WorldWideScience

Sample records for surface mode liquid

  1. Design of tunable surface mode waveguide based on photonic crystal composite structure using organic liquid*

    International Nuclear Information System (INIS)

    Zhang Lan-Lan; Liu Wei; Li Ping; Yang Xi; Cao Xu

    2017-01-01

    With the method of replacing the surface layer of photonic crystal with tubes, a novel photonic crystal composite structure used as a tunable surface mode waveguide is designed. The tubes support tunable surface states. The tunable propagation capabilities of the structure are investigated by using the finite-difference time-domain. Simulation results show that the beam transmission distributions of the composite structure are sensitive to the frequency range of incident light and the surface morphology which can be modified by filling the tubes with different organic liquids. By adjusting the filler in tubes, the T-shaped, Y-shaped, and L-shaped propagations can be realized. The property can be applied to the tunable surface mode waveguide. Compared with a traditional single function photonic crystal waveguide, our designed structure not only has a small size, but also is a tunable device. (paper)

  2. Comprehensive three-dimensional analysis of surface plasmon polariton modes at uniaxial liquid crystal-metal interface.

    Science.gov (United States)

    Yen, Yin-Ray; Lee, Tsun-Hsiun; Wu, Zheng-Yu; Lin, Tsung-Hsien; Hung, Yu-Ju

    2015-12-14

    This paper describes the derivation of surface plasmon polariton modes associated with the generalized three-dimensional rotation of liquid crystal molecules on a metal film. The calculated dispersion relation was verified by coupling laser light into surface plasmon polariton waves in a one-dimensional grating device. The grating-assisted plasmon coupling condition was consistent with the formulated k(spp) value. This provides a general rule for the design of liquid-crystal tunable plasmonic devices.

  3. Oscillation mode transformation of edge magnetoplasmons in two-dimensional electron system on liquid-helium surface

    International Nuclear Information System (INIS)

    Yamanaka, Shuji; Yayama, Hideki; Arai, Toshikazau; Anju Sawada, Anju; Fukuda, Akira

    2013-01-01

    We measured the resonance spectra of edge magnetoplasmon (EMP) oscillations in a two-dimensional (2D) electron system located on a liquid-helium surface below 1.1 K. Systematic measurements of the resonance frequency and the damping rate as a function of the lateral confinement electric field strength shows clear evidence of the oscillation mode transformation. A pronounced change corresponding to the mode transformation was observed in the damping rate. When 2D electrons are confined in a strong lateral electric field, the damping is weak. As the lateral confinement electric field is reduced below a certain threshold value, an abrupt enhancement of the damping rate is observed. We hypothesize that the weak damping mode in the strong lateral confinement electric field is the compressive density oscillation of the electrons near the edge (conventional EMP) and the strong damping mode in the weak confinement field is the coupled mode of conventional EMP and the boundary displacement wave (BDW). The observation of the strong damping in the BDW-EMP coupled mode is a manifestation of the nearly incompressible feature of strongly interacting classical electrons, which agrees with earlier theoretical predictions.

  4. Surface modes in physics

    CERN Document Server

    Sernelius, Bo E

    2011-01-01

    Electromagnetic surface modes are present at all surfaces and interfaces between material of different dielectric properties. These modes have very important effects on numerous physical quantities: adhesion, capillary force, step formation and crystal growth, the Casimir effect etc. They cause surface tension and wetting and they give rise to forces which are important e.g. for the stability of colloids.This book is a useful and elegant approach to the topic, showing how the concept of electromagnetic modes can be developed as a unifying theme for a range of condensed matter physics. The

  5. Localized Acoustic Surface Modes

    KAUST Repository

    Farhat, Mohamed

    2015-08-04

    We introduce the concept of localized acoustic surface modes (ASMs). We demonstrate that they are induced on a two-dimensional cylindrical rigid surface with subwavelength corrugations under excitation by an incident acoustic plane wave. Our results show that the corrugated rigid surface is acoustically equivalent to a cylindrical scatterer with uniform mass density that can be represented using a Drude-like model. This, indeed, suggests that plasmonic-like acoustic materials can be engineered with potential applications in various areas including sensing, imaging, and cloaking.

  6. Surface tearing modes in tokamaks

    International Nuclear Information System (INIS)

    Takizuka, Tomonori; Kurita, Gen-ichi; Azumi, Masafumi; Takeda, Tatsuoki

    1985-10-01

    Surface tearing modes in tokamaks are studied numerically and analytically. The eigenvalue problem is solved to obtain the growth rate and the mode structure. We investigate in detail dependences of the growth rate of the m/n = 2/1 resistive MHD modes on the safety factor at the plasma surface, current profile, wall position, and resistivity. The surface tearing mode moves the plasma surface even when the wall is close to the surface. The stability diagram for these modes is presented. (author)

  7. Guided mode studies of smectic liquid crystals

    International Nuclear Information System (INIS)

    Hodder, B.

    2000-03-01

    Recently there has been considerable interest in the use of ferroelectric liquid crystals in low power, fast switching display devices. At present the voltage switching process in surface stabilised ferroelectric liquid crystal (SSFLC) devices is not fully understood and a convenient theory for such cells has yet to be found. It is the primary aim of this work to characterise the optic tensor configuration (director profile) in thin cells (∼ 3.5 μm) containing ferroelectric liquid crystal (FLC) material. These results form a benchmark by which continuum theories may be tested. Polarised microscopy is, perhaps, the most common optical probe of liquid crystal cells. It should be appreciated that this technique is fundamentally limited, as the results are deduced from an integrated optical response of any given cell, and cannot be used to spatially resolve details of the director profile through the cell. The guided mode techniques used in this study are the primary non-integral probe and enable detailed spatial resolution of the director profile within liquid crystal cells. Analysis of guided mode data from cells containing homeotropically aligned FLC reveals the temperature dependence of the optical biaxiality and cone angle for a 40% chiral mixture of the commercially available FLC SCE8*. From these optical biaxiality measurements the temperature dependence of the biaxial order parameter C is determined. Guided mode studies of cells containing homogeneously aligned SCE8* (the conventional alignment for SSFLC devices) reveal the 0V equilibrium director profile from which a cone and chevron model is constructed. Subsequent studies of voltage induced elastic deformations of the director profile are presented and compared with a single elastic constant continuum theory which is shown to be inadequate. Optical guided mode techniques are not directly sensitive to the smectic layer configuration but X-ray scattering is. Here, for the first time, results are presented

  8. Viscoelastic modes in chiral liquid crystals

    Indian Academy of Sciences (India)

    amit@fs.rri.local.net (Amit Kumar Agarwal)

    our studies on the viscoelastic modes of some chiral liquid crystals using dynamic light scattering. We discuss viscoelastic ... In the vicinity of the direct beam for a sample aligned in the Bragg mode and. 297 ... experimental investigations on these modes. Duke and Du ..... scattering volume is not true in practice. In an actual ...

  9. Surface Loving and Surface Avoiding modes

    OpenAIRE

    Combe, Nicolas; Huntzinger, Jean Roch; Morillo, Joseph

    2008-01-01

    International audience; We theoretically study the propagation of sound waves in GaAs/AlAs superlattices focussing on periodic modes in the vicinity of the band gaps. Based on analytical and numerical calculations, we show that these modes are the product of a quickly oscillating function times a slowly varying envelope function. We carefully study the phase of the envelope function compared to the surface of a semi-infinite superlattice. Especially, the dephasing of the superlattice compared...

  10. Nonlinear surface elastic modes in crystals

    Science.gov (United States)

    Gorentsveig, V. I.; Kivshar, Yu. S.; Kosevich, A. M.; Syrkin, E. S.

    1990-03-01

    The influence of nonlinearity on shear horizontal surface elastic waves in crystals is described on the basis of the effective nonlinear Schrödinger equation. It is shown that the corresponding solutions form a set of surface modes and the simplest mode coincides with the solution proposed by Mozhaev. The higher order modes have internal frequencies caused by the nonlinearity. All these modes decay in the crystal as uoexp(- z/ zo) atz≫ zo- u o-1 ( z is the distance from the crystal surface, uo the wave amplitude at the surface). The creation of the modes from a localized surface excitation has a threshold. The stability of the modes is discussed.

  11. Surface Tension Confines Cryogenic Liquid

    Science.gov (United States)

    Castles, Stephen H.; Schein, Michael E.

    1989-01-01

    New type of Dewar provides passive, constant-temperature cryogenic cooling for scientific instruments under normal-to low-gravity conditions. Known as Surface-Tension-Contained Liquid Cryogen Cooler (STCLCC), keeps liquid cryogen in known location inside the Dewar by trapping liquid inside spongelike material. Unique sponge material fills most of volume of inner tank. Sponge is all-silica, open-cell material similar to that used for Space Shuttle thermal-protection tiles.

  12. Optical defect modes in chiral liquid crystals

    International Nuclear Information System (INIS)

    Belyakov, V. A.; Semenov, S. V.

    2011-01-01

    An analytic approach to the theory of optical defect modes in chiral liquid crystals (CLCs) is developed. The analytic study is facilitated by the choice of the problem parameters. Specifically, an isotropic layer (with the dielectric susceptibility equal to the average CLC dielectric susceptibility) sandwiched between two CLC layers is studied. The chosen model allows eliminating the polarization mixing and reducing the corresponding equations to the equations for light of diffracting polarization only. The dispersion equation relating the defect mode (DM) frequency to the isotropic layer thickness and an analytic expression for the field distribution in the DM structure are obtained and the corresponding dependences are plotted for some values of the DM structure parameters. Analytic expressions for the transmission and reflection coefficients of the DM structure (CLC-defect layer-CLC) are presented and analyzed for nonabsorbing, absorbing, and amplifying CLCs. The anomalously strong light absorption effect at the DM frequency is revealed. The limit case of infinitely thick CLC layers is considered in detail. It is shown that for distributed feedback lasing in a defect structure, adjusting the lasing frequency to the DM frequency results in a significant decrease in the lasing threshold. The DM dispersion equations are solved numerically for typical values of the relevant parameters. Our approach helps clarify the physics of the optical DMs in CLCs and completely agrees with the corresponding results of the previous numerical investigations.

  13. Longitudinal Modes along Thin Piezoelectric Waveguides for Liquid Sensing Applications

    Directory of Open Access Journals (Sweden)

    Cinzia Caliendo

    2015-06-01

    Full Text Available The propagation of longitudinally polarized acoustic modes along thin piezoelectric plates (BN, ZnO, InN, AlN and GaN is theoretically studied, aiming at the design of high frequency electroacoustic devices suitable for work in liquid environments. The investigation of the acoustic field profile across the plate revealed the presence of longitudinally polarized Lamb modes, travelling at velocities close to that of the longitudinal bulk acoustic wave propagating in the same direction. Such waves are suitable for the implementation of high-frequency, low-loss electroacoustic devices operating in liquid environments. The time-averaged power flow density, the phase velocity and the electroacoustic coupling coefficient K2 dispersion curves were studied, for the first (S0 and four higher order (S1, S2, S3, S4 symmetrical modes for different electrical boundary conditions. Two electroacoustic coupling configurations were investigated, based on interdigitated transducers, with or without a metal floating electrode at the opposite plate surface. Enhanced performances, such as a K2 as high as 8.5% and a phase velocity as high as 16,700 m/s, were demostrated for the ZnO- and BN-based waveguides, as an example. The relative velocity changes, and the inertial and viscous sensitivities of the first symmetric and anti-symmetric mode, S0 and A0, propagating along thin plates bordered by a viscous liquid were derived using the perturbation approach. The present study highlights the feasibility of the piezoelectric waveguides to the development of high-frequency, integrated-circuits compatible electroacoustic devices suitable for working in liquid environment.

  14. Surface boiling of superheated liquid

    Energy Technology Data Exchange (ETDEWEB)

    Reinke, P. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-01-01

    A basic vaporization mechanism that possibly affects the qualitative and quantitative prediction of the consequences of accidental releases of hazardous superheated liquids was experimentally and analytically investigated. The studies are of relevance for the instantaneous failure of a containment vessel filled with liquefied gas. Even though catastrophical vessel failure is a rare event, it is considered to be a major technological hazard. Modeling the initial phase of depressurisation and vaporization of the contents is an essential step for the subsequent analysis of the spread and dispersion of the materials liberated. There is only limited understanding of this inertial expansion stage of the superheated liquid, before gravity and atmospheric turbulence begin to dominate the expansion. This work aims at a better understanding of the vaporization process and to supply more precise source-term data. It is also intended to provide knowledge for the prediction of the behavior of large-scale releases by the investigation of boiling on a small scale. Release experiments with butane, propane, R-134a and water were conducted. The vaporization of liquids that became superheated by sudden depressurisation was studied in nucleation-site-free glass receptacles. Several novel techniques for preventing undesired nucleation and for opening the test-section were developed. Releases from pipes and from a cylindrical geometry allowed both linear one-dimensional, and radial-front two-dimensional propagation to be investigated. Releases were made to atmospheric pressure over a range of superheats. It was found that, above a certain superheat temperature, the free surface of the metastable liquid rapidly broke up and ejected a high-velocity vapor/liquid stream. The zone of intense vaporization and liquid fragmentation proceeded as a front that advanced into the test fluids. No nucleation of bubbles in the bulk of the superheated liquid was observed. (author) figs., tabs., refs.

  15. Surface boiling of superheated liquid

    International Nuclear Information System (INIS)

    Reinke, P.

    1997-01-01

    A basic vaporization mechanism that possibly affects the qualitative and quantitative prediction of the consequences of accidental releases of hazardous superheated liquids was experimentally and analytically investigated. The studies are of relevance for the instantaneous failure of a containment vessel filled with liquefied gas. Even though catastrophical vessel failure is a rare event, it is considered to be a major technological hazard. Modeling the initial phase of depressurisation and vaporization of the contents is an essential step for the subsequent analysis of the spread and dispersion of the materials liberated. There is only limited understanding of this inertial expansion stage of the superheated liquid, before gravity and atmospheric turbulence begin to dominate the expansion. This work aims at a better understanding of the vaporization process and to supply more precise source-term data. It is also intended to provide knowledge for the prediction of the behavior of large-scale releases by the investigation of boiling on a small scale. Release experiments with butane, propane, R-134a and water were conducted. The vaporization of liquids that became superheated by sudden depressurisation was studied in nucleation-site-free glass receptacles. Several novel techniques for preventing undesired nucleation and for opening the test-section were developed. Releases from pipes and from a cylindrical geometry allowed both linear one-dimensional, and radial-front two-dimensional propagation to be investigated. Releases were made to atmospheric pressure over a range of superheats. It was found that, above a certain superheat temperature, the free surface of the metastable liquid rapidly broke up and ejected a high-velocity vapor/liquid stream. The zone of intense vaporization and liquid fragmentation proceeded as a front that advanced into the test fluids. No nucleation of bubbles in the bulk of the superheated liquid was observed. (author) figs., tabs., refs

  16. Tapping mode atomic force microscopy in liquid

    NARCIS (Netherlands)

    Putman, Constant A.J.; Putman, C.A.J.; van der Werf, Kees; de Grooth, B.G.; van Hulst, N.F.; Greve, Jan

    1994-01-01

    We show that standard silicon nitride cantilevers can be used for tapping mode atomic force microscopy (AFM) in air, provided that the energy of the oscillating cantilever is sufficiently high to overcome the adhesion of the water layer. The same cantilevers are successfully used for tapping mode

  17. Acidic ionic liquids for n-alkane isomerization in a liquid-liquid or slurry-phase reaction mode

    Energy Technology Data Exchange (ETDEWEB)

    Meyer, C.; Hager, V.; Geburtig, D.; Kohr, C.; Wasserscheid, P. [Erlangen-Nuernberg Univ. (Germany). Lehrstuhl fuer Chemische Reaktionstechnik; Haumann, M. [Chemical Reaction Engineering, FAU Busan Campus, Korea (Korea, Republic of)

    2011-07-01

    Highly acidic ionic liquid (IL) catalysts offer the opportunity to convert n-alkanes at very low reaction temperatures. The results of IL catalyzed isomerization and cracking reactions of pure n-octane are presented. Influence of IL composition, [C{sub 4}C{sub 1}Im]Cl / AlCl{sub 3} / H{sub 2}SO{sub 4} and [C{sub 4}C{sub 1}Im]Cl / AlCl{sub 3} / 1-chlorooctane, on catalyst activity and selectivities to branched alkanes was investigated. Acidic chloroaluminate IL catalysts form liquid-liquid biphasic systems with unpolar organic product mixtures. Thus, recycling of the acidic IL is enabled by simple phase separation in the liquid-liquid biphasic reaction mode or the IL can be immobilized on an inorganic support with a large specific surface area. These supported ionic liquid phase (SILP) catalysts offer the advantage to get a macroscopically heterogeneous system while still preserving all benefits of the homogeneous catalyst which can be used for the slurry-phase n-alkane isomerization. The interaction of the solid support and acidic IL influences strongly the catalytic activity. (orig.)

  18. The breathing mode and the nuclear surface

    International Nuclear Information System (INIS)

    Blaizot, J.P.; Grammaticos, B.

    1981-01-01

    The role of nuclear surface in the breathing mode of nuclei is analyzed. We discuss a simple model in which the density varies according to a scaling of the coordinates. We show that this model reproduces accurately the results of microscopic calculations in heavy nuclei, and we use it to estimate the contribution of the surface to the effective compression modulus of semi-infinite nuclear matter. The calculation is performed in the framework of an extended Thomas-Fermi approximation and using several effective interactions. It is shown that the surface energy is maximum with respect to variations of the density around saturation density. The reduction of the effective compression modulus due to the surface turns to be proportional to the bulk compression modulus. The magnitude of the effect is compared with results of RPA calculations. Other contributions to the effective compressions modulus of finite nuclei are also discussed. (orig.)

  19. Suppression of the dayside magnetopause surface modes

    Directory of Open Access Journals (Sweden)

    Pilipenko V.A.

    2017-12-01

    Full Text Available Magnetopause surface eigenmodes were suggested as a potential source of dayside high-latitude broadband pulsations in the Pc5-6 band (frequency about 1–2 mHz. However, the search for a ground signature of these modes has not provided encouraging results. The comparison of multi-instrument data from Svalbard with the latitudinal structure of Pc5-6 pulsations, recorded by magnetometers covering near-cusp latitudes, has shown that often the latitudinal maximum of pulsation power occurs about 2–3° deeper in the magnetosphere than the dayside open-closed field line boundary (OCB. The OCB proxy was determined from SuperDARN radar data as the equatorward boundary of enhanced width of a return radio signal. The OCB-ULF correspondence is further examined by comparing the latitudinal profile of the near-noon pulsation power with the equatorward edge of the auroral red emission from the meridian scanning photometer. In most analyzed events, the “epicenter” of Pc5-6 power is at 1–2° lower latitude than the optical OCB proxy. Therefore, the dayside Pc5-6 pulsations cannot be associated with the ground image of the magnetopause surface modes or with oscillations of the last field line. A lack of ground response to these modes beneath the ionospheric projection of OCB seems puzzling. As a possible explanation, we suggest that a high variability of the outer magnetosphere near the magnetopause region may suppress the excitation efficiency. To quantify this hypothesis, we consider a driven field line resonator terminated by conjugate ionospheres with stochastic fluctuations of its eigenfrequency. A solution of this problem predicts a substantial deterioration of resonant properties of MHD resonator even under a relatively low level of background fluctuations. This effect may explain why there is no ground response to magnetopause surface modes or oscillations of the last field line at the OCB latitude, but it can be seen at somewhat lower latitudes

  20. Entanglement generation between two atoms via surface modes

    International Nuclear Information System (INIS)

    Xu Jingping; Yang Yaping; Al-Amri, M.; Zhu Shiyao; Zubairy, M. Suhail

    2011-01-01

    We discuss the coupling of two identical atoms, separated by a metal or metamaterial slab, through surface modes. We show that the coupling through the surface modes can induce entanglement. We discuss how to control the coupling for the metal or metamaterial slab by adjusting the symmetrical and antisymmetrical property of the surface modes. We analyze the dispersion relation of the surface modes and study the parameter ranges that support the surface modes with the same properties. Our results have potential applications in quantum communication and quantum computation.

  1. Electrons on the surface of liquid helium

    International Nuclear Information System (INIS)

    Lambert, D.K.

    1979-05-01

    Spectroscopic techniques were used to study transitions of electrons between bound states in the potential well near a helium surface. The charge density distribution of electrons on the surface was independently obtained from electrical measurements. From the measurements, information was obtained both about the interaction of the bound state electrons with the surface of liquid helium and about local disorder in the positions of electrons on the surface

  2. Surface modes of ultra-cold atomic clouds with very large number of vortices

    Energy Technology Data Exchange (ETDEWEB)

    Cazalilla, M A [Donostia International Physics Center, Donostia (Spain); [Abdus Salam International Centre for Theoretical Physics, Trieste (Italy)

    2003-04-01

    We study the surface modes of some of the vortex liquids recently found by means of exact diagonalizations in systems of rapidly rotating bosons. In contrast to the surface modes of Bose condensates, we find that the surface waves have a frequency linear in the excitation angular momentum, h-bar l > 0. Furthermore, in analogy with the edge waves of electronic quantum Hall states, these excitations are chiral, that is, they can be excited only for values of l that increase the total angular momentum of the vortex liquid. However, differently from the quantum Hall phenomena for electrons, we also find other excitations that are approximately degenerate in the laboratory frame with the surface modes, and which decrease the total angular momentum by l quanta. The surface modes of the Laughlin, as well as other scalar and vector boson states are analyzed, and their observable properties characterized. We argue that measurement of the response of a vortex liquid to a weak time-dependent potential that imparts angular momentum to the system should provide valuable information to characterize the vortex liquid. In particular, the intensity of the signal of the surface waves in the dynamic structure factor has been studied and found to depend on the type of vortex liquid. We point out that the existence of surface modes has observable consequences on the density profile of the Laughlin state. These features are due to the strongly correlated behavior of atoms in the vortex liquids. We point out that these correlations should be responsible for a remarkable stability of some vortex liquids with respect to three-body losses. (author)

  3. Surface studies of liquid metals and alloys

    International Nuclear Information System (INIS)

    Bastasz, Robert

    2003-01-01

    Liquid metals and alloys have been proposed for use in nuclear fusion reactors to serve as replaceable plasma-facing surfaces that remove particles and heat from reacting plasmas. Several materials are being considered for this purpose including lithium, gallium, and tin as well as some of the alloys made from these elements. In order to better understand the properties of liquid surfaces, the technique of low-energy ion scattering was used to examine the surface composition of several of these materials in vacuum as a function of temperature. Oxygen is found to rapidly segregate to the surface of several metallic liquids. The segregation process can be interpreted using a simple thermodynamic model based on Gibbs theory. In the case of an alloy of Sn and Li, Li also segregates to the liquid surface. This provides a means to produce a surface enriched in Li, which is more plasma compatible than Sn, without the need to handle large quantities of liquid Li. (author)

  4. Liquid-vapour surface sensors for liquid nitrogen and hydrogen

    Science.gov (United States)

    Siegwarth, J. D.; Voth, R. O.; Snyder, S. M.

    1992-01-01

    The present paper identifies devices to serve as liquid-vapor detectors in zero gravity. The testing in LH2 was done in a sealed glass Dewar system to eliminate any chance of mixing H2 and air. Most of the tests were performed with the leads to the sensor horizontal. Some results of rapid cycle testing of LVDG in LH2 are presented. Findings of rapid-cycle testing of LVDG in LH2 are discussed. The sensor crossed the liquid surface when the position sensor registered 1.9 V, which occurred at about 0.4075 s. The delay time was about 1.5 ms. From the estimated slope of the position sensor curve at 1.9 V, the velocity of the sensor through the liquid surface is over 3 m/s. Results of tests of optical sensors are presented as well.

  5. Surface study of liquid 3He using surface state electrons

    International Nuclear Information System (INIS)

    Shirahama, K.; Ito, S.; Suto, H.; Kono, K.

    1995-01-01

    We have measured the mobility of surface state electrons (SSE) on liquid 3 He, μ 3 , aiming to study the elementary surface excitations of the Fermi liquid. A gradual increase of μ 3 below 300 mK is attributed to the scattering of electrons by ripplons. Ripplons do exist in 3 He down to 100 mK. We observe an abrupt decrease of μ 3 , due to the transition to the Wigner solid (WS). The dependences of the WS conductivity and mobility on temperature and magnetic field differ from the SSE behavior on liquid 4 He

  6. Linking density functional and mode coupling models for supercooled liquids

    Energy Technology Data Exchange (ETDEWEB)

    Premkumar, Leishangthem; Bidhoodi, Neeta; Das, Shankar P. [School of Physical Sciences, Jawaharlal Nehru University, New Delhi 110067 (India)

    2016-03-28

    We compare predictions from two familiar models of the metastable supercooled liquid, respectively, constructed with thermodynamic and dynamic approaches. In the so called density functional theory the free energy F[ρ] of the liquid is a functional of the inhomogeneous density ρ(r). The metastable state is identified as a local minimum of F[ρ]. The sharp density profile characterizing ρ(r) is identified as a single particle oscillator, whose frequency is obtained from the parameters of the optimum density function. On the other hand, a dynamic approach to supercooled liquids is taken in the mode coupling theory (MCT) which predict a sharp ergodicity-non-ergodicity transition at a critical density. The single particle dynamics in the non-ergodic state, treated approximately, represents a propagating mode whose characteristic frequency is computed from the corresponding memory function of the MCT. The mass localization parameters in the above two models (treated in their simplest forms) are obtained, respectively, in terms of the corresponding natural frequencies depicted and are shown to have comparable magnitudes.

  7. Linking density functional and mode coupling models for supercooled liquids.

    Science.gov (United States)

    Premkumar, Leishangthem; Bidhoodi, Neeta; Das, Shankar P

    2016-03-28

    We compare predictions from two familiar models of the metastable supercooled liquid, respectively, constructed with thermodynamic and dynamic approaches. In the so called density functional theory the free energy F[ρ] of the liquid is a functional of the inhomogeneous density ρ(r). The metastable state is identified as a local minimum of F[ρ]. The sharp density profile characterizing ρ(r) is identified as a single particle oscillator, whose frequency is obtained from the parameters of the optimum density function. On the other hand, a dynamic approach to supercooled liquids is taken in the mode coupling theory (MCT) which predict a sharp ergodicity-non-ergodicity transition at a critical density. The single particle dynamics in the non-ergodic state, treated approximately, represents a propagating mode whose characteristic frequency is computed from the corresponding memory function of the MCT. The mass localization parameters in the above two models (treated in their simplest forms) are obtained, respectively, in terms of the corresponding natural frequencies depicted and are shown to have comparable magnitudes.

  8. Liquid infused porous surfaces for mineral fouling mitigation.

    Science.gov (United States)

    Charpentier, Thibaut V J; Neville, Anne; Baudin, Sophie; Smith, Margaret J; Euvrard, Myriam; Bell, Ashley; Wang, Chun; Barker, Richard

    2015-04-15

    Prevention of mineral fouling, known as scale, is a long-standing problem in a wide variety of industrial applications, such as oil production, water treatment, and many others. The build-up of inorganic scale such as calcium carbonate on surfaces and facilities is undesirable as it can result in safety risks and associated flow assurance issues. To date the overwhelming amount of research has mainly focused on chemical inhibition of scale bulk precipitation and little attention has been paid to deposition onto surfaces. The development of novel more environmentally-friendly strategies to control mineral fouling will most probably necessitate a multifunctional approach including surface engineering. In this study, we demonstrate that liquid infused porous surfaces provide an appealing strategy for surface modification to reduce mineral scale deposition. Microporous polypyrrole (PPy) coatings were fabricated onto stainless steel substrates by electrodeposition in potentiostatic mode. Subsequent infusion of low surface energy lubricants (fluorinated oil Fluorinert FC-70 and ionic liquid 1-Butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BMIm)) into the porous coatings results in liquid-repellent slippery surfaces. To assess their ability to reduce surface scaling the coatings were subjected to a calcium carbonate scaling environment and the scale on the surface was quantified using Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES). PPy surfaces infused with BMIm (and Fluorinert to a lesser extent) exhibit remarkable antifouling properties with the calcium carbonate deposition reduced by 18 times in comparison to untreated stainless steel. These scaling tests suggest a correlation between the stability of the liquid infused surfaces in artificial brines and fouling reduction efficiency. The current work shows the great potential of such novel coatings for the management of mineral scale fouling. Copyright © 2014 Elsevier Inc. All rights

  9. Collective dynamics of simple liquids: A mode-coupling description

    Directory of Open Access Journals (Sweden)

    W.Schirmacher

    2008-03-01

    Full Text Available We use the mode-coupling theory (MCT, which has been highly successful in accounting for the anomalous relaxation behaviour near the liquid-to-glass transition, for describing the dynamics of simple (i.e. monatomic liquids away from the glass formation regime. We find that the dynamical structure factor predicted by MCT compares well to experimental findings and results of computer simulations. The memory function exhibits a two-step decay as found frequently in experimental and simulation data. The long-time relaxation regime, in which the relaxation rate strongly depends on the density and is identified as the α relaxation. At high density this process leads the glass instability. The short-time relaxation rate is fairly independent of density.

  10. Interaction between liquid droplets and heated surface

    Energy Technology Data Exchange (ETDEWEB)

    Nigmatulin, B I [Research and Engineering Centre, LWR Nuclear Plants Safety, Elektrogorsk (Russian Federation); Vasiliev, N I [Research and Engineering Centre, LWR Nuclear Plants Safety, Elektrogorsk (Russian Federation); Guguchkin, V V [Research and Engineering Centre, LWR Nuclear Plants Safety, Elektrogorsk (Russian Federation)

    1993-06-01

    In this paper, experimental methods and investigation results of interaction between droplets of different liquids and a heated surface are presented. Wetted area, contact time period and transition boundary from wetted to non-wetted interaction regimes are experimentally evaluated. A simple connection of the wetted area value and contact time period with the heat removal efficiency is shown. (orig.)

  11. Evaporation of liquids on chemically patterned surfaces

    NARCIS (Netherlands)

    Vieyra Salas, J.A.; Darhuber, A.A.

    2011-01-01

    We studied evaporation rates of volatile liquids deposited onto chemically patterned surfaces by means of experiments and numerical simulations. We quantified the influence of the droplet geometry, in particular circular, triangular, rectangular and square shapes, as well as the influence of contact

  12. Biologically inspired hairy surfaces for liquid repellency

    Science.gov (United States)

    Hsu, Shu-Hau

    Owing to remarkable features, such as self-cleaning, anti-biofouling and drag reduction, interest on rendering surfaces water-repellent has significantly grown within this decade. Attempts on making surfaces "superhydrophobic", where high water contact angle (θc >150°) accompanied with only few degrees of roll-off angle, have been extensively demonstrated through the mimicking of the surface chemistry and morphology of lotus leaves. This appealing phenomenon also exists on another structure from nature: surfaces comprising soft hairs. Although the role of this piliferous integument has long been recognized for providing life, arthropods in particular, waterrepellency, the synthetic superhydrophobic surfaces based on this structure are still very limited. In this study, the goal was to develop a novel liquid-repellent surface by mimicking the hairy exterior of species. The artificial hairy surfaces were prepared by means of pressurized membrane casting, in which thermoplastic sheets were forced to flow into porous membranes at elevated temperature. The G-shaped pillars on the membrane cast polypropylene substrate are particularly similar to the conformation of natural hairs. The principle of this fabrication technique is relatively accessible and is expected to be compatible with large-area fabrication of superhydrophobic interfaces. The artificial hairy surface features perfectly hydrophobic response where no contact angle hysteresis was observed from video assessment. Thus the artificial hairy surface of the current work appears to be the first report to have such extreme hydrophobicity with only structural modification from the original substrate. This ultralow adhesion to water droplet is believed to be attributed to the hydrophobic methyl groups and the mechanical response of the artificial hairs. Liquid repellency of the hairy surfaces was further enhanced by coating with fluorocarbon (CF) layers via deep reactive ion etching (DRIE). The contact angle of

  13. Nonflat equilibrium liquid shapes on flat surfaces.

    Science.gov (United States)

    Starov, Victor M

    2004-01-15

    The hydrostatic pressure in thin liquid layers differs from the pressure in the ambient air. This difference is caused by the actions of surface forces and capillary pressure. The manifestation of the surface force action is the disjoining pressure, which has a very special S-shaped form in the case of partial wetting (aqueous thin films and thin films of aqueous electrolyte and surfactant solutions, both free films and films on solid substrates). In thin flat liquid films the disjoining pressure acts alone and determines their thickness. However, if the film surface is curved then both the disjoining and the capillary pressures act simultaneously. In the case of partial wetting their simultaneous action results in the existence of nonflat equilibrium liquid shapes. It is shown that in the case of S-shaped disjoining pressure isotherm microdrops, microdepressions, and equilibrium periodic films exist on flat solid substrates. Criteria are found for both the existence and the stability of these nonflat equilibrium liquid shapes. It is shown that a transition from thick films to thinner films can go via intermediate nonflat states, microdepressions and periodic films, which both can be more stable than flat films within some range of hydrostatic pressure. Experimental investigations of shapes of the predicted nonflat layers can open new possibilities of determination of disjoining pressure in the range of thickness in which flat films are unstable.

  14. A comparison of various modes of liquid-liquid based microextraction techniques: determination of picric acid.

    Science.gov (United States)

    Burdel, Martin; Šandrejová, Jana; Balogh, Ioseph S; Vishnikin, Andriy; Andruch, Vasil

    2013-03-01

    Three modes of liquid-liquid based microextraction techniques--namely auxiliary solvent-assisted dispersive liquid-liquid microextraction, auxiliary solvent-assisted dispersive liquid-liquid microextraction with low-solvent consumption, and ultrasound-assisted emulsification microextraction--were compared. Picric acid was used as the model analyte. The determination is based on the reaction of picric acid with Astra Phloxine reagent to produce an ion associate easily extractable by various organic solvents, followed by spectrophotometric detection at 558 nm. Each of the compared procedures has both advantages and disadvantages. The main benefit of ultrasound-assisted emulsification microextraction is that no hazardous chlorinated extraction solvents and no dispersive solvent are necessary. Therefore, this procedure was selected for validation. Under optimized experimental conditions (pH 3, 7 × 10(-5) mol/L of Astra Phloxine, and 100 μL of toluene), the calibration plot was linear in the range of 0.02-0.14 mg/L and the LOD was 7 μg/L of picric acid. The developed procedure was applied to the analysis of spiked water samples. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Preparation and evaluation of surface-bonded tricationic ionic liquid silica as stationary phases for high-performance liquid chromatography.

    Science.gov (United States)

    Qiao, Lizhen; Shi, Xianzhe; Lu, Xin; Xu, Guowang

    2015-05-29

    Two tricationic ionic liquids were prepared and then bonded onto the surface of supporting silica materials through "thiol-ene" click chemistry as new stationary phases for high-performance liquid chromatography. The obtained columns of tricationic ionic liquids were evaluated respectively in the reversed-phase liquid chromatography (RPLC) mode and hydrophilic interaction liquid chromatography (HILIC) mode, and possess ideal column efficiency of 80,000 plates/m in the RPLC mode with naphthalene as the test solute. The tricationic ionic liquid stationary phases exhibit good hydrophobic and shape selectivity to hydrophobic compounds, and RPLC retention behavior with multiple interactions. In the HILIC mode, the retention and selectivity were evaluated through the efficient separation of nucleosides and bases as well as flavonoids, and the typical HILIC retention behavior was demonstrated by investigating retention changes of hydrophilic solutes with water volume fraction in mobile phase. The results show that the tricationic ionic liquid columns possess great prospect for applications in analysis of hydrophobic and hydrophilic samples. Copyright © 2015 Elsevier B.V. All rights reserved.

  16. Nonlinear Longitudinal Mode Instability in Liquid Propellant Rocket Engine Preburners

    Science.gov (United States)

    Sims, J. D. (Technical Monitor); Flandro, Gary A.; Majdalani, Joseph; Sims, Joseph D.

    2004-01-01

    Nonlinear pressure oscillations have been observed in liquid propellant rocket instability preburner devices. Unlike the familiar transverse mode instabilities that characterize primary combustion chambers, these oscillations appear as longitudinal gas motions with frequencies that are typical of the chamber axial acoustic modes. In several respects, the phenomenon is similar to longitudinal mode combustion instability appearing in low-smoke solid propellant motors. An important feature is evidence of steep-fronted wave motions with very high amplitude. Clearly, gas motions of this type threaten the mechanical integrity of associated engine components and create unacceptably high vibration levels. This paper focuses on development of the analytical tools needed to predict, diagnose, and correct instabilities of this type. For this purpose, mechanisms that lead to steep-fronted, high-amplitude pressure waves are described in detail. It is shown that such gas motions are the outcome of the natural steepening process in which initially low amplitude standing acoustic waves grow into shock-like disturbances. The energy source that promotes this behavior is a combination of unsteady combustion energy release and interactions with the quasi-steady mean chamber flow. Since shock waves characterize the gas motions, detonation-like mechanisms may well control the unsteady combustion processes. When the energy gains exceed the losses (represented mainly by nozzle and viscous damping), the waves can rapidly grow to a finite amplitude limit cycle. Analytical tools are described that allow the prediction of the limit cycle amplitude and show the dependence of this wave amplitude on the system geometry and other design parameters. This information can be used to guide corrective procedures that mitigate or eliminate the oscillations.

  17. Design integration of liquid surface divertors

    International Nuclear Information System (INIS)

    Nygren, R.E.; Cowgill, D.F.; Ulrickson, M.A.; Nelson, B.E.; Fogarty, P.J.; Rognlien, T.D.; Rensink, M.E.; Hassanein, A.; Smolentsev, S.S.; Kotschenreuther, M.

    2004-01-01

    The US Enabling Technology Program in fusion is investigating the use of free flowing liquid surfaces facing the plasma. We have been studying the issues in integrating a liquid surface divertor into a configuration based upon an advanced tokamak, specifically the ARIES-RS configuration. The simplest form of such a divertor is to extend the flow of the liquid first wall into the divertor and thereby avoid introducing additional fluid streams. In this case, one can modify the flow above the divertor to enhance thermal mixing. For divertors with flowing liquid metals (or other electrically conductive fluids) MHD (magneto-hydrodynamics) effects are a major concern and can produce forces that redirect flow and suppress turbulence. An evaluation of Flibe (a molten salt) as a working fluid was done to assess a case in which the MHD forces could be largely neglected. Initial studies indicate that, for a tokamak with high power density, an integrated Flibe first wall and divertor does not seem workable. We have continued work with molten salts and replaced Flibe with Flinabe, a mixture of lithium, sodium and beryllium fluorides, that has some potential because of its lower melting temperature. Sn and Sn-Li have also been considered, and the initial evaluations on heat removal with minimal plasma contamination show promise, although the complicated 3D MHD flows cannot yet be fully modeled. Particle pumping in these design concepts is accomplished by conventional means (ports and pumps). However, trapping of hydrogen in these flowing liquids seems plausible and novel concepts for entrapping helium are also being studied

  18. Density and surface tension of ionic liquids.

    Science.gov (United States)

    Kolbeck, C; Lehmann, J; Lovelock, K R J; Cremer, T; Paape, N; Wasserscheid, P; Fröba, A P; Maier, F; Steinrück, H-P

    2010-12-30

    We measured the density and surface tension of 9 bis[(trifluoromethyl)sulfonyl]imide ([Tf(2)N](-))-based and 12 1-methyl-3-octylimidazolium ([C(8)C(1)Im](+))-based ionic liquids (ILs) with the vibrating tube and the pendant drop method, respectively. This comprehensive set of ILs was chosen to probe the influence of the cations and anions on density and surface tension. When the alkyl chain length in the [C(n)C(1)Im][Tf(2)N] series (n = 1, 2, 4, 6, 8, 10, 12) is increased, a decrease in density is observed. The surface tension initially also decreases but reaches a plateau for alkyl chain lengths greater than n = 8. Functionalizing the alkyl chains with ethylene glycol groups results in a higher density as well as a higher surface tension. For the dependence of density and surface tension on the chemical nature of the anion, relations are only found for subgroups of the studied ILs. Density and surface tension values are discussed with respect to intermolecular interactions and surface composition as determined by angle-resolved X-ray photoelectron spectroscopy (ARXPS). The absence of nonvolatile surface-active contaminants was proven by ARXPS.

  19. Synchrotron x-ray diffraction study of liquid surfaces

    DEFF Research Database (Denmark)

    Als-Nielsen, Jens Aage; Pershan, P.S.

    1983-01-01

    A spectrometer for X-ray diffraction and refraction studies of horizontal, free surfaces of liquids is described. As an illustration smetic-A layering at the surface of a liquid crystal is presented.......A spectrometer for X-ray diffraction and refraction studies of horizontal, free surfaces of liquids is described. As an illustration smetic-A layering at the surface of a liquid crystal is presented....

  20. Neutrons on a surface of liquid helium

    Science.gov (United States)

    Grigoriev, P. D.; Zimmer, O.; Grigoriev, A. D.; Ziman, T.

    2016-08-01

    We investigate the possibility of ultracold neutron (UCN) storage in quantum states defined by the combined potentials of the Earth's gravity and the neutron optical repulsion by a horizontal surface of liquid helium. We analyze the stability of the lowest quantum state, which is most susceptible to perturbations due to surface excitations, against scattering by helium atoms in the vapor and by excitations of the liquid, comprised of ripplons, phonons, and surfons. This is an unusual scattering problem since the kinetic energy of the neutron parallel to the surface may be much greater than the binding energies perpendicular. The total scattering time of these UCNs at 0.7 K is found to exceed 1 h, and rapidly increases with decreasing temperature. Such low scattering rates should enable high-precision measurements of the sequence of discrete energy levels, thus providing improved tests of short-range gravity. The system might also be useful for neutron β -decay experiments. We also sketch new experimental propositions for level population and trapping of ultracold neutrons above a flat horizontal mirror.

  1. Mode conversion and its utilization of degenerating surface wave modes on a plasma column

    International Nuclear Information System (INIS)

    Nonaka, S.; Akao, Y.

    1983-01-01

    Both mode conversion at degenerating points of dispersion relations for surface wave modes on a discharge plasma column and the methods for their detection and utilization are presented. Mode conversions at three degenerating points become observable by using a surface wave resonator when an azimuthal inhomogeneity of plasma is produced by a static magnetic field of about 1 G applied perpendicular to the column axis. Two of the three detected degenerating points can be utilized for an easy and exact determination of the electron density and its distribution in the discharge tube

  2. X-ray fractography of fatigue fracture surface under mode I and mode III loading

    International Nuclear Information System (INIS)

    Akiniwa, Yoshiaki; Tanaka, Keisuke; Tsumura, Tsuyoshi

    2001-01-01

    The propagation behavior of a circumferential fatigue crack in cylindrical bars of a carbon steel (JIS SGV410) and a stainless steel (JIS SUS316NG) was investigated under cyclic axial and torsional loadings. The J-integral range was used as a fracture mechanics parameter. When compared at the same J-integral range, the crack propagation rate under mode III was smaller than that under mode I. Parallel markings perpendicular to the crack propagation direction were observed on the fatigue fracture surface obtained under mode III loading. The residual stresses in the radial direction, σ r , and in the tangential direction, σ θ , were measured for both mode I and mode III fatigue fracture surfaces. For mode I fracture surface, σ r was tension, and was almost constant irrespective of the applied J-integral range. σ θ was close to zero for both materials. On the other hand, for mode III, σ r and σ θ were compression. For SUS316NG steel, the compressive stress of σ θ increased with the J-integral range. For SGV410 steel, the change of σ θ with the J-integral range was small. The breadth of diffraction profiles increased with J-integral range for both mode I and III. The breadth was found to be a good parameter to evaluate the applied J-integral range. (author)

  3. Localized modes in optics of photonic liquid crystals with local anisotropy of absorption

    Energy Technology Data Exchange (ETDEWEB)

    Belyakov, V. A., E-mail: bel1937@mail.ru, E-mail: bel@landau.ac.ru [Russian Academy of Science, Landau Institute for Theoretical Physics (Russian Federation); Semenov, S. V. [National Research Center “Kurchatov Institute,” (Russian Federation)

    2016-05-15

    The localized optical modes in spiral photonic liquid crystals are theoretically studied for the certainty at the example of chiral liquid crystals (CLCs) for the case of CLC with an anisotropic local absorption. The model adopted here (absence of dielectric interfaces in the structures under investigation) makes it possible to get rid of mixing of polarizations on the surfaces of the CLC layer and of the defect structure and to reduce the corresponding equations to only the equations for light with polarization diffracting in the CLC. The dispersion equations determining connection of the edge mode (EM) and defect mode (DM) frequencies with the CLC layer parameters (anisotropy of local absorption, CLC order parameter) and other parameters of the DMS are obtained. Analytic expressions for the transmission and reflection coefficients of CLC layer and DMS for the case of CLC with an anisotropic local absorption are presented and analyzed. It is shown that the CLC layers with locally anisotropic absorption reduce the EM and DM lifetimes (and increase the lasing threshold) in the way different from the case of CLC with an isotropic local absorption. Due to the Borrmann effect revealing of which is different at the opposite stop-band edges in the case of CLC layers with an anisotropic local absorption the EM life-times for the EM frequencies at the opposite stop-bands edges may be significantly different. The options of experimental observations of the theoretically revealed phenomena are briefly discussed.

  4. How to separate ionic liquids: Use of Hydrophilic Interaction Liquid Chromatography and mixed mode phases

    International Nuclear Information System (INIS)

    Lamouroux, C.

    2011-01-01

    This chromatographic study deals with the development of a convenient and versatile method to separate Room Temperature Ionic Liquids. Different modes of chromatography were studied. The study attempts to answer the following question: 'what were the most important interactions for the separation of ionic liquids?'. The results show that the essential interactions to assure a good retention of RTILs are the ionic ones and that hydrophobic interactions play a role in the selectivity of the separation. The separation of five imidazolium salt with a traditional dial columns in Hydrophilic Interaction Chromatography (HILIC) was demonstrated. It shows that neutral diol grafted column allows an important retention that we assume is due to the capability of diol to develop a thick layer of water. Furthermore, stationary phase based on mixed interaction associating ion exchange and hydrophobic properties were studied. Firstly, it will be argued that it is possible to separate RTILs with a convenient retention and resolution according to a reverse phase elution with the Primesep columns made of a brush type long alkyl chain with an embedded negatively charged functional group. Secondly, a successful separation of RTILs in HILIC mode with a mixed phase column containing a cationic exchanger and a hydrophobic octyl chain length will be demonstrated. (author)

  5. Surface vibrational modes in disk-shaped resonators.

    Science.gov (United States)

    Dmitriev, A V; Gritsenko, D S; Mitrofanov, V P

    2014-03-01

    The natural frequencies and distributions of displacement components for the surface vibrational modes in thin isotropic elastic disks are calculated. In particular, the research is focused on even solutions for low-lying resonant vibrations with large angular wave numbers. Several families of modes are found which are interpreted as modified surface modes of an infinitely long cylinder and Lamb modes of a plate. The results of calculation are compared with the results of the experimental measurements of vibrational modes generated by means of resonant excitation in duraluminum disk with radius of ≈90 mm and thickness of 16 mm in the frequency range of 130-200 kHz. An excellent agreement between the calculated and measured frequencies is found. Measurements of the structure of the resonant peaks show splitting of some modes. About a half of the measured modes has splitting Δfsplit/fmode at the level of the order of 10(-5). The Q-factors of all modes measured in vacuum lie in the interval (2…3)×10(5). This value is typical for duraluminum mechanical resonators in the ultrasonic frequency range. Copyright © 2013 Elsevier B.V. All rights reserved.

  6. Effect of surface parameter of interband surface mode frequencies of finite diatomic chain

    International Nuclear Information System (INIS)

    Puszkarski, H.

    1982-07-01

    The surface modes of a finite diatomic chain of alternating atoms (M 1 not= M 2 ) are investigated. The surface force constants are assumed to differ from the bulk ones, with the resulting surface parameter a-tilde identical on both ends of the chain. Criteria, governing the existence of interband surface (IBS) modes with frequencies lying in the forbidden gap between acoustical and optical bulk bands for natural (a = 1) as well as non-natural (a not= 1) surface defect, are analysed by the difference equation method. It is found that the IBS modes localize, depending on the value of the surface parameter a, either at the surface of lighter atoms (if a-tilde is positive), or at that of heavier atoms (if a-tilde is negative). Two, one of no IBS modes are found to exist in the chain depending on the relation between the mass ratio and surface parameter - quantities on which the surface localization increment t-tilde depends. If two modes are present (one acoustical and the other optical), their frequencies are disposed symmetrically with respect to the middle of the forbidden gap, provided the surface defect is natural, or asymmetrically - if it is other than natural. If the localization of the IBS mode exceeds a well defined critical value tsub(c), the mode frequency becomes complex, indicating that the mode undergoes a damping. A comparison of the present results and those obtained by Wallis for the diatomic chain with natural surface defect is also given. (author)

  7. Surface-bonded ionic liquid stationary phases in high-performance liquid chromatography--a review.

    Science.gov (United States)

    Pino, Verónica; Afonso, Ana M

    2012-02-10

    Ionic liquids (ILs) are a class of ionic, nonmolecular solvents which remain in liquid state at temperatures below 100°C. ILs possess a variety of properties including low to negligible vapor pressure, high thermal stability, miscibility with water or a variety of organic solvents, and variable viscosity. IL-modified silica as novel high-performance liquid chromatography (HPLC) stationary phases have attracted considerable attention for their differential behavior and low free-silanol activity. Indeed, around 21 surface-confined ionic liquids (SCIL) stationary phases have been developed in the last six years. Their chromatographic behavior has been studied, and, despite the presence of a positive charge on the stationary phase, they showed considerable promise for the separation of neutral solutes (not only basic analytes), when operated in reversed phase mode. This aspect points to the potential for truly multimodal stationary phases. This review attempts to summarize the state-of-the-art about SCIL phases including their preparation, chromatographic behavior, and analytical performance. Copyright © 2011 Elsevier B.V. All rights reserved.

  8. A Surface Formulation for Characteristic Modes of Material Bodies

    Science.gov (United States)

    1974-10-01

    42 CHAPTER 3 4: CHARACTERISTIC MODES - A SURFACE FORMULATION 3.1 Theoretical Development The treatment of characteristic modes for perfectly...cgs* i + y mp ein•£ (A6 V; 1 TP At • CA6 I --- 4 1 o#i ajk(X MPcoeo* + umpsin# ) Iim n p-l1 Tp -Ax sin#i + Ay co* ] i (A-7) A4 APPWOIX II fill I vIal

  9. Dispersion relations of the acoustic modes in divalent liquid metals

    Directory of Open Access Journals (Sweden)

    Inui Masanori

    2017-01-01

    Full Text Available Collective dynamics in liquid Ca and liquid Cd was studied by inelastic x-ray scattering (IXS. Using our experimental technique to prepare proper sample cells and high performance of an IXS beamline (BL35XU at SPring-8 in Japan, the dynamic structure factor with reasonable statistics was obtained for these divalent liquid metals. For both liquids, the dynamic structure factor at low Q exhibits a central peak with a shoulder or small hump clearly visible on each side, and the inelastic excitation energy determined using the model function composed of Lorentzian and the damped harmonic oscillator function disperses with increasing Q. The dispersion curves of these liquids were compared with that of the longitudinal acoustic phonon in each crystalline phase. From these results, clear difference in the interatomic interaction be- tween liquid Ca and liquid Cd was inferred.

  10. Numerical Study on Shape of Liquid Inlet for Venturi Scrubber in Self-Priming Mode

    Energy Technology Data Exchange (ETDEWEB)

    Lee, J. W.; Kim, H. S.; Kim, W. S. [KAERI, Daejeon (Korea, Republic of)

    2016-05-15

    In this study, the simulation was developed for different design of liquid inlet to improve injection in submerged self-priming mode venturi scrubber. 1. A hole type is easy to discharged gas from liquid inlet for submerged self-priming mode. 2. A spit type, the liquid is injected into venturi scrubber for all gas volume rate in submerged self-priming mode. 3. A spit type is better than a hole type on improving injection of liquid inlet for submerged self-priming mode in venturi scrubber.The gas accelerate in convergent segment and reach maximum velocity at throat. The liquid is injected into venturi scrubber depends on static pressure difference between outside and inside of the venturi throat, then liquid is atomized into fine droplet when it contacts with high speed airflow. Aerosol removal occur in the diverging section as the inlet gas stream mixes with the fog of tiny liquid droplets. Many studies dealing with the non-submerged selfpriming venturi scrubber. In a non-submerged condition, outlet nozzle of venturi scrubber is not immersed in water pool of a tank whereas in a submerged condition, the outlet of a venturi scrubber is immersed in water pool. The scrubbing liquid is supplied by water reservoir surrounding the throat and is drawn in due to a pressure difference between the outside and the inside of the venturi throat that arises out of the hydrostatic pressure of the liquid and static pressure of the flowing gas. The performance of a venturi scrubber is improved with high gas velocities and high liquid flow rate. Therefore, it is important to study the liquid fraction in venturi scrubber operated at different condition. The venturi scrubber is used to a submerged self-priming mode because the system operates in a passive mode in CFVS. The present study focuses on the liquid flow characteristics for various shapes of liquid inlet in submerged self-priming venturi scrubber.

  11. Numerical Study on Shape of Liquid Inlet for Venturi Scrubber in Self-Priming Mode

    International Nuclear Information System (INIS)

    Lee, J. W.; Kim, H. S.; Kim, W. S.

    2016-01-01

    In this study, the simulation was developed for different design of liquid inlet to improve injection in submerged self-priming mode venturi scrubber. 1. A hole type is easy to discharged gas from liquid inlet for submerged self-priming mode. 2. A spit type, the liquid is injected into venturi scrubber for all gas volume rate in submerged self-priming mode. 3. A spit type is better than a hole type on improving injection of liquid inlet for submerged self-priming mode in venturi scrubber.The gas accelerate in convergent segment and reach maximum velocity at throat. The liquid is injected into venturi scrubber depends on static pressure difference between outside and inside of the venturi throat, then liquid is atomized into fine droplet when it contacts with high speed airflow. Aerosol removal occur in the diverging section as the inlet gas stream mixes with the fog of tiny liquid droplets. Many studies dealing with the non-submerged selfpriming venturi scrubber. In a non-submerged condition, outlet nozzle of venturi scrubber is not immersed in water pool of a tank whereas in a submerged condition, the outlet of a venturi scrubber is immersed in water pool. The scrubbing liquid is supplied by water reservoir surrounding the throat and is drawn in due to a pressure difference between the outside and the inside of the venturi throat that arises out of the hydrostatic pressure of the liquid and static pressure of the flowing gas. The performance of a venturi scrubber is improved with high gas velocities and high liquid flow rate. Therefore, it is important to study the liquid fraction in venturi scrubber operated at different condition. The venturi scrubber is used to a submerged self-priming mode because the system operates in a passive mode in CFVS. The present study focuses on the liquid flow characteristics for various shapes of liquid inlet in submerged self-priming venturi scrubber.

  12. Single-mode surface plasmon distributed feedback lasers.

    Science.gov (United States)

    Karami Keshmarzi, Elham; Tait, R Niall; Berini, Pierre

    2018-03-29

    Single-mode surface plasmon distributed feedback (DFB) lasers are realized in the near infrared using a two-dimensional non-uniform long-range surface plasmon polariton structure. The surface plasmon mode is excited onto a 20 nm-thick, 1 μm-wide metal stripe (Ag or Au) on a silica substrate, where the stripe is stepped in width periodically, forming a 1st order Bragg grating. Optical gain is provided by optically pumping a 450 nm-thick IR-140 doped PMMA layer as the top cladding, which covers the entire length of the Bragg grating, thus creating a DFB laser. Single-mode lasing peaks of very narrow linewidth were observed for Ag and Au DFBs near 882 nm at room temperature. The narrow linewidths are explained by the low spontaneous emission rate into the surface plasmon lasing mode as well as the high quality factor of the DFB structure. The lasing emission is exclusively TM polarized. Kinks in light-light curves accompanied by spectrum narrowing were observed, from which threshold pump power densities can be clearly identified (0.78 MW cm-2 and 1.04 MW cm-2 for Ag and Au DFB lasers, respectively). The Schawlow-Townes linewidth for our Ag and Au DFB lasers is estimated and very narrow linewidths are predicted for the lasers. The lasers are suitable as inexpensive, recyclable and highly coherent sources of surface plasmons, or for integration with other surface plasmon elements of similar structure.

  13. Ultrasonically triggered ignition at liquid surfaces.

    Science.gov (United States)

    Simon, Lars Hendrik; Meyer, Lennart; Wilkens, Volker; Beyer, Michael

    2015-01-01

    Ultrasound is considered to be an ignition source according to international standards, setting a threshold value of 1mW/mm(2) [1] which is based on theoretical estimations but which lacks experimental verification. Therefore, it is assumed that this threshold includes a large safety margin. At the same time, ultrasound is used in a variety of industrial applications where it can come into contact with explosive atmospheres. However, until now, no explosion accidents have been reported in connection with ultrasound, so it has been unclear if the current threshold value is reasonable. Within this paper, it is shown that focused ultrasound coupled into a liquid can in fact ignite explosive atmospheres if a specific target positioned at a liquid's surface converts the acoustic energy into a hot spot. Based on ignition tests, conditions could be derived that are necessary for an ultrasonically triggered explosion. These conditions show that the current threshold value can be significantly augmented. Copyright © 2014 Elsevier B.V. All rights reserved.

  14. Characterization of the intrinsic density profiles for liquid surfaces

    International Nuclear Information System (INIS)

    Chacon, Enrique; Tarazona, Pedro

    2005-01-01

    This paper presents recent advances in the characterization of the intrinsic structures in computer simulations of liquid surfaces. The use of operational definitions for the intrinsic surface, associated with each molecular configuration of a liquid slab, gives direct access to the intrinsic profile and to the wavevector dependent surface tension. However, the characteristics of these functions depend on the definition used for the intrinsic surface. We discuss the pathologies associated with a local Gibbs dividing surface definition, and consider the alternative definition of a minimal area surface, going though a set of surface pivots, self-consistently chosen to represent the first liquid layer

  15. Liquid surface model for carbon nanotube energetics

    DEFF Research Database (Denmark)

    Solov'yov, Ilia; Mathew, Maneesh; Solov'yov, Andrey V.

    2008-01-01

    an important insight in the energetics and stability of nanotubes of different chirality and might be important for the understanding of nanotube growth process. For the computations we use empirical Brenner and Tersoff potentials and discuss their applicability to the study of carbon nanotubes. From......In the present paper we developed a model for calculating the energy of single-wall carbon nanotubes of arbitrary chirality. This model, which we call as the liquid surface model, predicts the energy of a nanotube with relative error less than 1% once its chirality and the total number of atoms...... the calculated energies we determine the elastic properties of the single-wall carbon nanotubes (Young modulus, curvature constant) and perform a comparison with available experimental measurements and earlier theoretical predictions....

  16. Surface modes of two spheres embedded into a third medium

    International Nuclear Information System (INIS)

    Nkoma, J.S.

    1990-07-01

    Surface modes of two spheres embedded into a third medium are studied. We obtain a result which relates the dependence of frequency on the distance between the two spheres. The derived expression reproduces previous results in the limit where the separation between the spheres is very large. Two surface mode branches are shown to exist for each order n. We apply the theory to three cases of practical interest: first, two similar metallic spheres in vacuum; secondly, two similar metallic spheres embedded into a different metal; thirdly, two spherical voids embedded into a metal. (author). 19 refs, 6 figs

  17. Suppression of an acoustic mode by an elastic mode of a liquid-filled spherical shell resonator.

    Science.gov (United States)

    Lonzaga, Joel B; Raymond, Jason L; Mobley, Joel; Gaitan, D Felipe

    2011-02-01

    The purpose of this paper is to report on the suppression of an approximately radial (radially symmetric) acoustic mode by an elastic mode of a water-filled, spherical shell resonator. The resonator, which has a 1-in. wall thickness and a 9.5-in. outer diameter, was externally driven by a small transducer bolted to the external wall. Experiments showed that for the range of drive frequencies (19.7-20.6 kHz) and sound speeds in water (1520-1570 m/s) considered in this paper, a nonradial (radially nonsymmetric) mode was also excited, in addition to the radial mode. Furthermore, as the sound speed in the liquid was changed, the resonance frequency of the nonradial mode crossed with that of the radial one and the amplitude of the latter was greatly reduced near the crossing point. The crossing of the eigenfrequency curves of these two modes was also predicted theoretically. Further calculations demonstrated that while the radial mode is an acoustic one associated with the interior fluid, the nonradial mode is an elastic one associated with the shell. Thus, the suppression of the radial acoustic mode is apparently caused by the overlapping with the nonradial elastic mode near the crossing point.

  18. Ionic liquids at the surface of graphite: Wettability and structure

    Science.gov (United States)

    Bordes, Emilie; Douce, Laurent; Quitevis, Edward L.; Pádua, Agílio A. H.; Costa Gomes, Margarida

    2018-05-01

    The aim of this work is to provide a better understanding of the interface between graphite and different molecular and ionic liquids. Experimental measurements of the liquid surface tension and of the graphite-liquid contact angle for sixteen ionic liquids and three molecular liquids are reported. These experimental values allowed the calculation of the solid/liquid interfacial energy that varies, for the ionic liquids studied, between 14.5 mN m-1 for 1-ethyl-3-methylimidazolium dicyanamide and 37.8 mN m-1 for 3-dodecyl-1-(naphthalen-1-yl)-1H-imidazol-3-ium tetrafluoroborate. Imidazolium-based ionic liquids with large alkyl side-chains or functionalized with benzyl groups seem to interact more favourably with freshly peeled graphite surfaces. Even if the interfacial energy seems a good descriptor to assess the affinity of a liquid for a carbon-based solid material, we conclude that both the surface tension of the liquid and the contact angle between the liquid and the solid can be significant. Molecular dynamics simulations were used to investigate the ordering of the ions near the graphite surface. We conclude that the presence of large alkyl side-chains in the cations increases the ordering of ions at the graphite surface. Benzyl functional groups in the cations lead to a large affinity towards the graphite surface.

  19. Surface modes at metallic an photonic crystal interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Dai, Weitao [Iowa State Univ., Ames, IA (United States)

    2009-01-01

    A surface mode is an electromagnetic field distribution bounded at a surface. It decays exponentially with the distance from the surface on both sides of the surface and propagates at the surface. The surface mode exists at a metal-dielectric interface as surface plasmon (1) or at a photonic crystal surface terminated properly (34; 35; 36). Besides its prominent near-filed properties, it can connect structures at its propagation surface and results in far-field effects. Extraordinary transmission (EOT) and beaming are two examples and they are the subjects I am studying in this thesis. EOT means the transmission through holes in an opaque screen can be much larger than the geometrical optics limitation. Based on our everyday experience about shadows, the transmission equals the filling ratio of the holes in geometrical optics. The conventional diffraction theory also proved that the transmission through a subwavelength circular hole in an infinitely thin perfect electric conductor (PEC) film converges to zero when the hole's dimension is much smaller than the wavelength (40). Recently it is discovered that the transmission can be much larger than the the filling ratio of the holes at some special wavelengths (41). This cannot be explained by conventional theories, so it is called extraordinary transmission. It is generally believed that surface plasmons play an important role (43; 44) in the EOT through a periodic subwavelength hole array in a metallic film. The common theories in literatures are based on these arguments. The surface plasmons cannot be excited by incident plane waves directly because of momentum mismatch. The periodicity of the hole arrays will provide addition momentum. When the momentum-matching condition of surface plasmons is satisfied, the surface plasmons will be excited. Then these surface plasmons will collect the energy along the input surface and carry them to the holes. So the transmission can be bigger than the filling ratio. Based

  20. Extremely confined gap surface-plasmon modes excited by electrons

    DEFF Research Database (Denmark)

    Raza, Søren; Stenger, Nicolas; Pors, Anders Lambertus

    2014-01-01

    High-spatial and energy resolution electron energy-loss spectroscopy (EELS) can be used for detailed characterization of localized and propagating surface-plasmon excitations in metal nanostructures, giving insight into fundamental physical phenomena and various plasmonic effects. Here, applying...... EELS to ultra-sharp convex grooves in gold, we directly probe extremely confined gap surface-plasmon (GSP) modes excited by swift electrons in nanometre-wide gaps. We reveal the resonance behaviour associated with the excitation of the antisymmetric GSP mode for extremely small gap widths, down to ~5...... mode exploited in plasmonic waveguides with extreme light confinement is a very important factor that should be taken into account in the design of nanoplasmonic circuits and devices....

  1. Laser ablation of liquid surface in air induced by laser irradiation through liquid medium

    Science.gov (United States)

    Utsunomiya, Yuji; Kajiwara, Takashi; Nishiyama, Takashi; Nagayama, Kunihito; Kubota, Shiro; Nakahara, Motonao

    2010-10-01

    The pulse laser ablation of a liquid surface in air when induced by laser irradiation through a liquid medium has been experimentally investigated. A supersonic liquid jet is observed at the liquid-air interface. The liquid surface layer is driven by a plasma plume that is produced by laser ablation at the layer, resulting in a liquid jet. This phenomenon occurs only when an Nd:YAG laser pulse (wavelength: 1064 nm) is focused from the liquid onto air at a low fluence of 20 J/cm2. In this case, as Fresnel’s law shows, the incident and reflected electric fields near the liquid surface layer are superposed constructively. In contrast, when the incident laser is focused from air onto the liquid, a liquid jet is produced only at an extremely high fluence, several times larger than that in the former case. The similarities and differences in the liquid jets and atomization processes are studied for several liquid samples, including water, ethanol, and vacuum oil. The laser ablation of the liquid surface is found to depend on the incident laser energy and laser fluence. A pulse laser light source and high-resolution film are required to observe the detailed structure of a liquid jet.

  2. Initial surface deformations during impact on a liquid pool

    NARCIS (Netherlands)

    Bouwhuis, W.; Hendrix, M.H.W.; van der Meer, Roger M.; Snoeijer, Jacobus Hendrikus

    2015-01-01

    A tiny air bubble can be entrapped at the bottom of a solid sphere that impacts onto a liquid pool. The bubble forms due to the deformation of the liquid surface by a local pressure buildup inside the surrounding gas, as also observed during the impact of a liquid drop on a solid wall. Here, we

  3. Influence of the mode of preparation of the UO3 trioxide on its specific surface

    International Nuclear Information System (INIS)

    Sauteron, J.

    1960-01-01

    As the specific surface of uranium trioxide UO 3 closely depends on the preparation mode and conditions, the authors report and discuss several results obtained on uranium trioxides produced either by precipitation of uranyl nitrate (with oxygenated water, liquid or gaseous ammoniac, and ammonium carbonate), then by calcination at 350 C, or by thermal decomposition of the uranyl nitrate. The authors also studied the influence of calcination temperature of ammonium uranate on the specific surface of the obtained oxide (between 200 and 900 deg.) [fr

  4. Surface- and interface-plasmon modes on small semiconducting spheres

    International Nuclear Information System (INIS)

    Ugarte, D.; Colliex, C.; Trebbia, P.

    1992-01-01

    The study of the electronic properties of small particles is of major interest because of their intriguing physicochemical properties. The very small electron probes available in scanning transmission electron microscopes offer unique capabilities for investigating small particles with subnanometer spatial resolution. The correlation between electron-energy-loss spectra and energy-filtered images is of great help in pinpointing the excitations under study. This paper presents a theoretical and experimental study of collective excitation modes in the bulk and at the interfaces and surfaces of small spherical silicon particles covered with a thin oxide coating. Among other results, our experimental measurements have shown that there exists a surface-mode excitation at 3--4 eV, precisely localized on the external surface of the oxide layer. Classical dielectric theory is used in interpreting these results, by invoking the presence of an ultrathin conductive layer

  5. The formation of liquid bridge in different operating modes of AFM

    Science.gov (United States)

    Wei, Zheng; Sun, Yan; Ding, WenXuan; Wang, ZaiRan

    2016-09-01

    The liquid bridge is one of the principal factors that cause artifacts in ambient-pressure atomic force microscope (AFM) images. Additionally, it is the main component of the adhesion force in ambient conditions. To understand the AFM imaging mechanism and the sample characteristics, it is essential to study the liquid bridge. This study interprets the physical mechanism involved in liquid bridge formation, which is composed of three different physical processes: the squeezing process, capillary condensation, and liquid film flow. We discuss the contributions of these three mechanisms to the volume and the capillary force of the liquid bridge in different AFM operation modes.

  6. Dynamic interactions of Leidenfrost droplets on liquid metal surface

    Science.gov (United States)

    Ding, Yujie; Liu, Jing

    2016-09-01

    Leidenfrost dynamic interaction effects of the isopentane droplets on the surface of heated liquid metal were disclosed. Unlike conventional rigid metal, such conductive and deformable liquid metal surface enables the levitating droplets to demonstrate rather abundant and complex dynamics. The Leidenfrost droplets at different diameters present diverse morphologies and behaviors like rotation and oscillation. Depending on the distance between the evaporating droplets, they attract and repulse each other through the curved surfaces beneath them and their vapor flows. With high boiling point up to 2000 °C, liquid metal offers a unique platform for testing the evaporating properties of a wide variety of liquid even solid.

