WorldWideScience

Sample records for surface conversion source

  1. Development of a dc low pressure D- surface-conversion source using a 10-cm-diameter solid barium converter

    International Nuclear Information System (INIS)

    Kwan, J.W.; Anderson, O.A.; Chan, C.F.; Cooper, W.S.; deVries, G.J.; Kunkel, W.B.; Leung, K.N.; Lietzke, A.F.; Steele, W.F.; van Os, C.F.A.; Wells, R.P.; Williams, M.D.

    1991-09-01

    A D - surface-conversion source using a solid barium converter is designed for steady-state operation to produce 200 mA of D - . A similar ion source of twice the size as the one discussed here will meet the requirements set by the present US-ITER neutral beam injector design. Among the possible types of ion sources being considered for the US-ITER neutral beam design, the barium converter surface-conversion source is the only kind that does not use cesium in the discharge. This absence of cesium will minimize the number of accelerator breakdowns. 15 refs., 4 figs

  2. Modeling of H- surface conversion sources; binary (H-Ba) and ternary (H-Cs/W) converter arrangements

    International Nuclear Information System (INIS)

    van Os, C.F.A.; Kunkel, W.B.; Leguijt, C.; Los, J.

    1991-01-01

    The production process for the formation of H - ions in a surface conversion source is sputtering of hydrogen atoms from the converter surface layers by incident positive ions, followed by electron attachment via resonant charge exchange with the converter surface. The sputtering process is in direct relation to the converter surface composition. New experimental data led us to identify two different classes of converters: metallic converters, like solid barium(binary) and adlayer converters, like cesium on tungsten (ternary). For a binary converter the hydrogen in the surface layers is directly sputtered by the incoming ions. Consequently, the negative ion yield scales with the hydrogen concentration in the surface layers. In the cesium/tungsten system (ternary) the hydrogen at the surface is believed to be sandwiched between the cesium adlayer and the tungsten surface. Hence, the negative ion yield scales with the sputter coefficient of hydrogen on adsorbed cesium. This is experimentally confirmed

  3. Creating Open Source Conversation

    Science.gov (United States)

    Sheehan, Kate

    2009-01-01

    Darien Library, where the author serves as head of knowledge and learning services, launched a new website on September 1, 2008. The website is built with Drupal, an open source content management system (CMS). In this article, the author describes how she and her colleagues overhauled the library's website to provide an open source content…

  4. Heterogeneous conversion of NO2 on secondary organic aerosol surfaces: A possible source of nitrous acid (HONO in the atmosphere?

    Directory of Open Access Journals (Sweden)

    R. Bröske

    2003-01-01

    Full Text Available The heterogeneous conversion of NO2 on different secondary organic aerosols (SOA was investigated with the focus on a possible formation of nitrous acid (HONO. In one set of experiments different organic aerosols were produced in the reactions of O3 with alpha-pinene, limonene or catechol and OH radicals with toluene or limonene, respectively. The aerosols were sampled on filters and exposed to humidified NO2  mixtures under atmospheric conditions. The estimated upper limits for the uptake coefficients of NO2  and the reactive uptake coefficients NO2  -> HONO are in the range of 10-6 and 10-7, respectively. The integrated HONO formation for 1 h reaction time was 13 cm-2 geometrical surface and 17 g-1 particle mass. In a second set of experiments the conversion of NO2 into HONO in the presence of organic particles was carried out in an aerosol flow tube under atmospheric conditions. In this case the aerosols were produced in the reaction of O3 with beta-pinene, limonene or catechol, respectively. The upper limits for the reactive uptake coefficients NO2 -> HONO were in the range of 7 x 10-7 - 9 x 10-6. The results from the present study show that heterogeneous formation of nitrous acid on secondary organic aerosols (SOA is unimportant for the atmosphere.

  5. Helicon plasma generator-assisted surface conversion ion source for the production of H(-) ion beams at the Los Alamos Neutron Science Center.

    Science.gov (United States)

    Tarvainen, O; Rouleau, G; Keller, R; Geros, E; Stelzer, J; Ferris, J

    2008-02-01

    The converter-type negative ion source currently employed at the Los Alamos Neutron Science Center (LANSCE) is based on cesium enhanced surface production of H(-) ion beams in a filament-driven discharge. In this kind of an ion source the extracted H(-) beam current is limited by the achievable plasma density which depends primarily on the electron emission current from the filaments. The emission current can be increased by increasing the filament temperature but, unfortunately, this leads not only to shorter filament lifetime but also to an increase in metal evaporation from the filament, which deposits on the H(-) converter surface and degrades its performance. Therefore, we have started an ion source development project focused on replacing these thermionic cathodes (filaments) of the converter source by a helicon plasma generator capable of producing high-density hydrogen plasmas with low electron energy. In our studies which have so far shown that the plasma density of the surface conversion source can be increased significantly by exciting a helicon wave in the plasma, and we expect to improve the performance of the surface converter H(-) ion source in terms of beam brightness and time between services. The design of this new source and preliminary results are presented, along with a discussion of physical processes relevant for H(-) ion beam production with this novel design. Ultimately, we perceive this approach as an interim step towards our long-term goal, combining a helicon plasma generator with an SNS-type main discharge chamber, which will allow us to individually optimize the plasma properties of the plasma cathode (helicon) and H(-) production (main discharge) in order to further improve the brightness of extracted H(-) ion beams.

  6. Helicon plasma generator-assisted surface conversion ion source for the production of H- ion beams at the Los Alamos Neutron Science Centera)

    Science.gov (United States)

    Tarvainen, O.; Rouleau, G.; Keller, R.; Geros, E.; Stelzer, J.; Ferris, J.

    2008-02-01

    The converter-type negative ion source currently employed at the Los Alamos Neutron Science Center (LANSCE) is based on cesium enhanced surface production of H- ion beams in a filament-driven discharge. In this kind of an ion source the extracted H- beam current is limited by the achievable plasma density which depends primarily on the electron emission current from the filaments. The emission current can be increased by increasing the filament temperature but, unfortunately, this leads not only to shorter filament lifetime but also to an increase in metal evaporation from the filament, which deposits on the H- converter surface and degrades its performance. Therefore, we have started an ion source development project focused on replacing these thermionic cathodes (filaments) of the converter source by a helicon plasma generator capable of producing high-density hydrogen plasmas with low electron energy. In our studies which have so far shown that the plasma density of the surface conversion source can be increased significantly by exciting a helicon wave in the plasma, and we expect to improve the performance of the surface converter H- ion source in terms of beam brightness and time between services. The design of this new source and preliminary results are presented, along with a discussion of physical processes relevant for H- ion beam production with this novel design. Ultimately, we perceive this approach as an interim step towards our long-term goal, combining a helicon plasma generator with an SNS-type main discharge chamber, which will allow us to individually optimize the plasma properties of the plasma cathode (helicon) and H- production (main discharge) in order to further improve the brightness of extracted H- ion beams.

  7. Helicon plasma generator-assisted surface conversion ion source for the production of H- ion beams at the Los Alamos Neutron Science Center

    International Nuclear Information System (INIS)

    Tarvainen, O.; Rouleau, G.; Keller, R.; Geros, E.; Stelzer, J.; Ferris, J.

    2008-01-01

    The converter-type negative ion source currently employed at the Los Alamos Neutron Science Center (LANSCE) is based on cesium enhanced surface production of H - ion beams in a filament-driven discharge. In this kind of an ion source the extracted H - beam current is limited by the achievable plasma density which depends primarily on the electron emission current from the filaments. The emission current can be increased by increasing the filament temperature but, unfortunately, this leads not only to shorter filament lifetime but also to an increase in metal evaporation from the filament, which deposits on the H - converter surface and degrades its performance. Therefore, we have started an ion source development project focused on replacing these thermionic cathodes (filaments) of the converter source by a helicon plasma generator capable of producing high-density hydrogen plasmas with low electron energy. In our studies which have so far shown that the plasma density of the surface conversion source can be increased significantly by exciting a helicon wave in the plasma, and we expect to improve the performance of the surface converter H - ion source in terms of beam brightness and time between services. The design of this new source and preliminary results are presented, along with a discussion of physical processes relevant for H - ion beam production with this novel design. Ultimately, we perceive this approach as an interim step towards our long-term goal, combining a helicon plasma generator with an SNS-type main discharge chamber, which will allow us to individually optimize the plasma properties of the plasma cathode (helicon) and H - production (main discharge) in order to further improve the brightness of extracted H - ion beams

  8. Surface Plasmon-Assisted Solar Energy Conversion.

    Science.gov (United States)

    Dodekatos, Georgios; Schünemann, Stefan; Tüysüz, Harun

    2016-01-01

    The utilization of localized surface plasmon resonance (LSPR) from plasmonic noble metals in combination with semiconductors promises great improvements for visible light-driven photocatalysis, in particular for energy conversion. This review summarizes the basic principles of plasmonic photocatalysis, giving a comprehensive overview about the proposed mechanisms for enhancing the performance of photocatalytically active semiconductors with plasmonic devices and their applications for surface plasmon-assisted solar energy conversion. The main focus is on gold and, to a lesser extent, silver nanoparticles in combination with titania as semiconductor and their usage as active plasmonic photocatalysts. Recent advances in water splitting, hydrogen generation with sacrificial organic compounds, and CO2 reduction to hydrocarbons for solar fuel production are highlighted. Finally, further improvements for plasmonic photocatalysts, regarding performance, stability, and economic feasibility, are discussed for surface plasmon-assisted solar energy conversion.

  9. Tritiated hydrogen conversion on heated metallic surfaces

    International Nuclear Information System (INIS)

    Ionita, G.; Mihaila, V.; Purghel, L.; Rebigan, F.

    1995-01-01

    This work reports investigations on tritiated hydrogen conversion to tritiated water on heated metallic surfaces. The HT conversion process has been revealed for copper, aluminium and stainless steel W4541 surfaces in the temperature range 150 to 300 o C, in case of the static regime and in the range 250 to 400 o C for the dynamic case. The most significant catalytic activity was shown by the copper sample. Studies on this subject are used as input information for different nuclear accident scenarios implying tritium leakage

  10. Energy technology sources, systems and frontier conversion

    CERN Document Server

    Ohta, Tokio

    1994-01-01

    This book provides a concise and technical overview of energy technology: the sources of energy, energy systems and frontier conversion. As well as serving as a basic reference book for professional scientists and students of energy, it is intended for scientists and policy makers in other disciplines (including practising engineers, biologists, physicists, economists and managers in energy related industries) who need an up-to-date and authoritative guide to the field of energy technology.Energy systems and their elemental technologies are introduced and evaluated from the view point

  11. Surface effects on converse piezoelectricity of crystals.

    Science.gov (United States)

    Molayem, Mohammad; Springborg, Michael; Kirtman, Bernard

    2017-09-20

    The contribution of surface units to bulk properties are often neglected in theoretical and computational studies of crystalline systems. We demonstrate that this assumption has to be made with caution in the case of (electric field) polarization. As a generalization of an earlier work on quasi-one-dimensional systems [Springborg, et al., Phys. Rev. B: Condens. Matter Mater. Phys., 2010, 82, 165442], it is shown that the polarization for 2D and 3D systems contains a surface contribution that can, in principle, take any value (within physical limits) and has consequences for converse piezoelectric responses. Subsequently, we determine the surface effects quantitatively for a group of ferroelectric perovskite structures. Our results indicate that such contributions can be substantial.

  12. Method of electroplating a conversion electron emitting source on implant

    Science.gov (United States)

    Srivastava, Suresh C [Setauket, NY; Gonzales, Gilbert R [New York, NY; Adzic, Radoslav [East Setauket, NY; Meinken, George E [Middle Island, NY

    2012-02-14

    Methods for preparing an implant coated with a conversion electron emitting source (CEES) are disclosed. The typical method includes cleaning the surface of the implant; placing the implant in an activating solution comprising hydrochloric acid to activate the surface; reducing the surface by H.sub.2 evolution in H.sub.2SO.sub.4 solution; and placing the implant in an electroplating solution that includes ions of the CEES, HCl, H.sub.2SO.sub.4, and resorcinol, gelatin, or a combination thereof. Alternatively, before tin plating, a seed layer is formed on the surface. The electroplated CEES coating can be further protected and stabilized by annealing in a heated oven, by passivation, or by being covered with a protective film. The invention also relates to a holding device for holding an implant, wherein the device selectively prevents electrodeposition on the portions of the implant contacting the device.

  13. Surface negative ion production in ion sources

    International Nuclear Information System (INIS)

    Belchenko, Y.

    1993-01-01

    Negative ion sources and the mechanisms for negative ion production are reviewed. Several classes of sources with surface origin of negative ions are examined in detail: surface-plasma sources where ion production occurs on the electrode in contact with the plasma, and ''pure surface'' sources where ion production occurs due to conversion or desorption processes. Negative ion production by backscattering, impact desorption, and electron- and photo-stimulated desorption are discussed. The experimental efficiencies of intense surface negative ion production realized on electrodes contacted with hydrogen-cesium or pure hydrogen gas-discharge plasma are compared. Recent modifications of surface-plasma sources developed for accelerator and fusion applications are reviewed in detail

  14. Implosive Thermal Plasma Source for Energy Conversion

    Czech Academy of Sciences Publication Activity Database

    Šonský, Jiří; Tesař, Václav; Gruber, Jan; Mašláni, Alan

    2017-01-01

    Roč. 4, č. 1 (2017), s. 87-90 ISSN 2336-2626 Institutional support: RVO:61388998 ; RVO:61389021 Keywords : implosion * thermal plasma * detonation wave Subject RIV: BL - Plasma and Gas Discharge Physics; BL - Plasma and Gas Discharge Physics (UFP-V) OBOR OECD: Fluids and plasma physics (including surface physics); Fluids and plasma physics (including surface physics) (UFP-V) https://ppt.fel.cvut.cz/ppt2017.html#number1

  15. Impedance-Source Networks for Electric Power Conversion Part II

    DEFF Research Database (Denmark)

    Siwakoti, Yam P.; Peng, Fang Zheng; Blaabjerg, Frede

    2015-01-01

    Impedance-source networks cover the entire spectrum of electric power conversion applications (dc-dc, dc-ac, ac-dc, ac-ac) controlled and modulated by different modulation strategies to generate the desired dc or ac voltage and current at the output. A comprehensive review of various impedance......-source-network-based power converters has been covered in a previous paper and main topologies were discussed from an application point of view. Now Part II provides a comprehensive review of the most popular control and modulation strategies for impedance-source network-based power converters/inverters. These methods...

  16. Impedance-Source Networks for Electric Power Conversion Part I

    DEFF Research Database (Denmark)

    Siwakoti, Yam P.; Peng, Fang Zheng; Blaabjerg, Frede

    2015-01-01

    power chain, which may improve the reliability and performance of the power system. The first part of this paper provides a comprehensive review of the various impedance-source-networks-based power converters and discusses the main topologies from an application point of view. This review paper...... is the first of its kind with the aim of providing a “one-stop” information source and a selection guide on impedance-source networks for power conversion for researchers, designers, and application engineers. A comprehensive review of various modeling, control, and modulation techniques for the impedance...

  17. Conversion degrees of resin composites using different light sources.

    Science.gov (United States)

    Ozturk, Bora; Cobanoglu, Nevin; Cetin, Ali Rıza; Gunduz, Beniz

    2013-01-01

    The objective of this study was to compare the conversion degree of six different composite materials (Filtek Z 250, Filtek P60, Spectrum TPH, Pertac II, Clearfil AP-X, and Clearfil Photo Posterior) using three different light sources (blue light-emitting diode [LED], plasma arc curing [PAC], and conventional halogen lamp [QTH]). Composites were placed in a 2 mm thick and 5 mm diameter Teflon molds and light cured from the top using three methods: LED for 40 s, PAC for 10 s, and QTH for 40 s. A Fourier Transform Infrared Spectroscopy (FTIR) was used to evaluate the degree of conversion (DC) (n=5). The results were analyzed with two-way analysis of variance and Tukey HSD test. DC was significantly influenced by two variables, light source and composite (PDC values than LED (PDC values of QTH and PAC or between DC values of LED and PAC (P>.05). The highest DC was observed in the Z 250 composite specimens following photopolymerization with QTH (70%). The lowest DC was observed in Clearfil Photo Posterior composite specimens following photo-polymerization with LED (43%). The DC was found to be changing according to both light sources and composite materials used. Conventional light halogen (QTH) from light sources and Filtek Z 250 and Filtek P 60 among composite materials showed the most DC performance.

  18. Energy conversion of source separated packaging; Energiutvinning ur kaellsorterade foerpackningsfraktioner

    Energy Technology Data Exchange (ETDEWEB)

    Blidholm, O; Wiklund, S E [AaF-Energikonsult (Sweden); Bauer, A C [Energikonsult A. Bauer (Sweden)

    1997-02-01

    The basic idea of this project is to study the possibilities to use source separated combustible material for energy conversion in conventional solid fuel boilers (i.e. not municipal waste incineration plants). The project has been carried out in three phases. During phase 1 and 2 a number of fuel analyses of different fractions were carried out. During phase 3 two combustion tests were carried out; (1) a boiler with grate equipped with cyclone, electrostatic precipitator and flue gas condenser, and (2) a bubbling fluidized bed boiler with electrostatic precipitator and flue gas condenser. During the tests source separated paper and plastic packagings were co-fired with biomass fuels. The mixing rate of packagings was approximately 15%. This study reports the results of phase 3 and the conclusions of the whole project. The technical terms of using packaging as fuel are good. The technique is available for shredding both paper and plastic packaging. The material can be co-fired with biomass. The economical terms of using source separated packaging for energy conversion can be very advantageous, but can also form obstacles. The result is to a high degree guided by such facts as how the fuel is collected, transported, reduced in size and handled at the combustion plant. The results of the combustion tests show that the environmental terms of using source separated packaging for energy conversion are good. The emissions of heavy metals into the atmosphere are very low. The emissions are well below the emission standards for waste incineration plants. 35 figs, 13 tabs, 8 appendices

  19. Assessment of dynamic energy conversion systems for radioisotope heat sources

    International Nuclear Information System (INIS)

    Thayer, G.R.; Mangeng, C.A.

    1985-06-01

    The use of dynamic conversion systems to convert the heat generated in a 7500 W(t) 90 Sr radioisotopic heat source to electricity is examined. The systems studies were Stirling; Brayton Cycle; three organic Rankines (ORCs) (Barber-Nichols/ORMAT, Sundstrand, and TRW); and an organic Rankine plus thermoelectrics. The systems were ranked for a North Warning System mission using a Los Alamos Multiattribute Decision Theory code. Three different heat source designs were used: case I with a beginning of life (BOL) source temperature of 640 C, case II with a BOL source temperature of 745 0 C, and case III with a BOL source temperature of 945 0 C. The Stirling engine system was the top-ranked system of cases I and II, closely followed by the ORC systems in case I and ORC plus thermoelectrics in case II. The Brayton cycle system was top-ranked for case III, with the Stirling engine system a close second. The use of 238 Pu in heat source sizes of 7500 W(t) was examined and found to be questionable because of cost and material availability and because of additional requirements for analysis of safeguards and critical mass

  20. Absorption and backscatter of internal conversion electrons in the measurements of surface contamination of 137Cs

    International Nuclear Information System (INIS)

    Yunoki, A.; Kawada, Y.; Yamada, T.; Unno, Y.; Sato, Y.; Hino, Y.

    2013-01-01

    We measured 4π and 2π counting efficiencies for internal conversion electrons (ICEs), gross β-particles and also β-rays alone with various source conditions regarding absorber and backing foil thickness using e-X coincidence technique. Dominant differences regarding the penetration, attenuation and backscattering properties among ICEs and β-rays were revealed. Although the abundance of internal conversion electrons of 137 Cs- 137 Ba is only 9.35%, 60% of gross counts may be attributed to ICEs in worse source conditions. This information will be useful for radionuclide metrology and for surface contamination monitoring. - Highlights: • Counting efficiencies for internal conversion electrons from 137 Cs were measured, and compared with those for β-rays. • Electron-X coincidence technique was employed. • A thin NaI(Tl) scintillation detector was used for X-ray detection. • Backscattering fractions of electrons and beta particles were studied by similar experiments

  1. Nano Sensing and Energy Conversion Using Surface Plasmon Resonance (SPR

    Directory of Open Access Journals (Sweden)

    Iltai (Isaac Kim

    2015-07-01

    Full Text Available Nanophotonic technique has been attracting much attention in applications of nano-bio-chemical sensing and energy conversion of solar energy harvesting and enhanced energy transfer. One approach for nano-bio-chemical sensing is surface plasmon resonance (SPR imaging, which can detect the material properties, such as density, ion concentration, temperature, and effective refractive index in high sensitivity, label-free, and real-time under ambient conditions. Recent study shows that SPR can successfully detect the concentration variation of nanofluids during evaporation-induced self-assembly process. Spoof surface plasmon resonance based on multilayer metallo-dielectric hyperbolic metamaterials demonstrate SPR dispersion control, which can be combined with SPR imaging, to characterize high refractive index materials because of its exotic optical properties. Furthermore, nano-biophotonics could enable innovative energy conversion such as the increase of absorption and emission efficiency and the perfect absorption. Localized SPR using metal nanoparticles show highly enhanced absorption in solar energy harvesting. Three-dimensional hyperbolic metamaterial cavity nanostructure shows enhanced spontaneous emission. Recently ultrathin film perfect absorber is demonstrated with the film thickness is as low as ~1/50th of the operating wavelength using epsilon-near-zero (ENZ phenomena at the wavelength close to SPR. It is expected to provide a breakthrough in sensing and energy conversion applications using the exotic optical properties based on the nanophotonic technique.

  2. Power conversion and control methods for renewable energy sources

    Science.gov (United States)

    Yu, Dachuan

    2005-07-01

    In recent years, there has been an increase in the use of renewable energy due to the growing concern over the pollution caused by fossil-fuel-based energy. Renewable energy sources, such as photovoltaic (PV) and fuel cell, can be used to enhance the safety, reliability, sustainability, and transmission efficiency of a power system. This dissertation focuses on the power conversion and control for two major renewable-energy sources: PV and fuel cell. Firstly, a current-based, maximum power-point tracking (MPPT) algorithm is proposed for PV energy. An economical converter system using the above scheme for converting the output from PV panels into 60 Hz AC voltage is developed and built. Secondly, a novel circuit model for the Proton Exchange Membrane (PEM) fuel-cell stack that is useful in the design and analysis of fuel-cell-based power systems is proposed. This Pspice-based model uses elements available in the Pspice library with some modifications to represent both the static and dynamic responses of a PEM fuel-cell module. The accuracy of the model is verified by comparing the simulation and experimental results. Thirdly, a DSP-controlled three-phase induction-motor drive using constant voltage over frequency is built and can be used in a fuel-cell automobile. A hydrogen sensor is used in the drive to both sound an alarm and shut down the inverter trigger pulses through the DSP. Finally, a hybrid power system consisting of PV panels and fuel cell is proposed and built. In the proposed system, PV panels can supply most of the power when the sunlight is available, and the excess power required by the load is supplied by a fuel cell. Load sharing between a fuel cell (FC) and the PV panel is investigated by both simulation and experiments.

  3. Plasma conversion of methane into higher hydrocarbons at surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Sackinger, W.M.; Kamath, V.A. [Univ. of Alaska, Fairbanks, AK (United States)

    1995-12-31

    Natural gas is widely abundant, is easily withdrawn from reservoirs, is commonly produced as an associated gas along with crude oil production, and is found in many geologic settings as a resource separate from oil. A much larger fraction of the natural gas may be produced from a gas reservoir, as compared with a crude oil reservoir. However, natural gas is normally transported by pipeline, and the energy throughput of such a pipeline is perhaps only 20% to 30% of the throughput of an oil pipeline of the same size and cost. Gas is difficult to transport in moderate quantities at low cost, as it must either have a special pipeline or must be liquified into LNG, shipped in cryogenic LNG tankers, and regasified chemical stability of methane has made it difficult to convert it directly into conventional hydrocarbon fuel mixtures, and has also impeded its use as a feedstock for petrochemical production. Experiments are described in which a methane plasma is created, and the resulting methyl and hydrogen ions have been accelerated within a microchannel array so that they interact with neutral methane molecules on the inside surfaces of the microchannels. No catalysts are used, and the device operates at room temperature. Impact energies of the ions are in the range of 15 ev to greater than 100 ev, and the energy delivered in the interaction at the surfaces has caused the production of larger hydrocarbon molecules, such as C{sub 2}H{sub 2}, C{sub 2}H{sub 4}, and C{sub 2}H{sub 6}, along with C{sub 3}, C{sub 4}, C{sub 5}, C{sub 6}, C{sub 7}, and C{sub 8} molecules. Conversion effectiveness is greater at higher pressure, due to the increased ionic activity. The costs of production of the plasma conversion devices are projected to be quite low, and the technology appears to be commercially and economically feasible.

  4. Optical surfacing via linear ion source

    International Nuclear Information System (INIS)

    Wu, Lixiang; Wei, Chaoyang; Shao, Jianda

    2017-01-01

    We present a concept of surface decomposition extended from double Fourier series to nonnegative sinusoidal wave surfaces, on the basis of which linear ion sources apply to the ultra-precision fabrication of complex surfaces and diffractive optics. The modified Fourier series, or sinusoidal wave surfaces, build a relationship between the fabrication process of optical surfaces and the surface characterization based on power spectral density (PSD) analysis. Also, we demonstrate that the one-dimensional scanning of linear ion source is applicable to the removal of mid-spatial frequency (MSF) errors caused by small-tool polishing in raster scan mode as well as the fabrication of beam sampling grating of high diffractive uniformity without a post-processing procedure. The simulation results show that optical fabrication with linear ion source is feasible and even of higher output efficiency compared with the conventional approach.

  5. Optical surfacing via linear ion source

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Lixiang, E-mail: wulx@hdu.edu.cn [Key Lab of RF Circuits and Systems of Ministry of Education, Zhejiang Provincial Key Lab of LSI Design, Microelectronics CAD Center, College of Electronics and Information, Hangzhou Dianzi University, Hangzhou (China); Wei, Chaoyang, E-mail: siomwei@siom.ac.cn [Key Laboratory of Materials for High Power Laser, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800 (China); Shao, Jianda, E-mail: jdshao@siom.ac.cn [Key Laboratory of Materials for High Power Laser, Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800 (China)

    2017-04-15

    We present a concept of surface decomposition extended from double Fourier series to nonnegative sinusoidal wave surfaces, on the basis of which linear ion sources apply to the ultra-precision fabrication of complex surfaces and diffractive optics. The modified Fourier series, or sinusoidal wave surfaces, build a relationship between the fabrication process of optical surfaces and the surface characterization based on power spectral density (PSD) analysis. Also, we demonstrate that the one-dimensional scanning of linear ion source is applicable to the removal of mid-spatial frequency (MSF) errors caused by small-tool polishing in raster scan mode as well as the fabrication of beam sampling grating of high diffractive uniformity without a post-processing procedure. The simulation results show that optical fabrication with linear ion source is feasible and even of higher output efficiency compared with the conventional approach.

  6. Reciprocity relations and the mode conversion-absorption equation with an inhomogeneous source term

    International Nuclear Information System (INIS)

    Cho, S.; Swanson, D.G.

    1990-01-01

    The fourth-order mode conversion equation is solved completely via the Green's function to include an inhomogeneous source term. This Green's function itself contains all the plasma responsive effects such as mode conversion and absorption, and can be used to describe the spontaneous emission. In the course of the analysis, the reciprocity relations between coupling parameters are proved

  7. Closed Brayton Cycle Power Conversion Unit for Fission Surface Power Phase I Final Report

    Science.gov (United States)

    Fuller, Robert L.

    2010-01-01

    A Closed Brayton cycle power conversion system has been developed to support the NASA fission surface power program. The goal is to provide electricity from a small nuclear reactor heat source for surface power production for lunar and Mars environments. The selected media for a heat source is NaK 78 with water as a cooling source. The closed Brayton cycle power was selected to be 12 kWe output from the generator terminals. A heat source NaK temperature of 850 K plus or minus 25 K was selected. The cold source water was selected at 375 K plus or minus 25 K. A vacuum radiation environment of 200 K is specified for environmental operation. The major components of the system are the power converter, the power controller, and the top level data acquisition and control unit. The power converter with associated sensors resides in the vacuum radiation environment. The power controller and data acquisition system reside in an ambient laboratory environment. Signals and power are supplied across the pressure boundary electrically with hermetic connectors installed on the vacuum vessel. System level analyses were performed on working fluids, cycle design parameters, heater and cooling temperatures, and heat exchanger options that best meet the needs of the power converter specification. The goal is to provide a cost effective system that has high thermal-to-electric efficiency in a compact, lightweight package.

  8. Surface ionization ion source with high current

    International Nuclear Information System (INIS)

    Fang Jinqing; Lin Zhizhou; Yu Lihua; Zhan Rongan; Huang Guojun; Wu Jianhua

    1986-04-01

    The working principle and structure of a surface ionization ion source with high current is described systematically. Some technological keypoints of the ion source are given in more detail, mainly including: choosing and shaping of the material of the surface ionizer, heating of the ionizer, distributing of working vapour on the ionizer surface, the flow control, the cooling problem at the non-ionization surface and the ion optics, etc. This ion source has been used since 1972 in the electromagnetic isotope separator with 180 deg angle. It is suitable for separating isotopes of alkali metals and rare earth metals. For instance, in the case of separating Rubidium, the maximum ion current of Rbsup(+) extracted from the ion source is about 120 mA, the maximum ion current accepted by the receiver is about 66 mA, the average ion current is more than 25 mA. The results show that our ion source have advantages of high ion current, good characteristics of focusing ion beam, working stability and structure reliability etc. It may be extended to other fields. Finally, some interesting phenomena in the experiment are disccused briefly. Some problems which should be investigated are further pointed out

  9. Study of electrochemical phosphate conversion coating of metallic surfaces

    International Nuclear Information System (INIS)

    Gougelin, Patrick

    1985-01-01

    After an overview on phosphate conversion coating processes, on models of iron electrochemical dissolution, on the passivation phenomenon, and on the phosphate conversion coating treatment, this research thesis reports a detailed study of this last process. The author presents the experimental method, reports the study of this process and of passivation under constant polarization. He reports the use of various techniques and conditions: chrono-amperometry, chrono-potentiometry, cyclic volt-amperometry

  10. Advanced energy sources and conversion techniques. Proceedings of a seminar. Volume 1. [35 papers

    Energy Technology Data Exchange (ETDEWEB)

    None

    1958-11-01

    The Seminar was organized as a series of tutorial presentations and round table discussions on a technical level to implement the following: (a) to identify and explore present and projected needs for energy sources and conversion techniques for military applications; (b) to exchange information on current and planned efforts in these fields; (c) to examine the effect of anticipated scientific and technological advances on these efforts; and (d) to present suggested programs aimed at satisfying the military needs for energy sources and conversion techniques. Volume I contains all of the unclassified papers presented at the Seminar. (W.D.M.)

  11. Preparation of Trivalent Chromium and Rare Earth Composite Conversion Coating on Aluminum Alloy Surface

    Science.gov (United States)

    Huang, Jianzhen

    2018-01-01

    In this paper, the surface conversion film on 6063 aluminum alloy was prepared by chemical plating process with chromium sulfate, lanthanum sulfate and sodium phosphate as film forming agent. The corrosion resistance and surface morphology of the conversion film were analyzed by pitting corrosion test of copper sulfate and SEM. The results show that when Cr2(SO4)3 is 10 g/L, La2(SO4)3 is 2 g/L, Na3PO4 is 8 g/L, pH value is 3, temperature is 40 °C, reaction time is 10 min, the corrosion resistance of the surface conversion film is the best. The conversion coating is light green, composed of Cr, La, P, Al, O and other elements.

  12. Surface tension mediated conversion of light to work

    Science.gov (United States)

    Okawa, David; Pastine, Stefan J; Zettl, Alexander K; Frechet, Jean M. J

    2014-12-02

    Disclosed are a method and apparatus for converting light energy to mechanical energy by modification of surface tension on a supporting fluid. The apparatus comprises an object which may be formed as a composite object comprising a support matrix and a highly light absorptive material. The support matrix may comprise a silicon polymer. The highly light absorptive material may comprise vertically aligned carbon nanotubes (VANTs) embedded in the support matrix. The composite object is supported on a fluid. By exposing the highly light absorptive material to light, heat is generated, which changes the surface tension of the composite object, causing it to move physically within the fluid.

  13. An in situ study of zirconium-based conversion treatment on zinc surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Taheri, P. [Materials innovation institute (M2i), Elektronicaweg 25, 2628 XG Delft (Netherlands); Delft University of Technology, Department of Materials Science and Engineering, Mekelweg 2, 2628 CD Delft (Netherlands); Laha, P. [Vrije Universiteit Brussel, Department of Electrochemical and Surface Engineering, Pleinlaan 2, B-1050 Brussels (Belgium); Terryn, H. [Delft University of Technology, Department of Materials Science and Engineering, Mekelweg 2, 2628 CD Delft (Netherlands); Vrije Universiteit Brussel, Department of Electrochemical and Surface Engineering, Pleinlaan 2, B-1050 Brussels (Belgium); Mol, J.M.C., E-mail: J.M.C.Mol@tudelft.nl [Delft University of Technology, Department of Materials Science and Engineering, Mekelweg 2, 2628 CD Delft (Netherlands)

    2015-11-30

    Highlights: • We investigated the deposition mechanism of zirconium conversion layer on zinc. • In situ FTIR and electrochemical measurements are conducted. • The initial hydroxyl fraction plays an important role in the deposition process. • Deposition starts with hydroxyl removal by fluoride ions. • An increase of alkalinity adjacent to the surface promotes deposition of Zr. - Abstract: This study is focused on the deposition process of zirconium-based conversion layers on Zn surfaces. The analysis approach is based on a Kretschmann configuration in which in situ ATR-FTIR spectroscopy is combined with open circuit potential (OCP) and near surface pH measurements. Differently pretreated Zn surfaces were subjected to conversion treatments, while the Zr-based deposition mechanism was probed in situ. It was found that the initial hydroxyl fraction promotes the overall Zr conversion process as the near surface pH values are influenced by the initial hydroxyl fraction. Kinetics of the early surface activation and the subsequent Zr-based conversion process are discussed and correlated to the initial hydroxyl fractions.

  14. Conceptual design of a FGM thermoelectric energy conversion system for high temperature heat source. 1. Design of thermoelectric energy conversion unit

    International Nuclear Information System (INIS)

    Kambe, Mitsuru; Teraki, Junichi; Hirano, Toru.

    1996-01-01

    Thermoelectric (TE) power conversion system has been focused as a candidate of direct energy conversion systems for high temperature heat source to meet the various power requirements in next century. A concept of energy conversion unit by using TE cell elements combined with FGM compliant pads has been presented to achieve high thermal energy density as well as high energy conversion efficiency. An energy conversion unit consists of 8 couples of P-N cell elements sandwiched between two FGM compliant pads. Performance analysis revealed that the power generated by this unit was 11 watts which is nearly ten times as much as conventional unit of the same size. Energy conversion efficiency of 12% was expected based on the assumption of ZT = 1. All the member of compliant pads as well as TE cells could be bonded together to avoid thermal resistance. (author)

  15. Analytical investigation of low temperature lift energy conversion systems with renewable energy source

    International Nuclear Information System (INIS)

    Lee, Hoseong; Hwang, Yunho; Radermacher, Reinhard

    2014-01-01

    The efficiency of the renewable energy powered energy conversion system is typically low due to its moderate heat source temperature. Therefore, improving its energy efficiency is essential. In this study, the performance of the energy conversion system with renewable energy source was theoretically investigated in order to explore its design aspect. For this purpose, a computer model of n-stage low temperature lift energy conversion (LTLEC) system was developed. The results showed that under given operating conditions such as temperatures and mass flow rates of heat source and heat sink fluids the unit power generation of the system increased with the number of stage, and it became saturated when the number of staging reached four. Investigation of several possible working fluids for the optimum stage LTLEC system revealed that ethanol could be an alternative to ammonia. The heat exchanger effectiveness is a critical factor on the system performance. The power generation was increased by 7.83% for the evaporator and 9.94% for the condenser with 10% increase of heat exchanger effectiveness. When these low temperature source fluids are applied to the LTLEC system, the heat exchanger performance would be very critical and it has to be designed accordingly. - Highlights: •Energy conversion system with renewable energy is analytically investigated. •A model of multi-stage low temperature lift energy conversion systems was developed. •The system performance increases as the stage number is increased. •The unit power generation is increased with increase of HX effectiveness. •Ethanol is found to be a good alternative to ammonia

  16. Multi-copy entanglement purification with practical spontaneous parametric down conversion sources

    International Nuclear Information System (INIS)

    Zhang Shuai-Shuai; Shu Qi; Sheng Yu-Bo; Zhou Lan

    2017-01-01

    Entanglement purification is to distill the high quality entanglement from the low quality entanglement with local operations and classical communications. It is one of the key technologies in long-distance quantum communication. We discuss an entanglement purification protocol (EPP) with spontaneous parametric down conversion (SPDC) sources, in contrast to previous EPP with multi-copy mixed states, which requires ideal entanglement sources. We show that the SPDC source is not an obstacle for purification, but can benefit the fidelity of the purified mixed state. This EPP works for linear optics and is feasible in current experiment technology. (paper)

  17. Preparation of {sup 114m}In low energy conversion electron sources

    Energy Technology Data Exchange (ETDEWEB)

    Wrede, C., E-mail: wrede@uw.ed [Center for Experimental Nuclear Physics and Astrophysics, and Department of Physics, University of Washington, Seattle, WA 98195 (United States); Filippone, B.W. [Kellogg Radiation Laboratory, California Institute of Technology, Pasadena, California 91125 (United States); Garcia, A.; Harper, G.C. [Center for Experimental Nuclear Physics and Astrophysics, and Department of Physics, University of Washington, Seattle, WA 98195 (United States); Lassell, S. [Department of Nuclear Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Liu, J. [Kellogg Radiation Laboratory, California Institute of Technology, Pasadena, California 91125 (United States); Department of Physics, Shanghai Jiao Tong University, Shanghai 200240 (China); Mendenhall, M.P. [Kellogg Radiation Laboratory, California Institute of Technology, Pasadena, California 91125 (United States); Palmer, A.S.C. [Center for Experimental Nuclear Physics and Astrophysics, and Department of Physics, University of Washington, Seattle, WA 98195 (United States); Pattie, R.W. [Department of Physics, North Carolina State University, Raleigh, North Carolina 27695 (United States); Will, D.I. [Center for Experimental Nuclear Physics and Astrophysics, and Department of Physics, University of Washington, Seattle, WA 98195 (United States); Young, A.R. [Department of Physics, North Carolina State University, Raleigh, North Carolina 27695 (United States)

    2011-05-15

    Highlights: {yields} Controlled ion implantation of In-113 into thin Al substrate. {yields} Production of In-114m (half life = 50 days) by neutron irradiation. {yields} Use of In-114m as a source of electron lines and continuum for calibrations. {yields} Source reactivation by short neutron irradiation. -- Abstract: The preparation of {sup 114m}In sources of conversion electrons in the energy range 162-190 keV and {beta} continuum with a 1989 keV endpoint via ion implantation of {sup 113}In into Al substrates and subsequent irradiation by thermal and epi-thermal neutrons in a nuclear reactor is described.

  18. Preparation of 114mIn low energy conversion electron sources

    International Nuclear Information System (INIS)

    Wrede, C.; Filippone, B.W.; Garcia, A.; Harper, G.C.; Lassell, S.; Liu, J.; Mendenhall, M.P.; Palmer, A.S.C.; Pattie, R.W.; Will, D.I.; Young, A.R.

    2011-01-01

    Highlights: → Controlled ion implantation of In-113 into thin Al substrate. → Production of In-114m (half life = 50 days) by neutron irradiation. → Use of In-114m as a source of electron lines and continuum for calibrations. → Source reactivation by short neutron irradiation. -- Abstract: The preparation of 114m In sources of conversion electrons in the energy range 162-190 keV and β continuum with a 1989 keV endpoint via ion implantation of 113 In into Al substrates and subsequent irradiation by thermal and epi-thermal neutrons in a nuclear reactor is described.

  19. Modular High Temperature Gas-Cooled Reactor heat source for coal conversion

    International Nuclear Information System (INIS)

    Schleicher, R.W. Jr.; Lewis, A.C.

    1992-09-01

    In the industrial nations, transportable fuels in the form of natural gas and petroleum derivatives constitute a primary energy source nearly equivalent to that consumed for generating electric power. Nations with large coal deposits have the option of coal conversion to meet their transportable fuel demands. But these processes themselves consume huge amounts of energy and produce undesirable combustion by-products. Therefore, this represents a major opportunity to apply nuclear energy for both the environmental and energy conservation reasons. Because the most desirable coal conversion processes take place at 800 degree C or higher, only the High Temperature Gas-Cooled Reactors (HTGRs) have the potential to be adapted to coal conversion processes. This report provides a discussion of this utilization of HTGR reactors

  20. Mode conversion and its utilization of degenerating surface wave modes on a plasma column

    International Nuclear Information System (INIS)

    Nonaka, S.; Akao, Y.

    1983-01-01

    Both mode conversion at degenerating points of dispersion relations for surface wave modes on a discharge plasma column and the methods for their detection and utilization are presented. Mode conversions at three degenerating points become observable by using a surface wave resonator when an azimuthal inhomogeneity of plasma is produced by a static magnetic field of about 1 G applied perpendicular to the column axis. Two of the three detected degenerating points can be utilized for an easy and exact determination of the electron density and its distribution in the discharge tube

  1. Conversion of tritiated hydrogen to tritiated water on heated metal surfaces

    International Nuclear Information System (INIS)

    Dickson, R.S.

    1993-05-01

    The conversion of tritium to tritiated water on metal surfaces was studied under conditions relevant to releases into a fusion reactor hall (metal temperatures between 473 K and 623 K, air or inert gas atmospheres). The rate constant of oxidation per unit geometric surface area was found to be about a factor of ten higher than the rate constant per unit gas adsorption surface area for H 2 to H 2 O conversion on metal oxides in excess oxygen, probably because of the roughness of the metal surfaces on a gas adsorption scale. Surface roughness and oxides were found to have a major influence on the reaction rate. The reaction exhibited a first-order dependence on Q 2 concentration. Changing the dew point of the atmosphere did not affect the rate significantly, and rate constants for most metals were independent of whether the atmosphere was argon or air. Coatings of hydrocarbon and silicone polymers did not significantly affect the reaction rate on carbon steel and ferrous metals and brass all had about the same conversion rate constant. Aluminum alloy gave about three times lower and copper in Ar gave ten times higher conversion rate constants. Based on these data, an accident scenario involving exposure of 1000 m 2 of stainless steel at 573 K to a 10 4 m 3 room would cause conversion of ca. 0.1% of the Q 2 present to Q 2 O in 24 hours, while air ingress to the torus without leakage of the tritium into the room would cause 1.2% conversion in that time. The rate values are only accurate within a multiplicative factor of three, so they should be applied cautiously in model calculations. (author). 27 refs., 4 tabs., 4 figs

  2. Improving tribological and anti-bacterial properties of titanium external fixation pins through surface ceramic conversion.

    Science.gov (United States)

    Dong, Huan; Mukinay, Tatiana; Li, Maojun; Hood, Richard; Soo, Sein Leung; Cockshott, Simon; Sammons, Rachel; Li, Xiaoying

    2017-01-01

    In this study, an advanced ceramic conversion surface engineering technology has been applied for the first time to self-drilling Ti6Al4V external fixation pins to improve their performance in terms of biomechanical, bio-tribological and antibacterial properties. Systematic characterisation of the ceramic conversion treated Ti pins was carried out using Scanning electron microscope, X-ray diffraction, Glow-discharge optical emission spectroscopy, nano- and micro-indentation and scratching; the biomechanical and bio-tribological properties of the surface engineered Ti pins were evaluated by insertion into high density bone simulation material; and the antibacterial behaviour was assessed with Staphylococcus aureus NCTC 6571. The experimental results have demonstrated that the surfaces of Ti6Al4V external fixation pins were successfully converted into a TiO 2 rutile layer (~2 μm in thickness) supported by an oxygen hardened case (~15 μm in thickness) with very good bonding due to the in-situ conversion nature. The maximum insertion force and temperature were reduced from 192N and 31.2 °C when using the untreated pins to 182N and 26.1 °C when the ceramic conversion treated pins were tested. This is mainly due to the significantly increased hardness (more than three times) and the effectively enhanced wear resistance of the cutting edge of the self-drilling Ti pins following the ceramic conversion treatment. The antibacterial tests also revealed that there was a significantly reduced number of bacteria isolated from the ceramic conversion treated pins compared to the untreated pins of around 50 % after 20 h incubation, P < 0.01 (0.0024). The results reported are encouraging and could pave the way towards high-performance anti-bacterial titanium external fixation pins with reduced pin-track infection and pin loosing.

  3. Multi-copy entanglement purification with practical spontaneous parametric down conversion sources

    Science.gov (United States)

    Zhang, Shuai-Shuai; Shu, Qi; Zhou, Lan; Sheng, Yu-Bo

    2017-06-01

    Entanglement purification is to distill the high quality entanglement from the low quality entanglement with local operations and classical communications. It is one of the key technologies in long-distance quantum communication. We discuss an entanglement purification protocol (EPP) with spontaneous parametric down conversion (SPDC) sources, in contrast to previous EPP with multi-copy mixed states, which requires ideal entanglement sources. We show that the SPDC source is not an obstacle for purification, but can benefit the fidelity of the purified mixed state. This EPP works for linear optics and is feasible in current experiment technology. Project supported by the National Natural Science Foundation of China (Grant Nos. 11474168 and 61401222), the Natural Science Foundation of Jiangsu Province, China (Grant No. BK20151502), the Qing Lan Project in Jiangsu Province, China, and a Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions, China.

  4. Source Term Model for Fine Particle Resuspension from Indoor Surfaces

    National Research Council Canada - National Science Library

    Kim, Yoojeong; Gidwani, Ashok; Sippola, Mark; Sohn, Chang W

    2008-01-01

    This Phase I effort developed a source term model for particle resuspension from indoor surfaces to be used as a source term boundary condition for CFD simulation of particle transport and dispersion in a building...

  5. Degree of conversion and surface hardness of resin cement cured with different curing units.

    Science.gov (United States)

    Ozturk, Nilgun; Usumez, Aslihan; Usumez, Serdar; Ozturk, Bora

    2005-01-01

    The aim of this study was to evaluate the degree of conversion and Vickers surface hardness of resin cement under a simulated ceramic restoration with 3 different curing units: a conventional halogen unit, a high-intensity halogen unit, and a light-emitting diode system. A conventional halogen curing unit (Hilux 550) (40 s), a high-intensity halogen curing unit used in conventional and ramp mode (Optilux 501) (10 s and 20 s, respectively), and a light-emitting diode system (Elipar FreeLight) (20 s, 40 s) were used in this study. The dual-curing resin cement (Variolink II) was cured under a simulated ceramic restoration (diameter 5 mm, height 2 mm), and the degree of conversion and Vickers surface hardness were measured. For degree of conversion measurement, 10 specimens were prepared for each group. The absorbance peaks were recorded using the diffuse-reflection mode of Fourier transformation infrared spectroscopy. For Vickers surface hardness measurement, 10 specimens were prepared for each group. A load of 200 N was applied for 15 seconds, and 3 evaluations of each of the samples were performed. Degree of conversion achieved with Optilux 501 (20 s) was significantly higher than those of Hilux, Optilux 501 (10 s), Elipar FreeLight (20 s), and Elipar FreeLight (40 s). For Vickers surface hardness measurement, Optilux 501 (20 s) produced the highest surface hardness value. No significant differences were found among the Hilux, Optilux 501 (10 s), Elipar FreeLight (20 s), and Elipar FreeLight (40 s). The high-intensity halogen curing unit used in ramp mode (20 s) produced harder resin cement surfaces than did the conventional halogen curing unit, high-intensity halogen curing unit used in conventional mode (10 s) and light-emitting diode system (20 s, 40 s), when cured through a simulated ceramic restoration.

  6. Potassium Rankine cycle power conversion systems for lunar-Mars surface power

    International Nuclear Information System (INIS)

    Holcomb, R.S.

    1992-01-01

    The potassium Rankine cycle has good potential for application to nuclear power systems for surface power on the moon and Mars. A substantial effort on the development of the power conversion system was carried out in the 1960's which demonstrated successful operation of components made of stainless steel at moderate temperatures. This technology could be applied in the near term to produce a 360 kW(e) power system by coupling a stainless steel power conversion system to the SP-100 reactor. Improved performance could be realized in later systems by utilizing niobium or tantalum refractory metal alloys in the reactor and power conversion system. The design characteristics and estimated mass of power systems for each of three technology levels are presented in the paper

  7. Efficiency and stability of a phosphor-conversion white light source using a blue laser diode

    Directory of Open Access Journals (Sweden)

    G. Ledru

    2014-10-01

    Full Text Available A white light source using direct phosphor-conversion excited by a blue laser diode is presented. In this preliminary study we have investigated the influence of phosphor’s thickness and operating current of the laser diode over the (x, y chromaticity coordinates, Correlated Color Temperature (CCT and Color Rendering Index (CRI. The best values found were 4000 K and 94. A 40 lm/W luminous efficacy was achieved together with a CRI close to 90 for an operating current of 0.8 A. Those values, to the best of our knowledge, were not previously reported in the literature.

  8. A trial fabrication of activity standard surface sources and positional standard surface sources for an imaging plate system

    International Nuclear Information System (INIS)

    Sato, Yasushi; Hino, Yoshio; Yamada, Takahiro; Matsumoto, Mikio

    2003-01-01

    An imaging plate system can detect low level activity, but quantitative analysis is difficult because there are no adequate standard surface sources. A new fabrication method was developed for standard surface sources by printing on a sheet of paper using an ink-jet printer with inks in which a radioactive material was mixed. The fabricated standard surface sources had high uniformity, high positional resolution arbitrary shapes and a broad intensity range. The standard sources were used for measurement of surface activity as an application. (H. Yokoo)

  9. Electron dose-rate conversion factors for external exposure of the skin from uniformly deposited activity on the body surface

    International Nuclear Information System (INIS)

    Kocher, D.C.; Eckerman, K.F.

    1987-01-01

    Dose-rate conversion factors have been calculated for external exposure of the skin from electrons emitted by sources that are deposited uniformly on the body surface. The dose-rate factors are obtained from electron scaled point kernels developed by Berger. The dose-rate factors are calculated at depths of 4, 8, and 40 mg cm-2 below the body surface as recommended by Whitton, and at a depth of 7 mg cm-2 as recommended in ICRP Publication 26 (ICRP77). The dependence of the dose-rate factors at selected depths on the energy of the emitted electrons is displayed. The dose-rate factors for selected radionuclides of potential importance in radiological assessments are tabulated

  10. An assessment of dynamic energy conversion systems for terrestrial radioisotope heat sources

    International Nuclear Information System (INIS)

    Thayer, G.R.

    1985-01-01

    The use of dynamic conversion systems to convert to electricity the heat generated in a 7500 W(t) 90 Sr radioisotopic heat source is examined. Brayton Cycle, three Organic Rankine systems (Barber-Nichols/ORMAT, Sundstrand, and TRW concepts), Organic Rankine plus thermoelectrics, and Stirling Engine systems were studied. The systems were ranked for a North Warning System mission using a Los Alamos Multi-Attribute Decision Theory code. Three different heat source designs were used: Case I with a beginning of life (BOL) source temperature of 640 0 C, Case II with a BOL source temperature of 745 0 C, and Case III with a BOL source temperature of 945 0 C. The Stirling Engine system was the top-ranked system for Cases I and II, closely followed by the ORC systems in Case I and ORC and thermoelectrics in Case II. The Brayton-Cycle system was top-ranked for Case III, with the Stirling Engine system a close second

  11. Advancing the Frontiers in Nanocatalysis, Biointerfaces, and Renewable Energy Conversion by Innovations of Surface Techniques

    Energy Technology Data Exchange (ETDEWEB)

    Somorjai, G.A.; Frei, H.; Park, J.Y.

    2009-07-23

    The challenge of chemistry in the 21st century is to achieve 100% selectivity of the desired product molecule in multipath reactions ('green chemistry') and develop renewable energy based processes. Surface chemistry and catalysis play key roles in this enterprise. Development of in situ surface techniques such as high-pressure scanning tunneling microscopy, sum frequency generation (SFG) vibrational spectroscopy, time-resolved Fourier transform infrared methods, and ambient pressure X-ray photoelectron spectroscopy enabled the rapid advancement of three fields: nanocatalysts, biointerfaces, and renewable energy conversion chemistry. In materials nanoscience, synthetic methods have been developed to produce monodisperse metal and oxide nanoparticles (NPs) in the 0.8-10 nm range with controlled shape, oxidation states, and composition; these NPs can be used as selective catalysts since chemical selectivity appears to be dependent on all of these experimental parameters. New spectroscopic and microscopic techniques have been developed that operate under reaction conditions and reveal the dynamic change of molecular structure of catalysts and adsorbed molecules as the reactions proceed with changes in reaction intermediates, catalyst composition, and oxidation states. SFG vibrational spectroscopy detects amino acids, peptides, and proteins adsorbed at hydrophobic and hydrophilic interfaces and monitors the change of surface structure and interactions with coadsorbed water. Exothermic reactions and photons generate hot electrons in metal NPs that may be utilized in chemical energy conversion. The photosplitting of water and carbon dioxide, an important research direction in renewable energy conversion, is discussed.

  12. Plasma-surface interaction in negative hydrogen ion sources

    Science.gov (United States)

    Wada, Motoi

    2018-05-01

    A negative hydrogen ion source delivers more beam current when Cs is introduced to the discharge, but a continuous operation of the source reduces the beam current until more Cs is added to the source. This behavior can be explained by adsorption and ion induced desorption of Cs atoms on the plasma grid surface of the ion source. The interaction between the ion source plasma and the plasma grid surface of a negative hydrogen ion source is discussed in correlation to the Cs consumption of the ion source. The results show that operation with deuterium instead of hydrogen should require more Cs consumption and the presence of medium mass impurities as well as ions of the source wall materials in the arc discharge enlarges the Cs removal rate during an ion source discharge.

  13. Preparation of XH-3001 floodgate type of calibration surface sources

    International Nuclear Information System (INIS)

    Lin Hui; Zhang Fenglan

    2005-10-01

    The preparation of a large sized (active area: 100 mm x 150 mm) calibration sources by oxide film filling of aluminum is introduced. The influence of current densities, oxidation time, filling time, the pH, the concentration and the consumption of filling solution on surface emission rate of the source is studied. The surface emission rate, adhensiveness and uniformity of the source are also tested. The testing results indicate that the surface emission rate of source is 1500-3500 (2π·s) -1 , the uniformity of the source is better than ±10%, the activity of the source removed with wipe test is less than 200 Bq. The large sized source have been used for calibrating the apparatus in Qinshan Nuclear Power Station. (authors)

  14. Volume and Surface-Enhanced Volume Negative Ion Sources

    International Nuclear Information System (INIS)

    Stockli, M P

    2013-01-01

    H - volume sources and, especially, caesiated H - volume sources are important ion sources for generating high-intensity proton beams, which then in turn generate large quantities of other particles. This chapter discusses the physics and technology of the volume production and the caesium-enhanced (surface) production of H - ions. Starting with Bacal's discovery of the H - volume production, the chapter briefly recounts the development of some H - sources, which capitalized on this process to significantly increase the production of H - beams. Another significant increase was achieved in the 1990s by adding caesiated surfaces to supplement the volume-produced ions with surface-produced ions, as illustrated with other H - sources. Finally, the focus turns to some of the experience gained when such a source was successfully ramped up in H - output and in duty factor to support the generation of 1 MW proton beams for the Spallation Neutron Source. (author)

  15. Conversion of HSPF Legacy Model to a Platform-Independent, Open-Source Language

    Science.gov (United States)

    Heaphy, R. T.; Burke, M. P.; Love, J. T.

    2015-12-01

    Since its initial development over 30 years ago, the Hydrologic Simulation Program - FORTAN (HSPF) model has been used worldwide to support water quality planning and management. In the United States, HSPF receives widespread endorsement as a regulatory tool at all levels of government and is a core component of the EPA's Better Assessment Science Integrating Point and Nonpoint Sources (BASINS) system, which was developed to support nationwide Total Maximum Daily Load (TMDL) analysis. However, the model's legacy code and data management systems have limitations in their ability to integrate with modern software, hardware, and leverage parallel computing, which have left voids in optimization, pre-, and post-processing tools. Advances in technology and our scientific understanding of environmental processes that have occurred over the last 30 years mandate that upgrades be made to HSPF to allow it to evolve and continue to be a premiere tool for water resource planners. This work aims to mitigate the challenges currently facing HSPF through two primary tasks: (1) convert code to a modern widely accepted, open-source, high-performance computing (hpc) code; and (2) convert model input and output files to modern widely accepted, open-source, data model, library, and binary file format. Python was chosen as the new language for the code conversion. It is an interpreted, object-oriented, hpc code with dynamic semantics that has become one of the most popular open-source languages. While python code execution can be slow compared to compiled, statically typed programming languages, such as C and FORTRAN, the integration of Numba (a just-in-time specializing compiler) has allowed this challenge to be overcome. For the legacy model data management conversion, HDF5 was chosen to store the model input and output. The code conversion for HSPF's hydrologic and hydraulic modules has been completed. The converted code has been tested against HSPF's suite of "test" runs and shown

  16. Type conversion, contacts, and surface effects in electroplated CdTe films

    International Nuclear Information System (INIS)

    Basol, B.M.; Ou, S.S.; Stafsudd, O.M.

    1985-01-01

    Efficient electroplated CdS/CdTe solar cells can be fabricated by heat treating and type-converting the n-CdTe films deposited on CdS layers. In this paper, various mechanisms which may give rise to the conversion of electroplated CdTe films from n to p type are investigated. It is concluded that Cd-vacancy generation is the main mechanism of type conversion. Possible effects of oxygen on this mechanism are also discussed. Evaporated Au contacts to electroplated p-CdTe films were studied. It was found that the Au contacts depleted the excess Te present on the surface of Br 2 -methanol etched p-CdTe films. Oxygen was found to affect the electrical characteristics of such contacts

  17. Large area, surface discharge pumped, vacuum ultraviolet light source

    Science.gov (United States)

    Sze, R.C.; Quigley, G.P.

    1996-12-17

    Large area, surface discharge pumped, vacuum ultraviolet (VUV) light source is disclosed. A contamination-free VUV light source having a 225 cm{sup 2} emission area in the 240-340 nm region of the electromagnetic spectrum with an average output power in this band of about 2 J/cm{sup 2} at a wall-plug efficiency of approximately 5% is described. Only ceramics and metal parts are employed in this surface discharge source. Because of the contamination-free, high photon energy and flux, and short pulse characteristics of the source, it is suitable for semiconductor and flat panel display material processing. 3 figs.

  18. Radiation resistant PIDECα cell using photon intermediate direct energy conversion and a 210Po source.

    Science.gov (United States)

    Weaver, Charles L; Schott, Robert J; Prelas, Mark A; Wisniewski, Denis A; Rothenberger, Jason B; Lukosi, Eric D; Oh, Kyuhak

    2018-02-01

    Radiation damage is a significant concern with both alphavoltaic and betavoltaic cells because their performance degrades, especially with high-energy - (>200keV) beta and alpha particles. Indirect excitation methods, such as the Photon Intermediate Direct Energy Conversion (PIDEC) framework, can protect the transducer from radiation. A nuclear battery using a 90 Sr beta source was constructed by the author's research group, which demonstrated the radiation resistance of a PIDEC cell driven by beta particles (PIDECβ cell). Use of alpha sources to drive nuclear batteries would appear to be much more attractive than beta sources due to higher potential power density. However, they are also subject to higher rates of radiation damage. This paper describes the successful incorporation of alpha particles into the PIDEC framework using the alpha emitter 210 Po to form a PIDECα cell. The PIDECα cell transducer was exposed to alpha particles for over one year without experiencing adverse effects from radiation damage. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. Consideration of ultra-high temperature nuclear heat sources for MHD conversion systems

    International Nuclear Information System (INIS)

    Holman, R.R.; Tobin, J.M.; Young, W.E.

    1975-01-01

    The nuclear technology reactors developed and tested in the Nuclear Engine Rocket Vehicle Application (NERVA) program operated with fuel exit gas temperatures in excess of 2600 K. This experience provided a significant ultra-high temperature technology base and design insight for commercial power applications. Design approaches to accommodate fission product retention and other key prevailing requirements are examined in view of the basic overriding functional requirements, and some interesting reconsiderations are suggested. Predicted overall system performance potentials for a 2000 K MHD conversion system and reactor parameter requirements are compared and related to existing technology status. Needed verification and development efforts are suggested. A reconsideration of basic design approaches is suggested that could open the door for immediate development of ultrahigh temperature nuclear heat sources for advanced energy systems

  20. Surface type conversion of CuInSe2 with H2S plasma exposure: A photoemission investigation

    International Nuclear Information System (INIS)

    Nelson, A.J.; Frigo, S.P.; Rosenberg, R.

    1995-01-01

    Surface type conversion of CuInSe 2 by H 2 S plasma exposure was studied by synchrotron radiation soft x-ray photoemission spectroscopy. The low power H 2 S plasma was generated with a commercial electron cyclotron resonance plasma source using pure H 2 S with the plasma exposure being performed at 400 degree C. In situ photoemission measurements were acquired after each plasma exposure in order to observe changes in the valence band electronic structure as well as changes in the In 4d and Se 3d core lines. The results were correlated in order to relate changes in surface chemistry to the electronic structure. These measurements indicate that the H 2 S plasma exposure type converts the n-type CuInSe 2 surface to a p-type surface at this elevated temperature and that the magnitude of the band bending is 0.5 eV, resulting in a homojunction interface. copyright 1995 American Vacuum Society

  1. Theory of ortho-para conversion in hydrogen adsorbed on metal and paramagnetic surfaces at low temperatures

    International Nuclear Information System (INIS)

    Yucel, S.

    1989-01-01

    In order to explain the experimental results on Cu(100), Ag(111), Ag thin films, graphite, and H 2 bubbles in Cu, the ortho-para conversion rates of H 2 and D 2 adsorbed on metal and paramagnetic surfaces at low temperatures have been considered. The conversion rates due to magnetic dipole-dipole, Fermi contact, and spin-orbit interaction between the conduction electrons, and nuclear spins of H 2 (D 2 ) are calculated to elucidate the role of the metal surface. Although the rates on clean metal surfaces are found to be too slow to account for the observed rates on Ag, they may explain the catalytic conversion on H 2 bubble surfaces at 1.3 K. Additionally, effects of impurities and defects on the surface are investigated by calculating the conversion rate in two-dimensional solid D 2 (H 2 ) by emission of one (two) phonon(s). Fast conversion rates observed on Ag and graphite surfaces as well as on the surfaces of H 2 bubbles may be accounted for by paramagnetic impurities or defects. On Grafoil, both in (√3 x √3)R30 0 commensurate and incommensurate solid phase, a temperature-independent conversion rate is predicted if the mobility of the molecules is high enough to prevent concentration gradients

  2. Mode Engineering of Single Photons from Cavity Spontaneous Parametric Down-Conversion Source and Quantum Dots

    Science.gov (United States)

    Paudel, Uttam

    Over the past decade, much effort has been made in identifying and characterizing systems that can form a building block of quantum networks, among which semiconductor quantum dots (QD) and spontaneous parametric down-conversion (SPDC) source are two of the most promising candidates. The work presented in this thesis will be centered on investigating and engineering the mentioned systems for generating customizable single photons. A type-II SPDC source can generate a highly flexible pair of entangled photons that can be used to interface disparate quantum systems. In this thesis, we have successfully implemented a cavity-SPDC source that emits polarization correlated photons at 942 nm with a lifetime of 950-1050ps that mode matches closely with InAs/GaAs QD photons. The source emits 80 photon pairs per second per mW pump power within the 150MHz bandwidth. Though the detection of idler photons, the source is capable of emitting heralded photons with g2?0.5 for up to 40 mW pump power. For a low pump power of 5 mW, the heralded g2 is 0.06, indicating that the system is an excellent heralded single photon source. By directly exciting a single QD with cavity-SPDC photons, we have demonstrated a heralded-absorption of SPDC photons by QD, resulting in the coupling of the two systems. Due to the large pump bandwidth, the emitted source is highly multimode in nature, requiring us to post-filter the downconverted field, resulting in a lower photon pair emission rate. We propose placing an intra-cavity etalon to suppress the multi-mode emissions and increase the photon count rate. Understanding and experimentally implementing two-photon interference (HOM) measurements will be crucial for building a scalable quantum network. A detailed theoretical description of HOM measurements is given and is experimentally demonstrated using photons emitted by QD. Through HOM measurements we demonstrated that the QD sample in the study is capable of emitting indistinguishable photons, with

  3. Source signature estimation from multimode surface waves via mode-separated virtual real source method

    Science.gov (United States)

    Gao, Lingli; Pan, Yudi

    2018-05-01

    The correct estimation of the seismic source signature is crucial to exploration geophysics. Based on seismic interferometry, the virtual real source (VRS) method provides a model-independent way for source signature estimation. However, when encountering multimode surface waves, which are commonly seen in the shallow seismic survey, strong spurious events appear in seismic interferometric results. These spurious events introduce errors in the virtual-source recordings and reduce the accuracy of the source signature estimated by the VRS method. In order to estimate a correct source signature from multimode surface waves, we propose a mode-separated VRS method. In this method, multimode surface waves are mode separated before seismic interferometry. Virtual-source recordings are then obtained by applying seismic interferometry to each mode individually. Therefore, artefacts caused by cross-mode correlation are excluded in the virtual-source recordings and the estimated source signatures. A synthetic example showed that a correct source signature can be estimated with the proposed method, while strong spurious oscillation occurs in the estimated source signature if we do not apply mode separation first. We also applied the proposed method to a field example, which verified its validity and effectiveness in estimating seismic source signature from shallow seismic shot gathers containing multimode surface waves.

  4. Determination of conversion factors and efficiency for GM detectors used in measurements of surface pollution

    International Nuclear Information System (INIS)

    Ayala G, J.; Alvarez R, J.T.

    1999-01-01

    One of the objectives of the Radiation protection, is to observe with the National and as International standardization referring to the ICRP dose limitation system (ICRP 26, ICRP 60). In this work it was treated the problem corresponding about how to determine the conversion factor of cpm/mR/h and the absolute efficiency ε, for a Geiger-Muller equipment with thin window. This equipment is used for the beta particle detection. Thus the correct use of calibration factors and the procedures to convert cpm in Bq is expedited and also to apply the ISO procedure for to evaluate contaminated surfaces. (Author)

  5. Heavy Metals Pollution on Surface Water Sources in Kaduna ...

    African Journals Online (AJOL)

    This study examine the effects of heavy metal pollutants to aquatic ecosystems and the environment by considering the role of urban, municipal, agricultural, industrial and other anthropogenic processes as sources of heavy metal pollution in surface water sources of Kaduna metropolis. Samples of the polluted water were ...

  6. A multi-agent conversational system with heterogeneous data sources access

    KAUST Repository

    Eisman, Eduardo M.

    2016-01-28

    In many of the problems that can be found nowadays, information is scattered across different heterogeneous data sources. Most of the natural language interfaces just focus on a very specific part of the problem (e.g. an interface to a relational database, or an interface to an ontology). However, from the point of view of users, it does not matter where the information is stored, they just want to get the knowledge in an integrated, transparent, efficient, effective, and pleasant way. To solve this problem, this article proposes a generic multi-agent conversational architecture that follows the divide and conquer philosophy and considers two different types of agents. Expert agents are specialized in accessing different knowledge sources, and decision agents coordinate them to provide a coherent final answer to the user. This architecture has been used to design and implement SmartSeller, a specific system which includes a Virtual Assistant to answer general questions and a Bookseller to query a book database. A deep analysis regarding other relevant systems has demonstrated that our proposal provides several improvements at some key features presented along the paper.

  7. A multi-agent conversational system with heterogeneous data sources access

    KAUST Repository

    Eisman, Eduardo M.; Navarro, Marí a; Castro, Juan Luis

    2016-01-01

    In many of the problems that can be found nowadays, information is scattered across different heterogeneous data sources. Most of the natural language interfaces just focus on a very specific part of the problem (e.g. an interface to a relational database, or an interface to an ontology). However, from the point of view of users, it does not matter where the information is stored, they just want to get the knowledge in an integrated, transparent, efficient, effective, and pleasant way. To solve this problem, this article proposes a generic multi-agent conversational architecture that follows the divide and conquer philosophy and considers two different types of agents. Expert agents are specialized in accessing different knowledge sources, and decision agents coordinate them to provide a coherent final answer to the user. This architecture has been used to design and implement SmartSeller, a specific system which includes a Virtual Assistant to answer general questions and a Bookseller to query a book database. A deep analysis regarding other relevant systems has demonstrated that our proposal provides several improvements at some key features presented along the paper.

  8. Calculated neutron air kerma strength conversion factors for a generically encapsulated Cf-252 brachytherapy source

    CERN Document Server

    Rivard, M J; D'Errico, F; Tsai, J S; Ulin, K; Engler, M J

    2002-01-01

    The sup 2 sup 5 sup 2 Cf neutron air kerma strength conversion factor (S sub K sub N /m sub C sub f) is a parameter needed to convert the radionuclide mass (mu g) provided by Oak Ridge National Laboratory into neutron air kerma strength required by modern clinical brachytherapy dosimetry formalisms indicated by Task Group No. 43 of the American Association of Physicists in Medicine (AAPM). The impact of currently used or proposed encapsulating materials for sup 2 sup 5 sup 2 Cf brachytherapy sources (Pt/Ir-10%, 316L stainless steel, nitinol, and Zircaloy-2) on S sub K sub N /m sub C sub f was calculated and results were fit to linear equations. Only for substantial encapsulation thicknesses, did S sub K sub N /m sub C sub f decrease, while the impact of source encapsulation composition is increasingly negligible as Z increases. These findings are explained on the basis of the non-relativistic kinematics governing the majority of sup 2 sup 5 sup 2 Cf neutron interactions. Neutron kerma and energy spectra resul...

  9. Material-specific Conversion Factors for Different Solid Phantoms Used in the Dosimetry of Different Brachytherapy Sources

    Directory of Open Access Journals (Sweden)

    Sedigheh Sina

    2015-07-01

    Full Text Available Introduction Based on Task Group No. 43 (TG-43U1 recommendations, water phantom is proposed as a reference phantom for the dosimetry of brachytherapy sources. The experimental determination of TG-43 parameters is usually performed in water-equivalent solid phantoms. The purpose of this study was to determine the conversion factors for equalizing solid phantoms to water. Materials and Methods TG-43 parameters of low- and high-energy brachytherapy sources (i.e., Pd-103, I-125 and Cs-137 were obtained in different phantoms, using Monte Carlo simulations. The brachytherapy sources were simulated at the center of different phantoms including water, solid water, poly(methyl methacrylate, polystyrene and polyethylene. Dosimetric parameters such as dose rate constant, radial dose function and anisotropy function of each source were compared in different phantoms. Then, conversion factors were obtained to make phantom parameters equivalent to those of water. Results Polynomial coefficients of conversion factors were obtained for all sources to quantitatively compare g(r values in different phantom materials and the radial dose function in water. Conclusion Polynomial coefficients of conversion factors were obtained for all sources to quantitatively compare g(r values in different phantom materials and the radial dose function in water.

  10. The influence of external source intensity in accelerator/target/blanket system on conversion ratio and fuel cycle

    Energy Technology Data Exchange (ETDEWEB)

    Kochurov, B.P. [Institute for Theoretical and Experimental Physics, Moscow (Russian Federation)

    1995-10-01

    The analysis of neutron balance relation for a subcritical system with external source shows that a high ratio of neutron utilization (conversion ratio, breeding ratio) much exceeding similar values for nuclear reactors (both thermal or fast spectrum) is reachable in accelerator/target/blanket system with high external neutron source intensity. An accelerator/target/blanket systems with thermal power in blanket about 1850 Mwt and operating during 30 years have been investigated. Continual feed up by plutonium (fissile material) and Tc-99 (transmuted material) was assumed. Accelerator beam intensity differed 6.3 times (16 mA - Case 1, and 100 mA-Case 2). Conversion ratio (CR) was defined as the ratio of Tc-99 nuclei transmuted to the number of Pu nuclei consumed. High value of conversion ratio considerably exceeding 1 (CR=1.66) was obtained in the system with high source intensity as compared with low source system (CR=0.77). Net output of electric power of high source intensity system is about twice lower due to consumption of electric power for accelerator feed up. The loss of energy for Tc-99 transmutation is estimated as 40 Mev(el)/nuclei. Yet high conversion ratio (or breeding ratio) achievable in electronuclear installations with high intensity of external source can effectively be used to close fuel cycle (including incineration of wastes) or to develop growing nuclear power production system.

