WorldWideScience

Sample records for surface emission coefficient

  1. Determination of the surface drag coefficient

    DEFF Research Database (Denmark)

    Mahrt, L.; Vickers, D.; Sun, J.L.

    2001-01-01

    This study examines the dependence of the surface drag coefficient on stability, wind speed, mesoscale modulation of the turbulent flux and method of calculation of the drag coefficient. Data sets over grassland, sparse grass, heather and two forest sites are analyzed. For significantly unstable ...

  2. Plasma sheath properties calculated using measured secondary electron emission coefficients

    International Nuclear Information System (INIS)

    Pedgley, J.M.; McCracken, G.M.

    1993-01-01

    Measurements of secondary electron emission (SEE) are presented for graphite, hydrogen-implanted graphite and an amorphous graphite (a-C:H) carbon layer, over a wide range of energies and angles of incidence. These data have been integrated over a Maxwellian velocity distribution to simulate the effect of SEE due to plasma electrons. The SEE yields have then been used to calculate plasma sheath potentials, sheath heat transmission coefficients and sputtering yields for a range of ions as a function of plasma temperature. The increased SEE yield with temperature reduces the normalized sheath potential and increases the sheath transmission coefficient markedly. The role of space charge in the sheath is discussed. (Author)

  3. Measurement of Dynamic Friction Coefficient on the Irregular Free Surface

    International Nuclear Information System (INIS)

    Yeom, S. H.; Seo, K. S.; Lee, J. H.; Lee, K. H.

    2007-01-01

    A spent fuel storage cask must be estimated for a structural integrity when an earthquake occurs because it freely stands on ground surface without a restriction condition. Usually the integrity estimation for a seismic load is performed by a FEM analysis, the friction coefficient for a standing surface is an important parameter in seismic analysis when a sliding happens. When a storage cask is placed on an irregular ground surface, measuring a friction coefficient of an irregular surface is very difficult because the friction coefficient is affected by the surface condition. In this research, dynamic friction coefficients on the irregular surfaces between a concrete cylinder block and a flat concrete slab are measured with two methods by one direction actuator

  4. FTIR Emission spectroscopy of surfaces

    Science.gov (United States)

    Van Woerkom, P. C. M.

    A number of vibrational spectroscopic techniques are available For the study of surfaces, such as ATR, IR reflection-absorption, IR emission, etc. Infrared emission is hardly used, although interesting applications are possible now due to the high sensitivity of Fourier transform IR (FTIR) spectrometers. Two examples, where infrared emission measurements are very fruitful, will be given. One is the investigation of the curing behaviour of organic coatings, the other is the in situ study of heterogeneously catalyzed reactions. Undoubtedly, infrared emission measurements offer a number of specific advantages in some cases. Especially the less critical demands on the sample preparation are important.

  5. Retrieving complex surface impedances from statistical absorption coefficients

    DEFF Research Database (Denmark)

    Mondet, Boris Jean-Francois; Brunskog, Jonas; Jeong, Cheol-Ho

    2017-01-01

    coefficients, prior information about the absorber of interest can be used as constraints, which is shown to help determine the correct impedance from absorption coefficient. Further stability and sensitivity investigations indicate that the method presented constitutes an efficient solution to convert sound......In room acoustic simulations the surface materials are commonly represented with energy parameters, such as the absorption and scattering coefficients, which do not carry phase information. This paper presents a method to transform statistical absorption coefficients into complex surface impedances...... that the impedance found has a physical meaning and respects causality in the time domain. Known material models, such as Miki’s and Maa’s models, are taken as references to assess the validity of the suggested model. Due to the non-uniqueness of retrieving complex-valued impedances from real-valued absorption...

  6. Carbon emission coefficient measurement of the coal-to-power energy chain in China

    OpenAIRE

    Shiwei Yu; Yi-Ming Wei; Haixiang Guo; Liping Ding

    2012-01-01

    Coal-fired electricity generation has become the largest source of carbon emission in China. This study utilizes life-cycle assessment to assess the effect of carbon emissions and to calculate the coefficient of carbon emissions in coal-to-energy chains. Results show that the carbon emission coefficient of the coal-to-energy chain in China is 875 g/kW h-1, which is a relatively low level compared with that of other countries. CO2 is the main type of greenhouse gas emission and the most abunda...

  7. Lorenz curve and Gini coefficient reveal hot spots and hot moments for nitrous oxide emissions

    Science.gov (United States)

    Identifying hot spots and hot moments of N2O emissions in the landscape is critical for monitoring and mitigating the emission of this powerful greenhouse gas. We propose a novel use of the Lorenz curve and Gini coefficient (G) to quantify the heterogeneous distribution of N2O emissions from a lands...

  8. Determining the surface roughness coefficient by 3D Scanner

    Directory of Open Access Journals (Sweden)

    Karmen Fifer Bizjak

    2010-12-01

    Full Text Available Currently, several test methods can be used in the laboratory to determine the roughness of rock joint surfaces.However, true roughness can be distorted and underestimated by the differences in the sampling interval of themeasurement methods. Thus, these measurement methods produce a dead zone and distorted roughness profiles.In this paper a new rock joint surface roughness measurement method is presented, with the use of a camera-typethree-dimensional (3D scanner as an alternative to current methods. For this study, the surfaces of ten samples oftuff were digitized by means of a 3D scanner, and the results were compared with the corresponding Rock JointCoefficient (JRC values. Up until now such 3D scanner have been mostly used in the automotive industry, whereastheir use for comparison with obtained JRC coefficient values in rock mechanics is presented here for the first time.The proposed new method is a faster, more precise and more accurate than other existing test methods, and is apromising technique for use in this area of study in the future.

  9. Carbon emission coefficient measurement of the coal-to-power energy chain in China

    International Nuclear Information System (INIS)

    Yu, Shiwei; Wei, Yi-Ming; Guo, Haixiang; Ding, Liping

    2014-01-01

    Highlights: • CO 2 emissions coefficient of the coal-energy chain in China is currently at 875 g/kW h −1 . • The emission coefficient is a relatively low level compared with other countries. • CO 2 is the main type of GHG emission and the most direct emission in the chain. • A great decline of potential energy use exists in the coal mining process of China compared with other countries. - Abstract: Coal-fired electricity generation has become the largest source of carbon emission in China. This study utilizes life-cycle assessment to assess the effect of carbon emissions and to calculate the coefficient of carbon emissions in coal-to-energy chains. Results show that the carbon emission coefficient of the coal-to-energy chain in China is 875 g/kW h −1 , which is a relatively low level compared with that of other countries. CO 2 is the main type of greenhouse gas emission and is the most abundant type of direct emission. China has to reduce electrical consumption in the coal-mining process to reduce carbon emissions in coal-to-energy chains. Moreover, China has to facilitate railway-line construction to improve the proportion of railway transportation to coal transportation

  10. Rough surface mitigates electron and gas emission

    International Nuclear Information System (INIS)

    Molvik, A.

    2004-01-01

    Heavy-ion beams impinging on surfaces near grazing incidence (to simulate the loss of halo ions) generate copious amounts of electrons and gas that can degrade the beam. We measured emission coefficients of η e (le) 130 and η 0 ∼ 10 4 respectively, with 1 MeV K + incident on stainless steel. Electron emission scales as η e ∝ 1/cos(θ), where θ is the ion angle of incidence relative to normal. If we were to roughen a surface by blasting it with glass beads, then ions that were near grazing incidence (90 o ) on smooth surface would strike the rims of the micro-craters at angles closer to normal incidence. This should reduce the electron emission: the factor of 10 reduction, Fig. 1(a), implies an average angle of incidence of 62 o . Gas desorption varies more slowly with θ (Fig. 1(b)) decreasing a factor of ∼2, and along with the electron emission is independent of the angle of incidence on a rough surface. In a quadrupole magnet, electrons emitted by lost primary ions are trapped near the wall by the magnetic field, but grazing incidence ions can backscatter and strike the wall a second time at an azimuth where magnetic field lines intercept the beam. Then, electrons can exist throughout the beam (see the simulations of Cohen, HIF News 1-2/04). The SRIM (TRIM) Monte Carlo code predicts that 60-70% of 1 MeV K + ions backscatter when incident at 88-89 o from normal on a smooth surface. The scattered ions are mostly within ∼10 o of the initial direction but a few scatter by up to 90 o . Ion scattering decreases rapidly away from grazing incidence, Fig. 1(c ). At 62 deg. the predicted ion backscattering (from a rough surface) is 3%, down a factor of 20 from the peak, which should significantly reduce electrons in the beam from lost halo ions. These results are published in Phys. Rev. ST - Accelerators and Beams

  11. Reconstruction of emission coefficients for a non-axisymmetric coupling arc by algebraic reconstruction technique

    International Nuclear Information System (INIS)

    Zhang Guangjun; Xiong Jun; Gao Hongming; Wu Lin

    2011-01-01

    A preliminary investigation of tomographic reconstruction of an asymmetric arc plasma has been carried out. The objective of this work aims at reconstructing emission coefficients of a non-axisymmetric coupling arc from measured intensities by means of an algebraic reconstruction technique (ART). In order to define the optimal experimental scheme for good quality with limited views, the dependence of the reconstruction quality on three configurations (four, eight, ten projection angles) are presented and discussed via a displaced Gaussian model. Then, the emission coefficients of a free burning arc are reconstructed by the ART with the ten-view configuration and an Abel inversion, respectively, and good agreement is obtained. Finally, the emission coefficient profiles of the coupling arc are successfully achieved with the ten-view configuration. The results show that the distribution of emission coefficient for the coupling arc is different from centrosymmetric shape. The ART is perfectly suitable for reconstructing emission coefficients of the coupling arc with the ten-view configuration, proving the feasibility and utility of the ART to characterize an asymmetric arc.

  12. Electron emission at the rail surface

    International Nuclear Information System (INIS)

    Thornhill, L.; Battech, J.

    1991-01-01

    In this paper the authors examine the processes by which current is transferred from the cathode rail to the plasma armature in an arc-driven railgun. Three electron emission mechanisms are considered, namely thermionic emission, field-enhanced thermionic emission (or Schottky emission), and photoemission. The author's calculations show that the dominant electron emission mechanism depends, to a great extent, on the work function of the rail surface, the rail surface temperature, the electric field at the rail surface, and the effective radiation temperature of the plasma. For conditions that are considered to be typical of a railgun armature, Schottky emission is the dominant electron emission mechanism, providing current densities on the order of 10 9 A/m 2

  13. Temperature coefficient for modeling denitrification in surface water sediments using the mass transfer coefficient

    Science.gov (United States)

    T.W. Appelboom; G.M. Chescheir; F. Birgand; R.W. Skaggs; J.W. Gilliam; D. Amatya

    2010-01-01

    Watershed modeling has become an important tool for researchers. Modeling nitrate transport within drainage networks requires quantifying the denitrification within the sediments in canals and streams. In a previous study, several of the authors developed an equation using a term called a mass transfer coefficient to mathematically describe sediment denitrification....

  14. Temperature Coefficient for Modeling Denitrification in Surface Water Sediments Using the Mass Transfer Coefficient

    Science.gov (United States)

    T. W. Appelboom; G. M. Chescheir; R. W. Skaggs; J. W. Gilliam; Devendra M. Amatya

    2006-01-01

    Watershed modeling has become an important tool for researchers with the high costs of water quality monitoring. When modeling nitrate transport within drainage networks, denitrification within the sediments needs to be accounted for. Birgand et. al. developed an equation using a term called a mass transfer coefficient to mathematically describe sediment...

  15. Carbon emission coefficient of power consumption in India: baseline determination from the demand side

    International Nuclear Information System (INIS)

    Nag, Barnali; Parikh, J.K.

    2005-01-01

    Substantial investments are expected in the Indian power sector under the flexibility mechanisms (CDM/JI) laid down in Article 12 of the Kyoto Protocol. In this context it is important to evolve a detailed framework for baseline construction in the power sector so as to incorporate the major factors that would affect the baseline values directly or indirectly. It is also important to establish carbon coefficients from electricity generation to help consider accurate project boundaries for numerous electricity conservation and DSM schemes. The objective of this paper is to provide (i) time series estimates of indirect carbon emissions per unit of power consumption (which can also be thought of as emission coefficient of power consumption) and (ii) baseline emissions for the power sector till 2015. Annual time series data on Indian electricity generating industry, for 1974-1998, has been used to develop emission projections till 2015. The impacts of generation mix, fuel efficiency, transmission and distribution losses and auxiliary consumption are studied in a Divisia decomposition framework and their possible future impacts on baseline emissions are studied through three scenarios of growth in power consumption. The study also estimates and projects the carbon emission coefficient per unit of final consumption of electricity that can be used for conducting cost benefit of emission reduction potential for several electricity conserving technologies and benchmarking policy models

  16. Properties of C4F7N–CO2 thermal plasmas: thermodynamic properties, transport coefficients and emission coefficients

    Science.gov (United States)

    Wu, Yi; Wang, Chunlin; Sun, Hao; Murphy, Anthony B.; Rong, Mingzhe; Yang, Fei; Chen, Zhexin; Niu, Chunpin; Wang, Xiaohua

    2018-04-01

    The thermophysical properties, including composition, thermodynamic properties, transport coefficients and net emission coefficients, of thermal plasmas formed from pure iso-C4 perfluoronitrile C4F7N and C4F7N–CO2 mixtures are calculated for temperatures from 300 to 30 000 K and pressures from 0.1 to 20 atm. These gases have received much attention as alternatives to SF6 for use in circuit breakers, due to the low global warming potential and good dielectric properties of C4F7N. Since the parameters of the large molecules formed in the dissociation of C4F7N are unavailable, the partition function and enthalpy of formation were calculated using computational chemistry methods. From the equilibrium composition calculations, it was found that when C4F7N is mixed with CO2, CO2 can capture C atoms from C4F7N, producing CO, since the system consisting of small molecules such as CF4 and CO has lower energy at room temperature. This is in agreement with previous experimental results, which show that CO dominates the decomposition products of C4F7N–CO2 mixtures; it could limit the repeated breaking performance of C4F7N. From the point of view of chemical stability, the mixing ratio of CO2 should therefore be chosen carefully. Through comparison with common arc quenching gases (including SF6, CF3I and C5F10O), it is found that for the temperature range for which electrical conductivity remains low, pure C4F7N has similar ρC p (product of mass density and specific heat) properties to SF6, and higher radiative emission coefficient, properties that are correlated with good arc extinguishing capability. For C4F7N–CO2 mixtures, the electrical conductivity is very close to that of SF6 while the ρC p peak at 7000 K caused by decomposition of CO implies inferior interruption capability to that of SF6. The calculated properties will be useful in arc simulations.

  17. ASTER L2 Surface Emissivity V003

    Data.gov (United States)

    National Aeronautics and Space Administration — The ASTER L2 Surface Emissivity is an on-demand product generated using the five thermal infrared (TIR) bands (acquired either during the day or night time) between...

  18. Secondary electron emission from textured surfaces

    Science.gov (United States)

    Huerta, C. E.; Patino, M. I.; Wirz, R. E.

    2018-04-01

    In this work, a Monte Carlo model is used to investigate electron induced secondary electron emission for varying effects of complex surfaces by using simple geometric constructs. Geometries used in the model include: vertical fibers for velvet-like surfaces, tapered pillars for carpet-like surfaces, and a cage-like configuration of interlaced horizontal and vertical fibers for nano-structured fuzz. The model accurately captures the secondary electron emission yield dependence on incidence angle. The model shows that unlike other structured surfaces previously studied, tungsten fuzz exhibits secondary electron emission yield that is independent of primary electron incidence angle, due to the prevalence of horizontally-oriented fibers in the fuzz geometry. This is confirmed with new data presented herein of the secondary electron emission yield of tungsten fuzz at incidence angles from 0-60°.

  19. Influence of Local Airflow on the Pollutant Emission from Indoor Building Surfaces

    DEFF Research Database (Denmark)

    Topp, Claus; Nielsen, Peter Vilhelm; Heiselberg, Per Kvols

    2001-01-01

    for the prediction of surface emissions is proposed. The work focused on the emission of vapours and gases and no particulate emissions were considered. The methods used were numerical calculations by computational fluid dynamics (CFD) and full-scale laboratory experiments. It was found that the emissions...... are a strong function of air-change rate, local air velocity and local turbulence, as the mass transfer coefficient increases in proportion to these parameters. The findings further show that the mass transfer coefficient increases in proportion to the velocity when the emission is controlled by evaporation...

  20. Exploring global Cryptosporidium emissions to surface water.

    Science.gov (United States)

    Hofstra, N; Bouwman, A F; Beusen, A H W; Medema, G J

    2013-01-01

    The protozoan parasite Cryptosporidium is a major cause of diarrhoea worldwide. This paper presents the first model-based inventory with 0.5 by 0.5 degree resolution of global Cryptosporidium emissions for the year 2000 from humans and animals to surface water. The model is based on nutrient distribution modelling, because the sources and transport of oocysts and nutrients to the surface water are comparable. Total emissions consist of point source emissions from wastewater and nonpoint source emissions by runoff of oocysts in manure from agricultural lands. Results indicate a global emission of 3 × 10(17) oocysts per year, with comparable contributions from point and nonpoint sources. Hot-spot areas for point sources are big cities in China, India and Latin America, while the area with the largest nonpoint source emissions is in China. Uncertainties in the model are large. Main areas for further study are (i) excretion rates of oocysts by humans and animals, (ii) emissions of humans not connected to sewage systems, and (iii) retention of oocysts to determine surface water pathogen concentrations rather than emissions. Our results are useful to health organisations to identify priority areas for further study and intervention. Copyright © 2012 Elsevier B.V. All rights reserved.

  1. Spectral emissivity of surface blackbody calibrators

    DEFF Research Database (Denmark)

    Clausen, Sønnik

    2007-01-01

    in emissivity using similar materials can be reduced to 0.5-1% by optimizing the coating process and the surface geometry. Results are discussed and an equation for calculation of the equivalent blackbody surface temperature from FTIR spectra is presented, including reflected ambient radiation. It is in most......The normal spectral emissivity of commercial infrared calibrators is compared with measurements of anodized aluminum samples and grooved aluminum surfaces coated with Pyromark. Measurements performed by FTIR spectroscopy in the wavelength interval from 2 to 20 mu m and at temperatures between 5...... and 550 degrees C are presented with absolute uncertainties from 0.25% to 1% in spectral regions with sufficient signal and no significant atmospheric gas absorption. A large variation in emissivity with wavelength is observed for some surfaces, i.e., from 1% to 3% to more than 10%. The variation...

  2. Determination of emissivity coefficient of heat-resistant super alloys and cemented carbide

    Directory of Open Access Journals (Sweden)

    Kieruj Piotr

    2016-12-01

    Full Text Available This paper presents the analysis of emissivity engineering materials according to temperature. Experiment is concerned on difficult to machine materials, which may be turned with laser assisting. Cylindrical samples made of nickel-based alloys Inconel 625, Inconel 718, Waspaloy and tungsten-carbides based on cobalt matrix were analyzed. The samples’ temperature in contact method was compared to the temperature measured by non-contact pyrometers. Based on this relative, the value of the emissivity coefficient was adjusted to the right indication of pyrometers.

  3. Far-infrared surface emissivity and climate.

    Science.gov (United States)

    Feldman, Daniel R; Collins, William D; Pincus, Robert; Huang, Xianglei; Chen, Xiuhong

    2014-11-18

    Presently, there are no global measurement constraints on the surface emissivity at wavelengths longer than 15 μm, even though this surface property in this far-IR region has a direct impact on the outgoing longwave radiation (OLR) and infrared cooling rates where the column precipitable water vapor (PWV) is less than 1 mm. Such dry conditions are common for high-altitude and high-latitude locations, with the potential for modeled climate to be impacted by uncertain surface characteristics. This paper explores the sensitivity of instantaneous OLR and cooling rates to changes in far-IR surface emissivity and how this unconstrained property impacts climate model projections. At high latitudes and altitudes, a 0.05 change in emissivity due to mineralogy and snow grain size can cause a 1.8-2.0 W m(-2) difference in the instantaneous clear-sky OLR. A variety of radiative transfer techniques have been used to model the far-IR spectral emissivities of surface types defined by the International Geosphere-Biosphere Program. Incorporating these far-IR surface emissivities into the Representative Concentration Pathway (RCP) 8.5 scenario of the Community Earth System Model leads to discernible changes in the spatial patterns of surface temperature, OLR, and frozen surface extent. The model results differ at high latitudes by as much as 2°K, 10 W m(-2), and 15%, respectively, after only 25 y of integration. Additionally, the calculated difference in far-IR emissivity between ocean and sea ice of between 0.1 and 0.2, suggests the potential for a far-IR positive feedback for polar climate change.

  4. Tire-to-Surface Friction-Coefficient Measurements with a C-123B Airplane on Various Runway Surfaces

    Science.gov (United States)

    Sawyer, Richard H.; Kolnick, Joseph J.

    1959-01-01

    An investigation was conducted to obtain information on the tire-to-surface friction coefficients available in aircraft braking during the landing run. The tests were made with a C-123B airplane on both wet and dry concrete and bituminous pavements and on snow-covered and ice surfaces at speeds from 12 to 115 knots. Measurements were made of the maximum (incipient skidding) friction coefficient, the full-skidding (locked wheel) friction coefficient, and the wheel slip ratio during braking.

  5. Exploring global Cryptosporidium emissions to surface water

    NARCIS (Netherlands)

    Hofstra, N.; Bouwman, A.F.; Beusen, A.H.W.; Medema, G.J.

    2013-01-01

    The protozoan parasite Cryptosporidium is a major cause of diarrhoea worldwide. This paper presents the first model-based inventory with 0.5 by 0.5 degree resolution of global Cryptosporidium emissions for the year 2000 from humans and animals to surface water. The model is based on nutrient

  6. Calculation of total cross sections and effective emission coefficients for B5+ collisions with ground-state and excited hydrogen

    International Nuclear Information System (INIS)

    Guzman, F; Errea, L F; Illescas, Clara; Mendez, L; Pons, B

    2010-01-01

    Classical and semiclassical calculations of nl-resolved charge exchange cross sections in B 5 + collisions with H(n i ) are performed to compute effective emission coefficients for the n = 7 → n = 6 transition in B 4 + for plasma conditions typical of the ASDEX-U tokamak. For n i = 1, the value of the emission coefficient is larger than that obtained from ADAS database by a factor of 2 at energies of 10 keV amu -1 , but no differences are found at energies above 50 keV amu -1 . For n i = 2, our calculation yields emission coefficients close to those derived from ADAS data from low to high impact energies. The emission coefficients corresponding to B 5 + + H(n i = 3) collisions are of the same order of magnitude as those for n i = 2.

  7. The heat transfer coefficients of the heating surface of 300 MWe CFB boiler

    Science.gov (United States)

    Wu, Haibo; Zhang, Man; Lu, Qinggang; Sun, Yunkai

    2012-08-01

    A study of the heat transfer about the heating surface of three commercial 300 MWe CFB boilers was conducted in this work. The heat transfer coefficients of the platen heating surface, the external heat exchanger (EHE) and cyclone separator were calculated according to the relative operation data at different boiler loads. Moreover, the heat transfer coefficient of the waterwall was calculated by heat balance of the hot circuit of the CFB boiler. With the boiler capacity increasing, the heat transfer coefficients of these heating surface increases, and the heat transfer coefficient of the water wall is higher than that of the platen heating surface. The heat transfer coefficient of the EHE is the highest in high boiler load, the heat transfer coefficient of the cyclone separator is the lowest. Because the fired coal is different from the design coal in No.1 boiler, the ash content of the fired coal is much lower than that of the design coal. The heat transfer coefficients which calculated with the operation data are lower than the previous design value and that is the reason why the bed temperature is rather high during the boiler operation in No.1 boiler.

  8. Experimental Study on the Tensile Strength and Linear Expansion Coefficient of Air Tunnel Terrazzo Surface

    Directory of Open Access Journals (Sweden)

    Boping Li

    2015-01-01

    Full Text Available At present, studies on the surface tension of air tunnel terrazzo under wind load and how regularly it is affected by temperature are relatively less, and the measured results of the thermal expansion coefficient of terrazzo have not yet been given. In this paper, based on the top terrazzo surface structure of the inner wall of the wind tunnel, the tensile performance tests of terrazzo surface layer are conducted, while the thermal expansion coefficient of the six terrazzo test blocks were tested. The tests and analysis show that the construction of terrazzo surface, based on the proposed construction process, can effectively guarantee the reliable cement performance for the binding layer between mortar and concrete base layer, terrazzo surface layer and the cement mortar layer. And the thermal expansion coefficient of terrazzo can be valued at 1.06e-5/ºC.

  9. Extracting surface diffusion coefficients from batch adsorption measurement data: application of the classic Langmuir kinetics model.

    Science.gov (United States)

    Chu, Khim Hoong

    2017-11-09

    Surface diffusion coefficients may be estimated by fitting solutions of a diffusion model to batch kinetic data. For non-linear systems, a numerical solution of the diffusion model's governing equations is generally required. We report here the application of the classic Langmuir kinetics model to extract surface diffusion coefficients from batch kinetic data. The use of the Langmuir kinetics model in lieu of the conventional surface diffusion model allows derivation of an analytical expression. The parameter estimation procedure requires determining the Langmuir rate coefficient from which the pertinent surface diffusion coefficient is calculated. Surface diffusion coefficients within the 10 -9 to 10 -6  cm 2 /s range obtained by fitting the Langmuir kinetics model to experimental kinetic data taken from the literature are found to be consistent with the corresponding values obtained from the traditional surface diffusion model. The virtue of this simplified parameter estimation method is that it reduces the computational complexity as the analytical expression involves only an algebraic equation in closed form which is easily evaluated by spreadsheet computation.

  10. Tuning apparent friction coefficient by controlled patterning bulk metallic glasses surfaces

    Science.gov (United States)

    Li, Ning; Xu, Erjiang; Liu, Ze; Wang, Xinyun; Liu, Lin

    2016-12-01

    Micro-honeycomb structures with various pitches between adjacent cells were hot-embossed on Zr35Ti30Cu8.25Be26.75 bulk metallic glass surface. The effect of pitch geometry on the frictional behavior of metallic glass surface was systematically investigated. The results revealed that all textured metallic glass surfaces show a reduction in friction coefficient compared to smooth surface. More intriguingly, the friction coefficient first decreased and then increased gradually with increasing pitches. Such unique behavior can be understood fundamentally from the perspective of competing effects between contact area and local stress level with increasing pitches. This finding not only enhance the in-depth understanding of the mechanism of the significant role of surface topography on the frictional behavior of metallic glass surface, but also opens a new route towards other functional applications for bulk metallic glasses.

  11. Experimental heat transfer coefficients between a surface and fixed and fluidized beds with PCM

    OpenAIRE

    Izquierdo-Barrientos, María Asunción; Sobrino, Celia; Almendros-Ibáñez, José Antonio

    2015-01-01

    This work presents an experimental study to determine the capacity of a phase change material (PCM) in granular form to be used in fixed and bubbling fluidized beds for thermal energy storage. The experimental measurements are focused on determination of the heat transfer coefficient between a heated surface immersed in the bed and the granular PCM. The flow rate is varied to quantify its influence on the heat transfer coefficient. The PCM used is Rubitherm GR50 with a phase change tem...

  12. Sustained frictional instabilities on nanodomed surfaces: Stick-slip amplitude coefficient

    DEFF Research Database (Denmark)

    Quignon, Benoit; Pilkington, Georgia A.; Thormann, Esben

    2013-01-01

    properties and their measured friction coefficients was identified. Furthermore, all the nanodomed textures exhibited pronounced oscillations in the shear traces, similar to the classic stick-slip behavior, under all the shear velocities and load regimes studied. That is, the nanotextured topography led...... to sustained frictional instabilities, effectively with no contact frictional sliding. The amplitude of the stick-slip oscillations, σf, was found to correlate with the topographic properties of the surfaces and scale linearly with the applied load. In line with the friction coefficient, we define the slope...... of this linear plot as the stick-slip amplitude coefficient (SSAC). We suggest that such stick-slip behaviors are characteristics of surfaces with nanotextures and that such local frictional instabilities have important implications to surface damage and wear. We thus propose that the shear characteristics...

  13. Influence of surface modification on friction coefficient of the titanium-elastomer couple.

    Science.gov (United States)

    Chladek, Wiesław; Hadasik, Eugeniusz; Chladek, Grzegorz

    2007-01-01

    This paper presents the results of a study of the friction coefficient of titanium-elastomer couple. The study was carried out with a view to potential future utilization of its results for constructing retentive elements of implanted prostheses. Changes in the friction force were recorded while removing titanium specimens placed between two silicone counter specimens made of Ufi Gel. The influence of the titanium specimen movement speed in relation that of to the counter specimens and the influence of clamping force on the friction force were assessed. Additionally, the surface roughness of titanium specimens differed; in one case, titanium was coated with polyethylene. The effect of introducing artificial saliva between the cooperating surfaces on the friction force and friction coefficient was analyzed as well. Based on the characteristics recorded, the possibilities of shaping the friction coefficient have been assessed, since it is the friction coefficient that determines effective operation of a friction couple through increasing the titanium specimen roughness. The artificial saliva being introduced between the specimens reduces considerably the friction coefficient through a change of the phenomenon model. An increase in the pressure force for the specimens of high roughness entails a reduction of the friction coefficient. The study carried out allows us to identify the roughness parameters, which in turn will enable obtaining the prescribed retention force for friction/membrane couplings.

  14. Estimation of the friction coefficient between wheel and rail surface using traction motor behaviour

    International Nuclear Information System (INIS)

    Zhao, Y; Liang, B; Iwnicki, S

    2012-01-01

    The friction coefficient between a railway wheel and rail surface is a crucial factor in maintaining high acceleration and braking performance of railway vehicles thus monitoring this friction coefficient is important. Restricted by the difficulty in directly measuring the friction coefficient, the creep force or creepage, indirect methods using state observers are used more frequently. This paper presents an approach using a Kalman filter to estimate the creep force and creepage between the wheel and rail and then to identify the friction coefficient using the estimated creep force-creepage relationship. A mathematic model including an AC motor, wheel and roller is built to simulate the driving system. The parameters are based on a test rig at Manchester Metropolitan University. The Kalman filter is designed to estimate the friction coefficient based on the measurements of the simulation model. Series of residuals are calculated through the comparison between the estimated creep force and theoretical values of different friction coefficient. Root mean square values of the residuals are used in the friction coefficient identification.

  15. Experimental rig to estimate the coefficient of friction between tire and surface in airplane touchdown simulations.

    Science.gov (United States)

    Li, Chengwei; Zhan, Liwei

    2015-08-01

    To estimate the coefficient of friction between tire and runway surface during airplane touchdowns, we designed an experimental rig to simulate such events and to record the impact and friction forces being executed. Because of noise in the measured signals, we developed a filtering method that is based on the ensemble empirical mode decomposition and the bandwidth of probability density function of each intrinsic mode function to extract friction and impact force signals. We can quantify the coefficient of friction by calculating the maximum values of the filtered force signals. Signal measurements are recorded for different drop heights and tire rotational speeds, and the corresponding coefficient of friction is calculated. The result shows that the values of the coefficient of friction change only slightly. The random noise and experimental artifact are the major reason of the change.

  16. Simultaneous reconstruction of emission activity and attenuation coefficient distribution from TOF data, acquired with external transmission source

    International Nuclear Information System (INIS)

    Panin, V Y; Aykac, M; Casey, M E

    2013-01-01

    The simultaneous PET data reconstruction of emission activity and attenuation coefficient distribution is presented, where the attenuation image is constrained by exploiting an external transmission source. Data are acquired in time-of-flight (TOF) mode, allowing in principle for separation of emission and transmission data. Nevertheless, here all data are reconstructed at once, eliminating the need to trace the position of the transmission source in sinogram space. Contamination of emission data by the transmission source and vice versa is naturally modeled. Attenuated emission activity data also provide additional information about object attenuation coefficient values. The algorithm alternates between attenuation and emission activity image updates. We also proposed a method of estimation of spatial scatter distribution from the transmission source by incorporating knowledge about the expected range of attenuation map values. The reconstruction of experimental data from the Siemens mCT scanner suggests that simultaneous reconstruction improves attenuation map image quality, as compared to when data are separated. In the presented example, the attenuation map image noise was reduced and non-uniformity artifacts that occurred due to scatter estimation were suppressed. On the other hand, the use of transmission data stabilizes attenuation coefficient distribution reconstruction from TOF emission data alone. The example of improving emission images by refining a CT-based patient attenuation map is presented, revealing potential benefits of simultaneous CT and PET data reconstruction. (paper)

  17. Measurement of Turbulent Skin Friction Drag Coefficients Produced by Distributed Surface Roughness of Pristine Marine Coatings

    DEFF Research Database (Denmark)

    Zafiryadis, Frederik; Meyer, Knud Erik; Gökhan Ergin, F.

    Skin friction drag coefficients are determined for marine antifouling coatings in pristine condition by use of Constant Temperature Anemometry (CTA) with uni-directionalhot-wires. Mean flow behaviour for varying surface roughness is analysed in zero pressure gradient, flat plate, turbulentboundary...... drag coefficients as well as roughness Reynolds numbers for the various marine coatings across the range of Rex by fitting of the van Driest profile. The results demonstrate sound agreement with the present ITTC method for determining skin friction coefficients for practically smooth surfaces at low...... layers for Reynolds numbers from Rex =1:91x105 to Rex = 9:54x105. The measurements were conducted at the Technical University of Denmark in a closed-loop wind tunnel redesigned for investigations as this. Ensemble averages of the boundary layer velocity profiles allowed for determination of skin friction...

  18. Influence of the convective surface transfer coefficients on the Heat, Air, and Moisture (HAM) building performance

    DEFF Research Database (Denmark)

    Steskens, Paul Wilhelmus Maria Hermanus; Janssen, Hans; Rode, Carsten

    2009-01-01

    Current models to predict heat, air and moisture (HAM) conditions in buildings assume constant boundary conditions for the temperature and relative humidity of the neighbouring air and for the surface heat and moisture transfer coefficients. These assumptions may introduce errors in the predicted...... influence on the predicted hygrothermal conditions at the surface of a building component and on the heat and vapour exchange with the indoor environment....

  19. Quality-factor and reflection-coefficient estimation using reflected surface waves

    NARCIS (Netherlands)

    Draganov, D.S.; Ruigrok, E.N.; Ghose, R.; Mikesell, D.; Van Wijk, K.

    2014-01-01

    We propose a method for estimating the reflection coefficient of a subvertical boundary and the the quality factor of the medium between a receiver and the subvertical boundary. The method uses surface waves from transient deterministic sources and is inspired by the occurrence of non-physical

  20. Effects of bridge cable surface roughness and cross-sectional distortion on aerodynamic force coefficients

    DEFF Research Database (Denmark)

    Matteoni, G.; Georgakis, C.T.

    2012-01-01

    of their inherent surface roughness and shape, which might present a significant disturbance for the surrounding wind flow. The present study focuses on the experimental determination, based on static wind tunnel tests, of the aerodynamic coefficients of full-scale bridge cable section models both perpendicular...

  1. Impact of overall and particle surface heat transfer coefficients on thermal process optimization in rotary retorts.

    Science.gov (United States)

    Simpson, R; Abakarov, A; Almonacid, S; Teixeira, A

    2008-10-01

    This study attempts to examine the significance of recent research that has focused on efforts to estimate values for global and surface heat transfer coefficients under forced convection heating induced by end-over-end rotation in retorting of canned peas in brine. The study confirms the accuracy of regression analysis used to predict values for heat transfer coefficients as a function of rotating speed and headspace, and uses them to predict values over a range of process conditions, which make up the search domain for process optimization. These coefficients were used in a convective heat transfer model to establish a range of lethality-equivalent retort temperature-time processes for various conditions of retort temperature, rotating speed, and headspace. Then, they were coupled with quality factor kinetics to predict the final volume average and surface quality retention resulting from each process and to find the optimal thermal process conditions for canned fresh green peas. Results showed that maximum quality retention (surface and volume average retention) was achieved with the shortest possible process time (made possible with highest retort temperature), and reached the similar level in all cases with small difference between surface and volume average quality retention. The highest heat transfer coefficients (associated with maximum rotating speed and headspace) showed a 10% reduction in process time over that required with minimum rotating speed and headspace. The study concludes with a discussion of the significance of these findings and degree to which they were expected.

  2. Self-affine roughness influence on the friction coefficient for rubbers onto solid surfaces

    NARCIS (Netherlands)

    Palasantzas, G

    2004-01-01

    In this paper we investigate the influence of self-affine roughness on the friction coefficient mu(f) of a rubber body under incomplete contact onto a solid surface. The roughness is characterized by the rms amplitude w, the correlation length xi, and the roughness exponent H. It is shown that with

  3. Calculation of the net emission coefficient of an air thermal plasma at very high pressure

    International Nuclear Information System (INIS)

    Billoux, T; Cressault, Y; Teulet, Ph; Gleizes, A

    2012-01-01

    The aim of this paper is to present an accurate evaluation of the phenomena appearing for high pressure air plasmas supposed to be in local thermodynamic equilibrium (LTE). In the past, we already calculated the net emission coefficient for air mixtures at atmospheric pressure and for temperatures up to 30kK (molecular contribution being restricted to 10kK). Unfortunately, the existence of high pressures does not allow us to use this database due to the non-ideality of the plasma (Viriel and Debye corrections, energy cut-off ...), and due to the significant shifts of molecular reactions towards upper temperatures. Consequently, this paper proposes an improvement of our previous works with a consideration of high pressure corrections in the composition algorithm in order to take into account the pressure effects, and with a new calculation of all the contributions of the plasma radiation (atomic lines and continuum, molecular continuum, and molecular bands) using an updated database. A particular attention is paid to calculate the contribution of all the major molecular band systems to the radiation: O 2 (Schumann–Runge), N 2 (VUV, 1st and 2nd positive), NO (IR, β, γ, δ, element of ) and N 2 + (1st negative and Meinel). The discrete atomic lines and molecular bands radiation including the overlapping are calculated by a line-by-line method up to 30kK and 100 bar. This updated database is validated in the case of optically thin plasmas and pressure of 1bar by the comparison of our integrated emission strength with the published results. Finally, this work shows the necessity to extend the molecular radiation database up to 15kK at high pressure (bands and continuum) since their corresponding contributions could not be neglected at high temperature.

  4. A universal empirical expression for the isotope surface exchange coefficients (k*) of acceptor-doped perovskite and fluorite oxides.

    Science.gov (United States)

    De Souza, R A

    2006-02-21

    The isotope surface exchange coefficient k* determined in an 18O/16O exchange experiment characterises the exchange flux of the dynamic equilibrium between oxygen in the gas phase and oxygen in a solid oxide. At present there is no atomistic expression that relates measured exchange coefficients to materials' parameters. In this study an empirical, atomistic expression is developed that describes the exchange kinetics of gaseous oxygen with diverse acceptor-doped perovskite and fluorite oxides at temperatures above T approximately 900 K. The expression is used to explain the observed correlations between surface exchange coefficients k* and oxygen tracer diffusion coefficients D* and to identify compounds that exhibit high surface exchange coefficients.

  5. Determination of the potential energy surfaces of refrigerant mixtures and their gas transport coefficients

    Directory of Open Access Journals (Sweden)

    Song Bo

    2017-01-01

    Full Text Available In this work, the inversion scheme was used to determine the potential energy surfaces of five polar refrigerant mixtures. The systems studied here are R123-R134a, R123-R142b, R123-R152a, R142b-R134a, and R142b-R152a. The low density transport coefficients of the refrigerant mixtures were calculated from the new invert potentials by the classical kinetic theory. The viscosity coefficient, binary diffusion coefficient, and thermal diffusion factor were computed for the temperature range from 313.15-973.15 K. The agreement with the NIST viscosity data demonstrates that the present calculated values are accurate enough to supplement experimental data over an extended temperature range. Correlations of the transport properties were also provided for the refrigerant mixtures at equimolar ratios.

  6. Collisional Dissociation of CO: ab initio Potential Energy Surfaces and Quasiclassical Trajectory Rate Coefficients

    Science.gov (United States)

    Schwenke, David W.; Jaffe, Richard L.; Chaban, Galina M.

    2016-01-01

    We have generated accurate global potential energy surfaces for CO+Ar and CO+O that correlate with atom-diatom pairs in their ground electronic states based on extensive ab initio electronic structure calculations and used these potentials in quasi-classical trajectory nuclear dynamics calculations to predict the thermal dissociation rate coefficients over 5000- 35000 K. Our results are not compatible with the 20-45 year old experimental results. For CO + Ar we obtain fairly good agreement with the experimental rate coefficients of Appleton et al. (1970) and Mick and Roth (1993), but our computed rate coefficients exhibit a stronger temperature dependence. For CO + O our dissociation rate coefficient is in close agreement with the value from the Park model, which is an empirical adjustment of older experimental results. However, we find the rate coefficient for CO + O is only 1.5 to 3.3 times larger than CO + Ar over the temperature range of the shock tube experiments (8000-15,000 K). The previously accepted value for this rate coefficient ratio is 15, independent of temperature. We also computed the rate coefficient for the CO + O ex- change reaction which forms C + O2. We find this reaction is much faster than previously believed and is the dominant process in the removal of CO at temperatures up to 16,000 K. As a result, the dissociation of CO is accomplished in two steps (react to form C+O2 and then O2 dissociates) that are endothermic by 6.1 and 5.1 eV, instead of one step that requires 11.2 eV to break the CO bond.

  7. The surface diffusion coefficient for an arbitrarily curved fluidfluid interface.(II). Coefficient for plane-parallel diffusion

    NARCIS (Netherlands)

    Sagis, L.M.C.

    2001-01-01

    In this paper we developed an expression for the coefficient for plane-parallel diffusion for an arbitrarily curved fluid–fluid interface. The expression is valid for ordinary diffusion in binary mixtures, with isotropic bulk phases and an interfacial region that is isotropic in the plane parallel

  8. Some experimental data on accommodation coefficients for the noble ions on metal surfaces

    International Nuclear Information System (INIS)

    Gusev, K.I.; Rijov, Y.A.; Shkarban, I.I.

    1974-01-01

    Methods and results of experimental measurements of energy accommodation for Ar + , Kr + , and Xe + ions with initial energy E 0 - 100-500eV bombarding Cu, Mo, Ag and other (including Mo - monocrystal) foil target are presented. The angular dependencies for the energy accommodation coefficient are obtained within the range of angle phi=0+70 deg (phi is the angle between the target surface normal and the beam direction)

  9. Experimental investigation of thermal conductivity coefficient and heat exchange between fluidized bed and inclined exchange surface

    Directory of Open Access Journals (Sweden)

    B. Stojanovic

    2009-06-01

    Full Text Available The paper presents experimental research of thermal conductivity coefficients of the siliceous sand bed fluidized by air and an experimental investigation of the particle size influence on the heat transfer coefficient between fluidized bed and inclined exchange surfaces. The measurements were performed for the specific fluidization velocity and sand particle diameters d p=0.3, 0.5, 0.9 mm. The industrial use of fluidized beds has been increasing rapidly in the past 20 years owing to their useful characteristics. One of the outstanding characteristics of a fluidized bed is that it tends to maintain a uniform temperature even with nonuniform heat release. On the basis of experimental research, the influence of the process's operational parameters on the obtained values of the bed's thermal conductivity has been analyzed. The results show direct dependence of thermal conductivity on the intensity of mixing, the degree of fluidization, and the size of particles. In the axial direction, the coefficients that have been treated have values a whole order higher than in the radial direction. Comparison of experimental research results with experimental results of other authors shows good agreement and the same tendency of thermal conductivity change. It is well known in the literature that the value of the heat transfer coefficient is the highest in the horizontal and the smallest in the vertical position of the heat exchange surface. Variation of heat transfer, depending on inclination angle is not examined in detail. The difference between the values of the relative heat transfer coefficient between vertical and horizontal heater position for all particle sizes reduces by approximately 15% with the increase of fluidization rate.

  10. The stochastic distribution of available coefficient of friction for human locomotion of five different floor surfaces.

    Science.gov (United States)

    Chang, Wen-Ruey; Matz, Simon; Chang, Chien-Chi

    2014-05-01

    The maximum coefficient of friction that can be supported at the shoe and floor interface without a slip is usually called the available coefficient of friction (ACOF) for human locomotion. The probability of a slip could be estimated using a statistical model by comparing the ACOF with the required coefficient of friction (RCOF), assuming that both coefficients have stochastic distributions. An investigation of the stochastic distributions of the ACOF of five different floor surfaces under dry, water and glycerol conditions is presented in this paper. One hundred friction measurements were performed on each floor surface under each surface condition. The Kolmogorov-Smirnov goodness-of-fit test was used to determine if the distribution of the ACOF was a good fit with the normal, log-normal and Weibull distributions. The results indicated that the ACOF distributions had a slightly better match with the normal and log-normal distributions than with the Weibull in only three out of 15 cases with a statistical significance. The results are far more complex than what had heretofore been published and different scenarios could emerge. Since the ACOF is compared with the RCOF for the estimate of slip probability, the distribution of the ACOF in seven cases could be considered a constant for this purpose when the ACOF is much lower or higher than the RCOF. A few cases could be represented by a normal distribution for practical reasons based on their skewness and kurtosis values without a statistical significance. No representation could be found in three cases out of 15. Copyright © 2013 Elsevier Ltd and The Ergonomics Society. All rights reserved.

  11. Surface renewal as a significant mechanism for dust emission

    Directory of Open Access Journals (Sweden)

    J. Zhang

    2016-12-01

    Full Text Available Wind tunnel experiments of dust emissions from different soil surfaces are carried out to better understand dust emission mechanisms. The effects of surface renewal on aerodynamic entrainment and saltation bombardment are analyzed in detail. It is found that flow conditions, surface particle motions (saltation and creep, soil dust content and ground obstacles all strongly affect dust emission, causing its rate to vary over orders of magnitude. Aerodynamic entrainment is highly effective, if dust supply is unlimited, as in the first 2–3 min of our wind tunnel runs. While aerodynamic entrainment is suppressed by dust supply limits, surface renewal through the motion of surface particles appears to be an effective pathway to remove the supply limit. Surface renewal is also found to be important to the efficiency of saltation bombardment. We demonstrate that surface renewal is a significant mechanism affecting dust emission and recommend that this mechanism be included in future dust models.

  12. Empirical mapping of the convective heat transfer coefficients with local hot spots on highly conductive surfaces

    Directory of Open Access Journals (Sweden)

    Tekelioğlu Murat

    2017-01-01

    Full Text Available An experimental method was proposed to assess the natural and forced convective heat transfer coefficients on highly conductive bodies. Experiments were performed at air velocities of 0m/s, 4.0m/s, and 5.4m/s, and comparisons were made between the current results and available literature. These experiments were extended to arbitrary-shape bodies. External flow conditions were maintained throughout. In the proposed method, in determination of the surface convective heat transfer coefficients, flow condition is immaterial, i.e., either laminar or turbulent. With the present method, it was aimed to acquire the local heat transfer coefficients on any arbitrary conductive shape. This method was intended to be implemented by the heat transfer engineer to identify the local heat transfer rates with local hot spots. Finally, after analyzing the proposed experimental results, appropriate decisions can be made to control the amount of the convective heat transfer off the surface. Limited mass transport was quantified on the cooled plate.

  13. Simulation calculations of physical sputtering and reflection coefficient of plasma-irradiated carbon surface

    International Nuclear Information System (INIS)

    Kawamura, T.; Ono, T.; Yamamura, Y.

    1994-08-01

    Physical sputtering yields from the carbon surface irradiated by the boundary plasma are obtained with the use of a Monte Carlo simulation code ACAT. The yields are calculated for many random initial energy and angle values of incident protons or deuterons with a Maxwellian velocity distribution, and then averaged. Here the temperature of the boundary plasma, the sheath potential and the angle δ between the magnetic field line and the surface normal are taken into account. A new fitting formula for an arrangement of the numerical data of sputtering yield is introduced, in which six fitting parameters are determined from the numerical results and listed. These results provide a way to estimate the erosion of carbon materials irradiated by boundary plasma. The particle reflection coefficients for deuterons and their neutrals from a carbon surface are also calculated by the same code and presented together with, for comparison, that for the case of monoenergetic normal incidence. (author)

  14. Measurement of thermal accommodation coefficients of inert gas mixtures on a surface of stainless steel

    Science.gov (United States)

    Jun, Byung Soon

    Heat transfer in the fuel-clad gap in a nuclear reactor impacts the overall temperature distribution, stored energy and the mechanical properties of a nuclear fuel rod. Therefore, an accurate estimation of the gap conductance between the UO2 fuel and the clad is critically important for reactor design and operations. To obtain the requisite accuracy in the gap conductance estimation, the thermal accommodation coefficients of the various gases present on the fuel outer surface and the cladding inner surface are very important. In present work, we studied the stainless steel that is the most favored cladding material for advanced gas-cooled reactors. Our goal was to obtain the thermal accommodation coefficients of select inert gases and mixtures of the same on this stainless steel. It has been found for pure helium, pure argon and select He-Ar mixtures that the thermal accommodation coefficient values with stainless steel are very close to constant over the range of pressures studied. The values obtained in this work are in good agreement with similar values reported previously in the literature. As far as we aware, these measurements are the first made of the thermal accommodation coefficients of inert gas mixtures on stainless steel. To aid in the verification of the kinetic theory, additional experiments were done using a two-sphere system and were analyzed using the equivalent sphere approximation. It is found that this theory can be applicable to spherical geometry problems and can be used for a wide range of values of the Knudsen number (Kn). Some sensitivity studies were performed to delineate some key parameter effect in terms of cooling rate, DeltaT difference, and Knudsen number.

  15. Field Measurements of PCB emissions from Building Surfaces Using a New Portable Emission Test Cell

    DEFF Research Database (Denmark)

    Lyng, Nadja; Haven, Rune; Gunnarsen, Lars Bo

    2016-01-01

    Danish elementary school. The emission test cell was capable of measuring widely varying specific emission rates of PCBtotal (8-3357 ng/(m2·h)). Remediated measures were found to reduce the emission rates by more than 96% compared with similar untreated surfaces. Emission rates may be affected...... by the conditions in the test cell (such as clean air and increased air velocity) and thereby potentially be different without the test cell attached to the surface. Still the measured emission rates obtained by using the test cell are valuable for determination of mitigation strategies. Additionally the test cell...

  16. Field emission from the surface of highly ordered pyrolytic graphite

    Energy Technology Data Exchange (ETDEWEB)

    Knápek, Alexandr, E-mail: knapek@isibrno.cz [Institute of Scientific Instruments of the ASCR, v.v.i., Královopolská 147, Brno (Czech Republic); Sobola, Dinara; Tománek, Pavel [Department of Physics, FEEC, Brno University of Technology, Technická 8, Brno (Czech Republic); Pokorná, Zuzana; Urbánek, Michal [Institute of Scientific Instruments of the ASCR, v.v.i., Královopolská 147, Brno (Czech Republic)

    2017-02-15

    Highlights: • HOPG shreds were created and analyzed in the UHV conditions. • Current-voltage measurements have been done to confirm electron tunneling, based on the Fowler-Nordheim theory. • Surface was characterized by other surface evaluation methods, in particular by: SNOM, SEM and AFM. - Abstract: This paper deals with the electrical characterization of highly ordered pyrolytic graphite (HOPG) surface based on field emission of electrons. The effect of field emission occurs only at disrupted surface, i.e. surface containing ripped and warped shreds of the uppermost layers of graphite. These deformations provide the necessary field gradients which are required for measuring tunneling current caused by field electron emission. Results of the field emission measurements are correlated with other surface characterization methods such as scanning near-field optical microscopy (SNOM) or atomic force microscopy.

  17. Noise emission of concrete pavement surfaces produced by diamond grinding

    Directory of Open Access Journals (Sweden)

    Jens Skarabis

    2015-04-01

    Full Text Available In Germany, diamond grinding is frequently used to improve the evenness and skid resistance of concrete pavement surfaces. Since diamond grinding has been observed to affect tyre/pavement noise emission favourably, the relationship among surface texture, concrete composition and noise emission of concrete pavement surfaces has been systematically investigated. The simulation program SPERoN was used in a parameter study to investigate the main factors which affect noise emission. Based on the results of the simulations, textured concrete surfaces were produced by using a laboratory grinding machine. As well as the composition of the concrete, the thickness and spacing of the diamond blades were varied. The ability of the textured surfaces to reduce noise emission was assessed from the texture characteristics and air flow resistance of textured surfaces measured in the laboratory. It was found that concrete composition and, in particular, the spacing of the blades affected the reduction in noise emission considerably. The noise emission behaviour of numerous road sections was also considered in field investigations. The pavement surfaces had been textured by diamond grinding during the last years or decades. The results show that diamond grinding is able to provide good, durable noise-reducing properties. Several new pavement sections were investigated using thicknesses and spacings of the blades similar to those used in the laboratory to optimize noise emission reduction. It is concluded that diamond grinding is a good alternative to exposed aggregate concrete for the production of low-noise pavement surfaces.

  18. The influence of the surface composition of mixed monolayer films on the evaporation coefficient of water.

    Science.gov (United States)

    Miles, Rachael E H; Davies, James F; Reid, Jonathan P

    2016-07-20

    We explore the dependence of the evaporation coefficient of water from aqueous droplets on the composition of a surface film, considering in particular the influence of monolayer mixed component films on the evaporative mass flux. Measurements with binary component films formed from long chain alcohols, specifically tridecanol (C13H27OH) and pentadecanol (C15H31OH), and tetradecanol (C14H29OH) and hexadecanol (C16H33OH), show that the evaporation coefficient is dependent on the mole fractions of the two components forming the monolayer film. Immediately at the point of film formation and commensurate reduction in droplet evaporation rate, the evaporation coefficient is equal to a mole fraction weighted average of the evaporation coefficients through the equivalent single component films. As a droplet continues to diminish in surface area with continued loss of water, the more-soluble, shorter alkyl chain component preferentially partitions into the droplet bulk with the evaporation coefficient tending towards that through a single component film formed simply from the less-soluble, longer chain alcohol. We also show that the addition of a long chain alcohol to an aqueous-sucrose droplet can facilitate control over the degree of dehydration achieved during evaporation. After undergoing rapid gas-phase diffusion limited water evaporation, binary aqueous-sucrose droplets show a continued slow evaporative flux that is limited by slow diffusional mass transport within the particle bulk due to the rapidly increasing particle viscosity and strong concentration gradients that are established. The addition of a long chain alcohol to the droplet is shown to slow the initial rate of water loss, leading to a droplet composition that remains more homogeneous for a longer period of time. When the sucrose concentration has achieved a sufficiently high value, and the diffusion constant of water has decreased accordingly so that bulk phase diffusion arrest occurs in the monolayer

  19. Low-order aberration coefficients applied to design of telescopes with freeform surfaces

    Science.gov (United States)

    Stone, Bryan D.; Howard, Joseph M.

    2017-09-01

    As the number of smallsats and cubesats continues to increase [1], so does the interest in the space optics community to miniaturize reflective optical instrumentation for these smaller platforms. Applications of smallsats are typically for the Earth observing community, but recently opportunities for them are being made available for planetary science, heliophysics and astrophysics concepts [2]. With the smaller satellite platforms come reduced instrument sizes that they accommodate, but the specifications such as field of view and working f/# imposed on the smaller optical systems are often the same, or even more challenging. To meet them, and to "fit in the box", it is necessary to employ additional degrees of freedom to the optical design. An effective strategy to reduce package size is to remove rotational symmetry constraints on the system layout, allowing it to minimize the unused volume by applying rigid body tilts and decenters to mirrors. Requirements for faster systems and wider fields of view can be addressed by allowing optical surfaces to become "freeform" in shape, essentially removing rotational symmetry constraints on the mirrors themselves. This dual approach not only can reduce package size, but also can allow for increased fields of view with improved image quality. Tools were developed in the 1990s to compute low-order coefficients of the imaging properties of asymmetric tilted and decentered systems [3][4]. That approach was then applied to reflective systems with plane symmetry, where the coefficients were used to create closed-form constraints to reduce the number of degrees of freedom of the design space confronting the designer [5][6]. In this paper we describe the geometric interpretation of these coefficients for systems with a plane of symmetry, and discuss some insights that follow for the design of systems without closed-form constraints. We use a common three-mirror design form example to help illustrate these concepts, and

  20. Changes in the surface roughness and friction coefficient of orthodontic bracket slots before and after treatment.

    Science.gov (United States)

    Liu, Xiaomo; Lin, Jiuxiang; Ding, Peng

    2013-01-01

    In this study, we tested the surface roughness of bracket slots and the friction coefficient between the bracket and the stainless steel archwire before and after orthodontic treatment. There were four experimental groups: groups 1 and 2 were 3M new and retrieved brackets, respectively, and groups 3 and 4 were BioQuick new and retrieved brackets, respectively. All retrieved brackets were taken from patients with the first premolar extraction and using sliding mechanics to close the extraction space. The surface roughness of specimens was evaluated using an optical interferometry profilometer, which is faster and nondestructive compared with a stylus profilometer, and provided a larger field, needing no sample preparation, compared with atomic force microscopy. Orthodontic treatment resulted in significant increases in surface roughness and coefficient of friction for both brands of brackets. However, there was no significant difference by brand for new or retrieved brackets. These retrieval analysis results highlight the necessity of reevaluating the properties and clinical behavior of brackets during treatment to make appropriate treatment decisions. © Wiley Periodicals, Inc.

  1. Electron emission during multicharged ion-metal surface interactions

    International Nuclear Information System (INIS)

    Zeijlmans van Emmichoven, P.A.; Havener, C.C.; Hughes, I.G.; Overbury, S.H.; Robinson, M.T.; Zehner, D.M.; Meyer, F.W.

    1992-01-01

    The electron emission during multicharged ion-metal surface interactions will be discussed. The interactions lead to the emission of a significant number of electrons. Most of these electrons have energies below 30 eV. For incident ions with innershell vacancies the emission of Auger electrons that fill these vacancies has been found to occur mainly below the surface. We will present recently measured electron energy distributions which will be used to discuss the mechanisms that lead to the emission of Auger and of low-energy electrons

  2. EPMA-EDS surface measurements of interdiffusion coefficients between miscible metals in thin films

    International Nuclear Information System (INIS)

    Christien, F.; Pierson, J.F.; Hassini, A.; Capon, F.; Le Gall, R.; Brousse, T.

    2010-01-01

    A new technique is developed to study interdiffusion between two miscible metals. The technique is applied to the Ni-Pd system. It consists in measuring the change of apparent surface composition of a Pd substrate coated with an 800 nm Ni thin film during annealing at a given temperature. The measurement is carried out in-situ inside the chamber of a SEM (scanning electron microscope) by EPMA-EDS (electron probe microanalysis-energy dispersive X-ray spectroscopy). The experimental data are processed using a model that mixes the Fick's diffusion equations and the electron probe microanalysis equation. This process allows the determination of the mean interdiffusion coefficient at a given annealing temperature. The main advantages of the technique are the possible determination of interdiffusion coefficients in thin films and at very low temperature (down to 430 deg. C, i.e. ∼0.4 T m ), which is not achievable with other techniques conventionally used for the study of interdiffusion. The Ni-Pd mean interdiffusion coefficient is shown to follow an Arrhenius law (D-tilde c =6.32x10 -3 exp((178.8kJmol -1 )/(RT) )cm 2 s -1 ) between 430 deg. C and 900 deg. C, in relatively good agreement with previous interdiffusion measurements made on the Ni-Pd system at higher temperature.

  3. Land Surface Microwave Emissivity Dynamics: Observations, Analysis and Modeling

    Science.gov (United States)

    Tian, Yudong; Peters-Lidard, Christa D.; Harrison, Kenneth W.; Kumar, Sujay; Ringerud, Sarah

    2014-01-01

    Land surface microwave emissivity affects remote sensing of both the atmosphere and the land surface. The dynamical behavior of microwave emissivity over a very diverse sample of land surface types is studied. With seven years of satellite measurements from AMSR-E, we identified various dynamical regimes of the land surface emission. In addition, we used two radiative transfer models (RTMs), the Community Radiative Transfer Model (CRTM) and the Community Microwave Emission Modeling Platform (CMEM), to simulate land surface emissivity dynamics. With both CRTM and CMEM coupled to NASA's Land Information System, global-scale land surface microwave emissivities were simulated for five years, and evaluated against AMSR-E observations. It is found that both models have successes and failures over various types of land surfaces. Among them, the desert shows the most consistent underestimates (by approx. 70-80%), due to limitations of the physical models used, and requires a revision in both systems. Other snow-free surface types exhibit various degrees of success and it is expected that parameter tuning can improve their performances.

  4. Sliding motion modulates stiffness and friction coefficient at the surface of tissue engineered cartilage.

    Science.gov (United States)

    Grad, S; Loparic, M; Peter, R; Stolz, M; Aebi, U; Alini, M

    2012-04-01

    Functional cartilage tissue engineering aims to generate grafts with a functional surface, similar to that of authentic cartilage. Bioreactors that stimulate cell-scaffold constructs by simulating natural joint movements hold great potential to generate cartilage with adequate surface properties. In this study two methods based on atomic force microscopy (AFM) were applied to obtain information about the quality of engineered graft surfaces. For better understanding of the molecule-function relationships, AFM was complemented with immunohistochemistry. Bovine chondrocytes were seeded into polyurethane scaffolds and subjected to dynamic compression, applied by a ceramic ball, for 1h daily [loading group 1 (LG1)]. In loading group 2 (LG2), the ball additionally oscillated over the scaffold, generating sliding surface motion. After 3 weeks, the surfaces of the engineered constructs were analyzed by friction force and indentation-type AFM (IT-AFM). Results were complemented and compared to immunohistochemical analyses. The loading type significantly influenced the mechanical and histological outcomes. Constructs of LG2 exhibited lowest friction coefficient and highest micro- and nanostiffness. Collagen type II and aggrecan staining were readily observed in all constructs and appeared to reach deeper areas in loaded (LG1, LG2) compared to unloaded scaffolds. Lubricin was specifically detected at the top surface of LG2. This study proposes a quantitative AFM-based functional analysis at the micrometer- and nanometer scale to evaluate the quality of cartilage surfaces. Mechanical testing (load-bearing) combined with friction analysis (gliding) can provide important information. Notably, sliding-type biomechanical stimuli may favor (re-)generation and maintenance of functional articular surfaces and support the development of mechanically competent engineered cartilage. Copyright © 2012 Osteoarthritis Research Society International. Published by Elsevier Ltd. All rights

  5. Analytical expressions of the imaging and aberration coefficients of a general form surface.

    Science.gov (United States)

    Yang, Liu; Qi, Jin Wei; Bin, Zhu

    2017-12-01

    A theoretical development is presented in this paper for describing and understanding the imaging and aberrations of a general form surface. The development is based on the Taylor expansion of an arbitrary ray trace from the object reference plane to the image reference plane, which is called the base mapping of the general form surface in this paper. The base mapping is expressed as two Taylor series of the object and pupil coordinates and the imaging and aberration coefficients in the third-order scope are derived and presented as analytical expressions relevant to the optic parameters, invoking no approximations. The situation with tilted object and observing plane is also considered, and the mapping from a tilted object to a tilted observing plane is derived via simple mathematical manipulations based on the base mapping.

  6. Slip safety risk analysis of surface properties using the coefficients of friction of rocks.

    Science.gov (United States)

    Çoşkun, Gültekin; Sarıışık, Gencay; Sarıışık, Ali

    2017-12-19

    This study was conducted to determine the most appropriate surface processing techniques (SPT), environmental conditions (EC) and surface roughness (SR) to minimize the risk of slipping when pedestrians walk on a floor covering of rocks barefoot and with shoes. Coefficients of friction (COFs) and values of SR were found using five different types of rocks, four SPT and two (ramp and pendulum) tests. Results indicate that the parameters which affect the COF values of rocks include SR, EC and SPT. Simple linear regression was performed to examine the relationship between the values of the COF and the SR. The value of the COF was identified as R 2  ≥ 0.864. Statistical results, which are based on experimental measurements, show that rocks are classified according to their safe use areas depending on their COF and SR values.

  7. Effect of the coefficient of friction of a running surface on sprint time in a sled-towing exercise.

    Science.gov (United States)

    Linthorne, Nicholas P; Cooper, James E

    2013-06-01

    This study investigated the effect of the coefficient of friction of a running surface on an athlete's sprint time in a sled-towing exercise. The coefficients of friction of four common sports surfaces (a synthetic athletics track, a natural grass rugby pitch, a 3G football pitch, and an artificial grass hockey pitch) were determined from the force required to tow a weighted sled across the surface. Timing gates were then used to measure the 30-m sprint time for six rugby players when towing a sled of varied weight across the surfaces. There were substantial differences between the coefficients of friction for the four surfaces (micro = 0.21-0.58), and in the sled-towing exercise the athlete's 30-m sprint time increased linearly with increasing sled weight. The hockey pitch (which had the lowest coefficient of friction) produced a substantially lower rate of increase in 30-m sprint time, but there were no significant differences between the other surfaces. The results indicate that although an athlete's sprint time in a sled-towing exercise is affected by the coefficient offriction of the surface, the relationship relationship between the athlete's rate of increase in 30-m sprint time and the coefficient of friction is more complex than expected.

  8. Effects of self-affine surface roughness on the friction coefficient of rubbers in the presence of a liquid interlayer

    NARCIS (Netherlands)

    Palasantzas, G; De Hosson, JTM

    2004-01-01

    In this article, we investigate how the friction coefficient is affected by the presence of a liquid layer in between a self-affine rough surface and a sliding rubber surface. The liquid layer will reduce energy dissipation from the small surface asperities and cavities of lateral sizes smaller than

  9. Theoretical model of fast electron emission from surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Reinhold, C.; Burgdoerfer, J. [Univ. of Tennessee, Knoxville, TN (United States)]|[Oak Ridge National Laboratory, TN (United States)

    1993-05-01

    Electron emission in glancing-angle ion-surface collisions has become a focus of ion-surface interactions. Electron spectra can provide detailed information on the above surface neutralization dynamics of multiply charged ions, the electronic structure of the surface (surface density of states), and the long-ranged image interactions near the surface. Recent experiments have found that the convoy peak, well known from ion-atom and ion-solid collisions, is dramatically altered. The peak is broadened and shifted in energy which has been attributed to dynamical image interactions. We present a microscopic model for the emission of fast electrons in glancing-angle surface collisions. A classical trajectory Monte Carlo approach is utilized to calculate the evolution of electrons in the presence of their self image, the projectile Coulomb field and the image potential induced by the projectile. The excitation of collective surface modes is also incorporated.

  10. Uptake Coefficients of NO3 Radicals on Solid Surfaces of Sea-Salts

    Science.gov (United States)

    Gratpanche, F.; Sawerysyn, J.-P.

    1999-02-01

    Uptake coefficients of nitrate radicals (γ NO_3) have been measured by a technique involving a coated-wall flow tube with radical detection by E.P.R. spectrometry. The variation of NO3 concentration in the gas phase was followed indirectly by monitoring OH radicals produced by the titration reaction H + NO_3. The mean initial value of γ NO3 measured on solid NaCl surfaces was (1.7± 1.2)× 10-2) in the temperature range 258-301 K, while for solid NaBr surfaces the value was (0.11 ± 0.06) at 293 K. In each case, errors limits correspond to one standard deviation. For NaBr, a slight negative temperature dependence was observed over the investigated range, 243-293 K, which can be represented by γ_NO_3^NaBr = 1.6 ≤ft(begin{array}{l}+1.8 -0.9) × 10-3exp [(1210± 200)/T]. An analysis of the results shows that under some conditions the heterogeneous loss of nitrate radicals on sea-salt aerosol particles at ambient temperature could be competitive with their loss by homogeneous reaction in the marine troposphere at night. Les coefficients de capture des radicaux nitrate (γ NO_3) sur des surfaces de sels marins (NaCl et NaBr) ont été mesurés aux températures troposphériques en utilisant la technique du réacteur à écoulement à paroi recouverte couplée à un spectromètre de résonance paramagnétique électronique (R.P.E). La variation de la concentration en phase gazeuse des radicaux nitrate en présence des surfaces étudiées est suivie en mesurant le signal R.P.E des radicaux OH produits par la réaction de titrage H + NO3. Pour des températures comprises entre 258 et 301 K, la valeur moyenne du coefficient de capture initial (γ NO_3) sur des surfaces solides de NaCl est égal à (1.7± 1.2)× 10-2). Sur des surfaces solides de NaBr, (γ NO_3) est égal à (0.11 ± 0.06) à 293 K. L'incertitude correspond à une déviation standard. Par ailleurs, pour ce type de surfaces, une légère dépendance négative avec la température est observée dans la

  11. Determination of absorption coefficients of glasses at high tempera-tures, by measuring the thermal emission

    NARCIS (Netherlands)

    Loenen, E.; Van der Tempel, L.