  7. Guiding, bending, and splitting of coupled defect surface modes in a surface-wave photonic crystal

    Energy Technology Data Exchange (ETDEWEB)

    Gao, Zhen; Gao, Fei [Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore, Singapore 637371 (Singapore); Zhang, Baile, E-mail: blzhang@ntu.edu.sg [Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore, Singapore 637371 (Singapore); Centre for Disruptive Photonic Technologies, Nanyang Technological University, Singapore, Singapore 637371 (Singapore)

    2016-01-25

    We experimentally demonstrate a type of waveguiding mechanism for coupled surface-wave defect modes in a surface-wave photonic crystal. Unlike conventional spoof surface plasmon waveguides, waveguiding of coupled surface-wave defect modes is achieved through weak coupling between tightly localized defect cavities in an otherwise gapped surface-wave photonic crystal, as a classical wave analogue of tight-binding electronic wavefunctions in solid state lattices. Wave patterns associated with the high transmission of coupled defect surface modes are directly mapped with a near-field microwave scanning probe for various structures including a straight waveguide, a sharp corner, and a T-shaped splitter. These results may find use in the design of integrated surface-wave devices with suppressed crosstalk.

  8. Guiding, bending, and splitting of coupled defect surface modes in a surface-wave photonic crystal

    International Nuclear Information System (INIS)

    Gao, Zhen; Gao, Fei; Zhang, Baile

    2016-01-01

    We experimentally demonstrate a type of waveguiding mechanism for coupled surface-wave defect modes in a surface-wave photonic crystal. Unlike conventional spoof surface plasmon waveguides, waveguiding of coupled surface-wave defect modes is achieved through weak coupling between tightly localized defect cavities in an otherwise gapped surface-wave photonic crystal, as a classical wave analogue of tight-binding electronic wavefunctions in solid state lattices. Wave patterns associated with the high transmission of coupled defect surface modes are directly mapped with a near-field microwave scanning probe for various structures including a straight waveguide, a sharp corner, and a T-shaped splitter. These results may find use in the design of integrated surface-wave devices with suppressed crosstalk

  9. Amorphous SiC/c-ZnO-Based Quasi-Lamb Mode Sensor for Liquid Environments

    Directory of Open Access Journals (Sweden)

    Cinzia Caliendo

    2017-05-01

    Full Text Available The propagation of the quasi-Lamb modes along a-SiC/ZnO thin composite plates was modeled and analysed with the aim to design a sensor able to detect the changes in parameters of a liquid environment, such as added mass and viscosity changes. The modes propagation was modeled by numerically solving the system of coupled electro-mechanical field equations in three media. The mode shape, the power flow, the phase velocity, and the electroacoustic coupling efficiency (K2 of the modes were calculated, specifically addressing the design of enhanced-coupling, microwave frequency sensors for applications in probing the solid/liquid interface. Three modes were identified that have predominant longitudinal polarization, high phase velocity, and quite good K2: the fundamental quasi symmetric mode (qS0 and two higher order quasi-longitudinal modes (qL1 and qL2 with a dominantly longitudinal displacement component in one plate side. The velocity and attenuation of these modes were calculated for different liquid viscosities and added mass, and the gravimetric and viscosity sensitivities of both the phase velocity and attenuation were theoretically calculated. The present study highlights the feasibility of the a-SiC/ZnO acoustic waveguides for the development of high-frequency, integrated-circuit compatible electroacoustic devices suitable for working in a liquid environment.

  10. Laser-induced surface modification of metals and alloys in liquid argon medium

    International Nuclear Information System (INIS)

    Kazakevich, V S; Kazakevich, P V; Yaresko, P S; Kamynina, D A

    2016-01-01

    Micro and nanostructuring of metals and alloys surfaces (Ti, Mo, Ni, T30K4) was considered by subnanocosecond laser radiation in stationary and dynamic mode in the liquid argon, ethanol and air. Depending of structures size on the samples surface from the energy density and the number of pulses were built. Non-periodic (NSS) and periodic (PSS) surface structures with periods about λ-λ/2 were obtained. PSS formation took place as at the target surface so at the NSS surface. (paper)

  11. Conjugate gradient filtering of instantaneous normal modes, saddles on the energy landscape, and diffusion in liquids.

    Science.gov (United States)

    Chowdhary, J; Keyes, T

    2002-02-01

    Instantaneous normal modes (INM's) are calculated during a conjugate-gradient (CG) descent of the potential energy landscape, starting from an equilibrium configuration of a liquid or crystal. A small number (approximately equal to 4) of CG steps removes all the Im-omega modes in the crystal and leaves the liquid with diffusive Im-omega which accurately represent the self-diffusion constant D. Conjugate gradient filtering appears to be a promising method, applicable to any system, of obtaining diffusive modes and facilitating INM theory of D. The relation of the CG-step dependent INM quantities to the landscape and its saddles is discussed.

  12. On the Surface Breakup of a Non-turbulent Round Liquid Jet in Cross-flow

    Science.gov (United States)

    Behzad, Mohsen; Ashgriz, Nasser

    2011-11-01

    The atomization of a non-turbulent liquid jet injected into a subsonic cross-flow consists of two parts: (1) primary breakup and (2) secondary breakup. Two distinct regimes for the liquid jet primary breakup have been recognized; the so called column breakup and surface breakup. In the column breakup mode, the entire liquid jet undergoes disintegration into large liquid lumps. Quiet differently in the surface breakup regime, liquid fragments with various sizes and shapes are separated from the surface of the jet. Despite many experimental studies the mechanisms of jet surface breakup is not fully understood. Thus this study aims at providing useful observations regarding the underlying physics involving the surface breakup mechanism of a liquid jet in cross-flow, using detailed numerical simulations. The results show that a two-stage mechanism can be responsible for surface breakup. In the first stage, a sheet-like structure extrudes towards the downstream, and in the second stage it disintegrates into ligaments and droplets due to aerodynamic instability.

  13. Kink modes and surface currents associated with vertical displacement events

    Science.gov (United States)

    Manickam, Janardhan; Boozer, Allen; Gerhardt, Stefan

    2012-08-01

    The fast termination phase of a vertical displacement event (VDE) in a tokamak is modeled as a sequence of shrinking equilibria, where the core current profile remains constant so that the safety-factor at the axis, qaxis, remains fixed and the qedge systematically decreases. At some point, the n = 1 kink mode is destabilized. Kink modes distort the magnetic field lines outside the plasma, and surface currents are required to nullify the normal component of the B-field at the plasma boundary and maintain equilibrium at finite pressure. If the plasma touches a conductor, the current can be transferred to the conductor, and may be measurable by the halo current monitors. This report describes a practical method to model the plasma as it evolves during a VDE, and determine the surface currents, needed to maintain equilibrium. The main results are that the onset conditions for the disruption are that the growth-rate of the n = 1 kink exceeds half the Alfven time and the associated surface current needed to maintain equilibrium exceeds one half of the core plasma current. This occurs when qedge drops below a low integer, usually 2. Application to NSTX provides favorable comparison with non-axisymmetric halo-current measurements. The model is also applied to ITER and shows that the 2/1 mode is projected to be the most likely cause of the final disruption.

  14. X-ray scattering at liquid surfaces and interfaces

    International Nuclear Information System (INIS)

    Daillant, Jean

    2000-01-01

    X-ray and neutron reflectivity techniques have become quite popular for the analysis of surfaces and interfaces over the last ten years. In this review, we discuss the specific aspects of both specular and diffuse x-ray reflectivity at liquid interfaces. We start from a model liquid surface for which the scattering cross-section can be calculated in terms of thermally excited capillary and acoustic waves, and we examine in detail the experimental consequences of the large bulk scattering and of the low q divergence of the surface scattering. Deviations from the simple calculated behaviour point to interesting phenomena which can be studied in detail, like the appearance of a bending stiffness. The method is illustrated through the discussion of representative studies of liquid surfaces, of surfactant monolayers, of liquid-liquid interfaces and of microemulsions. (author)

  15. Surface tension of liquid Al-Cu binary alloys.

    OpenAIRE

    Schmitz, Julianna; Brillo, Jürgen; Egry, Ivan; Schmid-Fetzer, Rainer

    2009-01-01

    Surface tension data of liquid Al–Cu binary alloys have been measured contactlessly using the technique of electromagnetic levitation. A digital CMOS-camera (400 fps) recorded image sequences of the oscillating liquid sample and surface tensions were determined from analysis of the frequency spectra. Measurements were performed for samples covering the entire range of composition and precise data were obtained in a broad temperature range. It was found that the surface tensions can ...

  16. Electronic collective modes and instabilities on semiconductor surfaces. I

    International Nuclear Information System (INIS)

    Muramatsu, A.; Hanke, W.

    1984-01-01

    A Green's-function theory of electronic collective modes is presented which leads to a practical scheme for a microscopic determination of surface elementary excitations in conducting as well as nonconducting solids. Particular emphasis is placed on semiconductor surfaces where the jellium approximation is not valid, due to the importance of density fluctuations on a microscopic scale (reflected in the local-field effects). Starting from the Bethe-Salpeter equation for the two-particle Green's function of the surface system, an equation of motion for the electron-hole pair is obtained. Its solutions determine the energy spectra, lifetimes, and amplitudes of the surface elementary excitations, i.e., surface plasmons, excitons, polaritons, and magnons. Exchange and correlation effects are taken into account through the random-phase and time-dependent Hartree-Fock (screened electron-hole attraction) approximations. The formalism is applied to the study of electronic (charge- and spin-density) instabilities at covalent semiconductor surfaces. Quantitative calculations for an eight-layer Si(111) slab display an instability of the ideal paramagnetic surface with respect to spin-density waves with wavelength nearly corresponding to (2 x 1) and (7 x 7) superstructures

  17. Evaporation of a liquid drop on a hot liquid surface, (1)

    International Nuclear Information System (INIS)

    Iida, Yoshihiro; Takashima, Takeo

    1980-01-01

    As for the phenomena occurring when two kinds of liquid at different temperature come in contact, the clarification of the basic, general matters of the phenomena has not been made yet. Such situation has been caused by the facts that the detailed observation of the aspect in liquid-liquid contact becomes impossible as the disturbance on the interface becomes violent, and it is difficult to obtain the quantitative data and to change temperature difference largely in practice. In this study, liquid drops were dropped on the free surface of another liquid at the temperature higher than the saturation temperature of the dropping liquid, and it was attempted to obtain the basic knowledge concerning the general behavior at the time of liquid-liquid contact by determining the aspect of evaporation and its change and evaporation time. For this experiment, the silicone oil with four different kinematic viscosity was used as the high temperature liquid, and n-pentane and dichloromethane soluble in the mother liquid, and acetone and methyl alcohol insoluble in the mother liquid were used as the liquid drops. The experimental apparatuses and method and the results are reported. The evaporation time curves presented lying S-shape basically, similarly to the evaporation on solid surfaces. The point of maximum evaporation time and the point of maximum heat transfer rate existed. (J.P.N.)

  18. Thermodynamics and structure of liquid surfaces investigated directly with surface analytical tools

    Energy Technology Data Exchange (ETDEWEB)

    Andersson, Gunther [Flinders Univ., Adelaide, SA (Australia). Centre for NanoScale Science and Technology; Morgner, Harald [Leipzig Univ. (Germany). Wilhelm Ostwald Inst. for Physical and Theoretical Chemistry

    2017-06-15

    Measuring directly the composition, the distribution of constituents as function of the depth and the orientation of molecules at liquid surfaces is essential for determining physicochemical properties of liquid surfaces. While the experimental tools that have been developed for analyzing solid surfaces can in principal be applied to liquid surfaces, it turned out that they had to be adjusted to the particular challenges imposed by liquid samples, e.g. by the unavoidable vapor pressure and by the mobility of the constituting atoms/molecules. In the present work it is shown, how electron spectroscopy and ion scattering spectroscopy have been used for analyzing liquid surfaces. The emphasis of this review is on using the structural information gained for determining the physicochemical properties of liquid surfaces. (copyright 2017 by WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  19. Localized surface plate modes via flexural Mie resonances

    KAUST Repository

    Farhat, M.; Chen, P. -Y.; Guenneau, S.; Salama, Khaled N.; Bagci, Hakan

    2017-01-01

    Surface-plasmon polaritons are naturally generated upon excitation of metals with high-frequency electromagnetic waves. However, the concept of spoof plasmons has made it possible to generate plasmoniclike effects in microwave electrodynamics, magnetics, and even acoustics. Similarly, in this paper, the concept of localized surface plate modes (SPMs) is introduced. It is demonstrated that SPMs can be generated on a two-dimensional (clamped or stress-free) cylindrical surface with subwavelength corrugations, which resides on a thin elastic plate, under excitation by an incident flexural plane wave. Numerical characterization of this corrugated rigid structure shows that it is elastically equivalent to a cylindrical scatterer with dispersive but uniformly negative flexural rigidity. This, indeed, suggests that plasmoniclike elastic materials can be engineered with potential applications in various areas including earthquake sensing and elastic imaging and cloaking.

  20. Localized surface plate modes via flexural Mie resonances

    KAUST Repository

    Farhat, M.

    2017-05-11

    Surface-plasmon polaritons are naturally generated upon excitation of metals with high-frequency electromagnetic waves. However, the concept of spoof plasmons has made it possible to generate plasmoniclike effects in microwave electrodynamics, magnetics, and even acoustics. Similarly, in this paper, the concept of localized surface plate modes (SPMs) is introduced. It is demonstrated that SPMs can be generated on a two-dimensional (clamped or stress-free) cylindrical surface with subwavelength corrugations, which resides on a thin elastic plate, under excitation by an incident flexural plane wave. Numerical characterization of this corrugated rigid structure shows that it is elastically equivalent to a cylindrical scatterer with dispersive but uniformly negative flexural rigidity. This, indeed, suggests that plasmoniclike elastic materials can be engineered with potential applications in various areas including earthquake sensing and elastic imaging and cloaking.

  1. Spoof surface plasmon modes on doubly corrugated metal surfaces at terahertz frequencies

    International Nuclear Information System (INIS)

    Liu, Yong-Qiang; Kong, Ling-Bao; Du, Chao-Hai; Liu, Pu-Kun

    2016-01-01

    Spoof surface plasmons (SSPs) have many potential applications such as imaging and sensing, communications, innovative leaky wave antenna and many other passive devices in the microwave and terahertz (THz) spectrum. The extraordinary properties of SSPs (e.g. extremely strong near field, enhanced beam–wave interaction) make them especially attractive for developing novel THz electronic sources. SSP modes on doubly corrugated metal surfaces are investigated and analyzed both theoretically and numerically in this paper. The analytical SSP dispersion expressions of symmetric and anti-symmetric modes are obtained with a simplified modal field expansion method; the results are also verified by the finite integration method. Additionally, the propagation losses are also considered for real copper surfaces with a limited constant conductivity in a THz regime. It is shown that the asymptotical frequency of the symmetric mode at the Brillouin boundary decreases along with the decreased gap size between these two corrugated metal surfaces while the asymptotical frequency increases for the anti-symmetric mode. The anti-symmetric mode demonstrates larger propagation losses than the symmetric mode. Further, the losses for both symmetric and anti-symmetric modes decrease when this gap size enlarges. By decreasing groove depth, the asymptotical frequency increases for both the symmetric and the anti-symmetric mode, but the variation of propagation losses is more complicated. Propagation losses increase along with the increased period. Our studies on the dispersion characteristics and propagation losses of SSP modes on this doubly corrugated metallic structure with various parameters is instructive for numerous applications such as waveguides, circuitry systems with high integration, filters and powerful electronic sources in the THz regime. (paper)

  2. Holographic optical tweezers for object manipulations at an air-liquid surface.

    Science.gov (United States)

    Jesacher, Alexander; Fürhapter, Severin; Maurer, Christian; Bernet, Stefan; Ritsch-Marte, Monika

    2006-06-26

    We investigate holographic optical tweezers manipulating micro-beads at a suspended air-liquid interface. Axial confinement of the particles in the two-dimensional interface is maintained by the interplay between surface tension and gravity. Therefore, optical trapping of the micro-beads is possible even with a long distance air objective. Efficient micro-circulation of the liquid can be induced by fast rotating beads, driven by the orbital angular momentum transfer of incident Laguerre-Gaussian (doughnut) laser modes. Our setup allows various ways of creating a tailored dynamic flow of particles and liquid within the surface. We demonstrate examples of surface manipulations like efficient vortex pumps and mixers, interactive particle flow steering by arrays of vortex pumps, the feasibility of achieving a "clocked" traffic of micro beads, and size-selective guiding of beads along optical "conveyor belts".

  3. Liquid Atomization Induced by Pulse Laser Reflection underneath Liquid Surface

    Science.gov (United States)

    Utsunomiya, Yuji; Kajiwara, Takashi; Nishiyama, Takashi; Nagayama, Kunihito; Kubota, Shiro; Nakahara, Motonao

    2009-05-01

    We observed a novel effect of pulse laser reflection at the interface between transparent materials with different refractive indices. The electric field intensity doubles when a laser beam is completely reflected from a material with a higher refractive index to a material with a lower index. This effect appreciably reduces pulse laser ablation threshold of transparent materials. We performed experiments to observe the entire ablation process for laser incidence on the water-air interface using pulse laser shadowgraphy with high-resolution film; the minimum laser fluence for laser ablation at the water-air interface was approximately 12-16 J/cm2. We confirmed that this laser ablation occurs only when the laser beam is incident on the water-air interface from water. Many slender liquid ligaments extend like a milk crown and seem to be atomized at the tip. Their detailed structures can be resolved only by pulse laser photography using high-resolution film.

  4. Ionic-Liquid-Infused Nanostructures as Repellent Surfaces.

    Science.gov (United States)

    Galvan, Yaraset; Phillips, Katherine R; Haumann, Marco; Wasserscheid, Peter; Zarraga, Ramon; Vogel, Nicolas

    2018-02-02

    In order to prepare lubricant-infused repellent coatings on silica nanostructures using low vapor pressure ionic liquids as lubricants, we study the wetting behavior of a set of imidazolium-based ionic liquids with different alkyl side chains as a function of the applied surface functionalities. We take advantage of the structural color of inverse opals prepared from a colloidal coassembly technique to study the infiltration of ionic liquids into these nanoporous structures. We find that the more hydrophobic ionic liquids with butyl and hexyl side chains can completely infiltrate inverse opals functionalized with mixed self-assembled monolayers composed of imidazole groups and aliphatic hydrocarbon chains, which we introduce via silane chemistry. These molecular species reflect the chemical nature of the ionic liquid, thereby increasing the affinity between the liquid and solid surface. The mixed surface chemistry provides sufficiently small contact angles with the ionic liquid to infiltrate the nanopores while maximizing the contact angle with water. As a result, the mixed monolayers enable the design of a stable ionic liquid/solid interface that is able to repel water as a test liquid. Our results underline the importance of matching chemical affinities to predict and control the wetting behavior in complex, multiphase systems.

  5. Newtonian liquid jet impaction on a high-speed moving surface

    International Nuclear Information System (INIS)

    Keshavarz, B.; Green, S.I.; Davy, M.H.; Eadie, D.T.

    2011-01-01

    Highlights: ► We studied experimentally the interaction of a liquid jet with a moving surface. ► Decreasing the Reynolds number reduced the incidence of splash. ► The Weber number had a much smaller impact on splash than the Reynolds number. ► The jet impingement angle had only a small effect on the splash. ► Increasing the surface roughness substantially decreased the splash threshold. - Abstract: In the railroad industry a friction modifying agent may be applied to the rail or wheel in the form of a liquid jet. In this mode of application the interaction between the high-speed liquid jet and a fast moving surface is important. Seven different Newtonian liquids with widely varying shear viscosities were tested to isolate the effect of viscosity from other fluid properties. Tests were also done on five surfaces of different roughness heights to investigate the effects of surface roughness. High-speed video imaging was employed to scrutinize the interaction between the impacting jet and the moving surface. For all surfaces, decreasing the Reynolds number reduced the incidence of splash and consequently enhanced the transfer efficiency. At the elevated Weber numbers of the testing, the Weber number had a much smaller impact on splash than the Reynolds number. The ratio of the surface velocity to the jet velocity has only a small effect on the splash, whereas increasing the roughness-height-to-jet-diameter ratio substantially decreased the splash threshold.

  6. Screening model for nanowire surface-charge sensors in liquid

    DEFF Research Database (Denmark)

    Sørensen, Martin Hedegård; Mortensen, Asger; Brandbyge, Mads

    2007-01-01

    The conductance change of nanowire field-effect transistors is considered a highly sensitive probe for surface charge. However, Debye screening of relevant physiological liquid environments challenge device performance due to competing screening from the ionic liquid and nanowire charge carriers....

  7. Surface Science at the Solid Liquid Interface

    Science.gov (United States)

    1993-10-06

    prominent experimental avenue, developed originally by Hubbard et al,_ involves emersing monocrystalline elec- As for metal surfaces in ultrahigh vacuum...reliable means of both preparing and dosateizn ordered monocrystalline metal surfaces in UHV has led to ing appropriate molecular components of...surface atoms in place of bottom panel of Fig. 2, equal intensity contours are shown 23 underlying surface atoms, the compression is 24/23 - I in the

  8. Liquid Water may Stick on Hydrophobic Surfaces

    Indian Academy of Sciences (India)

    IAS Admin

    Common Perception. A surface can be classified as. > Wetting. > Non-wetting. Depending on the spreading characteristics of a droplet of water that splashes on the surface. The behavior of fluid on a solid surface under static and dynamic ..... color of the number density profile. Ions at the interface tend to form pinning zones ...

  9. Modified Antifreeze Liquids for Use on Surfaces

    Science.gov (United States)

    Lynn, R. O.

    1983-01-01

    Report presents results of evaluation of two antifreeze liquids, dimethyl sulfoxide and ethylene glycol and five viscosity modifiers: gelatin, gum tragacanth, starch, agarose powder and citrus pectin. Purpose of evaluation to find best way of dealing with frost formation on Space Shuttle.

  10. Surface tension modelling of liquid Cd-Sn-Zn alloys

    Science.gov (United States)

    Fima, Przemyslaw; Novakovic, Rada

    2018-06-01

    The thermodynamic model in conjunction with Butler equation and the geometric models were used for the surface tension calculation of Cd-Sn-Zn liquid alloys. Good agreement was found between the experimental data for limiting binaries and model calculations performed with Butler model. In the case of ternary alloys, the surface tension variation with Cd content is better reproduced in the case of alloys lying on vertical sections defined by high Sn to Zn molar fraction ratio. The calculated surface tension is in relatively good agreement with the available experimental data. In addition, the surface segregation of liquid ternary Cd-Sn-Zn and constituent binaries has also been calculated.

  11. Electromagnetic controllable surfaces based on trapped-mode effect

    Directory of Open Access Journals (Sweden)

    V. Dmitriev

    2012-10-01

    Full Text Available In this paper we present some recent results of our theoretical investigations of electromagnetically controllable surfaces. These surfaces are designed on the basis of periodic arrays made of metallic inclusions of special form which are placed on a thin substrate of active material (magnetized ferrite or optically active semiconductor. The main peculiarity of the studied structures is their capability to support the trapped-mode resonance which is a result of the antiphase current oscillations in the elements of a periodic cell. Several effects, namely: tuning the position of passband and the linear and nonlinear (bistable transmission switching are considered when an external static magnetic field or optical excitation are applied. Our numerical calculations are fulfilled in both microwave and optical regions.

  12. Surface wave propagation in a double liquid layer over a liquid ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    Abstract. The frequency equation is derived for surface waves in a liquid- saturated porous half-space supporting a double layer, that of inhomogeneous and homogeneous liquids. Asymptotic approximations of Bessel functions are used for long and short wavelength cases. Certain other problems are discussed as spe-.

  13. Study of Magnetohydrodynamic Surface Waves on Liquid Gallium

    Energy Technology Data Exchange (ETDEWEB)

    Hantao Ji; William Fox; David Pace; H.L. Rappaport

    2004-05-13

    Magnetohydrodynamic (MHD) surface waves on liquid gallium are studied theoretically and experimentally in the small magnetic Reynolds number limit. A linear dispersion relation is derived when a horizontal magnetic field and a horizontal electric current is imposed. No wave damping is found in the shallow liquid limit while waves always damp in the deep liquid limit with a magnetic field parallel to the propagation direction. When the magnetic field is weak, waves are weakly damped and the real part of the dispersion is unaffected, while in the opposite limit waves are strongly damped with shortened wavelengths. In a table-top experiment, planar MHD surface waves on liquid gallium are studied in detail in the regime of weak magnetic field and deep liquid. A non-invasive diagnostic accurately measures surface waves at multiple locations by reflecting an array of lasers off the surface onto a screen, which is recorded by an Intensified-CCD camera. The measured dispersion relation is consistent with the linear theory with a reduced surface tension likely due to surface oxidation. In excellent agreement with linear theory, it is observed that surface waves are damped only when a horizontal magnetic field is imposed parallel to the propagation direction. No damping is observed under a perpendicular magnetic field. The existence of strong wave damping even without magnetic field suggests the importance of the surface oxide layer. Implications to the liquid metal wall concept in fusion reactors, especially on the wave damping and a Rayleigh-Taylor instability when the Lorentz force is used to support liquid metal layer against gravity, are discussed.

  14. Study of Magnetohydrodynamic Surface Waves on Liquid Gallium

    International Nuclear Information System (INIS)

    Hantao Ji; William Fox; David Pace; Rappaport, H.L.

    2004-01-01

    Magnetohydrodynamic (MHD) surface waves on liquid gallium are studied theoretically and experimentally in the small magnetic Reynolds number limit. A linear dispersion relation is derived when a horizontal magnetic field and a horizontal electric current is imposed. No wave damping is found in the shallow liquid limit while waves always damp in the deep liquid limit with a magnetic field parallel to the propagation direction. When the magnetic field is weak, waves are weakly damped and the real part of the dispersion is unaffected, while in the opposite limit waves are strongly damped with shortened wavelengths. In a table-top experiment, planar MHD surface waves on liquid gallium are studied in detail in the regime of weak magnetic field and deep liquid. A non-invasive diagnostic accurately measures surface waves at multiple locations by reflecting an array of lasers off the surface onto a screen, which is recorded by an Intensified-CCD camera. The measured dispersion relation is consistent with the linear theory with a reduced surface tension likely due to surface oxidation. In excellent agreement with linear theory, it is observed that surface waves are damped only when a horizontal magnetic field is imposed parallel to the propagation direction. No damping is observed under a perpendicular magnetic field. The existence of strong wave damping even without magnetic field suggests the importance of the surface oxide layer. Implications to the liquid metal wall concept in fusion reactors, especially on the wave damping and a Rayleigh-Taylor instability when the Lorentz force is used to support liquid metal layer against gravity, are discussed

  15. Simulation of liquid crystals. Disclinations and surface modification

    International Nuclear Information System (INIS)

    Downton, M.

    2001-01-01

    In this thesis we investigate the behaviour of molecular models liquid crystals in several different situations. Basic introductory material on liquid crystals and computer simulations is discussed in the first two chapters, we then discuss the research. The third chapter investigates the interaction between a liquid crystal and a modified surface. A confined system of hard spherocylinders in a slab geometry is examined. The surface consists of planar hard walls with elongated molecules grafted perpendicularly onto them. The concentration of grafted molecules is varied to give different surfaces. Several different behaviours are found including planar, homeotropic and tilted anchorings of the liquid crystal. Molecular dynamics simulations of a nematic liquid crystal in slab geometry with twisted boundary conditions are performed. By arranging the initial configuration suitably it is possible to create a simulation cell with two regions of opposite twist separated by a strength half disclination line. The properties of the line are examined both with and without an applied external field. Finally, we again examine the system of grafted molecules on a flat substrate using an atomistic model of both the liquid crystal and the surface molecules. Again the effect of varying the density of grafted molecules is found to change the anchoring characteristics of the surface; both homeotropic and planar anchorings are observed. (author)

  16. A magnetically tunable non-Bragg defect mode in a corrugated waveguide filled with liquid crystals

    Science.gov (United States)

    Zhang, Lu; Fan, Ya-Xian; Liu, Huan; Han, Xu; Lu, Wen-Qiang; Tao, Zhi-Yong

    2018-04-01

    A magnetically tunable, non-Bragg defect mode (NBDM) was created in the terahertz frequency range by inserting a defect in the middle of a periodically corrugated waveguide filled with liquid crystals (LCs). In the periodic waveguide, non-Bragg gaps beyond the Bragg ones, which appear in the transmission spectra, are created by different transverse mode resonances. The transmission spectra of the waveguide containing a defect showed that a defect mode was present inside the non-Bragg gap. The NBDM has quite different features compared to the Bragg defect mode, which includes more complex, high-order guided wave modes. In our study, we filled the corrugated waveguide with LCs to realize the tunability of the NBDM. The simulated results showed that the NBDM in a corrugated waveguide filled with LCs can be used in filters, sensors, switches, and other terahertz integrated devices.

  17. Surface structure evolution in a homologous series of ionic liquids.

    Science.gov (United States)

    Haddad, Julia; Pontoni, Diego; Murphy, Bridget M; Festersen, Sven; Runge, Benjamin; Magnussen, Olaf M; Steinrück, Hans-Georg; Reichert, Harald; Ocko, Benjamin M; Deutsch, Moshe

    2018-02-06

    Interfaces of room temperature ionic liquids (RTILs) are important for both applications and basic science and are therefore intensely studied. However, the evolution of their interface structure with the cation's alkyl chain length [Formula: see text] from Coulomb to van der Waals interaction domination has not yet been studied for even a single broad homologous RTIL series. We present here such a study of the liquid-air interface for [Formula: see text], using angstrom-resolution X-ray methods. For [Formula: see text], a typical "simple liquid" monotonic surface-normal electron density profile [Formula: see text] is obtained, like those of water and organic solvents. For [Formula: see text], increasingly more pronounced nanoscale self-segregation of the molecules' charged moieties and apolar chains yields surface layering with alternating regions of headgroups and chains. The layering decays into the bulk over a few, to a few tens, of nanometers. The layering periods and decay lengths, their linear [Formula: see text] dependence, and slopes are discussed within two models, one with partial-chain interdigitation and the other with liquid-like chains. No surface-parallel long-range order is found within the surface layer. For [Formula: see text], a different surface phase is observed above melting. Our results also impact general liquid-phase issues like supramolecular self-aggregation and bulk-surface structure relations.

  18. Bubble entrapment during sphere impact onto quiescent liquid surfaces

    KAUST Repository

    Marston, Jeremy

    2011-06-20

    We report observations of air bubble entrapment when a solid sphere impacts a quiescent liquid surface. Using high-speed imaging, we show that a small amount of air is entrapped at the bottom tip of the impacting sphere. This phenomenon is examined across a broad range of impact Reynolds numbers, 0.2 a Re = (DU0/Il) a 1.2\\' 105. Initially, a thin air pocket is formed due to the lubrication pressure in the air layer between the sphere and the liquid surface. As the liquid surface deforms, the liquid contacts the sphere at a finite radius, producing a thin sheet of air which usually contracts to a nearly hemispherical bubble at the bottom tip of the sphere depending on the impact parameters and liquid properties. When a bubble is formed, the final bubble size increases slightly with the sphere diameter, decreases with impact speed but appears independent of liquid viscosity. In contrast, for the largest viscosities tested herein, the entrapped air remains in the form of a sheet, which subsequently deforms upon close approach to the base of the tank. The initial contact diameter is found to conform to scalings based on the gas Reynolds number whilst the initial thickness of the air pocket or adimplea scales with a Stokes\\' number incorporating the influence of the air viscosity, sphere diameter and impact speed and liquid density. © 2011 Cambridge University Press.

  19. Surface phonon modes of the NaI(001) crystal surface by inelastic He atom scattering

    International Nuclear Information System (INIS)

    Brug, W.P.; Chern, G.; Duan, J.; Safron, S.A.; Skofronick, J.G.; Benedek, G.

    1990-01-01

    The present theoretical treatment of the surface dynamics of ionic insulators employs the shell model with parameters obtained from bulk materials. The approach has been generally very successful in comparisons with experiment. However, most of the experimental surface dynamics work has been on the low-mass alkali halides with very little effort on higher energy modes or on the heavier alkali halides, where effects from relaxation might be important. The work of this paper explores these latter two conditions. Inelastic scattering of He atoms from the left-angle 110 right-angle NaI(001) surface has been used to obtain the acoustic S 1 Rayleigh mode, the S 6 longitudinal mode, and the S 8 crossing mode, however, no gap S 4 optical mode was seen. The results compare favorably with reported theoretical models employing both slab calculations and the Green's function method thus indicating that bulk parameters and the shell model go a long way in explaining most of the observations

  20. Monolithic optofluidic mode coupler for broadband thermo- and piezo-optical characterization of liquids.

    Science.gov (United States)

    Pumpe, Sebastian; Chemnitz, Mario; Kobelke, Jens; Schmidt, Markus A

    2017-09-18

    We present a monolithic fiber device that enables investigation of the thermo- and piezo-optical properties of liquids using straightforward broadband transmission measurements. The device is a directional mode coupler consisting of a multi-mode liquid core and a single-mode glass core with pronounced coupling resonances whose wavelength strongly depend on the operation temperature. We demonstrated the functionality and flexibility of our device for carbon disulfide, extending the current knowledge of the thermo-optic coefficient by 200 nm at 20 °C and uniquely for high temperatures. Moreover, our device allows measuring the piezo-optic coefficient of carbon disulfide, confirming results first obtained by Röntgen in 1891. Finally, we applied our approach to obtain the dispersion of the thermo-optic coefficients of benzene and tetrachloroethylene between 450 and 800 nm, whereas no data was available for the latter so far.

  1. Surface flute modes in the bumpy magnetic field

    International Nuclear Information System (INIS)

    Girka, I.O.; Girka, V.O.; Lapshin, V.I.

    2005-01-01

    Surface electromagnetic waves are often determined as the most possible cause of undesirable heating of edge plasma that leads, in turn, to strengthening of plasma - wall interaction in stellarators and increased plasma contamination. The propagation of surface flute modes near the interface of plasma column separated by a vacuum layer from the ring cylindrical ideally conductive metallic chamber is studied. The external steady bumpy magnetic field B-vector 0 = B 0z e-vector z + B 0r e-vector r was considered, B 0z =B 00 [1+ε m (r)cos(k m z)], here ε m '≡dε m /dr, k m =2π/L, L is the period of nonuniformity. non-uniformity of B-vector 0 is planned to be dominant in the confining magnetic field of the modular stellarator Helias, ε m ∼ 0.13. In the bumpy magnetic field the electromagnetic disturbance propagates in the form of the wave envelope, in which one alongside with the fundamental harmonic, proportional to exp[i(mθ±-ωt)], infinite set of satellite spatial harmonics, proportional to exp[i(mθ ± jk m z - ωt)], j=1,2,3..., is present. It is shown, that in the first approximation in the respect to ε m , amplitudes of the fundamental harmonics of the E-wave with the field components E r , E θ , B z do not vary, small satellite harmonics of these fields arise, proportional to exp[i(mθ ± k m z - ωt)]. At the same time due to weak coupling of - and - modes, caused by B-vector 0 nonuniformity and nonzero axial wave number of satellite harmonics, small satellite harmonics of H-wave with the field components E z , B r , B θ also arise. The amplitudes of satellite harmonics of E-wave are shown to be symmetric: E r (+) =E r (-) , E θ (+) =E θ (-) , B z (+) =B z (-) , and the amplitudes of H-wave are antisymmetric: B r (+) =-B r (-) , B θ (+) =- B θ (-) , E z (+) =-E z (-) . In the second approximation in the respect to ε m corrections to the amplitudes of the fundamental harmonic of E-wave arise. The correction to the eigen frequency of the wave

  2. Characterisation of tissue factor-bearing extracellular vesicles with AFM: comparison of air-tapping-mode AFM and liquid Peak Force AFM

    Directory of Open Access Journals (Sweden)

    Julie Hardij

    2013-08-01

    Full Text Available Introduction: Extracellular vesicles (EVs are shed from cells and carry markers of the parent cells. Vesicles derived from cancer cells reach the bloodstream and locally influence important physiological processes. It has been previously shown that procoagulant vesicles are circulating in patients’ fluids. These EVs are therefore considered as promising biomarkers for the thrombotic risk. Because of their small size, classical methods such as flow cytometry suffer from limitation for their characterisation. Atomic force microscopy (AFM has been proposed as a promising complementary method for the characterisation of EVs. Objectives: The objectives of this study are: (a to develop and validate AFM with specific antibodies (anti-TF and (b to compare air and liquid modes for EVs’ size and number determination as potential biomarkers of the prothrombotic risk. Methods: AFM multimode nanoscope III was used for air tapping mode (TM. AFM catalyst was used for liquid Peak Force Tapping (PFT mode. Vesicles are generated according to Davila et al.'s protocol. Substrates are coated with various concentrations of antibodies, thanks to ethanolamine and glutaraldehyde. Results: Vesicles were immobilised on antibody-coated surfaces to select tissue factor (TF-positive vesicles. The size range of vesicles observed in liquid PFT mode is 6–10 times higher than in air mode. This corresponds to the data found in the literature. Conclusion: We recommend liquid PFT mode to analyse vesicles on 5 µg/ml antibody-coated substrates.

  3. Determination of Surface Properties of Liquid Transition Metals

    International Nuclear Information System (INIS)

    Korkmaz, S. D.

    2008-01-01

    Certain surface properties of liquid simple metals are reported. Using the expression derived by Gosh and coworkers we investigated the surface entropy of liquid transition metals namely Fe, Co and Ni. We have also computed surface tensions of the metals concerned. The pair distribution functions are calculated from the solution of Ornstein-Zernike integral equation with Rogers-Young closure using the individual version of the electron-ion potential proposed by Fioalhais and coworkers which was originally developed for solid state. The predicted values of surface tension and surface entropy are in very good agreement with available experimental data. The present study results show that the expression derived by Gosh and coworkers is very useful for the surface entropy by using Fioalhais pseudopotential and Rogers-Young closure

  4. An Analysis of Fundamental Mode Surface Wave Amplitude Measurements

    Science.gov (United States)

    Schardong, L.; Ferreira, A. M.; van Heijst, H. J.; Ritsema, J.

    2014-12-01

    Seismic tomography is a powerful tool to decipher the Earth's interior structure at various scales. Traveltimes of seismic waves are widely used to build velocity models, whereas amplitudes are still only seldomly accounted for. This mainly results from our limited ability to separate the various physical effects responsible for observed amplitude variations, such as focussing/defocussing, scattering and source effects. We present new measurements from 50 global earthquakes of fundamental-mode Rayleigh and Love wave amplitude anomalies measured in the period range 35-275 seconds using two different schemes: (i) a standard time-domain amplitude power ratio technique; and (ii) a mode-branch stripping scheme. For minor-arc data, we observe amplitude anomalies with respect to PREM in the range of 0-4, for which the two measurement techniques show a very good overall agreement. We present here a statistical analysis and comparison of these datasets, as well as comparisons with theoretical calculations for a variety of 3-D Earth models. We assess the geographical coherency of the measurements, and investigate the impact of source, path and receiver effects on surface wave amplitudes, as well as their variations with frequency in a wider range than previously studied.

  5. Asymmetric excitation of surface plasmons by dark mode coupling

    KAUST Repository

    Zhang, X.

    2016-02-19

    Control over surface plasmons (SPs) is essential in a variety of cutting-edge applications, such as highly integrated photonic signal processing systems, deep-subwavelength lasing, high-resolution imaging, and ultrasensitive biomedical detection. Recently, asymmetric excitation of SPs has attracted enormous interest. In free space, the analog of electromagnetically induced transparency (EIT) in metamaterials has been widely investigated to uniquely manipulate the electromagnetic waves. In the near field, we show that the dark mode coupling mechanism of the classical EIT effect enables an exotic and straightforward excitation of SPs in a metasurface system. This leads to not only resonant excitation of asymmetric SPs but also controllable exotic SP focusing by the use of the Huygens-Fresnel principle. Our experimental findings manifest the potential of developing plasmonic metadevices with unique functionalities.

  6. Asymmetric excitation of surface plasmons by dark mode coupling

    KAUST Repository

    Zhang, X.; Xu, Q.; Li, Q.; Xu, Y.; Gu, J.; Tian, Z.; Ouyang, C.; Liu, Y.; Zhang, S.; Zhang, Xixiang; Han, J.; Zhang, W.

    2016-01-01

    Control over surface plasmons (SPs) is essential in a variety of cutting-edge applications, such as highly integrated photonic signal processing systems, deep-subwavelength lasing, high-resolution imaging, and ultrasensitive biomedical detection. Recently, asymmetric excitation of SPs has attracted enormous interest. In free space, the analog of electromagnetically induced transparency (EIT) in metamaterials has been widely investigated to uniquely manipulate the electromagnetic waves. In the near field, we show that the dark mode coupling mechanism of the classical EIT effect enables an exotic and straightforward excitation of SPs in a metasurface system. This leads to not only resonant excitation of asymmetric SPs but also controllable exotic SP focusing by the use of the Huygens-Fresnel principle. Our experimental findings manifest the potential of developing plasmonic metadevices with unique functionalities.

  7. Identification of dominant flow structures in rapidly rotating convection of liquid metals using Dynamic Mode Decomposition

    Science.gov (United States)

    Horn, S.; Schmid, P. J.; Aurnou, J. M.

    2016-12-01

    The Earth's metal core acts as a dynamo whose efficiency in generating and maintaining the magnetic field is essentially determined by the rotation rate and the convective motions occurring in its outer liquid part. For the description of the primary physics in the outer core the idealized system of rotating Rayleigh-Bénard convection is often invoked, with the majority of studies considering only working fluids with Prandtl numbers of Pr ≳ 1. However, liquid metals are characterized by distinctly smaller Prandtl numbers which in turn result in an inherently different type of convection. Here, we will present results from direct numerical simulations of rapidly rotating convection in a fluid with Pr ≈ 0.025 in cylindrical containers and Ekman numbers as low as 5 × 10-6. In this system, the Coriolis force is the source of two types of inertial modes, the so-called wall modes, that also exist at moderate Prandtl numbers, and cylinder-filling oscillatory modes, that are a unique feature of small Prandtl number convection. The obtained flow fields were analyzed using the Dynamic Mode Decomposition (DMD). This technique allows to extract and identify the structures that govern the dynamics of the system as well as their corresponding frequencies. We have investigated both the regime where the flow is purely oscillatory and the regime where wall modes and oscillatory modes co-exist. In the purely oscillatory regime, high and low frequency oscillatory modes characterize the flow. When both types of modes are present, the DMD reveals that the wall-attached modes dominate the flow dynamics. They precess with a relatively low frequency in retrograde direction. Nonetheless, also in this case, high frequency oscillations have a significant contribution.

  8. Surface tension confined liquid cryogen cooler

    Science.gov (United States)

    Castles, Stephen H. (Inventor); Schein, Michael E. (Inventor)

    1989-01-01

    A cryogenic cooler is provided for use in craft such as launch, orbital, and space vehicles subject to substantial vibration, changes in orientation, and weightlessness. The cooler contains a small pore, large free volume, low density material to restrain a cryogen through surface tension effects during launch and zero-g operations and maintains instrumentation within the temperature range of 10 to 140 K. The cooler operation is completely passive, with no inherent vibration or power requirements.

  9. Transport Powder and Liquid Samples by Surface Acoustic Waves

    Science.gov (United States)

    Bao, Xiaoqi; Bar-Cohen, Yoseph; Sherrit, Stewart; Badescu, Mircea; Louyeh, Sahar

    2009-01-01

    Sample transport is an important requirement for In-situ analysis of samples in NASA planetary exploration missions. Tests have shown that powders or liquid drops on a surface can be transported by surface acoustic waves (SAW) that are generated on the surface using interdigital transducers. The phenomena were investigated experimentally and to generate SAWs interdigital electrodes were deposited on wafers of 128 deg rotated Y-cut LiNbO?. Transporting capability of the SAW device was tested using particles of various sizes and drops of various viscosities liquids. Because of different interaction mechanisms with the SAWs, the powders and the liquid drops were observed to move in opposite directions. In the preliminary tests, a speed of 180 mm/s was achieved for powder transportation. The detailed experimental setup and results are presented in this paper. The transporting mechanism can potentially be applied to miniaturize sample analysis system or " lab-on-chip" devices.

  10. Failure mode and effects analysis applied to the administration of liquid medication by oral syringes

    Directory of Open Access Journals (Sweden)

    Eva María Guerra-Alia

    2017-11-01

    Full Text Available To carry out a Failure Mode and Effects Analysis (FMEA to the use of oral syringes. Methods: A multidisciplinary team was assembled within the Safety Committee. The stages of oral administration process of liquid medication were analysed, identifying the most critical and establishing the potential modes of failure that can cause errors. The impact associated with each mode of failure was calculated using the Risk Priority Number (RPN. Preventive actions were proposed. Results: Five failure modes were identified, all classified as high risk (RPN> 100. Seven of the eight preventive actions were implemented. Conclusions: The FMEA methodology was a useful tool. It has allowed to know the risks, analyse the causes that cause them, their effects on patient safety and the measures to reduce them

  11. Competitive excitation and osmotic-pressure-mediated control of lasing modes in cholesteric liquid crystal microshells

    Science.gov (United States)

    Lin, Ya-Li; Gong, Ling-Li; Che, Kai-Jun; Li, Sen-Sen; Chu, Cheng-Xu; Cai, Zhi-Ping; Yang, Chaoyong James; Chen, Lu-Jian

    2017-05-01

    We examined the end-pumped lasing behaviors of dye doped cholesteric liquid crystal (DDCLC) microshells which were fabricated by glass capillary microfluidics. Several kinds of mode resonances, including distributed feedback, Fabry-Pérot (FP), and whispering gallery (WG) modes, can be robustly constructed in each individual DDCLC microshell by varying the beam diameter, namely, tuning the DDCLC gain area. The FP and WG modes were further confirmed experimentally, and the corresponding lasing mechanisms are clearly revealed from the unique material characteristics of DDCLC and the geometrical structure of the microshell. Additionally, we demonstrated that the osmotic pressure can be used to shrink/expand the microshell, productively tuning the excitation of lasing modes in a controlled manner. We wish our findings can provide a new insight into the design of DDCLC microlasers with tunable optical properties.

  12. Evaporation and condensation at a liquid methanol surface

    Science.gov (United States)

    Matsumoto, Mitsuhiro; Yasuoka, Kenji; Kataoka, Yosuke

    1994-07-01

    The dynamics of evaporation and condensation at a flat liquid surface of methanol were studied under the liquidvapor equilibrium condition at room temperature with molecular dynamics computer simulation techniques. Analysis of molecular trajectories shows that the condensation coefficient is 89%. It suggests that only a tenth of incident vapor molecules are reflected at the liquid surface, contrary to a prediction of a classical transition state theory. To investigate the potential barrier of the evaporation-condensation process, a particle insertion method was applied and the local chemical potential near the surface was evaluated. The calculated chemical potential is constant in the whole region including the surface layer and no potential barrier is observed in the vincinity of the surface, which casts strong doubt on the explanation of a transition state theory.

  13. AFM fluid delivery/liquid extraction surface sampling/electrostatic spray cantilever probe

    Science.gov (United States)

    Van Berkel, Gary J.

    2015-06-23

    An electrospray system comprises a liquid extraction surface sampling probe. The probe comprises a probe body having a liquid inlet and a liquid outlet, and having a liquid extraction tip. A solvent delivery conduit is provided for receiving solvent liquid from the liquid inlet and delivering the solvent liquid to the liquid extraction tip. An open liquid extraction channel extends across an exterior surface of the probe body from the liquid extraction tip to the liquid outlet. An electrospray emitter tip is in liquid communication with the liquid outlet of the liquid extraction surface sampling probe. A system for analyzing samples, a liquid junction surface sampling system, and a method of analyzing samples are also disclosed.

  14. Terahertz particle-in-liquid sensing with spoof surface plasmon polariton waveguides

    Directory of Open Access Journals (Sweden)

    Zhijie Ma

    2017-11-01

    Full Text Available We present a highly sensitive microfluidic sensing technique for the terahertz (THz region of the electromagnetic spectrum based on spoof surface plasmon polaritons (SPPs. By integrating a microfluidic channel in a spoof SPP waveguide, we take advantage of these highly confined electromagnetic modes to create a platform for dielectric sensing of liquids. Our design consists of a domino waveguide, that is, a series of periodically arranged rectangular metal blocks on top of a metal surface that supports the propagation of spoof SPPs. Through numerical simulations, we demonstrate that the transmission of spoof SPPs along the waveguide is extremely sensitive to the refractive index of a liquid flowing through a microfluidic channel crossing the waveguide to give an interaction volume on the nanoliter scale. Furthermore, by taking advantage of the insensitivity of the domino waveguide’s fundamental spoof SPP mode to the lateral width of the metal blocks, we design a tapered waveguide able to achieve further confinement of the electromagnetic field. Using this approach, we demonstrate the highly sensitive detection of individual subwavelength micro-particles flowing in the liquid. These results are promising for the creation of spoof SPP based THz lab-on-a-chip microfluidic devices that are suitable for the analysis of biological liquids such as proteins and circulating tumour cells in buffer solution.

  15. Few-mode vertical-cavity surface-emitting laser: Optional emission of transverse modes with different polarizations

    Science.gov (United States)

    Zhong, Chuyu; Zhang, Xing; Hofmann, Werner; Yu, Lijuan; Liu, Jianguo; Ning, Yongqiang; Wang, Lijun

    2018-05-01

    Few-mode vertical-cavity surface-emitting lasers that can be controlled to emit certain modes and polarization states simply by changing the biased contacts are proposed and fabricated. By directly etching trenches in the p-doped distributed Bragg reflector, the upper mesa is separated into several submesas above the oxide layer. Individual contacts are then deposited. Each contact is used to control certain transverse modes with different polarization directions emitted from the corresponding submesa. These new devices can be seen as a prototype of compact laser sources in mode division multiplexing communications systems.

  16. Solid surface vs. liquid surface: nanoarchitectonics, molecular machines, and DNA origami.

    Science.gov (United States)

    Ariga, Katsuhiko; Mori, Taizo; Nakanishi, Waka; Hill, Jonathan P

    2017-09-13

    The investigation of molecules and materials at interfaces is critical for the accumulation of new scientific insights and technological advances in the chemical and physical sciences. Immobilization on solid surfaces permits the investigation of different properties of functional molecules or materials with high sensitivity and high spatial resolution. Liquid surfaces also present important media for physicochemical innovation and insight based on their great flexibility and dynamicity, rapid diffusion of molecular components for mixing and rearrangements, as well as drastic spatial variation in the prevailing dielectric environment. Therefore, a comparative discussion of the relative merits of the properties of materials when positioned at solid or liquid surfaces would be informative regarding present-to-future developments of surface-based technologies. In this perspective article, recent research examples of nanoarchitectonics, molecular machines, DNA nanotechnology, and DNA origami are compared with respect to the type of surface used, i.e. solid surfaces vs. liquid surfaces, for future perspectives of interfacial physics and chemistry.

  17. Pulse mode actuation-readout system based on MEMS resonator for liquid sensing

    DEFF Research Database (Denmark)

    Tang, Meng; Cagliani, Alberto; Davis, Zachary James

    2014-01-01

    A MEMS (Micro-Electro-Mechanical Systems) bulk disk resonator is applied for mass sensing under its dynamic mode. The classical readout circuitry involves sophisticated feedback loop and feedthrough compensation. We propose a simple straightforward non-loop pulse mode actuation and capacitive...... readout scheme. In order to verify its feasibility in liquid bio-chemical sensing environment, an experimental measurement is conducted with humidity sensing application. The measured resonant frequency changes 60kHz of 67.7MHz with a humidity change of 0~80%....

  18. Liquid Lithium Limiter Effects on Tokamak Plasmas and Plasma-Liquid Surface Interactions

    Energy Technology Data Exchange (ETDEWEB)

    R. Kaita; R. Majeski; R. Doerner; G. Antar; M. Baldwin; R. Conn; P. Efthimion; M. Finkenthal; D. Hoffman; B. Jones; S. Krashenninikov; H. Kugel; S. Luckhardt; R. Maingi; J. Menard; T. Munsat; D. Stutman; G. Taylor; J. Timberlake; V. Soukhanovskii; D. Whyte; R. Woolley; L. Zakharov

    2002-10-15

    We present results from the first experiments with a large area liquid lithium limiter in a magnetic fusion device, and its effect on improving plasma performance by reducing particle recycling. Using large area liquid metal surfaces in any major fusion device is unlikely before a test on a smaller scale. This has motivated its demonstration in the CDX-U spherical torus with a unique, fully toroidal lithium limiter. The highest current discharges were obtained with a liquid lithium limiter. There was a reduction in recycling, as indicated by a significant decrease in the deuterium-alpha emission and oxygen radiation. How these results might extrapolate to reactors is suggested in recycling/retention experiments with liquid lithium surfaces under high-flux deuterium and helium plasma bombardment in PISCES-B. Data on deuterium atoms retained in liquid lithium indicate retention of all incident ions until full volumetric conversion to lithium deuteride. The PISCES-B results also show a material loss mechanism that lowers the maximum operating temperature compared to that for the liquid surface equilibrium vapor pressure. This may restrict the lithium temperature in reactors.

  19. Liquid Lithium Limiter Effects on Tokamak Plasmas and Plasma-Liquid Surface Interactions

    International Nuclear Information System (INIS)

    Kaita, R.; Majeski, R.; Doerner, R.; Antar, G.; Baldwin, M.; Conn, R.; Efthimion, P.; Finkenthal, M.; Hoffman, D.; Jones, B.; Krashenninikov, S.; Kugel, H.; Luckhardt, S.; Maingi, R.; Menard, J.; Munsat, T.; Stutman, D.; Taylor, G.; Timberlake, J.; Soukhanovskii, V.; Whyte, D.; Woolley, R.; Zakharov, L.

    2002-01-01

    We present results from the first experiments with a large area liquid lithium limiter in a magnetic fusion device, and its effect on improving plasma performance by reducing particle recycling. Using large area liquid metal surfaces in any major fusion device is unlikely before a test on a smaller scale. This has motivated its demonstration in the CDX-U spherical torus with a unique, fully toroidal lithium limiter. The highest current discharges were obtained with a liquid lithium limiter. There was a reduction in recycling, as indicated by a significant decrease in the deuterium-alpha emission and oxygen radiation. How these results might extrapolate to reactors is suggested in recycling/retention experiments with liquid lithium surfaces under high-flux deuterium and helium plasma bombardment in PISCES-B. Data on deuterium atoms retained in liquid lithium indicate retention of all incident ions until full volumetric conversion to lithium deuteride. The PISCES-B results also show a material loss mechanism that lowers the maximum operating temperature compared to that for the liquid surface equilibrium vapor pressure. This may restrict the lithium temperature in reactors

  20. Liquid lithium limiter effects on tokamak plasmas and plasma-liquid surface interactions

    International Nuclear Information System (INIS)

    Kaita, R.; Majeski, R.; Doerner, R.

    2003-01-01

    We present results from the first experiments with a large area liquid lithium limiter in a magnetic fusion device, and its effect on improving plasma performance by reducing particle recycling. Using large area liquid metal surfaces in any major fusion device is unlikely before a test on a smaller scale. This has motivated its demonstration in the CDX-U spherical torus with a unique, fully toroidal lithium limiter. The highest current discharges were obtained with a liquid lithium limiter. There was a reduction in recycling, as indicated by a significant decrease in the deuterium-alpha emission and oxygen radiation. How these results might extrapolate to reactors is suggested in recycling/retention experiments with liquid lithium surfaces under high-flux deuterium and helium plasma bombardment in PISCES-B. Data on deuterium atoms retained in liquid lithium indicate retention of all incident ions until full volumetric conversion to lithium deuteride. The PISCES-B results also show a material loss mechanism that lowers the maximum operating temperature compared to that for the liquid surface equilibrium vapor pressure. This may restrict the lithium temperature in reactors. (author)

  1. Reaction of water vapor with a clean liquid uranium surface

    International Nuclear Information System (INIS)

    Siekhaus, W.

    1985-01-01

    To study the reaction of water vapor with uranium, we have exposed clean liquid uranium surfaces to H 2 O under UHV conditions. We have measured the surface concentration of oxygen as a function of exposure, and determined the maximum attainable surface oxygen concentration X 0 /sup s/ as a function of temperature. We have used these measurements to estimate, close to the melting point, the solubility of oxygen (X 0 /sup b/, -4 ) and its surface segregation coefficient β/sup s/(> 10 3 ). 8 refs., 5 figs., 1 tab

  2. Liquid nitrogen cryotherapy for surface eye disease (an AOS thesis).

    Science.gov (United States)

    Fraunfelder, Frederick Web

    2008-01-01

    To evaluate the effects of new treatments with liquid nitrogen cryotherapy on some external eye conditions. In this retrospective case study, 6 separate series from a single tertiary care referral center practice are described. Liquid nitrogen cryotherapy was used to treat conjunctival amyloidosis, primary pterygia, recurrent pterygia, advancing wavelike epitheliopathy (AWLE), superior limbic keratoconjunctivitis (SLK), and palpebral vernal keratoconjunctivitis (VKC). The main outcome measure was the resolution of the disease process after treatment. Four patients with primary localized conjunctival amyloidosis were treated with liquid nitrogen cryotherapy. Two of them had recurrence of the amyloidosis, which cleared with subsequent treatment. Eighteen patients with primary pterygia had excision and cryotherapy with 1 recurrence. Of 6 subjects who presented with recurrent pterygia, 4 had a second recurrence after excision and cryotherapy. In 5 patients with AWLE, the condition resolved within 2 weeks without recurrence or the need for subsequent cryotherapy. Four patients with SLK were treated with liquid nitrogen cryotherapy. Disease recurred in 2 patients and 3 of 7 eyes, although subsequent cryotherapy eradicated SLK in all cases. Two patients and 3 eyelids with palpebral VKC were treated with liquid nitrogen cryotherapy. VKC recurred in all cases. Liquid nitrogen cryotherapy to the surface of the eye is effective in treating AWLE, and SLK. Excision followed by cryotherapy is successful in treating conjunctival amyloidosis and primary pterygia Liquid nitrogen cryotherapy is unsuccessful in the treatment of recurrent pterygia and VKC.

  3. Domain Structures in Nematic Liquid Crystals on a Polycarbonate Surface

    Directory of Open Access Journals (Sweden)

    Vasily F. Shabanov

    2013-08-01

    Full Text Available Alignment of nematic liquid crystals on polycarbonate films obtained with the use of solvents with different solvations is studied. Domain structures occurring during the growth on the polymer surface against the background of the initial thread-like or schlieren texture are demonstrated. It is established by optical methods that the domains are stable formations visualizing the polymer surface structures. In nematic droplets, the temperature-induced transition from the domain structure with two extinction bands to the structure with four bands is observed. This transition is shown to be caused by reorientation of the nematic director in the liquid crystal volume from the planar alignment to the homeotropic state with the pronounced radial configuration of nematic molecules on the surface. The observed textures are compared with different combinations of the volume LC orientations and the radial distribution of the director field and the disclination lines at the polycarbonate surface.

  4. On the stability of an evaporating liquid surface

    International Nuclear Information System (INIS)

    Krahl, R; Bänsch, E

    2012-01-01

    The stability of the interface between a volatile liquid and a gaseous phase has been studied in this paper. We consider the case when the liquid volume is not a film and thus the thin-film approximation might not be valid. A linear stability analysis leads to the Orr–Sommerfeld equation for the stream function and a second-order differential equation for the temperature. This system is solved semi-analytically. A parameter study shows that surface tension is stabilizing, while viscosity is destabilizing the liquid surface. The capillary number is identified as the most significant factor. The analytical results were compared with the growth of an initial perturbation for the full system by direct numerical simulations, and excellent agreement was observed. (paper)

  5. Surface dynamics and mechanics in liquid crystal polymer coatings

    NARCIS (Netherlands)

    Liu, D.; Broer, D.J.; Chien, L.-C.; Coles, H.J.; Kikuchi, H.; Smalyukh, I.I.

    2015-01-01

    Based on liquid crystal networks we developed 'smart' coatings with responsive surface topographies. Either by prepatterning or by the formation of self-organized structures they can be switched on and off in a pre-designed manner. Here we provide an overview of our methods to generate coatings that

  6. Surface effects on the propagation of sound in Fermi liquids

    International Nuclear Information System (INIS)

    Nagai, K.; Woelfle, P.

    1981-01-01

    The propagation of sound in a resonator is discussed in both the normal and superfluid Fermi liquids. A set of model hydrodynamic equations is developed for describing the transition from the hydrodynamic regime to the collisionless regime. Surface effects are incorporated by using a slip boundary condition. The resonance condition for the sound propagation in a cylindrical resonator is derived

  7. Silicon surface barrier detectors used for liquid hydrogen density measurement

    Science.gov (United States)

    James, D. T.; Milam, J. K.; Winslett, H. B.

    1968-01-01

    Multichannel system employing a radioisotope radiation source, strontium-90, radiation detector, and a silicon surface barrier detector, measures the local density of liquid hydrogen at various levels in a storage tank. The instrument contains electronic equipment for collecting the density information, and a data handling system for processing this information.

  8. Bubble entrapment during sphere impact onto quiescent liquid surfaces

    KAUST Repository

    Marston, Jeremy; Vakarelski, Ivan Uriev; Thoroddsen, Sigurdur T

    2011-01-01

    We report observations of air bubble entrapment when a solid sphere impacts a quiescent liquid surface. Using high-speed imaging, we show that a small amount of air is entrapped at the bottom tip of the impacting sphere. This phenomenon is examined

  9. Surface Structures of Binary Mixture of Ionic Liquids.

    Czech Academy of Sciences Publication Activity Database

    Nakajima, K.; Nakanishi, S.; Lísal, Martin; Kimura, K.

    2017-01-01

    Roč. 230, MARCH (2017), s. 542-549 ISSN 0167-7322 R&D Projects: GA ČR(CZ) GA16-12291S Institutional support: RVO:67985858 Keywords : ionic liquids * mixture * surface structure Subject RIV: CF - Physical ; Theoretical Chemistry OBOR OECD: Physical chemistry Impact factor: 3.648, year: 2016

  10. Characterization of fueling NSTX H-mode plasmas diverted to a liquid lithium divertor

    Energy Technology Data Exchange (ETDEWEB)

    Kaita, R., E-mail: kaita@pppl.gov [Princeton Plasma Physics Laboratory, P.O. Box 451, Princeton, NJ 08543 (United States); Kugel, H.W.; Abrams, T. [Princeton Plasma Physics Laboratory, P.O. Box 451, Princeton, NJ 08543 (United States); Allain, J.P. [Purdue University, West Lafayette, IN 47907 (United States); Bell, M.G.; Bell, R.E.; Diallo, A.; Gerhardt, S.P. [Princeton Plasma Physics Laboratory, P.O. Box 451, Princeton, NJ 08543 (United States); Heim, B. [Purdue University, West Lafayette, IN 47907 (United States); Jaworski, M.A., E-mail: mjaworsk@pppl.gov [Princeton Plasma Physics Laboratory, P.O. Box 451, Princeton, NJ 08543 (United States); Kallman, J. [Princeton Plasma Physics Laboratory, P.O. Box 451, Princeton, NJ 08543 (United States); Lawrence Livermore National Laboratory, Livermore, CA 94551 (United States); Kaye, S.; LeBlanc, B.P. [Princeton Plasma Physics Laboratory, P.O. Box 451, Princeton, NJ 08543 (United States); Maingi, R. [Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Mansfield, D. [Princeton Plasma Physics Laboratory, P.O. Box 451, Princeton, NJ 08543 (United States); McLean, A. [Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Menard, J.; Mueller, D. [Princeton Plasma Physics Laboratory, P.O. Box 451, Princeton, NJ 08543 (United States); Nygren, R. [Sandia National Laboratories, Albuquerque, NM 87185 (United States); Ono, M. [Princeton Plasma Physics Laboratory, P.O. Box 451, Princeton, NJ 08543 (United States); and others

    2013-07-15

    Deuterium fueling experiments were conducted with the NSTX Liquid Lithium Divertor (LLD). Lithium evaporation recoated the LLD surface to approximate flowing liquid Li to sustain D retention. In the first experiment with the diverted outer strike point on the LLD, the difference between the applied D gas input and the plasma D content reached very high values without disrupting the plasma, as would normally occur in the absence of Li pumping, and there was also little change in plasma D content. In the second experiment, constant fueling was applied, as the LLD temperature was varied to change the surface from solid to liquid. The D retention was relatively constant, and about the same as that for solid Li coatings on graphite, or twice that achieved without Li PFC coatings. Contamination of the LLD surface was also possible due to compound formation and erosion and redeposition from carbon PFCs.

  11. Photospheric Observations of Surface and Body Modes in Solar Magnetic Pores

    Science.gov (United States)

    Keys, Peter H.; Morton, Richard J.; Jess, David B.; Verth, Gary; Grant, Samuel D. T.; Mathioudakis, Mihalis; Mackay, Duncan H.; Doyle, John G.; Christian, Damian J.; Keenan, Francis P.; Erdélyi, Robertus

    2018-04-01

    Over the past number of years, great strides have been made in identifying the various low-order magnetohydrodynamic wave modes observable in a number of magnetic structures found within the solar atmosphere. However, one aspect of these modes that has remained elusive, until now, is their designation as either surface or body modes. This property has significant implications for how these modes transfer energy from the waveguide to the surrounding plasma. Here, for the first time to our knowledge, we present conclusive, direct evidence of these wave characteristics in numerous pores that were observed to support sausage modes. As well as outlining methods to detect these modes in observations, we make estimates of the energies associated with each mode. We find surface modes more frequently in the data, as well as that surface modes appear to carry more energy than those displaying signatures of body modes. We find frequencies in the range of ∼2–12 mHz, with body modes as high as 11 mHz, but we do not find surface modes above 10 mHz. It is expected that the techniques we have applied will help researchers search for surface and body signatures in other modes and in differing structures from those presented here.

  12. Local structural ordering in surface-confined liquid crystals

    Science.gov (United States)

    Śliwa, I.; Jeżewski, W.; Zakharov, A. V.

    2017-06-01

    The effect of the interplay between attractive nonlocal surface interactions and attractive pair long-range intermolecular couplings on molecular structures of liquid crystals confined in thin cells with flat solid surfaces has been studied. Extending the McMillan mean field theory to include finite systems, it has been shown that confining surfaces can induce complex orientational and translational ordering of molecules. Typically, local smectic A, nematic, and isotropic phases have been shown to coexist in certain temperature ranges, provided that confining cells are sufficiently thick, albeit finite. Due to the nonlocality of surface interactions, the spatial arrangement of these local phases can display, in general, an unexpected complexity along the surface normal direction. In particular, molecules located in the vicinity of surfaces can still be organized in smectic layers, even though nematic and/or isotropic order can simultaneously appear in the interior of cells. The resulting surface freezing of smectic layers has been confirmed to occur even for rather weak surface interactions. The surface interactions cannot, however, prevent smectic layers from melting relatively close to system boundaries, even when molecules are still arranged in layers within the central region of the system. The internal interfaces, separating individual liquid-crystal phases, are demonstrated here to form fronts of local finite-size transitions that move across cells under temperature changes. Although the complex molecular ordering in surface confined liquid-crystal systems can essentially be controlled by temperature variations, specific thermal properties of these systems, especially the nature of the local transitions, are argued to be strongly conditioned to the degree of molecular packing.

  13. Effect of smectic A temperature width on the soft mode in ferroelectric liquid crystals

    Science.gov (United States)

    Choudhary, A.; Kaur, S.; Prakash, J.; Sreenivas, K.; Bawa, S. S.; Biradar, A. M.

    2008-08-01

    The behavior of soft mode range with respect to the temperature width of smectic A (Sm A) phase has been studied in four different ferroelectric liquid crystal (FLC) materials in the frequency range 10Hz-10MHz. The studies have been carried out in a planarly well aligned cells at different temperatures and different bias fields in Sm C* and Sm A phases. Dielectric studies of these FLCs near Sm C*-Sm A phase transition show that the temperature range of soft mode relaxation frequency phenomenon varies with the temperature width of Sm A phase. The dependence of tilt angle on temperature shows the nature of the order of transition at Sm C*-Sm A phase. The coupling between order parameters of Sm C* and Sm A phase influences the soft mode and phase transition in Sm C* and Sm A phases.