  11. Study on road surface source pollution controlled by permeable pavement

    Science.gov (United States)

    Zheng, Chaocheng

    2018-06-01

    The increase of impermeable pavement in urban construction not only increases the runoff of the pavement, but also produces a large number of Non-Point Source Pollution. In the process of controlling road surface runoff by permeable pavement, a large number of particulate matter will be withheld when rainwater is being infiltrated, so as to control the source pollution at the source. In this experiment, we determined the effect of permeable road surface to remove heavy pollutants in the laboratory and discussed the related factors that affect the non-point pollution of permeable pavement, so as to provide a theoretical basis for the application of permeable pavement.

  12. Use of seismic pulses in surface sources of excitation

    Energy Technology Data Exchange (ETDEWEB)

    Szilagyi, L.

    1982-01-01

    A discussion is held of the experimental use of surface plus seismic sources. An examination is made of the technicalgeophysical criteria for using the pulse sources. Results are presented from measurements and tests obtained with the help of an air cushion and dinoseis. A comparison is made of the amplitude spectra of the seismic recordings obtained with the help of blasting, dinoseis and air cushion. Possibilities and limitations for using the surface sources in industrial exploration for oil and gas are discussed. Seismic profile is presented which intersects the Tisu River. It was obtained with the help of a dinoseis which notes a sharp change in the wave pattern.

  13. Calibrate the aerial surveying instrument by the limited surface source and the single point source that replace the unlimited surface source

    CERN Document Server

    Lu Cun Heng

    1999-01-01

    It is described that the calculating formula and surveying result is found on the basis of the stacking principle of gamma ray and the feature of hexagonal surface source when the limited surface source replaces the unlimited surface source to calibrate the aerial survey instrument on the ground, and that it is found in the light of the exchanged principle of the gamma ray when the single point source replaces the unlimited surface source to calibrate aerial surveying instrument in the air. Meanwhile through the theoretical analysis, the receiving rate of the crystal bottom and side surfaces is calculated when aerial surveying instrument receives gamma ray. The mathematical expression of the gamma ray decaying following height according to the Jinge function regularity is got. According to this regularity, the absorbing coefficient that air absorbs the gamma ray and the detective efficiency coefficient of the crystal is calculated based on the ground and air measuring value of the bottom surface receiving cou...

  14. A Black Phosphate Conversion Coating on Steel Surface Using Antimony(III)-Tartrate as an Additive

    Science.gov (United States)

    Li, Feng; Wang, Guiping

    2016-05-01

    A novel black phosphate conversion coating was formed on steel surface through a Zn-Mn phosphating bath containing mainly ZnO, H3PO4, Mn(H2PO4)2, and Ca(NO3)2, where antimony(III)-tartrate was used as the blackening agent of phosphatization. The surface morphology and composition of the coating were characterized by scanning electron microscopy, energy dispersion spectroscopy, and x-ray photoelectron spectroscopy. Corrosion resistance of the coating was studied by potentiodynamic polarization curves and electrochemical impedance spectroscopy. The pH value of the solution had significant influence on the formation and corrosion resistance of the coating. The experimental results indicated that the Sb plays a vital role in the blackening of phosphate conversion coating. The optimal concentration of antimony(III)-tartrate in the phosphating bath used in this experiment was 1.0 g L-1, as higher values reduced the corrosion resistance of the coating. In addition, by saponification and oil seals, the corrosion duration of the black phosphate coating in a copper sulfate spot test can be as long as 20 min.

  15. Surface structural evolvement in the conversion of polyacrylonitrile precursors to carbon fibers

    International Nuclear Information System (INIS)

    Qian, Xin; Zou, Ruifen; OuYang, Qin; Wang, Xuefei; Zhang, Yonggang

    2015-01-01

    Highlights: • The characteristic striated topography of PAN precursors resulted from the wet spinning process could pass down to carbon fibers. • The ridges and grooves monitored became much more well-defined after the thermo-oxidation. • Both the depth and the width of longitudinal grooves decreased after the carbonization. • Carbon, nitrogen, oxygen and silicon were the governing elements on the fiber surface. - Abstract: Surface structural evolvement in the conversion of polyacrylonitrile (PAN) precursors to carbon fibers was investigated through scanning electron microscopy (SEM), atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS). SEM results showed that the characteristic striated topography of PAN precursors resulted from the wet spinning process could pass down to carbon fibers. The fiber diameter gradually decreased from 11.3 μm to 5.5 μm and the corresponding density increased from 1.18 g/cm 3 to 1.80 g/cm 3 in the conversion of PAN precursors to carbon fibers. The ridges and grooves monitored by AFM became much more well-defined after the thermo-oxidation. However, the original longitudinal grooves were destroyed and both the depth and the width of longitudinal grooves decreased after the carbonization. XPS results revealed that carbon, nitrogen, oxygen and silicon were the governing elements on the fiber surface. The −C−C functional groups was the dominant groups and the relative contents of −C=O and −COO groups gradually increased in the process of thermo-oxidation and carbonization

  16. Radioactivity determination of sealed pure beta-sources by surface dose measurements and Monte Carlo simulations

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Chang Heon [Interdisciplinary Program in Radiation Applied Life Science, Seoul National University College of Medicine, Seoul (Korea, Republic of); Jung, Seongmoon [Program in Biomedical Radiation Sciences, Department of Transdisciplinary Studies, Graduate School of Convergence Science and Technology, Seoul National University, Seoul (Korea, Republic of); Choi, Kanghyuk; Son, Kwang-Jae; Lee, Jun Sig [Hanaro Applications Research, Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Ye, Sung-Joon, E-mail: sye@snu.ac.kr [Interdisciplinary Program in Radiation Applied Life Science, Seoul National University College of Medicine, Seoul (Korea, Republic of); Program in Biomedical Radiation Sciences, Department of Transdisciplinary Studies, Graduate School of Convergence Science and Technology, Seoul National University, Seoul (Korea, Republic of); Center for Convergence Research on Robotics, Advance Institutes of Convergence Technology, Seoul National University, Suwon (Korea, Republic of)

    2016-04-21

    This study aims to determine the activity of a sealed pure beta-source by measuring the surface dose rate using an extrapolation chamber. A conversion factor (cGy s{sup −1} Bq{sup −1}), which was defined as the ratio of surface dose rate to activity, can be calculated by Monte Carlo simulations of the extrapolation chamber measurement. To validate this hypothesis the certified activities of two standard pure beta-sources of Sr/Y-90 and Si/P-32 were compared with those determined by this method. In addition, a sealed test source of Sr/Y-90 was manufactured by the HANARO reactor group of KAERI (Korea Atomic Energy Research Institute) and used to further validate this method. The measured surface dose rates of the Sr/Y-90 and Si/P-32 standard sources were 4.615×10{sup −5} cGy s{sup −1} and 2.259×10{sup −5} cGy s{sup −1}, respectively. The calculated conversion factors of the two sources were 1.213×10{sup −8} cGy s{sup −1} Bq{sup −1} and 1.071×10{sup −8} cGy s{sup −1} Bq{sup −1}, respectively. Therefore, the activity of the standard Sr/Y-90 source was determined to be 3.995 kBq, which was 2.0% less than the certified value (4.077 kBq). For Si/P-32 the determined activity was 2.102 kBq, which was 6.6% larger than the certified activity (1.971 kBq). The activity of the Sr/Y-90 test source was determined to be 4.166 kBq, while the apparent activity reported by KAERI was 5.803 kBq. This large difference might be due to evaporation and diffusion of the source liquid during preparation and uncertainty in the amount of weighed aliquot of source liquid. The overall uncertainty involved in this method was determined to be 7.3%. We demonstrated that the activity of a sealed pure beta-source could be conveniently determined by complementary combination of measuring the surface dose rate and Monte Carlo simulations.

  17. Conversion of ICRP male reference phantom to polygon-surface phantom

    Science.gov (United States)

    Yeom, Yeon Soo; Han, Min Cheol; Kim, Chan Hyeong; Jeong, Jong Hwi

    2013-10-01

    The International Commission on Radiological Protection (ICRP) reference phantoms, developed based on computed tomography images of human bodies, provide much more realism of human anatomy than the previously used MIRD5 (Medical Internal Radiation Dose) mathematical phantoms. It has been, however, realized that the ICRP reference phantoms have some critical limitations showing a considerable amount of holes for the skin and wall organs mainly due to the nature of voxels of which the phantoms are made, especially due to their low voxel resolutions. To address this problem, we are planning to develop the polygon-surface version of ICRP reference phantoms by directly converting the ICRP reference phantoms (voxel phantoms) to polygon-surface phantoms. The objective of this preliminary study is to see if it is indeed possible to construct the high-quality polygon-surface phantoms based on the ICRP reference phantoms maintaining identical organ morphology and also to identify any potential issues, and technologies to address these issues, in advance. For this purpose, in the present study, the ICRP reference male phantom was roughly converted to a polygon-surface phantom. Then, the constructed phantom was implemented in Geant4, Monte Carlo particle transport code, for dose calculations, and the calculated dose values were compared with those of the original ICRP reference phantom to see how much the calculated dose values are sensitive to the accuracy of the conversion process. The results of the present study show that it is certainly possible to convert the ICRP reference phantoms to surface phantoms with enough accuracy. In spite of using relatively less resources (original ICRP reference phantoms, it is believed that the polygon-surface version of ICRP reference phantoms properly developed will not only provide the same or similar dose values (say, difference <5 or 10%) for highly penetrating radiations, but also provide correct dose values for the weakly penetrating

  18. The new fabrication method of standard surface sources

    Energy Technology Data Exchange (ETDEWEB)

    Sato, Yasushi E-mail: yss.sato@aist.go.jp; Hino, Yoshio; Yamada, Takahiro; Matsumoto, Mikio

    2004-04-01

    We developed a new fabrication method for standard surface sources by using an inkjet printer with inks in which a radioactive material is mixed to print on a sheet of paper. Three printed test patterns have been prepared: (1) 100 mmx100 mm uniformity-test patterns, (2) positional-resolution test patterns with different widths and intervals of straight lines, and (3) logarithmic intensity test patterns with different radioactive intensities. The results revealed that the fabricated standard surface sources had high uniformity, high positional resolution, arbitrary shapes and a broad intensity range.

  19. A positive (negative) surface ionization source concept for RIB generation

    International Nuclear Information System (INIS)

    Alton, G.D.; Mills, G.D.

    1995-01-01

    A novel, versatile, new concept, spherical-geometry, positive (negative) surface-ionization source has been designed and fabricated which will have the capability of generating both positive- and negative-ion beams without mechanical changes to the source. The source utilizes a highly permeable, high-work-function Ir ionizer (φ∼ = 5.29 eV) for ionizing highly electropositive atoms/molecules; while for negative-surface ionization, the work function is lowered to φ ∼ = 1.43 eV by continually feeding cesium vapor through the ionizer matrix. The use of Cs to effect low work function surfaces for negative ion beam generation has the potential of overcoming the chronic poisoning effects experienced with LaB 6 while enhancing the probability for negative ion formation of atomic and molecular species with low to intermediate electron affinities. The flexibility of operation in either mode makes it especially attractive for RIB applications and, therefore, the source will be used as a complementary replacement for the high-temperature electron impact ionization sources presently in use at the HRIBF The design features and operational principles of the source will be described in this report

  20. Observation of inner surface of flame-tower type reactor for uranium conversion

    International Nuclear Information System (INIS)

    Amamoto, Ippei; Terai, Takayuki; Umetsu, Hiroshi

    2003-01-01

    A fluorination reactor, which has been used to convert uranium tetrafluoride (UF 4 ) into uranium hexafluoride (UF 6 ), was completed after approximately 6000 hours operation at the uranium conversion facility in Japan. The observation of its inner surface was carried out to understand its corrosive condition and mechanism. The main wall of the reactor is made of Monel Alloy and its operational temperature is approximately 450degC at external surface under gaseous fluorine atmosphere. A sampling was undertaken from the most corrosive part of the reactor wall, and its analysis was carried out to obtain the data for the condition of appearance, thickness, macro and micro structure, etc. The results of observation are as follows: (1) The thickness decreased evenly (average 3.9 mm/year); (2) The chemical composition of corrosive products as coating was mainly nickel fluoride (NiF 2 ), which suggested that the corrosion mechanism could have been caused by the high temperature gas corrosion; (3) The total amount of coating was lower than that of a loss in thickness. For some reason, some of coating would seem to become extinct on the surface of the wall. The deterioration of coating, which formed a protector on the wall due to excess heating of the wall, the sand erosion effect by UF 4 , etc. have contributed to this state of condition. (author)

  1. Surface Coating of Plastic Parts for Business Machines (Industrial Surface Coating): New Source Performance Standards (NSPS)

    Science.gov (United States)

    Learn more about the new source performance standards (NSPS) for surface coating of plastic parts for business machines by reading the rule summary and history and finding the code of federal regulations as well as related rules.

  2. High-speed photonically assisted analog-to-digital conversion using a continuous wave multiwavelength source and phase modulation.

    Science.gov (United States)

    Bortnik, Bartosz J; Fetterman, Harold R

    2008-10-01

    A more simple photonically assisted analog-to-digital conversion system utilizing a cw multiwavelength source and phase modulation instead of a mode-locked laser is presented. The output of the cw multiwavelength source is launched into a dispersive device (such as a single-mode fiber). This fiber creates a pulse train, where the central wavelength of each pulse corresponds to a spectral line of the optical source. The pulses can then be either dispersed again to perform discrete wavelength time stretching or demultiplexed for continuous time analog-to-digital conversion. We experimentally demonstrate the operation of both time stretched and interleaved systems at 38 GHz. The potential of integrating this type of system on a monolithic chip is discussed.

  3. A silicon-based electrical source for surface plasmon polaritons

    NARCIS (Netherlands)

    Walters, Robert J.; van Loon, Rob V.A.; Brunets, I.; Schmitz, Jurriaan; Polman, Albert

    2009-01-01

    This work demonstrates the fabrication of a silicon-based electrical source for surface plasmon polaritons (SPPs) at low temperatures using silicon nanocrystal doped alumina within a metal-insulator-metal (MIM) waveguide geometry. The fabrication method uses established microtechnology processes

  4. The influence of lithology on surface water sources | Science ...

    Science.gov (United States)

    Understanding the temporal and spatial variability of surface water sources within a basin is vital to our ability to manage the impacts of climate variability and land cover change. Water stable isotopes can be used as a tool to determine geographic and seasonal sources of water at the basin scale. Previous studies in the Coastal Range of Oregon reported that the variation in the isotopic signatures of surface water does not conform to the commonly observed “rainout effect”, which exhibits a trend of increasing isotopic depletion with rising elevation. The primary purpose of this research is to investigate the mechanisms governing seasonal and spatial variations in the isotopic signature of surface waters within the Marys River Basin, located in the leeward side of the Oregon Coastal Range. Surface water and precipitation samples were collected every 2-3 weeks for isotopic analysis of δ18O and δ2H for one year. Results indicate a significant difference in isotopic signature between watersheds underlain by basalt and sandstone. The degree of separation was the most distinct during the summer when low flows reflect deeper groundwater sources, whereas isotopic signatures during the rainy season (fall and winter) showed a greater degree of similarity between the two lithologies. This indicates that baseflow within streams drained by sandstone versus basalt is being supplied from two distinctly separate water sources. In addition, Marys River flow at the outle

  5. Chemical state analysis of oxidation products on steel surface by conversion electron Moessbauer spectrometry

    International Nuclear Information System (INIS)

    Ujihira, Yusuke; Nomura, Kiyoshi

    1978-01-01

    The polished NT-70H steel (Fe: 95.97%, C: 0.56%, diameter: 5 cm, thickness: 0.5 cm) was immersed in deionized water or in solutions containing (0.25 -- 0.5) M of chloride, sulfate and nitrate ions. The chemical states of oxidation products of iron on the surface were identified through the analysis of conversion electron Moessbauer spectra (CEMS). CEMS of the steel surface, which had been dipped in deionized water, revealed that γ-FeOOH was formed on the surface. The thickness of γ-FeOOH layer increased with the increase of the duration of dipping. Dissolved oxygen in the solution played an essential role in the oxidation of iron to γ-FeOOH. Oxidation product of iron dipped in the 0.5 M sodium chloride solution was identified as γ-FeOOH. Amorphous paramagnetic iron (III) compound tended to form in the presence of hydrogen peroxide or ammonium ions in the solutions. The increase of alkalinity of the solution up to pH 12 suppressed the oxidation rate and assisted the formation of green rust, which was confirmed by the appearance of the quadrupole splitting peaks of the green rust. In the 0.25 M sodium sulfate solution, oxidation of the steel surface proceeded slowly and the quadrupole splitting peaks of Fe(OH) 2 were seen in the CEMS. The peak intensity of Fe(OH) 2 gradually decreased and that of γ-FeOOH increased by the extension of immersion of steel in the solution. Magnetite (Fe 3 O 4 ) layer was developed beneath the γ-FeOOH layer, when steel was dipped in 0.5 M sodium nitrate solution. However, the peaks of Fe 3 O 4 were not seen on CEMS of steel surface immersed in 0.5 M ammonium nitrate solution. Thus, applying the feasibility of CEMS for the characterization of oxidated compounds of iron on the steel surface formed by the immersion in solutions, the oxidation mechanism of the steel surface was discussed based upon the results of chemical state analyses. (author)

  6. Conversion chimique des surfaces d'alliages d'aluminium sans chrome hexavalent

    OpenAIRE

    Ely , Marion

    2016-01-01

    Conversion coatings are used in aerospace industry to protect the metal from corrosion and to promote paint adhesion. Currently, chromate conversion coatings are used, but chromate is toxic and carcinogenic and its use will be forbidden by the European REACh regulation. TCP (Trivalent Chromium Protection) conversion coatings, are considered as a promising alternative to replace chromate conversion coating. This work focuses on the characterisation of the TCP layer and considers each step of t...

  7. Broad beam ion sources and some surface processes

    International Nuclear Information System (INIS)

    Neumann, H.; Scholze, F.; Tarz, M.; Schindler, A.; Wiese, R.; Nestler, M.; Blum, T.

    2005-01-01

    Modern broad-beam multi-aperture ion sources are widely used in material and surface technology applications. Customizing the generated ion beam properties (i. e. the ion current density profile) for specific demands of the application is a main challenge in the improvement of the ion beam technologies. First we introduce ion sources based on different plasma excitation principles shortly. An overview of source plasma and ion beam measurement methods deliver input data for modelling methods. This beam profile modelling using numerical trajectory codes and the validation of the results by Faraday cup measurements as a basis for ion beam profile design are described. Furthermore possibilities for ex situ and in situ beam profile control are demonstrated, like a special method for in situ control of a linear ion source beam profile, a grid modification for circular beam profile design and a cluster principle for broad beam sources. By means of these methods, the beam shape may be adapted to specific technological demands. Examples of broad beam source application in ion beam figuring of optical surfaces, modification of stainless steel, photo voltaic processes and deposition of EUVL-multilayer stacks are finally presented. (Author)

  8. Calibrate the aerial surveying instrument by the limited surface source and the single point source that replace the unlimited surface source

    International Nuclear Information System (INIS)

    Lu Cunheng

    1999-01-01

    It is described that the calculating formula and surveying result is found on the basis of the stacking principle of gamma ray and the feature of hexagonal surface source when the limited surface source replaces the unlimited surface source to calibrate the aerial survey instrument on the ground, and that it is found in the light of the exchanged principle of the gamma ray when the single point source replaces the unlimited surface source to calibrate aerial surveying instrument in the air. Meanwhile through the theoretical analysis, the receiving rate of the crystal bottom and side surfaces is calculated when aerial surveying instrument receives gamma ray. The mathematical expression of the gamma ray decaying following height according to the Jinge function regularity is got. According to this regularity, the absorbing coefficient that air absorbs the gamma ray and the detective efficiency coefficient of the crystal is calculated based on the ground and air measuring value of the bottom surface receiving count rate (derived from total receiving count rate of the bottom and side surface). Finally, according to the measuring value, it is proved that imitating the change of total receiving gamma ray exposure rate of the bottom and side surfaces with this regularity in a certain high area is feasible

  9. Study of Syngas Conversion to Light Olefins by Response Surface Methodology

    Directory of Open Access Journals (Sweden)

    Hossein Atashi

    2013-01-01

    Full Text Available The effect of adding MgO to a precipitated iron-cobalt-manganese based Fischer-Tropsch synthesis (FTS catalyst was investigated via response surface methodology. The catalytic performance of the catalysts was examined in a fixed bed microreactor at a total pressure of 1–7 bar, temperature of 280–380°C, MgO content of 5–25% and using a syngas having a H2 to CO ratio equal to 2.The dependence of the activity and product distribution on MgO content, temperature, and pressure was successfully correlated via full quadratic second-order polynomial equations. The statistical analysis and response surface demonstrations indicated that MgO significantly influences the CO conversion and chain growth probability as well as ethane, propane, propylene, butylene selectivity, and alkene/alkane ratio. A strong interaction between variables was also evidenced in some cases. The decreasing effect of pressure on alkene to alkane ratio is investigated through olefin readsorption effects and CO hydrogenation kinetics. Finally, a multiobjective optimization procedure was employed to calculate the best amount of MgO content in different reactor conditions.

  10. Surface plasma source with saddle antenna radio frequency plasma generator.

    Science.gov (United States)

    Dudnikov, V; Johnson, R P; Murray, S; Pennisi, T; Piller, C; Santana, M; Stockli, M; Welton, R

    2012-02-01

    A prototype RF H(-) surface plasma source (SPS) with saddle (SA) RF antenna is developed which will provide better power efficiency for high pulsed and average current, higher brightness with longer lifetime and higher reliability. Several versions of new plasma generators with small AlN discharge chambers and different antennas and magnetic field configurations were tested in the plasma source test stand. A prototype SA SPS was installed in the Spallation Neutron Source (SNS) ion source test stand with a larger, normal-sized SNS AlN chamber that achieved unanalyzed peak currents of up to 67 mA with an apparent efficiency up to 1.6 mA∕kW. Control experiments with H(-) beam produced by SNS SPS with internal and external antennas were conducted. A new version of the RF triggering plasma gun has been designed. A saddle antenna SPS with water cooling is fabricated for high duty factor testing.

  11. Surface charge-conversion polymeric nanoparticles for photodynamic treatment of urinary tract bacterial infections

    International Nuclear Information System (INIS)

    Liu, Shijie; Shao, Chen; Qiao, Shenglin; Li, Lili; Qi, Guobin; Lin, Yaoxin; Qiao, Zengying; Wang, Hao

    2015-01-01

    Urinary tract infections are typical bacterial infections which result in a number of economic burdens. With increasing antibiotic resistance, it is urgent that new approaches are explored that can eliminate pathogenic bacteria without inducing drug resistance. Antimicrobial photodynamic therapy (PDT) is a new promising tactic. It is a gentle in situ photochemical reaction in which a photosensitizer (PS) generates reactive oxygen species (ROS) under laser irradiation. In this work, we have demonstrated Chlorin e6 (Ce6) encapsulated charge-conversion polymeric nanoparticles (NPs) for efficiently targeting and killing pathogenic bacteria in a weakly acidic urinary tract infection environment. Owing to the surface charge conversion of NPs in an acidic environment, the NPs exhibited enhanced recognition for Gram-positive (ex. S. aureus) and Gram-negative (ex. E. coli) bacteria due to the charge interaction. Also, those NPs showed significant antibacterial efficacy in vitro with low cytotoxicity. The MIC value of NPs to E. coli is 17.91 μg ml"−"1, compared with the free Ce6 value of 29.85 μg ml"−"1. Finally, a mouse acute cystitis model was used to assess the photodynamic therapy effects in urinary tract infections. A significant decline (P < 0.05) in bacterial cells between NPs and free Ce6 occurred in urine after photodynamic therapy treatment. And the plated counting results revealed a remarkable bacterial cells drop (P < 0.05) in the sacrificed bladder tissue. Above all, this nanotechnology strategy opens a new door for the treatment of urinary tract infections with minimal side effects. (paper)

  12. Surface charge-conversion polymeric nanoparticles for photodynamic treatment of urinary tract bacterial infections

    Science.gov (United States)

    Liu, Shijie; Qiao, Shenglin; Li, Lili; Qi, Guobin; Lin, Yaoxin; Qiao, Zengying; Wang, Hao; Shao, Chen

    2015-12-01

    Urinary tract infections are typical bacterial infections which result in a number of economic burdens. With increasing antibiotic resistance, it is urgent that new approaches are explored that can eliminate pathogenic bacteria without inducing drug resistance. Antimicrobial photodynamic therapy (PDT) is a new promising tactic. It is a gentle in situ photochemical reaction in which a photosensitizer (PS) generates reactive oxygen species (ROS) under laser irradiation. In this work, we have demonstrated Chlorin e6 (Ce6) encapsulated charge-conversion polymeric nanoparticles (NPs) for efficiently targeting and killing pathogenic bacteria in a weakly acidic urinary tract infection environment. Owing to the surface charge conversion of NPs in an acidic environment, the NPs exhibited enhanced recognition for Gram-positive (ex. S. aureus) and Gram-negative (ex. E. coli) bacteria due to the charge interaction. Also, those NPs showed significant antibacterial efficacy in vitro with low cytotoxicity. The MIC value of NPs to E. coli is 17.91 μg ml-1, compared with the free Ce6 value of 29.85 μg ml-1. Finally, a mouse acute cystitis model was used to assess the photodynamic therapy effects in urinary tract infections. A significant decline (P < 0.05) in bacterial cells between NPs and free Ce6 occurred in urine after photodynamic therapy treatment. And the plated counting results revealed a remarkable bacterial cells drop (P < 0.05) in the sacrificed bladder tissue. Above all, this nanotechnology strategy opens a new door for the treatment of urinary tract infections with minimal side effects.

  13. Influences of bulk and surface recombinations on the power conversion efficiency of perovskite solar cells

    International Nuclear Information System (INIS)

    Xie, Ziang; Sun, Shuren; Yan, Yu; Wang, Wei; Qin, Laixiang; Qin, G G

    2016-01-01

    For a novel kind of solar cell (SC) material, it is critical to estimate how far the power conversion efficiencies (PCEs) of the SCs made of it can go. In 2010 Han and Chen proposed the equation for the ultimate efficiency of SCs without considering the carrier recombination η un . η un is capable of estimating the theoretical upper limits of the SC efficiencies and has attracted much attention. However, carrier recombination, which is one of the key factors influencing the PCEs of the SCs, is ignored in the equation for η un . In this paper, we develop a novel equation to calculate the ultimate efficiency for the SCs, η ur , which considers both the bulk and the surface carrier recombinations. The novel equation for η ur can estimate how much the bulk and the surface carrier recombinations influence the PCEs of the SCs. Moreover, with η ur we can estimate how much PCE improvement space can be gained only by reducing the influence of the carrier recombination to the least. The perovskite organometal trihalide SCs have attracted tremendous attention lately. For the planar CH 3 NH 3 PbI 3 SCs, in the material depth range from 31.25–2000 nm, we apply the equation of η ur to investigate how the bulk and the surface carrier recombinations affect PCE. From a typically reported PCE of 15% for the planar CH 3 NH 3 PbI 3 SC, using the equation of η ur , it is concluded that by reducing the influence of carrier recombination to the least the improvement of PCE is in the range of 17–30%. (paper)

  14. Source effects on surface waves from Nevada Test Site explosions

    International Nuclear Information System (INIS)

    Patton, H.J.; Vergino, E.S.

    1981-11-01

    Surface waves recorded on the Lawrence Livermore National Laboratory (LLNL) digital network have been used to study five underground nuclear explosions detonated in Yucca Valley at the Nevada Test Site. The purpose of this study is to characterize the reduced displacement potential (RDP) at low frequencies and to test secondary source models of underground explosions. The observations consist of Rayleigh- and Love-wave amplitude and phase spectra in the frequency range 0.03 to 0.16 Hz. We have found that Rayleigh-wave spectral amplitudes are modeled well by a RDP with little or no overshoot for explosions detonated in alluvium and tuff. On the basis of comparisons between observed and predicted source phase, the spall closure source proposed by Viecelli does not appear to be a significant source of Rayleigh waves that reach the far field. We tested two other secondary source models, the strike-slip, tectonic strain release model proposed by Toksoez and Kehrer and the dip-slip thrust model of Masse. The surface-wave observations do not provide sufficient information to discriminate between these models at the low F-values (0.2 to 0.8) obtained for these explosions. In the case of the strike-slip model, the principal stress axes inferred from the fault slip angle and strike angle are in good agreement with the regional tectonic stress field for all but one explosion, Nessel. The results of the Nessel explosion suggest a mechanism other than tectonic strain release

  15. Mechanochemical activation and synthesis of nanomaterials for hydrogen storage and conversion in electrochemical power sources.

    Science.gov (United States)

    Wronski, Zbigniew S; Varin, Robert A; Czujko, Tom

    2009-07-01

    In this study we discuss a process of mechanical activation employed in place of chemical or thermal activation to improve the mobility and reactivity of hydrogen atoms and ions in nanomaterials for energy applications: rechargeable batteries and hydrogen storage for fuel cell systems. Two materials are discussed. Both are used or intended for use in power sources. One is nickel hydroxide, Ni(OH)2, which converts to oxyhydroxide in the positive Ni electrode of rechargeable metal hydride batteries. The other is a complex hydride, Mg(AIH4)2, intended for use in reversible, solid-state hydrogen storage for fuel cells. The feature shared by these unlikely materials (hydroxide and hydride) is a sheet-like hexagonal crystal structure. The mechanical activation was conducted in high-energy ball mills. We discuss and demonstrate that the mechanical excitation of atoms and ions imparted on these powders stems from the same class of phenomena. These are (i) proliferation of structural defects, in particular stacking faults in a sheet-like structure of hexagonal crystals, and (ii) possible fragmentation of a faulted structure into a mosaic of layered nanocrystals. The hydrogen atoms bonded in such nanocrystals may be inserted and abstracted more easily from OH- hydroxyl group in Ni(OH)2 and AlH4- hydride complex in Mg(AlH4)2 during hydrogen charge and discharge reactions. However, the effects of mechanical excitation imparted on these powders are different. While the Ni(OH)2 powder is greatly activated for cycling in batteries, the Mg(AlH4)2 complex hydride phase is greatly destabilized for use in reversible hydrogen storage. Such a "synchronic" view of the structure-property relationship in respect to materials involved in hydrogen energy storage and conversion is supported in experiments employing X-ray diffraction (XRD), differential scanning calorimetry (DSC) and direct imaging of the structure with a high-resolution transmission-electron microscope (HREM), as well as in

  16. The coupling effect of gas-phase chemistry and surface reactions on oxygen permeation and fuel conversion in ITM reactors

    KAUST Repository

    Hong, Jongsup

    2015-08-01

    © 2015 Elsevier B.V. The effect of the coupling between heterogeneous catalytic reactions supported by an ion transport membrane (ITM) and gas-phase chemistry on fuel conversion and oxygen permeation in ITM reactors is examined. In ITM reactors, thermochemical reactions take place in the gas-phase and on the membrane surface, both of which interact with oxygen permeation. However, this coupling between gas-phase and surface chemistry has not been examined in detail. In this study, a parametric analysis using numerical simulations is conducted to investigate this coupling and its impact on fuel conversion and oxygen permeation rates. A thermochemical model that incorporates heterogeneous chemistry on the membrane surface and detailed chemical kinetics in the gas-phase is used. Results show that fuel conversion and oxygen permeation are strongly influenced by the simultaneous action of both chemistries. It is shown that the coupling somewhat suppresses the gas-phase kinetics and reduces fuel conversion, both attributed to extensive thermal energy transfer towards the membrane which conducts it to the air side and radiates to the reactor walls. The reaction pathway and products, in the form of syngas and C2 hydrocarbons, are also affected. In addition, the operating regimes of ITM reactors in which heterogeneous- or/and homogeneous-phase reactions predominantly contribute to fuel conversion and oxygen permeation are elucidated.

  17. The effect of surface pre-conditioning treatments on the local composition of Zr-based conversion coatings formed on aluminium alloys

    Science.gov (United States)

    Cerezo, J.; Vandendael, I.; Posner, R.; de Wit, J. H. W.; Mol, J. M. C.; Terryn, H.

    2016-03-01

    This study investigates the effect of different alkaline, acidic and thermal pre-conditioning treatments applied to different Al alloy surfaces. The obtained results are compared to the characteristics of Zr-based conversion coatings that were subsequently generated on top of these substrates. Focus is laid on typical elemental distributions on the sample surfaces, in particular on the amount of precipitated functional additives such as Cu species that are present in the substrate matrix as well as in the conversion bath solutions. To this aim, Field Emission Auger Electron spectra, depth profiles and surface maps with superior local resolution were acquired and compared to scanning electron microscopy images of the sample. The results show how de-alloying processes, which occur at and around intermetallic particles in the Al matrix during typical industrial alkaline or acidic cleaning procedures, provide a significant source of crystallization cores for any following coating processes. This is in particular due for Cu-species, as the resulting local Cu structures on the surface strongly affect the film formation and compositions of state-of-the-art Zr-based films. The findings are highly relevant for industrial treatments of aluminium surfaces, especially for those that undergo corrosion protection and painting process steps prior to usage.

  18. Honeycomb surface-plasma negative-ion source

    International Nuclear Information System (INIS)

    Bel'chenko, Yu.I.

    1983-01-01

    A honeycomb surface-plasma source (SPS) of negative hydrogen ions the cathode of which consists of a great number of cells with spherical-concave surfaces, is described. Negative ions, knocked off the cathode by cesium-hydrogen discharge fast particles are accelerated in the near-cathode potential drop layer and focused geometrically on small emission apertures in the anode. Due to this, the gas and energy efficiency of the source is increased and the power density on the cathode is decreased. The H - yield is proportional to the number of celts. A pulse beam of negative ions with current up to 4 A is obtained and accelerated to 25 kV from the cathode effective area of 10.6 cm 2 through emission ports of 0.5 cm 2 total area. The honeycomb SPSs with a greater number of cells are promising as regards obtaining negative ion-beams with the current of scores of amperes

  19. Conversion of ICRP male reference phantom to polygon-surface phantom

    International Nuclear Information System (INIS)

    Yeom, Yeon Soo; Han, Min Cheol; Kim, Chan Hyeong; Jeong, Jong Hwi

    2013-01-01

    The International Commission on Radiological Protection (ICRP) reference phantoms, developed based on computed tomography images of human bodies, provide much more realism of human anatomy than the previously used MIRD5 (Medical Internal Radiation Dose) mathematical phantoms. It has been, however, realized that the ICRP reference phantoms have some critical limitations showing a considerable amount of holes for the skin and wall organs mainly due to the nature of voxels of which the phantoms are made, especially due to their low voxel resolutions. To address this problem, we are planning to develop the polygon-surface version of ICRP reference phantoms by directly converting the ICRP reference phantoms (voxel phantoms) to polygon-surface phantoms. The objective of this preliminary study is to see if it is indeed possible to construct the high-quality polygon-surface phantoms based on the ICRP reference phantoms maintaining identical organ morphology and also to identify any potential issues, and technologies to address these issues, in advance. For this purpose, in the present study, the ICRP reference male phantom was roughly converted to a polygon-surface phantom. Then, the constructed phantom was implemented in Geant4, Monte Carlo particle transport code, for dose calculations, and the calculated dose values were compared with those of the original ICRP reference phantom to see how much the calculated dose values are sensitive to the accuracy of the conversion process. The results of the present study show that it is certainly possible to convert the ICRP reference phantoms to surface phantoms with enough accuracy. In spite of using relatively less resources (<2 man-months), we were able to construct the polygon-surface phantom with the organ masses perfectly matching the ICRP reference values. The analysis of the calculated dose values also implies that the dose values are indeed not very sensitive to the detailed morphology of the organ models in the phantom

  20. Photocatalytic Conversion of Nitrogen to Ammonia with Water on Surface Oxygen Vacancies of Titanium Dioxide.

    Science.gov (United States)

    Hirakawa, Hiroaki; Hashimoto, Masaki; Shiraishi, Yasuhiro; Hirai, Takayuki

    2017-08-09

    Ammonia (NH 3 ) is an essential chemical in modern society. It is currently manufactured by the Haber-Bosch process using H 2 and N 2 under extremely high-pressure (>200 bar) and high-temperature (>673 K) conditions. Photocatalytic NH 3 production from water and N 2 at atmospheric pressure and room temperature is ideal. Several semiconductor photocatalysts have been proposed, but all suffer from low efficiency. Here we report that a commercially available TiO 2 with a large number of surface oxygen vacancies, when photoirradiated by UV light in pure water with N 2 , successfully produces NH 3 . The active sites for N 2 reduction are the Ti 3+ species on the oxygen vacancies. These species act as adsorption sites for N 2 and trapping sites for the photoformed conduction band electrons. These properties therefore promote efficient reduction of N 2 to NH 3 . The solar-to-chemical energy conversion efficiency is 0.02%, which is the highest efficiency among the early reported photocatalytic systems. This noble-metal-free TiO 2 system therefore shows a potential as a new artificial photosynthesis for green NH 3 production.

  1. Role of volume and surface spontaneous parametric down-conversion in the generation of photon pairs in layered media

    Czech Academy of Sciences Publication Activity Database

    Javůrek, D.; Peřina ml., Jan

    2017-01-01

    Roč. 95, č. 4 (2017), s. 1-13, č. článku 043828. ISSN 2469-9926 Institutional support: RVO:68378271 Keywords : surface spontaneous * parametric down-conversion * photon pairs * layered media Subject RIV: BH - Optics, Masers, Lasers OBOR OECD: Optics (including laser optics and quantum optics) Impact factor: 2.925, year: 2016

  2. Semantic Trouble Sources and Their Repair in Conversations Affected by Parkinson's Disease

    Science.gov (United States)

    Saldert, Charlotta; Ferm, Ulrika; Bloch, Steven

    2014-01-01

    Background: It is known that dysarthria arising from Parkinson's disease may affect intelligibility in conversational interaction. Research has also shown that Parkinson's disease may affect cognition and cause word-retrieval difficulties and pragmatic problems in the use of language. However, it is not known whether or how these…

  3. Source Water Assessment for the Las Vegas Valley Surface Waters

    Science.gov (United States)

    Albuquerque, S. P.; Piechota, T. C.

    2003-12-01

    The 1996 amendment to the Safe Drinking Water Act of 1974 created the Source Water Assessment Program (SWAP) with an objective to evaluate potential sources of contamination to drinking water intakes. The development of a Source Water Assessment Plan for Las Vegas Valley surface water runoff into Lake Mead is important since it will guide future work on source water protection of the main source of water. The first step was the identification of the watershed boundary and source water protection area. Two protection zones were delineated. Zone A extends 500 ft around water bodies, and Zone B extends 3000 ft from the boundaries of Zone A. These Zones extend upstream to the limits of dry weather flows in the storm channels within the Las Vegas Valley. After the protection areas were identified, the potential sources of contamination in the protection area were inventoried. Field work was conducted to identify possible sources of contamination. A GIS coverage obtained from local data sources was used to identify the septic tank locations. Finally, the National Pollutant Discharge Elimination System (NPDES) Permits were obtained from the State of Nevada, and included in the inventory. After the inventory was completed, a level of risk was assigned to each potential contaminating activity (PCA). The contaminants of concern were grouped into five categories: volatile organic compounds (VOCs), synthetic organic compounds (SOCs), inorganic compounds (IOCs), microbiological, and radionuclides. The vulnerability of the water intake to each of the PCAs was assigned based on these five categories, and also on three other factors: the physical barrier effectiveness, the risk potential, and the time of travel. The vulnerability analysis shows that the PCAs with the highest vulnerability rating include septic systems, golf courses/parks, storm channels, gas stations, auto repair shops, construction, and the wastewater treatment plant discharges. Based on the current water quality

  4. Blind source identification from the multichannel surface electromyogram

    International Nuclear Information System (INIS)

    Holobar, A; Farina, D

    2014-01-01

    The spinal circuitries combine the information flow from the supraspinal centers with the afferent input to generate the neural codes that drive the human skeletal muscles. The muscles transform the neural drive they receive from alpha motor neurons into motor unit action potentials (electrical activity) and force. Thus, the output of the spinal cord circuitries can be examined noninvasively by measuring the electrical activity of skeletal muscles at the surface of the skin i.e. the surface electromyogram (EMG). The recorded multi-muscle EMG activity pattern is generated by mixing processes of neural sources that need to be identified from the recorded signals themselves, with minimal or no a priori information available. Recently, multichannel source separation techniques that rely minimally on a priori knowledge of the mixing process have been developed and successfully applied to surface EMG. They act at different scales of information extraction to identify: (a) the activation signals shared by synergistic skeletal muscles, (b) the specific neural activation of individual muscles, separating it from that of nearby muscles i.e. from crosstalk, and (c) the spike trains of the active motor neurons. This review discusses the assumptions made by these methods, the challenges and limitations, as well as examples of their current applications. (topical review)

  5. Experimental study on source efficiencies for estimating surface contamination level

    International Nuclear Information System (INIS)

    Ichiji, Takeshi; Ogino, Haruyuki

    2008-01-01

    Source efficiency was measured experimentally for various materials, such as metals, nonmetals, flooring materials, sheet materials and other materials, contaminated by alpha and beta emitter radioactive nuclides. Five nuclides, 147 Pm, 60 Co, 137 Cs, 204 Tl and 90 Sr- 90 Y, were used as the beta emitters, and one nuclide 241 Am was used as the alpha emitter. The test samples were prepared by placing drops of the radioactive standardized solutions uniformly on the various materials using an automatic quantitative dispenser system from Musashi Engineering, Inc. After placing drops of the radioactive standardized solutions, the test materials were allowed to dry for more than 12 hours in a draft chamber with a hood. The radioactivity of each test material was about 30 Bq. Beta rays or alpha rays from the test materials were measured with a 2-pi gas flow proportional counter from Aloka Co., Ltd. The source efficiencies of the metals, nonmetals and sheet materials were higher than 0.5 in the case of contamination by the 137 Cs, 204 Tl and 90 Sr- 90 Y radioactive standardized solutions, higher than 0.4 in the case of contamination by the 60 Co radioactive standardized solution, and higher than 0.25 in the case of contamination by the alpha emitter the 241 Am radioactive standardized solution. These values were higher than those given in Japanese Industrial Standards (JIS) documents. In contrast, the source efficiencies of some permeable materials were lower than those given in JIS documents, because source efficiency varies depending on whether the materials or radioactive sources are wet or dry. This study provides basic data on source efficiency, which is useful for estimating the surface contamination level of materials. (author)

  6. Standardization method for alpha and beta surface sources

    Energy Technology Data Exchange (ETDEWEB)

    Sahagia, M; Grigorescu, E L; Razdolescu, A C; Ivan, C [Institute of Physics and Nuclear Engineering, Institute of Atomic Physics, PO Box MG-6, R-76900 Bucharest, (Romania)

    1994-01-01

    The installation and method of standardization of large surface alpha and beta sources are presented. A multiwire, flow-type proportional counter and the associated electronics is used. The counter is placed in a lead-shield. The response of the system in (s[sup -1]/Bq) or (s[sup -1]/(particle x s[sup -1])) was determined for [sup 241] Am, [sup 239] Pu, [sup 147] Pm, [sup 204] Tl, [sup 90](Sr+Y) and [sup 137] Cs using standard sources with different dimensions, from some mm[sup 2] to 180 x 220 mm[sup 2]. The system was legally attested for expanded uncertainties of +7%. (Author).

  7. 100 kWe lunar/Mars surface power utilizing the SP-100 reactor with dynamic conversion

    International Nuclear Information System (INIS)

    Harty, R.B.; Mason, L.S.

    1992-01-01

    This paper reports on an integration study which was performed coupling an SP-100 reactor with either a Brayton of Stirling power conversion subsystem. a power level of 100 kWe was selected for the study. The power system was to be compatible with both the lunar and Mars surface environment and require no site preparation. In addition, the reactor was to have integral shielding and be completely self-contained, including its own auxiliary power for start-up. Initial reliability studies were performed to determine power conversion redundancy and engine module size. For the lunar environment, the reactor and primary coolant loop would be contained in a guard vessel to protect from a loss of primary loop containment. For the Mars environment, all refractory components including the reactor, primary coolant, and power conversion components would be contained in a vacuum vessel for protection against the CO 2 environment

  8. On the Development of Fuel-Free Power Supply Sources on Pneumatic Energy Conversion Principles

    Science.gov (United States)

    Son, E. E.; Nikolaev, V. G.; Kudryashov, Yu. I.; Nikolaev, V. V.

    2017-12-01

    The article is devoted to the evaluation of capabilities and problems of creation of fuel-free power supply of isolated and autonomous Russian consumers of low (up to several hundreds kW) power based on the joint use of wind power plants and progressive systems of pneumatic accumulation and conversion of energy. The basic and functional schemes and component structure of the system prototype are developed and proposed, the evaluations of the expected technical and economic indicators of system are presented, and the ways of its further practical implementation are planned.

  9. A thermoelectric-conversion power supply system using a strontium heat source of high-level radioactive nuclear waste

    International Nuclear Information System (INIS)

    Chikazawa, Yoshitaka

    2011-01-01

    A thermoelectric-conversion power supply system with radioactive strontium in high-level radioactive waste has been proposed. A combination of Alkali Metal Thermo-Electric Conversion (AMTEC) and a strontium fluoride heat source can provide a compact and long-lived power supply system. A heat source design with strontium fluoride pin bundles with Hastelloy cladding and intermediate copper has been proposed. This design has taken heat transportation into consideration, and, in this regard, the feasibility has been confirmed by a three-dimensional thermal analysis using Star-CD code. This power supply system with an electric output of 1 MW can be arranged in a space of 50 m 2 and approximately 1.1 m height and can be operated for 15 years without refueling. This compact and long-lived power supply is suitable for powering sources for remote places and middle-sized ships. From the viewpoint of geological disposal of high-level waste, the proposed power supply system provides a financial base for strontium-cesium partitioning. That is, a combination of minor-actinide recycling and strontium-cesium partitioning can eliminate a large part of decay heat in high-level waste and thus can save much space for geological disposal. (author)

  10. Corrosion and biofouling on the non-heat-exchanger surfaces of an ocean thermal energy conversion power plant: a survey

    Energy Technology Data Exchange (ETDEWEB)

    Castelli, V.J. (ed.)

    1979-05-01

    Of the many foreseeable problems confronting economical ocean thermal energy conversion operation, two major items are the deterioration of the structural and functional components, which prevents efficient operation, and the biofouling of the surfaces, which adds excess weight to the floating ocean platform. The techniques required for effective long-term control of deterioration and corrosion have been investigated actively for many years, and successful solutions for most situations have been developed. For the most part, these solutions can be directly transferred to the ocean thermal energy conversion plant. The majority of problems in these areas are expected to be associated with scale-up and will require some advanced development due to the immensity of the ocean thermal energy conversion platform. Current antifouling control systems are not effective for long-term fouling prevention. Commercially available antifouling coatings are limited to a 3-year service life in temperate waters, and even shorter in tropical waters. However, underwater cleaning techniques and some fouling-control systems presently being used by conventional power plants may find utility on an ocean thermal energy conversion plant. In addition, some recent major advances in long-term antifouling coatings sponsored by the Navy may be applicable to ocean thermal energy conversion. 132 references.

  11. Conversion of time-varying Stokes coefficients into mass anomalies at the Earth's surface considering the Earth's oblateness

    Science.gov (United States)

    Ditmar, Pavel

    2018-02-01

    Time-varying Stokes coefficients estimated from GRACE satellite data are routinely converted into mass anomalies at the Earth's surface with the expression proposed for that purpose by Wahr et al. (J Geophys Res 103(B12):30,205-30,229, 1998). However, the results obtained with it represent mass transport at the spherical surface of 6378 km radius. We show that the accuracy of such conversion may be insufficient, especially if the target area is located in a polar region and the signal-to-noise ratio is high. For instance, the peak values of mean linear trends in 2003-2015 estimated over Greenland and Amundsen Sea embayment of West Antarctica may be underestimated in this way by about 15%. As a solution, we propose an updated expression for the conversion of Stokes coefficients into mass anomalies. This expression is based on the assumptions that: (i) mass transport takes place at the reference ellipsoid and (ii) at each point of interest, the ellipsoidal surface is approximated by the sphere with a radius equal to the current radial distance from the Earth's center ("locally spherical approximation"). The updated expression is nearly as simple as the traditionally used one but reduces the inaccuracies of the conversion procedure by an order of magnitude. In addition, we remind the reader that the conversion expressions are defined in spherical (geocentric) coordinates. We demonstrate that the difference between mass anomalies computed in spherical and ellipsoidal (geodetic) coordinates may not be negligible, so that a conversion of geodetic colatitudes into geocentric ones should not be omitted.

  12. Consequences of the conversion of research reactor cores on experimental facilities at the example of a cold neutron source

    International Nuclear Information System (INIS)

    Roegler, H.-J.; Goebs, H.; Stroemich, A.

    1985-01-01

    The consequences for and specifically the potential reduction of the performance of research reactors have been in discussions very often within the last five years as one of the draw-backs which has to be paid for the reduction of the proliferation risk at research reactor plants. Up to now and up to our knowledge the available results are restricted to unperturbated fluxes. Thus, this contribution makes the attempt to demonstrate the consequence of core conversion on an example of a real experimental facility and - at the same time - on one that is going to be used in the next decade a lot, i.e. a cold neutron source (CNS). (author)

  13. On the influence of the finite thickness of sources on the internal conversion lines observed in beta spectrometer

    International Nuclear Information System (INIS)

    Pecequilo, B.R.S.

    1976-01-01

    Electron lines are simulated by a Monte Carlo method in a digital computer in order to obtain an analytical formula to calculate the energy and the relative intensity of electron conversion lines when observed by beta spectrometry. The electrons come from the own thickness of the source. Computer program that simulate these lines is presented. In order to test the method, a direct comparison of the K-line of Hg-198 with the same line as simulated by the computer, is done [pt

  14. Multiple sources of boron in urban surface waters and groundwaters

    Energy Technology Data Exchange (ETDEWEB)

    Hasenmueller, Elizabeth A., E-mail: eahasenm@wustl.edu; Criss, Robert E.

    2013-03-01

    Previous studies attribute abnormal boron (B) levels in streams and groundwaters to wastewater and fertilizer inputs. This study shows that municipal drinking water used for lawn irrigation contributes substantial non-point loads of B and other chemicals (S-species, Li, and Cu) to surface waters and shallow groundwaters in the St. Louis, Missouri, area. Background levels and potential B sources were characterized by analysis of lawn and street runoff, streams, rivers, springs, local rainfall, wastewater influent and effluent, and fertilizers. Urban surface waters and groundwaters are highly enriched in B (to 250 μg/L) compared to background levels found in rain and pristine, carbonate-hosted streams and springs (< 25 μg/L), but have similar concentrations (150 to 259 μg/L) compared to municipal drinking waters derived from the Missouri River. Other data including B/SO{sub 4}{sup 2-}−S and B/Li ratios confirm major contributions from this source. Moreover, sequential samples of runoff collected during storms show that B concentrations decrease with increased discharge, proving that elevated B levels are not primarily derived from combined sewer overflows (CSOs) during flooding. Instead, non-point source B exhibits complex behavior depending on land use. In urban settings B is rapidly mobilized from lawns during “first flush” events, likely representing surficial salt residues from drinking water used to irrigate lawns, and is also associated with the baseflow fraction, likely derived from the shallow groundwater reservoir that over time accumulates B from drinking water that percolates into the subsurface. The opposite occurs in small rural watersheds, where B is leached from soils by recent rainfall and covaries with the event water fraction. Highlights: ► Boron sources and loads differ between urban and rural watersheds. ► Wastewaters are not the major boron source in small St. Louis, MO watersheds. ► Municipal drinking water used for lawn

  15. Development of a cell culture surface conversion technique using alginate thin film for evaluating effect upon cellular differentiation

    International Nuclear Information System (INIS)

    Nakashima, Y.; Tsusu, K.; Minami, K.; Nakanishi, Y.

    2014-01-01

    Here, we sought to develop a cell culture surface conversion technique that would not damage living cells. An alginate thin film, formed on a glass plate by spin coating of sodium alginate solution and dipping into calcium chloride solution, was used to inhibit adhesion of cells. The film could be removed by ethylenediaminetetraacetate (EDTA) at any time during cell culture, permitting observation of cellular responses to conversion of the culture surface in real time. Additionally, we demonstrated the validity of the alginate thin film coating method and the performance of the film. The thickness of the alginate thin film was controlled by varying the rotation speed during spin coating. Moreover, the alginate thin film completely inhibited the adhesion of cultured cells to the culture surface, irrespective of the thickness of the film. When the alginate thin film was removed from the culture surface by EDTA, the cultured cells adhered to the culture surface, and their morphology changed. Finally, we achieved effective differentiation of C2C12 myoblasts into myotube cells by cell culture on the convertible culture surface, demonstrating the utility of our novel technique

  16. Construction of a single/multiple wavelength RZ optical pulse source at 40 GHz by use of wavelength conversion in a high-nonlinearity DSF-NOLM

    DEFF Research Database (Denmark)

    Yu, Jianjun; Yujun, Qian; Jeppesen, Palle

    2001-01-01

    A single or multiple wavelength RZ optical pulse source at 40 GHz is successfully obtained by using wavelength conversion in a nonlinear optical loop mirror consisting of high nonlinearity-dispersion shifted fiber.......A single or multiple wavelength RZ optical pulse source at 40 GHz is successfully obtained by using wavelength conversion in a nonlinear optical loop mirror consisting of high nonlinearity-dispersion shifted fiber....

  17. Surface-Source Downhole Seismic Analysis in R

    Science.gov (United States)

    Thompson, Eric M.

    2007-01-01

    This report discusses a method for interpreting a layered slowness or velocity model from surface-source downhole seismic data originally presented by Boore (2003). I have implemented this method in the statistical computing language R (R Development Core Team, 2007), so that it is freely and easily available to researchers and practitioners that may find it useful. I originally applied an early version of these routines to seismic cone penetration test data (SCPT) to analyze the horizontal variability of shear-wave velocity within the sediments in the San Francisco Bay area (Thompson et al., 2006). A more recent version of these codes was used to analyze the influence of interface-selection and model assumptions on velocity/slowness estimates and the resulting differences in site amplification (Boore and Thompson, 2007). The R environment has many benefits for scientific and statistical computation; I have chosen R to disseminate these routines because it is versatile enough to program specialized routines, is highly interactive which aids in the analysis of data, and is freely and conveniently available to install on a wide variety of computer platforms. These scripts are useful for the interpretation of layered velocity models from surface-source downhole seismic data such as deep boreholes and SCPT data. The inputs are the travel-time data and the offset of the source at the surface. The travel-time arrivals for the P- and S-waves must already be picked from the original data. An option in the inversion is to include estimates of the standard deviation of the travel-time picks for a weighted inversion of the velocity profile. The standard deviation of each travel-time pick is defined relative to the standard deviation of the best pick in a profile and is based on the accuracy with which the travel-time measurement could be determined from the seismogram. The analysis of the travel-time data consists of two parts: the identification of layer-interfaces, and the

  18. Comparative evaluations of surface contamination detectors calibration with radioactive sources - used in the Goiania accident, and standard sources

    International Nuclear Information System (INIS)

    Becker, P.H.B.; Marecha, M.H.H.

    1997-01-01

    The construction of Cs-137 standard flat sources for calibration of surface contamination detectors, used in the Goiania accident in 1987, is described and the procedures adopted are reported. At that time, standard sources were not available. Nowadays the Instituto de Radioprotecao e Dosimetria has standard sources acquired from Amersham which are used as calibration standards for surface contamination detectors. Comparative evaluations between the standard flat sources constructed for the accident and the calibrated ones are presented

  19. Drinking Water Sources with Surface Intakes from LDHH source data, Geographic NAD83, LOSCO (1999) [drinking_water_surface_intakes_LDHH_1999

    Data.gov (United States)

    Louisiana Geographic Information Center — This is a point dataset for 87 public drinking water sources with surface intakes. It was derived from a larger statewide general drinking water source dataset...

  20. Molybdate/phosphate composite conversion coating on magnesium alloy surface for corrosion protection

    International Nuclear Information System (INIS)

    Yong Zhiyi; Zhu Jin; Qiu Cheng; Liu Yali

    2008-01-01

    In this paper, a new conversion coating-molybdate/phosphate (Mo/P) coating on magnesium alloy was prepared and investigated by electrochemical impedance spectra (EIS), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and salt-water immersion experiments, respectively. The results demonstrated that the Mo/P coating contained composite phases, which were consisted of metaphosphate as well as molybdate oxide with an 'alveolate-crystallized' structure. The composite Mo/P conversion coating had better corrosion resistance performance than molybdate (Mo) coating, and even had almost comparable corrosion protection for Mg alloy to the traditional chromate-based coating.

  1. Surface, interface and bulk materials characterization using Indus synchrotron sources

    International Nuclear Information System (INIS)

    Phase, Deodatta M.

    2014-01-01

    Synchrotron radiation sources, providing intense, polarized and stable beams of ultra violet, soft and hard x-ray photons, are having great impact on physics, chemistry, biology, materials science and other areas research. In particular synchrotron radiation has revolutionized materials characterization techniques by enhancing its capabilities for investigating the structural, electronic and magnetic properties of solids. The availability of synchrotron sources and necessary instrumentation has led to considerable improvements in spectral resolution and intensities. As a result, application scope of different materials characterization techniques has tremendously increased particularly in the analysis of solid surfaces, interfaces and bulk materials. The Indian synchrotron storage ring, Indus-1 and Indus-2 are in operation at RRCAT, Indore. The UGC-DAE CSR with the help of university scientist had designed and developed an angle integrated photoelectron spectroscopy (AlPES) beam line on Indus-1 storage ring of 450 MeV and polarized light beam line for soft x-ray absorption spectroscopy (SXAS) on Indus-2 storage ring of 2.5 GeV. (author)

  2. Hydrothermal conversion of biomass to liquid energy sources; Hydrothermale Konversion von Biomasse zu fluessigen Energietraegern

    Energy Technology Data Exchange (ETDEWEB)

    Kroeger, Michael; Peters, Mario; Klemm, Marco; Nelles, Michael [Deutsches Biomasseforschungszentrum (DBFZ) gemeinnuetzige GmbH, Leipzig (Germany)

    2013-10-01

    Beside thermo-chemical processes like pyrolysis, torrefaction and gasification another process group called hydrothermal conversion of biomass comes into the focus of research and development. Especially for wet biomass this process has several advantages: as the reaction medium is water wet biomass not needs to be dried. Beside the reaction pathways, which are still not completely understood, it is important to investigate reactor concepts. That gives the possibility to continuously process the given biomass to deduce specific process conditions for the production of chemicals and fuels. Experiments were conducted in a newly developed tubular reactor at temperatures from 150 to 270 C and reaction times from 1 to 6 min. By studying the HPLC analysis of the liquid products the formation and degradation of several products which may be utilized as base materials for chemicals and fuels (furfural, 5-HMF etc.) was conducted. The experiments illustrate the possibility to influence product composition to a certain extend only by varying temperature and time of the hydrothermal process. That could result in an economic and feasible way to produce intermediate chemicals from biomass. In a second step these product analysis will be used to develop catalysts and investigate the possibilities of in-situ-hydrogenation and synthesis of further valuable chemicals and fuels. (orig.)

  3. NON-POLLUTING METAL SURFACE FINISHING PRETREATMENT AND PRETREATMENT/CONVERSION COATING

    Science.gov (United States)

    Picklex, a proprietary formulation, is an alterantive to conventional metal surface pretreatments and is claimed not to produce waste or lower production or lower performance. A laboratory program was designed to evaluate Picklex in common, large scale, polluting surface finishin...

  4. Thermoelectric energy conversion in layered structures with strained Ge quantum dots grown on Si surfaces

    Science.gov (United States)

    Korotchenkov, Oleg; Nadtochiy, Andriy; Kuryliuk, Vasyl; Wang, Chin-Chi; Li, Pei-Wen; Cantarero, Andres

    2014-03-01

    The efficiency of the energy conversion devices depends in many ways on the materials used and various emerging cost-effective nanomaterials have promised huge potentials in highly efficient energy conversion. Here we show that thermoelectric voltage can be enhanced by a factor of 3 using layer-cake growth of Ge quantum dots through thermal oxidation of SiGe layers stacked in SiO2/Si3N4 multilayer structure. The key to achieving this behavior has been to strain the Ge/Si interface by Ge dots migrating to Si substrate. Calculations taking into account the carrier trapping in the dot with a quantum transmission into the neighboring dot show satisfactory agreement with experiments above ≈200 K. The results may be of interest for improving the functionality of thermoelectric devices based on Ge/Si.

  5. A pulsed source neutron reflectometer for surface studies

    International Nuclear Information System (INIS)

    Penfold, J.; Williams, W.G.

    1985-05-01

    A design for a neutron reflectometer for surface studies to be constructed at the SNS is presented. Examples of its use to study problems in surface chemistry, surface magnetism and low dimensional structures are highlighted. (author)

  6. Effects of acid and alkaline based surface preparations on spray deposited cerium based conversion coatings on Al 2024-T3

    Energy Technology Data Exchange (ETDEWEB)

    Pinc, W. [Department of Materials Science Engineering, Materials Research Center, Missouri University of Science and Technology, Rolla, MO 65409 (United States)], E-mail: wrphw5@mst.edu; Geng, S.; O' Keefe, M.; Fahrenholtz, W.; O' Keefe, T. [Department of Materials Science Engineering, Materials Research Center, Missouri University of Science and Technology, Rolla, MO 65409 (United States)

    2009-01-15

    Cerium based conversion coatings were spray deposited on Al 2024-T3 and characterized to determine the effect of surface preparation on the deposition rate and surface morphology. It was found that activation of the panel using a 1-wt.% sulfuric acid solution increased the coating deposition rate compared to alkaline cleaning alone. Analysis of the surface morphology of the coatings showed that the coatings deposited on the acid treated panels exhibited fewer visible cracks compared to coatings on alkaline cleaned panels. Auger electron spectroscopy depth profiling showed that the acid activation decreased the thickness of the aluminum oxide layer and the concentration of magnesium on the surface of the panels compared to the alkaline treatment. Additionally, acid activation increased the copper concentration at the surface of the aluminum substrate. Based on the results, the acid based surface treatment appeared to expose copper rich intermetallics, thus increasing the number of cathodic sites on the surface, which led to an overall increase in the deposition rate.

  7. Third-order spontaneous parametric down-conversion in thin optical fibers as a photon-triplet source

    Energy Technology Data Exchange (ETDEWEB)

    Corona, Maria [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico, apdo. postal 70-543, DF 04510 Mexico City (Mexico); Departamento de Optica, Centro de Investigacion Cientifica y de Educacion Superior de Ensenada, Apartado Postal 2732, BC 22860 Ensenada (Mexico); Garay-Palmett, Karina; U' Ren, Alfred B. [Instituto de Ciencias Nucleares, Universidad Nacional Autonoma de Mexico, apdo. postal 70-543, DF 04510 Mexico City (Mexico)

    2011-09-15

    We study the third-order spontaneous parametric down-conversion (TOSPDC) process, as a means to generate entangled photon triplets. Specifically, we consider thin optical fibers as the nonlinear medium to be used as the basis for TOSPDC in configurations where phase matching is attained through the use of more than one fiber transverse modes. Our analysis in this paper, which follows from our earlier paper [Opt. Lett. 36, 190-192 (2011)], aims to supply experimentalists with the details required in order to design a TOSPDC photon-triplet source. Specifically, our analysis focuses on the photon triplet state, on the rate of emission, and on the TOSPDC phase-matching characteristics for the cases of frequency-degenerate and frequency nondegenerate TOSPDC.

  8. Microbial conversion of agriculture wastes as a source of energy for developing countries: a case study in Nigeria

    International Nuclear Information System (INIS)

    Ejike, C.; Okereke, G.U.

    1991-01-01

    The direct relationship between level of economic development of any nation and its consumption of energy show that there is improve standard of living with increase in the per capita consumption of energy. In Nigeria, the need to offset some of the economic set backs brought about by increasing fuel costs and chronic lack of foreign currency reserves has compelled her to search for alternative sources of energy. The continuous increase in concern over environmental pollution has also resulted in greater negative cost values of wastes and hence has increased their potential as substrates for bio-derived energy. Cellulosic agricultural wastes are available in Nigeria in large amounts, are ordinarily of little economic value and are non toxic. Nigeria produces about 227,500 tons of animal waste per day implying the bio gas production could be a feasible alternative source of energy. Conversion of agricultural waste to usable energy at commercially acceptable rates involves the availability of raw materials and conversion of same to suitable substrates for fermentation to alcohol and then to bio gas. Saccharomyces spp. produced from fermentation of alcoholic beverages in Northern Nigeria have been used in the production of ethanol from corn corp waste and grass straw. Chromolaena odorata a weed that has no economic value which grows luxuriantly in Nigeria has been used in the generation of bio gas. Drying procedure and pH are among other conditions the affect methane yield. The development of the biotechnology of bio-derivable energy from agricultural waste if effectively harnessed will help to aleviate the energy problems of developing countries. The climate for the promotion of this technology is favourable because of low cost of raw material, high cost of fuel energy, and poor foreign exchange earning capacity of developing countries. (author)

  9. Sources of scattering in vegetarian and other surfaces and objects

    Science.gov (United States)

    Moore, R. K.

    1988-01-01

    The sources of scattering in vegetation and other surfaces and objects were studied. A special radar, SOURCESCAT, that could resolve a cylindrical volume 18 cm in diameter and 11 cm long was built. This system provided the first really fine-resolution measurements of radar backscatter from vegetation. The measurements showed that many of the assumptions used previously in modeling vegetation backscatter were false. Vegetation studied included various field crops, prairie grass, and various trees. Major differences were found in the roles of leaves, branches, stems, and trunks for different species. An artificial tree was studied in the laboratory using the systems. The most significant findings were that the average radar volume scattering coefficient is independent of azimuth, and that slanting of the polarization vector can give useful information not available with ordinary vertical and horizontal polarization. A model for scattering from a single leaf was developed. This model, for the first time, took into account the presence of veins in leaves. The pattern of scatter from a leaf was shown quite different from that for which the veins are ignored. A list of publications and presentations resulting from this project are attached.

  10. Directed surfaces structures and interfaces for enhanced electrocatalyst activity, selectivity, and stability for energy conversion reactions

    Energy Technology Data Exchange (ETDEWEB)

    Jaramillo, Thomas F. [Stanford Univ., CA (United States). Dept. of Chemical Engineering. Shriram Center

    2016-04-20

    In this project, we have employed a systematic approach to develop active, selective, and stable catalyst materials for important electrochemical reactions involving energy conversion. In particular, we have focused our attention on developing active catalyst materials for the hydrogen evolution reaction (HER), oxygen evolution reaction (OER) and oxygen reduction reaction (ORR). HER: We have synthesized and investigated several highly active and acid stable non-precious metal HER catalysts, including: [Mo3S13]2- nanoclusters (Nature Chemistry, 2014) and molybdenum phosphosulfide (MoP|S) (Angewandte Chemie, 2014). We have also aimed to engineer these catalyst formulations in a membrane electrode assembly (MEA) for fundamental studies of water electrolysis at high current densities, approximately 1 A/cm2 (ChemSusChem, 2015). We furthermore investigated transition metal phosphide (TMP) catalysts for HER by a combined experimental–theoretical approach (Energy & Environmental Science, 2015). By synthesizing different TMPs and comparing experimentally determined HER activities with the hydrogen adsorption free energies, ΔGH, calculated by density functional theory, we showed that the TMPs follow a volcano relationship for the HER. Using our combined experimental–theoretical model, we predicted that the mixed metal TMP, Fe0.5Co0.5P, should have a near-optimal ΔGH. We synthesized several mixtures of Co and Fe phosphides alloys and confirmed that Fe0.5Co0.5P exhibits the highest HER activity of the investigated TMPs (Energy & Environmental Science, 2015). The understanding gained as to how to improve catalytic activity for the HER, particularly for non-precious metal materials, is important to DOE targets for sustainable H2 production. OER: We have developed a SrIrO3/IrOx catalyst for acidic conditions (submitted, 2016). The Sr

  11. Formation of ZnSe/Bi2Se3 QDs by surface cation exchange and high photothermal conversion

    Directory of Open Access Journals (Sweden)

    Guozhi Jia

    2015-08-01

    Full Text Available Water-dispersed core/shell structure ZnSe/Bi2Se3 quantum dots were synthesized by ultrasonicwave-assisted cation exchange reaction. Only surface Zn ion can be replaced by Bi ion in ZnSe quantum dots, which lead to the ultrathin Bi2Se3 shell layer formed. It is significance to find to change the crystal of QDs due to the acting of ultrasonicwave. Cation exchange mechanism and excellent photothermal conversion properties are discussed in detail.

  12. Effect of cerium conversion of A3xx.x/SiCp composites surfaces on salt fog corrosion behaviour

    Energy Technology Data Exchange (ETDEWEB)

    Pardo, A.; Merino, M.C.; Arrabal, R.; Viejo, F.; Carboneras, M.; Coy, A.E. [Departamento de Ciencia de Materiales, Facultad de Quimica, Universidad Complutense, 28040, Madrid (Spain); Merino, S. [Departamento de Tecnologia Industrial, Universidad Alfonso X El Sabio, 28691, Villanueva de la Canada, Madrid (Spain)

    2004-07-01

    A study of the effect of cerium conversion treatment on surface of four composites (A360/SiC/10p, A360/SiC/20p, A380/SiC/10p, A380/SiC/20p) on their salt fog corrosion behaviour was performed. The conversion treatment was carried out using thermal activated full immersion in Ce(III) aqueous solutions. The matrix of A360/SiC/xxp composites is virtually free of Cu while the A380/SiC/xxp matrix contains 1.39-1.44 wt.%Ni and 3.13-3.45 wt.%Cu. Conversion performance was evaluated in neutral salt fog environment according to ASTM B117. The kinetics of the corrosion process were studied on the basis of gravimetric tests. The influence of SiCp proportion and matrix composition was evaluated and the nature of corrosion products was analysed by SEM and low angle XRD before and after accelerated testing to determine the influence of microstructural changes on corrosion behaviour during exposure to the corrosive environment. The Ce(III) precipitates on the cathodic sites, mainly on the intermetallic compounds, decreased both the cathodic current density and the corrosion rate of the composites tested. The presence of Cu in the matrix composition increased the corrosion rate, due to the galvanic couple Al/Cu. (authors)

  13. Return of naturally sourced Pb to Atlantic surface waters

    NARCIS (Netherlands)

    Bridgestock, L.; van de Flierdt, T.; Rehkämper, M.; Paul, P.; Middag, R.; Milne, A.; Lohan, M.C.; Baker, A.; Chance, R.; Khondoker, R.; Strekopytov, S.; Humphreys-Williams, E.; Achterberg, E.P.; Rijkenberg, M.J.A.; Gerringa, L.J.A.; De Baar, H.J.W.

    2016-01-01

    Anthropogenic emissions completely overwhelmed natural marine lead (Pb) sources duringthe past century, predominantly due to leaded petrol usage. Here, based on Pb isotopemeasurements, we reassess the importance of natural and anthropogenic Pb sources to thetropical North Atlantic following the

  14. Calculation of conversion coefficients of dose of a computational anthropomorphic simulator sit exposed to a plane source

    International Nuclear Information System (INIS)

    Santos, William S.; Carvalho Junior, Alberico B. de; Pereira, Ariana J.S.; Santos, Marcos S.; Maia, Ana F.

    2011-01-01

    In this paper conversion coefficients (CCs) of equivalent dose and effective in terms of kerma in the air were calculated suggested by the ICRP 74. These dose coefficients were calculated considering a plane radiation source and monoenergetic for a spectrum of energy varying from 10 keV to 2 MeV. The CCs were obtained for four geometries of irradiation, anterior-posterior, posterior-anterior, lateral right side and lateral left side. It was used the radiation transport code Visual Monte Carlo (VMC), and a anthropomorphic simulator of sit female voxel. The observed differences in the found values for the CCs at the four irradiation sceneries are direct results of the body organs disposition, and the distance of these organs to the irradiation source. The obtained CCs will be used for estimative more precise of dose in situations that the exposed individual be sit, as the normally the CCs available in the literature were calculated by using simulators always lying or on their feet

  15. Simulated Effects of Land Cover Conversion on the Surface Energy Budget in the Southwest of China

    Directory of Open Access Journals (Sweden)

    Jiangbo Gao

    2014-03-01

    Full Text Available In this paper, the coupled WRF/SSiB model, accompanied by a Karst Rocky Desertification (KRD map of the Guizhou Karst Plateau (GKP of China, was applied to detect how the changed vegetation and soil characteristics over the GKP modify the energy balance at the land surface. The results indicated that land degradation led to reduced net radiation by inducing more upward shortwave and longwave radiation, which were associated with increasing surface albedo and temperature, respectively. The KRD also resulted in changed surface energy partitioning into sensible and latent heat fluxes. The latent heat flux at land surface was reduced substantially due to the higher surface albedo and stomatal resistance, the lower Leaf Area Index (LAI and roughness length in the degradation experiment, while the sensible heat flux increased, mainly because of the higher surface temperature. Furthermore, the moisture flux convergence was reduced, owing to the lower atmospheric heating and the relative subsidence. However, compared with the reduced evaporation, the decrease in moisture flux convergence contributed much less to the reduced precipitation. Precipitation strongly affects soil moisture, vegetation growth and phenology, and thus evaporation and convective latent heating, so when precipitation was changed, a feedback loop was created.

