WorldWideScience

Sample records for surface materials including

  1. Development of symmetric composition-gradient materials including hard particles in its surface layer; Hyosobu ni koshitsu ryushi wo fukumu taishogata sosei keisha zairyo no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Development of new materials with both thermal resistance and thermal shock resistance was studied on the basis of symmetric ceramics/metal/ceramics gradient composition. Al2O3/TiC/Ni/TiC/Al2O3 was used as material model of basic composition, and the system was selected where WC-Co system alloy hard particles were dispersed into the Al2O3 ceramic surface layer. The layered material was sintered in N2 gas atmosphere by SHS/HIP method using exothermic caused by nitriding reaction. Since cracks were generated in some specimens of 5-layer structure, improved specimens of 7-layer structure were prepared. To examine the effect of a particle size on toughness, WC-Co system alloy specimens with different particle sizes were also prepared. As a result, no cracks were found, and residual stress and fracture toughness were affected by particle size. In addition, the following were studied: technique of mass production, observation of fine structures, analysis of thermal stress, thermal shock resistance, and friction and abrasion characteristics. 13 refs., 65 figs., 15 tabs.

  2. Surface physics of materials materials science and technology

    CERN Document Server

    Blakely, J M

    2013-01-01

    Surface Physics of Materials presents accounts of the physical properties of solid surfaces. The book contains selected articles that deal with research emphasizing surface properties rather than experimental techniques in the field of surface physics. Topics discussed include transport of matter at surfaces; interaction of atoms and molecules with surfaces; chemical analysis of surfaces; and adhesion and friction. Research workers, teachers and graduate students in surface physics, and materials scientist will find the book highly useful.

  3. Armor systems including coated core materials

    Science.gov (United States)

    Chu, Henry S [Idaho Falls, ID; Lillo, Thomas M [Idaho Falls, ID; McHugh, Kevin M [Idaho Falls, ID

    2012-07-31

    An armor system and method involves providing a core material and a stream of atomized coating material that comprises a liquid fraction and a solid fraction. An initial layer is deposited on the core material by positioning the core material in the stream of atomized coating material wherein the solid fraction of the stream of atomized coating material is less than the liquid fraction of the stream of atomized coating material on a weight basis. An outer layer is then deposited on the initial layer by positioning the core material in the stream of atomized coating material wherein the solid fraction of the stream of atomized coating material is greater than the liquid fraction of the stream of atomized coating material on a weight basis.

  4. Surface mobilities on solid materials

    International Nuclear Information System (INIS)

    Binh, V.T.

    1983-01-01

    This book constitutes the proceedings of the NATO Advanced Study Institute on Surface Mobilities on Solid Materials held in France in 1981. The goal of the two-week meeting was to review up-to-date knowledge on surface diffusion, both theoretical and experimental, and to highlight those areas in which much more knowledge needs to be accumulated. Topics include theoretical aspects of surface diffusion (e.g., microscopic theories of D at zero coverage; statistical mechanical models and surface diffusion); surface diffusion at the atomic level (e.g., FIM studies of surface migration of single adatoms and diatomic clusters; field emission studies of surface diffusion of adsorbates); foreign adsorbate mass transport; self-diffusion mass transport (e.g., different driving forces for the matter transport along surfaces; measurements of the morphological evolution of tips); the role of surface diffusion in some fundamental and applied sciences (e.g. adatomadatom pair interactions and adlayer superstructure formation; surface mobility in chemical reactions and catalysis); and recent works on surface diffusion (e.g., preliminary results on surface self-diffusion measurements on nickel and chromium tips)

  5. Surface Chemistry in Nanoscale Materials

    Science.gov (United States)

    Biener, Jürgen; Wittstock, Arne; Baumann, Theodore F.; Weissmüller, Jörg; Bäumer, Marcus; Hamza, Alex V.

    2009-01-01

    Although surfaces or, more precisely, the surface atomic and electronic structure, determine the way materials interact with their environment, the influence of surface chemistry on the bulk of the material is generally considered to be small. However, in the case of high surface area materials such as nanoporous solids, surface properties can start to dominate the overall material behavior. This allows one to create new materials with physical and chemical properties that are no longer determined by the bulk material, but by their nanoscale architectures. Here, we discuss several examples, ranging from nanoporous gold to surface engineered carbon aerogels that demonstrate the tuneability of nanoporous solids for sustainable energy applications.

  6. Surface Chemistry in Nanoscale Materials

    Directory of Open Access Journals (Sweden)

    Alex V. Hamza

    2009-12-01

    Full Text Available Although surfaces or, more precisely, the surface atomic and electronic structure, determine the way materials interact with their environment, the influence of surface chemistry on the bulk of the material is generally considered to be small. However, in the case of high surface area materials such as nanoporous solids, surface properties can start to dominate the overall material behavior. This allows one to create new materials with physical and chemical properties that are no longer determined by the bulk material, but by their nanoscale architectures. Here, we discuss several examples, ranging from nanoporous gold to surface engineered carbon aerogels that demonstrate the tuneability of nanoporous solids for sustainable energy applications.

  7. Ceramic substrate including thin film multilayer surface conductor

    Energy Technology Data Exchange (ETDEWEB)

    Wolf, Joseph Ambrose; Peterson, Kenneth A.

    2017-05-09

    A ceramic substrate comprises a plurality of ceramic sheets, a plurality of inner conductive layers, a plurality of vias, and an upper conductive layer. The ceramic sheets are stacked one on top of another and include a top ceramic sheet. The inner conductive layers include electrically conductive material that forms electrically conductive features on an upper surface of each ceramic sheet excluding the top ceramic sheet. The vias are formed in each of the ceramic sheets with each via being filled with electrically conductive material. The upper conductive layer includes electrically conductive material that forms electrically conductive features on an upper surface of the top ceramic sheet. The upper conductive layer is constructed from a stack of four sublayers. A first sublayer is formed from titanium. A second sublayer is formed from copper. A third sublayer is formed from platinum. A fourth sublayer is formed from gold.

  8. Vibration of Piezoelectric Nanowires Including Surface Effects

    Directory of Open Access Journals (Sweden)

    R. Ansari

    2014-04-01

    Full Text Available In this paper, surface and piezoelectric effects on the vibration behavior of nanowires (NWs are investigated by using a Timoshenko beam model. The electric field equations and the governing equations of motion for the piezoelectric NWs are derived with the consideration of surface effects. By the exact solution of the governing equations, an expression for the natural frequencies of NWs with simply-supported boundary conditions is obtained. The effects of piezoelectricity and surface effects on the vibrational behavior of Timoshenko NWs are graphically illustrated. A comparison is also made between the predictions of Timoshenko beam model and those of its Euler-Bernoulli counterpart. Additionally, the present results are validated through comparison with the available data in the literature.

  9. Composite material including nanocrystals and methods of making

    Science.gov (United States)

    Bawendi, Moungi G.; Sundar, Vikram C.

    2010-04-06

    Temperature-sensing compositions can include an inorganic material, such as a semiconductor nanocrystal. The nanocrystal can be a dependable and accurate indicator of temperature. The intensity of emission of the nanocrystal varies with temperature and can be highly sensitive to surface temperature. The nanocrystals can be processed with a binder to form a matrix, which can be varied by altering the chemical nature of the surface of the nanocrystal. A nanocrystal with a compatibilizing outer layer can be incorporated into a coating formulation and retain its temperature sensitive emissive properties.

  10. Zwitterionic materials for antifouling membrane surface construction.

    Science.gov (United States)

    He, Mingrui; Gao, Kang; Zhou, Linjie; Jiao, Zhiwei; Wu, Mengyuan; Cao, Jialin; You, Xinda; Cai, Ziyi; Su, Yanlei; Jiang, Zhongyi

    2016-08-01

    Membrane separation processes are often perplexed by severe and ubiquitous membrane fouling. Zwitterionic materials, keeping electric neutrality with equivalent positive and negative charged groups, are well known for their superior antifouling properties and have been broadly utilized to construct antifouling surfaces for medical devices, biosensors and marine coatings applications. In recent years, zwitterionic materials have been more and more frequently utilized for constructing antifouling membrane surfaces. In this review, the antifouling mechanisms of zwitterionic materials as well as their biomimetic prototypes in cell membranes will be discussed, followed by the survey of common approaches to incorporate zwitterionic materials onto membrane surfaces including surface grafting, surface segregation, biomimetic adhesion, surface coating and so on. The potential applications of these antifouling membranes are also embedded. Finally, we will present a brief perspective on the future development of zwitterionic materials modified antifouling membranes. Membrane fouling is a severe problem hampering the application of membrane separation technology. The properties of membrane surfaces play a critical role in membrane fouling and antifouling behavior/performance. Antifouling membrane surface construction has evolved as a hot research issue for the development of membrane processes. Zwitterionic modification of membrane surfaces has been recognized as an effective strategy to resist membrane fouling. This review summarizes the antifouling mechanisms of zwitterionic materials inspired by cell membranes as well as the popular approaches to incorporate them onto membrane surfaces. It can help form a comprehensive knowledge about the principles and methods of modifying membrane surfaces with zwitterionic materials. Finally, we propose the possible future research directions of zwitterionic materials modified antifouling membranes. Copyright © 2016 Acta Materialia Inc

  11. Surface materials considerations for fusion reactors

    International Nuclear Information System (INIS)

    Sone, Kazuho; Maeno, Masaki; Yamamoto, Shin; Ohtsuka, Hidewo; Abe, Tetsuya

    1982-11-01

    Surface materials considerations have been made to support the Impurity Control and First Wall Engineering task in the INTOR. They focussed on low-Z material candidates including C(graphite), SiC and TiC. Properties considered are listed in the following: 1) Physical Sputtering. 2) Chemical Sputtering. 3) Arcing. 4) H/He Retention/Release. 5) Redeposited Materials Characteristics. (author)

  12. Surface materials as reference standards

    International Nuclear Information System (INIS)

    Lemos, V.P.; Siqueira, N.V.M. de

    1982-01-01

    Studies about standardization of geological samples have been the main goal of analytical research works and have thus contributed to supply data concerning the contents of major, minor and trace elements in samples. As reference standards, silicates and surface materials have been used, the latter being less abundant and the most employed are: bauxite standards NBS-69-a, NBS-69-b and NBS-697 (USA) and BxN(France); soil standards SO-1, SO-2, SO-3, SO-4 (Canada) and Soil-5 (international). Additional contributions to analytical geochemistry will be obtained from works aiming the standardization of samples of weathering materials. Contents of major components (SiO 2 , Al 2 O 3 , Fe 2 O 3 and volatile materials), minor (TiO 2 , P 2 O 5 )and trace elements (Cu, Pb, Zn, Ni, Co, Mn, Y, Zr, Nb, V and Mo) are being determined in two samples of altered basalt, three samples of bauxite and two samples of soils. Among the analytical methods employed in this preliminary phase of the work are the classical methods (gravimetric and titrimetric), colorimetry and X-ray fluorescence analysis. (Author) [pt

  13. Composite materials and bodies including silicon carbide and titanium diboride and methods of forming same

    Science.gov (United States)

    Lillo, Thomas M.; Chu, Henry S.; Harrison, William M.; Bailey, Derek

    2013-01-22

    Methods of forming composite materials include coating particles of titanium dioxide with a substance including boron (e.g., boron carbide) and a substance including carbon, and reacting the titanium dioxide with the substance including boron and the substance including carbon to form titanium diboride. The methods may be used to form ceramic composite bodies and materials, such as, for example, a ceramic composite body or material including silicon carbide and titanium diboride. Such bodies and materials may be used as armor bodies and armor materials. Such methods may include forming a green body and sintering the green body to a desirable final density. Green bodies formed in accordance with such methods may include particles comprising titanium dioxide and a coating at least partially covering exterior surfaces thereof, the coating comprising a substance including boron (e.g., boron carbide) and a substance including carbon.

  14. A hydrodynamic model for granular material flows including segregation effects

    Directory of Open Access Journals (Sweden)

    Gilberg Dominik

    2017-01-01

    Full Text Available The simulation of granular flows including segregation effects in large industrial processes using particle methods is accurate, but very time-consuming. To overcome the long computation times a macroscopic model is a natural choice. Therefore, we couple a mixture theory based segregation model to a hydrodynamic model of Navier-Stokes-type, describing the flow behavior of the granular material. The granular flow model is a hybrid model derived from kinetic theory and a soil mechanical approach to cover the regime of fast dilute flow, as well as slow dense flow, where the density of the granular material is close to the maximum packing density. Originally, the segregation model has been formulated by Thornton and Gray for idealized avalanches. It is modified and adapted to be in the preferred form for the coupling. In the final coupled model the segregation process depends on the local state of the granular system. On the other hand, the granular system changes as differently mixed regions of the granular material differ i.e. in the packing density. For the modeling process the focus lies on dry granular material flows of two particle types differing only in size but can be easily extended to arbitrary granular mixtures of different particle size and density. To solve the coupled system a finite volume approach is used. To test the model the rotational mixing of small and large particles in a tumbler is simulated.

  15. A hydrodynamic model for granular material flows including segregation effects

    Science.gov (United States)

    Gilberg, Dominik; Klar, Axel; Steiner, Konrad

    2017-06-01

    The simulation of granular flows including segregation effects in large industrial processes using particle methods is accurate, but very time-consuming. To overcome the long computation times a macroscopic model is a natural choice. Therefore, we couple a mixture theory based segregation model to a hydrodynamic model of Navier-Stokes-type, describing the flow behavior of the granular material. The granular flow model is a hybrid model derived from kinetic theory and a soil mechanical approach to cover the regime of fast dilute flow, as well as slow dense flow, where the density of the granular material is close to the maximum packing density. Originally, the segregation model has been formulated by Thornton and Gray for idealized avalanches. It is modified and adapted to be in the preferred form for the coupling. In the final coupled model the segregation process depends on the local state of the granular system. On the other hand, the granular system changes as differently mixed regions of the granular material differ i.e. in the packing density. For the modeling process the focus lies on dry granular material flows of two particle types differing only in size but can be easily extended to arbitrary granular mixtures of different particle size and density. To solve the coupled system a finite volume approach is used. To test the model the rotational mixing of small and large particles in a tumbler is simulated.

  16. Cladding material, tube including such cladding material and methods of forming the same

    Science.gov (United States)

    Garnier, John E.; Griffith, George W.

    2016-03-01

    A multi-layered cladding material including a ceramic matrix composite and a metallic material, and a tube formed from the cladding material. The metallic material forms an inner liner of the tube and enables hermetic sealing of thereof. The metallic material at ends of the tube may be exposed and have an increased thickness enabling end cap welding. The metallic material may, optionally, be formed to infiltrate voids in the ceramic matrix composite, the ceramic matrix composite encapsulated by the metallic material. The ceramic matrix composite includes a fiber reinforcement and provides increased mechanical strength, stiffness, thermal shock resistance and high temperature load capacity to the metallic material of the inner liner. The tube may be used as a containment vessel for nuclear fuel used in a nuclear power plant or other reactor. Methods for forming the tube comprising the ceramic matrix composite and the metallic material are also disclosed.

  17. Olkiluoto surface hydrological modelling: Update 2012 including salt transport modelling

    International Nuclear Information System (INIS)

    Karvonen, T.

    2013-11-01

    Posiva Oy is responsible for implementing a final disposal program for spent nuclear fuel of its owners Teollisuuden Voima Oyj and Fortum Power and Heat Oy. The spent nuclear fuel is planned to be disposed at a depth of about 400-450 meters in the crystalline bedrock at the Olkiluoto site. Leakages located at or close to spent fuel repository may give rise to the upconing of deep highly saline groundwater and this is a concern with regard to the performance of the tunnel backfill material after the closure of the tunnels. Therefore a salt transport sub-model was added to the Olkiluoto surface hydrological model (SHYD). The other improvements include update of the particle tracking algorithm and possibility to estimate the influence of open drillholes in a case where overpressure in inflatable packers decreases causing a hydraulic short-circuit between hydrogeological zones HZ19 and HZ20 along the drillhole. Four new hydrogeological zones HZ056, HZ146, BFZ100 and HZ039 were added to the model. In addition, zones HZ20A and HZ20B intersect with each other in the new structure model, which influences salinity upconing caused by leakages in shafts. The aim of the modelling of long-term influence of ONKALO, shafts and repository tunnels provide computational results that can be used to suggest limits for allowed leakages. The model input data included all the existing leakages into ONKALO (35-38 l/min) and shafts in the present day conditions. The influence of shafts was computed using eight different values for total shaft leakage: 5, 11, 20, 30, 40, 50, 60 and 70 l/min. The selection of the leakage criteria for shafts was influenced by the fact that upconing of saline water increases TDS-values close to the repository areas although HZ20B does not intersect any deposition tunnels. The total limit for all leakages was suggested to be 120 l/min. The limit for HZ20 zones was proposed to be 40 l/min: about 5 l/min the present day leakages to access tunnel, 25 l/min from

  18. Monitoring of tritium-contaminated surfaces, including skin

    International Nuclear Information System (INIS)

    Surette, R.A.; Wood, M.J.

    1994-05-01

    We have examined various commercially available tritium surface contamination monitors along with different swipe media and techniques for direct and indirect (swipe) monitoring of contaminated surfaces, including skin. None of the methods or instruments evaluated were more sensitive than the swipe and liquid scintillation counting (LSC) method. Swipe measurements with open-window proportional counters were, in general, less than half as sensitive as LSC, but have the advantages of having the results available almost immediately, and no sample preparation is required. The Nuclear Measurement Corporation's PC-55 is the most suitable instrument we tested for the analysis of routine swipe measurement. The PC-55 was about one third as sensitive as LSC when used with Ontario Hydro filter paper swipe media. Surface contamination measurement results can be obtained within minutes using the PC-55, compared to hours using LSC. The selection of swipe media for use with proportional counter-based instruments is critical. A medium that is electrically insulating can develop an electrostatic charge on its surface; this may alter the field gradient in the detector and may adversely influence the results. Although the PC-55 is sufficiently sensitive and very convenient, operational experience with the instrument is needed before recommending that it replace current LSC methods. The PC-55's susceptibility to internal tritium contamination may limit its practical usefulness. Because of the complexity of using live animals to evaluate direct and indirect methods for assessing skin contamination, pig skin was investigated as a possible substitute. We concluded that, for the first few hours post-exposure, pig skin mimics the kinetics of animal skin that has contacted a tritium-contaminated surface. (author). 30 refs., 1 tab., 7 figs

  19. Surface analysis methods in materials science

    CERN Document Server

    Sexton, Brett; Smart, Roger

    1992-01-01

    The idea for this book stemmed from a remark by Philip Jennings of Murdoch University in a discussion session following a regular meeting of the Australian Surface Science group. He observed that a text on surface analysis and applica­ tions to materials suitable for final year undergraduate and postgraduate science students was not currently available. Furthermore, the members of the Australian Surface Science group had the research experience and range of coverage of sur­ face analytical techniques and applications to provide a text for this purpose. A of techniques and applications to be included was agreed at that meeting. The list intended readership of the book has been broadened since the early discussions, particularly to encompass industrial users, but there has been no significant alter­ ation in content. The editors, in consultation with the contributors, have agreed that the book should be prepared for four major groups of readers: - senior undergraduate students in chemistry, physics, metallur...

  20. Chemical equilibrium of ablation materials including condensed species

    Science.gov (United States)

    Stroud, C. W.; Brinkley, K. L.

    1975-01-01

    Equilibrium is determined by finding chemical composition with minimum free energy. Method of steepest descent is applied to quadratic representation of free-energy surface. Solution is initiated by selecting arbitrary set of mole fractions, from which point on free-energy surface is computed.

  1. Metal-organic framework materials with ultrahigh surface areas

    Science.gov (United States)

    Farha, Omar K.; Hupp, Joseph T.; Wilmer, Christopher E.; Eryazici, Ibrahim; Snurr, Randall Q.; Gomez-Gualdron, Diego A.; Borah, Bhaskarjyoti

    2015-12-22

    A metal organic framework (MOF) material including a Brunauer-Emmett-Teller (BET) surface area greater than 7,010 m.sup.2/g. Also a metal organic framework (MOF) material including hexa-carboxylated linkers including alkyne bond. Also a metal organic framework (MOF) material including three types of cuboctahedron cages fused to provide continuous channels. Also a method of making a metal organic framework (MOF) material including saponifying hexaester precursors having alkyne bonds to form a plurality of hexa-carboxylated linkers including alkyne bonds and performing a solvothermal reaction with the plurality of hexa-carboxylated linkers and one or more metal containing compounds to form the MOF material.

  2. PAVECHECK : training material updated user's manual including GPS.

    Science.gov (United States)

    2009-01-01

    PAVECHECK is a software package used to integrate nondestructive test data from various testing systems to provide the pavement engineer with a comprehensive evaluation of both surface and subsurface conditions. This User's Manual is intended to demo...

  3. Surface Modification of Catalytic Materials

    DEFF Research Database (Denmark)

    Nierhoff, Anders Ulrik Fregerslev

    aggregation techniques. With the use of two different filter mechanisms, the Quadrupole and the Lateral Time Of Flight, the nanoparticles were mass selected. This was done to correlate nanoparticle size with reactivity. Selected key findings can be summarized as: 1) CO induced surface changes of Pt based...... methanol synthesis. The importance of conducting well controlled UHV experiments and characterization in combination with experiments at higher pressures to span the pressure gap between UHV and operando conditions is definitely highlighted in this thesis....

  4. Exploration Technology Development including Surface Acoustic Wave RFID chips

    Data.gov (United States)

    National Aeronautics and Space Administration — This project is focused on maturing future surface exploration technologies and instrumentation and working towards flight instrumentation and systems to support...

  5. Ion surface treatments on organic materials

    Science.gov (United States)

    Iwaki, Masaya

    2001-04-01

    A study has been made of surface modification of various organic materials by ion bombardment or implantation to make the surface properties of high and multiple functions in RIKEN. Substrates used were polyimide (PI), polyacetylene, polytetrafluoroethylene (PTFE), polystyrene (PS), silicone rubber, various kinds of proteins and so on. Bombarded or implanted ions were inert gas elements, chemically active gaseous elements and metallic elements. Surface properties such as electrical conductivity, wettability and cell adhesion of implanted layers have been investigated. Surface characterization of implanted materials has been carried out by means of transmission electron microscopy, laser Raman spectroscopy, X-ray photoelectron spectroscopy and Rutherford backscattering spectroscopy. In this paper, studies in RIKEN are reviewed of electrical conductivity, optical absorbance, wettability and cell adhesion depending on current densities and doping elements. Applications of ion bombardment to biomedical materials are introduced using cell adhesion control. It is concluded that ion bombardment or implantation is useful to change and control surface properties of various organic materials.

  6. Reaction behaviour of reactor materials, including concrete during core meltdown

    International Nuclear Information System (INIS)

    Holleck, H.; Hofmann, P.; Skokan, A.

    1976-01-01

    The problems dealt with in the studies on the material behaviour of core meltdowns are sketched, and an outline is given on the experimental investigations now in progress. These studies aim at establishing a model which is as realistic as possible, and the paper tries to show that knowledge on the reaction behaviour is a basic prerequisite for this. (orig./TK) [de

  7. Thermal and Electrical Properties of Nanocomposites, Including Material Properties

    NARCIS (Netherlands)

    Kochetov, R.

    2012-01-01

    The research described in this thesis is part of a state-funded IOP-EMVT project in cooperation with industrial companies, aiming at the design, assessment and implementation of new, environmental friendly (e.g. oil and SF6 - free) solid dielectric materials. A large disadvantage of solid polymer

  8. Nodal surface semimetals: Theory and material realization

    Science.gov (United States)

    Wu, Weikang; Liu, Ying; Li, Si; Zhong, Chengyong; Yu, Zhi-Ming; Sheng, Xian-Lei; Zhao, Y. X.; Yang, Shengyuan A.

    2018-03-01

    We theoretically study the three-dimensional topological semimetals with nodal surfaces protected by crystalline symmetries. Different from the well-known nodal-point and nodal-line semimetals, in these materials, the conduction and valence bands cross on closed nodal surfaces in the Brillouin zone. We propose different classes of nodal surfaces, both in the absence and in the presence of spin-orbit coupling (SOC). In the absence of SOC, a class of nodal surfaces can be protected by space-time inversion symmetry and sublattice symmetry and characterized by a Z2 index, while another class of nodal surfaces are guaranteed by a combination of nonsymmorphic twofold screw-rotational symmetry and time-reversal symmetry. We show that the inclusion of SOC will destroy the former class of nodal surfaces but may preserve the latter provided that the inversion symmetry is broken. We further generalize the result to magnetically ordered systems and show that protected nodal surfaces can also exist in magnetic materials without and with SOC, given that certain magnetic group symmetry requirements are satisfied. Several concrete nodal-surface material examples are predicted via the first-principles calculations. The possibility of multi-nodal-surface materials is discussed.

  9. Towards ultra-stiff materials: Surface effects on nanoporous materials

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Dingjie; Xie, Yi Min; Huang, Xiaodong; Zhou, Shiwei, E-mail: shiwei.zhou@rmit.edu.au [Centre for Innovative Structures and Materials, School of Civil, Environmental and Chemical Engineering, RMIT University, GPO Box 2476, Melbourne 3001 (Australia); Li, Qing [School of Aerospace, Mechanical and Mechatronic Engineering, The University of Sydney, New South Wales 2006 (Australia)

    2014-09-08

    The significant rise in the strength and stiffness of porous materials at nanoscale cannot be described by conventional scaling laws. This letter investigates the effective Young's modulus of such materials by taking into account surface effect in a microcellular architecture designed for an ultralight material whose stiffness is an order of magnitude higher than most porous materials. We find that by considering the surface effects the predicted stiffness using Euler-Bernoulli beam theory compares well to experimental data for spongelike nanoporous gold with random microstructures. Analytical results show that, of the two factors influencing the effective Young's modulus, the residual stress is more important than the surface stiffness.

  10. Materials and surface engineering in tribology

    CERN Document Server

    Takadoum, Jamal

    2010-01-01

    This title is designed to provide a clear and comprehensive overview of tribology. The book introduces the notion of a surface in tribology where a solid surface is described from topographical, structural, mechanical, and energetic perspectives. It also describes the principal techniques used to characterize and analyze surfaces. The title then discusses what may be called the fundamentals of tribology by introducing and describing the concepts of adhesion, friction, wear, and lubrication. The book focuses on the materials used in tribology, introducing the major classes of materials used, ei

  11. Including Finite Surface Span Effects in Empirical Jet-Surface Interaction Noise Models

    Science.gov (United States)

    Brown, Clifford A.

    2016-01-01

    The effect of finite span on the jet-surface interaction noise source and the jet mixing noise shielding and reflection effects is considered using recently acquired experimental data. First, the experimental setup and resulting data are presented with particular attention to the role of surface span on far-field noise. These effects are then included in existing empirical models that have previously assumed that all surfaces are semi-infinite. This extended abstract briefly describes the experimental setup and data leaving the empirical modeling aspects for the final paper.

  12. Thermal inertia mapping. [for lithologic materials in earth surface

    Science.gov (United States)

    Kahle, A. B.; Gillespie, A. R.; Goetz, A. F. H.; Addington, J. D.

    1975-01-01

    A thermal model of the earth's surface has been developed and used to determine the thermal inertia of a test site in the Mojave Desert, California. The model, which includes meteorological heating terms as well as radiation and conduction heating terms, is used with remotely sensed surface temperature data to determine thermal inertia of materials. The thermal inertia is displayed in image form, and can aid in the differentiation of the various lithologic materials in the test site.

  13. Potential energy surface for ? dissociation including spin-orbit effects

    Science.gov (United States)

    Siebert, Matthew R.; Aquino, Adelia J. A.; de Jong, Wibe A.; Granucci, Giovanni; Hase, William L.

    2012-10-01

    Previous experiments [J. Phys. Chem. A 116, 2833 (2012)] have studied the dissociation of 1,2-diiodoethane radical cation ( ? ) and found a one-dimensional distribution of translational energy, an odd finding considering most product relative translational energy distributions are two-dimensional. The goal of this study is to obtain an accurate understanding of the potential energy surface (PES) topology for the unimolecular decomposition reaction ? → C2H4I+ + I•. This is done through comparison of many single-reference electronic structure methods, coupled-cluster single-point (energy) calculations, and multi-reference energy calculations used to quantify spin-orbit (SO) coupling effects. We find that the structure of the ? reactant has a substantial effect on the role of the SO coupling on the reaction energy. Both the BHandH and MP2 theories with an ECP/6-31++G** basis set, and without SO coupling corrections, provide accurate models for the reaction energetics. MP2 theory gives an unsymmetric structure with different C-I bond lengths, resulting in a SO energy for ? similar to that for the product I-atom and a negligible SO correction to the reaction energy. In contrast, DFT gives a symmetric structure for ? , similar to that of the neutral C2H4I2 parent, resulting in a substantial SO correction and increasing the reaction energy by 6.0-6.5 kcalmol-1. Also, we find that, for this system, coupled-cluster single-point energy calculations are inaccurate, since a small change in geometry can lead to a large change in energy.

  14. Surfaces and interfaces of electronic materials

    CERN Document Server

    Brillson, Leonard J

    2012-01-01

    An advanced level textbook covering geometric, chemical, and electronic structure of electronic materials, and their applications to devices based on semiconductor surfaces, metal-semiconductor interfaces, and semiconductor heterojunctions. Starting with the fundamentals of electrical measurements on semiconductor interfaces, it then describes the importance of controlling macroscopic electrical properties by atomic-scale techniques. Subsequent chapters present the wide range of surface and interface techniques available to characterize electronic, optical, chemical, and structural propertie

  15. EB surface sterilization of food material

    International Nuclear Information System (INIS)

    Kaneko, H.; Mizutani, A.; Kato, K.; Nishikimi, T.; Taniguchi, S.

    2001-01-01

    In this paper, we introduce a food irradiation with low energetic, lower than 300keV, electrons (so-called SOFT ELECTRON) as a rather new method of food sterilization. It is also a physical sterilization method, and free from the problems mentioned above. Low energetic electrons have small penetration power (50-200micron) through raw materials, and by selecting a proper energy of electrons we can sterilize only the surfaces or skins of target materials

  16. Spectroscopy of Icy Moon Surface Materials

    Science.gov (United States)

    Dalton, J. B.

    2010-06-01

    Remote sensing of icy objects in the outer solar system relies upon availability of appropriate laboratory measurements. Surface deposits of specific substances often provide our most direct route to understanding interior composition, thereby informing theories of endogenic surface modification, exogenic surface processing and processes involving exchange of material with the interiors. Visible to near-infrared reflectance spectra of properly prepared compounds are required to enable retrieval of surface abundances through linear and nonlinear mixture analysis applied to spacecraft observations of icy bodies. This chapter describes the techniques, conditions and approaches necessary to provide reference spectra of use to theoretical models of icy satellite surface compositions, and summarizes the current state of knowledge represented in the published literature.

  17. Surface analysis of selected hydrophobic materials

    Science.gov (United States)

    Wisniewska, Sylwia Katarzyna

    This dissertation contains a series of studies on hydrophobic surfaces by various surface sensitive techniques such as contact angle measurements, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and atomic force microscopy (AFM). Hydrophobic surfaces have been classified as mineral surfaces, organic synthetic surfaces, or natural biological surfaces. As a model hydrophobic mineral surface, elemental sulfur has been selected. The sulfur surface has been characterized for selected allotropic forms of sulfur such as rhombic, monoclinic, plastic, and cyclohexasulfur. Additionally, dextrin adsorption at the sulfur surface was measured. The structure of a dextrin molecule showing hydrophobic sites has been presented to support the proposed hydrophobic bonding nature of dextrin adsorption at the sulfur surface. As a model organic hydrophobic surface, primary fatty amines such as dodecylamine, hexadecylamine, and octadecylamine were chosen. An increase of hydrophobicity, significant changes of infrared bands, and surface topographical changes with time were observed for each amine. Based on the results it was concluded that hydrocarbon chain rearrangement associated with recrystallization took place at the surface during contact with air. A barley straw surface was selected as a model of biological hydrophobic surfaces. The differences in the contact angles for various straw surfaces were explained by the presence of a wax layer. SEM images confirmed the heterogeneity and complexity of the wax crystal structure. AFM measurements provided additional structural details including a measure of surface roughness. Additionally, straw degradation as a result of conditioning in an aqueous environment was studied. Significant contact angle changes were observed as soon as one day after conditioning. FTIR studies showed a gradual wax layer removal due to straw surface decomposition. SEM and AFM images revealed topographical changes and biological

  18. Material surface modification for first wall protection

    International Nuclear Information System (INIS)

    Davis, M.J.

    1979-01-01

    The elements and strategy of a program to develop low Z surfaces for tokamak reactors is described. The development of low Z coated limiters is selected as an interim goal. Candidate materials were selected from the elements: Be, B, Al, Ti, V, C, O, N and their compounds. The effect of low energy erosion on surface morphology is shown for Be, TiC and VBe 12 . The tradeoffs in coating design are described. Stress analysis results for TiB 2 coated POCO graphite limiters for ORNL's ISX-B tokamak are given

  19. Surface engineering of glazing materials and structures using plasma processes

    International Nuclear Information System (INIS)

    Anders, Andre; Monteiro, Othon R.

    2003-01-01

    A variety of coatings is commercially produced on a very large scale, including transparent conducting oxides and multi-layer silver-based low-emissivity and solar control coatings. A very brief review of materials and manufacturing process is presented and illustrated by ultrathin silver films and chevron copper films. Understanding the close relation between manufacturing processes and bulk and surface properties of materials is crucial for film growth and self-assembly processes

  20. Evaluation of the susceptibility to pitting corrosion of structural steels, including steels with modified surface

    International Nuclear Information System (INIS)

    Lunarska, E.; Nikiforow, K.

    2001-01-01

    Although the low alloy ferrite-perlite and bainite-martensite steels mostly undergo the general corrosion, pitting corrosion occurring under certain conditions jeopardizes the safety of installations, causing perforation of walls or initiation of crack. On the basis of electrochemical, corrosion and microscopic examinations, the conditions simulating typical industrial corrosion environments, containing Cl - ions have been selected, to which the parts of machines, devices and installation are subjected. The test parameters provide the preferential pitting corrosion without prevailing general corrosion, and provide the similar type of corrosion of different kinds of ferrite-perlite and bainite-martensite steels, including steels with modified surface layer. The proposed express method allows to evaluate the susceptibility to pitting corrosion and to evaluate the effect of surface modification on susceptibility to pitting corrosion in environments containing Cl - ions. The method may be applied for the proper selection of materials exploited under pitting corrosion conditions and for preparation of precorroded samples for mechanical testing. (author)

  1. Magnetic properties of Martian surface material

    Science.gov (United States)

    Hargraves, R. B.

    1984-01-01

    The hypothesis that the magnetic properties of the Martian surface material are due to the production of a magnetic phase in the clay mineral nontronite by transient shock heating is examined. In the course of the investigation a magnetic material is produced with rather unusual properties. Heating from 900 C to 1000 C, of natural samples of nontronite leads first to the production of what appears to be Si doped maghemite gamma (-Fe2O3). Although apparently metastable, the growth of gamma -Fe2O3 at these temprtures is unexpected, and its relative persistence of several hours at 1000 C is most surprising. Continued annealing of this material for longer periods promote the crystallization of alpha Fe2O3 and cristobalite (high temperature polymorph of SiO2). All available data correlate this new magnetic material with the cristobalite hence our naming it magnetic ferri cristobalite. Formation of this magnetic cristobalite, however, may require topotactic growth from a smectite precursor.

  2. Material, Mechanical, and Tribological Characterization of Laser-Treated Surfaces

    Science.gov (United States)

    Yilbas, Bekir Sami; Kumar, Aditya; Bhushan, Bharat; Aleem, B. J. Abdul

    2014-10-01

    Laser treatment under nitrogen assisting gas environment of cobalt-nickel-chromium-tungsten-based superalloy and high-velocity oxygen-fuel thermal spray coating of nickel-chromium-based superalloy on carbon steel was carried out to improve mechanical and tribological properties. Superalloy surface was preprepared to include B4C particles at the surface prior to the laser treatment process. Material and morphological changes in the laser-treated samples were examined using scanning electron microscopy, energy-dispersive spectroscopy, and x-ray diffraction (XRD) analysis. Residual stresses present at the surface region of the laser-treated layer were determined from the XRD data. The microhardness of the laser-treated surface was measured by indentation tests. Fracture toughness of the coating surfaces before and after laser treatment were also measured using overload indentation tests. Macrowear and macrofriction characterization were carried out using pin-on-disk tests.

  3. Materials surface damage and modification under high power plasma exposures

    Science.gov (United States)

    Garkusha, I.; Makhlaj, V.; Byrka, O.; Taran, V.; Voitsenya, V.; Malykhin, S.; Herashchenko, S.; Surovitskiy, S.; Nowakowska-Langier, K.; Sadowski, M. J.; Skladnik-Sadowska, E.; Terentyev, D.

    2018-01-01

    Influence of powerful plasma impacts on several materials used for the construction of energy systems, i.e. different grades of steels as well as tungsten coatings, has been discussed. Irradiations of these materials with hydrogen and helium plasma streams have been performed in several high-current-pulse and quasi-stationary plasma accelerators which provided the variation of a power load upon the exposed surface as well as changes of the particle flux in wide ranges: the energy flux density in the range of 1-25 MJ/m2, particle flux - up to 1026-1029 ion/m2s, the plasma stream velocity - up to about 500 km/s, and the pulse duration in the range of 1-250 μs. A response of the investigated materials to extreme plasma loads, which are relevant to transient events in fusion reactors, is briefly discussed. It is demonstrated that a broad combination of mechanisms of powerful plasma interactions with various materials includes not only a surface damage caused by different erosion mechanisms, but under certain conditions it may also result in a significant improvement of material properties in the near-surface surface layer of several tens-μm in thickness. Some improvement of the structure and substructure of such a layer may be caused by the high-speed quenching, the shock wave formation and material alloying with plasma- and coating-species. The creation of unique surface structures and a considerable improvement of physical and mechanical properties of different materials can be achieved by the pulsed plasma alloying, i.e. pre-deposited coating modifications and mixing caused by the impacting plasma streams.

  4. Switchable and responsive surfaces and materials for biomedical applications

    CERN Document Server

    Zhang, Johnathan

    2015-01-01

    Surface modification of biomaterials can ultimately determine whether a material is accepted or rejected from the human body, and a responsive surface can further make the material ""smart"" and ""intelligent"". Switchable and Responsive Surfaces and Materials for Biomedical Applications outlines synthetic and biological materials that are responsive under different stimuli, their surface design and modification techniques, and applicability in regenerative medicine/tissue engineering,  drug delivery, medical devices, and biomedical diagnostics. Part one provides a detailed overview of swit

  5. Shear bond strengths of tooth coating materials including the experimental materials contained various amounts of multi-ion releasing fillers and their effects for preventing dentin demineralization.

    Science.gov (United States)

    Arita, Shoko; Suzuki, Masaya; Kazama-Koide, Miku; Shinkai, Koichi

    2017-10-01

    We examined shear bond strengths (SBSs) of various tooth-coating-materials including the experimental materials to dentin and demineralization resistance of a fractured adhesive surface after the SBS testing. Three resin-type tooth-coating-materials (BC, PRG Barrier Coat; HC, Hybrid Coat II; and SF, Shield force plus) and two glass-ionomer-type tooth-coating-materials (CV, Clinpro XT Varnish; and FJ, Fuji VII) were selected. The experimental PRG Barrier Coat containing 0, 17, and 33 wt% S-PRG filler (BC0, BC17, and BC33, respectively) were developed. Each tooth-coating-material was applied to flattened dentin surfaces of extracted human teeth for SBS testing. After storing in water for 32 days with 4000 thermal cycling, the specimens were subjected to the SBS test. Specimens after SBS testing were subjected to a pH cycling test, and then, demineralization depths were measured using a polarized-light microscope. ANOVA and Tukey's HSD test were used for statistical analysis. The SBS value of FJ and CV was significantly lower than those of other materials except for BC (p coating-materials demonstrated significantly higher SBS for dentin than the glass-ionomer-type tooth-coating-materials; however, they were inferior to the glass ionomer-type tooth-coating-materials in regards to the acid resistance of the fractured adhesion surface.

  6. Enzyme-enabled responsive surfaces for anti-contamination materials.

    Science.gov (United States)

    Wu, Songtao; Buthe, Andreas; Jia, Hongfei; Zhang, Minjuan; Ishii, Masahiko; Wang, Ping

    2013-06-01

    Many real-life stains have origins from biological matters including proteins, lipids, and carbohydrates that act as gluing agents binding along with other particulates or microbes to exposed surfaces of automobiles, furniture, and fabrics. Mimicking naturally occurring self-defensive processes, we demonstrate in this work that a solid surface carrying partially exposed enzyme granules protected the surface in situ from contamination by biological stains and fingerprints. Attributed to the activities of enzymes which can be made compatible with a wide range of materials, such anti-contamination and self-cleaning functionalities are highly selective and efficient toward sticky chemicals. This observation promises a new mechanism in developing smart materials with desired anti-microbial, self-reporting, self-cleaning, or self-healing functions. Copyright © 2013 Wiley Periodicals, Inc.

  7. Surface and Interface Physics of Correlated Electron Materials

    Energy Technology Data Exchange (ETDEWEB)

    Millis, Andrew [Columbia Univ., New York, NY (United States)

    2004-09-01

    The {\\it Surface and Interface Physics of Correlated Electron Materials} research program provided conceptual understanding of and theoretical methodologies for understanding the properties of surfaces and interfaces involving materials exhibiting strong electronic correlations. The issues addressed in this research program are important for basic science, because the behavior of correlated electron superlattices is a crucial challenge to and crucial test of our understanding of the grand-challenge problem of correlated electron physics and are important for our nation's energy future because correlated interfaces offer opportunities for the control of phenomena needed for energy and device applications. Results include new physics insights, development of new methods, and new predictions for materials properties.

  8. Phenomenology of surface arcs on spacecraft dielectric materials

    Science.gov (United States)

    Balmain, K. G.; Gossland, M.; Reeves, R. D.; Kuller, W. G.

    1982-01-01

    For electron beam incidence on large specimens of Kapton thermal blanket material, surface arc discharges are shown to cause damage consisting of punchthrough holes which act as focal points for other types of damage, including subsurface tunnels, blowout holes and surface breakup. Under electron bombardment, dielectric sheet specimens separated by a gap are shown to discharge simultaneously. Teflon specimens which have been brushed or rubbed are shown to exhibit directional guidance of discharge arcs, and this phenomenon has been used to generate straight arcs whose velocities have been measured optically.

  9. Systems and Methods for Fabricating Structures Including Metallic Glass-Based Materials Using Low Pressure Casting

    Science.gov (United States)

    Hofmann, Douglas C. (Inventor); Kennett, Andrew (Inventor)

    2018-01-01

    Systems and methods to fabricate objects including metallic glass-based materials using low-pressure casting techniques are described. In one embodiment, a method of fabricating an object that includes a metallic glass-based material includes: introducing molten alloy into a mold cavity defined by a mold using a low enough pressure such that the molten alloy does not conform to features of the mold cavity that are smaller than 100 microns; and cooling the molten alloy such that it solidifies, the solid including a metallic glass-based material.

  10. Determining Surface Material Properties Using Satellite Imaging

    Science.gov (United States)

    Gloudeman, C.; Gerace, A. D.

    2017-12-01

    Knowledge of soil moisture content is necessary for drought monitoring, crop irrigation, and water runoff. Remote sensing techniques provide a more efficient alternative to traditional field measurements for determining soil moisture content. Thermal infrared sensors from Landsat, MODIS Aqua & Terra, and AVHRR MetOp A & B satellites were used to find thermal inertia, which is highly correlated with soil moisture. A diurnal cycle is converted from band effective radiance to Land Surface Temperature (LST) using Planck's Law for blackbody radiation and a modified split-window algorithm. The THERM model for finding expected LST is then used to determine the material properties. A second approach was used to calculate apparent thermal inertia and soil moisture content from day/ night pairs of LST. For this method, only the MODIS Aqua LST product was used.To this end, we have observed clear differences in moisture between areas of vegetation and sand and between different crop fields. Our results indicate that matching the observed data with the THERM model could be improved with increased satellite measurements.

  11. Microwave effective surface impedance of structures including a high-Tc superconducting film

    International Nuclear Information System (INIS)

    Hartemann, P.

    1992-01-01

    The microwave effective surface impedances of different stacks made of high-temperature superconducting films, dielectric materials and bulk normal metals were computed. The calculations were based on the two-fluid model of superconductors and the conventional transmission line theory. These effective impedances are compared to the calculated intrinsic surface impedances of the stacked superconducting films. The considered superconducting material has been the oxide YBa 2 Cu 3 O 7 epitaxially grown on crystalline substrates (MgO, LaAlO 3 , SrTiO 3 ), the film thickness ranging from a few nm to 1μm. Discrepancies between the effective surface resistances or reactances and the corresponding intrinsic values were determined at 10 GHz for non resonant or resonant structures. At resonance the surface resistance discrepancy exhibits a sharp peak which reaches 10 4 or more in relative value according to the geometry and the used materials. Obviously the effective surface reactance shows also huge variations about the resonance and may be negative. Moreover geometries allowing to obtain an effective resistance smaller than the film intrinsic value have been found. The effects of the resonance phenomenon on the electromagnetic wave reflectivity and reflection phase shift are investigated. Therefore the reported theoretical results demonstrate that the effective surface impedance of YBCO films with a thickness smaller than 500 nm can be very different from the intrinsic film impedance according to the structures. (Author). 3 refs., 10 figs., 2 tabs

  12. Implant surface material, design, and osseointegration.

    Science.gov (United States)

    Ogle, Orrett E

    2015-04-01

    The structural and functional union of the implant with living bone is greatly influenced by the surface properties of the implant. The success of a dental implant depends on the chemical, physical, mechanical, and topographic characteristics of its surface. The influence of surface topography on osseointegration has translated to shorter healing times from implant placement to restoration. This article presents a discussion of surface characteristics and design of implants, which should allow the clinician to better understand osseointegration and information coming from implant manufacturers, allowing for better implant selection. Copyright © 2015 Elsevier Inc. All rights reserved.

  13. Nonlocal continuum-based modeling of breathing mode of nanowires including surface stress and surface inertia effects

    International Nuclear Information System (INIS)

    Ghavanloo, Esmaeal; Fazelzadeh, S. Ahmad; Rafii-Tabar, Hashem

    2014-01-01

    Nonlocal and surface effects significantly influence the mechanical response of nanomaterials and nanostructures. In this work, the breathing mode of a circular nanowire is studied on the basis of the nonlocal continuum model. Both the surface elastic properties and surface inertia effect are included. Nanowires can be modeled as long cylindrical solid objects. The classical model is reformulated using the nonlocal differential constitutive relations of Eringen and Gurtin–Murdoch surface continuum elasticity formalism. A new frequency equation for the breathing mode of nanowires, including small scale effect, surface stress and surface inertia is presented by employing the Bessel functions. Numerical results are computed, and are compared to confirm the validity and accuracy of the proposed method. Furthermore, the model is used to elucidate the effect of nonlocal parameter, the surface stress, the surface inertia and the nanowire orientation on the breathing mode of several types of nanowires with size ranging from 0.5 to 4 nm. Our results reveal that the combined surface and small scale effects are significant for nanowires with diameter smaller than 4 nm.

  14. Nonlocal continuum-based modeling of breathing mode of nanowires including surface stress and surface inertia effects

    Science.gov (United States)

    Ghavanloo, Esmaeal; Fazelzadeh, S. Ahmad; Rafii-Tabar, Hashem

    2014-05-01

    Nonlocal and surface effects significantly influence the mechanical response of nanomaterials and nanostructures. In this work, the breathing mode of a circular nanowire is studied on the basis of the nonlocal continuum model. Both the surface elastic properties and surface inertia effect are included. Nanowires can be modeled as long cylindrical solid objects. The classical model is reformulated using the nonlocal differential constitutive relations of Eringen and Gurtin-Murdoch surface continuum elasticity formalism. A new frequency equation for the breathing mode of nanowires, including small scale effect, surface stress and surface inertia is presented by employing the Bessel functions. Numerical results are computed, and are compared to confirm the validity and accuracy of the proposed method. Furthermore, the model is used to elucidate the effect of nonlocal parameter, the surface stress, the surface inertia and the nanowire orientation on the breathing mode of several types of nanowires with size ranging from 0.5 to 4 nm. Our results reveal that the combined surface and small scale effects are significant for nanowires with diameter smaller than 4 nm.

  15. Material fluxes on the surface of the earth

    National Research Council Canada - National Science Library

    National Research Council Staff; Commission on Geosciences, Environment and Resources; Division on Earth and Life Studies; Board on Earth Sciences & Resources; National Research Council; National Academy of Sciences

    ...) level of surficial fluxes and their dynamics. Leading experts in the field offer a historical perspective on geofluxes and discuss the cycles of materials on the earth's surface, from weathering processes to the movement of material...

  16. TANK FARM INTERIM SURFACE BARRIER MATERIALS AND RUNOFF ALTERNATIVES STUDY

    Energy Technology Data Exchange (ETDEWEB)

    HOLM MJ

    2009-06-25

    This report identifies candidate materials and concepts for interim surface barriers in the single-shell tank farms. An analysis of these materials for application to the TY tank farm is also provided.

  17. Tank Farm Interim Surface Barrier Materials And Runoff Alternatives Study

    International Nuclear Information System (INIS)

    Holm, M.J.

    2009-01-01

    This report identifies candidate materials and concepts for interim surface barriers in the single-shell tank farms. An analysis of these materials for application to the TY tank farm is also provided.

  18. Nanocoating of titanium implant surfaces with organic molecules. Polysaccharides including glycosaminoglycans

    DEFF Research Database (Denmark)

    Gurzawska, Katarzyna Aleksandra; Svava, Rikke; Jørgensen, Niklas Rye

    2012-01-01

    Long-term stability of titanium implants are dependent on a variety of factors. Nanocoating with organic molecules is one of the method used to improve osseointegration. Nanoscale modification of titanium implants affects surface properties, such as hydrophilicity, biochemical bonding capacity...... with focus on polysaccharides including glycosaminoglycans, and how these molecules change surface properties, cell reactions and affect on osseointegartion. The included in vitro studies demonstrated increased cell adhesion, proliferation and mineralization of a number of the tested polysaccharide...

  19. Hayabusa2 Sampler: Collection of Asteroidal Surface Material

    Science.gov (United States)

    Sawada, Hirotaka; Okazaki, Ryuji; Tachibana, Shogo; Sakamoto, Kanako; Takano, Yoshinori; Okamoto, Chisato; Yano, Hajime; Miura, Yayoi; Abe, Masanao; Hasegawa, Sunao; Noguchi, Takaaki

    2017-07-01

    Japan Aerospace Exploration Agency (JAXA) launched the asteroid exploration probe "Hayabusa2" in December 3rd, 2014, following the 1st Hayabusa mission. With technological and scientific improvements from the Hayabusa probe, we plan to visit the C-type asteroid 162137 Ryugu (1999 JU3), and to sample surface materials of the C-type asteroid that is likely to be different from the S-type asteroid Itokawa and contain more pristine materials, including organic matter and/or hydrated minerals, than S-type asteroids. We developed the Hayabusa2 sampler to collect a minimum of 100 mg of surface samples including several mm-sized particles at three surface locations without any severe terrestrial contamination. The basic configuration of the sampler design is mainly as same as the 1st Hayabusa (Yano et al. in Science, 312(5778):1350-1353, 2006), with several minor but important modifications based on lessons learned from the Hayabusa to fulfill the scientific requirements and to raise the scientific value of the returned samples.

  20. Alternative surfacing materials for weed control at BC Hydro substations

    International Nuclear Information System (INIS)

    Wells, T.C.; Shrimpton, G.M.

    1997-01-01

    A two year study was conducted by BC Hydro in which a variety of surfacing materials were tested for their suitability for use in substations. Ideally, surfacing materials should have the following characteristics: high electrical resistivity in both dry and wet conditions, resistance to invasion by weeds, good driveability, good drainage, non-flammable, reasonably priced, no dust to foul conductors, and be aesthetically pleasing. Trials at Vernon Koksilah, and Ingledow substations were conducted to test the materials. A qualitative estimate of the amount of weed control provided by each material was recorded. The trials were meant to provide operational recommendations and screening information to allow for future testing of promising materials or combination of materials. Results showed that no single material meets all the desired criteria. The surfaces that best combined good weed control, electrical resistance and surface stability was a 15 cm deep layer of crushed gravel, especially if underlain by a layer of geotextile. 4 refs., 3 tabs., 1 fig

  1. Investigations of the surface resistance of superconducting materials

    International Nuclear Information System (INIS)

    Junginger, Tobias

    2012-01-01

    In particle accelerators superconducting RF cavities are widely used to achieve high accelerating gradients and low losses. Power consumption is proportional to the surface resistance R S which depends on a number of external parameters, including frequency, temperature, magnetic and electric field. Presently, there is no widely accepted model describing the increase of R S with applied field. In the frame of this project the 400 MHz Quadrupole Resonator has been extended to 800 and 1200 MHz to study surface resistance and intrinsic critical RF magnetic field of superconducting samples over a wide parameter range, establishing it as a world-wide unique test facility for superconducting materials. Different samples were studied and it was shown that R S is mainly caused by the RF electric field in the case of strongly oxidized surfaces. This can be explained by interface tunnel exchange of electrons between the superconductor and localized states in adjacent oxides. For well prepared surfaces, however, the majority of the dissipation is caused by the magnetic field and R S factorizes into field and temperature dependent parts. These different loss mechanisms were correlated to surface topography of the samples and distribution of oxides by using ultrasonic force microscopy and X-ray photon spectroscopy.

  2. A light reflecting apparatus including a multi-aberration light reflecting surface

    Science.gov (United States)

    Sawicki, R.H.; Sweatt, W.

    1985-11-21

    A light reflecting apparatus including a multi-aberration bendable light reflecting surface is disclosed herein. This apparatus includes a structural assembly comprised of a rectangular plate which is resiliently bendable, to a limited extent, and which has a front side defining the multi-aberration light reflecting surface and an opposite back side, and a plurality of straight leg members rigidly connected with the back side of the plate and extending rearwardly therefrom. The apparatus also includes a number of different adjustment mechanisms, each of which is connected with specific ones of the leg members. These mechanisms are adjustably movable in different ways for applying corresponding forces to the leg members in order to bend the rectangular plate and light reflecting surface into different predetermined curvatures and which specifically include quadratic and cubic curvatures corresponding to different optical aberrations.

  3. Surface chemical modification for exceptional wear life of MEMS materials

    Directory of Open Access Journals (Sweden)

    R. Arvind Singh

    2011-12-01

    Full Text Available Micro-Electro-Mechanical-Systems (MEMS are built at micro/nano-scales. At these scales, the interfacial forces are extremely strong. These forces adversely affect the smooth operation and cause wear resulting in the drastic reduction in wear life (useful operating lifetime of actuator-based devices. In this paper, we present a surface chemical modification method that reduces friction and significantly extends the wear life of the two most popular MEMS structural materials namely, silicon and SU-8 polymer. The method includes surface chemical treatment using ethanolamine-sodium phosphate buffer, followed by coating of perfluoropolyether (PFPE nanolubricant on (i silicon coated with SU-8 thin films (500 nm and (ii MEMS process treated SU-8 thick films (50 μm. After the surface chemical modification, it was observed that the steady-state coefficient of friction of the materials reduced by 4 to 5 times and simultaneously their wear durability increased by more than three orders of magnitude (> 1000 times. The significant reduction in the friction coefficients is due to the lubrication effect of PFPE nanolubricant, while the exceptional increase in their wear life is attributed to the bonding between the -OH functional group of ethanolamine treated SU-8 thin/thick films and the -OH functional group of PFPE. The surface chemical modification method acts as a common route to enhance the performance of both silicon and SU-8 polymer. It is time-effective (process time ≤ 11 min, cost-effective and can be readily integrated into MEMS fabrication/assembly processes. It can also work for any kind of structural material from which the miniaturized devices are/can be made.

  4. Surface Characteristics and Biofilm Development on Selected Dental Ceramic Materials

    Directory of Open Access Journals (Sweden)

    Kyoung H. Kim

    2017-01-01

    Full Text Available Background. Intraoral adjustment and polishing of dental ceramics often affect their surface characteristics, promoting increased roughness and consequent biofilm growth. This study correlated surface roughness to biofilm development with four commercially available ceramic materials. Methods. Four ceramic materials (Vita Enamic®, Lava™ Ultimate, Vitablocs Mark II, and Wieland Reflex® were prepared as per manufacturer instructions. Seventeen specimens of each material were adjusted and polished to simulate clinical intraoral procedures and another seventeen remained unaltered. Specimens were analysed by SEM imaging, confocal microscopy, and crystal violet assay. Results. SEM images showed more irregular surface topography in adjusted specimens than their respective controls. Surface roughness (Ra values were greater in all materials following adjustments. All adjusted materials with the exception of Vitablocs Mark II promoted significantly greater biofilm growth relative to controls. Conclusion. Simulated intraoral polishing methods resulted in greater surface roughness and increased biofilm accumulation.

  5. Facet‐Engineered Surface and Interface Design of Photocatalytic Materials

    Science.gov (United States)

    Wang, Lili; Li, Zhengquan

    2016-01-01

    The facet‐engineered surface and interface design for photocatalytic materials has been proven as a versatile approach to enhance their photocatalytic performance. This review article encompasses some recent advances in the facet engineering that has been performed to control the surface of mono‐component semiconductor systems and to design the surface and interface structures of multi‐component heterostructures toward photocatalytic applications. The review begins with some key points which should receive attention in the facet engineering on photocatalytic materials. We then discuss the synthetic approaches to achieve the facet control associated with the surface and interface design. In the following section, the facet‐engineered surface design on mono‐component photocatalytic materials is introduced, which forms a basis for the discussion on more complex systems. Subsequently, we elucidate the facet‐engineered surface and interface design of multi‐component photocatalytic materials. Finally, the existing challenges and future prospects are discussed. PMID:28105398

  6. Surface properties of copper based cermet materials

    International Nuclear Information System (INIS)

    Voinea, M.; Vladuta, C.; Bogatu, C.; Duta, A.

    2008-01-01

    The paper presents the characterization of the surface properties of copper based cermets obtained by two different techniques: spray pyrolysis deposition (SPD) and electrodeposition. Copper acetate was used as precursor of Cu/CuO x cermet. The surface morphology was tailored by adding copolymers of maleic anhydride with controlled hydrophobia. The films morphology of Cu/CuO x was assessed using contact angle measurements and AFM analysis. The porous structures obtained via SPD lead to higher liquid adsorption rate than the electrodeposited films. A highly polar liquid - water is recommended as testing liquid in contact angle measurements, for estimating the porosity of copper based cermets, while glycerol can be used to distinguish among ionic and metal predominant structures. Thus, contact angle measurements can be used for a primary evaluation of the films morphology and, on the other hand, of the ratio between the cermet components

  7. Surface properties of copper based cermet materials

    Energy Technology Data Exchange (ETDEWEB)

    Voinea, M. [The Centre: Product Design for Sustainable Development, Transilvania University of Brasov, Eroilor 29, 500036 (Romania)], E-mail: m.voinea@unitbv.ro; Vladuta, C.; Bogatu, C.; Duta, A. [The Centre: Product Design for Sustainable Development, Transilvania University of Brasov, Eroilor 29, 500036 (Romania)

    2008-08-25

    The paper presents the characterization of the surface properties of copper based cermets obtained by two different techniques: spray pyrolysis deposition (SPD) and electrodeposition. Copper acetate was used as precursor of Cu/CuO{sub x} cermet. The surface morphology was tailored by adding copolymers of maleic anhydride with controlled hydrophobia. The films morphology of Cu/CuO{sub x} was assessed using contact angle measurements and AFM analysis. The porous structures obtained via SPD lead to higher liquid adsorption rate than the electrodeposited films. A highly polar liquid - water is recommended as testing liquid in contact angle measurements, for estimating the porosity of copper based cermets, while glycerol can be used to distinguish among ionic and metal predominant structures. Thus, contact angle measurements can be used for a primary evaluation of the films morphology and, on the other hand, of the ratio between the cermet components.

  8. Experience in nuclear materials accountancy, including the use of computers, in the UKAEA

    International Nuclear Information System (INIS)

    Anderson, A.R.; Adamson, A.S.; Good, P.T.; Terrey, D.R.

    1976-01-01

    The UKAEA have operated systems of nuclear materials accountancy in research and development establishments handling large quantities of material for over 20 years. In the course of that time changing requirements for nuclear materials control and increasing quantities of materials have required that accountancy systems be modified and altered to improve either the fundamental system or manpower utilization. The same accountancy principles are applied throughout the Authority but procedures at the different establishments vary according to the nature of their specific requirements; there is much in the cumulative experience of the UKAEA which could prove of value to other organizations concerned with nuclear materials accountancy or safeguards. This paper reviews the present accountancy system in the UKAEA and summarizes its advantages. Details are given of specific experience and solutions which have been found to overcome difficulties or to strengthen previous weak points. Areas discussed include the use of measurements, the establishment of measurement points (which is relevant to the designation of MBAs), the importance of regular physical stock-taking, and the benefits stemming from the existence of a separate accountancy section independent of operational management at large establishments. Some experience of a dual system of accountancy and criticality control is reported, and the present status of computerization of nuclear material accounts is summarized. Important aspects of the relationship between management systems of accountancy and safeguards' requirements are discussed briefly. (author)

  9. New Nuclear Materials Including Non Metallic Fuel Elements. Vol. II. Proceedings of the Conference on New Nuclear Materials Technology, Including Non Metallic Fuel Elements

    International Nuclear Information System (INIS)

    1963-01-01

    One of the major aims of the International Atomic Energy Agency in furthering the peaceful uses of atomic energy is to encourage the development of economical nuclear power. Certainly, one of the more obvious methods of producing economical nuclear power is the development of economical fuels that can be used at high temperatures for long periods of time, and which have sufficient strength and integrity to operate under these conditions without permitting the release of fission products. In addition it is desirable that after irradiation these new fuels be economically reprocessed to reduce further the cost of the fuel cycle. As nuclear power becomes more and more competitive with conventional power the interest in new and more efficient higher-temperature fuels naturally increases rapidly. For these reasons, the Agency organized a Conference on New Nuclear Materials Technology, Including Non-Metallic Fuel Elements, which was held from 1 to 5 July 1963 at the International Hotel, Prague, with the assistance and co-operation of the Government of the Czechoslovak Socialist Republic. A total of 151 scientists attended, from 23 countries and 4 international organizations. The participants heard and discussed more than 60 scientific papers. The Agency wishes to thank the scientists who attended this Conference for their papers and for many spirited discussions that truly mark a successful meeting. The Agency wishes also to record its gratitude for the assistance and generous hospitality accorded the Conference, the participants and the Agency's staff by the Government of the Czechoslovak Socialist Republic and by the people of Prague. The scientific information contained in these Proceedings should help to quicken the pace of progress in the fabrication of new and m ore economical fuels, and it is hoped that these proceedings will be found useful to all workers in this and related fields

  10. Full-dimensional diabatic potential energy surfaces including dissociation: the ²E″ state of NO₃.

    Science.gov (United States)

    Eisfeld, Wolfgang; Vieuxmaire, Olivier; Viel, Alexandra

    2014-06-14

    A scheme to produce accurate full-dimensional coupled diabatic potential energy surfaces including dissociative regions and suitable for dynamical calculations is proposed. The scheme is successfully applied to model the two-sheeted surface of the (2)E″ state of the NO3 radical. An accurate potential energy surface for the NO₃⁻ anion ground state is developed as well. Both surfaces are based on high-level ab initio calculations. The model consists of a diabatic potential matrix, which is expanded to higher order in terms of symmetry polynomials of symmetry coordinates. The choice of coordinates is key for the accuracy of the obtained potential energy surfaces and is discussed in detail. A second central aspect is the generation of reference data to fit the expansion coefficients of the model for which a stochastic approach is proposed. A third ingredient is a new and simple scheme to handle problematic regions of the potential energy surfaces, resulting from the massive undersampling by the reference data unavoidable for high-dimensional problems. The final analytical diabatic surfaces are used to compute the lowest vibrational levels of NO₃⁻ and the photo-electron detachment spectrum of NO₃⁻ leading to the neutral radical in the (2)E″ state by full dimensional multi-surface wave-packet propagation for NO3 performed using the Multi-Configuration Time Dependent Hartree method. The achieved agreement of the simulations with available experimental data demonstrates the power of the proposed scheme and the high quality of the obtained potential energy surfaces.

  11. Improving weather predictability by including land-surface model parameter uncertainty

    Science.gov (United States)

    Orth, Rene; Dutra, Emanuel; Pappenberger, Florian

    2016-04-01

    The land surface forms an important component of Earth system models and interacts nonlinearly with other parts such as ocean and atmosphere. To capture the complex and heterogenous hydrology of the land surface, land surface models include a large number of parameters impacting the coupling to other components of the Earth system model. Focusing on ECMWF's land-surface model HTESSEL we present in this study a comprehensive parameter sensitivity evaluation using multiple observational datasets in Europe. We select 6 poorly constrained effective parameters (surface runoff effective depth, skin conductivity, minimum stomatal resistance, maximum interception, soil moisture stress function shape, total soil depth) and explore their sensitivity to model outputs such as soil moisture, evapotranspiration and runoff using uncoupled simulations and coupled seasonal forecasts. Additionally we investigate the possibility to construct ensembles from the multiple land surface parameters. In the uncoupled runs we find that minimum stomatal resistance and total soil depth have the most influence on model performance. Forecast skill scores are moreover sensitive to the same parameters as HTESSEL performance in the uncoupled analysis. We demonstrate the robustness of our findings by comparing multiple best performing parameter sets and multiple randomly chosen parameter sets. We find better temperature and precipitation forecast skill with the best-performing parameter perturbations demonstrating representativeness of model performance across uncoupled (and hence less computationally demanding) and coupled settings. Finally, we construct ensemble forecasts from ensemble members derived with different best-performing parameterizations of HTESSEL. This incorporation of parameter uncertainty in the ensemble generation yields an increase in forecast skill, even beyond the skill of the default system. Orth, R., E. Dutra, and F. Pappenberger, 2016: Improving weather predictability by

  12. Implementation of solar-reflective surfaces: Materials and utility programs

    Energy Technology Data Exchange (ETDEWEB)

    Bretz, S.; Akbari, H.; Rosenfeld, A.; Taha, H.

    1992-06-01

    This report focuses on implementation issues for using solar-reflective surfaces to cool urban heat islands, with specific examples for Sacramento, California. Advantages of solar-reflective surfaces for reducing energy use are: (1) they are cost-effective if albedo is increased during routine maintenance; (2) the energy savings coincide with peak demand for power; (3) there are positive effects on environmental quality; and (4) the white materials have a long service life. Important considerations when choosing materials for mitigating heat islands are identified as albedo, emissivity, durability, cost, pollution and appearance. There is a potential for increasing urban albedo in Sacramento by an additional 18%. Of residential roofs, we estimate that asphalt shingle and modified bitumen cover the largest area, and that built-up roofing and modified bitumen cover the largest area of commercial buildings. For all of these roof types, albedo may be increased at the time of re-roofing without any additional cost. When a roof is repaired, a solar-reflective roof coating may be applied to significantly increase albedo and extend the life of the root Although a coating may be cost-effective if applied to a new roof following installation or to an older roof following repair, it is not cost-effective if the coating is applied only to save energy. Solar-reflective pavement may be cost-effective if the albedo change is included in the routine resurfacing schedule. Cost-effective options for producing light-colored pavement may include: (1) asphalt concrete, if white aggregate is locally available; (2) concrete overlays; and (3) newly developed white binders and aggregate. Another option may be hot-rolled asphalt, with white chippings. Utilities could promote solar-reflective surfaces through advertisement, educational programs and cost-sharing of road resurfacing.

  13. Roughness, surface energy, and superficial damages of CAD/CAM materials after surface treatment.

    Science.gov (United States)

    Strasser, Thomas; Preis, Verena; Behr, Michael; Rosentritt, Martin

    2018-02-05

    The aim of this study was to examine the effects of surface pre-treatment on CAD/CAM materials including ceramics, zirconia, resin-infiltrated ceramic, and resin-based composite. Specimens were made of ten CAD/CAM materials (Celtra Duo, Degudent, D; Vita Suprinity, Vita, D; E.max CAD, Ivoclar-Vivadent, FL; E.max ZirCAD, Ivoclar-Vivadent, FL; Vita Enamic, Vita, D; Cerasmart, GC, B; LAVA Ultimate, 3M, D; SHOFU Block HC, SHOFU, US; Grandio Blocs, VOCO, D; BRILLIANT Crios, Coltene, CH) and pretreated to represent clinical procedures (Hf 20 s/5%; phosphoric acid 20 s/37%; Monobond etch and prime (Ivoclar-Vivadent, FL); water-cooled diamond bur (80 μm; 4 μm); Al 2 O 3 -blasting (50 μm/1 bar, 50 μm/2 bar, 120 μm/1 bar, 120 μm/2 bar); untreated; manufacturer's instructions). SEM-analysis (Phenom, FEI, NL) of the surfaces was performed (magnifications ≤ 10,000×). Roughness values R a , R z (KJ 3D, Keyence, J), and surface energy SE (OCA15 plus, SCA20, DataPhysics, D) were determined (statistics: non-parametric Mann-Whitney U test/Kruskal-Wallis test for independent specimen, α = 0.05). Kruskal-Wallis revealed significant (p CAD/CAM materials require individual pre-treatment for optimized and protective surface activation. Cementation is a key factor for clinical success. Given the variety of available CAD/CAM materials, specific procedures are needed.