    1996-01-01

    An experimental setup built in 1995 measures the spectral absorptioncoefficient of glass as a function of temperature and wavelength bythe emissive method. The setup was improved, as well as the softwarefor processing the measurement data. The measurement results of quartzwere validated by

  12. Coefficient of Friction Between Carboxymethylated Hyaluronic Acid-Based Polymer Films and the Ocular Surface.

    Science.gov (United States)

    Colter, Jourdan; Wirostko, Barbara; Coats, Brittany

    2017-12-01

    Hyaluronic acid-based polymer films are emerging as drug-delivery vehicles for local and continuous drug administration to the eye. The highly lubricating hyaluronic acid increases comfort, but displaces films from the eye, reducing drug exposure and efficacy. Previous studies have shown that careful control of the surface interaction of the film with the eye is critical for improved retention. In this study, the frictional interaction of a carboxymethylated, hyaluronic acid-based polymer (CMHA-S) with and without methylcellulose was quantified against ovine and human sclera at three axial loads (0.3, 0.5, and 0.7 N) and four sliding velocities (0.3, 1.0, 10, and 30 mm/s). Static coefficients of friction significantly increased with rate (P Friction became more rate-dependent when methylcellulose was added to CMHA-S. Kinetic coefficient of friction was not affected by rate, and averaged 0.15 ± 0.1. Methylcellulose increased CMHA-S static and kinetic friction by 60% and 80%, respectively, but was also prone to wear during testing. These data suggest that methylcellulose can be used to create a friction differential on the film, but a potentially increased degradation rate with the methylcellulose must be considered in the design.

  13. Multi-source SO2 emission retrievals and consistency of satellite and surface measurements with reported emissions

    Directory of Open Access Journals (Sweden)

    V. Fioletov

    2017-10-01

    Full Text Available Reported sulfur dioxide (SO2 emissions from US and Canadian sources have declined dramatically since the 1990s as a result of emission control measures. Observations from the Ozone Monitoring Instrument (OMI on NASA's Aura satellite and ground-based in situ measurements are examined to verify whether the observed changes from SO2 abundance measurements are quantitatively consistent with the reported changes in emissions. To make this connection, a new method to link SO2 emissions and satellite SO2 measurements was developed. The method is based on fitting satellite SO2 vertical column densities (VCDs to a set of functions of OMI pixel coordinates and wind speeds, where each function represents a statistical model of a plume from a single point source. The concept is first demonstrated using sources in North America and then applied to Europe. The correlation coefficient between OMI-measured VCDs (with a local bias removed and SO2 VCDs derived here using reported emissions for 1° by 1° gridded data is 0.91 and the best-fit line has a slope near unity, confirming a very good agreement between observed SO2 VCDs and reported emissions. Having demonstrated their consistency, seasonal and annual mean SO2 VCD distributions are calculated, based on reported point-source emissions for the period 1980–2015, as would have been seen by OMI. This consistency is further substantiated as the emission-derived VCDs also show a high correlation with annual mean SO2 surface concentrations at 50 regional monitoring stations.

  14. Near-surface temperature gradients and their effects on thermal-infrared emission spectra of particulate planetary surfaces

    Science.gov (United States)

    Henderson, B. G.; Jakosky, B. M.

    1993-01-01

    The infrared energy emitted from a planetary surface is generated within a finite depth determined by the material's absorption skin depth. This parameter varies significantly with wavelength in the infrared but has an average value of around 50 microns for most geologic materials. In solid rock, heat transfer is efficient enough so that this 50 micron zone of the near surface from which the radiation emanates will be more or less isothermal. In particulate materials, however, heat transfer is more complicated and occurs via a combination of mechanisms, including solid conduction within grains and across grain contacts, conduction through the interstitial gas, and thermal radiation within individual particles and across the void spaces in between grains. On planets with substantial atmospheres, the gas component dominates the heat transfer and tends to mitigate near-surface thermal gradients. However, on airless bodies, the gas component is absent and heat transfer occurs via solid conductions and radiation. If the particles are small relative to the average absorption skin depth, then the top 50-100 microns or so of the surface will be cooled by radiation to space allowing the creation of significant near-surface thermal gradients. In those regions of the spectrum where the absorption coefficient is low, the emission will come from the deeper, warmer parts of the medium, whereas in regions of high absorption, the emission will emanate from shallower, cooler parts of the medium. The resulting emission spectrum will show non-compositional features as a result of the thermal structure in the material. We have modeled the heat transfer in a particulate medium in order to determine the magnitude of near-surface thermal gradients for surfaces on airless bodies and on Mars. We use the calculated thermal structure to determine the effects it has on the infrared emission spectrum of the surface.

  15. Simulation of secondary electron emission from rough surfaces

    International Nuclear Information System (INIS)

    Kawata, J.; Ohya, K.; Nishimura, K.

    1995-01-01

    The effect of surface roughness on the secondary electron emission from a beryllium surface under low-energy (≤1 keV) electron bombardment is investigated using a Monte Carlo simulation combined with the model of bowl-structured surface. With increasing aspect ratio H/W of the bowl structure, the secondary electron yield becomes greater than that for a flat surface, whereas for large H/W the yield is smaller; where H and W are the depth and width of the bowl structure, respectively. The former is due to emission of electrons, which cannot escape from the flat surface, from an inclined plane; it increases the low-energy component in the energy distribution. The latter is due to re-entrance of once-emitted electrons into the next part of the topographic surface; it decreases the number of electrons emitted with oblique angles. ((orig.))

  16. Modeling of dust emission for a crusted surface

    Science.gov (United States)

    Ghodsi Zadeh, Z.; Klose, M.; DuBois, D. W.

    2017-12-01

    Dust storms are frequent phenomena in the southwestern United Sates. Dust source areas in the region are often (partly) crusted. A critical prerequisite in dust aerosol modeling is an accurate representation of dust emission. While several dust emission schemes have been developed over the last decades, their applicability for crusted surfaces is not well tested. In this study, we use and test the applicability of the dust emission scheme of Shao (2004) (S04), which estimates dust emission based on the soil volume removed by saltation particle impacts, to model dust emission from a crusted surface in New Mexico, USA, for three dust events in spring 2016. Detailed field data are available for these events which are used as scheme input (surface crust and vegetation fraction, friction velocity, minimally- and fully-dispersed particle-size distributions) and for evaluation (saltation flux and dust emission flux). Results show that the saltation flux modeled with the scheme of White (1979) was overestimated by three orders of magnitude. This is expected as the supply of particles available for saltation is limited at the site. As our focus is on dust emission, a constant scaling factor was applied to match modeled and observed saltation fluxes. Parameters that describe the efficiency of saltator impacts to emit dust and the degree of dispersion during erosion need to be adapted in the S04 scheme to represent the soil surface setting at the study site. Our results show that changing those parameters has little effect on the modeled dust emission and dust emission is generally underestimated when PSDs of the top 1 cm soil layer are used as it is common. The reason for this is that the crust at the site is relatively thin and the soil overall sandy, which results in only a small difference between the two PSDs. If, however, the minimally- and fully-dispersed PSDs are replaced with the PSDs of, respectively, loose erodible material and crust, then the difference increases

  17. Intelligent tires for identifying coefficient of friction of tire/road contact surfaces using three-axis accelerometer

    International Nuclear Information System (INIS)

    Matsuzaki, Ryosuke; Kamai, Kazuto; Seki, Ryosuke

    2015-01-01

    Intelligent tires equipped with sensors as well as the monitoring of the tire/road contact conditions are in demand for improving vehicle control and safety. With the aim of identifying the coefficient of friction of tire/road contact surfaces during driving, including during cornering, we develop an identification scheme for the coefficient of friction that involves estimation of the slip angle and applied force by using a single lightweight three-axis accelerometer attached on the inner surface of the tire. To validate the developed scheme, we conduct tire-rolling tests using an accelerometer-equipped tire with various slip angles on various types of road surfaces, including dry and wet surfaces. The results of these tests confirm that the estimated slip angle and applied force are reasonable. Furthermore, the identified coefficient of friction by the developed scheme agreed with that measured by standardized tests. (paper)

  18. Influence of the surface drag coefficient (young waves) on the current structure of the Berre lagoon

    Science.gov (United States)

    Alekseenko, Elena; Roux, Bernard; Kharif, Christian; Sukhinov, Alexander; Kotarba, Richard; Fougere, Dominique; Chen, Paul Gang

    2013-04-01

    Due to the shallowness, currents and hydrodynamics of Berre lagoon (South of France) are closely conditioned by the bottom topography, and wind affects the entire water column, as for many other Mediterranean lagoons (Perez-Ruzafa, 2011). Wind stress, which is caused by moving atmospheric disturbance, is known to have a major influence in lagoon water circulation. According to the numerical simulation for the main directions of the wind: N-NW, S-SE and W (wind speed of 80 km/h) it is observed that the current is maximal alongshore in the wind direction; the bottom nearshore current being larger in shallower area. This fact is coherent with fundamental principle of wind-driven flows in closed or partially closed basins which states that in shallow water the dominant force balance is between surface wind stress and bottom friction, yielding a current in the direction of the wind (Mathieu et al, 2002, Hunter and Hearn, 1987; Hearn and Hunter,1990). A uniform wind stress applied at the surface of a basin of variable depth sets up a circulation pattern characterized by relatively strong barotropic coastal currents in the direction of the wind, with return flow occurring over the deeper regions (Csanady, 1967; Csanady, 1971). One of the key parameters characterizing the wind stress formulation is a surface drag coefficient (Cds). Thus, an effect of a surface drag coefficient, in the range 0.0016 - 0.0032, will be analyzed in this work. The value of surface drag coefficient Cds = 0.0016 used in our previous studies (Alekseenko et al., 2012), would correspond to mature waves (open sea). But, in the case of semi-closed lagoonal ecosystem, it would be more appropriate to consider "young waves" mechanism. A dependency of this coefficient in terms of the wind speed is given by Young (1999) in both cases of mature waves and young waves. For "young waves" generated at a wind speed of 80 km/h, Cds = 0.0032. So, the influence of Cds on the vertical profile of the velocity in the

  19. Two-dimensional simulation research of secondary electron emission avalanche discharge on vacuum insulator surface

    Science.gov (United States)

    Cai, Libing; Wang, Jianguo; Zhu, Xiangqin; Wang, Yue; Zhang, Dianhui

    2015-01-01

    Based on the secondary electron emission avalanche (SEEA) model, the SEEA discharge on the vacuum insulator surface is simulated by using a 2D PIC-MCC code developed by ourselves. The evolutions of the number of discharge electrons, insulator surface charge, current, and 2D particle distribution are obtained. The effects of the strength of the applied electric field, secondary electron yield coefficient, rise time of the pulse, length of the insulator on the discharge are investigated. The results show that the number of the SEEA electrons presents a quadratic dependence upon the applied field strength. The SEEA current, which is on the order of Ampere, is directly proportional to the field strength and secondary electron yield coefficient. Finally, the electron-stimulated outgassing is included in the simulation code, and a three-phase discharge curve is presented by the simulation, which agrees with the experimental data.

  20. Two-dimensional simulation research of secondary electron emission avalanche discharge on vacuum insulator surface

    International Nuclear Information System (INIS)

    Cai, Libing; Wang, Jianguo; Zhu, Xiangqin; Wang, Yue; Zhang, Dianhui

    2015-01-01

    Based on the secondary electron emission avalanche (SEEA) model, the SEEA discharge on the vacuum insulator surface is simulated by using a 2D PIC-MCC code developed by ourselves. The evolutions of the number of discharge electrons, insulator surface charge, current, and 2D particle distribution are obtained. The effects of the strength of the applied electric field, secondary electron yield coefficient, rise time of the pulse, length of the insulator on the discharge are investigated. The results show that the number of the SEEA electrons presents a quadratic dependence upon the applied field strength. The SEEA current, which is on the order of Ampere, is directly proportional to the field strength and secondary electron yield coefficient. Finally, the electron-stimulated outgassing is included in the simulation code, and a three-phase discharge curve is presented by the simulation, which agrees with the experimental data

  1. REMOTE SENSING AND SURFACE ENERGY FLUX MODELS TO DERIVE EVAPOTRANSPIRATION AND CROP COEFFICIENT

    Directory of Open Access Journals (Sweden)

    Salvatore Barbagallo

    2008-06-01

    Full Text Available Remote sensing techniques using high resolution satellite images provide opportunities to evaluate daily crop water use and its spatial and temporal distribution on a field by field basis. Mapping this indicator with pixels of few meters of size on extend areas allows to characterize different processes and parameters. Satellite data on vegetation reflectance, integrated with in field measurements of canopy coverage features and the monitoring of energy fluxes through the soil-plant-atmosphere system, allow to estimate conventional irrigation components (ET, Kc thus improving irrigation strategies. In the study, satellite potential evapotranspiration (ETp and crop coefficient (Kc maps of orange orchards are derived using semi-empirical approaches between reflectance data from IKONOS imagery and ground measurements of vegetation features. The monitoring of energy fluxes through the orchard allows to estimate actual crop evapotranspiration (ETa using energy balance and the Surface Renewal theory. The approach indicates substantial promise as an efficient, accurate and relatively inexpensive procedure to predict actual ET fluxes and Kc from irrigated lands.

  2. Reporting central tendencies of chamber measured surface emission and oxidation.

    Science.gov (United States)

    Abichou, Tarek; Clark, Jeremy; Chanton, Jeffery

    2011-05-01

    Methane emissions, concentrations, and oxidation were measured on eleven MSW landfills in eleven states spanning from California to Pennsylvania during the three year study. The flux measurements were performed using a static chamber technique. Initial concentration samples were collected immediately after placement of the flux chamber. Oxidation of the emitted methane was evaluated using stable isotope techniques. When reporting overall surface emissions and percent oxidation for a landfill cover, central tendencies are typically used to report "averages" of the collected data. The objective of this study was to determine the best way to determine and report central tendencies. Results showed that 89% of the data sets of collected surface flux have lognormal distributions, 83% of the surface concentration data sets are also lognormal. Sixty seven percent (67%) of the isotope measured percent oxidation data sets are normally distributed. The distribution of data for all eleven landfills provides insight of the central tendencies of emissions, concentrations, and percent oxidation. When reporting the "average" measurement for both flux and concentration data collected at the surface of a landfill, statistical analyses provided insight supporting the use of the geometric mean. But the arithmetic mean can accurately represent the percent oxidation, as measured with the stable isotope technique. We examined correlations between surface CH(4) emissions and surface air CH(4) concentrations. Correlation of the concentration and flux values using the geometric mean proved to be a good fit (R(2)=0.86), indicating that surface scans are a good way of identifying locations of high emissions. Copyright © 2010 Elsevier Ltd. All rights reserved.

  3. Surface charge compensation for a highly charged ion emission microscope

    International Nuclear Information System (INIS)

    McDonald, J.W.; Hamza, A.V.; Newman, M.W.; Holder, J.P.; Schneider, D.H.G.; Schenkel, T.

    2003-01-01

    A surface charge compensation electron flood gun has been added to the Lawrence Livermore National Laboratory (LLNL) highly charged ion (HCI) emission microscope. HCI surface interaction results in a significant charge residue being left on the surface of insulators and semiconductors. This residual charge causes undesirable aberrations in the microscope images and a reduction of the Time-Of-Flight (TOF) mass resolution when studying the surfaces of insulators and semiconductors. The benefits and problems associated with HCI microscopy and recent results of the electron flood gun enhanced HCI microscope are discussed

  4. Global Occurrence and Emission of Rotaviruses to Surface Waters

    Directory of Open Access Journals (Sweden)

    Nicholas M. Kiulia

    2015-05-01

    Full Text Available Group A rotaviruses (RV are the major cause of acute gastroenteritis in infants and young children globally. Waterborne transmission of RV and the presence of RV in water sources are of major public health importance. In this paper, we present the Global Waterborne Pathogen model for RV (GloWPa-Rota model to estimate the global distribution of RV emissions to surface water. To our knowledge, this is the first model to do so. We review the literature to estimate three RV specific variables for the model: incidence, excretion rate and removal during wastewater treatment. We estimate total global RV emissions to be 2 × 1018 viral particles/grid/year, of which 87% is produced by the urban population. Hotspot regions with high RV emissions are urban areas in densely populated parts of the world, such as Bangladesh and Nigeria, while low emissions are found in rural areas in North Russia and the Australian desert. Even for industrialized regions with high population density and without tertiary treatment, such as the UK, substantial emissions are estimated. Modeling exercises like the one presented in this paper provide unique opportunities to further study these emissions to surface water, their sources and scenarios for improved management.

  5. Ion induced optical emission for surface and depth profile analysis

    International Nuclear Information System (INIS)

    White, C.W.

    1977-01-01

    Low-energy ion bombardment of solid surfaces results in the emission of infrared, visible, and ultraviolet radiation produced by inelastic ion-solid collision processes. The emitted optical radiation provides important insight into low-energy particle-solid interactions and provides the basis for an analysis technique which can be used for surface and depth profile analysis with high sensitivity. The different kinds of collision induced optical radiation emitted as a result of low-energy particle-solid collisions are reviewed. Line radiation arising from excited states of sputtered atoms or molecules is shown to provide the basis for surface and depth profile analysis. The spectral characteristics of this type of radiation are discussed and applications of the ion induced optical emission technique are presented. These applications include measurements of ion implant profiles, detection sensitivities for submonolayer quantities of impurities on elemental surfaces, and the detection of elemental impurities on complex organic substrates

  6. Variability of emissivity and surface temperature over a sparsely vegetated surface

    International Nuclear Information System (INIS)

    Humes, K.S.; Kustas, W.P.; Moran, M.S.; Nichols, W.D.; Weltz, M.A.

    1994-01-01

    Radiometric surface temperatures obtained from remote sensing measurements are a function of both the physical surface temperature and the effective emissivity of the surface within the band pass of the radiometric measurement. For sparsely vegetated areas, however, a sensor views significant fractions of both bare soil and various vegetation types. In this case the radiometric response of a sensor is a function of the emissivities and kinetic temperatures of various surface elements, the proportion of those surface elements within the field of view of the sensor, and the interaction of radiation emitted from the various surface components. In order to effectively utilize thermal remote sensing data to quantify energy balance components for a sparsely vegetated area, it is important to examine the typical magnitude and degree of variability of emissivity and surface temperature for such surfaces. Surface emissivity measurements and ground and low-altitude-aircraft-based surface temperature measurements (8-13 micrometer band pass) made in conjunction with the Monsoon '90 field experiment were used to evaluate the typical variability of those quantities during the summer rainy season in a semiarid watershed. The average value for thermal band emissivity of the exposed bare soil portions of the surface was found to be approximately 0.96; the average value measured for most of the varieties of desert shrubs present was approximately 0.99. Surface composite emissivity was estimated to be approximately 0.98 for both the grass-dominated and shrub-dominated portions of the watershed. The spatial variability of surface temperature was found to be highly dependent on the spatial scale of integration for the instantaneous field of view (IFOV) of the instrument, the spatial scale of the total area under evaluation, and the time of day

  7. Surface temperature measurements of heterogeneous explosives by IR emission

    Energy Technology Data Exchange (ETDEWEB)

    Henson, B.F.; Funk, D.J.; Dickson, P.M.; Fugard, C.S.; Asay, B.W.

    1998-03-01

    The authors present measurements of the integrated IR emission (1--5 {micro}m) from both the heterogeneous explosive PBX 9501 and pure HMX at calibrated temperatures from 300 C to 2,500 C. The IR power emitted as a function of temperature is that expected of a black body, attenuated by a unique temperature independent constant which the authors report as the thermal emissivity. The authors have utilized this calibration of IR emission in measurements of the surface temperature from PBX 9501 subject to 1 GPa, two dimensional impact, and spontaneous ignition in unconfined cookoff. They demonstrate that the measurement of IR emission in this spectral region provides a temperature probe of sufficient sensitivity to resolve the thermal response from the solid explosive throughout the range of weak mechanical perturbation, prolonged heating to ignition, and combustion.

  8. Mechanism of negative ion emission from surfaces of ferroelectrics

    Czech Academy of Sciences Publication Activity Database

    Šroubek, Zdeněk

    2012-01-01

    Roč. 606, 15-16 (2012), s. 1327-1330 ISSN 0039-6028 Institutional support: RVO:67985882 Keywords : Surface of ferroelectrics * Ion emission Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.838, year: 2012 http://www.sciencedirect.com/science/article/pii/S0039602812001525#gts0005

  9. Experimental determination of surface heat transfer coefficient in a dry ice-ethanol cooling bath using a numerical approach.

    Science.gov (United States)

    Santos, M V; Sansinena, M; Zaritzky, N; Chirife, J

    BACKGROUND: Dry ice-ethanol bath (-78 degree C) have been widely used in low temperature biological research to attain rapid cooling of samples below freezing temperature. The prediction of cooling rates of biological samples immersed in dry ice-ethanol bath is of practical interest in cryopreservation. The cooling rate can be obtained using mathematical models representing the heat conduction equation in transient state. Additionally, at the solid cryogenic-fluid interface, the knowledge of the surface heat transfer coefficient (h) is necessary for the convective boundary condition in order to correctly establish the mathematical problem. The study was to apply numerical modeling to obtain the surface heat transfer coefficient of a dry ice-ethanol bath. A numerical finite element solution of heat conduction equation was used to obtain surface heat transfer coefficients from measured temperatures at the center of polytetrafluoroethylene and polymethylmetacrylate cylinders immersed in a dry ice-ethanol cooling bath. The numerical model considered the temperature dependence of thermophysical properties of plastic materials used. A negative linear relationship is observed between cylinder diameter and heat transfer coefficient in the liquid bath, the calculated h values were 308, 135 and 62.5 W/(m 2 K) for PMMA 1.3, PTFE 2.59 and 3.14 cm in diameter, respectively. The calculated heat transfer coefficients were consistent among several replicates; h in dry ice-ethanol showed an inverse relationship with cylinder diameter.

  10. Sensitivity Analysis of the Surface Runoff Coefficient of HiPIMS in Simulating Flood Processes in a Large Basin

    Directory of Open Access Journals (Sweden)

    Yueling Wang

    2018-03-01

    Full Text Available To simulate flood processes at the basin level, the GPU-based High-Performance Integrated Hydrodynamic Modelling System (HiPIMS is gaining interest as computational capability increases. However, the difficulty of coping with rainfall input to HiPIMS reduces the possibility of acquiring a satisfactory simulation accuracy. The objective of this study is to test the sensitivity of the surface runoff coefficient in the HiPIMS source term in the Misai basin with an area of 797 km2 in south China. To achieve this, the basin was divided into 909,824 grid cells, to each of which a Manning coefficient was assigned based on its land use type interpreted from remote sensing data. A sensitivity analysis was conducted for three typical flood processes under four types of surface runoff coefficients, assumed a priori, upon three error functions. The results demonstrate the crucial role of the surface runoff coefficient in achieving better simulation accuracy and reveal that this coefficient varies with flood scale and is unevenly distributed over the basin.

  11. Different trends in extreme and median surface aerosol extinction coefficients over China inferred from quality-controlled visibility data

    Directory of Open Access Journals (Sweden)

    J. Li

    2018-03-01

    Full Text Available Although the temporal changes in aerosol properties have been widely investigated, the majority of studies has focused on average conditions without much emphasis on the extremes. However, the latter can be more important in terms of human health and climate change. This study uses a previously validated, quality-controlled visibility dataset to investigate the long-term trends (expressed in terms of relative changes in extreme surface aerosol extinction coefficient (AEC over China and compares them with the median trends. Two methods are used to independently evaluate the trends, which arrive at consistent results. The signs of extreme and median trends are generally coherent, whereas their magnitudes show distinct spatial and temporal differences. In the 1980s, an overall positive trend is found throughout China with the extreme trend exceeding the mean trend, except for northwest China and the North China Plain. In the 1990s, AEC over northeast and northwest China started to decline while the rest of the country still exhibited an increase. The extreme trends continued to dominate in the south while they yielded to the mean trend in the north. After the year 2000, the extreme trend became weaker than the mean trend overall in terms of both the magnitude and significance level. The annual trend can be primarily attributed to winter and fall trends. The results suggest that the decadal changes in pollution in China may be governed by different mechanisms. Synoptic conditions that often result in extreme air quality changes might have dominated in the 1980s, whereas emission increase might have been the main factor for the 2000s.

  12. Different trends in extreme and median surface aerosol extinction coefficients over China inferred from quality-controlled visibility data

    Science.gov (United States)

    Li, Jing; Li, Chengcai; Zhao, Chunsheng

    2018-03-01

    Although the temporal changes in aerosol properties have been widely investigated, the majority of studies has focused on average conditions without much emphasis on the extremes. However, the latter can be more important in terms of human health and climate change. This study uses a previously validated, quality-controlled visibility dataset to investigate the long-term trends (expressed in terms of relative changes) in extreme surface aerosol extinction coefficient (AEC) over China and compares them with the median trends. Two methods are used to independently evaluate the trends, which arrive at consistent results. The signs of extreme and median trends are generally coherent, whereas their magnitudes show distinct spatial and temporal differences. In the 1980s, an overall positive trend is found throughout China with the extreme trend exceeding the mean trend, except for northwest China and the North China Plain. In the 1990s, AEC over northeast and northwest China started to decline while the rest of the country still exhibited an increase. The extreme trends continued to dominate in the south while they yielded to the mean trend in the north. After the year 2000, the extreme trend became weaker than the mean trend overall in terms of both the magnitude and significance level. The annual trend can be primarily attributed to winter and fall trends. The results suggest that the decadal changes in pollution in China may be governed by different mechanisms. Synoptic conditions that often result in extreme air quality changes might have dominated in the 1980s, whereas emission increase might have been the main factor for the 2000s.

  13. The collective diffusion coefficient as a shape detector of the surface energy landscape

    Science.gov (United States)

    Mińkowski, Marcin; Załuska–Kotur, Magdalena A.

    2018-01-01

    The general expression for the diffusion coefficient for a dense, interacting particle system moving through a one-dimensional non-homogeneous energy potential is derived. Based on this expression, it is shown that the diffusion coefficient as a function of density depends to a great extent on the shape of the energy landscape. The presence of other particles affects the diffusion coefficient in another way as they pass through the same energy barriers, but set in a different order. The obtained result comes from a variational approach to diffusion and the interactions are taken into account using the transfer-matrix method. Interactions impact on the dynamics of the system, both by changing the equilibrium probabilities of the occupied states and by changing the barriers for the particle jumps. Several examples of diffusion in different energy potentials are presented and the dependence of the diffusion coefficient on potential and interactions is discussed.

  14. Laser method of acoustical emission control from vibrating surfaces

    Science.gov (United States)

    Motyka, Zbigniew

    2013-01-01

    For limitation of the noise in environment, the necessity occurs of determining and location of sources of sounds emitted from surfaces of many machines and devices, assuring in effect the possibility of suitable constructional changes implementation, targeted at decreasing of their nuisance. In the paper, the results of tests and calculations are presented for plane surface sources emitting acoustic waves. The tests were realized with the use of scanning laser vibrometer which enabled remote registration and the spectral analysis of the surfaces vibrations. The known hybrid digital method developed for determination of sound wave emission from such surfaces divided into small finite elements was slightly modified by distinguishing the phase correlations between such vibrating elements. The final method being developed may find use in wide range of applications for different forms of vibrations of plane surfaces.

  15. Quantum theory of spontaneous and stimulated emission of surface plasmons

    International Nuclear Information System (INIS)

    Archambault, Alexandre; Marquier, Francois; Greffet, Jean-Jacques; Arnold, Christophe

    2010-01-01

    We introduce a quantization scheme that can be applied to surface waves propagating along a plane interface. An important result is the derivation of the energy of the surface wave for dispersive nonlossy media without invoking any specific model for the dielectric constant. Working in Coulomb's gauge, we use a modal representation of the fields. Each mode can be associated with a quantum harmonic oscillator. We have applied the formalism to derive quantum mechanically the spontaneous emission rate of surface plasmon by a two-level system. The result is in very good agreement with Green's tensor approach in the nonlossy case. Green's approach allows also to account for losses, so that the limitations of a quantum approach of surface plasmons are clearly defined. Finally, the issue of stimulated versus spontaneous emission has been addressed. Because of the increasing density of states near the asymptote of the dispersion relation, it is quantitatively shown that the stimulated emission probability is too small to obtain gain in this frequency region.

  16. Effects of Surface Roughness, Oxidation, and Temperature on the Emissivity of Reactor Pressure Vessel Alloys

    Energy Technology Data Exchange (ETDEWEB)

    King, J. L. [University of Wisconsin–Madison, Department of Engineering Physics, Madison, Wisconsin; Jo, H. [University of Wisconsin–Madison, Department of Engineering Physics, Madison, Wisconsin; Tirawat, R. [National Renewable Energy Laboratory, Concentrating Solar Power Group, Golden, Colorado; Blomstrand, K. [University of Wisconsin–Madison, Department of Engineering Physics, Madison, Wisconsin; Sridharan, K. [University of Wisconsin–Madison, Department of Engineering Physics, Madison, Wisconsin

    2017-08-31

    Thermal radiation will be an important mode of heat transfer in future high-temperature reactors and in off-normal high-temperature scenarios in present reactors. In this work, spectral directional emissivities of two reactor pressure vessel (RPV) candidate materials were measured at room temperature after exposure to high-temperature air. In the case of SA508 steel, significant increases in emissivity were observed due to oxidation. In the case of Grade 91 steel, only very small increases were observed under the tested conditions. Effects of roughness were also investigated. To study the effects of roughening, unexposed samples of SA508 and Grade 91 steel were roughened via one of either grinding or shot-peening before being measured. Significant increases were observed only in samples having roughness exceeding the roughness expected of RPV surfaces. While the emissivity increases for SA508 from oxidation were indeed significant, the measured emissivity coefficients were below that of values commonly used in heat transfer models. Based on the observed experimental data, recommendations for emissivity inputs for heat transfer simulations are provided.

  17. Estimates of surface methane emissions over Europe using observed surface concentrations and the FLEXPART trajectory model

    Science.gov (United States)

    Weaver, C. J.; Kiemle, C.; Kawa, S. R.; Aalto, T.; Necki, J.; Steinbacher, M.; Arduini, J.; Apadula, F.; Berkhout, H.; Hatakka, J.; O'Doherty, S.

    2013-12-01

    We use surface methane observations from nine European ground stations, and the FLEXPART Lagrangian transport model to obtain surface methane emissions for 2010. Our inversion shows the strongest emissions from the Netherlands and the coal mines in Upper Silesia Poland. This is qualitatively consistent with the EDGAR surface flux inventory. We also report significant surface fluxes from wetlands in southern Finland during July and August and reduced wetland fluxes later in the year. Our simulated methane surface concentration captures at least half of the daily variability in the observations, suggesting that the transport model is correctly simulating the regional transport pathways over Europe. We also use our trajectory model to determine whether future space-based remote sensing instruments (MERLIN) will be able to detect both natural and anthropogenic changes in the surface flux strengths.

  18. Carbon dioxide emission from raised bog surface after peat extraction

    Directory of Open Access Journals (Sweden)

    Turbiak Janusz

    2017-12-01

    Full Text Available Research on CO2 emission from a raised bog after completion of peat extraction was performed in 2011–2013. CO2 emissions were determined by the chamber method. Twenty years after the termination of peat extraction, the bog surface was almost entirely devoid of plants. CO2 emission from the bog varied depending on temperature and water conditions and was 418 mg·m−2·h−1 on average during the research period. CO2 losses on the raised bog were on average 19.7 Mg·ha−1·year−1 during the research period which corresponded to a carbon loss of 5.37 Mg·ha−1·year−1 or mineralisation of 9.6 Mg·ha−1·year−1 of organic mass of 56% carbon content. It is possible to reduce organic mass losses and CO2 emission to the atmosphere from the bog surface after peat extraction has been terminated by reconstruction of initial water conditions, i.e. retaining a high ground water level and restoration of aquatic plant communities.

  19. Salt Efflorescence Effects on Soil Surface Erodibility and Dust Emissions

    Science.gov (United States)

    Van Pelt, R. S.; Zhang, G.

    2017-12-01

    Soluble salts resulting from weathering of geological materials often form surface crusts or efflorescences in areas with shallow saline groundwater. In many cases, the affected areas are susceptible to wind erosion due to their lack of protective vegetation and their flat topography. Fugitive dusts containing soluble salts affect the biogeochemistry of deposition regions and may result in respiratory irritation during transport. We created efflorescent crusts on soil trays by surface evaporation of single salt solutions and bombarded the resultant efflorescences with quartz abrader sand in a laboratory wind tunnel. Four replicate trays containing a Torrifluvent soil affected by one of nine salts commonly found in arid and semiarid streams were tested and the emissions were captured by an aspirated multi-stage deposition and filtering system. We found that in most cases the efflorescent crust reduced the soil surface erodibility but also resulted in the emission of salt rich dust. Two of the salts, sodium thiosulfate and calcium chloride, resulted in increased soil volume and erodibility. However, one of the calcium chloride replicates was tested after an outbreak of humid air caused hygroscopic wetting of the soil and it became indurated upon drying greatly decreasing the erodibility. Although saline affected soils are not used for agricultural production and degradation is not a great concern, the release of salt rich dust is an area of environmental concern and steps to control the dust emissions from affected soils should be developed. Future testing will utilize suites of salts found in streams of arid and semiarid regions.

  20. Diffusion coefficients-surface and interfacial tensions - Particular study of some lauryl compounds

    International Nuclear Information System (INIS)

    Morel, Jean-Emile

    1969-01-01

    Two important results of the double lipophilic and hydrophilic character of some heavy organic compounds with a polar group at the end of the chain, were studied: - In a first part, molecular diffusion coefficients were measured in order to prove the micellar aggregation of tri-laurylammonium nitrate in some organic solutions; - In a second part, the tensioactivity of some lauryl compounds (lauric acid, lauric alcohol, mono-laurylamine, etc.), was studied. (author) [fr

  1. Octanol Water Partition Coefficients of Surface and Ground Water Contaminants Found at Military Installations

    Science.gov (United States)

    1989-11-01

    34 method. Environ. Toxicol. Chem. 8(6):499-512. 23. Geyer, H., G. Politzki, and Freitag, D. 1984. Prediction of ecotoxicological behavior of chemicals...relationship between N-octanol/water partition coefficient and bloaccunulation of organic chemicals by Alga Chlorella. Chemosphere 13(2):269-284. 24...Branch Preventive Medicine Division (HSHA-IPM) * Fort Sam Houston, TX 78234-5000 17 .1 *1 - I Iii L - U.S. Army Engineers Division, Huntsville 106 Wynn

  2. Henry’s Law Constant and Overall Mass Transfer Coefficient for Formaldehyde Emission from Small Water Pools under Simulated Indoor Environmental Conditions

    Science.gov (United States)

    The Henry’s law constant (HLC) and the overall mass transfer coefficient are both important parameters for modeling formaldehyde emissions from aqueous solutions. In this work, the apparent HLCs for aqueous formaldehyde solutions were determined in the concentration range from 0....

  3. CFD simulation of direct contact condensation with ANSYS CFX using surface renewal theory based heat transfer coefficients

    Energy Technology Data Exchange (ETDEWEB)

    Wanninger, Andreas; Ceuca, Sabin Cristian; Macian-Juan, Rafael [Technische Univ. Muenchen, Garching (Germany). Dept. of Nuclear Engineering

    2013-07-01

    Different approaches for the calculation of Direct Contact Condensation (DCC) using Heat Transfer Coefficients (HTC) based on the Surface Renewal Theory (SRT) are tested using the CFD simulation tool ANSYS CFX. The present work constitutes a preliminary study of the flow patterns and conditions observed using different HTC models. A complex 3D flow pattern will be observed in the CFD simulations as well as a strong coupling between the condensation rate and the two-phase flow dynamics. (orig.)

  4. Mechanisms of subthreshold atomic emission from solid surfaces

    International Nuclear Information System (INIS)

    Kiv, A.E.; Elango, M.A.; Britavskaya, E.P.; Zaharchenko, I.G.

    1994-01-01

    Computer simulation of the dynamics of ions and atoms on the surfaces of solids has been carried out. The Coulomb, Pauli, exchange and Van der Waals potentials have been taken into account. The semi-empirical quantum-chemical method has been used also. In the case of alkali halide surfaces it is shown that if recharge of an anion (X - → X + ) occurs in two surface layers, it may initiate the ejection of positive metal ions (M + ) and, assisted by the capture of an electron by a departing M + , of metal atoms M 0 . Besides the Coulomb repulsion the Pauli shock is shown to play an essential role in the driving of the ejection process. This mechanism of desorption has large efficiency when the excitation of a core electron occurs in case of alkali halide crystals and has a strong dependence on the crystal ionicity. We obtained the energy distribution of ejected particles for different mechanisms of electron-ion emission. (orig.)

  5. Surface modification of hexatriacontane by CF_4 plasmas studied by optical emission and threshold ionization mass spectrometries

    Science.gov (United States)

    Poncin-Epaillard, F.; Wang, W.; Ausserré, D.; Scharzenbach, W.; Derouard, J.; Sadeghi, N.

    1998-11-01

    The behavior of tetrafluoromethane microwave plasma (2% argon included) has been studied by emission spectroscopy during the treatment of hexatriacontane, a model for high density polyethylene. The evolution of the densities of F* atoms, and CF, CF^*2, radicals has been followed by using the actinometric technique with 2% argon added to the gas. The surface properties, such as surface energy and surface roughness were correlated to the emission intensity of reactives species in the plasma gas phase. We found that the evolution of the fluorinated species emissions in the plasma gas phase can be a direct indication of the surface modifications by the plasma. A mild exposure to the plasma can result in a great decrease of surface energy corresponding to the fluorination. The surface roughness only changes under drastic plasma conditions. Threshold ionization mass spectroscopy is applied to detect the fluorine atoms and CFx radicals. Time resolved measurements in pulsed plasma, give access to the decay rate of F atoms concentration in the afterglow, and to their sticking coefficient on different surfaces. The influences of the discharge parameters and of the surfaces (metal, silicon or hexatriacontane) in contact with the plasma are investigated. The results show that the plasma generated ions and/or UV radiations highly enhance the reactivity of the F atoms on polymer surface.

  6. Trace moisture emissions from heated metal surfaces in hydrogen service

    International Nuclear Information System (INIS)

    Funke, Hans H.; Yao Jianlong; Raynor, Mark W.

    2004-01-01

    The formation of trace moisture by exposure of dry heated surfaces of 316 L stainless-steel, Restek Silcosteel registered , and nickel 1/8 in. outer diameter line segments to purified Ar and H 2 was studied using atmospheric pressure ionization mass spectrometry at flow rates of 2 slpm. Prior to H 2 exposure, adsorbed moisture was removed by heating incrementally to 500 deg. C in an argon matrix, where the Restek Silcosteel registered material released a maximum of 50 ppb moisture at 300 deg. C and moisture spikes from the Ni and stainless-steel surfaces reached several 100 ppb. Upon exposure to H 2 , persistent low ppb moisture emissions due to the reduction of surface oxide species were observed at temperatures as low as 100 deg. C. Spikes at 300-500 deg. C ranged from ∼100 ppb for the stainless-steel lines to 400 ppb for the Restek Silcosteel registered material. The observed moisture emissions have to be considered as a potential contamination source for high-purity processes utilizing H 2 purge at elevated temperatures

  7. Internal Energy Dependence of Molecular Condensation Coefficients Determined from Molecular Beam Surface Scattering Experiments

    Science.gov (United States)

    Sibener, S. J.; Lee, Y. T.

    1978-05-01

    An experiment was performed which confirms the existence of an internal mode dependence of molecular sticking probabilities for collisions of molecules with a cold surface. The scattering of a velocity selected effusive beam of CCl{sub 4} from a 90 K CC1{sub 4} ice surface has been studied at five translational velocities and for two different internal temperatures. At a surface temperature of 90 K (approx. 99% sticking probability) a four fold increase in reflected intensity was observed for the internally excited (560 K) CC1{sub 4} relative to the room temperature (298 K) CC1{sub 4} at a translational velocity of 2.5 X 10{sup 4} cm/sec. For a surface temperature of 90 K all angular distributions were found to peak 15{sup 0} superspecularly independent of incident velocity.

  8. The impact of surface and geometry on coefficient of friction of artificial hip joints.

    Science.gov (United States)

    Choudhury, Dipankar; Vrbka, Martin; Mamat, Azuddin Bin; Stavness, Ian; Roy, Chanchal K; Mootanah, Rajshree; Krupka, Ivan

    2017-08-01

    Coefficient of friction (COF) tests were conducted on 28-mm and 36-mm-diameter hip joint prostheses for four different material combinations, with or without the presence of Ultra High Molecular Weight Polyethylene (UHMWPE) particles using a novel pendulum hip simulator. The effects of three micro dimpled arrays on femoral head against a polyethylene and a metallic cup were also investigated. Clearance played a vital role in the COF of ceramic on polyethylene and ceramic on ceramic artificial hip joints. Micro dimpled metallic femoral heads yielded higher COF against a polyethylene cup; however, with metal on metal prostheses the dimpled arrays significantly reduced the COF. In situ images revealed evidence that the dimple arrays enhanced film formation, which was the main mechanism that contributed to reduced friction. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. A characteristic function to estimate the longitudinal dispersion coefficient in surface water flows over porous media

    Science.gov (United States)

    Nofuentes, M.; Polo, M. J.

    2012-04-01

    One-dimensional modelling of solute transport in shallow water flows relies on an accurate approximation of the longitudinal dispersion coefficient, E, especially under transient conditions of the water flow during the solute residence time. Previous approaches have used expressions (e.g., the Rutherford equation) that allow the inclusion of spatiotemporal variability of E during the transport process, but their accuracy is reduced in marked transient regimes since the data were obtained from experimental work in rivers. This work proposes a different approach from experimental work with slow, shallow flows over porous media in fertigation essays, and provides us with a simple, parametric sigmoid function to estimate a priori effective values of E from simple measurements of flow characteristics and variables. The results have been successfully validated and compared to the Rutherford equation approach. Furthermore, the methodology to develop this characteristic function can be easily adapted for application in other practical cases.

  10. Mapping Surface Water DOC in the Northern Gulf of Mexico Using CDOM Absorption Coefficients and Remote Sensing Imagery

    Science.gov (United States)

    Kelly, B.; Chelsky, A.; Bulygina, E.; Roberts, B. J.

    2017-12-01

    Remote sensing techniques have become valuable tools to researchers, providing the capability to measure and visualize important parameters without the need for time or resource intensive sampling trips. Relationships between dissolved organic carbon (DOC), colored dissolved organic matter (CDOM) and spectral data have been used to remotely sense DOC concentrations in riverine systems, however, this approach has not been applied to the northern Gulf of Mexico (GoM) and needs to be tested to determine how accurate these relationships are in riverine-dominated shelf systems. In April, July, and October 2017 we sampled surface water from 80+ sites over an area of 100,000 km2 along the Louisiana-Texas shelf in the northern GoM. DOC concentrations were measured on filtered water samples using a Shimadzu TOC-VCSH analyzer using standard techniques. Additionally, DOC concentrations were estimated from CDOM absorption coefficients of filtered water samples on a UV-Vis spectrophotometer using a modification of the methods of Fichot and Benner (2011). These values were regressed against Landsat visible band spectral data for those same locations to establish a relationship between the spectral data, CDOM absorption coefficients. This allowed us to spatially map CDOM absorption coefficients in the Gulf of Mexico using the Landsat spectral data in GIS. We then used a multiple linear regressions model to derive DOC concentrations from the CDOM absorption coefficients and applied those to our map. This study provides an evaluation of the viability of scaling up CDOM absorption coefficient and remote-sensing derived estimates of DOC concentrations to the scale of the LA-TX shelf ecosystem.

  11. The effect of surface tension on the contraction coefficient of a jet

    International Nuclear Information System (INIS)

    Gasmi, A; Mekias, H

    2003-01-01

    Two-dimensional free surface potential flow issued from an opening of a container is considered. The flow is assumed to be inviscid and incompressible. The mathematical problem, which is characterized by the nonlinear boundary condition on the free surface of an unknown equation, is solved via a series truncation. We computed solutions for all Weber numbers. Our problem is an extension of the work done by Ackerberg and Liu (1987 Phys. Fluids 30 289-96), the results confirm and extend their results

  12. Incorporation of velocity-dependent restitution coefficient and particle surface friction into kinetic theory for modeling granular flow cooling.

    Science.gov (United States)

    Duan, Yifei; Feng, Zhi-Gang

    2017-12-01

    Kinetic theory (KT) has been successfully used to model rapid granular flows in which particle interactions are frictionless and near elastic. However, it fails when particle interactions become frictional and inelastic. For example, the KT is not able to accurately predict the free cooling process of a vibrated granular medium that consists of inelastic frictional particles under microgravity. The main reason that the classical KT fails to model these flows is due to its inability to account for the particle surface friction and its inelastic behavior, which are the two most important factors that need be considered in modeling collisional granular flows. In this study, we have modified the KT model that is able to incorporate these two factors. The inelasticity of a particle is considered by establishing a velocity-dependent expression for the restitution coefficient based on many experimental studies found in the literature, and the particle friction effect is included by using a tangential restitution coefficient that is related to the particle friction coefficient. Theoretical predictions of the free cooling process by the classical KT and the improved KT are compared with the experimental results from a study conducted on an airplane undergoing parabolic flights without the influence of gravity [Y. Grasselli, G. Bossis, and G. Goutallier, Europhys. Lett. 86, 60007 (2009)10.1209/0295-5075/86/60007]. Our results show that both the velocity-dependent restitution coefficient and the particle surface friction are important in predicting the free cooling process of granular flows; the modified KT model that integrates these two factors is able to improve the simulation results and leads to better agreement with the experimental results.

  13. Incorporation of velocity-dependent restitution coefficient and particle surface friction into kinetic theory for modeling granular flow cooling

    Science.gov (United States)

    Duan, Yifei; Feng, Zhi-Gang

    2017-12-01

    Kinetic theory (KT) has been successfully used to model rapid granular flows in which particle interactions are frictionless and near elastic. However, it fails when particle interactions become frictional and inelastic. For example, the KT is not able to accurately predict the free cooling process of a vibrated granular medium that consists of inelastic frictional particles under microgravity. The main reason that the classical KT fails to model these flows is due to its inability to account for the particle surface friction and its inelastic behavior, which are the two most important factors that need be considered in modeling collisional granular flows. In this study, we have modified the KT model that is able to incorporate these two factors. The inelasticity of a particle is considered by establishing a velocity-dependent expression for the restitution coefficient based on many experimental studies found in the literature, and the particle friction effect is included by using a tangential restitution coefficient that is related to the particle friction coefficient. Theoretical predictions of the free cooling process by the classical KT and the improved KT are compared with the experimental results from a study conducted on an airplane undergoing parabolic flights without the influence of gravity [Y. Grasselli, G. Bossis, and G. Goutallier, Europhys. Lett. 86, 60007 (2009), 10.1209/0295-5075/86/60007]. Our results show that both the velocity-dependent restitution coefficient and the particle surface friction are important in predicting the free cooling process of granular flows; the modified KT model that integrates these two factors is able to improve the simulation results and leads to better agreement with the experimental results.

  14. New sensitive micro-measurements of dynamic surface tension and diffusion coefficients

    DEFF Research Database (Denmark)

    Kinoshita, Koji; Ortiz, Elisa Parra; Needham, David

    2017-01-01

    Currently available dynamic surface tension (DST) measurement methods, such as Wilhelmy plate, droplet- or bubble-based methods, still have various experimental limitations such as the large size of the interface, convection in the solution, or a certain “dead time” at initial measurement. These ...

  15. The coefficient of restitution of ice particles in glancing collisions: Experimental results for unfrosted surfaces

    Science.gov (United States)

    Supulver, Kimberley D.; Bridges, Frank G.; Lin, D. N. C.

    1995-01-01

    Both Saturn's rings and planetesimal disks are made up of particles in Keplerian orbits. Inelastic collisions between these particles regulate their dynamical evolution and possible aggregation. We present an experiment to simulate glancing collisions in Saturn's rings and in planetesimal disks and thus measure contributions to the energy loss for both normal and tangential velocity components. In this experiment, a spherical iceball mounted on a long-period, two dimensional pendulum is made to impact a flat ice surface in a low-temperature environment. This paper describes the experimental apparatus in detail and presents results for smooth unfrosted surfaces. The energy loss for tangential motion is suprisingly low, indicating that very little friction is present at low impact speeds for relatively smooth ice surfaces and temperatures near 100 K. We have also investigated room-temperature collisions of a rubber ball on a rough surface to understand the energy loss in situations where the tangential friction force is not small. In this analogous case, the energy loss is maximum for impact angles in the range 45 deg-60 deg.

  16. Distinct positive temperature coefficient effect of polymer-carbon fiber composites evaluated in terms of polymer absorption on fiber surface.

    Science.gov (United States)

    Zhang, Xi; Zheng, Shaodi; Zheng, Xiaofang; Liu, Zhengying; Yang, Wei; Yang, Mingbo

    2016-03-21

    In this article, the positive temperature coefficient (PTC) effect was studied for high-density polyethylene (HDPE)/carbon fiber (CF) composites. All of the samples showed a significant PTC effect during the heating processes without a negative temperature coefficient (NTC) effect, even at a temperature much higher than the melting point of the polymer matrix. An ever-increasing PTC intensity with increasing thermal cycles was observed in our study that had never been reported in previous research. The absence of a NTC effect resulted from the increased binding force between the matrix and fillers that contributed to the very special structure of CF surface. We incorporated thermal expansion theory and quantum tunneling effects to explain PTC effect. From the SEM micrographs for the HDPE/CF composites before and after the different thermal cycles, we found that the surface of CF was covered with a layer of polymer which resulted in a change in the gap length between CF and HDPE and its distribution. We believed that the gap change induced by polymer absorption on the fiber surface had a great effect on the PTC effect.

  17. Effect of surface tension and coefficient of thermal expansion in 30 nm scale nanoimprinting with two flexible polymer molds

    International Nuclear Information System (INIS)

    Kim, Jae Kwan; Cho, Hye Sung; Jung, Ho-Sup; Suh, Kahp-Yang; Lim, Kipil; Kim, Ki-Bum; Choi, Dae-Geun; Jeong, Jun-Ho

    2012-01-01

    We report on nanoimprinting of polymer thin films at 30 nm scale resolution using two types of ultraviolet (UV)-curable, flexible polymer molds: perfluoropolyether (PFPE) and polyurethane acrylate (PUA). It was found that the quality of nanopatterning at the 30 nm scale is largely determined by the combined effects of surface tension and the coefficient of thermal expansion of the polymer mold. In particular, the polar component of surface tension may play a critical role in clean release of the mold, as evidenced by much reduced delamination or broken structures for the less polarized PFPE mold when patterning a relatively hydrophilic PMMA film. In contrast, such problems were not notably observed with a relatively hydrophobic PS film for both polymer molds. In addition, the demolding characteristic was also influenced by the coefficient of thermal expansion so that no delamination or uniformity problems were observed when patterning a UV-curable polymer film at room temperature. These results suggest that a proper polymeric mold material needs to be chosen for patterning polymer films under different surface properties and processing conditions, providing insights into how a clean demolding characteristic can be obtained at 30 nm scale nanopatterning. (paper)

  18. The effect of surface roughness on the heat exchange and pressure-drop coefficients

    International Nuclear Information System (INIS)

    Malherbe, J.M.

    1963-02-01

    The effect of various types of roughness on the wall of an axial tube in an annular space of 15-25 mm cooled by an air-flow has been studied in the case of steady turbulence. Roughness of the type 'disrupter of the boundary layer' was set up using triangular threads of 0.2 to 0.4 mm thickness machined in the tube itself, or brass or glass wire wound on a smooth tube. Tests were also carried out using the roughness provided by regularly spaced pyramids 0.4 mm high. The results obtained showed that the heat exchange increased because of the presence of this roughness. A maximum in the heat exchange and pressure-drop coefficients was observed when the pitch equals about eight times the height of the thread. An analytical method has been developed and experiments have been carried out in which the two walls of the annular space were heated in such a way as to transmit unequal heat flows. The region considered is limited to Reynolds's numbers of between 5 X 10 3 and 5 x 10 4 and wall temperatures of under 250 deg C. (author) [fr

  19. Poloidal density variation of impurities in a rotating tokamak plasma - flux surface coordinates and effect on transport coefficients

    International Nuclear Information System (INIS)

    Romanelli, M.

    1999-09-01

    The poloidal variation of impurity densities over magnetic surfaces brings about an enhancement of neoclassical transport coefficients, as shown by Romanelli and Ottaviani for impurities in the Pfirsch Schlueter regime and by Helander for particles in the banana-plateau regime, both in a large aspect ratio tokamak. The same effect will occur in a finite aspect ratio tokamak and therefore it is considered to be relevant for inclusion in transport codes for comparison with the experimental measurements of impurity transport. Here an expression for the impurity-density poloidal-variation generated by the fast toroidal rotation of the plasma column is presented in general coordinates. (author)

  20. Experimental assessment of blade tip immersion depth from free surface on average power and thrust coefficients of marine current turbine

    Science.gov (United States)

    Lust, Ethan; Flack, Karen; Luznik, Luksa

    2014-11-01

    Results from an experimental study on the effects of marine current turbine immersion depth from the free surface are presented. Measurements are performed with a 1/25 scale (diameter D = 0.8m) two bladed horizontal axis turbine towed in the large towing tank at the U.S. Naval Academy. Thrust and torque are measured using a dynamometer, mounted in line with the turbine shaft. Shaft rotation speed and blade position are measured using a shaft position indexing system. The tip speed ratio (TSR) is adjusted using a hysteresis brake which is attached to the output shaft. Two optical wave height sensors are used to measure the free surface elevation. The turbine is towed at 1.68 m/s, resulting in a 70% chord based Rec = 4 × 105. An Acoustic Doppler Velocimeter (ADV) is installed one turbine diameter upstream of the turbine rotation plane to characterize the inflow turbulence. Measurements are obtained at four relative blade tip immersion depths of z/D = 0.5, 0.4, 0.3, and 0.2 at a TSR value of 7 to identify the depth where free surface effects impact overall turbine performance. The overall average power and thrust coefficient are presented and compared to previously conducted baseline tests. The influence of wake expansion blockage on the turbine performance due to presence of the free surface at these immersion depths will also be discussed.

  1. Manufacturing sector carbon dioxide emissions in nine OECD countries 1973--87: A Divisia index decomposition to changes in fuel mix, emission coefficients, industry structure, energy intensities, and international structure

    International Nuclear Information System (INIS)

    Torvanger, A.

    1990-11-01

    In this paper the reduction in energy-related manufacturing carbon dioxide emissions for nine OECD countries in the period 1973 to 1987 is analyzed. Carbon dioxide emissions are estimated from energy use data. The emphasis is on carbon dioxide intensities, defined as emissions divided by value added. The overall manufacturing carbon dioxide intensity for the nine OECD countries was reduced by 42% in the period 1973--1987. Five fuels are specified together with six subsectors of manufacturing. Carbon dioxide emissions are estimated from fossil fuel consumption, employing emissions coefficients for gas, oil and solids. In addition, electricity consumption is specified. For electricity use an emission coefficient index is calculated from the shares of fossil fuels, nuclear power and hydro power used to generate electricity, and the efficiency in electricity generation from these energy sources. A Divisia index approach is used to sort out the contribution to reduced carbon dioxide intensity from different components. The major finding is that the main contribution to reduced carbon dioxide intensity is from the general reduction in manufacturing energy intensity, most likely driven by economic growth and increased energy prices, giving incentives to invest in new technology and new industrial processes. There is also a significant contribution from reduced production in the most carbon dioxide intensive subsectors, and a contribution from higher efficiency in electricity generation together with a larger nuclear power share at the expense of oil. 19 refs., 5 figs., 11 tabs

  2. Combined ASTER and MODIS Emissivity database over Land (CAMEL) Coefficient Monthly Global 0.05Deg V001

    Data.gov (United States)

    National Aeronautics and Space Administration — The NASA Making Earth System Data Records for Use in Research Environments (MEaSUREs) Combined ASTER and MODIS Emissivity database over Land (CAMEL) dataset provides...

  3. Influence of inhomogeneous surface heat capacity on the estimation of radiative response coefficients in a two-zone energy balance model

    Science.gov (United States)

    Park, Jungmin; Choi, Yong-Sang

    2018-04-01

    Observationally constrained values of the global radiative response coefficient are pivotal to assess the reliability of modeled climate feedbacks. A widely used approach is to measure transient global radiative imbalance related to surface temperature changes. However, in this approach, a potential error in the estimate of radiative response coefficients may arise from surface inhomogeneity in the climate system. We examined this issue theoretically using a simple two-zone energy balance model. Here, we dealt with the potential error by subtracting the prescribed radiative response coefficient from those calculated within the two-zone framework. Each zone was characterized by the different magnitude of the radiative response coefficient and the surface heat capacity, and the dynamical heat transport in the atmosphere between the zones was parameterized as a linear function of the temperature difference between the zones. Then, the model system was forced by randomly generated monthly varying forcing mimicking time-varying forcing like an observation. The repeated simulations showed that inhomogeneous surface heat capacity causes considerable miscalculation (down to -1.4 W m-2 K-1 equivalent to 31.3% of the prescribed value) in the global radiative response coefficient. Also, the dynamical heat transport reduced this miscalculation driven by inhomogeneity of surface heat capacity. Therefore, the estimation of radiative response coefficients using the surface temperature-radiation relation is appropriate for homogeneous surface areas least affected by the exterior.

  4. High performance AlScN thin film based surface acoustic wave devices with large electromechanical coupling coefficient

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Wenbo; He, Xingli; Ye, Zhi, E-mail: yezhi@zju.edu.cn, E-mail: jl2@bolton.ac.uk; Wang, Xiaozhi [Department of Information Science and Electronic Engineering, Zhejiang University and Cyrus Tang Centre for Sensor Materials and Applications, 38 Zheda Road, Hangzhou 310027 (China); Mayrhofer, Patrick M.; Gillinger, Manuel; Bittner, Achim; Schmid, Ulrich [Institute of Sensor and Actuator Systems, Vienna University of Technology, Floragasse, 7/2/366-MST, A-1040 Vienna (Austria); Luo, J. K., E-mail: yezhi@zju.edu.cn, E-mail: jl2@bolton.ac.uk [Institute of Renewable Energy Environmental Technology, University of Bolton, Deane Road, Bolton BL3 5AB (United Kingdom); Department of Information Science and Electronic Engineering, Zhejiang University and Cyrus Tang Centre for Sensor Materials and Applications, 38 Zheda Road, Hangzhou 310027 (China)

    2014-09-29

    AlN and AlScN thin films with 27% scandium (Sc) were synthesized by DC magnetron sputtering deposition and used to fabricate surface acoustic wave (SAW) devices. Compared with AlN-based devices, the AlScN SAW devices exhibit much better transmission properties. Scandium doping results in electromechanical coupling coefficient, K{sup 2}, in the range of 2.0% ∼ 2.2% for a wide normalized thickness range, more than a 300% increase compared to that of AlN-based SAW devices, thus demonstrating the potential applications of AlScN in high frequency resonators, sensors, and high efficiency energy harvesting devices. The coupling coefficients of the present AlScN based SAW devices are much higher than that of the theoretical calculation based on some assumptions for AlScN piezoelectric material properties, implying there is a need for in-depth investigations on the material properties of AlScN.

  5. First-order exchange coefficient coupling for simulating surface water-groundwater interactions: Parameter sensitivity and consistency with a physics-based approach

    Science.gov (United States)

    Ebel, B.A.; Mirus, B.B.; Heppner, C.S.; VanderKwaak, J.E.; Loague, K.

    2009-01-01

    Distributed hydrologic models capable of simulating fully-coupled surface water and groundwater flow are increasingly used to examine problems in the hydrologic sciences. Several techniques are currently available to couple the surface and subsurface; the two most frequently employed approaches are first-order exchange coefficients (a.k.a., the surface conductance method) and enforced continuity of pressure and flux at the surface-subsurface boundary condition. The effort reported here examines the parameter sensitivity of simulated hydrologic response for the first-order exchange coefficients at a well-characterized field site using the fully coupled Integrated Hydrology Model (InHM). This investigation demonstrates that the first-order exchange coefficients can be selected such that the simulated hydrologic response is insensitive to the parameter choice, while simulation time is considerably reduced. Alternatively, the ability to choose a first-order exchange coefficient that intentionally decouples the surface and subsurface facilitates concept-development simulations to examine real-world situations where the surface-subsurface exchange is impaired. While the parameters comprising the first-order exchange coefficient cannot be directly estimated or measured, the insensitivity of the simulated flow system to these parameters (when chosen appropriately) combined with the ability to mimic actual physical processes suggests that the first-order exchange coefficient approach can be consistent with a physics-based framework. Copyright ?? 2009 John Wiley & Sons, Ltd.

  6. A theoretical and numerical study of polarimetric scattering and emission from random rough surfaces with anisotropic directional spectrum

    Science.gov (United States)

    Yueh, S. H.; Kwok, R.

    1993-01-01

    In this paper, theoretical and numerical results of the polarimetric scattering and emission from random rough surfaces with anisotropic directional spectrum are presented for the remote sensing of ocean and soil surfaces. The polarimetric scattered field for rough dielectric surfaces is derived to the second order by the small perturbation method (SPM). It is found that the second-order scattered field is coherent in nature, and its coefficients for different polarizations present the lowest-order corrections to the Fresnel reflection coefficients of the surfaces. In addition, the cross-polarized (HV and VH) components of the coherent fields are reciprocal and not zero for surfaces with anisotropic directional spectrum when the azimuth angle of the incident direction is not aligned with the symmetry directions of surfaces. In order to verify the energy conservation condition of the theoretical results, which is important if the theory is to be applied to the passive polarimetry of rough surfaces, a Monte Carlo simulation is performed to numerically calculate the polarimetric reflectivities of one-dimensional random rough surfaces which are generated with a prescribed power-law spectrum in the spectral domain and transformed to the spatial domain by the FFT. The surfaces simulated by this approach are periodic with the period corresponding to the low-wavenumber cutoff. To calculate the scattering from periodic dielectric surfaces, the authors present a new numerical technique which applies the Floquet theorem to reduce the problem to one period and does not require the evaluation of one-dimensional periodic Green's function used in the conventional method of moment formulation. Once the scattering coefficients are obtained, the polarimetric Stokes vectors for the emission from the random surfaces are then calculated according to the Kirchhoff's law and are illustrated as functions of relative azimuth observation and row directions. The second-order SPM is also

  7. Auger emission from solid surfaces bombarded with ions

    International Nuclear Information System (INIS)

    Grizzi, Oscar.

    1986-01-01

    The Auger electron emission from Be, Na, Mg, Al and Si bombarded with 0,5-20 KeV noble gas ions is studied. Sharp structures of the Auger electron spectra of Na and Be were identified. A Monte Carlo program was adapted to simulate the colision cascade in the solid, inner shell excitations and Auger decays. From the comparision of experimental and simulated Auger intensities, the relative role of symmetric and asymmetric collisions in Be K- and Al L-shell excitation were evaluated. In the case of Be, the discussion of the exciting processes to higher projectile energies was extended. To this end, the simulation to early measurements of Be K X-ray yields was applied. From this analysis, information about the variations of the fluorescence yield and outer-shell occupation numbers of Be with projectile energy was obtained. The study of the shape of the sharp Auger structures and their dependence with the energy and incidence projectile angle gives information about the collisional processes, inner hole lifetimes and Auger decays. From the evaluation of the energy and angular distribution of the excited sputtered atoms and the interaction between them and the metallic-surface, the energy shift distributions in the Auger energies were obtained. From the comparison of these distributions with the experimental atomic peaks, the main causes of the broadening of these peaks were determined. (M.E.L.) [es

  8. Effect of {gamma}-irradiation on the temperature coefficient of surface resistivity of two-dimensional island platinum films

    Energy Technology Data Exchange (ETDEWEB)

    Bishay, A.G. [Engineering Mathematics and Physics Department, Faculty of Engineering, Ain Shams University, Cairo (Egypt); El-Gamal, S., E-mail: samyelgamal@gmail.co [Physics Department, Faculty of Education, Ain Shams University, Cairo (Egypt)

    2011-05-15

    Three sets (A, B and C) of two-dimensional island platinum films (2D-I(Pt)Fs) were prepared via the thermal evaporation technique, where the substrates are corning 7059 glass slides. The mass thickness (d{sub m}) of the films of different sets is 5, 10 and 20 A, respectively. The Pt films were exposed to {gamma}-rays from {sup 137}Cs (0.662 MeV) radiation source of dose rate 0.5 Gy/min. and the different doses are 100, 200, 300, 500 and 700 Gy. The dependence of the surface resistivity ({rho}) on temperature over the range of 100-300 K was undertaken at different d{sub m} and doses then the temperature coefficient of surface resistivity ({alpha}) was deduced. It was found that; (i) for particular d{sub m} and T, the absolute value of {alpha} decreases as the dose increases (ii) for particular dose and T, the absolute value of {alpha} decreases as d{sub m} increases (iii) for particular dose and d{sub m}, the absolute value of {alpha} decreases as T increases. Qualitative interpretation for the results was offered on the ground that the electrons transfer among islands takes place by the activated tunneling mechanism and the {gamma}-irradiation has changed the shape of islands from spherical to prolate spheroid.

  9. Low thermal emissivity surfaces using AgNW thin films

    Science.gov (United States)

    Pantoja, Elisa; Bhatt, Rajendra; Liu, Anping; Gupta, Mool C.

    2017-12-01

    The properties of silver nanowire (AgNW) films in the optical and infrared spectral regime offer an interesting opportunity for a broad range of applications that require low-emissivity coatings. This work reports a method to reduce the thermal emissivity of substrates by the formation of low-emissivity AgNW coating films from solution. The spectral emissivity was characterized by thermal imaging with an FLIR camera, followed by Fourier transform infrared spectroscopy. In a combined experimental and simulation study, we provide fundamental data of the transmittance, reflectance, haze, and emissivity of AgNW thin films. Emissivity values were finely tuned by modifying the concentration of the metal nanowires in the films. The simulation models based on the transfer matrix method developed for the AgNW thin films provided optical values that show a good agreement with the measurements.

  10. Measurements of Heat-Transfer and Friction Coefficients for Helium Flowing in a Tube at Surface Temperatures up to 5900 Deg R

    Science.gov (United States)

    Taylor, Maynard F.; Kirchgessner, Thomas A.

    1959-01-01

    Measurements of average heat transfer and friction coefficients and local heat transfer coefficients were made with helium flowing through electrically heated smooth tubes with length-diameter ratios of 60 and 92 for the following range of conditions: Average surface temperature from 1457 to 4533 R, Reynolds numbe r from 3230 to 60,000, heat flux up to 583,200 Btu per hr per ft2 of heat transfer area, and exit Mach numbe r up to 1.0. The results indicate that, in the turbulent range of Reynolds number, good correlation of the local heat transfer coefficients is obtained when the physical properties and density of helium are evaluated at the surface temperature. The average heat transfer coefficients are best correlated on the basis that the coefficient varies with [1 + (L/D))(sup -0,7)] and that the physical properties and density are evaluated at the surface temperature. The average friction coefficients for the tests with no heat addition are in complete agreement with the Karman-Nikuradse line. The average friction coefficients for heat addition are in poor agreement with the accepted line.

  11. AMSR-E/Aqua Monthly Global Microwave Land Surface Emissivity

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set is a global land emissivity product using passive microwave observations from the Advanced Microwave Scanning Radiometer - Earth Observing System...

  12. On application of ion-photon emission method in spectral analysis of surface of different materials

    International Nuclear Information System (INIS)

    Bazhin, A.I.; Buravlev, Yu.M.; Ryzhov, V.N.

    1983-01-01

    Possibilities of application of ion-photom emission (IPE) method for determining element composition of the aluminium bronzes surface and profiles of distribution of hydrogen and helium implanted in metals (Mon Wn Cun Aln OKh18N10T steel) by ion bombardment have been studied. As ion source duoplasmatron which permits to obtain ions of inert (helium, argon) and active (hydrogenn oxygen) gases with current density 0.1-1 mA/cm 2 in the beam and energy from 5 to 25 keV has been applied. The photomultiplier PEM-79 has been used as a detector of optical radiation arising in the course of ion bombardment of the sample. For spectra recording the two-coordinate recorder has been used. Calibration charts which permit to determine the concentration of the investigated elements with 3-5% accuracy are obtained. The method sensitivity depends on excitation energy of transition observed in the spectrum. By known volumetric element concentration in the sample one can determine its concentration on a sUrface without resorting to a calibration chart in the coUrse of target sputtering. It has been found that the target impurity sputtering coefficient becomes nonselective to their relatiVe content. At wide incidence angles of ion beam. In contrast to other excitation methods (arc, spark) the IPE method possesses locality which constitutes 1 μm at a quite simple method of ion beam focussing (single lens)

  13. Variations in Near-Infrared Emissivity of Venus Surface Observed by the Galileo Near-Infrared Mapping Spectrometer

    Science.gov (United States)

    Hashimoto, G. L.; Roos-Serote, M.; Sugita, S.