  16. Surface reflectance and conversion efficiency dependence of technologies for mitigating global warming

    Energy Technology Data Exchange (ETDEWEB)

    Edmonds, Ian [Solartran Pty Ltd., 12 Lentara St, Kenmore, Brisbane 4069 (Australia); Smith, Geoff [Physics and Advanced Materials, University of Technology, Sydney, PO Box 123, Broadway, New South Wales 2007 (Australia)

    2011-05-15

    A means of assessing the relative impact of different renewable energy technologies on global warming has been developed. All power plants emit thermal energy to the atmosphere. Fossil fuel power plants also emit CO{sub 2} which accumulates in the atmosphere and provides an indirect increase in global warming via the greenhouse effect. A fossil fuel power plant may operate for some time before the global warming due to its CO{sub 2} emission exceeds the warming due to its direct heat emission. When a renewable energy power plant is deployed instead of a fossil fuel power plant there may be a significant time delay before the direct global warming effect is less than the combined direct and indirect global warming effect from an equivalent output coal fired plant - the ''business as usual'' case. Simple expressions are derived to calculate global temperature change as a function of ground reflectance and conversion efficiency for various types of fossil fuelled and renewable energy power plants. These expressions are used to assess the global warming mitigation potential of some proposed Australian renewable energy projects. The application of the expressions is extended to evaluate the deployment in Australia of current and new geo-engineering and carbon sequestration solutions to mitigate global warming. Principal findings are that warming mitigation depends strongly on the solar to electric conversion efficiency of renewable technologies, geo-engineering projects may offer more economic mitigation than renewable energy projects and the mitigation potential of reforestation projects depends strongly on the location of the projects. (author)

  17. Method for customizing an organic Rankine cycle to a complex heat source for efficient energy conversion, demonstrated on a Fischer Tropsch plant

    International Nuclear Information System (INIS)

    DiGenova, Kevin J.; Botros, Barbara B.; Brisson, J.G.

    2013-01-01

    Highlights: ► Methods for customizing organic Rankine cycles are proposed. ► A set of cycle modifications help to target available heat sources. ► Heat sources with complex temperature–enthalpy profiles can be matched. ► Significant efficiency improvements can be achieved over basic ORC’s. -- Abstract: Organic Rankine cycles (ORCs) provide an alternative to traditional steam Rankine cycles for the conversion of low grade heat sources into power, where conventional steam power cycles are known to be inefficient. A large processing plant often has multiple low temperature waste heat streams available for conversion to electricity by a low temperature cycle, resulting in a composite heat source with a complex temperature–enthalpy profile. This work presents a set of ORC design concepts: reheat stages, multiple pressure levels, and balanced recuperators; and demonstrates the use of these design concepts as building blocks to create a customized cycle that matches an available heat source. Organic fluids are modeled using a pure substance database. The pinch analysis technique of forming composite curves is applied to analyze the effect of each building block on the temperature–enthalpy profile of the ORC heat requirement. The customized cycle is demonstrated on a heat source derived from a Fischer Tropsch reactor and its associated processes. Analysis shows a steam Rankine cycle can achieve a 20.6% conversion efficiency for this heat source, whereas a simple organic Rankine cycle using hexane as the working fluid can achieve a 20.9% conversion efficiency. If the ORC building blocks are combined into a cycle targeted to match the temperature–enthalpy profile of the heat source, this customized ORC can achieve 28.5% conversion efficiency.

  18. Photoenhanced uptakes of NO2 by indoor surfaces: A new HONO source

    Science.gov (United States)

    Gligorovski, S.; Bartolomei, V.; Soergel, M.; Gomez Alvarez, E.; Zetzsch, C.; Wortham, H.

    2012-12-01

    conversion of NO2 to HONO on lacquer surfaces and on white wall paints is substantially enhanced in the presence of light and at higher relative humidity (RH = 60%). In runs carried out applying experimental conditions typically found indoors, i.e., NO2 mixing ratios of 25 ppb and 60% RH%, the observed NO2 uptakes on a surface coated with lacquer and paint showed an enhancement of one order of magnitude in the presence of light as compared to the uptake observed in the dark. Our results indicate, contrary to other study that claimed that humidity does not influence the NO2 reactions with adsorbed organics, that actually both postulated HONO sources combined i.e. heterogeneous NO2 reactions with adsorbed organics (photosensitizers) in presence of elevated humidity leads to even more pronounced HONO production. Reference: 1. M., Sleiman, L. A., Gundel, J. F., Pankow, P., Jacob, B. C., Singer, H., Destaillats, P. Natl. Acad. Sci. USA, 107, 6576 (2010). 2. B. J. Finlayson-Pitts, L. M. Wingen, A. L. Sumner, D. Syomin, K. A. Ramazan, Phys. Chem. Chem. Phys. 5, 223 (2003). 3. K., Stemmler, M., Ammann, C., Donders, J., Kleffmann, C., George, Nature 440, 195 (2006). 4. E. Gomez Alvarez, H. Wortham, R. Strekowski, C. Zetzsch, S. Gligorovski, Environ. Sci. Technol., 46, 1955 (2012).

  19. Engineering Cu surfaces for the electrocatalytic conversion of CO2: Controlling selectivity toward oxygenates and hydrocarbons

    Science.gov (United States)

    Hahn, Christopher; Hatsukade, Toru; Kim, Youn-Geun; Vailionis, Arturas; Baricuatro, Jack H.; Higgins, Drew C.; Nitopi, Stephanie A.; Soriaga, Manuel P.; Jaramillo, Thomas F.

    2017-01-01

    In this study we control the surface structure of Cu thin-film catalysts to probe the relationship between active sites and catalytic activity for the electroreduction of CO2 to fuels and chemicals. Here, we report physical vapor deposition of Cu thin films on large-format (∼6 cm2) single-crystal substrates, and confirm epitaxial growth in the , , and orientations using X-ray pole figures. To understand the relationship between the bulk and surface structures, in situ electrochemical scanning tunneling microscopy was conducted on Cu(100), (111), and (751) thin films. The studies revealed that Cu(100) and (111) have surface adlattices that are identical to the bulk structure, and that Cu(751) has a heterogeneous kinked surface with (110) terraces that is closely related to the bulk structure. Electrochemical CO2 reduction testing showed that whereas both Cu(100) and (751) thin films are more active and selective for C–C coupling than Cu(111), Cu(751) is the most selective for >2e− oxygenate formation at low overpotentials. Our results demonstrate that epitaxy can be used to grow single-crystal analogous materials as large-format electrodes that provide insights on controlling electrocatalytic activity and selectivity for this reaction. PMID:28533377

  20. Cooptimization of Adhesion and Power Conversion Efficiency of Organic Solar Cells by Controlling Surface Energy of Buffer Layers.

    Science.gov (United States)

    Lee, Inhwa; Noh, Jonghyeon; Lee, Jung-Yong; Kim, Taek-Soo

    2017-10-25

    Here, we demonstrate the cooptimization of the interfacial fracture energy and power conversion efficiency (PCE) of poly[N-9'-heptadecanyl-2,7-carbazole-alt-5,5-(4',7'-di-2-thienyl-2',1',3'-benzothiadiazole)] (PCDTBT)-based organic solar cells (OSCs) by surface treatments of the buffer layer. The investigated surface treatments of the buffer layer simultaneously changed the crack path and interfacial fracture energy of OSCs under mechanical stress and the work function of the buffer layer. To investigate the effects of surface treatments, the work of adhesion values were calculated and matched with the experimental results based on the Owens-Wendt model. Subsequently, we fabricated OSCs on surface-treated buffer layers. In particular, ZnO layers treated with poly[(9,9-bis(3'-(N,N-dimethylamino)propyl)-2,7-fluorene)-alt-2,7-(9,9-dioctylfluorene)] (PFN) simultaneously satisfied the high mechanical reliability and PCE of OSCs by achieving high work of adhesion and optimized work function.

  1. Conversion of a Surface Model of a Structure of Interest into a Volume Model for Medical Image Retrieval

    Directory of Open Access Journals (Sweden)

    Sarmad ISTEPHAN

    2015-06-01

    Full Text Available Volumetric medical image datasets contain vital information for noninvasive diagnosis, treatment planning and prognosis. However, direct and unlimited query of such datasets is hindered due to the unstructured nature of the imaging data. This study is a step towards the unlimited query of medical image datasets by focusing on specific Structures of Interest (SOI. A requirement in achieving this objective is having both the surface and volume models of the SOI. However, typically, only the surface model is available. Therefore, this study focuses on creating a fast method to convert a surface model to a volume model. Three methods (1D, 2D and 3D are proposed and evaluated using simulated and real data of Deep Perisylvian Area (DPSA within the human brain. The 1D method takes 80 msec for DPSA model; about 4 times faster than 2D method and 7.4 fold faster than 3D method, with over 97% accuracy. The proposed 1D method is feasible for surface to volume conversion in computer aided diagnosis, treatment planning and prognosis systems containing large amounts of unstructured medical images.

  2. Front Surface Tandem Filters using Sapphire (Al2O3) Substrates for Spectral Control in thermophotovoltaic Energy Conversion Systems

    International Nuclear Information System (INIS)

    T Rahmlow, Jr.; J Lazo-Wasem; E Gratrix; P Fourspring; D DePoy

    2005-01-01

    Front surface filters provide an effective means of improving thermophotovoltaic (TPV) system efficiency through spectral control of incident radiant energy. A front surface filter reflects the below band gap photons that can not be converted by the TPV cell back towards the high temperature radiator and allows convertible above band gap photons to pass through the filter into the TPV cell for conversion to electricity. The best spectral control efficiency to date has been demonstrated by front surface, tandem filters that combine an interference filter and an InPAs layer (plasma filter) in series. The InPAs material is a highly doped, epitaxially grown layer on an InP substrate. These tandem filter designs have been fabricated with energy and angle weighted spectral efficiencies of 76% for TPV cells with a 2.08(micro)m (0.6eV) band gap [1]. An alternative to the InPAs layer on an InP substrate is an Al 2 O 3 (sapphire) substrate. The use of Al 2 O 3 may increase transmission of above band gap photons, increase the mechanical strength of the tandem filter, and lower the cost of the tandem filter, all at the expense of lower spectral efficiency. This study presents design and fabrication results for front surface tandem filters that use an Al 2 O 3 substrate for 2.08(micro)m band gap TPV cells

  3. Fecal Contamination in the Surface Waters of a Rural- and an Urban-Source Watershed

    DEFF Research Database (Denmark)

    Stea, Emma C.; Hansen, Lisbeth Truelstrup; Jamieson, Rob C.

    2015-01-01

    Surface waters are commonly used as source water for drinking water and irrigation. Knowledge of sources of fecal pollution in source watersheds benefits the design of effective source water protection plans. This study analyzed the relationships between enteric pathogens (Escherichia coli O157:H...

  4. Surface tension and wetting properties of rapeseed oil to biofuel conversion by-products

    Science.gov (United States)

    Muszyński, Siemowit; Sujak, Agnieszka; Stępniewski, Andrzej; Kornarzyński, Krzysztof; Ejtel, Marta; Kowal, Natalia; Tomczyk-Warunek, Agnieszka; Szcześniak, Emil; Tomczyńska-Mleko, Marta; Mleko, Stanisław

    2018-04-01

    This work presents a study on the surface tension, density and wetting behaviour of distilled glycerol, technical grade glycerol and the matter organic non-glycerin fraction. The research was conducted to expand the knowledge about the physical properties of wastes from the rapeseed oil biofuel production. The results show that the densities of technical grade glycerol (1.300 g cm-3) and distilled glycerol (1.267 g cm-3) did not differ and were significantly lower than the density of the matter organic non-glycerin fraction (1.579 g cm-3). Furthermore, the surface tension of distilled glycerol (49.6 mN m-1) was significantly higher than the matter organic non-glycerin fraction (32.7 mN m-1) and technical grade glycerol (29.5 mN m-1). As a result, both technical grade glycerol and the matter organic non-glycerin fraction had lower contact angles than distilled glycerol. The examined physical properties of distilled glycerol were found to be very close to that of the commercially available pure glycerol. The results suggest that technical grade glycerol may have potential application in the production of glycerol/fuel blends or biosurfactants. The presented results indicate that surface tension measurements are more useful when examining the quality of biofuel wastes than is density determination, as they allow for a more accurate analysis of the effects of impurities on the physical properties of the biofuel by-products.

  5. Improving energy conversion efficiency for triboelectric nanogenerator with capacitor structure by maximizing surface charge density.

    Science.gov (United States)

    He, Xianming; Guo, Hengyu; Yue, Xule; Gao, Jun; Xi, Yi; Hu, Chenguo

    2015-02-07

    Nanogenerators with capacitor structures based on piezoelectricity, pyroelectricity, triboelectricity and electrostatic induction have been extensively investigated. Although the electron flow on electrodes is well understood, the maximum efficiency-dependent structure design is not clearly known. In this paper, a clear understanding of triboelectric generators with capacitor structures is presented by the investigation of polydimethylsiloxane-based composite film nanogenerators, indicating that the generator, in fact, acts as both an energy storage and output device. Maximum energy storage and output depend on the maximum charge density on the dielectric polymer surface, which is determined by the capacitance of the device. The effective thickness of polydimethylsiloxane can be greatly reduced by mixing a suitable amount of conductive nanoparticles into the polymer, through which the charge density on the polymer surface can be greatly increased. This finding can be applied to all the triboelectric nanogenerators with capacitor structures, and it provides an important guide to the structural design for nanogenerators. It is demonstrated that graphite particles with sizes of 20-40 nm and 3.0% mass mixed into the polydimethylsiloxane can reduce 34.68% of the effective thickness of the dielectric film and increase the surface charges by 111.27% on the dielectric film. The output power density of the triboelectric nanogenerator with the composite polydimethylsiloxane film is 3.7 W m(-2), which is 2.6 times as much as that of the pure polydimethylsiloxane film.

  6. Efficient cesiation in RF driven surface plasma negative ion source

    Energy Technology Data Exchange (ETDEWEB)

    Belchenko, Yu.; Ivanov, A.; Konstantinov, S.; Sanin, A., E-mail: sanin@inp.nsk.su; Sotnikov, O. [Budker Institute of Nuclear Physics, Siberian Branch of Russian Academy of Sciences, Novosibirsk (Russian Federation)

    2016-02-15

    Experiments on hydrogen negative ions production in the large radio-frequency negative ion source with cesium seed are described. The system of directed cesium deposition to the plasma grid periphery was used. The small cesium seed (∼0.5 G) provides an enhanced H{sup −} production during a 2 month long experimental cycle. The gradual increase of negative ion yield during the long-term source runs was observed after cesium addition to the source. The degraded H{sup −} production was recorded after air filling to the source or after the cesium washing away from the driver and plasma chamber walls. The following source conditioning by beam shots produces the gradual recovery of H{sup −} yield to the high value. The effect of H{sup −} yield recovery after cesium coverage passivation by air fill was studied. The concept of cesium coverage replenishment and of H{sup −} yield recovery due to sputtering of cesium from the deteriorated layers is discussed.

  7. Using radiometric surface temperature for surface energy flux estimation in Mediterranean drylands from a two-source perspective

    DEFF Research Database (Denmark)

    Morillas, L.; Garcia Garcia, Monica; Nieto Solana, Hector

    2013-01-01

    A two-source model (TSM) for surface energy balance, considering explicitly soil and vegetation components, was tested under water stress conditions. The TSM evaluated estimates the sensible heat flux (H) using the surface-air thermal gradient and the latent heat flux (LE) as a residual from the ...

  8. Functionalization of the hydroxyapatite nanoparticles surface: source of new applications

    International Nuclear Information System (INIS)

    Rojas Sanchez, Leonardo

    2012-01-01

    The surface of the nano-calcium hydroxyapatite, Ca 10 (PO 4 ) 6 (OH) 2 is reacted with stearic acid, succinic anhydride, succinimide and 2 a minoetil dihydrogenphosphate. Introduction of different functional groups is given onto the surface. An ionic interaction is identified by infrared spectroscopy and Raman between the carboxylate groups of the resulting organic molecules and calcium of the hydroxyapatite. The formation of a P-O-P pyrophosphate type bond has been for 2-aminoethyl dihydrogen phosphate with hydroxyapatite groups. Hydroxyapatite phase was remained in all cases after the reaction as demonstrated by diffraction of x-ray in powder. The amount of spiked molecules is quantified by analysis of thermal degradation which together with the determination of the surface area by BET isotherms of nitrogen adsorption. A degree of surface coverage is estimated by the organic molecules. A maximum percentage of 71% is obtained for the functionalization with succinic anhydride, followed by 57% for the reaction with stearic acid. Dilute suspensions of different materials were prepared for which in phosphate buffer solution have presented two populations around 2 and 5 μm in diameter for the modified particles. The ζ-Potential of various materials was determined occurring a variation in the potential of the unmodified hydroxyapatite. The particles with physicochemical properties different of the starting hydroxyapatite were obtained, this has expanded the range of application of the material. (author) [es

  9. Exact solution to surface displacement associated with sources ...

    African Journals Online (AJOL)

    user

    International Journal of Engineering, Science and Technology. Vol. 3, No.2 ... The z-axis is perpendicular to the free surface and directed inside the half ...... Pulse Generation in an Elastic Half space by Normal Pressure, International Journal of ...

  10. Surface fields on the source-excited dielectric wedge

    DEFF Research Database (Denmark)

    Balling, P

    1973-01-01

    Approximate surface fields due to a plane-wave solution and a local-mode solution are compared. The plane-wave solution, which is new, is shown to agree well with experiment. The local-mode solution, which often has been applied to tapered waveguides and antennas, fails near the cutoffs of the su...

  11. CONTAIN code calculations of the effects on the source term of CsI to I/sub 2/ conversion due to severe hydrogen burns

    International Nuclear Information System (INIS)

    Valdez, G.D.; Williams, D.C.

    1986-01-01

    In experiments conducted at Sandia National Laboratories large amounts of elemental iodine were produced when CsI-Al 2 O 3 aerosol was exposed to hydrogen/air combustion. To evaluate some of the implications of the iodide conversion (observed to occur with up to 75% efficiency) for the severe accident source term, computational simulations of representative accident sequences were conducted with the CONTAIN code. The following conclusions can be drawn from this preliminary source term assessment: (1) If the containment sprays are inoperative during the accident, or failed by the hydrogen burn, the late-time source term is almost tripled when the iodide is converted to I 2 . (2) With the sprays active, the amount released without conversion of the CsI aerosol is 63% higher than for the case when conversion occurs. (3) For the case where CsI is converted to I 2 continued operation of the sprays reduces the release by a factor of 40, relative to the case in which the sprays fail at the time of the hydrogen burn. When there is no conversion, the reduction factor for continued spray operation is about a factor of 9, relative to the failed spray case

  12. Monochromator on a synchrotron undulator source for liquid surface studies

    DEFF Research Database (Denmark)

    Als-Nielsen, Jens Aage; Freund, A.K.

    1992-01-01

    For liquid surface studies a monochromatic beam of relative bandwidth between 0.1% and 1% at a variable angle in the vertical plane between 0-degrees and 10-degrees is needed. The beam should be like a sheet some tens of mu-m thick and some mm wide, and as intense as possible. We discuss a monoch......For liquid surface studies a monochromatic beam of relative bandwidth between 0.1% and 1% at a variable angle in the vertical plane between 0-degrees and 10-degrees is needed. The beam should be like a sheet some tens of mu-m thick and some mm wide, and as intense as possible. We discuss......% of the useful x rays, in full agreement with diffraction theory including secondary extinction. Heat load experiments reported elsewhere in this conference prove that Be crystals can withstand high beam power density and that the thermal deformation is small compared to the mosaic spread. The results...... of the flux calculations are most encouraging: a gain of order 10(3) to 10(4) can be expected as compared to existing liquid surface spectrometers....

  13. Iterated multidimensional wave conversion

    International Nuclear Information System (INIS)

    Brizard, A. J.; Tracy, E. R.; Johnston, D.; Kaufman, A. N.; Richardson, A. S.; Zobin, N.

    2011-01-01

    Mode conversion can occur repeatedly in a two-dimensional cavity (e.g., the poloidal cross section of an axisymmetric tokamak). We report on two novel concepts that allow for a complete and global visualization of the ray evolution under iterated conversions. First, iterated conversion is discussed in terms of ray-induced maps from the two-dimensional conversion surface to itself (which can be visualized in terms of three-dimensional rooms). Second, the two-dimensional conversion surface is shown to possess a symplectic structure derived from Dirac constraints associated with the two dispersion surfaces of the interacting waves.

  14. Verification of surface source's characteristics using large-area 2π gas flow counter

    International Nuclear Information System (INIS)

    Abu Naser Waheed, M.M.; Mikami, S.; Kobayashi, H.; Noda, K.

    1998-09-01

    Power Reactor and Nuclear Fuel Development Corporation (PNC) has large-area 2π gas flow counter for the purpose of measuring activity of surface sources of alpha or beta ray emitter. Surface sources are used for the calibration of radiation measuring equipment for radiation control. Due to sequent use of sources, the surface of these sources are inclined to go in bad condition because of unwanted accidental incidents. For the better calibration achievement of radiation measuring instruments the rate of emission of these sources are to be checked periodically by the large-area 2π gas flow counter. In this paper described that eight U 3 O 8 surface sources were selected from many sources of PNC Tokai Works and activity of these sources was measured by the 2π gas flow counter. The results were compared with the values certified by Japan Radio Isotope Association (JRIA). It is evident from the result of comparison that the surface sources are in good condition, i.e., the sources are reliable to calibrate the radiation control instruments. (author)

  15. Highly Efficient Spin-to-Charge Current Conversion in Strained HgTe Surface States Protected by a HgCdTe Layer

    Science.gov (United States)

    Noel, P.; Thomas, C.; Fu, Y.; Vila, L.; Haas, B.; Jouneau, P.-H.; Gambarelli, S.; Meunier, T.; Ballet, P.; Attané, J. P.

    2018-04-01

    We report the observation of spin-to-charge current conversion in strained mercury telluride at room temperature, using spin pumping experiments. We show that a HgCdTe barrier can be used to protect the HgTe from direct contact with the ferromagnet, leading to very high conversion rates, with inverse Edelstein lengths up to 2.0 ±0.5 nm . The influence of the HgTe layer thickness on the conversion efficiency is found to differ strongly from what is expected in spin Hall effect systems. These measurements, associated with the temperature dependence of the resistivity, suggest that these high conversion rates are due to the spin momentum locking property of HgTe surface states.

  16. Study on surface modification of polymer films by using atmospheric plasma jet source

    International Nuclear Information System (INIS)

    Takemura, Yuichiro; Hara, Tamio; Yamaguchi, Naohiro

    2008-01-01

    Reactive gas plasma treatments of poly(ethylene terephthalate) (PET) and polyimide (Kapton) have been performed using an atmospheric plasmas jet source. Characteristics of surface modification have been examined by changing the distance between the plasma jet source and the treated sample, and by changing the working gas spaces. Simultaneously, each plasma jet source has been investigated by space-resolving spectroscopy in the UV/visible region. Polymer surfaces have been analyzed by X-ray photoelectron spectroscopy (XPS). A marked improvement in the hydrophilicity of the polymer surfaces has been made by using N 2 or O 2 plasma jet source with a very short exposure time of about 0.01 s, whereas the less improvement has been obtained using on air plasma jet source because of NO x compound production. Changes in the chemical states of C of the polymer surfaces have been observed in XPS spectra after N 2 plasma jet spraying. (author)

  17. Negative ion surface plasma source development for plasma trap injectors in Novosibirsk

    International Nuclear Information System (INIS)

    Bel'chenko, Yu.I.; Dimov, G.I.; Dudnikov, V.G.; Kupriyanov, A.S.

    1989-01-01

    Work on high-current ion sources carried out at the Novosibirsk Institute of Nuclear Physics (INP) is presented. The INP investigations on ''pure plasma'' planotron and ''pure surface'' secondary emission systems of H - generation, which preceded the surface-plasma concept developed in Novosibirsk, are described. The physical basis of the surface-plasma method of negative-ion production is considered. The versions and operating characteristics of different surface-plasma sources including the multi-ampere (approx-gt 10A) source are discussed. Research on efficient large-area (∼10 2 cm 2 ) negative ion surface-plasma emitters is described. The INP long-pulse multiaperture surface- plasma generators, with a current of about 1A, are described. 38 refs., 17 figs

  18. Interferometry with flexible point source array for measuring complex freeform surface and its design algorithm

    Science.gov (United States)

    Li, Jia; Shen, Hua; Zhu, Rihong; Gao, Jinming; Sun, Yue; Wang, Jinsong; Li, Bo

    2018-06-01

    The precision of the measurements of aspheric and freeform surfaces remains the primary factor restrict their manufacture and application. One effective means of measuring such surfaces involves using reference or probe beams with angle modulation, such as tilted-wave-interferometer (TWI). It is necessary to improve the measurement efficiency by obtaining the optimum point source array for different pieces before TWI measurements. For purpose of forming a point source array based on the gradients of different surfaces under test, we established a mathematical model describing the relationship between the point source array and the test surface. However, the optimal point sources are irregularly distributed. In order to achieve a flexible point source array according to the gradient of test surface, a novel interference setup using fiber array is proposed in which every point source can be independently controlled on and off. Simulations and the actual measurement examples of two different surfaces are given in this paper to verify the mathematical model. Finally, we performed an experiment of testing an off-axis ellipsoidal surface that proved the validity of the proposed interference system.

  19. SWRT: A package for semi-analytical solutions of surface wave propagation, including mode conversion, across transversely aligned vertical discontinuities

    Science.gov (United States)

    Datta, Arjun

    2018-03-01

    We present a suite of programs that implement decades-old algorithms for computation of seismic surface wave reflection and transmission coefficients at a welded contact between two laterally homogeneous quarter-spaces. For Love as well as Rayleigh waves, the algorithms are shown to be capable of modelling multiple mode conversions at a lateral discontinuity, which was not shown in the original publications or in the subsequent literature. Only normal incidence at a lateral boundary is considered so there is no Love-Rayleigh coupling, but incidence of any mode and coupling to any (other) mode can be handled. The code is written in Python and makes use of SciPy's Simpson's rule integrator and NumPy's linear algebra solver for its core functionality. Transmission-side results from this code are found to be in good agreement with those from finite-difference simulations. In today's research environment of extensive computing power, the coded algorithms are arguably redundant but SWRT can be used as a valuable testing tool for the ever evolving numerical solvers of seismic wave propagation. SWRT is available via GitHub (https://github.com/arjundatta23/SWRT.git).

  20. SWRT: A package for semi-analytical solutions of surface wave propagation, including mode conversion, across transversely aligned vertical discontinuities

    Directory of Open Access Journals (Sweden)

    A. Datta

    2018-03-01

    Full Text Available We present a suite of programs that implement decades-old algorithms for computation of seismic surface wave reflection and transmission coefficients at a welded contact between two laterally homogeneous quarter-spaces. For Love as well as Rayleigh waves, the algorithms are shown to be capable of modelling multiple mode conversions at a lateral discontinuity, which was not shown in the original publications or in the subsequent literature. Only normal incidence at a lateral boundary is considered so there is no Love–Rayleigh coupling, but incidence of any mode and coupling to any (other mode can be handled. The code is written in Python and makes use of SciPy's Simpson's rule integrator and NumPy's linear algebra solver for its core functionality. Transmission-side results from this code are found to be in good agreement with those from finite-difference simulations. In today's research environment of extensive computing power, the coded algorithms are arguably redundant but SWRT can be used as a valuable testing tool for the ever evolving numerical solvers of seismic wave propagation. SWRT is available via GitHub (https://github.com/arjundatta23/SWRT.git.

  1. Thermodynamics and kinetics of reduction and species conversion at a hydrophobic surface for mitochondrial cytochromes c and their cardiolipin adducts

    International Nuclear Information System (INIS)

    Ranieri, Antonio; Di Rocco, Giulia; Millo, Diego; Battistuzzi, Gianantonio; Bortolotti, Carlo A.; Lancellotti, Lidia; Borsari, Marco; Sola, Marco

    2015-01-01

    Highlights: • Cytochrome c and its adduct with cardiolipin can be immobilized on a hydrophobic SAM. • Adsorbed cytochrome c and its adduct undergo extensive unfolding and axial ligand substitution. • An equilibrium between a six-coordinated and a five-coordinated form is observed in both cases. • The reduced five-coordinated form is stabilized by cardiolipin binding. • Immobilized cytochrome c exchanges electrons more slowly upon cardiolipin binding. - Abstract: Cytochrome c (cytc) and its adduct with cardiolipin (CL) were immobilized on a hydrophobic SAM-coated electrode surface yielding a construct which mimics the environment experienced by the complex at the inner mitochondrial membrane where it plays a role in cell apoptosis. Under these conditions, both species undergo an equilibrium between a six-coordinated His/His-ligated and a five-coordinated His/- ligated forms stable in the oxidized and in the reduced state, respectively. The thermodynamics of the oxidation-state dependent species conversion were determined by temperature-dependent diffusionless voltammetry experiments. CL binding stabilizes the immobilized reduced His/- ligated form of cytc which was found previously to catalytically reduce dioxygen. Here, this adduct is also found to show pseudoperoxidase activity, catalysing reduction of hydrogen peroxide. These effects would impart CL with an additional role in the cytc-mediated peroxidation leading to programmed cell death. Moreover, immobilized cytc exchanges electrons more slowly upon CL binding possibly due to changes in solvent reorganization effects at the protein-SAM interface

  2. Natural Conversations as a Source of False Memories in Children: Implications for the Testimony of Young Witnesses

    Science.gov (United States)

    Principe, Gabrielle F.; Schindewolf, Erica

    2012-01-01

    Research on factors that can affect the accuracy of children’s autobiographical remembering has important implications for understanding the abilities of young witnesses to provide legal testimony. In this article, we review our own recent research on one factor that has much potential to induce errors in children’s event recall, namely natural memory sharing conversations with peers and parents. Our studies provide compelling evidence that not only can the content of conversations about the past intrude into later memory but that such exchanges can prompt the generation of entirely false narratives that are more detailed than true accounts of experienced events. Further, our work show that deeper and more creative participation in memory sharing dialogues can boost the damaging effects of conversationally conveyed misinformation. Implications of this collection of findings for children’s testimony are discussed. PMID:23129880

  3. Combustion-based power source for Venus surface missions

    Science.gov (United States)

    Miller, Timothy F.; Paul, Michael V.; Oleson, Steven R.

    2016-10-01

    The National Research Council has identified in situ exploration of Venus as an important mission for the coming decade of NASA's exploration of our solar system (Squyers, 2013 [1]). Heavy cloud cover makes the use of solar photovoltaics extremely problematic for power generation for Venus surface missions. In this paper, we propose a class of planetary exploration missions (for use on Venus and elsewhere) in solar-deprived situations where photovoltaics cannot be used, batteries do not provide sufficient specific energy and mission duration, and nuclear systems may be too costly or complex to justify or simply unavailable. Metal-fueled, combustion-based powerplants have been demonstrated for application in the terrestrial undersea environment. Modified or extended versions of the undersea-based systems may be appropriate for these sunless missions. We describe systems carrying lithium fuel and sulfur-hexafluoride oxidizer that have the potential for many days of operation in the sunless craters of the moon. On Venus a system level specific energy of 240 to 370 We-hr/kg should be possible if the oxidizer is brought from earth. By using either lithium or a magnesium-based alloy fuel, it may be possible to operate a similar system with CO2 derived directly from the Venus atmosphere, thus providing an estimated system specific energy of 1100 We+PV-hr/kg (the subscript refers to both electrical and mechanical power), thereby providing mission durations that enable useful scientific investigation. The results of an analysis performed by the NASA Glenn COMPASS team describe a mission operating at 2.3 kWe+PV for 5 days (120 h), with less than 260 kg power/energy system mass total. This lander would be of a size and cost suitable for a New Frontiers class of mission.

  4. Elements of energy conversion

    CERN Document Server

    Russell, Charles R

    2013-01-01

    Elements of Energy Conversion brings together scattered information on the subject of energy conversion and presents it in terms of the fundamental thermodynamics that apply to energy conversion by any process. Emphasis is given to the development of the theory of heat engines because these are and will remain most important power sources. Descriptive material is then presented to provide elementary information on all important energy conversion devices. The book contains 10 chapters and opens with a discussion of forms of energy, energy sources and storage, and energy conversion. This is foll

  5. Volatile organic compound conversion by ozone, hydroxyl radicals, and nitrate radicals in residential indoor air: Magnitudes and impacts of oxidant sources

    Science.gov (United States)

    Waring, Michael S.; Wells, J. Raymond

    2015-04-01

    Indoor chemistry may be initiated by reactions of ozone (O3), the hydroxyl radical (OH), or the nitrate radical (NO3) with volatile organic compounds (VOC). The principal indoor source of O3 is air exchange, while OH and NO3 formation are considered as primarily from O3 reactions with alkenes and nitrogen dioxide (NO2), respectively. Herein, we used time-averaged models for residences to predict O3, OH, and NO3 concentrations and their impacts on conversion of typical residential VOC profiles, within a Monte Carlo framework that varied inputs probabilistically. We accounted for established oxidant sources, as well as explored the importance of two newly realized indoor sources: (i) the photolysis of nitrous acid (HONO) indoors to generate OH and (ii) the reaction of stabilized Criegee intermediates (SCI) with NO2 to generate NO3. We found total VOC conversion to be dominated by reactions both with O3, which almost solely reacted with D-limonene, and also with OH, which reacted with D-limonene, other terpenes, alcohols, aldehydes, and aromatics. VOC oxidation rates increased with air exchange, outdoor O3, NO2 and D-limonene sources, and indoor photolysis rates; and they decreased with O3 deposition and nitric oxide (NO) sources. Photolysis was a strong OH formation mechanism for high NO, NO2, and HONO settings, but SCI/NO2 reactions weakly generated NO3 except for only a few cases.

  6. Derivation of pulse height to exposure rate conversion functions for aerial radiological surveys

    International Nuclear Information System (INIS)

    Artuso, J.F.

    1985-01-01

    A method is described for deriving conversion functions that can be used to convert pulse height spectra taken at altitude to the exposure rate at the 1-m level. An integral equation is set up which involves the integration of a calculated pulse height spectrum multiplied by an unknown conversion function and then set equal to the exposure rate at ground level. This equation is then solved for the conversion function by assuming as a solution a three-term polynomial. Conversion functions have been derived for various source distributions, including surface, uniform, and exponentially distributed sources. These conversion functions are independent of source energy, which means that a conversion can be made without any knowledge of the isotopic content of the source. In the case of a uniform distribution, these conversion functions provide conversions that agree to within 10% with ground truth measurements

  7. Bacterial community diversity and variation in spray water sources and the tomato fruit surface.

    Science.gov (United States)

    Telias, Adriana; White, James R; Pahl, Donna M; Ottesen, Andrea R; Walsh, Christopher S

    2011-04-21

    Tomato (Solanum lycopersicum) consumption has been one of the most common causes of produce-associated salmonellosis in the United States. Contamination may originate from animal waste, insects, soil or water. Current guidelines for fresh tomato production recommend the use of potable water for applications coming in direct contact with the fruit, but due to high demand, water from other sources is frequently used. We sought to describe the overall bacterial diversity on the surface of tomato fruit and the effect of two different water sources (ground and surface water) when used for direct crop applications by generating a 454-pyrosequencing 16S rRNA dataset of these different environments. This study represents the first in depth characterization of bacterial communities in the tomato fruit surface and the water sources commonly used in commercial vegetable production. The two water sources tested had a significantly different bacterial composition. Proteobacteria was predominant in groundwater samples, whereas in the significantly more diverse surface water, abundant phyla also included Firmicutes, Actinobacteria and Verrucomicrobia. The fruit surface bacterial communities on tomatoes sprayed with both water sources could not be differentiated using various statistical methods. Both fruit surface environments had a high representation of Gammaproteobacteria, and within this class the genera Pantoea and Enterobacter were the most abundant. Despite the major differences observed in the bacterial composition of ground and surface water, the season long use of these very different water sources did not have a significant impact on the bacterial composition of the tomato fruit surface. This study has provided the first next-generation sequencing database describing the bacterial communities living in the fruit surface of a tomato crop under two different spray water regimes, and therefore represents an important step forward towards the development of science

  8. Bacterial community diversity and variation in spray water sources and the tomato fruit surface

    Directory of Open Access Journals (Sweden)

    Ottesen Andrea R

    2011-04-01

    Full Text Available Abstract Background Tomato (Solanum lycopersicum consumption has been one of the most common causes of produce-associated salmonellosis in the United States. Contamination may originate from animal waste, insects, soil or water. Current guidelines for fresh tomato production recommend the use of potable water for applications coming in direct contact with the fruit, but due to high demand, water from other sources is frequently used. We sought to describe the overall bacterial diversity on the surface of tomato fruit and the effect of two different water sources (ground and surface water when used for direct crop applications by generating a 454-pyrosequencing 16S rRNA dataset of these different environments. This study represents the first in depth characterization of bacterial communities in the tomato fruit surface and the water sources commonly used in commercial vegetable production. Results The two water sources tested had a significantly different bacterial composition. Proteobacteria was predominant in groundwater samples, whereas in the significantly more diverse surface water, abundant phyla also included Firmicutes, Actinobacteria and Verrucomicrobia. The fruit surface bacterial communities on tomatoes sprayed with both water sources could not be differentiated using various statistical methods. Both fruit surface environments had a high representation of Gammaproteobacteria, and within this class the genera Pantoea and Enterobacter were the most abundant. Conclusions Despite the major differences observed in the bacterial composition of ground and surface water, the season long use of these very different water sources did not have a significant impact on the bacterial composition of the tomato fruit surface. This study has provided the first next-generation sequencing database describing the bacterial communities living in the fruit surface of a tomato crop under two different spray water regimes, and therefore represents an

  9. The surface oxide as a source of oxygen on Rh(1 1 1)

    Energy Technology Data Exchange (ETDEWEB)

    Lundgren, E. [Department of Synchrotron Radiation Research, Institute of Physics, Lund University, Box 118, S-221 00 Lund (Sweden)]. E-mail: edvin.lundgren@sljus.lu.se; Gustafson, J. [Department of Synchrotron Radiation Research, Institute of Physics, Lund University, Box 118, S-221 00 Lund (Sweden); Resta, A. [Department of Synchrotron Radiation Research, Institute of Physics, Lund University, Box 118, S-221 00 Lund (Sweden); Weissenrieder, J. [Department of Synchrotron Radiation Research, Institute of Physics, Lund University, Box 118, S-221 00 Lund (Sweden); Mikkelsen, A. [Department of Synchrotron Radiation Research, Institute of Physics, Lund University, Box 118, S-221 00 Lund (Sweden); Andersen, J.N. [Department of Synchrotron Radiation Research, Institute of Physics, Lund University, Box 118, S-221 00 Lund (Sweden); Koehler, L. [Institut fuer Materialphysik and Centre for Computational Materials Science, Universitaet Wien, A-1090 Vienna (Austria); Kresse, G. [Institut fuer Materialphysik and Centre for Computational Materials Science, Universitaet Wien, A-1090 Vienna (Austria); Klikovits, J. [Institut fuer Allgemeine Physik, Technische Universitaet Wien, A-1040 Vienna (Austria); Biederman, A. [Institut fuer Allgemeine Physik, Technische Universitaet Wien, A-1040 Vienna (Austria); Schmid, M. [Institut fuer Allgemeine Physik, Technische Universitaet Wien, A-1040 Vienna (Austria); Varga, P. [Institut fuer Allgemeine Physik, Technische Universitaet Wien, A-1040 Vienna (Austria)

    2005-06-15

    The reduction of a thin surface oxide on the Rh(1 1 1) surface by CO is studied in situ by photoemission spectroscopy, scanning tunneling microscopy, and density functional theory. CO molecules are found not to adsorb on the surface oxide at a sample temperature of 100 K, in contrast to on the clean and chemisorbed oxygen covered surface. Despite this behavior, the surface oxide may still be reduced by CO, albeit in a significantly different fashion as compared to the reduction of a phase containing only chemisorbed on surface oxygen. The experimental observations combined with theoretical considerations concerning the stability of the surface oxide, result in a model of the reduction process at these pressures suggesting that the surface oxide behaves as a source of oxygen for the CO-oxidation reaction.

  10. Rapid Surface Oxidation as a Source of Surface Degradation Factor for Bi 2 Se 3

    KAUST Repository

    Kong, Desheng

    2011-06-28

    Bismuth selenide (Bi2Se3) is a topological insulator with metallic surface states (SS) residing in a large bulk bandgap. In experiments, synthesized Bi2Se3 is often heavily n-type doped due to selenium vacancies. Furthermore, it is discovered from experiments on bulk single crystals that Bi2Se3 gets additional n-type doping after exposure to the atmosphere, thereby reducing the relative contribution of SS in total conductivity. In this article, transport measurements on Bi2Se3 nanoribbons provide additional evidence of such environmental doping process. Systematic surface composition analyses by X-ray photoelectron spectroscopy reveal fast formation and continuous growth of native oxide on Bi2Se3 under ambient conditions. In addition to n-type doping at the surface, such surface oxidation is likely the material origin of the degradation of topological SS. Appropriate surface passivation or encapsulation may be required to probe topological SS of Bi2Se3 by transport measurements. © 2011 American Chemical Society.

  11. Electrochemical, interfacial, and surface studies of the conversion of carbon dioxide to liquid fuels on tin electrodes

    Science.gov (United States)

    Wu, Jingjie

    The electrochemical reduction of carbon dioxide (CO2) into liquid fuels especially coupling with the intermittent renewable electricity offers a promising means of storing electricity in chemical form, which reduces the dependence on fossil fuels and mitigates the negative impact of anthropogenic CO2 emissions on the planet. Although converting CO2 to fuels is not in itself a new concept, the field has not substantially advanced in the last 30 years primarily because of the challenge of discovery of structural electrocatalysts and the development of membrane architectures for efficient collection of reactants and separation of products. An efficient catalyst for the electrochemical conversion of CO2 to fuels must be capable of mediating a proton-coupled electron transfer reaction at low overpotentials, reducing CO2 in the presence of water, selectively converting CO 2 to desirable chemicals, and sustaining long-term operations (Chapter 1). My Ph.D. research was an investigation of the electroreduction of CO2 on tin-based electrodes and development of an electrochemical cell to convert CO2 to liquid fuels. The initial study focused on understanding the CO2 reduction reaction chemistry in the electrical double layer with an emphasis on the effects of electrostatic adsorption of cations, specific adsorption of anion and electrolyte concentration on the potential and proton concentration at outer Helmholtz plane at which reduction reaction occurs. The variation of potential and proton concentration at outer Helmholtz plane accounts for the difference in activity and selectivity towards CO2 reduction when using different electrolytes (Chapter 2). Central to the highly efficient CO2 reduction is an optimum microstructure of catalyst layer in the Sn gas diffusion electrode (GDE) consisting of 100 nm Sn nanoparticles to facilitate gas diffusion and charge transfer. This microstructure in terms of the proton conductor fraction and catalyst layer thickness was optimized to

  12. Rapid Surface Oxidation as a Source of Surface Degradation Factor for Bi 2 Se 3

    KAUST Repository

    Kong, Desheng; Cha, Judy J.; Lai, Keji; Peng, Hailin; Analytis, James G.; Meister, Stefan; Chen, Yulin; Zhang, Hai-Jun; Fisher, Ian R.; Shen, Zhi-Xun; Cui, Yi

    2011-01-01

    Bismuth selenide (Bi2Se3) is a topological insulator with metallic surface states (SS) residing in a large bulk bandgap. In experiments, synthesized Bi2Se3 is often heavily n-type doped due to selenium vacancies. Furthermore, it is discovered from

  13. A One-Source Approach for Estimating Land Surface Heat Fluxes Using Remotely Sensed Land Surface Temperature

    Directory of Open Access Journals (Sweden)

    Yongmin Yang

    2017-01-01

    Full Text Available The partitioning of available energy between sensible heat and latent heat is important for precise water resources planning and management in the context of global climate change. Land surface temperature (LST is a key variable in energy balance process and remotely sensed LST is widely used for estimating surface heat fluxes at regional scale. However, the inequality between LST and aerodynamic surface temperature (Taero poses a great challenge for regional heat fluxes estimation in one-source energy balance models. To address this issue, we proposed a One-Source Model for Land (OSML to estimate regional surface heat fluxes without requirements for empirical extra resistance, roughness parameterization and wind velocity. The proposed OSML employs both conceptual VFC/LST trapezoid model and the electrical analog formula of sensible heat flux (H to analytically estimate the radiometric-convective resistance (rae via a quartic equation. To evaluate the performance of OSML, the model was applied to the Soil Moisture-Atmosphere Coupling Experiment (SMACEX in United States and the Multi-Scale Observation Experiment on Evapotranspiration (MUSOEXE in China, using remotely sensed retrievals as auxiliary data sets at regional scale. Validated against tower-based surface fluxes observations, the root mean square deviation (RMSD of H and latent heat flux (LE from OSML are 34.5 W/m2 and 46.5 W/m2 at SMACEX site and 50.1 W/m2 and 67.0 W/m2 at MUSOEXE site. The performance of OSML is very comparable to other published studies. In addition, the proposed OSML model demonstrates similar skills of predicting surface heat fluxes in comparison to SEBS (Surface Energy Balance System. Since OSML does not require specification of aerodynamic surface characteristics, roughness parameterization and meteorological conditions with high spatial variation such as wind speed, this proposed method shows high potential for routinely acquisition of latent heat flux estimation

  14. Conversational sensing

    Science.gov (United States)

    Preece, Alun; Gwilliams, Chris; Parizas, Christos; Pizzocaro, Diego; Bakdash, Jonathan Z.; Braines, Dave

    2014-05-01

    Recent developments in sensing technologies, mobile devices and context-aware user interfaces have made it pos- sible to represent information fusion and situational awareness for Intelligence, Surveillance and Reconnaissance (ISR) activities as a conversational process among actors at or near the tactical edges of a network. Motivated by use cases in the domain of Company Intelligence Support Team (CoIST) tasks, this paper presents an approach to information collection, fusion and sense-making based on the use of natural language (NL) and controlled nat- ural language (CNL) to support richer forms of human-machine interaction. The approach uses a conversational protocol to facilitate a ow of collaborative messages from NL to CNL and back again in support of interactions such as: turning eyewitness reports from human observers into actionable information (from both soldier and civilian sources); fusing information from humans and physical sensors (with associated quality metadata); and assisting human analysts to make the best use of available sensing assets in an area of interest (governed by man- agement and security policies). CNL is used as a common formal knowledge representation for both machine and human agents to support reasoning, semantic information fusion and generation of rationale for inferences, in ways that remain transparent to human users. Examples are provided of various alternative styles for user feedback, including NL, CNL and graphical feedback. A pilot experiment with human subjects shows that a prototype conversational agent is able to gather usable CNL information from untrained human subjects.

  15. Suppression of the e- coextracted from a Penning surface-plasma H-source

    International Nuclear Information System (INIS)

    Smith, V.H.; Allison, P.

    1992-01-01

    The ratio of electrons to negative ions extracted from Penning surface-plasma sources (SPS) such as the 8X source is low even before any steps are taken to suppress the electrons. For the 8X source the e - /H - ratio is typically four or five to one for H - operation and nine to one for D - operation. Because the coextracted e - present a power-loading problem to the 8X-source extraction system, methods to dissipate and/or reduce the power in the e - beam must be developed before extracting a dc H - or D - beam. Thus, we conducted this study to determine whether a collar installed in the near-extraction region of the 8X source suppresses the electrons extracted from that source. (Author) 8 refs., 6 figs

  16. Monthly CO surface sources inventory based on the 2000-2001 MOPITT satellite data

    Science.gov (United States)

    Pétron, Gabrielle; Granier, Claire; Khattatov, Boris; Yudin, Valery; Lamarque, Jean-François; Emmons, Louisa; Gille, John; Edwards, David P.

    2004-11-01

    This paper presents results of the inverse modeling of carbon monoxide surface sources on a monthly and regional basis using the MOPITT (Measurement Of the Pollution In The Troposphere) CO retrievals. The targeted time period is from April 2000 to March 2001. A sequential and time-dependent inversion scheme is implemented to correct an a priori set of monthly mean CO sources. The a posteriori estimates for the total anthropogenic (fossil fuel + biofuel + biomass burning) surface sources of CO in TgCO/yr are 509 in Asia, 267 in Africa, 140 in North America, 90 in Europe and 84 in Central and South America. Inverting on a monthly scale allows one to assess a corrected seasonality specific to each source type and each region. Forward CTM simulations with the a posteriori emissions show a substantial improvement of the agreement between modeled CO and independent in situ observations.

  17. A new concept positive (negative) surface ionization source for RIB applications

    International Nuclear Information System (INIS)

    Alton, G.D.; Welton, R.F.; Cui, B.

    1996-01-01

    A versatile, new concept, spherical-geometry, positive (negative) surface-ionization source has been designed. fabricated, and tests completed which can operate in either positive- or negative-ion beam generation modes without mechanical changes to the source. The highly permeable, composite Ir/C has an intrinsic work function of 0 = 5.29 eV and can be used directly for the generation of positive-ion beams of highly electropositive elements. For negative-surface ionization, the work function is lowered by dynamic flow of a highly electropositive adsorbate such as Cs through the ionizer matrix. The results of initial testing indicate that the source is reliable, stable and easy to operate, with efficiencies for Cs + estimated to exceed 60% and as high as ∼50% for F - generation. The design features, operational principles, and initial performance of the source for generating Cs + and F - , when operated with Cs, are discussed in this article

  18. Surface-water nutrient conditions and sources in the United States Pacific Northwest

    Science.gov (United States)

    Wise, D.R.; Johnson, H.M.

    2011-01-01

    The SPAtially Referenced Regressions On Watershed attributes (SPARROW) model was used to perform an assessment of surface-water nutrient conditions and to identify important nutrient sources in watersheds of the Pacific Northwest region of the United States (U.S.) for the year 2002. Our models included variables representing nutrient sources as well as landscape characteristics that affect nutrient delivery to streams. Annual nutrient yields were higher in watersheds on the wetter, west side of the Cascade Range compared to watersheds on the drier, east side. High nutrient enrichment (relative to the U.S. Environmental Protection Agency's recommended nutrient criteria) was estimated in watersheds throughout the region. Forest land was generally the largest source of total nitrogen stream load and geologic material was generally the largest source of total phosphorus stream load generated within the 12,039 modeled watersheds. These results reflected the prevalence of these two natural sources and the low input from other nutrient sources across the region. However, the combined input from agriculture, point sources, and developed land, rather than natural nutrient sources, was responsible for most of the nutrient load discharged from many of the largest watersheds. Our results provided an understanding of the regional patterns in surface-water nutrient conditions and should be useful to environmental managers in future water-quality planning efforts.

  19. High Fidelity Down-Conversion Source for Secure Communications using On-Demand Single Photons, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — In this NASA SBIR Phase II effort, AdvR will design and build an efficient, fully integrated, waveguide based, source of spectrally uncorrelated photon pairs that...

  20. Computerized study of several electrostatic, surface-ionization ion-source configurations

    Energy Technology Data Exchange (ETDEWEB)

    Balestrini, S.J.; Schuster, B.G.

    1984-08-01

    A computer-based method is presented whereby the optics of electrostatic, surface-ionization ion-source designs can be analyzed theoretically. The analysis solves for the luminosity and disperstion of a beam of charged particles at the final collimating slit and at locations preceding the slit. The performance of an ion source tested in 1960 and also some newer optical configurations are compared with theory.

  1. Source study of local coalfield events using the modal synthesis of shear and surface waves

    Energy Technology Data Exchange (ETDEWEB)

    MacBeth, C.D.; Redmayne, D.W.

    1989-10-01

    Results from the BGS LOWNET array from the Midlothian coalfield in Scotland have been studied. Vertical component seismograms have been analysed using a waveform matching technique based on the modal summation method for constructing synthetic seismograms. Results of the analysis are applied to S and surface wave portions of the seismogram. Effects of different earth structures, source depths, source orientation, and type of event, rockburst or triggered earthquake 2-3 km from the mine workings, can be evaluated.

  2. Ultrafast all-optical switching and error-free 10 Gbit/s wavelength conversion in hybrid InP-silicon on insulator nanocavities using surface quantum wells

    Energy Technology Data Exchange (ETDEWEB)

    Bazin, Alexandre; Monnier, Paul; Beaudoin, Grégoire; Sagnes, Isabelle; Raj, Rama [Laboratoire de Photonique et de Nanostructures (CNRS UPR20), Route de Nozay, Marcoussis 91460 (France); Lenglé, Kevin; Gay, Mathilde; Bramerie, Laurent [Université Européenne de Bretagne (UEB), 5 Boulevard Laënnec, 35000 Rennes (France); CNRS-Foton Laboratory (UMR 6082), Enssat, BP 80518, 22305 Lannion Cedex (France); Braive, Rémy; Raineri, Fabrice, E-mail: fabrice.raineri@lpn.cnrs.fr [Laboratoire de Photonique et de Nanostructures (CNRS UPR20), Route de Nozay, Marcoussis 91460 (France); Université Paris Diderot, Sorbonne Paris Cité, 75207 Paris Cedex 13 (France)

    2014-01-06

    Ultrafast switching with low energies is demonstrated using InP photonic crystal nanocavities embedding InGaAs surface quantum wells heterogeneously integrated to a silicon on insulator waveguide circuitry. Thanks to the engineered enhancement of surface non radiative recombination of carriers, switching time is obtained to be as fast as 10 ps. These hybrid nanostructures are shown to be capable of achieving systems level performance by demonstrating error free wavelength conversion at 10 Gbit/s with 6 mW switching powers.

  3. Physical fracture properties (fracture surfaces as information sources; crackgrowth and fracture mechanisms; exemples of cracks)

    International Nuclear Information System (INIS)

    Meny, Lucienne.

    1979-06-01

    Fracture surfaces are considered as a useful source of informations: an introduction to fractography is presented; the fracture surface may be observed through X ray microanalysis, and other physical methods such as Auger electron spectroscopy or secundary ion emission. The mechanisms of macroscopic and microscopic crackgrowth and fracture are described, in the case of unstable fracture (cleavage, ductile with shear, intergranular brittleness) and of progressive crack propagation (creep, fatigue). Exemples of cracks are presented in the last chapter [fr

  4. Conversion of Local and Surface-Wave Magnitudes to Moment Magnitude for Earthquakes in the Chinese Mainland

    Science.gov (United States)

    Li, X.; Gao, M.

    2017-12-01

    The magnitude of an earthquake is one of its basic parameters and is a measure of its scale. It plays a significant role in seismology and earthquake engineering research, particularly in the calculations of the seismic rate and b value in earthquake prediction and seismic hazard analysis. However, several current types of magnitudes used in seismology research, such as local magnitude (ML), surface wave magnitude (MS), and body-wave magnitude (MB), have a common limitation, which is the magnitude saturation phenomenon. Fortunately, the problem of magnitude saturation was solved by a formula for calculating the seismic moment magnitude (MW) based on the seismic moment, which describes the seismic source strength. Now the moment magnitude is very commonly used in seismology research. However, in China, the earthquake scale is primarily based on local and surface-wave magnitudes. In the present work, we studied the empirical relationships between moment magnitude (MW) and local magnitude (ML) as well as surface wave magnitude (MS) in the Chinese Mainland. The China Earthquake Networks Center (CENC) ML catalog, China Seismograph Network (CSN) MS catalog, ANSS Comprehensive Earthquake Catalog (ComCat), and Global Centroid Moment Tensor (GCMT) are adopted to regress the relationships using the orthogonal regression method. The obtained relationships are as follows: MW=0.64+0.87MS; MW=1.16+0.75ML. Therefore, in China, if the moment magnitude of an earthquake is not reported by any agency in the world, we can use the equations mentioned above for converting ML to MW and MS to MW. These relationships are very important, because they will allow the China earthquake catalogs to be used more effectively for seismic hazard analysis, earthquake prediction, and other seismology research. We also computed the relationships of and (where Mo is the seismic moment) by linear regression using the Global Centroid Moment Tensor. The obtained relationships are as follows: logMo=18

  5. A high-efficiency positive (negative) surface ionization source for radioactive ion beam (abstract)a

    International Nuclear Information System (INIS)

    Alton, G.D.; Mills, G.D.

    1996-01-01

    A versatile, new concept, spherical-geometry, positive (negative) surface-ionization source has been designed and fabricated which will have the capability of generating both positive- and negative-ion beams without mechanical changes to the source. The source utilizes a highly permeable, high-work-function Ir ionizer (φ≡5.29 eV) for ionizing highly electropositive atoms/molecules; while for negative-surface ionization, the work function is lowered to φ≡1.43 eV by continually feeding cesium vapor through the ionizer matrix. The use of this technique for negative ion beam generation has the potential of overcoming the chronic poisoning effects experienced with LaB 6 while enhancing considerably the efficiency for negative surface ionization of atoms and molecules with intermediate electron affinities. The flexibility of operation in either mode makes it especially attractive for radioactive ion beam applications and, therefore, the source will be used as a complementary replacement for the high-temperature electron impact ionization sources presently in use at the Holifield radioactive beam facility. The design features and operational principles of the source will be described in this report. copyright 1996 American Institute of Physics

  6. A positive (negative) surface ionization source concept for radioactive ion beam generation

    International Nuclear Information System (INIS)

    Alton, G.D.; Mills, G.D.

    1996-01-01

    A novel, versatile, new concept, spherical-geometry, positive (negative) surface-ionization source has been designed and fabricated which will have the capability of generating both positive- and negative-ion beams without mechanical changes to the source. The source utilizes a highly permeable, high-work-function Ir ionizer (φ ≅ 5.29 eV) for ionizing highly electropositive atoms/molecules; while for negative-surface ionization, the work function is lowered by continually feeding a highly electropositive vapor through the ionizer matrix. The use of this technique to effect low work function surfaces for negative ion beam generation has the potential of overcoming the chronic poisoning effects experienced with LaB 6 while enhancing the probability for negative ion formation of atomic and molecular species with low to intermediate electron affinities. The flexibility of operation in either mode makes it especially attractive for radioactive ion beam (RIB) applications and, therefore, the source will be used as a complementary replacement for the high-temperature electron impact ionization sources presently in the use at the Holifield radioactive ion beam facility (HRIBF). The design features and operational principles of the source are described in this report. (orig.)

  7. 'EXTSANGLE' - an extension of the efficiency conversion program 'SOLANG' to sources with a diameter larger than that of the Ge-detector

    International Nuclear Information System (INIS)

    Mihaljevic, N.; Jovanovic, S.; Vukotic, P.

    1993-01-01

    The computer program SOLANG, originally developed by MOENS et al. for the efficiency conversion via effective solid angles (Ω-bar), was extended to cylindrical sources with a diameter larger than that of the Ge-detector. New program, named EXTSANGLE, was experimentally checked in three laboratories. For the most unfavourable case from the standpoint of the accuracy of Ω-bar (bulky source counted at the top of detector), discrepancies were below 7% in the whole range of gamma-energies considered (88-1115 keV), with an average of 3-4%. EXTSANGLE is extensive and flexible with respect to the data input, storage and output, thus contributing to the automation of a gamma-spectrometry laboratory dealing, for instance, with the k 0 -NAA and/or environmental radioactivity monitoring. (author) 9 refs.; 3 figs.; 1 tab

  8. The coupling effect of gas-phase chemistry and surface reactions on oxygen permeation and fuel conversion in ITM reactors

    KAUST Repository

    Hong, Jongsup; Kirchen, Patrick; Ghoniem, Ahmed F.

    2015-01-01

    © 2015 Elsevier B.V. The effect of the coupling between heterogeneous catalytic reactions supported by an ion transport membrane (ITM) and gas-phase chemistry on fuel conversion and oxygen permeation in ITM reactors is examined. In ITM reactors

  9. Surface dose characterisation of the Varian Ir-192 HDR conical surface applicator set with a vertically orientated source

    Energy Technology Data Exchange (ETDEWEB)

    Buchauer, Konrad; Henke, Guido; Schiefer, Hans; Plasswilm, Ludwig [Kantonsspital St. Gallen, Department of Radiation Oncology, St. Gallen (Switzerland)

    2014-12-15

    Conical surface applicators with an Ir-192 high-dose-rate brachytherapy source are a common modality for the treatment of non-melanomatous skin cancer with high tumour control rates. Surface dose characterisation of the Varian Varisource GammaMed+ IX afterloader vertical type surface applicators is performed two dimensionally using high-resolution film dosimetry. The focus of this study was to determine if Varian surface applicators with a vertical source suffer from the dose distribution irregularities reported for comparable applicators. Our goal was to evaluate if the irregularities found affected treatment and dose output verification procedures. Ionisation chamber-based verification of applicator output was established according to guidelines provided by the manufacturer. For additional measurement of surface dose Gafchromic EBT3 film dosimetry was used. The term ''therapeutic dose'' was defined as 85 % of the prescribed dose level. For the 10 different applicator inserts evaluated, cold spots were observed. Mean cold spot size was 2.0 mm x 3.6 mm (± 0.6 mm). The cold spots were dosimetrically well below 85 % of the prescribed dose. The cold spot was situated 2.2 mm (1.4-2.7 mm) unilaterally from the central axis and caused general asymmetry in the dose profiles intersecting the cold spot area. A source tilt of approximately 8 (± 1 ) was determined for the source used for irradiation. A central underdosed area exceeding 15 % of the prescribed dose has not been previously reported. Source tilt was observed and found to affect clinical use and possibly treatment outcome in applicators using a vertically arranged source. Surface applicators with a vertically orientated source were subject to dose irregularities that could impact on chamber-based applicator output verification procedures. We recommend film dosimetry-backed applicator commissioning to avoid systematic errors. (orig.) [German] Konische Oberflaechenapplikatoren sind ein

  10. Evaluation of the homogeneity of reference flat sources used in calibration of surface contamination monitors

    International Nuclear Information System (INIS)

    Silva Junior, I.A.; Xavier, M.; Siqueira, P.T.D.; Potiens, M.P.A.

    2014-01-01

    The aim of this study was to re-evaluate the uniformity of the wide area reference sources of the Calibration Laboratory of Instruments (LCI-IPEN) used in the calibration of surface contamination monitors, according the recommendations of the ISO 8769 standard and the NRPB. In this work used six wide area reference sources of 150 cm 2 of 241 Am, 14 C, 36 Cl, 137 Cs, 90 Sr+ 90 Y and 99 Tc with reference dates between 1996 and 1997 and three sources of 100 cm 2 of 14 C, 137 Cs and 60 Co were used with reference dates 2007. Measurements were performed with a radiation monitor of the Thermo, model FH40GX with a pancake probe, model FHZ732GM. We also made several models on paper with the objective of define each measurement position and an aluminum plate with a square hole (6.25 cm 2 ) in its center, allowing the passage of the radiation only through the hole. Each wide area reference source was positioned in setup and measurements were performed in order to cover the entire surface of the source. The values of the uniformity obtained partially confirm previous data obtained in another study conducted by LCI-IPEN, showing that some wide area reference sources 150 cm 2 in disagree with ISO 8769. In the former work, just the source of 241 Am (7.3%) was within the range specified by the standard, now have sources of 241 Am (5.7%), 137 Cs (8.8%), 90 Sr+ 9 '0Y (8, 8%) and 99 Tc (9.2%) with values within the specified uniformity. The sources of 14 C (53.3%) and 36 Cl (16.6%) were outside the specified. The wide area reference sources of 100 cm 2 , show disagreement in values of uniformity of the sources 14 C (46.7%) and 60 Co (10.4%). The values of the uniformity of the wide area reference sources show that some fonts can not be used in calibrations, because not in accordance with the value of uniformity specified in ISO 8769:2010, this is a conditions to believe a laboratory according to ISO 17025, show the laboratory performs its services with a high quality. The

  11. Identification and quantification of point sources of surface water contamination in fruit culture in the Netherlands

    NARCIS (Netherlands)

    Wenneker, M.; Beltman, W.H.J.; Werd, de H.A.E.; Zande, van de J.C.

    2008-01-01

    Measurements of pesticide concentrations in surface water by the water boards show that they have decreased less than was expected from model calculations. Possibly, the implementation of spray drift reducing techniques is overestimated in the model calculation. The impact of point sources is

  12. An inexpensive way to analyze the optics of electrostatic, surface-ionization ion-source configurations

    International Nuclear Information System (INIS)

    Balestrini, S.J.

    1986-01-01

    The optical characteristics of surface ionization sources can often be studied in detail with the aid of a home computer. Sources with two-dimensional symmetry are considered. Ions are created on the surface of a hot filament. An accelerating voltage, V, is applied to the source and filament. The ions are accelerated and focused into a beam by a series of electrodes containing narrow axial slits. The ordering of elementary stages of acceleration that the electrodes form from is the optical stack. The focusing parameters are the fractions of the source voltage applied to the electrodes. A portion of the ions leaves the source through a beam-defining, collimating slit in the final electrode. An ion trajectory at any point along the symmetry axis is described by a vector with two phase space components, which are treated as small quantities. The components at the filament are ω, the displacement from the symmetry axis, and ν, the velocity component of the ion parallel to the filament surface divided by its speed when it leaves the first stage. Elsewhere, the trajectory components are the displacement from the symmetry axis and the slope

  13. Source apportionment of polycyclic aromatic hydrocarbons in surface soil in Tianjin, China

    International Nuclear Information System (INIS)

    Zuo, Q.; Duan, Y.H.; Yang, Y.; Wang, X.J.; Tao, S.

    2007-01-01

    Principal component analysis and multiple linear regression were applied to apportion sources of polycyclic aromatic hydrocarbons (PAHs) in surface soils of Tianjin, China based on the measured PAH concentrations of 188 surface soil samples. Four principal components were identified representing coal combustion, petroleum, coke oven plus biomass burning, and chemical industry discharge, respectively. The contributions of major sources were quantified as 41% from coal, 20% from petroleum, and 39% from coking and biomass, which are compatible with PAH emissions estimated based on fuel consumption and emission factors. When the study area was divided into three zones with distinctive differences in soil PAH concentration and profile, different source features were unveiled. For the industrialized Tanggu-Hangu zone, the major contributors were coking (43%), coal (37%) and vehicle exhaust (20%). In rural area, however, in addition to the three main sources, biomass burning was also important (13%). In urban-suburban zone, incineration accounted for one fourth of the total. - PAHs in surface soil of Tianjin were apportioned and coal combustion, vehicle exhaust, coke production, and biomass burning were found to be the major sources

  14. Tracing nitrate pollution sources and transformation in surface- and ground-waters using environmental isotopes

    International Nuclear Information System (INIS)

    Zhang, Yan; Li, Fadong; Zhang, Qiuying; Li, Jing; Liu, Qiang

    2014-01-01

    Water pollution in the form of nitrate nitrogen (NO 3 − –N) contamination is a major concern in most agricultural areas in the world. Concentrations and nitrogen and oxygen isotopic compositions of nitrate, as well as oxygen and deuterium isotopic compositions of surface and groundwater from a typical irrigated region in the North China Plain (NCP) collected from May to October in 2012 were analyzed to examine the major nitrate sources and transformations. Concentrations of NO 3 − –N ranged from 0.2 to 29.6 mg/L (mean of 11.2 mg/L) in surface water, and from 0.1 to 19.4 mg/L (mean of 2.8 mg/L) in groundwater. Approximately 46.7% of the surface water samples and 10% of the groundwater samples exceeded the World Health Organization (WHO) drinking water standard for NO 3 − –N. Surface water samples that exceeded the standard were collected mainly in the dry season (May and October), while groundwater samples that exceeded the standard were collected in the wet season (June). Overall, the highest nitrate levels were observed in surface water in May and in groundwater in June, indicating that fertilizer application, precipitation, and irrigation strongly influence the NO 3 − –N concentrations. Analyses of isotopic compositions suggest that the main sources of nitrate are nitrification of fertilizer and sewage in surface water, in contrast, mineralization of soil organic N and sewage is the groundwater sources during the dry season. When fertilizers are applied, nitrate will be transported by precipitation through the soil layers to the groundwater in the wet season (June). Denitrification only occurred in surface water in the wet season. Attempts should be made to minimize overuse of nitrogen fertilizers and to improve nitrogen use efficiency in irrigated agricultural regions. - Highlights: • Nitrate sources in surface and groundwater were identified by multiple isotopes. • Nitrate pollution displayed obvious seasonal variations. • Nitrate of

  15. Tracing nitrate pollution sources and transformation in surface- and ground-waters using environmental isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Yan [Key Laboratory of Ecosystem Network Observation and Modeling, Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing 100101 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Li, Fadong, E-mail: lifadong@igsnrr.ac.cn [Key Laboratory of Ecosystem Network Observation and Modeling, Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing 100101 (China); Zhang, Qiuying [Center for Agricultural Resources Research, Chinese Academy of Sciences, Shijiazhuang 050021 (China); Li, Jing [Key Laboratory of Ecosystem Network Observation and Modeling, Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing 100101 (China); Liu, Qiang [Key Laboratory of Ecosystem Network Observation and Modeling, Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing 100101 (China); University of Chinese Academy of Sciences, Beijing 100049 (China)

    2014-08-15

    Water pollution in the form of nitrate nitrogen (NO{sub 3}{sup −}–N) contamination is a major concern in most agricultural areas in the world. Concentrations and nitrogen and oxygen isotopic compositions of nitrate, as well as oxygen and deuterium isotopic compositions of surface and groundwater from a typical irrigated region in the North China Plain (NCP) collected from May to October in 2012 were analyzed to examine the major nitrate sources and transformations. Concentrations of NO{sub 3}{sup −}–N ranged from 0.2 to 29.6 mg/L (mean of 11.2 mg/L) in surface water, and from 0.1 to 19.4 mg/L (mean of 2.8 mg/L) in groundwater. Approximately 46.7% of the surface water samples and 10% of the groundwater samples exceeded the World Health Organization (WHO) drinking water standard for NO{sub 3}{sup −}–N. Surface water samples that exceeded the standard were collected mainly in the dry season (May and October), while groundwater samples that exceeded the standard were collected in the wet season (June). Overall, the highest nitrate levels were observed in surface water in May and in groundwater in June, indicating that fertilizer application, precipitation, and irrigation strongly influence the NO{sub 3}{sup −}–N concentrations. Analyses of isotopic compositions suggest that the main sources of nitrate are nitrification of fertilizer and sewage in surface water, in contrast, mineralization of soil organic N and sewage is the groundwater sources during the dry season. When fertilizers are applied, nitrate will be transported by precipitation through the soil layers to the groundwater in the wet season (June). Denitrification only occurred in surface water in the wet season. Attempts should be made to minimize overuse of nitrogen fertilizers and to improve nitrogen use efficiency in irrigated agricultural regions. - Highlights: • Nitrate sources in surface and groundwater were identified by multiple isotopes. • Nitrate pollution displayed obvious

  16. An open source Bayesian Monte Carlo isotope mixing model with applications in Earth surface processes

    Science.gov (United States)

    Arendt, Carli A.; Aciego, Sarah M.; Hetland, Eric A.

    2015-05-01

    The implementation of isotopic tracers as constraints on source contributions has become increasingly relevant to understanding Earth surface processes. Interpretation of these isotopic tracers has become more accessible with the development of Bayesian Monte Carlo (BMC) mixing models, which allow uncertainty in mixing end-members and provide methodology for systems with multicomponent mixing. This study presents an open source multiple isotope BMC mixing model that is applicable to Earth surface environments with sources exhibiting distinct end-member isotopic signatures. Our model is first applied to new δ18O and δD measurements from the Athabasca Glacier, which showed expected seasonal melt evolution trends and vigorously assessed the statistical relevance of the resulting fraction estimations. To highlight the broad applicability of our model to a variety of Earth surface environments and relevant isotopic systems, we expand our model to two additional case studies: deriving melt sources from δ18O, δD, and 222Rn measurements of Greenland Ice Sheet bulk water samples and assessing nutrient sources from ɛNd and 87Sr/86Sr measurements of Hawaiian soil cores. The model produces results for the Greenland Ice Sheet and Hawaiian soil data sets that are consistent with the originally published fractional contribution estimates. The advantage of this method is that it quantifies the error induced by variability in the end-member compositions, unrealized by the models previously applied to the above case studies. Results from all three case studies demonstrate the broad applicability of this statistical BMC isotopic mixing model for estimating source contribution fractions in a variety of Earth surface systems.