  14. Tunable single photonic defect-mode in cholesteric liquid crystals with laser-induced local modifications of helix

    International Nuclear Information System (INIS)

    Yoshida, Hiroyuki; Lee, Chee Heng; Fujii, Akihiko; Ozaki, Masanori

    2006-01-01

    The authors demonstrate a tunable single photonic defect-mode in a single cholesteric liquid crystal material based on a structural defect introduced by local modification of the helix. An unpolymerized region of cholesteric liquid crystal acting as the defect was left between two polymerized regions via a two-photon excitation laser-lithography process. Upon polymerization, the cholesteric liquid crystal helix elongated and became thermally stable, and a single photonic defect mode was exhibited due to the contrast in the helix pitch at the defect. The defect mode showed tunability upon heating, and a 36 nm redshift was seen over a temperature range of 30 deg. C

  15. Surface energies of metals in both liquid and solid states

    International Nuclear Information System (INIS)

    Aqra, Fathi; Ayyad, Ahmed

    2011-01-01

    Although during the last years one has seen a number of systematic studies of the surface energies of metals, the aim and the scientific meaning of this research is to establish a simple and a straightforward theoretical model to calculate accurately the mechanical and the thermodynamic properties of metal surfaces due to their important application in materials processes and in the understanding of a wide range of surface phenomena. Through extensive theoretical calculations of the surface tension of most of the liquid metals, we found that the fraction of broken bonds in liquid metals (f) is constant which is equal to 0.287. Using our estimated f value, the surface tension (γ m ), surface energy (γ SV ), surface excess entropy (-dγ/dT), surface excess enthalpy (H s ), coefficient of thermal expansion (α m and α b ), sound velocity (c m ) and its temperature coefficient (-dc/dT) have been calculated for more than sixty metals. The results of the calculated quantities agree well with available experimental data.

  16. Three modes of interdecadal trends in sea surface temperature and sea surface height

    Science.gov (United States)

    Gnanadesikan, A.; Pradal, M.

    2013-12-01

    It might be thought that sea surface height and sea surface temperature would be tightly related. We show that this is not necessarily the case on a global scale. We analysed this relationship in a suite of coupled climate models run under 1860 forcing conditions. The models are low-resolution variants of the GFDL Earth System Model, reported in Galbraith et al. (J. Clim. 2011). 1. Correlated changes in global sea surface height and global sea surface temperature. This mode corresponds to opening and closing of convective chimneys in the Southern Ocean. As the Southern Ocean destratifies, sea ice formation is suppressed during the winter and more heat is taken up during the summer. This mode of variability is highly correlated with changes in the top of the atmosphere radiative budget and weakly correlated with changes in the deep ocean circulation. 2. Uncorrelated changes in global sea surface height and global sea surface temperature. This mode of variability is associated with interdecadal variabliity in tropical winds. Changes in the advective flux of heat to the surface ocean play a critical role in driving these changes, which also result in significant local changes in sea level. Changes sea ice over the Southern Ocean still result in changes in solar absorption, but these are now largely cancelled by changes in outgoing longwave radiation. 3. Anticorrelated changes in global sea surface height and global sea surface temperatures. By varying the lateral diffusion coefficient in the ocean model, we are able to enhance and suppress convection in the Southern and Northern Pacific Oceans. Increasing the lateral diffusion coefficients shifts the balance sources of deep water away from the warm salty deep water of the North Atlantic and towards cold fresh deep water from the other two regions. As a result, even though the planet as a whole warms, the deep ocean cools and sea level falls, with changes of order 30 cm over 500 years. The increase in solar absorption

  17. Drop splashing: the role of surface wettability and liquid viscosity

    Science.gov (United States)

    Almohammadi, Hamed; Amirfazli, Alidad; -Team

    2017-11-01

    There are seemingly contradictory results in the literature about the role of surface wettability and drop viscosity for the splashing behavior of a drop impacting onto a surface. Motivated by such issues, we conducted a systematic experimental study where splashing behavior for a wide range of the liquid viscosity (1-100 cSt) and surface wettability (hydrophilic to hydrophobic) are examined. The experiments were performed for the liquids with both low and high surface tensions ( 20 and 72 mN/m). We found that the wettability affects the splashing threshold at high or low contact angle values. At the same drop velocity, an increase of the viscosity (up to 4 cSt) promotes the splashing; while, beyond such value, any increase in viscosity shows the opposite effect. It is also found that at a particular combination of liquid surface tension and viscosity (e.g. silicone oil, 10 cSt), an increase in the drop velocity changes the splashing to spreading. We relate such behaviors to the thickness, shape, and the velocity of the drop's lamella. Finally, to predict the splashing, we developed an empirical correlation which covers all of the previous reported data, hence clarifying the ostensible existing contradictions.

  18. The appearance of liquid surfaces and layers in routine radiographs

    International Nuclear Information System (INIS)

    Nilson, A.E.; Sahlgrenska Sjukhuset, Goeteborg

    1986-01-01

    As has been demonstrated, the interfaces between a gas and a body fluid or a contrast medium may be visualized in the radiographic image as various kinds of boundaries, as also may interfaces between a contrast medium and a body fluid. These can provide little diagnostic information. Data of clinical value are usually derived from boundaries that represent bounding surfaces of anatomic structures touched by the roentgen rays. In the interpretation of the radiographic image it is important to recognize whether a boundary represents an anatomic structure, a liquid surface or a diffusion layer. It is a traditional view that a liquid surface is visualized by a horizontal beam as a straight horizontal boundary and that the imaged surface is then also horizontal. As has been shown in the earlier investigations and the present one, this is not always the case, for these boundaries are usually curved with an upward concavity. It is important to bear in mind that also rays departing considerably from the horizontal may still touch the liquid surface in its meniscoid. Even a vertical beam will form a boundary when touching a meniscoid. It would also appear that the simple layering phenomenon can present difficulty in interpretation. Examples of this phenomenon that illustrate particularly important situations have been presented. Ambiguity associated with the interpretation of images produced by a vertical beam may be resolved with the aid of supplementary films exposed with a horizontal beam. (orig.)

  19. Hydrometer calibration by hydrostatic weighing with automated liquid surface positioning

    International Nuclear Information System (INIS)

    Aguilera, Jesus; Wright, John D; Bean, Vern E

    2008-01-01

    We describe an automated apparatus for calibrating hydrometers by hydrostatic weighing (Cuckow's method) in tridecane, a liquid of known, stable density, and with a relatively low surface tension and contact angle against glass. The apparatus uses a laser light sheet and a laser power meter to position the tridecane surface at the hydrometer scale mark to be calibrated with an uncertainty of 0.08 mm. The calibration results have an expanded uncertainty (with a coverage factor of 2) of 100 parts in 10 6 or less of the liquid density. We validated the apparatus by comparisons using water, toluene, tridecane and trichloroethylene, and found agreement within 40 parts in 10 6 or less. The new calibration method is consistent with earlier, manual calibrations performed by NIST. When customers use calibrated hydrometers, they may encounter uncertainties of 370 parts in 10 6 or larger due to surface tension, contact angle and temperature effects

  20. Hydrometer calibration by hydrostatic weighing with automated liquid surface positioning

    Science.gov (United States)

    Aguilera, Jesus; Wright, John D.; Bean, Vern E.

    2008-01-01

    We describe an automated apparatus for calibrating hydrometers by hydrostatic weighing (Cuckow's method) in tridecane, a liquid of known, stable density, and with a relatively low surface tension and contact angle against glass. The apparatus uses a laser light sheet and a laser power meter to position the tridecane surface at the hydrometer scale mark to be calibrated with an uncertainty of 0.08 mm. The calibration results have an expanded uncertainty (with a coverage factor of 2) of 100 parts in 106 or less of the liquid density. We validated the apparatus by comparisons using water, toluene, tridecane and trichloroethylene, and found agreement within 40 parts in 106 or less. The new calibration method is consistent with earlier, manual calibrations performed by NIST. When customers use calibrated hydrometers, they may encounter uncertainties of 370 parts in 106 or larger due to surface tension, contact angle and temperature effects.

  1. Rupture of thin liquid films on structured surfaces.

    Science.gov (United States)

    Ajaev, Vladimir S; Gatapova, Elizaveta Ya; Kabov, Oleg A

    2011-10-01

    We investigate stability and breakup of a thin liquid film on a solid surface under the action of disjoining pressure. The solid surface is structured by parallel grooves. Air is trapped in the grooves under the liquid film. Our mathematical model takes into account the effect of slip due to the presence of menisci separating the liquid film from the air inside the grooves, the deformation of these menisci due to local variations of pressure in the liquid film, and nonuniformities of the Hamaker constant which measures the strength of disjoining pressure. Both linear stability and strongly nonlinear evolution of the film are analyzed. Surface structuring results in decrease of the fastest growing instability wavelength and the rupture time. It is shown that a simplified description of film dynamics based on the standard formula for effective slip leads to significant deviations from the behavior seen in our simulations. Self-similar decay over several orders of magnitude of the film thickness near the rupture point is observed. We also show that the presence of the grooves can lead to instability in otherwise stable films if the relative groove width is above a critical value, found as a function of disjoining pressure parameters.

  2. Surface wave propagation in a double liquid layer over a liquid ...

    Indian Academy of Sciences (India)

    The frequency equation is derived for surface waves in a liquidsaturated porous half-space supporting a double layer, that of inhomogeneous and homogeneous liquids. Asymptotic approximations of Bessel functions are used for long and short wavelength cases. Certain other problems are discussed as special cases.

  3. Structure and dynamics at the liquid surface of benzyl alcohol

    International Nuclear Information System (INIS)

    Dietter, J.; Morgner, H.

    1999-01-01

    A molecular dynamics simulation of a liquid layer of benzyl alcohol has been performed in order to compare the results with those obtained in experimental studies of our group. The main result of the experimental work was a strong orientational ordering of the benzyl alcohol molecules in the surface as well as an exceptionally large surface potential of ca. 0.6 V. According to the experiments the surface molecules orientate in such a way that the benzene ring points toward the vapor phase while the CH 2 group and the OH group are directed towards the bulk of the liquid. The simulation confirms this orientation of the surface molecules. The surface potential resulting from the simulation is 350 mV. The simulation reveals that the rather large surface potential can be understood as a consequence of the mean orientation of the molecular dipole moment in the surface region. The mean orientation of the molecules themselves in the surface is due to the tendency of the system to maintain the hydrogen bonding structure of the bulk in the surface region as well. The preferential orientation of the surface molecules causes a change of the dynamics of the individual components of the molecules when switching from bulk to surface which depends on the separation of these components from the polar group. This becomes most obvious in case of the reorientation dynamics of the molecular axes, e.g. the reorientation of the benzene ring is faster than the reorientation of the OH group. (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)

  4. Modelling out-of-plane and in-plane resonant modes of microplates in liquid media

    International Nuclear Information System (INIS)

    Ruiz-Díez, V; Hernando-García, J; Manzaneque, T; Sánchez-Rojas, J L; Kucera, M; Schmid, U

    2015-01-01

    In this article, the quality factor and the resonant frequency of different vibrating modes of microplates immersed in liquid are simulated by means of a finite element method (FEM) and compared with experimental data. For the in-plane modes, we studied the first extensional mode of mid-point supported microplates, which may be efficiently actuated by a thin piezoelectric film on top of the structure. A comparison of different approaches to account for the viscous loading in computationally efficient 2D finite element models is presented. As an alternative to the harmonic response, a novel multitone excitation in the fluid–structure interaction model allows for the calculation of the frequency response of the structure. For the out-of-plane modes, different modes were simulated and compared to analytical models to validate our approach. Our 2D FEM model yields more accurate estimations of the experimental resonance frequency and quality factors than the available analytical models. With the help of these tools, the applicability of the micro-resonators as viscosity and density sensors is discussed. (paper)

  5. Reducing Friction with a Liquid Film on the Body Surface

    Directory of Open Access Journals (Sweden)

    Nikolay Klyuev

    2018-03-01

    Full Text Available A flow of a thin layer of liquid is simulated on a flat surface of a body located in a stream of air. Liquid film on the surface of the body reduces frictional resistance and can be used as a boundary layer control element. The paper presents a mathematical model of the film flow on a half-plane, located at an angle to the horizon. The fluid flow is determined by the force of gravity and friction from the external air current. A model of an incompressible viscous fluid is used in the boundary-layer approximation. The terms of the motion equation are averaged over the film thickness according to the Leibniz rule. In the cross section of the film, a quadratic law is adopted for the distribution of the longitudinal velocity, taking into account friction on the film surface. An analytical solution of the problem is obtained in the form of series in powers of the small parameter for determining the film thickness and the average longitudinal velocity along the length of the plate. It is shown that the friction decreases with flow around a half-plane with a film of liquid on the surface.

  6. Capillary origami: superhydrophobic ribbon surfaces and liquid marbles

    Directory of Open Access Journals (Sweden)

    Glen McHale

    2011-03-01

    Full Text Available In the wetting of a solid by a liquid it is often assumed that the substrate is rigid. However, for an elastic substrate the rigidity depends on the cube of its thickness and so reduces rapidly as the substrate becomes thinner as it approaches becoming a thin sheet. In such circumstances, it has been shown that the capillary forces caused by a contacting droplet of a liquid can shape the solid rather than the solid shaping the liquid. A substrate can be bent and folded as a (pinned droplet evaporates or even instantaneously and spontaneously wrapped on contact with a droplet. When this effect is used to create three dimensional shapes from initially flat sheets, the effect is called capillary origami or droplet wrapping.In this work, we consider how the conditions for the spontaneous, capillary induced, folding of a thin ribbon substrate might be altered by a rigid surface structure that, for a rigid substrate, would be expected to create Cassie–Baxter and Wenzel effects. For smooth thin substrates, droplet wrapping can occur for all liquids, including those for which the Young’s law contact angle (defined by the interfacial tensions is greater than 90° and which would therefore normally be considered relatively hydrophobic. However, consideration of the balance between bending and interfacial energies suggests that the tendency for droplet wrapping can be suppressed for some liquids by providing the flexible solid surface with a rigid topographic structure. In general, it is known that when a liquid interacts with such a structure it can either fully penetrate the structure (the Wenzel case or it can bridge between the asperities of the structure (the Cassie–Baxter case.In this report, we show theoretically that droplet wrapping should occur with both types of solid–liquid contact. We also derive a condition for the transition between the Cassie–Baxter and Wenzel type droplet wrapping and relate it to the same transition condition

  7. Instability of flow of liquid film over a heated surface

    International Nuclear Information System (INIS)

    Sha, W.T.

    1994-01-01

    Fundamental concepts and basic equations of a flowing thin liquid film cooling a heated surfaced by its vaporization and the effect of dry patches were treated. Stable film flow prior to the appearance of dry patches on the heated surface is maintained by a balance of various forces due to surface tension, shear stress, heat and mass transfer, and gravity. Film splitting at a critical film thickness produces dry patches due to perturbation by waves on a perfect surface, and often by surface imperfection and uneven heating. This work is primarily motivated by the design of next-generation nuclear reactors, which employ many novel passive heat-removal systems via natural circulation. These systems are design to prevent damage to the reactor core and containment without action by the reactor operators during or after a design basis accident such as a loss of coolant accident (LOCA) or a main steam-line break (MSLB) accident

  8. Study on surface wave characteristics of free surface flow of liquid metal lithium for IFMIF

    International Nuclear Information System (INIS)

    Hoashi, Eiji; Sugiura, Hirokazu; Yoshihashi-Suzuki, Sachiko; Yamaoka, Nobuo; Horiike, Hiroshi; Kanemura, Takuji; Kondo, Hiroo

    2011-01-01

    The international fusion materials irradiation facility (IFMIF) presents an intense neutron source to develop fusion reactor materials. The free surface flow of a liquid metal Lithium (Li) is planned as a target irradiated by two deuteron beams to generate intense neutrons and it is thus important to obtain knowledge of the surface wave characteristic for the safety and the efficiency of system in the IFMIF. We have been studying on surface wave characteristics experimentally using the liquid metal Li circulation facility at Osaka University and numerically using computational fluid dynamics (CFD) code, FLUENT. This paper reports the results of the surface fluctuation, the wave height and the surface velocity in the free surface flow of the liquid metal Li examined experimentally and numerically. In the experiment, an electro-contact probe apparatus was used to obtain the surface fluctuation and the wave height, and a high speed video was used to measure the surface velocity. We resulted in knowledge of the surface wave growth mechanism. On the other hand, a CFD simulation was also conducted to obtain information on the relation of the free surface with the inner flow. In the simulation, the model included from a two-staged contraction nozzle to a flow channel with a free surface flow region and simulation results were compared with the experimental data. (author)

  9. Time-Dependent Liquid Transport on a Biomimetic Topological Surface.

    Science.gov (United States)

    Yu, Cunlong; Li, Chuxin; Gao, Can; Dong, Zhichao; Wu, Lei; Jiang, Lei

    2018-05-02

    Liquid drops impacting on a solid surface is a familiar phenomenon. On rainy days, it is quite important for leaves to drain off impacting raindrops. Water can bounce off or flow down a water-repellent leaf easily, but with difficulty on a hydrophilic leaf. Here, we show an interesting phenomenon in which impacting drops on the hydrophilic pitcher rim of Nepenthes alata can spread outward to prohibit water filling the pitcher tank. We mimic the peristome surface through a designed 3D printing and replicating way and report a time-dependently switchable liquid transport based on biomimetic topological structures, where surface curvature can work synergistically with the surface microtextures to manipulate the switchable spreading performance. Motived by this strange behavior, we construct a large-scaled peristome-mimetic surface in a 3D profile, demonstrating the ability to reduce the need to mop or to squeegee drops that form during the drop impacting process on pipes or other curved surfaces in food processing, moisture transfer, heat management, etc.

  10. Surface dynamics and mechanics in liquid crystal polymer coatings

    Science.gov (United States)

    Liu, Danqing; Broer, Dirk J.

    2015-03-01

    Based on liquid crystal networks we developed `smart' coatings with responsive surface topographies. Either by prepatterning or by the formation of self-organized structures they can be switched on and off in a pre-designed manner. Here we provide an overview of our methods to generate coatings that form surface structures upon the actuation by light. The coating oscillates between a flat surface and a surface with pre-designed 3D micro-patterns by modulating a light source. With recent developments in solid state lighting, light is an attractive trigger medium as it can be integrated in a device for local control or can be used remotely for flood or localized exposure. The basic principle of formation of surface topographies is based on the change of molecular organization in ordered liquid crystal polymer networks. The change in order leads to anisotropic dimensional changes with contraction along the director and expansion to the two perpendicular directions and an increase in volume by the formation of free volume. These two effects work in concert to provide local expansion and contraction in the coating steered by the local direction of molecular orientation. The surface deformation, expressed as the height difference between the activated regions and the non-activated regions divided by the initial film thickness, is of the order of 20%. Switching occurs immediately when the light is switched `on' and `off' and takes several tens of seconds.

  11. Theory of the surface dipole layer and of surface tension in liquids of charged particles

    International Nuclear Information System (INIS)

    Senatore, G.; Tosi, M.P.

    1980-01-01

    The problem of the surface density profiles and of the surface tension of a two-component liquid of charged particles in equilibrium with its vapour is examined. The exact equilibrium conditions for the profiles are given in terms of the inverse response functions of the inhomogeneous fluid, and alternative exact expressions for the surface tension are derived. The use of a density gradient expansion reduces the problem to knowledge of properties of a homogeneous charged fluid on a uniform neutralizing background, in which the total particle density and the charge density are independent variables. Additional simplifications are discussed for special cases for which a perturbative treatment of the surface charge density profile can be developed, and in particular for nearly symmetric ionic liquids and for simple liquid metals. (author)

  12. Behavior of a Liquid Bridge between Nonparallel Hydrophobic Surfaces.

    Science.gov (United States)

    Ataei, Mohammadmehdi; Chen, Huanchen; Amirfazli, Alidad

    2017-12-26

    When a liquid bridge is formed between two nonparallel identical surfaces, it can move along the surfaces. Literature indicates that the direction of bridge movement is governed by the wettability of surfaces. When the surfaces are hydrophilic, the motion of the bridge is always toward the cusp (intersection of the plane of the two bounding surfaces). On the other hand, the movement is hitherto thought to be always pointing away from the cusp when the surfaces are hydrophobic. In this study, through experiments, numerical simulations, and analytical reasoning, we demonstrate that for hydrophobic surfaces, wettability is not the only factor determining the direction of the motion. A new geometrical parameter, i.e., confinement (cf), was defined as the ratio of the distance of the farthest contact point of the bridge to the cusp, and that of the closest contact point to the cusp. The direction of the motion depends on the amount of confinement (cf). When the distance between the surfaces is large (resulting in a small cf), the bridge tends to move toward the cusp through a pinning/depinning mechanism of contact lines. When the distance between the surfaces is small (large cf), the bridge tends to move away from the cusp. For a specific system, a maximum cf value (cf max ) exists. A sliding behavior (i.e., simultaneous advancing on the wider side and receding on the narrower side) can also be seen when a liquid bridge is compressed such that the cf exceeds the cf max . Contact angle hysteresis (CAH) is identified as an underpinning phenomenon that together with cf fundamentally explains the movement of a trapped liquid between two hydrophobic surfaces. If there is no CAH, however, i.e., the case of ideal hydrophobic surfaces, the cf will be a constant; we show that the bridge slides toward the cusp when it is stretched, while it slides away from the cusp when it is compressed (note sliding motion is different from motion due to pinning/depinning mechanism of contact

  13. A Liquid Metal Flume for Free Surface Magnetohydrodynamic Experiments

    International Nuclear Information System (INIS)

    Nornberg, M.D.; Ji, H.; Peterson, J.L.; Rhoads, J.R.

    2008-01-01

    We present an experiment designed to study magnetohydrodynamic effects in free-surface channel flow. The wide aspect ratio channel (the width to height ratio is about 15) is completely enclosed in an inert atmosphere to prevent oxidization of the liquid metal. A custom-designed pump reduces entrainment of oxygen, which was found to be a problem with standard centrifugal and gear pumps. Laser Doppler Velocimetry experiments characterize velocity profiles of the flow. Various flow constraints mitigate secondary circulation and end effects on the flow. Measurements of the wave propagation characteristics in the liquid metal demonstrate the surfactant effect of surface oxides and the damping of fluctuations by a cross-channel magnetic field

  14. Warm electrons on the liquid 4He surface

    International Nuclear Information System (INIS)

    Saitoh, Motohiko

    1977-01-01

    Detailed theoretical analysis of non-Ohmic transport of electrons on the liquid 4 He surface is given. The correct form of the electron-ripplon scattering as well as the electron- 4 He gas scattering is taken into account. A characteristic electric field at which electron mobility deviates from the Ohmic value is estimated as a function of temperature and the holding field on the basis of the electron effective temperature approximation. (auth.)

  15. Monochromator on a synchrotron undulator source for liquid surface studies

    DEFF Research Database (Denmark)

    Als-Nielsen, Jens Aage; Freund, A.K.

    1992-01-01

    For liquid surface studies a monochromatic beam of relative bandwidth between 0.1% and 1% at a variable angle in the vertical plane between 0-degrees and 10-degrees is needed. The beam should be like a sheet some tens of mu-m thick and some mm wide, and as intense as possible. We discuss a monoch......For liquid surface studies a monochromatic beam of relative bandwidth between 0.1% and 1% at a variable angle in the vertical plane between 0-degrees and 10-degrees is needed. The beam should be like a sheet some tens of mu-m thick and some mm wide, and as intense as possible. We discuss......% of the useful x rays, in full agreement with diffraction theory including secondary extinction. Heat load experiments reported elsewhere in this conference prove that Be crystals can withstand high beam power density and that the thermal deformation is small compared to the mosaic spread. The results...... of the flux calculations are most encouraging: a gain of order 10(3) to 10(4) can be expected as compared to existing liquid surface spectrometers....

  16. Stability of thin liquid films containing surface active particles

    Science.gov (United States)

    Umashankar, Hariharan; Kalpathy, Sreeram; Dixit, Harish

    2017-11-01

    The stability and dynamics of thin liquid films(industrial settings like coating and printing processes and extraction of oil from porous rocks. In this study a hydrodynamic model is introduced to capture the long term evolution of a Newtonian liquid film containing insoluble surfaceactive particles.We consider here the possibility of four distinct interaction regimes based on the surface rheological effects of the particles, such that either, both or neither of Marangoni and surface viscosity effects would be present at the leading order in the governing equations. The liquid film is bounded by a rigid impermeable solid below and covered by passive air phase above.A standard linear stability analysis and nonlinear simulations are performed on the set of highly coupled partial differential evolution equations. Linear stability analysis gives insights on whether a particular imposed perturbationwavenumber will grow or decay in time and also evaluating the fastest growing wavenumber. Parametric studies for all four regimes provides a strong confirmation that surface viscosity and Marangoni effects are indeed rupture delaying effects.

  17. Liquid metal actuator driven by electrochemical manipulation of surface tension

    Science.gov (United States)

    Russell, Loren; Wissman, James; Majidi, Carmel

    2017-12-01

    We examine the electrocapillary properties of a fluidic actuator composed of a liquid metal droplet that is submerged in electrolytic solution and attached to an elastic beam. The beam deflection is controlled by electrochemically driven changes in the surface energy of the droplet. The metal is a eutectic gallium-indium alloy that is liquid at room temperature and forms an nm-thin Ga2O3 skin when oxidized. The effective surface tension of the droplet changes dramatically with oxidation and reduction, which are reversibly controlled by applying low voltage to the electrolytic bath. Wetting the droplet to two copper pads allows for a controllable tensile force to be developed between the opposing surfaces. We demonstrate the ability to reliably control force by changing the applied oxidizing voltage. Actuator forces and droplet geometries are also examined by performing a computational fluid mechanics simulation using Surface Evolver. The theoretical predictions are in qualitative agreement with the experimental measurements and provide additional confirmation that actuation is driven by surface tension.

  18. Static phenomena at the charged surface of liquid hydrogen

    International Nuclear Information System (INIS)

    Levchenko, A.A.; Kolmakov, G.V.; Mezhov-Deglin, L.P.; Mikhjlov, M.G.; Trusov, A.B.

    1999-01-01

    The shape evolution of the equipotentially charged surface of liquid hydrogen layer covering the lower plate of a horizontally arranged diode in external electric fields has been studied experimentally for the first time. A reconstruction phenomenon (the formation of a stationary hump) at the flat charged surface at voltages higher than a certain critical U c1 was observed under the conditions of total compensation of the electric field in the bulk liquid by a surface charge. It is shown that the transition of the flat charged surface into the reconstructed state is a phase transition closed to the second order phase transition. The height of the hump increased with increasing the voltage and at U c2 > 1,2 U c1 the reconstructed surface lost the stability, and a stream discharge pulse was observed. The shape evolution of a changed droplet of constant volume suspended at the upper plate of the diode when the stretching electric field and gravity forces act in the same direction was studied as the voltage was increased up to the discharge

  19. Fast switchable ferroelectric liquid crystal gratings with two electro-optical modes

    International Nuclear Information System (INIS)

    Ma, Ying; Srivastava, A. K.; Chigrinov, V. G.; Kwok, H.-S.; Wang, Xiaoqian

    2016-01-01

    In this article, we reveal a theoretical and experimental illustration of the Ferroelectric liquid crystal (FLC) grating fabricated by mean of patterned alignment based on photo-alignment. The complexity related to the mismatching of the predefined alignment domains on the top and bottom substrate has been avoided by incorporating only one side photo aligned substrate while the other substrate does not have any alignment layer. Depending on the easy axis in the said alignment domains and the azimuth plane of the impinging polarized light, the diffracting element can be tuned in two modes i.e. DIFF/OFF switchable and DIFF/TRANS switchable modes, which can be applied to different applications. The diffraction profile has been illustrated theoretically that fits well with the experimental finding and thus the proposed diffraction elements with fast response time and high diffraction efficiency could find application in many modern devices.

  20. Dual-mode switching of a liquid crystal panel for viewing angle control

    Science.gov (United States)

    Baek, Jong-In; Kwon, Yong-Hoan; Kim, Jae Chang; Yoon, Tae-Hoon

    2007-03-01

    The authors propose a method to control the viewing angle of a liquid crystal (LC) panel using dual-mode switching. To realize both wide viewing angle (WVA) characteristics and narrow viewing angle (NVA) characteristics with a single LC panel, the authors use two different dark states. The LC layer can be aligned homogeneously parallel to the transmission axis of the bottom polarizer for WVA dark state operation, while it can be aligned vertically for NVA dark state operation. The authors demonstrated that viewing angle control can be achieved with a single panel without any loss of contrast at the front.

  1. Surface plasmon polariton nanocavity with ultrasmall mode volume

    Science.gov (United States)

    Yue, Wencheng; Yao, Peijun; Luo, Huiwen; Liu, Wen

    2017-08-01

    We present a plasmonic nanocavity structure, consisting of a gallium phosphide (GaP) cylinder penetrating into a rectangular silver plate, and study its properties using a finite element method (FEM). An ultrasmall mode volume of 1.5×10-5[λ_0/(2n)]3 is achieved, which is more than 200 times smaller than the previous ultrasmall mode volume plasmonic nanodisk resonators. Meanwhile, the quality factor of the plasmonic nanocavity is about 38.2 and is over two times greater than the ultrasmall mode volume plasmonic nanodisk resonators. Compared to the aforementioned plasmonic nanodisk resonators, a more than one-order of magnitude larger Purcell factor of 1.2×104 is achieved. We determined the resonant modes of our plasmonic nanocavity are dipolar plasmon modes by analyzing the electric field properties. In addition, we investigate the dependence of the optical properties on the refractive index of the cavity material and discuss the effect of including the silica (SiO2) substrate. Our work provides an alternative approach to achieve ultrasmall plasmonic nanocavity of interest in applications to many areas of research, including device physics, nonlinear optics and quantum optics.

  2. Experimental study of liquid drop impact onto a powder surface

    KAUST Repository

    Marston, Jeremy; Thoroddsen, Sigurdur T; Ng, Waikiong; Tan, Reginald

    2010-01-01

    The initial dynamics of liquid drop impact onto powder surfaces is studied experimentally using high-speed photography. For a range of bed packing fractions, φ, liquid physical properties and impact velocities, ui, we observe a variety of phenomena that can be representative of a hydrophobic surface, a rough surface or a porous medium. The solids packing fraction in the bed, 0.38≤φ≤0.65, and the impact Weber number, 3.5≤We=ρDui 2/φ≤750, (where ρ, D and φ are the drop density, diameter and surface tension respectively) are shown to be the critical parameters governing the outcome of an impact. For high packing fractions, φ≳0.5, we show that the observed spreading, rebound and splashing can be broadly characterised in terms of the Weber number while for looser packing fractions, φ≲0.5, we observe powder ejectas and provide a qualitative description of the granule nucleation at the centre of the impact sites. © 2010 Elsevier B.V.

  3. Experimental study of liquid drop impact onto a powder surface

    KAUST Repository

    Marston, Jeremy

    2010-11-01

    The initial dynamics of liquid drop impact onto powder surfaces is studied experimentally using high-speed photography. For a range of bed packing fractions, φ, liquid physical properties and impact velocities, ui, we observe a variety of phenomena that can be representative of a hydrophobic surface, a rough surface or a porous medium. The solids packing fraction in the bed, 0.38≤φ≤0.65, and the impact Weber number, 3.5≤We=ρDui 2/φ≤750, (where ρ, D and φ are the drop density, diameter and surface tension respectively) are shown to be the critical parameters governing the outcome of an impact. For high packing fractions, φ≳0.5, we show that the observed spreading, rebound and splashing can be broadly characterised in terms of the Weber number while for looser packing fractions, φ≲0.5, we observe powder ejectas and provide a qualitative description of the granule nucleation at the centre of the impact sites. © 2010 Elsevier B.V.

  4. Studies of nanosecond pulse surface ionization wave discharges over solid and liquid dielectric surfaces

    International Nuclear Information System (INIS)

    Petrishchev, Vitaly; Leonov, Sergey; Adamovich, Igor V

    2014-01-01

    Surface ionization wave discharges generated by high-voltage nanosecond pulses, propagating over a planar quartz surface and over liquid surfaces (distilled water and 1-butanol) have been studied in a rectangular cross section test cell. The discharge was initiated using a custom-made, alternating polarity, high-voltage nanosecond pulse plasma generator, operated at a pulse repetition rate of 100–500 Hz, with a pulse peak voltage and current of 10–15 kV and 7–20 A, respectively, a pulse FWHM of ∼100 ns, and a coupled pulse energy of 2–9 mJ/pulse. Wave speed was measured using a capacitive probe. ICCD camera images demonstrated that the ionization wave propagated predominantly over the quartz wall or over the liquid surface adjacent to the grounded waveguide placed along the bottom wall of the test cell. Under all experimental conditions tested, the surface plasma ‘sheet’ was diffuse and fairly uniform, both for positive and negative polarities. The parameters of ionization wave discharge propagating over distilled water and 1-butanol surfaces were close to those of the discharge over a quartz wall. No perturbation of the liquid surface by the discharge was detected. In most cases, the positive polarity surface ionization wave propagated at a higher speed and over a longer distance compared to the negative polarity wave. For all three sets of experiments (surface ionization wave discharge over quartz, water and 1-butanol), wave speed and travel distance decreased with pressure. Diffuse, highly reproducible surface ionization wave discharge was also observed over the liquid butanol–saturated butanol vapor interface, as well as over the distilled water–saturated water vapor interface, without buffer gas flow. No significant difference was detected between surface ionization discharges sustained using single-polarity (positive or negative), or alternating polarity high-voltage pulses. Plasma emission images yielded preliminary evidence of charge

  5. Separation of density and viscosity influence on liquid-loaded surface acoustic wave devices

    Science.gov (United States)

    Herrmann, F.; Hahn, D.; Büttgenbach, S.

    1999-05-01

    Love-mode sensors are reported for separate measurement of liquid density and viscosity. They combine the general merits of Love-mode devices, e.g., ease of sensitivity adjustment and robustness, with a highly effective procedure of separate determination of liquid density and viscosity. A model is proposed to describe the frequency response of the devices to liquid loading. Moreover, design rules are given for further optimization and sensitivity enhancement.

  6. Mechanisms for the control of two-mode transient stimulated Raman scattering in liquids

    International Nuclear Information System (INIS)

    Spanner, Michael; Brumer, Paul

    2006-01-01

    Recent adaptive feedback control experiments demonstrated control of transient (i.e. nonimpulsive) Stokes emission from two closely spaced Raman-active modes in liquid methanol [e.g., B. J. Pearson et al., Phys. Rev. A 63, 063412 (2001)]. Optimally shaped pulses were found that selectively excited one of the two Stokes lines alone, optimized emission from both modes together, or completely suppressed all Stokes emission. Here, two general control mechanisms capable of affecting the ratio of intensities of the Stokes lines are identified. The first is operational when the duration of the pump pulse (t p ) is on the order of the collisional dephasing time (t d ). The ratio of the peak heights of the two Stokes lines can then be controlled by simply varying the duration and/or intensity of the pump pulse. The second operates when 1/t p is on the order of the energy separation of the two Raman modes, and hence when the two Raman modes are coupled due to overlapping nonlinear polarizations that drive the stimulated Raman scattering. In this regime, asymmetry in the spectral amplitudes within the pump pulse can control the asymmetry in the peak heights of the Stokes emission. Both these mechanisms have the same clear physical interpretation: shaping the pump pulse controls the nonlinear optical response of the medium, which in turn controls the stimulated Stokes emission, itself a χ (3) nonlinear effect. In neither mechanism does the ratio of peak heights in the Stokes spectrum reflect directly the ratio of excited-state populations associated with the two Raman modes, as was assumed in the experiments, nor does the control involve coherent quantum interference effects

  7. Adaptive Fuzzy Integral Sliding-Mode Regulator for Induction Motor Using Nonlinear Sliding Surface

    OpenAIRE

    Yong-Kun Lu

    2015-01-01

    An adaptive fuzzy integral sliding-mode controller using nonlinear sliding surface is designed for the speed regulator of a field-oriented induction motor drive in this paper. Combining the conventional integral sliding surface with fractional-order integral, a nonlinear sliding surface is proposed for the integral sliding-mode speed control, which can overcome the windup problem and the convergence speed problem. An adaptive fuzzy control term is utilized to approximate the uncertainty. The ...

  8. Alphas and surface backgrounds in liquid argon dark matter detectors

    Science.gov (United States)

    Stanford, Christopher J.

    Current observations from astrophysics indicate the presence of dark matter, an invisible form of matter that makes up a large part of the mass of the universe. One of the leading theories for dark matter is that it is made up of Weakly Interacting Massive Particles (WIMPs). One of the ways we try to discover WIMPs is by directly detecting their interaction with regular matter. This can be done using a scintillator such as liquid argon, which gives off light when a particle interacts with it. Liquid argon (LAr) is a favorable means of detecting WIMPs because it has an inherent property that enables a technique called pulse-shape discrimination (PSD). PSD can distinguish a WIMP signal from the constant background of electromagnetic signals from other sources, like gamma rays. However, there are other background signals that PSD is not as capable of rejecting, such as those caused by alpha decays on the interior surfaces of the detector. Radioactive elements that undergo alpha decay are introduced to detector surfaces during construction by radon gas that is naturally present in the air, as well as other means. When these surface isotopes undergo alpha decay, they can produce WIMP-like signals in the detector. We present here two LAr experiments. The first (RaDOSE) discovered a property of an organic compound that led to a technique for rejecting surface alpha decays in LAr detectors with high efficiency. The second (DarkSide-50) is a dark matter experiment operated at LNGS in Italy and is the work of an international collaboration. A detailed look is given into alpha decays and surface backgrounds present in the detector, and projections are made of alpha-related backgrounds for 500 live days of data. The technique developed with RaDOSE is applied to DarkSide-50 to determine its effectiveness in practice. It is projected to suppress the surface background in DarkSide-50 by more than a factor of 1000.

  9. Hybrid Surface Plasmon Polariton Modes of Subwavelength Nanowire Resonators

    DEFF Research Database (Denmark)

    Filonenko, Konstantin; Duggen, Lars; Willatzen, Morten

    2015-01-01

    -localized gap plasmon mode are studied depending on the vacuum wavelength. In order to directly compare resonators, where metal and semiconductor nanowires are employed, we consider the two resonators, both including silver slab and magnesium fluoride gap region, as is shown in figure. The two compared......We perform Comsol simulations of two types of hybrid plasmonic resonator configurations, similar to those proposed for nanowire plasmonic laser in [1] and [2]. In both references the nanowire - based plasmonic resonators are studied, which overall sizes are larger than the wavelength in vacuum....... However, it is advantageous for the nanolaser to have subwavelength sizes at least in two dimensions. Therefore, we study the two configurations and the hybrid mode behavior in the case, where resonator sizes are smaller than the half of the wavelength in vacuum. First, we assume finite dimensions...

  10. A liquid aluminum corrosion resistance surface on steel substrate

    International Nuclear Information System (INIS)

    Wang Deqing; Shi Ziyuan; Zou Longjiang

    2003-01-01

    The process of hot dipping pure aluminum on a steel substrate followed by oxidation was studied to form a surface layer of aluminum oxide resistant to the corrosion of aluminum melt. The thickness of the pure aluminum layer on the steel substrate is reduced with the increase in temperature and time in initial aluminizing, and the thickness of the aluminum layer does not increase with time at given temperature when identical temperature and complete wetting occur between liquid aluminum and the substrate surface. The thickness of the Fe-Al intermetallic layer on the steel base is increased with increasing bath temperature and time. Based on the experimental data and the mathematics model developed by the study, a maximum exists in the thickness of the Fe-Al intermetallic at certain dipping temperature. X-ray diffraction (XRD) and energy dispersive X-ray (EDX) analysis reveals that the top portion of the steel substrate is composed of a thin layer of α-Al 2 O 3 , followed by a thinner layer of FeAl 3 , and then a much thicker one of Fe 2 Al 5 on the steel base side. In addition, there is a carbon enrichment zone in diffusion front. The aluminum oxide surface formed on the steel substrate is in perfect condition after corrosion test in liquid aluminum at 750 deg. C for 240 h, showing extremely good resistance to aluminum melt corrosion

  11. Anomalous magnetotransport of a surface electron layer above liquid helium

    International Nuclear Information System (INIS)

    Grigor'ev, V.N.; Kovdrya, Yu.Z.; Nikolaenko, V.A.; Kirichek, O.I.; Shcherbachenko, R.I.

    1991-01-01

    The magnetoconductivity σ xx of a surface electron layer above liquid helium has been measured at temperatures between 0.5-1.6 K, for concentrations up to about 4x10 8 cm -2 , in magnetic fields up to 25 kOe. As was observed, σ xx first decreases with lowering temperature, then has a minimum and at T xy , the earlier ascertained anomalous behaviour of the magnetoresistance ρ xx taken into consideration. The calculated dependence of ρ xx on T is in satisfactory agreement with the anomalous dependence ρ xx (T) found earlier by experiment

  12. Surface passivation of liquid phase epitaxial GaAs

    International Nuclear Information System (INIS)

    Alexiev, D.; Butcher, K.S.A.; Mo, L.; Edmondson, M.

    1995-10-01

    Passivation of the liquid phase epitaxial GaAs surface was attempted using aqueous P 2 S 5 -NH 4 OH, (NH 4 ) 2 S x and plasma nitrogenation and hydrogenation. Results indicate that plasma nitrogenation with pretreatment of plasma hydrogenation produced consistent reduction in reverse leakage current at room temperature for all p and n type Schottky diodes. Some diodes showed an order of magnitude improvement in current density. (NH 4 ) 2 S x passivation also results in improved I-V characteristics, though the long term stability of this passivation is questionable. 26 refs., 6 figs

  13. Vibrational Surface Electron-Energy-Loss Spectroscopy Probes Confined Surface-Phonon Modes

    Directory of Open Access Journals (Sweden)

    Hugo Lourenço-Martins

    2017-12-01

    Full Text Available Recently, two reports [Krivanek et al. Nature (London 514, 209 (2014NATUAS0028-083610.1038/nature13870, Lagos et al. Nature (London 543, 529 (2017NATUAS0028-083610.1038/nature21699] have demonstrated the amazing possibility to probe vibrational excitations from nanoparticles with a spatial resolution much smaller than the corresponding free-space phonon wavelength using electron-energy-loss spectroscopy (EELS. While Lagos et al. evidenced a strong spatial and spectral modulation of the EELS signal over a nanoparticle, Krivanek et al. did not. Here, we show that discrepancies among different EELS experiments as well as their relation to optical near- and far-field optical experiments [Dai et al. Science 343, 1125 (2014SCIEAS0036-807510.1126/science.1246833] can be understood by introducing the concept of confined bright and dark surface phonon modes, whose density of states is probed by EELS. Such a concise formalism is the vibrational counterpart of the broadly used formalism for localized surface plasmons [Ouyang and Isaacson Philos. Mag. B 60, 481 (1989PMABDJ1364-281210.1080/13642818908205921, García de Abajo and Aizpurua Phys. Rev. B 56, 15873 (1997PRBMDO0163-182910.1103/PhysRevB.56.15873, García de Abajo and Kociak Phys. Rev. Lett. 100, 106804 (2008PRLTAO0031-900710.1103/PhysRevLett.100.106804, Boudarham and Kociak Phys. Rev. B 85, 245447 (2012PRBMDO1098-012110.1103/PhysRevB.85.245447]; it makes it straightforward to predict or interpret phenomena already known for localized surface plasmons such as environment-related energy shifts or the possibility of 3D mapping of the related surface charge densities [Collins et al. ACS Photonics 2, 1628 (2015APCHD52330-402210.1021/acsphotonics.5b00421].

  14. Transverse-mode-selectable microlens vertical-cavity surface-emitting laser

    DEFF Research Database (Denmark)

    Chung, Il-Sug; Debernardi, Pierluigi; Lee, Yong Tak

    2010-01-01

    A new vertical-cavity surface-emitting laser structure employing a thin microlens is suggested and numerically investigated. The laser can be made to emit in either a high-power Gaussian-shaped single-fundamental mode or a high-power doughnut-shaped higher-order mode. The physical origin...

  15. Transient surface liquid in Titan's south polar region from Cassini

    Science.gov (United States)

    Hayes, A.G.; Aharonson, O.; Lunine, J.I.; Kirk, R.L.; Zebker, H.A.; Wye, L.C.; Lorenz, R.D.; Turtle, E.P.; Paillou, P.; Mitri, Giuseppe; Wall, S.D.; Stofan, E.R.; Mitchell, K.L.; Elachi, C.

    2011-01-01

    Cassini RADAR images of Titan's south polar region acquired during southern summer contain lake features which disappear between observations. These features show a tenfold increases in backscatter cross-section between images acquired one year apart, which is inconsistent with common scattering models without invoking temporal variability. The morphologic boundaries are transient, further supporting changes in lake level. These observations are consistent with the exposure of diffusely scattering lakebeds that were previously hidden by an attenuating liquid medium. We use a two-layer model to explain backscatter variations and estimate a drop in liquid depth of approximately 1-m-per-year. On larger scales, we observe shoreline recession between ISS and RADAR images of Ontario Lacus, the largest lake in Titan's south polar region. The recession, occurring between June 2005 and July 2009, is inversely proportional to slopes estimated from altimetric profiles and the exponential decay of near-shore backscatter, consistent with a uniform reduction of 4 ± 1.3 m in lake depth. Of the potential explanations for observed surface changes, we favor evaporation and infiltration. The disappearance of dark features and the recession of Ontario's shoreline represents volatile transport in an active methane-based hydrologic cycle. Observed loss rates are compared and shown to be consistent with available global circulation models. To date, no unambiguous changes in lake level have been observed between repeat images in the north polar region, although further investigation is warranted. These observations constrain volatile flux rates in Titan's hydrologic system and demonstrate that the surface plays an active role in its evolution. Constraining these seasonal changes represents the first step toward our understanding of longer climate cycles that may determine liquid distribution on Titan over orbital time periods.

  16. Biaxial potential of surface-stabilized ferroelectric liquid crystals

    Science.gov (United States)

    Kaznacheev, Anatoly; Pozhidaev, Evgeny; Rudyak, Vladimir; Emelyanenko, Alexander V.; Khokhlov, Alexei

    2018-04-01

    A biaxial surface potential Φs of smectic-C* surface-stabilized ferroelectric liquid crystals (SSFLCs) is introduced in this paper to explain the experimentally observed electric-field dependence of polarization P˜cell(E ) , in particular the shape of the static hysteresis loops. Our potential consists of three independent parts. The first nonpolar part Φn describes the deviation of the prime director n (which is the most probable orientation of the long molecular axes) from the easy alignment axis R , which is located in the boundary surface plane. It is introduced in the same manner as the uniaxial Rapini potential. The second part Φp of the potential is a polar term associated with the presence of the polar axis in a FLC. The third part Φm relates to the inherent FLC biaxiality, which has not been taken into consideration previously. The Φm part takes into account the deviations of the secondary director m (which is the most probable orientation of the short molecular axes) from the normal to the boundary surface. The overall surface potential Φs, which is a sum of Φn,Φp , and Φm, allows one to model the conditions when either one, two, or three minima of the SSFLC cell free energy are realized depending on the biaxiality extent. A monodomain or polydomain structure, as well as the bistability or monostability of SSFLC cells, depends on the number of free-energy minima, as confirmed experimentally. In this paper, we analyze the biaxiality impact on the FLC alignment. We also answer the question of whether the bistable or monostable structure can be formed in an SSFLC cell. Our approach is essentially based on a consideration of the biaxial surface potential, while the uniaxial surface potential cannot adequately describe the experimental observations in the FLC.

  17. A quantum-classical simulation of a multi-surface multi-mode ...

    Indian Academy of Sciences (India)

    Multi surface multi mode quantum dynamics; parallelized quantum classical approach; TDDVR method. 1. ... cal simulation on molecular system is a great cha- llenge for ..... on a multiple core cluster with shared memory using. OpenMP based ...

  18. Influence of bounce mode on surface roughness of CH coating on microshells

    International Nuclear Information System (INIS)

    Zhang Baoling; China Academy of Engineering Physics, Mianyang; He Zhibing; Wu Weidong; Liu Xinghua; Ma Xiaojun; Yang Mengsheng; Lin Huaping; Yang Xiangdong

    2008-01-01

    The CH coating on microshells was fabricated by low-pressure plasma chemical vapor deposition (LPPCVD) with a bounce pan system. The influence of bounce modes on the surface topography of the CH coating was discussed. The surface topography was probed by optical microscopy and scanning electron microscopy(SEM). Roughness and sphericity were measured with an atomic force microscopy(AFM). X-radiography was used to obtain the concentricity. The results show that the surface topography of the coating is improved significantly by the intermittent bounce mode, and the roughness of medium high mode is reduced. The surface finish is improved ulteriorly by the intermittent bounce mode as the duty ratio is reduced. The RMS roughness of 30 μm CH coating is less than 30 nm. The spericity and concentricity of hydrocarbon-polystyrene (CH-PS) microshell are all better than 99% when the duty ratio is 1/4. (authors)

  19. Terahertz plasmon and surface-plasmon modes in cylindrical metallic nanowires

    International Nuclear Information System (INIS)

    Wu Ping; Xu Wen; Li Long-Long; Lu Tie-Cheng; Wu Wei-Dong

    2014-01-01

    We present a theoretical study on collective excitation modes associated with plasmon and surface-plasmon oscillations in cylindrical metallic nanowires. Based on a two-subband model, the dynamical dielectric function matrix is derived under the random-phase approximation. An optic-like branch and an acoustic-like branch, which are free of Landau damping, are observed for both plasmon and surface-plasmon modes. Interestingly, for surface-plasmon modes, we find that two branches of the dispersion relation curves converge at a wavevector q z = q max beyond which no surface-plasmon mode exists. Moreover, we examine the dependence of these excitation modes on sample parameters such as the radius of the nanowires. It is found that in metallic nanowires realized by state-of-the-art nanotechnology the intra- and inter-subband plasmon and surface-plasmon frequencies are in the terahertz bandwidth. The frequency of the optic-like modes decreases with increasing radius of the nanowires, whereas that of the acoustic-like modes is not sensitive to the variation of the radius. This study is pertinent to the application of metallic nanowires as frequency-tunable terahertz plasmonic devices. (condensed matter: electronic structure, electrical, magnetic, and optical properties)

  20. Dielectrophoretic deformation of thin liquid films induced by surface charge patterns on dielectric substrates

    NARCIS (Netherlands)

    Berendsen, C.W.J.; Kuijpers, C.J.; Zeegers, J.C.H.; Darhuber, A.A.

    2013-01-01

    We studied the deformation of thin liquid films induced by surface charge patterns at the solid–liquid interface quantitatively by experiments and numerical simulations. We deposited a surface charge distribution on dielectric substrates by applying potential differences between a conductive liquid

  1. Commercial mode-locked vertical external cavity surface emitting lasers

    Science.gov (United States)

    Head, C. Robin; Paboeuf, David; Ortega, Tiago; Lubeigt, Walter; Bialkowski, Bartlomiej; Lin, Jipeng; Hempler, Nils; Maker, Gareth T.; Malcolm, Graeme P. A.

    2018-02-01

    This paper presents the latest efforts in the development of commercial optically-pumped semiconductor disk lasers (SDLs) at M Squared Lasers. Two types of SDLs are currently being developed: an ultrafast system and a continuous wave single frequency system under the names of Dragonfly and Infinite, respectively. Both offer a compact, low-cost, easy-to-use and maintenance-free tool for a range of growing markets including nonlinear microscopy and quantum technology. To facilitate consumer uptake of the SDL technology, the performance specifications aim to closely match the currently employed systems. An extended Dragonfly system is being developed targeting the nonlinear microscopy market, which typically requires 1-W average power pulse trains with pulse durations below 200 fs. The pulse repetition frequency (PRF) of the commonly used laser systems, typically Titanium-sapphire lasers, is 80 MHz. This property is particularly challenging for mode-locked SDLs which tend to operate at GHz repetition rates, due to their short upper state carrier lifetime. Dragonfly has found a compromise at 200 MHz to balance mode-locking instabilities with a low PRF. In the ongoing development of Dragonfly, additional pulse compression and nonlinear spectral broadening stages are used to obtain pulse durations as short as 130 fs with an average power of 0.85 W, approaching the required performance. A variant of the Infinite system was adapted to provide a laser source suitable for the first stage of Sr atom cooling at 461 nm. Such a source requires average powers of approximately 1 W with a sub-MHz linewidth. As direct emission in the blue is not a viable approach at this stage, an SDL emitting at 922 nm followed by an M Squared Lasers SolTiS ECD-X doubler is currently under development. The SDL oscillator delivered >1 W of single frequency (RMS frequency noise <150kHz) light at 922 nm.

  2. Influence of surface effects on subsecond processes in liquid metals

    International Nuclear Information System (INIS)

    Tkachenko, S.I.; Vorob'ev, V.S.; Khishchenko, K.V.

    2001-01-01

    Full Text: We discuss a problem of experimental-data interpretation during subsecond measurements of thermophysical properties of matter at high temperatures and pressures. Peculiarity of these measurements is optical opaqueness of matter under interesting conditions (T∼1 eV, ρ∼10 4 kg m -3 ), so only at assuming of bulk specimen uniformity one can obtain a temperature dependencies of the specific properties of matter. Changing circuit current and changing sample geometry we can avoid a development of hydromagnetic instability and decrease a nonuniform heating due to skin effect. As temperature of wire surface reaches the boiling temperature under normal pressure so part of internal energy is lost because of evaporation and surface radiation at high temperature. So one can register a surface temperature and ascribe it to the whole sample bulk. Computer simulation of wire explosion taking into account surface radiation losses was carried out. Typical phase tracks for matter were obtained in both case as in consideration of radiation losses as without it. Comparison of the results with data concerning to isobaric-expansion experiments and semi-empirical multi-phase equation of state were carried out. It was proposed uniformity criterion for investigation of thermophysical properties of liquid metal by subsecond wire explosion. (author)

  3. In-syringe dispersive liquid-liquid microextraction with liquid chromatographic determination of synthetic pyrethroids in surface water

    Directory of Open Access Journals (Sweden)

    Saeed S. Albaseer

    2012-03-01

    Full Text Available An indigenously fabricated in laboratory glass syringe was used for in-syringe dispersive liquid-liquid microextraction (is-DLLME and preconcentration of synthetic pyrethroids (SPs from surface waters suitable for their determination by high performance liquid chromatography. In contrast to classical DLLME, is-DLLME allows the use of lighter-than-water organic solvents and the analysis of environmental contaminants’ samples without prior filtration, which is of great importance due to the high affinity of pyrethroids to adsorb to solid particulates present in environmental samples. The effects of various parameters on the extraction efficiency were evaluated and optimized systemically using one-factor-at-a-time method (OFAT and statistically using full factorial design (24. Three SPs (viz.; cypermethrin, resmethrin and permethrin were analyzed. The method showed good accuracy with RSD% in the range of of 4.8–6.9%. The method detection limits of the three pesticides ranged from 0.14 to 0.16 ng mL-1. The proposed method was applied for the determination of synthetic pyrethroids in lake water

  4. Development of an on-line mixed-mode gel liquid chromatography×reversed phase liquid chromatography method for separation of water extract from Flos Carthami.

    Science.gov (United States)

    Wang, Yu-Qing; Tang, Xu; Li, Jia-Fu; Wu, Yun-Long; Sun, Yu-Ying; Fang, Mei-Juan; Wu, Zhen; Wang, Xiu-Min; Qiu, Ying-Kun

    2017-10-13

    A novel on-line comprehensive two-dimensional liquid chromatography (2D-LC) method by coupling mixed-mode gel liquid chromatography (MMG-LC) with reversed phase liquid chromatography (RPLC) was developed. A mixture of 17 reference compounds was used to study the separation mechanism. A crude water extract of Flos Carthami was applied to evaluate the performance of the novel 2D-LC system. In the first dimension, the extract was eluted with a gradient of water/methanol over a cross-linked dextran gel Sephadex LH-20 column. Meanwhile, the advantages of size exclusion, reversed phase partition and adsorption separation mechanism were exploited before further on-line reversed phase purification on the second dimension. This novel on-line mixed-mode Sephadex LH-20×RPLC method provided higher peak resolution, sample processing ability (2.5mg) and better orthogonality (72.9%) versus RPLC×RPLC and hydrophilic interaction liquid chromatography (HILIC)×RPLC. To the best of our knowledge, this is the first report of a mixed-mode Sephadex LH-20×RPLC separation method with successful applications in on-line mode, which might be beneficial for harvesting targets from complicated medicinal plants. Copyright © 2017 Elsevier B.V. All rights reserved.

  5. ESR modes in a Strong-Leg Ladder in the Tomonaga-Luttinger Liquid Phase

    Science.gov (United States)

    Zvyagin, S.; Ozerov, M.; Maksymenko, M.; Wosnitza, J.; Honecker, A.; Landee, C. P.; Turnbull, M.; Furuya, S. C.; Giamarchi, T.

    Magnetic excitations in the strong-leg quantum spin ladder compound (C7H10N)2CuBr4 (known as DIMPY) in the field-induced Tomonaga-Luttinger spin liquid phase are studied by means of high-field electron spin resonance (ESR) spectroscopy. The presence of a gapped ESR mode with unusual non-linear frequency-field dependence is revealed experimentally. Using a combination of analytic and exact diagonalization methods, we compute the dynamical structure factor and identify this mode with longitudinal excitations in the antisymmetric channel. We argue that these excitations constitute a fingerprint of the spin dynamics in a strong-leg spin-1/2 Heisenberg antiferromagnetic ladder and owe its ESR observability to the uniform Dzyaloshinskii-Moriya interaction. This work was partially supported by the DFG and Helmholtz Gemeinschaft (Germany), Swiss SNF under Division II, and ERC synergy UQUAM project. We acknowledge the support of the HLD at HZDR, member of the European Magnetic Field Laboratory (EMFL).

  6. Minimizing tip-sample forces in jumping mode atomic force microscopy in liquid

    Energy Technology Data Exchange (ETDEWEB)

    Ortega-Esteban, A. [Departamento de Fisica de la Materia Condensada, C-3, Universidad Autonoma de Madrid, Cantoblanco, 28049 Madrid (Spain); Horcas, I. [Nanotec Electronica S.L., Centro Empresarial Euronova 3, Ronda de Poniente 12, 28760 Tres Cantos, Madrid (Spain); Hernando-Perez, M. [Departamento de Fisica de la Materia Condensada, C-3, Universidad Autonoma de Madrid, Cantoblanco, 28049 Madrid (Spain); Ares, P. [Nanotec Electronica S.L., Centro Empresarial Euronova 3, Ronda de Poniente 12, 28760 Tres Cantos, Madrid (Spain); Perez-Berna, A.J.; San Martin, C.; Carrascosa, J.L. [Centro Nacional de Biotecnologia (CNB-CSIC), Darwin 3, 28049 Madrid (Spain); Pablo, P.J. de [Departamento de Fisica de la Materia Condensada, C-3, Universidad Autonoma de Madrid, Cantoblanco, 28049 Madrid (Spain); Gomez-Herrero, J., E-mail: julio.gomez@uam.es [Departamento de Fisica de la Materia Condensada, C-3, Universidad Autonoma de Madrid, Cantoblanco, 28049 Madrid (Spain)

    2012-03-15

    Control and minimization of tip-sample interaction forces are imperative tasks to maximize the performance of atomic force microscopy. In particular, when imaging soft biological matter in liquids, the cantilever dragging force prevents identification of the tip-sample mechanical contact, resulting in deleterious interaction with the specimen. In this work we present an improved jumping mode procedure that allows detecting the tip-sample contact with high accuracy, thus minimizing the scanning forces ({approx}100 pN) during the approach cycles. To illustrate this method we report images of human adenovirus and T7 bacteriophage particles which are prone to uncontrolled modifications when using conventional jumping mode. -- Highlights: Black-Right-Pointing-Pointer Improvement in atomic force microscopy in buffer solution. Black-Right-Pointing-Pointer Peak force detection. Black-Right-Pointing-Pointer Subtracting the cantilever dragging force. Black-Right-Pointing-Pointer Forces in the 100 pN range. Black-Right-Pointing-Pointer Imaging of delicate viruses with atomic force microscopy.

  7. Mode pattern of internal flow in a water droplet on a vibrating hydrophobic surface.

    Science.gov (United States)

    Kim, Hun; Lim, Hee-Chang

    2015-06-04

    The objective of this study is to understand the mode pattern of the internal flow in a water droplet placed on a hydrophobic surface that periodically and vertically vibrates. As a result, a water droplet on a vibrating hydrophobic surface has a typical shape that depends on each resonance mode, and, additionally, we observed a diversified lobe size and internal flows in the water droplet. The size of each lobe at the resonance frequency was relatively greater than that at the neighboring frequencies, and the internal flow of the nth order mode was also observed in the flow visualization. In general, large symmetrical flow streams were generated along the vertical axis in each mode, with a large circulating movement from the bottom to the top, and then to the triple contact line along the droplet surface. In contrast, modes 2 and 4 generated a Y-shaped flow pattern, in which the flow moved to the node point in the lower part of the droplet, but modes 6 and 8 had similar patterns, with only a little difference. In addition, as a result of the PIV measurement, while the flow velocity of mode 4 was faster than that of model 2, those of modes 6 and 8 were almost similar.

  8. Dual analyzer system for surface analysis dedicated for angle-resolved photoelectron spectroscopy at liquid surfaces and interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Niedermaier, Inga; Kolbeck, Claudia; Steinrück, Hans-Peter; Maier, Florian, E-mail: florian.maier@fau.de [Lehrstuhl für Physikalische Chemie II, FAU Universität Erlangen-Nürnberg, Egerlandstraße 3, 91058 Erlangen (Germany)

    2016-04-15

    The investigation of liquid surfaces and interfaces with the powerful toolbox of ultra-high vacuum (UHV)-based surface science techniques generally has to overcome the issue of liquid evaporation within the vacuum system. In the last decade, however, new classes of liquids with negligible vapor pressure at room temperature—in particular, ionic liquids (ILs)—have emerged for surface science studies. It has been demonstrated that particularly angle-resolved X-ray Photoelectron Spectroscopy (ARXPS) allows for investigating phenomena that occur at gas-liquid and liquid-solid interfaces on the molecular level. The results are not only relevant for IL systems but also for liquids in general. In all of these previous ARXPS studies, the sample holder had to be tilted in order to change the polar detection angle of emitted photoelectrons, which restricted the liquid systems to very thin viscous IL films coating a flat solid support. We now report on the concept and realization of a new and unique laboratory “Dual Analyzer System for Surface Analysis (DASSA)” which enables fast ARXPS, UV photoelectron spectroscopy, imaging XPS, and low-energy ion scattering at the horizontal surface plane of macroscopically thick non-volatile liquid samples. It comprises a UHV chamber equipped with two electron analyzers mounted for simultaneous measurements in 0° and 80° emission relative to the surface normal. The performance of DASSA on a first macroscopic liquid system will be demonstrated.

  9. Dual analyzer system for surface analysis dedicated for angle-resolved photoelectron spectroscopy at liquid surfaces and interfaces

    International Nuclear Information System (INIS)

    Niedermaier, Inga; Kolbeck, Claudia; Steinrück, Hans-Peter; Maier, Florian

    2016-01-01

    The investigation of liquid surfaces and interfaces with the powerful toolbox of ultra-high vacuum (UHV)-based surface science techniques generally has to overcome the issue of liquid evaporation within the vacuum system. In the last decade, however, new classes of liquids with negligible vapor pressure at room temperature—in particular, ionic liquids (ILs)—have emerged for surface science studies. It has been demonstrated that particularly angle-resolved X-ray Photoelectron Spectroscopy (ARXPS) allows for investigating phenomena that occur at gas-liquid and liquid-solid interfaces on the molecular level. The results are not only relevant for IL systems but also for liquids in general. In all of these previous ARXPS studies, the sample holder had to be tilted in order to change the polar detection angle of emitted photoelectrons, which restricted the liquid systems to very thin viscous IL films coating a flat solid support. We now report on the concept and realization of a new and unique laboratory “Dual Analyzer System for Surface Analysis (DASSA)” which enables fast ARXPS, UV photoelectron spectroscopy, imaging XPS, and low-energy ion scattering at the horizontal surface plane of macroscopically thick non-volatile liquid samples. It comprises a UHV chamber equipped with two electron analyzers mounted for simultaneous measurements in 0° and 80° emission relative to the surface normal. The performance of DASSA on a first macroscopic liquid system will be demonstrated.

  10. Visualization of multipolar longitudinal and transversal surface plasmon modes in nanowire dimers.

    Science.gov (United States)

    Alber, Ina; Sigle, Wilfried; Müller, Sven; Neumann, Reinhard; Picht, Oliver; Rauber, Markus; van Aken, Peter A; Toimil-Molares, Maria Eugenia

    2011-12-27

    We study the transversal and longitudinal localized surface plasmon resonances in single nanowires and nanowire dimers excited by the fast traveling electron beam in a transmission electron microscope equipped with high-resolution electron energy-loss spectroscopy. Bright and dark longitudinal modes up to the fifth order are resolved on individual metallic nanowires. On nanowire dimers, mode splitting into bonding and antibonding is measured up to the third order for several dimers with various aspect ratio and controlled gap size. We observe that the electric field maxima of the bonding modes are shifted toward the gap, while the electric field maxima of the antibonding modes are shifted toward the dimer ends. Finally, we observe that the transversal mode is not detected in the region of the dimer gap and decays away from the rod more rapidly than the longitudinal modes.

  11. Strong asymmetry for surface modes in nonlinear lattices with long-range coupling

    International Nuclear Information System (INIS)

    Martinez, Alejandro J.; Vicencio, Rodrigo A.; Molina, Mario I.

    2010-01-01

    We analyze the formation of localized surface modes on a nonlinear cubic waveguide array in the presence of exponentially decreasing long-range interactions. We find that the long-range coupling induces a strong asymmetry between the focusing and defocusing cases for the topology of the surface modes and also for the minimum power needed to generate them. In particular, for the defocusing case, there is an upper power threshold for exciting staggered modes, which depends strongly on the long-range coupling strength. The power threshold for dynamical excitation of surface modes increases (decreases) with the strength of long-range coupling for the focusing (defocusing) cases. These effects seem to be generic for discrete lattices with long-range interactions.

  12. Nonlocal continuum-based modeling of breathing mode of nanowires including surface stress and surface inertia effects

    Science.gov (United States)

    Ghavanloo, Esmaeal; Fazelzadeh, S. Ahmad; Rafii-Tabar, Hashem

    2014-05-01

    Nonlocal and surface effects significantly influence the mechanical response of nanomaterials and nanostructures. In this work, the breathing mode of a circular nanowire is studied on the basis of the nonlocal continuum model. Both the surface elastic properties and surface inertia effect are included. Nanowires can be modeled as long cylindrical solid objects. The classical model is reformulated using the nonlocal differential constitutive relations of Eringen and Gurtin-Murdoch surface continuum elasticity formalism. A new frequency equation for the breathing mode of nanowires, including small scale effect, surface stress and surface inertia is presented by employing the Bessel functions. Numerical results are computed, and are compared to confirm the validity and accuracy of the proposed method. Furthermore, the model is used to elucidate the effect of nonlocal parameter, the surface stress, the surface inertia and the nanowire orientation on the breathing mode of several types of nanowires with size ranging from 0.5 to 4 nm. Our results reveal that the combined surface and small scale effects are significant for nanowires with diameter smaller than 4 nm.

  13. Nonlocal continuum-based modeling of breathing mode of nanowires including surface stress and surface inertia effects

    International Nuclear Information System (INIS)

    Ghavanloo, Esmaeal; Fazelzadeh, S. Ahmad; Rafii-Tabar, Hashem

    2014-01-01

    Nonlocal and surface effects significantly influence the mechanical response of nanomaterials and nanostructures. In this work, the breathing mode of a circular nanowire is studied on the basis of the nonlocal continuum model. Both the surface elastic properties and surface inertia effect are included. Nanowires can be modeled as long cylindrical solid objects. The classical model is reformulated using the nonlocal differential constitutive relations of Eringen and Gurtin–Murdoch surface continuum elasticity formalism. A new frequency equation for the breathing mode of nanowires, including small scale effect, surface stress and surface inertia is presented by employing the Bessel functions. Numerical results are computed, and are compared to confirm the validity and accuracy of the proposed method. Furthermore, the model is used to elucidate the effect of nonlocal parameter, the surface stress, the surface inertia and the nanowire orientation on the breathing mode of several types of nanowires with size ranging from 0.5 to 4 nm. Our results reveal that the combined surface and small scale effects are significant for nanowires with diameter smaller than 4 nm.

  14. Nonlocal continuum-based modeling of breathing mode of nanowires including surface stress and surface inertia effects

    Energy Technology Data Exchange (ETDEWEB)

    Ghavanloo, Esmaeal, E-mail: ghavanloo@shirazu.ac.ir [School of Mechanical Engineering, Shiraz University, Shiraz 71963-16548 (Iran, Islamic Republic of); Fazelzadeh, S. Ahmad [School of Mechanical Engineering, Shiraz University, Shiraz 71963-16548 (Iran, Islamic Republic of); Rafii-Tabar, Hashem [Department of Medical Physics and Biomedical Engineering, Research Center for Medical Nanotechnology and Tissue Engineering, Shahid Beheshti University of Medical Sciences, Evin, Tehran (Iran, Islamic Republic of); Computational Physical Sciences Research Laboratory, School of Nano-Science, Institute for Research in Fundamental Sciences (IPM), Tehran (Iran, Islamic Republic of)

    2014-05-01

    Nonlocal and surface effects significantly influence the mechanical response of nanomaterials and nanostructures. In this work, the breathing mode of a circular nanowire is studied on the basis of the nonlocal continuum model. Both the surface elastic properties and surface inertia effect are included. Nanowires can be modeled as long cylindrical solid objects. The classical model is reformulated using the nonlocal differential constitutive relations of Eringen and Gurtin–Murdoch surface continuum elasticity formalism. A new frequency equation for the breathing mode of nanowires, including small scale effect, surface stress and surface inertia is presented by employing the Bessel functions. Numerical results are computed, and are compared to confirm the validity and accuracy of the proposed method. Furthermore, the model is used to elucidate the effect of nonlocal parameter, the surface stress, the surface inertia and the nanowire orientation on the breathing mode of several types of nanowires with size ranging from 0.5 to 4 nm. Our results reveal that the combined surface and small scale effects are significant for nanowires with diameter smaller than 4 nm.

