. PhACs with the highest detection frequencies and concentrations in the sampling region were analgesics and anti-inflammatories followed by antibiotics in the case of samples from Cadiz Bay or caffeine in oceanic seawater samples. Risk quotients, expressed as ratios between the measured environmental concentration (MEC) and the predicted no-effect concentrations (PNEC) were higher than 1 for two compounds (gemfibrozil and ofloxacin) in effluent of Jerez de la Frontera sewage treatment plant (STP). No high environmental risk was detected in both coastal and oceanic sampling areas, although the information available about the effects of these chemicals on marine biota is still very limited and negative effects on non-target species cannot be discarded. Copyright © 2017 Elsevier B.V. All rights reserved.

  9. Ikaite crystals in melting sea ice - implications for pCO(2) and pH levels in Arctic surface waters

    DEFF Research Database (Denmark)

    Rysgaard, Søren; Glud, Ronnie N.; Lennert, Kunuk

    2012-01-01

    A major issue of Arctic marine science is to understand whether the Arctic Ocean is, or will be, a source or sink for air-sea CO2 exchange. This has been complicated by the recent discoveries of ikaite (a polymorph of CaCO3 center dot 6H(2)O) in Arctic and Antarctic sea ice, which indicate......, melt reduced the ice floe thickness by 0.2m per week and resulted in an estimated 3.8 ppm decrease of pCO(2) in the ocean surface mixed layer. This corresponds to an air-sea CO2 uptake of 10.6 mmol m(-2) sea ice d(-1) or to 3.3 ton km(-2) ice floe week(-1). This is markedly higher than the estimated...... that multiple chemical transformations occur in sea ice with a possible effect on CO2 and pH conditions in surface waters. Here, we report on biogeochemical conditions, microscopic examinations and x-ray diffraction analysis of single crystals from a melting 1.7 km(2) (0.5-1m thick) drifting ice floe...

  10. Impacts of Ocean Waves on the Atmospheric Surface Layer: Simulations and Observations

    Science.gov (United States)

    2008-06-06

    than about 5 m s −1 (Makin, Kudryavtsev & Mastenbroek 1995; Banner & Peirson 1998). Ocean boundary layers with vortex force and stochastic breaking...amplitude. Proc. Roy. Soc. Lond. A 342, 157–174. Makin, V. K., Kudryavtsev , V. N. & Mastenbroek, C. 1995 Drag of the sea surface. Boundary- Layer Met. 73...to study some of the impacts of fast-moving waves on marine surface layers (e.g., Gent and Taylor 1976; Gent 1977; Li 1995; Kudryavtsev and Makin 2004

  11. Coccolith distribution patterns in South Atlantic and Southern Ocean surface sediments in relation to environmental gradients

    DEFF Research Database (Denmark)

    Boeckel, B.; Baumann, K.-H.; Henrich, R.

    2006-01-01

    In this study, the coccolith compositions of 213 surface sediment samples from the South Atlantic and Southern Ocean were analysed with respect to the environmental parameters of the overlying surface waters. From this data set, the abundance patterns of the main species and their ecological...... seems to be associated with high temperatures and salinities under low-nutrient conditions. Based on the relative abundances of Calcidiscus leptoporus, F. profunda, Gladiolithus flabellatus, Helicosphaera spp., Umbilicosphaera foliosa, Umbilicosphaera sibogae and a group of subordinate subtropical...

  12. Sea surface height evidence for long-term warming effects of tropical cyclones on the ocean.

    Science.gov (United States)

    Mei, Wei; Primeau, François; McWilliams, James C; Pasquero, Claudia

    2013-09-17

    Tropical cyclones have been hypothesized to influence climate by pumping heat into the ocean, but a direct measure of this warming effect is still lacking. We quantified cyclone-induced ocean warming by directly monitoring the thermal expansion of water in the wake of cyclones, using satellite-based sea surface height data that provide a unique way of tracking the changes in ocean heat content on seasonal and longer timescales. We find that the long-term effect of cyclones is to warm the ocean at a rate of 0.32 ± 0.15 PW between 1993 and 2009, i.e., ∼23 times more efficiently per unit area than the background equatorial warming, making cyclones potentially important modulators of the climate by affecting heat transport in the ocean-atmosphere system. Furthermore, our analysis reveals that the rate of warming increases with cyclone intensity. This, together with a predicted shift in the distribution of cyclones toward higher intensities as climate warms, suggests the ocean will get even warmer, possibly leading to a positive feedback.

  13. Physical Retracking of Jason-1 LRM data for ocean surface height/gravity field determination

    Science.gov (United States)

    Jain, Maulik; Baltazar Andersen, Ole; Stenseng, Lars; Dall, Jørgen

    2013-04-01

    Jason-1 Low Resolution Mode (LRM) waveforms can be processed to extract accurate heights of the ocean surface. These heights are adjusted taking into account various corrections available. Further the along surface slope/variation of these ocean heights can be used to make an estimation of the gravity field. An important part of this gravity field estimation is dependent on the way the LRM waveform is processed. Thus a physical model based on an error function is used, and the LRM waveforms are fit to this model. A processing system made up of 2 parameter and 3 parameter fitting models are used in order to extract the most reliable ocean surface heights. The quality of the processing system is judged by evaluating the standard deviation of the sea surface anomaly obtained after all corrections and the mean sea surface/geoid are removed. The lower the value of the standard deviation of the sea surface anomaly, the better the quality of processing is. Hence, different processing schemes are considered and evaluated in order to conclude towards the best retracking procedure which would eventually result in high accuracy gravity field estimations.

  14. Skin Surface pH in Acne Vulgaris: Insights from an Observational Study and Review of the Literature.

    Science.gov (United States)

    Prakash, Chaitra; Bhargava, Puneet; Tiwari, Siddhi; Majumdar, Banashree; Bhargava, Rishi Kumar

    2017-07-01

    OBJECTIVE: Recurrent and chronic course of acne vulgaris, despite effect-proven therapies, point to an underfocused aspect in its pathogenesis and management. This study aims to assess in subjects with and without acne, the skin surface pH, a parameter that cumulatively represents functioning of various units of skin, including the barrier. METHODS: A total of 200 patients with acne and 200 age- and sex-matched controls were included. Under basal conditions, facial skin pH was derived from five sites using a skin pH-meter. The relation between skin pH and acne was evaluated according to sex. RESULTS: There were more subjects with normal skin pH in the control group compared to the case group, and the majority of acne occurrences in the case group were related to high skin pH ( p =0.000). Mean pH among cases was higher than normal reference value (pH 4.5-5.5 for women, 4-5.5 for men) and that of controls p (pH in either cases or controls ( p >0.05). CONCLUSION: Increased facial skin pH in patients with acne at basal conditions mirrors a chronic state of stratum corneum instability, which could be predisposing individuals to acne occurrence and/or recurrences. It could possibly be a common domain via which the classical pathomechanisms might be acting in acne. Integrating measures that maintain stratum corneum pH during therapy might prove worthwhile.

  15. Changes in Energy Imbalance at the Ocean Surface during the "hiatus" period

    Science.gov (United States)

    Yu, L.

    2016-02-01

    Despite the recent slowdown in the rate of surface warming, a general consensus exists, that is, the Earth continues to gain energy and almost all the energy added to the Earth system is accumulated in the oceans. Nevertheless, key issues remain unaddressed regarding the actual energy imbalance at the top-of-atmosphere and the Earth surface, their changes over time, and their storage and distribution in the oceans. Quantifying and tracking the energy flow through the Earth System require consistent and accurate record of observations, but existing observation platforms contain various degrees of uncertainty. There is a need to cross-validate the energy budget estimates from different resources and from different approaches. In this study, we conducted an assessment of net energy budget at the ocean surface estimated from three general sources, the satellite-based analysis (WHOI OAFlux and NASA CERES), an ocean state estimator (MIT ECCO), and the atmospheric reanalysis products. For the "hiatus" period (2001-2010) in study, all products show that the oceans have been on net energy gain, but the magnitude varies and the differences in the rate of the decadal change in energy imbalance are large. While the reanalysis products show either upward or downward trends, ECCO and OAFlux/CERES indicate that the energy imbalance remains near constant. The downward trend in ERA-Interim started from 2006, driven by a peculiar pattern change in the Pacific. ECCO, which used ERA-Interim as initial surface forcing, corrected the pattern and maintained a near steady rate. ECCO assimilates observations from oceanographic satellites and Argo profiles, while the OAFlux/CERES Qnet were obtained from satellite atmospheric and near-surface observations using no dynamical models but the state-of-the-art flux algorithms and statistical approaches. Given the differences in input data sources and approaches, the agreement between ECCO and OAFlux/CERES is encouraging and instructive.

  16. Engaging the Applications Community of the future Surface Water and Ocean Topography (SWOT) Mission

    Science.gov (United States)

    Srinivasan, M.; Andral, A.; Dejus, M.; Hossain, F.; Peterson, C.; Beighley, E.; Pavelsky, T.; Chao, Y.; Doorn, B.; Bronner, E.; Houpert, L.

    2015-04-01

    NASA and the French space agency, CNES, with contributions from the Canadian Space Agency (CSA) and United Kingdom Space Agency (UKSA) are developing new wide swath altimetry technology that will cover most of the world's ocean and surface freshwater bodies. The proposed Surface Water and Ocean Topography (SWOT) mission will have the capability to make observations of surface water (lakes, rivers, wetland) heights and measurements of ocean surface topography with unprecedented spatial coverage, temporal sampling, and spatial resolution compared to existing technologies. These data will be useful for monitoring the hydrologic cycle, flooding, and characterizing human impacts on a changing environment. The applied science community is a key element in the success of the SWOT mission, demonstrating the high value of the science and data products in addressing societal issues and needs. The SWOT applications framework includes a working group made up of applications specialists, SWOT science team members, academics and SWOT Project members to promote applications research and engage a broad community of potential SWOT data users. A defined plan and a guide describing a program to engage early adopters in using proxies for SWOT data, including sophisticated ocean and hydrology simulators, an airborne analogue for SWOT (AirSWOT), and existing satellite datasets, are cornerstones for the program. A user survey is in development and the first user workshop was held in 2015, with annual workshops planned. The anticipated science and engineering advances that SWOT will provide can be transformed into valuable services to decision makers and civic organizations focused on addressing global disaster risk reduction initiatives and potential science-based mitigation activities for water resources challenges of the future. With the surface water measurements anticipated from SWOT, a broad range of applications can inform inland and coastal managers and marine operators of

  17. Atmospheric response to multidecadal sea surface temperature variability in the Pacific Ocean (IPV) and the North Atlantic Ocean (AMV)

    Science.gov (United States)

    Elsbury, D.; Peings, Y.; Magnusdottir, G.

    2017-12-01

    Multidecadal modes of sea surface temperature (SST) variability in the Pacific and Atlantic Oceans act as forcing fields in a series of atmospheric global climate model (AGCM) simulations. These modes, Interdecadal Pacific Variability (IPV) and Atlantic Multidecadal Variability (AMV), are important regulators of global temperature, precipitation, extreme climate events (droughts and temperature extremes), and have recently been implicated as playing an important role in the global warming hiatus. Despite a growing recognition of the importance of these climate modes, the most fundamental atmospheric and climatic responses to the long-term internal variability and interplay of these two ocean basins is not well understood. In a series of 200-yr experiments using the Whole Atmosphere Community Climate Model (WACCM), the atmosphere is forced by the 9 different combinations of the AMV and IPV states (neutral, positive, negative) using a single polarity from each the IPV and the AMV, and different combinations. The atmospheric response associated with each combination of SST anomalies is investigated, with a focus on modes of variability such as the North Atlantic Oscillation (NAO) and associated temperature/precipitation variability. Of particular interest is the response related to forcing from the tropical Pacific, the stratospheric response and associated stratosphere-troposphere interactions, and the response of extreme weather events in both winter and summer. These results yield a more complete understanding of climate predictability associated with each basin at multidecadal time scales, and how their respective influences interfere with each other.

  18. Remote sensing of ocean surface currents: a review of what is being observed and what is being assimilated

    OpenAIRE

    Isern-Fontanet, Jordi; Ballabrera-Poy, Joaquim; Turiel, Antonio; García-Ladona, Emilio

    2017-01-01

    Ocean currents play a key role in Earth's climate – they impact almost any process taking place in the ocean and are of major importance for navigation and human activities at sea. Nevertheless, their observation and forecasting are still difficult. First, no observing system is able to provide direct measurements of global ocean currents on synoptic scales. Consequently, it has been necessary to use sea surface height and sea surface temperature measurements and refer to dy...

  19. pH homeostasis during coral calcification in a free ocean CO2 enrichment (FOCE) experiment, Heron Island reef flat, Great Barrier Reef

    Science.gov (United States)

    Georgiou, Lucy; Falter, James; Trotter, Julie; Kline, David I.; Holcomb, Michael; Dove, Sophie G.; Hoegh-Guldberg, Ove; McCulloch, Malcolm

    2015-01-01

    Geochemical analyses (δ11B and Sr/Ca) are reported for the coral Porites cylindrica grown within a free ocean carbon enrichment (FOCE) experiment, conducted on the Heron Island reef flat (Great Barrier Reef) for a 6-mo period from June to early December 2010. The FOCE experiment was designed to simulate the effects of CO2-driven acidification predicted to occur by the end of this century (scenario RCP4.5) while simultaneously maintaining the exposure of corals to natural variations in their environment under in situ conditions. Analyses of skeletal growth (measured from extension rates and skeletal density) showed no systematic differences between low-pH FOCE treatments (ΔpH = ∼−0.05 to −0.25 units below ambient) and present day controls (ΔpH = 0) for calcification rates or the pH of the calcifying fluid (pHcf); the latter was derived from boron isotopic compositions (δ11B) of the coral skeleton. Furthermore, individual nubbins exhibited near constant δ11B compositions along their primary apical growth axes (±0.02 pHcf units) regardless of the season or treatment. Thus, under the highly dynamic conditions of the Heron Island reef flat, P. cylindrica up-regulated the pH of its calcifying fluid (pHcf ∼8.4–8.6), with each nubbin having near-constant pHcf values independent of the large natural seasonal fluctuations of the reef flat waters (pH ∼7.7 to ∼8.3) or the superimposed FOCE treatments. This newly discovered phenomenon of pH homeostasis during calcification indicates that coral living in highly dynamic environments exert strong physiological controls on the carbonate chemistry of their calcifying fluid, implying a high degree of resilience to ocean acidification within the investigated ranges. PMID:26438833

  20. pH homeostasis during coral calcification in a free ocean CO2 enrichment (FOCE) experiment, Heron Island reef flat, Great Barrier Reef.

    Science.gov (United States)

    Georgiou, Lucy; Falter, James; Trotter, Julie; Kline, David I; Holcomb, Michael; Dove, Sophie G; Hoegh-Guldberg, Ove; McCulloch, Malcolm

    2015-10-27

    Geochemical analyses (δ(11)B and Sr/Ca) are reported for the coral Porites cylindrica grown within a free ocean carbon enrichment (FOCE) experiment, conducted on the Heron Island reef flat (Great Barrier Reef) for a 6-mo period from June to early December 2010. The FOCE experiment was designed to simulate the effects of CO2-driven acidification predicted to occur by the end of this century (scenario RCP4.5) while simultaneously maintaining the exposure of corals to natural variations in their environment under in situ conditions. Analyses of skeletal growth (measured from extension rates and skeletal density) showed no systematic differences between low-pH FOCE treatments (ΔpH = ∼-0.05 to -0.25 units below ambient) and present day controls (ΔpH = 0) for calcification rates or the pH of the calcifying fluid (pHcf); the latter was derived from boron isotopic compositions (δ(11)B) of the coral skeleton. Furthermore, individual nubbins exhibited near constant δ(11)B compositions along their primary apical growth axes (±0.02 pHcf units) regardless of the season or treatment. Thus, under the highly dynamic conditions of the Heron Island reef flat, P. cylindrica up-regulated the pH of its calcifying fluid (pHcf ∼8.4-8.6), with each nubbin having near-constant pHcf values independent of the large natural seasonal fluctuations of the reef flat waters (pH ∼7.7 to ∼8.3) or the superimposed FOCE treatments. This newly discovered phenomenon of pH homeostasis during calcification indicates that coral living in highly dynamic environments exert strong physiological controls on the carbonate chemistry of their calcifying fluid, implying a high degree of resilience to ocean acidification within the investigated ranges.

  1. Implications of ocean acidification in the Pacific Arctic: Experimental responses of three Arctic bivalves to decreased pH and food availability

    Science.gov (United States)

    Goethel, Christina L.; Grebmeier, Jacqueline M.; Cooper, Lee W.; Miller, Thomas J.

    2017-10-01

    Recent sea ice retreat and seawater warming in the Pacific Arctic are physical changes that are impacting arctic biological communities. Recently, ocean acidification from increases in anthropogenic CO2 has been identified as an additional stressor, particularly to calcifying organisms like bivalves. These bivalves are common prey items for benthivorous predators such as Pacific walruses (Odobenus rosmarus divergens), bearded seals (Erignathus barbatus), and diving seaducks, such as Spectacled Eiders (Somateria fischeri). We investigated the effects of decreased pH and food availability on growth (% change in length and wet weight and allometric growth characterizations) and oxygen consumption (mg/L/hour) of three common Arctic bivalves, Macoma calcarea, Astarte montagui, and Astarte borealis. Two sets of experiments were run for seven and eleven weeks, exposing the bivalves to control (8.05 ± 0.02 and 8.19 ± 0.003, respectively) and acidified (7.76 ± 0.01 and 7.86 ± 0.01, respectively) pH treatments. Length, weight, and oxygen consumption were not significantly different among the varying treatments after the seven-week exposure and only one significant effect of decreased pH and one significant effect of decreased food availability were observed after the end of the eleven-week exposure. Specifically, shells of A. borealis displayed a decrease in length in response to decreased pH and M. calcarea showed a decrease in length in response to limited food. The negative effects of pH observed in the experiments on growth and oxygen consumption were small, suggesting that at least two of these species are generally resilient to decreasing pH.

  2. Global relationships of total alkalinity with salinity and temperature in surface waters of the world's oceans. (NCEI Accession 0157795)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Surface Total Alkalinity fields were estimated from five regional TA relationships presented in Lee et al. 2006, using monthly mean sea surface temperature and...

  3. Intercomparison of oceanic and atmospheric forced and coupled mesoscale simulations Part I: Surface fluxes

    Directory of Open Access Journals (Sweden)

    P. Josse

    1999-04-01

    Full Text Available A mesoscale non-hydrostatic atmospheric model has been coupled with a mesoscale oceanic model. The case study is a four-day simulation of a strong storm event observed during the SEMAPHORE experiment over a 500 × 500 km2 domain. This domain encompasses a thermohaline front associated with the Azores current. In order to analyze the effect of mesoscale coupling, three simulations are compared: the first one with the atmospheric model forced by realistic sea surface temperature analyses; the second one with the ocean model forced by atmospheric fields, derived from weather forecast re-analyses; the third one with the models being coupled. For these three simulations the surface fluxes were computed with the same bulk parametrization. All three simulations succeed well in representing the main oceanic or atmospheric features observed during the storm. Comparison of surface fields with in situ observations reveals that the winds of the fine mesh atmospheric model are more realistic than those of the weather forecast re-analyses. The low-level winds simulated with the atmospheric model in the forced and coupled simulations are appreciably stronger than the re-analyzed winds. They also generate stronger fluxes. The coupled simulation has the strongest surface heat fluxes: the difference in the net heat budget with the oceanic forced simulation reaches on average 50 Wm-2 over the simulation period. Sea surface-temperature cooling is too weak in both simulations, but is improved in the coupled run and matches better the cooling observed with drifters. The spatial distributions of sea surface-temperature cooling and surface fluxes are strongly inhomogeneous over the simulation domain. The amplitude of the flux variation is maximum in the coupled run. Moreover the weak correlation between the cooling and heat flux patterns indicates that the surface fluxes are not responsible for the whole cooling and suggests that the response of the ocean mixed layer

  4. Intercomparison of oceanic and atmospheric forced and coupled mesoscale simulations Part I: Surface fluxes

    Directory of Open Access Journals (Sweden)

    H. Giordani

    Full Text Available A mesoscale non-hydrostatic atmospheric model has been coupled with a mesoscale oceanic model. The case study is a four-day simulation of a strong storm event observed during the SEMAPHORE experiment over a 500 × 500 km2 domain. This domain encompasses a thermohaline front associated with the Azores current. In order to analyze the effect of mesoscale coupling, three simulations are compared: the first one with the atmospheric model forced by realistic sea surface temperature analyses; the second one with the ocean model forced by atmospheric fields, derived from weather forecast re-analyses; the third one with the models being coupled. For these three simulations the surface fluxes were computed with the same bulk parametrization. All three simulations succeed well in representing the main oceanic or atmospheric features observed during the storm. Comparison of surface fields with in situ observations reveals that the winds of the fine mesh atmospheric model are more realistic than those of the weather forecast re-analyses. The low-level winds simulated with the atmospheric model in the forced and coupled simulations are appreciably stronger than the re-analyzed winds. They also generate stronger fluxes. The coupled simulation has the strongest surface heat fluxes: the difference in the net heat budget with the oceanic forced simulation reaches on average 50 Wm-2 over the simulation period. Sea surface-temperature cooling is too weak in both simulations, but is improved in the coupled run and matches better the cooling observed with drifters. The spatial distributions of sea surface-temperature cooling and surface fluxes are strongly inhomogeneous over the simulation domain. The amplitude of the flux variation is maximum in the coupled run. Moreover the weak correlation between the cooling and heat flux patterns indicates that the surface fluxes are not responsible for the whole cooling and suggests that the response of the ocean mixed layer

  5. VOPcPhO:P3HT composite micro-structures with nano-porous surface morphology

    Energy Technology Data Exchange (ETDEWEB)

    Azmer, Mohamad Izzat [Low Dimensional Materials Research Centre (LDMRC), Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia); Ahmad, Zubair, E-mail: zubairtarar@qu.edu.qa [Center for Advanced Materials (CAM), Qatar University, P. O. Box 2713, Doha (Qatar); Sulaiman, Khaulah, E-mail: khaulah@um.edu.my [Low Dimensional Materials Research Centre (LDMRC), Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia); Touati, Farid [Department of Electrical Engineering, College of Engineering, Qatar University, P. O. Box 2713, Doha (Qatar); Bawazeer, Tahani M. [Department of Chemistry, Faculty of Applied Science, Umm Al-Qura University, Makkah (Saudi Arabia); Alsoufi, Mohammad S. [Mechanical Engineering Department, College of Engineering and Islamic Architecture, Umm Al-Qura University, Makkah (Saudi Arabia)

    2017-03-31

    Highlights: • VOPcPhO:P3HT micro-structures with nano-porous surface morphology have been formed. • Multidimensional structures have been formed by electro-spraying technique. • The electro-sprayed films are very promising for the humidity sensors. - Abstract: In this paper, composite micro-structures of Vanadyl 2,9,16,23-tetraphenoxy-29H,31H-phthalocyanine) (VOPcPhO) and Poly (3-hexylthiophene-2,5-diyl) (P3HT) complex with nano-porous surface morphology have been developed by electro-spraying technique. The structural and morphological characteristics of the VOPcPhO:P3HT composite films have been studied by field emission scanning electron microscopy (FESEM) and atomic force microscopy (AFM). The multidimensional VOPcPhO:P3HT micro-structures formed by electro-spraying with nano-porous surface morphology are very promising for the humidity sensors due to the pore sizes in the range of micro to nano-meters scale. The performance of the VOPcPhO:P3HT electro-sprayed sensor is superior in term of sensitivity, hysteresis and response/recovery times as compared to the spin-coated one. The electro-sprayed humidity sensor exhibits ∼3 times and 0.19 times lower hysteresis in capacitive and resistive mode, respectively, as compared to the spin-coated humidity sensor.

  6. Ocean Heat Uptake Slows 21st Century Surface Warming Driven by Extratropical Cloud Feedbacks

    Science.gov (United States)

    Frey, W.; Maroon, E.; Pendergrass, A. G.; Kay, J. E.

    2017-12-01

    Equilibrium climate sensitivity (ECS), the warming in response to instantaneously doubled CO2, has long been used to compare climate models. In many models, ECS is well correlated with warming produced by transient forcing experiments. Modifications to cloud phase at high latitudes in a state-of-the-art climate model, the Community Earth System Model (CESM), produce a large increase in ECS (1.5 K) via extratropical cloud feedbacks. However, only a small surface warming increase occurs in a realistic 21st century simulation including a full-depth dynamic ocean and the "business as usual" RCP8.5 emissions scenario. In fact, the increase in surface warming is only barely above the internal variability-generated range in the CESM Large Ensemble. The small change in 21st century warming is attributed to subpolar ocean heat uptake in both hemispheres. In the Southern Ocean, the mean-state circulation takes up heat while in the North Atlantic a slowdown in circulation acts as a feedback to slow surface warming. These results show the importance of subpolar ocean heat uptake in controlling the pace of warming and demonstrate that ECS cannot be used to reliably infer transient warming when it is driven by extratropical feedbacks.

  7. Extreme diving behaviour in devil rays links surface waters and the deep ocean

    KAUST Repository

    Thorrold, Simon R.

    2014-07-01

    Ecological connections between surface waters and the deep ocean remain poorly studied despite the high biomass of fishes and squids residing at depths beyond the euphotic zone. These animals likely support pelagic food webs containing a suite of predators that include commercially important fishes and marine mammals. Here we deploy pop-up satellite archival transmitting tags on 15 Chilean devil rays (Mobula tarapacana) in the central North Atlantic Ocean, which provide movement patterns of individuals for up to 9 months. Devil rays were considered surface dwellers but our data reveal individuals descending at speeds up to 6.0 ms-1 to depths of almost 2,000 m and water temperatures <4 C. The shape of the dive profiles suggests that the rays are foraging at these depths in deep scattering layers. Our results provide evidence of an important link between predators in the surface ocean and forage species occupying pelagic habitats below the euphotic zone in ocean ecosystems. 2014 Macmillan Publishers Limited. All rights reserved.

  8. Origin, dynamics and evolution of ocean garbage patches from observed surface drifters

    International Nuclear Information System (INIS)

    Van Sebille, Erik; England, Matthew H; Froyland, Gary

    2012-01-01

    Much of the debris in the near-surface ocean collects in so-called garbage patches where, due to convergence of the surface flow, the debris is trapped for decades to millennia. Until now, studies modelling the pathways of surface marine debris have not included release from coasts or factored in the possibilities that release concentrations vary with region or that pathways may include seasonal cycles. Here, we use observational data from the Global Drifter Program in a particle-trajectory tracer approach that includes the seasonal cycle to study the fate of marine debris in the open ocean from coastal regions around the world on interannual to centennial timescales. We find that six major garbage patches emerge, one in each of the five subtropical basins and one previously unreported patch in the Barents Sea. The evolution of each of the six patches is markedly different. With the exception of the North Pacific, all patches are much more dispersive than expected from linear ocean circulation theory, suggesting that on centennial timescales the different basins are much better connected than previously thought and that inter-ocean exchanges play a large role in the spreading of marine debris. This study suggests that, over multi-millennial timescales, a significant amount of the debris released outside of the North Atlantic will eventually end up in the North Pacific patch, the main attractor of global marine debris. (letter)

  9. Effects of Ocean Acidification and Flow on Oxygen and pH Conditions of Developing Squid (Doryteuthis pealeii) Egg Cases

    Science.gov (United States)

    Panyi, A.; Long, M. H.; Mooney, T. A.

    2016-02-01

    While young animals found future cohorts and populations, these early life stages are often particularly susceptible to conditions of the local environment in which they develop. The oxygen and pH of this critical developmental environment is likely impacted by the nearby physical conditions and the animals own respirations. Yet, in nearly all cases, this microenvironment is unknown, limiting our understanding of animal tolerances to current and future OA and hypoxic conditions. This study investigated the oxygen and pH environment adjacent to and within the egg cases of a keystone species, the longfin squid, Doryteuthis pealeii, under ambient and elevated CO2 (400 and 2200 ppm), and across differing water flow rates (0, 1, and 10 cm/s) using microprobes. Under both CO2 treatments, oxygen and pH in the egg case centers dropped dramatically across development to levels generally considered metabolically stressful even for adults. In the ambient CO2 trial, oxygen concentrations reached a minimum of 4.351 µmol/L, and pH reached a minimum of 7.36. In the elevated CO2 trial, oxygen concentrations reached a minimum of 9.910 µmol/L, and pH reached a minimum of 6.79. Flow appeared to alleviate these conditions, with highest O2 concentrations in the egg cases exposed to 10 cm/s flow in both CO2 trials, across all age classes measured. Surprisingly, all tested egg cases successfully hatched, demonstrating that developing D. pealeii embryos have a strong tolerance for low oxygen and pH, but there were more unsuccessful embryos counted in the 0 and 1 cm/s flow conditions. Further climate change could place young, keystone squid outside of their physiological limits, but water flow may play a key role in mitigating developmental stress to egg case bound embryos by increasing available oxygen.

  10. ENSO signals on sea-surface salinity in the eastern tropical pacific ocean

    Directory of Open Access Journals (Sweden)

    1998-01-01

    Full Text Available SIGNAUX DE L’ENSO SUR LA SALINITE DE LA SURFACE DE LA MER DANS L’OCEAN PACIFIQUE TROPICAL ORIENTAL. Nous présentons les variations de la température et de la salinité de surface. Des navires de commerce ont été récemment équipés de thermosalinographes automatiques qui permettent d’échantillonner en continu et de localiser le front de salinité le long de la ligne Panama-Tahiti, séparant les masses d’eaux du golfe de Panama et celles du Pacifique central sud. La variation en latitude de la position du front halin suit la position de la zone de convergence intertropicale des vents du Pacifique. La salinité donne ainsi des informations supplémentaires sur le développement du phénomène El Niño dans le Pacifique tropical. La future transmission par satellite de la salinité de surface permettra de suivre en temps réel la distribution de la salinité de surface qui est étroitement liée aux échanges entre l’océan et l’atmosphère. SEÑALES DEL ENSO SOBRE LA SALINIDAD DE LA SUPERFICIE DEL OCÉANO PACÍFICO ORIENTAL. Presentamos las variaciones de la temperatura y de la salinidad de superficie. Barcos de comercio fueron recientemente equipados con termo-saliógrafos automáticos, los cuales permiten observar un muestreo continuo y ubicar el frente de salinidad en la recta Panamá-Tahiti, la cual separa las masas de agua del golfo de Panamá con las del Pacífico centro Sur. La variación en latitud de la ubicación del frente halino acompaña a la posición de la Zona de Convergencia Intertropical de los vientos del Pacífico. La salinidad proporciona también informaciones adicionales sobre el desarrollo del Fenómeno El Niño en el Pacífico tropical. La futura transmisión por satélite de la salinidad de superficie permitirá el monitoreo en tiempo real de la distribución en tiempo real de la salinidad de superficie, la cual está estrechamente vinculada con los intercambios entre el océano y la atmósfera. Various data

  11. Observations of Near-Surface Current Shear Help Describe Oceanic Oil and Plastic Transport

    Science.gov (United States)

    Laxague, Nathan J. M.; Ö-zgökmen, Tamay M.; Haus, Brian K.; Novelli, Guillaume; Shcherbina, Andrey; Sutherland, Peter; Guigand, Cédric M.; Lund, Björn; Mehta, Sanchit; Alday, Matias; Molemaker, Jeroen

    2018-01-01

    Plastics and spilled oil pose a critical threat to marine life and human health. As a result of wind forcing and wave motions, theoretical and laboratory studies predict very strong velocity variation with depth over the upper few centimeters of the water column, an observational blind spot in the real ocean. Here we present the first-ever ocean measurements of the current vector profile defined to within 1 cm of the free surface. In our illustrative example, the current magnitude averaged over the upper 1 cm of the ocean is shown to be nearly four times the average over the upper 10 m, even for mild forcing. Our findings indicate that this shear will rapidly separate pieces of marine debris which vary in size or buoyancy, making consideration of these dynamics essential to an improved understanding of the pathways along which marine plastics and oil are transported.

  12. Assimilation of ocean sea-surface height observations of mesoscale eddies

    Science.gov (United States)

    Weiss, Jeffrey B.; Grooms, Ian

    2017-12-01

    Mesoscale eddies are one of the dominant sources of variability in the world's oceans. With eddy-resolving global ocean models, it becomes important to assimilate observations of mesoscale eddies to correctly represent the state of the mesoscale. Here, we investigate strategies for assimilating a reduced number of sea-surface height observations by focusing on the coherent mesoscale eddies. The study is carried out in an idealized perfect-model framework using two-layer forced quasigeostrophic dynamics, which captures the dominant dynamics of ocean mesoscale eddies. We study errors in state-estimation as well as error growth in forecasts and find that as fewer observations are assimilated, assimilating at vortex locations results in reduced state estimation and forecast errors.

  13. Multimodel simulations of Arctic Ocean sea surface height variability in the period 1970-2009

    DEFF Research Database (Denmark)

    Koldunov, Nikolay V.; Serra, Nuno; Koehl, Armin

    2014-01-01

    is in reasonable agreement with available measurements. Focusing on results from one of the models for a detailed analysis, it is shown that the decadal-scale SSH variability over shelf areas and deep parts of the Arctic Ocean have pronounced differences that are determined mostly by salinity variations. A further......The performance of several numerical ocean models is assessed with respect to their simulation of sea surface height (SSH) in the Arctic Ocean, and the main patterns of SSH variability and their causes over the past 40 years (1970-2009) are analyzed. In comparison to observations, all tested models...... of low-salinity shelf water. Overall, we show that present-day models can be used for investigating the reasons for low-frequency SSH variability in the region....

  14. Biochemical characteristics and bacterial community structure of the sea surface microlayer in the South Pacific Ocean

    Directory of Open Access Journals (Sweden)

    I. Obernosterer

    2008-05-01

    Full Text Available The chemical and biological characteristics of the surface microlayer were determined during a transect across the South Pacific Ocean in October-December 2004. Concentrations of particulate organic carbon (1.3 to 7.6-fold and nitrogen (1.4 to 7-fold, and POC:PON ratios were consistently higher in the surface microlayer as compared to surface waters (5 m. The large variability in particulate organic matter enrichment was negatively correlated to wind speed. No enhanced concentrations of dissolved organic carbon were detectable in the surface microlayer as compared to 5 m, but chromophoric dissolved organic matter was markedly enriched (by 2 to 4-fold at all sites. Based on pigment analysis and cell counts, no consistent enrichment of any of the major components of the autotrophic and heterotrophic microbial community was detectable. CE-SSCP fingerprints and CARD FISH revealed that the bacterial communities present in the surface microlayer had close similarity (>76% to those in surface waters. By contrast, bacterial heterotrophic production (3H-leucine incorporation was consistently lower in the surface microlayer than in surface waters. By applying CARD-FISH and microautoradiography, we observed that Bacteroidetes and Gammaproteobacteria dominated leucine uptake in the surface microlayer, while in surface waters Bacteroidetes and Alphaproteobacteria were the major groups accounting for leucine incorporation. Our results demonstrate that the microbial community in the surface microlayer closely resembles that of the surface waters of the open ocean. Even a short residence in the surface microlayer influences leucine incorporation by different bacterial groups, probably as a response to the differences in the physical and chemical nature of the two layers.

  15. CAROLS: A New Airborne L-Band Radiometer for Ocean Surface and Land Observations

    DEFF Research Database (Denmark)

    Zribi, Mehrez; Parde, Mickael; Boutin, Jacquline

    2011-01-01

    The "Cooperative Airborne Radiometer for Ocean and Land Studies" (CAROLS) L-Band radiometer was designed and built as a copy of the EMIRAD II radiometer constructed by the Technical University of Denmark team. It is a fully polarimetric and direct sampling correlation radiometer. It is installed ...... is conforming to specification and is a useful tool for Soil Moisture and Ocean Salinity (SMOS) satellite validation as well as for specific studies on surface soil moisture or ocean salinity.......The "Cooperative Airborne Radiometer for Ocean and Land Studies" (CAROLS) L-Band radiometer was designed and built as a copy of the EMIRAD II radiometer constructed by the Technical University of Denmark team. It is a fully polarimetric and direct sampling correlation radiometer. It is installed...... flights were carried out over South West France, the Valencia site and the Bay of Biscay (Atlantic Ocean) in 2007, 2008 and 2009, in coordination with in situ field campaigns. In order to validate the CAROLS data, various aircraft flight patterns and maneuvers were implemented, including straight...

  16. Northerly surface winds over the eastern North Pacific Ocean in spring and summer

    Science.gov (United States)

    Taylor, S.V.; Cayan, D.R.; Graham, N.E.; Georgakakos, K.P.