  17. Open-source algorithm for detecting sea ice surface features in high-resolution optical imagery

    Directory of Open Access Journals (Sweden)

    N. C. Wright

    2018-04-01

    Full Text Available Snow, ice, and melt ponds cover the surface of the Arctic Ocean in fractions that change throughout the seasons. These surfaces control albedo and exert tremendous influence over the energy balance in the Arctic. Increasingly available meter- to decimeter-scale resolution optical imagery captures the evolution of the ice and ocean surface state visually, but methods for quantifying coverage of key surface types from raw imagery are not yet well established. Here we present an open-source system designed to provide a standardized, automated, and reproducible technique for processing optical imagery of sea ice. The method classifies surface coverage into three main categories: snow and bare ice, melt ponds and submerged ice, and open water. The method is demonstrated on imagery from four sensor platforms and on imagery spanning from spring thaw to fall freeze-up. Tests show the classification accuracy of this method typically exceeds 96 %. To facilitate scientific use, we evaluate the minimum observation area required for reporting a representative sample of surface coverage. We provide an open-source distribution of this algorithm and associated training datasets and suggest the community consider this a step towards standardizing optical sea ice imagery processing. We hope to encourage future collaborative efforts to improve the code base and to analyze large datasets of optical sea ice imagery.

  18. Open-source algorithm for detecting sea ice surface features in high-resolution optical imagery

    Science.gov (United States)

    Wright, Nicholas C.; Polashenski, Chris M.

    2018-04-01

    Snow, ice, and melt ponds cover the surface of the Arctic Ocean in fractions that change throughout the seasons. These surfaces control albedo and exert tremendous influence over the energy balance in the Arctic. Increasingly available meter- to decimeter-scale resolution optical imagery captures the evolution of the ice and ocean surface state visually, but methods for quantifying coverage of key surface types from raw imagery are not yet well established. Here we present an open-source system designed to provide a standardized, automated, and reproducible technique for processing optical imagery of sea ice. The method classifies surface coverage into three main categories: snow and bare ice, melt ponds and submerged ice, and open water. The method is demonstrated on imagery from four sensor platforms and on imagery spanning from spring thaw to fall freeze-up. Tests show the classification accuracy of this method typically exceeds 96 %. To facilitate scientific use, we evaluate the minimum observation area required for reporting a representative sample of surface coverage. We provide an open-source distribution of this algorithm and associated training datasets and suggest the community consider this a step towards standardizing optical sea ice imagery processing. We hope to encourage future collaborative efforts to improve the code base and to analyze large datasets of optical sea ice imagery.

  19. Development of a new surface ion-source and ion guide in the ALTO project

    International Nuclear Information System (INIS)

    Cuong, P.V.

    2009-12-01

    The present work is dedicated to the ALTO project which is the production of neutron-rich gallium isotopes by the ISOL thick-target technique using photo-fission and a surface ion source. We aim at the study of the structure of 82 Ge, 83 Ge, 84 Ge via the β decay of 82 Ga, 83 Ga, and 84 Ga. We focus on the development of a new surface ion source made from materials with a high work function φ which can give high ionisation efficiencies for elements with low ionisation potentials, like alkaline as well as gallium and indium. Tungsten, rhenium and iridium are considered as good candidates for a surface ionizer because the Saha-Langmuir equation indicates high surface ionisation efficiencies for these materials. This has motivated us to equip the surface ion source at ALTO with rhenium and iridium-coated rhenium ionizer tubes of the same dimensions as the surface ion source at ISOLDE. We performed a test experiment to measure the ionisation efficiency for gallium. We also built a simulation code for the ionisation efficiency of the different surface ionisation sources (different materials and dimensions). On the other hand, for future nuclear structure studies of refractory elements such as cobalt or nickel, the ISOL technique with a thick target is no longer suitable. Indeed, the high melting point of these elements makes it difficult to volatilize and release them from a thick target. For such a situation, a technique based on thin targets is needed and the laser ion guide based on a gas cell to slow down, neutralize and stop the recoiling nuclear reaction products combined with a laser beam to re-ionize them selectively, seems a good choice. A code based on the Geant-4 tool-kit has been built to simulate the ionisation of the buffer gas. In this work, we also briefly show the results of the photo-fission yield measurements at ALTO. The fission fragments were ionized in a hot plasma ion source, mass separated and detected by germanium and scintillator detectors

  20. Performance evaluation of a direct-conversion flat-panel detector system in imaging and quality assurance for a high-dose-rate 192Ir source

    Science.gov (United States)

    Miyahara, Yoshinori; Hara, Yuki; Nakashima, Hiroto; Nishimura, Tomonori; Itakura, Kanae; Inomata, Taisuke; Kitagaki, Hajime

    2018-03-01

    In high-dose-rate (HDR) brachytherapy, a direct-conversion flat-panel detector (d-FPD) clearly depicts a 192Ir source without image halation, even under the emission of high-energy gamma rays. However, it was unknown why iridium is visible when using a d-FPD. The purpose of this study was to clarify the reasons for visibility of the source core based on physical imaging characteristics, including the modulation transfer functions (MTF), noise power spectral (NPS), contrast transfer functions, and linearity of d-FPD to high-energy gamma rays. The acquired data included: x-rays, [X]; gamma rays, [γ] dual rays (X  +  γ), [D], and subtracted data for depicting the source ([D]  -  [γ]). In the quality assurance (QA) test for the positional accuracy of a source core, the coordinates of each dwelling point were compared between the planned and actual source core positions using a CT/MR-compatible ovoid applicator and a Fletcher-Williamson applicator. The profile curves of [X] and ([D]  -  [γ]) matched well on MTF and NPS. The contrast resolutions of [D] and [X] were equivalent. A strongly positive linear correlation was found between the output data of [γ] and source strength (r 2  >  0.99). With regard to the accuracy of the source core position, the largest coordinate difference (3D distance) was noted at the maximum curvature of the CT/MR-compatible ovoid and Fletcher-Williamson applicators, showing 1.74  ±  0.02 mm and 1.01  ±  0.01 mm, respectively. A d-FPD system provides high-quality images of a source, even when high-energy gamma rays are emitted to the detector, and positional accuracy tests with clinical applicators are useful in identifying source positions (source movements) within the applicator for QA.

  1. Total luminous flux measurement for flexible surface sources with an integrating sphere photometer

    International Nuclear Information System (INIS)

    Yu, Hsueh-Ling; Liu, Wen-Chun

    2014-01-01

    Applying an integrating sphere photometer for total luminous flux measurement is a widely used method. However, the measurement accuracy depends on the spatial uniformity of the integrating sphere, especially when the test sample has a different light distribution from that of the standard source. Therefore, spatial correction is needed to eliminate the effect caused by non-uniformity. To reduce the inconvenience of spatial correction but retain the measurement accuracy, a new type of working standard is designed for flexible and curved surface sources. Applying this new type standard source, the measurement deviation due to different orientations is reduced by an order of magnitude compared with using a naked incandescent lamp as the standard source. (paper)

  2. Workflow for near-surface velocity automatic estimation: Source-domain full-traveltime inversion followed by waveform inversion

    KAUST Repository

    Liu, Lu; Fei, Tong; Luo, Yi; Guo, Bowen

    2017-01-01

    This paper presents a workflow for near-surface velocity automatic estimation using the early arrivals of seismic data. This workflow comprises two methods, source-domain full traveltime inversion (FTI) and early-arrival waveform inversion. Source

  3. Monomer conversion, dimensional stability, strength, modulus, surface apatite precipitation and wear of novel, reactive calcium phosphate and polylysine-containing dental composites.

    Directory of Open Access Journals (Sweden)

    Kanokrat Kangwankai

    Full Text Available The aim was to assess monomer conversion, dimensional stability, flexural strength / modulus, surface apatite precipitation and wear of mono / tri calcium phosphate (CaP and polylysine (PLS-containing dental composites. These were formulated using a new, high molecular weight, fluid monomer phase that requires no polymerisation activator.Urethane and Polypropylene Glycol Dimethacrylates were combined with low levels of an adhesion promoting monomer and a light activated initiator. This liquid was mixed with a hybrid glass containing either 10 wt% CaP and 1 wt% PLS (F1 or 20 wt% CaP and 2 wt% PLS (F2. Powder to liquid mass ratio was 5:1. Commercial controls included Gradia Direct Posterior (GD and Filtek Z250 (FZ. Monomer conversion and polymerisation shrinkage were calculated using Fourier Transform Infrared (FTIR. Subsequent volume increases in water over 7 weeks were determined using gravimetric studies. Biaxial flexural strength (BFS / modulus (BFM reduction and surface apatite precipitation upon 1 and 4 weeks immersion in water versus simulated body fluid (SBF were assessed using a mechanical testing frame and scanning electron microscope (SEM. Mass / volume loss and surface roughness (Ra following 7 weeks water immersion and subsequent accelerated tooth-brush abrasion were examined using gravimetric studies and profilometer.F1 and F2 exhibited much higher monomer conversion (72% than FZ (54% and low calculated polymerization shrinkage (2.2 vol%. Final hygroscopic expansions decreased in the order; F2 (3.5 vol% > F1 (1.8 vol% ~ Z250 (1.6 vol% > Gradia (1.0 vol%. BFS and BFM were unaffected by storage medium type. Average BFS / BFM upon 4 weeks immersion reduced from 144 MPa / 8 GPa to 107 MPa / 5 GPa for F1 and 105 MPa / 6 GPa to 82 MPa / 4 GPa for F2. Much of this change was observed in the first week of immersion when water sorption rate was high. Surface apatite layers were incomplete at 1 week, but around 2 and 15 micron thick for F1 and

  4. Persuasion detection in conversation

    OpenAIRE

    Gilbert, Henry T.

    2010-01-01

    Approved for public release; distribution is unlimited In this thesis, we present a system for annotating persuasion in conversation based on a social-psychological model. We augmented the social model developed by James Cialdini with some of our own categories for annotators to label. The conversations consisted of 37 hostage negotiation transcripts from private and public sources, with all personal information removed from the private source transcripts. We evaluated the level of agre...

  5. Perspective on direct conversion

    Energy Technology Data Exchange (ETDEWEB)

    Lewis, W B

    1963-10-15

    The objective of direct conversion is high electrical output for minimum total cost, and not always high conversion efficiency. The wide range of techniques embracing cryogenics and hot plasma derives from the special requirements of source, environment, and application. Sources include solar and other radiation, nuclear fission and fusion, chemical energy, and heat. Environments and applications range from space vehicles to submarines and from giant power networks to isolated buoys and pocket devices. (auth)

  6. Ion source techniques for high-speed processing of material surface by ion beams

    International Nuclear Information System (INIS)

    Ishikawa, Junzo

    1990-01-01

    The present paper discusses some key or candidate techniques for future ion source development and such ion sources developed by the author. Several types of microwave ion sources for producing low charge state ions have been developed in Japan. When a microwave plasma cathode developed by the author is adapted to a Kaufman type ion source, the electron emission currents are found to be 2.5 A for argon gas and 0.5-0.9 A for oxygen gas. An alternative ionization method for metal atoms is strongly required for high-speed processing of material surface by metal-ion beams. Detailed discussion is made of collisional ionization of vaporized atoms, and negative-ion production (secondary negative-ion emission by sputtering). An impregnated electrode type liquid-metal ion source developed by the author, which has a porous tip structure, is described. The negative-ion production efficiency is quite high. The report also presents a neutral and ionized alkaline-metal bombardment type heavy negative-ion source, which consists of a cesium plasma ion source, suppressor, target electrode, negative-ion extraction electrode, and einzel lens. (N.K.)

  7. Development of a surface ionization source for the production of radioactive alkali ion beams in SPIRAL

    International Nuclear Information System (INIS)

    Eleon, C.; Jardin, P.; Gaubert, G.; Saint-Laurent, M.-G.; Alcantara-Nunez, J.; Alves Conde, R.; Barue, C.; Boilley, D.; Cornell, J.; Delahaye, P.; Dubois, M.; Jacquot, B.; Leherissier, P.; Leroy, R.; Lhersonneau, G.; Marie-Jeanne, M.; Maunoury, L.; Pacquet, J.Y.; Pellemoine, F.; Pierret, C.

    2008-01-01

    In the framework of the production of radioactive alkali ion beams by the isotope separation on-line (ISOL) method in SPIRAL I, a surface ionization source has been developed at GANIL to produce singly-charged ions of Li, Na and K. This new source has been designed to work in the hostile environment whilst having a long lifetime. This new system of production has two ohmic heating components: the first for the target oven and the second for the ionizer. The latter, being in carbon, offers high reliability and competitive ionization efficiency. This surface ionization source has been tested on-line using a 48 Ca primary beam at 60.3 A MeV with an intensity of 0.14 pA. The ionization efficiencies obtained for Li, Na and K are significantly better than the theoretical values of the ionization probability per contact. The enhanced efficiency, due to the polarization of the ionizer, is shown to be very important also for short-lived isotopes. In the future, this source will be associated with the multicharged electron-cyclotron-resonance (ECR) ion source NANOGAN III for production of multicharged alkali ions in SPIRAL. The preliminary tests of the set up are also presented in this contribution.

  8. Inverting near-surface models from virtual-source gathers (SM Division Outstanding ECS Award Lecture)

    Science.gov (United States)

    Ruigrok, Elmer; Vossen, Caron; Paulssen, Hanneke

    2017-04-01

    The Groningen gas field is a massive natural gas accumulation in the north-east of the Netherlands. Decades of production have led to significant compaction of the reservoir rock. The (differential) compaction is thought to have reactivated existing faults and to be the main driver of induced seismicity. The potential damage at the surface is largely affected by the state of the near surface. Thin and soft sedimentary layers can lead to large amplifications. By measuring the wavefield at different depth levels, near-surface properties can directly be estimated from the recordings. Seismicity in the Groningen area is monitored primarily with an array of vertical arrays. In the nineties a network of 8 boreholes was deployed. Since 2015, this network has been expanded with 70 new boreholes. Each new borehole consists of an accelerometer at the surface and four downhole geophones with a vertical spacing of 50 m. We apply seismic interferometry to local seismicity, for each borehole individually. Doing so, we obtain the responses as if there were virtual sources at the lowest geophones and receivers at the other depth levels. From the retrieved direct waves and reflections, we invert for P- & S- velocity and Q models. We discuss different implementations of seismic interferometry and the subsequent inversion. The inverted near-surface properties are used to improve both the source location and the hazard assessment.

  9. [Distribution and sources of oxygen and sulfur heterocyclic aromatic compounds in surface soil of Beijing, China].

    Science.gov (United States)

    He, Guang-Xiu; Zhang, Zhi-Huan; Peng, Xu-Yang; Zhu, Lei; Lu, Ling

    2011-11-01

    62 surface soil samples were collected from different environmental function zones in Beijing. Sulfur and oxygen heterocyclic aromatic compounds were detected by GC/MS. The objectives of this study were to identify the composition and distribution of these compounds, and discuss their sources. The results showed that the oxygen and sulfur heterocyclic aromatic compounds in the surface soils mainly contained dibenzofuran, methyl- and C2-dibenzofuran series, dibenzothiophene, methyl-, C2- and C3-dibenzothiophene series and benzonaphthothiophene series. The composition and distribution of the oxygen and sulfur heterocyclic aromatic compounds in the surface soil samples varied in the different environmental function zones, of which some factories and the urban area received oxygen and sulfur heterocyclic aromatic compounds most seriously. In Beijing, the degree of contamination by oxygen and sulfur heterocyclic aromatic compounds in the north surface soil was higher than that in the south. There were preferable linear correlations between the concentration of dibenzofuran series and fluorene series, as well as the concentration of dibenzothiophene series and dibenzofuran series. The oxygen and sulfur heterocyclic aromatic compounds in the surface soil were mainly derived from combustion products of oil and coal and direct input of mineral oil, etc. There were some variations in pollution sources of different environmental function zones.

  10. Characteristics of airborne plutonium resuspended from near-background aged surface-sources

    International Nuclear Information System (INIS)

    Sehmel, G.A.

    1982-11-01

    Plutonium content in samples of airborne solids collected at five Hanford sites was determined in several experiments directed toward investigating resuspension processes for aged surface sources. Though airborne plutonium concentrations are extremely low, radiochemical technique sensitivities allow plutonium characterization to be considered as a function of host-particle diameter in samples of airborne solids. Plutonium concentrations and activity densities are a function of aerodynamic particle diameter, sampling height, wind speed, wind direction and plutonium isotopic ratios

  11. Characterization of an atmospheric pressure air plasma source for polymer surface modification

    Science.gov (United States)

    Yang, Shujun; Tang, Jiansheng

    2013-10-01

    An atmospheric pressure air plasma source was generated through dielectric barrier discharge (DBD). It was used to modify polyethyleneterephthalate (PET) surfaces with very high throughput. An equivalent circuit model was used to calculate the peak average electron density. The emission spectrum from the plasma was taken and the main peaks in the spectrum were identified. The ozone density in the down plasma region was estimated by Absorption Spectroscopy. NSF and ARC-ODU

  12. Spatial distribution and source apportionment of PFASs in surface sediments from five lake regions, China

    Science.gov (United States)

    Qi, Yanjie; Huo, Shouliang; Xi, Beidou; Hu, Shibin; Zhang, Jingtian; He, Zhuoshi

    2016-03-01

    Perfluoroalkyl substances (PFASs) have been found in environment globally. However, studies on PFAS occurrence in sediments of lakes or reservoirs remain relatively scarce. In this study, two hundred and sixty-two surface sediment samples were collected from forty-eight lakes and two reservoirs all over China. Average PFAS concentrations in surface sediments from each lake or reservoir varied from 0.086 ng/g dw to 5.79 ng/g dw with an average of 1.15 ng/g dw. Among five lake regions, average PFAS concentrations for the lakes from Eastern Plain Region were the highest. Perfluorooctanoic acid, perfluoroundecanoic acid and perfluorooctane sulfonic acid (PFOS) were the predominant PFASs in surface sediments. The significant positive correlations between PFAS concentrations and total organic carbon, total nitrogen and total phosphorus contents in sediments revealed the influences of sedimentary characteristics on PFAS occurrence. A two-dimensional hierarchical cluster analysis heat map was depicted to analyze the possible origins of sediments and individual PFAS. The food-packaging, textile, electroplating, firefighting and semiconductor industry emission sources and the precious metals and coating industry emission sources were identified as the main sources by two receptor models, with contributions of 77.7 and 22.3% to the total concentrations of C4-C14- perfluoroalkyl carboxylic acids and PFOS, respectively.

  13. Spatial distribution and source apportionment of PFASs in surface sediments from five lake regions, China.

    Science.gov (United States)

    Qi, Yanjie; Huo, Shouliang; Xi, Beidou; Hu, Shibin; Zhang, Jingtian; He, Zhuoshi

    2016-03-07

    Perfluoroalkyl substances (PFASs) have been found in environment globally. However, studies on PFAS occurrence in sediments of lakes or reservoirs remain relatively scarce. In this study, two hundred and sixty-two surface sediment samples were collected from forty-eight lakes and two reservoirs all over China. Average PFAS concentrations in surface sediments from each lake or reservoir varied from 0.086 ng/g dw to 5.79 ng/g dw with an average of 1.15 ng/g dw. Among five lake regions, average PFAS concentrations for the lakes from Eastern Plain Region were the highest. Perfluorooctanoic acid, perfluoroundecanoic acid and perfluorooctane sulfonic acid (PFOS) were the predominant PFASs in surface sediments. The significant positive correlations between PFAS concentrations and total organic carbon, total nitrogen and total phosphorus contents in sediments revealed the influences of sedimentary characteristics on PFAS occurrence. A two-dimensional hierarchical cluster analysis heat map was depicted to analyze the possible origins of sediments and individual PFAS. The food-packaging, textile, electroplating, firefighting and semiconductor industry emission sources and the precious metals and coating industry emission sources were identified as the main sources by two receptor models, with contributions of 77.7 and 22.3% to the total concentrations of C4-C14- perfluoroalkyl carboxylic acids and PFOS, respectively.

  14. FreeSASA: An open source C library for solvent accessible surface area calculations.

    Science.gov (United States)

    Mitternacht, Simon

    2016-01-01

    Calculating solvent accessible surface areas (SASA) is a run-of-the-mill calculation in structural biology. Although there are many programs available for this calculation, there are no free-standing, open-source tools designed for easy tool-chain integration. FreeSASA is an open source C library for SASA calculations that provides both command-line and Python interfaces in addition to its C API. The library implements both Lee and Richards' and Shrake and Rupley's approximations, and is highly configurable to allow the user to control molecular parameters, accuracy and output granularity. It only depends on standard C libraries and should therefore be easy to compile and install on any platform. The library is well-documented, stable and efficient. The command-line interface can easily replace closed source legacy programs, with comparable or better accuracy and speed, and with some added functionality.

  15. Simulation and analysis on thermodynamic performance of surface water source heat pump system

    Institute of Scientific and Technical Information of China (English)

    Nan Lv; Qing Zhang; Zhenqian Chen; Dongsheng Wu

    2017-01-01

    This work established a thermodynamic performance model of a heat pump system containing a heat pump unit model, an air conditioning cooling and heating load calculation model, a heat exchanger model and a water pump performance model based on mass and energy balances. The thermodynamic performance of a surface water source heat pump air conditioning system was simulated and verified by comparing the simulation results to an actual engineering project. In addition, the effects of the surface water temperature, heat exchanger structure and surface water pipeline transportation system on the thermodynamic performance of the heat pump air conditioning system were analyzed. Under the simulated conditions in this paper with a cooling load of 3400 kW, the results showed that a 1 ℃ decrease in the surface water temperature leads to a 2.3 percent increase in the coefficient of performance; furthermore, an additional 100 m of length for the closed-loop surface water heat exchanger tube leads to a 0.08 percent increase in the coefficient of performance. To decrease the system energy consumption, the optimal working point should be specified according to the surface water transportation length.

  16. Distribution and sources of n-alkanes in surface sediments of Taihu Lake, China

    Directory of Open Access Journals (Sweden)

    Yu Yunlong

    2016-03-01

    Full Text Available The last study on n-alkanes in surface sediments of Taihu Lake was in 2000, only 13 surface sediment samples were analysed, in order to have a comprehensive and up-to-date understanding of n-alkanes in the surface sediments of Taihu Lake, 41 surface sediment samples were analyzed by GC-MS. C10 to C37 were detected, the total concentrations of n-alkanes ranged from 2109 ng g−1 to 9096 ng g−1 (dry weight. There was strong odd carbon predominance in long chain n-alkanes and even carbon predominance in short chain n-alkanes. When this finding was combined with the analysis results of wax n-alkanes (WaxCn, carbon preference index (CPI, unresolved complex mixture (UCM, hopanes and steranes, it was considered that the long chain n-alkanes were mainly from terrigenous higher plants, and that the short chain n-alkanes mainly originated from bacteria and algae in the lake, compared with previous studies, there were no obvious anthropogenic petrogenic inputs. Terrestrial and aquatic hydrocarbons ratio (TAR and C21−/C25+ indicated that terrigenous input was higher than aquatic sources and the nearshore n-alkanes were mainly from land-derived sources. Moreover, the distribution of short chain n-alkanes presented a relatively uniform pattern, while the long chain n-alkanes presented a trend that concentrations dropped from nearshore places to the middle of lake.

  17. Integrated nanohole array surface plasmon resonance sensing device using a dual-wavelength source

    International Nuclear Information System (INIS)

    Escobedo, C; Vincent, S; Choudhury, A I K; Campbell, J; Gordon, R; Brolo, A G; Sinton, D

    2011-01-01

    In this paper, we demonstrate a compact integrated nanohole array-based surface plasmon resonance sensing device. The unit includes a LED light source, driving circuitry, CCD detector, microfluidic network and computer interface, all assembled from readily available commercial components. A dual-wavelength LED scheme was implemented to increase spectral diversity and isolate intensity variations to be expected in the field. The prototype shows bulk sensitivity of 266 pixel intensity units/RIU and a limit of detection of 6 × 10 −4 RIU. Surface binding tests were performed, demonstrating functionality as a surface-based sensing system. This work is particularly relevant for low-cost point-of-care applications, especially those involving multiple tests and field studies. While nanohole arrays have been applied to many sensing applications, and their suitability to device integration is well established, this is the first demonstration of a fully integrated nanohole array-based sensing device.

  18. Inner surface modification of a tube by magnetic glow-arc plasma source ion implantation

    International Nuclear Information System (INIS)

    Zhang Guling; Chinese Academy of Sciences, Beijing; Wang Jiuli; Feng Wenran; Chen Guangliang; Gu Weichao; Niu Erwu; Fan Songhua; Liu Chizi; Yang Size; Wu Xingfang

    2006-01-01

    A new method named the magnetic glow-arc plasma source ion implantation (MGA-PSII) is proposed for inner surface modification of tubes. In MGA-PSII, under the control of an axial magnetic field, which is generated by an electric coil around the tube sample, glow arc plasma moves spirally into the tube from its two ends. A negative voltage applied on the tube realized its inner surface implantation. Titanium nitride (TiN) films are prepared on the inner surface of a stainless steel tube in diameter 90 mm and length 600 mm. Hardness tests show that the hardness at the tube centre is up to 20 GPa. XRD, XPS and AES analyses demonstrate that good quality of TiN films can be achieved. (authors)

  19. Inner Surface Modification of a Tube by Magnetic Glow-Arc Plasma Source Ion Implantation

    Science.gov (United States)

    Zhang, Gu-Ling; Wang, Jiu-Li; Wu, Xing-Fang; Feng, Wen-Ran; Chen, Guang-Liang; Gu, Wei-Chao; Niu, Er-Wu; Fan, Song-Hua; Liu, Chi-Zi; Yang, Si-Ze

    2006-05-01

    A new method named the magnetic glow-arc plasma source ion implantation (MGA-PSII) is proposed for inner surface modification of tubes. In MGA-PSII, under the control of an axial magnetic field, which is generated by an electric coil around the tube sample, glow arc plasma moves spirally into the tube from its two ends. A negative voltage applied on the tube realized its inner surface implantation. Titanium nitride (TiN) films are prepared on the inner surface of a stainless steel tube in diameter 90 mm and length 600 mm. Hardness tests show that the hardness at the tube centre is up to 20 GPa. XRD, XPS and AES analyses demonstrate that good quality of TiN films can be achieved.

  20. Geochemically structural characteristics of municipal solid waste incineration fly ash particles and mineralogical surface conversions by chelate treatment.

    Science.gov (United States)

    Kitamura, Hiroki; Sawada, Takaya; Shimaoka, Takayuki; Takahashi, Fumitake

    2016-01-01

    Leaching behaviors of heavy metals contained in municipal solid waste incineration (MSWI) fly ash have been studied well. However, micro-characteristics of MSWI fly ash particles are still uncertain and might be non-negligible to describe their leaching behaviors. Therefore, this study investigated micro-characteristics of MSWI fly ash particles, especially their structural properties and impacts of chelate treatment on surface characteristics. According to SEM observations, raw fly ash particles could be categorized into four types based on their shapes. Because chelate treatment changed the surface of fly ash particles dramatically owing to secondary mineral formations like ettringite, two more types could be categorized for chelate-treated fly ash particles. Acid extraction experiments suggest that fly ash particles, tested in this study, consist of Si-base insoluble core structure, Al/Ca/Si-base semi-soluble matrices inside the body, and KCl/NaCl-base soluble aggregates on the surface. Scanning electron microscope (SEM) observations of the same fly ash particles during twice moistening treatments showed that KCl/NaCl moved under wet condition and concentrated at different places on the particle surface. However, element mobility depended on secondary mineral formations. When insoluble mineral like gypsum was generated and covered the particle surface, it inhibited element transfer under wet condition. Surface characteristics including secondary mineral formation of MSWI fly ash particles are likely non-negligible to describe trace element leaching behaviors.

  1. Energy conversion by ‘T-shaped’ cantilever type electromagnetic vibration based micro power generator from low frequency vibration sources

    International Nuclear Information System (INIS)

    Siddique, Abu Raihan Mohammad; Mahmud, Shohel; Van Heyst, Bill

    2017-01-01

    Highlights: • A T-shaped cantilever type electromagnetic vibration based MPG has been described. • The designed EVMPG is useful for low frequency based vibration sources. • Both experimental tests and theoretical analysis have been performed. • The final compact prototype was tested at different conditions of human movements. • The prototype can generate 35.2 mV and 0.22 mW at 7 Hz with 5.6 Ω. - Abstract: The design, development, and analyses of low-frequency vibration based T-shaped cantilever type electromagnetic micro power generators (EVMPGs) are presented in this paper. Four different configurations (Configurations A to D) of EVMPGs were designed and fabricated and subsequently characterized using detailed experimental and limited analytical techniques. Configuration A and B consisted of a single and a double cylindrical moving magnets (NdFeB), respectively, while Configuration C consisted of four rectangular moving magnets with respect to a fixed copper coil. In contrast, Configuration D used a moving coil between four rectangular magnets with a back-iron bar. The open circuit RMS voltage output was observed to be a maximum from Configuration D (98.2 mV at 6.29 Hz) with a base vibration acceleration of 0.8 m s"−"2. Therefore, Configuration D was selected for further experimental investigations, which included changing the back-iron bar thickness, changing the base acceleration level, and changing the air gap separation between the magnets in order to optimize this configuration. The maximum load RMS voltage and power outputs of Configuration D were 105.4 mV and 1.35 mW at 6.29 Hz for load resistance 8.2 Ω and a base acceleration of 0.8 m s"−"2 with a 4.2 mm back-iron bar when the air gap between the magnets was 20 mm. Finally, a small portable EVMPG prototype was developed based on the Configuration D and was tested at different human movement conditions (i.e., walking, quick walking, and running). The developed EVMPG prototype was capable of

  2. Selective detection of Fe and Mn species at mineral surfaces in weathered granite by conversion electron yield X-ray absorption fine structure

    International Nuclear Information System (INIS)

    Itai, Takaaki; Takahashi, Yoshio; Uruga, Tomoya; Tanida, Hajime; Iida, Atsuo

    2008-01-01

    A new method for the speciation of Fe and Mn at mineral surfaces is proposed using X-ray absorption fine structure in conversion electron yield mode (CEY-XAFS). This method generally reflects information on the species at the sub-μm scale from the particle surface due to the limited escape depth of the inelastic Auger electron. The surface sensitivity of this method was assessed by experiments on two samples of granite showing different degrees of weathering. The XANES spectra of the Fe-K and Mn-K edge clearly gave different information for CEY and fluorescence (FL) modes. These XANES spectra of Fe and Mn show a good fit upon application of least-squares fitting using ferrihydrite/MnO 2 and biotite as the end members. The XANES spectra collected by CEY mode provided more selective information on the secondary phases which are probably present at the mineral surfaces. In particular, CEY-XANES spectra of Mn indicated the presence of Mn oxide in unweathered granite despite a very small contribution of Mn oxide being indicated by FL-XANES and selective chemical-extraction analyses. Manganese oxide could not be detected by micro-beam XANES (beam size: 5 x 5 μm 2 ) in unweathered granite, suggesting that Mn oxide thinly and ubiquitously coats mineral surface at a sub-μm scale. This information is important, since Mn oxide can be the host for various trace elements. CEY-XAFS can prove to be a powerful tool as a highly sensitive surface speciation method. Combination of CEY and FL-XAFS will help identify minor phases that form at mineral surfaces, but identification of Fe and Mn oxides at mineral surfaces is critical to understand the migration of trace elements in water-rock interaction

  3. Selective detection of Fe and Mn species at mineral surfaces in weathered granite by conversion electron yield X-ray absorption fine structure

    Energy Technology Data Exchange (ETDEWEB)

    Itai, Takaaki [Department of Earth and Planetary Systems Science, Hiroshima University, Kagamiyama, Higashi-Hiroshima, Hiroshima 739-8526 (Japan)], E-mail: itai-epss@hiroshima-u.ac.jp; Takahashi, Yoshio [Department of Earth and Planetary Systems Science, Hiroshima University, Kagamiyama, Higashi-Hiroshima, Hiroshima 739-8526 (Japan); Uruga, Tomoya; Tanida, Hajime [Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Iida, Atsuo [Photon Factory, National Laboratory for High Energy Physics, O-ho, Tsukuba, Ibaraki 305 (Japan)

    2008-09-15

    A new method for the speciation of Fe and Mn at mineral surfaces is proposed using X-ray absorption fine structure in conversion electron yield mode (CEY-XAFS). This method generally reflects information on the species at the sub-{mu}m scale from the particle surface due to the limited escape depth of the inelastic Auger electron. The surface sensitivity of this method was assessed by experiments on two samples of granite showing different degrees of weathering. The XANES spectra of the Fe-K and Mn-K edge clearly gave different information for CEY and fluorescence (FL) modes. These XANES spectra of Fe and Mn show a good fit upon application of least-squares fitting using ferrihydrite/MnO{sub 2} and biotite as the end members. The XANES spectra collected by CEY mode provided more selective information on the secondary phases which are probably present at the mineral surfaces. In particular, CEY-XANES spectra of Mn indicated the presence of Mn oxide in unweathered granite despite a very small contribution of Mn oxide being indicated by FL-XANES and selective chemical-extraction analyses. Manganese oxide could not be detected by micro-beam XANES (beam size: 5 x 5 {mu}m{sup 2}) in unweathered granite, suggesting that Mn oxide thinly and ubiquitously coats mineral surface at a sub-{mu}m scale. This information is important, since Mn oxide can be the host for various trace elements. CEY-XAFS can prove to be a powerful tool as a highly sensitive surface speciation method. Combination of CEY and FL-XAFS will help identify minor phases that form at mineral surfaces, but identification of Fe and Mn oxides at mineral surfaces is critical to understand the migration of trace elements in water-rock interaction.

  4. Insight into the mechanism of methanol assistance with syngas conversion over partially hydroxylated γ-Al2O3(110D) surface in slurry bed.

    Science.gov (United States)

    Bai, Bing; Bai, Hui; Cao, Hao-Jie; Gao, Zhi-Hua; Zuo, Zhi-Jun; Huang, Wei

    2018-04-27

    Despite numerous studies devoted to the various properties of γ-Al2O3, the explorations of its catalytic activity remain scarce. In this study, density functional theory calculations are performed to study the elementary adsorption and reaction mechanisms for syngas conversion on partially hydroxylated γ-Al2O3(110D) surface in liquid paraffin. It is found that the partially hydroxylated γ-Al2O3(110D) surface with the hydroxyl coverage of 8.9 OH nm-2 is formed by two dissociative adsorptions of H2O on the dry γ-Al2O3(110D) surface. The hydroxyl coverage conditions play a key role in determining the dominant reaction mechanism on account of the existence of strong hydrogen bonds. The preferential pathway for syngas conversion with assistance of methanol over the partially hydroxylated γ-Al2O3(110D) surface in liquid paraffin has been proven to be CH3OH → CH3O + H → CH3 + OH, CH3 + CO → CH3CO. C2H5OH is then formed by successive hydrogenation via the pathway CH3CO + 3H → CH3CHO + 2H → CH3CH2O + H → C2H5OH. Here, CH3CHO formation by CH3CO hydrogenation is not inhibited. Actually, with the assistance of partially hydroxylated γ-Al2O3, CH3CHO has been synthesized with high selectivity in our previous experiment by the reaction of methanol and syngas, which provides favorable evidence for our results. The rate-limiting step is the formation of CH3O from CH3OH dehydrogenation with an activation barrier of 122.2 kJ mol-1. Moreover, the reaction barrier of CO insertion into the adsorbed CH3 group is at least 89.4 kJ mol-1, lower than those of CH4, C2H6, and CH3OCH3 formations. ADCH charge and ESP analyses indicate that the typical (Al, O) Lewis acid-base pair may have a significant effect upon the initial C-C chain formation. Thus, the present study provides a new approach for the rational tailoring and designing of new catalysts with superior reactivity involved in syngas conversion.

  5. Passive monitoring for near surface void detection using traffic as a seismic source

    Science.gov (United States)

    Zhao, Y.; Kuzma, H. A.; Rector, J.; Nazari, S.

    2009-12-01

    In this poster we present preliminary results based on our several field experiments in which we study seismic detection of voids using a passive array of surface geophones. The source of seismic excitation is vehicle traffic on nearby roads, which we model as a continuous line source of seismic energy. Our passive seismic technique is based on cross-correlation of surface wave fields and studying the resulting power spectra, looking for "shadows" caused by the scattering effect of a void. High frequency noise masks this effect in the time domain, so it is difficult to see on conventional traces. Our technique does not rely on phase distortions caused by small voids because they are generally too tiny to measure. Unlike traditional impulsive seismic sources which generate highly coherent broadband signals, perfect for resolving phase but too weak for resolving amplitude, vehicle traffic affords a high power signal a frequency range which is optimal for finding shallow structures. Our technique results in clear detections of an abandoned railroad tunnel and a septic tank. The ultimate goal of this project is to develop a technology for the simultaneous imaging of shallow underground structures and traffic monitoring near these structures.

  6. Spatial assessment and source identification of heavy metals pollution in surface water using several chemometric techniques.

    Science.gov (United States)

    Ismail, Azimah; Toriman, Mohd Ekhwan; Juahir, Hafizan; Zain, Sharifuddin Md; Habir, Nur Liyana Abdul; Retnam, Ananthy; Kamaruddin, Mohd Khairul Amri; Umar, Roslan; Azid, Azman

    2016-05-15

    This study presents the determination of the spatial variation and source identification of heavy metal pollution in surface water along the Straits of Malacca using several chemometric techniques. Clustering and discrimination of heavy metal compounds in surface water into two groups (northern and southern regions) are observed according to level of concentrations via the application of chemometric techniques. Principal component analysis (PCA) demonstrates that Cu and Cr dominate the source apportionment in northern region with a total variance of 57.62% and is identified with mining and shipping activities. These are the major contamination contributors in the Straits. Land-based pollution originating from vehicular emission with a total variance of 59.43% is attributed to the high level of Pb concentration in the southern region. The results revealed that one state representing each cluster (northern and southern regions) is significant as the main location for investigating heavy metal concentration in the Straits of Malacca which would save monitoring cost and time. The monitoring of spatial variation and source of heavy metals pollution at the northern and southern regions of the Straits of Malacca, Malaysia, using chemometric analysis. Copyright © 2015 Elsevier Ltd. All rights reserved.

  7. Modification of anti-bacterial surface properties of textile polymers by vacuum arc ion source implantation

    International Nuclear Information System (INIS)

    Nikolaev, A.G.; Yushkov, G.Yu.; Oks, E.M.; Oztarhan, A.; Akpek, A.; Hames-Kocabas, E.; Urkac, E.S.; Brown, I.G.

    2014-01-01

    Highlights: • Ion implantation. • Anti-bacterial properties. • Textile polymer. • Vacuum arc ion source. - Abstract: Ion implantation provides an important technology for the modification of material surface properties. The vacuum arc ion source is a unique instrument for the generation of intense beams of metal ions as well as gaseous ions, including mixed metal–gas beams with controllable metal:gas ion ratio. Here we describe our exploratory work on the application of vacuum arc ion source-generated ion beams for ion implantation into polymer textile materials for modification of their biological cell compatibility surface properties. We have investigated two specific aspects of cell compatibility: (i) enhancement of the antibacterial characteristics (we chose to use Staphylococcus aureus bacteria) of ion implanted polymer textile fabric, and (ii) the “inverse” concern of enhancement of neural cell growth rate (we chose Rat B-35 neuroblastoma cells) on ion implanted polymer textile. The results of both investigations were positive, with implantation-generated antibacterial efficiency factor up to about 90%, fully comparable to alternative conventional (non-implantation) approaches and with some potentially important advantages over the conventional approach; and with enhancement of neural cell growth rate of up to a factor of 3.5 when grown on suitably implanted polymer textile material

  8. Measurements of the cesium flow from a surface-plasma H- ion source

    International Nuclear Information System (INIS)

    Smith, H.V.; Allison, P.W.

    1979-01-01

    A surface ionization gauge (SIG) was constructed and used to measure the Cs 0 flow rate through the emission slit of a surface-plasma source (SPS) of H - ions with Penning geometry. The equivalent cesium density in the SPS discharge is deduced from these flow measurements. For dc operation the optimum H - current occurs at an equivalent cesium density of approx. 7 x 10 12 cm -3 (corresponding to an average cesium consumption rate of 0.5 mg/h). For pulsed operation the optimum H - current occurs at an equivalent cesium density of approx. 2 x 10 13 cm -3 (1-mg/h average cesium consumption rate). Cesium trapping by the SPS discharge was observed for both dc and pulsed operation. A cesium energy of approx. 0.1 eV is deduced from the observed time of flight to the SIG. In addition to providing information on the physics of the source, the SIG is a useful diagnostic tool for source startup and operation

  9. Modification of anti-bacterial surface properties of textile polymers by vacuum arc ion source implantation

    Energy Technology Data Exchange (ETDEWEB)

    Nikolaev, A.G., E-mail: nik@opee.hcei.tsc.ru [High Current Electronics Institute, Siberian Branch of the Russian Academy of Sciences, Tomsk 634055 (Russian Federation); Yushkov, G.Yu.; Oks, E.M. [High Current Electronics Institute, Siberian Branch of the Russian Academy of Sciences, Tomsk 634055 (Russian Federation); Oztarhan, A. [Izmir University, Izmir 35140 (Turkey); Akpek, A.; Hames-Kocabas, E.; Urkac, E.S. [Bioengineering Department, Ege University, Bornova 35100, Izmir (Turkey); Brown, I.G. [Lawrence Berkeley National Laboratory, Berkeley, CA 94708 (United States)

    2014-08-15

    Highlights: • Ion implantation. • Anti-bacterial properties. • Textile polymer. • Vacuum arc ion source. - Abstract: Ion implantation provides an important technology for the modification of material surface properties. The vacuum arc ion source is a unique instrument for the generation of intense beams of metal ions as well as gaseous ions, including mixed metal–gas beams with controllable metal:gas ion ratio. Here we describe our exploratory work on the application of vacuum arc ion source-generated ion beams for ion implantation into polymer textile materials for modification of their biological cell compatibility surface properties. We have investigated two specific aspects of cell compatibility: (i) enhancement of the antibacterial characteristics (we chose to use Staphylococcus aureus bacteria) of ion implanted polymer textile fabric, and (ii) the “inverse” concern of enhancement of neural cell growth rate (we chose Rat B-35 neuroblastoma cells) on ion implanted polymer textile. The results of both investigations were positive, with implantation-generated antibacterial efficiency factor up to about 90%, fully comparable to alternative conventional (non-implantation) approaches and with some potentially important advantages over the conventional approach; and with enhancement of neural cell growth rate of up to a factor of 3.5 when grown on suitably implanted polymer textile material.

  10. Clostridium difficile from food and surface samples in a Belgian nursing home: an unlikely source of contamination.

    Science.gov (United States)

    Rodriguez, C; Korsak, N; Taminiau, B; Avesani, V; Van Broeck, J; Brach, P; Delmée, M; Daube, G

    2015-04-01

    This study investigates the contamination of foods and surfaces with Clostridium difficile in a single nursing home. C. difficile PCR-ribotype 078 was found in one food sample and in none of the tested surfaces. These results indicate that food and surfaces are an unlikely source of C. difficile infection in this setting. Copyright © 2015 Elsevier Ltd. All rights reserved.

  11. VUV absorption spectroscopy of a Penning surface-plasma H- source

    International Nuclear Information System (INIS)

    Pitcher, E.J.

    1992-01-01

    Because H - is efficiently neutralized at high energies, these beams are ideally suited to applications where energetic neutral beams of particles are required to propagate across magnetic fields. A class of sources that holds great promise for meeting the stringent requirements for these beams is the surface-plasma source (SPS), and in particular, the Penning type of SPS. It has been conjectured that atomic hydrogen plays an important role in both H - formation and transport in these sources. Understanding the interdependence of atomic hydrogen properties and those of H - , and how this relationship might be exploited to improve source performance is the motivation for this research. An overview of SPS's is presented. Previous measurements on the discharge are reviewed. Absorption spectroscopy is discussed. Techniques that may potentially be used to measure the properties of H - in the discharge are discussed. The two absorption spectrometers used in this experiment are described. Measurements of ground-state atomic hydrogen density and temperature in a Penning SPS are presented. These measurements are the first of this kind for this type of discharge. An upper limit on the H - density in the extraction region of the source is measured by the application of a novel diagnostic technique: the hydrogen atom density following H - photodetachment by a Nd:YAG beam is measured and compared to the equilibrium atomic density. A simple model is derived that describes the dependence of the atomic temperature on the externally-controlled parameters of discharge current and H 2 gas flow. The measured atomic density is considered in light of the widely-accepted hypothesis of the mechanism for H - formation. The measured upper limit of the H - density is used to infer the potential of the discharge plasma relative to the source anode

  12. Theory for source-responsive and free-surface film modeling of unsaturated flow

    Science.gov (United States)

    Nimmo, J.R.

    2010-01-01

    A new model explicitly incorporates the possibility of rapid response, across significant distance, to substantial water input. It is useful for unsaturated flow processes that are not inherently diffusive, or that do not progress through a series of equilibrium states. The term source-responsive is used to mean that flow responds sensitively to changing conditions at the source of water input (e.g., rainfall, irrigation, or ponded infiltration). The domain of preferential flow can be conceptualized as laminar flow in free-surface films along the walls of pores. These films may be considered to have uniform thickness, as suggested by field evidence that preferential flow moves at an approximately uniform rate when generated by a continuous and ample water supply. An effective facial area per unit volume quantitatively characterizes the medium with respect to source-responsive flow. A flow-intensity factor dependent on conditions within the medium represents the amount of source-responsive flow at a given time and position. Laminar flow theory provides relations for the velocity and thickness of flowing source-responsive films. Combination with the Darcy-Buckingham law and the continuity equation leads to expressions for both fluxes and dynamic water contents. Where preferential flow is sometimes or always significant, the interactive combination of source-responsive and diffuse flow has the potential to improve prediction of unsaturated-zone fluxes in response to hydraulic inputs and the evolving distribution of soil moisture. Examples for which this approach is efficient and physically plausible include (i) rainstorm-generated rapid fluctuations of a deep water table and (ii) space- and time-dependent soil water content response to infiltration in a macroporous soil. ?? Soil Science Society of America.

  13. Simulation of ultrasonic surface waves with multi-Gaussian and point source beam models

    International Nuclear Information System (INIS)

    Zhao, Xinyu; Schmerr, Lester W. Jr.; Li, Xiongbing; Sedov, Alexander

    2014-01-01

    In the past decade, multi-Gaussian beam models have been developed to solve many complicated bulk wave propagation problems. However, to date those models have not been extended to simulate the generation of Rayleigh waves. Here we will combine Gaussian beams with an explicit high frequency expression for the Rayleigh wave Green function to produce a three-dimensional multi-Gaussian beam model for the fields radiated from an angle beam transducer mounted on a solid wedge. Simulation results obtained with this model are compared to those of a point source model. It is shown that the multi-Gaussian surface wave beam model agrees well with the point source model while being computationally much more efficient

  14. Pulse explosion ion beam source with one pulse regime supply for surface modification of materials

    International Nuclear Information System (INIS)

    Korenev, S.A.

    1989-01-01

    A variant of explosion ion beam source with one positive pulse supply for surface modification of materials is described. Ion source consists of vacuum diode and pulse generator Arcadiev-Marx type. Residual gas pressure was p∼5x10 -5 torr in the diode. The sort of ions was fixed by materials initiator anode plasma. The produce carbon ions a carbon-fibrous initiator is used for niobium and titanium-niobium-titanium cable with picking copper matrix. The ions density current regulation is realized by by change of diode gap in the correspondence with Child-Langmuir law. For carbon ions the current density is j∼6A/cm 2 for voltage U∼100kV and j∼32A/cm 2 for voltage U∼300 kV. 7 refs.; 1 fig

  15. Silicon surface barrier detector and study of energy spectrum of alpha particles from radioactive source

    International Nuclear Information System (INIS)

    Verma, S.D.; Sinha, Vijaya

    1986-01-01

    The principles of working of three commonly used radiation detectors, namely ionization chambers, scintillation counters with photomultiplier tube (PMT) systems and semiconductor detectors are briefly discussed. Out of the semiconductor detectors, the silicon surface barrier (SSB) detector has distinct advantages for detection of radiations, alpha particles in particular. The experimental setup to obtain the energy spectrum of alpha particles from 241 Am source using SSB fabricated in the Physics Department of Gujarat University, Ahmedabad is described. Its performance is compared with scintillation counter using PMT. SSB detector shows a sharp peak of #approx # 3 per cent energy resolution. The factors affecting the peak, namely, electronic noise, source dependent factors and detector-dependent factors are discussed. A method of calibrating SSB detectors based on energy loss mechanism of alpha particles in thin absorbers is described. Applications of such detectors are indicated. (M.G.B.)

  16. Point, surface and volumetric heat sources in the thermal modelling of selective laser melting

    Science.gov (United States)

    Yang, Yabin; Ayas, Can

    2017-10-01

    Selective laser melting (SLM) is a powder based additive manufacturing technique suitable for producing high precision metal parts. However, distortions and residual stresses within products arise during SLM because of the high temperature gradients created by the laser heating. Residual stresses limit the load resistance of the product and may even lead to fracture during the built process. It is therefore of paramount importance to predict the level of part distortion and residual stress as a function of SLM process parameters which requires a reliable thermal modelling of the SLM process. Consequently, a key question arises which is how to describe the laser source appropriately. Reasonable simplification of the laser representation is crucial for the computational efficiency of the thermal model of the SLM process. In this paper, first a semi-analytical thermal modelling approach is described. Subsequently, the laser heating is modelled using point, surface and volumetric sources, in order to compare the influence of different laser source geometries on the thermal history prediction of the thermal model. The present work provides guidelines on appropriate representation of the laser source in the thermal modelling of the SLM process.

  17. Surface Grafting of Ru(II) Diazonium-Based Sensitizers on Metal Oxides Enhances Alkaline Stability for Solar Energy Conversion.

    Science.gov (United States)

    Bangle, Rachel; Sampaio, Renato N; Troian-Gautier, Ludovic; Meyer, Gerald J

    2018-01-24

    The electrografting of [Ru(ttt)(tpy-C 6 H 4 -N 2 + )] 3+ , where "ttt" is 4,4',4″-tri-tert-butyl-2,2':6',2″-terpyridine, was investigated on several wide band gap metal oxide surfaces (TiO 2 , SnO 2 , ZrO 2 , ZnO, In 2 O 3 :Sn) and compared to structurally analogous sensitizers that differed only by the anchoring group, i.e., -PO 3 H 2 and -COOH. An optimized procedure for diazonium electrografting to semiconductor metal oxides is presented that allowed surface coverages that ranged between 4.7 × 10 -8 and 10.6 × 10 -8 mol cm -2 depending on the nature of the metal oxide. FTIR analysis showed the disappearance of the diazonium stretch at 2266 cm -1 after electrografting. XPS analysis revealed a characteristic peak of Ru 3d at 285 eV as well as a peak at 531.6 eV that was attributed to O 1s in Ti-O-C bonds. Photocurrents were measured to assess electron injection efficiency of these modified surfaces. The electrografted sensitizers exhibited excellent stability across a range of pHs spanning from 1 to 14, where classical binding groups such as carboxylic and phosphonic derivatives were hydrolyzed.

  18. Skeletonized inversion of surface wave: Active source versus controlled noise comparison

    KAUST Repository

    Li, Jing; Hanafy, Sherif

    2016-01-01

    We have developed a skeletonized inversion method that inverts the S-wave velocity distribution from surface-wave dispersion curves. Instead of attempting to fit every wiggle in the surface waves with predicted data, it only inverts the picked dispersion curve, thereby mitigating the problem of getting stuck in a local minimum. We have applied this method to a synthetic model and seismic field data from Qademah fault, located at the western side of Saudi Arabia. For comparison, we have performed dispersion analysis for an active and controlled noise source seismic data that had some receivers in common with the passive array. The active and passive data show good agreement in the dispersive characteristics. Our results demonstrated that skeletonized inversion can obtain reliable 1D and 2D S-wave velocity models for our geologic setting. A limitation is that we need to build layered initial model to calculate the Jacobian matrix, which is time consuming.

  19. Skeletonized inversion of surface wave: Active source versus controlled noise comparison

    KAUST Repository

    Li, Jing

    2016-07-14

    We have developed a skeletonized inversion method that inverts the S-wave velocity distribution from surface-wave dispersion curves. Instead of attempting to fit every wiggle in the surface waves with predicted data, it only inverts the picked dispersion curve, thereby mitigating the problem of getting stuck in a local minimum. We have applied this method to a synthetic model and seismic field data from Qademah fault, located at the western side of Saudi Arabia. For comparison, we have performed dispersion analysis for an active and controlled noise source seismic data that had some receivers in common with the passive array. The active and passive data show good agreement in the dispersive characteristics. Our results demonstrated that skeletonized inversion can obtain reliable 1D and 2D S-wave velocity models for our geologic setting. A limitation is that we need to build layered initial model to calculate the Jacobian matrix, which is time consuming.

  20. Convergent evidence for widespread rock nitrogen sources in Earth's surface environment.

    Science.gov (United States)

    Houlton, B Z; Morford, S L; Dahlgren, R A

    2018-04-06

    Nitrogen availability is a pivotal control on terrestrial carbon sequestration and global climate change. Historical and contemporary views assume that nitrogen enters Earth's land-surface ecosystems from the atmosphere. Here we demonstrate that bedrock is a nitrogen source that rivals atmospheric nitrogen inputs across major sectors of the global terrestrial environment. Evidence drawn from the planet's nitrogen balance, geochemical proxies, and our spatial weathering model reveal that ~19 to 31 teragrams of nitrogen are mobilized from near-surface rocks annually. About 11 to 18 teragrams of this nitrogen are chemically weathered in situ, thereby increasing the unmanaged (preindustrial) terrestrial nitrogen balance from 8 to 26%. These findings provide a global perspective to reconcile Earth's nitrogen budget, with implications for nutrient-driven controls over the terrestrial carbon sink. Copyright © 2018 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.

  1. Convergent evidence for widespread rock nitrogen sources in Earth’s surface environment

    Science.gov (United States)

    Houlton, B. Z.; Morford, S. L.; Dahlgren, R. A.

    2018-04-01

    Nitrogen availability is a pivotal control on terrestrial carbon sequestration and global climate change. Historical and contemporary views assume that nitrogen enters Earth’s land-surface ecosystems from the atmosphere. Here we demonstrate that bedrock is a nitrogen source that rivals atmospheric nitrogen inputs across major sectors of the global terrestrial environment. Evidence drawn from the planet’s nitrogen balance, geochemical proxies, and our spatial weathering model reveal that ~19 to 31 teragrams of nitrogen are mobilized from near-surface rocks annually. About 11 to 18 teragrams of this nitrogen are chemically weathered in situ, thereby increasing the unmanaged (preindustrial) terrestrial nitrogen balance from 8 to 26%. These findings provide a global perspective to reconcile Earth’s nitrogen budget, with implications for nutrient-driven controls over the terrestrial carbon sink.

  2. Meniscus and beam halo formation in a tandem-type negative ion source with surface production

    International Nuclear Information System (INIS)

    Miyamoto, K.; Okuda, S.; Hatayama, A.

    2012-01-01

    A meniscus of plasma-beam boundary in H - ion sources largely affects the extracted H - ion beam optics. Although it is hypothesized that the shape of the meniscus is one of the main reasons for the beam halo observed in experiments, a physical mechanism of the beam halo formation is not yet fully understood. In this letter, it is first shown by the 2D particle in cell simulation that the H - ions extracted from the periphery of the meniscus cause a beam halo since the surface produced H - ions penetrate into the bulk plasma, and, thus, the resultant meniscus has a relatively large curvature.

  3. High prevalence of enteric viruses in untreated individual drinking water sources and surface water in Slovenia.

    Science.gov (United States)

    Steyer, Andrej; Torkar, Karmen Godič; Gutiérrez-Aguirre, Ion; Poljšak-Prijatelj, Mateja

    2011-09-01

    Waterborne infections have been shown to be important in outbreaks of gastroenteritis throughout the world. Although improved sanitary conditions are being progressively applied, fecal contaminations remain an emerging problem also in developed countries. The aim of our study was to investigate the prevalence of fecal contaminated water sources in Slovenia, including surface waters and groundwater sources throughout the country. In total, 152 water samples were investigated, of which 72 samples represents groundwater from individual wells, 17 samples from public collection supplies and 63 samples from surface stream waters. Two liters of untreated water samples were collected and concentrated by the adsorption/elution technique with positively charged filters followed by an additional ultracentrifugation step. Group A rotaviruses, noroviruses (genogroups I and II) and astroviruses were detected with real-time RT-PCR method in 69 (45.4%) out of 152 samples collected, of which 31/89 (34.8%) drinking water and 38/63 (60.3%) surface water samples were positive for at least one virus tested. In 30.3% of drinking water samples group A rotaviruses were detected (27/89), followed by noroviruses GI (2.2%; 2/89) and astroviruses (2.2%; 2/89). In drinking groundwater samples group A rotaviruses were detected in 27 out of 72 tested samples (37.5%), genogroup I noroviruses in two (2.8%), and human astroviruses in one (1.4%) samples. In surface water samples norovirus genogroup GII was the most frequently detected (41.3%; 26/63), followed by norovirus GI (33.3%; 21/63), human astrovirus (27.0%; 17/63) and group A rotavirus (17.5%; 11/63). Our study demonstrates relatively high percentage of groundwater contamination in Slovenia and, suggests that raw groundwater used as individual drinking water supply may constitute a possible source of enteric virus infections. In the future, testing for enteric viruses should be applied for drinking water sources in waterborne outbreaks

  4. Diagnostics of microwave assisted electron cyclotron resonance plasma source for surface modification of nylon 6

    Science.gov (United States)

    More, Supriya E.; Das, Partha Sarathi; Bansode, Avinash; Dhamale, Gayatri; Ghorui, S.; Bhoraskar, S. V.; Sahasrabudhe, S. N.; Mathe, Vikas L.

    2018-01-01

    Looking at the increasing scope of plasma processing of materials surface, here we present the development and diagnostics of a microwave assisted Electron Cyclotron Resonance (ECR) plasma system suitable for surface modification of polymers. Prior to the surface-treatment, a detailed diagnostic mapping of the plasma parameters throughout the reactor chamber was carried out by using single and double Langmuir probe measurements in Ar plasma. Conventional analysis of I-V curves as well as the elucidation form of the Electron Energy Distribution Function (EEDF) has become the source of calibration of plasma parameters in the reaction chamber. The high energy tail in the EEDF of electron temperature is seen to extend beyond 60 eV, at much larger distances from the ECR zone. This proves the suitability of the rector for plasma processing, since the electron energy is much beyond the threshold energy of bond breaking in most of the polymers. Nylon 6 is used as a representative candidate for surface processing in the presence of Ar, H2 + N2, and O2 plasma, treated at different locations inside the plasma chamber. In a typical case, the work of adhesion is seen to almost get doubled when treated with oxygen plasma. Morphology of the plasma treated surface and its hydrophilicity are discussed in view of the variation in electron density and electron temperature at these locations. Nano-protrusions arising from plasma treatment are set to be responsible for the hydrophobicity. Chemical sputtering and physical sputtering are seen to influence the surface morphology on account of sufficient electron energies and increased plasma potential.

  5. Source tracking swine fecal waste in surface water proximal to swine concentrated animal feeding operations.

    Science.gov (United States)

    Heaney, Christopher D; Myers, Kevin; Wing, Steve; Hall, Devon; Baron, Dothula; Stewart, Jill R

    2015-04-01

    Swine farming has gone through many changes in the last few decades, resulting in operations with a high animal density known as confined animal feeding operations (CAFOs). These operations produce a large quantity of fecal waste whose environmental impacts are not well understood. The purpose of this study was to investigate microbial water quality in surface waters proximal to swine CAFOs including microbial source tracking of fecal microbes specific to swine. For one year, surface water samples at up- and downstream sites proximal to swine CAFO lagoon waste land application sites were tested for fecal indicator bacteria (fecal coliforms, Escherichia coli and Enterococcus) and candidate swine-specific microbial source-tracking (MST) markers (Bacteroidales Pig-1-Bac, Pig-2-Bac, and Pig-Bac-2, and methanogen P23-2). Testing of 187 samples showed high fecal indicator bacteria concentrations at both up- and downstream sites. Overall, 40%, 23%, and 61% of samples exceeded state and federal recreational water quality guidelines for fecal coliforms, E. coli, and Enterococcus, respectively. Pig-1-Bac and Pig-2-Bac showed the highest specificity to swine fecal wastes and were 2.47 (95% confidence interval [CI]=1.03, 5.94) and 2.30 times (95% CI=0.90, 5.88) as prevalent proximal down- than proximal upstream of swine CAFOs, respectively. Pig-1-Bac and Pig-2-Bac were also 2.87 (95% CI=1.21, 6.80) and 3.36 (95% CI=1.34, 8.41) times as prevalent when 48 hour antecedent rainfall was greater than versus less than the mean, respectively. Results suggest diffuse and overall poor sanitary quality of surface waters where swine CAFO density is high. Pig-1-Bac and Pig-2-Bac are useful for tracking off-site conveyance of swine fecal wastes into surface waters proximal to and downstream of swine CAFOs and during rain events. Copyright © 2014 Elsevier B.V. All rights reserved.

  6. The effect of anode surface roughness on radiation output for diagnostic x-ray sources

    International Nuclear Information System (INIS)

    Meghzifene, K.; Nowotny, R.; Aiginger, H.

    2002-01-01

    The calculation of entrance surface dose to patients in diagnostic radiology from tube output data is determined by often-unknown sources of inherent filtration. One of these sources is the roughness of the anode surface increasing with tube ageing. This effect increases the inherent filtration of the x-ray tube noticed by a reduced radiation output and increased half-value layers (HVL). To study this effect used rotating anodes were collected and the surface profile of 8 focal tracks was measured in radial direction using an instrument with a diamond tipped stylus (90 deg. tip, 1 μm radius). Surface roughness was determined as the arithmetic mean R a of the deviation in the profile from the centre line for 200 μm reference lengths ranging from 1.32 μm (sandblasted finish without surface degradation) to 5.22 μm (a track for a small focus). The surface profiles were then used to calculate x-ray spectra using a computer code. For each surface about 40000 spectra were calculated with the electrons entering the anode at random position and spectral parameters were then determined. The simulation showed that for rough surfaces the x-rays have to penetrate an additional absorbing layer of tungsten increasing in thickness with anode roughness. The anode with the roughest focal track (R a =5.22 μm) yields a mean additional absorber thickness in direction of the x-ray beam of about 18 μm. The corresponding loss in air kerma for this anode was about 20% at 70 kVp. The effect on mean photon energy is rather small but highest at 70 kVp (+1 keV at R a =5.22 μm) and lowest at 140 kVp (∼0 keV). This is due to the K-edge in the attenuation coefficients of tungsten at 69.5 keV. Beam hardening is thus reduced for higher voltages as absorption at lower photon energies is balanced by higher absorption above the K-edge while at lower voltages beam hardening is fully effective. The pattern of changes in HVL is more complex but in essence also reflects voltage, roughness and

  7. Evaluation of Skin Surface as an Alternative Source of Reference DNA Samples: A Pilot Study.

    Science.gov (United States)

    Albujja, Mohammed H; Bin Dukhyil, Abdul Aziz; Chaudhary, Abdul Rauf; Kassab, Ahmed Ch; Refaat, Ahmed M; Babu, Saranya Ramesh; Okla, Mohammad K; Kumar, Sachil

    2018-01-01

    An acceptable area for collecting DNA reference sample is a part of the forensic DNA analysis development. The aim of this study was to evaluate skin surface cells (SSC) as an alternate source of reference DNA sample. From each volunteer (n = 10), six samples from skin surface areas (forearm and fingertips) and two traditional samples (blood and buccal cells) were collected. Genomic DNA was extracted and quantified then genotyped using standard techniques. The highest DNA concentration of SSC samples was collected using the tape/forearm method of collection (2.1 ng/μL). Cotton swabs moistened with ethanol yielded higher quantities of DNA than swabs moistened with salicylic acid, and it gave the highest percentage of full STR profiles (97%). This study supports the use of SSC as a noninvasive sampling technique and as a extremely useful source of DNA reference samples among certain cultures where the use of buccal swabs can be considered socially unacceptable. © 2017 American Academy of Forensic Sciences.

  8. Revisiting the paper “Using radiometric surface temperature for surface energy flux estimation in Mediterranean drylands from a two-source perspective”

    DEFF Research Database (Denmark)

    Kustas, William P.; Nieto, Hector; Morillas, Laura

    2016-01-01

    The recent paper by Morillas et al. [Morillas, L. et al. Using radiometric surface temperature for surface energy flux estimation in Mediterranean drylands from a two-source perspective, Remote Sens. Environ. 136, 234–246, 2013] evaluates the two-source model (TSM) of Norman et al. (1995) with re......The recent paper by Morillas et al. [Morillas, L. et al. Using radiometric surface temperature for surface energy flux estimation in Mediterranean drylands from a two-source perspective, Remote Sens. Environ. 136, 234–246, 2013] evaluates the two-source model (TSM) of Norman et al. (1995......) with revisions by Kustas and Norman (1999) over a semiarid tussock grassland site in southeastern Spain. The TSM - in its current incarnation, the two-source energy balance model (TSEB) - was applied to this landscape using ground-based infrared radiometer sensors to estimate both the composite surface...... greenness and local leaf area index values as well as modifications to the coefficients of the soil resistance formulation to account for the very rough (rocky) soil surface conditions with a clumped canopy. This indicates that both limitations in remote estimates of biophysical indicators of the canopy...

  9. Surface Deformation by Thermo-capillary Convection -Sounding Rocket COMPERE Experiment SOURCE

    Science.gov (United States)

    Fuhrmann, Eckart; Dreyer, Michael E.

    The sounding rocket COMPERE experiment SOURCE was successfully flown on MASER 11, launched in Kiruna (ESRANGE), May 15th, 2008. SOURCE has been intended to partly ful-fill the scientific objectives of the European Space Agency (ESA) Microgravity Applications Program (MAP) project AO-2004-111 (Convective boiling and condensation). Three parties of principle investigators have been involved to design the experiment set-up: ZARM for thermo-capillary flows, IMFT (Toulouse, France) for boiling studies, EADS Astrium (Bremen, Ger-many) for depressurization. The scientific aims are to study the effect of wall heat flux on the contact line of the free liquid surface and to obtain a correlation for a convective heat transfer coefficient. The experiment has been conducted along a predefined time line. A preheating sequence at ground was the first operation to achieve a well defined temperature evolution within the test cell and its environment inside the rocket. Nearly one minute after launch, the pressurized test cell was filled with the test liquid HFE-7000 until a certain fill level was reached. Then the free surface could be observed for 120 s without distortion. Afterwards, the first depressurization was started to induce subcooled boiling, the second one to start saturated boiling. The data from the flight consists of video images and temperature measurements in the liquid, the solid, and the gaseous phase. Data analysis provides the surface shape versus time and the corresponding apparent contact angle. Computational analysis provides information for the determination of the heat transfer coefficient in a compensated gravity environment where a flow is caused by the temperature difference between the hot wall and the cold liquid. Correlations for the effective contact angle and the heat transfer coefficient shall be delivered as a function of the relevant dimensionsless parameters. The data will be used for benchmarking of commercial CFD codes and the tank design

  10. Complex source mechanisms of mining-induced seismic events - implications for surface effects

    Science.gov (United States)

    Orlecka-Sikora, B.; Cesca, S.; Lasocki, S.; Rudzinski, L.; Lizurek, L.; Wiejacz, P.; Urban, P.; kozlowska, M.

    2012-04-01

    The seismicity of Legnica-Głogów Copper District (LGCD) is induced by mining activities in three mines: Lubin, Rudna and Polkowice-Sieroszowice. Ground motion caused by strong tremors might affect local infrastructure. "Żelazny Most" tailings pond, the biggest structure of this type in Europe, is here under special concern. Due to surface objects protection, Rudna Mine has been running ground motion monitoring for several years. From June 2010 to June 2011 unusually strong and extensive surface impact has been observed for 6 mining tremors induced in one of Rudna mining sections. The observed peak ground acceleration (PGA) for both horizontal and vertical component were in or even beyond 99% confidence interval for prediction. The aim of this paper is analyze the reason of such unusual ground motion. On the basis of registrations from Rudna Mine mining seismological network and records from Polish Seismological Network held by the Institute of Geophysics Polish Academy of Sciences (IGF PAN), the source mechanisms of these 6 tremors were calculated using a time domain moment tensor inversion. Furthermore, a kinematic analysis of the seismic source was performed, in order to determine the rupture planes orientations and rupture directions. These results showed that in case of the investigated tremors, point source models and shear fault mechanisms, which are most often assumed in mining seismology, are invalid. All analyzed events indicate extended sources with non-shear mechanism. The rapture planes have small dip angles and the rupture starts at the tremors hypocenter and propagates in the direction opposite to the plane dip. The tensional component plays here also big role. These source mechanisms well explain such observed strong ground motion, and calculated synthetic PGA values well correlates with observed ones. The relationship between mining tremors were also under investigation. All subsequent tremors occurred in the area of increased stress due to

  11. Sources and fate of environmental radioactivity at the earth's surface

    International Nuclear Information System (INIS)

    El-Daoushy, F.

    2010-01-01

    Sources and fate of environmental radioactivity at the earth surface This is to link environmental radioactivity to RP in Africa? To describe the benefits of Africa from this field in terms of RP, safety and security policies. To create a mission and a vision to fulfil the needs of ONE PEOPLE, ONE GOAL, ONE FAITH. Sources, processes and fate of environmental radioactivity Previous experience helps setting up an African agenda.(1) Factors influencing cosmogenic radionuclides(2) Factors influencing artificial radionuclides: (a) nuclear weapon-tests (b) nuclear accidents (c) Energy, mining and industrial waste (3) Factors influencing the global Rn-222 and its daughters. (4) Dynamics of cycles of natural radioactivity, e.g. Pb-210. (5) Environmental radiotracers act as DIAGNOSTIC TOOLS to assess air and water quality and impacts of the atmospheric and hydrospheric compartments on ecosystems.6) Definition of base-lines for rehabilitation and protection. Climate influences sources/behaviour/fate of environmental radioactivity. Impacts on life forms in Africa would be severe. Assessing environmental radioactivity resolves these issue

  12. Modeling diffuse sources of surface water contamination with plant protection products

    Science.gov (United States)

    Wendland, Sandra; Bock, Michael; Böhner, Jürgen; Lembrich, David

    2015-04-01

    Entries of chemical pollutants in surface waters are a serious environmental problem. Among water pollutants plant protection products (ppp) from farming practice are of major concern not only for water suppliers and environmental agencies, but also for farmers and industrial manufacturers. Lost chemicals no longer fulfill their original purpose on the field, but lead to severe damage of the environment and surface waters. Besides point-source inputs of chemical pollutants, the diffuse-source inputs from agricultural procedures play an important and not yet sufficiently studied role concerning water quality. The two most important factors for diffuse inputs are erosion and runoff. The latter usually occurs before erosion begins, and is thus often not visible in hindsight. Only if it has come to erosion, it is obvious to expect runoff in foresight at this area, too. In addition to numerous erosion models, there are also few applications to model runoff processes available. However, these conventional models utilize approximations of catchment parameters based on long-term average values or theoretically calculated concentration peaks which can only provide indications to relative amounts. Our study aims to develop and validate a simplified spatially-explicit dynamic model with high spatiotemporal resolution that enables to measure current and forecast runoff potential not only at catchment scale but field-differentiated. This method allows very precise estimations of runoff risks and supports risk reduction measures to be targeted before fields are treated. By focusing on water pathways occurring on arable land, targeted risk reduction measures like buffer strips at certain points and adapted ppp use can be taken early and pollution of rivers and other surface waters through transported pesticides, fertilizers and their products could be nearly avoided or largely minimized. Using a SAGA-based physical-parametric modeling approach, major factors influencing runoff

  13. Dose distribution considerations of medium energy electron beams at extended source-to-surface distance

    International Nuclear Information System (INIS)

    Saw, Cheng B.; Ayyangar, Komanduri M.; Pawlicki, Todd; Korb, Leroy J.