    2004-11-01

    We evaluate the spatial variation of venusian surface emissivity at a near-infrared wavelength using multispectral images obtained by the Near-Infrared Mapping Spectrometer (NIMS) on board the Galileo spacecraft. The Galileo made a close flyby to Venus in February 1990. During this flyby, NIMS observed the nightside of Venus with 17 spectral channels, which includes the well-known spectral windows at 1.18, 1.74, and 2.3 μ m. The surface emissivity is evaluated at 1.18 μ m, at which thermal radiation emitted from the planetary surface could be detected. To analyze the NIMS observations, synthetic spectra have been generated by means of a line-by-line radiative transfer program which includes both scattering and absorption. We used the discrete ordinate method to calculate the spectra of vertically inhomogeneous plane-parallel atmosphere. Gas opacity is calculated based on the method of Pollack et al. (1993), though binary absorption coefficients for continuum opacity are adjusted to achieve an acceptable fit to the NIMS data. We used Mie scattering theory and a cloud model developed by Pollack et al. (1993) to determine the single scattering albedo and scattering phase function of the cloud particles. The vertical temperature profile of Venus International Reference Atmosphere (VIRA) is used in all our calculations. The procedure of the analysis is the followings. We first made a correction for emission angle. Then, a modulation of emission by the cloud opacities is removed using simultaneously measured 1.74 and 2.3 μ m radiances. The resulting images are correlated with the topographic map of Magellan. To search for variations in surface emissivity, this cloud corrected images are divided by synthetic radiance maps that were created from the Magellan data. This work has been supported by The 21st Century COE Program of Origin and Evolution of Planetary Systems of Ministry of Education, Culture, Sports, Science and Technology (MEXT).

  14. Volume and surface photoemission from tungsten. I. Calculation of band structure and emission spectra

    DEFF Research Database (Denmark)

    Christensen, N. Egede; Feuerbacher, B.

    1974-01-01

    of photoemission spectra from W single crystals. The nondirect as well as the direct models for bulk photoemission processes are investigated. The emission from the three low-index surfaces (100), (110), and (111) exhibits strong dependence on direction and acceptance cone. According to the present band model...... there should essentially be no emission normal to the (110) face for photon energies between 9.4 and 10.6 eV. Experimental observation of emission in this gap, however, implies effects not included in the simple bulk models. In particular, effects arising from surface emission have been considered, i.......e., emission of those electrons which are excited in a single-step process from initial states near the surface to final states outside the crystal. The electrons that are emitted from the surface in directions perpendicular to the crystal planes carry information on the one-dimensional surface density...

  15. Estimation of methane emission flux at landfill surface using laser methane detector: Influence of gauge pressure.

    Science.gov (United States)

    Park, Jin-Kyu; Kang, Jong-Yun; Lee, Nam-Hoon

    2016-08-01

    The aim of this study was to investigate the possibility of measuring methane emission fluxes, using surface methane concentration and gauge pressure, by analyzing the influence of gauge pressure on the methane emission flux and the surface methane concentration, as well as the correlation between the methane emission flux and surface methane concentrations. The surface methane concentration was measured using a laser methane detector. Our results show a positive linear relationship between the surface methane concentration and the methane emission flux. Furthermore, the methane emission flux showed a positive linear relationship with the gauge pressure; this implies that when the surface methane concentration and the surface gauge pressure are measured simultaneously, the methane emission flux can be calculated using Darcy's law. A decrease in the vertical permeability was observed when the gauge pressure was increased, because reducing the vertical permeability may lead to a reduced landfill gas emission to the atmosphere, and landfill gas would be accumulated inside the landfill. Finally, this method is simple and can allow for a greater number of measurements during a relatively shorter period. Thus, it provides a better representation of the significant space and time variations in methane emission fluxes. © The Author(s) 2016.

  16. Evaluation of self-absorption coefficients of aluminum emission lines in laser-induced breakdown spectroscopy measurements

    International Nuclear Information System (INIS)

    El Sherbini, A.M.; El Sherbini, Th.M.; Hegazy, H.; Cristoforetti, G.; Legnaioli, S.; Palleschi, V.; Pardini, L.; Salvetti, A.; Tognoni, E.

    2005-01-01

    In quantitative Laser Induced Breakdown Spectroscopy (LIBS) measurements it is essential to account for the effect of self-absorption on the emission lines intensity. In order to quantify this effect, in this paper we propose a simple method for evaluating the ratio between the actual measured line intensity and the intensity expected in absence of self-absorption and, if necessary, correcting the effect of self-absorption on line intensity. The method, based on a homogeneous plasma model, is applicable when the plasma electron density is known and in particular to lines whose Stark broadening parameter is available

  17. Energy-balance climate models: stability experiments with a refined albedo and updated coefficients for infrared emission

    NARCIS (Netherlands)

    Oerlemans, J.

    1978-01-01

    A zonally averaged' climate model of the energy-balance type is examined. Recently published satellite measurements were used to improve existing parameterizations of planetary albedo and outgoing radiation in terms of surface and sea level temperature. A realistic constant for the diffusion of

  18. A comparison of experiment, CEPXS/ONETRAN, TIGERP, and TIGER net electron emission coefficients for various bremsstrahlung spectra

    International Nuclear Information System (INIS)

    Ballard, W.P.; Lorence, L.J. Jr.; Snowden, D.P.; Van Lint, V.A.J.; Beale, E.S.

    1987-01-01

    This work compares a carefully designed experiment to measure photoemission with the predictions of three different codes (CEPXS/ONETRAN, TIGERP, and TIGER) for the complex bremsstrahlung spectra typical of very intense pulsed power x-ray generators. The Monte Carlo codes TIGER and TIGERP can calculate the net photon-induced electron emission but accurate results may require that statistical error be minimized. CEPXS/ONETRAN is a new deterministic coupled electron/photon transport code that is faster than Monte Carlo and is not subject to statistical error. The comparison of net yields is a sensitive test of the relative accuracy and efficiency of these various codes. The authors find that all of the codes substantially agree with the experiments for the forward net yields. However, for reverse net yields from high-Z materials, the codes overpredict relative to measurements

  19. The activity of γ-emitters as measured by ionisation chambers the determination of the specific emission coefficient γ for some radio-elements (1961)

    International Nuclear Information System (INIS)

    Engelmann, J.

    1962-06-01

    The object of this work is to study techniques of measurement using the gamma ionisation chamber, making it possible either to measure the activities of radioactive sources, or to determine the specific emission coefficient γ (or the coefficient K) of a given radioelement. The ionisation chambers studied belong to two categories: graphites cavity-chambers, and 4 π γ chambers. For the cavity-chamber measurements, the different correction factors of which account must be taken have been calculated, in particular the geometric and hygrometric corrections. The absorption and auto-absorption corrections have led to the introduction of the notion of the 'effective energy γ' of a radioelement. In the case of 4 π γ chambers, it has been shown that appropriately shaped electrodes make it possible to improve their performances. One of the chambers described permits the measurement of β emitters using the associated Bremsstrahlung. In order to measure the K coefficient of some radioelements, it has been found useful a 4 π γ chamber with graphite walls, the measurement being carried out by comparison with a radium standard. The validity of the method was checked with radioelements for whom the K coefficient values are well-known ( 24 Na, 60 Co, 131 I, 198 Au). For other radioelements, the following values were obtained (expressed in r cm 3 mc -1 h -1 ): 51 Cr: 0,18; 56 Mn: 8,8; 65 Zn: 3,05; 124 Sb: 9,9; 134 Cs: 9,3; 137 Cs: 3,35; 141 Ce: 0,46; 170 Tm: 0,023; 192 Ir: 24,9; 203 Hg: 1,18; These values have been corrected for the contribution to the dose of the fluorescent radiation which may be emitted by the source, except in the case of Tm 170 . In the last part of this work, the performances of the different electro-metric devices used were compared. (author) [fr

  20. Evaluation of gas emission from closed mines surface to atmosphere

    OpenAIRE

    Pokryszka, Zbigniew; Tauziède, Christian

    2000-01-01

    International audience; The closed mines are likely to release into atmosphere polluting or/and dangerous gases. The detection and hazard evaluation of those emissions are a complex problem. In order to quantify and qualify these gas emissions and check gas migrations special measuring methods are required. The research done at INERIS resulted in a reliable and appropriate methodology using a flux chamber. This methodology is intended for detecting, quantifying and qualifying gas discharges, ...

  1. Spontaneous emission near non-trivial conducting surfaces

    International Nuclear Information System (INIS)

    Melo e Souza, Reinaldo de; Kort-Kamp, W.J.M.; Taddei, M.M.; Farina, C.

    2013-01-01

    Full text: One of the remarkable phenomena associated with the zero-point fluctuations of the electromagnetic field is the spontaneous emission, which accounts for the emission of photons by an excited atom placed in vacuum. As discovered by Purcell in the 1940's, the spontaneous emission rate depends not only on the atomic properties but also on the nearby bodies. This should be expected once the electromagnetic field modes are affected by the boundary conditions imposed by these bodies. We begin our presentation reviewing a method which establishes a striking connection between the spontaneous emission of an excited atom and the classical radiation emitted by an oscillating real dipole. In fact, it can be shown, the influence of the neighbouring bodies is the same in both cases. We use this approach to evaluate the influence of an infinite conducting plane with a circular aperture on the spontaneous emission rate of the atom. This geometry will be particularly interesting if the atom is placed on the axis of symmetry of the hole and if it is predominantly polarizable in this axis, once this configuration is one of the those rare configurations that give rise to repulsive dispersive interactions. It would be very interesting to establish some connection between how the spontaneous emission rate of an excited atom is influenced by the presence of material bodies and the attractive or repulsive character of the dispersive force between that atom (in its ground state) and those material bodies. (author)

  2. Separation of Atmospheric and Surface Spectral Features in Mars Global Surveyor Thermal Emission Spectrometer (TES) Spectra

    Science.gov (United States)

    Smith, Michael D.; Bandfield, Joshua L.; Christensen, Philip R.

    2000-01-01

    We present two algorithms for the separation of spectral features caused by atmospheric and surface components in Thermal Emission Spectrometer (TES) data. One algorithm uses radiative transfer and successive least squares fitting to find spectral shapes first for atmospheric dust, then for water-ice aerosols, and then, finally, for surface emissivity. A second independent algorithm uses a combination of factor analysis, target transformation, and deconvolution to simultaneously find dust, water ice, and surface emissivity spectral shapes. Both algorithms have been applied to TES spectra, and both find very similar atmospheric and surface spectral shapes. For TES spectra taken during aerobraking and science phasing periods in nadir-geometry these two algorithms give meaningful and usable surface emissivity spectra that can be used for mineralogical identification.

  3. Thermal Rate Coefficients and Kinetic Isotope Effects for the Reaction OH + CH4 → H2O + CH3 on an ab Initio-Based Potential Energy Surface.

    Science.gov (United States)

    Li, Jun; Guo, Hua

    2018-03-15

    Thermal rate coefficients for the title reaction and its various isotopologues are computed using a tunneling-corrected transition-state theory on a global potential energy surface recently developed by fitting a large number of high-level ab initio points. The calculated rate coefficients are found to agree well with the measured ones in a wide temperature range, validating the accuracy of the potential energy surface. Strong non-Arrhenius effects are found at low temperatures. In addition, the calculations reproduced the primary and secondary kinetic isotope effects. These results confirm the strong influence of tunneling to this heavy-light-heavy hydrogen abstraction reaction.

  4. Near-surface thermal gradients and their effects on mid-infrared emission spectra of planetary surfaces

    Science.gov (United States)

    Henderson, B. G.; Jakosky, B. M.

    1994-01-01

    We model the heat transfer by radiation and conduction in the top few millimeters of a planetary surface to determine the magnitude of near-surface (approximately 100 micrometers) thermal gradients and their effects on mid-infrared emission spectra for a number of planetary environments. The model is one-dimensional and uses a finite difference scheme for approximately 10 micrometers layers. Calculations are peformed for samples heated at the base and from above by sunlight. Our results indicate that near-surface radiative cooling creates significant thermal gradients in the top few hundred microns of surfaces in which radiation is an importamnt heat transfer mechanism. The effect is maximized in evacuated, underdense particulate media with sufficiently high temperatures. Near-surface thermal gradients will be significant in fine-grained particulate surfaces on the Moon (40-60 K/100 micrometers) and Mercury (approximately 80 K/100 micrometers), increasing spectral contrast and creating emission maxima in the transparent regions of the spectra. They will be of lesser importance on the surface of Mars, with a maximum value of around 5 k/100 micrometers in areas of low thermal inertia, and will be negligible on planets with more substantial atmospheres (less than 1 K/100 micrometers). We conclude that the effects that thermal gradients have on mid-IR emission spectra are predictable and do not negate the utility of emission spectroscopy for remote determination of planetary surface composition.

  5. A Study on Infrared Emissivity Measurement of Material Surface by Reflection Method

    International Nuclear Information System (INIS)

    Kang, Byung Chul; Kim, Sang Myoung; Choi, Joung Yoon; Kim, Gun Ok

    2010-01-01

    Infrared emissivity is one of the most important factors for the temperature measurement by infrared thermography. Although the infrared emissivity of an object can be measured from the ratio of blackbody and the object, at room temperature it is practically difficult to measure the value due to the background effects. Hence, quantitative reflectance of bare steel plate and the surface of coating was measured by FT-IR spectroscopy and emissivity was calculated from this. The emissivity of polished bare steel surface was from 0.06 to 0.10 and the value for the unpolished bare steel can not be achieved because optical characteristics changes of surface roughness induces erroneous results. Emissivity of transparent paint coated steel was from 0.50 to 0.84. Depends on the IR absorption regions, which is a characteristic value of the coating, emissivity changes. This study suggests surface condition of material, thickness, roughness etcetra are important factor for IR optical characteristics. Emissivity measurement by reflection method is useful technique to be applied for metal and it with coating applied on the surface. The range of experimental errors of temperature can be narrowed by the application of infrared thermography from the measured thermal emissivity

  6. Effect of surface morphology and densification on the infrared emissivity of C/SiC composites

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Fuyuan, E-mail: wangfy1986@gmail.com; Cheng, Laifei; Zhang, Qing, E-mail: zhangqing@nwpu.edu.cn; Zhang, Litong

    2014-09-15

    Highlights: • The cauliflower-like microstructure improved the infrared emissivity multiply. • The infrared emissivity decreased continually with the improving surface flatness. • The densification process boosted the infrared emissivity. - Abstract: The effects of surface morphology and densification on the infrared emissivity of 2D C/SiC composites were investigated in 6–16 μm from 1000 °C to 1600 °C. As the sample surface was polished, the reflection and scattering for the electromagnetic waves of thermal radiation were reduced, causing a sustained decrease in the infrared emissivity. The space-variant polarizations caused by the cauliflower-like microstructure were enervated in the smooth surface, which enhanced the reduction trendy in the infrared emissivity. In densification process, the increasing SiC content and the growing amount of the cauliflower-like microstructure on sample surface improved the infrared emissivity of C/SiC composites, while the decreasing porosity decreased it. Due to the greater positive effects on the thermal radiation during the densification process, the infrared emissivity of C/SiC composites increased successively with density.

  7. Effects of fibre-form nanostructures on particle emissions from a tungsten surface in plasmas

    International Nuclear Information System (INIS)

    Takamura, S.; Miyamoto, T.; Ohno, N.

    2012-01-01

    The effects of fibre-form nanostructure of a tungsten surface on both electron emission and sputtering in helium/argon plasmas are represented. Generally, a nano-fibre forest, the so-called ‘fuzz’, made of tungsten with helium gas inside is found to have the tendency of suppressing the particle emission substantially. The electron emission comes from the impact of high-energy primary electrons. In addition, a deeply biased tungsten target, which inhibits the influx of even energetic primary electrons, seems to produce an electron emission, and it may be suppressed on the way to nanostructure formation on the surface of the W target. Such an emission process is discussed here. The sputtering yield of the He-damaged tungsten surface with the fibre-form nanostructure depends on the surface morphology while the sputtering itself changes the surface morphology, so that the time evolutions of sputtering yield from the W surface with an originally well-developed nanostructure are found to show a minimum in sputtering yield, which is about a half for the fresh nanostructured tungsten and roughly one-fifth of the yield for the original flat normal tungsten surface. The surface morphology at that time is, for the first time, made clear with field emission scanning electron microscopy observation. The physical mechanism for the appearance of such a minimum in sputtering yield is discussed. (paper)

  8. A comparison of experiment, CEPXS/ONETRAN, TIGERP, and QUICKE2 net electron emission coefficients for various bremsstrahlung spectra

    International Nuclear Information System (INIS)

    Ballard, W.P.; Lorence, L.J. Jr.; Snowden, D.P.; van Lint, V.A.J.; Beale, E.S.

    1987-01-01

    This work compares a carefully designed experiment with the predictions of four different codes (CEPXS/ONETRAN, TIGERP, TIGER and QUICKE2) for the complex bremsstrahlung spectra typical of very intense pulsed power x-ray generators. Accurate calculation of net photon-induced electron emission yields at material interfaces using Monte Carlo codes can be particularly difficult if the forward and reverse partial yields are of similar magnitudes. In such a circumstance, the statistical error in the Monte Carlo solution (TIGER or TIGERP) must be kept to a minimum to accurately resolve the difference. CEPXS/ONETRAN is a new deterministic coupled electron/photon transport code that is faster than Monte Carlo and is not subject to statistical error. QUICKE2 evaluates an analytical approximation and is also much less expensive to run than the Monte Carlo codes. The comparison of net yields is a sensitive test of the relative accuracy and efficiency of these various codes. We find that all of the codes except QUICKE2 substantially agree with the experiments for the forward net yields. Howver, for reverse net yields from high-Z materials, all the codes overpredict relative to measurements

  9. Study of land surface temperature and spectral emissivity using multi ...

    Indian Academy of Sciences (India)

    LST) and spectral emissivities over a hard rock terrain using multi-sensor satellite data. The study area, of about 6000 km2, is a part of Singhbhum–Orissa craton situated in the eastern part of India. TIR data from ASTER, MODIS and Landsat ...

  10. Dust emissions from undisturbed and disturbed, crusted playa surfaces: cattle trampling effects

    Science.gov (United States)

    Dry playa lake beds can be significant sources of fine dust emission. This study used a portable field wind tunnel to quantify the PM10 emissions from a bare, fine-textured playa surface located in the far northern Chihuahua Desert. The natural, undisturbed crust and its subjection to two levels of ...

  11. Measurement of PCB emissions from building surfaces using a novel portable emission test cell

    DEFF Research Database (Denmark)

    Lyng, Nadja; Gunnarsen, Lars Bo; Andersen, Helle Vibeke

    2016-01-01

    Polychlorinated biphenyls (PCBs) were used in building materials like caulks and paints from 1930 e1970s and in some cases that caused elevated PCB concentrations in the indoor air at levels considered harmful to occupant health. PCBs are semivolatile organic compounds and capable of spreading from...... and there is a need to prioritise remediation measures on different materials. An inexpensive and portable emission test cell was developed to resemble indoor conditions in relation to the area specific ventilation rate. Emissions were measured using the test cell in the laboratory on freshly made PCB paint. Further......, the chamber was used for determining emissions from PCB-containing building materials in the field as well as remediated walls. The measurements showed that sorption of PCBs to chamber walls was insignificant after 2-4 days of exposure to the source. Over a period of two weeks emission rates did not change...

  12. Surface Coating of Wood Building Products National Emission Standards for Hazardous Air Pollutants (NESHAP) Applicability Flowchart

    Science.gov (United States)

    This page contains a January 2005 document that has a flow chart to help you determine if this National Emission Standards for Hazardous Air Pollutants (NESHAP) rule for Surface Coating of Wood Building Products applies to your facility.

  13. Chemical analysis of industrial scale deposits by combined use of correlation coefficients with emission line detection of laser induced breakdown spectroscopy spectra

    International Nuclear Information System (INIS)

    Siozos, P.; Philippidis, A.; Hadjistefanou, M.; Gounarakis, C.; Anglos, D.

    2013-01-01

    Laser-induced breakdown spectroscopy (LIBS) was used to determine the mineral composition of various industrial scale samples. The aim of the study has been to investigate the capacity of LIBS to provide a fast, reliable analytical tool for carrying out routine analysis of inorganic scales, potentially on site, as a means to facilitate decision making concerning scale removal procedures. LIBS spectra collected in the range of 200–660 nm conveyed information about the metal content of the minerals. Via a straightforward analysis based on linear correlation of LIBS spectra it was possible to successfully discriminate scale samples into three main groups, Fe-rich, Ca-rich and Ba-rich, on the basis of correlation coefficients. By combining correlation coefficients with spectral data collected in the NIR, 860–960 nm, where sulfur emissions are detected, it became further possible to discriminate sulfates from carbonates as confirmed by independent analysis based on Raman spectroscopy. It is emphasized that the proposed LIBS-based method successfully identifies the major mineral or minerals present in the samples classifying the scales into relevant groups hence enabling process engineers to select appropriate scale dissolution strategies. - Highlights: • LIBS was used to determine the mineral composition of industrial scale samples. • Three groups of inorganic scales were identified: Ca rich, Ba rich and Fe rich. • A method that combines correlation coefficients and line detection is proposed. • The method successfully identifies the main mineral, or minerals, in the samples. • The results were compared with results obtained by use of Raman analysis

  14. Emission factors for wind erosion of exposed aggregates at surface coal mines

    Energy Technology Data Exchange (ETDEWEB)

    Cowherd, C.

    1982-06-01

    The information presented in this paper is directed to those interested in inventorying dust emissions generated by wind erosion of exposed aggregates at surface coal mines. A testing program is described which entailed the use of a portable wind tunnel and an isokinetic sampling system to measure windblown dust emissions from coal and overburden materials at three western mine sites. Test measurements consisted of particle mass emission rates and size distributions for various control wind speeds and times after the initiation of wind erosion. The results indicate that natural surface crusts are very effective in mitigating suspended dust emissions and that a given surface has a finite potential for wind erosion subsequent to mechanical disturbance. Test data are used to develop a predictive emission factor equation which relates emission rate (per unit surface area) to the frequency of disturbance and the erosion potential corresponding to the fastest mile of wind for the period between disturbances. This equation can be used directly for flat surfaces or it can be coupled with an analysis of wind flow patterns around elevated storage piles to develop dust emission estimates for overall pile erosion.

  15. Normalized lift: an energy interpretation of the lift coefficient simplifies comparisons of the lifting ability of rotating and flapping surfaces.

    Directory of Open Access Journals (Sweden)

    Phillip Burgers

    Full Text Available For a century, researchers have used the standard lift coefficient C(L to evaluate the lift, L, generated by fixed wings over an area S against dynamic pressure, ½ρv(2, where v is the effective velocity of the wing. Because the lift coefficient was developed initially for fixed wings in steady flow, its application to other lifting systems requires either simplifying assumptions or complex adjustments as is the case for flapping wings and rotating cylinders.This paper interprets the standard lift coefficient of a fixed wing slightly differently, as the work exerted by the wing on the surrounding flow field (L/ρ·S, compared against the total kinetic energy required for generating said lift, ½v(2. This reinterpreted coefficient, the normalized lift, is derived from the work-energy theorem and compares the lifting capabilities of dissimilar lift systems on a similar energy footing. The normalized lift is the same as the standard lift coefficient for fixed wings, but differs for wings with more complex motions; it also accounts for such complex motions explicitly and without complex modifications or adjustments. We compare the normalized lift with the previously-reported values of lift coefficient for a rotating cylinder in Magnus effect, a bat during hovering and forward flight, and a hovering dipteran.The maximum standard lift coefficient for a fixed wing without flaps in steady flow is around 1.5, yet for a rotating cylinder it may exceed 9.0, a value that implies that a rotating cylinder generates nearly 6 times the maximum lift of a wing. The maximum normalized lift for a rotating cylinder is 1.5. We suggest that the normalized lift can be used to evaluate propellers, rotors, flapping wings of animals and micro air vehicles, and underwater thrust-generating fins in the same way the lift coefficient is currently used to evaluate fixed wings.

  16. Investigation of sandwich material surface created by abrasive water jet (AWJ via vibration emission

    Directory of Open Access Journals (Sweden)

    P. Hreha

    2014-01-01

    Full Text Available The paper presents research a of abrasive waterjet cutting of heterogeneous “sandwich“ material with different Young modulus of elasticity of the cutted surface geometry by means of vibration emission. In order to confirm hypothetical assumptions about direct relation between vibration emission and surface quality an experiment in heterogeneous material consisting of stainless steel (DIN 1.4006 / AISI 410 and alloy AlCuMg2 has been provided.

  17. Surface influence on convoy electron emission at low energies

    International Nuclear Information System (INIS)

    Sanchez, E.A.

    1988-01-01

    It is studied the dependence of the production of convoy electrons induced by H + - 60 KeV with surface conditions of Al targets by in situ deposition of Na and O. The conclusion is that convoy electron production increases with the work function of the surface. (A.C.A.S.) [pt

  18. Field emission from the surface of highly ordered pyrolytic graphite

    Czech Academy of Sciences Publication Activity Database

    Knápek, Alexandr; Sobola, D.; Tománek, P.; Pokorná, Zuzana; Urbánek, Michal

    2017-01-01

    Roč. 395, FEB 15 (2017), s. 157-161 ISSN 0169-4332 R&D Projects: GA TA ČR(CZ) TE01020118 Institutional support: RVO:68081731 Keywords : field emission * HOPG * scanning electron microscopy * scanning near-field optical microscopy Subject RIV: JA - Electron ics ; Optoelectronics, Electrical Engineering OBOR OECD: Nano-processes (applications on nano-scale) Impact factor: 3.387, year: 2016

  19. VDI 2083-17: VOC emissions from material surfaces

    OpenAIRE

    Keller, Markus; Bürger, Frank

    2010-01-01

    In such fields as cleanroom technology, food, pharmaceutics and health care as well as in normal living and working environments, materials implemented in specific applications need to be assessed for VOC emissions and classified in order to permit direct comparisons to be made. The paper presents a standardized procedure for testing and classifying materials with uniform sample preparation and defined storage times. It describes preparation of the samples, their measurement in a VOC-free min...

  20. Estimating Land Surface Temperature from Feng Yun-3C/MERSI Data Using a New Land Surface Emissivity Scheme

    Directory of Open Access Journals (Sweden)

    Xiangchen Meng

    2017-12-01

    Full Text Available Land surface temperature (LST is a key parameter for a wide number of applications, including hydrology, meteorology and surface energy balance. In this study, we first proposed a new land surface emissivity (LSE scheme, including a lookup table-based method to determine the vegetated surface emissivity and an empirical method to derive the bare soil emissivity from the Global LAnd Surface Satellite (GLASS broadband emissivity (BBE product. Then, the Modern Era Retrospective-Analysis for Research and Applications (MERRA reanalysis data and the Feng Yun-3C/Medium Resolution Spectral Imager (FY-3C/MERSI precipitable water vapor product were used to correct the atmospheric effects. After resolving the land surface emissivity and atmospheric effects, the LST was derived in a straightforward manner from the FY-3C/MERSI data by the radiative transfer equation algorithm and the generalized single-channel algorithm. The mean difference between the derived LSE and field-measured LSE over seven stations is approximately 0.002. Validation of the LST retrieved with the LSE determined by the new scheme can achieve an acceptable accuracy. The absolute biases are less than 1 K and the STDs (RMSEs are less than 1.95 K (2.2 K for both the 1000 m and 250 m spatial resolutions. The LST accuracy is superior to that retrieved with the LSE determined by the commonly used Normalized Difference Vegetation Index (NDVI threshold method. Thus, the new emissivity scheme can be used to improve the accuracy of the LSE and further the LST for sensors with broad spectral ranges such as FY-3C/MERSI.

  1. Effect of metallic and hyperbolic metamaterial surfaces on electric and magnetic dipole emission transitions

    DEFF Research Database (Denmark)

    Ni, X.; Naik, G. V.; Kildishev, A. V.

    2011-01-01

    Spontaneous emission patterns of electric and magnetic dipoles on different metallic surfaces and a hyperbolic metamaterial (HMM) surface were simulated using the dyadic Green’s function technique. The theoretical approach was verified by experimental results obtained by measuring angular-depende......-dependent emission spectra of europium ions on top of different films. The results show the modified behavior of electric and magnetic dipoles on metallic and HMM surfaces. The results of numerical calculations agree well with experimental data.......Spontaneous emission patterns of electric and magnetic dipoles on different metallic surfaces and a hyperbolic metamaterial (HMM) surface were simulated using the dyadic Green’s function technique. The theoretical approach was verified by experimental results obtained by measuring angular...

  2. Field emission and high voltage cleaning of particulate contaminants on extended metallic surfaces

    International Nuclear Information System (INIS)

    Tan, J.; Bonin, B.; Safa, H.

    1996-01-01

    The vacuum insulation properties of extended metallic surfaces depends strongly on their cleanliness. The usual technique to reduce electronic field emission from such surfaces consists in exposing them to very high electric fields during limited periods of time. This kind of processing also reduces the occurrence of vacuum breakdown. The processing of the surface is generally believed to be due to a thermomechanical destruction of the emitting sites, initiated by the emission itself. Comparison of the electric forces vs adherence forces which act on dust particles lying on the surface shows that the processing could also be due simply to the mechanical removal of the dust particles, with a subsequent reduction of field emission from the contaminated surface. (author)

  3. Emission-dominated gas exchange of elemental mercury vapor over natural surfaces in China

    Directory of Open Access Journals (Sweden)

    X. Wang

    2016-09-01

    Full Text Available Mercury (Hg emission from natural surfaces plays an important role in global Hg cycling. The present estimate of global natural emission has large uncertainty and remains unverified against field data, particularly for terrestrial surfaces. In this study, a mechanistic model is developed for estimating the emission of elemental mercury vapor (Hg0 from natural surfaces in China. The development implements recent advancements in the understanding of air–soil and air–foliage exchange of Hg0 and redox chemistry in soil and on surfaces, incorporates the effects of soil characteristics and land use changes by agricultural activities, and is examined through a systematic set of sensitivity simulations. Using the model, the net exchange of Hg0 between the atmosphere and natural surfaces of mainland China is estimated to be 465.1 Mg yr−1, including 565.5 Mg yr−1 from soil surfaces, 9.0 Mg yr−1 from water bodies, and −100.4 Mg yr−1 from vegetation. The air–surface exchange is strongly dependent on the land use and meteorology, with 9 % of net emission from forest ecosystems; 50 % from shrubland, savanna, and grassland; 33 % from cropland; and 8 % from other land uses. Given the large agricultural land area in China, farming activities play an important role on the air–surface exchange over farmland. Particularly, rice field shift from a net sink (3.3 Mg uptake during April–October (rice planting to a net source when the farmland is not flooded (November–March. Summing up the emission from each land use, more than half of the total emission occurs in summer (51 %, followed by spring (28 %, autumn (13 %, and winter (8 %. Model verification is accomplished using observational data of air–soil/air–water fluxes and Hg deposition through litterfall for forest ecosystems in China and Monte Carlo simulations. In contrast to the earlier estimate by Shetty et al. (2008 that reported large emission from

  4. Temporal Arctic longwave surface emissivity feedbacks in the Community Earth System Model

    Science.gov (United States)

    Kuo, C.; Feldman, D.; Huang, X.; Flanner, M.; Yang, P.; Chen, X.

    2017-12-01

    We have investigated how the inclusion of realistic and consistent surface emissivity in both land-surface and atmospheric components of the CESM coupled-climate model affects a wide range of climate variables. We did this by replacing the unit emissivity values in RRTMG_LW for water, fine-grained snow, and desert scenes with spectral emissivity values, and by replacing broadband emissivity values in surface components with the Planck-curve weighted counterparts. We find that this harmonized treatment of surface emissivity within CESM can be important for reducing high-latitude temperature biases. We also find that short-term effects of atmospheric dynamics and spectral information need to be considered to understand radiative effects in higher detail, and are possible with radiative kernels computed for every grid and time point for the entire model integration period. We find that conventional climatological feedback calculations indicate that sea-ice emissivity feedback is positive in sign, but that the radiative effects of the difference in emissivity between frozen and unfrozen surfaces exhibit seasonal dependence. Furthermore, this seasonality itself exhibits meridional asymmetry due to differences in sea-ice response to climate forcing between the Arctic and the Antarctic. In the Arctic, this seasonal, temporally higher order analysis exhibits increasing outgoing surface emissivity radiative response in a warming climate. While the sea-ice emissivity feedback and seasonal sea-ice emissivity radiative response amplitudes are a few percent of surface albedo feedbacks, the feedback analysis methods outlined in this work demonstrate that spatially and temporally localized feedback analysis can give insight into the mechanisms at work on those scales which differ in amplitude and sign from conventional climatological analyses. We note that the inclusion of this realistic physics leads to improved agreement between CESM model results and Arctic surface

  5. Electron emission from MOS electron emitters with clean and cesium covered gold surface

    DEFF Research Database (Denmark)

    Nielsen, Gunver; Thomsen, Lasse Bjørchmar; Johansson, Martin

    2009-01-01

    MOS (metal-oxide-semiconductor) electron emitters consisting of a Si substrate, a SiO2 tunnel barrier and a Ti (1 nm)/Au(7 nm) top-electrode, with an active area of 1 cm(2) have been produced and studied with surface science techniques under UHV (ultra high vacuum) conditions and their emission...... characteristics have been investigated. It is known, that deposition of an alkali metal on the emitting surface lowers the work function and increases the emission efficiency. For increasing Cs coverages the surface has been characterized by X-ray Photoelectron Spectroscopy (XPS), Ion Scattering Spectroscopy (ISS...

  6. Surface Emissivity Retrieved with Satellite Ultraspectral IR Measurements for Monitoring Global Change

    Science.gov (United States)

    Zhou, Daniel K.; Larar, Allen M.; Liu, Xu; Smith, William L.; Schluessel, Peter

    2009-01-01

    Surface and atmospheric thermodynamic parameters retrieved with advanced ultraspectral remote sensors aboard Earth observing satellites are critical to general atmospheric and Earth science research, climate monitoring, and weather prediction. Ultraspectral resolution infrared radiance obtained from nadir observations provide atmospheric, surface, and cloud information. Presented here is the global surface IR emissivity retrieved from Infrared Atmospheric Sounding Interferometer (IASI) measurements under "clear-sky" conditions. Fast radiative transfer models, applied to the cloud-free (or clouded) atmosphere, are used for atmospheric profile and surface parameter (or cloud parameter) retrieval. The inversion scheme, dealing with cloudy as well as cloud-free radiances observed with ultraspectral infrared sounders, has been developed to simultaneously retrieve atmospheric thermodynamic and surface (or cloud microphysical) parameters. Rapidly produced surface emissivity is initially evaluated through quality control checks on the retrievals of other impacted atmospheric and surface parameters. Surface emissivity and surface skin temperature from the current and future operational satellites can and will reveal critical information on the Earth s ecosystem and land surface type properties, which can be utilized as part of long-term monitoring for the Earth s environment and global climate change.

  7. An intercomparative study of the effects of aircraft emissions on surface air quality

    Science.gov (United States)

    Cameron, M. A.; Jacobson, M. Z.; Barrett, S. R. H.; Bian, H.; Chen, C. C.; Eastham, S. D.; Gettelman, A.; Khodayari, A.; Liang, Q.; Selkirk, H. B.; Unger, N.; Wuebbles, D. J.; Yue, X.

    2017-08-01

    This study intercompares, among five global models, the potential impacts of all commercial aircraft emissions worldwide on surface ozone and particulate matter (PM2.5). The models include climate-response models (CRMs) with interactive meteorology, chemical-transport models (CTMs) with prescribed meteorology, and models that integrate aspects of both. Model inputs are harmonized in an effort to achieve a consensus about the state of understanding of impacts of 2006 commercial aviation emissions. Models find that aircraft increase near-surface ozone (0.3 to 1.9% globally), with qualitatively similar spatial distributions, highest in the Northern Hemisphere. Annual changes in surface-level PM2.5 in the CTMs (0.14 to 0.4%) and CRMs (-1.9 to 1.2%) depend on differences in nonaircraft baseline aerosol fields among models and the inclusion of feedbacks between aircraft emissions and changes in meteorology. The CTMs tend to result in an increase in surface PM2.5 primarily over high-traffic regions in the North American midlatitudes. The CRMs, on the other hand, demonstrate the effects of aviation emissions on changing meteorological fields that result in large perturbations over regions where natural emissions (e.g., soil dust and sea spray) occur. The changes in ozone and PM2.5 found here may be used to contextualize previous estimates of impacts of aircraft emissions on human health.

  8. Electron emission from MOS electron emitters with clean and cesium covered gold surface

    International Nuclear Information System (INIS)

    Nielsen, Gunver; Thomsen, Lasse Bjorchmar; Johansson, Martin; Hansen, Ole; Chorkendorff, Ib

    2009-01-01

    MOS (metal-oxide-semiconductor) electron emitters consisting of a Si substrate, a SiO 2 tunnel barrier and a Ti (1 nm)/Au(7 nm) top-electrode, with an active area of 1 cm 2 have been produced and studied with surface science techniques under UHV (ultra high vacuum) conditions and their emission characteristics have been investigated. It is known, that deposition of an alkali metal on the emitting surface lowers the work function and increases the emission efficiency. For increasing Cs coverages the surface has been characterized by X-ray Photoelectron Spectroscopy (XPS), Ion Scattering Spectroscopy (ISS) and work function measurements. Energy spectra of electron emission from the devices under an applied bias voltage have been recorded for the clean Au surface and for two Cs coverages and simultaneous work function curves have been obtained. The electron emission onset is seen to appear at the surface work function. A method for cleaning the ex situ deposited Au top electrodes to a degree satisfactory to surface science studies has been developed, and a threshold for oxide damage by low-energy ion exposure between 0.5 and 1 keV has been determined.

  9. Synthesis of Carbon Dots with Multiple Color Emission by Controlled Graphitization and Surface Functionalization.

    Science.gov (United States)

    Miao, Xiang; Qu, Dan; Yang, Dongxue; Nie, Bing; Zhao, Yikang; Fan, Hongyou; Sun, Zaicheng

    2018-01-01

    Multiple-color-emissive carbon dots (CDots) have potential applications in various fields such as bioimaging, light-emitting devices, and photocatalysis. The majority of the current CDots to date exhibit excitation-wavelength-dependent emissions with their maximum emission limited at the blue-light region. Here, a synthesis of multiple-color-emission CDots by controlled graphitization and surface function is reported. The CDots are synthesized through controlled thermal pyrolysis of citric acid and urea. By regulating the thermal-pyrolysis temperature and ratio of reactants, the maximum emission of the resulting CDots gradually shifts from blue to red light, covering the entire light spectrum. Specifically, the emission position of the CDots can be tuned from 430 to 630 nm through controlling the extent of graphitization and the amount of surface functional groups, COOH. The relative photoluminescence quantum yields of the CDots with blue, green, and red emission reach up to 52.6%, 35.1%, and 12.9%, respectively. Furthermore, it is demonstrated that the CDots can be uniformly dispersed into epoxy resins and be fabricated as transparent CDots/epoxy composites for multiple-color- and white-light-emitting devices. This research opens a door for developing low-cost CDots as alternative phosphors for light-emitting devices. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Laser pulse transient method for measuring the normal spectral emissivity of samples with arbitrary surface quality

    Science.gov (United States)

    Jeromen, A.; Grabec, I.; Govekar, E.

    2008-09-01

    A laser pulse transient method for measuring normal spectral emissivity is described. In this method, a laser pulse ( λ=1064 nm) irradiates the top surface of a flat specimen. A two-dimensional temperature response of the bottom surface is measured with a calibrated thermographic camera. By solving an axisymmetric boundary value heat conduction problem, the normal spectral emissivity at 1064 nm is determined by using an iterative nonlinear least-squares estimation procedure. The method can be applied to arbitrary sample surface quality. The method is tested on a nickel specimen and used to determine the normal spectral emissivity of AISI 304 stainless steel. The expanded combined uncertainty of the method has been estimated to be 18%.

  11. Low temperature rate coefficients of the H + CH(+) → C(+) + H2 reaction: New potential energy surface and time-independent quantum scattering.

    Science.gov (United States)

    Werfelli, Ghofran; Halvick, Philippe; Honvault, Pascal; Kerkeni, Boutheïna; Stoecklin, Thierry

    2015-09-21

    The observed abundances of the methylidyne cation, CH(+), in diffuse molecular clouds can be two orders of magnitude higher than the prediction of the standard gas-phase models which, in turn, predict rather well the abundances of neutral CH. It is therefore necessary to investigate all the possible formation and destruction processes of CH(+) in the interstellar medium with the most abundant species H, H2, and e(-). In this work, we address the destruction process of CH(+) by hydrogen abstraction. We report a new calculation of the low temperature rate coefficients for the abstraction reaction, using accurate time-independent quantum scattering and a new high-level ab initio global potential energy surface including a realistic model of the long-range interaction between the reactants H and CH(+). The calculated thermal rate coefficient is in good agreement with the experimental data in the range 50 K-800 K. However, at lower temperatures, the experimental rate coefficient takes exceedingly small values which are not reproduced by the calculated rate coefficient. Instead, the latter rate coefficient is close to the one given by the Langevin capture model, as expected for a reaction involving an ion and a neutral species. Several recent theoretical works have reported a seemingly good agreement with the experiment below 50 K, but an analysis of these works show that they are based on potential energy surfaces with incorrect long-range behavior. The experimental results were explained by a loss of reactivity of the lowest rotational states of the reactant; however, the quantum scattering calculations show the opposite, namely, a reactivity enhancement with rotational excitation.

  12. Time-Dependent Cryospheric Longwave Surface Emissivity Feedback in the Community Earth System Model

    Science.gov (United States)

    Kuo, Chaincy; Feldman, Daniel R.; Huang, Xianglei; Flanner, Mark; Yang, Ping; Chen, Xiuhong

    2018-01-01

    Frozen and unfrozen surfaces exhibit different longwave surface emissivities with different spectral characteristics, and outgoing longwave radiation and cooling rates are reduced for unfrozen scenes relative to frozen ones. Here physically realistic modeling of spectrally resolved surface emissivity throughout the coupled model components of the Community Earth System Model (CESM) is advanced, and implications for model high-latitude biases and feedbacks are evaluated. It is shown that despite a surface emissivity feedback amplitude that is, at most, a few percent of the surface albedo feedback amplitude, the inclusion of realistic, harmonized longwave, spectrally resolved emissivity information in CESM1.2.2 reduces wintertime Arctic surface temperature biases from -7.2 ± 0.9 K to -1.1 ± 1.2 K, relative to observations. The bias reduction is most pronounced in the Arctic Ocean, a region for which Coupled Model Intercomparison Project version 5 (CMIP5) models exhibit the largest mean wintertime cold bias, suggesting that persistent polar temperature biases can be lessened by including this physically based process across model components. The ice emissivity feedback of CESM1.2.2 is evaluated under a warming scenario with a kernel-based approach, and it is found that emissivity radiative kernels exhibit water vapor and cloud cover dependence, thereby varying spatially and decreasing in magnitude over the course of the scenario from secular changes in atmospheric thermodynamics and cloud patterns. Accounting for the temporally varying radiative responses can yield diagnosed feedbacks that differ in sign from those obtained from conventional climatological feedback analysis methods.

  13. Influence of the projectile charge state on electron emission spectra from a Cu(111) surface

    Science.gov (United States)

    Archubi, C. D.; Silkin, V. M.; Gravielle, M. S.

    2015-09-01

    Double differential electron emission distributions produced by grazing impact of fast dressed ions on a Cu(111) surface are investigated focusing on the effects of the electronic band structure. The process is described within the Band-Structure-Based approximation, which is a perturbative method that includes an accurate representation of the electron-surface interaction, incorporating information of the electronic band structure of the solid. Differences in the behavior of the emission spectra for He+ q, Li+ q, Be+ q and C+ q projectiles with different charge states q are explained by the combined effect of the projectile trajectory and the projectile charge distribution.

  14. The impact of anthropogenic and biogenic emissions on surface ozone concentrations in Istanbul.

    Science.gov (United States)

    Im, Ulas; Poupkou, Anastasia; Incecik, Selahattin; Markakis, Konstantinos; Kindap, Tayfun; Unal, Alper; Melas, Dimitros; Yenigun, Orhan; Topcu, Sema; Odman, M Talat; Tayanc, Mete; Guler, Meltem

    2011-03-01

    Surface ozone concentrations at Istanbul during a summer episode in June 2008 were simulated using a high resolution and urban scale modeling system coupling MM5 and CMAQ models with a recently developed anthropogenic emission inventory for the region. Two sets of base runs were performed in order to investigate for the first time the impact of biogenic emissions on ozone concentrations in the Greater Istanbul Area (GIA). The first simulation was performed using only the anthropogenic emissions whereas the second simulation was performed using both anthropogenic and biogenic emissions. Biogenic NMVOC emissions were comparable with anthropogenic NMVOC emissions in terms of magnitude. The inclusion of biogenic emissions significantly improved the performance of the model, particularly in reproducing the low night time values as well as the temporal variation of ozone concentrations. Terpene emissions contributed significantly to the destruction of the ozone during nighttime. Biogenic NMVOCs emissions enhanced ozone concentrations in the downwind regions of GIA up to 25ppb. The VOC/NO(x) ratio almost doubled due to the addition of biogenic NMVOCs. Anthropogenic NO(x) and NMVOCs were perturbed by ±30% in another set of simulations to quantify the sensitivity of ozone concentrations to the precursor emissions in the region. The sensitivity runs, as along with the model-calculated ozone-to-reactive nitrogen ratios, pointed NO(x)-sensitive chemistry, particularly in the downwind areas. On the other hand, urban parts of the city responded more to changes in NO(x) due to very high anthropogenic emissions. Copyright © 2010 Elsevier B.V. All rights reserved.

  15. H + O3 Fourier-transform infrared emission and laser absorption studies of OH(X2Pi) radical - An experimental dipole moment function and state-to-state Einstein A coefficients

    Science.gov (United States)

    Nelson, David D., Jr.; Schiffman, Aram; Nesbitt, David J.; Orlando, John J.; Burkholder, James B.

    1990-01-01

    FTIR emission/absorption spectroscopy is used to measure the relative intensities of 88 pairs of rovibrational transitions of OH(X2Pi) distributed over 16 vibrational bands. The experimental technique used to obtain the Einstein A ratios is discussed. The dipole moment function which follows from the intensity ratios along with Einstein A coefficients calculated from mu(r) is presented.

  16. Sound conversion phenomena at the free surface of liquid helium. I. Calculation of the coefficients of reflection, transmission, and transformation of sound waves incident on the liquid--vapor interface of helium

    International Nuclear Information System (INIS)

    Wiechert, H.; Buchholz, F.I.

    1980-01-01

    On the basis of a set of boundary conditions describing quite generally mass and energy transport processes across the free surface of helium II, the acoustic coefficients of reflection, transmission, and transformation of first sound, second sound, and the sound wave propagating in the vapor are calculated in the case of perpendicular incidence of sound waves against the liquid--vapor phase boundary. Considering rigoroulsy the influences of the Onsager surface coefficients, the isobaric thermal expansion coefficients, and the thermal conductivities of the liquid and the vapor, we derive sets of equations from which the acoustic coefficients are determined numerically. For estimations, simple explicit formulas of the acoustic coefficients are given. It is shown that the evaporation and energy transport processes occurring at the free surface of helium II due to the incidence of sound waves may be connected with appreciable energy dissipation. The surface absorption coefficients of first, second, and gas sound waves are deduced

  17. Land Surface Microwave Emissivities Derived from AMSR-E and MODIS Measurements with Advanced Quality Control

    Science.gov (United States)

    Moncet, Jean-Luc; Liang, Pan; Galantowicz, John F.; Lipton, Alan E.; Uymin, Gennady; Prigent, Catherine; Grassotti, Christopher

    2011-01-01

    A microwave emissivity database has been developed with data from the Advanced Microwave Scanning Radiometer-EOS (AMSR-E) and with ancillary land surface temperature (LST) data from the Moderate Resolution Imaging Spectroradiometer (MODIS) on the same Aqua spacecraft. The primary intended application of the database is to provide surface emissivity constraints in atmospheric and surface property retrieval or assimilation. An additional application is to serve as a dynamic indicator of land surface properties relevant to climate change monitoring. The precision of the emissivity data is estimated to be significantly better than in prior databases from other sensors due to the precise collocation with high-quality MODIS LST data and due to the quality control features of our data analysis system. The accuracy of the emissivities in deserts and semi-arid regions is enhanced by applying, in those regions, a version of the emissivity retrieval algorithm that accounts for the penetration of microwave radiation through dry soil with diurnally varying vertical temperature gradients. These results suggest that this penetration effect is more widespread and more significant to interpretation of passive microwave measurements than had been previously established. Emissivity coverage in areas where persistent cloudiness interferes with the availability of MODIS LST data is achieved using a classification-based method to spread emissivity data from less-cloudy areas that have similar microwave surface properties. Evaluations and analyses of the emissivity products over homogeneous snow-free areas are presented, including application to retrieval of soil temperature profiles. Spatial inhomogeneities are the largest in the vicinity of large water bodies due to the large water/land emissivity contrast and give rise to large apparent temporal variability in the retrieved emissivities when satellite footprint locations vary over time. This issue will be dealt with in the future by

  18. Acoustic emission-based in-process monitoring of surface generation in robot-assisted polishing

    DEFF Research Database (Denmark)

    Pilny, Lukas; Bissacco, Giuliano; De Chiffre, Leonardo

    2016-01-01

    The applicability of acoustic emission (AE) measurements for in-process monitoring of surface generation in the robot-assisted polishing (RAP) was investigated. Surface roughness measurements require interruption of the process, proper surface cleaning and measurements that sometimes necessitate......-process determination of the process endpoint. This makes it possible to reliably determine the right time for changing the polishing media to finer abrasive when applying a given set of parameters is no longer effective to create a smoother surface, thus improving the efficiency of the process. The findings enabling...

  19. The Complete Solution of Fick's Second Law of Diffusion with Time-dependent Diffusion Coefficient and Surface Concentration

    DEFF Research Database (Denmark)

    Mejlbro, Leif

    1996-01-01

    Fick's Second Law of Diffusion with time-dependent diffusioncoefficient and surface concentration is solved. Mimicking the classicalsolution, special time-dependent surface concentration functions areconsidered. These models are used in giving estimates of the lifetimeof the structure, when the c...... the concrete cover is given, as well as estimatesof the thickness of the concrete cover, when the expected lifetime is given.*Note: Book tilte: Durability of Concrete in Saline Environment...

  20. Surface excess elasticity of gold: Ab initio coefficients and impact on the effective elastic response of nanowires

    International Nuclear Information System (INIS)

    Elsner, B.A.M.; Müller, S.; Bargmann, S.; Weissmüller, J.

    2017-01-01

    Predicting the influence of the surface on the effective elastic properties of nanoscale structures and nanomaterials remains a challenge, which we here address on both levels, continuum and atomic. Density Functional Theory (DFT) computation at the atomic level yields the first reliable surface excess elastic parameters for the (111) and (001) surfaces of gold. At the continuum level, we derive closed-form expressions for the effective elastic behavior that can be combined with the DFT-derived excess elastic parameters to obtain the effective axial, torsion, and bending stiffness of circular nanowires with surface excess elasticity. The two approaches use different reference frames, and we emphasize the need for consistent stress definitions and for conversion between the separate stress measures when transferring results between the approaches. We present excess elastic parameters separately for Cauchy and 2 nd Piola-Kirchhoff stresses, demonstrating that the conversion substantially modifies their numerical value and may even invert their sign. The results afford an assessment of the contribution of the surface excess elastic parameters to the effective elastic response of nanoscale beams or wires. This assessment sheds doubt on earlier suggestions relating experimental observations of an effective stiffening or softening at small size to the excess elasticity of clean surfaces.

  1. Multi-Staged NDVI Dependent Snow-Free Land-Surface Shortwave Albedo Narrowband-to-Broadband (NTB Coefficients and Their Sensitivity Analysis

    Directory of Open Access Journals (Sweden)

    Shi Peng

    2017-01-01

    Full Text Available Narrowband-to-broadband conversion is a critical procedure for mapping land-surface broadband albedo using multi-spectral narrowband remote-sensing observations. Due to the significant difference in optical characteristics between soil and vegetation, NTB conversion is influenced by the variation in vegetation coverage on different surface types. To reduce this influence, this paper applies an approach that couples NTB coefficient with the NDVI. Multi-staged NDVI dependent NTB coefficient look-up tables (LUT for Moderate Resolution Imaging Spectroradiometer (MODIS, Polarization and Directionality of Earth’s Reflectance (POLDER and Advanced Very High Resolution Radiometer (AVHRR were calculated using 6000 spectra samples collected from two typical spectral databases. Sensitivity analysis shows that NTB conversion is affected more by the NDVI for sensors with fewer band numbers, such as POLDER and AVHRR. Analysis of the validation results based on simulations, in situ measurements and global albedo products indicates that by using the multi-staged NDVI dependent NTB method, the conversion accuracies of these two sensors could be improved by 2%–13% on different NDVI classes compared with the general method. This improvement could be as high as 15%, on average, and 35% on dense vegetative surface compared with the global broadband albedo product of POLDER. This paper shows that it is necessary to consider surface reflectance characteristics associated with the NDVI on albedo-NTB conversion for remote sensors with fewer than five bands.

  2. Investigation of the electron emission properties of silver: From exposed to ambient atmosphere Ag surface to ion-cleaned Ag surface

    Energy Technology Data Exchange (ETDEWEB)

    Gineste, T., E-mail: Thomas.Gineste@onera.fr [ONERA The French Aerospace Lab, 31055 Toulouse (France); Belhaj, M. [ONERA The French Aerospace Lab, 31055 Toulouse (France); Teyssedre, G. [LAPLACE - Laboratoire Plasma et Conversion d’Energie -UMR 5213, Université Paul Sabatier - 118, route de Narbonne, 31062 Toulouse Cedex (France); Puech, J. [CNES, 18 Avenue Edouard Belin 31055 Toulouse Cédex 9 (France)

    2015-12-30

    Highlights: • We investigated the electron emission yield of an air exposed Ag to a cleaned Ag. • Air exposed Ag sample was cleaned by ion Ar etching. • Surface composition was determined by AES. • Electron emission yield was related to surface composition evolution. • Natural contamination hugely influence electron properties of Ag sample. - Abstract: Electron emission properties of materials are highly dependent to the surface and the first nanometres subsurface. Technical materials, i.e. used within applications are ordinarily exposed to atmosphere, which interacts with the surface. The contamination layer building up at the surface of materials and/or oxidation layer affects dramatically the electron emission proprieties. In this paper, starting from 99.99% pure silver sample, exposed 4 years to ambient atmosphere, we monitored the variations of the electron emission properties and the surface composition during step by step ion etching procedure.

  3. Nanometer-scale discernment of field emission from tungsten surface with single carbon monoxide molecule

    Science.gov (United States)

    Matsunaga, Soichiro; Suwa, Yuji; Katagiri, Souichi

    2017-12-01

    Unusual quantized beam fluctuations were found in the emission current from a cold-field emitter (CFE) operating in an extremely high vacuum of 10-10 Pa. To clarify the microscopic mechanism behind these fluctuations, we developed a new calculation method to evaluate the field emission from a heterogeneous surface under a strong electric field of 4 × 109 V/m by using the local potential distribution obtained by a first-principles calculation, instead of by using the work function. As a result of the first-principles calculations of a single molecule adsorbed on a tungsten surface, we found that dissociative adsorption of a carbon monoxide (CO) molecule enhances the emission current by changing the potential barrier in the area surrounding the C and O adatoms when these two atoms are placed at their most stable positions. It is also found that the migration of the O atom from the most stable position reduces the emission current. These types of enhancement and reduction of the emission current quantitatively explain the observed quantized fluctuations of the CFE emission current.

  4. Influence of texture coefficient on surface morphology and sensing properties of W-doped nanocrystalline tin oxide thin films.

    Science.gov (United States)

    Kumar, Manjeet; Kumar, Akshay; Abhyankar, A C

    2015-02-18

    For the first time, a new facile approach based on simple and inexpensive chemical spray pyrolysis (CSP) technique is used to deposit Tungsten (W) doped nanocrystalline SnO2 thin films. The textural, optical, structural and sensing properties are investigated by GAXRD, UV spectroscopy, FESEM, AFM, and home-built sensing setup. The gas sensing results indicate that, as compared to pure SnO2, 1 wt % W-doping improves sensitivity along with better response (roughness values of 3.82 eV and 3.01 nm, respectively. Reduction in texture coefficient along highly dense (110) planes with concomitant increase along loosely packed (200) planes is found to have prominent effect on gas sensing properties of W-doped films.

  5. Spreadsheet program for estimating recovery coefficient to get partial volume corrected standardized uptake value in clinical positron emission tomography-computed tomography studies

    International Nuclear Information System (INIS)

    Pandey, Anil Kumar; Sharma, Punit; Pandey, Manjesh; Aswathi, KK; Malhotra, Arun; Kumar, Rakesh

    2012-01-01

    To develop a spreadsheet program for estimation of recovery coefficient (RC) to get partial volume corrected (PVC) standardized uptake value (SUV) in clinical positron emission tomography-computed tomography (PET-CT) studies. For formulation of this program we used data from a phantom study conducted at our center in which a phantom with a sphere assembly (seven spheres-different diameters) was filled with 18F-Fluorodeoxyglucose solution to get a sphere/background ratio of 8:1, 10:1 and 12:1. PET-CT images were acquired. RC was then calculated from processed PET-CT images. We plotted graph of RC versus lesion-size at different sphere/background ratio using MS Excel function. There was logarithmic increase in RC with increase in lesion size. We fitted the data with a logarithmic equation and found optimum fit (least-square fit). We then validated this program with clinical data using 42 lung nodules in five patients. The program estimates the value of RC and object to background ratio in PET-CT for the input lesion-size and displays graph with trendline. When the user enters SUV and background activity measured in clinical PET-CT, it provides the value of RC and PVC SUV. It also validates the data entry and displays appropriate message. It is consistent, reproducible, accurate and provides output for wide range of lesion-sizes (71% of lesions evaluated); however, program does not give output for lesion-size < 9 mm. The present spreadsheet program is a useful and easy tool for calculating PVC SUV of clinical PET-CT lesions

  6. Enhanced quantum efficiency of photoelectron emission, through surface textured metal electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Alexander, Anna; Bandaru, Prabhakar R., E-mail: pbandaru@ucsd.edu [Program in Materials Science, Department of Mechanical Engineering, University of California, San Diego, La Jolla, California, 92130 (United States); Moody, Nathan A. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

    2016-03-15

    It is predicted that the quantum efficiency (QE) of photoelectron emission from metals may be enhanced, possibly by an order of magnitude, through optimized surface texture. Through extensive computational simulations, it is shown that the absorption enhancement in select surface groove geometries may be a dominant contributor to enhanced QE and corresponds to localized Fabry–Perot resonances. The inadequacy of extant analytical models in predicting the QE increase, and suggestions for further improvement, are discussed.

  7. Modification of spontaneous emission from nanodiamond colour centres on a structured surface

    International Nuclear Information System (INIS)

    Inam, F A; Gaebel, T; Bradac, C; Withford, M J; Rabeau, J R; Steel, M J; Stewart, L; Dawes, J M

    2011-01-01

    Colour centres in diamond are promising candidates as a platform for quantum technologies and biomedical imaging based on spins and/or photons. Controlling the emission properties of colour centres in diamond is a key requirement for the development of efficient single-photon sources having high collection efficiency. A number of groups have achieved an enhancement in the emission rate over narrow wavelength ranges by coupling single emitters in nanodiamond crystals to resonant electromagnetic structures. In this paper, we characterize in detail the spontaneous emission rates of nitrogen-vacancy centres at various locations on a structured substrate. We found a factor of 1.5 average enhancement of the total emission rate when nanodiamonds are on an opal photonic crystal surface, and observed changes in the lifetime distribution. We present a model for explaining these observations and associate the lifetime properties with dipole orientation and polarization effects.

  8. Modification of spontaneous emission from nanodiamond colour centres on a structured surface

    Energy Technology Data Exchange (ETDEWEB)

    Inam, F A; Gaebel, T; Bradac, C; Withford, M J; Rabeau, J R; Steel, M J [Centre for Quantum Science and Technology, Department of Physics and Astronomy, Macquarie University, Sydney, NSW 2109 (Australia); Stewart, L; Dawes, J M, E-mail: james.rabeau@mq.edu.au, E-mail: michael.steel@mq.edu.au [MQ Photonics Research Centre, Department of Physics and Astronomy, Macquarie University, Sydney, NSW 2109 (Australia)

    2011-07-15

    Colour centres in diamond are promising candidates as a platform for quantum technologies and biomedical imaging based on spins and/or photons. Controlling the emission properties of colour centres in diamond is a key requirement for the development of efficient single-photon sources having high collection efficiency. A number of groups have achieved an enhancement in the emission rate over narrow wavelength ranges by coupling single emitters in nanodiamond crystals to resonant electromagnetic structures. In this paper, we characterize in detail the spontaneous emission rates of nitrogen-vacancy centres at various locations on a structured substrate. We found a factor of 1.5 average enhancement of the total emission rate when nanodiamonds are on an opal photonic crystal surface, and observed changes in the lifetime distribution. We present a model for explaining these observations and associate the lifetime properties with dipole orientation and polarization effects.

  9. Measurement of surface temperature and emissivity by a multitemperature method for Fourier-transform infrared spectrometers

    DEFF Research Database (Denmark)

    Clausen, Sønnik; Morgenstjerne, Axel; Rathmann, Ole

    1996-01-01

    measurement at a known sample temperature, for example, at ambient temperature. The temperature of the sample surface can be measured rather easily at ambient temperature. The spectrum at ambient temperature is used to eliminate background effects from spectra as measured at other surface temperatures....... The temperatures of the sample are found in a single calculation from the measured spectra independently of the response function of the instrument and the emissivity of the sample. The spectral emissivity of a sample can be measured if the instrument is calibrated against a blackbody source. Temperatures...... of blackbody sources are estimated with an uncertainty of 0.2-2 K. The method is demonstrated for measuring the spectral emissivity of a brass specimen and an oxidized nickel specimen. (C) 1996 Optical Society of America...

  10. Hotspot detection and spatial distribution of methane emissions from landfills by a surface probe method.

    Science.gov (United States)

    Gonzalez-Valencia, Rodrigo; Magana-Rodriguez, Felipe; Cristóbal, Jordi; Thalasso, Frederic

    2016-09-01

    A surface probe method previously developed was used to detect hotspots and to determine spatial variation of methane (CH4) emissions from three landfills located in Mexico, with an intermediate or a final cover, as well as with or without a landfill gas collection system. The method was effective in the three landfills and allowed mapping of CH4 emissions with a resolution of 24-64 measurements per hectare, as well as the detection and quantification of hotspots, with a moderate experimental effort. In the three selected landfills, CH4 emissions were quantified to 10, 72, and 575gm(-2)d(-1). Two straightforward parameters describing the spatial distribution of CH4 emissions were also developed. The first parameter provides the percentage of area responsible for a given percentage of total emissions, while the second parameter assigns a numerical value to flux homogeneity. Together, the emissions map and the spatial distribution parameters offer an appropriate tool to landfill operators willing to begin recovering CH4 emissions or to improve the effectiveness of an existing recovery system. This method may therefore help to reduce the greenhouse gas footprint of landfills, which are still the primary option for waste management in developing countries. Copyright © 2016 Elsevier Ltd. All rights reserved.

  11. Dust Emissions from Undisturbed and Disturbed, Crusted Playa Surfaces: Cattle Trampling Effect

    Science.gov (United States)

    Dry playa lake beds can be a significant source of fine dust emissions during high wind events in arid and semiarid landscapes. The physical and chemical properties of the playa surface control the amount and properties of the dust emitted. In this study, we use a field wind tunnel to quantify the...

  12. Stimulated emission of surface plasmons by electron tunneling in metal-barrier-metal structures

    Science.gov (United States)

    Siu, D. P.; Gustafson, T. K.

    1978-01-01

    It is shown that correlation currents arising from the superposition of pairs of states on distinct sides of a potential barrier in metal-barrier-metal structures can result in inelastic tunneling through the emission of surface plasmons. Net gain of an externally excited plasmon field is possible.

  13. Comparing optimized CO emission estimates using MOPITT or NOAA surface network observations

    NARCIS (Netherlands)

    Hooghiemstra, P.B.; Krol, M.C.; Bergamaschi, P.; Laat, de A.T.J.; Werf, van der G.R.; Novelli, P.C.; Deeter, M.N.; Aben, I.; Rockmann, T.

    2012-01-01

    This paper compares two global inversions to estimate carbon monoxide (CO) emissions for 2004. Either surface flask observations from the National Oceanic and Atmospheric Administration Earth System Research Laboratory (NOAA/ESRL) Global Monitoring Division (GMD) or CO total columns from the

  14. Electron emission induced by resonant coherent interaction in ion-surface scattering at grazing incidence

    International Nuclear Information System (INIS)

    Garcia de Abajo, F.J.; Ponce, V.H.; Echenique, P.M.

    1994-01-01

    The resonant coherent interaction of an ion with an oriented crystal surface, under grazing-incidence conditions with respect to a special direction of the crystal, gives rise to electron loss to the continuum from electronic bound states of the ion. The calculations presented below predict large probabilities for electron emission due to this mechanism. The electrons are emitted with well defined energies, expressed in terms of the condition of resonance. Furthermore, the emission takes place around certain preferential directions, which are determined by both the latter condition and the symmetry of the surface lattice. Our calculations for MeV He + ions scattered at a W(001) surface along the left-angle 100 right-angle direction with glancing angle of 0--2 mrad indicate a yield of emission close to 1. Using heavier projectiles, one obtains smaller yields, but still large enough to be measurable in some cases (e.g., ∼0.9 for 53 MeV B 4+ and an angle of incidence of 1 mrad). Besides, the initial bound state is energy shifted due to the interaction with both the crystal potential and the velocity-dependent image potential. This results in a slight shift of the peaks of emission, which suggests a possible spectroscopy for analyzing the dynamical interaction of electronic bound states with solid surfaces

  15. Greenhouse gas emissions from beef feedlot surface materials as affected by diet, moisture, temperature, and time

    Science.gov (United States)

    A laboratory study was conducted to measure the effects of diet, moisture, temperature, and time on greenhouse gas (GHG) emissions from feedlot surface materials (FSM). The FSM were collected from open lot, pens where beef cattle were fed either a dry-rolled corn (DRC) diet containing no wet distil...

  16. Gases Emission From Surface Layers of Sand Moulds and Cores Stored Under the Humid Air Conditions

    Directory of Open Access Journals (Sweden)

    Kaźnica N.

    2017-12-01

    Full Text Available A large number of defects of castings made in sand moulds is caused by gases. There are several sources of gases: gases emitted from moulds, cores or protective coatings during pouring and casting solidification; water in moulding sands; moisture adsorbed from surroundings due to atmospheric conditions changes. In investigations of gas volumetric emissions of moulding sands amounts of gases emitted from moulding sand were determined - up to now - in dependence of the applied binders, sand grains, protective coatings or alloys used for moulds pouring. The results of investigating gas volumetric emissions of thin-walled sand cores poured with liquid metal are presented in the hereby paper. They correspond to the surface layer in the mould work part, which is decisive for the surface quality of the obtained castings. In addition, cores were stored under conditions of a high air humidity, where due to large differences in humidity, the moisture - from surroundings - was adsorbed into the surface layer of the sand mould. Due to that, it was possible to asses the influence of the adsorbed moisture on the gas volumetric emission from moulds and cores surface layers by means of the new method of investigating the gas emission kinetics from thin moulding sand layers heated by liquid metal. The results of investigations of kinetics of the gas emission from moulding sands with furan and alkyd resins as well as with hydrated sodium silicate (water glass are presented. Kinetics of gases emissions from these kinds of moulding sands poured with Al-Si alloy were compared.

  17. MODIS/Aqua Land Surface Temperature/3-Band Emissivity Daily L3 Global 1km SIN Grid Day V006

    Data.gov (United States)

    National Aeronautics and Space Administration — MODIS/Aqua Land Surface Temperature/3-Band Emissivity Daily L3 Global 1km SIN Grid Day (MYD21A1D.006). A new suite of MODIS Land Surface Temperature (LST) and...

  18. MODIS/Terra Land Surface Temperature/3-Band Emissivity Daily L3 Global 1km SIN Grid Night V006

    Data.gov (United States)

    National Aeronautics and Space Administration — MODIS/Terra Land Surface Temperature/3-Band Emissivity Daily L3 Global 1km SIN Grid Night (MOD21A1N.006). A new suite of MODIS Land Surface Temperature (LST) and...

  19. MODIS/Aqua Land Surface Temperature/3-Band Emissivity Daily L3 Global 1km SIN Grid Night V006

    Data.gov (United States)

    National Aeronautics and Space Administration — MODIS/Aqua Land Surface Temperature/3-Band Emissivity Daily L3 Global 1km SIN Grid Night (MYD21A1N.006). A new suite of MODIS Land Surface Temperature (LST) and...

  20. MODIS/Terra Land Surface Temperature/3-Band Emissivity Daily L3 Global 1km SIN Grid Day V006

    Data.gov (United States)

    National Aeronautics and Space Administration — MODIS/Terra Land Surface Temperature/3-Band Emissivity Daily L3 Global 1km SIN Grid Day (MOD21A1D.006). A new suite of MODIS Land Surface Temperature (LST) and...