    2008-01-01

    Persistent spring and summer northerly surface winds are the defining climatological feature of the western coast of North America, especially south of the Oregon coast. Northerly surface winds are important for upwelling and a vast array of other biological, oceanic, and atmospheric processes. Intermittence in northerly coastal surface wind is characterized and wind events are quantitatively defined using coastal buoy data south of Cape Mendocino on the northern California coast. The defined wind events are then used as a basis for composites in order to explain the spatial evolution of various atmospheric and oceanic processes. Wind events involve large-scale changes in the three-dimensional atmospheric circulation including the eastern North Pacific subtropical anticyclone and southeast trade winds. Composites of QSCAT satellite scatterometer wind estimates from 1999 to 2005 based on a single coastal buoy indicate that wind events typically last 72-96 h and result in anomalies in surface wind and Ekman pumping that extend over 1000 kin from the west coast of North America. It may be useful to consider ocean circulation and dependent ecosystem dynamics and the distribution of temperature, moisture, and aerosols in the atmospheric boundary layer in the context of wind events defined herein. Copyright 2008 by the American Geophysical Union.

  17. Surface water and atmospheric underway carbon data obtained during the World Ocean Circulation Experiment Indian Ocean survey cruises (R/V Knorr, December 1998--January 1996)

    Energy Technology Data Exchange (ETDEWEB)

    Kozyr, A. [Univ. of Tennessee, Knoxville, TN (United States). Energy, Environment, and Resources Center; Allison, L. [Oak Ridge National Lab., TN (United States). Carbon Dioxide Information Analysis Center

    1997-11-01

    This data documentation presents the results of the surface water and atmospheric underway measurements of mole fraction of carbon dioxide (xCO{sub 2}), sea surface salinity, and sea surface temperature, obtained during the World Ocean Circulation Experiment (WOCE) Indian Ocean survey cruises (December 1994--January 1996). Discrete and underway carbon measurements were made by members of the CO{sub 2} survey team. The survey team is a part of the Joint Global Ocean Flux Study supported by the US Department of Energy to make carbon-related measurements on the WOCE global survey cruises. Approximately 200,000 surface seawater and 50,000 marine air xCO{sub 2} measurements were recorded.

  18. Oceanic Transport of Surface Meltwater from the Southern Greenland Ice Sheet

    Science.gov (United States)

    Luo, Hao; Castelao, Renato M.; Rennermalm, Asa K.; Tedesco, Marco; Bracco, Annalisa; Yager, Patricia L.; Mote, Thomas L.

    2016-01-01

    The Greenland ice sheet has undergone accelerating mass losses during recent decades. Freshwater runoff from ice melt can influence fjord circulation and dynamic1 and the delivery of bioavailable micronutrients to the ocean. It can also have climate implications, because stratification in the adjacent Labrador Sea may influence deep convection and the strength of the Atlantic meridional overturning circulation. Yet, the fate of the meltwater in the ocean remains unclear. Here, we use a high-resolution ocean model to show that only 1-15% of the surface meltwater runoff originating from southwest Greenland is transported westwards. In contrast, up to 50-60% of the meltwater runoff originating from southeast Greenland is transported westwards into the northern Labrador Sea, leading to significant salinity and stratification anomalies far from the coast. Doubling meltwater runoff, as predicted in future climate scenarios, results in a more-than-double increase in anomalies offshore that persists further into the winter. Interannual variability in offshore export of meltwater is tightly related to variability in wind forcing. The new insight that meltwaters originating from the west and east coasts have different fates indicates that future changes in mass loss rates and surface runoff will probably impact the ocean differently, depending on their Greenland origins.

  19. The artificial object detection and current velocity measurement using SAR ocean surface images

    Science.gov (United States)

    Alpatov, Boris; Strotov, Valery; Ershov, Maksim; Muraviev, Vadim; Feldman, Alexander; Smirnov, Sergey

    2017-10-01

    Due to the fact that water surface covers wide areas, remote sensing is the most appropriate way of getting information about ocean environment for vessel tracking, security purposes, ecological studies and others. Processing of synthetic aperture radar (SAR) images is extensively used for control and monitoring of the ocean surface. Image data can be acquired from Earth observation satellites, such as TerraSAR-X, ERS, and COSMO-SkyMed. Thus, SAR image processing can be used to solve many problems arising in this field of research. This paper discusses some of them including ship detection, oil pollution control and ocean currents mapping. Due to complexity of the problem several specialized algorithm are necessary to develop. The oil spill detection algorithm consists of the following main steps: image preprocessing, detection of dark areas, parameter extraction and classification. The ship detection algorithm consists of the following main steps: prescreening, land masking, image segmentation combined with parameter measurement, ship orientation estimation and object discrimination. The proposed approach to ocean currents mapping is based on Doppler's law. The results of computer modeling on real SAR images are presented. Based on these results it is concluded that the proposed approaches can be used in maritime applications.

  20. Magnetic Signatures of Fine-scale Processes in the Ocean Surface Layer

    Science.gov (United States)

    Soloviev, A.; Dean, C.; Avera, W. E.

    2015-12-01

    Fine-scale processes in the upper ocean turbulent boundary layer may have a measurable electromagnetic signature. In order to study magnetic signatures of these fine-scale processes, we have applied a magnetohydrodynamic (MHD) model combining a 3D computational fluid dynamics model and electromagnetic block, based on ANSYS Fluent software. In addition, the hydrodynamic component of the MHD model is coupled with a radar imaging algorithm, which potentially provides a link to synthetic aperture radar (SAR) satellite imagery. Capabilities of this model have been demonstrated using a simulation and observation of an internal wave soliton in the Straits of Florida, observed with in situ instrumentation (ADCP mooring) and COSMO Sky Med (SAR) satellite image. We have applied this model to study magnetic signatures of surface waves, freshwater lenses, spatially coherent organized motions in the near-surface layer of the ocean (Langmuir circulation and ramp-like structures), and bio-turbulence induced by diel vertical migrations of zooplankton in some areas of the ocean. Investigation of electromagnetic signatures in upper ocean processes offers a valuable new prospect in air-sea interaction.

  1. Oceanic transport of surface meltwater from the southern Greenland ice sheet

    Science.gov (United States)

    Luo, Hao; Castelao, Renato M.; Rennermalm, Asa K.; Tedesco, Marco; Bracco, Annalisa; Yager, Patricia L.; Mote, Thomas L.

    2016-07-01

    The Greenland ice sheet has undergone accelerating mass losses during recent decades. Freshwater runoff from ice melt can influence fjord circulation and dynamics and the delivery of bioavailable micronutrients to the ocean. It can also have climate implications, because stratification in the adjacent Labrador Sea may influence deep convection and the strength of the Atlantic meridional overturning circulation. Yet, the fate of the meltwater in the ocean remains unclear. Here, we use a high-resolution ocean model to show that only 1-15% of the surface meltwater runoff originating from southwest Greenland is transported westwards. In contrast, up to 50-60% of the meltwater runoff originating from southeast Greenland is transported westwards into the northern Labrador Sea, leading to significant salinity and stratification anomalies far from the coast. Doubling meltwater runoff, as predicted in future climate scenarios, results in a more-than-double increase in anomalies offshore that persists further into the winter. Interannual variability in offshore export of meltwater is tightly related to variability in wind forcing. The new insight that meltwaters originating from the west and east coasts have different fates indicates that future changes in mass loss rates and surface runoff will probably impact the ocean differently, depending on their Greenland origins.

  2. Ultrahigh nanoparticle stability against salt, pH, and solvent with retained surface accessibility via depletion stabilization.

    Science.gov (United States)

    Zhang, Xu; Servos, Mark R; Liu, Juewen

    2012-06-20

    For many applications, it is desirable to stabilize colloids over a wide range of buffer conditions while still retaining surface accessibility for adsorption and reaction. Commonly used charge or steric stabilization cannot achieve this goal since the former is sensitive to salt and the latter blocks the particle surface. We use depletion stabilization in the presence of high molecular weight polyethylene glycol (PEG) to stabilize a diverse range of nanomaterials, including gold nanoparticles (from 10 to 100 nm), graphene oxide, quantum dots, silica nanoparticles, and liposomes in the presence of Mg(2+) (>1.6 M), heavy metal ions, extreme pH (pH 1-13), organic solvents, and adsorbed nucleosides and drugs. At the same time, the particle surface remains accessible for adsorption of both small molecules and macromolecules. Based on this study, high loading of thiolated DNA was achieved in one step with just 2% PEG 20,000 in 2 h.

  3. An update to the Surface Ocean CO2 Atlas (SOCAT version 2)

    Digital Repository Service at National Institute of Oceanography (India)

    Bakker, D.C.E.; Hankin, S.; Olsen, A.; Pfeil, B.; Smith, K.; Alin, S.R.; Cosca, C.; Hales, B.; Harasawa, S.; Kozyr, A.; Nojiri, Y.; OBrien, K.M.; Schuster, U.; Telszewski, M.; Tilbrook, B.; Wada, C.; Akl, J.; Barbero, L.; Bates, N.; Boutin, J.; Cai, W.J.; Castle, R.D.; Chavez, F.; Chen, L.; Chierici, M.; Currie, K.; Evans, W.; Feely, R.A.; Fransson, A.; Gao, Z.; Hardman-Mountford, N.; Hoppema, M.; Huang, W.J.; Hunt, C.W.; Huss, B.; Ichikawa, T.; Jacobson, A.; Johannessen, T.; Jones, E.M.; Jones, S.; Sara, J.; Kitidis, V.; Kortzinger, A.; Lauvset, S.; Lefevre, N.; Manke, A.B.; Mathis, J.; Metzl, N.; Monteiro, P.; Murata, A.; Newberger, T.; Nobuo, T.; Ono, T.; Paterson, K.; Pierrot, D.; Rios, A.F.; Sabine, C.L.; Saito, S.; Salisbury, J.; Sarma, V.V.S.S.; Schlitzer, R.; Sieger, R.; Skjelvan, I.; Steinhoff, T.; Sullivan, K.; Sutherland, S.C.; Suzuki, T.; Sutton, A.; Sweeney, C.; Takahashi, T.; Tjiputra, J.; VanHeuven, S.; Vandemark, D.; Vlahos, P.; Wallace, D.W.R.; Wanninkhof, R.; Watson, A.J.

    /69/2014/ Earth Syst. Sci. Data, 6, 69–90, 2014 78 D. C. E. Bakker et al.: An update to the Surface Ocean CO2 Atlas (SOCAT version 2) 0 2 4 6 8 10 12 x 105 N um be r o f f C O 2 va lu es N at ha ni el B . P al m er E xp lo re r o f t he S ea s La ur en ce M.... Sci. Data, 6, 69–90, 2014 www.earth-syst-sci-data.net/6/69/2014/ doi:10.5194/essd-6-69-2014 © Author(s) 2014. CC Attribution 3.0 License. Op en A cc es s Earth System Science Data An update to the Surface Ocean CO2 Atlas (SOCAT version 2) D. C. E...

  4. Evaluation of pH Levels and Surface Roughness After Bleaching and Abrasion Tests of Eight Commercial Products.

    Science.gov (United States)

    Trentino, Ana Carolina; Soares, Ana Flavia; Duarte, Marco Antonio Hungaro; Ishikiriama, Sérgio Kiyoshi; Mondelli, Rafael Francisco Lia

    2015-07-01

    This in vitro study evaluated the effect of different bleaching protocols and the variation of pH levels of bleaching gels regarding roughness and wear of bovine enamel, after in-office bleaching protocols and brushing. Ninety fragments were randomly divided into nine groups: C, control; WHP15, 35% hydrogen peroxide (HP) (Whiteness HP, FGM) three gel applications of 15 min each, three sessions with 1 week intervals; WHP45, 35% HP (Whiteness HP) one application/45 min, three sessions with 1 week intervals; LPS, 35% HP (Lase Peroxide, DMC) plus hybrid light (HL) [light-emitting diode (LED)/diode laser], four applications/7 min 30 sec (6 min of HL activation), one session; LPSII, 25% HP (Lase Peroxide II, DMC) plus HL, four applications/7 min 30 sec (6 min of HL activation), one session; LPL, 15% HP (Lase Peroxide Light, DMC) four applications/7 min 30 sec (6 min of HL activation), one session; WO, 35% HP (Whitegold Office, Dentsply) three applications/15 min, three sessions with 1 week intervals; WBC40, 35% HP (Whiteness HP Blue Calcium, FGM) one application/40 min, three sessions with 1 week intervals; and WBC50, 20% HP (Whiteness HP Blue Calcium) one application/50 min, three sessions with 1 week intervals. The median pH values were determined utilizing a pH meter during the initial and final gel applications. A rugosimeter was utilized to evaluate the surface roughness (Ra) before and after bleaching and brushing (100,000 strokes), and the surface wear after brushing. For the results of the pH values, there was a decrease in the pH levels from the initial to the final bleaching time, except for the WBC50. The WO and WBC40 groups exhibited higher pH values. For the results of roughness and wear, there was an increase in surface roughness and wear among the groups. The pH values tended to decrease from the initial to the final bleaching. After tooth brushing, bleaching procedures with lower pH products provided a significant increase in

  5. Chemical equilibrium modeling of organic acids, pH, aluminum, and iron in Swedish surface waters.

    Science.gov (United States)

    Sjöstedt, Carin S; Gustafsson, Jon Petter; Köhler, Stephan J

    2010-11-15

    A consistent chemical equilibrium model that calculates pH from charge balance constraints and aluminum and iron speciation in the presence of natural organic matter is presented. The model requires input data for total aluminum, iron, organic carbon, fluoride, sulfate, and charge balance ANC. The model is calibrated to pH measurements (n = 322) by adjusting the fraction of active organic matter only, which results in an error of pH prediction on average below 0.2 pH units. The small systematic discrepancy between the analytical results for the monomeric aluminum fractionation and the model results is corrected for separately for two different fractionation techniques (n = 499) and validated on a large number (n = 3419) of geographically widely spread samples all over Sweden. The resulting average error for inorganic monomeric aluminum is around 1 µM. In its present form the model is the first internally consistent modeling approach for Sweden and may now be used as a tool for environmental quality management. Soil gibbsite with a log *Ks of 8.29 at 25°C together with a pH dependent loading function that uses molar Al/C ratios describes the amount of aluminum in solution in the presence of organic matter if the pH is roughly above 6.0.

  6. Surface Drift in the South-East Atlantic Ocean | Wedepohl | African ...

    African Journals Online (AJOL)

    Surface drift in the South-East Atlantic Ocean is described using historical shipdrift data. The Benguela Current has a width of 200 km in the south and 750 km in the north. The mean speeds of the current vary from <11 cm.s-1 to a maximum of 23 cm.s-1. The highest current speeds occur during summer in the southern ...

  7. An Overview of the Naval Research Laboratory Ocean Surface Flux (NFLUX) System

    Science.gov (United States)

    May, J. C.; Rowley, C. D.; Barron, C. N.

    2016-02-01

    The Naval Research Laboratory (NRL) ocean surface flux (NFLUX) system is an end-to-end data processing and assimilation system used to provide near-real time satellite-based surface heat flux fields over the global ocean. Swath-level air temperature (TA), specific humidity (QA), and wind speed (WS) estimates are produced using multiple polynomial regression algorithms with inputs from satellite sensor data records from the Special Sensor Microwave Imager/Sounder, the Advanced Microwave Sounding Unit-A, the Advanced Technology Microwave Sounder, and the Advanced Microwave Scanning Radiometer-2 sensors. Swath-level WS estimates are also retrieved from satellite environmental data records from WindSat, the MetOp scatterometers, and the Oceansat scatterometer. Swath-level solar and longwave radiative flux estimates are produced utilizing the Rapid Radiative Transfer Model for Global Circulation Models (RRTMG). Primary inputs to the RRTMG include temperature and moisture profiles and cloud liquid and ice water paths from the Microwave Integrated Retrieval System. All swath-level satellite estimates undergo an automated quality control process and are then assimilated with atmospheric model forecasts to produce 3-hourly gridded analysis fields. The turbulent heat flux fields, latent and sensible heat flux, are determined from the Coupled Ocean-Atmosphere Response Experiment (COARE) 3.0 bulk algorithms using inputs of TA, QA, WS, and a sea surface temperature model field. Quality-controlled in situ observations over a one-year time period from May 2013 through April 2014 form the reference for validating ocean surface state parameter and heat flux fields. The NFLUX fields are evaluated alongside the Navy's operational global atmospheric model, the Navy Global Environmental Model (NAVGEM). NFLUX is shown to have smaller biases and lower or similar root mean square errors compared to NAVGEM.

  8. Evaluation of fitting functions for the representation of an O(3P)+H2 potential energy surface. I

    International Nuclear Information System (INIS)

    Wagner, A.F.; Schatz, G.C.; Bowman, J.M.

    1981-01-01

    The DIM surface of Whitlock, Muckerman, and Fisher for the O( 3 P)+H 2 system is used as a test case to evaluate the usefulness of a variety of fitting functions for the representation of potential energy surfaces. Fitting functions based on LEPS, BEBO, and rotated Morse oscillator (RMO) forms are examined. Fitting procedures are developed for combining information about a small portion of the surface and the fitting function to predict where on the surface more information must be obtained to improve the accuracy of the fit. Both unbiased procedures and procedures heavily biased toward the saddle point region of the surface are investigated. Collinear quasiclassical trajectory calculations of the reaction rate constant and one and three dimensional transition state theory rate constant calculations are performed and compared for selected fits and the exact DIM test surface. Fitting functions based on BEBO and RMO forms are found to give quite accurate results

  9. KARIN: The Ka-Band Radar Interferometer for the Proposed Surface Water and Ocean Topography (SWOT) Mission

    Science.gov (United States)

    Esteban-Fernandez, Daniel; Peral, Eva; McWatters, Dalia; Pollard, Brian; Rodriguez, Ernesto; Hughes, Richard

    2013-01-01

    Over the last two decades, several nadir profiling radar altimeters have provided our first global look at the ocean basin-scale circulation and the ocean mesoscale at wavelengths longer than 100 km. Due to sampling limitations, nadir altimetry is unable to resolve the small wavelength ocean mesoscale and sub-mesoscale that are responsible for the vertical mixing of ocean heat and gases and the dissipation of kinetic energy from large to small scales. The proposed Surface Water and Ocean Topography (SWOT) mission would be a partnership between NASA, CNES (Centre National d'Etudes Spaciales) and the Canadian Space Agency, and would have as one of its main goals the measurement of ocean topography with kilometer-scale spatial resolution and centimeter scale accuracy. In this paper, we provide an overview of all ocean error sources that would contribute to the SWOT mission.

  10. The Surface Ocean Carbon Dioxide Atlas (SOCAT) - A Solid Data Base for Carbon Related Research

    Science.gov (United States)

    Steinhoff, T.; Bakker, D. C. E.; Wanninkhof, R. H.; Currie, K.; Landa, C.; Landschutzer, P.; Metzl, N.; Nakaoka, S. I.; Nojiri, Y.; O'Brien, K.; Olsen, A.; Pfeil, B.; Schuster, U.; Smith, K. M.; Tilbrook, B. D.

    2016-02-01

    The Surface Ocean CO2 Atlas (SOCAT) is an activity by the international marine carbon research community. It improves access to surface water CO2 data by regular releases of quality controlled and documented, synthesis fCO2 (fugacity of carbon dioxide) data products for the global surface oceans and coastal seas. The first version of SOCAT was publicly released in September 2011(Bakker et al., 2011) with 6.3 million observations. In June 2013 version 2 was released including already over 10 million observations and in September 2015 SOCAT version 3 was released with more than 14 million observations. With the release of version 3 in September 2015 a big step was made in the direction of an annual updated database by using an automated data ingestion and quality control tool. The database holds now data from 1957 to today which enables SOCAT data products the detection of changes in the ocean carbon sink. Here we present the innovations in version 3 and give an outlook of the next version(s) of SOCAT. A major improvement in version 3 is the inclusion of data from alternative sensors with a lower accuracy (better than 10 µatm) compared to the standard instrumentation (2 µatm), since their number will increase in the future. In addition exemplary studies using the SOCAT database will be presented which demonstrate the potential of the SOCAT database and point out possible improvements for the future.

  11. The corrosion of steam generator surfaces under typical secondary coolant conditions: effects of pH excusions on the alloy surface composition

    Energy Technology Data Exchange (ETDEWEB)

    McIntyre, N.S.; Davidson, R.D.; Walzak, T.L. [University of Western Ontario, London, ON (Canada); Brennenstuhl, A.M.; Gonzalez, F.; Corazza, S. [Ontario Hydro, Toronto, ON (Canada)

    1995-07-01

    Specimens of Inconel 600 (I-600), Inconel 690 (I-690), Incoloy 800 (I-800) and Monel 400 (M-400) were exposed to high temperature steam generator water conditions typical of those which might be found when the secondary coolant pH is allowed to fall into the acid regime. The specimens were analysed by surface and electrochemical techniques, either directly following exposure in the acid medium steam generator coolant or after adjusting the coolant pH and chemistry to near-normal steam generator conditions. The initial acid exposure resulted in the growth of a chromium-rich surface corrosion product film on all alloys (except M-400) and the precipitation of nickel-rich sulphates. Following the return to a high pH, the alloy again had chromium-rich surface oxides but also exhibited sulphide crystallites adhering to the base oxide, particularly for I-600. The tendency to retain these sulphides is attributed to the porosity of the protective oxide through which nickel is transported to the solution. The conversion of sulphate-sulphide is believed to occur as the pH is raised to normal alkaline conditions. In the case of M-400, a chromium oxide layer is not available to restrict the transport of nickel to the solution. As a result, a thick layer of sulphide crystals grows on the surface of the M-400 alloy even when subjected to a mild acid pH excursion. Even trace concentrations of sulphide/sulphate under normal pH control are shown to react with alloys whose oxide films appear permeable to nickel transport. (Author).

  12. Unveiling the role and life strategies of viruses from the surface to the dark ocean

    KAUST Repository

    Lara, Elena

    2017-09-07

    Viruses are a key component of marine ecosystems, but the assessment of their global role in regulating microbial communities and the flux of carbon is precluded by a paucity of data, particularly in the deep ocean. We assessed patterns in viral abundance and production and the role of viral lysis as a driver of prokaryote mortality, from surface to bathypelagic layers, across the tropical and subtropical oceans. Viral abundance showed significant differences between oceans in the epipelagic and mesopelagic, but not in the bathypelagic, and decreased with depth, with an average power-law scaling exponent of −1.03 km−1 from an average of 7.76 × 106 viruses ml−1 in the epipelagic to 0.62 × 106 viruses ml−1 in the bathypelagic layer with an average integrated (0 to 4000 m) viral stock of about 0.004 to 0.044 g C m−2, half of which is found below 775 m. Lysogenic viral production was higher than lytic viral production in surface waters, whereas the opposite was found in the bathypelagic, where prokaryotic mortality due to viruses was estimated to be 60 times higher than grazing. Free viruses had turnover times of 0.1 days in the bathypelagic, revealing that viruses in the bathypelagic are highly dynamic. On the basis of the rates of lysed prokaryotic cells, we estimated that viruses release 145 Gt C year−1 in the global tropical and subtropical oceans. The active viral processes reported here demonstrate the importance of viruses in the production of dissolved organic carbon in the dark ocean, a major pathway in carbon cycling.

  13. Rapid removal of plutonium from the oceanic surface layer by zooplankton faecal pellets

    International Nuclear Information System (INIS)

    Higgo, J.J.W.; Cherry, R.D.; Heyraud, M.; Fowler, S.W.

    1977-01-01

    In view of the possibility that increasing quantities of Pu may in due course be introduced into the marine environment, it is important to have a detailed knowledge of its oceanic behaviour. It has been suggested that algae and perhaps the phytoplanktonic mass may have an important role in determining the chemical and physical forms of Pu predominant in the ocean. The role of the zooplanktonic mass has not been investigated in detail, but it is known that for several elements zooplankton metabolism may be an important biological factor in the removal of elements from the surface layers of the ocean. The particular importance of zooplankton faecal pellets in this process has been stressed, and it has been found that M. norvegica is rich in the naturally-occurring α-emitter 210 Po when compared with whole organism levels. A study is here described for Pu, and it is reported that M. norvegica faecal pellets are relatively rich in Pu. It is suggested that zooplankton faecal pellet deposition might be an important vector in the vertical oceanic transport of this element. Experimental details are given and results are shown in tabular form. The implications of the high concentrations of Pu in faecal pellets are described, and rough estimates are made for the removal time of Pu from the upper mixed ocean layers by zooplankton pellets alone; the result is 3.6 years. It is suggested that faecal pellets may have a significant role in the removal of Pu from the surface layers of the sea. (U.K.)

  14. Conformational study of protein interactions with hydrogen-passivated amorphous silicon surfaces: Effect of pH

    Science.gov (United States)

    Brahmi, Yamina; Filali, Larbi; Sib, Jamal Dine; Bouhekka, Ahmed; Benlakehal, Djamel; Bouizem, Yahya; Kebab, Aissa; Chahed, Larbi

    2017-11-01

    The adsorption of Bovine Serum Albumin (BSA) proteins on amorphous silicon (a-Si) surfaces was studied with respect to solution pH. Thin films of a-Si were deposited using radio-frequency magnetron sputtering at room temperature and then treated in a hydrogen ambient to form a hydrogenated a-Si surface layer (a-Si:H). The interactions of the as-deposited and hydrogenated surfaces with the proteins at neutral, acidic, and basic environments was probed by means of Fourier transform infrared attenuated total reflection (FTIR-ATR) spectroscopy, Spectroscopic Ellipsometry (SE), and Atomic Force Microscopy (AFM), to study the influence of the charge of proteins on their adsorption and conformation on the a-Si:H surface, compared with the a-Si surface. The results show that the charge of the proteins has a significant effect on their interactions with these two substrates but in dissimilar ways. For the as-deposited substrate, these interactions are predictably coulombic since the surface is charged. For the hydrogenated substrate, the adsorption of the proteins depends on their conformation which is heavily affected by pH, and the size of their footprint (adsorption mode) on the surface.

  15. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from S. A. AGULHAS in the Indian Ocean, South Atlantic Ocean and Southern Oceans from 2009-01-26 to 2011-01-10 (NODC Accession 0081024)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0081024 includes Surface underway, chemical, meteorological and physical data collected from S. A. AGULHAS in the Indian Ocean, South Atlantic Ocean...

  16. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from surface underway observations using Barometric pressure sensor, Carbon dioxide (CO2) gas analyzer and other instruments from Hakuho Maru in the Indian Ocean, South Atlantic Ocean and Southern Oceans from 2009-12-16 to 2010-01-26 (NCEI Accession 0163190)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0163190 includes chemical, meteorological, physical and surface underway data collected from Hakuho Maru in the Indian Ocean, South Atlantic Ocean and...

  17. Interaction between surface wind and ocean circulation in the Carolina Capes in a coupled low-order model

    Energy Technology Data Exchange (ETDEWEB)

    Xie, L.; Pietrafesa, L.J.; Raman, S.

    1997-03-18

    Interactions between surface winds and ocean currents over an east-coast continental shelf are studied using a simple mathematical model. The model physics include cross-shelf advection of sea surface temperature (SST) by Ekman drift, upwelling due to Ekman transport divergence, differential heating of the low-level atmosphere by a cross-shelf SST gradient, and the Coriolis effect. Additionally, the effects of diabatic cooling of surface waters due to air-sea heat exchange and of the vertical density stratification on the thickness of the upper ocean Ekman layer are considered. The model results are qualitatively consistent with observed wind-driven coastal ocean circulation and surface wind signatures induced by SST. This simple model also demonstrates that two-way air-sea interaction plays a significant role in the subtidal frequency variability of coastal ocean circulation and mesoscale variability of surface wind fields over coastal waters.

  18. Biofilm three-dimensional architecture influences in situ pH distribution pattern on the human enamel surface.

    Science.gov (United States)

    Xiao, Jin; Hara, Anderson T; Kim, Dongyeop; Zero, Domenick T; Koo, Hyun; Hwang, Geelsu

    2017-06-01

    To investigate how the biofilm three-dimensional (3D) architecture influences in situ pH distribution patterns on the enamel surface. Biofilms were formed on human tooth enamel in the presence of 1% sucrose or 0.5% glucose plus 0.5% fructose. At specific time points, biofilms were exposed to a neutral pH buffer to mimic the buffering of saliva and subsequently pulsed with 1% glucose to induce re-acidification. Simultaneous 3D pH mapping and architecture of intact biofilms was performed using two-photon confocal microscopy. The enamel surface and mineral content characteristics were examined successively via optical profilometry and microradiography analyses. Sucrose-mediated biofilm formation created spatial heterogeneities manifested by complex networks of bacterial clusters (microcolonies). Acidic regions (pHinterior of microcolonies, which impedes rapid neutralization (taking more than 120 min for neutralization). Glucose exposure rapidly re-created the acidic niches, indicating formation of diffusion barriers associated with microcolonies structure. Enamel demineralization (white spots), rougher surface, deeper lesion and more mineral loss appeared to be associated with the localization of these bacterial clusters at the biofilm-enamel interface. Similar 3D architecture was observed in plaque-biofilms formed in vivo in the presence of sucrose. The formation of complex 3D architectures creates spatially heterogeneous acidic microenvironments in close proximity of enamel surface, which might correlate with the localized pattern of the onset of carious lesions (white spot like) on teeth.

  19. Remote sensing of ocean surface currents: a review of what is being observed and what is being assimilated

    Science.gov (United States)

    Isern-Fontanet, Jordi; Ballabrera-Poy, Joaquim; Turiel, Antonio; García-Ladona, Emilio

    2017-10-01

    Ocean currents play a key role in Earth's climate - they impact almost any process taking place in the ocean and are of major importance for navigation and human activities at sea. Nevertheless, their observation and forecasting are still difficult. First, no observing system is able to provide direct measurements of global ocean currents on synoptic scales. Consequently, it has been necessary to use sea surface height and sea surface temperature measurements and refer to dynamical frameworks to derive the velocity field. Second, the assimilation of the velocity field into numerical models of ocean circulation is difficult mainly due to lack of data. Recent experiments that assimilate coastal-based radar data have shown that ocean currents will contribute to increasing the forecast skill of surface currents, but require application in multidata assimilation approaches to better identify the thermohaline structure of the ocean. In this paper we review the current knowledge in these fields and provide a global and systematic view of the technologies to retrieve ocean velocities in the upper ocean and the available approaches to assimilate this information into ocean models.

  20. Remote sensing of ocean surface currents: a review of what is being observed and what is being assimilated

    Directory of Open Access Journals (Sweden)

    J. Isern-Fontanet

    2017-10-01

    Full Text Available Ocean currents play a key role in Earth's climate – they impact almost any process taking place in the ocean and are of major importance for navigation and human activities at sea. Nevertheless, their observation and forecasting are still difficult. First, no observing system is able to provide direct measurements of global ocean currents on synoptic scales. Consequently, it has been necessary to use sea surface height and sea surface temperature measurements and refer to dynamical frameworks to derive the velocity field. Second, the assimilation of the velocity field into numerical models of ocean circulation is difficult mainly due to lack of data. Recent experiments that assimilate coastal-based radar data have shown that ocean currents will contribute to increasing the forecast skill of surface currents, but require application in multidata assimilation approaches to better identify the thermohaline structure of the ocean. In this paper we review the current knowledge in these fields and provide a global and systematic view of the technologies to retrieve ocean velocities in the upper ocean and the available approaches to assimilate this information into ocean models.

  1. Distribution of benthic foraminifers (>125 um) in the surface sediments of the Arctic Ocean

    Science.gov (United States)

    Osterman, Lisa E.; Poore, Richard Z.; Foley, Kevin M.

    1999-01-01

    Census data on benthic foraminifers (>125 ?m) in surface sediment samples from 49 box cores are used to define four depth-controlled biofacies, which will aid in the paleoceanographic reconstruction of the Arctic Ocean. The shelf biofacies contains a mix of shallow-water calcareous and agglutinated species from the continental shelves of the Beaufort and Chukchi Seas and reflects the variable sedimentologic and oceanic conditions of the Arctic shelves. The intermediate-depth calcareous biofacies, found between 500 and 1,100 meters water depth (mwd), contains abundant Cassidulina teretis , presumably indicating the influence of Atlantic-derived water at this depth. In water depths between 1,100 and 3,500 m, a deepwater calcareous biofacies contains abundant Oridorsalis umbonatus . Below 3,500 mwd, the deepwater mixed calcareous/agglutinated biofacies of the Canada, Makarov, and Eurasian Basins reflects a combination of low productivity, dissolution, and sediment transport. Two other benthic foraminiferal species show specific environmental preferences. Fontbotia wuellerstorfi has a depth distribution between 900 and 3,500 mwd, but maximum abundance occurs in the region of the Mendeleyev Ridge. The elevated abundance of F. wuellerstorfi may be related to increased food supply carried by a branch of Atlantic water that crosses the Lomonosov Ridge near the Russian Continental Shelf. Triloculina frigida is recognized to be a species preferring lower slope sediments commonly disturbed by turbidites and bottom currents. INTRODUCTION At present, our understanding of the Arctic Ocean lags behind our understanding of other oceans, and fundamental questions still exist about its role in and response to global climate change. The Arctic Ocean is particularly sensitive to climatic fluctuations because small changes in the amounts of sea-ice cover can alter global albedo and thermohaline circulation (Aagaard and Carmack, 1994). Numerous questions still exist regarding the nature

  2. Intraseasonal Variability of the Equatorial Indian Ocean Observed from Sea Surface Height, Wind, and Temperature Data

    Science.gov (United States)

    Fu, Lee-Lueng

    2007-01-01

    The forcing of the equatorial Indian Ocean by the highly periodic monsoon wind cycle creates many interesting intraseasonal variabilities. The frequency spectrum of the wind stress observations from the European Remote Sensing Satellite scatterometers reveals peaks at the seasonal cycle and its higher harmonics at 180, 120, 90, and 75 days. The observations of sea surface height (SSH) from the Jason and Ocean Topography Experiment (TOPEX)/Poseidon radar altimeters are analyzed to study the ocean's response. The focus of the study is on the intraseasonal periods shorter than the annual period. The semiannual SSH variability is characterized by a basin mode involving Rossby waves and Kelvin waves traveling back and forth in the equatorial Indian Ocean between 10(deg)S and 10(deg)N. However, the interference of these waves with each other masks the appearance of individual Kelvin and Rossby waves, leading to a nodal point (amphidrome) of phase propagation on the equator at the center of the basin. The characteristics of the mode correspond to a resonance of the basin according to theoretical models. The theory also calls for similar modes at 90 and 60 days.

  3. Overview and preliminary results of the Surface Ocean Aerosol Production (SOAP campaign

    Directory of Open Access Journals (Sweden)

    C. S. Law

    2017-11-01

    Full Text Available Establishing the relationship between marine boundary layer (MBL aerosols and surface water biogeochemistry is required to understand aerosol and cloud production processes over the remote ocean and represent them more accurately in earth system models and global climate projections. This was addressed by the SOAP (Surface Ocean Aerosol Production campaign, which examined air–sea interaction over biologically productive frontal waters east of New Zealand. This overview details the objectives, regional context, sampling strategy and provisional findings of a pilot study, PreSOAP, in austral summer 2011 and the following SOAP voyage in late austral summer 2012. Both voyages characterized surface water and MBL composition in three phytoplankton blooms of differing species composition and biogeochemistry, with significant regional correlation observed between chlorophyll a and DMSsw. Surface seawater dimethylsulfide (DMSsw and associated air–sea DMS flux showed spatial variation during the SOAP voyage, with maxima of 25 nmol L−1 and 100 µmol m−2 d−1, respectively, recorded in a dinoflagellate bloom. Inclusion of SOAP data in a regional DMSsw compilation indicates that the current climatological mean is an underestimate for this region of the southwest Pacific. Estimation of the DMS gas transfer velocity (kDMS by independent techniques of eddy covariance and gradient flux showed good agreement, although both exhibited periodic deviations from model estimates. Flux anomalies were related to surface warming and sea surface microlayer enrichment and also reflected the heterogeneous distribution of DMSsw and the associated flux footprint. Other aerosol precursors measured included the halides and various volatile organic carbon compounds, with first measurements of the short-lived gases glyoxal and methylglyoxal in pristine Southern Ocean marine air indicating an unidentified local source. The application of a real-time clean sector

  4. Vertical eddy diffusion as a key mechanism for removing perfluorooctanoic acid (PFOA) from the global surface oceans

    NARCIS (Netherlands)

    Lohmann, R.; Jurado Cojo, E.; Dijkstra, H.A.; Dachs, J.

    2013-01-01

    Here we estimate the importance of vertical eddy diffusion in removing perfluorooctanoic acid (PFOA) from the surface Ocean and assess its importance as a global sink. Measured water column profiles of PFOA were reproduced by assuming that vertical eddy diffusion in a 3-layer ocean model is the sole

  5. Statistical investigation of surface bound ions and further development of BION server to include pH and salt dependence.