    1995-01-01

    Purpose: To determine the effects of extended source-to-surface distance (SSD) on dose distributions for a range of medium energy electron beams and cone sizes. Methods and Materials: The depth-dose curves and isodose distributions of 6 MeV, 10 MeV, and 14 MeV electron beams from a dual photon and multielectron energies linear accelerator were studied. To examine the influence of cone size, the smallest and the largest cone sizes available were used. Measurements were carried out in a water phantom with the water surface set at three different SSDs from 101 to 116 cm. Results: In the region between the phantom surface and the depth of maximum dose, the depth-dose decreases as the SSD increases for all electron beam energies. The effects of extended SSD in the region beyond the depth of maximum dose are unobservable and, hence, considered minimal. Extended SSD effects are apparent for higher electron beam energy with small cone size causing the depth of maximum dose and the rapid dose fall-off region to shift deeper into the phantom. However, the change in the depth-dose curve is small. On the other hand, the rapid dose fall-off region is essentially unaltered when the large cone is used. The penumbra enlarges and electron beam flatness deteriorates with increasing SSD

  14. Visco-elastic controlled-source full waveform inversion without surface waves

    Science.gov (United States)

    Paschke, Marco; Krause, Martin; Bleibinhaus, Florian

    2016-04-01

    We developed a frequency-domain visco-elastic full waveform inversion for onshore seismic experiments with topography. The forward modeling is based on a finite-difference time-domain algorithm by Robertsson that uses the image-method to ensure a stress-free condition at the surface. The time-domain data is Fourier-transformed at every point in the model space during the forward modeling for a given set of frequencies. The motivation for this approach is the reduced amount of memory when computing kernels, and the straightforward implementation of the multiscale approach. For the inversion, we calculate the Frechet derivative matrix explicitly, and we implement a Levenberg-Marquardt scheme that allows for computing the resolution matrix. To reduce the size of the Frechet derivative matrix, and to stabilize the inversion, an adapted inverse mesh is used. The node spacing is controlled by the velocity distribution and the chosen frequencies. To focus the inversion on body waves (P, P-coda, and S) we mute the surface waves from the data. Consistent spatiotemporal weighting factors are applied to the wavefields during the Fourier transform to obtain the corresponding kernels. We test our code with a synthetic study using the Marmousi model with arbitrary topography. This study also demonstrates the importance of topography and muting surface waves in controlled-source full waveform inversion.

  15. Use of a Bayesian isotope mixing model to estimate proportional contributions of multiple nitrate sources in surface water

    International Nuclear Information System (INIS)

    Xue Dongmei; De Baets, Bernard; Van Cleemput, Oswald; Hennessy, Carmel; Berglund, Michael; Boeckx, Pascal

    2012-01-01

    To identify different NO 3 − sources in surface water and to estimate their proportional contribution to the nitrate mixture in surface water, a dual isotope and a Bayesian isotope mixing model have been applied for six different surface waters affected by agriculture, greenhouses in an agricultural area, and households. Annual mean δ 15 N–NO 3 − were between 8.0 and 19.4‰, while annual mean δ 18 O–NO 3 − were given by 4.5–30.7‰. SIAR was used to estimate the proportional contribution of five potential NO 3 − sources (NO 3 − in precipitation, NO 3 − fertilizer, NH 4 + in fertilizer and rain, soil N, and manure and sewage). SIAR showed that “manure and sewage” contributed highest, “soil N”, “NO 3 − fertilizer” and “NH 4 + in fertilizer and rain” contributed middle, and “NO 3 − in precipitation” contributed least. The SIAR output can be considered as a “fingerprint” for the NO 3 − source contributions. However, the wide range of isotope values observed in surface water and of the NO 3 − sources limit its applicability. - Highlights: ► The dual isotope approach (δ 15 N- and δ 18 O–NO 3 − ) identify dominant nitrate sources in 6 surface waters. ► The SIAR model estimate proportional contributions for 5 nitrate sources. ► SIAR is a reliable approach to assess temporal and spatial variations of different NO 3 − sources. ► The wide range of isotope values observed in surface water and of the nitrate sources limit its applicability. - This paper successfully applied a dual isotope approach and Bayesian isotopic mixing model to identify and quantify 5 potential nitrate sources in surface water.

  16. A density functional theory study on the conversion of ethylene to carbon monomer on PdAu(1 0 0) surface

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Minhua; Yang, Bing [Key Laboratory for Green Chemical Technology of Ministry of Education, R& D Center for Petrochemical Technology, Tianjin University, Tianjin 300072 (China); Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072 (China); Yu, Yingzhe, E-mail: yzhyu@tju.edu.cn [Key Laboratory for Green Chemical Technology of Ministry of Education, R& D Center for Petrochemical Technology, Tianjin University, Tianjin 300072 (China); Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300072 (China)

    2015-11-30

    Graphical abstract: - Highlights: • The successive decomposition of ethylene on PdAu(1 0 0) was studied with DFT method. • The C−H, C−C bond scission and a hydrogen-shift process were investigated. • The alloying of Au with Pd affects the studied reactions on PdAu(1 0 0) greatly. - Abstract: Calculations based on the first-principles density functional theory (DFT) were performed to study the possible transformation pathways of ethylene on PdAu(1 0 0) surface to investigate the effect of Au atom alloying with Pd on the formation of CHx (x = 0–2), which may eventually form carbon monomer and lead to the deactivation of catalysts. The energetic properties of reactions including the scission of the C−H, C−C bond and a hydrogen-shift process were determined. The C−H bond scission is confirmed to be prone to happen on the studied surface, while it is difficult for the C−C bond scission to occur due to relatively high barriers, the values of which are as high as 2.72–4.62 eV. The activation barriers for all related reactions except for the dehydrogenation of vinyl, vinylidene and acetenyl demonstrate that it is harder for the conversion of ethylene to occur on PdAu(1 0 0) surface than on Pd(1 0 0) surface, especially for the C−C bond scission. All the results indicate that the alloying of Au atom with pure Pd catalyst can prevent the formation of carbon monomer, which may notably affect properties of catalysts.

  17. Incidence of the enterococcal surface protein (esp) gene in human and animal fecal sources

    Science.gov (United States)

    Whitman, R.L.; Przybyla-Kelly, K.; Shively, D.A.; Byappanahalli, M.N.

    2007-01-01

    The occurrence of the enterococcal surface protein (esp) gene in the opportunistic pathogens Enterococcus faecalis and E. faecium is well-documented in clinical research. Recently, the esp gene has been proposed as a marker of human pollution in environmental waters; however, information on its relative incidence in various human and animal fecal sources is limited. We have determined the occurrence of the esp gene in enterococci from human (n = 64) and animal (n = 233) fecal samples by polymerase chain reaction using two primer sets: one presumably specific for E. faecium (espfm) and the other for both E. faecalis and E. faecium (espfs/fm). We believe that this research is the first to explore the use of espfs/fm for the detection of human waste in natural environmental settings. The incidence in human sources was 93.1% espfm and 100% espfs/fm in raw sewage influent; 30% for both espfm and espfs/fm in septic waste; and 0% espfm and 80% espfs/fm in active pit toilets. The overall occurrence of the gene in animal feces was 7.7% (espfs/fm) and 4.7% (espfm); animal types with positive results included dogs (9/43, all espfm), gulls (10/34, espfs/fm; 2/34, espfm), mice (3/22, all espfs/fm), and songbirds (5/55, all espfs/fm). The esp gene was not detected in cat (0/34), deer (0/4), goose (0/18), or raccoon (0/23) feces. The inconsistent occurrence, especially in septic and pit toilet sewage, suggests a low statistical power of discrimination between animal and human sources, which means a large number of replicates should be collected. Both espfm and espfs/fm were common in raw sewage, but neither one efficiently differentiated between animal and other human sources.

  18. Occurrence and overlooked sources of the biocide carbendazim in wastewater and surface water.

    Science.gov (United States)

    Merel, Sylvain; Benzing, Saskia; Gleiser, Carolin; Di Napoli-Davis, Gina; Zwiener, Christian

    2018-08-01

    Carbendazim is a fungicide commonly used as active substance in plant protection products and biocidal products, for instance to protect facades of buildings against fungi. However, the subsequent occurrence of this fungicide and potential endocrine disruptor in the aqueous environment is a major concern. In this study, high resolution mass spectrometry shows that carbendazim can be detected with an increasing abundance from the source to the mouth of the River Rhine. Unexpectedly, the abundance of carbendazim correlates poorly with that of other fungicides used as active ingredients in plant protection products (r 2 of 0.32 for cyproconazole and r 2 of 0.57 for propiconazole) but it correlates linearly with that of pharmaceuticals (r 2 of 0.86 for carbamazepine and r 2 of 0.89 for lamotrigine). These results suggest that the occurrence of carbendazim in surface water comes mainly from the discharge of treated domestic wastewater. This hypothesis is further confirmed by the detection of carbendazim in wastewater effluents (n = 22). In fact, bench-scale leaching tests of textiles and papers revealed that these materials commonly found in households could be a source of carbendazim in domestic wastewater. Moreover, additional river samples collected nearby two paper industries indicate that the discharge of their treated process effluents is also a source of carbendazim in the environment. While characterizing paper and textile as overlooked sources of carbendazim, this study also shows the biocide as a possible ubiquitous wastewater contaminant that would require further systematic and worldwide monitoring due to its toxicological properties. Copyright © 2018 Elsevier Ltd. All rights reserved.

  19. Uranium conversion

    International Nuclear Information System (INIS)

    Oliver, Lena; Peterson, Jenny; Wilhelmsen, Katarina

    2006-03-01

    FOI, has performed a study on uranium conversion processes that are of importance in the production of different uranium compounds in the nuclear industry. The same conversion processes are of interest both when production of nuclear fuel and production of fissile material for nuclear weapons are considered. Countries that have nuclear weapons ambitions, with the intention to produce highly enriched uranium for weapons purposes, need some degree of uranium conversion capability depending on the uranium feed material available. This report describes the processes that are needed from uranium mining and milling to the different conversion processes for converting uranium ore concentrate to uranium hexafluoride. Uranium hexafluoride is the uranium compound used in most enrichment facilities. The processes needed to produce uranium dioxide for use in nuclear fuel and the processes needed to convert different uranium compounds to uranium metal - the form of uranium that is used in a nuclear weapon - are also presented. The production of uranium ore concentrate from uranium ore is included since uranium ore concentrate is the feed material required for a uranium conversion facility. Both the chemistry and principles or the different uranium conversion processes and the equipment needed in the processes are described. Since most of the equipment that is used in a uranium conversion facility is similar to that used in conventional chemical industry, it is difficult to determine if certain equipment is considered for uranium conversion or not. However, the chemical conversion processes where UF 6 and UF 4 are present require equipment that is made of corrosion resistant material

  20. Identification of perfluoroalkyl acid sources in Swiss surface waters with the help of the artificial sweetener acesulfame

    Energy Technology Data Exchange (ETDEWEB)

    Mueller, Claudia E., E-mail: claudia.mueller@empa.ch [Empa, Swiss Federal Laboratories for Materials Science and Technology, Uberlandstrasse 129, 8600 Duebendorf (Switzerland); Institute for Chemical and Bioengineering, ETH Zuerich, Wolfgang-Pauli-Strasse 10, 8093 Zuerich (Switzerland); Gerecke, Andreas C. [Empa, Swiss Federal Laboratories for Materials Science and Technology, Uberlandstrasse 129, 8600 Duebendorf (Switzerland); Alder, Alfredo C. [Eawag, Swiss Federal Institute of Aquatic Science and Technology, Uberlanstrasse 133, 8600 Duebendorf (Switzerland); Scheringer, Martin; Hungerbuehler, Konrad [Institute for Chemical and Bioengineering, ETH Zuerich, Wolfgang-Pauli-Strasse 10, 8093 Zuerich (Switzerland)

    2011-05-15

    Anthropogenic perfluorinated compounds (PFCs), especially the perfluoroalkyl acids (PFAAs) are ubiquitously found in surface waters around the globe. Emissions from households, industries and also atmospheric transport/deposition are discussed as the possible sources. In this study, these sources are evaluated using Switzerland as the study area. Forty-four surface water locations in different rivers and an Alpine lake were investigated for 14 PFAAs, four precursors and acesulfame, an artificial sweetener used as a population marker. Concentrations of individual PFAAs were generally low, between 0.02 and 10 ng/L. Correlation analysis showed that some PFAAs concentrations correlated well with population and less with catchment area, indicating that emissions from population, i.e., from consumer products, is the most important source to surface waters in Switzerland. The correlation with the population marker acesulfame confirmed this observation but highlighted also a few elevated PFAA levels, some of which could be attributed to industrial emissions. - Highlights: > Consumer products are the most important source of PFAAs in Swiss surface waters. > Acesulfame proofs to be a good population marker in surface waters. > PFAA pattern analyses reveal specific industrial emissions. - The analysis of correlations between surface water concentrations of perfluorinated compounds (PFCs) and source parameters revealed that consumer products are the most important source for PFCs in Switzerland, whereas industry and atmospheric deposition make a minor contribution.

  1. Identification of perfluoroalkyl acid sources in Swiss surface waters with the help of the artificial sweetener acesulfame

    International Nuclear Information System (INIS)

    Mueller, Claudia E.; Gerecke, Andreas C.; Alder, Alfredo C.; Scheringer, Martin; Hungerbuehler, Konrad

    2011-01-01

    Anthropogenic perfluorinated compounds (PFCs), especially the perfluoroalkyl acids (PFAAs) are ubiquitously found in surface waters around the globe. Emissions from households, industries and also atmospheric transport/deposition are discussed as the possible sources. In this study, these sources are evaluated using Switzerland as the study area. Forty-four surface water locations in different rivers and an Alpine lake were investigated for 14 PFAAs, four precursors and acesulfame, an artificial sweetener used as a population marker. Concentrations of individual PFAAs were generally low, between 0.02 and 10 ng/L. Correlation analysis showed that some PFAAs concentrations correlated well with population and less with catchment area, indicating that emissions from population, i.e., from consumer products, is the most important source to surface waters in Switzerland. The correlation with the population marker acesulfame confirmed this observation but highlighted also a few elevated PFAA levels, some of which could be attributed to industrial emissions. - Highlights: → Consumer products are the most important source of PFAAs in Swiss surface waters. → Acesulfame proofs to be a good population marker in surface waters. → PFAA pattern analyses reveal specific industrial emissions. - The analysis of correlations between surface water concentrations of perfluorinated compounds (PFCs) and source parameters revealed that consumer products are the most important source for PFCs in Switzerland, whereas industry and atmospheric deposition make a minor contribution.

  2. Deep Vs Profiling Along the Top of Yucca Mountain Using a Vibroseis Source and Surface Waves

    International Nuclear Information System (INIS)

    Stokoe, K.; Rosenblad, B.; Wong, I.; Bay, J.; Thomas, P.; Silva, W.

    2004-01-01

    Yucca Mountain, Nevada, was approved as the site for development of the geologic repository for high-level radioactive waste and spent nuclear fuel in the United States. The U.S. Department of Energy has been conducting studies to characterize the site and assess its future performance as a geologic repository. As part of these studies, a program of deep seismic profiling, to depths of 200 m, was conducted along the top of Yucca Mountain to evaluate the shear-wave velocity (V s ) structure of the repository block. The resulting V s data were used as input into the development of ground motions for the preclosure seismic design of the repository and for postclosure performance assessment. The noninvasive spectral-analysis-of-surface-waves (SASW) method was employed in the deep profiling. Field measurements involved the use of a modified Vibroseis as the seismic source. The modifications allowed the Vibroseis to be controlled by a signal analyzer so that slow frequency sweeps could be performed while simultaneous narrow-band filtering was performed on the receiver outputs. This process optimized input energy from the source and signal analysis of the receiver outputs. Six deep V s profiles and five intermediate-depth (about 100 m) profiles were performed along the top of Yucca Mountain over a distance of about 5 km. In addition, eleven shallower profiles (averaging about 45-m deep) were measured using a bulldozer source. The shallower profiles were used to augment the deeper profiles and to evaluate further the near-surface velocity structure. The V s profiles exhibit a strong velocity gradient within 5 m of the surface, with the mean V s value more than doubling. Below this depth, V s gradually increases from a mean value of about 900 to 1000 m/s at a depth of 150 m. Between the depths of 150 and 210 m, V s increases more rapidly to about 1350 m/s, but this trend is based on limited data. At depths less than 50 m, anisotropy in V s was measured for surveys conducted

  3. Conversion electron Moessbauer spectroscopic studies on the chemical states of surface layers of corroded tin plates and tin-coated iron plates

    International Nuclear Information System (INIS)

    Kato, Akinori; Endo, Kazutoyo; Sano, Hirotoshi

    1980-01-01

    By means of the conversion electron Moessbauer spectroscopy (CEMS), we studied surface layers of ''tin'' plates and tin-coated iron plates corroded by various acids. Transmission Moessbauer spectra and X-ray diffraction patterns were also measured. Metastannic acid was formed, when the ''tin'' plate was corroded by nitric acid solution. In corrosion by phosphoric acid solution, the X-ray diffractometry revealed the formation of tin(IV) pyrophosphate. In corrosion by various organic acid solutions, the formation of oxides was identified by the 119 Sn CEMS, but not by the X-ray diffractometry because of the too thin corrosion layer. In corrosion of tin-coated iron plates, maleic acid, malonic acid, formic acid, and oxalic acid were used. It was determined by CEMS that the corrosion products caused by these acids were tin(IV) oxides, although they could not be identified by the X-ray diffractometry. CEMS also confirmed that the surface of uncorroded tin-coated iron plate was already oxidized by air. Colorimetric determinations of Sn and Fe dissolved from tin-coated iron plates to various acid solutions confirmed that maleic acid had the strongest corrosion effect among the organic acids studied. (author)

  4. Novel Cavities in Vertical External Cavity Surface Emitting Lasers for Emission in Broad Spectral Region by Means of Nonlinear Frequency Conversion

    Science.gov (United States)

    Lukowski, Michal L.

    Optically pumped semiconductor vertical external cavity surface emitting lasers (VECSEL) were first demonstrated in the mid 1990's. Due to the unique design properties of extended cavity lasers VECSELs have been able to provide tunable, high-output powers while maintaining excellent beam quality. These features offer a wide range of possible applications in areas such as medicine, spectroscopy, defense, imaging, communications and entertainment. Nowadays, newly developed VECSELs, cover the spectral regions from red (600 nm) to around 5 microm. By taking the advantage of the open cavity design, the emission can be further expanded to UV or THz regions by the means of intracavity nonlinear frequency generation. The objective of this dissertation is to investigate and extend the capabilities of high-power VECSELs by utilizing novel nonlinear conversion techniques. Optically pumped VECSELs based on GaAs semiconductor heterostructures have been demonstrated to provide exceptionally high output powers covering the 900 to 1200 nm spectral region with diffraction limited beam quality. The free space cavity design allows for access to the high intracavity circulating powers where high efficiency nonlinear frequency conversions and wavelength tuning can be obtained. As an introduction, this dissertation consists of a brief history of the development of VECSELs as well as wafer design, chip fabrication and resonator cavity design for optimal frequency conversion. Specifically, the different types of laser cavities such as: linear cavity, V-shaped cavity and patented T-shaped cavity are described, since their optimization is crucial for transverse mode quality, stability, tunability and efficient frequency conversion. All types of nonlinear conversions such as second harmonic, sum frequency and difference frequency generation are discussed in extensive detail. The theoretical simulation and the development of the high-power, tunable blue and green VECSEL by the means of type I

  5. Use of multiple water surface flow constructed wetlands for non-point source water pollution control.

    Science.gov (United States)

    Li, Dan; Zheng, Binghui; Liu, Yan; Chu, Zhaosheng; He, Yan; Huang, Minsheng

    2018-05-02

    Multiple free water surface flow constructed wetlands (multi-FWS CWs) are a variety of conventional water treatment plants for the interception of pollutants. This review encapsulated the characteristics and applications in the field of ecological non-point source water pollution control technology. The roles of in-series design and operation parameters (hydraulic residence time, hydraulic load rate, water depth and aspect ratio, composition of influent, and plant species) for performance intensification were also analyzed, which were crucial to achieve sustainable and effective contaminants removal, especially the retention of nutrient. The mechanism study of design and operation parameters for the removal of nitrogen and phosphorus was also highlighted. Conducive perspectives for further research on optimizing its design/operation parameters and advanced technologies of ecological restoration were illustrated to possibly interpret the functions of multi-FWS CWs.

  6. Meniscus and beam halo formation in a tandem-type negative ion source with surface production

    Energy Technology Data Exchange (ETDEWEB)

    Miyamoto, K. [Naruto University of Education, 748 Nakashima, Takashima, Naruto-cho, Naruto-shi, Tokushima 772-8502 (Japan); Okuda, S.; Hatayama, A. [Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522 (Japan)

    2012-06-04

    A meniscus of plasma-beam boundary in H{sup -} ion sources largely affects the extracted H{sup -} ion beam optics. Although it is hypothesized that the shape of the meniscus is one of the main reasons for the beam halo observed in experiments, a physical mechanism of the beam halo formation is not yet fully understood. In this letter, it is first shown by the 2D particle in cell simulation that the H{sup -} ions extracted from the periphery of the meniscus cause a beam halo since the surface produced H{sup -} ions penetrate into the bulk plasma, and, thus, the resultant meniscus has a relatively large curvature.

  7. Sample dilution and bacterial community composition influence empirical leucine-to-carbon conversion factors in surface waters of the world's oceans.

    Science.gov (United States)

    Teira, Eva; Hernando-Morales, Víctor; Cornejo-Castillo, Francisco M; Alonso-Sáez, Laura; Sarmento, Hugo; Valencia-Vila, Joaquín; Serrano Catalá, Teresa; Hernández-Ruiz, Marta; Varela, Marta M; Ferrera, Isabel; Gutiérrez Morán, Xosé Anxelu; Gasol, Josep M

    2015-12-01

    The transformation of leucine incorporation rates to prokaryotic carbon production rates requires the use of either theoretical or empirically determined conversion factors. Empirical leucine-to-carbon conversion factors (eCFs) vary widely across environments, and little is known about their potential controlling factors. We conducted 10 surface seawater manipulation experiments across the world's oceans, where the growth of the natural prokaryotic assemblages was promoted by filtration (i.e., removal of grazers [F treatment]) or filtration combined with dilution (i.e., also relieving resource competition [FD treatment]). The impact of sunlight exposure was also evaluated in the FD treatments, and we did not find a significant effect on the eCFs. The eCFs varied from 0.09 to 1.47 kg C mol Leu(-1) and were significantly lower in the FD than in the F samples. Also, changes in bacterial community composition during the incubations, as assessed by automated ribosomal intergenic spacer analysis (ARISA), were more pronounced in the FD than in the F treatments, compared to unmanipulated controls. Thus, we discourage the common procedure of diluting samples (in addition to filtration) for eCF determination. The eCFs in the filtered treatment were negatively correlated with the initial chlorophyll a concentration, picocyanobacterial abundance (mostly Prochlorococcus), and the percentage of heterotrophic prokaryotes with high nucleic acid content (%HNA). The latter two variables explained 80% of the eCF variability in the F treatment, supporting the view that both Prochlorococcus and HNA prokaryotes incorporate leucine in substantial amounts, although this results in relatively low carbon production rates in the oligotrophic ocean. Copyright © 2015, American Society for Microbiology. All Rights Reserved.

  8. Sample Dilution and Bacterial Community Composition Influence Empirical Leucine-to-Carbon Conversion Factors in Surface Waters of the World's Oceans

    KAUST Repository

    Teira, Eva

    2015-09-25

    The transformation of leucine incorporation rates to prokaryotic carbon production rates requires the use of either theoretical or empirically determined conversion factors. Empirical leucine-to-carbon conversion factors (eCFs) vary widely across environments, and little is known about their potential controlling factors. We conducted 10 surface seawater manipulation experiments across the world\\'s oceans, where the growth of the natural prokaryotic assemblages was promoted by filtration (i.e., removal of grazers [F treatment]) or filtration combined with dilution (i.e., also relieving resource competition [FD treatment]). The impact of sunlight exposure was also evaluated in the FD treatments, and we did not find a significant effect on the eCFs. The eCFs varied from 0.09 to 1.47 kg C mol Leu−1 and were significantly lower in the FD than in the F samples. Also, changes in bacterial community composition during the incubations, as assessed by automated ribosomal intergenic spacer analysis (ARISA), were more pronounced in the FD than in the F treatments, compared to unmanipulated controls. Thus, we discourage the common procedure of diluting samples (in addition to filtration) for eCF determination. The eCFs in the filtered treatment were negatively correlated with the initial chlorophyll a concentration, picocyanobacterial abundance (mostly Prochlorococcus), and the percentage of heterotrophic prokaryotes with high nucleic acid content (%HNA). The latter two variables explained 80% of the eCF variability in the F treatment, supporting the view that both Prochlorococcus and HNA prokaryotes incorporate leucine in substantial amounts, although this results in relatively low carbon production rates in the oligotrophic ocean.

  9. Sample Dilution and Bacterial Community Composition Influence Empirical Leucine-to-Carbon Conversion Factors in Surface Waters of the World's Oceans

    KAUST Repository

    Teira, Eva; Hernando-Morales, Ví ctor; Cornejo-Castillo, Francisco M.; Alonso-Sá ez, Laura; Sarmento, Hugo; Valencia-Vila, Joaquí n; Serrano Catalá , Teresa; Herná ndez-Ruiz, Marta; Varela, Marta M.; Ferrera, Isabel; Moran, Xose Anxelu G.; Gasol, Josep M.

    2015-01-01

    The transformation of leucine incorporation rates to prokaryotic carbon production rates requires the use of either theoretical or empirically determined conversion factors. Empirical leucine-to-carbon conversion factors (eCFs) vary widely across environments, and little is known about their potential controlling factors. We conducted 10 surface seawater manipulation experiments across the world's oceans, where the growth of the natural prokaryotic assemblages was promoted by filtration (i.e., removal of grazers [F treatment]) or filtration combined with dilution (i.e., also relieving resource competition [FD treatment]). The impact of sunlight exposure was also evaluated in the FD treatments, and we did not find a significant effect on the eCFs. The eCFs varied from 0.09 to 1.47 kg C mol Leu−1 and were significantly lower in the FD than in the F samples. Also, changes in bacterial community composition during the incubations, as assessed by automated ribosomal intergenic spacer analysis (ARISA), were more pronounced in the FD than in the F treatments, compared to unmanipulated controls. Thus, we discourage the common procedure of diluting samples (in addition to filtration) for eCF determination. The eCFs in the filtered treatment were negatively correlated with the initial chlorophyll a concentration, picocyanobacterial abundance (mostly Prochlorococcus), and the percentage of heterotrophic prokaryotes with high nucleic acid content (%HNA). The latter two variables explained 80% of the eCF variability in the F treatment, supporting the view that both Prochlorococcus and HNA prokaryotes incorporate leucine in substantial amounts, although this results in relatively low carbon production rates in the oligotrophic ocean.

  10. Conversation Analysis.

    Science.gov (United States)

    Schiffrin, Deborah

    1990-01-01

    Summarizes the current state of research in conversation analysis, referring primarily to six different perspectives that have developed from the philosophy, sociology, anthropology, and linguistics disciplines. These include pragmatics; speech act theory; interactional sociolinguistics; ethnomethodology; ethnography of communication; and…

  11. A case study characterizing animal fecal sources in surface water using a mitochondrial DNA marker.

    Science.gov (United States)

    Bucci, John P; Shattuck, Michelle D; Aytur, Semra A; Carey, Richard; McDowell, William H

    2017-08-01

    Water quality impairment by fecal waste in coastal watersheds is a public health issue. The present study provided evidence for the use of a mitochondrial (mtDNA) marker to detect animal fecal sources in surface water. The accurate identification of fecal pollution is based on the notion that fecal microorganisms preferentially inhabit a host animal's gut environment. In contrast, mtDNA host-specific markers are inherent to eukaryotic host cells, which offers the advantage by detecting DNA from the host rather than its fecal bacteria. The present study focused on sampling water presumably from non-point sources (NPS), which can increase bacterial and nitrogen concentrations to receiving water bodies. Stream sampling sites located within the Piscataqua River Watershed (PRW), New Hampshire, USA, were sampled from a range of sites that experienced nitrogen inputs such as sewer and septic systems and suburban runoff. Three mitochondrial (mtDNA) gene marker assays (human, bovine, and canine) were tested from surface water. Nineteen sites were sampled during an 18-month period. Analyses of the combined single and multiplex assay results showed that the proportion of occurrence was highest for bovine (15.6%; n = 77) compared to canine (5.6%; n = 70) and human (5.7%; n = 107) mtDNA gene markers. For the human mtDNA marker, there was a statistically significant relationship between presence vs. absence and land use (Fisher's test p = 0.0031). This result was evident particularly for rural suburban septic, which showed the highest proportion of presence (19.2%) compared to the urban sewered (3.3%), suburban sewered (0%), and agricultural (0%) as well as forested septic (0%) sites. Although further testing across varied land use is needed, our study provides evidence for using the mtDNA marker in large watersheds.

  12. Sources and distribution of yttrium and rare earth elements in surface sediments from Tagus estuary, Portugal.

    Science.gov (United States)

    Brito, Pedro; Prego, Ricardo; Mil-Homens, Mário; Caçador, Isabel; Caetano, Miguel

    2018-04-15

    The distribution and sources of yttrium and rare-earth elements (YREE) in surface sediments were studied on 78 samples collected in the Tagus estuary (SW Portugal, SW Europe). Yttrium and total REE contents ranged from 2.4 to 32mg·kg -1 and 18 to 210mg·kg -1 , respectively, and exhibited significant correlations with sediment grain-size, Al, Fe, Mg and Mn, suggesting a preferential association to fine-grained material (e.g. aluminosilicates but also Al hydroxides and Fe oxyhydroxides). The PAAS (Post-Archean Australian Shale) normalized patterns display three distinct YREE fractionation pattern groups along the Tagus estuary: a first group, characterized by medium to coarse-grained material, a depleted and almost flat PAAS-normalized pattern, with a positive anomaly of Eu, representing one of the lithogenic components; a second group, characterized mainly by fine-grained sediment, with higher shale-normalized ratios and an enrichment of LREE relative to HREE, associated with waste water treatment plant (WWTP) outfalls, located in the northern margin; and, a third group, of fine-grained material, marked by a significant enrichment of Y, a depletion of Ce and an enrichment of HREE over LREE, located near an inactive chemical-industrial complex (e.g. pyrite roast plant, chemical and phosphorous fertilizer industries), in the southern margin. The data allow the quantification of the YREE contents and its spatial distribution in the surface sediments of the Tagus estuary, identifying the main potential sources and confirming the use of rare earth elements as tracers of anthropogenic activities in highly hydrodynamic estuaries. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. Sources

    International Nuclear Information System (INIS)

    Duffy, L.P.

    1991-01-01

    This paper discusses the sources of radiation in the narrow perspective of radioactivity and the even narrow perspective of those sources that concern environmental management and restoration activities at DOE facilities, as well as a few related sources. Sources of irritation, Sources of inflammatory jingoism, and Sources of information. First, the sources of irritation fall into three categories: No reliable scientific ombudsman to speak without bias and prejudice for the public good, Technical jargon with unclear definitions exists within the radioactive nomenclature, and Scientific community keeps a low-profile with regard to public information. The next area of personal concern are the sources of inflammation. This include such things as: Plutonium being described as the most dangerous substance known to man, The amount of plutonium required to make a bomb, Talk of transuranic waste containing plutonium and its health affects, TMI-2 and Chernobyl being described as Siamese twins, Inadequate information on low-level disposal sites and current regulatory requirements under 10 CFR 61, Enhanced engineered waste disposal not being presented to the public accurately. Numerous sources of disinformation regarding low level radiation high-level radiation, Elusive nature of the scientific community, The Federal and State Health Agencies resources to address comparative risk, and Regulatory agencies speaking out without the support of the scientific community

  14. Surface Modification Technology of ODS Alloying Treatment by using Laser Heat Source

    International Nuclear Information System (INIS)

    Kim, H. G.; Kim, I. H.; Choi, B. K.; Park, J. Y.; Koo, Y. H.

    2012-01-01

    The ODS (Oxide Dispersion Strengthed) alloys can be applied as structural materials for components in the core of a nuclear power plants since these components must have a high mechanical strength at high temperature up to 700 .deg. C. This type of alloy was generally manufactured by mechanical alloying from its source metal and Y 2 O 3 powders. The mechanical alloyed powder is subjected to the HIP (Hot Isotatic Pressing) or hot extrusion: and this product is heat treated at target temperature and time. Thus, the Y 2 O 3 particles are dispersed in the metal matrix. These manufacturing process of ODS alloy is very complex and expensive. Also, it is necessary the special techniques to obtain the uniform dispersion and volume control of Y 2 O 3 particles. Another problem is the final product forming such as tube and sheet because the intermediated-product has a high mechanical strength due to the dispersion of Y 2 O 3 particles. The laser cladding techniques was applied on the surface cladding of ceramics and inter-metallic compounds on metal base and ceramic base components to increase corrosion and wear resistance. The laser heat source can be used to the alloying the metal and ceramic materials, because thermally melting of metal and ceramic is possible. So, we are applied on ODS alloy manufacturing by using the laser heat source. The main advantages and disadvantage of this technology can be resumed as follows: · It is possible to apply to the sheet and tube shape component, directly. · Metallurgical damage such as HAZ and severe grain growth is considerably reduced. · Good control of the alloying element of the treated zone · Highly reproducible homogeneous zone · The pores and cracks are suppressed in the treated zone · Oxidation can be prevented during the process. · Good control is possible for the irregular shaped components. · The bulk material alloying is limited by the power of laser source. So, this work is studied on the ODS alloy manufacturing

  15. Laser Raman Spectroscopy with Different Excitation Sources and Extension to Surface Enhanced Raman Spectroscopy

    Directory of Open Access Journals (Sweden)

    Md. Wahadoszamen

    2015-01-01

    Full Text Available A dispersive Raman spectrometer was used with three different excitation sources (Argon-ion, He-Ne, and Diode lasers operating at 514.5 nm, 633 nm, and 782 nm, resp.. The system was employed to a variety of Raman active compounds. Many of the compounds exhibit very strong fluorescence while being excited with a laser emitting at UV-VIS region, hereby imposing severe limitation to the detection efficiency of the particular Raman system. The Raman system with variable excitation laser sources provided us with a desired flexibility toward the suppression of unwanted fluorescence signal. With this Raman system, we could detect and specify the different vibrational modes of various hazardous organic compounds and some typical dyes (both fluorescent and nonfluorescent. We then compared those results with the ones reported in literature and found the deviation within the range of ±2 cm−1, which indicates reasonable accuracy and usability of the Raman system. Then, the surface enhancement technique of Raman spectrum was employed to the present system. To this end, we used chemically prepared colloidal suspension of silver nanoparticles as substrate and Rhodamine 6G as probe. We could observe significant enhancement of Raman signal from Rhodamine 6G using the colloidal solution of silver nanoparticles the average magnitude of which is estimated to be 103.

  16. GIS based optimal impervious surface map generation using various spatial data for urban nonpoint source management.

    Science.gov (United States)

    Lee, Cholyoung; Kim, Kyehyun; Lee, Hyuk

    2018-01-15

    Impervious surfaces are mainly artificial structures such as rooftops, roads, and parking lots that are covered by impenetrable materials. These surfaces are becoming the major causes of nonpoint source (NPS) pollution in urban areas. The rapid progress of urban development is increasing the total amount of impervious surfaces and NPS pollution. Therefore, many cities worldwide have adopted a stormwater utility fee (SUF) that generates funds needed to manage NPS pollution. The amount of SUF is estimated based on the impervious ratio, which is calculated by dividing the total impervious surface area by the net area of an individual land parcel. Hence, in order to identify the exact impervious ratio, large-scale impervious surface maps (ISMs) are necessary. This study proposes and assesses various methods for generating large-scale ISMs for urban areas by using existing GIS data. Bupyeong-gu, a district in the city of Incheon, South Korea, was selected as the study area. Spatial data that were freely offered by national/local governments in S. Korea were collected. First, three types of ISMs were generated by using the land-cover map, digital topographic map, and orthophotographs, to validate three methods that had been proposed conceptually by Korea Environment Corporation. Then, to generate an ISM of higher accuracy, an integration method using all data was proposed. Error matrices were made and Kappa statistics were calculated to evaluate the accuracy. Overlay analyses were performed to examine the distribution of misclassified areas. From the results, the integration method delivered the highest accuracy (Kappa statistic of 0.99) compared to the three methods that use a single type of spatial data. However, a longer production time and higher cost were limiting factors. Among the three methods using a single type of data, the land-cover map showed the highest accuracy with a Kappa statistic of 0.91. Thus, it was judged that the mapping method using the land

  17. Photoemission studies of clean and adsorbate covered metal surfaces using synchrotron and uv radiation sources

    International Nuclear Information System (INIS)

    Apai, G.R. II.

    1977-09-01

    Photoemission energy distribution experiments on clean metal and adsorbate-covered surfaces were performed under ultrahigh vacuum conditions by using x-ray and ultraviolet photon sources in the laboratory as well as continuously-tunable, highly polarized synchrotron radiation obtainable at the Stanford Synchrotron Radiation Laboratory (SSRL). Studies focused on two general areas: cross-section modulation in the photoemission process was studied as a function of photon energy and orbital composition. Sharp decreases in intensity of the valence bands of several transition metals (i.e., Ag, Au, and Pt) are attributed to the radial nodes in the respective wave functions. Adsorbate photoemission studies of CO adsorbed on platinum single crystals have demonstrated a very high spectral sensitivity to the 4sigma and (1π + 5sigma) peaks of CO at photon energies of 150 eV. Angle-resolved photoemission allowed determination of the orientation of CO chemisorbed on a Pt (111) or Ni(111) surface. Prelinimary results at high photon energies (approximately 150 eV) indicated scattering from the substrate which could yield chemisorption site geometries

  18. Formation of hydrogen negative ions by surface and volume processes with application to negative ion sources

    International Nuclear Information System (INIS)

    Hiskes, J.R.

    1979-01-01

    During the last few decades interest in negative-hydrogen ion sources has been directed mainly toward synchrotron and other particle accelerator applications, with emphasis on high current densities delivered for short pulses. But within the last several years there has been an awareness in the magnetic fusion program of the future need for negative ions as a means for generating high energy neutral beams, beams with energies above a few hundred keV. Negative ions seem to be the only effective intermediary for efficiently producing such beams. Although methods for generating negative ion beams have relied upon synchrotron concepts, the requirements for fusion are very different: here one is interested in more moderate current densities, up to 100 m A cm -2 , but with continuous operation. Proposed source modules would accelerate of the order of 10 A of beam current and deliver several megawatts of beam power. Both H - and D - beams are being considered for application in different reactor systems. The conceptualization of negative ion sources is now in a very volatile stage. But of the great variety of proposals that have been offered to date, three general areas appear ready for development. These are: first, the double charge exchange method for converting a positive ion beam into a negative ion beam; second, electron-volume processes wherein low energy electrons interacting with molecular species lead to negative ion products via dissociative attachment or recombination; and third, generation of negative ions in surface interactions, principally via desorption and backscattering. Both our qualitative and our quantitative understanding of these processes diminishes as one proceeds from the first through the third. The physics of these three methods is considered in detail

  19. Element Content of Surface and Underground Water Sources around a Cement Factory Site in Calabar, Nigeria

    Directory of Open Access Journals (Sweden)

    Edmund Richard Egbe

    2017-01-01

    Full Text Available Background: Cement production is associated with heavy metal emissions and environmental pollution by cement dust. The degree of contamination of drinking water sources by major and trace elements present in cement dust generated by united cement factory (UNICEM is still uncertain. This study estimated the element content of ground and surface water samples (hand-dug wells, boreholes and streams around the factory site to determine the impact of cement dust exposure on the water levels of these elements. Methods: This study was conducted at UNICEM at Mfamosing, Akamkpa local government area, Cross River State, Nigeria. Drinking water samples (5 from each location were collected from the cement factory quarry site camp, 3 surrounding communities and Calabar metropolis (45 km away from factory serving as control. The lead (Pb, copper (Cu, manganes (Mn, iron (Fe, cadmium (Cd, selenium (Se, chromium (Cr, zinc (Zn and arsenic (As levels of samples were determined using Atomic Absorption Spectrometry (AAS. Data were analyzed using ANOVA and LSD post hoc at P = 0.05. Results: As and Pb content of samples from camp were above the WHO recommendations of 0.01mg/l and 0.01mg/l respectively. Chromium and cadmium content of all water samples were above and others below WHO recommendations. Water levels of Mn, Fe, Zn, As, Se, Cd, Ca and Si were significantly elevated (though below WHO recommendations in camp than other locations (P<0.05. Conclusion: Production of cement results in As, Pb, Cr and cd contamination of drinking water sources near the factory. Treatment of all drinking water sources is recommended before public use to avert deleterious health consequences.

  20. Performance Analysis of Fission and Surface Source Iteration Method for Domain Decomposed Monte Carlo Whole-Core Calculation

    International Nuclear Information System (INIS)

    Jo, Yu Gwon; Oh, Yoo Min; Park, Hyang Kyu; Park, Kang Soon; Cho, Nam Zin

    2016-01-01

    In this paper, two issues in the FSS iteration method, i.e., the waiting time for surface source data and the variance biases in local tallies are investigated for the domain decomposed, 3-D continuous-energy whole-core calculation. The fission sources are provided as usual, while the surface sources are provided by banking MC particles crossing local domain boundaries. The surface sources serve as boundary conditions for nonoverlapping local problems, so that each local problem can be solved independently. In this paper, two issues in the FSS iteration are investigated. One is quantifying the waiting time of processors to receive surface source data. By using nonblocking communication, 'time penalty' to wait for the arrival of the surface source data is reduced. The other important issue is underestimation of the sample variance of the tally because of additional inter-iteration correlations in surface sources. From the numerical results on a 3-D whole-core test problem, it is observed that the time penalty is negligible in the FSS iteration method and that the real variances of both pin powers and assembly powers are estimated by the HB method. For those purposes, three cases; Case 1 (1 local domain), Case 2 (4 local domains), Case 3 (16 local domains) are tested. For both Cases 2 and 3, the time penalties for waiting are negligible compared to the source-tracking times. However, for finer divisions of local domains, the loss of parallel efficiency caused by the different number of sources for local domains in symmetric locations becomes larger due to the stochastic errors in source distributions. For all test cases, the HB method very well estimates the real variances of local tallies. However, it is also noted that the real variances of local tallies estimated by the HB method show slightly smaller than the real variances obtained from 30 independent batch runs and the deviations become larger for finer divisions of local domains. The batch size used for the HB

  1. Tracing the source and fate of nitrate in contemporary mixed land-use surface water systems

    Science.gov (United States)

    Stewart, S. D.; Young, M. B.; Horton, T. W.; Harding, J. S.

    2011-12-01

    Nitrogenous fertilizers increase agricultural productivity, ultimately feeding the planet. Yet, it is possible to have too much of a good thing, and nitrogen is no exception. When in excess nitrogen has been shown to accelerate eutrophication of water bodies, and act as a chronic toxin (e.g. methemoglobinemia). As land-use intensity continues to rise in response to increases in agricultural productivity, the risk of adverse effects of nitrogen loading on surface water bodies will also increase. Stable isotope proxies are potential tracers of nitrate, the most common nitrogenous phase in surface waters. Applying stable isotope proxies therefore presents an opportunity to identify and manage sources of excess nitrogen before aquatic systems are severely degraded. However, the heterogeneous nature of potential pollution sources themselves, and their distribution with a modified catchment network, make understanding this issue highly complex. The Banks Peninsula, an eroded late tertiary volcanic complex located on the east coast of the South Island New Zealand, presents a unique opportunity to study and understand the sources and fates of nitrate within streams in a contemporary mixed land-use setting. Within this small geographic area there a variety of agricultural activities are practiced, including: heavily fertilized golf courses; stands of regenerating native forest; and areas of fallow gorse (Ulex europaeus; a invasive N-fixing shrub). Each of these landuse classes has its own unique nitrogen budget. Multivariate analysis was used on stream nitrate concentrations to reveal that stream reaches dominated by gorse had significantly higher nitrate concentrations than other land-use classes. Nitrate δ15N & δ18O data from these sites show strong covariance, plotting along a distinct fractionation line (r2 = 0.96). This finding facilitates interpretation of what processes are controlling nitrate concentration within these systems. Further, complementary aquatic

  2. Study of surface ionization and LASER ionization processes using the SOMEIL ion source: application to the Spiral 2 laser ion source development

    Energy Technology Data Exchange (ETDEWEB)

    Bajeat, O., E-mail: bajeat@ganil.fr; Lecesne, N.; Leroy, R.; Maunoury, L.; Osmond, B.; Sjodin, M. [GANIL (France); Maitre, A.; Pradeilles, N. [Laboratoire Science des Procedes Ceramiques et de Traitements de Surface (SPCTS) 12 (France)

    2013-04-15

    SPIRAL2 is the new project under construction at GANIL to provide radioactive ion beams to the Nuclear Physics Community and in particular neutron rich ion beams. For the production of condensable radioactive elements, a resonant ionization laser ion source is under development at GANIL. In order to generate the ions of interest with a good selectivity and purity, our group is studying the way to minimize surface ionization process by using refractory materials with low work function as ionizer tube. To do those investigations a dedicated ion source, called SOMEIL (Source Optimisee pour les Mesures d'Efficacite d'Ionisation Laser) is used. Numerous types of ionizer tubes made in various materials and geometry are tested. Surface ionization and laser ionization efficiencies can be measured for each of them.

  3. Laser source with high pulse energy at 3-5 μm and 8-12 μm based on nonlinear conversion in ZnGeP2

    Science.gov (United States)

    Lippert, Espen; Fonnum, Helge; Haakestad, Magnus W.

    2014-10-01

    We present a high energy infrared laser source where a Tm:fiber laser is used to pump a high-energy 2-μm cryogenically cooled Ho:YLF laser. We have achieved 550 mJ of output energy at 2.05 μm, and through non-linear conversion in ZnGeP2 generated 200 mJ in the 3-5-μm range. Using a numerical simulation tool we have also investigated a setup which should generate more than 70 mJ in the 8-12-μm range. The conversion stage uses a master-oscillator-power-amplifier architecture to enable high conversion efficiency and good beam quality.

  4. Using Dual Isotopes and a Bayesian Isotope Mixing Model to Evaluate Nitrate Sources of Surface Water in a Drinking Water Source Watershed, East China

    Directory of Open Access Journals (Sweden)

    Meng Wang

    2016-08-01

    Full Text Available A high concentration of nitrate (NO3− in surface water threatens aquatic systems and human health. Revealing nitrate characteristics and identifying its sources are fundamental to making effective water management strategies. However, nitrate sources in multi-tributaries and mix land use watersheds remain unclear. In this study, based on 20 surface water sampling sites for more than two years’ monitoring from April 2012 to December 2014, water chemical and dual isotopic approaches (δ15N-NO3− and δ18O-NO3− were integrated for the first time to evaluate nitrate characteristics and sources in the Huashan watershed, Jianghuai hilly region, China. Nitrate-nitrogen concentrations (ranging from 0.02 to 8.57 mg/L were spatially heterogeneous that were influenced by hydrogeological and land use conditions. Proportional contributions of five potential nitrate sources (i.e., precipitation; manure and sewage, M & S; soil nitrogen, NS; nitrate fertilizer; nitrate derived from ammonia fertilizer and rainfall were estimated by using a Bayesian isotope mixing model. The results showed that nitrate sources contributions varied significantly among different rainfall conditions and land use types. As for the whole watershed, M & S (manure and sewage and NS (soil nitrogen were major nitrate sources in both wet and dry seasons (from 28% to 36% for manure and sewage and from 24% to 27% for soil nitrogen, respectively. Overall, combining a dual isotopes method with a Bayesian isotope mixing model offered a useful and practical way to qualitatively analyze nitrate sources and transformations as well as quantitatively estimate the contributions of potential nitrate sources in drinking water source watersheds, Jianghuai hilly region, eastern China.

  5. Safety Problems of Disposal of Disused Sealed Sources in the Baldone Near Surface Repository

    International Nuclear Information System (INIS)

    Dreimanis, A.

    2003-01-01

    Current Latvian regulations encourage re-export of DSS, however, up to now in the repository has been disposed a lot of DSS. Baldone repository has received RW (mainly DSS) from ∼ 300 Latvia objects and from Kaliningrad region (from 1964 to 1973). DSS cause the major part of activity of the repository - from the total activity in facility ∼ 400 TBq more than 300 TBq is due to DSS. A long term Safety Assessment (SA) of the Baldone Radon-type near surface disposal facility has been performed by the consortium CASSIOPEE and recommendations are given. The waste disposal system consists of: vaults 1-6 (closed, as permanent disposal site), vault 7 (as a long-term retrievable storage site); 2 main components of the engineered barriers: the capping system and the vaults. Vaults 1 and 3-6 (of re-fabricated concrete elements, closed with reinforced concrete slabs, covered with hydro isolating layer completed by a sand/ soil layer). The vault No.7 (ten 130 m 3 underground concrete walled storage cells, protected from the weather by the building. These 10 underground storage cells are adjacent (2x5) with additional concrete walls in some of them. The cells are covered by 40 cm concrete slabs placed side to side. The assessment context and development of scenarios are presented in the paper. The results from the SA are presented. For the waste pathway scenarios - the resulting doses - ∼ 4 mSv/y at 30 y in the current status without cover, justify the implantation of a cover for the closure period of the repository. For air pathway scenarios - the basic dose target 1 mSv/y (for public) is not satisfied for all scenarios; the resulting effective dose for the on-site 'Western' residential scenario for the vaults with highest content of DSS: vault 3 - 303 mSv/y; vault 7 - 204 mSv/y. The main recommendations from the SA are: General Advice - to dispose sources with half-lives < 5,3 y; for the spent sources - to build a new long-term storage; 2. To move DSS from Vault 7 to the

  6. Pure and Nb2O5-doped TiO2 amorphous thin films grown by dc magnetron sputtering at room temperature: Surface and photo-induced hydrophilic conversion studies

    International Nuclear Information System (INIS)

    Suchea, M.; Christoulakis, S.; Tudose, I.V.; Vernardou, D.; Lygeraki, M.I.; Anastasiadis, S.H.; Kitsopoulos, T.; Kiriakidis, G.

    2007-01-01

    Photo-induced hydrophilicity of titanium dioxide makes this material one of the most suitable for various coating applications in antifogging mirrors and self-cleaning glasses. The field of functional titanium dioxide coatings is expanding rapidly not only in applications for glass but also in applications for polymer, metal and ceramic materials. The high hydrophilic surface of TiO 2 is interesting for understanding also the basic photon-related surface science of titanium dioxide. In doing so, it is inevitably necessary to understand the relationship between the photoreaction and the surface properties. In this work, photo-induced hydrophilic conversion was evaluated on amorphous pure and niobium oxide-doped titanium dioxide thin films on Corning 1737F glass grown by dc magnetron sputtering technique at room temperature. This study is focused on the influence of the Ar:O ratio during sputtering plasma deposition on thin film surface morphology and subsequent photo-induced hydrophilic conversion results. Structural characterization carried out by X-ray diffraction and atomic force microscopy (AFM) has shown that our films are amorphous and extremely smooth with a surface roughness bellow 1 nm. Contact angle measurements were performed on as-deposited and during/after 10 min UV exposure. We present evidence that the photo-induced hydrophilic conversion of film surface is directly correlated with surface morphology and can be controlled by growth conditions

  7. sources

    Directory of Open Access Journals (Sweden)

    Shu-Yin Chiang

    2002-01-01

    Full Text Available In this paper, we study the simplified models of the ATM (Asynchronous Transfer Mode multiplexer network with Bernoulli random traffic sources. Based on the model, the performance measures are analyzed by the different output service schemes.

  8. Fecal pollution source tracking toolbox for identification, evaluation and characterization of fecal contamination in receiving urban surface waters and groundwater.

    Science.gov (United States)

    Tran, Ngoc Han; Gin, Karina Yew-Hoong; Ngo, Huu Hao

    2015-12-15

    The quality of surface waters/groundwater of a geographical region can be affected by anthropogenic activities, land use patterns and fecal pollution sources from humans and animals. Therefore, the development of an efficient fecal pollution source tracking toolbox for identifying the origin of the fecal pollution sources in surface waters/groundwater is especially helpful for improving management efforts and remediation actions of water resources in a more cost-effective and efficient manner. This review summarizes the updated knowledge on the use of fecal pollution source tracking markers for detecting, evaluating and characterizing fecal pollution sources in receiving surface waters and groundwater. The suitability of using chemical markers (i.e. fecal sterols, fluorescent whitening agents, pharmaceuticals and personal care products, and artificial sweeteners) and/or microbial markers (e.g. F+RNA coliphages, enteric viruses, and host-specific anaerobic bacterial 16S rDNA genetic markers) for tracking fecal pollution sources in receiving water bodies is discussed. In addition, this review also provides a comprehensive approach, which is based on the detection ratios (DR), detection frequencies (DF), and fate of potential microbial and chemical markers. DR and DF are considered as the key criteria for selecting appropriate markers for identifying and evaluating the impacts of fecal contamination in surface waters/groundwater. Copyright © 2015 Elsevier B.V. All rights reserved.

  9. Acoustic-gravity waves generated by atmospheric and near-surface sources

    Science.gov (United States)

    Kunitsyn, Viacheslav E.; Kholodov, Alexander S.; Krysanov, Boris Yu.; Andreeva, Elena S.; Nesterov, Ivan A.; Vorontsov, Artem M.

    2013-04-01

    . The ionospheric footprints of atmospheric disturbances are given. The effects of AGW evolution after launching the rockets are studied. One of the possible applications of RT imaging of wavelike disturbances is the study of AGW and TID as probable precursors of the earthquakes. The key difficulty here is to distinguish between the AGW and atmospheric and ionospheric disturbances of non-seismic nature (for example, those caused by the enhanced solar-geomagnetic activity), which can be done by analyzing spatial two-dimensional and three-dimensional structures revealed by tomographic methods. The examples of AGW RT imaging based on the real experimental satellite data measured in regions of the Europe, North America and Asia are demonstrated. The example of AGW and TID generation by the tsunami wave after the Tohoku earthquake is presented. Our results prove the capability of RT methods to detect wavelike disturbances in the ionosphere, which are caused by the near-surface sources, and to distinguish between these disturbances and the influence from the atmosphere and space. The work was supported by the Russian Foundation for Basic Research (grants 11-05-01157 and 13-05-01122 ).

  10. Application of Taguchi Design and Response Surface Methodology for Improving Conversion of Isoeugenol into Vanillin by Resting Cells of Psychrobacter sp. CSW4.

    Science.gov (United States)

    Ashengroph, Morahem; Nahvi, Iraj; Amini, Jahanshir

    2013-01-01

    For all industrial processes, modelling, optimisation and control are the keys to enhance productivity and ensure product quality. In the current study, the optimization of process parameters for improving the conversion of isoeugenol to vanillin by Psychrobacter sp. CSW4 was investigated by means of Taguchi approach and Box-Behnken statistical design under resting cell conditions. Taguchi design was employed for screening the significant variables in the bioconversion medium. Sequentially, Box-Behnken design experiments under Response Surface Methodology (RSM) was used for further optimization. Four factors (isoeugenol, NaCl, biomass and tween 80 initial concentrations), which have significant effects on vanillin yield, were selected from ten variables by Taguchi experimental design. With the regression coefficient analysis in the Box-Behnken design, a relationship between vanillin production and four significant variables was obtained, and the optimum levels of the four variables were as follows: initial isoeugenol concentration 6.5 g/L, initial tween 80 concentration 0.89 g/L, initial NaCl concentration 113.2 g/L and initial biomass concentration 6.27 g/L. Under these optimized conditions, the maximum predicted concentration of vanillin was 2.25 g/L. These optimized values of the factors were validated in a triplicate shaking flask study and an average of 2.19 g/L for vanillin, which corresponded to a molar yield 36.3%, after a 24 h bioconversion was obtained. The present work is the first one reporting the application of Taguchi design and Response surface methodology for optimizing bioconversion of isoeugenol into vanillin under resting cell conditions.

  11. Moving gantry method for electron beam dose profile measurement at extended source-to-surface distances.

    Science.gov (United States)

    Fekete, Gábor; Fodor, Emese; Pesznyák, Csilla

    2015-03-08

    A novel method has been put forward for very large electron beam profile measurement. With this method, absorbed dose profiles can be measured at any depth in a solid phantom for total skin electron therapy. Electron beam dose profiles were collected with two different methods. Profile measurements were performed at 0.2 and 1.2 cm depths with a parallel plate and a thimble chamber, respectively. 108cm × 108 cm and 45 cm × 45 cm projected size electron beams were scanned by vertically moving phantom and detector at 300 cm source-to-surface distance with 90° and 270° gantry angles. The profiles collected this way were used as reference. Afterwards, the phantom was fixed on the central axis and the gantry was rotated with certain angular steps. After applying correction for the different source-to-detector distances and incidence of angle, the profiles measured in the two different setups were compared. Correction formalism has been developed. The agreement between the cross profiles taken at the depth of maximum dose with the 'classical' scanning and with the new moving gantry method was better than 0.5 % in the measuring range from zero to 71.9 cm. Inverse square and attenuation corrections had to be applied. The profiles measured with the parallel plate chamber agree better than 1%, except for the penumbra region, where the maximum difference is 1.5%. With the moving gantry method, very large electron field profiles can be measured at any depth in a solid phantom with high accuracy and reproducibility and with much less time per step. No special instrumentation is needed. The method can be used for commissioning of very large electron beams for computer-assisted treatment planning, for designing beam modifiers to improve dose uniformity, and for verification of computed dose profiles.

  12. Thallium dispersal and contamination in surface sediments from South China and its source identification.

    Science.gov (United States)

    Liu, Juan; Wang, Jin; Chen, Yongheng; Shen, Chuan-Chou; Jiang, Xiuyang; Xie, Xiaofan; Chen, Diyun; Lippold, Holger; Wang, Chunlin

    2016-06-01

    Thallium (Tl) is a non-essential element in humans and it is considered to be highly toxic. In this study, the contents, sources, and dispersal of Tl were investigated in surface sediments from a riverine system (the western Pearl River Basin, China), whose catchment has been contaminated by mining and roasting of Tl-bearing pyrite ores. The isotopic composition of Pb and total contents of Tl and other relevant metals (Pb, Zn, Cd, Co, and Ni) were measured in the pyrite ores, mining and roasting wastes, and the river sediments. Widespread contamination of Tl was observed in the sediments across the river, with the highest concentration of Tl (17.3 mg/kg) measured 4 km downstream from the pyrite industrial site. Application of a modified Institute for Reference Materials and Measurement (IRMM) sequential extraction scheme in representative sediments unveiled that 60-90% of Tl and Pb were present in the residual fraction of the sediments. The sediments contained generally lower (206)Pb/(207)Pb and higher (208)Pb/(206)Pb ratios compared with the natural Pb isotope signature (1.2008 and 2.0766 for (206)Pb/(207)Pb and (208)Pb/(206)Pb, respectively). These results suggested that a significant fraction of non-indigenous Pb could be attributed to the mining and roasting activities of pyrite ores, with low (206)Pb/(207)Pb (1.1539) and high (208)Pb/(206)Pb (2.1263). Results also showed that approximately 6-88% of Tl contamination in the sediments originated from the pyrite mining and roasting activities. This study highlights that Pb isotopic compositions could be used for quantitatively fingerprinting the sources of Tl contamination in sediments. Copyright © 2016 Elsevier Ltd. All rights reserved.

  13. Dust Aerosols at the Source Region During ACE-ASIA: A Surface/Satellite Perspective

    Science.gov (United States)

    Tsay, Si-Chee; Lau, William K. M. (Technical Monitor)

    2001-01-01

    ACE (Aerosol Characterization Experiment)-Asia is designed to study the compelling variability in spatial and temporal scale of both pollution-derived and naturally occurring aerosols, which often exist in high concentrations over eastern Asia and along the rim of the western Pacific. The phase-I of ACE-Asia was conducted from March-May 2001 in the vicinity of the Gobi desert, East Coast of China, Yellow Sea, Korea, and Japan, along the pathway of Kosa (severe events that blanket East Asia with yellow desert dust, peaked in the Spring season). Asian dust typically originates in desert areas far from polluted urban regions. During transport, dust layers can interact with anthropogenic sulfate and soot aerosols from heavily polluted urban areas. Added to the complex effects of clouds and natural marine aerosols, dust particles reaching the marine environment can have drastically different properties than those from the source. Thus, understanding the unique temporal and spatial variations of Asian dust is of special importance in regional-to-global climate issues such as radiative forcing, the hydrological cycle, and primary biological productivity in the mid-Pacific Ocean. During ACE-Asia we have measured continuously aerosol physical/optical/radiative properties, column precipitable water amount, and surface reflectivity over homogeneous areas from surface. The inclusion of flux measurements permits the determination of dust aerosol radiative flux in addition to measurements of loading and optical thickness. At the time of the Terra/MODIS, SeaWiFS, TOMS and other satellite overpasses, these ground-based observations can provide valuable data to compare with satellite retrievals over land. Preliminary results will be presented and discussed their implications in regional climatic effects.

  14. Landlab: an Open-Source Python Library for Modeling Earth Surface Dynamics

    Science.gov (United States)

    Gasparini, N. M.; Adams, J. M.; Hobley, D. E. J.; Hutton, E.; Nudurupati, S. S.; Istanbulluoglu, E.; Tucker, G. E.

    2016-12-01

    Landlab is an open-source Python modeling library that enables users to easily build unique models to explore earth surface dynamics. The Landlab library provides a number of tools and functionalities that are common to many earth surface models, thus eliminating the need for a user to recode fundamental model elements each time she explores a new problem. For example, Landlab provides a gridding engine so that a user can build a uniform or nonuniform grid in one line of code. The library has tools for setting boundary conditions, adding data to a grid, and performing basic operations on the data, such as calculating gradients and curvature. The library also includes a number of process components, which are numerical implementations of physical processes. To create a model, a user creates a grid and couples together process components that act on grid variables. The current library has components for modeling a diverse range of processes, from overland flow generation to bedrock river incision, from soil wetting and drying to vegetation growth, succession and death. The code is freely available for download (https://github.com/landlab/landlab) or can be installed as a Python package. Landlab models can also be built and run on Hydroshare (www.hydroshare.org), an online collaborative environment for sharing hydrologic data, models, and code. Tutorials illustrating a wide range of Landlab capabilities such as building a grid, setting boundary conditions, reading in data, plotting, using components and building models are also available (https://github.com/landlab/tutorials). The code is also comprehensively documented both online and natively in Python. In this presentation, we illustrate the diverse capabilities of Landlab. We highlight existing functionality by illustrating outcomes from a range of models built with Landlab - including applications that explore landscape evolution and ecohydrology. Finally, we describe the range of resources available for new

  15. A New Energy Source for Organic Synthesis in Europa's Surface Ice

    Science.gov (United States)

    Borucki, Jerome G.; Khare, Bishun; Cruikshank, Dale P.; DeVincenzi, D. (Technical Monitor)

    2002-01-01

    Colored regions on Jupiter's satellite Europa and other icy bodies in the outer Solar System may be contaminated by organic macromolecular solid material that is produced when surface ices are exposed to electrical energy. Hypervelocity meteorite impacts and fracture release tidal and tectonic stresses in icy crusts in the form of electrical discharges, which provide the energy for in situ synthesis of the organic solids. We report measurements of electrical discharge, light emission, and magnetic phenomena in hypervelocity impacts into ice with projectiles with V approx. 5 km/s. Part of the projectile's kinetic energy is converted into electrical potential, while the mechanical disruption of the impact also releases stress energy as light, heat, electrical, and magnetic fields as secondary emissions. These newly recognized energy sources suggest that the dark material in the area of impact craters are tholins generated from the energy of the impacts and that well up from the fracture zone. Large pools of liquid water would persist under the meteorite crater for thousands of years, with the potential for prebiotic chemistry to take place at an accelerated rate due to energy pumped in from the secondary emissions.

  16. Pictorial Conversations.

    Science.gov (United States)

    Hooper, Kristina

    1982-01-01

    Provides the rationale for considering communication in a graphic domain and suggests a specific goal for designing work stations which provide graphic capabilities in educational settings. The central element of this recommendation is the "pictorial conversation", a highly interactive exchange that includes pictures as the central elements.…

  17. Distribution and sources of polycyclic aromatic hydrocarbons in surface sediments of rivers and an estuary in Shanghai, China

    International Nuclear Information System (INIS)

    Ying Liu; Ling Chen; Zhao Jianfu; Huang Qinghui; Zhu Zhiliang; Gao Hongwen

    2008-01-01

    Concentrations, spatial distribution and sources of 17 polycyclic aromatic hydrocarbons (PAHs) and methylnaphthalene were investigated in surface sediments of rivers and an estuary in Shanghai, China. Total PAH concentrations, excluding perylene, ranged from 107 to 1707 ng/g-dw. Sedimentary PAH concentrations of the Huangpu River were higher than those of the Yangtze Estuary. The concentration of the Suzhou River was close to the average concentration of the Huangpu River. PAHs source analysis suggested that, in the Yangtze Estuary, PAHs at locations far away from cities were mainly from petrogenic sources. At other locations, both petrogenic and pyrogenic inputs were significant. In the Huangpu and Suzhou Rivers, pyrogenic input outweighed other sources. The pyrogenic PAHs in the upper reaches of the Huangpu River were mainly from the incomplete combustion of grass, wood and coal, and those in the middle and lower reaches were from vehicle and vessel exhaust. - Surface sediments of two rivers and an estuary in Shanghai were contaminated by PAHs

  18. Workflow for near-surface velocity automatic estimation: Source-domain full-traveltime inversion followed by waveform inversion

    KAUST Repository

    Liu, Lu

    2017-08-17

    This paper presents a workflow for near-surface velocity automatic estimation using the early arrivals of seismic data. This workflow comprises two methods, source-domain full traveltime inversion (FTI) and early-arrival waveform inversion. Source-domain FTI is capable of automatically generating a background velocity that can kinematically match the reconstructed plane-wave sources of early arrivals with true plane-wave sources. This method does not require picking first arrivals for inversion, which is one of the most challenging aspects of ray-based first-arrival tomographic inversion. Moreover, compared with conventional Born-based methods, source-domain FTI can distinguish between slower or faster initial model errors via providing the correct sign of the model gradient. In addition, this method does not need estimation of the source wavelet, which is a requirement for receiver-domain wave-equation velocity inversion. The model derived from source-domain FTI is then used as input to early-arrival waveform inversion to obtain the short-wavelength velocity components. We have tested the workflow on synthetic and field seismic data sets. The results show source-domain FTI can generate reasonable background velocities for early-arrival waveform inversion even when subsurface velocity reversals are present and the workflow can produce a high-resolution near-surface velocity model.

  19. The use of surface power for characterisation of structure-borne sound sources of low modal density

    DEFF Research Database (Denmark)

    Ohlrich, Mogens

    1996-01-01

    The use of the surface power methods for source characterisaiton of vibrating machinery of low modal density is investigated in this paper. It was demonstrated by Ohlrich and Larsen that this relatively simple, but very useful measurement technique for quantifying the vibratory strength of machin......The use of the surface power methods for source characterisaiton of vibrating machinery of low modal density is investigated in this paper. It was demonstrated by Ohlrich and Larsen that this relatively simple, but very useful measurement technique for quantifying the vibratory strength...

  20. Spheroidal and toroidal configurations as sources of the Kerr metric. Pt. 1. A kinematical approach. [Boyer surface condition, singularity

    Energy Technology Data Exchange (ETDEWEB)

    de Felice, F; Nobili, L [Padua Univ. (Italy). Istituto di Fisica; Calvani, M [Padua univ. (Italy). Istituto di Astronomia

    1976-03-01

    The existence of extended Kerr metric sources of perfect fluid is taken as work-hypothesis to investigate the structure of the boundaries which derive from Boyer's surface condition. We find closed spheroidal configurations which hide an internal cavity as well as toroidal configurations; however, both the boundary of the internal cavity and the tori touch the ring singularity. We judge this feature non-physical and conclude that Boyer's condition is not sufficient to completely define a well behaved physical source.

  1. Generation of H-, D- ions on composite surfaces with application to surface/plasma ion source systems

    International Nuclear Information System (INIS)

    Hiskes, J.R.; Karo, A.M.; Wimmer, E.; Freeman, A.J.; Chubb, S.R.

    1983-01-01

    We review some salient features of the experimental and theoretical data pertaining to hydrogen negative ion generation on minimum-work-function composite surfaces consisting of Cs/transition metal substrates. Cesium or hydrogen ion bombardment of a cesium-activated negatively-biased electrode exposed to a cesium-hydrogen discharge results in the release of hydrogen negative ions. These ions originate through desorbtion of hydrogen particles by incident cesium ions, desorbtion by incident hydrogen ions, and by backscattering of incident hydrogen. Each process is characterized by a specific energy and angular distribution. The calculation of ion formation in the crystal selvage region is discussed for different approximations to the surface potential. An ab initio, all-electron, local density functional model for the composite surface electronics is discussed

  2. Post-closure safety assessment of near surface disposal facilities for disused sealed radioactive sources

    International Nuclear Information System (INIS)

    Lee, Seunghee; Kim, Juyoul

    2017-01-01

    Highlights: • Post-closure safety assessment of near surface disposal facility for DSRS was performed. • Engineered vault and rock-cavern type were considered for normal and well scenario. • 14 C, 226 Ra, 241 Am were primary nuclides contributing large portion of exposure dose. • Near surface disposal of DSRSs containing 14 C, 226 Ra and 241 Am should be restricted. - Abstract: Great attention has been recently paid to the post-closure safety assessment of low- and intermediate-level radioactive waste (LILW) disposal facility for disused sealed radioactive sources (DSRSs) around the world. Although the amount of volume of DSRSs generated from industry, medicine and research and education organization was relatively small compared with radioactive wastes from commercial nuclear power plants, some DSRSs can pose a significant hazard to human health due to their high activities and long half-lives, if not appropriately managed and disposed. In this study, post-closure safety assessment was carried out for DSRSs generated from 1991 to 2014 in Korea in order to ensure long-term safety of near surface disposal facilities. Two kinds of disposal options were considered, i.e., engineered vault type disposal facility and rock-cavern type disposal facility. Rock-cavern type disposal facility has been under operation in Gyeongju city, republic of Korea since August 2015 and engineered vault type disposal facility will be constructed until December 2020 in the vicinity of rock-cavern disposal facility. Assessment endpoint was individual dose to the member of critical group, which was modeled by GoldSim, which has been widely used as probabilistic risk analysis software based on Monte Carlo simulation in the area of safety assessment of radioactive waste facilities. In normal groundwater scenario, the maximum exposure dose was extremely low, approximately 1 × 10 −7 mSv/yr, for both disposal options and satisfied the regulatory limit of 0.1 mSv/yr. However, in the

  3. Post-closure safety assessment of near surface disposal facilities for disused sealed radioactive sources

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Seunghee; Kim, Juyoul, E-mail: gracemi@fnctech.com

    2017-03-15

    Highlights: • Post-closure safety assessment of near surface disposal facility for DSRS was performed. • Engineered vault and rock-cavern type were considered for normal and well scenario. • {sup 14}C, {sup 226}Ra, {sup 241}Am were primary nuclides contributing large portion of exposure dose. • Near surface disposal of DSRSs containing {sup 14}C, {sup 226}Ra and {sup 241}Am should be restricted. - Abstract: Great attention has been recently paid to the post-closure safety assessment of low- and intermediate-level radioactive waste (LILW) disposal facility for disused sealed radioactive sources (DSRSs) around the world. Although the amount of volume of DSRSs generated from industry, medicine and research and education organization was relatively small compared with radioactive wastes from commercial nuclear power plants, some DSRSs can pose a significant hazard to human health due to their high activities and long half-lives, if not appropriately managed and disposed. In this study, post-closure safety assessment was carried out for DSRSs generated from 1991 to 2014 in Korea in order to ensure long-term safety of near surface disposal facilities. Two kinds of disposal options were considered, i.e., engineered vault type disposal facility and rock-cavern type disposal facility. Rock-cavern type disposal facility has been under operation in Gyeongju city, republic of Korea since August 2015 and engineered vault type disposal facility will be constructed until December 2020 in the vicinity of rock-cavern disposal facility. Assessment endpoint was individual dose to the member of critical group, which was modeled by GoldSim, which has been widely used as probabilistic risk analysis software based on Monte Carlo simulation in the area of safety assessment of radioactive waste facilities. In normal groundwater scenario, the maximum exposure dose was extremely low, approximately 1 × 10{sup −7} mSv/yr, for both disposal options and satisfied the regulatory limit

  4. Catalytic Conversion of Carbohydrates

    DEFF Research Database (Denmark)

    Osmundsen, Christian Mårup

    a renewable route to aromatics. The conversion of biomass by high temperature processes is a desirable prospect due to the high volumetric production rates which can be achieved, and the ability of these types of processes to convert a wide range of substrates. Current processes however typically have rather...... with the production of commodity chemicals from the most abundantly available renewable source of carbon, carbohydrates. The production of alkyl lactates by the Lewis acid catalyzed conversion of hexoses is an interesting alternative to current fermentation based processes. A range of stannosilicates were...... to be an efficient initial conversion step in the utilization of biomass for chemicals production. The shift from an oil based chemical industry to one based on renewable resources is bound to happen sooner or later, however the environmental problems associated with the burning of fossil resources means...