  14. Systems and methods for producing metal clusters; functionalized surfaces; and droplets including solvated metal ions

    Science.gov (United States)

    Cooks, Robert Graham; Li, Anyin; Luo, Qingjie

    2017-08-01

    The invention generally relates to systems and methods for producing metal clusters; functionalized surfaces; and droplets including solvated metal ions. In certain aspects, the invention provides methods that involve providing a metal and a solvent. The methods additionally involve applying voltage to the solvated metal to thereby produce solvent droplets including ions of the metal containing compound, and directing the solvent droplets including the metal ions to a target. In certain embodiments, once at the target, the metal ions can react directly or catalyze reactions.

  15. Statistics of ductile fracture surfaces: the effect of material parameters

    DEFF Research Database (Denmark)

    Ponson, Laurent; Cao, Yuanyuan; Bouchaud, Elisabeth

    2013-01-01

    distributed. The three dimensional analysis permits modeling of a three dimensional material microstructure and of the resulting three dimensional stress and deformation states that develop in the fracture process region. Material parameters characterizing void nucleation are varied and the statistics......The effect of material parameters on the statistics of fracture surfaces is analyzed under small scale yielding conditions. Three dimensional calculations of ductile crack growth under mode I plane strain, small scale yielding conditions are carried out using an elastic-viscoplastic constitutive...... of the resulting fracture surfaces is investigated. All the fracture surfaces are found to be self-affine over a size range of about two orders of magnitude with a very similar roughness exponent of 0.56 ± 0.03. In contrast, the full statistics of the fracture surfaces is found to be more sensitive to the material...

  16. Modification of Material Surface Using Plasma-Enhanced Ion Beams

    National Research Council Canada - National Science Library

    Bystritskii, V

    1998-01-01

    ...) Technology for Materials Surface Modification. Following second year programmatic plan, formulated in the conclusion of the 1-st year report we focused our effort on study of aluminum alloys modification (Al2024, 6061, 7075...

  17. Contact mechanics for layered materials with randomly rough surfaces.

    Science.gov (United States)

    Persson, B N J

    2012-03-07

    The contact mechanics model of Persson is applied to layered materials. We calculate the M function, which relates the surface stress to the surface displacement, for a layered material, where the top layer (thickness d) has different elastic properties than the semi-infinite solid below. Numerical results for the contact area as a function of the magnification are presented for several cases. As an application, we calculate the fluid leak rate for laminated rubber seals.

  18. Managing nuclear knowledge: IAEA activities and international coordination. Including resource material full text CD-ROM

    International Nuclear Information System (INIS)

    2005-06-01

    The present CD-ROM summarizes some activities carried out by the Departments of Nuclear Energy and Nuclear Safety and Security in the area of nuclear knowledge management in the period 2003-2005. It comprises, as open resource, most of the relevant documents in full text, including policy level documents, reports, presentation material by Member States and meeting summaries. The collection starts with a reprint of the report to the IAEA General Conference 2004 on Nuclear Knowledge [GOV/2004/56-GC(48)/12] summarizing the developments in nuclear knowledge management since the 47th session of the General Conference in 2003 and covers Managing Nuclear Knowledge including safety issues and Information and Strengthening Education and Training for Capacity Building. It contains an excerpt on Nuclear Knowledge from the General Conference Resolution [GC(48)/RES/13] on Strengthening the Agency's Activities Related to Nuclear Science, Technology and Applications. On the CD-ROM itself, all documents can easily be accessed by clicking on their titles on the subject pages (also printed at the end of this Working Material). Part 1 of the CD-ROM covers the activities in the period 2003-2005 and part 2 presents a resource material full text CD-ROM on Managing Nuclear Knowledge issued in October 2003

  19. Influence of starting material particle size on pellet surface roughness.

    Science.gov (United States)

    Sarkar, Srimanta; Ang, Bee Hwee; Liew, Celine Valeria

    2014-02-01

    The purpose of this study was to investigate the effect of pelletization aids, i.e., microcrystalline cellulose (MCC) and cross-linked polyvinyl pyrrolidone (XPVP), and filler, i.e., lactose, particle size on the surface roughness of pellets. Pellets were prepared from powder blends containing pelletization aid/lactose in 1:3 ratio by extrusion-spheronization. Surface roughness of pellets was assessed quantitatively and qualitatively using optical interferometry and scanning electron microscopy, respectively. Both quantitative and qualitative surface studies showed that surface roughness of pellets depended on the particle size of XPVP and lactose used in the formulation. Increase in XPVP or lactose particle size resulted in rougher pellets. Formulations containing MCC produced pellets with smoother surfaces than those containing XPVP. Furthermore, surface roughness of the resultant pellets did not appear to depend on MCC particle size. Starting material particle size was found to be a critical factor for determining the surface roughness of pellets produced by extrusion-spheronization. Smaller particles can pack well with lower peaks and valleys, resulting in pellets with smoother surfaces. Similar surface roughness of pellets containing different MCC grades could be due to the deaggregation of MCC particles into smaller subunits with more or less similar sizes during wet processing. Hence, for starting materials that deaggregate during the wet processing, pellet surface roughness is influenced by the particle size of the material upon deaggregation.

  20. Three Peaks of 2011 Draconid Activity Including that Connected with Pre-1900 Material

    Science.gov (United States)

    Koten, Pavel; Vaubaillon, Jeremie; Tóth, Juraj; Margonis, Anastasios; Ďuriš, František

    2014-08-01

    A Draconid meteor shower outburst was observed from on board two scientific aircraft deployed above Northern Europe on 8th October 2011. The activity profile was measured using a set of photographic and video cameras. The main peak of the activity occurred around 20:15 ± 0:0.5 UT which is consistent with the model prediction as well as with the IMO network visual observations. The corrected hourly rates reached a value of almost 350. The brighter meteors peaked about 15-20 min earlier than the dimmer ones. This difference can be explained by different directions of the ejection of the meteoroids from the parent comet. One of the instruments was even able to detect meteors connected with the material ejected from the parent comet before 1900 and thus confirmed the prediction of the model, although it was based on uncertain pre-1900 cometary data. Another small peak of the activity, which was caused by material ejected during the 1926 perihelion passage of the parent comet, was detected around 21:10 UT. The mass distribution index determined using the narrow field-of-view video camera was 2.0 ± 0.1. This work shows that the observation of meteor outbursts can constrain the orbital elements, outgassing activity and existence of jets at the surface of a comet.

  1. Removal of PCB from indoor air and surface materials by introduction of additional sorbing materials

    DEFF Research Database (Denmark)

    Gunnarsen, Lars Bo; Lyng, Nadja; Kolarik, Barbara

    2017-01-01

    Alleviation of indoor PCB contamination is extremely expensive because PCB from old primary sources has redistributed to most other surfaces over time. This study investigates the introduction of new removable sorbing materials as a method instantly lowering the concentration of PCB in indoor air...... and slowly decontaminating old surface materials. In three bedrooms of a contaminated apartment respectively new painted gypsum boards, sheets of flexible polyurethane foam and activated carbon fabric were introduced. The PCB concentrations in room air were monitored before the intervention and several times...... during the following 10 months. The PCB concentrations in the old surface materials as well as the new materials were also measured. An immediate reduction of PCB concentration in indoor air, a gradual increase of PCB in new material and as well a gradual reduction in old surface materials were...

  2. Geotoxic materials in the surface environment

    International Nuclear Information System (INIS)

    Koranda, J.J.; Cohen, J.J.; Smith, C.F.; Ciminesi, F.J.

    1981-01-01

    The toxicology and natural occurrence of several recognized geotoxic elements including arsenic, cadmium, chromium, nickel, lead, selenium, uranium, and vanadium is reviewed. The behavior of these elements in the environment and in biological systems is examined. The properties of these eight toxic elements are summarized and presented in a toxicity matrix. The toxicity matrix identifies each of the elements in terms of average crustal abundance, average soil concentration, drinking water standards, irrigation water standards, daily human intake, aquatic toxicity, phytotoxicity, mammalian toxicity, human toxicity, and bioaccumulation factors for fish. Fish are the major aquatic environment contribution to the human diet and bioaccumulation in aquatic ecosystems has been demonstrated to be an important factor in the cycling of elements in aquatic ecosystems. The toxicity matrix is used as a first approximation to rank the geotoxicity of elements for the purpose of focusing future efforts. The ranking from highest to lowest toxicity with respect to the toxicity parameters being discussed is as follows: arsenic, cadmium, lead, selenium, chromium, vanadium, nickel, and uranium

  3. Geotoxic materials in the surface environment

    Energy Technology Data Exchange (ETDEWEB)

    Koranda, J.J.; Cohen, J.J.; Smith, C.F.; Ciminesi, F.J.

    1981-12-07

    The toxicology and natural occurrence of several recognized geotoxic elements including arsenic, cadmium, chromium, nickel, lead, selenium, uranium, and vanadium is reviewed. The behavior of these elements in the environment and in biological systems is examined. The properties of these eight toxic elements are summarized and presented in a toxicity matrix. The toxicity matrix identifies each of the elements in terms of average crustal abundance, average soil concentration, drinking water standards, irrigation water standards, daily human intake, aquatic toxicity, phytotoxicity, mammalian toxicity, human toxicity, and bioaccumulation factors for fish. Fish are the major aquatic environment contribution to the human diet and bioaccumulation in aquatic ecosystems has been demonstrated to be an important factor in the cycling of elements in aquatic ecosystems. The toxicity matrix is used as a first approximation to rank the geotoxicity of elements for the purpose of focusing future efforts. The ranking from highest to lowest toxicity with respect to the toxicity parameters being discussed is as follows: arsenic, cadmium, lead, selenium, chromium, vanadium, nickel, and uranium.

  4. Commentary on guidelines for radiation measurement and treatment of substances including naturally occurring radioactive materials

    International Nuclear Information System (INIS)

    Sakurai, Naoyuki; Ishiguro, Hideharu

    2007-01-01

    Study group on safety regulation on research reactors in Ministry of Education, Culture, Sports, Science and Technology (MEXT) reported the guidelines of 'Guidelines on radiation measurement and treatment of naturally occurring radioactive materials (NORM)' on 6 February 2006. RANDEC made the website contents 'Study on use and safety of the substances including uranium or thorium', based on the contract with MEXT to make theirs contents. This paper describes the outline of the website in MEXT homepage, background and contents of NORM guidelines in order to understand easily and visually the NORM guidelines, adding in some flowcharts and figures. (author)

  5. Molten Materials Transfer and Handling on the Lunar Surface

    Science.gov (United States)

    Stefanescu, Doru M.; Curreri, Peter A.; Sen, Subhayu

    2008-01-01

    Electrolytic reduction processes as a means to provide pure elements for lunar resource utilization have many advantages. Such processes have. the potential of removing all the oxygen from the lunar soil for use in life support and for propellant. Electrochemical reduction also provides a direct path for the. production of pure metals and silicon which can be utilized for in situ manufacturing and power production. Some of the challenges encountered in the electrolytic reduction processes include the feeding of the electrolytic cell (the transfer of electrolyte containing lunar soil), the withdrawal of reactants and refined products such as the liquidironsiliconalloy with a number of impurities, and the spent regolith slag, produced in the hot electrolytic cell for the reduction of lunar regolith. The paper will discuss some of the possible solutions to the challenges of handling molten materials on the lunar surface, as well as the path toward the construction and testing of a proof-of-concept facility.

  6. ZnO materials and surface tailoring for biosensing.

    Science.gov (United States)

    Yakimova, Rositza; Selegard, Linnea; Khranovskyy, Volodymyr; Pearce, Ruth; Spetz, Anita Lloyd; Uvdal, Kajsa

    2012-01-01

    ZnO nanostructured materials, such as films and nanoparticles, could provide a suitable platform for development of high performance biosensors due to their unique fundamental material properties. This paper reviews different preparation techniques of ZnO nanocrystals and material issues like wettability, biocompatibility and toxicity, which have an important relevance to biosensor functionality. Efforts are made to summarize and analyze existing results regarding surface modification and molecular attachments for successful biofunctionalization and understanding of the mechanisms involved. A section is devoted to implementations of tailored surfaces in biosensors. We end with conclusions on the feasibility of using ZnO nanocrystals for biosensing.

  7. Laboratory Reference Spectroscopy of Icy Satellite Candidate Surface Materials (Invited)

    Science.gov (United States)

    Dalton, J. B.; Jamieson, C. S.; Shirley, J. H.; Pitman, K. M.; Kariya, M.; Crandall, P.

    2013-12-01

    The bulk of our knowledge of icy satellite composition continues to be derived from ultraviolet, visible and infrared remote sensing observations. Interpretation of remote sensing observations relies on availability of laboratory reference spectra of candidate surface materials. These are compared directly to observations, or incorporated into models to generate synthetic spectra representing mixtures of the candidate materials. Spectral measurements for the study of icy satellites must be taken under appropriate conditions (cf. Dalton, 2010; also http://mos.seti.org/icyworldspectra.html for a database of compounds) of temperature (typically 50 to 150 K), pressure (from 10-9 to 10-3 Torr), viewing geometry, (i.e., reflectance), and optical depth (must manifest near infrared bands but avoid saturation in the mid-infrared fundamentals). The Planetary Ice Characterization Laboratory (PICL) is being developed at JPL to provide robust reference spectra for icy satellite surface materials. These include sulfate hydrates, hydrated and hydroxylated minerals, and both organic and inorganic volatile ices. Spectral measurements are performed using an Analytical Spectral Devices FR3 portable grating spectrometer from .35 to 2.5 microns, and a Thermo-Nicolet 6500 Fourier-Transform InfraRed (FTIR) spectrometer from 1.25 to 20 microns. These are interfaced with the Basic Extraterrestrial Environment Simulation Testbed (BEEST), a vacuum chamber capable of pressures below 10-9 Torr with a closed loop liquid helium cryostat with custom heating element capable of temperatures from 30-800 Kelvins. To generate optical constants (real and imaginary index of refraction) for use in nonlinear mixing models (i.e., Hapke, 1981 and Shkuratov, 1999), samples are ground and sieved to six different size fractions or deposited at varying rates to provide a range of grain sizes for optical constants calculations based on subtractive Kramers-Kronig combined with Hapke forward modeling (Dalton and

  8. Dental Hetero-Graft Materials with Nano Hydroxyapatite Surface Treatment.

    Science.gov (United States)

    Kim, Dai-Hwan; Kim, Kyung-Il; Yoon, Seokyoung; Kim, Hyung-Jo; Ahn, Jin-Soo; Jun, Sang Ho; Kang, Ho Chang; Pang, Changhyun; Kim, Jaeyun; Cha, Hyung Joon; Han, Kwon-Hoon; Kim, Dong-Myong; Lee, Jung Heon

    2015-10-01

    We report the development of hydroxyapatite nanoparticle (HAp NP)-functionalized hetero-graft materials (HGMs) for dental applications. These HGMs were prepared by attaching platelet-, needle-, and sphere-shaped HAp NPs to the surface of xenograft materials through chemical conjugation. Although all three HAp NPs contributed to increase the surface area of bone graft material (BGM), the shape of the HAp NPs was a determining factor. Platelet HAp NPs were most effective, because they caused a 48.9% increase in BGM surface area whereas the influence of the spherical NP was only a 6.7% increase. This suggests that geometric factors regarding both the attached HAp NPs and graft material surface are essential in controlling the surface roughness of graft materials. Among the three HAp NPs, it was the platelet HAp NPs that helped to increase the efficacy of the BGM most significantly. Compared with BGM with no HAp NP attachment, HGM with platelet HAp NP ('platelet-HGM) treatment had ~46.1% higher cell attachment and proliferation rate. The MTT assay also showed that the HAp NP-treated hetero-graft materials had negligible cytotoxicity.

  9. STUDY OF SURFACE PHENOMENA IN MATERIALS OF PROSTHETIC RESTORATION

    Directory of Open Access Journals (Sweden)

    Mihaela-Păpuşa Vasiliu

    2012-12-01

    Full Text Available As a direct consequence of their application domain – the oral cavity – dental materials are subjected to the corosive action of saliva, being surrounded by microorganisms, fluids and alimentary rests, which modify their surface characteristics. Concerns on the quality of the dental materials explain the numeorus interdisciplinary studies, characterized by a close relation among various scientific domains (physics, chemistry, biology, science of biomaterials, techniques also applied in clinical stomatology. Analysis of the saliva–dental materials interface made use of ceramic surfaces, composites and artificial saliva, permitting to determine the main surface parameters of the materials of prosthetic restoration, calculated with some physical models, starting from measurements of the contact angle: surface energy, its polar and dispersive components, surface rugosity, adhesion mechanic work. All composites showed low values of the adhesion mechanic work, the conclusion being that they are much more hydrophobic than the ceramic materials. Such a property is especially important from an aesthetic perspective, as the hydrophobic materials have a better colour stability in time.

  10. Effects of bleaching agents on surface roughness of filling materials.

    Science.gov (United States)

    Markovic, Ljubisa; Jordan, Rainer Andreas; Glasser, Marie-Claire; Arnold, Wolfgang Hermann; Nebel, Jan; Tillmann, Wolfgang; Ostermann, Thomas; Zimmer, Stefan

    2014-01-01

    The aim of this study was to use a non-tactile optical measurement system to assess the effects of three bleaching agents' concentrations on the surface roughness of dental restoration materials. Two composites (Grandio, Venus) and one glass ionomer cement (Ketac Fil Plus) were used in this in vitro study. Specimens were treated with three different bleaching agents (16% and 22% carbamide peroxide (Polanight) and 38% hydrogen peroxide (Opalescence Boost)). Surface roughness was measured with an optical profilometer (Infinite Focus G3) before and after the bleaching treatment. Surface roughness increased in all tested specimens after bleaching treatment (p<0.05). Our in vitro study showed that dental bleaching agents influenced the surface roughness of different restoration materials, and the restoration material itself was shown to have an impact on alteration susceptibility. There seemed to be no clinical relevance in case of an optimal finish.

  11. Controlling coverage of solution cast materials with unfavourable surface interactions

    KAUST Repository

    Burlakov, V. M.

    2014-03-03

    Creating uniform coatings of a solution-cast material is of central importance to a broad range of applications. Here, a robust and generic theoretical framework for calculating surface coverage by a solid film of material de-wetting a substrate is presented. Using experimental data from semiconductor thin films as an example, we calculate surface coverage for a wide range of annealing temperatures and film thicknesses. The model generally predicts that for each value of the annealing temperature there is a range of film thicknesses leading to poor surface coverage. The model accurately reproduces solution-cast thin film coverage for organometal halide perovskites, key modern photovoltaic materials, and identifies processing windows for both high and low levels of surface coverage. © 2014 AIP Publishing LLC.

  12. Method of removing hazardous material deposited on concrete surface

    International Nuclear Information System (INIS)

    Komatsu, Fumiaki; Baba, Kyoji.

    1991-01-01

    A salt compound containing a carbonate group such as sodium carbonate or potassium carbonate is dissolved in water and the aqueous solution is sprayed on the surface of concretes, kept for a predetermined period and dried to deposit the carbonate on the surface of the concretes. Then, aqueous solution of an organic acid such as oxalic acid or citric acid is sprayed and reacted with the carbonate to form bubbles of gaseous carbon dioxide. With such procedures, hazardous material containing radioactive materials intruded to the unevenness or fine holes on the surface of the concrete, or heavy metals such as hexavalent chromium or lead are deposited to the bubbles of gaseous carbon dioxide to be raised up therewith. By removing the bubbles, hazardous materials such as radioactive materials or heavy metals intruded to the concretes can be removed without generating powdery dusts, without requiring a large-scaled device and without changing the characteristic of the concretes. (T.M.)

  13. Challenges for INAA in studies of materials from advanced material research including rare earth concentrates and carbon based ceramics

    International Nuclear Information System (INIS)

    Bode, P.; Van Meerten, Th.G.

    2000-01-01

    Rare-earth elements are increasingly applied in advanced materials to be used, e.g., in electronic industry, automobile catalysts, or lamps and optical devices. Trace element analysis of these materials might be an interesting niche for NAA because of the intrinsic high accuracy of this technique, and the shortage of matrix matching reference materials with other methods for elemental analysis. The carbon composite materials form another category of advanced materials, where sometimes a very high degree of purity is required. Also for these materials, NAA has favorable analytical characteristics. Examples are given of the use of NAA in the analysis of both categories of materials. (author)

  14. SHARC: ab Initio Molecular Dynamics with Surface Hopping in the Adiabatic Representation Including Arbitrary Couplings.

    Science.gov (United States)

    Richter, Martin; Marquetand, Philipp; González-Vázquez, Jesús; Sola, Ignacio; González, Leticia

    2011-05-10

    We present a semiclassical surface-hopping method which is able to treat arbitrary couplings in molecular systems including all degrees of freedom. A reformulation of the standard surface-hopping scheme in terms of a unitary transformation matrix allows for the description of interactions like spin-orbit coupling or transitions induced by laser fields. The accuracy of our method is demonstrated in two systems. The first one, consisting of two model electronic states, validates the semiclassical approach in the presence of an electric field. In the second one, the dynamics in the IBr molecule in the presence of spin-orbit coupling after laser excitation is investigated. Due to an avoided crossing that originates from spin-orbit coupling, IBr dissociates into two channels: I + Br((2)P3/2) and I + Br*((2)P1/2). In both systems, the obtained results are in very good agreement with those calculated from exact quantum dynamical simulations.

  15. A novel technique for including surface tension in PLIC-VOF methods

    Energy Technology Data Exchange (ETDEWEB)

    Meier, M.; Yadigaroglu, G. [Swiss Federal Institute of Technology, Nuclear Engineering Lab. ETH-Zentrum, CLT, Zurich (Switzerland); Smith, B. [Paul Scherrer Inst. (PSI), Villigen (Switzerland). Lab. for Thermal-Hydraulics

    2002-02-01

    Various versions of Volume-of-Fluid (VOF) methods have been used successfully for the numerical simulation of gas-liquid flows with an explicit tracking of the phase interface. Of these, Piecewise-Linear Interface Construction (PLIC-VOF) appears as a fairly accurate, although somewhat more involved variant. Including effects due to surface tension remains a problem, however. The most prominent methods, Continuum Surface Force (CSF) of Brackbill et al. and the method of Zaleski and co-workers (both referenced later), both induce spurious or 'parasitic' currents, and only moderate accuracy in regards to determining the curvature. We present here a new method to determine curvature accurately using an estimator function, which is tuned with a least-squares-fit against reference data. Furthermore, we show how spurious currents may be drastically reduced using the reconstructed interfaces from the PLIC-VOF method. (authors)

  16. Hardfacing materials used in valves for seating and wear surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Knecht, W.G.

    1996-12-01

    Most valves and essentially all critical service valves utilize hardfacing materials for seating and wear surfaces to minimize wear and galling. The type of hardfacing materials used, the methods of deposition, and the quality of the final product all contribute to the wear characteristics, required operating force, and life of the final product. Over the last forty years the most prevalent hardfacing materials furnished to the commercial nuclear industry consisted of cobalt base and nickel base materials. In the last several years there has been extensive development and evaluation work performed on iron base hardfacing materials. This presentation will address the wear characteristics of the various materials and the importance of consistent quality of deposited materials necessary to achieve optimum product performance and longevity.

  17. Monitoring of biofilm formation on different material surfaces of medical devices using hyperspectral imaging method

    Science.gov (United States)

    Kim, Do-Hyun; Kim, Moon S.; Hwang, Jeeseong

    2012-03-01

    Contamination of the inner surface of indwelling (implanted) medical devices by microbial biofilm is a serious problem. Some microbial bacteria such as Escherichia coli form biofilms that lead to potentially lifethreatening infections. Other types of medical devices such as bronchoscopes and duodenoscopes account for the highest number of reported endoscopic infections where microbial biofilm is one of the major causes for these infections. We applied a hyperspectral imaging method to detect biofilm contamination on the surface of several common materials used for medical devices. Such materials include stainless steel, titanium, and stainless-steeltitanium alloy. Potential uses of hyperspectral imaging technique to monitor biofilm attachment to different material surfaces are discussed.

  18. OCV Hysteresis in Li-Ion Batteries including Two-Phase Transition Materials

    Directory of Open Access Journals (Sweden)

    Michael A. Roscher

    2011-01-01

    Full Text Available The relation between batteries' state of charge (SOC and open-circuit voltage (OCV is a specific feature of electrochemical energy storage devices. Especially NiMH batteries are well known to exhibit OCV hysteresis, and also several kinds of lithium-ion batteries show OCV hysteresis, which can be critical for reliable state estimation issues. Electrode potential hysteresis is known to result from thermodynamical entropic effects, mechanical stress, and microscopic distortions within the active electrode materials which perform a two-phase transition during lithium insertion/extraction. Hence, some Li-ion cells including two-phase transition active materials show pronounced hysteresis referring to their open-circuit voltage. This work points out how macroscopic effects, that is, diffusion limitations, superimpose the latte- mentioned microscopic mechanisms and lead to a shrinkage of OCV hysteresis, if cells are loaded with high current rates. To validate the mentioned interaction, Li-ion cells' state of charge is adjusted to 50% with various current rates, beginning from the fully charged and the discharged state, respectively. As a pronounced difference remains between the OCV after charge and discharge adjustment, obviously the hysteresis vanishes as the target SOC is adjusted with very high current rate.

  19. Process For Controlling Flow Rate Of Viscous Materials Including Use Of Nozzle With Changeable Openings

    Science.gov (United States)

    Ellingson, William A.; Forster, George A.

    1999-11-02

    Apparatus and a method for controlling the flow rate of viscous materials through a nozzle includes an apertured main body and an apertured end cap coupled together and having an elongated, linear flow channel extending the length thereof. An end of the main body is disposed within the end cap and includes a plurality of elongated slots concentrically disposed about and aligned with the flow channel. A generally flat cam plate having a center aperture is disposed between the main body and end cap and is rotatable about the flow channel. A plurality of flow control vane assemblies are concentrically disposed about the flow channel and are coupled to the cam plate. Each vane assembly includes a vane element disposed adjacent the end of the flow channel. Rotation of the cam plate in a first direction causes a corresponding rotation of each of the vane elements for positioning the individual vane elements over the aperture in the end cap blocking flow through the flow channel, while rotation in an opposite direction removes the vane elements from the aperture and positions them about the flow channel in a nested configuration in the full open position, with a continuous range of vane element positions available between the full open and closed positions.

  20. Simulation tool for optical design of PET detector modules including scintillator material and sensor array

    Energy Technology Data Exchange (ETDEWEB)

    Jatekos, B.; Erdei, G.; Lorincz, E. [Budapest Univ. of Technology and Economics, Dept. of Atomic Physics, Budafoki ut 8, H-1111 Budapest (Hungary)

    2011-07-01

    The appearance of single photon avalanche diodes (SPADs) in the field of PET detector modules made it necessary to apply more complex optical design methods to refine the performance of such assemblies. We developed a combined simulation tool that is capable to model complex detector structures including scintillation material, light guide, light collection optics and sensor, correctly taking into account the statistical behavior of emission of scintillation light and its absorbance in SPADs. As a validation we compared simulation results obtained by our software and another optical design program. Calculations were performed for a simple PET detector arrangement used for testing purposes. According to the results, deviation of center of gravity coordinates between the two simulations is 0.0195 mm, the average ratio of total counts 1.0052. We investigated the error resulting from finite sampling in wavelength space and we found that 20 nm pitch is sufficient for the simulation in case of the given spectral dependencies. (authors)

  1. Consistent retrieval of land surface radiation products from EO, including traceable uncertainty estimates

    Science.gov (United States)

    Kaminski, Thomas; Pinty, Bernard; Voßbeck, Michael; Lopatka, Maciej; Gobron, Nadine; Robustelli, Monica

    2017-05-01

    Earth observation (EO) land surface products have been demonstrated to provide a constraint on the terrestrial carbon cycle that is complementary to the record of atmospheric carbon dioxide. We present the Joint Research Centre Two-stream Inversion Package (JRC-TIP) for retrieval of variables characterising the state of the vegetation-soil system. The system provides a set of land surface variables that satisfy all requirements for assimilation into the land component of climate and numerical weather prediction models. Being based on a 1-D representation of the radiative transfer within the canopy-soil system, such as those used in the land surface components of advanced global models, the JRC-TIP products are not only physically consistent internally, but they also achieve a high degree of consistency with these global models. Furthermore, the products are provided with full uncertainty information. We describe how these uncertainties are derived in a fully traceable manner without any hidden assumptions from the input observations, which are typically broadband white sky albedo products. Our discussion of the product uncertainty ranges, including the uncertainty reduction, highlights the central role of the leaf area index, which describes the density of the canopy. We explain the generation of products aggregated to coarser spatial resolution than that of the native albedo input and describe various approaches to the validation of JRC-TIP products, including the comparison against in situ observations. We present a JRC-TIP processing system that satisfies all operational requirements and explain how it delivers stable climate data records. Since many aspects of JRC-TIP are generic, the package can serve as an example of a state-of-the-art system for retrieval of EO products, and this contribution can help the user to understand advantages and limitations of such products.

  2. Effects of hydrogen peroxide bleaching strip gels on dental restorative materials in vitro: surface microhardness and surface morphology.

    Science.gov (United States)

    Duschner, Heinz; Götz, Hermann; White, Donald J; Kozak, Kathleen M; Zoladz, James R

    2004-01-01

    This study examined the effects of peroxide tooth bleaching, including Crest Whitestrips hydrogen peroxide gel treatments, on the surface hardness and morphology of common dental restorative treatments. American Dental Association (ADA) recommended dental restorative materials, including amalgam, dental gold, porcelain, glass ionomer, and composites, were prepared according to manufacturers' instructions. A cycling treatment methodology was employed which alternated ex vivo human salivary exposures with bleaching treatments under conditions of controlled temperature and durations of treatment. Bleaching treatments included commercial Crest Whitestrips bleaching gels, which utilize hydrogen peroxide as the in situ bleaching source, and several commercial carbamide peroxide bleaching gels. Control treatments included placebo gels and an untreated group. Crest Whitestrips bleaching included treatment exposures simulating recommended clinical exposures (14 hours), along with excess bleaching simulating exposure to five times suggested Crest Whitestrips use. At the conclusion of treatments, surface microhardness measures and surface morphological assessments with standard and variable pressure (VP-) SEMs were conducted to assess the effects of bleaching exposure on the surface morphology and structural integrity of the restoratives. Surface microhardness and SEM measures revealed no significant deleterious effects on the restoration surfaces from Whitestrips gels. These results confirm that tooth bleaching from the selected commercial hydrogen peroxide or carbamide peroxide bleaching systems does not produce changes in surface morphology or microhardness of common dental restorative materials. These results support the clinical safety of the selected commercial bleaching systems to the oral environment, matching results obtained from long-term use of these ingredients applied in dental offices and available in commercial formulations.

  3. Method for preparing microstructure arrays on the surface of thin film material

    KAUST Repository

    Wang, Peng

    2017-02-09

    Methods are provided for growing a thin film of a nanoscale material. Thin films of nanoscale materials are also provided. The films can be grown with microscale patterning. The method can include vacuum filtration of a solution containing the nanostructured material through a porous substrate. The porous substrate can have a pore size that is comparable to the size of the nanoscale material. By patterning the pores on the surface of the substrate, a film can be grown having the pattern on a surface of the thin film, including on the top surface opposite the substrate. The nanoscale material can be graphene, graphene oxide, reduced graphene oxide, molybdenum disulfide, hexagonal boron nitride, tungsten diselenide, molybdenum trioxide, or clays such as montmorillonite or lapnotie. The porous substrate can be a porous organic or inorganic membrane, a silicon stencil membrane, or similar membrane having pore sizes on the order of microns.

  4. Specialists meeting on properties of primary circuit structural materials including environmental effects

    International Nuclear Information System (INIS)

    1977-01-01

    The Specialists Meeting on Properties of Primary Circuit Structural Materials of LMFBRs covered the following topics: overview of materials program in different countries; mechanical properties of materials in air; fracture mechanics studies - component related activities; impact of environmental influences on mechanical properties; relationship of material properties and design methods. The purpose of the meeting was to provide a forum for exchange of information on structural materials behaviour in primary circuit of fast breeder reactors. Special emphasis was placed on environmental effects such as influence of sodium and irradiation on mechanical properties of reactor materials

  5. Surface Sensitive Techniques for Advanced Characterization of Luminescent Materials.

    Science.gov (United States)

    Swart, Hendrik C

    2017-08-04

    The important role of surface sensitive characterization techniques such as Auger electron spectroscopy (AES), X-ray photo electron spectroscopy (XPS), time of flight scanning ion mass spectrometry (TOF-SIMS) and High resolution transmission electron microscopy (HRTEM) for the characterization of different phosphor materials is discussed in this short review by giving selective examples from previous obtained results. AES is used to monitor surface reactions during electron bombardment and also to determine the elemental composition of the surfaces of the materials, while XPS and TOF-SIMS are used for determining the surface chemical composition and valence state of the dopants. The role of XPS to determine the presence of defects in the phosphor matrix is also stated with the different examples. The role of HRTEM in combination with Energy dispersive spectroscopy (EDS) for nanoparticle characterization is also pointed out.

  6. Surface Sensitive Techniques for Advanced Characterization of Luminescent Materials

    Directory of Open Access Journals (Sweden)

    Hendrik C. Swart

    2017-08-01

    Full Text Available The important role of surface sensitive characterization techniques such as Auger electron spectroscopy (AES, X-ray photo electron spectroscopy (XPS, time of flight scanning ion mass spectrometry (TOF-SIMS and High resolution transmission electron microscopy (HRTEM for the characterization of different phosphor materials is discussed in this short review by giving selective examples from previous obtained results. AES is used to monitor surface reactions during electron bombardment and also to determine the elemental composition of the surfaces of the materials, while XPS and TOF-SIMS are used for determining the surface chemical composition and valence state of the dopants. The role of XPS to determine the presence of defects in the phosphor matrix is also stated with the different examples. The role of HRTEM in combination with Energy dispersive spectroscopy (EDS for nanoparticle characterization is also pointed out.

  7. Laboratory Determination of Thermal Protection System Materials Surface Catalytic Properties

    Science.gov (United States)

    2007-07-01

    Zalar, A., "Recombination of Neutral Hydrogen Atoms on AISI 304 Stainless Steel Surface," Applied Surface Science, Vol. 144-145, 1999, pp. 399-403. 57...and test environments. Typically, these fits contain only the temperature dependence of the loss probability, with no information on pressure or...generated in the MESOX test facility in the PROMES-CNRS laboratory on a variety of ceramic materials.47-50 The MESOX facility uses a flow tube

  8. Directing neuronal cell growth on implant material surfaces by microstructuring.

    OpenAIRE

    Reich, Uta; Fadeeva, Elena; Warnecke, Athanasia; Paasche, Gerrit; Müller, Peter; Chichkov, Boris; Stöver, Timo; Lenarz, Thomas; Reuter, Günter

    2012-01-01

    For best hearing sensation, electrodes of auditory prosthesis must have an optimal electrical contact to the respective neuronal cells. To improve the electrode-nerve interface, microstructuring of implant surfaces could guide neuronal cells toward the electrode contact. To this end, femtosecond laser ablation was used to generate linear microgrooves on the two currently relevant cochlear implant materials, silicone elastomer and platinum. Silicone surfaces were structured by two different me...

  9. Surface Sensitive Techniques for Advanced Characterization of Luminescent Materials

    OpenAIRE

    Hendrik C. Swart

    2017-01-01

    The important role of surface sensitive characterization techniques such as Auger electron spectroscopy (AES), X-ray photo electron spectroscopy (XPS), time of flight scanning ion mass spectrometry (TOF-SIMS) and High resolution transmission electron microscopy (HRTEM) for the characterization of different phosphor materials is discussed in this short review by giving selective examples from previous obtained results. AES is used to monitor surface reactions during electron bombardment and al...

  10. STUDY OF SURFACE PHENOMENA IN MATERIALS OF PROSTHETIC RESTORATION

    OpenAIRE

    Mihaela-Păpuşa Vasiliu; Carmen Stadoleanu; Daniela Ivona Tomiţa; Cristina-Mihaela Stanilă; S.-C. Jalbă; Nicoleta Dumitraşcu

    2012-01-01

    As a direct consequence of their application domain – the oral cavity – dental materials are subjected to the corosive action of saliva, being surrounded by microorganisms, fluids and alimentary rests, which modify their surface characteristics. Concerns on the quality of the dental materials explain the numeorus interdisciplinary studies, characterized by a close relation among various scientific domains (physics, chemistry, biology, science of biomaterials), techniqu...

  11. Open literature review of threats including sabotage and theft of fissile material transport in Japan

    International Nuclear Information System (INIS)

    Cochran, John Russell; Furaus, James Phillip; Marincel, Michelle K.

    2005-01-01

    This report is a review of open literature concerning threats including sabotage and theft related to fissile material transport in Japan. It is intended to aid Japanese officials in the development of a design basis threat. This threat includes the external threats of the terrorist, criminal, and extremist, and the insider threats of the disgruntled employee, the employee forced into cooperation via coercion, the psychotic employee, and the criminal employee. Examination of the external terrorist threat considers Japanese demographics, known terrorist groups in Japan, and the international relations of Japan. Demographically, Japan has a relatively homogenous population, both ethnically and religiously. Japan is a relatively peaceful nation, but its history illustrates that it is not immune to terrorism. It has a history of domestic terrorism and the open literature points to the Red Army, Aum Shinrikyo, Chukaku-Ha, and Seikijuku. Japan supports the United States in its war on terrorism and in Iraq, which may make Japan a target for both international and domestic terrorists. Crime appears to remain low in Japan; however sources note that the foreign crime rate is increasing as the number of foreign nationals in the country increases. Antinuclear groups' recent foci have been nuclear reprocessing technology, transportation of MOX fuel, and possible related nuclear proliferation issues. The insider threat is first defined by the threat of the disgruntled employee. This threat can be determined by studying the history of Japan's employment system, where Keiretsu have provided company stability and lifetime employment. Recent economic difficulties and an increase of corporate crime, due to sole reliability on the honor code, have begun to erode employee loyalty

  12. Acoustic surface transformation realized by acoustic-null materials using bilayer natural materials

    Science.gov (United States)

    Li, Borui; Sun, Fei; He, Sailing

    2017-11-01

    We propose a general method, known as acoustic surface transformation (AST), to design novel acoustic devices and study the realization of such devices by using naturally available materials in broadband acoustic frequencies. All devices designed by AST only need one anisotropic homogeneous acoustic-null material (ANM). We design the ANM by exploiting natural material-based metal-fluid structures and verify that by numerical simulation. Unlike traditional methods, no complicated mathematical calculations are needed. We only need to design the geometrical shapes of the input and output surfaces of the devices. The proposed method will pave a new road for future acoustic design.

  13. Empirical Validation of a Thermal Model of a Complex Roof Including Phase Change Materials

    Directory of Open Access Journals (Sweden)

    Stéphane Guichard

    2015-12-01

    Full Text Available This paper deals with the empirical validation of a building thermal model of a complex roof including a phase change material (PCM. A mathematical model dedicated to PCMs based on the heat apparent capacity method was implemented in a multi-zone building simulation code, the aim being to increase the understanding of the thermal behavior of the whole building with PCM technologies. In order to empirically validate the model, the methodology is based both on numerical and experimental studies. A parametric sensitivity analysis was performed and a set of parameters of the thermal model has been identified for optimization. The use of the generic optimization program called GenOpt® coupled to the building simulation code enabled to determine the set of adequate parameters. We first present the empirical validation methodology and main results of previous work. We then give an overview of GenOpt® and its coupling with the building simulation code. Finally, once the optimization results are obtained, comparisons of the thermal predictions with measurements are found to be acceptable and are presented.

  14. Modeling and analysis for surface roughness and material removal ...

    African Journals Online (AJOL)

    user

    terms of cutting parameters is also developed using regression modeling. The results indicate that the developed model is suitable for prediction of surface roughness and material removal rate in machining of unidirectional glass fiber reinforced plastics (UD-GFRP) composites. The predicted values and measured values ...

  15. Difraction analysis of iron materials after surface machining

    Czech Academy of Sciences Publication Activity Database

    Čerňanský, Marian; Ganev, N.; Barcal, J.; Drahokoupil, Jan; Kolařík, K.

    2006-01-01

    Roč. 2006, suppl. 23 (2006), s. 369-374 ISSN 0044-2968 Institutional research plan: CEZ:AV0Z10100520 Keywords : iron materials * surface treatment * size-strain * residual stress * phase analysis Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.897, year: 2006

  16. Boundary surface and microstructure analysis of ceramic materials

    International Nuclear Information System (INIS)

    Woltersdorf, J.; Pippel, E.

    1992-01-01

    The article introduces the many possibilities of high voltage (HVEM) and high resolution electron microscopy (HREM) for boundary surface and microstructure analysis of ceramic materials. The investigations are limited to ceramic long fibre composites and a ceramic fibre/glass matrix system. (DG) [de

  17. Highway-rail grade crossing surface material performance.

    Science.gov (United States)

    2014-04-01

    Highway-Railroad grade crossings are an integral part of the transportation system, allowing the : two modes to operate in the same areas. Performance of the surface material at grade : crossings has been an ongoing issue. This study reviewed the lit...

  18. Modeling and analysis for surface roughness and material removal ...

    African Journals Online (AJOL)

    International Journal of Engineering, Science and Technology ... A multiple objective utility model has been studied to optimize both the dependent parameters. ... Keywords: UD-GFRP composites, ANOVA, multi response optimization, utility concept, regression modeling, surface roughness, material removal rate, ...

  19. Computational design of surfaces, nanostructures and optoelectronic materials

    Science.gov (United States)

    Choudhary, Kamal

    Properties of engineering materials are generally influenced by defects such as point defects (vacancies, interstitials, substitutional defects), line defects (dislocations), planar defects (grain boundaries, free surfaces/nanostructures, interfaces, stacking faults) and volume defects (voids). Classical physics based molecular dynamics and quantum physics based density functional theory can be useful in designing materials with controlled defect properties. In this thesis, empirical potential based molecular dynamics was used to study the surface modification of polymers due to energetic polyatomic ion, thermodynamics and mechanics of metal-ceramic interfaces and nanostructures, while density functional theory was used to screen substituents in optoelectronic materials. Firstly, polyatomic ion-beams were deposited on polymer surfaces and the resulting chemical modifications of the surface were examined. In particular, S, SC and SH were deposited on amorphous polystyrene (PS), and C2H, CH3, and C3H5 were deposited on amorphous poly (methyl methacrylate) (PMMA) using molecular dynamics simulations with classical reactive empirical many-body (REBO) potentials. The objective of this work was to elucidate the mechanisms by which the polymer surface modification took place. The results of the work could be used in tailoring the incident energy and/or constituents of ion beam for obtaining a particular chemistry inside the polymer surface. Secondly, a new Al-O-N empirical potential was developed within the charge optimized many body (COMB) formalism. This potential was then used to examine the thermodynamic stability of interfaces and mechanical properties of nanostructures composed of aluminum, its oxide and its nitride. The potentials were tested for these materials based on surface energies, defect energies, bulk phase stability, the mechanical properties of the most stable bulk phase, its phonon properties as well as with a genetic algorithm based evolution theory of

  20. Deposition of fine and ultrafine particles on indoor surface materials

    DEFF Research Database (Denmark)

    Afshari, Alireza; Reinhold, Claus

    2008-01-01

    -scale test chamber. Experiments took place in a 32 m3 chamber with walls and ceiling made of glass. Prior to each experiment the chamber was flushed with outdoor air to reach an initial particle concentration typical of indoor air in buildings with natural ventilation. The decay of particle concentrations...... The aim of this study was the experimental determination of particle deposition for both different particle size fractions and different indoor surface materials. The selected surface materials were glass, gypsum board, carpet, and curtain. These materials were tested vertically in a full...... was monitored. Seven particle size fractions were studied. These comprised ultrafine and fine particles. Deposition was higher on carpet and curtain than on glass and gypsum board. Particles ranging from 0.3 to 0.5 µm had the lowest deposition. This fraction also has the highest penetration and its indoor...

  1. Asteroid surface materials: mineralogical characterizations from reflectance spectra

    International Nuclear Information System (INIS)

    Gaffey, M.J.; McCord, T.B.

    1978-01-01

    The interpretation of diagnostic parameters in the spectral reflectance data for asteroids provides a means of characterizing the mineralogy and petrology of asteroid surface materials. An interpretive technique based on a quantitative understanding of the functional relationship between the optical properties of a mineral assemblage and its mineralogy, petrology and chemistry can provide a considerably more sophisticated characterization of a single material than any matching or classification technique for those objects bright enough to allow spectral reflectance measurements. Albedos derived from radiometry and polarization data for individual asteroids can be used with spectral data to establish the spectral albedo, to define the optical density of the surface material and, in general to constrain mineralogical interpretations. (Auth.)

  2. Electronic materials high-T(sub c) superconductivity polymers and composites structural materials surface science and catalysts industry participation

    Science.gov (United States)

    1988-01-01

    The fifth year of the Center for Advanced Materials was marked primarily by the significant scientific accomplishments of the research programs. The Electronics Materials program continued its work on the growth and characterization of gallium arsenide crystals, and the development of theories to understand the nature and distribution of defects in the crystals. The High Tc Superconductivity Program continued to make significant contributions to the field in theoretical and experimental work on both bulk materials and thin films and devices. The Ceramic Processing group developed a new technique for cladding YBCO superconductors for high current applications in work with the Electric Power Research Institute. The Polymers and Composites program published a number of important studies involving atomistic simulations of polymer surfaces with excellent correlations to experimental results. The new Enzymatic Synthesis of Materials project produced its first fluorinated polymers and successfully began engineering enzymes designed for materials synthesis. The structural Materials Program continued work on novel alloys, development of processing methods for advanced ceramics, and characterization of mechanical properties of these materials, including the newly documented characterization of cyclic fatigue crack propagation behavior in toughened ceramics. Finally, the Surface Science and Catalysis program made significant contributions to the understanding of microporous catalysts and the nature of surface structures and interface compounds.

  3. A constitutive model for the superplastic material ALNOVI-1 including leak risk information

    NARCIS (Netherlands)

    Snippe, Corijn H.C.; Snippe, Q.H.C.; Meinders, Vincent T.; Pietzyk, M.; Kusiak, J.; Majta, J.; Hartley, P.; Lin, J.; Mori, K.

    2008-01-01

    For some applications, it is important that a formed sheet of material is completely gas tight, therefore it is beneficial to be able to predict whether a formed sheet will be leak tight for gases or not. Superplastic materials show the ability to attain very high plastic strains before failure.

  4. Improved Composites Using Crosslinked, Surface-Modified Carbon Nanotube Materials

    Science.gov (United States)

    Baker, James Stewart

    2014-01-01

    Individual carbon nanotubes (CNTs) exhibit exceptional tensile strength and stiffness; however, these properties have not translated well to the macroscopic scale. Premature failure of bulk CNT materials under tensile loading occurs due to the relatively weak frictional forces between adjacent CNTs, leading to poor load transfer through the material. When used in polymer matrix composites (PMCs), the weak nanotube-matrix interaction leads to the CNTs providing less than optimal reinforcement.Our group is examining the use of covalent crosslinking and surface modification as a means to improve the tensile properties of PMCs containing carbon nanotubes. Sheet material comprised of unaligned multi-walled carbon nanotubes (MWCNT) was used as a drop-in replacement for carbon fiber in the composites. A variety of post-processing methods have been examined for covalently crosslinking the CNTs to overcome the weak inter-nanotube shear interactions, resulting in improved tensile strength and modulus for the bulk sheet material. Residual functional groups from the crosslinking chemistry may have the added benefit of improving the nanotube-matrix interaction. Composites prepared using these crosslinked, surface-modified nanotube sheet materials exhibit superior tensile properties to composites using the as received CNT sheet material.

  5. 75 FR 16514 - Bayer Material Science, LLC, Formally Known as Sheffield Plastics, Including On-Site Leased...

    Science.gov (United States)

    2010-04-01

    ... Employment and Training Administration Bayer Material Science, LLC, Formally Known as Sheffield Plastics... Material Science, LLC, formally known as Sheffield Plastics, including on-site leased workers from... that Bayer Material Science, LLC was formally known as Sheffield Plastics. Some workers separated from...

  6. Thermoelectric material including a multiple transition metal-doped type I clathrate crystal structure

    Science.gov (United States)

    Yang, Jihui [Lakeshore, CA; Shi, Xun [Troy, MI; Bai, Shengqiang [Shanghai, CN; Zhang, Wenqing [Shanghai, CN; Chen, Lidong [Shanghai, CN; Yang, Jiong [Shanghai, CN

    2012-01-17

    A thermoelectric material includes a multiple transition metal-doped type I clathrate crystal structure having the formula A.sub.8TM.sub.y.sub.1.sup.1TM.sub.y.sub.2.sup.2 . . . TM.sub.y.sub.n.sup.nM.sub.zX.sub.46-y.sub.1.sub.-y.sub.2.sub.- . . . -y.sub.n.sub.-z. In the formula, A is selected from the group consisting of barium, strontium, and europium; X is selected from the group consisting of silicon, germanium, and tin; M is selected from the group consisting of aluminum, gallium, and indium; TM.sup.1, TM.sup.2, and TM.sup.n are independently selected from the group consisting of 3d, 4d, and 5d transition metals; and y.sub.1, y.sub.2, y.sub.n and Z are actual compositions of TM.sup.1, TM.sup.2, TM.sup.n, and M, respectively. The actual compositions are based upon nominal compositions derived from the following equation: z=8q.sub.A-|.DELTA.q.sub.1|y.sub.1-|.DELTA.q.sub.2|y.sub.2- . . . -|.DELTA.q.sub.n|y.sub.n, wherein q.sub.A is a charge state of A, and wherein .DELTA.q.sub.1, .DELTA.q.sub.2, .DELTA.q.sub.n are, respectively, the nominal charge state of the first, second, and n-th TM.

  7. Formation of nanocrystalline surface layers in various metallic materials by near surface severe plastic deformation

    Directory of Open Access Journals (Sweden)

    Masahide Sato, Nobuhiro Tsuji, Yoritoshi Minamino and Yuichiro Koizumi

    2004-01-01

    Full Text Available The surface of the various kinds of metallic materials sheets were severely deformed by wire-brushing at ambient temperature to achieve nanocrystalline surface layer. The surface layers of the metallic materials developed by the near surface severe plastic deformation (NS-SPD were characterized by means of TEM. Nearly equiaxed nanocrystals with grain sizes ranging from 30 to 200 nm were observed in the near surface regions of all the severely scratched metallic materials, which are Ti-added ultra-low carbon interstitial free steel, austenitic stainless steel (SUS304, 99.99 wt.%Al, commercial purity aluminum (A1050 and A1100, Al–Mg alloy (A5083, Al-4 wt.%Cu alloy, OFHC-Cu (C1020, Cu–Zn alloy (C2600 and Pb-1.5%Sn alloy. In case of the 1050-H24 aluminum, the depth of the surface nanocrystalline layer was about 15 μm. It was clarified that wire-brushing is an effective way of NS-SPD, and surface nanocrystallization can be easily achieved in most of metallic materials.

  8. New electron-ion-plasma equipment for modification of materials and products surface

    International Nuclear Information System (INIS)

    Koval', N.N.

    2013-01-01

    Electron-ion-plasma treatment of materials and products, including surface clearing and activation, formation surface layers with changed chemical and phase structure, increased hardness and corrosion resistance; deposition of various functional coatings, has received a wide distribution in a science and industry. Widespread methods of ion-plasma modification of material and product surfaces are ion etching and activation, ion-plasma nitriding, arc or magnetron deposition of functional coatings, including nanostructured. The combination of above methods of surface modification allows essentially to improve exploitation properties of treated products and to optimize the characteristics of modified surfaces for concrete final requirements. For the purpose of a combination of various methods of ion-plasma treatment in a single work cycle at Institute of High Current Electronics of SB RAS (IHCE SB RAS) specialized technological equipment 'DUET', 'TRIO' and 'QUADRO' and 'KVINTA' have been developed. This equipment allow generating uniform low-temperature gas plasma at pressures of (0.1-1) Pa with concentration of (10 9 -10 11 ) cm -3 in volume of (0.1-1) m 3 . In the installations consistent realization of several various operations of materials and products treatment in a single work cycle is possible. The operations are preliminary heating and degassing, ion clearing, etching and activation of materials and products surface by plasma of arc discharges; chemicothermal treatment (nitriding) for formation of diffusion layer on a surface of treated sample using plasma of nonself-sustained low-pressure arc discharge; deposition of single- or multilayered superhard (≥40 GPa) nanocrystalline coatings on the basis of pure metals or their compounds (nitrides, carbides, carbonitrides) by the arc plasma-assisted method. For realization of the modes all installations are equipped by original sources of gas and metal plasma. Besides, in

  9. Compositions of graphene materials with metal nanostructures and microstructures and methods of making and using including pressure sensors

    KAUST Repository

    Chen, Ye

    2017-01-26

    Composition comprising at least one graphene material and at least one metal. The metal can be in the form of nanoparticles as well as microflakes, including single crystal microflakes. The metal can be intercalated in the graphene sheets. The composition has high conductivity and flexibility. The composition can be made by a one-pot synthesis in which a graphene material precursor is converted to the graphene material, and the metal precursor is converted to the metal. A reducing solvent or dispersant such as NMP can be used. Devices made from the composition include a pressure sensor which has high sensitivity. Two two- dimension materials can be combined to form a hybrid material.

  10. Discrete Material and Thickness Optimization of laminated composite structures including failure criteria

    DEFF Research Database (Denmark)

    Lund, Erik

    2017-01-01

    This work extends the Discrete Material and Thickness Optimization approach to structural optimization problems where strength considerations in the form of failure criteria are taken into account for laminated composite structures. It takes offset in the density approaches applied for stress...... constrained topology optimization of single-material problems and develops formulations for multi-material topology optimization problems applied for laminated composite structures. The method can be applied for both stress- and strain-based failure criteria. The large number of local constraints is reduced...

  11. Surface polaritons in grating composed of left-handed materials

    Science.gov (United States)

    Tiwari, D. C.; Premlal, P. L.; Chaturvedi, Vandana

    2018-01-01

    In this work, we developed a unique mathematical model to solve dispersion relation for surface polaritons (SPs) in artificial composite materials grating. Here, we have taken two types of materials for analysis. In the first case, the grating composed of epsilon-negative (ENG) material and air interface. In second case, grating composed of left-handed materials (LHMs) and ENG medium interface is considered. The dispersion curves of both p and s polarized SPs modes are obtained analytically. In the case of ENG grating and air interface, polaritons dispersion curves exist for p-polarization only, whereas for LHM grating and ENG medium interface, the polaritons dispersion curves for both p and s polarization are observed.

  12. Facies of ion bombarded surfaces of brittle materials

    International Nuclear Information System (INIS)

    Primak, W.

    1975-12-01

    Materials were bombarded by protons, deuterons, and helium ions. The materials investigated were quartz; glasses; carbides and borides (SiC, B 4 C, TiB 2 ); oxides and nitrides (magnorite, sapphire, spinel, Al 2 O 3 , Si 3 N 4 , ZrO 2 , BaTiO 3 ); and miscellaneous (graphite, LiNbO 3 , copper). Oberservations were of growth, reflectivity, blistering, surface ablation, and swelling. Calculations were made of the effects of a layer, of its gradual transformation, and of the introduction of a gas. It is concluded that: Radiation blistering is not a primary process. Observations of blister formation and exfoliation cannot be used to calculate the surface ablation rate. The primary process is the development of a microporous layer which causes swelling. Visible blisters are caused by fracturing by transverse stresses in this layer and may occur during the bombardment, or in some cases, much later, in storage. There is no evidence of extreme gas pressures in the blisters. When blisters develop, they may be stable under continued bombardment for a dose many times that at which they formed. The swelling is a better index of the effects than is the blistering, and must be associated in most cases with permeability to the gas. Behavior with protons and deuterons is similar, with helium different. All but quartz, vitreous silica, and Pyrex are impervious to hydrogen and deuterium; only dense barium crown glass, carbides, borides, oxides, and nitrides are impervious to helium. Quartz shows swelling caused by conversion to a vitreous product of much lower density but no porosity, while for the others, most of the swelling and surface growth is caused by porosity. Surface ablation by the blistering process may be reduced by initial porosity or by initial or subsequent surface fissuring. However, for impervious materials, surface damage by the introduction of porosity would continue

  13. Directing neuronal cell growth on implant material surfaces by microstructuring.

    Science.gov (United States)

    Reich, Uta; Fadeeva, Elena; Warnecke, Athanasia; Paasche, Gerrit; Müller, Peter; Chichkov, Boris; Stöver, Timo; Lenarz, Thomas; Reuter, Günter

    2012-05-01

    For best hearing sensation, electrodes of auditory prosthesis must have an optimal electrical contact to the respective neuronal cells. To improve the electrode-nerve interface, microstructuring of implant surfaces could guide neuronal cells toward the electrode contact. To this end, femtosecond laser ablation was used to generate linear microgrooves on the two currently relevant cochlear implant materials, silicone elastomer and platinum. Silicone surfaces were structured by two different methods, either directly, by laser ablation or indirectly, by imprinting using laser-microstructured molds. The influence of surface structuring on neurite outgrowth was investigated utilizing a neuronal-like cell line and primary auditory neurons. The pheochromocytoma cell line PC-12 and primary spiral ganglion cells were cultured on microstructured auditory implant materials. The orientation of neurite outgrowth relative to the microgrooves was determined. Both cell types showed a preferred orientation in parallel to the microstructures on both, platinum and on molded silicone elastomer. Interestingly, microstructures generated by direct laser ablation of silicone did not influence the orientation of either cell type. This shows that differences in the manufacturing procedures can affect the ability of microstructured implant surfaces to guide the growth of neurites. This is of particular importance for clinical applications, since the molding technique represents a reproducible, economic, and commercially feasible manufacturing procedure for the microstructured silicone surfaces of medical implants. Copyright © 2012 Wiley Periodicals, Inc.

  14. Surface modification of microfibrous materials with nanostructured carbon

    Energy Technology Data Exchange (ETDEWEB)

    Krasnikova, Irina V., E-mail: tokareva@catalysis.ru [Boreskov Institute of Catalysis SB RAS, pr. Ac. Lavrentieva, 5, Novosibirsk 630090 (Russian Federation); National Research Tomsk Polytechnic University, Lenin av., 30, Tomsk 634050 (Russian Federation); Mishakov, Ilya V.; Vedyagin, Aleksey A. [Boreskov Institute of Catalysis SB RAS, pr. Ac. Lavrentieva, 5, Novosibirsk 630090 (Russian Federation); National Research Tomsk Polytechnic University, Lenin av., 30, Tomsk 634050 (Russian Federation); Bauman, Yury I. [Boreskov Institute of Catalysis SB RAS, pr. Ac. Lavrentieva, 5, Novosibirsk 630090 (Russian Federation); Korneev, Denis V. [State Research Center of Virology and Biotechnology VECTOR, Koltsovo, Novosibirsk Region 630559 (Russian Federation)

    2017-01-15

    The surface of fiberglass cloth, carbon and basalt microfibers was modified with carbon nanostructured coating via catalytic chemical vapor deposition (CCVD) of 1,2-dichloroethane. Incipient wetness impregnation and solution combustion synthesis (SCS) methods were used to deposit nickel catalyst on the surface of microfibrous support. Prepared NiO/support samples were characterized by X-ray diffraction analysis and temperature-programmed reduction. The samples of resulted hybrid materials were studied by means of scanning and transmission electron microscopies as well as by low-temperature nitrogen adsorption. The nature of the support was found to have considerable effect on the CCVD process peculiarities. High yield of nanostructured carbon with largest average diameter of nanofibers within the studied series was observed when carbon microfibers were used as a support. This sample characterized with moderate surface area (about 80 m{sup 2}/g after 2 h of CCVD) shows the best anchorage effect. Among the mineral supports, fiberglass tissue was found to provide highest carbon yield (up to 3.07 g/g{sub FG}) and surface area (up to 344 m{sup 2}/g) due to applicability of SCS method for Ni deposition. - Highlights: • The microfibers of different nature were coated with nanostructured carbon layer. • Features of CNF growth and characteristics of hybrid materials were studied. • Appropriate anchorage of CNF layer on microfiber’s surface was demonstrated.

  15. Technology of surface wastewater purification, including high-rise construction areas

    Science.gov (United States)

    Tsyba, Anna; Skolubovich, Yury

    2018-03-01

    Despite on the improvements in the quality of high-rise construction areas and industrial wastewater treatment, the pollution of water bodies continues to increase. This is due to the organized and unorganized surface untreated sewage entry into the reservoirs. The qualitative analysis of some cities' surface sewage composition is carried out in the work. Based on the published literature review, the characteristic contamination present in surface wastewater was identified. The paper proposes a new technology for the treatment of surface sewage and presents the results of preliminary studies.

  16. XPS analysis of nanostructured materials and biological surfaces

    International Nuclear Information System (INIS)

    Baer, D.R.; Engelhard, M.H.

    2010-01-01

    This paper examines the types of information that XPS can provide about a variety of nanostructured materials. Although it is sometimes not considered a 'nanoscale analysis method,' XPS can provide a great deal of information about elemental distributions, layer or coating structure and thicknesses, surface functionality, and even particles sizes on the 1-20 nm scale for sample types that may not be readily analyzed by other methods. This information is important for both synthetic nanostructured or nanosized materials and a variety of natural materials with nanostructure. Although the links between nanostructure materials and biological systems may not at first be obvious, many biological molecules and some organisms are the sizes of nanoparticles. The nanostructure of cells and microbes plays a significant role in how they interact with their environment. The interaction of biomolecules with nanoparticles is important for medical and toxicity studies. The interaction of biomolecules is important for sensor function and many nanomaterials are now the active elements in sensors. This paper first discusses how nanostructures influences XPS data as a part of understanding how simple models of sample structure and data analysis can be used to extract information about the physical and chemical structures of the materials being analyzed. Equally important, aspects of sample and analysis limitations and challenges associated with understanding nanostructured materials are indicated. Examples of the application of XPS to nanostructured and biological systems and materials are provided.

  17. Surface Coating of Gypsum-Based Molds for Maxillofacial Prosthetic Silicone Elastomeric Material: The Surface Topography.

    Science.gov (United States)

    Khalaf, Salah; Ariffin, Zaihan; Husein, Adam; Reza, Fazal

    2015-07-01

    This study aimed to compare the surface roughness of maxillofacial silicone elastomers fabricated in noncoated and coated gypsum materials. This study was also conducted to characterize the silicone elastomer specimens after surfaces were modified. A gypsum mold was coated with clear acrylic spray. The coated mold was then used to produce modified silicone experimental specimens (n = 35). The surface roughness of the modified silicone elastomers was compared with that of the control specimens, which were prepared by conventional flasking methods (n = 35). An atomic force microscope (AFM) was used for surface roughness measurement of silicone elastomer (unmodified and modified), and a scanning electron microscope (SEM) was used to evaluate the topographic conditions of coated and noncoated gypsum and silicone elastomer specimens (unmodified and modified) groups. After the gypsum molds were characterized, the fabricated silicone elastomers molded on noncoated and coated gypsum materials were evaluated further. Energy-dispersive X-ray spectroscopy (EDX) analysis of gypsum materials (noncoated and coated) and silicone elastomer specimens (unmodified and modified) was performed to evaluate the elemental changes after coating was conducted. Independent t test was used to analyze the differences in the surface roughness of unmodified and modified silicone at a significance level of p silicone elastomers processed against coated gypsum materials (p silicone elastomers. Silicone elastomers with lower surface roughness of maxillofacial prostheses can be obtained simply by coating a gypsum mold. © 2014 by the American College of Prosthodontists.

  18. Electron density in reasonably real metallic surfaces, including interchange and correlation effects

    International Nuclear Information System (INIS)

    Moraga, L.A.; Martinez, G.

    1981-01-01

    By means of a new method, the electron density in a jellium surface is calculated taking in account interchange and correlation effects; reproducing, in this way, the Lang and Kohn results. The new method is self-consistent but not iterative and hence is possible extend it to the solution of the same problem in more reasonably real metallic surfaces. (L.C.) [pt

  19. Method of extruding and packaging a thin sample of reactive material including forming the extrusion die

    International Nuclear Information System (INIS)

    Lewandowski, E.F.; Peterson, L.L.

    1985-01-01

    This invention teaches a method of cutting a narrow slot in an extrusion die with an electrical discharge machine by first drilling spaced holes at the ends of where the slot will be, whereby the oil can flow through the holes and slot to flush the material eroded away as the slot is being cut. The invention further teaches a method of extruding a very thin ribbon of solid highly reactive material such as lithium or sodium through the die in an inert atmosphere of nitrogen, argon or the like as in a glovebox. The invention further teaches a method of stamping out sample discs from the ribbon and of packaging each disc by sandwiching it between two aluminum sheets and cold welding the sheets together along an annular seam beyond the outer periphery of the disc. This provides a sample of high purity reactive material that can have a long shelf life

  20. Outcrops of plastic material on the surface of Venus

    Science.gov (United States)

    Ksanfomality, L. V.

    2015-05-01

    The archive data of the television experiment performed by the Venera-14 spacecraft on the surface of the planet Venus in March, 1982, were reprocessed, which significantly improved the image definition quality. An unusual geologic object located relatively near the camera was found, which allowed its details to be analyzed. The object is a low long bank in shape; it is formed by a relatively thin, jagged, almost vertical stratum. The bank contours the oval formation 1.5-2 m across that stands out against the layered surface. The location of the bank suggests that its material is extruded from under the layered plates surrounding the oval formation. A segment of the bank resembling a falling wave is inclined and partly covers the surface by forming the beddings. The object is likely formed by the rocks that remain semisoftened (plastic), when they appear on the surface at the temperature characteristic for the Venusian surface (about 740 K). It is suggested that, from the data on the physical and chemical conditions and the composition of the Venusian surface, the nature of the observed plastic medium can be hypothesized, and it can be even modeled under laboratory conditions.

  1. Surface Modification of Polymeric Materials by Plasma Treatment

    Directory of Open Access Journals (Sweden)

    E.F. Castro Vidaurre

    2002-03-01

    Full Text Available Low-temperature plasma treatment has been used in the last years as a useful tool to modify the surface properties of different materials, in special of polymers. In the present work low temperature plasma was used to treat the surface of asymmetric porous substrates of polysulfone (PSf membranes. The main purpose of this work was to study the influence of the exposure time and the power supplied to argon plasma on the permeability properties of the membranes. Three rf power levels, respectively 5, 10 and 15 W were used. Treatment time ranged from 1 to 50 min. Reduction of single gas permeability was observed with Ar plasma treatments at low energy bombardment (5 W and short exposure time (20 min. Higher power and/or higher plasma exposition time causes a degradation process begins. The chemical and structural characterization of the membranes before and after the surface modification was done by AFM, SEM and XPS.

  2. Recharacterization of Rhinophis dorsimaculatus Deraniyagala, 1941 (Serpentes: Uropeltidae), including description of new material.

    Science.gov (United States)

    Gower, David J; Wickramasinghe, L J Mendis

    2016-08-29

    The Sri Lankan uropeltid (shieldtail) snake Rhinophis dorsimaculatus Deraniyagala, 1941 was described originally from two specimens that were subsequently lost. The small amount of previously published data and lack of published colour photographs made this one of South Asia's most poorly known snake species, and this resulted in at least one instance of taxonomic misidentification. An additional 10 specimens from a historical collection from the vicinity of the type locality recently came to light. This material is reviewed and documented and the species recharacterized. An additional locality for the species is reported. The newly reported material helps to corroborate the taxonomic validity and distinctiveness of Rhinophis dorsimaculatus. The species is readily distinguished from congeners by having 227 or more ventral scales; a large, dorsally carinate rostral shield; posterior margins of paired anals that are largely separated by the posteriormost ventral scale; and a distinctive colour pattern with bilaterally asymmetrical dark blotches within a broad, pale middorsal stripe and regularly punctate flanks.

