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Sample records for surface area concentrations

  1. Estimation of surface area concentration of workplace incidental nanoparticles based on number and mass concentrations

    Science.gov (United States)

    Park, J. Y.; Ramachandran, G.; Raynor, P. C.; Kim, S. W.

    2011-10-01

    Surface area was estimated by three different methods using number and/or mass concentrations obtained from either two or three instruments that are commonly used in the field. The estimated surface area concentrations were compared with reference surface area concentrations (SAREF) calculated from the particle size distributions obtained from a scanning mobility particle sizer and an optical particle counter (OPC). The first estimation method (SAPSD) used particle size distribution measured by a condensation particle counter (CPC) and an OPC. The second method (SAINV1) used an inversion routine based on PM1.0, PM2.5, and number concentrations to reconstruct assumed lognormal size distributions by minimizing the difference between measurements and calculated values. The third method (SAINV2) utilized a simpler inversion method that used PM1.0 and number concentrations to construct a lognormal size distribution with an assumed value of geometric standard deviation. All estimated surface area concentrations were calculated from the reconstructed size distributions. These methods were evaluated using particle measurements obtained in a restaurant, an aluminum die-casting factory, and a diesel engine laboratory. SAPSD was 0.7-1.8 times higher and SAINV1 and SAINV2 were 2.2-8 times higher than SAREF in the restaurant and diesel engine laboratory. In the die casting facility, all estimated surface area concentrations were lower than SAREF. However, the estimated surface area concentration using all three methods had qualitatively similar exposure trends and rankings to those using SAREF within a workplace. This study suggests that surface area concentration estimation based on particle size distribution (SAPSD) is a more accurate and convenient method to estimate surface area concentrations than estimation methods using inversion routines and may be feasible to use for classifying exposure groups and identifying exposure trends.

  2. Estimation of surface area concentration of workplace incidental nanoparticles based on number and mass concentrations

    International Nuclear Information System (INIS)

    Park, J. Y.; Ramachandran, G.; Raynor, P. C.; Kim, S. W.

    2011-01-01

    Surface area was estimated by three different methods using number and/or mass concentrations obtained from either two or three instruments that are commonly used in the field. The estimated surface area concentrations were compared with reference surface area concentrations (SA REF ) calculated from the particle size distributions obtained from a scanning mobility particle sizer and an optical particle counter (OPC). The first estimation method (SA PSD ) used particle size distribution measured by a condensation particle counter (CPC) and an OPC. The second method (SA INV1 ) used an inversion routine based on PM1.0, PM2.5, and number concentrations to reconstruct assumed lognormal size distributions by minimizing the difference between measurements and calculated values. The third method (SA INV2 ) utilized a simpler inversion method that used PM1.0 and number concentrations to construct a lognormal size distribution with an assumed value of geometric standard deviation. All estimated surface area concentrations were calculated from the reconstructed size distributions. These methods were evaluated using particle measurements obtained in a restaurant, an aluminum die-casting factory, and a diesel engine laboratory. SA PSD was 0.7–1.8 times higher and SA INV1 and SA INV2 were 2.2–8 times higher than SA REF in the restaurant and diesel engine laboratory. In the die casting facility, all estimated surface area concentrations were lower than SA REF . However, the estimated surface area concentration using all three methods had qualitatively similar exposure trends and rankings to those using SA REF within a workplace. This study suggests that surface area concentration estimation based on particle size distribution (SA PSD ) is a more accurate and convenient method to estimate surface area concentrations than estimation methods using inversion routines and may be feasible to use for classifying exposure groups and identifying exposure trends.

  3. Lung deposited surface area concentrations in a street canyon

    Science.gov (United States)

    Kuuluvainen, Heino; Hietikko, Riina; Järvinen, Anssi; Saukko, Erkka; Irjala, Matti; Niemi, Jarkko V.; Timonen, Hilkka; Keskinen, Jorma; Rönkkö, Topi

    2017-04-01

    Street canyons are interesting environments with respect to the dispersion of traffic emissions and human exposure. Pedestrians may be exposed to relatively high concentrations of fine particles and the vertical dispersion affects the human exposure above the ground level in buildings. Previously, particle concentrations have been measured in street canyons at a few different heights (Marini et al., 2015). The information on the lung deposited surface area (LDSA) concentration, which is a relevant metric for the negative health effects, is very limited even at the ground level of street canyons (Kuuluvainen et al., 2016). More information especially on the vertical dispersion and the ground level concentrations is needed, for instance, for the use of urban planning and the design of ventilation systems in buildings. Measurements were carried out in a busy street canyon in Helsinki, Finland, at an urban super-site measurement station (Mäkelänkatu 50). The data included vertical concentration profiles measured in an intensive measurement campaign with a Partector (Naneos GmbH) installed into a drone, long-term measurements with an AQ Urban particle sensor (Pegasor Ltd.), and an extensive comparison measurement in the field with different devices measuring the LDSA. These devices were an AQ Urban, Partector, DiSCmini (Testo AG), NSAM (TSI Inc.), and an ELPI+ (Dekati Ltd.). In addition, continuous measurements of gas phase components, particle size distributions, and meteorology were run at the supersite. The vertical profile measurements were con-ducted in November 2016 during two days. In the measurements, the drone was flown from the ground level to an altitude of 50 or 100 m, which is clearly above the roof level of the buildings. Altogether, 48 up-and-down flights were conducted during the two days. The vertical profiles were supported by continuous measurements at the ground level on both sides of the street canyon. The long-term measurements were conducted

  4. Can We Trust Real Time Measurements of Lung Deposited Surface Area Concentrations in Dust from Powder Nanomaterials?

    DEFF Research Database (Denmark)

    Levin, Marcus; Witschger, Olivier; Bau, Sebastien

    2016-01-01

    A comparison between various methods for real-time measurements of lung deposited surface area (LDSA) using spherical particles and powder dust with specific surface area ranging from 0.03 to 112 m2 g-1 was conducted. LDSA concentrations measured directly using Nanoparticle Surface Area Monitor...... (NSAM) and Aerotrak and were compared to LDSA concentrations recalculated from size distribution measurements using Electrical Low Pressure Impactor (ELPI) and Fast Mobility Particle Sizer (FMPS). FMPS and ELPI measurements were also compared to dust surface area concentrations estimated from...... gravimetrical filter measurements and specific surface areas. Measurement of LDSA showed very good correlation in measurements of spherical particles (R2 > 0.97, Ratio 1.0 to 1.04). High surface area nanomaterial powders showed a fairly reliable correlation between NSAM and Aerotrak (R2 0...

  5. Determination of particle concentration rankings by spatial mapping of particle surface area, number, and mass concentrations in a restaurant and a die casting plant.

    Science.gov (United States)

    Park, Ji Young; Ramachandran, Gurumurthy; Raynor, Peter C; Olson, Gregory M

    2010-08-01

    Measurements using several exposure metrics were carried out in a restaurant and a die casting plant to compare the spatial distributions of particle surface area (SA), number, and mass concentrations and rank exposures in different areas by those metrics. The different exposure metrics for incidental nanoparticle and fine particle exposures were compared using the concentration rankings, statistical differences between areas, and concentration ratios between different areas. In the die casting plant, area concentration rankings and spatial distributions differed by the exposure metrics chosen. Surface area and fine particle number concentrations were greatest near incidental nanoparticle sources and were significantly different between three areas. However, mass and coarse particle number concentrations were similar throughout the facility, and rankings of the work areas based on these metrics were different from those of SA and fine number concentrations. In the restaurant, concentrations in the kitchen for all metrics except respirable mass concentration were significantly greater than in the serving area, although SA and fine particle number concentrations showed larger differences between the two areas than either the mass or coarse particle number concentrations. Thus, the choice of appropriate exposure metric has significant implications for exposure groupings in epidemiologic and occupational exposure studies.

  6. Comparison of two estimation methods for surface area concentration using number concentration and mass concentration of combustion-related ultrafine particles

    Science.gov (United States)

    Park, Ji Young; Raynor, Peter C.; Maynard, Andrew D.; Eberly, Lynn E.; Ramachandran, Gurumurthy

    Recent research has suggested that the adverse health effects caused by nanoparticles are associated with their surface area (SA) concentrations. In this study, SA was estimated in two ways using number and mass concentrations and compared with SA (SA meas) measured using a diffusion charger (DC). Aerosol measurements were made twice: once starting in October 2002 and again starting in December 2002 in Mysore, India in residences that used kerosene or liquefied petroleum gas (LPG) for cooking. Mass, number, and SA concentrations and size distributions by number were measured in each residence. The first estimation method (SA PSD) used the size distribution by number to estimate SA. The second method (SA INV) used a simple inversion scheme that incorporated number and mass concentrations while assuming a lognormal size distribution with a known geometrical standard deviation. SA PSD was, on average, 2.4 times greater (range = 1.6-3.4) than SA meas while SA INV was, on average, 6.0 times greater (range = 4.6-7.7) than SA meas. The logarithms of SA PSD and SA INV were found to be statistically significant predictors of the logarithm of SA meas. The study showed that particle number and mass concentration measurements can be used to estimate SA with a correction factor that ranges between 2 and 6.

  7. Concentration Levels and Ecological Risks of Persistent Organic Pollutants in the Surface Sediments of Tianjin Coastal Area, China

    Directory of Open Access Journals (Sweden)

    Xiaoxia Lu

    2013-01-01

    Full Text Available Sediments were sampled from different surface water bodies in Tianjin coastal area, China, and persistent organic pollutants (POPs including polycyclic aromatic hydrocarbons (PAHs, organochlorine pesticides (OCPs, polychlorinated biphenyls (PCBs, and polybrominated diphenyl ethers (PBDEs were measured using GC/MS or GC/ECD. The purposes were to investigate the concentration levels of the POPs and to assess their ecological risks. The results showed that all the 16 priority PAHs were detected from the 10 sediments sampled with the total concentrations of the 16 PAHs ranging from 274.06 μg/kg to 2656.65 μg/kg, while the concentrations of the halogenated POPs were generally low except in the Dagu waste discharging river where the total concentrations of 24 OCPs, 35 PCBs, and 14 PBDEs were 3103.36 μg/kg, 87.31 μg/kg, and 13.88 μg/kg, respectively. In the studied sediments, PAHs exhibited risks to benthonic organisms; particularly the concentrations of naphthalene and/or acenaphthene exceeded their probable effect concentrations in several locations. In comparison, only in the Dagu waste discharging river, OCPs exhibited risks with the concentrations of heptachlor epoxide and lindane exceeding their probable effect concentrations. PCBs and PBDEs posed rare risks in the studied area.

  8. Experimental study of the response functions of direct-reading instruments measuring surface-area concentration of airborne nanostructured particles

    Science.gov (United States)

    Bau, Sébastien; Witschger, Olivier; Gensdarmes, François; Thomas, Dominique

    2009-05-01

    An increasing number of experimental and theoretical studies focus on airborne nanoparticles (NP) in relation with many aspects of risk assessment to move forward our understanding of the hazards, the actual exposures in the workplace, and the limits of engineering controls and personal protective equipment with regard to NP. As a consequence, generating airborne NP with controlled properties constitutes an important challenge. In parallel, toxicological studies have been carried out, and most of them support the concept that surface-area could be a relevant metric for characterizing exposure to airborne NP [1]. To provide NP surface-area concentration measurements, some direct-reading instruments have been designed, based on attachment rate of unipolar ions to NP by diffusion. However, very few information is available concerning the performances of these instruments and the parameters that could affect their responses. In this context, our work aims at characterizing the actual available instruments providing airborne NP surface-area concentration. The instruments (a- LQ1-DC, Matter Engineering; b-AeroTrak™ 9000, TSI; c- NSAM, TSI model 3550;) are thought to be relevant for further workplace exposure characterization and monitoring. To achieve our work, an experimental facility (named CAIMAN) was specially designed, built and characterized.

  9. Experimental study of the response functions of direct-reading instruments measuring surface-area concentration of airborne nanostructured particles

    Energy Technology Data Exchange (ETDEWEB)

    Bau, Sebastien; Witschger, Olivier [Institut National de Recherche et de Securite, INRS, Laboratoire de Metrologie des Aerosols, Rue du Morvan, CS 60027, 54519 Vandoeuvre Cedex (France); Gensdarmes, Francois [Institut de Radioprotection et de Surete Nucleaire, IRSN, Laboratoire de Physique et de Metrologie des Aerosols, BP 68, 91192 Gif-sur-Yvette Cedex (France); Thomas, Dominique [Laboratoire des Sciences du Genie Chimique, LSGC/CNRS, Nancy Universite, BP 2041, 54001 Nancy Cedex (France)], E-mail: sebastien.bau@inrs.fr

    2009-05-01

    An increasing number of experimental and theoretical studies focus on airborne nanoparticles (NP) in relation with many aspects of risk assessment to move forward our understanding of the hazards, the actual exposures in the workplace, and the limits of engineering controls and personal protective equipment with regard to NP. As a consequence, generating airborne NP with controlled properties constitutes an important challenge. In parallel, toxicological studies have been carried out, and most of them support the concept that surface-area could be a relevant metric for characterizing exposure to airborne NP. To provide NP surface-area concentration measurements, some direct-reading instruments have been designed, based on attachment rate of unipolar ions to NP by diffusion. However, very few information is available concerning the performances of these instruments and the parameters that could affect their responses. In this context, our work aims at characterizing the actual available instruments providing airborne NP surface-area concentration. The instruments (a- LQ1-DC, Matter Engineering; b-AeroTrak{sup x2122} 9000, TSI; c- NSAM, TSI model 3550;) are thought to be relevant for further workplace exposure characterization and monitoring. To achieve our work, an experimental facility (named CAIMAN) was specially designed, built and characterized.

  10. Polybrominated diphenyl ethers in surface soils from e-waste recycling areas and industrial areas in South China: concentration levels, congener profile, and inventory.

    Science.gov (United States)

    Gao, Shutao; Hong, Jianwen; Yu, Zhiqiang; Wang, Jingzhi; Yang, Guoyi; Sheng, Guoying; Fu, Jiamo

    2011-12-01

    Polybrominated diphenyl ethers (PBDEs) were determined in 60 surface soils from two e-waste recycling sites (Qingyuan and Guiyu, China) and their surrounding areas to assess the extent and influence of PBDEs from e-waste recycling sites on the surrounding areas. A total of 32 surface soils from industrial areas in South China were also investigated for comparison. The mean concentrations of total PBDEs in the e-waste recycling sites of Guiyu and Qingyuan were 2,909 and 3,230 ng/g dry weight, respectively, whereas the PBDE concentrations decreased dramatically (1-2 orders of magnitude) with increasing distance from the recycling site, suggesting that the e-waste recycling activities were the major source of PBDEs in the surrounding areas. Decabromodiphenyl ethers accounted for 77.0 to 85.8% of total PBDEs in e-waste recycling areas, whereas it accounted for 90.2% in industrial areas. Principal component analysis showed that the major source of PBDEs in e-waste recycling areas were a combination of penta-, octa-, and deca-BDE commercial formulations, whereas deca-BDE commercial formulations were the major source of PBDE congeners in industrial areas. The inventories of PBDEs gave preliminary estimates of 6.22 tons and 13.4 tons for the e-waste recycling areas and industrial areas. The results suggested that significantly higher PBDEs in the e-waste recycling sites have already affected surrounding areas negatively within a relatively large distance. Because of the environmental persistence, bioaccumulation, and toxicity of PBDEs, improving the recycling techniques employed at such facilities and developing e-waste management policies are necessary. Copyright © 2011 SETAC.

  11. Modeling of surface dust concentration in snow cover at industrial area using neural networks and kriging

    Science.gov (United States)

    Sergeev, A. P.; Tarasov, D. A.; Buevich, A. G.; Shichkin, A. V.; Tyagunov, A. G.; Medvedev, A. N.

    2017-06-01

    Modeling of spatial distribution of pollutants in the urbanized territories is difficult, especially if there are multiple emission sources. When monitoring such territories, it is often impossible to arrange the necessary detailed sampling. Because of this, the usual methods of analysis and forecasting based on geostatistics are often less effective. Approaches based on artificial neural networks (ANNs) demonstrate the best results under these circumstances. This study compares two models based on ANNs, which are multilayer perceptron (MLP) and generalized regression neural networks (GRNNs) with the base geostatistical method - kriging. Models of the spatial dust distribution in the snow cover around the existing copper quarry and in the area of emissions of a nickel factory were created. To assess the effectiveness of the models three indices were used: the mean absolute error (MAE), the root-mean-square error (RMSE), and the relative root-mean-square error (RRMSE). Taking into account all indices the model of GRNN proved to be the most accurate which included coordinates of the sampling points and the distance to the likely emission source as input parameters for the modeling. Maps of spatial dust distribution in the snow cover were created in the study area. It has been shown that the models based on ANNs were more accurate than the kriging, particularly in the context of a limited data set.

  12. Barium concentrations and speciation in surface waters collected from an active barium mining area in Guizhou Province, southwestern China.

    Science.gov (United States)

    Lu, Qinhui; Xu, Xiaohang; Xu, Zhidong; Liang, Longchao; Shang, Lihai; Xiao, Dean; Zhang, Sensen; Jiang, Yuping; Qiu, Guangle

    2018-03-01

    Barium (Ba) is a toxic element and can cause serious health effects. Humans have experienced increased exposure to Ba due to its intensive usage in industrial areas and daily life. Anthropogenic activities of Ba mining and the manufacture of Ba containing products introduce the element into surrounding areas, posing environmental concerns. Concentrations of total Ba (TBa) and dissolved Ba (DBa) in water samples collected from active Ba mines in Tianzhu, east Guizhou Province, southwestern China were measured to show the regional dispersion of Ba contamination. Aqueous Ba species in water were calculated using the PHREEQC program. The results showed that TBa and DBa concentrations ranged from 6.7 to 483.1 μg/L and from 7.5 to 222.7 μg/L, respectively. TBa concentrations presented a high average value of 126.6 μg/L and greatly exceeded the reported common value of 10 μg/L Ba in surface water set by the Ministry of Environment Protection of China. PHREEQC results indicated that Ba species in water were present as Ba 2+ , BaSO 4 , BaHCO 3 , BaCO 3 , and BaOH + . The distribution of Ba species in water is controlled by pH and total organic carbon (TOC), and the lower pH (pH < 7) the higher the dissolved fractions. The log K d values (K d , dissolved-particulate distribution coefficients) varied from 2.41 to 6.32. Significant correlations were observed among Ba 2+ and K + , Na + , Cl - , NO 3 - , with Pearson correlation coefficients of 0.425, 0.531, 0.853, 0.612, and 0.329, respectively (p < 0.01). Elevated Ba concentrations in water indicated that the Ba contamination and its distribution pattern in local aquatic ecosystems are derived from Ba mining sites in the Tianzhu area.

  13. Arsenic Concentration in the Surface Water of a Former Mining Area: The La Junta Creek, Baja California Sur, Mexico

    Science.gov (United States)

    Imaz Lamadrid, Miguel; Acosta Vargas, Baudilio

    2018-01-01

    The mining activity in the San Antonio-El Triunfo district, located in a mountainous region at 60 km southeast of La Paz, occured for more than 250 years and left behind severe contamination of soils and riverbed sediments which led to elevated concentrations of arsenic and other trace elements in the surface- and groundwater of the region. Although the main mining activity ended around 1911, contamination is still beeing distributed, especially from left behind tailings and mine waste piles. The contamination levels in the groundwater have been reported in several studies, but there is little information available on the surface water quality, and especially the temporal variation. In this study, we analyzed the surface water of the La Junta creek, in the southern part of the San Antonio-El Triunfo mining district. The working hypothesis was that by means of a spatial analysis of surface water and shallow groundwater, in combination with the temporal observation of the concentrations in runoff water, the effects of different sources of arsenic (natural geogene anomalies, due to historic mining activity, and hydrothermal related impact) in the La Junta creek can be recognized. This present study revealed that historic mining activity caused a mojor impact of arsenic but less contamination was observed than in the northern part of the district and elevated arsenic concentrations in stream water generally occurred during times of low streamflow. PMID:29498700

  14. Effect of pesticides on surface ozone concentration

    International Nuclear Information System (INIS)

    Farag, S.A.; Rizk, H.F.S.; Elbahnasawy, R.M.; Meleigy, M.I.

    1992-01-01

    A comparative study through seasonal variation of surface ozone concentration was carried out recently (1991-1992) at a background area free from expected urban pollutants (Shebin ElKom) and industrial and urban areas (Cairo). Surface ozone concentrations in ppb were generally lower in such area compared with urban or industrial areas studied through the comparative seasonal variations. Notable smog values (>100 ppb) of hourly surface ozone concentrations appeared during summer season in this rural area; during this season, some pesticides were sprayed over cotton and other crops fields in near by agricultural areas. The unexpected jump in the values of diurnal concentrations of surface ozone in that area may be due to the photochemical reactions of these organic pesticides in the atmosphere. 1 fig, 3 tab

  15. Differences in activity level between cownose rays (Rhinoptera bonasus) and Atlantic stingrays (Dasyatis sabina) are related to differences in heart mass, hemoglobin concentration, and gill surface area.

    Science.gov (United States)

    Grim, Jeffrey M; Ding, A Adam; Bennett, Wayne A

    2012-10-01

    Aquatic animals are faced with the challenge of extracting oxygen from water, a medium that is metabolically expensive to ventilate and that contains just a fraction of the oxygen concentration relative to air, yet the physiologies of fishes have evolved to support a wide range of activity levels in nature. Oxygen delivery components, including gill surface area (oxygen uptake), blood chemistry (oxygen transport), and the heart (system pump), have been positively correlated to activity level in teleost fishes, yet relatively little is known about how these components are related to activity in elasmobranches. The current study addresses this question by examining heart mass, hemoglobin concentration, hematocrit level, and gill surface area in wild-caught representatives of the benthic Atlantic stingray (Dasyatis sabina) and active cownose ray (Rhinoptera bonasus). Allometric scaling exponents are similar for all four measures between the study species. Heart mass, gill surfaces areas, and hemoglobin concentrations were 2.1 times, approximately 7.1 times, and 2.0 times higher, respectively, in active cownose rays, when compared to benthic Atlantic stingrays, after correcting for differences in body mass. When considered in the context of functional plasticity within the oxygen delivery systems of benthic and active species, data from the current study indicate that higher activity levels in cownose rays are supported by modifications that, at least in part, are likely to enhance oxygen uptake.

  16. Determination of free cyanide and total cyanide concentrations in surface and underground waters in Bogoso and its surrounding areas in Ghana

    Directory of Open Access Journals (Sweden)

    S. Obiri

    2007-08-01

    Full Text Available Concentrations of free cyanide and total cyanide in water samples in Bogoso and its surrounding areas in Ghana have been measured in this study. Concentrations of free cyanide and total cyanide were found to be above the maximum permissible discharge limit of effluent from mining companies into natural waters set by Environmental Protection Agency, Ghana (GEPA. A comparison of the results obtained in this study with permissible levels set by US Environmental Protection Agency and the World Health Organization reveals that surface waters in the study areas are highly polluted with cyanide and it's not safe for human consumptions. This means that, the resident in and around Bogoso are at risk.

  17. High surface area calcite

    Science.gov (United States)

    Schultz, L. N.; Andersson, M. P.; Dalby, K. N.; Müter, D.; Okhrimenko, D. V.; Fordsmand, H.; Stipp, S. L. S.

    2013-05-01

    Calcite (CaCO3) is important in many fields—in nature, because it is a component of aquifers, oil reservoirs and prospective CO2 storage sites, and in industry, where it is used in products as diverse as paper, toothpaste, paint, plastic and aspirin. It is difficult to obtain high purity calcite with a high surface area but such material is necessary for industrial applications and for fundamental calcite research. Commercial powder is nearly always contaminated with growth inhibitors such as sugars, citrate or pectin and most laboratory synthesis methods deliver large precipitates, often containing vaterite or aragonite. To address this problem, we (i) adapted the method of carbonating a Ca(OH)2 slurry with CO2 gas to develop the first simple, cheap, safe and reproducible procedure using common laboratory equipment, to obtain calcite that reproducibly had a surface area of 14-17 m2/g and (ii) conducted a thorough characterization of the product. Scanning electron microscopy (SEM) revealed nanometer scale, rhombohedral crystals. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and infrared spectroscopy (IR) confirmed highly crystalline, pure calcite that more closely resembles the dimensions of the biogenic calcite produced by algae in coccoliths than other methods for synthesizing calcite. We suggest that this calcite is useful when purity and high surface area are important.

  18. Some physiochemical and heavy metal concentration in surface water stream of Tutuka in the Kenyasi mining catchment area

    Directory of Open Access Journals (Sweden)

    B.M. Tiimub

    2012-09-01

    Full Text Available The research was conducted in the Akantansu stream of Tutuka in Kenyasi in the Brong Ahafo Region of Ghana from October 2010 to January 2011. The objectives of the study were to find out the contamination levels of pH, BOD5, Lead, Chromium, and Arsenic in the Akantansu stream of Tutuka to promote public health safety of people patronizing the stream for bathing and cooking. Determination of pH was achieved using Etech instrument (PC 300 series where as BOD5 level was assessed by means of empirical standard laboratory test which determined the relative oxygen requirements of waste water, effluents and polluted water using the standard procedure as per America Public Health Association (2006. An AAS 220 atomic absorption spectrometer was used for the analyses of heavy metals (lead, chromium and arsenic. The Research revealed that, the geometric mean levels of (0.01- 0.02, 0.03 – 0.26, 0 - 0.01, 3.99 – 7.06 mg/L and 5.64 – 6.40 for Arsenic, Lead, Chromium, BOD5 and pH compared to the EPA Maximum Permissible Limits of ( 0.5, 0.1, 0.1, 50 mg/L and 6-9 were respectively within the acceptable standards. However, due to slightly higher concentration of chromium (0.26 mg/L up the stream, the people of Tutuka may develop health effects such as nausea, vomiting, diarrhea, hallucinations, headaches, depression, sleeping disorders, skin cancers, tumours in lungs, bladder, kidney and liver if they continue to use water from the stream for bathing and cooking.

  19. Highly efficient simultaneous adsorption and biodegradation of a highly-concentrated anionic dye by a high-surface-area carbon-based biocomposite.

    Science.gov (United States)

    Zheng, Yuan; Chen, Dongyun; Li, Najun; Xu, Qingfeng; Li, Hua; He, Jinghui; Lu, Jianmei

    2017-07-01

    Mesoporous high-surface-area activated carbon (MHSA-AC), which has a honeycomb structure, was produced from coconut shells by simultaneous chemical and physical activation and used for the rapid adsorption of an anionic dye, namely acid orange 10 (AO10), from water. Owing to its porosity and high Brunauer-Emmett-Teller surface area (2283.91 m 2 g -1 ), MHSA-AC is a highly efficient adsorbent. It also has good biocompatibility and is a good immobilization carrier; the grooves on the MHSA-AC surface facilitate immobilization. Here, a new, highly efficient, and environmentally friendly simultaneous adsorption and biodegradation (SAB) process was developed. Highly concentrated AO10 (6000 mg L -1 , 20 mL) was removed with an efficiency of 100% (pH = 7, 35 °C) by SAB using cells immobilized on MHSA-AC (500 mg). The immobilized cells were used directly, without pretreatment; the SAB process is therefore simple and has good potential for application in the treatment of dyes in industrial wastewater. Copyright © 2017 Elsevier Ltd. All rights reserved.

  20. Concentration and distribution of heavy metals and radionuclides in topsoils from Middle Jiu Valley surface coal exploitations sourrounding area (Gorj County, Romania)

    Science.gov (United States)

    Corneanu, Mihaela; Corneanu, Gabriel; Lacatusu, Anca-Rovena; Cojocaru, Luminita; Butnariu, Monica

    2013-04-01

    Middle Jiu Valley is one of the largest surface coal exploitation area in Romania. The coal exploitation area is a dense populated one, along the valleys are villages and the inhabitants produce for their own consumption fruits and vegetables, in their personal gardens, or cereals in the fields, nearby the villages. There was considered to be of great interest to investigate the heavy metals and radionuclides content in gardens and cropfield soils from the villages sourrounding the Thermo Electric Power Plants (TEPP) and coal surface exploitation, as well as in crude /cultivated sterile soil or ash. The topsoil samples (104) were harvested from population gardens (58), cropfields sourronding Thermo Electric Power Plants (24), crude sterile dumps (7), cultivated sterile dumps (9) and ash dumps (6). The content in radionuclides in soil was performed by Duggan (1988) method. Radionuclide activity was expressed in Bqkg-1, confidence level 95%. The total content of heavy metals in soil (Zn, Cu, Fe, Mn, Pb, Cd, Ni, Cr, Co) was measured with flame atomic mass spectrometry. The content in heavy metals was expressed in mgkg-1. Soil analysis revealed the presence of natural radionuclides, beloging from ash and coal dust, as well as of Cs-137, of Cernobal provenance. In the cropfields radionuclides content in topsoil is lower than in gardens, due to the deepper soil mobilisation. Radionuclides content over the normal limits for Romania were registered for Th-234, Pb-210, U-235 and in few locations for Ra-226. The soil content for all analysed metals was over the normal limits in most samples, in few cases with values close to allert limits. Concentrations between allert and intervention limits were registered in samples collected from 15-20 km North of TEPP Turceni, in population gardens.

  1. Concentration and temperature effect on controlling pore size and surface area of mesoporous titania by using template of F-68 and F-127 co-polymer in the sol-gel process.

    Science.gov (United States)

    Jadhav, Nitin A; Kim, Chang Woo; Pal, Umapada; Kim, Jinheung; Kang, Young Soo

    2012-07-01

    Mesoporous titania with crystalline pore walls and controlled pore sizes was fabricated through triblock copolymer (pluronic series) templated sol-gel process by changing the copolymer concentration and by adjusting their calcination temperature. Compared with mesoprous silicate, the synthetic condition of mesoporous titania would be sensitive to calcination temperature. Their pore arrangement and pore size depend strongly on the concentration of copolymer used as a template. Their arrangement of pores and specific surface area increases with the increase of calcination temperature up to critical limit, 320 degrees C. Beyond the critical temperature, the orderness of pores and specific surface area decreases due to the collapse of the pore walls. The specific surface area, pore size and pore orderness can be controlled by optimizing calcination temperature as well as polymer concentration. We demonstrate the mechanism of pore formation and their collapse in the sol-gel synthesis of mesoporous titania.

  2. Retrieve Aerosol Concentration Based On Surface Model and Distribution of Concentration of PM2.5

    Science.gov (United States)

    Cui, Hongzhi

    2017-04-01

    As China's economy continues to grow, urbanization continues to advance, along with growth in all areas to pollutant emissions in the air industry, air quality also continued to deteriorate. Aerosol concentrations as a measure of air quality of the most important part of are more and more people's attention. Traditional monitoring stations measuring aerosol concentration method is accurate, but time-consuming and can't be done simultaneously measure a large area, can only rely on data from several monitoring sites to predict the concentration of the panorama. Remote Sensing Technology retrieves aerosol concentrations being by virtue of their efficient, fast advantages gradually into sight. In this paper, by the method of surface model to start with the physical processes of atmospheric transport, innovative aerosol concentration coefficient proposed to replace the traditional aerosol concentrations, pushed to a set of retrieval of aerosol concentration coefficient method, enabling fast and efficient Get accurate air pollution target area. At the same paper also monitoring data for PM2.5 in Beijing were analyzed from different angles, from the perspective of the data summarized in Beijing PM2.5 concentration of time, space, geographical distribution and concentration of PM2.5 and explored the relationship between aerosol concentration coefficient and concentration of PM2.5. Key words,Air Pollution, Aerosol concentration , PM2.5 , Retrieve

  3. Variations of surface ozone concentration across the Klang Valley, Malaysia

    Science.gov (United States)

    Latif, Mohd Talib; Huey, Lim Shun; Juneng, Liew

    2012-12-01

    Hourly air quality data covering the period 2004-2008 was obtained from the Air Quality Division, the Department of Environment (DOE) through long-term monitoring by Alam Sekitar Sdn. Bhd. (ASMA) were analysed to investigate the variations of surface ozone (O3) in the Klang Valley, Malaysia. A total of nine monitoring stations were selected for analysis in this study and the results show that there are distinct seasonal patterns in the surface O3 across the Klang Valley. A high surface O3 concentration is usually observed between January and April, while a low surface O3 concentration is found between June and August. Analysis of daily variations in surface O3 and the precursors - NO, NO2, CO, NMHC and UVb, indicate that the surface O3 photochemistry in this study area exhibits a positive response to the intensity and wavelength in UVb while being influenced by the concentration of NOx, particularly through tritration processes. Although results from our study suggested that NMHCs may influence the maximum O3 concentration, further investigation is required. Wind direction during different monsoons was found to influence the concentration of O3 around the Klang Valley. HYSPLIT back trajectories (-72 h) were used to indicate the air-mass transport patterns on days with high concentrations of surface O3 in the study area. Results show that 47% of the high O3 days was associated with the localized circulation. The remaining 32% and 22% were associated with mid-range and long-range transport across the South China Sea from the northeast.

  4. Contact area measurements on structured surfaces

    DEFF Research Database (Denmark)

    Kücükyildiz, Ömer Can; Jensen, Sebastian Hoppe Nesgaard; De Chiffre, Leonardo

    In connection with the use of brass specimens featuring structured surfaces in a tribology test, an algorithm was developed for automatic measurement of the contact area by optical means.......In connection with the use of brass specimens featuring structured surfaces in a tribology test, an algorithm was developed for automatic measurement of the contact area by optical means....

  5. Physicochemical properties of concentrated Martian surface waters

    Science.gov (United States)

    Tosca, Nicholas J.; McLennan, Scott M.; Lamb, Michael P.; Grotzinger, John P.

    2011-05-01

    Understanding the processes controlling chemical sedimentation is an important step in deciphering paleoclimatic conditions from the rock records preserved on both Earth and Mars. Clear evidence for subaqueous sedimentation at Meridiani Planum, widespread saline mineral deposits in the Valles Marineris region, and the possible role of saline waters in forming recent geomorphologic features all underscore the need to understand the physical properties of highly concentrated solutions on Mars in addition to, and as a function of, their distinct chemistry. Using thermodynamic models predicting saline mineral solubility, we generate likely brine compositions ranging from bicarbonate-dominated to sulfate-dominated and predict their saline mineralogy. For each brine composition, we then estimate a number of thermal, transport, and colligative properties using established models that have been developed for highly concentrated multicomponent electrolyte solutions. The available experimental data and theoretical models that allow estimation of these physicochemical properties encompass, for the most part, much of the anticipated variation in chemistry for likely Martian brines. These estimates allow significant progress in building a detailed analysis of physical sedimentation at the ancient Martian surface and allow more accurate predictions of thermal behavior and the diffusive transport of matter through chemically distinct solutions under comparatively nonstandard conditions.

  6. Concentrations of selected constituents in surface-water and streambed-sediment samples collected from streams in and near an area of oil and natural-gas development, south-central Texas, 2011-13

    Science.gov (United States)

    Opsahl, Stephen P.; Crow, Cassi L.

    2014-01-01

    During 2011–13, the U.S. Geological Survey, in cooperation with the San Antonio River Authority and the Guadalupe-Blanco River Authority, analyzed surface-water and streambed-sediment samples collected from 10 sites in the San Antonio River Basin to provide data for a broad range of constituents that might be associated with hydraulic fracturing and the produced waters that are a consequence of hydraulic fracturing. Among surface-water samples, all sulfide concentrations were less than the method detection limit of 0.79 milligrams per liter. Four glycols—diethylene glycol, ethylene glycol, propylene glycol, and triethylene glycol—were analyzed for in surface-water samples collected for this study, and none were detected. Of the 91 semivolatile organic compounds analyzed for this study, there were six detections, all but one of which were in storm-runoff samples. The base-flow sample collected at the San Antonio River at Goliad, Tex. (SAR Goliad), site contained bis(2-ethylhexyl) phthalate, a plasticizer in polyvinyl chloride and a constituent in hydraulic fracturing fluids. The storm-runoff samples collected at the San Antonio River near Elmendorf, Tex. (SAR Elmendorf), and Ecleto Creek at County Road 326 near Runge, Tex. (Ecleto 2), sites also contained bis(2-ethylhexyl) phthalate. The storm-runoff sample collected at the SAR Elmendorf site contained the plasticizer diethyl phthalate. Both storm-runoff samples collected at the Ecleto Creek near Runge, Tex. (Ecleto 1), and Ecleto 2 sites contained benzyl alcohol, a solvent commonly used in paints. Of the 67 volatile organic compounds analyzed in this study, there were a total of six detections, all of which were in base-flow samples. The surface-water sample collected at the SAR Elmendorf site contained bromodichloromethane, dibromochloromethane, and trichloromethane, all of which are disinfection byproducts associated with the chlorination of municipal water supplies and of treated municipal wastewater. The

  7. Surface moisture estimation in urban areas

    Science.gov (United States)

    Jiang, Yitong

    Surface moisture is an important parameter because it modifies urban microclimate and surface layer meteorology. The primary objectives of this paper are: 1) to analyze the impact of surface roughness from buildings on surface moisture in urban areas; and 2) to quantify the impact of surface roughness resulting from urban trees on surface moisture. To achieve the objectives, two hypotheses were tested: 1) the distribution of surface moisture is associated with the structural complexity of buildings in urban areas; and 2) The distribution and change of surface moisture is associated with the distribution and vigor of urban trees. The study area is Indianapolis, Indiana, USA. In the part of the morphology of urban trees, Warren Township was selected due to the limitation of tree inventory data. To test the hypotheses, the research design was made to extract the aerodynamic parameters, such as frontal areas, roughness length and displacement height of buildings and trees from Terrestrial and Airborne LiDAR data, then to input the aerodynamic parameters into the urban surface energy balance model. The methodology was developed for comparing the impact of aerodynamic parameters from LiDAR data with the parameters that were derived empirically from land use and land cover data. The analytical procedures are discussed below: 1) to capture the spatial and temporal variation of surface moisture, daily and hourly Land Surface Temperature (LST) were downscaled from 4 km to 1 km, and 960 m to 30 m, respectively, by regression between LST and various components that impact LST; 2) to estimate surface moisture, namely soil moisture and evapotranspiration (ET), land surfaces were classified into soil, vegetation, and impervious surfaces, using Linear Spectral Mixture Analysis (LSMA); 3) aerodynamic parameters of buildings and trees were extracted from Airborne and Terrestrial LiDAR data; 4) the Temperature-Vegetation-Index (TVX) method, and the Two-Source-Energy-Balance (TSEB

  8. Heavy metal concentration of settled surface dust in residential building

    International Nuclear Information System (INIS)

    Nor Aimi abdul Wahab; Fairus Muhamad Darus; Norain Isa; Siti Mariam Sumari; Nur Fatihah Muhamad Hanafi

    2012-01-01

    The concentrations of heavy metals (Cu, Ni, Pb and Zn) in settled surface dust were collected from nine residential buildings in different areas in Seberang Prai Tengah District, Pulau Pinang. The samples of settled surface dust were collected in 1 m 2 area by using a polyethylene brush and placed in the dust pan by sweeping the living room floor most accessible to the occupants. Heavy metals concentrations were determined by using inductively coupled plasma optical emission spectrometer (ICP-OES) after digestion with nitric acid and sulphuric acid. The results show that the range of heavy metals observed in residential buildings at Seberang Prai Tengah were in the range of 2.20-14.00 mg/ kg, 1.50-32.70 mg/ kg, 1.50-76.80 mg/ kg and 14.60-54.40 mg/ kg for Cu, Ni, Pb and Zn respectively. The heavy metal concentration in the investigated areas followed the order: Pb > Zn > Ni > Cu. Statistical analysis indicates significant correlation between all the possible pairs of heavy metal. The results suggest a likely common source for the heavy metal contamination, which could be traced most probably to vehicular emissions, street dust and other related activities. (author)

  9. Measurement of local interfacial area concentration in boiling loop

    International Nuclear Information System (INIS)

    Kyoung, Ho Kang; Byong, Jo Yun; Goon, Cherl Park

    1995-01-01

    An accurate prediction of two-phase flow is essential to many energy systems, including nuclear reactors. To model the two-phase flow, detailed information on the internal flow structure is required. The void fraction and interfacial area concentration are important fundamental parameters characterizing the internal structure of two-phase flow. The interfacial area concentration is defined as the available interfacial area per unit volume of the two-phase mixture in calculations of the interfacial transport of mass, momentum, and energy. Although a number of studies have been made in this area, the interfacial area concentration in two-phase flow has not been sufficiently investigated either experimentally or analytically. Most existing models for interfacial area concentration are limited to area-averaged interfacial area concentration in a flow channel. And the studies on local interfacial area concentration are limited to the case of air-water two-phase flow. However, the internal flow structure of steam-water two-phase flow having various bubble sizes could be quite different from that of air-water two-phase flow, the reliability of which weak in practical applications. In this study, the local interfacial area concentration steam-water two-phase flow has been investigated experimentally in a circular boiling tube having a heating rod in the center, and for the low flow with liquid superficial velocity <1 m/s

  10. Monitoring System for ALICE Surface Areas

    CERN Document Server

    Demirbasci, Oguz

    2016-01-01

    I have been at CERN for 12 weeks within the scope of Summer Student Programme working on a monitoring system project for surface areas of the ALICE experiment during this period of time. The development and implementation of a monitoring system for environmental parameters in the accessible areas where a cheap hardware setup can be deployed were aim of this project. This report explains how it was developed by using Arduino, Raspberry PI, WinCC OA and DIM protocol.

  11. Volumes and surface areas of pendular rings

    Science.gov (United States)

    Rose, W.

    1958-01-01

    A packing of spheres is taken as a suitable model of porous media. The packing may be regular and the sphere size may be uniform, but in general, both should be random. Approximations are developed to give the volumes and surface areas of pendular rings that exist at points of sphere contact. From these, the total free volume and interfacial specific surface area are derived as expressive of the textural character of the packing. It was found that the log-log plot of volumes and surface areas of pendular rings vary linearly with the angle made by the line joining the sphere centers and the line from the center of the largest sphere to the closest edge of the pendular ring. The relationship, moreover, was found not to be very sensitive to variation in the size ratio of the spheres in contact. It also was found that the addition of pendular ring material to various sphere packings results in an unexpected decrease in the surface area of the boundaries that confine the resulting pore space. ?? 1958 The American Institute of Physics.

  12. Estimating surface area in early hominins.

    Directory of Open Access Journals (Sweden)

    Alan Cross

    Full Text Available Height and weight-based methods of estimating surface area have played an important role in the development of the current consensus regarding the role of thermoregulation in human evolution. However, such methods may not be reliable when applied to early hominins because their limb proportions differ markedly from those of humans. Here, we report a study in which this possibility was evaluated by comparing surface area estimates generated with the best-known height and weight-based method to estimates generated with a method that is sensitive to proportional differences. We found that the two methods yield indistinguishable estimates when applied to taxa whose limb proportions are similar to those of humans, but significantly different results when applied to taxa whose proportions differ from those of humans. We also found that the discrepancy between the estimates generated by the two methods is almost entirely attributable to inter-taxa differences in limb proportions. One corollary of these findings is that we need to reassess hypotheses about the role of thermoregulation in human evolution that have been developed with the aid of height and weight-based methods of estimating body surface area. Another is that we need to use other methods in future work on fossil hominin body surface areas.

  13. Osmosis and Surface Area to Volume Ratio.

    Science.gov (United States)

    Barrett, D. R. B.

    1984-01-01

    Describes an experiment designed to help students understand the concepts of osmosis and surface area to volume ratio (SA:VOL). The task for students is to compare water uptake in different sizes of potato cubes and relate differences to their SA:VOL ratios. (JN)

  14. On semiautomatic estimation of surface area

    DEFF Research Database (Denmark)

    Dvorak, J.; Jensen, Eva B. Vedel

    2013-01-01

    . For convex particles, the estimator is equal to four times the area of the support set (flower set) of the particle transect. We study the statistical properties of the flower estimator and compare its performance to that of two discretizations of the flower estimator, namely the pivotal estimator......In this paper, we propose a semiautomatic procedure for estimation of particle surface area. It uses automatic segmentation of the boundaries of the particle sections and applies different estimators depending on whether the segmentation was judged by a supervising expert to be satisfactory....... If the segmentation is correct the estimate is computed automatically, otherwise the expert performs the necessary measurements manually. In case of convex particles we suggest to base the semiautomatic estimation on the so-called flower estimator, a new local stereological estimator of particle surface area...

  15. Characterization of high surface area silicon oxynitrides

    International Nuclear Information System (INIS)

    Lednor, P.W.; DeRuiter, R.; Emeis, K.A.

    1992-01-01

    In heterogenous catalysis, liquid or gaseous feedstocks are converted over a solid catalyst into more desirable products. Such processes form an essential part of the oil and petrochemical industries. The solid catalyst usually consists of an inorganic phase, with or without metal particles on the surface. Examples include platinum particles on gamma alumina (a reforming catalyst used in oil processing), chromium particles on silica (an ethylene polymerization catalyst) and zeolites or amorphous silica-aluminas (used as solid acids).Oxides have been widely investigated in catalysis, and silica, alumina, and aluminosilicates find application commercially on a large scale. On the other hand, non-oxide materials such as nitrides, carbides and borides have been relatively little investigated. The main reason for this has been the lack of routes to the high surface area forms usually required in catalysis. However, this situation has changed significantly in recent years, due to the interest in high surface area non-oxides as precursors to fully dense ceramics; in this paper, the authors have reviewed synthetic routes to high surface area non-oxides

  16. High Surface Area Tunnels in Hexagonal WO₃.

    Science.gov (United States)

    Sun, Wanmei; Yeung, Michael T; Lech, Andrew T; Lin, Cheng-Wei; Lee, Chain; Li, Tianqi; Duan, Xiangfeng; Zhou, Jun; Kaner, Richard B

    2015-07-08

    High surface area in h-WO3 has been verified from the intracrystalline tunnels. This bottom-up approach differs from conventional templating-type methods. The 3.67 Å diameter tunnels are characterized by low-pressure CO2 adsorption isotherms with nonlocal density functional theory fitting, transmission electron microscopy, and thermal gravimetric analysis. These open and rigid tunnels absorb H(+) and Li(+), but not Na(+) in aqueous electrolytes without inducing a phase transformation, accessing both internal and external active sites. Moreover, these tunnel structures demonstrate high specific pseudocapacitance and good stability in an H2SO4 aqueous electrolyte. Thus, the high surface area created from 3.67 Å diameter tunnels in h-WO3 shows potential applications in electrochemical energy storage, selective ion transfer, and selective gas adsorption.

  17. Estimation of surface area and surface area measure of three-dimensional sets from digitizations

    DEFF Research Database (Denmark)

    Ziegel, Johanna; Kiderlen, Markus

    2010-01-01

    A local method for estimating surface area and surface area measure of three-dimensional objects from discrete binary images is presented. A weight is assigned to each 2 × 2 × 2 configuration of voxels and the total surface area of an object is given by summation of the local area contributions....... The method is based on an exact asymptotic result that holds for increasing resolution of the digitization. It states that the number of occurrences of a 2 ×  2 × 2 configuration is asymptotically proportional to an integral of its “h-function” with respect to the surface area measure of the object. We find...

  18. High surface area fibrous silica nanoparticles

    KAUST Repository

    Polshettiwar, Vivek

    2014-11-11

    Disclosed are high surface area nanoparticles that have a fibrous morphology. The nanoparticles have a plurality of fibers, wherein each fiber is in contact with one other fiber and each fiber has a length of between about 1 nm and about 5000 nm. Also disclosed are applications of the nanoparticles of the present invention, and methods of fabrication of the nanoparticles of the present invention.

  19. Surface sampling concentration and reaction probe

    Science.gov (United States)

    Van Berkel, Gary J; Elnaggar, Mariam S

    2013-07-16

    A method of analyzing a chemical composition of a specimen is described. The method can include providing a probe comprising an outer capillary tube and an inner capillary tube disposed co-axially within the outer capillary tube, where the inner and outer capillary tubes define a solvent capillary and a sampling capillary in fluid communication with one another at a distal end of the probe; contacting a target site on a surface of a specimen with a solvent in fluid communication with the probe; maintaining a plug volume proximate a solvent-specimen interface, wherein the plug volume is in fluid communication with the probe; draining plug sampling fluid from the plug volume through the sampling capillary; and analyzing a chemical composition of the plug sampling fluid with an analytical instrument. A system for performing the method is also described.

  20. The Relationship between Gastric Juice Nitrate/Nitrite Concentrations and Gastric Mucosal Surface pH

    OpenAIRE

    Lee, Hae Kyung; Kim, Hyunjung; Kim, Hyung-Keun; Cho, Young-Seok; Kim, Byung-Wook; Han, Sok-Won; Maeng, Lee So; Chae, Hiun-Suk; Kim, Hee Na

    2012-01-01

    Purpose To investigate gastric juice nitrate/nitrite concentration according to mucosal surface pH extent (area) of gastric corpus intimately contacting the gastric juice. Materials and Methods We included ninety-nine patients with dyspepsia. To evaluate gastric mucosal surface pH and its extent, gastric chromosocpy was performed by spraying phenol red dye on the corpus mucosa and estimating the extent of area with color changed. Nitrate/nitrite concentrations and pH of gastric juice were mea...

  1. Storm water runoff concentration matrix for urban areas

    Science.gov (United States)

    Göbel, P.; Dierkes, C.; Coldewey, W. G.

    2007-04-01

    The infrastructure (roads, sidewalk, commercial and residential structures) added during the land development and urbanisation process is designed to collect precipitation and convey it out of the watershed, typically in existing surface water channels, such as streams and rivers. The quality of surface water, seepage water and ground water is influenced by pollutants that collect on impervious surfaces and that are carried by urban storm water runoff. Heavy metals, e.g. lead (Pb), zinc (Zn), copper (Cu), cadmium (Cd), polycyclic aromatic hydrocarbons (PAH), mineral oil hydrocarbons (MOH) and readily soluble salts in runoff, contribute to the degradation of water. An intensive literature search on the distribution and concentration of the surface-dependent runoff water has been compiled. Concentration variations of several pollutants derived from different surfaces have been averaged. More than 300 references providing about 1300 data for different pollutants culminate in a representative concentration matrix consisting of medians and extreme values. This matrix can be applied to long-term valuations and numerical modelling of storm water treatment facilities.

  2. A Simple Proof of Cauchy's Surface Area Formula

    OpenAIRE

    Tsukerman, Emmanuel; Veomett, Ellen

    2016-01-01

    We give a short and simple proof of Cauchy's surface area formula, which states that the average area of a projection of a convex body is equal to its surface area up to a multiplicative constant in the dimension.

  3. Concentration of plutonium in desert plants from contaminated area

    International Nuclear Information System (INIS)

    Xu Hui; Jin Yuren; Tian Mei; Li Weiping; Zeng Ke; Wang Yaoqin; Wang Yu

    2012-01-01

    The investigation of plutonium in desert plants from contaminated sites contributes to the evaluation of its pollution situation and to the survey of plutonium hyper accumulator. The concentration of 239 Pu in desert plants collected from a contaminated site was determined, and the influence factors were studied. The concentration of 239 Pu in plants was (1.8±4.9) Bq/kg in dry weight, and it means that the plants were contaminated, moreover, the resuspension results in dramatic plutonium pollution of plant surface. The concentration of plutonium in plants depends on species, live stages and the content of plutonium in the rhizosphere soil. The concentration of plutonium in herbage is higher than that in woody plant, and for the seven species of desert plants investigated, it decreases in the order of Hexinia polydichotoma, Phragmites australis, Halostashys caspica, Halogeton arachnoideus, Lycium ruthenicum, Tamarix hispida and Calligonum aphyllum. (authors)

  4. Natural variability in the surface ocean carbonate ion concentration

    OpenAIRE

    N. S. Lovenduski; M. C. Long; K. Lindsay

    2015-01-01

    We investigate variability in the surface ocean carbonate ion concentration ([CO32−]) on the basis of a long control simulation with a fully-coupled Earth System Model. The simulation is run with a prescribed, pre-industrial atmospheric CO2 concentration for 1000 years, permitting investigation of natural [CO32−] variability on interannual to multi-decadal timescales. We find high interannual variability in surface [CO32−] in the tropical...

  5. Natural variability in the surface ocean carbonate ion concentration

    OpenAIRE

    Lovenduski, N. S.; Long, M. C.; Lindsay, K.

    2015-01-01

    We investigate variability in the surface ocean carbonate ion concentration ([CO32−]) on the basis of a~long control simulation with an Earth System Model. The simulation is run with a prescribed, pre-industrial atmospheric CO2 concentration for 1000 years, permitting investigation of natural [CO32−] variability on interannual to multi-decadal timescales. We find high interannual variability in surface [CO32−] in the tropical Pacific and ...

  6. Study of a Greek area with enhanced indoor radon concentrations

    International Nuclear Information System (INIS)

    Louizi, A.; Nikolopoulos, D.; Koukouliou, V.; Kehagia, K.

    2003-01-01

    In this paper the focus is on Arnea Chalkidikis, an area in Greece with granitic geological background and indications of possible elevated radon concentration indoors. Data are reported of indoor radon measurements with etched track detectors and those used for dosimetric estimations. Moreover, data are reported on soil gas and soil radon concentrations in Arnea, as well as radon and uranium concentrations in water samples. From the measured radon concentrations in water samples the contribution to the overall dose has been calculated. For a period of 1 month, indoor radon and progeny activity has also been monitored in the dwelling that has the maximum indoor radon concentration in Greece. This dwelling is in Arnea and the dose delivered to the inhabitants has been calculated. Mean annual effective dose due to indoor radon was 4.5 mSv and about 11% of this was due to the use of water. Mean soil gas concentration and soil radon concentration were (90 ± 30) kBq m -3 (P -3 (P -1 (P<0.05). (author)

  7. Assessment of heavy metals (Cd and Pb) and micronutrients (Cu, Mn, and Zn) of paddy (Oryza sativa L.) field surface soil and water in a predominantly paddy-cultivated area at Puducherry (Pondicherry, India), and effects of the agricultural runoff on the elemental concentrations of a receiving rivulet.

    Science.gov (United States)

    Reddy, M Vikram; Satpathy, Deepmala; Dhiviya, K Shyamala

    2013-08-01

    The concentrations of toxic heavy metals-Cd and Pb and micronutrients-Cu, Mn, and Zn were assessed in the surface soil and water of three different stages of paddy (Oryza sativa L.) fields, the stage I-the first stage in the field soon after transplantation of the paddy seedlings, holding adequate amount of water on soil surface, stage II-the middle stage with paddy plants of stem of about 40 cm length, with sufficient amount of water on the soil surface, and stage III-the final stage with fully grown rice plants and very little amount of water in the field at Bahour, a predominantly paddy cultivating area in Puducherry located on the southeast Coast of India. Comparison of the heavy metal and micronutrient concentrations of the soil and water across the three stages of paddy field showed their concentrations were significantly higher in soil compared with that of water (p  Mn > Zn > Cu > Pb indicating concentration of Cd was maximum and Pb was minimum. The elemental concentrations in both soil and water across the three stages showed a ranking order of stage II > stage III > stage I. The runoff from the paddy fields has affected the elemental concentrations of the water and sediment of an adjacent receiving rivulet.

  8. [Near surface CO2 concentration and its quantitative relationship with character of underlying surface in Shanghai City, China].

    Science.gov (United States)

    Pan, Chen; Zhu, Xi-yang; Jia, Wen-xiao; Yang, Fang; Liu, Ming; Xiang, Wei-ning

    2015-07-01

    Land use change and fossil fuel combustion due to urbanization have a significant effect on global carbon cycle and climate change. It's important to have an explicit understanding of the spatial distribution of CO2 to recognize and control GHG emission, which is helpful to reduce human-induced contribution to global climate change. The study area of this project was set in the city of Shanghai with intensive human activity and rapid urbanization. The monitoring of near surface CO2 concentration along 3 transects was conducted across an urban-rural gradient by means of near infrared gas analyzer Li-840A in spring, 2014. Remote sensing data were also used to derive underlying surface information. Further quantitative analysis of the mechanism of CO2 concentration's response to the characteristics of underlying surface was presented in this paper. The results showed that the average near surface CO2 concentration was (443.4±22.0) µmol . mol-1. CO2 concentration in city center was in average 12.5% (52.5 µLmol . mol-1) higher than that in the suburban area. Also, CO2 concentration showed a significant spatial differentiation, with the highest CO2 concentration in the northwest, the second highest in the southwest, and the lowest in the southeast, which was in accordance with the urbanization level of the underlying surface. The results revealed that the vegetation coverage rate (CVeg) was an important indicator to describe near surface CO2 concentration with a negative correlation, and the impervious surface area coverage rate (CISA) had lower explanatory power with a positive correlation. The study also found that the determination coefficient (R2) between CO2 concentration (CCO2) and CISA or CVeg achieved its highest value when the buffer distance was 5 km, and their quantitative relationships be described by a stepwise regression equation: CCO2=0.32CISA-0.89CVeg+445.13 (R2 =0.66, P<0.01).

  9. Efficiency of a concentric matrix track detector surface scanning

    International Nuclear Information System (INIS)

    Bek-Uzarov, Dj.; Nikezic, D.; Kostic, D.; Krstic, D.; Cuknic, O.

    1995-01-01

    Heavy particle ionizing radiation track counting on the surface of a solid state round surface detector is made using the microscope and scanning step by step by a round field of vision. The whole solid state detector surface could not be fully or completely covered by round fields of visions. Therefore detector surface could be divided on the two parts, the larger surface, being under fields of vision, really scanned and no scanned missed or omitted surface. The ratio between omitted and scanned surfaces is so called track scanning efficiency. The knowledge of really counted, or scanned surface is a important value for evaluating the real surface track density an exposed solid state track detector. In the paper a matrix of a concentric field of vision made around the first microscope field of vision placed in center of the round disc of the scanned track detector is proposed. In a such scanning matrix the real scanned surface could be easy calculated and by the microscope scanning made as well. By this way scanned surface is very precisely obtained as well. Precise knowledge of scanned and omitted surface allows to obtain more precise scanning efficiency factor as well as real surface track density, the main parameter in solid state track detection measurements. (author)

  10. Indoor radon concentration in some earthquake prone areas of Haryana

    International Nuclear Information System (INIS)

    Kant, Krishan

    2005-01-01

    The problem of radon is an important global problem and the radon and its progeny are a major source of natural radiation exposure and contribute to more than 50% of the dose equivalent received by general population from all sources of radiation, both naturally occurring and man-made. In view of the above fact, the measurement of radon concentration levels in dwellings is of fundamental importance from health and hygiene point of view. Keeping this in view, alpha active pollutant (radon, thoron and their progeny) concentration inside the dwellings in earthquake prone districts of Haryana was measured using LR-115, Type II Plastic track detectors. Radon concentration and inhalation dose rates to the inhabitants in this area have been calculated. Results of various measurements on the radon and its progeny concentration, annual exposure and annual inhalation dose received by the workers have been reported. The calculated values of potential alpha energy concentration (PAEC), radon levels (EEC), annual exposure and annual inhalation dose in the dwellings of earthquake prone districts of Haryana varied from 2.76 mWL to 13.41 mWL with an average of 5.60 ± 0.76 mWL, 25.5 Bq m -3 to 124 Bq m -3 with an average of 51.78 ± 7.04 Bq m -3 , 0.11 WLM to 0.56 WLM with an average of 0.23 ± 0.03 WLM and 0.44 mSv to 2.13 mSv with an average of 0.88 ± 0.12 mSv respectively. The radon concentrations were found to be higher in these areas as compared to the studies carried out earlier in other parts of the state. (author)

  11. Method for treatment of a surface area of steel

    NARCIS (Netherlands)

    Bhowmik, S.; Aaldert, P.J.

    2009-01-01

    The invention relates to a method for treatment of a surface area of steel by polishing said surface area and performing a plasma treatment of said surface area wherein the plasma treatment is performed at at least atmospheric conditions and wherein the plasma treatment is carried out at a power of

  12. Concentration polarization, surface currents, and bulk advection in a microchannel

    DEFF Research Database (Denmark)

    Nielsen, Christoffer Peder; Bruus, Henrik

    2014-01-01

    We present a comprehensive analysis of salt transport and overlimiting currents in a microchannel during concentration polarization. We have carried out full numerical simulations of the coupled Poisson-Nernst-Planck-Stokes problem governing the transport and rationalized the behavior of the syst...... as in the limit of negligible surface charge. By including the effects of diffusion and advection in the diffuse part of the electric double layers, we extend a recently published analytical model of overlimiting current due to surface conduction....

  13. Surface areas of fractally rough particles studied by scattering

    International Nuclear Information System (INIS)

    Hurd, A.J.; Schaefer, D.W.; Smith, D.M.; Ross, S.B.; Le Mehaute, A.; Spooner, S.

    1989-01-01

    The small-angle scattering from fractally rough surfaces has the potential to give information on the surface area at a given resolution. By use of quantitative neutron and x-ray scattering, a direct comparison of surface areas of fractally rough powders was made between scattering and adsorption techniques. This study supports a recently proposed correction to the theory for scattering from fractal surfaces. In addition, the scattering data provide an independent calibration of molecular adsorbate areas

  14. Surface ozone in the urban area of Manaus, Amazonas, Brazil

    Science.gov (United States)

    Souza, R. A. F. D.; Costa, P. S.; Silva, C.; Godoi, R. M.; Martin, S. T.; Tota, J.; Barbosa, H. M.; Pauliquevis, T.; Ferreira De Brito, J.; Artaxo, P.; Manzi, A. O.; Wolf, S. A.; Cirino, G. G.

    2014-12-01

    When nitrogen oxides from vehicle and industrial emissions mix with volatile organic compounds from trees and plants with exposure to sunlight, a chemical reaction occurs contributing to ground-level ozone pollution. The preliminary results of the surface ozone study in urban area of Manaus, Amazonas State, Brazil, are presented for the first intensive operating period (IOP1) of the GoAmazon experiment (February/March 2014). Photochemical ozone production was found to be a regular process, with an afternoon maximum of the ozone mixing ratio of lower than 20 ppbv for cloudy days or clear sky weather. Typical ozone concentrations at mid-day were low (about 10 ppb). On the other hand, several high-value ozone episodes with surface ozone mixing ratios up to three times larger were registered during the dry season of 2013 (September/October). At the beginning of the wet season, the ozone concentration in Manaus decreased significantly, but diurnal variations can be found during the days with rainfall and other fast changes of meteorological conditions. Possible explanations of the nature of pulsations are discussed. Photochemical ozone production by local urban plumes of Manaus is named as a first possible source of the ozone concentration and biomass burning or power plant emissions are suggested as an alternative or an additional source.

  15. Nondestructive, stereological estimation of canopy surface area

    DEFF Research Database (Denmark)

    Wulfsohn, Dvora-Laio; Sciortino, Marco; Aaslyng, Jesper M.

    2010-01-01

    a canopy using the smooth fractionator, (ii) sampling of leaves from the selected plants using the fractionator, and (iii) area estimation of the sampled leaves using point counting. We apply this procedure to estimate the total area of a chrysanthemum (Chrysanthemum morifolium L.) canopy and evaluate both...

  16. Surface texturing of crystalline silicon and effective area measurement

    Science.gov (United States)

    Sun, Tietun; Chen, Dong; Chui, Rongqiang

    2000-11-01

    In this paper, the surface area of solar cell is determined by the capacitance measurements of MOS structure. The texture etching technology can be controlled according to the change of silicon surface area, furthermore, the textured silicon surface and interface characteristic of solar cell can be studied by measuring the relationship of capacitance and voltage for MOS structure.

  17. Hand surface area as a percentage of body surface area in Asian children: a pilot study.

    Science.gov (United States)

    Choi, Hyuk; Park, Man Sik; Lee, Heung-Man

    2011-09-01

    The hand surface area (HSA) of one hand has been estimated as 1% of the body surface area (BSA). This does change with the patient's age, gender, and body mass index (BMI). There are many HSA studies done on adult populations, but fewer done on children. Our hypothesis in this study is that the general HSA equation for Caucasian adults cannot be applied as accurately to children and Asian people. HSA was defined as the area of the palm without fingers in this study. Children are in a stage of growth. If a child's hand growth ratio is not the same as that of an adult, the result of HSA/BSA calculation could be different. We undertook this study to determine whether or not there were any differences in HSA/BSA among Korean children (7-18 years) and adults (20-60 years), and compared our results with western data. A total of 186 boys aged between 7 and 18 years, were recruited for this study; their HSA was measured, directly. A total of 186 adults aged between 20 and 60 years were selected as well. BSA was calculated only for volunteers in subjects who HSA had been measured. From these results, HSA/BSA was calculated. HSA/BSA ratio of Korean boys was 0.69±0.05%, which was less than 1%. It is suggested that the ratio of the western data may not be applicable to Asian children, particularly, Korean children. HSA/BSA ratio can be applied in administration of drug doses and estimation of the area of burns. Copyright © 2011 Elsevier Ltd and ISBI. All rights reserved.

  18. Satellite constraints on surface concentrations of particulate matter

    Science.gov (United States)

    Ford Hotmann, Bonne

    Because of the increasing evidence of the widespread adverse effects on human health from exposure to poor air quality and the recommendations of the World Health Organization to significantly reduce PM2.5 in order to reduce these risks, better estimates of surface air quality globally are required. However, surface measurements useful for monitoring particulate exposure are scarce, especially in developing countries which often experience the worst air pollution. Therefore, other methods are necessary to augment estimates in regions with limited surface observations. The prospect of using satellite observations to infer surface air quality is attractive; however, it requires knowledge of the complicated relationship between satellite-observed aerosol optical depth (AOD) and surface concentrations. This dissertation explores how satellite observations can be used in conjunction with a chemical transport model (GEOS-Chem) to better understand this relationship. First, we investigate the seasonality in aerosols over the Southeastern United States using observations from several satellite instruments (MODIS, MISR, CALIOP) and surface network sites (IMPROVE, SEARCH, AERONET). We find that the strong summertime enhancement in satellite-observed aerosol optical depth (factor 2-3 enhancement over wintertime AOD) is not present in surface mass concentrations (25-55% summertime enhancement). Goldstein et al. [2009] previously attributed this seasonality in AOD to biogenic organic aerosol; however, surface observations show that organic aerosol only accounts for ~35% of PM2.5 mass and exhibits similar seasonality to total surface PM2.5. The GEOS-Chem model generally reproduces these surface aerosol measurements, but under represents the AOD seasonality observed by satellites. We show that seasonal differences in water uptake cannot sufficiently explain the magnitude of AOD increase. As CALIOP profiles indicate the presence of additional aerosol in the lower troposphere

  19. SurfaceWater Source Protection Areas (SPAs)

    Data.gov (United States)

    Vermont Center for Geographic Information — Source Protection Area (SPA) boundaries have been located on RF 24000 & RF 25000 scale USGS topographic maps by Water Supply Division (DEC) and VT Dept of Health...

  20. Concentration of involatile salts at evaporating water surfaces

    International Nuclear Information System (INIS)

    Gardner, G.C.

    1988-02-01

    Safety cases for the PWR often need to know how much of the soluble salts in the water will evaporate with the steam during flashing and when the steam is discharged to the atmosphere. Some ideal evaporating systems to give guidance. Simple formulae are derived for the surface concentration relative to the bulk concentration. An analysis is also presented which derives a formula for the mass transfer process in the steam due to both diffusion and convection, which arises from the evaporation process. The convection process will usually dominate. (author)

  1. The Surface Chemical Properties of Novel High Surface Area Solids ...

    African Journals Online (AJOL)

    fired power stations in South Africa by hydrothermal treatment of the raw ash with concentrated aqueous NaOH solutions. The zeolite was then further modified by acid leaching at elevated temperatures. This resulted in the formation of a novel ...

  2. The Surface Chemical Properties of Novel High Surface Area Solids ...

    African Journals Online (AJOL)

    during zeolite synthesis.22 Because raw fly ash has large quanti- ties of a host of elements, many of these will act as nucleation sites, which results in many small crystals rather than a few large ones. Acid etching removed the needle-like structures on the particle surfaces, revealing a porous underlying structure. (Fig. 1c).

  3. Lead concentrations and risk exposure assessment in surface soils ...

    African Journals Online (AJOL)

    This study investigated lead concentrations in < 250 μm and < 75 μm of deposited dust and< 2000 μm, < 250 μm, and < 75 μm of surface soils at undeveloped residential lands leased to auto-mechanic artisans for a minimum of ten years and estimated exposure risk for children that will reside on the polluted lands after the ...