  15. Ionic liquid nanotribology: stiction suppression and surface induced shear thinning.

    Science.gov (United States)

    Asencio, Rubén Álvarez; Cranston, Emily D; Atkin, Rob; Rutland, Mark W

    2012-07-03

    The friction and adhesion between pairs of materials (silica, alumina, and polytetrafluoroethylene) have been studied and interpreted in terms of the long-ranged interactions present. In ambient laboratory air, the interactions are dominated by van der Waals attraction and strong adhesion leading to significant frictional forces. In the presence of the ionic liquid (IL) ethylammonium nitrate (EAN) the van der Waals interaction is suppressed and the attractive/adhesive interactions which lead to "stiction" are removed, resulting in an at least a 10-fold reduction in the friction force at large applied loads. The friction coefficient for each system was determined; coefficients obtained in air were significantly larger than those obtained in the presence of EAN (which ranged between 0.1 and 0.25), and variation in the friction coefficients between systems was correlated with changes in surface roughness. As the viscosity of ILs can be relatively high, which has implications for the lubricating properties, the hydrodynamic forces between the surfaces have therefore also been studied. The linear increase in repulsive force with speed, expected from hydrodynamic interactions, is clearly observed, and these forces further inhibit the potential for stiction. Remarkably, the viscosity extracted from the data is dramatically reduced compared to the bulk value, indicative of a surface ordering effect which significantly reduces viscous losses.

  16. Effect of Energetic Plasma Flux on Flowing Liquid Lithium Surfaces

    Science.gov (United States)

    Kalathiparambil, Kishor; Jung, Soonwook; Christenson, Michael; Fiflis, Peter; Xu, Wenyu; Szott, Mathew; Ruzic, David

    2014-10-01

    An operational liquid lithium system with steady state flow driven by thermo-electric magneto-hydrodynamic force and capable of constantly refreshing the plasma exposed surface have been demonstrated at U of I. To evaluate the system performance in reactor relevant conditions, specifically to understand the effect of disruptive plasma events on the performance of the liquid metal PFCs, the setup was integrated to a pulsed plasma generator. A coaxial plasma generator drives the plasma towards a theta pinch which preferentially heats the ions, simulating ELM like flux, and the plasma is further guided towards the target chamber which houses the flowing lithium system. The effect of the incident flux is examined using diagnostic tools including triple Langmuir probe, calorimeter, rogowski coils, Ion energy analyzers, and fast frame spectral image acquisition with specific optical filters. The plasma have been well characterized and a density of ~1021 m-3, with electron temperature ~10 - 20 eV is measured, and final plasma velocities of 34 - 74 kms-1 have been observed. Calorimetric measurements using planar molybdenum targets indicate a maximum plasma energy (with 6 kV plasma gun and 20 kV theta pinch) of 0.08 MJm-2 with plasma divergence effects resulting in marginal reduction of 40 +/- 23 J in plasma energy. Further results from the other diagnostic tools, using the flowing lithium targets and the planar targets coated with lithium will be presented. DOE DE-SC0008587.

  17. Surface dependent behaviour of CdS LO-phonon mode

    International Nuclear Information System (INIS)

    Molina-Contreras, J R; Medina-Gutierrez, C; Frausto-Reyes, C; Trejo-Vazquez, R; Villalobos-Pina, F J; Romo-Luevano, G; Calixto, S

    2007-01-01

    In this paper, we develop a sensitive optical method to monitor the surface roughness in the investigation of surfaces. By applying this method to measure the RMS surface roughness of various surfaces, we found RMS values which are comparable to those obtained by atomic force microscopy measurements. In addition, we present a simple empirical model to calculate the RMS surface roughness which shows very good agreement with the surface roughness measurements taken by the method reported in this paper. Finally, the application of our method to the study of the LO-phonon mode of CdS suggests that its intensity is dominated by the surface roughness. This roughness dependent behaviour of the CdS LO-phonon mode is experimentally confirmed by using an excitation wavelength near its E 0 transition

  18. Failure mode and effects analysis and fault tree analysis of surface image guided cranial radiosurgery.

    Science.gov (United States)

    Manger, Ryan P; Paxton, Adam B; Pawlicki, Todd; Kim, Gwe-Ya

    2015-05-01

    Surface image guided, Linac-based radiosurgery (SIG-RS) is a modern approach for delivering radiosurgery that utilizes optical stereoscopic imaging to monitor the surface of the patient during treatment in lieu of using a head frame for patient immobilization. Considering the novelty of the SIG-RS approach and the severity of errors associated with delivery of large doses per fraction, a risk assessment should be conducted to identify potential hazards, determine their causes, and formulate mitigation strategies. The purpose of this work is to investigate SIG-RS using the combined application of failure modes and effects analysis (FMEA) and fault tree analysis (FTA), report on the effort required to complete the analysis, and evaluate the use of FTA in conjunction with FMEA. A multidisciplinary team was assembled to conduct the FMEA on the SIG-RS process. A process map detailing the steps of the SIG-RS was created to guide the FMEA. Failure modes were determined for each step in the SIG-RS process, and risk priority numbers (RPNs) were estimated for each failure mode to facilitate risk stratification. The failure modes were ranked by RPN, and FTA was used to determine the root factors contributing to the riskiest failure modes. Using the FTA, mitigation strategies were formulated to address the root factors and reduce the risk of the process. The RPNs were re-estimated based on the mitigation strategies to determine the margin of risk reduction. The FMEA and FTAs for the top two failure modes required an effort of 36 person-hours (30 person-hours for the FMEA and 6 person-hours for two FTAs). The SIG-RS process consisted of 13 major subprocesses and 91 steps, which amounted to 167 failure modes. Of the 91 steps, 16 were directly related to surface imaging. Twenty-five failure modes resulted in a RPN of 100 or greater. Only one of these top 25 failure modes was specific to surface imaging. The riskiest surface imaging failure mode had an overall RPN-rank of eighth

  19. Non-linear self-reinforced growth of tearing modes with multiple rational surfaces

    International Nuclear Information System (INIS)

    Maschke, E.K.; Persson, M.; Dewar, R.L.; Australian National Univ., Canberra, ACT

    1993-06-01

    The non-linear evolution of tearing modes with multiple rational surfaces is discussed. It is demonstrated that, in the presence of small differential rotation, the non-linear growth might be faster than exponential. This growth occurs as the rotation frequencies of the plasma at the different rational surfaces go into equilibrium

  20. Tamm-plasmon and surface-plasmon hybrid-mode based refractometry in photonic bandgap structures.

    Science.gov (United States)

    Das, Ritwick; Srivastava, Triranjita; Jha, Rajan

    2014-02-15

    The transverse magnetic (TM) polarized hybrid modes formed as a consequence of coupling between Tamm plasmon polariton (TM-TPP) mode and surface plasmon polariton (SPP) mode exhibit interesting dispersive features for realizing a highly sensitive and accurate surface plasmon resonance (SPR) sensor. We found that the TM-TPP modes, formed at the interface of distributed Bragg reflector and metal, are strongly dispersive as compared to SPP modes at optical frequencies. This causes an appreciably narrow interaction bandwidth between TM-TPP and SPP modes, which leads to highly accurate sensing. In addition, appropriate tailoring of dispersion characteristics of TM-TPP as well as SPP modes could ensure high sensitivity of a novel SPR platform. By suitably designing the Au/TiO₂/SiO₂-based geometry, we propose a TM-TPP/SPP hybrid-mode sensor and achieve a sensitivity ≥900  nm/RIU with high detection accuracy (≥30  μm⁻¹) for analyte refractive indices varying between 1.330 and 1.345 in 600-700 nm wavelength range. The possibility to achieve desired dispersive behavior in any spectral band makes the sensing configuration an extremely attractive candidate to design sensors depending on the availability of optical sources.

  1. Bulk chirality effect for symmetric bistable switching of liquid crystals on topologically self-patterned degenerate anchoring surface.

    Science.gov (United States)

    Park, Min-Kyu; Joo, Kyung-Il; Kim, Hak-Rin

    2017-06-26

    We demonstrate a bistable switching liquid crystal (LC) mode utilizing a topologically self-structured dual-groove surface for degenerated easy axes of LC anchoring. In our study, the effect of the bulk elastic distortion of the LC directors on the bistable anchoring surface is theoretically analyzed for balanced bistable states based on a free energy diagram. By adjusting bulk LC chirality, we developed ideally symmetric and stable bistable anchoring and switching properties, which can be driven by a low in-plane pulsed field of about 0.7 V/µm. The fabricated device has a contrast ratio of 196:1.

  2. A study on changes in body surface temperature and thermal effect according to ultrasound mode

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Sung Hee [Dept. of Radiology, Ilsin Christian Hospital, Busan (Korea, Republic of); Lee, Jin Soo [Dept. of Radiology, University Haeundae Paik Hospital, Busan (Korea, Republic of)

    2017-06-15

    Recently, as the number of high-risk pregnancies increases, the use of new techniques such as Doppler, which have higher acoustic power than in the past, has been increasingly used in prenatal diagnosis and guidelines have been set up by various organizations to prevent excessive exposure. Therefore, in this study, we tried to investigate the temperature change of the body surface for each test mode according to the long time ultrasound examination and to examine the exposure time which is not influenced by the thermal effect. B mode, C mode, and PD mode according to time, and the temperature difference between exposed and unexposed sites were compared. As a result, the B mode showed a significant difference in the temperature change from 10 minutes, 50 minutes after exposed, 20 minutes from the C mode, and 30 minutes from the PD mode (p<0.01). In all three modes, the temperature difference was different(p<0.000), and PD mode was the most sensitive to temperature change. Also, it was found that the temperature rise time was shortened with the increase of the ultrasonic exposure time. Therefore, it is recommended that ultrasonography to observe the embryo or fetus should be used only for diagnostic purposes, avoiding excessive test time.

  3. Liquid--liquid surface impaction. Annual progress report, July 1, 1975--June 30, 1976

    International Nuclear Information System (INIS)

    Bankoff, S.G.

    1976-01-01

    The critical Weber number for coalescence, when a droplet of Freon-22 or pentane falls on a pool of hot (80-180 0 C) silicone oil or glycerine, has been determined as a function of pool temperature and droplet size. Using this information, a splash theory for local propagation of a vapor explosion has been formulated, which agrees with intermediate-scale peak pressure data of Henry, et al. A hydrodynamic theory has been constructed for the minimum thickness of the gas film in the approach phase. The Board-Hall theory for fuel-coolant detonation waves has been modified to take into account the presence of a swarm of drops, rather than a single drop. On this basis the existence of a steady-state Chapman-Jouguet wave in either the tin-water or UO 2 -sodium systems seems highly unlikely. Scoping experiments on Leidenfrost boiling of droplets and pool boiling from liquid metal surfaces have been initiated

  4. Surface alignment of liquid crystal multilayers evaporated on a photoaligned polyimide film observed by surface profiler

    International Nuclear Information System (INIS)

    Oo, T.N.; Iwata, T.; Kimura, M.; Akahane, T.

    2005-01-01

    The investigation of the surface alignment of liquid crystal (LC) multilayers evaporated on a photoaligned polyimide vertical alignment (PI-VA) film was carried out by means of a novel three-dimensional (3-D) surface profiler. The photoinduced anisotropy of the partially UV-exposed PI-VA film can be visualized as a topological image of LC multilayers. It seems that the topology of LC multilayers is indicating the orientational distribution of LC molecules on the treated film. Moreover, it was shown that the surface profiler can be used to produce non-contact images with high vertical resolution (∼ 0.01 nm). Copyright (2003) AD-TECH - International Foundation for the Advancement of Technology Ltd

  5. Spatially resolved localized vibrational mode spectroscopy of carbon in liquid encapsulated Czochralski grown gallium arsenide wafers

    International Nuclear Information System (INIS)

    Yau, Waifan.

    1988-04-01

    Substitutional carbon on an arsenic lattice site is the shallowest and one of the most dominant acceptors in semi-insulating Liquid Encapsulated Czochralski (LEC) GaAs. However, the role of this acceptor in determining the well known ''W'' shape spatial variation of neutral EL2 concentration along the diameter of a LEC wafer is not known. In this thesis, we attempt to clarify the issue of the carbon acceptor's effect on this ''W'' shaped variation by measuring spatial profiles of this acceptor along the radius of three different as-grown LEC GaAs wafers. With localized vibrational mode absorption spectroscopy, we find that the profile of the carbon acceptor is relatively constant along the radius of each wafer. Average values of concentration are 8 x 10E15 cm -3 , 1.1 x 10E15 cm -3 , and 2.2 x 10E15 cm -3 , respectively. In addition, these carbon acceptor LVM measurements indicate that a residual donor with concentration comparable to carbon exists in these wafers and it is a good candidate for the observed neutral EL2 concentration variation. 22 refs., 39 figs

  6. System upgradation for surface mode negative ion beam extraction experiments in ROBIN

    International Nuclear Information System (INIS)

    Pandya, Kaushal; Bansal, Gourab; Gahlaut, Agrajit; Soni, Jignesh; Yadav, Ratnakar K.; Mahesh, Vuppugalla; Tyagi, Himanshu; Parmar, KanuG.; Mistri, Hiren; Bhagora, Jighesh; Prajapati, Bhavesh; Patel, Kartik; Bhuyan, Manas; Gouswami, Mehul; Bandyopadhyay, Mainak; Chakraborty, Arun K.

    2017-01-01

    Operational commissioning of ROBIN forms an important milestone in the Indian programme on the R&D on negative ion beams. The commissioning activity has been effected in sequence, in synchronisation with the availability of High voltage Power Supply (HVPS) systems and routine operation has now been established in the cesiated, surface mode. Significant efforts have been placed in upgrading the system to initiate the surface mode operation. These include incorporation of a temperature controlled Cesium (Cs) delivery system, spectroscopic diagnostics for detection of Cs lines, installation of plasma grid heating and closed loop warm water circuit for source components heating and Doppler Shift Spectroscopy (DSS) system. The specific design and integration features for these upgrades are discussed and preliminary results obtained from the operation of ROBIN in the surface mode are presented.

  7. Terminal Sliding Mode Control with Unidirectional Auxiliary Surfaces for Hypersonic Vehicles Based on Adaptive Disturbance Observer

    Directory of Open Access Journals (Sweden)

    Naibao He

    2015-01-01

    Full Text Available A novel flight control scheme is proposed using the terminal sliding mode technique, unidirectional auxiliary surfaces and the disturbance observer model. These proposed dynamic attitude control systems can improve control performance of hypersonic vehicles despite uncertainties and external disturbances. The terminal attractor is employed to improve the convergence rate associated with the critical damping characteristics problem noted in short-period motions of hypersonic vehicles. The proposed robust attitude control scheme uses a dynamic terminal sliding mode with unidirectional auxiliary surfaces. The nonlinear disturbance observer is designed to estimate system uncertainties and external disturbances. The output of the disturbance observer aids the robust adaptive control scheme and improves robust attitude control performance. Finally, simulation results are presented to illustrate the effectiveness of the proposed terminal sliding mode with unidirectional auxiliary surfaces.

  8. Cladding defects in hollow core fibers for surface mode suppression and improved birefringence

    DEFF Research Database (Denmark)

    Michieletto, Mattia; Lyngso, J. K.; Lægsgaard, Jesper

    2014-01-01

    We demonstrate a novel polarization maintaining hollow-core photonic bandgap fiber geometry that reduces the impact of surface modes on fiber transmission. The cladding structure is modified with a row of partially collapsed holes to strip away unwanted surface modes. A theoretical investigation...... of the surface mode stripping is presented and compared to the measured performance of four 7-cells core fibers that were drawn with different collapse ratio of the defects. The varying pressure along the defect row in the cladding during drawing introduces an ellipticity of the core. This, combined...... with the presence of antiresonant features on the core wall, makes the fibers birefringent, with excellent polarization maintaining properties. (C) 2014 Optical Society of America...

  9. System upgradation for surface mode negative ion beam extraction experiments in ROBIN

    Energy Technology Data Exchange (ETDEWEB)

    Pandya, Kaushal, E-mail: kpandya@ipr.res.in [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar, 382428, Gujarat (India); Bansal, Gourab; Gahlaut, Agrajit; Soni, Jignesh [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar, 382428, Gujarat (India); Yadav, Ratnakar K. [ITER-India, Institute for Plasma Research, Gandhinagar, Gujarat (India); Mahesh, Vuppugalla [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar, 382428, Gujarat (India); Tyagi, Himanshu [ITER-India, Institute for Plasma Research, Gandhinagar, Gujarat (India); Parmar, KanuG.; Mistri, Hiren [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar, 382428, Gujarat (India); Bhagora, Jighesh [ITER-India, Institute for Plasma Research, Gandhinagar, Gujarat (India); Prajapati, Bhavesh; Patel, Kartik [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar, 382428, Gujarat (India); Bhuyan, Manas [ITER-India, Institute for Plasma Research, Gandhinagar, Gujarat (India); Gouswami, Mehul [Bhakti Management Services, Gandhinagar, 382007, Gujarat (India); Bandyopadhyay, Mainak [ITER-India, Institute for Plasma Research, Gandhinagar, Gujarat (India); Chakraborty, Arun K. [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar, 382428, Gujarat (India)

    2017-01-15

    Operational commissioning of ROBIN forms an important milestone in the Indian programme on the R&D on negative ion beams. The commissioning activity has been effected in sequence, in synchronisation with the availability of High voltage Power Supply (HVPS) systems and routine operation has now been established in the cesiated, surface mode. Significant efforts have been placed in upgrading the system to initiate the surface mode operation. These include incorporation of a temperature controlled Cesium (Cs) delivery system, spectroscopic diagnostics for detection of Cs lines, installation of plasma grid heating and closed loop warm water circuit for source components heating and Doppler Shift Spectroscopy (DSS) system. The specific design and integration features for these upgrades are discussed and preliminary results obtained from the operation of ROBIN in the surface mode are presented.

  10. Observation of a new surface mode on a fluid-saturated permeable solid

    International Nuclear Information System (INIS)

    Nagy, P.B.

    1992-01-01

    Almost ten years ago, S. Feng and D. L. Johnson predicted the presence of a new surface mode on a fluid/fluid-saturated porous solid interface with closed surface pores [J. Acoust. Soc. Am. 74, 906 (1983)]. We found that, due to surface tension, practically closed-pore boundary conditions can prevail at an interface between a nonwetting fluid (e.g., air) and a porous solid saturated with a wetting fluid (e.g., water or alcohol). Surface wave velocity and attenuation measurements were made on alcohol-saturated porous sintered glass at 100 kHz. The experimental results show clear evidence of the new ''slow'' surface mode predicted by Feng and Johnson

  11. Source signature estimation from multimode surface waves via mode-separated virtual real source method

    Science.gov (United States)

    Gao, Lingli; Pan, Yudi

    2018-05-01

    The correct estimation of the seismic source signature is crucial to exploration geophysics. Based on seismic interferometry, the virtual real source (VRS) method provides a model-independent way for source signature estimation. However, when encountering multimode surface waves, which are commonly seen in the shallow seismic survey, strong spurious events appear in seismic interferometric results. These spurious events introduce errors in the virtual-source recordings and reduce the accuracy of the source signature estimated by the VRS method. In order to estimate a correct source signature from multimode surface waves, we propose a mode-separated VRS method. In this method, multimode surface waves are mode separated before seismic interferometry. Virtual-source recordings are then obtained by applying seismic interferometry to each mode individually. Therefore, artefacts caused by cross-mode correlation are excluded in the virtual-source recordings and the estimated source signatures. A synthetic example showed that a correct source signature can be estimated with the proposed method, while strong spurious oscillation occurs in the estimated source signature if we do not apply mode separation first. We also applied the proposed method to a field example, which verified its validity and effectiveness in estimating seismic source signature from shallow seismic shot gathers containing multimode surface waves.

  12. Identification of surface species by vibrational normal mode analysis. A DFT study

    Science.gov (United States)

    Zhao, Zhi-Jian; Genest, Alexander; Rösch, Notker

    2017-10-01

    Infrared spectroscopy is an important experimental tool for identifying molecular species adsorbed on a metal surface that can be used in situ. Often vibrational modes in such IR spectra of surface species are assigned and identified by comparison with vibrational spectra of related (molecular) compounds of known structure, e. g., an organometallic cluster analogue. To check the validity of this strategy, we carried out a computational study where we compared the normal modes of three C2Hx species (x = 3, 4) in two types of systems, as adsorbates on the Pt(111) surface and as ligands in an organometallic cluster compound. The results of our DFT calculations reproduce the experimental observed frequencies with deviations of at most 50 cm-1. However, the frequencies of the C2Hx species in both types of systems have to be interpreted with due caution if the coordination mode is unknown. The comparative identification strategy works satisfactorily when the coordination mode of the molecular species (ethylidyne) is similar on the surface and in the metal cluster. However, large shifts are encountered when the molecular species (vinyl) exhibits different coordination modes on both types of substrates.

  13. Imaging surface nanobubbles at graphite–water interfaces with different atomic force microscopy modes

    International Nuclear Information System (INIS)

    Yang, Chih-Wen; Lu, Yi-Hsien; Hwang, Ing-Shouh

    2013-01-01

    We have imaged nanobubbles on highly ordered pyrolytic graphite (HOPG) surfaces in pure water with different atomic force microscopy (AFM) modes, including the frequency-modulation, the tapping, and the PeakForce techniques. We have compared the performance of these modes in obtaining the surface profiles of nanobubbles. The frequency-modulation mode yields a larger height value than the other two modes and can provide more accurate measurement of the surface profiles of nanobubbles. Imaging with PeakForce mode shows that a nanobubble appears smaller and shorter with increasing peak force and disappears above a certain peak force, but the size returns to the original value when the peak force is reduced. This indicates that imaging with high peak forces does not cause gas removal from the nanobubbles. Based on the presented findings and previous AFM observations, the existing models for nanobubbles are reviewed and discussed. The model of gas aggregate inside nanobubbles provides a better explanation for the puzzles of the high stability and the contact angle of surface nanobubbles. (paper)

  14. Method of driving liquid flow at or near the free surface using magnetic microparticles

    Science.gov (United States)

    Snezhko, Oleksiy [Woodridge, IL; Aronson, Igor [Darien, IL; Kwok, Wai-Kwong [Evanston, IL; Belkin, Maxim V [Woodridge, IL

    2011-10-11

    The present invention provides a method of driving liquid flow at or near a free surface using self-assembled structures composed of magnetic particles subjected to an external AC magnetic field. A plurality of magnetic particles are supported at or near a free surface of liquid by surface tension or buoyancy force. An AC magnetic field traverses the free surface and dipole-dipole interaction between particles produces in self-assembled snake structures which oscillate at the frequency of the traverse AC magnetic field. The snake structures independently move across the free surface and may merge with other snake structures or break up and coalesce into additional snake structures experiencing independent movement across the liquid surface. During this process, the snake structures produce asymmetric flow vortices across substantially the entirety of the free surface, effectuating liquid flow across the free surface.

  15. Asymptotic theory of dissipative trapped electron mode overlapping many rational surfaces

    International Nuclear Information System (INIS)

    Rogister, A.; Hasselberg, G.

    1978-01-01

    The two dimensional eigenvalue equation describing the dissipative trapped electron mode is solved exactly in the limit of the mode overlapping many rational surfaces using the Pogutse model for the magnetic field and the pitch angle collision operator. The trapped electron contribution to the growth rate decreases, with respect to the standard theory, by a factor of order Δ/chi sub(T) << 1 where chi sub(T) is the position of the turning point and Δ the distance between rational surfaces

  16. Stabilization of an Underactuated Surface Vessel Based on Adaptive Sliding Mode and Backstepping Control

    Directory of Open Access Journals (Sweden)

    Fuguang Ding

    2013-01-01

    Full Text Available The paper studied controlling problem of an underactuated surface vessel with unknown interferences. It proved that the control problem of underactuated surface vessel can be transformed into the stabilization analysis of two small subsystems. This controller was designed by backstepping method and adaptive sliding mode, was suitable for solving the problem of the control of higher systems, can keep the system global asymptotic stability, and can inhibit unknown interference, and boundary layer can weaken the buffeting generated by sliding mode. The unknown interference was estimated by adaptive function. Finally, the simulation results are given to demonstrate the effectiveness of the proposed control laws.

  17. Effect of surface modes on coupling to fast waves in the LHRF

    International Nuclear Information System (INIS)

    Pinsker, R.I.; Colestock, P.L.

    1990-01-01

    The effect of surface modes of propagation on coupling to fast waves in the LHRF is studied theoretically and experimentally. The previously reported 'up-down' poloidal phasing asymmetry for coupling to a uniform plasma is shown to be due to the properties of a mode which carries energy along the plasma-conducting wall interface. Comparison of the theory with coupling experiments performed on the PLT tokamak with a phased array of twelve dielectric-loaded waveguides at 800 MHz shows that the observed dependence of the net reflection coefficient on toroidal phase angle can be explained only if the surface wave is taken into account. 43 refs., 10 figs

  18. Comprehensive analysis of pharmaceutical products using simultaneous mixed-mode (ion-exchange/reversed-phase) and hydrophilic interaction liquid chromatography.

    Science.gov (United States)

    Kazarian, Artaches A; Nesterenko, Pavel N; Soisungnoen, Phimpha; Burakham, Rodjana; Srijaranai, Supalax; Paull, Brett

    2014-08-01

    Liquid chromatographic assays were developed using a mixed-mode column coupled in sequence with a hydrophilic interaction liquid chromatography column to allow the simultaneous comprehensive analysis of inorganic/organic anions and cations, active pharmaceutical ingredients, and excipients (carbohydrates). The approach utilized dual sample injection and valve-mediated column switching and was based upon a single high-performance liquid chromatography gradient pump. The separation consisted of three distinct sequential separation mechanisms, namely, (i) ion-exchange, (ii) mixed-mode interactions under an applied dual gradient (reversed-phase/ion-exchange), and (iii) hydrophilic interaction chromatography. Upon first injection, the Scherzo SS C18 column (Imtakt) provided resolution of inorganic anions and cations under isocratic conditions, followed by a dual organic/salt gradient to elute active pharmaceutical ingredients and their respective organic counterions and potential degradants. At the top of the mixed-mode gradient (high acetonitrile content), the mobile phase flow was switched to a preconditioned hydrophilic interaction liquid chromatography column, and the standard/sample was reinjected for the separation of hydrophilic carbohydrates, some of which are commonly known excipients in drug formulations. The approach afforded reproducible separation and resolution of up to 23 chemically diverse solutes in a single run. The method was applied to investigate the composition of commercial cough syrups (Robitussin®), allowing resolution and determination of inorganic ions, active pharmaceutical ingredients, excipients, and numerous well-resolved unknown peaks. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Modelling and characterization of the roof tile-shaped modes of AlN-based cantilever resonators in liquid media

    International Nuclear Information System (INIS)

    Ruiz-Díez, V; Hernando-García, J; Toledo, J; Manzaneque, T; Sánchez-Rojas, J L; Kucera, M; Pfusterschmied, G; Schmid, U

    2016-01-01

    In this work, roof tile-shaped modes of MEMS (micro electro-mechanical systems) cantilever resonators with various geometries and mode orders are analysed. These modes can be efficiently excited by a thin piezoelectric film and a properly designed top electrode. The electrical and optical characterization of the resonators are performed in liquid media and the device performance is evaluated in terms of quality factor, resonant frequency and motional conductance. A quality factor as high as 165 was measured in isopropanol for a cantilever oscillating in the seventh order roof tile-shaped mode at 2 MHz. To support the results of the experimental characterization, a 2D finite element method simulation model is presented and studied. An analytical model for the estimation of the motional conductance was also developed and validated with the experimental measurements. (paper)

  20. Ultraviolet curing of acrylated liquid natural rubber for surface coating application

    OpenAIRE

    Kannikar Kwanming; Pairote Klinpituksa; Wae-asae Waehamad

    2009-01-01

    Ultraviolet curable acrylated liquid natural rubber was prepared by grafting of photosensitive molecule onto liquid natural rubber for surface coating application. The liquid natural rubber (LNR) was firstly obtained by degradation of natural rubber latex with hydrogen peroxide and cobalt acetylacetonate at 65oC for 72 hrs. The preparation of acrylated natural rubber was carried out by the reaction of acrylic acid and epoxidized liquid natural rubber (ELNR) prior obtained from LNR with formic...

  1. Crystallization of glass-forming liquids: Specific surface energy

    International Nuclear Information System (INIS)

    Schmelzer, Jürn W. P.; Abyzov, Alexander S.

    2016-01-01

    A generalization of the Stefan-Skapski-Turnbull relation for the melt-crystal specific interfacial energy is developed in terms of the generalized Gibbs approach extending its standard formulation to thermodynamic non-equilibrium states. With respect to crystal nucleation, this relation is required in order to determine the parameters of the critical crystal clusters being a prerequisite for the computation of the work of critical cluster formation. As one of its consequences, a relation for the dependence of the specific surface energy of critical clusters on temperature and pressure is derived applicable for small and moderate deviations from liquid-crystal macroscopic equilibrium states. Employing the Stefan-Skapski-Turnbull relation, general expressions for the size and the work of formation of critical crystal clusters are formulated. The resulting expressions are much more complex as compared to the respective relations obtained via the classical Gibbs theory. Latter relations are retained as limiting cases of these more general expressions for moderate undercoolings. By this reason, the formulated, here, general relations for the specification of the critical cluster size and the work of critical cluster formation give a key for an appropriate interpretation of a variety of crystallization phenomena occurring at large undercoolings which cannot be understood in terms of the Gibbs’ classical treatment.

  2. The structure of organic langmuir films on liquid metal surfaces

    International Nuclear Information System (INIS)

    Kraack, H.; Deutsch, M.; Ocko, B.M.; Pershan, P.S.

    2003-01-01

    Langmuir films (LFs) on water have long been studied for their interest for basic science and their numerous applications in chemistry, physics, materials science and biology. We present here A-resolution synchrotron X-ray studies of the structure of stearic acid LFs on a liquid mercury surface. At low coverage, ≥110 A 2 /mol, a 2D gas phase of flat-lying molecules is observed. At high coverage, ≤23 A 2 /mol, two different hexatic phases of standing-up molecules are observed. At intermediate coverage, 52≤A≤110 A 2 /mol, novel single- and double-layered phases of flat-lying molecular dimers are found, exhibiting a 1D in-layer order. Such flat-lying phases were not hitherto observed in any LF. Measurements on LFs of fatty acids of other chain lengths indicate that this structure is generic to chain molecules on mercury, although the existence of some of the flat-lying phases, and the observed phase sequence, depend on the chain length. Organic LFs on Hg, and in particular the new flat-lying phases, should provide a broader nano-structural tunability range for molecular electronic device construction than most solid-supported self-assembled monolayers used at present

  3. PERFORMANCE, EMISSION, AND COMBUSTION CHARACTERISTICS OF A CI ENGINE USING LIQUID PETROLEUM GAS AND NEEM OIL IN DUAL FUEL MODE

    Directory of Open Access Journals (Sweden)

    Palanimuthu Vijayabalan

    2010-01-01

    Full Text Available Increased environmental awareness and depletion of resources are driving the industries to develop viable alternative fuels like vegetable oils, compresed natural gas, liquid petroleum gas, producer gas, and biogas in order to provide suitable substitute to diesel for compression ignition engine. In this investigation, a single cylinder, vertical, air-cooled diesel engine was modified to use liquid petroleum gas in dual fuel mode. The liquefied petroleum gas, was mixed with air and supplied through intake manifold. The liquid fuel neem oil or diesel was injected into the combustion chamber. The performance, emission, and combustion characteristics were studied and compared for neat fuel and dual fuel mode. The experimental results on dual fuel engine show a reduction in oxides of nitrogen up to 70% of the rated power and smoke in the entire power range. However the brake thermal efficiency was found decreased in low power range due to lower calorific value of liquid petroleum gas, and increase in higher power range due to the complete burning of liquid petroleum gas. Hydrocarbon and carbon monoxide emissions were increased significantly at lower power range and marginal variation in higher power range.

  4. Physics of foam formation on a solid surface in carbonated liquids

    NARCIS (Netherlands)

    Zuidberg, A.F.

    1997-01-01

    The amount and size of bubbles in a foam layer that have originated from a solid surface in a gas supersaturated solution is largely determined by the physical properties of that solid and liquid surface and the supersaturation level of the gas in the liquid. The presence of pre-existent

  5. The surface tension of pure liquids. Thermodynamic components and corresponding states

    NARCIS (Netherlands)

    Lyklema, J.

    1999-01-01

    From the temperature dependency of surface and interfacial tensions the surface excess energy and entropy per unit area can be obtained. The excess energy is a liquid-specific property; it varies over about three decades between liquid helium and molten metals. On the other hand, the excess entropy

  6. Fine tuning the ionic liquid-vacuum outer atomic surface using ion mixtures.

    Science.gov (United States)

    Villar-Garcia, Ignacio J; Fearn, Sarah; Ismail, Nur L; McIntosh, Alastair J S; Lovelock, Kevin R J

    2015-03-28

    Ionic liquid-vacuum outer atomic surfaces can be created that are remarkably different from the bulk composition. In this communication we demonstrate, using low-energy ion scattering (LEIS), that for ionic liquid mixtures the outer atomic surface shows significantly more atoms from anions with weaker cation-anion interactions (and vice versa).

  7. Tetra point wetting at the free surface of liquid Ga-Bi

    International Nuclear Information System (INIS)

    Huber, P.; Shpyrko, O.G.; Pershan, P.S.; Ocko, B.M.; Di Masi, E.; Deutsch, M.

    2002-01-01

    A continuous surface wetting transition, pinned to a solid-liquid-liquid-vapor tetra coexistence point, is studied by x-ray reflectivity in liquid Ga-Bi binary alloys. The short-range surface potential is determined from the measured temperature evolution of the wetting film. The thermal fluctuations are shown to be insufficient to induce a noticeable breakdown of mean-field behavior, expected in short-range-interacting systems due to their d u =3 upper critical dimensionality

  8. Acoustic streaming in simplified liquid rocket engines with transverse mode oscillations

    Science.gov (United States)

    Fischbach, Sean R.; Flandro, Gary A.; Majdalani, Joseph

    2010-06-01

    This study considers a simplified model of a liquid rocket engine in which uniform injection is imposed at the faceplate. The corresponding cylindrical chamber has a small length-to-diameter ratio with respect to solid and hybrid rockets. Given their low chamber aspect ratios, liquid thrust engines are known to experience severe tangential and radial oscillation modes more often than longitudinal ones. In order to model this behavior, tangential and radial waves are superimposed onto a basic mean-flow model that consists of a steady, uniform axial velocity throughout the chamber. Using perturbation tools, both potential and viscous flow equations are then linearized in the pressure wave amplitude and solved to the second order. The effects of the headwall Mach number are leveraged as well. While the potential flow analysis does not predict any acoustic streaming effects, the viscous solution carried out to the second order gives rise to steady secondary flow patterns near the headwall. These axisymmetric, steady contributions to the tangential and radial traveling waves are induced by the convective flow motion through interactions with inertial and viscous forces. We find that suppressing either the convective terms or viscosity at the headwall leads to spurious solutions that are free from streaming. In our problem, streaming is initiated at the headwall, within the boundary layer, and then extends throughout the chamber. We find that nonlinear streaming effects of tangential and radial waves act to alter the outer solution inside a cylinder with headwall injection. As a result of streaming, the radial wave velocities are intensified in one-half of the domain and reduced in the opposite half at any instant of time. Similarly, the tangential waves are either enhanced or weakened in two opposing sectors that are at 90° angle to the radial velocity counterparts. The second-order viscous solution that we obtain clearly displays both an oscillating and a steady flow

  9. Fingerprinting of traditional Chinese medicines on the C18-Diol mixed-mode column in online or offline two-dimensional liquid chromatography on the single column modes.

    Science.gov (United States)

    Wang, Qing; Tong, Ling; Yao, Lin; Zhang, Peng; Xu, Li

    2016-06-05

    In the present study, a mixed-mode stationary phase, C18-Diol, was applied for fingerprint analysis of traditional Chinese medicines. Hydrophobic, hydrogen bonding and electrostatic interactions were demonstrated to contribute the retention separately or jointly, which endowed the C18-Diol stationary phase with distinct selectivity compared to the bare C18 one. The separation of total alkaloids extracted from Fritillaria hupehensis was compared on the C18-Diol and conventional C18 column with the greater resolving power and better symmetry responses on the former one. Besides, a novel two-dimensional liquid chromatography on the single column (2D-LC-1C) was realized on C18-Diol with the offline mode for the alcohol extract of Fritillaria hupehensis and online mode for Ligusticum chuanxiong Hort. The early co-eluted extracted components with great polarity on the first dimension were reinjected on the same column and well separated on the second dimension. The results exhibited that the two complementary RPLC and HILIC modes on C18-Diol stationary phase enhanced the separation capacity and revealed more abundant chemical information of the sample, which was a powerful tool in analyzing complex herbal medicines. Copyright © 2016 Elsevier B.V. All rights reserved.

  10. Mobile Interfaces: Liquids as a Perfect Structural Material for Multifunctional, Antifouling Surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Grinthal, A; Aizenberg, J

    2014-01-14

    Life creates some of its most robust, extreme surface materials not from solids but from liquids: a purely liquid interface, stabilized by underlying nanotexture, makes carnivorous plant leaves ultraslippery, the eye optically perfect and dirt-resistant, our knees lubricated and pressure-tolerant, and insect feet reversibly adhesive and shape-adaptive. Novel liquid surfaces based on this idea have recently been shown to display unprecedented omniphobic, self-healing, anti-ice, antifouling, optical, and adaptive properties. In this Perspective, we present a framework and a path forward for developing and designing such liquid surfaces into sophisticated, versatile multifunctional materials. Drawing on concepts from solid materials design and fluid dynamics, we outline how the continuous dynamics, responsiveness, and multiscale patternability of a liquid surface layer can be harnessed to create a wide range of unique, active interfacial functions able to operate in harsh, changing environments not achievable with static solids. We discuss how, in partnership with the underlying substrate, the liquid surface can be programmed to adaptively and reversibly reconfigure from a defect-free, molecularly smooth, transparent interface through a range of finely tuned liquid topographies in response to environmental stimuli. With nearly unlimited design possibilities and unmatched interfacial properties, liquid materials as long-term stable interfaces yet in their fully liquid state may potentially transform surface design everywhere from medicine to architecture to energy infrastructure.

  11. Mode Specific Electronic Friction in Dissociative Chemisorption on Metal Surfaces: H2 on Ag(111)

    Science.gov (United States)

    Maurer, Reinhard J.; Jiang, Bin; Guo, Hua; Tully, John C.

    2017-06-01

    Electronic friction and the ensuing nonadiabatic energy loss play an important role in chemical reaction dynamics at metal surfaces. Using molecular dynamics with electronic friction evaluated on the fly from density functional theory, we find strong mode dependence and a dominance of nonadiabatic energy loss along the bond stretch coordinate for scattering and dissociative chemisorption of H2 on the Ag(111) surface. Exemplary trajectories with varying initial conditions indicate that this mode specificity translates into modulated energy loss during a dissociative chemisorption event. Despite minor nonadiabatic energy loss of about 5%, the directionality of friction forces induces dynamical steering that affects individual reaction outcomes, specifically for low-incidence energies and vibrationally excited molecules. Mode-specific friction induces enhanced loss of rovibrational rather than translational energy and will be most visible in its effect on final energy distributions in molecular scattering experiments.

  12. "Liquid-liquid-solid"-type superoleophobic surfaces to pattern polymeric semiconductors towards high-quality organic field-effect transistors.

    Science.gov (United States)

    Wu, Yuchen; Su, Bin; Jiang, Lei; Heeger, Alan J

    2013-12-03

    Precisely aligned organic-liquid-soluble semiconductor microwire arrays have been fabricated by "liquid-liquid-solid" type superoleophobic surfaces directed fluid drying. Aligned organic 1D micro-architectures can be built as high-quality organic field-effect transistors with high mobilities of >10 cm(2) ·V(-1) ·s(-1) and current on/off ratio of more than 10(6) . All these studies will boost the development of 1D microstructures of organic semiconductor materials for potential application in organic electronics. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. Surface plasmon modes of a single silver nanorod: An electron energy loss study

    DEFF Research Database (Denmark)

    Nicoletti, Olivia; Wubs, Martijn; Mortensen, N. Asger

    2011-01-01

    We present an electron energy loss study using energy filtered TEM of spatially resolved surface plasmon excitations on a silver nanorod of aspect ratio 14.2 resting on a 30 nm thick silicon nitride membrane. Our results show that the excitation is quantized as resonant modes whose intensity maxima...

  14. Flexible long-range surface plasmon polariton single-mode waveguide for optical interconnects

    DEFF Research Database (Denmark)

    Vernoux, Christian; Chen, Yiting; Markey, Laurent

    2018-01-01

    We present the design, fabrication and characterization of long-range surface plasmon polariton waveguide arrays with materials, mainly silicones, carefully selected with the aim to be used as mechanically flexible single-mode optical interconnections, the socalled "plasmonic arc" working at 1.55μm...

  15. Non-equipotential magnetic surfaces and mode-transition in tokamaks

    International Nuclear Information System (INIS)

    Li Xingzhong

    1988-01-01

    The solution of the Fokker-Planck equation is used to describe a phase transition in velocity space. This transition is related to the mode-transition in tokamaks. After the transition the electrostatic potential on a magnetic surface cannot be considered as a constant. (orig.)

  16. An in-plane solid-liquid-solid growth mode for self-avoiding lateral silicon nanowires.

    Science.gov (United States)

    Yu, Linwei; Alet, Pierre-Jean; Picardi, Gennaro; Roca i Cabarrocas, Pere

    2009-03-27

    We report an in-plane solid-liquid-solid (IPSLS) mode for obtaining self-avoiding lateral silicon nanowires (SiNW) in a reacting-gas-free annealing process, where the growth of SiNWs is guided by liquid indium drops that transform the surrounding a-SiratioH matrix into crystalline SiNWs. The SiNWs can be approximately mm long, with the smallest diameter down to approximately 22 nm. A high growth rate of >10(2) nm/s and rich evolution dynamics are revealed in a real-time in situ scanning electron microscopy observation. A qualitative growth model is proposed to account for the major features of this IPSLS SiNW growth mode.

  17. Calorimetry by immersion into liquid nitrogen and liquid argon: a better way to determine the internal surface area of micropores.

    Science.gov (United States)

    Navarrete, Ricardo; Llewellyn, Philip; Rouquerol, Françoise; Denoyel, Renaud; Rouquerol, Jean

    2004-09-15

    The aim of this work is to assess the internal surface area of a set of samples (either carbons or oxides, either porous or nonporous, either microporous or mesoporous) by microcalorimetry via immersion into liquid nitrogen or argon. We have made use of an isothermal, heat-flux microcalorimeter, initially designed and built in our laboratory for the sake of gas adsorption experiments at 77 or 87 K. It seems that immersion calorimetry into liquid nitrogen and argon makes it possible to go one step further in the determination of the internal surface area of micropores.

  18. Fluorination effects on the thermodynamic, thermophysical and surface properties of ionic liquids

    International Nuclear Information System (INIS)

    Vieira, N.S.M.; Luís, A.; Reis, P.M.; Carvalho, P.J.; Lopes-da-Silva, J.A.; Esperança, J.M.S.S.; Araújo, J.M.M.; Rebelo, L.P.N.; Freire, M.G.; Pereiro, A.B.

    2016-01-01

    Highlights: • Surface tension of fluorinated ionic liquids. • Thermophysical properties of fluorinated ionic liquids. • Thermal properties and thermodynamic functions. - Abstract: This paper reports the thermal, thermodynamic, thermophysical and surface properties of eight ionic liquids with fluorinated alkyl side chain lengths equal or greater than four carbon atoms. Melting and decomposition temperatures were determined together with experimental densities, surface tensions, refractive indices, dynamic viscosities and ionic conductivities in a temperature interval ranging from (293.15 to 353.15) K. The surface properties of these fluorinated ionic liquids were discussed and several thermodynamic functions, as well as critical temperatures, were estimated. Coefficients of isobaric thermal expansion, molecular volumes and free volume effects were calculated from experimental values of density and refractive index and compared with previous data. Finally, Walden plots were used to evaluate the ionicity of the investigated ionic liquids.

  19. Failure modes observed on worn surfaces of W-C-Co sputtered coatings

    International Nuclear Information System (INIS)

    Ramalho, A.; Cavaleiro, A.; Miranda, A.S.; Vieira, M.T.

    1993-01-01

    During scratch testing, the indenter gives rise to a distribution of stresses similar to that observed in tribocontacts. In this work, r.f.-sputtered W-C-Co coatings deposited from sintered WC + Co (6, 10 and 15 wt.% Co) at various substrate biases were scratched and tested tribologically and the morphology of the damaged surfaces was analysed. The cobalt content of the coatings is the main factor determining their tribological characteristics. The failure modes observed on the worn pin-on-disc tested surfaces are explained and compared with those obtained by scratch testing. In spite of it not being possible to establish quantitative results for the wear resistance of W-C-Co coatings from scratch testing, an estimation can be performed based on the observation of the failure modes in the scratch track. Thus scratch testing can be used to predict the tribological behaviour of coated surfaces. This possibility can reduce the number and cost of tribological tests. (orig.)

  20. Frequency splitter based on the directional emission from surface modes in dielectric photonic crystal structures.

    Science.gov (United States)

    Tasolamprou, Anna C; Zhang, Lei; Kafesaki, Maria; Koschny, Thomas; Soukoulis, Costas M

    2015-06-01

    We demonstrate the numerical design and the experimental validation of frequency dependent directional emission from a dielectric photonic crystal structure. The wave propagates through a photonic crystal line-defect waveguide, while a surface layer at the termination of the photonic crystal enables the excitation of surface modes and a subsequent grating layer transforms the surface energy into outgoing propagating waves of the form of a directional beam. The angle of the beam is controlled by the frequency and the structure operates as a frequency splitter in the intermediate and far field region.

  1. Effect of potential attraction term on surface tension of ionic liquids

    Science.gov (United States)

    Vaziri, N.; Khordad, R.; Rezaei, G.

    2018-03-01

    In this work, we have studied the effect of attraction term of molecular potential on surface tension of ionic liquids (ILs). For this purpose, we have introduced two different potential models to obtain analytical expressions for the surface tension of ILs. The introduced potential models have different attraction terms. The obtained surface tensions in this work have been compared with other theoretical methods and also experimental data. Using the calculated surface tension, the sound velocity is also estimated. We have studied the structural effects on the surface tensions of imidazolium-based ionic liquids. It is found that the cation alkyl chain length and the anion size play important roles to the surface tension of the selected ionic liquids. The calculated surface tensions show a good harmony with experimental data. It is clear that the attraction term of molecular potential has an important role on surface tension and sound velocity of our system.

  2. Hydrogenation of nitriles on a well-characterized nickel surface: From surface science studies to liquid phase catalytic activity measurements

    Energy Technology Data Exchange (ETDEWEB)

    Gardin, Denis Emmanuel [Univ. of California, Berkeley, CA (United States)

    1993-12-01

    Nitrile hydrogenation is the most commonly used method for preparing diverse amines. This thesis is aimed at the mechanism and factors affecting the performance of Ni-based catalysts in nitrile hydrogenations. Surface science techniques are used to study bonding of nitriles and amines to a Ni(111) surface and to identify surface intermediates. Liquid-phase hydrogenations of cyclohexene and 1-hexene on a Pt foil were carried out successfully. Finally, knowledge about the surface structure, surface chemical bond, dynamics of surface atoms (diffusion, growth), and reactivity of metal surfaces from solid-gas interface studies, is discussed.

  3. Surface boiling - an obvious but like no other decay mode of highly excited atomic nuclei

    International Nuclear Information System (INIS)

    Toke, J.

    2012-01-01

    Essentials of a generalized compound nucleus model are introduced based on a concept of an open microcanonical ensemble which considers explicitly the role of the diffuse surface domain and of the thermal expansion of nuclear systems in the quest for maximum entropy. This obvious generalization offers a unique and universal thermodynamic framework for understanding the changes in the gross behavior of excited nuclear systems with increasing excitation energy and, specifically, the competition between different statistical decay modes, including classical evaporation and binary fission, but also the Coulomb fragmentation of excited systems into multiple fragments - the famed multifragmentation. Importantly, the formalism offers a natural explanation, in terms of boiling or spinodal vaporization, for the experimentally observed appearance of limiting excitation energy that can be thermalized by an exited nuclear system and the associated limiting temperature. It is shown that it is the thermal expansion that leads to volume boiling in an infinite matter and surface boiling in finite nuclei. The latter constitutes an important and universal, but hitherto unappreciated decay mode of highly excited nuclei, a mode here named surface spinodal vaporization. It is also shown that in iso-asymmetric systems, thermal expansion leads to what constitutes distillation - a decay mode here named distillative spinodal vaporization

  4. Novel method for the simultaneous estimation of density and surface tension of liquids

    International Nuclear Information System (INIS)

    Thirunavukkarasu, G.; Srinivasan, G.J.

    2003-01-01

    The conventional Hare's apparatus generally used for the determination of density of liquids has been modified by replacing its vertical arms (glass tubes) with capillary tubes of 30 cm length and 0.072 cm diameter. When the columns of liquids are drawn through the capillary tubes with reduced pressure at the top of the liquid columns and kept at equilibrium with the atmospheric pressure acting on the liquid surface outside the capillary tubes, the downward pressure due to gravity of the liquid columns has to be coupled with the pressure arising due to the effect of surface tension of the liquids. A fresh expression for the density and surface tension of liquids has been arrived at while equating the pressure balancing system for the two individual liquid columns of the modified Hare's apparatus. The experimental results showed that the proposed method is precise and accurate in the simultaneous estimation of density and surface tension of liquids, with an error of less than 5%

  5. Degradation modes of austenitic and ferritic–martensitic stainless steels in He–CO–CO2 and liquid sodium environments of equivalent oxygen and carbon chemical potentials

    International Nuclear Information System (INIS)

    Gulsoy, G.; Was, G.S.; Pawel, S.J.; Busby, J.T.

    2013-01-01

    The objective of this work is to explore possible thermodynamic correlations between the degradation modes of austenitic and ferritic–martensitic alloys observed in high temperature He–CO–CO 2 environments with oxygen and carbon chemical potentials equivalent to that in a liquid sodium environment containing 2–5 molppm oxygen and 0.02–0.2 molppm carbon at temperatures 500–700 °C. Two He–CO–CO 2 environments (Pco/Pco 2 = 1320, Pco = 1980 molppm, and Pco/Pco 2 = 9, Pco = 13.5 molppm) were selected to test alloys NF616 and 316L at 700 and 850 °C. Upon exposure to He environments at 850 °C, 316L samples exhibited thick surface Cr 2 O 3 scales and substantial internal oxidation; however at 700 °C no significant internal oxidation was observed. NF616 samples exhibited relatively thinner surface Cr 2 O 3 scales compared to 316L samples at both temperatures. NF616 samples exposed to liquid sodium at 700 °C and He–Pco/Pco 2 = 9 at 850 °C showed decarburization. No surface oxide formation was observed on the sample exposed to the Na environment. Results obtained from He exposure experiments provide insight into what may occur during long exposure times in a sodium environment

  6. Degradation modes of austenitic and ferritic–martensitic stainless steels in He–CO–CO{sub 2} and liquid sodium environments of equivalent oxygen and carbon chemical potentials

    Energy Technology Data Exchange (ETDEWEB)

    Gulsoy, G., E-mail: gulsoy@umich.edu [Department of Materials Science and Engineering, University of Michigan, 2355 Bonisteel Boulevard, Ann Arbor, MI 48109 (United States); Was, G.S. [Department of Materials Science and Engineering, University of Michigan, 2355 Bonisteel Boulevard, Ann Arbor, MI 48109 (United States); Pawel, S.J.; Busby, J.T. [Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States)

    2013-10-15

    The objective of this work is to explore possible thermodynamic correlations between the degradation modes of austenitic and ferritic–martensitic alloys observed in high temperature He–CO–CO{sub 2} environments with oxygen and carbon chemical potentials equivalent to that in a liquid sodium environment containing 2–5 molppm oxygen and 0.02–0.2 molppm carbon at temperatures 500–700 °C. Two He–CO–CO{sub 2} environments (Pco/Pco{sub 2} = 1320, Pco = 1980 molppm, and Pco/Pco{sub 2} = 9, Pco = 13.5 molppm) were selected to test alloys NF616 and 316L at 700 and 850 °C. Upon exposure to He environments at 850 °C, 316L samples exhibited thick surface Cr{sub 2}O{sub 3} scales and substantial internal oxidation; however at 700 °C no significant internal oxidation was observed. NF616 samples exhibited relatively thinner surface Cr{sub 2}O{sub 3} scales compared to 316L samples at both temperatures. NF616 samples exposed to liquid sodium at 700 °C and He–Pco/Pco{sub 2} = 9 at 850 °C showed decarburization. No surface oxide formation was observed on the sample exposed to the Na environment. Results obtained from He exposure experiments provide insight into what may occur during long exposure times in a sodium environment.

  7. Physically and chemically stable ionic liquid-infused textured surfaces showing excellent dynamic omniphobicity

    Energy Technology Data Exchange (ETDEWEB)

    Miranda, Daniel F.; Urata, Chihiro; Masheder, Benjamin; Dunderdale, Gary J.; Hozumi, Atsushi, E-mail: a.hozumi@aist.go.jp [National Institute of Advanced Industrial Science and Technology (AIST), 2266-98, Anagahora, Shimo-Shidami, Moriyama-ku, Nagoya, Aichi 463-8560 (Japan); Yagihashi, Makoto [Nagoya Municipal Industrial Research Institute, Rokuban, Atsuta-ku, Nagoya 456-0058 (Japan)

    2014-05-01

    A fluorinated and hydrophobic ionic liquid (IL), 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide, effectively served as an advantageous lubricating liquid for the preparation of physically and chemically stable omniphobic surfaces based on slippery liquid-infused porous surfaces. Here, we used particulate microstructures as supports, prepared by the chemical vapor deposition of 1,3,5,7-tetramethylcyclotetrasiloxane and subsequent surface modification with (3-aminopropyl)triethoxysilane. Confirmed by SEM and contact angle measurements, the resulting IL-infused microtextured surfaces are smooth and not only water but also various low surface tension liquids can easily slide off at low substrate tilt angles of <5°, even after exposure to high temperature, vacuum, and UV irradiation.

  8. Physically and chemically stable ionic liquid-infused textured surfaces showing excellent dynamic omniphobicity

    Directory of Open Access Journals (Sweden)

    Daniel F. Miranda

    2014-05-01

    Full Text Available A fluorinated and hydrophobic ionic liquid (IL, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl imide, effectively served as an advantageous lubricating liquid for the preparation of physically and chemically stable omniphobic surfaces based on slippery liquid-infused porous surfaces. Here, we used particulate microstructures as supports, prepared by the chemical vapor deposition of 1,3,5,7-tetramethylcyclotetrasiloxane and subsequent surface modification with (3-aminopropyltriethoxysilane. Confirmed by SEM and contact angle measurements, the resulting IL-infused microtextured surfaces are smooth and not only water but also various low surface tension liquids can easily slide off at low substrate tilt angles of <5°, even after exposure to high temperature, vacuum, and UV irradiation.

  9. Phase transition detection by surface photo charge effect in liquid crystals

    Science.gov (United States)

    Ivanov, O.; Petrov, M.; Naradikian, H.; Perez-Diaz, J. L.

    2018-05-01

    The surface photo charge effect (SPCE) was applied for the first time at structure and phase transitions study of hydrogen bonded in dimer liquid crystals (HBDLCs). Due to the high sensitivity of this method, besides first-order phase transitions, characteristic for the p,n-octyloxibenzoic acids (8OBA), an order transition was definitely detected within the nematic range. We state that the SPCE, arising at the solid-HBDLCs interface due to the double electrical layer, is invariably concomitant with solid surface-liquid interfaces, and indicates that the changes of the characteristics of this layer, under incident optical irradiation, induce surface charge rearrangement and alternating potential difference. A mechanism of induction of the SPCE at the interface of solid surface-anisotropic liquids is proposed. We also indicate that this mechanism can be adapted for solid surface-isotropic liquid interface, including colloids (milk) and fog (aerosols)-condensed medium.

  10. Quantum State-Resolved Collision Dynamics of Nitric Oxide at Ionic Liquid and Molten Metal Surfaces

    Science.gov (United States)

    Zutz, Amelia Marie

    Detailed molecular scale interactions at the gas-liquid interface are explored with quantum state-to-state resolved scattering of a jet-cooled beam of NO(2pi1/2; N = 0) from ionic liquid and molten metal surfaces. The scattered distributions are probed via laser-induced fluorescence methods, which yield rotational and spin-orbit state populations that elucidate the dynamics of energy transfer at the gas-liquid interface. These collision dynamics are explored as a function of incident collision energy, surface temperature, scattering angle, and liquid identity, all of which are found to substantially affect the degree of rotational, electronic and vibrational excitation of NO via collisions at the liquid surface. Rotational distributions observed reveal two distinct scattering pathways, (i) molecules that trap, thermalize and eventually desorb from the surface (trapping-desorption, TD), and (ii) those that undergo prompt recoil (impulsive scattering, IS) prior to complete equilibration with the liquid surface. Thermally desorbing NO molecules are found to have rotational temperatures close to, but slightly cooler than the surface temperature, indicative of rotational dependent sticking probabilities on liquid surfaces. Nitric oxide is a radical with multiple low-lying electronic states that serves as an ideal candidate for exploring nonadiabatic state-changing collision dynamics at the gas-liquid interface, which induce significant excitation from ground (2pi1/2) to excited (2pi 3/2) spin-orbit states. Molecular beam scattering of supersonically cooled NO from hot molten metals (Ga and Au, Ts = 300 - 1400 K) is also explored, which provide preliminary evidence for vibrational excitation of NO mediated by thermally populated electron-hole pairs in the hot, conducting liquid metals. The results highlight the presence of electronically nonadiabatic effects and build toward a more complete characterization of energy transfer dynamics at gas-liquid interfaces.

  11. Analysis of spatial and temporal spectra of liquid film surface in annular gas-liquid flow

    Science.gov (United States)

    Alekseenko, Sergey; Cherdantsev, Andrey; Heinz, Oksana; Kharlamov, Sergey; Markovich, Dmitriy

    2013-09-01

    Wavy structure of liquid film in annular gas-liquid flow without liquid entrainment consists of fast long-living primary waves and slow short-living secondary waves. In present paper, results of spectral analysis of this wavy structure are presented. Application of high-speed LIF technique allowed us to perform such analysis in both spatial and temporal domains. Power spectra in both domains are characterized by one-humped shape with long exponential tail. Influence of gas velocity, liquid Reynolds number, liquid viscosity and pipe diameter on frequency of the waves is investigated. When gravity effect is much lesser than the shear stress, similarity of power spectra at different gas velocities is observed. Using combination of spectral analysis and identification of characteristic lines of primary waves, frequency of generation of secondary waves by primary waves is measured.

  12. Determination of surface tension coefficient of liquids by diffraction of light on capillary waves

    International Nuclear Information System (INIS)

    Nikolić, D; Nešić, Lj

    2012-01-01

    This paper describes a simple technique for determining the coefficient of the surface tension of liquids, based on laser light diffraction on capillary waves. Capillary waves of given frequency are created by an exciter needle acting on the surface of liquid and represent a reflective diffraction grating, the constant of which (the wavelength of capillary waves) can be determined based on a known incidence angle of light (grazing angle). We obtain the coefficient of the surface tension of liquids by applying the dispersion relation for capillary waves and analyze the difficulties that arise when setting up and conducting the experiment in detail. (paper)

  13. Levitation of Liquid Microdroplets Above A Solid Surface Subcooled to the Leidenfrost Temperature

    Directory of Open Access Journals (Sweden)

    Kirichenko D. P.

    2016-01-01

    Full Text Available Evaporation of liquid microdroplets that fall on a solid surface with the temperature of below the Leidenfrost temperature is studied. It has been found out that sufficiently small liquid droplets of about 10 microns can suspend at some distance from the surface (levitate and do not reach the surface; at that, the rate of droplet evaporation is reduced by an order as compared to microdroplets, which touch the surface. It is determined that in contrast to microdroplets, which touch the surface, the specific evaporation rate of levitating droplets is constant in time.

  14. Adhesion force imaging in air and liquid by adhesion mode atomic force microscopy

    NARCIS (Netherlands)

    van der Werf, Kees; Putman, C.A.J.; Putman, Constant A.; de Grooth, B.G.; Greve, Jan

    1994-01-01

    A new imaging mode for the atomic force microscope(AFM), yielding images mapping the adhesion force between tip and sample, is introduced. The adhesion mode AFM takes a force curve at each pixel by ramping a piezoactuator, moving the silicon‐nitride tip up and down towards the sample. During the

  15. Overmoded subterahertz surface wave oscillator with pure TM01 mode output

    International Nuclear Information System (INIS)

    Wang, Guangqiang; Zeng, Peng; Wang, Dongyang; Wang, Jianguo; Li, Shuang

    2016-01-01

    Overmoded O-type Cerenkov generators using annular electron beams are facing the problem of multi-modes output due to the inevitable structural discontinuities. A simple but effective method to achieve the pure TM 01 mode output is applied on the 0.14 THz overmoded surface wave oscillator (SWO) in this paper. In spite of still using an overmoded slow wave structure to ensure the easy fabrication, the followed smooth circular waveguide is shrinkingly tapered to the output waveguide with appropriate radius that it cuts off other higher modes except TM 01 mode. Moreover, the modified device here has the same power capacity as the previous one according to the numerical analysis. By optimized lengths of the transition waveguide and tapered waveguide, particle-in-cell simulation results indicate that the subterahertz wave with output power increased 14.2% at the same frequency is obtained from the proposed SWO under the previous input conditions, and importantly, the output power is all carried by TM 01 mode as expected. Further simulation results in the pulse regime confirm the feasibility of the optimized structure in the actual experiments. This simple and viable design is also applicable to overmoded devices in the lower frequency band of subterahertz wave

  16. Spatial potential ripples of azimuthal surface modes in topological insulator Bi2Te3 nanowires.

    Science.gov (United States)

    Muñoz Rojo, Miguel; Zhang, Yingjie; Manzano, Cristina V; Alvaro, Raquel; Gooth, Johannes; Salmeron, Miquel; Martin-Gonzalez, Marisol

    2016-01-11

    Topological insulators (TI) nanowires (NW) are an emerging class of structures, promising both novel quantum effects and potential applications in low-power electronics, thermoelectrics and spintronics. However, investigating the electronic states of TI NWs is complicated, due to their small lateral size, especially at room temperature. Here, we perform scanning probe based nanoscale imaging to resolve the local surface potential landscapes of Bi2Te3 nanowires (NWs) at 300 K. We found equipotential rings around the NWs perimeter that we attribute to azimuthal 1D modes. Along the NW axis, these modes are altered, forming potential ripples in the local density of states, due to intrinsic disturbances. Potential mapping of electrically biased NWs enabled us to accurately determine their conductivity which was found to increase with the decrease of NW diameter, consistent with surface dominated transport. Our results demonstrate that TI NWs can pave the way to both exotic quantum states and novel electronic devices.

  17. Polarity control and growth mode of InN on yttria-stabilized zirconia (111) surfaces

    International Nuclear Information System (INIS)

    Kobayashi, Atsushi; Okubo, Kana; Ohta, Jitsuo; Oshima, Masaharu; Fujioka, Hiroshi

    2012-01-01

    We have found that polarity of epitaxial InN layers has been controlled by choice of a capping material during high-temperature annealing of yttria-stabilized zirconia (YSZ) (111) substrates in air. Angle-resolved X-ray photoelectron spectroscopy has revealed that the amount of segregation of Y atoms to the YSZ surface depended on the capping material of the substrates. In-polar and N-polar InN have been reproducibly grown on Y-segregated and Y-segregation-free YSZ surfaces, respectively. We have also found that the growth of the first monolayer (ML) of N-polar InN proceeds in a step-flow mode which then switches to layer-by-layer mode after the coverage by 1-ML-thick InN. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  18. Novel method for the measurement of liquid film thickness during fuel spray impingement on surfaces.

    Science.gov (United States)

    Henkel, S; Beyrau, F; Hardalupas, Y; Taylor, A M K P

    2016-02-08

    This paper describes the development and application of a novel optical technique for the measurement of liquid film thickness formed on surfaces during the impingement of automotive fuel sprays. The technique makes use of the change of the light scattering characteristics of a metal surface with known roughness, when liquid is deposited. Important advantages of the technique over previously established methods are the ability to measure the time-dependent spatial distribution of the liquid film without a need to add a fluorescent tracer to the liquid, while the measurement principle is not influenced by changes of the pressure and temperature of the liquid or the surrounding gas phase. Also, there is no need for non-fluorescing surrogate fuels. However, an in situ calibration of the dependence of signal intensity on liquid film thickness is required. The developed method can be applied to measure the time-dependent and two-dimensional distribution of the liquid fuel film thickness on the piston or the liner of gasoline direct injection (GDI) engines. The applicability of this technique was evaluated with impinging sprays of several linear alkanes and alcohols with different thermo-physical properties. The surface temperature of the impingement plate was controlled to simulate the range of piston surface temperatures inside a GDI engine. Two sets of liquid film thickness measurements were obtained. During the first set, the surface temperature of the plate was kept constant, while the spray of different fuels interacted with the surface. In the second set, the plate temperature was adjusted to match the boiling temperature of each fuel. In this way, the influence of the surface temperature on the liquid film created by the spray of different fuels and their evaporation characteristics could be demonstrated.

  19. Study on dynamic deformation synchronized measurement technology of double-layer liquid surfaces

    Science.gov (United States)

    Tang, Huiying; Dong, Huimin; Liu, Zhanwei

    2017-11-01

    Accurate measurement of the dynamic deformation of double-layer liquid surfaces plays an important role in many fields, such as fluid mechanics, biomechanics, petrochemical industry and aerospace engineering. It is difficult to measure dynamic deformation of double-layer liquid surfaces synchronously for traditional methods. In this paper, a novel and effective method for full-field static and dynamic deformation measurement of double-layer liquid surfaces has been developed, that is wavefront distortion of double-wavelength transmission light with geometric phase analysis (GPA) method. Double wavelength lattice patterns used here are produced by two techniques, one is by double wavelength laser, and the other is by liquid crystal display (LCD). The techniques combine the characteristics such as high transparency, low reflectivity and fluidity of liquid. Two color lattice patterns produced by laser and LCD were adjusted at a certain angle through the tested double-layer liquid surfaces simultaneously. On the basis of the refractive indexes difference of two transmitted lights, the double-layer liquid surfaces were decoupled with GPA method. Combined with the derived relationship between phase variation of transmission-lattice patterns and out-of plane heights of two surfaces, as well as considering the height curves of the liquid level, the double-layer liquid surfaces can be reconstructed successfully. Compared with the traditional measurement method, the developed method not only has the common advantages of the optical measurement methods, such as high-precision, full-field and non-contact, but also simple, low cost and easy to set up.

  20. Direct mass spectrometric screening of antibiotics from bacterial surfaces using liquid extraction surface analysis.

    Science.gov (United States)

    Kai, Marco; González, Ignacio; Genilloud, Olga; Singh, Sheo B; Svatoš, Aleš

    2012-10-30

    There is a need to find new antibiotic agents to fight resistant pathogenic bacteria. To search successfully for novel antibiotics from bacteria cultivated under diverse conditions, we need a fast and cost-effective screening method. A combination of Liquid Extraction Surface Analysis (LESA), automated chip-based nanoelectrospray ionization, and high-resolution mass or tandem mass spectrometry using an Orbitrap XL was tested as the screening platform. Actinobacteria, known to produce well-recognized thiazolyl peptide antibiotics, were cultivated on a plate of solid medium and the antibiotics were extracted by organic solvent mixtures from the surface of colonies grown on the plate and analyzed using mass spectrometry (MS). LESA combined with high-resolution MS is a powerful tool with which to extract and detect thiazolyl peptide antibiotics from different Actinobacteria. Known antibiotics were correctly detected with high mass accuracy (antibiotics in particular and natural products in general. The method described in this paper is suitable for (1) screening the natural products produced by bacterial colonies on cultivation plates within the first 2 min following extraction and (2) detecting antibiotics at high mass accuracy; the cost is around 2 Euro per sample. Copyright © 2012 John Wiley & Sons, Ltd.