  1. Influence on rod-pinch diode performance of suppressing electron emission from different cathode surfaces

    International Nuclear Information System (INIS)

    Gao Yi; Lv Min; Qiu Aici; Yang Hailiang; Liang Tianxue; Zhang Zhong

    2010-01-01

    The electron pinching process of a rod-pinch diode is simulated with UNIPIC. It indicates that the pinching characteristics of the electrons emitted from different cathode surfaces differ significantly. The electrons emitted from the downstream surface pinch worst, with large amount of electrons hitting upstream of the rod, which increases the axial bremsstrahlung X-ray spot size. The simulation results show that suppressing electron emission from the downstream surface will reduce the axial X-ray spot size and improve the pinching quality. Composite cathodes are designed to investigate the influence of suppressing electron emission from the upstream or downstream surface. Experiments are performed on the new-built IVA (Inductive Voltage Adder) device at the peak voltage of ∼1.5 MV, and the peak current of ∼44 kA. It is shown that the composite cathode is effective in suppressing electron emission from the specific surface, the axial X-ray spot size in the case of downstream suppression is about 14.5% less than the case of upstream suppression and in both cases, the axis-on X-ray dose at 1 meter from the rod tip is ∼1.9rads, validating the simulation results. (authors)

  2. X-ray emission in slow highly charged ion-surface collisions

    International Nuclear Information System (INIS)

    Watanabe, H; Abe, T; Fujita, Y; Sun, J; Takahashi, S; Tona, M; Yoshiyasu, N; Nakamura, N; Sakurai, M; Yamada, C; Ohtani, S

    2007-01-01

    X-rays emitted in the collisions of highly charged ions with a surface have been measured to investigate dissipation schemes of their potential energies. While 8.1% of the potential energy was dissipated in the collisions of He-like I ions with a W surface, 29.1% has been dissipated in the case of He-like Bi ions. The x-ray emissions play significant roles in the dissipation of the potential energies in the interaction of highly charged heavy ions with the surface

  3. Hydrothermal alteration of sediments associated with surface emissions from the Cerro Prieto geothermal field

    Energy Technology Data Exchange (ETDEWEB)

    Valette-Silver, J.N.; Esquer P., I.; Elders, W.A.; Collier, P.C.; Hoagland, J.R.

    1981-01-01

    A study of the mineralogical changes associated with these hydrothermal vents was initiated with the aim of developing possible exploration tools for geothermal resources. The Cerro Prieto reservoir has already been explored by extensive deep drilling so that relationships between surface manifestations and deeper hydrothermal processes could be established directly. Approximately 120 samples of surface sediments were collected both inside and outside of the vents. The mineralogy of the altered sediments studied appears to be controlled by the type of emission. A comparison between the changes in mineralogy due to low temperature hydrothermal activity in the reservoir, seen in samples from boreholes, and mineralogical changes in the surface emission samples shows similar general trends below 180 C: increase of quartz, feldspar and illite, with subsequent disappearance of kaolinite, montmorillonite, calcite and dolomite. These mineral assemblages seem to be characteristic products of the discharge from high intensity geothermal fields.

  4. Modelling CO2 emissions from water surface of a boreal hydroelectric reservoir.

    Science.gov (United States)

    Wang, Weifeng; Roulet, Nigel T; Kim, Youngil; Strachan, Ian B; Del Giorgio, Paul; Prairie, Yves T; Tremblay, Alain

    2018-01-15

    To quantify CO 2 emissions from water surface of a reservoir that was shaped by flooding the boreal landscape, we developed a daily time-step reservoir biogeochemistry model. We calibrated the model using the measured concentrations of dissolved organic and inorganic carbon (C) in a young boreal hydroelectric reservoir, Eastmain-1 (EM-1), in northern Quebec, Canada. We validated the model against observed CO 2 fluxes from an eddy covariance tower in the middle of EM-1. The model predicted the variability of CO 2 emissions reasonably well compared to the observations (root mean square error: 0.4-1.3gCm -2 day -1 , revised Willmott index: 0.16-0.55). In particular, we demonstrated that the annual reservoir surface effluxes were initially high, steeply declined in the first three years, and then steadily decreased to ~115gCm -2 yr -1 with increasing reservoir age over the estimated "engineering" reservoir lifetime (i.e., 100years). Sensitivity analyses revealed that increasing air temperature stimulated CO 2 emissions by enhancing CO 2 production in the water column and sediment, and extending the duration of open water period over which emissions occur. Increasing the amount of terrestrial organic C flooded can enhance benthic CO 2 fluxes and CO 2 emissions from the reservoir water surface, but the effects were not significant over the simulation period. The model is useful for the understanding of the mechanism of C dynamics in reservoirs and could be used to assist the hydro-power industry and others interested in the role of boreal hydroelectric reservoirs as sources of greenhouse gas emissions. Copyright © 2017 Elsevier B.V. All rights reserved.

  5. Surface plasmon-coupled emission from shaped PMMA films doped with fluorescence molecules.

    Science.gov (United States)

    Zhang, D G; Moh, K J; Yuan, X-C

    2010-06-07

    Surface plasmon-coupled emission from shaped PMMA films doped with randomly oriented fluorescence molecules was investigated. Experimental results show that for different shapes, such as triangle or circular structures, the SPCE ring displays different intensity patterns. For a given shape, it was observed that the relative position and polarization of an incident laser spot on the shaped PMMA can be used to adjust the fluorescence intensity distribution of the SPCE ring. The proposed method enables controlling the fluorescence emission in azimuthal direction in addition to the radial angle controlled by common SPCE, which will further enhances the fluorescence collection efficiency and has applications in fluorescence sensing, imaging and so on.

  6. Enhanced biogenic emissions of nitric oxide and nitrous oxide following surface biomass burning

    Science.gov (United States)

    Anderson, Iris C.; Levine, Joel S.; Poth, Mark A.; Riggan, Philip J.

    1988-01-01

    Recent measurements indicate significantly enhanced biogenic soil emissions of both nitric oxide (NO) and nitrous oxide (N2O) following surface burning. These enhanced fluxes persisted for at least six months following the burn. Simultaneous measurements indicate enhanced levels of exchangeable ammonium in the soil following the burn. Biomass burning is known to be an instantaneous source of NO and N2O resulting from high-temperature combustion. Now it is found that biomass burning also results in significantly enhanced biogenic emissions of these gases, which persist for months following the burn.

  7. MODIS/Aqua Land Surface Temperature/3-Band Emissivity 8-Day L3 Global 1km SIN Grid V006

    Data.gov (United States)

    National Aeronautics and Space Administration — MODIS/Aqua Land Surface Temperature/3-Band Emissivity 8-Day L3 Global 1km SIN Grid (MYD21A2.006). A new suite of MODIS Land Surface Temperature (LST) and Emissivity...

  8. MODIS/Terra Land Surface Temperature/3-Band Emissivity 8-Day L3 Global 1km SIN Grid V006

    Data.gov (United States)

    National Aeronautics and Space Administration — MODIS/Terra Land Surface Temperature/3-Band Emissivity 8-Day L3 Global 1km SIN Grid (MOD21A2.006). A new suite of MODIS Land Surface Temperature (LST) and Emissivity...

  9. Simulation of torrential rain as a means for assessment of surface runoff coefficients and calculation of recurrent design events in alpine catchments

    Science.gov (United States)

    Markart, Gerhard; Kohl, Bernhard; Sotier, Bernadette; Klebinder, Klaus; Schauer, Thomas; Bunza, Günther

    2010-05-01

    Simulation of heavy rain is an established method for studying infiltration characteristics, runoff and erosion behaviour in alpine catchments. Accordingly for characterization and differentiation of various runoff producing areas in alpine catchments transportable spray irrigation installations for large plots have been developed at the BFW, Department of Natural Hazards and Alpine Timberline, in Innsbruck, Austria. One installation has been designed for assessment of surface runoff coefficients under convective torrential rain with applicable precipitation intensities between 30 and 120 mm*h-1 and a plot size between 50 and 100 m2. The second device is used for simulation of persistent rain events (rain intensity about 10 mm*h-1, plot size: 400-1200 m2). Very reasonable results have been achieved during the comparison with spray irrigations from other institutions (e.g. Bavarian Environmental Agency in Munich) in the field. Rain simulations at BFW are mostly combined with comprehensive additional investigations on land-use, vegetation cover, soil physical characteristics, soil humidity, hydrogeology and other features of the test-sites. This allows proper interpretation of the achieved runoff data. At the moment results from more than 280 rain simulations are available from about 25 catchments / regions of the Eastern Alps at the BFW. Results show that the surface runoff coefficient, when runoff is constant at the test site (φconst) increases only slightly between rain intensities from 30 to 120 mm*h-1 (increment is 6%). Therefore φconst shall be used for assessment of runoff behaviour of runoff contributing areas, because it is less dependent form system conditions than φtot. BFW-data have been consolidated with results of the LfU (Bavarian Environmental Agency in Munich) in a data base and formed the basis for the development of a simple code of practice for assessment of surface runoff coefficients in torrential rain. The manual is freely available under

  10. Low-energy electron scattering at surfaces using STM tips as a field emission gun

    International Nuclear Information System (INIS)

    Mizuno, S.; Iwanaga, M.; Tochihara, H.

    2004-01-01

    Full text: The field emission from scanning tunnelling microscopy (STM) tips has the potential to probe small surface areas with electron beams. Several groups have demonstrated their capabilities. Intensity mapping of the secondary electrons and projection of the transmitted electrons have been shown to have high lateral resolution. Spin-polarized secondary electron microscopy, energy loss spectroscopy and scanning Auger electron microscopy have been also reported. We examined low-energy electron scattering at surfaces. Our final target is a development of a low-energy electron diffraction (LEED) technique using field emission from STM tips to determine structures of surface small regions. Our apparatus was designed based on a commercial STM system (UNISOKU USM-1100). The STM part was suspended by four springs to remove vibrations. The sample holder was mounted on a tube-type piezo scanner, while the tip was fixed rigidly on the holder. The bias voltages were applied to the sample up to +100 V. The tunnel current and the emission current were monitored on the tip. The emission current was fixed at 0.1 nA in the field emission mode. The apparatus was designed to detect backscattered electrons toward surface normal direction. The scattered electrons were guided by the electric field of the tip shield and an extractor, passed through a three-grid electron energy filter, and detected by a microchannel plate equipped with a phosphor screen. Tips were made of tungsten single crystal wire with a diameter of 0.25 mm. They have orientation of direction, and were sharpened by electrochemical etching with a NaOH solution of 2 N. The tips were welded on a tantalum wire for annealing in a preparation chamber. Field emission patterns and field ion microscopy images of them were obtained before and after experiments. The sensitivity and stability of the apparatus were sufficient to observe scattering patterns on the screen. We measured the kinetic energies of the scattered

  11. Comparison of distributed vortex receptivity coefficients at excitation of 3D TS-waves in presence and absence of surface waviness and pressure gradient

    Science.gov (United States)

    Borodulin, V. I.; Ivanov, A. V.; Kachanov, Y. S.; Mischenko, D. A.; Fedenkova, A. A.

    2016-10-01

    The paper is devoted to quantitative experimental investigation of effective mechanisms of excitation of 3D TS instability waves due to distributed boundary layer receptivity to free-stream vortices. Experiments carried out in a self-similar boundary layer with Hartree parameter βH = -0.115 and concentrated on studying two receptivity mechanisms connected with distributed scattering of 3D unsteady free-stream vortices both on the natural boundary layer nonuniformity (smooth surface) and on 2D surface nonuniformity (waviness). Obtained quantitative characteristics (distributed receptivity coefficients) are compared directly with those obtained in Blasius boundary layer. It is found that the adverse pressure gradient leads to reduction of efficiency of the vortex-roughness receptivity mechanism.

  12. Force Field Benchmark of the TraPPE_UA for Polar Liquids: Density, Heat of Vaporization, Dielectric Constant, Surface Tension, Volumetric Expansion Coefficient, and Isothermal Compressibility.

    Science.gov (United States)

    Núñez-Rojas, Edgar; Aguilar-Pineda, Jorge Alberto; Pérez de la Luz, Alexander; de Jesús González, Edith Nadir; Alejandre, José

    2018-02-08

    The transferable potential for a phase equilibria force field in its united-atom version, TraPPE_UA, is evaluated for 41 polar liquids that include alcohols, thiols, ethers, sulfides, aldehydes, ketones, and esters to determine its ability to reproduce experimental properties that were not included in the parametrization procedure. The intermolecular force field parameters for pure components were fit to reproduce experimental boiling temperature, vapor-liquid coexisting densities, and critical point (temperature, density, and pressure) using Monte Carlo simulations in different ensembles. The properties calculated in this work are liquid density, heat of vaporization, dielectric constant, surface tension, volumetric expansion coefficient, and isothermal compressibility. Molecular dynamics simulations were performed in the gas and liquid phases, and also at the liquid-vapor interface. We found that relative error between calculated and experimental data is 1.2% for density, 6% for heat of vaporization, and 6.2% for surface tension, in good agreement with the experimental data. The dielectric constant is systematically underestimated, and the relative error is 37%. Evaluating the performance of the force field to reproduce the volumetric expansion coefficient and isothermal compressibility requires more experimental data.

  13. Atmospheric Compensation and Surface Temperature and Emissivity Retrieval with LWIR Hyperspectral Imagery

    Science.gov (United States)

    Pieper, Michael

    Accurate estimation or retrieval of surface emissivity spectra from long-wave infrared (LWIR) or Thermal Infrared (TIR) hyperspectral imaging data acquired by airborne or space-borne sensors is necessary for many scientific and defense applications. The at-aperture radiance measured by the sensor is a function of the ground emissivity and temperature, modified by the atmosphere. Thus the emissivity retrieval process consists of two interwoven steps: atmospheric compensation (AC) to retrieve the ground radiance from the measured at-aperture radiance and temperature-emissivity separation (TES) to separate the temperature and emissivity from the ground radiance. In-scene AC (ISAC) algorithms use blackbody-like materials in the scene, which have a linear relationship between their ground radiances and at-aperture radiances determined by the atmospheric transmission and upwelling radiance. Using a clear reference channel to estimate the ground radiance, a linear fitting of the at-aperture radiance and estimated ground radiance is done to estimate the atmospheric parameters. TES algorithms for hyperspectral imaging data assume that the emissivity spectra for solids are smooth compared to the sharp features added by the atmosphere. The ground temperature and emissivity are found by finding the temperature that provides the smoothest emissivity estimate. In this thesis we develop models to investigate the sensitivity of AC and TES to the basic assumptions enabling their performance. ISAC assumes that there are perfect blackbody pixels in a scene and that there is a clear channel, which is never the case. The developed ISAC model explains how the quality of blackbody-like pixels affect the shape of atmospheric estimates and the clear channel assumption affects their magnitude. Emissivity spectra for solids usually have some roughness. The TES model identifies four sources of error: the smoothing error of the emissivity spectrum, the emissivity error from using the incorrect

  14. Toluene diisocyanate emission to air and migration to a surface from a flexible polyurethane foam.

    Science.gov (United States)

    Vangronsveld, Erik; Berckmans, Steven; Spence, Mark

    2013-06-01

    Flexible polyurethane foam (FPF) is produced from the reaction of toluene diisocyanate (TDI) and polyols. Because of the potential for respiratory sensitization following exposure to TDI, concerns have been raised about potential consumer exposure to TDI from residual 'free TDI' in FPF products. Limited and conflicting results exist in the literature concerning the presence of unreacted TDI remaining in FPF as determined by various solvent extraction and analysis techniques. Because residual TDI results are most often intended for application in assessment of potential human exposure to TDI from FPF products, testing techniques that more accurately simulated human contact with foam were designed. To represent inhalation exposure to TDI from polyurethane foam, a test that measured the emission of TDI to air was conducted. For simulation of human dermal exposure to TDI from polyurethane foam, a migration test technique was designed. Emission of TDI to air was determined for a representative FPF using three different emission test cells. Two were commercially available cells that employ air flow over the surface of the foam [the Field and Laboratory Emission Cell (FLEC®) and the Micro-Chamber/Thermal Extraction™ cell]. The third emission test cell was of a custom design and features air flow through the foam sample rather than over the foam surface. Emitted TDI in the air of the test cells was trapped using glass fiber filters coated with 1-(2-methoxyphenyl)-piperazine (MP), a commonly used derivatizing agent for diisocyanates. The filters were subsequently desorbed and analyzed by liquid chromatography/mass spectrometry. Measurement of TDI migration from representative foam was accomplished by placing glass fiber filters coated with MP on the outer surfaces of a foam disk and then compressing the filters against the disk using a clamping apparatus for periods of 8 and 24 h. The sample filters were subsequently desorbed and analyzed in the same manner as for the

  15. Experimental verification of directional liquid surface wave emission at band edge frequencies

    International Nuclear Information System (INIS)

    Wang, Zhenyu; Zhang, Pei; Zhang, Yongqiang; Nie, Xiaofei

    2013-01-01

    Directional liquid surface wave emission at band edge frequencies is an interesting physical phenomenon and has already been studied in theoretical research. There has been no experimental validation of it to date, however. This paper has as its subject the experimental investigation of the emission effect when a point source is placed inside a finite square array of rigid cylinders standing vertically in liquid. Both the wave patterns and spatial intensities are obtained by experiment and compared with simulated results calculated by using the finite element method. We can see from this comparison that the two results correspond closely both at lower and upper band edge frequency. Obvious directional wave emission along a desired direction is observed in the source structures, confirming previous theoretical predictions. In the future, this method could serve as a directional liquid wave source in applications used in hydraulic and ocean engineering for the concentration of wave energy

  16. Potential and Kinetic Electron Emissions from HOPG Surface Irradiated by Highly Charged Xenon and Neon Ions

    International Nuclear Information System (INIS)

    Yu-Yu, Wang; Yong-Tao, Zhao; Jian-Rong, Sun; De-Hui, Li; Jin-Yu, Li; Ping-Zhi, Wang; Guo-Qing, Xiao; Abdul, Qayyum

    2011-01-01

    Highly charged 129 Xe q+ (q = 10−30) and 40 Ne q+ (q = 4−8) ion-induced secondary electron emissions on the surface of highly oriented pyrolytic graphite (HOPG) are reported. The total secondary electron yield is measured as a function of the potential energy of incident ions. The experimental data are used to separate contributions of kinetic and potential electron yields. Our results show that about 4.5% and 13.2% of ion's potential energies are consumed in potential electron emission due to different Xe q+ -HOPG and Ne q+ -HOPG combinations. A simple formula is introduced to estimate the fraction of ion's potential energy for potential electron emission. (atomic and molecular physics)

  17. Transfer coefficient models for escherichia coli O157:H7 on contacts between beef tissue and high-density polyethylene surfaces.

    Science.gov (United States)

    Flores, Rolando A; Tamplin, Mark L; Marmer, Benne S; Phillips, John G; Cooke, Peter H

    2006-06-01

    Risk studies have identified cross-contamination during beef fabrication as a knowledge gap, particularly as to how and at what levels Escherichia coli O157:H7 transfers among meat and cutting board (or equipment) surfaces. The objectives of this study were to determine and model transfer coefficients (TCs) between E. coli O157:H7 on beef tissue and high-density polyethylene (HDPE) cutting board surfaces. Four different transfer scenarios were evaluated: (i) HDPE board to agar, (ii) beef tissue to agar, (iii) HDPE board to beef tissue to agar, and (iv) beef tissue to HDPE board to agar. Also, the following factors were studied for each transfer scenario: two HDPE surface roughness levels (rough and smooth), two beef tissues (fat and fascia), and two conditions of the initial beef tissue inoculation with E. coli O157:H7 (wet and dry surfaces), for a total of 24 treatments. The TCs were calculated as a function of the plated inoculum and of the cells recovered from the first contact. When the treatments were compared, all of the variables evaluated interacted significantly in determining the TC. An overall TC-per-treatment model did not adequately represent the reduction of the cells on the original surface after each contact and the interaction of the factors studied. However, an exponential model was developed that explained the experimental data for all treatments and represented the recontamination of the surfaces with E. coli O157:H7. The parameters for the exponential model for cross-contamination with E. coli O157:H7 between beef tissue and HDPE surfaces were determined, allowing for the use of the resulting model in quantitative microbial risk assessment.

  18. Impacts of population growth, urbanisation and sanitation changes on global human Cryptosporidium emissions to surface water.

    Science.gov (United States)

    Hofstra, Nynke; Vermeulen, Lucie C

    2016-10-01

    Cryptosporidium is a pathogenic protozoan parasite and is a leading cause of diarrhoea worldwide. The concentration of Cryptosporidium in the surface water is a determinant for probability of exposure and the risk of disease. Surface water concentrations are expected to change with population growth, urbanisation and changes in sanitation. The objective of this paper is to assess the importance of future changes in population, urbanisation and sanitation on global human emissions of Cryptosporidium to surface water. The GloWPa-Crypto H1 (the Global Waterborne Pathogen model for Human Cryptosporidium emissions version 1) model is presented and run for 2010 and with scenarios for 2050. The new scenarios are based on the Shared Socio-economic Pathways (SSPs) developed for the climate community. The scenarios comprise assumptions on sanitation changes in line with the storylines and population and urbanisation changes from the SSPs. In SSP1 population growth is limited, urbanisation large and sanitation and waste water treatment strongly improve. SSP1* is the same as SSP1, but waste water treatment does not improve. SSP3 sees large population growth, moderate urbanisation and sanitation and waste water treatment fractions that are the same as in 2010. Total global Cryptosporidium emissions to surface water for 2010 are estimated to be 1.6×10 17 oocysts per year, with hotspots in the most urbanised parts of the world. In 2050 emissions are expected to decrease by 24% or increase by 52% and 70% for SSP1, SSP3 and SSP1* respectively. The emissions increase in all scenarios for countries in the Middle East and Africa (MAF) region, while emissions in large parts in Europe decrease in scenarios SSP1 and SSP3. Improving sanitation by connecting the population to sewers, should be combined with waste water treatment, otherwise (SSP1*) emissions in 2050 are expected to be much larger than in a situation with strong population growth and slow development of safe water and

  19. Greenhouse gas emissions from beef cattle pen surfaces in North Dakota.

    Science.gov (United States)

    Rahman, Shafiqur; Borhan, Md Saidul; Swanson, Kendall

    2013-01-01

    There is a global interest to quantify and mitigate greenhouse gas (GHG) (e.g. methane-CH4, nitrous oxide-N2O and carbon dioxide-CO2) emissions in animal feeding operations. The goal of this study was to quantify GHG emissions from the feedlot pen surface under North Dakota climatic conditions. In this study gaseous flux from the pen surfaces was generated using a custom-made wind tunnel at different times of the year (summer, fall, winter and spring). Gaseous fluxes (air samples) were drawn in the Tedlar bags using a vacuum chamber and gas concentrations were measured using a gas chromatograph within 24 h of sampling. The CH4 concentrations and flux rates (FRs) or flux among the months were not significantly different. Overall CH4, CO2 and N2O concentrations over a 7-month period were 2.66, 452 and 0.67 ppm, respectively. Estimated overall CH4, CO and N2O FRs were 1.32, 602 and 0.90 g m(-2) d(-1), respectively. Estimated emission rates using the wind tunnel were 38 g hd(-1) d(-1), 17 kg hd(-1) d(-1) and 26 g hd(-1) d(-1) for CH4, CO2 and N2O, respectively. The emission factors for GHG estimated in the research for North Dakota climate were the first of its kind, and these emission estimates can be used as a basis for planning and implementing management practices to minimize GHG emissions.

  20. Soil-soil solution distribution coefficient of soil organic matter is a key factor for that of radioiodide in surface and subsurface soils.

    Science.gov (United States)

    Unno, Yusuke; Tsukada, Hirofumi; Takeda, Akira; Takaku, Yuichi; Hisamatsu, Shun'ichi

    2017-04-01

    We investigated the vertical distribution of the soil-soil-solution distribution coefficients (K d ) of 125 I, 137 Cs, and 85 Sr in organic-rich surface soil and organic-poor subsurface soil of a pasture and an urban forest near a spent-nuclear-fuel reprocessing plant in Rokkasho, Japan. K d of 137 Cs was highly correlated with water-extractable K + . K d of 85 Sr was highly correlated with water-extractable Ca 2+ and SOC. K d of 125 I - was low in organic-rich surface soil, high slightly below the surface, and lowest in the deepest soil. This kinked distribution pattern differed from the gradual decrease of the other radionuclides. The thickness of the high- 125 I - K d middle layer (i.e., with high radioiodide retention ability) differed between sites. K d of 125 I - was significantly correlated with K d of soil organic carbon. Our results also showed that the layer thickness is controlled by the ratio of K d -OC between surface and subsurface soils. This finding suggests that the addition of SOC might prevent further radioiodide migration down the soil profile. As far as we know, this is the first report to show a strong correlation of a soil characteristic with K d of 125 I - . Further study is needed to clarify how radioiodide is retained and migrates in soil. Copyright © 2017 Elsevier Ltd. All rights reserved.

  1. SURFACE FILMS TO SUPPRESS FIELD EMISSION IN HIGH-POWER MICROWAVE COMPONENTS

    Energy Technology Data Exchange (ETDEWEB)

    Hirshfield, Jay l

    2014-02-07

    Results are reported on attempts to reduce the RF breakdown probability on copper accelerator structures by applying thin surface films that could suppress field emission of electrons. Techniques for application and testing of copper samples with films of metals with work functions higher than copper are described, principally for application of platinum films, since platinum has the second highest work function of any metal. Techniques for application of insulating films are also described, since these can suppress field emission and damage on account of dielectric shielding of fields at the copper surface, and on account of the greater hardness of insulating films, as compared with copper. In particular, application of zirconium oxide films on high-field portions of a 11.424 GHz SLAC cavity structure for breakdown tests are described.

  2. MEaSUReS Land Surface Temperature and Emissivity data records

    Science.gov (United States)

    Cawse-Nicholson, K.; Hook, S. J.; Gulley, G.; Borbas, E. E.; Knuteson, R. O.

    2017-12-01

    The NASA MEaSUReS program was put into place to produce long-term, well calibrated and validated data records for Earth Science research. As part of this program, we have developed three Earth System Data Records (ESDR) to measure Land Surface Temperature (LST) and emissivity: a high spatial resolution (1km) LST product using Low Earth Orbiting (LEO) satellites; a high temporal resolution (hourly over North America) LST product using Geostationary (GEO) satellites; and a Combined ASTER MODIS Emissivity for Land (CAMEL) ESDR. CAMEL was produced by merging two state-of-the-art emissivity datasets: the UW-Madison MODIS Infrared emissivity dataset (UWIREMIS), and the JPL ASTER Global Emissivity Dataset v4 (GEDv4). The CAMEL ESDR is currently available for download, and is being tested in sounder retrieval schemes (e.g. CrIS, IASI, AIRS) to reduce uncertainties in water vapor retrievals, and has already been implemented in the radiative transfer software RTTOV v12 for immediate use in numerical weather modeling and data assimilation systems. The LEO-LST product combines two existing MODIS products, using an uncertainty analysis approach to optimize accuracy over different landcover classes. Validation of these approaches for retrieving LST have shown that they are complementary, with the split-window approach (MxD11) being more stable over heavily vegetated regions and the physics-based approach (MxD21) demonstrating higher accuracy in semi-arid and arid regions where the largest variations in emissivity exist, both spatially and spectrally. The GEO LST-ESDR product uses CAMEL ESDR for improved temperature-emissivity separation, and the same atmospheric correction as the LEO LST product to ensure consistency across all three data records.

  3. Surface irrigation reduces the emission of volatile 1,3-dichloropropene from agricultural soils.

    Science.gov (United States)

    Ashworth, D J; Yates, S R

    2007-04-01

    Low-cost, practicable techniques are required to limit the release of volatile organic compound-containing fumigants such as 1,3-D to the atmosphere. In this study, we aimed to quantify 1,3-D diffusion and emission from laboratory soil columns maintained under realistic conditions and thereby assess the efficacy of soil irrigation as a technique for reducing emissions. In two soils (one relatively high, and one relatively low, in organic matter), irrigation led to a limiting of upward diffusion of the fumigant and to the maintenance of higher soil gas concentrations. Therefore, rather than being emitted from the column, the 1,3-D was maintained in the soil where it was ultimately degraded. As a consequence, emission of 1,3-D from the irrigated columns was around half of thatfrom the nonirrigated columns. It is concluded that surface irrigation represents an effective, low-cost, and readily practicable approach to lessening the environmental impact of 1,3-D fumigant use. In addition, the higher organic matter soil exhibited emissions of around one-fifth of the lower organic matter soil in both irrigated and nonirrigated treatments, due to markedly enhanced degradation of the fumigant. Organic matter amendment of soils may, therefore, also represent an extremely effective, relatively low-cost approach to reducing 1,3-D emissions.

  4. IRAS surface brightness maps of visible reflection nebulae: evidence for non-equilibrium infrared emission

    International Nuclear Information System (INIS)

    Castelaz, M.W.; Werner, M.W.; Sellgren, K.

    1986-01-01

    Surface brightness maps at 12, 25, 60, and 100 microns of 16 visible reflection nebulae were extracted from the Infrared Astronomy Satellite (IRAS) database. The maps were produced by coadding IRAS survey scans over areas centered on the illuminating stars, and have spatial resolutions of 0.9' x 4' at 12 and 25 microns, 1.8' x 4.5' at 60 microns, and 3.6' x 5' at 100 microns. Extended emission in the four IRAS bandpasses was detected in fourteen of the reflection nebulae. The IRAS data were used to measure the flux of the infrared emission associated with each source. The energy distributions show that the 12 micron flux is greater than the 25 micron flux in 11 of the nebulae, and the peak flux occurs in the 60 or 100 micron bandpass in all 16 nebular. The 60 and 100 micron flux can be approximated by blackbodies with temperatures between 30 and 50 K, consistent with temperatures expected from extrapolation of greybody fits to the 60 and 100 micron data. The excess 12 and 25 micron emission is attributed to a nonequilibrium process such as emission from thermal fluctuations of very small grains excited by single ultraviolet photons, or emission from polycyclic aromatic hydrocarbons (PAHs) excited by ultraviolet radiation. The common features of the energy distributions of the 16 reflection nebulae, also seen in the reflection nebulae associated with the Pleiades, suggest that PAHs or very small grains may be found in most reflection nebulae

  5. Moderate Resolution Imaging Spectroradiometer (MODIS) MOD21 Land Surface Temperature and Emissivity Algorithm Theoretical Basis Document

    Science.gov (United States)

    Hulley, G.; Malakar, N.; Hughes, T.; Islam, T.; Hook, S.

    2016-01-01

    This document outlines the theory and methodology for generating the Moderate Resolution Imaging Spectroradiometer (MODIS) Level-2 daily daytime and nighttime 1-km land surface temperature (LST) and emissivity product using the Temperature Emissivity Separation (TES) algorithm. The MODIS-TES (MOD21_L2) product, will include the LST and emissivity for three MODIS thermal infrared (TIR) bands 29, 31, and 32, and will be generated for data from the NASA-EOS AM and PM platforms. This is version 1.0 of the ATBD and the goal is maintain a 'living' version of this document with changes made when necessary. The current standard baseline MODIS LST products (MOD11*) are derived from the generalized split-window (SW) algorithm (Wan and Dozier 1996), which produces a 1-km LST product and two classification-based emissivities for bands 31 and 32; and a physics-based day/night algorithm (Wan and Li 1997), which produces a 5-km (C4) and 6-km (C5) LST product and emissivity for seven MODIS bands: 20, 22, 23, 29, 31-33.

  6. Silver-graphene oxide based plasmonic spacer for surface plasmon-coupled fluorescence emission enhancements

    Science.gov (United States)

    Badiya, Pradeep Kumar; Srinivasan, Venkatesh; Sathish Ramamurthy, Sai

    2017-06-01

    We report the application of single layered graphene oxide (SLGO) and silver decorated SLGO (Ag-SLGO) as plasmonic spacer material for obtaining enhanced fluorescence from a Rhodamine 6G (Rh6G) radiating dipole in a surface plasmon-coupled emission platform. To this end, we have decorated SLGO with biphasic silver nanoparticles using an in situ deposition technique to achieve 112-fold fluorescence enhancements.

  7. Transition absorption as a mechanism of surface photoelectron emission from metals

    DEFF Research Database (Denmark)

    Zhukovsky, Sergei; Protsenko, Igor E.; Ikhsanov, Renat Sh

    2015-01-01

    Transition absorption of a photon by an electron passingthrough a boundary between two media with different permit-tivities is described both classically and quantum mechani-cally. Transition absorption is shown to make a substantialcontribution to photoelectron emission at a metal....../semicon-ductor interface in nanoplasmonic systems, and is put forth asa possible microscopic mechanism of the surface photoelec-tric effect in photodetectors and solar cells containing plas-monic nanoparticles....

  8. Surface trapping phenomena in thermionic emission generating l/f noise

    International Nuclear Information System (INIS)

    Stepanescu, A.

    1975-01-01

    A general expression of the power spectrum of''flicker noise'', involving stochastic trapping phenomena and calculated on the basis of a two parameter model, is applied in the case of thermoionic emission from cathode surface. The fluctuation of the work function over the cathode surface is interpreted as being due to a trapping process of foreign atoms by the cathode. Taking into account the very physical nature of the trapping mechanism, under self-consistent assumptions, a 1/f power spectrum is obtained in a certain range of frequency. The two parameter model removes some discrepancies involved in the preceding theories. (author)

  9. Surface effects during exoelectron-emission of BeO ceramics

    International Nuclear Information System (INIS)

    Siegel, V.; Kirchner, H.H.

    1979-01-01

    Studying the behaviour of the two thermally stimulated exoelectron emission (TSEE) maxima of BeO ceramics at about 270 0 C und 325 0 C it can be shown that the TSEE maximum at 270 0 C is closely connected with adsorption and desorption processes occuring on the surface of the samples. In particular, this TSEE maximum is strongly influenced as well by donor-like behaviour of adsorbed hydrogen and lithium as by acceptor-like behaviour of alcohols and nitrides of the lithium. The detailed surface processes leading to the apperance or disapperance of the TSEE maximum at 270 0 C are discussed. (orig.) [de

  10. Research on surface modification and infrared emissivity of In2O3: W thin films

    International Nuclear Information System (INIS)

    Fu, Qiang; Wang, Wenwen; Li, Dongliang; Pan, Jiaojiao

    2014-01-01

    Tungsten-doped indium oxide films (In 2 O 3 : W, IWO) were deposited on glass substrates by DC reactive magnetron sputtering method. The as-deposited IWO films have a minimum resistivity of 6.3 × 10 −4 Ω·cm and an average infrared emissivity of 0.22 in 8–14 μm. The average transmittance is about 90% in visible region and above 81% in near-infrared region. Polystyrene microsphere template and DC magnetron sputtering were used to prepare an Ag micro-grid monolayer on the as-deposited IWO films. After surface modification, the resistivity of the films was reduced by 50% and the average infrared emissivity in 8–14 μm also reduced by 25%. The effects of sphere size and sputtering time on the surface morphology, optical and electrical properties, and infrared emissivity of the IWO thin films were investigated and the mechanism was studied. - Highlights: • High performance In 2 O 3 : W (IWO) films were obtained by DC magnetron sputtering. • Micro-grids on surface were prepared by polystyrene microsphere template method. • Influences of micro-grid size and depth on properties of IWO films were analyzed. • High conductivity and transparency in near-infrared region are obtained

  11. Thermal Performance of Hollow Clay Brick with Low Emissivity Treatment in Surface Enclosures

    Directory of Open Access Journals (Sweden)

    Roberto Fioretti

    2014-10-01

    Full Text Available External walls made with hollow clay brick or block are widely used for their thermal, acoustic and structural properties. However, the performance of the bricks frequently does not conform with the minimum legal requirements or the values required for high efficiency buildings, and for this reason, they need to be integrated with layers of thermal insulation. In this paper, the thermal behavior of hollow clay block with low emissivity treatment on the internal cavity surfaces has been investigated. The purpose of this application is to obtain a reduction in the thermal conductivity of the block by lowering the radiative heat exchange in the enclosures. The aims of this paper are to indicate a methodology for evaluating the thermal performance of the brick and to provide information about the benefits that should be obtained. Theoretical evaluations are carried out on several bricks (12 geometries simulated with two different thermal conductivities of the clay, using a finite elements model. The heat exchange procedure is implemented in accordance with the standard, so as to obtain standardized values of the thermal characteristics of the block. Several values of emissivity are hypothesized, related to different kinds of coating. Finally, the values of the thermal transmittance of walls built with the evaluated blocks have been calculated and compared. The results show how coating the internal surface of the cavity provides a reduction in the thermal conductivity of the block, of between 26% and 45%, for a surface emissivity of 0.1.

  12. Improving the indoor air quality by using a surface emissions trap

    Science.gov (United States)

    Markowicz, Pawel; Larsson, Lennart

    2015-04-01

    The surface emissions trap, an adsorption cloth developed for reducing emissions of volatile organic compounds and particulate matter from surfaces while allowing evaporation of moisture, was used to improve the indoor air quality of a school building with elevated air concentrations of 2-ethyl-1-hexanol. An improvement of the perceived air quality was noticed a few days after the device had been attached on the PVC flooring. In parallel, decreased air concentrations of 2-ethyl-1-hexanol were found as well as a linear increase of the amounts of the same compound adsorbed on the installed cloth as observed up to 13 months after installation. Laboratory studies revealed that the performance of the device is not affected by differences in RH (35-85%), temperature (30-40 °C) or by accelerated aging simulating up to 10 years product lifetime, and, from a blinded exposure test, that the device efficiently blocks chemical odors. This study suggests that the device may represent a fast and efficient means of restoring the indoor air quality in a building e.g. after water damage leading to irritating and potentially harmful emissions from building material surfaces indoors.

  13. Topographic Effects on the Surface Emissivity of a Mountainous Area Observed by a Spaceborne Microwave Radiometer

    Directory of Open Access Journals (Sweden)

    Frank S. Marzano

    2008-03-01

    Full Text Available A simulation study to understand the influence of topography on the surfaceemissivity observed by a satellite microwave radiometer is carried out. We analyze theeffects due to changes in observation angle, including the rotation of the polarization plane.A mountainous area in the Alps (Northern Italy is considered and the information on therelief extracted from a digital elevation model is exploited. The numerical simulation refersto a radiometric image, acquired by a conically-scanning radiometer similar to AMSR-E,i.e., flying at 705 km of altitude with an observation angle of 55°. To single out the impacton surface emissivity, scattering of the radiation due to the atmosphere or neighboringelevated surfaces is not considered. C and X bands, for which atmospheric effects arenegligible, and Ka band are analyzed. The results indicate that the changes in the localobservation angle tend to lower the apparent emissivity of a radiometric pixel with respectto the corresponding flat surface characteristics. The effect of the rotation of thepolarization plane enlarges (vertical polarization, or attenuates (horizontal polarizationthis decrease. By doing some simplifying assumptions for the radiometer antenna, theconclusion is that the microwave emissivity at vertical polarization is underestimated,whilst the opposite occurs for horizontal polarization, except for Ka band, for which bothunder- and overprediction may occur. A quantification of the differences with respect to aflat soil and an approximate evaluation of their impact on soil moisture retrieval areyielded.

  14. Tunable wideband-directive thermal emission from SiC surface using bundled graphene sheets

    Science.gov (United States)

    Inampudi, Sandeep; Mosallaei, Hossein

    2017-09-01

    Coherent thermal radiation emitters based on diffraction gratings inscribed on surface of a polar material, such as silicon carbide, always possess high angular dispersion resulting in wideband-dispersive or monochromatic-directive emission. In this paper, we identify roots of the high angular dispersion as the rapid surface phonon polariton (SPhP) resonance of the material surface and the misalignment of the dispersion curve of the diffraction orders of the grating with respect to light line. We minimize the rapid variation of SPhP resonance by compensating the material dispersion using bundled graphene sheets and mitigate the misalignment by a proper choice of the grating design. Utilizing a modified form of rigorous coupled wave analysis to simultaneously incorporate atomic-scale graphene sheets and bulk diffraction gratings, we accurately compute the emissivity profiles of the composite structure and demonstrate reduction in the angular dispersion of thermal emission from as high as 30∘ to as low as 4∘ in the SPhP dominant wavelength range of 11-12 μ m . In addition, we demonstrate that the graphene sheets via their tunable optical properties allow a fringe benefit of dynamical variation of the angular dispersion to a wide range.

  15. Secondary electron emission from rough metal surfaces: a multi-generation model

    International Nuclear Information System (INIS)

    Cao, Meng; Zhang, Na; Wang, Fang; Hu, Tian-Cun; Cui, Wan-Zhao

    2015-01-01

    We develop a multi-generation model to examine secondary electron emission (SEE) from a rough metal surface. In this model, the traces of both primary electrons (PEs) and secondary electrons (SEs) are tracked by combining the electron scattering in the material and the multi-interaction with the rough surface. The effective secondary electron emission yield (SEY) is then obtained from the final states of the multi-generation SEs. Using this model, the SEE properties of the surfaces with rectangular and triangular grooves have been examined. We find that a rectangular groove can be used for effective SEE suppression. For a triangular groove, the criterion of SEY enhancement/suppression has been achieved, indicating that a small groove angle is required for effective SEE suppression, especially for a high PE energy. Furthermore, the SEE properties for some random rough surfaces are examined and some preliminary results are presented. Accordingly, our model and results could provide a powerful tool to give a comprehensive insight into the SEE of rough metal surfaces. (paper)

  16. Ocean Surface Emissivity at L-band (1.4 GHz): The Dependence on Salinity and Roughness

    Science.gov (United States)

    Le Vine, D. M.; Lang, R. H.; Wentz, F. J.; Meissner, T.

    2012-12-01

    radiometric brightness temperature with the value expected for a surface with the same salinity and physical temperature. A parametric model for the excess brightness temperature as a function of wind speed and wind direction is developed in the form: ΔTB = A0(w) + A1(w) cos(φ) + A2(w) cos(2φ) where w = wind speed; φ = wind direction (relative to the look direction of the radiometer) and ΔTB = ΔE Ts where Ts is the physical temperature and ΔE is the change in emissivity caused by the waves. A0(w) is roughly linear with wind speed with values on the order of 3 K at 15 m/s. The directional dependence is much smaller but the data definitely indicate a directional component for wind speeds greater than 10-15 m/s. The coefficients depend on the incidence angle of the radiometer.

  17. Gas-surface interactions using accommodation coefficients for a dilute and a dense gas in a micro- or nanochannel: heat flux predictions using combined molecular dynamics and Monte Carlo techniques.

    Science.gov (United States)

    Nedea, S V; van Steenhoven, A A; Markvoort, A J; Spijker, P; Giordano, D

    2014-05-01

    The influence of gas-surface interactions of a dilute gas confined between two parallel walls on the heat flux predictions is investigated using a combined Monte Carlo (MC) and molecular dynamics (MD) approach. The accommodation coefficients are computed from the temperature of incident and reflected molecules in molecular dynamics and used as effective coefficients in Maxwell-like boundary conditions in Monte Carlo simulations. Hydrophobic and hydrophilic wall interactions are studied, and the effect of the gas-surface interaction potential on the heat flux and other characteristic parameters like density and temperature is shown. The heat flux dependence on the accommodation coefficient is shown for different fluid-wall mass ratios. We find that the accommodation coefficient is increasing considerably when the mass ratio is decreased. An effective map of the heat flux depending on the accommodation coefficient is given and we show that MC heat flux predictions using Maxwell boundary conditions based on the accommodation coefficient give good results when compared to pure molecular dynamics heat predictions. The accommodation coefficients computed for a dilute gas for different gas-wall interaction parameters and mass ratios are transferred to compute the heat flux predictions for a dense gas. Comparison of the heat fluxes derived using explicit MD, MC with Maxwell-like boundary conditions based on the accommodation coefficients, and pure Maxwell boundary conditions are discussed. A map of the heat flux dependence on the accommodation coefficients for a dense gas, and the effective accommodation coefficients for different gas-wall interactions are given. In the end, this approach is applied to study the gas-surface interactions of argon and xenon molecules on a platinum surface. The derived accommodation coefficients are compared with values of experimental results.

  18. Field and laboratory emission cell automation and control system for investigating surface chemistry reactions

    Science.gov (United States)

    Flemmer, Michael M.; Ham, Jason E.; Wells, J. R.

    2007-01-01

    A novel system [field and laboratory emission cell (FLEC) automation and control system] has been developed to deliver ozone to a surface utilizing the FLEC to simulate indoor surface chemistry. Ozone, humidity, and air flow rate to the surface were continuously monitored using an ultraviolet ozone monitor, humidity, and flow sensors. Data from these sensors were used as feedback for system control to maintain predetermined experimental parameters. The system was used to investigate the chemistry of ozone with α-terpineol on a vinyl surface over 72h. Keeping all other experimental parameters the same, volatile organic compound emissions from the vinyl tile with α-terpineol were collected from both zero and 100ppb(partsper109) ozone exposures. System stability profiles collected from sensor data indicated experimental parameters were maintained to within a few percent of initial settings. Ozone data from eight experiments at 100ppb (over 339h) provided a pooled standard deviation of 1.65ppb and a 95% tolerance of 3.3ppb. Humidity data from 17 experiments at 50% relative humidity (over 664h) provided a pooled standard deviation of 1.38% and a 95% tolerance of 2.77%. Data of the flow rate of air flowing through the FLEC from 14 experiments at 300ml/min (over 548h) provided a pooled standard deviation of 3.02ml/min and a 95% tolerance range of 6.03ml/min. Initial experimental results yielded long term emissions of ozone/α-terpineol reaction products, suggesting that surface chemistry could play an important role in indoor environments.

  19. N2O emission from plant surfaces - light stimulated and a global phenomenon.

    Science.gov (United States)

    Mikkelsen, Teis; Bruhn, Dan; Ambus, Per

    2017-04-01

    Nitrous oxide (N2O) is an important long-lived greenhouse gas and precursor of stratospheric ozone depleting mono-nitrogen oxides. The atmospheric concentration of N2O is persistently increasing; however, large uncertainties are associated with the distinct source strengths. Here we investigate for the first time N2O emission from terrestrial vegetation in response to natural solar ultra violet radiation. We conducted field site measurements to investigate N2O atmosphere exchange from grass vegetation exposed to solar irradiance with and without UV-screening. Further laboratory tests were conducted with a range of species to study the controls and possible loci of UV-induced N2O emission from plants. Plants released N2O in response to natural sunlight at rates of c. 20-50 nmol m-2 h-1, mostly due to the UV component. The emission rate is temperature dependent with a rather high activation energy indicative for an abiotic process. The prevailing zone for the N2O formation appears to be at the very surface of leaves. However, only c. 26% of the UV-induced N2O appears to originate from plant-N. Further, the process is dependent on atmospheric oxygen concentration. Our work demonstrates that ecosystem emission of the important greenhouse gas, N2O, may be up to c. 30% higher than hitherto assumed. Literature: Mikkelsen TN, Bruhn D & Ambus P. (2016). Solar UV Irradiation-Induced Production of Greenhouse Gases from Plant Surfaces: From Leaf to Earth. Progress in Botany, DOI 10.1007/124_2016_10. Bruhn D, Albert KR, Mikkelsen TN & Ambus P. (2014). UV-induced N2O emission from plants. Atmospheric Environment 99, 206-214.

  20. Uncontrolled methane emissions from a MSW landfill surface: influence of landfill features and side slopes.

    Science.gov (United States)

    Di Trapani, Daniele; Di Bella, Gaetano; Viviani, Gaspare

    2013-10-01

    Sanitary landfills for Municipal Solid Waste (MSW) disposal have been identified as one of the most important anthropogenic sources of methane (CH4) emissions; in order to minimize its negative effects on the environment, landfill gas (LFG) recovery is a suitable tool to control CH4 emissions from a landfill site; further, the measurement of CH4 emissions can represent a good way to evaluate the effectiveness of LFG recovering systems. In general, LFG will escape through any faults in the landfill capping or in the LFG collection system. Indeed, some areas of the capping can be more permeable than others (e.g. portions of a side slope), especially when considering a temporarily capped zone (covered area that is not expected to receive any further waste for a period of at least 3 months, but for engineering reasons does not have a permanent cap yet). These areas, which are characterized by abnormal emissions, are usually defined as "features": in particular, a feature is a small, discrete area or an installation where CH4 emissions significantly differ from the surrounding zones. In the present study, the influence that specific features have on CH4 emissions has been investigated, based on direct measurements carried out in different seasons by means of a flux chamber to the case study of Palermo (IT) landfill (Bellolampo). The results showed that the flux chamber method is reliable and easy to perform, and the contoured flux maps, obtained by processing the measured data were found to be a suitable tool for identifying areas with abnormal (high) emissions. Further, it was found that a relationship between methane emission rates and landfill side slope can be established. Concerning the influence of the temporary HDPE cover system on CH4 recovery efficiency, it contributed to a significant decrease of the free surface area available for uncontrolled emissions; this aspect, coupled to the increase of the CH4 volumes collected by the LFG recovery system, led to a

  1. Anisotropy of the Seebeck Coefficient in the Cuprate Superconductor YBa_{2}Cu_{3}O_{y}: Fermi-Surface Reconstruction by Bidirectional Charge Order

    Directory of Open Access Journals (Sweden)

    O. Cyr-Choinière

    2017-09-01

    Full Text Available The Seebeck coefficient S of the cuprate YBa_{2}Cu_{3}O_{y} is measured in magnetic fields large enough to suppress superconductivity, at hole dopings p=0.11 and p=0.12, for heat currents along the a and b directions of the orthorhombic crystal structure. For both directions, S/T decreases and becomes negative at low temperature, a signature that the Fermi surface undergoes a reconstruction due to broken translational symmetry. Above a clear threshold field, a strong new feature appears in S_{b}, for conduction along the b axis only. We attribute this feature to the onset of 3D-coherent unidirectional charge-density-wave modulations seen by x-ray diffraction, also along the b axis only. Because these modulations have a sharp onset temperature well below the temperature where S/T starts to drop towards negative values, we infer that they are not the cause of Fermi-surface reconstruction. Instead, the reconstruction must be caused by the quasi-2D bidirectional modulations that develop at significantly higher temperature. The unidirectional order only confers an additional anisotropy to the already reconstructed Fermi surface, also manifest as an in-plane anisotropy of the resistivity.

  2. Climate change impact of livestock CH4emission in India: Global temperature change potential (GTP) and surface temperature response.

    Science.gov (United States)

    Kumari, Shilpi; Hiloidhari, Moonmoon; Kumari, Nisha; Naik, S N; Dahiya, R P

    2018-01-01

    Two climate metrics, Global surface Temperature Change Potential (GTP) and the Absolute GTP (AGTP) are used for studying the global surface temperature impact of CH 4 emission from livestock in India. The impact on global surface temperature is estimated for 20 and 100 year time frames due to CH 4 emission. The results show that the CH 4 emission from livestock, worked out to 15.3 Tg in 2012. In terms of climate metrics GTP of livestock-related CH 4 emission in India in 2012 were 1030 Tg CO 2 e (GTP 20 ) and 62 Tg CO 2 e (GTP 100 ) at the 20 and 100 year time horizon, respectively. The study also illustrates that livestock-related CH 4 emissions in India can cause a surface temperature increase of up to 0.7mK and 0.036mK over the 20 and 100 year time periods, respectively. The surface temperature response to a year of Indian livestock emission peaks at 0.9mK in the year 2021 (9 years after the time of emission). The AGTP gives important information in terms of temperature change due to annual CH 4 emissions, which is useful when comparing policies that address multiple gases. Copyright © 2017 Elsevier Inc. All rights reserved.

  3. A Remote Sensing Analysis on the Spatiotemporal Variation of Land Surface Albedo and Emissivity in South Florida: An Implication for Surface-Atmosphere Energy and Water Exchange

    Science.gov (United States)

    Kandel, H. P.; Melesse, A. M.

    2016-12-01

    Land use /land cover has wide range of impacts from surface energy budget to radiative forcing of climate change. This study aims to analyze the variation in two radiative properties, albedo and emissivity in South Florida landscape to investigate how radially distinct surfaces lead to a energy and moisture contrast on the near-surface atmosphere and eventually to surface-induced climate. Maps of land surface albedo and emissivity were prepared using algorithms that convert narrow-band spectral reflectance to total short-wave albedo, and vegetation index to emissivity from Landsat -5 TM images of several different summer dates. A comparative analysis was made using the zonal statistics in ArcGIS. Relatively higher albedos were found over cultivated and developed lands (0.17 - 0.21) than in forests and herbaceous wetland (0.09 - 0.16). The emissivities, on the other hand, are lower for developed and drained lands. Average albedo exhibits a slight increase whereas emissivity is found to be decreasing through time. Urban areas showing higher albedos, a unique occurrence in this landscape, store less short-wave radiation, however, their lower emissivities points to increased storage of long-wave radiation. The results imply that the emissivity perhaps play a dominant role in heat island development and initiation of local circulation in urbanized South Florida.

  4. An assessment of surface emissivity variation effects on plasma uniformity analysis using IR cameras

    Science.gov (United States)

    Greenhalgh, Abigail; Showers, Melissa; Biewer, Theodore

    2017-10-01

    The Prototype-Material Plasma Exposure eXperiment (Proto-MPEX) is a linear plasma device operating at Oak Ridge National Laboratory (ORNL). Its purpose is to test plasma source and heating concepts for the planned Material Plasma Exposure eXperiment (MPEX), which has the mission to test the plasma-material interactions under fusion reactor conditions. In this device material targets will be exposed to high heat fluxes (>10 MW/m2). To characterize the heat fluxes to the target a IR thermography system is used taking up to 432 frames per second videos. The data is analyzed to determine the surface temperature on the target in specific regions of interest. The IR analysis has indicated a low level of plasma uniformity; the plasma often deposits more heat to the edge of the plate than the center. An essential parameter for IR temperature calculation is the surface emissivity of the plate (stainless steel). A study has been performed to characterize the variation in the surface emissivity of the plate as its temperature changes and its surface finish is modified by plasma exposure.

  5. Impact of Future Emissions and Climate Change on Surface Ozone over China

    Science.gov (United States)

    Ma, C. T.; Westervelt, D. M.; Fiore, A. M.; Rieder, H. E.; Kinney, P.; Wang, S.; Correa, G. J. P.

    2017-12-01

    China's immense ambient air pollution problem and world-leading greenhouse gas emissions place it at the forefront of global efforts to address these related environmental concerns. Here, we analyze the impact of ECLIPSE (Evaluating the Climate and Air Quality Impacts of Short-Lived Pollutants) future emissions scenarios representative of current legislation (CLE) and maximum technically feasible emissions reductions (MFR) on surface ozone (O3) concentrations over China in the 2030s and 2050s, in the context of a changing climate. We use a suite of simulations performed with the NOAA Geophysical Fluid Dynamics Laboratory's AM3 global chemistry-climate model. To estimate the impact of climate change in isolation on Chinese air quality, we hold emissions of air pollutants including O3 precursors fixed at 2015 levels but allow climate (global sea surface temperatures and sea ice cover) to change according to decadal averages for the years 2026-2035 and 2046-2055 from a three-member ensemble of GFDL-CM3 simulations under the RCP8.5 high warming scenario. Evaluation of the present-day simulation (2015 CLE) with observations from 1497 chiefly urban air quality monitoring stations shows that simulated surface O3 is positively biased by 26 ppb on average over the domain of China. Previous studies, however, have shown that the modeled ozone response to changes in NOx emissions over the Eastern United States mirrors the magnitude and structure of observed changes in maximum daily average 8-hour (MDA8) O3 distributions. Therefore, we use the model's simulated changes for the 2030s and 2050s to project changes in policy-relevant MDA8 O3 concentrations. We find an overall increase in MDA8 O3 for CLE scenarios in which emissions of NOx precursors are projected to increase, and under MFR scenarios, an overall decrease, with the highest changes occurring in summertime for both 2030 and 2050 MFR. Under climate change alone, the model simulates a mean summertime decrease of 1.3 ppb

  6. Using satellite data to guide emission control strategies for surface ozone pollution

    Science.gov (United States)

    Jin, X.; Fiore, A. M.

    2017-12-01

    Surface ozone (O3) has adverse effects on public health, agriculture and ecosystems. As a secondary pollutant, ozone is not emitted directly. Ozone forms from two classes of precursors: NOx and VOCs. We use satellite observations of formaldehyde (a marker of VOCs) and NO2 (a marker of NOx) to identify areas which would benefit more from reducing NOx emissions (NOx-limited) versus areas where reducing VOC emissions would lead to lower ozone (VOC-limited). We use a global chemical transport model (GEOS-Chem) to develop a set of threshold values that separate the NOx-limited and VOC-limited conditions. Combining these threshold values with a decadal record of satellite observations, we find that U.S. cities (e.g. New York, Chicago) have shifted from VOC-limited to NOx-limited ozone production regimes in the warm season. This transition reflects the NOx emission controls implemented over the past decade. Increasing NOx sensitivity implies that regional NOx emission control programs will improve O3 air quality more now than it would have a decade ago.

  7. Enhanced Field Emission Studies on Niobium Surfaces Relevant to High Field Superconducting Radio-Frequency Devices

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Tong [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)

    2002-09-18

    Enhanced field emission (EFE) presents the main impediment to higher acceleration gradients in superconducting niobium (Nb) radiofrequency cavities for particle accelerators. The strength, number and sources of EFE sites strongly depend on surface preparation and handling. The main objective of this thesis project is to systematically investigate the sources of EFE from Nb, to evaluate the best available surface preparation techniques with respect to resulting field emission, and to establish an optimized process to minimize or eliminate EFE. To achieve these goals, a scanning field emission microscope (SFEM) was designed and built as an extension to an existing commercial scanning electron microscope (SEM). In the SFEM chamber of ultra high vacuum, a sample is moved laterally in a raster pattern under a high voltage anode tip for EFE detection and localization. The sample is then transferred under vacuum to the SEM chamber equipped with an energy-dispersive x-ray spectrometer for individual emitting site characterization. Compared to other systems built for similar purposes, this apparatus has low cost and maintenance, high operational flexibility, considerably bigger scan area, as well as reliable performance. EFE sources from planar Nb have been studied after various surface preparation, including chemical etching and electropolishing, combined with ultrasonic or high-pressure water rinse. Emitters have been identified, analyzed and the preparation process has been examined and improved based on EFE results. As a result, field-emission-free or near field-emission-free surfaces at ~140 MV/m have been consistently achieved with the above techniques. Characterization on the remaining emitters leads to the conclusion that no evidence of intrinsic emitters, i.e., no fundamental electric field limit induced by EFE, has been observed up to ~140 MV/m. Chemically etched and electropolished Nb are compared and no significant difference is observed up to ~140 MV/m. To

  8. Factors Influencing Surface Emissions of CO and NOx From a Brazilian Savanna

    Science.gov (United States)

    Zepp, R. G.; Kisselle, K. W.; Burke, R. A.; Pinto, A. S.; Bustamante, M. M.

    2002-12-01

    Human activities in savannas such as biomass burning and land conversion influence soil and plant emissions of atmospheric carbon monoxide (CO) and NOx [nitric oxide (NO) plus nitrogen dioxide (NO2)]. Direct emissions of these gases from burning are a major global source. In addition, emissions of CO and NOX from soils and plant litter also provide a significant source of the gases. Here, we report field and laboratory investigations of the production of CO and NOx from soils and surface litter derived from two natural vegetation types in central Brazil, cerrado stricto sensu (20-50% canopy cover) and campo sujo (open scrubland). The field studies were conducted using opaque and transparent flux chambers to investigate the effects of illumination and heating of the land surface on the gas fluxes. These studies showed that both NOx and CO fluxes were elevated in the transparent chambers. The largest increases in NOx and CO fluxes were observed from recently burned surfaces, indicating that photochemical or temperature-sensitive precursors of the gases were produced in the surface residue by fire. Laboratory studies of the thermal production of CO from plant litter were species specific with activation energies ranging from 72 to 100 kJ mol-1. Activation energies for deciduous plant litter from the Brazilian sites were higher than those previously reported for African savanna grass litter. Other laboratory studies using simulated solar radiation demonstrated that removal of UV radiation by light filters strongly reduced CO fluxes, indicating that the observed enhancement of CO production under illumination was primarily due to photodegradation of the litter rather than enhanced thermal production.

  9. Calcium pyroxenes at Mercurian surface temperatures: investigation of in-situ emissivity spectra and thermal expansion

    Science.gov (United States)

    Ferrari, S.; Nestola, F.; Helbert, J.; Maturilli, A.; D'Amore, M.; Alvaro, M.; Domeneghetti, M.; Massironi, M.; Hiesinger, H.

    2013-12-01

    The European Space Agency and Japan Aerospace Agency mission to Mercury, named BepiColombo, will carry on board the Mercury Radiometer and Thermal Infrared Spectrometer (MERTIS) that will be able to provide surface Thermal Infra-Red (TIR) emissivity spectra from 7 to 14 μm. This range of wavelengths is very useful to identify the fine-scale structural properties of several silicates. For mineral families as pyroxenes, the emissivity peak positions are good indicators of the composition. A complication in the interpretation of MERTIS data could arise from the extreme daily surface temperature range of Mercury (70 to 725 K) that significantly affects the crystal structure and density of minerals and consequently should affect the TIR spectral signature of each single mineral present on the surface of the planet. In preparation for the MERTIS data analysis, we are extensively investigating at high temperatures conditions several mineral phases potentially detectable on the surface of Mercury. Two C2/c augitic pyroxenes, with constant calcium content and very different magnesium to iron ratio, were studied by in situ high-temperature thermal infrared spectroscopy (up to 750 K) and in situ high-temperature single-crystal X-ray diffraction (up to 770 K). The emissivity spectra of the two samples show similar band center shifts of the main three bands toward lower wavenumbers with increasing temperature. Our results indicate that the center position of bands 1 and 2 is strictly dependent on temperature, whereas the center position of band 3 is a strong function of the composition regardless the temperature. These data suggest that MERTIS spectra will be able to provide indications of C2/c augitic pyroxene with different magnesium contents and will allow a correct interpretation independently on the spectra acquisition temperature.

  10. Experimental study of a high-efficiency low-emission surface combustor-heater

    International Nuclear Information System (INIS)

    Xiong, Tian-yu; Khinkis, M.J.; Fish, F.F.

    1991-01-01

    The surface combustor-heater is a combined combustion/heat-transfer device in which the heat-exchange surfaces are embedded in a stationary bed of refractory material where gaseous fuel is burned. Because of intensive heat radiation from the hot solid particles and enhanced heat convection from the gas flow to the heat-exchange tubes, heat transfer is significantly intensified. Removing heat simultaneously with the combustion process has the benefit of reducing the combustion temperature, which suppresses NO x formation. A basic experimental study was conducted on a 60-kW bench-scale surface combustor-heater with two rows of water-cooled tube coils to evaluate its performance and explore the mechanism of combined convective-radiative heat transfer and its interaction with combustion in the porous matrix. Combustion stability in the porous matrix, heat-transfer rates, emissions, and pressure drop through the unit have been investigated for the variable parameters of operation and unit configurations. Experimental results have demonstrated that high combustion intensity (up to 2.5 MW/m 2 ), high heat-transfer rates (up to 310 kW/m 2 ), high density of energy conversion (up to 8 MW/m 3 ), as well as ultra-low emissions (NO x and CO as low as 15 vppm*) have been achieved. The excellent performance of the test unit and the extensive data obtained from the present experimental study provide the basis for further development of high-efficiency and ultra low-emission water heaters, boilers, and process heaters based on the surface combustor-heater concept. 4 refs., 16 figs

  11. Surface plasmon polariton assisted red shift in excitonic emission of semiconductor microflowers

    Science.gov (United States)

    Parameswaran, Chithra; Warrier, Anita R.; Bingi, Jayachandra; Vijayan, C.

    2014-10-01

    We report on the study of metal nanoparticle-semiconductor hybrid system composed of β-indium sulfide (β-In2S3) and gold (Au) nanoparticles. β-In2S3 micron sized flower like structures (˜1 μm) and Au nanoparticles (˜10 nm) were synthesized by chemical route. These Au nanoparticles have surface plasmon resonance at ˜ 520 nm. We study the influence of Au surface plasmon polaritons on the radiative properties of the β-In2S3 microflowers. As a result of the coupling between the surface plasmon polaritons and the excitons there is a red shift ˜ 50 nm in emission spectrum of hybrid β-In2S3-Au system. Such hybrid systems provide scope for a control on the optical properties of semiconductor microstructures, thus rendering them suitable for specific device applications in optoelectronics and photovoltaics.

  12. Surface emission from neutron stars and implications for the physics of their interiors

    International Nuclear Information System (INIS)

    Özel, Feryal

    2013-01-01

    Neutron stars are associated with diverse physical phenomena that take place in conditions characterized by ultrahigh densities as well as intense gravitational, magnetic and radiation fields. Understanding the properties and interactions of matter in these regimes remains one of the challenges in compact object astrophysics. Photons emitted from the surfaces of neutron stars provide direct probes of their structure, composition and magnetic fields. In this review, I discuss in detail the physics that governs the properties of emission from the surfaces of neutron stars and their various observational manifestations. I present the constraints on neutron star radii, core and crust composition, and magnetic field strength and topology obtained from studies of their broadband spectra, evolution of thermal luminosity, and the profiles of pulsations that originate on their surfaces. (review article)

  13. Surface emission from neutron stars and implications for the physics of their interiors.

    Science.gov (United States)

    Ozel, Feryal

    2013-01-01

    Neutron stars are associated with diverse physical phenomena that take place in conditions characterized by ultrahigh densities as well as intense gravitational, magnetic and radiation fields. Understanding the properties and interactions of matter in these regimes remains one of the challenges in compact object astrophysics. Photons emitted from the surfaces of neutron stars provide direct probes of their structure, composition and magnetic fields. In this review, I discuss in detail the physics that governs the properties of emission from the surfaces of neutron stars and their various observational manifestations. I present the constraints on neutron star radii, core and crust composition, and magnetic field strength and topology obtained from studies of their broadband spectra, evolution of thermal luminosity, and the profiles of pulsations that originate on their surfaces.

  14. Effect of the field dependence of the coefficient of ion-electron emission on the characteristics of a normal cathode discharge

    NARCIS (Netherlands)

    Azarov, AV; Ochkin, VN

    2004-01-01

    The electric characteristics of the cathode layer of a normal glow discharge are discussed. The value of the normal current density and its dependence on the discharge parameters are modeled within a one-dimensional drift approximation with a local ionization. The dependence of the coefficient of

  15. Fourier emission infrared microspectrophotometer for surface analysis. I - Application to lubrication problems

    Science.gov (United States)

    Lauer, J. L.; King, V. W.

    1979-01-01

    A far-infrared interferometer was converted into an emission microspectrophotometer for surface analysis. To cover the mid-infrared as well as the far-infrared the Mylar beamsplitter was made replaceable by a germanium-coated salt plate, and the Moire fringe counting system used to locate the moveable Michelson mirror was improved to read 0.5 micron of mirror displacement. Digital electronics and a dedicated minicomputer were installed for data collection and processing. The most critical element for the recording of weak emission spectra from small areas was, however, a reflecting microscope objective and phase-locked signal detection with simultaneous referencing to a blackbody source. An application of the technique to lubrication problems is shown.

  16. The Venus Emissivity Mapper - gaining a global perspective on the surface composition of Venus

    Science.gov (United States)

    Helbert, Joern; Dyar, Melinda; Widemann, Thomas; Marcq, Emmanuel; Maturilli, Alessandro; Mueller, Nils; Kappel, David; Ferrari, Sabrina; D'Amore, Mario; Tsang, Constantine; Arnold, Gabriele; Smrekar, Suzanne; VEM Team

    2017-10-01

    The permanent cloud cover of Venus prohibits observations of the surface with traditional imaging techniques over much of the EM spectral range, leading to the false notion that information about the composition of Venus’ surface could only be derived from lander missions. However, harsh environmental conditions on the surface cause landed missions to be sole site, highly complex, and riskier than orbiting missions.It is now known that 5 transparency windows occur in the Venus atmosphere, ranging from 0.86 µm to 1.18 µm. Recent advances in high temperature laboratory spectroscopy at the PSL at DLR these windows are highly diagnostic for surface mineralogy. Mapping of the southern hemisphere of Venus with VIRTIS on VEX in the 1.02 µm band was a proof-of-concept for an orbital remote sensing approach to surface composition and weathering studies[1-3]. The Venus Emissivity Mapper [4] proposed for the NASA’s Venus Origins Explorer (VOX) and the ESA EnVision proposal builds on these recent advances. It is the first flight instrument specially designed with a sole focus on mapping the surface of Venus using the narrow atmospheric windows around 1 µm. Operating in situ from Venus orbit, VEM will provide a global map of surface composition as well as redox state of the surface, providing a comprehensive picture of surface-atmosphere interaction and support for landing site selection. Continuous observation of the thermal emission of the Venus will provide tight constraints on the current day volcanic activity[5]. This is complemented by measurements of atmospheric water vapor abundance as well as cloud microphysics and dynamics. These data will allow for accurate correction of atmospheric interference on the surface measurements, which provide highly valuable science on their own. A mission combining VEM with a high-resolution radar mapper such as VOX or EnVision in a low circular orbit will provide key insights into the divergent evolution of Venus.1. Smrekar, S

  17. Atmospheric emissions of methyl isothiocyanate and chloropicrin following soil fumigation and surface containment treatment in bare-root forest nurseries

    Science.gov (United States)

    D. Wang; J. Juzwik; S.W. Fraedrich; K. Spokas; Y. Zhang; W.C. Koskinen

    2005-01-01

    Methylisothiocyanate (MITC) and chloropicrin (CP) are alternatives to methyl bromide for soil fumigation. However, surface transport of MITC emission has been cited as the cause for seedling damage in adjacent fields at several bare-root forest-tree nurseries. Field experiments were conducted at nurseries to measure air emissions of MITC and CP after fumigation....