  5. New method to determine initial surface water displacement at tsunami source

    Science.gov (United States)

    Lavrentyev, Mikhail; Romanenko, Alexey; Tatarintsev, Pavel

    2013-04-01

    Friday, March 11, 2011 at 05:46:23 UTC, Japan was struck by an 8.9-magnitude earthquake near its Northeastern coast. This is one of the largest earthquakes that Japan has ever experienced. Tsunami waves swept away houses and cars and caused massive human losses. To predict tsunami wave parameters better and faster, we propose to improve data inversion scheme and achieve the performance gain of data processing. One of the reasons of inaccurate predictions of tsunami parameters is that very little information is available about the initial disturbance of the sea bed at tsunami source. In this paper, we suggest a new way of improving the quality of tsunami source parameters prediction. Modern computational technologies can accurately calculate tsunami wave propagation over the deep ocean provided that the initial displacement (perturbation of the sea bed at tsunami source) is known [4]. Direct geophysical measurements provide the location of an earthquake hypocenter and its magnitude (the released energy evaluation). Among the methods of determination of initial displacement the following ones should be considered. Calculation through the known fault structure and available seismic information. This method is widely used and provides useful information. However, even if the exact knowledge about rock blocks shifts is given, recalculation in terms of sea bed displacement is needed. This results in a certain number of errors. GPS data analysis. This method was developed after the December 2004 event in the Indian Ocean. A good correlation between dry land based GPS sensors and tsunami wave parameters was observed in the particular case of the West coast of Sumatra, Indonesia. This approach is very unique and can hardly been used in other geo locations. Satellite image analysis. The resolution of modern satellite images has dramatically improved. In the future, correct data of sea surface displacement will probably be available in real time, right after a tsunamigenic

  6. Surface-ionization ion source designed for in-beam operation with the BEMS-2 isotope separator

    International Nuclear Information System (INIS)

    Bogdanov, D.D.; Voboril, J.; Demyanov, A.V.; Karnaukhov, V.A.; Petrov, L.A.

    1976-01-01

    A surface-ionization ion source designed to operate in combination with the BEMS-2 isotope separator in a heavy ion beam is described. The ion source is adjusted for the separation of rare-earth elements. The separation efficiency for 150 Dy is determined to be equal to about 20% at the ionizer temperature of 2600 deg K. The hold-up times for praseodymium, promethium and dysprosium in the ion source range from 5 to 10 sec at the ionizer temperature of 2500-2700 deg K

  7. External dose-rate conversion factors of radionuclides for air submersion, ground surface contamination and water immersion based on the new ICRP dosimetric setting.

    Science.gov (United States)

    Yoo, Song Jae; Jang, Han-Ki; Lee, Jai-Ki; Noh, Siwan; Cho, Gyuseong

    2013-01-01

    For the assessment of external doses due to contaminated environment, the dose-rate conversion factors (DCFs) prescribed in Federal Guidance Report 12 (FGR 12) and FGR 13 have been widely used. Recently, there were significant changes in dosimetric models and parameters, which include the use of the Reference Male and Female Phantoms and the revised tissue weighting factors, as well as the updated decay data of radionuclides. In this study, the DCFs for effective and equivalent doses were calculated for three exposure settings: skyshine, groundshine and water immersion. Doses to the Reference Phantoms were calculated by Monte Carlo simulations with the MCNPX 2.7.0 radiation transport code for 26 mono-energy photons between 0.01 and 10 MeV. The transport calculations were performed for the source volume within the cut-off distances practically contributing to the dose rates, which were determined by a simplified calculation model. For small tissues for which the reduction of variances are difficult, the equivalent dose ratios to a larger tissue (with lower statistical errors) nearby were employed to make the calculation efficient. Empirical response functions relating photon energies, and the organ equivalent doses or the effective doses were then derived by the use of cubic-spline fitting of the resulting doses for 26 energy points. The DCFs for all radionuclides considered important were evaluated by combining the photon emission data of the radionuclide and the empirical response functions. Finally, contributions of accompanied beta particles to the skin equivalent doses and the effective doses were calculated separately and added to the DCFs. For radionuclides considered in this study, the new DCFs for the three exposure settings were within ±10 % when compared with DCFs in FGR 13.

  8. Linear surface photoelectric effect of gold in intense laser field as a possible high-current electron source

    International Nuclear Information System (INIS)

    Farkas, G.; Horvath, Z.G.; Toth, C.; Fotakis, C.; Hontzopoulos, E.

    1987-01-01

    Investigations were conducted on radiation-induced electron emission processes on a gold target surface with a high-intensity (2 MW/cm 2 ) KrF laser (λ = 248 nm). The single photon surface photoelectric emission obtained can be used for high-current density electron sources. The measured polarization dependence of electron current shows the dominance of the surface-type effect over that of the volume type, thereby making it possible to optimize the short, high-density electron current creation conditions. The advantage of the grazing light incidence and the multiphoton photoeffect giving rise to a 500 A/cm 2 electron current has been demonstrated

  9. Leaf surface wax is a source of plant methane formation under UV radiation and in the presence of oxygen

    DEFF Research Database (Denmark)

    Bruhn, Dan; Mikkelsen, Teis Nørgaard; Rolsted, M. M. M.

    2014-01-01

    to this, we demonstrated that the UV radiation-induced CH4 emission is independent of leaf area index above unity. Further, we observed that the presence of O2 in the atmosphere was necessary for achieving the highest rates of CH4 emission. Methane formation from leaf surface wax is supposedly a two...... investigated the potential of the leaf surface wax itself as a source of UV radiationinduced leaf aerobic CH4 formation. Isolated leaf surface wax emitted CH4 at substantial rates in response to UV radiation. This discovery has implications for how the phenomenon should be scaled to global levels. In relation...

  10. Quantum conversion

    OpenAIRE

    Mazilu, Michael

    2015-01-01

    ICOAM 2015 The electromagnetic momentum transferred transferred to scattering particles is proportional to the intensity of the incident fields, however, the momentum of single photons ℏk does not naturally appear in these classical expressions. Here, we discuss an alternative to Maxwell's stress tensor that renders the classical electromagnetic field momentum compatible to the quantum mechanical one. This is achieved through the introduction of the quantum conversion which allows the tran...

  11. Conversational sensemaking

    Science.gov (United States)

    Preece, Alun; Webberley, Will; Braines, Dave

    2015-05-01

    Recent advances in natural language question-answering systems and context-aware mobile apps create opportunities for improved sensemaking in a tactical setting. Users equipped with mobile devices act as both sensors (able to acquire information) and effectors (able to act in situ), operating alone or in collectives. The currently- dominant technical approaches follow either a pull model (e.g. Apple's Siri or IBM's Watson which respond to users' natural language queries) or a push model (e.g. Google's Now which sends notifications to a user based on their context). There is growing recognition that users need more flexible styles of conversational interaction, where they are able to freely ask or tell, be asked or told, seek explanations and clarifications. Ideally such conversations should involve a mix of human and machine agents, able to collaborate in collective sensemaking activities with as few barriers as possible. Desirable capabilities include adding new knowledge, collaboratively building models, invoking specific services, and drawing inferences. As a step towards this goal, we collect evidence from a number of recent pilot studies including natural experiments (e.g. situation awareness in the context of organised protests) and synthetic experiments (e.g. human and machine agents collaborating in information seeking and spot reporting). We identify some principles and areas of future research for "conversational sensemaking".

  12. Utilizing various data sources for surface transportation human factors research : workshop summary report, November 6-7, 2013

    Science.gov (United States)

    2014-07-01

    The report summarizes a 2-day workshop held on November 6-7, 2013, to discuss data sources for surface transportation human factors research. The workshop was designed to assess the increasing number of different datasets and multiple ways of collect...

  13. A new approach for calculation of volume confined by ECR surface and its area in ECR ion source

    International Nuclear Information System (INIS)

    Filippov, A.V.

    2007-01-01

    The volume confined by the resonance surface and its area are important parameters of the balance equations model for calculation of ion charge-state distribution (CSD) in the electron-cyclotron resonance (ECR) ion source. A new approach for calculation of these parameters is given. This approach allows one to reduce the number of parameters in the balance equations model

  14. Safety considerations of disposal of disused sealed sources in near surface facilities

    International Nuclear Information System (INIS)

    Pla, E.

    2003-01-01

    The report presents European commission studies on sealed radioactive sources - Management of Spent Radiation Sources in the European Union: Quantities, Storage, Recycling and Disposal. EUR 16960 EN. EC 1996; Management of sealed radioactive sources produced and sold in the Russian Federation. EUR 18191 EN. EC, 1999; Management and Disposal of Disused Sealed Radioactive Sources in the European Union. EUR 18186 EN. EC, 2000; Management of Spent Sealed Radioactive Sources in Central and Eastern Europe. EUR 19842 EN. EC, April 2001; Management of Spent Sealed Radioactive Sources in Bulgaria, Latvia, Lithuania, Romania and Slovakia. EUR 20654 EN. EC, January 2003. The conclusions and recommendations in them are given. The International catalogue of sealed radioactive sources and devices is described

  15. Distribution, sources and ecological risk assessment of PAHs in surface sediments from the Luan River Estuary, China.

    Science.gov (United States)

    Zhang, Daolai; Liu, Jinqing; Jiang, Xuejun; Cao, Ke; Yin, Ping; Zhang, Xunhua

    2016-01-15

    The distribution, sources and risk assessment of 16 polycyclic aromatic hydrocarbons (PAHs) of surface sediments in the Luan River Estuary, China, have been investigated in the research. The results indicated that the total concentrations of 16 PAHs in surface sediments of the Luan River Estuary ranged from 5.1 to 545.1 ng g(-1)dw with a mean value of 120.8 ng g(-1)dw, which is relatively low in comparison with other estuaries around the world. The PAHs in the study area were mainly originated from pyrogenic sources. Besides, PAHs may be contaminated by petrogenic PAHs as indicated by the selected ratios of PAHs, the 2-tailed Pearson correlation analysis and principal components analysis at different sites. The result of the ecological risk assessment shows little negative effect for most individual PAHs in surface sediments of the Luan River Estuary, China. Copyright © 2015 Elsevier Ltd. All rights reserved.

  16. SU-E-T-459: Impact of Source Position and Traveling Time On HDR Skin Surface Applicator Dosimetry

    International Nuclear Information System (INIS)

    Jeong, J; Barker, C; Zaider, M; Cohen, G

    2015-01-01

    Purpose: Observed dosimetric discrepancy between measured and treatment planning system (TPS) predicted values, during applicator commissioning, were traced to source position uncertainty in the applicator. We quantify the dosimetric impact of this geometric uncertainty, and of the source traveling time inside the applicator, and propose corrections for clinical use. Methods: We measured the dose profiles from the Varian Leipzig-style (horizontal) HDR skin applicator, using EBT3 film, photon diode, and optically stimulated luminescence dosimeter (OSLD) and three different GammaMed HDR afterloders. The dose profiles and depth dose of each aperture were measured at several depths (up to about 10 mm, depending on the dosimeter). The measured dose profiles were compared with Acuros calculated profiles in BrachyVision TPS. For the impact of the source position, EBT3 film measurements were performed with applicator, facing-down and facing-up orientations. The dose with and without source traveling was measured with diode detector using HDR timer and electrometer timer, respectively. Results: Depth doses measured using the three dosimeters were in good agreement, but were consistently higher than the Acuros dose calculations. Measurements with the applicator facing-up were significantly lower than those in the facing-down position with maximum difference of about 18% at the surface, due to source sag inside the applicator. Based on the inverse-square law, the effective source sag was evaluated to be about 0.5 mm from the planned position. The additional dose from the source traveling was about 2.8% for 30 seconds with 10 Ci source, decreasing with increased dwelling time and decreased source activity. Conclusion: Due to the short source-to-surface distance of the applicator, the small source sag inside the applicator has significant dosimetric impact, which should be considered before the clinical use of the applicator. Investigation of the effect for other applicators

  17. Source attribution of Arctic black carbon constrained by aircraft and surface measurements

    Directory of Open Access Journals (Sweden)

    J.-W. Xu

    2017-10-01

    Full Text Available Black carbon (BC contributes to Arctic warming, yet sources of Arctic BC and their geographic contributions remain uncertain. We interpret a series of recent airborne (NETCARE 2015; PAMARCMiP 2009 and 2011 campaigns and ground-based measurements (at Alert, Barrow and Ny-Ålesund from multiple methods (thermal, laser incandescence and light absorption with the GEOS-Chem global chemical transport model and its adjoint to attribute the sources of Arctic BC. This is the first comparison with a chemical transport model of refractory BC (rBC measurements at Alert. The springtime airborne measurements performed by the NETCARE campaign in 2015 and the PAMARCMiP campaigns in 2009 and 2011 offer BC vertical profiles extending to above 6 km across the Arctic and include profiles above Arctic ground monitoring stations. Our simulations with the addition of seasonally varying domestic heating and of gas flaring emissions are consistent with ground-based measurements of BC concentrations at Alert and Barrow in winter and spring (rRMSE  < 13 % and with airborne measurements of the BC vertical profile across the Arctic (rRMSE  = 17 % except for an underestimation in the middle troposphere (500–700 hPa.Sensitivity simulations suggest that anthropogenic emissions in eastern and southern Asia have the largest effect on the Arctic BC column burden both in spring (56 % and annually (37 %, with the largest contribution in the middle troposphere (400–700 hPa. Anthropogenic emissions from northern Asia contribute considerable BC (27 % in spring and 43 % annually to the lower troposphere (below 900 hPa. Biomass burning contributes 20 % to the Arctic BC column annually.At the Arctic surface, anthropogenic emissions from northern Asia (40–45 % and eastern and southern Asia (20–40 % are the largest BC contributors in winter and spring, followed by Europe (16–36 %. Biomass burning from North America is the most important

  18. The use of an ion-beam source to alter the surface morphology of biological implant materials

    Science.gov (United States)

    Weigand, A. J.

    1978-01-01

    An electron-bombardment ion-thruster was used as a neutralized-ion-beam sputtering source to texture the surfaces of biological implant materials. The materials investigated included 316 stainless steel; titanium-6% aluminum, 4% vanadium; cobalt-20% chromium, 15% tungsten; cobalt-35% nickel, 20% chromium, 10% molybdenum; polytetrafluoroethylene; polyoxymethylene; silicone and polyurethane copolymer; 32%-carbon-impregnated polyolefin; segmented polyurethane; silicone rubber; and alumina. Scanning electron microscopy was used to determine surface morphology changes of all materials after ion-texturing. Electron spectroscopy for chemical analysis was used to determine the effects of ion-texturing on the surface chemical composition of some polymers. Liquid contact angle data were obtained for ion-textured and untextured polymer samples. Results of tensile and fatigue tests of ion-textured metal alloys are presented. Preliminary data of tissue response to ion-textured surfaces of some metals, polytetrafluoroethylene, alumina, and segmented polyurethane have been obtained.

  19. Replacement of ultrasonic energy as the heat source for a greener bio diesel production: A response surface methodology

    International Nuclear Information System (INIS)

    Babak Salamatinia; Hamed Mootabadi; Subhash Bhatia; Ahmad Zuhairi Abdullah

    2010-01-01

    The use of ultrasonic energy for mixing and the subsequent conversion to heat energy in the transesterification reaction of vegetable oil is reported. Effects of 5 important variables i.e. pulse on (s), pulse off (s), reaction time (min), power (%) and oil volume (ml) at constant alcohol to palm oil molar ratio (9:1) and initial reaction temperature of 35 degree Celsius were studied. A central composite design (CCD) using response surface technology (RSM) was employed. The results indicated that the reaction time did not play much role as the system reached steady state within the first few minutes. Longer the pulse on and the lower the pulse off at 70 % of the maximum power of could bring the reaction to desired temperature for volume of up to 60 ml. A model was proposed based on heat capacity of reactants for conversion of ultrasonic into heat and the final temperature of the system could be predicted. This model was tested with 5 types of vegetable oil including used palm oil, canola oil, sunflower oil and corn oil to study the effect of specific heat capacity of the oil. Three different types of catalysts with varying heat capacities were also tested for verification of the model. The model developed showed good predictions with less than 5 % error in different conditions. (author)

  20. Hall Current Plasma Source Having a Center-Mounted or a Surface-Mounted Cathode

    Science.gov (United States)

    Martinez, Rafael A. (Inventor); Williams, John D. (Inventor); Moritz, Jr., Joel A. (Inventor); Farnell, Casey C. (Inventor)

    2018-01-01

    A miniature Hall current plasma source apparatus having magnetic shielding of the walls from ionized plasma, an integrated discharge channel and gas distributor, an instant-start hollow cathode mounted to the plasma source, and an externally mounted keeper, is described. The apparatus offers advantages over other Hall current plasma sources having similar power levels, including: lower mass, longer lifetime, lower part count including fewer power supplies, and the ability to be continuously adjustable to lower average power levels using pulsed operation and adjustment of the pulse duty cycle. The Hall current plasma source can provide propulsion for small spacecraft that either do not have sufficient power to accommodate a propulsion system or do not have available volume to incorporate the larger propulsion systems currently available. The present low-power Hall current plasma source can be used to provide energetic ions to assist the deposition of thin films in plasma processing applications.

  1. Poorly processed reusable surface disinfection tissue dispensers may be a source of infection.

    Science.gov (United States)

    Kampf, Günter; Degenhardt, Stina; Lackner, Sibylle; Jesse, Katrin; von Baum, Heike; Ostermeyer, Christiane

    2014-01-21

    Reusable surface disinfectant tissue dispensers are used in hospitals in many countries because they allow immediate access to pre-soaked tissues for targeted surface decontamination. On the other hand disinfectant solutions with some active ingredients may get contaminated and cause outbreaks. We determined the frequency of contaminated surface disinfectant solutions in reusable dispensers and the ability of isolates to multiply in different formulations. Reusable tissue dispensers with different surface disinfectants were randomly collected from healthcare facilities. Solutions were investigated for bacterial contamination. The efficacy of two surface disinfectants was determined in suspension tests against two isolated species directly from a contaminated solution or after 5 passages without selection pressure in triplicate. Freshly prepared use solutions were contaminated to determine survival of isolates. 66 dispensers containing disinfectant solutions with surface-active ingredients were collected in 15 healthcare facilities. 28 dispensers from nine healthcare facilities were contaminated with approximately 107 cells per mL of Achromobacter species 3 (9 hospitals), Achromobacter xylosoxidans or Serratia marcescens (1 hospital each). In none of the hospitals dispenser processing had been adequately performed. Isolates regained susceptibility to the disinfectants after five passages without selection pressure but were still able to multiply in different formulations from different manufacturers at room temperature within 7 days. Neglecting adequate processing of surface disinfectant dispensers has contributed to frequent and heavy contamination of use-solutions based on surface active ingredients. Tissue dispenser processing should be taken seriously in clinical practice.

  2. Elucidating source processes of N2O fluxes following grassland-to-field-conversion using isotopologue signatures of soil-emitted N2O

    Science.gov (United States)

    Roth, G.; Giesemann, A.; Well, R.; Flessa, H.

    2012-04-01

    Conversion of grassland to arable land often causes enhanced nitrous oxide (N2O) emissions to the atmosphere. This is due to the tillage of the sward and subsequent decomposition of organic matter. Prediction of such effects is uncertain so far because emissions may differ depending on site and soil conditions. The processes of N2O turnover (nitrification, production by bacterial or fungal denitrifiers, bacterial reduction to N2) are difficult to identify, however. Isotopologue signatures of N2O such as δ18O, average δ15N (δ15Nbulk) and 15N site preference (SP = difference in δ15N between the central and peripheral N positions of the asymmetric N2O molecule) can be used to characterize N2O turnover processes using the known ranges of isotope effects of the various N2O pathways. We aim to evaluate the impact of grassland-to-field-conversion on N2O fluxes and the governing processes using isotopic signatures of emitted N2O. At two sites, in Kleve (North Rhine-Westphalia, Germany, conventional farming) and Trenthorst (Schleswig-Holstein, Germany, organic farming), a four times replicated plot experiment with (i) mechanical conversion (ploughing, maize), (ii) chemical conversion (broadband herbicide, maize per direct seed) and (iii) continuous grassland as reference was started in April 2010. In Trenthorst we additionally established a (iv) field with continuous maize cultivation as further reference. Over a period of two years, mineral nitrogen (Nmin) content was measured weekly on soil samples taken from 0-10 cm and 10-30 cm depth. Soil water content and N2O emissions were measured weekly as well. Gas samples were collected using a closed chamber system. Isotope ratio mass spectrometry was carried out on gas samples from selected high flux events to determine δ18O, δ15Nbulk and SP of N2O. δ18O and SP of N2O exhibited a relatively large range (32 to 72 ‰ and 6 to 34 ‰, respectively) indicating highly variable process dynamics. The data-set is grouped

  3. Mid-infrared source with 0.2 J pulse energy based on nonlinear conversion of Q-switched pulses in ZnGeP2.

    Science.gov (United States)

    Haakestad, Magnus W; Fonnum, Helge; Lippert, Espen

    2014-04-07

    Mid-infrared (3-5 μm) pulses with high energy are produced using nonlinear conversion in a ZnGeP(2)-based master oscillator-power amplifier, pumped by a Q-switched cryogenic Ho:YLF oscillator. The master oscillator is based on an optical parametric oscillator with a V-shaped 3-mirror ring resonator, and the power amplifier is based on optical parametric amplification in large-aperture ZnGeP(2) crystals. Pulses with up to 212 mJ energy at 1 Hz repetition rate are obtained, with FWHM duration 15 ns and beam quality M(2) = 3.

  4. Disposal of disused sealed sources and approach for safety assessment of near surface disposal facilities (national practice of Ukraine)

    International Nuclear Information System (INIS)

    Alekseeva, Z.; Letuchy, A.; Tkachenko, N.V.

    2003-01-01

    The main sources of wastes are 13 units of nuclear power plants under operation at 4 NPP sites (operational wastes and spent sealed sources), uranium-mining industry, area of Chernobyl exclusion zone contaminated as a result of ChNPP accident, and over 8000 small users of sources of ionising radiation in different fields of scientific, medical and industrial applications. The management of spent sources is carried out basing on the technology from the early sixties. In accordance with this scheme accepted sources are disposed of either in the near surface concrete vaults or in borehole facilities of typical design. Radioisotope devices and gamma units are placed into near surface vaults and sealed sources in capsules into borehole repositories respectively. Isotope content of radwaste in the repositories is multifarious including Co-60, Cs-137, Sr-90, Ir-192, Tl-204, Po-210, Ra-226, Pu-239, Am-241, H-3, Cf-252. A new programme for waste management has been adopted. It envisions the modifying of the 'Radon' facilities for long-term storage safety assessment and relocation of respective types of waste in 'Vector' repositories.Vector Complex will be built in the site which is located within the exclusion zone 10Km SW of the Chernobyl NPP. In Vector Complex two types of disposal facilities are designed to be in operation: 1) Near surface repositories for short lived LLRW and ILRW disposal in reinforced concrete containers. Repositories will be provided with multi layer waterproofing barriers - concrete slab on layer composed of mixture of sand and clay. Every layer of radwaste is supposed to be filled with 1cm clay layer following disposal; 2) Repositories for disposal of bulky radioactive waste without cans into concrete vaults. Approaches to safety assessment are discussed. Safety criteria for waste disposal in near surface repositories are established in Radiation Protection Standards (NRBU-97) and Addendum 'Radiation protection against sources of potential exposure

  5. Defect inspection in hot slab surface: multi-source CCD imaging based fuzzy-rough sets method

    Science.gov (United States)

    Zhao, Liming; Zhang, Yi; Xu, Xiaodong; Xiao, Hong; Huang, Chao

    2016-09-01

    To provide an accurate surface defects inspection method and make the automation of robust image region of interests(ROI) delineation strategy a reality in production line, a multi-source CCD imaging based fuzzy-rough sets method is proposed for hot slab surface quality assessment. The applicability of the presented method and the devised system are mainly tied to the surface quality inspection for strip, billet and slab surface etcetera. In this work we take into account the complementary advantages in two common machine vision (MV) systems(line array CCD traditional scanning imaging (LS-imaging) and area array CCD laser three-dimensional (3D) scanning imaging (AL-imaging)), and through establishing the model of fuzzy-rough sets in the detection system the seeds for relative fuzzy connectedness(RFC) delineation for ROI can placed adaptively, which introduces the upper and lower approximation sets for RIO definition, and by which the boundary region can be delineated by RFC region competitive classification mechanism. For the first time, a Multi-source CCD imaging based fuzzy-rough sets strategy is attempted for CC-slab surface defects inspection that allows an automatic way of AI algorithms and powerful ROI delineation strategies to be applied to the MV inspection field.

  6. Hypothesis for the mechanism of negative ion production in the surface-plasma negative hydrogen ion source

    International Nuclear Information System (INIS)

    Hiskes, J.R.

    1975-01-01

    An analysis of the surface-plasma negative hydrogen ion source has shown that the tungsten cathode supports approximately a monolayer of cesium. The backscattering of protons from the cathode as energetic neutrals and the subsequent backscattering of these neutrals from the anode provides for a flux of energetic atoms incident upon the cathode which is comparable to the ion flux. A hypothesis is proposed for the generation of negative ions during the collision of these energetic atoms with the cathode. Several mechanisms for negative ion production by proton collision with the surface are discussed. (U.S.)

  7. A CASE STUDY OF NONPOINT SOURCES BACTERIAL CONTRIBUTION TO RURAL SURFACE WATER

    Science.gov (United States)

    The presentation will address several bacterial issues affecting the Turkey Creek (TC) watershed, in north central Ok. Our results from seasonal stream Escherichia coli (E. coli) analysis, bacterial source tracking, and antibiotic resistance will be shared and discussed in relat...

  8. Active tectonics in Central Italy: Constraint from surface wave tomography and source moment tensor inversion

    International Nuclear Information System (INIS)

    Chimera, G.; Aoudia, A.; Panza, G.F.; Sarao, A.

    2002-06-01

    We make a multiscale investigation of the lithosphere-asthenosphere structure and of the active tectonics along a stripe from the Tyrrhenian to the Adriatic coast, with emphasis on the Umbria-Marche area, by means of surface-wave tomography and inversion experiments for structure and seismic moment tensor retrieval. The data include: a large number of new local and regional group velocity measurements sampling the Umbria-Marche Apennines and the Adria margin respectively; new and published phase velocity measurements sampling Italy and surroundings; deep seismic soundings which, crossing the whole Peninsula from the Tyrrhenian to the Adriatic coasts, go through the Umbria-Marche area. The local group velocity maps cover the area reactivated by the 1997-1998 Umbria-Marche earthquake sequence. These maps suggest an intimate relation between the lateral variations and distribution of the active fault systems and related sedimentary basins. Such relation is confirmed by the non-linear inversion of the local dispersion curves. To image the structure of the lithosphere-asthenosphere system from the Tyrrhenian to the Adriatic coast, we fix the upper crust parameters consistently with our Umbria-Marche models and with pertinent deep seismic sounding data and invert the regional long period dispersion measurements. At a local scale, in the Umbria-Marche area, the retrieved models for the upper crust reveal the importance of the inherited compressional tectonics on the ongoing extensional deformation and related seismic activity. The lateral and in-depth structural changes in the upper crust are likely controlling fault segmentation and seismogenesis. Source inversion studies of the large crustal events of the 1997 earthquake sequence show the dominance of normal faulting mechanisms, whereas selected aftershocks between the fault segments reveal that the prevailing deformation at the step-over is of strike-slip faulting type and may control the lateral fault extent. At the

  9. Change of the Asian dust source region deduced from the composition of anthropogenic radionuclides in surface soil in Mongolia

    Directory of Open Access Journals (Sweden)

    Y. Igarashi

    2011-07-01

    Full Text Available Recent climate change, especially during the 2000s, may be the primary reason for the expansion of the Asian dust source region. The change in the dust source region was investigated by examining anthropogenic radionuclides contained in surface soil samples from Mongolia. Surface soil was globally labeled by radioactive fallout from nuclear testing during the late 1950s and early 1960s, but there are no current direct sources for anthropogenic radionuclides in the air (before the Fukushima nuclear power plant accident in 2011. Radionuclides in the atmosphere are therefore carried mainly by wind-blown dust from surface soil, that is, aeolian dust. Asian dust carries traces of 90Sr, 137Cs, and other anthropogenic radionuclides; the heaviest deposition occurs in spring and has been recorded in Japan since the early 1990s. The composition of anthropogenic radionuclides in atmospheric depositions would be affected by a change in the dust source. Previous studies of atmospheric deposition at long-term monitoring sites (e.g. in Tsukuba, Japan have detected changes in the 137Cs/90Sr ratio and in the specific activity of the radionuclides. These changes in the composition of observed atmospheric depositions are supposed to reflect changes in the climatic conditions of the dust source region. To investigate this dust source change, we conducted a field survey of radionuclides (90Sr and 137Cs in surface soil samples in September 2007 in the eastern and southern regions of Mongolia, where dust storms have occurred more frequently since 2000. The specific activities of both radionuclides as well as the 137Cs/90Sr ratio in the surface soil were well correlated with annual average precipitation in the Mongolian desert-steppe zone. Higher specific activities and a higher 137Cs/90Sr ratio were found in grassland regions that experienced greater

  10. Transient thermal stresses due to a zonal heat source moving back and forth over the surface on an infinite plate

    International Nuclear Information System (INIS)

    Sumi, N.; Hetnarski, R.B.

    1989-01-01

    A solution is given for the transient thermal stresses due to a zonal heat source moving back and forth with a constant angular frequency over the surface of an infinite elastic plate. The transient temperature distribution is obtained by using the complex Fourier and Laplace transforms, and the associated thermal stresses are obtained by means of the thermoelastic displacement potential and the Galerkin function. Graphical representations for the solution in dimensionless terms are included in this paper. (orig.)

  11. Linking potential heat source and sink to urban heat island: Heterogeneous effects of landscape pattern on land surface temperature.

    Science.gov (United States)

    Li, Weifeng; Cao, Qiwen; Lang, Kun; Wu, Jiansheng

    2017-05-15

    Rapid urbanization has significantly contributed to the development of urban heat island (UHI). Regulating landscape composition and configuration would help mitigate the UHI in megacities. Taking Shenzhen, China, as a case study area, we defined heat source and heat sink and identified strong and weak sources as well as strong and weak sinks according to the natural and socioeconomic factors influencing land surface temperature (LST). Thus, the potential thermal contributions of heat source and heat sink patches were differentiated. Then, the heterogeneous effects of landscape pattern on LST were examined by using semiparametric geographically weighted regression (SGWR) models. The results showed that landscape composition has more significant effects on thermal environment than configuration. For a strong source, the percentage of patches has a positive impact on LST. Additionally, when mosaicked with some heat sink, even a small improvement in the degree of dispersion of a strong source helps to alleviate UHI. For a weak source, the percentage and density of patches have positive impacts on LST. For a strong sink, the percentage, density, and degree of aggregation of patches have negative impacts on LST. The effects of edge density and patch shape complexity vary spatially with the fragmentation of a strong sink. Similarly, the impacts of a weak sink are mainly exerted via the characteristics of percent, density, and shape complexity of patches. Copyright © 2017 Elsevier B.V. All rights reserved.

  12. Signal information available for plume source tracking with and without surface waves and learning by undergraduates assisting with the research

    Science.gov (United States)

    Wiley, Megan Beth

    Autonomous vehicles have had limited success in locating point sources of pollutants, chemicals, and other passive scalars. However, animals such as stomatopods, a mantis shrimp, track odor plumes easily for food, mates, and habitat. Laboratory experiments using Planar Laser Induced Fluorescence measured odor concentration downstream of a diffusive source with and without live stomatopods to investigate their source-tracking strategies in unidirectional and "wave-affected" (surface waves with a mean current) flows. Despite the dearth of signal, extreme temporal variation, and meandering plume centerline, the stomatopods were able to locate the source, especially in the wave-affected flow. Differences in the two plumes far from the source (>160 cm) appeared to help the animals in the wave-affected flow position themselves closer to the source (fluid mechanics, and there was little evidence of learning by participation in the RAship. One RA's conceptions of turbulence did change, but a group workshop seemed to support this learning more than the RAship. The documented conceptions could aid in curriculum design, since situating new information within current knowledge seems to deepen learning outcomes. The RAs' conceptions varied widely with some overlap of ideas. The interviews also showed that most RAs did not discuss molecular diffusion as part of the mixing process and some remembered information from course demonstrations, but applied them inappropriately to the interview questions.

  13. Spatial distribution and source identification of heavy metals in surface soils in a typical coal mine city, Lianyuan, China.

    Science.gov (United States)

    Liang, Jie; Feng, Chunting; Zeng, Guangming; Gao, Xiang; Zhong, Minzhou; Li, Xiaodong; Li, Xin; He, Xinyue; Fang, Yilong

    2017-06-01

    In this study, we investigated the pollution degree and spatial distribution of heavy metals and determined their sources in topsoil in a typical coal mine city, Lianyuan, Hunan Province, China. We collected 6078 soil surface samples in different land use types. And the concentrations of Zn, Cd, Cu, Hg, Pb, Sb, As, Mo, V, Mn, Fe and Cr were measured. The average contents of all heavy metals were lower than their corresponding Grade II values of Chinese Soil Quality Standard with the exception of Hg. However, average contents of twelve heavy metals, except for Mn, exceeded their background level in soils in Hunan Province. Based on one-way analysis of variance (ANOVA), the contents of Cu, Zn, Cd, Pb, Hg, Mo and V were related to the anthropogenic source and there were statistically significant differences in their concentrations among different land use patterns. The spatial variation of heavy metal was visualized by GIS. The PMF model was used to ascertain contamination sources of twelve heavy metals and apportion their source contributions in Lianyuan soils. The results showed that the source contributions of the natural source, atmospheric deposition, industrial activities and agricultural activities accounted for 33.6%, 26.05%, 23.44% and 16.91%, respectively. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. Conversion electrons in the SDC

    International Nuclear Information System (INIS)

    Wicklund, A.B.

    1991-01-01

    We summarize a preliminary analysis of the rates for conversion electrons in the SDC detector, relative to other interesting sources of prompt electrons. We have used Papageno V3.30, and other available NLO calculations to estimate inclusive rates in the central region (η less than 2.0), and we have cross checked these using CDF data at 1.8 TeV. We have considered three sources of ''isolated'' electrons, namely inclusive W/Z production; top quark (Mt=140); and QCD prompt photon production, followed by conversion in 10% XO. This value approximates the inner silicon detector at SDC. Additional conversions will occur in the outer tracking chamber, but the trigger and track reconstruction efficiency will be lower. We have also considered ''nonisolated'' leptons coming from inclusive bottom production, photon conversions resulting from π 0 ,η production in jets, and high pt hadrons faking electrons

  15. Surface characterization of III-V MOCVD films from heterocyclic single-source precursors; Oberflaechencharakterisierung von III-V MOCVD-Filmen aus heterozyklischen Single Source Precursoren

    Energy Technology Data Exchange (ETDEWEB)

    Seemayer, Andreas

    2009-07-13

    In the present thesis the sublimation and evaporation properties of heterocyclic gallium and antimony containing single-source precursors as well as the chemical composition and morphology of the films fabricated from this were studied. The single-source precursors available by a new synthesis route were characterized concerning their evaporation properties and the obtained films studied surface-physically. By this way the process parameters were optimized and the applicability of the single-source precursors in HV-MOCVD processes studied. By evaporation experiments in the UHV it could be shown that thereby lighter ligands like ethyl- and methyl-groups lead to a lower contamination of the reaction space with carbon containing molecules. Furthermore it was expected that the 6-rings synthetized with short ligands exhibit a high stability. This however could not be confirmed. By unwanted parasitary reactions in the gaseous phase respectively dissociative sublimation in the gaseous phase a deposition of GaSb with these precursors was not possible. The 4-ring stabilized with tertiary-butyl and ethyl-groups caused in the evaporation the largest contamination of the gaseous phase, becauselonger-chain hydrocarbons exhibil only a bad pump cross section. By parasitary reactions originating elementary antimony is detectable in the gaseous phase. The films were studied concerning their chemical composition and their transport- respectively storage-conditioned surface contamination. Furthermore it has become clear that not only a purely synthetized precursor substance but also the reactor design is deciding for a successful deposition and a high film quality. First by successive optimization of the evaporation geometry it was possible to reduce the roughness of the produced GaSb films down to about 10 nm-30 nm.

  16. Occurrence and sources of aliphatic hydrocarbons in surface soils from Riyadh city, Saudi Arabia

    Directory of Open Access Journals (Sweden)

    Ahmed I. Rushdi

    2013-01-01

    Full Text Available Soil particles contain a variety of anthropogenic and natural organic components derived from many sources such as industrial and traffic fossil fuel emissions and terrestrial biota. The organic contents of soil and sand from the Arabian region have not fully characterized. Thus, samples of fine soil particles (sieved to <125 μM were collected from the Riyadh area in November 2006 (late summer and February 2007 (late winter. The samples were extracted with a mixture of dichloromethane/hexane and analyzed by gas chromatography–mass spectroscopy (GCMS in order to characterize the chemical composition and sources of aliphatic hydrocarbons. The results showed that both anthropogenic and natural biogenic inputs were the major sources of the aliphatic hydrocarbons in these extracts. Vehicular emission products and discarded plastics were the major anthropogenic sources in the fine particles of the soils and ranged from 64% to 96% in November 2006 and from 70% to 92% in February 2007. Their tracers were n-alkanes, hopanes, sterane, plasticizers and UCM. Vegetation was also a major natural source of hydrocarbon compounds in samples ranging from ∼0% to18% in November 2006 and from 1% to 13% in February 2007 and included n-alkanes and triterpenoids.

  17. FreeSASA: An open source C library for solvent accessible surface area calculations [version 1; referees: 2 approved

    Directory of Open Access Journals (Sweden)

    Simon Mitternacht

    2016-02-01

    Full Text Available Calculating solvent accessible surface areas (SASA is a run-of-the-mill calculation in structural biology. Although there are many programs available for this calculation, there are no free-standing, open-source tools designed for easy tool-chain integration. FreeSASA is an open source C library for SASA calculations that provides both command-line and Python interfaces in addition to its C API. The library implements both Lee and Richards’ and Shrake and Rupley’s approximations, and is highly configurable to allow the user to control molecular parameters, accuracy and output granularity. It only depends on standard C libraries and should therefore be easy to compile and install on any platform. The library is well-documented, stable and efficient. The command-line interface can easily replace closed source legacy programs, with comparable or better accuracy and speed, and with some added functionality.

  18. Distribution, Source, and Ecological Risk Assessment of Polycyclic Aromatic Hydrocarbons in Surface Sediment of Liaodong Bay, Northeast China

    Science.gov (United States)

    Xu, Shuang; Tao, Ping; Li, Yuxia; Guo, Qi; Zhang, Yan; Wang, Man; Jia, Hongliang; Shao, Mihua

    2018-01-01

    Sixteen polycyclic aromatic hydrocarbons (PAHs) were determined in surface sediments from Liaodong Bay, northeast China. The concentration levels of total PAHs (Σ16PAHs) in sediment were 11.0˜249.6 ng·g-1 dry weight (dw), with a mean value of 89.9 ng·g-1 dry weight (dw). From the point of the spatial distribution, high PAHs levels were found in the western areas of Liaodong Bay. In the paper, sources of PAHs were investigated by diagnostic ratios, which indicated that pyrogenic sources were the main sources of PAHs in the sediment of Liaodong Bay. Therefore, selected PAH levels in sediments were compared with Sediments Quality Guidelines (ERM-ERL indexes) for evaluation probable toxic effects on marine organism.

  19. Surface wastewater in Samara and their impact on water basins as water supply sources

    Science.gov (United States)

    Strelkov, Alexander; Shuvalov, Mikhail; Gridneva, Marina

    2017-10-01

    The paper gives an overview of surface wastewater outlets in Samara through the rainwater sewer system into the Saratov water reservoir and the Samara river. The rainwater sewer system in Samara is designed and executed according to a separate scheme, except for the old part of the city, where surface run-off is dumped into the sewer system through siphoned drain. The rainwater system disposes of surface, drainage, industrial clean-contamined waters, emergency and technology discharges from the city’s heat supply and water supply systems. The effluent discharge is carried out by means of separate wastewater outlets into ravines or directly into the Samara river and the Saratov water reservoir without cleaning. The effluent discharge is carried out through the rainwater sewer system with 17 wastewater outlets into the Saratov water reservoir. In the Samara river, surface runoff drainage and clean-contamined water of industrial enterprises is carried out through 14 wastewater outlets. This study emphasizes the demand to arrange effluent discharge and construction of sewage treatment plants to prevent contamination of water objects by surface run-off from residential areas and industrial territories.

  20. SEI power source alternatives for rovers and other multi-kWe distributed surface applications

    Science.gov (United States)

    Bents, David J.; Kohout, L. L.; Mckissock, Barbara I.; Rodriguez, C. D.; Withrow, C. A.; Colozza, A.; Hanlon, James C.; Schmitz, Paul C.

    1991-01-01

    To support the Space Exploration Initiative (SEI), a study was performed to investigate power system alternatives for the rover vehicles and servicers that were subsequently generated for each of these rovers and servicers, candidate power sources incorporating various power generation and energy storage technologies were identified. The technologies were those believed most appropriate to the SEI missions, and included solar, electrochemical, and isotope systems. The candidates were characterized with respect to system mass, deployed area, and volume. For each of the missions a preliminary selection was made. Results of this study depict the available power sources in light of mission requirements as they are currently defined.

  1. Desorption of surface positrons: A source of free positronium at thermal velocities

    International Nuclear Information System (INIS)

    Mills, A.P. Jr.; Pfeiffer, L.

    1979-01-01

    A direct measurement is reported of the velocity of positronium (Ps) ejected into a vacuum when 0- to 100-eV positrons (e + ) strike a negatively biased Cu(111) surface. At 30 0 C, about half the e + form Ps with normal energy component E-bar=3.4(3) eV. At 790 0 C, most of the remaining e + form Ps but with E-bar=0.14(1) eV, and a non-Maxwellian thermal distribution. We infer that surface-bound e + are thermally desorbed to form the extra Ps. These low Ps velocities suggest exciting possibilities for experiments on free Ps

  2. Computer code conversion using HISTORIAN

    International Nuclear Information System (INIS)

    Matsumoto, Kiyoshi; Kumakura, Toshimasa.

    1990-09-01

    When a computer program written for a computer A is converted for a computer B, in general, the A version source program is rewritten for B version. However, in this way of program conversion, the following inconvenient problems arise. 1) The original statements to be rewritten for B version are lost. 2) If the original statements of the A version rewritten for B version would remain as comment lines, the B version source program becomes quite large. 3) When update directives of the program are mailed from the organization which developed the program or when some modifications are needed for the program, it is difficult to point out the part to be updated or modified in the B version source program. To solve these problems, the conversion method using the general-purpose software management aid system, HISTORIAN, has been introduced. This conversion method makes a large computer code a easy-to-use program for use to update, modify or improve after the conversion. This report describes the planning and procedures of the conversion method and the MELPROG-PWR/MOD1 code conversion from the CRAY version to the JAERI FACOM version as an example. This report would provide useful information for those who develop or introduce large programs. (author)

  3. SURFACE AND LIGHTNING SOURCES OF NITROGEN OXIDES OVER THE UNITED STATES: MAGNITUDES, CHEMICAL EVOLUTION, AND OUTFLOW

    Science.gov (United States)

    We use observations from two aircraft during the ICARTT campaign over the eastern United States and North Atlantic during summer 2004, interpreted with a global 3-D model of tropospheric chemistry (GEOS-Chem) to test current understanding of regional sources, chemical evolution...

  4. Sensitivity of the near-surface vertical electric field land Controlled-Source Electromagnetic monitoring

    NARCIS (Netherlands)

    Schaller, A.M.; Hunziker, J.W.; Streich, R.; Drijkoningen, G.G.

    2014-01-01

    We investigate potential benefits of measuring the vertical electric field component in addition to the routinely measured horizontal electric field components in onshore time-lapse controlled-source electromagnetics. Synthetic electromagnetic data based on a model of the Schoonebeek onshore oil

  5. A comparison of two open source LiDAR surface classification algorithms

    Science.gov (United States)

    With the progression of LiDAR (Light Detection and Ranging) towards a mainstream resource management tool, it has become necessary to understand how best to process and analyze the data. While most ground surface identification algorithms remain proprietary and have high purchase costs; a few are op...

  6. A comparison of two open source LiDAR surface classification algorithms

    Science.gov (United States)

    Wade T. Tinkham; Hongyu Huang; Alistair M.S. Smith; Rupesh Shrestha; Michael J. Falkowski; Andrew T. Hudak; Timothy E. Link; Nancy F. Glenn; Danny G. Marks

    2011-01-01

    With the progression of LiDAR (Light Detection and Ranging) towards a mainstream resource management tool, it has become necessary to understand how best to process and analyze the data. While most ground surface identification algorithms remain proprietary and have high purchase costs; a few are openly available, free to use, and are supported by published results....

  7. Comparison of fipronil sources in North Carolina surface water and identification of a novel fipronil transformation product in recycled wastewater

    International Nuclear Information System (INIS)

    McMahen, Rebecca L.; Strynar, Mark J.; McMillan, Larry; DeRose, Eugene; Lindstrom, Andrew B.

    2016-01-01

    Fipronil is a phenylpyrazole insecticide that is widely used in residential and agricultural settings to control ants, roaches, termites, and other pests. Fipronil and its transformation products have been found in a variety of environmental matrices, but the source[s] which makes the greatest contribution to fipronil in surface water has yet to be determined. A sampling effort designed to prioritize known fipronil inputs (golf courses, residential areas, biosolids application sites and wastewater facilities) was conducted in North Carolina to learn more about the origins of fipronil in surface water. High resolution mass spectrometry (HRMS) analysis indicated that fipronil and its known derivatives were routinely present in all samples, but concentrations were substantially elevated near wastewater treatment plant outfalls (range 10–500 ng/L combined), suggesting that they predominate as environmental sources. Corresponding recycled wastewater samples, which were treated with NaOCl for disinfection, showed disappearance of fipronil and all known degradates. HRMS and nuclear magnetic resonance (NMR) analysis techniques were used to determine that all fipronil-related compounds are oxidized to a previously unidentified fipronil sulfone chloramine species in recycled wastewater. The implications of the presence of a new fipronil-related compound in recycled wastewater need to be considered. - Highlights: • The most important sources of fipronil in the environment have yet to be determined. • Sampling was conducted to learn more about the origins of fipronil in surface water. • High resolution mass spec analysis indicated that fipronil was routinely present. • Concentrations were substantially elevated near wastewater treatment plant outfalls. • In recycled water fipronil compounds are oxidized to a novel species.

  8. Comparison of fipronil sources in North Carolina surface water and identification of a novel fipronil transformation product in recycled wastewater

    Energy Technology Data Exchange (ETDEWEB)

    McMahen, Rebecca L. [United States Environmental Protection Agency, National Exposure Research Laboratory, 109 TW Alexander Dr., Durham, North Carolina 27705 (United States); Strynar, Mark J., E-mail: strynar.mark@epa.gov [United States Environmental Protection Agency, National Exposure Research Laboratory, 109 TW Alexander Dr., Durham, North Carolina 27705 (United States); McMillan, Larry [National Caucus and Center on Black Aged Employee, U.S. Environmental Protection Agency, National Exposure Research Laboratory, 109 TW Alexander Dr., Durham, North Carolina 27705 (United States); DeRose, Eugene [National Institute for Environmental Health Sciences, Nuclear Magnetic Resonance Facility, 111 TW Alexander Dr., Durham, North Carolina 27713 (United States); Lindstrom, Andrew B. [United States Environmental Protection Agency, National Exposure Research Laboratory, 109 TW Alexander Dr., Durham, North Carolina 27705 (United States)

    2016-11-01

    Fipronil is a phenylpyrazole insecticide that is widely used in residential and agricultural settings to control ants, roaches, termites, and other pests. Fipronil and its transformation products have been found in a variety of environmental matrices, but the source[s] which makes the greatest contribution to fipronil in surface water has yet to be determined. A sampling effort designed to prioritize known fipronil inputs (golf courses, residential areas, biosolids application sites and wastewater facilities) was conducted in North Carolina to learn more about the origins of fipronil in surface water. High resolution mass spectrometry (HRMS) analysis indicated that fipronil and its known derivatives were routinely present in all samples, but concentrations were substantially elevated near wastewater treatment plant outfalls (range 10–500 ng/L combined), suggesting that they predominate as environmental sources. Corresponding recycled wastewater samples, which were treated with NaOCl for disinfection, showed disappearance of fipronil and all known degradates. HRMS and nuclear magnetic resonance (NMR) analysis techniques were used to determine that all fipronil-related compounds are oxidized to a previously unidentified fipronil sulfone chloramine species in recycled wastewater. The implications of the presence of a new fipronil-related compound in recycled wastewater need to be considered. - Highlights: • The most important sources of fipronil in the environment have yet to be determined. • Sampling was conducted to learn more about the origins of fipronil in surface water. • High resolution mass spec analysis indicated that fipronil was routinely present. • Concentrations were substantially elevated near wastewater treatment plant outfalls. • In recycled water fipronil compounds are oxidized to a novel species.

  9. Environmental monitoring handbook for coal conversion facilities

    Energy Technology Data Exchange (ETDEWEB)

    Salk, M.S.; DeCicco, S.G. (eds.)

    1978-05-01

    The primary objectives of the Department of Energy's (DOE) coal conversion program are to demonstrate the environmental acceptability, technical feasibility, and economic viability of various technologies for gaseous, liquid, and solid fuels from coal. The Environmental Monitoring Handbook for Coal Conversion Facilities will help accomplish the objective of environmental acceptability by guiding the planning and execution of socioeconomic and environmental monitoring programs for demonstration facilities. These programs will provide information adequate to (1) predict, insofar as is possible, the potential impacts of construction and operation of a coal conversion plant, (2) verify the occurrence of these or any other impacts during construction and operation, (3) determine the adequacy of mitigating measures to protect the environment, (4) develop effluent source terms for process discharges, and (5) determine the effectiveness of pollution control equipment. Although useful in a variety of areas, the handbook is intended primarily for contractors who, as industrial partners with DOE, are building coal conversion plants. For the contractor it is a practical guide on (1) the methodology for developing site- and process-specific environmental monitoring programs, (2) state-of-the-art sampling and analytical techniques, and (3) impact analyses.To correspond to the phases of project activity, the subject matter is divided into four stages of monitoring: (1) a reconnaissance or synoptic survey, (2) preconstruction or baseline, (3) construction, and (4) operation, including process monitoring (prepared by Radian Corp., McLean, Va.). For each stage of monitoring, guidelines are given on socioeconomics, aquatic and terrestrial ecology, air quality and meteorology, surface and groundwater quality, geohydrology and soil survey, and surface water hydrology.

  10. Application of Taguchi Design and Response Surface Methodology for Improving Conversion of Isoeugenol into Vanillin by Resting Cells of Psychrobacter sp. CSW4

    OpenAIRE

    Ashengroph, Morahem; Nahvi, Iraj; Amini, Jahanshir

    2013-01-01

    For all industrial processes, modelling, optimisation and control are the keys to enhance productivity and ensure product quality. In the current study, the optimization of process parameters for improving the conversion of isoeugenol to vanillin by Psychrobacter sp. CSW4 was investigated by means of Taguchi approach and Box-Behnken statistical design under resting cell conditions. Taguchi design was employed for screening the significant variables in the bioconversion medium. Sequentially, B...

  11. Methods for evaluating potential sources of chloride in surface waters and groundwaters of the conterminous United States

    Science.gov (United States)

    Granato, Gregory E.; DeSimone, Leslie A.; Barbaro, Jeffrey R.; Jeznach, Lillian C.

    2015-09-04

    Chloride exists as a major ion in most natural waters, but many anthropogenic sources are increasing concentrations of chloride in many receiving waters. Although natural concentrations in continental waters can be as high as 200,000 milligrams per liter, chloride concentrations that are suitable for freshwater ecology, human consumption, and agricultural and industrial water uses commonly are on the order of 10 to 1,000 milligrams per liter. “Road salt” frequently is identified as the sole source of anthropogenic chloride, but only about 30 percent of the salt consumed and released to the environment is used for deicing. Furthermore, several studies in Southern States where the use of deicing salt is minimal also show anthropogenic chloride in rising concentrations and in strong correlation to imperviousness and road density. This is because imperviousness and road density also are strongly correlated to population density. The term “road salt” is a misnomer because deicers applied to parking lots, sidewalks, and driveways can be a substantial source of chloride in some catchments because these land covers are comparable to roadways as a percentage of the total impervious area and commonly receive higher salt application rates than some roadways. Other sources of anthropogenic chloride include wastewater, dust control on unpaved roads, fertilizer, animal waste, irrigation, aquaculture, energy production wastes, and landfill leachates. The assumption that rising chloride concentrations in surface water or groundwater is indicative of contamination by deicing chemicals rather than one or more other potential sources may preclude the identification of toxic, carcinogenic, mutagenic, or endocrine-disrupting contaminants that are associated with many sources of elevated chloride concentrations. Once the sources of anthropogenic chloride in an area of interest have been identified and measured, water and solute budgets can be estimated to guide decisionmakers to

  12. Efficient and tunable high-order harmonic light sources for photoelectron spectroscopy at surfaces

    International Nuclear Information System (INIS)

    Chiang, Cheng-Tien; Huth, Michael; Trützschler, Andreas; Schumann, Frank O.; Kirschner, Jürgen; Widdra, Wolf

    2015-01-01

    Highlights: • An overview of photoelectron spectroscopy using high-order harmonics is presented. • Photoemission spectra on Ag(0 0 1) using megahertz harmonics are shown. • A gas recycling system for harmonic generation is presented. • Non-stop operation of megahertz harmonics up to 76 h is demonstrated. • The bandwidth and pulse duration of the harmonics are discussed. - Abstract: With the recent progress in high-order harmonic generation (HHG) using femtosecond lasers, laboratory photoelectron spectroscopy with an ultrafast, widely tunable vacuum-ultraviolet light source has become available. Despite the well-established technique of HHG-based photoemission experiments at kilohertz repetition rates, the efficiency of these setups can be intrinsically limited by the space-charge effects. Here we present recent developments of compact HHG light sources for photoelectron spectroscopy at high repetition rates up to megahertz, and examples for angle-resolved photoemission experiments are demonstrated.

  13. Impact Metamorphism of Subsurface Organic Matter on Mars: A Potential Source for Methane and Surface Alteration

    Science.gov (United States)

    Oehler, D. Z.; Allen, C. C.; McKay, D. S.

    2005-01-01

    Reports of methane in the Martian atmosphere have spurred speculation about sources for that methane [1-3]. Discussion has centered on cometary/ meteoritic delivery, magmatic/mantle processes, UV-breakdown of organics, serpentinization of basalts, and generation of methane by living organisms. This paper describes an additional possibility: that buried organic remains from past life on Mars may have been generating methane throughout Martian history as a result of heating associated with impact metamorphism.

  14. Sources of groundwater and characteristics of surface-water recharge at Bell, White, and Suwannee Springs, Florida, 2012–13

    Science.gov (United States)

    Stamm, John F.; McBride, W. Scott

    2016-12-21

    Discharge from springs in Florida is sourced from aquifers, such as the Upper Floridan aquifer, which is overlain by an upper confining unit that locally can have properties of an aquifer. Water levels in aquifers are affected by several factors, such as precipitation, recharge, and groundwater withdrawals, which in turn can affect discharge from springs. Therefore, identifying groundwater sources and recharge characteristics can be important in assessing how these factors might affect flows and water levels in springs and can be informative in broader applications such as groundwater modeling. Recharge characteristics include the residence time of water at the surface, apparent age of recharge, and recharge water temperature.The groundwater sources and recharge characteristics of three springs that discharge from the banks of the Suwannee River in northern Florida were assessed for this study: Bell Springs, White Springs, and Suwannee Springs. Sources of groundwater were also assessed for a 150-foot-deep well finished within the Upper Floridan aquifer, hereafter referred to as the UFA well. Water samples were collected for geochemical analyses in November 2012 and October 2013 from the three springs and the UFA well. Samples were analyzed for a suite of major ions, dissolved gases, and isotopes of sulfur, strontium, oxygen, and hydrogen. Daily means of water level and specific conductance at White Springs were continuously recorded from October 2012 through December 2013 by the Suwannee River Water Management District. Suwannee River stage at White Springs was computed on the basis of stage at a U.S. Geological Survey streamgage about 2.4 miles upstream. Water levels in two wells, located about 2.5 miles northwest and 13 miles southeast of White Springs, were also used in the analyses.Major ion concentrations were used to differentiate water from the springs and Upper Floridan aquifer into three groups: Bell Springs, UFA well, and White and Suwannee Springs. When

  15. AdS5 solutions from M5-branes on Riemann surface and D6-branes sources

    Energy Technology Data Exchange (ETDEWEB)

    Bah, Ibrahima [Department of Physics and Astronomy, University of Southern California,Los Angeles, CA 90089 (United States); Institut de Physique Théorique, CEA/Saclay,91191 Gif-sur-Yvette (France)

    2015-09-24

    We describe the gravity duals of four-dimensional N=1 superconformal field theories obtained by wrapping M5-branes on a punctured Riemann surface. The internal geometry, normal to the AdS{sub 5} factor, generically preserves two U(1)s, with generators (J{sup +},J{sup −}), that are fibered over the Riemann surface. The metric is governed by a single potential that satisfies a version of the Monge-Ampère equation. The spectrum of N=1 punctures is given by the set of supersymmetric sources of the potential that are localized on the Riemann surface and lead to regular metrics near a puncture. We use this system to study a class of punctures where the geometry near the sources corresponds to M-theory description of D6-branes. These carry a natural (p,q) label associated to the circle dual to the killing vector pJ{sup +}+qJ{sup −} which shrinks near the source. In the generic case the world volume of the D6-branes is AdS{sub 5}×S{sup 2} and they locally preserve N=2 supersymmetry. When p=−q, the shrinking circle is dual to a flavor U(1). The metric in this case is non-degenerate only when there are co-dimension one sources obtained by smearing M5-branes that wrap the AdS{sub 5} factor and the circle dual the superconformal R-symmetry. The D6-branes are extended along the AdS{sub 5} and on cups that end on the co-dimension one branes. In the special case when the shrinking circle is dual to the R-symmetry, the D6-branes are extended along the AdS{sub 5} and wrap an auxiliary Riemann surface with an arbitrary genus. When the Riemann surface is compact with constant curvature, the system is governed by a Monge-Ampère equation.

  16. Developing Coastal Surface Roughness Maps Using ASTER and QuickBird Data Sources

    Science.gov (United States)

    Spruce, Joe; Berglund, Judith; Davis, Bruce

    2006-01-01

    This viewgraph presentation regards one element of a larger project on the integration of NASA science models and data into the Hazards U.S. Multi-Hazard (HAZUS-MH) Hurricane module for hurricane damage and loss risk assessment. HAZUS-MH is a decision support tool being developed by the National Institute of Building Sciences for the Federal Emergency Management Agency (FEMA). It includes the Hurricane Module, which employs surface roughness maps made from National Land Cover Data (NLCD) maps to estimate coastal hurricane wind damage and loss. NLCD maps are produced and distributed by the U.S. Geological Survey. This presentation discusses an effort to improve upon current HAZUS surface roughness maps by employing ASTER multispectral classifications with QuickBird "ground reference" imagery.

  17. Survey of Techniques for Deep Web Source Selection and Surfacing the Hidden Web Content

    OpenAIRE

    Khushboo Khurana; M.B. Chandak

    2016-01-01

    Large and continuously growing dynamic web content has created new opportunities for large-scale data analysis in the recent years. There is huge amount of information that the traditional web crawlers cannot access, since they use link analysis technique by which only the surface web can be accessed. Traditional search engine crawlers require the web pages to be linked to other pages via hyperlinks causing large amount of web data to be hidden from the crawlers. Enormous data is available in...

  18. Snow cover as a source of technogenic pollution of surface water during the snow melting period

    OpenAIRE

    Labuzova Olga; Noskova Tatyana; Lysenko Maria; Ovcharenko Elena; Papina Tatyana

    2016-01-01

    The study of pollutants in melt water of snow cover and snow disposal sites in the city of Barnaul showed that during the snow melting period the surface water is not subjected to significant technogenic impact according to a number of studied indices. The oils content is an exception: it can exceed MAC more than 20 times in river- water due to the melting of city disposal sites. Environmental damage due to an oils input into water resources during the snow melting period...

  19. Heavy metal contamination of surface soil in electronic waste dismantling area: site investigation and source-apportionment analysis.

    Science.gov (United States)

    Jinhui Li; Huabo Duan; Pixing Shi

    2011-07-01

    The dismantling and disposal of electronic waste (e-waste) in developing countries is causing increasing concern because of its impacts on the environment and risks to human health. Heavy-metal concentrations in the surface soils of Guiyu (Guangdong Province, China) were monitored to determine the status of heavy-metal contamination on e-waste dismantling area with a more than 20 years history. Two metalloids and nine metals were selected for investigation. This paper also attempts to compare the data among a variety of e-waste dismantling areas, after reviewing a number of heavy-metal contamination-related studies in such areas in China over the past decade. In addition, source apportionment of heavy metal in the surface soil of these areas has been analysed. Both the MSW open-burning sites probably contained invaluable e-waste and abandoned sites formerly involved in informal recycling activities are the new sources of soil-based environmental pollution in Guiyu. Although printed circuit board waste is thought to be the main source of heavy-metal emissions during e-waste processing, requirement is necessary to soundly manage the plastic separated from e-waste, which mostly contains heavy metals and other toxic substances.

  20. Two-step design method for highly compact three-dimensional freeform optical system for LED surface light source.

    Science.gov (United States)

    Mao, Xianglong; Li, Hongtao; Han, Yanjun; Luo, Yi

    2014-10-20

    Designing an illumination system for a surface light source with a strict compactness requirement is quite challenging, especially for the general three-dimensional (3D) case. In accordance with the two key features of an expected illumination distribution, i.e., a well-controlled boundary and a precise illumination pattern, a two-step design method is proposed in this paper for highly compact 3D freeform illumination systems. In the first step, a target shape scaling strategy is combined with an iterative feedback modification algorithm to generate an optimized freeform optical system with a well-controlled boundary of the target distribution. In the second step, a set of selected radii of the system obtained in the first step are optimized to further improve the illuminating quality within the target region. The method is quite flexible and effective to design highly compact optical systems with almost no restriction on the shape of the desired target field. As examples, three highly compact freeform lenses with ratio of center height h of the lens and the maximum dimension D of the source ≤ 2.5:1 are designed for LED surface light sources to form a uniform illumination distribution on a rectangular, a cross-shaped and a complex cross pierced target plane respectively. High light control efficiency of η > 0.7 as well as low relative standard illumination deviation of RSD < 0.07 is obtained simultaneously for all the three design examples.

  1. A lifting-surface theory solution for the diffraction of internal sound sources by an engine nacelle

    Science.gov (United States)

    Martinez, R.

    1986-07-01

    Lifting-surface theory is used to solve the problem of diffraction by a rigid open-ended pipe of zero thickness and finite length, with application to the prediction of acoustic insertion-loss performance for the encasing structure of a ducted propeller or turbofan. An axisymmetric situation is assumed, and the incident field due to a force applied directly to the fluid in the cylinder axial direction is used. A virtual-source distribution of unsteady dipoles is found whose integrated component of radial velocity is set to cancel that of the incident field over the surface. The calculated virtual load is verified by whether its effect on the near-field input power at the actual source is consistent with the far-field power radiated by the system, a balance which is possible if the no-flow-through boundary condition has been satisfied over the rigid pipe surface such that the velocity component of the acoustic intensity is zero.

  2. Differences in staining intensities affect reported occurrences and concentrations of Giardia spp. in surface drinking water sources.

    Science.gov (United States)

    Alderisio, K A; Villegas, L F; Ware, M W; McDonald, L A; Xiao, L; Villegas, E N

    2017-12-01

    USEPA Method 1623, or its equivalent, is currently used to monitor for protozoan contamination of surface drinking water sources worldwide. At least three approved staining kits used for detecting Cryptosporidium and Giardia are commercially available. This study focuses on understanding the differences among staining kits used for Method 1623. Merifluor and EasyStain labelling kits were used to monitor Cryptosporidium oocyst and Giardia cyst densities in New York City's raw surface water sources. In the year following a change to the approved staining kits for use with Method 1623, an anomaly was noted in the occurrence of Giardia cysts in New York City's raw surface water. Specifically, Merifluor-stained samples had higher Giardia cyst densities as compared with those stained with EasyStain. Side by side comparison revealed significantly lower fluorescence intensities of Giardia muris as compared with Giardia duodenalis cysts when labelled with EasyStain. This study showed very poor fluorescence intensity signals by EasyStain on G. muris cysts resulting in lower cyst counts, while Merifluor, with its broader Giardia cyst staining specificity, resulted in higher cyst counts, when using Methods 1623. These results suggest that detected Giardia cyst concentrations are dependent on the staining kits used, which can result in a more or less conservative estimation of occurrences and densities of zoonotic Giardia cysts by detecting a broader range of Giardia species/Assemblages. Published 2017. This article is a U.S. Government work and is in the public domain in the USA.

  3. The measurement of internal conversion electrons of selected nuclei: A physics undergraduate laboratory experience

    International Nuclear Information System (INIS)

    Nagy, P.; Duggan, J.L.; Desmarais, D.

    1992-01-01

    Thin sources are now commercially available for a wide variety of isotopes that have measurable internal conversion coefficients. The authors have used standard surface barrier detectors, NIM electronics, and a personal computer analyzer to measure conversion electrons from a few of these sources. Conversion electrons energy and intensity were measured for 113 Sn, 133 Ba, 137 Cs, and 207 Bi. From the measured spectra the innershell binding energies of the K ampersand L Shell electrons from the daughter nuclei were determined and compared to theory. The relative conversion coefficients a k /a L and the K/L ration were also measured. The spin and parity change of the transitions will also be assigned based on the selection rules of the transitions

  4. A perspective on direct conversion

    Energy Technology Data Exchange (ETDEWEB)

    Lewis, W. B.

    1963-10-15

    As flowing energy, electricity is sought for its versatility. Its generation from some other flow or release of energy without mechanical power, or even sometimes heat, as intermediary is called direct conversion. The objective is high electrical output for minimum total cost and not always high conversion efficiency. The wide range of techniques embracing cryogenics and hot plasma derives from the special requirements of source, environment and application. Sources include solar and other radiation, nuclear fission and fusion, chemical energy and heat. Environments and applications range from space vehicles to submarines and from giant power networks to isolated buoys and pocket devices. (author)

  5. A perspective on direct conversion

    International Nuclear Information System (INIS)

    Lewis, W.B.

    1963-10-01

    As flowing energy, electricity is sought for its versatility. Its generation from some other flow or release of energy without mechanical power, or even sometimes heat, as intermediary is called direct conversion. The objective is high electrical output for minimum total cost and not always high conversion efficiency. The wide range of techniques embracing cryogenics and hot plasma derives from the special requirements of source, environment and application. Sources include solar and other radiation, nuclear fission and fusion, chemical energy and heat. Environments and applications range from space vehicles to submarines and from giant power networks to isolated buoys and pocket devices. (author)

  6. Radiation by Sources on Perfectly Conducting Convex Cylinders with an Impedance Surface Patch.

    Science.gov (United States)

    1980-01-01

    U -- = - (a to0 . 0 0 m 4- 0 4- 04 0-0 1 - .0 4’ U-- ~4- 4 0 n4- -- C_ to S~0- 4J C >1 cu S)-0’ (0 C 0)~ 00 =3 .r aCCA 50 It is observed from these...by such a source has only a z-component and it will be denoted by H . H satisfies the reduced, inhomo- geneous wave equation, and the f6 1llowing

  7. Variability of Surface pollutants and aerosol concentration over Abu Dhabi, UAE - sources, transport and current levels

    Science.gov (United States)

    Phanikumar, Devulapalli V.; Basha, Ghouse; Ouarda, Taha B. M. J.

    2015-04-01

    In the view of recent economic, industrial, and rapid development, Abu Dhabi (24.4oN; 54.4oE; 27m msl) has become one of the most populated regions in the world despite of extreme heat, frequent dust storms, and with distinctive topography. The major sources of air pollution are from the dust and sand storms, greenhouse gas emissions, and to some extent from industrial pollution. In order to realize the accurate and comprehensive understanding of air quality and plausible sources over this region, we have made a detailed analysis of three years simultaneous measurements during 2011-13 of pollutants such as O3, SO2, NO2, CO, and PM10 concentrations. Diurnal variation of meteorological parameters such as temperature and wind speed/relative humidity clearly shows daytime maximum/minimum in summer followed by pre-monsoon, post-monsoon and winter. The prevailing winds over this region are mostly from northwesterly direction (Shamal wind). Diurnal wind pattern showed a clear contrast with the majority of the wind pattern during nighttime and early morning is from the westerly/northwesterly and daytime is from southwesterly/southeasterly directions. The diurnal pattern of O3 shows minimum during 08 LT and increases thereafter reaching maximum at 17 LT and decreases during nighttime. However, the diurnal pattern of SO2 and NO2 show a peak at ~ 08 LT and dip at ~ 14 LT during all the seasons with some variability in each season. On the other hand, the diurnal pattern of CO shows a peculiar picture of elevated levels during daytime peaking at ~ 10 LT (prominent in summer and post-monsoon) followed by a sharp decrease and minimum is ~14 LT. PM10 concentration has an early morning peak at ~ 02 LT and then decreases to a minimum value at ~11 LT and again increases in the afternoon hours (maximum at ~17 LT) depicting a forenoon-afternoon asymmetry. Monthly variation of PM10 shows maximum in pre-monsoon season and minimum in winter. Our observations show the diurnal pattern of

  8. Response-surface models for deterministic effects of localized irradiation of the skin by discrete β/γ -emitting sources

    International Nuclear Information System (INIS)

    Scott, B.R.

    1995-01-01

    Individuals who work at nuclear reactor facilities can be at risk for deterministic effects in the skin from exposure to discrete Β- and γ-emitting (ΒγE) sources (e.g., ΒγE hot particles) on the skin or clothing. Deterministic effects are non-cancer effects that have a threshold and increase in severity as dose increases (e.g., ulcer in skin). Hot ΒγE particles are 60 Co- or nuclear fuel-derived particles with diameters > 10 μm and < 3 mm and contain at least 3.7 kBq (0.1 μCi) of radioactivity. For such ΒγE sources on the skin, it is the beta component of the dose that is most important. To develop exposure limitation systems that adequately control exposure of workers to discrete ΒγE sources, models are needed for systems that adequately control exposure of workers to discrete ΒγE sources, models are needed for evaluating the risk of deterministic effects of localized Β irradiation of the skin. The purpose of this study was to develop dose-rate and irradiated-area dependent, response-surface models for evaluating risks of significant deterministic effects of localized irradiation of the skin by discrete ΒγE sources and to use modeling results to recommend approaches to limiting occupational exposure to such sources. The significance of the research results as follows: (1) response-surface models are now available for evaluating the risk of specific deterministic effects of localized irradiation of the skin; (2) modeling results have been used to recommend approaches to limiting occupational exposure of workers to Β radiation from ΒγE sources on the skin or on clothing; and (3) the generic irradiated-volume, weighting-factor approach to limiting exposure can be applied to other organs including the eye, the ear, and organs of the respiratory or gastrointestinal tract and can be used for both deterministic and stochastic effects

  9. Response-surface models for deterministic effects of localized irradiation of the skin by discrete {beta}/{gamma} -emitting sources

    Energy Technology Data Exchange (ETDEWEB)

    Scott, B.R.

    1995-12-01

    Individuals who work at nuclear reactor facilities can be at risk for deterministic effects in the skin from exposure to discrete {Beta}- and {gamma}-emitting ({Beta}{gamma}E) sources (e.g., {Beta}{gamma}E hot particles) on the skin or clothing. Deterministic effects are non-cancer effects that have a threshold and increase in severity as dose increases (e.g., ulcer in skin). Hot {Beta}{gamma}E particles are {sup 60}Co- or nuclear fuel-derived particles with diameters > 10 {mu}m and < 3 mm and contain at least 3.7 kBq (0.1 {mu}Ci) of radioactivity. For such {Beta}{gamma}E sources on the skin, it is the beta component of the dose that is most important. To develop exposure limitation systems that adequately control exposure of workers to discrete {Beta}{gamma}E sources, models are needed for systems that adequately control exposure of workers to discrete {Beta}{gamma}E sources, models are needed for evaluating the risk of deterministic effects of localized {Beta} irradiation of the skin. The purpose of this study was to develop dose-rate and irradiated-area dependent, response-surface models for evaluating risks of significant deterministic effects of localized irradiation of the skin by discrete {Beta}{gamma}E sources and to use modeling results to recommend approaches to limiting occupational exposure to such sources. The significance of the research results as follows: (1) response-surface models are now available for evaluating the risk of specific deterministic effects of localized irradiation of the skin; (2) modeling results have been used to recommend approaches to limiting occupational exposure of workers to {Beta} radiation from {Beta}{gamma}E sources on the skin or on clothing; and (3) the generic irradiated-volume, weighting-factor approach to limiting exposure can be applied to other organs including the eye, the ear, and organs of the respiratory or gastrointestinal tract and can be used for both deterministic and stochastic effects.