  1. Apparent contact angle and contact angle hysteresis on liquid infused surfaces.

    Science.gov (United States)

    Semprebon, Ciro; McHale, Glen; Kusumaatmaja, Halim

    2016-12-21

    We theoretically investigate the apparent contact angle and contact angle hysteresis of a droplet placed on a liquid infused surface. We show that the apparent contact angle is not uniquely defined by material parameters, but also has a dependence on the relative size between the droplet and its surrounding wetting ridge formed by the infusing liquid. We derive a closed form expression for the contact angle in the limit of vanishing wetting ridge, and compute the correction for small but finite ridge, which corresponds to an effective line tension term. We also predict contact angle hysteresis on liquid infused surfaces generated by the pinning of the contact lines by the surface corrugations. Our analytical expressions for both the apparent contact angle and contact angle hysteresis can be interpreted as 'weighted sums' between the contact angles of the infusing liquid relative to the droplet and surrounding gas phases, where the weighting coefficients are given by ratios of the fluid surface tensions.

  2. Relation between bulk compressibility and surface energy of electron-hole liquids

    International Nuclear Information System (INIS)

    Singwi, K.S.; Tosi, M.P.

    1979-08-01

    Attention is drawn to the existence of an empirical relation chiσ/asup(*)sub(B) approximately 1 between the compressibility, the surface energy and the excitonic radius in electron-hole liquids. (author)

  3. Plasma-implantation-based surface modification of metals with single-implantation mode

    Science.gov (United States)

    Tian, X. B.; Cui, J. T.; Yang, S. Q.; Fu, Ricky K. Y.; Chu, Paul K.

    2004-12-01

    Plasma ion implantation has proven to be an effective surface modification technique. Its biggest advantage is the capability to treat the objects with irregular shapes without complex manipulation of target holder. Many metal materials such as aluminum, stainless steel, tool steel, titanium, magnesium etc, has been treated using this technique to improve their wear-resistance, corrosion-resistance, fatigue-resistance, oxidation-resistance, bio-compatiblity etc. However in order to achieve thicker modified layers, hybrid processes combining plasma ion implantation with other techniques have been frequently employed. In this paper plasma implantation based surface modification of metals using single-implantation mode is reviewed.

  4. Axial propagation of free surface boiling into superheated liquids in vertical tubes

    International Nuclear Information System (INIS)

    Grolmes, M.A.; Fauske, H.K.

    1974-01-01

    A unique free surface boiling phenomenon has been observed as a result of rapid depressurization of an initially saturated or slightly subcooled stagnant liquid column in the absence of wall and bulk nucleation sites. Closeup high-speed photographs of water, refrigerant-11, and methyl alcohol in tubes from 0.2 to 15 in. dia reveal that the initiation of violent free surface flashing (vapor plus entrained liquid) follows from the development of Marangoni-type surface waves. The rate of propagation of the flashing surface shows evidence of choked flow limitations and proceeds at a rate which is several orders of magnitude greater than surface evaporation (vapor only) alone. The onset of free surface flashing was found to be dependent upon both the degree of initial liquid superheat and the tube diameter. (U.S.)

  5. Surface modification and characterization for dispersion stability of inorganic nanometer-scaled particles in liquid media

    International Nuclear Information System (INIS)

    Kamiya, Hidehiro; Iijima, Motoyuki

    2010-01-01

    Inorganic nanoparticles are indispensable for science and technology as materials, pigments and cosmetics products. Improving the dispersion stability of nanoparticles in various liquids is essential for those applications. In this review, we discuss why it is difficult to control the stability of nanoparticles in liquids. We also overview the role of surface interaction between nanoparticles in their dispersion and characterization, e.g. by colloid probe atomic force microscopy (CP-AFM). Two types of surface modification concepts, post-synthesis and in situ modification, were investigated in many previous studies. Here, we focus on post-synthesis modification using adsorption of various kinds of polymer dispersants and surfactants on the particle surface, as well as surface chemical reactions of silane coupling agents. We discuss CP-AFM as a technique to analyze the surface interaction between nanoparticles and the effect of surface modification on the nanoparticle dispersion in liquids. (topical review)

  6. Surface modification and characterization for dispersion stability of inorganic nanometer-scaled particles in liquid media

    Directory of Open Access Journals (Sweden)

    Hidehiro Kamiya and Motoyuki Iijima

    2010-01-01

    Full Text Available Inorganic nanoparticles are indispensable for science and technology as materials, pigments and cosmetics products. Improving the dispersion stability of nanoparticles in various liquids is essential for those applications. In this review, we discuss why it is difficult to control the stability of nanoparticles in liquids. We also overview the role of surface interaction between nanoparticles in their dispersion and characterization, e.g. by colloid probe atomic force microscopy (CP-AFM. Two types of surface modification concepts, post-synthesis and in situ modification, were investigated in many previous studies. Here, we focus on post-synthesis modification using adsorption of various kinds of polymer dispersants and surfactants on the particle surface, as well as surface chemical reactions of silane coupling agents. We discuss CP-AFM as a technique to analyze the surface interaction between nanoparticles and the effect of surface modification on the nanoparticle dispersion in liquids.

  7. Liquid crystal elastomer coatings with programmed response of surface profile

    NARCIS (Netherlands)

    Babakhanova, G.; Turiv, T.; Guo, Y.; Hendrikx, M.; Wei, Q.H.; Schenning, A.P.H.J.; Broer, D.J.; Lavrentovich, O.D.

    2018-01-01

    Stimuli-responsive liquid crystal elastomers with molecular orientation coupled to rubber-like elasticity show a great potential as elements in soft robotics, sensing, and transport systems. The orientational order defines their mechanical response to external stimuli, such as thermally activated

  8. The profile of a capillary liquid bridge between solid surfaces

    NARCIS (Netherlands)

    van Honschoten, J.W.; Tas, Niels Roelof; Elwenspoek, Michael Curt

    2010-01-01

    Scanning force microscopy, such as atomic force microscopy (AFM) is complicated by the capillary force of a water meniscus formed in air between the probe tip and the sample. This small liquid bridge between the hydrophilic sample and the sharp AFM tip can be formed by capillary condensation from

  9. Structures of simple liquids in contact with nanosculptured surfaces.

    Science.gov (United States)

    Singh, Swarn Lata; Schimmele, Lothar; Dietrich, S

    2015-03-01

    We present a density functional study of Lennard-Jones liquids in contact with a nanocorrugated wall. The corresponding substrate potential is taken to exhibit a repulsive hard core and a Van der Waals attraction. The corrugation is modeled by a periodic array of square nanopits. We have used the modified Rosenfeld density functional in order to study the interfacial structure of these liquids which with respect to their thermodynamic bulk state are considered to be deep inside their liquid phase. We find that already considerably below the packing fraction of bulk freezing of these liquids, inside the nanopits a three-dimensional-like density localization sets in. If the sizes of the pits are commensurate with the packing requirements, we observe high-density spots separated from each other in all spatial directions by liquid of comparatively very low density. The number, shape, size, and density of these high-density spots depend sensitively on the depth and width of the pits. Outside the pits, only layering is observed; above the pit openings these layers are distorted with the distortion reaching up to a few molecular diameters. We discuss quantitatively how this density localization is affected by the geometrical features of the pits and how it evolves upon increasing the bulk packing fraction. Our results are transferable to colloidal systems and pit dimensions corresponding to several diameters of the colloidal particles. For such systems the predicted unfolding of these structural changes can be studied experimentally on much larger length scales and more directly (e.g., optically) than for molecular fluids which typically call for sophisticated x-ray scattering.

  10. Liquid-solid contact measurements using a surface thermocouple temperature probe in atmospheric pool boiling water

    International Nuclear Information System (INIS)

    Lee, L.Y.W.; Chen, J.C.; Nelson, R.A.

    1984-01-01

    Objective was to apply the technique of using a microthermocouple flush-mounted at the boiling surface for the measurement of the local-surface-temperature history in film and transition boiling on high temperature surfaces. From this measurement direct liquid-solid contact in film and transition boiling regimes was observed. In pool boiling of saturated, distilled, deionized water on an aluminum-coated copper surface, the time-averaged, local-liquid-contact fraction increased with decreasing surface superheat. Average contact duration increased monotonically with decreasing surface superheat, while frequency of liquid contact reached a maximum of approx. 50 contacts/s at a surface superheat of approx. 100 K and decreased gradually to 30 contacts/s near the critical heat flux. The liquid-solid contact duration distribution was dominated by short contacts 4 ms at low surface superheats, passing through a relatively flat contact duration distribution at about 80 0 K. Results of this paper indicate that liquid-solid contacts may be the dominant mechanism for energy transfer in the transition boiling process

  11. Hyperparametric effects in a whispering-gallery mode rutile dielectric resonator at liquid helium temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Nand, Nitin R.; Goryachev, Maxim; Floch, Jean-Michel le; Creedon, Daniel L.; Tobar, Michael E. [ARC Centre for Engineered Quantum Systems, School of Physics, The University of Western Australia, 35 Stirling Highway, Crawley 6009, Western Australia (Australia)

    2014-10-07

    We report the first observation of low power drive level sensitivity, hyperparametric amplification, and single-mode hyperparametric oscillations in a dielectric rutile whispering-gallery mode resonator at 4.2 K. The latter gives rise to a comb of sidebands at 19.756 GHz. Whereas, most frequency combs in the literature have been observed in optical systems using an ensemble of equally spaced modes in microresonators or fibers, the present work represents generation of a frequency comb using only a single-mode. The experimental observations are explained by an additional 1/2 degree-of-freedom originating from an intrinsic material nonlinearity at optical frequencies, which affects the microwave properties due to the extremely low loss of rutile. Using a model based on lumped circuits, we demonstrate that the resonance between the photonic and material 1/2 degree-of-freedom, is responsible for the hyperparametric energy transfer in the system.

  12. Indium-tin oxide surface treatments: Effects on the performance of liquid crystal devices

    International Nuclear Information System (INIS)

    Abderrahmen, A.; Romdhane, F.F.; Ben Ouada, H.; Gharbi, A.

    2006-01-01

    In this work, we investigate the effect of indium tin oxide (ITO) substrate cleaning on the surface properties. Wettability technique was used to measure the contact angle and the surface energy of the different treated ITO substrates. It is found that treatment with the methanol without dehydration gives the lowest water contact angle (most hydrophilic surface) and the highest surface energy compared to other solvents. This result was confirmed by impedance measurements performed on nematic liquid crystal cells with ITO electrodes. Indeed, we check the decrease of ionic entities in the interface ITO/liquid crystal. The polarity and dielectric parameters of the used solvents explain the obtained results

  13. Indium-tin oxide surface treatments: Effects on the performance of liquid crystal devices

    Energy Technology Data Exchange (ETDEWEB)

    Abderrahmen, A. [Laboratoire de physique et chimie des interfaces, Faculte des sciences, 5000, Monastir (Tunisia)]. E-mail: asma_abderrahmen@yahoo.fr; Romdhane, F.F. [Laboratoire de la matiere molle, Faculte des sciences, Tunis (Tunisia); Ben Ouada, H. [Laboratoire de physique et chimie des interfaces, Faculte des sciences, 5000, Monastir (Tunisia); Gharbi, A. [Laboratoire de la matiere molle, Faculte des sciences, Tunis (Tunisia)

    2006-03-15

    In this work, we investigate the effect of indium tin oxide (ITO) substrate cleaning on the surface properties. Wettability technique was used to measure the contact angle and the surface energy of the different treated ITO substrates. It is found that treatment with the methanol without dehydration gives the lowest water contact angle (most hydrophilic surface) and the highest surface energy compared to other solvents. This result was confirmed by impedance measurements performed on nematic liquid crystal cells with ITO electrodes. Indeed, we check the decrease of ionic entities in the interface ITO/liquid crystal. The polarity and dielectric parameters of the used solvents explain the obtained results.

  14. Pesticide residue determination in surface waters by stir bar sorptive extraction and liquid chromatography/tandem mass spectrometry.

    Science.gov (United States)

    Giordano, A; Fernández-Franzón, M; Ruiz, M J; Font, G; Picó, Y

    2009-03-01

    In this stir bar sorptive extraction (SBSE) method, 16 pesticides were extracted from surface water samples by sorption onto 1 mm polydimethylsiloxane layer coated on a 10-mm-length stir bar magnet. After liquid desorption of the analytes with 1 ml of methanol, the detection was performed on a liquid chromatography-tandem mass spectrometry with a triple quadrupole (QqQ) analyzer using selected reaction monitoring mode via electrospray ionization. Parameters affecting SBSE operation, including sample volume, salt addition, extraction time, stirring rate, and desorption conditions, have been evaluated. The optimized SBSE method required two 50 ml aliquots of surface water samples, one aliquot was added of 30% NaCl and stirred at 900 rpm during 1 h for testing five pesticides with log K(o/w) 3. The method was validated in spiked surface water samples at limits of quantifications (LOQs) and ten times the LOQs showing recoveries Albufera Lake and surrounding channels, showing that SBSE is a powerful tool for routine control analysis of pesticide residues in surface water.

  15. Parallel-aligned GaAs nanowires with (110) orientation laterally grown on [311]B substrates via the gold-catalyzed vapor-liquid-solid mode

    International Nuclear Information System (INIS)

    Zhang Guoqiang; Tateno, Kouta; Gotoh, Hideki; Nakano, Hidetoshi

    2010-01-01

    We report parallel aligned GaAs nanowires (NWs) with (110) orientation laterally grown on [311]B substrates via the vapor-liquid-solid mode and demonstrate their controllability and growth mechanism. We control the size, density, and site of the lateral NWs by using size- and density-selective Au colloidal particles and Au dot arrays defined by electron-beam lithography. The lateral NWs grow only along the [110] and [1-bar 1-bar 0] directions and formation of the stable facets of (111)B and (001) on the sides of the lateral NWs is crucial for lateral NW growth. We clarify the growth mechanism by comparing the growth results on [311]B, (311)A, and (001) substrates and the surface energy change of lateral and freestanding NWs.

  16. Upper Mantle Shear Wave Structure Beneath North America From Multi-mode Surface Wave Tomography

    Science.gov (United States)

    Yoshizawa, K.; Ekström, G.

    2008-12-01

    The upper mantle structure beneath the North American continent has been investigated from measurements of multi-mode phase speeds of Love and Rayleigh waves. To estimate fundamental-mode and higher-mode phase speeds of surface waves from a single seismogram at regional distances, we have employed a method of nonlinear waveform fitting based on a direct model-parameter search using the neighbourhood algorithm (Yoshizawa & Kennett, 2002). The method of the waveform analysis has been fully automated by employing empirical quantitative measures for evaluating the accuracy/reliability of estimated multi-mode phase dispersion curves, and thus it is helpful in processing the dramatically increasing numbers of seismic data from the latest regional networks such as USArray. As a first step toward modeling the regional anisotropic shear-wave velocity structure of the North American upper mantle with extended vertical resolution, we have applied the method to long-period three-component records of seismic stations in North America, which mostly comprise the GSN and US regional networks as well as the permanent and transportable USArray stations distributed by the IRIS DMC. Preliminary multi-mode phase-speed models show large-scale patterns of isotropic heterogeneity, such as a strong velocity contrast between the western and central/eastern United States, which are consistent with the recent global and regional models (e.g., Marone, et al. 2007; Nettles & Dziewonski, 2008). We will also discuss radial anisotropy of shear wave speed beneath North America from multi-mode dispersion measurements of Love and Rayleigh waves.

  17. Processing method and processing device for liquid waste containing surface active agent and radioactive material

    International Nuclear Information System (INIS)

    Nishi, Takashi; Matsuda, Masami; Baba, Tsutomu; Yoshikawa, Ryozo; Yukita, Atsushi.

    1998-01-01

    Washing liquid wastes containing surface active agents and radioactive materials are sent to a deaerating vessel. Ozone is blown into the deaerating vessel. The washing liquid wastes dissolved with ozone are introduced to a UV ray irradiation vessel. UV rays are irradiated to the washing liquid wastes, and hydroxy radicals generated by photodecomposition of dissolved ozone oxidatively decompose surface active agents contained in the washing liquid wastes. The washing liquid wastes discharged from the UV ray irradiation vessel are sent to an activated carbon mixing vessel and mixed with powdery activated carbon. The surface active agents not decomposed in the UV ray irradiation vessel are adsorbed to the activated carbon. Then, the activated carbon and washing liquid wastes are separated by an activated carbon separating/drying device. Radioactive materials (iron oxide and the like) contained in the washing liquid wastes are mostly granular, and they are separated and removed from the washing liquid wastes in the activated carbon separating/drying device. (I.N.)

  18. A new facility for studying plasma interacting with flowing liquid lithium surface

    International Nuclear Information System (INIS)

    Cao, X.; Ou, W.; Tian, S.; Wang, C.; Zhu, Z.; Wang, J.; Gou, F.; Yang, D.; Chen, S.

    2014-01-01

    A new facility to study plasmas interacting with flowing liquid lithium surface was designed and is constructing in Sichuan University. The integrated setup includes the liquid lithium circulating part and linear high density plasma generator. The circulating part is consisted of main loop, on-line monitor system, lithium purification system and temperature programmed desorption system. In our group a linear high density plasma generator was built in 2012. Three coils were mounted along the vessel to produce an axial magnetic field inside. The magnetic field strength is up to 0.45 T and work continuously. Experiments on plasmas interacting with free flowing liquid lithium surface will be performed

  19. Electron spin resonance modes in a strong-leg ladder in the Tomonaga-Luttinger liquid phase

    Science.gov (United States)

    Ozerov, M.; Maksymenko, M.; Wosnitza, J.; Honecker, A.; Landee, C. P.; Turnbull, M. M.; Furuya, S. C.; Giamarchi, T.; Zvyagin, S. A.

    2015-12-01

    Magnetic excitations in the strong-leg quantum spin ladder compound (C7H10N) 2CuBr4 (known as DIMPY) in the field-induced Tomonaga-Luttinger spin-liquid phase are studied by means of high-field electron spin resonance (ESR) spectroscopy. The presence of a gapped ESR mode with unusual nonlinear frequency-field dependence is revealed experimentally. Using a combination of analytic and exact-diagonalization methods, we compute the dynamical structure factor and identify this mode with longitudinal excitations in the antisymmetric channel. We argue that these excitations constitute a fingerprint of the spin dynamics in a strong-leg spin-1/2 Heisenberg antiferromagnetic ladder and owe their ESR observability to the uniform Dzyaloshinskii-Moriya interaction.

  20. Optical manipulation of photonic defect-modes in cholesteric liquid crystals induced by direct laser-lithography

    International Nuclear Information System (INIS)

    Yoshida, Hiroyuki; Lee, Chee Heng; Miura, Yusuke; Fujii, Akihiko; Ozaki, Masanori

    2008-01-01

    Manipulation of photonic defect-modes in cholesteric liquid crystals (ChLCs), which are one-dimensional pseudo photonic band-gap materials have been demonstrated by an external optical field. A structural defect in which the pitch length of the ChLC in the bulk and the defect are different was introduced by inducing local polymerization in a photo-polymerizable ChLC material by a direct laser-lithography process, and infiltrating a different ChLC material as the defect medium. When an azobenzene dye-doped ChLC was infiltrated in the defect, the trans-cis isomerization of the dye upon ultraviolet (UV) exposure caused the pitch to shorten, changing the contrast in the pitch lengths at the bulk and the defect, leading to a consequent shifting of the defect-mode. The all-optical manipulation was reversible and had high reproducibility

  1. Electrically tunable whispering gallery mode microresonator based on a grapefruit-microstructured optical fiber infiltrated with nematic liquid crystals.

    Science.gov (United States)

    Yang, Chengkun; Zhang, Hao; Liu, Bo; Lin, Shiwei; Li, Yuetao; Liu, Haifeng

    2017-08-01

    An electrically tunable whispering gallery mode (WGM) microresonator based on an HF-etched microstructured optical fiber (MOF) infiltrated with nematic liquid crystals (NLCs) is proposed and experimentally demonstrated. Experimental results indicate that as the peak-to-peak voltage of the applied AC electric field increases from 160 to 220 V, WGM resonance peaks gradually move toward a shorter wavelength region by 0.527 nm with a wavelength sensitivity up to 0.01  nm/V for a TM1691 mode, and the Q-factor for each WGM resonance peak rapidly decreases with the increment of applied electric voltage. The proposed electrically controlled WGM tuning scheme shows a linear resonance wavelength shift with good spectral reversibility, which makes it a promising candidate to serve as an integrated functional photonic device in practical use and in related fundamental scientific studies.

  2. Liquid flow along a solid surface reversibly alters interfacial chemistry.

    Science.gov (United States)

    Lis, Dan; Backus, Ellen H G; Hunger, Johannes; Parekh, Sapun H; Bonn, Mischa

    2014-06-06

    In nature, aqueous solutions often move collectively along solid surfaces (for example, raindrops falling on the ground and rivers flowing through riverbeds). However, the influence of such motion on water-surface interfacial chemistry is unclear. In this work, we combine surface-specific sum frequency generation spectroscopy and microfluidics to show that at immersed calcium fluoride and fused silica surfaces, flow leads to a reversible modification of the surface charge and subsequent realignment of the interfacial water molecules. Obtaining equivalent effects under static conditions requires a substantial change in bulk solution pH (up to 2 pH units), demonstrating the coupling between flow and chemistry. These marked flow-induced variations in interfacial chemistry should substantially affect our understanding and modeling of chemical processes at immersed surfaces. Copyright © 2014, American Association for the Advancement of Science.

  3. Corneal surface temperature change as the mode of stimulation of the non-contact corneal aesthesiometer.

    Science.gov (United States)

    Murphy, P J; Morgan, P B; Patel, S; Marshall, J

    1999-05-01

    The non-contact corneal aesthesiometer (NCCA) assesses corneal sensitivity by using a controlled pulse of air, directed at the corneal surface. The purpose of this paper was to investigate whether corneal surface temperature change was a component in the mode of stimulation. Thermocouple experiment: A simple model corneal surface was developed that was composed of a moistened circle of filter paper placed on a thermocouple and mounted on a glass slide. The temperature change produced by different stimulus pressures was measured for five different ambient temperatures. Thermal camera experiment: Using a thermal camera, the corneal surface temperature change was measured in nine young, healthy subjects after exposure to different stimulus air pulses. Pulse duration was set at 0.9 s but was varied in pressure from 0.5 to 3.5 millibars. Thermocouple experiment: An immediate drop in temperature was detected by the thermocouple as soon as the air flow was incident on the filter paper. A greater temperature change was produced by increasing the pressure of the incident air flow. A relationship was found and a calibration curve plotted. Thermal camera experiment: For each subject, a drop in surface temperature was detected at each stimulus pressure. Furthermore, as the stimulus pressure increased, the induced reduction in temperature also increased. A relationship was found and a calibration curve plotted. The NCCA air-pulse stimulus was capable of producing a localized temperature change on the corneal surface. The principal mode of corneal nerve stimulation, by the NCCA air pulse, was the rate of temperature change of the corneal surface.

  4. Giant enhancement of reflectance due to the interplay between surface confined wave modes and nonlinear gain in dielectric media.

    Science.gov (United States)

    Kim, Sangbum; Kim, Kihong

    2017-12-11

    We study theoretically the interplay between the surface confined wave modes and the linear and nonlinear gain of the dielectric layer in the Otto configuration. The surface confined wave modes, such as surface plasmons or waveguide modes, are excited in the dielectric-metal bilayer by obliquely incident p waves. In the purely linear case, we find that the interplay between linear gain and surface confined wave modes can generate a large reflectance peak with its value much greater than 1. As the linear gain parameter increases, the peak appears at smaller incident angles, and the associated modes also change from surface plasmons to waveguide modes. When the nonlinear gain is turned on, the reflectance shows very strong multistability near the incident angles associated with surface confined wave modes. As the nonlinear gain parameter is varied, the reflectance curve undergoes complicated topological changes and sometimes displays separated closed curves. When the nonlinear gain parameter takes an optimally small value, a giant amplification of the reflectance by three orders of magnitude occurs near the incident angle associated with a waveguide mode. We also find that there exists a range of the incident angle where the wave is dissipated rather than amplified even in the presence of gain. We suggest that this can provide the basis for a possible new technology for thermal control in the subwavelength scale.

  5. Theoretical calculations of the surface tension of Ag(1-x)-Cu(x) liquid alloys

    International Nuclear Information System (INIS)

    Aqra, Fathi; Ayyad, Ahmed

    2011-01-01

    Highlights: → A thermodynamic model for calculating the surface tension, and its temperature and composition dependences, of liquid binary alloys is described. → The model does not require the prior knowledge of the surface concentration and Gibbs energy. → The surface tension of the liquid Ag-Cu binary alloys has been calculated as a function of temperature and concentration. → The calculated values agree well with existing experimental data. - Abstract: The surface tension of silver-copper binary liquid alloys is calculated, in the frame work of Eyring theory. The calculations were made for different compositions (mole fraction, x Cu = 0, 0.2, 0.4, 0.6, 0.8 and 1), in the temperature range 1100-1800 K. The surface tension decreases with temperature increase, at a fixed copper fraction x Cu , and increases with increasing copper content. The calculated results are appropriately compared with existing literature data.

  6. Measuring adhesion on rough surfaces using atomic force microscopy with a liquid probe

    Directory of Open Access Journals (Sweden)

    Juan V. Escobar

    2017-04-01

    Full Text Available We present a procedure to perform and interpret pull-off force measurements during the jump-off-contact process between a liquid drop and rough surfaces using a conventional atomic force microscope. In this method, a micrometric liquid mercury drop is attached to an AFM tipless cantilever to measure the force required to pull this drop off a rough surface. We test the method with two surfaces: a square array of nanometer-sized peaks commonly used for the determination of AFM tip sharpness and a multi-scaled rough diamond surface containing sub-micrometer protrusions. Measurements are carried out in a nitrogen atmosphere to avoid water capillary interactions. We obtain information about the average force of adhesion between a single peak or protrusion and the liquid drop. This procedure could provide useful microscopic information to improve our understanding of wetting phenomena on rough surfaces.

  7. A reconfigurable frequency-selective surface for dual-mode multi-band filtering applications

    Science.gov (United States)

    Majidzadeh, Maryam; Ghobadi, Changiz; Nourinia, Javad

    2017-03-01

    A reconfigurable single-layer frequency-selective surface (FSS) with dual-mode multi-band modes of operation is presented. The proposed structure is printed on a compact 10 × 10 mm2 FR4 substrate with the thickness of 1.6 mm. A simple square loop is printed on the front side while another one along with two defected vertical arms is deployed on the backside. To realise the reconfiguration, two pin diodes are embedded on the backside square loop. Suitable insertion of conductive elements along with pin diodes yields in dual-mode multi-band rejection of applicable in service frequency ranges. The first operating mode due to diodes' 'ON' state provides rejection of 2.4 GHz WLAN in 2-3 GHz, 5.2/5.8 GHz WLAN and X band in 5-12 GHz, and a part of Ku band in 13.9-16 GHz. In diodes 'OFF' state, the FSS blocks WLAN in 4-7.3 GHz, X band in 8-12.7 GHz as well as part of Ku band in 13.7-16.7 GHz. As well, high attenuation of incident waves is observed by a high shielding effectiveness (SE) in the blocked frequency bands. Also, a stable behaviour against different polarisations and angles of incidence is obtained. Comprehensive studies are conducted on a fabricated prototype to assess its performance from which encouraging results are obtained.

  8. X-Ray Reflectivity from the Surface of a Liquid Crystal:

    DEFF Research Database (Denmark)

    Pershan, P.S.; Als-Nielsen, Jens Aage

    1984-01-01

    X-ray reflectivity from the surface of a nematic liquid crystal is interpreted as the coherent superposition of Fresnel reflection from the surface and Bragg reflection from smectic order induced by the surface. Angular dependence of the Fresnel effect yields information on surface structure....... Measurement of the intensity of diffuse critical scattering relative to the Fresnel reflection yields the absolute value of the critical part of the density-density correlation function....

  9. Propagation of a TE surface mode in a relativistic electron beam–quantum plasma system

    International Nuclear Information System (INIS)

    Abdel Aziz, M.

    2012-01-01

    The dispersion properties of a transverse electric (TE) surface waves propagating along the interface between a magneto-quantum plasma–relativistic beam system and vacuum are studied by using the quantum hydrodynamic model. The general dispersion relations are derived and analyzed in some special cases of interest. Moreover, the effects of density gradients for the beam and plasma on the dispersion properties of surface waves are investigated. The kind of dispersion relations depends strongly on the ambient magnetic field B o via the gyro-frequency ω c , the quantum parameters, and the width of the plasma layer as well as the relativistic factor for the electron beam. It is found that the quantum effects play a crucial role to facilitate the propagation of TE surface waves. -- Highlights: ► Propagation of TE surface waves on bounded magneto-quantum plasma by relativistic beam is studied. ► The quantum plasma consists of transitional layer adjacent to uniform layer. ► Influence of quantum effects on the propagation of TE surface waves are taken into account. ► Effects of homogeneity and inhomogeneity for beam on TE surface waves are considered. ► It is found that quantum effects facilitate the propagation of TE surface modes.

  10. Solar wind: A possible factor driving the interannual sea surface temperature tripolar mode over North Atlantic

    Science.gov (United States)

    Xiao, Ziniu; Li, Delin

    2016-06-01

    The effect of solar wind (SW) on the North Atlantic sea surface temperature (SST) in boreal winter is examined through an analysis of observational data during 1964-2013. The North Atlantic SSTs show a pronounced meridional tripolar pattern in response to solar wind speed (SWS) variations. This pattern is broadly similar to the leading empirical orthogonal function (EOF) mode of interannual variations in the wintertime SSTs over North Atlantic. The time series of this leading EOF mode of SST shows a significant interannual period, which is the same as that of wintertime SWS. This response also appears as a compact north-south seesaw of sea level pressure and a vertical tripolar structure of zonal wind, which simultaneously resembles the North Atlantic Oscillation (NAO) in the overlying atmosphere. As compared with the typical low SWS winters, during the typical high SWS winters, the stratospheric polar night jet (PNJ) is evidently enhanced and extends from the stratosphere to the troposphere, even down to the North Atlantic Ocean surface. Notably, the North Atlantic Ocean is an exclusive region in which the SW signal spreads downward from the stratosphere to the troposphere. Thus, it seems that the SW is a possible factor for this North Atlantic SST tripolar mode. The dynamical process of stratosphere-troposphere coupling, together with the global atmospheric electric circuit-cloud microphysical process, probably accounts for the particular downward propagation of the SW signal.

  11. Excitation of surface plasmon polariton modes with multiple nitrogen vacancy centers in single nanodiamonds

    International Nuclear Information System (INIS)

    Kumar, Shailesh; Lausen, Jens L; Andersen, Sebastian K H; Roberts, Alexander S; Radko, Ilya P; Bozhevolnyi, Sergey I; Garcia-Ortiz, Cesar E; Smith, Cameron L C; Kristensen, Anders

    2016-01-01

    Nitrogen-vacancy (NV) centers in diamonds are interesting due to their remarkable characteristics that are well suited to applications in quantum-information processing and magnetic field sensing, as well as representing stable fluorescent sources. Multiple NV centers in nanodiamonds (NDs) are especially useful as biological fluorophores due to their chemical neutrality, brightness and room-temperature photostability. Furthermore, NDs containing multiple NV centers also have potential in high-precision magnetic field and temperature sensing. Coupling NV centers to propagating surface plasmon polariton (SPP) modes gives a base for lab-on-a-chip sensing devices, allows enhanced fluorescence emission and collection which can further enhance the precision of NV-based sensors. Here, we investigate coupling of multiple NV centers in individual NDs to the SPP modes supported by silver surfaces protected by thin dielectric layers and by gold V-grooves (VGs) produced via the self-terminated silicon etching. In the first case, we concentrate on monitoring differences in fluorescence spectra obtained from a source ND, which is illuminated by a pump laser, and from a scattering ND illuminated only by the fluorescence-excited SPP radiation. In the second case, we observe changes in the average NV lifetime when the same ND is characterized outside and inside a VG. Fluorescence emission from the VG terminations is also observed, which confirms the NV coupling to the VG-supported SPP modes. (paper)

  12. Excitation of surface plasmon polariton modes with multiple nitrogen vacancy centers in single nanodiamonds

    Science.gov (United States)

    Kumar, Shailesh; Lausen, Jens L.; Garcia-Ortiz, Cesar E.; Andersen, Sebastian K. H.; Roberts, Alexander S.; Radko, Ilya P.; Smith, Cameron L. C.; Kristensen, Anders; Bozhevolnyi, Sergey I.

    2016-02-01

    Nitrogen-vacancy (NV) centers in diamonds are interesting due to their remarkable characteristics that are well suited to applications in quantum-information processing and magnetic field sensing, as well as representing stable fluorescent sources. Multiple NV centers in nanodiamonds (NDs) are especially useful as biological fluorophores due to their chemical neutrality, brightness and room-temperature photostability. Furthermore, NDs containing multiple NV centers also have potential in high-precision magnetic field and temperature sensing. Coupling NV centers to propagating surface plasmon polariton (SPP) modes gives a base for lab-on-a-chip sensing devices, allows enhanced fluorescence emission and collection which can further enhance the precision of NV-based sensors. Here, we investigate coupling of multiple NV centers in individual NDs to the SPP modes supported by silver surfaces protected by thin dielectric layers and by gold V-grooves (VGs) produced via the self-terminated silicon etching. In the first case, we concentrate on monitoring differences in fluorescence spectra obtained from a source ND, which is illuminated by a pump laser, and from a scattering ND illuminated only by the fluorescence-excited SPP radiation. In the second case, we observe changes in the average NV lifetime when the same ND is characterized outside and inside a VG. Fluorescence emission from the VG terminations is also observed, which confirms the NV coupling to the VG-supported SPP modes.

  13. Adaptive Sliding Mode Control Method Based on Nonlinear Integral Sliding Surface for Agricultural Vehicle Steering Control

    Directory of Open Access Journals (Sweden)

    Taochang Li

    2014-01-01

    Full Text Available Automatic steering control is the key factor and essential condition in the realization of the automatic navigation control of agricultural vehicles. In order to get satisfactory steering control performance, an adaptive sliding mode control method based on a nonlinear integral sliding surface is proposed in this paper for agricultural vehicle steering control. First, the vehicle steering system is modeled as a second-order mathematic model; the system uncertainties and unmodeled dynamics as well as the external disturbances are regarded as the equivalent disturbances satisfying a certain boundary. Second, a transient process of the desired system response is constructed in each navigation control period. Based on the transient process, a nonlinear integral sliding surface is designed. Then the corresponding sliding mode control law is proposed to guarantee the fast response characteristics with no overshoot in the closed-loop steering control system. Meanwhile, the switching gain of sliding mode control is adaptively adjusted to alleviate the control input chattering by using the fuzzy control method. Finally, the effectiveness and the superiority of the proposed method are verified by a series of simulation and actual steering control experiments.

  14. Ultracompact 1×4 TM-polarized beam splitter based on photonic crystal surface mode.

    Science.gov (United States)

    Jiang, Bin; Zhang, Yejin; Wang, Yufei; Liu, Anjin; Zheng, Wanhua

    2012-05-01

    We provide an improved surface-mode photonic crystal (PhC) T-junction waveguide, combine it with an improved PhC bandgap T-junction waveguide, and then provide an ultracompact 1×4 TM-polarized beam splitter. The energy is split equally into the four output waveguides. The maximal transmission ratio of each output waveguide branch equals 24.7%, and the corresponding total transmission ratio of the ultracompact 1×4 beam splitter equals 98.8%. The normalized frequency of maximal transmission ratio is 0.397(2πc/a), and the bandwidth of the ultracompact 1×4 TM-polarized beam splitter is 0.0106(2πc/a). To the best of our knowledge, this is the first time such a high-efficiency 1×4 beam splitter exploiting the nonradiative surface mode as a guided mode has been proposed. Although we only employed a 1×4 beam splitter, our design can easily be extended to other 1×n beam splitters.

  15. Transmission-lattice based geometric phase analysis for evaluating the dynamic deformation of a liquid surface.

    Science.gov (United States)

    Shi, Wenxiong; Huang, Xianfu; Liu, Zhanwei

    2014-05-05

    Quantitatively measuring a dynamic liquid surface often presents a challenge due to high transparency, fluidity and specular reflection. Here, a novel Transmission-Lattice based Geometric Phase Analysis (TLGPA) method is introduced. In this method, a special lattice is placed underneath a liquid to be tested and, when viewed from above, the phase of the transmission-lattice image is modulated by the deformation of the liquid surface. Combining this with multi-directional Newton iteration algorithms, the dynamic deformation field of the liquid surface can be calculated from the phase variation of a series of transmission-lattice images captured at different moments. The developed method has the advantage of strong self-adaption ability to initial lattice rotational errors and this is discussed in detail. Dynamic 3D ripples formation and propagation was investigated and the results obtained demonstrated the feasibility of the method.

  16. Investigation of surface charge density on solid–liquid interfaces by modulating the electrical double layer

    International Nuclear Information System (INIS)

    Moon, Jong Kyun; Song, Myung Won; Pak, Hyuk Kyu

    2015-01-01

    A solid surface in contact with water or aqueous solution usually carries specific electric charges. These surface charges attract counter ions from the liquid side. Since the geometry of opposite charge distribution parallel to the solid–liquid interface is similar to that of a capacitor, it is called an electrical double layer capacitor (EDLC). Therefore, there is an electrical potential difference across an EDLC in equilibrium. When a liquid bridge is formed between two conducting plates, the system behaves as two serially connected EDLCs. In this work, we propose a new method for investigating the surface charge density on solid–liquid interfaces. By mechanically modulating the electrical double layers and simultaneously applying a dc bias voltage across the plates, an ac electric current can be generated. By measuring the voltage drop across a load resistor as a function of bias voltage, we can study the surface charge density on solid–liquid interfaces. Our experimental results agree very well with the simple equivalent electrical circuit model proposed here. Furthermore, using this method, one can determine the polarity of the adsorbed state on the solid surface depending on the material used. We expect this method to aid in the study of electrical phenomena on solid–liquid interfaces. (paper)

  17. Effect of Liquid Ga on Metal Surfaces: Characterization of Morphology and Chemical Composition of Metals Heated in Liquid Ga

    Directory of Open Access Journals (Sweden)

    Eun Je Lee

    2013-01-01

    Full Text Available This study investigates the effect of liquid gallium (Ga on metal foils made of titanium (Ti, niobium (Nb, and molybdenum (Mo. The Ti, Nb, and Mo foils were heated in liquid Ga at 120°C for a maximum of two weeks. After heating, the changes in the morphology and the chemical composition of the metal foils were analyzed by using a field emission scanning electron microscope, energy-dispersive X-ray spectrometer, X-ray diffractometer, and X-ray photoelectron spectrometer. The results of the analysis indicated that the Nb foil showed the minimum adhesion of liquid Ga to the surface while the maximum amount of liquid Ga was observed to adhere to the Ti foil. In addition, the Nb foil was oxidized and the Mo foil was reduced during the heating process. Considering these effects, we conclude that Mo may be used as an alternative encapsulation material for Ga in addition to Nb, which is used as the conventional encapsulation material, due to its chemical resistance against oxidation in hot liquid Ga.

  18. Linear theory period ratios for surface helium enhanced double-mode Cepheids

    International Nuclear Information System (INIS)

    Cox, A.N.; Hodson, S.W.; King, D.S.

    1979-01-01

    Linear nonadiabatic theory period ratios for models of double-mode Cepheids with their two periods between 1 and 7 days have been computed, assuming differing amounts and depths of surface helium enhancement. Evolution theory masses and luminosities are found to be consistent with the observed periods. All models give Pi 1 /Pi 0 approx. =0.70 as observed for the 11 known variables, contrary to previous theoretical conclusions. The composition structure that best fits the period ratios has the helium mass fraction in the outer 10 -3 of the stellar mass (T< or =250,000 K) as 0.65, similar to a previous model for the triple-mode pulsator AC And. This enrichment can be established by a Cepheid wind and downward inverted μ gradient instability mixing in the lifetime of these low-mass classical Cepheids

  19. System upgradation for surface mode negative ion beam extraction experiments in ROBIN

    International Nuclear Information System (INIS)

    Pandya, Kaushal; Bansal, Gourab; Soni, Jignesh

    2015-01-01

    ROBIN (Replica Of BATMAN source in India) is a replica of BATMAN source of IPP, Garching. Plasma production (inductively coupled, RF produced plasma), plasma diagnostic (langmuir probe, optical emission spectroscopy), negative ion beam extraction in volume mode with reduced extraction area of 2 cm 2 (4 apertures) using small bench top type power supply (10kV, 400mA), with increase extraction area of 73 cm 2 (146 apertures) and using actual power supplies (Extraction Power Supply System, EPSS (11kV, 35A), and Accelerator Power Supply System, APSS (35kV, 15A)) and beam diagnostic etc have been performed successfully in ROBIN. This paper will describe the details of the system upgradation for surface mode negative ion experiments and its performance in ROBIN

  20. Rate-Dependent Slip of Newtonian Liquid at Smooth Surfaces

    International Nuclear Information System (INIS)

    Zhu, Yingxi; Granick, Steve

    2001-01-01

    Newtonian fluids were placed between molecularly smooth surfaces whose spacing was vibrated at spacings where the fluid responded as a continuum. Hydrodynamic forces agreed with predictions from the no-slip boundary condition only provided that flow rate (peak velocity normalized by spacing) was low, but implied partial slip when it exceeded a critical level, different in different systems, correlated with contact angle (surface wettability). With increasing flow rate and partially wetted surfaces, hydrodynamic forces became up to 2--4 orders of magnitude less than expected by assuming the no-slip boundary condition that is commonly stated in textbooks

  1. Evaporation and condensation at a liquid surface. II. Methanol

    Science.gov (United States)

    Matsumoto, Mitsuhiro; Yasuoka, Kenji; Kataoka, Yosuke

    1994-11-01

    The rates of evaporation and condensation of methanol under the vapor-liquid equilibrium condition at the temperature of 300 and 350 K are investigated with a molecular dynamics computer simulation. Compared with the argon system (reported in part I), the ratio of self-reflection is similar (˜10%), but the ratio of molecule exchange is several times larger than the argon, which suggests that the conventional assumption of condensation as a unimolecular process completely fails for associating fluids. The resulting total condensation coefficient is 20%-25%, and has a quantitative agreement with a recent experiment. The temperature dependence of the evaporation-condensation behavior is not significant.

  2. Constant pressure mode extended simple gradient liquid chromatography system for micro and nanocolumns

    Czech Academy of Sciences Publication Activity Database

    Šesták, Jozef; Kahle, Vladislav

    2014-01-01

    Roč. 1350, Jul (2014), s. 68-71 ISSN 0021-9673 R&D Projects: GA MV VG20102015023 Institutional support: RVO:68081715 Keywords : constant pressure HPLC * gradient elution * simple liquid chromatograph Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 4.169, year: 2014 http://hdl.handle.net/11104/0233990

  3. Interfacial morphologies and growth modes of F.C.C. metallic crystals from liquid alloys

    International Nuclear Information System (INIS)

    Camel, Denis

    1980-01-01

    Equilibrium and growth morphologies of f.c.c. metallic crystals in contact with liquid alloys have been observed in-situ using transmission electron microscopy. These morphologies have been discussed in terms of atomic interfacial structure and growth mechanisms with the help of a statistical thermodynamic model which takes into account the effects of chemical interactions and interfacial adsorption. (author) [fr

  4. Submicrosecond electro-optic switching in the liquid-crystal smectic A phase: The soft-mode ferroelectric effect

    Science.gov (United States)

    Andersson, G.; Dahl, I.; Keller, P.; Kuczyński, W.; Lagerwall, S. T.; Skarp, K.; Stebler, B.

    1987-08-01

    A new liquid-crystal electro-optic modulating device similar to the surface-stabilized ferroelectric liquid-crystal device is described. It uses the same kind of ferroelectric chiral smectics and the same geometry as that device (thin sample in the ``bookshelf '' layer arrangement) but instead of using a tilted smectic phase like the C* phase, it utilizes the above-lying, nonferroelectric A phase, taking advantage of the electroclinic effect. The achievable optical intensity modulation that can be detected through the full range of the A phase is considerably lower than for the surface-stabilized device, but the response is much faster. Furthermore, the response is strictly linear with respect to the applied electric field. The device concept is thus appropriate for modulator rather than for display applications. We describe the underlying physics and present measurements of induced tilt angle, of light modulation depth, and of rise time.

  5. Asymmetric liquid wetting and spreading on surfaces with slanted micro-pillar arrays

    KAUST Repository

    Yang, Xiaoming

    2013-01-01

    Uni-directional liquid spreading on asymmetric silicone-fabricated nanostructured surfaces has recently been reported. In this work, uniformly deflected polydimethylsiloxane (PDMS) micro-pillars covered with silver films were fabricated. Asymmetric liquid wetting and spreading behaviors in a preferential direction were observed on the slanted micro-pillar surfaces and a micro-scale thin liquid film advancing ahead of the bulk liquid droplet was clearly observed by high-speed video imaging. It is found that the slanted micro-pillar array is able to promote or inhibit the propagation of this thin liquid film in different directions by the asymmetric capillary force. The spreading behavior of the bulk liquid was guided and finally controlled by this micro-scale liquid film. Different spreading regimes are defined by the relationship between the liquid intrinsic contact angle and the critical angles, which were determined by the pillar height, pillar deflection angle and inter-pillar spacing. © The Royal Society of Chemistry 2013.

  6. Electrostatics in liquids: from electrolytes and suspensions towards emulsions and patchy surfaces

    NARCIS (Netherlands)

    van Roij, R.H.H.G.

    2010-01-01

    These lecture notes describe ionic screening of liquid-immersed charged surfaces within the linear and the nonlinear Poisson–Boltzmann theory. The classic Gouy–Chapman description of a single charged planar surface is extensively described, as well as its linearised version and the connection with

  7. The effect of holes in the dispersion relation of propagative surface plasmon modes of nanoperforated semitransparent metallic films

    Energy Technology Data Exchange (ETDEWEB)

    Kekesi, R., E-mail: renata.kekesi@csic.es; Meneses-Rodríguez, D.; García-Pérez, F.; González, M. U.; García-Martín, A.; Cebollada, A.; Armelles, G., E-mail: gaspar@imm.cnm.csic.es [IMM-Instituto de Microelectrónica de Madrid (CNM-CSIC), Isaac Newton 8, PTM, E-28760 Tres Cantos, Madrid (Spain)

    2014-10-07

    We have analysed the effect that holes have on the properties of propagative surface plasmon modes in semitransparent nanoperforated Au films. The modes have been excited in Kretschmann configuration. Contrary to continuous films, where only one mode is excited, two modes are observed in Au nanohole array. The origin of this different behavior is discussed using effective optical properties for the nanoperforated films. The presence of the holes affects the effective optical constants of the membranes in two ways: it changes the contribution of the free electrons, and it gives rise to a localized transition due to a hole induced plasmon resonance. This localized transition interacts with the propagative surface plasmon modes, originating the two detected modes.

  8. The effect of holes in the dispersion relation of propagative surface plasmon modes of nanoperforated semitransparent metallic films

    International Nuclear Information System (INIS)

    Kekesi, R.; Meneses-Rodríguez, D.; García-Pérez, F.; González, M. U.; García-Martín, A.; Cebollada, A.; Armelles, G.

    2014-01-01

    We have analysed the effect that holes have on the properties of propagative surface plasmon modes in semitransparent nanoperforated Au films. The modes have been excited in Kretschmann configuration. Contrary to continuous films, where only one mode is excited, two modes are observed in Au nanohole array. The origin of this different behavior is discussed using effective optical properties for the nanoperforated films. The presence of the holes affects the effective optical constants of the membranes in two ways: it changes the contribution of the free electrons, and it gives rise to a localized transition due to a hole induced plasmon resonance. This localized transition interacts with the propagative surface plasmon modes, originating the two detected modes.

  9. Surface tension of liquid Cu-Ti binary alloys measured by electromagnetic levitation and thermodynamic modelling

    International Nuclear Information System (INIS)

    Amore, S.; Brillo, J.; Egry, I.; Novakovic, R.

    2011-01-01

    The surface tension of liquid Cu-Ti alloys has been measured by using the containerless technique of electromagnetic levitation and theoretically calculated in the framework of the compound formation model. Measurements have been carried out on alloys covering the entire range of composition and over the temperature range 1275-2050 K. For all investigated alloys the surface tension can be described by a linear function of the temperature with negative slope. Due to the presence of different intermetallic compounds in the solid state the surface properties of liquid Cu-Ti alloys are satisfactory described by the compound formation model.

  10. Ballistic Evaporation and Solvation of Helium Atoms at the Surfaces of Protic and Hydrocarbon Liquids.

    Science.gov (United States)

    Johnson, Alexis M; Lancaster, Diane K; Faust, Jennifer A; Hahn, Christine; Reznickova, Anna; Nathanson, Gilbert M

    2014-11-06

    Atomic and molecular solutes evaporate and dissolve by traversing an atomically thin boundary separating liquid and gas. Most solutes spend only short times in this interfacial region, making them difficult to observe. Experiments that monitor the velocities of evaporating species, however, can capture their final interactions with surface solvent molecules. We find that polarizable gases such as N2 and Ar evaporate from protic and hydrocarbon liquids with Maxwell-Boltzmann speed distributions. Surprisingly, the weakly interacting helium atom emerges from these liquids at high kinetic energies, exceeding the expected energy of evaporation from salty water by 70%. This super-Maxwellian evaporation implies in reverse that He atoms preferentially dissolve when they strike the surface at high energies, as if ballistically penetrating into the solvent. The evaporation energies increase with solvent surface tension, suggesting that He atoms require extra kinetic energy to navigate increasingly tortuous paths between surface molecules.

  11. Numerical simulation of liquid film flow on revolution surfaces with momentum integral method

    International Nuclear Information System (INIS)

    Bottoni Maurizio

    2005-01-01

    The momentum integral method is applied in the frame of safety analysis of pressure water reactors under hypothetical loss of coolant accident (LOCA) conditions to simulate numerically film condensation, rewetting and vaporization on the inner surface of pressure water reactor containment. From the conservation equations of mass and momentum of a liquid film arising from condensation of steam upon the inner of the containment during a LOCA in a pressure water reactor plant, an integro-differential equation is derived, referring to an arbitrary axisymmetric surface of revolution. This equation describes the velocity distribution of the liquid film along a meridian of a surface of revolution. From the integro-differential equation and ordinary differential equation of first order for the film velocity is derived and integrated numerically. From the velocity distribution the film thickness distribution is obtained. The solution of the enthalpy equation for the liquid film yields the temperature distribution on the inner surface of the containment. (authors)

  12. Demonstrating electromagnetic control of free-surface, liquid-metal flows relevant to fusion reactors

    Science.gov (United States)

    Hvasta, M. G.; Kolemen, E.; Fisher, A. E.; Ji, H.

    2018-01-01

    Plasma-facing components (PFC’s) made from solid materials may not be able to withstand the large heat and particle fluxes that will be produced within next-generation fusion reactors. To address the shortcomings of solid PFC’s, a variety of liquid-metal (LM) PFC concepts have been proposed. Many of the suggested LM-PFC designs rely on electromagnetic restraint (Lorentz force) to keep free-surface, liquid-metal flows adhered to the interior surfaces of a fusion reactor. However, there is very little, if any, experimental data demonstrating that free-surface, LM-PFC’s can actually be electromagnetically controlled. Therefore, in this study, electrical currents were injected into a free-surface liquid-metal that was flowing through a uniform magnetic field. The resultant Lorentz force generated within the liquid-metal affected the velocity and depth of the flow in a controllable manner that closely matched theoretical predictions. These results show the promise of electromagnetic control for LM-PFC’s and suggest that electromagnetic control could be further developed to adjust liquid-metal nozzle output, prevent splashing within a tokamak, and alter heat transfer properties for a wide-range of liquid-metal systems.

  13. The role of integer-mode rational surface on peaked profile formation in toroidal rotation velocity and ion temperature

    International Nuclear Information System (INIS)

    Koide, Yoshihiko; Ishida, Shin-ichi; Sakasai, Akira

    1991-03-01

    A particular role of integer-mode rational surfaces on the formation of peaked T i (r) and V t (r) is observed. In the case of JT-60 hot-ion regime, the plasma spontaneously changes its peaking region from the inside of q=2 surface to that of broader q=3 surface. (author)

  14. Modeling, design, packing and experimental analysis of liquid-phase shear-horizontal surface acoustic wave sensors

    Science.gov (United States)

    Pollard, Thomas B

    Recent advances in microbiology, computational capabilities, and microelectromechanical-system fabrication techniques permit modeling, design, and fabrication of low-cost, miniature, sensitive and selective liquid-phase sensors and lab-on-a-chip systems. Such devices are expected to replace expensive, time-consuming, and bulky laboratory-based testing equipment. Potential applications for devices include: fluid characterization for material science and industry; chemical analysis in medicine and pharmacology; study of biological processes; food analysis; chemical kinetics analysis; and environmental monitoring. When combined with liquid-phase packaging, sensors based on surface-acoustic-wave (SAW) technology are considered strong candidates. For this reason such devices are focused on in this work; emphasis placed on device modeling and packaging for liquid-phase operation. Regarding modeling, topics considered include mode excitation efficiency of transducers; mode sensitivity based on guiding structure materials/geometries; and use of new piezoelectric materials. On packaging, topics considered include package interfacing with SAW devices, and minimization of packaging effects on device performance. In this work novel numerical models are theoretically developed and implemented to study propagation and transduction characteristics of sensor designs using wave/constitutive equations, Green's functions, and boundary/finite element methods. Using developed simulation tools that consider finite-thickness of all device electrodes, transduction efficiency for SAW transducers with neighboring uniform or periodic guiding electrodes is reported for the first time. Results indicate finite electrode thickness strongly affects efficiency. Using dense electrodes, efficiency is shown to approach 92% and 100% for uniform and periodic electrode guiding, respectively; yielding improved sensor detection limits. A numerical sensitivity analysis is presented targeting viscosity

  15. First results from negative ion beam extraction in ROBIN in surface mode

    Science.gov (United States)

    Pandya, Kaushal; Gahlaut, Agrajit; Yadav, Ratnakar K.; Bhuyan, Manas; Bandyopadhyay, Mainak; Das, B. K.; Bharathi, P.; Vupugalla, Mahesh; Parmar, K. G.; Tyagi, Himanshu; Patel, Kartik; Bhagora, Jignesh; Mistri, Hiren; Prajapati, Bhavesh; Pandey, Ravi; Chakraborty, Arun. K.

    2017-08-01

    ROBIN, the first step in the Indian R&D program on negative ion beams has reached an important milestone, with the production of negative ions in the surface conversion mode through Cesium (Cs) vapor injection into the source. In the present set-up, negative hydrogen ion beam extraction is effected through an extraction area of ˜73.38 cm2 (146 apertures of 8mm diameter). The three grid electrostatic accelerator system of ROBIN is fed by high voltage DC power supplies (Extraction Power Supply System: 11kV, 35A and Acceleration Power Supply System: 35kV, 15A). Though, a considerable reduction of co-extracted electron current is usually observed during surface mode operation, in order to increase the negative ion current, various other parameters such as plasma grid temperature, plasma grid bias, extraction to acceleration voltage ratio, impurity control and Cs recycling need to be optimized. In the present experiments, to control and to understand the impurity behavior, a Cryopump (14,000 l/s for Hydrogen) is installed along with a Residual Gas Analyzer (RGA). To characterize the source plasma, two sets of Langmuir probes are inserted through the diagnostic flange ports available at the extraction plane. To characterize the beam properties, thermal differential calorimeter, Doppler Shift Spectroscopy and electrical current measurements are implemented in ROBIN. In the present set up, all the negative ion beam extraction experiments have been performed by varying different experimental parameters e.g. RF power (30-70 kW), source operational pressure (0.3 - 0.6Pa), plasma grid bias voltage, extraction & acceleration voltage combination etc. The experiments in surface mode operation is resulted a reduction of co-extracted electron current having electron to ion ratio (e/i) ˜2 whereas the extracted negative ion current density was increased. However, further increase in negative ion current density is expected to be improved after a systematic optimization of the

  16. Waves on the surface of a boiling liquid at various medium stratifications

    International Nuclear Information System (INIS)

    Sinkevich, O. A.

    2015-01-01

    The stability of relatively small perturbations of the stationary state consisting of a plane liquid layer and a vapor film is studied when no liquid evaporation or vapor condensation occurs in the stationary state. In this case, heat from a hot to cold wall is removed through a vapor–liquid layer via heat conduction. The boundary conditions that take into account liquid evaporation (appearance of a mass flux) at the vapor–liquid phase surface and the temperature dependence of the saturation pressure are derived. Dispersion equations are obtained. The wave processes for the stable (light vapor under a liquid layer) and unstable stratifications of the phases at rest and during their relative motion are studied. The deformation of the phase boundary results in liquid evaporation, changes in the boiling temperature and the saturation pressure, and generation of weakly damped low-amplitude waves of a new type. These waves ensure the stability of a vapor film under a liquid layer at rest or a liquid layer moving at a constant velocity in the gravity field. The velocities of these waves are much higher than the gravity wave velocities. The critical heat flows and wavelengths at which wave boiling regimes at normal pressure can exist are determined, and the calculated and experimental data are compared

  17. Refining femtosecond laser induced periodical surface structures with liquid assist

    International Nuclear Information System (INIS)

    Jiao, L.S.; Ng, E.Y.K.; Zheng, H.Y.

    2013-01-01

    Highlights: ► LIPSS on silicon wafer was made in air and in ethanol environment. ► Ethanol environment produce cleaner surface ripples. ► Ethanol environment decrease spatial wavelength of the LIPSS by 30%. ► More number of pulses produce smaller spatial wavelength in air. ► Number of pulses do not influence spatial wavelength in ethanol environment. - Abstract: Laser induced periodic surface structures were generated on silicon wafer using femtosecond laser. The medium used in this study is both air and ethanol. The laser process parameters such as wavelength, number of pulse, laser fluence were kept constant for both the mediums. The focus of the study is to analyze spatial wavelength. When generating surface structures with air as a medium and same process parameter of the laser, spatial wavelength results showed a 30% increase compared to ethanol. The cleanliness of the surface generated using ethanol showed considerably less debris than in air. The results observed from the above investigation showed that the medium plays a predominant role in the generation of surface structures.

  18. Measurement of anchoring coefficient of homeotropically aligned nematic liquid crystal using a polarizing optical microscope in reflective mode

    Directory of Open Access Journals (Sweden)

    Sang-In Baek

    2015-09-01

    Full Text Available Although the homeotropic alignment of liquid crystals is widely used in LCD TVs, no easy method exists to measure its anchoring coefficient. In this study, we propose an easy and convenient measurement technique in which a polarizing optical microscope is used in the reflective mode with an objective lens having a low depth of focus. All measurements focus on the reflection of light near the interface between the liquid crystal and alignment layer. The change in the reflected light is measured by applying an electric field. We model the response of the director of the liquid crystal to the electric field and, thus, the change in reflectance. By adjusting the extrapolation length in the calculation, we match the experimental and calculated results and obtain the anchoring coefficient. In our experiment, the extrapolation lengths were 0.31 ± 0.04 μm, 0.32 ± 0.08 μm, and 0.23 ± 0.05 μm for lecithin, AL-64168, and SE-5662, respectively.

  19. Design and fabrication of a piezoelectric mode 2 sensor based on optical modulated liquid crystal and spiropyran

    International Nuclear Information System (INIS)

    Chen, Kuan-Ting; Lee, Chih-Kung; Chang, Chin-Kai; Kuo, Hui-Lung

    2011-01-01

    In this paper, we propose an innovative photoelectric material made of a mixture of liquid crystal and spiropyran which can be used to tailor the performance of piezoelectric sensors. The impedance variation of this photoelectric material can be controlled using different ultraviolet (UV) irradiation times. We found that the impedance of the liquid crystal–spiropyran mixture remains stable after the UV irradiation. Results showed that UV irradiation at 180 s resulted in the lowest mixture impedance. It appears that the electrical properties of the mixture have great potential to modulate a piezoelectric system since UV irradiation can be used to tailor the impedance of a photosensitive electrode made of a liquid crystal–spiropyran sensor for PZT (i.e. lead zirconate titanate) modal actuator/sensor applications. The main innovation of this paper is the demonstration of a new approach towards producing a positive and negative bias voltage in different regions of a sensor by using UV illumination for different time periods. A one-dimensional mode 2 sensor for a cantilever beam was designed and tested to verify the validity of this innovative approach. Since UV illumination can be changed in situ or in real time, this research also represents the creation of an optically defined/tailored modal sensor. In the future, a two-dimensional optical modal control could also be obtained using the method demonstrated

  20. Effect of electrolytes on surface tension and surface adsorption of 1-hexyl-3-methylimidazolium chloride ionic liquid in aqueous solution

    International Nuclear Information System (INIS)

    Ghasemian, Ensieh; Najafi, Mojgan; Rafati, Amir Abbas; Felegari, Zahra

    2010-01-01

    Surface and bulk properties of 1-hexyl-3-methylimidazolium chloride [C 6 mim][Cl] as an ionic liquid (IL) have been investigated by surface tension and electrical conductivity techniques at various temperatures. Results reveal that the ionic liquid behaves as surfactant-like and aggregates in aqueous solution. Critical aggregation concentration (cac) values obtained by conductivity and surface tension measurements are in good agreement with values found in the literature. A series of important and useful adsorption parameters including cac, surface excess concentration (Γ), and minimum surface area per molecule (A min ) at the air + water interface were estimated from surface tension in the presence and absence of different electrolytes. Obtained data show that the surface tension as well as the cac of [C 6 mim][Cl] is reduced by electrolytes. Also, values of surface excess concentration (Γ) show that the IL ions in the presence of electrolyte have much larger affinity to adsorption at the surface and this affinity increased in aqueous electrolyte solution in the order of I - > Br - > Cl - for counter ion of salts that was explained in terms of a larger repulsion of chloride anions from interface to the bromide and iodide anion as well as difference in their excess polarizability.

  1. Structure in a confined smectic liquid crystal with competing surface and sample elasticities

    International Nuclear Information System (INIS)

    Idziak, S.H.; Koltover, I.; Israelachvili, J.N.; Safinya, C.R.

    1996-01-01

    We report on studies using the x-ray surface forces apparatus (XSFA) to compare the structure of a liquid crystal confined between hard surfaces and, for the first time, between soft surfaces that can deform due to the stresses imposed by the confined fluid. We find that the alignment of smectic domains in confined films depends critically on both the shape and compliance of the confining walls or surfaces: open-quote open-quote Soft surfaces close-quote close-quote exhibit a critical gap thickness of 3.4 μm for the liquid crystal studied at which maximum alignment occurs, while open-quote open-quote hard surfaces close-quote close-quote do not exhibit gap-dependent alignment. copyright 1996 The American Physical Society

  2. Resonant and kinematical enhancement of He scattering from LiF(001) surface and pseudosurface vibrational normal modes

    International Nuclear Information System (INIS)

    Nichols, W.L.; Weare, J.H.

    1986-01-01

    One-phonon cross sections calculated from sagittally polarized vibrational normal modes account for most salient inelastic-scattering intensities seen in He-LiF(001) and measurements published by Brusdeylins, Doak, and Toennies. We have found that most inelastic intensities which cannot be attributed to potential resonances can be explained as kinematically enhanced scattering from both surface and pseudosurface bulk modes

  3. Multiparameter-dependent spontaneous emission in PbSe quantum dot-doped liquid-core multi-mode fiber

    International Nuclear Information System (INIS)

    Zhang, Lei; Zhang, Yu; Wu, Hua; Zhang, Tieqiang; Gu, Pengfei; Chu, Hairong; Cui, Tian; Wang, Yiding; Zhang, Hanzhuang; Zhao, Jun; Yu, William W.

    2013-01-01

    A theoretical model was established in this paper to analyze the properties of 3.50 and 4.39 nm PbSe quantum dot-doped liquid-core multi-mode fiber. This model was applicable to both single- and multi-mode fiber. The three-level system-based light-propagation equations and rate equations were used to calculate the guided spontaneous emission spectra. Considering the multi-mode in the fiber, the normalized intensity distribution of transversal model was improved and simplified. The detailed calculating results were thus obtained and explained using the above-mentioned model. The redshift of the peak position and the evolution of the emission power were observed and analyzed considering the influence of the fiber length, fiber diameter, doping concentration, and the pump power. The redshift increased with the increases of fiber length, fiber diameter, and doping concentration. The optimal fiber length, fiber diameter, and doping concentration were analyzed and confirmed, and the related spontaneous emission power was obtained. Besides, the normalized emission intensity increased with the increase of pump power in a nearly linear way. The calculating results fitted well to the experimental data

  4. US assessment of free surface liquid metal divertors -- Design analysis and R and D needs

    International Nuclear Information System (INIS)

    Mattas, R.F.

    1997-01-01

    One of the objectives of the restructured US Fusion Energy Sciences Program is to identify and evaluate new high performance concepts for advanced technology with high neutron wall load capability and attractive safety and environmental features. One promising technology specified by the Advanced Technologies and Materials Working Group is liquid plasma-facing surfaces for divertors. Some of the possible advantages of using liquid surfaces in divertors, relative to conventional solid surface approaches, include higher surface heat flux capability, continuously renewable surfaces, and higher temperature operation. A planning activity has been undertaken to identify the work to be performed over approximately three years to evaluate liquid surface concepts on the basis of such factors as their compatibility with fusion plasmas, high power density handling capabilities, engineering feasibility, lifetime, safety, and R and D requirements. A group, known as the Advanced Liquid Plasma-facing Surface (ALPS) planning group, was organized to prepare a plan for the activities needed to conduct such an evaluation. This paper will summarize the work of the ALPS group including recommendations on specific activities and a tentative schedule

  5. Extreme Wetting-Resistant Multiscale Nano-/Microstructured Surfaces for Viscoelastic Liquid Repellence

    Directory of Open Access Journals (Sweden)

    Aoythip Chunglok

    2016-01-01

    Full Text Available We demonstrate exceptional wetting-resistant surfaces capable of repelling low surface tension, non-Newtonian, and highly viscoelastic liquids. Theoretical analysis and experimental result confirm that a higher level of multiscale roughness topography composed of at least three structural length scales, ranging from nanometer to supermicron sizes, is crucial for the reduction of liquid-solid adhesion hysteresis. With Cassie-Baxter nonwetting state satisfied at all roughness length scales, the surface has been proven to effectively repel even highly adhesive liquid. Practically, this high-level hierarchical structure can be achieved through fractal-like structures of silica aggregates induced by siloxane oligomer interparticle bridges. The induced aggregation and surface functionalization of the silica particles can be performed simultaneously within a single reaction step, by utilizing trifunctional fluoroalkylsilane precursors that largely form a disordered fluoroalkylsiloxane grafting layer under the presence of sufficient native moisture preadsorbed at the silica surface. Spray-coating deposition of a particle surface layer on a precoated primer layer ensures facile processability and scalability of the fabrication method. The resulting low-surface-energy multiscale roughness exhibits outstanding liquid repellent properties, generating equivalent lotus effect for highly viscous and adhesive natural latex concentrate, with apparent contact angles greater than 160°, and very small roll-off angles of less than 3°.

  6. AFM imaging of bacteria in liquid media immobilized on gelatin coated mica surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Doktycz, M.J.; Sullivan, C.J.; Hoyt, P.R.; Pelletier, D.A.; Wu, S.; Allison, D.P

    2003-10-15

    Immobilization of particulates, especially biomolecules and cells, onto surfaces is critical for imaging with the atomic force microscope (AFM). In this paper, gelatin coated mica surfaces are shown to be suitable for immobilizing and imaging both gram positive, Staphylococcus aureus, and gram negative, Escherichia coli, bacteria in both air and liquid environments. Gelatin coated surfaces are shown to be superior to poly-L-lysine coated surfaces that are commonly used for the immobilization of cells. This cell immobilization technique is being developed primarily for live cell imaging of Rhodopseudomonas palustris. The genome of R. palustris has been sequenced and the organism is the target of intensive studies aimed at understanding genome function. Images of R. palustris grown both aerobically and anaerobically in liquid media are presented. Images in liquid media show the bacteria is rod shaped and smooth while images in air show marked irregularity and folding of the surface. Significant differences in the vertical dimension are also apparent with the height of the bacteria in liquid being substantially greater than images taken in air. In air immobilized bacterial flagella are clearly seen while in liquid this structure is not visible. Additionally, significant morphological differences are observed that depend on the method of bacterial growth.

  7. Stability conditions of stationary rupture of liquid layers on an immiscible fluid surface

    Energy Technology Data Exchange (ETDEWEB)

    Viviani, A. [Seconda Univ. di Napoli, Aversa (Italy). Facolta di Ingegneria; Kostarev, K.; Shmyrov, A.; Zuev, A. [Inst. of Continuous Media Mechanics, Perm (Russian Federation)

    2009-07-01

    The stationary equilibrium shape of a 3-phase liquids-gas system was investigated. The system consisted of a horizontal liquid layer with an upper free boundary placed on the immiscible fluid interface. The study investigated the stability conditions of rupture of the liquid layer surface. The dependence of rupture parameters on the experimental cuvette diameter and layer thickness was investigated, as well as the difference in the values of surface tension of the examined fluids. The 2-layer system of horizontal fluid layers was formed in a glass cylindrical cuvette. The liquid substrate was tetrachloride carbon (CCI{sub 4}), while upper layers included water, glycerine, ethyleneglycol, and aqueous solutions of 1,4-butanediol C{sub 4}H{sub 10}O{sub 2} and isopropanol C{sub 3H8L}. Initially, the surface of the substrate fluid was overlaid with a horizontal liquid layer. The rupture was formed by subjecting the layer surface to short-time actions of a narrow directional air jet. After rupture formation, the layer thickness increased gradually. The measurements demonstrated that the rupture diameter depends on the initial thickness of the upper layer as well as the diameter of the cuvette, and the difference in the values of the surface tension of the examined fluids. Analysis of the experimental relationships indicated that the critical thickness of the breaking layer is a constant value for any specific pairs of fluids. 4 refs., 7 figs.