  3. Results of a Saxitoxin Proficiency Test Including Characterization of Reference Material and Stability Studies

    Directory of Open Access Journals (Sweden)

    Kirsi Harju

    2015-11-01

    Full Text Available A saxitoxin (STX proficiency test (PT was organized as part of the Establishment of Quality Assurance for the Detection of Biological Toxins of Potential Bioterrorism Risk (EQuATox project. The aim of this PT was to provide an evaluation of existing methods and the European laboratories’ capabilities for the analysis of STX and some of its analogues in real samples. Homogenized mussel material and algal cell materials containing paralytic shellfish poisoning (PSP toxins were produced as reference sample matrices. The reference material was characterized using various analytical methods. Acidified algal extract samples at two concentration levels were prepared from a bulk culture of PSP toxins producing dinoflagellate Alexandrium ostenfeldii. The homogeneity and stability of the prepared PT samples were studied and found to be fit-for-purpose. Thereafter, eight STX PT samples were sent to ten participating laboratories from eight countries. The PT offered the participating laboratories the possibility to assess their performance regarding the qualitative and quantitative detection of PSP toxins. Various techniques such as official Association of Official Analytical Chemists (AOAC methods, immunoassays, and liquid chromatography-mass spectrometry were used for sample analyses.

  4. Mechanical experiments on the superplastic material ALNOVI-1, including leak information

    Energy Technology Data Exchange (ETDEWEB)

    Snippe, Q.H.C., E-mail: csnippe@nikhef.nl; Meinders, T.

    2011-01-25

    Research highlights: {yields} Mechanical testing of superplastic materials, in particular ALNOVI-1. {yields} Uniaxial tests to show the one-dimensional stress-strain behaviour and the high amount of strain rate sensitivity. {yields} Void volume fractions have been observed. {yields} Free bulge experiments to show the dependence on the backpressure during the forming stage. {yields} Measuring leak tightness of superplastically formed sheets. {yields} Experiments are used in order to develop a constitutive model in a later stage. - Abstract: In subatomic particle physics, unstable particles can be detected with a so-called vertex detector, placed inside a particle accelerator. A detecting unit close to the accelerator bunch of charged particles must be separated from the accelerator vacuum. A thin sheet with a complex 3D shape prevents the detector vacuum from polluting the accelerator vacuum. Therefore, this sheet has to be completely leak tight. However, this can conflict with restrictions concerning maximum sheet thickness of the product. To produce such a complex thin sheet, superplastic forming can be very attractive in cases where a small number of products is needed. In order to predict gas permeability of these formed sheets, many mechanical experiments are necessary, where the gas leak has to be measured. To obtain insight in the mechanical behaviour of the used material, ALNOVI-1, tensile experiments were performed to describe the uniaxial stress-strain behaviour. From these experiments, a high strain rate sensitivity was measured. The flow stress of this material under superplastic conditions was low and the material behaved in an isotropic manner upon large plastic strains. The results of these experiments were used to predict the forming pressure as a function of time in a free bulge experiment, such that a predefined target strain rate will not be exceeded in the material. An extra parameter within these bulging experiments is the application of a

  5. Removal of PCB from indoor air and surface materials by introduction of additional sorbing materials

    DEFF Research Database (Denmark)

    Gunnarsen, Lars Bo; Lyng, Nadja; Kolarik, Barbara

    2017-01-01

    and slowly decontaminating old surface materials. In three bedrooms of a contaminated apartment respectively new painted gypsum boards, sheets of flexible polyurethane foam and activated carbon fabric were introduced. The PCB concentrations in room air were monitored before the intervention and several times...

  6. Surface modification of materials to encourage beneficial biofilm formation

    Directory of Open Access Journals (Sweden)

    Amreeta Sarjit

    2015-10-01

    Full Text Available Biofilms are communities of sessile microorganisms that grow and produce extrapolymeric substances on an abiotic or biotic surface. Although biofilms are often associated with negative impacts, the role of beneficial biofilms is wide and include applications in bioremediation, wastewater treatment and microbial fuel cells. Microbial adhesion to a surface, which is highly dependent on the physicochemical properties of the cells and surfaces, is an essential step in biofilm formation. Surface modification therefore represents an important way to modulate microbial attachment and ultimately biofilm formation by microorganisms. In this review different surface modification processes such as organosilane surface modification, plasma treatment, and chemical modification of carbon nanotubes, electro-oxidation and covalent-immobilization with neutral red and methylene blue molecules are outlined. The effectiveness of these modifications and their industrial applications are also discussed. There is inadequate literature on surface modification as a process to enhance beneficial biofilm formation. These methods need to be safe, economically viable, scalable and environmental friendly and their potential to fulfil these criteria for many applications has yet to be determined.

  7. Simultaneous measurements of work function and H‒ density including caesiation of a converter surface

    Science.gov (United States)

    Cristofaro, S.; Friedl, R.; Fantz, U.

    2017-08-01

    Negative hydrogen ion sources rely on the surface conversion of neutral atomic hydrogen and positive hydrogen ions to H-. The efficiency of this process depends on the actual work function of the converter surface. By introducing caesium into the source the work function decreases, enhancing the negative ion yield. In order to study the impact of the work function on the H- surface production at similar conditions to the ones in ion sources for fusion devices like ITER and DEMO, fundamental investigations are performed in a flexible laboratory experiment. The work function of the converter surface can be absolutely measured by photoelectric effect, while a newly installed cavity ring-down spectroscopy system (CRDS) measures the H- density. The CRDS is firstly tested and characterized by investigations on H- volume production. Caesiation of a stainless steel sample is then performed in vacuum and the plasma effect on the Cs layer is investigated also for long plasma-on times. A minimum work function of (1.9±0.1) eV is reached after some minutes of plasma treatment, resulting in a reduction by a value of 0.8 eV compared to vacuum measurements. The H- density above the surface is (2.1±0.5)×1015 m-3. With further plasma exposure of the caesiated surface, the work function increases up to 3.75 eV, due to the impinging plasma particles which gradually remove the Cs layer. As a result, the H- density decreases by a factor of at least 2.

  8. Development of microwave absorbing materials prepared from a polymer binder including Japanese lacquer and epoxy resin

    Science.gov (United States)

    Iwamaru, T.; Katsumata, H.; Uekusa, S.; Ooyagi, H.; Ishimura, T.; Miyakoshi, T.

    Microwave absorption composites were synthesized from a poly urushiol epoxy resin (PUE) mixed with one of microwave absorbing materials; Ni-Zn ferrite, Soot, Black lead, and carbon nano tube (CNT) to investigate their microwave absorption properties. PUE binders were specially made from Japanese lacquer and epoxy resin, where Japanese lacquer has been traditionally used for bond and paint because it has excellent beauty. Japanese lacquer solidifies with oxygen contained in air's moisture, which has difficulty in making composite, but we improved Japanese lacquer's solidification properties by use of epoxy resin. We made 10 mm thickness composite samples and cut them into toroidal shape to measure permittivity, permeability, and reflection loss in frequencies ranging from 50 Hz to 20 GHz. Electric magnetic absorber's composites synthesized from a PUE binders mixed either with Soot or CNT showed significantly higher wave absorption over -27 dB than the others at frequencies around 18 GHz, although Japanese lacquer itself doesn't affect absorption. This means Japanese lacquer can be used as binder materials for microwave absorbers.

  9. Ion doping of surface layers in conducting electrical materials

    International Nuclear Information System (INIS)

    Zukowski, P.; Karwat, Cz.; Kozak, Cz. M.; Kolasik, M.; Kiszczak, K.

    2009-01-01

    The presented article gives basic component elements of an implanter MKPCz-99, its parameters and methods for doping surface layers of conducting electrical materials. The discussed device makes possible to dope the materials with ions of gaseous elements. At the application of cones made of solid-element sheets it is possible to perform doping with atoms that do not chemically react with the modified material. By performing voltage drop measurements with a specialized circuit between a movable testing electrode and the modified sample the dependence of transition resistance on pressure force of the testing electrode on the sample can be determined. The testing can be performed at the current passage of a determined value for surfaces modified with ions of gaseous elements or atoms of solid elements. A computer stand for switch testing makes possible to measure temperature of switch contacts and voltage drop at the contact and thereby to determine contact resistance of a switch depending on the number of switch cycles (ON-OFF). Pattern recording of current and voltage at the switch contacts and the application of an adequate computer software makes possible to determined the value of energy between fixed and moving contacts at their getting apart. In order to eliminate action of the environment onto the switch operation measurements can be performed at placing the tested switch together with the driving system in an atmosphere of noble gas like argon. (authors)

  10. Mapping Carrier Dynamics on Material Surfaces in Space and Time using Scanning Ultrafast Electron Microscopy

    KAUST Repository

    Sun, Jingya

    2016-02-25

    Selectively capturing the ultrafast dynamics of charge carriers on materials surfaces and at interfaces is crucial to the design of solar cells and optoelectronic devices. Despite extensive research efforts over the past few decades, information and understanding about surface-dynamical processes, including carrier trapping and recombination remains extremely limited. A key challenge is to selectively map such dynamic processes, a capability that is hitherto impractical by time-resolved laser techniques, which are limited by the laser’s relatively large penetration depth and consequently they record mainly bulk information. Such surface dynamics can only be mapped in real space and time by applying four-dimensional (4D) scanning ultrafast electron microscopy (S-UEM), which records snapshots of materials surfaces with nanometer spatial and sub-picosecond temporal resolutions. In this method, the secondary electron (SE) signal emitted from the sample’s surface is extremely sensitive to the surface dynamics and is detected in real time. In several unique applications, we spatially and temporally visualize the SE energy gain and loss, the charge carrier dynamics on the surface of InGaN nanowires and CdSe single crystals and its powder film. We also provide the mechanisms for the observed dynamics, which will be the foundation for future potential applications of S-UEM to a wide range of studies on material surfaces and device interfaces.

  11. Surface wave site characterization at 27 locations near Boston, Massachusetts, including 2 strong-motion stations

    Science.gov (United States)

    Thompson, Eric M.; Carkin, Bradley A.; Baise, Laurie G.; Kayen, Robert E.

    2014-01-01

    The geotechnical properties of the soils in and around Boston, Massachusetts, have been extensively studied. This is partly due to the importance of the Boston Blue Clay and the extent of landfill in the Boston area. Although New England is not a region that is typically associated with seismic hazards, there have been several historical earthquakes that have caused significant ground shaking (for example, see Street and Lacroix, 1979; Ebel, 1996; Ebel, 2006). The possibility of strong ground shaking, along with heightened vulnerability from unreinforced masonry buildings, motivates further investigation of seismic hazards throughout New England. Important studies that are pertinent to seismic hazards in New England include source-parameter studies (Somerville and others, 1987; Boore and others, 2010), wave-propagation studies (Frankel, 1991; Viegas and others, 2010), empirical ground-motion prediction equations (GMPE) for computing ground-motion intensity (Tavakoli and Pezeshk, 2005; Atkinson and Boore, 2006), site-response studies (Hayles and others, 2001; Ebel and Kim, 2006), and liquefaction studies (Brankman and Baise, 2008). The shear-wave velocity (VS) profiles collected for this report are pertinent to the GMPE, site response, and liquefaction aspects of seismic hazards in the greater Boston area. Besides the application of these data for the Boston region, the data may be applicable throughout New England, through correlations with geologic units (similar to Ebel and Kim, 2006) or correlations with topographic slope (Wald and Allen, 2007), because few VS measurements are available in stable tectonic regions.Ebel and Hart (2001) used felt earthquake reports to infer amplification patterns throughout the greater Boston region and noted spatial correspondence with the dominant period and amplification factors obtained from ambient noise (horizontal-to-vertical ratios) by Kummer (1998). Britton (2003) compiled geotechnical borings in the area and produced a

  12. Comparison of glass surfaces as a countertop material to existing surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Turo, Laura A.; Winschell, Abigail E.

    2011-09-01

    Gleen Glass, a small production glass company that creates countertops, was selected for the Technology Assistance Program through Pacific Northwest National Laboratory. Gleen Glass was seeking material property analysis comparing glass as a countertop material to current surfaces (i.e. marble, granite and engineered stone). With samples provided from Gleen Glass, testing was done on granite, marble, and 3 different glass surfaces ('Journey,' 'Pebble,' and 'Gleen'). Results showed the glass surfaces have a lower density, lower water absorption, and are stronger in compressive and flexural tests as compared to granite and marble. Thermal shock tests showed the glass failed when objects with a high thermal mass are placed directly on them, whereas marble and granite did not fracture under these conditions.

  13. Seven-wavelength pyrometer for determining surface temperature of ablation materials

    Science.gov (United States)

    Yi, H.

    1985-01-01

    Results which were achieved by a seven-wavelength pyrometer last year are reported in this paper. These studies are directed toward the development of a method for determining the real surface temperature of thermal protection materials and for evaluating its emittance under varieties of reentry environment. A description of the data processing method and apparatus is also included.

  14. New Material Development for Surface Layer and Surface Technology in Tribology Science to Improve Energy Efficiency

    Science.gov (United States)

    Ismail, R.; Tauviqirrahman, M.; Jamari, Jamari; Schipper, D. J.

    2009-09-01

    This paper reviews the development of new material and surface technology in tribology and its contribution to energy efficiency. Two examples of the economic benefits, resulted from the optimum tribology in the transportation sector and the manufacturing industry are discussed. The new materials are proposed to modify the surface property by laminating the bulk material with thin layer/coating. Under a suitable condition, the thin layer on a surface can provide a combination of good wear, a low friction and corrosion resistance for the mechanical components. The innovation in layer technology results molybdenum disulfide (MoS2), diamond like carbon (DLC), cubic boron nitride (CBN) and diamond which perform satisfactory outcome. The application of the metallic coatings to carbon fibre reinforced polymer matrix composites (CFRP) has the capacity to provide considerable weight and power savings for many engineering components. The green material for lubricant and additives such as the use of sunflower oil which possesses good oxidation resistance and the use of mallee leaves as bio-degradable solvent are used to answer the demand of the environmentally friendly material with good performance. The tribology research implementation for energy efficiency also touches the simple things around us such as: erasing the laser-print in a paper with different abrasion techniques. For the technology in the engineering surface, the consideration for generating the suitable surface of the components in running-in period has been discussed in order to prolong the components life and reduce the machine downtime. The conclusion, tribology can result in reducing manufacturing time, reducing the maintenance requirements, prolonging the service interval, improving durability, reliability and mechanical components life, and reducing harmful exhaust emission and waste. All of these advantages will increase the energy efficiency and the economic benefits.

  15. Characterization of the damage produced on different materials surfaces

    International Nuclear Information System (INIS)

    Dellavale Clara, Hector Damian

    2004-01-01

    In the present work the characterization techniques of surfaces ULOI and RIMAPS have been applied on laboratory samples made from aluminium, stainless steel and material based on fiberglass.The resultant surfaces of, chemical etching with corrosive agents Keller and Tucker, mechanic damage from the wear and tear of abrasive paper and sandrubbing with alumina particles, are analyzed to different level of damage.The systematic application of the above mentioned techniques is carried out with the objective of finding information, which allows to characterize the superficial damage, both in its incipient state as in the extreme situation revealed by the presence of etch pits. Important results have been obtained, in the characterization of the incipient stage of the chemical etching, using the curves of the normalized area.In addition, it was possible to verify the capacity of the techniques in the early detection of the preferential directions generated by the etch pits

  16. Photometric stereo sensor for robot-assisted industrial quality inspection of coated composite material surfaces

    Science.gov (United States)

    Weigl, Eva; Zambal, Sebastian; Stöger, Matthias; Eitzinger, Christian

    2015-04-01

    While composite materials are increasingly used in modern industry, the quality control in terms of vision-based surface inspection remains a challenging task. Due to the often complex and three-dimensional structures, a manual inspection of these components is nearly impossible. We present a photometric stereo sensor system including an industrial robotic arm for positioning the sensor relative to the inspected part. Two approaches are discussed: stop-and-go positioning and continuous positioning. Results are presented on typical defects that appear on various composite material surfaces in the production process.

  17. Comprehensive capacitance-voltage analysis including quantum effects for high-k interfaces on germanium and other alternative channel materials

    Science.gov (United States)

    Anwar, Sarkar R. M.

    High mobility alternative channel materials to silicon are critical to the continued scaling of metal oxide semiconductor (MOS) devices. However, before they can be incorporated into advanced devices, some major issues need to be solved. The high mobility materials suffer from lower allowable thermal budgets compared to Si (before desorption and defect formation becomes an issue) and the absence of a good quality native oxide has further increased the interest in the use of high-k dielectrics. However, the high interface state density and high electric fields at these semiconductor/high-k interfaces can significantly impact the capacitance-voltage (C-V) profile, and current C-V modeling software cannot account for these effects. This in turn affects the parameters extracted from the C-V data of the high mobility semiconductor/high-k interface, which are crucial to fully understand the interface properties and expedite process development. To address this issue, we developed a model which takes into account quantum corrections which can be applied to a number of these alternative channel materials including SixGe1-x, Ge, InGaAs, and GaAs. The C-V simulation using this QM correction model is orders of magnitude faster compared to a full band Schrodinger-Poisson solver. The simulated C-V is directly benchmarked to a self consistent Schrodinger-Poisson solution for each bulk semiconductor material, and from the benchmarking process the QM correction parameters are extracted. The full program, C-V Alternative Channel Extraction (CV ACE), incorporates a quantum mechanical correction model, along with the interface state density model, and can extract device parameters such as equivalent oxide thickness (EOT), doping density and flat band voltage (Vfb) as well as the interface state density profile using multiple measurements performed at different frequencies and temperatures, simultaneously. The program was used to analyze experimentally measured C-V profiles and the

  18. Method for producing high surface area chromia materials for catalysis

    Science.gov (United States)

    Gash, Alexander E [Brentwood, CA; Satcher, Joe [Patterson, CA; Tillotson, Thomas [Tracy, CA; Hrubesh, Lawrence [Pleasanton, CA; Simpson, Randall [Livermore, CA

    2007-05-01

    Nanostructured chromium(III)-oxide-based materials using sol-gel processing and a synthetic route for producing such materials are disclosed herein. Monolithic aerogels and xerogels having surface areas between 150 m.sup.2/g and 520 m.sup.2/g have been produced. The synthetic method employs the use of stable and inexpensive hydrated-chromium(III) inorganic salts and common solvents such as water, ethanol, methanol, 1-propanol, t-butanol, 2-ethoxy ethanol, and ethylene glycol, DMSO, and dimethyl formamide. The synthesis involves the dissolution of the metal salt in a solvent followed by an addition of a proton scavenger, such as an epoxide, which induces gel formation in a timely manner. Both critical point (supercritical extraction) and atmospheric (low temperature evaporation) drying may be employed to produce monolithic aerogels and xerogels, respectively.

  19. On the modelling of semi-insulating GaAs including surface tension and bulk stresses

    Energy Technology Data Exchange (ETDEWEB)

    Dreyer, W.; Duderstadt, F.

    2004-07-01

    Necessary heat treatment of single crystal semi-insulating Gallium Arsenide (GaAs), which is deployed in micro- and opto- electronic devices, generate undesirable liquid precipitates in the solid phase. The appearance of precipitates is influenced by surface tension at the liquid/solid interface and deviatoric stresses in the solid. The central quantity for the description of the various aspects of phase transitions is the chemical potential, which can be additively decomposed into a chemical and a mechanical part. In particular the calculation of the mechanical part of the chemical potential is of crucial importance. We determine the chemical potential in the framework of the St. Venant-Kirchhoff law which gives an appropriate stress/strain relation for many solids in the small strain regime. We establish criteria, which allow the correct replacement of the St. Venant-Kirchhoff law by the simpler Hooke law. The main objectives of this study are: (i) We develop a thermo-mechanical model that describes diffusion and interface motion, which both are strongly influenced by surface tension effects and deviatoric stresses. (ii) We give an overview and outlook on problems that can be posed and solved within the framework of the model. (iii) We calculate non-standard phase diagrams, i.e. those that take into account surface tension and non-deviatoric stresses, for GaAs above 786 C, and we compare the results with classical phase diagrams without these phenomena. (orig.)

  20. Growth of crystalline semiconductor materials on crystal surfaces

    CERN Document Server

    Aleksandrov, L

    2013-01-01

    Written for physicists, chemists, and engineers specialising in crystal and film growth, semiconductor electronics, and various applications of thin films, this book reviews promising scientific and engineering trends in thin films and thin-films materials science. The first part discusses the physical characteristics of the processes occurring during the deposition and growth of films, the principal methods of obtaining semiconductor films and of reparing substrate surfaces on which crystalline films are grown, and the main applications of films. The second part contains data on epitaxial i

  1. Application of MEVVA discharge to material surface modification

    International Nuclear Information System (INIS)

    Gao Yu; Geng Man; Huang Yuming; Gong Xiaorong; Yu Yijun; Tang Deli; Tie Jun

    1996-01-01

    The authors describes some characteristics of the MEVVA discharge, the process of generating a cathode-arc plasma and the advantages of the MEVVA discharge compared with the kind of heating-vaporizing-ionizing source. Some practical parameters and the operating process of the MEVVA ion source as well as a plasma source with MEVVA discharge used in a PSII device are presented. Various plasmas having good-quality and high-performance are obtained with MEVVA discharges and have been widely used in sight-line processing and omnibearing ion implantation for material surface modification

  2. Breakage mechanics for granular materials in surface-reactive environments

    Science.gov (United States)

    Zhang, Yida; Buscarnera, Giuseppe

    2018-03-01

    It is known that the crushing behaviour of granular materials is sensitive to the state of the fluids occupying the pore space. Here, a thermomechanical theory is developed to link such macroscopic observations with the physico-chemical processes operating at the microcracks of individual grains. The theory relies on the hypothesis that subcritical fracture propagation at intra-particle scale is the controlling mechanism for the rate-dependent, water-sensitive compression of granular specimens. First, the fracture of uniaxially compressed particles in surface-reactive environments is studied in light of irreversible thermodynamics. Such analysis recovers the Gibbs adsorption isotherm as a central component linking the reduction of the fracture toughness of a solid to the increase of vapour concentration. The same methodology is then extended to assemblies immersed in wet air, for which solid-fluid interfaces have been treated as a separate phase. It is shown that this choice brings the solid surface energy into the dissipation equations of the granular matrix, thus providing a pathway to (i) integrate the Gibbs isotherm with the continuum description of particle assemblies and (ii) reproduce the reduction of their yield strength in presence of high relative humidity. The rate-effects involved in the propagation of cracks and the evolution of breakage have been recovered by considering non-homogenous dissipation potentials associated with the creation of surface area at both scales. It is shown that the proposed model captures satisfactorily the compression response of different types of granular materials subjected to varying relative humidity. This result was achieved simply by using parameters based on the actual adsorption characteristics of the constituting minerals. The theory therefore provides a physically sound and thermodynamically consistent framework to study the behaviour of granular solids in surface-reactive environments.

  3. Surface, interface and bulk materials characterization using Indus synchrotron sources

    International Nuclear Information System (INIS)

    Phase, Deodatta M.

    2014-01-01

    Synchrotron radiation sources, providing intense, polarized and stable beams of ultra violet, soft and hard x-ray photons, are having great impact on physics, chemistry, biology, materials science and other areas research. In particular synchrotron radiation has revolutionized materials characterization techniques by enhancing its capabilities for investigating the structural, electronic and magnetic properties of solids. The availability of synchrotron sources and necessary instrumentation has led to considerable improvements in spectral resolution and intensities. As a result, application scope of different materials characterization techniques has tremendously increased particularly in the analysis of solid surfaces, interfaces and bulk materials. The Indian synchrotron storage ring, Indus-1 and Indus-2 are in operation at RRCAT, Indore. The UGC-DAE CSR with the help of university scientist had designed and developed an angle integrated photoelectron spectroscopy (AlPES) beam line on Indus-1 storage ring of 450 MeV and polarized light beam line for soft x-ray absorption spectroscopy (SXAS) on Indus-2 storage ring of 2.5 GeV. (author)

  4. [Clinical and microbiological study regarding surface antibacterial properties of bioactive dental materials].

    Science.gov (United States)

    Târcă, T; Bădescu, Aida; Topoliceanu, C; Lăcătuşu, St

    2010-01-01

    In the new era of dentistry the coronal restoration materials must possess "bio-active" features represented by fluor ions release, chemical adhesion and antibacterial agents. Our study aims to determine the surface antibacterial properties of glassionomer cements and compomers. The study group included 64 patients with high cariogenic risk with 80 teeth with acute and chronic dental caries affecting proximal and occlusal dental surfaces. The teeth with cariogenic lesions were restored with zinc-oxide-eugenol (n=20), glassionomer cement GC Fuji Triage (n=20), glassionomer cement modified with resins Fuji II LC (n=20), compomer Dyract (n=20). DENTOCULT SM test (Orion Diagnostica, Finland) was used for bacterial analyses. The samples from bacterial biofilm were collected from the restorated dental surfaces (study group) and intact enamel surfaces (control group). The recorded data were processed using non-parametrical statistical tests. The lowest mean value of bacterial indices was recorded for glassionomer cement Fuji Triage (0.4), and Fuji II LC (1.2), material with highest surface antibacterial properties. The highest value (1.5) was recorded for compomer Dyract. The Kruskal-Wallis test proves the significant statistical differences between the three bioactive materials. The materials with bioactive features have the ability to inhibate the growth of Streptococcus mutans in bacterial biofilm to the surfaces of coronal restoration.

  5. Application of Glow Discharge Plasma to Alter Surface Properties of Materials

    Science.gov (United States)

    Trigwell, Steve; Buhler, Charles R.; Calle, Carlos I.

    2005-01-01

    Some polymer materials that are considered important for spaceport operations are rendered noncompliant when subjected to the Kennedy Space Center (KSC) Standard electrostatic testing. These materials operate in stringent environmental conditions, such as high humidity. Treating materials that fail electrostatic testing and altering their surface properties so that they become compliant would result in considerable cost savings. Significant improvement in electrostatic dissipation of Saf-T-Vu PVC after treatment with air Atmospheric Plasma Glow Discharge (APGD) was observed and the material now passed the KSC electrostatic test. The O:C ratio on the surface, as monitored by X-ray Photoelectron Spectroscopy, increased from 0.165 tO 0.275 indicating enhanced oxidation, and surface contact angle measurements decreased from 107.5 to 72.6 showing increased hydrophilicity that accounted for the increased conductivity. Monitoring of the aging showed that the materials hydrophobic recovery resulted in it failing the electrostatic test 30 hours after treatment. This was probably due to the out-diffusion of the added Zn, Ba, and Cd salt stabilizers detected on the surface and/or diffusion of low molecular weight oligomers. On going work includes improving the long term hydrophilicity by optimizing the APGD process with different gas mixtures. Treatment of other spaceport materials is also presented.

  6. Electric fields, weighting fields, signals and charge diffusion in detectors including resistive materials

    International Nuclear Information System (INIS)

    Riegler, W.

    2016-01-01

    In this report we discuss static and time dependent electric fields in detector geometries with an arbitrary number of parallel layers of a given permittivity and weak conductivity. We derive the Green's functions i.e. the field of a point charge, as well as the weighting fields for readout pads and readout strips in these geometries. The effect of 'bulk' resistivity on electric fields and signals is investigated. The spreading of charge on thin resistive layers is also discussed in detail, and the conditions for allowing the effect to be described by the diffusion equation is discussed. We apply the results to derive fields and induced signals in Resistive Plate Chambers, MICROMEGAS detectors including resistive layers for charge spreading and discharge protection as well as detectors using resistive charge division readout like the MicroCAT detector. We also discuss in detail how resistive layers affect signal shapes and increase crosstalk between readout electrodes.

  7. Method for contamination control and barrier apparatus with filter for containing waste materials that include dangerous particulate matter

    Science.gov (United States)

    Pinson, Paul A.

    1998-01-01

    A container for hazardous waste materials that includes air or other gas carrying dangerous particulate matter has incorporated in barrier material, preferably in the form of a flexible sheet, one or more filters for the dangerous particulate matter sealably attached to such barrier material. The filter is preferably a HEPA type filter and is preferably chemically bonded to the barrier materials. The filter or filters are preferably flexibly bonded to the barrier material marginally and peripherally of the filter or marginally and peripherally of air or other gas outlet openings in the barrier material, which may be a plastic bag. The filter may be provided with a backing panel of barrier material having an opening or openings for the passage of air or other gas into the filter or filters. Such backing panel is bonded marginally and peripherally thereof to the barrier material or to both it and the filter or filters. A coupling or couplings for deflating and inflating the container may be incorporated. Confining a hazardous waste material in such a container, rapidly deflating the container and disposing of the container, constitutes one aspect of the method of the invention. The chemical bonding procedure for producing the container constitutes another aspect of the method of the invention.

  8. Multi trace element analysis of dry biological materials by neutron activation analysis including a chemical group separation

    International Nuclear Information System (INIS)

    Weers, C.A.

    1980-07-01

    Multi-element analysis of dry biological material by neutron activation analysis has to include radiochemical separation. The evaporation process is described in terms of the half-volume. The pretreatment of the samples and the development of the destruction-evaporation apparatus are described. The successive adsorption steps with active charcoal, Al 2 O 3 and coprecipitation with Fe(OH) 3 are described. Results obtained for standard reference materials are summarized. (G.T.H.)

  9. Determining surface wave attenuation by modeling surface wave amplitudes including finite-frequency focusing and defocusing effects

    Science.gov (United States)

    Ma, Z.; Masters, G.

    2011-12-01

    We have developed a technique that uses cluster analysis method to efficiently measure Rayleigh wave phase and amplitude anomalies. Amplitude anomaly measurements have been made on the vertical components of all permanent stations recording LHZ data from IRIS. We currently consider earthquakes with Ms>5.5 between 1990 and 2004 and correct for source phase and magnitude according to the CMT. This technique leads to a large set of amplitude measurements at 7mHz, 10mHz, 15mHz and 20mHz. We discard data with erroneously large amplitude anomalies (|dlnA|>1) and inconsistent instrument responses and we only use earthquakes recorded by more than 30 stations. Out of about 250000 raw measurements for each frequency, about 140000 measurements are retained for inverting for attenuation structure. Similar to Dalton and Ekstrom (2006), phase and amplitude data are inverted together for phase velocity maps, attenuation maps, and source and receiver terms. However, we use the 2D finite frequency amplitude kernel of Zhou et al, (2004) to model the focusing-defocusing effects. Ray theory, which has been used to date, gives amplitude anomaly predictions which depend strongly on short wavelength structure and so are very sensitive to how phase velocity maps are smoothed. Our resulting attenuation maps show structures correlating well with surface tectonics, with high attenuation in regions of ridges, back-arc basins and western North America, and low attenuation in stable continental shields. The success of getting reasonable attenuation structures demonstrates the feasibility of applying 2D finite frequency amplitude kernel to real data.

  10. Crack propagation in disordered materials: how to decipher fracture surfaces

    Science.gov (United States)

    Ponson, L.

    For a half-century, engineers know how to describe and predict the propagation of a crack in a model elastic homogeneous medium. The case of real materials is much more complex. Indeed, we do not know how to relate their lifetime or their resistance to their microstructure. To achieve such a prediction, understanding the role of the microstructural disorder on the behavior of a crack is determinant. Fracture surfaces represent a promising field of investigation to address this question. From the study of various disordered materials, we propose a statistical description of their roughness and determine to which extent their properties are dependent of the material. We show that fracture surfaces display an anisotropic scale invariant geometry characterized by two universal exponents. Glass ceramics is then studied because its microstructure can be tuned in a controlled manner. Their fracture surfaces display the same general anisotropic properties but with surprisingly low exponents independent of the detail of the ceramics microstructure. This suggests the existence of a second universality class in failure problems. Using finally theoretical tools from out-of-equilibrium statistical physics and fracture mechanics, we relate the statistical properties of fracture surfaces with the mechanisms occurring at the microscopic scale during the failure of a material. In particular, we show that the first class of fracture surfaces results from a failure involving damage processes while the second one results from a perfectly brittle failure. Propagation de fissures dans les matériaux désordonnés : comment déchiffrer les surfaces de rupture. Depuis près d'un demi-siècle, les ingénieurs savent décrire et prévoir la propagation d'une fissure dans un milieu élastique homogène modèle. Le cas des matériaux réels est beaucoup plus complexe. En effet, on ne sait pas relier leur durée de vie ou leur résistance à leur microstructure. Passage obligé avant de telles

  11. CONFERENCE SUMMARY: Summary and comment on superconducting analogue electronics research, including materials and fabrication, as presented at ISEC 07

    Science.gov (United States)

    Foley, C. P.

    2007-11-01

    The main theme at ISEC 2007 for superconducting materials, fabrication and analogue electronics was the description of incremental developments, including a few new directions that indicate breakthroughs in this area of research. The work on applications focused on their cost-benefit analysis (in order to improve their appeal), the development of simpler systems, making more of the data collected, improving packaging and being responsive to the power handling requirements for commercial systems. All papers presenting this level of research highlighted the importance of obtaining all the necessary details in order to investigate analogue devices and the effectiveness and commercial viability of their systems. This stage of development is important if we are to achieve the transition of superconducting electronics from the laboratory to commercial use. There were some exciting disruptive breakthroughs reported. These were in the areas of nano-SQUIDs, rotating gradiometers, superconducting scanning tunnelling microscopy (Hayashi et al) and the potential of superconducting photonics using optical interfaces with superconducting vortex flow transistors, for example. The materials research in low (LTS), high (HTS) and medium (MTS) critical temperature superconductors was reported. In LTS, nitrides emerged as important materials for use as new tunnel barriers, either insulating or semiconducting. Papers on BaN, NbN, TaN, GaN and Nb-Si superconducting materials were also presented. The MTS material of MgB2 is still under development (Zhao et al). There were also new research groups from South Africa and Turkey attending the conference. The fabrication research presented covered the areas of critical current Ic spread, which is still an issue in reducing the reproducibility of Josephson junctions, a 150 mm process for Nb/Al-AlOx/Nb and methods to improve barrier layers using both new materials and smooth surfaces at thin film interfaces (Du et al). New methods to make sub

  12. Colour measurements of surfaces to evaluate the restoration materials

    Science.gov (United States)

    Lo Monaco, Angela; Marabelli, Maurizio; Pelosi, Claudia; Picchio, Rodolfo

    2011-06-01

    In this paper two case studies on the application of colour measurements for the evaluation of some restoration materials are discussed. The materials related to the research are: watercolours employed in restoration of wall paintings and preservative/consolidants for wood artifacts. Commercial watercolours, supplied by Maimeri, Windsor&Newton and Talens factories have been tested. Colour measurements have been performed by means of a reflectance spectrophotometer (RS) before and after accelerated ageing of watercolours at 92% relative humidity (RH) and in a Solar Box chamber. The experimental results show that watercolours based on natural earths and artificial ultramarine undergo the main colour changes, expressed as L*, a* and b* variations and total colour difference (▵E*). In the other cases colour differences depend on both watercolour typology and suppliers. The other example concerns the evaluation of colour change due to surface treatment of Poplar (Populus sp.) and chestnut (Castanea sativa L.) wood samples. The wooden samples have been treated with a novel organic preservative/consolidant product that has been tested also in a real case as comparison. The treated samples have been artificially aged in Solar Box chamber equipped with a 280 nm UV filter. Colour has been measured before and after the artificial ageing by means of a RS. Colour changes have been determined also for the main door of an historical mansion in Viterbo, made of chestnut wood, and exposed outdoors.

  13. Surface plasmon resonance sensors a materials guide to design and optimization

    CERN Document Server

    Oliveira, Leiva Casemiro; Thirstrup, Carsten; Neff, Helmut Franz

    2015-01-01

    This book addresses the important physical phenomenon of Surface Plasmon Resonance or Surface Plasmon Polaritons in thin metal films, a phenomenon which is exploited in the design of a large variety of physico-chemical optical sensors. In this treatment, crucial materials aspects for design and optimization of SPR sensors are investigated and outlined in detail. The text covers the selection of nanometer thin metal films, ranging from free-electron to the platinum type conductors, along with their combination with a large variety of dielectric substrate materials, and associated individual layer and opto-geometric arrangements. Furthermore, as-yet hardly explored SPR features of selected metal–metal and metal–dielectric super lattices are included in this report. An in-depth multilayer Fresnel evaluation provides the mathematical tool for this optical analysis, which otherwise relies solely on experimentally determined electro-optical materials parameters.

  14. Improved explosive collection and detection with rationally assembled surface sampling materials

    Energy Technology Data Exchange (ETDEWEB)

    Chouyyok, Wilaiwan; Bays, J. Timothy; Gerasimenko, Aleksandr A.; Cinson, Anthony D.; Ewing, Robert G.; Atkinson, David A.; Addleman, R. Shane

    2016-01-01

    Sampling and detection of trace explosives is a key analytical process in modern transportation safety. In this work we have explored some of the fundamental analytical processes for collection and detection of trace level explosive on surfaces with the most widely utilized system, thermal desorption IMS. The performance of the standard muslin swipe material was compared with chemically modified fiberglass cloth. The fiberglass surface was modified to include phenyl functional groups. When compared to standard muslin, the phenyl functionalized fiberglass sampling material showed better analyte release from the sampling material as well as improved response and repeatability from multiple uses of the same swipe. The improved sample release of the functionalized fiberglass swipes resulted in a significant increase in sensitivity. Various physical and chemical properties were systematically explored to determine optimal performance. The results herein have relevance to improving the detection of other explosive compounds and potentially to a wide range of other chemical sampling and field detection challenges.

  15. Expansion Hamiltonian model for a diatomic molecule adsorbed on a surface: Vibrational states of the CO/Cu(100) system including surface vibrations

    Energy Technology Data Exchange (ETDEWEB)

    Meng, Qingyong, E-mail: mengqingyong@dicp.ac.cn [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Zhongshan Road 457, 116023 Dalian (China); Meyer, Hans-Dieter, E-mail: hans-dieter.meyer@pci.uni-heidelberg.de [Theoretische Chemie, Physikalisch-Chemisches Institut, Ruprecht-Karls Universität Heidelberg, Im Neuenheimer Feld 229, D-69120 Heidelberg (Germany)

    2015-10-28

    Molecular-surface studies are often done by assuming a corrugated, static (i.e., rigid) surface. To be able to investigate the effects that vibrations of surface atoms may have on spectra and cross sections, an expansion Hamiltonian model is proposed on the basis of the recently reported [R. Marquardt et al., J. Chem. Phys. 132, 074108 (2010)] SAP potential energy surface (PES), which was built for the CO/Cu(100) system with a rigid surface. In contrast to other molecule-surface coupling models, such as the modified surface oscillator model, the coupling between the adsorbed molecule and the surface atoms is already included in the present expansion SAP-PES model, in which a Taylor expansion around the equilibrium positions of the surface atoms is performed. To test the quality of the Taylor expansion, a direct model, that is avoiding the expansion, is also studied. The latter, however, requests that there is only one movable surface atom included. On the basis of the present expansion and direct models, the effects of a moving top copper atom (the one to which CO is bound) on the energy levels of a bound CO/Cu(100) system are studied. For this purpose, the multiconfiguration time-dependent Hartree calculations are carried out to obtain the vibrational fundamentals and overtones of the CO/Cu(100) system including a movable top copper atom. In order to interpret the results, a simple model consisting of two coupled harmonic oscillators is introduced. From these calculations, the vibrational levels of the CO/Cu(100) system as function of the frequency of the top copper atom are discussed.

  16. Formation of a deposit on workpiece surface in polishing nonmetallic materials

    Science.gov (United States)

    Filatov, Yu. D.; Monteil, G.; Sidorko, V. I.; Filatov, O. Y.

    2013-05-01

    During the last decades in the theory of machining nonmetallic materials some serious advances have been achieved in the field of applying fundamental scientific approaches to the grinding and polishing technologies for high-quality precision surfaces of electronic components, optical systems, and decorative articles made of natural and synthetic stone [1-9]. These achievements include a cluster model of material removal in polishing dielectric workpieces [1-3, 6-7] and a physical-statistical model of formation of debris (wear) particles and removal thereof from a workpiece surface [8-10]. The aforesaid models made it possible to calculate, without recourse to Preston's linear law, the removal rate in polishing nonmetallic materials and the wear intensity for bound-abrasive tools. Equally important for the investigation of the workpiece surface generation mechanism and formation of debris particles are the kinetic functions of surface roughness and reflectance of glass and quartz workpiece surfaces, which have been established directly in the course of polishing. During the in situ inspection of a workpiece surface by laser ellipsometry [11] and reflectometry [12] it was found out that the periodic change of the light reflection coefficient of a workpiece surface being polished is attributed to the formation of fragments of a deposit consisting of work material particles (debris particles) and tool wear particles [13, 14]. The subsequent studies of the mechanism of interaction between the debris particles and wear particles in the tool-workpiece contact zone, which were carried out based on classical concepts [15, 16], yielded some unexpected results. It was demonstrated that electrically charged debris and wear particles, which are located in the coolant-filled gap between a tool and a workpiece, move by closed circular trajectories enclosed in spheres measuring less than one fifth of the gap thickness. This implies that the probability of the debris and wear

  17. Biofilm formation and Candida albicans morphology on the surface of denture base materials.

    Science.gov (United States)

    Susewind, Sabine; Lang, Reinhold; Hahnel, Sebastian

    2015-12-01

    Fungal biofilms may contribute to the occurrence of denture stomatitis. The objective of the study was to investigate the biofilm formation and morphology of Candida albicans in biofilms on the surface of denture base materials. Specimens were prepared from different denture base materials. After determination of surface properties and salivary pellicle formation, mono- and multispecies biofilm formation including Candida albicans ATCC 10231 was initiated. Relative amounts of adherent cells were determined after 20, 44, 68 and 188 h; C. albicans morphology was analysed employing selective fluorescence microscopic analysis. Significant differences were identified in the relative amount of cells adherent to the denture base materials. Highest blastospore/hyphae index suggesting an increased percentage of hyphae was observed in mono- and multispecies biofilms on the soft denture liner, which did not necessarily respond to the highest relative amount of adherent cells. For both biofilm models, lowest relative amount of adherent cells was identified on the methacrylate-based denture base material, which did not necessarily relate to a significantly lower blastospore/hyphae index. The results indicate that there are significant differences in both biofilm formation as well as the morphology of C. albicans cells in biofilms on the surface of different denture base materials. © 2015 Blackwell Verlag GmbH.

  18. Materials SIG quantification and characterization of surface contaminants

    Science.gov (United States)

    Crutcher, E. Russ

    1992-01-01

    When LDEF entered orbit its cleanliness was approximately a MIL-STD-1246B Level 2000C. Its burden of contaminants included particles from every part of its history including a relatively small contribution from the shuttle bay itself. Although this satellite was far from what is normally considered clean in the aerospace industry, contaminating events in orbit and from processing after recovery were easily detected. The molecular contaminants carried into orbit were dwarfed by the heavy deposition of UV polymerized films from outgassing urethane paints and silicone based materials. Impacts by relatively small objects in orbit could create particulate contaminants that easily dominated the particle counts within a centimeter of the impact site. During the recovery activities LDEF was 'sprayed' with a liquid high in organics and water soluble salts. With reentry turbulence, vibration, and gravitational loading particulate contaminants were redistributed about LDEF and the shuttle bay.

  19. Geochemical and mineralogical interpretation of the Viking inorganic chemical results. [for Martian surface materials

    Science.gov (United States)

    Toulmin, P., III; Rose, H. J., Jr.; Christian, R. P.; Baird, A. K.; Evans, P. H.; Clark, B. C.; Keil, K.; Kelliher, W. C.

    1977-01-01

    The current status of geochemical, mineralogical, petrological interpretation of refined Viking Lander data is reviewed, and inferences that can be drawn from data on the composition of Martian surface materials are presented. The materials are dominantly fine silicate particles admixed with, or including, iron oxide particles. Both major element and trace element abundances in all samples are indicative of mafic source rocks (rather than more highly differentiated salic materials). The surface fines are nearly identical in composition at the two widely separated Lander sites, except for some lithologic diversity at the 100-m scale. This implies that some agency (presumably aeolian processes) has thoroughly homogenized them on a planetary scale. The most plausible model for the mineralogical constitution of the fine-grained surface materials at the two Lander sites is a fine-grained mixture dominated by iron-rich smectites, or their degradation products, with ferric oxides, probably including maghemite and carbonates (such as calcite), but not such less stable phases as magnesite or siderite.

  20. CORROSION AND SURFACE PROTECTION IN MACHINE MATERIALS FRICTION HAVE DIFFERENT SURFACE PAIRS EXPERIMENTAL INVESTIGATION OF FACTORS

    Directory of Open Access Journals (Sweden)

    Senai YALCINKAYA

    2017-05-01

    Full Text Available Friction force, normal force, linear change. The normal force varies with the loads on the friction object. In order to determine the friction force and the friction coefficient, the friction object and the friction speed are used. The experimental work was carried out in three stages. In the first stage, the effect of normal force on the friction force was studied. In the second step, the friction force of the friction surface area is influenced. The effect of the change of the shear rate in step 3 on the friction force was investigated. At the last stage, the experimental study of the effect of the material selection on the friction force was made and it was seen that the aluminum / brass surface pair had the smallest friction coefficient as a result of the opening. The greatest coefficient of friction is found in the pair of glass / felt objects.

  1. Neutrality Versus Materiality: A Thermodynamic Theory of Neutral Surfaces

    Directory of Open Access Journals (Sweden)

    Rémi Tailleux

    2016-09-01

    Full Text Available In this paper, a theory for constructing quasi-neutral density variables γ directly in thermodynamic space is formulated, which is based on minimising the absolute value of a purely thermodynamic quantity J n . Physically, J n has a dual dynamic/thermodynamic interpretation as the quantity controlling the energy cost of adiabatic and isohaline parcel exchanges on material surfaces, as well as the dependence of in-situ density on spiciness, in a description of water masses based on γ, spiciness and pressure. Mathematically, minimising | J n | in thermodynamic space is showed to be equivalent to maximising neutrality in physical space. The physics of epineutral dispersion is also reviewed and discussed. It is argued, in particular, that epineutral dispersion is best understood as the aggregate effect of many individual non-neutral stirring events (being understood here as adiabatic and isohaline events with non-zero buoyancy, so that it is only the net displacement aggregated over many events that is approximately neutral. This new view resolves an apparent paradox between the focus in neutral density theory on zero-buoyancy motions and the overwhelming evidence that lateral dispersion in the ocean is primarily caused by non-zero buoyancy processes such as tides, residual currents and sheared internal waves. The efficiency by which a physical process contributes to lateral dispersion can be characterised by its energy signature, with those processes releasing available potential energy (negative energy cost being more efficient than purely neutral processes with zero energy cost. The latter mechanism occurs in the wedge of instability, and its source of energy is the coupling between baroclinicity, thermobaricity, and density compensated temperature/salinity anomalies. Such a mechanism, which can only exist in a salty ocean, is speculated to be important for dissipating spiciness anomalies and neutral helicity. The paper also discusses potential

  2. Guide for Operational Configuration Management Program including the adjunct programs of design reconstitution and material condition and aging management

    International Nuclear Information System (INIS)

    1993-11-01

    This standard presents program criteria and implementation guidance for an operational configuration management program for DOE nuclear and non-nuclear facilities in the operational phase. Portions of this standard are also useful for other DOE processes, activities, and programs. This Part 1 contains foreword, glossary, acronyms, bibliography, and Chapter 1 on operational configuration management program principles. Appendices are included on configuration management program interfaces, and background material and concepts for operational configuration management

  3. Characterization of lunar surface materials for use in construction

    Science.gov (United States)

    Johnson, Stewart W.; Burns, Jack O.

    1992-01-01

    The Workshop on the Concept of a Common Lunar Lander, which was held at the NASA Johnson Space Center on July 1 and 2, 1991, discussed potential payloads to be placed on the Moon by a common, generic, unmanned, vehicle beginning late in this decade. At this workshop, a variety of payloads were identified including a class of one-meter (and larger) optical telescopes to operate on the lunar surface. These telescopes for lunar-based astronomy are presented in an earlier section of this report. The purpose of this section is to suggest that these and other payloads for the Common Lunar Lander be used to facilitate technology development for the proposed 16-meter Aperture UV/Visible/IR Large Lunar Telescope (LLT) and a large optical aperture-synthesis instrument analogous to the Very Large Array of the National Radio Astronomy Observatory.

  4. Novel surface coating materials for endodontic dental implant

    International Nuclear Information System (INIS)

    Fathi, M.H.; Mortazavi, V.; Moosavi, S.B.

    2003-01-01

    The aim of this study was to design and produce novel coating materials in order to obtain two goals including; improvement of the corrosion behavior of metallic dental endodontic implant and the bone osteointegration simultaneously. Stainless steel 316L (SS) was used as a metallic substrate and a novel Hydroxyapatite/Titanium (HA/Ti) composite coating was prepared on it. Structural characterization techniques including XRD, SEM and EDX were utilized to investigate the microstructure and morphology of the coating. Electrochemical tests were performed in physiological solutions in order to determine and compare the corrosion behavior of the coated and uncoated specimens as an indication of biocompatibility. Two types of endodontic implants including; SS with and without (HA/Ti) composite coating were prepared and subsequently implanted in the mandibular canine of 20 cats after completion of root canal treatment and osseous preparation. After a healing period of 4 months, osteointegration evaluation and histopathological interpretation was carried out using SEM and optical microscopy. Results indicate that the novel HA/Ti composite coating improves the corrosion behavior and biocompatibility of SS endodontic dental implant. The clinical evaluation (in vivo test) results showed that there was significant difference in osteointegration between coated and uncoated endodontic dental implants and average bone osteointegration of coated implants were more than uncoated implants. The histopathological results and bone tissue response to the coated implants was acceptable and it was concluded that HA/Ti composite coated SS could be used as well as an endodontic dental implant. (author)

  5. Novel surface coating materials for endodontic dental implant

    Energy Technology Data Exchange (ETDEWEB)

    Fathi, M.H. [Isfahan Univ. of Technology, Materials Engineering Dept., Isfahan (Iran, Islamic Republic of); Mortazavi, V.; Moosavi, S.B. [Isfahan Univ. of Medical Sciences, Faculty of Dentistry, Isfahan (Iran, Islamic Republic of)

    2003-07-01

    The aim of this study was to design and produce novel coating materials in order to obtain two goals including; improvement of the corrosion behavior of metallic dental endodontic implant and the bone osteointegration simultaneously. Stainless steel 316L (SS) was used as a metallic substrate and a novel Hydroxyapatite/Titanium (HA/Ti) composite coating was prepared on it. Structural characterization techniques including XRD, SEM and EDX were utilized to investigate the microstructure and morphology of the coating. Electrochemical tests were performed in physiological solutions in order to determine and compare the corrosion behavior of the coated and uncoated specimens as an indication of biocompatibility. Two types of endodontic implants including; SS with and without (HA/Ti) composite coating were prepared and subsequently implanted in the mandibular canine of 20 cats after completion of root canal treatment and osseous preparation. After a healing period of 4 months, osteointegration evaluation and histopathological interpretation was carried out using SEM and optical microscopy. Results indicate that the novel HA/Ti composite coating improves the corrosion behavior and biocompatibility of SS endodontic dental implant. The clinical evaluation (in vivo test) results showed that there was significant difference in osteointegration between coated and uncoated endodontic dental implants and average bone osteointegration of coated implants were more than uncoated implants. The histopathological results and bone tissue response to the coated implants was acceptable and it was concluded that HA/Ti composite coated SS could be used as well as an endodontic dental implant. (author)

  6. Plasma-Assisted Synthesis and Surface Modification of Electrode Materials for Renewable Energy.

    Science.gov (United States)

    Dou, Shuo; Tao, Li; Wang, Ruilun; El Hankari, Samir; Chen, Ru; Wang, Shuangyin

    2018-02-14

    Renewable energy technology has been considered as a "MUST" option to lower the use of fossil fuels for industry and daily life. Designing critical and sophisticated materials is of great importance in order to realize high-performance energy technology. Typically, efficient synthesis and soft surface modification of nanomaterials are important for energy technology. Therefore, there are increasing demands on the rational design of efficient electrocatalysts or electrode materials, which are the key for scalable and practical electrochemical energy devices. Nevertheless, the development of versatile and cheap strategies is one of the main challenges to achieve the aforementioned goals. Accordingly, plasma technology has recently appeared as an extremely promising alternative for the synthesis and surface modification of nanomaterials for electrochemical devices. Here, the recent progress on the development of nonthermal plasma technology is highlighted for the synthesis and surface modification of advanced electrode materials for renewable energy technology including electrocatalysts for fuel cells, water splitting, metal-air batteries, and electrode materials for batteries and supercapacitors, etc. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Modification of Semiconductor Surfaces through Si-N Linkages by Wet-Chemistry Approaches and Modular Functionalization of Zinc Oxide Surfaces for Chemical Protection of Material Morphology

    Science.gov (United States)

    Gao, Fei

    Semiconductor substrates are widely used in many applications. Multiple practical uses involving these materials require the ability to tune their physical and chemical properties to adjust those to a specific application. In recent years, surface and interface reactions have affected dramatically device fabrication and material design. Novel surface functionalization techniques with diverse chemical approaches make the desired physical, thermal, electrical, and mechanical properties attainable. Meanwhile, the modified surface can serve as one of the most important key steps for further assembly process in order to make novel devices and materials. In the following chapters, novel chemical approaches to the functionalization of silicon and zinc oxide substrates will be reviewed and discussed. The specific functionalities including amines, azides, and alkynes on surfaces of different materials will be applied to address subsequent attachment of large molecules and assembly processes. This research is aimed to develop new strategies for manipulating the surface properties of semiconductor materials in a controlled way. The findings of these investigations will be relevant for future applications in molecular and nanoelectronics, sensing, and solar energy conversion. The ultimate goals of the projects are: 1) Preparation of an oxygen-and carbon-free silicon surface based exclusively on Si-N linkages for further modification protocols.. This project involves designing the surface reaction of hydrazine on chlorine-terminated silicon surface, introduction of additional functional group through dehydrohalogenation condensation reaction and direct covalent attachment of C60. 2) Demonstrating alternative method to anchor carbon nanotubes to solid substrates directly through the carbon cage.. This project targets surface modification of silicon and gold substrates with amine-terminated organic monolayers and the covalent attachment of nonfunctionalized and carboxylic acid

  8. Auto-recognition of surfaces and auto-generation of material removal volume for finishing process

    Science.gov (United States)

    Kataraki, Pramod S.; Salman Abu Mansor, Mohd

    2018-03-01

    Auto-recognition of a surface and auto-generation of material removal volumes for the so recognised surfaces has become a need to achieve successful downstream manufacturing activities like automated process planning and scheduling. Few researchers have contributed to generation of material removal volume for a product but resulted in material removal volume discontinuity between two adjacent material removal volumes generated from two adjacent faces that form convex geometry. The need for limitation free material removal volume generation was attempted and an algorithm that automatically recognises computer aided design (CAD) model’s surface and also auto-generate material removal volume for finishing process of the recognised surfaces was developed. The surfaces of CAD model are successfully recognised by the developed algorithm and required material removal volume is obtained. The material removal volume discontinuity limitation that occurred in fewer studies is eliminated.

  9. Use of Intense Ion Beams for Surface Modification and Creation of New Materials

    CERN Document Server

    Renk, T; Prasad, S V; Provencio, P P; Thompson, M

    2002-01-01

    We have conducted surface treatment and alloying experiments with Al, Fe, and Ti-based metals on the RHEPP-1 accelerator (0.8 MV, 20 W, 80 ns FHWM, up to 1 Hz repetition rate) at Sandia National Laboratories. Ions are generated by the MAP gas-breakdown active anode, which can yield a number of different beam species including H, N, and C, depending upon the injected gas. Beams of intense pulsed high-power ion beams have been used to produce surface modification by changes in microstructure caused by rapid heating and cooling of the surface. Increase of beam power leads to ablation of a target surface, and redeposition of ablated material onto a separate substrate. Experiments are described in which ion beams are used in an attempt to increase high-voltage breakdown of a treated surface. Surface alloying of coated Pt and Hf layers is also described. This mixing of a previously deposited thin-film layer into a Ti-alloy substrate leads to significantly enhanced surface wear durability, compared to either untreat...

  10. 'Bootstrap' charging of surfaces composed of multiple materials

    Science.gov (United States)

    Stannard, P. R.; Katz, I.; Parks, D. E.

    1981-01-01

    The paper examines the charging of a checkerboard array of two materials, only one of which tends to acquire a negative potential alone, using the NASA Charging Analyzer Program (NASCAP). The influence of the charging material's field causes the otherwise 'non-charging' material to acquire a negative potential due to the suppression of its secondary emission ('bootstrap' charging). The NASCAP predictions for the equilibrium potential difference between the two materials are compared to results based on an analytical model.

  11. Development of Advanced Wear and Corrosion Resistant Systems Through Laser Surface Alloying and Materials Simulations

    Energy Technology Data Exchange (ETDEWEB)

    R. P. Martukanitz and S. Babu

    2007-05-03

    precipitation of titanium carbonitrides during laser surface alloying provided there was sufficient amount of dissolved titanium, carbon, and nitrogen in the liquid steel. This was confirmed experimentally by using a powder mixture of 431-martensitic steel, titanium carbide powder, and nitrogen shielding, during laser deposition to produce deposits exhibiting relatively high hardness (average surface hardness of 724 HV). The same approach was extended to direct diode laser processing and similar microstructures were attained. The above analysis was extended to develop an in-situ precipitation of Ti(CN) during laser deposition. The Ti addition was achieving by mixing the 431 martensitic steel powders with ferro-titanium. The dissolution of nitrogen was achieved by using 100% nitrogen shielding gas, which was indicated by thermodynamic analysis. Demonstrations were also conducted utilizing the tools developed during the program and resulted in several viable composite coating systems being identified. This included the use of TiC and ferro-titanium in martensitic-grade stainless steel matrix material with and without the use of active N2 shielding gas, WC hard particles in a martensitic-grade stainless steel matrix material, WC and BN in a nickel-based matrix material, and WC in highly alloyed iron-based matrix. Although these demonstrations indicated the potential of forming composite coatings, in certain instances, the intended industrial applications involved unique requirements, such as coating of internal surfaces, which hindered the full development of the improved coating technology. However, it is believed that the addition of common hard particles, such as WC or TiC, to matrix material representing martensitic grades of stainless steel offer opportunities for improved performance at relatively low material cost.

  12. Evaluation of materials and surface treatments for the DWPF melter pour spout bellows protective liner

    Energy Technology Data Exchange (ETDEWEB)

    Imrich, K.J.; Bickford, D.F.; Wicks, G.G.

    1997-06-27

    A study was undertaken to evaluate a variety of materials and coatings for the DWPF pour spout bellows liner. The intent was to identify materials that would minimize or eliminate adherence of glass on the bellows liner wall and help minimize possible pluggage during glass pouring operations in DWPF. Glass has been observed adhering to the current bellow`s liner, which is made of 304L stainless steel. Materials were identified which successfully allowed molten glass to hit these surfaces and not adhere. Results of this study suggest that if these materials are used in the pouring system glass could still fall into the canister without appreciable plugging, even if an unstable glass stream is produced. The materials should next be evaluated under the most realistic DWPF conditions possible. Other findings of this study include the following: (1) increasing coupon thickness produced a favorable increase in the glass sticking temperature; (2) highly polished surfaces, with the exception of the oxygen-free copper coupon coated with Armoloy dense chromium, did not produce a significant improvement in the glass sticking temperature, increasing angle of contact of the coupon to the falling glass did not yield a significant performance improvement; (3) electroplating with gold and silver and various diffusion coatings did not produce a significant increase in the glass sticking temperature. However, they may provide added oxidation and corrosion resistance for copper and bronze liners. Boron nitride coatings delaminated immediately after contact with the molten glass.

  13. Evaluation of materials and surface treatments for the DWPF melter pour spout bellows protective liner

    International Nuclear Information System (INIS)

    Imrich, K.J.; Bickford, D.F.; Wicks, G.G.

    1997-01-01

    A study was undertaken to evaluate a variety of materials and coatings for the DWPF pour spout bellows liner. The intent was to identify materials that would minimize or eliminate adherence of glass on the bellows liner wall and help minimize possible pluggage during glass pouring operations in DWPF. Glass has been observed adhering to the current bellow's liner, which is made of 304L stainless steel. Materials were identified which successfully allowed molten glass to hit these surfaces and not adhere. Results of this study suggest that if these materials are used in the pouring system glass could still fall into the canister without appreciable plugging, even if an unstable glass stream is produced. The materials should next be evaluated under the most realistic DWPF conditions possible. Other findings of this study include the following: (1) increasing coupon thickness produced a favorable increase in the glass sticking temperature; (2) highly polished surfaces, with the exception of the oxygen-free copper coupon coated with Armoloy dense chromium, did not produce a significant improvement in the glass sticking temperature, increasing angle of contact of the coupon to the falling glass did not yield a significant performance improvement; (3) electroplating with gold and silver and various diffusion coatings did not produce a significant increase in the glass sticking temperature. However, they may provide added oxidation and corrosion resistance for copper and bronze liners. Boron nitride coatings delaminated immediately after contact with the molten glass

  14. Characterization of dissolved organic materials in surface waters within the blast zone of Mount St Helens, Washington

    Science.gov (United States)

    McKnight, Diane M.; Pereira, W.E.; Ceazan, M.L.; Wissmar, Robert C.

    1982-01-01

    After the May 18, 1980, eruption of Mount St Helens, the concentration of dissolved organic material in surface waters near the volcano increased significantly as a result of the destruction of the surrounding conifer forest. Low molecular weight organic compounds identified in the blast zone surface waters were derived from pyrolysis of plant and soil organic materials incorporated into pyroclastic flow, mud flow and debris avalanche deposits. A major fraction of the dissolved organic material consisted of high molecular weight, colored, organic acids that are similar in their general properties to aquatic fulvic acids found in more typical surface waters except for greater sulfur contents. The other major fraction of the dissolved organic material consisted of hydrophilic acids, which may include compounds capable of supporting heterotrophic microorganisms, and precursors in the formation of aquatic fulvic acids. The organic chemistry of blast zone surface waters will probably be greatly influenced by the May 18, 1980, eruption for many years. ?? 1982.

  15. Surface Treatment of Polymeric Materials Controlling the Adhesion of Biomolecules

    Directory of Open Access Journals (Sweden)

    Willy Zorzi

    2012-08-01

    Full Text Available This review describes different strategies of surface elaboration for a better control of biomolecule adsorption. After a brief description of the fundamental interactions between surfaces and biomolecules, various routes of surface elaboration are presented dealing with the attachment of functional groups mostly thanks to plasma techniques, with the grafting to and from methods, and with the adsorption of surfactants. The grafting of stimuli-responsive polymers is also pointed out. Then, the discussion is focused on the protein adsorption phenomena showing how their interactions with solid surfaces are complex. The adsorption mechanism is proved to be dependent on the solid surface physicochemical properties as well as on the surface and conformation properties of the proteins. Different behaviors are also reported for complex multiple protein solutions.

  16. Surface Treatment of Polymeric Materials Controlling the Adhesion of Biomolecules

    Science.gov (United States)

    Poncin-Epaillard, Fabienne; Vrlinic, Tjasa; Debarnot, Dominique; Mozetic, Miran; Coudreuse, Arnaud; Legeay, Gilbert; El Moualij, Benaïssa; Zorzi, Willy

    2012-01-01

    This review describes different strategies of surface elaboration for a better control of biomolecule adsorption. After a brief description of the fundamental interactions between surfaces and biomolecules, various routes of surface elaboration are presented dealing with the attachment of functional groups mostly thanks to plasma techniques, with the grafting to and from methods, and with the adsorption of surfactants. The grafting of stimuli-responsive polymers is also pointed out. Then, the discussion is focused on the protein adsorption phenomena showing how their interactions with solid surfaces are complex. The adsorption mechanism is proved to be dependent on the solid surface physicochemical properties as well as on the surface and conformation properties of the proteins. Different behaviors are also reported for complex multiple protein solutions. PMID:24955631

  17. Detection of defects and evaluation of material deterioration using surface wave technique

    International Nuclear Information System (INIS)

    Yokono, Yoshikazu; Yoshiara, Toshikatsu; Suetsugu, Jun; Imanaka, Takuichi

    1996-01-01

    It is very important to detect surface damage and evaluate deterioration of material surface because of their influences on mechanical properties of materials. In general, magnetic particle testing, liquid penetrant testing and eddy current testing are commonly used for detecting surface flaws. These methods, however, are neither effective for estimating flaw height nor for evaluating material deterioration. In this paper the authors apply surface wave propagating along the test surface for these purposes. The surface wave (Rayleigh wave) propagates only near the surface layer in the order of one wave length. In other words, the lower the frequency, the deeper the penetration depth of the surface wave. Accordingly, they can select the frequency considering the inspection purpose. On the other hand, when surface wave having broad-band frequency propagates along the surface of a specimen, higher frequency ultrasound propagates very close to the surface and lower frequency ultrasound propagates deeper in the specimen. Hence, frequency analysis is expected to be effective for estimating upper edge of flaw. Surface wave is also very sensitive to material surface properties such as existence of voids or micro cracks. Acoustic characteristics such as sound velocity, attenuation and other feature parameters are influenced by the variation of the material properties. Hence, material deterioration can be evaluated by the acoustic features

  18. FORMALDEHYDE GAS INACTIVATION OF BACILLUS ANTHRACIS, BACILLUS SUBTILIS AND GEOBACILLUS STEAROTHERMOPHILUS SPORES ON INDOOR SURFACE MATERIALS.

    Science.gov (United States)

    Research evaluated the decontamination of Bacillus anthracis, Bacillus subtilis, and Geobacillus stearothermophilus spores on indoor surface material using formaldehyde gas. Spores were dried on seven types of indoor surfaces and exposed to 1100 ppm formaldehyde gas for 10 hr. Fo...

  19. Comparison of the surface roughness of gypsum models constructed using various impression materials and gypsum products

    Directory of Open Access Journals (Sweden)

    Yi-Chih Chang

    2016-03-01

    Conclusion: The surface roughness of stone models was mainly determined by the type of alginate impression material, and was less affected by the type of silicone rubber impression material or gypsum product, or the storage time before repouring.

  20. Electrical characterization of the near-surface region of semiconductor materials by photoconductive decay

    Science.gov (United States)

    Drummond, Patrick J.

    As the trend in mainstream IC manufacturing continues to move towards using very thin layers of silicon and very shallow junctions, the near-surface electrical properties become more important. Likewise, in the photovoltaic industry, thin layers of amorphous silicon and shallow junction solar cells using single crystal and multi-crystalline silicon are of significant interest. For all of these applications, an effective method of in-line monitoring of near-surface electrical properties is essential. The near-surface properties of solar cell materials are of particular interest, where there is a delicate balance between having the surface textured sufficiently to minimize reflectivity, but not too excessively as to dramatically reduce carrier lifetime. As solar cell wafers are becoming thinner and bulk recombination lifetimes improve, carrier diffusion lengths will begin to exceed the thickness of the wafer. Hence, the back surface recombination velocity, which directly affects cell efficiency, becomes a critical factor. Difficulties in determining the impact of near-surface effects on carrier transport properties of thin layer semiconductors have been encountered with traditional methods of electrical characterization. The goal of this research was to investigate the near-surface electrical properties of semiconductor materials, including multi-crystalline silicon used in the photovoltaic industry, by a modified method of electrical characterization based on the photoconductive decay (PCD) effect. The project was completed in two phases. The first phase involved verification of a photoconductive decay method with a newly developed tool, in both a non-contact version and a physical contact version, with respect to capability for characterizing a shallow subsurface region of selected semiconductor materials. To evaluate the capability of the tool, the longer recombination lifetimes of single crystal wafers of indirect bandgap semiconductors Si and Ge (10--100 micros

  1. Radiation-curing of acrylate composites including carbon fibres: A customized surface modification for improving mechanical performances

    International Nuclear Information System (INIS)

    Martin, Arnaud; Pietras-Ozga, Dorota; Ponsaud, Philippe; Kowandy, Christelle; Barczak, Mariusz; Defoort, Brigitte; Coqueret, Xavier

    2014-01-01

    The lower transverse mechanical properties of radiation-cured acrylate-based composites reinforced with carbon-fibre with respect to the thermosettable analogues was investigated from the viewpoint of chemical interactions at the interface between the matrix and the carbon material. XPS analysis of representative commercial carbon fibres revealed the presence of a significant amount of chemical functions potentially exerting an adverse effect on the initiation and propagation of the free radical polymerization initiated under high energy radiation. The EB-induced polymerization of n-butyl acrylate as a simple model monomer was conducted in the presence of various aromatic additives exhibiting a strong inhibiting effect, whereas thiols efficiently sensitize the initiation mechanism and undergo transfer reactions. A method based on the surface modification of sized fibres by thiomalic acid is proposed for overcoming the localized inhibition phenomenon and for improving the mechanical properties of the resulting acrylate-based composites. - Highlights: • Surface functions of C-fibres are analyzed for their effect on radical reaction. • Irradiation of nBu-acrylate in presence of aromatic additives reveals inhibition. • Thiol groups sensitize the radiation-initiated polymerization of nBu-acrylate. • Modification of C-fibres with thiomalic acid enhances composite properties

  2. Surface scattering efficiency of some common materials for shielding pulsed neutron scattering instruments

    International Nuclear Information System (INIS)

    Bartoli, L.; Becherini, F.; Grazzi, F.; Zoppi, M.