    Science.gov (United States)

    Petukh, Marharyta; Zhang, Min; Alexov, Emil

    2015-12-15

    Ions are engaged in multiple biological processes in cells. By binding to the macromolecules or being mobile in the solvent, they maintain the integrity of the structure of macromolecules; participate in their enzymatic activity; or screen electrostatic interactions. While experimental methods are not always able to assign the exact location of ions, computational methods are in demand. Although the majority of computational methods are successful in predicting the position of ions buried inside macromolecules, they are less effective in deciphering positions of surface bound ions. Here, we propose the new BION algorithm (http://compbio.clemson.edu/bion_server_ph/) that predicts the location of the surface bound ions. It is more efficient and accurate compared to the previous version since it uses more advanced clustering algorithm in combination with pairing rules. In addition, the BION webserver allows specifying the pH and the salt concentration in predicting ions positions. © 2015 Wiley Periodicals, Inc.

  6. Rheologic Profile, Specific Gravity, Surface Tension, and pH of Fifteen Over-the-Counter Preparations.

    Science.gov (United States)

    Al-Achi, Antoine; Baghat, Tushar; Chukwubeze, Onah; Dembla, Ishwin

    2007-01-01

    Knowledge of the physical characteristics of commercially available over-the-counter preparations can aid the compounding pharmacist in preparing medication. In this study, 15 over-the-counter products were studied with regard to their specific gravity, surface tension, pH, and rheologic profile. The specific gravities of all the products were greater than 1, with the exceptions of Nivea Lotion and rubbing alcohol, which were less than 1. The majority of the products had an acidic pH. With the exception of two products, Citrucel and Chloraseptic, all products demonstrated a surface tension value less than that of water (72.8 dynes/cm). Chloraseptic had the lowest Newtonian viscosity (1.27 cPs), whereas Vicks DayQuil had the highest (098.86 cPs). Citrucel exhibited dilatant-type flow; Suave Shampoo, herbal shampoo, Tangerine Tickle Herbal Shampoo, and Metamucil pseudoplastic flow; the remaining non-Newtonian formulations, plastic flow profiles.

  7. Possibilities of new materials surface sensibility express determination based on ZnSe-CdS system by pH isoelectric state measurements of the surface state

    Science.gov (United States)

    Kirovskaya, I. A.; Mironova, E. V.; Ushakov, O. V.; Nor, P. E.; Yureva, A. V.; Matyash, Yu I.

    2018-01-01

    A method for determining the hydrogen index of the surfaces isoelectric state (pHiso) at various gases pressures -possible components of the surrounding and technological media has been developed. With its use, changes in pH of binary and more complex semiconductors-components of the new system-ZnSe-CdS under the influence of nitrogen dioxide-have been found. The limiting sensitivity of surfaces - minimum PNO2, causing a change in pH has been estimated. The most active components of ZnSe-CdS system, recommended as materials for measuring cells of NO2, have been revealed. The relationship between the changing patterns with the composition of surface (acid-base) and bulk (in particular, theoretical calculated crystal density) properties has been established, allowing to find the most effective materials for sensor technology and for semiconductor analysis.

  8. Distribution of surface plastic debris in the eastern Pacific Ocean from an 11-year data set.

    Science.gov (United States)

    Law, Kara Lavender; Morét-Ferguson, Skye E; Goodwin, Deborah S; Zettler, Erik R; Deforce, Emelia; Kukulka, Tobias; Proskurowski, Giora

    2014-05-06

    We present an extensive survey of floating plastic debris in the eastern North and South Pacific Oceans from more than 2500 plankton net tows conducted between 2001 and 2012. From these data we defined an accumulation zone (25 to 41 °N, 130 to 180 °W) in the North Pacific subtropical gyre that closely corresponds to centers of accumulation resulting from the convergence of ocean surface currents predicted by several oceanographic numerical models. Maximum plastic concentrations from individual surface net tows exceeded 10(6) pieces km(-2), with concentrations decreasing with increasing distance from the predicted center of accumulation. Outside the North Pacific subtropical gyre the median plastic concentration was 0 pieces km(-2). We were unable to detect a robust temporal trend in the data set, perhaps because of confounded spatial and temporal variability. Large spatiotemporal variability in plastic concentration causes order of magnitude differences in summary statistics calculated over short time periods or in limited geographic areas. Utilizing all available plankton net data collected in the eastern Pacific Ocean (17.4 °S to 61.0 °N; 85.0 to 180.0 °W) since 1999, we estimated a minimum of 21,290 t of floating microplastic.

  9. Chemical characterization of detrital sugar chains with peptides in oceanic surface particulate organic matter

    Science.gov (United States)

    Tsukasaki, A.; Nishida, T.; Tanoue, E.

    2016-02-01

    For better understanding of the dynamics of organic matter in the ocean interior, particulate organic matter (POM) in oceanic surface water is a key material as a starting material in food chain and biological carbon pump, and the source of dissolved organic matter. POM consists of a mixture of non-living POM (detritus) and small amount of living POM (organisms). Particulate combined amino acids (PCAAs) are one of the major components of POM and the most important source of nitrogen and carbon for heterotrophic organisms in marine environments. In our previous studies of molecular-level characterization of PCAAs using electrophoretic separation (SDS-PAGE: sodium dodecyl sulfate-polyacrylamide gel electrophoresis) with specific detection of protein/peptide and sugar chains, we reported that most of PCAAs existed as small-sized peptide chains with carbohydrate-rich remnants. Although carbohydrates are one of the major carbon components of POM, the details of molecular-level structures including sugar chains are unknown. In this study, we applied electrophoretic separation for sugar chains (FACE: fluorophore-assisted carbohydrate electrophoresis) to the POM samples collected from the surface water of the Pacific Ocean. The results showed that sugar chains with various degree of polymerization were detected in POM. The possible roles of such sugar chains in marine biogeochemical cycle of organic matter are discussed in the presentation.

  10. Observations and simulations of microplastic marine debris in the ocean surface boundary layer

    Science.gov (United States)

    Kukulka, T.; Brunner, K.; Proskurowski, G. K.; Lavender Law, K. L.

    2016-02-01

    Motivated by observations of buoyant microplastic marine debris (MPMD) in the ocean surface boundary layer (OSBL), this study applies a large eddy simulation model and a parametric one-dimensional column model to examine vertical distributions of MPMD. MPMD is widely distributed in vast regions of the subtropical gyres and has emerged as a major open ocean pollutant whose distribution is subject to upper ocean turbulence. The models capture wind-driven turbulence, Langmuir turbulence (LT), and enhanced turbulent kinetic energy input due to breaking waves (BW). Model results are only consistent with MPMD observations if LT effects are included. Neither BW nor shear-driven turbulence is capable of deeply submerging MPMD, suggesting that the observed vertical MPMD distributions are a characteristic signature of wave-driven LT. Thus, this study demonstrates that LT substantially increases turbulent transport in the OSBL, resulting in deep submergence of buoyant tracers. The parametric model is applied to eleven years of observations in the North Atlantic and North Pacific subtropical gyres to show that surface measurements substantially underestimate MPMD concentrations by a factor of three to thirteen.

  11. High colored dissolved organic matter (CDOM) absorption in surface waters of the central-eastern Arctic Ocean: Implications for biogeochemistry and ocean color algorithms.

    Science.gov (United States)

    Gonçalves-Araujo, Rafael; Rabe, Benjamin; Peeken, Ilka; Bracher, Astrid

    2018-01-01

    As consequences of global warming sea-ice shrinking, permafrost thawing and changes in fresh water and terrestrial material export have already been reported in the Arctic environment. These processes impact light penetration and primary production. To reach a better understanding of the current status and to provide accurate forecasts Arctic biogeochemical and physical parameters need to be extensively monitored. In this sense, bio-optical properties are useful to be measured due to the applicability of optical instrumentation to autonomous platforms, including satellites. This study characterizes the non-water absorbers and their coupling to hydrographic conditions in the poorly sampled surface waters of the central and eastern Arctic Ocean. Over the entire sampled area colored dissolved organic matter (CDOM) dominates the light absorption in surface waters. The distribution of CDOM, phytoplankton and non-algal particles absorption reproduces the hydrographic variability in this region of the Arctic Ocean which suggests a subdivision into five major bio-optical provinces: Laptev Sea Shelf, Laptev Sea, Central Arctic/Transpolar Drift, Beaufort Gyre and Eurasian/Nansen Basin. Evaluating ocean color algorithms commonly applied in the Arctic Ocean shows that global and regionally tuned empirical algorithms provide poor chlorophyll-a (Chl-a) estimates. The semi-analytical algorithms Generalized Inherent Optical Property model (GIOP) and Garver-Siegel-Maritorena (GSM), on the other hand, provide robust estimates of Chl-a and absorption of colored matter. Applying GSM with modifications proposed for the western Arctic Ocean produced reliable information on the absorption by colored matter, and specifically by CDOM. These findings highlight that only semi-analytical ocean color algorithms are able to identify with low uncertainty the distribution of the different optical water constituents in these high CDOM absorbing waters. In addition, a clustering of the Arctic Ocean

  12. Arctic surface temperatures from Metop AVHRR compared to in situ ocean and land data

    Directory of Open Access Journals (Sweden)

    G. Dybkjær

    2012-11-01

    Full Text Available The ice surface temperature (IST is an important boundary condition for both atmospheric and ocean and sea ice models and for coupled systems. An operational ice surface temperature product using satellite Metop AVHRR infra-red data was developed for MyOcean. The IST can be mapped in clear sky regions using a split window algorithm specially tuned for sea ice. Clear sky conditions prevail during spring in the Arctic, while persistent cloud cover limits data coverage during summer. The cloud covered regions are detected using the EUMETSAT cloud mask. The Metop IST compares to 2 m temperature at the Greenland ice cap Summit within STD error of 3.14 °C and to Arctic drifting buoy temperature data within STD error of 3.69 °C. A case study reveals that the in situ radiometer data versus satellite IST STD error can be much lower (0.73 °C and that the different in situ measurements complicate the validation. Differences and variability between Metop IST and in situ data are analysed and discussed. An inter-comparison of Metop IST, numerical weather prediction temperatures and in situ observation indicates large biases between the different quantities. Because of the scarcity of conventional surface temperature or surface air temperature data in the Arctic, the satellite IST data with its relatively good coverage can potentially add valuable information to model analysis for the Arctic atmosphere.

  13. A simple mathematical model to predict sea surface temperature over the northwest Indian Ocean

    Science.gov (United States)

    Noori, Roohollah; Abbasi, Mahmud Reza; Adamowski, Jan Franklin; Dehghani, Majid

    2017-10-01

    A novel and simple mathematical model was developed in this study to enhance the capacity of a reduced-order model based on eigenvectors (RMEV) to predict sea surface temperature (SST) in the northwest portion of the Indian Ocean, including the Persian and Oman Gulfs and Arabian Sea. Developed using only the first two of 12,416 possible modes, the enhanced RMEV closely matched observed daily optimum interpolation SST (DOISST) values. Spatial distribution of the first mode indicated the greatest variations in DOISST occurred in the Persian Gulf. Also, the slightly increasing trend in the temporal component of the first mode observed in the study area over the last 34 years properly reflected the impact of climate change and rising DOISST. Given its simplicity and high level of accuracy, the enhanced RMEV can be applied to forecast DOISST in oceans, which the poor forecasting performance and large computational-time of other numerical models may not allow.

  14. Sea surface temperature (SST) and surface current data collected from the Mar Mostro during the around-the-world Volvo Ocean Race (VOR) from 2011-11-05 to 2012-07-12 (NCEI Accession 0130694)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Navigation, surface current, sea surface temperature, wind, and atmospheric pressure data collected by the Mar Mostro during the around-the-world Volvo Ocean Race...

  15. Surfactant-Associated Bacteria in the Near Surface Layer of the Ocean

    Science.gov (United States)

    Kurata, Naoko; Vella, Katie; Soloviev, Alexander; Matt, Silvia; Tartar, Aurelien; Shivji, Mahmood; Perrie, William

    2013-04-01

    It has recently been realized that biogeochemical processes in the ocean are, to a large extent, the result of nanoscale processes in the microbial part of the pelagic food web. Bacteria found in thin near-surface layers of the ocean - bacterioneuston - are of special interest due to a number of practical applications, including air-sea gas exchange, production of climate-active marine aerosols and remote sensing of the ocean. In particular, bacteria involved in the production of the surface active materials resulting in slicks on the sea surface can potentially be observed from space using high-resolution remote sensing techniques. In this work done by a multidisciplinary team, we demonstrate a direct connection between surfactant-associated bacteria, identified with an advanced DNA analysis, and fine-scale features on the sea surface in synthetic aperture radar (SAR) imagery. Experiments were conducted in the Straits of Florida during RASRASAT 2 satellite overpasses. The sea surface microlayer sampling method was designed to enable aseptic bacterial sampling. A 47 mm polycarbonate membrane was utilized at each sampling site to obtain a snapshot of the bacteria community structure at a specific space and time. Microbial composition was determined using DNA analysis of 16S rRNA genes. A new generation high-throughput sequencing method (454) was employed to compensate for the small sample size. A total of 27,006 nucleotide sequences with an average 437.8 bp in length were analyzed. From in situ samples taken during satellite overpasses, we found a higher abundance of surfactant-associated bacteria in slick (visible in SAR from space) as compared to non-slick areas; furthermore, higher abundance of this type of bacteria was observed in subsurface samples than in those taken from the sea surface. These observations suggest that surfactants are produced by marine bacteria mostly in the water column and migrate up to the sea surface by diffusion, air bubbles, or

  16. Remote sensing of global surface shortwave radiation and PAR over the ocean

    Science.gov (United States)

    Gautier, Catherine H.; Byers, Michael L.

    1992-12-01

    During the past few years many methods have been proposed for estimating surface radiative fluxes (shortwave radiation, photosynthetically active radiation - PAR) from satellite observations. We have developed algorithms for computing the shortwave radiative flux (shortwave irradiance) at the ocean surface from visible radiance observations and they have been found to be quite successful under most atmospheric and cloud conditions. For broken clouds, however, the simple plane parallel assumption for solving the radiative transfer equations may need to be corrected to account for cloud geometry. The estimation of PAR is simpler because the most commonly used satellite radiance measurements cover a similar region of the solar spectrum. We are in the process of producing global $ARDNSW and PAR as a contribution to the Sequoia 2000 project (to implement a distributed processing system designed for the needs of global change researchers). Results from our algorithms developed for Sequoia and preliminary global surface solar irradiance and PAR fields are presented and discussed.

  17. Drivers of Antarctic sea-ice expansion and Southern Ocean surface cooling over the past four decades

    Science.gov (United States)

    Purich, Ariaan; England, Matthew

    2017-04-01

    Despite global warming, total Antarctic sea-ice coverage has increased overall during the past four decades. In contrast, the majority of CMIP5 models simulate a decline. In addition, Southern Ocean surface waters have largely cooled, in stark contrast to almost all historical CMIP5 simulations. Subantarctic Surface Waters have cooled and freshened while waters to the north of the Antarctic Circumpolar Current have warmed and increased in salinity. It remains unclear as to what extent the cooling and Antarctic sea-ice expansion is due to natural variability versus anthropogenic forcing; due for example to changes in the Southern Annular Mode (SAM). It is also unclear what the respective role of surface buoyancy fluxes is compared to internal ocean circulation changes, and what the implications are for longer-term climate change in the region. In this presentation we will outline three distinct drivers of recent Southern Ocean surface trends that have each made a significant contribution to regional cooling: (1) wind-driven surface cooling and sea-ice expansion due to shifted westerly winds, (2) teleconnections of decadal variability from the tropical Pacific, and (3) surface cooling and ice expansion due to large-scale Southern Ocean freshening, most likely driven by SAM-related precipitation trends over the open ocean. We will also outline the main reasons why climate models for the most part miss these Southern Ocean cooling trends, despite capturing overall trends in the SAM.

  18. Modeling of the integrity of machining surfaces: application to the case of 15-5 PH stainless steel finish turning

    International Nuclear Information System (INIS)

    Mondelin, A.

    2012-01-01

    During machining, extreme conditions of pressure, temperature and strain appear in the cutting zone. In this thermo-mechanical context, the link between the cutting conditions (cutting speed, lubrication, feed rate, wear, tool coating...) and the machining surface integrity represents a major scientific target. This PhD study is a part of a global project called MIFSU (Modeling of the Integrity and Fatigue resistance of Machining Surfaces) and it focuses on the finish turning of the 15-5PH (a martensitic stainless steel used for parts of helicopter rotor). Firstly, material behavior has been studied in order to provide data for machining simulations. Stress-free dilatometry tests were conducted to obtain the austenitization kinetics of 15-5PH steel for high heating rates (up to 11,000 degrees C/s). Then, parameters of Leblond metallurgical model have been calibrated. In addition, dynamic compression tests (de/dt ranging from 0.01 to 80/s and e ≥ 1) have been performed to calibrate a strain-rate dependent elasto-plasticity model (for high strains). These tests also helped to highlight the dynamic recrystallization phenomena and their influence on the flow stress of the material. Thus, recrystallization model has also been implemented.In parallel, a numerical model for the prediction of machined surface integrity has been constructed. This model is based on a methodology called 'hybrid' (developed during the PhD thesis of Frederic Valiorgue for the AISI 304L steel). The method consists in replacing tool and chip modeling by equivalent loadings (obtained experimentally). A calibration step of these loadings has been carried out using orthogonal cutting and friction tests (with sensitivity studies of machining forces, friction and heat partition coefficients to cutting parameters variations).Finally, numerical simulations predictions of microstructural changes (austenitization and dynamic recrystallization) and residual stresses have been successfully compared with

  19. Optimization of free radical scavenging capacity and pH of Hylocereus polyrhizus peel by Response Surface Methodology

    Science.gov (United States)

    Putranto, A. W.; Dewi, S. R.; Puspitasari, Y.; Nuriah, F. A.

    2018-03-01

    Red dragon fruit (Hylocereus polyrhizus) peel, a by-product of juice processing, contains a high antioxidant that can be used for nutraceuticals. Hence, it is important to extract and investigate its antioxidant stability. The aim of this study was to optimize the free radical scavenging capacity and pH of H. polyrhizus peel extract using Central Composite Design (CCD) under Response Surface Methodology (RSM). The extraction of H. polyrhizus peel was done by using green-Pulsed Electric Field (PEF)-assisted extraction method. Factors optimized were electric field strength (kV/cm) and extraction time (seconds). The result showed that the correlation between responses (free radical-scavenging capacity and pH) and two factors was quadratic model. The optimum conditions was obtained at the electric field strength of 3.96 kV/cm, and treatment time of 31.9 seconds. Under these conditions, the actual free radical-scavenging capacity and pH were 75.86 ± 0.2 % and 4.8, respectively. The verification model showed that the actual values are in accordance with the predicted values, and have error rate values of free radical-scavenging capacity and pH responses were 0.1% and 3.98%, respectively. We suggest to extract the H. polyrhizus peel using a green and non-thermal extraction technology, PEF-assisted extraction, for research, food applications and nutraceuticals industry.

  20. Temperature, Salinity, Oxygen, Phosphate, pH and Alkalinity data collected in the North Atlantic Ocean, Baltic Sea, Barents Sea, Greenland Sea, North Sea, Norwegian Sea and White Sea from R/Vs Artemovsk, Atlantida, Okeanograf, Professor Rudovits, and ice observations, 1957 - 1995 (NODC Accession 0073674)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Temperature, Salinity, Oxygen, Phosphate, pH and Alkalinity data collected in the North Atlantic Ocean, Baltic Sea, Barents Sea, Greenland Sea, North Sea, Norwegian...

  1. Dependence of the cyanobacterium Prochlorococcus on hydrogen peroxide scavenging microbes for growth at the ocean's surface.

    Directory of Open Access Journals (Sweden)

    J Jeffrey Morris

    2011-02-01

    Full Text Available The phytoplankton community in the oligotrophic open ocean is numerically dominated by the cyanobacterium Prochlorococcus, accounting for approximately half of all photosynthesis. In the illuminated euphotic zone where Prochlorococcus grows, reactive oxygen species are continuously generated via photochemical reactions with dissolved organic matter. However, Prochlorococcus genomes lack catalase and additional protective mechanisms common in other aerobes, and this genus is highly susceptible to oxidative damage from hydrogen peroxide (HOOH. In this study we showed that the extant microbial community plays a vital, previously unrecognized role in cross-protecting Prochlorococcus from oxidative damage in the surface mixed layer of the oligotrophic ocean. Microbes are the primary HOOH sink in marine systems, and in the absence of the microbial community, surface waters in the Atlantic and Pacific Ocean accumulated HOOH to concentrations that were lethal for Prochlorococcus cultures. In laboratory experiments with the marine heterotroph Alteromonas sp., serving as a proxy for the natural community of HOOH-degrading microbes, bacterial depletion of HOOH from the extracellular milieu prevented oxidative damage to the cell envelope and photosystems of co-cultured Prochlorococcus, and facilitated the growth of Prochlorococcus at ecologically-relevant cell concentrations. Curiously, the more recently evolved lineages of Prochlorococcus that exploit the surface mixed layer niche were also the most sensitive to HOOH. The genomic streamlining of these evolved lineages during adaptation to the high-light exposed upper euphotic zone thus appears to be coincident with an acquired dependency on the extant HOOH-consuming community. These results underscore the importance of (indirect biotic interactions in establishing niche boundaries, and highlight the impacts that community-level responses to stress may have in the ecological and evolutionary outcomes for co

  2. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2011-12-30 to 2012-12-24 (NCEI Accession 0144349)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144349 includes Surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60...

  3. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2013-12-31 to 2014-12-20 (NCEI Accession 0144532)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144532 includes Surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60...

  4. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2007-12-30 to 2008-10-28 (NCEI Accession 0144348)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144348 includes Surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60...

  5. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2007-01-02 to 2007-12-22 (NCEI Accession 0144528)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144528 includes Surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60...

  6. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2002-12-29 to 2003-11-30 (NCEI Accession 0144351)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144351 includes Surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60...

  7. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2002-03-23 to 2002-12-23 (NCEI Accession 0148766)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0148766 includes Surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60...

  8. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2011-12-30 to 2012-12-23 (NCEI Accession 0148774)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0148774 includes Surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60...

  9. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2010-01-01 to 2011-12-19 (NCEI Accession 0148765)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0148765 includes Surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60...

  10. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2006-01-02 to 2006-12-26 (NCEI Accession 0148764)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0148764 includes Surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60...

  11. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2007-01-02 to 2007-12-20 (NCEI Accession 0148773)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0148773 includes Surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60...

  12. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2014-01-01 to 2014-12-20 (NCEI Accession 0145200)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0145200 includes Surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60...

  13. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2003-01-01 to 2003-12-29 (NCEI Accession 0148770)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0148770 includes Surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60...

  14. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2007-12-31 to 2008-10-27 (NCEI Accession 0148763)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0148763 includes Surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60...

  15. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2011-01-02 to 2011-12-18 (NCEI Accession 0148767)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0148767 includes Surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60...

  16. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2006-01-01 to 2006-12-27 (NCEI Accession 0144535)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144535 includes Surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60...

  17. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2002-03-07 to 2002-12-23 (NCEI Accession 0144356)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144356 includes Surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans (> 60...

  18. Sea surface salinity variability during the Indian Ocean Dipole and ENSO events in the tropical Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Grunseich, G.; Subrahmanyam, B.; Murty, V.S.N.; Giese, B.S.

    into the southwestern tropical Indian Ocean. The impact of concomitant La Niña with negative IOD is also large with an intense freshening in the southeastern Arabian Sea and salting off the northern Sumatra coast....

  19. Effect of concentration and pH on the surface-enhanced Raman scattering of captopril on nano-colloidal silver surface

    Science.gov (United States)

    Gao, Junxiang; Gu, Huaimin; Liu, Fangfang; Dong, Xiao; Xie, Min; Hu, Yongjun

    2011-07-01

    In this report, Raman and surface-enhanced Raman scattering (SERS) spectra of captopril are studied in detail. Herein, the Raman bands are assigned by the density functional theory (DFT) calculations and potential energy distributions (PED) based on internal coordinates of the molecule, which are found to be in good agree with the experimental values. Furthermore, the concentration and pH dependence of the SERS intensity of the molecule is discussed. By analyzing the intensities variation of SERS bands of the different concentrations of captopril solution, it can be concluded that the molecules orientation adsorbed on the silver nanoparticles surface change with the change of the concentrations. The variation of SERS spectra of captopril with the change of pH suggests that the interaction among the adsorbates with Ag cluster depend on the protonated state of the adsorbate and the aggregation of silver nanoparticles.

  20. Antagonistic Effects of Ocean Acidification and Rising Sea Surface Temperature on the Dissolution of Coral Reef Carbonate Sediments

    Directory of Open Access Journals (Sweden)

    Daniel Trnovsky

    2016-11-01

    Full Text Available Increasing atmospheric CO2 is raising sea surface temperature (SST and increasing seawater CO2 concentrations, resulting in a lower oceanic pH (ocean acidification; OA, which is expected to reduce the accretion of coral reef ecosystems. Although sediments comprise most of the calcium carbonate (CaCO3 within coral reefs, no in situ studies have looked at the combined effects of increased SST and OA on the dissolution of coral reef CaCO3 sediments. In situ benthic chamber incubations were used to measure dissolution rates in permeable CaCO3 sands under future OA and SST scenarios in a coral reef lagoon on Australia’s Great Barrier Reef (Heron Island. End of century (2100 simulations (temperature +2.7°C and pH -0.3 shifted carbonate sediments from net precipitating to net dissolving. Warming increased the rate of benthic respiration (R by 29% per 1°C and lowered the ratio of productivity to respiration (P/R; ΔP/R = -0.23, which increased the rate of CaCO3 sediment dissolution (average net increase of 18.9 mmol CaCO3 m-2 d-1 for business as usual scenarios. This is most likely due to the influence of warming on benthic P/R which, in turn, was an important control on sediment dissolution through the respiratory production of CO2. The effect of increasing CO2 on CaCO3 sediment dissolution (average net increase of 6.5 mmol CaCO3 m-2 d-1 for business as usual scenarios was significantly less than the effect of warming. However, the combined effect of increasing both SST and pCO2 on CaCO3 sediment dissolution was non-additive (average net increase of 5.6 mmol CaCO3 m-2 d-1 due to the different responses of the benthic community. This study highlights that benthic biogeochemical processes such as metabolism and associated CaCO3 sediment dissolution respond rapidly to changes in SST and OA, and that the response to multiple environmental changes are not necessarily additive.

  1. Annual and interannual variability of scatterometer ocean surface wind over the South China Sea

    DEFF Research Database (Denmark)

    Zhang, GS; Xu, Q.; Gong, Z.

    2014-01-01

    To investigate the annual and interannual variability of ocean surface wind over the South China Sea (SCS), the vector empirical orthogonal function (VEOF) method and the Hilbert-Huang transform (HHT) method were employed to analyze a set of combined satellite scatterometer wind data during...... the period from December 1992 to October 2009. The merged wind data were generated from European Remote Sensing Satellite (ERS)-1/2 Scatterometer, NASA Scatterometer (NSCAT) and NASA's Quick Scatterometer (QuikSCAT) wind products. The first VEOF mode corresponds to a winter-summer mode which accounts for 87...

  2. Fluorine uptake into the human enamel surface from fluoride-containing sealing materials during cariogenic pH cycling

    International Nuclear Information System (INIS)

    Yasuhiro, Matsuda; Katsushi, Okuyama; Hiroko, Yamamoto; Hisanori, Komatsu; Masashi, Koka; Takahiro, Sato; Naoki, Hashimoto; Saiko, Oki; Chiharu, Kawamoto; Hidehiko, Sano

    2015-01-01

    To prevent the formation of caries and reduce dentin hypersensitivity, sealing materials, either with or without fluoride, are generally applied on the tooth in clinical practice. Application of fluoride-free sealing materials results in the formation of an acid-resistant layer on the tooth surface. On the other hand, fluoride-containing sealing materials might not only form an acid-resistant layer but could possibly further provide fluoride to enhance remineralization and reduce demineralization. In this study, the demineralization prevention ability and fluorine uptake rate in human enamel of fluoride-containing sealing materials [“MS coats F” (MSF)] and fluoride-free sealing materials (“hybrid coats 2” [HI]) were evaluated using an automatic pH cycling system. Each material was applied to the original tooth surface, the cut surfaces were covered with sticky wax, and the automatic pH-cycling system simulated daily acid changes (pH 6.8–4.5) occurring in the oral cavity for 4 weeks. Caries progression was analyzed using transverse microradiography (TMR) taken pre and post the 4 weeks of pH cycling. The fluorine and calcium distributions in the carious lesion in each specimen were evaluated using the proton-induced gamma emission (PIGE) and proton-induced X-ray (PIXE) techniques, respectively. TMR analysis showed that both MSF and HI had a caries-preventing effect after 4 weeks of pH cycling. PIGE/PIXE analysis demonstrated that only MSF resulted in fluoride uptake in the enamel surface. Therefore, MSF can help to form an acid-resistant layer and provide fluoride to the enamel surface. The presence of fluoride on the enamel surface suggested that MSF could prevent demineralization, even if the acid-resistant layer was removed, in clinical settings. The data obtained using the PIGE and PIXE techniques are useful for understanding the benefits of the use of a fluoride-containing sealing material for preventing caries

  3. Fluorine uptake into the human enamel surface from fluoride-containing sealing materials during cariogenic pH cycling

    Energy Technology Data Exchange (ETDEWEB)

    Yasuhiro, Matsuda, E-mail: matsuda@den.hokudai.ac.jp [Department of Restorative Dentistry, Graduate School of Dental Medicine Hokkaido University (Japan); Katsushi, Okuyama [Department of Restorative Dentistry, Graduate School of Dental Medicine Hokkaido University (Japan); Hiroko, Yamamoto [Graduate School of Dentistry, Osaka University (Japan); Hisanori, Komatsu [Department of Restorative Dentistry, Graduate School of Dental Medicine Hokkaido University (Japan); Masashi, Koka; Takahiro, Sato [Takasaki Advanced Radiation Research Institute, JAEA (Japan); Naoki, Hashimoto; Saiko, Oki; Chiharu, Kawamoto; Hidehiko, Sano [Department of Restorative Dentistry, Graduate School of Dental Medicine Hokkaido University (Japan)

    2015-04-01

    To prevent the formation of caries and reduce dentin hypersensitivity, sealing materials, either with or without fluoride, are generally applied on the tooth in clinical practice. Application of fluoride-free sealing materials results in the formation of an acid-resistant layer on the tooth surface. On the other hand, fluoride-containing sealing materials might not only form an acid-resistant layer but could possibly further provide fluoride to enhance remineralization and reduce demineralization. In this study, the demineralization prevention ability and fluorine uptake rate in human enamel of fluoride-containing sealing materials [“MS coats F” (MSF)] and fluoride-free sealing materials (“hybrid coats 2” [HI]) were evaluated using an automatic pH cycling system. Each material was applied to the original tooth surface, the cut surfaces were covered with sticky wax, and the automatic pH-cycling system simulated daily acid changes (pH 6.8–4.5) occurring in the oral cavity for 4 weeks. Caries progression was analyzed using transverse microradiography (TMR) taken pre and post the 4 weeks of pH cycling. The fluorine and calcium distributions in the carious lesion in each specimen were evaluated using the proton-induced gamma emission (PIGE) and proton-induced X-ray (PIXE) techniques, respectively. TMR analysis showed that both MSF and HI had a caries-preventing effect after 4 weeks of pH cycling. PIGE/PIXE analysis demonstrated that only MSF resulted in fluoride uptake in the enamel surface. Therefore, MSF can help to form an acid-resistant layer and provide fluoride to the enamel surface. The presence of fluoride on the enamel surface suggested that MSF could prevent demineralization, even if the acid-resistant layer was removed, in clinical settings. The data obtained using the PIGE and PIXE techniques are useful for understanding the benefits of the use of a fluoride-containing sealing material for preventing caries.

  4. Coralline algal barium as indicator for 20th century northwestern North Atlantic surface ocean freshwater variability.

    Science.gov (United States)

    Hetzinger, S; Halfar, J; Zack, T; Mecking, J V; Kunz, B E; Jacob, D E; Adey, W H

    2013-01-01

    During the past decades climate and freshwater dynamics in the northwestern North Atlantic have undergone major changes. Large-scale freshening episodes, related to polar freshwater pulses, have had a strong influence on ocean variability in this climatically important region. However, little is known about variability before 1950, mainly due to the lack of long-term high-resolution marine proxy archives. Here we present the first multidecadal-length records of annually resolved Ba/Ca variations from Northwest Atlantic coralline algae. We observe positive relationships between algal Ba/Ca ratios from two Newfoundland sites and salinity observations back to 1950. Both records capture episodical multi-year freshening events during the 20th century. Variability in algal Ba/Ca is sensitive to freshwater-induced changes in upper ocean stratification, which affect the transport of cold, Ba-enriched deep waters onto the shelf (highly stratified equals less Ba/Ca). Algal Ba/Ca ratios therefore may serve as a new resource for reconstructing past surface ocean freshwater changes.

  5. Study of the synergistic effects of salinity, pH, and temperature on the surface-active properties of biosurfactants produced by Lactobacillus pentosus.

    Science.gov (United States)

    Bello, Xanel Vecino; Devesa-Rey, Rosa; Cruz, José Manuel; Moldes, Ana Belén

    2012-02-08

    Many studies have investigated the effects of pH, temperature, and salinity on the surface-active properties of various surfactants, although in most cases the variables have been studied separately, without considering the effects of any interactions between them. In the present study, a Box-Behnken factorial design was applied to study the effects of pH, temperature, and salinity on the surface-active properties of a biosurfactant produced by Lactobacillus pentosus. The data obtained enabled development of a second-order model describing the interrelationships between operational and experimental variables, by equations including linear, interaction, and quadratic terms. The variable that had the greatest effect on the surface-active properties of the biosurfactant was pH. Moreover, at pH 3-5.5, decreases in salinity and temperature acted synergistically, reducing the surface tension of the biosurfactant; at pH 8, the same effect was observed with increasing salinity and temperature.

  6. The effect of prolonged immersion of giomer bulk-fill composite resin on the pH value of artificial saliva and resin surface roughness

    Science.gov (United States)

    Ratna, A. A.; Triaminingsih, S.; Eriwati, Y. K.

    2017-08-01

    This study aimed to determine the effect of immersion time on the surface roughness of Giomer Bulk-Fill composite resin and on the pH value of artificial saliva. Sixty-three specimens were divided into nine groups and immersed in artificial saliva with pH values of 7, 5.5, and 4.5 for 1 hour, 24 hours, and 72 hours at 37 °C. The changes in artificial saliva pH were measured using a pH meter and the surface roughness was measured using a surface roughness tester. Longer immersion time increases the pH of artificial saliva and the surface roughness of Giomer Bulk-Fill composite resin.

  7. Volcanic ash as an iron-fertilizer in ocean surface water

    Science.gov (United States)

    Olgun, N.; Duggen, S.; Croot, P.; Dietze, H.; Schacht, U.; Oskarsson, N.; Siebe, C.; Auer, A.

    2007-12-01

    Surface ocean fertilisation with iron may affect the marine primary productivity, C-cycles and eventually climate development. Volcanic ash has the potential to release iron on contact with seawater and to stimulate phytoplankton growth (1,2) but the relative importance of volcanism at destructive plate margins (subduction zones, SZ) and intraplate volcanic settings (ocean islands at hot spots) remains unknown. Here we present new results from geochemical experiments with natural seawater and numerous volcanic ash samples from SZ volcanoes in the Pacific Ring of Fire (Alaska, Japan, Kamchatka, Northern and Central America and Papua New Guinea) and hot spot volcanoes (on Iceland and Hawaii). The release of iron as a function of time was determined in situ in seawater by means of Cathodic Stripping Voltammetry. Our experiments show that: A) volcanic ash from both SZ and hot spot volcanic areas mobilise significant amounts of iron, B) with the highest mobilisation rates within the first 10-20 minutes and C) indicate that volcanic ash from hot spot volcanoes mobilise less iron than volcanic ash from SZ. We propose that the higher iron-mobilisation potential of SZ volcanic ash results from higher HCl/HF ratios in SZ volcanic gases that seem to be involved in the formation of Fe-bearing soluble salt coatings (condensed gases and adsorbed aerosols) on ash particles (1,2,3). Higher HCl/HF ratios in SZ volcanic gases thus appear to be linked to the recycling of seawater through subduction of oceanic lithosphere at destructive plate margins. Together, taking into account differences in ash-fluxes from SZ and hot spot volcanoes into the oceans, our study suggests that SZ volcanic ash plays a more important role for the global surface ocean iron budget than ash from volcanoes in hot spot areas. 1 Frogner, Gislason, Oskarsson (2001). Geology, 29, 487-490. 2 Duggen, Croot, Schacht, Hofmann (2007) Geoph. Res. Letters 34, 5. 3 Oskarsson (1980), J. Volc. and Geoth. Res. 8, 251-266.