  4. Natural variability in the surface ocean carbonate ion concentration

    Directory of Open Access Journals (Sweden)

    N. S. Lovenduski

    2015-11-01

    Full Text Available We investigate variability in the surface ocean carbonate ion concentration ([CO32−] on the basis of a~long control simulation with an Earth System Model. The simulation is run with a prescribed, pre-industrial atmospheric CO2 concentration for 1000 years, permitting investigation of natural [CO32−] variability on interannual to multi-decadal timescales. We find high interannual variability in surface [CO32−] in the tropical Pacific and at the boundaries between the subtropical and subpolar gyres in the Northern Hemisphere, and relatively low interannual variability in the centers of the subtropical gyres and in the Southern Ocean. Statistical analysis of modeled [CO32−] variance and autocorrelation suggests that significant anthropogenic trends in the saturation state of aragonite (Ωaragonite are already or nearly detectable at the sustained, open-ocean time series sites, whereas several decades of observations are required to detect anthropogenic trends in Ωaragonite in the tropical Pacific, North Pacific, and North Atlantic. The detection timescale for anthropogenic trends in pH is shorter than that for Ωaragonite, due to smaller noise-to-signal ratios and lower autocorrelation in pH. In the tropical Pacific, the leading mode of surface [CO32−] variability is primarily driven by variations in the vertical advection of dissolved inorganic carbon (DIC in association with El Niño–Southern Oscillation. In the North Pacific, surface [CO32−] variability is caused by circulation-driven variations in surface DIC and strongly correlated with the Pacific Decadal Oscillation, with peak spectral power at 20–30-year periods. North Atlantic [CO32−] variability is also driven by variations in surface DIC, and exhibits weak correlations with both the North Atlantic Oscillation and the Atlantic Multidecadal Oscillation. As the scientific community seeks to detect the anthropogenic influence on ocean carbonate chemistry, these results

  5. Natural variability in the surface ocean carbonate ion concentration

    Science.gov (United States)

    Lovenduski, N. S.; Long, M. C.; Lindsay, K.

    2015-11-01

    We investigate variability in the surface ocean carbonate ion concentration ([CO32-]) on the basis of a~long control simulation with an Earth System Model. The simulation is run with a prescribed, pre-industrial atmospheric CO2 concentration for 1000 years, permitting investigation of natural [CO32-] variability on interannual to multi-decadal timescales. We find high interannual variability in surface [CO32-] in the tropical Pacific and at the boundaries between the subtropical and subpolar gyres in the Northern Hemisphere, and relatively low interannual variability in the centers of the subtropical gyres and in the Southern Ocean. Statistical analysis of modeled [CO32-] variance and autocorrelation suggests that significant anthropogenic trends in the saturation state of aragonite (Ωaragonite) are already or nearly detectable at the sustained, open-ocean time series sites, whereas several decades of observations are required to detect anthropogenic trends in Ωaragonite in the tropical Pacific, North Pacific, and North Atlantic. The detection timescale for anthropogenic trends in pH is shorter than that for Ωaragonite, due to smaller noise-to-signal ratios and lower autocorrelation in pH. In the tropical Pacific, the leading mode of surface [CO32-] variability is primarily driven by variations in the vertical advection of dissolved inorganic carbon (DIC) in association with El Niño-Southern Oscillation. In the North Pacific, surface [CO32-] variability is caused by circulation-driven variations in surface DIC and strongly correlated with the Pacific Decadal Oscillation, with peak spectral power at 20-30-year periods. North Atlantic [CO32-] variability is also driven by variations in surface DIC, and exhibits weak correlations with both the North Atlantic Oscillation and the Atlantic Multidecadal Oscillation. As the scientific community seeks to detect the anthropogenic influence on ocean carbonate chemistry, these results will aid the interpretation of trends

  6. Surface Area Distribution Descriptor for object matching

    Directory of Open Access Journals (Sweden)

    Mohamed F. Gafar

    2010-07-01

    Full Text Available Matching 3D objects by their similarity is a fundamental problem in computer vision, computer graphics and many other fields. The main challenge in object matching is to find a suitable shape representation that can be used to accurately and quickly discriminate between similar and dissimilar shapes. In this paper we present a new volumetric descriptor to represent 3D objects. The proposed descriptor is used to match objects under rigid transformations including uniform scaling. The descriptor represents the object by dividing it into shells, acquiring the area distribution of the object through those shells. The computed areas are normalised to make the descriptor scale-invariant in addition to rotation and translation invariant. The effectiveness and stability of the proposed descriptor to noise and variant sampling density as well as the effectiveness of the similarity measures are analysed and demonstrated through experimental results.

  7. Why Do We Need the Derivative for the Surface Area?

    Science.gov (United States)

    Hristova, Yulia; Zeytuncu, Yunus E.

    2016-01-01

    Surface area and volume computations are the most common applications of integration in calculus books. When computing the surface area of a solid of revolution, students are usually told to use the frustum method instead of the disc method; however, a rigorous explanation is rarely provided. In this note, we provide one by using geometric…

  8. Averaging of diffusing contaminant concentrations in atmosphere surface layer

    International Nuclear Information System (INIS)

    Ivanov, E.A.; Ramzina, T.V.

    1985-01-01

    Calculations permitting to average concentration fields of diffusing radioactive contaminant coming from the NPP exhaust stack in the atmospheric surface layer are given. Formulae of contaminant concentration field calculation are presented; it depends on the average wind direction value (THETA) for time(T) and stability of this direction (σsub(tgTHETA) or σsub(THETA)). Probability of wind direction deviation from the average value for time T is satisfactory described by the Gauss law. With instability increase in the atmosphere σ increases, when wind velocity increasing the values of σ decreases for all types of temperature gradients. Nonuniformity of σ value dependence on averaging time T is underlined, that requires accurate choice of σsub(tgTHETA) and σsub(THETA) parameters in calculations

  9. Lage-area planar RF plasma productions by surface waves

    International Nuclear Information System (INIS)

    Nonaka, S.

    1994-01-01

    Large-area rf plasmas are confirmed to be produced by means of RF discharges inside a large-area dielectric tube. The plasma space is 73 cm x 176 cm and 2.5 cm. The plasma is thought to be produced by an odd plasma-surface wave (PSW ο ) in case of using large-area electrodes and by an even plasma-surface wave (PSW ο ) in case of without the electrodes. (author). 7 refs, 4 figs

  10. Spatiotemporal analysis of the PM10 concentration over the Taranto area.

    Science.gov (United States)

    Pollice, Alessio; Jona Lasinio, Giovanna

    2010-03-01

    In this paper, an analysis of air quality data is provided for the municipal area of Taranto (southern Italy) characterized by high environmental risks as formally decreed by the Italian government in the 1990s with two administrative measures. This is due to the massive presence of industrial sites with elevated environmental impact activities along the NW boundary of the city conurbation. The aforementioned activities have effects on the environment and on public health, as a number of epidemiological researches concerning this area reconfirm. The present study is focused on particulate matter as measured by PM10 concentrations at 13 monitoring stations, equipped with analogous instruments based on the Beta absorption technology, either reporting hourly, two-hourly, or daily measurements. Daily estimates of the PM10 concentration surfaces are obtained in order to identify areas of higher concentration (hot spots), possibly related to specific anthropic activities. Preliminary analysis involved addressing several data problems: (1) due to the use of two different validation techniques, a calibration procedure was devised to allow for data comparability; (2) imputation techniques were considered to cope with the large number of missing data, due to both different working periods and occasional malfunctions of PM10 sensors; and (3) reliable weather covariates (wind speed and direction, pressure, temperature, etc.) were obtained and considered within the analysis. Spatiotemporal modelling was addressed by a Bayesian kriging-based model proposed by Le and Zidek (2006) characterized by the use of time varying covariates and a semiparametric covariance structure. Advantages and disadvantages of the model are highlighted and assessed in terms of fit and performance. Estimated daily PM10 concentration surfaces are suitable for the interpretation of time trends and for identifying concentration peaks within the urban area.

  11. Estimates of surface methane emissions over Europe using observed surface concentrations and the FLEXPART trajectory model

    Science.gov (United States)

    Weaver, C. J.; Kiemle, C.; Kawa, S. R.; Aalto, T.; Necki, J.; Steinbacher, M.; Arduini, J.; Apadula, F.; Berkhout, H.; Hatakka, J.; O'Doherty, S.

    2013-12-01

    We use surface methane observations from nine European ground stations, and the FLEXPART Lagrangian transport model to obtain surface methane emissions for 2010. Our inversion shows the strongest emissions from the Netherlands and the coal mines in Upper Silesia Poland. This is qualitatively consistent with the EDGAR surface flux inventory. We also report significant surface fluxes from wetlands in southern Finland during July and August and reduced wetland fluxes later in the year. Our simulated methane surface concentration captures at least half of the daily variability in the observations, suggesting that the transport model is correctly simulating the regional transport pathways over Europe. We also use our trajectory model to determine whether future space-based remote sensing instruments (MERLIN) will be able to detect both natural and anthropogenic changes in the surface flux strengths.

  12. Indexing aortic valve area by body surface area increases the prevalence of severe aortic stenosis

    DEFF Research Database (Denmark)

    Jander, Nikolaus; Gohlke-Bärwolf, Christa; Bahlmann, Edda

    2014-01-01

    To account for differences in body size in patients with aortic stenosis, aortic valve area (AVA) is divided by body surface area (BSA) to calculate indexed AVA (AVAindex). Cut-off values for severe stenosis are......To account for differences in body size in patients with aortic stenosis, aortic valve area (AVA) is divided by body surface area (BSA) to calculate indexed AVA (AVAindex). Cut-off values for severe stenosis are...

  13. Concentration of Heavy Metals in Drinking Water from Urban Areas ...

    African Journals Online (AJOL)

    Bheema

    ABSTRACT. The study was undertaken to assess the status of drinking water quality in the urban areas of the. Tigray region, northern Ethiopia. A total of 106 drinking water samples were collected from 16 densely populated urban areas of the region, viz.: Alamata, Korem, Maichew, Adigudom, Abyi-. Adi, Hagereselam ...

  14. Investigation of the areas of high radon concentration in Gyeongju

    International Nuclear Information System (INIS)

    Lee, Jung Min; Park, Chan Hee; Kim, Shin Jae; Moon, Joo Hyun

    2013-01-01

    The aim of this study was to survey the radon concentrations at 21 elementary schools in Gyeongju, Republic of Korea, to identify those schools with high radon concentrations. Considering their geological characteristics and the preliminary survey results, three schools were finally placed under close scrutiny. For these three schools, continuous measurements over 48 h were taken at the principal's and administration office. The radon concentrations at one school, Naenam, exceeded the action level (148 Bq/m 3 ) established by the U.S. EPA, while those at the other two schools were below that level. - Highlights: • Preliminary measurements of the indoor radon concentrations were performed at the auditoriums in 23 elementary schools in Gyeongju. • Considering the geological characteristics and preliminary survey results, three elementary schools were screened for closer scrutiny. • For the three schools, continuous measurements were made at their principal's and administration offices over 48-h period. • The scrutiny revealed one elementary school of high radon concentration much higher than the U.S. EPA action level

  15. Effect of impervious surface area and vegetation changes on mean ...

    African Journals Online (AJOL)

    This land use or land cover changes are also thought to affect the climate of the Tshwane metropolis as is evidenced by heat waves in 2013 and 2014. This paper describes how vegetation and impervious surface area (ISA) or built up areas were classified from Landsat 8 LCDM, 2013, and Landsat 7 ETM+, 2003 images ...

  16. Influence of architectural style on indoor radon concentration in a radon prone area: A case study.

    Science.gov (United States)

    Baeza, A; García-Paniagua, J; Guillén, J; Montalbán, B

    2018-01-01

    Indoor radon is a major health concern as it is a known carcinogenic. Nowadays there is a trend towards a greater energy conservation in buildings, which is reflected in an increasing number of regulations. But, can this trend increase the indoor radon concentration? In this paper, we selected a radon prone area in Spain and focused on single-family dwellings constructed in a variety of architectural styles. These styles ranged from 1729 up to 2014, with varying construction techniques (from local resources to almost universally standard building materials) and regulations in force (from none to the Spanish regulation in force). The 226 Ra concentrations in soil and surface radon exhalation rates were rather similar in this area, mean values ranging 70-126Bq/kg and 49-100mBq/m 2 ·s, respectively. Indoor radon concentration was generally greater than the contribution from soil exhalation (surface exhalation rates), especially in New dwellings (1980-2014). Its concentration in dwellings built in the Traditional style (1729-1940) was significantly lower than in the new houses. This can be consequence of the air tightness of the dwellings as a consequence of the different regulations in force. In the period covered by the Traditional style, there was no regulation in force, and dwelling had loose air tight. Whereas in recent times, there are mandatory regulations assuring a better air tightness of the buildings. Refurbishment of Traditional dwellings also seems to increase the indoor radon concentration, as they must also comply with the regulations in force. Copyright © 2017 Elsevier B.V. All rights reserved.

  17. Manganese concentrations in soil and settled dust in an area with historic ferroalloy production.

    Science.gov (United States)

    Pavilonis, Brian T; Lioy, Paul J; Guazzetti, Stefano; Bostick, Benjamin C; Donna, Filippo; Peli, Marco; Zimmerman, Neil J; Bertrand, Patrick; Lucas, Erika; Smith, Donald R; Georgopoulos, Panos G; Mi, Zhongyuan; Royce, Steven G; Lucchini, Roberto G

    2015-01-01

    Ferroalloy production can release a number of metals into the environment, of which manganese (Mn) is of major concern. Other elements include lead, iron, zinc, copper, chromium, and cadmium. Mn exposure derived from settled dust and suspended aerosols can cause a variety of adverse neurological effects to chronically exposed individuals. To better estimate the current levels of exposure, this study quantified the metal levels in dust collected inside homes (n=85), outside homes (n=81), in attics (n=6), and in surface soil (n=252) in an area with historic ferroalloy production. Metals contained in indoor and outdoor dust samples were quantified using inductively coupled plasma optical emission spectroscopy, whereas attic and soil measurements were made with a X-ray fluorescence instrument. Mean Mn concentrations in soil (4600 μg/g) and indoor dust (870 μg/g) collected within 0.5 km of a plant exceeded levels previously found in suburban and urban areas, but did decrease outside 1.0 km to the upper end of background concentrations. Mn concentrations in attic dust were ~120 times larger than other indoor dust levels, consistent with historical emissions that yielded high airborne concentrations in the region. Considering the potential health effects that are associated with chronic Mn inhalation and ingestion exposure, remediation of soil near the plants and frequent, on-going hygiene indoors may decrease residential exposure and the likelihood of adverse health effects.

  18. Surface area considerations for corroding N reactor fuel

    International Nuclear Information System (INIS)

    Johnson, A.B. Jr.; Pitner, A.L.

    1996-06-01

    The N Reactor fuel is corroding at sites where the Zircaloy cladding was damaged when the fuel was discharged from the reactor. Corroding areas are clearly visible on the fuel stored in open cans in the K East Basin. There is a need to estimate the area of the corroding uranium to analyze aspects of fuel behavior as it is transitioned. from current wet storage to dry storage. In this report, the factors that contribute to open-quotes trueclose quotes surface area are analyzed in terms of what is currently known about the N Reactor fuel. Using observations from a visual examinations of the fuel in the K East wet storage facility, a value for the corroding geometric area is estimated. Based on observations of corroding uranium and surface roughness values for other metals, a surface roughness factor is also estimated and applied to the corroding K East fuel to provide an estimated open-quotes trueclose quotes surface area. While the estimated area may be modified as additional data become available from fuel characterization studies, the estimate provides a basis to assess effects of exposed uranium metal surfaces on fuel behavior in operations involved in transitioning from wet to dry storage, during shipment and staging, conditioning, and dry interim storage

  19. Modeling of surface dust concentrations using neural networks and kriging

    Science.gov (United States)

    Buevich, Alexander G.; Medvedev, Alexander N.; Sergeev, Alexander P.; Tarasov, Dmitry A.; Shichkin, Andrey V.; Sergeeva, Marina V.; Atanasova, T. B.

    2016-12-01

    Creating models which are able to accurately predict the distribution of pollutants based on a limited set of input data is an important task in environmental studies. In the paper two neural approaches: (multilayer perceptron (MLP)) and generalized regression neural network (GRNN)), and two geostatistical approaches: (kriging and cokriging), are using for modeling and forecasting of dust concentrations in snow cover. The area of study is under the influence of dust emissions from a copper quarry and a several industrial companies. The comparison of two mentioned approaches is conducted. Three indices are used as the indicators of the models accuracy: the mean absolute error (MAE), root mean square error (RMSE) and relative root mean square error (RRMSE). Models based on artificial neural networks (ANN) have shown better accuracy. When considering all indices, the most precision model was the GRNN, which uses as input parameters for modeling the coordinates of sampling points and the distance to the probable emissions source. The results of work confirm that trained ANN may be more suitable tool for modeling of dust concentrations in snow cover.

  20. [Distribution Characteristics of Fluoroquinolones Antibiotics in Surface Water and Groundwater from Typical Areas in A City].

    Science.gov (United States)

    Cui, Ya-feng; He, Jiang-tao; Su, Si-hui; Yang, Lei; Qiao, Xiao-cui

    2015-11-01

    In order to investigate the characteristics of 5 typical kinds of fluoroquinolones (FQs) pollution in waters from a city, surface water and groundwater samples from main drainage rivers and typical areas were collected, respectively. The conventional test and FQs concentrations analysis of the water samples were conducted. The results showed the concentration and composition of FQs in groundwater differed substantially from those in surface water. The average concentration of FQs in surface water was 789.1 ng x L(-1) with the main components of ofloxacin (OFL) and lomefloxacin (LOM). This value was higher than the average concentration of FQs in groundwater: 342.7 ng x L(-1) with the main components of norfloxacin (NOR) and lomefloxacin (LOM). The enrofloxacin (ENR) exhibited relatively lower levels in both surface water and groundwater as compared to others. The highest FQs concentrations in surface water were found in trenches, followed by tributaries and the main stream. For groundwater, FQs concentrations were relatively higher in the sewage riverside. A decreasing trend of FQs concentration was monitored with the increasing distance of sampling points to the drainage rivers and all components mentioned above showed similar changing trends. The results of this study preliminarily indicated that FQs in groundwater along the riverside probably came from the surface water.

  1. Polycyclic aromatic hydrocarbons in urban street dust and surface soil: comparisons of concentration, profile, and source.

    Science.gov (United States)

    Wang, De-Gao; Yang, Meng; Jia, Hong-Liang; Zhou, Lei; Li, Yi-Fan

    2009-02-01

    Street dust and surface soil samples in urban areas of Dalian, a coastal city in Liaoning Province, China, were collected and analyzed for 25 polycyclic aromatic hydrocarbons (PAHs). The concentrations, distribution, and sources of PAHs in dust and soil were determined. The concentrations of total PAHs in street dust ranged between 1890 and 17,070 ng/g (dry weight), with an average of 7460 ng/g, whereas the concentrations of total PAHs in surface soil varied greatly, from 650 to 28,900 ng/g, with a mean value of 6440 ng/g. Statistical paired t-test confirmed that total PAH concentrations have no significant difference between street dust and surface soil. Mean PAH concentrations in two type samples were much higher at industrial sites than at business/residential or garden sites. PAHs were dominated by higher molecular weight PAH (4- to 6-ring) homologues, which accounted for about 73% and 72% of total PAHs in street dust and surface soil, respectively. Principal component analysis was used in source apportionment of PAHs in dust and soil. Pyrogenic and petrogenic sources contributed 70% and 22.4% of total PAHs in street dusts, and fossil fuel (coal and petroleum) and biomass combustion accounted for 64.4% and 5.6% of total PAHs in pyrogenic sources, respectively. In surface soil, total PAHs were dominated by pyrogenic sources. The diagnostic ratios of benz[a]anthracene/chrysene confirmed that PAHs in street dust and surface soil of a Dalian urban zone might come mostly from the emission of local sources.

  2. Assessment of dialyzer surface in online hemodiafiltration; objective choice of dialyzer surface area

    Directory of Open Access Journals (Sweden)

    Francisco Maduell

    2015-05-01

    Conclusion: The increase in 40% and 80% of dialyzer surface area entails an increase in convective volume of 6 and 16% respectively, showing minimal differences both in convective volume and clearance capacity when UFC was greater than 45 mL/h/mmHg. It is advisable to optimise dialyser efficiency to the smallest surface area possible, adjusting treatment prescription.

  3. Concentration of Heavy Metals in Drinking Water from Urban Areas ...

    African Journals Online (AJOL)

    Bheema

    Adwa, Axum, Firewoini,Edagahamus, Inda-Selassie, Korem, Alamata, Maychew, Wukro,. Quiha, and Zalambessa,. The region has six administrative zones namely; Western,North west,Eastern, Central, South Estern and Southern. With an estimated area of 50,078.64 square kilometers, this region has an estimated density ...

  4. Specific surface area of a crushed welded tuff before and after aqueous dissolution

    Science.gov (United States)

    Reddy, M.M.; Claassen, H.C.

    1994-01-01

    Specific surface areas were measured for several reference minerals (anorthoclase, labradorite and augite), welded tuff and stream sediments from Snowshoe Mountain, near Creede, Colorado. Crushed and sieved tuff had an unexpectedly small variation in specific surface area over a range of size fractions. Replicate surface area measurements of the largest and smallest tuff particle size fractions examined (1-0.3 mm and <0.212 mm) were 2.3 ?? 0.2 m2/g for each size fraction. Reference minerals prepared in the same way as the tuff had smaller specific surface areas than that of the tuff of the same size fraction. Higher than expected tuff specific surface areas appear to be due to porous matrix. Tuff, reacted in solutions with pH values from 2 to 6, had little change in specific surface area in comparison with unreacted tuff. Tuff, reacted with solutions having high acid concentrations (0.1 M hydrochloric acid or sulfuric-hydrofluoric acid), exhibited a marked increase in specific surface area compared to unreacted tuff. ?? 1994.

  5. Students' and Teachers' Application of Surface Area to Volume Relationships

    Science.gov (United States)

    Taylor, Amy R.; Jones, M. Gail

    2013-02-01

    The National Science Education Standards emphasize teaching unifying concepts and processes such as basic functions of living organisms, the living environment, and scale (NRC 2011). Scale includes understanding that different characteristics, properties, or relationships within a system might change as its dimensions are increased or decreased (NRC 2011). One such relationship involves surface area to volume which is a pervasive concept that can be found throughout different sciences. This concept is important for students to not only understand the association of the two, but to also be able to apply this relationship in science contexts. The purpose of this study is to investigate the factors that influence the understanding surface area to volume relationships. This study examined middle school students', high school students', and science teachers' logical thinking skills (including proportional reasoning), visual-spatial skills, and understandings of surface area to volume relationships. Regression results indicated that participants' reasoning abilities and components of visual-spatial skills could be possible predictors for one's ability to understand surface area to volume relationships. Implications for teaching scale concepts such as surface area to volume relationships in the science classroom are discussed.

  6. Surface deformation of the secondary former mining areas

    Directory of Open Access Journals (Sweden)

    Tadeusz Głowacki

    2013-09-01

    Full Text Available The paper discuss the problem of secondary deformation observed on the surface of the land in the area of the old, non-existent copper and coal mines. The authors discuss the formation of the deformation in the final period of the mine, and after his arrest, after the close of any work of protecting the surface area of influence of mining activities. Discusses the reduction of the surface of the example of two disused mines: mining copper “Konrad” in Iwiny and “Thorez” in Walbrzych, an old coal mine. In the first part of the paper discusses a brief history of the creation of old copper basin and the Lower Silesian coal basin. It then discusses the formation of deformation processes in mining areas. Conducting continuous surveying allows you to monitor changes in the formation of land, in the paper indicate the source of the vertical displacements after ending of operation, the closure of the mine and stopped all work safety. In the area of Lower Silesia there are many remnants of disused mines, surface geodetic measurements show a constant activity in post-mining areas and the need to control the formation of the surface.

  7. Can foot anthropometric measurements predict dynamic plantar surface contact area?

    Directory of Open Access Journals (Sweden)

    Collins Natalie

    2009-10-01

    Full Text Available Abstract Background Previous studies have suggested that increased plantar surface area, associated with pes planus, is a risk factor for the development of lower extremity overuse injuries. The intent of this study was to determine if a single or combination of foot anthropometric measures could be used to predict plantar surface area. Methods Six foot measurements were collected on 155 subjects (97 females, 58 males, mean age 24.5 ± 3.5 years. The measurements as well as one ratio were entered into a stepwise regression analysis to determine the optimal set of measurements associated with total plantar contact area either including or excluding the toe region. The predicted values were used to calculate plantar surface area and were compared to the actual values obtained dynamically using a pressure sensor platform. Results A three variable model was found to describe the relationship between the foot measures/ratio and total plantar contact area (R2 = 0.77, p R2 = 0.76, p Conclusion The results of this study indicate that the clinician can use a combination of simple, reliable, and time efficient foot anthropometric measurements to explain over 75% of the plantar surface contact area, either including or excluding the toe region.

  8. Bioaerosols concentrations in working areas in biomethanization facilities.

    Science.gov (United States)

    Dubuis, Marie-Eve; M'Bareche, Hamza; Veillette, Marc; Bakhiyi, Bouchra; Zayed, Joseph; Lavoie, Jacques; Duchaine, Caroline

    2017-11-01

    This study sought to fill the gap in information about the type and the concentration of bioaerosols present in the air of biomethanization facilities (BF). Evaluation of bioaerosol composition and concentration was achieved in two biomethanization facilities located in Eastern Canada, during summer and winter. In order to have a thorough understanding of the studied environment, the methodology combined culture of bacteria and molds, qualitiative polymerase chain reaction (qPCR) for specific microorganisms, endotoxin quantification, and next-generation sequencing (NGS) for bacterial diversity. Results revealed that workers in biomethanization facilities are exposed to bioaerosols and pathogenic microorganisms similar to those found in composting plants. However, human exposure levels to bioaerosols are lower in BF than in composting plants. Despite these differences, use of personal protective equipment is recommended to lower the risks of health problems. Biomethanization is a new technology used in eastern Canada for waste management. In the next few years, it is expected that there will be an expansion of facilities in response of tight governmental regulations. Workers in biomethanization facilities are exposed to various amounts of bioaerosols composed of some harmful microorganisms. Therefore, monitoring this occupational exposure could be an interesting tool for improving worker's health.

  9. Correlation between sub-micron surface roughness of iron oxide encrustations and trace element concentrations

    International Nuclear Information System (INIS)

    Fischer, Cornelius; Karius, Volker; Luettge, Andreas

    2009-01-01

    Iron oxide encrustations are formed on black slate surfaces during oxidative weathering of iron sulfide and phosphate bearing, organic matter-rich slates. Synchronously, trace elements are released during ongoing weathering. Laser ablation ICP-MS analyses of a weathered and encrusted slate showed that major portions of the V, Cu, As, Mo, Pb, Th, and U reside in the encrustation. Recently a potential relationship between several micrometer to 500 nm surface topography roughness of such encrustations and its uranium concentration was shown. Based on laser scanning microscopy measurements, the present study shows that this interrelation must be expanded to small submicron-sized half-pores with diameters between 100 nm and 500 nm. We demonstrate that the relationship is not limited to topography variations of a single encrustation in the hand-specimen scale. Surface topography and geochemical analyses of iron oxide encrustations from several locations but from the same geochemical environment and with similar weathering history showed that the concentrations of U, P, Cu, and Zn correlate inversely with the surface roughness parameter F. This parameter represents the total surface area and is - in this case - a proxy for the root-mean square surface roughness Rq. This study substantiates the environmental importance that micrometer- to submicrometer topography variations of fluid-rock interfaces govern the trapping of trace elements.

  10. Correlation between sub-micron surface roughness of iron oxide encrustations and trace element concentrations

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, Cornelius, E-mail: cornelius@rice.edu [Department of Earth Science, MS-126, Rice University, 6100 Main Street, Houston, TX 77005 (United States); Geowissenschaftliches Zentrum der Universitaet Goettingen, Abt. Sedimentologie and Umweltgeologie, Goldschmidtstr. 3, D-37077 Goettingen (Germany); Karius, Volker [Geowissenschaftliches Zentrum der Universitaet Goettingen, Abt. Sedimentologie and Umweltgeologie, Goldschmidtstr. 3, D-37077 Goettingen (Germany); Luettge, Andreas [Department of Earth Science, MS-126, Rice University, 6100 Main Street, Houston, TX 77005 (United States); Department of Chemistry, Rice University, 6100 Main Street, Houston, TX 77005 (United States)

    2009-08-01

    Iron oxide encrustations are formed on black slate surfaces during oxidative weathering of iron sulfide and phosphate bearing, organic matter-rich slates. Synchronously, trace elements are released during ongoing weathering. Laser ablation ICP-MS analyses of a weathered and encrusted slate showed that major portions of the V, Cu, As, Mo, Pb, Th, and U reside in the encrustation. Recently a potential relationship between several micrometer to 500 nm surface topography roughness of such encrustations and its uranium concentration was shown. Based on laser scanning microscopy measurements, the present study shows that this interrelation must be expanded to small submicron-sized half-pores with diameters between 100 nm and 500 nm. We demonstrate that the relationship is not limited to topography variations of a single encrustation in the hand-specimen scale. Surface topography and geochemical analyses of iron oxide encrustations from several locations but from the same geochemical environment and with similar weathering history showed that the concentrations of U, P, Cu, and Zn correlate inversely with the surface roughness parameter F. This parameter represents the total surface area and is - in this case - a proxy for the root-mean square surface roughness Rq. This study substantiates the environmental importance that micrometer- to submicrometer topography variations of fluid-rock interfaces govern the trapping of trace elements.

  11. High surface area electrode for high efficient microbial electrosynthesis

    Science.gov (United States)

    Nie, Huarong; Cui, Mengmeng; Lu, Haiyun; Zhang, Tian; Russell, Thomas; Lovley, Derek

    2012-02-01

    Microbial electrosynthesis, a process in which microorganisms directly accept electrons from an electrode to convert carbon dioxide and water into multi carbon organic compounds, affords a novel route for the generation of valuable products from electricity or even wastewater. The surface area of the electrode is critical for high production. A biocompatible, highly conductive, three-dimensional cathode was fabricated from a carbon nanotube textile composite to support the microorganism to produce acetate from carbon dioxide. The high surface area and macroscale porous structure of the intertwined CNT coated textile ?bers provides easy microbe access. The production of acetate using this cathode is 5 fold larger than that using a planar graphite electrode with the same volume. Nickel-nanowire-modified carbon electrodes, fabricated by microwave welding, increased the surface area greatly, were able to absorb more bacteria and showed a 1.5 fold increase in performance

  12. Particle surface area and bacterial activity in recirculating aquaculture systems

    DEFF Research Database (Denmark)

    Pedersen, Per Bovbjerg; von Ahnen, Mathis; Fernandes, Paulo

    2017-01-01

    Suspended particles in recirculating aquaculture systems (RAS) provide surface area that can be colonized by bacteria. More particles accumulate as the intensity of recirculation increases thus potentially increasing the bacterial carrying capacity of the systems. Applying a recent, rapid, cultur...... for determining bacterial activity might provide a means for future monitoring and assessment of microbial water quality in aquaculture farming systems......Suspended particles in recirculating aquaculture systems (RAS) provide surface area that can be colonized by bacteria. More particles accumulate as the intensity of recirculation increases thus potentially increasing the bacterial carrying capacity of the systems. Applying a recent, rapid, culture......-independent fluorometric detection method (Bactiquant®) for measuring bacterial activity, the current study explored the relationship between total particle surface area (TSA, derived from the size distribution of particles >5 μm) and bacterial activity in freshwater RAS operated at increasing intensity of recirculation...

  13. OBSERVED ASTEROID SURFACE AREA IN THE THERMAL INFRARED

    Energy Technology Data Exchange (ETDEWEB)

    Nugent, C. R. [Infrared Processing and Analysis Center, California Institute of Technology, Pasadena, CA 91125 (United States); Mainzer, A.; Masiero, J.; Bauer, J.; Kramer, E.; Sonnett, S. [Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States); Wright, E. L. [Department of Physics and Astronomy, University of California, Los Angeles, CA 90095 (United States); Grav, T. [Planetary Science Institute, Tucson, AZ (United States)

    2017-02-01

    The rapid accumulation of thermal infrared observations and shape models of asteroids has led to increased interest in thermophysical modeling. Most of these infrared observations are unresolved. We consider what fraction of an asteroid’s surface area contributes the bulk of the emitted thermal flux for two model asteroids of different shapes over a range of thermal parameters. The resulting observed surface in the infrared is generally more fragmented than the area observed in visible wavelengths, indicating high sensitivity to shape. For objects with low values of the thermal parameter, small fractions of the surface contribute the majority of thermally emitted flux. Calculating observed areas could enable the production of spatially resolved thermal inertia maps from non-resolved observations of asteroids.

  14. STEREOLOGICAL ESTIMATION OF SURFACE AREA FROM DIGITAL IMAGES

    Directory of Open Access Journals (Sweden)

    Johanna Ziegel

    2011-05-01

    Full Text Available A sampling design of local stereology is combined with a method from digital stereology to yield a novel estimator of surface area based on counts of configurations observed in a digitization of an isotropic 2- dimensional slice with thickness s. As a tool, a result of the second author and J. Rataj on infinitesimal increase of volumes of morphological transforms is refined and used. The proposed surface area estimator is asymptotically unbiased in the case of sets contained in the ball centred at the origin with radius s and in the case of balls centred at the origin with unknown radius. For general shapes bounds for the asymptotic expected relative worst case error are given. A simulation example is discussed for surface area estimation based on 2×2×2-configurations.

  15. The influence of surface roughness and solution concentration on pool boiling process in Diethanolamine aqueous solution

    Science.gov (United States)

    Khoshechin, Mohsen; Salimi, Farhad; Jahangiri, Alireza

    2018-04-01

    In this research, the effect of surface roughness and concentration of solution on bubble departing frequency and nucleation site density for pool boiling of water/diethanolamine (DEA) binary solution were investigated experimentally. In this investigation, boiling heat transfer coefficient, bubble departing frequency and nucleation site density have been experimentally investigated in various concentrations and heat fluxes. Microstructured surfaces with a wide range of well-defined surface roughness were fabricated, and a heat flux between 1.5-86 kW/m2 was achieved under atmospheric conditions. The Results indicated that surface roughness and concentration of solution increase the bubble departing frequency and nucleation site density with increasing heat flux. The boiling heat transfer coefficient in mixtures of water/DEA increases with increasing concentration of DEA in water. The experimental results were compared with predictions of several used correlations in the literatures. Results showed that the boiling heat transfer coefficients of this case study are much higher than the predicted values by major existing correlations and models. The excellent agreement for bubble departing frequency found between the models of Jackob and Fritz (1966) and experimental data and also the nucleation site density were in close agreement with the model of Paul (1983) data. f bubble departure frequency, 1/s or Hz N Number of nucleation sites per area per time R c Minimum cavity size, m D c critical diameter, m g gravitational acceleration, m/s2 ρ density, kg/m3 T temperature, °c ΔT temperature difference, °c d d vapor bubble diameter, m h fg enthalpy of vaporization, J/kg R Roughness, μm Ja Jakob number cp specific heat, J/kg °c Pr Prandtl number Ar Archimedes number h Heat transfer coefficient, J/(m2 °c) tg time it takes to grow a bubble, s q/A heat flux (kW/m2) tw time required to heat the layer, s gc Correction coefficient of incompatible units R a Surface

  16. High surface area carbon and process for its production

    Energy Technology Data Exchange (ETDEWEB)

    Romanos, Jimmy; Burress, Jacob; Pfeifer, Peter; Rash, Tyler; Shah, Parag; Suppes, Galen

    2016-12-13

    Activated carbon materials and methods of producing and using activated carbon materials are provided. In particular, biomass-derived activated carbon materials and processes of producing the activated carbon materials with prespecified surface areas and pore size distributions are provided. Activated carbon materials with preselected high specific surface areas, porosities, sub-nm (<1 nm) pore volumes, and supra-nm (1-5 nm) pore volumes may be achieved by controlling the degree of carbon consumption and metallic potassium intercalation into the carbon lattice during the activation process.

  17. Surface barrier silicon detectors with a large active area

    International Nuclear Information System (INIS)

    Kim, Y.; Husimi, K.; Ikeda, Y.; Kim, C.; Ohkawa, S.; Sakai, T.

    1985-01-01

    Surface barrier silicon detectors with a large active area have been produced by using high resistive n-type silicon crystals, diameters of which are 3 to 5 inches. High quality detectors with a low leakage current and a low noise were achieved by developing the improved surface treatment. Characteristics of detectors obtained are good in energy resolution compared with conventional large area Si(Li) detectors. It has also been confirmed that local dead region is not found from measuring results of photo-pulse injection

  18. Stereological estimation of surface area from digital images

    DEFF Research Database (Denmark)

    Ziegel, Johanna; Kiderlen, Markus

    2010-01-01

    A sampling design of local stereology is combined with a method from digital stereology to yield a novel estimator of surface area based on counts of configurations observed in a digitization of an isotropic 2- dimensional slice with thickness s. As a tool, a result of the second author and J....... Rataj on infinitesimal increase of volumes of morphological transforms is refined and used. The proposed surface area estimator is asymptotically unbiased in the case of sets contained in the ball centred at the origin with radius s and in the case of balls centred at the origin with unknown radius...

  19. Determining Surface Roughness in Urban Areas Using Lidar Data

    Science.gov (United States)

    Holland, Donald

    2009-01-01

    An automated procedure has been developed to derive relevant factors, which can increase the ability to produce objective, repeatable methods for determining aerodynamic surface roughness. Aerodynamic surface roughness is used for many applications, like atmospheric dispersive models and wind-damage models. For this technique, existing lidar data was used that was originally collected for terrain analysis, and demonstrated that surface roughness values can be automatically derived, and then subsequently utilized in disaster-management and homeland security models. The developed lidar-processing algorithm effectively distinguishes buildings from trees and characterizes their size, density, orientation, and spacing (see figure); all of these variables are parameters that are required to calculate the estimated surface roughness for a specified area. By using this algorithm, aerodynamic surface roughness values in urban areas can then be extracted automatically. The user can also adjust the algorithm for local conditions and lidar characteristics, like summer/winter vegetation and dense/sparse lidar point spacing. Additionally, the user can also survey variations in surface roughness that occurs due to wind direction; for example, during a hurricane, when wind direction can change dramatically, this variable can be extremely significant. In its current state, the algorithm calculates an estimated surface roughness for a square kilometer area; techniques using the lidar data to calculate the surface roughness for a point, whereby only roughness elements that are upstream from the point of interest are used and the wind direction is a vital concern, are being investigated. This technological advancement will improve the reliability and accuracy of models that use and incorporate surface roughness.

  20. Clay mineralogy in different geomorphic surfaces in sugarcane areas

    Science.gov (United States)

    Camargo, L.; Marques, J., Jr.

    2012-04-01

    The crystallization of the oxides and hydroxides of iron and aluminum and kaolinite of clay fraction is the result of pedogenetic processes controlled by the relief. These minerals have influence on the physical and chemical attributes of soil and exhibit spatial dependence. The pattern of spatial distribution is influenced by forms of relief as the geomorphic surfaces. In this sense, the studies aimed at understanding the relationship between relief and the distribution pattern of the clay fraction attributes contribute to the delineation of specific areas of management in the field. The objective of this study was to evaluate the spatial distribution of oxides and hydroxides of iron and aluminum and kaolinite of clay fraction and its relationship with the physical and chemical attributes in different geomorphic surfaces. Soil samples were collected in a transect each 25 m (100 samples) and in the sides of the same (200 samples) as well as an area of 500 ha (1 sample each six hectare). Geomorphic surfaces (GS) in the transect were mapped in detail to support mapping the entire area. The soil samples were taken to the laboratory for chemical, physical, and mineralogical analysis, and the pattern of spatial distribution of soil attributes was obtained by statistics and geostatistics. The GS I is considered the oldest surface of the study area, with depositional character, and a slope ranging from 0 to 4%. GS II and III are considered to be eroded, and the surface II plan a gentle slope that extends from the edge of the surface until the beginning of I and III. The crystallographic characteristics of the oxides and hydroxides of iron and aluminum and kaolinite showed spatial dependence and the distribution pattern corresponding to the limits present of the GS in the field. Surfaces I and II showed the best environments to the degree of crystallinity of hematite and the surface III to the greatest degree of crystallinity of goethite agreeing to the pedoenvironment

  1. Impact of regional ventilation changes on surface particulate matter concentrations in South Korea

    Science.gov (United States)

    Kim, H. C.; Stein, A. F.; Chai, T.; Ngan, F.; Kim, B. U.; Jin, C. S.; Hong, S. Y.; Park, R.; Son, S. W.; Bae, C.; Bae, M.; Song, C. K.; Kim, S.

    2017-12-01

    The recent increase in surface particulate matter (PM) concentrations in South Korea is intriguing due to its disagreement with current intensive emission reduction efforts. The long-term trend of surface PM concentrations in South Korea declined in the 2000s, but since 2012 its concentrations have tended to increase, resulting in frequent severe haze events in the region. This study demonstrates that the interannual variation of surface PM concentrations in South Korea is not only affected by changes in local or regional emission sources, but also closely linked with the interannual variations in regional ventilation. Using EPA Community Multiscale Air Quality modeling system, a 12-year (2004-2015) regional air quality simulation was conducted to assess the impact of the meteorological conditions under constant anthropogenic emissions. In addition, NOAA HYSPLIT dispersion model was utilized to estimate the strength of regional ventilation that dissipates local pollutions. Simulated PM concentrations show a strong negative correlation (i.e. R=-0.86) with regional wind speed, implying that reduced regional ventilation is likely associated with more stagnant conditions that cause severe pollutant episodes in South Korea. We conclude that the current PM concentration trend in South Korea is a combination of long-term decline by emission control efforts and short-term fluctuations in regional wind speed interannual variability. When the meteorology-driven variations are removed, PM concentrations in South Korea have declined continuously even after 2012, with -1.45±0.12, -1.41±0.16, and -1.09±0.16 mg/m3 per year in Seoul, the Seoul Metropolitan Area, and South Korea, respectively.

  2. Determination of the radon Concentration in underground water in selected areas in and around Kumasi

    International Nuclear Information System (INIS)

    Owusu, Seth Adjei

    2012-06-01

    Radon (Rn-222) is a radioactive noble gas of natural origin that may be found anywhere in soil, air and different types of water: surface, borehole, well and spring. It is worth to carry out surveys for the radon in water for radiation protection as well as for geological considerations. The research presenters here was carried out in selected towns in and around Kumasi for the determination of radon concentration in groundwater. The major towns from which samples were taken are , Mowire, Kronum, Aburaso, Medoma, Kenyase, Buokrom, Bomfa, Ayeduase, Kotei, Tikrom. All the samples are used for domestic purposes such as cooking, drinking, bathing and washing. Waters from boreholes and wells in the selected towns were sampled and the radon concentration level measured. The Roll’s method was used for the radon concentration analysis on all the 100 samples. The results shows that, the minimum radon concentration in groundwater was 13015.934 Bq/m3 and it was found at Bomfa, and the highest was found to be 964628.480 Bq/m3, recorded at Mowire. It is believed that this variation of levels is mainly due to the difference in rock type, soil type and geology of the area as well as the depth of the water samples. This information can be used to estimate the possible health hazards from radon in the selected towns in the future from environmental point of view. The data would promote public awareness related to risk of radon exposure. (au)

  3. The effect of some soil characteristics on soil radon concentration and radon exhalation from soil surface

    International Nuclear Information System (INIS)

    Sun, Kainan; Cheng, Jianping; Guo, Qiuju

    2004-01-01

    To find out the impacts of soil characters on radon concentration in soil and radon exhalation from soil, field measurements on soil radon concentrations (60 cm under the soil surface) and radon exhalation rate from soil surface were carried out in totally 31 points with different types of soil in three cities in both South and North China. Soil radium contents, water contents, soil porosity and grain size were concretely analyzed in our laboratory. The linear simulation was used to analyze the above data. The results showed that radon exhalation rate from soil and radon concentrations in soil have direct proportion to soil radium contents. Rather high radium content and radon exhalation rate were measured in Guiyang area, 67±28Bq/Kg and 40±59 mBq/m 2 ·s, however no high soil radon concentration was found due to the difficulties in the measurements on clay soils with high saturation. Compared with soil radium contents, radon exhalation rate from soil and soil radon concentrations are more easily impacted by soil characters and change in a rather large range. (author)

  4. Indexing Glomerular Filtration Rate to Body Surface Area

    DEFF Research Database (Denmark)

    Redal-Baigorri, Belén; Rasmussen, Knud; Heaf, James Goya

    2014-01-01

    BACKGROUND: Kidney function is mostly expressed in terms of glomerular filtration rate (GFR). A common feature is the expression as ml/min per 1.73 m(2) , which represents the adjustment of the individual kidney function to a standard body surface area (BSA) to allow comparison between individuals...

  5. Plasma Creatinine, Age and Body Surface Area in Nigerian Children ...

    African Journals Online (AJOL)

    In a bid to establish reference values for plasma creatinine in children and adolescents using age, and body surface area (BSA), 462 apparently healthy Nigerian children/adolescents aged one day to 15 years were studied. They were recruited from well baby clinics, as well as primary and secondary schools. Plasma ...

  6. Evaluation of five formulae for estimating body surface area of ...

    African Journals Online (AJOL)

    Background: Physiological functions are often assessed by standardizing for body surface area (BSA) to avoid excessive variation in calculations in pediatric practice. Aim: To explore the suitability of existing formulae for estimating the BSA of Nigerian children. Subjects and Methods: This cross‑sectional study involved ...

  7. (Impervious) Surfaces on the Microclimate of Urban Area

    African Journals Online (AJOL)

    The present paper shows the considerable impacts of both vegetated and synthetic surfaces on the microclimate of urban area. Vegetation of a particular place affects the microclimate through reduced solar radiation and lower air temperature due to shading and evapotranspiration. Lower air temperatures are essential ...

  8. Installation and performance evaluation of an indigenous surface area analyser

    International Nuclear Information System (INIS)

    Pillai, S.N.; Solapurkar, M.N.; Venkatesan, V.; Prakash, A.; Khan, K.B.; Kumar, Arun; Prasad, R.S.

    2014-01-01

    An indigenously available surface area analyser was installed inside glove box and checked for its performance by analyzing uranium oxide and thorium oxide powders at RMD. The unit has been made ready for analysis of Plutonium oxide powders after incorporating several important features. (author)

  9. Influence of Ear Surface Area on Heat Tolerance of Composite ...

    African Journals Online (AJOL)

    Low correlation (r = 0.12) was observed between body weight and ear width. There were no correlations between ear width, respiratory rates and pulse rate. However, a residual correlation (r = -0.03) was obtained between ear width and body temperature. Large ear surface area in composite rabbits enhances better ...

  10. Assessment of large aperture scintillometry for large-area surface ...

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Earth System Science; Volume 126; Issue 5. Assessment of large aperture scintillometry for large-area surface energy fluxes over an irrigated cropland in north India. Abhishek Danodia V K Sehgal N R Patel R Dhakar J Mukherjee S K Saha A Senthil Kumar. Volume 126 Issue 5 July 2017 Article ...

  11. Surface water and groundwater interaction in Marala - Khanki area, Punjab

    International Nuclear Information System (INIS)

    Akram, W.; Ahmad, M.; Latif, Z.; Tariq, J.A.; Malik, M.R.

    2011-07-01

    Isotope hydrological investigations were carried out in two selected areas of Indus Basin viz. Haripur Area and Chashma- Taunsa Area for elucidating various aspects of surface water and groundwater interaction. Groundwater samples were collected on seasonal basis (low and high river discharge periods) while surface water samples were collected more frequently (weekly or monthly basis). Isotopic data suggested that there is no contribution of surface water to groundwater recharge in Haripur Area and rain is the prevailing source of groundwater recharge. The data further revealed that isotopic values of the Haripur pocket of Tarbela Lake are higher than those of Main Lake / Indus River meaning that there is a significant contribution of base flow in this pocket. Indus River appeared to be the dominant source of groundwater recharge at most of the locations in Chashma- Taunsa Area. Isotopic data of Indus River showed an increase at Taunsa as compared to Chashma in low flow period indicating the high contribution of base flow at this point in time. Stable isotopes were successfully used to quantify the base flow contribution. (author)

  12. Growth of contact area between rough surfaces under normal stress

    Science.gov (United States)

    Stesky, R. M.; Hannan, S. S.

    1987-05-01

    The contact area between deforming rough surfaces in marble, alabaster, and quartz was measured from thin sections of surfaces bonded under load with low viscosity resin epoxy. The marble and alabaster samples had contact areas that increased with stress at an accelerating rate. This result suggests that the strength of the asperity contacts decreased progressively during the deformation, following some form of strain weakening relationship. This conclusion is supported by petrographic observation of the thin sections that indicate that much of the deformation was cataclastic, with minor twinning of calcite and kinking of gypsum. In the case of the quartz, the observed contact area was small and increased approximately linearly with normal stress. Only the irreversible cataclastic deformation was observed; however strain-induced birefringence and cracking of the epoxy, not observed with the other rocks, suggests that significant elastic deformation occurred, but recovered during unloading.

  13. Radionuclide concentrations in vegetation at radioactive-waste disposal Area G during the 1994 growing season

    International Nuclear Information System (INIS)

    Fresquez, P.R.; Biggs, J.B.; Bennett, K.D.

    1995-01-01

    Overstory (pinon pine) and understory (grass and forb) vegetation samples were collected within and around selected points at Area G-a low-level radioactive solid-waste disposal facility at Los Alamos National Laboratory-for the analysis of tritium ( 3 H), strontium ( 90 Sr), plutonium ( 238 Pu and 239 Pu), cesium ( 137 Cs), americium ( 241 Am), and total uranium. In general, most vegetation samples collected within and around Area G contained radionuclide levels in higher concentrations than vegetation collected from background areas. Tritium, in particular, was detected as high as 5,800 pCi/mL in overstory vegetation collected outside the fence just west of the tritium shafts; this suggests that tritium is migrating from this waste repository through subsurface pathways. Also, understory vegetation collected north of the transuranic (TRU) pads (outside the fence of Area G) contained the highest values of 90 Sr, 238 Pu, 239 Pu, 137 Cs, and 241 Am, and may be a result of surface holding, storage, or disposal activities

  14. Models of bedrock surface and overburden thickness over Olkiluoto island and nearby sea area

    Energy Technology Data Exchange (ETDEWEB)

    Moenkkoenen, H. [WSP Finland Oy, Helsinki (Finland)

    2012-04-15

    In this report, a model of bedrock surface and a model of overburden thickness over the Olkiluoto Island and the nearby sea area are presented. Also in purpose to produce material for biosphere and radionuclide transport modelling, stratigraphy models of different sediment layers were created at two priority areas north and south of the Olkiluoto Island. The work concentrated on the collection and description of available data of bedrock surface and overburden thickness. Because the information on the bedrock surface and overburden is collected from different sources and is based on a number of types of data the quality and applicability of data sets varies. Consequently also the reliability in different parts of the models varies. Input data for the bedrock surface and overburden thickness models include 2928 single points and additional outcrops observations (611 polygons) in the modelled area. In addition, the input data include 173 seismic refraction lines (6534 points) and acousticseismic sounding lines (26655 points from which 13721 points are located in model area) in the Olkiluoto offshore area. The average elevation of bedrock surface in area is 2.1 metres above the sea level. The average thickness of overburden is 2.5 metres varying typically between 2 - 4 metres. Thickest overburden covers (approximately 16 metres) of terrestrial area are located at the western end of the Olkiluoto Island and in sea basin south of the island. (orig.)

  15. A new general dynamic model predicting radionuclide concentrations and fluxes in coastal areas from readily accessible driving variables

    International Nuclear Information System (INIS)

    Haakanson, Lars

    2004-01-01

    This paper presents a general, process-based dynamic model for coastal areas for radionuclides (metals, organics and nutrients) from both single pulse fallout and continuous deposition. The model gives radionuclide concentrations in water (total, dissolved and particulate phases and concentrations in sediments and fish) for entire defined coastal areas. The model gives monthly variations. It accounts for inflow from tributaries, direct fallout to the coastal area, internal fluxes (sedimentation, resuspension, diffusion, burial, mixing and biouptake and retention in fish) and fluxes to and from the sea outside the defined coastal area and/or adjacent coastal areas. The fluxes of water and substances between the sea and the coastal area are differentiated into three categories of coast types: (i) areas where the water exchange is regulated by tidal effects; (ii) open coastal areas where the water exchange is regulated by coastal currents; and (iii) semi-enclosed archipelago coasts. The coastal model gives the fluxes to and from the following four abiotic compartments: surface water, deep water, ET areas (i.e., areas where fine sediment erosion and transport processes dominate the bottom dynamic conditions and resuspension appears) and A-areas (i.e., areas of continuous fine sediment accumulation). Criteria to define the boundaries for the given coastal area towards the sea, and to define whether a coastal area is open or closed are given in operational terms. The model is simple to apply since all driving variables may be readily accessed from maps and standard monitoring programs. The driving variables are: latitude, catchment area, mean annual precipitation, fallout and month of fallout and parameters expressing coastal size and form as determined from, e.g., digitized bathymetric maps using a GIS program. Selected results: the predictions of radionuclide concentrations in water and fish largely depend on two factors, the concentration in the sea outside the given

  16. Ross Sea Polynyas: Response of Ice Concentration Retrievals to Large Areas of Thin Ice

    Science.gov (United States)

    Kwok, R.; Comiso, J. C.; Martin, S.; Drucker, R.

    2007-01-01

    For a 3-month period between May and July of 2005, we examine the response of the Advanced Microwave Scanning Radiometer (AMSR-E) Enhanced NASA Team 2 (NT2) and AMSR-E Bootstrap (ABA) ice concentration algorithms to large areas of thin ice of the Ross Sea polynyas. Coincident Envisat Synthetic Aperture Radar (SAR) coverage of the region during this period offers a detailed look at the development of the polynyas within several hundred kilometers of the ice front. The high-resolution imagery and derived ice motion fields show bands of polynya ice, covering up to approximately 105 km(sup 2) of the Ross Sea, that are associated with wind-forced advection. In this study, ice thickness from AMSR-E 36 GHz polarization information serves as the basis for examination of the response. The quality of the thickness of newly formed sea ice (<10 cm) from AMSR-E is first assessed with thickness estimates derived from ice surface temperatures from the Moderate Resolution Imaging Spectroradiometer (MODIS) instrument. The effect of large areas of thin ice in lowering the ice concentration estimates from both NT2/ABA approaches is clearly demonstrated. Results show relatively robust relationships between retrieved ice concentrations and thin ice thickness estimates that differ between the two algorithms. These relationships define the approximate spatial coincidence of ice concentration and thickness isopleths. Using the 83% (ABA) and 91% (NT2) isopleths as polynya boundaries, we show that the computed coverage compares well with that using the estimated 10-cm thickness contour. The thin ice response characterized here suggests that in regions with polynyas, the retrieval results could be used to provide useful geophysical information, namely thickness and coverage.

  17. Metal concentration at surface water using multivariate analysis and ...

    African Journals Online (AJOL)

    This study defined the concentration of metals in Kerteh and Paka River water and their potential health risk towards human. 54 water samples were collected and analyzed using ICP-OES. Results revealed that most of the stations in Kerteh River gave the higher concentration of Cd, Cu, Zn, Co, Ni, As, Cr and Pb compared ...

  18. Tropical cyclone rainfall area controlled by relative sea surface temperature.

    Science.gov (United States)

    Lin, Yanluan; Zhao, Ming; Zhang, Minghua

    2015-03-12

    Tropical cyclone rainfall rates have been projected to increase in a warmer climate. The area coverage of tropical cyclones influences their impact on human lives, yet little is known about how tropical cyclone rainfall area will change in the future. Here, using satellite data and global atmospheric model simulations, we show that tropical cyclone rainfall area is controlled primarily by its environmental sea surface temperature (SST) relative to the tropical mean SST (that is, the relative SST), while rainfall rate increases with increasing absolute SST. Our result is consistent with previous numerical simulations that indicated tight relationships between tropical cyclone size and mid-tropospheric relative humidity. Global statistics of tropical cyclone rainfall area are not expected to change markedly under a warmer climate provided that SST change is relatively uniform, implying that increases in total rainfall will be confined to similar size domains with higher rainfall rates.

  19. Spectral theory of infinite-area hyperbolic surfaces

    CERN Document Server

    Borthwick, David

    2016-01-01

    This text introduces geometric spectral theory in the context of infinite-area Riemann surfaces, providing a comprehensive account of the most recent developments in the field. For the second edition the context has been extended to general surfaces with hyperbolic ends, which provides a natural setting for development of the spectral theory while still keeping technical difficulties to a minimum. All of the material from the first edition is included and updated, and new sections have been added. Topics covered include an introduction to the geometry of hyperbolic surfaces, analysis of the resolvent of the Laplacian, scattering theory, resonances and scattering poles, the Selberg zeta function, the Poisson formula, distribution of resonances, the inverse scattering problem, Patterson-Sullivan theory, and the dynamical approach to the zeta function. The new sections cover the latest developments in the field, including the spectral gap, resonance asymptotics near the critical line, and sharp geometric constan...

  20. Thermal Desorption Analysis of Effective Specific Soil Surface Area

    Science.gov (United States)

    Smagin, A. V.; Bashina, A. S.; Klyueva, V. V.; Kubareva, A. V.

    2017-12-01

    A new method of assessing the effective specific surface area based on the successive thermal desorption of water vapor at different temperature stages of sample drying is analyzed in comparison with the conventional static adsorption method using a representative set of soil samples of different genesis and degree of dispersion. The theory of the method uses the fundamental relationship between the thermodynamic water potential (Ψ) and the absolute temperature of drying ( T): Ψ = Q - aT, where Q is the specific heat of vaporization, and a is the physically based parameter related to the initial temperature and relative humidity of the air in the external thermodynamic reservoir (laboratory). From gravimetric data on the mass fraction of water ( W) and the Ψ value, Polyanyi potential curves ( W(Ψ)) for the studied samples are plotted. Water sorption isotherms are then calculated, from which the capacity of monolayer and the target effective specific surface area are determined using the BET theory. Comparative analysis shows that the new method well agrees with the conventional estimation of the degree of dispersion by the BET and Kutilek methods in a wide range of specific surface area values between 10 and 250 m2/g.

  1. Effects of acid treatment on the clay palygorskite: XRD, surface area, morphological and chemical composition

    Energy Technology Data Exchange (ETDEWEB)

    Xavier, Katiane Cruz Magalhaes; Santos, Maria do Socorro Ferreira dos; Santos, Maria Rita Morais Chaves; Oliveira, Marilia Evelyn Rodrigues; Osajima, Josy Antevelli; Silva Filho, Edson Cavalcanti da [Universidade Federal do Piaui (UFPI), Teresina, PI (Brazil); Carvalho, Maria Wilma Nunes Cordeiro, E-mail: edsonfilho@ufpi.edu.br [Universidade Federal de Campina Grande (UFCG), PB (Brazil)

    2014-08-15

    The palygorskite is an aluminum-magnesium silicate that has a fibrous morphology. Their physicochemical characteristics are the result of high surface area, porosity and thermal resistance which make it an attractive adsorbent. Its adsorption capacity can be increased through chemical reactions and/or heat treatments. The objective of this work is to verify the effects of acid activation on the palygorskite, treated with HCl at 90 °C at concentrations of 2, 4 and 6 mol L{sup -1} in 2 and 4 hours, with clay/acid solution ratio 1 g 10 mL{sup -1} and characterized by techniques: XRF, XRD and surface area. A significant increase in specific surface area was observed in the sample treated with HCl at the concentration 6 mol L{sup -1}. The changes were more pronounced at stricter concentrations of acidity, with decreasing intensity of reflection of the clay indicated in the XRD. These changes were confirmed in the XRF with the leaching of some oxides and with increasing concentration of SiO{sub 2}. (author)

  2. Complex Surface Concentration Gradients by Stenciled "Electro Click Chemistry"

    DEFF Research Database (Denmark)

    Hansen, Thomas Steen; Lind, Johan Ulrik; Daugaard, Anders Egede

    2010-01-01

    Complex one- or two-dimensional concentration gradients of alkynated molecules are produced on azidized conducting polymer substrates by stenciled "electro click chemistry". The latter describes the local electrochemical generation of catalytically active Cu(I) required to complete a "click...... reaction" between alkynes and azides at room temperature. A stencil on the counter electrode defines the shape and multiplicity of the gradient(s) on the conducting polymer substrate, while the specific reaction conditions control gradient steepness and the maximum concentration deposited. Biologically...

  3. Solvent accessible surface area (ASA) of simulated phospholipid membranes

    DEFF Research Database (Denmark)

    Tuchsen, E.; Jensen, Morten Østergaard; Westh, P.

    2003-01-01

    The membrane-solvent interface has been investigated through calculations of the solvent accessible surface area (ASA) for simulated membranes of DPPC and POPE. For DPPC at 52 degreesC we found an ASA of 126 +/- 8 Angstrom(2) per lipid molecule, equivalent to twice the projected lateral area......, even the most exposed parts of the PC head-group show average ASAs of less than half of its maximal or 'fully hydrated' value. The average ASA of a simulated POPE membrane was 96 +/- 7 Angstrom(2) per lipid. The smaller value than for DPPC reflects much lower ASA of the ammonium ion, which is partially...... compensated by increased exposure of the ethylene and phosphate moieties. The ASA of the polar moieties Of (PO4, NH3 and COO) constitutes 65% of the total accessible area for POPE, making this interface more polar than that of DPPC. It is suggested that ASA information can be valuable in attempts...

  4. Assessment of Heavy Metals Concentrations in the Surface Water of ...

    African Journals Online (AJOL)

    The digested samples were analyzed for Fe, Cr, Cu, Zn and Pb using Atomic Absorption Spectrophotometer (Model IL250). The seasonal sequence of heavy metals concentrations showed Zn>Fe>Cr>Cu>Pb and Fe>Zn>Cr>Cu>Pb in dry and wet seasons respectively, while that of annual was Cr>Fe>Zn>Cu>Pb. The results ...

  5. Trapped surfaces due to concentration of gravitational radiation

    International Nuclear Information System (INIS)

    Beig, R.; O Murchadha, N.

    1991-01-01

    Sequences of global, asympotically flat solutions to the time-symmetric initial value constraints of general relativity in vacuo are constructed which develop outer trapped surfaces for large values of the argument. Thus all such configurations must gravitationally collapse. A new proof of the positivity of mass in the strong-field regime is also found. (Authors) 22 refs

  6. Lead Concentrations and Risk Exposure Assessment in Surface ...

    African Journals Online (AJOL)

    ADOWIE PERE

    µm, < 250 µm, and < 75 µm of surface soils at undeveloped residential lands leased to auto-mechanic artisans for a minimum of ten years and estimated exposure risk for children that will reside on the polluted lands after the lease periods. Soil-Pb levels ranges obtained were ... Other factors considered were closeness to.

  7. Study of measurement methods of ultrafine aerosols surface-area for characterizing occupational exposure

    International Nuclear Information System (INIS)

    Bau, S.

    2008-12-01

    This work aims at improving knowledge on ultrafine aerosols surface-area measurement. Indeed, the development of nano-technologies may lead to occupational exposure to airborne nano-structured particles, which involves a new prevention issue. There is currently no consensus concerning what parameter (mass, surface-area, number) should be measured. However, surface-area could be a relevant metric, since it leads to a satisfying correlation with biological effects when nano-structured particles are inhaled. Hence, an original theoretical work was performed to position the parameter of surface-area in relation to other aerosol characteristics. To investigate measurement techniques of nano-structured aerosols surface-area, the experimental facility CAIMAN (Characterization of Instruments for the Measurement of Aerosols of Nano-particles) was designed and built. Within CAIMAN, it is possible to produce nano-structured aerosols with varying and controlled properties (size, concentration, chemical nature, morphology, state-of-charge), stable and reproducible in time. The generated aerosols were used to experimentally characterize the response of the instruments in study (NSAM and AeroTrak 9000 TSI, LQ1-DC Matter Engineering). The response functions measured with monodisperse aerosols show a good agreement with the corresponding theoretical curves in a large size range, from 15 to 520 nm. Furthermore, hypotheses have been formulated to explain the reasonable biases observed when measuring poly-disperse aerosols. (author)

  8. Characteristics of PAHs adsorbed on street dust and the correlation with specific surface area and TOC.

    Science.gov (United States)

    Wang, Chengkun; Li, Yingxia; Liu, Jingling; Xiang, Li; Shi, Jianghong; Yang, Zhifeng

    2010-10-01

    Street dust was collected from five roads with different traffic volumes in the metropolitan area of Beijing and separated into five size fractions. Concentrations of polycyclic aromatic hydrocarbons (PAHs) adsorbed on street dust in different size ranges and their correlation with specific surface area and total organic carbon (TOC) were investigated. Results show that the concentration of 16-PAHs of sieved samples ranges from 0.27 to 1.30 mg/kg for all the sampling sites. Particles smaller than 40 mum in diameter have the highest 16-PAHs concentration among all of the size ranges for street dust from the four sampling sites with vehicles running on. PAHs with three or four rings account for 68% of the overall 16-PAHs on average. Remarkable positive correlation exists between 16-PAHs concentration and specific surface area with R(2) values from 0.7 to 0.96 for the four sampling sites with vehicles running on. The relationship between the concentration of 16-PAHs and TOC is less clear.

  9. Ambient pressure dried tetrapropoxysilane-based silica aerogels with high specific surface area

    Science.gov (United States)

    Parale, Vinayak G.; Han, Wooje; Jung, Hae-Noo-Ree; Lee, Kyu-Yeon; Park, Hyung-Ho

    2018-01-01

    In the present paper, we report the synthesis of tetrapropoxysilane (TPOS)-based silica aerogels with high surface area and large pore volume. The silica aerogels were prepared by a two-step sol-gel process followed by surface modification via a simple ambient pressure drying approach. In order to minimize drying shrinkage and obtain hydrophobic aerogels, the surface of the alcogels was modified using trichloromethylsilane as a silylating agent. The effect of the sol-gel compositional parameters on the polymerization of aerogels prepared by TPOS, one of the precursors belonging to the Si(OR)4 family, was reported for the first time. The oxalic acid and NH4OH concentrations were adjusted to achieve good-quality aerogels with high surface area, low density, and high transparency. Controlling the hydrolysis and condensation reactions of the TPOS precursor turned out to be the most important factor to determine the pore characteristics of the aerogel. Highly transparent aerogels with high specific surface area (938 m2/g) and low density (0.047 g/cm3) could be obtained using an optimized TPOS/MeOH molar ratio with appropriate concentrations of oxalic acid and NH4OH.

  10. Concentration distributions of thoron and radon near the ground surface

    Energy Technology Data Exchange (ETDEWEB)

    Katase, Akira [Tohwa Univ., Fukuoka (Japan). Faculty of Engineering

    1996-12-01

    One dimensional diffusion model with a constant diffusion coefficient is applied to the thoron concentration distributions in air above the ground. The experimental distributions are well described by the exponential function obtained from the model. Diffusion coefficients and thoron exhalation rates are estimated from the measured distributions, which are the average values for three months. The present values of thoron exhalation are however several times as small as those measured by other researchers. (author)

  11. Molecularly-Limited Fractal Surface Area of Mineral Powders

    Directory of Open Access Journals (Sweden)

    Petr Jandacka

    2016-05-01

    Full Text Available The topic of the specific surface area (SSA of powders is not sufficiently described in the literature in spite of its nontrivial contribution to adsorption and dissolution processes. Fractal geometry provides a way to determine this parameter via relation SSA ~ x(D − 3s(2 − D, where x (m is the particle size and s (m is a scale. Such a relation respects nano-, micro-, or macro-topography on the surface. Within this theory, the fractal dimension 2 ≤ D < 3 and scale parameter s plays a significant role. The parameter D may be determined from BET or dissolution measurements on several samples, changing the powder particle sizes or sizes of adsorbate molecules. If the fractality of the surface is high, the SSA does not depend on the particle size distribution and vice versa. In this paper, the SSA parameter is analyzed from the point of view of adsorption and dissolution processes. In the case of adsorption, a new equation for the SSA, depending on the term (2 − D∙(s2 − sBET/sBET, is derived, where sBET and s2 are effective cross-sectional diameters for BET and new adsorbates. Determination of the SSA for the dissolution process appears to be very complicated, since the fractality of the surface may change in the process. Nevertheless, the presented equations have good application potential.

  12. Area G Perimeter Surface-Soil Sampling Environmental Surveillance for Fiscal Year 1998 Hazardous and Solid Waste Group (ESH-19)

    Energy Technology Data Exchange (ETDEWEB)

    Marquis Childs

    1999-09-01

    Material Disposal Area G (Area G) is at Technical Area 54 at Los Alamos National Laboratory (LANL). Area G has been the principal facility for the disposal of low-level, solid-mixed, and transuranic waste since 1957. It is currently LANL's primary facility for radioactive solid waste burial and storage. As part of the annual environmental surveillance effort at Area G, surface soil samples are collected around the facility's perimeter to characterize possible radionuclide movement off the site through surface water runoff During 1998, 39 soil samples were collected and analyzed for percent moisture, tritium, plutonium-238 and 239, cesium-137 and americium-241. To assess radionuclide concentrations, the results from these samples are compared with baseline or background soil samples collected in an undisturbed area west of the active portion Area G. The 1998 results are also compared to the results from analogous samples collected during 1996 and 1997 to assess changes over this time in radionuclide activity concentrations in surface soils around the perimeter of Area G. The results indicate elevated levels of all the radionuclides assessed (except cesium-137) exist in Area G perimeter surface soils vs the baseline soils. The comparison of 1998 soil data to previous years (1996 and 1997) indicates no significant increase or decrease in radionuclide concentrations; an upward or downward trend in concentrations is not detectable at this time. These results are consistent with data comparisons done in previous years. Continued annual soil sampling will be necessary to realize a trend if one exists. The radionuclide levels found in the perimeter surface soils are above background but still considered relatively low. This perimeter surface soil data will be used for planning purposes at Area G, techniques to prevent sediment tm.nsport off-site are implemented in the areas where the highest radionuclide concentrations are indicated.