    2009-01-01

    We have measured the surface scattering efficiency of a new ceramic composite, based on boron carbide, that was recently proposed for use as a shielding material for pulsed neutron scattering instrumentation. The results show that, due to a relevant presence of clay material in the composite, the surface scattering efficiency is higher than other common shielding materials, which are used on pulsed neutron scattering instrumentation, and suggest revising the material composition.

  3. Thin film materials: stress, defect formation, and surface evolution

    National Research Council Canada - National Science Library

    Freund, L. B; Suresh, S

    2003-01-01

    ... scientific basis with which stress, deformation and failure in thin film materials can be characterized, an attempt is also made to link the scientific concepts to a broad range of practical applications through example problems, historical notes, case studies and exercises. Of particular interest to engineers, materials scientists and physicist...

  4. Development of material measures for performance verifying surface topography measuring instruments

    International Nuclear Information System (INIS)

    Leach, Richard; Giusca, Claudiu; Rickens, Kai; Riemer, Oltmann; Rubert, Paul

    2014-01-01

    The development of two irregular-geometry material measures for performance verifying surface topography measuring instruments is described. The material measures are designed to be used to performance verify tactile and optical areal surface topography measuring instruments. The manufacture of the material measures using diamond turning followed by nickel electroforming is described in detail. Measurement results are then obtained using a traceable stylus instrument and a commercial coherence scanning interferometer, and the results are shown to agree to within the measurement uncertainties. The material measures are now commercially available as part of a suite of material measures aimed at the calibration and performance verification of areal surface topography measuring instruments

  5. Improving the antimicrobial properties of titanium condenser material by surface modification using nanotechnology

    International Nuclear Information System (INIS)

    George, Rani P.; Dash, S.; Krishnan, R.; Kamruddin, M.; Kalavathi, S.; Tyagi, A.K.; Manoharan, N.; Dayal, R.K.; Vishwakarma, Vinita; Theresa, Josephine

    2008-01-01

    Biofouling is one of the major problems faced by condenser materials of power plants using seawater for cooling. Fouling control strategies in condensers include a combination of mechanical and chemical treatments like sponge ball cleaning, back washing and chlorination. In general, numerous studies have shown that no routine treatment regime can successfully keep the condenser tube clean over a period extending to years. Surface properties of the substratum influence initial adhesion and growth of bacterial cells on materials, modification of the surface for mitigating microbial attachment is the need of the hour. Metal nanoparticles are known to exhibit enhanced physical and chemical properties when compared to their bulk counter parts because of their high surface to volume ratios. Metals like copper are very toxic to microorganisms and effectively kill most of the microbes by blocking the respiratory enzyme. Copper alloys with their excellent resistance to biofouling are used extensively for marine applications. However, they are prone to localized corrosion initiation and consequently are getting replaced by extremely corrosion resistant titanium. Still, the inertness and biocompatibility of titanium makes it very susceptible to biofouling. Hence, this study attempts to use nano technology methods of surface modification of titanium using thin film of copper and also multilayers and bilayers of copper and nickel. This is aimed at improving the antimicrobial properties of this condenser pipe material. These nano structured thin films have been grown on titanium substrate using pulsed DC magnetron-sputtering and pulsed laser deposition. The thin films were characterized using Atomic Force Microscopy (AFM), Glancing Incidence X-ray Diffraction (GIXRD) and scanning electron microscopy (SEM with EDAX analysis). Antimicrobial properties were evaluated by exposure studies in seawater and bacterial cultures and by post exposure analysis using culture and

  6. Surface Antibacterial Properties of Four Tooth-Colored Restorative Materials

    Directory of Open Access Journals (Sweden)

    F. Shirani

    2008-03-01

    Full Text Available Objective: This study investigated the antibacterial properties of an ion-releasing resin composite (Degufill, a hybrid resin composite (InTen-S, a compomer (Compoglass F and a resin-modified glass ionomer (Vitremer against streptococcus mutans.Materials and Methods: The bacteria were derived from the dental plaque and cultured on blood agar plates. Eppendorf tubes were filled by unset restorative materials. A narrow conical cavity was created in the center of each material, prior to curing and the bacterial suspension was placed into each cavity. Each tube was incubated for the selected time pe-riods of 8, 24, 48 hours and 5 days and the procedure was repeated five times. After the incubation period, the suspensions were removed and the number of viable bacteria was evaluated. The data were analyzed using two-way ANOVA, one-way ANOVA and Tukey HSD tests.Results: After the incubation periods of 8, 24 and 48 hours, all restorative materials ex-cept InTen-S showed significant growth inhibition when compared to the control group. There was a significant difference in the number of bacterial colonies in different incuba-tion periods. The interaction between the materials and time intervals was also significant (P<0.05.Conclusion: The method used in this study was almost successful in ranking restorative dental materials according to their antibacterial effects. InTen-S showed no inhibitory ef-fect on bacterial growth, while other materials, especially Vitremer, showed considerable antibacterial effects.

  7. Raman and Surface Enhanced Raman of Biological Material

    National Research Council Canada - National Science Library

    Guicheteau, Jason A; Gonser, Kristina; Christesen, Steven Dale

    2004-01-01

    .... Vibrational spectroscopic methods such as Raman and surface enhanced Raman scattering (SERS) provide rapid detailed fingerprint information about the molecular composition of biomaterial in a non-destructive manner...

  8. Surface modification and preparation techniques for textile materials

    CSIR Research Space (South Africa)

    Jacob John, Maya

    2009-01-01

    Full Text Available as it improves various properties – such as softness, dyeability, absorbance and wettability. In this chapter, the most commonly used surface modification techniques, ranging from plasma treatment to nanocoatings, for both natural and synthetic fibres have been...

  9. Alternative aggregates and materials for high friction surface treatments.

    Science.gov (United States)

    2016-05-01

    The State of Florida has used high friction surface treatments (HFSTs) since 2006 to reduce wet weather crashes on : tight curves and intersections and to maintain bridge decks; however, the Florida Department of Transportation : (FDOT) has reported ...

  10. A quasi-static algorithm that includes effects of characteristic time scales for simulating failures in brittle materials

    KAUST Repository

    Liu, Jinxing

    2013-04-24

    When the brittle heterogeneous material is simulated via lattice models, the quasi-static failure depends on the relative magnitudes of Telem, the characteristic releasing time of the internal forces of the broken elements and Tlattice, the characteristic relaxation time of the lattice, both of which are infinitesimal compared with Tload, the characteristic loading period. The load-unload (L-U) method is used for one extreme, Telem << Tlattice, whereas the force-release (F-R) method is used for the other, Telem T lattice. For cases between the above two extremes, we develop a new algorithm by combining the L-U and the F-R trial displacement fields to construct the new trial field. As a result, our algorithm includes both L-U and F-R failure characteristics, which allows us to observe the influence of the ratio of Telem to Tlattice by adjusting their contributions in the trial displacement field. Therefore, the material dependence of the snap-back instabilities is implemented by introducing one snap-back parameter γ. Although in principle catastrophic failures can hardly be predicted accurately without knowing all microstructural information, effects of γ can be captured by numerical simulations conducted on samples with exactly the same microstructure but different γs. Such a same-specimen-based study shows how the lattice behaves along with the changing ratio of the L-U and F-R components. © 2013 The Author(s).

  11. Review of the IAEA nuclear fuel cycle and material section activities connected with nuclear fuel including WWER fuel

    International Nuclear Information System (INIS)

    Sokolov, F.

    2001-01-01

    Program activities on Nuclear Fuel Cycle and Materials cover the areas of: 1) raw materials (B.1.01); 2) fuel performance and technology (B.1.02); 3) pent fuel (B.1.03); 4) fuel cycle issues and information system (B.1.04); 5) support to technical cooperation activities (B.1.05). The IAEA activities in fuel performance and technology in 2001 include organization of the fuel experts meetings and completion of the Co-ordinate Research Projects (CRP). The special attention is given to the advanced post-irradiation examination techniques for water reactor fuel and fuel behavior under transients and LOCA conditions. An international research program on modeling of activity transfer in primary circuit of NPP is finalized in 2001. A new CRP on fuel modeling at extended burnup (FUMEX II) has planed to be carried out during the period 2002-2006. In the area of spent fuel management the implementation of burnup credit (BUC) in spent fuel management systems has motivated to be used in criticality safety applications, based on economic consideration. An overview of spent fuel storage policy accounting new fuel features as higher enrichment and final burnup, usage of MOX fuel and prolongation of the term of spent fuel storage is also given

  12. The influence of Fe doping on the surface topography of GaN epitaxial material

    International Nuclear Information System (INIS)

    Cui Lei; Yin Haibo; Jiang Lijuan; Wang Quan; Feng Chun; Xiao Hongling; Wang Cuimei; Wang Xiaoliang; Gong Jiamin; Zhang Bo; Li Baiquan; Wang Zhanguo

    2015-01-01

    Fe doping is an effective method to obtain high resistivity GaN epitaxial material. But in some cases, Fe doping could result in serious deterioration of the GaN material surface topography, which will affect the electrical properties of two dimensional electron gas (2DEG) in HEMT device. In this paper, the influence of Fe doping on the surface topography of GaN epitaxial material is studied. The results of experiments indicate that the surface topography of Fe-doped GaN epitaxial material can be effectively improved and the resistivity could be increased after increasing the growth rate of GaN materials. The GaN material with good surface topography can be manufactured when the Fe doping concentration is 9 × 10 19 cm −3 . High resistivity GaN epitaxial material which is 1 × 10 9 Ω·cm is achieved. (paper)

  13. VDI 2083-17: VOC emissions from material surfaces

    OpenAIRE

    Keller, Markus; Bürger, Frank

    2010-01-01

    In such fields as cleanroom technology, food, pharmaceutics and health care as well as in normal living and working environments, materials implemented in specific applications need to be assessed for VOC emissions and classified in order to permit direct comparisons to be made. The paper presents a standardized procedure for testing and classifying materials with uniform sample preparation and defined storage times. It describes preparation of the samples, their measurement in a VOC-free min...

  14. Surface and catalysis science in the Materials and Molecular Research Division

    International Nuclear Information System (INIS)

    1980-01-01

    Surface science studies at Lawrence Berkeley Laboratory are detailed. Subject areas include: structure of surfaces and adsorbed monolayers; reduction and oxidation of surfaces; catalytic chemistry; and structure of interfaces and thin films

  15. The use of an ion-beam source to alter the surface morphology of biological implant materials

    Science.gov (United States)

    Weigand, A. J.

    1978-01-01

    An electron-bombardment ion-thruster was used as a neutralized-ion-beam sputtering source to texture the surfaces of biological implant materials. The materials investigated included 316 stainless steel; titanium-6% aluminum, 4% vanadium; cobalt-20% chromium, 15% tungsten; cobalt-35% nickel, 20% chromium, 10% molybdenum; polytetrafluoroethylene; polyoxymethylene; silicone and polyurethane copolymer; 32%-carbon-impregnated polyolefin; segmented polyurethane; silicone rubber; and alumina. Scanning electron microscopy was used to determine surface morphology changes of all materials after ion-texturing. Electron spectroscopy for chemical analysis was used to determine the effects of ion-texturing on the surface chemical composition of some polymers. Liquid contact angle data were obtained for ion-textured and untextured polymer samples. Results of tensile and fatigue tests of ion-textured metal alloys are presented. Preliminary data of tissue response to ion-textured surfaces of some metals, polytetrafluoroethylene, alumina, and segmented polyurethane have been obtained.

  16. Database of Pb - free soldering materials, surface tension and density, experiment vs. Modeling

    Directory of Open Access Journals (Sweden)

    Z Moser

    2006-01-01

    Full Text Available Experimental studies of surface tension and density by the maximum bubble pressure method and dilatometric technique were undertaken and the accumulated data for liquid pure components, binary, ternary and multicomponent alloys were used to create the SURDAT data base for Pb-free soldering materials. The data base enabled, also to compare the experimental results with those obtained by the Butler’s model and with the existing literature data. This comparison has been extended by including the experimental data of Sn-Ag-Cu-Sb alloys.

  17. Surface treatments for material protection in nuclear power plants

    International Nuclear Information System (INIS)

    De, P.K.; Gadiyar, H.S.

    1987-01-01

    The paper highlights some of the surface treatment methods used in nuclear power plants to improve their performance. The corrosion resistance of zirconium alloys results from the formation of an adherent and protective film of ZrO 2 . Graphite coating of zircaloy-2 cladding minimizes the susceptibility to environmental induced cracking. Magnetite formation during the hot conditioning operation improves the corrosion resistance of carbon steel as well as controls the spread of radioactivity. It has been illustrated how the surface treatment is helpful for redistributing residual stress to facilitate conversion of tensile stress to compressive stress to mitigate failures due to stress corrosion and fatigue corrosion. Inhibitors and passivators can modify the surface conditions (in situ) of condenser tubes and cooling water systems. These aspects have been dealt in the text of the paper. (author). 8 refs., 3 figures

  18. Usage of analytical diagnostics when evaluating functional surface material defects

    Directory of Open Access Journals (Sweden)

    R. Frischer

    2015-10-01

    Full Text Available There are occurring defects due to defects mechanisms on parts of production devices surfaces. Outer defects pronouncement is changing throw the time with unequal speed. This variability of defect’s mechanism development cause that is impossible to evaluate technical state of the device in any moment, without the necessary underlying information. Proposed model is based on analytical diagnostics basis. Stochastic model with usage of Weibull probability distribution can assign probability of function surface defect occurrence on the operational information in any moment basis. The knowledge of defect range limiting moment, then enable when and in what range will be necessary to make renewal.

  19. Structure and stability of surface passivation layers on semiconductor materials

    Science.gov (United States)

    Kluth, George Jonathan

    The structure and stability of passivating layers on silicon surfaces have been examined on the molecular level using the methods of surface science. Hydrogen-terminated surfaces were prepared through wet chemical treatment with ammonium fluoride. The oxidation of these surfaces was studied using high resolution electron energy loss spectroscopy (HREELS), which showed that oxidation occurred through oxygen insertion in silicon backbonds, while the hydrogen termination remained intact. Oxygen was observed in both the surface layer and bulk layers, suggesting that initial oxidation was not restricted to layer-by-layer growth. Because the surface did oxidize with time, other passivating treatments, specifically self-assembled monolayers, were examined. The thermal stability of alkylsiloxane monolayers on oxidized Si(100) was studied in vacuum. Using HREELS it was found that the monolayers were stable up to 740 K. Above that temperature, they began to decompose through cleavage of C-C bonds, resulting in a reduction in chain length. The thermal stability of alkyl monolayers, which form directly on silicon without requiring an oxide layer, was also examined. These monolayers were stable to 620 K, significantly lower than the alkylsiloxane monolayers. Desorption was accompanied by the appearance of Si-H bonds, suggesting that desorption took place through a hydrogen elimination reaction. The thermal behavior of these two different monolayers highlighted the importance of bonding between the surface and the chains. The bonding of alkylsiloxane monolayers was examined in more detail by forming them on both SiOsb2 and Sisb3Nsb4. It was found that cross linking between adjacent head groups was critical to the formation of high quality monolayers. Bonding between the chains and the surface was of secondary importance, but played a key role in the initial stages of growth, when nucleation occurred. The chemical stability of alkylsiloxane monolayers on oxidized silicon was also

  20. Three-dimensional reconstruction of fracture surfaces of CFRP type composite materials

    International Nuclear Information System (INIS)

    Lobo, Raquel de Moraes

    2009-01-01

    The three-dimensional reconstruction of fracture surfaces of CFRP type composite materials is presented in this work as a possible method for the fractographic analysis of this material, whose rupture surface can present an accentuated roughness, with great variation in height. Two methods are presented for this purpose: the reconstruction for variable focus, carried through with images of optic microscopy and the reconstruction for parallax, carried through with pair of stereo images, obtained by means of scanning electronic microscopy. An evaluation is carried through for each one of the two methods, having argued its limits and the efficiency of each one of them, before the difficulties of analysis of unidirectional and multidirectional composite materials. The method of variable focus presented an excellent reconstruction result, but it has the need of a great number of images, spent time of the instrument and magnifying limit of the images as factors to be considered in the choice of better method. The tilting of the specimen, during the parallax method, discloses alterations in the histograms of the images acquired in the clockwise direction that limit the use of the method for materials with high roughness. The acquiring of images in only one direction and the construction of a region of interest, located in the center of the image are suggestions to turn the method most including. The linearity of the projections of features in the inclined image also suggests the possibility to carry through the reconstruction using, instead of only two, multiple images gotten in the counter-clockwise direction. The alterations proposals to modify the routine, are suggested so that the program can be applied in a more comprehensive form, independent of the quality of the observed fracture surface. (author)

  1. Tyre - Road Noise, Surface Characteristics and Material Properties

    NARCIS (Netherlands)

    Li, M.

    2013-01-01

    Noise levels due to road traffic have reached intolerable high levels in and around many urban areas all around the world. Because of health reasons and reasons of well- being these noise levels have to be reduced. The noise produced from the interaction between the rolling tyre and road surface is

  2. Novel surface coating strategies for better battery materials

    CSIR Research Space (South Africa)

    Wen, L

    2018-03-01

    Full Text Available concepts of ‘ultrathin conformal coating’, ‘continuous phase coating’ and ‘multifunctional coating’ are proposed and discussed, followed by the authors’ rational perspectives on the future development and potential research hot spot in the surface...

  3. Mineral Surface Reactivity in teaching of Science Materials

    Science.gov (United States)

    Del Hoyo Martínez, Carmen

    2013-04-01

    In the last fifty years, science materials issues has required the study of air pollution, water and soil to prevent and remedy the adverse effects of waste originating from anthropogenic activity and the development of new energies and new materials. The teaching of this discipline has been marked by lectures on general lines, materials, disciplines, who explained biased objects of reality, but often forgot the task of reconstruction and integration of such visions. Moving from that model, otherwise quite static, to a dynamic relational model, would in our view, a real revolution in education. This means taking a systematic approach to complex both in interpreting reality and in favor when learning. Children relationships are as important or more than single objects, and it is to discover fundamental organizational principles of phenomena we seek to interpret or in other words, find the pattern that connects. Thus, we must work on relationships and also take into account the relation between the observer and the observed. Educate about relationships means that studies should always be considered within a framework of probabilities, not absolute certainties. This model of systemic thinking, dealing with complexity, is a possibility to bring coherence to our educational work, because the complexity is not taught, complexity is live, so that complex thinking is extended (and fed) in a form educate complex. It is the task of teaching to help people move from level to level of decision reviews. This means that systems thinking should be extended in a local action, action that engages the individual and the environment. Science Materials has emerged as a discipline of free choice for pupils attending chemical engineering which has been assigned 6.0 credits. The chemical engineer's professional profile within the current framework is defined as a professional knowledge as a specialization technical / functional, working in a learning organization and the formation of

  4. Original Research. Surface Roughness Changes of Different Restoration Materials after Tooth Brushing Simulation Using Different Toothpastes

    Directory of Open Access Journals (Sweden)

    Dudás Csaba

    2017-03-01

    Full Text Available Background: The need for the whitening effects of toothpastes became primary for most users. Changes in the surface roughness of restoration materials after tooth brushing are inevitable, and the abrasion is known to increase the possibility of dental plaque accumulation. Aim of the study: To evaluate in vitro surface roughness changes of different dental restorative materials after tooth brushing simulation. Material and methods: Fifty specimens of two composite materials (Evicrol, Super-Cor, two glass ionomer materials (Glassfill, Kavitan Cem and a silicate cement (Fritex were prepared according to the manufacturer’s instructions. Each group of specimens was divided in three subgroups for tooth brushing simulation: using two different types of toothpaste and without toothpaste. Before and after 153 hours of tooth brushing simulation with a custom-made device, the surface roughness was measured with a surface roughness tester. Statistical analysis was performed after collecting the data. Results: All materials exhibited changes in surface roughness after the use of both toothpastes. The self-curing composite showed the less change and glass ionomer materials showed the greatest changes in surface roughness. Conclusions: The surface changes of dental materials depended on their composition and the cleaning procedure. Although self-curing composite was the most resistant to surface changes, its surface roughness values were high. Light-curing composite presented the lowest surface roughness values, even after brushing with toothpastes. The “medium” labeled toothbrush caused significant changes without toothpaste on the surface of light-curing composite, glass ionomer and silicate cement materials.

  5. The Effect of Plasma Surface Treatment on a Porous Green Ceramic Film with Polymeric Binder Materials

    International Nuclear Information System (INIS)

    Yun Jeong Woo

    2013-01-01

    To reduce time and energy during thermal binder removal in the ceramic process, plasma surface treatment was applied before the lamination process. The adhesion strength in the lamination films was enhanced by oxidative plasma treatment of the porous green ceramic film with polymeric binding materials. The oxygen plasma characteristics were investigated through experimental parameters and weight loss analysis. The experimental results revealed the need for parameter analysis, including gas material, process time, flow rate, and discharge power, and supported a mechanism consisting of competing ablation and deposition processes. The weight loss analysis was conducted for cyclic plasma treatment rather than continuous plasma treatment for the purpose of improving the film's permeability by suppressing deposition of the ablated species. The cyclic plasma treatment improved the permeability compared to the continuous plasma treatment.

  6. Surface potential based modeling of charge, current, and capacitances in DGTFET including mobile channel charge and ambipolar behaviour

    Science.gov (United States)

    Jain, Prateek; Yadav, Chandan; Agarwal, Amit; Chauhan, Yogesh Singh

    2017-08-01

    We present a surface potential based analytical model for double gate tunnel field effect transistor (DGTFET) for the current, terminal charges, and terminal capacitances. The model accounts for the effect of the mobile charge in the channel and captures the device physics in depletion as well as in the strong inversion regime. The narrowing of the tunnel barrier in the presence of mobile charges in the channel is incorporated via modeling of the inverse decay length, which is constant under channel depletion condition and bias dependent under inversion condition. To capture the ambipolar current behavior in the model, tunneling at the drain junction is also included. The proposed model is validated against TCAD simulation data and it shows close match with the simulation data.

  7. Effect of airflow velocity on moisture exchange at surfaces of building materials

    DEFF Research Database (Denmark)

    Mortensen, Lone Hedegaard; Rode, Carsten; Peuhkuri, Ruut Hannele

    2006-01-01

    The moisture transfer between air and construction are affected of the boundary layer conditions close to the surface, which is influenced by the airflow patterns in the room. Therefore an investigation of the relation be-tween the surface resistance and the airflow velocity above a material samp...... resistances decrease for increasing airflow velocity above the boundary layer of the material surface. The measured resistances are somewhat smaller than the ones esti-mated by use of the Lewis relation....

  8. NTERACTION BETWEEN SURFACE CHARGE PHENOMENA AND MULTI-SPECIES DIFFUSION IN CEMENT BASED MATERIALS

    DEFF Research Database (Denmark)

    Johannesson, Björn

    2008-01-01

    Measurements strongly indicate that the ‘inner’ surface of the microscopic structure of cement based materials has a fixed negative charge. This charge contributes to the formation of so-called electrical double layers. In the case of cement based materials the ionic species located in such layers...... are typically potassium -, sodium - and calcium ions. Due to the high specific surface area of hydrated cement, a large amount of ions can be located in theses double layers even if the surface charge is relatively low. The attraction force, caused by the fixed surface charge on ions located close to surfaces...

  9. Surface ablation of inorganic transparent materials using 70W femtosecond pulses at 1MHz (Conference Presentation)

    Science.gov (United States)

    Mishchik, Konstantin; Gaudfrin, Kevin; Audouard, Eric F.; Mottay, Eric P.; Lopez, John

    2017-03-01

    Nowadays processing of transparent materials, such as glass, quartz, sapphire and others, is a subject of high interest for worldwide industry since these materials are widely used for mass markets such as consumer electronics, flat display panels manufacturing, optoelectronics or watchmaking industry. The key issue is to combine high throughput, low residual stress and good processing quality in order to avoid chipping and any post-processing step such as grinding or polishing. Complimentary to non-ablative techniques used for zero-kerf glass cutting, surface ablation of such materials is interesting for engraving, grooving as well as full ablation cutting. Indeed this technique enables to process complex parts including via or blind, open or closed, straight or small radius of curvature patterns. We report on surface ablation experiments on transparent materials using a high average power (70W) and high repetition rate (1 MHz) femtosecond laser. These experiments have been done at 1030nm and 515nm on different inorganic transparent materials, such as regular and strengthened glass, borosilicate glass or sapphire, in order to underline their different ablation behavior. Despite the heat accumulation that occurs above 100 kHz we have reached a good compromise between throughput and processing quality. The effects of fluence, pulse-to-pulse overlap and number of passes are discussed in terms of etch rate, ablation efficiency, optimum fluence, maximum achievable depth, micro cracks formation and residual stresses. These experimental results will be also compared with numerical calculations obtained owing to a simple engineering model based on the two-temperature description of the ultrafast ablation.

  10. The application of a layer of carbonaceous material to a surface

    International Nuclear Information System (INIS)

    Holland, L.A.

    1981-01-01

    A method of applying a carbonaceous material to a surface is described. It consists of exposing the surface to an ionised gas atmosphere generated in a gas consisting substantially of carbon and hydrogen, and applying to the surface through capacitive means an electrical potential which changes in sign at time intervals of between 5 x 10 -9 seconds and 10 -6 seconds. (author)

  11. Three-Body Abrasion Testing Using Lunar Dust Simulants to Evaluate Surface System Materials

    Science.gov (United States)

    Kobrick, Ryan L.; Budinski, Kenneth G.; Street, Kenneth W., Jr.; Klaus, David M.

    2010-01-01

    Numerous unexpected operational issues relating to the abrasive nature of lunar dust, such as scratched visors and spacesuit pressure seal leaks, were encountered during the Apollo missions. To avoid reoccurrence of these unexpected detrimental equipment problems on future missions to the Moon, a series of two- and three-body abrasion tests were developed and conducted in order to begin rigorously characterizing the effect of lunar dust abrasiveness on candidate surface system materials. Two-body scratch tests were initially performed to examine fundamental interactions of a single particle on a flat surface. These simple and robust tests were used to establish standardized measurement techniques for quantifying controlled volumetric wear. Subsequent efforts described in the paper involved three-body abrasion testing designed to be more representative of actual lunar interactions. For these tests, a new tribotester was developed to expose samples to a variety of industrial abrasives and lunar simulants. The work discussed in this paper describes the three-body hardware setup consisting of a rotating rubber wheel that applies a load on a specimen as a loose abrasive is fed into the system. The test methodology is based on ASTM International (ASTM) B611, except it does not mix water with the abrasive. All tests were run under identical conditions. Abraded material specimens included poly(methyl methacrylate) (PMMA), hardened 1045 steel, 6061-T6 aluminum (Al) and 1018 steel. Abrasives included lunar mare simulant JSC- 1A-F (nominal size distribution), sieved JSC-1A-F (sieved version of the simulant. The lunar dust displayed abrasivity to all of the test materials, which are likely to be used in lunar landing equipment. Based on this test experience and pilot results obtained, recommendations are made for systematic abrasion testing of candidate materials intended for use in lunar exploration systems and in other environments with similar dust challenges.

  12. Surface characteristics changes in polymeric material by swift ion beam

    Science.gov (United States)

    Abdul-Kader, A. M.; El-Gendy, Y. A.

    2018-03-01

    In this work, polyethylene (PE) samples were subjected to 9 MeV Cl+2 ions with fluences ranging from 1 × 1013 to 5 × 1014 ion/cm2. Rutherford back scattering spectrometry (RBS), X-ray diffraction (XRD), ultraviolet-visible (UV-vis) spectroscopy and Vicker's micro-hardness (Hv) techniques were used to investigate the compositional transformation, changes in the structure, optical and surface hardness of bombarded samples. The adhesion parameters were analyzed using the contact angle measurements. The obtained results showed that the ion irradiation caused a decrease in the crystallinity of polyethylene and increase in absorption of oxygen on the polymer surface as well. The absorption edge shifted towards the red shift as Cl-ion fluence increases. It was found that the hardness and adhesion parameters increase with increasing the ion beam fluence.

  13. Sound absorption of low-temperature reusable surface insulation candidate materials

    Science.gov (United States)

    Johnston, J. D.

    1974-01-01

    Sound absorption data from tests of four candidate low-temperature reusable surface insulation materials are presented. Limitations on the use of the data are discussed, conclusions concerning the effective absorption of the materials are drawn, and the relative significance to Vibration and Acoustic Test Facility test planning of the absorption of each material is assessed.

  14. Surface alloys as interfacial layers between quasicrystalline and periodic materials

    Science.gov (United States)

    Duguet, T.; Ledieu, J.; Dubois, J. M.; Fournée, V.

    2008-08-01

    Low adhesion with normal metals is an intrinsic property of many quasicrystalline surfaces. Although this property could be useful to develop low friction or non-stick coatings, it is also responsible for the poor adhesion of quasicrystalline coatings on metal substrates. Here we investigate the possibility of using complex metallic surface alloys as interface layers to enhance the adhesion between quasicrystals and simple metal substrates. We first review some examples where such complex phases are formed as an overlayer. Then we study the formation of such surface alloys in a controlled way by annealing a thin film deposited on a quasicrystalline substrate. We demonstrate that a coherent buffer layer consisting of the γ-Al4Cu9 approximant can be grown between pure Al and the i-Al-Cu-Fe quasicrystal. The interfacial relationships between the different layers are defined by [111]_{\\mathrm {Al}}\\parallel [110]_{\\mathrm {Al_4Cu_9}}\\parallel [5\\mathrm {f}]_{i\\mbox {-}\\mathrm {Al\\mbox {--}Cu \\mbox {--}Fe}} .

  15. Surface alloys as interfacial layers between quasicrystalline and periodic materials

    Energy Technology Data Exchange (ETDEWEB)

    Duguet, T; Ledieu, J; Dubois, J M; Fournee, V [Laboratoire de Science et Genie des Materiaux et de Metallurgie, UMR 7584 CNRS-Nancy Universite, Ecole des Mines de Nancy, Parc de Saurupt, F-54042 Nancy (France)], E-mail: fournee@lsg2m.org

    2008-08-06

    Low adhesion with normal metals is an intrinsic property of many quasicrystalline surfaces. Although this property could be useful to develop low friction or non-stick coatings, it is also responsible for the poor adhesion of quasicrystalline coatings on metal substrates. Here we investigate the possibility of using complex metallic surface alloys as interface layers to enhance the adhesion between quasicrystals and simple metal substrates. We first review some examples where such complex phases are formed as an overlayer. Then we study the formation of such surface alloys in a controlled way by annealing a thin film deposited on a quasicrystalline substrate. We demonstrate that a coherent buffer layer consisting of the {gamma}-Al{sub 4}Cu{sub 9} approximant can be grown between pure Al and the i-Al-Cu-Fe quasicrystal. The interfacial relationships between the different layers are defined by [111]{sub Al} parallel [110]{sub Al4Cu9} parallel [5f]{sub i-Al-}C{sub u-Fe}.

  16. New design of material surface utilizing introduction of hydroxyl

    International Nuclear Information System (INIS)

    Kim, Min; Tsuneda, Satoshi; Saito, Kyoichi

    1994-01-01

    In order to give new function to the polymer materials having various shapes which are easily available, for example films, unwoven cloths, tubes and hollow threads, while maintaining the shapes, graft polymerization is suitable. The common procedure for graft poly merization is first a radical is formed in an original polymer, then vinyl monomer is brought in contact with there, and it is converted to the desired functional radical. The research group of the authors developed the new film material which can separate and refine rapidly and in large capacity protein from culture solution and blood plasma, and proposed the new technique for synthesizing the ion exchange material having the shape suitable to use more simply. In both cases, the graft polymer chain having hydroxyl plays the important role. By extending graft polymer chain from the circumferences of holes in a porous film toward the holes and passing protein solution through it, protein is recovered. The method of making such porous films and the method of introducing hydroxyl are explained. When the vinyl monomer having sulfonic acid radical is given to polyethylene films and tubes, the films change to ion exchange films, and the tubes change to acid catalyst. These processes are explained. (K.I.)

  17. Surface roughness and adaptation of different materials to secure implant attachment housings.

    Science.gov (United States)

    Ozkir, Serhat Emre; Yilmaz, Burak; Kurkcuoglu, Isin; Culhaoglu, Ahmet; Unal, Server Mutluay

    2017-01-01

    Various materials are available to secure implant attachment housings in overdentures. Surface roughness and the adaptation of these materials to the denture base and the housings may increase the microcracks and bacterial adhesion at the interfaces in the long term. The surface characteristics of the interface between the denture base orientation material and the attachment housing have not been extensively studied. The purpose of this in vitro study was to evaluate the surface roughness and the adaptation of 5 different housing orientation materials to the housings and the denture base. Fifty-five poly(methyl methacrylate) (PMMA) specimens (15 mm in diameter and 4 mm in height) were prepared with a clearance inside to allow the insertion of overdenture housings. Five different materials were used for housing orientation (Quick Up, Ufi Gel Hard, Tokuyama Rebase II Fast, Meliodent, and Paladent). The specimens were thermocycled 5000 times between 5°C and 55°C. The surface roughness (Ra values) of the specimens was measured with a noncontact profilometer. Scanning electron images were made in order to inspect the PMMA-orientation material-housing interfaces. The Kruskal-Wallis test was used to investigate the differences between the surface roughness values of the orientation materials, and the Iman-Conover test was used for pairwise comparisons (α=.05). The surface roughness values significantly differed between Quick up and Ufi Gel orientation materials only, and Quick up had smaller surface roughness values than Ufi Gel (P=.009). Microcracks were observed among the groups only at the junction of the orientation material and the housing after thermocycling. Ufi Gel Hard showed the roughest surfaces around the overdenture attachment housings. The adaptation between the orientation material and the housing may deteriorate, and increased surface roughness and microcrack formation may be seen around the housings. Copyright © 2016 Editorial Council for the

  18. Surface Hardness of Resin Cement Polymerized under Different Ceramic Materials

    OpenAIRE

    Kesrak, Pimmada; Leevailoj, Chalermpol

    2012-01-01

    Objectives. To evaluate the surface hardness of two light-cured resin cements polymerized under different ceramic discs. Methods. 40 experimental groups of 2 light-cured resin cement specimens (Variolink Veneer and NX3) were prepared and polymerized under 5 different ceramic discs (IPS e.max Press HT, LT, MO, HO, and Cercon) of 4 thicknesses (0.5, 1.0, 1.5, and 2.0 mm), Those directly activated of both resin cements were used as control. After light activation and 3 7 ∘ C storage in an incuba...

  19. Systems and Methods of Laser Texturing of Material Surfaces and Their Applications

    Science.gov (United States)

    Gupta, Mool C. (Inventor); Nayak, Barada K. (Inventor)

    2014-01-01

    The surface of a material is textured and by exposing the surface to pulses from an ultrafast laser. The laser treatment causes pillars to form on the treated surface. These pillars provide for greater light absorption. Texturing and crystallization can be carried out as a single step process. The crystallization of the material provides for higher electric conductivity and changes in optical and electronic properties of the material. The method may be performed in vacuum or a gaseous environment. The gaseous environment may aid in texturing and/or modifying physical and chemical properties of the surfaces. This method may be used on various material surfaces, such as semiconductors, metals and their alloys, ceramics, polymers, glasses, composites, as well as crystalline, nanocrystalline, polycrystalline, microcrystalline, and amorphous phases.

  20. Antimicrobial activity of transition metal acid MoO3 prevents microbial growth on material surfaces

    International Nuclear Information System (INIS)

    Zollfrank, Cordt; Gutbrod, Kai; Wechsler, Peter; Guggenbichler, Josef Peter

    2012-01-01

    Serious infectious complications of patients in healthcare settings are often transmitted by materials and devices colonised by microorganisms (nosocomial infections). Current strategies to generate material surfaces with an antimicrobial activity suffer from the consumption of the antimicrobial agent and emerging multidrug-resistant pathogens amongst others. Consequently, materials surfaces exhibiting a permanent antimicrobial activity without the risk of generating resistant microorganisms are desirable. This publication reports on the extraordinary efficient antimicrobial properties of transition metal acids such as molybdic acid (H 2 MoO 4 ), which is based on molybdenum trioxide (MoO 3 ). The modification of various materials (e.g. polymers, metals) with MoO 3 particles or sol–gel derived coatings showed that the modified materials surfaces were practically free of microorganisms six hours after contamination with infectious agents. The antimicrobial activity is based on the formation of an acidic surface deteriorating cell growth and proliferation. The application of transition metal acids as antimicrobial surface agents is an innovative approach to prevent the dissemination of microorganisms in healthcare units and public environments. Highlights: ► The presented modifications of materials surfaces with MoO 3 are non-cytotoxic and decrease biofilm growth and bacteria transmission. ► The material is insensitive towards emerging resistances of bacteria. ► Strong potential to reduce spreading of infectious agents on inanimate surfaces.

  1. Surface hardness of different restorative materials after long-term immersion in sports and energy drinks.

    Science.gov (United States)

    Erdemir, Ugur; Yildiz, Esra; Eren, Meltem Mert; Ozel, Sevda

    2012-01-01

    The purpose of this study was to evaluate the effect of sports and energy drinks on the surface hardness of different restorative materials over a 6-month period. Forty-two disk-shaped specimens were prepared for each of the four restorative materials tested: Compoglass F, Filtek Z250, Filtek Supreme, and Premise. Specimens were immersed for 2 min daily, up to 6 months, in six storage solutions (n=7 per material for each solution): distilled water, Powerade, Gatorade, X-IR, Burn, and Red Bull. Surface hardness was measured at baseline, after 1 week, 1 month, and 6 months. Data were analyzed statistically using repeated measures ANOVA followed by the Bonferroni test for multiple comparisons (α=0.05). Surface hardness of the restorative materials was significantly affected by both immersion solution and immersion period (p<0.001). All tested solutions induced significant reduction in surface hardness of the restorative materials over a 6-month immersion period.

  2. Surface modification of layered zirconium phosphates: a novel pathway to multifunctional materials.

    Science.gov (United States)

    Mosby, Brian M; Díaz, Agustín; Clearfield, Abraham

    2014-07-21

    The intercalation of inorganic layered materials has resulted in a wide range of applicability. In such cases the applicability of the material is largely dependent upon the species intercalated within the layer, and the layered material acts largely as a host. Recently, the surface modification of inorganic layered materials has been investigated and it has been shown that the exterior layers can be exclusively functionalized. The advent of surface chemistry allows for the synthesis of particles with both a controlled interlayer and surface. This approach can be used to tailor nanoparticles for specific applications. Herein we review the surface chemistry of α-zirconium bis(monohydrogen orthophosphate) monohydrate (Zr(HPO4)2·H2O, α-ZrP) along with some applications of recent interest. Not only can these reactions be applied to α-ZrP, but similar chemistry can also be expanded to other layered materials and systems.

  3. Characterization of genotoxic response to 15 multiwalled carbon nanotubes with variable physicochemical properties including surface functionalizations in the FE1-Muta(TM) mouse lung epithelial cell line.

    Science.gov (United States)

    Jackson, Petra; Kling, Kirsten; Jensen, Keld Alstrup; Clausen, Per Axel; Madsen, Anne Mette; Wallin, Håkan; Vogel, Ulla

    2015-03-01

    Carbon nanotubes vary greatly in physicochemical properties. We compared cytotoxic and genotoxic response to 15 multiwalled carbon nanotubes (MWCNT) with varying physicochemical properties to identify drivers of toxic responses. The studied MWCNT included OECD Working Party on Manufactured Nanomaterials (WPMN) (NM-401, NM-402, and NM-403), materials (NRCWE-026 and MWCNT-XNRI-7), and three sets of surface-modified MWCNT grouped by physical characteristics (thin, thick, and short I-III, respectively). Each Groups I-III included pristine, hydroxylated and carboxylated MWCNT. Group III also included an amino-functionalized MWCNT. The level of surface functionalization of the MWCNT was low. The level and type of elemental impurities of the MWCNT varied by <2% of the weight, with exceptions. Based on dynamic light scattering data, the MWCNT were well-dispersed in stock dispersion of nanopure water with 2% serum, but agglomerated and sedimented during exposure. FE1-Muta(TM) Mouse lung epithelial cells were exposed for 24 hr. The levels of DNA strand breaks (SB) were evaluated using the comet assay, a screening assay suitable for genotoxicity testing of nanomaterials. Exposure to MWCNT (12.5-200 µg/ml) did not induce significant cytotoxicity (viability above 92%). Cell proliferation was reduced in highest doses of some MWCNT after 24 hr, and was associated with generation of reactive oxygen species and high surface area. Increased levels of DNA SB were only observed for Group II consisting of MWCNT with large diameters and high Fe2 O3 and Ni content. Significantly, increased levels of SB were only observed at 200 µg/ml of MWCNT-042. Overall, the MWCNT were not cytotoxic and weakly genotoxic after 24 hr exposure to doses up to 200 µg/ml. © 2014 Wiley Periodicals, Inc.

  4. Teacher-Made Tactile Science Materials with Critical and Creative Thinking Activities for Learners Including Those with Visual Impairments

    Science.gov (United States)

    Teske, Jolene K.; Gray, Phyllis; Kuhn, Mason A.; Clausen, Courtney K.; Smith, Latisha L.; Alsubia, Sukainah A.; Ghayoorad, Maryam; Rule, Audrey C.; Schneider, Jean Suchsland

    2014-01-01

    Gifted students with visual impairments are twice exceptional learners and may not evidence their advanced science aptitudes without appropriate accommodations for learning science. However, effective tactile science teaching materials may be easily made. Recent research has shown that when tactile materials are used with "all" students…

  5. Effect of a glaze/composite sealant on the 3-D surface roughness of esthetic restorative materials.

    Science.gov (United States)

    Perez, Cesar dos Reis; Hirata, Raphael Júnior; da Silva, Antonio Henrique Monteiro da Fonseca Thomé; Sampaio, Eduardo Martins; de Miranda, Mauro Sayão

    2009-01-01

    The main goal of the current study was to evaluate the surface roughness of tooth-colored restorative materials after different finishing/polishing protocols, including a liquid polisher (BisCover, BISCO, Schaumburg, IL, USA). The restorative materials tested included two nanofilled resin composites (Filtek Supreme, 3M Dental Products, St Paul, MN, USA and Grandio, Voco, Cuxhaven, Germany), one resin-modified glass ionomer cement (Vitremer, 3M Dental Products) and one conventional glass ionomer cement (Meron Molar ART, Voco). The finishing/polishing methods were divided into five groups: G1 (compression with Mylar matrix), G2 (finishing with diamond burs), G3 (Sof-Lex, 3M Dental Products), G4 (BisCover, BISCO, after diamond burs) and G5 (BisCover after Sof-Lex). Five cylindrical specimens of each material were prepared for each group according to the manufacturer's instructions. The finishing/polishing methods were performed by a single operator in one direction to avoid variations at low speed (15,000 RPM). The surface roughness was evaluated using a 3-D scanning instrument with two parameters considered (Ra and Rz). The data was analyzed using one-way ANOVA followed by a multiple comparison Tukey's test. The results showed that BisCover (BISCO) was capable of reducing surface roughness and provided polished surfaces for all materials, enhancing smoothness over already polished surfaces (Sof-Lex, 3M Dental Products) and achieving polishing after finishing with diamond burs.

  6. Water Quality Instructional Resources Information System (IRIS): A Compilation of Abstracts to Water Quality and Water Resources Materials. Includes May 1979 edition and Supplements 1-15.

    Science.gov (United States)

    Ohio State Univ., Columbus, OH. Information Reference Center for Science, Mathematics, and Environmental Education.

    Compiled are abstracts and indexes to selected print and non-print materials related to wastewater treatment and water quality education and instruction, as well as materials related to pesticides, hazardous wastes, and public participation. Sources of abstracts/indexed materials include all levels of government, private concerns, and educational…

  7. Transfer of Impact Ejecta Material from the Surface of Mars to Phobos and Deimos

    Science.gov (United States)

    Melosh, Henry J.; Vaquero, Mar; Howell, Kathleen C.

    2013-01-01

    Abstract The Russian Phobos-Grunt spacecraft originally planned to return a 200 g sample of surface material from Phobos to Earth. Although it was anticipated that this material would mainly be from the body of Phobos, there is a possibility that such a sample may also contain material ejected from the surface of Mars by large impacts. An analysis of this possibility is completed by using current knowledge of aspects of impact cratering on the surface of Mars and the production of high-speed ejecta that might reach Phobos or Deimos. Key Words: Impact cratering—Ejecta transfer—Phobos. Astrobiology 13, 963–980. PMID:24131246

  8. Transfer of impact ejecta material from the surface of Mars to Phobos and Deimos.

    Science.gov (United States)

    Chappaz, Loïc; Melosh, Henry J; Vaquero, Mar; Howell, Kathleen C

    2013-10-01

    The Russian Phobos-Grunt spacecraft originally planned to return a 200 g sample of surface material from Phobos to Earth. Although it was anticipated that this material would mainly be from the body of Phobos, there is a possibility that such a sample may also contain material ejected from the surface of Mars by large impacts. An analysis of this possibility is completed by using current knowledge of aspects of impact cratering on the surface of Mars and the production of high-speed ejecta that might reach Phobos or Deimos.

  9. Compositions of stone and stone surface materials of historical monuments from Vidzeme and Zemgale

    International Nuclear Information System (INIS)

    Actins, A.; Spricis, A.; Zekunde, A.; Nemerova, A.

    2004-01-01

    By means of x-ray analysis composition of stone and stone surface materials of historical monuments from Vidzeme and Zemgale was investigated. Corrosion products of tuffa materials were identified on surfaces of some investigated monuments. Similarity of composition of products of stone corrosion for monuments from Latvia and Poland was recognised. Content of heavy metals at stone materials of historical monuments and at the surface layers of these monuments was investigated by means of atomic absorption and potentiometric stripping methods. Reasons of formation of compounds and pollution of investigated samples were discussed. (full text)

  10. Small-angle and surface scattering from porous and fractal materials.

    Energy Technology Data Exchange (ETDEWEB)

    Sinha, S. K.

    1998-09-18

    We review the basic theoretical methods used to treat small-angle scattering from porous materials, treated as general two-phase systems, and also the basic experimental techniques for carrying out such experiments. We discuss the special forms of the scattering when the materials exhibit mass or surface fractal behavior, and review the results of recent experiments on several types of porous media and also SANS experiments probing the phase behavior of binary fluid mixtures or polymer solutions confined in porous materials. Finally, we discuss the analogous technique of off-specular scattering from surfaces and interfaces which is used to study surface roughness of various kinds.

  11. Surface engineering of ultrafine cellulose nanofibrils toward polymer nanocomposite materials.

    Science.gov (United States)

    Fujisawa, Shuji; Saito, Tsuguyuki; Kimura, Satoshi; Iwata, Tadahisa; Isogai, Akira

    2013-05-13

    Surface grafting of crystalline and ultrafine cellulose nanofibrils with poly(ethylene glycol) (PEG) chains via ionic bonds was achieved by a simple ion-exchange treatment. The PEG-grafted cellulose nanofibrils exhibited nanodispersibility in organic solvents such as chloroform, toluene, and tetrahydrofuran. Then, the PEG-grafted cellulose nanofibril/chloroform dispersion and poly(L-lactide) (PLLA)/chloroform solution were mixed, and the PEG-grafted cellulose nanofibril/PLLA composite films with various blend ratios were prepared by casting the mixtures on a plate and drying. The tensile strength, Young's modulus, and work of fracture of the composite films were remarkably improved, despite low cellulose addition levels (cellulose nanofibrils in the PLLA matrix. Moreover, some attractive interactions mediated by the PEG chains were likely to be formed between the cellulose nanofibrils and PLLA molecules in the composites, additionally enhancing the efficient nanocomposite effect.

  12. Surface regulated arsenenes as Dirac materials: From density functional calculations

    Energy Technology Data Exchange (ETDEWEB)

    Yuan, Junhui; Xie, Qingxing; Yu, Niannian, E-mail: niannianyu@whut.edu.cn; Wang, Jiafu, E-mail: jasper@whut.edu.cn

    2017-02-01

    Highlights: • The presence of Dirac cones in chemically decorated buckled arsenene AsX (X = CN, NC, NCO, NCS, and NCSe) has been revealed. • First-principles calculations show that all these chemically decorated arsenenes are kinetically stable in defending thermal fluctuations in room temperature. - Abstract: Using first principle calculations based on density functional theory (DFT), we have systematically investigated the structure stability and electronic properties of chemically decorated arsenenes, AsX (X = CN, NC, NCO, NCS and NCSe). Phonon dispersion and formation energy analysis reveal that all the five chemically decorated buckled arsenenes are energetically favorable and could be synthesized. Our study shows that wide-bandgap arsenene would turn into Dirac materials when functionalized by -X (X = CN, NC, NCO, NCS and NCSe) groups, rendering new promises in next generation high-performance electronic devices.

  13. Mercurian bright patches - Evidence for physio-chemical alteration of surface material

    Science.gov (United States)

    Dzurisin, D.

    1977-01-01

    Morphologically and photometrically anomalous patches of highly-reflective material exist inside several large Mercurian craters. Calculations assuming that the patches exhibit an average lunar photometric function yield normal albedos of .39-.45, roughly 60% higher than Aristarchus, the brightest feature on the moon. Color-ratio images derived from Mariner 10 imaging data indicate that bright patches are bluer than typical Mercurian surface material, and are surrounded by material redder than typical surface material. Local physio-chemical alteration along impact-induced fractures may have been involved in production of these uniquely Mercurian features.

  14. Nonlinear Thermo-mechanical Finite Element Analysis of Polymer Foam Cored Sandwich Structures including Geometrical and Material Nonlinearity

    DEFF Research Database (Denmark)

    Palleti, Hara Naga Krishna Teja; Thomsen, Ole Thybo; Taher, Siavash Talebi

    In this paper, polymer foam cored sandwich structures with fibre reinforced composite face sheets subjected to combined mechanical and thermal loads will be analysed using the commercial FE code ABAQUS® incorporating both material and geometrical nonlinearity. Large displacements and rotations...

  15. Influence of material removal programming on ion beam figuring of high-precision optical surfaces

    Science.gov (United States)

    Liao, Wenlin; Dai, Yifan; Xie, Xuhui

    2014-09-01

    Ion beam figuring (IBF) provides a nanometer/subnanometer precision fabrication technology for optical components, where the surface materials on highlands are gradually removed by the physical sputtering effect. In this deterministic method, the figuring process is usually divided into several iterations and the sum of the removed material in each iteration is expected to approach the ideally removed material as nearly as possible. However, we find that the material removal programming in each iteration would influence the surface error convergence of the figuring process. The influence of material removal programming on the surface error evolution is investigated through the comparative study of the contour removal method (CRM) and the geometric proportion removal method (PRM). The research results indicate that the PRM can maintenance the smoothness of the surface topography during the whole figuring process, which would benefit the stable operation of the machine tool and avoid the production of mid-to-high spatial frequency surface errors. Additionally, the CRM only has the corrective effect on the area above the contour line in each iteration, which would result in the nonuniform convergence of the surface errors in various areas. All these advantages distinguish PRM as an appropriate material removal method for ultraprecision optical surfaces.

  16. Differences in Tribological Behaviors upon Switching Fixed and Moving Materials of Tribo-pairs including Metal and Polymer.

    Science.gov (United States)

    Xu, Aijie; Tian, Pengyi; Wen, Shizhu; Guo, Fei; Hu, Yueqiang; Jia, Wenpeng; Dong, Conglin; Tian, Yu

    2017-10-12

    The coefficient of friction (COF) between two materials is usually believed to be an intrinsic property of the materials themselves. In this study, metals of stainless steel (304) and brass (H62), and polymers of polypropylene (PP) and polytetrafluoroethylene (PTFE) were tested on a standard ball-on-three-plates test machine. Significantly different tribological behaviors were observed when fixed and moving materials of tribo-pairs (metal/polymer) were switched. As an example, under the same applied load and rotating speed, the COF (0.49) between a rotating PP ball and three fixed H62 plates was approximately 2.3 times higher than that between switched materials of tribo-pairs. Meanwhile, the COF between H62 and PTFE was relatively stable. The unexpected tribological behaviors were ascribed to the thermal and mechanical properties of tribo-pairs. Theoretical analysis revealed that the differences in the maximum local temperature between switching the fixed and moving materials of tribo-pairs were consistent with the differences in the tested COF. This result indicated the precise prediction of the COF of two materials is complexcity, and that thermal and mechanical properties should be properly considered in designing tribo-pairs, because these properties may significantly affect tribological performance.

  17. Improved Nanomechanical Test Techniques for Surface Engineered Materials

    Directory of Open Access Journals (Sweden)

    Stephen R. Goodes

    2010-06-01

    Full Text Available The development and implementation of a wide range of innovative nanomechanical test techniques to solve tribological problems in applications as diverse as biomedical and automotive are described in this review. For improved wear resistance and durability, the importance of understanding the system response rather than the coating-only properties is emphasized. There are many applications involving mechanical contact where the key to understanding the problem is to test at higher load and to combine reliable measurements taken across different length scales using both nano- and micro-indentation and related wear measurement techniques which more closely simulate contact conditions to fully understand the mechanical behaviour and hence deliver improved application performance. Results are presented with the NanoTest platform for applications for biomedical devices and surface engineering of lightweight alloys for the automotive industry. By combining results with different techniques it is possible to postulate predictive design rules – based on the elastic and plastic deformation energies involved in contact - to aid the reliable optimisation of mechanical properties in the various contact situations in the different applications.

  18. Material transport of a magnetizable fluid by surface perturbation

    Energy Technology Data Exchange (ETDEWEB)

    Böhm, V. [Faculty of Mechanical Engineering, Ilmenau University of Technology, Ilmenau D-98693 (Germany); Naletova, V.A. [Faculty of Mechanics and Mathematics, Lomonosov Moscow State University, Vorobyovy gory, 119899 Moscow (Russian Federation); Popp, J. [Faculty of Mechanical Engineering, Ilmenau University of Technology, Ilmenau D-98693 (Germany); Zeidis, I., E-mail: igor.zeidis@tu-ilmenau.de [Faculty of Mechanical Engineering, Ilmenau University of Technology, Ilmenau D-98693 (Germany); Zimmermann, K. [Faculty of Mechanical Engineering, Ilmenau University of Technology, Ilmenau D-98693 (Germany)

    2015-12-01

    Within the research for apedal, contour variable locomotion systems, the influence of an alternating magnetic field on the shape of the free surface of a magnetizable fluid (magnetic fluid) is studied. In the framework of the Stokes approximation, for the case where the amplitude of the alternating component of the applied magnetic field is much less than the magnitude of the permanent component, it is shown analytically that a periodical traveling applied magnetic field can generate a transport of the fluid in a prescribed direction. Numerical computations are performed to calculate and analyze the flow rate of the fluid as a function of the parameters of the field and the fluid. This effect can be used in fluid transporting engineering mini- and microsystems. - Highlights: • The influence of a magnetic field on the shape of a magnetic fluid is studied. • A periodical traveling magnetic field can generate a transport of the fluid. • This effect can be used in fluid transporting engineering mini- and microsystems.

  19. The effect of disinfectant agents on dimensional stability and surface roughness of a tissue conditioner material

    Directory of Open Access Journals (Sweden)

    Amiralireza Khaledi

    2011-01-01

    Conclusion: The results showed that the disinfectant solutions used in this study did not have a significant effect on the surface quality and dimensional accuracy of Visco-gel as a functional impression material.

  20. Effect of Surface Impulsive Thermal Loads on Fatigue Behavior of Constant Volume Propulsion Engine Combustor Materials

    National Research Council Canada - National Science Library

    Zhu, Dongming

    2004-01-01

    .... In this study, a simulated engine test rig has been established to evaluate thermal fatigue behavior of a candidate engine combustor material, Haynes 188, under superimposed CO2 laser surface impulsive thermal loads (30 to 100 Hz...

  1. Surface dispersive energy determined with IGC-ID in anti-graffiti-coated building materials

    OpenAIRE

    Carmona-Quiroga, Paula María; Rubio, J.; Sánchez, M. Jesús; Martínez-Ramírez, S.; Blanco-Varela, María Teresa

    2011-01-01

    Coating building materials with anti-graffiti treatments hinders or prevents spray paint adherence by generating low energy surfaces. This paper describes the effect of coating cement paste, lime mortar, granite, limestone and brick with two anti-graffiti agents (a water-base fluoroalkylsiloxane, “Protectosil Antigraffiti®”, and a Zr ormosil) on the dispersive component of the surface energy of these five construction materials. The agents were rediluted in their respective solvents at concen...

  2. Influence of citric acid on the surface texture of glass ionomer restorative materials.

    Science.gov (United States)

    Reddy, Dappili Swami Ranga; Kumar, Ramachandran Anil; Venkatesan, Sokkalingam Mothilal; Narayan, Gopal Shankar; Duraivel, Dasarathan; Indra, Rajamani

    2014-09-01

    This study determined the effectiveness of G-coat plus surface protective agent over petroleum jelly on the surface texture of conventional Glass ionomer restorative materials. Three chemically cured conventional glass ionomer restorative materials type II, type IX and ketac molar were evaluated in this study. Sixty specimens were made for each restorative material. They were divided into two groups of thirty specimens each. Of the sixty specimens, thirty were coated with G-coat plus (a nano-filler coating) and the rest with petroleum jelly. Thirty samples of both protective coating agents were randomly divided into six groups of five specimens and conditioned in citric acid solutions of differing pH (pH 2, 3, 4, 5, 6 & 7). Each specimen was kept in citric acid for three hours a day, and the rest of time stored in salivary substitute. This procedure was repeated for 8 days. After conditioning, the surface roughness (Ra, μm) of each specimen was measured using a surface profilometer (Taylor & Habson, UK). Data was analyzed using one-way analysis of variance (ANOVA) and Tukey's HSD test at a significance level of 0.05. The surface textures of all the tested glass ionomer restorative materials protected with G-coat plus were not significantly affected by acids at low pH. The surface textures of all the tested glass ionomer restorative materials protected with petroleum jelly coating were significantly affected by acids at low pH. The effects of pH on the surface texture of glass ionomer restoratives are material dependent. Among all the materials tested the surface texture of Type II GIC (Group I) revealed marked deterioration when conditioned in solutions of low pH and was statistically significant. Hence, a protective coating either with G-coat plus or with light polymerized low viscosity unfilled resin adhesives is mandatory for all the glass ionomer restorations to increase the wear resistance of the restorative materials.

  3. Investigation of sandwich material surface created by abrasive water jet (AWJ via vibration emission

    Directory of Open Access Journals (Sweden)

    P. Hreha

    2014-01-01

    Full Text Available The paper presents research a of abrasive waterjet cutting of heterogeneous “sandwich“ material with different Young modulus of elasticity of the cutted surface geometry by means of vibration emission. In order to confirm hypothetical assumptions about direct relation between vibration emission and surface quality an experiment in heterogeneous material consisting of stainless steel (DIN 1.4006 / AISI 410 and alloy AlCuMg2 has been provided.

  4. Extended automated separation techniques in destructive neutron activation analysis; application to various biological materials, including human tissues and blood

    International Nuclear Information System (INIS)

    Tjioe, P.S.; Goeij, J.J.M. de; Houtman, J.P.W.

    1976-09-01

    Neutron activation analysis may be performed as a multi-element and low-level technique for many important trace elements in biological materials, provided that post-irradiation chemical separations are applied. This paper describes a chemical separation consisting of automated procedures for destruction, distillation, and anion-chromatography. The system developed enables the determination of 14 trace elements in biological materials, viz. antimony, arsenic, bromine, cadmium, chromium, cobalt, copper, gold, iron, mercury, molybdenum, nickel, selenium, and zinc. The aspects of sample preparation, neutron irradiation, gamma-spectrum evaluation, and blank-value contribution are also discussed

  5. A Review of Removable Surface Contamination on Radioactive Materials Transportation Containers

    Energy Technology Data Exchange (ETDEWEB)

    Kennedy, Jr, W. E.; Watson, E. C.; Murphy, D. W.; Harrer, B. J.; Harty, R.; Aldrich, J. M.

    1981-05-01

    This report contains the results of a study sponsored by the U.S. Nuclear Regulatory Commission (NRC) of removable surface contamination on radioactive materials transportation containers. The purpose of the study is to provide information to the NRC during their review of existing regulations. Data was obtained from both industry and literature on three major topics: 1) radiation doses, 2) economic costs, and 3) contamination frequencies. Containers for four categories of radioactive materials are considered including radiopharmaceuticals, industrial sources, nuclear fuel cycle materials, and low-level radioactive waste. Assumptions made in this study use current information to obtain realistic yet conservative estimates of radiation dose and economic costs. Collective and individual radiation doses are presented for each container category on a per container basis. Total doses, to workers and the public, are also presented for spent fuel cask and low-level waste drum decontamination. Estimates of the additional economic costs incurred by lowering current limits by factors of 10 and 100 are presented. Current contamination levels for each category of container are estimated from the data collected. The information contained in this report is designed to be useful to the NRC in preparing their recommendations for new regulations.

  6. 10 CFR 170.31 - Schedule of fees for materials licenses and other regulatory services, including inspections, and...

    Science.gov (United States)

    2010-01-01

    ... production of accelerator-produced radionuclides. Application [Program Code(s): 03210] $6,500 4. Waste.... Users. Application $3,100 Inspections Full Cost C. Evaluation of security plans, route approvals, route... under the reciprocity provisions of 10 CFR 150.20. Application $1,800 17. Master materials licenses of...

  7. Analysis of alternative transportation methods for radioactive materials shipments including the use of special trains for spent fuel and wastes

    International Nuclear Information System (INIS)

    Smith, D.R.; Luna, R.E.; Taylor, J.M.

    1978-01-01

    Two studies were completed which evaluate the environmental impact of radioactive material transport. The first was a generic study which evaluated all radioactive materials and all transportation modes; the second addressed spent fuel and fuel-cycle wastes shipped by truck, rail and barge. A portion of each of those studies dealing with the change in impact resulting from alternative shipping methods is presented in this paper. Alternatives evaluated in each study were mode shifts, operational constraints, and, in generic case, changes in material properties and package capabilities. Data for the analyses were obtained from a shipper survey and from projections of shipments that would occur in an equilibrium fuel cycle supporting one hundred 1000-MW(e) reactors. Population exposures were deduced from point source radiation formulae using separation distances derived for scenarios appropriate to each shipping mode and to each exposed population group. Fourteen alternatives were investigated for the generic impact case. All showed relatively minor changes in the overall radiological impact. Since the radioactive material transport is estimated to be fewer than 3 latent cancer fatalities (LCF) for each shipment year (compared to some 300,000 yearly cancer fatalities or 5000 LCF's calculated for background radiation using the same radiological effects model), a 15% decrease caused by shifting from passenger air to cargo air is a relatively small effect. Eleven alternatives were considered for the fuel cycle/special train study, but only one produced a reduction in total special train baseline LCF's (.047) that was larger than 5%

  8. Evaluation of surface fractal dimension of carbon for plasma-facing material damaged by hydrogen plasma

    International Nuclear Information System (INIS)

    Nishino, Nobuhiro

    1997-01-01

    The surface structure of the plasma facing materials (PFM) changes due to plasma-surface interaction in a nuclear fusion reactor. Usually B 4 C coated graphite block are used as PFM. In this report, the surface fractal was applied to study the surface structure of plasma-damaged PFM carbon. A convenient flow-type adsorption apparatus was developed to evaluate the surface fractal dimension of materials. Four branched alkanol molecules with different apparent areas were used as the probe adsorbates. The samples used here were B 4 C coated isotopic graphite which were subjected to hydrogen plasma for various periods of exposure. The monolayer capacities of these samples for alkanols were determined by applying BET theory. The surface fractal dimension was calculated using the monolayer capacities and molecular areas for probe molecules and was found to increase from 2 to 3 with the plasma exposure time. (author)

  9. Effect of plasticizer and surface topography on the cleanability of plasticized PVC materials

    International Nuclear Information System (INIS)

    Maeaettae, J.; Koponen, H.-K.; Kuisma, R.; Kymaelaeinen, H.-R.; Pesonen-Leinonen, E.; Uusi-Rauva, A.; Hurme, K.-R.; Sjoeberg, A.-M.; Suvanto, M.; Pakkanen, T.A.

    2007-01-01

    A quantitative radiochemical measuring procedure was used to investigate soil adhesion on laboratory-made polyvinyl chloride (PVC) surfaces. The materials contained different plasticizers and microstructures. Both the quality and amount of plasticizers and the microstructure affected the cleanability of the PVC samples. The surface topography and structures were examined with a contact angle meter, atomic force microscopy (AFM) and a contact profilometer

  10. Characterization of the surface of protein-adsorbed dental materials by wetting and streaming potential measurements

    NARCIS (Netherlands)

    Matsumura, H.; Kawasaki, K.; Okumura, N.; Kambara, M.; Norde, W.

    2003-01-01

    In this study we have elucidated the water-wettability and the electrokinetic surface potential of protein-covered dental materials. The proteins used here as typical proteins were human serum albumin and lysozyme from hen*s egg. The wettability (hydrophobicity/hydrophilicity) and the surface

  11. Characterization of the surface of protein-adsorbed dental materials by wetting and streaming potential measurements

    NARCIS (Netherlands)

    Matsumura, H; Kawasaki, K; Okumura, N; Kambara, M; Norde, W

    2003-01-01

    In this study we have elucidated the water-wettability and the electrokinetic surface potential of protein-covered dental materials. The proteins used here as typical proteins were human serum albumin and lysozyme from hen's egg. The wettability (hydrophobicity/hydrophilicity) and the surface

  12. Influence of mechanical and chemical degradation on surface gloss of resin composite materials

    NARCIS (Netherlands)

    Ardu, S.; Braut, V.; Uhac, I.; Benbachir, N.; Feilzer, A.J.; Krejci, I.

    2009-01-01

    Purpose: To determine the changes in surface gloss of different composite materials after simulation of mechanical and chemical aging mechanisms. Methods: 36 specimens were fabricated for each material and polished with 120-, 220-, 500-, 1200-, 2400- and 4000- grit SiC abrasive paper, respectively.

  13. Microwave surface resistance of bulk YBa2Cu3O6+x material

    Science.gov (United States)

    Fathy, A.; Kalokitis, D.; Belohoubek, E.; Sundar, H. G. K.; Safari, A.

    1988-10-01

    Superconducting Y-Ba-Cu-O samples were prepared by conventional solid-state reaction. The microwave surface resistance of 1:2:3 compound superconductor material was measured in a special disk resonator structure at 10 GHz. At liquid-nitrogen temperatures the microwave surface resistance is comparable to that of Au. At lower temperature (~10 K) the surface resistance is an order of magnitude lower than that of Au at the same temperature.

  14. Choosing of rational parameters of vibrational cleaning of sieving surfaces during materials classification

    OpenAIRE

    Кадильникова, Татьяна Михайловна; Силина, Наталья Александровна

    2012-01-01

    The article considers the issues of creation of energy-efficient technologies of vibrational cleaning of sieving surfaces during the classification of bulk solids of various sizes. The effects of vibration on the bulk solids were studied, its positive impact on the distribution of material on the work surface and the passage of solids through the sieve fractions of the mesh were determined. The article presents the dynamic scheme of vibrational cleaning of sieving surfaces during the classifi...

  15. Study of surfaces and surface layers on high temperature materials after short-time thermal loads

    International Nuclear Information System (INIS)

    Bolt, H.; Hoven, H.; Koizlik, K.; Linke, J.; Nickel, H.; Wallura, E.

    1985-11-01

    Being part of the plasma-wall interaction during TOKAMAK operation, erosion- and redeposition processes of First Wall materials substantially influence plasma parameters as well as the properties of the First Wall. An important redeposition process of eroded material is the formation of thin films by atomic condensation. Examinations of First Wall components after TOKAMAK operation lead to the assumption that these thin metallic films tend to agglomerate to small particles under subsequent heat load. In laboratory experiments it is shown that thin metallic films on various substrates can agglomerate under short time high heat fluxes and also under longer lasting lower thermal loads, thus verifying the ''agglomeration hypothesis''. (orig.) [de

  16. Properties and cleanability of new and traditional surface materials in cattle barns - a field study

    Directory of Open Access Journals (Sweden)

    R. KUISMA

    2008-12-01

    Full Text Available In this study surface properties and cleanability of new and traditional surface materials in cattle barns were examined in a field test. The concrete and plastic-coated samples were placed on a walking path on the floor and on a feeding table in a cattle barn. The surfaces were characterized using colorimetric and gloss measurements and determination of topography. In most cases, the colour of the surfaces placed on the floor darkened during the one year study period, whereas the colour changes of the samples placed on the feeding table did not show a similar trend. However, in both locations the plastic-coated surfaces were generally the easiest to clean, and the highest colour changes indicating soil residues were detected on the uncoated and silane-impregnated concrete surfaces. The difference between the locations was also seen in the gloss values, which increased in the samples placed on the floor during the one-year test period but varied considerably between the different materials on the surfaces placed on the feeding table. This field study confirmed the observation from earlier laboratory studies that plastic coatings improved the cleanability of concrete cattle barn surfaces. Silane impregnation was not functionally competitive with the plastic coatings. In general, the cleanability results were in accordance with the results of previous laboratory experiments but the field study provided practical information about the behaviour of the surface materials examined.;

  17. Evaluation of the anti-inflammatory actions of various functional food materials including glucosamine on synovial cells.