  8. Surface signature of Mediterranean water eddies in the Northeastern Atlantic: effect of the upper ocean stratification

    Directory of Open Access Journals (Sweden)

    I. Bashmachnikov

    2012-11-01

    Full Text Available Meddies, intra-thermocline eddies of Mediterranean water, can often be detected at the sea surface as positive sea-level anomalies. Here we study the surface signature of several meddies tracked with RAFOS floats and AVISO altimetry.

    While pushing its way through the water column, a meddy raises isopycnals above. As a consequence of potential vorticity conservation, negative relative vorticity is generated in the upper layer. During the initial period of meddy acceleration after meddy formation or after a stagnation stage, a cyclonic signal is also generated at the sea-surface, but mostly the anticyclonic surface signal follows the meddy.

    Based on geostrophy and potential vorticity balance, we present theoretical estimates of the intensity of the surface signature. It appears to be proportional to the meddy core radius and to the Coriolis parameter, and inversely proportional to the core depth and buoyancy frequency. This indicates that surface signature of a meddy may be strongly reduced by the upper ocean stratification. Using climatic distribution of the stratification intensity, we claim that the southernmost limit for detection in altimetry of small meddies (with radii on the order of 10–15 km should lie in the subtropics (35–45° N, while large meddies (with radii of 25–30 km could be detected as far south as the northern tropics (25–35° N. Those results agree with observations.

  9. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the North Pacific Ocean, South Atlantic Ocean and others from 2004-12-31 to 2005-12-26 (NCEI Accession 0144531)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144531 includes Surface underway data collected from LAURENCE M. GOULD in the North Pacific Ocean, South Atlantic Ocean, South Pacific Ocean and...

  10. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Barometric pressure sensor, Carbon dioxide (CO2) gas analyzer and other instruments from ROGER REVELLE in the Indian Ocean, South Pacific Ocean and others from 2007-02-04 to 2007-03-16 (NCEI Accession 0144252)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144252 includes Surface underway data collected from ROGER REVELLE in the Indian Ocean, South Pacific Ocean, Southern Oceans (> 60 degrees South)...

  11. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the North Pacific Ocean, South Atlantic Ocean and others from 2004-12-30 to 2005-11-20 (NCEI Accession 0148772)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0148772 includes Surface underway data collected from LAURENCE M. GOULD in the North Pacific Ocean, South Atlantic Ocean, South Pacific Ocean and...

  12. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the North Pacific Ocean, South Atlantic Ocean and others from 2008-12-31 to 2009-12-21 (NCEI Accession 0148771)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0148771 includes Surface underway data collected from LAURENCE M. GOULD in the North Pacific Ocean, South Atlantic Ocean, South Pacific Ocean and...

  13. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from LAURENCE M. GOULD in the North Pacific Ocean, South Atlantic Ocean and others from 2008-12-31 to 2009-12-22 (NCEI Accession 0144533)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144533 includes Surface underway data collected from LAURENCE M. GOULD in the North Pacific Ocean, South Atlantic Ocean, South Pacific Ocean and...

  14. A History of Warming Sea Surface Temperature and Ocean Acidification Recorded by Planktonic Foraminifera Geochemistry from the Santa Barbara Basin, California

    Science.gov (United States)

    Osborne, E.; Thunell, R.; Bizimis, M.; Buckley, W. P., Jr.; benitez-Nelson, C. R.; Chartier, C. J.

    2015-12-01

    The geochemistry of foraminiferal shells has been widely used to reconstruct past conditions of the ocean and climate. Since the onset of the Industrial Revolution, anthropogenically produced CO2 has resulted in an increase in global temperatures and a decline in the mean pH of the world's oceans. The California Current System is a particularly susceptible region to ocean acidification due to natural upwelling processes that also cause a reduction in seawater pH. The trace element concentration of magnesium and boron in planktonic foraminiferal shells are used here as proxies for temperature and carbonate ion concentration ([CO32-]), respectively. Newly developed calibrations relating Mg/Ca ratios to temperature (R2 0.91) and B/Ca ratios to [CO32-] (R2 0.84) for the surface-mixed layer species Globogerina bulloides were generated using material collected in the Santa Barbara Basin sediment trap time-series. Using these empirical relationships, temperature and [CO32-] are reconstructed using a 0.5 meter long multi-core collected within the basin. 210Pb activities were used to determine a sedimentation rate for the core to estimate ages for core samples (sedimentation rate: 0.341 cm/yr). A spike in 137Cs activity is used as a tie-point to the year 1965 coinciding with the peak of nuclear bomb testing. Our down-core record extends through the mid-19th century to create a history of rising sea surface temperatures and declining [CO32-] as a result of anthropogenic CO2 emissions.

  15. Impact of river discharge on the coastal water pH and pCO2 levels during the Indian Ocean Dipole (IOD) years in the western Bay of Bengal

    Digital Repository Service at National Institute of Oceanography (India)

    Sarma, V.V.S.S.; Paul, Y.S.; Vani, D.G.; Murty, V.S.N.

    due to variations in river discharge and phases of IOD may significantly modify the coastal ecosystem that requires careful evaluation.   2    Introduction The fossil fuels burning, cement manufacturing and land-use changes are some... Centre for Ocean Information and Services (INCOIS). The ASCAT ocean surface winds are a 10 meter neutral stability wind, and these winds are processed by National Oceanic and Atmospheric Administration/National Environmental Satellite, Data...

  16. Investigating the role of wind in generating surface currents over the slope area of the Laptev Sea, Arctic Ocean

    Science.gov (United States)

    Patteson, R. N.

    2017-12-01

    Mixing mechanisms of the Arctic Ocean have profound impacts on sea ice, global ocean dynamics, and arctic communities. This project used a two-year long time series of ocean current velocities collected from eight moorings located on the Eurasian basin, as well as ERA-interim wind data, to compare and assess relationships between current and wind velocities at different depths. Determining the strength of these correlations will further scientific understanding of the degree to which wind influences mixing, with implications for heat flux, diffusion, and sea ice changes. Using statistical analysis, I calculated whether a significant relationship between wind velocity and ocean currents existed beginning at the surface level ( 50m) .The final correlation values, ranging from R = 0.11 to R = 0.28, indicated a weak relationship between wind velocity and ocean currents at the surface for all eight mooring sites. The results for the surface depth imply that correlation likely decreases with increasing depths, and thus further testing of deeper depth levels was unnecessary. This finding suggests that there is another dominant factor at play in the ocean; we postulate that topography exerts a significant influence on subsurface mixing. This study highlights the need for further research of the different mechanisms and their importance in influencing the dynamic structure of the ocean.

  17. An Anisotropic Ocean Surface Emissivity Model Based on WindSat Polarimetric Brightness Observations

    Science.gov (United States)

    Smith, D. F.; Gasiewski, A. J.; Sandeep, S.; Weber, B. L.

    2012-12-01

    The goal of this research has been to develop a standardized fast full-Stokes ocean surface emissivity model with Jacobian for a wind-driven ocean surface applicable at arbitrary microwave frequencies, polarizations, and incidence angles. The model is based on the Ohio State University (OSU) two-scale code for surface emission developed by Johnson (2006, IEEE TGRS, 44, 560) but modified as follows: (1) the Meissner-Wentz dielectric permittivity (2012, IEEE TGRS, 50, 3004) replaces the original permittivity, (2) the Elfouhaily sea surface spectrum (1997, JGR, 102, C7,15781) replaces the Durden-Vesecky spectrum (1985, IEEE TGRS, OE-10, 445), but the Durden-Vesecky angular spreading function is retained, (3) the high-frequency portion of the Elfouhaily spectrum is multiplied by the Pierson-Moskowitz shape spectrum to correct an error in the original paper, (4) the generalized Phillips-Kitaigorodskii equilibrium range parameter for short waves is modeled as a continuous function of the friction velocity at the water surface to eliminate a discontinuous jump in the original paper. A total of five physical tuning parameters were identified, including the spectral strength and the hydrodynamic modulation factor. The short wave part of the spectrum is also allowed to have an arbitrary ratio relative to the long wave part. The foam fraction is multiplied by a variable correction factor, and also modulated to allow an anisotropic foam fraction with more foam on the leeward side of a wave. The model is being tuned against multi-year sequences of WindSat and Special Sensor Microwave/Imager (SSMI) data as analyzed by Meissner and Wentz (2012, IEEE TGRS, 50, 3004) for up to four Stokes brightnesses and in all angular harmonics up to two in twenty five wind bins from 0.5-25.5 m/s and of 1 m/s width. As a result there are 40 brightnesses per wind bin, for a total of 1000 brightnesses used to constrain the modified model. A chi-squared tuning criterion based on error standard

  18. Regime-Dependent Differences in Surface Freshwater Exchange Estimates Over the Ocean

    Science.gov (United States)

    Wong, Sun; Behrangi, Ali

    2018-01-01

    Differences in gridded precipitation (P), surface evaporation (E), and the resultant surface freshwater exchange (P - E) among different products over the ocean are diagnosed as functions of moisture advection (Qadvt) and moisture tendency by dynamical convergence (Qcnvg). Compared to the GPCP product, the TRMM3B42 product captures higher frequency of precipitation with larger extreme precipitation rates in regimes of deep convection and more light rain detections in regimes of frequent occurrence of boundary layer clouds. Discrepancies in E depend on moisture flux divergence, with the OAFlux product having the largest E in regimes of divergence. Discrepancies in mean P - E in deep convective regimes are highly influenced by differences in precipitation, with the TRMM3B42 product yielding P - E histograms closer to those inferred from the reanalysis moisture flux convergence. In nonconvergent regimes, observation-based P - E histograms skew toward positive values while the inferred reanalysis histograms are symmetric about the means.

  19. Modeled Oceanic Response and Sea Surface Cooling to Typhoon Kai-Tak

    Directory of Open Access Journals (Sweden)

    Yu-Heng Tseng

    2010-01-01

    Full Text Available An ocean response to typhoon Kai-Tak is simulated using an accurate fourth-order, basin-scale ocean model. The surface winds of typhoon Kai-Tak were obtained from QuikSCAT satellite images blended with the ECMWF wind fields. An intense nonlinear mesoscale eddy is generated in the northeast South China Sea (SCS with a Rossby number of O(1 and on a 50 - 100 km horizontal scale. Inertial oscillation is clearly observed. Advection dominates as a strong wind shear drives the mixed layer flows outward, away from the typhoon center, thus forcing upwelling from deep levels with a high upwelling velocity (> 30 m day-1. A drop in sea surface temperature (SST of more than 9°C is found in both observation and simulation. We attribute this significant SST drop to the influence of the slow moving typhoon, initial stratification and bathymetry-induced upwelling in the northeast of the SCS where the typhoon hovered.

  20. Variable but persistent coexistence of Prochlorococcus ecotypes along temperature gradients in the ocean's surface mixed layer.

    Science.gov (United States)

    Chandler, Jeremy W; Lin, Yajuan; Gainer, P Jackson; Post, Anton F; Johnson, Zackary I; Zinser, Erik R

    2016-04-01

    The vast majority of the phytoplankton communities in surface mixed layer of the oligotrophic ocean are numerically dominated by one of two ecotypes of Prochlorococcus, eMIT9312 or eMED4. In this study, we surveyed large latitudinal transects in the Atlantic and Pacific Ocean to determine if these ecotypes discretely partition the surface mixed layer niche, or if populations exist as a continuum along key environmental gradients, particularly temperature. Transitions of dominance occurred at approximately 19-21°C, with the eMED4 ecotype dominating the colder, and eMIT9312 ecotype dominating the warmer regions. Within these zones of regional dominance, however, the minority ecotype was not competed to extinction. Rather, a robust log-linear relationship between ecotype ratio and temperature characterized this stabilized coexistence: for every 2.5°C increase in temperature, the eMIT9312:eMED4 ratio increased by an order of magnitude. This relationship was observed in both quantitative polymerase chain reaction and in pyrosequencing assays. Water column stratification also contributed to the ecotype ratio along the basin-scale transects, but to a lesser extent. Finally, instances where the ratio of the eMED4 and eMIT9312 abundances did not correlate well with temperature were identified. Such occurrences are likely due to changes in water temperatures outpacing changes in community structure. © 2016 Society for Applied Microbiology and John Wiley & Sons Ltd.

  1. Predicting East African spring droughts using Pacific and Indian Ocean sea surface temperature indices

    Science.gov (United States)

    Funk, C.; Hoell, A.; Shukla, S.; Bladé, I.; Liebmann, B.; Roberts, J. B.; Robertson, F. R.; Husak, G.

    2014-12-01

    In eastern East Africa (the southern Ethiopia, eastern Kenya and southern Somalia region), poor boreal spring (long wet season) rains in 1999, 2000, 2004, 2007, 2008, 2009, and 2011 contributed to severe food insecurity and high levels of malnutrition. Predicting rainfall deficits in this region on seasonal and decadal time frames can help decision makers implement disaster risk reduction measures while guiding climate-smart adaptation and agricultural development. Building on recent research that links more frequent East African droughts to a stronger Walker circulation, resulting from warming in the Indo-Pacific warm pool and an increased east-to-west sea surface temperature (SST) gradient in the western Pacific, we show that the two dominant modes of East African boreal spring rainfall variability are tied to SST fluctuations in the western central Pacific and central Indian Ocean, respectively. Variations in these two rainfall modes can thus be predicted using two SST indices - the western Pacific gradient (WPG) and central Indian Ocean index (CIO), with our statistical forecasts exhibiting reasonable cross-validated skill (rcv ≈ 0.6). In contrast, the current generation of coupled forecast models show no skill during the long rains. Our SST indices also appear to capture most of the major recent drought events such as 2000, 2009 and 2011. Predictions based on these simple indices can be used to support regional forecasting efforts and land surface data assimilations to help inform early warning and guide climate outlooks.

  2. Lagrangian modelling of ocean surface waves and synthetic aperture radar wave measurements

    Energy Technology Data Exchange (ETDEWEB)

    Fouques, Sebastien

    2005-07-01

    The present thesis is concerned with the estimation of the ocean wave spectrum from synthetic aperture radar imaging and the modelling of ocean surface waves using the Lagrangian formalism. The first part gives a short overview of the theories of ocean surface waves and synthetic aperture radar (SAR) whereas the second part consists of five independent publications. The first two articles investigate the influence of the radar backscatter model on the SAR imaging of ocean waves. In Article I, Monte Carlo simulations of SAR images of the ocean surface are carried out using a nonlinear backscatter model that include both specular reflection and Bragg scattering and the results are compared to simulations from the classical Hasselmann integral transform (Hasselmann and Hasselmann, 1991). It is shown that nonlinearities in the backscatter model strongly influence the imaging of range-travelling waves and that the former can suppress the range-splitting effect (Bruning et al., 1988). Furthermore, in Article II a database of Envisat-ASAR Wave Mode products co-located with directional wave spectra from the numerical model WAM and which contains range-travelling wave cases only, is set up. The WAM spectra are used as input to several ocean-to-SAR integral transforms, with various real aperture radar (RAR) models and the obtained SAR image cross-spectra are compared to the Envisat-ASAR observations. A first result is that the use of a linear backscatter model leads to a high proportion of non-physical negative backscatter values in the RAR image, as suggested by Schulz-Stellenfleth (2001). Then, a comparison between the observed SAR cross-spectra and the ones simulated through Hasselmann's integral transform reveals that only twenty percents of the observations show a range-splitting effect as strong as in the simulations. A much better agreement is obtained when using the integral transform by Schulz-Stellenfleth (2003), which is based on a nonlinear hackscatter model

  3. Surface Properties and Photocatalytic Activities of the Colloidal ZnS:Mn Nanocrystals Prepared at Various pH Conditions

    Science.gov (United States)

    Heo, Jungho; Hwang, Cheong-Soo

    2015-01-01

    Water-dispersible ZnS:Mn nanocrystals (NC) were synthesized by capping the surface with mercaptoacetic acid (MAA) molecules at three different pH conditions. The obtained ZnS:Mn-MAA NC products were physically and optically characterized by corresponding spectroscopic methods. The UV-Visible absorption spectra and PL emission spectra showed broad peaks at 310 and 590 nm, respectively. The average particle sizes measured from the HR-TEM images were 5 nm, which were also supported by the Debye-Scherrer calculations using the X-ray diffraction (XRD) data. Moreover, the surface charges and the degrees of aggregation of the ZnS:Mn-MAA NCs were determined by electrophoretic and hydrodynamic light scattering methods, indicating formation of agglomerates in water with various sizes (50–440 nm) and different surface charge values accordingly the preparation conditions of the NCs (−7.59 to −24.98 mV). Finally, the relative photocatalytic activities of the ZnS:Mn-MAA NCs were evaluated by measuring the degradation rate of methylene blue (MB) molecule in a pseudo first-order reaction condition under the UV-visible light irradiation. As a result, the ZnS:Mn-MAA NC prepared at the pH 7 showed the best photo-degradation efficiency of the MB molecule with the first-order rate constant (kobs) of 2.0 × 10−3·min−1. PMID:28347105

  4. Ocean Circulation

    OpenAIRE

    Thompson, Andrew F.; Rahmstorf, Stefan

    2009-01-01

    The ocean moderates the Earth's climate due to its vast capacity to store and transport heat; the influence of the large-scale ocean circulation on changes in climate is considered in this chapter. The ocean experiences both buoyancy forcing (through heating/cooling and evaporation/precipitation) and wind forcing. Almost all ocean forcing occurs at the surface, but these changes are communicated throughout the entire depth of the ocean through the meridional overturning circulation (MOC). In ...

  5. Reconstructing surface ocean circulation with129I time series records from corals.

    Science.gov (United States)

    Chang, Ching-Chih; Burr, George S; Jull, A J Timothy; Russell, Joellen L; Biddulph, Dana; White, Lara; Prouty, Nancy G; Chen, Yue-Gau; Shen, Chuan-Chou; Zhou, Weijian; Lam, Doan Dinh

    2016-12-01

    The long-lived radionuclide 129 I (half-life: 15.7 × 10 6  yr) is well-known as a useful environmental tracer. At present, the global 129 I in surface water is about 1-2 orders of magnitude higher than pre-1960 levels. Since the 1990s, anthropogenic 129 I produced from industrial nuclear fuels reprocessing plants has been the primary source of 129 I in marine surface waters of the Atlantic and around the globe. Here we present four coral 129 I time series records from: 1) Con Dao and 2) Xisha Islands, the South China Sea, 3) Rabaul, Papua New Guinea and 4) Guam. The Con Dao coral 129 I record features a sudden increase in 129 I in 1959. The Xisha coral shows similar peak values for 129 I as the Con Dao coral, punctuated by distinct low values, likely due to the upwelling in the central South China Sea. The Rabaul coral features much more gradual 129 I increases in the 1970s, similar to a published record from the Solomon Islands. The Guam coral 129 I record contains the largest measured values for any site, with two large peaks, in 1955 and 1959. Nuclear weapons testing was the primary 129 I source in the Western Pacific in the latter part of the 20th Century, notably from testing in the Marshall Islands. The Guam 1955 peak and Con Dao 1959 increases are likely from the 1954 Castle Bravo test, and the Operation Hardtack I test is the most likely source of the 1959 peak observed at Guam. Radiogenic iodine found in coral was carried primarily through surface ocean currents. The coral 129 I time series data provide a broad picture of the surface distribution and depth penetration of 129 I in the Pacific Ocean over the past 60 years. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

  6. Reconstructing surface ocean circulation with 129I time series records from corals

    Science.gov (United States)

    Chang, Ching-Chih; Burr, George S.; Jull, A. J. Timothy; Russell, Joellen L.; Biddulph, Dana; White, Lara; Prouty, Nancy G.; Chen, Yue-Gau; Chuan-Chou Shen,; Zhou, Weijian; Lam, Doan Dinh

    2016-01-01

    The long-lived radionuclide 129I (half-life: 15.7 × 106 yr) is well-known as a useful environmental tracer. At present, the global 129I in surface water is about 1–2 orders of magnitude higher than pre-1960 levels. Since the 1990s, anthropogenic 129I produced from industrial nuclear fuels reprocessing plants has been the primary source of 129I in marine surface waters of the Atlantic and around the globe. Here we present four coral 129I time series records from: 1) Con Dao and 2) Xisha Islands, the South China Sea, 3) Rabaul, Papua New Guinea and 4) Guam. The Con Dao coral 129I record features a sudden increase in 129I in 1959. The Xisha coral shows similar peak values for 129I as the Con Dao coral, punctuated by distinct low values, likely due to the upwelling in the central South China Sea. The Rabaul coral features much more gradual 129I increases in the 1970s, similar to a published record from the Solomon Islands. The Guam coral 129I record contains the largest measured values for any site, with two large peaks, in 1955 and 1959. Nuclear weapons testing was the primary 129I source in the Western Pacific in the latter part of the 20th Century, notably from testing in the Marshall Islands. The Guam 1955 peak and Con Dao 1959 increases are likely from the 1954 Castle Bravo test, and the Operation Hardtack I test is the most likely source of the 1959 peak observed at Guam. Radiogenic iodine found in coral was carried primarily through surface ocean currents. The coral 129I time series data provide a broad picture of the surface distribution and depth penetration of 129I in the Pacific Ocean over the past 60 years.

  7. Chemistry of Frozen NaCl and MgSO4 Brines - Implications for Surface Expression of Europa's Ocean Composition

    Science.gov (United States)

    Johnson, P. V.; Hodyss, R. P.; Choukroun, M.; Vu, T. H.

    2015-12-01

    The composition of Europa's subsurface ocean is a critical determinant of its habitability, but current analysis of the ocean composition is limited to its expression on the Europan surface. While there is observational evidence indicating that ocean materials make their way to the surface, our understanding of the chemical processes that can alter this material under Europan surface conditions is limited. We present experimental data on the chemistry of mixed solutions of NaCl and MgSO4 as they are frozen to 100 K, replicating the conditions that may occur when subsurface ocean fluids are emplaced onto Europa's surface. Confocal micro-Raman spectroscopy is used to study the formation of salts during the freezing process, and the interaction of ions in the frozen brines. Our data indicate that mixed aqueous solutions of NaCl and MgSO4 form Na2SO4 and MgCl2 preferentially when frozen, rather than making NaCl and MgSO4 precipitates. The detection of epsomite (MgSO4Ÿ•7H2O) on Europa's surface may therefore imply an ocean composition relatively low in sodium, unless radiolytic chemistry converts MgCl2 to MgSO4 as suggested by Hand and Brown 2013 (ApJ 145 110). These results have important implications for the interpretation of remote sensing data of Europa's surface.

  8. Ocean Surface Topography Mission (OSTM) /Jason-3: Near Real-Time Altimetry Validation System (NRTAVS) QA Reports, 2015 - (NCEI Accession 0122600)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Jason-3 is the fourth mission in U.S.-European series of satellite missions that measure the height of the ocean surface. Scheduled to launch in 2015, the mission...

  9. Calcium carbonate saturation in the surface water of the Arctic Ocean: undersaturation in freshwater influenced shelves

    Directory of Open Access Journals (Sweden)

    A. Fransson

    2009-11-01

    Full Text Available In the summer of 2005, we sampled surface water and measured pH and total alkalinity (AT underway aboard IB Oden along the Northwest Passage from Cape Farewell (South Greenland to the Chukchi Sea. We investigated the variability of carbonate system parameters, focusing particularly on carbonate concentration [CO32−] and calcium carbonate saturation states, as related to freshwater addition, biological processes and physical upwelling. Measurements on AT, pH at 15°C, salinity (S and sea surface temperature (SST, were used to calculate total dissolved inorganic carbon (CT, [CO32−] and the saturation of aragonite (ΩAr and calcite (ΩCa in the surface water. The same parameters were measured in the water column of the Bering Strait. Some surface waters in the Canadian Arctic Archipelago (CAA and on the Mackenzie shelf (MS were found to be undersaturated with respect to aragonite (ΩAr<1. In these areas, surface water was low in AT and CT (<1500 μmol kg−1 relative to seawater and showed low [CO32−]. The low saturation states were probably due to the likely the effect of dilution due to freshwater addition by sea ice melt (CAA and river runoff (MS. High AT and CT and low pH, corresponded with the lowest [CO32−], ΩAr and ΩCa, observed near Cape Bathurst and along the South Chukchi Peninsula. This was linked to the physical upwelling of subsurface water with elevated CO2. The highest surface ΩAr and ΩCa of 3.0 and 4.5, respectively, were found on the Chukchi Sea shelf and in the cold water north of Wrangel Island, which is heavily influenced by high CO2 drawdown and lower CT from intense biological production. In the western Bering Strait, the cold and saline Anadyr Current carries water that is enriched in AT and

  10. Nonuniform ocean acidification and attenuation of the ocean carbon sink

    Science.gov (United States)

    Fassbender, Andrea J.; Sabine, Christopher L.; Palevsky, Hilary I.

    2017-08-01

    Surface ocean carbon chemistry is changing rapidly. Partial pressures of carbon dioxide gas (pCO2) are rising, pH levels are declining, and the ocean's buffer capacity is eroding. Regional differences in short-term pH trends primarily have been attributed to physical and biological processes; however, heterogeneous seawater carbonate chemistry may also be playing an important role. Here we use Surface Ocean CO2 Atlas Version 4 data to develop 12 month gridded climatologies of carbonate system variables and explore the coherent spatial patterns of ocean acidification and attenuation in the ocean carbon sink caused by rising atmospheric pCO2. High-latitude regions exhibit the highest pH and buffer capacity sensitivities to pCO2 increases, while the equatorial Pacific is uniquely insensitive due to a newly defined aqueous CO2 concentration effect. Importantly, dissimilar regional pH trends do not necessarily equate to dissimilar acidity ([H+]) trends, indicating that [H+] is a more useful metric of acidification.

  11. The Sentinel-3 Surface Topography Mission (S-3 STM): Level 2 SAR Ocean Retracker

    Science.gov (United States)

    Dinardo, S.; Lucas, B.; Benveniste, J.

    2015-12-01

    The SRAL Radar Altimeter, on board of the ESA Mission Sentinel-3 (S-3), has the capacity to operate either in the Pulse-Limited Mode (also known as LRM) or in the novel Synthetic Aperture Radar (SAR) mode. Thanks to the initial results from SAR Altimetry obtained exploiting CryoSat-2 data, lately the interest by the scientific community in this new technology has significantly increased and consequently the definition of accurate processing methodologies (along with validation strategies) has now assumed a capital importance. In this paper, we present the algorithm proposed to retrieve from S-3 STM SAR return waveforms the standard ocean geophysical parameters (ocean topography, wave height and sigma nought) and the validation results that have been so far achieved exploiting the CryoSat-2 data as well as the simulated data. The inversion method (retracking) to extract from the return waveform the geophysical information is a curve best-fitting scheme based on the bounded Levenberg-Marquardt Least-Squares Estimation Method (LEVMAR-LSE). The S-3 STM SAR Ocean retracking algorithm adopts, as return waveform’s model, the “SAMOSA” model [Ray et al, 2014], named after the R&D project SAMOSA (led by Satoc and funded by ESA), in which it has been initially developed. The SAMOSA model is a physically-based model that offers a complete description of a SAR Altimeter return waveform from ocean surface, expressed in the form of maps of reflected power in Delay-Doppler space (also known as stack) or expressed as multilooked echoes. SAMOSA is able to account for an elliptical antenna pattern, mispointing errors in roll and yaw, surface scattering pattern, non-linear ocean wave statistics and spherical Earth surface effects. In spite of its truly comprehensive character, the SAMOSA model comes with a compact analytical formulation expressed in term of Modified Bessel functions. The specifications of the retracking algorithm have been gathered in a technical document (DPM

  12. An explanation for the different climate sensitivities of land and ocean surfaces based on the diurnal cycle

    Science.gov (United States)

    Kleidon, Axel; Renner, Maik

    2017-09-01

    Observations and climate model simulations consistently show a higher climate sensitivity of land surfaces compared to ocean surfaces. Here we show that this difference in temperature sensitivity can be explained by the different means by which the diurnal variation in solar radiation is buffered. While ocean surfaces buffer the diurnal variations by heat storage changes below the surface, land surfaces buffer it mostly by heat storage changes above the surface in the lower atmosphere that are reflected in the diurnal growth of a convective boundary layer. Storage changes below the surface allow the ocean surface-atmosphere system to maintain turbulent fluxes over day and night, while the land surface-atmosphere system maintains turbulent fluxes only during the daytime hours, when the surface is heated by absorption of solar radiation. This shorter duration of turbulent fluxes on land results in a greater sensitivity of the land surface-atmosphere system to changes in the greenhouse forcing because nighttime temperatures are shaped by radiative exchange only, which are more sensitive to changes in greenhouse forcing. We use a simple, analytic energy balance model of the surface-atmosphere system in which turbulent fluxes are constrained by the maximum power limit to estimate the effects of these different means to buffer the diurnal cycle on the resulting temperature sensitivities. The model predicts that land surfaces have a 50 % greater climate sensitivity than ocean surfaces, and that the nighttime temperatures on land increase about twice as much as daytime temperatures because of the absence of turbulent fluxes at night. Both predictions compare very well with observations and CMIP5 climate model simulations. Hence, the greater climate sensitivity of land surfaces can be explained by its buffering of diurnal variations in solar radiation in the lower atmosphere.

  13. Ocean acidification and calcium carbonate saturation states in the coastal zone of the West Antarctic Peninsula

    NARCIS (Netherlands)

    Jones, Elizabeth M.; Fenton, Mairi; Meredith, Michael P.; Clargo, Nicola M.; Ossebaar, Sharyn; Ducklow, Hugh W.; Venables, Hugh J.; de Baar, Henricus

    The polar oceans are particularly vulnerable to ocean acidification; the lowering of seawater pH and carbonate mineral saturation states due to uptake of atmospheric carbon dioxide (CO2). High spatial variability in surface water pH and saturation states (Omega) for two biologically-important

  14. Ocean acidification and calcium carbonate saturation states in the coastal zone of the West Antarctic Peninsula

    NARCIS (Netherlands)

    Jones, E.M.; Fenton, M.; Meredith, M.P.; Clargo, N.M.; Ossebaar, S.; Ducklow, H.W.; Venables, H.J.; De Baar, H.J.W.

    2017-01-01

    The polar oceans are particularly vulnerable to ocean acidification; the lowering of seawater pH and carbonate mineral saturation states due to uptake of atmospheric carbon dioxide (CO2). High spatial variability in surface water pH and saturation states (Ω) for two biologically-important calcium

  15. The surface drifter program for real time and off-line validation of ocean forecasts and reanalyses

    Science.gov (United States)

    Hernandez, Fabrice; Regnier, Charly; Drévillon, Marie

    2017-04-01

    As part of the Global Ocean Observing System, the Global Drifter Program (GDP) is comprised of an array of about 1250 drifting buoys spread over the global ocean, that provide operational, near-real time surface velocity, sea surface temperature (SST) and sea level pressure observations. This information is used mainly used for numerical weather forecasting, research, and in-situ calibration/verification of satellite observations. Since 2013 the drifting buoy SST measurements are used for near real time assessment of global forecasting systems from Canada, France, UK, USA, Australia in the frame of the GODAE OceanView Intercomparison and Validation Task. For most of these operational systems, these data are not used for assimilation, and offer an independent observation assessment. This approach mimics the validation performed for SST satellite products. More recently, validation procedures have been proposed in order to assess the surface dynamics of Mercator Océan global and regional forecast and reanalyses. Velocities deduced from drifter trajectories are used in two ways. First, the Eulerian approach where buoy and ocean model velocity values are compared at the position of drifters. Then, from discrepancies, statistics are computed and provide an evaluation of the ocean model's surface dynamics reliability. Second, the Lagrangian approach, where drifting trajectories are simulated at each location of the real drifter trajectory using the ocean model velocity fields. Then, on daily basis, real and simulated drifter trajectories are compared by analyzing the spread after one day, two days etc…. The cumulated statistics on specific geographical boxes are evaluated in term of dispersion properties of the "real ocean" as captured by drifters, and those properties in the ocean model. This approach allows to better evaluate forecasting score for surface dispersion applications, like Search and Rescue, oil spill forecast, drift of other objects or contaminant

  16. Analysis of the global ocean sampling (GOS project for trends in iron uptake by surface ocean microbes.

    Directory of Open Access Journals (Sweden)

    Eve Toulza

    Full Text Available Microbial metagenomes are DNA samples of the most abundant, and therefore most successful organisms at the sampling time and location for a given cell size range. The study of microbial communities via their DNA content has revolutionized our understanding of microbial ecology and evolution. Iron availability is a critical resource that limits microbial communities' growth in many oceanic areas. Here, we built a database of 2319 sequences, corresponding to 140 gene families of iron metabolism with a large phylogenetic spread, to explore the microbial strategies of iron acquisition in the ocean's bacterial community. We estimate iron metabolism strategies from metagenome gene content and investigate whether their prevalence varies with dissolved iron concentrations obtained from a biogeochemical model. We show significant quantitative and qualitative variations in iron metabolism pathways, with a higher proportion of iron metabolism genes in low iron environments. We found a striking difference between coastal and open ocean sites regarding Fe(2+ versus Fe(3+ uptake gene prevalence. We also show that non-specific siderophore uptake increases in low iron open ocean environments, suggesting bacteria may acquire iron from natural siderophore-like organic complexes. Despite the lack of knowledge of iron uptake mechanisms in most marine microorganisms, our approach provides insights into how the iron metabolic pathways of microbial communities may vary with seawater iron concentrations.

  17. A Note on the Relationship of Temperature and Water Vapor over Oceans, as well as the Sea Surface Temperature Impact

    Science.gov (United States)

    Shie, C.-L.; Tao, W.-K.; Simpson, J.

    2005-01-01

    This note follows up on a recent study by Shie et al. (2005) and extends the investigation of the domain-averaged moisture-temperature (Q-T) relationship from the Tropics (i.e., the previous study) to the tropical Pacific, Atlantic and Indian Oceans. The Q and T data examined in this study are obtained from the GEOS-3 [Goddard Earth Observing System Version-3] global re-analysis monthly products. Similar to what was found earlier in the Tropics, Q is also found to increase with T over the entire oceanic region; however, Q increases faster with T over oceans than over the Tropics. The Q-T distribution for the Tropics is in a quasi-linear relationship, which is embedded in a global Q-T distribution that is, however, in a more complex curvilinear relationship. The Q-T distribution over the oceanic regions seems to fall within the lower bound (ie., the relatively colder and driver regime) of the tropical Q-T distribution. T over oceans is also found increasing with SST (sea surface temperature), which seemingly implies that an air mass might have gained heat more readily from a warmer ocean as compared to a colder ocean. Q is also found to increase with SST in a manner that quantitatively resembles an earlier finding by Stevens (1990). We also found that relative humidity exhibits similar behaviors for oceanic and tropical regions, respectively, i.e., it increases with both SST and T over oceans and increases with T in the Tropics (Shie et al. 2005). All these similar features found between oceanic and tropical regions seem to inform us that oceans occupy most of the Tropics and so play a key role in determining what have happened in the Tropics.

  18. Adsorption and nanowear properties of bovine submaxillary mucin films on solid surfaces: Influence of solution pH and substrate hydrophobicity

    DEFF Research Database (Denmark)

    Sotres, Javier; Madsen, Jan Busk; Arnebrant, Thomas

    2014-01-01

    The adsorption and mechanical stability of bovine submaxillary mucins (BSM) films at solid-liquid interfaces were studied with respect to both substrate hydrophobicity and solution pH. Dynamic light scattering revealed a single peak distribution in neutral aqueous solution (pH 7.4) and a small...... fraction with enhanced aggregation was observed in acidic solution (pH 3.8). Both substrate hydrophobicity and solution pH were found to affect the spontaneous adsorption of BSM onto solid surfaces; BSM adsorbed more onto hydrophobic surfaces than hydrophilic ones, and adsorbed more at pH 3.8 than at pH 7.......4. Thus, the highest "dry" adsorbed mass was observed for hydrophobic surfaces in pH 3.8 solution. However, a highest "wet" adsorbed mass, i.e. which includes the solvent coupled to the film, was observed for hydrophobic surfaces at pH 7.4. The mechanical stability of the films was studied...

  19. Connection between Ocean Acidification and Sound Propagation

    Directory of Open Access Journals (Sweden)

    Cem Gazioğlu

    2015-08-01

    Full Text Available Ocean Ambient Noise (OAN results from both anthropogenic and natural sources. Varied noise sources are dominant in low (LFB: 10 to 500 Hz, medium (MFB: 500 Hz to 25 kHz and high (HFB:>25 kHz frequency bands. Mostly, LFB is dominated by anthropogenic sources. MFB that cannot spread over long ranges of sound sources contribute to the OAN. Ocean is an exceptionally noisy place. Ocean acidification (OAc from rising Carbon dioxide (CO2 levels will result in decreased sound absorption and therefore, amplified levels of OAN. Carbon dioxide spewed into the atmosphere by burned fossil-fuel which dissolves in the seawater causes more acidic condition in oceans which has strong connection between chemical oceanography and sound propagation. As the ocean becomes more acidic, sound absorption at LFB decreases and acidic oceans would result in significant decreases in ocean sound absorption. In the recent years, the acoustic environment of oceans has reacted to transformations in both natural and anthropogenic impacts. Greenhouse gases concentrations, especially CO2 , rises in atmosphere due to industrial revolution. CO2 dissolved in the seawaters deposited in two major forms (carbonate and bicarbonate, which both lead to decrease pH of surface waters. Over the last 400 million years, pH of oceans has been stable around 8.2 globally. Latest investigations suggest that global pH is around 8.1 globally and various general oceanic circulation models (GOCM calculate that, emissions could reduce ocean pH by a degree between 0.4 units (according to moderate approach and 0.7 units (according to an aggressive one by the end of this century. This article discusses the CO2 considerations both in the atmosphere and hydrosphere which are directly related with seawater pH and oceans noise levels.