  18. 40 CFR 63.7905 - What emissions limitations or work practice standards must I meet for surface impoundments?

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 13 2010-07-01 2010-07-01 false What emissions limitations or work practice standards must I meet for surface impoundments? 63.7905 Section 63.7905 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) AIR PROGRAMS (CONTINUED) NATIONAL EMISSION STANDARDS FOR HAZARDOUS AIR POLLUTANTS FOR SOURCE...

  19. MODIS/Aqua Land Surface Temperature/Emissivity Monthly L3 Global 0.05Deg CMG V004

    Data.gov (United States)

    National Aeronautics and Space Administration — The MYD11C3.004 dataset was decommissioned as of October 20, 2017. Users are encouraged to use Version 6 of MODIS/Aqua Land Surface Temperature and Emissivity Daily...

  20. MODIS/Aqua Land Surface Temperature/Emissivity 8-Day L3 Global 0.05Deg CMG V041

    Data.gov (United States)

    National Aeronautics and Space Administration — The MYD11C2.041 dataset was decommissioned as of March 1, 2018. Users are encouraged to use Version 6 of MODIS/Aqua Land Surface Temperature and Emissivity Daily L3...

  1. MODIS/Terra Land Surface Temperature/Emissivity 8-Day L3 Global 0.05Deg CMG V041

    Data.gov (United States)

    National Aeronautics and Space Administration — The MOD11C2.041 dataset was decommissioned as of March 1, 2018. Users are encouraged to use Version 6 of MODIS/Terra Land Surface Temperature and Emissivity Daily L3...

  2. MODIS/Terra Land Surface Temperature/Emissivity Monthly L3 Global 0.05Deg CMG V004

    Data.gov (United States)

    National Aeronautics and Space Administration — The MOD11C3.004 dataset was decommissioned as of October 19, 2017. Users are encouraged to use Version 6 of MODIS/Terra Land Surface Temperature and Emissivity Daily...

  3. MODIS/Terra Near Real Time (NRT) Land Surface Temperature/Emissivity 5-Min L2 Swath 1km

    Data.gov (United States)

    National Aeronautics and Space Administration — The MODIS/Terra Near Real Time (NRT) level-2 Land Surface Temperature and Emissivity (LST/E) data (Shortname: MOD11_L2) incorporate 1 km pixels, which are produced...

  4. MODIS/Aqua Land Surface Temperature/Emissivity Daily L3 Global 5km SIN Grid V004

    Data.gov (United States)

    National Aeronautics and Space Administration — The MYD11B1.004 dataset was decommissioned as of October 27, 2017. Users are encouraged to use Version 6 of MODIS/Aqua Land Surface Temperature and Emissivity Daily...

  5. MODIS/Terra Land Surface Temperature/Emissivity Daily L3 Global 1km SIN Grid V041

    Data.gov (United States)

    National Aeronautics and Space Administration — The MOD11A1.041 dataset was decommissioned as of October 30, 2017. Users are encouraged to use Version 6 of MODIS/Terra Land Surface Temperature and Emissivity Daily...

  6. MODIS/Terra Land Surface Temperature/Emissivity 8-Day L3 Global 0.05Deg CMG V004

    Data.gov (United States)

    National Aeronautics and Space Administration — The MOD11C2.004 dataset was decommissioned as of October 19, 2017. Users are encouraged to use Version 6 of MODIS/Terra Land Surface Temperature and Emissivity Daily...

  7. MODIS/Terra Land Surface Temperature/Emissivity 5-Min L2 Swath 1km V005

    Data.gov (United States)

    National Aeronautics and Space Administration — The MODIS/Terra level-2 Land Surface Temperature and Emissivity (LST/E) data (Shortname: MOD11_L2) incorporate 1 km pixels, which are produced daily at 5-minute...

  8. MODIS/Terra Land Surface Temperature/Emissivity Monthly L3 Global 0.05Deg CMG V041

    Data.gov (United States)

    National Aeronautics and Space Administration — The MOD11C3.041 dataset was decommissioned as of March 1, 2018. Users are encouraged to use Version 6 of MODIS/Terra Land Surface Temperature and Emissivity Daily L3...

  9. MODIS/Aqua Land Surface Temperature/Emissivity 8-Day L3 Global 0.05Deg CMG V004

    Data.gov (United States)

    National Aeronautics and Space Administration — The MYD11C2.004 dataset was decommissioned as of October 20, 2017. Users are encouraged to use Version 6 of MODIS/Aqua Land Surface Temperature and Emissivity Daily...

  10. MODIS/Terra Land Surface Temperature/Emissivity 8-Day L3 Global 1km SIN Grid V005

    Data.gov (United States)

    National Aeronautics and Space Administration — The level-3 MODIS global Land Surface Temperature (LST) and Emissivity 8-day data are composed from the daily 1-kilometer LST product (MOD11A1) and stored on a...

  11. MODIS/Terra Land Surface Temperature/Emissivity Daily L3 Global 5km SIN Grid V041

    Data.gov (United States)

    National Aeronautics and Space Administration — The MOD11B1.041 dataset was decommissioned as of March 1, 2018. Users are encouraged to use Version 6 of MODIS/Terra Land Surface Temperature and Emissivity Daily L3...

  12. MODIS/Terra Land Surface Temperature/Emissivity Daily L3 Global 0.05Deg CMG V004

    Data.gov (United States)

    National Aeronautics and Space Administration — The MOD11C1.004 dataset was decommissioned as of October 19, 2017. Users are encouraged to use Version 6 of MODIS/Terra Land Surface Temperature and Emissivity Daily...

  13. MODIS/Terra Land Surface Temperature/Emissivity Daily L3 Global 0.05Deg CMG V041

    Data.gov (United States)

    National Aeronautics and Space Administration — The MOD11C1.041 dataset was decommissioned as of March 1, 2018. Users are encouraged to use Version 6 of MODIS/Terra Land Surface Temperature and Emissivity Daily L3...

  14. MODIS/Aqua Land Surface Temperature/Emissivity Daily L3 Global 0.05Deg CMG V004

    Data.gov (United States)

    National Aeronautics and Space Administration — The MYD11C1.004 dataset was decommissioned as of October 18, 2017. Users are encouraged to use Version 6 of MODIS/Aqua Land Surface Temperature and Emissivity Daily...

  15. MODIS/Terra Land Surface Temperature/Emissivity 5-Min L2 Swath 1km V041

    Data.gov (United States)

    National Aeronautics and Space Administration — The MOD11_L2.041 dataset was decommissioned as of October 30, 2017. Users are encouraged to use Version 6 of MODIS/Terra Land Surface Temperature and Emissivity...

  16. MODIS/Aqua Land Surface Temperature/Emissivity Daily L3 Global 0.05Deg CMG V041

    Data.gov (United States)

    National Aeronautics and Space Administration — The MYD11C1.041 dataset was decommissioned as of March 1, 2018. Users are encouraged to use Version 6 of MODIS/Aqua Land Surface Temperature and Emissivity Daily L3...

  17. MODIS/Aqua Near Real Time (NRT) Land Surface Temperature/Emissivity 5-Min L2 Swath 1km

    Data.gov (United States)

    National Aeronautics and Space Administration — The MODIS/Aqua Near Real Time (NRT) level-2 Land Surface Temperature and Emissivity (LST/E) data (Shortname: MYD11_L2) incorporate 1 km pixels, which are produced...

  18. MODIS/Aqua Land Surface Temperature/Emissivity Daily L3 Global 1km SIN Grid V004

    Data.gov (United States)

    National Aeronautics and Space Administration — The MYD11A1.004 dataset was decommissioned as of October 24, 2017. Users are encouraged to use Version 6 of MODIS/Aqua Land Surface Temperature and Emissivity Daily...

  19. MODIS/Terra Land Surface Temperature/Emissivity 5-Min L2 Swath 1km V006

    Data.gov (United States)

    National Aeronautics and Space Administration — The MOD11_L2 version 6 swath product provides per-pixel land surface temperature (LST) and emissivity. The product is produced daily in 5-minute temporal increments...

  20. MODIS/Terra Land Surface Temperature/Emissivity Daily L3 Global 5km SIN Grid V004

    Data.gov (United States)

    National Aeronautics and Space Administration — The MOD11B1.004 dataset was decommissioned as of October 23, 2017. Users are encouraged to use Version 6 of MODIS/Terra Land Surface Temperature and Emissivity Daily...

  1. MODIS/Aqua Land Surface Temperature/Emissivity 5-Min L2 Swath 1km V006

    Data.gov (United States)

    National Aeronautics and Space Administration — The MYD11_L2 version 6 swath product provides per-pixel land surface temperature (LST) and emissivity. The product is produced daily in 5-minute temporal increments...

  2. MODIS/Terra Land Surface Temperature/Emissivity Daily L3 Global 1km SIN Grid V004

    Data.gov (United States)

    National Aeronautics and Space Administration — The MOD11A1.004 dataset was decommissioned as of October 20, 2017. Users are encouraged to use Version 6 of MODIS/Terra Land Surface Temperature and Emissivity Daily...

  3. MODIS/Aqua Land Surface Temperature/Emissivity Monthly L3 Global 0.05Deg CMG V006

    Data.gov (United States)

    National Aeronautics and Space Administration — The MYD11C3 Version 6 product provides daily land surface temperature (LST) and emissivity values in a 0.05 (5600 m x 5600 m) degree latitude/longitude climate...

  4. Linking seasonal surface water dynamics with methane emissions and export from small, forested wetlands

    Science.gov (United States)

    Hondula, K. L.; Palmer, M.

    2017-12-01

    One of the biggest uncertainties about global methane sources and sinks is attributed to uncertainties regarding wetland area and its dynamics. This is exacerbated by confusion over the role of small, shallow water bodies like Delmarva bay wetlands that could be categorized as both wetlands and ponds. These small inland water bodies are often poorly quantified due to their size, closed forest canopies, and inter- and intra-annual variability in surface water extent. We are studying wetland-rich areas on the Delmarva Peninsula in the U.S. mid-Atlantic to address this uncertainty at the scale of individual wetland ecosystems (chamber measurements spanning from wetland center to upland, in order to quantify the areal extent of the methane emissions source area throughout seasonal changes in surface water inundation (water level 0 to > 1m depth). We estimated the size and temporal variability of the methane emissions source area by combining these measurements with daily estimates of the extent of surface water inundation derived from water level monitoring and a high-resolution digital elevation model. This knowledge is critical for informing land use decisions (e.g. restoring wetlands specifically for climate mitigation), the jurisdiction of environmental policies in the US, and for resolving major outstanding discrepancies in our understanding of the global methane budget.

  5. Local emission spectroscopy of surface micrograins in A{sup III}B{sup V} semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    Zhukov, N. D., E-mail: ndzhukov@rambler.ru; Gluhovskoy, E. G.; Mosiyash, D. S. [Saratov State University (Russian Federation)

    2016-07-15

    The density-of-states spectra and the parameters of levels of electron states in locally chosen surface micrograins of indium antimonide and arsenide and gallium arsenide are studied with a tunneling electron microscope in the field-emission mode of measurements. By correlating the current–voltage characteristics with the formula for the probability of emission via levels, the activation energies of the levels (ψ) and the lifetimes of electrons at the levels (τ) are determined. Two types of levels for electron localization are identified. These are levels in the micrograin bulk (ψ ≈ 0.75, 1.15, and 1.59 eV for n-InSb, n-InAs, and n-GaAs, respectively; τ ~ 10{sup –8}–10{sup –7} s) and in the surface region of an i-InSb micrograin (ψ ~ 0.73, 1.33, 1.85, 2.15, 5.1 eV; τ ≈ 5 × 10{sup –8}–3 × 10{sup –7} s). A physical model involving the Coulomb-interaction-induced localization of light electrons and their size quantization determined by the electron effective mass, energy, and concentration and by the surface curvature of the micrograin is proposed.

  6. Performance of the JULES land surface model for UK Biogenic VOC emissions

    Science.gov (United States)

    Hayman, Garry; Comyn-Platt, Edward; Vieno, Massimo; Langford, Ben

    2017-04-01

    Emissions of biogenic non-methane volatile organic compounds (NMVOCs) are important for air quality and tropospheric composition. Through their contribution to the production of tropospheric ozone and secondary organic aerosol (SOA), biogenic VOCs indirectly contribute to climate forcing and climate feedbacks [1]. Biogenic VOCs encompass a wide range of compounds and are produced by plants for growth, development, reproduction, defence and communication [2]. There are both biological and physico-chemical controls on emissions [3]. Only a few of the many biogenic VOCs are of wider interest and only two or three (isoprene and the monoterpenes, α- and β-pinene) are represented in chemical transport models. We use the Joint UK Land Environment Simulator (JULES), the UK community land surface model, to estimate biogenic VOC emission fluxes. JULES is a process-based model that describes the water, energy and carbon balances and includes temperature, moisture and carbon stores [4, 5]. JULES currently provides emission fluxes of the 4 largest groups of biogenic VOCs: isoprene, terpenes, methanol and acetone. The JULES isoprene scheme uses gross primary productivity (GPP), leaf internal carbon and the leaf temperature as a proxy for the electron requirement for isoprene synthesis [6]. In this study, we compare JULES biogenic VOC emission estimates of isoprene and terepenes with (a) flux measurements made at selected sites in the UK and Europe and (b) gridded estimates for the UK from the EMEP/EMEP4UK atmospheric chemical transport model [7, 8], using site-specific or EMEP4UK driving meteorological data, respectively. We compare the UK-scale emission estimates with literature estimates. We generally find good agreement in the comparisons but the estimates are sensitive to the choice of the base or reference emission potentials. References (1) Unger, 2014: Geophys. Res. Lett., 41, 8563, doi:10.1002/2014GL061616; (2) Laothawornkitkul et al., 2009: New Phytol., 183, 27, doi

  7. Sensitivity of coefficients for converting entrance surface dose and kerma-area product to effective dose and energy imparted to the patient

    International Nuclear Information System (INIS)

    Wise, K.N.; Sandborg, M.; Persliden, J.; Alm Carlsson, G.

    1999-01-01

    We investigate the sensitivity of the conversions from entrance surface dose (ESD) or kerma-area product (KAP) to effective dose (E) or to energy imparted to the patient (ε) to the likely variations in tube potential, field size, patient size and sex which occur in clinical work. As part of a factorial design study for chest and lumbar spine examinations, the tube potentials were varied to be ±10% of the typical values for the examinations while field sizes and the positions of the field centres were varied to be representative of values drawn from measurements on patient images. Variation over sex and patient size was based on anthropomorphic phantoms representing males and females of ages 15 years (small adult) and 21 years (reference adult). All the conversion coefficients were estimated using a mathematical phantom programmed with the Monte Carlo code EGS4 for all factor combinations and analysed statistically to derive factor effects. In general, the factors studied behaved independently in the sense that interaction of the physical factors generally gave no more than a 5% variation in a conversion coefficient. Taken together, variation of patient size, sex, field size and field position can lead to significant variation of E/KAP by up to a factor of 2, of E/ESD by up to a factor of 3, of ε/KAP by a factor of 1.3 and of ε/ESD by up to a factor of 2. While KAP is preferred to determine ε, the results show no strong preference of KAP over ESD in determining E. The mean absorbed dose D-bar in the patient obtained by dividing ε (determined using KAP) by the patient's mass was found to be the most robust measure of E. (author)

  8. Use of silver nanoparticles to enhance surface plasmon-coupled emission (SPCE)

    OpenAIRE

    Chowdhury, Mustafa H.; Ray, Krishanu; Geddes, Chris D.; Lakowicz, Joseph R.

    2008-01-01

    We report that self-assembled monolayers of colloidal silver nanoparticles can increase the intensity of the surface plasmon-coupled emission (SPCE) signal from sulforhodamine 101 (S101). The S101 was spin coated on a glass slide coated with a layer of continuous silver, and a silica layer upon which the nanoparticle layer was self-assembled. Of the various colloid sizes studied, the 40 nm colloids showed both the highest enhancements in the SPCE signal and the largest extent of plasmon coupl...

  9. X-ray emission in collisions of highly charged I, Pr, Ho, and Bi ions with a W surface

    International Nuclear Information System (INIS)

    Watanabe, H.; Tona, M.; Ohtani, S.; Sun, J.; Nakamura, N.; Yamada, C.; Yoshiyasu, N.; Sakurai, M.

    2007-01-01

    X-ray emission yields, which are defined as the total number of emitted x-ray photons per incident ion, and dissipated fractions of potential energies through x-ray emission have been measured for slow highly charged ions of I, Pr, Ho, and Bi colliding with a W surface. A larger amount of potential energy was consumed for the x-ray emission with increasing the atomic number and the charge state. The present measurements show that x-ray emission is one of the main decay channels of hollow atoms produced in collisions of very highly charged ions of heavy elements

  10. Effect of localized surface-plasmon mode on exciton transport and radiation emission in carbon nanotubes.

    Science.gov (United States)

    Roslyak, Oleksiy; Cherqui, Charles; Dunlap, David H; Piryatinski, Andrei

    2014-07-17

    We report on a general theoretical approach to study exciton transport and emission in a single-walled carbon nanotube (SWNT) in the presence of a localized surface-plasmon (SP) mode within a metal nanoparticle interacting via near-field coupling. We derive a set of quantum mechanical equations of motion and approximate rate equations that account for the exciton, SP, and the environmental degrees of freedom. The material equations are complemented by an expression for the radiated power that depends on the exciton and SP populations and coherences, allowing for an examination of the angular distribution of the emitted radiation that would be measured in experiment. Numerical simulations for a (6,5) SWNT and cone-shaped Ag metal tip (MT) have been performed using this methodology. Comparison with physical parameters shows that the near-field interaction between the exciton-SP occurs in a weak coupling regime, with the diffusion processes being much faster than the exciton-SP population exchange. In such a case, the effect of the exciton population transfer to the MT with its subsequent dissipation (i.e., the Förster energy transfer) is to modify the exciton steady state distribution while reducing the equilibration time for excitons to reach a steady sate distribution. We find that the radiation distribution is dominated by SP emission for a SWNT-MT separation of a few tens of nanometers due to the fast SP emission rate, whereas the exciton-SP coherences can cause its rotation.

  11. [Study on plasma temperature of a large area surface discharge by optical emission spectrum].

    Science.gov (United States)

    Dong, Li-Fang; Tong, Guo-Liang; Zhang, Yu; Zhou, Bin

    2014-04-01

    A large area surface discharge was realized in air/argon gas mixture by designing a discharge device with water electrodes. By using optical emission spectrum, the variations of the molecular vibrational temperature, the mean energy of electron, and the electronic excitation temperature as a function of the gas pressure were studied. The nitrogen molecular vibrational temperature was calculated according to the emission line of the second positive band system of the nitrogen molecule (C3 pi(u) --> B 3 pi(g)). The electronic excitation temperature was obtained by using the intensity ratio of Ar I 763.51 nm (2P(6) --> 1S(5)) to Ar I 772.42 nm (2P(2) --> 1S(3)). The changes in the mean energy of electron were studied by the relative intensity ratio of the nitrogen molecular ion 391.4 nm to nitrogen 337.1 nm. It was found that the intensity of emission spectral line increases with the increase in the gas pressure, meanwhile, the outline and the ratios of different spectral lines intensity also change. The molecular vibrational temperature, the mean energy of electron, and the electronic excitation temperature decrease as the gas pressure increases from 0.75 x 10(5) Pa to 1 x 10(5) Pa.

  12. An Anisotropic Ocean Surface Emissivity Model Based on WindSat Polarimetric Brightness Observations

    Science.gov (United States)

    Smith, D. F.; Gasiewski, A. J.; Sandeep, S.; Weber, B. L.

    2012-12-01

    The goal of this research has been to develop a standardized fast full-Stokes ocean surface emissivity model with Jacobian for a wind-driven ocean surface applicable at arbitrary microwave frequencies, polarizations, and incidence angles. The model is based on the Ohio State University (OSU) two-scale code for surface emission developed by Johnson (2006, IEEE TGRS, 44, 560) but modified as follows: (1) the Meissner-Wentz dielectric permittivity (2012, IEEE TGRS, 50, 3004) replaces the original permittivity, (2) the Elfouhaily sea surface spectrum (1997, JGR, 102, C7,15781) replaces the Durden-Vesecky spectrum (1985, IEEE TGRS, OE-10, 445), but the Durden-Vesecky angular spreading function is retained, (3) the high-frequency portion of the Elfouhaily spectrum is multiplied by the Pierson-Moskowitz shape spectrum to correct an error in the original paper, (4) the generalized Phillips-Kitaigorodskii equilibrium range parameter for short waves is modeled as a continuous function of the friction velocity at the water surface to eliminate a discontinuous jump in the original paper. A total of five physical tuning parameters were identified, including the spectral strength and the hydrodynamic modulation factor. The short wave part of the spectrum is also allowed to have an arbitrary ratio relative to the long wave part. The foam fraction is multiplied by a variable correction factor, and also modulated to allow an anisotropic foam fraction with more foam on the leeward side of a wave. The model is being tuned against multi-year sequences of WindSat and Special Sensor Microwave/Imager (SSMI) data as analyzed by Meissner and Wentz (2012, IEEE TGRS, 50, 3004) for up to four Stokes brightnesses and in all angular harmonics up to two in twenty five wind bins from 0.5-25.5 m/s and of 1 m/s width. As a result there are 40 brightnesses per wind bin, for a total of 1000 brightnesses used to constrain the modified model. A chi-squared tuning criterion based on error standard

  13. Effects of airflow and liquid temperature on ammonia mass transfer above an emission surface: Experimental study on emission rate

    DEFF Research Database (Denmark)

    Rong, Li; Nielsen, P V; Zhang, Guo-Qiang

    2009-01-01

    The present study performed a series of experiments in a wind tunnel to investigate the impact of velocity, turbulence intensity and liquid-air temperature difference on ammonia emission rates. Decreasing velocity, turbulence intensity and liquid temperature are shown to reduce the ammonia emission...... rates. The emission rates are more sensitive to the change of velocity at a low velocity compared to change of velocity at a higher velocity range, which corresponds with the conclusion that the boundary layer thickness of velocity increases sharply when velocity is changed from 0.2 m/s to 0.1 m....../s. In addition, the emission rates are more sensitive to the change of temperature at a higher temperature than at a lower liquid temperature range. The influence of velocity and liquid-air temperature difference on boundary layer thickness is also analyzed. The relationship between the emission rate...

  14. Sabine absorption coefficients to random incidence absorption coefficients

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2014-01-01

    into random incidence absorption coefficients for porous absorbers are investigated. Two optimization-based conversion methods are suggested: the surface impedance estimation for locally reacting absorbers and the flow resistivity estimation for extendedly reacting absorbers. The suggested conversion methods...

  15. The influence of surface stress on dislocation emission from sharp and blunt cracks in f.c.c. metals

    DEFF Research Database (Denmark)

    Schiøtz, Jakob

    2000-01-01

    with respect to the emission of a dislocation from the crack tip, whereas for all other metals studied the sharp crack is unstable. This result cannot be explained by existing criteria for the intrinsic ductile/brittle behaviour of crack tips, but is probably caused by surface stresses. When the crack...... is no longer atomically sharp dislocation emission becomes easier in all the studied metals. The effect is relatively strong; the critical stress intensity factor for emission to occur is reduced by up to 20%. This behaviour appears to be caused by the surface stress near the crack tip. The surface stress...... is a consequence of the many-body nature of the interatomic interactions. The enhanced dislocation emission can cause an order-of-magnitude increase in the fracture toughness of certain materials, in which a sharp crack would propagate by cleavage. Collisions with already existing dislocations will blunt the crack...

  16. Surprisingly small HONO emissions from snow surfaces at Browning Pass, Antarctica

    Directory of Open Access Journals (Sweden)

    H. J. Beine

    2006-01-01

    Full Text Available Measured Fluxes of nitrous acid at Browning Pass, Antarctica were very low, despite conditions that are generally understood as favorable for HONO emissions, including: acidic snow surfaces, an abundance of NO3- anions in the snow surface, and abundant UV light for NO3- photolysis. Photochemical modeling suggests noon time HONO fluxes of 5–10 nmol m-2 h-1; the measured fluxes, however, were close to zero throughout the campaign. The location and state of NO3- in snow is crucial to its reactivity. The analysis of soluble mineral ions in snow reveals that the NO3- ion is probably present in aged snows as NaNO3. This is peculiar to our study site, and we suggest that this may affect the photochemical reactivity of NO3-, by preventing the release of products, or providing a reactive medium for newly formed HONO. In fresh snow, the NO3- ion is probably present as dissolved or adsorbed HNO3 and yet, no HONO emissions were observed. We speculate that HONO formation from NO3- photolysis may involve electron transfer reactions of NO2 from photosensitized organics and that fresh snows at our site had insufficient concentrations of adequate organic compounds to favor this reaction.

  17. Interference effects in laser-induced plasma emission from surface-bound metal micro-particles.

    Science.gov (United States)

    Feigenbaum, Eyal; Malik, Omer; Rubenchik, Alexander M; Matthews, Manyalibo J

    2017-05-01

    The light-matter interaction of an optical beam and metal micro-particulates at the vicinity of an optical substrate surface is critical to the many fields of applied optics. Examples of impacted fields are laser-induced damage in high power laser systems, sub-wavelength laser machining of transmissive materials, and laser-target interaction in directed energy applications. We present a full-wave-based model that predicts the laser-induced plasma pressure exerted on a substrate surface as a result of light absorption in surface-bound micron-scale metal particles. The model predictions agree with experimental observation of laser-induced shallow pits, formed by plasma emission and etching from surface-bound metal micro-particulates. It provides an explanation for the prototypical side lobes observed along the pit profile, as well as for the dependence of the pit shape on the incident laser and particle parameters. Furthermore, the model highlights the significance of the interference of the incident light in the open cavity geometry formed between the micro-particle and the substrate in the resulting pit shape.

  18. Evaluation of the use of partition coefficients and molecular surface properties as predictors of drug absorption: a provisional biopharmaceutical classification of the list of national essential medi

    Directory of Open Access Journals (Sweden)

    NU Rahman

    2011-05-01

    Full Text Available Background and the purpose of the study: Partition coefficients (log D and log P and molecular surface area (PSA are potential predictors of the intestinal permeability of drugs. The aim of this investigation was to evaluate and compare these intestinal permeability indicators.   Methods: Aqueous solubility data were obtained from literature or calculated using ACD/Labs and ALOGPS. Permeability data were predicted based on log P, log D at pH 6.0 (log D6.0, and PSA.  Results: Metoprolol's log P, log D6.0 and a PSA of <65 Å correctly predicted 55.9%, 50.8% and 54.2% of permeability classes, respectively. Labetalol's log P, log D6.0, and PSA correctly predicted 54.2%, 64.4% and 61% of permeability classes, respectively. Log D6.0 correlated well (81% with Caco-2 permeability (Papp. Of the list of national essential medicines, 135 orally administered drugs were classified into biopharmaceutical classification system (BCS. Of these, 57 (42.2%, 28 (20.7%, 44 (32.6%, and 6 (4.4% were class I, II, III and IV respectively. Conclusion: Log D6.0 showed better prediction capability than log P. Metoprolol as permeability internal standard was more conservative than labetalol.

  19. A New Global Potential Energy Surface for the Hydroperoxyl Radical, HO2: Reaction Coefficients for H + O2 and Vibrational Splittings for H Atom Transfer

    Science.gov (United States)

    Dateo, Christopher E.; Arnold, James O. (Technical Monitor)

    1994-01-01

    A new analytic global potential energy surface describing the hydroperoxyl radical system H((sup 2)S) + O2(X (sup 3)Sigma((sup -)(sub g))) (reversible reaction) HO2 ((X-tilde) (sup 2)A'') (reversible reaction) O((sup 3)P) + O H (X (sup 2)Pi) has been fitted using the ab initio complete active space SCF (self-consistent-field)/externally contracted configuration interaction (CASSCF/CCI) energy calculations of Walch and Duchovic. Results of quasiclassical trajectory studies to determine the rate coefficients of the forward and reverse reactions at combustion temperatures will be presented. In addition, vibrational energy levels were calculated using the quantum DVR-DGB (discrete variable representation-distributed Gaussian basis) method and the splitting due to H atom migration is investigated. The material of the proposed presentation was reviewed and the technical content will not reveal any information not already in the public domain and will not give any foreign industry or government a competitive advantage.

  20. Fine Structure in the Secondary Electron Emission Peak for Diamond Crystal with (100) Negative Electron Affinity Surface

    Science.gov (United States)

    Asnin, V. M.; Krainsky, I. L.

    1998-01-01

    A fine structure was discovered in the low-energy peak of the secondary electron emission spectra of the diamond surface with negative electron affinity. We studied this structure for the (100) surface of the natural type-IIb diamond crystal. We have found that the low-energy peak consists of a total of four maxima. The relative energy positions of three of them could be related to the electron energy minima near the bottom of the conduction band. The fourth peak, having the lowest energy, was attributed to the breakup of the bulk exciton at the surface during the process of secondary electron emission.

  1. Explaining global surface aerosol number concentrations in terms of primary emissions and particle formation

    Directory of Open Access Journals (Sweden)

    D. V. Spracklen

    2010-05-01

    Full Text Available We synthesised observations of total particle number (CN concentration from 36 sites around the world. We found that annual mean CN concentrations are typically 300–2000 cm−3 in the marine boundary layer and free troposphere (FT and 1000–10 000 cm−3 in the continental boundary layer (BL. Many sites exhibit pronounced seasonality with summer time concentrations a factor of 2–10 greater than wintertime concentrations. We used these CN observations to evaluate primary and secondary sources of particle number in a global aerosol microphysics model. We found that emissions of primary particles can reasonably reproduce the spatial pattern of observed CN concentration (R2=0.46 but fail to explain the observed seasonal cycle (R2=0.1. The modeled CN concentration in the FT was biased low (normalised mean bias, NMB=−88% unless a secondary source of particles was included, for example from binary homogeneous nucleation of sulfuric acid and water (NMB=−25%. Simulated CN concentrations in the continental BL were also biased low (NMB=−74% unless the number emission of anthropogenic primary particles was increased or a mechanism that results in particle formation in the BL was included. We ran a number of simulations where we included an empirical BL nucleation mechanism either using the activation-type mechanism (nucleation rate, J, proportional to gas-phase sulfuric acid concentration to the power one or kinetic-type mechanism (J proportional to sulfuric acid to the power two with a range of nucleation coefficients. We found that the seasonal CN cycle observed at continental BL sites was better simulated by BL particle formation (R2=0.3 than by increasing the number emission from primary anthropogenic sources (R2=0.18. The nucleation constants that resulted in best overall match between model and observed CN concentrations were

  2. Excimer emission properties on pyrene-labeled protein surface: correlation between emission spectra, ring stacking modes, and flexibilities of pyrene probes.

    Science.gov (United States)

    Fujii, Akira; Sekiguchi, Yutaka; Matsumura, Hiroyoshi; Inoue, Tsuyoshi; Chung, Wen-Sheng; Hirota, Shun; Matsuo, Takashi

    2015-03-18

    The excimer emission of pyrene is popularly employed for investigating the association between pyrene-labeled biomolecules or between pyrene-labeled places in a biomolecule. The property of pyrene excimer emission is affected by the fluctuation in ring stacking modes, which originates from the structural flexibilities of pyrene probes and/or of labeled places. Investigations of the excimer emission in terms of dynamics of pyrene stacking modes provide the detailed spatial information between pyrene-labeled places. In order to evaluate the effects of probe structures and fluctuation in pyrene-pyrene association modes on their emission properties on protein surface, three types of pyrene probe with different linker lengths were synthesized and conjugated to two cysteine residues in the A55C/C77S/V169C mutant of adenylate kinase (Adk), an enzyme that shows a structural transition between OPEN and CLOSED forms. In the CLOSED form of Adk labeled by a pyrene probe with a short linker, excimer emission was found to be predominated by the ground-state association of pyrenes. The pyrene stacking structure on the protein surface was successfully determined by an X-ray crystallographic analysis. However, the emission decay in the protein suggested the existence of several stacking orientations in solution. With the increase in the linker length, the effect of fluctuation in pyrene association modes on the spectral properties distinctly emerged at both ground and excited states. The combination of steady-state and time-resolved spectroscopic analyses is useful for differentiation in the origin of the excimer emission, which is essential for precisely understanding the interaction fashions between pyrene-labeled biomolecules.

  3. Fate factors and emission flux estimates for emerging contaminants in surface waters

    Directory of Open Access Journals (Sweden)

    Hoa T. Trinh

    2016-01-01

    Full Text Available Pharmaceuticals, personal care products, hormones, and wastewater products are emerging environmental concerns for manifold reasons, including the potential of some compounds found in these products for endocrine disruption at a very low chronic exposure level. The environmental occurrences and sources of these contaminants in the water, soil, sediment and biota in European nations and the United States are well documented. This work reports a screening-level emission and fate assessment of thirty compounds, listed in the National Reconnaissance of the United States Geological Survey (USGS, 1999–2000 as the most frequently detected organic wastewater contaminants in U.S. streams and rivers. Estimations of the surface water fate factors were based on Level II and Level III multimedia fugacity models for a 1000 km2 model environment, the size of a typical county in the eastern United States. The compounds are categorized into three groups based upon the sensitivity of their predicted surface water fate factors to uncertainties in their physicochemical property values and the landscape parameters. The environmental fate factors, mass distributions, and loss pathways of all of the compounds are strongly affected by their assumed modes of entry into the environment. It is observed that for thirteen of the thirty organic wastewater contaminants most commonly detected in surface waters, conventional treatment strategies may be ineffective for their removal from wastewater effluents. The surface water fate factors predicted by the fugacity models were used in conjunction with the surface water concentrations measured in the USGS reconnaissance to obtain emission flux estimates for the compounds into U.S. streams and rivers. These include estimated fluxes of 6.8 × 10−5 to 0.30 kg/h km2 for the biomarker coprostanol; 1.7 × 10−5 to 6.5 × 10−5 kg/h km2 for the insect repellent N,N-diethyltoluamide; and 4.3 × 10−6 to 3.1 × 10−5 kg/h km2 for

  4. Emission spectroscopic analysis of oxygen-plasma reaction on polymer surface: Effective polyacrylonitrile treatment by the plasma

    International Nuclear Information System (INIS)

    Kobayashi, Takaomi; Sasama, Tomonori; Wada, Hiroshi; Fujii, Nobuyuki

    2001-01-01

    Emission spectroscopy was applied to observe decomposed species of polyacrylonitrile (PAN) exposed with oxygen (O 2 ) plasma, which was generated by microwave discharge with 8x10 -2 dm 3 /s flow rate in the range of 1.8-4.7 Torr. As O 2 plasma was exposed to the polymer, the surface was etched and a violet emission was observed on the surface. The strong emission assigned to CN(B 2 Σ-X 2 Π) transition appeared near 340-460 nm and also CH(A 2 Δ-X 2 Π) at 431 nm. These results indicated that the PAN sample was decomposed by the plasma etching and the decomposed species emitted the violet light on the surface. The time dependence of the emission intensities was also investigated. When the discharge time of O 2 plasma increased, the emission intensities of the CN and CH transitions increased and then gradually decreased. Evidence was presented by infrared measurements that a hetrocyclic nitrile group was formed on the treated surface. Furthermore, the polymer surface decomposition in O 2 plasma was compared with that observed in nitrogen (N 2 ) and air plasma. The N 2 and air discharge showed less PAN decomposition than observed in O 2 discharge

  5. Microwave emission measurements of sea surface roughness, soil moisture, and sea ice structure

    Science.gov (United States)

    Gloersen, P.; Wilheit, T. T.; Schmugge, T. J.

    1972-01-01

    In order to demonstrate the feasibility of the microwave radiometers to be carried aboard the Nimbus 5 and 6 satellites and proposed for one of the earth observatory satellites, remote measurements of microwave radiation at wavelengths ranging from 0.8 to 21 cm have been made of a variety of the earth's surfaces from the NASA CV-990 A/C. Brightness temperatures of sea water surfaces of varying roughness, of terrain with varying soil moisture, and of sea ice of varying structure were observed. In each case, around truth information was available for correlation with the microwave brightness temperature. The utility of passive microwave radiometry in determining ocean surface wind speeds, at least for values higher than 7 meters/second has been demonstrated. In addition, it was shown that radiometric signatures can be used to determine soil moisture in unvegetated terrain to within five percentage points by weight. Finally, it was demonstrated that first year thick, multi-year, and first year thin sea ice can be distinguished by observing their differing microwave emissivities at various wavelengths.

  6. Radiative forcing from aircraft emissions of NOx: model calculations with CH4 surface flux boundary condition

    Directory of Open Access Journals (Sweden)

    Giovanni Pitari

    2017-12-01

    Full Text Available Two independent chemistry-transport models with troposphere-stratosphere coupling are used to quantify the different components of the radiative forcing (RF from aircraft emissions of NOx, i.e., the University of L'Aquila climate-chemistry model (ULAQ-CCM and the University of Oslo chemistry-transport model (Oslo-CTM3. The tropospheric NOx enhancement due to aircraft emissions produces a short-term O3 increase with a positive RF (+17.3 mW/m2 (as an average value of the two models. This is partly compensated by the CH4 decrease due to the OH enhancement (−9.4 mW/m2. The latter is a long-term response calculated using a surface CH4 flux boundary condition (FBC, with at least 50 years needed for the atmospheric CH4 to reach steady state. The radiative balance is also affected by the decreasing amount of CO2 produced at the end of the CH4 oxidation chain: an average CO2 accumulation change of −2.2 ppbv/yr is calculated on a 50 year time horizon (−1.6 mW/m2. The aviation perturbed amount of CH4 induces a long-term response of tropospheric O3 mostly due to less HO2 and CH3O2 being available for O3 production, compared with the reference case where a constant CH4 surface mixing ratio boundary condition is used (MBC (−3.9 mW/m2. The CH4 decrease induces a long-term response of stratospheric H2O (−1.4 mW/m2. The latter finally perturbs HOx and NOx in the stratosphere, with a more efficient NOx cycle for mid-stratospheric O3 depletion and a decreased O3 production from HO2+NO in the lower stratosphere. This produces a long-term stratospheric O3 loss, with a negative RF (−1.2 mW/m2, compared with the CH4 MBC case. Other contributions to the net NOx RF are those due to NO2 absorption of UV-A and aerosol perturbations (the latter calculated only in the ULAQ-CCM. These comprise: increasing sulfate due to more efficient oxidation of SO2, increasing inorganic and organic nitrates and the net aerosols indirect effect on warm clouds

  7. Largely enhanced near band edge emission of ultrathin zinc oxide nanowire/gold nanoparticles composites by surface plasmon resonance

    Science.gov (United States)

    Li, Lei; Wang, Chenying; Han, Feng; Yang, Shuming; Jing, Weixuan; Jiang, Zhuangde

    2018-03-01

    Ultrathin zinc oxide nanowires with diameter less than 50 nm were synthesized by polyethyleneimine assisted solution method. Zinc oxide nanowire near band edge emission was enhanced obviously by gold nanoparticles coating, and a max 26 times enhancement was realized. The defects caused visible light emission was also quenched to noise level when gold was deposited more than 10 s. The large near band edge emission enhancement was caused by surface plasmon resonance mediated luminescent energy transfer, which absorbed the visible light energy and transferred to the near band edge emission. The large surface to volume ratio enhanced the coupling strength between gold nanoparticles and ultrathin zinc oxide nanowires. This research provide a method to improve the luminescent efficiency of zinc oxide nanowires.

  8. Synergistic impacts of anthropogenic and biogenic emissions on summer surface O3 in East Asia.

    Science.gov (United States)

    Qu, Yu; An, Junling; Li, Jian

    2013-03-01

    A factor separation technique and an improved regional air quality model (RAQM) were applied to calculate synergistic contributions of anthropogenic volatile organic compounds (AVOCs), biogenic volatile organic compounds (BVOCs) and nitrogen oxides (NOx) to daily maximum surface 03 (O3DM) concentrations in East Asia in summer (June to August 2000). The summer averaged synergistic impacts of AVOCs and NOx are dominant in most areas of North China, with a maximum of 60 ppbv, while those of BVOCs and NOx are notable only in some limited areas with high BVOC emissions in South China, with a maximum of 25 ppbv. This result implies that BVOCs contribute much less to summer averaged O3DM concentrations than AVOCs in most areas of East Asia at a coarse spatial resolution (1 degree x 1 degree) although global emissions of BVOCs are much greater than those of AVOCs. Daily maximum total contributions of BVOCs can approach 20 ppbv in North China, but they can reach 40 ppbv in South China, approaching or exceeding those in some developed countries in Europe and North America. BVOC emissions in such special areas should be considered when 03 control measures are taken. Synergistic contributions among AVOCs, BVOCs and NOx significantly enhance O3 concentrations in the Beijing-Tianjin-Tangshan region and decrease them in some areas in South China. Thus, the total contributions of BVOCs to O3DM vary significantly from day to day and from location to location. This result suggests that 03 control measures obtained from episodic studies could be limited for long-term applications.

  9. The role of electron induced secondary electron emission from SiO2 surfaces in capacitively coupled radio frequency plasmas operated at low pressures

    Science.gov (United States)

    Horváth, B.; Daksha, M.; Korolov, I.; Derzsi, A.; Schulze, J.

    2017-12-01

    The effects of electron induced secondary electron (SE) emission from SiO2 electrodes in single-frequency capacitively coupled plasmas (CCPs) are studied by particle-in-cell/Monte Carlo collisions (PIC/MCC) simulations in argon gas at 0.5 Pa for different voltage amplitudes. Unlike conventional simulations, we use a realistic model for the description of electron-surface interactions, which takes into account the elastic reflection and the inelastic backscattering of electrons, as well as the emission of electron induced SEs (δ-electrons). The emission coefficients corresponding to these elementary processes are determined as a function of the electron energy and angle of incidence, taking the properties of the surface into account. Compared to the results obtained by using a simplified model for the electron-surface interaction, widely used in PIC/MCC simulations of CCPs, which includes only elastic electron reflection at a constant probability of 0.2, strongly different electron power absorption and ionization dynamics are observed. We find that ion induced SEs (γ-electrons) emitted at one electrode and accelerated to high energies by the local sheath electric field propagate through the plasma almost collisionlessly and impinge on the opposing sheath within a few nanoseconds. Depending on the instantaneous local sheath voltage these energetic electrons are either reflected by the sheath electric field or they hit the electrode surface, where each γ-electron can generate multiple δ-electrons upon impact. These electron induced SEs are accelerated back into the plasma by the momentary sheath electric field and can again generate δ-electrons at the opposite electrode after propagating through the plasma bulk. Overall, a complex dynamics of γ- and δ-electrons is observed including multiple reflections between the boundary sheaths. At high voltages, the electron induced SE emission is found to strongly affect the plasma density and the ionization dynamics and

  10. Localized-Surface-Plasmon Enhanced the 357 nm Forward Emission from ZnMgO Films Capped by Pt Nanoparticles

    Directory of Open Access Journals (Sweden)

    Song XM

    2009-01-01

    Full Text Available Abstract The Pt nanoparticles (NPs, which posses the wider tunable localized-surface-plasmon (LSP energy varying from deep ultraviolet to visible region depending on their morphology, were prepared by annealing Pt thin films with different initial mass-thicknesses. A sixfold enhancement of the 357 nm forward emission of ZnMgO was observed after capping with Pt NPs, which is due to the resonance coupling between the LSP of Pt NPs and the band-gap emission of ZnMgO. The other factors affecting the ultraviolet emission of ZnMgO, such as emission from Pt itself and light multi-scattering at the interface, were also discussed. These results indicate that Pt NPs can be used to enhance the ultraviolet emission through the LSP coupling for various wide band-gap semiconductors.

  11. Surface structures for enhancement of quantum yield in broad spectrum emission nanocrystals

    Science.gov (United States)

    Schreuder, Michael A.; McBride, James R.; Rosenthal, Sandra J.

    2014-07-22

    Disclosed are inorganic nanoparticles comprising a body comprising cadmium and/or zinc crystallized with selenium, sulfur, and/or tellurium; a multiplicity of phosphonic acid ligands comprising at least about 20% of the total surface ligand coverage; wherein the nanocrystal is capable of absorbing energy from a first electromagnetic region and capable of emitting light in a second electromagnetic region, wherein the maximum absorbance wavelength of the first electromagnetic region is different from the maximum emission wavelength of the second electromagnetic region, thereby providing a Stokes shift of at least about 20 nm, wherein the second electromagnetic region comprises an at least about 100 nm wide band of wavelengths, and wherein the nanoparticle exhibits has a quantum yield of at least about 10%. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

  12. Soil surface Hg emission flux in coalfield in Wuda, Inner Mongolia, China.

    Science.gov (United States)

    Li, Chunhui; Liang, Handong; Liang, Ming; Chen, Yang; Zhou, Yi

    2018-03-30

    Hg emission flux from various land covers, such as forests, wetlands, and urban areas, have been investigated. China has the largest area of coalfield in the world, but data of Hg flux of coalfields, especially, those with coal fires, are seriously limited. In this study, Hg fluxes of a coalfield were measured using the dynamic flux chamber (DFC) method, coupled with a Lumex multifunctional Hg analyzer RA-915+ (Lumex Ltd., Russia). The results show that the Hg flux in Wuda coalfield ranged from 4 to 318 ng m -2  h -1 , and the average value for different areas varied, e.g., coal-fire area 99 and 177 ng m -2  h -1 ; no coal-fire area 19 and 32 ng m -2  h -1 ; and backfilling area 53 ng m -2  h -1 . Hg continued to be emitted from an underground coal seam, even if there were no phenomena, such as vents, cracks, and smog, of coal fire on the soil surface. This phenomenon occurred in all area types, i.e., coal-fire area, no coal-fire area, and backfilling area, which is universal in Wuda coalfield. Considering that many coalfields in northern China are similar to Wuda coalfield, they may be large sources of atmospheric Hg. The correlations of Hg emission flux with influence factors, such as sunlight intensity, soil surface temperature, and atmospheric Hg content, were also investigated for Wuda coalfield. Graphical abstract ᅟ.

  13. Effect of surface application of ammonium thiosulfate on field-scale emissions of 1,3-dichloropropene.

    Science.gov (United States)

    Yates, S R; Ashworth, D J; Zhang, Q

    2017-02-15

    Soil fumigation is important for food production but has the potential to discharge toxic chemicals into the environment, which may adversely affect human and ecosystem health. A field experiment was conducted to evaluate the effect of applying ammonium thiosulfate fertilizer to the soil surface prior to fumigating with 1,3-dichloropropene (1,3-D). The ammonium thiosulfate solution was applied as a spray with minimal water to minimize the effect on emissions from saturating (e.g. sealing) the soil pores with water. Two independent data sets were collected for determining the emission rate. One data set was used with three micrometeorological approaches: aerodynamic, integrated horizontal flux and theoretical profile shape; the other dataset with two indirect, back calculation methods that used the CALPUFF and ISCST3 dispersion models. Using the five methodologies, the 1,3-D emission rate was obtained for 16days. The maximum emission rates ranged from 7 to 20μgm -2 s -1 , the maximum 24-hour averaged emission rates ranged from 5 to 13μgm -2 s -1 , and the total 1,3-D emissions ranged from 12 to 26%. Comparing to fumigation without ammonium thiosulfate spray revealed that emissions were reduced from 3% (CALPUFF) to 29% (ADM). Using a simulation model, ammonium thiosulfate spray would be expected to reduce emissions by almost 21%. These data provide evidence that emissions of 1,3-D can be reduced by spraying ammonium thiosulfate fertilizer on the soil surface prior to soil fumigation, and provides another emission-reduction strategy to those recently reported (e.g., deep injection, water seals and organic amendments). Published by Elsevier B.V.

  14. Force Field Benchmark of Organic Liquids: Density, Enthalpy of Vaporization, Heat Capacities, Surface Tension, Isothermal Compressibility, Volumetric Expansion Coefficient, and Dielectric Constant.

    Science.gov (United States)

    Caleman, Carl; van Maaren, Paul J; Hong, Minyan; Hub, Jochen S; Costa, Luciano T; van der Spoel, David

    2012-01-10

    The chemical composition of small organic molecules is often very similar to amino acid side chains or the bases in nucleic acids, and hence there is no a priori reason why a molecular mechanics force field could not describe both organic liquids and biomolecules with a single parameter set. Here, we devise a benchmark for force fields in order to test the ability of existing force fields to reproduce some key properties of organic liquids, namely, the density, enthalpy of vaporization, the surface tension, the heat capacity at constant volume and pressure, the isothermal compressibility, the volumetric expansion coefficient, and the static dielectric constant. Well over 1200 experimental measurements were used for comparison to the simulations of 146 organic liquids. Novel polynomial interpolations of the dielectric constant (32 molecules), heat capacity at constant pressure (three molecules), and the isothermal compressibility (53 molecules) as a function of the temperature have been made, based on experimental data, in order to be able to compare simulation results to them. To compute the heat capacities, we applied the two phase thermodynamics method (Lin et al. J. Chem. Phys.2003, 119, 11792), which allows one to compute thermodynamic properties on the basis of the density of states as derived from the velocity autocorrelation function. The method is implemented in a new utility within the GROMACS molecular simulation package, named g_dos, and a detailed exposé of the underlying equations is presented. The purpose of this work is to establish the state of the art of two popular force fields, OPLS/AA (all-atom optimized potential for liquid simulation) and GAFF (generalized Amber force field), to find common bottlenecks, i.e., particularly difficult molecules, and to serve as a reference point for future force field development. To make for a fair playing field, all molecules were evaluated with the same parameter settings, such as thermostats and barostats

  15. A physics-based algorithm for retrieving land-surface emissivity and temperature from EOS/MODIS data

    International Nuclear Information System (INIS)

    Wan, Z.; Li, Z.L.

    1997-01-01

    The authors have developed a physics-based land-surface temperature (LST) algorithm for simultaneously retrieving surface band-averaged emissivities and temperatures from day/night pairs of MODIS (Moderate Resolution Imaging Spectroradiometer) data in seven thermal infrared bands. The set of 14 nonlinear equations in the algorithm is solved with the statistical regression method and the least-squares fit method. This new LST algorithm was tested with simulated MODIS data for 80 sets of band-averaged emissivities calculated from published spectral data of terrestrial materials in wide ranges of atmospheric and surface temperature conditions. Comprehensive sensitivity and error analysis has been made to evaluate the performance of the new LST algorithm and its dependence on variations in surface emissivity and temperature, upon atmospheric conditions, as well as the noise-equivalent temperature difference (NEΔT) and calibration accuracy specifications of the MODIS instrument. In cases with a systematic calibration error of 0.5%, the standard deviations of errors in retrieved surface daytime and nighttime temperatures fall between 0.4--0.5 K over a wide range of surface temperatures for mid-latitude summer conditions. The standard deviations of errors in retrieved emissivities in bands 31 and 32 (in the 10--12.5 microm IR spectral window region) are 0.009, and the maximum error in retrieved LST values falls between 2--3 K

  16. The Role of Meteorology and Surface Condition to Multi-Decadal Variations of Dust Emission in Sahara and Sahel

    Science.gov (United States)

    Kim, D.; Chin, M.; Diehl, T. L.; Bian, H.; Brown, M. E.; Remer, L. A.; Stockwell, W. R.

    2014-12-01

    North Africa is the world's largest dust source region influencing regional and global climate, human health, and even the local economy. However North Africa as a dust source is not uniform but it consists of the arid region (Sahara) and the semi-arid region (Sahel) with emission rates depending on meteorological and surface conditions. Several recent studies have shown that dust from North Africa seems to have a decreasing trend in the past three decades. The goal of this study is to better understand the controlling factors that determine the change of dust in North Africa using observational data and model simulations. First we analyze surface bareness conditions determined from a long-term satellite observed Normalized Difference Vegetation Index for 1980-2008. Then we examine the key meteorological variables of precipitation and surface winds. Modeling experiments were conducted using the NASA Goddard Chemistry Aerosol Radiation and Transport (GOCART) model, which has been recently updated with a dynamic dust source function. Using the method we separate the dust originating from the Sahel from that of the Sahara desert. We find that the surface wind speed is the most dominant factor affecting Sahelian dust emission while vegetation has a modulating effect. We will show regional differences in meteorological variables, surface conditions, dust emission, and dust distribution and address the relationships among meteorology, surface conditions, and dust emission/loading in the past three decades (1980-2008).

  17. Rear surface light emission measurements from laser-produced shock waves in clear and Al-coated polystyrene targets

    Science.gov (United States)

    McLean, E. A.; Deniz, A. V.; Schmitt, A. J.; Stamper, J. A.; Obenschain, S. P.; Lehecka, T.; Mostovych, A. N.; Seely, J.

    1999-08-01

    The Nike KrF laser, with its very uniform focal distributions, has been used at intensities near 10 14 W/cm 2 to launch shock waves in polystyrene targets. The rear surface visible light emission differed between clear polystyrene (CH) targets and targets with a thin (125 nm) Al coating on the rear side. The uncoated CH targets showed a relatively slowly rising emission followed by a sudden fall when the shock emerges, while the Al-coated targets showed a rapid rise in emission when the shock emerges followed by a slower fall, allowing an unambiguous determination of the time the shock arrived at the rear surface. A half-aluminized target allowed us to observe this difference in a single shot. The brightness temperature of both the aluminized targets and the non-aluminized targets was slightly below but close to rear surface temperature predictions of a hydrodynamic code. A discussion of preheat effects is given.

  18. Staircase and saw-tooth field emission steps from nanopatterned n-type GaSb surfaces

    CERN Document Server

    Kildemo, M.; Le Roy, S.; Søndergård, E.

    2009-01-01

    High resolution field emission experiments from nanopatterned GaSb surfaces consisting of densely packed nanocones prepared by low ion-beam-energy sputtering are presented. Both uncovered and metal-covered nanopatterned surfaces were studied. Surprisingly, the field emission takes place by regular steps in the field emitted current. Depending on the field, the steps are either regular, flat, plateaus, or saw-tooth shaped. To the author’s knowledge, this is the first time that such results have been reported. Each discrete jump in the field emission may be understood in terms of resonant tunneling through an extended surface space charge region in an n-type, high aspect ratio, single GaSb nanocone. The staircase shape may be understood from the spatial distribution of the aspect ratio of the cones.

  19. Atom-specific look at the surface chemical bond using x-ray emission spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Nilsson, A.; Wassdahl, N.; Weinelt, M. [Uppsala Univ. (Sweden)] [and others

    1997-04-01

    CO and N{sub 2} adsorbed on the late transition metals have become prototype systems regarding the general understanding of molecular adsorption. It is in general assumed that the bonding of molecules to transition metals can be explained in terms of the interaction of the frontier HOMO and LUMO molecular orbitals with the d-orbitals. In such a picture the other molecular orbitals should remain essentially the same as in the free molecule. For the adsorption of the isoelectronic molecules CO and N{sub 2} this has led to the so called Blyholder model i.e., a synergetic {sigma} (HOMO) donor and {pi} (LUMO) backdonation bond. The authors results at the ALS show that such a picture is oversimplified. The direct observation and identification of the states related to the surface chemical bond is an experimental challenge. For noble and transition metal surfaces, the adsorption induced states overlap with the metal d valence band. Their signature is therefore often obscured by bulk substrate states. This complication has made it difficult for techniques such as photoemission and inverse photoemission to provide reliable information on the energy of chemisorption induced states and has left questions unanswered regarding the validity of the frontier orbitals concept. Here the authors show how x-ray emission spectroscopy (XES), in spite of its inherent bulk sensitivity, can be used to investigate adsorbed molecules. Due to the localization of the core-excited intermediate state, XE spectroscopy allows an atomic specific separation of the valence electronic states. Thus the molecular contributions to the surface measurements make it possible to determine the symmetry of the molecular states, i.e., the separation of {pi} and {sigma} type states. In all the authors can obtain an atomic view of the electronic states involved in the formation of the chemical bond to the surface.

  20. Solution of underground mine gas emissions on surface of abandoned mining sites where steep deposited coal seams have been exploited

    Energy Technology Data Exchange (ETDEWEB)

    Takla, G.; Froml, K. [OKD, DPB, Paskov (Czech Republic)

    2005-07-01

    The solution of uncontrolled gas emissions from abandoned underground coal mine sites in Ostrava-Karvina coal-field to surface ground in connection with old mine shafts and drifts and with old mining workings in horizontal and inclined coal seams has many forms. It varies according to geological and mining conditions and the disposition of the site surface. Since four years the gas emission risk has appeared in the area of former exploited vertical coal seams within the historical centre of Orlova town, which is protected by State Monument Protection office. A project based on such special nature of mining-geological and urban conditions was elaborated and already implemented. (authors)

  1. Solution of underground mine gas emissions on surface of abandoned mining sites where steep deposited coal seams have been exploited

    International Nuclear Information System (INIS)

    Takla, G.; Froml, K.

    2005-01-01

    The solution of uncontrolled gas emissions from abandoned underground coal mine sites in Ostrava-Karvina coal-field to surface ground in connection with old mine shafts and drifts and with old mining workings in horizontal and inclined coal seams has many forms. It varies according to geological and mining conditions and the disposition of the site surface. Since four years the gas emission risk has appeared in the area of former exploited vertical coal seams within the historical centre of Orlova town, which is protected by State Monument Protection office. A project based on such special nature of mining-geological and urban conditions was elaborated and already implemented. (authors)

  2. Ag-protein plasmonic architectures for surface plasmon-coupled emission enhancements and Fabry-Perot mode-coupled directional fluorescence emission

    Science.gov (United States)

    Badiya, Pradeep Kumar; Patnaik, Sai Gourang; Srinivasan, Venkatesh; Reddy, Narendra; Manohar, Chelli Sai; Vedarajan, Raman; Mastumi, Noriyoshi; Belliraj, Siva Kumar; Ramamurthy, Sai Sathish

    2017-10-01

    We report the use of silver decorated plant proteins as spacer material for augmented surface plasmon-coupled emission (120-fold enhancement) and plasmon-enhanced Raman scattering. We extracted several proteins from different plant sources [Triticum aestivum (TA), Aegle marmelos (AM), Ricinus communis (RC), Jatropha curcas (JC) and Simarouba glauca (SG)] followed by evaluation of their optical properties and simulations to rationalize observed surface plasmon resonance. Since the properties exhibited by protein thin films is currently gaining research interest, we have also carried out simulation studies with Ag-protein biocomposites as spacer materials in metal-dielectric-metal planar microcavity architecture for guided emission of Fabry-Perot mode-coupled fluorescence.

  3. Analytical modelling of acoustic emission from buried or surface-breaking cracks under stress

    International Nuclear Information System (INIS)

    Ben Khalifa, W; Jezzine, K; Hello, G; Grondel, S

    2012-01-01

    Acoustic emission (AE) is a non-destructive testing method used in various industries (aerospace, petrochemical and pressure-vessel industries in general, power generation, civil engineering, mechanical engineering, etc...) for the examination of large structures subjected to various stresses (e.g. mechanical loading).The energy released by a defect under stress (the AE phenomenon) can propagate as guided waves in thin structures or as surface Rayleigh waves in thick ones. Sensors (possibly permanently) are positioned at various locations on the structure under examination and are assumed to be sensitive to these waves. Then, post-processing tools typically based on signal processing and triangulation algorithms can be used to inverse these data, allowing one to estimate the position of the defect from which emanates the waves measured. The French Atomic Energy Commission is engaged in the development of tools for simulating AE examinations. These tools are based on specific models for the AE sources, for the propagation of guided or Rayleigh waves and for the behaviour of AE sensors. Here, the coupling of a fracture mechanics based model for AE source and surface/guided wave propagation models is achieved through an integral formulation relying on the elastodynamic reciprocity principle. As a first approximation, a simple piston-like model is used to predict the sensitivity of AE sensors. Predictions computed by our simulation tool are compared to results from the literature for validation purpose.

  4. Transition process leading to microbubble emission boiling on horizontal circular heated surface in subcooled pool

    Science.gov (United States)

    Ueno, Ichiro; Ando, Jun; Horiuchi, Kazuna; Saiki, Takahito; Kaneko, Toshihiro

    2016-11-01

    Microbubble emission boiling (MEB) produces a higher heat flux than critical heat flux (CHF) and therefore has been investigated in terms of its heat transfer characteristics as well as the conditions under which MEB occurs. Its physical mechanism, however, is not yet clearly understood. We carried out a series of experiments to examine boiling on horizontal circular heated surfaces of 5 mm and of 10 mm in diameter, in a subcooled pool, paying close attention to the transition process to MEB. High-speed observation results show that, in the MEB regime, the growth, condensation, and collapse of the vapor bubbles occur within a very short time. In addition, a number of fine bubbles are emitted from the collapse of the vapor bubbles. By tracking these tiny bubbles, we clearly visualize that the collapse of the vapor bubbles drives the liquid near the bubbles towards the heated surface, such that the convection field around the vapor bubbles under MEB significantly differs from that under nucleate boiling. Moreover, the axial temperature gradient in a heated block (quasi-heat flux) indicates a clear difference between nucleate boiling and MEB. A combination of quasi-heat flux and the measurement of the behavior of the vapor bubbles allows us to discuss the transition to MEB. This work was financially supported by the 45th Research Grant in Natural Sciences from The Mitsubishi Foundation (2014 - 2015), and by Research Grant for Boiler and Pressurized Vessels from The Japan Boiler Association (2016).

  5. A Consistent Treatment of Microwave Emissivity and Radar Backscatter for Retrieval of Precipitation over Water Surfaces

    Science.gov (United States)

    Munchak, S. Joseph; Meneghini, Robert; Grecu, Mircea; Olson, William S.

    2016-01-01

    The Global Precipitation Measurement satellite's Microwave Imager (GMI) and Dual-frequency Precipitation Radar (DPR) are designed to provide the most accurate instantaneous precipitation estimates currently available from space. The GPM Combined Algorithm (CORRA) plays a key role in this process by retrieving precipitation profiles that are consistent with GMI and DPR measurements; therefore, it is desirable that the forward models in CORRA use the same geophysical input parameters. This study explores the feasibility of using internally consistent emissivity and surface backscatter cross-sectional (sigma(sub 0)) models for water surfaces in CORRA. An empirical model for DPR Ku and Ka sigma(sub 0) as a function of 10m wind speed and incidence angle is derived from GMI-only wind retrievals under clear-sky conditions. This allows for the sigma(sub 0) measurements, which are also influenced by path-integrated attenuation (PIA) from precipitation, to be used as input to CORRA and for wind speed to be retrieved as output. Comparisons to buoy data give a wind rmse of 3.7 m/s for Ku+GMI and 3.2 m/s for Ku+Ka+GMI retrievals under precipitation (compared to 1.3 m/s for clear-sky GMI-only), and there is a reduction in bias from GANAL background data (-10%) to the Ku+GMI (-3%) and Ku+Ka+GMI (-5%) retrievals. Ku+GMI retrievals of precipitation increase slightly in light (less than 1 mm/h) and decrease in moderate to heavy precipitation (greater than 1 mm/h). The Ku+Ka+GMI retrievals, being additionally constrained by the Ka reflectivity, increase only slightly in moderate and heavy precipitation at low wind speeds (less than 5 m/s) relative to retrievals using the surface reference estimate of PIA as input.

  6. The Use of Satellite Data to Relate Waterbody Surface Area and Temperature to Greenhouse Gas Emissions Across a Subarctic Landscape

    Science.gov (United States)

    Herrick, C.; Palace, M. W.; Wik, M.; Burke, S. A.; Varner, R. K.

    2017-12-01

    High latitude lakes and ponds are significant sources of methane (CH4) and carbon dioxide (CO2) emission. Increased near-surface air temperature has linked these water bodies to large increases in methane emissions due to longer ice-free seasons, impacting climate change and further changing air temperature as a feedback mechanism. The impacts of changes in lake surface temperatures cannot be assessed until we know more about the baseline mechanistic biogeochemical controls that influence these emissions. Using a combination of image-based atmospheric corrections and image fusion models, thermal data from Landsat and MODIS satellites were used to characterize the temperature regimes of artic lakes in northern Sweden. This analysis provides insight into the temporal attributes of individual lakes in regard to temperature shifts and variability, as well as provides a rich temporal dataset where in situ temperature data is unavailable. Field-based measurements of temperature and associated methane release were used for calibration and correlation. This enabled the creation of emissions estimates over the broader pan-arctic landscape, including inter-seasonal and inter-annual variabilities. The result is a multi-year snapshot of temperature and emissions, allowing for future estimates of greenhouse gas emissions.

  7. Field Emission Properties of Carbon Nanotube Pillar Arrays Patterned Directly on Metal Alloy Surfaces

    National Research Council Canada - National Science Library

    Killian, Jessica L; Niemann, Darrell L; Silan, Nathaniel Zuckerman ;Jeremy; Ribaya, Bryan P; Rahman, Mahmud; Meyyappan, M; Nguyen, Cattien V

    2008-01-01

    Carbon nanotube pillar arrays (CPAs) for cold field emission were fabricated using a conventional photolithography process, and the geometry of these arrays was studied and the effect of pillar height on field emission was quantified...

  8. A close look to subthreshold kinetic emission from clean metal surfaces: "Surface-assisted kinetic emission" and "potential excitation of plasmons"

    Czech Academy of Sciences Publication Activity Database

    Winter, H. P.; Aumayr, F.; Lörinčík, Jan; Šroubek, Zdeněk

    2002-01-01

    Roč. 66, č. 4 (2002), s. 548-550 ISSN 0367-6765 R&D Projects: GA ČR GA202/99/0881 Institutional research plan: CEZ:AV0Z4040901 Keywords : electron-emission * slow ions * Al(111) Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 0.088, year: 2001

  9. Commentary Relative to the Emission Spectrum of the Solar Atmosphere: Further Evidence for a Distinct Solar Surface

    Directory of Open Access Journals (Sweden)

    Robitaille P.-M.

    2013-07-01

    Full Text Available The chromosphere and corona of the Sun represent tenuous regions which are characterized by numerous optically thin emission lines in the ultraviolet and X-ray bands. When observed from the center of the solar disk outward, these emission lines experience modest brightening as the limb is approached. The intensity of many ultraviolet and X-ray emission lines nearly doubles when observation is extended just beyond the edge of the disk. These findings indicate that the solar body is opaque in this frequency range and that an approximately two fold greater region of the solar atmosphere is being sampled outside the limb. These observations provide strong support for the presence of a distinct solar surface. Therefore, the behavior of the emission lines in this frequency range constitutes the twenty fifth line of evidence that the Sun is comprised of condensed matter

  10. Surface properties and field emission characteristics of chemical vapor deposition diamond grown on Fe/Si substrates

    International Nuclear Information System (INIS)

    Hirakuri, Kenji; Yokoyama, Takahiro; Enomoto, Hirofumi; Mutsukura, Nobuki; Friedbacher, Gernot

    2001-01-01

    Electron field emission characteristics of diamond grains fabricated on iron dot-patterned silicon (Fe/Si) substrates at different methane concentrations have been investigated. The characteristics of the samples could be improved by control of the methane concentration during diamond fabrication. Etching treatment of the as-grown diamond has enhanced the emission properties both with respect to current and threshold voltage. In order to study the influence of etching effects on the field emission characteristics, the respective surfaces were studied by Raman spectroscopy, Auger electron spectroscopy, and electron spectroscopy for chemical analysis (ESCA). ESCA revealed intensive graphite and FeO x peaks on the sample surface grown at high methane concentration. For the etched samples, the peaks of diamond and silicon carbide were observed, and the peaks of nondiamond carbon disappeared. The experimental results show that the etching process removes graphitic and nondiamond carbon components. [copyright] 2001 American Institute of Physics

  11. Method for measurement of emissivity and absorptivity of highly reflective surfaces from 20 K to room temperatures

    Czech Academy of Sciences Publication Activity Database

    Králík, Tomáš; Musilová, Věra; Hanzelka, Pavel; Frolec, Jiří

    2016-01-01

    Roč. 53, č. 2 (2016), s. 743-753 ISSN 0026-1394 R&D Projects: GA ČR(CZ) GA14-07397S; GA MŠk(CZ) LO1212 Institutional support: RVO:68081731 Keywords : absorptivity * emissivity * radiative heat transfer * metallic surfaces * cryogenics * uncertainty evaluation Subject RIV: BJ - Thermodynamics Impact factor: 3.411, year: 2016

  12. Secondary electron emission from the entrance and exit surfaces of thin carbon foils under fast ion bombardment

    International Nuclear Information System (INIS)

    Shi, C.R.; Toh, H.S.; Lo, D.; Livi, R.P.; Mendenhall, M.H.; Zhang, D.Z.; Tombrello, T.A.