  13. Investigation on the growth of DAST crystals of large surface area for THz applications

    International Nuclear Information System (INIS)

    Vijay, R. Jerald; Melikechi, N.; Thomas, Tina; Gunaseelan, R.; Arockiaraj, M. Antony; Sagayaraj, P.

    2012-01-01

    Graphical abstract: It is evident from the photographs that the crystal tend to grow as a needle (Fig. 1a) in the lower concentration region (2–3 g/200 mL); whereas, in the high concentration region (5 g/200 mL) though there is a marked enlargement in the size of the crystal, the morphology of the resulting DAST crystal is slightly irregular (Fig. 1d) in nature. Among the four concentrations employed, best result was obtained with the DAST–methanol solution of concentration 4 g/200 mL; which resulted in the DAST crystal of large surface area (270 mm 2 ) with high transparency and nearly square shape (Fig. 1c) in a growth period of 20–25 days. Highlights: ► DAST crystals of different sizes are obtained for different concentrations. ► The main focus is to grow DAST crystals with large surface area. ► Structural, optical, thermal and mechanical properties are investigated. - Abstract: The growth of high quality 4-N,N-dimethylamino-4-N-methyl-stilbazoliumtosylate (DAST) crystal with large surface area is reported by adopting the slope nucleation coupled slow evaporation method (SNM-SE). The structure and composition of the crystal are studied by single crystal X-ray diffraction and CHN analyses. The linear optical properties are investigated by UV–vis absorption. The melting point and thermal behavior of DAST are investigated using differential scanning calorimetric (DSC) and thermogravimetric analyses (TGA). The Vickers microhardness number (VHN) and work hardening coefficient of the grown crystal have been determined. The surface features of the DAST crystal are analyzed by scanning electron microscopy (SEM) and it confirmed the presence of narrow line defects (NLDs) in the sample.

  14. Radionuclide Concentrations in Honey Bees from Area G at TA-54 during 1999

    Energy Technology Data Exchange (ETDEWEB)

    T. K. Haarmann; P. R. Fresquez

    2000-06-01

    Honey bees were collected from two colonies located at Los Alamos National Laboratory's Area G, Technical Area 54, and from one control (background) colony located near Jemez Springs, NM. Samples were analyzed for various radionuclides. Area G sample results from both colonies were higher than the upper (95%) level background concentration for {sup 3}H. Sample results from one colony were higher than the upper (95%) level background concentration for total uranium, while sample results from the other colony were higher than the upper (95%) level background concentration for {sup 90}Sr.

  15. Radionuclide Concentrations in Honey Bees from Area G at TA-54 during 1999

    International Nuclear Information System (INIS)

    Haarmann, T. K.; Fresquez, P.R.

    2000-01-01

    Honey bees were collected from two colonies located at Los Alamos National Laboratory's Area G, Technical Area 54, and from one control (background) colony located near Jemez Springs, NM. Samples were analyzed for various radionuclides. Area G sample results from both colonies were higher than the upper (95%) level background concentration for 3 H. Sample results from one colony were higher than the upper (95%) level background concentration for total uranium, while sample results from the other colony were higher than the upper (95%) level background concentration for 90 Sr

  16. The impact of anthropogenic and biogenic emissions on surface ozone concentrations in Istanbul.

    Science.gov (United States)

    Im, Ulas; Poupkou, Anastasia; Incecik, Selahattin; Markakis, Konstantinos; Kindap, Tayfun; Unal, Alper; Melas, Dimitros; Yenigun, Orhan; Topcu, Sema; Odman, M Talat; Tayanc, Mete; Guler, Meltem

    2011-03-01

    Surface ozone concentrations at Istanbul during a summer episode in June 2008 were simulated using a high resolution and urban scale modeling system coupling MM5 and CMAQ models with a recently developed anthropogenic emission inventory for the region. Two sets of base runs were performed in order to investigate for the first time the impact of biogenic emissions on ozone concentrations in the Greater Istanbul Area (GIA). The first simulation was performed using only the anthropogenic emissions whereas the second simulation was performed using both anthropogenic and biogenic emissions. Biogenic NMVOC emissions were comparable with anthropogenic NMVOC emissions in terms of magnitude. The inclusion of biogenic emissions significantly improved the performance of the model, particularly in reproducing the low night time values as well as the temporal variation of ozone concentrations. Terpene emissions contributed significantly to the destruction of the ozone during nighttime. Biogenic NMVOCs emissions enhanced ozone concentrations in the downwind regions of GIA up to 25ppb. The VOC/NO(x) ratio almost doubled due to the addition of biogenic NMVOCs. Anthropogenic NO(x) and NMVOCs were perturbed by ±30% in another set of simulations to quantify the sensitivity of ozone concentrations to the precursor emissions in the region. The sensitivity runs, as along with the model-calculated ozone-to-reactive nitrogen ratios, pointed NO(x)-sensitive chemistry, particularly in the downwind areas. On the other hand, urban parts of the city responded more to changes in NO(x) due to very high anthropogenic emissions. Copyright © 2010 Elsevier B.V. All rights reserved.

  17. Metal-organic framework materials with ultrahigh surface areas

    Science.gov (United States)

    Farha, Omar K.; Hupp, Joseph T.; Wilmer, Christopher E.; Eryazici, Ibrahim; Snurr, Randall Q.; Gomez-Gualdron, Diego A.; Borah, Bhaskarjyoti

    2015-12-22

    A metal organic framework (MOF) material including a Brunauer-Emmett-Teller (BET) surface area greater than 7,010 m.sup.2/g. Also a metal organic framework (MOF) material including hexa-carboxylated linkers including alkyne bond. Also a metal organic framework (MOF) material including three types of cuboctahedron cages fused to provide continuous channels. Also a method of making a metal organic framework (MOF) material including saponifying hexaester precursors having alkyne bonds to form a plurality of hexa-carboxylated linkers including alkyne bonds and performing a solvothermal reaction with the plurality of hexa-carboxylated linkers and one or more metal containing compounds to form the MOF material.

  18. Asymptotic variance of grey-scale surface area estimators

    DEFF Research Database (Denmark)

    Svane, Anne Marie

    Grey-scale local algorithms have been suggested as a fast way of estimating surface area from grey-scale digital images. Their asymptotic mean has already been described. In this paper, the asymptotic behaviour of the variance is studied in isotropic and sufficiently smooth settings, resulting...... in a general asymptotic bound. For compact convex sets with nowhere vanishing Gaussian curvature, the asymptotics can be described more explicitly. As in the case of volume estimators, the variance is decomposed into a lattice sum and an oscillating term of at most the same magnitude....

  19. Isopleths of surface air concentration and surface air kerma rate due to a radioactive cloud released from a stack (3)

    International Nuclear Information System (INIS)

    Tachibana, Haruo; Kikuchi, Masamitsu; Sekita, Tsutomu; Yamaguchi, Takenori

    2004-06-01

    This report is a revised edition of 'Isopleths of Surface Air Concentration and Surface Air Absorbed Dose Rate due to a Radioactive Cloud Released from a Stack(II) '(JAERI-M 90-206) and based on the revised Nuclear Safety Guidelines reflected the ICRP1990 Recommendation. Characteristics of this report are the use of Air Karma Rate (Gy/h) instead of Air Absorbed Dose Rate (Gy/h), and the record of isopleths of surface air concentration and surface air karma rate on CD-ROM. These recorded data on CD-ROM can be printed out on paper and/or pasted on digital map by personal computer. (author)

  20. The protection of urban areas from surface wastewater pollutions

    Directory of Open Access Journals (Sweden)

    Vialkova Elena

    2017-01-01

    Full Text Available In this paper it considered the problem of collection, treatment and discharge into waters of rain and melted wastewater. To reduce the load on the combined sewer system, there are engineering solutions collect rain and melt water for use in the irrigation of lawns and green spaces. Research carried out at the department “Water supply and sanitation”, (Russia, confirm the high pollution concentrations of meltwater and rainfall in urban arias. Series of measurements of heavy metal in rainwater runoff carried out in Hungary demonstrates clearly the differences in concentrations in the function of distance from the edge of the road. Also differences are introduced between pollution concentrations in runoff water from within and outside urban traffic roads. The quality of snow cover, forming meltwater is observed to be changing in dependence on roadway location. Quality characteristics of surface runoff and its sediments can be effectively improved with super-high frequency radiation (SHF treatment which is presented in this paper.

  1. Modulation of ATP/ADP concentration at the endothelial surface by shear stress: effect of flow recirculation.

    Science.gov (United States)

    Choi, Hyo Won; Ferrara, Katherine W; Barakat, Abdul I

    2007-04-01

    The extracellular presence of the adenine nucleotides ATP and ADP induces calcium mobilization in vascular endothelial cells (ECs). ATP/ADP concentration at the EC surface is determined by a balance of convective-diffusive transport to and from the EC surface, hydrolysis by ectonucleotidases at the cell surface, and flow-induced ATP release from ECs. Our previous numerical simulations in a parallel plate geometry had demonstrated that flow-induced ATP release has a profound effect on nucleotide concentration at the EC surface. In the present study, we have extended the modeling to probe the impact of flow separation and recirculation downstream of a backward facing step (BFS) on ATP/ADP concentration at the EC surface. The results show that for both steady and pulsatile flow over a wide range of wall shear stresses, the ATP+ADP concentration at the EC surface is considerably lower within the flow recirculation region than in areas of undisturbed flow outside the recirculation zone. Pulsatile flow also leads to sharp temporal gradients in nucleotide concentration. If confirmed experimentally, the present findings suggest that disturbed and undisturbed flow may affect EC calcium mobilization differently. Such differences might, in turn, contribute to the observed endothelial dysfunction in regions of disturbed flow.

  2. Heavy metal contamination in surface runoff sediments of the urban area of Vilnius, Lithuania

    Directory of Open Access Journals (Sweden)

    Gytautas Ignatavičius

    2017-02-01

    Full Text Available Surface runoff from urbanized territories carries a wide range of pollutants. Sediments in untreated runoff from direct discharge stormwater systems significantly contribute to urban waterway pollution. In this study, heavy metal (Pb, Zn, Cu, Cr, Ba, As and Fe contamination in surface runoff sediments of the urban area of the city of Vilnius was investigated. The surface runoff sediment samples were collected from seven dischargers with the highest volume rate of water flow and concentrations of suspended solids. The geospatial analysis of the distribution of heavy metals shows that there are several active pollution sources supplying the dischargers with contaminated sediments. Most of these areas are located in the central part of the city and in old town with intense traffic. Principal components analysis and t-test results clearly depicted the significantly different chemical compositions of winter and autumn surface sediment samples. The sampling approach and assessment of results provide a useful tool to examine the contamination that is generated in urban areas, distinguish pollution sources and give a better understanding of the importance of permeable surfaces and green areas.

  3. [Arterial plasma histamine concentration for airway obstruction due to different areas of the bronchial system. IV. Communication (author's transl)].

    Science.gov (United States)

    Zimmermann, I; Ulmer, W T

    1980-01-01

    The separate inhalation of A.E. aerosol in the upper and the peripheral parts of the airways in allergic dogs is followed by an increase of the histamine concentration in the arterial plasma. The correlation between the plasma histamine concentration and dynamic elastance and the correlation between dynamic elastance and arterial oxygen pressure is very similar following the challenge of the upper and the peripheral parts of the airways. The results argue for reflex bronchoconstriction also by challenge of the more peripheral airways. The results are in accord with the idea that the answer of Edyn depends on a product of local histamine concentration and the area in which the histamine is released. The number of sensory receptors per surface area which is suspected to be greater in the upper part of the airways may also be important.

  4. Overcoming the reference large-area sources non-uniformity in surface area monitor calibration

    Energy Technology Data Exchange (ETDEWEB)

    Junior, Iremar Alves S.; Siqueira, Paulo de T.D.; Xavier, Marcs; Nascimento, Eduardo do; Potiens, Maria da Penha A., E-mail: iremarjr@usp.br, E-mail: ptsiquei@ipen.br, E-mail: mxavier@ipen.br, E-mail: eduardon@ufba.br, E-mail: mppalbu@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2015-07-01

    This paper describes a study using MCNP5 simulations, a Monte Carlo based radiation transport code, in order to evaluate the possibility of using reference large-area sources that do not meet the uniformity recommendations of the ISO 8769:2010 in surface contamination monitors calibration. {sup 14}C, {sup 36}Cl, {sup 99}Tc, {sup 137}Cs and {sup 90}Sr + {sup 90}Y large area reference sources were simulated as well as the setup and the detector probe. Simulations were carried out for both uniform and non-uniform surface distributions. In the case of uniform distribution, specific weights for each region were considered, as obtained in the uniformity evaluation measurements. To each simulation, it was considered the average number of signals generated in each detector probe, i.e., it was determined the fraction of stories depositing energy in the corresponding gas filled region of the detector. Simulations results show differences in detection efficiency values up to 15%. (author)

  5. Program for estimating surface air concentrations of NPP discharge radionuclides

    International Nuclear Information System (INIS)

    Ivanov, E.A.; Ramzina, T.V.; Sokolova, E.Yu.

    1986-01-01

    Methods for calculating short-term values of ground-level specific activity in the NPP region and the values averaged for an extended period are described. These methods are realized in the LAURA program on the FORTRAN 4 language for the ES-1033 computer with the OS ES translator and the EMQ-666 computer. As a result of program execution, the user receives the following information: 1) the table for radionuclide surface specific activity values depending on the direction and distance from the source; the wind rose matrix and conditional probabilities of the atmosphere stability category; 2) the map of isolines of radionuclide specific activity in a grid given in polar coordinates with marks of level lines according to their values

  6. A baseline record of trace elements concentration along the beach placer mining areas of Kanyakumari coast, South India.

    Science.gov (United States)

    Simon Peter, T; Chandrasekar, N; John Wilson, J S; Selvakumar, S; Krishnakumar, S; Magesh, N S

    2017-06-15

    Trace element concentration in the beach placer mining areas of Kanyakumari coast, South India was assessed. Sewage and contaminated sediments from mining sites has contaminated the surface sediments. Enrichment factor indicates moderately severe enrichment for Pb, minor enrichment for Mn, Zn, Ni, Fe and no enrichment for Cr and Cu. The Igeo values show higher concentration of Pb ranging in the scale of 3-4, which shows strong contamination due to high anthropogenic activity such as mining and terrestrial influences into the coastal regions. Correlation coefficient shows that most of the elements are associated with each other except Ni and Pb. Factor analysis reveals that Mn, Zn, Fe, Cr, Pb and Cu are having a significant loading and it indicates that these elements are mainly derived from similar origin. The cluster analysis clearly indicated that the mining areas are grouped under cluster 2 and non-mining areas are clustered under group 1. Copyright © 2017 Elsevier Ltd. All rights reserved.

  7. Error bounds for surface area estimators based on Crofton's formula

    DEFF Research Database (Denmark)

    Kiderlen, Markus; Meschenmoser, Daniel

    2009-01-01

    According to Crofton’s formula, the surface area S(A) of a sufficiently regular compact set A in R^d is proportional to the mean of all total projections pA (u) on a linear hyperplane with normal u, uniformly averaged over all unit vectors u. In applications, pA (u) is only measured in k directio...... in the sense that the relative error of the surface area estimator is very close to the minimal error....... and the mean is approximated by a finite weighted sum S(A) of the total projections in these directions. The choice of the weights depends on the selected quadrature rule. We define an associated zonotope Z (depending only on the projection directions and the quadrature rule), and show that the relative error...... S (A)/S (A) is bounded from below by the inradius of Z and from above by the circumradius of Z. Applying a strengthened isoperimetric inequality due to Bonnesen, we show that the rectangular quadrature rule does not give the best possible error bounds for d = 2. In addition, we derive asymptotic...

  8. Variation of radiocesium concentrations in cedar pollen in the Okutama area since the Fukushima Daiichi Nuclear Power Plant accident

    International Nuclear Information System (INIS)

    Tsuruoka, H.; Inoue, K.; Sakano, Y.; Hamada, M.; Shimizu, H.; Fukushi, M.

    2015-01-01

    Due to releases of radionuclides in the Fukushima Daiichi Nuclear Power Plant accident, radiocesium ( 134 Cs and 137 Cs) has been incorporated into large varieties of plant species and soil types. There is a possibility that radiocesium taken into plants is being diffused by pollen. Radiocesium concentrations in cedar pollen have been measured in Ome City, located in the Okutama area of metropolitan Tokyo, for the past 3 y. In this research, the variation of radiocesium concentrations was analysed by comparing data from 2011 to 2014. Air dose rates at 1 m above the ground surface in Ome City from 2011 to 2014 showed no significant difference. Concentration of 137 Cs contained in the cedar pollen in 2012 was about half that in 2011. Between 2012 and 2014, the concentration decreased by approximately one-fifth, which was similar to the result of a press release distributed by the Japanese Ministry of Agriculture, Forestry and Fisheries. (authors)

  9. Irradiation induced surface segregation in concentrated alloys: a contribution

    International Nuclear Information System (INIS)

    Grandjean, Y.

    1996-01-01

    A new computer modelization of irradiation induced surface segregation is presented together with some experimental determinations in binary and ternary alloys. The model we propose handles the alloy thermodynamics and kinetics at the same level of sophistication. Diffusion is described at the atomistic level and proceeds vis the jumps of point defects (vacancies, dumb-bell interstitials): the various jump frequencies depend on the local composition in a manner consistent with the thermodynamics of the alloy. For application to specific alloys, we have chosen the simplest statistical approximation: pair interactions in the Bragg Williams approximation. For a system which exhibits the thermodynamics and kinetics features of Ni-Cu alloys, the model generates the behaviour parameters (flux and temperature) and of alloy composition. Quantitative agreement with the published experimental results (two compositions, three temperatures) is obtained with a single set of parameters. Modelling austenitic steels used in nuclear industry requires taking into account the contribution of dumbbells to mass transport. The effects of this latter contribution are studied on a model of Ni-Fe. Interstitial trapping on dilute impurities is shown to delay or even suppress the irradiation induced segregation. Such an effect is indeed observed in the experiments we report on Fe 50 Ni 50 and Fe 49 Ni 50 Hf 1 alloys. (author)

  10. Airborne and waterborne radon concentrations in areas with use of groundwater supplies

    International Nuclear Information System (INIS)

    Ishikawa, T.; Tokonami, S.; Yoshinaga, S.; Narazaki, Y.

    2006-01-01

    A preliminary survey of airborne and waterborne radon concentrations was given for an area where groundwater is used as a source of public water supply. The average of the waterborne radon concentrations was 77 Bq/l for 36 samples and that of airborne radon concentrations was 18 Bq/m 3 for ten houses. It is concluded that the exposure dose due to radon-in-water is likely to be much smaller than the total dose from natural radiation. (author)

  11. Spatial Evaluation of Heavy Metals Concentrations in the Surface Sediment of Taihu Lake

    Science.gov (United States)

    Niu, Yong; Jiao, Wei; Yu, Hui; Niu, Yuan; Pang, Yong; Xu, Xiangyang; Guo, Xiaochun

    2015-01-01

    With regard to the size of China’s freshwater lakes, Taihu Lake ranks third and it plays an important role in the supply of drinking water, flood prevention, farming and navigation, as well as in the travelling industry. The problem of environmental pollution has attracted widespread attention in recent years. In order to understand the levels, distribution and sources of heavy metals in sediments of Taihu Lake, random selection was carried out to obtain 59 samples of surface sediment from the entire lake and study the concentrations of Pb, Cd, Cu, Zn, Cr and Ni. Toxic units were also calculated to normalize the toxicities caused by various heavy metals. As a result, Cd and Cu in sediment were considered lower than the effect range low (ERL) at all regions where samples were gathered, while Pb and Ni were categorized into ERL-effect range median (ERM) at over 22% of the regions where samples were obtained. Nevertheless, all average concentrations of the samples were below the level of potential effect. According to the findings of this research, significant spatial heterogeneity existed in the above heavy metals. In conclusion, the distribution areas of heavy metals with higher concentrations were mainly the north bays, namely Zhushan Bay, Meiliang Bay as well as Gonghu Bay. The distribution areas of Cu, Zn, Cr and Ni with higher concentration also included the lake’s central region, whereas the uniform distribution areas of those with lower concentrations were the lake’s southeast region. In addition, it was most probable that the spatial distribution of heavy metals was determined by river inputs, whereas atmospheric precipitation caused by urban and traffic contamination also exerted considerable effects on the higher concentrations of Pb and Cd. Through evaluating the total amount of toxic units (ΣTU), it was found that higher toxicity existed primarily in the north bays and central region of the lake. If the heavy metals were sorted by the reduction of

  12. Heavy metal concentrations in soils and vegetation in urban areas of Quezon City, Philippines.

    Science.gov (United States)

    Navarrete, Ian A; Gabiana, Christella C; Dumo, Joan Ruby E; Salmo, Severino G; Guzman, Maria Aileen Leah G; Valera, Nestor S; Espiritu, Emilyn Q

    2017-04-01

    Limited data have been published on the chemistry of urban soils and vegetation in the Philippines. The aim of this study is to quantify the concentrations of heavy metals (i.e., Cr, Ni, Cu, Zn, and Pb) in soils and vegetation in the urban landscape of Quezon City, Philippines, and to elucidate the relationships between soil properties and the concentration of heavy metals pertaining to different land uses [i.e., protected forest (LM), park and wildlife area (PA), landfill (PL), urban poor residential and industrial areas (RA), and commercial areas (CA)]. Soil (0-15 cm) and senescent plant leaves were collected and were analyzed for soil properties and heavy metal concentrations. Results revealed that the concentrations of heavy metals (i.e., Cr, Ni, Cu, Zn, and Pb) in urban soils were higher in areas where anthropogenic activities or disturbance (PL, RA, and CA) were dominant as compared to the less disturbed areas (LM and PA). Organic matter and available phosphorous were strongly correlated with heavy metal concentrations, suggesting that heavy metal concentrations were primarily controlled by these soil properties. The average foliar heavy metal concentrations varied, ranging from 0 to 0.4 mg/kg for Cd, 0-10 mg/kg for Cr, 2-22 mg/kg for Cu, 0-5 mg/kg for Pb, and 11-250 mg/kg for Zn. The concentrations of Cd and Cr exceeded the critical threshold concentrations in some plants. Leaves of plants growing in PL (i.e., landfill) showed the highest levels of heavy metal contamination. Our results revealed that anthropogenic activities and disturbance caused by the rapid urbanization of the city are major contributors to the heavy metal accumulation and persistence in the soils in these areas.

  13. Amylolytic hydrolysis of native starch granules affected by granule surface area.

    Science.gov (United States)

    Kim, J C; Kong, B W; Kim, M J; Lee, S H

    2008-11-01

    Initial stage of hydrolysis of native starch granules with various amylolytic enzymes, alpha-amylase from Bacillus subtilis, glucoamylase I (GA-I) and II (GA-II) from Aspergillus niger, and beta-amylase from sweet potato showed that the reaction was apparently affected by a specific surface area of the starch granules. The ratios of the reciprocal of initial velocity of each amylolytic hydrolysis for native potato and maize starch to that for rice with the amylolytic enzymes were nearly equivalent to the ratio of surface area per mass of the 2 starch granules to that of rice, that is, 6.94 and 2.25, respectively. Thus, the reciprocal of initial velocity of each enzymatic hydrolysis as expressed in a Lineweaver-Burk plot was a linear function of the reciprocal of surface area for each starch granule. As a result, it is concluded that amylolytic hydrolysis of native starch granules is governed by the specific surface area, not by the mass concentration, of each granule.

  14. Kernel density surface modelling as a means to identify significant concentrations of vulnerable marine ecosystem indicators.

    Directory of Open Access Journals (Sweden)

    Ellen Kenchington

    Full Text Available The United Nations General Assembly Resolution 61/105, concerning sustainable fisheries in the marine ecosystem, calls for the protection of vulnerable marine ecosystems (VME from destructive fishing practices. Subsequently, the Food and Agriculture Organization (FAO produced guidelines for identification of VME indicator species/taxa to assist in the implementation of the resolution, but recommended the development of case-specific operational definitions for their application. We applied kernel density estimation (KDE to research vessel trawl survey data from inside the fishing footprint of the Northwest Atlantic Fisheries Organization (NAFO Regulatory Area in the high seas of the northwest Atlantic to create biomass density surfaces for four VME indicator taxa: large-sized sponges, sea pens, small and large gorgonian corals. These VME indicator taxa were identified previously by NAFO using the fragility, life history characteristics and structural complexity criteria presented by FAO, along with an evaluation of their recovery trajectories. KDE, a non-parametric neighbour-based smoothing function, has been used previously in ecology to identify hotspots, that is, areas of relatively high biomass/abundance. We present a novel approach of examining relative changes in area under polygons created from encircling successive biomass categories on the KDE surface to identify "significant concentrations" of biomass, which we equate to VMEs. This allows identification of the VMEs from the broader distribution of the species in the study area. We provide independent assessments of the VMEs so identified using underwater images, benthic sampling with other gear types (dredges, cores, and/or published species distribution models of probability of occurrence, as available. For each VME indicator taxon we provide a brief review of their ecological function which will be important in future assessments of significant adverse impact on these habitats here

  15. Radionuclide Concentrations in Honey Bees from Area G at TA-54 during 1998

    Energy Technology Data Exchange (ETDEWEB)

    Haarmann, T.K.; Fresquez, P.R.

    1999-06-01

    Honey bees were collected from two colonies located at Los Alamos National Laboratory's Area G, Technical Area 54, and from one control (background) colony located near Jemez Springs, NM. Samples were analyzed for various radionuclides. Area G sample results from both colonies were higher than the upper (95%) level background concentration for {sup 239,240}Pu, {sup 3}H, and total uranium. Sample results from one colony were higher than the upper (95%) level background concentration for {sup 238}Pu.

  16. A preformulation evaluation of a photosensitive surface active compound, explaining concentration dependent degradation.

    Science.gov (United States)

    Sigfridsson, Kalle; Carlsson, Karin E

    2017-11-15

    A candidate drug within the cardiovascular area was identified during early research and evaluated for further development. The aim was to understand and explain the degradation mechanisms for the present compound. The stability of the active pharmaceutical ingredient (API) in solution and solid state was studied during different conditions. The bulk compound was exposed to elevated temperatures, increased relative humidity and stressed light conditions. Degradation of the drug in solutions was followed in the presence versus absence of ethylenediaminetetraacetic acid (EDTA), during aerobic versus anaerobic conditions, stored protected from light versus exposed to light and as a function of pH and concentration. It was possible to improve the stability by adding EDTA and completely abolish degradation by storing dissolved compound at anaerobic conditions. Solutions of API were stable between pH3 and 7, with some degradation at pH1, when stored protected from light and at 22°C, but degrade rapidly when exposed to ambient light conditions. The degradation products were identified by mass spectroscopy. Degradation schemes were drawn. There was concentration dependence in the degradation of dissolved drug when exposed to light, showing a titration behavior that concurred with the measured critical micelle/aggregation concentration (CMC/CAC) of the compound. The compound was stable in solution during the investigated time period, at concentrations above CMC/CAC, where the molecule was protected from photodegradation when the compound aggregated. Below CMC/CAC, a significant degradation of the API occurred. This may be a potential explanation why other surface active compounds show concentration dependent degradation. The photosensitivity was also observed for the neutral compound in crystalline and amorphous form, as well as for the crystalline chloride salt of the drug. However, the degradation of amorphous form was faster compared to crystalline material. No

  17. Radionuclide concentrations in honey bees from Area G at TA-54 during 1997. Progress report

    International Nuclear Information System (INIS)

    Haarmann, T.K.; Fresquez, P.R.

    1998-07-01

    Honey bees were collected from two colonies located at Los Alamos National Laboratory's Area G, Technical Area 54, and from one control (background) colony located near Jamez Springs, NM. Samples were analyzed for the following: cesium ( 137 Cs), americium ( 241 Am), plutonium ( 238 Pu and 239,240 Pu), tritium ( 3 H), total uranium, and gross gamma activity. Area G sample results from both colonies were higher than the upper (95%) level background concentration for 238 Pu and 3 H

  18. Effects of trans-Eurasian transport of anthropogenic pollutants on surface ozone concentrations over China

    Science.gov (United States)

    Liu, J.; Li, X.; Mauzerall, D. L.; Emmons, L. K.; Horowitz, L. W.; Guo, Y.; Tao, S.

    2015-12-01

    Due to a lack of industrialization in Western China, surface air there was, until recently, believed to be relatively unpolluted. However, recent measurements and modeling studies have found high levels of ozone (O3) there. Based on the state-of-the-science global chemical transport model MOZART-4, we identify the origin, pathway, and mechanism of trans-Eurasian transport of air pollutants to Western China in 2000. MOZART-4 generally simulates well the observed surface O3 over inland areas of China. Simulations find surface ozone concentrations over Western China on average to be about 10 ppbv higher than Eastern China. Using sensitivity studies as well as a fully-tagged approach, we find that anthropogenic emissions from all Eurasian regions except China contribute 10-15 ppbv surface O3 over Western China, superimposed upon a 35-40 ppbv natural background. Transport from European anthropogenic sources to Northwestern China results in 2-6 ppbv O3 enhancements in spring and summer. Indian anthropogenic sources strongly influence O3 over the Tibetan Plateau during the summer monsoon. Transport of O3 originating from emissions in the Middle East occasionally reach Western China and increase surface ozone there by about 1-4 ppbv. These influences are of similar magnitude as trans-Pacific and transatlantic transport of O3 and its precursors, indicating the significance of trans-Eurasian ozone transport in hemispheric transport of air pollution. Our study further indicates that mitigation of anthropogenic emissions from Europe, the Indian subcontinent, and the Middle East could benefit public health and agricultural productivity in Western China.

  19. Measurement of radon concentration in some water samples belonging to some adjoining areas of Pathankot, Punjab

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, Ajay, E-mail: ajay782@rediffmail.com; Sharma, Sumit, E-mail: sumitshrm210@gmail.com [Post Graduate Department of Physics, DAV College, Amritsar-143001 (India)

    2015-08-28

    The study of radon concentration was measured in some areas of Pathankot district, Punjab, India, from the health hazard point of view due to radon. The exposure to radon through drinking water is largely by inhalation and ingestion. RAD 7, an electronic solid state silicon detector (Durridgeco., USA) was used to measure the radon concentration in drinking water samples of the study area. The recorded values of radon concentration in these water samples are below the recommended limit by UNSCEAR and European commission. The recommended limit of radon concentration in water samples is 4 to 40 Bq/l given by UNSCEAR [1] and European commission has recommended the safe limit for radon concentration in water sample is 100 Bq/l [2].

  20. Method for producing high surface area chromia materials for catalysis

    Science.gov (United States)

    Gash, Alexander E [Brentwood, CA; Satcher, Joe [Patterson, CA; Tillotson, Thomas [Tracy, CA; Hrubesh, Lawrence [Pleasanton, CA; Simpson, Randall [Livermore, CA

    2007-05-01

    Nanostructured chromium(III)-oxide-based materials using sol-gel processing and a synthetic route for producing such materials are disclosed herein. Monolithic aerogels and xerogels having surface areas between 150 m.sup.2/g and 520 m.sup.2/g have been produced. The synthetic method employs the use of stable and inexpensive hydrated-chromium(III) inorganic salts and common solvents such as water, ethanol, methanol, 1-propanol, t-butanol, 2-ethoxy ethanol, and ethylene glycol, DMSO, and dimethyl formamide. The synthesis involves the dissolution of the metal salt in a solvent followed by an addition of a proton scavenger, such as an epoxide, which induces gel formation in a timely manner. Both critical point (supercritical extraction) and atmospheric (low temperature evaporation) drying may be employed to produce monolithic aerogels and xerogels, respectively.

  1. Fully automated algorithm for wound surface area assessment.

    Science.gov (United States)

    Deana, Alessandro Melo; de Jesus, Sérgio Henrique Costa; Sampaio, Brunna Pileggi Azevedo; Oliveira, Marcelo Tavares; Silva, Daniela Fátima Teixeira; França, Cristiane Miranda

    2013-01-01

    Worldwide, clinicians, dentists, nurses, researchers, and other health professionals need to monitor the wound healing progress and to quantify the rate of wound closure. The aim of this study is to demonstrate, step by step, a fully automated numerical method to estimate the size of the wound and the percentage damaged relative to the body surface area (BSA) in images, without the requirement for human intervention. We included the formula for BSA in rats in the algorithm. The methodology was validated in experimental wounds and human ulcers and was compared with the analysis of an experienced pathologist, with good agreement. Therefore, this algorithm is suitable for experimental wounds and burns and human ulcers, as they have a high contrast with adjacent normal skin. © 2013 by the Wound Healing Society.

  2. Electromagnetic surface waves for large-area RF plasma productions between large-area planar electrodes

    International Nuclear Information System (INIS)

    Nonaka, S.

    1992-01-01

    Recently, large-area plasma production has been tested by means of a 13.56 MHz radio-frequency (RF) discharge between a pair of large-area planar electrodes, approximately 0.5 m x 1.4 m, as one of the semiconductor technologies for fabrication of large-area amorphous silicon solar cells in the ''Sunshine Project'' of the Agency of Industrial Science and Technology in Japan. We also confirmed long plasma production between a pair of long electrodes. In this paper, normal electromagnetic (EM) waves propagating in a region between a planar waveguide with one plasma and two dielectric layers are analyzed in order to study the feasibility of large-area plasma productions by EM wave-discharges between a pair of large-area RF electrodes larger than the half-wavelength of RF wave. In conclusion, plasmas higher than an electron plasma frequency will be produced by an odd TMoo surface mode. (author) 4 refs., 3 figs

  3. Heavy metal concentration in mangrove surface sediments from the north-west coast of South America.

    Science.gov (United States)

    Fernández-Cadena, J C; Andrade, S; Silva-Coello, C L; De la Iglesia, R

    2014-05-15

    Mangrove ecosystems are coastal estuarine systems confined to the tropical and subtropical regions. The Estero Salado mangrove located in Guayaquil, Ecuador, has suffered constant disturbances during the past 20 years, due to industrial wastewater release. However, there are no published data for heavy metals present in its sediments and the relationship with anthropogenic disturbance. In the present study, metal concentrations were evaluated in surface sediment samples of the mangrove, showing that B, Cd, Cu, Pb, Se, V, and Zn levels exceeded those declared in international environmental quality standards. Moreover, several metals (Pb, Sn, Cd, Ag, Mo, Zn and Ni) could be linked to the industrial wastewater present in the studied area. In addition, heavy metal levels detected in this mangrove are higher than previous reports on mangrove sediments worldwide, indicating that this mangrove ecosystem is one of the most disrupted on earth. Copyright © 2014 Elsevier Ltd. All rights reserved.

  4. Human cortical areas involved in perception of surface glossiness.

    Science.gov (United States)

    Wada, Atsushi; Sakano, Yuichi; Ando, Hiroshi

    2014-09-01

    Glossiness is the visual appearance of an object's surface as defined by its surface reflectance properties. Despite its ecological importance, little is known about the neural substrates underlying its perception. In this study, we performed the first human neuroimaging experiments that directly investigated where the processing of glossiness resides in the visual cortex. First, we investigated the cortical regions that were more activated by observing high glossiness compared with low glossiness, where the effects of simple luminance and luminance contrast were dissociated by controlling the illumination conditions (Experiment 1). As cortical regions that may be related to the processing of glossiness, V2, V3, hV4, VO-1, VO-2, collateral sulcus (CoS), LO-1, and V3A/B were identified, which also showed significant correlation with the perceived level of glossiness. This result is consistent with the recent monkey studies that identified selective neural response to glossiness in the ventral visual pathway, except for V3A/B in the dorsal visual pathway, whose involvement in the processing of glossiness could be specific to the human visual system. Second, we investigated the cortical regions that were modulated by selective attention to glossiness (Experiment 2). The visual areas that showed higher activation to attention to glossiness than that to either form or orientation were identified as right hV4, right VO-2, and right V3A/B, which were commonly identified in Experiment 1. The results indicate that these commonly identified visual areas in the human visual cortex may play important roles in glossiness perception. Copyright © 2014. Published by Elsevier Inc.

  5. Assessment of Surface Area Characteristics of Dental Implants with Gradual Bioactive Surface Treatment

    Science.gov (United States)

    Czan, Andrej; Babík, Ondrej; Miklos, Matej; Záušková, Lucia; Mezencevová, Viktória

    2017-10-01

    Since most of the implant surface is in direct contact with bone tissue, shape and integrity of said surface has great influence on successful osseointegration. Among other characteristics that predetermine titanium of different grades of pureness as ideal biomaterial, titanium shows high mechanical strength making precise miniature machining increasingly difficult. Current titanium-based implants are often anodized due to colour coding. This anodized layer has important functional properties for right usage and also bio-compatibility of dental implants. Physical method of anodizing and usage of anodizing mediums has a significant influence on the surface quality and itself functionality. However, basic requirement of the dental implant with satisfactory properties is quality of machined surface before anodizing. Roughness, for example, is factor affecting of time length of anodizing operation and so whole productivity. The paper is focused on monitoring of surface and area characteristics, such as roughness or surface integrity after different cutting conditions of miniature machining of dental implants and their impact on suitability for creation of satisfactory anodized layer with the correct biocompatible functional properties.

  6. The deconvolution of sputter-etching surface concentration measurements to determine impurity depth profiles

    International Nuclear Information System (INIS)

    Carter, G.; Katardjiev, I.V.; Nobes, M.J.

    1989-01-01

    The quasi-linear partial differential continuity equations that describe the evolution of the depth profiles and surface concentrations of marker atoms in kinematically equivalent systems undergoing sputtering, ion collection and atomic mixing are solved using the method of characteristics. It is shown how atomic mixing probabilities can be deduced from measurements of ion collection depth profiles with increasing ion fluence, and how this information can be used to predict surface concentration evolution. Even with this information, however, it is shown that it is not possible to deconvolute directly the surface concentration measurements to provide initial depth profiles, except when only ion collection and sputtering from the surface layer alone occur. It is demonstrated further that optimal recovery of initial concentration depth profiles could be ensured if the concentration-measuring analytical probe preferentially sampled depths near and at the maximum depth of bombardment-induced perturbations. (author)

  7. Influence of inundation of ground surface on 222Rn concentrations in shallow groundwater

    International Nuclear Information System (INIS)

    Hamada, Hiromasa; Abenney-Mickson, Stephen; Komae, Takami

    2004-01-01

    Radon-222 ( 222 Rn) is a good indicator for analyzing the speed at which surface water infiltrates the ground and reaches groundwater. Preferential flow, which is very fast, is expected to occur when the ground surface is inundated. Piston flow, which is very slow, is expected to occur when the ground surface is not inundated but is only sprinkled with water such as during a light rainfall. We hypothesized that preferential flow would reduce the 222 Rn concentration in groundwater but that piston flow would not; our study verified this hypothesis experimentally. We then measured 222 Rn concentration in groundwater for one year in low-land and upland locations. 222 Rn concentrations in groundwater decreased at the lowland site, where the ground surface was inundated by irrigation and heavy rainfall, while 222 Rn concentrations in groundwater did not decrease at the upland site, where the ground surface was not inundated. (author)

  8. Baseline ambient gaseous ammonia concentrations in the Four Corners area and eastern Oklahoma, USA.

    Science.gov (United States)

    Sather, Mark E; Mathew, Johnson; Nguyen, Nghia; Lay, John; Golod, George; Vet, Robert; Cotie, Joseph; Hertel, Terry; Aaboe, Erik; Callison, Ryan; Adam, Jacque; Keese, Danielle; Freise, Jeremy; Hathcoat, April; Sakizzie, Brenda; King, Michael; Lee, Chris; Oliva, Sylvia; San Miguel, George; Crow, Leon; Geasland, Frank

    2008-11-01

    Ambient ammonia monitoring using Ogawa passive samplers was conducted in the Four Corners area and eastern Oklahoma, USA during 2007. The resulting data will be useful in the multipollutant management of ozone, nitrogen oxides, and visibility (atmospheric regional haze) in the Four Corners area, an area with growing oil/gas production and increasing coal-based power plant construction. The passive monitoring data also add new ambient ammonia concentration information for the U.S. and will be useful to scientists involved in present and future visibility modeling exercises. Three week integrated passive ammonia samples were taken at five sites in the Four Corners area and two sites in eastern Oklahoma from December, 2006 through December, 2007 (January, 2008 for two sites). Results show significantly higher regional background ammonia concentrations in eastern Oklahoma (1.8 parts per billion (ppb) arithmetic mean) compared to the Four Corners area (0.2 ppb arithmetic mean). Annual mean ammonia concentrations for all Four Corners area sites for the 2007 study ranged from 0.2 ppb to 1.5 ppb. Peak ambient ammonia concentrations occurred in the spring and summer in both areas. The passive samplers deployed at the Stilwell, Oklahoma site compared favorably with other passive samplers and a continuous ammonia monitoring instrument.

  9. Estimating the surface area of birds: using the homing pigeon (Columba livia as a model

    Directory of Open Access Journals (Sweden)

    Cristina R. Perez

    2014-05-01

    Full Text Available Estimation of the surface area of the avian body is valuable for thermoregulation and metabolism studies as well as for assessing exposure to oil and other surface-active organic pollutants from a spill. The use of frozen carcasses for surface area estimations prevents the ability to modify the posture of the bird. The surface area of six live homing pigeons in the fully extended flight position was estimated using a noninvasive method. An equation was derived to estimate the total surface area of a pigeon based on its body weight. A pigeon's surface area in the fully extended flight position is approximately 4 times larger than the surface area of a pigeon in the perching position. The surface area of a bird is dependent on its physical position, and, therefore, the fully extended flight position exhibits the maximum area of a bird and should be considered the true surface area of a bird.

  10. NEW CONCEPTS AND TEST METHODS OF CURVE PROFILE AREA DENSITY IN SURFACE: ESTIMATION OF AREAL DENSITY ON CURVED SPATIAL SURFACE

    OpenAIRE

    Hong Shen

    2011-01-01

    The concepts of curve profile, curve intercept, curve intercept density, curve profile area density, intersection density in containing intersection (or intersection density relied on intersection reference), curve profile intersection density in surface (or curve intercept intersection density relied on intersection of containing curve), and curve profile area density in surface (AS) were defined. AS expressed the amount of curve profile area of Y phase in the unit containing surface area, S...

  11. Moving to 3D: relationships between coral planar area, surface area and volume.

    Science.gov (United States)

    House, Jenny E; Brambilla, Viviana; Bidaut, Luc M; Christie, Alec P; Pizarro, Oscar; Madin, Joshua S; Dornelas, Maria

    2018-01-01

    Coral reefs are a valuable and vulnerable marine ecosystem. The structure of coral reefs influences their health and ability to fulfill ecosystem functions and services. However, monitoring reef corals largely relies on 1D or 2D estimates of coral cover and abundance that overlook change in ecologically significant aspects of the reefs because they do not incorporate vertical or volumetric information. This study explores the relationship between 2D and 3D metrics of coral size. We show that surface area and volume scale consistently with planar area, albeit with morphotype specific conversion parameters. We use a photogrammetric approach using open-source software to estimate the ability of photogrammetry to provide measurement estimates of corals in 3D. Technological developments have made photogrammetry a valid and practical technique for studying coral reefs. We anticipate that these techniques for moving coral research from 2D into 3D will facilitate answering ecological questions by incorporating the 3rd dimension into monitoring.

  12. Hanford 200 East Area ambient NO/sub x/ concentrations, February 1968 through February 1969

    International Nuclear Information System (INIS)

    Ramsdell, J.V.

    1981-09-01

    Ambient concentrations of oxides of nitrogen (NO/sub x/) were measured in the vicinity of the 200 East Area of Hanford from late February 1968 through February 1969. This report contains an analysis of the complete set to document the ambient NO/sub x/ concentrations during time periods when the Purex Plant was emitting NO/sub x/. It is not intended to represent either current ambient NO/sub x/ concentrations or concentrations during Purex Plant operation in the future. However, it does provide a reference for use in comparison of ambient NO/sub x/ concentrations during future periods of Purex emissions with those occurring in past periods. It is also of interest to compare the annual average concentrations estimated from the measurements with the national primary ambient air quality standard for NO 2 , which is 50 parts per billion (ppb) annual arithmetic mean

  13. Perfluorinated compounds in soil, surface water, and groundwater from rural areas in eastern China.

    Science.gov (United States)

    Chen, Shu; Jiao, Xing-Chun; Gai, Nan; Li, Xiao-Jie; Wang, Xiao-Chun; Lu, Guo-Hui; Piao, Hai-Tao; Rao, Zhu; Yang, Yong-Liang

    2016-04-01

    Little research on perfluorinated compounds (PFCs) has been conducted in rural areas, although rural PFC sources are less complicated than in urban and industrial areas. To determine the levels and geographical distribution of 17 PFC compounds, samples of soil, surface water, and groundwater were collected from eight rural areas in eastern China. The total PFC concentrations (∑PFCs) in soils ranged from 0.34 to 65.8 ng/g ∑PFCs in surface waters ranged from 7.0 to 489 ng/L and ∑PFCs in groundwater ranged from 5.3 to 615 ng/L. Ratios of perfluorononanoic acid/perfluorooctanoic acid (PFNA/PFOA), perfluoro-n-butyric acid/perfluorooctanoic acid (PFBA/PFOA), and perfluoroheptanoic acid/perfluorooctanoic acid (PFHpA/PFOA) in rainwater increased due to the fluorine chemical plants in the surrounding rural and urban areas, suggesting that atmospheric precipitation may carry PFCs and their precursors from the fluorochemical industrial area to the adjacent rural areas. Copyright © 2015 Elsevier Ltd. All rights reserved.

  14. Dynamic characterisation of the specific surface area for fracture networks

    Science.gov (United States)

    Cvetkovic, V.

    2017-12-01

    One important application of chemical transport is geological disposal of high-level nuclear waste for which crystalline rock is a prime candidate for instance in Scandinavia. Interconnected heterogeneous fractures of sparsely fractured rock such as granite, act as conduits for transport of dissolved tracers. Fluid flow is known to be highly channelized in such rocks. Channels imply narrow flow paths, adjacent to essentially stagnant water in the fracture and/or the rock matrix. Tracers are transported along channelised flow paths and retained by minerals and/or stagnant water, depending on their sorption properties; this mechanism is critical for rocks to act as a barrier and ultimately provide safety for a geological repository. The sorbing tracers are retained by diffusion and sorption on mineral surfaces, whereas non-sorbing tracers can be retained only by diffusion into stagnant water of fractures. The retention and transport properties of a sparsely fractured rock will primarily depend on the specific surface area (SSA) of the fracture network which is determined by the heterogeneous structure and flow. The main challenge when characterising SSA on the field-scale is its dependence on the flow dynamics. We first define SSA as a physical quantity and clarify its importance for chemical transport. A methodology for dynamic characterisation of SSA in fracture networks is proposed that relies on three sets of data: i) Flow rate data as obtained by a flow logging procedure; ii) transmissivity data as obtained by pumping tests; iii) fracture network data as obtained from outcrop and geophysical observations. The proposed methodology utilises these data directly as well as indirectly through flow and particle tracking simulations in three-dimensional discrete fracture networks. The methodology is exemplified using specific data from the Swedish site Laxemar. The potential impact of uncertainties is of particular significance and is illustrated for radionuclide

  15. Potential effects of groundwater and surface water contamination in an urban area, Qus City, Upper Egypt

    Science.gov (United States)

    Abdalla, Fathy; Khalil, Ramadan

    2018-05-01

    The potential effects of anthropogenic activities, in particular, unsafe sewage disposal practices, on shallow groundwater in an unconfined aquifer and on surface water were evaluated within an urban area by the use of hydrogeological, hydrochemical, and bacteriological analyses. Physicochemical and bacteriological data was obtained from forty-five sampling points based on33 groundwater samples from variable depths and 12 surface water samples. The pollution sources are related to raw sewage and wastewater discharges, agricultural runoff, and wastewater from the nearby Paper Factory. Out of the 33 groundwater samples studied, 17 had significant concentrations of NO3-, Cl- and SO42-, and high bacteria counts. Most of the water samples from the wells contained high Fe, Mn, Pb, Zn, Cd, and Cr. The majority of surface water samples presented high NO3- concentrations and high bacteria counts. A scatter plot of HCO3- versus Ca indicates that 58% of the surface water samples fall within the extreme contamination zone, while the others are within the mixing zone; whereas 94% of groundwater samples showed evidence of mixing between groundwater and wastewater. The bacteriological assessment showed that all measured surface and groundwater samples contained Escherichia coli and total coliform bacteria. A risk map delineated four classes of contamination, namely, those sampling points with high (39.3%), moderate (36.3%), low (13.3%), and very low (11.1%) levels of contamination. Most of the highest pollution points were in the middle part of the urban area, which suffers from unmanaged sewage and industrial effluents. Overall, the results demonstrate that surface and groundwater in Qus City are at high risk of contamination by wastewater since the water table is shallow and there is a lack of a formal sanitation network infrastructure. The product risk map is a useful tool for prioritizing zones that require immediate mitigation and monitoring.

  16. Derived concentration guideline levels for Argonne National Laboratory's building 310 area.

    Energy Technology Data Exchange (ETDEWEB)

    Kamboj, S., Dr.; Yu, C ., Dr. (Environmental Science Division)

    2011-08-12

    The derived concentration guideline level (DCGL) is the allowable residual radionuclide concentration that can remain in soil after remediation of the site without radiological restrictions on the use of the site. It is sometimes called the single radionuclide soil guideline or the soil cleanup criteria. This report documents the methodology, scenarios, and parameters used in the analysis to support establishing radionuclide DCGLs for Argonne National Laboratory's Building 310 area.

  17. Quantifying the impact of climate change on enteric waterborne pathogen concentrations in surface water

    NARCIS (Netherlands)

    Hofstra, N.

    2011-01-01

    Climate change, among other factors, will impact waterborne pathogen concentrations in surface water worldwide, possibly increasing the risk of diseases caused by these pathogens. So far, the impacts are only determined qualitatively and thorough quantitative estimates of future pathogen

  18. Laser surface processing with controlled nitrogen-argon concentration levels for regulated surface life time

    Science.gov (United States)

    Obeidi, M. Ahmed; McCarthy, E.; Brabazon, D.

    2018-03-01

    Laser surface modification can be used to enhance the mechanical properties of a material, such as hardness, toughness, fatigue strength, and corrosion resistance. Surface nitriding is a widely used thermochemical method of surface modification, in which nitrogen is introduced into a metal or other material at an elevated temperature within a furnace. It is used on parts where there is a need for increased wear resistance, corrosion resistance, fatigue life, and hardness. Laser nitriding is a novel method of nitriding where the surface is heated locally by a laser, either in an atmosphere of nitrogen or with a jet of nitrogen delivered to the laser heated site. It combines the benefits of laser modification with those of nitriding. Recent work on high toughness tool steel samples has shown promising results due to the increased nitrogen gas impingement onto the laser heated region. Increased surface activity and nitrogen adsorption was achieved which resulted in a deeper and harder surface compared to conventional hardening methods. In this work, the effects of the laser power, pulse repetition frequency, and overlap percentage on laser surface treatment of 316 L SST steel samples with an argon-nitrogen jet will be presented. Resulting microstructure, phase type, microhardness, and wear resistance are presented.

  19. Effect of soil surface management on radiocesium concentrations in apple orchard and fruit

    International Nuclear Information System (INIS)

    Kusaba, Shinnosuke; Matsuoka, Kaori; Abe, Kazuhiro

    2016-01-01

    We investigated the effect of soil surface management on radiocesium accumulation in an apple orchard in Fukushima Prefecture over 4 years after Tokyo Electric Power Company’s Fukushima Daiichi nuclear power plant accident in mid-March 2011. Different types of soil surface management such as clean cultivation, intertillage management, intertillage with bark compost application, sod culture, and zeolite application were employed. The radiocesium concentrations in soil were higher in the surface layer (0–5 cm) than in the other layers. The radiocesium concentration in the surface layer soil with sod culture in 2014 increased non-significantly compared with that observed in 2011. The radiocesium concentration in the mid-layer soil (5–15 cm) managed with intertillage was higher than that in soil managed using other types of management. The radiocesium amount in the organic matter on the soil surface was the highest in sod culture, and was significantly lower in the management with intertillage. The radiocesium concentration in fruit decreased exponentially during the 4 years in each types of soil surface management. The decrease in radiocesium concentration showed similar trends with each type of soil surface management, even if the concentration in each soil layer varied according to the management applied. Furthermore, intertillage with bark compost application did not affect the radiocesium concentration in fruit. These results suggest that the soil surface management type that affected the radiocesium distribution in the soil or the compost application with conventional practice did not affect its concentration in fruit of apple trees for at least 4 years since the nuclear power plant accident, at a radiocesium deposition level similar to that recorded in Fukushima City. (author)

  20. Extent of Stream Burial and Relationships to Watershed Area, Topography, and Impervious Surface Area

    Directory of Open Access Journals (Sweden)

    Roy E. Weitzell

    2016-11-01

    Full Text Available Stream burial—the routing of streams through culverts, pipes, and concrete lined channels, or simply paving them over—is common during urbanization, and disproportionately affects small, headwater streams. Burial undermines the physical and chemical processes governing life in streams, with consequences for water quality and quantity that may amplify from headwaters to downstream receiving waters. Knowledge of the extent of stream burial is critical for understanding cumulative impacts to stream networks, and for future decision-making allowing for urban development while protecting ecosystem function. We predicted stream burial across the urbanizing Potomac River Basin (USA for each 10-m stream segment in the basin from medium-resolution impervious cover data and training observations obtained from high-resolution aerial photography in a GIS. Results were analyzed across a range in spatial aggregation, including counties and independent cities, small watersheds, and regular spatial grids. Stream burial was generally correlated with total impervious surface area (ISA, with areas exhibiting ISA above 30% often subject to elevated ratios of stream burial. Recurring patterns in burial predictions related to catchment area and topographic slope were also detected. We discuss these results in the context of physiographic constraints on stream location and urban development, including implications for environmental management of aquatic resources.

  1. Retrieval of AOD and PM2.5 Concentrations over Urban Areas of Shenyang City using MODIS Data

    Science.gov (United States)

    Wang, Z.

    2016-12-01

    Atmospheric aerosols play an important part in the Earth's radiation balance as well as global climate change, aerosols also have very important impact on environment as well as human and other organisms' health, PM2.5 and other small particle aerosols, can enter bronchi directly, thus causing bronchitis, cardiovascular disease, asthma and so on.Detection of AOD by satellite and remote sensing is currently one of the hotest issues , diffierent from the traditional monitoring method, this method has much more advantanges, for emample wide area coverage, fast and convenient etc. So it is possible for people to know the regional changes of AOD real time over large area. Now, detection aerosol by RS technology has reached a high level in marine and dense vegetation land areas, but result is not ideal for urban areas, the higher surface reflectance in urban areas is a bottleneck of AOD retrieval. Focus on the high surface reflectance and low accuracy of the AOD products of urban areas, this paper propose an algorithm coupled with surface reflectance to get red band surface reflectance, based on Dens Dark Vegetation algorithm and geometrical optics model theory, to distinguish urban reflectivity from other targets. Considering the appropriate aerosol model which adapt to season and other proper parameters, this paper uses 6S model to establish look-up table, thus retrieve AOD for urban as well as other high reflectance areas. This paper take Shenyang region as pilot area, then retrieve the AOD and PM2.5 concentration of Shenyang in 2015 based on MODIS data, thus get 1km resolution distribution map, and then analyzed the results in spatial, intensity and temporal. At last, real-time monitoring data from the ground monitor station is used to verify the outcome, the results have good accuracy and the the correlation reached 0.9004 when the weather is sunny. The research shows that this algorithm has relatively higher precision and certain universality. This method has

  2. Kriging analysis of uranium concentrations in Test Area C-74L, Eglin Air Force Base, Florida

    International Nuclear Information System (INIS)

    White, G.C.

    1981-05-01

    Soil samples from Test Area C-74L, Eglin Air Force Base, Florida, were analyzed for depleted uranium by instrumental epithermal neutron activation analysis. The sampling design used was a modified polar coordinate scheme. The resulting data were analyzed with a statistical procedure called kriging to obtain a contour map of concentration and a 95% confidence interval map. The majority of uranium remains in the center of the area near the target abutment

  3. Concentration, enrichment and distribution of heavy metals in surface sediments of the Tangier Bay, Morocco

    Directory of Open Access Journals (Sweden)

    María Rocío Rodríguez-Barroso

    2010-11-01

    Full Text Available The distribution, enrichment, and accumulation of heavy metals in the surface sediments of the Tangier Bay, Morocco, were investigated. Surface sediment samples from eleven locations in the Bay of Tangier were collected in 2007 and characterized for grain size, organic matter and metal content (e.g. Fe, Mn, Cr, Cu, Ni, Pb, Zn and Cd. The evaluation of the heavy metal contamination status of the bay showed minor enrichment by the enrichment factors (EF calculation, corroborated by the metal pollution index (MPI. The results of a Pearson correlation showed high positive correlations among organic carbon and most metals (0.788 < r < 0.939 and cluster analysis grouped the stations inside the harbour (stations 1, 10 and 9 and in the vicinity of the principal rivers in the bay (stations 3 and 11, which showed the highest concentrations of metal content. The main sources of contamination are domestic and industrial effluents, which arise due to the lack of sewage treatment. However, these areas could not be classified as polluted when the data were compared with sediment quality guidelines (USEPA, 1997.

  4. Geostatistical integration and uncertainty in pollutant concentration surface under preferential sampling

    Directory of Open Access Journals (Sweden)

    Laura Grisotto

    2016-04-01

    Full Text Available In this paper the focus is on environmental statistics, with the aim of estimating the concentration surface and related uncertainty of an air pollutant. We used air quality data recorded by a network of monitoring stations within a Bayesian framework to overcome difficulties in accounting for prediction uncertainty and to integrate information provided by deterministic models based on emissions meteorology and chemico-physical characteristics of the atmosphere. Several authors have proposed such integration, but all the proposed approaches rely on representativeness and completeness of existing air pollution monitoring networks. We considered the situation in which the spatial process of interest and the sampling locations are not independent. This is known in the literature as the preferential sampling problem, which if ignored in the analysis, can bias geostatistical inferences. We developed a Bayesian geostatistical model to account for preferential sampling with the main interest in statistical integration and uncertainty. We used PM10 data arising from the air quality network of the Environmental Protection Agency of Lombardy Region (Italy and numerical outputs from the deterministic model. We specified an inhomogeneous Poisson process for the sampling locations intensities and a shared spatial random component model for the dependence between the spatial location of monitors and the pollution surface. We found greater predicted standard deviation differences in areas not properly covered by the air quality network. In conclusion, in this context inferences on prediction uncertainty may be misleading when geostatistical modelling does not take into account preferential sampling.

  5. Numerical simulation of the double pits stress concentration in a curved casing inner surface

    Directory of Open Access Journals (Sweden)

    Wei Yan

    2016-12-01

    Full Text Available Sour or sweet oil fields development is common in recent years. Casing and tubing are usually subjected to pitting corrosion because of exposure to the strong corrosion species, such as CO2, H2S, and saline water. When the corrosion pits formed in the casing inner surface, localized stress concentration will occur and the casing strength will be degraded. Thus, it is essential to evaluate the degree of stress concentration factor accurately. This article performed a numerical simulation on double pits stress concentration factor in a curved inner surface using the finite element software ABAQUS. The results show that the stress concentration factor of double pits mainly depends on the ratio of two pits distance to the pit radius (L/R. It should not be only assessed by the absolute distance between the two pits. When the two pits are close and tangent, the maximum stress concentration factor will appear on the inner tangential edges. Stress concentration increased by double pits in a curved casing inner surface is more serious than that in a flat surface. A correction factor of 1.9 was recommended in the curved inner surface double pits stress concentration factor predict model.

  6. Climatologies at high resolution for the earth's land surface areas

    Science.gov (United States)

    Karger, Dirk Nikolaus; Conrad, Olaf; Böhner, Jürgen; Kawohl, Tobias; Kreft, Holger; Soria-Auza, Rodrigo Wilber; Zimmermann, Niklaus E.; Linder, H. Peter; Kessler, Michael

    2017-09-01

    High-resolution information on climatic conditions is essential to many applications in environmental and ecological sciences. Here we present the CHELSA (Climatologies at high resolution for the earth's land surface areas) data of downscaled model output temperature and precipitation estimates of the ERA-Interim climatic reanalysis to a high resolution of 30 arc sec. The temperature algorithm is based on statistical downscaling of atmospheric temperatures. The precipitation algorithm incorporates orographic predictors including wind fields, valley exposition, and boundary layer height, with a subsequent bias correction. The resulting data consist of a monthly temperature and precipitation climatology for the years 1979-2013. We compare the data derived from the CHELSA algorithm with other standard gridded products and station data from the Global Historical Climate Network. We compare the performance of the new climatologies in species distribution modelling and show that we can increase the accuracy of species range predictions. We further show that CHELSA climatological data has a similar accuracy as other products for temperature, but that its predictions of precipitation patterns are better.

  7. Surface Rupture Effects on Earthquake Moment-Area Scaling Relations

    Science.gov (United States)

    Luo, Yingdi; Ampuero, Jean-Paul; Miyakoshi, Ken; Irikura, Kojiro

    2017-09-01

    Empirical earthquake scaling relations play a central role in fundamental studies of earthquake physics and in current practice of earthquake hazard assessment, and are being refined by advances in earthquake source analysis. A scaling relation between seismic moment ( M 0) and rupture area ( A) currently in use for ground motion prediction in Japan features a transition regime of the form M 0- A 2, between the well-recognized small (self-similar) and very large (W-model) earthquake regimes, which has counter-intuitive attributes and uncertain theoretical underpinnings. Here, we investigate the mechanical origin of this transition regime via earthquake cycle simulations, analytical dislocation models and numerical crack models on strike-slip faults. We find that, even if stress drop is assumed constant, the properties of the transition regime are controlled by surface rupture effects, comprising an effective rupture elongation along-dip due to a mirror effect and systematic changes of the shape factor relating slip to stress drop. Based on this physical insight, we propose a simplified formula to account for these effects in M 0- A scaling relations for strike-slip earthquakes.

  8. In Situ Aerosol Profile Measurements and Comparisons with SAGE 3 Aerosol Extinction and Surface Area Profiles at 68 deg North

    Science.gov (United States)

    2005-01-01

    Under funding from this proposal three in situ profile measurements of stratospheric sulfate aerosol and ozone were completed from balloon-borne platforms. The measured quantities are aerosol size resolved number concentration and ozone. The one derived product is aerosol size distribution, from which aerosol moments, such as surface area, volume, and extinction can be calculated for comparison with SAGE III measurements and SAGE III derived products, such as surface area. The analysis of these profiles and comparison with SAGE III extinction measurements and SAGE III derived surface areas are provided in Yongxiao (2005), which comprised the research thesis component of Mr. Jian Yongxiao's M.S. degree in Atmospheric Science at the University of Wyoming. In addition analysis continues on using principal component analysis (PCA) to derive aerosol surface area from the 9 wavelength extinction measurements available from SAGE III. Ths paper will present PCA components to calculate surface area from SAGE III measurements and compare these derived surface areas with those available directly from in situ size distribution measurements, as well as surface areas which would be derived from PCA and Thomason's algorithm applied to the four wavelength SAGE II extinction measurements.

  9. Surface and subsurface conditions in permafrost areas - a literature review

    International Nuclear Information System (INIS)

    Vidstrand, Patrik

    2003-02-01

    This report contains a summary of some of the information within existing technical and scientific literature on permafrost. Permafrost is viewed as one of the future climate driven process domains that may exist in Scandinavia, and that may give rise to significantly different surface and subsurface conditions than the present. Except for changes in the biosphere, permafrost may impact hydraulic, mechanical, and chemical subsurface processes and conditions. Permafrost and its influences on the subsurface conditions are thus of interest for the performance and safety assessments of deep geological waste repositories. The definition of permafrost is 'ground that stays at or below 0 deg C for at least two consecutive years'. Permafrost will effect the geological subsurface to some depth. How deep the permafrost may grow is a function of the heat balance, thermal conditions at the surface and within the ground, and the geothermal heat flux from the Earth's inner parts. The main chapters of the report summaries the knowledge on permafrost evolution, occurrence and distribution, and extracts information concerning hydrology and mechanical and chemical impacts due to permafrost related conditions. The results of a literature review are always dependent on the available literature. Concerning permafrost there is some literature available from investigations in the field of long-term repositories and some from mining industries. However, reports of these investigations are few and the bulk of permafrost literature comes from the science departments concerned with surficial processes (e.g. geomorphology, hydrology, agriculture, etc) and from engineering concerns, such as foundation of constructions and pipeline design. This focus within the permafrost research inevitably yields a biased but also an abundant amount of information on localised surficial processes and a limited amount on regional and deep permafrost characteristics. Possible conclusions are that there is

  10. Surface and subsurface conditions in permafrost areas - a literature review

    Energy Technology Data Exchange (ETDEWEB)

    Vidstrand, Patrik [Bergab, Goeteborg (Sweden)

    2003-02-01

    This report contains a summary of some of the information within existing technical and scientific literature on permafrost. Permafrost is viewed as one of the future climate driven process domains that may exist in Scandinavia, and that may give rise to significantly different surface and subsurface conditions than the present. Except for changes in the biosphere, permafrost may impact hydraulic, mechanical, and chemical subsurface processes and conditions. Permafrost and its influences on the subsurface conditions are thus of interest for the performance and safety assessments of deep geological waste repositories. The definition of permafrost is 'ground that stays at or below 0 deg C for at least two consecutive years'. Permafrost will effect the geological subsurface to some depth. How deep the permafrost may grow is a function of the heat balance, thermal conditions at the surface and within the ground, and the geothermal heat flux from the Earth's inner parts. The main chapters of the report summaries the knowledge on permafrost evolution, occurrence and distribution, and extracts information concerning hydrology and mechanical and chemical impacts due to permafrost related conditions. The results of a literature review are always dependent on the available literature. Concerning permafrost there is some literature available from investigations in the field of long-term repositories and some from mining industries. However, reports of these investigations are few and the bulk of permafrost literature comes from the science departments concerned with surficial processes (e.g. geomorphology, hydrology, agriculture, etc) and from engineering concerns, such as foundation of constructions and pipeline design. This focus within the permafrost research inevitably yields a biased but also an abundant amount of information on localised surficial processes and a limited amount on regional and deep permafrost characteristics. Possible conclusions are that

  11. 30 CFR 912.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... surface coal mining operations. 912.764 Section 912.764 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE IDAHO § 912.764 Process for designating areas unsuitable for surface coal mining... coal mining and reclamation operations. ...

  12. Decreased DOC concentrations in soil water in forested areas in southern Sweden during 1987-2008.

    Science.gov (United States)

    Löfgren, Stefan; Zetterberg, Therese

    2011-04-15

    During the last two decades, there is a common trend of increasing concentrations of dissolved organic carbon (DOC) in streams and lakes in Europe, Canada and the US. Different processes have been proposed to explain this trend and recently a unifying hypothesis was presented, concluding that declining sulphur deposition and recovery from acidification, is the single most important factor for the long-term DOC concentration trends in surface waters. If this recovery hypothesis is correct, the soil water DOC concentrations should increase as well. However, long-term soil water data from Sweden and Norway indicate that there are either decreasing or indifferent DOC concentrations, while positive DOC trends have been found in the Czech Republic. Based on the soil water data from two Swedish integrated monitoring sites and geochemical modelling, it has been shown that depending on changes in pH, ionic strength and soil Al pools, the DOC solubility might be positive, negative or indifferent. In this study, we test the acidification recovery hypothesis on long-term soil water data (25 and 50cm soil depth) from 68 forest covered sites in southern Sweden, showing clear signs of recovery from acidification. The main aim was to identify potential drivers for the DOC solubility in soil solution by comparing trends in DOC concentrations with observed changes in pH, ionic strength and concentrations of Al(n+). As in earlier Swedish and Norwegian studies, the DOC concentrations in soil water decreased or showed no trend. The generally small increases in pH (median <0.3 pH units) during the investigation period seem to be counterbalanced by the reduced ionic strength and diminished Al concentrations, increasing the organic matter coagulation. Hence, opposite to the conclusion for surface waters, the solubility of organic matter seems to decrease in uphill soils, as a result of the acidification recovery. Copyright © 2011 Elsevier B.V. All rights reserved.

  13. 30 CFR 941.761 - Areas designated unsuitable for surface coal mining by act of Congress.

    Science.gov (United States)

    2010-07-01

    ... WITHIN EACH STATE SOUTH DAKOTA § 941.761 Areas designated unsuitable for surface coal mining by act of Congress. Part 761 of this chapter, Areas Designated by Act of Congress, shall apply to surface coal mining... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Areas designated unsuitable for surface coal...

  14. 30 CFR 937.761 - Areas designated unsuitable for surface coal mining by Act of Congress.

    Science.gov (United States)

    2010-07-01

    ... WITHIN EACH STATE OREGON § 937.761 Areas designated unsuitable for surface coal mining by Act of Congress. Part 761 of this chapter, Areas Designated by Act of Congress, shall apply to surface coal mining and... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Areas designated unsuitable for surface coal...

  15. 30 CFR 905.761 - Areas designated unsuitable for surface coal mining by act of Congress.