  10. Sources of heavy metals in surface sediments and an ecological risk assessment from two adjacent Plateau reservoirs.

    Directory of Open Access Journals (Sweden)

    Binbin Wu

    Full Text Available The concentrations of heavy metals (mercury (Hg, cadmium (Cd, lead (Pb, chromium (Cr, copper (Cu and arsenic (As in surface water and sediments were investigated in two adjacent drinking water reservoirs (Hongfeng and Baihua Reservoirs on the Yunnan-Guizhou Plateau in Southwest China. Possible pollution sources were identified by spatial and statistical analyses. For both reservoirs, Cd was most likely from industrial activities, and As was from lithogenic sources. For the Hongfeng Reservoir, Pb, Cr and Cu might have originated from mixed sources (traffic pollution and residual effect of former industrial practices, and the sources of Hg included the inflows, which were different for the North (industrial activities and South (lithogenic origin Lakes, and atmospheric deposition resulting from coal combustion. For the Baihua Reservoir, the Hg, Cr and Cu were primarily derived from industrial activities, and the Pb originated from traffic pollution. The Hg in the Baihua Reservoir might also have been associated with coal combustion pollution. An analysis of ecological risk using sediment quality guidelines showed that there were moderate toxicological risks for sediment-dwelling organisms in both reservoirs, mainly from Hg and Cr. Ecological risk analysis using the Hakanson index suggested that there was a potential moderate to very high ecological risk to humans from fish in both reservoirs, mainly because of elevated levels of Hg and Cd. The upstream Hongfeng Reservoir acts as a buffer, but remains an important source of Cd, Cu and Pb and a moderately important source of Cr, for the downstream Baihua Reservoir. This study provides a replicable method for assessing aquatic ecosystem health in adjacent plateau reservoirs.

  11. Investigation of Seismic Waves from Non-Natural Sources: A Case Study for Building Collapse and Surface Explosion

    Science.gov (United States)

    Houng, S.; Hong, T.

    2013-12-01

    The nature and excitation mechanism of incidents or non-natural events have been widely investigated using seismological techniques. With introduction of dense seismic networks, small-sized non-natural events such as building collapse and chemical explosions are well recorded. Two representative non-natural seismic sources are investigated. A 5-story building in South Korea, Sampoong department store, was collapsed in June 25, 1995, causing casualty of 1445. This accident is known to be the second deadliest non-terror-related building collapse in the world. The event was well recorded by a local station in ~ 9 km away. P and S waves were recorded weak, while monotonic Rayleigh waves were observed well. The origin time is determined using surface-wave arrival time. The magnitude of event is determined to be 1.2, which coincides with a theoretical estimate based on the mass and volume of building. Synthetic waveforms are modeled for various combinations of velocity structures and source time functions, which allow us to constrain the process of building collapse. It appears that the building was collapsed once within a couple of seconds. We also investigate a M2.1 chemical explosion at a fertilizer plant in Texas on April 18, 2013. It was reported that more than one hundred people were dead or injured by the explosion. Seismic waveforms for nearby stations are collected from Incorporated Research Institution of Seismology (IRIS). The event was well recorded at stations in ~500 km away from the source. Strong acoustic signals were observed at stations in a certain great-circle direction. This observation suggests preferential propagation of acoustic waves depending on atmospheric environment. Waveform cross-correlation, spectral analysis and waveform modeling are applied to understand the source physics. We discuss the nature of source and source excitation mechanism.

  12. Distribution and sources of organic matter in surface sediments of the eastern continental margin of India

    Digital Repository Service at National Institute of Oceanography (India)

    Krishna, M.S.; Naidu, S.A.; Subbaiah, Ch.V.; Sarma, V.V.S.S.; Reddy, N.P.C.

    of the northern and western Gulf of Mexico, the north coast of Alaska and the Niger Delta [Gearing et al., 1977], surface sediments from the Beaufort shelf, Beaufort Sea [Goni et al., 2000], coastal sediments from the Gulf of Trieste, N Adriatic Sea [Ogrinc et... the chemical composition of SOC off the Washington margin [Keil et al. 1994; Prahl et al. 1994], Amazon [Goni, 1997], Bengal fans [Lanord and Derry, 1994], and Gulf of Mexico [Goni et al. 1997]. Other possible reason could be preferential removal of N...

  13. An optimal control problem by controlling heat source of the surface of tissue

    OpenAIRE

    Dhar, 1Rikhiya; Dhar, Ranajit; Dhar, Piyanka

    2013-01-01

    A distributed optimal control problem for a system described by bio-heat equation for a homogeneous plane tissue is analytically investigated such that a desired temperature of the tissue at a particular point of location of tumour in hyperthermia can be attained at the end of a total time of operation of the process due to induced microwave on the surface of the tissue which is taken as control. Here the temperature of the tissue along the length of the tissue at different times of operation...

  14. Snow cover as a source of technogenic pollution of surface water during the snow melting period

    Directory of Open Access Journals (Sweden)

    Labuzova Olga

    2016-10-01

    Full Text Available The study of pollutants in melt water of snow cover and snow disposal sites in the city of Barnaul showed that during the snow melting period the surface water is not subjected to significant technogenic impact according to a number of studied indices. The oils content is an exception: it can exceed MAC more than 20 times in river- water due to the melting of city disposal sites. Environmental damage due to an oils input into water resources during the snow melting period can be more than 300000 thousand rubles.

  15. [Sources, pollution statue and potential ecological risk of heavy metals in surface sediments of Aibi Lake, Northwest China].

    Science.gov (United States)

    Zhang, Zhao-Yong; Abuduwaili, Jilili; Jiang, Feng-Qing

    2015-02-01

    In this paper, the surface sediment samples were harvested from Aibi Lake, and total contents of 8 heavy metals ( Cu, Pb, Zn, As, Hg, Cr, Ni and Cd) were determined. Then the sources, pollution statue, and potential ecological risk were analyzed by using multiple analysis methods. The results show that: (1) The order of the skewness for these 8 heavy metals is: Hg > Cd > Pb > Zn > As > Cu > Cr > Ni. (2) Multivariate statistical analysis shows that 8 heavy metals can be classified to 2 principle components, among which PC1 ( Cd, Pb, Hg and Zn) is man-made source factor and mainly came from all kinds of waste of agriculture; PC2 ( Cu, Ni, Cr and As) is natural source and was mainly controlled by the background of the natural geography of this area. (3) Accumulation of index evaluation results show that the order of pollution degree values of 8 heavy metals in surface sediments of Aibi Lake is: Cd > Hg > Pb > Zn > As > Cu > Ni > Cr. In all samples, heavy metals Hg, Cd and Pb all belong to low and partial moderate pollution statue, while Zn, As, Cr, Ni and Cu belong to no pollution statue in majority samples. (4) Potential ecological risk assessment results show that the potential ecological risk of heavy metals in surface sediments of Aibi Lake mainly caused by Cd, Hg and Pb, and they accounting for 42.6%, 28.6% and 24.0% of the total amount, respectively, among which Cd is the main ecological risk factor, followed by Hg and Pb. In all samples, the potential ecological risk index values (RI) of 8 heavy metals are all lower than 150, and they are all at low ecological risk levels. However, this research also shows that there have high content of Cd and Pb in the sediment. Therefore, we should make long-term monitoring of the lake environment.

  16. Energy coupling of nuclear bursts in and above the ocean surface: source region calculations and experimental validation

    International Nuclear Information System (INIS)

    Clarke, D.B.; Harben, P.E.; Rock, D.W.; White, J.W.; Piacsek, A.

    1997-01-01

    In support of the Comprehensive Test Ban, research is under way on the long range propagation of signals from nuclear explosions in deep underwater sound (SOFAR) channel. Initially our work at LLNL on signals in the source region considered explosions in or above deep ocean. We studied the variation of wave properties and source region energy coupling as a function of height or depth of burst. Initial calculations on the CALE hydrodynamics code were linked at a few hundred milliseconds to a version of NRL's weak code, NPE, which solves the nonlinear progressive wave equation. The simulation of the wave propagation was carried down to 5000 m depth and out to 10,000 m range. We have completed ten such simulations at a variety of heights and depths below the ocean surface

  17. Painted surfaces - Important sources of polychlorinated biphenyls (PCBs) contamination to the urban and marine environment

    International Nuclear Information System (INIS)

    Jartun, Morten; Ottesen, Rolf Tore; Steinnes, Eiliv; Volden, Tore

    2009-01-01

    A study of a large number of samples of flaking old paint from various buildings in Bergen, Norway (N = 68) suggests that paint may be the most important contemporary source of PCBs in this urban environment with concentrations of PCB 7 up to 3.39 g/kg. Twenty-three of the samples were collected from a single building, and the concentrations were found to vary over 3 orders of magnitude. In addition, 16 concrete samples from a large bridge previously coated with PCB-containing paint were collected and separated into outer- and inner samples indicating that PCBs are still present in high concentrations subsequent to renovation. PCBs were found in several categories of paint from wooden and concrete buildings, potentially introduced to the environment by natural weathering, renovation, and volatilization. Consequently, this dispersion may lead to increased levels of PCBs in urban atmospheres, soils, and harbor sediments where high concentrations have resulted in Governmental advice against consumption of certain seafood. - Paint from structures built during the period 1950-1970 may be the most important source of PCBs in an urban environment

  18. Sources of present Chernobyl-derived caesium concentrations in surface air and deposition samples

    Energy Technology Data Exchange (ETDEWEB)

    Hoetzl, H.; Rosner, G.; Winkler, R. (Gesellschaft fuer Strahlen-und Umweltforschung Munich, Neuherberg (Germany). Forschungszentrum fuer Umwelt und Gesundheit Gesellschaft fuer Strahlen- und Umweltforschung mbH Muenchen, Neuherberg (Germany). Inst. fuer Strahlenschutz)

    1992-06-01

    The sources of Chernobyl-derived caesium concentrations in air and deposition samples collected from mid-1986 to end-1990 at Munich- Neuherberg, Germany, were investigated. Local resuspension has been found to be the main source. By comparison with deposition data from other locations it is estimated that within a range from 20 Bq m[sup -2] to 60 kBq m[sup -2] of initially deposited [sup 137]Cs activity [approx]2% is re-deposited by the process of local resuspension in Austria, Germany, Japan and United Kingdom, while significantly higher total resuspension is to be expected for Denmark and Finland. Stratospheric contribution to present concentrations is shown to be negligible. This is confirmed by cross correlation analysis between the time series of [sup 137]Cs in air and precipitation before and after the Chernobyl accident and the respective time series of cosmogenic [sup 7]Be, which is an indicator of stratospheric input. Seasonal variations of caesium concentrations with maxima in winter were observed. (author). 32 refs.; 5 figs.; 1 tab.

  19. Sources of present Chernobyl-derived caesium concentrations in surface air and deposition samples

    International Nuclear Information System (INIS)

    Hoetzl, H.; Rosner, G.; Winkler, R.; Gesellschaft fuer Strahlen- und Umweltforschung mbH Muenchen, Neuherberg

    1992-01-01

    The sources of Chernobyl-derived caesium concentrations in air and deposition samples collected from mid-1986 to end-1990 at Munich- Neuherberg, Germany, were investigated. Local resuspension has been found to be the main source. By comparison with deposition data from other locations it is estimated that within a range from 20 Bq m -2 to 60 kBq m -2 of initially deposited 137 Cs activity ∼2% is re-deposited by the process of local resuspension in Austria, Germany, Japan and United Kingdom, while significantly higher total resuspension is to be expected for Denmark and Finland. Stratospheric contribution to present concentrations is shown to be negligible. This is confirmed by cross correlation analysis between the time series of 137 Cs in air and precipitation before and after the Chernobyl accident and the respective time series of cosmogenic 7 Be, which is an indicator of stratospheric input. Seasonal variations of caesium concentrations with maxima in winter were observed. (author). 32 refs.; 5 figs.; 1 tab

  20. Online characterization of planetary surfaces: PlanetServer, an open-source analysis and visualization tool

    Science.gov (United States)

    Marco Figuera, R.; Pham Huu, B.; Rossi, A. P.; Minin, M.; Flahaut, J.; Halder, A.

    2018-01-01

    The lack of open-source tools for hyperspectral data visualization and analysis creates a demand for new tools. In this paper we present the new PlanetServer, a set of tools comprising a web Geographic Information System (GIS) and a recently developed Python Application Programming Interface (API) capable of visualizing and analyzing a wide variety of hyperspectral data from different planetary bodies. Current WebGIS open-source tools are evaluated in order to give an overview and contextualize how PlanetServer can help in this matters. The web client is thoroughly described as well as the datasets available in PlanetServer. Also, the Python API is described and exposed the reason of its development. Two different examples of mineral characterization of different hydrosilicates such as chlorites, prehnites and kaolinites in the Nili Fossae area on Mars are presented. As the obtained results show positive outcome in hyperspectral analysis and visualization compared to previous literature, we suggest using the PlanetServer approach for such investigations.

  1. Susceptibility of ground water to surface and shallow sources of contamination in Mississippi

    Science.gov (United States)

    O'Hara, Charles G.

    1996-01-01

    Ground water, because of its extensive use in agriculture, industry, and public-water supply, is one of Mississippi's most important natural resources.  Ground water is the source for about 80 percent of the total freshwater used by the State's population (Solley and others, 1993).  About 2,600 Mgal/d of freshwater is withdrawn from aquifers in Mississippi (D.E. Burt, Jr., U.S. Geological Survey, oral commun., 1995).  Wells capable of yielding 200 gal/min of water with quality suitable for most uses can be developed nearly anywhere in the State (Bednar, 1988).  The U.S. Geological Survey (USGS), in cooperation with the Mississippi Department of Environmental Quality, Office of Pollution Control, and the Mississippi Department of Agriculture and Commerce, Bureau of Plant Industry, conducted an investigation to evaluate the susceptibility of ground water to contamination from surgace and shallow sources in Mississippi.  A geographic information system (GIS) was used to develop and analyze statewide spatial data layers that contain geologic, hydrologic, physiographic, and cultural information.

  2. Advances in surface ion suppression from RILIS: Towards the Time-of-Flight Laser Ion Source (ToF-LIS)

    CERN Document Server

    Rothe, S; Crepieux, B; Day Goodacre, T; Fedosseev, V N; Giles, T; Marsh, B A; Ramos, J P; Rossel, R E

    2016-01-01

    We present results from the development towards the Time-of-Flight Laser Ion Source (ToF-LIS) aiming for the suppression of isobaric contaminants through fast beam gating. The capability to characterize high resistance ion sources has been successfully demonstrated. A ninefold selectivity gain has been achieved through suppression of surface ionized potassium, while maintaining >90% transmission for laser-ionized gallium using a thin wall graphite ionizer cavity combined with a fast beam gate. Initial results from the investigation of glassy carbon as a potential hot cavity ion source are presented. Power-cycle tests of a newly designed mount for fragile ion source cavities indicates its capability to survive the thermal stress expected during operation in an ISOLDE target unit. Finally, we introduce fast ion beam switching at a rate of 10 kHz using the ISOLDE ion beam switchyard as a new concept for ion beam distribution and conclude by highlighting the potential applications of this ion beam multiplexing te...

  3. Application of Response Surface Methodology to study the effect of different calcium sources in fish muscle-alginate restructured products

    Directory of Open Access Journals (Sweden)

    Helena María Moreno

    2011-03-01

    Full Text Available Sodium alginate needs the presence of calcium ions to gelify. For this reason, the contribution of the calcium source in a fish muscle mince added by sodium alginate, makes gelification possible, resulting a restructured fish product. The three different calcium sources considered were: Calcium Chloride (CC; Calcium Caseinate (CCa; and Calcium lactate (CLa. Several physical properties were analyzed, including mechanical properties, colour and cooking loss. Response Surface Methodology (RSM was used to determine the contribution of different calcium sources to a restructured fish muscle. The calcium source that modifies the system the most is CC. A combination of CC and sodium alginate weakened mechanical properties as reflected in the negative linear contribution of sodium alginate. Moreover, CC by itself increased lightness and cooking loss. The mechanical properties of restructured fish muscle elaborated were enhanced by using CCa and sodium alginate, as reflected in the negative linear contribution of sodium alginate. Also, CCa increased cooking loss. The role of CLa combined with sodium alginate was not so pronounced in the system discussed here.

  4. Bistatic High Frequency Radar Ocean Surface Cross Section for an FMCW Source with an Antenna on a Floating Platform

    Directory of Open Access Journals (Sweden)

    Yue Ma

    2016-01-01

    Full Text Available The first- and second-order bistatic high frequency radar cross sections of the ocean surface with an antenna on a floating platform are derived for a frequency-modulated continuous wave (FMCW source. Based on previous work, the derivation begins with the general bistatic electric field in the frequency domain for the case of a floating antenna. Demodulation and range transformation are used to obtain the range information, distinguishing the process from that used for a pulsed radar. After Fourier-transforming the autocorrelation and comparing the result with the radar range equation, the radar cross sections are derived. The new first- and second-order antenna-motion-incorporated bistatic radar cross section models for an FMCW source are simulated and compared with those for a pulsed source. Results show that, for the same radar operating parameters, the first-order radar cross section for the FMCW waveform is a little lower than that for a pulsed source. The second-order radar cross section for the FMCW waveform reduces to that for the pulsed waveform when the scattering patch limit approaches infinity. The effect of platform motion on the radar cross sections for an FMCW waveform is investigated for a variety of sea states and operating frequencies and, in general, is found to be similar to that for a pulsed waveform.

  5. Distribution, enrichment and sources of thallium in the surface sediments of the southwestern coastal Laizhou Bay, Bohai Sea.

    Science.gov (United States)

    Zhuang, Wen; Gao, Xuelu

    2015-07-15

    The concentrations of thallium (Tl) in the surface sediments of the southwestern coastal Laizhou Bay and the rivers it connects were determined. In riverine sediments, the Tl concentrations ranged from 0.34 to 0.76 μg g(-1) in summer; in autumn, the corresponding data were 0.35-1.08 μg g(-1). In marine sediments, the Tl concentrations ranged from 0.36 to 0.58 μg g(-1) in summer; and from 0.30 to 0.56 μg g(-1) in autumn. The grain size, Al and Fe oxides were major factors affecting Tl distribution. Tl in the surface sediments of the studied area was mainly from the natural input with the non-natural input as a subsidiary source. The low concentrations of Tl made it hard to cause potential negative environmental effects in this area. Copyright © 2015 Elsevier Ltd. All rights reserved.

  6. Distribution and sources of polycyclic aromatic hydrocarbons in surface sediments from the Bering Sea and western Arctic Ocean.

    Science.gov (United States)

    Zhao, Mengwei; Wang, Weiguo; Liu, Yanguang; Dong, Linsen; Jiao, Liping; Hu, Limin; Fan, Dejiang

    2016-03-15

    To analyze the distribution and sources of polycyclic aromatic hydrocarbons (PAHs) and evaluate their potential ecological risks, the concentrations of 16 PAHs were measured in 43 surface sediment samples from the Bering Sea and western Arctic Ocean. Total PAH (tPAH) concentrations ranged from 36.95 to 150.21 ng/g (dry weight). In descending order, the surface sediment tPAH concentrations were as follows: Canada Basin>northern Chukchi Sea>Chukchi Basin>southern Chukchi Sea>Aleutian Basin>Makarov Basin>Bering Sea shelf. The Bering Sea and western Arctic Ocean mainly received PAHs of pyrogenic origin due to pollution caused by the incomplete combustion of fossil fuels. The concentrations of PAHs in the sediments of the study areas did not exceed effects range low (ERL) values. Copyright © 2016 Elsevier Ltd. All rights reserved.

  7. A summary of the sources of input parameter values for the Waste Isolation Pilot Plant final porosity surface calculations

    International Nuclear Information System (INIS)

    Butcher, B.M.

    1997-08-01

    A summary of the input parameter values used in final predictions of closure and waste densification in the Waste Isolation Pilot Plant disposal room is presented, along with supporting references. These predictions are referred to as the final porosity surface data and will be used for WIPP performance calculations supporting the Compliance Certification Application to be submitted to the U.S. Environmental Protection Agency. The report includes tables and list all of the input parameter values, references citing their source, and in some cases references to more complete descriptions of considerations leading to the selection of values

  8. A summary of the sources of input parameter values for the Waste Isolation Pilot Plant final porosity surface calculations

    Energy Technology Data Exchange (ETDEWEB)

    Butcher, B.M.

    1997-08-01

    A summary of the input parameter values used in final predictions of closure and waste densification in the Waste Isolation Pilot Plant disposal room is presented, along with supporting references. These predictions are referred to as the final porosity surface data and will be used for WIPP performance calculations supporting the Compliance Certification Application to be submitted to the U.S. Environmental Protection Agency. The report includes tables and list all of the input parameter values, references citing their source, and in some cases references to more complete descriptions of considerations leading to the selection of values.

  9. Surface microlayer enrichment of volatile organic compounds and semi-volatile organic compounds in drinking water source.

    Science.gov (United States)

    Huang, Zhi; Zhou, Wen; Yu, Ya-juan; Zhang, Ai-qian; Han, Shuo-kui; Wang, Lian-sheng

    2004-01-01

    Enrichment of volatile organic compounds(VOC) and semi-volatility organic compounds(SVOC) in surface microlayer(SM) of three drinking water sources were studied. The enrichment factor(EFs) were 0.67 to 13.37 and 0.16 to 136, respectively. The results showed some VOC and most SVOC could enrich in SM. Some EFs of SVOC was quite high. Suspension and temperature could affect EFs of SVOC, slim wind and water movement do not destroy enrichment of organic in SM.

  10. Mineralization sources of surface and subsurface waters at the southeastern edges of dead sea basin in Jordan

    International Nuclear Information System (INIS)

    AbdEl-Samie, S.G.; EL-Shahat, M.F.; Al-Nawayseh, K.M.

    2004-01-01

    Surface and ground waters within the shallow-Alluvial and deep- Kurnub aquifers in four areas (Issal, Mazraa, Safi and Haditha) in the southeastern edge of the Dead Sea basin were evaluated according to Salinity changes and water quality degradation. Chemical and isotopic parameters were integrated to follow the chemical evolutionary trend and sources of mineralization in these waters. The isotopic results indicated that the main recharge sources Issal. Mazraa and Safi groundwaters are the flash flood and base flow water from the eastern highland through wadies. In Safi area, the groundwater that mixed with other depleted source could be paleowater seeped from older formation. The depletion in stable isotopic values with low d-parametewr (less than 10%) for Haditha groundwater confirms that the replenishment to the aquifer (Kurnub sandstone) had been formed during the pluvial time. The chemical data showed that the base flow water from the eastern highland is denoted by the least salinity values, whereas drainage water acquired the highest values as aa result of receiving a considerable amount of the remaining water from salt extraction processes. The groundwater in Safi wells has low salt content with respect to the other areas taping the same aquifer. The elevation in Ca and Mg ions reflects the dissolution of Ca-Mg rich minerals that actively reached saturation with respect to calcite and dolomite in all samples except Haditha deep aquifer due to its low ph values. In spite of the meteoric origin of the recharge source, the presence of MgCl 2 and CaCl 2 salts in almost all samples changed the water character to be old or recent marine genesis. This points to the effect of Dead Sea in both surface and ground waters. The obvious depletion in O-18 and isotopes for all ground waters samples with respect to the positive values of Dead Sea sample is good indicative for non mixing trend with Dead Sea water in the Alluvial and Kurnub aquifers

  11. Relationship between source-surface distance and patient dose in fluoroscopic X-ray examinations

    International Nuclear Information System (INIS)

    Suzuki, Shoichi; Asada, Yasuki; Nishi, Kazuta; Mizuno, Emiko; Hara, Natsue; Orito, Takeo; Kamei, Tetsuya; Koga, Sukehiko

    2000-01-01

    The International Electrotechnical Commission, IEC provided in its standard IEC 60601-1-3 (1994) to prevent the use during radioscopic irradiation of focal spot to skin distances less than 20 cm if the X-RAY EQUIPMENT is specified for RADIOSCOPY during surgery or 30 cm for other specified applications. This standard was reflected in the Japanese Industrial Standard JIS Z 4701-1997, which provided the minimum distance from focal spot to skin to be 30 cm for the use of a fluoroscopic and radiographic table (Under-table type). However, JIS had formerly provided the minimum distance to be 40 cm and so does the current Medical Treatment Law. The draft revision for the Medical Treatment Law currently discussed has consideration to adopt the value 30 cm in accordance with the current JIS. Our research intended to investigate the impact on the entrance surface dose for the change of the focal spot to skin distance from 40 cm to 30 cm. The result was 20-30% increase of the entrance surface dose for the focal spot to skin distance 30 cm. Taking patient exposure dose into account, we need further and more sufficient discussion with this result before adopting this value to the Medical Treatment Law. (author)

  12. Cooperation in carbon source degradation shapes spatial self-organization of microbial consortia on hydrated surfaces.

    Science.gov (United States)

    Tecon, Robin; Or, Dani

    2017-03-06

    Mounting evidence suggests that natural microbial communities exhibit a high level of spatial organization at the micrometric scale that facilitate ecological interactions and support biogeochemical cycles. Microbial patterns are difficult to study definitively in natural environments due to complex biodiversity, observability and variable physicochemical factors. Here, we examine how trophic dependencies give rise to self-organized spatial patterns of a well-defined bacterial consortium grown on hydrated surfaces. The model consortium consisted of two Pseudomonas putida mutant strains that can fully degrade the aromatic hydrocarbon toluene. We demonstrated that obligate cooperation in toluene degradation (cooperative mutualism) favored convergence of 1:1 partner ratio and strong intermixing at the microscale (10-100 μm). In contrast, competition for benzoate, a compound degraded independently by both strains, led to distinct segregation patterns. Emergence of a persistent spatial pattern has been predicted for surface attached microbial activity in liquid films that mediate diffusive exchanges while permitting limited cell movement (colony expansion). This study of a simple microbial consortium offers mechanistic glimpses into the rules governing the assembly and functioning of complex sessile communities, and points to general principles of spatial organization with potential applications for natural and engineered microbial systems.

  13. From Intensity Profile to Surface Normal: Photometric Stereo for Unknown Light Sources and Isotropic Reflectances.

    Science.gov (United States)

    Lu, Feng; Matsushita, Yasuyuki; Sato, Imari; Okabe, Takahiro; Sato, Yoichi

    2015-10-01

    We propose an uncalibrated photometric stereo method that works with general and unknown isotropic reflectances. Our method uses a pixel intensity profile, which is a sequence of radiance intensities recorded at a pixel under unknown varying directional illumination. We show that for general isotropic materials and uniformly distributed light directions, the geodesic distance between intensity profiles is linearly related to the angular difference of their corresponding surface normals, and that the intensity distribution of the intensity profile reveals reflectance properties. Based on these observations, we develop two methods for surface normal estimation; one for a general setting that uses only the recorded intensity profiles, the other for the case where a BRDF database is available while the exact BRDF of the target scene is still unknown. Quantitative and qualitative evaluations are conducted using both synthetic and real-world scenes, which show the state-of-the-art accuracy of smaller than 10 degree without using reference data and 5 degree with reference data for all 100 materials in MERL database.

  14. ConoSurf: Open-source 3D scanning system based on a conoscopic holography device for acquiring surgical surfaces.

    Science.gov (United States)

    Brudfors, Mikael; García-Vázquez, Verónica; Sesé-Lucio, Begoña; Marinetto, Eugenio; Desco, Manuel; Pascau, Javier

    2017-09-01

    A difficulty in computer-assisted interventions is acquiring the patient's anatomy intraoperatively. Standard modalities have several limitations: low image quality (ultrasound), radiation exposure (computed tomography) or high costs (magnetic resonance imaging). An alternative approach uses a tracked pointer; however, the pointer causes tissue deformation and requires sterilizing. Recent proposals, utilizing a tracked conoscopic holography device, have shown promising results without the previously mentioned drawbacks. We have developed an open-source software system that enables real-time surface scanning using a conoscopic holography device and a wide variety of tracking systems, integrated into pre-existing and well-supported software solutions. The mean target registration error of point measurements was 1.46 mm. For a quick guidance scan, surface reconstruction improved the surface registration error compared with point-set registration. We have presented a system enabling real-time surface scanning using a tracked conoscopic holography device. Results show that it can be useful for acquiring the patient's anatomy during surgery. © 2016 The Authors. The International Journal of Medical Robotics and Computer Assisted Surgery Published by John Wiley & Sons Ltd.

  15. Food contact surfaces coated with nitrogen-doped titanium dioxide: effect on Listeria monocytogenes survival under different light sources

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, D.; Teixeira, P. [Institute for Biotechnology and Bioengineering, Centre of Biological Engineering, University of Minho, Campus de Gualtar, 4710-057 Braga (Portugal); Tavares, C.J. [Center of Physics, University of Minho, Campus de Azurém, 4800-058 Guimarães (Portugal); Azeredo, J., E-mail: jazeredo@deb.uminho.pt [Institute for Biotechnology and Bioengineering, Centre of Biological Engineering, University of Minho, Campus de Gualtar, 4710-057 Braga (Portugal)

    2013-04-01

    Improvement of food safety is a very important issue, and is on the basis of production and application of new/modified food contact surfaces. Titanium dioxide (TiO{sub 2}) and, more recently, nitrogen-doped titanium dioxide (N-TiO{sub 2}) coatings are among the possible forms to enhance food contact surfaces performance in terms of higher hygiene and easier sanitation. In this context, the present work aimed at evaluating the bactericidal activity of an N-TiO{sub 2} coating on glass and stainless steel under two different sources of visible light – fluorescent and incandescent – and ultraviolet (UV) irradiation. Listeria monocytogenes was chosen as representative of major foodborne pathogens and its survival was tested on N-TiO{sub 2} coated coupons. In terms of survival percentage, good results were obtained after exposure of coated surfaces to all light types since, apart from the value obtained after exposing glass to fluorescent light (56.3%), survival rates were always below 50%. However, no effective disinfection was obtained, given that for a disinfectant or sanitizing agent to be claimed as effective it needs to be able to promote at least a 3-log reduction of the microbial load, which was not observed for any of the experimental conditions assessed. Even so, UV irradiation was the most successful on eliminating cells on coated surfaces, since the amount of bacteria was reduced to 1.49 × 10{sup 6} CFU/ml on glass and 2.37 × 10{sup 7} on stainless steel. In contrast, both visible light sources had only slightly decreased the amount of viable cells, which remained in the range of 8 log CFU/ml. Hence, although some bactericidal effect was accomplished under visible light, UV was the most effective light source on promoting photocatalytic reactions on N-TiO{sub 2} coated coupons and none of the experimental conditions have reached a satisfactory disinfection level. Thus, this surface coating needs further research and improvement in order to become truly

  16. Food contact surfaces coated with nitrogen-doped titanium dioxide: effect on Listeria monocytogenes survival under different light sources

    International Nuclear Information System (INIS)

    Rodrigues, D.; Teixeira, P.; Tavares, C.J.; Azeredo, J.

    2013-01-01

    Improvement of food safety is a very important issue, and is on the basis of production and application of new/modified food contact surfaces. Titanium dioxide (TiO 2 ) and, more recently, nitrogen-doped titanium dioxide (N-TiO 2 ) coatings are among the possible forms to enhance food contact surfaces performance in terms of higher hygiene and easier sanitation. In this context, the present work aimed at evaluating the bactericidal activity of an N-TiO 2 coating on glass and stainless steel under two different sources of visible light – fluorescent and incandescent – and ultraviolet (UV) irradiation. Listeria monocytogenes was chosen as representative of major foodborne pathogens and its survival was tested on N-TiO 2 coated coupons. In terms of survival percentage, good results were obtained after exposure of coated surfaces to all light types since, apart from the value obtained after exposing glass to fluorescent light (56.3%), survival rates were always below 50%. However, no effective disinfection was obtained, given that for a disinfectant or sanitizing agent to be claimed as effective it needs to be able to promote at least a 3-log reduction of the microbial load, which was not observed for any of the experimental conditions assessed. Even so, UV irradiation was the most successful on eliminating cells on coated surfaces, since the amount of bacteria was reduced to 1.49 × 10 6 CFU/ml on glass and 2.37 × 10 7 on stainless steel. In contrast, both visible light sources had only slightly decreased the amount of viable cells, which remained in the range of 8 log CFU/ml. Hence, although some bactericidal effect was accomplished under visible light, UV was the most effective light source on promoting photocatalytic reactions on N-TiO 2 coated coupons and none of the experimental conditions have reached a satisfactory disinfection level. Thus, this surface coating needs further research and improvement in order to become truly effective against foodborne

  17. Food contact surfaces coated with nitrogen-doped titanium dioxide: effect on Listeria monocytogenes survival under different light sources

    Science.gov (United States)

    Rodrigues, D.; Teixeira, P.; Tavares, C. J.; Azeredo, J.

    2013-04-01

    Improvement of food safety is a very important issue, and is on the basis of production and application of new/modified food contact surfaces. Titanium dioxide (TiO2) and, more recently, nitrogen-doped titanium dioxide (N-TiO2) coatings are among the possible forms to enhance food contact surfaces performance in terms of higher hygiene and easier sanitation. In this context, the present work aimed at evaluating the bactericidal activity of an N-TiO2 coating on glass and stainless steel under two different sources of visible light - fluorescent and incandescent - and ultraviolet (UV) irradiation. Listeria monocytogenes was chosen as representative of major foodborne pathogens and its survival was tested on N-TiO2 coated coupons. In terms of survival percentage, good results were obtained after exposure of coated surfaces to all light types since, apart from the value obtained after exposing glass to fluorescent light (56.3%), survival rates were always below 50%. However, no effective disinfection was obtained, given that for a disinfectant or sanitizing agent to be claimed as effective it needs to be able to promote at least a 3-log reduction of the microbial load, which was not observed for any of the experimental conditions assessed. Even so, UV irradiation was the most successful on eliminating cells on coated surfaces, since the amount of bacteria was reduced to 1.49 × 106 CFU/ml on glass and 2.37 × 107 on stainless steel. In contrast, both visible light sources had only slightly decreased the amount of viable cells, which remained in the range of 8 log CFU/ml. Hence, although some bactericidal effect was accomplished under visible light, UV was the most effective light source on promoting photocatalytic reactions on N-TiO2 coated coupons and none of the experimental conditions have reached a satisfactory disinfection level. Thus, this surface coating needs further research and improvement in order to become truly effective against foodborne pathogens and

  18. Residues, Sources and Potential Biological Risk of Organochlorine Pesticides in Surface Sediments of Qiandao Lake, China.

    Science.gov (United States)

    Yang, Huayun; Zhou, Shanshan; Li, Weidong; Liu, Qi; Tu, Yunjie

    2015-10-01

    Sediment samples were analyzed to comprehensively characterize the concentrations, distribution, possible sources and potential biological risk of organochlorine pesticides in Qiandao Lake, China. Concentrations of sumHCH and sumDDT in sediments ranged from 0.03 to 5.75 ng/g dry weight and not detected to 14.39 ng/g dry weight. The predominant β-HCH and the α-HCH/γ-HCH ratios indicated that the residues of HCHs were derived not only from historical technical HCH use but also from additional usage of lindane. Ratios of o,p'-DDT/p,p'-DDT and DDD/DDE suggested that both dicofol-type DDT and technical DDT applications may be present in most study areas. Additionally, based on two sediment quality guidelines, γ-HCH, o,p'-DDT and p,p'-DDT could be the main organochlorine pesticides species of ecotoxicological concern in Qiandao Lake.

  19. Monitoring the energy scale of KATRIN with conversion electrons of a solid {sup 83m}Kr source as nuclear standard

    Energy Technology Data Exchange (ETDEWEB)

    Schloesser, Klaus [IKP, Karlsruher Institut fuer Technologie (Germany); Collaboration: KATRIN-Collaboration

    2016-07-01

    For KATRIN to be able to achieve the desired sensitivity of 200 meV/c{sup 2} for the effective electron neutrino mass, it is of crucial importance that the energy scale of the main spectrometer (18.6 keV) is under control within +/-60 mV at any given time over the planned measurement time of approximately 5 years. Besides conventional high voltage dividers and high precision volt meters, a nuclear standard will be deployed additionally in a separate spectrometer of MAC-E filter type. The filter electrodes of both spectrometers are connected galvanically. For permanent and continuous monitoring an easy to use ion implanted source containing the noble gas {sup 83m}Kr was developed and qualified for HV monitoring at the ppm level in the 30 kV regime. This talk presents the methods applied and the achievements made.

  20. Microbial conversion of sulfur dioxide in flue gas to sulfide using bulk drug industry wastewater as an organic source by mixed cultures of sulfate reducing bacteria

    International Nuclear Information System (INIS)

    Rao, A. Gangagni; Ravichandra, P.; Joseph, Johny; Jetty, Annapurna; Sarma, P.N.

    2007-01-01

    Mixed cultures of sulfate reducing bacteria (SRB) were isolated from anaerobic cultures and enriched with SRB media. Studies on batch and continuous reactors for the removal of SO 2 with bulk drug industry wastewater as an organic source using isolated mixed cultures of SRB revealed that isolation and enrichment methodology adopted in the present study were apt to suppress the undesirable growth of anaerobic bacteria other than SRB. Studies on anaerobic reactors showed that process was sustainable at COD/S ratio of 2.2 and above with optimum sulfur loading rate (SLR) of 5.46 kg S/(m 3 day), organic loading rate (OLR) of 12.63 kg COD/(m 3 day) and at hydraulic residence time (HRT) of 8 h. Free sulfide (FS) concentration in the range of 300-390 mg FS/l was found to be inhibitory to mixed cultures of SRB used in the present studies

  1. Accurate source location from waves scattered by surface topography: Applications to the Nevada and North Korean test sites

    Science.gov (United States)

    Shen, Y.; Wang, N.; Bao, X.; Flinders, A. F.

    2016-12-01

    Scattered waves generated near the source contains energy converted from the near-field waves to the far-field propagating waves, which can be used to achieve location accuracy beyond the diffraction limit. In this work, we apply a novel full-wave location method that combines a grid-search algorithm with the 3D Green's tensor database to locate the Non-Proliferation Experiment (NPE) at the Nevada test site and the North Korean nuclear tests. We use the first arrivals (Pn/Pg) and their immediate codas, which are likely dominated by waves scattered at the surface topography near the source, to determine the source location. We investigate seismograms in the frequency of [1.0 2.0] Hz to reduce noises in the data and highlight topography scattered waves. High resolution topographic models constructed from 10 and 90 m grids are used for Nevada and North Korea, respectively. The reference velocity model is based on CRUST 1.0. We use the collocated-grid finite difference method on curvilinear grids to calculate the strain Green's tensor and obtain synthetic waveforms using source-receiver reciprocity. The `best' solution is found based on the least-square misfit between the observed and synthetic waveforms. To suppress random noises, an optimal weighting method for three-component seismograms is applied in misfit calculation. Our results show that the scattered waves are crucial in improving resolution and allow us to obtain accurate solutions with a small number of stations. Since the scattered waves depends on topography, which is known at the wavelengths of regional seismic waves, our approach yields absolute, instead of relative, source locations. We compare our solutions with those of USGS and other studies. Moreover, we use differential waveforms to locate pairs of the North Korea tests from years 2006, 2009, 2013 and 2016 to further reduce the effects of unmodeled heterogeneities and errors in the reference velocity model.

  2. CONTROLLING INFLUENCE OF MAGNETIC FIELD ON SOLAR WIND OUTFLOW: AN INVESTIGATION USING CURRENT SHEET SOURCE SURFACE MODEL

    Energy Technology Data Exchange (ETDEWEB)

    Poduval, B., E-mail: bpoduval@spacescience.org [Space Science Institute, Boulder, CO 80303 (United States)

    2016-08-10

    This Letter presents the results of an investigation into the controlling influence of large-scale magnetic field of the Sun in determining the solar wind outflow using two magnetostatic coronal models: current sheet source surface (CSSS) and potential field source surface. For this, we made use of the Wang and Sheeley inverse correlation between magnetic flux expansion rate (FTE) and observed solar wind speed (SWS) at 1 au. During the period of study, extended over solar cycle 23 and beginning of solar cycle 24, we found that the coefficients of the fitted quadratic equation representing the FTE–SWS inverse relation exhibited significant temporal variation, implying the changing pattern of the influence of FTE on SWS over time. A particularly noteworthy feature is an anomaly in the behavior of the fitted coefficients during the extended minimum, 2008–2010 (CRs 2073–2092), which is considered due to the particularly complex nature of the solar magnetic field during this period. However, this variation was significant only for the CSSS model, though not a systematic dependence on the phase of the solar cycle. Further, we noticed that the CSSS model demonstrated better solar wind prediction during the period of study, which we attribute to the treatment of volume and sheet currents throughout the corona and the more accurate tracing of footpoint locations resulting from the geometry of the model.

  3. Pollution characteristics and ecological risk assessment of heavy metals in the surface sediments from a source water reservoir

    Directory of Open Access Journals (Sweden)

    Changming Yang

    2016-10-01

    Full Text Available Surface sediment samples were collected from a source water reservoir in Zhejiang Province, East of China to investigate pollution characteristics and potential ecological risk of heavy metals. The BCR sequential extraction method was used to determine the four chemical fractions of heavy metals such as acid soluble, easily reducible, easily oxidizable and residual fractions. The heavy metals pollution and potential ecological risk were evaluated systematically using geoaccumulation index (Igeo and Hakanson potential ecological risk index (H′. The results showed that the sampling sites from the estuaries of tributary flowing through downtowns and heavy industrial parks showed significantly (p < 0.05 higher average concentrations of heavy metals in the surface sediments, as compared to the other sampling sites. Chemical fractionation showed that Mn existed mainly in acid extractable fraction, Cu and Pb were mainly in reducible fraction, and As existed mainly in residual fraction in the surface sediments despite sampling sites. The sampling sites from the estuary of tributary flowing through downtown showed significantly (p < 0.05 higher proportions of acid extractable and reducible fractions than the other sampling sites, which would pose a potential toxic risk to aquatic organisms as well as a potential threat to drinking water safety. As, Pb, Ni and Cu were at relatively high potential ecological risk with high Igeo values for some sampling locations. Hakanson potential ecological risk index (H′ showed the surface sediments from the tributary estuaries with high population density and rapid industrial development showed significantly (p < 0.05 higher heavy metal pollution levels and potential ecological risk in the surface sediments, as compared to the other sampling sites.

  4. Spatial Variation, Pollution Assessment and Source Identification of Major Nutrients in Surface Sediments of Nansi Lake, China

    Directory of Open Access Journals (Sweden)

    Longfeng Wang

    2017-06-01

    Full Text Available Nansi Lake has been seriously affected by intensive anthropogenic activities in recent years. In this study, an extensive survey on spatial variation, pollution assessment as well as the possible sources identification of major nutrients (Total phosphorus: TP, Total nitrogen: TN, and Total organic carbon: TOC in the surface sediments of Nansi Lake was conducted. Results showed that the mean contents of TP, TN and TOC were 1.13-, 5.40- and 2.50- fold higher than their background values respectively. Most of the TN and TOC contents in the surface sediments of Nansi Lake were four times as high or higher and twice as high or higher than the background values except the Zhaoyang sub-lake, and the spatial distribution of TN and TOC contents were remarkably similar over a large area. Nearly all the TP contents in the surface sediments of Nansi Lake were all higher than its background values except most part of the Zhaoyang sub-lake. Based on the enrichment factor (EF and the organic pollution evaluation index (Org-index, TP, TOC and TN showed minor enrichment (1.13, minor enrichment (2.50 and moderately severe enrichment (5.40, respectively, and most part of the Dushan sub-lake and the vicinity of the Weishan island were in moderate or heavy sediments organic pollution, while the other parts were clean. Moreover, according to the results of multivariate statistical analysis, we deduced that anthropogenic TN and TOC were mainly came from industrial sources including enterprises distributed in Jining, Yanzhou and Zoucheng along with iron and steel industries distributed in the southern of the Weishan sub-lake, whereas TP mainly originated from runoff and soil erosion coming from agricultural lands located in Heze city and Weishan island, the local aquacultural activities as well as the domestic sewage discharge of Jining city.

  5. Temporal sea-surface gravity changes observed near the source area prior to the 2011 Tohoku earthquake

    Science.gov (United States)

    Nakamura, T.; Tsuboi, S.

    2013-12-01

    Recent seismological studies suggested subsurface activities preceding the 2011 Tohoku earthquake; the occurrence of migration of seismicity (Kato et al., 2012) and slow slip events (Ito et al., 2013) in and around the source area one month before the mainshock. In this study, we investigated sea-surface gravity changes observed by the shipboard gravimeter mounted on research vessels before the mainshock. The vessels incidentally passed through the source area along almost the same cruise track twice, four months before and one month before the mainshock. Comparing the sea surface gravity in the former track with that in the latter after Bouguer correction, we find the gravity changes of approximately 7 mGal in coseismic slip areas near the trench axis during the three months. We find these gravity changes even in the crossing areas of the cruise tracks where seafloor topographies have no differences between the tracks. We also find that the topographic differences show positive changes but the gravity changes negative ones in other areas, which is a negative correlation inconsistent with the theoretical relationship between the topographic difference and the gravity change. These mean that the differences of seafloor topographies due to differences between the two cruise tracks are not main causes of the observed gravity changes there. The changes cannot also be explained by drifts of the gravimeter and geostrophic currents. Although we have not had any clear evidences, we speculate that the possible cause may be density increases around the seismogenic zone or uplifts of seafloor in order to explain the changes of this size. We estimate the density increases of 1.0 g/cm**3 in a disk with a radius of 40 km and a width of 200 m or the uplifts of several tens of meters in seafloor areas for the observed gravity changes. Our results indicate that sea-surface gravity observations may be one of valid approaches to monitor the approximate location of a possible great

  6. Independent Subspace Analysis of the Sea Surface Temperature Variability: Non-Gaussian Sources and Sensitivity to Sampling and Dimensionality

    Directory of Open Access Journals (Sweden)

    Carlos A. L. Pires

    2017-01-01

    Full Text Available We propose an expansion of multivariate time-series data into maximally independent source subspaces. The search is made among rotations of prewhitened data which maximize non-Gaussianity of candidate sources. We use a tensorial invariant approximation of the multivariate negentropy in terms of a linear combination of squared coskewness and cokurtosis. By solving a high-order singular value decomposition problem, we extract the axes associated with most non-Gaussianity. Moreover, an estimate of the Gaussian subspace is provided by the trailing singular vectors. The independent subspaces are obtained through the search of “quasi-independent” components within the estimated non-Gaussian subspace, followed by the identification of groups with significant joint negentropies. Sources result essentially from the coherency of extremes of the data components. The method is then applied to the global sea surface temperature anomalies, equatorward of 65°, after being tested with non-Gaussian surrogates consistent with the data anomalies. The main emerging independent components and subspaces, supposedly generated by independent forcing, include different variability modes, namely, The East-Pacific, the Central Pacific, and the Atlantic Niños, the Atlantic Multidecadal Oscillation, along with the subtropical dipoles in the Indian, South Pacific, and South-Atlantic oceans. Benefits and usefulness of independent subspaces are then discussed.

  7. Ecological risk assessment and source identification for heavy metals in surface sediment from the Liaohe River protected area, China.

    Science.gov (United States)

    Ke, Xin; Gui, Shaofeng; Huang, Hao; Zhang, Haijun; Wang, Chunyong; Guo, Wei

    2017-05-01

    Surface sediment samples collected from 19 sites in the Liaohe River protected area were analysed for heavy metals to evaluate their potential ecological risk. The results demonstrated that the degree of pollution from seven heavy metals decreases in the following sequence: cadmium(Cd)>arsenic(As)>copper(Cu)>nickel(Ni)>lead(Pb)>chromium(Cr)>zinc(Zn). The metal speciation analysis indicated that Cd, Pb and Zn were dominated by non-residual fractions and have high mobility and bioavailability, indicating significant anthropogenic sources. Based on the potential ecological risk index (PERI), geo-accumulation index (I geo ) and risk assessment code (RAC), Cd made the most dominant contribution, with a high to very high potential ecological risk being determined in this studied area. Moreover, in reference to the results of multivariate statistical analyses, we deduced that Cd and Zn originated from agriculture sources within the Liaohe River protected area, whereas Cu, Cr and Ni primarily originated from natural sources. Copyright © 2017 Elsevier Ltd. All rights reserved.

  8. Analyse of pollution sources in Horna Nitra river basin using the system GeoEnviron such as instrument for groundwater and surface water pollution risk assessment

    International Nuclear Information System (INIS)

    Kutnik, P.

    2004-01-01

    In this presentation author deals with the analyse of pollution sources in Horna Nitra river basin using the system GeoEnviron such as instrument for groundwater and surface water pollution risk assessment

  9. The conversational interface talking to smart devices

    CERN Document Server

    McTear, Michael; Griol, David

    2016-01-01

    This book provides a comprehensive introduction to the conversational interface, which is becoming the main mode of interaction with virtual personal assistants, smart devices, various types of wearables, and social robots. The book consists of four parts: Part I presents the background to conversational interfaces, examining past and present work on spoken language interaction with computers; Part II covers the various technologies that are required to build a conversational interface along with practical chapters and exercises using open source tools; Part III looks at interactions with smart devices, wearables, and robots, and then goes on to discusses the role of emotion and personality in the conversational interface; Part IV examines methods for evaluating conversational interfaces and discusses future directions. · Presents a comprehensive overview of the various technologies that underlie conversational user interfaces; · Combines descriptions of conversational user interface technologies with a gui...

  10. Microscopic isolation and characterization of free living amoebae (FLA from surface water sources.in Birjand, the capital city of the South Khorasan

    Directory of Open Access Journals (Sweden)

    Mahmoodreza Behravan

    2015-07-01

    Conclusion: The results indicated that a significant percentage of surface water sources in Birjand city was contaminated with Acanthamoeba spp. It is necessary for physicians, therefore, to take into account the diseases caused by these infectious agents. Besides, local regional health professionals should take into consideration the potential role of surface stagnant water sources in transferring these infectious agents. Placing warning signs in areas contaminated with these infectious agents seems a useful measure.

  11. Concentrations and sources of polycyclic aromatic hydrocarbons in surface coastal sediments of the northern Gulf of Mexico

    Science.gov (United States)

    2014-01-01

    Background Coastal sediments in the northern Gulf of Mexico have a high potential of being contaminated by petroleum hydrocarbons, such as polycyclic aromatic hydrocarbons (PAHs), due to extensive petroleum exploration and transportation activities. In this study we evaluated the spatial distribution and contamination sources of PAHs, as well as the bioavailable fraction in the bulk PAH pool, in surface marsh and shelf sediments (top 5 cm) of the northern Gulf of Mexico. Results PAH concentrations in this region ranged from 100 to 856 ng g−1, with the highest concentrations in Mississippi River mouth sediments followed by marsh sediments and then the lowest concentrations in shelf sediments. The PAH concentrations correlated positively with atomic C/N ratios of sedimentary organic matter (OM), suggesting that terrestrial OM preferentially sorbs PAHs relative to marine OM. PAHs with 2 rings were more abundant than those with 5–6 rings in continental shelf sediments, while the opposite was found in marsh sediments. This distribution pattern suggests different contamination sources between shelf and marsh sediments. Based on diagnostic ratios of PAH isomers and principal component analysis, shelf sediment PAHs were petrogenic and those from marsh sediments were pyrogenic. The proportions of bioavailable PAHs in total PAHs were low, ranging from 0.02% to 0.06%, with higher fractions found in marsh than shelf sediments. Conclusion PAH distribution and composition differences between marsh and shelf sediments were influenced by grain size, contamination sources, and the types of organic matter associated with PAHs. Concentrations of PAHs in the study area were below effects low-range, suggesting a low risk to organisms and limited transfer of PAHs into food web. From the source analysis, PAHs in shelf sediments mainly originated from direct petroleum contamination, while those in marsh sediments were from combustion of fossil fuels. PMID:24641695

  12. SU-F-BRA-09: New Efficient Method for Xoft Axxent Electronic Brachytherapy Source Calibration by Pre-Characterizing Surface Applicators

    Energy Technology Data Exchange (ETDEWEB)

    Pai, S [iCAD Inc., Los Gatos, CA (United States)

    2015-06-15

    Purpose: The objective is to improve the efficiency and efficacy of Xoft™ Axxent™ electronic brachytherapy (EBT) calibration of the source & surface applicator using AAPM TG-61 formalism. Methods: Current method of Xoft EBT source calibration involves determination of absolute dose rate of the source in each of the four conical surface applicators using in-air chamber measurements & TG61 formalism. We propose a simplified TG-61 calibration methodology involving initial characterization of surface cone applicators. This is accomplished by calibrating dose rates for all 4 surface applicator sets (for 10 sources) which establishes the “applicator output ratios” with respect to the selected reference applicator (20 mm applicator). After the initial time, Xoft™ Axxent™ source TG61 Calibration is carried out only in the reference applicator. Using the established applicator output ratios, dose rates for other applicators will be calculated. Results: 200 sources & 8 surface applicator sets were calibrated cumulatively using a Standard Imaging A20 ion-chamber in accordance with manufacturer-recommended protocols. Dose rates of 10, 20, 35 & 50mm applicators were normalized to the reference (20mm) applicator. The data in Figure 1 indicates that the normalized dose rate variation for each applicator for all 200 sources is better than ±3%. The average output ratios are 1.11, 1.02 and 0.49 for the 10 mm,35 mm and 50 mm applicators, respectively, which are in good agreement with the manufacturer’s published output ratios of 1.13, 1.02 and 0.49. Conclusion: Our measurements successfully demonstrate the accuracy of a new calibration method using a single surface applicator for Xoft EBT sources and deriving the dose rates of other applicators. The accuracy of the calibration is improved as this method minimizes the source position variation inside the applicator during individual source calibrations. The new method significantly reduces the calibration time to less

  13. Modelling surface energy fluxes over a Dehesa ecosystem using a two-source energy balance model.

    Science.gov (United States)

    Andreu, Ana; Kustas, William. P.; Anderson, Martha C.; Carrara, Arnaud; Patrocinio Gonzalez-Dugo, Maria

    2013-04-01

    The Dehesa is the most widespread agroforestry land-use system in Europe, covering more than 3 million hectares in the Iberian Peninsula and Greece (Grove and Rackham, 2001; Papanastasis, 2004). It is an agro-silvo-pastural ecosystem consisting of widely-spaced oak trees (mostly Quercus ilex L.), combined with crops, pasture and Mediterranean shrubs, and it is recognized as an example of sustainable land use and for his importance in the rural economy (Diaz et al., 1997; Plieninger and Wilbrand, 2001). The ecosystem is influenced by a Mediterranean climate, with recurrent and severe droughts. Over the last decades the Dehesa has faced multiple environmental threats, derived from intensive agricultural use and socio-economic changes, which have caused environmental degradation of the area, namely reduction in tree density and stocking rates, changes in soil properties and hydrological processes and an increase of soil erosion (Coelho et al. 2004; Schnabel and Ferreira, 2004; Montoya 1998; Pulido and Díaz, 2005). Understanding the hydrological, atmospheric and physiological processes that affect the functioning of the ecosystem will improve the management and conservation of the Dehesa. One of the key metrics in assessing ecosystem health, particularly in this water-limited environment, is the capability of monitoring evaporation (ET). To make large area assessments requires the use of remote sensing. Thermal-based energy balance techniques that distinguish soil/substrate and vegetation contributions to the radiative temperature and radiation/turbulent fluxes have proven to be reliable in such semi-arid sparse canopy-cover landscapes. In particular, the two-source energy balance (TSEB) model of Norman et al. (1995) and Kustas and Norman (1999) has shown to be robust for a wide range of partially-vegetated landscapes. The TSEB formulation is evaluated at a flux tower site located in center Spain (Majadas del Tietar, Caceres). Its application in this environment is

  14. Dedicated detectors for surface studies by Moessbauer spectroscopy

    International Nuclear Information System (INIS)

    Bibicu, I.; Rogalski, M.S.; Nicolescu, G.

    2001-01-01

    Moessbauer spectroscopy is a nuclear resonance method largely utilized in solid state studies. Following resonant nuclear absorption, gamma radiations, conversion X-rays, conversion or Auger electrons are emitted. By detection of gamma radiations information about the sample as a whole are obtained while by detection of electrons or X radiation one obtains data on the surface layer. Our laboratory was among the firsts to produce and use flow gas proportional detectors for surface studies by Moessbauer spectroscopy. Four types of detectors were devised: - detectors for electron detection (90% He + 10% CH 4 ); - detectors for conversion X-ray detection (90% Ar + 10% CH 4 ); - detectors for electrons or internal conversion X rays; - detectors for simultaneous detection of electrons and conversion X rays emitted from the same source. All detectors allow simultaneous Moessbauer measurements both for surface and volume for a given sample. Details of construction are presented for the four types of detectors

  15. Sources, pathways, and relative risks of contaminants in surface water and groundwater: a perspective prepared for the Walkerton inquiry.

    Science.gov (United States)

    Ritter, Len; Solomon, Keith; Sibley, Paul; Hall, Ken; Keen, Patricia; Mattu, Gevan; Linton, Beth

    2002-01-11

    On a global scale, pathogenic contamination of drinking water poses the most significant health risk to humans, and there have been countless numbers of disease outbreaks and poisonings throughout history resulting from exposure to untreated or poorly treated drinking water. However, significant risks to human health may also result from exposure to nonpathogenic, toxic contaminants that are often globally ubiquitous in waters from which drinking water is derived. With this latter point in mind, the objective of this commission paper is to discuss the primary sources of toxic contaminants in surface waters and groundwater, the pathways through which they move in aquatic environments, factors that affect their concentration and structure along the many transport flow paths, and the relative risks that these contaminants pose to human and environmental health. In assessing the relative risk of toxic contaminants in drinking water to humans, we have organized our discussion to follow the classical risk assessment paradigm, with emphasis placed on risk characterization. In doing so, we have focused predominantly on toxic contaminants that have had a demonstrated or potential effect on human health via exposure through drinking water. In the risk assessment process, understanding the sources and pathways for contaminants in the environment is a crucial step in addressing (and reducing) uncertainty associated with estimating the likelihood of exposure to contaminants in drinking water. More importantly, understanding the sources and pathways of contaminants strengthens our ability to quantify effects through accurate measurement and testing, or to predict the likelihood of effects based on empirical models. Understanding the sources, fate, and concentrations of chemicals in water, in conjunction with assessment of effects, not only forms the basis of risk characterization, but also provides critical information required to render decisions regarding regulatory

  16. Calculation of conversion coefficients of dose of a computational anthropomorphic simulator sit exposed to a plane source; Calculo de coeficientes de conversao de dose de um simulador antropomorfico computacional sentado exposto a uma fonte plana

    Energy Technology Data Exchange (ETDEWEB)

    Santos, William S.; Carvalho Junior, Alberico B. de; Pereira, Ariana J.S.; Santos, Marcos S.; Maia, Ana F., E-mail: williathan@yahoo.com.b, E-mail: ablohem@gmail.co, E-mail: ariana-jsp@hotmail.co, E-mail: m_souzasantos@hotmail.co, E-mail: afmaia@ufs.b [Universidade Federal de Sergipe (UFS), Aracaju, SE (Brazil)

    2011-10-26

    In this paper conversion coefficients (CCs) of equivalent dose and effective in terms of kerma in the air were calculated suggested by the ICRP 74. These dose coefficients were calculated considering a plane radiation source and monoenergetic for a spectrum of energy varying from 10 keV to 2 MeV. The CCs were obtained for four geometries of irradiation, anterior-posterior, posterior-anterior, lateral right side and lateral left side. It was used the radiation transport code Visual Monte Carlo (VMC), and a anthropomorphic simulator of sit female voxel. The observed differences in the found values for the CCs at the four irradiation sceneries are direct results of the body organs disposition, and the distance of these organs to the irradiation source. The obtained CCs will be used for estimative more precise of dose in situations that the exposed individual be sit, as the normally the CCs available in the literature were calculated by using simulators always lying or on their feet

  17. Unraveling the role of support surface hydroxyls and its effect on the selectivity of C{sub 2} species over Rh/γ-Al{sub 2}O{sub 3} catalyst in syngas conversion: A theoretical study

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Riguang; Duan, Tian; Wang, Baojun, E-mail: wangbaojun@tyut.edu.cn; Ling, Lixia

    2016-08-30

    Highlights: • The selectivity toward CH{sub x} (x = 1–3) depends on γ-Al{sub 2}O{sub 3} support and its surface properties. • Rh/γ-Al{sub 2}O{sub 3} catalyst exhibits the higher selectivity toward CH{sub x} (x = 1,2) formation from syngas. • C{sub 2} species (C{sub 2}H{sub 2},CHCO,CH{sub 2}CHO) are the main products on Rh/γ-Al{sub 2}O{sub 3} catalyst. • γ-Al{sub 2}O{sub 3} surface hydroxyls affect the selectivity of C{sub 2} species over Rh/γ-Al{sub 2}O{sub 3} catalyst. - Abstract: The supported Rh-based catalysts exhibit the excellent catalytic performances for syngas conversion to C{sub 2} species. In this study, all possible elementary steps leading to C{sub 2} species from syngas have been explored to identify the role of support and its surface hydroxyls over Rh/γ-Al{sub 2}O{sub 3} catalyst; Here, the results are obtained using density functional theory (DFT) method. Two models: Rh4 cluster supported on the dry γ-Al{sub 2}O{sub 3}(110) surface, D(Rh4), and on the hydroxylated γ-Al{sub 2}O{sub 3}(110) surface, H(Rh4), have been used to model Rh/γ-Al{sub 2}O{sub 3} catalyst. Our results show that CO prefers to be hydrogenated to CHO, subsequently, starting from CHO species, CH and CH{sub 2} species are the dominate monomers among CH{sub x}(x = 1–3) species rather than CH{sub 3} and CH{sub 3}OH on D(Rh4) and H(Rh4) surfaces, suggesting that γ-Al{sub 2}O{sub 3}-supported Rh catalyst exhibits the high selectivity towards CH{sub x} formation compared to the pure Rh catalyst. On the other hand, D(Rh4) is more favorable for C{sub 2} hydrocarbon (C{sub 2}H{sub 2}) formation, whereas H(Rh4) surface easily produces C{sub 2} hydrocarbon (C{sub 2}H{sub 2}) and C{sub 2} oxygenates (CHCO,CH{sub 2}CHO), indicating that the surface hydroxyls of support can affect the selectivity of C{sub 2} species over Rh/γ-Al{sub 2}O{sub 3} catalyst in syngas conversion. Moreover, compared to the pure Rh(111) surface, Rh/γ-Al{sub 2}O{sub 3} catalyst can achieve the

  18. Fine structure of the electromagnetic fields formed by backward surface waves in an azimuthally symmetric surface wave-excited plasma source

    International Nuclear Information System (INIS)

    Kousaka, Hiroyuki; Ono, Kouichi

    2003-01-01

    The electromagnetic fields and plasma parameters have been studied in an azimuthally symmetric surface wave-excited plasma (SWP) source, by using a two-dimensional numerical analysis based on the finite-difference time-domain (FDTD) approximation to Maxwell's equations self-consistently coupled with a fluid model for plasma evolution. The FDTD/fluid hybrid simulation was performed for different gas pressures in Ar and different microwave powers at 2.45 GHz, showing that the surface waves (SWs) occur along the plasma-dielectric interfaces to sustain overdense plasmas. The numerical results indicated that the electromagnetic SWs consist of two different waves, Wave-1 and Wave-2, having relatively shorter and longer wavelengths. The Wave-1 was seen to fade away with increasing pressure and increasing power, while the Wave-2 remained relatively unchanged over the range of pressure and power investigated. The numerical results revealed that the Wave-1 propagates as backward SWs whose phase velocity and group velocity point in the opposite directions. In contrast, the Wave-2 appeared to form standing waves, being ascribed to a superposition of forward SWs whose phase and group velocities point in the same direction. The fadeaway of the Wave-1 or backward SWs at increased pressures and increased powers was seen with the damping rate increasing in the axial direction, being related to the increased plasma electron densities. A comparison with the conventional FDTD simulation indicated that such fine structure of the electromagnetic fields of SWs is not observed in the FDTD simulation with spatially uniform and time-independent plasma distributions; thus, the FDTD/fluid hybrid model should be employed in simulating the electromagnetic fields and plasma parameters in SWPs with high accuracy

  19. Single-exposure two-dimensional superresolution in digital holography using a vertical cavity surface-emitting laser source array.

    Science.gov (United States)

    Granero, Luis; Zalevsky, Zeev; Micó, Vicente

    2011-04-01

    We present a new implementation capable of producing two-dimensional (2D) superresolution (SR) imaging in a single exposure by aperture synthesis in digital lensless Fourier holography when using angular multiplexing provided by a vertical cavity surface-emitting laser source array. The system performs the recording in a single CCD snapshot of a multiplexed hologram coming from the incoherent addition of multiple subholograms, where each contains information about a different 2D spatial frequency band of the object's spectrum. Thus, a set of nonoverlapping bandpass images of the input object can be recovered by Fourier transformation (FT) of the multiplexed hologram. The SR is obtained by coherent addition of the information contained in each bandpass image while generating an enlarged synthetic aperture. Experimental results demonstrate improvement in resolution and image quality.

  20. Quantifying Sources, Sinks and Gas-surface Interactions on the Moon from LADEE Measurements of Exospheric Na and K

    Science.gov (United States)

    Colaprete, A.; Sarantos, M.; Poppe, A. R.; Bennett, C.; Orlando, T. M.

    2015-12-01

    We present numerical simulations of the generation and loss of the sodium (Na) and potassium (K) exospheres of the Moon and compare these results to recent LADEE observations. While both species appear to migrate towards the poles like other volatiles, Na resides on the soil and exosphere for one to two months before getting lost to the solar wind or the subsurface. K exhibits a different evolutionary trend: it is lost much more quickly than ionization and sputtering rates allow for, suggesting that it is lost to the ground in just a few bounces. Thus, the two alkalis exhibit very different interactions with the lunar surface. Reproducing the monthly variation exhibited by Na requires higher source rates at Mare, or higher sink rates at Highlands, or a combination of both. The very different behavior of Na on Mare and Highlands soils is reminiscent of laboratory experiments of water binding on Apollo fine soils.

  1. Mitigation technologies for damage induced by pressure waves in high-power mercury spallation neutron sources (1). Material surface improvement

    International Nuclear Information System (INIS)

    Naoe, Takashi; Futakawa, Masatoshi; Wakui, Takashi; Kogawa, Hiroyuki; Shoubu, Takahisa; Takeuchi, Hirotsugu; Kawai, Masayoshi

    2008-01-01

    Liquid-mercury target systems for MW-class spallation neutron sources are being developed in the world. Proton beams will be used to induce the spallation reaction. At the moment the proton beam hits the target, pressure waves are generated in the mercury because of the abrupt heat deposition. The pressure waves interact with the target vessel leading to negative pressure that may cause cavitation along the vessel wall. Localized impacts by microjets and/or shock waves that are caused by cavitation bubble collapse impose pitting damage on the vessel wall. Bubble collapse behavior was observed by using a high-speed video camera, as well as simulated numerically. Localized impact due to cavitation bubble collapse was quantitatively estimated through comparison between numerical simulation and experiment. A novel surface treatment technique that consists of carburizing and nitriding processes was developed and the treatment condition was optimized to mitigate the pitting damage due to localized impacts. (author)

  2. Anti-solvent surface engineering via diethyl ether to enhance the photovoltaic conversion efficiency of perovskite solar cells to 18.76%

    Science.gov (United States)

    Gao, Yanbo; Yang, Lili; Wang, Fengyou; Sui, Yingrui; Sun, Yunfei; Wei, Maobin; Cao, Jian; Liu, Huilian

    2018-01-01

    A quick and repeatable fabrication of compact CH3NH3PbI3 film was achieved by the anti-solvent method which consists of the one-step deposition to the CH3NH3PbI3 film and quickly exposition to the anti-solvent of diethyl ether. The morphology, crystalline quality and properties of the CH3NH3PbI3 film were found to be extraordinary influenced by the adding amount of diethyl ether. Accordingly, the native relationship between the crystal quality of perovskite films and solar cells was revealed. The CH3NH3PbI3 film by adding optimized 600 μL diethyl ether delivered the best power conversion efficiency (PCE) of 18.76% and average PCE of 18.41% with remarkable reproducibility. These results provide an approach to fabricate the high-quality perovskite film and encourage the researchers to further improve the PCE of perovskite solar cells from the aspect of the fabrication process.

  3. Source contribution analysis of surface particulate polycyclic aromatic hydrocarbon concentrations in northeastern Asia by source–receptor relationships

    International Nuclear Information System (INIS)

    Inomata, Yayoi; Kajino, Mizuo; Sato, Keiichi; Ohara, Toshimasa; Kurokawa, Jun-ichi; Ueda, Hiromasa; Tang, Ning; Hayakawa, Kazuichi; Ohizumi, Tsuyoshi; Akimoto, Hajime

    2013-01-01

    We analyzed the source–receptor relationships for particulate polycyclic aromatic hydrocarbon (PAH) concentrations in northeastern Asia using an aerosol chemical transport model. The model successfully simulated the observed concentrations. In Beijing (China) benzo[a]pyren (BaP) concentrations are due to emissions from its own domain. In Noto, Oki and Tsushima (Japan), transboundary transport from northern China (>40°N, 40–60%) and central China (30–40°N, 10–40%) largely influences BaP concentrations from winter to spring, whereas the relative contribution from central China is dominant (90%) in Hedo. In the summer, the contribution from Japanese domestic sources increases (40–80%) at the 4 sites. Contributions from Japan and Russia are additional source of BaP over the northwestern Pacific Ocean in summer. The contribution rates for the concentrations from each domain are different among PAH species depending on their particulate phase oxidation rates. Reaction with O 3 on particulate surfaces may be an important component of the PAH oxidation processes. -- Highlights: •Source–receptor analysis was conducted for investigating PAHs in northeast Asia. •In winter, transboundary transport from China is large contribution in leeward. •Relative contribution from Korea, Japan, and eastern Russia is increased in summer. •This seasonal variation is strongly controlled by the meteorological conditions. •The transport distance is different among PAH species. -- Transboundary transport of PAHs in northeast Asia was investigated by source–receptor analysis

  4. Occurrence and sources of natural and anthropogenic lipid tracers in surface soils from arid urban areas of Saudi Arabia

    International Nuclear Information System (INIS)

    Rushdi, Ahmed I.; Al-Mutlaq, Khalid F.; El-Mubarak, Aarif H.; Al-Saleh, Mohammed A.; El-Otaibi, Mubarak T.; Ibrahim, Sami M.M.; Simoneit, Bernd R.T.

    2016-01-01

    Soil particles contain a variety of natural and anthropogenic organic components, and in urban areas can be considered as local collectors of pollutants. Surface soil samples were taken from ten urban areas in Riyadh during early winter of 2007. They were extracted with dichloromethane-methanol mixture and the extracts were analyzed by gas chromatography-mass spectrometry. The major compounds were unresolved complex mixture (UCM), plasticizers, n-alkanes, carbohydrates, n-alkanoic acids, hopanes, n-alkanols, and sterols. Vegetation detritus was the major natural source of organic compounds (24.0 ± 15.7%) in samples from areas with less human activities and included n-alkanes, n-alkanoic acids, n-alkanols, sterols and carbohydrates. Vehicular emission products and discarded plastics were the major anthropogenic sources in the soil particles (53.3 ± 21.3% and 22.7 ± 10.7%, respectively). The anthropogenic tracers were UCM, plasticizers, n-alkanes, hopanes and traces of steranes. Vegetation and human activities control the occurrence and distribution of natural and anthropogenic extractable organic matter in this arid urban area. - Highlights: • Human activities influence the distribution of EOM in soils of urban arid regions. • Petroleum residues and plastics are the dominant anthropogenic input. • Low soil organic matter and moisture limit microbial/fungal alteration. - This work shows that human activities are critical factors that influence the characteristics and distribution of EOM in soils of arid urban regions.

  5. Occurrence and sources of natural and anthropogenic lipid tracers in surface soils from arid urban areas of Saudi Arabia.