  8. A fast anharmonic mode in electrooptical switching of liquid crystal structures based on chiral nematics

    Energy Technology Data Exchange (ETDEWEB)

    Palto, S. P., E-mail: palto@online.ru; Barnik, M I; Blinov, L M; Umanskii, B. A., E-mail: umanskii@yahoo.com; Shtykov, N M [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)

    2010-09-15

    Polarization, spectral, and relaxation features of a new electrooptical effect in oriented layers of chiral nematic liquid crystals (LCs) are considered. The physics behind this electrooptical effect is the induction of higher order spatial harmonics in the helical distribution of the director field, which ensures the high speed of electrooptical response. It is shown that the spectral properties of the electrooptical response can be effectively controlled by varying the optical anisotropy of the LC and the pitch of the helical structure.

  9. Impurity deposition on surface probes during different operation modes at EXTRAP T1

    International Nuclear Information System (INIS)

    Gudowska, I.; Bergsaker, H.; Hellblom, G.

    1991-01-01

    Surface probes were used in the impurity control program during initial operation of the EXTRAP T1 device. The EXTRAP concept, design and operation characteristics are given elsewhere. The dimensions of the device are R/a=0.5m/0.06m. Four different modes of operation were studied: pure EXTRAP, mixed EXTRAP, RFP and ULQ. Briefly, all four are toroidal plasma discharges, with poloidal magnetic field due to the toroidal plasma current. In the ULQ case, a relatively strong external toroidal magnetic field is applied. In the RFP, and in the mixed mode, an external toroidal field is applied early in the discharge, and the plasma subsequently relaxes into a state with self-generated toroidal field. In the EXTRAP and mixed EXTRAP modes, an additional strong external octupole field is applied, breaking the poloidal symmetry. Throughout the initial period of operation of the device, the plasma performance was largely dominated by impurities, in particular fluorine, which was present due to an accidental contamination of the vessel. Probes have been exposed in wall/liner position, and the objective has been to measure erosion and deposition and try to identify which mechanisms are mainly responsible for impurity production. (author) 5 refs., 2 figs., 1 tab

  10. Analysis of Leaky Modes in Photonic Crystal Fibers Using the Surface Integral Equation Method

    Directory of Open Access Journals (Sweden)

    Jung-Sheng Chiang

    2018-04-01

    Full Text Available A fully vectorial algorithm based on the surface integral equation method for the modelling of leaky modes in photonic crystal fibers (PCFs by solely solving the complex propagation constants of characteristic equations is presented. It can be used for calculations of the complex effective index and confinement losses of photonic crystal fibers. As complex root examination is the key technique in the solution, the new algorithm which possesses this technique can be used to solve the leaky modes of photonic crystal fibers. The leaky modes of solid-core PCFs with a hexagonal lattice of circular air-holes are reported and discussed. The simulation results indicate how the confinement loss by the imaginary part of the effective index changes with air-hole size, the number of rings of air-holes, and wavelength. Confinement loss reductions can be realized by increasing the air-hole size and the number of air-holes. The results show that the confinement loss rises with wavelength, implying that the light leaks more easily for longer wavelengths; meanwhile, the losses are decreased significantly as the air-hole size d/Λ is increased.

  11. Density-functional calculations of the surface tension of liquid Al and Na

    Science.gov (United States)

    Stroud, D.; Grimson, M. J.

    1984-01-01

    Calculations of the surface tensions of liquid Al and Na are described using the full ionic density functional formalism of Wood and Stroud (1983). Surface tensions are in good agreement with experiment in both cases, with results substantially better for Al than those found previously in the gradient approximation. Preliminary minimization with respect to surface profile leads to an oscillatory profile superimposed on a nearly steplike ionic density disribution; the oscillations have a wavellength of about a hardsphere diameter.

  12. Liquid-infiltrated photonic crystals: Ohmic dissipation and broadening of modes

    DEFF Research Database (Denmark)

    Mortensen, Niels Asger; Ejsing, Louise Wellendorph; Xiao, Sanshui

    2006-01-01

    The pronounced light-matter interactions in photonic crystals make them interesting as opto-fludic "building blocks" for lab-on-a-chip applications. We show how conducting electrolytes cause dissipation and smearing of the density-of-states, thus altering decay dynamics of excited bio......-molecules dissolved in the electrolyte. Likewise, we find spatial damping of propagating modes, of the order dB/cm, for naturally occurring electrolytes such as drinking water or physiological salt water....

  13. Quantized layer growth at liquid-crystal surfaces

    DEFF Research Database (Denmark)

    Ocko, B. M.; Braslau, A.; Pershan, P. S.

    1986-01-01

    of the specular reflectivity is consistent with a sinusoidal density modulation, starting at the surface and terminating abruptly, after an integral number of bilayers. As the transition is approached the number of layers increases in quantized steps from zero to five before the bulk undergoes a first...

  14. Surface-Enhanced Raman Scattering Using Silica Whispering-Gallery Mode Resonators

    Science.gov (United States)

    Anderson, Mark S.

    2013-01-01

    The motivation of this work was to have robust spectroscopic sensors for sensitive detection and chemical analysis of organic and molecular compounds. The solution is to use silica sphere optical resonators to provide surface-enhanced spectroscopic signal. Whispering-gallery mode (WGM) resonators made from silica microspheres were used for surface-enhanced Raman scattering (SERS) without coupling to a plasmonic mechanism. Large Raman signal enhancement is observed by exclusively using 5.08-micron silica spheres with 785-nm laser excitation. The advantage of this non-plasmonic approach is that the active substrate is chemically inert silica, thermally stable, and relatively simple to fabricate. The Raman signal enhancement is broadly applicable to a wide range of molecular functional groups including aliphatic hydrocarbons, siloxanes, and esters. Applications include trace organic analysis, particularly for in situ planetary instruments that require robust sensors with consistent response.

  15. Apparent Contact Angle and Contact Angle Hysteresis on Liquid Infused Surfaces

    OpenAIRE

    Semprebon, Ciro; McHale, Glen; Kusumaatmaja, Halim

    2016-01-01

    We theoretically investigate the apparent contact angle and contact angle hysteresis of a droplet placed on a liquid infused surface. We show that the apparent contact angle is not uniquely defined by material parameters, but also has a strong dependence on the relative size between the droplet and its surrounding wetting ridge formed by the infusing liquid. We derive a closed form expression for the contact angle in the limit of vanishing wetting ridge, and compute the correction for small b...

  16. Progress in linear optics, non-linear optics and surface alignment of liquid crystals

    Science.gov (United States)

    Ong, H. L.; Meyer, R. B.; Hurd, A. J.; Karn, A. J.; Arakelian, S. M.; Shen, Y. R.; Sanda, P. N.; Dove, D. B.; Jansen, S. A.; Hoffmann, R.

    We first discuss the progress in linear optics, in particular, the formulation and application of geometrical-optics approximation and its generalization. We then discuss the progress in non-linear optics, in particular, the enhancement of a first-order Freedericksz transition and intrinsic optical bistability in homeotropic and parallel oriented nematic liquid crystal cells. Finally, we discuss the liquid crystal alignment and surface effects on field-induced Freedericksz transition.

  17. Frequency shifts of resonant modes of the Sun due to near-surface convective scattering

    Science.gov (United States)

    Bhattacharya, J.; Hanasoge, S. M.; Antia, H. M.

    Measurements of oscillation frequencies of the Sun and stars can provide important independent constraints on their internal structure and dynamics. Seismic models of these oscillations are used to connect structure and rotation of the star to its resonant frequencies, which are then compared with observations, the goal being that of minimizing the difference between the two. Even in the case of the Sun, for which structure models are highly tuned, observed frequencies show systematic deviations from modeled frequencies, a phenomenon referred to as the ``surface term.'' The dominant source of this systematic effect is thought to be vigorous near-surface convection, which is not well accounted for in both stellar modeling and mode-oscillation physics. Here we bring to bear the method of homogenization, applicable in the asymptotic limit of large wavelengths (in comparison to the correlation scale of convection), to characterize the effect of small-scale surface convection on resonant-mode frequencies in the Sun. We show that the full oscillation equations, in the presence of temporally stationary 3D flows, can be reduced to an effective ``quiet-Sun'' wave equation with altered sound speed, Brünt-Väisäla frequency, and Lamb frequency. We derive the modified equation and relations for the appropriate averaging of 3D flows and thermal quantities to obtain the properties of this effective medium. Using flows obtained from 3D numerical simulations of near-surface convection, we quantify their effect on solar oscillation frequencies and find that they are shifted systematically and substantially. We argue therefore that consistent interpretations of resonant frequencies must include modifications to the wave equation that effectively capture the impact of vigorous hydrodynamic convection.

  18. FREQUENCY SHIFTS OF RESONANT MODES OF THE SUN DUE TO NEAR-SURFACE CONVECTIVE SCATTERING

    International Nuclear Information System (INIS)

    Bhattacharya, J.; Hanasoge, S.; Antia, H. M.

    2015-01-01

    Measurements of oscillation frequencies of the Sun and stars can provide important independent constraints on their internal structure and dynamics. Seismic models of these oscillations are used to connect structure and rotation of the star to its resonant frequencies, which are then compared with observations, the goal being that of minimizing the difference between the two. Even in the case of the Sun, for which structure models are highly tuned, observed frequencies show systematic deviations from modeled frequencies, a phenomenon referred to as the “surface term.” The dominant source of this systematic effect is thought to be vigorous near-surface convection, which is not well accounted for in both stellar modeling and mode-oscillation physics. Here we bring to bear the method of homogenization, applicable in the asymptotic limit of large wavelengths (in comparison to the correlation scale of convection), to characterize the effect of small-scale surface convection on resonant-mode frequencies in the Sun. We show that the full oscillation equations, in the presence of temporally stationary three-dimensional (3D) flows, can be reduced to an effective “quiet-Sun” wave equation with altered sound speed, Brünt–Väisäla frequency, and Lamb frequency. We derive the modified equation and relations for the appropriate averaging of 3D flows and thermal quantities to obtain the properties of this effective medium. Using flows obtained from 3D numerical simulations of near-surface convection, we quantify their effect on solar oscillation frequencies and find that they are shifted systematically and substantially. We argue therefore that consistent interpretations of resonant frequencies must include modifications to the wave equation that effectively capture the impact of vigorous hydrodynamic convection

  19. Ultraviolet curing of acrylated liquid natural rubber for surface coating application

    Directory of Open Access Journals (Sweden)

    Kannikar Kwanming

    2009-01-01

    Full Text Available Ultraviolet curable acrylated liquid natural rubber was prepared by grafting of photosensitive molecule onto liquid natural rubber for surface coating application. The liquid natural rubber (LNR was firstly obtained by degradation of natural rubber latex with hydrogen peroxide and cobalt acetylacetonate at 65oC for 72 hrs. The preparation of acrylated natural rubber was carried out by the reaction of acrylic acid and epoxidized liquid natural rubber (ELNR prior obtained from LNR with formic acid and hydrogen peroxide in the ratio of 2:1 by weight in toluene at 80oC for 6, 9, 12, 18, and 24 hrs. It was found that the percentage of acrylate grafted onto liquid natural rubber depended on the reaction time. Surface coating was performed by using acrylated liquid natural rubber and 1,6-hexanediol diacrylate (HDDA or tripropylene glycol diacrylate (TPGDA as a crosslinker and Irgarcure 184 or Irgarcure 651 as a photoinitiator under UV exposure for 30, 60, and 90 seconds. The hardness test of cured products was investigated using the Pencil hardness test at pencil level of 2B to 6H. It was found that the highest hardness of surface coating was at pencil level of 4H for the product using TPGDA and Irgacure 651 in the ratio of 80:10 parts per hundred of rubber (phr. The cured products were able to resist to 2% H2SO4 and distilled water for more than 24 hrs.

  20. Dipolar interaction induced band gaps and flat modes in surface-modulated magnonic crystals

    Science.gov (United States)

    Gallardo, R. A.; Schneider, T.; Roldán-Molina, A.; Langer, M.; Fassbender, J.; Lenz, K.; Lindner, J.; Landeros, P.

    2018-04-01

    Theoretical results for the magnetization dynamics of a magnonic crystal formed by grooves on the surface of a ferromagnetic film, called a surface-modulated magnonic crystal, are presented. For such a system, the role of the periodic dipolar field induced by the geometrical modulation is addressed by using the plane-wave method. The results reveal that, under the increasing of the depth of the grooves, zones with magnetizing and demagnetizing fields act on the system in such a way that magnonic band gaps are observed in both Damon-Eshbach and backward volume geometries. Particularly, in the backward volume configuration, high-frequency band gaps and low-frequency flat modes are obtained. By taking into account the properties of the internal field induced by the grooves, the flattening of the modes and their shift towards low frequencies are discussed and explained. To test the validity of the model, the theoretical results of this work are confirmed by micromagnetic simulations, and good agreement between both methods is achieved. The theoretical model allows for a detailed understanding of the physics underlying these kinds of systems, thereby providing an outlook for potential applications on magnonic devices.

  1. Quantification of deexcitation processes for analyzing liquid surfaces

    International Nuclear Information System (INIS)

    Morgner, H.

    2014-01-01

    In the last two decades the mathematical tools for quantitative data evaluation have been developed for several surface spectroscopic techniques like Angular Resolved X-ray Photoelectron Spectroscopy (ARXPS), Neutral Impact Collision Ion Scattering Spectroscopy (NICISS) and Metastable Induced Electron Spectroscopy (MIES). Provided that the experimental data are of good quality, quantitative data processing can add a lot to the information that can be gained from surface spectroscopy. We give a selection of references that contain information on these methods. The emphasis of this contribution aims at providing motivation to apply quantitative data evaluation by presenting a few examples. We try to demonstrate, that careful data evaluation may lead to interesting insight into basic concepts as well as to results that are useful for practical applications

  2. Quantification of deexcitation processes for analyzing liquid surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Morgner, H., E-mail: hmorgner@rz.uni-leipzig.de

    2014-12-01

    In the last two decades the mathematical tools for quantitative data evaluation have been developed for several surface spectroscopic techniques like Angular Resolved X-ray Photoelectron Spectroscopy (ARXPS), Neutral Impact Collision Ion Scattering Spectroscopy (NICISS) and Metastable Induced Electron Spectroscopy (MIES). Provided that the experimental data are of good quality, quantitative data processing can add a lot to the information that can be gained from surface spectroscopy. We give a selection of references that contain information on these methods. The emphasis of this contribution aims at providing motivation to apply quantitative data evaluation by presenting a few examples. We try to demonstrate, that careful data evaluation may lead to interesting insight into basic concepts as well as to results that are useful for practical applications.

  3. Model of a liquid droplet impinging on a high-temperature solid surface

    International Nuclear Information System (INIS)

    Gulikov, A.V.; Berlin, I.I.; Karpyshev, A.V.

    2004-01-01

    The model of the collision of the liquid droplet, vertically falling on the heated solid surface, is presented. The wall temperature is predeterminated so that the droplet interaction with the wall proceeds through the gas interlayer (T≥400 Deg C). The droplet liquid is incompressible, nonviscous. The droplet surface is assigned as free one. The pressure is composed of two components. The first component is the surface tension. The record component is the steam pressure between the droplet and the wall. The liquid motion inside the droplet is assumed to be potential, axisymmetric. The calculation of the droplet collision are carried out with application of the above model. The obtained results are compared with the data of other authors [ru

  4. Solutal Marangoni flows of miscible liquids drive transport without surface contamination

    Science.gov (United States)

    Kim, Hyoungsoo; Muller, Koen; Shardt, Orest; Afkhami, Shahriar; Stone, Howard A.

    2017-11-01

    Mixing and spreading of different liquids are omnipresent in nature, life and technology, such as oil pollution on the sea, estuaries, food processing, cosmetic and beverage industries, lab-on-a-chip devices, and polymer processing. However, the mixing and spreading mechanisms for miscible liquids remain poorly characterized. Here, we show that a fully soluble liquid drop deposited on a liquid surface remains as a static lens without immediately spreading and mixing, and simultaneously a Marangoni-driven convective flow is generated, which are counterintuitive results when two liquids have different surface tensions. To understand the dynamics, we develop a theoretical model to predict the finite spreading time and length scales, the Marangoni-driven convection flow speed, and the finite timescale to establish the quasi-steady state for the Marangoni flow. The fundamental understanding of this solutal Marangoni flow may enable driving bulk flows and constructing an effective drug delivery and surface cleaning approach without causing surface contamination by immiscible chemical species.

  5. Inorganic Surface Coating with Fast Wetting-Dewetting Transitions for Liquid Manipulations.

    Science.gov (United States)

    Yang, Yajie; Zhang, Liaoliao; Wang, Jue; Wang, Xinwei; Duan, Libing; Wang, Nan; Xiao, Fajun; Xie, Yanbo; Zhao, Jianlin

    2018-06-06

    Liquid manipulation is a fundamental issue for microfluidics and miniaturized sensors. Fast wetting-state transitions by optical methods have proven being efficient for liquid manipulations by organic surface coatings, however rarely been achieved by using inorganic coatings. Here, we report a fast optical-induced wetting-state transition surface achieved by inorganic coating, enabling tens of second transitions for a wetting-dewetting cycle, shortened from an hour, as typically reported. Here, we demonstrate a gravity-driven microfluidic reactor and switch it to a mixer after a second-step exposure in a minimum of within 80 s of UV exposure. The fast wetting-dewetting transition surfaces enable the fast switchable or erasable smart surfaces for water collection, miniature chemical reaction, or sensing systems by using inorganic surface coatings.

  6. Thermodynamic and surface properties of liquid Co–Cr–Ni alloys

    International Nuclear Information System (INIS)

    Costa, C.; Delsante, S.; Borzone, G.; Zivkovic, D.; Novakovic, R.

    2014-01-01

    Highlights: • The liquid phases of Co–Cr, Co–Ni and Cr–Ni were modelled by the Quasi Chemical Approximation for regular solutions. • The excess Gibbs free energy of mixing of the liquid Co–Cr–Ni phase is estimated by the three thermodynamic models. • Prediction of structure can compensate the lack of structural data of Co–Cr, Co–Ni and Cr–Ni melts. • Thermodynamic modelling of the surface properties of Co–Cr–Ni melts. • Weak effects of short range ordering among nearest neighbours in Co–Cr, Co–Ni and Cr–Ni liquid alloys can be deduced. -- Abstract: Direct measurements of bulk and surface properties of liquid alloys at elevated temperatures are often technically difficult or even impossible, and therefore, theoretical models can be used to estimate missing property values. The energetics of mixing in liquid Co–Cr, Cr–Ni and Co–Ni systems has been analysed through the study of the concentration dependence of various thermodynamic, surface (surface tension and surface composition) and structural properties (concentration fluctuations in the long-wavelength limit and chemical short-range order parameter) by the first or the Quasi-Chemical Approximation (QCA) for regular solutions, developed by Bhatia and Singh, in the framework of statistical mechanical theory in conjunction with the Quasi-Lattice Theory (QLT). The results obtained for these binary systems have been extended to study the thermodynamics and surface properties of ternary Co–Cr–Ni liquid alloys

  7. Effects of self-affine surface roughness on the friction coefficient of rubbers in the presence of a liquid interlayer

    NARCIS (Netherlands)

    Palasantzas, G; De Hosson, JTM

    2004-01-01

    In this article, we investigate how the friction coefficient is affected by the presence of a liquid layer in between a self-affine rough surface and a sliding rubber surface. The liquid layer will reduce energy dissipation from the small surface asperities and cavities of lateral sizes smaller than

  8. Direct numerical simulation of turbulent channel flow over a liquid-infused micro-grooved surface

    Science.gov (United States)

    Chang, Jaehee; Jung, Taeyong; Choi, Haecheon; Kim, John

    2016-11-01

    Recently a superhydrophobic surface has drawn much attention as a passive device to achieve high drag reduction. Despite the high performance promised at ideal conditions, maintaining the interface in real flow conditions is an intractable problem. A non-wetting surface, known as the slippery liquid-infused porous surface (SLIPS) or the lubricant-impregnated surface (LIS), has shown a potential for drag reduction, as the working fluid slips at the interface but cannot penetrate into the lubricant layer. In the present study, we perform direct numerical simulation of turbulent channel flow over a liquid-infused micro-grooved surface to investigate the effects of this surface on the interfacial slip and drag reduction. The flow rate of water is maintained constant corresponding to Reτ 180 in a fully developed turbulent channel flow, and the lubricant layer is shear-driven by the turbulent water flow. The lubricant layer is also simulated with the assumption that the interface is flat (i.e. the surface tension effect is neglected). The solid substrate in which the lubricant is infused is modelled as straight ridges using an immersed boundary method. DNS results show that drag reduction by the liquid-infused surface is highly dependent on the viscosity of the lubricant.

  9. Ionic liquids influence on the surface properties of electron beam irradiated wood

    Energy Technology Data Exchange (ETDEWEB)

    Croitoru, Catalin [“Transilvania” University of Brasov, Product Design and Environment Department, 29 Eroilor Str., 500036, Brasov (Romania); Patachia, Silvia, E-mail: st.patachia@unitbv.ro [“Transilvania” University of Brasov, Product Design and Environment Department, 29 Eroilor Str., 500036, Brasov (Romania); Doroftei, Florica; Parparita, Elena; Vasile, Cornelia [“Petru Poni” Institute of Macromolecular Chemistry, Physical Chemistry of Polymers Department, 41A Gr. Ghica Voda Alley, Iasi (Romania)

    2014-09-30

    Highlights: • Wood veneers impregnated with three imidazolium-based ionic liquids and irradiated with electron beam were studied by FTIR-ATR, SEM/EDX, AFM, contact angle and image analysis. • ILs preserve the surface properties of the wood (surface energy, roughness, color) upon irradiation, in comparison with the reference wood, but the surface composition is changed by treatment with IL-s, mainly with 1-butyl-3-methylimidazolium tetrafluoroborate. • Under electron beam irradiation covalent bonding of the imidazolium moiety to wood determines a higher resistance to water penetration and spreading on the surface. - Abstract: In this paper, the influence of three imidazolium-based ionic liquids (1-butyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium hexafluorophosphate and 1-hexyl-3-methylimidazolium chloride) on the structure and surface properties of sycamore maple (Acer pseudoplatanus) veneers submitted to electron beam irradiation with a dose of 50 kGy has been studied by using Fourier transform infrared spectroscopy, as well as image, scanning electron microscopy/SEM/EDX, atomic force microscopy and contact angle analysis. The experimental results have proven that the studied ionic liquids determine a better preservation of the structural features of wood (cellulose crystallinity index and lignin concentration on the surface) as well as some of surface properties such as surface energy, roughness, color upon irradiation with electron beam, in comparison with the reference wood, but surface composition is changed by treatment with imidazolium-based ionic liquids mainly with 1-butyl-3-methylimidazolium tetrafluoroborate. Also, under electron beam irradiation covalent bonding of the imidazolium moiety to wood determines a higher resistance to water penetration and spreading on the surface.

  10. Acoustic characteristics of bubble bursting at the surface of a high-viscosity liquid

    International Nuclear Information System (INIS)

    Liu Xiao-Bo; Zhang Jian-Run; Li Pu

    2012-01-01

    An acoustic pressure model of bubble bursting is proposed. An experiment studying the acoustic characteristics of the bursting bubble at the surface of a high-viscosity liquid is reported. It is found that the sudden bursting of a bubble at the high-viscosity liquid surface generates N-shape wave at first, then it transforms into a jet wave. The fundamental frequency of the acoustic signal caused by the bursting bubble decreases linearly as the bubble size increases. The results of the investigation can be used to understand the acoustic characteristics of bubble bursting. (electromagnetism, optics, acoustics, heat transfer, classical mechanics, and fluid dynamics)

  11. High-power spallation target using a heavy liquid metal free surface flow

    International Nuclear Information System (INIS)

    Litfin, K.; Fetzer, J.R.; Batta, A.; Class, A.G.; Wetzel, Th.

    2015-01-01

    A prototype of a heavy liquid metal free surface target as proposed for the multi-purpose hybrid research reactor for high-tech applications in Mol, Belgium, has been set up and experimentally investigated at the Karlsruhe Liquid Metal Laboratory. A stable operation was demonstrated in a wide range of operating conditions and the surface shape was detected and compared with numerical pre-calculations employing Star-CD. Results show a very good agreement of experiment and numerical predictions which is an essential input for other windowless target designs like the META:LIC target for the European Spallation Source. (author)

  12. A simple laboratory experiment to measure the surface tension of a liquid in contact with air

    International Nuclear Information System (INIS)

    Riba, Jordi-Roger; Esteban, Bernat

    2014-01-01

    A simple and accurate laboratory experiment to measure the surface tension of liquids has been developed, which is well suited to teach the behaviour of liquids to first- or second-year students of physics, engineering or chemistry. The experimental setup requires relatively inexpensive equipment usually found in physics and chemistry laboratories, since it consists of a used or recycled burette, an analytical balance and a stereoscopic microscope or a micrometer. Experimental data and error analysis show that the surface tension of distilled water, 1-butanol and glycerol can be determined with accuracy better than 1.4%. (paper)

  13. Standard reference data for the air-liquid and vapor-liquid surface tension of benzene

    Czech Academy of Sciences Publication Activity Database

    Součková, Monika; Klomfar, Jaroslav; Pátek, Jaroslav

    2013-01-01

    Roč. 356, October (2013), s. 329-337 ISSN 0378-3812 R&D Projects: GA ČR GA101/09/0010 Institutional support: RVO:61388998 Keywords : benzene * surface tension * experimental data * standard reference data Subject RIV: BJ - Thermodynamics Impact factor: 2.241, year: 2013 http://www.sciencedirect.com/science/article/pii/S0378381213004196

  14. Observation of OH radicals produced by pulsed discharges on the surface of a liquid

    Energy Technology Data Exchange (ETDEWEB)

    Kanazawa, Seiji; Kawano, Hirokazu; Watanabe, Satoshi; Furuki, Takashi; Akamine, Shuichi; Ichiki, Ryuta; Ohkubo, Toshikazu [Department of Electrical and Electronic Engineering, Oita University, 700 Dannoharu, Oita 870-1192 (Japan); Kocik, Marek; Mizeraczyk, Jerzy, E-mail: skana@cc.oita-u.ac.jp [Szewalski Institute of Fluid Flow Machinery, Polish Academy of Sciences Fiszera 14, 80-952, Gdansk (Poland)

    2011-06-15

    The hydroxyl radical (OH) plays an important role in plasma chemistry at atmospheric pressure. OH radicals have a higher oxidation potential compared with other oxidative species such as free radical O, atomic oxygen, hydroperoxyl radical (HO{sub 2}), hydrogen peroxide(H{sub 2}O{sub 2}) and ozone. In this study, surface discharges on liquids (water and its solutions) were investigated experimentally. A pulsed streamer discharge was generated on the liquid surface using a point-to-plane electrode geometry. The primary generation process of OH radicals is closely related to the streamer propagation, and the subsequent secondary process after the discharge has an influence on the chemical reaction. Taking into account the timescale of these processes, we investigated the behavior of OH radicals using two different diagnostic methods. Time evolution of the ground-state OH radicals above the liquid surface after the discharge was observed by a laser-induced fluorescence (LIF) technique. In order to observe the ground-state OH, an OH [A {sup 2}{Sigma}{sup +}(v' = 1) <- X {sup 2}{Pi}(v'' = 0)] system at 282 nm was used. As the secondary process, a portion of OH radicals diffused from gas phase to the liquid surface and dissolved in the liquid. These dissolved OH radicals were measured by a chemical probe method. Terephthalic acid was used as an OH radical trap and fluorescence of the resulting 2-hydroxyterephthalic acid was measured. This paper directly presents visualization of OH radicals over the liquid surface by means of LIF, and indirectly describes OH radicals dissolved in water by means of a chemical method.

  15. Observation of OH radicals produced by pulsed discharges on the surface of a liquid

    Science.gov (United States)

    Kanazawa, Seiji; Kawano, Hirokazu; Watanabe, Satoshi; Furuki, Takashi; Akamine, Shuichi; Ichiki, Ryuta; Ohkubo, Toshikazu; Kocik, Marek; Mizeraczyk, Jerzy

    2011-06-01

    The hydroxyl radical (OH) plays an important role in plasma chemistry at atmospheric pressure. OH radicals have a higher oxidation potential compared with other oxidative species such as free radical O, atomic oxygen, hydroperoxyl radical (HO2), hydrogen peroxide(H2O2) and ozone. In this study, surface discharges on liquids (water and its solutions) were investigated experimentally. A pulsed streamer discharge was generated on the liquid surface using a point-to-plane electrode geometry. The primary generation process of OH radicals is closely related to the streamer propagation, and the subsequent secondary process after the discharge has an influence on the chemical reaction. Taking into account the timescale of these processes, we investigated the behavior of OH radicals using two different diagnostic methods. Time evolution of the ground-state OH radicals above the liquid surface after the discharge was observed by a laser-induced fluorescence (LIF) technique. In order to observe the ground-state OH, an OH [A 2∑+(v' = 1) <-- X 2Π(v'' = 0)] system at 282 nm was used. As the secondary process, a portion of OH radicals diffused from gas phase to the liquid surface and dissolved in the liquid. These dissolved OH radicals were measured by a chemical probe method. Terephthalic acid was used as an OH radical trap and fluorescence of the resulting 2-hydroxyterephthalic acid was measured. This paper directly presents visualization of OH radicals over the liquid surface by means of LIF, and indirectly describes OH radicals dissolved in water by means of a chemical method.

  16. Liquid phase surface nitriding of Ti-6Al-4V pre-placed with chromium

    Energy Technology Data Exchange (ETDEWEB)

    Vahedi Nemani, Alireza, E-mail: alireza_vahedi@ut.ac.ir; Sohi, M. Heydarzadeh; Amadeh, A.A.; Ghaffari, Mahya

    2016-08-01

    In this study, liquid phase surface nitriding of Ti-6Al-4V was carried out by pre-placing of chromium powder on the substrate and subsequent Tungsten Inert Gas (TIG) surface melting. The effect of the application of low and high heat inputs on the microstructure, microhardness and wear resistance of the treated layers were studied. Surface alloying with chromium in a nitrogen containing atmosphere resulted in the formation of hard intermetallic compounds such as TiN, Cr{sub 2}N and TiCr{sub 2}. Moreover, the presence of beta stabilizer chromium together with the application of high heat input during surface treatment resulted in the presence of beta phase at room temperature. However, applying low heat input could not prevent transformation of beta to martensite. The hardness of the layers fabricated at high and low heat inputs were respectively 1050 and 1200 HV{sub 0.3} compared to average 280 HV{sub 0.3} for the as-received material. Liquid phase surface treatment of titanium at the aforementioned conditions improved the wear resistance. The lowest weight loss belonged to the specimen with the beta phase matrix. The formation of the fairly ductile bcc-β phase hindered crack nucleation during wear. The weight loss in this condition was 7 times lower than that of the base material. - Highlights: • Liquid phase surface nitriding of Ti-6Al-4V was carried out by TIG surface melting. • Cr powder was pre-placed on the surface as the beta stabilizer alloying element. • The treated layers were characterized by OM, SEM and X-ray diffraction pattern. • Hardness of the layers increased up to 3 times higher than that of the base alloy. • Liquid phase surface alloying improved the wear resistance.

  17. Effect of liquid film on near-threshold laser ablation of a solid surface

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Dongsik; Oh, Bukuk; Lee, Ho

    2004-01-30

    Enhancement of material ablation and photoacoustic excitation by an artificially deposited liquid film in the process of pulsed-laser ablation (PLA) is investigated in this paper. Ablation threshold, ablation rate, surface topography, and acoustic-transient emission are also measured for dry and liquid film-coated surfaces. The physical mechanisms of enhanced ablation in the liquid-assisted process are analyzed at relatively low laser fluences with negligible effect of laser-produced plasma. Particularly, correlation between material ablation and acoustic-transient generation is examined. In the experiment, aluminum thin-films and bulk foils are ablated by Q-switched Nd:YAG laser pulses. The dependence of ablation rate and laser-induced topography on liquid film thickness and chemical composition is also examined. Photoacoustic emission is measured by the probe beam deflection method utilizing a CW HeNe laser and a microphone. In comparison with a dry ablation process, the liquid-assisted ablation process results in substantially augmented ablation efficiency and reduced ablation threshold. The results indicate that both increased laser-energy coupling, i.e., lowered reflectance, and amplified photoacoustic excitation in explosive vaporization of liquid are responsible for the enhanced material ablation.

  18. An analytical model for displacement velocity of liquid film on a hot vertical surface

    International Nuclear Information System (INIS)

    Yoshioka, Keisuke; Hasegawa, Shu

    1975-01-01

    The downward progress of the advancing front of a liquid film streaming down a heated vertical surface, as it would occur in emergency core cooling, is much slower than in the case of ordinary streaming down along a heated surface already wetted with the liquid. A two-dimensional heat conduction model is developed for evaluating this velocity of the liquid front, which takes account of the heat removal by ordinary flow boiling mechanism. In the analysis, the maximum heat flux and the calefaction temperature are taken up as parameters in addition to the initial dry heated wall temperature, the flow rate and the velocity of downward progress of the liquid front. The temperature profile is calculated for various combinations of these parameters. Two criteria are proposed for choosing the most suitable combination of the parameters. One is to reject solutions that represent an oscillating wall temperature distribution, and the second criterion requires that the length of the zone of violent boiling immediately following the liquid front should not be longer than about 1 mm, this value being determined from comparisons made between experiment and calculation. Application of the above two criteria resulted in reasonable values obtained for the calefaction temperature and the maximum heat flux, and the velocity of the liquid front derived therefrom showed good agreement with experiment. (auth.)

  19. Mode of production of monomolecular structuring water in liquid crystalline form

    International Nuclear Information System (INIS)

    Hasanov, A.M.

    2011-01-01

    Full text : Mode to protect living organisms from the biological effects of electromagnetic radiation of mobile phones and personal computers, including the determination of the energy absorbed by the body over time, depending on the biological factors of the body, characterized in that a biological factor using the total amount of water contained in the body, with time corresponding to the absorbed energy is equated to the maximum allowable rate, determined by the formula dt=dEBBNH/EodEeksp. Here K is the coefficient of the percentage of water in biological tissues, dEeksp. - Experimentally established energy flux density of the mobile phone or personal computer, dEBBNH ∼10mkVt/si 2 - maximum permissible rate of absorbed energy.

  20. Ultrasonic pumping of liquids in the two directions of a vertical tube by a vibrating surface

    DEFF Research Database (Denmark)

    Santillan, Arturo Orozco; Cutanda Henriquez, Vicente

    2010-01-01

    of the oscillations of the vibrating horizontal surface determine the direction in which the liquid is pumped. In addition, the size of the gap is also a relevant factor, which has to be significantly small. The carried out numerical simulations show that the Lagrangian excess pressure and the density of linear......It has been reported that it is possible to pump a liquid into the interior of a vertical pipe when its lower end is facing a vibrating plane surface immersed in the liquid. The column of liquid pumped in a thin pipe can be higher than 2 m if the gap between the pipe end and the vibrating...... horizontal surface is very small, around 0.01 mm. In this paper we present experimental results showing that, with a similar set up as the one mentioned above, it is also possible to pump liquids in the opposite direction, from the interior of the pipe through the gap. The general objective of the work has...

  1. Galvanic Liquid Applied Coating System for Protection of Embedded Steel Surfaces from Corrosion

    Science.gov (United States)

    Curran, Joseph; MacDowell, Louis; Voska, N. (Technical Monitor)

    2002-01-01

    The corrosion of reinforcing steel in concrete is an insidious problem for the Kennedy Space Center, government agencies, and the general public. Existing corrosion protection systems on the market are costly, complex, and time-consuming to install, require continuous maintenance and monitoring, and require specialized skills for installation. NASA's galvanic liquid-applied coating offers companies the ability to conveniently protect embedded steel rebar surfaces from corrosion. Liquid-applied inorganic galvanic coating contains one ore more of the following metallic particles: magnesium, zinc, or indium and may contain moisture attracting compounds that facilitate the protection process. The coating is applied to the outer surface of reinforced concrete so that electrical current is established between metallic particles and surfaces of embedded steel rebar; and electric (ionic) current is responsible for providing the necessary cathodic protection for embedded rebar surfaces.

  2. Molar Surface Gibbs Energy of the Aqueous Solution of Ionic Liquid [C4mim][Oac

    Institute of Scientific and Technical Information of China (English)

    TONG Jing; ZHENG Xu; TONG Jian; QU Ye; LIU Lu; LI Hui

    2017-01-01

    The values of density and surface tension for aqueous solution of ionic liquid(IL) 1-butyl-3-methylimidazolium acetate([C4mim][OAc]) with various molalities were measured in the range of 288.15-318.15 K at intervals of 5 K.On the basis of thermodynamics,a semi-empirical model-molar surface Gibbs energy model of the ionic liquid solution that could be used to predict the surface tension or molar volume of solutions was put forward.The predicted values of the surface tension for aqueous [C4im][OAc] and the corresponding experimental ones were highly correlated and extremely similar.In terms of the concept of the molar Gibbs energy,a new E(o)tv(o)s equation was obtained and each parameter of the new equation has a clear physical meaning.

  3. One - step nanosecond laser microstructuring, sulfur hyperdoping, and annealing of silicon surfaces in liquid carbondisulfide

    Science.gov (United States)

    Van Luong, Nguyen; Danilov, P. A.; Ionin, A. A.; Khmel'nitskii, P. A.; Kudryashov, S. I.; Mel'nik, N. N.; Saraeva, I. N.; Смirnov, H. A.; Rudenko, A. A.; Zayarny, D. A.

    2017-09-01

    We perform a single-shot IR nanosecond laser processing of commercial silicon wafers in ambient air and under a 2 mm thick carbon disulfide liquid layer. We characterize the surface spots modified in the liquid ambient and the spots ablated under the same conditions in air in terms of its surface topography, chemical composition, band-structure modification, and crystalline structure by means of SEM and EDX microscopy, as well as of FT-IR and Raman spectroscopy. These studies indicate that single-step microstructuring and deep (up to 2-3% on the surface) hyperdoping of the crystalline silicon in its submicron surface layer, preserving via pulsed laser annealing its crystallinity and providing high (103 - 104 cm-1) spectrally at near- and mid-IR absorption coefficients, can be obtained in this novel approach, which is very promising for thin - film silicon photovoltaic devices

  4. Surface plasmon-enhanced two-photon excited whispering-gallery modes ultraviolet laser from Zno microwire

    Directory of Open Access Journals (Sweden)

    Yunpeng Wang

    2017-11-01

    Full Text Available The two-photon excited UV laser with narrow line width and high Q value was obtained. The total internal reflection from the four side surfaces of the quadrilateral-ZnO microwire offered the whispering gallery mode (WGM resonant cavity. The UV emission, resonant mechanism, and laser mode characteristics were discussed in detail for this special type of micro-cavity. In addition, in order to enhance the power of the two-photon excited UV laser, the surface plasmon enhancement by the Au nanoparticles was also performed and explained well by the theory of the localized surface plasmon.

  5. Ice dynamic response to two modes of surface lake drainage on the Greenland ice sheet

    International Nuclear Information System (INIS)

    Tedesco, Marco; Alexander, Patrick; Willis, Ian C; Banwell, Alison F; Arnold, Neil S; Hoffman, Matthew J

    2013-01-01

    Supraglacial lake drainage on the Greenland ice sheet opens surface-to-bed connections, reduces basal friction, and temporarily increases ice flow velocities by up to an order of magnitude. Existing field-based observations of lake drainages and their impact on ice dynamics are limited, and focus on one specific draining mechanism. Here, we report and analyse global positioning system measurements of ice velocity and elevation made at five locations surrounding two lakes that drained by different mechanisms and produced different dynamic responses. For the lake that drained slowly (>24 h) by overtopping its basin, delivering water via a channel to a pre-existing moulin, speedup and uplift were less than half those associated with a lake that drained rapidly (∼2 h) through hydrofracturing and the creation of new moulins in the lake bottom. Our results suggest that the mode and associated rate of lake drainage govern the impact on ice dynamics. (letter)

  6. Anharmonic vibrational modes of chemisorbed H on the Rh(001) surface

    International Nuclear Information System (INIS)

    Hamann, D.R.; Feibelman, P.J.

    1988-01-01

    The potential for H atoms in the vicinity of the fourfold hollow chemisorption site on the Rh(001) surface at monolayer coverage is calculated using local-density-functional theory, and the linear-augmented-plane-wave method. The potential is found to contain important anharmonic components, one that couples parallel and perpendicular motion, and another producing azimuthal anisotropy. Variational solutions are found for the ground and low-lying excited states of H and D in this potential. The fundamental asymmetric- and symmetric-stretch H vibrational excitations are found to have energies of 67 and 92 meV. The latter agrees with recent experimental results, and higher-lying experimental modes are interpreted as mixed excitations. Comparisons are made with spring-constant models, calculated potentials for H on Ni and Pd(001), and theories of Bloch states for H on Ni

  7. Single-Step Fabrication of High-Density Microdroplet Arrays of Low-Surface-Tension Liquids.

    Science.gov (United States)

    Feng, Wenqian; Li, Linxian; Du, Xin; Welle, Alexander; Levkin, Pavel A

    2016-04-01

    A facile approach for surface patterning that enables single-step fabrication of high-density arrays of low-surface-tension organic-liquid microdroplets is described. This approach enables miniaturized and parallel high-throughput screenings in organic solvents, formation of homogeneous arrays of hydrophobic nanoparticles, polymer micropads of specific shapes, and polymer microlens arrays. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Surface properties and wetting behavior of liquid Ag-Sb-Sn alloys

    Directory of Open Access Journals (Sweden)

    Sklyarchuk V.

    2012-01-01

    Full Text Available Surface tension and density measurements of liquid Ag-Sb-Sn alloys were carried out over a wide temperature range by using the sessile drop method. The surface tension experimental data were analyzed by the Butler thermodynamic model in the regular solution approximation. The wetting characteristics of these alloys on Cu and Ni substrates have been also determined. The new experimental results were compared with the calculated values as well as with data available in the literature.

  9. Binding modes and functional surface of anti-mammalian scorpion α-toxins to sodium channels.

    Science.gov (United States)

    Chen, Rong; Chung, Shin-Ho

    2012-10-02

    Scorpion α-toxins bind to the voltage-sensing domains of voltage-gated sodium (Na(V)) channels and interfere with the inactivation mechanisms. The functional surface of α-toxins has been shown to contain an NC-domain consisting of the five-residue turn (positions 8-12) and the C-terminus (positions 56-64) and a core-domain centered on the residue 18. The NC- and core-domains are interconnected by the linker-domain (positions 8-18). Here with atomistic molecular dynamics simulations, we examine the binding modes between two α-toxins, the anti-mammalian AahII and the anti-insect LqhαIT, and the voltage-sensing domain of rat Na(V)1.2, a subtype of Na(V) channels expressed in nerve cells. Both toxins are docked to the extracellular side of the voltage-sensing domain of Na(V)1.2 using molecular dynamics simulations, with the linker-domain assumed to wedge into the binding pocket. Several salt bridges and hydrophobic clusters are observed to form between the NC- and core-domains of the toxins and Na(V)1.2 and stabilize the toxin-channel complexes. The binding modes predicted are consistent with available mutagenesis data and can readily explain the relative affinities of AahII and LqhαIT for Na(V)1.2. The dissociation constants for the two toxin-channel complexes are derived, which compare favorably with experiment. Our models demonstrate that the functional surface of anti-mammalian scorpion α-toxins is centered on the linker-domain, similar to that of β-toxins.

  10. Synthesis of monodisperse silica microspheres and modification with diazoresin for mixed-mode ultra high performance liquid chromatography separations.

    Science.gov (United States)

    Cong, Hailin; Yu, Bing; Tian, Chao; Zhang, Shuai; Yuan, Hua

    2017-11-01

    Monodisperse silica particles with average diameters of 1.9-2.9 μm were synthesized by a modified Stöber method, in which tetraethyl orthosilicate was continuously supplied to the reaction mixture containing KCl electrolyte, water, ethanol, and ammonia. The obtained silica particles were modified by self-assembly with positively charged photosensitive diazoresin on the surface. After treatment with ultraviolet light, the ionic bonding between silica and diazoresin was converted into covalent bonding through a unique photochemistry reaction of diazoresin. Depending on the chemical structure of diazoresin and mobile phase composition, the diazoresin-modified silica stationary phase showed different separation mechanisms, including reversed phase and hydrophilic interactions. Therefore, a variety of baseline separation of benzene analogues and organic acids was achieved by using the diazoresin-modified silica particles as packing materials in ultra high performance liquid chromatography. According to the π-π interactional difference between carbon rings of fullerenes and benzene rings of diazoresin, C 60 and C 70 were also well separated by ultra-high performance liquid chromatography. Because it has a small size, the ∼2.5 μm monodisperse diazoresin-modified silica stationary phase shows ultra-high efficiency compared with the commercial C 18 -silica high-performance liquid chromatography stationary phase with average diameters of ∼5 μm. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Sensory and Postural Input in the Occurrence of a Gender Difference in Orienting Liquid Surfaces

    Science.gov (United States)

    Robert, Michele; Longpre, Sophie

    2005-01-01

    In the water-level task, both spatial skill and physical knowledge contribute to representing the surface of a liquid as horizontal irrespective of the container's tilt. Under the standard visual format of the task, men systematically surpass women at drawing correct water lines in outlines of tilted containers. The present exploratory experiments…

  12. Density, viscosity and surface tension of liquid phase Beckmann rearrangement mixtures

    NARCIS (Netherlands)

    Zuidhof, K.T.; Croon, de M.H.J.M.; Schouten, J.C.; Tinge, J.T.

    2015-01-01

    We have determined the density, dynamic viscosity, and surface tension of liquid phase Beckmann rearrangement mixtures, consisting of e-caprolactam and fuming oleum. These important properties have been measured in wide ranges of both temperature and molar ratios of acid and e-caprolactam, covering

  13. Thermocapillary migration of liquids on patterned surfaces : design concept for microfluidic

    NARCIS (Netherlands)

    Darhuber, A.A.; Davis, J.M.; Reisner, W.W.; Troian, S.M.

    2001-01-01

    We present a novel method of fluidic transport on the open surface of a chemically patterned substrate using thermocapillary actuation. Our experimental and numerical studies provide the desired correlations between the microstream flow rate and tunable parameters like the liquid sample volume,

  14. Perfect Composition Depth Profiling of Ionic Liquid Surfaces Using High-Resolution RBS/ERDA.

    Czech Academy of Sciences Publication Activity Database

    Nakajima, K.; Zolboo, E.; Ohashi, T.; Lísal, Martin; Kimura, K.

    2016-01-01

    Roč. 32, č. 10 (2016), s. 1089-1094 ISSN 0910-6340 R&D Projects: GA ČR(CZ) GA16-12291S Institutional support: RVO:67985858 Keywords : surface structure * ionic liquid * hydrogen Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.228, year: 2016

  15. Method for controlling a coolant liquid surface of cooling system instruments in an atomic power plant

    International Nuclear Information System (INIS)

    Monta, Kazuo.

    1974-01-01

    Object: To prevent coolant inventory within a cooling system loop in an atomic power plant from being varied depending on loads thereby relieving restriction of varied speed of coolant flow rate to lowering of a liquid surface due to short in coolant. Structure: Instruments such as a superheater, an evaporator, and the like, which constitute a cooling system loop in an atomic power plant, have a plurality of free liquid surface of coolant. Portions whose liquid surface is controlled and portions whose liquid surface is varied are adjusted in cross-sectional area so that the sum total of variation in coolant inventory in an instrument such as a superheater provided with an annulus portion in the center thereof and an inner cylindrical portion and a down-comer in the side thereof comes equal to that of variation in coolant inventory in an instrument such as an evaporator similar to the superheater. which is provided with an overflow pipe in its inner cylindrical portion or down-comer, thereby minimizing variation in coolant inventory of the entire coolant due to loads thus minimizing variation in varied speed of the coolant. (Kamimura, M.)

  16. Experiment and model for the surface tension of amine–ionic liquids aqueous solutions

    International Nuclear Information System (INIS)

    Zhang, Pan; Du, LeiXia; Fu, Dong

    2014-01-01

    Highlights: • The surface tensions of MEA/DEA–ionic liquids aqueous solutions were measured. • The experiments were modeled satisfactorily by using a thermodynamic equation. • The temperature dependence of the surface tension was illustrated. • The effects of the mass fractions of MEA/DEA and ionic liquids were demonstrated. - Abstract: The surface tension (γ) of 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim][BF 4 ])–monoethanolamine (MEA), 1-butyl-3-methylimidazolium bromide ([Bmim][Br])–MEA, [Bmim][BF 4 ]–diethanolamine (DEA) and [Bmim][Br]–DEA aqueous solutions was measured by using the BZY-1 surface tension meter. The temperature ranged from (293.2 to 323.2) K. The mass fraction of amines and ionic liquids (ILS) respectively ranged from 0.15 to 0.30 and 0.05 to 0.10. A thermodynamic equation was proposed to model the surface tension of amines–ILS aqueous solutions and the calculated results agreed well with the experiments. The effects of temperature, mass fraction of amines and ILS on the surface tension were demonstrated on the basis of experiments and calculations

  17. Surface Quality Improvement of AA6060 Aluminum Extruded Components through Liquid Nitrogen Mold Cooling

    Directory of Open Access Journals (Sweden)

    Andrea Francesco Ciuffini

    2018-06-01

    Full Text Available 6xxx aluminum alloys are suitable for the realization of both structural applications and architectural decorative elements, thanks to the combination of high corrosion resistance and good surface finish. In areas where the aesthetic aspects are fundamental, further improvements in surface quality are significant. The cooling of the extrusion mold via internal liquid nitrogen fluxes is emerging as an important innovation in aluminum extrusion. Nowadays, this innovation is providing a large-scale solution to obtain high quality surface finishes in extruded aluminum semi-finished products. These results are also coupled to a significant increase in productivity. The aim of the work is to compare the surface quality of both cooled liquid nitrogen molds and classically extruded products. In this work, adhesion phenomena, occurring during the extrusion between the mold and the flowing material, have been detected as the main causes of the presence of surface defects. The analysis also highlighted a strong increase in the surface quality whenever the extrusion mold was cooled with liquid nitrogen fluxes. This improvement has further been confirmed by an analysis performed on the finished products, after painting and chromium plating. This work on the AA6060 alloy has moreover proceeded to roughness measurements and metallographic analyses, to investigate the eventual occurrence of other possible benefits stemming from this new extrusion mold cooling technology.

  18. Experimental and numerical investigation of liquid jet impingement on superhydrophobic and hydrophobic convex surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Kibar, Ali, E-mail: alikibar@kocaeli.edu.tr [Department of Mechanical and Material Technologies, Kocaeli University, Arslanbey Campus, 41285, Kocaeli (Turkey)

    2017-02-15

    Experiments and numerical simulations were carried out to examine the vertical impingement a round liquid jet on the edges of horizontal convex surfaces that were either superhydrophobic or hydrophobic. The experiments examine the effects on the flow behaviour of curvature, wettability, inertia of the jet, and the impingement rate. Three copper pipes with outer diameters of 15, 22, and 35 mm were investigated. The pipes were wrapped with a piece of a Brassica oleracea leaf or a smooth Teflon sheet, which have apparent contact angles of 160° and 113°. The Reynolds number ranged from 1000 to 4500, and the impingement rates of the liquid jets were varied. Numerical results show good agreement with the experimental results for explaining flow and provide detailed information about the impingement on the surfaces. The liquid jet reflected off the superhydrophobic surfaces for all conditions. However, the jet reflected or deflected off the hydrophobic surface, depending on the inertia of the jet, the curvature of the surface, and the impingement rate. The results suggest that pressure is not the main reason for the bending of the jet around the curved hydrophobic surface. (paper)

  19. Experimental and numerical investigation of liquid jet impingement on superhydrophobic and hydrophobic convex surfaces

    International Nuclear Information System (INIS)

    Kibar, Ali

    2017-01-01

    Experiments and numerical simulations were carried out to examine the vertical impingement a round liquid jet on the edges of horizontal convex surfaces that were either superhydrophobic or hydrophobic. The experiments examine the effects on the flow behaviour of curvature, wettability, inertia of the jet, and the impingement rate. Three copper pipes with outer diameters of 15, 22, and 35 mm were investigated. The pipes were wrapped with a piece of a Brassica oleracea leaf or a smooth Teflon sheet, which have apparent contact angles of 160° and 113°. The Reynolds number ranged from 1000 to 4500, and the impingement rates of the liquid jets were varied. Numerical results show good agreement with the experimental results for explaining flow and provide detailed information about the impingement on the surfaces. The liquid jet reflected off the superhydrophobic surfaces for all conditions. However, the jet reflected or deflected off the hydrophobic surface, depending on the inertia of the jet, the curvature of the surface, and the impingement rate. The results suggest that pressure is not the main reason for the bending of the jet around the curved hydrophobic surface. (paper)

  20. Electron mobility on the surface of liquid Helium: influence of surface level atoms and depopulation of lowest subbands

    International Nuclear Information System (INIS)

    Grigoriev, P. D.; Dyugaev, A. M.; Lebedeva, E. V.

    2008-01-01

    The temperature dependence of electron mobility is examined. We calculate the contribution to the electron scattering rate from the surface level atoms (SLAs), proposed in [10]. This contribution is substantial at low temperatures T < 0.5, when the He vapor concentration is exponentially small. We also study the effect of depopulation of the lowest energy subband, which leads to an increase in the electron mobility at high temperature. The results explain certain long-standing discrepancies between the existing theory and experiment on electron mobility on the surface of liquid helium

  1. Modeling guided wave excitation in plates with surface mounted piezoelectric elements: coupled physics and normal mode expansion

    Science.gov (United States)

    Ren, Baiyang; Lissenden, Cliff J.

    2018-04-01

    Guided waves have been extensively studied and widely used for structural health monitoring because of their large volumetric coverage and good sensitivity to defects. Effectively and preferentially exciting a desired wave mode having good sensitivity to a certain defect is of great practical importance. Piezoelectric discs and plates are the most common types of surface-mounted transducers for guided wave excitation and reception. Their geometry strongly influences the proportioning between excited modes as well as the total power of the excited modes. It is highly desirable to predominantly excite the selected mode while the total transduction power is maximized. In this work, a fully coupled multi-physics finite element analysis, which incorporates the driving circuit, the piezoelectric element and the wave guide, is combined with the normal mode expansion method to study both the mode tuning and total wave power. The excitation of circular crested waves in an aluminum plate with circular piezoelectric discs is numerically studied for different disc and adhesive thicknesses. Additionally, the excitation of plane waves in an aluminum plate, using a stripe piezoelectric element is studied both numerically and experimentally. It is difficult to achieve predominant single mode excitation as well as maximum power transmission simultaneously, especially for higher order modes. However, guidelines for designing the geometry of piezoelectric elements for optimal mode excitation are recommended.

  2. Evaporation of a Volatile Liquid Lens on the Surface of an Immiscible Liquid.

    Science.gov (United States)

    Sun, Wei; Yang, Fuqian

    2016-06-21

    The evaporation behavior of toluene and hexane lenses on the surface of deionized (DI) water is studied. The toluene and hexane lenses during evaporation experience an advancing stage and a receding stage. There exists a significant difference of the evaporation behavior between the toluene lenses and the hexane lenses. The lifetime and largest diameter of both the toluene and hexane lenses increase with increasing the initial volume of the lenses. For the evaporation of the toluene lenses, the lifetime and largest diameter of the lenses decrease with increasing the temperature of DI water. The effect of the residual of the oil molecules on the evaporation of toluene lenses at a temperature of 21 °C is investigated via the evaporation of a series of consecutive toluene lenses being placed on the same position of the surface of DI water. The temporal evolution of the toluene lenses placed after the first toluene lens deviates significantly from that of the first toluene lens. Significant increase of the receding speed occurs at the dimensionless time in a range 0.7-0.8.

  3. Liquid lithium surface control and its effect on plasma performance in the HT-7 tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Zuo, G.Z.; Ren, J. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); Hu, J.S., E-mail: hujs@ipp.ac.cn [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); Sun, Z.; Yang, Q.X.; Li, J.G. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); Zakharov, L.E. [Princeton University Plasma Physics Laboratory Princeton, NJ 08543 (United States); Ruzic, David N. [University of Illinois, Urbana, IL 61801 (United States)

    2014-12-15

    Highlights: • Strong interaction between plasma and Li would cause strong Li emission and lead to disruptive plasmas, and probable reasons were analyzed. • Serious Li would be emitted from the free statics surface mainly due to J × B force leading to plasma instable and disruptions. • CPS surface would partially suppress the emission and be beneficial for plasma operation. • Li emission from flowing LLLs on free surfaces on SS trenches and on SS plate were compared. - Abstract: Experiments with liquid lithium limiters (LLLs) have been successfully performed in HT-7 since 2009 and the effects of different limiter surface structures on the ejection of Li droplets have been studied and compared. The experiments have demonstrated that strong interaction between the plasma and the liquid surface can cause intense Li efflux in the form of ejected Li droplets – which can, in turn, lead to plasma disruptions. The details of the LLL plasma-facing surface were observed to be extremely important in determining performance. Five different LLLs were evaluated in this work: two types of static free-surface limiters and three types of flowing liquid Li (FLLL) structures. It has been demonstrated that a FLLL with a slowly flowing thin liquid Li film on vertical flow plate which was pre-treated with evaporated Li was much less susceptible to Li droplet ejection than any of the other structures tested in this work. It was further observed that the plasmas run against this type of limiter were reproducibly well-behaved. These results provide technical references for the design of FLLLs in future tokamaks so as to avoid strong Li ejection and to decrease disruptive plasmas.

  4. Circular mode: a new scanning probe microscopy method for investigating surface properties at constant and continuous scanning velocities.

    Science.gov (United States)

    Nasrallah, Hussein; Mazeran, Pierre-Emmanuel; Noël, Olivier

    2011-11-01

    In this paper, we introduce a novel scanning probe microscopy mode, called the circular mode, which offers expanded capabilities for surface investigations especially for measuring physical properties that require high scanning velocities and/or continuous displacement with no rest periods. To achieve these specific conditions, we have implemented a circular horizontal displacement of the probe relative to the sample plane. Thus the relative probe displacement follows a circular path rather than the conventional back and forth linear one. The circular mode offers advantages such as high and constant scanning velocities, the possibility to be combined with other classical operating modes, and a simpler calibration method of the actuators generating the relative displacement. As application examples of this mode, we report its ability to (1) investigate the influence of scanning velocity on adhesion forces, (2) measure easily and instantly the friction coefficient, and (3) generate wear tracks very rapidly for tribological investigations. © 2011 American Institute of Physics

  5. Continuous-flow liquid microjunction surface sampling probe connected on-line with high-performance liquid chromatography/mass spectrometry for spatially resolved analysis of small molecules and proteins.

    Science.gov (United States)

    Van Berkel, Gary J; Kertesz, Vilmos

    2013-06-30

    A continuous-flow liquid microjunction surface sampling probe extracts soluble material from surfaces for direct ionization and detection by mass spectrometry. Demonstrated here is the on-line coupling of such a probe with high-performance liquid chromatography/mass spectrometry (HPLC/MS) enabling extraction, separation and detection of small molecules and proteins from surfaces in a spatially resolved (~0.5 mm diameter spots) manner. A continuous-flow liquid microjunction surface sampling probe was connected to a six-port, two-position valve for extract collection and injection to an HPLC column. A QTRAP® 5500 hybrid triple quadrupole linear ion trap equipped with a Turbo V™ ion source operated in positive electrospray ionization (ESI) mode was used for all experiments. The system operation was tested with the extraction, separation and detection of propranolol and associated metabolites from drug dosed tissues, caffeine from a coffee bean, cocaine from paper currency, and proteins from dried sheep blood spots on paper. Confirmed in the tissue were the parent drug and two different hydroxypropranolol glucuronides. The mass spectrometric response for these compounds from different locations in the liver showed an increase with increasing extraction time (5, 20 and 40 s). For on-line separation and detection/identification of extracted proteins from dried sheep blood spots, two major protein peaks dominated the chromatogram and could be correlated with the expected masses for the hemoglobin α and β chains. Spatially resolved sampling, separation, and detection of small molecules and proteins from surfaces can be accomplished using a continuous-flow liquid microjunction surface sampling probe coupled on-line with HPLC/MS detection. Published in 2013. This article is a U.S. Government work and is in the public domain in the USA.

  6. Three distinct modes in a surface micro-discharge in atmospheric pressure He + N{sub 2} mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Li, Dong; Liu, Dingxin, E-mail: liudingxin@mail.xjtu.edu.cn; He, Tongtong; Li, Qiaosong; Wang, Xiaohua [State Key Laboratory of Electrical Insulation and Power Equipment, Center for Plasma Biomedicine, Xi' an Jiaotong University, Xi' an 710049 (China); Kong, Michael G. [State Key Laboratory of Electrical Insulation and Power Equipment, Center for Plasma Biomedicine, Xi' an Jiaotong University, Xi' an 710049 (China); Frank Reidy Center for Bioelectrics, Old Dominion University, Norfolk, Virginia 23508 (United States); Department of Electrical and Computer Engineering, Old Dominion University, Norfolk, Virginia 23529 (United States)

    2015-12-15

    A surface micro-discharge in atmospheric pressure He + N{sub 2} mixtures is studied in this paper with an emphasis on the discharge modes. With the N{sub 2} admixture increasing from 0.1% to 20%, the discharge evolves from a spatially diffuse mode to a filamentary mode during positive half-cycles of the applied voltage. However during the negative half-cycles, an additional patterned mode emerges between the diffuse and the filamentary modes, which has not been reported before to exist in surface micro-discharges. In the diffuse and patterned modes, the plasmas cover almost the entirety of the mesh area during one cycle after plasma ignition in all mesh elements, and the discharge power increases linearly with the applied voltage. In contrast, plasma coverage of the mesh area is only partial in the filamentary mode and the plasma is more unstable with the discharge power increasing exponentially with the applied voltage. As the surface micro-discharge evolves through the three modes, the density of excited species changes significantly, for instance, the density of N{sub 2}{sup +}(B) drops by ∼20-fold from [N{sub 2}] = 0.2% to 20%. The N{sub 2}{sup +}(B) is predicted to be generated mainly through successive processes of Penning ionization by helium metastables and electron-impact excitation of N{sub 2}{sup +}(X), the latter is most responsible for the density decrease of N{sub 2}{sup +}(B) because much more N{sub 2}{sup +}(X) is converted to N{sub 4}{sup +}(X) as the increase of N{sub 2} fraction. Also, the electron density and electron temperature decrease with the discharge mode transition.

  7. Molecular dynamics study of room temperature ionic liquids with water at mica surface

    Directory of Open Access Journals (Sweden)

    Huanhuan Zhang

    2018-04-01

    Full Text Available Water in room temperature ionic liquids (RTILs could impose significant effects on their interfacial properties at a charged surface. Although the interfaces between RTILs and mica surfaces exhibit rich microstructure, the influence of water content on such interfaces is little understood, in particular, considering the fact that RTILs are always associated with water due to their hygroscopicity. In this work, we studied how different types of RTILs and different amounts of water molecules affect the RTIL-mica interfaces, especially the water distribution at mica surfaces, using molecular dynamics (MD simulation. MD results showed that (1 there is more water and a thicker water layer adsorbed on the mica surface as the water content increases, and correspondingly the average location of K+ ions is farther from mica surface; (2 more water accumulated at the interface with the hydrophobic [Emim][TFSI] than in case of the hydrophilic [Emim][BF4] due to the respective RTIL hydrophobicity and ion size. A similar trend was also observed in the hydrogen bonds formed between water molecules. Moreover, the 2D number density map of adsorbed water revealed that the high-density areas of water seem to be related to K+ ions and silicon/aluminum atoms on mica surface. These results are of great importance to understand the effects of hydrophobicity/hydrophicility of RTIL and water on the interfacial microstructure at electrified surfaces. Keywords: Room temperature ionic liquids, Hydrophobicity/hydrophicility, Water content, Electrical double layer, Mica surface

  8. Surface science and model catalysis with ionic liquid-modified materials.

    Science.gov (United States)

    Steinrück, H-P; Libuda, J; Wasserscheid, P; Cremer, T; Kolbeck, C; Laurin, M; Maier, F; Sobota, M; Schulz, P S; Stark, M

    2011-06-17

    Materials making use of thin ionic liquid (IL) films as support-modifying functional layer open up a variety of new possibilities in heterogeneous catalysis, which range from the tailoring of gas-surface interactions to the immobilization of molecularly defined reactive sites. The present report reviews recent progress towards an understanding of "supported ionic liquid phase (SILP)" and "solid catalysts with ionic liquid layer (SCILL)" materials at the microscopic level, using a surface science and model catalysis type of approach. Thin film IL systems can be prepared not only ex-situ, but also in-situ under ultrahigh vacuum (UHV) conditions using atomically well-defined surfaces as substrates, for example by physical vapor deposition (PVD). Due to their low vapor pressure, these systems can be studied in UHV using the full spectrum of surface science techniques. We discuss general strategies and considerations of this approach and exemplify the information available from complementary methods, specifically photoelectron spectroscopy and surface vibrational spectroscopy. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Initial adhesion of Listeria monocytogenes to solid surfaces under liquid flow

    DEFF Research Database (Denmark)

    Szlavik, Julie; Soares Paiva, Dionísio; Mørk, Nils

    2012-01-01

    .001) was observed but not of interactions between surface-shear stress. No correlation between surface hydrophobicity and IAR was observed. Addition of 5% NaCl during propagation resulted in a decrease in IAR whilst propagation in low nutrient media caused an increase indicating a general change in surface......Some strains of the food borne pathogen Listeria monocytogenes persist in food processing environments. The exact reason behind this phenomenon is not known, but strain differences in the ability to adhere to solid surfaces could offer an explanation. In the present work, initial adhesion of nine...... strains of L. monocytogenes was investigated under liquid flow at two levels of shear stress on six different surfaces using a flow chamber set-up with microscopy measurements. The surfaces tested were glass and PVC, and glass coated with beef extract, casein, and homogenised and unhomogenised milk...

  10. Improvement in Surface Characterisitcs of Polymers for Subsequent Electroless Plating Using Liquid Assisted Laser Processing

    DEFF Research Database (Denmark)

    Marla, Deepak; Zhang, Yang; Jabbaribehnam, Mirmasoud

    2016-01-01

    Metallization of polymers is a widely used process in the electronic industry that involves their surface modification as a pre-treatment step. Laser-based surface modification is one of the commonly used techniques for polymers due to its speed and precision. The process involves laser heating...... of the polymer surface to generate a rough or porous surface. Laser processing in liquid generates superior surface characteristics that result in better metal deposition. In this study, a comparison of the surface characteristics obtained by laser processing in water vis-à-vis air along with the deposition...... characteristics are presented. In addition, a numerical model based on the finite volume method is developed to predict the temperature profile during the process. Based on the model results, it is hypothesized that physical phenomena such as vapor bubble generation and plasma formation may occur in the presence...

  11. An experimental study of the surface chemistry and evaporation kinetics of liquid sodium

    International Nuclear Information System (INIS)

    Becker, C.H.

    1983-01-01

    The evaporation rate and internal energy distribution of Na 2 evaporating from clean liquid Na and liquid Na exposed separately to O 2 and benzene were investigated by laser spectroscopy. The evaporating Na 2 was always found to be in thermal equilibrium with the surface. Oxygen increased the evaporation rate while benzene diminished it. A 3 keV Ar + beam was used to examine the surface by monitoring secondary ion emission. Ion emission from clean and oxygen exposed Na was extremely low; only limits could be established. Ion emission from sodium exposed to benzene could be observed only at lowered temperatures. The secondary ion emission, as well as visual observations of Na( 2 P-> 2 S) emission, are found to correspond to the evaporation rate behavior indicating that the Na surface remains very metal rich even while reacting with impinging oxygen at high (10 monolayers/s) rates. (orig.)

  12. Tracking Traction Force Changes of Single Cells on the Liquid Crystal Surface

    Directory of Open Access Journals (Sweden)

    Chin Fhong Soon

    2015-01-01

    Full Text Available Cell migration is a key contributor to wound repair. This study presents findings indicating that the liquid crystal based cell traction force transducer (LCTFT system can be used in conjunction with a bespoke cell traction force mapping (CTFM software to monitor cell/surface traction forces from quiescent state in real time. In this study, time-lapse photo microscopy allowed cell induced deformations in liquid crystal coated substrates to be monitored and analyzed. The results indicated that the system could be used to monitor the generation of cell/surface forces in an initially quiescent cell, as it migrated over the culture substrate, via multiple points of contact between the cell and the surface. Future application of this system is the real-time assaying of the pharmacological effects of cytokines on the mechanics of cell migration.