    Science.gov (United States)

    2010-07-01

    ... WITHIN EACH STATE CALIFORNIA § 905.761 Areas designated unsuitable for surface coal mining by act of Congress. Part 761 of this chapter, Areas Designated by Act of Congress, shall apply to surface coal mining... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Areas designated unsuitable for surface coal...

  16. 30 CFR 910.761 - Areas designated unsuitable for surface coal mining by Act of Congress.

    Science.gov (United States)

    2010-07-01

    ... WITHIN EACH STATE GEORGIA § 910.761 Areas designated unsuitable for surface coal mining by Act of Congress. Part 761 of this chapter, Areas Designated by Act of Congress, shall apply to surface coal mining... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Areas designated unsuitable for surface coal...

  17. 30 CFR 903.761 - Areas designated unsuitable for surface coal mining by act of Congress.

    Science.gov (United States)

    2010-07-01

    ... WITHIN EACH STATE ARIZONA § 903.761 Areas designated unsuitable for surface coal mining by act of Congress. Part 761 of this chapter, Areas Designated by Act of Congress, applies to surface coal mining... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Areas designated unsuitable for surface coal...

  18. 30 CFR 939.761 - Areas designated unsuitable for surface coal mining by Act of Congress.

    Science.gov (United States)

    2010-07-01

    ... WITHIN EACH STATE RHODE ISLAND § 939.761 Areas designated unsuitable for surface coal mining by Act of Congress. Part 761 of this chapter, Areas Designated by Act of Congress, shall apply to surface coal mining... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Areas designated unsuitable for surface coal...

  19. 30 CFR 922.761 - Areas designated unsuitable for surface coal mining by act of Congress.

    Science.gov (United States)

    2010-07-01

    ... WITHIN EACH STATE MICHIGAN § 922.761 Areas designated unsuitable for surface coal mining by act of Congress. Part 761 of this chapter, Areas Designated by Act of Congress, shall apply to surface coal mining... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Areas designated unsuitable for surface coal...

  20. 30 CFR 921.761 - Areas designated unsuitable for surface coal mining by Act of Congress.

    Science.gov (United States)

    2010-07-01

    ... WITHIN EACH STATE MASSACHUSETTS § 921.761 Areas designated unsuitable for surface coal mining by Act of Congress. Part 761 of this chapter, Areas Designated by Act of Congress, shall apply to surface coal mining... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Areas designated unsuitable for surface coal...

  1. 30 CFR 912.761 - Areas designated unsuitable for surface coal mining by act of Congress.

    Science.gov (United States)

    2010-07-01

    ... WITHIN EACH STATE IDAHO § 912.761 Areas designated unsuitable for surface coal mining by act of Congress. Part 761 of this chapter, Areas Designated by Act of Congress, shall apply to surface coal mining and... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Areas designated unsuitable for surface coal...

  2. 30 CFR 947.761 - Areas designated unsuitable for surface coal mining by act of Congress.

    Science.gov (United States)

    2010-07-01

    ... WITHIN EACH STATE WASHINGTON § 947.761 Areas designated unsuitable for surface coal mining by act of Congress. Part 761 of this chapter, Areas Designated by Act of Congress, shall apply to surface coal mining... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Areas designated unsuitable for surface coal...

  3. 30 CFR 942.761 - Areas designated unsuitable for surface coal mining by act of Congress.

    Science.gov (United States)

    2010-07-01

    ... WITHIN EACH STATE TENNESSEE § 942.761 Areas designated unsuitable for surface coal mining by act of Congress. Part 761 of this chapter, Areas Designated by Act of Congress, shall apply to surface coal mining... 30 Mineral Resources 3 2010-07-01 2010-07-01 false Areas designated unsuitable for surface coal...

  4. 30 CFR 903.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 903.762 Section 903.762 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE ARIZONA § 903.762 Criteria for designating areas as unsuitable for surface coal mining operations. Part 762 of this chapter, Criteria for Designating Areas Unsuitable for Surface Coal Mining...

  5. 30 CFR 922.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 922.762 Section 922.762 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE MICHIGAN § 922.762 Criteria for designating areas as unsuitable for surface coal mining operations. Part 762 of this chapter, Criteria for Designating Areas Unsuitable for Surface Coal Mining...

  6. 30 CFR 937.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 937.762 Section 937.762 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE OREGON § 937.762 Criteria for designating areas as unsuitable for surface coal mining operations. Part 762 of this chapter, Criteria for Designating Areas Unsuitable for Surface Coal Mining...

  7. 30 CFR 912.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 912.762 Section 912.762 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE IDAHO § 912.762 Criteria for designating areas as unsuitable for surface coal mining operations. Part 762 of this chapter, Criteria for Designating Areas Unsuitable for Surface Coal Mining...

  8. 30 CFR 910.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 910.762 Section 910.762 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE GEORGIA § 910.762 Criteria for designating areas as unsuitable for surface coal mining operations. Part 762 of this chapter, Criteria for Designating Areas Unsuitable for Surface Coal Mining...

  9. Dissolved Platinum Concentrations in Coastal Seawater: Boso to Sanriku Areas, Japan.

    Science.gov (United States)

    Mashio, Asami Suzuki; Obata, Hajime; Gamo, Toshitaka

    2017-08-01

    Platinum, one of the rarest elements in the earth's crust, is now widely used in a range of products, such as catalytic converters in automobiles and anticancer drugs. Increasing use and dispersal of platinum has the potential to affect aquatic environments. Platinum concentrations in open ocean seawater have been found to be very low (approximately 0.2 pmol/L); however, Pt distributions and biogeochemical cycles in coastal areas are unknown. In this study, we investigated Pt concentrations in coastal waters between the Boso and Sanriku areas, Japan, after the 2011 tsunami. We determined sub-picomolar levels of dissolved Pt using isotope-dilution Inductively coupled plasma mass spectrometry after column preconcentration with an anion exchange resin. Dissolved Pt concentrations were found to be in the range 0.20-1.5 pmol/L, with the highest concentration in bottom water of the Boso coastal area, and at stations close to Tokyo Bay. Assuming thermodynamical equilibrium, Pt was determined to be present in the form PtCl 5 (OH) 2- , even in low-oxygen coastal waters. Vertical profiles indicated Pt levels increased toward seafloors near coastal stations and were similar to those of the open ocean at trench stations. High concentrations of dissolved Pt are thought to be derived from coastal sediments.

  10. Radionuclide concentrations in honey bees from Area G at TA-54 during 1997. Progress report

    Energy Technology Data Exchange (ETDEWEB)

    Haarmann, T.K.; Fresquez, P.R.

    1998-07-01

    Honey bees were collected from two colonies located at Los Alamos National Laboratory`s Area G, Technical Area 54, and from one control (background) colony located near Jamez Springs, NM. Samples were analyzed for the following: cesium ({sup 137}Cs), americium ({sup 241}Am), plutonium ({sup 238}Pu and {sup 239,240}Pu), tritium ({sup 3}H), total uranium, and gross gamma activity. Area G sample results from both colonies were higher than the upper (95%) level background concentration for {sup 238}Pu and {sup 3}H.

  11. Do Leaders' Experience and Concentration Area Influence School Performance?

    Science.gov (United States)

    Sturgis, Kimberlin; Shiflett, Brittanee; Tanner, Tyrone

    2017-01-01

    The purpose of this study was to examine the educational background of leaders in small, high poverty, high minority schools in an effort to determine if the leader's concentration area and background were related to the academic success of the students. Through a causal comparative design, a modified version of the Interstate School Leaders…

  12. Surface modification of platelet concentrate bags to reduce biofilm formation and transfusion sepsis.

    Science.gov (United States)

    Wilson-Nieuwenhuis, Joels S T; Dempsey-Hibbert, Nina; Liauw, Christopher M; Whitehead, Kathryn A

    2017-12-01

    Bacterial contamination of blood products poses a major risk in transfusion medicine, including transfusions involving platelet products. Although testing systems are in place for routine screening of platelet units, the formation of bacterial biofilms in such units may decrease the likelihood that bacteria will be detected. This work determined the surface properties of p-PVC platelet concentrate bags and investigated how these characteristics influenced biofilm formation. Serratia marcescens and Staphylococcus epidermidis, two species commonly implicated in platelet contamination, were used to study biofilm growth. The platelet concentrate bags were physically flattened to determine if reducing the surface roughness altered biofilm formation. The results demonstrated that the flattening process of the platelet bags affected the chemistry of the surface and reduced the surface hydrophobicity. Flattening of the surfaces resulted in a reduction in biofilm formation for both species after 5 days, with S. marcescens demonstrating a greater reduction. However, there was no significant difference between the smooth and flat surfaces following 7 days' incubation for S. marcescens and no significant differences between any of the surfaces following 7 days' incubation for S. epidermidis. The results suggest that flattening the p-PVC surfaces may limit potential biofilm formation for the current duration of platelet storage time of 5 days. It is hoped that this work will enhance the understanding of how surface properties influence the development of microbial biofilms in platelet concentrate bags in order to devise a solution to discourage biofilm formation. Copyright © 2017 Elsevier B.V. All rights reserved.

  13. Anthropogenic Pollution in Izmit Bay: Heavy Metal Concentrations in Surface Sediments

    OpenAIRE

    YAŞAR, D.

    2014-01-01

    The extent of marine pollution in İzmit Bay is studied using geochemical data in surface sediments. The concentrations of 41 elements in 24 samples establish that surface sediments in inner and central İzmit Bay display significant enrichments in Ag, As, Cd, Cr, Co, Cu, Hg, Mo, P, Pb, Sb, Ti, V, and Zn associated with high concentrations of total organic carbon and sulphur. Geo-accumulation indices indicate that the inner and central İzmit Bay surface sediments are moderately to very...

  14. Effect of concentration and temperature on surface tension of sodium hyaluronate saline solutions.

    Science.gov (United States)

    Ribeiro, Walkiria; Mata, José Luis; Saramago, Benilde

    2007-06-19

    The effect of concentration and temperature on the surface tension of sodium hyaluronate (NaHA) saline solutions was investigated using the technique of the shape of pendant drops. The decay rate of the surface tension with the increase of NaHA concentration was well-described by the empirical Hua-Rosen equation. Adsorption at the air-liquid interface was estimated using the Gibbs equation. The temperature dependence of a dilute solution and a semidilute entangled solution was numerically fitted with a second-order polynomial equation. The surface behavior of the NaHA saline solutions was interpreted in terms of their known viscoelastic properties.

  15. Measurement of radon exhalation rate and soil gas radon concentration in areas of southern Punjab (Pakistan)

    International Nuclear Information System (INIS)

    Mujahid, S. A.; Hussain, S.; Ramzan, M.

    2010-01-01

    Plastic track detectors were used to measure the radon concentration and exhalation rate from the soil samples. The samples were collected from areas of southern Punjab (Pakistan). In a laboratory experiment, passive alpha dosemeters were installed inside cylindrical bottles containing the soil samples. The radon concentrations and the radon exhalation rate were found in the ranges of 34±7 to 260±42 Bq m -3 and 38±8 to 288±46 mBq m -2 h -1 , respectively. The on-site measurements of radon in the soil gas were also carried out in these areas using a scintillation alpha counter. The concentration of radon in the soil gas was found in the range of 423±82-3565±438 Bq m -3 . (authors)

  16. Mercury concentrations in bats (Chiroptera) from a gold mining area in the Peruvian Amazon.

    Science.gov (United States)

    Moreno-Brush, Mónica; Portillo, Alejandro; Brändel, Stefan Dominik; Storch, Ilse; Tschapka, Marco; Biester, Harald

    2018-01-01

    In the southeastern Peruvian Amazon, artisanal and small-scale gold mining (ASGM) is estimated to have released up to 300 tonnes of mercury (Hg) to the environment between 1995 and 2007 alone, and is claimed to be responsible for Hg concentrations above international thresholds for aquatic wildlife species. Here, we examined whether Hg concentrations in bat populations are potentially related to regional ASGM-Hg releases. We determined Hg concentrations in the fur of bats collected at three different distances from the major ASGM areas in Peru. Our findings from 204 individuals of 32 species indicate that Hg concentrations in bat fur mainly resulted from differences in feeding habits, because Hg concentrations were significantly higher in omnivorous bats than in frugivorous bats. At least in two species, populations living in ASGM-affected sites harbored higher Hg concentrations than did populations in unaffected sites. Because Hg concentrations reflect Hg dietary exposure, Hg emissions from amalgam roasting sites appear to deposit locally and enter the terrestrial food web. Although our study demonstrates that ASGM activities (and Hg point sources) increase Hg exposure in wildlife, the overall Hg concentrations reported here are relatively low. The measured Hg concentrations were below the toxicity threshold at which adverse neurological effects have been reported in rodents and mink (>10 µg g -1 ), and were in the range of Hg concentrations in the fur of bats from nonpoint source affected sites in other latitudes. This study emphasizes the importance of considering feeding habits when evaluating Hg concentrations in bats and other vertebrates.

  17. Assessing metaldehyde concentrations in surface water catchments and implications for drinking water abstraction

    Science.gov (United States)

    Asfaw, Alemayehu; Shucksmith, James; Smith, Andrea; Cherry, Katherine

    2015-04-01

    Metaldehyde is an active ingredient in agricultural pesticides such as slug pellets, which are heavily applied to UK farmland during the autumn application season. There is current concern that existing drinking water treatment processes may be inadequate in reducing potentially high levels of metaldehyde in surface waters to below the UK drinking water quality regulation limit of 0.1 µg/l. In addition, current water quality monitoring methods can miss short term fluctuations in metaldehyde concentration caused by rainfall driven runoff, hampering prediction of the potential risk of exposure. Datasets describing levels, fate and transport of metaldehyde in river catchments are currently very scarce. This work presents results from an ongoing study to quantify the presence of metaldehyde in surface waters within a UK catchment used for drinking water abstraction. High resolution water quality data from auto-samplers installed in rivers are coupled with radar rainfall, catchment characteristics and land use data to i) understand which hydro-meteorological characteristics of the catchment trigger the peak migration of metaldehyde to surface waters; ii) assess the relationship between measured metaldehyde levels and catchment characteristics such as land use, topographic index, proximity to water bodies and runoff generation area; iii) describe the current risks to drinking water supply and discuss mitigation options based on modelling and real-time control of water abstraction. Identifying the correlation between catchment attributes and metaldehyde generation will help in the development of effective catchment management strategies, which can help to significantly reduce the amount of metaldehyde finding its way into river water. Furthermore, the effectiveness of current water quality monitoring strategy in accurately quantifying the generation of metaldehyde from the catchment and its ability to benefit the development of effective catchment management practices

  18. Surface Sediment Analysis on Petroleum Hydrocarbon and Total Organic Carbon from Coastal Area of Papar to Tuaran, Sabah

    International Nuclear Information System (INIS)

    Siti Aishah Mohd Ali; Payus, C.; Masni Mohd Ali

    2015-01-01

    Total petroleum hydrocarbons (TPH) and total organic carbon (TOC) were investigated in surface sediments along coastal area of Papar to Tuaran, Sabah. Surface sediment samples were collected in 24 different stations in each area by using Ponar grab sampler. Samples were extracted for TPH using standard method sediment/ sludge APHA 5520E and analyzed using UV/VIS spectrophotometer while for TOC method analysis using United Nations Environment Programme (UNEP)/ MAP Athens (2006). The range of TPH concentrations in surface sediments were recorded at 0.24 - 20.65 mg/ kg dw Miri crude oil equivalents, meanwhile the TOC percentage ranged from 0.03 - 4.02 %. In the mean time, the statistical analysis by Pearson correlation showed a positive correlation with coefficient, r = 0.790 which showing the TPH concentrations significantly have influence on the TOC accumulations in the surface sediment. (author)

  19. Dependence of Ideality Factor in Lateral PNP Transistors on Surface Carrier Concentration

    Science.gov (United States)

    Li, Xingji; Yang, Jianqun; Barnaby, Hugh J.; Galloway, Kenneth F.; Schrimpf, Ronald D.; Fleetwood, Daniel M.; Liu, Chaoming

    2017-06-01

    The influence of surface carrier concentration on the ideality factor of excess base current (ΔIB) in gated lateral PNP (GLPNP) bipolar junction transistors (BJTs) induced by 1-MeV electrons is investigated. ΔIB in LPNP BJTs is impacted by the surface carrier density and radiation-induced interface traps. In GLPNP BJTs, the surface carrier concentration can be controlled by the voltage applied to a gate over the base region. The ideality factor changes after irradiation, and its dependence on emitter-base voltage (VEB) is a function of gate voltage. For the irradiated devices, as the gate voltage decreases from +20 to -5 V, the ideality factor for excess base current changes from a single slope to two-slope behavior. The majority carrier concentration at the surface of the base, controlled by the gate voltage, impacts the excess base current and its ideality factor.

  20. Concentrations of the UV filter ethylhexyl methoxycinnamate in the aquatic compartment: a comparison of modelled concentrations for Swiss surface waters with empirical monitoring data.

    Science.gov (United States)

    Straub, Jürg Oliver

    2002-05-10

    UV filters in sunscreens and cosmetics protect the skin from damage through UV radiation. Many tonnes per year of UV filters are being used in Europe and will be present, at least seasonally, in detectable concentrations in surface waters similar to common pharmaceutically active substances. Predicted environmental concentrations (PECs) of ethylhexyl methoxycinnamate (EHMC; CAS 5466-77-3) were extrapolated for Switzerland, taking into consideration substance-specific environmental fate data and marketing estimates, by crude worst-case reckoning and by applying two environmental models (Mackay Level III; USES 3.0), both configured for Swiss hydrological and area data. By worst-case reckoning the summer PEC is 70.8-81.3 ng/l while for the remaining 8 months of the year the PEC is 13.1-15.1 ng/l. The Level III model results in concentrations of 2.4 ng/l during the summer and 0.44 ng/l during the rest of the year, while the USES 3.0 model gives an average PEC for the whole year of 7.6 ng/l. Pooling summer monitoring data (90 single analyses) from the River Rhine below Basel in the year 1997 (Water Protection Board of Basel) and from Lakes Zurich and Hüttner in 1998 (Poiger et al., in preparation) allowed a derivation of a probabilistic median concentration of 4.6 ng/l, a 95th-percentile concentration of 18.6 ng/l and a 99th-percentile concentration of 33.5 ng/l. The 6-fold range from the median value to the maximum calls for caution in interpreting published monitoring concentrations. Comparison of modelled PECs with realistic median concentrations shows that crude reckoning overestimates actual concentrations by a factor of about 10, probably through insufficient consideration of (further) degradation of EHMC in sewage works, surface waters, sediments or river banks. Both computer models, in contrast, are within the same order of magnitude as the actual summer concentrations. Based on the available data, both these environmental fate and distribution models give

  1. The effects of large-scale atmospheric flows on berylium-7 activity concentration in surface air.

    Science.gov (United States)

    Arkian, Foroozan; Meshkatee, Amir-Hussain; Bidokhti, Ali Akbar

    2010-09-01

    Understanding the exchange mechanism between stratosphere and troposphere is one of the most important concerns of meteorologists and climatologists for decades. Different methods are being adopted to study those mechanisms. One of those methods is the study upon the tropospheric concentration of conserve or passive entities with stratospheric origin. One of those passive entities is (7)Be that is produced upon the incident of cosmic rays on light atmospheric nuclei in the stratosphere. The availability of 5 years observations of (7)Be concentration in surface air in Tehran (35 degrees 41(') N, 51 degrees 18(') E) encouraged us to investigate meteorological condition effect on the surface concentration of (7)Be. Also, the intention was to see if there was any intrusion of stratospheric air into the troposphere at the time of high surface concentration of (7)Be and scavenging mechanism when the concentration was low. During the course of this study, it has been found that (7)Be concentration is high whenever there is a jet stream over Tehran. Since high-level jet streams normally form near tropopause folding, it could be interpreted as a sign of the intrusion of stratospheric air into the troposphere. It was also found that high concentration of (7)Be in the Tehran surface air in summer is associated with an upper ridge on 500 hPa surface located east of the city, and low concentration in winter is associated with an upper trough. The latter normally is seen whenever there is precipitation that suggests wet scavenging could be the reason for that observed low concentration.

  2. Effects of different sulfuric acid etching concentrations on PEEK surface bonding to resin composite.

    Science.gov (United States)

    Chaijareenont, Pisaisit; Prakhamsai, Sasiprapha; Silthampitag, Patcharawan; Takahashi, Hidekazu; Arksornnukit, Mansuang

    2018-01-26

    This study evaluated the effects of surface pretreatment with different concentrations of sulfuric acid etching on surface properties and bonding between Polyetheretherketone (PEEK) and a resin composite. Six groups of surface pretreatment (no pretreatment, etched with 70, 80, 85, 90, and 98% sulfuric acid for 60 s) were treated on PEEK. Surface roughness, scanning electron microscopy (SEM) and atomic force microscopy (AFM) analyses were examined. Shear bond strength (SBS) and cross-sectional observations of the interfaces were performed. One-way ANOVA analysis revealed differences in surface roughness and SBS between groups. The 90 and 98% sulfuric acid etching significantly achieved the highest SBS (psulfuric acid etching were suggested to be the optimal concentration to improve adhesion between PEEK and the resin composite.

  3. Characteristics of surface O{sub 3} over Qinghai Lake area in Northeast Tibetan Plateau, China

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Zhenxing, E-mail: zxshen@mail.xjtu.edu.cn [Department of Environmental Sciences and Engineering, Xi' an Jiaotong University, Xi' an (China); Key Lab of Aerosol, SKLLQG, Institute of Earth Environment, Chinese Academy of Sciences, Xi' an (China); Cao, Junji [Key Lab of Aerosol, SKLLQG, Institute of Earth Environment, Chinese Academy of Sciences, Xi' an (China); Zhang, Leiming [Air Quality Research Division, Environment Canada, Toronto (Canada); Zhao, Zhuzi [Key Lab of Aerosol, SKLLQG, Institute of Earth Environment, Chinese Academy of Sciences, Xi' an (China); Dong, Jungang [School of Architecture, Xi' an University of Architecture and Technology, Xi' an 710055 (China); Wang, Linqing [Department of Environmental Sciences and Engineering, Xi' an Jiaotong University, Xi' an (China); Wang, Qiyuan; Li, Guohui; Liu, Suixin [Key Lab of Aerosol, SKLLQG, Institute of Earth Environment, Chinese Academy of Sciences, Xi' an (China); Zhang, Qian [Department of Environmental Sciences and Engineering, Xi' an Jiaotong University, Xi' an (China)

    2014-12-01

    Surface O{sub 3} was monitored continuously during Aug. 12, 2010 to Jul. 21, 2011 at a high elevation site (3200 m above sea level) in Qinghai Lake area (36°58′37″N, 99°53′56″E) in Northeast Tibetan Plateau, China. Daily average O{sub 3} ranged from 21.8 ppbv to 65.3 ppbv with an annual average of 41.0 ppbv. Seasonal average of O{sub 3} followed a decreasing order of summer > autumn > spring > winter. Diurnal variations of O{sub 3} showed low concentrations during daytime and high concentrations during late night and early morning. An intensive campaign was also conducted during Aug. 13–31, 2010 to investigate correlations between meteorological or chemical conditions and O{sub 3}. It was found that O{sub 3} was poorly correlated with solar radiation due to the insufficient NO{sub x} in the ambient air, thus limiting O{sub 3} formation under strong solar radiation. In contrast, high O{sub 3} levels always coincided with strong winds, suggesting that stratospheric O{sub 3} and long range transport might be the main sources of O{sub 3} in this rural area. Back-trajectory analysis supported this hypothesis and further indicated the transport of air masses from northwest, northeast and southeast directions. - Highlights: • Surface O{sub 3} was measured in Qinghai Lake area in Northeast Tibetan Plateau, China. • The O{sub 3} chemical formation was under a strong NOx-limited in Qinghai Lake areas. • Stratospheric O{sub 3} and transport might be the main sources of O{sub 3} in this area.

  4. Characteristics of surface O3 over Qinghai Lake area in Northeast Tibetan Plateau, China

    International Nuclear Information System (INIS)

    Shen, Zhenxing; Cao, Junji; Zhang, Leiming; Zhao, Zhuzi; Dong, Jungang; Wang, Linqing; Wang, Qiyuan; Li, Guohui; Liu, Suixin; Zhang, Qian

    2014-01-01

    Surface O 3 was monitored continuously during Aug. 12, 2010 to Jul. 21, 2011 at a high elevation site (3200 m above sea level) in Qinghai Lake area (36°58′37″N, 99°53′56″E) in Northeast Tibetan Plateau, China. Daily average O 3 ranged from 21.8 ppbv to 65.3 ppbv with an annual average of 41.0 ppbv. Seasonal average of O 3 followed a decreasing order of summer > autumn > spring > winter. Diurnal variations of O 3 showed low concentrations during daytime and high concentrations during late night and early morning. An intensive campaign was also conducted during Aug. 13–31, 2010 to investigate correlations between meteorological or chemical conditions and O 3 . It was found that O 3 was poorly correlated with solar radiation due to the insufficient NO x in the ambient air, thus limiting O 3 formation under strong solar radiation. In contrast, high O 3 levels always coincided with strong winds, suggesting that stratospheric O 3 and long range transport might be the main sources of O 3 in this rural area. Back-trajectory analysis supported this hypothesis and further indicated the transport of air masses from northwest, northeast and southeast directions. - Highlights: • Surface O 3 was measured in Qinghai Lake area in Northeast Tibetan Plateau, China. • The O 3 chemical formation was under a strong NOx-limited in Qinghai Lake areas. • Stratospheric O 3 and transport might be the main sources of O 3 in this area

  5. Forecasts of methane concentration at the outlet of the longwall with caving area - case study

    Science.gov (United States)

    Badura, Henryk; Bańka, Piotr; Musioł, Dariusz; Wesołowski, Marek

    2017-11-01

    This paper presents the characteristics of methane hazard and prevention undertaken in the N-6 longwall of seam 330/2 in “Krupiński" coal mine. On the basis of methane concentration measurements conducted with the use of telemetric system, time series of the average and maximum methane concentration at the outlet of the longwall area were generated. It was ascertained that they exhibit a strong autocorrelation. Based on a series of the average methane concentration, a time series of ventilation methane content was created and a total methane content was calculated with the use of methane flow rate measurements in the demethanization system. It was ascertained that dependence between methane concentration and output on the examined day and on the previous day is weak and also that the dependence between methane concentration and air flow rate is very weak. Dependencies between ventilation methane content, total methane content and demethanization efficiency were also investigated. Based on forecasting models [1] developed earlier by H. Badura, forecasts have been made to predict the average and maximum methane concentrations. The measured values f methane concentration show a high level of accordance with forecasted ones.

  6. Radionuclide concentrations in/on vegetation at radioactive-waste disposal Area G during the 1995 growing season. Progress report

    International Nuclear Information System (INIS)

    Fresquez, P.R.; Vold, E.L.; Naranjo, L. Jr.

    1996-01-01

    Overstory (pinon pine) and understory (grass and forb) vegetation were collected within and around selected points at Area G--a low- level radioactive solid-waste disposal facility at Los Alamos National Laboratory--for the analysis of tritium ( 3 H), strontium ( 90 Sr), plutonium ( 238 Pu and 239 Pu), cesium ( 137 Cs), and total uranium. Also, heavy metals (Ag, As, Ba, Be, Cd, Cr, Hg, Ni, Pb, Sb, Se, and Tl) in/on vegetation were determined. In general, most (unwashed) vegetation collected within and around Area G contained 3 H, uranium, 238 Pu, and 239 Pu in higher concentrations than vegetation collected from background areas. Tritium, in particular, was detected as high as 7300 pCi mL -1 in understory vegetation collected from the west side of the transuranic (TRU) pads. The south and west ends of the tritium shaft field also contained elevated levels of 3 H in overstory, and especially in understory vegetation, as compared to background; this suggests that 3 H may be migrating from this waste repository through surface and subsurface pathways. Also, understory vegetation collected north of the TRU pads (adjacent to the fence line of Area G) contained the highest values of 238 Pu and 239 Pu as compared to background, and may be a result of surface holding, storage, and/or disposal activities

  7. Seasonal trends in environmental tritium concentrations in a small forest adjacent to a radioactive waste storage area

    International Nuclear Information System (INIS)

    Amano, H.; Garten, C.T. Jr.

    1992-01-01

    Tritium (HTO) concentrations were studied for an entire year in a floodplain forest adjacent to a low-level radioactive solid waste storage areas (SWSA No. 5) at Oak Ridge National Laboratory (ORNL) near Oak Ridge, Tennessee, USA. Tritium in soil was the principal source of HTO to the deciduous forest. Evaporation from the surface soil along with transpiration from tree leaves both contributed to HTO in the forest atmosphere. During the growing season, transpiration was the principal contributor of HTO to the forest atmosphere, while during he dormant season, the main source of atmospheric HTO was evaporation from the surface soil. This paper discovers seasonal changes and the characteristics of vegetation which will influence the relative importance of evaporation and transpiration as sources of atmospheric HTO near the ground in temperate deciduous forests

  8. GC/MS Analysis of Pesticides in the Ferrara Area (Italy) Surface Water: A Chemometric Study

    International Nuclear Information System (INIS)

    Pasti, L.; Dondi, F.; Nava, E.; Morelli, M.; Bignami, S.

    2007-01-01

    The development of a network to monitor surface waters is a critical element in the assessment, restoration and protection of water quality. In this study, concentrations of 42 pesticides - determined by GC-MS on samples from 11 points along the Ferrara area rivers - have been analyzed by chemometric tools. The data were collected over a three-year period (2002-2004). Principal component analysis of the detected pesticides was carried out in order to define the best spatial locations for the sampling points. The results obtained have been interpreted in view of agricultural land use. Time series data regarding pesticide contents in surface waters has been analyzed using the Autocorrelation function. This chemometric tool allows for seasonal trends and makes it possible to optimize sampling frequency in order to detect the effective maximum pesticide content

  9. Outdoor (222)Rn-concentrations in Germany - part 2 - former mining areas.

    Science.gov (United States)

    Kümmel, M; Dushe, C; Müller, S; Gehrcke, K

    2014-06-01

    In the German Federal States of Saxony, Saxony-Anhalt and Thuringia, centuries of mining and milling activities resulted in numerous residues with increased levels of natural radioactivity such as waste rock dumps and tailings ponds. These may have altered potential radiation exposures of the population significantly. Especially waste rock dumps from old mining activities as well as 20th century uranium mining may, due to their radon ((222)Rn) exhalation capacity, lead to significant radiation exposures. They often lie close to or within residential areas. In order to study the impact on the natural radon level, the Federal Office for Radiation Protection (BfS) has run networks of radon measurement points in 16 former mining areas, together with 2 networks in regions not influenced by mining for comparison purposes. Representative overviews of the long-term outdoor radon concentrations could be established including estimates of regional background concentrations. Former mining and milling activities did not result in large-area impacts on the outdoor radon level. However, significantly increased radon concentrations were observed in close vicinity of shafts and large waste rock dumps. They are partly located in residential areas and need to be considered under radiation protection aspects. Examples are given that illustrate the consequences of the Wismut Ltd. Company's reclamation activities on the radon situation. Copyright © 2014 Elsevier Ltd. All rights reserved.

  10. Blood lead concentrations in Alaskan tundra swans: linking breeding and wintering areas with satellite telemetry

    Science.gov (United States)

    Ely, Craig R.; Franson, Christian

    2014-01-01

    Tundra swans (Cygnus columbianus) like many waterfowl species are susceptible to lead (Pb) poisoning, and Pb-induced mortality has been reported from many areas of their wintering range. Little is known however about Pb levels throughout the annual cycle of tundra swans, especially during summer when birds are on remote northern breeding areas where they are less likely to be exposed to anthropogenic sources of Pb. Our objective was to document summer Pb levels in tundra swans throughout their breeding range in Alaska to determine if there were population-specific differences in blood Pb concentrations that might pose a threat to swans and to humans that may consume them. We measured blood Pb concentrations in tundra swans at five locations in Alaska, representing birds that winter in both the Pacific Flyway and Atlantic Flyway. We also marked swans at each location with satellite transmitters and coded neck bands, to identify staging and wintering sites and determine if winter site use correlated with summer Pb concentrations. Blood Pb levels were generally low ( < 0.2 μg/ml) in swans across all breeding areas. Pb levels were lower in cygnets than adults, suggesting that swans were likely exposed to Pb on wintering areas or on return migration to Alaska, rather than on the summer breeding grounds. Blood Pb levels varied significantly across the five breeding areas, with highest concentrations in birds on the North Slope of Alaska (wintering in the Atlantic Flyway), and lowest in birds from the lower Alaska Peninsula that rarely migrate south for winter.

  11. Effect of impervious surface area and vegetation changes on mean ...

    African Journals Online (AJOL)

    adeniyi adeyemi

    sprawl and this has contributed to increase in surface temperature. Keyword: Thematic indices, surface temperature, Landsat, vegetation, ISA, Tshwane Metropolis. 1. Introduction. Globally, rapid increase in population in major cities has led to urban sprawl at an unprecedented rate which is, according to the analysis and ...

  12. Reanalysis of and attribution to near-surface ozone concentrations in Sweden during 1990-2013

    Science.gov (United States)

    Andersson, Camilla; Alpfjord, Heléne; Robertson, Lennart; Karlsson, Per Erik; Engardt, Magnuz

    2017-11-01

    We have constructed two data sets of hourly resolution reanalyzed near-surface ozone (O3) concentrations for the period 1990-2013 for Sweden. Long-term simulations from a chemistry-transport model (CTM) covering Europe were combined with hourly ozone concentration observations at Swedish and Norwegian background measurement sites using retrospective variational data analysis. The reanalysis data sets show improved performance over the original CTM when compared to independent observations. In one of the reanalyses, we included all available hourly near-surface O3 observations, whilst in the other we carefully selected time-consistent observations. Based on the second reanalysis we investigated statistical aspects of the distribution of the near-surface O3 concentrations, focusing on the linear trend over the 24-year period. We show that high near-surface O3 concentrations are decreasing and low O3 concentrations are increasing, which is reflected in observed improvement of many health and vegetation indices (apart from those with a low threshold). Using the CTM we also conducted sensitivity simulations to quantify the causes of the observed change, focusing on three factors: change in hemispheric background concentrations, meteorology and anthropogenic emissions. The rising low concentrations of near-surface O3 in Sweden are caused by a combination of all three factors, whilst the decrease in the highest O3 concentrations is caused by European O3 precursor emissions reductions. While studying the impact of anthropogenic emissions changes, we identified systematic differences in the modeled trend compared to observations that must be caused by incorrect trends in the utilized emissions inventory or by too high sensitivity of our model to emissions changes.

  13. MLP based models to predict PM10, O3 concentrations, in Sines industrial area

    Science.gov (United States)

    Durao, R.; Pereira, M. J.

    2012-04-01

    Sines is an important Portuguese industrial area located southwest cost of Portugal with important nearby protected natural areas. The main economical activities are related with this industrial area, the deep-water port, petrochemical and thermo-electric industry. Nevertheless, tourism is also an important economic activity especially in summer time with potential to grow. The aim of this study is to develop prediction models of pollutant concentration categories (e.g. low concentration and high concentration) in order to provide early warnings to the competent authorities who are responsible for the air quality management. The knowledge in advanced of pollutant high concentrations occurrence will allow the implementation of mitigation actions and the release of precautionary alerts to population. The regional air quality monitoring network consists in three monitoring stations where a set of pollutants' concentrations are registered on a continuous basis. From this set stands out the tropospheric ozone (O3) and particulate matter (PM10) due to the high concentrations occurring in the region and their adverse effects on human health. Moreover, the major industrial plants of the region monitor SO2, NO2 and particles emitted flows at the principal chimneys (point sources), also on a continuous basis,. Therefore Artificial neuronal networks (ANN) were the applied methodology to predict next day pollutant concentrations; due to the ANNs structure they have the ability to capture the non-linear relationships between predictor variables. Hence the first step of this study was to apply multivariate exploratory techniques to select the best predictor variables. The classification trees methodology (CART) was revealed to be the most appropriate in this case.. Results shown that pollutants atmospheric concentrations are mainly dependent on industrial emissions and a complex combination of meteorological factors and the time of the year. In the second step, the Multi

  14. AFM Studies of Salt Concentration Effects on the (110) Surface Structure of Tetragonal Lysozyme Crystals

    Science.gov (United States)

    Pusey, Marc Lee; Gorti, Sridhar; Forsythe, Elizabeth; Konnert, John

    2002-01-01

    Previous high resolution AFM studies of the (110) surface of tetragonal chicken egg white lysozyme crystals had shown that only one of two possible molecular surfaces is present, those constituting the completed 43 helices. These suggested that the crystal growth process was by the solution-phase assembly of the growth units, which then attach to the surface. However, the best fit for the imaged surfaces, vs. those predicted based upon the bulk crystallographic coordinates, were obtained when the packing about the 43 helices was "tightened up", while maintaining the underlying crystallographic unit cell spacing. This results in a widening of the gap between adjacent helices, and the top- most layer(s) may no longer be in contact. We postulated that the tightened packing about the helices is a result of the high salt concentrations in the bulk solution, used to crystallize the protein, driving hydrophobic interactions. Once the crystal surface is sufficiently buried by subsequent growth layers the ratio of salt to protein molecules decreases and the helices relax to their bulk crystallographic coordinates. The crystal surface helix structure is thus a reflection of the solution structure, and the tightness of the packing about the 43 helices would be a function of the bulk salt concentration. AFM images of the (110) surface of tetragonal lysozyme crystals grown under low (2%) and high (5%) NaCl concentrations reveal differences in the packing about the 43 helices consistent with the above proposal.

  15. Mineral Element Concentrations in Vegetables Cultivated in Acidic Compared to Alkaline Areas of South Sweden

    Directory of Open Access Journals (Sweden)

    Ingegerd Rosborg

    2009-01-01

    Full Text Available A study in 1997, on mineral levels in acidic compared to alkaline well waters, and in women’s hair, revealed higher concentrations of a number of mineral elements like Ca, Mo and Se in alkaline waters and hair. Thus, median Ca levels were six times higher in well water and five times higher in hair from the alkaline area compared to the acidic area. This finding raised the probability of similar differences in vegetables from these areas. Thus, in the year 2006, 60 women who had participated in the study in 1997 were asked to cultivate parsley, lettuce, carrot and chive. During the spring of 2006, the women from the water and hair study of 1997, 30 of them from the acidic area and 30 women from the alkaline district cultivated vegetables: carrot (Daucus carota L, parsley (Petroselinum crispum, chive (Allium schoenoprasum and lettuce (Eruca sativa. The vegetables were harvested, and rinsed in tap water from the kitchens of the participating women in August. The concentrations of about 35 elements and ions were determined by ICP OES and ICP-MS predominantly. In addition, soil samples from the different cultivators were also analyzed for a number of elements. Lettuce and parsley showed the highest concentrations of mineral elements per gram dry weight. Only Mo concentrations were significantly higher in all the different vegetables from the alkaline district compared to vegetables from the acidic areas. On the other hand, the concentrations of Ba, Br, Mn, Rb and Zn were higher in all the different vegetables from the acidic area. In the soil, only pH and exchangeable Ca from the alkaline area were higher than from the acidic area, while exchangeable Fe, Mn and Na concentrations were higher in soils from the acidic area. Soil elements like Al, Fe, Li, Ni, Pb, Si, Ti, V, Zn and Zr were found in higher concentrations in lettuce and parsley, which were attributed to soil particles being splashed on the plants by the rain and absorbed by the leaves

  16. Seasonal Trend of PAHs Concentrations in Farmed Mussels from the Coastal Areas of the Naples, Italy.

    Science.gov (United States)

    Esposito, Mauro; Perugini, Monia; Lambiase, Sara; Conte, Annamaria; Baldi, Loredana; Amorena, Michele

    2017-09-01

    This paper reports on the results about the chemical pollution pressure in the Gulf of Naples and nearby coastal areas. Farmed mussels were analysed for the presence of polycyclic aromatic hydrocarbons (PAHs). The results documented a decreasing trend in the PAHs levels respect to the past years. The Bay of Pozzuoli remains as the most contaminated site within the Lucrino area with the highest reported number of samples exceeding the benzo(a)pyrene and PAHs sum limits. All the samples with concentrations above the European regulatory limit were collected in the winter period illustrating a seasonal trend of PAHs distribution in mussels during the 4 years investigated.

  17. Problems caused by the Concentration of Nuclear Power Plants in Border Areas

    International Nuclear Information System (INIS)

    Billman, C.

    1979-01-01

    The concentration of nuclear power plants in border areas raises the problem of protection of the population and the environment in border lands. The author recalls the fundamental legal principle according to which no country may cause a prejudice to a neighbouring country due to installations harmful to the environment which are located in its own territory. Several legal systems are reviewed which provide for participation by neighbouring states in nuclear plant projects and licensing; the recourse procedure against such plants is also discussed. Finally, consideration is given to problems to be solved in order to coordinate legal and administrative measures in case of construction of nuclear plants in border areas. (NEA) [fr

  18. SMAPVEX12 Surface Roughness Data for Agricultural Area V001

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set contains surface roughness data collected at several agricultural sites as a part of the Soil Moisture Active Passive Validation Experiment 2012...

  19. Metal concentrations in surface water and sediments from Pardo River, Brazil: human health risks.

    Science.gov (United States)

    Alves, Renato I S; Sampaio, Carolina F; Nadal, Martí; Schuhmacher, Marta; Domingo, José L; Segura-Muñoz, Susana I

    2014-08-01

    Pardo River (Brazil) is suffering from an important anthropogenic impact due to the pressure of highly populated areas and the influence of sugarcane cultivation. The objective of the present study was to determine the levels of 13 trace elements (As, Be, Cd, Cr, Cu, Pb, Mn, Hg, Ni, Tl, Sn, V and Zn) in samples of surface water and sediments from the Pardo River. Furthermore, the human health risks associated with exposure to those metals through oral intake and dermal absorption were also evaluated. Spatial and seasonal trends of the data were closely analyzed from a probabilistic approach. Manganese showed the highest mean concentrations in both water and sediments, remarking the incidence of the agricultural activity and the geological characteristics within the basin. Thallium and arsenic were identified as two priority pollutants, being the most important contributors to the Hazard Index (HI). Since non-carcinogenic risks due to thallium exposure slightly exceeded international guidelines (HI>1), a special effort should be made on this trace element. However, the current concentrations of arsenic, a carcinogenic element, were in accordance to acceptable lifetime risks. Nowadays, there is a clear increasing growth in human population and economic activities in the Pardo River, whose waters have become a serious strategic alternative for the potential supply of drinking water. Therefore, environmental monitoring studies are required not only to assure that the current state of pollution of Pardo River does not mean a risk for the riverside population, but also to assess the potential trends in the environmental levels of those elements. Copyright © 2014 Elsevier Inc. All rights reserved.

  20. Cacao roasting in rural areas of Peru using concentrated solar thermal energy: experimental results

    OpenAIRE

    Veynandt François; Perez Panduro Juan Pablo; Soria Navarro Jorge Elías; Hadzich Miguel

    2016-01-01

    Solar food processing is gaining interest for income generation. Our solar cacao roaster, designed for rural areas, consists in a horizontal rotating drum, opened at one end to collect solar radiation from Scheffler concentrators of 2.7 or 8 m2. The experimental results presented bring knowledge on the system's behavior and optimal operation. The influence of the most significant parameters is studied: quantity of cacao, absorptivity of drum's coating, thermal insulation, inclination and rota...

  1. Long-term variations in the surface air 7Be concentration and climatic changes.

    Science.gov (United States)

    Jiwen, Liu; Starovoitova, Valeriia N; Wells, Douglas P

    2013-02-01

    We have used EML Surface Air Sampling Program (SASP) data to analyze the long-term trend in (7)Be surface concentration and address possible correlation between this long-term trend and climatic changes, namely changes in precipitation patterns and temperature. In this paper we present (7)Be concentration data from 23 sites, spanning over 25 years, all over the world, and extract long-term trend parameter using two independent techniques. The (7)Be concentrations in most stations show a pronounced decreasing trend, potentially corresponding to statistically significant changes in transporting (7)Be from upper atmosphere source to these sites. Weak negative correlation between (7)Be concentration and amount of precipitation was also observed. However, more data from more representative sites around the world are needed the statistical robustness of this trend. Published by Elsevier Ltd.

  2. The osmolyte xylitol reduces the salt concentration of airway surface liquid and may enhance bacterial killing

    Science.gov (United States)

    Zabner, Joseph; Seiler, Michael P.; Launspach, Janice L.; Karp, Philip H.; Kearney, William R.; Look, Dwight C.; Smith, Jeffrey J.; Welsh, Michael J.

    2000-10-01

    The thin layer of airway surface liquid (ASL) contains antimicrobial substances that kill the small numbers of bacteria that are constantly being deposited in the lungs. An increase in ASL salt concentration inhibits the activity of airway antimicrobial factors and may partially explain the pathogenesis of cystic fibrosis (CF). We tested the hypothesis that an osmolyte with a low transepithelial permeability may lower the ASL salt concentration, thereby enhancing innate immunity. We found that the five-carbon sugar xylitol has a low transepithelial permeability, is poorly metabolized by several bacteria, and can lower the ASL salt concentration in both CF and non-CF airway epithelia in vitro. Furthermore, in a double-blind, randomized, crossover study, xylitol sprayed for 4 days into each nostril of normal volunteers significantly decreased the number of nasal coagulase-negative Staphylococcus compared with saline control. Xylitol may be of value in decreasing ASL salt concentration and enhancing the innate antimicrobial defense at the airway surface.

  3. Isoniazid concentrations in hair and plasma area-under-the-curve exposure among children with tuberculosis.

    Directory of Open Access Journals (Sweden)

    Vidya Mave

    Full Text Available We measured hair and plasma concentrations of isoniazid among sixteen children with tuberculosis who underwent personal or video-assisted directly observed therapy and thus had 100% adherence. This study therefore defined typical isoniazid exposure parameters after two months of treatment among fully-adherent patients in both hair and plasma (plasma area under the concentration-time curve, AUC, estimated using pharmacokinetic data collected 0, 2, 4, and 6 hours after drug administration. We found that INH levels in hair among highly-adherent individuals did not correlate well with plasma AUC or trough concentrations, suggesting that each measure may provide incremental and complementary information regarding drug exposure in the context of TB treatment.

  4. Hair mercury concentrations and associated factors in an electronic waste recycling area, Guiyu, China.

    Science.gov (United States)

    Ni, Wenqing; Chen, Yaowen; Huang, Yue; Wang, Xiaoling; Zhang, Gairong; Luo, Jiayi; Wu, Kusheng

    2014-01-01

    Toxic heavy metals are released to the environment constantly from unregulated electronic waste (e-waste) recycling in Guiyu, China, and thus may contribute to the elevation of mercury (Hg) and other heavy metals levels in human hair. We aimed to investigate concentrations of mercury in hair from Guiyu and potential risk factors and compared them with those from a control area where no e-waste processing occurs. A total of 285 human hair samples were collected from three villages (including Beilin, Xianma, and Huamei) of Guiyu (n=205) and the control area, Jinping district of Shantou city (n=80). All the volunteers were administered a questionnaire regarding socio-demographic characteristics and other possible factors contributed to hair mercury concentration. Hair mercury concentration was analyzed by hydride generation atomic fluorescence spectrometry (AFS). Our results suggested that hair mercury concentrations in volunteers of Guiyu (median, 0.99; range, 0.18-3.98μg/g) were significantly higher than those of Jinping (median, 0.59; range, 0.12-1.63μg/g). We also observed a higher over-limit ratio (>1μg/g according to USEPA) in Guiyu than in Jinping (48.29% vs. 11.25%, P<0.001). Logistic regression model showed that the variables of living house also served as an e-waste workshop, work related to e-waste, family income, time of residence in Guiyu, the distance between home and waste incineration, and fish intake were associated with hair mercury concentration. After multiple stepwise regression analysis, in the Guiyu samples, hair mercury concentration was found positively associated with the time residence in Guiyu (β=0.299, P<0.001), and frequency of shellfish intake (β=0.184, P=0.016); and negatively associated with the distance between home and waste incineration (β=-0.190, P=0.015) and whether house also served as e-waste workshop (β=-0.278, P=0.001). This study investigated human mercury exposure and suggested elevated hair mercury concentrations in

  5. Hair mercury concentrations and associated factors in an electronic waste recycling area, Guiyu, China

    Energy Technology Data Exchange (ETDEWEB)

    Ni, Wenqing [Department of Preventive Medicine, Shantou University Medical College, Shantou 515041, Guangdong (China); Chen, Yaowen [Central Laboratory of Shantou University, Shantou 515063, Guangdong (China); Huang, Yue; Wang, Xiaoling [Department of Preventive Medicine, Shantou University Medical College, Shantou 515041, Guangdong (China); Zhang, Gairong [Central Laboratory of Shantou University, Shantou 515063, Guangdong (China); Luo, Jiayi [Department of Preventive Medicine, Shantou University Medical College, Shantou 515041, Guangdong (China); Wu, Kusheng, E-mail: kswu@stu.edu.cn [Department of Preventive Medicine, Shantou University Medical College, Shantou 515041, Guangdong (China)

    2014-01-15

    Objective: Toxic heavy metals are released to the environment constantly from unregulated electronic waste (e-waste) recycling in Guiyu, China, and thus may contribute to the elevation of mercury (Hg) and other heavy metals levels in human hair. We aimed to investigate concentrations of mercury in hair from Guiyu and potential risk factors and compared them with those from a control area where no e-waste processing occurs. Methods: A total of 285 human hair samples were collected from three villages (including Beilin, Xianma, and Huamei) of Guiyu (n=205) and the control area, Jinping district of Shantou city (n=80). All the volunteers were administered a questionnaire regarding socio-demographic characteristics and other possible factors contributed to hair mercury concentration. Hair mercury concentration was analyzed by hydride generation atomic fluorescence spectrometry (AFS). Results: Our results suggested that hair mercury concentrations in volunteers of Guiyu (median, 0.99; range, 0.18–3.98 μg/g) were significantly higher than those of Jinping (median, 0.59; range, 0.12–1.63 μg/g). We also observed a higher over-limit ratio (>1 μg/g according to USEPA) in Guiyu than in Jinping (48.29% vs. 11.25%, P<0.001). Logistic regression model showed that the variables of living house also served as an e-waste workshop, work related to e-waste, family income, time of residence in Guiyu, the distance between home and waste incineration, and fish intake were associated with hair mercury concentration. After multiple stepwise regression analysis, in the Guiyu samples, hair mercury concentration was found positively associated with the time residence in Guiyu (β=0.299, P<0.001), and frequency of shellfish intake (β=0.184, P=0.016); and negatively associated with the distance between home and waste incineration (β=−0.190, P=0.015) and whether house also served as e-waste workshop (β=−0.278, P=0.001). Conclusions: This study investigated human mercury exposure

  6. Hair mercury concentrations and associated factors in an electronic waste recycling area, Guiyu, China

    International Nuclear Information System (INIS)

    Ni, Wenqing; Chen, Yaowen; Huang, Yue; Wang, Xiaoling; Zhang, Gairong; Luo, Jiayi; Wu, Kusheng

    2014-01-01

    Objective: Toxic heavy metals are released to the environment constantly from unregulated electronic waste (e-waste) recycling in Guiyu, China, and thus may contribute to the elevation of mercury (Hg) and other heavy metals levels in human hair. We aimed to investigate concentrations of mercury in hair from Guiyu and potential risk factors and compared them with those from a control area where no e-waste processing occurs. Methods: A total of 285 human hair samples were collected from three villages (including Beilin, Xianma, and Huamei) of Guiyu (n=205) and the control area, Jinping district of Shantou city (n=80). All the volunteers were administered a questionnaire regarding socio-demographic characteristics and other possible factors contributed to hair mercury concentration. Hair mercury concentration was analyzed by hydride generation atomic fluorescence spectrometry (AFS). Results: Our results suggested that hair mercury concentrations in volunteers of Guiyu (median, 0.99; range, 0.18–3.98 μg/g) were significantly higher than those of Jinping (median, 0.59; range, 0.12–1.63 μg/g). We also observed a higher over-limit ratio (>1 μg/g according to USEPA) in Guiyu than in Jinping (48.29% vs. 11.25%, P<0.001). Logistic regression model showed that the variables of living house also served as an e-waste workshop, work related to e-waste, family income, time of residence in Guiyu, the distance between home and waste incineration, and fish intake were associated with hair mercury concentration. After multiple stepwise regression analysis, in the Guiyu samples, hair mercury concentration was found positively associated with the time residence in Guiyu (β=0.299, P<0.001), and frequency of shellfish intake (β=0.184, P=0.016); and negatively associated with the distance between home and waste incineration (β=−0.190, P=0.015) and whether house also served as e-waste workshop (β=−0.278, P=0.001). Conclusions: This study investigated human mercury exposure

  7. Properties that influence the specific surface areas of carbon nanotubes and nanofibers.

    Science.gov (United States)

    Birch, M Eileen; Ruda-Eberenz, Toni A; Chai, Ming; Andrews, Ronnee; Hatfield, Randal L

    2013-11-01

    Commercially available carbon nanotubes and nanofibers were analyzed to examine possible relationships between their Brunauer-Emmett-Teller specific surface areas (SSAs) and their physical and chemical properties. Properties found to influence surface area were number of walls/diameter, impurities, and surface functionalization with hydroxyl and carboxyl groups. Characterization by electron microscopy, energy-dispersive X-ray spectrometry, thermogravimetric analysis, and elemental analysis indicates that SSA can provide insight on carbon nanomaterials properties, which can differ vastly depending on synthesis parameters and post-production treatments. In this study, how different properties may influence surface area is discussed. The materials examined have a wide range of surface areas. The measured surface areas differed from product specifications, to varying degrees, and between similar products. Findings emphasize the multiple factors that influence surface area and mark its utility in carbon nanomaterial characterization, a prerequisite to understanding their potential applications and toxicities. Implications for occupational monitoring are discussed.

  8. Indoor Radon Concentration Related to Different Radon Areas and Indoor Radon Prediction

    Science.gov (United States)

    Juhásová Šenitková, Ingrid; Šál, Jiří

    2017-12-01

    Indoor radon has been observed in the buildings at areas with different radon risk potential. Preventive measures are based on control of main potential radon sources (soil gas, building material and supplied water) to avoid building of new houses above recommended indoor radon level 200 Bq/m3. Radon risk (index) estimation of individual building site bedrock in case of new house siting and building protection according technical building code are obligatory. Remedial actions in buildings built at high radon risk areas were carried out principally by unforced ventilation and anti-radon insulation. Significant differences were found in the level of radon concentration between rooms where radon reduction techniques were designed and those where it was not designed. The mathematical model based on radon exhalation from soil has been developed to describe the physical processes determining indoor radon concentration. The model is focused on combined radon diffusion through the slab and advection through the gap from sub-slab soil. In this model, radon emanated from building materials is considered not having a significant contribution to indoor radon concentration. Dimensional analysis and Gauss-Newton nonlinear least squares parametric regression were used to simplify the problem, identify essential input variables and find parameter values. The presented verification case study is introduced for real buildings with respect to various underground construction types. Presented paper gives picture of possible mathematical approach to indoor radon concentration prediction.

  9. Assesment of Pb concentration in PM2,5 and PM10 at Serpong area

    International Nuclear Information System (INIS)

    Rita; Esrom Hamonangan; Halimah Syafrul; Muhayatun Santoso; Diah Dwiana Lestian

    2010-01-01

    Ambient air pollution, especially Pb, in Serpong area has been detected since 1996. Pollution caused by heavy metals Pb deserve serious attention because of the impact is very influential on health such as reduced levels of intelligence, learning disability, symptoms of anemia, barriers to growth, poor cognitive development, weakened immune system, symptoms of autism, and even premature death. This study was conducted to determine Pb concentration of PM 2,5 and PM 10 in four residential locations in Serpong area as part of a series of comprehensive studies for the characterization and identification of sources pollution. Particulates were sampled using Gent Stacked Filter Unit Sampler at 3 housing locations and 1 office location in the period of August 25 to November 3, 2008, Samples were analyzed using nuclear analytical techniques, Proton Induced X-ray Emission. The results showed that the activity concentration of Pb in PM 2,5 for the location of Setu, Pusarpedal, Batan Indah, and BSD were in the range of 33-388, 12-254, 6-282, and 5-332 ng/m 3 , while for PM 10 were 69-732, 59-647, 31-810, and 28718 ng/m 3 , respectively, In general, Pb concentrations in Serpong area were higher than those in some other cities in Asia region. These results are expected to be used as scientific based reference in formulating, taking action, and appropriate policies to overcome environmental problems. (author)

  10. Comparison of DDT and its metabolites concentrations in cow milk from agricultural and industrial areas.

    Science.gov (United States)

    Kuba, Jarosław; Tomza-Marciniak, Agnieszka; Pilarczyk, Bogumiła; Tarasewicz, Natalia; Pilarczyk, Renata; Ligocki, Marek

    2015-01-01

    The risk of pesticidal intoxication in humans is severe, especially because of the strongly negative impact on human health. The consequences of the exposure to these substances may include cancerogenesis or endocrine abnormalities resulting for example in decreased fertility. Therefore, the aim of our study was to evaluate the content of dichlorodiphenyltrichloroethane (DDT) and its metabolites in cow milk from two regions of Poland, varying by level of industrialization. Samples were collected from agricultural (n = 25) and industrial (n = 25) areas, and the concentrations of DDT and its metabolites were evaluated by gas chromatography. Residues of DDT were detected in all the milk samples tested, mostly in the samples from the agricultural area, where a total DDT median concentration reached 0.336 μg L(-1). In the milk samples from the industrial area, the median concentration was lower, at 0.131 μg L(-1). 4,4'-DDT was the main metabolite, constituting 83% of total DDT metabolites. Although none of the samples exceeded the level above which they should be considered dangerous, the results showed that the problem of DDT had not diminished and so should be constantly monitored.

  11. 20 CFR 645.525 - What special consideration will be given to rural areas and cities with large concentrations of...

    Science.gov (United States)

    2010-04-01

    ... rural areas and cities with large concentrations of poverty? 645.525 Section 645.525 Employees' Benefits... cities with large concentrations of poverty? (a) Competitive grant awards will be targeted to geographic... rural areas and cities with large concentrations of residents living in poverty. (b) Grant application...

  12. Helium concentration in tungsten nano-tendril surface morphology using Elastic Recoil Detection

    International Nuclear Information System (INIS)

    Woller, K.B.; Whyte, D.G.; Wright, G.M.; Doerner, R.P.; De Temmerman, G.

    2013-01-01

    Helium (He) concentrations in tungsten nano-tendrils (W fuzz) have been measured for the first time using Elastic Recoil Detection (ERD). Fuzzy and non-fuzzy W surfaces were analyzed in order to illuminate the role of He in the transition in surface morphologies. Samples grown in the PISCES-A and PILOT-PSI experiments allowed a survey of surface temperature ranging from T s = 470–2595 K and of He fluence on the order of Φ He ∼ 10 24 –10 27 ions/m 2 . He concentrations measured in the bulk of W fuzz layers are roughly uniform with bulk He concentration 1–4 at.% while samples with just He in the near surface peaked at 1–2 at.%. This confirms that the nano-tendrils are filled with high pressure He bubbles since the solubility of He in W is ∼10 −5 at.%. This indicates that the ∼1000 K temperature fuzz-growth threshold is determined by the response of the W, not the near-surface He concentration

  13. Concentration of uranium in the drinking and surface water around the WIPP site

    International Nuclear Information System (INIS)

    Khaing, H.; Lemons, B.G.; Thakur, P.

    2016-01-01

    Activity concentration of uranium isotopes ( 238 U, 234 U and 235 U) were analyzed in drinking and surface water samples collected in the vicinity of the WIPP site using alpha spectroscopy. The purpose of this study was to investigate the changes in uranium concentrations (if any) in the vicinity of the WIPP site and whether the February 14, 2014 radiation release event at the WIPP had any detectable impact on the water bodies around the WIPP. (author)

  14. High-surface-area silica nanospheres (KCC-1) with a fibrous morphology

    KAUST Repository

    Polshettiwar, Vivek

    2010-08-02

    Fibrous nanosilica: A new family of high-surface-area silica nanospheres (KCC-1) have been prepared (see picture). KCC-1 features excellent physical properties, including high surface area, unprecedented fibrous surface morphology, high thermal (up to 950 °C) and hydrothermal stabilities, and high mechanical stability. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Surface deformation of active volcanic areas retrieved with the SBAS-DInSAR technique: an overview

    Directory of Open Access Journals (Sweden)

    G. Zeni

    2008-06-01

    Full Text Available This paper presents a comprehensive overview of the surface deformation retrieval capability of the Differential Synthetic Aperture Radar Interferometry (DInSAR algorithm, referred to as Small BAseline Subset (SBAS technique, in the context of active volcanic areas. In particular, after a brief description of the algorithm some experiments relevant to three selected case-study areas are presented. First, we concentrate on the application of the SBAS algorithm to a single-orbit scenario, thus considering a set of SAR data composed by images acquired on descending orbits by the European Remote Sensing (ERS radar sensors and relevant to the Long Valley caldera (eastern California area. Subsequently, we address the capability of the SBAS technique in a multipleorbit context by referring to Mt. Etna volcano (southern Italy test site, with respect to which two different ERS data set, composed by images acquired both on ascending and descending orbits, are available. Finally, we take advantage of the capability of the algorithm to work in a multi-platform scenario by jointly exploiting two different sets of SAR images collected by the ERS and the Environment Satellite (ENVISAT radar sensors in the Campi Flegrei caldera (southern Italy area. The presented results demonstrate the effectiveness of the algorithm to investigate the deformation field in active volcanic areas and the potential of the DInSAR methodologies within routine surveillance scenario.

  16. Concentration polarization and desalination in nanochannels: Effect of surface charge dynamics

    Science.gov (United States)

    Andersen, Mathias B.; Bruus, Henrik; Mani, Ali; Bazant, Martin Z.

    2011-11-01

    Mani, Zangle, and Santiago (Langmuir, 25, 3898-3916) have shown that at microchannel-nanochannel junctions the coupled effect of concentration polarization and surface conduction can lead to long range propagation of bulk ion-depletion shocks. Essential for this phenomena is the surface charge which for many materials depends on both the concentration and the pH of the local bulk electrolyte. Standard models predict that the surface charge decreases with decreasing concentration leading to the contradictory expectation that there is little or no surface charge in the depleted region and hence no mechanism to sustain long range propagation of desalination shocks. We show that this simple prediction fails to take into account axial transport terms. As such, we couple a surface charge model with the Poisson-Nernst-Planck equations for electric potential and ionic species combined with the Navier-Stokes and continuity equations for fluid velocity. Motivated by experimental work we consider steady-state solutions at the dead end of a nanochannel against a membrane, a scenario where especially space charge and electroosmotic flow are important. Our results suggest that the surface charge density remains finite and does not vanish, and even grows, as the depletion front propagates through the channel.

  17. Modeling the dynamics of radionuclide concentration in animal derived products after an accident in tropical areas

    International Nuclear Information System (INIS)

    Vinhas, Denise M.; Rochedo, Elaine R.R.; Wasserman, Maria A.V.; Conti, Luiz F.C.

    2005-01-01

    Following an accidental release of radionuclides to the atmosphere with the contamination of large areas, a detailed and fast methodology to assess the prognosis of public exposure is needed to estimate radiological consequences and optimize decisions to the protection of the public. The German model ECOSYS has been chosen to integrate the SIEM - Integrated Emergency System, developed by IRD/CNEN to assess the doses to the public after an accidental contamination of rural areas. The use the model demands a considerable effort in adapting scenarios to fit the specific conditions of a location, considering the differences related to climate, environmental characteristics, agricultural calendar and practices, along with population diet. The area selected to start this adaptation considers the characteristics of the 50 km radius area surrounding the nuclear power plants at Angra dos Reis, Rio de Janeiro. At a first stage, the concentration on vegetal food products has been studied. This work describes the methodology used to select scenarios and presents results of the dynamics of the predicted concentration of radionuclides in different kinds of animal derived food products. The work provides guidance to the need of radioecological research needed to improve the adequacy of the estimates to actual Brazilian scenarios. (author)

  18. Lead (Pb) and Zinc (Zn) Concentrations in Marine Gastropod Strombus Canarium in Johor Coastal Areas

    International Nuclear Information System (INIS)

    Shaikhah Sabri; Mohd Ismid Mohd Said; Shamila Azman

    2014-01-01

    Strombus canarium is a popular food source with high commercial value in southern part of Peninsular Malaysia. As a deposit feeder, Strombus canarium can accumulate pollutants especially heavy metals in their system. Study on this species was conducted at Teluk Sengat and Mersing, Johor where samples of seawater and Strombus canarium were collected during spring low tides around 0 to 0.2 meters. Lead (Pb) and zinc (Zn) concentrations were investigated to determine pollution status in the area. Samples from Teluk Sengat showed that Zn has higher concentration in both water and S. canarium with 0.055 mg/ L and 20.257 mg/ kg wet weight respectively. However the concentrations were within permissible limit of Malaysia Marine Water Quality Criteria and Standard (MMWQS). In contrast, Pb concentration at Teluk Sengat exceeded the MMWQS and its concentration in soft tissues of S. canarium also exceeded the permissible limit recommended by Food and Agriculture Organisation (0.5 mg/ kg wet weight) and World Health Organisation (0.2 mg/ kg wet weight). (author)

  19. RESRAD soil concentration guidelines for the Old F-Area Retention Basin

    International Nuclear Information System (INIS)

    Hamby, D.M.

    1994-01-01

    Concentration guidelines for residual radionuclides in soil at the site of the Old F-Area Retention Basin have been calculated using a dose-based approach. Estimation of these soil guidelines was completed using RESRAD 5.0 in accordance with the DOE RESRAD methodology specified in DOE/CH/8901. Guidelines are provided for the two predominant nuclides, Sr-90 and Cs-137, known to be present in the soil beneath the old basin. A guideline is also given for Pu-238 since it is known to exist at the H-Area Retention Basin. Site-specific soil characteristics are defined for the areas above, within, and beneath the contaminated zone

  20. Guidelines for acceptable soil concentrations in the old F- and H-Area Retention Basins

    International Nuclear Information System (INIS)

    Hamby, D.M.

    1994-01-01

    Concentration guidelines for residual radionuclides in soil at the sites of the Old F- and H-Area Retention Basins (281-3F, 281-3H) have been calculated using a dose-based approach. The guidelines also are being applied to areas around the F-Basin's Process Line. Estimation of these soil guidelines was completed using RESRAD 5.0 in accordance with the DOE RESRAD methodology specified in DOE/CH/8901 (Gi89). Guidelines are provided for the nuclides known to be present in the soils at each basin (Sc87). Soil and hydrologic characteristics specific to each basin are defined for the areas above, within, and beneath the contaminated zones

  1. Rodent movements, densities and radionuclide concentrations at a liquid radioactive waste disposal area

    International Nuclear Information System (INIS)

    Halford, D.K.

    1983-01-01

    Movements and densities of rodents at a liquid radioactive waste disposal area were studied from June to September 1981 using trap line and assessment line techniques. The average distance between points of successive capture was 42 +- 25 (SD) m for deer mice (Peromyscus maniculatus) and 37 +- 21 m for kangaroo rats (Dipodomys ordii). Densities of deer mice averaged 10.2/ha with a population estimate of 57 within the area of rodent captures. The population estimate of 4 species of small mammals at the waste pond complex was 93. Radionuclide concentrations averaged 133 +- 97 pCi/g for rodents captured inside the disposal area boundary, 18 +- 22 pCi/g for those captured outside of the dispoal area fence and 0.50 +- 0.6 pCi/g for control animals. Species captured outside of the waste area boundary had significantly lower (P 137 Cs, 134 Cs, 60 Co and 65 Zn) in rodents at the liquid waste disposal area was estimated to be about 162 nCi

  2. Plutonium isotopes concentration in seawater and bottom sediment off the Pacific coast of Aomori sea area during 1991-2005

    Energy Technology Data Exchange (ETDEWEB)

    Oikawa, Shinji, E-mail: oikawa@kaiseiken.or.j [Marine Ecology Research Institute, Head Office, Research and Survey Group, Towa-Edogawabashi Bldg. 7F., 347 Yamabuki-cho, Shinjuku-ku, Tokyo 162-0801 (Japan); Watabe, Teruhisa [Marine Ecology Research Institute, Head Office, Research and Survey Group, Towa-Edogawabashi Bldg. 7F., 347 Yamabuki-cho, Shinjuku-ku, Tokyo 162-0801 (Japan); Inatomi, Naohiko [Marine Ecology Research Institute, Central Laboratory, 300 Iwawada, Onjuku-machi, Isumi-gun, Chiba 299-5105 (Japan); Isoyama, Naohiko; Misonoo, Jun; Suzuki, Chiyoshi; Nakahara, Motokazu; Nakamura, Ryoichi; Morizono, Shigemitsu; Fujii, Seiji [Marine Ecology Research Institute, Head Office, Research and Survey Group, Towa-Edogawabashi Bldg. 7F., 347 Yamabuki-cho, Shinjuku-ku, Tokyo 162-0801 (Japan); Hara, Takeya [Marine Ecology Research Institute, Central Laboratory, 300 Iwawada, Onjuku-machi, Isumi-gun, Chiba 299-5105 (Japan); Kido, Katsutoshi [Marine Ecology Research Institute, Head Office, Research and Survey Group, Towa-Edogawabashi Bldg. 7F., 347 Yamabuki-cho, Shinjuku-ku, Tokyo 162-0801 (Japan)

    2011-03-15

    A radioactivity survey was launched in 1991 to determine the background levels of {sup 239+240}Pu in the marine environment off a commercial spent nuclear fuel reprocessing plant before full operation of the facility. Particular attention was focused on the {sup 240}Pu/{sup 239}Pu atom ratio in seawater and bottom sediment to identify the origins of Pu isotopes. The concentration of {sup 239+240}Pu was almost uniform in surface water, decreasing slowly over time. Conversely, the {sup 239+240}Pu concentration varied markedly in the bottom water and was dependent upon the sampling point, with higher concentrations of {sup 239+240}Pu observed in the bottom water sample at sampling points having greater depth. The {sup 240}Pu/{sup 239}Pu atom ratio in the seawater and sediment samples was higher than that of global fallout Pu, and comparable with the data in the other sea area around Japan which has likely been affected by close-in fallout Pu originating from the Pacific Proving Grounds. The {sup 240}Pu/{sup 239}Pu atom ratio in bottom sediment samples decreased with sea depth. The land-originated Pu is not considered as the reason of the increasing {sup 239+240}Pu concentration and also decreasing the {sup 240}Pu/{sup 239}Pu atom ratio with sea depth, and further study is required to clarify it. - Research highlights: {yields} A radioactivity survey on Pu isotopes was carried out in the coastal sea adjacent the nuclear fuel reprocessing plant in Aomori, Japan during 1991-2005. {yields} The {sup 239+240}Pu concentrations were uniform in surface water from one sampling point to another and decreased with a half-life of 17.8 y on the average. {yields} The time dependent decrease of {sup 239+240}Pu concentration in bottom water became more gradual with the increase of the depth. {yields} The {sup 239+240}Pu concentrations were relatively low in sediments at the shallow sampling points, but higher at the deeper points, without time dependent changes. {yields} The higher

  3. Application of Full Factorial Experimental Design and Response Surface Methodology for Chromite Beneficiation by Knelson Concentrator

    Directory of Open Access Journals (Sweden)

    Gul Akar Sen

    2016-01-01

    Full Text Available The present work is undertaken to determine the effect of operational variables, namely: feed rate, centrifugal force and fluidization water flow rate on the efficiency of Knelson concentrator for chromite ore beneficiation. A full factorial design with three factors at three levels and response surface methodology (RSM were applied for this purpose. The quadratic models were developed to predict the concentrate Cr2O3 grade and recovery as the process responses. The results suggest that all the variables affect the grade and recovery of the Cr2O3 concentrate to some degree. However, the fluidization water rate was found as the most effective parameter.