    Science.gov (United States)

    Yamagishi, Yoshie; Someya, Akimasa; Imai, Kensuke; Nagao, Junji; Nagaoka, Isao

    2017-08-01

    The anti-inflammatory actions of glucosamine (GlcN) on arthritic disorders involve the suppression of inflammatory mediator production from synovial cells. GlcN has also been reported to inhibit the activation of the p38 mitogen-activated protein kinase (MAPK) pathway. The present study aimed to determine the cooperative and anti‑inflammatory actions of functional food materials and evaluated the production of interleukin (IL)‑8 and phosphorylation of p38 MAPK in IL-1β-activated synovial cells, incubated with the combination of GlcN and various functional food materials containing L‑methionine (Met), undenatured type II collagen (UC‑II), chondroitin sulfate (CS), methylsulfonylmethane (MSM) and agaro-oligosaccharide (AO). The results indicated that Met, UC‑II, CS, MSM and AO slightly or moderately suppressed the IL-1β-stimulated IL‑8 production by human synovial MH7A cells. The same compounds further decreased the IL‑8 level lowered by GlcN. Similarly, they slightly suppressed the phosphorylation level of p38 MAPK and further reduced the phosphorylation level lowered by GlcN. These observations suggest a possibility that these functional food materials exert an anti‑inflammatory action (inhibition of IL‑8 production) in combination with GlcN by cooperatively suppressing the p38 MAPK signaling (phosphorylation).

  18. Synthesis and Sintering Behavior of Cordierite Prepared from Multi-Component Materials Including Alkaline-Earth Minerals

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Suk-In; Kim, Nam-Il; Lee, Sang-Jin [Mokpo National University, Muan (Korea, Republic of)

    2016-10-15

    Cordierite was synthesized using multi-component materials based on a talc-alumina-clay system. The cordierite sintered at 1360 °C showed a high relative density of 98.8% and a low thermal expansion coefficient of 1.59×10{sup -}6/°C. To study the effect of adding alkaline-earth minerals on the cordierite properties, petalite, potash-feldspar, and dicalcium phosphate were added to the synthesized cordierite. In the case of 9 wt% petalite or potash-feldspar addition, the cordierite was more densified; however, the thermal expansion coefficient and the pyroplasticity index were increased. In particular, a 5 μm thick self-glazed coating was formed with the addition of 9 wt% potash-feldspar. In the case of adding dicalcium phosphate, a glass phase was formed at low temperature and gas bubbles formed at high temperature above 1320 ℃. The cordierite synthesized using multi-component materials is expected to be employed as a material for high thermal shock, dense-microstructure flameware.

  19. Is Graphene a Promising Nano-Material for Promoting Surface Modification of Implants or Scaffold Materials in Bone Tissue Engineering?

    Science.gov (United States)

    Gu, Ming; Liu, Yunsong; Chen, Tong; Du, Feng; Zhao, Xianghui; Xiong, Chunyang

    2014-01-01

    Bone tissue engineering promises to restore bone defects that are caused by severe trauma, congenital malformations, tumors, and nonunion fractures. How to effectively promote the proliferation and osteogenic differentiation of mesenchymal stem cells (MSCs) or seed cells has become a hot topic in this field. Many researchers are studying the ways of conferring a pro-osteodifferentiation or osteoinductive capability on implants or scaffold materials, where osteogenesis of seed cells is promoted. Graphene (G) provides a new kind of coating material that may confer the pro-osteodifferentiation capability on implants and scaffold materials by surface modification. Here, we review recent studies on the effects of graphene on surface modifications of implants or scaffold materials. The ability of graphene to improve the mechanical and biological properties of implants or scaffold materials, such as nitinol and carbon nanotubes, and its ability to promote the adhesion, proliferation, and osteogenic differentiation of MSCs or osteoblasts have been demonstrated in several studies. Most previous studies were performed in vitro, but further studies will explore the mechanisms of graphene's effects on bone regeneration, its in vivo biocompatibility, its ability to promote osteodifferentiation, and its potential applications in bone tissue engineering. PMID:24447041

  20. Enhanced localization of Dyakonov-like surface waves in left-handed materials

    DEFF Research Database (Denmark)

    Crasovan, L. C.; Takayama, O.; Artigas, D.

    2006-01-01

    We address the existence and properties of hybrid surface waves forming at interfaces between left-handed materials and dielectric birefringent media. The existence conditions of such waves are found to be highly relaxed in comparison to Dyakonov waves existing in right-handed media. We show...... that left-handed materials cause the coexistence of several surface solutions, which feature an enhanced degree of localization. Remarkably, we find that the hybrid surface modes appear for large areas in the parameter space, a key property in view of their experimental observation....

  1. Assessment of interplay between UV wavelengths, material surfaces and food residues in open surface hygiene validation

    DEFF Research Database (Denmark)

    Abban, Stephen; Jakobsen, Mogens; Jespersen, Lene

    2014-01-01

    The use of UV-visible radiation for detecting invisible residue on different surfaces as a means of validating cleanliness was investigated. Wavelengths at 365, 395, 435, 445, 470 and 490 nm from a monochromator were used to detect residues of beef, chicken, apple, mango and skim milk. These were...

  2. Surface sieving coordinated IMAC material for purification of His-tagged proteins.

    Science.gov (United States)

    Li, Senwu; Yang, Kaiguang; Liu, Lukuan; Zhao, Baofeng; Chen, Yuanbo; Li, Xiao; Zhang, Lihua; Zhang, Yukui

    2018-01-02

    Tailor-made materials for the purification of proteins with His-tag was designed through synergizing the selectivity of surface sieving and metal ion affinity. By excluding impurity proteins out of the surface polymer network, such materials could purify His-tagged proteins from the crude cell lysis with purity up to 90%, improved by 14% compared to that obtained by the commercial metal chelating affinity materials. This study might promote the His-tagged protein purification to a new level. Copyright © 2017 Elsevier B.V. All rights reserved.

  3. Surface properties of ceramic/metal composite materials for thermionic converter applications

    International Nuclear Information System (INIS)

    Davis, P.R.; Bozack, M.J.; Swanson, L.W.

    1983-01-01

    Ceramic/metal composite electrode materials are of interest for thermionic energy conversion (TEC) applications for several reasons. These materials consist of submicron metal fibers or islands in an oxide matrix and therefore provide a basis for fabricating finely structured electrodes, with projecting or recessed metallic regions for more efficient electron emission or collection. Furthermore, evaporation and surface diffusion of matrix oxides may provide oxygen enhancement of cesium adsorption and work function lowering at both the collecting and emitting electrode surfaces of the TEC. Finally, the high work function oxide matrix or oxide-metal interfaces may provide efficient surface ionization of cesium for space-charge reduction in the device. The authors are investigating two types of ceramic/metal composite materials. One type is a directionally solidified eutectic consisting of a bulk oxide matrix such as UO 2 or stabilized ZrO 2 with parallel metal fibers (W) running through the oxide being exposed at the surface by cutting perpendicular to the fiber direction. The second type of material, called a surface eutectic, consists of a refractory substrate (Mo) with a thin layer of deposited and segregated material (Mo-Cr 2 O 3 -A1 2 O 3 ) on the surface. The final configuration of this layer is an oxide matrix with metallic islands scattered throughout

  4. Preliminary SEM Observations on the Surface of Elastomeric Impression Materials after Immersion or Ozone Disinfection

    Science.gov (United States)

    Prombonas, Anthony; Yannikakis, Stavros; Karampotsos, Thanasis; Katsarou, Martha-Spyridoula; Drakoulis, Nikolaos

    2016-01-01

    Introduction Surface integrity of dental elastomeric impression materials that are subjected to disinfection is of major importance for the quality of the final prosthetic restorations. Aim The aim of this qualitative Scanning Electronic Microscopy (SEM) study was to reveal the effects of immersion or ozone disinfection on the surface of four dental elastomeric impression materials. Materials and Methods Four dental elastomeric impression material brands were used (two vinyl polysiloxane silicones, one polyether, and one vinyl polyether silicone). Total of 32 specimens were fabricated, eight from each impression material. Specimens were immersion (0.525% sodium hypochlorite solution or 0.3% benzalkonium chloride solution) or ozone disinfected or served as controls and examined with SEM. Results Surface degradation was observed on several speci-mens disinfected with 0.525% sodium hypochlorite solution. Similar wavy-wrinkling surface structures were observed in almost all specimens, when treated either with 0.3% benzalkonium chloride solution or ozone. Conclusion The SEM images obtained from this study revealed that both immersion disinfectants and ozone show similar impression material surface alterations. Ozone seems to be non-inferior as compared to immersion disinfectants, but superior as to environmental protection. PMID:28208993

  5. The pore-load modulus of ordered nanoporous materials with surface effects

    Science.gov (United States)

    Liu, Mingchao; Wu, Jian; Gan, Yixiang; Chen, C. Q.

    2016-03-01

    Gas and liquid adsorption-induced deformation of ordered porous materials is an important physical phenomenon with a wide range of applications. In general, the deformation can be characterized by the pore-load modulus and, when the pore size reduces to nanoscale, it is affected by surface effects and shows prominent size-dependent features. In this Letter, the influence of surface effects on the elastic properties of ordered nanoporous materials with internal pressure is accounted for in a single pore model. A porosity and surface elastic constants dependent closed form solution for the size dependent pore-load modulus is obtained and verified by finite element simulations and available experimental results. In addition, it is found to depend on the geometrical arrangement of pores. This study provides an efficient tool to analyze the surface effects on the elastic response of ordered nanoporous materials.

  6. Surface hardening of optic materials by deposition of diamond like carbon coatings from separated plasma of arc discharge

    Science.gov (United States)

    Osipkov, A. S.; Bashkov, V. M.; Belyaeva, A. O.; Stepanov, R.; Mironov, Y. M.; Galinovsky, A. L.

    2015-02-01

    This article considers the issue of strengthening of optic materials used in the IR spectrum by deposition of diamond like carbon coatings from separated plasma arc discharge. The report shows results of tests of bare and strengthened optical materials such as BaF2, MgF2, Si, Ge, including the testing of their strength and spectral characteristics. Results for the determination of optical constants for the DLC coatings deposited on substrates of Ge and Si, by using separated plasma, are also presented. Investigations showed that surface hardening of optical materials operable in the IR range, by the deposition of diamond like carbon coating onto their surface, according to this technology, considerably improves operational properties and preserves or improves their optic properties.

  7. Apparent Surface Free Energy of Polymer/Paper Composite Material Treated by Air Plasma

    Directory of Open Access Journals (Sweden)

    Konrad Terpiłowski

    2017-01-01

    Full Text Available Surface plasma treatment consists in changes of surface properties without changing internal properties. In this paper composite polymer/paper material is used for production of packaging in cosmetic industry. There are problems with bonding this material at the time of packaging production due to its properties. Composite surface was treated by air plasma for 1, 10, 20, and 30 s. The advancing and receding contact angles of water, formamide, and diiodomethane were measured using both treated and untreated samples. Apparent surface free energy was estimated using the hysteresis (CAH and Van Oss, Good, Chaudhury approaches (LWAB. Surface roughness was investigated using optical profilometry and identification of after plasma treatment emerging chemical groups was made by means of the XPS (X-ray photoelectron spectroscopy technique. After plasma treatment the values of contact angles decreased which is particularly evident for polar liquids. Apparent surface free energy increased compared to that of untreated samples. Changes of energy value are due to the electron-donor parameter of energy. This parameter increases as a result of adding polar groups at the time of surface plasma activation. Changes of surface properties are combination of increase of polar chemical functional groups, increase on the surface, and surface roughness increase.

  8. CORROSION AND SURFACE PROTECTION IN MACHINE MATERIALS FRICTION HAVE DIFFERENT SURFACE PAIRS EXPERIMENTAL INVESTIGATION OF FACTORS

    OpenAIRE

    Senai YALCINKAYA

    2017-01-01

    Friction force, normal force, linear change. The normal force varies with the loads on the friction object. In order to determine the friction force and the friction coefficient, the friction object and the friction speed are used. The experimental work was carried out in three stages. In the first stage, the effect of normal force on the friction force was studied. In the second step, the friction force of the friction surface area is influenced. The effect of the change of the s...

  9. Effects of surface material, ventilation, and human behavior on indirect contact transmission risk of respiratory infection.

    Science.gov (United States)

    Sze-To, Gin Nam; Yang, Yang; Kwan, Joseph K C; Yu, Samuel C T; Chao, Christopher Y H

    2014-05-01

    Infectious particles can be deposited on surfaces. Susceptible persons who contacted these contaminated surfaces may transfer the pathogens to their mucous membranes via hands, leading to a risk of respiratory infection. The exposure and infection risk contributed by this transmission route depend on indoor surface material, ventilation, and human behavior. In this study, quantitative infection risk assessments were used to compare the significances of these factors. The risks of three pathogens, influenza A virus, respiratory syncytial virus (RSV), and rhinovirus, in an aircraft cabin and in a hospital ward were assessed. Results showed that reducing the contact rate is relatively more effective than increasing the ventilation rate to lower the infection risk. Nonfabric surface materials were found to be much more favorable in the indirect contact transmission for RSV and rhinovirus than fabric surface materials. In the cases considered in this study, halving the ventilation rate and doubling the hand contact rate to surfaces and the hand contact rate to mucous membranes would increase the risk by 3.7-16.2%, 34.4-94.2%, and 24.1-117.7%, respectively. Contacting contaminated nonfabric surfaces may pose an indirect contact risk up to three orders of magnitude higher than that of contacting contaminated fabric surfaces. These findings provide more consideration for infection control and building environmental design. © 2013 Society for Risk Analysis.

  10. Modeling the Nonlinear, Strain Rate Dependent Deformation of Shuttle Leading Edge Materials with Hydrostatic Stress Effects Included

    Science.gov (United States)

    Goldberg, Robert K.; Carney, Kelly S.

    2004-01-01

    An analysis method based on a deformation (as opposed to damage) approach has been developed to model the strain rate dependent, nonlinear deformation of woven ceramic matrix composites, such as the Reinforced Carbon Carbon (RCC) material used on the leading edges of the Space Shuttle. In the developed model, the differences in the tension and compression deformation behaviors have also been accounted for. State variable viscoplastic equations originally developed for metals have been modified to analyze the ceramic matrix composites. To account for the tension/compression asymmetry in the material, the effective stress and effective inelastic strain definitions have been modified. The equations have also been modified to account for the fact that in an orthotropic composite the in-plane shear response is independent of the stiffness in the normal directions. The developed equations have been implemented into LS-DYNA through the use of user defined subroutines (UMATs). Several sample qualitative calculations have been conducted, which demonstrate the ability of the model to qualitatively capture the features of the deformation response present in woven ceramic matrix composites.

  11. Application of atomic mutations included in nuclear reactions, 40Ar(γ, p)39Cl(β decay)39Ar, to surface study

    International Nuclear Information System (INIS)

    Ohkuma, Juzo

    1987-01-01

    It has been found that the nuclear transformation processes which are initiated by photonuclear reactions can be used for studying the adsorption and chemical reactions taking place on solid surfaces. Chemically reactive 39 Cl was produced by irradiating 40 Ar with high-energy bremsstrahlung, and its blow was directed onto several material surfaces. The amount of chlorine adsorption was ascertained by detecting its radioactivity. Desorption without heating the adsorber samples inevitably occurred owing to the nuclear decay of 39 Cl. The adsorption and desorption rates were compared for several elements. A fast growth of oxide islands on sample surfaces was observed during the adsorption-desorption process. (author)

  12. Investigation of thermal effect on exterior wall surface of building material at urban city area

    Energy Technology Data Exchange (ETDEWEB)

    Md Din, Mohd Fadhil; Dzinun, Hazlini; Ponraj, M.; Chelliapan, Shreeshivadasan; Noor, Zainura Zainun [Institute of Environmental Water Resources and Management (IPASA), Faculty of Civil Engineering, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor (Malaysia); Remaz, Dilshah [Faculty of Built Environment, Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor (Malaysia); Iwao, Kenzo [Nagoya Institute of Technology, Nagoya (Japan)

    2012-07-01

    This paper describes the investigation of heat impact on the vertical surfaces of buildings based on their thermal behavior. The study was performed based on four building materials that is commonly used in Malaysia; brick, concrete, granite and white concrete tiles. The thermal performances on the building materials were investigated using a surface temperature sensor, data logging system and infrared thermography. Results showed that the brick had the capability to absorb and store heat greater than other materials during the investigation period. The normalized heat (total heat/solar radiation) of the brick was 0.093 and produces high heat (51% compared to granite), confirming a substantial amount of heat being released into the atmosphere through radiation and convection. The most sensitive material that absorbs and stores heat was in the following order: brick > concrete > granite > white concrete tiles. It was concluded that the type of exterior wall material used in buildings had significant impact to the environment.

  13. Triphenyl borate as a bi-functional additive to improve surface stability of Ni-rich cathode material

    Science.gov (United States)

    Yim, Taeeun; Jang, Seol Heui; Han, Young-Kyu

    2017-12-01

    Nickel-rich cathode material has received marked attention as an advanced cathode material, however, its inferior surface property limits the achievement of high performance in lithium-ion batteries. We propose the use of a bi-functional additive of triphenyl borate (TPB) for improvement of the safety and electrochemical performance of Ni-rich cathode materials. First, TPB removes residual lithium species from the Ni-rich cathode surface via chemical binding with anion part of residual lithium species, and effectively reduces swelling behavior of the cell. Second, TPB creates effective cathode-electrolyte interphase (CEI) layers on the electrode surface by an electrochemical reaction, and greatly enhances the surface stability of the nickel-rich cathode. This work demonstrate that a cell cycled with the TPB additive exhibits a remarkable retention of 88.6% at 60 °C after 100 cycles for an NCM721 cathode material. We suggest a working mechanism for TPB based on systematic analyses, including in-situ and ex-situ experiments.

  14. Modelling and analysis of material removal rate and surface roughness in wire-cut EDM of armour materials

    Directory of Open Access Journals (Sweden)

    Ravindranadh Bobbili

    2015-12-01

    Full Text Available The current work presents a comparative study of wire electrical discharge machining (WEDM of armour materials such as aluminium alloy 7017 and rolled homogeneous armour (RHA steel using buckingham pi theorem to model the input variables and thermo-physical characteristics of WEDM on material removal rate (MRR and surface roughness (Ra of Al 7017 and RHA steel. The parameters of the model such as pulse-on time, flushing pressure, input power, thermal diffusivity and latent heat of vaporization have been determined through design of experiment methodology. Wear rate of brass wire increases with rise in input energy in machining Al 7017. The dependence of thermo-physical properties and machining variables on mechanism of MRR and Ra has been described by performing scanning electron microscope (SEM study. The rise in pulse-on time from 0.85μs to 1.25μs causes improvement in MRR and deterioration of surface finish. The machined surface has revealed that craters are found on the machined surface. The propensity of formation of craters increases during WEDM with a higher current and larger pulse-on time.

  15. Theoretical investigation of five-layer waveguide structure including two left-handed material layers for refractometric applications

    Science.gov (United States)

    Alkanoo, Anas A.; Taya, Sofyan A.

    2018-03-01

    A slab waveguide structure consisting of five layers is studied for optical sensing applications. The five-layer waveguide structure has a guiding dielectric film, two left-handed material (LHM) layers and two dielectric layers as a substrate and a cladding. The dispersion relation and the sensitivity to any change in the index of the analyte layer are derived. The sensitivity is explored with different parameters of the structure. It is found that the sensitivity of the proposed structure can be significantly improved with the increase of the index of the guiding layer and the decrease of the permittivity of the LHM layers. Moreover, it can be also improved with the increase of the thickness of the LHM layers.

  16. End of FY2014 Report - Filter Measurement System for Nuclear Material Storage Canisters (Including Altitude Correction for Filter Pressure Drop)

    Energy Technology Data Exchange (ETDEWEB)

    Moore, Murray E. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Reeves, Kirk Patrick [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-02-24

    Two LANL FTS (Filter Test System ) devices for nuclear material storage canisters are fully operational. One is located in PF-4 ( i.e. the TA-55 FTS) while the other is located at the Radiation Protection Division’s Aerosol Engineering Facility ( i.e. the TA-3 FTS). The systems are functionally equivalent , with the TA-3 FTS being the test-bed for new additions and for resolving any issues found in the TA-55 FTS. There is currently one unresolved issue regarding the TA-55 FTS device. The canister lid clamp does not give a leak tight seal when testing the 1 QT (quart) or 2 QT SAVY lids. An adapter plate is being developed that will ensure a correct test configuration when the 1 or 2 QT SAVY lid s are being tested .

  17. Light transmittance and surface roughness of a feldspathic ceramic CAD-CAM material as a function of different surface treatments.

    Science.gov (United States)

    Ural, Çağrı; Duran, İbrahim; Evmek, Betül; Kavut, İdris; Cengiz, Seda; Yuzbasioglu, Emir

    2016-07-15

    The aim of the present study was to determine the effect of different surface treatments on light transmission of aesthetic feldspathic ceramics used in CAD-CAM chairside restorations. Forty eight feldspatic ceramic test specimens were prepared from prefabricated CAD-CAM blocks by using a slow speed diamond saw. Test specimens were prepared and divided into 4 groups (n = 12). In the control group, no surface treatments were applied on the feldspathic ceramic surfaces. In the hydrofluoric acid group, the bonding surfaces of feldspathic ceramics were etched with 9.5 % hydrofluoric acid. In the sandblasting group the feldspathic ceramic surfaces were air-abraded with 30-μm alumium oxide (Al2O3) particles and Er:YAG laser was used to irradiate the ceramic surfaces. The incident light power given by the LED device and the transmitted light power through each ceramic sample was registered using a digital LED radiometer device. Each polymerization light had a light guide with 8-mm-diameter tips. Light transmission of feldspathic ceramic samples was determined by placing it on the radiometer and irradiating the specimen for 10 s at the highest setting for each light polymerization. All specimens were coated with gold using a sputter coater and examined under a field emission scanning electron microscope. Surface roughness measurement each group were evaluated with 3D optical surface and tactile profilometers. One-way ANOVA test results revealed that both surface conditioning method significantly affect the light transmittance (F:412.437; p ceramic material below the value of 400 mW/cm(2) which is critical limit for safe polymerization.

  18. Virus-based surface patterning of biological molecules, probes, and inorganic materials.

    Science.gov (United States)

    Ahn, Suji; Jeon, Seongho; Kwak, Eun-A; Kim, Jong-Man; Jaworski, Justyn

    2014-10-01

    An essential requirement for continued technological advancement in many areas of biology, physics, chemistry, and materials science is the growing need to generate custom patterned materials. Building from recent achievements in the site-specific modification of virus for covalent surface tethering, we show in this work that stable 2D virus patterns can be generated in custom geometries over large area glass surfaces to yield templates of biological, biochemical, and inorganic materials in high density. As a nanomaterial building block, filamentous viruses have been extensively used in recent years to produce materials with interesting properties, owing to their ease of genetic and chemical modification. By utilizing un-natural amino acids generated at specific locations on the filamentous fd bacteriophage protein coat, surface immobilization is carried out on APTES patterned glass resulting in precise geometries of covalently linked virus material. This technique facilitated the surface display of a high density of virus that were labeled with biomolecules, fluorescent probes, and gold nanoparticles, thereby opening the possibility of integrating virus as functional components for surface engineering. Copyright © 2014 Elsevier B.V. All rights reserved.

  19. Material removal and surface figure during pad polishing of fused silica

    Energy Technology Data Exchange (ETDEWEB)

    Suratwala, T I; Feit, M D; Steele, W A

    2009-05-04

    The material removal and surface figure after ceria pad polishing of fused silica glass have been measured and analyzed as a function of kinematics, loading conditions, and polishing time. Also, the friction at the workpiece/lap interface, the slope of the workpiece relative to the lap plane, and lap viscoelastic properties have been measured and correlated to material removal. The results show that the relative velocity between the workpiece & lap (determined by the kinematics) and the pressure distribution determine the spatial and temporal material removal and hence the final surface figure of the workpiece. In the case where the applied loading and relative velocity distribution over the workpiece are spatially uniform, a significant non-uniform spatial material removal from the workpiece surface is observed. This is due to a non-uniform pressure distribution resulting from: (1) a moment caused by a pivot point and interface friction forces; (2) viscoelastic relaxation of the polyurethane lap; and (3) a physical workpiece/lap interface mismatch. Both the kinematics and these contributions to the pressure distribution are quantitatively described, and then combined to form a spatial and temporal Preston model & code for material removal (called Surface Figure or SurF{copyright}). The surface figure simulations are consistent with the experiment for a wide variety of polishing conditions. This study is an important step towards deterministic full-aperture polishing, which would allow optical glass fabrication to be performed in a more repeatable, less iterative, and hence more economical manner.

  20. High-speed surface temperature measurements on plasma facing materials for fusion applications

    Science.gov (United States)

    Araki, Masanori; Kobayashi, Masanobu

    1996-01-01

    For the lifetime evaluation of plasma facing materials in fusion experimental machines, it is essential to investigate their surface behavior and their temperature responses during an off-normal event such as the plasma disruptions. An infrared thermometer with a sampling speed as fast as 1×10-6 s/data, namely, the high-speed infrared thermometer (HSIR), has been developed by the National Research Laboratory of Metrology in Japan. To evaluate an applicability of the newly developed HSIR on the surface temperature measurement of plasma facing materials, high heat flux beam irradiation experiments have been performed with three different materials under the surface heat fluxes up to 170 MW/m2 for 0.04 s in a hydrogen ion beam test facility at the Japan Atomic Energy Research Institute. As for the results, HSIR can be applicable for measuring the surface temperature responses of the armor tile materials with a little modification. It is also confirmed that surface temperatures measured with the HSIR thermometer show good agreement with the analytical results for stainless steel and carbon based materials at a temperature range of up to 2500 °C. However, for aluminum the HSIR could measure the temperature of the high dense vapor cloud which was produced during the heating due to lower melting temperature. Based on the result, a multichannel arrayed HSIR thermometer has been designed and fabricated.

  1. Statistical investigation of surface bound ions and further development of BION server to include pH and salt dependence.

    Science.gov (United States)

    Petukh, Marharyta; Zhang, Min; Alexov, Emil

    2015-12-15

    Ions are engaged in multiple biological processes in cells. By binding to the macromolecules or being mobile in the solvent, they maintain the integrity of the structure of macromolecules; participate in their enzymatic activity; or screen electrostatic interactions. While experimental methods are not always able to assign the exact location of ions, computational methods are in demand. Although the majority of computational methods are successful in predicting the position of ions buried inside macromolecules, they are less effective in deciphering positions of surface bound ions. Here, we propose the new BION algorithm (http://compbio.clemson.edu/bion_server_ph/) that predicts the location of the surface bound ions. It is more efficient and accurate compared to the previous version since it uses more advanced clustering algorithm in combination with pairing rules. In addition, the BION webserver allows specifying the pH and the salt concentration in predicting ions positions. © 2015 Wiley Periodicals, Inc.

  2. Surface-mediated molecular events in material-induced blood-plasma coagulation

    Science.gov (United States)

    Chatterjee, Kaushik

    Coagulation and thrombosis persist as major impediments associated with the use of blood-contacting medical devices. We are investigating the molecular mechanism underlying material-induced blood-plasma coagulation focusing on the role of the surface as a step towards prospective development of improved hemocompatible biomaterials. A classic observation in hematology is that blood/blood-plasma in contact with clean glass surface clots faster than when in contact with many plastic surfaces. The traditional biochemical theory explaining the underlying molecular mechanism suggests that hydrophilic surfaces, like that of glass, are specific activators of the coagulation cascade because of the negatively-charged groups on the surface. Hydrophobic surfaces are poor procoagulants or essentially "benign" because they lack anionic groups. Further, these negatively-charged surfaces are believed to not only activate blood factor XII (FXII), the key protein in contact activation, but also play a cofactor role in the amplification and propagation reactions that ultimately lead to clot formation. In sharp contrast to the traditional theory, our investigations indicate a need for a paradigm shift in the proposed sequence of contact activation events to incorporate the role of protein adsorption at the material surfaces. These studies have lead to the central hypothesis for this work proposing that protein adsorption to hydrophobic surfaces attenuates the contact activation reactions so that poorly-adsorbent hydrophilic surfaces appear to be stronger procoagulants relative to hydrophobic surfaces. Our preliminary studies measuring the plasma coagulation response of activated FXII (FXIIa) on different model surfaces suggested that the material did not play a cofactor role in the processing of this enzyme dose through the coagulation pathway. Therefore, we focused our efforts on studying the mechanism of initial production of enzyme at the procoagulant surface. Calculations for the

  3. Surface Texture and Optical Properties of Self-Adhering Composite Materials after Toothbrush Abrasion.

    Science.gov (United States)

    Malavasi, Caroline Veiga; Macedo, Elisa Maria; Souza, Karoline da Costa; Rego, Guilherme Ferreira; Schneider, Luis Felipe Jochims; Cavalcante, Larissa Maria

    2015-10-01

    This study evaluated the surface texture and optical properties of two self-adhering composites and a nanofilled composite before and after toothbrush abrasion. Vertise Flow (Kerr), Fusio Liquid (Pentron Clinical) and Filtek Z350 XT (3M ESPE) composites were divided into 3 groups (n = 6). Disks of 12 mm diameter and 2 mm thick were made. All materials were light-cured with a LED light source for 40 seconds. Analyses of surface roughness, gloss retention and color stability were performed 24 hours after light curing and after 20,000 brushing cycles. Data were analyzed with analysis of variance (ANOVA) and Tukey's test (α = 5%). Tukey's test ascertained that toothbrush abrasion resulted in rougher and matte surfaces for all composites tested. Filtek Z350 presented better gloss retention after abrasion. On surface roughness evaluation, there was no statistical difference between Fusio Liquid Dentin and Filtek Z350 resins (p > 0.05). Vertise Flow resin showed better color stability (ΔE), than the other two materials. Nanofilled material presented better gloss retention but it did not produce the best results in aspects related to surface roughness and color stability compared to self-adhering composites. A simulation of degradation process by using toothbrush abrasion produced a rougher and matte surface in all composites tested. The surface texture was not only related to filler's amount present in materials, but also with the organic matrix composition of them. The results suggested that the constant development of new materials, seeking for a technical simplification, seems an innovative attraction for dentist's clinical routine, even though larger studies are necessary to promote to everyone a better understanding and improvement of action and effectiveness of this new class of materials.

  4. Effect of different finishing techniques for restorative materials on surface roughness and bacterial adhesion.

    Science.gov (United States)

    Aykent, Filiz; Yondem, Isa; Ozyesil, Atilla G; Gunal, Solen K; Avunduk, Mustafa C; Ozkan, Semiha

    2010-04-01

    The formation of biofilm and bacterial accumulation on dental materials may lead to the development of gingival inflammation and secondary caries. The purpose of this study was to examine the effect of different surface finishing and polishing methods on surface roughness and the adhesion of S. mutans bacteria to 2 new-generation indirect composite resins, 1 direct composite resin, and 1 ceramic material. Forty specimens (10 x 10 x 2 mm) of each material, indirect composite resins (SR Adoro, Estenia), direct composite resin (Tetric), and a ceramic material (VITABLOCS Mark II), were fabricated. Specimens were divided into 4 groups (n=10) that were treated with 1 of the following 4 surface finishing techniques: diamond rotary cutting instrument, sandpaper discs (Sof-Lex), silicone-carbide rubber points (Shofu), or a felt wheel with diamond paste. Surface roughness was measured with a profilometer. Test specimens were covered with artificial saliva and mucin to produce pellicle. Bacterial suspension (10(9) CFU/ml) was then added to the pellicle-coated specimens, and bacterial adhesion was determined using a confocal laser microscope and image analyzing program. Data were analyzed with 2-way ANOVA, followed by Tukey HSD test, Pearson correlation, and regression analysis (alpha=.05). The highest surface roughness values were recorded in SR Adoro and diamond rotary cutting instrument groups. The lowest vital S. mutans adhesion was seen in the ceramic group and in SR Adoro indirect composite resin (Padhesion to indirect composite resin materials differed from that to ceramic material after surface treatments. A positive correlation was observed between surface roughness and the vital S. mutans adhesion. Copyright 2010 The Editorial Council of the Journal of Prosthetic Dentistry. Published by Mosby, Inc. All rights reserved.

  5. Radioactivity decontamination of materials commonly used as surfaces in general-purpose radioisotope laboratories.

    Science.gov (United States)

    Leonardi, Natalia M; Tesán, Fiorella C; Zubillaga, Marcela B; Salgueiro, María J

    2014-12-01

    In accord with as-low-as-reasonably-achievable and good-manufacturing-practice concepts, the present study evaluated the efficiency of radioactivity decontamination of materials commonly used in laboratory surfaces and whether solvent spills on these materials affect the findings. Four materials were evaluated: stainless steel, a surface comprising one-third acrylic resin and two-thirds natural minerals, an epoxy cover, and vinyl-based multipurpose flooring. Radioactive material was eluted from a (99)Mo/(99m)Tc generator, and samples of the surfaces were control-contaminated with 37 MBq (100 μL) of this eluate. The same procedure was repeated with samples of surfaces previously treated with 4 solvents: methanol, methyl ethyl ketone, acetone, and ethanol. The wet radioactive contamination was allowed to dry and then was removed with cotton swabs soaked in soapy water. The effectiveness of decontamination was defined as the percentage of activity removed per cotton swab, and the efficacy of decontamination was defined as the total percentage of activity removed, which was obtained by summing the percentages of activity in all the swabs required to complete the decontamination. Decontamination using our protocol was most effective and most efficacious for stainless steel and multipurpose flooring. Moreover, treatment with common organic solvents seemed not to affect the decontamination of these surfaces. Decontamination of the other two materials was less efficient and was interfered with by the organic solvents; there was also great variability in the overall results obtained for these other two materials. In expanding our laboratory, it is possible for us to select those surface materials on which our decontamination protocol works best. © 2014 by the Society of Nuclear Medicine and Molecular Imaging, Inc.

  6. Methods of creating solar-reflective nonwhite surfaces and their application to residential roofing materials

    Energy Technology Data Exchange (ETDEWEB)

    Levinson, Ronnen; Berdahl, Paul; Akbari, Hashem [Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Miller, William [Oak Ridge National Laboratory, PO Box 2008, MS6070, Oak Ridge, TN 37831 (United States); Joedicke, Ingo [ISP Mineral Products, Inc., 34 Charles St., Hagerstown, MD 21740 (United States); Reilly, Joseph [American Rooftile Coatings, 250 Viking Avenue, Brea, CA 92821 (United States); Suzuki, Yoshi [MCA Clay Tile, 1985 Sampson Avenue, Corona, CA 92879 (United States); Vondran, Michelle [Steelscape Inc., 1200 Arrow Route, Rancho Cucamonga, CA 91730 (United States)

    2007-02-15

    We describe methods for creating solar-reflective nonwhite surfaces and their application to a wide variety of residential roofing materials, including metal, clay tile, concrete tile, wood, and asphalt shingle. Reflectance in the near-infrared (NIR) spectrum (0.7-2.5{mu}m) is maximized by coloring a topcoat with pigments that weakly absorb and (optionally) strongly backscatter NIR radiation, and by adding an NIR-reflective basecoat (e.g., one colored with titanium dioxide rutile white) if both the topcoat and the substrate weakly reflect NIR radiation. Coated steel and glazed clay-tile roofing products achieved NIR reflectances of up to 0.50 and 0.75, respectively, using only cool topcoats. Gray-cement concrete tiles achieved NIR reflectances as high as 0.60 with coatings colored by NIR-scattering pigments. Such tiles could attain NIR reflectances of up to 0.85 by overlaying a white basecoat with a topcoat colored by NIR-transparent organic pigments. Granule-surfaced asphalt shingles achieved NIR reflectances as high as 0.45 when the granules were covered with a white basecoat and a cool color topcoat. (author)

  7. The Effect of Membrane Material and Surface Pore Size on the Fouling Properties of Submerged Membranes

    Directory of Open Access Journals (Sweden)

    Sungil Jeon

    2016-12-01

    Full Text Available We aimed to investigate the relationship between membrane material and the development of membrane fouling in a membrane bioreactor (MBR using membranes with different pore sizes and hydrophilicities. Batch filtration tests were performed using submerged single hollow fiber membrane ultrafiltration (UF modules with different polymeric membrane materials including cellulose acetate (CA, polyethersulfone (PES, and polyvinylidene fluoride (PVDF with activated sludge taken from a municipal wastewater treatment plant. The three UF hollow fiber membranes were prepared by a non-solvent-induced phase separation method and had similar water permeabilities and pore sizes. The results revealed that transmembrane pressure (TMP increased more sharply for the hydrophobic PVDF membrane than for the hydrophilic CA membrane in batch filtration tests, even when membranes with similar permeabilities and pore sizes were used. PVDF hollow fiber membranes with smaller pores had greater fouling propensity than those with larger pores. In contrast, CA hollow fiber membranes showed good mitigation of membrane fouling regardless of pore size. The results obtained in this study suggest that the surface hydrophilicity and pore size of UF membranes clearly affect the fouling properties in MBR operation when using activated sludge.

  8. New techniques for high-temperature melting measurements in volatile refractory materials via laser surface heating.

    Science.gov (United States)

    Manara, D; Sheindlin, M; Heinz, W; Ronchi, C

    2008-11-01

    An original technique for the measurement of high-temperature phase transitions was implemented based on a laser-heating method, enabling chemically unstable, refractory materials to be melted under controlled conditions. This technique includes two independent but correlated methods: In the first, fast multichannel pyrometry is employed to measure thermograms and spectral emissivity; in the second, a low-power probe laser beam is used for the detection of reflectivity changes induced by phase transitions on the sample surface. The experiments are carried out under medium ( approximately 10(2) kPa) or high ( approximately 10(2) MPa) inert-gas pressures in order to kinetically suppress evaporation in volatile or chemically instable samples. Two models for the simulation of the laser-heating pulses are as well introduced. Some results are presented about the successful application of this technique to the study of the melting behavior of oxides such as UO(2+x), ZrO(2), and their mixed oxides. The method can be extended to a broad class of refractory materials.

  9. Measuring evapotranspiration: comparison of in situ micrometeorological methods including eddy covariance, scintillometer, Bowen ratio, and surface renewal method

    Science.gov (United States)

    Poznikova, G.; Fischer, M.; Orsag, M.; Trnka, M.

    2016-12-01

    Quantifying evapotranspiration (ET) is a challenging task as different methods can induce large discrepancies. Comparisons of various techniques are not rare, however it is demanding to maintain several in situ measurements for longer time. In our study, we aimed to compare four micrometeorological methods measuring ET at relatively large homogeneous area. The study took place on a winter wheat field in Polkovice, the Czech Republic (49°23'42.8"N 17°14'47.3"E) from Jul 1st 2015 until Sep 15th 2015. In the centre of 26-ha experimental field we deployed the eddy covariance (EC) system, the Bowen ratio energy balance (BREB) system, thermocouples for surface renewal technique, and the surface layer scintillometer with 106 m path length. Additionally, we installed the large aperture scintillometer with 617 m path length across the field. Our results showed good agreement of compared methods during the wetter periods of the measurements with slight overestimation of the scintillometry. The BREB method agreed the best with EC. Both scintillometers gave very consistent results throughout the whole measurement period. The EC tended to underestimate other methods. One of potential reasons is energy balance disclosure which reached 27.4 % for the measured period. The surface renewal method showed good potential however, need to be further tested in our conditions. Our experimental locality is one of several we are running as a part of ground based measurement network for ET estimation. Gained results helped us to enhance and optimise our network to ensure effective and reliable data acquisition for future validation of airborne images (satellite based drought monitoring).

  10. Soy-based Polymers for Surface Modification and Interactions with Lignocellulosic Materials

    Science.gov (United States)

    Salas Araujo, Carlos Luis

    Recent environmental concerns about the use of synthetic materials that are often used to maintain our quality of life has triggered a significant amount of research to develop new technologies and to adopt sustainable, bio-based materials. Cellulose, lignin and other plant-derived macromolecules including proteins from soybeans have witnessed recent, renewed interest by the industrial and scientific communities. For example, soybean proteins have been proposed for a variety of applications, including wood adhesives, bio-plastics, composites and functional materials that may include synthetic polymers. Despite its importance in such systems or materials, very little is known about the fundamental nature of the interactions between soy proteins and other polymers. Therefore, this work addresses this issue by a systematic investigation of the interactions between soy proteins with the two most abundant macromolecules in the biosphere, namely, cellulose and lignin and with the most widely used synthetic polymer, polypropylene (PP). The adsorption of the main soy protein globulins, glycinin (11S) and beta-conglycinin (7S), was studied by using ultrathin films of cellulose, lignin and PP (as well as reference silica and organic self-assembled monolayers (SAMs) surfaces) that were used as substrates. The extent and dynamics of adsorption was monitored by using quartz crystal microgravimetry with dissipation (QCM-D), surface plasmon resonance (SPR) as well as complementary techniques including circular dichroism (CD) and atomic force microscopy (AFM). QCM-D experiments indicated that soy protein adsorption was strongly affected by changes in the physicochemical environment. An increased adsorption of glycinin on silica (by 13%) and cellulose (by 89%) was observed with the increased ionic strength of the aqueous solution, from 0 to 0.1 M NaCl. This highlights the relevance of electrostatic interactions in the adsorption process. In contrast, the adsorption of beta

  11. Tribological properties of amorphous alloys and the role of surfaces in abrasive wear of materials

    Science.gov (United States)

    Miyoshi, K.; Buckley, D. H.

    1982-01-01

    The research approach undertaken by the authors relative to the subject, and examples of results from the authors are reviewed. The studies include programs in adhesion, friction, and various wear mechanisms (adhesive and abrasive wear). The materials which have been studied include such ceramic and metallic materials as silicon carbide, ferrites, diamond, and amorphous alloys.

  12. Development of Additive Construction Technologies for Application to Development of Lunar/Martian Surface Structures Using In-Situ Materials

    Science.gov (United States)

    Werkheiser, Niki J.; Fiske, Michael R.; Edmunson, Jennifer E.; Khoshnevis, Berokh

    2015-01-01

    For long-duration missions on other planetary bodies, the use of in situ materials will become increasingly critical. As human presence on these bodies expands, so must the breadth of the structures required to accommodate them including habitats, laboratories, berms, radiation shielding for natural radiation and surface reactors, garages, solar storm shelters, greenhouses, etc. Planetary surface structure manufacturing and assembly technologies that incorporate in situ resources provide options for autonomous, affordable, pre-positioned environments with radiation shielding features and protection from micrometeorites, exhaust plume debris, and other hazards. The ability to use in-situ materials to construct these structures will provide a benefit in the reduction of up-mass that would otherwise make long-term Moon or Mars structures cost prohibitive. The ability to fabricate structures in situ brings with it the ability to repair these structures, which allows for the self-sufficiency and sustainability necessary for long-duration habitation. Previously, under the auspices of the MSFC In-Situ Fabrication and Repair (ISFR) project and more recently, under the jointly-managed MSFC/KSC Additive Construction with Mobile Emplacement (ACME) project, the MSFC Surface Structures Group has been developing materials and construction technologies to support future planetary habitats with in-situ resources. One such additive construction technology is known as Contour Crafting. This paper presents the results to date of these efforts, including development of novel nozzle concepts for advanced layer deposition using this process. Conceived initially for rapid development of cementitious structures on Earth, it also lends itself exceptionally well to the automated fabrication of planetary surface structures using minimally processed regolith as aggregate, and binders developed from in situ materials as well. This process has been used successfully in the fabrication of

  13. Surface effects on tritium diffusion in materials in a radiation environment

    International Nuclear Information System (INIS)

    Caskey, G.R. Jr.

    1975-01-01

    Tritium transport and distribution in a material are controlled by chemical potential and thermal gradients and cross-coupling to impurities and defects. Surfaces influence tritium diffusion by acting as sources and sinks for defects and impurities, and surface films restricting tritium transfer between the solid and surrounding fluids. Radiation directly affects boundary processes such as dissociation or adsorption, may erode a surface film or the surface itself, and introduces defects and impurities into the solid by radiation damage, transmutation, or ion implantation, thereby modifying tritium transport within the solid and its transfer across external interfaces. There have been no definitive investigations of these effects, but their practical significance has been demonstrated in tritium release or absorption studies with stainless steel, Zircaloy, niobium, and other materials. (auth)

  14. The effect of different surface materials on runoff quality in permeable pavement systems.

    Science.gov (United States)

    Li, Haiyan; Li, Zhifei; Zhang, Xiaoran; Li, Zhuorong; Liu, Dongqing; Li, Tanghu; Zhang, Ziyang

    2017-09-01

    To investigate the effect of different permeable pavement surface materials on the removal of pollutants from urban storm-runoff, six commonly surface materials (porous asphalt, porous concrete, cement brick, ceramic brick, sand base brick, and shale brick) were selected in this study and the research was carried out by column experiments. Except the concentrations of total suspended solids (TSS), chemical oxygen demand (COD), ammonia nitrogen (NH 4 -N), nitrate nitrogen (NO 3 -N), total nitrogen (TN), and total phosphorus (TP) in the influent and effluent that were measured, the removal mechanism of pollutants was discussed further. The results indicate that the surface materials influence the removal efficiency of pollutants greatly and have different effects on certain pollutant. Furthermore, the physical interception and adsorption would be the main mechanism for the removal of pollutants from runoff. For example, for all surface materials, the average removal efficiency of TSS is nearly about 90.0% because of physical interception. Due to the amount of iron oxide, the removal efficiency of COD, NO 3 -N, and TN of shale brick was 88.2, 35.1, and 17.5%, respectively. NH 4 -N and TN can be easily removed by porous asphalt due to the high content of organic matter. By lacking of useful adsorption sites, all the surface materials had little effect on the removal of TP from runoff. This research could offer useful guidelines for the better design of permeable pavement system and promote the insight into the removal mechanism of pollutants in permeable pavement system. Graphical abstract Different types of materials for the different types of pollutants in the runoff purification capacity were significantly different, overall, shale brick and porous asphalt Shale bricks and porous asphalt have a better purification effect according to the six kinds of materials.

  15. Inverse gas chromatography as a method for determination of surface properties of binding materials

    Science.gov (United States)

    Yu, Jihai; Lu, Xiaolei; Yang, Chunxia; Du, Baoli; Wang, Shuxian; Ye, Zhengmao

    2017-09-01

    Inverse gas chromatography (IGC) is a promising measurement technique for investigating the surface properties of binding materials, which are the major influence element for the adsorption performance of superplasticizer. In this work, using the IGC method, blast furnace slag (BFS), sulphoaluminate cement (SAC) and portland cement (P·O) are employed to systematically evaluate the corresponding dispersive component (γsd), specific surface free energy (γsab), and acid-base properties. The obtained results show that γsd contributes to a major section of the surface free energy in the three binding materials, suggesting they are of a relatively low polarity. Compared to the two kinds of cements, the BFS possesses the highest dispersive and specific surface free energies (the values are 45.01 mJ/m2 and 11.68 mJ/m2, respectively), and also exhibits a wider distribution range of γsd, indicating their surfaces are heterogeneous. For acid-base properties, the results indicate the surfaces of three samples are basic in nature. In addition, the adsorption investigation shows that per unit surface of BFS adsorbs the most superplasticizer molecules, which indicates the higher surface free energies is beneficial to the superplasticizer adsorption.

  16. [Materiality Analysis of Health Plans Based on Stakeholder Engagement and the Issues Included at ISO 26000:2010].

    Science.gov (United States)

    Moyano Santiago, Miguel Angel; Rivera Lirio, Juana María

    2017-01-18

    Health plans of the Spanish autonomous communities can incorporate sustainable development criteria in its development. There have been no analysis or proposals about development and indicators. The goal is to add a contribution to help build better health plans aimed at sustainable development and help to manage economic, social and environmental impacts of health systems criteria. We used a variation of the RAND/UCLA or modified Delphi technique method. The process consisted of a bibliographical and context matters and issues related to health and social responsibility analysis based on ISO 26000: 2010. A survey by deliberately to a selection of 70 expert members of the identified stakeholders was carried out and a discussion group was held to determine the consensus on the issues addressed in the survey sample. The research was conducted in 2015. From the literature review 33 health issues included in ISO 26000:2010 were obtained. 7 survey proved relevant high consensus, 8 relevance and average consensus and 18 with less relevance and high level of dissent. The expert group excluded 4 of the 18 subjects with less consensus. 29 issues included 33 at work, divided into 7 subjects contained in the guide ISO 26000 of social responsibility, were relevant stakeholders regarding possible inclusion in health plans. Considering the direct relationship published by ISO (International Organization for Standardization) among the issues ISO 26000 and the economic, social and environmental indicators in GRI (Global Reporting Initiative) in its G4 version, a panel with monitoring indicators related to relevant issues were elaborated.

  17. International Materials Research Meeting in the Greater Region: “Current Trends in the Characterisation of Materials and Surface Modification”

    Science.gov (United States)

    2017-10-01

    Preface Dear ladies and gentlemen, On 6th and 7th of April 2017 took place the “International Materials Research Meeting in the Greater Region” at the Saarland University, Saarbrücken, Germany. This meeting corresponded to the 9th EEIGM International Conference on Advanced Materials Research and it was intended as a meeting place for researchers of the Greater Region as well as their partners of the different cooperation activities, like the EEIGM program, the ‘Erasmus Mundus’ Advanced Materials Science and Engineering Master program (AMASE), the ‘Erasmus Mundus’ Doctoral Program in Materials Science and Engineering (DocMASE) and the CREATe-Network. On this meeting, 72 participants from 15 countries and 24 institutions discussed and exchanged ideas on the latest trends in the characterization of materials and surface modifications. Different aspects of the material research of metals, ceramics, polymers and biomaterials were presented. As a conclusion of the meeting, the new astronaut of the European Space Agency Dr. Matthias Maurer, who is an alumni of the Saarland University and the EEIGM, held an exciting presentation about his activities. Following the publication of selected papers of the 2009 meeting in Volume 5 and 2012 meeting in Volume 31 of this journal, it is a great pleasure to present this selection of 9 articles to the readers of the IOP Conference Series: Materials Science and Engineering. The editors are thankful to all of the reviewers for reviewing the papers. Special praise is also given to the sponsors of the conference: European Commission within the program Erasmus Mundus (AMASE and DocMASE), Erasmus+ (AMASE), and Horizon2020 (CREATe-Network, Grant agreement No 644013): the DAAD (Alumni Program), and the German-French University (PhD-Track). List of Author signatures, Conference topics, Organization, Conference impressions and list of the participants are available in this PDF.

  18. Experimental investigation of surface determination process on multi-material components for dimensional computed tomography

    DEFF Research Database (Denmark)

    Borges de Oliveira, Fabrício; Stolfi, Alessandro; Bartscher, Markus

    2016-01-01

    and suitable surface determination settings, limits a better acceptance of CT as a CMS. Moreover, standard CT users are subject to the algorithms and boundary conditions implied by the use of commercial analysis software. In this context, this paper is concerned with the experimental evaluation...... of the influence of surface determination process on multi-material measurements, using functions available in the commercial CT data analysis software Volume Graphics VGStudio Max 2.2.6. Calibrated step gauges made of different materials, i.e. PEEK, PPS, and Al were used as reference standards. The step gauges...... were assembled in such a way as to have different multi-material X-ray absorption ratios. Comparative measurements of mono-material assemblies were performed as well. Different segmentation processes were considered (e.g. ISO-50%, local threshold, region growing, etc.), patch-based bidirectional length...

  19. Prediction of the adhesive behavior of bio-inspired functionally graded materials against rough surfaces

    Directory of Open Access Journals (Sweden)

    Chen Peijian

    2014-06-01

    Full Text Available Roughness effect and adhesion properties are important characteristics to be accessed in the development of functionally graded materials for biological and biomimetic applications, particularly for the hierarchical composition in biomimetic gecko robot. A multi-asperities adhesion model to predict the adhesive forces is presented in this work. The effect of surface roughness and graded material properties, which significantly alter the adhesive strength between contact bodies, can be simultaneously considered in the generalized model. It is found that proper interfacial strength can be controlled by adjusting surface roughness σ / R, graded exponent k and material parameter E*R / Δγ. The results should be helpful in the design of new biomimetic materials and useful in application of micro functional instruments.

  20. Materials surface modification by plasma bombardment under simultaneous erosion and redeposition conditions

    International Nuclear Information System (INIS)

    Hirooka, Y.; Goebel, D.M.; Conn, R.W.

    1986-07-01

    The first in-depth investigation of surface modification of materials by continuous, high-flux argon plasma bombardment under simultaneous erosion and redeposition conditions have been carried out for copper and 304 stainless steel using the PISCES facility. The plasma bombardment conditions are: incident ion flux range from 10 17 to 10 19 ions sec -1 cm -2 , total ion fluence is controlled between 10 19 and 10 22 ions cm -2 , electron temperature range from 5 to 15 eV, and plasma density range from 10 11 to 10 13 cm -3 . The incident ion energy is 100 eV. The sample temperature is between 300 and 700K. Under redeposition dominated conditions, the material erosion rate due to the plasma bombardment is significantly smaller (by a factor up to 10) than that can be expected from the classical ion beam sputtering yield data. It is found that surface morphologies of redeposited materials strongly depend on the plasma bombardment condition. The effect of impurities on surface morphology is elucidated in detail. First-order modelings are implemented to interpret the reduced erosion rate and the surface evolution. Also, fusion related surface properties of redeposited materials such as hydrogen reemission and plasma driven permeation have been characterized

  1. The study of sub-surface damage distributions during grinding process on different abrasion materials

    Science.gov (United States)

    Kuo, Ching-Hsiang; Huang, Chien-Yao; Yu, Zong-Ru; Shu, Shyu-Cheng; Chang, Keng-Shou; Hsu, Wei-Yao

    2017-10-01

    The grinding process is the primary technology for curvature generation (CG) on glass optics. The higher material removal rate (MRR) leads to deeper sub-surface damage (SSD) on lens surface. The SSD must be removed by following lapping and polishing processes to ensure the lens quality. However, these are not an easy and an efficient process to remove the SSD from ground surface directly for aspheric surfaces with tens or hundreds microns departure from bestfit- sphere (BFS). An efficient fabrication procedure for large aspheric departure on glass materials must be considered. We propose 3-step fabrication procedures for aspheric surface with larger departure. 1st step is to generate a specific aspheric surface with depth less than 10 μm of SSD residual. 2nd step is to remove SSD and keep the aspheric form by using Zeeko polisher with higher MRR pad. Final step is to figure and finish the aspheric surface by using QED MRF machine. In this study, we focus on the 1st step to investigate the residual depth of SSD after grinding process on different abrasion materials. The materials of tested part are fused silica, S-NPH2, and S-PHM52. The cross grinding would be configured and depth of SSD/surface roughness would be evaluated in this study. The characteristic of SSD could be observed after etching by confocal microscope. The experimental results show the depth of SSD below 31.1 μm with #400 grinding wheel. And the near 10 μm depth of SSD would be achieved with #1,000 grinding wheel. It means the aspherization polishing on large parts with large departure from best fit sphere would be replaced. The fabrication of large aspheric part would be efficient.

  2. Influence of Energy Beverages on the Surface Texture of Glass lonomer Restorative Materials.

    Science.gov (United States)

    Al-Samadani, Khalid H

    2017-10-01

    The objective of the study was to find whether energy beverages have an erosive effect, leading to a risk in the clinical performance of glass ionomer restorative materials. This study evaluated the influence of energy beverages on the surface texture of glass ionomer restorative materials. Glass ionomer materials used were Ionofil Plus AC, GC EQUIA, and Ketac Molar; energy beverages are Code Red, Red Bull, and Power Horse. Specimens prepared were discs of 8 mm diameter and 3 mm thickness; specimens from each material were evaluated following aging with Code Red, Red Bull, and Power Horse energy beverages. Distilled water was used as a control. The surface roughness (Ra) was assessed by surface scanning interferometry. The surface roughness values (ΔRa and Ra) were measured for each specimen. The data were analyzed statistically using multiple repeated measures [analysis of variance (ANOVA)] and paired data t-test (p glass ionomers with increasing immersion time. Energy beverages have an erosive effect on glass ionomer, which influences the clinical importance of the material; it also has anticarious property because it releases the fluoride.

  3. Effect of Soft Drinks and Fresh Fruit Juice on Surface Roughness of Commonly used Restorative Materials.

    Science.gov (United States)

    Maganur, Prabhadevi; Satish, V; Prabhakar, A R; Namineni, Srinivas

    2015-01-01

    In this in vitro study, the effects of a Cola drink, and fresh fruit juice (citrus) on the surface roughness on flowable composite and resin-modified glass ionomer cement (RMGIC) each was evaluated and compared. Using a brass mold 70 pellets each of flowable composite (Filtek™ Flow) and RMGIC tricure restorative material were prepared according to the manufacturer's instructions. Two groups (groups I and II) were formed containing 30 pellets of each material. Remaining 10 pellets of each restorative material did form the control group [water (group III)]. Experimental group pellets were again divided into three subgroups (mild, moderate and severe) containing 10 pellets each and were kept in plastic containers with 30 ml Cola drink (group I) and fresh fruit juice (group II) respectively. Immersion regime was followed according to M aupome G et al. Baseline and final surface roughness (Ra) value for each pellet was evaluated using a profilometer. Statistical analysis was done with Wilcoxon's signed rank test and analysis of variance (ANOVA) followed by Mann-Whitney test. Results showed that the erosive effect of both Cola drink and fresh fruit juice caused significant surface roughness on both flowable composite and RMGIC restorative materials in the mild, moderate and severe immersion regimes. How to cite this article: Maganur P, Satish V, Prabhakar AR, Namineni S. Effect of Soft Drinks and Fresh Fruit Juice on Surface Roughness of Commonly used Restorative Materials. Int J Clin Pediatr Dent 2015;8(1):1-5.

  4. Shear bond strength of veneering ceramic to coping materials with different pre-surface treatments.

    Science.gov (United States)

    Tarib, Natasya Ahmad; Anuar, Norsamihah; Ahmad, Marlynda

    2016-10-01

    Pre-surface treatments of coping materials have been recommended to enhance the bonding to the veneering ceramic. Little is known on the effect on shear bond strength, particularly with new coping material. The aim of this study was to investigate the shear bond strength of veneering ceramic to three coping materials: i) metal alloy (MA), ii) zirconia oxide (ZO), and iii) lithium disilicate (LD) after various pre-surface treatments. Thirty-two (n = 32) discs were prepared for each coping material. Four pre-surface treatments were prepared for each sub-group (n = 8); a) no treatment or control (C), b) sandblast (SB), c) acid etch (AE), and d) sandblast and acid etch (SBAE). Veneering ceramics were applied to all discs. Shear bond strength was measured with a universal testing machine. Data were analyzed with two-way ANOVA and Tukey's multiple comparisons tests. Mean shear bond strengths were obtained for MA (19.00 ± 6.39 MPa), ZO (24.45 ± 5.14 MPa) and LD (13.62 ± 5.12 MPa). There were statistically significant differences in types of coping material and various pre-surface treatments ( P veneering ceramic to zirconia oxide was higher than metal alloy and lithium disilicate. The highest shear bond strengths were obtained in sandblast and acid etch treatment for zirconia oxide and lithium disilicate groups, and in acid etch treatment for metal alloy group.

  5. Human alveolar macrophage responses to air pollution particulates are associated with insoluble components of coarse material, including particulate endotoxin.

    Science.gov (United States)

    Soukup, J M; Becker, S

    2001-02-15

    Inhalation of particulate matter in the ambient air has been shown to cause pulmonary morbidity and exacerbate asthma. Alveolar macrophage (AM) are essential for effective removal of inhaled particles and microbes in the lower airways. While some particles minimally effect AM function others inhibit antimicrobial activity or cause cytokine and growth factor production leading to inflammation and tissue remodeling. This study has investigated the effects of water soluble (s) and insoluble (is) components of Chapel Hill, North Carolina ambient particulate matter in the size ranges 0.1-2.5 microm (PM2.5) and 2.5-10 microm (PM10) diameter, on human AM IL-6, TNFalpha, and MCP-1 cytokine production and host defense mechanisms including phagocytosis and oxidant production. Cytokines were found to be induced by isPM10 to a much higher extent (>50-fold) than sPM10, which in turn stimulated production better than isPM2.5, while sPM2.5 was inactive. Previous studies have indicated that endotoxin (ETOX) is a component of sPM10 responsible for cytokine production. Here, it is shown that inhibition of isPM10-induced cytokine production was partially achieved with polymyxin B and LPS-binding protein (LBP), but not with a metal chelator, implicating ETOX as a cytokine-inducing moiety also in isPM10. In addition to inducing cytokines, exposure to isPM10, but not the other PM fractions, also inhibited phagocytosis and oxidant generation in response to yeast. This inhibition was ETOX independent. The decrease in host defenses may be the result of apoptosis in the AM population, which was also found to be specifically caused by isPM10. These results show that the functional capacity of AM is selectively modulated by insoluble components of coarse PM, including the biocontaminant ETOX.

  6. A neural network potential energy surface for the F + CH4reaction including multiple channels based on coupled cluster theory.

    Science.gov (United States)

    Chen, Jun; Xu, Xin; Liu, Shu; Zhang, Dong H

    2018-03-22

    We report here a new global and full dimensional potential energy surface (PES) for the F + CH4 reaction. This PES was constructed by using neural networks (NN) fitting to about 99 000 ab initio energies computed at the UCCSD(T)-F12a/aug-cc-pVTZ level of theory, and the correction terms considering the influence of a larger basis set as well as spin-orbit couplings were further implemented with a hierarchial scheme. This PES, covering both the abstraction and substitution channels, has an overall fitting error of 8.24 meV in total, and 4.87 meV for energies within 2.5 eV using a segmented NN fitting method, and is more accurate than the previous PESs.

  7. Surface Modification for Improved Design and Functionality of Nanostructured Materials and Devices

    Science.gov (United States)

    Keiper, Timothy Keiper

    Progress in nanotechnology is trending towards applications which require the integration of soft (organic or biological) and hard (semiconductor or metallic) materials. Many applications for functional nanomaterials are currently being explored, including chemical and biological sensors, flexible electronics, molecular electronics, etc., with researchers aiming to develop new paradigms of nanoelectronics through manipulation of the physical properties by surface treatments. This dissertation focuses on two surface modification techniques important for integration of hard and soft materials: thermal annealing and molecular modification of semiconductors. First, the effects of thermal annealing are investigated directly for their implication in the fundamental understanding of transparent conducting oxides with respect to low resistivity contacts for electronic and optoelectronic applications and the response to environmental stimuli for sensing applications. The second focus of this dissertation covers two aspects of the importance of molecular modification on semiconductor systems. The first of these is the formation of self-assembled monolayers in patterned arrays which leads explicitly to the directed self-assembly of nanostructures. The second aspect concerns the modification of the underlying magnetic properties of the preeminent dilute magnetic semiconductor, manganese-doped gallium arsenide. Tin oxide belongs to a class of materials known as transparent conducting oxides which have received extensive interest due to their sensitivity to environmental stimuli and their potential application in transparent and flexible electronics. Nanostructures composed of SnO2 have been demonstrated as an advantageous material for high performance, point-of-care nanoelectronic sensors, capable of detecting and distinguishing gaseous or biomolecular interactions on unprecedented fast timescales. Through bottom-up fabrication techniques, binary oxide nanobelts synthesized

  8. On thermophysical effects on the surface of functional nanostructured materials obtained with the application of femtosecond laser pulses

    Science.gov (United States)

    Babenko, D. D.; Dmitriev, A. S.; Makarov, P. G.; Mikhailova, I. A.

    2017-11-01

    In recent years, a great scientific and practical interest is caused by functional energy surfaces, modified for certain technological problems. The urgency of the work is to develop promising technologies for thermal and nuclear power engineering, methods for converting solar energy, cooling low-current and high-current electronics devices, energy storage and transport systems on the basis of studying and developing new ways of creating and modifying the functional surfaces of heat exchange and other devices. Modified functional surfaces must have a number of new mechanical and thermophysical properties, including mechanical strength, a new surface morphology for controlling the processes of wetting and spreading working fluids on them, and have high efficiency from the viewpoint of thermohydrodynamic processes of flow and heat and mass transfer of working fluids to them. Among the various ways of modifying surfaces, recently, the method of surface exposure to femtosecond laser pulses (FLI) has become widespread. The technology of femtosecond laser surface treatment (FLPO) of solid materials has shown high efficiency, reliability, high productivity and a huge variety of modification methods. The paper presents new results on the study of thermophysical phenomena - the wetting and spreading of drops of various liquids, the study of the hysteresis of the contact angle, the study of evaporation and boiling processes on functional energy surfaces modified by femtosecond laser pulses. It is shown that in the majority of cases the presence of regular or stochastic nanostructures on the surface leads to a very strong change in the basic properties of the surface, which makes it possible to use such a technology to quickly and efficiently modify and obtain functional energy surfaces for certain predetermined purposes.

  9. Relationship between Surface Properties and In Vitro Drug Release from Compressed Matrix Containing Polymeric Materials with Different Hydrophobicity Degrees

    Directory of Open Access Journals (Sweden)

    Cristhian J. Yarce

    2017-01-01

    Full Text Available This work is the continuation of a study focused on establishing relations between surface thermodynamic properties and in vitro release mechanisms using a model drug (ampicillin trihydrate, besides analyzing the granulometric properties of new polymeric materials and thus establishing the potential to be used in the pharmaceutical field as modified delivery excipients. To do this, we used copolymeric materials derived from maleic anhydride with decreasing polarity corresponding to poly(isobutylene-alt-maleic acid (hydrophilic, sodium salt of poly(maleic acid-alt-octadecene (amphiphilic, poly(maleic anhydride-alt-octadecene (hydrophobic and the reference polymer hydroxyl-propyl-methyl-cellulose (HPMC. Each material alone and in blends underwent spectroscopic characterization by FTIR, thermal characterization by DSC and granulometric characterization using flow and compaction tests. Each tablet was prepared at different polymer ratios of 0%, 10%, 20%, 30% and 40%, and the surface properties were determined, including the roughness by micro-visualization, contact angle and water absorption rate by the sessile drop method and obtaining Wadh and surface free energy (SFE using the semi-empirical models of Young–Dupré and  Owens-Wendt-Rabel-Käelbe (OWRK, respectively. Dissolution profiles were determined simulating physiological conditions in vitro, where the kinetic models of order-zero, order-one, Higuchi and Korsmeyer–Peppas were evaluated. The results showed a strong relationship between the proportion and nature of the polymer to the surface thermodynamic properties and kinetic release mechanism.

  10. Abrasive wear mechanisms and surface layer structure of refractory materials after mechanical working

    International Nuclear Information System (INIS)

    Milman, Y.V.; Lotsko, D.V.

    1989-01-01

    The mechanisms of abrasive wear and surface layer structure formation after different kinds of mechanical working are considered in terms of fracture and plastic deformation mechanisms for various refractory materials. The principles for classification of abrasive wear mechanisms are proposed, the four types of wear mechanisms are distinguished for various combinations of fractures and plastic deformation types. The concept of characteristic deformation temperature t * (knee temperature) is used. Detailed examples are given of investigating the surface layer structures in grinded crystals of sapphire and molybdenum. The amorphisation tendency of the thinnest surface layer while mechanical polishing is discussed separately. 19 refs., 11 figs., 2 tabs. (Author)

  11. Selection Criteria and Methods for Testing Different Surface Materials for Contact Frying Processes

    DEFF Research Database (Denmark)

    Ashokkumar, Saranya

    these coatings are not mechanically stable, they do not tolerate high enough temperatures (above 260⁰ C) to give the right product quality, and the surfaces wear easily calling for regular service of the equipment. The present project concerns an investigation of the possibilities of replacing the widely used......Inner surfaces of industrial process equipment for food are often coated to give the surfaces particular properties with respect to adhesion and cleanability. Existing coating materials (PTFE (Teflon®) or silicone based polymers) suffer from drawbacks when used in contact frying, because...