  13. Dependence of partial molecules surface area on the third component in lyotropic liquid crystals

    International Nuclear Information System (INIS)

    Badalyan, H.G.; Ghazaryan, Kh.M.; Yayloyan, S.M.

    2015-01-01

    Free surface of one amphiphilic molecule head of a lyotropic liquid crystal has been investigated by X-Ray diffraction method, at small and large angles, in the presence of the third component. The pentadecilsulphonat-water system in the presence of cholesterol as well as the lecithin-water system in the presence of decanol were investigated. It is shown that the above mentioned free surface decreases if the cholesterol concentration increases, while this surface increases in the case of water concentration increase. However, it increases slower than in the case of the two-component system. The same is observed for the lecithin-water-decanol system

  14. Quasi-one-dimensional electron transport over the surface of a liquid-helium film

    International Nuclear Information System (INIS)

    Sokolov, Sviatoslav; Studart, Nelson

    2003-01-01

    Quasi-one-dimensional mobility of surface electrons over a liquid-helium suspended film is studied for a conducting channel. The electron mobility is calculated taking into account the electron scattering by helium atoms in the vapor phase, ripplons, and surface defects of the film substrate both in one-electron regime and in the so-called complete-control limit where the influence of inter-electron collisions on the electron distribution function is taken into account. It is shown that the mobility for low temperatures is dominated by the surface-defect scattering and its temperature dependence is essentially different from that of the electron-ripplon scattering

  15. Temporal instability of viscous liquid microjets with spatially varying surface tension

    Energy Technology Data Exchange (ETDEWEB)

    Furlani, E P [Integrated Materials and Microstructures Laboratory, Electronic Imaging Products, Eastman Kodak Company, Rochester, NY 14650-2121 (United States)

    2005-01-07

    A linear theory is developed for the temporal instability of a viscous liquid microjet of Newtonian fluid with a spatially periodic variation of surface tension imposed along its length. The variation of surface tension induces Marangoni flow within the jet that leads to breakup and drop formation. An analytical expression is derived for the behaviour of the free surface of the microjet. This expression is useful for parametric analysis of jet instability and breakup as a function of jet radius, wavelength and fluid properties.

  16. Temporal instability of viscous liquid microjets with spatially varying surface tension

    International Nuclear Information System (INIS)

    Furlani, E P

    2005-01-01

    A linear theory is developed for the temporal instability of a viscous liquid microjet of Newtonian fluid with a spatially periodic variation of surface tension imposed along its length. The variation of surface tension induces Marangoni flow within the jet that leads to breakup and drop formation. An analytical expression is derived for the behaviour of the free surface of the microjet. This expression is useful for parametric analysis of jet instability and breakup as a function of jet radius, wavelength and fluid properties

  17. Equilibrium and surface stability of liquid dielectric interface in electrical and gravitational fields

    Energy Technology Data Exchange (ETDEWEB)

    Ievlev, I I; Isers, A B

    1976-01-01

    An examination is made of the problem of locating the stable equilibrium surface shape of the interface between two liquid, uniform, isotropic, ideal dielectrics subject to the force of gravity, surface tension, and electrical forces. The conditions for the equilibrium and surface stability of the interface were obtained from the minimum free energy principle. These conditions are used for solving problems on locating the stable equilibrium interface boundary between two dielectrics positioned between infinite charged vertical plates, between infinite vertical coaxial cylinders, between infinite grounded plates and two horizontal charged thin cylinders placed between them. 8 references, 4 figures.

  18. Equilibrium configurations of the conducting liquid surface in a nonuniform electric field

    Science.gov (United States)

    Zubarev, N. M.; Zubareva, O. V.

    2011-01-01

    Possible equilibrium configurations of the free surface of a conducting liquid deformed by a nonuniform external electric field are investigated. The liquid rests on an electrode that has the shape of a dihedral angle formed by two intersecting equipotential half-planes (conducting wedge). It is assumed that the problem has plane symmetry: the surface is invariant under shift along the edge of the dihedral angle. A one-parametric family of exact solutions for the shape of the surface is found in which the opening angle of the region above the wedge serves as a parameter. The solutions are valid when the pressure difference between the inside and outside of the liquid is zero. For an arbitrary pressure difference, approximate solutions to the problem are constructed and it is demonstrated the approximation error is small. It is found that, when the potential difference exceeds a certain threshold value, equilibrium solutions are absent. In this case, the region occupied by the liquid disintegrates, the disintegration scenario depending on the opening angle.

  19. Sum frequency and second harmonic generation from the surface of a liquid microjet

    Energy Technology Data Exchange (ETDEWEB)

    Smolentsev, Nikolay; Chen, Yixing; Roke, Sylvie, E-mail: sylvie.roke@epfl.ch [Laboratory for Fundamental Biophotonics (LBP), Institute of Bioengineering (IBI), School of Engineering STI, École Polytechnique Fédérale de Lausanne EPFL, 1015 Lausanne (Switzerland); Jena, Kailash C. [Laboratory for Fundamental Biophotonics (LBP), Institute of Bioengineering (IBI), School of Engineering STI, École Polytechnique Fédérale de Lausanne EPFL, 1015 Lausanne (Switzerland); Department of Physics, Indian Institute of Technology Ropar, Rupnagar, 140001 (India); Brown, Matthew A. [Laboratory for Surface Science and Technology, Department of Materials, ETH Zürich, CH-8093 Zurich (Switzerland)

    2014-11-14

    The use of a liquid microjet as a possible source of interest for Second Harmonic Generation (SHG) and Sum Frequency Generation (SFG) spectroscopy is examined. We measured non-resonant SHG scattering patterns from the air/water interface of a microjet of pure water and observe a strong enhancement of the SHG signal for certain scattering angles. These enhancements can be explained by the optical properties and the shape of the liquid microjet. SFG experiments at the surface of a liquid microjet of ethanol in air show that it is also possible to measure the coherent vibrational SFG spectrum of the ethanol/air interface in this way. Our findings are useful for future far-UV or X-ray based nonlinear optical surface experiments on liquid jets. In addition, combined X-ray photoelectron spectroscopy and SHG/SFG measurements are feasible, which will be very useful in improving our understanding of the molecular foundations of electrostatic and chemical surface properties and phenomena.

  20. Sum frequency and second harmonic generation from the surface of a liquid microjet

    Science.gov (United States)

    Smolentsev, Nikolay; Chen, Yixing; Jena, Kailash C.; Brown, Matthew A.; Roke, Sylvie

    2014-11-01

    The use of a liquid microjet as a possible source of interest for Second Harmonic Generation (SHG) and Sum Frequency Generation (SFG) spectroscopy is examined. We measured non-resonant SHG scattering patterns from the air/water interface of a microjet of pure water and observe a strong enhancement of the SHG signal for certain scattering angles. These enhancements can be explained by the optical properties and the shape of the liquid microjet. SFG experiments at the surface of a liquid microjet of ethanol in air show that it is also possible to measure the coherent vibrational SFG spectrum of the ethanol/air interface in this way. Our findings are useful for future far-UV or X-ray based nonlinear optical surface experiments on liquid jets. In addition, combined X-ray photoelectron spectroscopy and SHG/SFG measurements are feasible, which will be very useful in improving our understanding of the molecular foundations of electrostatic and chemical surface properties and phenomena.

  1. Sum frequency and second harmonic generation from the surface of a liquid microjet

    International Nuclear Information System (INIS)

    Smolentsev, Nikolay; Chen, Yixing; Roke, Sylvie; Jena, Kailash C.; Brown, Matthew A.

    2014-01-01

    The use of a liquid microjet as a possible source of interest for Second Harmonic Generation (SHG) and Sum Frequency Generation (SFG) spectroscopy is examined. We measured non-resonant SHG scattering patterns from the air/water interface of a microjet of pure water and observe a strong enhancement of the SHG signal for certain scattering angles. These enhancements can be explained by the optical properties and the shape of the liquid microjet. SFG experiments at the surface of a liquid microjet of ethanol in air show that it is also possible to measure the coherent vibrational SFG spectrum of the ethanol/air interface in this way. Our findings are useful for future far-UV or X-ray based nonlinear optical surface experiments on liquid jets. In addition, combined X-ray photoelectron spectroscopy and SHG/SFG measurements are feasible, which will be very useful in improving our understanding of the molecular foundations of electrostatic and chemical surface properties and phenomena

  2. Undulations on the surface of elongated bubbles in confined gas-liquid flows

    Science.gov (United States)

    Magnini, M.; Ferrari, A.; Thome, J. R.; Stone, H. A.

    2017-08-01

    A systematic analysis is presented of the undulations appearing on the surface of long bubbles in confined gas-liquid flows. CFD simulations of the flow are performed with a self-improved version of the open-source solver ESI OpenFOAM (release 2.3.1), for Ca =0.002 -0.1 and Re =0.1 -1000 , where Ca =μ U /σ and Re =2 ρ U R /μ , with μ and ρ being, respectively, the viscosity and density of the liquid, σ the surface tension, U the bubble velocity, and R the tube radius. A model, based on an extension of the classical axisymmetric Bretherton theory, accounting for inertia and for the curvature of the tube's wall, is adopted to better understand the CFD results. The thickness of the liquid film, and the wavelength and decay rate of the undulations extracted from the CFD simulations, agree well with those obtained with the theoretical model. Inertial effects appear when the Weber number of the flow We =Ca Re =O (10-1) and are manifest by a larger number of undulation crests that become evident on the surface of the rear meniscus of the bubble. This study demonstrates that the necessary bubble length for a flat liquid film region to exist between the rear and front menisci rapidly increases above 10 R when Ca >0.01 and the value of the Reynolds number approaches 1000.

  3. Optical microcavities based on surface modes in two-dimensional photonic crystals and silicon-on-insulator photonic crystals

    DEFF Research Database (Denmark)

    Xiao, Sanshui; Qiu, M.

    2007-01-01

    Surface-mode optical microcavities based on two-dimensional photonic crystals and silicon-on-insulator photonic crystals are studied. We demonstrate that a high-quality-factor microcavity can be easily realized in these structures. With an increasing of the cavity length, the quality factor is gr...... is gradually enhanced and the resonant frequency converges to that of the corresponding surface mode in the photonic crystals. These structures have potential applications such as sensing.......Surface-mode optical microcavities based on two-dimensional photonic crystals and silicon-on-insulator photonic crystals are studied. We demonstrate that a high-quality-factor microcavity can be easily realized in these structures. With an increasing of the cavity length, the quality factor...

  4. Visualization of high speed liquid jet impaction on a moving surface.

    Science.gov (United States)

    Guo, Yuchen; Green, Sheldon

    2015-04-17

    Two apparatuses for examining liquid jet impingement on a high-speed moving surface are described: an air cannon device (for examining surface speeds between 0 and 25 m/sec) and a spinning disk device (for examining surface speeds between 15 and 100 m/sec). The air cannon linear traverse is a pneumatic energy-powered system that is designed to accelerate a metal rail surface mounted on top of a wooden projectile. A pressurized cylinder fitted with a solenoid valve rapidly releases pressurized air into the barrel, forcing the projectile down the cannon barrel. The projectile travels beneath a spray nozzle, which impinges a liquid jet onto its metal upper surface, and the projectile then hits a stopping mechanism. A camera records the jet impingement, and a pressure transducer records the spray nozzle backpressure. The spinning disk set-up consists of a steel disk that reaches speeds of 500 to 3,000 rpm via a variable frequency drive (VFD) motor. A spray system similar to that of the air cannon generates a liquid jet that impinges onto the spinning disc, and cameras placed at several optical access points record the jet impingement. Video recordings of jet impingement processes are recorded and examined to determine whether the outcome of impingement is splash, splatter, or deposition. The apparatuses are the first that involve the high speed impingement of low-Reynolds-number liquid jets on high speed moving surfaces. In addition to its rail industry applications, the described technique may be used for technical and industrial purposes such as steelmaking and may be relevant to high-speed 3D printing.

  5. Surface functionalization by fine ultraviolet-patterning of nanometer-thick liquid lubricant films

    International Nuclear Information System (INIS)

    Lu, Renguo; Zhang, Hedong; Komada, Suguru; Mitsuya, Yasunaga; Fukuzawa, Kenji; Itoh, Shintaro

    2014-01-01

    Highlights: • We present fine UV-patterning of nm-thick liquid films for surface functionalization. • The patterned films exhibit both a morphological pattern and a functional pattern of different surface properties. • The finest pattern linewidth was 0.5 μm. • Fine patterning is crucial for improving surface and tribological properties. - Abstract: For micro/nanoscale devices, surface functionalization is essential to achieve function and performance superior to those that originate from the inherent bulk material properties. As a method of surface functionalization, we dip-coated nanometer-thick liquid lubricant films onto solid surfaces and then patterned the lubricant films with ultraviolet (UV) irradiation through a photomask. Surface topography, adhesion, and friction measurements demonstrated that the patterned films feature a concave–convex thickness distribution with thicker lubricant in the irradiated regions and a functional distribution with lower adhesion and friction in the irradiated convex regions. The pattern linewidth ranged from 100 to as fine as 0.5 μm. The surface functionalization effect of UV-patterning was investigated by measuring the water contact angles, surface energies, friction forces, and depletion of the patterned, as-dipped, and full UV-irradiated lubricant films. The full UV-irradiated lubricant film was hydrophobic with a water contact angle of 102.1°, and had lower surface energy, friction, and depletion than the as-dipped film, which was hydrophilic with a water contact angle of 80.7°. This demonstrates that UV irradiation substantially improves the surface and tribological properties of the nanometer-thick liquid lubricant films. The UV-patterned lubricant films exhibited superior surface and tribological properties than the as-dipped film. The water contact angle increased and the surface energy, friction, and depletion decreased as the pattern linewidth decreased. In particular, the 0.5-μm patterned lubricant

  6. Superfocusing modes of surface plasmon polaritons in conical geometry based on the quasi-separation of variables approach

    International Nuclear Information System (INIS)

    Kurihara, Kazuyoshi; Otomo, Akira; Syouji, Atsushi; Takahara, Junichi; Suzuki, Koji; Yokoyama, Shiyoshi

    2007-01-01

    Analytic solutions to the superfocusing modes of surface plasmon polaritons in a conical geometry are theoretically studied using an ingenious method called the quasi-separation of variables. This method can be used to look for fundamental solutions to the wave equation for a field that must satisfy boundary conditions at all points on the continuous surface of tapered geometries. The set of differential equations exclusively separated from the wave equation can be consistently solved in combination with perturbation methods. This paper presents the zeroth-order perturbation solution of conical superfocusing modes with azimuthal symmetry and graphically represents them in electric field-line patterns

  7. Experimental and numerical investigations of the impingement of an oblique liquid jet onto a superhydrophobic surface: energy transformation

    Energy Technology Data Exchange (ETDEWEB)

    Kibar, Ali, E-mail: alikibar@kocaeli.edu.tr [Department of Mechanical and Material Technologies, Kocaeli University, 41285, Arslanbey Campus, Kocaeli (Turkey)

    2016-02-15

    This study presents the theory of impinging an oblique liquid jet onto a vertical superhydrophobic surface based on both experimental and numerical results. A Brassica oleracea leaf with a 160° apparent contact angle was used for the superhydrophobic surface. Distilled water was sent onto the vertical superhydrophobic surface in the range of 1750–3050 Reynolds number, with an inclination angle of 20°−40°, using a circular glass tube with a 1.75 mm inner diameter. The impinging liquid jet spread onto the surface governed by the inertia of the liquid and then reflected off the superhydrophobic surface due to the surface energy of the spreading liquid. Two different energy approaches, which have time-scale and per-unit length, were performed to determine transformation of the energy. The kinetic energy of the impinging liquid jet was transformed into the surface energy with an increasing interfacial surface area between the liquid and air during spreading. Afterwards, this surface energy of the spreading liquid was transformed into the reflection kinetic energy. (paper)

  8. Orientations of Liquid Crystals in Contact with Surfaces that Present Continuous Gradients of Chemical Functionality

    International Nuclear Information System (INIS)

    Clare, B.; Efimenko, K.; Fischer, D.; Genzer, J.; Abbott, N.

    2006-01-01

    We report the formation of continuous spatial gradients in the density of grafted semifluorinated chains on silicon oxide surfaces by vapor-phase diffusion of semifluorinated silanes. We quantify the orientations of the nematic liquid crystal (LC) 4-cyano-4'-pentylbiphenyl on these surfaces as a function of local surface composition obtained by using NEXAFS. These measurements demonstrate that it is possible to obtain the full range of tilt angles of a LC on these surfaces. We also use the data provided by these gradient surfaces to test hypotheses regarding the nature of the interaction between the LC and surfaces that give rise to the range of tilted orientations of the LC. We conclude that the orientations of the LC are not determined solely by the density of grafted semifluorinated chains or by the density of residual hydroxyl groups presented at these surfaces following reactions with the silanes. Instead, our results raise the possibility that the tilt angles of the semifluorinated chains on these surfaces (which are a function of the density of the grafted chains) may influence the orientation of the LC. These results, when combined, demonstrate the potential utility of gradient surfaces for screening surface chemistries that achieve desired orientations of LCs as well as for rapidly assembling experimental data sets that can be used to test propositions regarding mechanisms of anchoring LCs at surfaces

  9. A thermodynamic perturbation theory for the surface tension and ion density profile of a liquid metal

    International Nuclear Information System (INIS)

    Evans, R.; Kumaravadivel, R.

    1976-01-01

    A simple scheme for determining the ion density profile and the surface tension of a liquid metal is described. Assuming that the interaction between metallic pseudo-ions is of the form introduced by Evans, an approximate expression for the excess free energy of the system is derived using the thermodynamic perturbation theory of Weeks, Chandler and Anderson. This excess free energy is then minimized with respect to a parameter which specifies the ion density profile, and the surface tension is given directly. From a consideration of the dependence of the interionic forces on the electron density it is predicted that the ions should take up a very steep density profile at the liquid metal surface. This behaviour is contrasted with that to be expected for rare-gas fluids in which the interatomic forces are density-independent. The values of the surface tension calculated for liquid Na, K and Al from a simplified version of the theory are in reasonable agreement with experiment. (author)

  10. Temperature dependence of the bulk and surface properties of liquid Zn-Cd alloys

    Energy Technology Data Exchange (ETDEWEB)

    Awe, O.E. [University of Ibadan, Department of Physics, Ibadan (Nigeria); Azeez, A.A. [African University of Science and Technology, Abuja (Nigeria)

    2017-05-15

    The effects of temperature on the bulk and surface properties of liquid Zn-Cd alloys have been theoretically investigated, using a combination of self association model, Darken's thermodynamic equation for diffusion, empirical model for viscosity and a statistical mechanics model. The results from this study show that change in temperature resulted in cross-over effects in bulk and surface properties. We also found that with an increase in temperature, a pronounced asymmetry of viscosity isotherm is significantly reduced, and viscosity isotherm exhibited anomalous behaviour. Our results reveal that the homocoordination tendency in Zn-Cd liquid alloys is not strong and reduces with increasing temperature. The study further suggests a pronounced segregation of Cd-atoms at the surface of Zn-Cd liquid alloys and the extent of segregation reduces with temperature. We as well found that, in addition to the reported understanding that size-factor determines the compositional location of asymmetry of the viscosity isotherm, temperature is an operating parameter that has effect, not only on the composition of asymmetry, but also on the magnitude of asymmetry. In all the properties investigated, the most pronounced effect of temperature (52.9 %) is on the viscosity while the least effect (7.1 %) is on the surface tension. (orig.)

  11. Nucleation and growth of vapor bubbles in the liquid bulk and at a solid surface

    International Nuclear Information System (INIS)

    Yagov, V.V.

    1977-01-01

    The main achievements in the study of the vapor phase origin in liquid and the subsequent growth of the vapor bubbles are presented briefly, and a number of issues on which there is no single opinion as yet are also outlined. The theory of homogeneous nucleation and a great number of experiments make it possible not only to explain qualitatively the causes of spontaneous formation of vapor nucleation centers in the metastable liquid but provides a simple computational relation for the estimating the intensity of this process. None of the existing hypotheses, however, can give a complete answer to the question of the mechanism of the vapor phase nucleation on a solid surface under ''pure conditions'', although this is a more pressing problem. At the same time, the role of cavities of reservoir type (with a narrow orifice) on the surface under heating as reliable stabilizers of the vapor formation (especially in liquid metals) is clarified from the practical point of view. Thus, the identification of technology for production of such cavities would make it possible to increase substantially the efficiency of heat transferring surfaces. Any computational relations for the growth of bubbles on the heating surface also are (and, according to the author, necessarily will be) approximate ones, although considerable success has been achieved in this field

  12. Transmission X-ray scattering as a probe for complex liquid-surface structures

    Energy Technology Data Exchange (ETDEWEB)

    Fukuto, Masafumi; Yang, Lin; Nykypanchuk, Dmytro; Kuzmenko, Ivan

    2016-01-28

    The need for functional materials calls for increasing complexity in self-assembly systems. As a result, the ability to probe both local structure and heterogeneities, such as phase-coexistence and domain morphologies, has become increasingly important to controlling self-assembly processes, including those at liquid surfaces. The traditional X-ray scattering methods for liquid surfaces, such as specular reflectivity and grazing-incidence diffraction, are not well suited to spatially resolving lateral heterogeneities due to large illuminated footprint. A possible alternative approach is to use scanning transmission X-ray scattering to simultaneously probe local intermolecular structures and heterogeneous domain morphologies on liquid surfaces. To test the feasibility of this approach, transmission small- and wide-angle X-ray scattering (TSAXS/TWAXS) studies of Langmuir films formed on water meniscus against a vertically immersed hydrophilic Si substrate were recently carried out. First-order diffraction rings were observed in TSAXS patterns from a monolayer of hexagonally packed gold nanoparticles and in TWAXS patterns from a monolayer of fluorinated fatty acids, both as a Langmuir monolayer on water meniscus and as a Langmuir–Blodgett monolayer on the substrate. The patterns taken at multiple spots have been analyzed to extract the shape of the meniscus surface and the ordered-monolayer coverage as a function of spot position. These results, together with continual improvement in the brightness and spot size of X-ray beams available at synchrotron facilities, support the possibility of using scanning-probe TSAXS/TWAXS to characterize heterogeneous structures at liquid surfaces.

  13. Non-equilibrium Thermodynamic Dissolution Theory for Multi-Component Solid/Liquid Surfaces Involving Surface Adsorption and Radiolysis Kinetics

    International Nuclear Information System (INIS)

    Stout, R B

    2001-01-01

    A theoretical expression is developed for the dissolution rate response for multi-component radioactive materials that have surface adsorption kinetics and radiolysis kinetics when wetted by a multi-component aqueous solution. An application for this type of dissolution response is the performance evaluation of multi-component spent nuclear fuels (SNFs) for long term interim storage and for geological disposition. Typically, SNF compositions depend on initial composition, uranium oxide and metal alloys being most common, and on reactor burnup which results in a wide range of fission product and actinide concentrations that decay by alpha, beta, and gamma radiation. These compositional/burnup ranges of SNFs, whether placed in interim storage or emplaced in a geologic repository, will potentially be wetted by multi-component aqueous solutions, and these solutions may be further altered by radiolytic aqueous species due to three radiation fields. The solid states of the SNFs are not thermodynamically stable when wetted and will dissolve, with or without radiolysis. The following development of a dissolution theory is based on a non-equilibrium thermodynamic analysis of energy reactions and energy transport across a solid-liquid phase change discontinuity that propagates at a quasi-steady, dissolution velocity. The integral form of the energy balance equation is used for this spatial surface discontinuity analysis. The integral formulation contains internal energy functional of classical thermodynamics for both the SNFs' solid state and surface adsorption species, and the adjacent liquid state, which includes radiolytic chemical species. The steady-state concentrations of radiolytic chemical species are expressed by an approximate analysis of the decay radiation transport equation. For purposes of illustration a modified Temkin adsorption isotherm was assumed for the surface adsorption kinetics on an arbitrary, finite area of the solid-liquid dissolution interface. For

  14. Measurement of surface temperature profiles on liquid uranium metal during electron beam evaporation

    Energy Technology Data Exchange (ETDEWEB)

    Ohba, Hironori; Shibata, Takemasa [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    1998-11-01

    Surface temperature distributions of liquid uranium in a water-cooled copper crucible during electron beam evaporation were measured. Evaporation surface was imaged by a lens through a band-path filter (650{+-}5 nm) and a double mirror system on a charge coupled device (CCD) camera. The video signals of the recorded image were connected to an image processor and converted to two-dimensional spectral radiance profiles. The surface temperatures were obtained from the spectral radiation intensity ratio of the evaporation surface and a freezing point of uranium and/or a reference light source using Planck`s law of radiation. The maximum temperature exceeded 3000 K and had saturation tendency with increasing electron beam input. The measured surface temperatures agreed with those estimated from deposition rates and data of saturated vapor pressure of uranium. (author)

  15. Surface tension anomalies in room temperature ionic liquids-acetone solutions

    Science.gov (United States)

    Abe, Hiroshi; Murata, Keisuke; Kiyokawa, Shota; Yoshimura, Yukihiro

    2018-05-01

    Surface tension anomalies were observed in room temperature ionic liquid (RTIL)-acetone solutions. The RTILs are 1-alkyl-3-methylimidazorium iodide with [Cnmim][I] in a [Cnmim][I]-x mol% acetone. The maximum value of the surface tension appeared at 40 mol% acetone, although density decreased monotonically with an increase in acetone concentration. A small alkyl chain length effect of the Cnmim+ cations was observed in the surface tension. By the Gibbs adsorption isotherm, it was found that I- anion-mediated surface structure became dominant above 40 mol%. In the different [Cnmim][TFSI]-acetone mixtures, normal decay of the surface tension was observed on the acetone concentration scale, where TFSI- is bis(trifluoromethanesulfonyl)imide.

  16. Potentiostatic control of ionic liquid surface film formation on ZE41 magnesium alloy.

    Science.gov (United States)

    Efthimiadis, Jim; Neil, Wayne C; Bunter, Andrew; Howlett, Patrick C; Hinton, Bruce R W; MacFarlane, Douglas R; Forsyth, Maria

    2010-05-01

    The generation of potentially corrosion-resistant films on light metal alloys of magnesium have been investigated. Magnesium alloy, ZE41 [Mg-Zn-Rare Earth (RE)-Zr, nominal composition approximately 4 wt % Zn, approximately 1.7 wt % RE (Ce), approximately 0.6 wt % Zr, remaining balance, Mg], was exposed under potentiostatic control to the ionic liquid trihexyl(tetradecyl)phosphonium diphenylphosphate, denoted [P(6,6,6,14)][DPP]. During exposure to this IL, a bias potential, shifted from open circuit, was applied to the ZE41 surface. Electrochemical impedance spectroscopy (EIS) and chronoamperometry (CA) were used to monitor the evolution of film formation on the metal surface during exposure. The EIS data indicate that, of the four bias potentials examined, applying a potential of -200 mV versus OCP during the exposure period resulted in surface films of greatest resistance. Both EIS measurements and scanning electron microscopy (SEM) imaging indicate that these surfaces are substantially different to those formed without potential bias. Time of flight-secondary ion mass spectrometry (ToF-SIMS) elemental mapping of the films was utilized to ascertain the distribution of the ionic liquid cationic and anionic species relative to the microstructural surface features of ZE41 and indicated a more uniform distribution compared with the surface following exposure in the absence of a bias potential. Immersion of the treated ZE41 specimens in a chloride contaminated salt solution clearly indicated that the ionic liquid generated surface films offered significant protection against pitting corrosion, although the intermetallics were still insufficiently protected by the IL and hence favored intergranular corrosion processes.

  17. Liquid-bridge stability and breakup on surfaces with contact-angle hysteresis.

    Science.gov (United States)

    Akbari, Amir; Hill, Reghan J

    2016-08-10

    We study the stability and breakup of liquid bridges with a free contact line on surfaces with contact-angle hysteresis (CAH) under zero-gravity conditions. Non-ideal surfaces exhibit CAH because of surface imperfections, by which the constraints on three-phase contact lines are influenced. Given that interfacial instabilities are constraint-sensitive, understanding how CAH affects the stability and breakup of liquid bridges is crucial for predicting the drop size in contact-drop dispensing. Unlike ideal surfaces on which contact lines are always free irrespective of surface wettability, contact lines may undergo transitions from pinned to free and vice versa during drop deposition on non-ideal surfaces. Here, we experimentally and theoretically examine how stability and breakup are affected by CAH, highlighting cases where stability is lost during a transition from a pinned-pinned (more constrained) to pinned-free (less constrained) interface-rather than a critical state. This provides a practical means of expediting or delaying stability loss. We also demonstrate how the dynamic contact angle can control the contact-line radius following stability loss.

  18. Biomimetic Implant Surface Functionalization with Liquid L-PRF Products: In Vitro Study

    Directory of Open Access Journals (Sweden)

    Marco Lollobrigida

    2018-01-01

    Full Text Available Objective. Platelet-rich fibrin (PRF clots and membranes are autologous blood concentrates widely used in oral surgical procedures; less is known, however, about the liquid formulations of such products. The aim of this in vitro study is to assess the behavior of different implant surfaces when in contact with two liquid leucocyte- and platelet-rich fibrin (L-PRF products. Methods. Six commercial pure titanium discs, of 9.5 mm diameter and 1.5 mm thickness, were used. Three of these samples had a micro/nano-rough surface; three were machined. Three different protocols were tested. Protocols involved the immersion of the samples in (1 a platelets, lymphocytes, and fibrinogen liquid concentrate (PLyF for 10 minutes, (2 an exudate obtained from L-PRF clots rich in fibronectin and vitronectin for 5 minutes, and (3 the fibronectin/vitronectin exudate for 2 minutes followed by immersion in the PLyF concentrate for further 8 minutes. After these treatments, the samples were fixed and observed using a scanning electron microscope (SEM. Results. Under microscopic observation, (1 the samples treated with the PLyF concentrate revealed a dense fibrin network in direct contact with the implant surface and a significant number of formed elements of blood; (2 in the samples treated with the fibronectin/vitronectin exudates, only a small number of white and red blood cells were detectable; and (3 in samples exposed to the combined treatment, there was an apparent increase in the thickness of the fibrin layer. When compared to the machined surface, the micro/nano-rough samples showed an overall increased retention of fibrin, leading to a thicker coating. Conclusions. Liquid L-PRF products promote the formation of a dense fibrin clot on micro/nano-rough implant surfaces in vitro. The adjunctive treatment of surfaces with the fibronectin/vitronectin exudate could provide support to contact of the fibrin with the surface, though it is not essential for the clot

  19. A high-performance lab-on-a-chip liquid sensor employing surface acoustic wave resonance

    Science.gov (United States)

    Kustanovich, K.; Yantchev, V.; Kirejev, V.; Jeffries, G. D. M.; Lobovkina, T.; Jesorka, A.

    2017-11-01

    We demonstrate herein a new concept for lab-on-a-chip in-liquid sensing, through integration of surface acoustic wave resonance (SAR) in a one-port configuration with a soft polymer microfluidic delivery system. In this concept, the reflective gratings of a one-port surface acoustic wave (SAW) resonator are employed as mass loading-sensing elements, while the SAW transducer is protected from the measurement environment. We describe the design, fabrication, implementation, and characterization using liquid medium. The sensor operates at a frequency of 185 MHz and has demonstrated a comparable sensitivity to other SAW in-liquid sensors, while offering quality factor (Q) value in water of about 250, low impedance and fairly low susceptibility to viscous damping. For proof of principle, sensing performance was evaluated by means of binding 40 nm neutravidin-coated SiO2 nanoparticles to a biotin-labeled lipid bilayer deposited over the reflectors. Frequency shifts were determined for every step of the affinity assay. Demonstration of this integrated technology highlights the potential of SAR technology for in-liquid sensing.

  20. Dynamics of liquid nitrogen cooling process of solid surface at wetting contact coefficient

    International Nuclear Information System (INIS)

    Smakulski, P; Pietrowicz, S

    2015-01-01

    Liquid cryogens cooling by direct contact is very often used as a method for decreasing the temperature of electronic devices or equipment i.e. HTS cables. Somehow, cooldown process conducted in that way could not be optimized, because of cryogen pool boiling characteristic and low value of the heat transfer coefficient. One of the possibilities to increase the efficiency of heat transfer, as well as the efficiency of cooling itself, it is to use a spray cooling method. The paper shows dynamics analysis of liquid nitrogen cooling solid surface process. The model of heat transfer for the single droplet of liquid nitrogen, which hits on a flat and smooth surface with respect to the different Weber numbers, is shown. Temperature profiles in calculation domains are presented, as well as the required cooling time. The numerical calculations are performed for different initial and boundary conditions, to study how the wetting contact coefficient is changing, and how it contributed to heat transfer between solid and liquid cryogen. (paper)

  1. The evolution of droplet impacting on thin liquid film at superhydrophilic surface

    Science.gov (United States)

    Li, Yun; Zheng, Yi; Lan, Zhong; Xu, Wei; Ma, Xuehu

    2017-12-01

    Thin films are ubiquitous in nature, and the evolution of a liquid film after droplet impact is critical in many industrial processes. In this paper, a series of experiments and numerical simulations are conducted to investigate the distribution and evolution features of local temperature as the droplet impacts a thin film on the superhydrophilic surface by the thermal tracing method. A cold area is formed in the center after droplet impacts on heated solid surfaces. For the droplet impact on thin heated liquid film, a ring-shaped low temperature zone is observed in this experiment. Meanwhile, numerical simulation is adopted to analyze the mechanism and the interaction between the droplet and the liquid film. It is found that due to the vortex velocity distribution formed inside the liquid film after the impact, a large part of the droplet has congested. The heating process is not obvious in the congested area, which leads to the formation of a low-temperature area in the results.

  2. Luminescence of Quantum Dots by Coupling with Nonradiative Surface Plasmon Modes in a Scanning Tunneling Microscope

    International Nuclear Information System (INIS)

    Romero, M.J.; van de Lagemaat, J.

    2009-01-01

    The electronic coupling between quantum dots (QDs) and surface plasmons (SPs) is investigated by a luminescence spectroscopy based on scanning tunneling microscopy (STM). We show that tunneling luminescence from the dot is excited by coupling with the nonradiative plasmon mode oscillating at the metallic tunneling gap formed during the STM operation. This approach to the SP excitation reveals aspects of the SP-QD coupling not accessible to the more conventional optical excitation of SPs. In the STM, luminescence from the dot is observed when and only when the SP is in resonance with the fundamental transition of the dot. The tunneling luminescence spectrum also suggests that excited SP-QD hybrid states can participate in the excitation of QD luminescence. Not only the SP excitation regulates the QD luminescence but the presence of the dot at the tunneling gap imposes restrictions to the SP that can be excited in the STM, in which the SP cannot exceed the energy of the fundamental transition of the dot. The superior SP-QD coupling observed in the STM is due to the tunneling gap acting as a tunable plasmonic resonator in which the dot is fully immersed.

  3. Optimization of electrocoagulation process to treat grey wastewater in batch mode using response surface methodology.

    Science.gov (United States)

    Karichappan, Thirugnanasambandham; Venkatachalam, Sivakumar; Jeganathan, Prakash Maran

    2014-01-10

    Discharge of grey wastewater into the ecological system causes the negative impact effect on receiving water bodies. In this present study, electrocoagulation process (EC) was investigated to treat grey wastewater under different operating conditions such as initial pH (4-8), current density (10-30 mA/cm2), electrode distance (4-6 cm) and electrolysis time (5-25 min) by using stainless steel (SS) anode in batch mode. Four factors with five levels Box-Behnken response surface design (BBD) was employed to optimize and investigate the effect of process variables on the responses such as total solids (TS), chemical oxygen demand (COD) and fecal coliform (FC) removal. The process variables showed significant effect on the electrocoagulation treatment process. The results were analyzed by Pareto analysis of variance (ANOVA) and second order polynomial models were developed in order to study the electrocoagulation process statistically. The optimal operating conditions were found to be: initial pH of 7, current density of 20 mA/cm2, electrode distance of 5 cm and electrolysis time of 20 min. These results indicated that EC process can be scale up in large scale level to treat grey wastewater with high removal efficiency of TS, COD and FC.

  4. Optimization of electrocoagulation process to treat grey wastewater in batch mode using response surface methodology

    Science.gov (United States)

    2014-01-01

    Background Discharge of grey wastewater into the ecological system causes the negative impact effect on receiving water bodies. Methods In this present study, electrocoagulation process (EC) was investigated to treat grey wastewater under different operating conditions such as initial pH (4–8), current density (10–30 mA/cm2), electrode distance (4–6 cm) and electrolysis time (5–25 min) by using stainless steel (SS) anode in batch mode. Four factors with five levels Box-Behnken response surface design (BBD) was employed to optimize and investigate the effect of process variables on the responses such as total solids (TS), chemical oxygen demand (COD) and fecal coliform (FC) removal. Results The process variables showed significant effect on the electrocoagulation treatment process. The results were analyzed by Pareto analysis of variance (ANOVA) and second order polynomial models were developed in order to study the electrocoagulation process statistically. The optimal operating conditions were found to be: initial pH of 7, current density of 20 mA/cm2, electrode distance of 5 cm and electrolysis time of 20 min. Conclusion These results indicated that EC process can be scale up in large scale level to treat grey wastewater with high removal efficiency of TS, COD and FC. PMID:24410752

  5. Effect of localized surface-plasmon mode on exciton transport and radiation emission in carbon nanotubes.

    Science.gov (United States)

    Roslyak, Oleksiy; Cherqui, Charles; Dunlap, David H; Piryatinski, Andrei

    2014-07-17

    We report on a general theoretical approach to study exciton transport and emission in a single-walled carbon nanotube (SWNT) in the presence of a localized surface-plasmon (SP) mode within a metal nanoparticle interacting via near-field coupling. We derive a set of quantum mechanical equations of motion and approximate rate equations that account for the exciton, SP, and the environmental degrees of freedom. The material equations are complemented by an expression for the radiated power that depends on the exciton and SP populations and coherences, allowing for an examination of the angular distribution of the emitted radiation that would be measured in experiment. Numerical simulations for a (6,5) SWNT and cone-shaped Ag metal tip (MT) have been performed using this methodology. Comparison with physical parameters shows that the near-field interaction between the exciton-SP occurs in a weak coupling regime, with the diffusion processes being much faster than the exciton-SP population exchange. In such a case, the effect of the exciton population transfer to the MT with its subsequent dissipation (i.e., the Förster energy transfer) is to modify the exciton steady state distribution while reducing the equilibration time for excitons to reach a steady sate distribution. We find that the radiation distribution is dominated by SP emission for a SWNT-MT separation of a few tens of nanometers due to the fast SP emission rate, whereas the exciton-SP coherences can cause its rotation.

  6. Exercise muscle fatigue detection system implementation via wireless surface electromyography and empirical mode decomposition.

    Science.gov (United States)

    Chang, Kang-Ming; Liu, Shing-Hong; Wang, Jia-Jung; Cheng, Da-Chuan

    2013-01-01

    Surface electromyography (sEMG) is an important measurement for monitoring exercise and fitness. A wireless Bluetooth transmission sEMG measurement system with a sampling frequency of 2 KHz is developed. Traditional muscle fatigue is detected from the median frequency of the sEMG power spectrum. The regression slope of the linear regression of median frequency is an important muscle fatigue index. As fatigue increases, the power spectrum of the sEMG shifts toward lower frequencies. The goal of this study is to evaluate the sensitivity of empirical mode decomposition (EMD) quantifying the electrical manifestations of the local muscle fatigue during exercising in health people. We also compared this method with the raw data and discrete wavelet transform (DWT). Five male and five female volunteers participated. Each subject was asked to run on a multifunctional pedaled elliptical trainer for about 30 minutes, twice a week, and there were a total of six recording times for each subject with a wireless EMG recording system. The results show that sensitivity of the highest frequency component of EMD is better than the highest frequency component of DWT, and raw data.

  7. Empirical Mode Decomposition on the sphere: application to the spatial scales of surface temperature variations

    Directory of Open Access Journals (Sweden)

    N. Fauchereau

    2008-06-01

    Full Text Available Empirical Mode Decomposition (EMD is applied here in two dimensions over the sphere to demonstrate its potential as a data-adaptive method of separating the different scales of spatial variability in a geophysical (climatological/meteorological field. After a brief description of the basics of the EMD in 1 then 2 dimensions, the principles of its application on the sphere are explained, in particular via the use of a zonal equal area partitioning. EMD is first applied to an artificial dataset, demonstrating its capability in extracting the different (known scales embedded in the field. The decomposition is then applied to a global mean surface temperature dataset, and we show qualitatively that it extracts successively larger scales of temperature variations related, for example, to topographic and large-scale, solar radiation forcing. We propose that EMD can be used as a global data-adaptive filter, which will be useful in analysing geophysical phenomena that arise as the result of forcings at multiple spatial scales.

  8. Surface, dynamic and structural properties of liquid Al-Ti alloys

    International Nuclear Information System (INIS)

    Novakovic, R.; Giuranno, D.; Ricci, E.; Tuissi, A.; Wunderlich, R.; Fecht, H.-J.; Egry, I.

    2012-01-01

    The systems containing highly reactive element such as Ti are the most difficult to be determined experimentally and therefore, it is often necessary to estimate the missing values by theoretical models. The thermodynamic data of the Al-Ti system are scarce, its phase diagram is still incomplete and there are very few data on the thermophysical properties of Al-Ti melts. The study on surface, dynamic and static structural properties of liquid Al-Ti alloys has been carried out within the framework of the Compound Formation Model. In spite of the experimental difficulties, the surface tension of liquid Al-2 at.%Ti alloy has been measured over a temperature range by the pinned drop method.

  9. H-mode-like discharge under the presence of 1/1 rational surface at ergodic layer in LHD

    International Nuclear Information System (INIS)

    Morita, Shigeru; Morisaki, Tomohiro; Tanaka, Kenji

    2004-01-01

    H-mode-like discharge was found in LHD with a full B t field of 2.5T at an outwardly shifted configuration of R ax = 4.00 m where the m/n = 1/1 rational surface is located at the ergodic layer. The H-mode-like discharge was triggered by changing the P NBI from 9MW to 5 MW in a density range of 4-8 x 10 13 cm -3 , followed by a clear density rise, ELM-like H α bursts, and a reduction of magnetic fluctuation. These H-mode-like features vanished with a small radial movement of the 1/1 surface. (author)

  10. Liquid interfacial water and brines in the upper surface of Mars

    Science.gov (United States)

    Moehlmann, Diedrich

    2013-04-01

    Liquid interfacial water and brines in the upper surface of Mars Diedrich T.F. Möhlmann DLR Institut für Planetenforschung, Rutherfordstr. 2, D - 12489 Berlin, Germany dirk.moehlmann@dlr.de Interfacial water films and numerous brines are known to remain liquid at temperatures far below 0° C. The physical processes behind are described in some detail. Deliquescence, i.e. the liquefaction of hygroscopic salts at the threshold of a specific "Deliquescence Relative Humidity", is shown to be that process, which on present Mars supports the formation of stable interfacial water and bulk liquids in form of temporary brines on and in a salty upper surface of present Mars in a diurnally temporary and repetitive process. Temperature and relative humidity are the governing conditions for deliquescence (and the counterpart "efflorescence") to evolve. The current thermo-dynamical conditions on Mars support these processes to evolve on present Mars. The deliquescence-driven presence of liquid brines in the soil of the upper surface of Mars can expected to be followed by physical and chemical processes like "surface cementation", down-slope flows, and physical and chemical weathering processes. A remarkable and possibly also biologically relevant evolution towards internally interfacial water bearing structures of dendritic capillaries is related to their freezing - thawing driven formation. The internal walls of these network-pores or -tubes can be covered by films of interfacial water, providing that way possibly habitable crack-systems in soil and rock. These evolutionary processes of networks, driven by their tip-growth, can expected to be ongoing also at present.

  11. Drop deposition on surfaces with contact-angle hysteresis: Liquid-bridge stability and breakup

    OpenAIRE

    Akbari, Amir; Hill, Reghan J.

    2015-01-01

    We study the stability and breakup of liquid bridges with a free contact line on a surface with contact-angle hysteresis under zero-gravity conditions. Theoretical predictions of the stability limits are validated by experimental measurements. Experiments are conducted in a water-methanol-silicon oil system where the gravity force is offset by buoyancy. We highlight cases where stability is lost during the transition from a pinned-pinned to pinned-free interface when the receding contact angl...

  12. Surface-induced ordering of a liquid crystal in the isotropic phase

    International Nuclear Information System (INIS)

    Miyano, K.

    1979-01-01

    A detailed account of a measurement of order parameter of a liquid crystal at the boundary by means of the wall-induced pretransitional birefringence is given. Several surface treatments were studied including surfactants and evaporated films. Although all treatments produced good alignment in the nematic phase, the boundary order parameter (hence the strength of the aligning force) in the isotropic phase differed very much depending on the treatment, indicating the diverse nature of the alignment process

  13. Propagation of liquid surface waves over finite graphene structured arrays of cylinders

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    Based on the multiple scattering method,this paper investigates a benchmark problem of the propagation of liquid surface waves over finite graphene (or honeycomb) structured arrays of cylinders.Comparing the graphene structured array with the square structured and with triangle structured arrays,it finds that the finite graphene structure can produce more complete band gaps than the other finite structures,and the finite graphene structure has less localized ability than the other finite structures.

  14. Effects of airway surface liquid height on the kinetics of extracellular nucleotides in airway epithelia.

    Science.gov (United States)

    Amarante, Tauanne D; da Silva, Jafferson K L; Garcia, Guilherme J M

    2014-12-21

    Experimental techniques aimed at measuring the concentration of signaling molecules in the airway surface liquid (ASL) often require an unrealistically large ASL volume to facilitate sampling. This experimental limitation, prompted by the difficulty of pipetting liquid from a very shallow layer (~15 μm), leads to dilution and the under-prediction of physiologic concentrations of signaling molecules that are vital to the regulation of mucociliary clearance. Here, we use a computational model to describe the effect of liquid height on the kinetics of extracellular nucleotides in the airway surface liquid coating respiratory epithelia. The model consists of a reaction-diffusion equation with boundary conditions that represent the enzymatic reactions occurring on the epithelial surface. The simulations reproduce successfully the kinetics of extracellular ATP following hypotonic challenge for ASL volumes ranging from 25 μl to 500 μl in a 12-mm diameter cell culture. The model reveals that [ATP] and [ADO] reach 1200 nM and 2200 nM at the epithelial surface, respectively, while their volumetric averages remain less than 200 nM at all times in experiments with a large ASL volume (500 μl). These findings imply that activation of P2Y2 and A2B receptors is robust after hypotonic challenge, in contrast to what could be concluded based on experimental measurements of volumetric concentrations in large ASL volumes. Finally, given the central role that ATP and ADO play in regulating mucociliary clearance, we investigated which enzymes, when inhibited, provide the greatest increase in ATP and ADO concentrations. Our findings suggest that inhibition of NTPDase1/highTNAP would cause the greatest increase in [ATP] after hypotonic challenge, while inhibition of the transporter CNT3 would provide the greatest increase in [ADO]. Copyright © 2014 Elsevier Ltd. All rights reserved.

  15. Atomistic modelling of evaporation and explosive boiling of thin film liquid argon over internally recessed nanostructured surface

    Energy Technology Data Exchange (ETDEWEB)

    Hasan, Mohammad Nasim, E-mail: nasim@me.buet.ac.bd.com; Shavik, Sheikh Mohammad, E-mail: shavik@me.buet.ac.bd.com; Rabbi, Kazi Fazle, E-mail: rabbi35.me10@gmail.com; Haque, Mominul, E-mail: mominulmarup@gmail.com [Department of Mechanical Engineering, Bangladesh University of Engineering & Technology (BUET) Dhaka-1000 (Bangladesh)

    2016-07-12

    Molecular dynamics (MD) simulations have been carried out to investigate evaporation and explosive boiling phenomena of thin film liquid argon on nanostructured solid surface with emphasis on the effect of solid-liquid interfacial wettability. The nanostructured surface considered herein consists of trapezoidal internal recesses of the solid platinum wall. The wetting conditions of the solid surface were assumed such that it covers both the hydrophilic and hydrophobic conditions and hence effect of interfacial wettability on resulting evaporation and boiling phenomena was the main focus of this study. The initial configuration of the simulation domain comprised of a three phase system (solid platinum, liquid argon and vapor argon) on which equilibrium molecular dynamics (EMD) was performed to reach equilibrium state at 90 K. After equilibrium of the three-phase system was established, the wall was set to different temperatures (130 K and 250 K for the case of evaporation and explosive boiling respectively) to perform non-equilibrium molecular dynamics (NEMD). The variation of temperature and density as well as the variation of system pressure with respect to time were closely monitored for each case. The heat flux normal to the solid surface was also calculated to illustrate the effectiveness of heat transfer for hydrophilic and hydrophobic surfaces in cases of both nanostructured surface and flat surface. The results obtained show that both the wetting condition of the surface and the presence of internal recesses have significant effect on normal evaporation and explosive boiling of the thin liquid film. The heat transfer from solid to liquid in cases of surface with recesses are higher compared to flat surface without recesses. Also the surface with higher wettability (hydrophilic) provides more favorable conditions for boiling than the low-wetting surface (hydrophobic) and therefore, liquid argon responds quickly and shifts from liquid to vapor phase faster in

  16. Light reflection from a rough liquid surface including wind-wave effects in a scattering atmosphere

    International Nuclear Information System (INIS)

    Salinas, Santo V.; Liew, S.C.

    2007-01-01

    Visible and near-IR images of the ocean surface, taken from remote satellites, often contain important information of near-surface or sub-surface processes, which occur on, or over the ocean. Remote measurements of near surface winds, sea surface temperature and salinity, ocean color and underwater bathymetry, all, one way or another, depend on how well we understand sea surface roughness. However, in order to extract useful information from our remote measurements, we need to construct accurate models of the transfer of solar radiation inside the atmosphere as well as, its reflection from the sea surface. To approach this problem, we numerically solve the radiative transfer equation (RTE) by implementing a model for the atmosphere-ocean system. A one-dimensional atmospheric radiation model is solved via the widely known doubling and adding method and the ocean body is treated as a boundary condition to the problem. The ocean surface is modeled as a rough liquid surface which includes wind interaction and wave states, such as wave age. The model can have possible applications to the retrieval of wind and wave states, such as wave age, near a Sun glint region

  17. Liquid-solid surface phase transformation of fluorinated fullerene on monolayer tungsten diselenide

    KAUST Repository

    Song, Zhibo

    2018-04-04

    Hybrid van der Waals heterostructures constructed by the integration of organic molecules and two-dimensional (2D) transition metal dichalcogenide (TMD) materials have useful tunable properties for flexible electronic devices. Due to the chemically inert and atomically smooth nature of the TMD surface, well-defined crystalline organic films form atomically sharp interfaces facilitating optimal device performance. Here, the surface phase transformation of the supramolecular packing structure of fluorinated fullerene (C60F48) on single-layer tungsten diselenide (WSe2) is revealed by low-temperature scanning tunneling microscopy, from thermally stable liquid to solid phases as the coverage increases. Statistical analysis of the intermolecular interaction potential reveals that the repulsive dipole-dipole interaction induced by interfacial charge transfer and substrate-mediated interactions play important roles in stabilizing the liquid C60F48 phases. Theoretical calculations further suggest that the dipole moment per C60F48 molecule varies with the surface molecule density, and the liquid-solid transformation could be understood from the perspective of the thermodynamic free energy for open systems. This study offers insights into the growth behavior at 2D organic/TMD hybrid heterointerfaces.

  18. Measurement of the airway surface liquid volume with simple light refraction microscopy.

    Science.gov (United States)

    Harvey, Peter R; Tarran, Robert; Garoff, Stephen; Myerburg, Mike M

    2011-09-01

    In the cystic fibrosis (CF) lung, the airway surface liquid (ASL) volume is depleted, impairing mucus clearance from the lung and leading to chronic airway infection and obstruction. Several therapeutics have been developed that aim to restore normal airway surface hydration to the CF airway, yet preclinical evaluation of these agents is hindered by the paucity of methods available to directly measure the ASL. Therefore, we sought to develop a straightforward approach to measure the ASL volume that would serve as the basis for a standardized method to assess mucosal hydration using readily available resources. Primary human bronchial epithelial (HBE) cells cultured at an air-liquid interface develop a liquid meniscus at the edge of the culture. We hypothesized that the size of the fluid meniscus is determined by the ASL volume, and could be measured as an index of the epithelial surface hydration status. A simple method was developed to measure the volume of fluid present in meniscus by imaging the refraction of light at the ASL interface with the culture wall using low-magnification microscopy. Using this method, we found that primary CF HBE cells had a reduced ASL volume compared with non-CF HBE cells, and that known modulators of ASL volume caused the predicted responses. Thus, we have demonstrated that this method can detect physiologically relevant changes in the ASL volume, and propose that this novel approach may be used to rapidly assess the effects of airway hydration therapies in high-throughput screening assays.

  19. Liquid-solid surface phase transformation of fluorinated fullerene on monolayer tungsten diselenide

    Science.gov (United States)

    Song, Zhibo; Wang, Qixing; Li, Ming-Yang; Li, Lain-Jong; Zheng, Yu Jie; Wang, Zhuo; Lin, Tingting; Chi, Dongzhi; Ding, Zijing; Huang, Yu Li; Thye Shen Wee, Andrew

    2018-04-01

    Hybrid van der Waals heterostructures constructed by the integration of organic molecules and two-dimensional (2D) transition metal dichalcogenide (TMD) materials have useful tunable properties for flexible electronic devices. Due to the chemically inert and atomically smooth nature of the TMD surface, well-defined crystalline organic films form atomically sharp interfaces facilitating optimal device performance. Here, the surface phase transformation of the supramolecular packing structure of fluorinated fullerene (C60F48 ) on single-layer tungsten diselenide (WSe2) is revealed by low-temperature scanning tunneling microscopy, from thermally stable liquid to solid phases as the coverage increases. Statistical analysis of the intermolecular interaction potential reveals that the repulsive dipole-dipole interaction induced by interfacial charge transfer and substrate-mediated interactions play important roles in stabilizing the liquid C60F48 phases. Theoretical calculations further suggest that the dipole moment per C60F48 molecule varies with the surface molecule density, and the liquid-solid transformation could be understood from the perspective of the thermodynamic free energy for open systems. This study offers insights into the growth behavior at 2D organic/TMD hybrid heterointerfaces.

  20. Antiferroelectric surface layers in a liquid crystal as observed by synchrotron x-ray scattering

    DEFF Research Database (Denmark)

    Gramsbergen, E. F.; de Jeu, W. H.; Als-Nielsen, Jens Aage

    1986-01-01

    The X-ray reflectivity form the surface of a liquid crystal with terminally polar (cyano substituted) molecules has been studied using a high-resolution triple-axis X-ray spectrometer in combination with a synchrotron source. It is demonstrated that at the surface of the smectic Al phase a few...... antiferroelectric double layers develop that can be distinguished from the bulk single layer structure. A model is developed that separates the electron density in a contribution from the molecular form factor, and from the structure factor of the mono- and the bilayers, respectively. It shows that (i) the first...

  1. Basic research on nonlinear instability phenomena of liquid surface. Fiscal year 1996 report on preceding basic engineering field

    International Nuclear Information System (INIS)

    Madarame, Haruki; Okamoto, Koji; Iida, Masao

    1997-03-01

    Various nonlinear behaviors caused by nonlinear boundary conditions have been observed, and it is feared that in large vessels like FBRs, the instability phenomena such as self-exciting sloshing may occur in the free liquid surface of coolant. In this research, the nonlinear instability phenomena in free liquid surface were examined by the basic experiment and the analysis. As to the self-exciting oscillation 'jet flutter' of upward plane jet that collides against liquid surface, in order to know the mechanism of determining the frequency and supplying energy, the amplitude and phase relation of various variable quantities were investigated. The simplified model for calculating the displacement of jet was made, and compared with the experiment. The jet flutter phenomena are explained. The interaction of free liquid surface and turbulent flow, which is important for considering the nonlinearity in free liquid surface, was measured by LDV and visualization, and the turbulent flow phenomena in free liquid surface were investigated. In the experiment, turbulent flow energy was given to the free liquid surfaces of water and polymers, and the effect that the Toms effect exerted to interface turbulent flow was observed. The results of these studies are reported. (K.I.) studies are reported. (K.I.)

  2. Surface tension and density of liquid In-Sn-Zn alloys

    Science.gov (United States)

    Pstruś, Janusz

    2013-01-01

    Using the dilatometric method, measurements of the density of liquid alloys of the ternary system In-Sn-Zn in four sections with a constant ratio Sn:In = 24:1, 3:1, 1:1, 1:3, for various Zn additions (5, 10, 14, 20, 3 5, 50 and 75 at.% Zn) were performed at the temperature ranges of 500-1150 K. Density decreases linearly for all compositions. The molar volume calculated from density data exhibits close to ideal dependence on composition. Measurements of the surface tension of liquid alloys have been conducted using the method of maximum pressure in the gas bubbles. There were observed linear dependences on temperature with a negative gradients dσ/dT. Generally, with two exceptions, there was observed the increase of surface tension with increasing content of zinc. Using the Butler's model, the surface tension isotherms were calculated for temperatures T = 673 and 1073 K. Calculations show that only for high temperatures and for low content of zinc (up to about 35 at.%), the modeling is in very good agreement with experiment. Using the mentioned model, the composition of the surface phase was defined at two temperatures T = 673 and 973 K. Regardless of the temperature and of the defined section, the composition of the bulk is very different in comparison with the composition of the surface.

  3. Native Liquid Extraction Surface Analysis Mass Spectrometry: Analysis of Noncovalent Protein Complexes Directly from Dried Substrates

    Science.gov (United States)

    Martin, Nicholas J.; Griffiths, Rian L.; Edwards, Rebecca L.; Cooper, Helen J.

    2015-08-01

    Liquid extraction surface analysis (LESA) mass spectrometry is a promising tool for the analysis of intact proteins from biological substrates. Here, we demonstrate native LESA mass spectrometry of noncovalent protein complexes of myoglobin and hemoglobin from a range of surfaces. Holomyoglobin, in which apomyoglobin is noncovalently bound to the prosthetic heme group, was observed following LESA mass spectrometry of myoglobin dried onto glass and polyvinylidene fluoride surfaces. Tetrameric hemoglobin [(αβ)2 4H] was observed following LESA mass spectrometry of hemoglobin dried onto glass and polyvinylidene fluoride (PVDF) surfaces, and from dried blood spots (DBS) on filter paper. Heme-bound dimers and monomers were also observed. The `contact' LESA approach was particularly suitable for the analysis of hemoglobin tetramers from DBS.

  4. Effect of metal surface composition on deposition behavior of stainless steel component dissolved in liquid sodium

    International Nuclear Information System (INIS)

    Yokota, Norikatsu; Shimoyashiki, Shigehiro

    1988-01-01

    Deposition behavior of corrosion products has been investigated to clarify the effect of metal surface composition on the deposition process in liquid sodium. For the study a sodium loop made of Type 304 stainless steel was employed. Deposition test pieces, which were Type 304 stainless steel, iron, nickel or Inconel 718, were immersed in the sodium pool of the test pot. Corrosion test pieces, which were Type 304 stainless steel, 50 at% Fe-50 at%Mn and Inconel 718, were set in a heater pin assembly along the axial direction of the heater pin surface. Sodium temperatures at the outlet and inlet of the heater pin assembly were controlled at 943 and 833 K, respectively. Sodium was purified at a cold trap temperature of 393 K and the deposition test was carried out for 4.3 x 10 2 - 2.9 x 10 4 ks. Several crystallized particles were observed on the surface of the deposition test pieces. The particles had compositions and crystal structures which depended on both the composition of deposition test pieces and the concentration of iron and manganese in sodium. Only iron-rich particles having a polyhedral shape deposited on the iron surface. Two types of particles, iron-rich α-phase and γ-phase with nearly the same composition as stainless steel, were deposited on Type 304 stainless steel. A Ni-Mn alloy was deposited on the nickel surface in the case of a higher concentration of manganese in sodium. On the other hand, for a lower manganese concentration, a Fe-Ni alloy was precipitated on the nickel surface. Particles deposited on nickel had a γ-phase crystal structure similar to the deposition test piece of nickel. Hence, the deposition process can be explained as follows: Corrosion products in liquid sodium were deposited on the metal surface by forming a metal alloy selectively with elements of the metal surface. (author)

  5. Electrochemical Impedance Response of the surface treated FMS in Liquid Sodium Environment

    International Nuclear Information System (INIS)

    Lee, Jeong Hyeon; Shin, Sang Hun; Kim, Ji Hyun

    2014-01-01

    HT9 and Gr.92 are known as compatible in sodium environment because the usual refueling time of SFRs is designed about 54 months. It is very important to investigate the corrosion-related behavior such as surface corrosion rate, carburization, decarburization and mechanical properties for its operation time. SiC and Si 3 N 4 CVD coating for decarburization barrier on the surface of FMS is considered in this study. The decarburization process where dissolved carbon near the specimen surface disused in to the liquid sodium. This process can originate from the difference between dissolved carbon in the material and liquid sodium. A compatibility test the cladding tube revealed that a decrease of the mechanical property instigated by the aging proves governed the whole mechanical property. To monitor the corrosion behavior of these candidate materials in sodium environment, Electrochemical Impedance Spectroscopy (EIS) method is first introduced and investigated in this study. The compatibility of cladding and structural materials with sodium has to be carefully investigated, as sodium could promote corrosion of cladding and structural materials in two ways. One is produced by the dissolution of alloy constituents into the sodium, and the other is produced through a chemical reaction with impurities (especially oxygen and carbon) in the sodium environment. EIS test with pre-oxidized Gr. 92 specimen in 200 .deg. C liquid sodium environment was carried out in this study. A clear Nyquist and Bode plots were obtained in liquid metal environment and the resistance of sodium and the oxide, and the capacitance of the oxide were measured from this result

  6. Colonial vs. planktonic type of growth: mathematical modeling of microbial dynamics on surfaces and in liquid, semi-liquid and solid foods.

    Science.gov (United States)

    Skandamis, Panagiotis N; Jeanson, Sophie

    2015-01-01

    Predictive models are mathematical expressions that describe the growth, survival, inactivation, or biochemical processes of foodborne bacteria. During processing of contaminated raw materials and food preparation, bacteria are entrapped into the food residues, potentially transferred to the equipment surfaces (abiotic or inert surfaces) or cross-contaminate other foods (biotic surfaces). Growth of bacterial cells can either occur planktonically in liquid or immobilized as colonies. Colonies are on the surface or confined in the interior (submerged colonies) of structured foods. For low initial levels of bacterial population leading to large colonies, the immobilized growth differs from planktonic growth due to physical constrains and to diffusion limitations within the structured foods. Indeed, cells in colonies experience substrate starvation and/or stresses from the accumulation of toxic metabolites such as lactic acid. Furthermore, the micro-architecture of foods also influences the rate and extent of growth. The micro-architecture is determined by (i) the non-aqueous phase with the distribution and size of oil particles and the pore size of the network when proteins or gelling agent are solidified, and by (ii) the available aqueous phase within which bacteria may swarm or swim. As a consequence, the micro-environment of bacterial cells when they grow in colonies might greatly differs from that when they grow planktonically. The broth-based data used for modeling (lag time and generation time, the growth rate, and population level) are poorly transferable to solid foods. It may lead to an over-estimation or under-estimation of the predicted population compared to the observed population in food. If the growth prediction concerns pathogen bacteria, it is a major importance for the safety of foods to improve the knowledge on immobilized growth. In this review, the different types of models are presented taking into account the stochastic behavior of single cells

  7. Mass effect of redox reactions: A novel mode for surface plasmon resonance-based bioanalysis.

    Science.gov (United States)

    Yuan, Pei-Xin; Deng, Sheng-Yuan; Xin, Peng; Ji, Xu-Bo; Shan, Dan; Cosnier, Serge

    2015-12-15

    The pursuit of more specific and sensitive response is a perpetual goal for modern bioassays. This work proposed a novel label-free strategy about redox-related mass effect based on the surface plasmon resonance (SPR) technique for ultrasensitive determination of DNA. The protocol starts with the modification of SPR gilded disk with the capture DNA (cDNA). After the conjugation of immobilized cDNA with the target DNA (tDNA), the hybridization chain reaction was triggered by the introduction of mutual partial complementary primers to elongate the terminal into a nanoscale duplex. As it is reported that porphyrin could intercalate into the grooves of the double-stranded DNA (dsDNA) scaffold, multiple positive-charged Fe(III)meso-tetra(N-methyl-4-pyridyl) porphine (FeTMPyP) with symmetric structure were uptaken for in situ formation of porphyrin-dsDNA complex. Given FeTMPyP a highly efficient catalysis for the peroxide reduction, its presence as a biomimetic cofactor was validated via circular dichroism and UV-vis spectroscopy, demonstrating a tight binding as well as high catalytic activity and stability. Using 4-chloro-1-naphthol as a proton donor, the catalytic reduction of H2O2 would oxidize it into insoluble benzo-4-chloro-hexadienone, which simultaneously deposited on the heterogeneous interface, leading to a significant amplification in both SPR response and topological height profile. The signal increment was proportional to the concentration of tDNA, thus an ultrasensitive SPR-based DNA assay was developed with a linear range over four orders of magnitudes and a sub-femtomolar detection limit of 0.73 fM. The developed methodology exemplifies a different way of thinking about mass-sensing modes, extending conventional SPR-based DNA analysis to relevant biomedical applications. Copyright © 2015 Elsevier B.V. All rights reserved.

  8. The approximate determination of the critical temperature of a liquid by measuring surface tension versus the temperature

    International Nuclear Information System (INIS)

    Maroto, J A; Nieves, F J de las; Quesada-Perez, M

    2004-01-01

    A classical experience in a physics student laboratory is to determine the surface tension of a liquid versus the temperature and to check the linear appearance of the obtained graph. In this work we show a simple method to estimate the critical temperature of three liquids by using experimental data of surface tension at different temperatures. By a logarithm fitting between surface tension and temperature, the critical temperature can be determined and compared with data from the literature. For two liquids (butanol and nitrobenzene) the comparison is acceptable but the differences are too high for the third liquid (water). By discussing the results it seems to be clear that the difference between the critical temperature of the liquid and the maximum temperature of the surface tension measurements is the determining factor in obtaining acceptable results. From this study it is possible to obtain more information on the liquid characteristics from surface tension measurements that are currently carried out in a student laboratory. Besides, in this paper it is shown how to select the most suitable liquids which provide both acceptable values for the critical temperature and measurements of the surface tension at moderate temperatures. The complementary use of numerical methods permits us to offer a complete experience for the students with a simple laboratory experiment which we recommend for physics students in advanced university courses

  9. Predicting the minimum liquid surface tension activity of pseudomonads expressing biosurfactants.

    Science.gov (United States)

    Mohammed, I U; Deeni, Y; Hapca, S M; McLaughlin, K; Spiers, A J

    2015-01-01

    Bacteria produce a variety of biosurfactants capable of significantly reducing liquid (aqueous) surface tension (γ) with a range of biological roles and biotechnological uses. To determine the lowest achievable surface tension (γMin ), we tested a diverse collection of Pseudomonas-like isolates from contaminated soil and activated sludge and identified those expressing biosurfactants by drop-collapse assay. Liquid surface tension-reducing ability was quantitatively determined by tensiometry, with 57 isolates found to significantly lower culture supernatant surface tensions to 24·5-49·1 mN m(-1) . Differences in biosurfactant behaviour determined by foaming, emulsion and oil-displacement assays were also observed amongst isolates producing surface tensions of 25-27 mN m(-1) , suggesting that a range of structurally diverse biosurfactants were being expressed. Individual distribution identification (IDI) analysis was used to identify the theoretical probability distribution that best fitted the surface tension data, which predicted a γMin of 24·24 mN m(-1) . This was in agreement with predictions based on earlier work of published mixed bacterial spp. data, suggesting a fundamental limit to the ability of bacterial biosurfactants to reduce surface tensions in aqueous systems. This implies a biological restriction on the synthesis and export of these agents or a physical-chemical restriction on their functioning once produced. Numerous surveys of biosurfactant-producing bacteria have been conducted, but only recently has an attempt been made to predict the minimum liquid surface tension these surface-active agents can achieve. Here, we determine a theoretical minimum of 24 mN m(-1) by statistical analysis of tensiometry data, suggesting a fundamental limit for biosurfactant activity in bacterial cultures incubated under standard growth conditions. This raises a challenge to our understanding of biosurfactant expression, secretion and function, as well as

  10. Experimental and numerical investigation of liquid-metal free-surface flows in spallation targets

    Energy Technology Data Exchange (ETDEWEB)

    Batta, A., E-mail: batta@kit.edu [Karlsruhe Institute of Technology, Germany Hermann-von-Helmholtz-PLATZ 1, 76344 Eggenstein-Leopoldshafen (Germany); Class, A.G.; Litfin, K.; Wetzel, Th. [Karlsruhe Institute of Technology, Germany Hermann-von-Helmholtz-PLATZ 1, 76344 Eggenstein-Leopoldshafen (Germany); Moreau, V.; Massidda, L. [CRS4 Centre for Advanced Studies, Research and Development in Sardinia, Polaris, Edificio 1, 09010 Pula, CA (Italy); Thomas, S.; Lakehal, D. [ASCOMP GmbH Zurich, Zurich (Switzerland); Angeli, D.; Losi, G. [DIEF – Department of Engineering “Enzo Ferrari”, University of Modena and Reggio Emilia, via Vignolese 905, 41125 Modena (Italy); Mooney, K.G. [University of Massachusetts Amherst, Department of Mechanical and Industrial Engineering, Amherst (United States); Van Tichelen, K. [SCK-CEN, Belgian Nuclear Research Centre, Boeretang 200, 2400 Mol (Belgium)

    2015-08-15

    Highlights: • Experimental study of free surface for lead bismuth eutectic target. • Numerical investigation of free surface of a liquid metal target. • Advanced free surface modelling. - Abstract: Accelerator Driven Systems (ADS) are extensively investigated for the transmutation of high-level nuclear waste within many worldwide research programs. The first advanced design of an ADS system is currently developed in SCK• CEN, Mol, Belgium: the Multi-purpose hYbrid Research Reactor for High-tech Applications (MYRRHA). Many European research programs support the design of MYRRHA. In the framework of the Euratom project ‘Thermal Hydraulics of Innovative nuclear Systems (THINS)’ a liquid-metal free-surface experiment is performed at the Karlsruhe Liquid Metal Laboratory (KALLA) of Karlsruhe Institute of Technology (KIT). The experiment investigates a full-scale model of the concentric free-surface spallation target of MYRRHA using Lead Bismuth Eutectic (LBE) as coolant. In parallel, numerical free surface models are developed and tested which are reviewed in the article. A volume-of-fluid method, a moving mesh model, a free surface model combining the Level-Set method with Large-Eddy Simulation model and a smoothed-particle hydrodynamics approach are investigated. Verification of the tested models is based on the experimental results obtained within the THINS project and on previous water experiments performed at the University Catholic de Louvain (UCL) within the Euratom project ‘EUROpean Research Programme for the TRANSmutation of High Level Nuclear Waste in Accelerator Driven System (EUROTRANS)’. The design of the target enables a high fluid velocity and a stable surface at the beam entry. The purpose of this paper is to present an overview of both experimental and numerical results obtained for free surface target characterization. Without entering in technical details, the status, the major achievements and lessons for the future with respect to

  11. Liquid Hydrogen Propellant Tank Sub-Surface Pressurization with Gaseous Helium

    Science.gov (United States)

    Stephens, J. R.; Cartagena, W.