  4. Military Surface Grid Areas: Atlantic / Gulf of Mexico

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A regular pattern of polygons that represent arbitrary delineations of an Operating Area (OPAREA). The MarineCadastre.gov team worked with the Navy to provide this...

  5. Diurnal variations of airborne fungal spores concentration in the town and rural area

    Directory of Open Access Journals (Sweden)

    Idalia Kasprzyk

    2012-12-01

    Full Text Available Airborne fungal spores were monitored in 2001-2002 in Rzeszów (town and its neighborhood. The aim of investigations was to ascertain if there were differences in diurnal variations of airborne fungal spores concentration between town and rural area. The sampling was carried out using volumetric method. Traps were located at the same heights - app. 12 m. Airborne spores were sampled continuously. Microscopical slides were prepared for each day. Analysis was carried out on one longitudinal band of 48 mm long divided into 24 segments corresponding following hours of day. The results were expressed as mean number of fungal spores per cubic meter per 24 hours. For this survey, five geni of allergenic fungi were selected: Alternaria, Botrytis, Cladosporium, Epicoccum, Ganoderma. The concentrations of their airborne spores were high or very high. It was calculated theoretical day, where the hourly count was the percentage mean of number of spores at that time every chosen day without rainfall from 2001 and 2001 years. The diurnal periodicity of Alternaria, Cladosporium, Epicoccum and Ganoderma showed one peak, while Botrytis two. Anamorphic spores peaked in the afternoon, while their minima occurred in the morning. The highest concentrations of Ganoderma basidiospores were at down or at night, but minima during the day. There were no clear differences in the peak values between two studied sites. The results indicate that maximum concentrations of all spores generally occurred a few hour earlier in the rural area than in the town. Probably, in the rural area airborne spores came from many local sources and their diurnal periodicity reflected rhythm of spore liberation. Towns are characterized by specific microclimate with higher temperature and wind blowing to the centre. In Rzeszów fungal spores could be transported outside and carried out by wind from distant sources. This study showed, among others, that habitat conditions are an important factors

  6. Corrective Action Decision Document for Corrective Action Unit 417: Central Nevada Test Area Surface, Nevada

    International Nuclear Information System (INIS)

    1999-01-01

    This Corrective Action Decision Document (CADD) identifies and rationalizes the U.S. Department of Energy, Nevada Operations Office's selection of a recommended corrective action alternative (CAA) appropriate to facilitate the closure of Corrective Action Unit (CAU) 417: Central Nevada Test Area Surface, Nevada, under the Federal Facility Agreement and Consent Order. Located in Hot Creek Valley in Nye County, Nevada, and consisting of three separate land withdrawal areas (UC-1, UC-3, and UC-4), CAU 417 is comprised of 34 corrective action sites (CASs) including 2 underground storage tanks, 5 septic systems, 8 shaker pad/cuttings disposal areas, 1 decontamination facility pit, 1 burn area, 1 scrap/trash dump, 1 outlier area, 8 housekeeping sites, and 16 mud pits. Four field events were conducted between September 1996 and June 1998 to complete a corrective action investigation indicating that the only contaminant of concern was total petroleum hydrocarbon (TPH) which was found in 18 of the CASs. A total of 1,028 samples were analyzed. During this investigation, a statistical approach was used to determine which depth intervals or layers inside individual mud pits and shaker pad areas were above the State action levels for the TPH. Other related field sampling activities (i.e., expedited site characterization methods, surface geophysical surveys, direct-push geophysical surveys, direct-push soil sampling, and rotosonic drilling located septic leachfields) were conducted in this four-phase investigation; however, no further contaminants of concern (COCs) were identified. During and after the investigation activities, several of the sites which had surface debris but no COCs were cleaned up as housekeeping sites, two septic tanks were closed in place, and two underground storage tanks were removed. The focus of this CADD was to identify CAAs which would promote the prevention or mitigation of human exposure to surface and subsurface soils with contaminant

  7. Concentration of radiocesium in stream water from a mountainous catchment area during rainfall events

    International Nuclear Information System (INIS)

    Nakamura, Kimihito; Yasutaka, Tetsuo; Hatakeyama, Masato

    2013-01-01

    Terrestrial and aquatic systems were contaminated with radioactive materials following the nuclear accident at Fukushima Daiichi Nuclear Power Station on 11 March, 2011. It is important that levels of radiocesium (Cs) in stream water from affected areas be monitored as this water is used for paddy irrigation and domestic water. Additionally, soil particles and organic matter from the streams are deposited in rivers, estuaries and into the ocean. Predictions suggest that Cs levels will increase during intense rainfall-runoff events. To check this prediction, we monitored temporal changes in runoff events and Cs levels in stream water from a mountainous catchment area northwest of the Fukushima plant. In March and April, 2012, the concentrations of Cs and suspended solids (SS) in stream water taken from low-level water flow were found to be 0.2-0.3 Bq/L and 2-7 mg/L, respectively. A heavy rainfall event in July 2012 resulted in an increase and subsequent decrease of both the runoff volume and SS concentration. At the beginning of the rainfall event the concentration of Cs absorbed in the SS was measured to be 23 Bq/L, this decreased gradually to 0.3 Bq/L over the course of the event. The concentration of Cs dissolved in the water was 0.1 Bq/L, this decreased only slightly during the runoff event. During a low rainfall event in September 2012 the concentration of Cs absorbed in the SS at the beginning of the rainfall event was found to be 15 Bq/L, this decreased gradually to 0.5 Bq/L as the amount of SS in the water decreased. The concentration of Cs dissolved in the water was 0.2 Bq/L, again this decreased only slightly over the course of the runoff event. The Cs levels in stream water, during rainfall-runoff events, were primary influenced by the concentration of SS. The amount of Cs dissolved in the water, on the other hand, was roughly constant at 0.1-0.2 Bq/L. The results of this study indicate that, although the concentration of Cs in stream water is below the

  8. Concentration of radiocesium in stream water from a mountainous catchment area during rainfall events

    International Nuclear Information System (INIS)

    Nakamura, Kimihito; Yasutaka, Tetsuo; Hatakeyama, Masato

    2012-01-01

    Terrestrial and aquatic systems were contaminated with radioactive materials following the nuclear accident at Fukushima Daiichi Nuclear Power Station on 11 March, 2011. It is important that levels of radiocesium (Cs) in stream water from affected areas be monitored as this water is used for paddy irrigation and domestic water. Additionally, soil particles and organic matter from the streams are deposited in rivers, estuaries and into the ocean. Predictions suggest that Cs levels will increase during intense rainfall-runoff events. To check this prediction, we monitored temporal changes in runoff events and Cs levels in stream water from a mountainous catchment area northwest of the Fukushima plant. In March and April, 2012, the concentrations of Cs and suspended solids (SS) in stream water taken from low-level water flow were found to be 0.2–0.3 Bq/L and 2–7 mg/L, respectively. A heavy rainfall event in July 2012 resulted in an increase and subsequent decrease of both the runoff volume and SS concentration. At the beginning of the rainfall event the concentration of Cs absorbed in the SS was measured to be 23 Bq/L, this decreased gradually to 0.3 Bq/L over the course of the event. The concentration of Cs dissolved in the water was 0.1 Bq/L, this decreased only slightly during the runoff event. During a low rainfall event in September 2012 the concentration of Cs absorbed in the SS at the beginning of the rainfall event was found to be 15 Bq/L, this decreased gradually to 0.5 Bq/L as the amount of SS in the water decreased. The concentration of Cs dissolved in the water was 0.2 Bq/L, again this decreased only slightly over the course of the runoff event. The Cs levels in stream water, during rainfall-runoff events, were primary influenced by the concentration of SS. The amount of Cs dissolved in the water, on the other hand, was roughly constant at 0.1–0.2 Bq/L. The results of this study indicate that, although the concentration of Cs in stream water is below

  9. Influence of Traffic Activity on Heavy Metal Concentrations of Roadside Farmland Soil in Mountainous Areas

    Directory of Open Access Journals (Sweden)

    Tandong Yao

    2012-05-01

    Full Text Available Emission of heavy metals from traffic activities is an important pollution source to roadside farmland ecosystems. However, little previous research has been conducted to investigate heavy metal concentrations of roadside farmland soil in mountainous areas. Owing to more complex roadside environments and more intense driving conditions on mountainous highways, heavy metal accumulation and distribution patterns in farmland soil due to traffic activity could be different from those on plain highways. In this study, design factors including altitude, roadside distance, terrain, and tree protection were considered to analyze their influences on Cu, Zn, Cd, and Pb concentrations in farmland soils along a mountain highway around Kathmandu, Nepal. On average, the concentrations of Cu, Zn, Cd, and Pb at the sampling sites are lower than the tolerable levels. Correspondingly, pollution index analysis does not show serious roadside pollution owing to traffic emissions either. However, some maximum Zn, Cd, and Pb concentrations are close to or higher than the tolerable level, indicating that although average accumulations of heavy metals pose no hazard in the region, some spots with peak concentrations may be severely polluted. The correlation analysis indicates that either Cu or Cd content is found to be significantly correlated with Zn and Pb content while there is no significant correlation between Cu and Cd. The pattern can be reasonably explained by the vehicular heavy metal emission mechanisms, which proves the heavy metals’ homology of the traffic pollution source. Furthermore, the independent factors show complex interaction effects on heavy metal concentrations in the mountainous roadside soil, which indicate quite a different distribution pattern from previous studies focusing on urban roadside environments. It is found that the Pb concentration in the downgrade roadside soil is significantly lower than that in the upgrade soil while the Zn

  10. 30 CFR 910.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... surface coal mining operations. 910.764 Section 910.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE GEORGIA § 910.764 Process for designating areas unsuitable for surface coal mining...

  11. 30 CFR 937.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... surface coal mining operations. 937.764 Section 937.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE OREGON § 937.764 Process for designating areas unsuitable for surface coal mining...

  12. 30 CFR 947.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 947.762 Section 947.762 Mineral Resources OFFICE OF SURFACE MINING... mining operations. Part 762 of this chapter, Criteria for Designating Areas Unsuitable for Surface Coal Mining Operations, shall apply to surface coal mining and reclamation operations. ...

  13. 30 CFR 921.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 921.762 Section 921.762 Mineral Resources OFFICE OF SURFACE MINING... mining operations. Part 762 of this chapter, Criteria for Designating Areas Unsuitable for Surface Coal Mining Operations, shall apply to surface coal mine operations. ...

  14. 30 CFR 922.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... surface coal mining operations. 922.764 Section 922.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE MICHIGAN § 922.764 Process for designating areas unsuitable for surface coal mining...

  15. 30 CFR 942.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... surface coal mining operations. 942.764 Section 942.764 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE TENNESSEE § 942.764 Process for designating areas unsuitable for surface coal mining... Mining Operations, shall apply to surface coal mining and reclamation operations. (b) The Secretary shall...

  16. 30 CFR 941.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... surface coal mining operations. 941.764 Section 941.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE SOUTH DAKOTA § 941.764 Process for designating areas unsuitable for surface coal mining...

  17. 30 CFR 941.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 941.762 Section 941.762 Mineral Resources OFFICE OF SURFACE MINING... mining operations. Part 762 of this chapter, Criteria for Designating Areas Unsuitable for Surface Coal Mining Operations, shall apply to surface coal mine operations. ...

  18. 30 CFR 939.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... surface coal mining operations. 939.764 Section 939.764 Mineral Resources OFFICE OF SURFACE MINING RECLAMATION AND ENFORCEMENT, DEPARTMENT OF THE INTERIOR PROGRAMS FOR THE CONDUCT OF SURFACE MINING OPERATIONS WITHIN EACH STATE RHODE ISLAND § 939.764 Process for designating areas unsuitable for surface coal mining...

  19. 30 CFR 933.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 933.762 Section 933.762 Mineral Resources OFFICE OF SURFACE MINING... mining operations. Part 762 of this chapter, Criteria for Designation Areas Unsuitable for Surface Coal Mining Operations, shall apply to surface coal mining and reclamation operations. ...

  20. 30 CFR 939.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 939.762 Section 939.762 Mineral Resources OFFICE OF SURFACE MINING... mining operations. Part 762 of this chapter, Criteria for Designating Areas Unsuitable for Surface Coal Mining Operations, shall apply to surface coal mining and reclamation operations. ...

  1. 30 CFR 905.762 - Criteria for designating areas as unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... for surface coal mining operations. 905.762 Section 905.762 Mineral Resources OFFICE OF SURFACE MINING... mining operations. Part 762 of this chapter, Criteria for Designating Areas Unsuitable for Surface Coal Mining Operations, shall apply to surface coal mining operations. ...

  2. Effects of contact time and concentration on bactericidal efficacy of 3 disinfectants on hard nonporous surfaces.

    Science.gov (United States)

    Hong, Yingying; Teska, Peter J; Oliver, Haley F

    2017-11-01

    This study investigated the influence of contact time and concentration on bactericidal efficacy of 3 types of disinfectants (accelerated hydrogen peroxide [AHP], quaternary ammonium compounds [Quats], and sodium hypochlorite) on stainless steel surfaces using Environmental Protection Agency procedure MB-25-02. We found that bactericidal efficacy was not reduced at contact times or concentrations immediate lower than label use values, but all 3 disinfectants were significantly less bactericidal at significantly lower than label use contact times and concentrations. Overall, the bactericidal efficacy of the sodium hypochlorite disinfectant was most tolerant to the decreases of contact times and concentrations, followed closely by AHP disinfectant, and Quat disinfectant was most affected by contact time and concentration. Copyright © 2017 Association for Professionals in Infection Control and Epidemiology, Inc. Published by Elsevier Inc. All rights reserved.

  3. STRATIGRAPHIC CONTROL ON CCL4 AND CHCL3 CONCENTRATIONS IN THE 200 WEST AREA, HANFORD SITE

    Energy Technology Data Exchange (ETDEWEB)

    Winsor, K.; Last, G.V.

    2008-01-01

    An extensive subsurface contaminant plume of carbon tetrachloride (CCl4) is the focus of a remedial effort in the 200 West Area of the U.S. Department of Energy’s Hanford Site in eastern Washington. Remediation requires a high-resolution understanding of the region’s spatially variable lithofacies and of the effect these lithofacies have on CCl4 migration through the unconfi ned aquifer. To increase the level of detail of our current understanding, a transect was chosen along the primary groundwater fl ow path in the most heavily contaminated area. Borehole logs of wells along this 3.7 km-long transect were standardized and used to create a cross section displaying the depth and continuity of lithofacies. Natural and spectral gamma geophysical logs were examined to pinpoint the depths of geologic units. Depth discrete concentrations of CCl4 and its reductive dechlorination product, chloroform (CHCl3), were overlain on this cross section. Comparison of stratigraphy to contaminant levels shows that peaks in CCl4 concentration occur in thin, fine-grained layers and that other fine-grained layers frequently form lower boundaries to regions of high concentration. Peaks in CCl4 concentrations are frequently located at different depths from those of CHCl3, suggesting that these concentrations are affected by dechlorination of CCl4. Transformation of CCl4 to CHCl3 appears to be more prevalent within reduced, iron-containing sediments. The infl uence of thin, fine-grained layers within the larger aquifer unit indicates that characterization of contamination in this locality should consider subsurface geology with at least as much resolution as provided in this study.

  4. Surface albedo measurements in Mexico City metropolitan area

    Energy Technology Data Exchange (ETDEWEB)

    Castro, T; Mar, B; Longoria, R; Ruiz Suarez, L. G [Centro de Ciencias de la Atmosfera, UNAM, Mexico, D.F. (Mexico); Morales, L [Instituto de Geografia, UNAM, Mexico, D.F. (Mexico)

    2001-04-01

    Optical and thermal properties of soils are important input data for the meteorological and photochemical modules of air quality models. As development of these models increase on spatial resolution good albedo data become more important. In this paper measurements of surface albedo of UV (295-385 nm) and visible (450-550 nm) radiation are reported for different urban and rural surfaces in the vicinity of Mexico City. It was found for the downtown zone and average albedo value of 0.05 which is in very good agreement with reported values for urban surfaces. Our albedo values measured in UV region for grey cement and green grass are of 0.10 and 0.009, respectively, and quite similar to those found at the literature of 0.11 and 0.008 for those type of surfaces. [Spanish] Las propiedades opticas y termicas de suelos son datos importantes para los modulos meteorologicos y fotoquimicos de los modelos de calidad del aire. Conforme aumenta la resolucion espacial del modelo se vuelve mas importante contar con buenos datos de albedo. En este articulo se presentan mediciones de albedo superficial de radiacion Ultravioleta (295-385 nm) y visible (450-550 nm) para diferentes superficies urbanas. Los valores medidos de albedo en la region UV para cemento gris y pasto verde son de 0.10 y 0.009, respectivamente, y son muy similares a los reportados en la literatura, 0.11 y 0.008 para este tipo de superficies.

  5. Large Area Diamond Tribological Surfaces with Negligible Wear in Extreme Environments, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — In Phase I we propose to demonstrate the processing of very large area diamond sliding bearings and tribological surfaces. The bearings and surfaces will experience...

  6. Surface concentration nonuniformities resulting from chronoamperometry of a reversible reaction at an ultramicrodisk electrode

    DEFF Research Database (Denmark)

    Britz, Dieter H.; Strutwolf, Jörg

    2016-01-01

    The chronoamperometric experiment at a disk electrode was simulated, assuming a reversible reaction. When the diffusion coefficients of the two substances involved are different, there appears a surface concentration non- uniformity in the radial direction, exhibiting a maximum effect in time...

  7. Nocturnal intermittency in surface CO2 concentrations in sub-Saharan Africa

    Science.gov (United States)

    Data obtained over four adjacent fields of differing management practices in Zimbabwe illustrate the role of atmospheric intermittency as a mechanism for transferring CO2 between the surface and the atmosphere above. At night, limited atmospheric mixing permits CO2 concentrations to increase to leve...

  8. Using ANN and EPR models to predict carbon monoxide concentrations in urban area of Tabriz

    Directory of Open Access Journals (Sweden)

    Mohammad Shakerkhatibi

    2015-09-01

    Full Text Available Background: Forecasting of air pollutants has become a popular topic of environmental research today. For this purpose, the artificial neural network (AAN technique is widely used as a reliable method for forecasting air pollutants in urban areas. On the other hand, the evolutionary polynomial regression (EPR model has recently been used as a forecasting tool in some environmental issues. In this research, we compared the ability of these models to forecast carbon monoxide (CO concentrations in the urban area of Tabriz city. Methods: The dataset of CO concentrations measured at the fixed stations operated by the East Azerbaijan Environmental Office along with meteorological data obtained from the East Azerbaijan Meteorological Bureau from March 2007 to March 2013, were used as input for the ANN and EPR models. Results: Based on the results, the performance of ANN is more reliable in comparison with EPR. Using the ANN model, the correlation coefficient values at all monitoring stations were calculated above 0.85. Conversely, the R2 values for these stations were obtained <0.41 using the EPR model. Conclusion: The EPR model could not overcome the nonlinearities of input data. However, the ANN model displayed more accurate results compared to the EPR. Hence, the ANN models are robust tools for predicting air pollutant concentrations.

  9. Experimental Measurements of Concentration Fluctuations and Scales in a Dispersing Plume in the Atmospheric Surface Layer Obtained Using a Very Fast Response Concentration Detector

    Science.gov (United States)

    2016-06-14

    VOLUME 33 Experimental Measurements of Concentration Fluctuations and Scales in a Dispersing Plume in the Atmospheric Surface Layer Obtained Using a...Very Fast Response Concentration Detector EUGENE YEE Defence Research Establishment Suffield, Medicine Hat, Alberta , Canada R. CHAN AND P. R...various concentration timescales, length scales , and microscales (e.g., Taylor microscale, correlation scale , length scale based on the spectral

  10. Volatile methyl siloxanes (VMS) concentrations in outdoor air of several Catalan urban areas

    Science.gov (United States)

    Gallego, E.; Perales, J. F.; Roca, F. J.; Guardino, X.; Gadea, E.

    2017-04-01

    Volatile methyl siloxanes (VMS) were evaluated in ten Catalan urban areas with different industrial impacts, such as petrochemical industry, electrical and mechanical equipment, metallurgical and chemical industries, municipal solid waste treatment plant and cement and food industries, during 2013-2015. 24 h samples were taken with LCMA-UPC pump samplers specially designed in our laboratory, with a flow range of 70 ml min-1. A sorbent-based sampling method, successfully developed to collect a wide-range of VOC, was used. The analysis was performed by automatic thermal desorption coupled with capillary gas chromatography/mass spectrometry detector. The presented methodology allows the evaluation of VMS together with a wide range of other VOC, increasing the number of compounds that can be determined in outdoor air quality assessment of urban areas. This aspect is especially relevant as a restriction of several VMS (D4 and D5) in consumer products has been made by the European Chemicals Agency and US EPA is evaluating to include D4 in the Toxic Substances Control Act, regarding the concern of the possible effects of these compounds in human health and the environment. ΣVMS concentrations (L2-L5, D3-D6 and trimethylsilanol) varied between 0.3 ± 0.2 μg m-3 and 18 ± 12 μg m-3, determined in a hotspot area. Observed VMS concentrations were generally of the same order of magnitude than the previously determined in Barcelona, Chicago and Zurich urban areas, but higher than the published from suburban sites and Arctic locations. Cyclic siloxanes concentrations were up to two-three orders of magnitude higher than those of linear siloxanes, accounting for average contributions to the total concentrations of 97 ± 6% for all samples except for the hotspot area, where cyclic VMS accounted for 99.9 ± 0.1%. D5 was the most abundant siloxane in 5 sampling points; however, differing from the generally observed in previous studies, D3 was the most abundant compound in the

  11. Antifoulant (butyltin and copper) concentrations in sediments from the Great Barrier Reef World Heritage Area, Australia

    International Nuclear Information System (INIS)

    Haynes, David; Loong, Dominica

    2002-01-01

    Antifoulant concentrations are generally low in the Great Barrier Reef, although ship grounding sites present a previously unidentified significant source of antifoulant pollutants in the Great Barrier Reef. - Antifoulant concentrations were determined in marine sediments collected from commercial harbours, marinas, mooring locations on mid-shelf continental islands, and outer reef sites in four regions within the Great Barrier Reef World Heritage Area in 1999. Highest copper concentrations were present in sediments collected from commercial harbour sampling sites (28-233 μg Cu g -1 dry wt.). In contrast, copper concentrations in sediments collected from boat mooring sites on mid-shelf continental islands and outer reef sites were at background concentrations (i.e. -1 dry wt.). Butyltin was only detectable in four of the 42 sediments sampled for analysis, and was only present in sediments collected from commercial harbours (18-1275 ng Sn g -1 dry wt.) and from marinas (4-5 ng Sn g -1 dry wt.). The detection of tributyltin at marina sites implies that this antifoulant may continue to be used illegally on the hulls of smaller recreational vessels. Sediment samples were also collected opportunistically from the site of a 22,000 t cargo ship grounding in May 1999 at Heath Reef, in the far northern Great Barrier Reef. Butyltin concentrations were grossly elevated (660-340,000 ng Sn g -1 dry wt.) at the grounding site. The impact of residual antifoulants at large ship grounding sites should be recognised as a significant, long-term environmental problem unless antfoulant clean-up strategies are undertaken

  12. The protection of urban areas from surface wastewater pollutions

    OpenAIRE

    Vialkova Elena; Zemlyanova Marina; Vorotnikova Anna; Cherkashin Dmitriy; Voronov Andrey; Maksimov Lev

    2017-01-01

    In this paper it considered the problem of collection, treatment and discharge into waters of rain and melted wastewater. To reduce the load on the combined sewer system, there are engineering solutions collect rain and melt water for use in the irrigation of lawns and green spaces. Research carried out at the department “Water supply and sanitation”, (Russia), confirm the high pollution concentrations of meltwater and rainfall in urban arias. Series of measurements of heavy metal in rainwate...

  13. Chemical analysis and surface morphology of enamel following ozone application with different concentrations and exposure times

    Directory of Open Access Journals (Sweden)

    Iman I. Elsayad

    2011-04-01

    Full Text Available This study aimed to determine the effect of different ozone concentrations applied with different exposure times on the chemical composition and the surface morphology of enamel. Twenty human mandibular molars were divided into four groups according to ozone concentration and exposure times. Group A received 90 μg of ozone/ml oxygen for 1 min, group B received 90 μg of ozone/ml oxygen for 2 min, group C received 120 μg of ozone/ml oxygen for 1 min and group D received 120 μg of ozone/ml oxygen for 2 min. The ozone source was from a medical ozone generator equipped with a device to adjust the concentration. Buccal surfaces of teeth were tested before and after ozone application so that each tooth served as a control for itself, using Environmental Scanning Electron Microscope (ESEM connected to an Electron Dispersive Analytical X-ray (EDAX. Changes in calcium and phosphorus percentage levels were recorded and the Ca/P ratio was calculated. The values were statistically analyzed using the one-way ANOVA test with a level of significance set at P ⩽ 0.05. No statistical significant difference was found between the control and the tested groups in minerals content or ratio as P > 0.05. ESEM images showed enamel surface roughness with 2 min ozone exposure times. High ozone concentration with prolonged exposure time does not change the chemical composition of enamel. Applying ozone for 2 min alters the surface morphology of enamel causing variable degrees of roughness. Using high ozone concentrations with prolonged exposure times for caries reversal or prevention and for bleaching may be contraindicated if this changes the surface morphology of enamel.

  14. Possibilities of surface waters monitoring at mining areas using UAV

    Science.gov (United States)

    Lisiecka, Ewa; Motyka, Barbara; Motyka, Zbigniew; Pierzchała, Łukasz; Szade, Adam

    2018-04-01

    The selected, remote measurement methods are discussed, useful for determining surface water properties using mobile unmanned aerial platforms (UAV). The possibilities of using this type of solutions in the scope of measuring spatial, physicochemical and biological parameters of both natural and anthropogenic water reservoirs, including flood polders, water-filled pits, settling tanks and mining sinks were analyzed. Methods of remote identification of the process of overgrowing this type of ecosystems with water and coastal plant formations have also been proposed.

  15. The Effect of 200 MPa Pressure on Specific Surface Area of Clay

    Directory of Open Access Journals (Sweden)

    Koszela-Marek Ewa

    2015-02-01

    Full Text Available The paper presents the results of laboratory studies of the 200 MPa pressure effect on specific surface area of clay. The original high-pressure investigation stand was used for the pressure tests. Determination of the specific surface area was performed by the methylene blue adsorption method. The results of the specific surface area test were compared for non-pressurized clays and for clays pressured in a high-pressure chamber. It was found that the specific surface area of pressurized soil clearly increased. This shows that some microstructural changes take place in the soil skeleton of clays.

  16. Estimating the surface area of birds: using the homing pigeon (Columba livia) as a model.

    Science.gov (United States)

    Perez, Cristina R; Moye, John K; Pritsos, Chris A

    2014-05-08

    Estimation of the surface area of the avian body is valuable for thermoregulation and metabolism studies as well as for assessing exposure to oil and other surface-active organic pollutants from a spill. The use of frozen carcasses for surface area estimations prevents the ability to modify the posture of the bird. The surface area of six live homing pigeons in the fully extended flight position was estimated using a noninvasive method. An equation was derived to estimate the total surface area of a pigeon based on its body weight. A pigeon's surface area in the fully extended flight position is approximately 4 times larger than the surface area of a pigeon in the perching position. The surface area of a bird is dependent on its physical position, and, therefore, the fully extended flight position exhibits the maximum area of a bird and should be considered the true surface area of a bird. © 2014. Published by The Company of Biologists Ltd | Biology Open.

  17. Comparison of diffusion charging and mobility-based methods for measurement of aerosol agglomerate surface area.

    Science.gov (United States)

    Ku, Bon Ki; Kulkarni, Pramod

    2012-05-01

    We compare different approaches to measure surface area of aerosol agglomerates. The objective was to compare field methods, such as mobility and diffusion charging based approaches, with laboratory approach, such as Brunauer, Emmett, Teller (BET) method used for bulk powder samples. To allow intercomparison of various surface area measurements, we defined 'geometric surface area' of agglomerates (assuming agglomerates are made up of ideal spheres), and compared various surface area measurements to the geometric surface area. Four different approaches for measuring surface area of agglomerate particles in the size range of 60-350 nm were compared using (i) diffusion charging-based sensors from three different manufacturers, (ii) mobility diameter of an agglomerate, (iii) mobility diameter of an agglomerate assuming a linear chain morphology with uniform primary particle size, and (iv) surface area estimation based on tandem mobility-mass measurement and microscopy. Our results indicate that the tandem mobility-mass measurement, which can be applied directly to airborne particles unlike the BET method, agrees well with the BET method. It was also shown that the three diffusion charging-based surface area measurements of silver agglomerates were similar within a factor of 2 and were lower than those obtained from the tandem mobility-mass and microscopy method by a factor of 3-10 in the size range studied. Surface area estimated using the mobility diameter depended on the structure or morphology of the agglomerate with significant underestimation at high fractal dimensions approaching 3.

  18. Activity concentrations of 239+240 Pu in sediment at Sabah and Sarawak coastal areas

    International Nuclear Information System (INIS)

    Jalal Sharib; Zaharudin Ahmad; Yii Mei Wo; Hidayah Shahar

    2009-01-01

    The coastal sediment sampling was carried out in July 2004 as part of the Marine Radioactivity Database Development Project for Malaysia. The determination of plutonium, 239+240 Pu activity concentration and their distributions along the coastal areas of Sabah and Sarawak was by the alpha spectrometry counting system. Prior to counting, the radionuclides were isolated from the samples using radiochemical separation technique and mounted on a stainless steel disc by using electro-deposition. The results show that the distribution of 239+240 Pu activity concentration in coastal sediment is consistent, ranging from BDL - 1.83 Bq/kg and 0.11 - 0.84 Bq/kg dry weight, respectively. Lubok Sabanan, SB 15, in Sabah and Sungai Similajau, SR 13, in Sarawak were sampling stations that gave highest 239+240 Pu activity concentration. Overall, the 239+240 Pu activity concentration of Sabah and Sarawak are slightly higher in comparison the West Coast coastal stations of Peninsular Malaysia, and can be used as database. (Author)

  19. Characteristics of hazardous airborne dust around an Indian surface coal mining area.

    Science.gov (United States)

    Ghose, Mrinal K; Majee, S R

    2007-07-01

    Surface coal mining creates more air pollution problems with respect to dust than underground mining . An investigation was conducted to evaluate the characteristics of the airborne dust created by surface coal mining in the Jharia Coalfield. Work zone air quality monitoring was conducted at six locations, and ambient air quality monitoring was conducted at five locations, for a period of 1 year. Total suspended particulate matter (TSP) concentration was found to be as high as 3,723 microg/m(3), respirable particulate matter (PM10) 780 microg/m(3), and benzene soluble matter was up to 32% in TSP in work zone air. In ambient air, the average maximum level of TSP was 837 microg/m(3), PM10 170 microg/m(3) and benzene soluble matter was up to 30%. Particle size analysis of TSP revealed that they were more respirable in nature and the median diameter was around 20 microm. Work zone air was found to have higher levels of TSP, PM10 and benzene soluble materials than ambient air. Variations in weight percentages for different size particles are discussed on the basis of mining activities. Anionic concentration in TSP was also determined. This paper concludes that more stringent air quality standards should be adopted for coal mining areas and due consideration should be given on particle size distribution of the air-borne dust while designing control equipment.

  20. Assessment of large aperture scintillometry for large-area surface ...

    Indian Academy of Sciences (India)

    29

    This study defines that large aperture scintillometer is robust instrument which can evaluate energy flux over a large area with a long term series time domain. Moreover, further studied should be conducted to use in crop simulation modelling, developing of new model with calibration and validation of remote sensing energy ...

  1. Radon concentrations inside public and commercial buildings in the Pittsburgh area.

    Science.gov (United States)

    Cohen, B L; Kulwicki, D R; Warner, K R; Grassi, C L

    1984-09-01

    Radon concentrations in ambient air from numerous schools, stores and other public and commercial buildings in the Pittsburgh, PA, area were measured by grab sampling. This is more appropriate than using long-term integrating monitors because of the correlation between times of occupancy and Rn levels. Results indicate that Rn concentrations in these buildings are nearly an order of magnitude less than in homes, and not much higher than outdoors. Variations among sites is also much less than for homes, probably because there is less variability in ventilation and building maintenance practices. Colleges and universities have somewhat higher Rn levels and a larger degree of variability than commercial buildings or hospitals. There was no indication of higher Rn levels in cold weather than in warm weather, or of correlations with the age of the building.

  2. Heavy metals concentration in soils from parks and green areas in Belgrade

    Directory of Open Access Journals (Sweden)

    MIRJANA D. MARJANOVIĆ

    2009-06-01

    Full Text Available The current study included the investigation of several metals and their distribution in urban soils from parks and green areas in the city of Belgrade. The soils were sampled in January and February 2008. The concentrations of Cd, Co, Cu, Pb, Mn and Zn were measured, as well as the pH values and organic matter contents. The obtained results showed that there was a significant level of contamination in some samples, especially with lead, and that it was most probably caused by anthropogenic activities, mostly from traffic. The results were compared with the National legislation and Netherlands standards. Also, the recent results were compared with the data from previous work and it was concluded that there has been a certain increase of the Pb concentration in the past three years. The level of pollution in playground soil was very high and each analyzed sample exceeded the Dutch target value for Cd, Co and Pb.

  3. Concentrations of radiocesium and stable elements in different parts of pine tree collected in Chernobyl area

    International Nuclear Information System (INIS)

    Yoshida, Satoshi; Watanabe, Masumi; Suzuki, Akira; Linkov, Igor; Dvornik, Alexander; Zhuchenko, Tatiana

    2007-01-01

    Radial distributions of 137 Cs and related stable elements in a pine tree collected in Chernobyl contaminated area in Belarus were determined, in order to get basic information for dose estimation of pine tree. The concentration of 137 Cs in annual tree rings was the highest in cambium, and decreased sharply toward inside. The highest concentration of 137 Cs in cambium suggests the highest radiation dose to growing part of wood. Distribution of stable Cs was similar as that of 137 Cs, and the 137 Cs/stable Cs ratio was almost constant, indicating the equilibrium of Chernobyl 137 Cs with stable Cs in the pine wood. The similar distributions as Cs were observed for K and Rb. (author)

  4. Groundwater impacts on surface water quality and nutrient loads in lowland polder catchments: monitoring the greater Amsterdam area

    Science.gov (United States)

    Yu, Liang; Rozemeijer, Joachim; van Breukelen, Boris M.; Ouboter, Maarten; van der Vlugt, Corné; Broers, Hans Peter

    2018-01-01

    The Amsterdam area, a highly manipulated delta area formed by polders and reclaimed lakes, struggles with high nutrient levels in its surface water system. The polders receive spatially and temporally variable amounts of water and nutrients via surface runoff, groundwater seepage, sewer leakage, and via water inlets from upstream polders. Diffuse anthropogenic sources, such as manure and fertiliser use and atmospheric deposition, add to the water quality problems in the polders. The major nutrient sources and pathways have not yet been clarified due to the complex hydrological system in lowland catchments with both urban and agricultural areas. In this study, the spatial variability of the groundwater seepage impact was identified by exploiting the dense groundwater and surface water monitoring networks in Amsterdam and its surrounding polders. A total of 25 variables (concentrations of total nitrogen (TN), total phosphorus (TP), NH4, NO3, HCO3, SO4, Ca, and Cl in surface water and groundwater, N and P agricultural inputs, seepage rate, elevation, land-use, and soil type) for 144 polders were analysed statistically and interpreted in relation to sources, transport mechanisms, and pathways. The results imply that groundwater is a large source of nutrients in the greater Amsterdam mixed urban-agricultural catchments. The groundwater nutrient concentrations exceeded the surface water environmental quality standards (EQSs) in 93 % of the polders for TP and in 91 % for TN. Groundwater outflow into the polders thus adds to nutrient levels in the surface water. High correlations (R2 up to 0.88) between solutes in groundwater and surface water, together with the close similarities in their spatial patterns, confirmed the large impact of groundwater on surface water chemistry, especially in the polders that have high seepage rates. Our analysis indicates that the elevated nutrient and bicarbonate concentrations in the groundwater seepage originate from the decomposition of

  5. Groundwater impacts on surface water quality and nutrient loads in lowland polder catchments: monitoring the greater Amsterdam area

    Directory of Open Access Journals (Sweden)

    L. Yu

    2018-01-01

    Full Text Available The Amsterdam area, a highly manipulated delta area formed by polders and reclaimed lakes, struggles with high nutrient levels in its surface water system. The polders receive spatially and temporally variable amounts of water and nutrients via surface runoff, groundwater seepage, sewer leakage, and via water inlets from upstream polders. Diffuse anthropogenic sources, such as manure and fertiliser use and atmospheric deposition, add to the water quality problems in the polders. The major nutrient sources and pathways have not yet been clarified due to the complex hydrological system in lowland catchments with both urban and agricultural areas. In this study, the spatial variability of the groundwater seepage impact was identified by exploiting the dense groundwater and surface water monitoring networks in Amsterdam and its surrounding polders. A total of 25 variables (concentrations of total nitrogen (TN, total phosphorus (TP, NH4, NO3, HCO3, SO4, Ca, and Cl in surface water and groundwater, N and P agricultural inputs, seepage rate, elevation, land-use, and soil type for 144 polders were analysed statistically and interpreted in relation to sources, transport mechanisms, and pathways. The results imply that groundwater is a large source of nutrients in the greater Amsterdam mixed urban–agricultural catchments. The groundwater nutrient concentrations exceeded the surface water environmental quality standards (EQSs in 93 % of the polders for TP and in 91 % for TN. Groundwater outflow into the polders thus adds to nutrient levels in the surface water. High correlations (R2 up to 0.88 between solutes in groundwater and surface water, together with the close similarities in their spatial patterns, confirmed the large impact of groundwater on surface water chemistry, especially in the polders that have high seepage rates. Our analysis indicates that the elevated nutrient and bicarbonate concentrations in the groundwater seepage originate

  6. Concentrations and geographic distribution of selected organic pollutants in Scottish surface soils

    International Nuclear Information System (INIS)

    Rhind, S.M.; Kyle, C.E.; Kerr, C.; Osprey, M.; Zhang, Z.L.; Duff, E.I.; Lilly, A.; Nolan, A.; Hudson, G.; Towers, W.; Bell, J.; Coull, M.; McKenzie, C.

    2013-01-01

    Concentrations of selected persistent organic pollutants (POPs) representing three chemical classes (polycyclic aromatic hydrocarbons (PAH), polybrominated diphenyl ethers (PBDE) and polychlorinated biphenyls (PCB) and the organic pollutant diethylhexyl phthalate (DEHP), were determined in surface soil samples (0–5 cm) collected at 20 km grid intersects throughout Scotland over a three-year period. Detectable amounts of all chemical classes and most individual congeners were present in all samples. There were no consistent effects of soil or vegetation type, soil carbon content, pH, altitude or distance from centres of population on concentrations which exhibited extreme variation, even in adjacent samples. It is concluded that soil POPs and DEHP concentrations and associated rates of animal and human exposure were highly variable, influenced by multiple, interacting factors, and not clearly related to local sources but possibly related to wet atmospheric deposition and the organic carbon content of the soil. -- Highlights: •Concentrations of selected organic pollutants in Scottish soils were determined. •Concentrations were highly variable. •There were few effects of soil or vegetation type, soil carbon, pH or altitude. •Distance from cities was not an important determinant of concentrations. •Atmospheric deposition and soil organic carbon content may affect concentrations. -- Soil concentrations of anthropogenic persistent organic pollutants are not clearly related to soil type or pH, vegetation, altitude, or distance from pollutant sources

  7. Effect of temperature and concentration on the surface tension of chia seed mucilage

    Science.gov (United States)

    Fu, Yuting; Arye, Gilboa

    2017-04-01

    The production of mucilage by the seed coat during hydration is a common adaptation of many different plant species. The mucilage may play many ecological roles in adaptation and seed germination in diverse environments, especially in extreme desert conditions. The major compound of the seed mucilage is polysaccharides (e.g. pectins and hemicelluloses), which makes it highly hydrophilic. Consequently, it can hydrate quickly in the presence of water; forming a gel like coating surrounding the seed. However, the seed mucilage also reported to contain small amounts of protein and lipid which may exhibit surface activity at the water-air interface. As a result, decay in the surface tension of water can be occur and consequently a reduction in soil capillary pressure. This in turn may affect the water retention and transport during seed germination. The physical properties of the seeds mucilage have been studied mainly in conjunction with its rheological properties. To the best of our knowledge, its surface activity at the water-air interface has been reported mainly in the realms of food engineering, using a robust method of extraction. The main objective of this study was to quantify the effect of temperature and concentration on the surface tension of seed mucilage. The mucilage in this study was extracted from chia (Salvia hispanica L.) seeds, using distilled water (1:20 w/w) by shaking for 12 h at 4°C. The extracts were freeze dried after centrifuge (5000rpm for 20min). Fresh samples of different concentrations, ranging from 0.5 to 6 mg/ml, were prepared before each surface tension measurements. The equilibrium surface tension was measured by the Wilhelmy plate method using a tensiometer (DCAT 11, Data Physics) with temperature control unit. For a given mucilage concentration, surface tension measurements carried out at 5, 15, 25, 35, 45 °C. The quantitative and thermodynamic analysis of the results will be presented and discussed.

  8. Differences in surface roughness of nanohybrid composites immersed in varying concentrations of citric acid

    Directory of Open Access Journals (Sweden)

    Gabriela Kevina Alifen

    2017-06-01

    Full Text Available Background: The surface roughness of restoration is important in predicting the length of time it might remain in the mouth. Conditions within the oral cavity can affect the surface roughness of a restoration. Nanohybrid composite is widely used in dentistry because it can be applied to restore anterior and posterior teeth. Athletes routinely consume isotonic drinks which are acidic and even more erosive than the carbonated variety because they contain a range of acids; the highest content of which being citric acid. Purpose: The aim of the study was to analyze the surface roughness of nanohybrid composite after having been subjected to immersion in varying concentrations of citric acid. Methods: Two isotonic drinks (Pocari Sweat and Mizone were analyzed using high performance liquid chromatography (HPLC to quantify the respective concentrations of citric acid which they contained. A total of 27 samples of cylindrical nanohybrid composite were prepared before being divided into three groups. In Group 1, samples were immersed in citric acid solution derived from Pocari Sweat. Those of Group 2 were immersed in citric acid solution derived from Mizone; while Group 3, samples were immersed in distilled water as a control. All samples were immersed for 7 days, before their surface roughness was tested by means of a surface roughness tester (Mitutoyo SJ-201. Data was analyzed using a one-way ANOVA test. Results: The results showed that there was no significant difference in surface roughness between Groups 1, 2 and 3 (p=0.985. Conclusion: No difference in surface roughness of nanohybrid composites results from prolonged immersion in varying concentrations of citric acid.

  9. Experimental determination and modelling of interface area concentration in horizontal stratified flow

    International Nuclear Information System (INIS)

    Junqua-Moullet, Alexandra

    2003-01-01

    This research thesis concerns the modelling and experimentation of biphasic liquid/gas flows (water/air) while using the two-fluid model, a six-equation model. The author first addresses the modelling of interfacial magnitudes for a known topology (problem of two-fluid model closure, closure relationships for some variables, equation for a given configuration). She reports the development of an equation system for interfacial magnitudes. The next parts deal with experiments and report the study of stratified flows in the THALC experiment, and more particularly the study of the interfacial area concentration and of the liquid velocities in such flows. Results are discussed, as well as their consistency

  10. Cacao roasting in rural areas of Peru using concentrated solar thermal energy: experimental results

    Directory of Open Access Journals (Sweden)

    Veynandt François

    2016-01-01

    Full Text Available Solar food processing is gaining interest for income generation. Our solar cacao roaster, designed for rural areas, consists in a horizontal rotating drum, opened at one end to collect solar radiation from Scheffler concentrators of 2.7 or 8 m2. The experimental results presented bring knowledge on the system's behavior and optimal operation. The influence of the most significant parameters is studied: quantity of cacao, absorptivity of drum's coating, thermal insulation, inclination and rotational speed of the drum. Cacao temperature and direct solar irradiance are monitored to evaluate the performance in roasting time per kilogram of cacao.

  11. Siloxanes removal from biogas by high surface area adsorbents.

    Science.gov (United States)

    Gislon, P; Galli, S; Monteleone, G

    2013-12-01

    Biogas utilized for energy production needs to be free from organic silicon compounds, as their burning has damaging effects on turbines and engines; organic silicon compounds in the form of siloxanes can be found in biogas produced from urban wastes, due to their massive industrial use in synthetic product, such as cosmetics, detergents and paints. Siloxanes removal from biogas can be carried out by various methods (Mona, 2009; Ajhar et al., 2010 May; Schweigkofler and Niessner, 2001); aim of the present work is to find a single practical and economic way to drastically and simultaneously reduce both the hydrogen sulphide and the siloxanes concentration to less than 1 ppm. Some commercial activated carbons previously selected (Monteleone et al., 2011) as being effective in hydrogen sulfide up taking have been tested in an adsorption measurement apparatus, by flowing the most volatile siloxane (hexamethyldisiloxane or L2) in a nitrogen stream, typically 100-200 ppm L2 over N2, through an activated carbon powder bed; the adsorption process was analyzed by varying some experimental parameters (concentration, grain size, bed height). The best activated carbon shows an adsorption capacity of 0.1g L2 per gram of carbon. The next thermogravimetric analysis (TGA) confirms the capacity data obtained experimentally by the breakthrough curve tests. The capacity results depend on L2 concentration. A regenerative carbon process is then carried out by heating the carbon bed up to 200 °C and flushing out the adsorbed L2 samples in a nitrogen stream in a three step heating procedure up to 200 °C. The adsorption capacity is observed to degrade after cycling the samples through several adsorption-desorption cycles. Copyright © 2013 Elsevier Ltd. All rights reserved.

  12. Tritium in Precipitation, Surface and Groundwaters in the Zagreb Area

    International Nuclear Information System (INIS)

    Horvatincic, N.; Baresic, J.; Sironic, A.; Krajcar Bronic, I.; Obelic, B.

    2011-01-01

    Radioactive isotope tritium (3H) and stable isotopes of hydrogen (2H/1H) and oxygen (18O/16O) were measured in Sava River, precipitation and groundwater at 3 monitoring wells (piezometers) and 1 production well of the Petrusevec aquifer, close to the Sava River. Samples were collected monthly during 2010. The investigation is included in the Regional IAEA Project RER/8/016 Using Environmental Isotopes for Evaluation of Streamwater/Groundwater Interactions in Selected Aquifers in the Danube Basin. Sava River is a tributary of Danube River and the aim of the investigation is to determine the influence of surface stream of Sava River to the groundwater of aquifer used for water exploitation. In this work only 3H results were presented. 3H was measured by liquid scintillation counter Quantulus 1220, using electrolytic enrichment for all samples. 3H activity in precipitation showed slight seasonal fluctuation between 4 TU and 14 TU, with higher values in summer. 3H activity of Sava River and groundwater of the Petrusevec aquifer followed 3H of precipitation till May 2010. Significant increase of 3H in Sava River was observed in June, (199 @ 20) TU, and in the next month it fell down at 6 TU. Increase of 3H was also observed in groundwater but with damped response (maximum 60 TU) and with delay of 2 - 3 months related to Sava River. Different response of different piezometers and the well indicated the different infiltration times of surface water of Sava River to groundwater of the Petrusevec aquifer. The increased 3H activity in surface and groundwaters was caused by release of tritiated water from the Krsko Nuclear Power Plant, 30 km upstream from Zagreb. The results of 3H, 2H/1H and 18O/16O measurements will be used to determine the infiltration time of groundwater of the Petrusevec aquifer using conceptual and mathematical models. (author)

  13. Remaining Sites Verification Package for the 100-B-1 Surface Chemical and Solid Waste Dumping Area, Waste Site Reclassification Form 2006-003

    Energy Technology Data Exchange (ETDEWEB)

    R. A. Carlson

    2006-04-24

    The 100-B-1 waste site was a dumping site that was divided into two areas. One area was used as a laydown area for construction materials, and the other area was used as a chemical dumping area. The 100-B-1 Surface Chemical and Solid Waste Dumping Area site meets the remedial action objectives specified in the Remaining Sites ROD. The results demonstrate that residual contaminant concentrations support future unrestricted land uses that can be represented by a rural-residential scenario. The results also demonstrate that residual contaminant concentrations are protective of groundwater and the Columbia River.

  14. Spatial distribution of the electrical potential and ion concentration in the downstream area of atmospheric pressure remote plasma

    Directory of Open Access Journals (Sweden)

    M. V. Mishin

    2014-10-01

    Full Text Available This paper presents the results from an experimental study of the ion flux characteristics behind the remote plasma zone in a vertical tube reaction chamber for atmospheric pressure plasma enhanced chemical vapor deposition. Capacitively coupled radio frequency plasma was generated in pure He and gas mixtures: He–Ar, He–O2, He–TEOS. We previously used the reaction system He–TEOS for the synthesis of self-assembled structures of silicon dioxide nanoparticles. It is likely that the electrical parameters of the area, where nanoparticles have been transported from the synthesis zone to the substrate, play a significant role in the self-organization processes both in the vapor phase and on the substrate surface. The results from the spatial distribution of the electrical potential and ion concentration in the discharge downstream area measured by means of the external probe of original design and the special data processing method are demonstrated in this work. Positive and negatives ions with maximum concentrations of 106–107 cm−3 have been found at 10–80 mm distance behind the plasma zone. On the basis of the revealed distributions for different gas mixtures, the physical model of the observed phenomena is proposed. The model illustrates the capability of the virtual ion emitter formation behind the discharge gap and the presence of an extremum of the electrical potential at the distance of approximately 10−2–10−1 mm from the grounded electrode.

  15. Concentration of 210Po in local foodstuffs grown nearby High Background Areas (HBRA)

    International Nuclear Information System (INIS)

    Kamesh Viswanathan, B.; Arunachalam, Kantha D.; Sathesh Kumar, A.; Jayakrishna, K.; Rao, D.D.

    2012-01-01

    210 Po is the decay product of natural radionuclide of 238 U series. The presence of a radionuclide migrates from soil > plant > food and ingested by the humans residing in the areas of syentite rocks nearby the High Background Radiation Area's (HBRA). The food samples were studied by Market Basket Study (MBS). The average concentration of 210 Po in foodstuffs like green leafy vegetables, other vegetables, roots and tubers; fruits, fish, other flesh foods, milk and cereals were 1671 ± 163.3, 28.2 ± 7.3, 320 ± 99, 53 ± 17.5, 251.5 ± 54.5, 37 ± 14.5, 16 ± 6 and 230 ± 75 mBq. Kg -1 fresh weight. (author)

  16. Muscle conduction velocity, surface electromyography variables, and echo intensity during concentric and eccentric fatigue.

    Science.gov (United States)

    Gonzalez-Izal, Miriam; Lusa Cadore, Eduardo; Izquierdo, Mikel

    2014-03-01

    Concentric (CON) and eccentric (ECC) contractions may involve different mechanisms related to changes in sarcolemma status and the consequent alteration of action potential transmission along muscle fibers. Muscle conduction velocity (CV), surface electromyography signal (sEMG), muscle quality, and blood lactate concentrations were analyzed during CON and ECC actions. Compared with ECC, the CON protocol resulted in greater muscle force losses, blood lactate concentrations, and changes in sEMG parameters. Similar reductions in CV were detected in both protocols. Higher echo intensity values were observed 2 days after ECC due to greater muscle damage. The effects of the muscle damage produced by ECC exercise on the transmission of action potentials along muscle fibers (measured as the CV) may be comparable with the effects of hydrogen accumulation produced by CON exercise (related to greater lactate concentrations), which causes greater force loss and change in other sEMG variables during CON than during ECC actions.

  17. Biochar-based constructed wetlands to treat reverse osmosis rejected concentrates in chronic kidney disease endemic areas in Sri Lanka.

    Science.gov (United States)

    Athapattu, B C L; Thalgaspitiya, T W L R; Yasaratne, U L S; Vithanage, Meththika

    2017-12-01

    The objectives were to investigate the potential remedial measures for reverse osmosis (RO) rejected water through constructed wetlands (CWs) with low-cost materials in the media established in chronic kidney disease of unknown etiology (CKDu) prevalent area in Sri Lanka. A pilot-scale surface and subsurface water CWs were established at the Medawachchiya community-based RO water supply unit. Locally available soil, calicut tile and biochar were used in proportions of 81, 16.5 and 2.5% (w/w), respectively, as filter materials in the subsurface. Vetiver grass and Scirpus grossus were selected for subsurface wetland while water lettuce and water hyacinth were chosen for free water surface CWs. Results showed that the CKDu sensitive parameters; total dissolved solids, hardness, total alkalinity and fluoride were reduced considerably (20-85%) and most met desirable levels of stipulated ambient standards. Biochar seemed to play a major role in removing fluoride from the system which may be due to the existing and adsorbed K + , Ca +2 , Mg +2 , etc. on the biochar surface via chemisorption. The least reduction was observed for alkalinity. This study indicated potential purification of aforesaid ions in water which are considerably present in RO rejection. Therefore, the invented bio-geo constructed wetland can be considered as a sustainable, economical and effective option for reducing high concentrations of CKDu sensitive parameters in RO rejected water before discharging into the inland waters.

  18. Experimental Study on the Microstructure Evolution of Mixed Disposal Paste in Surface Subsidence Areas

    Directory of Open Access Journals (Sweden)

    Wei Sun

    2016-05-01

    Full Text Available The integrated disposal of surface subsidence pits and surface solid waste can be realized by backfilling a surface subsidence area with a paste made from the solid wastes of mines, such as tailings and waste rock. The microstructures of these wastes determine the macroscopic properties of a paste backfill. This paper presents an experimental study on the internal structure evolution of pasty fluid mixed with different waste rock concentrations (10%, 30%, and 50% and cement dosages (1% and 2% under damage. To this end, a real-time computed tomography (CT scan is conducted using medical CT and a small loading device. Results show that UCS (uniaxial compressive strength increases when the amount of cement increases. Given a constant amount of cement, UCS increases first and then decreases as waste rock content increases. UCS is maximized at 551 kPa when the waste rock content is 30%. The paste body is a typical medium used to investigate initial damage, which mainly consists of microholes, pores, and microcracks. The initial damages also exhibit a high degree of random inhomogeneity. After loading, cracks are initiated and expand gradually from the original damage location until the overall damages are generated. The mesostructure evolution model of the paste body is divided into six categories, and this mesostructure is reasonable when the waste rock content is 30%.

  19. Data on the role of accessible surface area on osmolytes-induced protein stabilization

    Directory of Open Access Journals (Sweden)

    Safikur Rahman

    2017-02-01

    Full Text Available This paper describes data related to the research article “Testing the dependence of stabilizing effect of osmolytes on the fractional increase in the accessible surface area on thermal and chemical denaturations of proteins” [1]. Heat- and guanidinium chloride (GdmCl-induced denaturation of three disulfide free proteins (bovine cytochrome c (b-cyt-c, myoglobin (Mb and barstar in the presence of different concentrations of methylamines (sarcosine, glycine-betaine (GB and trimethylamine-N-oxide (TMAO was monitored by [ϴ]222, the mean residue ellipticity at 222 nm at pH 7.0. Methylamines belong to a class of osmolytes known to protect proteins from deleterious effect of urea. This paper includes comprehensive thermodynamic data obtained from the heat- and GdmCl-induced denaturations of barstar, b-cyt-c and Mb.

  20. Response of three instruments devoted to surface-area for monodisperse and polydisperse aerosols in molecular and transition regimes

    Energy Technology Data Exchange (ETDEWEB)

    Bau, Sebastien; Witschger, Olivier [Institut National de Recherche et de Securite (INRS), Laboratoire de Metrologie des Aerosols, Rue du Morvan, CS 60027, 54519 Vandoeuvre Cedex (France); Gensdarmes, Francois [Institut de Radioprotection et de Surete Nucleaire (IRSN), Laboratoire de Physique et de Metrologie des Aerosols, BP 68, 91192 Gif-sur-Yvette (France); Thomas, Dominique, E-mail: sebastien.bau@inrs.fr [Laboratoire Reactions et Genie des Procedes (LRGP), groupe SAFE, 1 rue Grandville, BP 20041, 54001 Nancy Cedex (France)

    2011-07-06

    An increasing number of experimental and theoretical studies focus on airborne nanoparticles (NP) in relation with many aspects of risk assessment. Indeed, our understanding of the hazards, the actual exposures in the workplace and the limits of engineering controls and personal protective equipment with regard to NP are still under development. Several studies have already identified surface-area as an important determinant of low solubility nanoparticles toxicity. As a consequence, the concept that surface-area could be a relevant metric for characterizing exposure to low solubility airborne NP has been proposed [1]. To provide NP surface-area concentration, some direct-reading instruments have been designed, based on diffusion charging. The actual available instruments providing airborne NP surface-area concentration are studied in this work: LQ1-DC (Matter Engineering), AeroTrak{sup TM} 9000 (TSI) and NSAM (TSI model 3550). Their performances regarding monodisperse carbon NP have been investigated by Bau et al.. This work aims at completing the instruments characterization regarding monodisperse NP of other chemical composition (aluminium, copper, silver) and studying their performances against polydisperse aerosols of NP.

  1. Assessing surface water quality and its relation with urban land cover changes in the Lake Calumet area, Greater Chicago.

    Science.gov (United States)

    Wilson, Cyril; Weng, Qihao

    2010-05-01

    Urban land use and land cover change significantly affect spatial and temporal patterns of runoff, which in turn impacts surface water quality. With the exponential growth in urban areas over the past three decades, changes in land use and land cover to cater for the growth of cities has been a conspicuous spectacle in urban spaces. The main goal of this study was to assess the impacts of land cover change on runoff and surface water quality using a partial area hydrology framework. The study employed ArcHydro GIS extension and a modified version of Long-Term Hydrologic and Nonpoint Source Pollution model (L-THIA-NPS) in estimating runoff and nonpoint source pollutant concentration around Lake Calumet between 1992 and 2001. Data employed include National Land Cover Data set, rainfall data, digital elevation model (DEM), Soil Survey Geographic (SSURGO) data, and The United States Environmental Protection Agency's STORET (storage and retrieval) water quality data. The model was able to predict surface water quality reasonably well over the study period. Sensitivity analysis facilitated a manual calibration of the model. Model validation was executed by comparing simulated results following calibration and observed water quality data for the study area. The study demonstrates that the level of concentration of nonpoint source pollutants in surface water within an urban watershed heavily depends on the spatiotemporal variations in areas that contribute towards runoff compared to the spatial extent of change in major land use/land cover.

  2. Response of three instruments devoted to surface-area for monodisperse and polydisperse aerosols in molecular and transition regimes

    International Nuclear Information System (INIS)

    Bau, Sebastien; Witschger, Olivier; Gensdarmes, Francois; Thomas, Dominique

    2011-01-01

    An increasing number of experimental and theoretical studies focus on airborne nanoparticles (NP) in relation with many aspects of risk assessment. Indeed, our understanding of the hazards, the actual exposures in the workplace and the limits of engineering controls and personal protective equipment with regard to NP are still under development. Several studies have already identified surface-area as an important determinant of low solubility nanoparticles toxicity. As a consequence, the concept that surface-area could be a relevant metric for characterizing exposure to low solubility airborne NP has been proposed [1]. To provide NP surface-area concentration, some direct-reading instruments have been designed, based on diffusion charging. The actual available instruments providing airborne NP surface-area concentration are studied in this work: LQ1-DC (Matter Engineering), AeroTrak T M 9000 (TSI) and NSAM (TSI model 3550). Their performances regarding monodisperse carbon NP have been investigated by Bau et al.. This work aims at completing the instruments characterization regarding monodisperse NP of other chemical composition (aluminium, copper, silver) and studying their performances against polydisperse aerosols of NP.

  3. Modification of sea surface temperature by chlorophyll concentration in the Atlantic upwelling systems

    Science.gov (United States)

    Hernandez, O.; Jouanno, J.; Echevin, V.; Aumont, O.

    2017-07-01

    The influence of the chlorophyll on the upper Tropical Atlantic Ocean is investigated with long-term (1979-2012) regional oceanic simulations with 1/4° horizontal resolution based on the NEMO3.6 model. The model solar radiation penetration scheme depends on the chlorophyll concentration. Simulations with time and spatially varying concentrations obtained from satellite ocean color observations are compared with a simulation forced with constant chlorophyll concentration of 0.05 mg m-3, representative of chlorophyll depleted waters. Results indicate that regions of the Tropical Atlantic with chlorophyll concentrations larger than in the reference simulation (i.e., [chl] > 0.05 mg m-3) get warmer at the surface, with the exception of the main upwelling regions where high chlorophyll concentrations are associated with a significant cooling of the sea surface (˜1°C in the Benguela upwelling). The analysis of the model heat balance shows that the biological differential heating causes negative temperature anomalies in subsurface source waters prior to their upwelling at the coast. The shallow mixed-layer in the eastern equatorial and tropical Atlantic favors the persistence of these subsurface anomalies and may explain why the Benguela is particularly sensitive to the biological differential heating. In spite of the presence of high chlorophyll concentrations in the upwelling regions, both the larger amount of shortwave radiation captured in the surface layers and the modifications of the horizontal and vertical advection at the coast are found to play a secondary role in the SST change in the upwelling region.

  4. Large area optical mapping of surface contact angle.

    Science.gov (United States)

    Dutra, Guilherme; Canning, John; Padden, Whayne; Martelli, Cicero; Dligatch, Svetlana

    2017-09-04

    Top-down contact angle measurements have been validated and confirmed to be as good if not more reliable than side-based measurements. A range of samples, including industrially relevant materials for roofing and printing, has been compared. Using the top-down approach, mapping in both 1-D and 2-D has been demonstrated. The method was applied to study the change in contact angle as a function of change in silver (Ag) nanoparticle size controlled by thermal evaporation. Large area mapping reveals good uniformity for commercial Aspen paper coated with black laser printer ink. A demonstration of the forensic and chemical analysis potential in 2-D is shown by uncovering the hidden CsF initials made with mineral oil on the coated Aspen paper. The method promises to revolutionize nanoscale characterization and industrial monitoring as well as chemical analyses by allowing rapid contact angle measurements over large areas or large numbers of samples in ways and times that have not been possible before.

  5. Limited sampling strategy for determining metformin area under the plasma concentration-time curve

    DEFF Research Database (Denmark)

    Santoro, Ana Beatriz; Stage, Tore Bjerregaard; Struchiner, Claudio José

    2016-01-01

    AIM: The aim was to develop and validate limited sampling strategy (LSS) models to predict the area under the plasma concentration-time curve (AUC) for metformin. METHODS: Metformin plasma concentrations (n = 627) at 0-24 h after a single 500 mg dose were used for LSS development, based on all...... subsets linear regression analysis. The LSS-derived AUC(0,24 h) was compared with the parameter 'best estimate' obtained by non-compartmental analysis using all plasma concentration data points. Correlation between the LSS-derived and the best estimated AUC(0,24 h) (r(2) ), bias and precision of the LSS.......9-7.7%. The accuracy of the two point LSS model was verified in study cohorts of individuals receiving single 500 or 1000 mg (r(2) = -0.933-0.934) or seven 1000 mg daily doses (r(2) = 0.918), as well as using data from 16 published studies covering a wide range of metformin doses, demographics, clinical...

  6. Trace element concentrations in wild mussels from the coastal area of the southeastern Adriatic, Montenegro

    Directory of Open Access Journals (Sweden)

    Markovic Jelena

    2012-01-01

    Full Text Available The aim of the present investigation was to quantify the levels of trace elements (Zn, Cu, As, Pb, Cd and total Hg in the Mediterranean mussel, Mytilus galloprovincialis (L.. Based on their levels, the quality of Montenegro seawater for future mussel farming was estimated. The mussel M. galloprovincialis (L. was collected from four sites in the Montenegrin costal area in the period of two years to determine trace element concentrations and to classify the quality of the coastal water and possible health risks from its consumption. The mean metal concentrations in the mussels ranged from 133.5-205.9 for Zn, 7.50-14.5 for Cu, 4.42-13.3 for As, 4.70-12.9 for Pb, 1.73-2.41 for Cd and 0.07-0.59 for total Hg in mg/kg dry weight. The levels of toxic metals (except for Pb in the mussels were within the maximum residual levels prescribed by the laws of Montenegro, the EU and the USFDA. In addition, the trace metal concentrations found in the mussels in this study were similar to regional data using this mussel as a biomonitoring agent of seawater quality.

  7. Measurements of indoor radon concentrations in the Santiago de Compostela area

    Energy Technology Data Exchange (ETDEWEB)

    Cortina, D.; Duran, I. [Departamento de Fisica de Particulas, Grupo Experimental de Nucleos y Particulas (GENP), Universidad de Santiago de Compostela, 15782 Santiago de Compostela (Spain); Llerena, J.J. [Departamento de Fisica de Particulas, Grupo Experimental de Nucleos y Particulas (GENP), Universidad de Santiago de Compostela, 15782 Santiago de Compostela (Spain)], E-mail: jjllerena@usc.es

    2008-10-15

    Galician soils are among those with the highest {sup 222}Rn exhalation rates in Spain. A year-round study of the indoor {sup 222}Rn concentration in buildings in the Santiago de Compostela area (Galicia, Northwest of Spain) was performed. The study is based on systematic samplings with active charcoal canisters, following a modified EPA 520/5-87-005 protocol. These measurements were complemented by others obtained using etched track dosimeters. Each data set follows a log-normal distribution, with a geometric mean of (253 {+-} 3) Bq m{sup -3} for charcoal canisters and (285 {+-} 2.5) Bq m{sup -3} for etched track detectors. After correcting for the different measuring conditions, the mean value of both methods differed by only 2%. A careful analysis of the seasonal dependence of our measurements did not reveal any significant seasonal variations in the {sup 222}Rn concentration. Parallel to these measurements, different meteorological parameters were recorded, which revealed a direct correlation between the indoor radon concentration and the outdoor temperature derivative with respect to time.

  8. BLM National Surface Management Agency: Area Polygons, Withdrawal Area Polygons, and Special Public Purpose Withdrawal Area Polygons

    Data.gov (United States)

    Federal Geographic Data Committee — The SMA implementation is comprised of one feature dataset, with several polygon feature classes, rather than a single feature class. SurfaceManagementAgency: The...

  9. Dissolved methane concentrations in the water column and surface sediments of Hanna Shoal and Barrow Canyon, Northern Chukchi Sea

    Science.gov (United States)

    Lapham, Laura; Marshall, Kathleen; Magen, Cédric; Lyubchich, Viacheslav; Cooper, Lee W.; Grebmeier, Jacqueline M.