  12. Anisotropic wetting characteristics versus roughness on machined surfaces of hydrophilic and hydrophobic materials

    International Nuclear Information System (INIS)

    Liang, Yande; Shu, Liming; Natsu, Wataru; He, Fuben

    2015-01-01

    Graphical abstract: - Highlights: • The aim is to investigate the influence of roughness on anisotropic wetting on machined surfaces. • The relationship between roughness and anisotropic wetting is modeled by thermodynamical analysis. • The effect of roughness on anisotropic wetting on hydrophilic materials is stronger than that on hydrophobic materials. • The energy barrier existing in the direction perpendicular to the lay is one of the main reasons for the anisotropic wetting. • The contact angle in the parallel direction is larger than that in the perpendicular direction. - Abstract: Anisotropic wetting of machined surfaces is widely applied in industries which can be greatly affected by roughness and solid's chemical properties. However, there has not been much work on it. A free-energy thermodynamic model is presented by analyzing geometry morphology of machined surfaces (2-D model surfaces), which demonstrates the influence of roughness on anisotropic wetting. It can be concluded that the energy barrier is one of the main reasons for the anisotropic wetting existing in the direction perpendicular to the lay. In addition, experiments in investigating anisotropic wetting, which was characterized by the static contact angle and droplet's distortion, were performed on machined surfaces with different roughness on hydrophilic and hydrophobic materials. The droplet's anisotropy found on machined surfaces increased with mean slope of roughness profile Kr. It indicates that roughness on anisotropic wetting on hydrophilic materials has a stronger effect than that on hydrophobic materials. Furthermore, the contact angles predicted by the model are basically consistent with the experimentally ones

  13. Increased critical current and improved magnetic field response of BSCCO material by surface diffusion of silver

    International Nuclear Information System (INIS)

    Negm, Y.Z.; Zimmerman, G.O.; Powers, R.E.; Eckhardt, K.A.

    1994-01-01

    The authors have developed a procedure of increasing the critical current of BSCCO ceramic superconducting material, the value of the critical current is increased by 30%. Moreover the degradation of the critical current with the applied magnetic field had been decreased. The procedure consists of applying a thin layer of silver to the surface of the conductor. The details of the procedure and the improved performance are discussed. This procedure has great significance for any future application of HTSC materials where high current carrying capacity is necessary. It will therefore be important in the application of HTSC materials to SSC high current leads

  14. Locating critical points on multi-dimensional surfaces by genetic algorithm: test cases including normal and perturbed argon clusters

    Science.gov (United States)

    Chaudhury, Pinaki; Bhattacharyya, S. P.

    1999-03-01

    It is demonstrated that Genetic Algorithm in a floating point realisation can be a viable tool for locating critical points on a multi-dimensional potential energy surface (PES). For small clusters, the standard algorithm works well. For bigger ones, the search for global minimum becomes more efficient when used in conjunction with coordinate stretching, and partitioning of the strings into a core part and an outer part which are alternately optimized The method works with equal facility for locating minima, local as well as global, and saddle points (SP) of arbitrary orders. The search for minima requires computation of the gradient vector, but not the Hessian, while that for SP's requires the information of the gradient vector and the Hessian, the latter only at some specific points on the path. The method proposed is tested on (i) a model 2-d PES (ii) argon clusters (Ar 4-Ar 30) in which argon atoms interact via Lennard-Jones potential, (iii) Ar mX, m=12 clusters where X may be a neutral atom or a cation. We also explore if the method could also be used to construct what may be called a stochastic representation of the reaction path on a given PES with reference to conformational changes in Ar n clusters.

  15. SWRT: A package for semi-analytical solutions of surface wave propagation, including mode conversion, across transversely aligned vertical discontinuities

    Directory of Open Access Journals (Sweden)

    A. Datta

    2018-03-01

    Full Text Available We present a suite of programs that implement decades-old algorithms for computation of seismic surface wave reflection and transmission coefficients at a welded contact between two laterally homogeneous quarter-spaces. For Love as well as Rayleigh waves, the algorithms are shown to be capable of modelling multiple mode conversions at a lateral discontinuity, which was not shown in the original publications or in the subsequent literature. Only normal incidence at a lateral boundary is considered so there is no Love–Rayleigh coupling, but incidence of any mode and coupling to any (other mode can be handled. The code is written in Python and makes use of SciPy's Simpson's rule integrator and NumPy's linear algebra solver for its core functionality. Transmission-side results from this code are found to be in good agreement with those from finite-difference simulations. In today's research environment of extensive computing power, the coded algorithms are arguably redundant but SWRT can be used as a valuable testing tool for the ever evolving numerical solvers of seismic wave propagation. SWRT is available via GitHub (https://github.com/arjundatta23/SWRT.git.

  16. SWRT: A package for semi-analytical solutions of surface wave propagation, including mode conversion, across transversely aligned vertical discontinuities

    Science.gov (United States)

    Datta, Arjun

    2018-03-01

    We present a suite of programs that implement decades-old algorithms for computation of seismic surface wave reflection and transmission coefficients at a welded contact between two laterally homogeneous quarter-spaces. For Love as well as Rayleigh waves, the algorithms are shown to be capable of modelling multiple mode conversions at a lateral discontinuity, which was not shown in the original publications or in the subsequent literature. Only normal incidence at a lateral boundary is considered so there is no Love-Rayleigh coupling, but incidence of any mode and coupling to any (other) mode can be handled. The code is written in Python and makes use of SciPy's Simpson's rule integrator and NumPy's linear algebra solver for its core functionality. Transmission-side results from this code are found to be in good agreement with those from finite-difference simulations. In today's research environment of extensive computing power, the coded algorithms are arguably redundant but SWRT can be used as a valuable testing tool for the ever evolving numerical solvers of seismic wave propagation. SWRT is available via GitHub (https://github.com/arjundatta23/SWRT.git).

  17. Surface roughness of polyvinyl siloxane impression materials following chemical disinfection, autoclave and microwave sterilization.

    Science.gov (United States)

    Al Kheraif, Abdulaziz Abdullah

    2013-05-01

    Autoclave sterilization and microwave sterilization has been suggested as the effective methods for the disinfection of elastomeric impressions, but subjecting elastomeric impressions to extreme temperature may have adverse effects on critical properties of the elastomers. To evaluate the effect of chemical disinfection as well as autoclave and microwave sterilization on the surface roughness of elastomeric impression materials. The surface roughness of five commercially available polyvinyl siloxane impression materials (Coltene President, Affinis Perfect impression, Aquasil, 3M ESPE Express and GC Exafast) were evaluated after subjecting them to chemical disinfection, autoclaving and microwave sterilization using a Talysurf Intra 50 instrument. Twenty specimens from each material were fabricated and divided into four equal groups, three experimental and one control (n=25). The differences in the mean surface roughness between the treatment groups were recorded and statistically analyzed. No statistically significant increase in the surface roughness was observed when the specimens were subjected to chemical disinfection and autoclave sterilization, increase in roughness and discoloration was observed in all the materials when specimens were subjected to microwave sterilization. Chemical disinfection did not have a significant effect but, since it is less effective, autoclave sterilization can be considered effective and autoclaving did not show any specimen discoloration as in microwave sterilization. Microwave sterilization may be considered when impressions are used to make diagnostic casts. A significant increase in surface roughness may produce rougher casts, resulting in rougher tissue surfaces for denture and cast restorations. Autoclave sterilization of vinyl polysiloxane elastomeric impressions for 5 minutes at 134°C at 20 psi may be considered an effective method over chemical disinfection and microwave sterilization, because chemical disinfection does

  18. Repellent materials. Robust self-cleaning surfaces that function when exposed to either air or oil.

    Science.gov (United States)

    Lu, Yao; Sathasivam, Sanjayan; Song, Jinlong; Crick, Colin R; Carmalt, Claire J; Parkin, Ivan P

    2015-03-06

    Superhydrophobic self-cleaning surfaces are based on the surface micro/nanomorphologies; however, such surfaces are mechanically weak and stop functioning when exposed to oil. We have created an ethanolic suspension of perfluorosilane-coated titanium dioxide nanoparticles that forms a paint that can be sprayed, dipped, or extruded onto both hard and soft materials to create a self-cleaning surface that functions even upon emersion in oil. Commercial adhesives were used to bond the paint to various substrates and promote robustness. These surfaces maintained their water repellency after finger-wipe, knife-scratch, and even 40 abrasion cycles with sandpaper. The formulations developed can be used on clothes, paper, glass, and steel for a myriad of self-cleaning applications. Copyright © 2015, American Association for the Advancement of Science.

  19. Measured Properties of Turbulent Premixed Flames for Model Assessment, Including Burning Velocities, Stretch Rates, and Surface Densities (Postprint)

    Science.gov (United States)

    2006-10-01

    conditions was stabilized on a large two-dimensional slot Bunsen burner . It was found that the turbulent burning velocity of Bunsen flames depends...burning velocity of Bunsen flames are inadequate because they should include two additional parameters: mean velocity Ū and burner width W. These...corru- gated) flame with well-defined boundary conditions was stabilized on a large two-dimensional slot Bunsen burner . It was found that the turbulent

  20. Experimental measurements of surface damage and residual stresses in micro-engineered plasma facing materials

    Science.gov (United States)

    Rivera, David; Wirz, Richard E.; Ghoniem, Nasr M.

    2017-04-01

    The thermomechanical damage and residual stresses in plasma-facing materials operating at high heat flux are experimentally investigated. Materials with micro-surfaces are found to be more resilient, when exposed to cyclic high heat flux generated by an arc-jet plasma. An experimental facility, dedicated to High Energy Flux Testing (HEFTY), is developed for testing cyclic heat flux in excess of 10 MW/m2. We show that plastic deformation and subsequent fracture of the surface can be controlled by sample cooling. We demonstrate that W surfaces with micro-pillar type surface architecture have significantly reduced residual thermal stresses after plasma exposure, as compared to those with flat surfaces. X-ray diffraction (XRD) spectra of the W-(110) peak reveal that broadening of the Full Width at Half Maximum (FWHM) for micro-engineered samples is substantially smaller than corresponding flat surfaces. Spectral shifts of XRD signals indicate that residual stresses due to plasma exposure of micro-engineered surfaces build up in the first few cycles of exposure. Subsequent cyclic plasma heat loading is shown to anneal out most of the built-up residual stresses in micro-engineered surfaces. These findings are consistent with relaxation of residual thermal stresses in surfaces with micro-engineered features. The initial residual stress state of highly polished flat W samples is compressive (≈ -1.3 GPa). After exposure to 50 plasma cycles, the surface stress relaxes to -1.0 GPa. Micro-engineered samples exposed to the same thermal cycling show that the initial residual stress state is compressive at (- 250 MPa), and remains largely unchanged after plasma exposure.

  1. X-ray photoelectron spectroscopic depth profilometry of nitrogen implanted in materials for modification of their surface properties

    International Nuclear Information System (INIS)

    Sarkissian, A.H.; Paynter, R.; Stansfield, B.L.

    1996-01-01

    The modification of the surface properties of materials has a wide range of industrial applications. For example, the authors change the electrical characteristics of semiconductors, improve surface hardness, decrease friction, increase resistance to corrosion, improve adhesion, etc. Nitriding is one of the most common processes used in industry for surface treatment. Nitrogen ion implantation is one technique often used to achieve this goal. Ion implantation offers the power to control the deposition profile, and can be achieved by either conventional ion beam implantation or plasma assisted ion implantation. They have used the technique of plasma assisted ion implantation to implant nitrogen in several materials, including titanium, silicon and stainless steel. The plasma source is a surface ECR source developed at INRS-Energie et Materiaux. The depth profile of the implanted ions has been measured by X-ray photoelectron spectroscopy. They have also conducted simulations using the TRIM-95 code to predict the depth profile of the implanted ions. Comparisons of the measured results with those from simulations are used to deduce information regarding the plasma composition and the collisional effects in the plasma. A fast responding, current and voltage measuring circuit with fiber optic links is being developed, which allows more accurate quantitative measurements. Further experiments to study the characteristics of the plasma, and their effects on the characteristics of the implanted surfaces are in progress, and the results are presented at this meeting

  2. Enhancing the antibacterial performance of orthopaedic implant materials by fibre laser surface engineering

    Science.gov (United States)

    Chan, Chi-Wai; Carson, Louise; Smith, Graham C.; Morelli, Alessio; Lee, Seunghwan

    2017-05-01

    Implant failure caused by bacterial infection is extremely difficult to treat and usually requires the removal of the infected components. Despite the severe consequence of bacterial infection, research into bacterial infection of orthopaedic implants is still at an early stage compared to the effort on enhancing osseointegration, wear and corrosion resistance of implant materials. In this study, the effects of laser surface treatment on enhancing the antibacterial properties of commercially pure (CP) Ti (Grade 2), Ti6Al4V (Grade 5) and CoCrMo alloy implant materials were studied and compared for the first time. Laser surface treatment was performed by a continuous wave (CW) fibre laser with a near-infrared wavelength of 1064 nm in a nitrogen-containing environment. Staphylococcus aureus, commonly implicated in infection associated with orthopaedic implants, was used to investigate the antibacterial properties of the laser-treated surfaces. The surface roughness and topography of the laser-treated materials were analysed by a 2D roughness testing and by AFM. The surface morphologies before and after 24 h of bacterial cell culture were captured by SEM, and bacterial viability was determined using live/dead staining. Surface chemistry was analysed by XPS and surface wettability was measured using the sessile drop method. The findings of this study indicated that the laser-treated CP Ti and Ti6Al4V surfaces exhibited a noticeable reduction in bacterial adhesion and possessed a bactericidal effect. Such properties were attributable to the combined effects of reduced hydrophobicity, thicker and stable oxide films and presence of laser-induced nano-features. No similar antibacterial effect was observed in the laser-treated CoCrMo.

  3. Greenhouse gas emissions from beef feedlot surface materials as affected by diet, moisture, temperature, and time

    Science.gov (United States)

    A laboratory study was conducted to measure the effects of diet, moisture, temperature, and time on greenhouse gas (GHG) emissions from feedlot surface materials (FSM). The FSM were collected from open lot, pens where beef cattle were fed either a dry-rolled corn (DRC) diet containing no wet distil...

  4. Effect of finishing/polishing techniques and time on surface roughness of esthetic restorative materials

    Directory of Open Access Journals (Sweden)

    Prashanthi Sampath Madhyastha

    2017-01-01

    Conclusion: It might be concluded that: (i Filtek P90 showed least Ra values followed by < Z100 < Dyract < GIC; (ii immediate (24 h finishing/polishing of materials is better than delayed; and (iii among all these polishing systems, diamond bur–Astropol and Astrobrush showed good surface finish.

  5. Incompletely-Condensed Fluoroalkyl Silsesquioxanes and Derivatives: Precursors for Low Surface Energy Materials (Preprint)

    Science.gov (United States)

    2011-09-13

    controlled functionalization of Fluorinated Polyhedral Oligomeric SilSesquioxanes (F-POSS), which are useful as low surface energy materials for...fluorinated nanobuilding blocks with a controlled level of reactive functionality for the development of new superhydrophobic and oleophobic... structures were subsequently modified with non-fluorinated symmetric and asymmetric dichlorosilanes to produce functionalized F-POSS for applications in

  6. Performance analysis of nitride alternative plasmonic materials for localized surface plasmon applications

    DEFF Research Database (Denmark)

    Guler, U.; Naik, G. V.; Boltasseva, Alexandra

    2012-01-01

    efficiency, which is a generalized form of the well-known scattering efficiency, is a more flexible and useful metric for local-field enhancement applications. We also examine the evolution of the field enhancement from a particle surface to the far-field regime for spherical nanoparticles with varying radii......We consider methods to define the performance metrics for different plasmonic materials to be used in localized surface plasmon applications. Optical efficiencies are shown to be better indicators of performance as compared to approximations in the quasistatic regime. The near-field intensity....... Titanium nitride and zirconium nitride, which were recently suggested as alternative plasmonic materials in the visible and near-infrared ranges, are compared to the performance of gold. In contrast to the results from quasistatic methods, both nitride materials are very good alternatives to the usual...

  7. Adsorption and revaporisation studies on iodine oxide aerosols deposited on containment surface materials in LWR

    Energy Technology Data Exchange (ETDEWEB)

    Tietze, S.; Foreman, M.R.StJ.; Ekberg, C. [Chalmers Univ. of Technology, Goeteborg (Sweden); Kaerkelae, T.; Auvinen, A.; Tapper, U.; Lamminmaeki, S.; Jokiniemi, J. [VTT Technical Research Centre of Finland, Espoo (Finland)

    2012-12-15

    During a hypothetical severe nuclear accident, the radiation field will be very high in the nuclear reactor containment building. As a result gaseous radiolysis products will be formed. Elemental iodine can react in the gaseous phase with ozone to form solid iodine oxide aerosol particles (iodine oxide). Within the AIAS (Adsorption of Iodine oxide Aerosols on Surfaces) project the interactions of iodine oxide (IOx) aerosols with common containment surface materials were investigated. Common surface materials in Swedish and Finnish LWRs are Teknopox Aqua V A paint films and metal surfaces such as Cu, Zn, Al and SS, as well as Pt and Pd surfaces from hydrogen recombiners. Non-radioactive and {sup 131}I labelled iodine oxide aerosols were produced with the EXSI CONT facility from elemental iodine and ozone at VTT Technical Research Centre of Finland. The iodine oxide deposits were analysed with microscopic and spectroscopic measurement techniques to identify the kind of iodine oxide formed and if a chemical conversion on the different surface materials occurs. The revaporisation behaviour of the deposited iodine oxide aerosol particles from the different surface materials was studied under the influence of heat, humidity and gamma irradiation at Chalmers University of Technology, Sweden. Studies on the effects of humidity were performed using the FOMICAG facility, while heat and irradiation experiments were performed in a thermostated heating block and with a gammacell 22 having a dose rate of 14 kGy/h. The revaporisation losses were measured using a HPGe detector. The revaporisated {sup 131}I species from the surfaces were chemically tested for elemental iodine formation. The parameter dominating the degradation of the produced iodine oxide aerosols was humidity. Cu and Zn surfaces were found to react with iodine from the iodine oxide aerosols to form iodides, while no metal iodides were detected for Al and SS samples. Most of the iodine oxide aerosols are assumed to

  8. Effect of polishing systems on stain susceptibility and surface roughness of nanocomposite resin material.

    Science.gov (United States)

    Barakah, Haifa M; Taher, Nadia M

    2014-09-01

    Different polishing systems vary in their effect on reducing surface roughness and stain susceptibility of dental composite resin materials. The purpose of this study was to compare the effect of 3 polishing systems on the stain susceptibility and surface roughness of 2 nanocomposite resins and a microhybrid composite resin. Forty-five disks (2×10 mm) each were fabricated of 2 nanocomposite resins (Filtek Supreme XT and Tetric EvoCeram) and 1 microhybrid composite resin (Z250). Both sides of the disks were wet finished, and 1 side was polished with PoGo, Astropol, or Hi-Shine (n=5). Unpolished surfaces served as controls. The average roughness (Ra, μm) was measured with a profilometer, and the baseline color was recorded with a spectrophotometer. All specimens were incubated while soaking in a staining solution of coffee, green tea, and berry juice for 3 weeks. The color was recorded again, and the data were analyzed with 2-way ANOVA at α=.05 and Tukey multiple comparison tests. All polishing systems improved the staining resistance of Filtek Supreme XT and Z250 but did not affect that of Tetric EvoCeram. The surface color of Filtek Supreme XT was changed significantly and was the smoothest after polishing with PoGo, whereas Hi-Shine produced significantly rougher surfaces but with the lowest color change. Hi-Shine produced the highest color change in Z250. The surface roughness did not differ significantly between the other polishing systems. Tetric EvoCeram showed no significant differences in color change or surface roughness. Staining susceptibility and surface roughness depend mainly on material composition and on the polishing procedures. Polishing improves the staining resistance of composite resins. Nanocomposite resins did not exhibit better staining resistance or surface roughness than microhybrid composite resin. Copyright © 2014 Editorial Council for the Journal of Prosthetic Dentistry. Published by Elsevier Inc. All rights reserved.

  9. Boiling performance and material robustness of modified surfaces with multi scale structures for fuel cladding development

    International Nuclear Information System (INIS)

    Jo, HangJin; Kim, Jin Man; Yeom, Hwasung; Lee, Gi Cheol; Park, Hyun Sun; Kiyofumi, Moriyama; Kim, Moo Hwan; Sridharan, Kumar; Corradini, Michael

    2015-01-01

    Highlights: • We improved boiling performance and material robustness using surface modification. • We combined micro/millimeter post structures and nanoparticles with heat treatments. • Compactly-arranged micrometer posts had improved boiling performance. • CHF increased significantly due to capillary pumping by the deposited NP layers. • Sintering procedure increased mechanical strength of the NP coating surface. - Abstract: By regulating the geometrical characteristics of multi-scale structures and by adopting heat treatment for protective layer of nanoparticles (NPs), we improved critical heat flux (CHF), boiling heat transfer (BHT), and mechanical robustness of the modified surface. We fabricated 1-mm and 100-μm post structures and deposited NPs on the structured surface as a nano-scale structured layer and protective layer at the same time, then evaluated the CHF and BHT and material robustness of the modified surfaces. On the structured surfaces without NPs, the surface with compactly-arranged micrometer posts had improved CHF (118%) and BHT (41%). On the surface with structures on which NPs had been deposited, CHF increased significantly (172%) due to capillary pumping by the deposited NP layers. The heat treatment improved robustness of coating layer in comparison to the one of before heat treatment. In particular, low-temperature sintering increased the hardness of the modified surface by 140%. The increased mechanical strength of the NP coating is attributed to reduction in coating porosity during sintering. The combination of micrometer posts structures and sintered NP coating can increase the safety, efficiency and reliability of advanced nuclear fuel cladding

  10. Pure and Oxidized Copper Materials as Potential Antimicrobial Surfaces for Spaceflight Activities

    Science.gov (United States)

    Hahn, C.; Hans, M.; Hein, C.; Mancinelli, R. L.; Mücklich, F.; Wirth, R.; Rettberg, P.; Hellweg, C. E.; Moeller, R.

    2017-12-01

    Microbial biofilms can lead to persistent infections and degrade a variety of materials, and they are notorious for their persistence and resistance to eradication. During long-duration space missions, microbial biofilms present a danger to crew health and spacecraft integrity. The use of antimicrobial surfaces provides an alternative strategy for inhibiting microbial growth and biofilm formation to conventional cleaning procedures and the use of disinfectants. Antimicrobial surfaces contain organic or inorganic compounds, such as antimicrobial peptides or copper and silver, that inhibit microbial growth. The efficacy of wetted oxidized copper layers and pure copper surfaces as antimicrobial agents was tested by applying cultures of Escherichia coli and Staphylococcus cohnii to these metallic surfaces. Stainless steel surfaces were used as non-inhibitory control surfaces. The production of reactive oxygen species and membrane damage increased rapidly within 1 h of exposure on pure copper surfaces, but the effect on cell survival was negligible even after 2 h of exposure. However, longer exposure times of up to 4 h led to a rapid decrease in cell survival, whereby the survival of cells was additionally dependent on the exposed cell density. Finally, the release of metal ions was determined to identify a possible correlation between copper ions in suspension and cell survival. These measurements indicated a steady increase of free copper ions, which were released indirectly by cells presumably through excreted complexing agents. These data indicate that the application of antimicrobial surfaces in spaceflight facilities could improve crew health and mitigate material damage caused by microbial contamination and biofilm formation. Furthermore, the results of this study indicate that cuprous oxide layers were superior to pure copper surfaces related to the antimicrobial effect and that cell density is a significant factor that influences the time dependence of

  11. Revisiting the Challenges in Fabricating Uniform Coatings with Polyfunctional Molecules on High Surface Energy Materials

    Directory of Open Access Journals (Sweden)

    Stephanie Oyola-Reynoso

    2015-12-01

    Full Text Available Modifying the chemistry of a surface has been widely used to influence interfacial properties of a material or nature of interaction between two materials. This article provides an overview on the role of polyfunctional molecules, specifically silanes, in surface modification of polar surfaces (bearing soft nucleophiles. An emphasis on the mechanism of the reaction in the presence of adsorbed water, where the modifying reagents are hydrolysable, is discussed. To highlight the complexity of the reaction, modification of paper with trichlorosilanes is highlighted. Preparation of hydrophobic cellulosic paper, and structure–property relations under different treatment conditions is used to highlight that a monolayer is not always formed during the surface modification. Gel-formation via step-growth polymerization suggests that at the right monomer:adsorbed water ratio, a monolayer will not form but rather self-assembly driven particle formation will occur leading to a textured surface. The review highlights recent work indicating that the focus on monolayer formation, is at the very least, not always the case but gel formation, with concomitant self-assembly, might be the culprit in understanding challenges associated with the use of polyfunctional molecules in surface modification.

  12. Suitability of dredged material for reclamation of surface-mined land. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Harrison, W.; Van Luik, A.

    1979-12-01

    Eroding ridges of acidic coal-mine spoil in La Salle County, Illinois, were leveled to form a gently-sloped raised plateau. Four test plots were constructed: a control plot and three treatment plots that received a 0.9-m-thick cover of dredged material obtained from the Metropolitan Sanitary District of Greater Chicago. Two treatment plots received lime applications and all plots were seeded with a mixture of grasses. Pressure-vacuum soil water samplers were installed, in duplicate, at two levels in the control plot and at three levels in each treatment plot. The three levels in the treatment plots coincided with dredged material, the dredged-material mine-spoil interface, and the underlying mine spoil. Surface water, soil water, and groundwater were monitored for 29 water-quality parameters for one year. Rainfall, air temperature, runoff, and water-level elevation data were collected also. Detailed analysis of the data indicates that the dredged material used in this study does not adversely affect water quality; it supports abundant plant growth, lessens groundwater contamination, and controls acid runoff. The dredged material is judged to be a suitable material for use in reclamation of surface-mined land.

  13. Surface modification of food contact materials for processing and packaging applications

    Science.gov (United States)

    Barish, Jeffrey A.

    This body of work investigates various techniques for the surface modification of food contact materials for use in food packaging and processing applications. Nanoscale changes to the surface of polymeric food packaging materials enables changes in adhesion, wettability, printability, chemical functionality, and bioactivity, while maintaining desirable bulk properties. Polymer surface modification is used in applications such as antimicrobial or non-fouling materials, biosensors, and active packaging. Non-migratory active packagings, in which bioactive components are tethered to the package, offer the potential to reduce the need for additives in food products while maintaining safety and quality. A challenge in developing non-migratory active packaging materials is the loss of biomolecular activity that can occur when biomolecules are immobilized. Polyethylene glycol (PEG), a biocompatible polymer, is grafted from the surface of ozone treated low-density polyethylene (LDPE) resulting in a surface functionalized polyethylene to which a range of amine-terminated bioactive molecules can be immobilized. The grafting of PEG onto the surface of polymer packaging films is accomplished by free radical graft polymerization, and to covalently link an amine-terminated molecule to the PEG tether, demonstrating that amine-terminated bioactive compounds (such as peptides, enzymes, and some antimicrobials) can be immobilized onto PEG-grafted LDPE in the development of non-migratory active packaging. Fouling on food contact surfaces during food processing has a significant impact on operating efficiency and can promote biofilm development. Processing raw milk on plate heat exchangers results in significant fouling of proteins as well as minerals, and is exacerbated by the wall heating effect. An electroless nickel coating is co-deposited with polytetrafluoroethylene onto stainless steel to test its ability to resist fouling on a pilot plant scale plate heat exchanger. Further

  14. Use of polyamfolit complexes of ethyl-amino-crotonate/acrylic acid with surface-active materials for radionuclide extraction

    International Nuclear Information System (INIS)

    Kabdyrakova, A.M.; Artem'ev, O.I.; Protskij, A.V.; Bimendina, L.A.; Yashkarova, M.G.; Orazzhanova, L.K.

    2005-01-01

    Pentifylline of betaine structure was synthesised on the basis of 3-aminocrotonate and acrylic acid. Polyamfolit composition and its complexes with anionic surface-active material (lauryl sulfate of sodium) were determined. It is revealed that complex formation occurs with [polyamfolit]:[surface active material]=1:1 ratio and is accompanied by significant reduce of system characteristics viscosity. The paper presents results of [polyamfolit]:[surface active material] complex apply experimental investigation for radionuclide directed migration in soil. (author)

  15. Electrochemical Characteristics of Layered Transition Metal Oxide Cathode Materials for Lithium Ion Batteries: Surface, Bulk Behavior, and Thermal Properties.

    Science.gov (United States)

    Tian, Chixia; Lin, Feng; Doeff, Marca M

    2018-01-16

    Layered lithium transition metal oxides, in particular, NMCs (LiNi x Co y Mn z O 2 ) represent a family of prominent lithium ion battery cathode materials with the potential to increase energy densities and lifetime, reduce costs, and improve safety for electric vehicles and grid storage. Our work has focused on various strategies to improve performance and to understand the limitations to these strategies, which include altering compositions, utilizing cation substitutions, and charging to higher than usual potentials in cells. Understanding the effects of these strategies on surface and bulk behavior and correlating structure-performance relationships advance our understanding of NMC materials. This also provides information relevant to the efficacy of various approaches toward ensuring reliable operation of these materials in batteries intended for demanding traction and grid storage applications. In this Account, we start by comparing NMCs to the isostructural LiCoO 2 cathode, which is widely used in consumer batteries. Effects of changing the metal content (Ni, Mn, Co) upon structure and performance of NMCs are briefly discussed. Our early work on the effects of partial substitution of Al, Fe, and Ti for Co on the electrochemical and bulk structural properties is then covered. The original aim of this work was to reduce the Co content (and thus the raw materials cost) and to determine the effect of the substitutions on the electrochemical and bulk structural properties. More recently, we have turned to the application of synchrotron and advanced microscopy techniques to understand both bulk and surface characteristics of the NMCs. Via nanoscale-to-macroscale spectroscopy and atomically resolved imaging techniques, we were able to determine that the surfaces of NMC undergo heterogeneous reconstruction from a layered structure to rock salt under a variety of conditions. Interestingly, formation of rock salt also occurs under abuse conditions. The surface

  16. Fabrication of biomimetic superhydrophobic surface on engineering materials by a simple electroless galvanic deposition method.

    Science.gov (United States)

    Xu, Xianghui; Zhang, Zhaozhu; Yang, Jin

    2010-03-02

    We have reported an easy means in this paper to imitate the "lotus leaf" by constructing a superhydrophobic surface through a process combining both electroless galvanic deposition and self-assembly of n-octadecanethiol. Superhydrophobicity with a static water contact angle of about 169 +/- 2 degrees and a sliding angle of 0 +/- 2 degrees was achieved. Both the surface chemical compositions and morphological structures were analyzed. We have obtained a feather-like surface structure, and the thickness of the Ag film is about 10-30 microm. The stability of the superhydrophobic surface was tested under the following three conditions: (1) pH value from 1 to 13; (2) after freezing treatment at -20 degrees C; (3) at ambient temperature. It shows a notable stability in that the contact angle of the sample still remained higher than 150 degrees in different conditions. It can be concluded that our approach can provide an alternative way to fabricate stable superhydrophobic materials.

  17. A literature review on road surface marking materials and retroreflectivity properties

    Directory of Open Access Journals (Sweden)

    Metin Mutlu Aydın

    2017-10-01

    Full Text Available Urban and rural roads are opened to service after the application of road surface markings in Turkey. However, visibility of these roads reduce or disappear caused by the disrepair in a short time after the construction. These road surface markings have a mission to be a visual guide on behavior of lane utilization of drivers. For this reason, it has crucial importance to prevent traffic accidents. Unfortunately, the necessary importance to road surface markings are not given by the authorities in urban and rural roads of Turkey. Generally, standard road marking paint are used in all roads because of its low price and it loses retroreflectivity performance after short time. As a result of this situation chaos, lane indiscipline and many traffic accidents occur in urban and rural roads. Whereas, many different road painting materials are used such as Epoxy, Methyl Methacrylate, Polyester, Thermoplastic, Polyurea etc. to obtain higher performance and resistance according to different road characteristics and environmental conditions. In the scope of this study, a general information were given about the utilization of different surface marking materials which is used in developed countries effectively. Additionally, a number of recommendations and guidance notes have been provided for road makers and decision authorities wishing to use these materials in Turkey.

  18. The application of surface science in the solution of aircraft materials problems

    International Nuclear Information System (INIS)

    Arnott, D.R.

    1999-01-01

    Full text: There is now a tendency for both commercial and military aircraft to be maintained and operated for several decades. Indeed some of our front-line defence aircraft have programme withdrawal lives approaching half a century. This places significant demands on the materials used in engines and airframes. The properties and performance of the materials can degrade with time leading to an increase in the importance of repair and maintenance technologies. As most materials problems start at a surface or an interface, it is not surprising that surface sensitive tools are used to resolve many degradation problems. In some cases, the resolution of problems can lead to life-enhancing improvements for the aircraft. This paper will examine some of the practical issues in the use of surface analytical tools for the examination and resolution of practical aircraft problems. Illustrations will be drawn from the application of surface analysis in the areas of corrosion, fracture and adhesive bonding. Copyright (1999) Australian X-ray Analytical Association Inc

  19. A tri-continuous mesoporous material with a silica pore wall following a hexagonal minimal surface

    KAUST Repository

    Han, Yu

    2009-04-06

    Ordered porous materials with unique pore structures and pore sizes in the mesoporous range (2-50nm) have many applications in catalysis, separation and drug delivery. Extensive research has resulted in mesoporous materials with one-dimensional, cage-like and bi-continuous pore structures. Three families of bi-continuous mesoporous materials have been made, with two interwoven but unconnected channels, corresponding to the liquid crystal phases used as templates. Here we report a three-dimensional hexagonal mesoporous silica, IBN-9, with a tri-continuous pore structure that is synthesized using a specially designed cationic surfactant template. IBN-9 consists of three identical continuous interpenetrating channels, which are separated by a silica wall that follows a hexagonal minimal surface. Such a tri-continuous mesostructure was predicted mathematically, but until now has not been observed in real materials. © 2009 Macmillan Publishers Limited. All rights reserved.

  20. Dark Material at the Surface of Polar Crater Deposits on Mercury

    Science.gov (United States)

    Neumann, Gregory A.; Cavanaugh, John F.; Sun, Xiaoli; Mazarico, Erwan; Smith, David E.; Zuber, Maria T.; Solomon, Sean C.; Paige, Daid A.

    2012-01-01

    Earth-based radar measurements [1-3] have yielded images of radar-bright material at the poles of Mercury postulated to be near-surface water ice residing in cold traps on the permanently shadowed floors of polar impact craters. The Mercury Laser Altimeter (MLA) on board the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft has now mapped much of the north polar region of Mercury [4] (Fig. 1). Radar-bright zones lie within polar craters or along poleward-facing scarps lying mainly in shadow. Calculations of illumination with respect to solid-body motion [5] show that at least 0.5% of the surface area north of 75deg N lies in permanent shadow, and that most such permanently shadowed regions (PSRs) coincide with radar-bright regions. MLA transmits a 1064-nm-wavelength laser pulse at 8 Hz, timing the leading and trailing edges of the return pulse. MLA can in some cases infer energy and thereby surface reflectance at the laser wavelength from the returned pulses. Surficial exposures of water ice would be optically brighter than the surroundings, but persistent surface water ice would require temperatures over all seasons to remain extremely low (Mercury s eccentric orbit, 3:2 spin-orbit resonance, and near-zero obliquity generally do not support such conditions in all permanently shadowed craters but suggest that water ice buried near the surface ( 1 Gy. We describe measurements of reflectivity derived from MLA pulse returns. These reflectivity data show that surface materials in the shadowed regions are darker than their surroundings, enough to strongly attenuate or extinguish laser returns. Such measurements appear to rule out widespread surface exposures of water ice. We consider explanations for the apparent low reflectivity of these regions involving other types of volatile deposit.

  1. The effect of milling and postmilling procedures on the surface roughness of CAD/CAM materials.

    Science.gov (United States)

    Mota, Eduardo Gonçalves; Smidt, Laura Nunes; Fracasso, Lisiane Martins; Burnett, Luiz Henrique; Spohr, Ana Maria

    2017-11-12

    The aim of this study was to evaluate the surface roughness and analyze the surface topography of five different CAD/CAM ceramics and one CAD/CAM composite resin for CEREC after milling and postmilling procedures. Blocks of the ceramics Mark II, IPS Empress CAD, IPS e.max CAD, Suprinity and Enamic, and blocks of the composite resin Lava Ultimate were milled at CEREC MCXL. Ten flat samples of each material were obtained. The surface roughness (Ra) test was performed before and after milling, crystallization, polishing, and glaze when indicated, followed by SEM and AFM analysis. Data were submitted to one-way ANOVA with repeated measures and the Tukey HSD test (α = 0.05). The milling step significantly increased the roughness of all the tested materials (P CAD and Suprinity) were more suitable to roughness than the other tested materials (P CAD/CAM materials, that is, fully sintered, should be only hand polished. The glaze step can be suppressed resulting in time saving. However, the glaze step in soft-milling lithium disilicate is imperative. © 2017 Wiley Periodicals, Inc.

  2. 3D Surface Profile and Color Stability of Tooth Colored Filling Materials after Bleaching.

    Science.gov (United States)

    Irawan, Bryant Anthony; Irawan, Stacey Natalie; Masudi, Sam'an Malik; Sukminingrum, Ninin; Alam, Mohammad Khursheed

    2015-01-01

    This study aims to evaluate the effects of vital tooth bleaching with carbamide peroxide home bleaching and in-office bleaching on the color stability and 3D surface profile of dental restorative filling materials. Thirty discs (n = 30) measure 6 mm in diameter and 2 mm thick for each of three restorative materials. These are nanofilled composite Filtek Z350 XT, the submicron composite Estelite Σ Quick, and nanofilled glass ionomer Ketac N100 nanoionomer and were fabricated in shade A2. Each group was further divided into three subgroups (n = 10): subgroup A (Opalescence PF), subgroup B (Opalescence Boost in-office bleaching), and subgroup C (distilled water) serving as control. Samples were bleached according to the manufacturer's instructions for a period of two weeks. The Commission Internationale de L'Eclairage (CIE L(*), a(*), b(*)) system was chosen for image processing, while 3D surface profile was tested with atomic force microscopy (AFM). Statistical analyses were performed with the Mann-Whitney tests and Krusal-Wallis with a P value of ≤ 0.05. The three restorative materials showed significant color changes (ΔE); P ≤ 0.05. In diminishing order, the mean color changes recorded were Estelite Σ (3.82 ± 1.6) > Ketac Nano (2.97 ± 1.2) > Filtek Z350 XT (2.25 ± 1.0). However, none of the tested materials showed statistically significant changes in surface roughness; P > 0.05.

  3. Thermal performance of a phase change material on a nickel-plated surface

    International Nuclear Information System (INIS)

    Nurmawati, M.H.; Siow, K.S.; Rasiah, I.J.

    2004-01-01

    Thermal control becomes increasingly vital with IC chips becoming faster and smaller. The need to keep chips within acceptable operating temperatures is a growing challenge. Thermal interface materials (TIM) form the interfaces that improve heat transfer from the heat-generating chip to the heat dissipating thermal solution. One of the most commonly used materials in today's electronics industry is phase change material (PCM). Typically, the heat spreader is a nickel-plated copper surface. The compatibility of the PCM to this surface is crucial to the performance of the TIM. In this paper, we report on the performance of this interface. To that end, an instrument to suitably measure critical parameters, like the apparent and contact thermal resistance of the TIM, is developed according to the ASTM D5470 and calibrated. A brief theory of TIM is described and the properties of the PCM were investigated using the instrument. Thermal resistance measurements were made to investigate the effects of physical parameters like pressure, temperature and supplied power on the thermal performance of the material on nickel-plated surface. Conclusions were drawn on the effectiveness of the interface and their application in IC packages

  4. The surface quality of AWJ cut parts as a function of abrasive material reusing rate

    Science.gov (United States)

    Schnakovszky, C.; Herghelegiu, E.; Radu, M. C.; Tampu, N. C.

    2015-11-01

    Abrasive water jet cutting (AWJ) has been extensively used during the last years to process a large variety of materials since it offers important advantages as a good quality of the processed surface, without heat affected zones, low environmental impact (no emission of dust or other compounds that endanger the health of the user), small induced mechanical stresses etc. The main disadvantage is the high cost of processing (cost of equipment and consumables). In view of this, the effects of reusing the abrasive material on the quality of processed surface are investigated in this paper. Two steel materials were used: OL 37 (S 235) with large applicability in machine building industry and 2P armor steel used in the arms industry. The reusing rate of the garnet abrasive material was: 0%, 20%, 40%, 60%, 80% and 100%. The quality of processed surface was quantified by the following parameters: width at the jet inlet (Li), width at the jet outlet (Lo), inclination angle (α), deviation from perpendicularity (u) and roughness (Ra).

  5. Prediction of material removal rate and surface roughness for wire electrical discharge machining of nickel using response surface methodology

    Directory of Open Access Journals (Sweden)

    Thangam Chinnadurai

    2016-12-01

    Full Text Available This study focuses on investigating the effects of process parameters, namely, Peak current (Ip, Pulse on time (Ton, Pulse off time (Toff, Water pressure (Wp, Wire feed rate (Wf, Wire tension (Wt, Servo voltage (Sv and Servo feed setting (Sfs, on the Material Removal Rate (MRR and Surface Roughness (SR for Wire electrical discharge machining (Wire-EDM of nickel using Taguchi method. Response Surface Methodology (RSM is adopted to evolve mathematical relationships between the wire cutting process parameters and the output variables of the weld joint to determine the welding input parameters that lead to the desired optimal wire cutting quality. Besides, using response surface plots, the interaction effects of process parameters on the responses are analyzed and discussed. The statistical software Mini-tab is used to establish the design and to obtain the regression equations. The developed mathematical models are tested by analysis-of-variance (ANOVA method to check their appropriateness and suitability. Finally, a comparison is made between measured and calculated results, which are in good agreement. This indicates that the developed models can predict the responses accurately and precisely within the limits of cutting parameter being used.

  6. Prediction of material removal rate and surface roughness for wire electrical discharge machining of nickel using response surface methodology

    Energy Technology Data Exchange (ETDEWEB)

    Chinnadurai, T.; Vendan, S.A.

    2016-07-01

    This study focuses on investigating the effects of process parameters, namely, Peak current (Ip), Pulse on time (Ton), Pulse off time (Toff), Water pressure (Wp), Wire feed rate (Wf), Wire tension (Wt), Servo voltage (Sv) and Servo feed setting (Sfs), on the Material Removal Rate (MRR) and Surface Roughness (SR) for Wire electrical discharge machining (Wire-EDM) of nickel using Taguchi method. Response Surface Methodology (RSM) is adopted to evolve mathematical relationships between the wire cutting process parameters and the output variables of the weld joint to determine the welding input parameters that lead to the desired optimal wire cutting quality. Besides, using response surface plots, the interaction effects of process parameters on the responses are analyzed and discussed. The statistical software Mini-tab is used to establish the design and to obtain the regression equations. The developed mathematical models are tested by analysis-of-variance (ANOVA) method to check their appropriateness and suitability. Finally, a comparison is made between measured and calculated results, which are in good agreement. This indicates that the developed models can predict the responses accurately and precisely within the limits of cutting parameter being used. (Author)

  7. Surface modification of traditional and bioresorbable metallic implant materials for improved biocompatibility

    Science.gov (United States)

    Walker, Emily K.

    Due to their strength, elasticity, and durability, a variety of metal alloys are commonly used in medical implants. Traditionally, corrosion-resistant metals have been preferred. These permanent materials can cause negative systemic and local tissue effects in the long-term. Permanent stenting can lead to late-stent thrombosis and in-stent restenosis. Metallic pins and screws for fracture fixation can corrode and fail, cause loss of bone mass, and contribute to inflammation and pain at the implant site, requiring reintervention. Corrodible metallic implants have the potential to prevent many of these complications by providing transient support to the affected tissue, dissolving at a rate congruent with the healing of the tissue. Alloys of iron and manganese (FeMn) exhibit similar fatigue strength, toughness, and elasticity compared with 316L stainless steel, making them very attractive candidates for bioresorbable stents and temporary fracture fixation devices. Much attention in recent years has been given to creating alloys with ideal mechanical properties for various applications. Little work has been done on determining the blood compatibility of these materials or on examining how their surfaces can be improved to improve cell adhesion, however. We examined thethrombogenic response of blood exposed to various resorbable ferrous stent materials through contact with porcine blood. The resorbable materials induced comparable or lower levels of several coagulation factors compared with 316L stainless steel. Little platelet adhesion was observed on any of the tested materials. Endothelialization is an important process after the implantation of a vascular stent, as it prevents damage to the vessel wall that can accelerate neointimal hyperplasia. Micromotion can lead to the formation of fibrous tissue surrounding an orthopedic implant, loosening, and ultimately failure of the implant. Nanoscale features were created on the surfaces of noble metal coatings, silicon

  8. Material discovery by combining stochastic surface walking global optimization with a neural network.

    Science.gov (United States)

    Huang, Si-Da; Shang, Cheng; Zhang, Xiao-Jie; Liu, Zhi-Pan

    2017-09-01

    While the underlying potential energy surface (PES) determines the structure and other properties of a material, it has been frustrating to predict new materials from theory even with the advent of supercomputing facilities. The accuracy of the PES and the efficiency of PES sampling are two major bottlenecks, not least because of the great complexity of the material PES. This work introduces a "Global-to-Global" approach for material discovery by combining for the first time a global optimization method with neural network (NN) techniques. The novel global optimization method, named the stochastic surface walking (SSW) method, is carried out massively in parallel for generating a global training data set, the fitting of which by the atom-centered NN produces a multi-dimensional global PES; the subsequent SSW exploration of large systems with the analytical NN PES can provide key information on the thermodynamics and kinetics stability of unknown phases identified from global PESs. We describe in detail the current implementation of the SSW-NN method with particular focuses on the size of the global data set and the simultaneous energy/force/stress NN training procedure. An important functional material, TiO 2 , is utilized as an example to demonstrate the automated global data set generation, the improved NN training procedure and the application in material discovery. Two new TiO 2 porous crystal structures are identified, which have similar thermodynamics stability to the common TiO 2 rutile phase and the kinetics stability for one of them is further proved from SSW pathway sampling. As a general tool for material simulation, the SSW-NN method provides an efficient and predictive platform for large-scale computational material screening.

  9. Application Of A New Semi-Empirical Model For Forming Limit Prediction Of Sheet Material Including Superposed Loads Of Bending And Shearing

    Science.gov (United States)

    Held, Christian; Liewald, Mathias; Schleich, Ralf; Sindel, Manfred

    2010-06-01

    The use of lightweight materials offers substantial strength and weight advantages in car body design. Unfortunately such kinds of sheet material are more susceptible to wrinkling, spring back and fracture during press shop operations. For characterization of capability of sheet material dedicated to deep drawing processes in the automotive industry, mainly Forming Limit Diagrams (FLD) are used. However, new investigations at the Institute for Metal Forming Technology have shown that High Strength Steel Sheet Material and Aluminum Alloys show increased formability in case of bending loads are superposed to stretching loads. Likewise, by superposing shearing on in plane uniaxial or biaxial tension formability changes because of materials crystallographic texture. Such mixed stress and strain conditions including bending and shearing effects can occur in deep-drawing processes of complex car body parts as well as subsequent forming operations like flanging. But changes in formability cannot be described by using the conventional FLC. Hence, for purpose of improvement of failure prediction in numerical simulation codes significant failure criteria for these strain conditions are missing. Considering such aspects in defining suitable failure criteria which is easy to implement into FEA a new semi-empirical model has been developed considering the effect of bending and shearing in sheet metals formability. This failure criterion consists of the combination of the so called cFLC (combined Forming Limit Curve), which considers superposed bending load conditions and the SFLC (Shear Forming Limit Curve), which again includes the effect of shearing on sheet metal's formability.

  10. Application Of A New Semi-Empirical Model For Forming Limit Prediction Of Sheet Material Including Superposed Loads Of Bending And Shearing

    International Nuclear Information System (INIS)

    Held, Christian; Liewald, Mathias; Schleich, Ralf; Sindel, Manfred

    2010-01-01

    The use of lightweight materials offers substantial strength and weight advantages in car body design. Unfortunately such kinds of sheet material are more susceptible to wrinkling, spring back and fracture during press shop operations. For characterization of capability of sheet material dedicated to deep drawing processes in the automotive industry, mainly Forming Limit Diagrams (FLD) are used. However, new investigations at the Institute for Metal Forming Technology have shown that High Strength Steel Sheet Material and Aluminum Alloys show increased formability in case of bending loads are superposed to stretching loads. Likewise, by superposing shearing on in plane uniaxial or biaxial tension formability changes because of materials crystallographic texture. Such mixed stress and strain conditions including bending and shearing effects can occur in deep-drawing processes of complex car body parts as well as subsequent forming operations like flanging. But changes in formability cannot be described by using the conventional FLC. Hence, for purpose of improvement of failure prediction in numerical simulation codes significant failure criteria for these strain conditions are missing. Considering such aspects in defining suitable failure criteria which is easy to implement into FEA a new semi-empirical model has been developed considering the effect of bending and shearing in sheet metals formability. This failure criterion consists of the combination of the so called cFLC (combined Forming Limit Curve), which considers superposed bending load conditions and the SFLC (Shear Forming Limit Curve), which again includes the effect of shearing on sheet metal's formability.

  11. Use of 3-aminopropyltriethoxysilane deposited from aqueous solution for surface modification of III-V materials

    International Nuclear Information System (INIS)

    Knorr Jr, Daniel B.; Williams, Kristen S.; Baril, Neil F.; Weiland, Conan; Andzelm, Jan W.; Lenhart, Joseph L.; Woicik, Joseph C.; Fischer, Daniel A.; Tidrow, Meimei Z.; Bandara, Sumith V.; Henry, Nathan C.

    2014-01-01

    was high (∼50%) for the thinnest films (∼1 nm), and decreased with increasing film thickness. These results indicate that APTES can indeed be used to form a silane surface layer to cover III-V materials substrates. Such APTES silane layers may prove useful in surface passivation of these materials alone, or as surface functionalizing agents for subsequent covalent binding with polymer overlayers like polyimide

  12. Use of 3-aminopropyltriethoxysilane deposited from aqueous solution for surface modification of III-V materials

    Energy Technology Data Exchange (ETDEWEB)

    Knorr Jr, Daniel B., E-mail: daniel.knorr.civ@mail.mil [U.S. Army Research Laboratory, Aberdeen Proving Ground, MD 21005, United States of America (United States); Williams, Kristen S. [U.S. Army Research Laboratory, Aberdeen Proving Ground, MD 21005, United States of America (United States); Baril, Neil F. [U.S. Army, RDECOM, CERDEC, NVSED, Ft. Belvoir, VA 22060, United States of America (United States); Weiland, Conan [National Institute of Standards and Technology, Gaithersburg, MD 20899, United States of America (United States); Andzelm, Jan W. [U.S. Army Research Laboratory, Aberdeen Proving Ground, MD 21005, United States of America (United States); Lenhart, Joseph L., E-mail: joseph.l.lenhart.civ@mail.mil [U.S. Army Research Laboratory, Aberdeen Proving Ground, MD 21005, United States of America (United States); Woicik, Joseph C.; Fischer, Daniel A. [National Institute of Standards and Technology, Gaithersburg, MD 20899, United States of America (United States); Tidrow, Meimei Z.; Bandara, Sumith V. [U.S. Army, RDECOM, CERDEC, NVSED, Ft. Belvoir, VA 22060, United States of America (United States); Henry, Nathan C. [U.S. Army, RDECOM, CERDEC, NVSED, Ft. Belvoir, VA 22060, United States of America (United States); Corbin Company, Alexandria, VA 22314, United States of America (United States)

    2014-11-30

    the content of ionic nitrogen was high (∼50%) for the thinnest films (∼1 nm), and decreased with increasing film thickness. These results indicate that APTES can indeed be used to form a silane surface layer to cover III-V materials substrates. Such APTES silane layers may prove useful in surface passivation of these materials alone, or as surface functionalizing agents for subsequent covalent binding with polymer overlayers like polyimide.

  13. The Effect of Water Repellent Surface Impregnation on Durability of Cement-Based Materials

    Directory of Open Access Journals (Sweden)

    Peng Zhang

    2017-01-01

    Full Text Available In many cases, service life of reinforced concrete structures is severely limited by chloride penetration until the steel reinforcement or by carbonation of the covercrete. Water repellent treatment on the surfaces of cement-based materials has often been considered to protect concrete from these deteriorations. In this paper, three types of water repellent agents have been applied on the surface of concrete specimens. Penetration profiles of silicon resin in treated concrete have been determined by FT-IR spectroscopy. Water capillary suction, chloride penetration, carbonation, and reinforcement corrosion in both surface impregnated and untreated specimens have been measured. Results indicate that surface impregnation reduced the coefficient of capillary suction of concrete substantially. An efficient chloride barrier can be established by deep impregnation. Water repellent surface impregnation by silanes also can make the process of carbonation action slow. In addition, it also has been concluded that surface impregnation can provide effective corrosion protection to reinforcing steel in concrete with migrating chloride. The improvement of durability and extension of service life for reinforced concrete structures, therefore, can be expected through the applications of appropriate water repellent surface impregnation.

  14. Enterococcus faecalis surface proteins determine its adhesion mechanism to bile drain materials.

    Science.gov (United States)

    Waar, Karola; van der Mei, Henny C; Harmsen, Hermie J M; Degener, John E; Busscher, Henk J

    2002-06-01

    An important step in infections associated with biliary drains is adhesion of micro-organisms to the surface. In this study the role of three surface proteins of Enterococcus faecalis (enterococcal surface protein, aggregation substances 1 and 373) in the adhesion to silicone rubber, fluoro-ethylene-propylene and polyethylene was examined. Four isogenic E. faecalis strains with and without aggregation substances and one strain expressing enterococcal surface protein were used. The kinetics of enterococcal adhesion to the materials was measured in situ in a parallel plate flow chamber. Initial deposition rates were similar for all strains, whereas the presence of surface proteins increased the total number of adhering bacteria. Nearest neighbour analysis demonstrated that enterococci expressing the whole sex-pheromone plasmid encoding aggregation substances 1 or 373 adhered in higher numbers through mechanisms of positive cooperativity, which means that adhesion of bacteria enhances the probability of adhesion of other bacteria near these bacteria. Enterococci with the enterococcal surface protein did not adhere through this mechanism. These findings indicate that the surface proteins of E. faecalis play a key role in the adhesion to bile drains and bile drain associated infections.

  15. Bacillus megaterium mediated mineralization of calcium carbonate as biogenic surface treatment of green building materials.

    Science.gov (United States)

    Dhami, Navdeep Kaur; Reddy, M Sudhakara; Mukherjee, Abhijit

    2013-12-01

    Microbially induced calcium carbonate precipitation is a biomineralization process that has various applications in remediation and restoration of range of building materials. In the present study, calcifying bacteria, Bacillus megaterium SS3 isolated from calcareous soil was applied as biosealant to enhance the durability of low energy, green building materials (soil-cement blocks). This bacterial isolate produced high amounts of urease, carbonic anhydrase, extra polymeric substances and biofilm. The calcium carbonate polymorphs produced by B. megaterium SS3 were analyzed by scanning electron microscopy, confocal laser scanning microscopy, X-ray diffraction and Fourier transmission infra red spectroscopy. These results suggested that calcite is the most predominant carbonate formed by this bacteria followed by vaterite. Application of B. megaterium SS3 as biogenic surface treatment led to 40 % decrease in water absorption, 31 % decrease in porosity and 18 % increase in compressive strength of low energy building materials. From the present investigation, it is clear that surface treatment of building materials by B. megaterium SS3 is very effective and eco friendly way of biodeposition of coherent carbonates that enhances the durability of building materials.

  16. Effects of surface materials on polarimetric-thermal measurements: applications to face recognition.

    Science.gov (United States)

    Short, Nathaniel J; Yuffa, Alex J; Videen, Gorden; Hu, Shuowen

    2016-07-01

    Materials, such as cosmetics, applied to the face can severely inhibit biometric face-recognition systems operating in the visible spectrum. These products are typically made up of materials having different spectral properties and color pigmentation that distorts the perceived shape of the face. The surface of the face emits thermal radiation, due to the living tissue beneath the surface of the skin. The emissivity of skin is approximately 0.99; in comparison, oil- and plastic-based materials, commonly found in cosmetics and face paints, have an emissivity range of 0.9-0.95 in the long-wavelength infrared part of the spectrum. Due to these properties, all three are good thermal emitters and have little impact on the heat transferred from the face. Polarimetric-thermal imaging provides additional details of the face and is also dependent upon the thermal radiation from the face. In this paper, we provide a theoretical analysis on the thermal conductivity of various materials commonly applied to the face using a metallic sphere. Additionally, we observe the impact of environmental conditions on the strength of the polarimetric signature and the ability to recover geometric details. Finally, we show how these materials degrade the performance of traditional face-recognition methods and provide an approach to mitigating this effect using polarimetric-thermal imaging.

  17. Reusable Surface Insulation Tile Thermal Protection Materials: Past, Present and the Future

    Science.gov (United States)

    Leiser, Daniel B.; Stewart, David A.; Venkatapathy, Ethiras (Technical Monitor)

    2002-01-01

    Silica (LI-900) Reusable Surface Insulation (RSI) tile have been used on the majority of the Shuttle since its initial flight. Its overall performance with Reaction Cured Glass (RCG) coating applied will be reviewed. Improvements in insulations, Fibrous Refractory Composite Insulation (FRCI-12) and Alumina Enhanced Thermal Barrier (AETB-8) and coatings/surface treatments such as Toughened Uni-Piece Fibrous Insulation (TUFI) have been developed and successfully applied. The performance of these enhancements on the Shuttle Orbiters over the past few years along with the next version of tile materials, High Efficiency Tantalum-based Ceramic (HETC) with even broader applicability will also be discussed.

  18. Representation of Glossy Material Surface in Ventral Superior Temporal Sulcal Area of Common Marmosets.

    Science.gov (United States)

    Miyakawa, Naohisa; Banno, Taku; Abe, Hiroshi; Tani, Toshiki; Suzuki, Wataru; Ichinohe, Noritaka

    2017-01-01

    The common marmoset ( Callithrix jacchus ) is one of the smallest species of primates, with high visual recognition abilities that allow them to judge the identity and quality of food and objects in their environment. To address the cortical processing of visual information related to material surface features in marmosets, we presented a set of stimuli that have identical three-dimensional shapes (bone, torus or amorphous) but different material appearances (ceramic, glass, fur, leather, metal, stone, wood, or matte) to anesthetized marmoset, and recorded multiunit activities from an area ventral to the superior temporal sulcus (STS) using multi-shanked, and depth resolved multi-electrode array. Out of 143 visually responsive multiunits recorded from four animals, 29% had significant main effect only of the material, 3% only of the shape and 43% of both the material and the shape. Furthermore, we found neuronal cluster(s), in which most cells: (1) showed a significant main effect in material appearance; (2) the best stimulus was a glossy material (glass or metal); and (3) had reduced response to the pixel-shuffled version of the glossy material images. The location of the gloss-selective area was in agreement with previous macaque studies, showing activation in the ventral bank of STS. Our results suggest that perception of gloss is an important ability preserved across wide range of primate species.

  19. Preparation and certification of the Polish reference material Virginia Tobacco Leaves (CTA-VTL-2) for inorganic trace analysis including microanalysis

    International Nuclear Information System (INIS)

    Dybczynski, R.; Polkowska-Motrenko, H.; Samczynski, Z.; Szopa, Z.

    1997-01-01

    A new Polish certified reference material Virginia Tobacco Leaves (CTA-VTL-2) for inorganic trace analysis including microanalysis has been prepared. Certification of the candidate reference material was based on the world-wide interlaboratory comparison in which 60 laboratories from 18 countries, participated using various analytical methods and techniques. Data evaluation performed by means of the new multifunctional software package -SSQC. Recommended values were assigned for 33 and 'information' values for 10 elements, respectively. The validity of 'certified' values was confirmed for several elements using 'very accurate' methods developed in this Laboratory. (author)

  20. Preparation and certification of the Polish reference material Virginia Tobacco Leaves (CTA-VTL-2) for inorganic trace analysis including microanalysis

    Energy Technology Data Exchange (ETDEWEB)

    Dybczynski, R.; Polkowska-Motrenko, H.; Samczynski, Z.; Szopa, Z.

    1997-12-31

    A new Polish certified reference material Virginia Tobacco Leaves (CTA-VTL-2) for inorganic trace analysis including microanalysis has been prepared. Certification of the candidate reference material was based on the world-wide interlaboratory comparison in which 60 laboratories from 18 countries, participated using various analytical methods and techniques. Data evaluation performed by means of the new multifunctional software package -SSQC. Recommended values were assigned for 33 and `information` values for 10 elements, respectively. The validity of `certified` values was confirmed for several elements using `very accurate` methods developed in this Laboratory. (author). 47 refs, 28 figs, 12 tabs.

  1. Night time cooling by ventilation or night sky radiation combined with in-room radiant cooling panels including phase change materials

    DEFF Research Database (Denmark)

    Bourdakis, Eleftherios; Olesen, Bjarne W.; Grossule, Fabio

    constructed at the Technical University of Denmark, where the outside PVT panels are connected through a storage tank to in-room radiant ceiling panels. The radiant ceiling panels include phase change material (PCM) and embedded pipes for circulating water. Due to the phase change material it is possible...... depending on the sky clearness. This cooling power was enough to remove the stored heat and regenerate the ceiling panels. The validation simulation model results related to PCM were close to the corresponding results extracted from the experiment, while the results related to the production of cold water...

  2. A simple approach to measure the surface resistivity of insulating materials

    DEFF Research Database (Denmark)

    Yang, Zhenyu; Wang, Qian

    2011-01-01

    or 250V DC signal. The probe assembly is constructed according to Danish Standard (DS/EN 1149-1:2006). The multi-meter (Agilent 3440 1A 6½) is used to measure the micro voltage over a known resistor which is serially connected with electrodes in the probe assembly. In order to obtain reliable...... for different materials, source voltages, and serially connected resistors. The testing results showed that the developed system and methods can provide a reasonably accurate measurement of surface resistivity of insulating materials in a robust and economic manner....

  3. Fatigue crack growth and fracture mechanics analysis of a working roll surface layer material

    Directory of Open Access Journals (Sweden)

    M. Drobne

    2014-10-01

    Full Text Available Fatigue crack growth and fracture mechanics analysis of a working roll surface layer material is presented in this paper. The research is done on a hot strip mill working roll where High Chromium Steel is used for roll’s shell material. To obtain corresponding parameters, a rectangular single edge notched bend specimens – SENB, according to standard BS 7448, were used. The fatigue crack growth analysis was done on a resonant testing machine with use of special crack gauges, while for fracture mechanics parameters the electro–mechanical testing machine was used.

  4. Heterogeneous catalytic materials solid state chemistry, surface chemistry and catalytic behaviour

    CERN Document Server

    Busca, Guido

    2014-01-01

    Heterogeneous Catalytic Materials discusses experimental methods and the latest developments in three areas of research: heterogeneous catalysis; surface chemistry; and the chemistry of catalysts. Catalytic materials are those solids that allow the chemical reaction to occur efficiently and cost-effectively. This book provides you with all necessary information to synthesize, characterize, and relate the properties of a catalyst to its behavior, enabling you to select the appropriate catalyst for the process and reactor system. Oxides (used both as catalysts and as supports for cata

  5. Surface modification of polymeric materials using ultra low energy electron beam irradiation

    International Nuclear Information System (INIS)

    Oshima, Akihiro; Shiraki, Fumiya; Fujita, Hajime; Washio, Masakazu

    2011-01-01

    An ultra low energy electron beam (UL-EB) was used to irradiate various polymeric materials such as fluorinated polymers and a polyimide under an oxygen-free atmosphere. After the irradiation of the polyimide, the change in the thermal properties was measured by DSC and TGA. The surface modification of fluorinated polymers was demonstrated by use of styrene grafting by the preirradiation grafting method. By the use of UL-EB irradiation it was possible to facilitate styrene monomer grafting onto the surface of fluorinated polymers without losing their material characteristics. Moreover, in the case of the polyimide (Kapton TM ), which has excellent radiation resistance, the glass transition temperature was improved by about 20 o C by irradiation up to 40 MGy within 1 h.

  6. Evaluation of Sulfur 'Concrete' for Use as a Construction Material on the Lunar Surface

    Science.gov (United States)

    Grugel, R. N.

    2008-01-01

    Combining molten sulfur with any number of aggregate materials forms, when solid, a mixture having attributes similar, if not better, to conventional water-based concrete. As a result the use of sulfur "concrete" on Earth is well established, particularly in corrosive environments. Consequently, discovery of troilite (FeS) on the lunar surface prompted numerous scenarios about its reduction to elemental sulfur for use, in combination with lunar regolith, as a potential construction material; not requiring water, a precious resource, for its manufacture is an obvious advantage. However, little is known about the viability of sulfur concrete in an environment typified by extreme temperatures and essentially no atmosphere. The experimental work presented here evaluates the response of pure sulfur and sulfur concrete subjected to laboratory conditions that approach those expected on the lunar surface, the results suggesting a narrow window of application.

  7. Corrosion properties of sealing surface material for RPV under abnormal working conditions

    International Nuclear Information System (INIS)

    Liu Jinhua; Wen Yan; Zhang Xuemei; Hou Songmin; Gong Bin; He Yanchun

    2012-01-01

    Based on the corrosion issue of sealing surface material for RPV in some nuclear projects, the corrosion properties of sealing surface material for RPV under abnormal working conditions were investigated. The corrosion behavior of 308L stainless steel were studied by using autoclave in different contents of Cl - solutions, and these samples were observed and analyzed by means of the metalloscope and Scanning electron microscope (SEM). Results show that no pitting, crevice and stress corrosion occurred, when the content of Cl - was lower than 1 mg/L at the temperatures of 270℃ and the pressure of 5.5 MPa. However, with the increase of the content of Cl - , the susceptibility to pitting, crevice and stress corrosion of 308L was enhanced remarkably. (authors)

  8. Study of Interfacial Interactions Using Thing Film Surface Modification: Radiation and Oxidation Effects in Materials

    Energy Technology Data Exchange (ETDEWEB)

    Sridharan, Kumar; Zhang, Jinsuo

    2014-01-09

    ) multi-scale computational modeling involving first- principle molecular dynamics (FPMD) and coarse-grained dissipative particle dynamics (DPD) approaches to develop theories underlying the evolution and stability of structures and phases. Samples from Tasks 1 to 3 (above) will be rigorously characterized and analyzed using scanning electron microscopy, Auger electron microscopy, x-ray diffraction, Rutherford back scatter spectroscopy, and transmission electron microscopy. Expected outcomes of the experimental work include a quantitative understanding film-substrate interface mixing, evolution of defects and other phases at the interface, interaction of interfaces with defects, and the ability of the Y and Ti films to mitigate irradiation-assisted oxidation.The aforementioned experimental work will be closely coupled with multi-scale molecular dynamics (MD) modeling to understand the reactions at the surface, the transport of oxidant through the thin film, and the stabilities of the deposited thin films under radiation and oxidation. Simulations of materials property changes under conditions of radiation and oxidation require multiple size domains and a different simulation scheme for each of these domains. This will be achieved by coupling the FPMD and coarse-grained kinetic Monte Carlo (KMC). This will enable the comparison of the results of each simulation approach with the experimental results.

  9. Study of Interfacial Interactions Using Thin Film Surface Modification: Radiation and Oxidation Effects in Materials

    International Nuclear Information System (INIS)

    2014-01-01

    ) multi-scale computational modeling involving first- principle molecular dynamics (FPMD) and coarse-grained dissipative particle dynamics (DPD) approaches to develop theories underlying the evolution and stability of structures and phases. Samples from Tasks 1 to 3 (above) will be rigorously characterized and analyzed using scanning electron microscopy, Auger electron microscopy, x-ray diffraction, Rutherford back scatter spectroscopy, and transmission electron microscopy. Expected outcomes of the experimental work include a quantitative understanding film-substrate interface mixing, evolution of defects and other phases at the interface, interaction of interfaces with defects, and the ability of the Y and Ti films to mitigate irradiation-assisted oxidation.The aforementioned experimental work will be closely coupled with multi-scale molecular dynamics (MD) modeling to understand the reactions at the surface, the transport of oxidant through the thin film, and the stabilities of the deposited thin films under radiation and oxidation. Simulations of materials property changes under conditions of radiation and oxidation require multiple size domains and a different simulation scheme for each of these domains. This will be achieved by coupling the FPMD and coarse-grained kinetic Monte Carlo (KMC). This will enable the comparison of the results of each simulation approach with the experimental results.