    2015-01-01

    A series of tests were conducted to evaluate the performance of a propellant tank pressurization system with the pressurant diffuser intentionally submerged beneath the surface of the liquid. Propellant tanks and pressurization systems are typically designed with the diffuser positioned to apply pressurant gas directly into the tank ullage space when the liquid propellant is settled. Space vehicles, and potentially propellant depots, may need to conduct tank pressurization operations in micro-gravity environments where the exact location of the liquid relative to the diffuser is not well understood. If the diffuser is positioned to supply pressurant gas directly to the tank ullage space when the propellant is settled, then it may become partially or completely submerged when the liquid becomes unsettled in a microgravity environment. In such case, the pressurization system performance will be adversely affected requiring additional pressurant mass and longer pressurization times. This series of tests compares and evaluates pressurization system performance using the conventional method of supplying pressurant gas directly to the propellant tank ullage, and then supplying pressurant gas beneath the liquid surface. The pressurization tests were conducted on the Engineering Development Unit (EDU) located at Test Stand 300 at NASA Marshall Space Flight Center (MSFC). EDU is a ground based Cryogenic Fluid Management (CFM) test article supported by Glenn Research Center (GRC) and MSFC. A 150 ft3 propellant tank was filled with liquid hydrogen (LH2). The pressurization system used regulated ambient helium (GHe) as a pressurant, a variable position valve to maintain flow rate, and two identical independent pressurant diffusers. The ullage diffuser was located in the forward end of the tank and was completely exposed to the tank ullage. The submerged diffuser was located in the aft end of the tank and was completely submerged when the tank liquid level was 10% or greater

  12. Quantum calculations of the IR spectrum of liquid water using ab initio and model potential and dipole moment surfaces and comparison with experiment

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Hanchao; Wang, Yimin; Bowman, Joel M. [Cherry L. Emerson Center for Scientific Computation and Department of Chemistry, Emory University, Atlanta, Georgia 30322 (United States)

    2015-05-21

    The calculation and characterization of the IR spectrum of liquid water have remained a challenge for theory. In this paper, we address this challenge using a combination of ab initio approaches, namely, a quantum treatment of IR spectrum using the ab initio WHBB water potential energy surface and a refined ab initio dipole moment surface. The quantum treatment is based on the embedded local monomer method, in which the three intramolecular modes of each embedded H{sub 2}O monomer are fully coupled and also coupled singly to each of six intermolecular modes. The new dipole moment surface consists of a previous spectroscopically accurate 1-body dipole moment surface and a newly fitted ab initio intrinsic 2-body dipole moment. A detailed analysis of the new dipole moment surface in terms of the coordinate dependence of the effective atomic charges is done along with tests of it for the water dimer and prism hexamer double-harmonic spectra against direct ab initio calculations. The liquid configurations are taken from previous molecular dynamics calculations of Skinner and co-workers, using the TIP4P plus E3B rigid monomer water potential. The IR spectrum of water at 300 K in the range of 0–4000 cm{sup −1} is calculated and compared with experiment, using the ab initio WHBB potential and new ab initio dipole moment, the q-TIP4P/F potential, which has a fixed-charged description of the dipole moment, and the TTM3-F potential and dipole moment surfaces. The newly calculated ab initio spectrum is in very good agreement with experiment throughout the above spectral range, both in band positions and intensities. This contrasts to results with the other potentials and dipole moments, especially the fixed-charge q-TIP4P/F model, which gives unrealistic intensities. The calculated ab initio spectrum is analyzed by examining the contribution of various transitions to each band.

  13. Quantum calculations of the IR spectrum of liquid water using ab initio and model potential and dipole moment surfaces and comparison with experiment

    International Nuclear Information System (INIS)

    Liu, Hanchao; Wang, Yimin; Bowman, Joel M.

    2015-01-01

    The calculation and characterization of the IR spectrum of liquid water have remained a challenge for theory. In this paper, we address this challenge using a combination of ab initio approaches, namely, a quantum treatment of IR spectrum using the ab initio WHBB water potential energy surface and a refined ab initio dipole moment surface. The quantum treatment is based on the embedded local monomer method, in which the three intramolecular modes of each embedded H 2 O monomer are fully coupled and also coupled singly to each of six intermolecular modes. The new dipole moment surface consists of a previous spectroscopically accurate 1-body dipole moment surface and a newly fitted ab initio intrinsic 2-body dipole moment. A detailed analysis of the new dipole moment surface in terms of the coordinate dependence of the effective atomic charges is done along with tests of it for the water dimer and prism hexamer double-harmonic spectra against direct ab initio calculations. The liquid configurations are taken from previous molecular dynamics calculations of Skinner and co-workers, using the TIP4P plus E3B rigid monomer water potential. The IR spectrum of water at 300 K in the range of 0–4000 cm −1 is calculated and compared with experiment, using the ab initio WHBB potential and new ab initio dipole moment, the q-TIP4P/F potential, which has a fixed-charged description of the dipole moment, and the TTM3-F potential and dipole moment surfaces. The newly calculated ab initio spectrum is in very good agreement with experiment throughout the above spectral range, both in band positions and intensities. This contrasts to results with the other potentials and dipole moments, especially the fixed-charge q-TIP4P/F model, which gives unrealistic intensities. The calculated ab initio spectrum is analyzed by examining the contribution of various transitions to each band

  14. Pressure and surface tension of solid-liquid interface using Tara zona density functional theory

    International Nuclear Information System (INIS)

    Moradi, M.; Kavosh Tehrani, M.

    2001-01-01

    The weighted density functional theory proposed by Tara zona is applied to study the solid-liquid interface. In the last two decades the weighted density functional became a useful tool to consider the properties of inhomogeneous liquids. In this theory, the role of the size of molecules or the particles of which the matter is composed, was found to be important. In this research we study a hard sphere fluid beside a hard wall. For this study the liquid is an inhomogeneous system. We use the definition of the direct correlation function as a second derivative of free energy with respect to the density. We use this definition and the definition of the weighting function, then we minimize the grand potential with respect to the density to get the Euler Lagrange equation and we obtain an integral equation to find the inhomogeneous density profile. The obtained density profile as a function of the distance from the wall, for different bulk density is pitted in three dimensions. We also calculate the pressure and compare it with the Carnahan-Starling results, and finally we obtained the surface tension at liquid-solid interface and compared it with the results of Monte Carlo simulation

  15. Pressure and surface tension of soild-liquid interface using Tarazona density functional theory

    Directory of Open Access Journals (Sweden)

    M. M.

    2000-12-01

    Full Text Available   The weighted density functional theory proposed by Tarazona is applied to study the solid-liquid interface. In the last two decades the weighted density functional became a useful tool to consider the properties of inhomogeneous liquids. In this theory, the role of the size of molecules or the particles of which the matter is composed, was found to be important. In this resarch we study a hard sphere fluid beside a hard wall. For this study the liquid is an inhomogeneous system. We use the definition of the direct correlation function as a second derivative of free energy with respect to the density. We use this definition and the definition of the weighting function, then we minimize the grand potential with respect to the density to get the Euler Lagrange equation and we obtain an integral equation to find the inhomogeneous density profile. The obtained density profile as a function of the distance from the wall, for different bulk density is plotted in three dimensions. We also calculate the pressure and compare it with the Carnahan-starling results, and finally we obtained the surface tension at liquid-solid interface and compared it with the results of Monte Carlo simulation.

  16. A variational model of disjoining pressure: Liquid film on a nonplanar surface

    Energy Technology Data Exchange (ETDEWEB)

    Silin, D.; Virnovsky, G.

    2009-06-01

    Variational methods have been successfully used in modelling thin liquid films in numerous theoretical studies of wettability. In this paper, the variational model of the disjoining pressure is extended to the general case of a two-dimensional solid surface. The Helmgoltz free energy functional depends both on the disjoining pressure isotherm and the shape of the solid surface. The augmented Young-Laplace equation (AYLE) is a nonlinear second-order partial differential equation. A number of solutions describing wetting films on spherical grains have been obtained. In the case of cylindrical films, the phase portrait technique describes the entire variety of mathematically feasible solutions. It turns out that a periodic solution, which would describe wave-like wetting films, does not satisfy the Jacobi's condition of the classical calculus of variations. Therefore, such a solution is nonphysical. The roughness of the solid surface significantly affects liquid film stability. AYLE solutions suggest that film rupture is more likely at a location where the pore-wall surface is most exposed into the pore space and the curvature is positive.

  17. Thermally induced delay and reversal of liquid film dewetting on chemically patterned surfaces.

    Science.gov (United States)

    Kalpathy, Sreeram K; Francis, Lorraine F; Kumar, Satish

    2013-10-15

    A thin liquid film resting on a solid substrate that is heated or cooled from below experiences surface tension gradients, which lead to Marangoni flows. We explore the behavior of such a film on a chemically patterned substrate which drives film dewetting in order to determine how surface patterning and applied temperature gradients can be designed to influence the behavior of thin-film coatings. A nonlinear partial differential equation for the film height based on lubrication theory is solved numerically for a broad range of problem parameters. Uniform cooling of the substrate is found to significantly delay dewetting that is driven by wettability gradients. Uniform heating speeds up dewetting but can destroy the near-perfect templating imposed by the surface patterning. However, localized heating and cooling together can accelerate dewetting while maintaining templating quality. Localized heating and cooling can also be used to drive liquid onto areas that it would dewet from in the absence of heating. Overall, these results indicate that applied temperature gradients can significantly influence dewetting driven by surface patterning, and suggest strategies for the creation of spatially patterned thin-film coatings and flow control in microfluidic devices. Copyright © 2013 Elsevier Inc. All rights reserved.

  18. Inactivation of Burkholderia pseudomallei on environmental surfaces using spray-applied, common liquid disinfectants.

    Science.gov (United States)

    Calfee, M W; Wendling, M

    2015-11-01

    Five commercially available liquid antimicrobials were evaluated for their ability to decontaminate common environmental surface materials, contaminated with Burkholderia pseudomallei, using a spray-based disinfectant delivery procedure. Tests were conducted at both an ambient temperature (c. 20°C) and a lower temperature (c. 12°C) condition. Nonporous materials (glass and aluminium) were more easily decontaminated than porous materials (wood, concrete and carpet). Citric acid (1%) demonstrated poor efficacy in all test conditions. Bleach (pH-adjusted), ethanol (70%), quaternary ammonium and PineSol®, demonstrated high (>6 log10 reduction) efficacies on glass and aluminium at both temperatures, but achieved varying results for wood, carpet and concrete. Temperature had minimal effect on decontamination efficacy during these tests. Much of the antimicrobial efficacy data for pathogenic micro-organisms are generated with testing that utilizes hard nonporous surface materials. These data are not directly translatable for decontaminant selection following an incident whereby complex and porous environmental surfaces are contaminated. This study presents efficacy data for spray-applied antimicrobial liquids, when used to decontaminate common environmental surfaces contaminated with Burkholderia pseudomallei. These data can help responders develop effective remediation strategies following an environmental contamination incident involving B. pseudomallei. Published 2015. This article is a U.S. Government work and is in the public domain in the USA.

  19. Preparation of polymer monolithic column functionalized by arsonic acid groups for mixed-mode capillary liquid chromatography.

    Science.gov (United States)

    Qin, Zhang-Na; Yu, Qiong-Wei; Wang, Ren-Qi; Feng, Yu-Qi

    2018-04-27

    A mixed-mode polymer monolithic column functionalized by arsonic acid groups was prepared by single-step in situ copolymerization of monomers p-methacryloylaminophenylarsonic acid (p-MAPHA) and pentaerythritol triacrylate (PETA). The prepared poly(p-MAPHA-co-PETA) monolithic column has a homogeneous monolithic structure with good permeability and mechanical stability. Zeta potential measurements reveal that the monolithic stationary phase holds a negative surface charge when the mobile phase resides in the pH range of 3.0-8.0. The retention mechanisms of prepared monolithic column are explored by the separation of selected polycyclic aromatic hydrocarbons (PAHs), nucleosides, and three basic compounds. The results indicate that the column functions in three different separation modes associated with reversed-phase chromatography based on hydrophobic interaction, hydrophilic interaction chromatography, and cation-exchange chromatography. The column efficiency of prepared monolithic column is estimated to be 70,000 and 76,000 theoretical plates/m for thiourea and naphthalene, respectively, at a linear flow velocity of 0.85 mm/s using acetonitrile/H 2 O (85/15, v/v) as the mobile phase. Furthermore, an analysis of the retention factors obtained for the PAHs indicates that the prepared monolithic column exhibits good reproducibility with relative standard deviations of 2.9%, 4.0%, and 4.7% based on run-to-run injections, column-to-column preparation, and batch-to-batch preparation, respectively. Finally, we investigate the separation performance of the proposed monolithic column for select phenols, sulfonamides, nucleobases and nucleosides. Copyright © 2018 Elsevier B.V. All rights reserved.

  20. Multiple surface plasmon polaritons modes on thin silver film controlled by a two-dimensional lattice of silver nanodimers

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Ying; Jiang, Yongyuan, E-mail: jiangyy@hit.edu.cn [Harbin Institute of Technology, Department of Physics (China)

    2015-01-15

    We study the optical resonant spectrum of a two-dimensional periodic array of silver nanodimers on a thin silver film using multiple scattering formalism. The excited multiple plasmonic modes on two interfaces of the silver film reveal that the dispersion relationships of surface plasmon polaritons on metallic film are modified by doubly periodic lattice due to the fact that wave vectors matching conditions are satisfied. Moreover, we demonstrate that the plasmonic modes are directly controlled by the thickness of silver film, as well as the gap between nanodimer array and silver film. These effects provide novel high-efficient and steady way for excitation in future plasmonic nanodevices.

  1. Experimental Study of gas-liquid two-phase flow affected by wall surface wettability

    International Nuclear Information System (INIS)

    Takamasa, T.; Hazuku, T.; Hibiki, T.

    2008-01-01

    To evaluate the effect of wall surface wettability on the characteristics of upward gas-liquid two-phase flow in a vertical pipe, an experimental study was performed using three test pipes: an acrylic pipe, a hydrophilic pipe and a hydrophobic pipe. Basic flow characteristics such as flow patterns, pressure drop and void fraction were measured in these three pipes. In the hydrophilic pipe, a slug to churn flow transition boundary was shifted to a higher gas velocity at a given liquid velocity, whereas a churn to annular flow transition boundary was shifted to a lower gas velocity at a given liquid velocity. In the hydrophobic pipe, an inverted-churn flow regime was observed in the region where the churn flow regime was observed in the acrylic pipe, while a droplet flow regime was observed in the region where an annular flow regime was observed in the acrylic pipe. At a high gas flow rate, the mean void fraction in the hydrophobic pipe was higher than in the acrylic pipe. The effect of surface wettability on frictional pressure loss was confirmed to be insignificant under the present experimental conditions

  2. Spherical Torus Plasma Interactions with Large-area Liquid Lithium Surfaces in CDX-U

    International Nuclear Information System (INIS)

    Kaita, R.; Majeski, R.; Boaz, M.; Efthimion, P.; Jones, B.; Hoffman, D.; Kugel, H.; Menard, J.; Munsat, T.; Post-Zwicker, A.; Soukhanovskii, V.; Spaleta, J.; Taylor, G.; Timberlake, J.; Woolley, R.; Zakharov, L.; Finkenthal, M.; Stutman, D.; Antar, G.; Doerner, R.; Luckhardt, S.; Maingi, R.; Maiorano, M.; Smith, S.

    2002-01-01

    The Current Drive Experiment-Upgrade (CDX-U) device at the Princeton Plasma Physics Laboratory (PPPL) is a spherical torus (ST) dedicated to the exploration of liquid lithium as a potential solution to reactor first-wall problems such as heat load and erosion, neutron damage and activation, and tritium inventory and breeding. Initial lithium limiter experiments were conducted with a toroidally-local liquid lithium rail limiter (L3) from the University of California at San Diego. Spectroscopic measurements showed a clear reduction of impurities in plasmas with the L3, compared to discharges with a boron carbide limiter. The evidence for a reduction in recycling was less apparent, however. This may be attributable to the relatively small area in contact with the plasma, and the presence of high-recycling surfaces elsewhere in the vacuum chamber. This conclusion was tested in subsequent experiments with a fully toroidal lithium limiter that was installed above the floor of the vacuum vessel. The new limiter covered over ten times the area of the L3 facing the plasma. Experiments with the toroidal lithium limiter have recently begun. This paper describes the conditioning required to prepare the lithium surface for plasma operations, and effect of the toroidal liquid lithium limiter on discharge performance

  3. Spherical Torus Plasma Interactions with Large-area Liquid Lithium Surfaces in CDX-U

    Energy Technology Data Exchange (ETDEWEB)

    R. Kaita; R. Majeski; M. Boaz; P. Efthimion; B. Jones; D. Hoffman; H. Kugel; J. Menard; T. Munsat; A. Post-Zwicker; V. Soukhanovskii; J. Spaleta; G. Taylor; J. Timberlake; R. Woolley; L. Zakharov; M. Finkenthal; D. Stutman; G. Antar; R. Doerner; S. Luckhardt; R. Maingi; M. Maiorano; S. Smith

    2002-01-18

    The Current Drive Experiment-Upgrade (CDX-U) device at the Princeton Plasma Physics Laboratory (PPPL) is a spherical torus (ST) dedicated to the exploration of liquid lithium as a potential solution to reactor first-wall problems such as heat load and erosion, neutron damage and activation, and tritium inventory and breeding. Initial lithium limiter experiments were conducted with a toroidally-local liquid lithium rail limiter (L3) from the University of California at San Diego. Spectroscopic measurements showed a clear reduction of impurities in plasmas with the L3, compared to discharges with a boron carbide limiter. The evidence for a reduction in recycling was less apparent, however. This may be attributable to the relatively small area in contact with the plasma, and the presence of high-recycling surfaces elsewhere in the vacuum chamber. This conclusion was tested in subsequent experiments with a fully toroidal lithium limiter that was installed above the floor of the vacuum vessel. The new limiter covered over ten times the area of the L3 facing the plasma. Experiments with the toroidal lithium limiter have recently begun. This paper describes the conditioning required to prepare the lithium surface for plasma operations, and effect of the toroidal liquid lithium limiter on discharge performance.

  4. Evaluation on Dorsey Method in Surface Tension Measurement of Solder Liquids Containing Surfactants

    Science.gov (United States)

    Zhao, Xingke; Xie, Feiming; Fan, Jinsheng; Liu, Dayong; Huang, Jihua; Chen, Shuhai

    2018-06-01

    With the purpose of developing a feasible approach for measuring the surface tension of solders containing surfactants, the surface tension of Sn-3Ag-0.5Cu-xP solder alloys, with various drop sizes as well as different phosphorus (P) content, was evaluated using the Dorsey method based on the sessile drop test. The results show that the accuracy of the surface tension calculations depends on both of sessile drop size and the liquid metal composition. With a proper drop size, in the range of 4.5 mm to 5.3 mm in equivalent spherical diameters, the deviation of the surface tension calculation can be limited to 1.43 mN·m-1 and 6.30 mN·m-1 for SnAgCu and SnAgCu-P, respectively. The surface tension of SnAgCu-xP solder alloys decreases quickly to a minimum value when the P content reaches 0.5 wt% and subsequently increases slowly with the P content further increasing. The formation of a P-enriched surface layer and Sn4P3 intermetallic phases is regarded to be responsible for the decreasing and subsequent increasing of surface tension, respectively.

  5. Efficacy of liquid and foam decontamination technologies for chemical warfare agents on indoor surfaces.

    Science.gov (United States)

    Love, Adam H; Bailey, Christopher G; Hanna, M Leslie; Hok, Saphon; Vu, Alex K; Reutter, Dennis J; Raber, Ellen

    2011-11-30

    Bench-scale testing was used to evaluate the efficacy of four decontamination formulations on typical indoor surfaces following exposure to the liquid chemical warfare agents sarin (GB), soman (GD), sulfur mustard (HD), and VX. Residual surface contamination on coupons was periodically measured for up to 24h after applying one of four selected decontamination technologies [0.5% bleach solution with trisodium phosphate, Allen Vanguard Surface Decontamination Foam (SDF™), U.S. military Decon Green™, and Modec Inc. and EnviroFoam Technologies Sandia Decontamination Foam (DF-200)]. All decontamination technologies tested, except for the bleach solution, performed well on nonporous and nonpermeable glass and stainless-steel surfaces. However, chemical agent residual contamination typically remained on porous and permeable surfaces, especially for the more persistent agents, HD and VX. Solvent-based Decon Green™ performed better than aqueous-based bleach or foams on polymeric surfaces, possibly because the solvent is able to penetrate the polymer matrix. Bleach and foams out-performed Decon Green for penetrating the highly polar concrete surface. Results suggest that the different characteristics needed for an ideal and universal decontamination technology may be incompatible in a single formulation and a strategy for decontaminating a complex facility will require a range of technologies. Copyright © 2011 Elsevier B.V. All rights reserved.

  6. Smooth perfluorinated surfaces with different chemical and physical natures: their unusual dynamic dewetting behavior toward polar and nonpolar liquids.

    Science.gov (United States)

    Cheng, Dalton F; Masheder, Benjamin; Urata, Chihiro; Hozumi, Atsushi

    2013-09-10

    The effects of surface chemistry and the mobility of surface-tethered functional groups of various perfluorinated surfaces on their dewetting behavior toward polar (water) and nonpolar (n-hexadecane, n-dodecane, and n-decane) liquids were investigated. In this study, three types of common smooth perfluorinated surfaces, that is, a perfluoroalkylsilane (heptadecafluoro-1,1,2,2-tetrahydrooctyl-dimethylchlorosilane, FAS17) monomeric layer, an amorphous fluoropolymer film (Teflon AF 1600), and a perfluorinated polyether (PFPE)-terminated polymer brush film (Optool DSX), were prepared and their static/dynamic dewetting characteristics were compared. Although the apparent static contact angles (CAs) of these surfaces with all probe liquids were almost identical to each other, the ease of movement of liquid drops critically depended on the physical (solidlike or liquidlike) natures of the substrate surface. CA hysteresis and substrate tilt angles (TAs) of all probe liquids on the Optool DSX surface were found to be much lower than those of Teflon AF1600 and FAS17 surfaces due to its physical polymer chain mobility at room temperature and the resulting liquidlike nature. Only 6.0° of substrate incline was required to initiate movement for a small drop (5 μL) of n-decane, which was comparable to the reported substrate TA value (5.3°) for a superoleophobic surface (θ(S) > 160°, textured perfluorinated surface). Such unusual dynamic dewetting behavior of the Optool DSX surface was also markedly enhanced due to the significant increase in the chain mobility of PFPE by moderate heating (70 °C) of the surface, with substrate TA reducing to 3.0°. CA hysteresis and substrate TAs rather than static CAs were therefore determined to be of greater consequence for the estimation of the actual dynamic dewetting behavior of alkane probe liquids on these smooth perfluorinated surfaces. Their dynamic dewettability toward alkane liquids is in the order of Optool DSX > Teflon AF1600

  7. Vapor-Liquid-Solid Etch of Semiconductor Surface Channels by Running Gold Nanodroplets.

    Science.gov (United States)

    Nikoobakht, Babak; Herzing, Andrew; Muramoto, Shin; Tersoff, Jerry

    2015-12-09

    We show that Au nanoparticles spontaneously move across the (001) surface of InP, InAs, and GaP when heated in the presence of water vapor. As they move, the particles etch crystallographically aligned grooves into the surface. We show that this process is a negative analogue of the vapor-liquid-solid (VLS) growth of semiconductor nanowires: the semiconductor dissolves into the catalyst and reacts with water vapor at the catalyst surface to create volatile oxides, depleting the dissolved cations and anions and thus sustaining the dissolution process. This VLS etching process provides a new tool for directed assembly of structures with sublithographic dimensions, as small as a few nanometers in diameter. Au particles above 100 nm in size do not exhibit this process but remain stationary, with oxide accumulating around the particles.

  8. What happens when iron becomes wet? Observation of reactions at interfaces between liquid and metal surfaces

    CERN Document Server

    Kimura, M

    2003-01-01

    Synchrotron-radiation has been applied to investigation of interfaces between liquid and metal surfaces, with a special attention to corrosion. Three topics are shown: (1) nano structures of rusts formed on steel after atmospheric corrosion. Evolution of 'Fe(O, OH) sub 6 network' is the key to understand how the durable rusts prevent from formation of more rusts. (2) In situ observation of reactions at the interface has been carried out for localized corrosion of stainless steel. It is shown that change in states of Cr sup 3 sup + and Br sup - ions near the interface is deeply related with a breakout of the passivation film. (3) A structural phase transformation on a Cu sub 3 Au(001) surface was investigated. Ordering remains even at a temperature higher than the bulk-critical temperature, showing surface-induced ordering. These approaches gives us crucial information for a new steel-product. (author)

  9. Noncontact surface tension and viscosity measurements of rhenium in the liquid and undercooled states

    International Nuclear Information System (INIS)

    Ishikawa, Takehiko; Paradis, Paul-Francois; Yoda, Shinichi

    2004-01-01

    Surface tension and viscosity of liquid rhenium, which have hardly been measured due to the extremely high melting temperature of rhenium, were measured using an electrostatic levitation method combined with the oscillation drop technique. Sample position instability problems caused by the photon pressure of the heating lasers and by sample evaporation were solved by modifying the electrodes design. Good sample stability allowed the measurements of the surface tension and the viscosity over wide temperature ranges including the undercooled states. Over the 2800-3600 K interval, the surface tension of rhenium was measured as σ(T)=2.71x10 3 -0.23(T-T m ), where T m is the melting temperature, 3453 K. At T m , the datum agrees well with the literature values. Similarly, on the same temperature range, the viscosity was determined as η(T)=0.08 exp[1.33x10 5 /(RT)] (mPa s)

  10. Bulk and surface properties of liquid Al-Cr and Cr-Ni alloys

    International Nuclear Information System (INIS)

    Novakovic, R

    2011-01-01

    The energetics of mixing and structural arrangement in liquid Al-Cr and Cr-Ni alloys has been analysed through the study of surface properties (surface tension and surface segregation), dynamic properties (chemical diffusion) and microscopic functions (concentration fluctuations in the long-wavelength limit and chemical short-range order parameter) in the framework of statistical mechanical theory in conjunction with quasi-lattice theory. The Al-Cr phase diagram exhibits the existence of different intermetallic compounds in the solid state, while that of Cr-Ni is a simple eutectic-type phase diagram at high temperatures and includes the low-temperature peritectoid reaction in the range near a CrNi 2 composition. Accordingly, the mixing behaviour in Al-Cr and Cr-Ni alloy melts was studied using the complex formation model in the weak interaction approximation and by postulating Al 8 Cr 5 and CrNi 2 chemical complexes, respectively, as energetically favoured.

  11. Bulk and surface properties of liquid Al-Cr and Cr-Ni alloys.

    Science.gov (United States)

    Novakovic, R

    2011-06-15

    The energetics of mixing and structural arrangement in liquid Al-Cr and Cr-Ni alloys has been analysed through the study of surface properties (surface tension and surface segregation), dynamic properties (chemical diffusion) and microscopic functions (concentration fluctuations in the long-wavelength limit and chemical short-range order parameter) in the framework of statistical mechanical theory in conjunction with quasi-lattice theory. The Al-Cr phase diagram exhibits the existence of different intermetallic compounds in the solid state, while that of Cr-Ni is a simple eutectic-type phase diagram at high temperatures and includes the low-temperature peritectoid reaction in the range near a CrNi(2) composition. Accordingly, the mixing behaviour in Al-Cr and Cr-Ni alloy melts was studied using the complex formation model in the weak interaction approximation and by postulating Al(8)Cr(5) and CrNi(2) chemical complexes, respectively, as energetically favoured.

  12. Measurement of free-surface of liquid metal lithium jet for IFMIF target

    International Nuclear Information System (INIS)

    Hiroo Kondo; Nobuo Yamaoka; Takuji Kanemura; Seiji Miyamoto; Hiroshi Horiike; Mizuho Ida; Hiroo Nakamura; Izuru Matsushita; Takeo Muroga

    2006-01-01

    This reports an experimental study on flow characteristics of a lithium target flow of International Fusion Materials Irradiation Facility (IFMIF). Surface shapes of the target were tried to measure by pattern projection method that is a three dimensional image measurement method. Irregularity of the surface shape caused by surface wakes was successfully measured by the method. IFMIF liquid lithium target is formed a flat plane jet of 25 mm in depth and 260 mm in width, and flows in a flow velocity range of 10 to 20 m/s. Aim of this study is to develop measurement techniques for monitoring of the target when IFMIF is in operation. The lithium target flow is high speed jet and the temperature high is more than 500 K. Also, light is not transmitted into liquid metal lithium. Therefore, almost of all flow measurement techniques developed for water are not used for lithium flow. In this study, pattern projection method was employed to measure the surface irregularity of the target. In the method, stripe patterns are projected onto the flow surface. The projected patterns are deformed according the surface shape. Three-dimensional surface shape is measured by analyzing the deformed patterns recorded using a CCD camera. The method uses the property that lithium dose not transmit visible lights. The experiments were carried out using a lithium loop at Osaka University. In this facility, lithium plane jet of 10 mm in depth and 70 mm width is obtained in the velocity range of less than 15 m/s using a two contractions nozzle. The pattern projection method was used to measure the amplitude of surface irregularity caused by surface wakes. The surface wakes were generated from small damaged at the nozzle edge caused by erosion, and those were successfully measured by the method. The measurement results showed the amplitude of the surface wakes were approximately equal to a size of damage of a nozzle. The amplitude was decreasing with distance to down stream and with decreasing

  13. Theory of the surface-induced magnetism in liquid 3He

    International Nuclear Information System (INIS)

    Jichu, Hisao; Kuroda, Yoshihiro

    1982-01-01

    A theory of the surface-induced magnetism of liquid 3 He confined in a restricted geometry is presented. In a general model, three different types of contributions to the effective exchange interactions among spins of the 3 He atoms in a solid layer adsorbed on a substrate are distinguished on the basis of the second order perturbation theory; one is from a direct process and the others are mediated by the spins of the 3 He atoms in the remaining bulk liquid. By using a simplified model, the exchange constants are calculated to find that an RKKY-type indirect exchange interaction appears to be most dominant and to explain the observed ferromagnetic tendency. (author)

  14. High-resolution bistable nematic liquid crystal device realized on orientational surface patterns

    International Nuclear Information System (INIS)

    Kim, Jong-Hyun; Yoneya, Makoto; Yokoyama, Hiroshi

    2003-01-01

    The four-fold symmetry of a checkerboard-like surface alignment consisted of square domains arrived at the macroscopic orientational bistability of nematic liquid crystals. Switching between the two orientations took place with an appropriate electric field. Here the threshold field of bistable switching decreased as temperature increased, and the light could heat only the selected region in the cell including a light-absorbing medium. Irradiating the laser concurrently with an electric field, we addressed a selected region in the alignment pattern without the disturbance of neighboring regions. Extending this process, we realized an extremely fine bistable device of nematic liquid crystal with a pixel size down to about 2 μm

  15. Two-phase gas bubble-liquid boundary layer flow along vertical and inclined surfaces

    International Nuclear Information System (INIS)

    Cheung, F.B.; Epstein, M.

    1985-01-01

    The behavior of a two-phase gas bubble-liquid boundary layer along vertical and inclined porous surfaces with uniform gas injection is investigated experimentally and analytically. Using argon gas and water as the working fluids, a photographical study of the two-phase boundary layer flow has been performed for various angles of inclination ranging from 45 0 to 135 0 and gas injection rates ranging from 0.01 to 0.1 m/s. An integral method has been employed to solve the system of equations governing the two-phase motion. The effects of the gas injection rate and the angle of inclination on the growth of the boundary layer have been determined. The predicted boundary layer thickness is found to be in good agreement with the experimental results. The calculated axial liquid velocity and the void fraction in the two-phase region are also presented along with the observed flow behavior

  16. Theory and Modeling of Lasing Modes in Vertical Cavity Surface Emitting Lasers

    Directory of Open Access Journals (Sweden)

    Benjamin Klein

    1998-01-01

    modes that the VCSEL can support are then determined by matching the gain necessary for the optical system in both magnitude and phase to the gain available from the laser's electronic system. Examples are provided.

  17. Model-Based Resource and Mode Management for Lunar Surface Operations, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed project is aimed at developing a model based resource and mode management system for space robotics systems that will allow real time assessment of...

  18. Aerosol indirect effects on the nighttime Arctic Ocean surface from thin, predominantly liquid clouds

    Directory of Open Access Journals (Sweden)

    L. M. Zamora

    2017-06-01

    Full Text Available Aerosol indirect effects have potentially large impacts on the Arctic Ocean surface energy budget, but model estimates of regional-scale aerosol indirect effects are highly uncertain and poorly validated by observations. Here we demonstrate a new way to quantitatively estimate aerosol indirect effects on a regional scale from remote sensing observations. In this study, we focus on nighttime, optically thin, predominantly liquid clouds. The method is based on differences in cloud physical and microphysical characteristics in carefully selected clean, average, and aerosol-impacted conditions. The cloud subset of focus covers just ∼ 5 % of cloudy Arctic Ocean regions, warming the Arctic Ocean surface by ∼ 1–1.4 W m−2 regionally during polar night. However, within this cloud subset, aerosol and cloud conditions can be determined with high confidence using CALIPSO and CloudSat data and model output. This cloud subset is generally susceptible to aerosols, with a polar nighttime estimated maximum regionally integrated indirect cooling effect of ∼ −0.11 W m−2 at the Arctic sea ice surface (∼ 8 % of the clean background cloud effect, excluding cloud fraction changes. Aerosol presence is related to reduced precipitation, cloud thickness, and radar reflectivity, and in some cases, an increased likelihood of cloud presence in the liquid phase. These observations are inconsistent with a glaciation indirect effect and are consistent with either a deactivation effect or less-efficient secondary ice formation related to smaller liquid cloud droplets. However, this cloud subset shows large differences in surface and meteorological forcing in shallow and higher-altitude clouds and between sea ice and open-ocean regions. For example, optically thin, predominantly liquid clouds are much more likely to overlay another cloud over the open ocean, which may reduce aerosol indirect effects on the surface. Also, shallow clouds over

  19. Topological valley transport of plate-mode waves in a homogenous thin plate with periodic stubbed surface

    Directory of Open Access Journals (Sweden)

    Jiu-Jiu Chen

    2017-11-01

    Full Text Available The study for exotic topological effects of sound has attracted uprising interests in fundamental physics and practical applications. Based on the concept of valley pseudospin, we demonstrate the topological valley transport of plate-mode waves in a homogenous thin plate with periodic stubbed surface, where a deterministic two-fold Dirac degeneracy is form by two plate modes. We show that the topological property can be controlled by the height of stubs deposited on the plate. By adjusting the relative heights of adjacent stubs, the valley vortex chirality and band inversion are induced, giving rise to a phononic analog of valley Hall phase transition. We further numerically demonstrate the valley states of plate-mode waves with robust topological protection. Our results provide a new route to design unconventional elastic topological insulators and will significantly broaden its practical application in the engineering field.

  20. Alkyl chain interaction at the surface of room temperature ionic liquids: systematic variation of alkyl chain length (R = C(1)-C(4), C(8)) in both cation and anion of [RMIM][R-OSO(3)] by sum frequency generation and surface tension.

    Science.gov (United States)

    Santos, Cherry S; Baldelli, Steven

    2009-01-29

    The gas-liquid interface of halide-free 1,3-dialkylimidazolium alkyl sulfates [RMIM][R-OSO(3)] with R chain length from C(1)-C(4) and C(8) has been studied systematically using the surface-specific sum frequency generation (SFG) vibrational spectroscopy and surface tension measurements. From the SFG spectra, vibrational modes from the methyl group of both cation and anion are observed for all ionic liquid samples considered in the present study. These results suggest the presence of both ions at the gas-liquid interface, which is further supported by surface tension measurements. Surface tension data show a decreasing trend as the alkyl chain in the imidazolium cation is varied from methyl to butyl chain, with a specific anion. A similar trend is observed when the alkyl chain of the anion is modified and the cation is fixed.

  1. Individual and collective modes of surface magnetoplasmon in thiolate-protected silver nanoparticles studied by MCD spectroscopy

    Science.gov (United States)

    Yao, Hiroshi; Shiratsu, Taisuke

    2016-05-01

    Large magneto-optical (MO) responses at the energy of localized surface plasmon resonance (LSPR), namely, surface magnetoplasmons, are demonstrated for the first time in thiolate-protected silver nanoparticles with magnetic circular dichroism (MCD) spectroscopy. The samples examined are decanethiol (DT)-, azobenzenethiol (ABT)-, and ABT/DT mixed-monolayer-protected Ag nanoparticles. ABT-protected Ag nanoparticles are somewhat aggregated and thus exhibit a broad, collective mode of plasmonic absorption, whereas other samples with highly-dispersed nanoparticles show an individual mode of LSPR absorption. In all Ag nanoparticles, a derivative-like MCD signal is observed under an applied magnetic field of 1.6 T, which can be explained in terms of two circular modes of magnetoplasmon caused by the increase (or decrease) in the Lorentz force imparted on the free electrons that oscillate in the left (or right) circular orbits in the nanosphere. For the Ag nanoparticles exhibiting an individual LSPR mode, in particular, simultaneous deconvolution analysis of UV-vis absorption and MCD spectra reveal that (i) the amplitude of the magnetoplasmonic component with lower frequency (ω-), resulting from the reduction in the confinement strength of collective electrons by the Lorentz force, is stronger than that with a higher frequency (ω+) (ii) the accurate shift or cyclotron frequency between two magnetoplasmonic modes (ωc = ω+ - ω-) is size-dependent, and presents a very large value with implications for the apparent enhancement of the local magnetic-field in the Ag nanoparticles. These results strongly suggest that the Ag-thiolate layer or Ag-S bonding on the nanoparticle surface plays a significant role in the MO enhancement.Large magneto-optical (MO) responses at the energy of localized surface plasmon resonance (LSPR), namely, surface magnetoplasmons, are demonstrated for the first time in thiolate-protected silver nanoparticles with magnetic circular dichroism (MCD

  2. The effect of changing the contact surface area between pleural liquid and pleura on the turnover of pleural liquid.

    Science.gov (United States)

    Nakamura, T; Hara, H; Ijima, F; Arai, T; Kira, S

    1984-03-01

    To study the dynamics of pleural liquid, 250 ml of saline labeled with markers were injected into the pleural cavity of anesthetized dogs. For 3 h, liquid volume and concentration of these markers were measured. In a control group of dogs, the turnover rate of pleural liquid was 19.6 +/- 5.6 ml/min and lymphatic flow was 0.58 +/- 0.07 ml/min. In a group of pneumonectomized dogs, the turnover rate and lymphatic flow fell to about one fourth of those in the control group. When the left pulmonary artery was occluded, the turnover rate was halved, but lymphatic flow was not significantly different from that in the control group. These results suggest that the turnover rate of pleural liquid is dependent on the area of contact between pleural liquid and pleura and on the blood flow of the pleura. In addition, it appears that changes in pleural liquid volume are dependent on lymphatic flow.

  3. Evaluation and application of a mixed-mode chromatographic stationary phase in two-dimensional liquid chromatography for the separation of traditional Chinese medicine.

    Science.gov (United States)

    Wei, Zhishen; Fu, Qing; Cai, Jianfeng; Huan, Liyun; Zhao, Jianchao; Shi, Hui; Jin, Yu; Liang, Xinmiao

    2016-06-01

    In this study, two mixed-mode chromatography stationary phases (C8SAX and C8SCX) were evaluated and used to establish a two-dimensional liquid chromatography system for the separation of traditional Chinese medicine. The chromatographic properties of the mixed-mode columns were systematically evaluated by comparing with other three columns of C8, strong anion exchanger, and strong cation exchanger. The result showed that C8SAX and C8SCX had a mixed-mode retention mechanism including electrostatic interaction and hydrophobic interaction. Especially, they were suitable for separating acidic and/or basic compounds and their separation selectivities could be easily adjusted by changing pH value. Then, several off-line 2D-LC systems based on the C8SAX in the first dimension and C8SAX, C8SCX, or C8 columns in the second dimension were developed to analyze a traditional Chinese medicine-Uncaria rhynchophylla. The two-dimensional liquid chromatography system of C8SAX (pH 3.0) × C8SAX (pH 6.0) exhibited the most effective peak distribution. Finally, fractions of U. rhynchophylla prepared from the first dimension were successfully separated on the C8SAX column with a gradient pH. Thus, the mixed-mode stationary phase could provide a platform to separate the traditional Chinese medicine in practical applications. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Inhibition of ice nucleation by slippery liquid-infused porous surfaces (SLIPS).

    Science.gov (United States)

    Wilson, Peter W; Lu, Weizhe; Xu, Haojun; Kim, Philseok; Kreder, Michael J; Alvarenga, Jack; Aizenberg, Joanna

    2013-01-14

    Ice repellent coatings have been studied and keenly sought after for many years, where any advances in the durability of such coatings will result in huge energy savings across many fields. Progress in creating anti-ice and anti-frost surfaces has been particularly rapid since the discovery and development of slippery, liquid infused porous surfaces (SLIPS). Here we use SLIPS-coated differential scanning calorimeter (DSC) pans to investigate the effects of the surface modification on the nucleation of supercooled water. This investigation is inherently different from previous studies which looked at the adhesion of ice to SLIPS surfaces, or the formation of ice under high humidity conditions. Given the stochastic nature of nucleation of ice from supercooled water, multiple runs on the same sample are needed to determine if a given surface coating has a real and statistically significant effect on the nucleation temperature. We have cycled supercooling to freezing and then thawing of deionized water in hydrophilic (untreated aluminum), hydrophobic, superhydrophobic, and SLIPS-treated DSC pans multiple times to determine the effects of surface treatment on the nucleation and subsequent growth of ice. We find that SLIPS coatings lower the nucleation temperature of supercooled water in contact with statistical significance and show no deterioration or change in the coating performance even after 150 freeze-thaw cycles.

  5. Pore and surface diffusion in multicomponent adsorption and liquid chromatography systems

    International Nuclear Information System (INIS)

    Ma, Z.; Whitley, R.D.; Wang, N.H.L.

    1996-01-01

    A generalized parallel pore and surface diffusion model for multicomponent adsorption and liquid chromatography is formulated and solved numerically. Analytical solution for first- and second-order central moments for a pulse on a plateau input is used as benchmarks for the numerical solutions. Theoretical predictions are compared with experimental data for two systems: ion-exchange of strontium, sodium, and calcium in a zeolite and competitive adsorption of two organics on activated carbon. In a linear isotherm region of single-component systems, both surface and pore diffusion cause symmetric spreading in breakthrough curves. In a highly nonlinear isotherm region, however, surface diffusion causes pronounced tailing in breakthrough curves; the larger the step change in concentration, the more pronounced tailing, in contrast to relatively symmetric breakthroughs due to pore diffusion. If only a single diffusion mechanism is assumed in analyzing the data of parallel diffusion systems, a concentration-dependent apparent surface diffusivity or pore diffusivity results; for a convex isotherm, the apparent surface diffusivity increases, whereas the apparent pore diffusivity decreases with increasing concentration. For a multicomponent nonlinear system, elution order can change if pore diffusion dominates for a low-affinity solute, whereas surface diffusion dominates for a high-affinity solute

  6. Contact-angle hysteresis on periodic microtextured surfaces: Strongly corrugated liquid interfaces.

    Science.gov (United States)

    Iliev, Stanimir; Pesheva, Nina

    2016-06-01

    We study numerically the shapes of a liquid meniscus in contact with ultrahydrophobic pillar surfaces in Cassie's wetting regime, when the surface is covered with identical and periodically distributed micropillars. Using the full capillary model we obtain the advancing and the receding equilibrium meniscus shapes when the cross-sections of the pillars are both of square and circular shapes, for a broad interval of pillar concentrations. The bending of the liquid interface in the area between the pillars is studied in the framework of the full capillary model and compared to the results of the heterogeneous approximation model. The contact angle hysteresis is obtained when the three-phase contact line is located on one row (block case) or several rows (kink case) of pillars. It is found that the contact angle hysteresis is proportional to the line fraction of the contact line on pillars tops in the block case and to the surface fraction for pillar concentrations 0.1-0.5 in the kink case. The contact angle hysteresis does not depend on the shape (circular or square) of the pillars cross-section. The expression for the proportionality of the receding contact angle to the line fraction [Raj et al., Langmuir 28, 15777 (2012)LANGD50743-746310.1021/la303070s] in the case of block depinning is theoretically substantiated through the capillary force, acting on the solid plate at the meniscus contact line.

  7. Effect of liquid surface tension on circular and linear hydraulic jumps; theory and experiments

    Science.gov (United States)

    Bhagat, Rajesh Kumar; Jha, Narsing Kumar; Linden, Paul F.; Wilson, David Ian

    2017-11-01

    The hydraulic jump has attracted considerable attention since Rayleigh published his account in 1914. Watson (1964) proposed the first satisfactory explanation of the circular hydraulic jump by balancing the momentum and hydrostatic pressure across the jump, but this solution did not explain what actually causes the jump to form. Bohr et al. (1992) showed that the hydraulic jump happens close to the point where the local Froude number equals to one, suggesting a balance between inertial and hydrostatic contributions. Bush & Aristoff (2003) subsequently incorporated the effect of surface tension and showed that this is important when the jump radius is small. In this study, we propose a new account to explain the formation and evolution of hydraulic jumps under conditions where the jump radius is strongly influenced by the liquid surface tension. The theory is compared with experiments employing liquids of different surface tension and different viscosity, in circular and linear configurations. The model predictions and the experimental results show excellent agreement. Commonwealth Scholarship Commission, St. John's college, University of Cambridge.

  8. Measurement and modeling of surface temperature dynamics of the NSTX liquid lithium divertor

    Energy Technology Data Exchange (ETDEWEB)

    McLean, A.G., E-mail: mclean@fusion.gat.com [Lawrence Livermore National Laboratory, Livermore, CA 94551 (United States); Gan, K.F. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei (China); Ahn, J.-W.; Gray, T.K.; Maingi, R. [Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Abrams, T.; Jaworski, M.A.; Kaita, R.; Kugel, H.W. [Princeton Plasma Physics Laboratory, Princeton, NJ 08543 (United States); Nygren, R.E. [Sandia National Laboratories, Albuquerque, NM 87185 (United States); Skinner, C.H. [Princeton Plasma Physics Laboratory, Princeton, NJ 08543 (United States); Soukhanovskii, V.A. [Lawrence Livermore National Laboratory, Livermore, CA 94551 (United States)

    2013-07-15

    Dual-band infrared (IR) measurements of the National Spherical Torus eXperiment (NSTX) Liquid Lithium Divertor (LLD) are reported that demonstrate liquid Li is more effective at removing plasma heat flux than Li-conditioned graphite. Extended dwell of the outer strike point (OSP) on the LLD caused an incrementally larger area to be heated above the Li melting point through the discharge leading to enhanced D retention and plasma confinement. Measurement of T{sub surface} near the OSP demonstrates a significant reduction of the LLD surface temperature compared to that of Li-coated graphite at the same major radius. Modeling of these data with a 2-D simulation of the LLD structure in the DFLUX code suggests that the structure of the LLD was successful at handling up to q{sub ⊥,peak} = 5 MW/m{sup 2} inter-ELM and up to 10 MW/m{sup 2} during ELMs from its plasma-facing surface as intended, and provide an innovative method for inferring the Li layer thickness.

  9. Electric field stabilization of viscous liquid layers coating the underside of a surface

    Science.gov (United States)

    Anderson, Thomas G.; Cimpeanu, Radu; Papageorgiou, Demetrios T.; Petropoulos, Peter G.

    2017-05-01

    We investigate the electrostatic stabilization of a viscous thin film wetting the underside of a horizontal surface in the presence of an electric field applied parallel to the surface. The model includes the effect of bounding solid dielectric regions above and below the liquid-air system that are typically found in experiments. The competition between gravitational forces, surface tension, and the nonlocal effect of the applied electric field is captured analytically in the form of a nonlinear evolution equation. A semispectral solution strategy is employed to resolve the dynamics of the resulting partial differential equation. Furthermore, we conduct direct numerical simulations (DNS) of the Navier-Stokes equations using the volume-of-fluid methodology and assess the accuracy of the obtained solutions in the long-wave (thin-film) regime when varying the electric field strength from zero up to the point when complete stabilization occurs. We employ DNS to examine the limitations of the asymptotically derived behavior as the liquid layer thickness increases and find excellent agreement even beyond the regime of strict applicability of the asymptotic solution. Finally, the asymptotic and computational approaches are utilized to identify robust and efficient active control mechanisms allowing the manipulation of the fluid interface in light of engineering applications at small scales, such as mixing.

  10. Flow boiling heat transfer on nanowire-coated surfaces with highly wetting liquid

    International Nuclear Information System (INIS)

    Shin, Sangwoo; Choi, Geehong; Kim, Beom Seok; Cho, Hyung Hee

    2014-01-01

    Owing to the recent advances in nanotechnology, one significant progress in energy technology is increased cooling ability. It has recently been shown that nanowires can improve pool boiling heat transfer due to the unique features such as enhanced wetting and enlarged nucleation sites. Applying such nanowires on a flow boiling, which is another major class of boiling phenomenon that is associated with forced convection, is yet immature and scarce despite its importance in various applications such as liquid cooling of energy, electronics and refrigeration systems. Here, we investigate flow boiling heat transfer on surfaces that are coated with SiNWs (silicon nanowires). Also, we use highly-wetting dielectric liquid, FC-72, as a working fluid. An interesting wetting behavior is observed where the presence of SiNWs reduces wetting and wicking that in turn leads to significant decrease of CHF (critical heat flux) compared to the plain surface, which opposes the current consensus. Also, the effects of nanowire length and Reynolds number on the boiling heat transfer are shown to be highly nonmonotonic. We attempt to explain such an unusual behavior on the basis of wetting, nucleation and forced convection, and we show that such factors are highly coupled in a way that lead to unusual behavior. - Highlights: • Observation of suppressed wettability in the presence of surface roughness (nanowires). • Significant reduction of critical heat flux in the presence of nanowires. • Nonmonotonic behavior of heat transfer coefficient vs. nanowire length and Reynolds number

  11. Modeling Replenishment of Ultrathin Liquid Perfluoro polyether Z Films on Solid Surfaces Using Monte Carlo Simulation

    International Nuclear Information System (INIS)

    Mayeed, M.S.; Kato, T.

    2014-01-01

    Applying the reptation algorithm to a simplified perfluoro polyether Z off-lattice polymer model an NVT Monte Carlo simulation has been performed. Bulk condition has been simulated first to compare the average radius of gyration with the bulk experimental results. Then the model is tested for its ability to describe dynamics. After this, it is applied to observe the replenishment of nano scale ultrathin liquid films on solid flat carbon surfaces. The replenishment rate for trenches of different widths (8, 12, and 16 nms for several molecular weights) between two films of perfluoro polyether Z from the Monte Carlo simulation is compared to that obtained solving the diffusion equation using the experimental diffusion coefficients of Ma et al. (1999), with room condition in both cases. Replenishment per Monte Carlo cycle seems to be a constant multiple of replenishment per second at least up to 2 nm replenished film thickness of the trenches over the carbon surface. Considerable good agreement has been achieved here between the experimental results and the dynamics of molecules using reptation moves in the ultrathin liquid films on solid surfaces.

  12. Liquid extraction surface analysis (LESA) of food surfaces employing chip-based nano-electrospray mass spectrometry.

    Science.gov (United States)

    Eikel, Daniel; Henion, Jack

    2011-08-30

    An automated surface-sampling technique called liquid extraction surface analysis (LESA), coupled with infusion nano-electrospray high-resolution mass spectrometry and tandem mass spectrometry (MS/MS), is described and applied to the qualitative determination of surface chemical residues resulting from the artificial spraying of selected fresh fruits and vegetables with representative pesticides. Each of the targeted pesticides was readily detected with both high-resolution and full-scan collision-induced dissociation (CID) mass spectra. In the case of simazine and sevin, a mass resolution of 100,000 was insufficient to distinguish the isobaric protonated molecules for these compounds. When the surface of a spinach leaf was analyzed by LESA, trace levels of diazinon were readily detected on the spinach purchased directly from a supermarket before they were sprayed with the five-pesticide mixture. A 30 s rinse under hot running tap water appeared to quantitatively remove all remaining residues of this pesticide. Diazinon was readily detected by LESA analysis on the skin of the artificially sprayed spinach. Finally, incurred pyrimethanil at a level of 169 ppb in a batch slurry of homogenized apples was analyzed by LESA and this pesticide was readily detected by both high-resolution mass spectrometry and full-scan CID mass spectrometry, thus showing that pesticides may also be detected in whole fruit homogenized samples. This report shows that representative pesticides on fruit and vegetable surfaces present at levels 20-fold below generally allowed EPA tolerance levels are readily detected and confirmed by the title technologies making LESA-MS as interesting screening method for food safety purposes. Copyright © 2011 John Wiley & Sons, Ltd.

  13. Surface tensions of binary mixtures of ionic liquids with bis(trifluoromethylsulfonyl)imide as the common anion

    International Nuclear Information System (INIS)

    Oliveira, M.B.; Domínguez-Pérez, M.; Cabeza, O.; Lopes-da-Silva, J.A.; Freire, M.G.; Coutinho, J.A.P.

    2013-01-01

    Highlights: • Novel data for the surface tensions of mixtures [C 4 mim][NTf 2 ] + [C 4 C 1 mim]/[C 3 mpy]/[C 3 mpyr]/[C 3 mpip][NTf 2 ] are presented. • γ were determined at a fixed temperature, 298.2 K, and at atmospheric pressure, for the whole composition range. • Surface tension deviations showed the near ideal behavior of the selected mixtures. • Gibbs adsorption isotherms showed the surface preferential adsorption of one ionic liquid over the other. -- Abstract: While values for thermophysical properties of ionic liquids are becoming widely available, data for ionic liquid mixtures are still scarce. In an effort to overcome this limitation and understand the behavior of ionic liquid mixtures, novel data for the surface tension of mixtures composed of 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide, [C 4 mim][NTf 2 ], with other ionic liquids with a common anion, namely 1-butyl-2,3-dimethylimidazolium, [C 4 C 1 mim] + , 3-methyl-1-propylpyridinium, [C 3 mpy] + , 1-methyl-1-propylpyrrolidinium, [C 3 mpyr] + , and 1-methyl-1-propylpiperidinium, [C 3 mpip] + , were measured at T = 298.2 K and atmospheric pressure over the entire composition range. From the surface tension deviations derived from the experimental results, it was possible to infer that the cation alkyl chain length of the second ionic liquid constituting the mixture has a stronger influence in the ideal mixture behavior than the type of family the ionic liquid cation belongs to. The Gibbs adsorption isotherms, estimated from the experimental values, show that the composition of the vapor–liquid interface is not the same as that of the bulk and that the interface is richer in the ionic liquid with the lowest surface tension, [C 4 mim][NTf 2

  14. Effect of liquid environment on the titanium surface modification by laser ablation

    Energy Technology Data Exchange (ETDEWEB)

    Ali, Nisar, E-mail: chnisarali@gmail.com [Laser Laboratories, Institute for Applied Physics, Vienna University of Technology, 1040 Vienna (Austria); Department of Basic Science and Humanities, University of Engineering and Technology Lahore, Faisalabad Campus, Faisalabad (Pakistan); Laser Laboratories, Centre for Advanced Studies in Physics, GC University, 1-Church Road, Lahore (Pakistan); Department of Physics, GC University, Kachehri Road, Lahore (Pakistan); Bashir, Shazia [Laser Laboratories, Centre for Advanced Studies in Physics, GC University, 1-Church Road, Lahore (Pakistan); Umm-i-Kalsoom [Laser Laboratories, Institute for Applied Physics, Vienna University of Technology, 1040 Vienna (Austria); Laser Laboratories, Centre for Advanced Studies in Physics, GC University, 1-Church Road, Lahore (Pakistan); Department of Physics, GC University, Kachehri Road, Lahore (Pakistan); Department of Basic Science and Humanities, University of Engineering and Technology Lahore, Kala Shah Kaku Campus, Lahore (Pakistan); Begum, Narjis [Department of Physics, COMSATS Institute of Information Technology, Islamabad (Pakistan); Rafique, Muhammad Shahid [Department of Physics, University of Engineering and Technology Lahore (Pakistan); Husinsky, Wolfgang [Laser Laboratories, Institute for Applied Physics, Vienna University of Technology, 1040 Vienna (Austria)

    2017-05-31

    Highlights: • Liquid assisted ablation effects on the titanium under varying number of laser pulses is investigated. • SEM analysis reveals the growth of various features like ripples, dendritic structures, pores, grains and craters. • Raman and XRD analyses shows the presence of TiO{sub 2} & TiH in both media whereas, TiC, TiCxOy are only identified in propanol. • Hardness of ablated Ti explored by Nano indentation is found to decrease with increasing number of pulses in both media. • Relationship between surface, structural and mechanical modifications is established. - Abstract: The effect of liquid environment (de-ionized water and propanol) on surface, structural and mechanical properties of femtosecond laser ablated titanium has been investigated. For this purpose, Ti: sapphire laser (800 nm, 30 fs, 1 kHz) has been employed, at a fluence of 3.6 J/cm{sup 2} in ambient environments of de-ionized water, and propanol for various number of laser pulses i.e. 500, 1000, 1500 and 2000. The surface features, chemical composition, structural analysis and mechanical properties of irradiated targets have been evaluated by using Scanning Electron Microscope (SEM), Energy Dispersive X-Ray Spectroscopy (EDS), X -ray Diffraction (XRD), Raman Spectroscopy and Nano-hardness tester. Various features like dendritic structures, globules, porous granular morphology, cones, crater, circular ripples and thermal stress cracking are observed at the ablated area after irradiation. These features are instigated by various thermal and chemical phenomena induced by laser heating at the solid–liquid interface. Decrease in nano-hardness observed in both ambient environments is attributable to the formation of hydrides after irradiation in both media.

  15. Transverse mode selection in vertical-cavity surface-emitting lasers via deep impurity-induced disordering

    Science.gov (United States)

    O'Brien, Thomas R.; Kesler, Benjamin; Dallesasse, John M.

    2017-02-01

    Top emission 850-nm vertical-cavity surface-emitting lasers (VCSELs) demonstrating transverse mode selection via impurity-induced disordering (IID) are presented. The IID apertures are fabricated via closed ampoule zinc diffusion. A simple 1-D plane wave model based on the intermixing of Group III atoms during IID is presented to optimize the mirror loss of higher-order modes as a function of IID strength and depth. In addition, the impact of impurity diffusion into the cap layer of the lasers is shown to improve contact resistance. Further investigation of the mode-dependent characteristics of the device imply an increase in the thermal impedance associated with the fraction of IID contained within the oxide aperture. The optimization of the ratio of the IID aperture to oxide aperture is experimentally determined. Single fundamental mode output of 1.6 mW with 30 dBm side mode suppression ratio is achieved by a 3.0 μm oxide-confined device with an IID aperture of 1.3 μm indicating an optimal IID aperture size of 43% of the oxide aperture.

  16. Single-mode temperature and polarisation-stable high-speed 850nm vertical cavity surface emitting lasers

    International Nuclear Information System (INIS)

    Nazaruk, D E; Blokhin, S A; Maleev, N A; Bobrov, M A; Pavlov, M M; Kulagina, M M; Vashanova, K A; Zadiranov, Yu M; Ustinov, V M; Kuzmenkov, A G; Vasil'ev, A P; Gladyshev, A G; Blokhin, A A; Salut, 7 Larina Str, N Novgorod, 603950 (Russian Federation))" data-affiliation=" (JSV Salut, 7 Larina Str, N Novgorod, 603950 (Russian Federation))" >Fefelov, A G

    2014-01-01

    A new intracavity-contacted design to realize temperature and polarization-stable high-speed single-mode 850 nm vertical cavity surface emitting lasers (VCSELs) grown by molecular-beam epitaxy is proposed. Temperature dependences of static and dynamic characteristics of the 4.5 pm oxide aperture InGaAlAs VCSEL were investigated in detail. Due to optimal gain-cavity detuning and enhanced carrier localization in the active region the threshold current remains below 0.75 mA for the temperature range within 20-90°C, while the output power exceeds 1 mW up to 90°C. Single-mode operation with side-mode suppression ratio higher than 30 dB and orthogonal polarization suppression ratio more than 18 dB was obtained in the whole current and temperature operation range. Device demonstrates serial resistance less than 250 Ohm, which is rather low for any type of single-mode short- wavelength VCSELs. VCSEL demonstrates temperature robust high-speed operation with modulation bandwidth higher than 13 GHz in the entire temperature range of 20-90°C. Despite high resonance frequency the high-speed performance of developed VCSELs was limited by the cut-off frequency of the parasitic low pass filter created by device resistances and capacitances. The proposed design is promising for single-mode high-speed VCSEL applications in a wide spectral range

  17. Heterogeneous nucleation from a supercooled ionic liquid on a carbon surface.

    Science.gov (United States)

    He, Xiaoxia; Shen, Yan; Hung, Francisco R; Santiso, Erik E

    2016-12-07

    Classical molecular dynamics simulations were used to study the nucleation of the crystal phase of the ionic liquid [dmim + ][Cl - ] from its supercooled liquid phase, both in the bulk and in contact with a graphitic surface of D = 3 nm. By combining the string method in collective variables [Maragliano et al., J. Chem. Phys. 125, 024106 (2006)], with Markovian milestoning with Voronoi tessellations [Maragliano et al., J. Chem. Theory Comput. 5, 2589-2594 (2009)] and order parameters for molecular crystals [Santiso and Trout, J. Chem. Phys. 134, 064109 (2011)], we computed minimum free energy paths, the approximate size of the critical nucleus, the free energy barrier, and the rates involved in these nucleation processes. For homogeneous nucleation, the subcooled liquid phase has to overcome a free energy barrier of ∼85 kcal/mol to form a critical nucleus of size ∼3.6 nm, which then grows into the monoclinic crystal phase. This free energy barrier becomes about 42% smaller (∼49 kcal/mol) when the subcooled liquid phase is in contact with a graphitic disk, and the critical nucleus formed is about 17% smaller (∼3.0 nm) than the one observed for homogeneous nucleation. The crystal formed in the heterogeneous nucleation scenario has a structure that is similar to that of the bulk crystal, with the exception of the layers of ions next to the graphene surface, which have larger local density and the cations lie with their imidazolium rings parallel to the graphitic surface. The critical nucleus forms near the graphene surface separated only by these layers of ions. The heterogeneous nucleation rate (∼4.8 × 10 11 cm -3 s -1 ) is about one order of magnitude faster than the homogeneous rate (∼6.6 × 10 10 cm -3 s -1 ). The computed free energy barriers and nucleation rates are in reasonable agreement with experimental and simulation values obtained for the homogeneous and heterogeneous nucleation of other systems (ice, urea, Lennard-Jones spheres, and oxide

  18. Bonding two surfaces by exposing to actinic radiation an epoxide liquid composition

    International Nuclear Information System (INIS)

    Green, G.E.

    1981-01-01

    A method for preparing a film adhesive from an epoxide resin is described. A liquid containing an epoxide resin and a photopolymerizable compound is polymerized to form a solid continuous film by exposure to actinide radiation. A catalyst can be used but no thermal crosslinking should be allowed to occur. The film so obtained is used to bond surfaces together by the application of heat and pressure. The period of heating can be very short, as there need be no solvent to evaporate and the films need not be thick, typically 20 to 250 μm. (O.T.)

  19. Variable Structure Disturbance Rejection Control for Nonlinear Uncertain Systems with State and Control Delays via Optimal Sliding Mode Surface Approach

    Directory of Open Access Journals (Sweden)

    Jing Lei

    2013-01-01

    Full Text Available The paper considers the problem of variable structure control for nonlinear systems with uncertainty and time delays under persistent disturbance by using the optimal sliding mode surface approach. Through functional transformation, the original time-delay system is transformed into a delay-free one. The approximating sequence method is applied to solve the nonlinear optimal sliding mode surface problem which is reduced to a linear two-point boundary value problem of approximating sequences. The optimal sliding mode surface is obtained from the convergent solutions by solving a Riccati equation, a Sylvester equation, and the state and adjoint vector differential equations of approximating sequences. Then, the variable structure disturbance rejection control is presented by adopting an exponential trending law, where the state and control memory terms are designed to compensate the state and control delays, a feedforward control term is designed to reject the disturbance, and an adjoint compensator is designed to compensate the effects generated by the nonlinearity and the uncertainty. Furthermore, an observer is constructed to make the feedforward term physically realizable, and thus the dynamical observer-based dynamical variable structure disturbance rejection control law is produced. Finally, simulations are demonstrated to verify the effectiveness of the presented controller and the simplicity of the proposed approach.

  20. Étude de l'efficacité des modes de Lamb dans la signature acoustique en fonction du liquide de couplage

    Science.gov (United States)

    Brunet, N.; Cros, B.; Despaux, G.; Saurel, J.-M.

    1998-06-01

    The acoustic signature allows to measure the velocity of the longitudinal and transverse acoustic waves in bulk materials. From the velocities and density values the elastic properties can be calculated. For thin layer materials, these velocities are not directly measured but computed from the experimentally available velocities: the generalized Lamb waves velocities. These waves velocities are dispersive and their measurement depends on the liquid acting as a coupling fluid. In this study, the two faces of the layer are in contact with the liquid (methanol, water or aqueous solutions of potassium iodide KI_aq. 6 M and potassium hydroxyde KOH_aq. 12 M) chosen according to its acoustic parameters. The acoustic signature modeling allows to know their respective influence, the possible detection of the fast modes and, in general, the velocity measurement accuracy increase for all available modes. The experimental studies bear out that each mode characterization may be optimized by the appropriate choice of the frequency and of the coupling liquid according to its velocity, density and attenuation. L'étude de la signature acoustique permet de mesurer les vitesses de propagation des ondes acoustiques longitudinale et transverse dans les matériaux massifs, vitesses à partir desquelles on détermine leurs propriétés mécaniques. Pour des matériaux en couche mince, ces vitesses ne sont plus mesurées directement mais calculées à partir des vitesses accessibles expérimentalement : celles des modes de Lamb généralisés. Ces modes ont des vitesses dispersives et leur mesure dépend du liquide servant de couplant, dans lequel la couche est immergée. Dans cette étude, les liquides de couplage (méthanol, eau et solutions aqueuses de iodure de potassium KI_aq. 6 M et d'hydroxyde de potassium KOH_aq. 12 M) sont choisis en fonction de leurs paramètres acoustiques. La modélisation de la signature acoustique permet de prévoir leur influence respective, comment ils