    2017-10-01

    Current estimates of methane (CH4) flux suggest that Arctic shelves may be a significant source of atmospheric CH4, a potent greenhouse gas. However, little information is known about the CH4 flux from most Arctic shelves, other than the East Siberian Arctic Shelf. We report here dissolved CH4 concentrations in the water column and within surface sediments of the Northern Chukchi Sea. We hypothesized that this area contains high concentrations of CH4 because it receives nutrient rich waters through the Bering Strait, promoting primary production that enhances an organic-rich material flux to the seafloor and eventual microbial methanogenesis in the sediments. In August 2012, as part of the Chukchi Sea Offshore Monitoring in Drilling Area (COMIDA) project, fourteen stations were sampled on Hanna Shoal, a shallow feature on the shelf, and ten stations across the undersea Barrow Canyon. On Hanna Shoal, water column CH4 concentrations ranged from 14 to 74 nM, and surface concentrations were up to 15 times supersaturated in CH4 compared to equilibrium with the average atmospheric concentrations (3 nM). CH4 concentrations at the sediment-water interface were around 1,500 nM, and typically increased with depth in the sediment. At the head of Barrow Canyon, water column CH4 concentrations ranged from 5 to 46 nM, with the highest concentrations in the deepest waters that were sampled (118 m). Overall, the calculated fluxes to the atmosphere ranged from 1 to 80 μmol CH4 m-2 d-1 for Hanna Shoal and 4 to 17 μmol CH4 m-2 d-1 across the Barrow Canyon stations. Although there was a large range in these fluxes, the average atmospheric flux (20 μmol CH4 m-2 d-1) across Hanna Shoal was 12 times lower than the flux reported from the East Siberian Arctic Shelf in summer. We conclude that while there is a positive flux of CH4 to the atmosphere, this part of the Chukchi Sea is not a significant source of atmospheric CH4 compared to the East Siberian Sea shelf.

  10. Cyclic Brunn-Minkowski Inequalities for p -affine surface area | Zhao ...

    African Journals Online (AJOL)

    In 2010, Werner and Ye extended the denition for mixed p-affine surface area to all real numbers p. Following this, we establish some isoperimetric inequalities for the general mixed p-affine surface area. The results in special cases yield some of the recent results on inequalities of this type. Mathematics Subject ...

  11. 30 CFR 933.761 - Areas designated unsuitable for surface coal mining by Act of Congress.

    Science.gov (United States)

    2010-07-01

    ... WITHIN EACH STATE NORTH CAROLINA § 933.761 Areas designated unsuitable for surface coal mining by Act of Congress. Part 761 of this chapter, Areas Designated Unsuitable for Coal Mining by Act of Congress, with the exception of §§ 761.11(c) and 761.12(f)(1), shall apply to surface coal mining and reclamation...

  12. Multivariate Analyses of Heavy Metals in Surface Soil Around an Organized Industrial Area in Eskisehir, Turkey.

    Science.gov (United States)

    Malkoc, S; Yazici, B

    2017-02-01

    A total of 50 surface industrial area soil in Eskisehir, Turkey were collected and the concentrations of As, Cr, Cd, Co, Cu, Ni, Pb, Zn, Fe and Mg, at 11.34, 95.8, 1.37, 15.28, 33.06, 143.65, 14.34, 78.79 mg/kg, 188.80% and 78.70%, respectively. The EF values for As, Cu, Pb and Zn at a number of sampling sites were found to be the highest among metals. Igeo-index results show that the study area is moderately polluted with respect to As, Cd, Ni. According to guideline values of Turkey Environmental Quality Standard for Soils, there is no problem for Pb, but the Cd values are fairly high. However, Cr, Cu, Ni and Zn values mostly exceed the limits. Cluster analyses suggested that soil the contaminator values are homogenous in those sub classes. The prevention and remediation of the heavy metal soil pollution should focus on these high-risk areas in the future.

  13. Target surface area effects on hot electron dynamics from high intensity laser-plasma interactions

    Science.gov (United States)

    Zulick, C.; Raymond, A.; McKelvey, A.; Chvykov, V.; Maksimchuk, A.; Thomas, A. G. R.; Willingale, L.; Yanovsky, V.; Krushelnick, K.

    2016-06-01

    Reduced surface area targets were studied using an ultra-high intensity femtosecond laser in order to determine the effect of electron sheath field confinement on electron dynamics. X-ray emission due to energetic electrons was imaged using a {K}α imaging crystal. Electrons were observed to travel along the surface of wire targets, and were slowed mainly by the induced fields. Targets with reduced surface areas were correlated with increased hot electron densities and proton energies. Hybrid Vlasov-Fokker-Planck simulations demonstrated increased electric sheath field strength in reduced surface area targets.

  14. Measurement of the specific surface area of loose copper deposit by electrochemical methods

    Directory of Open Access Journals (Sweden)

    E. A. Dolmatova

    2016-07-01

    Full Text Available In the work the surface area of the electrode with dispersed copper deposit obtained within 30 seconds was evaluated by techniques of chronopotentiometry (CPM and impedance spectroscopy. In method CPM the electrode surface available for measurement depends on the value of the polarizing current. At high currents during the transition time there is a change of surface relief that can not determine the full surface of loose deposit. The electrochemical impedance method is devoid of this shortcoming since the measurements are carried out in indifferent electrolyte in the absence of current. The area measured by the impedance is tens of times higher than the value obtained by chronopotentiometry. It is found that from a solution containing sulfuric acid the deposits form with a high specific surface area. Based on these data it was concluded that the method of impedance spectroscopy can be used to measure in situ the surface area of the dispersed copper deposits.

  15. Quality of surface-water supplies in the Triangle area of North Carolina, water year 2009

    Science.gov (United States)

    Pfeifle, C. A.; Giorgino, M. J.; Rasmussen, R. B.

    2014-01-01

    Surface-water supplies are important sources of drinking water for residents in the Triangle area of North Carolina, which is located within the upper Cape Fear and Neuse River Basins. Since 1988, the U.S. Geological Survey and a consortium of governments have tracked water-quality conditions and trends in several of the area’s water-supply lakes and streams. This report summarizes data collected through this cooperative effort, known as the Triangle Area Water Supply Monitoring Project, during October 2008 through September 2009. Major findings for this period include: - Annual precipitation was approximately 20 percent below the long-term mean (average) annual precipitation. - Streamflow was below the long-term mean at the 10 project streamgages during most of the year. - More than 7,000 individual measurements of water quality were made at a total of 26 sites—15 in the Neuse River Basin and 11 in the Cape Fear River Basin. Forty-seven water-quality properties and constituents were measured. - All observations met North Carolina water-quality standards for water temperature, pH, hardness, chloride, fluoride, sulfate, nitrate, arsenic, cadmium, chromium, lead, nickel, and selenium. - North Carolina water-quality standards were exceeded one or more times for dissolved oxygen, dissolved oxygen percent saturation, chlorophyll a, mercury, copper, iron, manganese, silver, and zinc. Exceedances occurred at 23 sites—13 in the Neuse River Basin and 10 in the Cape Fear River Basin. - Stream samples collected during storm events contained elevated concentrations of 18 water-quality constituents compared to samples collected during non-storm events. - Concentrations of nitrogen and phosphorus were within ranges observed during previous years. - Five reservoirs had chlorophyll a concentrations in excess of 40 micrograms per liter at least once during 2009: Little River Reservoir, Falls Lake, Cane Creek Reservoir, University Lake, and Jordan Lake.

  16. Sea ice concentration temporal variability over the Weddell Sea and its relationship with tropical sea surface temperature

    Science.gov (United States)

    Barreira, S.; Compagnucci, R.

    2007-01-01

    Principal Components Analysis (PCA) in S-Mode (correlation between temporal series) was performed on sea ice monthly anomalies, in order to investigate which are the main temporal patterns, where are the homogenous areas located and how are they related to the sea surface temperature (SST). This analysis provides 9 patterns (4 in the Amundsen and Bellingshausen Seas and 5 in the Weddell Sea) that represent the most important temporal features that dominated sea ice concentration anomalies (SICA) variability in the Weddell, Amundsen and Bellingshausen Seas over the 1979-2000 period. Monthly Polar Gridded Sea Ice Concentrations data set derived from satellite information generated by NASA Team algorithm and acquired from the National Snow and Ice Data Center (NSIDC) were used. Monthly means SST are provided by the National Center for Environmental Prediction reanalysis. The first temporal pattern series obtained by PCA has its homogeneous area located at the external region of the Weddell and Bellingshausen Seas and Drake Passage, mostly north of 60°S. The second region is centered in 30°W and located at the southeast of the Weddell. The third area is localized east of 30°W and north of 60°S. South of the first area, the fourth PC series has its homogenous region, between 30° and 60°W. The last area is centered at 0° W and south of 60°S. Correlation charts between the five Principal Components series and SST were performed. Positive correlations over the Tropical Pacific Ocean were found for the five PCs when SST series preceded SICA PC series. The sign of the correlation could relate the occurrence of an El Niño/Southern Oscillation (ENSO) warm (cold) event with posterior positive (negative) anomalies of sea ice concentration over the Weddell Sea.

  17. 30 CFR 905.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... surface coal mining operations. 905.764 Section 905.764 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE CALIFORNIA § 905.764 Process for designating areas unsuitable for surface coal mining... coal mining operations beginning one year after the effective date of this program. ...

  18. 30 CFR 947.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... surface coal mining operations. 947.764 Section 947.764 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE WASHINGTON § 947.764 Process for designating areas unsuitable for surface coal mining... coal mining and reclamation operations. (b) The Secretary shall notify the Washington Department of...

  19. 30 CFR 903.764 - Process for designating areas unsuitable for surface coal mining operations.

    Science.gov (United States)

    2010-07-01

    ... surface coal mining operations. 903.764 Section 903.764 Mineral Resources OFFICE OF SURFACE MINING... WITHIN EACH STATE ARIZONA § 903.764 Process for designating areas unsuitable for surface coal mining... coal mining operations beginning June 24, 1996, one year after the effective date of this program. ...

  20. ASSESSMENT FORM - NEW IMPROVEMENT OF ACTIONS: CONCENTRATION AND RESEARCH AREAS / CURRICULUM STRUCTURE / FUNDRAISING

    Directory of Open Access Journals (Sweden)

    Iracema MP Calderon

    Full Text Available Objective: This review aims to develop a critical and current analysis of the basic structure of a Postgraduate program for proposing improvement actions and new evaluation criteria. Method: To examine the items that are areas of concentration (AC, research lines (LP, research projects (PP, curricular structure and fundraising were consulted the Area Document, the 2013 Evaluation Report and the Assessment Sheets of Medicine III programs, evaluated in the 2010-2012 period. Results: Consistency is recommended especially among AC, LP and PP, with genuine link between activities and permanent teachers skills and based on structured curriculum in the education of the student. The Program Proposal interfere, and much, in qualifying a program. The curriculum should provide subsidy to the formation of the researcher, through the core subjects, and development of PP, being the concept of disciplines to support lines and research projects. Fundraise should be set out in research projects and in the CV-Lattes. The area recommended that at least 40-50% of permanent teachers present fundraising and the minimum 20-25% of these teachers to have productivity scholarship PQ / CNPq during the triennium. Conclusion: It is necessary to promote wide discussion and find a consensus denominator for these issues. The actions should contribute to the improvement of evaluation forms and certainly for the qualification of the programs but graduate.

  1. Probabilistic risk assessment of insecticide concentrations in agricultural surface waters: a critical appraisal.

    Science.gov (United States)

    Stehle, Sebastian; Knäbel, Anja; Schulz, Ralf

    2013-08-01

    Due to the specific modes of action and application patterns of agricultural insecticides, the insecticide exposure of agricultural surface waters is characterized by infrequent and short-term insecticide concentration peaks of high ecotoxicological relevance with implications for both monitoring and risk assessment. Here, we apply several fixed-interval strategies and an event-based sampling strategy to two generalized and two realistic insecticide exposure patterns for typical agricultural streams derived from FOCUS exposure modeling using Monte Carlo simulations. Sampling based on regular intervals was found to be inadequate for the detection of transient insecticide concentrations, whereas event-triggered sampling successfully detected all exposure incidences at substantially lower analytical costs. Our study proves that probabilistic risk assessment (PRA) concepts in their present forms are not appropriate for a thorough evaluation of insecticide exposure. Despite claims that the PRA approach uses all available data to assess exposure and enhances risk assessment realism, we demonstrate that this concept is severely biased by the amount of insecticide concentrations below detection limits and therefore by the sampling designs. Moreover, actual insecticide exposure is of almost no relevance for PRA threshold level exceedance frequencies and consequential risk assessment outcomes. Therefore, we propose a concept that features a field-relevant ecological risk analysis of agricultural insecticide surface water exposure. Our study quantifies for the first time the environmental and economic consequences of inappropriate monitoring and risk assessment concepts used for the evaluation of short-term peak surface water pollutants such as insecticides.

  2. Spatial Gradients in Trace Metal Concentrations in the Surface Microlayer of the Mediterranean Sea

    Directory of Open Access Journals (Sweden)

    Antonio eTovar-Sanchez

    2014-12-01

    Full Text Available The relationship between dust deposition and surface water metal concentrations is poorly understood. Dissolution, solubility, and partitioning reactions of trace metals from dust particles are governed by complex chemical, biological, and physical processes occurring in the surface ocean. Despite that, the role of the sea surface microlayer (SML, a thin, but fundamental component modulating the air-sea exchange of materials has not been properly evaluated. Our study revealed that the SML of the Mediterranean Sea is enriched with bioactive trace metals (i.e., Cd, Co, Cu and Fe, ranging from 8 (for Cd to 1000 (for Fe times higher than the dissolved metal pool in the underlying water column. The highest enrichments were spatially correlated with the atmospheric deposition of mineral particles. Our mass balance results suggest that the SML in the Mediterranean Sea contains about 2 tonnes of Fe. However, we did not detect any trends between the concentrations of metals in SML with the subsurface water concentrations and biomass distributions. These findings suggest that future studies are needed to quantify the rate of metal exchange between the SML and the bioavailable pool and that the SML should be considered to better understand the effect of atmospheric inputs on the biogeochemistry of trace metals in the ocean.

  3. Concentrating solar power plants versus groundwater resources in Mediterranean areas of Spain: The environmental dilemma.

    Science.gov (United States)

    Moreno Merino, Luis; Imbern Fernández, Núria; Durán Valsero, Juan José; Aguilera, Héctor

    2018-01-15

    Concentrating solar power plants (CSPPs) are considered to be particularly respectful of the environment but under Mediterranean climate where surface water scarcity is a key issue, these types of electrical plants usually require groundwater for their cooling towers and use the same aquifers to discharge their salinized effluents. This study analyses de Spanish case, where fifteen out of the fifty active CSPPs use groundwater directly, four discharge their effluents to infiltration ponds and forty-three to surface watercourses most of which recharge underlying aquifers. The volume of water withdrawn and discharged varies greatly among similar plants. The salinity of the effluent exceeds 2.5 times that of the withdrawn water in half of the plants and it may alter the current or potential use of the water turning it unsuitable for drinking or even for irrigation. There is a risk that the impact on groundwater can be extended to related ecosystems such as wetlands. This can become a serious environmental problem, but specific impacts on groundwater are often overlooked in environmental impact assessments of CSPPs and no research on the matter has been reported so far. Other legal and political implications of CSPPs are further discussed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  4. Impact of Donor Age, Gender and Handling Time on the DNA Concentration Left on Different Surfaces

    Directory of Open Access Journals (Sweden)

    Branka Gršković

    2014-09-01

    Full Text Available Background: We analyzed the correlation between several factors (donor age and gender, and handling time and trace DNA concentration that participants left on different surfaces (paper, plastic, plastic coated metal while holding items in their hands or rubbing them with their fingers, their palms, and the side of the palm of the dominant hand. Material and Methods: Sixty participants took part in the study. Items were swabbed with a moistened cotton swab. DNA was isolated using the Chelex procedure and quantified by real-time PCR. Results: We found that DNA concentration transferred to an item was independent of the handling time. On the contrary, it was dependent on the item’s texture; the greatest concentration was left on plastic coated metal (PCM and the least on paper. The greatest concentration of trace DNA was left by participants from 35 to 44 years of age. Results of the study showed that men deposit a higher DNA concentration than do women. Conclusion: Item texture, donor age, and gender influence trace DNA concentration. Further investigations are necessary to fully understand the process of DNA transfer from donors to handled items.

  5. Surface Area, and Oxidation Effects on Nitridation Kinetics of Silicon Powder Compacts

    Science.gov (United States)

    Bhatt, R. T.; Palczer, A. R.

    1998-01-01

    Commercially available silicon powders were wet-attrition-milled from 2 to 48 hr to achieve surface areas (SA's) ranging from 1.3 to 70 sq m/g. The surface area effects on the nitridation kinetics of silicon powder compacts were determined at 1250 or 1350 C for 4 hr. In addition, the influence of nitridation environment, and preoxidation on nitridation kinetics of a silicon powder of high surface area (approximately equals 63 sq m/g) was investigated. As the surface area increased, so did the percentage nitridation after 4 hr in N2 at 1250 or 1350 C. Silicon powders of high surface area (greater than 40 sq m/g) can be nitrided to greater than 70% at 1250 C in 4 hr. The nitridation kinetics of the high-surface-area powder compacts were significantly delayed by preoxidation treatment. Conversely, the nitridation environment had no significant influence on the nitridation kinetics of the same powder. Impurities present in the starting powder, and those accumulated during attrition milling, appeared to react with the silica layer on the surface of silicon particles to form a molten silicate layer, which provided a path for rapid diffusion of nitrogen and enhanced the nitridation kinetics of high surface area silicon powder.

  6. Concentration Dependences of the Surface Tension and Density of Solutions of Acetone-Ethanol-Water Systems at 293 K

    Science.gov (United States)

    Dadashev, R. Kh.; Dzhambulatov, R. S.; Mezhidov, V. Kh.; Elimkhanov, D. Z.

    2018-05-01

    Concentration dependences of the surface tension and density of solutions of three-component acetone-ethanol-water systems and the bounding binary systems at 273 K are studied. The molar volume, adsorption, and composition of surface layers are calculated. Experimental data and calculations show that three-component solutions are close to ideal ones. The surface tensions of these solutions are calculated using semi-empirical and theoretical equations. Theoretical equations qualitatively convey the concentration dependence of surface tension. A semi-empirical method based on the Köhler equation allows us to predict the concentration dependence of surface tension within the experimental error.

  7. Environmental and geochemical assessment of surface sediments on irshansk ilmenite deposit area

    Directory of Open Access Journals (Sweden)

    Наталия Олеговна Крюченко

    2015-03-01

    Full Text Available It is revealed the problem of pollution of surface sediments of Irshansk ilmenite deposit area of various chemical elements hazard class (Mn, V, Ba, Ni, Co, Cr, Mo, Cu, Pb, Zn. It is determined its average content in surface sediments of various functional areas (forest and agricultural land, flood deposits, reclaimed land, calculated geochemical criteria, so given ecological and geochemical assessment of area

  8. Modeling the dynamics of radionuclide concentration in food after an accident in tropical areas

    International Nuclear Information System (INIS)

    Vinhas, Denise M.; Rochedo, Elaine R.R.; Wasserman, Maria Angelica; Conti, Luiz Fernando C.

    2005-01-01

    Following an accidental release of radionuclides to the atmosphere that leads to the contamination of large areas, a detailed and fast methodology to assess the prognosis of public exposure is needed, in order to estimate radiological consequences as a base to propose and optimize decisions related to the protection of the public. The German model ECOSYS has been chosen to integrate the SIEM - Integrated Emergency System, developed by IRD/CNEN to assess the doses to the public at the short, medium and long term after an accidental contamination of rural areas. The use of such a model demands a considerable effort in adapting the scenarios to fit the specific conditions of the location where it is to be applied, in particular considering the differences on climate, environmental characteristics, agricultural calendar and practices, along with population diet. The area selected as reference to start this adaptation process is the 50 km radius area surrounding the Brazilian nuclear power plants, at Angra dos Reis County, in Rio de Janeiro State. Radionuclides included in this study were 137 Cs, 90 Sr and 131 I. This work describes the methodology used to select scenarios and describes the results related to the dynamics of the predicted concentration of radionuclides in different kinds of vegetable foods. It also discusses the relevance of criteria, parameter values and site specific aspects that are to be considered in performing assessments of public exposure. The work provides guidance to the need of radioecological research and on the database needed to perform the simulations, in order to improve the adequacy of the estimates to actual Brazilian scenarios. (author)

  9. Changes in the Surface Area of Glaciers in Northern Eurasia

    Science.gov (United States)

    Khromova, T.; Nosenko, G.

    2012-12-01

    Glaciers are widely recognized as key indicators of climate change. Recent evidence suggests an acceleration of glacier mass loss in several key mountain regions. Glacier recession implies the landscape changes in the glacial zone, origin of new lakes and activation of natural disaster processes, catastrophic mudflows, ice avalanches, outburst floods, and etc. The presence of glaciers in itself threats to human life, economic activity and growing infrastructure. Economical and recreational human activity in mountain regions requires relevant information on snow and ice objects. Absence or inadequacy of such information results in financial and human losses. A more comprehensive evaluation of glacier changes is imperative to assess ice contributions to global sea level rise and the future of water resources from glacial basins. One of the urgent steps is a full inventory of all ice bodies, their volume and changes The first estimation of glaciers state and glaciers distribution in the big part of Northern Eurasia has been done in the USSR Glacier Inventory published in 1966 -1980 as a part of IHD activity. The Inventory is based on topographic maps and air photos and reflects the status of the glaciers in 1957-1970y. There is information about 23796 glaciers with area of 78222.3 km2 in the Inventory. It covers 23 glacier systems on Northern Eurasia. In the 80th the USSR Glacier Inventory has been transformed in the digital form as a part of the World Glacier Inventory. Recent satellite data provide a unique opportunity to look again at these glaciers and to evaluate changes in glacier extent for the second part of XX century. In the paper we report about 15 000 glaciers outlines for Caucasus, Pamir, Tien-Shan, Altai, Syntar-Khayata, Cherskogo Range, Kamchatka and Russian Arctic which have been derived from ASTER and Landsat imagery and could be used for glacier changes evaluation. The results show that glaciers are retreating in all these regions. There is, however

  10. Final characterization report for the non-process areas of the 233-S Plutonium Concentration Facility

    International Nuclear Information System (INIS)

    Encke, D.B.; Harris, R.A.

    1997-04-01

    This report addresses the 233-S Plutonium Concentration Facility characterization survey data collected from January 21, 1997 through February 3, 1997. The characterization activities evaluated the radiological status and identified the hazardous materials locations. The scope of this report is limited to the nonprocess areas in the facility, which include the special work permit (SWP) change room, toilet, equipment room, electrical cubicle, control room, and pipe gallery. A portion of the roof (excluding the roof over the process hood and viewing room) was also included. Information in this report will be used to identify waste streams, provide specific chemical and radiological data to aid in planning decontamination and demolition activities, and allow proper disposal of the demolition debris, as required by the Comprehensive Environmental Response, Compensation, and Liability Act of 1980

  11. Methodology for assessing the concentrations of the primary marine aerosol in coastal areas

    International Nuclear Information System (INIS)

    Barsanti, P.; Briganti, G.; Cappelletti, A.; Marri, P.

    2009-01-01

    European and Italian regulations (DM 60/2002) fix for atmospheric particulate matter PM10 the threshold of 50 μg/m 3 as limit not to be exceeded more than 35 times per year (24 hour mean); unfortunately, such prescriptions do not distinguish anthropic contributions from natural ones (sea salt, Saharan sand, coastal erosion, volcanic ashes, etc.). The aim of this study is to set up a methodology in order to estimate sea salt emissions, both from open sea and surf zone, and to model atmospheric dispersion of marine aerosols. The proposed methodology, applied to the coastal zone between Massa Carrara and Viareggio (Tuscany, Italy), shows specific open sea emissions are generally very low in comparison with the surf zone ones: they are not negligible only with strong winds, but such meteorological conditions are neither persistent nor very frequent in the selected area. On the contrary, sea surf contributions are much more strong (at least 1 order of magnitude), peak-shaped and persistent then the first ones, and can lead to high PM10 concentration fields up to few kilometres inland. The comparison between model outputs and observations, in two points placed at 2000 and 4000 m from the shoreline, has shown an amount of sea salt in total PM10 even greater then 70% in mass. The existence of a surf zone, which can persist many hours or days even after a storm, can produce both elevated PM concentrations and gradients, mainly for light winds perpendicular to the shoreline. This work, supported by MINNI Project (www.minni.org), is suitable for other coastal areas as well and it is aimed to furnish an overview of marine particulate production and atmospheric dispersion processes; it is the starting point of an experimental investigation program, supported by institutional air quality authorities [it

  12. No difference in urinary iodine concentrations between Boston-area breastfed and formula-fed infants.

    Science.gov (United States)

    Gordon, Joshua H; Leung, Angela M; Hale, Andrea R; Pearce, Elizabeth N; Braverman, Lewis E; He, Xuemei; Belfort, Mandy B; Nelson, Sara M; Brown, Rosalind S

    2014-08-01

    Thyroid hormone is essential for normal mental and physical development in infancy and childhood and is dependent on adequate iodine intake. During the first few months of life, infants are reliant on breastmilk and/or infant formula as their sole sources of dietary iodine. The iodine status of U.S. infants has not been well studied. This was a cross-sectional study of 95 breastfed and/or formula-fed infants less than 3 months of age in the Boston area. We measured iodine content from infants' single spot urine samples and assessed associations with infant feeding type as well as maternal demographic data, salt and multivitamin use, smoking status, and diet. The median infant urine iodine concentration was 197.5 μg/L (range 40-897.5 μg/L). Median infant urine iodine concentrations were similar between infants who were exclusively breastfed (n=39, 203.5 μg/L; range 61.5-395.5 μg/L), formula-fed (n=44, 182.5 μg/L; range 40-897.5 μg/L), and mixed (n=10, 197.8 μg/L; range 123-592.5) (p=0.88). There were no significant correlations of infant urinary iodine with maternal salt or multivitamin use (regularly or in the past 24 hours), active or secondhand cigarette smoke exposures, infant weight, infant length, or recent maternal ingestion of common iodine-containing foods, although the correlations with iodine-containing foods are difficult to accurately determine due to the small sample sizes of these variables. Both breastfed and formula-fed infants less than 3 months of age in the Boston area were generally iodine sufficient. Larger studies are needed to confirm these observations among infants nationwide and elucidate other factors that may contribute to infant iodine nutrition.

  13. RADON CONCENTRATION IN THE AREA OF WASTE ROCK DUMPS, BROD, CR-CASE STUDY.

    Science.gov (United States)

    Thinova, L; Bican, R; Fronka, A; Johnova, K; Solc, J; Vosahlik, J

    2017-11-01

    There are ~7000 mining waste storage facilities including waste rock dumps in the Czech Republic. One of the radiation protection present subjects is a health impact estimation of the huge mass of material in waste rock dumps left after uranium mining. In this document are presented selected results of waste rock dump long-term monitoring in the area of shaft No. 15 (Pribram, CR) and its estimated health impact to the representative person in a village Brod. The external irradiation was estimated based on in situ gamma spectrometry measurement results and on a Monte Carlo model and it turned out to be negligible (tens μSv), while the internal irradiation (RAMARN, ALGADE Environmental and RAMONIS detection systems) is more significant. The estimated total annual effective dose for representative person is mainly caused by indoor radon inhalation. The maximum outdoor radon concentration in summer season was measured during night hours between 9 p.m. and 7 a.m. and could reach thousands Bq/m3. The average indoor concentration measured in randomly selected houses was 450 Bq/m3. The radon exhalation rate was 35-40 mBq m-2 s-1. © The Author 2017. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  14. Determination of the surface area and sizes of supported copper nanoparticles through organothiol adsorption—ñhemisorption

    International Nuclear Information System (INIS)

    Ndolomingo, Matumuene Joe; Meijboom, Reinout

    2016-01-01

    Highlights: • Cu on γ-Al 2 O 3 catalysts were prepared and characterized. • The ligand sorption-based technique was used for the determination of specific surface area and particle sizes. • The ligand packing density on Cu nanoparticles was quantified. • A fair agreement was found between the Cu particle sizes obtained from ligand adsorption and TEM methods. • The oxidation of morin by hydrogen peroxide was used to evaluate the catalytic activities of the Cu supported catalysts. - Abstract: The mechanisms involving the nanoparticle surfaces in catalytic reactions are more difficult to elucidate due to the nanoparticle surface unevenness, size distributions, and morphological irregularity. True surface area and particle sizes determination are key aspects of the activity of metal nanoparticle catalysts. Here we report on the organothiol adsorption-based technique for the determination of specific surface area of Cu nanoparticles, and their resultant sizes on γ-Al 2 O 3 supports. Quantification of ligand packing density on copper nanoparticles is also reported. The concentration of the probe ligand, 2-mercaptobenzimidazole (2-MBI) before and after immersion of supported copper catalysts was determined by ultraviolet-visible spectrometry (UV–vis). The amount of ligand adsorbed was found to be proportional to the copper nanoparticles surface area. Atomic absorption spectrometry (AAS), N 2 -physisorption (BET), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA) were used for the characterization of the catalysts. A fair agreement was found between particle sizes obtained from ligand adsorption and TEM methods. The catalytic activity of the copper nanoparticles related to their inherent surface area was evaluated using the model reaction of the oxidation of morin by hydrogen peroxide.

  15. Determination of the surface area and sizes of supported copper nanoparticles through organothiol adsorption—ñhemisorption

    Energy Technology Data Exchange (ETDEWEB)

    Ndolomingo, Matumuene Joe; Meijboom, Reinout, E-mail: rmeijboom@uj.ac.za

    2016-12-30

    Highlights: • Cu on γ-Al{sub 2}O{sub 3} catalysts were prepared and characterized. • The ligand sorption-based technique was used for the determination of specific surface area and particle sizes. • The ligand packing density on Cu nanoparticles was quantified. • A fair agreement was found between the Cu particle sizes obtained from ligand adsorption and TEM methods. • The oxidation of morin by hydrogen peroxide was used to evaluate the catalytic activities of the Cu supported catalysts. - Abstract: The mechanisms involving the nanoparticle surfaces in catalytic reactions are more difficult to elucidate due to the nanoparticle surface unevenness, size distributions, and morphological irregularity. True surface area and particle sizes determination are key aspects of the activity of metal nanoparticle catalysts. Here we report on the organothiol adsorption-based technique for the determination of specific surface area of Cu nanoparticles, and their resultant sizes on γ-Al{sub 2}O{sub 3} supports. Quantification of ligand packing density on copper nanoparticles is also reported. The concentration of the probe ligand, 2-mercaptobenzimidazole (2-MBI) before and after immersion of supported copper catalysts was determined by ultraviolet-visible spectrometry (UV–vis). The amount of ligand adsorbed was found to be proportional to the copper nanoparticles surface area. Atomic absorption spectrometry (AAS), N{sub 2}-physisorption (BET), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA) were used for the characterization of the catalysts. A fair agreement was found between particle sizes obtained from ligand adsorption and TEM methods. The catalytic activity of the copper nanoparticles related to their inherent surface area was evaluated using the model reaction of the oxidation of morin by hydrogen peroxide.

  16. Development of cortical thickness and surface area in autism spectrum disorder

    Directory of Open Access Journals (Sweden)

    Vincent T. Mensen

    2017-01-01

    Full Text Available Autism spectrum disorder (ASD is a neurodevelopmental disorder often associated with changes in cortical volume. The constituents of cortical volume – cortical thickness and surface area – have separable developmental trajectories and are related to different neurobiological processes. However, little is known about the developmental trajectories of cortical thickness and surface area in ASD. In this magnetic resonance imaging (MRI study, we used an accelerated longitudinal design to investigate the cortical development in 90 individuals with ASD and 90 typically developing controls, aged 9 to 20 years. We quantified cortical measures using the FreeSurfer software package, and then used linear mixed model analyses to estimate the developmental trajectories for each cortical measure. Our primary finding was that the development of surface area follows a linear trajectory in ASD that differs from typically developing controls. In typical development, we found a decline in cortical surface area between the ages of 9 and 20 that was absent in ASD. We found this pattern in all regions where developmental trajectories for surface area differed between groups. When we applied a more stringent correction that takes the interdependency of measures into account, this effect on cortical surface area retained significance for left banks of superior temporal sulcus, postcentral area, and right supramarginal area. These areas have previously been implicated in ASD and are involved in the interpretation and processing of audiovisual social stimuli and distinction between self and others. Although some differences in cortical volume and thickness were found, none survived the more stringent correction for multiple testing. This study underscores the importance of distinguishing between cortical surface area and thickness in investigating cortical development, and suggests the development of cortical surface area is of importance to ASD.

  17. Influence of geology on arsenic concentrations in ground and surface water in central Lesvos, Greece.

    Science.gov (United States)

    Aloupi, Maria; Angelidis, Michael O; Gavriil, Apostolos M; Koulousaris, Michael; Varnavas, Soterios P

    2009-04-01

    The occurrence of As was studied in groundwater used for human consumption and irrigation, in stream water and sediments and in water from thermal springs in the drainage basin of Kalloni Gulf, island of Lesvos, Greece, in order to investigate the potential influence of the geothermal field of Polichnitos-Lisvori on the ground and surface water systems of the area. Total dissolved As varied in the range geology exerts a determinant influence on As geochemical behaviour. On the other hand, the geothermal activity manifested in the area of Polichnitos-Lisvori does not affect the presence of As in groundwater and streams.

  18. 226Ra concentration in the teeth of habitants of areas with high level of natural radioactivity in Ramsar

    International Nuclear Information System (INIS)

    Aghamiri, S. Mahmoud Reza; Ghorbani, Zahra; Darafsheh, Arash; Torabzadeh, Hasan; Fathivand, Ali Asghar; Minuchehr, Abdulhamid; Jalinoos, Alireza

    2006-01-01

    The level of natural radiation in some regions of Ramsar, a northern coastal city of Iran, is known to be among the highest levels of natural radiation in the world. 226 Ra existing in high concentrations in the soil of this region is washed by underground water and transferred to the surface. In this way, 226 Ra enters the food chain of residents and substitutes within the hard body tissues of humans. 226 Ra is one of the so-called bone seekers as its metabolic processes in the human body are similar to calcium and remains in hard tissues of body because of its long half-life, and being an α emitter causes dangerous effects on human health. The purpose of this study is to determine the concentration of 226 Ra in the teeth of residents of these high-level natural radiation areas, compared with a control group. Thirteen teeth in five groups were studied as the case group and thirteen teeth in five corresponding control groups were inspected. The mean values of the activity of 226 Ra in the case group and in the control group were 0.32 and 0.18 mBq g -1 , respectively

  19. Optimization of artificial neural network models through genetic algorithms for surface ozone concentration forecasting.

    Science.gov (United States)

    Pires, J C M; Gonçalves, B; Azevedo, F G; Carneiro, A P; Rego, N; Assembleia, A J B; Lima, J F B; Silva, P A; Alves, C; Martins, F G

    2012-09-01

    This study proposes three methodologies to define artificial neural network models through genetic algorithms (GAs) to predict the next-day hourly average surface ozone (O(3)) concentrations. GAs were applied to define the activation function in hidden layer and the number of hidden neurons. Two of the methodologies define threshold models, which assume that the behaviour of the dependent variable (O(3) concentrations) changes when it enters in a different regime (two and four regimes were considered in this study). The change from one regime to another depends on a specific value (threshold value) of an explanatory variable (threshold variable), which is also defined by GAs. The predictor variables were the hourly average concentrations of carbon monoxide (CO), nitrogen oxide, nitrogen dioxide (NO(2)), and O(3) (recorded in the previous day at an urban site with traffic influence) and also meteorological data (hourly averages of temperature, solar radiation, relative humidity and wind speed). The study was performed for the period from May to August 2004. Several models were achieved and only the best model of each methodology was analysed. In threshold models, the variables selected by GAs to define the O(3) regimes were temperature, CO and NO(2) concentrations, due to their importance in O(3) chemistry in an urban atmosphere. In the prediction of O(3) concentrations, the threshold model that considers two regimes was the one that fitted the data most efficiently.

  20. Development of the interfacial area concentration measurement method using a five sensor conductivity probe

    International Nuclear Information System (INIS)

    Euh, Dong Jin; Yun, Byong Jo; Song, Chul Hwa; Kwon, Tae Soon; Chung, Moon Ki; Lee, Un Chul

    2000-01-01

    The interfacial area concentration(IAC) is one of the most important parameters in the two-fluid model for two-phase flow analysis. The IAE can be measured by a local conductivity probe method that uses the difference of conductivity between water and air/steam. The number of sensors in the conductivity probe may be differently chosen by considering the flow regime of two-phase flow. The four sensor conductivity probe method predicts the IAC without any assumptions of the bubble shape. The local IAC can be obtained by measuring the three dimensional velocity vector elements at the measuring point, and the directional cosines of the sensors. The five sensor conductivity probe method proposed in this study is based on the four sensor probe method. With the five sensor probe, the local IAC for a given referred measuring area of the probe can be predicted more exactly than the four sensor prober. In this paper, the mathematical approach of the five sensor probe method for measuring the IAC is described, and a numerical simulation is carried out for ideal cap bubbles of which the sizes and locations are determined by a random number generator

  1. Variation in glyphosate and AMPA concentrations of surface water and groundwater

    Science.gov (United States)

    Caprile, Ana Clara; Aparicio, Virginia; Sasal, Carolina; Andriulo, Enrique

    2017-04-01

    The presence of pesticides in various environmental matrices indicate that the soil's ability to function as a bio-physical-chemical reactor is declining. As it operates as an interface between air and water, it causes a negative impact on these two vital resources. Currently, the pampa agriculture is simplified with a marked tendency towards spring-summer crops, where the main crops are RR soybean and corn. Herbicides are neither retained nor degraded in the soil, which results in polluted groundwater and surface waters. The objectives of this study were: a) to verify the presence of glyphosate and aminomethylphosphonic acid (AMPA) in Pergamino stream (a typical representative of the most productive agricultural region of Argentina) under different land use and to detect if in the detections there was a space-time pattern, and b) to verify the detection of these molecules in groundwater of the upper same basin under exclusively rural land use. Surface stream was sampling in six sites (five under rural land use and one under urban-industrial land use) at a rate of one sample by spring, summer and winter seasons (2010-2013, 54 total samples). Groundwater glyphosate and AMPA concentrations were determined in 24 piezometers constructed at two positions of the landscape, across the groundwater flow direction, sampled at two sampling dates (2010 and 2012, 45 total samples). In surface water, glyphosate and AMPA were detected in 54 and 69% of the samples analyzed, respectively. The median concentrations were 0.9 and 0.8 µg L-1 for glyphosate and AMPA and maximal concentrations 258 and 5865 µg L-1, respectively. The sampling site under urban-industrial land use had abnormally high concentrations of glyphosate in the spring (attributed to point pollution), a fact that not allowed to see differences in the remaining sampling times under different land uses. AMPA concentrations under urban-industrial land use were high and higher than rural land use in 3 studied seasons

  2. Simulation of trace metals and PAH atmospheric pollution over Greater Paris: Concentrations and deposition on urban surfaces

    Science.gov (United States)

    Thouron, L.; Seigneur, C.; Kim, Y.; Legorgeu, C.; Roustan, Y.; Bruge, B.

    2017-10-01

    Urban areas can be subject not only to poor air quality, but also to contamination of other environmental media by air pollutants. Here, we address the potential transfer of selected air pollutants (two metals and three PAH) to urban surfaces. To that end, we simulate meteorology and air pollution from Europe to a Paris suburban neighborhood, using a four-level one-way nesting approach. The meteorological and air quality simulations use urban canopy sub-models in order to better represent the effect of the urban morphology on the air flow, atmospheric dispersion, and deposition of air pollutants to urban surfaces. This modeling approach allows us to distinguish air pollutant deposition among various urban surfaces (roofs, roads, and walls). Meteorological model performance is satisfactory, showing improved results compared to earlier simulations, although precipitation amounts are underestimated. Concentration simulation results are also satisfactory for both metals, with a fractional bias air pollutants to other environmental media. Dry deposition fluxes to various urban surfaces are mostly uniform for PAH, which are entirely present in fine particles. However, there is significantly less wall deposition compared to deposition to roofs and roads for trace metals, due to their coarse fraction. Meteorology, particle size distribution, and urban morphology are all important factors affecting air pollutant deposition. Future work should focus on the collection of data suitable to evaluate the performance of atmospheric models for both wet and dry deposition with fine spatial resolution.

  3. Levels and isomer profiles of Dechlorane Plus in the surface soils from e-waste recycling areas and industrial areas in South China

    Energy Technology Data Exchange (ETDEWEB)

    Yu Zhiqiang [State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environment and Resources, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); Lu Shaoyou; Gao Shutao; Wang Jingzhi [State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environment and Resources, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); Graduate School of the Chinese Academy of Sciences, Beijing 100039 (China); Li Huiru, E-mail: huiruli@gig.ac.c [State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environment and Resources, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); Zeng Xiangying; Sheng Guoying; Fu Jiamo [State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environment and Resources, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China)

    2010-09-15

    Dechlorane Plus (DP) is a highly chlorinated flame retardant. Levels of DP were measured in surface soils from e-waste recycling areas and industrial areas in South China. Higher DP levels were found in e-waste recycling areas (undetectable-47.4 ng/g) than those in industrial areas (0.0336-4.65 ng/g) in South China. The highest DP concentration (3327 ng/g) was found at the e-waste recycling site in Qingyuan, while DP levels fell dramatically with increasing distance away from the recycling site, suggesting that the e-waste recycling activities are an important source of DP emissions. The mean ratios of anti-DP to total DP (f{sub anti}) for different sampling areas ranged from 0.58 to 0.76 and showed no significant difference from the ratio for the technical DP products (t-test, p > 0.05). Further intensive studies are needed to investigate the process of DP degradation and its degradation products. - High DP concentrations were found in the soils from e-waste recycling regions, and e-waste recycling was the major source of DP emissions in South China.

  4. Polymer and Concentrator Photovoltaic Technologies - Energy Return Factors and Area Efficiency

    Energy Technology Data Exchange (ETDEWEB)

    Loefgren, Birger; Gustaf Zettergren

    2006-12-20

    Market diffusion of flat plate crystalline silicon photovoltaic (PV) technology has been induced by economical support schemes and has lead to reduced cost per produced kWh electricity. For further market penetration of the PV technology, a continued reduction of production cost is required. Two alternative approaches to achieve this are using less expensive materials or changing the active materials. The technologies of concentrator PV (CPV) systems and polymer PV (PPV) devices represent these two strategies. The potential energy performance of these technologies is studied in terms of the process primary energy requirements for manufacturing, how many times this energy is paid back during its lifetime and as the required land area for electricity generation. The study is an energy analysis incorporating the inherent uncertainties in technology development. Uncertainties are identified in data acquisition, in design choices, as induced by development and improvement, in performance and by different application scenarios. The future technology alternatives are defined in different ways for CPV and PPV. CPV parameters are derived from existing products and ideas for improvements and PPV parameters from the directions of research. This study shows that the invested energy in future CPV and PPV is potentially paid back up to about 90 and 170 times, respectively, under Arizona (CPV) and average European (PPV) solar irradiation conditions. However the result is highly dependent on configuration, inventory data and device performance. Thus, for certain design alternatives, data and performance, PPV production energy is far from paid back during its lifetime. For CPV the energy return factor is decreased to about 13 in the least beneficial case. Area efficiency is studied as the land area requirements for producing a net output electricity of 1 MWh during 25 years. With device efficiencies from 1 to 5 per cent and lifetimes from 1 to 5 years a PPV device requires from 2

  5. Quantitative kinetics of proteolytic enzymes determined by a surface concentration-based assay using peptide arrays.

    Science.gov (United States)

    Jung, Se-Hui; Kong, Deok-Hoon; Park, Seoung-Woo; Kim, Young-Myeong; Ha, Kwon-Soo

    2012-08-21

    Peptide arrays have emerged as a key technology for drug discovery, diagnosis, and cell biology. Despite the promise of these arrays, applications of peptide arrays to quantitative analysis of enzyme kinetics have been limited due to the difficulty in obtaining quantitative information of enzymatic reaction products. In this study, we developed a new approach for the quantitative kinetics analysis of proteases using fluorescence-conjugated peptide arrays, a surface concentration-based assay with solid-phase peptide standards using dry-off measurements, and compared it with an applied concentration-based assay. For fabrication of the peptide arrays, substrate peptides of cMMP-3, caspase-3, caspase-9, and calpain-1 were functionalized with TAMRA and cysteine, and were immobilized onto amine-functionalized arrays using a heterobifunctional linker, N-[γ-maleimidobutyloxy]succinimide ester. The proteolytic activities of the four enzymes were quantitatively analyzed by calculating changes induced by enzymatic reactions in the concentrations of peptides bound to array surfaces. In addition, this assay was successfully applied for calculating the Michaelis constant (K(m,surf)) for the four enzymes. Thus, this new assay has a strong potential for use in the quantitative evaluation of proteases, and for drug discovery through kinetics studies including the determination of K(m) and V(max).

  6. Biofunctionalization of the implant surface with different concentrations of a synthetic peptide (P-15).

    Science.gov (United States)

    Lutz, R; Prechtl, C; Nonhoff, J; Weisel, T; Damien, C J; Schlegel, K A

    2013-07-01

    This study aimed at identifying the ideal concentration of a biofunctional surface coating of dental implants with a synthetic peptide (P-15). In a previous study, P-15 was shown to enhance osseointegration parameters. Implants (modified ANKYLOS(®) A8; FRIADENT Plus(®) surface) with five different concentrations (0-400 μg/ml) of a P-15 coating as well as uncoated controls were inserted in the frontal bone of 45 adult domestic pigs. The histomorphometric and microradiographic findings for the coated implants were compared to those for the uncoated ones after 7, 14, and 30 days. No significant differences were observed comparing the peri-implant bone density between the coated and uncoated implants The bone-to-implant contact, as the primary histological parameter for osseointegration, showed high rates for all surfaces investigated (between 73.3 ± 17.9% for the control and 81.9 ± 15.2% for P15 20 μg/ml after 30 days). No significant benefit on osseointegration of a biofunctional P-15 coating of dental implants could be displayed in the present study. © 2012 John Wiley & Sons A/S.

  7. Optimization of sampling for the determination of the mean Radium-226 concentration in surface soil

    International Nuclear Information System (INIS)

    Williams, L.R.; Leggett, R.W.; Espegren, M.L.; Little, C.A.

    1987-08-01

    This report describes a field experiment that identifies an optimal method for determination of compliance with the US Environmental Protection Agency's Ra-226 guidelines for soil. The primary goals were to establish practical levels of accuracy and precision in estimating the mean Ra-226 concentration of surface soil in a small contaminated region; to obtain empirical information on composite vs. individual soil sampling and on random vs. uniformly spaced sampling; and to examine the practicality of using gamma measurements in predicting the average surface radium concentration and in estimating the number of soil samples required to obtain a given level of accuracy and precision. Numerous soil samples were collected on each six sites known to be contaminated with uranium mill tailings. Three types of samples were collected on each site: 10-composite samples, 20-composite samples, and individual or post hole samples; 10-composite sampling is the method of choice because it yields a given level of accuracy and precision for the least cost. Gamma measurements can be used to reduce surface soil sampling on some sites. 2 refs., 5 figs., 7 tabs

  8. Effect of specific surface area of MWCNTS on surface roughness and delamination in drilling Epoxy/Glass Fabric Composite

    Science.gov (United States)

    Ponnuvel, S.; Ananth, M. Prem

    2018-03-01

    In this study the effect of specific surface area of the MWCNTs on the drilled hole qualities was investigated. Epoxy araldite LY556 with hardener HY951 and E-glass coarse plain weave fabric are used for the fabrication of reference material (specimen A). Multi-WalledCarbon Nanotubes (MWCNTs) with diameters fabrication of study materials, namely specimen B and specimen C respectively. In specimen B the epoxy resin was filled with MWCNTs having a specific surface area >500 m2 g‑1. MWCNTs in specimen C had a specific surface area >110 m2 g‑1. Drilling experiments were conducted on all the three specimens. Two dimensional delamination factor and the surface roughness of the inner wall of the drilled holes were investigated using Grey Relational Analysis (GRA) and Analysis of variance (ANOVA). Two dimensional delamination factor showed better performance from specimen B and specimen C in comparison with specimen A suggesting improvement in the bonding between epoxy and the glass fiber in the presence of MWCNTs. Similar observations were made for surface roughness of the inner wall of the drilled holes at 1250 rpm. Whereas the presence of MWCNTs (Specimen B and specimen C) produced poor surface finish at 500 rpm in comparison with specimen A. Variations in the hole quality characteristics between specimen B and specimen C was marginal with better observations in specimen C.

  9. Large-area electromagnetic enhancement by a resonant excitation of surface waves on a metallic surface with periodic subwavelength patterns.

    Science.gov (United States)

    Zhang, Xin; Liu, Haitao; Zhong, Ying

    2013-10-07

    We theoretically investigate the electromagnetic enhancement on a metallic surface patterned with periodic subwavelength structures. Fully-vectorial calculations show a large-area electromagnetic enhancement (LAEE) on the surface, which strongly contrasts with the previously reported "hot spots" that occur in specific tiny regions and which relieves the rigorous requirement of the nano-scale location of sample molecules. The LAEE allows for designing more practicable substrates for many enhanced-spectra applications. By building up microscopic models, the LAEE is shown due to a resonant excitation of surface waves that include both the surface plasmon polariton (SPP) and a quasi-cylindrical wave (QCW). The surface waves propagate on the substrate over a long distance and thus greatly enlarge the area of electromagnetic enhancement compared to the nano-sized hot spots caused by localized modes. Gain medium is introduced to further strengthen the large-area surface-wave resonance, with which an enhancement factor (EF) of electric-field intensity up to a few thousands is achieved.

  10. Rapid fabrication of large-area, corrosion-resistant superhydrophobic Mg alloy surfaces.

    Science.gov (United States)

    Xu, Wenji; Song, Jinlong; Sun, Jing; Lu, Yao; Yu, Ziyuan

    2011-11-01

    A superhydrophobic magnesium (Mg) alloy surface was successfully fabricated via a facile electrochemical machining process, and subsequently covered with a fluoroalkylsilane (FAS) film. The surface morphologies and chemical compositions were investigated using a scanning electron microscope (SEM) equipped with an energy-dispersive spectroscopy (EDS) and a Fourier-transform infrared spectrophotometer (FTIR). The results show hierarchal rough structures and an FAS film with a low surface energy on the Mg alloy surfaces, which confers good superhydrophobicity with a water contact angle of 165.2° and a water tilting angle of approximately 2°. The processing conditions, such as the processing time and removal rate per unit area at a constant removal mass per unit area, were investigated to determine their effects on the superhydrophobicity. Interestingly, when the removal mass per unit area is constant at approximately 11.10 mg/cm(2), the superhydrophobicity does not change with the removal rate per unit area. Therefore, a superhydrophobic Mg alloy surface can be rapidly fabricated based on this property. A large-area superhydrophobic Mg alloy surface was also fabricated for the first time using a small-area moving cathode. The corrosion resistance and durability of the superhydrophobic surfaces were also examined.

  11. Relationship between Mineral Soil Surface Area and the Biological Degradation of Biosolids Added to Soil

    Directory of Open Access Journals (Sweden)

    Dongqi Wen

    2015-12-01

    Full Text Available Geochemical and biological processes that operate in the soil matrix and on the soil surface are important to the degradation of biosolids in soil. Due to the large surface area of soils it is assumed that the microbial ecology is associated with mineral soil surface area. The total mineral surface areas were determined for soils from eight different fields selected from a long term study (1972–2006 of annual biosolids application to 41 fields in central Illinois varying in size from 3.6 to 66 ha. The surface areas for the soils varied from 1 to 9 m2/g of soil. The biological degradation rates for the eight soils were determined using a biological degradation rate model (DRM and varied from 0.02 to 0.20/year−1. Regression analysis revealed that the degradation rate was positively associated with mineral soil surface area (1 m2/g produces 0.018 year−1 increase in the degradation rate. The annual soil sequestration rate was calculated to increase from 1% to 6% when the soil total surface area increased from 1 to 9 m2/g of soil. Therefore, land application of biosolids is an effective way to enhance carbon sequestration in soils and reduce greenhouse gas emissions.

  12. High concentrations of polycyclic aromatic hydrocarbons found in water and sediments of car wash and Kisat areas of Winam Gulf, Lake Victoria-Kenya.

    Science.gov (United States)

    Kwach, B O; Lalah, J O

    2009-11-01

    Mean concentrations of selected USEPA priority polycyclic aromatic hydrocarbons (PAHs) in surface sediments and water samples from Car Wash and Kisat areas of Winam Gulf, Lake Victoria in Kenya have been determined using GC-FID and GC-MS. Sampling was done during the rainy season in April 2006. The PAH concentrations in sediment and water ranged from 0.04 to 31.95 microg/g dry weight and 3.32 to 55.8 microg/L, respectively, depending upon the sampling location. The total concentration levels of PAHs in both the sediment and water phase in this study were found to be much higher compared with those reported from other regions worldwide, revealing significant PAH pollution of Car Wash and Kisat areas of Kisumu city bay as a consequent of anthropogenic activities as described in the text. The GC-detected PAHs were confirmed by GC-MS.

  13. Separation and concentration of natural products by fast forced adsorption using well-dispersed velvet-like graphitic carbon nitride with response surface methodology optimisation.

    Science.gov (United States)

    Ding, Xinru; Zhu, Jun; Zhang, Yue; Xia, Qian; Bi, Wentao; Yang, Xiaodi; Yang, Jinfei

    2016-07-01

    Well-dispersed velvet-like graphitic carbon nitride nanoparticles with a large surface area were prepared and utilized for separation and concentration of bioactive compounds from fruit extracts by fast (20s) forced adsorption. The large surface area, enhanced non-covalent interactions of this nanoparticle with bioactive compounds and good dispersity in different solvents benefited its application as a good sorbent. To evaluate their adsorption capabilities, these carbon nitride nanoparticles were used for separation and concentration of flavonoids from fruit extracts by a forced-adsorption dispersive solid phase extraction method. The combined use of this nanoparticle and our experimental conditions showed excellent precision (3.6-4.7%) and sensitivity (limits of detection (S/N=3): 0.6-3.75ng/mL). This research provides an alternative strategy to prepare suitable sorbents for adsorption, separation and concentration of various compounds from different extracts. Copyright © 2016 Elsevier B.V. All rights reserved.

  14. Concentrations of organotin compounds in sediment and clams collected from coastal areas in Vietnam

    International Nuclear Information System (INIS)

    Midorikawa, Sayaka; Arai, Takaomi; Harino, Hiroya; Ohji, Madoka; Nguyen Duc Cu; Miyazaki, Nobuyuki

    2004-01-01

    Levels of butyltin (BT) and phenyltin (PT) compounds were determined in sediments and clam Meretrix spp. collected from north and central coastal areas in Vietnam. Concentrations of TBT in sediments ranged from 0.89 to 34 ng g -1 dry wt and those in clams ranged from 1.4 to 56 ng g -1 wet wt. The levels of TBT in sediments and clams from Vietnam were within limits reported from other countries. Further, the TBT level in clams was lower than the tolerable average residue level (TARL) estimated based on tolerable daily intake (TDI). Trace amounts of PTs were also found in both sediment and clam samples. In sediments from north and central Vietnam, the concentrations of TBT were highest in the order of Hue (28 ng g -1 dry wt), Cua Luc (15 ng g -1 dry wt), Sam Son (6.3 ng g -1 dry wt), and Tra Co (5.5 ng g -1 dry wt). Among the clams from north and central Vietnam, the levels of TBT in clams from Cua Luc were dramatically high at 47 ng g -1 wet wt. TBT formed the principal butyltin species in sediment at all sites studied. The ratios of TBT in sediment were higher among BT compounds at all study sites. Of total BTs, TBT was the dominant species in clams from almost all sites studied. In spatial distribution, TPT showed a pattern similar to TBT, suggesting the use of TPT as an antifouling paint. The partition coefficient between sediment and calms was calculated. The partition coefficients of TBT and TPT were 2.01 (0.56-5.5) and 9.23 (3.1-20), respectively. These results show that sediment-bound TBT is a source of contamination to clams in addition to dissolved TBT

  15. The influence of meteorological factors and biomass burning on surface ozone concentrations at Tanah Rata, Malaysia

    Science.gov (United States)

    Toh, Ying Ying; Lim, Sze Fook; von Glasow, Roland

    2013-05-01

    The surface ozone concentrations at the Tanah Rata regional Global Atmosphere Watch (GAW) station, Malaysia (4°28‧N, 101°23‧E, 1545 m above Mean Sea Level (MSL)) from June 2006 to August 2008 were analyzed in this study. Overall the ozone mixing ratios are very low; the seasonal variations show the highest mixing ratios during the Southwest monsoon (average 19.1 ppb) and lowest mixing ratios during the spring intermonsoon (average 14.2 ppb). The diurnal variation of ozone is characterised by an afternoon maximum and night time minimum. The meteorological conditions that favour the formation of high ozone levels at this site are low relative humidity, high temperature and minimum rainfall. The average ozone concentration is lower during precipitation days compared to non-precipitation days. The hourly averaged ozone concentrations show significant correlations with temperature and relative humidity during the Northeast monsoon and spring intermonsoon. The highest concentrations are observed when the wind is blowing from the west. We found an anticorrelation between the atmospheric pressure tide and ozone concentrations. The ozone mixing ratios do not exceed the recommended Malaysia Air Quality Guidelines for 1-h and 8-h averages. Five day backward trajectories on two high ozone episodes in 07 August 2006 (40.0 ppb) and 24 February 2008 (45.7 ppb) are computed using the HYbrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model to investigate the origin of the pollutants and influence of regional transport. The high ozone episode during 07 August 2006 (burning season during southwest monsoon) is mainly attributed to regional transport from biomass burning in Sumatra, whereas favourable meteorological conditions (i.e. low relative humidity, high temperature and solar radiation, zero rainfall) and long range transport from Indo-China have elevated the ozone concentrations during 24 February 2008.

  16. Temperature and concentration stratification effects on non-Newtonian fluid flow past a cylindrical surface

    Science.gov (United States)

    Rehman, Khalil Ur; Khan, Abid Ali; Malik, M. Y.; Zehra, Iffat; Ali, Usman

    The theme of present work is to report the numerical solution of mixed convection tangent hyperbolic fluid flow towards stretching cylindrical surface immersed in a double stratified media. The fluid flow is attained through no slip condition. The flow regime characteristics are modelled in terms of partial differential equations. A similarity transformation is used to transform partial differential equations into coupled non-linear ordinary differential equations. A computational algorithm is executed to predict numerical results. The effects of flow controlling parameters namely, mixed convection parameter, thermal stratification and solutal stratification parameters on velocity, temperature and concentration are examined and offered by means of graphical outcomes. It is noticed that in the presence of mixed convection effect both the fluid temperature and concentration are decreasing function of thermal stratification and solutal stratification parameters respectively. The obtained values are certified by developing comparison with existing values and an excellent agreement is observed which confirms the execution of computational algorithm.

  17. Estimating sub-surface dispersed oil concentration using acoustic backscatter response.

    Science.gov (United States)

    Fuller, Christopher B; Bonner, James S; Islam, Mohammad S; Page, Cheryl; Ojo, Temitope; Kirkey, William

    2013-05-15

    The recent Deepwater Horizon disaster resulted in a dispersed oil plume at an approximate depth of 1000 m. Several methods were used to characterize this plume with respect to concentration and spatial extent including surface supported sampling and autonomous underwater vehicles with in situ instrument payloads. Additionally, echo sounders were used to track the plume location, demonstrating the potential for remote detection using acoustic backscatter (ABS). This study evaluated use of an Acoustic Doppler Current Profiler (ADCP) to quantitatively detect oil-droplet suspensions from the ABS response in a controlled laboratory setting. Results from this study showed log-linear ABS responses to oil-droplet volume concentration. However, the inability to reproduce ABS response factors suggests the difficultly in developing meaningful calibration factors for quantitative field analysis. Evaluation of theoretical ABS intensity derived from the particle size distribution provided insight regarding method sensitivity in the presence of interfering ambient particles. Copyright © 2013 Elsevier Ltd. All rights reserved.

  18. Comparative analysis of surface soil moisture retrieval using VSWI and TVDI in karst areas

    Science.gov (United States)

    Yan, Hongbo; Zhou, Guoqing; Lu, Xianjian

    2015-12-01

    Vegetation Supply Water Index (VSWI) and Temperature Vegetation dryness Index (TVDI) are two most commonly used methods for surface soil moisture (SSM) retrieval using electromagnetic spectrum of visible, near infrared and thermal infrared band. Both of them take into account the effect of vegetation index (VI) and surface temperature (Ts) on SSM. A comparative analysis of the ability and effect of the two methods for SSM retrieval in karst areas was carried out, using the remote sensing data of Landsat 8 OLI_TIRS. The study area is located in Guilin, which is a typical karst area. The experimental results show that TVDI is more suitable for SSM retrieval in karst areas.

  19. Measurement of the radon exhalation rate from the medium surface by tracing the radon concentration

    International Nuclear Information System (INIS)

    Yanliang Tan; Detao Xiao

    2013-01-01

    The paper will present a method based on the accumulation chamber technique for measuring of radon exhalation from the medium surface. A radon monitor traces the change of radon concentration in the accumulation chamber, and then the radon exhalation can be obtained accurately through linear fit. Based on our recent experiments, the radon exhalation rate from the medium surface obtained from this method is in good agreement with the actual exhalation rate of our simulation facility. This method is superior to the competition method which obtains the radon exhalation through the exponential fit by an external PC-system. The calculation for the exponential fit is very easy by computer and related software. However, for portable instruments, the single chip microcomputer can't calculate the exponential fit rapidly. Thus, this method is usable for developing the new portable instrument to classify building materials, etc. (author)

  20. Influence of Ecological Factors on Estimation of Impervious Surface Area Using Landsat 8 Imagery

    Directory of Open Access Journals (Sweden)

    Yuqiu Jia

    2017-07-01

    Full Text Available Estimation of impervious surface area is important to the study of urban environments and social development, but surface characteristics, as well as the temporal, spectral, and spatial resolutions of remote sensing images, influence the estimation accuracy. To investigate the effects of regional environmental characteristics on the estimation of impervious surface area, we divided China into seven sub-regions based on climate, soil type, feature complexity, and vegetation phenology: arid and semi-arid areas, Huang-Huai-Hai winter wheat production areas, typical temperate regions, the Pearl River Delta, the middle and lower reaches of the Yangtze River, typical tropical and subtropical regions, and the Qinghai Tibet Plateau. Impervious surface area was estimated from Landsat 8 images of five typical cities, including Yinchuan, Shijiazhuang, Shenyang, Ningbo, and Kunming. Using the linear spectral unmixing method, impervious and permeable surface areas were determined at the pixel-scale based on end-member proportions. We calculated the producer’s accuracy, user’s accuracy, and overall accuracy to assess the estimation accuracy, and compared the accuracies among images acquired from different seasons and locations. In tropical and subtropical regions, vegetation canopies can confound the identification of impervious surfaces and, thus, images acquired in winter, early spring, and autumn are most suitable; estimations in the Pearl River Delta, the middle and lower reaches of the Yangtze River are influenced by soil, vegetation phenology, vegetation canopy, and water, and images acquired in spring, summer, and autumn provide the best results; in typical temperate areas, images acquired from spring to autumn are most effective for estimations; in winter wheat-growing areas, images acquired throughout the year are suitable; and in arid and semi-arid areas, summer and early autumn, during which vegetation is abundant, are the optimal seasons for

  1. Reducing surface water total and methyl mercury concentrations and bioavailability using a coagulation-wetland system

    Science.gov (United States)

    Kraus, T. E.; Fleck, J.; Henneberry, Y. K.; Stumpner, E. B.; Krabbenhoft, D. P.; Bachand, P.; Randall, P.

    2013-12-01

    With the recent passage of laws regulating concentrations and loads of mercury (Hg) in surface waters, there is a need to develop management practices that will reduce the export of Hg from both point and non-point sources. Coagulation with metal based salts to remove particles and dissolved organic matter (DOM) from solution is a practice commonly employed by drinking water utilities. Because dissolved Hg is associated with particles and DOM, it follows that Hg should also be removed during the coagulation process and end up associated with the organo-metal precipitate, termed flocculate (floc). The effectiveness of iron- and aluminum-based coagulants for removing both inorganic and methyl mercury (IHg and MeHg, respectively) from solution was demonstrated in laboratory studies conducted on agricultural drainage waters of the Sacramento-San Joaquin Delta: dissolved concentrations of MeHg decreased by 80% while IHg decreased by 97% following coagulation. To test the field application of this technology, samples were collected from the inflows and outflows of wetland treatment cells constructed in the central Delta of California. This replicated field experiment includes three replicates each of three inflow waters treatments: (1) iron sulfate addition, (2) polyaluminum chloride addition, and (3) untreated controls. Water entering and exiting the nine treatment cells was sampled approximately monthly over a 1-year period for total Hg and MeHg in both the dissolved and particulate aqueous phases. Initial results confirm that coagulant addition is removing Hg (total and methyl, particulate and dissolved) from solution and sequestering it in the floc. Seasonal effects on DOM concentration and other factors appear to effect whether passage through the wetland cells alters surface water dissolved organic carbon (DOC) and Hg concentrations. Related studies will examine whether the presence of the floc affects the production and fate of MeHg within the wetland cells. If

  2. CLPX-Satellite: EO-1 Hyperion Surface Reflectance, Snow-Covered Area, and Grain Size

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set consists of apparent surface reflectance, subpixel snow-covered area and grain size collected from the Hyperion hyperspectral imager. The Hyperion...

  3. Two-group interfacial area concentration correlations of two-phase flows in large diameter pipes

    International Nuclear Information System (INIS)

    Shen, Xiuzhong; Hibiki, Takashi

    2015-01-01

    The reliable empirical correlations and models are one of the important ways to predict the interfacial area concentration (IAC) in two-phase flows. However, up to now, no correlation or model is available for the prediction of the IAC in the two-phase flows in large diameter pipes. This study collected an IAC experimental database of two-phase flows taken under various flow conditions in large diameter pipes and presented a systematic way to predict the IAC for two-phase flows from bubbly, cap-bubbly to churn flow in large diameter pipes by categorizing bubbles into two groups (group-1: spherical and distorted bubble, group-2: cap bubble). Correlations were developed to predict the group-1 void fraction from the void fraction of all bubble. The IAC contribution from group-1 bubbles was modeled by using the dominant parameters of group-1 bubble void fraction and Reynolds number based on the parameter-dependent analysis of Hibiki and Ishii (2001, 2002) using one-dimensional bubble number density and interfacial area transport equations. A new drift velocity correlation for two-phase flow with large cap bubbles in large diameter pipes was derived in this study. By comparing the newly-derived drift velocity correlation with the existing drift velocity correlation of Kataoka and Ishii (1987) for large diameter pipes and using the characteristics of the representative bubbles among the group 2 bubbles, we developed the model of IAC and bubble size for group 2 cap bubbles. The developed models for estimating the IAC are compared with the entire collected database. A reasonable agreement was obtained with average relative errors of ±28.1%, ±54.4% and ±29.6% for group 1, group 2 and all bubbles respectively. (author)

  4. Interdependence between body surface area and ultraviolet B dose in vitamin D production

    DEFF Research Database (Denmark)

    Bogh, M K B; Schmedes, Anne; Philipsen, P A

    2011-01-01

    Ultraviolet (UV) B radiation increases serum vitamin D level expressed as 25-hydroxyvitamin-D(3) [25(OH)D], but the relationship to body surface area and UVB dose needs investigation.......Ultraviolet (UV) B radiation increases serum vitamin D level expressed as 25-hydroxyvitamin-D(3) [25(OH)D], but the relationship to body surface area and UVB dose needs investigation....

  5. Changes in the intestinal microvillous surface area during reproduction and ageing in the female rat.

    OpenAIRE

    Pénzes, L; Regius, O

    1985-01-01

    A morphometric study has been undertaken of the changes that occur in the microvillous surface area of young, pregnant, lactating, old and senescent rats. It has been shown that the microvilli are organelles with a quite stable conformation and that they exhibit no large scale dimensional changes throughout almost the entire life span. Lactation, however, does induce an apparent increase in microvillous surface area which may be associated with the significant changes which occur to the struc...

  6. Relationship between specific surface area and spatial correlation functions for anisotropic porous media

    Energy Technology Data Exchange (ETDEWEB)

    Berryman, J.G.

    1987-01-01

    A result of Debye, Anderson, and Brumberger (P. Debye, H. R. Anderson, Jr., and H. Brumberger, J. Appl. Phys. 28, 679 (1957)) for isotropic porous media states that the derivative of the two-point spatial correlation at the origin is equal to minus one-quarter of the specific surface area. This result is generalized for nonisotropic media by noting that the angular average of the anisotropic two-point spatial correlation function has the same relationship to the specific surface area.

  7. Persistent Organic Pollutants and Heavy Metal Concentrations in Soil from the Metropolitan Area of Monterrey, Nuevo Leon, Mexico.