  10. The use of lightweight aggregate saturated with PCM as a temperature stabilizing material for road surfaces

    International Nuclear Information System (INIS)

    Ryms, Michał; Lewandowski, Witold M.; Klugmann-Radziemska, Ewa; Denda, Hubert; Wcisło, Patrycja

    2015-01-01

    This paper presents the possibility of adding lightweight building aggregates to increase the stability – mechanical as well as thermal – of constructions and road objects. This stability can be achieved through saturating the porous granules of aggregate with a phase-change material (PCM) that allows the accumulation of solar heat. Intense solar radiation, especially during the summer, can cause the asphalt on road surfaces, bridges and parking lots to melt, thus protecting the structure from further overheating. The absence of asphalt layers results in thermal stress and strain conditions causes accelerated wear of road surface. Lightweight aggregate, previously used to reduce the weight of the structures, while maintaining the bearing capacity similar to that offered by conventional concrete structures, thereby gains a new functionality, as a temperature stabilizing material. The paper contains a review of several phase-change materials as well as a study justifying the choice of ceresin, a product of crude oil distillation, as a suitable material for such applications. Information about the aggregate and its possible applications, and a proposed method of saturating the aggregate with ceresin has also been collected and presented. With the help of quantitative research conducted through the use of differential scanning calorimetry, the characteristic of thermodynamic parameters of pure ceresin and expanded clay aggregate (Pollytag) saturated with ceresin was determined. Simulation tests conducted under real conditions on two asphalt surfaces (0.32 × 0.22 × 0.15 m), one of which contained the PCM while the other did not, have shown that even a small addition of ceresin (3% mass relative to the weight of the ground) causes a reduction in surface temperature of about 5 K within the tested temperature range of 318.15–338.15 K. - Highlights: • Road surface overheating on summer days may reach up to 344 K. • Solution against overheating through

  11. Real-Space Imaging of Carrier Dynamics of Materials Surfaces by Second-Generation Four-Dimensional Scanning Ultrafast Electron Microscopy

    KAUST Repository

    Sun, Jingya

    2015-09-14

    In the fields of photocatalysis and photovoltaics, ultrafast dynamical processes, including carrier trapping and recombination on material surfaces, are among the key factors that determine the overall energy conversion efficiency. A precise knowledge of these dynamical events on the nanometer (nm) and femtosecond (fs) scales was not accessible until recently. The only way to access such fundamental processes fully is to map the surface dynamics selectively in real space and time. In this study, we establish a second generation of four-dimensional scanning ultrafast electron microscopy (4D S-UEM) and demonstrate the ability to record time-resolved images (snapshots) of material surfaces with 650 fs and ∼5 nm temporal and spatial resolutions, respectively. In this method, the surface of a specimen is excited by a clocking optical pulse and imaged using a pulsed primary electron beam as a probe pulse, generating secondary electrons (SEs), which are emitted from the surface of the specimen in a manner that is sensitive to the local electron/hole density. This method provides direct and controllable information regarding surface dynamics. We clearly demonstrate how the surface morphology, grains, defects, and nanostructured features can significantly impact the overall dynamical processes on the surface of photoactive-materials. In addition, the ability to access two regimes of dynamical probing in a single experiment and the energy loss of SEs in semiconductor-nanoscale materials will also be discussed.

  12. Bibliographic data on surface processes in particle-material interactions published in Japan, 1986-1987

    International Nuclear Information System (INIS)

    Gesi, Kazuo; Nagai, Siro; Ozawa, Kunio.

    1989-01-01

    Data on surface processes in particle-material interactions for fusion technology have been surveyed and collected over 24 publications which have been published during January, 1986 - December, 1987 in Japan. The bibliographic data in the form of data sheets were sent to the International Data Center in IAEA. This report presents 97 selected data sheets arranged in the order of codes of relevant phenomena. A list of literature is given. (author) 159 refs

  13. Betsy Pugel, Tiny houses: Planetary protection-focused materials selection for spaceflight hardware surfaces

    OpenAIRE

    Schriml, Lynn

    2017-01-01

    Betsy Pugel, National Aeronautics and Space Administration Tiny houses: Planetary protection-focused materials selection for spaceflight hardware surfacesOn October 10-12th, 2017 the Alfred P. Sloan Foundation and The National Academies of Sciences, Engineering and Medicine co-hosting MoBE 2017 (Microbiology of the Built Environment Research and Applications Symposium) at the National Academy of Sciences Building to present the current state-of-the-science in understanding the formation and ...

  14. Study of the Effect of Material Machinability on Quality of Surface Created by Abrasive Water Jet

    Czech Academy of Sciences Publication Activity Database

    Klichová, Dagmar; Klich, Jiří

    2016-01-01

    Roč. 149, č. 149 (2016), s. 177-182 E-ISSN 1877-7058. [International Conference on Manufacturing Engineering and Materials, ICMEM 2016. Nový Smokovec, 06.06.2016-10.06.2016] R&D Projects: GA MŠk(CZ) LO1406 Institutional support: RVO:68145535 Keywords : machinability * surface roughness * abrasive water jet * study of quality * aluminium alloy * optical profilometer Subject RIV: JQ - Machines ; Tools http://www.sciencedirect.com/science/article/pii/S1877705816311614

  15. Teeth and bones: applications of surface science to dental materials and related biomaterials

    Science.gov (United States)

    Jones, F. H.

    2001-05-01

    Recent years have seen a considerable upsurge in publications concerning the surface structure and chemistry of materials with biological or biomedical applications. Within the body, gas-solid interactions become relatively less significant and solid-liquid or solid-solid interfaces dominate, providing new challenges for the surface scientist. The current paper aims to provide a timely review of the use of surface analysis and modification techniques within the biomaterials field. A broad overview of applications in a number of related areas is given with particular attention focusing on those materials commonly encountered in dentistry and oral or maxillofacial implantology. Several specific issues of current interest are discussed. The interaction between synthetic and natural solids, both in the oral environment and elsewhere in the body is important in terms of adhesion, related stresses and strains and ultimately the longevity of a dental restoration, biomedical implant, or indeed the surrounding tissue. Exposure to body fluids, of course, can also affect stability, leading to the degradation or corrosion of materials within the body. Whilst this could potentially be harmful, e.g., if cytotoxic elements are released, it may alternatively provide a route to the preferential release of beneficial substances. Furthermore, in some cases, the controlled disintegration of a biomaterial is desirable, allowing the removal of an implant, e.g., without the need for further surgery. The presence of cells in the immediate bioenvironment additionally complicates the situation. A considerable amount of current research activity is targeted at the development of coatings or surface treatments to encourage tissue growth. If this is to be achieved by stimulating enhanced cell productivity, determination of the relationship between cell function and surface composition is essential.

  16. A new structure for comparing surface passivation materials of GaAs solar cells

    Science.gov (United States)

    Desalvo, Gregory C.; Barnett, Allen M.

    1989-01-01

    The surface recombination velocity (S sub rec) for bare GaAs is typically as high as 10 to the 6th power to 10 to the 7th power cm/sec, which dramatically lowers the efficiency of GaAs solar cells. Early attempts to circumvent this problem by making an ultra thin junction (xj less than .1 micron) proved unsuccessful when compared to lowering S sub rec by surface passivation. Present day GaAs solar cells use an GaAlAs window layer to passivate the top surface. The advantages of GaAlAs in surface passivation are its high bandgap energy and lattice matching to GaAs. Although GaAlAs is successful in reducing the surface recombination velocity, it has other inherent problems of chemical instability (Al readily oxidizes) and ohmic contact formation. The search for new, more stable window layer materials requires a means to compare their surface passivation ability. Therefore, a device structure is needed to easily test the performance of different passivating candidates. Such a test device is described.

  17. A hybrid 3D SEM reconstruction method optimized for complex geologic material surfaces.

    Science.gov (United States)

    Yan, Shang; Adegbule, Aderonke; Kibbey, Tohren C G

    2017-08-01

    Reconstruction methods are widely used to extract three-dimensional information from scanning electron microscope (SEM) images. This paper presents a new hybrid reconstruction method that combines stereoscopic reconstruction with shape-from-shading calculations to generate highly-detailed elevation maps from SEM image pairs. The method makes use of an imaged glass sphere to determine the quantitative relationship between observed intensity and angles between the beam and surface normal, and the detector and surface normal. Two specific equations are derived to make use of image intensity information in creating the final elevation map. The equations are used together, one making use of intensities in the two images, the other making use of intensities within a single image. The method is specifically designed for SEM images captured with a single secondary electron detector, and is optimized to capture maximum detail from complex natural surfaces. The method is illustrated with a complex structured abrasive material, and a rough natural sand grain. Results show that the method is capable of capturing details such as angular surface features, varying surface roughness, and surface striations. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. Accuracy of Implant Position Transfer and Surface Detail Reproduction with Different Impression Materials and Techniques

    Directory of Open Access Journals (Sweden)

    Marzieh Alikhasi

    2016-03-01

    Full Text Available Objectives: The purpose of this study was to compare the accuracy of implant position transfer and surface detail reproduction using two impression techniques and materials.Materials and Methods: A metal model with two implants and three grooves of 0.25, 0.50 and 0.75 mm in depth on the flat superior surface of a die was fabricated. Ten regular-body polyether (PE and 10 regular-body polyvinyl siloxane (PVS impressions with square and conical transfer copings using open tray and closed tray techniques were made for each group. Impressions were poured with type IV stone, and linear and angular displacements of the replica heads were evaluated using a coordinate measuring machine (CMM. Also, accurate reproduction of the grooves was evaluated by a video measuring machine (VMM. These measurements were compared with the measurements calculated on the reference model that served as control, and the data were analyzed with two-way ANOVA and t-test at P= 0.05.Results: There was less linear displacement for PVS and less angular displacement for PE in closed-tray technique, and less linear displacement for PE in open tray technique (P<0.001. Also, the open tray technique showed less angular displacement with the use of PVS impression material. Detail reproduction accuracy was the same in all the groups (P>0.05(.Conclusion: The open tray technique was more accurate using PE, and also both closed tray and open tray techniques had acceptable results with the use of PVS. The choice of impression material and technique made no significant difference in surface detail reproduction.Keywords: Dental Implants; Dental Impression Materials, Dental Impression Technique

  19. Laser-based microstructuring of materials surfaces using low-cost microlens arrays

    Science.gov (United States)

    Nieto, Daniel; Vara, G.; Diez, J. A.; O`Connor, Gerard M.; Arines, Justo; Gómez-Reino, C.; Flores-Arias, M.

    2012-03-01

    Since frictional interactions in microscopically small components are becoming increasingly important for the development of new products for all modern technology, we present a laser-based technique for micro-patterning surfaces of materials using low-cost microlens arrays. The microlens used were fabricated on soda-lime glass using a laser direct-write technique, followed by a thermal treatment into an oven. By combining laser direct-write and the thermal treatment it was possible to obtain high quality elements using a low cost infrared laser widely implemented in industry which makes this technique attractive in comparison with other more expensive methods. The main advantage of using microlens arrays for micropatterning surfaces is the possibility of fabricating a large number of identical structures simultaneously, leading to a highly efficient process. In order to study the capabilities of the microlens fabricated for microstructuring materials, identical structures and arrays of holes were fabricated over a variety of materials, such us, stainless steel, polymer and ceramic. The minimum diameter of the individual microstructure generated at surface is 5 μm. Different nanosecond lasers operating at Infrared, Green and UV were used. The topography and morphology of the elements obtained were determined using a confocal microscope SENSOFAR 2300 Plμ.

  20. Mg Isotope Inter-Laboratory Comparison of Reference Materials from Earth-Surface Low-Temperature Environments

    OpenAIRE

    Shalev, Netta; Farkas, Juraj; Fietzke, Jan; Novak, Martin; Schuessler, Jan A.; Pogge von Strandmann, Philip A.E; Törber, Philip B.

    2018-01-01

    To enable quality control of measurement procedures for determinations of Mg isotope amount ratios, expressed as δ26Mg and δ25Mg values, in Earth-surface studies, the δ26Mg and δ25Mg values of eight reference materials (RMs) were determined by inter-laboratory comparison between five laboratories and considering published data, if available. These matrix RMs, including river water SLRS-5, spring water NIST SRM 1640a, Dead Sea brine DSW-1, dolomites JDo-1 and CRM 512, limestone CRM 513, soil N...

  1. Nanoscale Surface Photovoltage Mapping of 2D Materials and Heterostructures by Illuminated Kelvin Probe Force Microscopy

    KAUST Repository

    Shearer, Melinda J.

    2018-02-01

    Nanomaterials are interesting for a variety of applications, such as optoelectronics and photovoltaics. However, they often have spatial heterogeneity, i.e. composition change or physical change in the topography or structure, which can lead to varying properties that would influence their applications. New techniques must be developed to understand and correlate spatial heterogeneity with changes in electronic properties. Here we highlight the technique of surface photovoltage-Kelvin probe force microscopy (SPV-KFM), which is a modified version of non-contact atomic force microscopy capable of imaging not only the topography and surface potential, but also the surface photovoltage on the nanoscale. We demonstrate its utility in probing monolayer WSe2-MoS2 lateral heterostructures, which form an ultrathin p-n junction promising for photovoltaic and optoelectronic applications. We show surface photovoltage maps highlighting the different photoresponse of the two material regions as a result of the effective charge separation across this junction. Additionally, we study the variations between different heterostructure flakes and emphasize the importance of controlling the synthesis and transfer of these materials to obtain consistent properties and measurements.

  2. Plasma immersion ion implantation for the efficient surface modification of medical materials

    Energy Technology Data Exchange (ETDEWEB)

    Slabodchikov, Vladimir A., E-mail: dipis1991@mail.ru; Borisov, Dmitry P., E-mail: borengin@mail.ru; Kuznetsov, Vladimir M., E-mail: kuznetsov@rec.tsu.ru [National Research Tomsk State University, Tomsk, 634050 (Russian Federation)

    2015-10-27

    The paper reports on a new method of plasma immersion ion implantation for the surface modification of medical materials using the example of nickel-titanium (NiTi) alloys much used for manufacturing medical implants. The chemical composition and surface properties of NiTi alloys doped with silicon by conventional ion implantation and by the proposed plasma immersion method are compared. It is shown that the new plasma immersion method is more efficient than conventional ion beam treatment and provides Si implantation into NiTi surface layers through a depth of a hundred nanometers at low bias voltages (400 V) and temperatures (≤150°C) of the substrate. The research results suggest that the chemical composition and surface properties of materials required for medicine, e.g., NiTi alloys, can be successfully attained through modification by the proposed method of plasma immersion ion implantation and by other methods based on the proposed vacuum equipment without using any conventional ion beam treatment.

  3. Effect of different polishing methods on surface roughness of provisional prosthetic materials.

    Science.gov (United States)

    Tupinambá, Ívian Verena Maia; Giampá, Priscila Couy Corrêa; Rocha, Isadora Almeida Rios; Lima, Emilena Maria Castor Xisto

    2018-01-01

    To evaluate the surface roughness of bis-acrylic and acrylic resins submitted to different methods of polishing. Fifty samples of each provisional restorative material (Structur 2, Protemp 4, Duralay, and Dencrilay) were fabricated (10 mm × 2 mm) and divided into five groups ( n = 10): (1) positive control group - polyester strip; (2) negative control - unpolished; (3) abrasive tips (Exa-Technique-Edenta); (4) goat hair brush and diamond polishing paste; and (5) silicone tips (Enhance). Each material was mixed and polymerized according to manufacturer's instructions. The parameter evaluated was the arithmetic mean of the surface roughness (Ra) determined using the rugosimeter SJ 301 (Mitutoyo, Japan). The data were analyzed with two-way analysis of variance ( post hoc Tukey's test) ( P < 0.05). The lowest surface roughness values (0,22-0,90 μm) were observed in the Group 4 - goat hair brush and diamond paste, while the highest values (1,17-1,44 μm) were found in the Group 5 - silicone tips (enhance), with statistically significant differences between them, except for Dencrilay acrylic resin. There was statistically significant difference between bis-acrylic and acrylic resins in the Groups 1, 2, and 4. Within the limitations of this study, it was concluded that the most effective polishing system was the goat hair brush with diamond paste for both bis-acrylic and acrylic resins. The bis-acrylic resins exhibited significantly smoother surfaces than the acrylic resins.

  4. Surface element segregation and electrical conductivity of lithium layered transition-metal oxide cathode materials

    Science.gov (United States)

    Li, Guohua; Li, Qi; Li, Liping; Fan, Jianming; Ge, Qingqin; Xie, Dongjiu; Zheng, Jing; Li, Guangshe

    2018-01-01

    Surface element segregation and electric conductivity are critical in determining lithium storage ability of given cathode materials, which are poorly understood and not correlated with the structure and overall performance. Here, layered lithium transition-metal oxides, one of the state-of-the-art cathode materials for lithium ion batteries are chosen to study. A serial of LiNixCo1-2xMnxO2 samples were prepared via a solid state reaction and subsequently characterized by XRD in conjunction with structural refinement, XPS depth profiling, and AC impedance spectroscopy. Slightly different expansion rates are observed for lattice parameters (a and c/3) with varying of Ni content, which is attributed to the increase of average metal-ion radius and an increase of eg electron that enhances the columbic repulsion between transition metal and oxygen atoms. XPS depth profiling results show that surface composition is significantly deviated from bulk, in which Ni and Mn atoms tend to enrich in the surface region, while Co element is relatively deficient. Further, surface element segregation is alleviated by the increase of Ni/Mn content. Moreover, increasing the Ni/Mn content also raises the activation energy of bulk conduction.

  5. Comparing Multiple Evapotranspiration-calculating Methods, Including Eddy Covariance and Surface Renewal, Using Empirical Measurements from Alfalfa Fields in the Sacramento-San Joaquin River Delta

    Science.gov (United States)

    Clay, J.; Kent, E. R.; Leinfelder-Miles, M.; Lambert, J. J.; Little, C.; Paw U, K. T.; Snyder, R. L.

    2016-12-01

    Eddy covariance and surface renewal measurements were used to estimate evapotranspiration (ET) over a variety of crop fields in the Sacramento-San Joaquin River Delta during the 2016 growing season. However, comparing and evaluating multiple measurement systems and methods for determining ET was focused upon at a single alfalfa site. The eddy covariance systems included two systems for direct measurement of latent heat flux: one using a separate sonic anemometer and an open path infrared gas analyzer and another using a combined system (Campbell Scientific IRGASON). For these methods, eddy covariance was used with measurements from the Campbell Scientific CSAT3, the LI-COR 7500a, the Campbell Scientific IRGASON, and an additional R.M. Young sonic anemometer. In addition to those direct measures, the surface renewal approach included several energy balance residual methods in which net radiation, ground heat flux, and sensible heat flux (H) were measured. H was measured using several systems and different methods, including using multiple fast-response thermocouple measurements and using the temperatures measured by the sonic anemometers. The energy available for ET was then calculated as the residual of the surface energy balance equation. Differences in ET values were analyzed between the eddy covariance and surface renewal methods, using the IRGASON-derived values of ET as the standard for accuracy.

  6. Effects of materials surface preparation for use in spacecraft potable water storage tanks

    Science.gov (United States)

    Wallace, William T.; Wallace, Sarah L.; Loh, Leslie J.; Kuo, C. K. Mike; Hudson, Edgar K.; Marlar, Tyler J.; Gazda, Daniel B.

    2017-12-01

    Maintaining a safe supply of potable water is of utmost importance when preparing for long-duration spaceflight missions, with the minimization of microbial growth being one major aspect. While biocides, such as ionic silver, historically have been used for microbial control in spaceflight, their effectiveness is sometimes limited due to surface reactions with the materials of the storage containers that reduce their concentrations below the effective range. For the Multi-Purpose Crew Vehicle, the primary wetted materials of the water storage system are stainless steel and a titanium alloy, and ionic silver has been chosen to serve as the biocide. As an attempt to understand what processes might reduce the known losses of silver, different treatment processes were attempted and samples of the wetted materials were tested, individually and together, to determine the relative loss of biocide under representative surface area-to-volume ratios. The results of testing presented here showed that the materials could be treated by a nitric acid rinse or a high-concentration silver spike to reduce the loss of silver and bacterial growth. It was also found that the minimum biocidal concentration could be maintained for over 28 days. These results have pointed to approaches that could be used to successfully maintain silver in spacecraft water systems for long-duration missions.

  7. Selection of replacement material for the failed surface level gauge wire in Hanford waste tanks

    International Nuclear Information System (INIS)

    Anantatmula, R.P.; Pitman, S.G.; Lund, A.L.

    1995-10-01

    Surface level gauges fabricated from AISI Type 316 stainless steel (316) wire failed after only a few weeks of operation in underground storage tanks at the Hanford Site. The wire failure was determined to be due to chloride ion assisted corrosion of the 316 wire. Radiation-induced breakdown of the polyvinyl chloride (PVC) riser liners is suspected to be the primary source of the chloride ions. An extensive literature search followed by expert concurrence was undertaken to select a replacement material for the wire. Platinum (Pt)-20 % Iridium (Ir) alloy was selected as the replacement material from tile candidate materials, P-20% Ir, Pt-1O% Rhodium (Rh), Pt-20%Rh and Hastelloy C-22. The selection was made on the basis of the alloy's immunity towards acidic and basic environments as well as its adequate tensile properties in the fully annealed state

  8. Selection of replacement material for the failed surface level gauge wire in Hanford waste tanks

    Energy Technology Data Exchange (ETDEWEB)

    Anantatmula, R.P. [Westinghouse Hanford Co., Richland, WA (United States); Pitman, S.G.; Lund, A.L. [Pacific Northwest Lab., Richland, WA (United States)

    1995-10-01

    Surface level gauges fabricated from AISI Type 316 stainless steel (316) wire failed after only a few weeks of operation in underground storage tanks at the Hanford Site. The wire failure was determined to be due to chloride ion assisted corrosion of the 316 wire. Radiation-induced breakdown of the polyvinyl chloride (PVC) riser liners is suspected to be the primary source of the chloride ions. An extensive literature search followed by expert concurrence was undertaken to select a replacement material for the wire. Platinum (Pt){minus}20 % Iridium (Ir) alloy was selected as the replacement material from tile candidate materials, P-20% Ir, Pt-1O% Rhodium (Rh), Pt-20%Rh and Hastelloy C-22. The selection was made on the basis of the alloy`s immunity towards acidic and basic environments as well as its adequate tensile properties in the fully annealed state.

  9. The effect of cleaning substances on the surface of denture base material.

    Science.gov (United States)

    Žilinskas, Juozas; Junevičius, Jonas; Česaitis, Kęstutis; Junevičiūtė, Gabrielė

    2013-12-11

    The aim of this study was to evaluate the effect of substances used for hygienic cleaning of dentures on the surface of the denture base material. Meliodent Heat Cure (Heraeus-Kulzer, Germany) heat-polymerized acrylic resin was used to produce plates with all the characteristics of removable denture bases (subsequently, "plates"). Oral-B Complete toothbrushes of various brush head types were fixed to a device that imitated tooth brushing movements; table salt and baking soda (frequently used by patients to improve tooth brushing results), toothpaste ("Colgate Total"), and water were also applied. Changes in plate surfaces were monitored by measuring surface reflection alterations on spectrometry. Measurements were conducted before the cleaning and at 2 and 6 hours after cleaning. No statistically significant differences were found between the 3 test series. All 3 plates used in the study underwent statistically significant (pbaking soda--the total reflection reduction was 4.82 ± 0.1%; among toothbrushes with toothpaste, the hard-type toothbrush had the greatest reflection-reducing effect--4.6 ± 0.05%, while the toothbrush with table salt inflicted the least damage (3.5 ± 0.16%) due to the presence of rounded crystals between the bristles and the resin surface. Toothbrushes with water had a uniform negative effect on the plate surface - 3.8 9 ± 0.07%. All substances used by the patients caused surface abrasion of the denture base material, which reduced the reflection; a hard toothbrush with toothpaste had the greatest abrasive effect, while soft toothbrushes inflicted the least damage.

  10. Nanoscale chemical surface characterization of four different types of dental pulp-capping materials.

    Science.gov (United States)

    Gong, Victor; França, Rodrigo

    2017-03-01

    The surface of any dental pulp-capping material has important implications for its clinical success because it is in direct contact with dental tissue, which influences its cytotoxicity. The aim was to determine the chemical composition of the first atomic layers of four pulp-protection agents because these atoms can initiate the pulp healing process. Biodentine (Septodont), ProRoot MTA (Dentsply), Dycal (Caulk) and TheraCal (Bisco) were prepared (n=5) according to manufacturer recommendations. The chemical surface composition was analyzed using X-ray photoelectron spectroscopy (XPS), and the bulk composition was analyzed by Fourier transform infrared spectroscopy (FTIR), energy-dispersive X-ray spectroscopy (EDX). Both survey and high resolution XPS spectra of the elements detected were obtained, with element-dependent probe depths of 4-5nm; the binding energy scale was normalized to the C1s adventitious carbon peak at 285eV. There was a significant difference between bulk and surface compositions for all the pulp-capping materials. The calcium surface concentrations at 0nm and 70nm were Dycal 7.9% and 15.1%; ProRoot MTA 14.1% and 17%; TheraCal 0% and 3.6%; and Biodentine 17.6% and 33.7%, respectively. Trace amounts of the following elements (<1%) were also found: Ti, S and Zr in Biodentine; Bi in ProRoot MTA and TheraCal; Na, P, Zn and N in Dycal. The XPS results showed that Ca in the surface layer could vary from 0 to 18%, depending on the material. Aliphatic carbons, from the polymerization reactions, especially in Dycal and TheraCal, were found to mask the other components. This study compares, for the first time, the chemical composition of the first atomic layers of four pulp-capping materials. This information is relevant because the interaction between pulpar cells and the material's outermost atomic layer is an important factor for leading the pulpal response. Copyright © 2016 Elsevier Ltd. All rights reserved.

  11. Differentiating pedogenesis from diagenesis in early terrestrial paleoweathering surfaces formed on granitic composition parent materials

    Science.gov (United States)

    Driese, S.G.; Medaris, L.G.; Ren, M.; Runkel, Anthony C.; Langford, R.P.

    2007-01-01

    Unconformable surfaces separating Precambrian crystalline basement and overlying Proterozoic to Cambrian sedimentary rocks provide an exceptional opportunity to examine the role of primitive soil ecosystems in weathering and resultant formation of saprolite (weathered rock retaining rock structure) and regolith (weathered rock without rock structure), but many appear to have been affected by burial diagenesis and hydrothermal fluid flow, leading some researchers to discount their suitability for such studies. We examine one modern weathering profile (Cecil series), four Cambrian paleoweathering profiles from the North American craton (Squaw Creek, Franklin Mountains, Core SQ-8, and Core 4), one Neoproterozoic profile (Sheigra), and one late Paleoproterozoic profile (Baraboo), to test the hypothesis that these paleoweathering profiles do provide evidence of primitive terrestrial weathering despite their diagenetic and hydrothermal overprinting, especially additions of potassium. We employ an integrated approach using (1) detailed thin-section investigations to identify characteristic pedogenic features associated with saprolitization and formation of well-drained regoliths, (2) electron microprobe analysis to identify specific weathered and new mineral phases, and (3) geochemical mass balance techniques to characterize volume changes during weathering and elemental gains and losses of major and minor elements relative to the inferred parent materials. There is strong pedogenic evidence of paleoweathering, such as clay illuviation, sepic-plasmic fabrics, redoximorphic features, and dissolution and alteration of feldspars and mafic minerals to kaolinite, gibbsite, and Fe oxides, as well as geochemical evidence, such as whole-rock losses of Na, Ca, Mg, Si, Sr, Fe, and Mn greater than in modern profiles. Evidence of diagenesis includes net additions of K, Ba, and Rb determined through geochemical mass balance, K-feldspar overgrowths in overlying sandstone sections, and

  12. Failure of heterogeneous materials: Scaling properties of fracture surfaces and implications on models of cracks in disordered media.

    Science.gov (United States)

    Bonamy, Daniel

    2007-03-01

    While there exists a unified theoretical framework - Linear Elastic Fracture Mechanics (LEFM) - to describe the failure of homogeneous materials, understanding and modelling the mechanical properties of heterogeneous media continue to raise significant fundamental challenges. These mechanical properties, observed at the macroscopic scale, result from microscopic processes occurring at the scale of the material. To include these local processes into a statistical description constitutes then a crucial step toward the setup of predictive macroscopic models. Crack surface roughness is a consequence of these local processes. Consequently, many fractography experiments have focussed on their analysis. In this context, it was recently evidenced that, in many materials, fracture surfaces exhibit anisotropic scaling properties reminiscent to interface growth problems, fully characterized by two couples of parameters: The roughness exponents and the characteristic length-scales measured along and perpendicular to the direction of crack growth respectively. While the characteristic length-scales do depend on the considered material, the exponents are surprisingly universal: Two distinct sets of critical exponents are observed whether the surfaces are examined at scales below or above the size of the damaged zone at the crack front. Models of crack growth in disordered media are discussed at the light of these experimental observations. In particular, one can derive a model from LEFM which describe the development of crack roughness as an ``elastic'' manifold creeping in a random media. This approach captures quantitatively the experimental observations performed at length-scales above the size of the process zone. In this approach, the onset of crack propagation can be interpreted as a dynamic phase transition while sub-critical crack growth can be assimilated to thermally-assisted depinning.

  13. Characterization of Surface Properties of Glass Vials Used as Primary Packaging Material for Parenterals.

    Science.gov (United States)

    Ditter, Dominique; Mahler, Hanns-Christian; Roehl, Holger; Wahl, Michael; Huwyler, Joerg; Nieto, Alejandra; Allmendinger, Andrea

    2018-01-10

    The appropriate selection of adequate primary packaging, such as the glass vial, rubber stopper, and crimp cap for parenteral products is of high importance to ensure product stability, microbiological quality (integrity) during storage as well as patient safety. A number of issues can arise when inadequate vial material is chosen, and sole compliance to hydrolytic class I is sometimes not sufficient when choosing a glass vial. Using an appropriate pre-treatment, such as surface modification or coating of the inner vial surface after the vial forming process the glass container quality is often improved and interactions of the formulation with the surface of glass may be minimized. This study aimed to characterize the inner surface of different type I glass vials (Exp33, Exp51, Siliconized, TopLyo TM and Type I plus®) at the nanoscale level. All vials were investigated topographically by colorimetric staining and Scanning Electron Microscopy (SEM). Glass composition of the surface was studied by Time-of-Flight - Secondary Ion Mass Spectrometry (ToF-SIMS) and X-ray Photoelectron Spectroscopy (XPS), and hydrophobicity/hydrophilicity of the inner surface was assessed by dye tests and surface energy measurements. All containers were studied unprocessed, as received from the vendor, i.e. in unwashed and non-depyrogenized condition. Clear differences were found between the different vial types studied. Especially glass vials without further surface modifications, like Exp33 and Exp51 vials, showed significant (I) vial-to-vial variations within one vial lot as well as (II) variations along the vertical axis of a single vial when studying topography and chemical composition. In addition, differences and heterogeneity in surface energy were found within a given tranche (circumferential direction) of Exp51 as well as Type I plus® vials. Most consistent quality was achieved with TopLyo TM vials. The present comprehensive characterization of surface properties of the

  14. 3D Surface Profile and Color Stability of Tooth Colored Filling Materials after Bleaching

    Directory of Open Access Journals (Sweden)

    Bryant Anthony Irawan

    2015-01-01

    Full Text Available This study aims to evaluate the effects of vital tooth bleaching with carbamide peroxide home bleaching and in-office bleaching on the color stability and 3D surface profile of dental restorative filling materials. Thirty discs (n=30 measure 6 mm in diameter and 2 mm thick for each of three restorative materials. These are nanofilled composite Filtek Z350 XT, the submicron composite Estelite Σ Quick, and nanofilled glass ionomer Ketac N100 nanoionomer and were fabricated in shade A2. Each group was further divided into three subgroups (n=10: subgroup A (Opalescence PF, subgroup B (Opalescence Boost in-office bleaching, and subgroup C (distilled water serving as control. Samples were bleached according to the manufacturer’s instructions for a period of two weeks. The Commission Internationale de L’Eclairage (CIE L*, a*, b* system was chosen for image processing, while 3D surface profile was tested with atomic force microscopy (AFM. Statistical analyses were performed with the Mann-Whitney tests and Krusal-Wallis with a P value of ≤0.05. The three restorative materials showed significant color changes (ΔE; P≤0.05. In diminishing order, the mean color changes recorded were Estelite Σ (3.82 ± 1.6 > Ketac Nano (2.97 ± 1.2 > Filtek Z350 XT (2.25 ± 1.0. However, none of the tested materials showed statistically significant changes in surface roughness; P>0.05.

  15. A new surface catalytic model for silica-based thermal protection material for hypersonic vehicles

    Directory of Open Access Journals (Sweden)

    Li Kai

    2015-10-01

    Full Text Available Silica-based materials are widely employed in the thermal protection system for hypersonic vehicles, and the investigation of their catalytic characteristics is crucially important for accurate aerothermal heating prediction. By analyzing the disadvantages of Norman’s high and low temperature models, this paper combines the two models and proposes an eight-reaction combined surface catalytic model to describe the catalysis between oxygen and silica surface. Given proper evaluation of the parameters according to many references, the recombination coefficient obtained shows good agreement with experimental data. The catalytic mechanisms between oxygen and silica surface are then analyzed. Results show that with the increase of the wall temperature, the dominant reaction contributing to catalytic coefficient varies from Langmuir–Hinshelwood (LH recombination (TW  1350 K. The surface coverage of chemisorption areas varies evidently with the dominant reactions in the high temperature (HT range, while the surface coverage of physisorption areas varies within quite low temperature (LT range (TW < 250 K. Recommended evaluation of partial parameters is also given.

  16. A Study on Infrared Emissivity Measurement of Material Surface by Reflection Method

    International Nuclear Information System (INIS)

    Kang, Byung Chul; Kim, Sang Myoung; Choi, Joung Yoon; Kim, Gun Ok

    2010-01-01

    Infrared emissivity is one of the most important factors for the temperature measurement by infrared thermography. Although the infrared emissivity of an object can be measured from the ratio of blackbody and the object, at room temperature it is practically difficult to measure the value due to the background effects. Hence, quantitative reflectance of bare steel plate and the surface of coating was measured by FT-IR spectroscopy and emissivity was calculated from this. The emissivity of polished bare steel surface was from 0.06 to 0.10 and the value for the unpolished bare steel can not be achieved because optical characteristics changes of surface roughness induces erroneous results. Emissivity of transparent paint coated steel was from 0.50 to 0.84. Depends on the IR absorption regions, which is a characteristic value of the coating, emissivity changes. This study suggests surface condition of material, thickness, roughness etcetra are important factor for IR optical characteristics. Emissivity measurement by reflection method is useful technique to be applied for metal and it with coating applied on the surface. The range of experimental errors of temperature can be narrowed by the application of infrared thermography from the measured thermal emissivity

  17. Effect of one-step polishing systems on surface roughness of different flowable restorative materials.

    Science.gov (United States)

    Ozel, Emre; Korkmaz, Yonca; Attar, Nuray; Karabulut, Erdem

    2008-11-01

    The purpose of this study was to investigate the influence of one-step polishing systems on the surface roughness of different flowable composites and a microhybrid composite. A total of 120 disks were fabricated and divided into six groups according to the different composite restorative materials tested (n = 20). Each group was further divided into four subgroups according to the polishing system (n = 5). For the control group, samples were left undisturbed after removal of Mylar strip. For the other three subgroups, samples were polished with PoGo, OptraPol, or Sof-Lex disks. Surface roughness was determined using a profilometer and observed under scanning electron microscope (SEM). Data were analyzed by one-way ANOVA and Duncan's multiple range test. For Tetric Flow, Grandio Flow, Filtek Supreme XT Flow, and Admira Flow, their lowest surface roughness values were obtained in Mylar Strip and PoGo groups. For Compoglass Flow, there were no significant differences between Mylar Strip, PoGo, and OptraPol. For Filtek Z250, the lowest surface roughness value was obtained with Mylar Strip. In light of the surface roughness results obtained, one-step polishing systems seemed to be a good choice for polishing flowable composites.

  18. Surface conjugation of poly (dimethyl siloxane) with itaconic acid-based materials for antibacterial effects

    Science.gov (United States)

    Birajdar, Mallinath S.; Cho, Hyunjoo; Seo, Youngmin; Choi, Jonghoon; Park, Hansoo

    2018-04-01

    Poly (dimethyl siloxane) (PDMS) is widely used in various biomedical applications. However, the PDMS surface is known to cause bacterial adhesion and protein absorption issues due to its high hydrophobicity. Therefore, the development of antibacterial and anti-protein products is necessary to prevent these problems. In this study, to improve its antibacterial property and prevent protein adsorption, PDMS surfaces were conjugated with itaconic acid (IA) and poly (itaconic acid) (PIA) via a chemical method. Additionally, IA and PIA were physically blended with PDMS to compare the antibacterial properties of these materials with those of the chemically conjugated PDMS surfaces. The successful synthesis of the PIA polymer structure was confirmed by proton nuclear magnetic resonance (1H NMR) spectroscopy. The successful conjugation of IA and PIA on PDMS was confirmed by attenuated total reflection-Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), water contact angle measurements, and microbicinchoninic acid (BCA) protein assay analyses. The PDMS surfaces functionalized with IA and PIA by the conjugation method better prevented protein adsorption than the bare PDMS. Therefore, these surface-conjugated PDMS can be used in various biomedical applications.

  19. Improvement of β-TCP/PLLA biodegradable material by surface modification with stearic acid.

    Science.gov (United States)

    Ma, Fengcang; Chen, Sai; Liu, Ping; Geng, Fang; Li, Wei; Liu, Xinkuan; He, Daihua; Pan, Deng

    2016-05-01

    Poly-L-lactide (PLLA) is a biodegradable polymer and used widely. Incorporation of beta tricalcium phosphate (β-TCP) into PLLA can enhance its osteoinductive properties. But the interfacial layer between β-TCP particles with PLLA matrix is easy to be destroyed due to inferior interfacial compatibility of the organic/inorganic material. In this work, a method of β-TCP surface modification with stearic acid was investigated to improve the β-TCP/PLLA biomaterial. The effects of surface modification on the β-TCP were investigated by FTIR, XPS, TGA and CA. It was found that the stearic acid reacted with β-TCP and oxhydryl was formed during the surface modification. Hydrophilicity of untreated or modified β-TCP/PLLA composite was increased by the addition of 10 wt.% β-TCP, but it decreased as the addition amount increased from 10 wt.% to 20 wt.%. Two models were suggested to describe the effect of β-TCP concentration on CA of the composites. Mechanical properties of β-TCP/PLLA composites were tested by bending and tensile tests. Fractures of the composites after mechanical test were observed by SEM. It was found that surface modification with stearic acid improved bending and tensile strengths of the β-TCP/PLLA composites obviously. The SEM results indicated that surface modification decreased the probability of interface debonding between fillers and matrix under load. Copyright © 2016 Elsevier B.V. All rights reserved.

  20. In situ evaluation of surface roughness and micromorphology of temporary soft denture liner materials at different time intervals.

    Science.gov (United States)

    Araújo, Célio U; Basting, Roberta T

    2018-03-01

    To perform an in situ evaluation of surface roughness and micromorphology of two soft liner materials for dentures at different time intervals. The surface roughness of materials may influence the adhesion of micro-organisms and inflammation of the mucosal tissues. The in situ evaluation of surface roughness and the micromorphology of soft liner materials over the course of time may present results different from those of in vitro studies, considering the constant presence of saliva and food, the changes in temperature and the pH level in the oral cavity. Forty-eight rectangular specimens of each of the two soft liner materials were fabricated: a silicone-based material (Mucopren Soft) and an acrylic resin-based material (Trusoft). The specimens were placed in the dentures of 12 participants (n = 12), and the materials were evaluated for surface roughness and micromorphology at different time intervals: 0, 7, 30 and 60 days. Roughness (Ra) was evaluated by means of a roughness tester. Surface micromorphology was evaluated by scanning electron microscopy. Analysis of variance for randomised block design and Tukey's test showed that surface roughness values were lower in the groups using the silicone-based material at all the time intervals (P < .0001). The average surface roughness was higher at time interval 0 than at the other intervals, for both materials (P < .0001). The surface micromorphology showed that the silicone material presented a more regular and smoother surface than the acrylic resin-based material. The surface roughness of acrylic resin-based and silicone-based denture soft liner materials decreased after 7 days of evaluation, leading to a smoother surface over time. The silicone-based material showed lower roughness values and a smoother surface than the acrylic resin-based material, thereby making it preferred when selecting more appropriate material, due its tendency to promote less biofilm build-up. © 2017 John Wiley & Sons A/S and The

  1. Effect of Surface Treatment on Performance of Electrode Material Based on Carbon Fiber Cloth

    Directory of Open Access Journals (Sweden)

    XU Jian

    2018-01-01

    Full Text Available The carbon fiber cloth was treated by surface treatment, and then it was used as the electrode substrate. The electrode material based on carbon fibers was synthesized by a galvanostatic electrodeposition method. The interface resistivity, electrochemical property and corrosion resistance of the CF/β-PbO2 electrode were characterized by four-probe method and electrochemical workstation, respectively. The results show that the surface roughness and chemical activity of the carbon fibers can be significantly improved through surface treatment. The carbon fibers possess the best chemical activity on the surface at the hot-air oxidation temperature of 400℃. Joint hot-air and liquid-phase oxidations show that the chemical activity of the carbon fibers on the surface is further improved, the grooves and pits on the surface of the carbon fibers are more obvious, after this treatment, the interface resistivity of the CF/β-PbO2 electrode reaches the minimum value of 6.19×10-5Ω·m, meanwhile, the conductivity and the electrochemical property of the CF/β-PbO2 electrode reaches the best, and with the best corrosion resistance, the corrosion rate is only 1.44×10-3g·cm-2·h-1.Thus, the interface resistivity, electrochemical property and corrosion resistance of the CF/β-PbO2 electrode depend on the the interface structure of the CF/β-PbO2 electrode obtained under different surface treatments.

  2. Factors affecting the wettability of different surface materials with vegetable oil at high temperatures and its relation to cleanability

    DEFF Research Database (Denmark)

    Ashokkumar, Saranya; Adler-Nissen, Jens; Møller, Per

    2012-01-01

    The main aim of the work was to investigate the wettability of different surface materials with vegetable oil (olive oil) over the temperature range of 25–200°C to understand the differences in cleanability of different surfaces exposed to high temperatures in food processes. The different surface...... different levels of roughness. The cosine of the contact angle of olive oil on different surface materials rises linearly with increasing temperature. Among the materials analyzed, polymers (PTFE, silicone) gave the lowest cosθ values. Studies of the effect of roughness and surface flaws on wettability...... contact angle and cleanability. In addition to surface wettability with oil many other factors such as roughness and surface defects play an essential role in determining their cleanability....

  3. GGVS. Ordinance on road transport of hazardous materials, including the European agreement on international road transport of hazardous materials (ADR), in their wording. Annexes A and B. Ordinances regarding exceptions from GGVS and from the ordinance on rail transport of hazardous materials, GGVE. Reasons. Selected guidelines. List of materials. 6. rev. and enlarged ed.

    International Nuclear Information System (INIS)

    Ridder, K.

    1990-01-01

    The brochure contains the following texts: (1) Ordinance on road transport of hazardous materials (GGVS), including the European agreement on international road transport of hazardous materials (ADR), as of 1990: Skeleton ordinance, annexes A and B, reasons given for the first version, and for the first amendment in 1988, execution guidelines - RS 002 (guidelines for executing the ordinance on road transport of hazardous materials, with catalogue of penalties), guidelines for drawing up written instructions for the event of accidents - RS 006, guiding principles for the training of vehicle conductors; (2) ordinance regarding exceptions from the ordinance on road transport of hazardous materials; (3) ordinance regarding exceptions from the ordinance on rail transport of hazardous materials; (4) selected guidelines: Technical guidelines TR IBC K 001, TRS 003, TRS 004, TRS 005, TRS 006; (5) listing of materials and objects governed by the ordinance on hazardous materials transport; (6) catalogue of penalties relative to road transport of hazardous materials. (orig./HP) [de

  4. Peptide-Directed PdAu Nanoscale Surface Segregation: Toward Controlled Bimetallic Architecture for Catalytic Materials.

    Science.gov (United States)

    Bedford, Nicholas M; Showalter, Allison R; Woehl, Taylor J; Hughes, Zak E; Lee, Sungsik; Reinhart, Benjamin; Ertem, S Piril; Coughlin, E Bryan; Ren, Yang; Walsh, Tiffany R; Bunker, Bruce A

    2016-09-27

    Bimetallic nanoparticles are of immense scientific and technological interest given the synergistic properties observed when two different metallic species are mixed at the nanoscale. This is particularly prevalent in catalysis, where bimetallic nanoparticles often exhibit improved catalytic activity and durability over their monometallic counterparts. Yet despite intense research efforts, little is understood regarding how to optimize bimetallic surface composition and structure synthetically using rational design principles. Recently, it has been demonstrated that peptide-enabled routes for nanoparticle synthesis result in materials with sequence-dependent catalytic properties, providing an opportunity for rational design through sequence manipulation. In this study, bimetallic PdAu nanoparticles are synthesized with a small set of peptides containing known Pd and Au binding motifs. The resulting nanoparticles were extensively characterized using high-resolution scanning transmission electron microscopy, X-ray absorption spectroscopy, and high-energy X-ray diffraction coupled to atomic pair distribution function analysis. Structural information obtained from synchrotron radiation methods was then used to generate model nanoparticle configurations using reverse Monte Carlo simulations, which illustrate sequence dependence in both surface structure and surface composition. Replica exchange with solute tempering molecular dynamics simulations were also used to predict the modes of peptide binding on monometallic surfaces, indicating that different sequences bind to the metal interfaces via different mechanisms. As a testbed reaction, electrocatalytic methanol oxidation experiments were performed, wherein differences in catalytic activity are clearly observed in materials with identical bimetallic composition. Taken together, this study indicates that peptides could be used to arrive at bimetallic surfaces with enhanced catalytic properties, which could be leveraged

  5. Direct investigation of (sub-) surface preparation artifacts in GaAs based materials by FIB sectioning

    Energy Technology Data Exchange (ETDEWEB)

    Belz, Jürgen; Beyer, Andreas; Torunski, Torsten; Stolz, Wolfgang; Volz, Kerstin

    2016-04-15

    The introduction of preparation artifacts is almost inevitable when producing samples for (scanning) transmission electron microscopy ((S)TEM). These artifacts can be divided in extrinsic artifacts like damage processes and intrinsic artifacts caused by the deviations from the volume strain state in thin elastically strained material systems. The reduction and estimation of those effects is of great importance for the quantitative analysis of (S)TEM images. Thus, optimized ion beam preparation conditions are investigated for high quality samples. Therefore, the surface topology is investigated directly with atomic force microscopy (AFM) on the actual TEM samples. Additionally, the sectioning of those samples by a focused ion beam (FIB) is used to investigate the damage depth profile directly in the TEM. The AFM measurements show good quantitative agreement of sample height modulation due to strain relaxation to finite elements simulations. Strong indications of (sub-) surface damage by ion beams are observed. Their influence on high angle annular dark field (HAADF) imaging is estimated with focus on thickness determination by absolute intensity methods. Data consolidation of AFM and TEM measurements reveals a 3.5 nm surface amorphization, negligible surface roughness on the scale of angstroms and a sub-surface damage profile in the range of up to 8.0 nm in crystalline gallium arsenide (GaAs) and GaAs-based ternary alloys. A correction scheme for thickness evaluation of absolute HAADF intensities is proposed and applied for GaAs based materials. - Highlights: • The damage by Ar-ion milling during TEM sample preparation is investigated directly. • After FIB sectioning damage and deep disorder of c-GaAs is seen in cross-section. • The influence of such disorder on conventional ADF measurements is estimated. • A correction for HAADF measurements is proposed with focus on thickness estimations.

  6. Using the level set method in geodynamical modeling of multi-material flows and Earth's free surface

    NARCIS (Netherlands)

    Hillebrand, B.; Thieulot, C.; Geenen, T.; Van Den Berg, A. P.; Spakman, W.

    2014-01-01

    The level set method allows for tracking material surfaces in 2-D and 3-D flow modeling and is well suited for applications of multi-material flow modeling. The level set method utilizes smooth level set functions to define material interfaces, which makes the method stable and free of oscillations

  7. Metallurgical aspects of fatigue fractured surfaces of al grain refined by some rare earth materials

    International Nuclear Information System (INIS)

    Zaid, A.I.O.

    2005-01-01

    Aluminum and aluminum alloys are widely used materials in the automobile and air craft industries due to their high strength-to-weight ratio, in addition to some other attractive characteristics e.g. corrosion resistance and high electrical and thermal conductivities. Aluminum and its alloys are normally grain refined by Ti or Ti+B to enhance their surface quality and improve their mechanical strength. Although the effect of addition of these grain refiners on the microstructure mechanical behaviour has been investigated and reported, little work has been published on the effect of the refiners on the fatigue life of aluminum and its alloys. In this paper, the effect of addition of some rare earth materials, namely Vanadium and Zirconium on the fatigue life of commercially pure aluminum grain refined by Ti or Ti+B is reported and discussed. Furthermore, metallurgical aspects of these elements on the fatigue fractured surfaces are also discussed using scanning electron microscopy, SEM. Finally, photoscans of the fractured surfaces at different fatigue stresses are presented and discussed. (author)

  8. The Properties of Nano Silver (Ag-Geopolymer as Antibacterial Composite for Functional Surface Materials

    Directory of Open Access Journals (Sweden)

    Armayani. M

    2017-01-01

    Full Text Available The purpose of this research was to produce and characterize nano silver (Ag-geopolymer composite for functional surface materials. Geopolymer matrix was synthesized through alkali activation of metakaolin and nano silver was added into geopolymers paste with a mass of 0, 0.5 g, 1 g, 1.5 g and 2 g keeping the mass of metakaolin constant. The mixture was cured at 70°C/1 hour and stored for 7 days before conducting any measurements. The structure of the resulting composite was examined by using Rigaku Mini Flex II x-ray diffraction (XRD. Scanning Electron Microscopy (SEM coupled with Energy Dispersive Spectroscopy (EDS was used to examine the morphology of the composite surface as well as the capability of the composite to isolate the growth of bacteria. The thermal properties of composites in terms of their working temperature and enthalpy were examined by using Perkin Elmer Differential Scanning Calorimetry (DSC. The heat resistance of composite was observed through calcination at 750°C for 18 hours. The results indicate that the resulting composites were able resist up 750°C. SEM examinations showed that nano Ag-geopolymer composites were effectively restraining the growth of bacteria. It is suggested that nano Ag-geopolymer composites are suitable for functional surface applications such as floor and wall, kitchen ware utensils, hospital instruments, art and decoration materials.

  9. Processing method and processing device for liquid waste containing surface active agent and radioactive material

    International Nuclear Information System (INIS)

    Nishi, Takashi; Matsuda, Masami; Baba, Tsutomu; Yoshikawa, Ryozo; Yukita, Atsushi.

    1998-01-01

    Washing liquid wastes containing surface active agents and radioactive materials are sent to a deaerating vessel. Ozone is blown into the deaerating vessel. The washing liquid wastes dissolved with ozone are introduced to a UV ray irradiation vessel. UV rays are irradiated to the washing liquid wastes, and hydroxy radicals generated by photodecomposition of dissolved ozone oxidatively decompose surface active agents contained in the washing liquid wastes. The washing liquid wastes discharged from the UV ray irradiation vessel are sent to an activated carbon mixing vessel and mixed with powdery activated carbon. The surface active agents not decomposed in the UV ray irradiation vessel are adsorbed to the activated carbon. Then, the activated carbon and washing liquid wastes are separated by an activated carbon separating/drying device. Radioactive materials (iron oxide and the like) contained in the washing liquid wastes are mostly granular, and they are separated and removed from the washing liquid wastes in the activated carbon separating/drying device. (I.N.)

  10. Mid-infrared thermal imaging for an effective mapping of surface materials and sub-surface detachments in mural paintings: integration of thermography and thermal quasi-reflectography

    Science.gov (United States)

    Daffara, C.; Parisotto, S.; Mariotti, P. I.

    2015-06-01

    Cultural Heritage is discovering how precious is thermal analysis as a tool to improve the restoration, thanks to its ability to inspect hidden details. In this work a novel dual mode imaging approach, based on the integration of thermography and thermal quasi-reflectography (TQR) in the mid-IR is demonstrated for an effective mapping of surface materials and of sub-surface detachments in mural painting. The tool was validated through a unique application: the "Monocromo" by Leonardo da Vinci in Italy. The dual mode acquisition provided two spatially aligned dataset: the TQR image and the thermal sequence. Main steps of the workflow included: 1) TQR analysis to map surface features and 2) to estimate the emissivity; 3) projection of the TQR frame on reference orthophoto and TQR mosaicking; 4) thermography analysis to map detachments; 5) use TQR to solve spatial referencing and mosaicking for the thermal-processed frames. Referencing of thermal images in the visible is a difficult aspect of the thermography technique that the dual mode approach allows to solve in effective way. We finally obtained the TQR and the thermal maps spatially referenced to the mural painting, thus providing the restorer a valuable tool for the restoration of the detachments.

  11. Research on change of surface structure of organic materials by Kr+ irradiation

    International Nuclear Information System (INIS)

    Nakase, Yoshiaki

    1990-01-01

    When ionized atoms or molecules are irradiated to materials, the irradiation effect based on the release of the energy that the ions possess and the effect due to the introduction of the atoms or molecules must be considered. These can be confirmed as the structural change, the change in molecular arrangement and crystalline structure, originated in the severance and cross-link of the molecules composing material, and as the structural change of higher order originated in the movement and recoil of the atoms or molecules of base materials accompanying the introduction of the atoms or molecules. It has been known that by the ion irradiation to polymer films, the film surfaces are easily colored. In order to examine the range and dose of ion irradiation, polyethylene telephthalate (PET), cellulose triacetate (CTA) and polyimide were irradiated with Kr + having medium energy of 35 keV. As for the irradiated samples, the measurement of light absorption and the general surface analysis were carried out. In the case of ion irradiation, light absorption increases due to substantial coloring. The experiment and the results are reported. (K.I.)

  12. Importance of including small-scale tile drain discharge in the calibration of a coupled groundwater-surface water catchment model

    DEFF Research Database (Denmark)

    Hansen, Anne Lausten; Refsgaard, Jens Christian; Christensen, Britt Stenhøj Baun

    2013-01-01

    the catchment. In this study, a coupled groundwater-surface water model based on the MIKE SHE code was developed for the 4.7 km2 Lillebæk catchment in Denmark, where tile drain flow is a major contributor to the stream discharge. The catchment model was calibrated in several steps by incrementally including...... the observation data into the calibration to see the effect on model performance of including diverse data types, especially tile drain discharge. For the Lillebæk catchment, measurements of hydraulic head, daily stream discharge, and daily tile drain discharge from five small (1–4 ha) drainage areas exist....... The results showed that including tile drain data in the calibration of the catchment model improved its general performance for hydraulic heads and stream discharges. However, the model failed to correctly describe the local-scale dynamics of the tile drain discharges, and, furthermore, including the drain...

  13. Enhanced surface functionality via plasma modification and plasma deposition techniques to create more biologically relevant materials

    Science.gov (United States)

    Shearer, Jeffrey C.

    Functionalizing nanoparticles and other unusually shaped substrates to create more biologically relevant materials has become central to a wide range of research programs. One of the primary challenges in this field is creating highly functionalized surfaces without modifying the underlying bulk material. Traditional wet chemistry techniques utilize thin film depositions to functionalize nanomaterials with oxygen and nitrogen containing functional groups, such as --OH and --NHx. These functional groups can serve to create surfaces that are amenable to cell adhesion or can act as reactive groups for further attachment of larger structures, such as macromolecules or antiviral agents. Additional layers, such as SiO2, are often added between the nanomaterial and the functionalized coating to act as a barrier films, adhesion layers, and to increase overall hydrophilicity. However, some wet chemistry techniques can damage the bulk material during processing. This dissertation examines the use of plasma processing as an alternative method for producing these highly functionalized surfaces on nanoparticles and polymeric scaffolds through the use of plasma modification and plasma enhanced chemical vapor deposition techniques. Specifically, this dissertation will focus on (1) plasma deposition of SiO2 barrier films on nanoparticle substrates; (2) surface functionalization of amine and alcohol groups through (a) plasma co-polymerization and (b) plasma modification; and (3) the design and construction of plasma hardware to facilitate plasma processing of nanoparticles and polymeric scaffolds. The body of work presented herein first examines the fabrication of composite nanoparticles by plasma processing. SiOxC y and hexylamine films were coated onto TiO2 nanoparticles to demonstrate enhanced water dispersion properties. Continuous wave and pulsed allyl alcohol plasmas were used to produce highly functionalized Fe2 O3 supported nanoparticles. Specifically, film composition was

  14. Surface morphology of silicone soft relining material after mechanical and chemical cleaning.

    Science.gov (United States)

    Ueda, Takayuki; Kubo, Keitaro; Saito, Takeshi; Obata, Tomokuni; Wada, Takeshi; Yanagisawa, Koichiro; Sakurai, Kaoru

    2018-04-07

    The objective was to investigate the influence of chemical and mechanical cleaning on the surface morphology of a silicone soft relining material. Three plate-shaped specimens were prepared for each group (Control, Hard and Soft) by laminating a 1.5-mm-thick silicone soft relining material. The Control group specimens were stored in water, and the Hard and Soft group specimens were cleaned with hard and soft bristle denture brushes, respectively. Abrasion testing with a toothbrush and immersion testing with an enzyme-containing peroxide denture cleanser were performed, simulating a period of approximately 4 months. The arithmetic mean roughness (Sa) and maximum height of the cross-section (Sz) were measured before and after abrasion and immersion testing. Sa was 4.9±0.9, 22.1±4.2 and 44.2±4.0μm in the Control, Soft and Hard groups, respectively. Sz was 257.5±31.7, 392.0±23.8 and 452.2±41.9μm in the Control, Soft and Hard groups, respectively. After abrasion testing, Sa and Sz differed significantly between the Soft and Control groups and between the Hard and Control groups. Sa was 2.2±1.2μm before and after immersion, and Sz was 142.1±81.4μm before and after immersion. No significant difference was noted in either Sa or Sz in the Control specimens before or after immersion. Surfaces cleaned using a soft bristle brush were less likely to roughen than those cleaned with a hard bristle brush under the conditions of this study. Additionally, chemical cleaning using the enzyme+neutral peroxide denture cleanser did not roughen the surface of the silicone soft relining material. Copyright © 2018 Japan Prosthodontic Society. Published by Elsevier Ltd. All rights reserved.

  15. Study of Abrasion of Rubber Materials by Experimental Design, Response Surface and Artificial Neural Network Modeling

    Directory of Open Access Journals (Sweden)

    Mehdi Shiva

    2015-07-01

    Full Text Available Effect of different formulation ingredients on the abrasion behavior, crack growth and modulus of tire tread formulation was studied using two different case studies. In the first case study, the effect of the partial substitution of natural rubber by cis-butadiene and the content variation of oil and sulfur in the presence of modified clay was studied on the basis of central composite design experiment in a NR/SBR-based truck tire tread formulation. In the second case study, the effect of oil, sulfur and highly dispersible silica level was investigated via Box-Benken design experiment in a SBR/BR-based passenger tire tread formulation. In each study a suitable response surface model was developed on the basis of the data obtained using the experimental design. Artificial neural network models with forwarding multi-layers were also developed to investigate the potential of the current approach in modeling of fracture behavior of rubber materials. It was observed that the complex dependency of the fracture/abrasion behavior of rubbery materials on formulation variations could be modeled with high accuracy through response surface and artificial neural models. The response surface profiles were developed to explain the abrasion behavior better. The observed behaviors for the abrasion of rubber formulations were also investigated with the aid of the modulus statistical analysis, deMattia crack growth model and also the Fukahori and mechano-chemical abrasion theories. In the presence of high levels of cis-butadiene, the abrasion with the mechano-chemical mechanism is dominant. However, according to the Fukahori model, the mean amplitude strain has a key effect on the abrasion of rubbery materials.

  16. EVALUATION OF SURFACE CONDITION AFTER FINISHING AND POLISHING OF A FLOWABLE COMPOSITE MATERIAL

    Directory of Open Access Journals (Sweden)

    Bogdan MUNTEANU

    2016-06-01

    Full Text Available The aim of the study was to evaluate the surface condition, after finishing and polishing with 3 different systems, of a flowable composite material, starting from the microstructure experimentally analyzed by atomic force microscopy. Materials and method. The material tested in the present study was Filtek Ultimate Flowable Restorative (3M ESPE composite. 20 cylindrical samples, 5 mm in diameter and 2 mm thick, were prepared by using metallic molds. The samples were randomly divided into 4 groups: a group containing 5 control samples, not subjected to finishing and 3 groups formed, each, of 5 samples for each of the three finishing and polishing systems, respectively system 1: the two-step Sof-Lex (3M ESPE, system 2: multistep Super Snap (Shofu, Inc. Kyoto, Japan and system 3: multi-step OptiDisc (KerrHawe SA, Switzerland. The surfaces of the samples were analyzed by atomic force microscopy. For quantitative evaluations, the rugosity parameter (Ra, and the mean deviation of the determined profile were calculated. Results. All 3 polishing systems determined an increase of the Ra parameter, comparatively with the control samples; the highest mean Ra value, of 1.19 µm, was recorded for system 3, followed by system 2 (mean Ra value = 1.12 µm, while the lowest mean value, of 1.10 µm, was registered for system 1. Conclusions. All three systems under investigation induced increased rugosity on the surfaces of the samples prepared from the Filtek Ultimate Flowable Restorative (3M ESPE composite resin. The most abrasive system appears to be OptiDisc (KerrHawe SA, Switzerland, followed by the Super Snap (Shofu, Inc. Kyoto, Japan system, the one recording the lowest abrasion being SofLex (3M ESPE.

  17. Anti-graffiti nanocomposite materials for surface protection of a very porous stone

    Science.gov (United States)

    Licchelli, Maurizio; Malagodi, Marco; Weththimuni, Maduka; Zanchi, Chiara

    2014-09-01

    The preservation of stone substrates from defacement induced by graffiti represents a very challenging task, which can be faced by applying suitable protective agents on the surface. Although different anti-graffiti materials have been developed, it is often found that their effectiveness is unsatisfactory, most of all when applied on very porous stones, e.g. Lecce stone. The aim of this work was to study the anti-graffiti behaviour of new nanocomposite materials obtained by dispersing montmorillonite nanoparticles (layered aluminosilicates with a high-aspect ratio) into a fluorinated polymer matrix (a fluorinated polyurethane based on perfluoropolyether blocks). Polymeric structure was modified by inducing a cross-linking process, in order to produce a durable anti-graffiti coating with enhanced barrier properties. Several composites were prepared using a naturally occurring and an organically modified montmorillonite clay (1, 3, and 5 % w/w concentrations). Materials were applied on Lecce stone specimens, and then their treated surfaces were soiled by a black ink permanent marker or by a black acrylic spray paint. Several repeated staining/cleaning cycles were performed in order to evaluate anti-graffiti effectiveness. Colorimetric measurements were selected to assess the anti-graffiti performance. It was found that the presence of 3 % w/w organically modified montmorillonite in the polymer coating is enough to induce a durable anti-graffiti effect when the stone surface is stained by acrylic paint. Less promising results are obtained when staining by permanent marker is considered as all the investigated treatments afford a reasonable protection from ink only for the first staining/cleaning cycle.

  18. The third generation multi-purpose plasma immersion ion implanter for surface modification of materials

    CERN Document Server

    Tang Bao Yin; Wang Xiao Feng; Gan Kong Yin; Wang Song Yan; Chu, P K; Huang Nian Ning; Sun Hong

    2002-01-01

    The third generation multi-purpose plasma immersion ion implantation (PIII) equipment has been successfully used for research and development of surface modification of biomedical materials, metals and their alloys in the Southwest Jiaotong University. The implanter equipped with intense current, pulsed cathodic arc metal plasma sources which have both strong coating function and gas and metal ion implantation function. Its pulse high voltage power supply can provide big output current. It can acquire very good implantation dose uniformity. The equipment can both perform ion implantation and combine ion implantation with sputtering deposition and coating to form many kinds of synthetic surface modification techniques. The main design principles, features of important components and achievement of research works in recent time have been described

  19. 3D-confocal microscopy for surface analysis of microstructured materials

    Science.gov (United States)

    Kagerer, Bernd; Brodmann, Rainer; Valentin, Juergen; Filzek, Jan; Popp, Uwe

    2002-06-01

    The surface of technical materials is playing an ever more important part in modern production processes. However, standard roughness values, which are obtained from a profile, frequently no longer provide sufficient descriptions. What are desired are three-dimensional measurements of surfaces over a macroscopic range with a high degree of vertical and lateral resolution. This has become necessary to be able to describe both deterministic and non-deterministic structures in the same fashion. Due to increased requirements for data and the measuring speed demanded by industry, only optical systems are a possibility. Using the example of tribology, the capability of this technology is shown in this article on the basis of the commercial confocal 3D white light microscope, the NanoFocusTMμSurfTM. On the one hand, the technology and data preparation used are discussed, and on the other, a comparison is drawn with other standard optical measuring methods.

  20. Difference in radiocarbon ages of carbonized material from the inner and outer surfaces of pottery from a wetland archaeological site.

    Science.gov (United States)

    Miyata, Yoshiki; Minami, Masayo; Onbe, Shin; Sakamoto, Minoru; Matsuzaki, Hiroyuki; Nakamura, Toshio; Imamura, Mineo

    2011-01-01

    AMS (Accelerator Mass Spectrometry) radiocarbon dates for eight potsherds from a single piece of pottery from a wetland archaeological site indicated that charred material from the inner pottery surfaces (5052 ± 12 BP; N = 5) is about 90 (14)C years older than that from the outer surfaces (4961 ± 22 BP; N = 7). We considered three possible causes of this difference: the old wood effect, reservoir effects, and diagenesis. We concluded that differences in the radiocarbon ages between materials from the inner and outer surfaces of the same pot were caused either by the freshwater reservoir effect or by diagenesis. Moreover, we found that the radiocarbon ages of carbonized material on outer surfaces (soot) of pottery from other wetland archaeological sites were the same as the ages of material on inner surfaces (charred food) of the same pot within error, suggesting absence of freshwater reservoir effect or diagenesis.

  1. The importance of the active surface area of graphite materials in the first lithium intercalation

    Energy Technology Data Exchange (ETDEWEB)

    Novak, P.; Ufheil, J.; Buqa, H. [Paul Scherrer Institut, Electrochemistry Laboratory, CH-5232 Villigen PSI (Switzerland); Krumeich, F. [ETH Zuerich, Laboratory of Inorganic Chemistry, CH-8093 Zurich (Switzerland); Spahr, M.E.; Goers, D.; Wilhelm, H.; Vix-Guterl, C. [TIMCAL SA, CH-6743 Bodio TI (Switzerland); Dentzer, J.; Gadiou, R. [Institut de Chimie des Surfaces et Interfaces, CNRS UPR 9069, F-68057 Mulhouse Cedex (France)

    2007-12-06

    When lithium is intercalated into graphite in ethylene carbonate (EC) containing electrolytes, solvent co-intercalation leading to the exfoliation of the graphite structure could occur. The exfoliation can be suppressed if an efficient solid electrolyte interphase (SEI, a passivation layer) is formed. Here we study the role played by the active surface area (ASA) of graphite materials during their first electrochemical reduction. ASA (related to the presence of defects at the carbon surface) appears as a critical graphite surface parameter influencing the surface passivation mechanism and the graphite exfoliation. The ASA of TIMREX {sup registered} SLX50 synthetic graphite was modified by thermal treatment in argon and air. The electrochemical performance was characterized in 1 M LiPF{sub 6}, EC:DMC electrolyte and post mortem analyses were performed by SEM imaging. It turned out that a decrease of the graphite ASA, i.e., an increase of the graphite structural order, hinders the formation of the passivation layer and favors the exfoliation process. In contrast, the exfoliation of the same graphite can be suppressed if its ASA is increased for example by air treatment. The ASA of the graphite kinetically controls the formation of an efficient SEI film and accordingly the irreversible charge loss is much lower in the case of graphite with a high ASA value. (author)

  2. New Developments for Radiation Enhancements from Metal Surfaces by Using Nanoscale Materials in the Membrane

    Science.gov (United States)

    Yamada, Koji; Matsuda, Masami

    2017-12-01

    The enhancements of thermal radiations from the surfaces of devices are very important for electric machines to prevent from heating up and/or efficiency degradations. In this investigation, new applications of micro-scale membrane of Si, SiO2 etc. on the metal surfaces have been studied to cool down the temperature without breaking insulations of the devices by selecting materials. The modified black-body radiations were sensitively detected by thermisters with sub-second responses. The optimum membrane thicknesses were successfully determined by subtractions a of radiation intensities between those at membranes with and without membrane, respectively. We obtained the best cooling condition in SiO2 membrane with 20μmt for an Al-plate of 10cmx10cmx1mmt. Further, we observed the detaching/attaching processes of massive molecule clusters from the metal surface as a sudden change in temperature changes just like the noises in the detectors. A characteristic pattern of temperature change was observed in diatomite membranes during the cooling process in a temperature range between 200-50°C. These radiation phenomena as a function of temperature might be available as a molecular analysis on the metal surface.