  20. Comparison of several databases of downward solar daily irradiation data at ocean surface with PIRATA measurements

    Science.gov (United States)

    Trolliet, Mélodie; Wald, Lucien

    2017-04-01

    The solar radiation impinging at sea surface is an essential variable in climate system. There are several means to assess the daily irradiation at surface, such as pyranometers aboard ship or on buoys, meteorological re-analyses and satellite-derived databases. Among the latter, assessments made from the series of geostationary Meteosat satellites offer synoptic views of the tropical and equatorial Atlantic Ocean every 15 min with a spatial resolution of approximately 5 km. Such Meteosat-derived databases are fairly recent and the quality of the estimates of the daily irradiation must be established. Efforts have been made for the land masses and must be repeated for the Atlantic Ocean. The Prediction and Research Moored Array in the Tropical Atlantic (PIRATA) network of moorings in the Tropical Atlantic Ocean is considered as a reference for oceanographic data. It consists in 17 long-term Autonomous Temperature Line Acquisition System (ATLAS) buoys equipped with sensors to measure near-surface meteorological and subsurface oceanic parameters, including downward solar irradiation. Corrected downward solar daily irradiation from PIRATA were downloaded from the NOAA web site and were compared to several databases: CAMS RAD, HelioClim-1, HelioClim-3 v4 and HelioClim-3 v5. CAMS-RAD, the CAMS radiation service, combines products of the Copernicus Atmosphere Monitoring Service (CAMS) on gaseous content and aerosols in the atmosphere together with cloud optical properties deduced every 15 min from Meteosat imagery to supply estimates of the solar irradiation. Part of this service is the McClear clear sky model that provides estimates of the solar irradiation that should be observed in cloud-free conditions. The second and third databases are HelioClim-1 and HelioClim-3 v4 that are derived from Meteosat images using the Heliosat-2 method and the ESRA clear sky model, based on the Linke turbidity factor. HelioClim-3 v5 is the fourth database and differs from v4 by the

  1. Sea Surface Salinity and Ocean Color Observations in the Northern Gulf

    Science.gov (United States)

    Wesson, J. C.; Burrage, D. M.; Wang, D. W.; Howden, S. D.

    2012-04-01

    Airborne mapping of Sea Surface Salinity (SSS) has been performed using L-Band radiometers for over 15 years, and has been operationally practical for over a decade. Ocean scale L-band observations of SSS are now obtained by satellite. ESA's SMOS has been operational for over two years and NASA's Aquarius satellite, launched in Jun, 2011, for over 6 months. Aircraft SSS complements satellite measurements by measuring nearer to coasts and with finer (˜1 km) spatial resolution. Due to the large effective pixel size of the satellite L-Band SSS measurements(˜35-80km), SMOS measurements do not reach the coast. Land microwave brightness signal in a given pixel contaminates the measurement of sea surface brightness temperature. However, the high signal to noise ratio (salinity contrast of 7-15 psu over 10km in some cases) of the coastal salinity signal, due to large freshwater sources, may dominate land contamination effects, to allow closer than usual SMOS SSS observations of strong coastal salinity patterns. An additional method to estimate SSS near coasts is using ocean color. Very near to coasts, freshwater sources such as rivers are relatively rich in Colored Dissolved Organic Matter (CDOM). As freshwater mixes with saltwater, salinity increases and CDOM concentrations fall. For conservative mixing, there is an inverse linear relation between CDOM and salinity, allowing estimates of SSS based on CDOM. The airborne sensors we use during STARRS flights include 2 SeaWifs airborne simulator sensors, one upward looking and one downward looking, as well as digital cameras, which we have used to identify color fronts. These provide ocean color measurements in addition to the STARRS microwave SSS measurements. We present results from an airborne campaign in the northern Gulf of Mexico, June 2-13, 2011. We made four types of flights. 1) Underflights of SMOS tracks at times coincident with SMOS passes. 2) Zig-zag flights along the coast, between Texas and Mississippi. 3

  2. Surface Wind and Upper-Ocean Variability Associated with the Madden-Julian Oscillation Simulated by the Coupled Ocean-Atmosphere Mesoscale Prediction System

    Science.gov (United States)

    2013-07-01

    temperature is observed during the suppressed phase of the MJO because of the weak winds and large shortwave radiation (Weller and Anderson 1996...western PacificOceans (e.g.,Weller andAnderson 1996; Soloviev and Lukas 1997; Bellenger and Duvel 2009). The diurnal cycle of the solar radiation ...the difference in surface shortwave radiation caused by the small-scale cloud variability, which cannot be resolved by the atmospheric model. Also

  3. Transport of contaminants by Arctic sea ice and surface ocean currents

    International Nuclear Information System (INIS)

    Pfirman, S.

    1995-01-01

    Sea ice and ocean currents transport contaminants in the Arctic from source areas on the shelves, to biologically active regions often more than a thousand kilometers away. Coastal regions along the Siberian margin are polluted by discharges of agricultural, industrial and military wastes in river runoff, from atmospheric deposition and ocean dumping. The Kara Sea is of particular concern because of deliberate dumping of radioactive waste, as well as the large input of polluted river water. Contaminants are incorporated in ice during suspension freezing on the shelves, and by atmospheric deposition during drift. Ice releases its contaminant load through brine drainage, surface runoff of snow and meltwater, and when the floe disintegrates. The marginal ice zone, a region of intense biological activity, may also be the site of major contaminant release. Potentially contaminated ice from the Kara Sea is likely to influence the marginal ice zones of the Barents and Greenland seas. From studies conducted to date it appears that sea ice from the Kara Sea does not typically enter the Beaufort Gyre, and thus is unlikely to affect the northern Canadian and Alaskan margins

  4. Relationships between Indian Ocean Sea surface temperature and the rainfall of Sri Lanka

    Energy Technology Data Exchange (ETDEWEB)

    Suppiah, Ramasamy

    1988-02-28

    Spatial and temporal variations of the sea surface temperature (SST) over the Indian Ocean are examined by using empirical orthogonal function (EOF) analysis. The first EOF mode explains 20.54% of the total variance indicating positive values over the study area. The second and third EOF modes explain relatively less contribution, 5.6% and 5.1% of the total variance. A weak positive correlation coefficient is observed between the time coefficients of the first EOF mode of SST anomalies and the time coefficients of the first EOF mode of the rainfall anomalies over Sri Lanka when all months are considered. The positive relationships between SST anomalies of the Pacific and the Indian Oceans and rainfall anomalies of Sri Lanka first appear in March and April, and then gradually build up towards the significant level. In the case of the summer monsoon, Arabian Sea SST's strongly influence the rainfall of Sri Lank, particularly striking in the southwestern quadrant of the island. (8 figs, 4 tabs, 27 refs)

  5. Surface area and the seabed area, volume, depth, slope, and topographic variation for the world's seas, oceans, and countries.

    Science.gov (United States)

    Costello, Mark John; Cheung, Alan; De Hauwere, Nathalie

    2010-12-01

    Depth and topography directly and indirectly influence most ocean environmental conditions, including light penetration and photosynthesis, sedimentation, current movements and stratification, and thus temperature and oxygen gradients. These parameters are thus likely to influence species distribution patterns and productivity in the oceans. They may be considered the foundation for any standardized classification of ocean ecosystems and important correlates of metrics of biodiversity (e.g., species richness and composition, fisheries). While statistics on ocean depth and topography are often quoted, how they were derived is rarely cited, and unless calculated using the same spatial resolution the resulting statistics will not be strictly comparable. We provide such statistics using the best available resolution (1-min) global bathymetry, and open source digital maps of the world's seas and oceans and countries' Exclusive Economic Zones, using a standardized methodology. We created a terrain map and calculated sea surface and seabed area, volume, and mean, standard deviation, maximum, and minimum, of both depth and slope. All the source data and our database are freely available online. We found that although the ocean is flat, and up to 71% of the area has a ocean volume exceeds 1.3 billion km(3) (or 1.3 sextillion liters), and sea surface and seabed areas over 354 million km(2). We propose the coefficient of variation of slope as an index of topographic heterogeneity. Future studies may improve on this database, for example by using a more detailed bathymetry, and in situ measured data. The database could be used to classify ocean features, such as abyssal plains, ridges, and slopes, and thus provide the basis for a standards based classification of ocean topography.

  6. Seasonal Variations of the Earth's Gravitational Field: An Analysis of Atmospheric Pressure, Ocean Tidal, and Surface Water Excitation

    Science.gov (United States)

    Dong, D,; Gross, R.S.; Dickey, J.

    1996-01-01

    Monthly mean gravitational field parameters (denoted here as C(sub even)) that represent linear combinations of the primarily even degree zonal spherical harmonic coefficients of the Earth's gravitational field have been recovered using LAGEOS I data and are compared with those derived from gridded global surface pressure data of the National meteorological center (NMC) spanning 1983-1992. The effect of equilibrium ocean tides and surface water variations are also considered. Atmospheric pressure and surface water fluctuations are shown to be the dominant cause of observed annual C(sub even) variations. Closure with observations is seen at the 1sigma level when atmospheric pressure, ocean tide and surface water effects are include. Equilibrium ocean tides are shown to be the main source of excitation at the semiannual period with closure at the 1sigma level seen when both atmospheric pressure and ocean tide effects are included. The inverted barometer (IB) case is shown to give the best agreement with the observation series. The potential of the observed C(sub even) variations for monitoring mass variations in the polar regions of the Earth and the effect of the land-ocean mask in the IB calculation are discussed.

  7. Monitoring and assessment of ocean acidification in the Arctic Ocean-A scoping paper

    Science.gov (United States)

    Robbins, Lisa L.; Yates, Kimberly K.; Feely, Richard; Fabry, Victoria

    2010-01-01

    Carbon dioxide (CO2) in the atmosphere is absorbed at the ocean surface by reacting with seawater to form a weak, naturally occurring acid called carbonic acid. As atmospheric carbon dioxide increases, the concentration of carbonic acid in seawater also increases, causing a decrease in ocean pH and carbonate mineral saturation states, a process known as ocean acidification. The oceans have absorbed approximately 525 billion tons of carbon dioxide from the atmosphere, or about one-quarter to one-third of the anthropogenic carbon emissions released since the beginning of the Industrial Revolution. Global surveys of ocean chemistry have revealed that seawater pH has decreased by about 0.1 units (from a pH of 8.2 to 8.1) since the 1700s due to absorption of carbon dioxide (Raven and others, 2005). Modeling studies, based on Intergovernmental Panel on Climate Change (IPCC) CO2 emission scenarios, predict that atmospheric carbon dioxide levels could reach more than 500 parts per million (ppm) by the middle of this century and 800 ppm by the year 2100, causing an additional decrease in surface water pH of 0.3 pH units. Ocean acidification is a global threat and is already having profound and deleterious effects on the geology, biology, chemistry, and socioeconomic resources of coastal and marine habitats. The polar and sub-polar seas have been identified as the bellwethers for global ocean acidification.

  8. The importance of kinetics and redox in the biogeochemical cycling of iron in the surface ocean.

    Directory of Open Access Journals (Sweden)

    Peter L. Croot

    2012-06-01

    Full Text Available It is now well established that Iron (Fe is a limiting element in many regions of the open ocean. Our current understanding of the key processes which control iron distribution in the open ocean have been largely based on thermodynamic measurements performed under the assumption of equilibrium conditions. Using this equilibrium approach, researchers have been able to detect and quantify organic complexing ligands in seawater and examine their role in increasing the overall solubility of iron. Our current knowledge about iron bioavailability to phytoplankton and bacteria is also based heavily on carefully controlled laboratory studies where it is assumed the chemical species are in equilibrium in line with the free ion association model (FIAM and/or its successor the biotic ligand model (BLM. Similarly most field work on Fe biogeochemistry generally consists of a single profile which is in essence a ‘snap-shot’ in time of the system under investigation. However it is well known that the surface ocean is an extremely dynamic environment and it is unlikely if thermodynamic equilibrium between all the iron species present is ever truly achieved. In sunlit waters this is mostly due to the daily passage of the sun across the sky leading to photoredox processes which alter Fe speciation by cycling between redox states and between inorganic and organic species. Episodic deposition events, are also important perturbations to iron cycling as they bring new iron to the system altering the equilibrium between species and phases. Over the last 20 years the mesoscale iron enrichment experiments (e.g. IronEx I /II, SOIREE, EisenEx, SOFeX, EIFeX, SAGE, SEEDS and SERIES I /II and the FeCycle (I/II experiments have provided the first insights into processes altering iron speciation and distribution which occur over temporal scales of days to weeks. Here we utilize new field data collected in the open ocean on the redox and complexation kinetics of iron in the

  9. Temperature and surface-ocean water balance of the mid-holocene tropical western Pacific

    Energy Technology Data Exchange (ETDEWEB)

    Gagan, M.K.; Ayliffe, K.K.; Cali, J.A. [Australian National Univ., Canberra (Australia)] [and others

    1998-02-13

    Skeletal Sr/Ca and {sup 18}O/{sup 16}O ratios in corals from the Great Barrier Reef, Australia, indicate that the tropical ocean surface {approx} 5350 years ago was 1{degree}C warmer and enriched in {sup 18}O by 0.5 per mil relative to modern seawater. The results suggest that the temperature increase enhanced the evaporative enrichment of {sup 18}O in seawater. Transport of part of the additional atmospheric water vapor to extratropical latitudes may have sustained the {sup 18}O/{sup 16}O anomaly. The reduced glacial-Holocene shift in seawater {sup 18}O/{sup 16}O ratio produced by the mid-Holocene {sup 18}O enrichment may help to reconcile the different temperature histories for the last deglaciation given by coral Sr/Ca thermometry and foraminiferal oxygen-isotope records. 37 refs., 2 figs., 1 tab.

  10. Non-monotonic swelling of surface grafted hydrogels induced by pH and/or salt concentration

    Science.gov (United States)

    Longo, Gabriel S.; Olvera de la Cruz, Monica; Szleifer, I.

    2014-09-01

    We use a molecular theory to study the thermodynamics of a weak-polyacid hydrogel film that is chemically grafted to a solid surface. We investigate the response of the material to changes in the pH and salt concentration of the buffer solution. Our results show that the pH-triggered swelling of the hydrogel film has a non-monotonic dependence on the acidity of the bath solution. At most salt concentrations, the thickness of the hydrogel film presents a maximum when the pH of the solution is increased from acidic values. The quantitative details of such swelling behavior, which is not observed when the film is physically deposited on the surface, depend on the molecular architecture of the polymer network. This swelling-deswelling transition is the consequence of the complex interplay between the chemical free energy (acid-base equilibrium), the electrostatic repulsions between charged monomers, which are both modulated by the absorption of ions, and the ability of the polymer network to regulate charge and control its volume (molecular organization). In the absence of such competition, for example, for high salt concentrations, the film swells monotonically with increasing pH. A deswelling-swelling transition is similarly predicted as a function of the salt concentration at intermediate pH values. This reentrant behavior, which is due to the coupling between charge regulation and the two opposing effects triggered by salt concentration (screening electrostatic interactions and charging/discharging the acid groups), is similar to that found in end-grafted weak polyelectrolyte layers. Understanding how to control the response of the material to different stimuli, in terms of its molecular structure and local chemical composition, can help the targeted design of applications with extended functionality. We describe the response of the material to an applied pressure and an electric potential. We present profiles that outline the local chemical composition of the

  11. Correlations Between Sea-Surface Salinity Tendencies and Freshwater Fluxes in the Pacific Ocean

    Science.gov (United States)

    Li, Zhen; Adamec, David

    2007-01-01

    Temporal changes in sea-surface salinity (SSS) from 21 years of a high resolution model integration of the Pacific Ocean are correlated with the freshwater flux that was used to force the integration. The correlations are calculated on a 1 x10 grid, and on a monthly scale to assess the possibility of deducing evaporation minus precipitation (E-P) fields from the salinity measurements to be taken by the upcoming Aquarius/SAC-D mission. Correlations between the monthly mean E-P fields and monthly mean SSS temporal tendencies are mainly zonally-oriented, and are highest where the local precipitation is relatively high. Nonseasonal (deviations from the monthly mean) correlations are highest along mid-latitude storm tracks and are relatively small in the tropics. The response of the model's surface salinity to surface forcing is very complex, and retrievals of freshwater fluxes from SSS measurements alone will require consideration of other processes, including horizontal advection and vertical mixing, rather than a simple balance between the two.

  12. Correlation characteristics of signals reflected by the wavy surface of ocean in mirror direction

    Science.gov (United States)

    Zhitkovskiy, Y. Y.; Nosov, A. V.; Savelyev, V. V.

    1985-06-01

    An experimental study was carried out to determine the correlation characteristics of pseudonoise signals reflected from a wave-covered surface in the mirror direction. The major measured quantity was the reciprocal correlation coefficient between the transmitted signal and the reflected signal. The transmitter was lowered from a ship on a 150 m cable. The receiver and preamplifier were lowered to the same depth from a buoy which was allowed to drift from the ship to a distance of 100-500 m, the changing distance changing the angle of the beam reflected from the surface of the ocean back down to the hydrophone. The radiator transmitted a pulsed signal with a pseudonoise carrier. The results were interpreted within the framework of ordinary correlation theory by processing several recordings, calculating the sign and ordinary correlation coefficients to determine the variation in sign correlation coefficient as a function of the ordinary correlation coefficient. Graphs of the average variation are presented. It was found that the medium did not distort the signal as it propagated through the water mass (within the limits of experimental accuracy). The correlation coefficient between the transmitted and reflected signals is thus determined entirely by the characteristics of reradiation of the sound by the wavecovered surface.

  13. How well will the Surface Water and Ocean Topography (SWOT) mission observe global reservoirs?

    Science.gov (United States)

    Solander, Kurt C.; Reager, John T.; Famiglietti, James S.

    2016-03-01

    Accurate observations of global reservoir storage are critical to understand the availability of managed water resources. By enabling estimates of surface water area and height for reservoir sizes exceeding 250 m2 at a maximum repeat orbit of up to 21 days, the NASA Surface Water and Ocean Topography (SWOT) satellite mission (anticipated launch date 2020) is expected to greatly improve upon existing reservoir monitoring capabilities. It is thus essential that spatial and temporal measurement uncertainty for water bodies is known a priori to maximize the utility of SWOT observations as the data are acquired. In this study, we evaluate SWOT reservoir observations using a three-pronged approach that assesses temporal aliasing, errors due to specific reservoir spatial properties, and SWOT performance over actual reservoirs using a combination of in situ and simulated reservoir observations from the SWOTsim instrument simulator. Results indicate temporal errors to be less than 5% for the smallest reservoir sizes (100 km2). Surface area and height errors were found to be minimal (area SWOT, this study will be have important implications for future applications of SWOT reservoir measurements in global monitoring systems and models.

  14. An explanation for the different climate sensitivities of land and ocean surfaces based on the diurnal cycle

    Directory of Open Access Journals (Sweden)

    A. Kleidon

    2017-09-01

    Full Text Available Observations and climate model simulations consistently show a higher climate sensitivity of land surfaces compared to ocean surfaces. Here we show that this difference in temperature sensitivity can be explained by the different means by which the diurnal variation in solar radiation is buffered. While ocean surfaces buffer the diurnal variations by heat storage changes below the surface, land surfaces buffer it mostly by heat storage changes above the surface in the lower atmosphere that are reflected in the diurnal growth of a convective boundary layer. Storage changes below the surface allow the ocean surface–atmosphere system to maintain turbulent fluxes over day and night, while the land surface–atmosphere system maintains turbulent fluxes only during the daytime hours, when the surface is heated by absorption of solar radiation. This shorter duration of turbulent fluxes on land results in a greater sensitivity of the land surface–atmosphere system to changes in the greenhouse forcing because nighttime temperatures are shaped by radiative exchange only, which are more sensitive to changes in greenhouse forcing. We use a simple, analytic energy balance model of the surface–atmosphere system in which turbulent fluxes are constrained by the maximum power limit to estimate the effects of these different means to buffer the diurnal cycle on the resulting temperature sensitivities. The model predicts that land surfaces have a 50 % greater climate sensitivity than ocean surfaces, and that the nighttime temperatures on land increase about twice as much as daytime temperatures because of the absence of turbulent fluxes at night. Both predictions compare very well with observations and CMIP5 climate model simulations. Hence, the greater climate sensitivity of land surfaces can be explained by its buffering of diurnal variations in solar radiation in the lower atmosphere.

  15. Effect of growth at low pH on the cell surface properties of a typical strain of Lactobacillus casei group.

    Science.gov (United States)

    Hossein Nezhad, M; Stenzel, Dj; Britz, Ml

    2010-09-01

    Although members of the Lactobacillus casei group are known to survive under acidic conditions, the underlying mechanisms of growth at acidic condition and the impact of low pH on the relative level of protein expression at the cell surface remain poorly studied. After confirming the taxonomy of L. casei strain GCRL 12 which was originally isolated from cheese and confirmed by 16S rRNA sequence analysis, the impact of acidic pH on growth rate was determined. Late log-phase cells cultured at pH 4.0 showed obvious changes in Gram staining properties while transmission electron microscopy analysis revealed evidence of structural distortions of the cell surface relative to the controls cultured at pH 6.5. When comparing cytosolic or whole cell preparations on SDS-PAGE, few changes in protein profiles were observed under the two growth conditions. However, analysis of surface protein extracted by 5M LiCl demonstrated changes in the proportions of proteins present in the molecular weight range of 10 to 80 kDa, with some proteins more dominant at pH 6.5 and other at pH 4. These data suggest that surface proteins of this strain are associated with growth and survival at low pH. The function of these proteins is subject to further investigation.

  16. Dissolved inorganic carbon, pH, temperature, salinity and other variables collected from time series and surface observations using Moored Autonomous Dissolved Inorganic Carbon (MADIC) System, Sunburst SAMI2 pH sensor, and other instruments from Kewalo Buoy near the coast of Honolulu, Hawaii from 2013-10-31 to 2014-06-15 (NCEI Accession 0132048)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — To expand the number of tools available for autonomous carbonate system observations, we have developed a robust surface ocean dissolved inorganic carbon (DIC)...

  17. A Novel Low-cost, Ka-band, High Altitude, Multi-Baseline Unmanned Aerial Vehicle Sensor for Surface Water Ocean Topography, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — The NRC Decadal Survey recommended the Surface Water Ocean Topography (SWOT) satellite mission to address terrestrial fresh water hydrology and physical oceanography...

  18. Surface pH changes suggest a role for H+/OH-channels in salinity response of Chara australis.

    Science.gov (United States)

    Absolonova, Marketa; Beilby, Mary J; Sommer, Aniela; Hoepflinger, Marion C; Foissner, Ilse

    2017-12-15

    To understand salt stress, the full impact of salinity on plant cell physiology has to be resolved. Electrical measurements suggest that salinity inhibits the proton pump and opens putative H + /OH - channels all over the cell surface of salt sensitive Chara australis (Beilby and Al Khazaaly 2009; Al Khazaaly and Beilby 2012). The channels open transiently at first, causing a characteristic noise in membrane potential difference (PD), and after longer exposure remain open with a typical current-voltage (I/V) profile, both abolished by the addition of 1 mM ZnCl 2 , the main known blocker of animal H + channels. The cells were imaged with confocal microscopy, using fluorescein isothiocyanate (FITC) coupled to dextran 70 to illuminate the pH changes outside the cell wall in artificial fresh water (AFW) and in saline medium. In the early saline exposure, we observed alkaline patches (bright fluorescent spots) appearing transiently in random spatial distribution. After longer exposure, some of the spots became fixed in space. Saline also abolished or diminished the pH banding pattern observed in the untreated control cells. ZnCl 2 suppressed the alkaline spot formation in saline and the pH banding pattern in AFW. The osmotic component of the saline stress did not produce transient bright spots or affect banding. The displacement of H + from the cell wall charges, the H + /OH - channel conductance/density, and self-organization are discussed. No homologies to animal H + channels were found. Salinity activation of the H + /OH - channels might contribute to saline response in roots of land plants and leaves of aquatic angiosperms.

  19. Ocean Surface Topography Mission (OSTM) /Jason-2 Data Collection, 2008-present (NODC Accession 0118277)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — OSTM/JASON-2 is a follow-on mission continuing the TOPEX/Poseidon and Jason-1, and is designed to ensure continuity of high quality measurements for ocean science...

  20. Ocean Surface Topography Mission (OSTM) /Jason-2: Level-2 Geophysical Data Records (GDR) (NODC Accession 0043269)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — OSTM/JASON-2 is a follow-on mission continuing the TOPEX/Poseidon and Jason-1, and is designed to ensure continuity of high quality measurements for ocean science...

  1. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Micro-porous membrane equilibrator and other instruments from WAKATAKA MARU in the North Atlantic Ocean, North Pacific Ocean and South Atlantic Ocean from 2011-06-10 to 2011-12-06 (NCEI Accession 0157428)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157428 includes Surface underway, chemical, meteorological and physical data collected from WAKATAKA MARU in the North Atlantic Ocean, North Pacific...

  2. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Barometric pressure sensor, Carbon dioxide (CO2) gas analyzer and other instruments from Investigator in the North Pacific Ocean, South Pacific Ocean and Southern Oceans from 2016-04-26 to 2016-06-29 (NCEI Accession 0160555)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0160555 includes Surface underway, chemical, meteorological and physical data collected from Investigator in the North Pacific Ocean, South Pacific...

  3. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from surface underway observations using Carbon dioxide (CO2) gas analyzer and other instruments from LAURENCE M. GOULD in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2012-12-31 to 2013-12-19 (NCEI Accession 0163187)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0163187 includes chemical, meteorological, physical and surface underway data collected from LAURENCE M. GOULD in the South Atlantic Ocean, South...

  4. Near 7-day response of ocean bottom pressure to atmospheric surface pressure and winds in the northern South China Sea

    Science.gov (United States)

    Zhang, Kun; Zhu, Xiao-Hua; Zhao, Ruixiang

    2018-02-01

    Ocean bottom pressures, observed by five pressure-recording inverted echo sounders (PIESs) from October 2012 to July 2014, exhibit strong near 7-day variability in the northern South China Sea (SCS) where long-term in situ bottom pressure observations are quite sparse. This variability was strongest in October 2013 during the near two years observation period. By joint analysis with European Center for Medium-Range Weather Forecasts (ECMWF) data, it is shown that the near 7-day ocean bottom pressure variability is closely related to the local atmospheric surface pressure and winds. Within a period band near 7 days, there are high coherences, exceeding 95% significance level, of observed ocean bottom pressure with local atmospheric surface pressure and with both zonal and meridional components of the wind. Ekman pumping/suction caused by the meridional component of the wind in particular, is suggested as one driving mechanism. A Kelvin wave response to the near 7-day oscillation would propagate down along the continental slope, observed at the Qui Nhon in the Vietnam. By multiple and partial coherence analyses, we find that local atmospheric surface pressure and Ekman pumping/suction show nearly equal influence on ocean bottom pressure variability at near 7-day periods. A schematic diagram representing an idealized model gives us a possible mechanism to explain the relationship between ocean bottom pressure and local atmospheric forcing at near 7-day periods in the northern SCS.

  5. Solutions Network Formulation Report: Improving NOAA's PORTS(R) Through Enhanced Data Inputs from NASA's Ocean Surface Topography Mission

    Science.gov (United States)

    Guest, DeNeice

    2007-01-01

    The Nation uses water-level data for a variety of practical purposes, including nautical charting, maritime navigation, hydrography, coastal engineering, and tsunami and storm surge warnings. Long-term applications include marine boundary determinations, tidal predictions, sea-level trend monitoring, oceanographic research, and climate research. Accurate and timely information concerning sea-level height, tide, and ocean current is needed to understand their impact on coastal management, disaster management, and public health. Satellite altimeter data products are currently used by hundreds of researchers and operational users to monitor ocean circulation and to improve scientists understanding of the role of the oceans in climate and weather. The NOAA (National Oceanic and Atmospheric Administration) National Ocean Service has been monitoring sea-level variations for many years. NOAA s PORTS (Physical Oceanographic Real-Time System) DST (decision support tool), managed by the Center for Operational Oceanographic Products and Services, supports safe and cost-efficient navigation by providing ship masters and pilots with accurate real-time information required to avoid groundings and collisions. This report assesses the capacity of NASA s satellite altimeter data to meet societal decision support needs through incorporation into NOAA s PORTS. NASA has a long heritage of collecting data for ocean research, including its current Terra and Aqua missions. Numerous other missions provide additional important information for coastal management issues, and data collection will continue in the coming decade with such missions as the OSTM (Ocean Surface Topography Mission). OSTM will provide data on sea-surface heights for determining ocean circulation, climate change, and sea-level rise. We suggest that NASA incorporate OSTM altimeter data (C- and Ku-band) into NOAA s PORTS DST in support of NASA s Coastal Management National Application with secondary support to the

  6. Simulation of the Impact of New Ocean Surface Wind Measurements on H*Wind Analyses

    Science.gov (United States)

    Miller, Timothy; Atlas, Robert; Black, Peter; Chen, Shuyi; Hood, Robbie; Johnson, James; Jones, Linwood; Ruf, Chris; Uhlhorn, Eric

    2008-01-01

    The H*Wind analysis, a product of the Hurricane Research Division of NOAA's Atlantic Oceanographic and Meteorological Laboratory, brings together wind measurements from a variety of observation platforms into an objective analysis of the distribution of surface wind speeds in a tropical cyclone. This product is designed to improve understanding of the extent and strength of the wind field, and to improve the assessment of hurricane intensity. See http://www.aoml.noaa.gov/hrd/data sub/wind.html. The Hurricane Imaging Radiometer (HIRAD) is a new passive microwave remote sensor for hurricane observations that is currently under development by NASA Marshall Space Flight Center, NOAA Hurricane Research Division, the University of Central Florida and the University of Michigan. HIRAD is being designed to enhance the current real-time airborne ocean surface winds observation capabilities of NOAA and USAF Weather Squadron hurricane hunter aircraft using the operational airbome Stepped Frequency Microwave Radiometer (SFMR). Unlike SFMR, which measures wind speed and rain rate along the ground track directly beneath the aircraft, HIRAD will provide images of the surface wind and rain field over a wide swath (approximately 3 x the aircraft altitude, or approximately 2 km from space). The instrument is described in a separate paper presented at this conference. The present paper describes a set of Observing System Simulation Experiments (OSSEs) in which measurements from the new instrument as well as those from existing instruments (air, surface, and space-based) are simulated from the output of a numerical model from the University of Miami, and those results are used to construct H*Wind analyses. Evaluations will be presented on the relative impact of HIRAD and other instruments on H*Wind analyses, including the use of HIRAD from 2 aircraft altitudes and from a space-based platform.

  7. Evaluation of the Ca ion release, pH and surface apatite formation of a prototype tricalcium silicate cement.

    Science.gov (United States)

    Yamamoto, S; Han, L; Noiri, Y; Okiji, T

    2017-12-01

    To evaluate the Ca 2+ -releasing, alkalizing and apatite-like surface precipitate-forming abilities of a prototype tricalcium silicate cement, which was mainly composed of synthetically prepared tricalcium silicate and zirconium oxide radiopacifier. The prototype tricalcium silicate cement, white ProRoot MTA (WMTA) and TheraCal LC (a light-cured resin-modified calcium silicate-filled material) were examined. The chemical compositions were analysed with a wavelength-dispersive X-ray spectroscopy electron probe microanalyser with an image observation function (SEM-EPMA). The pH and Ca 2+ concentrations of water in which the set materials had been immersed were measured, and the latter was assessed with the EDTA titration method. The surface precipitates formed on the materials immersed in phosphate-buffered saline (PBS) were analysed with SEM-EPMA and X-ray diffraction (XRD). Kruskal-Wallis tests followed by Mann-Whitney U-test with Bonferroni correction were used for statistical analysis (α = 0.05). The prototype cement contained Ca, Si and Zr as major elemental constituents, whereas it did not contain some metal elements that were detected in the other materials. The Ca 2+ concentrations and pH of the immersion water samples exhibited the following order: WMTA = prototype cement > TheraCal LC (P prototype cement and WMTA. The prototype tricalcium silicate cement exhibited similar Ca 2+ -releasing, alkalizing and apatite-like precipitate-forming abilities to WMTA. The Ca 2+ -releasing, alkalizing and apatite-like precipitate-forming abilities of TheraCal LC were lower than those of the other materials. © 2016 International Endodontic Journal. Published by John Wiley & Sons Ltd.

  8. Response of the North Atlantic surface and intermediate ocean structure to climate warming of MIS 11.

    Science.gov (United States)

    Kandiano, Evgenia S; van der Meer, Marcel T J; Schouten, Stefan; Fahl, Kirsten; Sinninghe Damsté, Jaap S; Bauch, Henning A

    2017-04-10

    Investigating past interglacial climates not only help to understand how the climate system operates in general, it also forms a vital basis for climate predictions. We reconstructed vertical stratification changes in temperature and salinity in the North Atlantic for a period some 400 ka ago (MIS11), an interglacial time analogue of a future climate. As inferred from a unique set of biogeochemical, geochemical, and faunal data, the internal upper ocean stratification across MIS 11 shows distinct depth-dependent dynamical changes related to vertical as well as lateral shifts in the upper Atlantic meridional circulation system. Importantly, transient cold events are recognized near the end of the long phase of postglacial warming at surface, subsurface, mid, and deeper water layers. These data demonstrate that MIS 11 coolings over the North Atlantic were initially triggered by freshwater input at the surface and expansion of cold polar waters into the Subpolar Gyre. The cooling signal was then transmitted downwards into mid-water depths. Since the cold events occurred after the main deglacial phase we suggest that their cause might be related to continuous melting of the Greenland ice sheet, a mechanism that might also be relevant for the present and upcoming climate.

  9. Surface temperatures of the Mid-Pliocene North Atlantic Ocean: Implications for future climate

    Science.gov (United States)

    Dowsett, Harry J.; Chandler, Mark A.; Robinson, Marci M.

    2009-01-01

    The Mid-Pliocene is the most recent interval in the Earth's history to have experienced warming of the magnitude predicted for the second half of the twenty-first century and is, therefore, a possible analogue for future climate conditions. With continents basically in their current positions and atmospheric CO2 similar to early twenty-first century values, the cause of Mid-Pliocene warmth remains elusive. Understanding the behaviour of the North Atlantic Ocean during the Mid-Pliocene is integral to evaluating future climate scenarios owing to its role in deep water formation and its sensitivity to climate change. Under the framework of the Pliocene Research, Interpretation and Synoptic Mapping (PRISM) sea surface reconstruction, we synthesize Mid-Pliocene North Atlantic studies by PRISM members and others, describing each region of the North Atlantic in terms of palaeoceanography. We then relate Mid-Pliocene sea surface conditions to expectations of future warming. The results of the data and climate model comparisons suggest that the North Atlantic is more sensitive to climate change than is suggested by climate model simulations, raising the concern that estimates of future climate change are conservative.

  10. Statistical multi-model climate projections of surface ocean waves in Europe

    Science.gov (United States)

    Perez, Jorge; Menendez, Melisa; Camus, Paula; Mendez, Fernando J.; Losada, Inigo J.

    2015-12-01

    In recent years, the impact of climate change on sea surface waves has received increasingly more attention by the climate community. Indeed, ocean waves reaching the coast play an important role in several processes concerning coastal communities, such as inundation and erosion. However, regional downscaling at the high spatial resolution necessary for coastal studies has received less attention. Here, we present a novel framework for regional wave climate projections and its application in the European region. Changes in the wave dynamics under different scenarios in the Northeast Atlantic Ocean and the Mediterranean are analyzed. The multi-model projection methodology is based on a statistical downscaling approach. The statistical relation between the predictor (atmospheric conditions) and the predictand (multivariate wave climate) is based on a weather type (WT) classification. This atmospheric classification is developed by applying the k-means clustering technique over historical offshore sea level pressure (SLP) fields. Each WT is linked to sea wave conditions from a wave hindcast. This link is developed by associating atmospheric conditions from reanalysis with multivariate local waves. This predictor-predictand relationship is applied to the daily SLP fields from global climate models (GCMs) in order to project future changes in regional wave conditions. The GCMs used in the multi-model projection are selected according to skill criteria. The application of this framework uses CMIP5-based wave climate projections in Europe. The low computational requirements of the statistical approach allow a large number of GCMs and climate change scenarios to be studied. Consistent with previous works on global wave climate projections, the estimated changes from the regional wave climate projections show a general decrease in wave heights and periods in the Atlantic Europe for the late twenty-first century. The regional projections, however, allow a more detailed

  11. High-Resolution Specification of the Land and Ocean Surface for Improving Regional Mesoscale Model Predictions

    Science.gov (United States)

    Case, Jonathan L.; Lazarus, Steven M.; Splitt, Michael E.; Crosson, William L.; Lapenta, William M.; Jedlovec, Gary J.; Peters-Lidard, Christa D.