    Science.gov (United States)

    Orta-García, Sandra Teresa; Ochoa-Martinez, Angeles Catalina; Carrizalez-Yáñez, Leticia; Varela-Silva, José Antonio; Pérez-Vázquez, Francisco Javier; Pruneda-Álvarez, Lucia Guadalupe; Torres-Dosal, Arturo; Guzmán-Mar, Jorge Luis; Pérez-Maldonado, Iván N

    2016-04-01

    The purpose of this study was to assess the levels of polybrominated diphenyl ethers (PBDEs), polychlorinated biphenyls (PCBs), dichlorodiphenyltrichloroethane (DDT), dichlorodiphenyldichloroethane (DDE), and four heavy metals (arsenic, cadmium, and lead) in outdoor surface soils (50 samples) collected from the metropolitan area of Monterrey in Mexico. Total PBDEs levels ranged from 1.80 to 127 µg/kg, with mean total PBDEs level of 14.2 ± 21.5 µg/kg (geometric mean ± standard deviation). For PCBs, the mean total level in the studied soils was 23.5 ± 20.2 µg/kg (range 4.0-65.5 µg/kg). An important finding in our study was that all soil samples (100%) had detectable levels of the metabolite p,p'-DDE. Moreover, the mean total DDT level (∑p'p-DDT and p'p-DDE) was approximately 132 ± 175 µg/kg. The mean levels for arsenic, cadmium, and lead in soil were 5.30 ± 1.35 (range 1.55-7.85) mg/kg, 2.20 ± 1.20 (range 0.65-6.40) mg/kg, and 455 ± 204 (range 224-1230) mg/kg, respectively. Our study has several limitations, the most notable of which is the small sample of soils evaluated. However, this screening study provided concentration data for the occurrence of POPs and four heavy metals in soil from the metropolitan area of Monterrey, Nuevo Leon, Mexico, and taking into consideration that soil is an important pathway of exposure for people, a biomonitoring program for the surveillance of the general population in the metropolitan area of Monterrey, Nuevo Leon is deemed necessary.

  8. Atmospheric particulate matter size distribution and concentration in West Virginia coal mining and non-mining areas.

    Science.gov (United States)

    Kurth, Laura M; McCawley, Michael; Hendryx, Michael; Lusk, Stephanie

    2014-07-01

    People who live in Appalachian areas where coal mining is prominent have increased health problems compared with people in non-mining areas of Appalachia. Coal mines and related mining activities result in the production of atmospheric particulate matter (PM) that is associated with human health effects. There is a gap in research regarding particle size concentration and distribution to determine respiratory dose around coal mining and non-mining areas. Mass- and number-based size distributions were determined with an Aerodynamic Particle Size and Scanning Mobility Particle Sizer to calculate lung deposition around mining and non-mining areas of West Virginia. Particle number concentrations and deposited lung dose were significantly greater around mining areas compared with non-mining areas, demonstrating elevated risks to humans. The greater dose was correlated with elevated disease rates in the West Virginia mining areas. Number concentrations in the mining areas were comparable to a previously documented urban area where number concentration was associated with respiratory and cardiovascular disease.

  9. Lake Chad Total Surface Water Area as Derived from Land Surface Temperature and Radar Remote Sensing Data

    Directory of Open Access Journals (Sweden)

    Frederick Policelli

    2018-02-01

    Full Text Available Lake Chad, located in the middle of the African Sahel belt, underwent dramatic decreases in the 1970s and 1980s leaving less than ten percent of its 1960s surface water extent as open water. In this paper, we present an extended record (dry seasons 1988–2016 of the total surface water area of the lake (including both open water and flooded vegetation derived using Land Surface Temperature (LST data (dry seasons 2000–2016 from the NASA Terra MODIS sensor and EUMETSAT Meteosat-based LST measurements (dry seasons 1988–2001 from an earlier study. We also examine the total surface water area for Lake Chad using radar data (dry seasons 2015–2016 from the ESA Sentinel-1a mission. For the limited number of radar data sets available to us (18 data sets, we find on average a close match between the estimates from these data and the corresponding estimates from LST, though we find spatial differences in the estimates using the two types of data. We use these spatial differences to adjust the record (dry seasons 2000–2016 from MODIS LST. Then we use the adjusted record to remove the bias of the existing LST record (dry seasons 1988–2001 derived from Meteosat measurements and combine the two records. From this composite, extended record, we plot the total surface water area of the lake for the dry seasons of 1988–1989 through 2016–2017. We find for the dry seasons of 1988–1989 to 2016–2017 that the maximum total surface water area of the lake was approximately 16,800 sq. km (February and May, 2000, the minimum total surface water area of the lake was approximately 6400 sq. km (November, 1990, and the average was approximately 12,700 sq. km. Further, we find the total surface water area of the lake to be highly variable during this period, with an average rate of increase of approximately 143 km2 per year.

  10. Geohydrology and susceptibility of major aquifers to surface contamination in Alabama, area 7

    Science.gov (United States)

    Mooty, W.S.

    1987-01-01

    The geohydrology and susceptibility of the seven major aquifers to surface contamination in Area 7 - Bibb, Dallas, Hale, Perry, and Wilcox Counties, are described. Aquifers in the northern part of the study area are in Paleozoic limestones and dolomite formations. Deposits in the central part of the study area are predominately of Cretaceous age and contain the Coker, Gordo, and Eutaw aquifers. Although the southern part of the study area has many deposits of Tertiary age, the Ripley Formation of Cretaceous age is the major aquifer. Contamination of any of the major aquifers is improbable because the majority of the recharge area for the primary aquifers is woodland, pasture, or farmland. Downdip from their outcrops, the major aquifers in the study area are protected from land surface contamination by relatively impermeable layers of clay and chalk. The aquifers that are highly susceptible to contamination are the ones in the limestone and dolomite formations in northern Bibb County. Sinkholes exist in the recharge area of these formations and could provide a direct link for contaminates from the land surface to the water table. An area northeast of the Selma well field is also highly susceptible to contamination. The Eutaw Formation in this area is overlain by alluvial deposits that could increase recharge to the aquifer by slowing the runoff rate of surface water. (USGS)

  11. Activities concentration of 239+240Pu in sediment in Sabah and Sarawak coastal area

    International Nuclear Information System (INIS)

    Jalal Sharib; Zaharudin Ahmad; Yii Mei Wo; Ahmad Sanadi Abu Bakar; Norfaizal Mohamed; Kamarozaman Ishak; Zulkifli Daud

    2008-08-01

    The determination of plutonium, 239+240 Pu activity concentration and their distributions along the coastal area of the Sabah and Sarawak have been performed using alpha spectrometry counting system. The sampling coastal sediment for this study was carried out in July 2004 as part of the Marine Radioactivity Database Development Project for Malaysia. This results show that the distribution of Plutonium, 239+240 Pu radionuclides in coastal sediment is consistent, their activities are depending on the sampling locations. Generally, the 239+240 Pu activities measured in Sabah and Sarawak coastal sediment are in the range of BDL - 1.83 Bq/kg and 0.11 - 0.841 Bq/kg dry weights, respectively. The sampling stations, Persisiran Lubok Sabanan, SB 15 and Sungai Similajau, SR 13 showed the highest plutonium, 239+240 Pu radionuclides isotopes activity in Sabah and Sarawak. Meanwhile, these two stations shows higher activity compare to West Coast of Peninsular of Malaysia station for the Marine Radioactivity Database Development Project for Malaysia. (Author)

  12. Changes in Thickness and Surface Area of the Human Cortex and Their Relationship with Intelligence

    NARCIS (Netherlands)

    Schnack, Hugo G.; Van Haren, Neeltje E M; Brouwer, Rachel M.; Evans, Alan; Durston, Sarah; Boomsma, Dorret I.; Kahn, René S.; Hulshoff Pol, Hilleke E.

    2015-01-01

    Changes in cortical thickness over time have been related to intelligence, but whether changes in cortical surface area are related to general cognitive functioning is unknown. We therefore examined the relationship between intelligence quotient (IQ) and changes in cortical thickness and surface

  13. Greenland surface mass-balance observations from the ice-sheet ablation area and local glaciers

    DEFF Research Database (Denmark)

    Machguth, Horst; Thomsen, Henrik H.; Weidick, Anker

    2016-01-01

    Glacier surface mass-balance measurements on Greenland started more than a century ago, but no compilation exists of the observations from the ablation area of the ice sheet and local glaciers. Such data could be used in the evaluation of modelled surface mass balance, or to document changes in g...

  14. Greenland surface mass-balance observations from the ice-sheet ablation area and local glaciers

    NARCIS (Netherlands)

    Machguth, Horst; Thomsen, Henrik H.; Weidick, Anker; Ahlstrøm, Andreas P.; Abermann, Jakob; Andersen, Morten L.; Andersen, Signe B.; Bjørk, Anders A.; Box, Jason E.; Braithwaite, Roger J.; Bøggild, Carl E.; Citterio, Michele; Clement, Poul; Colgan, William; Fausto, Robert S.; Gleie, Karin; Gubler, Stefanie; Hasholt, Bent; Hynek, Bernhard; Knudsen, Niels T.; Larsen, Signe H.; Mernild, Sebastian H.; Oerlemans, Johannes; Oerter, Hans; Olesen, Ole B.; Smeets, C. J P Paul; Steffen, Konrad; Stober, Manfred; Sugiyama, Shin; Van As, Dirk; Van Den Broeke, Michiel R.; Van De Wal, Roderik S W

    2016-01-01

    Glacier surface mass-balance measurements on Greenland started more than a century ago, but no compilation exists of the observations from the ablation area of the ice sheet and local glaciers. Such data could be used in the evaluation of modelled surface mass balance, or to document changes in

  15. Spatial pattern of hormone and antibiotic concentrations in surface waters in Delaware

    Science.gov (United States)

    Vaicunas, R.; Inamdar, S. P.; Dutta, S.; Aga, D.; Zimmerman, L. R.

    2011-12-01

    Water quality surveys of the U.S. have confirmed the presence of hormones and antibiotics in some surface waters. Although the reported concentrations of these substances are extremely low, there is substantial concern about their effect on aquatic species. For example, chronic exposure to estradiol (E2β) concentrations as low as 40 ng/L have been shown to cause endocrine disruption in fish. Furthermore, there is potential for contaminants to enter our drinking supply. Significant sources of hormones and antibiotics include discharge from concentrated animal feeding operations (CAFOs) and wastewater treatment plants as well as runoff from agricultural land receiving application of animal manure. Since Sussex County, Delaware is one of the leading poultry producing counties in the nation, and many farmers in the state use poultry litter as fertilizer for their crops, it is critical to study the concentrations of contaminants in surface waters. Fifty surface water (streams, lakes, and ponds) sampling locations throughout the state of Delaware were chosen based on DNREC (Delaware Department of Natural Resources and Environmental Control) data. Locations with the highest nitrogen and phosphorus levels were assumed to be associated with agriculture and wastewater sources and therefore were likely to be contaminated with hormones and antibiotics. The first set of sampling occurred in April representing high-flow conditions, and the second set will occur in September representing low-flow conditions. Water samples will be screened through the cost-effective enzyme-linked immunosorbent assay (ELISA) method followed by more rigorous analyses of selected samples using liquid chromatography-mass spectrometry (LC/MS/MS). ELISA screening includes estradiol (E2β), sulfamethazine and triclosan, while LC/MS/MS will quantify both free and conjugated forms of estrone (E1), estradiol (E2β), estriol (E3), as well as selected sulfa and tetracycline antibiotics. Initial ELISA results

  16. Concentrations and sources of polycyclic aromatic hydrocarbons in surface coastal sediments of the northern Gulf of Mexico

    Science.gov (United States)

    2014-01-01

    Background Coastal sediments in the northern Gulf of Mexico have a high potential of being contaminated by petroleum hydrocarbons, such as polycyclic aromatic hydrocarbons (PAHs), due to extensive petroleum exploration and transportation activities. In this study we evaluated the spatial distribution and contamination sources of PAHs, as well as the bioavailable fraction in the bulk PAH pool, in surface marsh and shelf sediments (top 5 cm) of the northern Gulf of Mexico. Results PAH concentrations in this region ranged from 100 to 856 ng g−1, with the highest concentrations in Mississippi River mouth sediments followed by marsh sediments and then the lowest concentrations in shelf sediments. The PAH concentrations correlated positively with atomic C/N ratios of sedimentary organic matter (OM), suggesting that terrestrial OM preferentially sorbs PAHs relative to marine OM. PAHs with 2 rings were more abundant than those with 5–6 rings in continental shelf sediments, while the opposite was found in marsh sediments. This distribution pattern suggests different contamination sources between shelf and marsh sediments. Based on diagnostic ratios of PAH isomers and principal component analysis, shelf sediment PAHs were petrogenic and those from marsh sediments were pyrogenic. The proportions of bioavailable PAHs in total PAHs were low, ranging from 0.02% to 0.06%, with higher fractions found in marsh than shelf sediments. Conclusion PAH distribution and composition differences between marsh and shelf sediments were influenced by grain size, contamination sources, and the types of organic matter associated with PAHs. Concentrations of PAHs in the study area were below effects low-range, suggesting a low risk to organisms and limited transfer of PAHs into food web. From the source analysis, PAHs in shelf sediments mainly originated from direct petroleum contamination, while those in marsh sediments were from combustion of fossil fuels. PMID:24641695

  17. Variability of pesticides and nitrates concentrations along a river transect: chemical and isotopic evidence of groundwater - surface water interconnections

    Science.gov (United States)

    Baran, Nicole; Petelet-Giraud, Emmanuelle; Saplairoles, Maritxu

    2015-04-01

    Groundwater quality is increasingly monitored in Europe where various levels of nitrate and pesticide and/or metabolite contamination have been demonstrated (Loos et al., 2010, Stuart et al., 2012). The Groundwater Daughter Directive (2006/118/EC) to Water Framework Directive (WFD) particularly requires measures to prevent or limit inputs of pollutants into groundwater and compliance with good chemical status criteria (based on EU standards of nitrate and pesticides). The WFD mentioned the need to protect groundwater but also to have a particular regard to its impact and interrelationship with associated surface waters and directly dependent terrestrial Ecosystems. The Ariège river basin (SW France - 538 km²) is an alluvial plain under high agricultural pressure leading to a contamination of the aquifer by several pesticides and metabolites (Amalric et al., 2013). The Crieu is an allochtone river, crossing the plain (~ 10 km length) before joining the Ariège River. The Crieu is often dry in its middle section suggesting water leakage from surface water towards groundwater. At the opposite, the permanent flow observed downstream suggests an input of groundwater into surface water. In May 2014, while the Crieu flow was continuous through the plain, 7 river samples were collected and analyzed for pesticides, major ions, strontium concentration and isotopes. In situ measurements of electric conductivity were also performed as well as flow gauging. Two groundwaters close to the river were also sampled. The flow gauging measurements show a decreasing river discharge in the central area of the Crieu River, suggesting surface water leakage towards groundwater. Nevertheless, the electric conductivity increases along the river flow as well as some pesticides and nitrates concentrations. This chemical evolution of the river water is thus inconsistent with a simple water infiltration and another source of dissolved solutes is required to explain the increased of

  18. Estimation of cerebral surface area using vertical sectioning and magnetic resonance imaging: a stereological study.

    Science.gov (United States)

    Acer, Niyazi; Cankaya, Mehmet Niyazi; Işçi, Oznur; Baş, Orhan; Camurdanoğlu, Mehmet; Turgut, Mehmet

    2010-01-15

    Stereological techniques using isotropic uniform random and vertical uniform random sections have been used for surface area estimation. However, there are a few studies in which the surface area of the brain is estimated using the vertical section technique in a stereological approach. The objective of the current study was to apply the vertical section technique using cycloid test probes for estimation of cerebral surface area in magnetic resonance imaging (MRI). In this study, cerebral surface areas were estimated in a total of 13 young subjects (6 males, 7 females) who were free of any neurological symptoms and signs. The means (+/-S.D.) of the surface areas were 1619.92+/-140. 97 cm (2), 1625.69+/-147. 58 cm(2) and 1674.69+/-160. 60 cm(2) for 36, 18 and 12 vertical sections, respectively. The mean coefficient of error obtained by applying cycloid test lines that use a 2. 8-cm ratio of area associated with each cycloid was estimated at 0.05). In addition, the three models correlated well with each other. From these results, it is concluded that the vertical section technique is an unbiased, efficient and reliable method and is ideally suited to in vivo examination of MRI data for estimating the surface area of the brain. Hence, we suggest that estimation of surface area using MRI and stereology may be clinically relevant for assessing cortical atrophy as well as for investigating the structure and function of cerebral hemispheres. Copyright 2009 Elsevier B.V. All rights reserved.

  19. Application of stereological methods to estimate post-mortem brain surface area using 3T MRI

    DEFF Research Database (Denmark)

    Furlong, Carolyn; García-Fiñana, Marta; Puddephat, Michael

    2013-01-01

    The Cavalieri and Vertical Sections methods of design based stereology were applied in combination with 3 tesla (i.e. 3T) Magnetic Resonance Imaging (MRI) to estimate cortical and subcortical volume, area of the pial surface, area of the grey-white matter boundary, and thickness of the cerebral c...

  20. Bayesian Estimation of the Active Concentration and Affinity Constants Using Surface Plasmon Resonance Technology.

    Directory of Open Access Journals (Sweden)

    Feng Feng

    Full Text Available Surface plasmon resonance (SPR has previously been employed to measure the active concentration of analyte in addition to the kinetic rate constants in molecular binding reactions. Those approaches, however, have a few restrictions. In this work, a Bayesian approach is developed to determine both active concentration and affinity constants using SPR technology. With the appropriate prior probabilities on the parameters and a derived likelihood function, a Markov Chain Monte Carlo (MCMC algorithm is applied to compute the posterior probability densities of both the active concentration and kinetic rate constants based on the collected SPR data. Compared with previous approaches, ours exploits information from the duration of the process in its entirety, including both association and dissociation phases, under partial mass transport conditions; do not depend on calibration data; multiple injections of analyte at varying flow rates are not necessary. Finally the method is validated by analyzing both simulated and experimental datasets. A software package implementing our approach is developed with a user-friendly interface and made freely available.

  1. Simultaneous measurement of gas concentration and temperature by the ball surface acoustic wave sensor

    Science.gov (United States)

    Yamanaka, Kazushi; Akao, Shingo; Takeda, Nobuo; Tsuji, Toshihiro; Oizumi, Toru; Tsukahara, Yusuke

    2017-07-01

    We have developed a ball surface acoustic wave (SAW) trace moisture sensor with an amorphous silica sensitive film and realized wide-range measurement from 0.017 ppmv [a frost point (FP) of -99 °C] to 6.0 × 103 ppmv (0 °C FP). However, since the sensitivity of the sensor depends on the temperature, measurement results are disturbed when the temperature largely changes. To overcome this problem, we developed a method to simultaneously measure temperature and gas concentration using a ball SAW sensor. Temperature and concentration is derived by solving equations for the delay time change at two frequencies. When the temperature had a large jump, the delay time change was significantly disturbed, but the water concentration was almost correctly measured, by compensating the sensitivity change using measured temperature. The temperature measured by a ball SAW sensor will also be used to control the ball temperature. This method will make a ball SAW sensor reliable in environments of varying temperatures.

  2. Estimate of main local sources to ambient ultrafine particle number concentrations in an urban area

    Science.gov (United States)

    Rahman, Md Mahmudur; Mazaheri, Mandana; Clifford, Sam; Morawska, Lidia

    2017-09-01

    Quantifying and apportioning the contribution of a range of sources to ultrafine particles (UFPs, D urban environments. Although vehicular emissions have long been considered one of the major sources of ultrafine particles in urban areas, the contribution of other major urban sources is not yet fully understood. This paper aims to determine and quantify the contribution of local ground traffic, nucleated particle (NP) formation and distant non-traffic (e.g. airport, oil refineries, and seaport) sources to the total ambient particle number concentration (PNC) in a busy, inner-city area in Brisbane, Australia using Bayesian statistical modelling and other exploratory tools. The Bayesian model was trained on the PNC data on days where NP formations were known to have not occurred, hourly traffic counts, solar radiation data, and smooth daily trend. The model was applied to apportion and quantify the contribution of NP formations and local traffic and non-traffic sources to UFPs. The data analysis incorporated long-term measured time-series of total PNC (D ≥ 6 nm), particle number size distributions (PSD, D = 8 to 400 nm), PM2.5, PM10, NOx, CO, meteorological parameters and traffic counts at a stationary monitoring site. The developed Bayesian model showed reliable predictive performances in quantifying the contribution of NP formation events to UFPs (up to 4 × 104 particles cm- 3), with a significant day to day variability. The model identified potential NP formation and no-formations days based on PNC data and quantified the sources contribution to UFPs. Exploratory statistical analyses show that total mean PNC during the middle of the day was up to 32% higher than during peak morning and evening traffic periods, which were associated with NP formation events. The majority of UFPs measured during the peak traffic and NP formation periods were between 30-100 nm and smaller than 30 nm, respectively. To date, this is the first application of Bayesian model to

  3. Total iron concentrations in waters and fish tissues in the Nam Theun 2 Reservoir area (Lao PDR).

    Science.gov (United States)

    Cottet, Maud; Descloux, Stéphane; Guédant, Pierre; Godon, Arnaud; Cerdan, Philippe; Vigouroux, Régis

    2015-08-01

    Data on total iron concentrations in waters and freshwater fish tissues in man-made reservoirs are scarce, especially in Southeast Asia. Changes in total iron concentrations in water and in fish tissues were studied after the impoundment of the Nam Theun 2 Reservoir (central Lao PDR). Water quality parameters were monitored at 11 stations (reservoir, upstream area and downstream areas) from 2008 to 2010. In 2009 and 2010, total iron concentrations were measured in three different fish tissues (viscera, gills and flesh) from 14 species belonging to the omnivorous and carnivorous feeding groups. The results indicated that iron concentrations in the water were influenced by the reservoir impoundment during the first year after the creation of the reservoir. Intra-annual variations of the total iron concentration in these waters appeared to be driven by the soil leaching processes mainly during the wet season. In fish, total iron accumulated preferentially in viscera, followed by gills and flesh. Iron concentration was highly species dependant and related to the ecology of the species whereas feeding habits (omnivorous or carnivorous) did not influence total iron concentration in fish tissues. Finally, reservoir impoundment did not affect iron concentrations in fish from the reservoir and from both downstream areas.

  4. Large Differences between Glaciers 3D Surface Extents and 2D Planar Areas in Central Tianshan

    Directory of Open Access Journals (Sweden)

    Xianwei Wang

    2017-04-01

    Full Text Available Most glaciers in China lie in high mountainous environments and have relatively large surface slopes. Common analyses consider glaciers’ projected areas (2D Area in a two-dimensional plane, which are much smaller than glacier’s topographic surface extents (3D Area. The areal difference between 2D planar areas and 3D surface extents exceeds −5% when the glacier’s surface slope is larger than 18°. In this study, we establish a 3D model in the Muzart Glacier catchment using ASTER GDEM data. This model is used to quantify the areal difference between glaciers’ 2D planar areas and their 3D surface extents in various slope zones and elevation bands by using the second Chinese Glacier Inventory (CGI2. Finally, we analyze the 2D and 3D area shrinking rate between 2007 and 2013 in Central Tianshan using glaciers derived from Landsat images by an object-based classification approach. This approach shows an accuracy of 89% when it validates by comparison of glaciers derived from Landsat and high spatial resolution GeoEye images. The extracted glaciers in 2007 also have an agreement of 89% with CGI2 data in the Muzart Glacier catchment. The glaciers’ 3D area is 34.2% larger than their 2D area from CGI2 in the Muzart Glacier catchment and by 27.9% in the entire Central Tianshan. Most underestimation occurs in the elevation bands of 4000–5000 m above sea level (a.s.l.. The 3D glacier areas reduced by 30 and 115 km2 between 2007 and 2013 in the Muzart Glacier catchment and Central Tianshan, being 37.0% and 27.6% larger than their 2D areas reduction, respectively. The shrinking rates decrease with elevation increase.

  5. Greenland surface mass-balance observations from the ice-sheet ablation area and local glaciers

    DEFF Research Database (Denmark)

    Machguth, Horst; Thomsen, Henrik H.; Weidick, Anker

    2016-01-01

    Glacier surface mass-balance measurements on Greenland started more than a century ago, but no compilation exists of the observations from the ablation area of the ice sheet and local glaciers. Such data could be used in the evaluation of modelled surface mass balance, or to document changes...... in glacier melt independently from model output. Here, we present a comprehensive database of Greenland glacier surface mass-balance observations from the ablation area of the ice sheet and local glaciers. The database spans the 123 a from 1892 to 2015, contains a total of similar to 3000 measurements from......-term time series of which there are only two exceeding 20 a. We use the data to analyse uncertainties in point measurements of surface mass balance, as well as to estimate surface mass-balance profiles for most regions of Greenland....

  6. Concentration of radiocesium in rice, vegetables, and fruits cultivated in the evacuation area in Okuma Town, Fukushima

    International Nuclear Information System (INIS)

    Kenji Ohse; Kyo Kitayama; Akira Kanno; Chika Suzuki; Kencho Kawatsu; Hirofumi Tsukada

    2015-01-01

    Radiocesium concentration in the crops cultivated in contaminated and decontaminated soils in the evacuation area were measured. The radiocesium concentration in the decontaminated soil decreased approximately one-quarter to that in the contaminated soil. The radiocesium concentration in the rice and vegetables cultivated in the decontaminated soil decreased to one-half to tenth of that in the contaminated soil. Except for eggplant and pumpkin cultivated in the decontaminated field, the radiocesium concentration in crops was higher than the standard limit in foods in Japan. The obtained transfer factors of most crops were within the reported values. (author)

  7. Spatial distribution of ground-level urban background O3 concentrations in the Metropolitan Area of Buenos Aires, Argentina

    International Nuclear Information System (INIS)

    Pineda Rojas, Andrea L.; Venegas, Laura E.

    2013-01-01

    In this work, a recently developed urban-scale atmospheric dispersion model (DAUMOD-GRS) is applied to evaluate the ground-level ozone (O 3 ) concentrations resulting from anthropogenic area sources of NO x and VOC in the Metropolitan Area of Buenos Aires (MABA). The statistical comparison of model results with observations (including new available data from seventeen sites) shows a good model performance. Estimated summer highest diurnal O 3 1-h concentrations in the MABA vary between 15 ppb in the most urbanised area and 53 ppb in the suburbs. All values are below the air quality standard. Several runs are performed to evaluate the impact of possible future emission reductions on O 3 concentrations. Under all hypothetical scenarios, the maximum diurnal O 3 1-h concentration obtained for the area is slightly reduced (up to 4%). However, maximum diurnal O 3 concentrations could increase at some less urbanised areas of MABA depending on the relative reductions of the emissions of NO x and VOC. -- Highlights: ► A recently developed air quality model reproduces well observed O 3 levels in MABA. ► Modelled summer maximum diurnal O 3 concentrations vary in the area between 15 and 53 ppb. ► All hourly values are below the air quality standard (120 ppb). ► Possible future emission reductions would have small impact on the highest level. -- The distribution of summer maximum diurnal ground-level O 3 concentrations in the Metropolitan Area of Buenos Aires is evaluated applying a recently developed simple urban air quality model

  8. New Caledonia surface lagoon chlorophyll modeling as coastal reef area health indicator

    Science.gov (United States)

    Fuchs, R.; Pinazo, C.; Douillet, P.; Dupouy, C.; Faure, V.; Mangin, A.

    2010-10-01

    The major part of the New Caledonia (NC) lagoon was classified as UNESCO Natural Site of Humanity Patrimony. Indeed, 22 175 km2 of tropical coral lagoon area exhibit high biodiversity. The NC lagoon is semi enclosed and connected to the Coral Sea through a barrier reef segmented by narrow passes. The environment is oligotrophic, due to important flush during trade winds events, and bathymetry is highly variable. In order to predict eutrophication events, we used an extension of a 3D coupled physical-biogeochemical model recently developed on NC south western lagoon. The model is based on the Nitrogen and Carbon cycles, relating the variable stoechiometry of the elements in each biological compartment. The ecological model was developed to include an explicit description of the microbial loop. The resulting coupled model, forced by tide, wind, light, temperature and freshwater inputs, was used to calculate phytoplankton biomass, bacterial production, dissolved organic matter concentrations and nutrient recycling. Here we present results issued from the 3D coupled model ECO3M_LAGOON (biogeochemical, LOPB-IRD) and MARS3D (regional physical model, IFREMER-IRD) describing spatial and temporal interactions between water motion and biology, on larger domain including reef barrier and water exchanges through ocean-lagoon interface. To validate physical processes in the lagoon we used in situ data collected during field cruise (ValHyBio 2008, La Niña episode). Surface chlorophyll concentrations are compared with water color data from ValHyBio cruise and satellite data (MODIS/MERIS) corrected from bathymetry effects.

  9. Planar spatial correlations, anisotropy, and specific surface area of stationary random porous media

    International Nuclear Information System (INIS)

    Berryman, J.G.

    1998-01-01

    An earlier result of the author showed that an anisotropic spatial correlation function of a random porous medium could be used to compute the specific surface area when it is stationary as well as anisotropic by first performing a three-dimensional radial average and then taking the first derivative with respect to lag at the origin. This result generalized the earlier result for isotropic porous media of Debye et al. [J. Appl. Phys. 28, 679 (1957)]. The present article provides more detailed information about the use of spatial correlation functions for anisotropic porous media and in particular shows that, for stationary anisotropic media, the specific surface area can be related to the derivative of the two-dimensional radial average of the correlation function measured from cross sections taken through the anisotropic medium. The main concept is first illustrated using a simple pedagogical example for an anisotropic distribution of spherical voids. Then, a general derivation of formulas relating the derivative of the planar correlation functions to surface integrals is presented. When the surface normal is uniformly distributed (as is the case for any distribution of spherical voids), our formulas can be used to relate a specific surface area to easily measurable quantities from any single cross section. When the surface normal is not distributed uniformly (as would be the case for an oriented distribution of ellipsoidal voids), our results show how to obtain valid estimates of specific surface area by averaging measurements on three orthogonal cross sections. One important general observation for porous media is that the surface area from nearly flat cracks may be underestimated from measurements on orthogonal cross sections if any of the cross sections happen to lie in the plane of the cracks. This result is illustrated by taking the very small aspect ratio (penny-shaped crack) limit of an oblate spheroid, but holds for other types of flat surfaces as well

  10. Pore scale heterogeneity in the mineral distribution and surface area of porous rocks

    Science.gov (United States)

    Lai, Peter; Moulton, Kevin; Krevor, Samuel

    2014-05-01

    There are long-standing challenges in characterizing reactive transport in porous media at scales larger than individual pores. This hampers the prediction of the field-scale impact of geochemical processes on fluid flow [1]. This is a source of uncertainty for carbon dioxide injection, which results in a reactive fluid-rock system, particularly in carbonate rock reservoirs. A potential cause is the inability of the continuum approach to incorporate the impact of heterogeneity in pore-scale reaction rates. This results in part from pore-scale heterogeneities in surface area of reactive minerals [2,3]. The objective of this study was to quantify heterogeneity in reactive surface and observe the extent of its non-normal character. In this study we describe our work in using micron-scale x-ray imaging and other spectroscopic techniques for the purpose of describing the statistical distribution of reactive surface area within a porous medium, and identifying specific mineral phases and their distribution in 3-dimensions. Using in-house image processing techniques and auxilary charactersation with thin section, electron microscope and spectroscopic techniques we quantified the surface area of each mineral phase in the x-ray CT images. This quantification was validated against nitrogen BET surface area and backscattered electron imaging measurements of the CT-imaged samples. Distributions in reactive surface area for each mineral phase were constructed by calculating surface areas in thousands of randomly selected subvolume images of the total sample, each normalized to the pore volume in that image. In all samples, there is little correlation between the reactive surface area fraction and the volumetric fraction of a mineral in a bulk rock. Berea sandstone was far less heterogeneous and has a characteristic pore size at which a surface area distribution may be used to quantify heterogeneity. In carbonates, heterogeneity is more complex and surface area must be

  11. Technology of surface wastewater purification, including high-rise construction areas

    Science.gov (United States)

    Tsyba, Anna; Skolubovich, Yury

    2018-03-01

    Despite on the improvements in the quality of high-rise construction areas and industrial wastewater treatment, the pollution of water bodies continues to increase. This is due to the organized and unorganized surface untreated sewage entry into the reservoirs. The qualitative analysis of some cities' surface sewage composition is carried out in the work. Based on the published literature review, the characteristic contamination present in surface wastewater was identified. The paper proposes a new technology for the treatment of surface sewage and presents the results of preliminary studies.

  12. Estimating surface fluxes over the north Tibetan Plateau area with ASTER imagery

    Directory of Open Access Journals (Sweden)

    Weiqiang Ma

    2009-01-01

    Full Text Available Surface fluxes are important boundary conditions for climatological modeling and Asian monsoon system. The recent availability of high-resolution, multi-band imagery from the ASTER (Advanced Space-borne Thermal Emission and Reflection radiometer sensor has enabled us to estimate surface fluxes to bridge the gap between local scale flux measurements using micrometeorological instruments and regional scale land-atmosphere exchanges of water and heat fluxes that are fundamental for the understanding of the water cycle in the Asian monsoon system. A parameterization method based on ASTER data and field observations has been proposed and tested for deriving surface albedo, surface temperature, Normalized Difference Vegetation Index (NDVI, Modified Soil Adjusted Vegetation Index (MSAVI, vegetation coverage, Leaf Area Index (LAI, net radiation flux, soil heat flux, sensible heat flux and latent heat flux over heterogeneous land surface in this paper. As a case study, the methodology was applied to the experimental area of the Coordinated Enhanced Observing Period (CEOP Asia-Australia Monsoon Project (CAMP on the Tibetan Plateau (CAMP/Tibet, located at the north Tibetan Plateau. The ASTER data of 24 July 2001, 29 November 2001 and 12 March 2002 was used in this paper for the case of summer, winter and spring. To validate the proposed methodology, the ground-measured surface variables (surface albedo and surface temperature and land surface heat fluxes (net radiation flux, soil heat flux, sensible heat flux and latent heat flux were compared to the ASTER derived values. The results show that the derived surface variables and land surface heat fluxes in three different months over the study area are in good accordance with the land surface status. Also, the estimated land surface variables and land surface heat fluxes are in good accordance with ground measurements, and all their absolute percentage difference (APD is less than 10% in the validation sites

  13. Tritium Concentrations in Environmental Samples and Transpiration Rates from the Vicinity of Mary's Branch Creek and Background Areas, Barnwell, South Carolina, 2007-2009

    Science.gov (United States)

    Vroblesky, Don A.; Canova, Judy L.; Bradley, Paul M.; Landmeyer, James E.

    2009-01-01

    Tritium in groundwater from a low-level radioactive waste disposal facility near Barnwell, South Carolina, is discharging to Mary's Branch Creek. The U.S. Geological Survey conducted an investigation from 2007 to 2009 to examine the tritium concentration in trees and air samples near the creek and in background areas, in groundwater near the creek, and in surface water from the creek. Tritium was found in trees near the creek, but not in trees from background areas or from sites unlikely to be in direct root contact with tritium-contaminated groundwater. Tritium was found in groundwater near the creek and in the surface water of the creek. Analysis of tree material has the potential to be a useful tool in locating shallow tritium-contaminated groundwater. A tritium concentration of 1.4 million picocuries per liter was measured in shallow groundwater collected near a tulip poplar located in an area of tritium-contaminated groundwater discharge. Evapotranspiration rates from the tree and tritium concentrations in water extracted from tree cores indicate that during the summer, this tulip poplar may remove more than 17.1 million picocuries of tritium per day from the groundwater that otherwise would discharge to Mary's Branch Creek. Analysis of air samples near the tree showed no evidence that the transpirative release of tritium to the air created a vapor hazard in the forest.

  14. Satellite remotely-sensed land surface parameters and their climatic effects on urban areas

    Science.gov (United States)

    Zoran, M.; Savastru, R.; Savastru, D.; Ciobanu, M.; Tautan, M. N.; Miclos, S.

    2009-04-01

    Rapid urbanization transforms the natural landscape to anthropogenic urban land and changes surface biogeophysical characteristics.Urban growth affects the ecology of cities in a number of ways, such as eliminating and fragmenting native habitats, modifying local climate conditions, and generating anthropogenic pollutants.Urbanization has changed many landscapes throughout the world with serious ecological consequences.To understand the ecology of urban systems, it is necessary to quantify the spatial and temporal patterns of urbanization, which often requires dynamic modeling and spatial analysis. Geospatial information provided by satellite remote sensing sensors and biogeophysical field data are very useful for urban landuse-landcover dynamics and impacts analysis. The spatial and spectral variability of urban environments present fundamental challenges to deriving accurate remote sensing information for urban areas. By integrating high-resolution and medium-resolution satellite imagery with other geospatial information, have been investigated several land surface parameters including impervious surfaces and land surface temperatures for Bucharest metropolitan area in Romania. Percent impervious surface was used to quantitatively define the spatial extent and development density of urban land use. Land surface temperatures were retrieved by using a single band algorithm that processes both thermal infrared satellite data and total atmospheric water vapour content. Land surface temperatures have been analysed for different land use and land cover categories both in urban as well as in periurban areas. Because of the removal of vegetative cover and the reduction in evaporation over urban impervious surfaces, the urban heterogeneity of land surface and associated spatial extents influence surface thermal conditions. In situ meteorological data were integrated to assess regional climatic conditions. The spatial structure of surface heating influenced by landscape

  15. Nitrate and nitrite contamination of sub-surface water in some areas of North West Frontier Province (N.W.F.P.) Pakistan

    International Nuclear Information System (INIS)

    Khan, M.; Khawaja, M.A.; Imdadullah

    1998-01-01

    Over the past few years, nitrate and nitrite contamination of sub-surface water samples from Peshawar, Charsada, Mardan and Nowshera districts of NWFP has been studied. In all the areas under study, nitrate concentration of sub-surface water was found to be below WHO approved limit of 45 mg/l. Whereas city area after 1987 showed a decreasing level of nitrate contamination of sub-surface water, it appeared to be on the increase in water samples from the outskirts of Peshawar-Charsada road. No uniform increasing or decreasing patterns of nitrate contamination were observed for water samples from cantonment, University and Hayatabad, areas of Mardan, Charsada and Nowshera under study. The nitrate contamination of sub-surface water appeared to be due to both the agricultural activities as well as human and animal wastes. A few sub-surface water samples from Peshawar city, Mardan and Nowshera areas indicated high concentration of nitrite, which is alarming in view of the earlier reports showing absence of nitrite in water samples from these areas. However, since 1993, nitrite presence has not been detected in sub-surface water samples from all the areas under present investigation. (author)

  16. ASSESSMENT FORM - NEW IMPROVEMENT OF ACTIONS: CONCENTRATION AND RESEARCH AREAS / CURRICULUM STRUCTURE / FUNDRAISING.

    Science.gov (United States)

    Calderon, Iracema Mp

    2015-01-01

    This review aims to develop a critical and current analysis of the basic structure of a Postgraduate program for proposing improvement actions and new evaluation criteria. To examine the items that are areas of concentration (AC), research lines (LP), research projects (PP), curricular structure and fundraising were consulted the Area Document, the 2013 Evaluation Report and the Assessment Sheets of Medicine III programs, evaluated in the 2010-2012 period. Consistency is recommended especially among AC, LP and PP, with genuine link between activities and permanent teachers skills and based on structured curriculum in the education of the student. The Program Proposal interfere, and much, in qualifying a program. The curriculum should provide subsidy to the formation of the researcher, through the core subjects, and development of PP, being the concept of disciplines to support lines and research projects. Fundraise should be set out in research projects and in the CV-Lattes. The area recommended that at least 40-50% of permanent teachers present fundraising and the minimum 20-25% of these teachers to have productivity scholarship PQ / CNPq during the triennium. It is necessary to promote wide discussion and find a consensus denominator for these issues. The actions should contribute to the improvement of evaluation forms and certainly for the qualification of the programs but graduate. Essa revisão tem como objetivo elaborar uma análise crítica e atual da estrutura básica de um programa de Pós-Graduação para a proposição de ações de aperfeiçoamento e novos critérios de avaliação. Para analisarem-se os itens áreas de concentração (AC), linhas de pesquisa (LP), projetos de pesquisa (PP), estrutura curricular e captação de recursos/fomentos foram consultados o documento de área, o relatório de avaliação 2013 e as fichas de avaliação dos programas da Medicina III, avaliados no triênio 2010-2012. A coerência é recomendada especialmente entre

  17. Analysis of concentric and eccentric contractions in biceps brachii muscles using surface electromyography signals and multifractal analysis.

    Science.gov (United States)

    Marri, Kiran; Swaminathan, Ramakrishnan

    2016-06-23

    Muscle contractions can be categorized into isometric, isotonic (concentric and eccentric) and isokinetic contractions. The eccentric contractions are very effective for promoting muscle hypertrophy and produce larger forces when compared to the concentric or isometric contractions. Surface electromyography signals are widely used for analyzing muscle activities. These signals are nonstationary, nonlinear and exhibit self-similar multifractal behavior. The research on surface electromyography signals using multifractal analysis is not well established for concentric and eccentric contractions. In this study, an attempt has been made to analyze the concentric and eccentric contractions associated with biceps brachii muscles using surface electromyography signals and multifractal detrended moving average algorithm. Surface electromyography signals were recorded from 20 healthy individuals while performing a single curl exercise. The preprocessed signals were divided into concentric and eccentric cycles and in turn divided into phases based on range of motion: lower (0°-90°) and upper (>90°). The segments of surface electromyography signal were subjected to multifractal detrended moving average algorithm, and multifractal features such as strength of multifractality, peak exponent value, maximum exponent and exponent index were extracted in addition to conventional linear features such as root mean square and median frequency. The results show that surface electromyography signals exhibit multifractal behavior in both concentric and eccentric cycles. The mean strength of multifractality increased by 15% in eccentric contraction compared to concentric contraction. The lowest and highest exponent index values are observed in the upper concentric and lower eccentric contractions, respectively. The multifractal features are observed to be helpful in differentiating surface electromyography signals along the range of motion as compared to root mean square and median

  18. Evaluation of Relation between Mercury Concentration in Saliva with Number and Surfaces of Amalgam Fillings

    Directory of Open Access Journals (Sweden)

    F. Agha Hosseini

    2004-09-01

    Full Text Available Statement of Problem: Amalgam is the most widely used dental restorative material.However, because of continuous low-level release of Mercury from amalgam fillings, its safety has been questionable.Purpose: The aim of this study was the evaluation of concentration of Mercury in saliva before and after amalgam fillings and its relation with numbers and surfaces of amalgam fillings.Materials and Methods: In an analytic interventional study we surveyed concentration Mercury in saliva before and after amalgam fillings. Twenty-five Patients (9 male, 16 female who referred to oral medicine department of Tehran university of medical scienceand Haj- Abdol- Vahab medical center who had no amalgam fillings were selected and the samples of saliva (5cc was collected before fillings. After that all of posterior decayed teeth were filled in an appointment with amalgam and, 24 hours later, the second samplesof saliva (5cc was collected. The amount of saliva Mercury before and after filling was measured and its difference was analyzed by paired t- test.Results: In this study the mean of Mercury in saliva was 0.00896 μg/ml before and 0.16404 μg/ml after amalgam fillings. The mean of number of fillings was 1.96 and mean of size of surfaces was 76.43 mm2 and mean of consumption amalgam was 4.1 units.Conclusion: There was no significant correlation between age (P=0.677, sex, number of fillings (P=0.055, number of surface of filling (P=0.059 and size of surfaces of fillings (P=0.072, with Mercury levels in saliva after amalgam fillings. There was a significant relation between Mercury level of saliva after fillings and amalgam amount (P= 0.036.Therefore amalgam may be designate a significant source for Mercury release in saliva.Since this is a preliminary study, it needs supplementary evaluations in saliva, blood and urine in different periods after amalgam fillings.

  19. Pore scale heterogeneity in the mineral distribution and reactive surface area of rocks

    Science.gov (United States)

    Lai, P. E.; Krevor, S. C.

    2013-12-01

    There are long-standing challenges in characterizing reactive transport in porous media at scales larger than individual pores. This hampers the prediction of the field-scale impact of geochemical processes on fluid flow [1]. This is a source of uncertainty for CO2 injection, which results in a reactive fluid-rock system, particularly in carbonate rock reservoirs. A potential cause is the inability of the continuum approach to incorporate the impact of heterogeneity in pore-scale reaction rates. This results in part from pore-scale heterogeneities in surface area of reactive minerals [2,3]. In this study we have created μm resolution 3D images of 3 sandstone and 4 carbonate rocks using x-ray microtomography. Using in-house image processing techniques and auxiliary characterisation with thin section, electron microscope and spectroscopic techniques we quantified the surface area of each mineral phase in the x-ray CT images. This quantification was validated against N2 BET surface area and He porosity measurements of the imaged samples. Distributions in reactive surface area for each mineral phase were constructed by calculating surface areas in thousands of randomly selected subvolume images of the total sample, each normalized to the pore volume in that image. In all samples, there is little correlation between the reactive surface area fraction and the volumetric fraction of a mineral in a bulk rock. Berea sandstone was far less heterogeneous and has a characteristic pore size at which a surface area distribution may be used to quantify heterogeneity. In carbonates, heterogeneity is more complex and surface area must be characterized at multiple length scales for an accurate description of reactive transport. [1] Maher, Steefel, Depaolo and Vianni (2006) Geochimica et Cosmochimica Acta, 70, 337-363 [2] Landrot, Ajo-Franklin, Yang, Cabrini and Steefel (2012) Chemical Geology 318-319, 113-125 [3] Li, Peters and Celia (2007) American Journal of Science 307, 1146

  20. Radionuclide Concentrations in Soils and Vegetation at Low-Level Radioactive Waste Disposal Area G during the 1997 Growing Season

    Energy Technology Data Exchange (ETDEWEB)

    L. Naranjo, Jr.; P. R. Fresquez; R. J. Wechsler

    1998-08-01

    Soil and overstory and understory vegetation (washed and unwashed) collected at eight locations within and around Area G-a low-level radioactive solid-waste disposal facility at Los Alamos National Laboratory-were analyzed for 3H, 238Pu, 239Pu, 137CS, 234U, 235U, 228AC, Be, 214Bi, 60Co, 40& 54Mn, 22Na, 214Pb and 208Tl. In general, most radionuclide concentrations, with the exception of 3Ef and ~9Pu, in soils and overstory and understory vegetation collected from within and around Area G were within upper (95'%) level background concentrations. Although 3H concentrations in vegetation from most sites were significantly higher than background (>2 pCi mL-l), concentrations decreased markedly in comparison to last year's results. The highest `H concentration in vegetation was detected from a juniper tree that was growing over tritium shaft /+150; it contained 530,000 pCi 3H mL-l. Also, as in the pas~ the transuranic waste pad area contained the highest levels of 239Pu in soils and in understory vegetation as compared to other areas at Area G.

  1. Spatial distribution of ground-level urban background O3 concentrations in the Metropolitan Area of Buenos Aires, Argentina.

    Science.gov (United States)

    Pineda Rojas, Andrea L; Venegas, Laura E

    2013-12-01

    In this work, a recently developed urban-scale atmospheric dispersion model (DAUMOD-GRS) is applied to evaluate the ground-level ozone (O3) concentrations resulting from anthropogenic area sources of NOx and VOC in the Metropolitan Area of Buenos Aires (MABA). The statistical comparison of model results with observations (including new available data from seventeen sites) shows a good model performance. Estimated summer highest diurnal O3 1-h concentrations in the MABA vary between 15 ppb in the most urbanised area and 53 ppb in the suburbs. All values are below the air quality standard. Several runs are performed to evaluate the impact of possible future emission reductions on O3 concentrations. Under all hypothetical scenarios, the maximum diurnal O3 1-h concentration obtained for the area is slightly reduced (up to 4%). However, maximum diurnal O3 concentrations could increase at some less urbanised areas of MABA depending on the relative reductions of the emissions of NOx and VOC. Copyright © 2012 Elsevier Ltd. All rights reserved.

  2. Variability of silver fir (Abies alba Mill. cones – variability structure of scale surface area

    Directory of Open Access Journals (Sweden)

    Aniszewska Monika

    2017-03-01

    Full Text Available This study was conducted on a batch of closed silver fir cones from Jawor Forest District and a mixture of scales from the seed extraction facility Grotniki. The scales were divided into three size classes corresponding to the bottom, middle and upper part of the cones and their area was measured with the Multi Scan Base v.18.03 software. Based on the sum of the inner and outer surface area of all scales, we then determined the total area of evaporation from the cones. In addition, the area of protruding scales was measured for differently sized scales from different parts of the cones. Previous studies have shown that the average outer surface of a closed cone, calculated as the sum of protruding scales, accounts for 10% of the outer surface of an open cone. Pictures of both scale surfaces with the internal seed bed and the external protrusions were taken using a scanning electron microscope. We noticed significant differences in dimension and shape of the channels and trichomes on the scale surface. On the inner side of the scales, we found a high diversity of trichomes of different lengths, whilst the outer side contained channels. Presumably, these characteristics affect the rate of water loss from the cones during desiccation and separation of the seed. In-depth knowledge on the evaporative surfaces of fir cones and scale structure will be helpful for optimizing the industrial processes of seed extraction.

  3. Heavy metal concentrations in the surface marine sediments of Sfax Coast, Tunisia.

    Science.gov (United States)

    Gargouri, Dorra; Azri, Chafai; Serbaji, Mohamed Moncef; Jedoui, Younes; Montacer, Mabrouk

    2011-04-01

    Sixty-seven surface marine sediment samples in the Sfax (Tunisia) were analyzed by inductively coupled plasma-atomic emission spectrometry for seven heavy metals (Pb, Ni, Cu, Cr, Zn, Cd, and Fe). Metal concentrations were compared with natural values, marine sediment quality standards, and also with other results concerning sediments from several Mediterranean coasts. The study of their spatial distributions refined by complementary approaches including principal component analysis, enrichment factors, and geoaccumulation index showed a significant impact of multiple anthropogenic sources. These included industrial sources and municipal discharges of the urban Sfax and also non-controlled discharges in rural zones close to the coastline. Moderate pollution of sediments, especially by Pb, Zn, and Ni, was shown to exist in localized sites. Besides, it was shown that other sites, slightly to highly enriched in terms of Cu, Cr, and Cd, are characterized by a quality of sediments varying from unpolluted to moderately polluted.

  4. First observations of surface ozone concentration from the summit region of Mount Everest

    Science.gov (United States)

    Semple, John L.; Moore, G. W. K.

    2008-10-01

    The extreme height of Mount Everest is such that its summit region may periodically be in the lower stratosphere. In this regard it provides a unique location for observing the exchange of ozone between the upper troposphere and lower stratosphere. Here we report the first surface ozone measurements from the summit region of Mount Everest. Simultaneous measurements were recorded at different elevations on the north side from base camp (5676 m) to the summit (8848 m) during May 2005. The concentrations measured were as high as 70 ppb. Meteorological diagnostics suggest that the stratosphere as well as the long range transport of polluted tropospheric air masses from South East Asia are sources of the observed ozone. There is evidence that the source region for ozone in the vicinity of Mount Everest may vary with the onset of the summer monsoon.

  5. Shape of shock wave produced by a concentrated impact on a surface

    International Nuclear Information System (INIS)

    Nutt, G.; Klein, L.

    1981-01-01

    An approximate similarity solution, derived by Raizer, of a concentrated impact (or intense explosion) at the boundary of a semi-infinite volume of a perfect gas is used to determine the propagation velocity of the shock front as a function of its position. This velocity function is then used to obtain the shape of the propagating shock wave. It is shown that dish-shaped shock fronts are formed when the movement of the gas at the surface is into the gas region and that cup-shaped shock fronts are formed when the movement is out of the gas region. Comparison of these results with the shapes of explosions and meteorite craters are discussed

  6. Evaluating polymer degradation with complex mixtures using a simplified surface area method.

    Science.gov (United States)

    Steele, Kandace M; Pelham, Todd; Phalen, Robert N

    2017-09-01

    Chemical-resistant gloves, designed to protect workers from chemical hazards, are made from a variety of polymer materials such as plastic, rubber, and synthetic rubber. One material does not provide protection against all chemicals, thus proper polymer selection is critical. Standardized testing, such as chemical degradation tests, are used to aid in the selection process. The current methods of degradation ratings based on changes in weight or tensile properties can be expensive and data often do not exist for complex chemical mixtures. There are hundreds of thousands of chemical products on the market that do not have chemical resistance data for polymer selection. The method described in this study provides an inexpensive alternative to gravimetric analysis. This method uses surface area change to evaluate degradation of a polymer material. Degradation tests for 5 polymer types against 50 complex mixtures were conducted using both gravimetric and surface area methods. The percent change data were compared between the two methods. The resulting regression line was y = 0.48x + 0.019, in units of percent, and the Pearson correlation coefficient was r = 0.9537 (p ≤ 0.05), which indicated a strong correlation between percent weight change and percent surface area change. On average, the percent change for surface area was about half that of the weight change. Using this information, an equivalent rating system was developed for determining the chemical degradation of polymer gloves using surface area.

  7. Analysis of relationships between NDVI and land surface temperature in coastal area

    Science.gov (United States)

    Ning, Jicai; Gao, Zhiqiang; Chen, Maosi

    2017-09-01

    Using Landsat 5 Thematic Mapper and Landsat 8 Operational Land Imager and Thermal Infrared Sensor imagery of the Yellow River Delta, this study analyzed the relationships between NDVI and LST (land surface temperature). Six Landsat images comprising two time series were used to calculate the land surface temperature and correlated vegetation indices. The Yellow River Delta area has expanded substantially because of the deposited sediment carried from upstream reaches of the river. Between 1986 and 2015, approximately 35% of the land use area of the Yellow River Delta has been transformed into salterns and aquaculture ponds. Overall, land use conversion has occurred primarily from poorly utilized land into highly utilized land. To analyze the variation of land surface temperature, a mono-window algorithm was applied to retrieve the regional land surface temperature. The results showed bilinear correlation between land surface temperature and the vegetation indices (i.e., Normalized Difference Vegetation Index, Adjusted-Normalized Vegetation Index, Soil-Adjusted Vegetation Index, and Modified Soil-Adjusted Vegetation Index). Generally, values of the vegetation indices greater than the inflection point mean the land surface temperature and the vegetation indices are correlated negatively, and vice versa. Land surface temperature in coastal areas is affected considerably by local seawater temperature and weather conditions.

  8. NOAA JPSS Visible Infrared Imaging Radiometer Suite (VIIRS) Ice Concentration and Ice Surface Temperature Environmental Data Records (EDRs) from NDE

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This dataset contains a high quality operational Environmental Data Record (EDR) of Sea Ice Concentration (SIC) and Ice Surface Temperature (IST) from the Visible...

  9. Corrective Action Decision Document for Corrective Action Unit 417: Central Nevada Test Area Surface, Nevada Appendix D - Corrective Action Investigation Report, Central Nevada Test Area, CAU 417

    Energy Technology Data Exchange (ETDEWEB)

    U.S. Department of Energy, Nevada Operations office

    1999-04-02

    This Corrective Action Decision Document (CADD) identifies and rationalizes the U.S. Department of Energy, Nevada Operations Office's selection of a recommended corrective action alternative (CAA) appropriate to facilitate the closure of Corrective Action Unit (CAU) 417: Central Nevada Test Area Surface, Nevada, under the Federal Facility Agreement and Consent Order. Located in Hot Creek Valley in Nye County, Nevada, and consisting of three separate land withdrawal areas (UC-1, UC-3, and UC-4), CAU 417 is comprised of 34 corrective action sites (CASs) including 2 underground storage tanks, 5 septic systems, 8 shaker pad/cuttings disposal areas, 1 decontamination facility pit, 1 burn area, 1 scrap/trash dump, 1 outlier area, 8 housekeeping sites, and 16 mud pits. Four field events were conducted between September 1996 and June 1998 to complete a corrective action investigation indicating that the only contaminant of concern was total petroleum hydrocarbon (TPH) which was found in 18 of the CASs. A total of 1,028 samples were analyzed. During this investigation, a statistical approach was used to determine which depth intervals or layers inside individual mud pits and shaker pad areas were above the State action levels for the TPH. Other related field sampling activities (i.e., expedited site characterization methods, surface geophysical surveys, direct-push geophysical surveys, direct-push soil sampling, and rotosonic drilling located septic leachfields) were conducted in this four-phase investigation; however, no further contaminants of concern (COCs) were identified. During and after the investigation activities, several of the sites which had surface debris but no COCs were cleaned up as housekeeping sites, two septic tanks were closed in place, and two underground storage tanks were removed. The focus of this CADD was to identify CAAs which would promote the prevention or mitigation of human exposure to surface and subsurface soils with contaminant

  10. Concentration patterns of agricultural pesticides and urban biocides in surface waters of a catchment of mixed land use

    Science.gov (United States)

    Stamm, C.; Wittmer, I.; Bader, H.-P.; Scheidegger, R.; Alder, A.; Lück, A.; Hanke, I.; Singer, H.

    2009-04-01

    Organic pesticides and biocides that are found in surface waters, can originate from agricultural and urban sources. For a long time, agricultural pesticides have received substantially more attention than biocidal compounds from urban use like material protection or in-can preservatives (cosmetics etc.). Recent studies however revealed that the amounts of urban biocides used may exceed those of agricultural pesticides. This study aims at comparing the input of several important pesticides and biocides into a small Swiss stream with a special focus on loss events triggered by rainfall. A set of 16 substances was selected to represent urban and agricultural sources. The selected substances are either only used as biocides (irgarol, isothiazolinones, IPBC), as pesticides (atrazine, sulcotrione, dichlofluanid, tolylfluanid) or have a mixed use (isoproturon, terbutryn, terbutylazine, mecoprop, diazinon, carbendazim) The study catchment has an area of 25 km2 and is inhabited by about 12'000 people. Four sampling sites were selected in the river system in order to reflect different urban and agricultural sources. Additionally, we sampled a combined sewer overflow, a rain sewer and the outflow of a wastewater treatment plant. At each site discharge was measured continuously from March to November 2007. During 16 rain events samples were taken by automatic devices at a high temporal resolution. The results, based on more than 500 analyzed samples, revealed distinct concentration patterns for different compounds and sources. Agricultural pesticides exhibited a strong seasonality as expected based on the application periods. During the first one or two rain events after application the concentrations reached up to several thousand ng/l during peak flow (atrazine, isoproturon). The temporal patterns of urban biocides were more diverse. Some compounds obviously stem from permanent sources independent of rainfall because they were found mostly in the outlet of the wastewater

  11. Statistical analysis of surface and subsurface radiometric uranium exploration data, Pongtung area, East Khasi Hills District, Meghalaya: a multivariate approach

    International Nuclear Information System (INIS)

    Sharma, G.K.; Gupta, C.S.; Singh, R.V.; Buhphang, A.J.

    2015-01-01

    The drilling (non-core) based on initial radiometric survey was under taken in Pongtung area of Pynursla plateau in sedimentary environment to trace the subsurface uranium mineralization, if any. Although radiometric surveys and radiometric analysis of grab and channel samples indicated presence of high uranium concentration, but gamma ray logging of exploratory boreholes did not show significant results. To address this anomalous behavior between surface and subsurface data, statistical analysis of grab sample, channel sample and subsurface sample data was performed. The results indicate presence of thorium bearing minerals in lower Mahadek sandstone and basement granites and confirm the continuation of three different geological formations

  12. Relationship among land surface temperature and LUCC, NDVI in typical karst area.

    Science.gov (United States)

    Deng, Yuanhong; Wang, Shijie; Bai, Xiaoyong; Tian, Yichao; Wu, Luhua; Xiao, Jianyong; Chen, Fei; Qian, Qinghuan

    2018-01-12

    Land surface temperature (LST) can reflect the land surface water-heat exchange process comprehensively, which is considerably significant to the study of environmental change. However, research about LST in karst mountain areas with complex topography is scarce. Therefore, we retrieved the LST in a karst mountain area from Landsat 8 data and explored its relationships with LUCC and NDVI. The results showed that LST of the study area was noticeably affected by altitude and underlying surface type. In summer, abnormal high-temperature zones were observed in the study area, perhaps due to karst rocky desertification. LSTs among different land use types significantly differed with the highest in construction land and the lowest in woodland. The spatial distributions of NDVI and LST exhibited opposite patterns. Under the spatial combination of different land use types, the LST-NDVI feature space showed an obtuse-angled triangle shape and showed a negative linear correlation after removing water body data. In summary, the LST can be retrieved well by the atmospheric correction model from Landsat 8 data. Moreover, the LST of the karst mountain area is controlled by altitude, underlying surface type and aspect. This study provides a reference for land use planning, ecological environment restoration in karst areas.

  13. Surface Area of Patellar Facets: Inferential Statistics in the Iraqi Population

    Directory of Open Access Journals (Sweden)

    Ahmed Al-Imam

    2017-01-01

    Full Text Available Background. The patella is the largest sesamoid bone in the body; its three-dimensional complexity necessitates biomechanical perfection. Numerous pathologies occur at the patellofemoral unit which may end in degenerative changes. This study aims to test the presence of statistical correlation between the surface areas of patellar facets and other patellar morphometric parameters. Materials and Methods. Forty dry human patellae were studied. The morphometry of each patella was measured using a digital Vernier Caliper, electronic balance, and image analyses software known as ImageJ. The patellar facetal surface area was correlated with patellar weight, height, width, and thickness. Results. Inferential statistics proved the existence of linear correlation of total facetal surface area and patellar weight, height, width, and thickness. The correlation was strongest for surface area versus patellar weight. The lateral facetal area was found persistently larger than the medial facetal area, the p value was found to be <0.001 (one-tailed t-test for right patellae, and another significant p value of < 0.001 (one-tailed t-test was found for left patellae. Conclusion. These data are vital for the restoration of the normal biomechanics of the patellofemoral unit; these are to be consulted during knee surgeries and implant designs and can be of an indispensable anthropometric, interethnic, and biometric value.

  14. The Complete Solution of Fick's Second Law of Diffusion with Time-dependent Diffusion Coefficient and Surface Concentration

    DEFF Research Database (Denmark)

    Mejlbro, Leif

    1996-01-01

    Fick's Second Law of Diffusion with time-dependent diffusioncoefficient and surface concentration is solved. Mimicking the classicalsolution, special time-dependent surface concentration functions areconsidered. These models are used in giving estimates of the lifetimeof the structure, when the c...... the concrete cover is given, as well as estimatesof the thickness of the concrete cover, when the expected lifetime is given.*Note: Book tilte: Durability of Concrete in Saline Environment...

  15. The concentration of 137Cs in the surface of the Greek marine environment

    International Nuclear Information System (INIS)

    The radiological status of the Greek marine environment, prior to the Chernobyl accident, was characterized mainly by the fallout from nuclear weapon tests. However, the release of radioactivity into the environment from the accident in the Chernobyl Nuclear Power Plant and its deposition in the Greek marine environment resulted in an increase of the 137 Cs activity concentration by approximately one order of magnitude. In addition, the direct transport of radiocaesium into the North Aegean Sea has been further influenced by the late impact of the Chernobyl accident on the Greek marine environment, related to the transfer of 137 Cs, mainly through the Dnieper but also the Danube rivers, to the Black Sea and further to the North Aegean Sea through the Straits of Dardanelles. The aim of this work is to provide a present day picture of the geographic variation of the concentration of 137 Cs in the surface layer of the Greek marine environment and hence, to evaluate the annual committed effective dose delivered to humans through the ingestion pathway from marine sources.

  16. Marine organic geochemistry in industrially affected coastal areas in Greece: Hydrocarbons in surface sediments

    Science.gov (United States)

    Hatzianestis, Ioannis

    2015-04-01

    Hydrocarbons are abundant components of the organic material in coastal zones. Their sources are mainly anthropogenic, but several natural ones have also been recognized. Among hydrocarbons, the polycyclic aromatic ones (PAHs) have received special attention since they considered as hazardous environmental chemicals and are included in priority pollutant lists. The purpose of this study was to investigate the distribution, sources and transport pathways of hydrocarbons in marine areas in Greece directly influenced from the operation of major industrial units in the coastal zone by using a molecular marker approach, characteristic compositional patterns and related indices and also to evaluate their potential toxicity. Thirty two surface sediment samples were collected from three marine areas: a) Antikyra bay in Korinthiakos gulf, affected from the operation of an alumina and production plant b) Larymna bay in Noth Evoikos, affected from the operation of a nickel production plant and c) Aliveri bay in South Evoikos Gulf, affected from a cement production plant. In all the studied areas aquaculture and fishing activities have been also developed in the coastal zone. High aliphatic hydrocarbon (AHC) concentrations (~500 μg/g), indicating significant petroleum related inputs, were measured only in Antikyra bay. In all the other samples, AHC values were below 100 μg/g. N-alkanes were the most prominent resolved components (R) with an elevated odd to even carbon number preference, revealing the high importance of terrestrial inputs in the study areas. The unresolved complex mixture (UCM) was the major component of the aliphatic fraction (UCM/R > 4), indicating a chronic oil pollution. A series of hopanes were also identified, with patterns characteristic of oil-derived hydrocarbons, further confirming the presence of pollutant inputs from fossil fuel products. Extremely high PAH concentrations (> 100,000 ng/g) were found in the close vicinity of the alumina production

  17. Assessment of Radioactive Materials and Heavy Metals in the Surface Soil around the Bayanwula Prospective Uranium Mining Area in China.

    Science.gov (United States)

    Bai, Haribala; Hu, Bitao; Wang, Chengguo; Bao, Shanhu; Sai, Gerilemandahu; Xu, Xiao; Zhang, Shuai; Li, Yuhong

    2017-03-14

    The present work is the first systematic and large scale study on radioactive materials and heavy metals in surface soil around the Bayanwula prospective uranium mining area in China. In this work, both natural and anthropogenic radionuclides and heavy metals in 48 surface soil samples were analyzed using High Purity Germanium (HPGe) γ spectrometry and inductively coupled plasma-mass spectrometry (ICP-MS). The obtained mean activity concentrations of 238 U, 226 Ra, 232 Th, 40 K, and 137 Cs were 25.81 ± 9.58, 24.85 ± 2.77, 29.40 ± 3.14, 923.0 ± 47.2, and 5.64 ± 4.56 Bq/kg, respectively. The estimated average absorbed dose rate and annual effective dose rate were 76.7 ± 3.1 nGy/h and 83.1 ± 3.8 μ Sv, respectively. The radium equivalent activity, external hazard index, and internal hazard index were also calculated, and their mean values were within the acceptable limits. The estimated lifetime cancer risk was 3.2 × 10 -4 /Sv. The heavy metal contents of Cr, Ni, Cu, Zn, As, Cd, and Pb from the surface soil samples were measured and their health risks were then assessed. The concentrations of all heavy metals were much lower than the average backgrounds in China except for lead which was about three times higher than that of China's mean. The non-cancer and cancer risks from the heavy metals were estimated, which are all within the acceptable ranges. In addition, the correlations between the radionuclides and the heavy metals in surface soil samples were determined by the Pearson linear coefficient. Strong positive correlations between radionuclides and the heavy metals at the 0.01 significance level were found. In conclusion, the contents of radionuclides and heavy metals in surface soil around the Bayanwula prospective uranium mining area are at a normal level.

  18. Fish Mercury and Surface Water Sulfate Relationships in the Everglades Protection Area

    Science.gov (United States)

    Few published studies present data on relationships between fish mercury and surface or pore water sulfate concentrations, particularly on an ecosystem-wide basis. Resource managers can use these relationships to identify the sulfate conditions that contain fish with health-conce...

  19. Correlating humidity-dependent ionically conductive surface area with transport phenomena in proton-exchange membranes.

    Science.gov (United States)

    He, Qinggang; Kusoglu, Ahmet; Lucas, Ivan T; Clark, Kyle; Weber, Adam Z; Kostecki, Robert

    2011-10-13

    The objective of this effort was to correlate the local surface ionic conductance of a Nafion 212 proton-exchange membrane with its bulk and interfacial transport properties as a function of water content. Both macroscopic and microscopic proton conductivities were investigated at different relative humidity levels, using direct-current voltammetry and current-sensing atomic force microscopy (CSAFM). We were able to identify small ion-conducting domains that grew with humidity at the surface of the membrane. Numerical analysis of the surface ionic conductance images recorded at various relative humidity levels helped determine the fractional area of ion-conducting active sites. A simple square-root relationship between the fractional conducting area and observed interfacial mass-transport resistance was established. Furthermore, the relationship between the bulk ionic conductivity and surface ionic conductance pattern of the Nafion membrane was examined.

  20. Correlating Humidity-Dependent Ionically Conductive Surface Area with Transport Phenomena in Proton-Exchange Membranes

    Energy Technology Data Exchange (ETDEWEB)

    He, Qinggang; Kusoglu, Ahmet; Lucas, Ivan T.; Clark, Kyle; Weber, Adam Z.; Kostecki, Robert

    2011-08-01

    The objective of this effort was to correlate the local surface ionic conductance of a Nafion? 212 proton-exchange membrane with its bulk and interfacial transport properties as a function of water content. Both macroscopic and microscopic proton conductivities were investigated at different relative humidity levels, using electrochemical impedance spectroscopy and current-sensing atomic force microscopy (CSAFM). We were able to identify small ion-conducting domains that grew with humidity at the surface of the membrane. Numerical analysis of the surface ionic conductance images recorded at various relative humidity levels helped determine the fractional area of ion-conducting active sites. A simple square-root relationship between the fractional conducting area and observed interfacial mass-transport resistance was established. Furthermore, the relationship between the bulk ionic conductivity and surface ionic conductance pattern of the Nafion? membrane was examined.