    Science.gov (United States)

    Rushdi, Ahmed I; Al-Mutlaq, Khalid F; El-Mubarak, Aarif H; Al-Saleh, Mohammed A; El-Otaibi, Mubarak T; Ibrahim, Sami M M; Simoneit, Bernd R T

    2016-01-01

    Soil particles contain a variety of natural and anthropogenic organic components, and in urban areas can be considered as local collectors of pollutants. Surface soil samples were taken from ten urban areas in Riyadh during early winter of 2007. They were extracted with dichloromethane-methanol mixture and the extracts were analyzed by gas chromatography-mass spectrometry. The major compounds were unresolved complex mixture (UCM), plasticizers, n-alkanes, carbohydrates, n-alkanoic acids, hopanes, n-alkanols, and sterols. Vegetation detritus was the major natural source of organic compounds (24.0 ± 15.7%) in samples from areas with less human activities and included n-alkanes, n-alkanoic acids, n-alkanols, sterols and carbohydrates. Vehicular emission products and discarded plastics were the major anthropogenic sources in the soil particles (53.3 ± 21.3% and 22.7 ± 10.7%, respectively). The anthropogenic tracers were UCM, plasticizers, n-alkanes, hopanes and traces of steranes. Vegetation and human activities control the occurrence and distribution of natural and anthropogenic extractable organic matter in this arid urban area. Copyright © 2015 Elsevier Ltd. All rights reserved.

  6. Quality characterization and pollution source identification of surface water using multivariate statistical techniques, Nalagarh Valley, Himachal Pradesh, India

    Science.gov (United States)

    Herojeet, Rajkumar; Rishi, Madhuri S.; Lata, Renu; Dolma, Konchok

    2017-09-01

    Sirsa River flows through the central part of the Nalagarh valley, belongs to the rapid industrial belt of Baddi, Barotiwala and Nalagarh (BBN). The appraisal of surface water quality to ascertain its utility in such ecologically sensitive areas is need of the hour. The present study envisages the application of multivariate analysis, water utility class and conventional graphical representation to reveal the hidden factor responsible for deterioration of water quality and determine the hydrochemical facies and its evolution processes of water types in Nalagarh valley, India. The quality assessment is made by estimating pH, electrical conductivity (EC), total dissolved solids (TDS), total hardness, major ions (Na+, K+, Ca2+, Mg2+, HCO3 -, Cl-, SO4 2-, NO3 - and PO4 3-), dissolved oxygen (DO), biological oxygen demand (BOD) and total coliform (TC) to determine its suitability for drinking and domestic purposes. The parameters like pH, TDS, TH, Ca2+, HCO3 -, Cl-, SO4 2-, NO3 - are within the desirable limit as per Bureau of Indian Standards (Indian Standard Drinking Water Specification (Second Edition) IS:10500. Indian Standard Institute, New Delhi, pp 1-18, 2012). Mg2+, Na+ and K+ ions for pre monsoon and EC during pre and post monsoon at few sites and approx 40% samples of BOD and TC for both seasons exceeds the permissible limits indicate organic contamination from human activities. Water quality classification for designated use indicates that maximum surface water samples are not suitable for drinking water source without conventional treatment. The result of piper trillinear and Chadha's diagram classified majority of surface water samples for both seasons fall in the fields of Ca2+-Mg2+-HCO3 - water type indicating temporary hardness. PCA and CA reveal that the surface water chemistry is influenced by natural factors such as weathering of minerals, ion exchange processes and anthropogenic factors. Thus, the present paper illustrates the importance of

  7. Spatial distribution of heavy metals in the surface soil of source-control stormwater infiltration devices - Inter-site comparison.

    Science.gov (United States)

    Tedoldi, Damien; Chebbo, Ghassan; Pierlot, Daniel; Branchu, Philippe; Kovacs, Yves; Gromaire, Marie-Christine

    2017-02-01

    Stormwater runoff infiltration brings about some concerns regarding its potential impact on both soil and groundwater quality; besides, the fate of contaminants in source-control devices somewhat suffers from a lack of documentation. The present study was dedicated to assessing the spatial distribution of three heavy metals (copper, lead, zinc) in the surface soil of ten small-scale infiltration facilities, along with several physical parameters (soil moisture, volatile matter, variable thickness of the upper horizon). High-resolution samplings and in-situ measurements were undertaken, followed by X-ray fluorescence analyses and spatial interpolation. Highest metal accumulation was found in a relatively narrow area near the water inflow zone, from which concentrations markedly decreased with increasing distance. Maximum enrichment ratios amounted to >20 in the most contaminated sites. Heavy metal patterns give a time-integrated vision of the non-uniform infiltration fluxes, sedimentation processes and surface flow pathways within the devices. This element indicates that the lateral extent of contamination is mainly controlled by hydraulics. The evidenced spatial structure of soil concentrations restricts the area where remediation measures would be necessary in these systems, and suggests possible optimization of their hydraulic functioning towards an easier maintenance. Heterogeneous upper boundary conditions should be taken into account when studying the fate of micropollutants in infiltration facilities with either mathematical modeling or soil coring field surveys. Copyright © 2016 Elsevier B.V. All rights reserved.

  8. Ecological risk, source and preliminary assessment of metals in the surface sediments of Chabahar Bay, Oman Sea

    International Nuclear Information System (INIS)

    Agah, Homira; Saleh, Abolfazl; Bastami, Kazem Darvish; Fumani, Neda Sheijooni

    2016-01-01

    In this study, concentrations of Aluminum (Al), Iron (Fe), Chromium (Cr), Copper (Cu), Nickel (Ni), Vanadium (V), Zinc (Zn), Arsenic (As), Cobalt (Co) and lead (Pb) in the surface sediments from Chabahar Bay were studied to assess the degree of heavy metal pollution as a consequence of natural and anthropogenic sources. Metal contents in the sediments were observed in the order of: Al > Fe > Cr > V > Ni > Zn > Cu > > As > Pb > Co. According to enrichment factor (EF), Arsenic was higher than 1.5 at some sites, indicating anthropogenic inputs. Contents of Ni, As and Cr in the some sampling sites were higher than sediment quality guideline implying adverse impacts of these metals. Based on potential ecological risk (PER), the Chabahar Bay had low ecological risk. - Highlights: •Metals and major elements were determined in surface sediments from Chabahar Bay, Oman Sea. •EF values indicated non-enriched to moderate-enriched. •Ni, As and Cr were above ERL values.

  9. Heavy metals in the surface sediments of the northern portion of the South China Sea shelf: distribution, contamination, and sources.

    Science.gov (United States)

    Xu, Fangjian; Tian, Xu; Yin, Feng; Zhao, Yongfang; Yin, Xuebo

    2016-05-01

    The concentrations of seven heavy metals (Cr, Ni, Cu, Zn, As, Cd, and Pb) in the surface sediments of the northern portion of the South China Sea (SCS) shelf collected between 2012 and 2014 were measured to assess the potential contamination levels and determine the environmental risks that are associated with heavy metals in the area. The measured concentrations in the sediments were 12.4-72.5 mg kg(-1) for Cr, 4.4-29.2 mg kg(-1) for Ni, 7.1-38.1 mg kg(-1) for Cu, 19.3-92.5 mg kg(-1) for Zn, 1.3-12.1 mg kg(-1) for As, 0.03-0.24 mg kg(-1) for Cd, and 8.5-24.4 mg kg(-1) for Pb. These results indicate that the heavy metal concentrations in the sediments generally meet the China Marine Sediment Quality criteria and suggest that the overall sediment quality of the northern portion of the SCS shelf has not been significantly impacted by heavy metal pollution. However, the enrichment factor (EF) and geoaccumulation index (I geo) clearly show that elevated concentrations of Cd occur in the region. A Pearson's correlation analysis was performed, and the results suggest that Cr, Ni, Cu, and Zn have a natural origin; Cd is primarily sourced from anthropogenic activities, with partial lithogenic components, and As and Pb may be affected by factors such as varying input sources or pathways (i.e., coal burning activities and aerosol precipitation). Heavy metal contamination mostly occurred to the east of Hainan Island, mainly because of the rapid economic and social developments in the Hainan Island. The results of this study will be useful for marine environment managers for the remediation of pollution sources.

  10. Characterization, Distribution, Sources and Origins of Aliphatic Hydrocarbons from Surface Sediment of Prai Strait, Penang, Malaysia: A Widespread Anthropogenic Input

    Directory of Open Access Journals (Sweden)

    Mahyar Sakari

    2008-07-01

    Full Text Available Persistent organic pollutants such as petroleum hydrocarbons are one of the most serious and important class of pollutants that face to many countries including Malaysia. Aliphatic hydrocarbons contain straight chain alkane; derive from anthropogenic and natural sources to the marine environment. The multi-purpose strait of Prai is located in the Northwest of Peninsular Malaysia plays an important economic role in the Southeast Asia. Twenty surface sediment samples were collected using Eckman dredge to measure the concentration and determine the characterization, sources and origins of the aliphatic hydrocarbons in December 2006. Samples (top 4 cm were extracted with Soxhlet, treated with activated copper and subjected to 2 steps column chromatography for purification and fractionation. Alkane fraction injected into Gas Chromatography–Flame Ionization Detector (GC-FID for instrumental analysis. The results showed that total n-alkane concentrations are ranging from 512 to 10770 ng/mg d. w. Carbon Preferences Index (CPI revealed an extreme widespread anthropogenic input and naturally derived (CPI= 0 to 4.88 hydrocarbons in the study area. The ratio of C31/C19 indicated that natural hydrocarbons are generating from terrestrial vascular plants and transferring by rivers. The characteristics of Major Hydrocarbons provided evidences that oil and its derivatives either fresh or degraded are the major contributors of the pollution in the study area. Statistical approaches also confirmed that 85% of study area affected by oil sources of pollution. It is seen that aliphatic hydrocarbons mostly transfer by lateral input to the marine environment than atmospheric movements.

  11. 224Ra distribution in surface and deep water of Long Island Sound: sources and horizontal transport rates

    International Nuclear Information System (INIS)

    Torgersen, T.; O'Donnell, J.; DeAngelo, E.; Turekian, K.K.; Turekian, V.C.; Tanaka, N.

    1997-01-01

    Measurements of surface water and deep water 224 Ra(half-life 3.64 days) distributions in Long Island Sound (LIS) were conducted in July 1991. Because the pycnocline structure of LIS had been in place for about 50 days in July (long compared to the half-life of 224 Ra) in the surface water and the deep water operate as separate systems. In the surface water, the fine-grain sediments of nearshore and saltmarsh environments provide a strong source of 224 Ra, which is horizontally mixed away from the short to central LIS. A one-dimensional model of 224 Ra distribution suggests a cross-LIS horizontal eddy dispersivity of 5-50 m 2 s -1 . In the deep water, the mid-LIS sediment flux of 224 Ra is enhanced by ∼ 2x relative to the periphery, and the horizontal eddy flux is from central LIS to the periphery. A second one-dimensional model suggests a cross-LIS horizontal eddy dispersivity below the thermocline of 5-50 m 2 -1 . 224 Ra fluxes into the deep water of the central LIS are likely enhanced by (1) inhomogeneous sediment or (2) a reduced scavenging of 224 Ra in the sediments of central LIS brought about by low oxygen conditions (hypoxia) and the loss of the MnO 2 scavenging layer in the sediments. These rates of horizontal eddy dispersivity are significantly less than the estimate of 100-650 m 2 s -1 (Riley, 1967) but are consistent with the transport necessary to explain the dynamics of oxygen depletion in summer LIS. These results demonstrate the use of 224 Ra for quantifying the parameters needed to describe estuarine mixing and transport. (Author)

  12. Facile formation of 2D Co2P@Co3O4 microsheets through in-situ toptactic conversion and surface corrosion: Bifunctional electrocatalysts towards overall water splitting

    Science.gov (United States)

    Yao, Lihua; Zhang, Nan; Wang, Yin; Ni, Yuanman; Yan, Dongpeng; Hu, Changwen

    2018-01-01

    Exploring efficient non-precious electrocatalysts for both the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) is crucial for many renewable energy conversion processes. In this work, we report that 2D Co2P@Co3O4 microsheets can be prepared through an in-situ toptactic conversion from single-crystal β-Co(OH)2 microplatelets, associated with a surface phosphatization and corrosion process. The resultant Co2P@Co3O4 2D hybrid materials can further serve as self-supported bifunctional catalytic electrodes to drive the overall water splitting for HER and OER simultaneously, with low overpotentials and high long-term stability. Furthermore, a water electrolyzer based on Co2P@Co3O4 hybrid as both anode and cathode is fabricated, which achieves 10 mA cm-2 current at only 1.57 V during water splitting process. Therefore, this work provides a facile strategy to obtain 2D Co2P-based micro/nanostructures, which act as low-cost and highly active electrocatalysts towards overall water splitting application.

  13. Identification of Major Risk Sources for Surface Water Pollution by Risk Indexes (RI) in the Multi-Provincial Boundary Region of the Taihu Basin, China

    Science.gov (United States)

    Yao, Hong; Li, Weixin; Qian, Xin

    2015-01-01

    Environmental safety in multi-district boundary regions has been one of the focuses in China and is mentioned many times in the Environmental Protection Act of 2014. Five types were categorized concerning the risk sources for surface water pollution in the multi-provincial boundary region of the Taihu basin: production enterprises, waste disposal sites, chemical storage sites, agricultural non-point sources and waterway transportations. Considering the hazard of risk sources, the purification property of environmental medium and the vulnerability of risk receptors, 52 specific attributes on the risk levels of each type of risk source were screened out. Continuous piecewise linear function model, expert consultation method and fuzzy integral model were used to calculate the integrated risk indexes (RI) to characterize the risk levels of pollution sources. In the studied area, 2716 pollution sources were characterized by RI values. There were 56 high-risk sources screened out as major risk sources, accounting for about 2% of the total. The numbers of sources with high-moderate, moderate, moderate-low and low pollution risk were 376, 1059, 101 and 1124, respectively, accounting for 14%, 38%, 5% and 41% of the total. The procedure proposed could be included in the integrated risk management systems of the multi-district boundary region of the Taihu basin. It could help decision makers to identify major risk sources in the risk prevention and reduction of surface water pollution. PMID:26308032

  14. Identification of Major Risk Sources for Surface Water Pollution by Risk Indexes (RI) in the Multi-Provincial Boundary Region of the Taihu Basin, China.

    Science.gov (United States)

    Yao, Hong; Li, Weixin; Qian, Xin

    2015-08-21

    Environmental safety in multi-district boundary regions has been one of the focuses in China and is mentioned many times in the Environmental Protection Act of 2014. Five types were categorized concerning the risk sources for surface water pollution in the multi-provincial boundary region of the Taihu basin: production enterprises, waste disposal sites, chemical storage sites, agricultural non-point sources and waterway transportations. Considering the hazard of risk sources, the purification property of environmental medium and the vulnerability of risk receptors, 52 specific attributes on the risk levels of each type of risk source were screened out. Continuous piecewise linear function model, expert consultation method and fuzzy integral model were used to calculate the integrated risk indexes (RI) to characterize the risk levels of pollution sources. In the studied area, 2716 pollution sources were characterized by RI values. There were 56 high-risk sources screened out as major risk sources, accounting for about 2% of the total. The numbers of sources with high-moderate, moderate, moderate-low and low pollution risk were 376, 1059, 101 and 1124, respectively, accounting for 14%, 38%, 5% and 41% of the total. The procedure proposed could be included in the integrated risk management systems of the multi-district boundary region of the Taihu basin. It could help decision makers to identify major risk sources in the risk prevention and reduction of surface water pollution.

  15. Identification of Major Risk Sources for Surface Water Pollution by Risk Indexes (RI in the Multi-Provincial Boundary Region of the Taihu Basin, China

    Directory of Open Access Journals (Sweden)

    Hong Yao

    2015-08-01

    Full Text Available Environmental safety in multi-district boundary regions has been one of the focuses in China and is mentioned many times in the Environmental Protection Act of 2014. Five types were categorized concerning the risk sources for surface water pollution in the multi-provincial boundary region of the Taihu basin: production enterprises, waste disposal sites, chemical storage sites, agricultural non-point sources and waterway transportations. Considering the hazard of risk sources, the purification property of environmental medium and the vulnerability of risk receptors, 52 specific attributes on the risk levels of each type of risk source were screened out. Continuous piecewise linear function model, expert consultation method and fuzzy integral model were used to calculate the integrated risk indexes (RI to characterize the risk levels of pollution sources. In the studied area, 2716 pollution sources were characterized by RI values. There were 56 high-risk sources screened out as major risk sources, accounting for about 2% of the total. The numbers of sources with high-moderate, moderate, moderate-low and low pollution risk were 376, 1059, 101 and 1124, respectively, accounting for 14%, 38%, 5% and 41% of the total. The procedure proposed could be included in the integrated risk management systems of the multi-district boundary region of the Taihu basin. It could help decision makers to identify major risk sources in the risk prevention and reduction of surface water pollution.

  16. Skin dose estimation for various beam modifiers and source-to-surface distances for 6MV photons

    Directory of Open Access Journals (Sweden)

    Yadav Girigesh

    2009-01-01

    Full Text Available The purpose of this study was to learn the skin dose estimation for various beam modifiers at various source-to-surface distances (SSDs for a 6 MV photon. Surface and buildup region doses were measured with an acrylic slab phantom and Markus 0.055 cc parallel plate (PP ionization chamber. Measurements were carried out for open fields, motorized wedge fields, acrylic block tray fields ranging from 3 x 3 cm 2 to 30 x 30 cm 2 . Twenty-five percent of the field was blocked with a cerrobend block and a Multileaf collimator (MLC. The effect of the blocks on the skin dose was measured for a 20 x 20 cm 2 field size, at 80 cm, 100 cm and 120 cm SSD. During the use of isocentric treatments, whereby the tumor is positioned at 100 cm from the source, depending on the depth of the tumor and size of the patient, the SSD can vary from 80 cm to 100 cm. To achieve a larger field size, the SSD can also be extended up to 120 cm at times. The skin dose increased as field size increased. The skin dose for the open 10 x10 cm 2 field was 15.5%, 14.8% and 15.5% at 80 cm, 100 cm and 120 cm SSDs, respectively. The skin dose due to a motorized 60 0 wedge for the 10 x 10 cm 2 field was 9.9%, 9.5%, and 9.5% at 80 cm, 100 cm and 120 cm SSDs. The skin dose due to acrylic block tray, of thickness 1.0 cm for a 10 x 10 cm 2 field was 27.0%, 17.2% and 16.1% at 80, 100 and 120 cm SSD respectively. Due to the use of an acrylic block tray, the surface dose was increased for all field sizes at the above three SSDs and the percentage skin dose was more dominant at the lower SSD and larger field size. The skin dose for a 30 x 30 cm 2 field size at 80 cm SSD was 38.3% and it was 70.4% for the open and acrylic block tray fields, respectively. The skin doses for motorized wedge fields were lower than for open fields. The effect of SSDs on the surface dose for motorized 60° wedge fields was not significant for a small field size (difference was less than 1% up to a 15 x 15 cm 2 field size

  17. Energy conversion and utilization technologies

    International Nuclear Information System (INIS)

    1988-01-01

    The DOE Energy Conversion and Utilization Technologies (ECUT) Program continues its efforts to expand the generic knowledge base in emerging technological areas that support energy conservation initiatives by both the DOE end-use sector programs and US private industry. ECUT addresses specific problems associated with the efficiency limits and capabilities to use alternative fuels in energy conversion and end-use. Research is aimed at understanding and improving techniques, processes, and materials that push the thermodynamic efficiency of energy conversion and usage beyond the state of the art. Research programs cover the following areas: combustion, thermal sciences, materials, catalysis and biocatalysis, and tribology. Six sections describe the status of direct contact heat exchange; the ECUT biocatalysis project; a computerized tribology information system; ceramic surface modification; simulation of internal combustion engine processes; and materials-by-design. These six sections have been indexed separately for inclusion on the database. (CK)

  18. Conversion of biomass into energy source

    International Nuclear Information System (INIS)

    Antonescu, S.; Garjoaba, M.; Antonescu, A.

    2005-01-01

    This study assists the identification of possible application and markets of the CHP-plants in the NAS states, and forms the first part of a detailed study on economical and ecological prospects of small scale and large heat pipe reformers in NAS. It is well known that the energy strategy of the European Union, foresees the increase of the participation of the renewable energy from the total of the energy resources of the European Union, up to 12% in 2010. This participation is of a great importance for the adequate reduction of green house effect gases. From the energy production point of view it is proven the fact that in 2010 the production of renewable energy will be: electricity - 675 tWh; heat - 80 Mtoe (930 TWh). From the above mentioned energy demand, the biomass will cover: electricity - 230 TWh-34,1%; heat - 75 Mtoe (93,8%)

  19. Surface Reduced CeO2 Nanowires for Direct Conversion of CO2 and Methanol to Dimethyl Carbonate: Catalytic Performance and Role of Oxygen Vacancy

    Directory of Open Access Journals (Sweden)

    Zhongwei Fu

    2018-04-01

    Full Text Available Ultralong 1D CeO2 nanowires were synthesized via an advanced solvothermal method, surface reduced under H2 atmosphere, and first applied in direct synthesis of dimethyl carbonate (DMC from CO2 and CH3OH. The micro morphologies, physical parameters of nanowires were fully investigated by transmission electron microscopy (TEM, X-ray diffraction (XRD, N2 adsorption, X-ray photoelectron spectrum (XPS, and temperature-programmed desorption of ammonia/carbon dioxide (NH3-TPD/CO2-TPD. The effects of surface oxygen vacancy and acidic/alkaline sites on the catalytic activity was explored. After reduction, the acidic/alkaline sites of CeO2 nanowires can be dramatically improved and evidently raised the catalytic performance. CeO2 nanowires reduced at 500 °C (CeO2_NW_500 exhibited notably superior activity with DMC yield of 16.85 mmol gcat−1. Furthermore, kinetic insights of initial rate were carried out and the apparent activation energy barrier of CeO2_NW_500 catalyst was found to be 41.9 kJ/mol, much tiny than that of CeO2_NW catalyst (74.7 KJ/mol.

  20. Facile conversion of bulk metal surface to metal oxide single-crystalline nanostructures by microwave irradiation: Formation of pure or Cr-doped hematite nanostructure arrays

    International Nuclear Information System (INIS)

    Cho, Seungho; Jeong, Haeyoon; Lee, Kun-Hong

    2010-01-01

    We report a method for converting the surfaces of bulk metal substrates (pure iron or stainless steel) to metal oxide (hematite or Cr-doped hematite) nanostructures using microwave irradiation. When microwave radiation (2.45 GHz, single-mode) was applied to a metal substrate under the flow of a gas mixture containing O 2 and Ar, metal oxide nanostructures formed and entirely covered the substrate. The nanostructures were single crystalline, and the atomic ratios of the substrate metals were preserved in the nanostructures. When a pure iron sheet was used as a substrate, hematite nanowires (1000 W microwave radiation) or nanosheets (1800 W microwave radiation) formed on the surface of the substrate. When a SUS410 sheet was used as a substrate, slightly curved rod-like nanostructures were synthesized. The oxidation states of Fe and Cr in these nanorods were Fe 3+ and Cr 3+ . Quantitative analyses revealed an average Fe/Cr atomic ratio of 9.2, nearly identical to the ratio of the metals in the SUS410 substrate.

  1. Evaluation of smoothing in an iterative lp-norm minimization algorithm for surface-based source localization of MEG

    Science.gov (United States)

    Han, Jooman; Sic Kim, June; Chung, Chun Kee; Park, Kwang Suk

    2007-08-01

    The imaging of neural sources of magnetoencephalographic data based on distributed source models requires additional constraints on the source distribution in order to overcome ill-posedness and obtain a plausible solution. The minimum lp norm (0 temporal gyrus.

  2. Mechanisms of Ectopic Gene Conversion

    Directory of Open Access Journals (Sweden)

    P.J. Hastings

    2010-11-01

    Full Text Available Gene conversion (conversion, the unidirectional transfer of DNA sequence information, occurs as a byproduct of recombinational repair of broken or damaged DNA molecules. Whereas excision repair processes replace damaged DNA by copying the complementary sequence from the undamaged strand of duplex DNA, recombinational mechanisms copy similar sequence, usually in another molecule, to replace the damaged sequence. In mitotic cells the other molecule is usually a sister chromatid, and the repair does not lead to genetic change. Less often a homologous chromosome or homologous sequence in an ectopic position is used. Conversion results from repair in two ways. First, if there was a double-strand gap at the site of a break, homologous sequence will be used as the template for synthesis to fill the gap, thus transferring sequence information in both strands. Second, recombinational repair uses complementary base pairing, and the heteroduplex molecule so formed is a source of conversion, both as heteroduplex and when donor (undamaged template information is retained after correction of mismatched bases in heteroduplex. There are mechanisms that favour the use of sister molecules that must fail before ectopic homology can be used. Meiotic recombination events lead to the formation of crossovers required in meiosis for orderly segregation of pairs of homologous chromosomes. These events result from recombinational repair of programmed double-strand breaks, but in contrast with mitotic recombination, meiotic recombinational events occur predominantly between homologous chromosomes, so that transfer of sequence differences by conversion is very frequent. Transient recombination events that do not form crossovers form both between homologous chromosomes and between regions of ectopic homology, and leave their mark in the occurrence of frequent non-crossover conversion, including ectopic conversion.

  3. Iodine budget in surface waters from Atacama: Natural and anthropogenic iodine sources revealed by halogen geochemistry and iodine-129 isotopes

    International Nuclear Information System (INIS)

    Álvarez, Fernanda; Reich, Martin; Snyder, Glen; Pérez-Fodich, Alida; Muramatsu, Yasuyuki; Daniele, Linda; Fehn, Udo

    2016-01-01

    Iodine enrichment in the Atacama Desert of northern Chile is widespread and varies significantly between reservoirs, including nitrate-rich “caliche” soils, supergene Cu deposits and marine sedimentary rocks. Recent studies have suggested that groundwater has played a key role in the remobilization, transport and deposition of iodine in Atacama over scales of millions-of-years. However, and considering that natural waters are also anomalously enriched in iodine in the region, the relative source contributions of iodine in the waters and its extent of mixing remain unconstrained. In this study we provide new halogen data and isotopic ratios of iodine ("1"2"9I/I) in shallow seawater, rivers, salt lakes, cold and thermal spring water, rainwater and groundwater that help to constrain the relative influence of meteoric, marine and crustal sources in the Atacama waters. Iodine concentrations in surface and ground waters range between 0.35 μM and 26 μM in the Tarapacá region and between 0.25 μM and 48 μM in the Antofagasta region, and show strong enrichment when compared with seawater concentrations (I = ∼0.4 μM). In contrast, no bromine enrichment is detected (1.3–45.7 μM for Tarapacá and 1.7–87.4 μM for Antofagasta) relative to seawater (Br = ∼600 μM). These data, coupled to the high I/Cl and low Br/Cl ratios are indicative of an organic-rich sedimentary source (related with an “initial” fluid) that interacted with meteoric water to produce a mixed fluid, and preclude an exclusively seawater origin for iodine in Atacama natural waters. Iodine isotopic ratios ("1"2"9I/I) are consistent with halogen chemistry and confirm that most of the iodine present in natural waters derives from a deep initial fluid source (i.e., groundwater which has interacted with Jurassic marine basement), with variable influence of at least one atmospheric or meteoric source. Samples with the lowest isotopic ratios ("1"2"9I/I from ∼215 to ∼1000 × 10"

  4. Assessment and potential sources of metals in the surface sediments of the Yellow River Delta, Eastern China.

    Science.gov (United States)

    Cheng, Qingli; Lou, Guangyan; Huang, Wenhai; Li, Xudong

    2017-07-01

    The Yellow River Delta is the most intact estuary wetland in China and suffers from great pressure of metals. Seventy-seven surface sediment samples were collected in the delta, and contents of Cu, Pb, Cd, Cr, Zn, Ni, and Mn were analyzed by inductively coupled plasma spectrometry and those of Hg and As by atomic fluorescence spectrometry. The results showed that means of metal contents (ppm, dry weight) were as follows: Hg, 0.04; Cr, 61.72; Cu, 20.97; Zn, 60.73; As, 9.47; Pb, 21.91; Cd, 0.12; Ni, 27.24; and Mn, 540.48. 43.8% of Hg and 14.3% of Cd were from the allogenic source while others from the authigenic source. The results of the geoaccumulation indexes appeared that 6.5% of sites from the estuarine and the Gudao areas were moderately polluted by Hg. All ecological risk index values of Hg and 37.7% of Cd were more than 40, which were the main factors of strongly and moderately potential ecological risks of 37.7% of sites in the delta. High Cd contents may be due to the alkaline conditions of the delta and the unreasonable management of the farmland, while the abnormal distribution of Hg to the wet or dry deposition and the erosion of the seawater. It was suggested to monitor Hg content in the atmosphere of the Yellow River Delta. The results were expected to update the pollution status of metals in the delta and created awareness of preserving the sound condition of the Yellow River Delta.

  5. Characterization of Dust Properties Near Source Region During ACE-Asia: A Column Satellite-Surface Perspective

    Science.gov (United States)

    Tsay, S. -C.; Ji, Q.; Chu, A.; Hsu, C.; Holben, B.; Campbell, J.; Welton, E. J.; Shu, P. K.

    2002-01-01

    Many recent field experiments are designed to study the compelling variability in spatial and temporal scale of both pollution-derived and naturally occurring aerosols, which often exist in high concentrations over eastern/southeastern Asia and along the rim of the western Pacific. For example, the ACE-Asia was conducted from March-May 2001 in the vicinity of the Taklimakan and Gobi deserts, East Coast of China, Yellow Sea, Korea, and Japan, along the pathway of Kosa (severe events that blanket East Asia with yellow desert dust, peaked in the Spring season). Asian dust typically originates in desert areas far from polluted urban regions. During transport, dust layers can interact with anthropogenic sulfate and soot aerosols from heavily polluted urban areas. Added to the complex effects of clouds and natural marine aerosols, dust particles reaching the marine environment can have drastically different properties than those from the source. Thus, understanding the unique temporal and spatial variations of Asian aerosols is of special importance in regional-to-global climate issues such as radiative forcing, the hydrological cycle, and primary biological productivity in the mid-Pacific Ocean. During ACE-Asia we have measured continuously aerosol physical/optical/radiative properties, column precipitable water amount, and surface reflectivity over homogeneous areas from surface. The inclusion of flux measurements permits the determination of aerosol radiative flux in addition to measurements of loading and optical depth. At the time of the Terra/MODIS, SeaWiFS, TOMS and other satellite overpasses, these ground-based observations can provide valuable data to compare with satellite retrievals over land. Preliminary results will be presented and discussed their implications in regional climatic effects.

  6. Special issue: Plasma Conversion

    NARCIS (Netherlands)

    Nozaki, T.; Bogaerts, A.; Tu, X.; van de Sanden, M. C. M.

    2017-01-01

    With growing concern of energy and environmental issues, the combination of plasma and heterogeneous catalysts receives special attention in greenhouse gas conversion, nitrogen fixation and hydrocarbon chemistry. Plasma gas conversion driven by renewable electricity is particularly important for the

  7. Identification of a time-varying point source in a system of two coupled linear diffusion-advection- reaction equations: application to surface water pollution

    International Nuclear Information System (INIS)

    Hamdi, Adel

    2009-01-01

    This paper deals with the identification of a point source (localization of its position and recovering the history of its time-varying intensity function) that constitutes the right-hand side of the first equation in a system of two coupled 1D linear transport equations. Assuming that the source intensity function vanishes before reaching the final control time, we prove the identifiability of the sought point source from recording the state relative to the second coupled transport equation at two observation points framing the source region. Note that at least one of the two observation points should be strategic. We establish an identification method that uses these records to identify the source position as the root of a continuous and strictly monotonic function. Whereas the source intensity function is recovered using a recursive formula without any need of an iterative process. Some numerical experiments on a variant of the surface water pollution BOD–OD coupled model are presented

  8. Si(001):B gas-source molecular-beam epitaxy: Boron surface segregation and its effect on film growth kinetics

    Energy Technology Data Exchange (ETDEWEB)

    Kim, H.; Glass, G.; Spila, T.; Taylor, N.; Park, S.Y.; Abelson, J.R.; Greene, J.E. [Department of Materials Science, Coordinated Science Laboratory, and Materials Research Laboratory, University of Illinois, 1101 West Springfield, Urbana, Illinois 61801 (United States)

    1997-09-01

    B-doped Si(001) films, with concentrations C{sub B} up to 1.7{times}10{sup 22}cm{sup {minus}3}, were grown by gas-source molecular-beam epitaxy from Si{sub 2}H{sub 6} and B{sub 2}H{sub 6} at T{sub s}=500{endash}800{degree}C. D{sub 2} temperature-programed desorption (TPD) spectra were then used to determine B coverages {theta}{sub B} as a function of C{sub B} and T{sub s}. In these measurements, as-deposited films were flash heated to desorb surface hydrogen, cooled, and exposed to atomic deuterium until saturation coverage. Strong B surface segregation was observed with surface-to-bulk B concentration ratios ranging up to 1200. TPD spectra exhibited {beta}{sub 2} and {beta}{sub 1} peaks associated with dideuteride and monodeuteride desorption as well as lower-temperature B-induced peaks {beta}{sub 2}{sup {asterisk}} and {beta}{sub 1}{sup {asterisk}}. Increasing {theta}{sub B} increased the area under {beta}{sub 2}{sup {asterisk}} and {beta}{sub 1}{sup {asterisk}} at the expense of {beta}{sub 2} and {beta}{sub 1} and decreased the total D coverage {theta}{sub D}. The TPD results were used to determine the B segregation enthalpy, {minus}0.53eV, and to explain and model the effects of high B coverages on Si(001) growth kinetics. Film deposition rates R increase by {ge}50{percent} with increasing C{sub B}{tilde {gt}}1{times}10{sup 19}cm{sup {minus}3} at T{sub s}{le}550{degree}C, due primarily to increased H desorption rates from B-backbonded Si adatoms, and decrease by corresponding amounts at T{sub s}{ge}600{degree}C due to decreased adsorption site densities. At T{sub s}{ge}700{degree}C, high B coverages also induce {l_brace}113{r_brace} facetting. {copyright} {ital 1997 American Institute of Physics.}

  9. A Model for Conversation

    DEFF Research Database (Denmark)

    Ayres, Phil

    2012-01-01

    This essay discusses models. It examines what models are, the roles models perform and suggests various intentions that underlie their construction and use. It discusses how models act as a conversational partner, and how they support various forms of conversation within the conversational activity...

  10. Direct Conversion of Energy.

    Science.gov (United States)

    Corliss, William R.

    This publication is one of a series of information booklets for the general public published by the United States Atomic Energy Commission. Direct energy conversion involves energy transformation without moving parts. The concepts of direct and dynamic energy conversion plus the laws governing energy conversion are investigated. Among the topics…

  11. Aggregation of Individual Sensing Units for Signal Accumulation: Conversion of Liquid-Phase Colorimetric Assay into Enhanced Surface-Tethered Electrochemical Analysis.

    Science.gov (United States)

    Wei, Tianxiang; Dong, Tingting; Wang, Zhaoyin; Bao, Jianchun; Tu, Wenwen; Dai, Zhihui

    2015-07-22

    A novel concept is proposed for converting liquid-phase colorimetric assay into enhanced surface-tethered electrochemical analysis, which is based on the analyte-induced formation of a network architecture of metal nanoparticles (MNs). In a proof-of-concept trial, thymine-functionalized silver nanoparticle (Ag-T) is designed as the sensing unit for Hg(2+) determination. Through a specific T-Hg(2+)-T coordination, the validation system based on functionalized sensing units not only can perform well in a colorimetric Hg(2+) assay, but also can be developed into a more sensitive and stable electrochemical Hg(2+) sensor. In electrochemical analysis, the simple principle of analyte-induced aggregation of MNs can be used as a dual signal amplification strategy for significantly improving the detection sensitivity. More importantly, those numerous and diverse colorimetric assays that rely on the target-induced aggregation of MNs can be augmented to satisfy the ambitious demands of sensitive analysis by converting them into electrochemical assays via this approach.

  12. Ge(001):B gas-source molecular beam epitaxy: B surface segregation, hydrogen desorption, and film growth kinetics

    Energy Technology Data Exchange (ETDEWEB)

    Kim, H.; Greene, J.E. [Materials Science Department, the Coordinated Science Laboratory and the Materials Research Laboratory, University of Illinois, Urbana, Illinois 61801 (United States)

    1999-03-01

    Ultrahigh B-doped Ge(001) layers, with concentrations C{sub B} up to 8{times}10{sup 21} cm{sup {minus}3}, were grown by gas-source molecular beam epitaxy from Ge{sub 2}H{sub 6} and B{sub 2}H{sub 6} at temperatures T{sub s}=325{degree}C (in the surface-reaction-limited regime) and 600{degree}C (in the flux-limited regime). The samples were quenched, D site exchanged for H, and D{sub 2} temperature-programed desorption (TPD) used to determine B coverages {theta}{sub B} as a function of C{sub B} and T{sub s} by comparison with B-adsorbed Ge(001) reference samples with known {theta}{sub B} values. During Ge(001):B film growth, strong surface B segregation to the second layer was observed with surface-to-bulk B concentration ratios ranging up to 6000. The TPD spectra exhibited {alpha}{sub 2} and {alpha}{sub 1} peaks associated with dideuteride and monodeuteride desorption as well as lower-temperature B-induced {alpha}{sub 2}{sup {asterisk}} and {alpha}{sub 1}{sup {asterisk}} peaks associated with deuterium desorption from Ge{sup {asterisk}} surface atoms with B backbonds. Increasing {theta}{sub B} expanded the area under {alpha}{sub 2}{sup {asterisk}} and {alpha}{sub 1}{sup {asterisk}} at the expense of {alpha}{sub 2} and {alpha}{sub 1} and decreased the total D coverage {theta}{sub D}. The TPD results were used to determine the B segregation enthalpy, {minus}0.64 eV, and to explain and model the effects of high B coverages on Ge(001) growth kinetics. At T{sub s}=325{degree}C, where B segregation is kinetically hindered, film deposition rates R{sub Ge} are not a strong function of C{sub B}, exhibiting only a small decrease at C{sub B}{approx_gt}5{times}10{sup 18} cm{sup {minus}3}. However, at T{sub s}=600{degree}C, R{sub Ge} decreases by up to 40{percent} with increasing C{sub B}{approx_gt}1{times}10{sup 18} cm{sup {minus}3}. This is due primarily to the combination of B-induced Ge dimer vacancies and the deactivation of surface dangling bonds caused by charge transfer

  13. Unsteady MHD flow of a dusty nanofluid past a vertical stretching surface with non-uniform heat source/sink

    Directory of Open Access Journals (Sweden)

    C. Sulochana

    2016-02-01

    Full Text Available We analyzed the momentum and heat transfer characteristics of unsteady MHD flow of a dusty nanofluid over a vertical stretching surface in presence of volume fraction of dust and nano particles with non uniform heat source/sink. We considered two types of nanofluids namely Ag-water and Cu-water embedded with conducting dust particles. The governing equations are transformed in to nonlinear ordinary differential equations by using similarity transformation and solved numerically using Shooting technique. The effects of non-dimensional governing parameters on velocity and temperature profiles for fluid and dust phases are discussed and presented through graphs. Also, the skin friction coefficient and Nusselt number are discussed and presented for two dusty nanofluids separately in tabular form. Results indicate that an increase in the volume fraction of dust particles enhances the heat transfer in Cu-water nanofluid compared with Ag-water nanofluid and a raise in the volume fraction of nano particles shows uniform heat transfer in both Cu-water and Ag-water nanofluids.

  14. Response surface optimization of carbon and nitrogen sources for nuclease P1 production by Penicillium citrinum F-5-5

    International Nuclear Information System (INIS)

    Liang Xinle; Huang Yingying; Zhang Hong; Chen Min; Liu Xuan

    2011-01-01

    Penicillium citrinum F-5-5, a nuclease P1 high-producing strain with 978.6 U/ml in potato glucose medium, was derived from the original Penicillium citrinum CICC 4011 with 60 Co γ-rays irradiation mutation and then protoplasts fusion treatment. Culture components were optimized for the nuclease P1 production, and response surface methodology was applied for the critical medium components(carbon and nitrogen sources) which were preselected by Plackett-Burman design approach. Glucose, soluble starch and corn steep powder showed significant effects on production of nuclease. Central composite design was used for the optimization levels by software Minitab 15, and it showed that, the optimal values for the concentration of glucose, soluble starch and corn steep powder were 30.89, 42.46 and 11.60 g/L, respectively. With this medium,an enzyme activity of 1687.16 U/ml could be obtained theoretically. Using this optimized medium, an experimental enzyme activity of 1672.6 U/ml was reached. (authors)

  15. Photoluminescence studies of organic phosphor coated diffusing surface using blue inorganic light-emitting diode as excitation source

    International Nuclear Information System (INIS)

    Singh, Gyanendra; Mehta, Dalip Singh

    2013-01-01

    We report the studies on photoluminescence (PL) of organic phosphor coated on a diffusing surface using a blue inorganic light-emitting diode (LED) array as an excitation source. The organic phosphor composite coated diffuser was used to scatter the directional blue light from the LED array. Some of the blue light is absorbed by the organic phosphor composite and the phosphor molecules are excited and re-emit light at longer wavelengths due to the PL process. The output light consists of scattered blue light plus phosphor generated broadband yellow light, thus making white light. The diffuser was made up of a plastic substrate coated with an organic composite of small molecule fluorescent material zinc(II)bis(8-hydroxyquinoline) (Znq 2 ) doped with different percentages of electro-phosphorescent metal complex iridium(III)bis(2-methyldibenzo-[f, h] quinoxaline) (acetylacetonate) ([Ir(MDQ) 2 (acac)]). By means of changing the concentration and the thickness of the phosphor composite material the colour coordinates of white light were achieved. The CIE coordinates and correlated colour temperature were calculated for various thicknesses and phosphor composite concentrations and the results are reported. (paper)

  16. Surface-micromachined magnetic undulator with period length between 10μm and 1 mm for advanced light sources

    Science.gov (United States)

    Harrison, Jere; Joshi, Abhijeet; Lake, Jonathan; Candler, Rob; Musumeci, Pietro

    2012-07-01

    A technological gap exists between the μm-scale wiggling periods achieved using electromagnetic waves of high intensity laser pulses and the mm scale of permanent-magnet and superconducting undulators. In the sub-mm range, surface-micromachined soft-magnetic micro-electro-mechanical system inductors with integrated solenoidal coils have already experimentally demonstrated 100 to 500 mT field amplitude across air gaps as large as 15μm. Simulations indicate that magnetic fields as large as 1.5 T across 50μm inductor gaps are feasible. A simple rearranging of the yoke and pole geometry allows for fabrication of 10+ cm long undulator structures with period lengths between 12.5μm and 1 mm. Such undulators find application both in high average power spontaneous emission sources and, if used in combination with ultrahigh-brightness electron beams, could lead to the realization of low energy compact free-electron lasers. Challenges include electron energy broadening due to wakefields and Joule heating in the electromagnet.

  17. Near-source surface seismic measurements for the NPE, NPE Calibration, Hunter`s Trophy, and Mineral Quarry

    Energy Technology Data Exchange (ETDEWEB)

    Reinke, R.E.; Leverette, J.A. [Field Command Defense Nuclear Agency, Kirtland AFB, NM (United States); Stump, B.W. [Los Alamos National Laboratory, NM (United States)] [and others

    1994-12-31

    An extensive seismic network was deployed on the surface of Rainier Mesa for both the Non-Proliferation Experiment (NPE) Calibration shot as well as the full scale NPE event. This network was very similar to previous deployments for the nuclear events MISTY ECHO, MINERAL QUARRY, and HUNTERS TROPHY. For the full scale NPE event three-component accelerometers and seismometers were fielded at 32 sites across the mesa. A slightly smaller network with 28 stations was in operation for the 300 pound NPE calibration event. The mesa top array included both accelerometers and seismometers. The accelerometers were used to obtain data from the main NPE event while the seismometers with their higher sensitivity were used to record the 300 pound cal shot and several hundred after events from the NPE. Large spatial variations in ground motion are evident in both the full mesa data set as well as a small (80 m on a side) aperture, 9-element triangular array. This paper summarizes the data and discusses wave propagation effects. A companion paper presents a comparative source analysis.

  18. Distribution, sources, and risk assessment of polychlorinated biphenyls in surface waters and sediments of rivers in Shanghai, China

    Science.gov (United States)

    Wang, Xueping; Han, Jingchao; Bi, Chunjuan; Huang, Xing; Jia, Jinpu; Chen, Zhenlou

    2017-06-01

    The distribution, sources, and potential risks of polychlorinated biphenyl (PCB) contamination in the rivers of Shanghai, China were investigated. Fourteen PCB congeners in surface waters and sediments, which were collected from 53 sampling sites, were quantified by gas chromatography-mass spectrometer (GC-MS). The total concentrations of PCBs in the dissolved phase, in particulates, and in sediments ranged from not detected (nd) to 34.8 ng•L‒1, from 0.76 to 39.71 ng•L‒1, and from 1.46 to 46.11 ng•g-1 (dry weight, dw), respectively. The corresponding WHO toxic equivalents (TEQs) of dioxinlike polychlorinated biphenyls (dl-PCBs) ranged between nd-1135.63 pg TEQ•L-1, 0.02-605.94 pg TEQ•L-1, and 0.05-432.12 pg TEQ•g-1 dw, respectively. The penta-CBs, especially PCB 118 and PCB 105, were the dominant congeners in all samples. Principle Component Analysis (PCA) indicated that the PCBs were mainly influenced by a historical accumulation of commercial PCB products, the burning of house coal, and emissions from municipal solid waste incineration (MSWI) and secondary metallurgy industries. The center of Shanghai was significantly affected by PCB contamination, followed by the industrial parklands and suburban towns, while the farmland of Chongming Island was the least affected area. Adverse biological and health effects would be likely in the central urban areas, industrial parks, and residential towns of Shanghai.

  19. IMAGE CONVERSION FOR LASER PYROGRAPHY

    Directory of Open Access Journals (Sweden)

    Adrian PETRU

    2015-12-01

    Full Text Available All previous studies of pyrography have been focussed on colour obtained through modifying the work parameters. This paper analyses colour nuances obtained by laser woodworking by measuring colour changes digitally. The investigated parameter is colour reproduction by laser technology, using different image conversion methods (Halftone Round, Jarvis, and so on. The changes of image reproduction are analysed globally and colour by colour. The results show that the colour nuances are represented to a more and less degree, according to the conversion method selected. To evaluate the aesthetic changes, CIEL*a*b* colour measurements were applied. The results show that laser burning on wood surfaces has a great influence on wood colour. These findings will be useful to develop innovative design possibilities for wood surfaces for furniture and other products.

  20. A two dimensional analytical modeling of surface potential in triple metal gate (TMG) fully-depleted Recessed-Source/Drain (Re-S/D) SOI MOSFET

    Science.gov (United States)

    Priya, Anjali; Mishra, Ram Awadh

    2016-04-01

    In this paper, analytical modeling of surface potential is proposed for new Triple Metal Gate (TMG) fully depleted Recessed-Source/Dain Silicon On Insulator (SOI) Metal Oxide Semiconductor Field Effect Transistor (MOSFET). The metal with the highest work function is arranged near the source region and the lowest one near the drain. Since Recessed-Source/Drain SOI MOSFET has higher drain current as compared to conventional SOI MOSFET due to large source and drain region. The surface potential model developed by 2D Poisson's equation is verified by comparison to the simulation result of 2-dimensional ATLAS simulator. The model is compared with DMG and SMG devices and analysed for different device parameters. The ratio of metal gate length is varied to optimize the result.

  1. Study of temperature distribution of pipes heated by moving rectangular gauss distribution heat source. Development of pipe outer surface irradiated laser stress improvement process (L-SIP)

    International Nuclear Information System (INIS)

    Ohta, Takahiro; Kamo, Kazuhiko; Asada, Seiji; Terasaki, Toshio

    2009-01-01

    The new process called L-SIP (outer surface irradiated Laser Stress Improvement Process) is developed to improve the tensile residual stress of the inner surface near the butt welded joints of pipes in the compression stress. The temperature gradient occurs in the thickness of pipes in heating the outer surface rapidly by laser beam. By the thermal expansion difference between the inner surface and the outer surface, the compression stress occurs near the inner surface of pipes. In this paper, the theoretical equation for the temperature distributions of pipes heated by moving rectangular Gauss distribution heat source on the outer surface is derived. The temperature histories of pipes calculated by theoretical equation agree well with FEM analysis results. According to the theoretical equation, the controlling parameters of temperature distributions and histories are q/2a y , vh, a x /h and a y /h, where q is total heat input, a y is heat source length in the axial direction, a x is Gaussian radius of heat source in the hoop direction, ν is moving velocity, and h is thickness of the pipe. The essential variables for L-SIP, which are defined on the basis of the measured temperature histories on the outer surface of the pipe, are Tmax, F 0 =kτ 0 /h 2 , vh, W Q and L Q , where Tmax is maximum temperature on the monitor point of the outer surface, k is thermal diffusivity coefficient, τ 0 is the temperature rise time from 100degC to maximum temperature on the monitor point of the outer surface, W Q is τ 0 x ν, and L Q is the uniform temperature length in the axial direction. It is verified that the essential variables for L-SIP match the controlling parameters by the theoretical equation. (author)

  2. Analytic model of the stress waves propagation in thin wall tubes, seeking the location of a harmonic point source in its surface

    International Nuclear Information System (INIS)

    Boaratti, Mario Francisco Guerra

    2006-01-01

    Leaks in pressurized tubes generate acoustic waves that propagate through the walls of these tubes, which can be captured by accelerometers or by acoustic emission sensors. The knowledge of how these walls can vibrate, or in another way, how these acoustic waves propagate in this material is fundamental in the detection and localization process of the leak source. In this work an analytic model was implemented, through the motion equations of a cylindrical shell, with the objective to understand the behavior of the tube surface excited by a point source. Since the cylindrical surface has a closed pattern in the circumferential direction, waves that are beginning their trajectory will meet with another that has already completed the turn over the cylindrical shell, in the clockwise direction as well as in the counter clockwise direction, generating constructive and destructive interferences. After enough time of propagation, peaks and valleys in the shell surface are formed, which can be visualized through a graphic representation of the analytic solution created. The theoretical results were proven through measures accomplished in an experimental setup composed of a steel tube finished in sand box, simulating the condition of infinite tube. To determine the location of the point source on the surface, the process of inverse solution was adopted, that is to say, known the signals of the sensor disposed in the tube surface , it is determined through the theoretical model where the source that generated these signals can be. (author)

  3. Effects of Thermal Radiation and Chemical Reaction on MHD Free Convection Flow past a Flat Plate with Heat Source and Convective Surface Boundary Condition

    OpenAIRE

    E.Hemalatha; N. Bhaskar Reddy

    2015-01-01

    This paper analyzes the radiation and chemical reaction effects on MHD steady two-dimensional laminar viscous incompressible radiating boundary layer flow over a flat plate in the presence of internal heat generation and convective boundary condition. It is assumed that lower surface of the plate is in contact with a hot fluid while a stream of cold fluid flows steadily over the upper surface with a heat source that decays exponentially. The Rosseland approximation is used to desc...

  4. Autonomous renewable energy conversion system

    Energy Technology Data Exchange (ETDEWEB)

    Valtchev, V. [Technical University of Varna (Bulgaria). Dept. of Electronics; Bossche, A. van den; Ghijselen, J.; Melkebeek, J. [University of Gent (Belgium). Dept. of Electrical Power Engineering

    2000-02-01

    This paper briefly reviews the need for renewable power generation and describes a medium-power Autonomous Renewable Energy Conversion System (ARECS), integrating conversion of wind and solar energy sources. The objectives of the paper are to extract maximum power from the proposed wind energy conversion scheme and to transfer this power and the power derived by the photovoltaic system in a high efficiency way to a local isolated load. The wind energy conversion operates at variable shaft speed yielding an improved annual energy production over constant speed systems. An induction generator (IG) has been used because of its reduced cost, robustness, absence of separate DC source for excitation, easier dismounting and maintenance. The maximum energy transfer of the wind energy is assured by a simple and reliable control strategy adjusting the stator frequency of the IG so that the power drawn is equal to the peak power production of the wind turbine at any wind speed. The presented control strategy also provides an optimal efficiency operation of the IG by applying a quadratic dependence between the IG terminal voltage and frequency V {approx} f{sup 2}. For improving the total system efficiency, high efficiency converters have been designed and implemented. The modular principle of the proposed DC/DC conversion provides the possibility for modifying the system structure depending on different conditions. The configuration of the presented ARECS and the implementation of the proposed control algorithm for optimal power transfer are fully discussed. The stability and dynamic performance as well as the different operation modes of the proposed control and the operation of the converters are illustrated and verified on an experimental prototype. (author)

  5. Assessing spatial distribution, sources, and potential ecological risk of heavy metals in surface sediments of the Nansi Lake, Eastern China

    International Nuclear Information System (INIS)

    Jianshu Lv; Bin Dai; Zulu Zhang; Yuanyuan Sun; Shuang Li; Yang Liu

    2014-01-01

    The study is conducted to investigate the spatial distribution, sources and ecological risk of seven heavy metals in surface sediments of Nansi Lake, Eastern China. A total of 29 samples were collected in surface sediments of Nansi Lake, and were analyzed for three nutrients (TN, TOC and TP), two major metals (Al and Fe), as well as seven trace metals (As, Cd, Cr, Cu, Hg, Pb and Zn). The mean concentrations of As, Cd, Cr, Cu, Hg, Pb, Zn, Fe and Al were 14.41, 0.22, 71.10, 30.1, 0.048, 29.14, 90.2, 30,816 and 70,653 mg kg -1 , respectively, and the mean contents of these metals were higher than the background values with the exception of Cu and Fe. The spatial distribution indicated that the contents of all seven heavy metals were characterized by relatively higher contents in the upper lake than the lower lake. The hotspots with high values of As, Cd and Hg were associated with the river mouths, and the hotspots of Pb were mainly located around the dam in the central part, while no significant associations were displayed between spatial distribution of Cr, Cu, Zn and the river mouths. The mean enrichment factor (EF) values of As, Cd, Hg and Pb were 2.03, 2.93, 3.21 and 2.18, respectively, showing their moderate enrichment, while Cr, Cu and Zn with mean EF values of 1.19, 0.89 and 1.01 were deficiency to minimal enrichment. Multivariate and geostatistical analyses suggested that PC1 controlled by Cr, Cu and Zn was a lithogenic component, and come from parent rocks leaching. PC2 including Cd and partially Hg represented the factor from industrial wastewater discharge. PC3 showed elevated loadings of As and partially Cd, and could be attributed to the agricultural practices. While PC4 including Pb and partially Hg, was dominated by coal combustion. The results of potential ecological risk suggested that sediment environment of Nansi Lake suffered from high ecological risk. (author)

  6. SU-E-T-232: Custom High-Dose-Rate Brachytherapy Surface Mold Applicators: The Importance Source to Skin Distance

    International Nuclear Information System (INIS)

    Park, S; Demanes, J; Kamrava, M

    2015-01-01

    Purpose: Surface mold applicators can be customized to fit irregular skin surfaces that are difficult to treat with other radiation therapy techniques. Optimal design of customized HDR skin brachytherapy is not well-established. We evaluated the impact of applicator thickness (source to skin distance) on target dosimetry. Methods: 27 patients had 34 treated sites: scalp 4, face 13, extremity 13, and torso 4. Custom applicators were constructed from 5–15 mm thick thermoplastic bolus molded over the skin lesion. A planar array of plastic brachytherapy catheters spaced 5–10 mm apart was affixed to the bolus. CT simulation was used to contour the target volume and to determine the prescription depth. Inverse planning simulated annealing followed by graphical optimization was used to plan and deliver 40–56 Gy in 8–16 fractions. Target coverage parameters (D90, Dmean, and V100) and dose uniformity (V110–200, D0.1cc, D1cc, and D2cc) were studied according to target depth (<5mm vs. ≥5mm) and applicator thickness (5–10mm vs. ≥10mm). Results: The average prescription depth was 4.2±1.5mm. The average bolus thickness was 9.2±2.4mm. The median CTV volume was 10.0 cc (0.2–212.4 cc). Similar target coverage was achieved with prescription depths of <5mm and ≥5mm (Dmean = 113.8% vs. 112.4% and D90 = 100.2% vs. 98.3%). The <5mm prescription depth plans were more uniform (D0.1cc = 131.8% vs. 151.8%). Bolus thickness <10mm vs. ≥10mm plans also had similar target coverage (Dmean = 118.2% vs. 110.7% and D90 = 100.1% vs. 99.0%). Applicators ≥10mm thick, however, provide more uniform target dosimetry (D0.1cc = 146.9% vs. 139.5%). Conclusion: Prescription depth is based upon the thickness of the lesion and upon the clinical needs of the patient. Applicators ≥10mm thick provide more dose uniformity than 5–10mm thick applicators. Applicator thickness is an important variable that should be considered during treatment planning to achieve optimal dose uniformity

  7. Temporal Evolution of Surface Deformation and Magma Sources at Pacaya Volcano, Guatemala Revealed by InSAR

    Science.gov (United States)

    Wnuk, K.; Wauthier, C.

    2016-12-01

    Pacaya Volcano, Guatemala is a persistently active volcano whose western flank is unstable. Despite continuous activity since 1961, a lack of high temporal resolution geodetic surveying has prevented detailed modeling of Pacaya's underlying magmatic plumbing system. A new, temporally dense dataset of Interferometric Synthetic Aperture Radar (InSAR) RADARSAT-2 images, spanning December 2012 to March 2014, shows magmatic deformation before and during major eruptions in January and March 2014. Inverse modeling of InSAR surface displacements suggest that three magma bodies are responsible for observed deformation: (1) a 3.7 km deep spherical reservoir located northwest of the summit, (2) a 0.4 km deep spherical source located directly west of the summit, and (3) a shallow dike below the summit that provides the primary transport pathway for erupted materials. Periods of heightened activity are brought on by magma pulses at depth, which result in rapid inflation of the edifice. We observe an intrusion cycle at Pacaya that consists of deflation of one or both magma reservoirs followed by dike intrusion. Intrusion volumes are proportional to reservoir volume loss, and do not always result in an eruption. Periods of increased activity culminate with larger dike fed eruptions. Large eruptions are followed by inter eruptive periods marked by a decrease in crater explosions and a lack of deformation. A full understanding of magmatic processes at Pacaya is required to assess potential impacts on other aspects of the volcano such as the unstable western flank. Co-eruptive flank motion appears to have initiated a new stage of volcanic rifting at Pacaya defined by repeated NW-SE dike intrusions. This creates a positive feedback relationship whereby magmatic forcing from eruptive dike intrusions induces flank motion

  8. Natural uranium and strontium isotope tracers of water sources and surface water-groundwater interactions in arid wetlands: Pahranagat Valley, Nevada, USA

    Science.gov (United States)

    Paces, James B.; Wurster, Frederic C.

    2014-01-01

    Near-surface physical and chemical process can strongly affect dissolved-ion concentrations and stable isotope compositions of water in wetland settings, especially under arid climate conditions. In contrast, heavy radiogenic isotopes of strontium (87Sr/86Sr) and uranium (234U/238U) remain largely unaffected and can be used to help identify unique signatures from different sources and quantify end-member mixing that would otherwise be difficult to determine. The utility of combined Sr and U isotopes are demonstrated in this study of wetland habitats on the Pahranagat National Wildlife Refuge, which depend on supply from large-volume springs north of the Refuge, and from small-volume springs and seeps within the Refuge. Water budgets from these sources have not been quantified previously. Evaporation, transpiration, seasonally variable surface flow, and water management practices complicate the use of conventional methods for determining source contributions and mixing relations. In contrast, 87Sr/86Sr and 234U/238U remain unfractionated under these conditions, and compositions at a given site remain constant. Differences in Sr- and U-isotopic signatures between individual sites can be related by simple two- or three-component mixing models. Results indicate that surface flow constituting the Refuge’s irrigation source consists of a 65:25:10 mixture of water from two distinct regionally sourced carbonate aquifer springs, and groundwater from locally sourced volcanic aquifers. Within the Refuge, contributions from the irrigation source and local groundwater are readily determined and depend on proximity to those sources as well as water management practices.

  9. Study of highly charged ion production by electron cyclotron resonance ion source. Interactions of Argon 17+ ions with metallic surface at grazing incidence

    International Nuclear Information System (INIS)

    Ban, G.

    1992-04-01

    In this thesis divided in 2 parts, the author first presents the operating of MiniMafios 16/18 GHz ECR ion sources and methods of extracted multicharged ion identification and then, studies the highly charged ion interactions with a metallic surface and the formation of 'hollow atoms'. 556 figs., 17 tabs

  10. A One Year Study on the Concentrations of Norovirus and Enteric Adenoviruses in Wastewater and A Surface Drinking Water Source in Norway.

    Science.gov (United States)

    Grøndahl-Rosado, Ricardo C; Yarovitsyna, Ekaterina; Trettenes, Elin; Myrmel, Mette; Robertson, Lucy J

    2014-12-01

    Enteric viruses transmitted via the faecal-oral route occur in high concentrations in wastewater and may contaminate drinking water sources and cause disease. In order to quantify enteric adenovirus and norovirus genotypes I and II (GI and GII) impacting a drinking source in Norway, samples of surface water (52), wastewater inlet (64) and outlet (59) were collected between January 2011 and April 2012. Samples were concentrated in two steps, using an electropositive disc filter and polyethylene glycol precipitation, followed by nucleic acid extraction and analysis by quantitative polymerase chain reaction. Virus was detected in 47/52 (90.4%) of surface water, 59/64 (92%) of wastewater inlet and 55/59 (93%) of wastewater outlet samples. Norovirus GI occurred in the highest concentrations in surface water (2.51e + 04) and adenovirus in wastewater (2.15e + 07). While adenovirus was the most frequently detected in all matrices, norovirus GI was more frequently detected in surface water and norovirus GII in wastewater. This study is the first in Norway to monitor both sewage and a drinking water source in parallel, and confirms the year-round presence of norovirus and adenovirus in a Norwegian drinking water source.

  11. High magnetic susceptibility granodiorite as a source of surface magnetic anomalies in the King George Island, Antarctica

    Science.gov (United States)

    Kon, S.; Nakamura, N.; Funaki, M.; Sakanaka, S.

    2012-12-01

    station) in the western side of King George Island. The plutonic rocks of diorite and granodiorite show high values of bulk magnetic susceptibility of c.a. 0.01-0.4 SI, appearing to be the source of positive magnetic anomaly. We also revealed the preferred petrofabric lineation directions at the sites using anisotropy of magnetic susceptibility (AMS). The AMS showed the plutonic rocks represent the vertical intrusion from the deep seated magma. Our optical microscope observation verified the maximum AMS orientation is parallel to the preferred alignment of framework-forming plagioclase, suggesting the alignment of euhedral magnetite grains along the long-axes of plagioclases. Our ship-borne and foot-borne surveys of geomagnetic filed anomaly agree well with the distribution of the plutonic rocks, revealing the possible origin of surface magnetic anomaly. These suggests that the plutons in this area may be included ACG, and this magnetic surveys is proposed to infer the availability to find out the presence of granitoid.

  12. Computers and conversation

    CERN Document Server

    Luff, Paul; Gilbert, Nigel G

    1986-01-01

    In the past few years a branch of sociology, conversation analysis, has begun to have a significant impact on the design of human*b1computer interaction (HCI). The investigation of human*b1human dialogue has emerged as a fruitful foundation for interactive system design.****This book includes eleven original chapters by leading researchers who are applying conversation analysis to HCI. The fundamentals of conversation analysis are outlined, a number of systems are described, and a critical view of their value for HCI is offered.****Computers and Conversation will be of interest to all concerne

  13. Condenser design for AMTEC power conversion

    Science.gov (United States)

    Crowley, Christopher J.

    1991-01-01

    The condenser and the electrodes are the two elements of an alkali metal thermal-to-electric conversion (AMTEC) cell which most greatly affect the energy conversion performance. A condenser is described which accomplishes two critical functions in an AMTEC cell: management of the fluid under microgravity conditions and optimization of conversion efficiency. The first function is achieved via the use of a controlled surface shape, along with drainage grooves and arteries to collect the fluid. Capillary forces manage the fluid in microgravity and dominate hydrostatic effects on the ground so the device is ground-testable. The second function is achieved via a smooth film of highly reflective liquid sodium on the condensing surface, resulting in minimization of parasitic heat losses due to radiation heat transfer. Power conversion efficiencies of 25 percent to 30 percent are estimated with this condenser using present technology for the electrodes.

  14. Determining water sources in the boundary layer from tall tower profiles of water vapor and surface water isotope ratios after a snowstorm in Colorado

    Directory of Open Access Journals (Sweden)

    D. Noone

    2013-02-01

    Full Text Available The D/H isotope ratio is used to attribute boundary layer humidity changes to the set of contributing fluxes for a case following a snowstorm in which a snow pack of about 10 cm vanished. Profiles of H2O and CO2 mixing ratio, D/H isotope ratio, and several thermodynamic properties were measured from the surface to 300 m every 15 min during four winter days near Boulder, Colorado. Coeval analysis of the D/H ratios and CO2 concentrations find these two variables to be complementary with the former being sensitive to daytime surface fluxes and the latter particularly indicative of nocturnal surface sources. Together they capture evidence for strong vertical mixing during the day, weaker mixing by turbulent bursts and low level jets within the nocturnal stable boundary layer during the night, and frost formation in the morning. The profiles are generally not well described with a gradient mixing line analysis because D/H ratios of the end members (i.e., surface fluxes and the free troposphere evolve throughout the day which leads to large uncertainties in the estimate of the D/H ratio of surface water flux. A mass balance model is constructed for the snow pack, and constrained with observations to provide an optimal estimate of the partitioning of the surface water flux into contributions from sublimation, evaporation of melt water in the snow and evaporation from ponds. Results show that while vapor measurements are important in constraining surface fluxes, measurements of the source reservoirs (soil water, snow pack and standing liquid offer stronger constraint on the surface water balance. Measurements of surface water are therefore essential in developing observational programs that seek to use isotopic data for flux attribution.

  15. Energy conversion and management principles and applications

    CERN Document Server

    Petrecca, Giovanni

    2014-01-01

    This book provides an overall view of energy conversion and management in industry and in buildings by following the streams of energy from the site boundaries to the end users. Written for an audience of both practitioners and faculty/students, Energy Conversion and Management: Principles and Applications presents general principles of energy conversion and energy sources, both traditional and renewable, in a broad range of facilities such as electrical substations, boiler plants, heat and power plants, electrical networks, thermal fluid distributions lines and insulations, pumps and fans, ai

  16. Linear mode conversion in a toroidal plasma

    International Nuclear Information System (INIS)

    Hellsten, T.

    1980-05-01

    Linear mode conversion at the perpendicular ion cyclotron resonance has been treated for an axially symmetric toroidal plasma. The mode conversion appears between a fast electromagnetic wave and a slow-quasi electrostatic wave, due to finite electron inertia. The problem reduces to the Orr-Sommerfeld equation where the coefficients determining the reflectron, transmission and conversion are functions of the arc length along a poloidal intersection of the resonance surface. These coefficients can be determined from eigenfunctions of an ordinary differential equation. (author)

  17. An novel identification method of the environmental risk sources for surface water pollution accidents in chemical industrial parks.

    Science.gov (United States)

    Peng, Jianfeng; Song, Yonghui; Yuan, Peng; Xiao, Shuhu; Han, Lu

    2013-07-01

    The chemical industry is a major source of various pollution accidents. Improving the management level of risk sources for pollution accidents has become an urgent demand for most industrialized countries. In pollution accidents, the released chemicals harm the receptors to some extent depending on their sensitivity or susceptibility. Therefore, identifying the potential risk sources from such a large number of chemical enterprises has become pressingly urgent. Based on the simulation of the whole accident process, a novel and expandable identification method for risk sources causing water pollution accidents is presented. The newly developed approach, by analyzing and stimulating the whole process of a pollution accident between sources and receptors, can be applied to identify risk sources, especially on the nationwide scale. Three major types of losses, such as social, economic and ecological losses, were normalized, analyzed and used for overall consequence modeling. A specific case study area, located in a chemical industry park (CIP) along the Yangtze River in Jiangsu Province, China, was selected to test the potential of the identification method. The results showed that there were four risk sources for pollution accidents in this CIP. Aniline leakage in the HS Chemical Plant would lead to the most serious impact on the surrounding water environment. This potential accident would severely damage the ecosystem up to 3.8 km downstream of Yangtze River, and lead to pollution over a distance stretching to 73.7 km downstream. The proposed method is easily extended to the nationwide identification of potential risk sources.

  18. Simulations of a spectral gamma-ray logging tool response to a surface source distribution on the borehole wall

    International Nuclear Information System (INIS)

    Wilson, R.D.; Conaway, J.G.

    1991-01-01

    We have developed Monte Carlo and discrete ordinates simulation models for the large-detector spectral gamma-ray (SGR) logging tool in use at the Nevada Test Site. Application of the simulation models produced spectra for source layers on the borehole wall, either from potassium-bearing mudcakes or from plate-out of radon daughter products. Simulations show that the shape and magnitude of gamma-ray spectra from sources distributed on the borehole wall depend on radial position with in the air-filled borehole as well as on hole diameter. No such dependence is observed for sources uniformly distributed in the formation. In addition, sources on the borehole wall produce anisotropic angular fluxes at the higher scattered energies and at the source energy. These differences in borehole effects and in angular flux are important to the process of correcting SGR logs for the presence of potassium mudcakes; they also suggest a technique for distinguishing between spectral contributions from formation sources and sources on the borehole wall. These results imply the existence of a standoff effect not present for spectra measured in air-filled boreholes from formation sources. 5 refs., 11 figs

  19. Application of stochastic models in identification and apportionment of heavy metal pollution sources in the surface soils of a large-scale region.

    Science.gov (United States)

    Hu, Yuanan; Cheng, Hefa

    2013-04-16

    As heavy metals occur naturally in soils at measurable concentrations and their natural background contents have significant spatial variations, identification and apportionment of heavy metal pollution sources across large-scale regions is a challenging task. Stochastic models, including the recently developed conditional inference tree (CIT) and the finite mixture distribution model (FMDM), were applied to identify the sources of heavy metals found in the surface soils of the Pearl River Delta, China, and to apportion the contributions from natural background and human activities. Regression trees were successfully developed for the concentrations of Cd, Cu, Zn, Pb, Cr, Ni, As, and Hg in 227 soil samples from a region of over 7.2 × 10(4) km(2) based on seven specific predictors relevant to the source and behavior of heavy metals: land use, soil type, soil organic carbon content, population density, gross domestic product per capita, and the lengths and classes of the roads surrounding the sampling sites. The CIT and FMDM results consistently indicate that Cd, Zn, Cu, Pb, and Cr in the surface soils of the PRD were contributed largely by anthropogenic sources, whereas As, Ni, and Hg in the surface soils mostly originated from the soil parent materials.

  20. The recovery of a time-dependent point source in a linear transport equation: application to surface water pollution

    International Nuclear Information System (INIS)

    Hamdi, Adel

    2009-01-01

    The aim of this paper is to localize the position of a point source and recover the history of its time-dependent intensity function that is both unknown and constitutes the right-hand side of a 1D linear transport equation. Assuming that the source intensity function vanishes before reaching the final control time, we prove that recording the state with respect to the time at two observation points framing the source region leads to the identification of the source position and the recovery of its intensity function in a unique manner. Note that at least one of the two observation points should be strategic. We establish an identification method that determines quasi-explicitly the source position and transforms the task of recovering its intensity function into solving directly a well-conditioned linear system. Some numerical experiments done on a variant of the water pollution BOD model are presented

  1. Energy conversion alternatives study

    Science.gov (United States)

    Shure, L. T.

    1979-01-01

    Comparison of coal based energy systems is given. Study identifies and compares various advanced energy conversion systems using coal or coal derived fuels for baselaoad electric power generation. Energy Conversion Alternatives Study (ECAS) reports provede government, industry, and general public with technically consistent basis for comparison of system's options of interest for fossilfired electric-utility application.

  2. Hydrothermal conversion of biomass

    NARCIS (Netherlands)

    Knezevic, D.

    2009-01-01

    This thesis presents research of hydrothermal conversion of biomass (HTC). In this process, hot compressed water (subcritical water) is used as the reaction medium. Therefore this technique is suitable for conversion of wet biomass/ waste streams. By working at high pressures, the evaporation of

  3. Conversations in African Philosophy

    African Journals Online (AJOL)

    JONATHAN

    Conversational philosophy is articulated by Jonathan O. Chimakonam as the new wave of philosophical practice both in “place” and in “space”. This journal adopts and promotes this approach to philosophizing for African philosophy. Readers are encouraged to submit their conversational piece (maximum of 2000 words) ...

  4. Microwave plasma mode conversion

    International Nuclear Information System (INIS)

    Torres, H.S.; Sakanaka, P.H.; Villarroel, C.H.

    1985-01-01

    The behavior of hot electrons during the process of laser-produced plasma is studied. The basic equations of mode conversion from elect