    2008-01-01

    The exchange of energy and moisture between the Earth's surface and the atmospheric boundary layer plays a critical role in many meteorological processes. High-resolution, accurate representations of surface properties such as sea-surface temperature (SST), soil temperature and moisture content, ground fluxes, and vegetation are necessary to better understand the Earth-atmosphere interactions and improve numerical predictions of sensible weather. The NASA Short-term Prediction Research and Transition (SPoRT) Center has been conducting separate studies to examine the impacts of high-resolution land-surface initialization data from the Goddard Space Flight Center Land Information System (LIS) on subsequent WRF forecasts, as well as the influence of initializing WRF with SST composites derived from the MODIS instrument. This current project addresses the combined impacts of using high-resolution lower boundary data over both land (LIS data) and water (MODIS SSTs) on the subsequent daily WRF forecasts over Florida during May 2004. For this experiment, the WRF model is configured to run on a nested domain with 9- km and 3-kin grid spacing, centered on the Florida peninsula and adjacent coastal waters of the Gulf of Mexico and Atlantic Ocean. A control configuration of WRF is established to take all initial condition data from the NCEP Eta model. Meanwhile, two WRF experimental runs are configured to use high-resolution initialization data from (1) LIS land-surface data only, and (2) a combination of LIS data and high-resolution MODIS SST composites. The experiment involves running 24-hour simulations of the control WRF configuration, the MS-initialized WRF, and the LIS+MODIS-initialized WRF daily for the entire month of May 2004. All atmospheric data for initial and boundary conditions for the Control, LIS, and LIS+MODIS runs come from the NCEP Eta model on a 40-km grid. Verification statistics are generated at land surface observation sites and buoys, and the impacts

  12. On the role of surface heat budget parameters over the tropical Indian Ocean in relation to the summer monsoon

    Digital Repository Service at National Institute of Oceanography (India)

    RameshKumar, M.R.; Sastry, J.S.

    This study presents the role of sea surface temperature (SST) in the Arabian Sea and Bay of Bengal, cloud motion vector winds in the Equatorial Indian Ocean, and the cold fronts in the South Africa-Malagassy region on the onset and quantum...

  13. Late Holocene (0-2.4 ka BP) surface water temperature and salinity variability, Feni Drift, NE Atlantic Ocean

    NARCIS (Netherlands)

    Richter, T.O.; Peeters, F.J.C.; van Weering, T.C.E.

    2009-01-01

    Planktonic foraminiferal Mg/Ca ratios and oxygen isotopic compositions of a spliced sediment record from Feni Drift, NE Atlantic Ocean (box core M200309 and piston core ENAM9606) trace late Holocene sea surface temperature (SST) and salinity changes over the past 2400 years. At this location, the

  14. Sea surface height determination in the arctic ocean from Cryosat2 SAR data, the impact of using different empirical retrackers

    DEFF Research Database (Denmark)

    Jain, Maulik; Andersen, Ole Baltazar; Stenseng, Lars

    2012-01-01

    Cryosat2 Level 1B SAR data can be processed using different empirical retrackers to determine the sea surface height and its variations in the Arctic Ocean. Two improved retrackers based on the combination of OCOG (Offset Centre of Gravity), Threshold methods and Leading Edge Retrieval is used...... to estimate the sea surface height in the Arctic Region. This sea surface height determination is to be compared with the Level2 sea surface height components available in the Cryosat2 data. Further a comparison is done with the marine gravity field for retracker performance evaluation....

  15. Impact of surface ocean conditions and aerosol provenance on the dissolution of aerosol manganese, cobalt, nickel and lead in seawater

    OpenAIRE

    Fishwick, MP; Ussher, SJ; Sedwick, PN; Lohan, MC; Worsfold, PJ; Buck, KN; Church, TM

    2018-01-01

    © 2017. Atmospheric deposition is an important pathway by which bioactive trace metals are delivered to the surface ocean. The proportions of total aerosol trace metals that dissolve in seawater, and thus become available to biota, are not well constrained and are therefore a key uncertainty when estimating atmospheric fluxes of these elements to surface waters. The aim of this study was to elucidate the main physico-chemical controls on the dissolution of the bioactive trace metals manganese...

  16. [Measurements of surface ocean carbon dioxide partial pressure during WOCE]. Summary of research progress

    Energy Technology Data Exchange (ETDEWEB)

    1992-12-31

    This paper discusses the research progress of the second year of research under ``Measurement of Surface Ocean Carbon Dioxide Partial Pressure During WOCE`` and proposes to continue measurements of underway pCO{sub 2}. During most of the first year of this grant, our efforts to measure pCO{sub 2} on WOCE WHP legs were frustrated by ship problems. The R/V Knorr, which was originally scheduled to carry out the first work on WHP lines P19 and P16 in the southeastem Pacific during the 1990-91 austral summer, was delayed in the shipyard during her mid-life refit for more than a year. In the interim, the smaller R/V Thomas Washington, was pressed into service to carry out lower-latitude portions of WHP lines P16 and P17 during mid-1991 (TUNES Expedition). We installed and operated our underway chromatographic system on this expedition, even though space and manpower on this smaller vessel were limited and no one from our group would be aboard any of the 3 WHP expedition legs. The results for carbon dioxide and nitrous oxide are shown. A map of the cruise track is shown for each leg, marked with cumulative distance. Following each track is a figure showing the carbon dioxide and nitrous oxide results as a function of distance along this track. The results are plotted as dry-gas mole fractions (in ppm and ppb, respectively) in air and in gas equilibrated with surface seawater at a total pressure equal to the barometric pressure. The air data are plotted as a 10-point running mean, and appear as a roughly horizontal line. The seawater data are plotted as individual points, using a 5-point Gaussian smoother. Equal values Of xCO{sub 2} in air and surface seawater indicate air-sea equilibrium.

  17. Automated River Reach Definition Strategies: Applications for the Surface Water and Ocean Topography Mission

    Science.gov (United States)

    Frasson, Renato Prata de Moraes; Wei, Rui; Durand, Michael; Minear, J. Toby; Domeneghetti, Alessio; Schumann, Guy; Williams, Brent A.; Rodriguez, Ernesto; Picamilh, Christophe; Lion, Christine; Pavelsky, Tamlin; Garambois, Pierre-André

    2017-10-01

    The upcoming Surface Water and Ocean Topography (SWOT) mission will measure water surface heights and widths for rivers wider than 100 m. At its native resolution, SWOT height errors are expected to be on the order of meters, which prevent the calculation of water surface slopes and the use of slope-dependent discharge equations. To mitigate height and width errors, the high-resolution measurements will be grouped into reaches (˜5 to 15 km), where slope and discharge are estimated. We describe three automated river segmentation strategies for defining optimum reaches for discharge estimation: (1) arbitrary lengths, (2) identification of hydraulic controls, and (3) sinuosity. We test our methodologies on 9 and 14 simulated SWOT overpasses over the Sacramento and the Po Rivers, respectively, which we compare against hydraulic models of each river. Our results show that generally, height, width, and slope errors decrease with increasing reach length. However, the hydraulic controls and the sinuosity methods led to better slopes and often height errors that were either smaller or comparable to those of arbitrary reaches of compatible sizes. Estimated discharge errors caused by the propagation of height, width, and slope errors through the discharge equation were often smaller for sinuosity (on average 8.5% for the Sacramento and 6.9% for the Po) and hydraulic control (Sacramento: 7.3% and Po: 5.9%) reaches than for arbitrary reaches of comparable lengths (Sacramento: 8.6% and Po: 7.8%). This analysis suggests that reach definition methods that preserve the hydraulic properties of the river network may lead to better discharge estimates.

  18. The Surface Ocean CO2 Atlas: Stewarding Underway Carbon Data from Collection to Archival

    Science.gov (United States)

    O'Brien, K.; Smith, K. M.; Pfeil, B.; Landa, C.; Bakker, D. C. E.; Olsen, A.; Jones, S.; Shrestha, B.; Kozyr, A.; Manke, A. B.; Schweitzer, R.; Burger, E. F.

    2016-02-01

    The Surface Ocean CO2 Atlas (SOCAT, www.socat.info) is a quality controlled, global surface ocean carbon dioxide (CO2) data set gathered on research vessels, SOOP and buoys. To the degree feasible SOCAT is comprehensive; it draws together and applies uniform QC procedures to all such observations made across the international community. The first version of SOCAT (version 1.5) was publicly released September 2011(Bakker et al., 2011) with 6.3 million observations. This was followed by the release of SOCAT version 2, expanded to over 10 million observations, in June 2013 (Bakker et al., 2013). Most recently, in September 2015 SOCAT version 3 was released containing over 14 millions observations spanning almost 60 years! The process of assembling, QC'ing and publishing V1.5 and V2 of SOCAT required an unsustainable level of manual effort. To ease the burden on data managers and data providers, the SOCAT community agreed to embark an automated data ingestion process which would create a streamlined workflow to improve data stewardship from ingestion to quality control and from publishing to archival. To that end, for version 3 and beyond, the SOCAT automation team created a framework which was based upon standards and conventions, yet at the same time allows scientists to work in the data formats they felt most comfortable with (ie, csv files). This automated workflow provides several advantages: 1) data ingestion into uniform and standards-based file formats; 2) ease of data integration into standard quality control system; 3) data ingestion and quality control can be performed in parallel; 4) provides uniform method of archiving carbon data and generation of digital object identifiers (DOI).In this presentation, we will discuss and demonstrate the SOCAT data ingestion dashboard and the quality control system. We will also discuss the standards, conventions, and tools that were leveraged to create a workflow that allows scientists to work in their own formats, yet

  19. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, salinity and other variables collected from underway - surface observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from the POLARSTERN in the Indian Ocean, North Atlantic Ocean and South Atlantic Ocean from 2000-10-04 to 2000-12-01 (NODC Accession 0113246)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113246 includes chemical, meteorological, physical and underway - surface data collected from POLARSTERN in the Indian Ocean, North Atlantic Ocean...

  20. Tropical cooling of the ocean surface during the Last Glacial Maximum

    Science.gov (United States)

    Bard, Edouard

    2013-04-01

    Many studies have shown the importance of a correct evaluation of the mean tropical cooling to estimate the relative impact of climate forcings during the LGM, notably the effect of lower concentrations of atmospheric greenhouse gases, and in turn, have applied these results to quantify the so-called equilibrium climate sensitivity (ECS) to a CO2 doubling. Several geochemical paleothermometers have been used to estimate the tropical sea surface temperatures (e.g. SST based on alkenones and magnesium/calcium ratios measured in ocean sediments) that can be compared with model estimates (e.g. Bard 1999 Science for a short discussion). For alkenones, the TEMPUS group (Rosell-Mele et al. 2004 GRL) and MARGO group (Waelbroeck et al. Nat. Geo. 2009) used a linear equation of UK37' vs. SST based on the global core top calibration compiled by Müller et al. (1998 GCA). This calibration is indistinguishable from the original calibration based on Emiliana huxleyi cultures (Prahl et al. 1988 GCA). However, it has also been shown that the warm end of the UK37' calibration is flatter than indicated by a single straight line over the full SST range. For the warm end, this started with our study by Sonzogni et al. (1997 QR) based on low-latitude core tops from the Indian Ocean including samples representing SST between 24 and 30°C. This UK37' versus SST linear equation has a reduced slope (0.023/°C) when compared to that (0.033/°C) derived from the linear equation based on core tops compiled from all oceans (Müller et al. 1998). Support for this complexity also comes from close inspection of the global compilation by Müller et al., suggesting that the relationship flattens out at high temperatures (see also Pelejero & Calvo 2003 G3). In addition, culture studies of different strains of Gephyrocapsa oceanica and E. huxleyi (Conte et al., 1998 GCA) and measurements of sinking particulate matter from Bermuda (Conte et al. 2001 GCA) strongly suggest that the real shape of the UK

  1. Measurements of total dissolved inorganic carbon (DIC), total alkalinity (TA) and pH (on total scale) and other variables collected from surface underway observations using Dissolved Inorganic Carbon Extractor (DICE), Metrohm 876 Dosimat Plus, Agilent 8453 spectrometer and other instruments from R/V Roger Revelle in the Indian Ocean during the transit time on GO-SHIP sections I08S and I09N (EXPOCODEs 33RR20160208 and 33RR20160321) from 2016-02-08 to 2016-03-24 (NCEI Accession 0162262)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Global Ocean Ship-based Hydrographic Investigations Program (GO-SHIP) brings together scientists with interests in physical oceanography, the carbon cycle,...

  2. On the role of sea surface temperature variability over the Tropical Indian Ocean in relation to summer monsoon using satellite data

    Digital Repository Service at National Institute of Oceanography (India)

    RameshKumar, M.R.; Muraleedharan, P.M.; Sathe, P.V.

    The sea surface temperature (SST) variability over the tropical Indian Ocean is studied for the period January 1988 to December 1992 using the multichannel sea surface temperature (MCSST) from the NOAA series of satellites. The MCSST values were...

  3. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, thermosalinographs and other instruments from JAMES CLARK ROSS in the South Atlantic Ocean and Southern Oceans from 2008-01-02 to 2008-02-17 (NCEI Accession 0157284)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157284 includes Surface underway, chemical and physical data collected from JAMES CLARK ROSS in the South Atlantic Ocean and Southern Oceans (> 60...

  4. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, thermosalinographs and other instruments from JAMES CLARK ROSS in the South Atlantic Ocean and Southern Oceans from 2006-10-24 to 2006-12-01 (NCEI Accession 0157244)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157244 includes Surface underway, chemical and physical data collected from JAMES CLARK ROSS in the South Atlantic Ocean and Southern Oceans (> 60...

  5. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, thermosalinographs and other instruments from JAMES CLARK ROSS in the South Atlantic Ocean and Southern Oceans from 2009-03-11 to 2009-04-17 (NCEI Accession 0157275)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157275 includes Surface underway, chemical and physical data collected from JAMES CLARK ROSS in the South Atlantic Ocean and Southern Oceans (> 60...

  6. Partial pressure (or fugacity) of carbon dioxide and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from POLARSTERN in the North Atlantic Ocean, South Atlantic Ocean and others from 2016-02-20 to 2016-05-08 (NCEI Accession 0160572)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0160572 includes Surface underway, chemical and meteorological data collected from POLARSTERN in the North Atlantic Ocean, South Atlantic Ocean, South...

  7. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from TANGAROA in the South Pacific Ocean, Southern Oceans and Tasman Sea from 2015-01-05 to 2015-12-23 (NCEI Accession 0157326)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157326 includes Surface underway, chemical, meteorological and physical data collected from TANGAROA in the South Pacific Ocean, Southern Oceans...

  8. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from surface underway observations using Barometric pressure sensor, Carbon dioxide (CO2) gas analyzer and other instruments from Hakuho Maru in the Indian Ocean and Southern Oceans from 2010-12-17 to 2011-01-17 (NCEI Accession 0163189)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0163189 includes chemical, meteorological, physical and surface underway data collected from Hakuho Maru in the Indian Ocean and Southern Oceans (>...

  9. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer, Shower head chamber equilibrator for autonomous carbon dioxide (CO2) measurement and other instruments from MIRAI in the Indian Ocean, Mozambique Channel and South Atlantic Ocean from 2003-12-09 to 2004-01-24 (NCEI Accession 0144250)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144250 includes Surface underway data collected from MIRAI in the Indian Ocean, Mozambique Channel and South Atlantic Ocean from 2003-12-09 to...

  10. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Barometric pressure sensor, Carbon dioxide (CO2) gas analyzer and other instruments from ROGER REVELLE in the South Pacific Ocean and Southern Oceans from 2005-01-06 to 2005-02-19 (NCEI Accession 0144243)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144243 includes Surface underway data collected from ROGER REVELLE in the South Pacific Ocean and Southern Oceans (> 60 degrees South) from...

  11. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer and other instruments from ROGER REVELLE in the Indian Ocean and Southern Oceans from 2016-02-08 to 2016-03-15 (NCEI Accession 0157333)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157333 includes Surface underway, chemical, meteorological and physical data collected from ROGER REVELLE in the Indian Ocean and Southern Oceans...

  12. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Barometric pressure sensor, Carbon dioxide (CO2) gas analyzer and other instruments from Investigator in the Indian Ocean, South Pacific Ocean and Tasman Sea from 2016-03-14 to 2016-04-15 (NCEI Accession 0157615)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157615 includes Surface underway, chemical, meteorological and physical data collected from Investigator in the Indian Ocean, South Pacific Ocean and...

  13. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from surface underway observations using Barometric pressure sensor, Carbon dioxide (CO2) gas analyzer and other instruments from Investigator in the Indian Ocean, South Pacific Ocean and Tasman Sea from 2015-03-21 to 2015-03-29 (NCEI Accession 0163179)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0163179 includes chemical, meteorological, physical and surface underway data collected from Investigator in the Indian Ocean, South Pacific Ocean and...

  14. Partial pressure (or fugacity) of carbon dioxide, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer and other instruments from POLARSTERN in the Arctic Ocean, North Atlantic Ocean and others from 2007-12-03 to 2008-08-05 (NCEI Accession 0157407)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157407 includes Surface underway, chemical, meteorological and physical data collected from POLARSTERN in the Arctic Ocean, North Atlantic Ocean,...

  15. Partial pressure (or fugacity) of carbon dioxide, temperature, salinity and other variables collected from Surface underway observations using Carbon dioxide (CO2) gas analyzer and other instruments from TANGAROA in the Indian Ocean, South Pacific Ocean and others from 1999-02-02 to 1999-02-28 (NCEI Accession 0155958)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0155958 includes Surface underway, chemical, meteorological and physical data collected from TANGAROA in the Indian Ocean, South Pacific Ocean,...

  16. Correction of Sampling Errors in Ocean Surface Cross-Sectional Estimates from Nadir-Looking Weather Radar

    Science.gov (United States)

    Caylor, I. Jeff; Meneghini, R.; Miller, L. S.; Heymsfield, G. M.

    1997-01-01

    The return from the ocean surface has a number of uses for airborne meteorological radar. The normalized surface cross section has been used for radar system calibration, estimation of surface winds, and in algorithms for estimating the path-integrated attenuation in rain. However, meteorological radars are normally optimized for observation of distributed targets that fill the resolution volume, and so a point target such as the surface can be poorly sampled, particularly at near-nadir look angles. Sampling the nadir surface return at an insufficient rate results in a negative bias of the estimated cross section. This error is found to be as large as 4 dB using observations from a high-altitude airborne radar. An algorithm for mitigating the error is developed that is based upon the shape of the surface echo and uses the returned signal at the three range gates nearest the peak surface echo.

  17. Simulating ocean acidification and CO2 leakages from carbon capture and storage to assess the effects of pH reduction on cladoceran Moina mongolica Daday and its progeny.

    Science.gov (United States)

    Wang, Zaosheng; Wang, Youshao; Yan, Changzhou

    2016-07-01

    In order to evaluate the effects of pH reduction in seawater as a result of increasing levels of atmospheric CO2, laboratory-scale experiments simulating the scenarios of ocean acidification (OA) and CO2 leakages of carbon capture and storage (CCS) were performed using the model organism Moina mongolica Daday. The LpH50s calculated in cladoceran toxicity tests showed that M. mongolica exhibited intermediate sensitivity to OA, which varied among species and with ontogeny, when compared with different phyla or classes of marine biota. Survival, reproduction and fecundity of parthenogenetic females were evaluated after 21-day exposures. Results showed that increased acidity significantly reduced the rate of reproduction of M. mongolica resulting in a decreased intrinsic rate of natural increase (rm) across the gradients of pH reduction. The analysis of macromolecule contents in neonates suggested that nutritional status in progeny from all broods were significantly reduced as seawater pH decreased, with increasing magnitude in latter broods, except the contents of protein from two former broods and lipids from the first brood. Our findings clearly showed that for this ecologically and economically important fish species, the negative effects of pH reduction on both "quantity" and "quality" of progeny may have far-reaching implications, providing direct evidence that OA could influence the energetic transfer of marine food web and ecosystem functions in acidified oceans in the future. Copyright © 2016 Elsevier Ltd. All rights reserved.

  18. NOAA AVHRR Clear-Sky Products over Oceans (ACSPO): Sea Surface Temperature, Clear Sky Radiances, and Aerosol Optical Depth for the Global Ocean, 2011 - present (NCEI Accession 0072979)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The AVHRR Clear-Sky Processor over Oceans, jointly developed between NESDIS STAR and OSDPD, produces AVHRR clear-sky products over oceans. ACSPO generates output...

  19. The OSMOSIS Model of the Wind-Driven Ocean Surface Boundary Layer.

    Science.gov (United States)

    Grant, A. L.; Belcher, S. E.; Pearson, B.; Polton, J.

    2016-02-01

    In the wind-driven ocean surface boundary layer (OSBL) the vertical velocity variance is observed to be larger than in shear driven turbulence. The observed variances are consistent with the results from large-eddy simulations (LES) which parametrize the interaction between the Stokes drift of the surface waves and vorticity. The resulting flow is known as Langmuir turbulence and the close connection between winds and waves suggests that Langmuir turbulence is common in the OSBL. This poster describes a model of the OSBL, developed as part of the OSMOSIS project, in which mixing is by Langmuir turbulence. The transports of momentum, heat and salinity are represented by a first-order closure scheme with flux-gradient relationships that include non-gradient contributions. In this the model is similar to the KPP scheme which uses flux-gradient relationships with non-gradient contributions to represent scalar transports. The flux-gradient relationships are derived from an analysis of the turbulent flux budgets of momentum and scalars (heat) obtained from LES. The non-gradient terms represent the contributions to the turbulent flux by the terms in the turbulent flux budget that represent the effects of the Stokes shear, buoyancy and turbulent transport. The eddy viscosity, diffusivities and non-gradient components are represented by similarity profiles. The depth of the boundary layer is determined by a prognostic equation, which represents the time variation of the boundary layer depth in both unstable and stable conditions. It is based on the equation for the depth integrated potential energy combined with a parametrization of the turbulent kinetic energy budget. The use of the prognostic equation allows the effects of Langmuir turbulence on boundary layer depth to be explicitly represented in the model. Comparison with the results from LES of the diurnal cycle of the OSBL are presented as a test for the model.

  20. The Application of Jason-1 Measurements to Estimate the Global Near Surface Ocean Circulation for Climate Research

    Science.gov (United States)

    Niiler, Peran P.

    2004-01-01

    The scientific objective of this research program was to utilize drifter, Jason-1 altimeter data and a variety of wind data for the determination of time mean and time variable wind driven surface currents of the global ocean. To accomplish this task has required the interpolation of 6-hourly winds on drifter tracks and the computation of the wind coherent motions of the drifters. These calculations showed that the Ekman current model proposed by Ralph and Niiler for the tropical Pacific was valid for all the oceans south of 40N latitude. Improvements to RN99 model were computed and poster presentations of the results were given in several ocean science venues, including the November 2004 GODAY meeting in St. Petersburg, FL.

  1. Ocean Surface Topography Mission (OSTM) /Jason-3 Data Collection, 2015- (NCEI Accession 0118278)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — OSTM/JASON-3 is a follow-on mission continuing the TOPEX/Poseidon and Jason-1/2, and is designed to ensure continuity of high quality measurements for ocean science...

  2. Abrupt sea surface pH change at the end of the Younger Dryas in the central sub-equatorial Pacific inferred from boron isotope abundance in corals (Porites

    Directory of Open Access Journals (Sweden)

    A. Juillet-Leclerc

    2010-08-01

    Full Text Available The "δ11B-pH" technique was applied to modern and ancient corals Porites from the sub-equatorial Pacific areas (Tahiti and Marquesas spanning a time interval from 0 to 20.720 calendar years to determine the amplitude of pH changes between the Last Glacial Period and the Holocene. Boron isotopes were measured by Multi-Collector – Inductively Coupled Plasma Mass Spectrometry (MC-ICPMS with an external reproducibility of 0.25‰, allowing a precision of about ±0.03 pH-units for pH values between 8 and 8.3. The boron concentration [B] and isotopic composition of modern samples indicate that the temperature strongly controls the partition coefficient KD for different aragonite species. Modern coral δ11B values and the reconstructed sea surface pH values for different Pacific areas match the measured pH expressed on the seawater scale and confirm the calculation parameters that were previously determined by laboratory calibration exercises. Most ancient sea surface pH reconstructions near Marquesas are higher than modern values. These values range between 8.19 and 8.27 for the Holocene and reached 8.30 at the end of the last glacial period (20.7 kyr BP. At the end of the Younger Dryas (11.50±0.1 kyr BP, the central sub-equatorial Pacific experienced a dramatic drop of up to 0.2 pH-units from the average pH of 8.2 before and after this short event. Using the marine carbonate algorithms, we recalculated the aqueous pCO2 to be 440±25 ppmV at around 11.5 kyr BP for corals at Marquesas and ~500 ppmV near Tahiti where it was assumed that pCO2 in the atmosphere was 250 ppmV. Throughout the Holocene, the difference in pCO2 between the ocean and the atmosphere at Marquesas (ΔpCO2 indicates that the surface waters behave as a moderate CO2 sink or source (−53 to 20 ppmV during El Niño-like conditions. By contrast, during the last glacial/interglacial transition, this area was a marked source of CO2 (21 to 92 ppmV for the atmosphere, highlighting

  3. The Impact of the Assimilation of Aquarius Sea Surface Salinity Data in the GEOS Ocean Data Assimilation System

    Science.gov (United States)

    Vernieres, Guillaume Rene Jean; Kovach, Robin M.; Keppenne, Christian L.; Akella, Santharam; Brucker, Ludovic; Dinnat, Emmanuel Phillippe

    2014-01-01

    Ocean salinity and temperature differences drive thermohaline circulations. These properties also play a key role in the ocean-atmosphere coupling. With the availability of L-band space-borne observations, it becomes possible to provide global scale sea surface salinity (SSS) distribution. This study analyzes globally the along-track (Level 2) Aquarius SSS retrievals obtained using both passive and active L-band observations. Aquarius alongtrack retrieved SSS are assimilated into the ocean data assimilation component of Version 5 of the Goddard Earth Observing System (GEOS-5) assimilation and forecast model. We present a methodology to correct the large biases and errors apparent in Version 2.0 of the Aquarius SSS retrieval algorithm and map the observed Aquarius SSS retrieval into the ocean models bulk salinity in the topmost layer. The impact of the assimilation of the corrected SSS on the salinity analysis is evaluated by comparisons with insitu salinity observations from Argo. The results show a significant reduction of the global biases and RMS of observations-minus-forecast differences at in-situ locations. The most striking results are found in the tropics and southern latitudes. Our results highlight the complementary role and problems that arise during the assimilation of salinity information from in-situ (Argo) and space-borne surface (SSS) observations

  4. Variability and trends in surface seawater pCO2 and CO2 flux in the Pacific Ocean

    Science.gov (United States)

    Sutton, A. J.; Wanninkhof, R.; Sabine, C. L.; Feely, R. A.; Cronin, M. F.; Weller, R. A.

    2017-06-01

    Variability and change in the ocean sink of anthropogenic carbon dioxide (CO2) have implications for future climate and ocean acidification. Measurements of surface seawater CO2 partial pressure (pCO2) and wind speed from moored platforms are used to calculate high-resolution CO2 flux time series. Here we use the moored CO2 fluxes to examine variability and its drivers over a range of time scales at four locations in the Pacific Ocean. There are significant surface seawater pCO2, salinity, and wind speed trends in the North Pacific subtropical gyre, especially during winter and spring, which reduce CO2 uptake over the 10 year record of this study. Starting in late 2013, elevated seawater pCO2 values driven by warm anomalies cause this region to be a net annual CO2 source for the first time in the observational record, demonstrating how climate forcing can influence the timing of an ocean region shift from CO2 sink to source.

  5. Adhesion of Streptococcus mitis and Actinomyces oris in co-culture to machined and anodized titanium surfaces as affected by atmosphere and pH

    Science.gov (United States)

    2013-01-01

    Background With the rising demand for osseointegrated titanium implants for replacing missing teeth, often in patients with a history of periodontitis, implant-related infections have become an issue of growing concern. Novel methods for treating and preventing implant-associated infections are urgently needed. The aim of this study was to investigate if different pH, atmosphere and surface properties could restrict bacterial adhesion to titanium surfaces used in dental implants. Methods Titanium discs with machined or anodized (TiUnite™) surface were incubated with a co-culture of Streptococcus mitis and Actinomyces oris (early colonizers of oral surfaces) at pH 5.0, 7.0 and 9.0 at aerobic or anaerobic atmosphere. The adhesion was analysed by counting colony forming (CFU) units on agar and by confocal laser scanning microscopy (CLSM). Results The CFU analysis showed that a pH of 5.0 was found to significantly decrease the adhesion of S. mitis, and an aerobic atmosphere, the adhesion of A. oris. S. mitis was found in significantly less amounts on the anodized surface than the machined surface, while A. oris was found in equal amounts on both surfaces. The CLSM analysis confirmed the results from the CFU count and provided additional information on how the two oral commensal species adhered to the surfaces: mainly in dispersed clusters oriented with the groves of the machined surface and the pores of the anodized surface. Conclusions Bacterial adhesion by S. mitis and A. oris can be restricted by acidic pH and aerobic atmosphere. The anodized surface reduced the adhesion of S. mitis compared to the machined surface; while A. oris adhered equally well to the pores of the anodized surface and to the grooves of the machined surface. It is difficult to transfer these results directly into a clinical situation. However, it is worth further investigating these findings from an in vitro perspective, as well as clinically, to gain more knowledge of the effects acid pH and

  6. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from MIRAI in the Indian Ocean, South Pacific Ocean and Southern Oceans from 2012-11-28 to 2013-01-04 (NCEI Accession 0143950)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0143950 includes discrete sample and profile data collected from MIRAI in the Indian Ocean, South Pacific Ocean and Southern Oceans (> 60 degrees...

  7. Iron dissolution from volcanic ash in low-pH atmospheric water: a key control on volcanic iron input to the surface ocean?

    Science.gov (United States)

    Maters, E.; Delmelle, P.; Ayris, P. M.; Opfergelt, S.

    2012-12-01

    A low concentration of dissolved iron (Fe) limits phytoplankton growth in approximately 30% of the ocean. The input of soluble Fe to these High-Nutrient Low-Chlorophyll (HNLC) regions has the potential to boost primary production and thereby enhance the drawdown of atmospheric carbon dioxide (CO2). Over geological timescales, volcanic activity may alter the flux of Fe to the surface ocean and so contribute to modulating atmospheric CO2 concentrations, ultimately impacting the global climate. Ocean Fe fertilisation has also recently been found to contribute to century-scale carbon sequestration via the export of biomass to the seafloor. Atmospherically deposited volcanic ash is now increasingly seen as an intermittent source of Fe to the surface ocean. Understanding the process of Fe release from ash in solution is key for assessing the potential for ash, particularly that produced by large but rare explosive eruptions or during sustained periods of intense volcanism, to fertilise the marine environment. Previous studies have measured the release of Fe from ash in near-neutral pH solution, but the influence of interaction between ash and acidic cloud- or rainwater during transport on Fe release is poorly understood. In this study, seven volcanic ash samples ranging from tephrite to rhyolite (49-74 wt.% SiO2) were leached in pH 1 H2SO4 in batch reactors for 336 h, at a 1:500 ash-to-solution ratio, to investigate Fe release under acidic conditions. Major element concentrations were measured by inductively coupled plasma- atomic emission spectroscopy (ICP-AES) across a time series of ash leachates. Changes in ash surface composition induced by contact with acid solution were assessed by X-ray photoelectron spectroscopy (XPS). The Fe2+/Fe3+ ratio in ash leachates was also determined for the first time, using the Ferrozine method. The ash samples released 42 to 411 μmol m-2 of Fe over 336 h of leaching. High initial Fe release rates (>1 μmol m-2 h-1) sustained for up

  8. Local inertial oscillations in the surface ocean generated by time-varying winds

    Science.gov (United States)

    Chen, Shengli; Polton, Jeff A.; Hu, Jianyu; Xing, Jiuxing

    2015-12-01

    A new relationship is presented to give a review study on the evolution of inertial oscillations in the surface ocean locally generated by time-varying wind stress. The inertial oscillation is expressed as the superposition of a previous oscillation and a newly generated oscillation, which depends upon the time-varying wind stress. This relationship is employed to investigate some idealized wind change events. For a wind series varying temporally with different rates, the induced inertial oscillation is dominated by the wind with the greatest variation. The resonant wind, which rotates anti-cyclonically at the local inertial frequency with time, produces maximal amplitude of inertial oscillations, which grows monotonically. For the wind rotating at non-inertial frequencies, the responses vary periodically, with wind injecting inertial energy when it is in phase with the currents, but removing inertial energy when it is out of phase. The wind rotating anti-cyclonically with time is much more favorable to generate inertial oscillations than the cyclonic rotating wind. The wind with a frequency closer to the inertial frequency generates stronger inertial oscillations. For a diurnal wind, the induced inertial oscillation is dependent on latitude and is most significant at 30 °. This relationship is also applied to examine idealized moving cyclones. The inertial oscillation is much stronger on the right-hand side of the cyclone path than on the left-hand side (in the northern hemisphere). This is due to the wind being anti-cyclonic with time on the right-hand side, but cyclonic on the other side. The inertial oscillation varies with the cyclone translation speed. The optimal translation speed generating the greatest inertial oscillations is 2 m/s at the latitude of 10 ° and gradually increases to 6 m/s at the latitude of 30 °.

  9. Distribution and sources of polycyclic aromatic hydrocarbons in surface sediments from the Bering Sea and western Arctic Ocean.

    Science.gov (United States)

    Zhao, Mengwei; Wang, Weiguo; Liu, Yanguang; Dong, Linsen; Jiao, Liping; Hu, Limin; Fan, Dejiang

    2016-03-15

    To analyze the distribution and sources of polycyclic aromatic hydrocarbons (PAHs) and evaluate their potential ecological risks, the concentrations of 16 PAHs were measured in 43 surface sediment samples from the Bering Sea and western Arctic Ocean. Total PAH (tPAH) concentrations ranged from 36.95 to 150.21 ng/g (dry weight). In descending order, the surface sediment tPAH concentrations were as follows: Canada Basin>northern Chukchi Sea>Chukchi Basin>southern Chukchi Sea>Aleutian Basin>Makarov Basin>Bering Sea shelf. The Bering Sea and western Arctic Ocean mainly received PAHs of pyrogenic origin due to pollution caused by the incomplete combustion of fossil fuels. The concentrations of PAHs in the sediments of the study areas did not exceed effects range low (ERL) values. Copyright © 2016 Elsevier Ltd. All rights reserved.

  10. Detecting the influence of ocean process on the moisture supply for India summer monsoon from Satellite Sea Surface Salinity

    Science.gov (United States)

    Tang, W.; Yueh, S. H.; Liu, W. T.; Fore, A.; Hayashi, A.

    2016-02-01

    A strong contrast in the onset of Indian summer monsoon was observed by independent satellites: average rain rate over India subcontinent (IS) in June was more than doubled in 2013 than 2012 (TRMM); also observed are larger area of wet soil (Aquarius) and high water storage (GRACE). The difference in IS rainfall was contributed to the moisture inputs through west coast of India, estimated from ocean wind (OSCAT2) and water vapor (TMI). This is an interesting testbed for studying the role of ocean on terrestrial water cycle, in particular the Indian monsoon, which has tremendous social-economical impact. What is the source of extra moisture in 2013 or deficit in 2012 for the monsoon onset? Is it possible to quantify the contribution of ocean process that maybe responsible for redistributing the freshwater in favor of the summer monsoon moisture supply? This study aims to identify the influence of ocean processes on the freshwater exchange between air-sea interfaces, using Aquarius sea surface salinity (SSS). We found two areas in Indian Ocean with high correlation between IS rain rate and Aquarius SSS: one area is in the Arabian Sea adjacent to IS, another area is a horizontal patch from 60°E to 100°E centered around 10°S. On the other hand, E-P (OAflux, TRMM) shows no similar correlation patterns with IS rain. Based on the governing equation of the salt budget in the upper ocean, we define the freshwater flux, F, from the oceanic branch of the water cycle, including contributions from salinity tendency, advection, and subsurface process. The tendency and advection terms are estimated using Aquarius SSS and OSCAR ocean current. We will present results of analyzing the spatial and temporal variability of F and evidence of and hypothesis on how the oceanic processes may enhance the moisture supply for summer Indian monsoon onset in 2013 comparing with 2012. The NASA Soil Moisture Active Passive (SMAP) has been producing the global soil moisture (SM) every 2-3 days

  11. Remarkable Impacts of Indian Ocean Sea Surface Temperature on Interdecadal Variability of Summer Rainfall in Southwestern China

    OpenAIRE

    Jingpeng Liu; Hong-Li Ren; Weijing Li; Jinqing Zuo

    2018-01-01

    During the boreal summer from June to August, rainfall in Southwestern China shows substantial interdecadal variabilities on timescales longer than 10 years. Based on observational analyses and numerical modeling, we investigated the characteristics of interdecadal Southwestern China summer rainfall (SWCSR) and its dynamic drivers. We find that the SWCSR is markedly impacted by the interdecadal Indian Ocean basin mode (ID-IOBM) of the sea surface temperature (SST), which may induce anomalous ...