    1985-01-01

    The total secondary electron emission (SEE) yield from the entrance and exit surfaces of thin carbon foils under fast ion ( 16 O, 19 F, 35 Cl) bombardment has been measured as a function of the ion energy and the ion beam current intensity. Using a retarding field, the energy distribution of secondary electrons integrated over almost all angles of emission in the backward and forward directions has also been measured. It is found that total forward emission is larger than backward emission by factors of up to 2.5, 2.7, and 3.4 for 16 O +3 , 19 F +3 , and 35 Cl +5 , respectively. It is suggested that the enhancement of forward SEE may be partly due to effects from the instantaneous charge state of the heavy ion beam in the solid in addition to the binary collisions of the projectile with individual electrons in the target. It is also shown that the total SEE yield from the entrance and exit surfaces of the target foils decreases with ion beam current intensity; this may be a beam-induced temperature effect. The total SEE yield in both the forward and backward directions is less sensitive to surface conditions for high velocity ions than for low velocity ions, and the total yield from both surfaces of the foils is proportional to the ion stopping power in the target, where the constant of proportionality depends on the properties of material. (orig.)

  13. MODIS/Aqua Land Surface Temperature/Emissivity Daily L3 Global 0.05Deg CMG V006

    Data.gov (United States)

    National Aeronautics and Space Administration — The MYD11C1 version 6 product provides land surface temperature (LST) and emissivity values in a 0.05 (5.6k x 5.6k) degree latitude/longitude Climate Modeling Grid...

  14. Reproducibility of The Random Incidence Absorption Coefficient Converted From the Sabine Absorption Coefficient

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho; Chang, Ji-ho

    2015-01-01

    Absorption coefficients measured in reverberation chambers, Sabine absorption coefficients, suffer from two major problems. Firstly, they sometimes exceed unity. Secondly, the reproducibility of the Sabine absorption coefficients is quite poor, meaning that the Sabine absorption coefficients vary...... resistivity optimization outperforms the surface impedance optimization in terms of the reproducibility....

  15. Scenarios for global emissions from air traffic. The development of regional and gridded (5 degrees x 5 degrees) emissions scenarios for aircraft and for surface sources, based on CPB scenarios and existing emission inventories for aircraft and surface sources

    NARCIS (Netherlands)

    Olivier JGJ; LAE

    1995-01-01

    An estimate was made of present global emissions from air traffic using statistical information on fuel consumption, aircraft types and applying emission factors for various compounds. To generate scenarios for future emissions from air traffic, assumptions were used regarding the development of the

  16. Impact of surface roughness and soil texture on mineral dust emission fluxes modeling

    Science.gov (United States)

    Menut, Laurent; Pérez, Carlos; Haustein, Karsten; Bessagnet, Bertrand; Prigent, Catherine; Alfaro, Stéphane

    2013-06-01

    Dust production models (DPM) used to estimate vertical fluxes of mineral dust aerosols over arid regions need accurate data on soil and surface properties. The Laboratoire Inter-Universitaire des Systemes Atmospheriques (LISA) data set was developed for Northern Africa, the Middle East, and East Asia. This regional data set was built through dedicated field campaigns and include, among others, the aerodynamic roughness length, the smooth roughness length of the erodible fraction of the surface, and the dry (undisturbed) soil size distribution. Recently, satellite-derived roughness length and high-resolution soil texture data sets at the global scale have emerged and provide the opportunity for the use of advanced schemes in global models. This paper analyzes the behavior of the ERS satellite-derived global roughness length and the State Soil Geographic data base-Food and Agriculture Organization of the United Nations (STATSGO-FAO) soil texture data set (based on wet techniques) using an advanced DPM in comparison to the LISA data set over Northern Africa and the Middle East. We explore the sensitivity of the drag partition scheme (a critical component of the DPM) and of the dust vertical fluxes (intensity and spatial patterns) to the roughness length and soil texture data sets. We also compare the use of the drag partition scheme to a widely used preferential source approach in global models. Idealized experiments with prescribed wind speeds show that the ERS and STATSGO-FAO data sets provide realistic spatial patterns of dust emission and friction velocity thresholds in the region. Finally, we evaluate a dust transport model for the period of March to July 2011 with observed aerosol optical depths from Aerosol Robotic Network sites. Results show that ERS and STATSGO-FAO provide realistic simulations in the region.

  17. Impact of Surface Roughness and Soil Texture on Mineral Dust Emission Fluxes Modeling

    Science.gov (United States)

    Menut, Laurent; Perez, Carlos; Haustein, Karsten; Bessagnet, Bertrand; Prigent, Catherine; Alfaro, Stephane

    2013-01-01

    Dust production models (DPM) used to estimate vertical fluxes of mineral dust aerosols over arid regions need accurate data on soil and surface properties. The Laboratoire Inter-Universitaire des Systemes Atmospheriques (LISA) data set was developed for Northern Africa, the Middle East, and East Asia. This regional data set was built through dedicated field campaigns and include, among others, the aerodynamic roughness length, the smooth roughness length of the erodible fraction of the surface, and the dry (undisturbed) soil size distribution. Recently, satellite-derived roughness length and high-resolution soil texture data sets at the global scale have emerged and provide the opportunity for the use of advanced schemes in global models. This paper analyzes the behavior of the ERS satellite-derived global roughness length and the State Soil Geographic data base-Food and Agriculture Organization of the United Nations (STATSGO-FAO) soil texture data set (based on wet techniques) using an advanced DPM in comparison to the LISA data set over Northern Africa and the Middle East. We explore the sensitivity of the drag partition scheme (a critical component of the DPM) and of the dust vertical fluxes (intensity and spatial patterns) to the roughness length and soil texture data sets. We also compare the use of the drag partition scheme to a widely used preferential source approach in global models. Idealized experiments with prescribed wind speeds show that the ERS and STATSGO-FAO data sets provide realistic spatial patterns of dust emission and friction velocity thresholds in the region. Finally, we evaluate a dust transport model for the period of March to July 2011 with observed aerosol optical depths from Aerosol Robotic Network sites. Results show that ERS and STATSGO-FAO provide realistic simulations in the region.

  18. Impacts of global, regional, and sectoral black carbon emission reductions on surface air quality and human mortality

    Directory of Open Access Journals (Sweden)

    S. C. Anenberg

    2011-07-01

    Full Text Available As a component of fine particulate matter (PM2.5, black carbon (BC is associated with premature human mortality. BC also affects climate by absorbing solar radiation and reducing planetary albedo. Several studies have examined the climate impacts of BC emissions, but the associated health impacts have been studied less extensively. Here, we examine the surface PM2.5 and premature mortality impacts of halving anthropogenic BC emissions globally and individually from eight world regions and three major economic sectors. We use a global chemical transport model, MOZART-4, to simulate PM2.5 concentrations and a health impact function to calculate premature cardiopulmonary and lung cancer deaths. We estimate that halving global anthropogenic BC emissions reduces outdoor population-weighted average PM2.5 by 542 ng m−3 (1.8 % and avoids 157 000 (95 % confidence interval, 120 000–194 000 annual premature deaths globally, with the vast majority occurring within the source region. Most of these avoided deaths can be achieved by halving emissions in East Asia (China; 54 %, followed by South Asia (India; 31 %, however South Asian emissions have 50 % greater mortality impacts per unit BC emitted than East Asian emissions. Globally, halving residential, industrial, and transportation emissions contributes 47 %, 35 %, and 15 % to the avoided deaths from halving all anthropogenic BC emissions. These contributions are 1.2, 1.2, and 0.6 times each sector's portion of global BC emissions, owing to the degree of co-location with population globally. We find that reducing BC emissions increases regional SO4 concentrations by up to 28 % of the magnitude of the regional BC concentration reductions, due to reduced absorption of radiation that drives photochemistry. Impacts of residential BC emissions are likely underestimated since indoor PM2.5 exposure is excluded. We estimate ∼8 times

  19. Impacts of global, regional, and sectoral black carbon emission reductions on surface air quality and human mortality

    Science.gov (United States)

    Anenberg, S. C.; Talgo, K.; Arunachalam, S.; Dolwick, P.; Jang, C.; West, J. J.

    2011-07-01

    As a component of fine particulate matter (PM2.5), black carbon (BC) is associated with premature human mortality. BC also affects climate by absorbing solar radiation and reducing planetary albedo. Several studies have examined the climate impacts of BC emissions, but the associated health impacts have been studied less extensively. Here, we examine the surface PM2.5 and premature mortality impacts of halving anthropogenic BC emissions globally and individually from eight world regions and three major economic sectors. We use a global chemical transport model, MOZART-4, to simulate PM2.5 concentrations and a health impact function to calculate premature cardiopulmonary and lung cancer deaths. We estimate that halving global anthropogenic BC emissions reduces outdoor population-weighted average PM2.5 by 542 ng m-3 (1.8 %) and avoids 157 000 (95 % confidence interval, 120 000-194 000) annual premature deaths globally, with the vast majority occurring within the source region. Most of these avoided deaths can be achieved by halving emissions in East Asia (China; 54 %), followed by South Asia (India; 31 %), however South Asian emissions have 50 % greater mortality impacts per unit BC emitted than East Asian emissions. Globally, halving residential, industrial, and transportation emissions contributes 47 %, 35 %, and 15 % to the avoided deaths from halving all anthropogenic BC emissions. These contributions are 1.2, 1.2, and 0.6 times each sector's portion of global BC emissions, owing to the degree of co-location with population globally. We find that reducing BC emissions increases regional SO4 concentrations by up to 28 % of the magnitude of the regional BC concentration reductions, due to reduced absorption of radiation that drives photochemistry. Impacts of residential BC emissions are likely underestimated since indoor PM2.5 exposure is excluded. We estimate ∼8 times more avoided deaths when BC and organic carbon (OC) emissions are halved together, suggesting

  20. Enhancing Optically Pumped Organic-Inorganic Hybrid Perovskite Amplified Spontaneous Emission via Compound Surface Plasmon Resonance

    Directory of Open Access Journals (Sweden)

    Xiaoyan Wu

    2018-03-01

    Full Text Available Organic-inorganic hybrid perovskite has attracted intensive attention from researchers as the gain medium in lasing devices. However, achieving electrically driven lasing remains a significant challenge. Modifying the devices’ structure to enhance the optically pumped amplified spontaneous emission (ASE is the key issue. In this work, gold nanoparticles (Au NPs are first doped into PEDOT: PSS buffer layer in a slab waveguide device structure: Quartz/PEDOT: PSS (with or w/o Au NPs/CH3NH3PbBr3. As a result, the facile device shows a significantly enhanced ASE intensity and a narrowed full width at half maximum. Based on experiments and theoretical simulation data, the improvement is mainly a result of the compound surface plasmon resonance, including simultaneous near- and far-field effects, both of which could increase the density of excitons excited state and accelerate the radiative decay process. This method is highly significant for the design and development and fabrication of high-performance organic-inorganic hybrid perovskite lasing diodes.

  1. On a model for the prediction of the friction coefficient in mixed lubrication based on a load-sharing concapt with measured surface roughness

    NARCIS (Netherlands)

    Akchurin, Aydar; Bosman, Rob; Lugt, Pieter Martin; van Drogen, Mark

    2015-01-01

    A new model was developed for the simulation of the friction coefficient in lubricated sliding line contacts. A half-space-based contact algorithm was linked with a numerical elasto-hydrodynamic lubrication solver using the load-sharing concept. The model was compared with an existing asperity-based

  2. Influence of Non-Perfect Step Input Concentration at the Feed Side of the Membrane Surface on the Diffusion Coefficient Evaluation

    Czech Academy of Sciences Publication Activity Database

    Čermáková, Jiřina; Fialová, Kateřina; Petričkovič, Roman; Kudrna, V.; Uchytil, Petr

    2006-01-01

    Roč. 15, č. 3 (2006), s. 246-251 ISSN 1022-1344 R&D Projects: GA AV ČR(CZ) 1QS401250509; GA AV ČR(CZ) IAA4072402 Institutional research plan: CEZ:AV0Z40720504 Keywords : diffusion coefficient * flux * dispersion Subject RIV: CI - Industrial Chemistry, Chemical Engineering Impact factor: 1.073, year: 2006

  3. A Framework for Estimating the 30 m Thermal-Infrared Broadband Emissivity From Landsat Surface Reflectance Data

    Science.gov (United States)

    Cheng, Jie; Liu, Hao; Liang, Shunlin; Nie, Aixiu; Liu, Qiang; Guo, Yamin

    2017-11-01

    The land surface thermal-infrared broadband emissivity (BBE) is a vital variable for estimating land surface radiation budgets (SRBs). We develop a framework for retrieving the 30 m BBE from Landsat surface reflectance data to estimate SRBs at finer scales and validate coarse resolution data. In the developed framework, the land surface is classified as bare soils and vegetated surfaces to allow different algorithms to be used for the BBE estimation. We propose a downscaling algorithm that uses the empirical relationship between the Advanced Spaceborne Thermal Emission and Reflectance Radiometer (ASTER) BBE and Landsat surface reflectance at 90 m to retrieve the 30 m BBE over bare soils. A look-up table (LUT)-based algorithm is proposed for vegetated surfaces. The BBE is interpolated from a LUT that is constructed from the 4SAIL radiative transfer model with inputs of the leaf BBE, the soil background BBE, and the leaf area index (LAI). Ground measurements that were collected at 11 relatively homogeneous sandy sites during three independent field campaigns are used to validate the proposed algorithm over bare soils. The average difference between the retrieved and field-measured BBEs is 0.012. We produce the land surface BBE of China in 2008 by using the developed framework and composited winter and summer seasonal BBE maps. The composited seasonal BBE maps are compared to the seasonal BBE maps derived from the ASTER emissivity product. The bias is within ±0.005 over bare soils and ranges from 0.012 to 0.019 over vegetated surfaces. Combined with the validated results in this study and published references, the comparison results demonstrate the good performance of the developed framework. This study provides a new perspective on estimating BBEs from sensors with only a thermal-infrared channel.

  4. The effect of temperature on the secondary electron emission yield from single crystal and polycrystalline diamond surfaces

    International Nuclear Information System (INIS)

    Stacey, A.; Prawer, S.; Rubanov, S.; Ahkvlediani, R.; Michaelson, Sh.; Hoffman, A.

    2009-01-01

    The effect of temperature in the 293-473 K range, on the secondary electron emission (SEE) yield of single crystal and polycrystalline diamond film surfaces is reported. For the polycrystalline films the SEE yield was found to decay as function of electron irradiation dose while for the single crystal an increase occurs first, followed by a decrease. For both surfaces, the SEE yield increases significantly upon heating and obtained a nearly constant value with electron dose at 473 K. These effects are explained as due to the temperature dependence of the electron beam induced hydrogen desorption and surface band bending.

  5. Microwave remote sensing: Active and passive. Volume 2 - Radar remote sensing and surface scattering and emission theory

    Science.gov (United States)

    Ulaby, F. T.; Moore, R. K.; Fung, A. K.

    1982-01-01

    The fundamental principles of radar backscattering measurements are presented, including measurement statistics, Doppler and pulse discrimination techniques, and associated ambiguity functions. The operation of real and synthetic aperture sidelooking airborne radar systems is described, along with the internal and external calibration techniques employed in scattering measurements. Attention is given to the physical mechanisms responsible for the scattering emission behavior of homogeneous and inhomogeneous media, through a discussion of surface roughness, dielectric properties and inhomogeneity, and penetration depth. Simple semiempirical models are presented. Theoretical models involving greater mathematical sophistication are also given for extended ocean and bare soil surfaces, and the more general case of a vegetation canopy over a rough surface.

  6. InP quantum dots: Electronic structure, surface effects, and the redshifted emission

    International Nuclear Information System (INIS)

    Fu, H.; Zunger, A.

    1997-01-01

    We present pseudopotential plane-wave electronic-structure calculations on InP quantum dots in an effort to understand quantum confinement and surface effects and to identify the origin of the long-lived and redshifted luminescence. We find that (i) unlike the case in small GaAs dots, the lowest unoccupied state of InP dots is the Γ 1c -derived direct state rather than the X 1c -derived indirect state and (ii) unlike the prediction of k·p models, the highest occupied state in InP dots has a 1sd-type envelope function rather than a (dipole-forbidden) 1pf envelope function. Thus explanations (i) and (ii) to the long-lived redshifted emission in terms of an orbitally forbidden character can be excluded. Furthermore, (iii) fully passivated InP dots have no surface states in the gap. However, (iv) removal of the anion-site passivation leads to a P dangling bond (DB) state just above the valence band, which will act as a trap for photogenerated holes. Similarly, (v) removal of the cation-site passivation leads to an In dangling-bond state below the conduction band. While the energy of the In DB state depends only weakly on quantum size, its radiative lifetime increases with quantum size. The calculated ∼300-meV redshift and the ∼18 times longer radiative lifetime relative to the dot-interior transition for the 26-Angstrom dot with an In DB are in good agreement with the observations of full-luminescence experiments for unetched InP dots. Yet, (vi) this type of redshift due to surface defect is inconsistent with that measured in selective excitation for HF-etched InP dots. (vii) The latter type of (open-quotes resonantclose quotes) redshift is compatible with the calculated screened singlet-triplet splitting in InP dots, suggesting that the slow emitting state seen in selective excitation could be a triplet state. copyright 1997 The American Physical Society

  7. Low-Computation Strategies for Extracting CO2 Emission Trends from Surface-Level Mixing Ratio Observations

    Science.gov (United States)

    Shusterman, A.; Kim, J.; Lieschke, K.; Newman, C.; Cohen, R. C.

    2017-12-01

    Global momentum is building for drastic, regulated reductions in greenhouse gas emissions over the coming decade. With this increasing regulation comes a clear need for increasingly sophisticated monitoring, reporting, and verification (MRV) strategies capable of enforcing and optimizing emissions-related policy, particularly as it applies to urban areas. Remote sensing and/or activity-based emission inventories can offer MRV insights for entire sectors or regions, but are not yet sophisticated enough to resolve unexpected trends in specific emitters. Urban surface monitors can offer the desired proximity to individual greenhouse gas sources, but due to the densely-packed nature of typical urban landscapes, surface observations are rarely representative of a single source. Most previous efforts to decompose these complex signals into their contributing emission processes have involved inverse atmospheric modeling techniques, which are computationally intensive and believed to depend heavily on poorly understood a priori estimates of error covariance. Here we present a number of transparent, low-computation approaches for extracting source-specific emissions estimates from signals with a variety of nearfield influences. Using observations from the first several years of the BErkeley Atmospheric CO2 Observation Network (BEACO2N), we demonstrate how to exploit strategic pairings of monitoring "nodes," anomalous wind conditions, and well-understood temporal variations to hone in on specific CO2 sources of interest. When evaluated against conventional, activity-based bottom-up emission inventories, these strategies are seen to generate quantitatively rigorous emission estimates. With continued application as the BEACO2N data set grows in time and space, these approaches offer a promising avenue for optimizing greenhouse gas mitigation strategies into the future.

  8. Role of Surface Wind and Vegetation Cover in Multi-decadal Variations of Dust Emission in the Sahara and Sahel

    Science.gov (United States)

    Kim, Dong; Chin, Mian; Remer, Lorraine A.; Diehl, Thomas L.; Bian, Huisheng; Yu, Hongbin; Brown, Molly E.; Stockwell, William R.

    2016-01-01

    North Africa, the world's largest dust source, is non-uniform, consisting of a permanently arid region (Sahara), a semi-arid region (Sahel), and a relatively moist vegetated region (Savanna), each with very different rainfall patterns and surface conditions. This study aims to better understand the controlling factors that determine the variation of dust emission in North Africa over a 27-year period from 1982 to 2008, using observational data and model simulations. The results show that the model-derived Saharan dust emission is only correlated with the 10-m winds (W10m) obtained from reanalysis data, but the model-derived Sahel dust emission is correlated with both W10m and the Normalized Difference Vegetation Index (NDVI) that is obtained from satellite. While the Saharan dust accounts for 82 of the continental North Africa dust emission (1340-1570 Tg year(exp -1) in the 27-year average, the Sahel accounts for 17 with a larger seasonal and inter-annual variation (230-380 Tg year(exp -1), contributing about a quarter of the transatlantic dust transported to the northern part of South America. The decreasing dust emission trend over the 27-year period is highly correlated with W10m over the Sahara (R equals 0.92). Over the Sahel, the dust emission is correlated with W10m (R 0.69) but is also anti-correlated with the trend of NDVI (R equals 0.65). W10m is decreasing over both the Sahara and the Sahel between 1982 and 2008, and the trends are correlated (R equals 0.53), suggesting that Saharan Sahelian surface winds are a coupled system, driving the inter-annual variation of dust emission.

  9. White light emission from fluorescent SiC with porous surface

    DEFF Research Database (Denmark)

    Lu, Weifang; Ou, Yiyu; Fiordaliso, Elisabetta Maria

    2017-01-01

    the bulk fuorescent SiC layer. A high color rendering index of 81.1 has been achieved. Photoluminescence spectra in porous layers fabricated in both commercial n-type and lab grown N-B co-doped 6H-SiC show two emission peaks centered approximately at 460nm and 530nm. Such bluegreen emission phenomenon can......, the photoluminescence intensity from the porous layer was signifcant enhanced by a factor of more than 12. Using a porous layer of moderate thickness (~10µm), high-quality white light emission was realized by combining the independent emissions of blue-green emission from the porous layer and yellow emission from...

  10. AMSR-E/Aqua Monthly Global Microwave Land Surface Emissivity, Version 1

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set is a global land emissivity product using passive microwave observations from the Advanced Microwave Scanning Radiometer - Earth Observing System...

  11. Evaluation and management of the impact of land use change on the nitrogen and phosphorus load delivered to surface waters: the export coefficient modelling approach

    Science.gov (United States)

    Johnes, P. J.

    1996-09-01

    A manageable, relatively inexpensive model was constructed to predict the loss of nitrogen and phosphorus from a complex catchment to its drainage system. The model used an export coefficient approach, calculating the total nitrogen (N) and total phosphorus (P) load delivered annually to a water body as the sum of the individual loads exported from each nutrient source in its catchment. The export coefficient modelling approach permits scaling up from plot-scale experiments to the catchment scale, allowing application of findings from field experimental studies at a suitable scale for catchment management. The catchment of the River Windrush, a tributary of the River Thames, UK, was selected as the initial study site. The Windrush model predicted nitrogen and phosphorus loading within 2% of observed total nitrogen load and 0.5% of observed total phosphorus load in 1989. The export coefficient modelling approach was then validated by application in a second research basin, the catchment of Slapton Ley, south Devon, which has markedly different catchment hydrology and land use. The Slapton model was calibrated within 2% of observed total nitrogen load and 2.5% of observed total phosphorus load in 1986. Both models proved sensitive to the impact of temporal changes in land use and management on water quality in both catchments, and were therefore used to evaluate the potential impact of proposed pollution control strategies on the nutrient loading delivered to the River Windrush and Slapton Ley.

  12. Tunable emission in surface passivated Mn-ZnS nanophosphors and its application for Glucose sensing

    Directory of Open Access Journals (Sweden)

    Manoj Sharma

    2012-03-01

    Full Text Available The present work describes the tunable emission in inorganic-organic hybrid NPs which can be useful for optoelectronic and biosensing applications. In this work, Mn- ZnS nanoparticles emitting various colors, including blue and orange, were synthesized by simple chemical precipitation method using chitosan as a capping agent. Earlier reports describe that emission color characteristics in nanoparticles are tuned by varying particle size and with doping concentration. Here in this article tunable emission has been achieved by varying excitation wavelength in a single sample. This tunable emission property with high emission intensity was further achieved by changing capping concentration keeping host Mn-ZnS concentration same. Tunable emission is explained by FRET mechanism. Commission Internationale de l’Eclairage (CIE chromaticity coordinates shifts from (0.273, 0.20 and (0.344, 0.275 for same naocrystals by suitably tuning excitation energy from higher and lower ultra-violet (UV range. Synthesized nanoparticles have been characterized by X-ray diffraction, SEM, HRTEM, UV- Visible absorption and PL spectroscopy for structural and optical studies. Using tunable emission property, these highly emissive nanoparticles functionalized with biocompatible polymer chitosan were further used for glucose sensing applications.

  13. Surface ozone seasonality under global change: Influence from dry deposition and isoprene emissions at northern mid-latitudes

    Science.gov (United States)

    Clifton, O.; Paulot, F.; Fiore, A. M.; Horowitz, L. W.; Malyshev, S.; Shevliakova, E.; Correa, G. J. P.; Lin, M.

    2017-12-01

    Identifying the contributions of nonlinear chemistry and transport to observed surface ozone seasonal cycles over land using global models relies on an accurate representation of ozone uptake by vegetation (dry deposition). It is well established that in the absence of ozone precursor emission changes, a warming climate will increase surface ozone in polluted regions, and that a rise in temperature-dependent isoprene emissions would exacerbate this "climate penalty". However, the influence of changes in ozone dry deposition, expected to evolve with climate and land use, is often overlooked in air quality projections. With a new scheme that represents dry deposition within the NOAA GFDL dynamic vegetation land model (LM3) coupled to the NOAA GFDL atmospheric chemistry-climate model (AM3), we simulate the impact of 21st century climate and land use on ozone dry deposition and isoprene emissions. This dry deposition parameterization is a version of the Wesely scheme, but uses parameters explicitly calculated by LM3 that respond to climate and land use (e.g., stomatal conductance, canopy interception of water, leaf area index). The parameterization includes a nonstomatal deposition dependence on humidity. We evaluate climatological present-day seasonal cycles of ozone deposition velocities and abundances with those observed at northern mid-latitude sites. With a set of 2010s and 2090s decadal simulations under a high climate warming scenario (RCP8.5) and a sensitivity simulation with well-mixed greenhouse gases following RCP8.5 but air pollutants held at 2010 levels (RCP8.5_WMGG), we examine changes in surface ozone seasonal cycles. We build on our previous findings, which indicate that strong reductions in anthropogenic NOx emissions under RCP8.5 cause the surface ozone seasonal cycle over the NE USA to reverse, shifting from a summer peak at present to a winter peak by 2100. Under RCP8.5_WMGG, we parse the separate effects of climate and land use on ozone dry

  14. Comparison of designing simple steel frame & coaxial brace systems by contrast of blast, using two methods of load & resistance coefficients & performance surfaces

    OpenAIRE

    P. Hassanvand; M. H. Rasoul Abadi; A. S. Moghadam; M. Hosseini

    2016-01-01

    Nowadays, because of the increasing terrorist attacks around the urban areas, designing buildings by contrast of resulted loads of blast came into consideration particularly in some sensitive buildings & vital arteries. When a blast occurs, the resulted emissions in environment leads to appearance of several penalties and endangers to the human life. Steel structures generally are designed on the basis of standard seismic and gravity loads, it is necessary to investigate the implantation of t...

  15. Extinction Coefficient of Gold Nanostars

    OpenAIRE

    de Puig, Helena; Tam, Justina O.; Yen, Chun-Wan; Gehrke, Lee; Hamad-Schifferli, Kimberly

    2015-01-01

    Gold nanostars (NStars) are highly attractive for biological applications due to their surface chemistry, facile synthesis and optical properties. Here, we synthesize NStars in HEPES buffer at different HEPES/Au ratios, producing NStars of different sizes and shapes, and therefore varying optical properties. We measure the extinction coefficient of the synthesized NStars at their maximum surface plasmon resonances (SPR), which range from 5.7 × 108 to 26.8 × 108 M−1cm−1. Measured values correl...

  16. Surface defect assisted broad spectra emission from CdSe quantum dots for white LED application

    Science.gov (United States)

    Samuel, Boni; Mathew, S.; Anand, V. R.; Correya, Adrine Antony; Nampoori, V. P. N.; Mujeeb, A.

    2018-02-01

    This paper reports, broadband photoluminescence from CdSe quantum dots (QDs) under the excitation of 403 nm using fluorimeter and 403 nm CW laser excitation. The broad spectrum obtained from the colloidal quantum dots was ranges from 450 nm to 800 nm. The broadness of the spectra was attributed to the merging of band edge and defect driven emissions from the QDs. Six different sizes of particles were prepared via kinetic growth method by using CdO and elemental Se as sources of Cd and Se respectively. The particle sizes were measured from TEM images. The size dependent effect on broad emission was also studied and the defect state emission was found to be predominant in very small QDs. The defect driven emission was also observed to be redshifted, similar to the band edge emission, due to quantum confinement effect. The emission corresponding to different laser power was also studied and a linear relation was obtained. In order to study the colour characteristics of the emission, CIE chromaticity coordinate, CRI and CCT of the prepared samples were measured. It is observed that, these values were tunable by the addition of suitable intensity of blue light from the excitation source to yield white light of various colour temperatures. The broad photoluminescence spectrum of the QDs, were compared with that of a commercially available white LED. It was found that the prepared QDs are good alternatives for the phosphor in phosphor converted white LEDs, to provide good spectral tunability.

  17. Producing the surface structures with required properties with the help of concentrated fluxes of particles

    International Nuclear Information System (INIS)

    Li, I.P.; Rukhlyada, N.Ya.

    2005-01-01

    Pulsed plasma treatment has been proposed for modification of the surface layers of metal-matrix-porous cathodes and parts of electronic-vacuum devices. Surface plasma treatment leads to improvement of thermal emission properties of effective cathodes: work function decreases, secondary electron emission coefficient increases, and surface emission uniformity improves. With the help of pulse plasma, surface smoothing as well as formation of composite coatings can be done [ru

  18. InGaAs/GaAs frequency tunable twin-guide quantum-well laser designed for steerable surface emission

    Science.gov (United States)

    Rosenberger, Matthias; Koeck, Anton; Gmachl, Claire F.; Gornik, Erich; Riechert, Henning; Bernklau, D.

    1993-11-01

    Based on a frequency tunable twin-guide (TTG) InGaAs/GaAs multiple quantum well (MQW) laser structure, we developed a novel design concept for a surface emitting laser device enabling spatial beam steering. Utilizing a change in the refractive index of the parallel monolithically integrated modulator diode due to carrier injection, we observe a continuous emission frequency (wavelength) shift up to (Delta) f equals 85 GHz ((Delta) (lambda) equals -0.35 nm). For this preliminary structure the experimental results are consistent with our model calculations. Based on the theoretical model, for an optimized device a tuning range of (Delta) f equals 1600 GHz ((Delta) (lambda) >= 5 nm) is expected. For the novel surface emitting device design, we make use of an additional structure on top of the TTG laser including a second waveguide and a grating. This will enable a wavelength dependent surface emission angle, i.e., continuous beam steering, by coupling the laser and the surface mode. A calculational model was developed to estimate the steering characteristics in dependence on the dielectric device structure including mode guiding and the surface grating shape.

  19. Land Surface Temperature and Emissivity Separation from Cross-Track Infrared Sounder Data with Atmospheric Reanalysis Data and ISSTES Algorithm

    Directory of Open Access Journals (Sweden)

    Yu-Ze Zhang

    2017-01-01

    Full Text Available The Cross-track Infrared Sounder (CrIS is one of the most advanced hyperspectral instruments and has been used for various atmospheric applications such as atmospheric retrievals and weather forecast modeling. However, because of the specific design purpose of CrIS, little attention has been paid to retrieving land surface parameters from CrIS data. To take full advantage of the rich spectral information in CrIS data to improve the land surface retrievals, particularly the acquisition of a continuous Land Surface Emissivity (LSE spectrum, this paper attempts to simultaneously retrieve a continuous LSE spectrum and the Land Surface Temperature (LST from CrIS data with the atmospheric reanalysis data and the Iterative Spectrally Smooth Temperature and Emissivity Separation (ISSTES algorithm. The results show that the accuracy of the retrieved LSEs and LST is comparable with the current land products. The overall differences of the LST and LSE retrievals are approximately 1.3 K and 1.48%, respectively. However, the LSEs in our study can be provided as a continuum spectrum instead of the single-channel values in traditional products. The retrieved LST and LSEs now can be better used to further analyze the surface properties or improve the retrieval of atmospheric parameters.

  20. Total vertical sediment flux and PM10 emissions from disturbed Chihuahuan Desert Surfaces

    Science.gov (United States)

    Desert surfaces are typically stable and represent some of the oldest landforms on Earth. For surfaces without vegetation, the evolution of a desert pavements of gravel protects the surface from erosive forces and vegetation further protects the surface in arid and semi-arid rangelands. The suscep...

  1. Greenhouse gas emissions from reservoir water surfaces: A new global synthesis

    Science.gov (United States)

    Collectively, reservoirs created by dams are thought to be an important source ofgreenhouse gases (GHGs) to the atmosphere. So far, efforts to quantify, model, andmanage these emissions have been limited by data availability and inconsistenciesin methodological approach. Here we ...

  2. Short-range surface plasmonics: Localized electron emission dynamics from a 60-nm spot on an atomically flat single-crystalline gold surface.

    Science.gov (United States)

    Frank, Bettina; Kahl, Philip; Podbiel, Daniel; Spektor, Grisha; Orenstein, Meir; Fu, Liwei; Weiss, Thomas; Horn-von Hoegen, Michael; Davis, Timothy J; Meyer Zu Heringdorf, Frank-J; Giessen, Harald

    2017-07-01

    We experimentally and theoretically visualize the propagation of short-range surface plasmon polaritons using atomically flat single-crystalline gold platelets on silicon substrates. We study their excitation and subfemtosecond dynamics via normal-incidence two-photon photoemission electron microscopy. By milling a plasmonic disk and grating structure into a single-crystalline gold platelet, we observe nanofocusing of the short-range surface plasmon polariton. Localized two-photon ultrafast electron emission from a spot with a smallest dimension of 60 nm is observed. Our novel approach opens the door toward reproducible plasmonic nanofocusing devices, which do not degrade upon high light intensity or heating due to the atomically flat surface without any tips, protrusions, or holes. Our nanofoci could also be used as local emitters for ultrafast electron bunches in time-resolved electron microscopes.

  3. Secondary ion emission from surface and volume with high and low energy ions

    International Nuclear Information System (INIS)

    Deprun, C.; Della-Negra, S.; Le Beyec, Y.

    1987-01-01

    Secondary ion emission from fast ion impact (Cf252 fission fragments) of Langmuir-Blodgett films consisting of superposed two molecule layers with similar structure and mass (Cd stereate and Cd arachidate) was analyzed. Emission of deproton secondary ions of stereate and arachidate acids was studied for various target configurations. Results show that under the influence of high energy ions, secondary ion ejection comes from a conical volume of 200A depth [fr

  4. Atmospheric characterization through fused mobile airborne and surface in situ surveys: methane emissions quantification from a producing oil field

    Directory of Open Access Journals (Sweden)

    I. Leifer

    2018-03-01

    Full Text Available Methane (CH4 inventory uncertainties are large, requiring robust emission derivation approaches. We report on a fused airborne–surface data collection approach to derive emissions from an active oil field near Bakersfield, central California. The approach characterizes the atmosphere from the surface to above the planetary boundary layer (PBL and combines downwind trace gas concentration anomaly (plume above background with normal winds to derive flux. This approach does not require a well-mixed PBL; allows explicit, data-based, uncertainty evaluation; and was applied to complex topography and wind flows. In situ airborne (collected by AJAX – the Alpha Jet Atmospheric eXperiment and mobile surface (collected by AMOG – the AutoMObile trace Gas – Surveyor data were collected on 19 August 2015 to assess source strength. Data included an AMOG and AJAX intercomparison transect profiling from the San Joaquin Valley (SJV floor into the Sierra Nevada (0.1–2.2 km altitude, validating a novel surface approach for atmospheric profiling by leveraging topography. The profile intercomparison found good agreement in multiple parameters for the overlapping altitude range from 500 to 1500 m for the upper 5 % of surface winds, which accounts for wind-impeding structures, i.e., terrain, trees, buildings, etc. Annualized emissions from the active oil fields were 31.3 ± 16 Gg methane and 2.4 ± 1.2 Tg carbon dioxide. Data showed the PBL was not well mixed at distances of 10–20 km downwind, highlighting the importance of the experimental design.

  5. Impact of high-resolution sea surface temperature, emission spikes and wind on simulated surface ozone in Houston, Texas during a high ozone episode

    Science.gov (United States)

    Pan, Shuai; Choi, Yunsoo; Jeon, Wonbae; Roy, Anirban; Westenbarger, David A.; Kim, Hyun Cheol

    2017-03-01

    Model-measurement comparisons for surface ozone often show significant error, which could be attributed to problems in meteorology and emissions fields. A WRF-SMOKE-CMAQ air quality modeling system was used to investigate the contributions of these inputs. In this space, a base WRF run (BASE) and a WRF run initializing with NOAA GOES satellite sea surface temperature (SST) (SENS) were performed to clarify the impact of high-resolution SST on simulated surface ozone (O3) over the Greater Houston area during 25 September 2013, corresponding to the high O3 episode during the NASA DISCOVER-AQ Texas campaign. The SENS case showed reduced land-sea thermal contrast during early morning hours due to 1-2 °C lower SST over water bodies. The lowered SST reduced the model wind speed and slowed the dilution rate. These changes led to a simulated downwind O3 change of ∼5 ppb near the area over land with peak simulated afternoon O3. However, the SENS case still under-predicted surface O3 in urban and industrial areas. Episodic flare emissions, dry sunny postfrontal stagnated conditions, and land-bay/sea breeze transitions could be the potential causes of the high O3. In order to investigate the additional sources of error, three sensitivity simulations were performed for the high ozone time period. These involved adjusted emissions, adjusted wind fields, and both adjusted emissions and winds. These scenarios were superimposed on the updated SST (SENS) case. Adjusting NOx and VOC emissions using simulated/observed ratios improved correlation and index of agreement (IOA) for NOx from 0.48 and 0.55 to 0.81 and 0.88 respectively, but still reported spatial misalignment of afternoon O3 hotspots. Adjusting wind fields to represent morning weak westerly winds and afternoon converging zone significantly mitigated under-estimation of the observed O3 peak. For example, simulations with adjusted wind fields and adjusted (emissions + wind fields) reduced under-estimation of the peak

  6. Research of fuel temperature control in fuel pipeline of diesel engine using positive temperature coefficient material

    Directory of Open Access Journals (Sweden)

    Xiaolu Li

    2016-01-01

    Full Text Available As fuel temperature increases, both its viscosity and surface tension decrease, and this is helpful to improve fuel atomization and then better combustion and emission performances of engine. Based on the self-regulated temperature property of positive temperature coefficient material, this article used a positive temperature coefficient material as electric heating element to heat diesel fuel in fuel pipeline of diesel engine. A kind of BaTiO3-based positive temperature coefficient material, with the Curie temperature of 230°C and rated voltage of 24 V, was developed, and its micrograph and element compositions were also analyzed. By the fuel pipeline wrapped in six positive temperature coefficient ceramics, its resistivity–temperature and heating characteristics were tested on a fuel pump bench. The experiments showed that in this installation, the surface temperature of six positive temperature coefficient ceramics rose to the equilibrium temperature only for 100 s at rated voltage. In rated power supply for six positive temperature coefficient ceramics, the temperature of injection fuel improved for 21°C–27°C within 100 s, and then could keep constant. Using positive temperature coefficient material to heat diesel in fuel pipeline of diesel engine, the injection mass per cycle had little change, approximately 0.3%/°C. This study provides a beneficial reference for improving atomization of high-viscosity liquids by employing positive temperature coefficient material without any control methods.

  7. Onset of surface stimulated emission at 260 nm from AlGaN multiple quantum wells

    KAUST Repository

    Li, Xiaohang

    2015-12-14

    We demonstrated onset of deep-ultraviolet (DUV) surface stimulated emission (SE) from c-plane AlGaNmultiple-quantum well(MQW)heterostructuresgrown on a sapphire substrate by optical pumping at room temperature. The onset of SE became observable at a pumping power density of 630 kW/cm2. Spectral deconvolution revealed superposition of a linearly amplified spontaneous emission peak at λ ∼ 257.0 nm with a full width at half maximum (FWHM) of ∼12 nm and a superlinearly amplified SE peak at λ ∼ 260 nm with a narrow FWHM of less than 2 nm. In particular, the wavelength of ∼260 nm is the shortest wavelength of surface SE from III-nitride MQWheterostructures to date. Atomic force microscopy and scanning transmission electron microscopy measurements were employed to investigate the material and structural quality of the AlGaNheterostructures, showing smooth surface and sharp layer interfaces. This study offers promising results for AlGaNheterostructuresgrown on sapphire substrates for the development of DUV vertical cavity surface emitting lasers(VCSELs).

  8. On the capability of IASI measurements to inform about CO surface emissions

    Directory of Open Access Journals (Sweden)

    S. Szopa

    2009-11-01

    Full Text Available Between July and November 2008, simultaneous observations were conducted by several orbiting instruments that monitor carbon monoxide in the atmosphere, among them the Infrared Atmospheric Sounding Instrument (IASI and Measurements Of Pollution In The Troposphere (MOPITT. In this paper, the concentration retrievals at about 700 hPa from these two instruments are successively used in a variational Bayesian system to infer the global distribution of CO emissions. Starting from a global emission budget of 479 Tg for the considered period, the posterior estimate of CO emissions using IASI retrievals gives a total of 643 Tg, which is in close agreement with the budget calculated with version 3 of the MOPITT data (649 Tg. The regional totals are also broadly consistent between the two inversions. Even though our theoretical error budget indicates that IASI constrains the emissions slightly less than MOPITT, because of lesser sensitivity in the lower troposphere, these first results indicate that IASI may play a major role in the quantification of the emissions of CO.

  9. Impact of regional climate change and future emission scenarios on surface O3 and PM2.5 over India

    Science.gov (United States)

    Pommier, Matthieu; Fagerli, Hilde; Gauss, Michael; Sharma, Sumit; Sinha, Vinay; Ghude, Sachin; Langren, Oskar; Nyiri, Agnes; Wind, Peter

    2017-04-01

    This work aims to study the changes in surface ozone (O3) and fine particulate matter (PM2.5) in a world of changing emissions and climate by focusing on India. Stakeholders in India are already aware about air quality issues but anthropogenic emissions are projected to largely increase for some of the pollutants in the short-term (2030) and medium-term (2050) futures in India, especially if no more policy efforts are made. Only the policies in place before 2014/15 have been taken into account while projecting the future emissions. Current policies have led to decrease in emission intensities, however may not be enough for control of absolute emissions in future. In this study, the regional EMEP/MSC-W chemical transport model is used forced by downscaled meteorological fields at a 50 km resolution following the RCP8.5 greenhouse gas concentration scenario. The reference scenario (for present-day) is evaluated with surface-based measurements. Given the relatively coarse resolution of the meteorological fields used for this comparison with urban observations, the agreement can be considered satisfactory as high correlations with O3 (r=0.9) and PM2.5 (r=0.5 and r=0.8 depending on the data set) are noticed. The bias in PM2.5 is limited (lower than 6%) but the model overestimates the O3 by 35%. Then, this work shows that in the 2050s, the variation in O3 linked to the climate change is mainly due to the change in O3 deposition velocity related to the change in the boundary layer height and, over a few areas, by changes in VOCs. At short term and medium-term, the PM2.5 is predicted to increase due to climate change, by up to 6.5% in the 2050s. This climatic variation is mainly explained by increases in dust, organic matter and secondary inorganic aerosols which are affected by the change in wind speed and precipitations. The large increase in anthropogenic emissions will modify the composition of PM2.5 over India as the secondary inorganic aerosols will be dominant. The

  10. Studying the Impacts of Environmental Factors and Agricultural Management on Methane Emissions from Rice Paddies Using a Land Surface Model

    Science.gov (United States)

    Lin, T. S.; Gahlot, S.; Shu, S.; Jain, A. K.; Kheshgi, H. S.

    2017-12-01

    Continued growth in population is projected to drive increased future demand for rice and the methane emissions associated with its production. However, observational studies of methane emissions from rice have reported seemingly conflicting results and do not all support this projection. In this study we couple an ecophysiological process-based rice paddy module and a methane emission module with a land surface model, Integrated Science Assessment Model (ISAM), to study the impacts of various environmental factors and agricultural management practices on rice production and methane emissions from rice fields. This coupled modeling framework accounts for dynamic rice growth processes with adaptation of photosynthesis, rice-specific phenology, biomass accumulation, leaf area development and structures responses to water, temperature, light and nutrient stresses. The coupled model is calibrated and validated with observations from various rice cultivation fields. We find that the differing results of observational studies can be caused by the interactions of environmental factors, including climate, atmospheric CO2 concentration, and N deposition, and agricultural management practices, such as irrigation and N fertilizer applications, with rice production at spatial and temporal scales.

  11. The role of surface and deep-level defects on the emission of tin oxide quantum dots

    International Nuclear Information System (INIS)

    Kumar, Vinod; Kumar, Vijay; Som, S; Ntwaeaborwa, O M; Swart, H C; Neethling, J H; Lee, Mike

    2014-01-01

    This paper reports on the role of surface and deep-level defects on the blue emission of tin oxide quantum dots (SnO 2 QDs) synthesized by the solution-combustion method at different combustion temperatures. X-ray diffraction studies showed the formation of a single rutile SnO 2 phase with a tetragonal lattice structure. High resolution transmission electron microscopy studies revealed an increase in the average dot size from 2.2 to 3.6 nm with an increase of the combustion temperature from 350 to 550 °C. A decrease in the band gap value from 3.37 to 2.76 eV was observed with the increase in dot size due to the quantum confinement effect. The photoluminescence emission was measured for excitation at 325 nm and it showed a broad blue emission band for all the combustion temperatures studied. This was due to the creation of various oxygen and tin vacancies/defects as confirmed by x-ray photoelectron spectroscopy data. The origin of the blue emission in the SnO 2 QDs is discussed with the help of an energy band diagram. (paper)

  12. N2O emission from plant surfaces – light stimulated and a global phenomenon

    DEFF Research Database (Denmark)

    Mikkelsen, Teis Nørgaard; Bruhn, Dan; Ambus, Per

    2017-01-01

    Nitrous oxide (N2O) is an important long-lived greenhouse gas and precursor of stratospheric ozone depletingmono-nitrogen oxides. The atmospheric concentration of N2O is persistently increasing; however, large uncertaintiesare associated with the distinct source strengths. Here we investigate...... for the first time N2O emission fromterrestrial vegetation in response to natural solar ultra violet radiation. We conducted field site measurementsto investigate N2O atmosphere exchange from grass vegetation exposed to solar irradiance with and withoutUV-screening. Further laboratory tests were conducted...... with a range of species to study the controls and possibleloci of UV-induced N2O emission from plants. Plants released N2O in response to natural sunlight at rates of c.20-50 nmol m-2 h-1, mostly due to the UV component. The emission rate is temperature dependent with a ratherhigh activation energy indicative...

  13. Improved detection of highly energetic materials traces on surfaces by standoff laser-induced thermal emission incorporating neural networks

    Science.gov (United States)

    Figueroa-Navedo, Amanda; Galán-Freyle, Nataly Y.; Pacheco-Londoño, Leonardo C.; Hernández-Rivera, Samuel P.

    2013-05-01

    Terrorists conceal highly energetic materials (HEM) as Improvised Explosive Devices (IED) in various types of materials such as PVC, wood, Teflon, aluminum, acrylic, carton and rubber to disguise them from detection equipment used by military and security agency personnel. Infrared emissions (IREs) of substrates, with and without HEM, were measured to generate models for detection and discrimination. Multivariable analysis techniques such as principal component analysis (PCA), soft independent modeling by class analogy (SIMCA), partial least squares-discriminant analysis (PLS-DA), support vector machine (SVM) and neural networks (NN) were employed to generate models, in which the emission of IR light from heated samples was stimulated using a CO2 laser giving rise to laser induced thermal emission (LITE) of HEMs. Traces of a specific target threat chemical explosive: PETN in surface concentrations of 10 to 300 ug/cm2 were studied on the surfaces mentioned. Custom built experimental setup used a CO2 laser as a heating source positioned with a telescope, where a minimal loss in reflective optics was reported, for the Mid-IR at a distance of 4 m and 32 scans at 10 s. SVM-DA resulted in the best statistical technique for a discrimination performance of 97%. PLS-DA accurately predicted over 94% and NN 88%.

  14. Analysis of Field Emission of Fabricated Nanogap in Pd Strips for Surface Conduction Electron-Emitter Displays

    Science.gov (United States)

    Lo, Hsiang-Yu; Li, Yiming; Tsai, Chih-Hao; Pan, Fu-Ming

    2008-04-01

    We study the field emission (FE) property of a nanometer-scale gap structure in a palladium strip, which was fabricated by hydrogen absorption under high-pressure treatment. A vigorous cracking process could be accompanied by extensive atomic migration during the hydrogen treatment. A three-dimensional finite-difference time-domain particle-in-cell method is adopted to simulate the electron emission in a surface-conduction electron-emitter display (SED) device. Examinations of conducting characteristics, FE efficiency, the local field around the emitter, and the current density on the anode plate with one FE emitter are conducted. The image of a light spot is successfully produced on a phosphor plate, which implies that the explored electrode with nanometer separation possesses a potential SED application. Experimental observation and numerical simulation show that the proposed structure can be used as a surface conduction electron emitter and has a high FE efficiency with low turn-on voltage and a different electron emission mechanism. This study benefits the advanced SED design for a new type of electron source.

  15. NASA's MODIS/VIIRS Land Surface Temperature and Emissivity Products: Asssessment of Accuracy, Continuity and Science Uses

    Science.gov (United States)

    Hulley, G. C.; Malakar, N.; Islam, T.

    2017-12-01

    Land Surface Temperature and Emissivity (LST&E) are an important Earth System Data Record (ESDR) and Environmental Climate Variable (ECV) defined by NASA and GCOS respectively. LST&E data are key variables used in land cover/land use change studies, in surface energy balance and atmospheric water vapor retrieval models and retrievals, and in climate research. LST&E products are currently produced on a routine basis using data from the MODIS instruments on the NASA EOS platforms and by the VIIRS instrument on the Suomi-NPP platform that serves as a bridge between NASA EOS and the next-generation JPSS platforms. Two new NASA LST&E products for MODIS (MxD21) and VIIRS (VNP21) are being produced during 2017 using a new approach that addresses discrepancies in accuracy and consistency between the current suite of split-window based LST products. The new approach uses a Temperature Emissivity Separation (TES) algorithm, originally developed for the ASTER instrument, to physically retrieve both LST and spectral emissivity consistently for both sensors with high accuracy and well defined uncertainties. This study provides a rigorous assessment of accuracy of the MxD21/VNP21 products using temperature- and radiance-based validation strategies and demonstrates continuity between the products using collocated matchups over CONUS. We will further demonstrate potential science use of the new products with studies related to heat waves, monitoring snow melt dynamics, and land cover/land use change.

  16. [Study on Square Super-Lattice Pattern with Surface Discharge in Dielectric Barrier Discharge by Optical Emission Spectra].

    Science.gov (United States)

    Niu, Xue-jiao; Dong, Li-fang; Liu, Ying; Wang, Qian; Feng, Jian-yu

    2016-02-01

    Square super-lattice pattern with surface discharge consisting of central spots and dim spots is firstly observed in the mixture of argon and air by using a dielectric barrier discharge device with water electrodes. By observing the image, it is found that the central spot is located at the centriod of its surrounding four dim spots. The short-exposure image recorded by a high speed video camera shows that the dim spot results from the surface discharges (SDs). The brightness of the central spot and is quite different from that of the dim spot, which indicates that the plasma states of the central spot and the dim spot may be differentiated. The optical emission spectrum method is used to further study the several plasma parameters of the central spot and the dim spot in different argon content. The emission spectra of the N₂ second positive band (C³IIu --> B³ IIg) are measured, from which the molecule vibration temperatures of the central spot and the dim spot are calculated respectively. The broadening of spectral line 696.57 nm (2P₂-->1S₅) is used to study the electron densities of the central spot and the dim spot. It is found that the molecule vibration temperature and electron density of the dim spot are higher than those of the central spot in the same argon content The molecule vibration temperature and electron density of the central spot and the dim spot increase with the argon content increasing from 90% to 99.9%. The surface discharge induced by the volume discharge (VD) has the determinative effect on the formation of the dim spot The experimental results above play an important role in studying the formation mechanism of surface discharg&of square super-lattice pattern with surface discharge. In addition, the studies exert an influence on the application of surface discharge and volume discharge in different fields.

  17. Diffusion and Evaporation-Controlled Emission in Ventilated Rooms

    DEFF Research Database (Denmark)

    Topp, Claus

    is proposed. The interest has been focused on the emission of vapours and gases as no particulate emissions have been considered. The methods used are numerical calculations by computational fluid dynamics (CFD) and full-scale laboratory experiments. It was found that the emission is a strong function of air...... change rate, local air velocity and local turbulence intensity as the mass transfer coefficient increases in proportion to these parameters. The experimental results moreover exhibit the behaviour of a diffusion-controlled emission process at the end of the experiments. A simplified version of the model...... proposed was applied to investigate the influence of source diffusion coefficient and air velocity on the concentration distribution. The findings show that the mass transfer coefficient increases in proportion to the velocity when the emission is controlled by evaporation from the surface. As to diffusion...

  18. Limitations on the use of scanning probe microscopy for the measurement of field emission from copper surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Mizuno, Y.

    2004-02-25

    High electric-field breakdown in cm-wave x-band radio frequency (rf) accelerating structures is an important phenomenon limiting attainable accelerating gradients. Linear collider development requires an accelerating gradient of, at least, 70MeV/m (150MV/m surface electric field). The observed breakdown sequence usually consists of field emission (FE) from an electrically-conducting surface feature which heats the point of emission, thereby releasing gas from the surface and nearby bulk. The ionized gas makes a plasma that regeneratively heats the metal and releases more gas and electrons (via secondary emission) until a flashover occurs. The FE, however, occurs at a much lower surface electric field in experiments than predicted by theory. Experimental measurements of FE from macroscopic surface areas require the use of a geometrical field-enhancement factor, {beta}, to fit best the data to a Fowler-Nordheim (F-N) emission model with reasonable physical parameters. A newer, microscopic interpretation of the results proposes the existence of quasi-filamentary electrically-conducting channels between the metal bulk and the surface. These channels connect to emitting features near or on the surface, acting as microscopically field-enhanced electron emission sources. Analysis of emitter behavior suggesting that the macroscopic emission should primarily be due to classical geometrical-enhancement is, at least in some cases, due to the presence of these conducting nano-structures in the surface region. We describe an accelerator materials-related study of high electric field breakdown from polished copper (and other) surfaces, in dry-nitrogen gas ambient, using an atomic force microscope (AFM) modified to make F-N FE measurements. In early periods of this work, the results showed that the instrument might be capable of making F-N measurements on small surface areas of mechanically-polished and natively-oxidized high-quality copper surfaces to the GV/m level. The

  19. The effect of MAO processing time on surface properties and low temperature infrared emissivity of ceramic coating on aluminium 6061 alloy

    Science.gov (United States)

    Al Bosta, Mohannad M. S.; Ma, Keng-Jeng; Chien, Hsi-Hsin

    2013-09-01

    MAO ceramic coatings were prepared on aluminium 6061 surfaces at different treating durations (10, 20, ... 60 min), using alkali silicate electrolyte and pulsed bipolar current mode. The surface microstructures and properties were studied using SEM, XRD, EDX and a surface roughness tester. Image-Pro Plus and MATCH! softwares were used to analyze SEM micrographs and XRD results, respectively. The infrared emissivities of the ceramic coatings were measured at the 70 °C using FTIR spectrometer. We found a linear correlation between the volcano-like area and the surface roughness. The compositions and phases were associated with the volcano-like population and area. The curve of IR spectral emissivity was influenced by surface roughness, γ-alumina, sillimanite and cristobalite phases. The emissivity was enhanced by the surface roughness in the ranges 4.0-9.6 μm and 10.5-14.8 μm. In the range 7.0-8.0 μm, α-alumina and sillimanite phases enhanced the emissivity, while the cristobalite has a negative impact to the emissivity. A negative contributions were found for α-alumina in the region 9.6-16.0 μm and for the surface thickness in the region 15.0-16.0 μm. Overall, the average of long wave infrared (LWIR) emissivity ranged from 87.05% to 91.65%.

  20. Measurements of average heat-transfer and friction coefficients for subsonic flow of air in smooth tubes at high surface and fluid temperatures

    Science.gov (United States)

    Humble, Leroy V; Lowdermilk, Warren H; Desmon, Leland G

    1951-01-01

    An investigation of forced-convection heat transfer and associated pressure drops was conducted with air flowing through smooth tubes for an over-all range of surface temperature from 535 degrees to 3050 degrees r, inlet-air temperature from 535 degrees to 1500 degrees r, Reynolds number up to 500,000, exit Mach number up to 1, heat flux up to 150,000 btu per hour per square foot, length-diameter ratio from 30 to 120, and three entrance configurations. Most of the data are for heat addition to the air; a few results are included for cooling of the air. The over-all range of surface-to-air temperature ratio was from 0.46 to 3.5.

  1. Spatial variability in nitrous oxide and methane emissions from beef cattle feedyard pen surfaces

    Science.gov (United States)

    Greenhouse gas emissions from beef cattle feedlots include enteric carbon dioxide and methane, and manure-derived methane, nitrous oxide and carbon dioxide. Enteric methane comprises the largest portion of the greenhouse gas footprint of beef cattle feedyards. For the manure component, methane is th...

  2. Kinetic electron emission due to perpendicular impact of carbon ions on tungsten surfaces

    Czech Academy of Sciences Publication Activity Database

    Lorinčík, Jan; Šroubek, Zdeněk; Brunmayr, M.; Kowarik, G.; Aumayr, F.

    2009-01-01

    Roč. 255, č. 12 (2009), s. 6303-6307 ISSN 0169-4332 Institutional research plan: CEZ:AV0Z20670512 Keywords : Kinetic electron emission * Carbon Subject RIV: JB - Sensors, Measurment, Regulation Impact factor: 1.616, year: 2009

  3. Kinetic electron emission from metal surfaces induced by impact of slow ions

    Czech Academy of Sciences Publication Activity Database

    Šroubek, Zdeněk; Lorinčík, Jan

    -, č. 625 (2014), s. 7-9 ISSN 0039-6028 R&D Projects: GA MŠk(CZ) ME10086 Institutional support: RVO:67985882 Keywords : Ion induced kinetic electron emission * Electronic excitation Subject RIV: JA - Electronics ; Optoelectronics, Electrical Engineering Impact factor: 1.925, year: 2014

  4. Thermal emission from particulate surfaces: A comparison of scattering models with measured spectra

    Science.gov (United States)

    Moersch, J. E.; Christensen, P. R.

    1995-01-01

    Emissivity spectra of particulate mineral samples are highly dependent on particle size when that size is comparable to the wavelength of light emitted (5-50 micrometers for the midinfrared). Proper geologic interpretation of data from planetary infrared spectrometers will require that these particle size effects be well understood. To address this issue, samples of quartz powders were produced with narrow, well-characterized particle size distributions. Mean particle diameters in these samples ranged from 15 to 227 micrometers. Emission spectra of these powders allow the first detailed comparison of the complex spectral variations with particle size observed in laboratory data with the predictions of radiative transfer models. Four such models are considered here. Hapke's relectance theory (converted to emissivity via Kirchoff's law) is the first model tested. Hapke's more recently published emission theory is also employed. The third model, the 'Mie/Conel' model, uses Mie single scattering with a two-stream approximation for multiple scattering. This model, like the first, is a converted reflec- tance model. Mie scattering assumes particles are both spherical and well separated, which is not true for the quartz powders, but includes diffraction effects. The fourth model uses the Mie solution for single scattering by spheres and inputs those results into the multiple scattering formalism of Hapke's emission theory. The results of the four models are considered in relation to the values of the optical constants n and k. We have grouped these as class 1 (k large), class 2 (k moderate, n is approximately 2), class 3 (k small, n is approximately 2), and class 4 (k small, n is approximately 1). In general, the Mie/Hapke hybrid model does best at predicting variations with grain size. In particular, it predicts changes of the correct pattern, although incorrect magnitude, for class 1 bands, where large increases in emissivity with decreasing grain size are observed

  5. Comparison of designing simple steel frame & coaxial brace systems by contrast of blast, using two methods of load & resistance coefficients & performance surfaces

    Directory of Open Access Journals (Sweden)

    P. Hassanvand

    2016-12-01

    Full Text Available Nowadays, because of the increasing terrorist attacks around the urban areas, designing buildings by contrast of resulted loads of blast came into consideration particularly in some sensitive buildings & vital arteries. When a blast occurs, the resulted emissions in environment leads to appearance of several penalties and endangers to the human life. Steel structures generally are designed on the basis of standard seismic and gravity loads, it is necessary to investigate the implantation of these structures under the impact of the loads originated from blast. This article presents numerical studies of two-dimensional structural models with 2 and 5 stories which are including simple steel frame system in addition to CBF. The models were analyzed by nonlinear dynamic analysis method using the instruction UFC 3-340-02 in two adverse levels of blast loads by SAP 2000 software. In this study structural models are designed and analyzed using two designing methods: the basic performance design, and Load and Resistance Factor Design (LRFD. Finally, two set of results are compared in detail.

  6. Application of Gauss's theorem to quantify localized surface emissions from airborne measurements of wind and trace gases

    Science.gov (United States)

    Conley, Stephen; Faloona, Ian; Mehrotra, Shobhit; Suard, Maxime; Lenschow, Donald H.; Sweeney, Colm; Herndon, Scott; Schwietzke, Stefan; Pétron, Gabrielle; Pifer, Justin; Kort, Eric A.; Schnell, Russell

    2017-09-01

    Airborne estimates of greenhouse gas emissions are becoming more prevalent with the advent of rapid commercial development of trace gas instrumentation featuring increased measurement accuracy, precision, and frequency, and the swelling interest in the verification of current emission inventories. Multiple airborne studies have indicated that emission inventories may underestimate some hydrocarbon emission sources in US oil- and gas-producing basins. Consequently, a proper assessment of the accuracy of these airborne methods is crucial to interpreting the meaning of such discrepancies. We present a new method of sampling surface sources of any trace gas for which fast and precise measurements can be made and apply it to methane, ethane, and carbon dioxide on spatial scales of ˜ 1000 m, where consecutive loops are flown around a targeted source region at multiple altitudes. Using Reynolds decomposition for the scalar concentrations, along with Gauss's theorem, we show that the method accurately accounts for the smaller-scale turbulent dispersion of the local plume, which is often ignored in other average mass balance methods. With the help of large eddy simulations (LES) we further show how the circling radius can be optimized for the micrometeorological conditions encountered during any flight. Furthermore, by sampling controlled releases of methane and ethane on the ground we can ascertain that the accuracy of the method, in appropriate meteorological conditions, is often better than 10 %, with limits of detection below 5 kg h-1 for both methane and ethane. Because of the FAA-mandated minimum flight safe altitude of 150 m, placement of the aircraft is critical to preventing a large portion of the emission plume from flowing underneath the lowest aircraft sampling altitude, which is generally the leading source of uncertainty in these measurements. Finally, we show how the accuracy of the method is strongly dependent on the number of sampling loops and/or time

  7. SAIL-Thermique: a model for land surface spectral emissivity in the thermal infrared. Evaluation and reassesment of the temperature - emissivity separation (TES) algorithm in presence of vegetation canopies.

    Science.gov (United States)

    Olioso, A.; Jacob, F.; Lesaignoux, A.

    2014-12-01

    The SAIL-Thermique model was developed to simulate thermal infrared (TIR) radiative transfers inside vegetation canopies and land surface emissivity. It is based on the SAIL model developed by Verhoef (1984) for simulating spectral reflectances in the solar domain. Due to the difficulty to measure land surface emissivity, no emissivity model was validated against ground measurements. In this study, several datasets extracted from the literature and from recent databases were used for evaluating emissivity simulations. Model simulations were performed from the knowledge of leaf area index, leaf inclination distribution, direction of viewing, and leaf and soil optical properties. As data on leaf inclination and leaf optical properties were usually not available, stochastic simulations were performed from a priori knowledges on their distribution (extracted from the literature and recent databases). Simulated 8-14 μm emissivities were favorably compared to measurements with a root mean square difference (RMSD) around 0.006 (0.004 when considering only herbaceous species). The model was then used for simulating emissivity spectra for providing information for the interpretation of TIR multispectral data from the ASTER sensor. We used the land surface emissivity simulations for re-assessing the TES algorithm used to separate emissivity and land surface temperature. We showed that the inclusion of vegetated land surfaces significantly modified the relationship between minimum emissivity and minimum maximum difference (ɛmin- MMD) which is at the heart of the TES algorithm. This relationship was originally established on the ASTER spectral library which did not include vegetated land surface (Schmugge et al. 1998). On a synthetic database, estimations of spectral emissivities and surface temperature were significantly improved when using the new ɛmin- MMD relationship in comparison to the classical one: RMSD dropped from ~0.012 to ~0.006 for spectral emissivity and from

  8. MODELING THE ANOMALY OF SURFACE NUMBER DENSITIES OF GALAXIES ON THE GALACTIC EXTINCTION MAP DUE TO THEIR FIR EMISSION CONTAMINATION

    Energy Technology Data Exchange (ETDEWEB)

    Kashiwagi, Toshiya; Suto, Yasushi; Taruya, Atsushi; Yahata, Kazuhiro [Department of Physics, The University of Tokyo, Tokyo 113-0033 (Japan); Kayo, Issha [Department of Physics, Toho University, Funabashi, Chiba 274-8510 (Japan); Nishimichi, Takahiro, E-mail: kashiwagi@utap.phys.s.u-tokyo.ac.jp [Institute for the Physics and Mathematics of the Universe, University of Tokyo, Kashiwa, Chiba 277-8568 (Japan)

    2015-02-01

    The most widely used Galactic extinction map is constructed assuming that the observed far-infrared (FIR) fluxes come entirely from Galactic dust. According to the earlier suggestion by Yahata et al., we consider how FIR emission of galaxies affects the SFD map. We first compute the surface number density of Sloan Digital Sky Survey (SDSS) DR7 galaxies as a function of the r-band extinction, A {sub r,} {sub SFD}. We confirm that the surface densities of those galaxies positively correlate with A {sub r,} {sub SFD} for A {sub r,} {sub SFD} < 0.1, as first discovered by Yahata et al. for SDSS DR4 galaxies. Next we construct an analytical model to compute the surface density of galaxies, taking into account the contamination of their FIR emission. We adopt a log-normal probability distribution for the ratio of 100 μm and r-band luminosities of each galaxy, y ≡ (νL){sub 100} {sub μm}/(νL) {sub r}. Then we search for the mean and rms values of y that fit the observed anomaly, using the analytical model. The required values to reproduce the anomaly are roughly consistent with those measured from the stacking analysis of SDSS galaxies. Due to the limitation of our statistical modeling, we are not yet able to remove the FIR contamination of galaxies from the extinction map. Nevertheless, the agreement with the model prediction suggests that the FIR emission of galaxies is mainly responsible for the observed anomaly. Whereas the corresponding systematic error in the Galactic extinction map is 0.1-1 mmag, it is directly correlated with galaxy clustering and thus needs to be carefully examined in precision cosmology.

  9. Ocean Surface Emissivity at L-band (1.4 GHz): The Dependence on Salinity and Roughness

    Science.gov (United States)

    LeVine, D. M.; Lang, R.; Wentz, F.; Messiner, T.

    2012-01-01

    A characterization of the emissivity of sea water at L-band is important for the remote sensing of sea surface salinity. Measurements of salinity are currently being made in the radio astronomy band at 1.413 GHz by ESA's Soil Moisture and Ocean Salinity (SMOS) mission and NASA's Aquarius instrument aboard the Aquarius/SAC-D observatory. The goal of both missions is accuracy on the order of 0.1 psu. This requires accurate knowledge of the dielectric constant of sea water as a function of salinity and temperature and also the effect of waves (roughness). The former determines the emissivity of an ideal (i.e. flat) surface and the later is the major source of error from predictions based on a flat surface. These two aspects of the problem of characterizing the emissivity are being addressed in the context of the Aquarius mission. First, laboratory measurements are being made of the dielectric constant of sea water. This is being done at the George Washington University using a resonant cavity. In this technique, sea water of known salinity and temperature is fed into the cavity along its axis through a narrow tube. The sea water changes the resonant frequency and Q of the cavity which, if the sample is small enough, can be related to the dielectric constant of the sample. An extensive set of measurements have been conducted at 1.413 GHz to develop a model for the real and imaginary part of the dielectric constant as a function of salinity and temperature. The results are compared to the predictions of models based on parameterization of the Debye resonance of the water molecule. The models and measurements are close; however, the differences are significant for remote sensing of salinity. This is especially true at low temperatures where the sensitivity to salinity is lowest.