  3. Conformal surface coatings to enable high volume expansion Li-ion anode materials.

    Science.gov (United States)

    Riley, Leah A; Cavanagh, Andrew S; George, Steven M; Jung, Yoon Seok; Yan, Yanfa; Lee, Se-Hee; Dillon, Anne C

    2010-07-12

    An alumina surface coating is demonstrated to improve electrochemical performance of MoO(3) nanoparticles as high capacity/high-volume expansion anodes for Li-ion batteries. Thin, conformal surface coatings were grown using atomic layer deposition (ALD) that relies on self-limiting surface reactions. ALD coatings were tested on both individual nanoparticles and prefabricated electrodes containing conductive additive and binder. The coated and non-coated materials were characterized using transmission electron microscopy, energy-dispersive X-ray spectroscopy, electrochemical impedance spectroscopy, and galvanostatic charge/discharge cycling. Importantly, increased stability and capacity retention was only observed when the fully fabricated electrode was coated. The alumina layer both improves the adhesion of the entire electrode, during volume expansion/contraction and protects the nanoparticle surfaces. Coating the entire electrode also allows for an important carbothermal reduction process that occurs during electrode pre-heat treatment. ALD is thus demonstrated as a novel and necessary method that may be employed to coat the tortuous network of a battery electrode.

  4. Antimicrobial activity of transition metal acid MoO{sub 3} prevents microbial growth on material surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Zollfrank, Cordt, E-mail: cordt.zollfrank@ww.uni-erlangen.de [University of Erlangen-Nuremberg, Department of Materials Science and Engineering 3-Glass and Ceramics, Martensstr. 5, D-91058 Erlangen (Germany); Gutbrod, Kai [University of Erlangen-Nuremberg, Department of Materials Science and Engineering 3-Glass and Ceramics, Martensstr. 5, D-91058 Erlangen (Germany); Wechsler, Peter [LEONI Kabel GmbH, Stieberstrasse 5, D-91154 Roth (Germany); Guggenbichler, Josef Peter [Laboratory for the Development of Healthcare Products, Leitweg 23, A-6345 Koessen (Austria)

    2012-01-01

    Serious infectious complications of patients in healthcare settings are often transmitted by materials and devices colonised by microorganisms (nosocomial infections). Current strategies to generate material surfaces with an antimicrobial activity suffer from the consumption of the antimicrobial agent and emerging multidrug-resistant pathogens amongst others. Consequently, materials surfaces exhibiting a permanent antimicrobial activity without the risk of generating resistant microorganisms are desirable. This publication reports on the extraordinary efficient antimicrobial properties of transition metal acids such as molybdic acid (H{sub 2}MoO{sub 4}), which is based on molybdenum trioxide (MoO{sub 3}). The modification of various materials (e.g. polymers, metals) with MoO{sub 3} particles or sol-gel derived coatings showed that the modified materials surfaces were practically free of microorganisms six hours after contamination with infectious agents. The antimicrobial activity is based on the formation of an acidic surface deteriorating cell growth and proliferation. The application of transition metal acids as antimicrobial surface agents is an innovative approach to prevent the dissemination of microorganisms in healthcare units and public environments. Highlights: Black-Right-Pointing-Pointer The presented modifications of materials surfaces with MoO{sub 3} are non-cytotoxic and decrease biofilm growth and bacteria transmission. Black-Right-Pointing-Pointer The material is insensitive towards emerging resistances of bacteria. Black-Right-Pointing-Pointer Strong potential to reduce spreading of infectious agents on inanimate surfaces.

  5. Assessment of microbial growth on the surface of materials in contact with water intended for human consumption using ATP method.

    Science.gov (United States)

    Szczotko, Maciej; Krogulski, Adam

    2010-01-01

    Elaboration of an assessment method for plumbing materials contacting drinking water was the main purpose of this study. The investigation was conducted in 8 week cycles in dynamic conditions using a continuous flow reactor. Microbial growth was measured indirectly by a bioluminescence technique (ATP assay). Every week swabs from the surface of tested materials (polypropylene and different types of polyethylene), from the domestic market were collected and the level of bioluminescence was examined. The results obtained from the surface of tested materials were repeatable and clearly approximated those obtained from the surface of a negative control (stainless steel, low susceptibility for microbial growth). The level of bioluminescence (ATP) on the surface of positive control (paraffin, high susceptibility for microbial growth) was many times higher than that observed on other materials. The presented investigation was the main part of a validation process, which in short time will serve to initiate a complete assessment system for organic materials contacting drinking water.

  6. Surface modification induced enhanced CO2 sorption in cucurbit[6]uril, an organic porous material.

    Science.gov (United States)

    Mohan, Midhun; Suzuki, T; Nair, Akhil K; Pillai, Saju; Warrier, K G K; Hareesh, U S; Nair, Balagopal N; Gale, J D

    2017-09-27

    The CO 2 adsorption properties of an organic macrocycle, cucurbit[6]uril (CB[6]), have been evaluated through experimental and theoretical studies. Quantum mechanical calculations show that CB[6] is capable of adsorbing the CO 2 molecule selectively within its cavity relative to nitrogen. Adsorption experiments at 298 K and at 1 bar pressure gave a CO 2 adsorption value of 1.23 mmol g -1 for the unmodified material. Significant enhancements in the CO 2 adsorption capacity of the material were experimentally demonstrated through surface modification using physical and chemical methods. Ethanolamine (EA) modified CB[6] provided an excellent sorption selectivity value of 121.4 for CO 2 /N 2 at 323 K and is unique with respect to its discrimination potential between CO 2 and N 2 . The chemical nature of the interaction between CO 2 and amine is shown to be the primary mechanism for the enhanced CO 2 absorption performance.

  7. RF Surface Impedance Characterization of Potential New Materials for SRF-based Accelerators

    International Nuclear Information System (INIS)

    In the development of new superconducting materials for possible use in SRF-based accelerators, it is useful to work with small candidate samples rather than complete resonant cavities. The recently commissioned Jefferson Lab RF Surface Impedance Characterization (SIC) system can presently characterize the central region of 50 mm diameter disk samples of various materials from 2 to 40 K exposed to RF magnetic fields up to 14 mT at 7.4 GHz. We report the recent measurement results of bulk Nb, thin film Nb on Cu and sapphire substrates, Nb 3 Sn sample, and thin film MgB 2 on sapphire substrate provided by colleagues at JLab and Temple University

  8. Nano-materials for adhesive-free adsorbers for bakable extreme high vacuum cryopump surfaces

    Science.gov (United States)

    Stutzman, Marcy; Jordan, Kevin; Whitney, Roy R.

    2016-10-11

    A cryosorber panel having nanomaterials used for the cryosorption material, with nanomaterial either grown directly on the cryopanel or freestanding nanomaterials attached to the cryopanel mechanically without the use of adhesives. Such nanomaterial cryosorber materials can be used in place of conventional charcoals that are attached to cryosorber panels with special low outgassing, low temperature capable adhesives. Carbon nanotubes and other nanomaterials could serve the same purpose as conventional charcoal cryosorbers, providing a large surface area for cryosorption without the need for adhesive since the nanomaterials can be grown directly on a metallic substrate or mechanically attached. The nanomaterials would be capable of being fully baked by heating above 100.degree. C., thereby eliminating water vapor from the system, eliminating adhesives from the system, and allowing a full bake of the system to reduce hydrogen outgassing, with the goal of obtaining extreme high vacuum where the pump can produce pressures below 1.times.10.sup.-12 Torr.

  9. Modification of backfill material used in near surface disposal of low-level radwaste

    International Nuclear Information System (INIS)

    Gu Cunli; Liu Zhen; Fan Zhiwen; Xie Jianxun; Huang Yawen

    1993-01-01

    Clay has the merits of good airtightness and strong anti-permeability when it is used as backfill material in near-surface disposal of low-level radwaste, though its ion exchange capacity is not large. In order to increase its ability to retard nuclides, 9 kinds of 5 categories of additives have been used in the test for its modification. The results show that the anti-permeability of the mixed material decreases unnoticeably, while the distribution coefficients (K d ) for 60 Co, 134 Cs and 85 Sr are 4.8, 4.6, and 4.7 times that using pure clay respectively, when the amount of Ca-bentonite added is 10%. The migration of 60 Co, 134 Cs, and 85 Sr in the clay of different densities under dynamic conditions has been studied, and the retardation factor Rd, obtained

  10. Change in surface of polymer materials upon irradiation of accelerated micro-particles

    Science.gov (United States)

    Kudo, Hisaaki; Tadokoro, Masashi; Narita, Shintaro; Matsuoka, Leo; Muroya, Yusa; Katsumura, Yosuke

    2005-07-01

    As a new method of use of a particle accelerator (ionizing radiation generator), we irradiated accelerated micro-particles of silver (Ag) onto polymer materials such as polyimides, glass, ceramics and semi-conductors. The particles can be generated at a Van de Graaff electrostatic accelerator operating at 1-3 MV. The velocity was around 1-10 km/s, size of diameter was about 1-10 μm and charge was about 1-2 μC. We investigated the change in surface of materials upon irradiation, by using laser microscope, atomic force microscope and scanning electron microscope. Crater-shaped irradiation spots having limb structure were found, and their diameter and depth were evaluated, ranging in a few micrometers. The planar distribution of the projectile around the irradiation spot was examined with energy dispersive X-ray spectroscopy. Correlation between size of the irradiation spots and kinetic energy of the accelerated micro-particles was investigated, and compared with an empirical formula and molecular dynamics study. Numerical simulation dealing with dynamic behaviour of elastic structure was carried out based on SPH (Smoothed Particle Hydrodynamics) method, a kind of (virtual) particle method. The simulation also found that a crater-shaped spot having limb structure is formed upon collision of the accelerated projectile with the target-materials. The results of simulation were compared with the experimental observations. These experiment and simulation are important for the evaluation of damages and resistance of polymer materials used in the space, such as the thermal control material, and cover glass of solar cells etc., towards space debris and dusts. It would be complement the on-ground radiation resistant tests on the materials conducted by using electron and ion beam accelerators.

  11. Decontamination of scientific and laboratory equipment with different materials and surface

    International Nuclear Information System (INIS)

    Kharita, M. H.; Khaito, M.; Wali, K.

    2003-01-01

    The process of decontamination of scientific and laboratory equipment is considered to be a very important scientific work with a good economical justification due to the expensive value of some of the contaminated equipment. This will lead to the rehabilitation of these equipment on one hand and decrease in volume of the radioactive waste on the other hand. The materials used for this process are cheap and widely available. The process developed and employed in this work showed a very good values for the decontamination factor for glass, metallic and plastic surfaces contaminated with different radioisotopes. (author)

  12. Specific heats of lunar surface materials from 90 to 350 degrees Kelvin

    Science.gov (United States)

    Robie, R.A.; Hemingway, B.S.; Wilson, W.H.

    1970-01-01

    The specific heats of lunar samples 10057 and 10084 returned by the Apollo 11 mission have been measured between 90 and 350 degrees Kelvin by use of an adiabatic calorimeter. The samples are representative of type A vesicular basalt-like rocks and of finely divided lunar soil. The specific heat of these materials changes smoothly from about 0.06 calorie per gram per degree at 90 degrees Kelvin to about 0.2 calorie per gram per degree at 350 degrees Kelvin. The thermal parameter ??=(k??C)-1/2 for the lunar surface will accordingly vary by a factor of about 2 between lunar noon and midnight.

  13. Ceramics for Molten Materials Containment, Transfer and Handling on the Lunar Surface

    Science.gov (United States)

    Standish, Evan; Stefanescu, Doru M.; Curreri, Peter A.

    2009-01-01

    As part of a project on Molten Materials Transfer and Handling on the Lunar Surface, molten materials containment samples of various ceramics were tested to determine their performance in contact with a melt of lunar regolith simulant. The test temperature was 1600 C with contact times ranging from 0 to 12 hours. Regolith simulant was pressed into cylinders with the approximate dimensions of 1.25 dia x 1.25cm height and then melted on ceramic substrates. The regolith-ceramic interface was examined after processing to determine the melt/ceramic interaction. It was found that the molten regolith wetted all oxide ceramics tested extremely well which resulted in chemical reaction between the materials in each case. Alumina substrates were identified which withstood contact at the operating temperature of a molten regolith electrolysis cell (1600 C) for eight hours with little interaction or deformation. This represents an improvement over alumina grades currently in use and will provide a lifetime adequate for electrolysis experiments lasting 24 hours or more. Two types of non-oxide ceramics were also tested. It was found that they interacted to a limited degree with the melt resulting in little corrosion. These ceramics, Sic and BN, were not wetted as well as the oxides by the melt, and so remain possible materials for molten regolith handling. Tests wing longer holding periods and larger volumes of regolith are necessary to determine the ultimate performance of the tested ceramics.

  14. Effect of heater material and coolant additives on CHF for a downward facing curved surface

    International Nuclear Information System (INIS)

    Park, Hae Min; Jeong, Yong Hoon; Heo, Sun

    2014-01-01

    Highlights: • Critical heat flux experiment for a downward facing curved surface was conducted. • We investigate the effect of heater material and coolant additives. • Critical heat flux is affected by the steel oxidation. - Abstract: The critical heat flux (CHF) in the vicinity of an inclination angle of 90° for the reactor vessel lower head external wall was measured on a downward facing curved surface. Two test sections having radii of curvature 0.15 m and 0.5 m were used. The objective was to investigate the effect of heater material and the combined effect of the heater material and additives on flow boiling CHF to assess the CHF enhancement under accident conditions. The heater material SA508 (low alloy steel) and the additive solutions of boric acid and tri-sodium phosphate (TSP, Na 3 PO 4 ·12H 2 O) were used. An enhancement of CHF with the SA508 heater was confirmed in comparison with stainless steel reference heaters, which have negligible steel oxidation. As a result of the combined effect tests, the CHF with a TSP solution was reduced and the CHFs with a boric acid and a mixed solution (boric acid and TSP) were enhanced in comparison with the deionized water reference case. The CHF results are discussed in terms of steel oxidation according to the pH of the working fluid. Steel oxidation is also affected by local flow conditions as shown in the R = 0.5 m tests in which the boric acid and mixed solution had negligible effects on CHF enhancement. Under a relatively high concentration of boric acid (2.5 wt%), additive deposition as well as steel oxidation were observed and resulted in CHF enhancement

  15. Analysis of Material Removal and Surface Characteristics in Machining Multi Walled Carbon Nanotubes Filled Alumina Composites by WEDM Process

    Directory of Open Access Journals (Sweden)

    Annebushan Singh Meinam

    2017-01-01

    Full Text Available The reinforcement of ceramic materials with electrically conductive particles increases the overall conductivity of the ceramic material. This allows the ceramic material to be more readily machined using wire electrical discharge machining process. The current work is an approach to identify the machinability of multi walled carbon nanotubes filled alumina composites in wire electrical discharge machining process. Alumina samples of 5 vol. % and 10 vol. % multi walled carbon nanotubes are machined and analysed for material removal rate and the surface characteristics. An increase in material removal rate is observed with increase in filler concentrations. At the same time, better surface roughness is observed. The surface characteristics of composite alumina are further compared with Monel 400 alloy. It has been observed that spalling action is the dominating material removal mechanism for alumina composites, while melting and evaporation is for the Monel 400 alloy.

  16. Environmental Impact Assessment of a School Building in Iceland Using LCA-Including the Effect of Long Distance Transport of Materials

    Directory of Open Access Journals (Sweden)

    Nargessadat Emami

    2016-11-01

    Full Text Available Buildings are the key components of urban areas and society as a complex system. A life cycle assessment was applied to estimate the environmental impacts of the resources applied in the building envelope, floor slabs, and interior walls of the Vættaskóli-Engi building in Reykjavik, Iceland. The scope of this study included four modules of extraction and transportation of raw material to the manufacturing site, production of the construction materials, and transport to the building site, as described in the standard EN 15804. The total environmental effects of the school building in terms of global warming potential, ozone depletion potential, human toxicity, acidification, and eutrophication were calculated. The total global warming potential impact was equal to 255 kg of CO2 eq/sqm, which was low compared to previous studies and was due to the limited system boundary of the current study. The effect of long-distance overseas transport of materials was noticeable in terms of acidification (25% and eutrophication (31% while it was negligible in other impact groups. The results also concluded that producing the cement in Iceland caused less environmental impact in all five impact categories compared to the case in which the cement was imported from Germany. The major contribution of this work is that the environmental impacts of different plans for domestic production or import of construction materials to Iceland can be precisely assessed in order to identify effective measures to move towards a sustainable built environment in Iceland, and also to provide consistent insights for stakeholders.

  17. Automatic construction of subject-specific human airway geometry including trifurcations based on a CT-segmented airway skeleton and surface

    Science.gov (United States)

    Miyawaki, Shinjiro; Tawhai, Merryn H.; Hoffman, Eric A.; Wenzel, Sally E.; Lin, Ching-Long

    2016-01-01

    We propose a method to construct three-dimensional airway geometric models based on airway skeletons, or centerlines (CLs). Given a CT-segmented airway skeleton and surface, the proposed CL-based method automatically constructs subject-specific models that contain anatomical information regarding branches, include bifurcations and trifurcations, and extend from the trachea to terminal bronchioles. The resulting model can be anatomically realistic with the assistance of an image-based surface; alternatively a model with an idealized skeleton and/or branch diameters is also possible. This method systematically identifies and classifies trifurcations to successfully construct the models, which also provides the number and type of trifurcations for the analysis of the airways from an anatomical point of view. We applied this method to 16 normal and 16 severe asthmatic subjects using their computed tomography images. The average distance between the surface of the model and the image-based surface was 11% of the average voxel size of the image. The four most frequent locations of trifurcations were the left upper division bronchus, left lower lobar bronchus, right upper lobar bronchus, and right intermediate bronchus. The proposed method automatically constructed accurate subject-specific three-dimensional airway geometric models that contain anatomical information regarding branches using airway skeleton, diameters, and image-based surface geometry. The proposed method can construct (i) geometry automatically for population-based studies, (ii) trifurcations to retain the original airway topology, (iii) geometry that can be used for automatic generation of computational fluid dynamics meshes, and (iv) geometry based only on a skeleton and diameters for idealized branches. PMID:27704229

  18. PREFACE Surface Modifications of Diamond and Related Materials (Session D, E-MRS Spring Meeting)

    Science.gov (United States)

    Nebel, Christoph E.

    2010-11-01

    This special issue contains selected papers which were presented at the E-MRS Symposium BIOMATERIALS, SENSORS & SURFACES, D: 'Surface modifications of diamond and related materials' which was held on 7-9 June 2010 in Strasbourg (France). With about 54 oral and poster presentations given from teams all over the world it was a very interesting, dense and lively meeting. The symposium focused on chemical modifications applied to graft surfaces of diamond, nano-diamond particles, diamond-like carbon, graphene, graphite and carbon nano-tubes with linker molecular layers for realization of bio-sensors, bio-markers, separation techniques, and switchable chemical links. Presented techniques span spontaneous bonding to photo-chemical attachment, electrochemical modifications, to Suzuki-coupling of aryl molecules. Special attention was drawn to mechanisms driving bonding kinetics such as electron transfer reactions, hydrogen cleavage reactions by nucleophilic molecules and growths schemas which vary from correlated two-dimensional chain reactions to three-dimensional cross polymerization. Hydrogen terminations, surface defects, surface roughness and atomic arrangements of surface carbon atoms were of interest to elucidate bonding mechanisms. In addition, bonding stability, either of linker molecules or of complex functionalized surfaces with DNA, proteins and enzymes was discussed by several speakers as well as details of the electronic interfaces between solid transducers and bio-layers. Here the characterization of surface and interface defect densities, of Fermi level pinning and of electron transfer rates was a major topic. Miniaturization of sensor area and application of new detection schemas was discussed. Diamond nano-particles which are increasingly used as biomarkers in drug delivery experiments also attracted attention. The organizers express our gratitude to the international members of the scientific committee who actively contributed to ensure an attractive

  19. Effect of two different polishing systems on fluoride release, surface roughness and bacterial adhesion of newly developed restorative materials.

    Science.gov (United States)

    Bayrak, Gokcen Deniz; Sandalli, Nuket; Selvi-Kuvvetli, Senem; Topcuoglu, Nursen; Kulekci, Guven

    2017-11-12

    To evaluate the effects of two different polishing systems on fluoride release, surface roughness and bacterial adhesion of five restorative materials MATERIALS AND METHODS: The study groups were comprised of five different restorative materials, Beautifil II (B); GCP Glass Fill (G); Amalgomer CR (A); Dyract XP (D); Fuji IX GP (F) and 21 specimens were prepared from each material. Each group was divided into three subgroups according to the polishing system: Mylar (control) (C), Sof-lex (S), and Enhance-Pogo (EP). The amount of fluoride release was measured using a fluoride ion-selective electrode and surface roughness was investigated with a profilometer. Bacterial adhesion on the materials was evaluated by optical density readouts for S.mutans on a spectrophotometer. The highest amount of fluoride was released from specimens in the S subgroup of group G during all measurement days. Surface roughness values were significantly lower in subgroup C than the other polishing systems in all study groups except group G (P restorative materials especially in glass ionomer-based materials. This article stated that polishing promoted a significant increase of fluoride release on restorative materials especially in glass ionomer-based materials. Further, proper polishing systems must be chosen according to the structure and composition of materials to provide the best clinical benefits in terms of fluoride release, surface roughness and bacterial adhesion. © 2017 Wiley Periodicals, Inc.

  20. Signals from fluorescent materials on the surface of silicon micro-strip sensors

    CERN Document Server

    Sperlich, Dennis; The ATLAS collaboration

    2017-01-01

    For the High-Luminosity Upgrade of the Large Hadron Collider at CERN, the ATLAS Inner Detector will be replaced with a new, all-silicon tracker. In order to minimise the amount of material in the detector, circuit boards with readout electronics will be glued on to the active area of the sensor. Several adhesives investigated to be used for the construction of detector modules were found to become fluorescent when exposed to UV light. These adhesives could become a light source in the high-radiation environment of the ATLAS detector. The effect of fluorescent material covering the sensor surface in a high- radiation environment has been studied for a silicon micro-strip sensor using a micro-focused X-ray beam. By pointing the beam both inside the sensor and parallel to the sensor surface, the sensor responses from direct hits and fluorescence can be compared with high precision. This contribution presents a setup to study the susceptibility of silicon strip sensors to light contamination from fluorescent mate...

  1. Optical find of hypersonic surface acoustic waves in bulk transparent materials

    Science.gov (United States)

    Jiménez Riobóo, Rafael J.; Sánchez-Sánchez, Alberto; Prieto, Carlos

    2016-07-01

    It is shown that direct information from surface acoustic waves (SAWs) of bulk transparent materials can be obtained by using Brillouin light scattering (BLS). The study of surface phonons by means of an optical spectroscopy such as BLS has been historically constrained to nontransparent and highly reflecting bulk and film samples or even to very thin films deposited on reflecting substrates. Probably due to its low signal and to the narrow window in experimental conditions, it was assumed for years that bulk transparent samples were not suited for Brillouin spectroscopy in order to get information on SAWs, negating this optical technique in the search for SAW properties. The reported experiments on transparent glasses and single crystals (cubic MgO and trigonal sapphire) prove that there is no intrinsic physical reason not to collect SAW propagation velocity data from transparent bulk samples and opens a challenge to apply the Brillouin spectroscopy in a wider scenario to obtain direct information, in a nondestructive and contactless way, about SAWs in bulk materials.

  2. Signals from fluorescent materials on the surface of silicon micro-strip sensors

    CERN Document Server

    Sperlich, Dennis; The ATLAS collaboration

    2018-01-01

    For the High-Luminosity Upgrade of the Large Hadron Collider at CERN, the ATLAS Inner Detector will be replaced with a new, all-silicon tracker (ITk). In order to minimise the amount of material in the ITk, circuit boards with readout electronics will be glued onto the active area of the sensor. Several adhesives, investigated to be used for the construction of detector modules, were found to become fluorescent when exposed to UV light. These adhesives could become a light source in the high-radiation environment of the ATLAS detector. The effect of fluorescent material covering the sensor surface in a high-radiation environment has been studied for a silicon micro-strip sensor using a micro-focused X-ray beam. By positioning the beam parallel to the sensor surfave and pointing it both inside the sensor and above the sensor surface inside the deposited glue, the sensor responses from direct hits and fluorescence can be compared with high precision. This contribution presents a setup to study the susceptibilit...

  3. Molecular surface structural changes of plasticized PVC materials after plasma treatment.

    Science.gov (United States)

    Zhang, Xiaoxian; Zhang, Chi; Hankett, Jeanne M; Chen, Zhan

    2013-03-26

    In this research, a variety of analytical techniques including sum frequency generation vibrational spectroscopy (SFG), coherent anti-Stokes Raman spectroscopy (CARS), and X-ray photoelectron spectroscopy (XPS) have been employed to investigate the surface and bulk structures of phthalate plasticized poly(vinyl chloride) (PVC) at the molecular level. Two types of phthalate molecules with different chain lengths, diethyl phthalate (DEP) and dibutyl phthalate (DBP), mixed with PVC in various weight ratios were examined to verify their different surface and bulk behaviors. The effects of oxygen and argon plasma treatment on PVC/DBP and PVC/DEP hybrid films were investigated on both the surface and bulk of films using SFG and CARS to evaluate the different plasticizer migration processes. Without plasma treatment, SFG results indicated that more plasticizers segregate to the surface at higher plasticizer bulk concentrations. SFG studies also demonstrated the presence of phthalates on the surface even at very low bulk concentration (5 wt %). Additionally, the results gathered from SFG, CARS, and XPS experiments suggested that the PVC/DEP system was unstable, and DEP molecules could leach out from the PVC under low vacuum after several minutes. In contrast, the PVC/DBP system was more stable; the migration process of DBP out of PVC could be effectively suppressed after oxygen plasma treatment. XPS results indicated the increase of C═O/C-O groups and decrease of C-Cl functionalities on the polymer surface after oxygen plasma treatment. The XPS results also suggested that exposure to argon plasma induced chemical bond breaking and formation of cross-linking or unsaturated groups with chain scission on the surface. Finally, our results indicate the potential risk of using DEP molecules in PVC since DEP can easily leach out from the polymeric bulk.

  4. Analysis of the Effect of Surface Modification on Polyimide Composites Coated with Erosion Resistant Materials

    Science.gov (United States)

    Ndalama, Tchinga; Hirschfeld, Deidre; Sutter, James K. (Technical Monitor)

    2003-01-01

    The aim of this research is to enhance performance of composite coatings through modification of graphite-reinforced polyimide composite surfaces prior to metal bond coat/ hard topcoat application for use in the erosive and/or oxidative environments of advanced engines. Graphite reinforced polyimide composites, PMR-15 and PMR-II-50, formed by sheet molding and pre-pregging will be surface treated, overlaid with a bond coat and then coated with WC-Co. The surface treatment will include cleaning, RF plasma or ultraviolet light- ozone etching, and deposition of SiO(x) groups. These surface treatments will be studied in order to investigate and improve adhesion and oxidation resistance. The following panels were provided by NASA-Glenn Research Center(NASA-GRC): Eight compression molded PMR-II-50; 6 x 6 x 0.125 in. Two vacuum-bagged PMR-II-50; 12 x 12 x 0.125 in. Eight compression molded PMR-15; 6 x 6 x 0.125 in. One vacuum-bagged PMR-15; 12 x 12 x 0.125 in. All panels were made using a 12 x 12 in. T650-35 8HS (3K-tow) graphite fabric. A diamond-wafering blade, with deionized water as a cutting fluid, was used to cut PMR-II-50 and PMR-15 panels into 1 x 1 in. pieces for surface tests. The panel edges exhibiting delamination were used for the preliminary surface preparation tests as these would be unsuitable for strength and erosion testing. PMR-15 neat resin samples were also provided by NASA GRC. Surface profiles of the as-received samples were determined using a Dektak III Surface profile measuring system. Two samples of compression molded PMR-II-50 and PMR-15, vacuum-bagged PMR-II-50 and PMR-15 were randomly chosen for surface profile measurement according to ANSI/ASME B46.1. Prior to each measurement, the samples were blasted with compressed air to remove any artifacts. Five 10 mm-long scans were made on each sample. The short and long wavelength cutoff filter values were set at 100 and 1000 m, diamond stylus radius was 12.5 microns. Table 1 is a summary of the

  5. Development of Neutron Probes for Characterization of Hazardous Materials in the Sub-surface Medium

    International Nuclear Information System (INIS)

    Keegan, R.P.; McGrath, C.A.; Lopez, J.C.

    2002-01-01

    Neutron probes are being developed at the Idaho National Engineering and Environmental Laboratory (INEEL) for the detection, identification and quantification of hazardous materials in the ground. Such materials include plutonium, uranium, americium, chlorine and fluorine. Both a Neutron Gamma (NG) probe and a Prompt Fission Neutron (PFN) probe are being developed. The NG probe is used primarily for nuclide identification and quantification measurements. The PFN is used mostly for the detection and measurement of fissile material, but also for the determination of thermal neutron macroscopic absorption cross sections of the various elements comprising the ground matrix. Calibration of these probes will be carried out at the INEEL using an indoor facility that has been designed for this activity

  6. Disposal project for LLW and VLLW generated from research facilities in Japan: A feasibility study for the near surface disposal of VLLW that includes uranium

    International Nuclear Information System (INIS)

    Sakai, Akihiro; Hasegawa, M.; Sakamoto, Y.; Nakatani, T.

    2016-01-01

    Conclusion and future work: • JAEA plans trench disposal of U-bearing waste with less than 100 Bq/g. • Two safety measures of trench disposal of U-bearing waste have been discussed taking into account increasing radioactivity over a long period of time. 1. First is to carry out dose assessment of site use scenario by using a conservatively stylized condition. 2. Second is to control the average concentration of U in the trench facilities based on the concept of the existing exposure situation. • We are continuously developing the method for safety measures of near surface disposal of VLLW including U-bearing waste.

  7. Graphdiyne as Electrode Material: Tuning Electronic State and Surface Chemistry for Improved Electrode Reactivity.

    Science.gov (United States)

    Guo, Shuyue; Yan, Hailong; Wu, Fei; Zhao, Lijun; Yu, Ping; Liu, Huibiao; Li, Yuliang; Mao, Lanqun

    2017-12-05

    Graphdiyne (GDY) is recently synthesized two-dimensional carbon allotrope with hexagonal rings cross-linked by diacetylene through introducing butadiyne linkages (-C≡C-C≡C-) to form 18-C hexagons and is emerging to be fundamentally interesting and particularly useful in various research fields. In this study, we for the first time find that GDY can be used as an electrode material with reactivity tunable by electronic states and surface chemistry of GDY. To demonstrate this, GDY is oxidized into graphdiyne oxide (GDYO) that is then chemically and electrochemically reduced into chemically reduced GDYO (cr-GDYO) and electrochemically reduced GDYO (er-GDYO), respectively. Electrode reactivity of GDY and its derivatives (i.e., GDYO, cr-GDYO, and er-GDYO) is studied with hexaammineruthenium chloride ([Ru(NH 3 ) 6 ]Cl 3 ) and potassium ferricyanide (K 3 Fe(CN) 6 ) as redox probes. We find that electron transfer kinetics of the redox probes employed here at GDYs depends on the density of electronic state (DOS) and the synergetic effects of the surface chemistry as well as the hydrophilicity of the materials, and that the electron transfer kinetics at cr-GDYO and er-GDYO are faster than those at GDY and GDYO, and quite comparable with those at carbon nanotubes and graphene and its derivatives (i.e., GO, cr-GO, and er-GO). These properties, combined with the unique electronic and chemical structures of GDY, essentially enable GDY as a new kind of electrode material for fundamental studies on carbon electrochemistry and various electroanalytical applications.

  8. Laser material micro-working (LMμW): some new surface processes

    Science.gov (United States)

    Daurelio, G.; D'Alonzo, M.

    2007-05-01

    On the last recent years many new Laser Surface Processes have been studied and tested in the field of the L.M. μW. - Laser Material Micro Working. Still today many of these "young" processes are to study and more and more searches are dedicated to they. These are the Marking, Texturing, Fine Texturing, Filling, Polishing, Micro Shot-Penning, Silking and Colouring. This experimental work reports the results obtained in the field of the Laser Surface Fine Texturing on AISI 304 and 430 Stainless Steels by using a Marking System, that is a Nd:YAG Laser, VECTORMARK type by TRUMPH ( D ). So some new laser surface finishes, called by Authors, - Effetto tessuto, con trama e ordito (Woven effect, with weft and warp) - Effetto pelle scamosciata ( Effect shammy leather ) - Effetto pelle uncinata ( Effect hooked skin ) - Effetto pelle unghiata ( Effect skin looking like scratch ) - Effetto pelle damascata ( Effect damask skin ) - Effetto speculare , ottonato ( Specular effect, looking like brass ) Effetto speculare, bronzato ( specular effect looking like bronze ) - Effetto speculare, argenteo ( specular, looking like silver effect ) - Effetto speculare, ramato ( Specular effect, looking like copper ), Effetto Speculare, dorato ( Specular effect, looking like gold ) - Effetto speculare , dorato, a raggiera ( Specular effect, looking like gold, to aureole) , were carried out. The work is still in progress.

  9. Bacterial colonization of resin composite cements: influence of material composition and surface roughness.

    Science.gov (United States)

    Glauser, Stephanie; Astasov-Frauenhoffer, Monika; Müller, Johannes A; Fischer, Jens; Waltimo, Tuomas; Rohr, Nadja

    2017-08-01

    So-called secondary caries may develop in the cement gap between the tooth and the bonded restoration. Cement materials with a low susceptibility to biofilm formation are therefore desirable. In the present study, the adhesion of Strepococcus mutans onto three adhesive (Multilink Automix, RelyX Ultimate, and Panavia V5) and three self-adhesive (Multilink Speed Cem, RelyX Unicem 2 Automix, and Panavia SA plus) resin composite cements was evaluated. Previous studies have failed to evaluate concomitantly the effect of both the composition of the cements and their surface roughness on biofilm formation. The presence of S. mutans on cement surfaces with differing degrees of roughness was therefore recorded using fluorescence microscopy and crystal violet staining, and the composition of the cements was analyzed using energy-dispersive X-ray spectroscopy mapping. Biofilm formation on resin composite cements was found to be higher on rougher surfaces, implying that adequate polishing of the cement gap is essential. The use of copper-containing cements (Multilink Automix, Panavia V5, and Panavia SA plus) significantly reduced biofilm formation. © 2017 Eur J Oral Sci.

  10. Simple surface sulfonation retards plasticiser migration and impacts upon blood/material contact activation processes.

    Science.gov (United States)

    Gourlay, Terence; Shedden, Laurie; Horne, David; Stefanou, Demetrios M

    2010-01-01

    The use of Di-2-ethylhexyl phthalate (DEHP) plasticised polyvinyl chloride (DEHPPPVC) in medical devices persists despite evidence suggesting that DEHP migration can be harmful. Researchers have shown that a simple surface sulfonation process can retard the migration of DEHP, which may reduce the associated inflammatory response. The present study is designed to investigate the effects of surface sulfonation on DEHP migration and blood contact activation using in vitro and rodent models. The study was carried out in two phases: phase 1, in which the migration rate of DEHP from DEHPPPVC and sulfonated DEHP plasticised PVC (SDEHPPPVC) was measured; phase 2 of the study, in which the materials were incorporated into a rat recirculation biomaterial test model and blood samples taken to assess CD11b expression on neutrophils, IL-6 and Factor XIIa. The initial DEHP concentration washed from the surface after storage was 37.19 +/- 1.17 mg/l in the PPVC group and 5.89 +/- 0.81 mg/l in the SPPVC group (psulfonation process significantly retards the migration of DEHP and is associated with the moderation of contact activation processes.

  11. Influence of material ductility and crack surface roughness on fracture instability

    International Nuclear Information System (INIS)

    Khezrzadeh, Hamed; Wnuk, Michael P; Yavari, Arash

    2011-01-01

    This paper presents a stability analysis for fractal cracks. First, the Westergaard stress functions are proposed for semi-infinite and finite smooth cracks embedded in the stress fields associated with the corresponding self-affine fractal cracks. These new stress functions satisfy all the required boundary conditions and according to Wnuk and Yavari's (2003 Eng. Fract. Mech. 70 1659-74) embedded crack model they are used to derive the stress and displacement fields generated around a fractal crack. These results are then used in conjunction with the final stretch criterion to study the quasi-static stable crack extension, which in ductile materials precedes the global failure. The material resistance curves are determined by solving certain nonlinear differential equations and then employed in predicting the stress levels at the onset of stable crack growth and at the critical point, where a transition to the catastrophic failure occurs. It is shown that the incorporation of the fractal geometry into the crack model, i.e. accounting for the roughness of the crack surfaces, results in (1) higher threshold levels of the material resistance to crack propagation and (2) higher levels of the critical stresses associated with the onset of catastrophic fracture. While the process of quasi-static stable crack growth (SCG) is viewed as a sequence of local instability states, the terminal instability attained at the end of this process is identified with the global instability. The phenomenon of SCG can be used as an early warning sign in fracture detection and prevention.

  12. Calculating the optical properties of defects and surfaces in wide band gap materials

    Science.gov (United States)

    Deák, Peter

    2018-04-01

    The optical properties of a material critically depend on its defects, and understanding that requires substantial and accurate input from theory. This paper describes recent developments in the electronic structure theory of defects in wide band gap materials, where the standard local or semi-local approximations of density functional theory fail. The success of the HSE06 screened hybrid functional is analyzed in case of Group-IV semiconductors and TiO2, and shown that it is the consequence of error compensation between semi-local and non-local exchange, resulting in a proper derivative discontinuity (reproduction of the band gap) and a total energy which is a linear function of the fractional occupation numbers (removing most of the electron self-interaction). This allows the calculation of electronic transitions with accuracy unseen before, as demonstrated on the single-photon emitter NV(-) center in diamond and on polaronic states in TiO2. Having a reliable tool for electronic structure calculations, theory can contribute to the understanding of complicated cases of light-matter interaction. Two examples are considered here: surface termination effects on the blinking and bleaching of the light-emission of the NV(-) center in diamond, and on the efficiency of photocatalytic water-splitting by TiO2. Finally, an outlook is presented for the application of hybrid functionals in other materials, as, e.g., ZnO, Ga2O3 or CuGaS2.

  13. Control of interior surface materials for speech privacy in high-speed train cabins.

    Science.gov (United States)

    Jang, H S; Lim, H; Jeon, J Y

    2017-05-01

    The effect of interior materials with various absorption coefficients on speech privacy was investigated in a 1:10 scale model of one high-speed train cabin geometry. The speech transmission index (STI) and privacy distance (r P ) were measured in the train cabin to quantify speech privacy. Measurement cases were selected for the ceiling, sidewall, and front and back walls and were classified as high-, medium- and low-absorption coefficient cases. Interior materials with high absorption coefficients yielded a low r P , and the ceiling had the largest impact on both the STI and r P among the interior elements. Combinations of the three cases were measured, and the maximum reduction in r P by the absorptive surfaces was 2.4 m, which exceeds the space between two rows of chairs in the high-speed train. Additionally, the contribution of the interior elements to speech privacy was analyzed using recorded impulse responses and a multiple regression model for r P using the equivalent absorption area. The analysis confirmed that the ceiling was the most important interior element for improving speech privacy. These results can be used to find the relative decrease in r P in the acoustic design of interior materials to improve speech privacy in train cabins. © 2016 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  14. Influence of bioactive materials used on the dentin surface whitened with carbamide peroxide 16%

    Directory of Open Access Journals (Sweden)

    Helena Burlamaqui Pinheiro

    2010-06-01

    Full Text Available This study investigated the influence of bioactive materials on the dentin surface whitened. MATERIAL AND METHODS: Three bovine teeth were shaped into three dentin wafers. Each wafer was then sectioned, into six dentin slices. One slice from each tooth was distributed into one of 6 groups: 1.CG = control group (distilled water; 2.WT = whitening treatment; 3.WT + MI Paste Plus, applied once a day; 4.WT + Relief ACP30, applied once a day for 30 mintes; 5.WT + Relief ACP60, applied once a day for 60 minutes; 6.WT + Biosilicate®, applied once a week. All groups were treated over 14 days. RESULTS: CG presented all dentinal tubules occluded by smear layer; WT group was observed all dentinal tubules opened. In the groups 3, 4 and 6, tubules were occluded. Group 5, dentinal tubules were completely occluded by mineral deposits. CONCLUSION: The use of bioactive materials immediately after whitening treatment can reduce or even avoid the demineralization effect of whitening and avoid exposing dentinal tubules.

  15. Influence of surface free energy of denture base and liner materials on Candida albicans biofilms.

    Science.gov (United States)

    da Silva, Wander J; Leal, Cristiane Maria B; Viu, Flávia C; Gonçalves, Letícia M; Barbosa, Célia Marisa R; Del Bel Cury, Altair A

    2015-05-01

    This study aimed to evaluate the influence of surface free energy (SFE) of denture base and liner materials on Candida albicans biofilm development. Discs were fabricated using poly(methyl methacrylate) acrylic resin and poly(ethyl methacrylate) denture liner, according to the manufacturers' instructions. For SFE test, discs were pellicle-coated with saliva alone, saliva + blood plasma, or blood plasma alone. Candida albicans biofilms were allowed to form on pellicle-coated discs for 48 h. Biofilms were evaluated for cell counts, metabolic activity, and structural characteristics at adhesion phase (after 1.5 h of development) and at biofilm maturity (after 48 h of development). Data were analyzed by anova and Tukey tests using a significance level of 5%. Saliva + blood plasma pellicles had a higher SFE compared to pellicles of saliva or blood plasma alone (P  0.05). In contrast, the presence of blood plasma resulted in higher cell counts, biovolume, and thickness of mature biofilms on both materials (P < 0.001). Increases in SFE from pellicle-coating leads to robust mature C. albicans biofilms on both denture materials. © 2014 Wiley Publishing Asia Pty Ltd.

  16. The effects of silane-SiO2 nanocomposite films on Candida albicans adhesion and the surface and physical properties of acrylic resin denture base material.

    Science.gov (United States)

    Yodmongkol, Sirasa; Chantarachindawong, Rojcharin; Thaweboon, Sroisiri; Thaweboon, Boonyanit; Amornsakchai, Taweechai; Srikhirin, Toemsak

    2014-12-01

    Polysiloxane has been used as a coupling material in restorative dental materials for several decades. However, few studies are available on the application of polysiloxane in other dental prosthesis functions. The purpose of this study was to investigate the effects of silane-SiO2 nanocomposite films on Candida albicans adhesion and the surface and physical properties of acrylic resin denture base materials. Specimens were separated into 2 groups, uncoated and coated. They were coated with a film by using the dip-coating method. Specimens were incubated with Candida albicans 10(7) cells/mL for 1 hour, and the adherent cells were counted under an optical microscope. The following surface properties were measured: surface chemical composition with Fourier-transform infrared spectrometry, surface roughness with a surface profiler, surface energy with the sessile drop method, and surface hardness with a microhardness tester. The physical properties, including water sorption, water solubility, ultimate flexural strength, and flexural modulus, were evaluated according to International Organization for Standardization 20795-1 requirements. The adhesion of Candida albicans and the surface properties of the specimens were investigated after cleaning with effervescent tablets and brushing. An MTT assay was used to evaluate the coated specimens. The results were statistically analyzed with the Mann-Whitney U test (α=.05). A significant reduction in Candida albicans adhesion (P=.002) was observed before cleaning. In addition, the surface energy was comparable (P=.100), the surface hardness increased significantly (P=.008), and the surface roughness remained unchanged (P=.310). After cleaning with effervescent tablets, a significant decrease in Candida albicans adhesion (P=.002) and in surface roughness (P=.008) was observed; however, similar surface energies were measured (P=.100). After cleaning with a toothbrush, the adhesion of Candida albicans was significantly higher on

  17. Hydrogel modified materials surfaces for the ERDA artificial heart. Final report

    International Nuclear Information System (INIS)

    Hoffman, A.S.

    1978-01-01

    This report summarizes a series of studies on the suitability of silicone surgical grafts. The studies performed include an evaluation of vena cava rings to study thrombogenicity of grafted polymer coatings, the interaction of platelets with radiation grafted polymers, an in vitro evaluation of knitted dacron artery sections, the tissue compatibility of HEMA-EMA copolymers, the in vitro cell adhesion to polymeric materials, and the use of the ESCA technique for determining HEMA/EMA ratios

  18. Protective or damage promoting effect of calcium carbonate layers on the surface of cement based materials in aqueous environments

    International Nuclear Information System (INIS)

    Schwotzer, M.; Scherer, T.; Gerdes, A.

    2010-01-01

    Cement based materials permanently exposed to aggressive aqueous environments are subject to chemical changes affecting their durability. However, this holds also for tap water that is considered to be not aggressive to cementitious materials, although in that case a formation of covering layers of CaCO 3 on the alkaline surfaces is commonly supposed to provide protection against reactive transport processes. Thus, investigations of the structural and chemical properties of the material/water interface were carried out in laboratory experiments and case studies to elucidate the consequences of surface reactions for the durability of cement based materials exposed to tap water. Focused Ion Beam investigations revealed that a protective effect of a CaCO 3 covering layer depends on its structural properties, which are in turn affected by the hydro-chemical conditions during crystallization. Surface precipitation of CaCO 3 can trigger further chemical degradation, if the required calcium is supplied by the pore solution of the material.

  19. The Impact and Oxidation Survival of Selected Meteoritic Compounds: Signatures of Asteroid Organic Material on Planetary Surfaces

    Science.gov (United States)

    Cooper, George; Horz, Fred; Oleary, Alanna; Chang, Sherwood

    2013-01-01

    Polar, non-volatile organic compounds may be present on the surfaces (or near surfaces) of multiple Solar System bodies. If found, by current or future missions, it would be desirable to determine the origin(s) of such compounds, e.g., asteroidal or in situ. To test the possible survival of meteoritic compounds both during impacts with planetary surfaces and under subsequent (possibly) harsh ambient conditions, we subjected known meteoritic compounds to relatively high impact-shock pressures and/or to varying oxidizing/corrosive conditions. Tested compounds include sulfonic and phosphonic acids (S&P), polyaromatic hydrocarbons (PAHs) amino acids, keto acids, dicarboxylic acids, deoxy sugar acids, and hydroxy tricarboxylic acids (Table 1). Meteoritic sulfonic acids were found to be relatively abundant in the Murchison meteorite and to possess unusual S-33 isotope anomalies (non mass-dependent isotope fractionations). Combined with distinctive C-S and C-P bonds, the S&P are potential signatures of asteroidal organic material.

  20. The decontamination of soft-plated nickel surfaces compared to alternative surface materials used in radioactive transport and storage containers

    International Nuclear Information System (INIS)

    Zwicky, H.U.; Bedenig, D.O.; Bohringer, I.M.; Petrik, F.

    1983-01-01

    Surfaces of raw, nickel-plated, and epoxy-coated spheroidal graphite cast iron, together with stainless steel, were contaminated with a modified fission product solution then conditioned by heat treatment. This was followed by a variety of simple decontamination techniques. It was shown that the ease of removal of contaminations similar to those expected on a dry storage container surface is significantly affected by the roughness of the surface. The raw cast iron surface was virtually impossible to significantly decontaminate. Highest decontamination factors were obtained on nickel-plated and epoxy-painted surfaces using steam/detergent mixtures. Stainless steel only performed well in a polished condition. In a supplementary irradiation experiment, scanning electron microscopy indicated visible decomposition of an epoxy-painted surface at a gamma dose of 3.1 X 10 6 Gy (3.1 X 10 8 rad). A nickel-plated surface did not undergo any visible changes at the same dose

  1. Durable protection of the surface of wood used outdoors: material constraints, problems and approaches to solutions

    Directory of Open Access Journals (Sweden)

    Merlin A.

    2018-01-01

    Full Text Available The aesthetic durability of wooden structures is a major challenge for the use of this material in construction. Wood is used for its technical performances but also for its architectural qualities and its aesthetic perception. The premature aging of the wooden structures is detrimental because these disorders, even if they do not affect the strength of the structures, are mostly irremediable. The surface protection of wood is generally ensured by the use of a finish, whose essential role is to protect wood from climatic aggressions (water, solar radiation, oxygen, .... The secondary wood processing industry consists of a series of manufacturing and processing activities, each containing a portion of the added value of the product. The application of a finish on a wood-based work is usually the last and most visible step in this value chain.In outdoor use, the protection of the wood surface with transparent finishes is not yet sufficiently durable to be able to compete with materials used in industrial carpentry such as PVC or aluminum. Opaque finishes generally provide more durable protection but they mask the appearance of the wood sought by users.With the aim of positioning wood in this construction sector, research on transparent finishes has focused on the efficiency and improvement of the durability of the protection of the surface appearance of structures. Faced with climatic aggressions, the optimum conservation of a structure is not only linked to the performance of the finish but also to the characteristics of the wood material. In particular, in order to fulfill its protective function, the finish film must be able to follow the dimensional variations of the wood it covers without breaking and without detachment. In addition to the criteria for the effectiveness of finishes in the protection of structures, the environmental impact must be considered with increasing attention. Currently, more than 80% of composite or solid wood

  2. 16 CFR 1145.2 - Paint (and other similar surface-coating materials) containing lead; toys, children's articles...

    Science.gov (United States)

    2010-01-01

    ... 16 Commercial Practices 2 2010-01-01 2010-01-01 false Paint (and other similar surface-coating materials) containing lead; toys, children's articles, and articles of furniture bearing such paint (or... TO OTHER ACTS UNDER THE CONSUMER PRODUCT SAFETY ACT § 1145.2 Paint (and other similar surface-coating...

  3. Lessons learned from the development and manufacture of ceramic reusable surface insulation materials for the space shuttle orbiters

    Science.gov (United States)

    Banas, R. P.; Elgin, D. R.; Cordia, E. R.; Nickel, K. N.; Gzowski, E. R.; Aguiler, L.

    1983-01-01

    Three ceramic, reusable surface insulation materials and two borosilicate glass coatings were used in the fabrication of tiles for the Space Shuttle orbiters. Approximately 77,000 tiles were made from these materials for the first three orbiters, Columbia, Challenger, and Discovery. Lessons learned in the development, scale up to production and manufacturing phases of these materials will benefit future production of ceramic reusable surface insulation materials. Processing of raw materials into tile blanks and coating slurries; programming and machining of tiles using numerical controlled milling machines; preparing and spraying tiles with the two coatings; and controlling material shrinkage during the high temperature (2100-2275 F) coating glazing cycles are among the topics discussed.

  4. Controlling Structure and Properties of High Surface Area Nonwoven Materials via Hydroentangling

    Science.gov (United States)

    Luzius, Dennis

    Hydroentangling describes a technique using a series of high-velocity water jets to mechanically interlock and entangle fibers. Over the last decades researchers worked on a fundamental understanding of the process and the factors influencing the properties of the final nonwoven material. Recent studies discovered hydroentangling to be capable to create unique, knot-like structures characterized by high- and low density regions, which are believed to have interesting properties for filtration applications. However, just little is known about the impact of hydroentangling parameters on the properties of filtration media to this day. In this study we report on the effect of various hydroentangling parameters, such as jet spacing, manifold pressure, number of manifolds but also specific energy on the structure and properties of high surface area nonwoven materials. Latter was achieved by different bicomponent fiber technologies and subsequent treatments removing the sacrificial compound from the structure. The highest BET surface area was measured to be 3.5 m2 g-1 and the smallest mean fiber size about 0.5 mum. Hydroentangling with large jet spacing was found to be a parameter significantly enhancing the filtration properties of caustic-treated island-in-the-sea nonwoven materials. Moreover, improved capture efficiencies and reduced pressure drops were achieved by reducing the manifold pressure and therefore specific energy during hydroentangling. Jet spacing but not island count was found to be the dominant factor influencing the structure and properties of island-in-the-sea nonwovens. Contrary to our initial expectations increasing the island count and thus decreasing the fiber size did not result in better filtration properties. Mixed media nonwoven structures made from homocomponent and island-in-the-sea fibers were found to have lower densities, higher air permeabilities and better quality factors compared to island-in-the-sea structures hydroentangled under the

  5. Surface Modification of Carbon Nanotubes with Conjugated Polyelectrolytes: Fundamental Interactions and Applications in Composite Materials, Nanofibers, Electronics, and Photovoltaics

    KAUST Repository

    Ezzeddine, Alaa

    2015-10-01

    Ever since their discovery, Carbon nanotubes (CNTs) have been renowned to be potential candidates for a variety of applications. Nevertheless, the difficulties accompanied with their dispersion and poor solubility in various solvents have hindered CNTs potential applications. As a result, studies have been developed to address the dispersion problem. The solution is in modifying the surfaces of the nanotubes covalently or non-covalently with a desired dispersant. Various materials have been employed for this purpose out of which polymers are the most common. Non-covalent functionalization of CNTs via polymer wrapping represents an attractive method to obtain a stable and homogenous CNTs dispersion. This method is able to change the surface properties of the nanotubes without destroying their intrinsic structure and preserving their properties. This thesis explores and studies the surface modification and solublization of pristine single and multiwalled carbon nanotubes via a simple solution mixing technique through non-covalent interactions of CNTs with various anionic and cationic conjugated polyelectrolytes (CPEs). The work includes studying the interaction of various poly(phenylene ethynylene) electrolytes with MWCNTs and an imidazolium functionalized poly(3-hexylthiophene) with SWCNTs. Our work here focuses on the noncovalent modifications of carbon nanotubes using novel CPEs in order to use these resulting CPE/CNT complexes in various applications. Upon modifying the CNTs with the CPEs, the resulting CPE/CNT complex has been proven to be easily dispersed in various organic and aqueous solution with excellent homogeneity and stability for several months. This complex was then used as a nanofiller and was dispersed in another polymer matrix (poly(methyl methacrylate), PMMA). The PMMA/CPE/CNT composite materials were cast or electrospun depending on their desired application. The presence of the CPE modified CNTs in the polymer matrix has been proven to enhance

  6. Influence of the surface quality due to a hole derived in initial material processing of cold sheets with drawing

    OpenAIRE

    Cvetkov, Slavco; Kocov, Atanas

    2010-01-01

    A research was performed about the influence of the surface quality due to a hole derived in initial material processing of cold-rolled steel sheets with drawing. This influence was researched through the surface quality obtained bu the type of preparation of the hole surface without prejudice to the precise measurement of the achieved quality (asperity). the aim is to indicate how the type of manufacturing the holes can improve the workability of cold-rolled sheets and help solve technical p...

  7. PREFACE: Exploring surfaces and buried interfaces of functional materials by advanced x-ray and neutron techniques Exploring surfaces and buried interfaces of functional materials by advanced x-ray and neutron techniques

    Science.gov (United States)

    Sakurai, Kenji

    2010-12-01

    This special issue is devoted to describing recent applications of x-ray and neutron scattering techniques to the exploration of surfaces and buried interfaces of various functional materials. Unlike many other surface-sensitive methods, these techniques do not require ultra high vacuum, and therefore, a variety of real and complicated surfaces fall within the scope of analysis. It must be particularly emphasized that the techniques are capable of seeing even buried function interfaces as well as the surface. Furthermore, the information, which ranges from the atomic to mesoscopic scale, is highly quantitative and reproducible. The non-destructive nature of the techniques is another important advantage of using x-rays and neutrons, when compared with other atomic-scale analyses. This ensures that the same specimen can be measured by other techniques. Such features are fairly attractive when exploring multilayered materials with nanostructures (dots, tubes, wires, etc), which are finding applications in electronic, magnetic, optical and other devices. The Japan Applied Physics Society has established a group to develop the research field of studying buried function interfaces with x-rays and neutrons. As the methods can be applied to almost all types of materials, from semiconductor and electronic devices to soft materials, participants have fairly different backgrounds but share a common interest in state-of-the-art x-ray and neutron techniques and sophisticated applications. A series of workshops has been organized almost every year since 2001. Some international interactions have been continued intensively, although the community is part of a Japanese society. This special issue does not report the proceedings of the recent workshop, although all the authors are in some way involved in the activities of the above society. Initially, we intended to collect quite long overview papers, including the authors' latest and most important original results, as well as

  8. Bond strength of novel CAD/CAM restorative materials to self-adhesive resin cement: the effect of surface treatments.

    Science.gov (United States)

    Elsaka, Shaymaa E

    2014-12-01

    To evaluate the effect of different surface treatments on the microtensile bond strength (μTBS) of novel CAD/CAM restorative materials to self-adhesive resin cement. Two types of CAD/CAM restorative materials (Vita Enamic [VE] and Lava Ultimate [LU]) were used. The specimens were divided into five groups in each test according to the surface treatment performed; Gr 1 (control; no treatment), Gr 2 (sandblasted [SB]), Gr 3 (SB+silane [S]), Gr 4 (hydrofluoric acid [HF]), and Gr 5 (HF+S). A dual-curing self-adhesive resin cement (Bifix SE [BF]) was applied to each group for testing the adhesion after 24 h of storage in distilled water or after 30 days using the μTBS test. Following fracture testing, specimens were examined with a stereomicroscope and SEM. Surface roughness and morphology of the CAD/CAM restorative materials were characterized after treatment. Data were analyzed using ANOVA and Tukey's test. The surface treatment, type of CAD/CAM restorative material, and water storage periods showed a significant effect on the μTBS (p0.05). On the other hand, for the VE/BF system, surface treatment with HF+S showed higher bond strength values compared with SB and HF surface treatments (pmaterials was modified after treatments. The effect of surface treatments on the bond strength of novel CAD/CAM restorative materials to resin cement is material dependent. The VE/BF CAD/CAM material provided higher bond strength values compared with the LU/BF CAD/CAM material.

  9. Effectiveness of a coral-derived surfacing material for reducing sediment production on unpaved roads, Schoffield barracks, Oahu, Hawaii.

    Science.gov (United States)

    Ziegler, Alan D; Sutherland, Ross A

    2006-01-01

    This study evaluated the effectiveness of two application rates of a coral-derived surfacing material for both traffic and nontraffic road conditions using simulated rainfall (110-120 mm h(-1) for 30-90 min) on 0.75-m (wide) x 5.0-m (long) plots of similar slope (roughly 0.1 m m(-1)). The coral is a locally available material that has been applied to unpaved roads surfaces on Schoffield Barracks, Oahu, Hawaii (USA), where this experiment was conducted. The simulations show that compared with a bare control plot, the coral-based surface application rates of 80 and 160 kg m(-2) (equivalent to only 10- and 20-mm thicknesses) reduced road sediment production by 75% and 95%, respectively, for nontraffic conditions. However, after two passes of the research vehicle during wet conditions, sediment production rates for the two coral treatments were not significantly different from those on the bare road plots. The overall effectiveness of the coral-derived surfacing material is unsatisfactory, primarily because the on-road surface thickness associated with the application rates tested was too small. These rates were selected to bracket those applied to training roads in the study area. Furthermore, the composition of the coral-based material does not facilitate the development of a sealed, erosion-resistant surface. When applied at the low rates tested, the coral material breaks down under normal traffic conditions, thereby losing its ability to counter shearing forces exerted by overland flow on long hillslopes where erosion measures are most needed. These simulations, combined with observations on roads in the study area, indicate that this material is not an appropriate road surfacing material for the site-at least for the low application rates examined. These results are preliminary; extended testing of higher applications rates at the hillslope scale under natural climate and traffic conditions is needed to better judge the effectiveness of this material over time.

  10. Surface, interface and thin film characterization of nano-materials using synchrotron radiation

    International Nuclear Information System (INIS)

    Kimura, Shigeru; Kobayashi, Keisuke

    2005-01-01

    From the results of studies in the nanotechnology support project of the Ministry of Education, Culture, Sports, Science and Technology of Japan, several investigations on the surface, interface and thin film characterization of nano-materials are described; (1) the MgB 2 thin film by X-ray diffraction, (2) the magnetism of the Pt thin film on a Co film by X-ray magnetic circular dichroism measurement, (3) the structure and physical properties of oxygen molecules absorbed in a micro hole of the cheleted polymer crystal by the direct observation in X-ray powder diffraction, and (4) the thin film gate insulator with a large dielectric constant, thermally treated HfO 2 /SiO 2 /Si, by X-ray photoelectron spectroscopy. (M.H.)

  11. Materials selection of surface coatings in an advanced size reduction facility

    International Nuclear Information System (INIS)

    Briggs, J.L.; Younger, A.F.

    1980-01-01

    A materials selection test program was conducted to characterize optimum interior surface coatings for an advanced size reduction facility. The equipment to be processed by this facility consists of stainless steel apparatus (e.g., glove boxes, piping, and tanks) used for the chemical recovery of plutonium. Test results showed that a primary requirement for a satisfactory coating is ease of decontamination. A closely related concern is the resistance of paint films to nitric acid - plutonium environments. A vinyl copolymer base paint was the only coating, of eight paints tested, with properties that permitted satisfactory decontamination of plutonium and also performed equal to or better than the other paints in the chemical resistance, radiation stability, and impact tests

  12. Mechanical Properties of Laminate Materials: From Surface Waves to Bloch Oscillations

    DEFF Research Database (Denmark)

    Liang, Z.; Willatzen, Morten; Christensen, Johan

    2015-01-01

    for designing Bloch oscillations in classical plate structures and show how mechanical Bloch oscillations can be generated in arrays of solid plates when the modal wavelength is gradually reduced. The design recipe describes how Bloch oscillations in classical structures of arbitrary dimensions can be generated......We propose hitherto unexplored and fully analytical insights into laminate elastic materials in a true condensed-matter-physics spirit. Pure mechanical surface waves that decay as evanescent waves from the interface are discussed, and we demonstrate how these designer Scholte waves are controlled......, and we demonstrate this numerically for structures with millimeter and centimeter dimensions in the kilohertz to megahertz range. Analytical predictions agree entirely with full wave simulations showing how elastodynamics can mimic quantum-mechanical condensed-matter phenomena....

  13. Field Trial of Resin-Based Composite Materials for the Treatment of Surface Collapses Associated with Former Shallow Coal Mining

    OpenAIRE

    Philip T. Broughton; Mark P. Bettney; Isla L. Smail

    2016-01-01

    Effective treatment of ground instability is essential when managing the impacts associated with historic mining. A field trial was undertaken by the Coal Authority to investigate the geotechnical performance and potential use of composite materials comprising resin and fill or stone to safely treat surface collapses, such as crown-holes, associated with shallow mining. Test pits were loosely filled with various granular fill materials. The fill material was injected with commercially availab...

  14. Ascertaining Grain Scale Effects Of Seismic Or Aseismic Stimulation Upon Strength Of Near Surface Geological Materials

    Directory of Open Access Journals (Sweden)

    Bilal Hassan

    2017-02-01

    Full Text Available Certain peculiarities of inelastic nonlinearity of unconsolidated near surface periodically stressed granular media contributed at micro- scale are investigated to ascertain possible anomalous time dependent strength behavior macro-effects with geotechnicalgeo-environmental implications. Comparative examination of ultrasonic P- and S-wave repeatable displacement response wave-forms in time records and spectra of pulse stimulated both confined dry and fully saturated ceramic grains analogue endorsable by pertinent theory is performed. Examination is primarily aimed at both understanding connectivity of louder response generated by seemingly unobtrusive quieter seismic and aseismic events in granular sediments. Secondarily results impart an enhanced conceptual substantiation of some previously disseminated andor published results. The results hint certain persistive time and frequency restricted occurrences vouching vital insights. It could be unambiguously clarified that subtle acoustic emission andor stick-slip type micro events in stimulated i.e. seismic or aseismic unconsolidated granular sediments do occur. When spread over time andor space their cumulated effect may be capable of altering granular material macro strength behavior. It is clearly deducible from resonant type spectral results that material fragmentation or force chain formation type phenomenon occurs possibly due to macro-scale friction mobilization by grain-scale events. It is further speculated that invisible high frequency events may irreversibly alter grain-scale surface properties andor intergranular friction as pseudo enhanced elasticity type effect more elusive with saturation. An assessment of an examined temporal distribution of grain-scale stick-slip type events when stimulated by P- and S-wave modes is posited to be non-identical. The former as if is retardation associated while the latter relaxation type in a characteristic sense. Presented result forms combined not

  15. Effects of Surface Morphology ZnAl2O4 of Ceramic Materials on Osteoblastic Cells Responses

    International Nuclear Information System (INIS)

    Suarez-Franco, J.L.; Fernandez-Pedrero, J.A.; Ivarez-Perez, M.A.; Garcia-Hipolito, M.; Surarez-Rosales, M.; Fregoso, O.; Juarez-Islas, J.A.; Ivarez-Perez, M.A.

    2013-01-01

    Ceramic scaffolds are widely studied in the tissue engineering field due to their potential in medical applications as bone substitutes or as bone-filling materials. The purpose of this study was to investigate the effect of surface morphology of nano structure thin films of ZnAl 2 O 4 prepared by spray pyrolysis and bulk pellets of polycrystalline ZnAl 2 O 4 prepared by chemical coprecipitation reaction on the in vitro cell adhesion, viability, and cell-material interactions of osteoblastic cells. Our result showed that cell attachment was significantly enhanced from 60 to 80% on the ZnAl 2 O 4 nano structured material surface when compared with bulk ceramic surfaces. Moreover, our results showed that the balance of morphological properties of the thin film nano structure ceramic improves cell-material interaction with enhanced spreading and filopodia with multiple cellular extensions on the surface of the ceramic and enhancing cell viability/proliferation in comparison with bulk ceramic surfaces used as control. Altogether, these results suggest that zinc aluminate nano structured materials have a great potential to be used in dental implant and bone substitute applications.Ceramic scaffolds are widely studied in the tissue engineering field due to their potential in medical applications as bone substitutes or as bone-filling materials. The purpose of this study was to investigate the effect of surface morphology of nano structure thin films of ZnAl 2 O 4 prepared by spray pyrolysis and bulk pellets of polycrystalline ZnAl 2 O 4 prepared by chemical coprecipitation reaction on the in vitro cell adhesion, viability, and cell-material interactions of osteoblastic cells. Our result showed that cell attachment was significantly enhanced from 60 to 80% on the ZnAl 2 O 4 nano structured material surface when compared with bulk ceramic surfaces. Moreover, our results showed that the balance of morphological properties of the thin film nano structure ceramic improves

  16. Experimental studies of lithium-based surface chemistry for fusion plasma-facing materials applications

    International Nuclear Information System (INIS)

    Allain, J.P.; Rokusek, D.L.; Harilal, S.S.; Nieto-Perez, M.; Skinner, C.H.; Kugel, H.W.; Heim, B.; Kaita, R.; Majeski, R.

    2009-01-01

    Lithium has enhanced the operational performance of fusion devices such as: TFTR, CDX-U, FTU, T-11 M, and NSTX. Lithium in the solid and liquid state has been studied extensively in laboratory experiments including its erosion and hydrogen-retaining properties. Reductions in physical sputtering up to 40-60% have been measured for deuterated solid and liquid lithium surfaces. Computational modeling indicates that up to a 1:1 deuterium volumetric retention in lithium is possible. This paper presents the results of systematic in situ laboratory experimental studies on the surface chemistry evolution of ATJ graphite under lithium deposition. Results are compared to post-mortem analysis of similar lithium surface coatings on graphite exposed to deuterium discharge plasmas in NSTX. Lithium coatings on plasma-facing components in NSTX have shown substantial reduction of hydrogenic recycling. Questions remain on the role lithium surface chemistry on a graphite substrate has on particle sputtering (physical and chemical) as well as hydrogen isotope recycling. This is particularly due to the lack of in situ measurements of plasma-surface interactions in tokamaks such as NSTX. Results suggest that the lithium bonding state on ATJ graphite is lithium peroxide and with sufficient exposure to ambient air conditions, lithium carbonate is generated. Correlation between both results is used to assess the role of lithium chemistry on the state of lithium bonding and implications on hydrogen pumping and lithium sputtering. In addition, reduction of factors between 10 and 30 reduction in physical sputtering from lithiated graphite compared to pure lithium or carbon is also measured.

  17. Laser-line rejection or transmission filters based on surface structures built on infrared transmitting materials

    Science.gov (United States)

    Hobbs, Douglas S.

    2005-05-01

    Night vision and related thermal imaging systems play a critical role in the protection of our nation's security. These systems record images using video cameras designed for operation in the infrared (IR) region of the light spectrum. As with any imaging system, increased functionality and new information is gained when discrete portions of the observed light spectrum are analyzed separately using optical filters. Highly di