  12. Surface water iron supplies in the Southern Ocean sustained by deep winter mixing

    CSIR Research Space (South Africa)

    Tagliabue, A

    2014-04-01

    Full Text Available Low levels of iron limit primary productivity across much of the Southern Ocean. At the basin scale, most dissolved iron is supplied to surfacewaters from subsurface reservoirs, because land inputs are spatially limited. Deep mixing in winter...

  13. A Smart Climatology of Evaporation Duct Height and Surface Radar Propagation in the Indian Ocean

    National Research Council Canada - National Science Library

    Twigg, Katherine L

    2007-01-01

    .... We have used existing, civilian, dynamically balanced reanalysis data, for 1970 to 2006, and a state-of-the-art ED model, to produce a spatially and temporally refined EDH climatology for the Indian Ocean (10) and nearby seas...

  14. Airborne Measurements of Rain and the Ocean Surface Backscatter Response at C- and Ku-band

    National Research Council Canada - National Science Library

    Fernandez, Daniel E; Chang, Paul S; Carswell, James R; Contreras, Robert F; Frasier, Stephen J

    2005-01-01

    ...) and the Simultaneous Frequency Microwave Radiometer (SFMR). IWRAP is a dual-band (C- and Ku), dual-polarized pencilbeam airborne radar that profiles the volume backscatter and Doppler velocity from rain and that also measures the ocean backscatter response...

  15. Ocean Surface Topography Mission (OSTM) /Jason-2: Auxiliary Files (NODC Accession 0044983)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This accession contains the data descriptions for the OSTM/Jason-2 Auxiliary data files, which is served through the NOAA/NESDIS Comprehensive Large Array-data...

  16. Ocean Surface Topography Mission (OSTM) /Jason-2: Orbital Information (NODC Accession 0044985)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This accession contains the descriptions for the OSTM/Jason-2 orbital information, which is served through the NOAA/NESDIS Comprehensive Large Array-data Stewardship...

  17. NOAA Climate Data Record (CDR) of Ocean Near Surface Atmospheric Properties, Version 1 (Version Superseded)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Please note, this dataset has been superseded by a newer version (see below). Users should not use this version except in rare cases (e.g., when reproducing previous...

  18. Ocean Surface Topography Mission (OSTM) /Jason-2: Ancillary Files (NODC Accession 0044982)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This accession contains the data descriptions for the OSTM/Jason-2 Ancillary data files, which is served through the NOAA/NESDIS Comprehensive Large Array-data...

  19. Ocean Surface Topography Mission (OSTM) /Jason-2: Telemetry (NODC Accession 0044986)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This accession contains the data descriptions for the OSTM/Jason-2 Telemetry data, which is served through the NOAA/NESDIS Comprehensive Large Array-data Stewardship...

  20. Ocean Surface Topography Mission (OSTM) - Jason-2 and Jason-3: Data Documentation Records (NCEI Accession 0118276)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — OSTM/JASON-2 and Jason-3 (scheduled for launch in 2015) are follow-on missions continuing the TOPEX/Poseidon and Jason-1 missions, and are designed to ensure...

  1. Molecular dynamics simulation of the effect of pH on the adsorption of rhodamine laser dyes on TiO2 hydroxylated surfaces

    OpenAIRE

    2009-01-01

    Abstract We have carried out a study of the adsorption, on the (101) surface of anatase TiO2, of two industrially relevant rhodamines molecules (rhodamine 6G and rhodamine 800) employing Molecular Dynamics. These theoretical studies have shown that Rhodamine 6G must adsorb on surfaces under basic conditions. Moreover, the adsorption of this molecule shows a strong dependence upon the pH of the system, i.e. under neutral conditions the adsorption energy is quite smaller, and under ...

  2. Passive buoyant tracers in the ocean surface boundary layer: 2. Observations and simulations of microplastic marine debris

    Science.gov (United States)

    Brunner, K.; Kukulka, T.; Proskurowski, G.; Law, K. L.

    2015-11-01

    This paper is the second of a two-part series that investigates passive buoyant tracers in the ocean surface boundary layer (OSBL). The first part examines the influence of equilibrium wind-waves on vertical tracer distributions, based on large eddy simulations (LESs) of the wave-averaged Navier-Stokes equation. Motivated by observations of buoyant microplastic marine debris (MPMD), this study applies the LES model and the parametric one-dimensional column model from part one to examine the vertical distributions of MPMD. MPMD is widely distributed in vast regions of the subtropical gyres and has emerged as a major open ocean pollutant whose distribution is subject to upper ocean turbulence. The models capture shear-driven turbulence, Langmuir turbulence (LT), and enhanced turbulent kinetic energy input due to breaking waves (BWs). Model results are only consistent with observations of MPMD profiles and the relationship between surface concentrations and wind speed if LT effects are included. Neither BW nor shear-driven turbulence is capable of deeply submerging MPMD, suggesting that the observed vertical MPMD distributions are a characteristic signature of wave-driven LT. Thus, this study demonstrates that LT substantially increases turbulent transport in the OSBL, resulting in deep submergence of buoyant tracers. The parametric model is applied to 11 years of observations in the North Atlantic and North Pacific subtropical gyres to show that surface measurements substantially underestimate MPMD concentrations by a factor of 3-13.

  3. Seasonal surface ocean circulation and dynamics in the Philippine Archipelago region during 2004-2008

    Science.gov (United States)

    Han, Weiqing; Moore, Andrew M.; Levin, Julia; Zhang, Bin; Arango, Hernan G.; Curchitser, Enrique; Di Lorenzo, Emanuele; Gordon, Arnold L.; Lin, Jialin

    2009-06-01

    The dynamics of the seasonal surface circulation in the Philippine Archipelago (117°E-128°E, 0°N-14°N) are investigated using a high-resolution configuration of the Regional Ocean Modeling System (ROMS) for the period of January 2004-March 2008. Three experiments were performed to estimate the relative importance of local, remote and tidal forcing. On the annual mean, the circulation in the Sulu Sea shows inflow from the South China Sea at the Mindoro and Balabac Straits, outflow into the Sulawesi Sea at the Sibutu Passage, and cyclonic circulation in the southern basin. A strong jet with a maximum speed exceeding 100 cm s -1 forms in the northeast Sulu Sea where currents from the Mindoro and Tablas Straits converge. Within the Archipelago, strong westward currents in the Bohol Sea carry the surface water of the western Pacific (WP) from the Surigao Strait into the Sulu Sea via the Dipolog Strait. In the Sibuyan Sea, currents flow westward, which carry the surface water from the WP near the San Bernardino Strait into the Sulu Sea via the Tablas Strait. These surface currents exhibit strong variations or reversals from winter to summer. The cyclonic (anticyclonic) circulation during winter (summer) in the Sulu Sea and seasonally reversing currents within the Archipelago region during the peak of the winter (summer) monsoon result mainly from local wind forcing, while remote forcing dominates the current variations at the Mindoro Strait, western Sulu Sea and Sibutu passage before the monsoons reach their peaks. The temporal variations (with the mean removed), also referred to as anomalies, of volume transports in the upper 40 m at eight major Straits are caused predominantly by remote forcing, although local forcing can be large during sometime of a year. For example, at the Mindoro Strait, the correlation between the time series of transport anomalies due to total forcing (local, remote and tides) and that due only to the remote forcing is 0.81 above 95

  4. Historical temperature, salinity, oxygen, pH, and meteorological data collected from Former Soviet Union platforms Lomonosov, Murmanets, and Akademik Shokalsky in 1933 - 1962 years from Arctic Ocean, Barents Sea, Bering Sea, Chukchi Sea, East Siberian Sea, Kara Sea, and Laptev Sea (NODC Accession 0108117)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Historical temperature, salinity, oxygen, pH, and meteorological data collected from Former Soviet Union platforms Lomonosov,Murmanets, and Akademik Shokalsky in...

  5. Dissolved inorganic carbon, total alkalinity, pH, nutrients and other variables collected from profile and discrete sample observations using CTD, Niskin bottle, and other instruments from NOAA Ship Gordon Gunter off the U.S. East Coast during the East Coast Ocean Acidification (GU-15-04 ECOA1) from 2015-06-20 to 2015-07-23 (NCEI Accession 0159428)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This archival package contains dissolved inorganic carbon, total alkalinity, pH, nutrients and other variables collected from profile and discrete sample...

  6. Surface pH of fresh beef as a parameter to validate effectiveness of lactic acid treatment against E. coli O157:H7 and Salmonella

    Science.gov (United States)

    The beef industry must provide documentation to the regulatory agency that the antimicrobial interventions implemented or any subsequent change in the process is effective under the actual conditions that apply in its operation. The main objective of this study was to determine whether surface pH af...

  7. Impact of Environmental Conditions (pH, Ionic Strength, And Electrolyte Type) On The Surface Charge And Aggregation Of Silver Nanoparticles Suspensions

    Science.gov (United States)

    The impact of capping agents and environmental conditions (pH, ionic strength, and background electrolytes) on surface charge and aggregation potential of silver nanoparticles (AgNPs) suspensions were investigated. Capping agents are chemicals used in the synthesis of nanopartic...

  8. Linking sardine recruitment in coastal areas to ocean currents using surface drifters and HF radar. A case study in the Gulf of Manfredonia, Adriatic Sea

    DEFF Research Database (Denmark)

    Sciascia, Roberta; Berta, Maristella; Carlson, Daniel Frazier

    2017-01-01

    with observations of surface ocean currents to test two hypotheses: 1) ELHS are transported from remote spawning areas (SAs) by ocean cur- rents to the Gulf of Manfredonia; 2) sardines spawn locally and ELHS are retained by eddies. A historical surface drifter database is used to test hypothesis 1. Hypothesis 2......Understanding the role of ocean currents in the recruitment of commercially and ecologically important fish is an important step towards developing sustainable resource management guidelines. To this end, we attempt to elucidate the role of surface ocean transport in supplying recruits of sardine...... is tested by estimating residence times of surface drifters and virtual particles trajectories that were computed from high resolution observations of surface currents measured by a High Frequency (HF) radar network. Transport from remote SAs seems more likely than local spawning and retention given...

  9. Effects of pH and surface metal oxyhydroxides on deposition and transport of carboxyl-functionalized graphene in saturated porous media

    International Nuclear Information System (INIS)

    This work investigated the effects of solution pH and surface metal oxyhydroxides on the transport behaviors of carboxyl-functionalized graphene (GR) in saturated porous media. Column experiments were conducted to elucidate the transport behavior of functionalized GR in acid-cleaned and natural sand under different solution pH conditions (i.e., 5.6 and 8.3). The results showed that the functionalized GR was highly mobile in the acid-cleaned sand columns at both pH 5.6 and 8.3 with recovery rates close to 100 %. The deposition of the functionalized GR was higher in the natural sand columns, and the recovery rates were 88.4 and 96.5 % for pH 5.6 and 8.3, respectively. The reductions of the mobility of the functionalized GR in the natural sand columns could be caused by the interaction between carboxyl functional groups of the GR and the surface metal hydroxides on the sand grains, which is pH dependent. An advection–dispersion-reaction model was applied to the data and successfully simulated the transport of the functionalized GR through the acid-cleaned and natural sand columns

  10. Surface pH and bond strength of a self-etching primer/adhesive system to intracoronal dentin after application of hydrogen peroxide bleach with sodium perborate.

    Science.gov (United States)

    Elkhatib, Hanadi; Nakajima, Masatoshi; Hiraishi, Noriko; Kitasako, Yuichi; Tagami, Junji; Nomura, Satoshi

    2003-01-01

    This study compared the dentin bond strength of a self-etching primer/adhesive system with dentin surface pH with or without bleaching and observed the morphological changes in bleached dentin treated with a self-etching primer. Dentin disks were prepared from the coronal-labial region of 32 human anterior teeth. The pulpal surfaces of the dentin disks were polished with 600-grit SiC paper under running water. The dentin surfaces on all specimens were bleached with a mixture of 30% hydrogen peroxide and sodium perborate in 100% humidity at 37 degrees C for one week. The bleaching agent was then rinsed off with water for 5, 15 or 30 seconds. All specimens were stored in water at 37 degrees C. Half of the five-second rinsing specimens were stored in water for an additional week. Dentin surface pH with or without bleaching was examined using a pH-imaging microscope (SCHEM-100). A self-etching primer/adhesive system (Clearfil SE Bond) was applied to bleached or unbleached dentin according to the manufacturer's instructions. After 24-hour water storage, the bonded specimens were prepared for microtensile testing. Microtensile bond strength (microTBS) to dentin was measured using a universal-testing machine (EZ test, Shimadzu, Japan) at a crosshead speed of 1.0 mm/minute. Data were analyzed by one-way ANOVA and Scheffe's test (alpha=0.05). The pH values of the dentin surfaces of the 5 and 15 second rinsing groups were significantly higher than the control group (ppH values to the control group (ppH value of the dentin surface and decreased the bond strength of the self-etching primer/adhesive system. One-week water storage after bleaching recovered the surface pH and the microTBS to dentin.

  11. Effect of Exposed Surface Area, Volume and Environmental pH on the Calcium Ion Release of Three Commercially Available Tricalcium Silicate Based Dental Cements

    Directory of Open Access Journals (Sweden)

    Sivaprakash Rajasekharan

    2018-01-01

    Full Text Available Tricalcium silicate cements (TSC are used in dental traumatology and endodontics for their bioactivity which is mostly attributed to formation of calcium hydroxide during TSC hydration and its subsequent release of calcium and hydroxide ions. The aim of this study was to determine the effect of volume (Vol, exposed surface area (ESA and pH of surrounding medium on calcium ion release. Three commercially available hydraulic alkaline dental cements were mixed and condensed into cylindrical tubes of varying length and diameter (n = 6/group. For the effect of ESA and Vol, tubes were immersed in 10 mL of deionized water. To analyze the effect of environmental pH, the tubes were randomly immersed in 10 mL of buffer solutions with varying pH (10.4, 7.4 or 4.4. The solutions were collected and renewed at various time intervals. pH and/or calcium ion release was measured using a pH glass electrode and atomic absorption spectrophotometer respectively. The change of pH, short-term calcium ion release and rate at which calcium ion release reaches maximum were dependent on ESA (p < 0.05 while maximum calcium ion release was dependent on Vol of TSC (p < 0.05. Maximum calcium ion release was significantly higher in acidic solution followed by neutral and alkaline solution (p < 0.05.

  12. Effect of Exposed Surface Area, Volume and Environmental pH on the Calcium Ion Release of Three Commercially Available Tricalcium Silicate Based Dental Cements.

    Science.gov (United States)

    Rajasekharan, Sivaprakash; Vercruysse, Chris; Martens, Luc; Verbeeck, Ronald

    2018-01-13

    Tricalcium silicate cements (TSC) are used in dental traumatology and endodontics for their bioactivity which is mostly attributed to formation of calcium hydroxide during TSC hydration and its subsequent release of calcium and hydroxide ions. The aim of this study was to determine the effect of volume (Vol), exposed surface area (ESA) and pH of surrounding medium on calcium ion release. Three commercially available hydraulic alkaline dental cements were mixed and condensed into cylindrical tubes of varying length and diameter ( n = 6/group). For the effect of ESA and Vol, tubes were immersed in 10 mL of deionized water. To analyze the effect of environmental pH, the tubes were randomly immersed in 10 mL of buffer solutions with varying pH (10.4, 7.4 or 4.4). The solutions were collected and renewed at various time intervals. pH and/or calcium ion release was measured using a pH glass electrode and atomic absorption spectrophotometer respectively. The change of pH, short-term calcium ion release and rate at which calcium ion release reaches maximum were dependent on ESA ( p < 0.05) while maximum calcium ion release was dependent on Vol of TSC ( p < 0.05). Maximum calcium ion release was significantly higher in acidic solution followed by neutral and alkaline solution ( p < 0.05).

  13. Vorticity models of ocean surface diffusion in coastal jets and eddies

    Science.gov (United States)

    Cano, D.; Matulka, A.; Sekula, E.

    2010-05-01

    We present and discuss the use of multi-fractal techniques used to investigete vorticity and jet dynamical state of these features detected in the sea surface as well as to identify possible local parametrizations of turbulent diffusion in complex non-homogeneous flows. We use a combined vorticity/energy equation to parametrize mixing at the Rossby Deformation Radius, which may be used even in non Kolmogorov types of flows. The vorticity cascade is seen to be different to the energy cascade and may have important cnsecuences in pollutant dispersion prediction, both in emergency accidental releases and on a day to day operational basis. We also identify different SAR signatures of river plumes near the coast, which are usefull to provide calibrations for the different local configurations that allow to predict the behaviour of different tracers and tensioactives in the coastal sea surface area by means of as a geometrical characterization of the vorticity and velocity maps which induce local mixing and dilution jet processes. The satellite-borne SAR seems to be a good system for the identification of dynamic. lt is also a convenient tool to investigate the eddy structures of a certain area where the effect of bathymetry and local currents are important in describing the ocean surface behavior. Maximum eddy size agrees remarkably well with the limit imposed by the local Rossby deformation radius using the usual thermocline induced stratification, Redondo and Platonov (2000). The Rossby deformation radius, defined as Rd = (N/f)h, where N is the Brunt-Vaisalla frequency, f is the local Coriolis parameter (f=2Osin(lat), where O is the rotation of the earth as function of the latitude), The role of buoyancy may be also detected by seasonal changes in h, the thermocline depth, with these considerations Rd is ranged between 6 and 30 Km. Bezerra M.O., Diez M., Medeiros C. Rodriguez A., Bahia E., Sanchez Arcilla A and Redondo J.M. (1998) "Study on the influence of waves on

  14. The SURFEXv7.2 land and ocean surface platform for coupled or offline simulation of earth surface variables and fluxes

    Science.gov (United States)

    Masson, V.; Le Moigne, P.; Martin, E.; Faroux, S.; Alias, A.; Alkama, R.; Belamari, S.; Barbu, A.; Boone, A.; Bouyssel, F.; Brousseau, P.; Brun, E.; Calvet, J.-C.; Carrer, D.; Decharme, B.; Delire, C.; Donier, S.; Essaouini, K.; Gibelin, A.-L.; Giordani, H.; Habets, F.; Jidane, M.; Kerdraon, G.; Kourzeneva, E.; Lafaysse, M.; Lafont, S.; Lebeaupin Brossier, C.; Lemonsu, A.; Mahfouf, J.-F.; Marguinaud, P.; Mokhtari, M.; Morin, S.; Pigeon, G.; Salgado, R.; Seity, Y.; Taillefer, F.; Tanguy, G.; Tulet, P.; Vincendon, B.; Vionnet, V.; Voldoire, A.

    2013-07-01

    SURFEX is a new externalized land and ocean surface platform that describes the surface fluxes and the evolution of four types of surfaces: nature, town, inland water and ocean. It is mostly based on pre-existing, well-validated scientific models that are continuously improved. The motivation for the building of SURFEX is to use strictly identical scientific models in a high range of applications in order to mutualise the research and development efforts. SURFEX can be run in offline mode (0-D or 2-D runs) or in coupled mode (from mesoscale models to numerical weather prediction and climate models). An assimilation mode is included for numerical weather prediction and monitoring. In addition to momentum, heat and water fluxes, SURFEX is able to simulate fluxes of carbon dioxide, chemical species, continental aerosols, sea salt and snow particles. The main principles of the organisation of the surface are described first. Then, a survey is made of the scientific module (including the coupling strategy). Finally, the main applications of the code are summarised. The validation work undertaken shows that replacing the pre-existing surface models by SURFEX in these applications is usually associated with improved skill, as the numerous scientific developments contained in this community code are used to good advantage.

  15. The SURFEXv7.2 land and ocean surface platform for coupled or offline simulation of earth surface variables and fluxes

    Directory of Open Access Journals (Sweden)

    V. Masson

    2013-07-01

    Full Text Available SURFEX is a new externalized land and ocean surface platform that describes the surface fluxes and the evolution of four types of surfaces: nature, town, inland water and ocean. It is mostly based on pre-existing, well-validated scientific models that are continuously improved. The motivation for the building of SURFEX is to use strictly identical scientific models in a high range of applications in order to mutualise the research and development efforts. SURFEX can be run in offline mode (0-D or 2-D runs or in coupled mode (from mesoscale models to numerical weather prediction and climate models. An assimilation mode is included for numerical weather prediction and monitoring. In addition to momentum, heat and water fluxes, SURFEX is able to simulate fluxes of carbon dioxide, chemical species, continental aerosols, sea salt and snow particles. The main principles of the organisation of the surface are described first. Then, a survey is made of the scientific module (including the coupling strategy. Finally, the main applications of the code are summarised. The validation work undertaken shows that replacing the pre-existing surface models by SURFEX in these applications is usually associated with improved skill, as the numerous scientific developments contained in this community code are used to good advantage.

  16. Polyunsaturated Aldehydes from Large Phytoplankton of the Atlantic Ocean Surface (42°N to 33°S

    Directory of Open Access Journals (Sweden)

    Ana Bartual

    2014-01-01

    Full Text Available Polyunsaturated aldehydes (PUAs are organic compounds mainly produced by diatoms, after cell wounding. These compounds are increasingly reported as teratogenic for species of grazers and deleterious for phytoplanktonic species, but there is still scarce information regarding concentration ranges and the composition of PUAs in the open ocean. In this study, we analyzed the spatial distribution and the type of aldehydes produced by the large-sized (>10 μm phytoplankton in the Atlantic Ocean surface. Analyses were conducted on PUAs released after mechanical disruption of the phytoplankton cells, referred to here as potential PUAs (pPUAs. Results show the ubiquitous presence of pPUA in the open ocean, including upwelling areas, as well as oligotrophic gyres. Total pPUA concentrations ranged from zero to 4.18 pmol from cells in 1 L. Identified PUAs were heptadienal, octadienal and decadienal, with heptadienal being the most common (79% of total stations. PUA amount and composition across the Atlantic Ocean was mainly related to the nitrogen:phosphorus ratio, suggesting nutrient-driven mechanisms of PUA production. Extending the range of trophic conditions considered by adding data reported for productive coastal waters, we found a pattern of PUA variation in relation to trophic status.

  17. Detecting anthropogenic carbon dioxide uptake and ocean acidification in the North Atlantic Ocean

    Directory of Open Access Journals (Sweden)

    N. R. Bates

    2012-07-01

    Full Text Available Fossil fuel use, cement manufacture and land-use changes are the primary sources of anthropogenic carbon dioxide (CO2 to the atmosphere, with the ocean absorbing approximately 30% (Sabine et al., 2004. Ocean uptake and chemical equilibration of anthropogenic CO2 with seawater results in a gradual reduction in seawater pH and saturation states (Ω for calcium carbonate (CaCO3 minerals in a process termed ocean acidification. Assessing the present and future impact of ocean acidification on marine ecosystems requires detection of the multi-decadal rate of change across ocean basins and at ocean time-series sites. Here, we show the longest continuous record of ocean CO2 changes and ocean acidification in the North Atlantic subtropical gyre near Bermuda from 1983–2011. Dissolved inorganic carbon (DIC and partial pressure of CO2 (pCO2 increased in surface seawater by ~40 μmol kg−1 and ~50 μatm (~20%, respectively. Increasing Revelle factor (β values imply that the capacity of North Atlantic surface waters to absorb CO2 has also diminished. As indicators of ocean acidification, seawater pH decreased by ~0.05 (0.0017 yr−1 and ω values by ~7–8%. Such data provide critically needed multi-decadal information for assessing the North Atlantic Ocean CO2 sink and the pH changes that determine marine ecosystem responses to ocean acidification.

  18. Global Ocean Surface Water Partial Pressure of CO2 Database: Measurements Performed During 1957-2016 (LDEO Database Version 2016) (NCEI Accession 0160492)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Approximately 10.8 million measurements of surface water pCO2 made over the global oceans during 1957-2016 have been processed to make a uniform data file in this...

  19. Temporal and spatial characteristics of sea surface height variability in the North Atlantic Ocean

    Directory of Open Access Journals (Sweden)

    D. Cromwell

    2006-01-01

    Full Text Available We investigate the spatial and temporal variability of sea surface height (SSH in the North Atlantic basin using satellite altimeter data from October 1992–January 2004. Our primary aim is to provide a detailed description of such variability, including that associated with propagating signals. We also investigate possible correlations between SSH variability and atmospheric pressure changes as represented by climate indices. We first investigate interannual SSH variations by deriving the complex empirical orthogonal functions (CEOFs of altimeter data lowpass-filtered at 18 months. We determine the spatial structure of the leading four modes (both in amplitude and phase and also the associated principal component (PC time series. Using wavelet analysis we derive the time-varying spectral density of the PCs, revealing when particular modes were strongest between 1992–2004. The spatial pattern of the leading CEOF, comprising 30% of the total variability, displays a 5-year periodicity in phase; signal propagation is particularly marked in the Labrador Sea. The second mode, with a dominant 3-year signal, has strong variability in the eastern basin. Secondly, we focus on the Azores subtropical frontal zone. The leading mode (35% is strong in the south and east of this region with strong variations at 3- and 5-year periods. The second mode (21% has a near-zonal band of low variance between  22°–27° N, sandwiched between two regions of high variance. Thirdly, we lowpass filter the altimeter data at a cutoff of 30 days, instead of 18 months, in order to retain signals associated with propagating baroclinic Rossby waves and/or eddies. The leading mode is the annual steric signal, around 46% of the SSH variability. The third and fourth CEOFs,  11% of the remaining variability, are associated with westward propagation which is particularly dominant in a "waveband" between 32°–36° N. For all three cases considered above, no significant cross

  20. Effect of surface chemistry, solution pH, and ionic strength on the removal of herbicides diuron and amitrole from water by an activated carbon fiber.

    Science.gov (United States)

    Fontecha-Cámara, M A; López-Ramón, M V; Alvarez-Merino, M A; Moreno-Castilla, C

    2007-01-30

    A study was conducted on the effects of carbon surface chemistry, solution pH, and ionic strength on the removal of diuron and amitrole from aqueous solutions by adsorption on an as-received and oxidized activated carbon fiber. Results obtained were explained by the surface characteristics of the adsorbents and the characteristics of the herbicide molecules. Under the experimental conditions used, diuron uptake was much higher than that of amitrole, despite its larger molecular dimensions, due to the lesser water solubility, greater hydrophobicity, and larger dipolar moment of diuron compared with amitrole. Uptake variations associated with differences in carbon surface oxidation, solution pH, and ionic strength were explained by corresponding changes in electrostatic, hydrophobic, and van der Waals interactions.

  1. Characterization of the Fermi surface of BEDT-TTF4[Hg2Cl6].PhCl by electronic band structure calculations

    International Nuclear Information System (INIS)

    Veiros, L.F.; Canadell, E.

    1994-01-01

    Tight-binding band structure calculations for the room temperature structure of BEDT-TTF 4 [Hg 2 Cl 6 ]-PhCl show the existence of closed electron and hole Fermi surfaces, in agreement with the 2D metallic conductivity of this salt. It is shown that these closed Fermi surfaces result from the hybridization of two hidden 1D Fermi surfaces. However, our study also shows that a transition associated with either a usual or a hidden nesting type mechanism is unlikely. This explains why this salt retains its metallic properties without any resistivity anomaly down to 1.3 K. Our study suggests that BEDT-TTF 4 [Hg 2 Cl 6 ]-PhCl is somewhat anisotropic 2D semimetal and should exhibit Shubnikov-de Haas oscillations corresponding to a cross-sectional area of approximately 13% of the first Brillouin zone. (orig.)

  2. Use of weather research and forecasting model outputs to obtain near-surface refractive index structure constant over the ocean.

    Science.gov (United States)

    Qing, Chun; Wu, Xiaoqing; Li, Xuebin; Zhu, Wenyue; Qiao, Chunhong; Rao, Ruizhong; Mei, Haipin

    2016-06-13

    The methods to obtain atmospheric refractive index structure constant (Cn2) by instrument measurement are limited spatially and temporally and they are more difficult and expensive over the ocean. It is useful to forecast Cn2 effectively from Weather Research and Forecasting Model (WRF) outputs. This paper introduces a method that WRF Model is used to forecast the routine meteorological parameters firstly, and then Cn2 is calculated based on these parameters by the Bulk model from the Monin-Obukhov similarity theory (MOST) over the ocean near-surface. The corresponding Cn2 values measured by the micro-thermometer which is placed on the ship are compared with the ones forecasted by WRF model to determine how this method performs. The result shows that the forecasted Cn2 is consistent with the measured Cn2 in trend and the order of magnitude as a whole, as well as the correlation coefficient is up to 77.57%. This method can forecast some essential aspects of Cn2 and almost always captures the correct magnitude of Cn2, which experiences fluctuations of two orders of magnitude. Thus, it seems to be a feasible and meaningful method that using WRF model to forecast near-surface Cn2 value over the ocean.

  3. Trichodesmium blooms and warm-core ocean surface features in the Arabian Sea and the Bay of Bengal.

    Science.gov (United States)

    Jyothibabu, R; Karnan, C; Jagadeesan, L; Arunpandi, N; Pandiarajan, R S; Muraleedharan, K R; Balachandran, K K

    2017-08-15

    Trichodesmium is a bloom-forming, diazotrophic, non-heterocystous cyanobacteria widely distributed in the warmer oceans, and their bloom is considered a 'biological indication' of stratification and nitrogen limitation in the ocean surface layer. In the first part of this paper, based on the retrospective analyses of the ocean surface mesoscale features associated with 59 Trichodesmium bloom incidences recorded in the past, 32 from the Arabian Sea and the Bay of Bengal, and 27 from the rest of the world, we have showed that warm-core features have an inducing effect on bloom formation. In the second part, we have considered the environmental preferences of Trichodesmium bloom based on laboratory and field studies across the globe, and proposed a view about how warm-core features could provide an inducing pre-requisite condition for the bloom formation in the Arabian Sea and the Bay of Bengal. Proposed that the subsurface waters of warm-core features maintain more likely chances for the conducive nutrient and light conditions required for the triggering of the blooms. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. One- to two-month oscillations in SSMI surface wind speed in western tropical Pacific Ocean

    Science.gov (United States)

    Collins, Michael L.; Stanford, John L.; Halpern, David

    1994-01-01

    The 10-m wind speed over the ocean can be estimated from microwave brightness temperature measurements recorded by the Special Sensor Microwave Imager (SSMI) instrument mounted on a polar-orbiting spacecraft. Four-year (1988-1991) time series of average daily 1 deg x 1 deg SSMI wind speeds were analyzed at selected sites in the western tropical Pacific Ocean. One- to two-month period wind speed oscillations with amplitudes statistically significant at the 95% confidence level were observed near Kanton, Eniwetok, Guam, and Truk. This is the first report of such an oscillation in SSMI wind speeds.

  5. Strong relationship between DMS and the solar radiation dose over the global surface ocean.

    Science.gov (United States)

    Vallina, Sergio M; Simó, Rafel

    2007-01-26

    Marine biogenic dimethylsulfide (DMS) is the main natural source of tropospheric sulfur, which may play a key role in cloud formation and albedo over the remote ocean. Through a global data analysis, we found that DMS concentrations are highly positively correlated with the solar radiation dose in the upper mixed layer of the open ocean, irrespective of latitude, plankton biomass, or temperature. This is a necessary condition for the feasibility of a negative feedback in which light-attenuating DMS emissions are in turn driven by the light dose received by the pelagic ecosystem.

  6. New sea surface salinity product in the tropical Indian Ocean estimated from outgoing longwave radiation

    Digital Repository Service at National Institute of Oceanography (India)

    Subrahmanyam, B.; Murty, V.S.N.; O'Brien, J.J.

    .... Teaming Toward the Future September 22-26, 2003 San Diego, California Town and Country -Hotel and Convention Center • • IEEE OCEANS 2003 MTSIIEEE CONFERENCE PROCEEDINGS PUBLISHED BY: OCEANS 2003 MTSIIEEE CONFERENCE COMMITTEE Responsibility for the contents... © 2003 by The Marine Technology Society IEEE Catalog Number: 03CH37492 ISBN: 0-933957-30-0 DVDVersion ISBN: 0-933957-32-7 DVD, CD-ROM Layout and Replication by: HoUand Enterprises Book Layout and Printing by: HoUand Publications 1782 Solana Glen Escondido...

  7. Satellite monitoring of the global ocean surface during 1987-1989

    Science.gov (United States)

    Halpern, David

    1992-01-01

    Long-term simultaneous global coverage of AVHRR sea surface temperature, SSMI surface wind speed, GEOSAT sea surface height, and ARGOS buoy drift began in 1987. Methodology to create annual atlases of monthly mean distributions is described.

  8. Big Jump of Record Warm Global Mean Surface Temperature in 2014-2016 Related to Unusually Large Oceanic Heat Releases

    Science.gov (United States)

    Yin, Jianjun; Overpeck, Jonathan; Peyser, Cheryl; Stouffer, Ronald

    2018-01-01

    A 0.24°C jump of record warm global mean surface temperature (GMST) over the past three consecutive record-breaking years (2014-2016) was highly unusual and largely a consequence of an El Niño that released unusually large amounts of ocean heat from the subsurface layer of the northwestern tropical Pacific. This heat had built up since the 1990s mainly due to greenhouse-gas (GHG) forcing and possible remote oceanic effects. Model simulations and projections suggest that the fundamental cause, and robust predictor of large record-breaking events of GMST in the 21st century, is GHG forcing rather than internal climate variability alone. Such events will increase in frequency, magnitude, and duration, as well as impact, in the future unless GHG forcing is reduced.

  9. MERRA 2D IAU Ocean Surface Diagnostic, Single Level, Time Avg 1-hr (2/3x1/2L1) V5.2.0

    Data.gov (United States)

    National Aeronautics and Space Administration — The MAT1NXOCN or tavg1_2d_ocn_Nx data product is the MERRA Data Assimilation System 2-Dimensional ocean surface single-level diagnostics that is time averaged...

  10. MERRA 2D IAU Ocean Surface Diagnostic, Single Level, Monthly Mean (2/3x1/2L1) V5.2.0

    Data.gov (United States)

    National Aeronautics and Space Administration — The MATMNXOCN or tavgM_2d_ocn_Nx data product is the MERRA Data Assimilation System 2-Dimensional ocean surface single-level diagnostics that is monthly mean...

  11. MERRA 2D IAU Ocean Surface Diagnostic, Single Level, Diurnal (2/3x1/2L1) V5.2.0

    Data.gov (United States)

    National Aeronautics and Space Administration — The MATUNXOCN or tavgU_2d_ocn_Nx data product is the MERRA Data Assimilation System 2-Dimensional ocean surface single-level diagnostics that is monthly mean...

  12. Diagnostic model of 3-D circulation in the Arabian Sea and western equatorial Indian Ocean: Results of monthly mean sea surface topography

    Digital Repository Service at National Institute of Oceanography (India)

    Bahulayan, N.; Shaji, C.

    A three-dimensional diagnostic model has been developed to compute the monthly mean circulation and sea surface topography in the Western Tropical Indian Ocean north of 20 degrees S and west of 80 degrees E. The diagnostic model equations...

  13. Testing the alkenone D/H ratio as a paleo indicator of sea surface salinity in a coastal ocean margin (Mozambique Channel)

    NARCIS (Netherlands)

    Kasper, S.; der Meer, M.T.J.; Castañeda, I.S.; Tjallingii, R.; Brummer, G.J.A.; Sinninghe Damsté, J.S.; Schouten, S.

    2015-01-01

    Reconstructing past ocean salinity is important for assessing paleoceanographic change and therefore past climatic dynamics. Commonly, sea water salinity reconstruction is based on planktonic foraminifera oxygen isotope values combined with sea surface temperature reconstruction. However, the

  14. A Novel Low-cost, Ka-band, High Altitude, Multi-Baseline Unmanned Aerial Vehicle Sensor for Surface Water Ocean Topography, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — This proposal presents the Ka-band SWOT Phenomenology Airborne Radar (KaSPAR) to support the surface water ocean topography (SWOT) mission for science and algorithm...