  10. Impacts of population growth, urbanisation and sanitation changes on global human Cryptosporidium emissions to surface water

    NARCIS (Netherlands)

    Hofstra, Nynke; Vermeulen-Henstra, Lucie

    2016-01-01

    Cryptosporidium is a pathogenic protozoan parasite and is a leading cause of diarrhoea worldwide. The concentration of Cryptosporidium in the surface water is a determinant for probability of exposure and the risk of disease. Surface water concentrations are expected to change with population

  11. Nano-sized emission from commercially available paints used for indoor surfaces during drying.

    Science.gov (United States)

    Jørgensen, Rikke Bramming; Hveding, Ingrid Grav; Solheim, Karoline

    2017-12-01

    Consumers worry about the presence of nano-particles in paints and the risk of exposure. As a result, the paint industry now omits marketing paints as containing nanoparticles. The industry claims that no nanoparticles are released into the indoor environment; this, however, has yet to be documented. In this study, the emission of nano-sized emission from four indoor paints was investigated. The emission was studied for both base and full-pigmented versions of the paints, which consisted of three water-borne acrylic paints and one solvent-borne alkyd paint. All experiments were performed twice in a 6.783 m 3 stainless-steel test chamber under standardized conditions (22.98 °C, 50.08% RH, air exchange rate 0.48 h -1 ). Emissions during the paint-drying period were measured using a TSI Fast Mobility Particle Sizer (FMPS) measuring the number concentration of nano-particles and the size distribution in the range 5.6-560 nm. The results from the solvent-borne paint showed the highest concentration, with a mean concentration of 3.2·10 5 particles/cm 3 and a maximum of 1.4·10 6 particles/cm 3 . This paint also had the smallest particle size distribution, with 9.31 nm particles as the most dominant particle size. The results from this study showed that the exposure to nanoparticles for the residents evaluated over a 7 or 28 day period was low and that interior paints are probably not very important when it comes to identifying products that release nano-particles into indoor environments. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. Effect of fiber surface conditioning on the acoustic emission behavior of steel fiber reinforced concrete

    Science.gov (United States)

    Aggelis, D. G.; Soulioti, D. V.; Gatselou, E.; Barkoula, N. M.; Paipetis, A.; Matikas, T. E.

    2011-04-01

    The role of coating in preserving the bonding between steel fibers and concrete is investigated in this paper. Straight types of fibers with and without chemical coating are used in steel fiber reinforced concrete mixes. The specimens are tested in bending with concurrent monitoring of their acoustic emission activity throughout the failure process using two broadband sensors. The different stages of fracture (before, during and after main crack formation) exhibit different acoustic fingerprints, depending on the mechanisms that are active during failure (concrete matrix micro-cracking, macro-cracking and fiber pull out). Additionally, it was seen that the acoustic emission behaviour exhibits distinct characteristics between coated and uncoated fiber specimens. Specifically, the frequency of the emitted waves is much lower for uncoated fiber specimens, especially after the main fracture incident, during the fiber pull out stage of failure. Additionally, the duration and the rise time of the acquired waveforms are much higher for uncoated specimens. These indices are used to distinguish between tensile and shear fracture in concrete and suggest that friction is much stronger for the uncoated fibers. On the other hand, specimens with coated fibers exhibit more tensile characteristics, more likely due to the fact that the bond between fibers and concrete matrix is stronger. The fibers therefore, are not simply pulled out but also detach a small volume of the brittle concrete matrix surrounding them. It seems that the effect of chemical coating can be assessed by acoustic emission parameters additionally to the macroscopic measurements of ultimate toughness.

  13. Secondary ion emission from cleaned surfaces bombarded by 100 MeV accelerator beams at the GSI Darmstadt

    International Nuclear Information System (INIS)

    Wien, K.; Becker, O.; Guthier, W.; Knippelberg, W.; Koczon, P.

    1988-01-01

    The 1.4 MeV/n beam facility for the UNILAC/GSI has been used to study secondary ion emission from surfaces cleaned under UHV conditions by ion etching or cleaving of crystals. The desorption phenomena observed by means of TOF mass spectrometry can be classified as follows: (1) Clean metal surfaces emit metal ions being ejected by atomic collisions cascades. Electronic excitation of surface states seems to support ionization. (2) The desorption of contaminants adsorbed at the metal surface is strongly correlated with the electronic energy loss of the projectiles - even, if the content of impurities is very low. (3) Ion formation at the epitaxial surface of fluoride crystals as CaF 2 , MgF 2 and NaF is initiated by the electronic excitation of the crystal. At high beam energies the mass spectrum is dominated by a series of cluster ions. These cluster ions disappear below a certain energy deposit threshold, whereas small atomic ions are observed over the whole energy range

  14. Investigation on surface-plasmon-enhanced light emission of InGaN/GaN multiple quantum wells

    Science.gov (United States)

    Yu, Zhenzhong; Li, Qiang; Fan, Qigao; Zhu, Yixin

    2018-05-01

    We demonstrate surface-plasmon (SP) enhanced light emission from InGaN/GaN near ultraviolet (NUV) multiple quantum wells (MQWs) using Ag thin films and nano-particles (NPs). Two types of Ag NP arrays are fabricated on the NUV-MQWs, one is fabricated on p-GaN layer with three different sizes of about 120, 160 and 240 nm formed by self-assembled process, while the other is embedded close to the MQWs. In addition, the influence of the surface plasmon polariton (SPP) and localized surface plasmon (LSP) in NUV-MQWs has been investigated by photoluminescence (PL) measurement. Both PL measurements and theoretical simulation results show that the NUV light would be extracted more effectively under LSP mode than that of SPP mode. The highest enhancement of PL intensity is increased by 324% for the sample with NPs embedded in etched p-GaN near the MQWs as compared with the bare MQWs, also is about 1.24 times higher than the MQW sample covered with Ag NPs on the surface, indicating strong surface scattering and SP coupling between Ag NPs and NUV-MQWs.

  15. Calculation of illuminance distribution and its coefficient of variation in infinitely long interior with luminous surface ceiling by Monte Carlo simulation. Monte Carlo simulation ni yoru tenjomen kogen wo motsu mugencho shitsunal no shodo bunpu to hendo keisu

    Energy Technology Data Exchange (ETDEWEB)

    Nagata, M. (The University of Tokushima, Tokushima (Japan))

    1991-01-15

    Monte Carlo simulation (MCS) was applied to the estimation of illuminance distribution in infinitely long interiors which had visual obstructions and luminous surface ceilings, and its coefficient of variation (percentage of standard deviation to average value) was studied. The illuminance distributions obtained by MCS were compared with those calculated by theoretical equations hased on teh contour integration method, and the conservation law of photon bundles was also investigated. As a result, it was concluded that MCS results of direct illuminance distributions agree with those obtained by contour integration method in infinitely long concave interiors which have luminous surface ceilings of various shapes and four visual obstructions. The coefficient of variation varies noteworthily when visual obstructions are located in asymmetrical positions. The uniformity in illuminance distributions is improved by transparent visual obstructions. The conservation law of photon bundles holds well in the concave interiors with transparent visual obstructions. Therefore, it seems that MCS technique for illuminance calculation is a very powerful tool in infinite long concave interior spaces. 19 refs., 11 figs.

  16. The impact of climate and composition on playa surface roughness: Investigation of atmospheric mineral dust emission mechanisms

    Science.gov (United States)

    Tollerud, H. J.; Fantle, M. S.

    2011-12-01

    Atmospheric mineral dust has a wide range of impacts, including the transport of elements in geochemical cycles, health hazards from small particles, and climate forcing via the reflection of sunlight from dust particles. In particular, the mineral dust component of climate forcing is one of the most uncertain elements in the IPCC climate forcing summary. Mineral dust is also an important component of geochemical cycles. For instance, dust inputs to the ocean potentially affect the iron cycle by stimulating natural iron fertilization, which could then modify climate via the biological pump. Also dust can transport nutrients over long distances and fertilize nutrient-poor regions, such as island ecosystems or the Amazon rain forest. However, there are still many uncertainties in quantifying dust emissions from source regions. One factor that influences dust emission is surface roughness and texture, since a weak, unconsolidated surface texture is more easily ablated by wind than a strong, hard crust. We are investigating the impact of processes such as precipitation, groundwater evaporation, and wind on surface roughness in a playa dust source region. We find that water has a significant influence on surface roughness. We utilize ESA's Advanced Synthetic Aperture Radar (ASAR) instrument to measure roughness in the playa. A map of roughness indicates where the playa surface is smooth (on the scale of centimeters) and potentially very strong, and where it is rough and might be more sensitive to disturbance. We have analyzed approximately 40 ASAR observations of the Black Rock Desert from 2007-2011. In general, the playa is smoother and more variable over time relative to nearby areas. There is also considerable variation within the playa. While the playa roughness maps changed significantly between summers and between observations during the winters, over the course of each summer, the playa surface maintained essentially the same roughness pattern. This suggests that

  17. A Mouse Positron Emission Tomography Study of the Biodistribution of Gold Nanoparticles with Different Surface Coatings Using Embedded Copper-64

    DEFF Research Database (Denmark)

    Frellsen, Anders Floor; Hansen, Anders Elias; Jølck, Rasmus Irming

    2016-01-01

    By taking advantage of the ability of (64)Cu to bind non-specifically to gold surfaces, we have developed a new methodology to embed this radionuclide inside gold nanoparticles (AuNPs). (64)Cu enables the in vivo imaging of AuNPs by positron emission tomography (PET). AuNPs have a multitude of uses...... within health technology and are useful tools for general nanoparticle research. (64)Cu-AuNPs were prepared by incubating AuNP seeds with (64)Cu(2+), followed by the entrapment of the radionuclide by grafting a second layer of gold on the surface. This resulted in radiolabeling efficiencies of 53 ± 6...... to be superior to PEG. The new embedding method provides the utilization of PET imaging in combination with the multituide of uses that AuNPs have found in health technology, and the method can equally well be utilized for therapeutic copper radioisotopes for use in radiotherapy....

  18. Electron emission induced by resonant coherent ion-surface interaction at grazing incidence

    International Nuclear Information System (INIS)

    Garcia de Abajo, F.J.; Ponce, V.H.; Echenique, P.M.

    1992-01-01

    A new spectroscopy based on the resonant coherently induced electron loss to the continuum in ion-surface scattering under grazing incidence is proposed. A series of peaks, corresponding to the energy differences determined by the resonant interaction with the rows of atoms in the surface, is predicted to appear in the energy distribution of electrons emitted from electronic states bound to the probe. Calculations for MeV He + ions scattered at a W(001) surface along the left-angle 100 right-angle direction with a glancing angle of 0--2 mrad show a total yield close to 1

  19. Simultaneous and multi-point measurement of ammonia emanating from human skin surface for the estimation of whole body dermal emission rate.

    Science.gov (United States)

    Furukawa, Shota; Sekine, Yoshika; Kimura, Keita; Umezawa, Kazuo; Asai, Satomi; Miyachi, Hayato

    2017-05-15

    Ammonia is one of the members of odor gases and a possible source of odor in indoor environment. However, little has been known on the actual emission rate of ammonia from the human skin surface. Then, this study aimed to estimate the whole-body dermal emission rate of ammonia by simultaneous and multi-point measurement of emission fluxes of ammonia employing a passive flux sampler - ion chromatography system. Firstly, the emission fluxes of ammonia were non-invasively measured for ten volunteers at 13 sampling positions set in 13 anatomical regions classified by Kurazumi et al. The measured emission fluxes were then converted to partial emission rates using the surface body areas estimated by weights and heights of volunteers and partial rates of 13 body regions. Subsequent summation of the partial emission rates provided the whole body dermal emission rate of ammonia. The results ranged from 2.9 to 12mgh -1 with an average of 5.9±3.2mgh -1 per person for the ten healthy young volunteers. The values were much greater than those from human breath, and thus the dermal emission of ammonia was found more significant odor source than the breath exhalation in indoor environment. Copyright © 2017 Elsevier B.V. All rights reserved.

  20. Measurements of thermal accommodation coefficients.

    Energy Technology Data Exchange (ETDEWEB)

    Rader, Daniel John; Castaneda, Jaime N.; Torczynski, John Robert; Grasser, Thomas W.; Trott, Wayne Merle

    2005-10-01

    A previously-developed experimental facility has been used to determine gas-surface thermal accommodation coefficients from the pressure dependence of the heat flux between parallel plates of similar material but different surface finish. Heat flux between the plates is inferred from measurements of temperature drop between the plate surface and an adjacent temperature-controlled water bath. Thermal accommodation measurements were determined from the pressure dependence of the heat flux for a fixed plate separation. Measurements of argon and nitrogen in contact with standard machined (lathed) or polished 304 stainless steel plates are indistinguishable within experimental uncertainty. Thus, the accommodation coefficient of 304 stainless steel with nitrogen and argon is estimated to be 0.80 {+-} 0.02 and 0.87 {+-} 0.02, respectively, independent of the surface roughness within the range likely to be encountered in engineering practice. Measurements of the accommodation of helium showed a slight variation with 304 stainless steel surface roughness: 0.36 {+-} 0.02 for a standard machine finish and 0.40 {+-} 0.02 for a polished finish. Planned tests with carbon-nanotube-coated plates will be performed when 304 stainless-steel blanks have been successfully coated.

  1. Temperature and pressure dependent rate coefficients for the reaction of C2H4 + HO2 on the C2H4O2H potential energy surface.

    Science.gov (United States)

    Guo, JunJiang; Xu, JiaQi; Li, ZeRong; Tan, NingXin; Li, XiangYuan

    2015-04-02

    The potential energy surface (PES) for reaction C2H4 + HO2 was examined by using the quantum chemical methods. All rates were determined computationally using the CBS-QB3 composite method combined with conventional transition state theory(TST), variational transition-state theory (VTST) and Rice-Ramsberger-Kassel-Marcus/master-equation (RRKM/ME) theory. The geometries optimization and the vibrational frequency analysis of reactants, transition states, and products were performed at the B3LYP/CBSB7 level. The composite CBS-QB3 method was applied for energy calculations. The major product channel of reaction C2H4 + HO2 is the formation C2H4O2H via an OH(···)π complex with 3.7 kcal/mol binding energy which exhibits negative-temperature dependence. We further investigated the reactions related to this complex, which were ignored in previous studies. Thermochemical properties of the species involved in the reactions were determined using the CBS-QB3 method, and enthalpies of formation of species were compared with literature values. The calculated rate constants are in good agreement with those available from literature and given in modified Arrhenius equation form, which are serviceable in combustion modeling of hydrocarbons. Finally, in order to illustrate the effect for low-temperature ignition of our new rate constants, we have implemented them into the existing mechanisms, which can predict ethylene ignition in a shock tube with better performance.

  2. Sensitivity analysis of surface ozone to emission controls in Beijing and its neighboring area during the 2008 Olympic Games.

    Science.gov (United States)

    Gao, Yi; Zhang, Meigen

    2012-01-01

    The regional air quality modeling system RAMS (regional atmospheric modeling system)-CMAQ (community multi-scale air quality modeling system) is applied to analyze temporal and spatial variations in surface ozone concentration over Beijing and its surrounding region from July to October 2008. Comparison of simulated and observed meteorological elements and concentration of nitrogen oxides (NOx) and ozone at one urban site and three rural sites during Olympic Games show that model can generally reproduce the main observed feature of wind, temperature and ozone, but NOx concentration is overestimated. Although ozone concentration decreased during Olympics, high ozone episodes occurred on 24 July and 24 August with concentration of 360 and 245 microg/m3 at Aoyuncun site, respectively. The analysis of sensitive test, with and without emission controls, shows that emission controls could reduce ozone concentration in the afternoon when ozone concentration was highest but increase it at night and in the morning. The evolution of the weather system during the ozone episodes (24 July and 24 August) indicates that hot and dry air and a stable weak pressure field intensified the production of ozone and allowed it to accumulate. Process analysis at the urban site and rural site shows that under favorable weather condition on 24 August, horizontal transport was the main contributor of the rural place and the pollution from the higher layer would be transported to the surface layer. On 24 July, as the wind velocity was smaller, the impact of transport on the rural place was not obvious.

  3. Exoelectron emission from surface layer of Li2B4O7 glass ceramics

    International Nuclear Information System (INIS)

    Kawamoto, Takamichi; Katsube, Shizuko; Yanagisawa, Hideo; Kikuchi, Riichi; Kawanishi, Masaharu.

    1984-01-01

    The thermally stimulated exoelectron emission (TESS) of Li 2 B 4 O 7 glass ceramics was investigated for its application to the dosimetric use. It has been found the TSEE glow patterns of Li 2 B 4 O 7 glass ceramics and of the thin layer of LiF evaporated on Li 2 B 4 O 7 glass ceramics depend on the kind of radiations irradiated. The TSEE glow pattern of the duplicated structure sample indicated a possibility of determining the dose of each kind of radiation separately in the mixed radiation field. (author)

  4. Transcontinental Surface Validation of Satellite Observations of Enhanced Methane Anomalies Associated with Fossil Fuel Industrial Methane Emissions

    Science.gov (United States)

    Leifer, I.; Culling, D.; Schneising, O.; Bovensmann, H.; Buchwitz, M.; Burrows, J. P.

    2012-12-01

    A ground-based, transcontinental (Florida to California - i.e., satellite-scale) survey was conducted to understand better the role of fossil fuel industrial (FFI) fugitive emissions of the potent greenhouse gas, methane. Data were collected by flame ion detection gas chromatography (Fall 2010) and by a cavity ring-down sensor (Winter 2012) from a nearly continuously moving recreational vehicle, allowing 24/7 data collection. Nocturnal methane measurements for similar sources tended to be higher compared to daytime values, sometime significantly, due to day/night meteorological differences. Data revealed strong and persistent FFI methane sources associated with refining, a presumed major pipeline leak, and several minor pipeline leaks, a coal loading plant, and areas of active petroleum production. Data showed FFI source emissions were highly transient and heterogeneous; however, integrated over these large-scale facilities, methane signatures overwhelmed that of other sources, creating clearly identifiable plumes that were well elevated above ambient. The highest methane concentration recorded was 39 ppm at an active central valley California production field, while desert values were as low as 1.80 ppm. Surface methane data show similar trends with strong emissions correlated with FFI on large (4° bin) scales and positive methane anomalies centered on the Gulf Coast area of Houston, home to most of US refining capacity. Comparison with SCIAMACHY and GOSAT satellite data show agreement with surface data in the large-scale methane spatial patterns. Positive satellite methane anomalies in the southeast and Mexico largely correlated with methane anthropogenic and wetland inventory models suggests most strong ground methane anomalies in the Gulf of Mexico region were related to dominant FFI input for most seasons. Wind advection played a role, in some cases confounding a clear relationship. Results are consistent with a non-negligible underestimation of the FFI

  5. Discrepancies between soft x-ray emissivity contours and magnetic flux surfaces in Alcator C-Mod

    International Nuclear Information System (INIS)

    Borras, M.C.; Granetz, R.S.

    1996-01-01

    The soft x-ray diagnostic system of Alcator C-Mod, equipped with 152 detectors distributed in four arrays, is used to obtain iso-emissivity surfaces. These surfaces have been characterized by giving their elongation and relative shift from the centre of the tokamak as functions of plasma radius. Flux surfaces, provided by magnetic diagnostics, have also been described with elongation and shift. Results from the comparison of the two sets of geometric parameters obtained from magnetic and x-ray diagnostics are presented. We find that, whereas the shifts obtained from these two diagnostic methods are always in good agreement, the corresponding elongation curves show different patterns. An agreement between elongations better than 2% is only found in a range of about 2 cm in minor radius. On the other hand, the elongations can differ by 10% towards the plasma edge and the plasma centre. Error bars for the x-ray diagnostic are obtained by propagating the effect of ± 1% random errors at the detector signals, and can amount to ± 1-2% of the estimated values near the edge and the centre of the plasma. The estimated uncertainties in the determination of elongation from magnetic flux surfaces are of the order of 4%. A series of tests and simulations performed to verify the accuracy of the X-ray diagnostic system is presented. The discrepancies found could imply the existence of asymmetries in impurity concentration. (Author)

  6. Estimation of infarct size by three-dimensional surface display method of myocardial single photon emission CT with 201Tl

    International Nuclear Information System (INIS)

    Kubota, Masahiro; Tsuda, Takatoshi; Akiba, Hidenari; Morita, Kazuo; Hosoba, Minoru; Ban, Ryuichi; Hirano, Takako.

    1987-01-01

    To estimate infarct size, we devised three-dimensional (3D) surface display method of 201 Tl myocardial single photon emission CT (SPECT). The method was performed with maximum-count circumferential profiles (CPs) of short axis views of 201 Tl myocardial SPECT. The counts of maximum-count CP were put into a pixel line with the calculated left ventricular circumferential length on each short axis slice. A 3D-surface display map was created by arrangement of these pixel lines from apex to base of left ventricle in order. The sizes of defects in myocardial phantom were calculated by this method. There was a high correlation between the real defect sizes and the calculated defect sizes. In 6 patients with anterior myocardial infarction, the infarct sizes were calculated by this method. The extent of abnormality was identified by automatic computer comparison of each patient's profiles with corresponding lower limits of normal profiles. The infarct sizes calculated by 3D-surface display method were closely correlated not only with the infarct sizes calculated by summation of defect sizes in short axis views, but also with left ventricular ejection fractions. We concluded that the 3D-surface display method of 201 Tl myocardial SPECT is effective for noninvasive assessment of the extent of myocardial infarction. (author)

  7. Vicinage effects in energy loss and electron emission during grazing scattering of heavy molecular ions from a solid surface

    International Nuclear Information System (INIS)

    Song Yuanhong; Wang Younian; Miskovic, Z.L.

    2005-01-01

    Vicinage effects in the energy loss and the electron emission spectra are studied in the presence of Coulomb explosion of swift, heavy molecular ions, during their grazing scattering from a solid surface. The dynamic response of the surface is treated by means of the dielectric theory within the specular reflection model using the plasmon pole approximation for the bulk dielectric function, whereas the angle-resolved energy spectra of the electrons emitted from the surface are obtained on the basis of the first-order, time-dependent perturbation theory. The evolution of the charge states of the constituent ions in the molecule during scattering is described by a nonequilibrium extension of the Brandt-Kitagawa model. The molecule scattering trajectories and the corresponding Coulomb explosion dynamics are evaluated for the cases of the internuclear axis being either aligned in the beam direction or randomly oriented in the directions parallel to the surface. Our calculations show that the vicinage effect in the energy loss is generally weaker for heavy molecules than for light molecules. In addition, there is clear evidence of the negative vicinage effect in both the energy loss and the energy spectra of the emitted electrons for molecular ions at lower speeds and with the axis aligned in the direction of motion

  8. Transport Coefficients of Fluids

    CERN Document Server

    Eu, Byung Chan

    2006-01-01

    Until recently the formal statistical mechanical approach offered no practicable method for computing the transport coefficients of liquids, and so most practitioners had to resort to empirical fitting formulas. This has now changed, as demonstrated in this innovative monograph. The author presents and applies new methods based on statistical mechanics for calculating the transport coefficients of simple and complex liquids over wide ranges of density and temperature. These molecular theories enable the transport coefficients to be calculated in terms of equilibrium thermodynamic properties, and the results are shown to account satisfactorily for experimental observations, including even the non-Newtonian behavior of fluids far from equilibrium.

  9. Surface morphology evolution with fabrication parameters of ZnO nanowires toward emission properties enhancement

    Science.gov (United States)

    Belhaj, Marwa; Dridi, Cherif; Habba, Yamina Ghozlene; Capo-Chichi, Martine; Leprince-Wang, Yamin

    2017-12-01

    ZnO nanowire (NW) arrays were successfully grown on pre-seeded indium Tin oxide (ITO)-coated glass substrate using hydrothermal synthesis. Herein, the effects of ZnO seed layer density on the performance of ZnO NWs were investigated in details. The orientation and the dimension of ZnO NWs were found to depend on seeded substrate density as shown by scanning electron microscopy (SEM) micrographs which revealed that the typical morphology with the most uniform size can be obtained. From the X-ray diffraction (XRD) measurement, it can be seen that hexagonal c -axis oriented NWs were grown. The resonant Raman scattering was also investigated in details. It confirmed the wurtzite structure of the NW arrays and expected for good optical properties. The optical band gaps of synthesized ZnO NWs were found to decrease comparing to bulk ZnO and as function of seed layer. The photoluminescence (PL) spectra at room temperature have shown strong UV excitonic emission and weak deep-level emissions which reveal that the as-grown NW arrays have good optical properties with limited deep-level defects.

  10. Modelling the impact of sanitation, population growth and urbanization on human emissions of cryptosporidium to surface waters : A case study for Bangladesh and India

    NARCIS (Netherlands)

    Vermeulen, L.C.; Kraker, J.; Hofstra, N.; Kroeze, C.; Medema, G.

    2015-01-01

    Cryptosporidium is a protozoan parasite that can cause diarrhoea. Human faeces are an important source of Cryptosporidium in surface waters. We present a model to study the impact of sanitation, urbanization and population growth on human emissions of Cryptosporidium to surface waters. We build on a

  11. Modelling the impact of sanitation, population growth and urbanization on human emissions of Cryptosporidium to surface waters—a case study for Bangladesh and India

    NARCIS (Netherlands)

    Vermeulen, L.C.; Kraker, Dummy; Hofstra, N.; Kroeze, C.; Medema, G.J.

    2015-01-01

    Cryptosporidium is a protozoan parasite that can cause diarrhoea. Human faeces are an important source of Cryptosporidium in surface waters. We present a model to study the impact of sanitation, urbanization and population growth on human emissions of Cryptosporidium to surface waters. We build on a

  12. Kinetic Electron Emission from Higly Oriented Pyrolytic Graphite Surfaces Induced by Singly Charged Ions

    Czech Academy of Sciences Publication Activity Database

    Cernusca, S.; Diem, A.; Winter, H. P.; Aumayr, F.; Lörinčík, Jan; Šroubek, Zdeněk

    2002-01-01

    Roč. 193, - (2002), s. 616-620 ISSN 0168-583X Institutional research plan: CEZ:AV0Z4040901 Keywords : clean metal-surface * slow * polycrystalline gold Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 1.158, year: 2002

  13. Parametric exponentially correlated surface emission model for L-band passive microwave soil moisture retrieval

    Science.gov (United States)

    Surface soil moisture is an important parameter in hydrology and climate investigations. Current and future satellite missions with L-band passive microwave radiometers can provide valuable information for monitoring the global soil moisture. A factor that can play a significant role in the modeling...

  14. Surface roughness-aided hard X-ray emission from carbon nanotubes

    Indian Academy of Sciences (India)

    A clear enhancement in the low to moderately high-energy. X-rays has been noticed. In this report, we present a highly efficient, low-debris hard X-ray source based on multiwalled carbon nanotubes (MWNT) irradiated by intense, femtosecond laser. In the process we also demonstrate the critical role of surface roughness ...

  15. Thermal Emission Spectra of Silica-coated Basalt and Considerations for Martian Surface Mineralogy

    Science.gov (United States)

    Kraft, M. D.; Sharp, T. G.; Michalski, J. R.

    2003-01-01

    Among the most important discoveries made during the Mars Global Surveyor (MGS) mission was that the rocky materials of Mars are broadly divisible into two distinct rock types. The geological significance of this finding is dependent on the mineralogy of these rock types as well as their geographic and stratigraphic positions. Much work has yet to be done to understand these relationships and the small-scale variability of these units. For now, it is worth considering various scenarios that could have resulted in Mars global-scale mineralogical dichotomy. Such work will make clearer what must be looked for in Thermal Emission Spectrometer (TES) and Thermal Imaging Spectrometer (THEMIS) data, what to test with other data sets, and what geological processes can be considered or ruled out as we advance with interpreting Martian geologic history. Here, we suggest that exogenic coatings of secondary silica on basaltic rocks may provide a plausible explanation for the newly discovered distribution of rock types.

  16. Discovery of megaparsec-scale, low surface brightness nonthermal emission in merging galaxy clusters using the green bank telescope

    Energy Technology Data Exchange (ETDEWEB)

    Farnsworth, Damon; Rudnick, Lawrence [Minnesota Institute for Astrophysics, University of Minnesota, 116 Church Street S.E., Minneapolis, MN 55455 (United States); Brown, Shea [Department of Physics and Astronomy, University of Iowa, 203 Van Allen Hall, Iowa City, IA 52242 (United States); Brunetti, Gianfranco [INAF/Istituto di Radioastronomia, via Gobetti 101, I-40129 Bologna (Italy)

    2013-12-20

    We present results from a study of 12 X-ray bright clusters at 1.4 GHz with the 100 m Green Bank Telescope. After subtraction of point sources using existing interferometer data, we reach a median (best) 1σ rms sensitivity level of 0.01 (0.006) μJy arcsec{sup –2}, and find a significant excess of diffuse, low surface brightness emission in 11 of 12 Abell clusters observed. We also present initial results at 1.4 GHz of A2319 from the Very Large Array. In particular, we find: (1) four new detections of diffuse structures tentatively classified as two halos (A2065, A2069) and two relics (A2067, A2073); (2) the first detection of the radio halo in A2061 at 1.4 GHz, which qualifies this as a possible ultra-steep spectrum halo source with a synchrotron spectral index of α ∼ 1.8 between 327 MHz and 1.4 GHz; (3) a ∼2 Mpc radio halo in the sloshing, minor-merger cluster A2142; (4) a >2× increase of the giant radio halo extent and luminosity in the merging cluster A2319; (5) a ∼7× increase to the integrated radio flux and >4× increase to the observed extent of the peripheral radio relic in A1367 to ∼600 kpc, which we also observe to be polarized on a similar scale; (6) significant excess emission of ambiguous nature in three clusters with embedded tailed radio galaxies (A119, A400, A3744). Our radio halo detections agree with the well-known X-ray/radio luminosity correlation, but they are larger and fainter than current radio power correlation studies would predict. The corresponding volume-averaged synchrotron emissivities are 1-2 orders of magnitude below the characteristic value found in previous studies. Some of the halo-like detections may be some type of previously unseen, low surface brightness radio halo or blend of unresolved shock structures and sub-Mpc-scale turbulent regions associated with their respective cluster merging activity. Four of the five tentative halos contain one or more X-ray cold fronts, suggesting a possible connection between gas

  17. Friction coefficient dependence on electrostatic tribocharging.

    Science.gov (United States)

    Burgo, Thiago A L; Silva, Cristiane A; Balestrin, Lia B S; Galembeck, Fernando

    2013-01-01

    Friction between dielectric surfaces produces patterns of fixed, stable electric charges that in turn contribute electrostatic components to surface interactions between the contacting solids. The literature presents a wealth of information on the electronic contributions to friction in metals and semiconductors but the effect of triboelectricity on friction coefficients of dielectrics is as yet poorly defined and understood. In this work, friction coefficients were measured on tribocharged polytetrafluoroethylene (PTFE), using three different techniques. As a result, friction coefficients at the macro- and nanoscales increase many-fold when PTFE surfaces are tribocharged, but this effect is eliminated by silanization of glass spheres rolling on PTFE. In conclusion, tribocharging may supersede all other contributions to macro- and nanoscale friction coefficients in PTFE and probably in other insulating polymers.

  18. Effect of system variables involved in packed column SFC of nevirapine as model analyte using response surface methodology: application to retention thermodynamics, solute transfer kinetic study and binary diffusion coefficient determination.

    Science.gov (United States)

    Kaul, Neerej; Agrawal, Himani; Paradkar, A R; Mahadik, K R

    2005-08-31

    A multifactor optimization technique is successfully applied to study the effect of simultaneously varying the system variables on feasibility of nevirapine analysis by packed column supercritical fluid chromatography (PC-SFC). The optimal conditions were determined with the aid of the response surface methodology using 3(3) factorial designs. The method is based on methanol-modified carbon dioxide as the mobile phase at flow rate of 3.0 ml/min with elution through a JASCO Finepak SIL-5, [C18 (5-micron, 25 cm x 4.6 mm, i.d.)] column using photodiode array detection. The method has been successfully used to analyze commercial solid dosage form to assess the chromatographic performance of SFC system. The present work briefs the thermodynamic applications of PC-SFC with an emphasis on the results of nevirapine. The foremost of such applications is the determination of solute diffusion coefficient in supercritical mobile phase by Taylor-Aris peak broadening technique.

  19. The application of rational approximation in the calculation of a temperature field with a non-linear surface heat-transfer coefficient during quenching for 42CrMo steel cylinder

    Science.gov (United States)

    Cheng, Heming; Huang, Xieqing; Fan, Jiang; Wang, Honggang

    1999-10-01

    The calculation of a temperature field has a great influence upon the analysis of thermal stresses and stains during quenching. In this paper, a 42CrMo steel cylinder was used an example for investigation. From the TTT diagram of the 42CrMo steel, the CCT diagram was simulated by mathematical transformation, and the volume fraction of phase constituents was calculated. The thermal physical properties were treated as functions of temperature and the volume fraction of phase constituents. The rational approximation was applied to the finite element method. The temperature field with phase transformation and non-linear surface heat-transfer coefficients was calculated using this technique, which can effectively avoid oscillationin the numerical solution for a small time step. The experimental results of the temperature field calculation coincide with the numerical solutions.

  20. Directional Thermal Emission and Absorption from Surface Microstructures in Metalized Plastics

    Science.gov (United States)

    2013-09-01

    directional thermal emitter with enhanced surface durability due to its extended metal deposition thickness. 1.3.3 Dual-Cavity-Width Structure Design...crystals. The definition is applied to one-dimensionally periodic stacks, two-dimensionally periodic slabs , and three- dimensionally periodic complex...sufficiently to significantly effect the film durability and thermal conductivity, the profile of the cavity begins to change shape. Although a case

  1. Surface plasmon-enhanced amplified spontaneous emission from organic single crystals by integrating graphene/copper nanoparticle hybrid nanostructures.

    Science.gov (United States)

    Li, Yun-Fei; Feng, Jing; Dong, Feng-Xi; Ding, Ran; Zhang, Zhen-Yu; Zhang, Xu-Lin; Chen, Yang; Bi, Yan-Gang; Sun, Hong-Bo

    2017-12-14

    Organic single crystals have attracted great attention because of their advantages such as high carrier mobility and high thermal stability. Amplified spontaneous emission (ASE) is an important parameter for the optoelectronic applications of organic single crystals. Here, surface plasmon-enhanced ASE from the organic single crystals has been demonstrated by integrating graphene/copper nanoparticle (Cu NP) hybrid nanostructures. Graphene is fully accommodating to the topography of Cu NPs by the transfer-free as-grown method for the configuration of the hybrid nanostructures, which makes full electrical contact and strong interactions between graphene and the local electric field of surface plasmon resonances. The enhanced localized surface plasmon resonances induced by the hybrid nanostructures result in an enhanced intensity and lowered threshold of ASE from the organic single crystals. Moreover, the as-grown graphene sheets covering fully and uniformly on the Cu NPs act as a barrier against oxidation, and results in an enhanced stability of the fluorescence from the crystals.

  2. MeV surface fast electron emission from femtosecond laser pulses interacting with planar and nanowire targets

    Science.gov (United States)

    Tian, Ye; Liu, Jiansheng; Wang, Wentao; Wang, Cheng; Lu, Xiaoming; Leng, Yuxin; Liang, Xiaoyan; Li, Ruxin; Xu, Zhizhan

    2014-07-01

    The mechanics of generating MeV target surface fast electrons (SFEs) is investigated using a 5 J, 50 fs laser pulse focused on a Cu planar and nanowire target. The energy spectrum and spatial angular distribution of fast electrons emitted from the planar target are determined and compared with those from the nanowire target. When the laser intensity reaches 1 × 1019 W cm-2, the coupling from the laser to 1-3 MeV electrons reaches 1.1% on the planar target at a 45° incidence angle, while the number of SFEs generated from the nanowire target is about 10% of those from the planar target. The two-dimensional particle-in-cell simulation results reproduce the electron emission characteristics and reveal a strong continuous surface magnetic field on the surface of the planar target as compared with the discrete magnetic field on the nanowire target which decreases SFEs. A high, hot electron temperature in the forward direction at 556keV is achieved for the nanowire structure capable of guiding and confining fast electrons along the wire direction, compared with 178keV for the planar target.

  3. Molecular projectile effects for kinetic electron emission from carbon- and metal-surfaces bombarded by slow hydrogen ions

    CERN Document Server

    Cernusca, S; Aumayr, F; Diez-Muino, R; Juaristi, J I

    2003-01-01

    Total yields for kinetic electron emission (KE) have been determined for impact of hydrogen monomer-, dimer- and trimer-ions (impact energy <10 keV) on atomically clean surfaces of carbon-fiber inforced graphite used as first-wall armour in magnetic fusion devices. The data are compared with KE yields for impact of same projectile ions on atomically clean highly oriented pyrolytic graphite and polycrystalline gold. We discuss KE yields for the different targets if bombarded by equally fast molecular and atomic ions in view to 'projectile molecular effects' (different yields per proton for equally fast atomic and molecular ions), which are expected from calculated electronic projectile energy losses in these target materials.

  4. Molecular projectile effects for kinetic electron emission from carbon- and metal-surfaces bombarded by slow hydrogen ions

    International Nuclear Information System (INIS)

    Cernusca, S.; Winter, H.P.; Aumayr, F.; Diez Muino, R.; Juaristi, J.I.

    2003-01-01

    Total yields for kinetic electron emission (KE) have been determined for impact of hydrogen monomer-, dimer- and trimer-ions (impact energy <10 keV) on atomically clean surfaces of carbon-fiber inforced graphite used as first-wall armour in magnetic fusion devices. The data are compared with KE yields for impact of same projectile ions on atomically clean highly oriented pyrolytic graphite and polycrystalline gold. We discuss KE yields for the different targets if bombarded by equally fast molecular and atomic ions in view to 'projectile molecular effects' (different yields per proton for equally fast atomic and molecular ions), which are expected from calculated electronic projectile energy losses in these target materials

  5. Triple layered core–shell structure with surface fluorinated ZnO-carbon nanotube composites and its electron emission properties

    International Nuclear Information System (INIS)

    Wang, H.Y.; Chua, Daniel H.C.

    2013-01-01

    Highlights: ► The effects of CF 4 plasma on ZnO-CNT core–shell structures were studied. ► ZnO was effective in protecting the aligned CNTs core for as long as 30 min of plasma etching. ► SEM showed the surface morphology was nearly similar between pristine, 2 min and 30 min plasma etched specimens. ► F was observed to displace O in ZnO. ► This is the first report of an ultra long plasma etch of fluorine onto ZnO surface. - Abstract: Core-shelled structures such as zinc oxide (ZnO) on carbon nanotubes (CNTs) give rise to interesting material properties. In this work, a triple-layered core–shell–shell structure is presented where the effects of fluorine (F) incorporation on the outmost shell of the ZnO-CNT structure are studied. The samples prepared ranged from a short 2 min to a 30 min immersion in carbon tetraflouride (CF 4 ) plasma. In addition, its effects on the electron emission properties also studied and it is shown that the plasma immersions create thinner field emitters with sharp tiny wrinkles giving rise to more electron emission sites and higher enhancement factor. In addition, X-ray photoelectron spectroscopy measurements showed that F ions replace O in ZnO coatings during immersion process, thus increasing the electrical conductivity and shifts the Fermi level of ZnO upwards. Both physical and electronic effects further contribute to a lower threshold field.

  6. Assessment of the Effects of Total Emission Control Policies on Surface Water Quality in China: 2004 to 2014.

    Science.gov (United States)

    Liu, Xia; Feng, Jianfeng; Qiao, Yinhuan; Wang, Yuqiu; Zhu, Lin

    2017-05-01

    Water quality deterioration is a problem throughout the globe, especially in China. The Chinese government established national total emission control (TEC) policies related to the nation's surface water quality over the past 10 yr to restore, protect, and promote healthy water quality. The objective of this study is to evaluate the effects of China's TEC policies by analyzing three water quality constituents (ammonium nitrogen [NH-N], dissolved oxygen [DO], and the permanganate index [COD]) at 73 monitoring stations, which account for most of the surface waters of eastern China. The seasonal Mann-Kendall test revealed that approximately 60, 50, and 65% of stations had nonsignificant trends for COD, NH-N, and DO, respectively. Concentrations of COD and NH-N significantly (α = 0.05) decreased by 27.4 and 38.4% at the monitoring stations over the 11-yr study period, whereas DO significantly (α = 0.05) increased by 24.7%. Correlation analysis indicated that the water quality improved at approximately 30% (COD) and 20% (NH-N) of monitoring sites with the reduction of water pollutant emissions from industrial sources. A seasonal pattern was observed for the three water quality parameters at most of the stations but not at a regional scale. Results also indicated that COD concentrations decreased significantly (α = 0.05) at most river stations but increased significantly (α = 0.05) at nearly all lake stations, suggesting that TEC in China might be more effective for rivers than for lakes and reservoirs. Although there are many nonsignificant relationships with the water quality constituents selected as top pollutants in China, a few noticeable significant relationships were established. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  7. ASOS Surface Extinction Coefficient by STI

    Data.gov (United States)

    Washington University St Louis — ASOS_STI represents a 250-station subset of the national ASOS SURF_MET dataset. The unique feature of this data is that the visibility sensor values are available in...

  8. Estimating source-attributable health impacts of ambient fine particulate matter exposure: global premature mortality from surface transportation emissions in 2005

    International Nuclear Information System (INIS)

    Chambliss, S E; Zeinali, M; Minjares, R; Silva, R; West, J J

    2014-01-01

    Exposure to ambient fine particular matter (PM 2.5 ) was responsible for 3.2 million premature deaths in 2010 and is among the top ten leading risk factors for early death. Surface transportation is a significant global source of PM 2.5 emissions and a target for new actions. The objective of this study is to estimate the global and national health burden of ambient PM 2.5 exposure attributable to surface transportation emissions. This share of health burden is called the transportation attributable fraction (TAF), and is assumed equal to the proportional decrease in modeled ambient particulate matter concentrations when surface transportation emissions are removed. National population-weighted TAFs for 190 countries are modeled for 2005 using the MOZART-4 global chemical transport model. Changes in annual average concentration of PM 2.5 at 0.5 × 0.67 degree horizontal resolution are based on a global emissions inventory and removal of all surface transportation emissions. Global population-weighted average TAF was 8.5 percent or 1.75 μg m −3 in 2005. Approximately 242 000 annual premature deaths were attributable to surface transportation emissions, dominated by China, the United States, the European Union and India. This application of TAF allows future Global Burden of Disease studies to estimate the sector-specific burden of ambient PM 2.5 exposure. Additional research is needed to capture intraurban variations in emissions and exposure, and to broaden the range of health effects considered, including the effects of other pollutants. (letter)

  9. Summertime state-level source-receptor relationships between nitrogen oxides emissions and surface ozone concentrations over the continental United States.

    Science.gov (United States)

    Tong, Daniel Q; Mauzerall, Denise L

    2008-11-01

    Interstate transport of ozone (O3) and its precursors can contribute substantially to state-level surface o3 concentrations, making it difficult for some states to meet the National Ambient Air Quality Standards (NAAQS) for O3 by limiting only their own emissions. We analyze the effect of interstate transport on surface O3 in each continental U.S. state in July 1996 using the community multiscale air quality (CMAQ) model. By examining the difference between a baseline simulation and perturbation simulations in which each state's nitrogen oxides (NOx) emissions are removed, we establish for the first time a summertime source-receptor matrix for all 48 continental states. We find that for 16 (20) states at least one neighboring state's NOx emissions are responsible for a larger increase in monthly mean peak 8 h (all-hour) O3 concentrations than the state's own emissions. For over 80% of the contiguous states, interstate transport is more importantthan local emissions for summertime peak O3 concentrations. Our source-receptor matrices indicate that the geographic range of the clean air interstate rule (CAIR) was sufficient to address interstate transport of O3 in most of the states included in the program. However, the exclusion of Texas, which has particularly large NOx emissions, from the CAIR O3 program left emission sources uncontrolled that contribute more than 1 ppbv to the July mean of peak 8 h O3 concentrations in over a dozen states.

  10. Bloch Surface Waves for MoS2 Emission Coupling and Polariton Systems

    Directory of Open Access Journals (Sweden)

    Giovanni Lerario

    2017-11-01

    Full Text Available Due to their extraordinary quality factor and extreme sensitivity to surface perturbations, Bloch surface waves (BSW have been widely investigated for sensing applications so far. Over the last few years, on-chip control of optical signals through BSW has experienced a rapidly-expanding interest in the scientific community, attesting to BSW’s position at the forefront towards on-chip optical operations. The backbone of on-chip optical devices requires the choice of integrated optical sources with peculiar optic/optoelectronic properties, the efficient in-plane propagation of the optical signal and the possibility to dynamic manipulate the signal through optical or electrical driving. In this paper, we discuss our approach in addressing these requirements. Regarding the optical source integration, we demonstrate the possibility to couple the MoS2 mono- and bi-layers emission—when integrated on top of a 1D photonic crystal—to a BSW. Afterward, we review our results on BSW-based polariton systems (BSWP. We show that the BSWPs combine long-range propagation with energy tuning of their dispersion through polariton–polariton interactions, paving the way for logic operations.

  11. Normal emission photoelectron diffraction: a new technique for determining surface structure

    International Nuclear Information System (INIS)

    Kevan, S.D.

    1980-05-01

    One technique, photoelectron diffraction (PhD) is characterized. It has some promise in surmounting some of the problems of LEED. In PhD, the differential (angle-resolved) photoemission cross-section of a core level localized on an adsorbate atom is measured as a function of some final state parameter. The photoemission final state consists of two components, one of which propagates directly to the detector and another which scatters off the surface and then propagates to the detector. These are added coherently, and interference between the two manifests itself as cross-section oscillations which are sensitive to the local structure around the absorbing atom. We have shown that PhD deals effectively with two- and probably also three-dimensionally disordered systems. Its non-damaging and localized, atom-specific nature gives PhD a good deal of promise in dealing with molecular overlayer systems. It is concluded that while PhD will never replace LEED, it may provide useful, complementary and possibly also more accurate surface structural information

  12. Passive wireless surface acoustic wave sensors for monitoring sequestration sites CO2 emission

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yizhong [Univ. of Pittsburgh, PA (United States); Chyu, Minking [Univ. of Pittsburgh, PA (United States); Wang, Qing-Ming [Univ. of Pittsburgh, PA (United States)

    2013-02-14

    University of Pittsburgh’s Transducer lab has teamed with the U.S. Department of Energy’s National Energy Technology Laboratory (DOE NETL) to conduct a comprehensive study to develop/evaluate low-cost, efficient CO2 measuring technologies for geological sequestration sites leakage monitoring. A passive wireless CO2 sensing system based on surface acoustic wave technology and carbon nanotube nanocomposite was developed. Surface acoustic wave device was studied to determine the optimum parameters. Delay line structure was adopted as basic sensor structure. CNT polymer nanocomposite was fabricated and tested under different temperature and strain condition for natural environment impact evaluation. Nanocomposite resistance increased for 5 times under pure strain, while the temperature dependence of resistance for CNT solely was -1375ppm/°C. The overall effect of temperature on nanocomposite resistance was -1000ppm/°C. The gas response of the nanocomposite was about 10% resistance increase under pure CO2 . The sensor frequency change was around 300ppm for pure CO2 . With paralyne packaging, the sensor frequency change from relative humidity of 0% to 100% at room temperature decreased from over 1000ppm to less than 100ppm. The lowest detection limit of the sensor is 1% gas concentration, with 36ppm frequency change. Wireless module was tested and showed over one foot transmission distance at preferred parallel orientation.

  13. Indirect global warming effects of ozone and stratospheric water vapor induced by surface methane emission

    International Nuclear Information System (INIS)

    Wuebbles, D.J.; Grossman, A.S.; Tamaresis, J.S.; Patten, K.O. Jr.; Jain, A.; Grant, K.A.

    1994-07-01

    Methane has indirect effects on climate due to chemical interactions as well as direct radiative forcing effects as a greenhouse gas. We have calculated the indirect, time-varying tropospheric radiative forcing and GWP of O 3 and stratospheric H 2 O due to an impulse of CH 4 . This impulse, applied to the lowest layer of the atmosphere, is the increase of the atmospheric mass of CH 4 resulting from a 25 percent steady state increase in the current emissions as a function of latitude. The direct CH 4 radiative forcing and GWP are also calculated. The LLNL 2-D radiative-chemistry-transport model is used to evaluate the resulting changes in the O 3 , H 2 O and CH 4 atmospheric profiles as a function of time. A correlated k-distribution radiative transfer model is used to calculate the radiative forcing at the tropopause of the globally-averaged atmosphere profiles. The O 3 indirect GWPs vary from ∼27 after a 20 yr integration to ∼4 after 500 years, agreeing with the previous estimates to within about 10 percent. The H 2 O indirect GWPs vary from ∼2 after a 20 yr integration to ∼0.3 after 500 years, and are in close agreement with other estimates. The CH 4 GWPs vary from ∼53 at 20 yrs to ∼7 at 500 yrs. The 20 year CH 4 GWP is ∼20% larger than previous estimates of the direct CH 4 GWP due to a CH 4 response time (∼17 yrs) that is much longer than the overall lifetime (10 yrs). The increased CH 4 response time results from changes in the OH abundances caused by the CH 4 impulse. The CH 4 radiative forcing results are consistent with IPCC values. Estimates are made of latitude effects in the radiative forcing calculations, and UV effects on the O 3 radiative forcing calculations (10%)

  14. Study of electronic field emission from large surfaces under static operating conditions and hyper-frequency; Etude de l'emision electronique par effet de champ sur des surfaces larges en regime statique et hyperfrequence

    Energy Technology Data Exchange (ETDEWEB)

    Luong, M

    1997-09-01

    The enhanced electronic field emission from large area metallic surfaces lowers performances of industrial devices that have to sustain high electric field under vacuum. Despite of numerous investigations in the past, the mechanisms of such an emission have never been well clarified. Recently, research in our laboratory has pointed out the importance played by conducting sites (particles and protrusions). A refined geometrical model, called superposed protrusions model has been proposed to explain the enhanced emission by local field enhancement. As a logical continuation, the present work aims at testing this model and, in the same time, investigating the means to suppress the emission where it is undesirable. Thus, we have showed: the cause of current fluctuations in a continuous field regime (DC), the identity of emission characteristics ({beta}, A{sub e}) in both radiofrequency (RF) and DC regimes, the effectiveness of a thermal treatment by extern high density electronic bombardment, the effectiveness of a mechanical treatment by high pressure rinsing with ultra pure water, the mechanisms and limits of an in situ RF processing. Furthermore, the electronic emission from insulating particles has also been studied concurrently with a spectral analysis of the associated luminous emission. Finally, the refined geometrical model for conducting sites is reinforced while another model is proposed for some insulating sites. Several emission suppressing treatments has been explored and validated. At last, the characteristic of a RF pulsed field emitted electron beam has been checked for the first time as a possible application of such a field emission. (author)

  15. The ion- and atom-induced secondary electron emission yield: numerical study for the effect of clean and dirty cathode surfaces

    International Nuclear Information System (INIS)

    Bogaerts, Annemie; Gijbels, Renaat

    2002-01-01

    The effect of the ion- and atom-induced secondary electron emission yields for both 'clean' and 'dirty' cathode surfaces is investigated by means of a hybrid model, for typical conditions used in analytical direct current glow discharges (i.e. a pressure of 50-100 Pa, a voltage of 600-1200 V, and an electrical current of 1-10 mA). The hybrid model consists of a number of Monte Carlo models for fast electrons, fast argon ions and atoms in the cathode dark space, and sputtered copper atoms, a fluid model for slow electrons and argon ions, and a heat transfer model to calculate the gas temperature. For clean surfaces, secondary electron emission is almost exclusively attributed to argon ions, at the conditions under study. For dirty surfaces, on the other hand, fast argon ions and atoms contribute each about 50% to secondary electron emission, at the same discharge conditions. A so-called 'apparent' secondary electron emission yield (i.e. per bombarding ion) is determined for the range of conditions under study. This value for clean surfaces was found equal to 0.07 for argon on a copper cathode, at all conditions investigated; for dirty surfaces, this value was always higher than 0.07 and it strongly depends on the discharge conditions. With these data, current-voltage-pressure characteristics have been calculated for both clean and dirty surfaces, and compared to experimental data. The absolute current values differ by a factor of 1-1.6 between clean and dirty surfaces. However, both calculated currents show more or less the same rise with voltage as the experimental data, in spite of the different behaviour of secondary electron emission yields for clean and dirty surfaces as a function of voltage

  16. Surface heat flow and CO2 emissions within the Ohaaki hydrothermal field, Taupo Volcanic Zone, New Zealand

    Science.gov (United States)

    Rissmann, C.; Christenson, B.; Werner, C.; Leybourne, M.; Cole, J.; Gravley, D.

    2012-01-01

    Carbon dioxide emissions and heat flow have been determined from the Ohaaki hydrothermal field, Taupo Volcanic Zone (TVZ), New Zealand following 20a of production (116MW e). Soil CO2 degassing was quantified with 2663 CO2 flux measurements using the accumulation chamber method, and 2563 soil temperatures were measured and converted to equivalent heat flow (Wm -2) using published soil temperature heat flow functions. Both CO2 flux and heat flow were analysed statistically and then modelled using 500 sequential Gaussian simulations. Forty subsoil CO 2 gas samples were also analysed for stable C isotopes. Following 20a of production, current CO2 emissions equated to 111??6.7T/d. Observed heat flow was 70??6.4MW, compared with a pre-production value of 122MW. This 52MW reduction in surface heat flow is due to production-induced drying up of all alkali-Cl outflows (61.5MW) and steam-heated pools (8.6MW) within the Ohaaki West thermal area (OHW). The drying up of all alkali-Cl outflows at Ohaaki means that the soil zone is now the major natural pathway of heat release from the high-temperature reservoir. On the other hand, a net gain in thermal ground heat flow of 18MW (from 25MW to 43.3??5MW) at OHW is associated with permeability increases resulting from surface unit fracturing by production-induced ground subsidence. The Ohaaki East (OHE) thermal area showed no change in distribution of shallow and deep soil temperature contours despite 20a of production, with an observed heat flow of 26.7??3MW and a CO 2 emission rate of 39??3T/d. The negligible change in the thermal status of the OHE thermal area is attributed to the low permeability of the reservoir beneath this area, which has limited production (mass extraction) and sheltered the area from the pressure decline within the main reservoir. Chemistry suggests that although alkali-Cl outflows once contributed significantly to the natural surface heat flow (~50%) they contributed little (99% of the original CO 2

  17. Surface heat flow and CO2 emissions within the Ohaaki hydrothermal field, Taupo Volcanic Zone, New Zealand

    Science.gov (United States)

    Rissmann, C.; Christenson, B.; Werner, C.; Leybourne, M.; Cole, J.; Gravley, D.

    2012-01-01

    Carbon dioxide emissions and heat flow have been determined from the Ohaaki hydrothermal field, Taupo Volcanic Zone (TVZ), New Zealand following 20a of production (116MW e). Soil CO2 degassing was quantified with 2663 CO2 flux measurements using the accumulation chamber method, and 2563 soil temperatures were measured and converted to equivalent heat flow (Wm -2) using published soil temperature heat flow functions. Both CO2 flux and heat flow were analysed statistically and then modelled using 500 sequential Gaussian simulations. Forty subsoil CO 2 gas samples were also analysed for stable C isotopes. Following 20a of production, current CO2 emissions equated to 111??6.7T/d. Observed heat flow was 70??6.4MW, compared with a pre-production value of 122MW. This 52MW reduction in surface heat flow is due to production-induced drying up of all alkali-Cl outflows (61.5MW) and steam-heated pools (8.6MW) within the Ohaaki West thermal area (OHW). The drying up of all alkali-Cl outflows at Ohaaki means that the soil zone is now the major natural pathway of heat release from the high-temperature reservoir. On the other hand, a net gain in thermal ground heat flow of 18MW (from 25MW to 43.3??5MW) at OHW is associated with permeability increases resulting from surface unit fracturing by production-induced ground subsidence. The Ohaaki East (OHE) thermal area showed no change in distribution of shallow and deep soil temperature contours despite 20a of production, with an observed heat flow of 26.7??3MW and a CO 2 emission rate of 39??3T/d. The negligible change in the thermal status of the OHE thermal area is attributed to the low permeability of the reservoir beneath this area, which has limited production (mass extraction) and sheltered the area from the pressure decline within the main reservoir. Chemistry suggests that although alkali-Cl outflows once contributed significantly to the natural surface heat flow (~50%) they contributed little (99% of the original CO 2

  18. Indirect global warming effects of ozone and stratospheric water vapor induced by surface methane emission

    Energy Technology Data Exchange (ETDEWEB)

    Wuebbles, D.J.; Grossman, A.S.; Tamaresis, J.S.; Patten, K.O. Jr.; Jain, A.; Grant, K.A.

    1994-07-01

    Methane has indirect effects on climate due to chemical interactions as well as direct radiative forcing effects as a greenhouse gas. We have calculated the indirect, time-varying tropospheric radiative forcing and GWP of O{sub 3} and stratospheric H{sub 2}O due to an impulse of CH{sub 4}. This impulse, applied to the lowest layer of the atmosphere, is the increase of the atmospheric mass of CH{sub 4} resulting from a 25 percent steady state increase in the current emissions as a function of latitude. The direct CH{sub 4} radiative forcing and GWP are also calculated. The LLNL 2-D radiative-chemistry-transport model is used to evaluate the resulting changes in the O{sub 3}, H{sub 2}O and CH{sub 4} atmospheric profiles as a function of time. A correlated k-distribution radiative transfer model is used to calculate the radiative forcing at the tropopause of the globally-averaged atmosphere profiles. The O{sub 3} indirect GWPs vary from {approximately}27 after a 20 yr integration to {approximately}4 after 500 years, agreeing with the previous estimates to within about 10 percent. The H{sub 2}O indirect GWPs vary from {approximately}2 after a 20 yr integration to {approximately}0.3 after 500 years, and are in close agreement with other estimates. The CH{sub 4} GWPs vary from {approximately}53 at 20 yrs to {approximately}7 at 500 yrs. The 20 year CH{sub 4} GWP is {approximately}20% larger than previous estimates of the direct CH{sub 4} GWP due to a CH{sub 4} response time ({approximately}17 yrs) that is much longer than the overall lifetime (10 yrs). The increased CH{sub 4} response time results from changes in the OH abundances caused by the CH{sub 4} impulse. The CH{sub 4} radiative forcing results are consistent with IPCC values. Estimates are made of latitude effects in the radiative forcing calculations, and UV effects on the O{sub 3} radiative forcing calculations (10%).

  19. Mobile load simulators - A tool to distinguish between the emissions due to abrasion and resuspension of PM10 from road surfaces

    Science.gov (United States)

    Gehrig, R.; Zeyer, K.; Bukowiecki, N.; Lienemann, P.; Poulikakos, L. D.; Furger, M.; Buchmann, B.

    2010-12-01

    Mechanically produced abrasion particles and resuspension processes are responsible for a significant part of the PM10 emissions of road traffic. However, specific differentiation between PM10 emissions due to abrasion and resuspension from road pavement is very difficult due to their similar elemental composition and highly correlated variation in time. In this work Mobile Load Simulators were used to estimate PM10 emission factors for pavement abrasion and resuspension on different pavement types for light and heavy duty vehicles. From the experiments it was derived that particle emissions due to abrasion from pavements in good condition are quite low in the range of only a few mg·km -1 per vehicle if quantifiable at all. Considerable abrasion emissions, however, can occur from damaged pavements. Resuspension of deposited dust can cause high and extremely variable particle emissions depending strongly on the dirt load of the road surface. Porous pavements seem to retain deposited dust better than dense pavements, thus leading to lower emissions due to resuspension compared to pavements with a dense structure (e.g. asphalt concrete). Tyre wear seemed not to be a quantitatively significant source of PM10 emissions from road traffic.

  20. Environment-friendly adhesives for surface bonding of wood-based flooring using natural tannin to reduce formaldehyde and TVOC emission.

    Science.gov (United States)

    Kim, Sumin

    2009-01-01

    The objective of this research was to develop environment-friendly adhesives for face fancy veneer bonding of engineered flooring using the natural tannin form bark in the wood. The natural wattle tannin adhesive were used to replace UF resin in the formaldehyde-based resin system in order to reduce formaldehyde and volatile organic compound (VOC) emissions from the adhesives used between plywoods and fancy veneers. PVAc was added to the natural tannin adhesive to increase viscosity of tannin adhesive for surface bonding. For tannin/PVAc hybrid adhesives, 5%, 10%, 20% and 30% of PVAc to the natural tannin adhesives were added. tannin/PVAc hybrid adhesives showed better bonding than the commercial natural tannin adhesive with a higher level of wood penetration. The initial adhesion strength was sufficient to be maintained within the optimum initial tack range. The standard formaldehyde emission test (desiccator method), field and laboratory emission cell (FLEC) and VOC analyzer were used to determine the formaldehyde and VOC emissions from engineered flooring bonded with commercial the natural tannin adhesive and tannin/PVAc hybrid adhesives. By desiccator method and FLEC, the formaldehyde emission level of each adhesive showed the similar tendency. All adhesives satisfied the E(1) grade (below 1.5 mg/L) and E(0) grade (below 0.5 mg/L) with UV coating. VOC emission results by FLEC and VOC analyzer were different with the formaldehyde emission results. TVOC emission was slightly increased as adding PVAc.

  1. The effect of surface oxide layer on the rate of hydrogen emission from aluminum and its alloys in a high vacuum

    Science.gov (United States)

    Makarova, V. I.; Zyabrev, A. A.

    1979-01-01

    The influence of surface oxide layers on the kinetics of hydrogen emission at the high vacuum of 10 to the minus 8th power torr was investigated at temperatures from 20 to 450 C using samples of pure AB00 aluminum and the cast alloy AMg. Cast and deformed samples of AMts alloy were used to study the effect of oxide film thickness on the rate of hydrogen emission. Thermodynamic calculations of the reactions of the generation and dissociation of aluminum oxide show that degasification at elevated temperatures (up to 600 C) and high vacuum will not reduce the thickness of artificially-generated surface oxide layers on aluminum and its alloys.

  2. A Comparative Study of the Monitoring of a Self Aligning Spherical Journal using Surface Vibration, Airborne Sound and Acoustic Emission

    International Nuclear Information System (INIS)

    Raharjo, P; Tesfa, B; Gu, F; Ball, A D

    2012-01-01

    A Self aligning spherical journal bearing is a plain bearing which has spherical surface contact that can be applied in high power industrial machinery. This type of bearing can accommodate a misalignment problem. The journal bearing faults degrade machine performance, decrease life time service and cause unexpected failure which are dangerous for safety issues. Non-intrusive measurements such as surface vibration (SV), airborne sound (AS) and acoustic emission (AE) measurement are appropriate monitoring methods for early stage journal bearing fault in low, medium and high frequency. This paper focuses on the performance comparison using SV, AS and AE measurements in monitoring a self aligning spherical journal bearing for normal and faulty (scratch) conditions. It examines the signals in the time domain and frequency domain and identifies the frequency ranges for each measurement in which significant changes are observed. The results of SV, AS and AE experiments indicate that the spectrum can be used to detect the differences between normal and faulty bearing. The statistic parameter shows that RMS value and peak value for faulty bearing is higher than normal bearing.

  3. Modeled Trends in Impacts of Landing and Takeoff Aircraft Emissions on Surface Air-Quality in U.S for 2005, 2010 and 2018

    Science.gov (United States)

    Vennam, L. P.

    2014-12-01

    Understanding the present-day impacts of aircraft emissions on surface air quality is essential to plan potential mitigation policies for future growth. Stringent regulation on mobile source-related emissions in the recent past coupled with anticipated rise in the growth in aviation activity can increase the relative impacts of aviation-attributable surface air quality if adequate measures for reducing aviation emissions are not implemented. Though aircraft emissions during in-flight mode (at upper altitudes) contribute a significant (70 - 80%) proportion of the total aviation emissions, landing and takeoff (LTO) related emissions can have immediate impact on surface air quality, as most of the large airports are located in urban areas, specifically those that are designated in nonattainment for O3 and/or PM2.5. In this study, we modeled impacts of aircraft emissions during LTO cycles on surface air quality using the latest version of the CMAQ model for two contemporary years (2005, 2010) and one future year (2018). For this regional scale modeling study, we used highly resolved aircraft emissions from the FAA's Aviation Environmental Design Tool (AEDT), meteorology from NASA's Modern-Era Retrospective Analysis for Research and Applications (MERRA) downscaled with the WRF model, dynamically varying chemical boundary conditions from the CAM-Chem global model (which also used the same AEDT emissions but at the global scale), and spatio-temporally resolved lightning NOx emissions estimated using National Lightning Detection Network (NLDN) flash density data. We evaluated our model results with air quality observations from surface-based networks and in-situ aircraft observation data for the contemporary years. We will present results from model evaluation using this enhanced modeling system, as well as the trajectories in aviation- related air quality (focusing on O3, NO2 and PM2.5) for the three modeling years considered in this study. These findings will help plan

  4. Reflection and absorption coefficients for use in room acoustic simulations

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2013-01-01

    Two ideas to improve the boundary conditions for room acoustic simulations are presented. First, all rooms have finite boundary surfaces, thereby a reflection coefficient for finite surfaces should be physically more suitable than that for infinitely large surfaces. Second, absorption coefficients...

  5. Extinction Coefficient of Gold Nanostars.

    Science.gov (United States)

    de Puig, Helena; Tam, Justina O; Yen, Chun-Wan; Gehrke, Lee; Hamad-Schifferli, Kimberly

    2015-07-30

    Gold nanostars (NStars) are highly attractive for biological applications due to their surface chemistry, facile synthesis and optical properties. Here, we synthesize NStars in HEPES buffer at different HEPES/Au ratios, producing NStars of different sizes and shapes, and therefore varying optical properties. We measure the extinction coefficient of the synthesized NStars at their maximum surface plasmon resonances (SPR), which range from 5.7 × 10 8 to 26.8 × 10 8 M -1 cm -1 . Measured values correlate with those obtained from theoretical models of the NStars using the discrete dipole approximation (DDA), which we use to simulate the extinction spectra of the nanostars. Finally, because NStars are typically used in biological applications, we conjugate DNA and antibodies to the NStars and calculate the footprint of the bound biomolecules.

  6. Multiparametric voxel-based analyses of standardized uptake values and apparent diffusion coefficients of soft-tissue tumours with a positron emission tomography/magnetic resonance system: Preliminary results

    Energy Technology Data Exchange (ETDEWEB)

    Sagiyama, Koji; Kamei, Ryotaro; Honda, Hiroshi [Kyushu University, Department of Clinical Radiology, Graduate School of Medical Sciences, Fukuoka (Japan); Watanabe, Yuji; Kawanami, Satoshi [Kyushu University, Department of Molecular Imaging and Diagnosis, Graduate School of Medical Sciences, Fukuoka (Japan); Hong, Sungtak [Philips Electronics Japan, Healthcare, Tokyo (Japan); Matsumoto, Yoshihiro [Kyushu University, Departmant of Orthopaedic Surgery, Graduate School of Medical Sciences, Fukuoka (Japan)

    2017-12-15

    To investigate the usefulness of voxel-based analysis of standardized uptake values (SUVs) and apparent diffusion coefficients (ADCs) for evaluating soft-tissue tumour malignancy with a PET/MR system. Thirty-five subjects with either ten low/intermediate-grade tumours or 25 high-grade tumours were prospectively enrolled. Zoomed diffusion-weighted and fluorodeoxyglucose ({sup 18}FDG)-PET images were acquired along with fat-suppressed T2-weighted images (FST2WIs). Regions of interest (ROIs) were drawn on FST2WIs including the tumour in all slices. ROIs were pasted onto PET and ADC-maps to measure SUVs and ADCs within tumour ROIs. Tumour volume, SUVmax, ADCminimum, the heterogeneity and the correlation coefficients of SUV and ADC were recorded. The parameters of high- and low/intermediate-grade groups were compared, and receiver operating characteristic (ROC) analysis was also performed. The mean correlation coefficient for SUV and ADC in high-grade sarcomas was lower than that of low/intermediate-grade tumours (-0.41 ± 0.25 vs. -0.08 ± 0.34, P < 0.01). Other parameters did not differ significantly. ROC analysis demonstrated that correlation coefficient showed the best diagnostic performance for differentiating the two groups (AUC 0.79, sensitivity 96.0%, specificity 60%, accuracy 85.7%). SUV and ADC determined via PET/MR may be useful for differentiating between high-grade and low/intermediate-grade soft tissue tumours. (orig.)