  15. Surface distribution of dissolved trace metals in the oligotrophic ocean and their influence on phytoplankton biomass and productivity

    KAUST Repository

    Pinedo-González, Paulina

    2015-10-25

    The distribution of bioactive trace metals has the potential to enhance or limit primary productivity and carbon export in some regions of the world ocean. To study these connections, the concentrations of Cd, Co, Cu, Fe, Mo, Ni, and V were determined for 110 surface water samples collected during the Malaspina 2010 Circumnavigation Expedition (MCE). Total dissolved Cd, Co, Cu, Fe, Mo, Ni, and V concentrations averaged 19.0 ± 5.4 pM, 21.4 ± 12 pM, 0.91 ± 0.4 nM, 0.66 ± 0.3 nM, 88.8 ± 12 nM, 1.72 ± 0.4 nM, and 23.4 ± 4.4 nM, respectively, with the lowest values detected in the Central Pacific and increased values at the extremes of all transects near coastal zones. Trace metal concentrations measured in surface waters of the Atlantic Ocean during the MCE were compared to previously published data for the same region. The comparison revealed little temporal changes in the distribution of Cd, Co, Cu, Fe, and Ni over the last 30 years. We utilized a multivariable linear regression model to describe potential relationships between primary productivity and the hydrological, biological, trace nutrient and macronutrient data collected during the MCE. Our statistical analysis shows that primary productivity in the Indian Ocean is best described by chlorophyll a, NO3, Ni, temperature, SiO4, and Cd. In the Atlantic Ocean, primary productivity is correlated with chlorophyll a, NO3, PO4, mixed layer depth, Co, Fe, Cd, Cu, V, and Mo. The variables salinity, temperature, SiO4, NO3, PO4, Fe, Cd, and V were found to best predict primary productivity in the Pacific Ocean. These results suggest that some of the lesser studied trace elements (e.g., Ni, V, Mo, and Cd) may play a more important role in regulating oceanic primary productivity than previously thought and point to the need for future experiments to verify their potential biological functions.

  16. Temperature-dependent remineralization in a warming ocean increases surface pCO2 through changes in marine ecosystem composition

    Science.gov (United States)

    Segschneider, Joachim; Bendtsen, Jørgen

    2014-05-01

    Temperature-dependent remineralization of organic matter is, in general, not included in marine biogeochemistry models currently used for Coupled Model Intercomparison Project Phase 5 (CMIP5) climate projections. Associated feedbacks with climate and the carbon cycle have therefore not been quantified. In this study we aim at investigating how temperature-dependent remineralization rates (Q10 = 2) in a warming ocean impact on the marine carbon cycle, and if this may weaken the oceanic sink for anthropogenic CO2. We perturb an Earth system model used for CMIP5 with temperature-dependent remineralization rates of organic matter using representative concentration pathway (RCP)8.5-derived oceanic temperature anomalies for 2100. The result is a modest change of organic carbon export but more important derived effects associated with feedback processes between changed nutrient concentrations and ecosystem structure. As more nutrients are recycled in the euphotic layer, increased primary production causes a depletion of silicate in the surface layer because opal is exported to depth more efficiently than particulate organic carbon. Shifts in the ecosystem occur as diatoms find less favorable conditions. Export production of calcite shells increases causing a decrease in alkalinity and higher surface pCO2. With regard to future climate projections, the results indicate a reduction of oceanic uptake of anthropogenic CO2 of about 0.2 PgC yr-1 towards the end of the 21st century. This is in addition to reductions caused by already identified climate-carbon cycle feedbacks. Similar shifts in the ecosystem as identified here, but driven by external forcing, have been proposed to drive glacial/interglacial changes in atmospheric pCO2. We propose a similar positive feedback between climate perturbations and the global carbon cycle but driven solely by internal marine biogeochemical processes.

  17. Climate change and ocean deoxygenation within intensified surface-driven upwelling circulations.

    Science.gov (United States)

    Bakun, Andrew

    2017-09-13

    Ocean deoxygenation often takes place in proximity to zones of intense upwelling. Associated concerns about amplified ocean deoxygenation arise from an arguable likelihood that coastal upwelling systems in the world's oceans may further intensify as anthropogenic climate change proceeds. Comparative examples discussed include the uniquely intense seasonal Somali Current upwelling, the massive upwelling that occurs quasi-continuously off Namibia and the recently appearing and now annually recurring 'dead zone' off the US State of Oregon. The evident 'transience' in causal dynamics off Oregon is somewhat mirrored in an interannual-scale intermittence in eruptions of anaerobically formed noxious gases off Namibia. A mechanistic scheme draws the three examples towards a common context in which, in addition to the obvious but politically problematic remedy of actually reducing 'greenhouse' gas emissions, the potentially manageable abundance of strongly swimming, finely gill raker-meshed small pelagic fish emerges as a plausible regulating factor.This article is part of the themed issue 'Ocean ventilation and deoxygenation in a warming world'. © 2017 The Author(s).

  18. Size, surface texture, chemical composition and mineralogy interrelations in ferromanganese nodules of central Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Banakar, V.K.; Pattan, J.N.; Jauhari, P.

    Fiftyseven ferromanganese nodules, classified into 3 size class (4,4-6 and 6-8 cm diam.), from the siliceous sediments of central Indian Ocean were analysed for transition metals and representative sample from each size class for mineralogy. Smaller...

  19. Deep-Sea Bioluminescence Blooms after Dense Water Formation at the Ocean Surface

    NARCIS (Netherlands)

    Tamburini, C.; Canals, M.; de Madron, X.D.; Houpert, L.; Lefevre, D.; Martini, V.; D'Ortenzio, F.; Robert, A.; Testor, P.; Aguilar, J.A.; Al Samarai, I.; Albert, A.; Andre, M.; Anghinolfi, M.; Anton, G.; Anvar, S.; Ardid, M.; Jesus, A.C.A.; Astraatmadja, T.L.; Aubert, J.J.; Baret, B.; Basa, S.; Bertin, V.; Biagi, S.; Bigi, A.; Bigongiari, C.; Bogazzi, C.; Bou-Cabo, M.; Bouhou, B.; Bouwhuis, M.C.; Brunner, J.; Busto, J.; Camarena, F.; Capone, A.; Carloganu, C.; Carminati, G.; Carr, J.; Cecchini, S.; Charif, Z.; Charvis, P.; Chiarusi, T.; Circella, M.; Coniglione, R.; Costantini, H.; Coyle, P.; Curtil, C.; Decowski, P.; Dekeyser, I.; Deschamps, A.; Donzaud, C.; Dornic, D.; Dorosti, H.Q.; Drouhin, D.; Eberl, T.; Emanuele, U.; Ernenwein, J.P.; Escoffier, S.; Fermani, P.; Ferri, M.; Flaminio, V.; Folger, F.; Fritsch, U.; Fuda, J.L.; Galata, S.; Gay, P.; Giacomelli, G.; Giordano, V.; Gomez-Gonzalez, J.P.; Graf, K.; Guillard, G.; Halladjian, G.; Hallewell, G.; van Haren, H.; Hartman, J.; Heijboer, A.J.; Hello, Y.; Hernandez-Rey, J.J.; Herold, B.; Hossl, J.; Hsu, C.C.; De Jong, M.; Kadler, M.; Kalekin, O.; Kappes, A.; Katz, U.; Kavatsyuk, O.; Kooijman, P.; Kopper, C.; Kouchner, A.; Kreykenbohm, I.; Kulikovskiy, V.; Lahmann, R.; Lamare, P.; Larosa, G.; Lattuada, D.; Lim, G.; Lo Presti, D.; Loehner, H.; Loucatos, S.; Mangano, S.; Marcelin, M.; Margiotta, A.; Martinez-Mora, J.A.; Meli, A.; Montaruli, T.; Moscoso, L.; Motz, H.; Neff, M.; Nezri, E.N.; Palioselitis, D.; Pavalas, G.E.; Payet, K.; Payre, P.; Petrovic, J.; Piattelli, P.; Picot-Clemente, N.; Popa, V.; Pradier, T.; Presani, E.; Racca, C.; Reed, C.; Riccobene, G.; Richardt, C.; Richter, R.; Riviere, C.; Roensch, K.; Rostovtsev, A.; Ruiz-Rivas, J.; Rujoiu, M.; Russo, V.G.; Salesa, F.; Sanchez-Losa, A.; Sapienza, P.; Schock, F.; Schuller, J.P.; Schussler, F.; Shanidze, R.; Simeone, F.; Spies, A.; Spurio, M.; Steijger, J.J.M.; Stolarczyk, T.; Taiuti, M.G.F.; Toscano, S.; Vallage, B.; Van Elewyck, V.; Vannoni, G.; Vecchi, M.; Vernin, P.; Wijnker, G.; Wilms, J.; de Wolf, E.; Yepes, H.; Zaborov, D.; Zornoza, J.D.; Zuniga, J.

    2013-01-01

    The deep ocean is the largest and least known ecosystem on Earth. It hosts numerous pelagic organisms, most of which are able to emit light. Here we present a unique data set consisting of a 2.5-year long record of light emission by deep-sea pelagic organisms, measured from December 2007 to June

  20. Climate change and ocean deoxygenation within intensified surface-driven upwelling circulations

    Science.gov (United States)

    Bakun, Andrew

    2017-08-01

    Ocean deoxygenation often takes place in proximity to zones of intense upwelling. Associated concerns about amplified ocean deoxygenation arise from an arguable likelihood that coastal upwelling systems in the world's oceans may further intensify as anthropogenic climate change proceeds. Comparative examples discussed include the uniquely intense seasonal Somali Current upwelling, the massive upwelling that occurs quasi-continuously off Namibia and the recently appearing and now annually recurring `dead zone' off the US State of Oregon. The evident `transience' in causal dynamics off Oregon is somewhat mirrored in an interannual-scale intermittence in eruptions of anaerobically formed noxious gases off Namibia. A mechanistic scheme draws the three examples towards a common context in which, in addition to the obvious but politically problematic remedy of actually reducing `greenhouse' gas emissions, the potentially manageable abundance of strongly swimming, finely gill raker-meshed small pelagic fish emerges as a plausible regulating factor. This article is part of the themed issue 'Ocean ventilation and deoxygenation in a warming world'.

  1. Guest editor - Material exchanges at marine boundaries and surface ocean processes: Forcings and feedbacks

    Digital Repository Service at National Institute of Oceanography (India)

    DileepKumar, M.

    the equatorial Indian Ocean. I thank all the authors for contributing to Ses- sion OA-18 of the AOGS 2005 meeting and to this Special section. I am grateful to the review- ers (Drs. Hermann W Bange of Forschungs- bereich Marine Biogeochemie, Kiel, Germany...

  2. Oceanic sources of continental precipitation and the correlation with sea surface temperature

    NARCIS (Netherlands)

    Van der Ent, R.J.; Savenije, H.H.G.

    2013-01-01

    Identifying the sources of continental precipitation has received increasing attention in recent years. With the use of various numerical methods, sources of precipitation have been identified from local to global scales. In this paper we identify the oceanic sources based on an atmospheric

  3. Surface and subsurface geostrophic current variability in the Indian Ocean from altimetry

    Digital Repository Service at National Institute of Oceanography (India)

    Cadden, D.D; Subrahmanyam, B; Chambers, D; Murty, V.S.N.

    the World Ocean Atlas 2005. The results of this method were validated with currents measured using Acoustic Doppler Current Profilers moored along the equator at 77 degrees E, 83 degrees E, and 93 degrees E. The measured and computed currents compared...

  4. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from NATHANIEL B. PALMER in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2011-02-19 to 2011-04-23 (NODC Accession 0109933)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0109933 includes discrete sample and profile data collected from NATHANIEL B. PALMER in the South Atlantic Ocean, South Pacific Ocean and Southern...

  5. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from NOAA Ship RONALD H. BROWN in the North Pacific Ocean, South Pacific Ocean and Southern Oceans from 2007-12-15 to 2008-02-23 (NODC Accession 0109903)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0109903 includes discrete sample and profile data collected from NOAA Ship RONALD H. BROWN in the North Pacific Ocean, South Pacific Ocean and...

  6. PH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from JAMES CLARK ROSS in the South Atlantic Ocean, South Pacific Ocean and Southern Oceans from 2015-12-17 to 2016-01-13 (NCEI Accession 0157011)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157011 includes chemical, discrete sample, physical and profile data collected from JAMES CLARK ROSS in the South Atlantic Ocean, South Pacific Ocean...

  7. The influence of small-scale sea surface temperature gradients on surface vector winds and subsequent impacts on oceanic Ekman pumping

    Science.gov (United States)

    Hughes, Paul J.

    Satellite observations have revealed a small-scale (air--sea coupling in regions of strong sea surface temperature (SST) gradients (e.g., fronts, currents, eddies, and tropical instability waves), where the surface wind and wind stress are modified. Surface winds and wind stresses are persistently higher over the warm side of the SST front compared to the cool side, causing perturbations in the dynamically and thermodynamically curl and divergence fields. Capturing this small-scale SST--wind variability is important because it can significantly impact both local and remote (i.e., large scale) oceanic and atmospheric processes. The SST--wind relationship is not well represented in numerical weather prediction (NWP) and climate models, and the relative importance of the physical processes that are proposed to be responsible for this relationship is actively and vehemently debated. This study focuses on the physical mechanisms that are primarily responsible for the SST-induced changes in surface wind and wind stress, and on the physical implication on ocean forcing through Ekman pumping. The roles that SST-induced atmospheric baroclinicity and boundary-layer stability play in modifying the surface vector wind in regions of strong SST gradients are examined with an idealized model. Modeled changes in surface wind speed due to changes in atmospheric boundary-layer stability and baroclinicity are largely between -2.0 and 2.0 m s-1, which is consistent with past observational findings. The baroclinic-related changes in the surface vector wind are found to have a largely linear dependence on the SST gradient, whereas the stability-related changes are highly non-linear. The linearity of the baroclinic impacts matches that of the observed (satellite and in situ) SST--wind relationship. This result suggests that the baroclinic-related mechanism is the leading factor in driving the observed surface wind response to strong open ocean SST fronts on scales greater than 25 km

  8. Monitoring the near-surface pH to probe the role of nitrogen in corrosion behaviour of low-temperature plasma nitrided 316L stainless steel

    International Nuclear Information System (INIS)

    Flis-Kabulska, I.; Sun, Y.; Flis, J.

    2013-01-01

    Highlights: • Nitrided steel is pitting resistant but in acidic solution anodic current is high. • Sb electrode showed a rise of pH at nitrided surface during anodic dissolution. • In cathodic sweeps nitrided steel showed reactivation indicating poor passivity. • Improvement of passivity after injection of NH 4 OH is ascribed to oxides and NO 2 − . • Pitting resistance is ascribed to oxides and NO 2 − following the formation of NH 4 + . -- Abstract: Low temperature plasma nitriding of stainless steels improves tribological properties and pitting resistance, but it can activate anodic dissolution in acidic solutions. This work aimed at determining how anodic behaviour can be affected by nitrogen present in the steel. The electrochemical behaviour of AISI 316L steel after nitriding at 415 °C (with up to 17 at.% N) was examined in solutions of 0.1 M Na 2 SO 4 + 0.4 M NaCl acidified down to pH 2.4. An antimony microelectrode was used to measure pH close to the sample surface. It was found that the nitrided layer was resistant to pitting corrosion at all pH's, but at pH below about 3.5 anodic currents were higher than those on untreated steel. For nitrided steel the near-surface pH was increasing when anodic current was rising in the active region, evidently due to binding of protons into NH 4 + . Nitrided steel underwent reactivation during reverse cathodic sweeps which is characteristic of low content of chromium oxide in surface film. Injection of NH 4 OH into the solution improved the passivation. Thermodynamic data indicated that the accompanying pH rise enabled the formation of Fe 3 O 4 , Fe 2 O 3 , Cr 2 O 3 , FeCr 2 O 4 , NiFe 2 O 4 , MoO 4 2− and NO 2 − . It is suggested that the pitting resistance of nitrided steel results from an easy repassivation of incipient pits due to the formation of the above species

  9. Calcium Hypochlorite Solutions: Evaluation of Surface Tension and Effect of Different Storage Conditions and Time Periods over pH and Available Chlorine Content.

    Science.gov (United States)

    Leonardo, Natália Gomes e Silva; Carlotto, Israel Bangel; Luisi, Simone Bonato; Kopper, Patrícia Maria Poli; Grecca, Fabiana Soares; Montagner, Francisco

    2016-04-01

    The aim of this study was to evaluate the pH and the available chlorine content from sodium hypochlorite (NaOCl) and calcium hypochlorite (Ca[OCl]2) solutions stored in different conditions and time periods and the surface tension of Ca(OCl)2 solutions in comparison with NaOCl. Solutions at 0.5%, 1%, 2.5%, and 5.25% concentrations were prepared. The pH level and the available chlorine content of freshly prepared solutions and solutions stored for 30, 60, and 90 days at 25°C, 4°C, or 37°C were evaluated in a digital pH meter and by titration, respectively. Surface tension was tested using a Du Nouy tensiometer (Sigma 702, Force Tensiometer; Attension, Espoo, Finland). Descriptive and inferential statistical analyses were performed. A precipitate formed by 2.5% and 5.25% Ca(OCl)2 solutions was observed. Ca(OCl)2 showed a higher concentration of available chlorine than NaOCl. Both 2.5% and 5.25% NaOCl and Ca(OCl)2 had a decrease in the available chlorine content when compared with freshly prepared solutions; 0.5% and 1% NaOCl tend to have a lower pH compared with 0.5% and 1% Ca(OCl)2. NaOCl, 5.25%, showed higher pH compared with 5.25% Ca(OCl)2. NaOCl and Ca(OCl)2 in 0.5% and 1% concentrations tend to show a reduced pH level, whereas 2.5% and 5.25% solutions showed an increase in pH. The heat contributed to the instability of the solutions. NaOCl showed lower surface tension values than Ca(OCl)2. Ca(OCl)2 solutions are extremely alkaline and tend to have more available chlorine content than NaOCl but have a higher surface tension than NaOCl. Regarding the available chlorine content, these solutions tend to be stable to 30 days of storage when kept at 4°C or at 25°C. Copyright © 2016 American Association of Endodontists. Published by Elsevier Inc. All rights reserved.

  10. The geological record of ocean acidification

    Science.gov (United States)

    Hoenisch, B.; Ridgwell, A. J.; Thomas, E.; Zachos, J. C.; Gibbs, S. J.

    2011-12-01

    Marine sediments contain information on a variety of past climate and carbon cycle perturbation events that may provide insights into the consequences of ongoing ocean acidification and potential future biotic changes. A variety of candidate events have been proposed, for which we assess the evidence for elevated CO2, global warming, and seawater carbonate chemistry changes, as well as having been primarily driven by massive carbon release. However, in order to be able to draw valid parallels with anthropogenic ocean acidification, we must distinguish between long-term changes and quasi steady states of marine carbon cycling, and transient changes, as only events shorter than ~10,000 years will exhibit the coupled reductions in ocean pH and carbonate saturation state that characterize today's (and the future) ocean. Quantifying the magnitude and rate of carbon cycle perturbations is therefore key to identifying and interpreting past intervals of ocean acidification. However, much evidence for paleocean acidification has been inferred from biotic changes, which could alternatively have been caused by other environmental changes such as changes in temperature, nutrient supply and oxygenation. Independent geochemical proxy evidence for paleo-seawater pH and carbonate saturation is therefore critical to confirm that ocean acidification did indeed take place. As a case study, we focus on the Paleocene/Eocene Thermal Maximum (56 Ma), an extreme climate event that displays close similarities with worst-case scenarios for the future, in terms of massive carbon release (~4,500 Pg C), associated warming (5-9°C), and its worldwide extent. We have applied the boron isotope/paleo-pH proxy to quantify the extent of ocean acidification associated with this event, and find a consistent pH decrease in the surface and deep ocean over the extent of the carbon isotope excursion, both in the Atlantic and Pacific Ocean basins, confirming that ocean acidification did take place.

  11. The influence of surface modification, coating agents and pH value of aqueous solutions on physical properties of magnetite nanoparticles investigated by ESR method

    Energy Technology Data Exchange (ETDEWEB)

    Dobosz, Bernadeta, E-mail: benia@amu.edu.pl [Medical Physics Division, Faculty of Physics, Adam Mickiewicz University, Umultowska 85, 61-614 Poznań (Poland); Krzyminiewski, Ryszard [Medical Physics Division, Faculty of Physics, Adam Mickiewicz University, Umultowska 85, 61-614 Poznań (Poland); Kurczewska, Joanna; Schroeder, Grzegorz [Faculty of Chemistry, Adam Mickiewicz University, Umultowska 89B, 61-614 Poznań (Poland)

    2017-05-01

    The article presents the results of electron spin resonance (ESR) studies for aqueous solutions of functionalized superparamagnetic iron(II,III) oxide nanoparticles. The samples studied differed in type of organic ligands at the magnetite surface, type of coating agent and pH value of aqueous solutions. The ESR spectra of the samples were obtained at room temperature and at 230 K. The field cooling (FC) experiment was performed for selected samples, and the effective anisotropy field (H{sub K2}) and the first order magnetocrystalline anisotropy constant (K{sub 1}) was calculated. The process of the nanoparticles diffusion in different environments (human blood, human serum) forced by an inhomogeneous magnetic field was monitored and their interactions with different solvents have been discussed. It has been shown that ESR method is useful to observe the impact of organic ligands at the magnetite surface, type of coating agent and pH value of aqueous solutions on the properties of iron(II,III) oxide nanoparticles. - Highlights: • The influence of different organic ligands, coatings and pH values of aqueous solutions on the physical properties of the magnetite nanoparticles studied by ESR method. • Nanoparticles diffusion forced by inhomogeneous magnetic field monitored by ESR and explained. • A narrow line separated in ESR spectra by CREM. • The influence of different coatings and pH values of aqueous solutions on ESR spectra of TEMPO attached to the magnetite core.

  12. Effect of pH and pulsed electric field process parameters on the aflatoxin reduction in model system using response surface methodology: Effect of pH and PEF on Aflatoxin Reduction.

    Science.gov (United States)

    Vijayalakshmi, Subramanian; Nadanasabhapathi, Shanmugam; Kumar, Ranganathan; Sunny Kumar, S

    2018-03-01

    The presence of aflatoxin, a carcinogenic and toxigenic secondary metabolite produced by Aspergillus species, in food matrix has been a major worldwide problem for years now. Food processing methods such as roasting, extrusion, etc. have been employed for effective destruction of aflatoxins, which are known for their thermo-stable nature. The high temperature treatment, adversely affects the nutritive and other quality attributes of the food, leading to the necessity of application of non-thermal processing techniques such as ultrasonication, gamma irradiation, high pressure processing, pulsed electric field (PEF), etc. The present study was focused on analysing the efficacy of the PEF process in the reduction of the toxin content, which was subsequently quantified using HPLC. The process parameters of different pH model system (potato dextrose agar) artificially spiked with aflatoxin mix standard was optimized using the response surface methodology. The optimization of PEF process effects on the responses aflatoxin B1 and total aflatoxin reduction (%) by pH (4-10), pulse width (10-26 µs) and output voltage (20-65%), fitted 2FI model and quadratic model respectively. The response surface plots obtained for the processes were of saddle point type, with the absence of minimum or maximum response at the centre point. The implemented numerical optimization showed that the predicted and actual values were similar, proving the adequacy of the fitted models and also proved the possible application of PEF in toxin reduction.

  13. Using coral Ba/Ca records to investigate seasonal to decadal scale biogeochemical cycling in the surface and intermediate ocean.

    Science.gov (United States)

    LaVigne, M.; Cobb, K. M.; DeLong, K. L.; Freiberger, M. M.; Grottoli, A. G.; Hill, T. M.; Miller, H. R.; Nurhati, I. S.; Richey, J. N.; Serrato Marks, G.; Sherrell, R. M.

    2016-12-01

    Dissolved barium (BaSW), a bio-intermediate element, is linked to several biogeochemical processes such as the cycling and export of nutrients, organic carbon (Corg), and barite in surface and intermediate oceans. Dynamic BaSW cycling has been demonstrated in the water column on short timescales (days-weeks) while sedimentary records have documented geologic-scale changes in barite preservation driven by export production. Our understanding of how seasonal-decadal scale climate variability impacts these biogeochemical processes currently lacks robust records. Ba/Ca calibrations in surface and deep sea corals suggest barium is incorporated via cationic substitution in both aragonite and calcite. Here we demonstrate the utility of Ba/Ca for reconstructing biogeochemical variability using examples of surface and deep sea coral records. Century-long deep sea coral records from the California Current System (bamboo corals: 900-1500m) record interannual variations in Ba/Ca, likely reflecting changes in barite formation via bacterial Corg respiration or barite saturation state. A surface Porites coral Ba/Ca record from Christmas Island (central equatorial Pacific: 1978-1995) shows maxima during low productivity El Niño warm periods, suggesting that variations in BaSW are driven by biological removal via direct cellular uptake or indirectly via barite precipitation with the decomposition of large phytoplankton blooms at this location. Similarly, a sixteen-year long Siderastera siderea surface coral record from Dry Tortugas, FL (Gulf of Mexico: 1991-2007) shows seasonal Ba/Ca cycles that align with annual chlorophyll and δ13C. Taken together, these records demonstrate the linkages among Corg, nutrient cycling and BaSW in the surface and intermediate ocean on seasonal to decadal timescales. Multi-proxy paleoceanographic reconstructions including Ba/Ca have the potential to elucidate the mechanisms linking past climate, productivity, nutrients, and BaSW cycling in the past.

  14. Cloud Properties Observed From the Surface and by Satellite at the Northern Edge of the Southern Ocean

    Science.gov (United States)

    Alexander, S. P.; Protat, A.

    2018-01-01

    A Raman depolarization lidar was deployed at Cape Grim, Australia (40.7°S, 144.7°E), at the northern edge of the Southern Ocean from July 2013 to February 2014 from which we determine cloud boundaries, cloud phase, ice virga, and cloud effective top heights. We compare surface-based lidar with results from the raDAR/liDAR (DARDAR) data set within 1,000 km of Cape Grim. DARDAR combines information from the CloudSat and Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) instruments. We extract single-layer clouds that are sufficiently thin for signal to be present on the farside of the cloud and which have a liquid cloud top phase. These conditions maximize the likelihood that both surface-based lidar and DARDAR are observing the full vertical extent of the same clouds. Differences in low-level cloud occurrence frequencies for these single-layer clouds reveal that DARDAR underestimates cloud at 0.2-1.0 km altitude by a factor of 3 compared with the surface-based lidar. When multiple cloud decks are present, the underestimate in this altitude region is around 2.5 times. Heterogeneous glaciation observed by the Cape Grim lidar in midlevel stratiform supercooled water clouds is similar to that reported by previous surface-based observations adjacent to the Southern Ocean, with half of these clouds precipitating ice at cloud top temperatures of -20°C. This transition occurs around -15°C in the DARDAR data set, and this difference is likely due to the reduced sensitivity of surface-based lidar in detecting precipitating ice compared with what a surface-based radar could observe.

  15. Biotic Control of Surface pH and Evidence of Light-Induced H+ Pumping and Ca2+-H+ Exchange in a Tropical Crustose Coralline Alga.

    Directory of Open Access Journals (Sweden)

    Laurie C Hofmann

    Full Text Available Presently, an incomplete mechanistic understanding of tropical reef macroalgae photosynthesis and calcification restricts predictions of how these important autotrophs will respond to global change. Therefore, we investigated the mechanistic link between inorganic carbon uptake pathways, photosynthesis and calcification in a tropical crustose coralline alga (CCA using microsensors. We measured pH, oxygen (O2, and calcium (Ca2+ dynamics and fluxes at the thallus surface under ambient (8.1 and low (7.8 seawater pH (pHSW and across a range of irradiances. Acetazolamide (AZ was used to inhibit extracellular carbonic anhydrase (CAext, which mediates hydrolysis of HCO3-, and 4,4' diisothiocyanatostilbene-2,2'-disulphonate (DIDS that blocks direct HCO3- uptake by anion exchange transport. Both inhibited photosynthesis, suggesting both diffusive uptake of CO2 via HCO3- hydrolysis to CO2 and direct HCO3- ion transport are important in this CCA. Surface pH was raised approximately 0.3 units at saturating irradiance, but less when CAext was inhibited. Surface pH was lower at pHSW 7.8 than pHSW 8.1 in the dark, but not in the light. The Ca2+ fluxes were large, complex and temporally variable, but revealed net Ca2+ uptake under all conditions. The temporal variability in Ca2+ dynamics was potentially related to localized dissolution during epithallial cell sloughing, a strategy of CCA to remove epiphytes. Simultaneous Ca2+ and pH dynamics suggest the presence of Ca2+/H+ exchange. Rapid light-induced H+ surface dynamics that continued after inhibition of photosynthesis revealed the presence of a light-mediated, but photosynthesis-independent, proton pump. Thus, the study indicates metabolic control of surface pH can occur in CCA through photosynthesis and light-inducible H+ pumps. Our results suggest that complex light-induced ion pumps play an important role in biological processes related to inorganic carbon uptake and calcification in CCA.

  16. Relationship Between the Clouds and the Earth's Radiant Energy System (CERES) Measurements and Surface Temperatures of Selected Ocean Regions

    Science.gov (United States)

    Pandey, Dhirendra, K.; Lee, Robert B., III; Brown, Shannon B.; Paden, Jack; Spence, Peter L.; Thomas, Susan; Wilson, Robert S.; Al-Hajjah, Aiman

    2001-01-01

    Clear sky longwave radiances and fluxes are compared with the sea surface temperatures for three oceanic regions: Atlantic, Indian, and Pacific. The Clouds and the Earth's Radiant Energy System (CERES) measurements were obtained by the three thermistor bolometers: total channel which measures the radiation arising from the earth-atmosphere system between 0.3 - greater than 100 micrometers; the window channel which measures the radiation from 8-12 micrometers; and the shortwave channel which measures the reflected energy from 0.3 - less than 5.0 micrometers. These instruments have demonstrated measurement precisions of approximately 0.3% on the International Temperature Scale of 1990 (ITS-90) between ground and on-orbit sensor calibrations. In this work we have used eight months of clear sky earth-nadir-view radiance data starting from January 1998 through August 1998. We have found a very strong correlation of 0.97 between the CERES window channel's weekly averaged unfiltered spectral radiance values at satellite altitude (350 km) and the corresponding weekly averaged sea surface temperature (SST) data covering all the oceanic regions. Such correlation can be used in predicting the sea surface temperatures using the present CERES Terra's window channel radiances at satellite altitude very easily.

  17. Ocean acidification impacts bacteria – phytoplankton coupling at low-nutrient conditions

    NARCIS (Netherlands)

    Hornick, T.; Bach, L.T.; Crawfurd, K.J.; Spilling, K.; Achterberg, E.P.; Woodhouse, J.N.; Schulz, K.G.; Brussaard, C.P.D.; Riebesell, U.; Grossart, H.-P.

    2017-01-01

    The oceans absorb about a quarter of the annuallyproduced anthropogenic atmospheric carbon dioxide(CO2/, resulting in a decrease in surface water pH, aprocess termed ocean acidification (OA). Surprisingly littleis known about how OA affects the physiology of heterotrophicbacteria or the coupling of

  18. The impact of a seasonally ice free Arctic Ocean on the temperature, precipitation and surface mass balance of Svalbard

    Directory of Open Access Journals (Sweden)

    J. J. Day

    2012-01-01

    Full Text Available The observed decline in summer sea ice extent since the 1970s is predicted to continue until the Arctic Ocean is seasonally ice free during the 21st Century. This will lead to a much perturbed Arctic climate with large changes in ocean surface energy flux. Svalbard, located on the present day sea ice edge, contains many low lying ice caps and glaciers and is expected to experience rapid warming over the 21st Century. The total sea level rise if all the land ice on Svalbard were to melt completely is 0.02 m.

    The purpose of this study is to quantify the impact of climate change on Svalbard's surface mass balance (SMB and to determine, in particular, what proportion of the projected changes in precipitation and SMB are a result of changes to the Arctic sea ice cover. To investigate this a regional climate model was forced with monthly mean climatologies of sea surface temperature (SST and sea ice concentration for the periods 1961–1990 and 2061–2090 under two emission scenarios. In a novel forcing experiment, 20th Century SSTs and 21st Century sea ice were used to force one simulation to investigate the role of sea ice forcing. This experiment results in a 3.5 m water equivalent increase in Svalbard's SMB compared to the present day. This is because over 50 % of the projected increase in winter precipitation over Svalbard under the A1B emissions scenario is due to an increase in lower atmosphere moisture content associated with evaporation from the ice free ocean. These results indicate that increases in precipitation due to sea ice decline may act to moderate mass loss from Svalbard's glaciers due to future Arctic warming.

  19. Recent summer precipitation trends in the Greater Horn of Africa and the emerging role of Indian Ocean sea surface temperature

    Energy Technology Data Exchange (ETDEWEB)

    Williams, A.P. [Los Alamos National Laboratory, Earth and Environmental Sciences Division, Los Alamos, NM (United States); University of California, Geography Department, Santa Barbara, CA (United States); Funk, Chris [University of California, Geography Department, Santa Barbara, CA (United States); U.S. Geological Survey, Earth Resources Observation and Science (EROS), Sioux Falls, SD (United States); Michaelsen, Joel [University of California, Geography Department, Santa Barbara, CA (United States); Rauscher, Sara A. [Los Alamos National Laboratory, Theoretical Division, Los Alamos, NM (United States); Robertson, Iain; Loader, Neil J. [Swansea University, Department of Geography, College of Science, Swansea (United Kingdom); Wils, Tommy H.G. [Rotterdam University, Department of Geography, Rotterdam (Netherlands); Koprowski, Marcin [Nicolaus Copernicus University, Laboratory of Dendrochronology, Institute of Ecology and Environment Protection, Torun (Poland); Eshetu, Zewdu [Ethiopian Institute of Agricultural Research, Forestry Research Centre, Addis Ababa (Ethiopia)

    2012-11-15

    We utilize a variety of climate datasets to examine impacts of two mechanisms on precipitation in the Greater Horn of Africa (GHA) during northern-hemisphere summer. First, surface-pressure gradients draw moist air toward the GHA from the tropical Atlantic Ocean and Congo Basin. Variability of the strength of these gradients strongly influences GHA precipitation totals and accounts for important phenomena such as the 1960s-1980s rainfall decline and devastating 1984 drought. Following the 1980s, precipitation variability became increasingly influenced by the southern tropical Indian Ocean (STIO) region. Within this region, increases in sea-surface temperature, evaporation, and precipitation are linked with increased exports of dry mid-tropospheric air from the STIO region toward the GHA. Convergence of dry air above the GHA reduces local convection and precipitation. It also produces a clockwise circulation response near the ground that reduces moisture transports from the Congo Basin. Because precipitation originating in the Congo Basin has a unique isotopic signature, records of moisture transports from the Congo Basin may be preserved in the isotopic composition of annual tree rings in the Ethiopian Highlands. A negative trend in tree-ring oxygen-18 during the past half century suggests a decline in the proportion of precipitation originating from the Congo Basin. This trend may not be part of a natural cycle that will soon rebound because climate models characterize Indian Ocean warming as a principal signature of greenhouse-gas induced climate change. We therefore expect surface warming in the STIO region to continue to negatively impact GHA precipitation during northern-hemisphere summer. (orig.)

  20. The Zn abundance and isotopic composition of diatom frustules, a proxy for Zn availability in ocean surface seawater

    Science.gov (United States)

    Andersen, Morten B.; Vance, Derek; Archer, Corey; Anderson, Robert F.; Ellwood, Michael J.; Allen, Claire S.

    2011-01-01

    We have developed cleaning methods for extracting diatomopal from bulk marine sediment samples, for measurement of both zinc (Zn) abundance and isotope composition. This cleaning technique was then applied to a set of Holocene core-top samples from the Southern Ocean. The measured δ66Zn (reported relative to the JMCLyon standard) and Zn/Si ratios from the Southern Ocean diatomopal samples range from 0.7 to 1.5‰, and from 14 to 0.9 μmol/mol, respectively. The Zn abundance and isotope composition data show a clear correlation with opal burial rates and other oceanographic parameters. In common with previous work, we interpret the systematic changes in the Zn/Si ratio to be linked to the variability in the concentrations of bioavailable Zn in the ambient surface seawater where the diatom opal is formed. This variability is likely to be primarily controlled by the degree to which Zn is taken up into phytoplankton biomass. The observed systematic pattern in the δ66Zn compositions of the diatomopal core-top samples is, similarly, likely to reflect changes in the δ66Zn composition of the ambient Zn in the surface waters above the core-top sites, which is progressively driven towards isotopically heavier values by preferential incorporation of the lighter isotopes into phytoplankton organic material. Thus, the systematic relationship between Zn isotopes and abundance observed in the core-top diatomopal samples suggests a potential tool for investigating the biogeochemical cycling of Zn in the past surface ocean for down-core diatomopal material. In this respect, it may be possible to test hypotheses that attribute variations in atmospheric CO2 on glacial-interglacial timescales to the degree to which trace metals limited primary productivity in HNLC zones.