  7. Impact of regional climate change and future emission scenarios on surface O3 and PM2.5 over India

    Science.gov (United States)

    Pommier, Matthieu; Fagerli, Hilde; Gauss, Michael; Simpson, David; Sharma, Sumit; Sinha, Vinay; Ghude, Sachin D.; Landgren, Oskar; Nyiri, Agnes; Wind, Peter

    2018-01-01

    Eleven of the world's 20 most polluted cities are located in India and poor air quality is already a major public health issue. However, anthropogenic emissions are predicted to increase substantially in the short-term (2030) and medium-term (2050) futures in India, especially if no further policy efforts are made. In this study, the EMEP/MSC-W chemical transport model has been used to predict changes in surface ozone (O3) and fine particulate matter (PM2.5) for India in a world of changing emissions and climate. The reference scenario (for present-day) is evaluated against surface-based measurements, mainly at urban stations. The evaluation has also been extended to other data sets which are publicly available on the web but without quality assurance. The evaluation shows high temporal correlation for O3 (r = 0.9) and high spatial correlation for PM2.5 (r = 0.5 and r = 0.8 depending on the data set) between the model results and observations. While the overall bias in PM2.5 is small (lower than 6 %), the model overestimates O3 by 35 %. The underestimation in NOx titration is probably the main reason for the O3 overestimation in the model. However, the level of agreement can be considered satisfactory in this case of a regional model being evaluated against mainly urban measurements, and given the inevitable uncertainties in much of the input data.For the 2050s, the model predicts that climate change will have distinct effects in India in terms of O3 pollution, with a region in the north characterized by a statistically significant increase by up to 4 % (2 ppb) and one in the south by a decrease up to -3 % (-1.4 ppb). This variation in O3 is assumed to be partly related to changes in O3 deposition velocity caused by changes in soil moisture and, over a few areas, partly also by changes in biogenic non-methane volatile organic compounds.Our calculations suggest that PM2.5 will increase by up to 6.5 % over the Indo-Gangetic Plain by the 2050s. The increase over India

  8. Impact of regional climate change and future emission scenarios on surface O3 and PM2.5 over India

    Directory of Open Access Journals (Sweden)

    M. Pommier

    2018-01-01

    Full Text Available Eleven of the world's 20 most polluted cities are located in India and poor air quality is already a major public health issue. However, anthropogenic emissions are predicted to increase substantially in the short-term (2030 and medium-term (2050 futures in India, especially if no further policy efforts are made. In this study, the EMEP/MSC-W chemical transport model has been used to predict changes in surface ozone (O3 and fine particulate matter (PM2.5 for India in a world of changing emissions and climate. The reference scenario (for present-day is evaluated against surface-based measurements, mainly at urban stations. The evaluation has also been extended to other data sets which are publicly available on the web but without quality assurance. The evaluation shows high temporal correlation for O3 (r =  0.9 and high spatial correlation for PM2.5 (r =  0.5 and r =  0.8 depending on the data set between the model results and observations. While the overall bias in PM2.5 is small (lower than 6 %, the model overestimates O3 by 35 %. The underestimation in NOx titration is probably the main reason for the O3 overestimation in the model. However, the level of agreement can be considered satisfactory in this case of a regional model being evaluated against mainly urban measurements, and given the inevitable uncertainties in much of the input data.For the 2050s, the model predicts that climate change will have distinct effects in India in terms of O3 pollution, with a region in the north characterized by a statistically significant increase by up to 4 % (2 ppb and one in the south by a decrease up to −3 % (−1.4 ppb. This variation in O3 is assumed to be partly related to changes in O3 deposition velocity caused by changes in soil moisture and, over a few areas, partly also by changes in biogenic non-methane volatile organic compounds.Our calculations suggest that PM2.5 will increase by up to 6.5 % over the Indo

  9. Impact of the 2008 Global Recession on air quality over the United States: Implications for surface ozone levels from changes in NOx emissions

    Science.gov (United States)

    Tong, Daniel; Pan, Li; Chen, Weiwei; Lamsal, Lok; Lee, Pius; Tang, Youhua; Kim, Hyuncheol; Kondragunta, Shobha; Stajner, Ivanka

    2016-09-01

    Satellite and ground observations detected large variability in nitrogen oxides (NOx) during the 2008 economic recession, but the impact of the recession on air quality has not been quantified. This study combines observed NOx trends and a regional chemical transport model to quantify the impact of the recession on surface ozone (O3) levels over the continental United States. The impact is quantified by simulating O3 concentrations under two emission scenarios: business-as-usual (BAU) and recession. In the BAU case, the emission projection from the Cross-State Air Pollution Rule is used to estimate the "would-be" NOx emission level in 2011. In the recession case, the actual NO2 trends observed from Air Quality System ground monitors and the Ozone Monitoring Instrument on the Aura satellite are used to obtain "realistic" changes in NOx emissions. The model prediction with the recession effect agrees better with ground O3 observations over time and space than the prediction with the BAU emission. The results show that the recession caused a 1-2 ppbv decrease in surface O3 concentration over the eastern United States, a slight increase (0.5-1 ppbv) over the Rocky Mountain region, and mixed changes in the Pacific West. The gain in air quality benefits during the recession, however, could be quickly offset by the much slower emission reduction rate during the post-recession period.

  10. Impact of the 2008 Global Recession on Air Quality over the United States: Implications for Surface Ozone Levels from Changes in NOx Emissions

    Science.gov (United States)

    Tong, Daniel; Pan, Li; Chen, Weiwei; Lamsal, Lok; Lee, Pius; Tang, Youhua; Kim, Hyuncheol; Kondragunta, Shobha; Stajner, Ivanka

    2016-01-01

    Satellite and ground observations detected large variability in nitrogen oxides (NOx) during the 2008 economic recession, but the impact of the recession on air quality has not been quantified. This study combines observed NOx trends and a regional chemical transport model to quantify the impact of the recession on surface ozone (O3) levels over the continental United States. The impact is quantified by simulating O3 concentrations under two emission scenarios: business-as-usual (BAU) and recession. In the BAU case, the emission projection from the Cross-State Air Pollution Rule is used to estimate the would-be NOx emission level in 2011. In the recession case, the actual NO2 trends observed from Air Quality System ground monitors and the Ozone Monitoring Instrument on the Aura satellite are used to obtain realistic changes in NOx emissions. The model prediction with the recession effect agrees better with ground O3 observations over time and space than the prediction with the BAU emission. The results show that the recession caused a 12ppbv decrease in surface O3 concentration over the eastern United States, a slight increase (0.51ppbv) over the Rocky Mountain region, and mixed changes in the Pacific West. The gain in air quality benefits during the recession, however, could be quickly offset by the much slower emission reduction rate during the post-recession period.

  11. Climate and emission changes contributing to changes in near-surface ozone in Europe over the coming decades: results from model studies.

    Science.gov (United States)

    Engardt, Magnuz; Bergström, Robert; Andersson, Camilla

    2009-12-01

    We used an off-line, regional, model of atmospheric transport and chemistry to investigate current and future levels of near-surface ozone and accumulated ozone exposure over a threshold of 40 ppb(v) (AOT40) in Europe. To describe the current situation and enable an evaluation of the model's performance we simulated a number of years around 2000. To assess changes in ozone concentrations due to possible emission changes in Europe, the model was run with the meteorology of the early 2000s and precursor emissions from a set of Clean Air for Europe (CAFE) emissions scenarios. By extrapolation of the observed increase in near-surface O3 at coastal locations in northwest Europe we constructed model boundaries that were used to simulate the impact of increasing hemispheric background in 2020. To assess changes in ozone concentrations due to climate change, the model was run with recent (2000) emissions but using meteorology from a regional climate model simulating a control (1961-1990) and a future (2021-2050) climate. The results indicate that climate change will have a small impact on ozone concentrations and AOT40 in the Nordic countries. Changes in hemispheric background concentrations and changes in precursor emissions in Europe will have a larger effect on ozone in Northern Europe. The situation is quite different in southern Europe, where climate change is expected to result in a very large increase in near-surface ozone concentrations.

  12. Prestarlike functions with negative coefficients

    Directory of Open Access Journals (Sweden)

    H. Silverman

    1979-01-01

    Full Text Available The extreme points for prestarlike functions having negative coefficients are determined. Coefficient, distortion and radii of univalence, starlikeness, and convexity theorems are also obtained.

  13. The effect of feeding high fat diet to beef cattle on manure composition and gaseous emission from a feedlot pen surface

    Directory of Open Access Journals (Sweden)

    Dhan Prasad Gautam

    2016-06-01

    Full Text Available Abstract Background Dietary manipulation is a common practice to mitigate gaseous emission from livestock production facilities, and the variation of fat level in the diet has shown great influence on ruminal volatile fatty acids (VFA and enteric methane generation. The changes in dietary fat levels influence rumen chemistry that could modify manure nutrient composition along with odor and gaseous emissions from manure management facilities. Methods A field experiment was carried out on beef cattle feedlots to investigate the effect of four levels of dietary fat concentrations (3 to 5.5 % on the manure composition and gaseous emissions (methane-CH4, nitrous oxide-N2O, carbon dioxide-CO2 and hydrogen sulfide-H2S from the feedlot pen surface. The experiment was carried out over a 5-month period from June to October during North Dakota’s summer-fall climatic condition. Air and manure sampling was conducted five times at a 20–30 day intervals. Results Overall, this research indicated that fat levels in diet have no or little effect on the nutrient composition of manure and gaseous emission from the pens with cattle fed with different diet. Though significant variation of gaseous emission and manure composition were observed between different sampling periods, no effect of high fat diet was observed on manure composition and gaseous emission. Conclusions It can be concluded that addition of fat to animal diet may not have any impact on gaseous emission and manure compositions.

  14. The effect of feeding high fat diet to beef cattle on manure composition and gaseous emission from a feedlot pen surface.

    Science.gov (United States)

    Gautam, Dhan Prasad; Rahman, Shafiqur; Borhan, Md Saidul; Engel, Chanda

    2016-01-01

    Dietary manipulation is a common practice to mitigate gaseous emission from livestock production facilities, and the variation of fat level in the diet has shown great influence on ruminal volatile fatty acids (VFA) and enteric methane generation. The changes in dietary fat levels influence rumen chemistry that could modify manure nutrient composition along with odor and gaseous emissions from manure management facilities. A field experiment was carried out on beef cattle feedlots to investigate the effect of four levels of dietary fat concentrations (3 to 5.5 %) on the manure composition and gaseous emissions (methane-CH4, nitrous oxide-N2O, carbon dioxide-CO2 and hydrogen sulfide-H2S) from the feedlot pen surface. The experiment was carried out over a 5-month period from June to October during North Dakota's summer-fall climatic condition. Air and manure sampling was conducted five times at a 20-30 day intervals. Overall, this research indicated that fat levels in diet have no or little effect on the nutrient composition of manure and gaseous emission from the pens with cattle fed with different diet. Though significant variation of gaseous emission and manure composition were observed between different sampling periods, no effect of high fat diet was observed on manure composition and gaseous emission. It can be concluded that addition of fat to animal diet may not have any impact on gaseous emission and manure compositions.

  15. Simulating the carbon, water, energy budgets and greenhouse gas emissions of arctic soils with the ISBA land surface model

    Science.gov (United States)

    Morel, Xavier; Decharme, Bertrand; Delire, Christine

    2017-04-01

    model behaviour in the case of a flooded fen, hence giving a first insight of the sensitivity of greenhouse gas emissions with respect to surface hydrology. Comparing the model results on these three climatically distinct sites also gives a first insight on the model sensitivity to the forcing climate variables, and show that the model is generic enough to reasonably model methane and carbon dioxyde emission behaviour from different types of boreal ecosystems.

  16. Origin of surface and columnar Indian Ocean Experiment (INDOEX) aerosols using source- and region-tagged emissions transport in a general circulation model

    Science.gov (United States)

    Verma, S.; Venkataraman, C.; Boucher, O.

    2008-12-01

    We study the relative influence of aerosols emitted from different sectors and geographical regions on aerosol loading in south Asia. Sectors contributing aerosol emissions include biofuel and fossil fuel combustion, open biomass burning, and natural sources. Geographical regions include India (the Indo-Gangetic plain, central India, south India, and northwest India), southeast Asia, east Asia, Africa-west Asia, and the rest of the world. Simulations of the Indian Ocean Experiment (INDOEX), from January to March 1999, are made in the general circulation model of Laboratoire de Météorologie Dynamique (LMD-ZT GCM) with emissions tagged by sector and geographical region. Anthropogenic emissions dominate (54-88%) the predicted aerosol optical depth (AOD) over all the receptor regions. Among the anthropogenic sectors, fossil fuel combustion has the largest overall influence on aerosol loading, primarily sulfate, with emissions from India (50-80%) and rest of the world significantly influencing surface concentrations and AOD. Biofuel combustion has a significant influence on both the surface and columnar black carbon (BC) in particular over the Indian subcontinent and Bay of Bengal with emissions largely from the Indian region (60-80%). Open biomass burning emissions influence organic matter (OM) significantly, and arise largely from Africa-west Asia. The emissions from Africa-west Asia affect the carbonaceous aerosols AOD in all receptor regions, with their largest influence (AOD-BC: 60%; and AOD-OM: 70%) over the Arabian Sea. Among Indian regions, the Indo-Gangetic Plain is the largest contributor to anthropogenic surface mass concentrations and AOD over the Bay of Bengal and India. Dust aerosols are contributed mainly through the long-range transport from Africa-west Asia over the receptor regions. Overall, the model estimates significant intercontinental incursion of aerosol, for example, BC, OM, and dust from Africa-west Asia and sulfate from distant regions (rest

  17. Quenching of Einstein-coefficients by photons

    International Nuclear Information System (INIS)

    Aumayr, F.; Lee, W.; Skinner, C.H.; Suckewer, S.

    1991-03-01

    Experimental evidence is presented for the change of Einstein's A- coefficients for spontaneous transitions from the upper laser level of argon ion laser discharge due to the presence of the high- intensity laser flux. To demonstrate that this quenching effect cannot be attributed to a reduction in self-absorption of the strong spontaneous emission line, absorption and line profile measurements have been performed. Computer modelling of the reduction of self absorption due to Rabi splitting also indicated that this effect is too small to explain the observed quenching of spontaneous line emissions. 13 refs., 11 figs

  18. Emission of perfluoroalkyl carboxylic acids (PFCA) from heated surfaces made of polytetrafluoroethylene (PTFE) applied in food contact materials and consumer products.

    Science.gov (United States)

    Schlummer, Martin; Sölch, Christina; Meisel, Theresa; Still, Mona; Gruber, Ludwig; Wolz, Gerd

    2015-06-01

    Polytetrafluoroethylene (PTFE) has been widely discussed as a source of perfluorooctanoic acid (PFOA), which has been used in the production of fluoropolymers. PTFE may also contain unintended perfluoroalkyl carboxylic acids (PFCAs) caused by thermolysis of PTFE, which has been observed at temperatures above 300°C. Common PTFE coated food contact materials and consumer goods are operated at temperatures above 200°C. However, knowledge on possible emissions of PFCAs is limited. Therefore, it was the aim of this study to investigate and evaluate the emission of PFCAs from PTFE coated products with both, normal use and overheating scenarios. Four pans, claimed to be PFOA free, and nine consumer products were investigated. At normal use conditions (PTFE surfaces were trapped for 1h. Overheating scenarios (>260°C) recorded emissions during a 30min heating of empty pans on a stove. Emissions were analyzed by LC-ESI-MS. Results indicate the emission of PFCAs, whereas no perfluorinated sulfonic acids were traced. At normal use conditions total emissions of PFCAs accounted for 4.75ng per hour. Overheated pans, however, released far higher amounts with up to 12190ng PFCAs per hour at 370°C. Dominating contributors where PFBA and PFOA at normal use and PFBA and PFPeA during overheating. Temperature seems to be the main factor controlling the emission of PFCAs. A worst case estimation of human exposure revealed that emissions of PFCAs from heated PTFE surfaces would be far below the TDI of 1500ng PFOA per kg body weight. Copyright © 2014 Elsevier Ltd. All rights reserved.

  19. Surface heat flow and CO2 emissions within the Ohaaki hydrothermal field, Taupo Volcanic Zone, New Zealand

    International Nuclear Information System (INIS)

    Rissmann, Clinton; Christenson, Bruce; Werner, Cynthia; Leybourne, Matthew; Cole, Jim; Gravley, Darren

    2012-01-01

    Carbon dioxide emissions and heat flow have been determined from the Ohaaki hydrothermal field, Taupo Volcanic Zone (TVZ), New Zealand following 20 a of production (116 MW e ). Soil CO 2 degassing was quantified with 2663 CO 2 flux measurements using the accumulation chamber method, and 2563 soil temperatures were measured and converted to equivalent heat flow (W m −2 ) using published soil temperature heat flow functions. Both CO 2 flux and heat flow were analysed statistically and then modelled using 500 sequential Gaussian simulations. Forty subsoil CO 2 gas samples were also analysed for stable C isotopes. Following 20 a of production, current CO 2 emissions equated to 111 ± 6.7 T/d. Observed heat flow was 70 ± 6.4 MW, compared with a pre-production value of 122 MW. This 52 MW reduction in surface heat flow is due to production-induced drying up of all alkali–Cl outflows (61.5 MW) and steam-heated pools (8.6 MW) within the Ohaaki West thermal area (OHW). The drying up of all alkali–Cl outflows at Ohaaki means that the soil zone is now the major natural pathway of heat release from the high-temperature reservoir. On the other hand, a net gain in thermal ground heat flow of 18 MW (from 25 MW to 43.3 ± 5 MW) at OHW is associated with permeability increases resulting from surface unit fracturing by production-induced ground subsidence. The Ohaaki East (OHE) thermal area showed no change in distribution of shallow and deep soil temperature contours despite 20 a of production, with an observed heat flow of 26.7 ± 3 MW and a CO 2 emission rate of 39 ± 3 T/d. The negligible change in the thermal status of the OHE thermal area is attributed to the low permeability of the reservoir beneath this area, which has limited production (mass extraction) and sheltered the area from the pressure decline within the main reservoir. Chemistry suggests that although alkali–Cl outflows once contributed significantly to the natural surface heat flow (∼50%) they

  20. Modeling and evaluation of the global sea-salt aerosol distribution: sensitivity to size-resolved and sea-surface temperature dependent emission schemes

    Directory of Open Access Journals (Sweden)

    M. Spada

    2013-12-01

    Full Text Available One of the major sources of uncertainty in model estimates of the global sea-salt aerosol distribution is the emission parameterization. We evaluate a new sea-salt aerosol life cycle module coupled to the online multiscale chemical transport model NMMB/BSC-CTM. We compare 5 yr global simulations using five state-of-the-art sea-salt open-ocean emission schemes with monthly averaged coarse aerosol optical depth (AOD from selected AERONET sun photometers, surface concentration measurements from the University of Miami's Ocean Aerosol Network, and measurements from two NOAA/PMEL cruises (AEROINDOEX and ACE1. Model results are highly sensitive to the introduction of sea-surface-temperature (SST-dependent emissions and to the accounting of spume particles production. Emission ranges from 3888 Tg yr−1 to 8114 Tg yr−1, lifetime varies between 7.3 h and 11.3 h, and the average column mass load is between 5.0 Tg and 7.2 Tg. Coarse AOD is reproduced with an overall correlation of around 0.5 and with normalized biases ranging from +8.8% to +38.8%. Surface concentration is simulated with normalized biases ranging from −9.5% to +28% and the overall correlation is around 0.5. Our results indicate that SST-dependent emission schemes improve the overall model performance in reproducing surface concentrations. On the other hand, they lead to an overestimation of the coarse AOD at tropical latitudes, although it may be affected by uncertainties in the comparison due to the use of all-sky model AOD, the treatment of water uptake, deposition and optical properties in the model and/or an inaccurate size distribution at emission.

  1. Influence of surface emission processes on a fast-pulsed dielectric barrier discharge in air at atmospheric pressure

    Science.gov (United States)

    Pechereau, François; Bonaventura, Zdeněk; Bourdon, Anne

    2016-08-01

    This paper presents simulations of an atmospheric pressure air discharge in a point-to-plane geometry with a dielectric layer parallel to the cathode plane. Experimentally, a discharge reignition in the air gap below the dielectrics has been observed. With a 2D fluid model, it is shown that due to the fast rise of the high voltage applied and the sharp point used, a first positive spherical discharge forms around the point. Then this discharge propagates axially and impacts the dielectrics. As the first discharge starts spreading on the upper dielectric surface, in the second air gap with a low preionization density of {{10}4}~\\text{c}{{\\text{m}}-3} , the 2D fluid model predicts a rapid reignition of a positive discharge. As in experiments, the discharge reignition is much slower, a discussion on physical processes to be considered in the model to increase the reignition delay is presented. The limit case with no initial seed charges in the second air gap has been studied. First, we have calculated the time to release an electron from the cathode surface by thermionic and field emission processes for a work function φ \\in ≤ft[3,4\\right] eV and an amplification factor β \\in ≤ft[100,220\\right] . Then a 3D Monte Carlo model has been used to follow the dynamics of formation of an avalanche starting from a single electron emitted at the cathode. Due to the high electric field in the second air gap, we have shown that in a few nanoseconds, a Gaussian cloud of seed charges is formed at a small distance from the cathode plane. This Gaussian cloud has been used as the initial condition of the 2D fluid model in the second air gap. In this case, the propagation of a double headed discharge in the second air gap has been observed and the reignition delay is in rather good agreement with experiments.

  2. Land Surface Temperature and Emissivity Retrieval from Field-Measured Hyperspectral Thermal Infrared Data Using Wavelet Transform

    Directory of Open Access Journals (Sweden)

    Yu-Ze Zhang

    2017-05-01

    Full Text Available Currently, the main difficulty in separating the land surface temperature (LST and land surface emissivity (LSE from field-measured hyperspectral Thermal Infrared (TIR data lies in solving the radiative transfer equation (RTE. Based on the theory of wavelet transform (WT, this paper proposes a method for accurately and effectively separating LSTs and LSEs from field-measured hyperspectral TIR data. We show that the number of unknowns in the RTE can be reduced by decomposing and reconstructing the LSE spectrum, thus making the RTE solvable. The final results show that the errors introduced by WT are negligible. In addition, the proposed method usually achieves a greater accuracy in a wet-warm atmosphere than that in a dry-cold atmosphere. For the results under instrument noise conditions (NE∆T = 0.2 K, the overall accuracy of the LST is approximately 0.1–0.3 K, while the Root Mean Square Error (RMSE of the LSEs is less than 0.01. In contrast to the effects of instrument noise, our method is quite insensitive to noises from atmospheric downwelling radiance, and all the RMSEs of our method are approximately zero for both the LSTs and the LSEs. When we used field-measured data to better evaluate our method’s performance, the results showed that the RMSEs of the LSTs and LSEs were approximately 1.1 K and 0.01, respectively. The results from both simulated data and field-measured data demonstrate that our method is promising for decreasing the number of unknowns in the RTE. Furthermore, the proposed method overcomes some known limitations of current algorithms, such as singular values and the loss of continuity in the spectrum of the retrieved LSEs.

  3. Subsurface watering resulted in reduced soil N2O and CO2 emissions and their global warming potentials than surface watering

    Science.gov (United States)

    Wei, Qi; Xu, Junzeng; Yang, Shihong; Liao, Linxian; Jin, Guangqiu; Li, Yawei; Hameed, Fazli

    2018-01-01

    Water management is an important practice with significant effect on greenhouse gases (GHG) emission from soils. Nitrous oxide (N2O) and carbon dioxide (CO2) emissions and their global warming potentials (GWPs) from subsurface watering soil (SUW) were investigated, with surface watering (SW) as a control. Results indicated that the N2O and CO2 emissions from SUW soils were somewhat different to those from SW soil, with the peak N2O and CO2 fluxes from SUW soil reduced by 28.9% and 19.4%, and appeared 72 h and 168 h later compared with SW. The fluxes of N2O and CO2 from SUW soils were lower than those from SW soil in both pulse and post-pulse periods, and the reduction was significantly (p0.1) lower that from SW soil. Moreover, N2O and CO2 fluxes from both watering treatments increased exponentially with increase of soil water-filled pore space (WFPS) and temperature. Our results suggest that watering soil from subsurface could significantly reduce the integrative greenhouse effect caused by N2O and CO2 and is a promising strategy for soil greenhouse gases (GHGs) mitigation. And the pulse period, contributed most to the reduction in emissions of N2O and CO2 from soils between SW and SUW, should be a key period for mitigating GHGs emissions. Response of N2O and CO2 emissions to soil WFPS and temperature illustrated that moisture was the dominant parameters that triggering GHG pulse emissions (especially for N2O), and temperature had a greater effect on the soil microorganism activity than moisture in drier soil. Avoiding moisture and temperature are appropriate for GHG emission at the same time is essential for GHGs mitigation, because peak N2O and CO2 emission were observed only when moisture and temperature are both appropriate.

  4. RF Sheath-Enhanced Plasma Surface Interaction Studies using Beryllium Optical Emission Spectroscopy in JET ITER-Like Wall

    Energy Technology Data Exchange (ETDEWEB)

    Agarici, G. [Fusion for Energy (F4E), Barcelona, Spain; Klepper, C Christopher [ORNL; Colas, L. [French Atomic Energy Commission (CEA); Krivska, Alena [Ecole Royale Militaire, Brussels Belgium; Bobkov, V. [Max-Planck-Institut fur Plasmaphysik, EURATOM Association, Garching, Germany; Jacquet, P. [Culham Centre for Fusion Energy (CCFE), Abingdon, UK; Delabie, Ephrem G. [ORNL; Giroud, C. [EURATOM / UKAEA, UK; Kirov, K K. [Association EURATOM-CCFE, Abingdon, UK; Lasa Esquisabel, Ane [ORNL; Lerche, E. [ERM-KMS, Association EURATOM-Belgian State, Brussels, Belgium; Dumortier, P. [ERM-KMS, Association EURATOM-Belgian State, Brussels, Belgium; Durodie, Frederic [Ecole Royale Militaire, Brussels Belgium

    2017-10-01

    A dedicated study on JET-ILW, deploying two types of ICRH antennas and spectroscopic observation spots at two outboard, beryllium limiters, has provided insight on long-range (up to 6m) RFenhanced plasma-surface interactions (RF-PSI) due to near-antenna electric fields. To aid in the interpretation of optical emission measurements of these effects, the antenna near-fields are computed using the TOPICA code, specifically run for the ITER-like antenna (ILA); similar modelling already existed for the standard JET antennas (A2). In the experiment, both antennas were operated in current drive mode, as RF-PSI tends to be higher in this phasing and at similar power (∼0.5 MW). When sweeping the edge magnetic field pitch angle, peaked RF-PSI effects, in the form of 2-4 fold increase in the local Be source,are consistently measured with the observation spots magnetically connect to regions of TOPICAL-calculated high near-fields, particularly at the near-antenna limiters. It is also found that similar RF-PSI effects are produced by the two types of antenna on similarly distant limiters. Although this mapping of calculated near-fields to enhanced RF-PSI gives only qualitative interpretion of the data, the present dataset is expected to provide a sound experimental basis for emerging RF sheath simulation model validation.

  5. RF Sheath-Enhanced Plasma Surface Interaction Studies using Beryllium Optical Emission Spectroscopy in JET ITER-Like Wall

    Science.gov (United States)

    Christopher Klepper, C.; Colas, Laurent; Křivská, Alena; Bobkov, Volodymyr; Jacquet, Philippe; Delabie, Ephrem; Giroud, Carine; Kirov, Krassimir; Lasa, Ane; Lerche, Ernesto; Dumortier, Pierre; Durodié, Frederic; Firdaouss, Mehdi

    2017-10-01

    A dedicated study on JET-ILW, deploying two types of ICRH antennas and spectroscopic observation spots at two outboard, beryllium limiters, has provided insight on long-range (up to 6m) RFenhanced plasma-surface interactions (RF-PSI) due to near-antenna electric fields. To aid in the interpretation of optical emission measurements of these effects, the antenna near-fields are computed using the TOPICA code, specifically run for the ITER-like antenna (ILA); similar modelling already existed for the standard JET antennas (A2). In the experiment, both antennas were operated in current drive mode, as RF-PSI tends to be higher in this phasing and at similar power (˜0.5 MW). When sweeping the edge magnetic field pitch angle, peaked RF-PSI effects, in the form of 2-4 fold increase in the local Be source,are consistently measured with the observation spots magnetically connect to regions of TOPICAL-calculated high near-fields, particularly at the near-antenna limiters. It is also found that similar RF-PSI effects are produced by the two types of antenna on similarly distant limiters. Although this mapping of calculated near-fields to enhanced RF-PSI gives only qualitative interpretion of the data, the present dataset is expected to provide a sound experimental basis for emerging RF sheath simulation model validation.

  6. What a difference a year makes: Patterns in CO2 and N2O accumulation during winter and surface and subsurface emissions.

    Science.gov (United States)

    Burton, D.; Janes, D.; Haverstock, J.

    2016-12-01

    In temperate climates soil microbial processes during the winter period may be slowed, but they do not stop. This results in accumulation of CO2 and N2O in the soil profile and often results in significant bursts of microbial activity during thawing events. Winters in Nova Scotia are no longer characterized by a single "spring thaw" event and it is more common to experience numerous thaw events throughout the winter period. We examined the accumulation of CO2 and N2O in the soil atmosphere, surface emissions and dissolved N2O being lost in drainage water from agricultural fields under conventional and no tillage management over a 6-year period. The diversity of patterns in soil gas accumulation in relation to freeze/thaw events and the timing and magnitude of surface and sub-surface emissions will be presented and related to climatic and management events.

  7. Modelling the impact of sanitation, population growth and urbanization on human emissions of Cryptosporidium to surface waters—a case study for Bangladesh and India

    Science.gov (United States)

    Vermeulen, Lucie C.; de Kraker, Jelske; Hofstra, Nynke; Kroeze, Carolien; Medema, Gertjan

    2015-09-01

    Cryptosporidium is a protozoan parasite that can cause diarrhoea. Human faeces are an important source of Cryptosporidium in surface waters. We present a model to study the impact of sanitation, urbanization and population growth on human emissions of Cryptosporidium to surface waters. We build on a global model by Hofstra et al (2013 Sci. Total Environ. 442 10-9) and zoom into Bangladesh and India as illustrative case studies. The model is most sensitive to changes in oocyst excretion and infection rate, and to assumptions on the share of faeces reaching the surface water for different sanitation types. We find urban centres to be hotspots of human Cryptosporidium emissions. We estimate that 53% (Bangladesh) and 91% (India) of total emissions come from urban areas. 50% of oocysts come from only 8% (Bangladesh) and 3% (India) of the country area. In the future, population growth and urbanization may further deteriorate water quality in Bangladesh and India, despite improved sanitation. Under our ‘business as usual’ (‘sanitation improvements’) scenario, oocyst emissions will increase by a factor 2.0 (1.2) for India and 2.9 (1.1) for Bangladesh between 2010 and 2050. Population growth, urbanization and sanitation development are important processes to consider for large scale water quality modelling.

  8. Constraining surface emissions of air pollutants using inverse modelling: method intercomparison and a new two-step two-scale regularization approach

    Energy Technology Data Exchange (ETDEWEB)

    Saide, Pablo (CGRER, Center for Global and Regional Environmental Research, Univ. of Iowa, Iowa City, IA (United States)), e-mail: pablo-saide@uiowa.edu; Bocquet, Marc (Universite Paris-Est, CEREA Joint Laboratory Ecole des Ponts ParisTech and EDF RandD, Champs-sur-Marne (France); INRIA, Paris Rocquencourt Research Center (France)); Osses, Axel (Departamento de Ingeniera Matematica, Universidad de Chile, Santiago (Chile); Centro de Modelamiento Matematico, UMI 2807/Universidad de Chile-CNRS, Santiago (Chile)); Gallardo, Laura (Centro de Modelamiento Matematico, UMI 2807/Universidad de Chile-CNRS, Santiago (Chile); Departamento de Geofisica, Universidad de Chile, Santiago (Chile))

    2011-07-15

    When constraining surface emissions of air pollutants using inverse modelling one often encounters spurious corrections to the inventory at places where emissions and observations are colocated, referred to here as the colocalization problem. Several approaches have been used to deal with this problem: coarsening the spatial resolution of emissions; adding spatial correlations to the covariance matrices; adding constraints on the spatial derivatives into the functional being minimized; and multiplying the emission error covariance matrix by weighting factors. Intercomparison of methods for a carbon monoxide inversion over a city shows that even though all methods diminish the colocalization problem and produce similar general patterns, detailed information can greatly change according to the method used ranging from smooth, isotropic and short range modifications to not so smooth, non-isotropic and long range modifications. Poisson (non-Gaussian) and Gaussian assumptions both show these patterns, but for the Poisson case the emissions are naturally restricted to be positive and changes are given by means of multiplicative correction factors, producing results closer to the true nature of emission errors. Finally, we propose and test a new two-step, two-scale, fully Bayesian approach that deals with the colocalization problem and can be implemented for any prior density distribution

  9. Coefficient estimates of negative powers and inverse coefficients for ...

    Indian Academy of Sciences (India)

    λ. Using this we shall determine the ... Univalent; starlike; meromorphic functions; subordination; coefficient bounds; inverse ...... [6] FitzGerald C H, Quadratic inequalities and coefficient estimates for Schlicht functions, Arch. Ration. Mech. Anal.

  10. Pressure-viscosity coefficient of biobased lubricants

    Science.gov (United States)

    Film thickness is an important tribological property that is dependent on the combined effect of lubricant properties, material property of friction surfaces, and the operating conditions of the tribological process. Pressure-viscosity coefficient (PVC) is one of the lubricant properties that influe...

  11. An alternative coefficient for sound absorption

    NARCIS (Netherlands)

    Wijnant, Ysbrand H.; Kuipers, E.R.; de Boer, Andries; Sas, P; Jonckheere, S.; Moens, D.

    2013-01-01

    The acoustic absorption coefficient is a number that indicates which fraction of the incident acoustic power impinging on a surface is being absorbed. The incident acoustic power is obtained by spatial integration of the incident intensity, which is (classically) defined as the time-averaged

  12. Determination of the convective heat transfer coefficient

    NARCIS (Netherlands)

    Spierings, D.; Bosman, F.; Peters, T.; Plasschaert, F.

    The value of the convective heat transfer coefficient (htc) is determined under different loading conditions by using a computer aided method. The thermal load has been applied mathematically as well as experimentally to the coronal surface of an axisymmetric tooth model. To verify the assumptions

  13. Optimizing global CO emission estimates using a four-dimensional variational data assimilation system and surface network observations

    NARCIS (Netherlands)

    Hooghiemstra, P.B.; Krol, M.C.; Meirink, J.F.; Bergamaschi, P.; van der Werf, G.R.; Novelli, P.C.; Aben, I.; Rockmann, T.

    2011-01-01

    We apply a four-dimensional variational (4D-VAR) data assimilation system to optimize carbon monoxide (CO) emissions for 2003 and 2004 and to reduce the uncertainty of emission estimates from individual sources using the chemistry transport model TM5. The system is designed to assimilate large

  14. Effect of sporadic destratification, seasonal overturn and artificial mixing on CH4 emissions at the surface of a subtropical hydroelectric reservoir (Nam Theun 2 Reservoir, Lao PDR)

    Science.gov (United States)

    Guérin, F.; Deshmukh, C.; Labat, D.; Pighini, S.; Vongkhamsao, A.; Guédant, P.; Rode, W.; Godon, A.; Chanudet, V.; Descloux, S.; Serça, D.

    2015-07-01

    lowest observed at the reservoir surface. Emissions from this area contributed 15-25 % to total annual emissions although they occur on a surface area representative of less than 1 % of the total reservoir surface. We highly recommend measurements of diffusive fluxes around water intakes in order to evaluate if such results can be generalized.

  15. The present-day and future impact of NOx emissions from subsonic aircraft on the atmosphere in relation to the impact of NOx surface sources

    Directory of Open Access Journals (Sweden)

    G. J. M. Velders

    Full Text Available The effect of present-day and future NOx emissions from aircraft on the NOx and ozone concentrations in the atmosphere and the corresponding radiative forcing were studied using a three-dimensional chemistry transport model (CTM and a radiative model. The effects of the aircraft emissions were compared with the effects of the three most important anthropogenic NOx surface sources: road traffic, electricity generation and industrial combustion. From the model results, NOx emissions from aircraft are seen to cause an increase in the NOx and ozone concentrations in the upper troposphere and lower stratosphere, and a positive radiative forcing. For the reference year 1990, the aircraft emissions result in an increase in the NOx concentration at 250 hPa of about 20 ppt in January and 50 ppt in July over the eastern USA, the North Atlantic Flight Corridor and Western Europe, corresponding to a relative increase of about 50%. The maximum increase in the ozone concentrations due to the aircraft emissions is about 3-4 ppb in July over the northern mid-latitudes, corresponding to a relative increase of about 3-4%. The aircraft-induced ozone changes cause a global average radiative forcing of 0.025 W/m2 in July. According to the ANCAT projection for the year 2015, the aircraft NOx emissions in that year will be 90% higher than in the year 1990. As a consequence of this, the calculated NOx perturbation by aircraft emissions increases by about 90% between 1990 and 2015, and the ozone perturbation by about 50-70%. The global average radiative forcing due to the aircraft-induced ozone changes increases by about 50% between 1990 and 2015. In the year 2015, the effects of the aircraft emissions on the ozone burden and radiative forcing are clearly larger than the individual effects of the NOx surface sources. Taking chemical conversion in the aircraft plume into account in the CTM explicitly, by means of modified aircraft NOx emissions, a significant reduction

  16. The present-day and future impact of NOx emissions from subsonic aircraft on the atmosphere in relation to the impact of NOx surface sources

    Directory of Open Access Journals (Sweden)

    P. J. M. Valks

    1999-08-01

    Full Text Available The effect of present-day and future NOx emissions from aircraft on the NOx and ozone concentrations in the atmosphere and the corresponding radiative forcing were studied using a three-dimensional chemistry transport model (CTM and a radiative model. The effects of the aircraft emissions were compared with the effects of the three most important anthropogenic NOx surface sources: road traffic, electricity generation and industrial combustion. From the model results, NOx emissions from aircraft are seen to cause an increase in the NOx and ozone concentrations in the upper troposphere and lower stratosphere, and a positive radiative forcing. For the reference year 1990, the aircraft emissions result in an increase in the NOx concentration at 250 hPa of about 20 ppt in January and 50 ppt in July over the eastern USA, the North Atlantic Flight Corridor and Western Europe, corresponding to a relative increase of about 50%. The maximum increase in the ozone concentrations due to the aircraft emissions is about 3-4 ppb in July over the northern mid-latitudes, corresponding to a relative increase of about 3-4%. The aircraft-induced ozone changes cause a global average radiative forcing of 0.025 W/m2 in July. According to the ANCAT projection for the year 2015, the aircraft NOx emissions in that year will be 90% higher than in the year 1990. As a consequence of this, the calculated NOx perturbation by aircraft emissions increases by about 90% between 1990 and 2015, and the ozone perturbation by about 50-70%. The global average radiative forcing due to the aircraft-induced ozone changes increases by about 50% between 1990 and 2015. In the year 2015, the effects of the aircraft emissions on the ozone burden and radiative forcing are clearly larger than the individual effects of the NOx surface sources. Taking chemical conversion in the aircraft plume into account in the CTM explicitly, by means of modified aircraft NOx emissions, a significant reduction

  17. Validation of the MODIS MOD21 and MOD11 land surface temperature and emissivity products in an arid area of Northwest China

    Science.gov (United States)

    Li, H.; Yang, Y.; Yongming, D.; Cao, B.; Qinhuo, L.

    2017-12-01

    Land surface temperature (LST) is a key parameter for hydrological, meteorological, climatological and environmental studies. During the past decades, many efforts have been devoted to the establishment of methodology for retrieving the LST from remote sensing data and significant progress has been achieved. Many operational LST products have been generated using different remote sensing data. MODIS LST product (MOD11) is one of the most commonly used LST products, which is produced using a generalized split-window algorithm. Many validation studies have showed that MOD11 LST product agrees well with ground measurements over vegetated and inland water surfaces, however, large negative biases of up to 5 K are present over arid regions. In addition, land surface emissivity of MOD11 are estimated by assigning fixed emissivities according to a land cover classification dataset, which may introduce large errors to the LST product due to misclassification of the land cover. Therefore, a new MODIS LSE&E product (MOD21) is developed based on the temperature emissivity separation (TES) algorithm, and the water vapor scaling (WVS) method has also been incorporated into the MODIS TES algorithm for improving the accuracy of the atmospheric correction. The MOD21 product will be released with MODIS collection 6 Tier-2 land products in 2017. Due to the MOD21 products are not available right now, the MODTES algorithm was implemented including the TES and WVS methods as detailed in the MOD21 Algorithm Theoretical Basis Document. The MOD21 and MOD11 C6 LST products are validated using ground measurements and ASTER LST products collected in an arid area of Northwest China during the Heihe Watershed Allied Telemetry Experimental Research (HiWATER) experiment. In addition, lab emissivity spectra of four sand dunes in the Northwest China are also used to validate the MOD21 and MOD11 emissivity products.

  18. WE-AB-303-04: A Tissue Model of Cherenkov Emission From the Skin Surface During Megavoltage X-Ray Radiotherapy

    Energy Technology Data Exchange (ETDEWEB)

    Wiles, A. N.; Loyalka, S. K. [University of Missouri, Columbia, MO (United States); Izaguirre, E. W. [University of Missouri, Columbia, MO (United States); Baylor Scott & White Health, Temple, TX (United States)

    2015-06-15

    Purpose: To develop a tissue model of Cherenkov radiation emitted from the skin surface during external beam radiotherapy. Imaging Cherenkov radiation emitted from human skin allows visualization of the beam position and potentially surface dose estimates, and our goal is to characterize the optical properties of these emissions. Methods: We developed a Monte Carlo model of Cherenkov radiation generated in a semi-infinite tissue slab by megavoltage x-ray beams with optical transmission properties determined by a two-layered skin model. We separate the skin into a dermal and an epidermal layer in our model, where distinct molecular absorbers modify the Cherenkov intensity spectrum in each layer while we approximate the scattering properties with Mie and Rayleigh scattering from the highly structured molecular organization found in human skin. Results: We report on the estimated distributions of the Cherenkov wavelength spectrum, emission angles, and surface distribution for the modeled irradiated skin surface. The expected intensity distribution of Cherenkov radiation emitted from skin shows a distinct intensity peak around 475 nm, the blue region of the visible spectrum, between a pair of optical absorption bands in hemoglobin and a broad plateau beginning near 600 nm and extending to at least 700 nm where melanin and hemoglobin absorption are both low. We also find that the Cherenkov intensity decreases with increasing angle from the surface normal, the majority being emitted within 20 degrees of the surface normal. Conclusion: Our estimate of the spectral distribution of Cherenkov radiation emitted from skin indicates an advantage to using imaging devices with long wavelength spectral responsivity. We also expect the most efficient imaging to be near the surface normal where the intensity is greatest; although for contoured surfaces, the relative intensity across the surface may appear to vary due to decreasing Cherenkov intensity with increased angle from the

  19. Dependence of secondary electron emission on the incident angle and the energy of primary electrons bombarding bowl-structured beryllium surfaces

    International Nuclear Information System (INIS)

    Kawata, Jun; Ohya, Kaoru.

    1994-01-01

    A Monte Carlo simulation of the secondary electron emission from beryllium is combined with a model of bowl structure for surface roughness, for analyzing the difference between the electron emissions for normal and oblique incidences. At normal incidence, with increasing the roughness parameter H/W, the primary energy E pm at which the maximum electron yield occurs becomes higher, and at more than the E pm , the decrease in the yield is slower; where H and W are the depth and width of the bowl structure, respectively. The dispersion of incident angle to the microscopic surface causes a small increase in the yield at oblique incidence, whereas the blocking of primary electrons from bombarding the bottom of the structure causes an opposite trend. The strong anisotropy in the polar angular distribution with respect to the azimuthal angle is calculated at oblique incidence. (author)

  20. Comparison of surface vacuum ultraviolet emissions with resonance level number densities. II. Rare-gas plasmas and Ar-molecular gas mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Boffard, John B., E-mail: jboffard@wisc.edu; Lin, Chun C. [Department of Physics, University of Wisconsin, Madison, Wisconsin 53706 (United States); Wang, Shicong; Wendt, Amy E. [Department of Electrical and Computer Engineering, University of Wisconsin, Madison, Wisconsin 53706 (United States); Culver, Cody [Materials Science Program, University of Wisconsin, Madison, Wisconsin 53706 (United States); Radovanov, Svetlana; Persing, Harold [Applied Materials Inc., Gloucester, Massachusetts 01939 (United States)

    2015-03-15

    Vacuum ultraviolet (VUV) emissions from excited plasma species can play a variety of roles in processing plasmas, including damaging the surface properties of materials used in semiconductor processing. Depending on their wavelength, VUV photons can easily transmit thin upper dielectric layers and affect the electrical characteristics of the devices. Despite their importance, measuring VUV fluxes is complicated by the fact that few materials transmit at VUV wavelengths, and both detectors and windows are easily damaged by plasma exposure. The authors have previously reported on measuring VUV fluxes in pure argon plasmas by monitoring the concentrations of Ar(3p{sup 5}4s) resonance atoms that produce the VUV emissions using noninvasive optical emission spectroscopy in the visible/near-infrared wavelength range [Boffard et al., J. Vac. Sci. Technol., A 32, 021304 (2014)]. Here, the authors extend this technique to other rare-gases (Ne, Kr, and Xe) and argon-molecular gas plasmas (Ar/H{sub 2}, Ar/O{sub 2}, and Ar/N{sub 2}). Results of a model for VUV emissions that couples radiation trapping and the measured rare-gas resonance level densities are compared to measurements made with both a calibrated VUV photodiode and a sodium salicylate fluorescence detection scheme. In these more complicated gas mixtures, VUV emissions from a variety of sources beyond the principal resonance levels of the rare gases are found to contribute to the total VUV flux.

  1. Nitrogen removal and nitrous oxide emission in surface flow constructed wetlands for treating sewage treatment plant effluent: Effect of C/N ratios.

    Science.gov (United States)

    Li, Ming; Wu, Haiming; Zhang, Jian; Ngo, Huu Hao; Guo, Wenshan; Kong, Qiang

    2017-09-01

    In order to design treatment wetlands with maximal nitrogen removal and minimal nitrous oxide (N 2 O) emission, the effect of influent C/N ratios on nitrogen removal and N 2 O emission in surface flow constructed wetlands (SF CWs) for sewage treatment plant effluent treatment was investigated in this study. The results showed that nitrogen removal and N 2 O emission in CWs were significantly affected by C/N ratio of influent. Much higher removal efficiency of NH 4 + -N (98%) and TN (90%) was obtained simultaneously in SF CWs at C/N ratios of 12:1, and low N 2 O emission (8.2mg/m 2 /d) and the percentage of N 2 O-N emission in TN removal (1.44%) were also observed. These results obtained in this study would be utilized to determine how N 2 O fluxes respond to variations in C/N ratios and to improve the sustainability of CWs for wastewater treatment. Copyright © 2017 Elsevier Ltd. All rights reserved.

  2. The role of drainage ditches in greenhouse gas emissions and surface leaching losses from a cutaway peatland cultivated with a perennial bioenergy crop

    Energy Technology Data Exchange (ETDEWEB)

    Hyvonen, N.P.; Huttunen, J.T.; Shurpali, N.J.; Lind, S.E.; Marushchak, M.E.; Martikainen, P.J. [University of Eastern Finland, Kuopio (Finland). Dept. of Environmental Science], E-mail: niina.hyvonen@uef.fi; Heitto, L. [Environmental Research of Savo-Karjala Ltd, Kuopio (Finland)

    2013-06-01

    We studied greenhouse gas (GHG) emissions from drainage ditches and leaching losses in a boreal cutaway peatland cultivated with reed canary grass (Phalaris arundinacea) for bioenergy. The objectives of the study were to assess to what extent GHG emissions from drainage ditches and leaching of carbon and nutrients via surface drainage contribute to the total losses of carbon and nitrogen from the site. The emissions of CH{sub 4}, N{sub 2}O and CO{sub 2} were measured with static chamber methods for three years and leaching losses for seven years. On average, the drainage ditches (covering 6% of the study site area) released 10% of the total CH{sub 4} emission (0.33 g m{sup -2} a{sup -1}), and 1% and 5% of the total N{sub 2}O and CO{sub 2} emissions, respectively. Leaching of total nitrogen and phosphorous were 0.31 and 0.03 g m{sup -2} a{sup -1}, respectively. Leaching values were lower than those reported for agricultural catchments in general. (orig.)

  3. Measurement of yields for electron emission from surfaces upon impact of laser-excited Ar*(4p) and Kr*(5p) atoms

    NARCIS (Netherlands)

    Schohl, S.; Meijer, H.A.J.; Ruf, M.-W.; Hotop, H.

    1992-01-01

    A laser method for the determination of the electron emission coeflicient γ for the impact of slow laser-excited rare gas atoms Rg*[mp5(m+1)p3D3] on surfaces is described. It is based on controlled partial depletion of metastable Rg*[mp5(m+1)s3P2] atoms in a collimated beam by two-step laser

  4. Comparison of field-measured radon diffusion coefficients with laboratory-measured coefficients

    International Nuclear Information System (INIS)

    Lepel, E.A.; Silker, W.B.; Thomas, V.W.; Kalkwarf, D.R.

    1983-04-01

    Experiments were conducted to compare radon diffusion coefficients determined for 0.1-m depths of soils by a steady-state method in the laboratory and diffusion coefficients evaluated from radon fluxes through several-fold greater depths of the same soils covering uranium-mill tailings. The coefficients referred to diffusion in the total pore volume of the soils and are equivalent to values for the quantity, D/P, in the Generic Environmental Impact Statement on Uranium Milling prepared by the US Nuclear Regulatory Commission. Two soils were tested: a well-graded sand and an inorganic clay of low plasticity. For the flux evaluations, radon was collected by adsorption on charcoal following passive diffusion from the soil surface and also from air recirculating through an aluminum tent over the soil surface. An analysis of variance in the flux evaluations showed no significant difference between these two collection methods. Radon diffusion coefficients evaluated from field data were statistically indistinguishable, at the 95% confidence level, from those measured in the laboratory; however, the low precision of the field data prevented a sensitive validation of the laboratory measurements. From the field data, the coefficients were calculated to be 0.03 +- 0.03 cm 2 /s for the sand cover and 0.0036 +- 0.0004 cm 2 /s for the clay cover. The low precision in the coefficients evaluated from field data was attributed to high variation in radon flux with time and surface location at the field site

  5. Dependence of sputtering coefficient on ion dose

    International Nuclear Information System (INIS)

    Colligon, J.S.; Patel, M.H.

    1977-01-01

    The sputtering coefficient of polycrystalline gold bombarded by 10-40 keV Ar + ions had been measured as a function of total ion dose and shown to exhibit oscillations in magnitude between 30 and 100%. Possible experimental errors which would give rise to such an oscillation have been considered, but it is apparent that these factors are unable to explain the measurements. It is proposed that a change in the Sublimation Energy associated with either bulk damage or formation of surface topographical features arising during ion bombardment may be responsible for the observed variations in sputtering coefficient. (author)

  6. The effect of insulated combustion chamber surfaces on direct-injected diesel engine performance, emissions, and combustion

    Science.gov (United States)

    Dickey, Daniel W.; Vinyard, Shannon; Keribar, Rifat

    1988-01-01

    The combustion chamber of a single-cylinder, direct-injected diesel engine was insulated with ceramic coatings to determine the effect of low heat rejection (LHR) operation on engine performance, emissions, and combustion. In comparison to the baseline cooled engine, the LHR engine had lower thermal efficiency, with higher smoke, particulate, and full load carbon monoxide emissions. The unburned hydrocarbon emissions were reduced across the load range. The nitrous oxide emissions increased at some part-load conditions and were reduced slightly at full loads. The poor LHR engine performance was attributed to degraded combustion characterized by less premixed burning, lower heat release rates, and longer combustion duration compared to the baseline cooled engine.

  7. Effects of acetic acid injection and operating conditions on NO emission in a vortexing fluidized bed combustor using response surface methodology

    Energy Technology Data Exchange (ETDEWEB)

    Fuping Qian; Chiensong Chyang; Weishen Yen [Anhui University of Technology, Ma' anshan (China). School of Civil Engineering and Architecture

    2009-07-15

    The effects of acetic acid injection and operating conditions on NO emission were investigated in a pilot scale vortexing fluidized bed combustor (VFBC), an integration of circular freeboard and a rectangular combustion chamber. Operating conditions, such as the stoichiometric oxygen in the combustion chamber, the bed temperature and the injecting location of acetic acid, were determined by means of response surface methodology (RSM), which enables the examination of parameters with a moderate number of experiments. In RSM, NO emission concentration after acetic acid injection and NO removal percentage at the exit of the VFBC are used as the objective function. The results show that the bed temperature has a more important effect on the NO emission than the injecting location of acetic acid and the stoichiometric oxygen in the combustion chamber. Meanwhile, the injecting location of acetic acid and the stoichiometric oxygen in the combustion chamber have a more important effect on the NO removal percentage than the bed temperature. NO emission can be decreased by injecting the acetic acid into the combustion chamber, and NO emission decreases with the height of the acetic acid injecting location above the distributor. On the other hand, NO removal percentage increases with the height of the acetic acid injecting location, and NO emission increases with the stoichiometric oxygen in the combustion chamber and the bed temperature. NO removal percentage increases with the stoichiometric oxygen, and increases first, then decreases with the bed temperature. Also, a higher NO removal percentage could be obtained at 850{sup o}C. 26 refs., 12 figs., 8 tabs.

  8. Application of response surface methodology in optimization of performance and exhaust emissions of secondary butyl alcohol-gasoline blends in SI engine

    International Nuclear Information System (INIS)

    Yusri, I.M.; Mamat, R.; Azmi, W.H.; Omar, A.I.; Obed, M.A.; Shaiful, A.I.M.

    2017-01-01

    Highlights: • Adding 2-butanol in gasoline fuel can improve engine performance. • 2-Butanol addition reduced NO x , CO, and HC but produced higher CO 2 . • RSM was applied to optimize the engine performance and exhaust emissions. - Abstract: Producing an optimal balance between engine performance and exhaust emissions has always been one of the main challenges in automotive technology. This paper examines the use of RSM (response surface methodology) to optimize the engine performance, and exhaust emissions of a spark-ignition (SI) engine which operates with 2-butanol–gasoline blends of 5%, 10%, and 15% called GBu5, GBu10, and GBu15. In the experiments, the engine ran at various speeds for each test fuel and 13 different conditions were constructed. The optimization of the independent variables was performed by means of a statistical tool known as DoE (design of experiments). The desirability approach by RSM was employed with the aim of minimizing emissions and maximizing of performance parameters. Based on the RSM model, performance characteristics revealed that increments of 2-butanol in the blended fuels lead to increasing trends of brake power, brake mean effective pressure and brake thermal efficiency. Nonetheless, marginal higher brake specific fuel consumption was observed. Furthermore, the RSM model suggests that the presence of 2-butanol exhibits a decreasing trend of nitrogen oxides, carbon monoxides, and unburnt hydrocarbon, however, a higher trend was observed for carbon dioxides exhaust emissions. It was established from the study that the GBu15 blend with an engine speed of 3205 rpm was found to be optimal to provide the best performance and emissions characteristics as compared to the other tested blends.

  9. High Resolution CH4 Emissions and Dissolved CH4 Measurements Elucidate Surface Gas Exchange Processes in Toolik Lake, Arctic Alaska

    Science.gov (United States)

    Del Sontro, T.; Sollberger, S.; Kling, G. W.; Shaver, G. R.; Eugster, W.

    2013-12-01

    Approximately 14% of the Alaskan North Slope is covered in lakes of various sizes and depths. Diffusive carbon emissions (CH4 and CO2) from these lakes offset the tundra sink by ~20 %, but the offset would substantially increase if ebullitive CH4 emissions were also considered. Ultimately, arctic lake CH4 emissions are not insignificant in the global CH4 budget and their contribution is bound to increase due to impacts from climate change. Here we present high resolution CH4 emission data as measured via eddy covariance and a Los Gatos gas analyzer during the ice free period from Toolik Lake, a deep (20 m) Arctic lake located on the Alaskan North Slope, over the last few summers. Emissions are relatively low (Gatos gas analyzer. Thus, having both the flux and the CH4 gradient across the air-water interface measured directly, we can calculate k and investigate the processes influencing CH4 gas exchange in this lake. Preliminary results indicate that there are two regimes in wind speed that impact k - one at low wind speeds up to ~5 m s-1 and another at higher wind speeds (max ~10 m s-1). The differential wind speeds during night and day may compound the effect of convective mixing and cause the diurnal variation in observed fluxes.

  10. Solar UV irradiation-induced production of N2O from plant surfaces - low emissions rates but all over the world.

    Science.gov (United States)

    Mikkelsen, T. N.; Bruhn, D.; Ambus, P.

    2016-12-01

    Nitrous oxide (N2O) is an important long-lived greenhouse gas and precursor of stratospheric ozone depleting mono-nitrogen oxides. The atmospheric concentration of N2O is persistently increasing; however, large uncertainties are associated with the distinct source strengths. Here we investigate for the first time N2O emission from terrestrial vegetation in response to natural solar ultra violet radiation. We conducted field site measurements to investigate N2O atmosphere exchange from grass vegetation exposed to solar irradiance with and without UV-screening. Further laboratory tests were conducted with a range of species to study the controls and possible loci of UV-induced N2O emission from plants. Plants released N2O in response to natural sunlight at rates of c. 20-50 nmol m-2 h-1, mostly due to the UV component. The emission rate is temperature dependent with a rather high activation energy indicative for an abiotic process. The prevailing zone for the N2O formation appears to be at the very surface of leaves. However, only c. 26% of the UV-induced N2O appears to originate from plant-N. Further, the process is dependent on atmospheric oxygen concentration. Our work demonstrates that ecosystem emission of the important greenhouse gas, N2O, may be up to c. 30% higher than hitherto assumed.

  11. Husbandry Emissions at the Sub-Facility Scale by Fused Mobile Surface In Situ and Airborne Remote Sensing

    Science.gov (United States)

    Leifer, I.; Melton, C.; Tratt, D. M.; Hall, J. L.; Buckland, K. N.; Frash, J.; Leen, J. B.; Lundquist, T.; Vigil, S. A.

    2017-12-01

    Husbandry methane (CH4) and ammonia (NH3) are strong climate and air pollution drivers. Husbandry emission factors have significant uncertainty and can differ from lab estimates as real-world practices affect emissions including where and how husbandry activities occur, their spatial and temporal relationship to micro-climate (winds, temperature, insolation, rain, and lagoon levels, which vary diurnally and seasonally), and animal care. Research dairies provide a unique opportunity to combine insights on sub-facility scale emissions to identify best practices. Two approaches with significant promise for quantifying husbandry emissions are airborne remote sensing and mobile in situ trace gas with meteorological measurements. Both capture snapshot data to allow deconvolution of temporal and spatial variability, which challenges stationary measurements, while also capturing micro-scale processes, allowing connection of real-world practices to emissions. Mobile in situ concentration data on trace gases and meteorology were collected by AMOG (AutoMObile trace Gas) Surveyor on 10 days spanning 31 months at the California Polytechnic State University Research Dairy, San Luis Obispo, CA. AMOG Surveyor is a commuter vehicle modified for atmospheric science. CH4, NH3, H2O, COS, CO, CO2, H2S, O3, NO, NO2, SO2, NOX, solar spectra, temperature, and winds were measured. The airborne hyperspectral thermal infrared sensor, Mako, collected data on 28 Sept. 2015. Research dairies allow combining insights on sub-facility scale emissions to identify best practices holistically - i.e., considering multiple trace gases. In situ data were collected while transecting plumes, approximately orthogonal to winds. Emission strength and source location were estimated by Gaussian plume inversion, validated by airborne data. Good agreement was found on source strength and location at meter length-scales. Data revealed different activities produced unique emissions with distinct trace gas

  12. Quadrature formulas for Fourier coefficients

    KAUST Repository

    Bojanov, Borislav

    2009-09-01

    We consider quadrature formulas of high degree of precision for the computation of the Fourier coefficients in expansions of functions with respect to a system of orthogonal polynomials. In particular, we show the uniqueness of a multiple node formula for the Fourier-Tchebycheff coefficients given by Micchelli and Sharma and construct new Gaussian formulas for the Fourier coefficients of a function, based on the values of the function and its derivatives. © 2009 Elsevier B.V. All rights reserved.

  13. Measuring of heat transfer coefficient

    DEFF Research Database (Denmark)

    Henningsen, Poul; Lindegren, Maria

    Subtask 3.4 Measuring of heat transfer coefficient Subtask 3.4.1 Design and setting up of tests to measure heat transfer coefficient Objective: Complementary testing methods together with the relevant experimental equipment are to be designed by the two partners involved in order to measure...... the heat transfer coefficient for a wide range of interface conditions in hot and warm forging processes. Subtask 3.4.2 Measurement of heat transfer coefficient The objective of subtask 3.4.2 is to determine heat transfer values for different interface conditions reflecting those typically operating in hot...

  14. Changes in Electrokinetic Coupling Coefficients of Granite under Triaxial Deformation

    Directory of Open Access Journals (Sweden)

    Osamu Kuwano

    2012-01-01

    Full Text Available Electrokinetic phenomena are believed to be the most likely origin of electromagnetic signals preceding or accompanying earthquakes. The intensity of the source current due to the electrokinetic phenomena is determined by the fluid flux and the electrokinetic coupling coefficient called streaming current coefficient; therefore, how the coefficient changes before rupture is essential. Here, we show how the electrokinetic coefficients change during the rock deformation experiment up to failure. The streaming current coefficient did not increase before failure, but continued to decrease up to failure, which is explained in terms of the elastic closure of capillary. On the other hand, the streaming potential coefficient, which is the product of the streaming current coefficient and bulk resistivity of the rock, increased at the onset of dilatancy. It may be due to change in bulk resistivity. Our result indicates that the zeta potential of the newly created surface does not change so much from that of the preexisting fluid rock interface.

  15. Response surface modeling-based source contribution analysis and VOC emission control policy assessment in a typical ozone-polluted urban Shunde, China.

    Science.gov (United States)

    You, Zhiqiang; Zhu, Yun; Jang, Carey; Wang, Shuxiao; Gao, Jian; Lin, Che-Jen; Li, Minhui; Zhu, Zhenghua; Wei, Hao; Yang, Wenwei

    2017-01-01

    To develop a sound ozone (O 3 ) pollution control strategy, it is important to well understand and characterize the source contribution due to the complex chemical and physical formation processes of O 3 . Using the "Shunde" city as a pilot summer case study, we apply an innovative response surface modeling (RSM) methodology based on the Community Multi-Scale Air Quality (CMAQ) modeling simulations to identify the O 3 regime and provide dynamic analysis of the precursor contributions to effectively assess the O 3 impacts of volatile organic compound (VOC) control strategy. Our results show that Shunde is a typical VOC-limited urban O 3 polluted city. The "Jiangmen" city, as the main upper wind area during July 2014, its VOCs and nitrogen oxides (NO x ) emissions make up the largest contribution (9.06%). On the contrary, the contribution from local (Shunde) emission is lowest (6.35%) among the seven neighbor regions. The local VOCs industrial source emission has the largest contribution comparing to other precursor emission sectors in Shunde. The results of dynamic source contribution analysis further show that the local NO x control could slightly increase the ground O 3 under low (10.00%) and medium (40.00%) reduction ratios, while it could start to turn positive to decrease ground O 3 under the high NO x abatement ratio (75.00%). The real-time assessment of O 3 impacts from VOCs control strategies in Pearl River Delta (PRD) shows that the joint regional VOCs emission control policy will effectively reduce the ground O 3 concentration in Shunde. Copyright © 2016. Published by Elsevier B.V.

  16. Aerosol Direct, Indirect, Semidirect, and Surface Albedo Effects from Sector Contributions Based on the IPCC AR5 Emissions for Preindustrial and Present-day Conditions

    Science.gov (United States)

    Bauer, Susanne E.; Menon, Surabi

    2012-01-01

    The anthropogenic increase in aerosol concentrations since preindustrial times and its net cooling effect on the atmosphere is thought to mask some of the greenhouse gas-induced warming. Although the overall effect of aerosols on solar radiation and clouds is most certainly negative, some individual forcing agents and feedbacks have positive forcing effects. Recent studies have tried to identify some of those positive forcing agents and their individual emission sectors, with the hope that mitigation policies could be developed to target those emitters. Understanding the net effect of multisource emitting sectors and the involved cloud feedbacks is very challenging, and this paper will clarify forcing and feedback effects by separating direct, indirect, semidirect and surface albedo effects due to aerosols. To this end, we apply the Goddard Institute for Space Studies climate model including detailed aerosol microphysics to examine aerosol impacts on climate by isolating single emission sector contributions as given by the Coupled Model Intercomparison Project Phase 5 (CMIP5) emission data sets developed for Intergovernmental Panel on Climate Change (IPCC) AR5. For the modeled past 150 years, using the climate model and emissions from preindustrial times to present-day, the total global annual mean aerosol radiative forcing is -0.6 W/m(exp 2), with the largest contribution from the direct effect (-0.5 W/m(exp 2)). Aerosol-induced changes on cloud cover often depends on cloud type and geographical region. The indirect (includes only the cloud albedo effect with -0.17 W/m(exp 2)) and semidirect effects (-0.10 W/m(exp 2)) can be isolated on a regional scale, and they often have opposing forcing effects, leading to overall small forcing effects on a global scale. Although the surface albedo effects from aerosols are small (0.016 W/m(exp 2)), triggered feedbacks on top of the atmosphere (TOA) radiative forcing can be 10 times larger. Our results point out that each

  17. Permeability dependence of streaming potential coefficient in porous media

    NARCIS (Netherlands)

    Thanh, L.D.; Sprik, R.

    2015-01-01

    In theory, the streaming potential coefficient depends not only on the zeta potential but also on the permeability of the rocks that partially determines the surface conductivity of the rocks. However, in practice, it is hard to show the permeability dependence of streaming potential coefficients

  18. Influence of a single lightning discharge on the intensity of an air electric field and acoustic emission of near-surface rocks

    Directory of Open Access Journals (Sweden)

    S. E. Smirnov

    2012-10-01

    Full Text Available The effect was observed as a sharp fall of the electric potential gradient from +80 V m−1 down to –21 V m−1. After that the field returned to its normal level according to the formula of the capacitor discharge with 17 s characteristic time. Simultaneously, the response of the acoustic emission of surface rocks in the range of frequencies between 6.5 kHz and 11 kHz was evaluated.

  19. Probabilistic estimation of future emissions of isoprene and surface oxidant chemistry associated with land-use change in response to growing food needs

    Directory of Open Access Journals (Sweden)

    C. J. Hardacre

    2013-06-01

    Full Text Available We quantify the impact of land-use change, determined by our growing demand for food and biofuel production, on isoprene emissions and subsequent atmospheric oxidant chemistry in 2015 and 2030, relative to 1990, ignoring compound climate change effects over that period. We estimate isoprene emissions from an ensemble (n = 1000 of land-use change realizations from 1990–2050, broadly guided by the IPCC AR4/SRES scenarios A1 and B1. We also superimpose land-use change required to address projected biofuel usage using two scenarios: (1 assuming that world governments make no changes to biofuel policy after 2009, and (2 assuming that world governments develop biofuel policy with the aim of keeping equivalent atmospheric CO2 at 450 ppm. We present the median and interquartile range (IQR statistics of the ensemble and show that land-use change between −1.50 × 1012 m2 to +6.06 × 1012 m2 was found to drive changes in the global isoprene burden of −3.5 to +2.8 Tg yr−1 in 2015 and −7.7 to +6.4 Tg yr−1 in 2030. We use land-use change realizations corresponding to the median and IQR of these emission estimates to drive the GEOS-Chem global 3-D chemistry transport model to investigate the perturbation to global and regional surface concentrations of isoprene, nitrogen oxides (NO+NO2, and the atmospheric concentration and deposition of ozone (O3. We show that across subcontinental regions the monthly surface O3 increases by 0.1–0.8 ppb, relative to a zero land-use change calculation, driven by increases (decreases in surface isoprene in high (low NOx environments. At the local scale (4° × 5° we find that surface O3 increases by 5–12 ppb over temperate North America, China and boreal Eurasia, driven by large increases in isoprene emissions from short-rotation coppice crop cultivation for biofuel production.

  20. Surface-plasmon-induced modification on the spontaneous emission spectrum via subwavelength-confined anisotropic Purcell factor.

    Science.gov (United States)

    Gu, Ying; Wang, Luojia; Ren, Pan; Zhang, Junxiang; Zhang, Tiancai; Martin, Olivier J F; Gong, Qihuang

    2012-05-09

    The mechanism of using the anisotropic Purcell factor to control the spontaneous emission linewidths in a four-level atom is theoretically demonstrated; if the polarization angle bisector of the two dipole moments lies along the axis of large/small Purcell factor, destructive/constructive interference narrows/widens the fluorescence center spectral lines. Large anisotropy of the Purcell factor, confined in the subwavelength optical mode volume, leads to rapid spectral line narrowing of atom approaching a metallic nanowire, nanoscale line width pulsing following periodically varying decay rates near a periodic metallic nanostructure, and dramatic modification on the spontaneous emission spectrum near a custom-designed resonant plasmon nanostructure. The combined system opens a good perspective for applications in ultracompact active quantum devices.