  1. Assessment of the total uranium concentration in surface and underground water samples from the Caetite region, Bahia, Brazil

    International Nuclear Information System (INIS)

    Silva, Julia Grasiela Batista; Geraldo, Luiz Paulo; Yamazaki, Ione Makiko

    2011-01-01

    At the region of Caetite, BA, it is located the largest uranium mine in exploration at present days in Brazil. During the uranium extraction process, it may be having an environmental contamination by this heavy metal due to rain water and other natural transport mechanism, with potential exposition risk to the local population. The aim of this work was to investigate the total uranium concentration in surface and underground water samples collected at the Caetite region, using the nuclear track registration technique (SSNTD) in a polycarbonate plastic. A 100 mL volume of water samples were initially treated in 10 mL of HNO 3 (PA) and concentrated by evaporation at a temperature around 80 deg C. The resulting residue was diluted to a total volume of 25 mL without pass it to a filter. About 10 μL of this solution was deposited on the plastic detector surface (around 1.0 cm 2 area) together with 5 μL of a Cyastat detergent solution (5%) and evaporated under an infrared lamp. All the resulting deposits of non volatile constituents were irradiated, together with a uranium standard sample, at the IPEN-IEA-R1 (3.5 MW) nuclear reactor for approximately 3 min. After irradiations, chemical etching of the plastic detectors was carried out at 60 deg C, for 65 min. in a NaOH (6N) solution. The fission tracks were counted scanning all the deposit area of the polycarbonate plastic detector with a system consisting of an optical microscope together with a video camera and TV monitor. The average values of uranium concentrations obtained in this work ranged from (0.95±0.19) μg.L -1 to (25.60±3.3) μg.L -1 . These results were compared to values reported in the literature for water samples from other regions and discussed in terms of safe limits recommended by WHO -World Health Organization and CONAMA - Conselho Nacional do Meio Ambiente. (author)

  2. Assessment of the total uranium concentration in surface and underground water samples from the Caetite region, Bahia, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Julia Grasiela Batista; Geraldo, Luiz Paulo [Centro Universitario da Fundacao Educacional de Barretos (UNIFEB), (SP) (Brazil); Yamazaki, Ione Makiko [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

    2011-07-01

    At the region of Caetite, BA, it is located the largest uranium mine in exploration at present days in Brazil. During the uranium extraction process, it may be having an environmental contamination by this heavy metal due to rain water and other natural transport mechanism, with potential exposition risk to the local population. The aim of this work was to investigate the total uranium concentration in surface and underground water samples collected at the Caetite region, using the nuclear track registration technique (SSNTD) in a polycarbonate plastic. A 100 mL volume of water samples were initially treated in 10 mL of HNO{sub 3} (PA) and concentrated by evaporation at a temperature around 80 deg C. The resulting residue was diluted to a total volume of 25 mL without pass it to a filter. About 10 {mu}L of this solution was deposited on the plastic detector surface (around 1.0 cm{sup 2} area) together with 5 {mu}L of a Cyastat detergent solution (5%) and evaporated under an infrared lamp. All the resulting deposits of non volatile constituents were irradiated, together with a uranium standard sample, at the IPEN-IEA-R1 (3.5 MW) nuclear reactor for approximately 3 min. After irradiations, chemical etching of the plastic detectors was carried out at 60 deg C, for 65 min. in a NaOH (6N) solution. The fission tracks were counted scanning all the deposit area of the polycarbonate plastic detector with a system consisting of an optical microscope together with a video camera and TV monitor. The average values of uranium concentrations obtained in this work ranged from (0.95{+-}0.19) {mu}g.L{sup -1} to (25.60{+-}3.3) {mu}g.L{sup -1}. These results were compared to values reported in the literature for water samples from other regions and discussed in terms of safe limits recommended by WHO -World Health Organization and CONAMA - Conselho Nacional do Meio Ambiente. (author)

  3. High variability of indoor radon concentrations in uraniferous bedrock areas in the Balkan region.

    Science.gov (United States)

    Žunić, Z S; Ujić, P; Nađđerđ, L; Yarmoshenko, I V; Radanović, S B; Komatina Petrović, S; Čeliković, I; Komatina, M; Bossew, P

    2014-12-01

    In this work the strong influence of geological factors on the variability of indoor radon is found in two of three geologically very different regions of South-Eastern Europe. A method to estimate the annual mean concentration when one seasonal measurement is missing is proposed. Large differences of radon concentrations in different rooms of the same house and significant difference in radon concentrations in one season comparing it to the others are noted in certain cases. Geological factors that can lead to such behavior are discussed. Copyright © 2014 Elsevier Ltd. All rights reserved.

  4. Determination of surface heterogeneity of D-mannitol by sessile drop contact angle and finite concentration inverse gas chromatography.

    Science.gov (United States)

    Ho, Raimundo; Hinder, Steven J; Watts, John F; Dilworth, Sarah E; Williams, Daryl R; Heng, Jerry Y Y

    2010-03-15

    The sensitivity of two techniques in tracking changes in surface energetics was investigated for a crystalline excipient, D-mannitol. Macroscopic crystals of D-mannitol were grown from saturated water solution by slow cooling, and sessile drop contact angle was employed to measure the anisotropic surface energy. The facet-specific surface energy was consistent with localised hydroxyl group concentrations determined by X-ray photoelectron spectroscopy (XPS), and was also in excellent agreement with the surface energy distribution of the powder form of mannitol measured via a new methodology using inverse gas chromatography (IGC) at finite concentrations. The gamma(SV)(d) was found to vary between 39.5 mJ/m(2) and 44.1 mJ/m(2) for contact angle and between 40 mJ/m(2) and 49 mJ/m(2) for IGC measurements. We report here, a high level of surface heterogeneity on the native mannitol crystal surfaces. When the surfaces of both D-mannitol samples (powder and large single crystals) were modified by dichlorodimethylsilane to induce surface hydrophobicity, both IGC and contact angle revealed a homogeneous surface due to functionalisation of mannitol crystal surface with methyl groups resulting in gamma(SV)(d) of approximately 34 mJ/m(2). It was shown that both IGC and contact angle techniques are able to detect surface chemical variations and detailed surface energetic distribution. 2010 Elsevier B.V. All rights reserved.

  5. Geohydrology and susceptibility of major aquifers to surface contamination in Alabama; area 11

    Science.gov (United States)

    Castleberry, R.D.; Moreland, R.S.; Scott, J.C.

    1989-01-01

    This report delineates and describes the geohydrology and susceptibility of major aquifers to contamination in Butler, Conecuh, Covington, Crenshaw, Escambia, and Monroe Counties, Alabama. The major aquifers are the Pliocene-Miocene, Upper Floridan, Lisbon, Nanafalia-Clayton, and Providence-Ripley. The largest pumping centers in the area are Andalusia and Monroeville, where groundwater use is about 5 and 4 million gal/day, respectively. Estimated maximum withdrawal in 1987 for all uses in the area was about 44 million gal/day. Depressions have developed in the potentiometric surfaces of the Lisbon aquifer near Andalusia and Opp, the Nanafalia-Clayton aquifer near Luverne, Andalusia, Beatrice, and Monroeville, and the Providence-Ripley aquifer at Greenville. Significant declines in the potentiometric surfaces of the other major aquifers are not apparent. Recharge areas for all major aquifers are susceptible to contamination, but the probability of contamination of the Lisbon, Nanafalia-Clayton, and Providence-Ripley aquifers is low because the recharge areas are remote from areas of the withdrawal. The depressions in the recharge area for the Upper Floridan aquifer and the area where the Pliocene-Miocene aquifer is overlain by the gravelly sands of the Citronelle Formation are highly susceptible to contamination from the surface. (USGS)

  6. Microbiology of the surface water samples in the high background radiation areas of Ramsar, Iran

    International Nuclear Information System (INIS)

    Motamedifar, Mohammad; Zamani, Khosrow; Sedigh, Hadi; Mortazavi, Seyed Mohammad Javad; Taeb, Shahram; Haghani, M.; Mortazavi, Seyed Ali Reza; Soofi, Amir

    2014-01-01

    Residents of high background radiation areas of Ramsar have lived in these areas for many generations and received radiation doses much higher than the dose limit recommended by ICRP for radiation workers. The radioactivity of the high background radiation areas of Ramsar is reported to be due to 226 Ra and its decay products, which have been brought to the surface by the waters of hot springs. Over the past years the department has focused on different aspects of the health effects of the elevated levels of natural radiation in Ramsar. This study was aimed to perform a preliminary investigation on the bioeffects of exposure to elevated levels of natural radiation on the microbiology of surface water samples. Water samples were collected from surface water streams in Talesh Mahalleh district, Ramsar as well as a nearby area with normal levels of background radiation. Only two strains of bacteria, that is, Providencia stuartii and Shimwellia blattae, could be isolated from the water samples collected from high background radiation areas, while seven strains (Escherichia coli, Enterobacter asburiae, Klebsiella pneumoniae, Shigella dysenteriae, Buttiauxella agerstis, Tatumella punctuata and Raoultella ornithinolytica) were isolated from the water samples collected from normal background radiation areas. All the bacteria isolated from water samples of high and normal background radiation areas were sensitive to ultraviolet radiation, heat, betadine, alcohol, and deconex. Although other investigators have reported that bacteria isolated from hot springs show radioresistance, the results reported here do not reveal any adaptive response. (author)

  7. Synthesis of cerium oxide (CeO2) with high surface area through microwave assisted hydrothermal method

    International Nuclear Information System (INIS)

    Oliveira, M.J.C. de; Neiva, L.S.; Gama, L.; Oliveira, J.B.

    2011-01-01

    The objective of this research is synthesize nanoparticles with high surface area of Ceria (CeO 2 ) catalyst by a microwave hydrothermal method. For that it was used a 5% concentration in weight of [Ce(NO 3 ) 3. 6H 2 O] and 10 mL of [NaOH (5M)] under processing conditions in the equipment: maximum temperature of 150 deg C for 60 min with heating rate of 15 C /min. The resulting sample was characterized by XRD, SEM and BET method. It was observed that the Ceria particles are presented spatially in cubic structure, with crystallite size of 10 nm and surface area of 112 m²/g. Through the pore size distribution it was possible to observe that these were in mesoporous size, ranging from 3 to 30 nm. The possibility of obtaining catalysts with nanometer scale and high surface area by beans of microwave hydrothermal method, which involves low energy (low temperatures) and short synthesis time, makes this method very interesting and promising. (author)

  8. Physicochemical properties and in vitro cytocompatibility of modified titanium surfaces prepared via micro-arc oxidation with different calcium concentrations

    International Nuclear Information System (INIS)

    Wu, Sui-Dan; Zhang, Hui; Dong, Xu-Dong; Ning, Cheng-Yun; Fok, Alex S.L.; Wang, Yan

    2015-01-01

    Highlights: • MAO coating improves the surface characteristics and cytocompatibility of titanium. • Composition of MAO coating varies with the electrolyte concentration. • MAO coating properties can be optimized by adjusting the electrolyte concentration. • Higher CA concentration contributes to more favorable MAO coating cytocompatibility. - Abstract: Objective: To explore the effect of calcium concentration in the electrolyte solution on the physicochemical properties and biocompatibility of coatings formed by micro-arc oxidation (MAO) on titanium surfaces. Methods: The surfaces of pure titanium plates were modified by MAO in an electrolytic solution containing calcium acetate (CA; C 4 H 6 CaO 4 ) at concentrations of 0.05, 0.1, 0.2, or 0.3 M and β-glycerophosphate disodium salt pentahydrate (β-GP; C 3 H 7 Na 2 O 6 P·5H 2 O) at a fixed concentration of 0.02 M. Surface topography, elemental characteristics, phase composition, and roughness were investigated by scanning electron microscopy, energy-dispersive X-ray analysis, X-ray diffraction, and a surface roughness tester, respectively. To assess the cytocompatibility and osteoinductivity of the surfaces, MC3T3-E1 preosteoblasts were cultured on the surfaces in vitro, and cell morphology, adhesion, proliferation, and differentiation were observed. Results: The porous MAO coating was composed primarily of TiO 2 rutile and anatase. The amount of TiO 2 rutile, the Ca/P ratio, and the surface roughness of the MAO coating increased with increasing CA concentration in the electrolyte solution. Ca 3 (PO 4 ) 2 , CaCO 3 , and CaTiO 3 were formed on MAO-treated surfaces prepared with CA concentrations of 0.2 and 0.3 M. Cell proliferation and differentiation increased with increasing CA concentration, with MC3T3-E1 cells exhibiting favorable morphologies for bone–implant integration. Conclusions: MAO coating improves the surface characteristics and cytocompatibility of titanium for osseointegration. Higher CA

  9. Physicochemical properties and in vitro cytocompatibility of modified titanium surfaces prepared via micro-arc oxidation with different calcium concentrations

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Sui-Dan; Zhang, Hui [Guanghua School of Stomatology, Hospital of Stomatology, Guangdong Key Laboratory of Stomatology, Sun Yat-sen University, Guangzhou 510055 (China); Dong, Xu-Dong [Faculty of Pharmaceutical Sciences, University of British Columbia, Vancouver, BC V6T 1Z3 (Canada); Ning, Cheng-Yun [College of Material Science and Engineering, South China University of Technology, Guangzhou 510641 (China); Fok, Alex S.L. [Minnesota Dental Research Center of Biomaterials and Biomechanics, School of Dentistry, University of Minnesota, Minneapolis, MN 55414 (United States); Wang, Yan, E-mail: wyan65@163.com [Guanghua School of Stomatology, Hospital of Stomatology, Guangdong Key Laboratory of Stomatology, Sun Yat-sen University, Guangzhou 510055 (China)

    2015-02-28

    Highlights: • MAO coating improves the surface characteristics and cytocompatibility of titanium. • Composition of MAO coating varies with the electrolyte concentration. • MAO coating properties can be optimized by adjusting the electrolyte concentration. • Higher CA concentration contributes to more favorable MAO coating cytocompatibility. - Abstract: Objective: To explore the effect of calcium concentration in the electrolyte solution on the physicochemical properties and biocompatibility of coatings formed by micro-arc oxidation (MAO) on titanium surfaces. Methods: The surfaces of pure titanium plates were modified by MAO in an electrolytic solution containing calcium acetate (CA; C{sub 4}H{sub 6}CaO{sub 4}) at concentrations of 0.05, 0.1, 0.2, or 0.3 M and β-glycerophosphate disodium salt pentahydrate (β-GP; C{sub 3}H{sub 7}Na{sub 2}O{sub 6}P·5H{sub 2}O) at a fixed concentration of 0.02 M. Surface topography, elemental characteristics, phase composition, and roughness were investigated by scanning electron microscopy, energy-dispersive X-ray analysis, X-ray diffraction, and a surface roughness tester, respectively. To assess the cytocompatibility and osteoinductivity of the surfaces, MC3T3-E1 preosteoblasts were cultured on the surfaces in vitro, and cell morphology, adhesion, proliferation, and differentiation were observed. Results: The porous MAO coating was composed primarily of TiO{sub 2} rutile and anatase. The amount of TiO{sub 2} rutile, the Ca/P ratio, and the surface roughness of the MAO coating increased with increasing CA concentration in the electrolyte solution. Ca{sub 3}(PO{sub 4}){sub 2}, CaCO{sub 3}, and CaTiO{sub 3} were formed on MAO-treated surfaces prepared with CA concentrations of 0.2 and 0.3 M. Cell proliferation and differentiation increased with increasing CA concentration, with MC3T3-E1 cells exhibiting favorable morphologies for bone–implant integration. Conclusions: MAO coating improves the surface characteristics and

  10. Distribution of 210Pb activity concentrations in marine surface sediments within East Coast Peninsula Malaysia Exclusive Economic Zone (EEZ)

    International Nuclear Information System (INIS)

    Ahmad Sanadi Abu Bakar; Zaharudin Ahmad

    2010-01-01

    A sampling expedition into the East Coast Peninsula Malaysia Exclusive Economic Zone (EEZ) was carried in June 2008. Marine surface sediment samples were taken and the activity concentrations of 210 Pb have been determined. Its distribution was plotted and the findings show that the activity concentrations decline from north to south. On the other hand, the activity concentrations are increasing from west to east right to the edge of the EEZ. The highest activity concentrations were found to be near offshore oil platforms. The 210 Pb activity concentrations were found to be in the range of 18.3 - 123.1 Bq/ kg. (author)

  11. A Three-Dimensional Enormous Surface Area Aluminum Microneedle Array with Nanoporous Structure

    OpenAIRE

    Chen, Po Chun; Hsieh, Sheng Jen; Chen, Chien Chon; Zou, Jun

    2013-01-01

    We proposed fabricating an aluminum microneedle array with a nanochannel structure on the surface by combining micromachining, electrolyte polishing, and anodization methods. The microneedle array provides a three-dimensional (3D) structure that possesses several hundred times more surface area than a traditional nanochannel template. Therefore, the microneedle array can potentially be used in many technology applications. This 3D microneedle array device can not only be used for painless inj...

  12. Area-averaged surface fluxes and their time-space variability over the FIFE experimental domain

    Science.gov (United States)

    Smith, E. A.; Hsu, A. Y.; Crosson, W. L.; Field, R. T.; Fritschen, L. J.; Gurney, R. J.; Kanemasu, E. T.; Kustas, W. P.; Nie, D.; Shuttleworth, W. J.

    1992-01-01

    The underlying mean and variance properties of surface net radiation, sensible-latent heat fluxes and soil heat flux are studied over the densely instrumented grassland region encompassing FIFE. Flux variability is discussed together with the problem of scaling up to area-averaged fluxes. Results are compared and contrasted for cloudy and clear situations and examined for the influence of surface-induced biophysical controls (burn and grazing treatments) and topographic controls (aspect ratios and slope factors).

  13. Water chemistry and radon concentrations of thermal springs in Bastak area, south of Persia

    International Nuclear Information System (INIS)

    Mirhosseini, S.M.; Moattar, F.; Karbassi, A.R.

    2015-01-01

    Physicochemical factors, major and some minor ions and 222 Rn concentration was measured in Todruyeh, Fotuyeh and Sanguyeh thermal balneutherapy springs in Bastak, south of Iran. Water type of these springs is Na-Cl and water-mixing phenomena seem possible in them. The average of U concentration in Fatuyeh's, Sanguyeh's and Todruyeh's water are 2.2, 1.1, 0.306 ppb, respectively, and the concentration of heavy metals such as Ag, Cd, Co, Cr, Cu, Hg, Ni, Pb, Se, Zn varies from 1 to 10 ppb. The concentration of 222 Rn in the water of Fotuyeh, Sanguyeh and Todruyeh Springs includes 125-253, 53-104, and 7.4-134.7 kBq/m 3 , respectively. Values of mean annual effective doses for inhalation from these waters are below the reference level recommended by WHO. (author)

  14. DMSA scan nomograms for renal length and area: Related to patient age and to body weight, height or surface area

    International Nuclear Information System (INIS)

    Hassan, I.M.; Que, L.; Rutland, M.D.

    2002-01-01

    Aim: To create nomograms for renal size as measured from DMSA renal studies, and to test the nomograms for their ability to separate normal from abnormal kidneys. Method: Renal length was measured from posterior oblique views and renal area from posterior views. Results from 253 patients with bilateral normal kidneys were used to create nomograms for renal size relative to patient age, body height, weight or body surface area (BSA). The nomograms enclosed 95% of the normal kidneys, thus indicating the range for 95% confidence limits, and hence the specificity. Each nomogram was then tested against 46 hypertrophied kidneys and 46 damaged kidneys. Results: The results from nomograms of renal length and renal area, compared to age, body height, body weight and BSA are presented. For each nomogram, the range is presented as a fraction of the mean value, and the number of abnormal kidneys (hypertrophied or damaged) outside the normal range is presented as a percentage (indicating the sensitivity). Conclusion: Renal Area was no better than renal length for detecting abnormal kidneys. Patient age was the least useful method of normalisation. BSA normalisation produced the best results most frequently (narrower ranges and highest detection of abnormal kidneys)

  15. Thyroid Dose Estimation Using WBC and I-131 Concentration in Working Area of Radioisotope Production at Normal Operation

    International Nuclear Information System (INIS)

    Tedjasari, R S; Lubis, E

    1996-01-01

    Thyroid dose estimation at Radioisotope Production Centre workers using WBC and calculation based on I-131 concentration in working area has been done. The aim of this research is to get the relation between WBC result and calculation using I-131 concentration in working area. The result indicates differences in a range of 3,2% to 53,2%. These differences caused of parameters which influence the calculation are not accurate. These results also indicate that dose estimation using WBC is relatively batter and more accurate but need to have certain information about time of intake

  16. 233-S Plutonium Concentration Facility Characterization Plan--non-process areas

    International Nuclear Information System (INIS)

    1996-12-01

    The 233-S Plutonium Concentration Facility is to be decommissioned. This characterization plan incorporates all items addressed in BHI-00832, 233-S Plutonium Concentration Facility Data Quality Objectives, and provides instruction for obtaining and analyzing samples for waste designation and disposal. This plan covers the pipe gallery, control room, equipment room, special work permit; change room, toilet, electrical cubicle within the 233-S Facility, and the roof over these rooms and over the can storage and loadout rooms

  17. Dye-Sensitized Solar Cells Based on High Surface Area Nanocrystalline Zinc Oxide Spheres

    Directory of Open Access Journals (Sweden)

    Pavuluri Srinivasu

    2011-01-01

    Full Text Available High surface area nanocrystalline zinc oxide material is fabricated using mesoporous nanostructured carbon as a sacrificial template through combustion process. The resulting material is characterized by XRD, N2 adsorption, HR-SEM, and HR-TEM. The nitrogen adsorption measurement indicates that the materials possess BET specific surface area ca. 30 m2/g. Electron microscopy images prove that the zinc oxide spheres possess particle size in the range of 0.12 μm–0.17 μm. The nanocrystalline zinc oxide spheres show 1.0% of energy conversion efficiency for dye-sensitized solar cells.

  18. Volumes, Masses, and Surface Areas for Shippingport LWBR Spent Nuclear Fuel in a DOE SNF Canister

    International Nuclear Information System (INIS)

    J.W. Davis

    1999-01-01

    The purpose of this calculation is to estimate volumes, masses, and surface areas associated with (a) an empty Department of Energy (DOE) 18-inch diameter, 15-ft long spent nuclear fuel (SNF) canister, (b) an empty DOE 24-inch diameter, 15-ft long SNF canister, (c) Shippingport Light Water Breeder Reactor (LWBR) SNF, and (d) the internal basket structure for the 18-in. canister that has been designed specifically to accommodate Seed fuel from the Shippingport LWBR. Estimates of volumes, masses, and surface areas are needed as input to structural, thermal, geochemical, nuclear criticality, and radiation shielding calculations to ensure the viability of the proposed disposal configuration

  19. Pore Scale Heterogeneity in the Mineral Distribution, Surface Area and Adsorption in Porous Rocks

    Science.gov (United States)

    Lai, P. E. P.; Krevor, S. C.

    2014-12-01

    The impact of heterogeneity in chemical transport and reaction is not understood in continuum (Darcy/Fickian) models of reactive transport. This is manifested in well-known problems such as scale dependent dispersion and discrepancies in reaction rate observations made at laboratory and field scales [1]. Additionally, this is a source of uncertainty for carbon dioxide injection, which produces a reactive fluid-rock system particularly in carbonate rock reservoirs. A potential cause is the inability of the continuum approach to incorporate the impact of heterogeneity in pore-scale reaction rates. This results in part from pore-scale heterogeneities in surface area of reactive minerals [2, 3]. We use x-ray micro tomography to describe the non-normal 3-dimensional distribution of reactive surface area within a porous medium according to distinct mineral groups. Using in-house image processing techniques, thin sections, nitrogen BET surface area, backscattered electron imaging and energy dispersive spectroscopy, we compare the surface area of each mineral phase to those obtained from x-ray CT imagery. In all samples, there is little correlation between the reactive surface area fraction and the volumetric fraction of a mineral in a bulk rock. Berea sandstone was far less heterogeneous and has a characteristic pore size at which a surface area distribution may be used to quantify heterogeneity. In carbonates, heterogeneity is more complex and surface area must be characterized at multiple length scales for an accurate description of reactive transport. We combine the mineral specific surface area characterisation to dynamic tomography, imaging the flow of water and solutes, to observe flow dependent and mineral specific adsorption. The observations may contribute to the incorporation of experimentally based statistical descriptions of pore scale heterogeneity in reactive transport into upscaled models, moving it closer to predictive capabilities for field scale

  20. A process to enhance the specific surface area and capacitance of hydrothermally reduced graphene oxide

    KAUST Repository

    Alazmi, Amira

    2016-08-26

    The impact of post-synthesis processing in reduced graphene oxide materials for supercapacitor electrodes has been analyzed. A comparative study of vacuum, freeze and critical point drying was carried out for hydrothermally reduced graphene oxide demonstrating that the optimization of the specific surface area and preservation of the porous network are critical to maximize its supercapacitance performance. As described below, using a supercritical fluid as the drying medium, unprecedented values of the specific surface area (364 m2 g−1) and supercapacitance (441 F g−1) for this class of materials have been achieved.

  1. N2-specific surface area of ZrO2-montmorillonite MK-10 synthesis

    International Nuclear Information System (INIS)

    Muzakky; Imam Proyogo

    2016-01-01

    A measurements of N 2 -specific surface area of ZrO 2 -montmorillonite MK-10 synthesis have been done. The purpose of this study is to observed the effect of calcination on the a specific surface area (SSA N2 -BET) of ZrO 2 -montmorillonite MK-10 synthesis. Calcination were carried out at a 200°C; 400°C and 700°C. While the observations were made with surface area analyzer (SAA) and transmission electron microscopy (TEM). The measurement results obtained that SSA N2 -BET ZrO 2 -MK-10 obtained at 214 m 2 g -1 for before calcination and 195 m 2 g -1 after calcination at 400°C. The effected of calcination temperature will cause more towards of multilayer system surface, but the distribution of pore volume becomes smaller. Result of visualization of ZrO 2 -MK-10 surface that by means of TEM showed before calcination are more transparent and has a pore more. While calcination at 400°C has a darker impression and became multilayer and have a larger volume. Synthesized of ZrO 2 -MK 10 that using the ethylene glycol precursor have SSA N2 -BET higher than using glycerol is 195.33 m 2 g -1 and more memorable surface of a solid compact and orderly. (author)

  2. Observation of contact area of bubbles with heating surface in pool boiling of water under microgravity

    International Nuclear Information System (INIS)

    Suzuki, K.; Kawamura, H.; Suzuki, M.; Takahashi, S.; Abe, Y.

    2003-01-01

    Burnout heat flux was measured in subcooled pool boiling of water under attached boiling bubbles on heating surface with bubble holding plate in ground experiment. A thin stainless flat plate was employed for heating surface. The experimental setup and the heating procedures were same as used in reduced gravity experiment performed by a parabolic flight of jet aircraft. Same burnout heat flux as in the reduced gravity was obtained by adjusting the clearance between the bubble holder and the heating surface. They were 100 ∝ 400 percent higher than the widely accepted existing theories. As extending heating time longer than the reduced gravity duration until burnout occurred, burnout heat flux decreased gradually and became a constant value calculated from the existing theories. In a result of observing contact area of boiling bubbles with transparent heating surface, the contact area was smaller in quick heating time than that in long time heating at same heat flux. The experimental results suggest in microgravity that liquid layer is remained between rapidly expanded bubbles and heating surface. In microgravity experiment by a drop shaft facility, contact area of bubbles with heating surface increased considerably at starting of microgravity. (orig.)

  3. City landscape changes effects on land surface temperature in Bucharest metropolitan area

    Science.gov (United States)

    Savastru, Dan M.; Zoran, Maria A.; Savastru, Roxana S.; Dida, Adrian I.

    2017-10-01

    This study investigated the influences of city land cover changes and extreme climate events on land surface temperature in relationship with several biophysical variables in Bucharest metropolitan area of Romania through satellite and in-situ monitoring data. Remote sensing data from IKONOS, Landsat TM/ETM+ and time series MODIS Terra/Aqua and NOAA AVHRR sensors have been used to assess urban land cover- temperature interactions over 2000 - 2016 period. Time series Thermal InfraRed (TIR) satellite remote sensing data in synergy with meteorological data (air temperatureAT, precipitations, wind, solar radiation, etc.) were applied mainly for analyzing land surface temperature (LST) pattern and its relationship with surface landscape characteristics, assessing urban heat island (UHI), and relating urban land cover temperatures (LST). The land surface temperature, a key parameter for urban thermal characteristics analysis, was also analyzed in relation with the Normalized Difference Vegetation Index (NDVI) at city level. Results show that in the metropolitan area ratio of impervious surface in Bucharest increased significantly during investigated period, the intensity of urban heat island and heat wave events being most significant. The correlation analyses revealed that, at the pixel-scale, LST and AT possessed a strong positive correlation with percent impervious surfaces and negative correlation with vegetation abundances at metropolitan scale respectively. The NDVI was significantly correlated with precipitation. The spatial average air temperatures in urban test areas rise with the expansion of the urban size.

  4. Description of surface systems. Preliminary site description Simpevarp sub area - Version 1.2

    International Nuclear Information System (INIS)

    Lindborg, Tobias

    2005-03-01

    Swedish Nuclear Fuel and Waste Management Co is currently conducting site characterisation in the Simpevarp area. The area is divided into two subareas, the Simpevarp and the Laxemar subarea. The two subareas are surrounded by a common regional model area, the Simpevarp area. This report describes both the regional area and the subareas. This report is an interim version (model version 1.2) of the description of the surface systems at the Simpevarp area, and should be seen as a background report to the site description of the Simpevarp area, version 1.2, SKB-R--05-08. The basis for this description is quality-assured field data available in the SKB SICADA and GIS databases, together with generic data from the literature. The Surface system, here defined as everything above the bedrock, comprises a number of separate disciplines (e.g. hydrology, geology, topography, oceanography and ecology). Each discipline has developed descriptions and models for a number of properties that together represent the site description. The current methodology for developing the surface system description and the integration to ecosystem models is documented in a methodology strategy report SKB-R--03-06. The procedures and guidelines given in that report were followed in this report. Compared with version 1.1 of the surface system description SKB-R--04-25, this report presents considerable additional features, especially in the ecosystem description (Chapter 4) and in the description of the surface hydrology (Section 3.4). A first attempt has also been made to connect the flow of matter (carbon) between the different ecosystems into an overall ecosystem model at a landscape level. A summarised version of this report is also presented in SKB-R--05-08 together with geological-, hydrogeological-, transport properties-, thermal properties-, rock mechanics- and hydrogeochemical descriptions

  5. Description of surface systems. Preliminary site description Simpevarp sub area - Version 1.2

    Energy Technology Data Exchange (ETDEWEB)

    Lindborg, Tobias (ed.)

    2005-03-01

    Swedish Nuclear Fuel and Waste Management Co is currently conducting site characterisation in the Simpevarp area. The area is divided into two subareas, the Simpevarp and the Laxemar subarea. The two subareas are surrounded by a common regional model area, the Simpevarp area. This report describes both the regional area and the subareas. This report is an interim version (model version 1.2) of the description of the surface systems at the Simpevarp area, and should be seen as a background report to the site description of the Simpevarp area, version 1.2, SKB-R--05-08. The basis for this description is quality-assured field data available in the SKB SICADA and GIS databases, together with generic data from the literature. The Surface system, here defined as everything above the bedrock, comprises a number of separate disciplines (e.g. hydrology, geology, topography, oceanography and ecology). Each discipline has developed descriptions and models for a number of properties that together represent the site description. The current methodology for developing the surface system description and the integration to ecosystem models is documented in a methodology strategy report SKB-R--03-06. The procedures and guidelines given in that report were followed in this report. Compared with version 1.1 of the surface system description SKB-R--04-25, this report presents considerable additional features, especially in the ecosystem description (Chapter 4) and in the description of the surface hydrology (Section 3.4). A first attempt has also been made to connect the flow of matter (carbon) between the different ecosystems into an overall ecosystem model at a landscape level. A summarised version of this report is also presented in SKB-R--05-08 together with geological-, hydrogeological-, transport properties-, thermal properties-, rock mechanics- and hydrogeochemical descriptions.

  6. Evaporation and wetted area of single droplets on waxy and hairy leaf surfaces.

    Science.gov (United States)

    Zhu, H; Yu, Y; Ozkan, H E; Derksen, R C; Krause, C R

    2008-01-01

    Understanding the evaporation of pesticide droplets and wetting of Leaf surfaces can increase foliar application efficiency and reduce pesticide use. Evaporation time and wetted area of single pesticide droplets on hairy and waxy geranium leaf surfaces were measured under the controlled conditions for five droplet sizes and three relative humidities. The sprays used to form droplets included water, a nonionic colloidal polymer drift retardant, an alkyl polyoxyethylene surfactant, and an insecticide. Adding the surfactant into spray mixtures greatly increased droplet wetted area on the surfaces while droplet evaporation time was greatly reduced. Adding the drift retardant into spray mixture slightly increased the droplet evaporation time and the wetted area. Also, droplets had Longer evaporation times on waxy leaves than on hairy leaves for all droplet diameters and all relative humidity conditions. Increasing relative humidity could increase the droplet evaporation time greatly but did not change the the wetted area. The droplet evaporation time and wetted area increased exponentially as the droplet size increased. Therefore, droplet size, surface characteristics of the target, relative humidity, and chemical composition of the spray mixtures (water alone, pesticide, additives) should be included as important factors that affect the efficacy and efficiency of pesticide applications.

  7. Measuring variation of indoor radon concentration using bare nuclear tracks detectors, scintillation counters and surface barrier detectors

    International Nuclear Information System (INIS)

    Ishak, I.; Mahat, R.H.; Amin, Y.M.

    1996-01-01

    Bare LRI 15 nuclear track detectors , scintillators counter and surface barrier detectors were used to measured the indoor radon concentration in various location within two rooms. Spatial variation of the radon concentration is caused by positioning of the door, windows, furniture, cracks in the building and also distances from floor, wall and ceiling. It is found that the change in temperature are causing radon concentration to increase at certain time of the day

  8. Concentrations and health risk assessment of rare earth elements in vegetables from mining area in Shandong, China.

    Science.gov (United States)

    Zhuang, Maoqiang; Zhao, Jinshan; Li, Suyun; Liu, Danru; Wang, Kebo; Xiao, Peirui; Yu, Lianlong; Jiang, Ying; Song, Jian; Zhou, Jingyang; Wang, Liansen; Chu, Zunhua

    2017-02-01

    To investigate the concentrations of rare earth elements in vegetables and assess human health risk through vegetable consumption, a total of 301 vegetable samples were collected from mining area and control area in Shandong, China. The contents of 14 rare earth elements were determined by Inductively Coupled Plasma-Mass Spectrometry (ICP-MS). The total rare earth elements in vegetables from mining and control areas were 94.08 μg kg -1 and 38.67 μg kg -1 , respectively, and the difference was statistically significant (p rare earth elements concentration (984.24 μg kg -1 and 81.24 μg kg -1 for mining and control areas, respectively) and gourd vegetable had the lowest rare earth elements concentration (37.34 μg kg -1 and 24.63 μg kg -1 for mining and control areas, respectively). For both areas, the rare earth elements concentration in vegetables declined in the order of leaf vegetable > taproot vegetable > alliaceous vegetable > gourd vegetable. The rare earth elements distribution patterns for both areas were characterized by enrichment of light rare earth elements. The health risk assessment demonstrated that the estimated daily intakes (0.69 μg kg -1 d -1 and 0.28 μg kg -1 d -1 for mining and control areas, respectively) of rare earth elements through vegetable consumption were significantly lower than the acceptable daily intake (70 μg kg -1 d -1 ). The damage to adults can be neglected, but more attention should be paid to the effects of continuous exposure to low levels of rare earth elements on children. Copyright © 2016 Elsevier Ltd. All rights reserved.

  9. Transparent self-cleaning lubricant-infused surfaces made with large-area breath figure patterns

    Science.gov (United States)

    Zhang, Pengfei; Chen, Huawei; Zhang, Liwen; Ran, Tong; Zhang, Deyuan

    2015-11-01

    Nepenthes pitcher inspired slippery lubricant-infused porous surfaces greatly impact the understanding of liquid-repellent surfaces construction and have attracted extensive attention in recent years due to their potential applications in self-cleaning, anti-fouling, anti-icing, etc. In this work, we have successfully fabricated transparent slippery lubricant-infused surfaces based on breath figure patterns (BFPs). Large-area BFPs with interconnected pores were initially formed on the glass substrate and then a suitable lubricant was added onto the surfaces. The interconnected pores in BFPs were able to hold the lubricant liquid in place and form a stable liquid/solid composite surface capable of repelling a variety of liquids. The liquid-repellent surfaces show extremely low critical sliding angles for various liquids, thus providing the surfaces with efficient self-cleaning property. It was also found that the liquid droplets' sliding behaviors on the surfaces were significantly influenced by the tilting angle of the substrate, liquid volume, liquid chemical properties, and pore sizes of the surfaces.

  10. Variations in time and space of trace metal aerosol concentrations in urban areas and their surroundings

    Science.gov (United States)

    Moreno, T.; Querol, X.; Alastuey, A.; Reche, C.; Cusack, M.; Amato, F.; Pandolfi, M.; Pey, J.; Richard, A.; Prévôt, A. S. H.; Furger, M.; Gibbons, W.

    2011-09-01

    Using an unprecedentedly large geochemical database, we compare temporal and spatial variations in inhalable trace metal background concentrations in a major city (Barcelona, Spain) and at a nearby mountainous site (Montseny) affected by the urban plume. Both sites are contaminated by technogenic metals, with V, Pb, Cu, Zn, Mn, Sn, Bi, Sb and Cd all showing upper continental crust (UCC) normalised values >1 in broadly increasing order. The highest metal concentrations usually occur during winter at Barcelona and summer in Montseny. This seasonal difference was especially marked at the remote mountain site in several elements such as Ti and Rare Earth Elements, which recorded campaign maxima, exceeding PM10 concentrations seen in Barcelona. The most common metals were Zn, Ti, Cu, Mn, Pb and V. Both V and Ni show highest concentrations in summer, and preferentially fractionate into the finest PM sizes (PM1/PM10 > 0.5) especially in Barcelona, this being attributed to regionally dispersed contamination from fuel oil combustion point sources. Within the city, hourly metal concentrations are controlled either by traffic (rush hour double peak for Cu, Sb, Sn, Ba) or industrial plumes (morning peak of Ni, Mn, Cr generated outside the city overnight), whereas at Montseny metal concentrations rise during the morning to a single, prolonged afternoon peak as contaminated air transported by the sea breeze moves into the mountains. Our exceptional database, which includes hourly measurements of chemical concentrations, demonstrates in more detail than previous studies the spatial and temporal variability of urban pollution by trace metals in a given city. Technogenic metalliferous aerosols are commonly fine in size and therefore potentially bioavailable, emphasising the case for basing urban background PM characterisation not only on physical parameters such as mass but also on sample chemistry and with special emphasis on trace metal content.

  11. Monitoring of nutrients concentration in surface waters of small mid-field water bodies in agricultural watershed

    Directory of Open Access Journals (Sweden)

    Katarzyna Ligocka

    2018-04-01

    Full Text Available Studies were conducted on surface waters of mid-field ponds in agricultural watershed. The resarch were aimed to perform introductory assessment of ammoniacal nitrogen's and nitric nitrogen's aswell as phosphates concentrations in surface waters. The studies have been performed from March to October, 2015 to 2017. The highest concentration of phosphates were detected in year 2017, whereas the highest concentrations of these were experienced in June in every year. The lowest concentration of phosphates were detected in the first year of studies (2015. The average concentration of phosphate got higher every year. Phosphates' concentrations got higher from March to October, however, the decline were experienced in later period. Conducted research confirmed the dependence, that in lower temperatures the concentrations of ammonia cal nitrogen were generally lower than in the months with higher average temperature. The highest average concentration of ammonia cal nitrogen (0,29 mg•kg -1 was detected in the first year of studies (2015. Average concentrations of nitric nitrogen’s fluctuates from from 0,15 to 0,24 mg•kg -1 . In every year, the concentrations of nitrates were highest in June. The lowest concentrations of nitrates in 2015 and 2016 were experienced in August, and in July of 2017.

  12. Heavy metal contamination of surface soil in electronic waste dismantling area: site investigation and source-apportionment analysis.

    Science.gov (United States)

    Jinhui Li; Huabo Duan; Pixing Shi

    2011-07-01

    The dismantling and disposal of electronic waste (e-waste) in developing countries is causing increasing concern because of its impacts on the environment and risks to human health. Heavy-metal concentrations in the surface soils of Guiyu (Guangdong Province, China) were monitored to determine the status of heavy-metal contamination on e-waste dismantling area with a more than 20 years history. Two metalloids and nine metals were selected for investigation. This paper also attempts to compare the data among a variety of e-waste dismantling areas, after reviewing a number of heavy-metal contamination-related studies in such areas in China over the past decade. In addition, source apportionment of heavy metal in the surface soil of these areas has been analysed. Both the MSW open-burning sites probably contained invaluable e-waste and abandoned sites formerly involved in informal recycling activities are the new sources of soil-based environmental pollution in Guiyu. Although printed circuit board waste is thought to be the main source of heavy-metal emissions during e-waste processing, requirement is necessary to soundly manage the plastic separated from e-waste, which mostly contains heavy metals and other toxic substances.

  13. Size resolved mass concentration and elemental composition of atmospheric aerosols over the Eastern Mediterranean area

    Directory of Open Access Journals (Sweden)

    J. Smolík

    2003-01-01

    Full Text Available A Berner low pressure impactor was used to collect size-segregated aerosol samples at Finokalia, located on the north-eastern coast of Crete, Greece during July 2000 and January 2001. Several samples were also collected during the summer campaign aboard the research vessel "AEGAIEO" in the Aegean Sea. Gravimetric analysis and inversion techniques yielded daily PM1 and PM10 mass concentrations. The samples were also analysed by PIXE giving the elemental size distributions of Al, Si, K, Ca, Ti, Mn, Fe, Sr, S, Cl, Ni, V, Cu, Cr, Zn, and Pb. The crustal elements and sea-salt had a unimodal supermicron size distribution. Sulphur was found predominantly in submicron fractions. K, V, and Ni exhibited a bimodal distribution with a submicron mode produced by forest fires and oil combustion. The anthropogenic elements had broad and not well-defined distributions. The time series for PM1 and PM10 mass and elemental concentrations showed both daily and seasonal variation. Higher mass concentrations were observed during two incursions of Saharan dust, whilst higher concentrations of S, Cu, Zn, and Pb were encountered in samples collected in air masses arriving from northern Greece or the western coast of Turkey. Elevated concentrations of chlorine were found in samples with air masses either originating above the Atlantic Ocean and arriving at Finokalia via western Europe or recirculating over the western coast of the Black Sea.

  14. Fractional-Slot Surface Mounted PM Motors with Concentrated Windings for HEV Traction Drives

    Energy Technology Data Exchange (ETDEWEB)

    Bailey, J.M.

    2005-10-24

    High-power density and efficiency resulting from elimination of rotor windings and reduced magnetic-flux losses have made the rare earth permanent magnet (PM) motor a leading candidate for the Department of Energy's Office of FreedomCAR and Vehicle Technologies (FCVTs) traction drive motor. These traction drives are generally powered by radial-gap motors, having the magnets on or embedded in a rotating cylinder separated from the inside surface of a slotted cylindrical stator by an annular gap. The two main types of radial-gap PM rotors are those with magnets mounted on the surface of a supporting back iron, called PM surface mounted (PMSM) motors, and those with magnets mounted in slots in the rotor, called interior PM (IPM) motors. Most early PM motor research was on the PMSM motor, which was thought to have an inherently low stator inductance. A low stator inductance can lead to currents dangerously exceeding rated current as the back-emf across the inductance increases with speed; consequently, part of the attempted solution has been to increase the stator inductance to reduce the rate of current rise. Although analysis suggested that there should be no problem designing sufficiently high stator inductance into PMSMs, attempts to do so were often not successful and a motor design was sought that would have a higher intrinsic inductance. Commercial research at Toyota has focused on IPM motors because they can achieve a high-saliency ratio, which helps them operate over a high constant power speed ratio (CPSR), but they are more difficult to fabricate. The Oak Ridge National Laboratory's (ORNL) position has been to continue research on brushless direct current (dc) motors (BDCMs) because of ease of fabrication and increased power output. Recently there has been a revival of interest in a fractional-slot PMSMs [15] made with concentrated windings because they possess three important features. First, they can increase the motor's inductance

  15. Tritium concentrations in flow from selected springs that discharge to the Snake River, Twin Falls-Hagerman area, Idaho

    International Nuclear Information System (INIS)

    Mann, L.J.

    1989-01-01

    Concern has been expressed that some of the approximately 30,900 curies of tritium disposed to the Snake River Plain aquifer from 1952 to 1988 at the INEL (idaho National Engineering Laboratory) have migrated to springs discharging to the Snake River in the Twin Falls-Hagerman area. To document tritium concentrations in springflow, 17 springs were sampled in November 1988 and 19 springs were sampled in March 1989. Tritium concentrations were less than the minimum detectable concentration of 0.5 pCi/mL (picocuries/mL) in November 1988 and less than the minimum detectable concentration of 0.2 pCi/mL in March 1989 the minimum detectable concentration was smaller in March 1989. The maximum contaminant level of tritium in drinking water as established by the US Environmental Protection Agency is 20 pCi/mL. US Environmental Protection Agency sample analyses indicate that the tritium concentration has decreased in the Snake River near Buhl since the 1970's. In 1974-79, tritium concentrations were less than 0.3 ± 0.2 pCi/mL in 3 of 20 samples; in 1983-88, 17 of 23 samples contaminated less than 0.3 ± 0.2 pCi/mL of tritium; the minimum detectable concentration is 0.2 pCi/mL. On the basis of decreasing tritium concentrations in the Snake River, their correlation to cessation of atmospheric weapons tests tritium concentrations in springflow less than the minimum detectable concentration, and the distribution of tritium in groundwater at the INEL, aqueous disposal of tritium at the INEL has had no measurable effect on tritium concentrations in springflow from the Snake River Plain aquifer and in the Snake River near Buhl. 15 refs., 2 figs., 3 tabs

  16. Distribution of Mercury Concentrations in Tree Rings and Surface Soils Adjacent to a Phosphate Fertilizer Plant in Southern Korea.

    Science.gov (United States)

    Jung, Raae; Ahn, Young Sang

    2017-08-01

    This study aimed to determine mercury concentrations in tree rings and surface soils at distances of 4, 26 and 40 km from a fertilizer plant located in Yeosu City, Korea. Mercury concentrations in all tree rings were low prior to the establishment of the plant in 1977 and became elevated thereafter. The highest average mercury concentration in the tree rings was 11.96 ng g -1 at the Yeosu site located nearest to the plant, with the lowest average mercury concentration of 4.45 ng g -1 at the Suncheon site furthest away from the plant. In addition, the highest mercury content in the surface soil was 108.51 ng cm -3 at the Yeosu site, whereas the lowest mercury content in the surface soil was 31.47 ng cm -3 at the Suncheon site. The mercury levels decreased gradually with increasing distance from the plant.

  17. Asymmetric correlations in the ozone concentration dynamics of the Mexico City Metropolitan Area

    Science.gov (United States)

    Meraz, M.; Alvarez-Ramirez, J.; Echeverria, J. C.

    2017-04-01

    Mexico City is a megalopolis with severe pollution problems caused by vehicles and industrial activity. This condition imposes important risks to human health and economic activity. Based on hourly-sampled data during the last decade, in a recent work (Meraz et al., 2015) we showed that the pollutant dynamics in Mexico City exhibits long-term and scale-dependent persistence effects resulting from the combination of pollutants generation by vehicles and removal by advection mechanisms. In this work, we analyzed the dynamics of ozone, a key component reflecting the degree of atmospheric contamination, to determine if its long-term correlations are asymmetric in relation to the actual concentration trend (increasing or decreasing). The analysis is conducted with detrended fluctuation analysis. The results showed that the average ozone dynamics is uncorrelated when the concentration is increasing. In contrast, the ozone dynamics shows long-term anti-persistence effects when the concentration is decreasing.

  18. Surface area and the seabed area, volume, depth, slope, and topographic variation for the world's seas, oceans, and countries.

    Science.gov (United States)

    Costello, Mark John; Cheung, Alan; De Hauwere, Nathalie

    2010-12-01

    Depth and topography directly and indirectly influence most ocean environmental conditions, including light penetration and photosynthesis, sedimentation, current movements and stratification, and thus temperature and oxygen gradients. These parameters are thus likely to influence species distribution patterns and productivity in the oceans. They may be considered the foundation for any standardized classification of ocean ecosystems and important correlates of metrics of biodiversity (e.g., species richness and composition, fisheries). While statistics on ocean depth and topography are often quoted, how they were derived is rarely cited, and unless calculated using the same spatial resolution the resulting statistics will not be strictly comparable. We provide such statistics using the best available resolution (1-min) global bathymetry, and open source digital maps of the world's seas and oceans and countries' Exclusive Economic Zones, using a standardized methodology. We created a terrain map and calculated sea surface and seabed area, volume, and mean, standard deviation, maximum, and minimum, of both depth and slope. All the source data and our database are freely available online. We found that although the ocean is flat, and up to 71% of the area has a ocean volume exceeds 1.3 billion km(3) (or 1.3 sextillion liters), and sea surface and seabed areas over 354 million km(2). We propose the coefficient of variation of slope as an index of topographic heterogeneity. Future studies may improve on this database, for example by using a more detailed bathymetry, and in situ measured data. The database could be used to classify ocean features, such as abyssal plains, ridges, and slopes, and thus provide the basis for a standards based classification of ocean topography.

  19. Analysis of 25(OHD serum concentrations of hospitalized elderly patients in the Shanghai area.

    Directory of Open Access Journals (Sweden)

    Xudong Mao

    Full Text Available OBJECTIVE: To find an association between basic characteristics, seasons as well as disease types and 25-Hydroxyvitamin D serum concentrations in Chinese patients. METHODS: We randomly selected 5470 Chinese patients with various diseases, who were hospitalized between May 2012 and August 2013 in Shanghai and analyzed their serum 25-Hydroxyvitamin D2 (25 (OHD2 and 25-Hydroxyvitamin D3 (25(OHD3 concentrations with liquid chromatography-tandem mass spectrometry (LC-MS/MS as well as their parathyroid hormone (PTH and serum creatinine blood levels. The resulting data were analyzed by linear regression and variance analyses or multivariate analysis with covariance. RESULTS: The 25(OHD serum concentrations were lowest in December. Among the subjects with a median age of 83.0 ± 16.0, the median 25(OHD2, 25(OHD3 and total 25(OHD serum concentrations were 1.00 ± 1.80 ng/ml, 12.20 ± 8.50 ng/ml and 14.80 ± 9.80 respectively, indicating a prevalent 25(OHD deficiency. According to our multivariate analysis of covariance, the factors affecting 25(OHD2 and 25(OHD3 serum concentrations included age, creatinine, PTH, season and type of disease, whereas gender correlated only with 25(OHD2 and 25(OHD2 and D3 values correlated negatively with each other. Our results further revealed that 25(OHD3 levels were low while 25(OHD2 levels were high among patients with lung diseases, dyskinesia and coronary heart diseases. In addition, participants with diabetes and cerebral infarction had higher 25(OHD3 serum concentrations compared with lung disease patients. CONCLUSION: Vitamin D intake particularly during winter and summer seasons is important especially for elderly lung disease, dyskinesia and coronary heart disease patients to improve their quality of life.

  20. Quantitative estimation of hydrogen concentration on the Ni3Al specimens surface in the process of hydrogen release

    International Nuclear Information System (INIS)

    Katano, Gen; Sano, Shogo; Saito, Hideo; Mori, Minoru

    2000-01-01

    The method to calculate the hydrogen concentration in metal specimens is given by tritium counts with the liquid scintillation counter. As segments to measure, Ni 3 Al intermetallic compound crystals were used. Tritium was charged to crystals with the method of cathode charging. The charged tritium was transported by diffusion and released from specimen surface. The tritium releasing rate was calculated from the increasing rate of tritium activity. Then the concentration of hydrogen at the surface was calculated from tritium counts. The outcome showed that the hydrogen concentration decreases at specimens surface by elapsed time. Then, the behavior of tritium diffusion was affected by doped boron (up to 0.235 atom% B and 0.470 atom% B) in Ni 3 Al crystals. As the amount of boron increased, the tritium diffusion coefficient decreased. And the hydrogen concentration varied with the amount of boron. After passing enough time, the hydrogen concentration in crystals with boron was much larger than the one without boron. Since it is very likely that the hydrogen concentration is affected by the number of hydrogen sites in the crystal, it is obvious judging by these phenomena, that by doping boron, numbers of hydrogen trapping sites were created. As the hydrogen distribution becomes homogenous after passing enough time, it is possible to measure the hydrogen concentration in all the crystals from β-ray counts at specimens surface. (author)

  1. Rapid Adjustments Cause Weak Surface Temperature Response to Increased Black Carbon Concentrations

    Science.gov (United States)

    Stjern, Camilla Weum; Samset, Bjørn Hallvard; Myhre, Gunnar; Forster, Piers M.; Hodnebrog, Øivind; Andrews, Timothy; Boucher, Olivier; Faluvegi, Gregory; Iversen, Trond; Kasoar, Matthew; Kharin, Viatcheslav; Kirkevâg, Alf; Lamarque, Jean-François; Olivié, Dirk; Richardson, Thomas; Shawki, Dilshad; Shindell, Drew; Smith, Christopher J.; Takemura, Toshihiko; Voulgarakis, Apostolos

    2017-11-01

    We investigate the climate response to increased concentrations of black carbon (BC), as part of the Precipitation Driver Response Model Intercomparison Project (PDRMIP). A tenfold increase in BC is simulated by nine global coupled-climate models, producing a model median effective radiative forcing of 0.82 (ranging from 0.41 to 2.91) W m-2, and a warming of 0.67 (0.16 to 1.66) K globally and 1.24 (0.26 to 4.31) K in the Arctic. A strong positive instantaneous radiative forcing (median of 2.10 W m-2 based on five of the models) is countered by negative rapid adjustments (-0.64 W m-2 for the same five models), which dampen the total surface temperature signal. Unlike other drivers of climate change, the response of temperature and cloud profiles to the BC forcing is dominated by rapid adjustments. Low-level cloud amounts increase for all models, while higher-level clouds are diminished. The rapid temperature response is particularly strong above 400 hPa, where increased atmospheric stabilization and reduced cloud cover contrast the response pattern of the other drivers. In conclusion, we find that this substantial increase in BC concentrations does have considerable impacts on important aspects of the climate system. However, some of these effects tend to offset one another, leaving a relatively small median global warming of 0.47 K per W m-2—about 20% lower than the response to a doubling of CO2. Translating the tenfold increase in BC to the present-day impact of anthropogenic BC (given the emissions used in this work) would leave a warming of merely 0.07 K.

  2. Baseline Radionuclide and Nonradionuclide Concentrations in Soils, Vegetation, and Small Mammals at the Proposed Expansion Area at TA-54 Area G

    Energy Technology Data Exchange (ETDEWEB)

    D. D. Romero, P. R. Fresquez

    2007-11-30

    Area G is a 25.5-hectare (63-acre), fenced, low-level radioactive solid waste processing and disposal area located on the east end of Mesa del Buey at Technical Area 54 at Los Alamos National Laboratory. This disposal area has been in existence since 1957 and is expected to be filled by the year 2015. Thus, a new area, located adjacent to Area G on the west side, has been proposed for the expansion of disposal activities. Since 1994 to the present, baseline levels of several radionuclides and nonradionuclides have been collected in soils, vegetation, and small mammals (field mice and rock squirrels). These data will be used to assess potential impacts, if any, at the expanded site once operations begin. Baseline statistical reference levels (BSRLs) (mean plus three standard deviations = 99% confidence level) of radionuclides and nonradionuclides in these media were calculated and compared with regional statistical reference levels (RSRLs). RSRLs are calculated from regional areas away from the influence of the Laboratory and represent natural and worldwide fallout sources. BSRLs in most media, with the exception of field mice (mostly Peromyscus spp.), compare very well with RSRLs. Field mice, probably because they are mobile and may have spent time within the active disposal area, appeared to be impacted by Area G operations as they contained higher concentrations of {sup 3}H, {sup 238}Pu, {sup 239,240}Pu, and {sup 241}Am as compared to RSRLs. Overall, however, the preoperational data from the other media show that the proposed expansion area has been impacted very little by Area G operations.

  3. Radionuclide Concentrations in soils an Vegetation at Low-Level Radioactive Waste Disposal Area G During 2004

    International Nuclear Information System (INIS)

    Fresquez, P.R.; Lopez, E.A.

    2004-01-01

    Soil samples were collected at 15 locations and unwashed overstory and understory vegetation samples were collected at nine locations within and around the perimeter of Area G, the primary disposal facility for low-level radioactive solid waste at Los Alamos National Laboratory (LANL). These samples were analyzed for 3 H, 238 Pu, 239,240 Pu, 90 Sr, 241 Am, 137 Cs, 234 U, 235 U, and 238 U. Soil samples collected at Area G contained detectable concentrations of 3H (27%), 239,240 Pu (60%), 238 Pu (40%), and 241 Am (47%) above regional statistical reference levels (RSRLs). In contrast, the levels of 137 Cs, 90 Sr, and U in all of the soil samples at Area G were either nondetectable or within RSRLs. The highest levels of 3 H in soils were detected in the southwestern portion of Area G near the 3 H shafts, whereas the highest concentrations of the Pu isotopes were detected in the northern and northeastern portions. All concentrations of 3 H and Pu in soils, however, were far below LANL screening action levels. As for vegetation, most radionuclides in/on plants were either nondetectable or within RSRLs. The exceptions were 3 H in overstory and some understory vegetation, particularly in the southwestern portion of Area G, which correlated very well with the soils data in that area. Also, there was some foliar contamination from 241 Am and Pu isotopes in/on a few plant samples--the highest concentrations occurring in the northern section of Area G

  4. Radionuclide Concentrations in soils an Vegetation at Low-Level Radioactive Waste Disposal Area G During 2004

    Energy Technology Data Exchange (ETDEWEB)

    P.R. Fresquez; E.A. Lopez

    2004-11-01

    Soil samples were collected at 15 locations and unwashed overstory and understory vegetation samples were collected at nine locations within and around the perimeter of Area G, the primary disposal facility for low-level radioactive solid waste at Los Alamos National Laboratory (LANL). These samples were analyzed for {sup 3}H, {sup 238}Pu, {sup 239,240}Pu, {sup 90}Sr, {sup 241}Am, {sup 137}Cs, {sup 234}U, {sup 235}U, and {sup 238}U. Soil samples collected at Area G contained detectable concentrations of 3H (27%), {sup 239,240}Pu (60%), {sup 238}Pu (40%), and {sup 241}Am (47%) above regional statistical reference levels (RSRLs). In contrast, the levels of {sup 137}Cs, {sup 90}Sr, and U in all of the soil samples at Area G were either nondetectable or within RSRLs. The highest levels of {sup 3}H in soils were detected in the southwestern portion of Area G near the {sup 3}H shafts, whereas the highest concentrations of the Pu isotopes were detected in the northern and northeastern portions. All concentrations of {sup 3}H and Pu in soils, however, were far below LANL screening action levels. As for vegetation, most radionuclides in/on plants were either nondetectable or within RSRLs. The exceptions were {sup 3}H in overstory and some understory vegetation, particularly in the southwestern portion of Area G, which correlated very well with the soils data in that area. Also, there was some foliar contamination from {sup 241}Am and Pu isotopes in/on a few plant samples--the highest concentrations occurring in the northern section of Area G.

  5. Heavy metals concentration and distribution in soils and vegetation at Korle Lagoon area in Accra, Ghana

    DEFF Research Database (Denmark)

    Fosu-Mensah, Benedicta Yayra; Addae, Emmanuel; Yirenya-Tawiah, Dzidzo

    2017-01-01

    The call for reclamation of land around Korle Lagoon in Accra, Ghana, where burning of E-waste and cultivation of vegetables takes place, make risk assessment of heavy metal contaminations important. This study aimed at evaluating the levels and risk of heavy metal contamination in soils and vege......The call for reclamation of land around Korle Lagoon in Accra, Ghana, where burning of E-waste and cultivation of vegetables takes place, make risk assessment of heavy metal contaminations important. This study aimed at evaluating the levels and risk of heavy metal contamination in soils...... and vegetation around the Korle lagoon area in Accra. Geoaccumulation index, enrichment factor and pollution load index were determined to assess the risk of contamination. The levels and distribution of nine heavy metals (Pb, Hg, Cd, As, Zn, Sn, Ni, Cu and Cr) in soil (0 – 20 cm) and common vegetation (Panicum...... maximum, Imperata cylindrica, Lactuca sativa and Hibiscus sabdariffa) from the area using Atomic Absorption Spectrometer (AAS) were assessed. The area was divided into five sites namely; the e-waste site (S1), gardens area (S2), recreational area (S3), reclaimed area (S4) estuary (S5), and the control (S6...

  6. Snow specific surface area simulation using the one-layer snow model in the Canadian LAnd Surface Scheme (CLASS

    Directory of Open Access Journals (Sweden)

    A. Roy

    2013-06-01

    Full Text Available Snow grain size is a key parameter for modeling microwave snow emission properties and the surface energy balance because of its influence on the snow albedo, thermal conductivity and diffusivity. A model of the specific surface area (SSA of snow was implemented in the one-layer snow model in the Canadian LAnd Surface Scheme (CLASS version 3.4. This offline multilayer model (CLASS-SSA simulates the decrease of SSA based on snow age, snow temperature and the temperature gradient under dry snow conditions, while it considers the liquid water content of the snowpack for wet snow metamorphism. We compare the model with ground-based measurements from several sites (alpine, arctic and subarctic with different types of snow. The model provides simulated SSA in good agreement with measurements with an overall point-to-point comparison RMSE of 8.0 m2 kg–1, and a root mean square error (RMSE of 5.1 m2 kg–1 for the snowpack average SSA. The model, however, is limited under wet conditions due to the single-layer nature of the CLASS model, leading to a single liquid water content value for the whole snowpack. The SSA simulations are of great interest for satellite passive microwave brightness temperature assimilations, snow mass balance retrievals and surface energy balance calculations with associated climate feedbacks.

  7. Variation of NO2 and NOx concentrations between and within 36 European study areas: Results from the ESCAPE study

    NARCIS (Netherlands)

    Cyrys, J.; Eeftens, M.R.|info:eu-repo/dai/nl/315028300; Heinrich, J.; Ampe, C.; Armengaud, A.; Beelen, R.; Bellander, T.; Beregszaszi, T.; Birk, M.; Cesaroni, G.; Cirach, M.; de Hoogh, K.; de Nazelle, A.; de Vocht, F.; Declercq, C.; Dėdelė, A.; Dimakopoulou, K.; Eriksen, K.; Galassi, C.; Grąulevičienė, R.; Grivas, G.; Gruzieva, O.; Gustafsson, A.H.; Hoffmann, B.; Iakovides, M.; Ineichen, A.; Krämer, U.; Lanki, T.; Lozano, P.; Madsen, C.; Meliefste, K.; Modig, L.; Mölter, A.; Mosler, G.; Nieuwenhuijsen, M.; Nonnemacher, M.; Oldenwening, M.; Peters, A.; Pontet, S.; Probst-Hensch, N.; Quass, U.; Raaschou-Nielsen, O.; Ranzi, A.; Sugiri, D.; Stephanou, E.G.; Taimisto, P.; Tsai, M-Y.; Vaskövi, É.; Villani, S.; Wang, M.|info:eu-repo/dai/nl/345480279; Brunekreef, B.|info:eu-repo/dai/nl/067548180; Hoek, G.|info:eu-repo/dai/nl/069553475

    2012-01-01

    The ESCAPE study (European Study of Cohorts for Air Pollution Effects) investigates long-term effects of exposure to air pollution on human health in Europe. This paper documents the spatial variation of measured NO2 and NOx concentrations between and within 36 ESCAPE study areas across Europe. In

  8. Stunting and zinc deficiency among primary school children in rural areas with low soil zinc concentrations in Jiangsu Province, China

    NARCIS (Netherlands)

    Qin, Yu; Boonstra, A.; Zhao, J.; Wu, M.; Hu, X.; Kok, F.J.

    2009-01-01

    OBJECTIVE: To assess stunting and zinc deficiency among primary school children in north rural area of Jiangsu Province with low soil zinc concentrations, eastern part of China. METHODS: Two data collection rounds were conducted. In the first data collection round, 2268 primary school children aged

  9. Impact of microstructure evolution on the difference between geometric and reactive surface areas in natural chalk

    Science.gov (United States)

    Yang, Y.; Bruns, S.; Stipp, S. L. S.; Sørensen, H. O.

    2018-05-01

    The coupling between flow and mineral dissolution drives the evolution of many natural and engineered flow systems. Pore surface changes as microstructure evolves but this transient behaviour has traditionally been difficult to model. We combined a reactor network model with experimental, greyscale tomography data to establish the morphological grounds for differences among geometric, reactive and apparent surface areas in dissolving chalk. This approach allowed us to study the effects of initial geometry and macroscopic flow rate independently. The simulations showed that geometric surface, which represents a form of local transport heterogeneity, increases in an imposed flow field, even when the porous structure is chemically homogeneous. Hence, the fluid-reaction coupling leads to solid channelisation, which further results in fluid focusing and an increase in geometric surface area. Fluid focusing decreases the area of reactive surface and the residence time of reactant, both contribute to the over-normalisation of reaction rate. In addition, the growing and merging of microchannels, near the fluid entrance, contribute to the macroscopic, fast initial dissolution rate of rocks.

  10. Changes in thickness and surface area of the human cortex and their relationship with intelligence.

    Science.gov (United States)

    Schnack, Hugo G; van Haren, Neeltje E M; Brouwer, Rachel M; Evans, Alan; Durston, Sarah; Boomsma, Dorret I; Kahn, René S; Hulshoff Pol, Hilleke E

    2015-06-01

    Changes in cortical thickness over time have been related to intelligence, but whether changes in cortical surface area are related to general cognitive functioning is unknown. We therefore examined the relationship between intelligence quotient (IQ) and changes in cortical thickness and surface over time in 504 healthy subjects. At 10 years of age, more intelligent children have a slightly thinner cortex than children with a lower IQ. This relationship becomes more pronounced with increasing age: with higher IQ, a faster thinning of the cortex is found over time. In the more intelligent young adults, this relationship reverses so that by the age of 42 a thicker cortex is associated with higher intelligence. In contrast, cortical surface is larger in more intelligent children at the age of 10. The cortical surface is still expanding, reaching its maximum area during adolescence. With higher IQ, cortical expansion is completed at a younger age; and once completed, surface area decreases at a higher rate. These findings suggest that intelligence may be more related to the magnitude and timing of changes in brain structure during development than to brain structure per se, and that the cortex is never completed but shows continuing intelligence-dependent development. © The Author 2014. Published by Oxford University Press. All rights reserved. For Permissions, please e-mail: journals.permissions@oup.com.

  11. Quality of surface-water supplies in the Triangle area of North Carolina, water year 2008

    Science.gov (United States)

    Giorgino, M.J.; Rasmussen, R.B.; Pfeifle, C.A.

    2012-01-01

    Surface-water supplies are important sources of drinking water for residents in the Triangle area of North Carolina, which is located within the upper Cape Fear and Neuse River Basins. Since 1988, the U.S. Geological Survey and a consortium of governments have tracked water-quality conditions and trends in several of the area's water-supply lakes and streams. This report summarizes data collected through this cooperative effort, known as the Triangle Area Water Supply Monitoring Project, during October 2007 through September 2008. Major findings for this period include:

  12. Minimal area surfaces dual to Wilson loops and the Mathieu equation

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Changyu; He, Yifei; Kruczenski, Martin [Department of Physics and Astronomy, Purdue University, 525 Northwestern Avenue, W. Lafayette, IN, 47907-2036 (United States)

    2016-08-11

    The AdS/CFT correspondence relates Wilson loops in N=4 SYM to minimal area surfaces in AdS{sub 5}×S{sup 5} space. Recently, a new approach to study minimal area surfaces in AdS{sub 3}⊂AdS{sub 5} was discussed based on a Schroedinger equation with a periodic potential determined by the Schwarzian derivative of the shape of the Wilson loop. Here we use the Mathieu equation, a standard example of a periodic potential, to obtain a class of Wilson loops such that the area of the dual minimal area surface can be computed analytically in terms of eigenvalues of such equation. As opposed to previous examples, these minimal surfaces have an umbilical point (where the principal curvatures are equal) and are invariant under λ-deformations. In various limits they reduce to the single and multiple wound circular Wilson loop and to the regular light-like polygons studied by Alday and Maldacena. In this last limit, the periodic potential becomes a series of deep wells each related to a light-like segment. Small corrections are described by a tight-binding approximation. In the circular limit they are well approximated by an expansion developed by A. Dekel. In the particular case of no umbilical points they reduce to a previous solution proposed by J. Toledo. The construction works both in Euclidean and Minkowski signature of AdS{sub 3}.

  13. Minimal area surfaces dual to Wilson loops and the Mathieu equation

    Science.gov (United States)

    Huang, Changyu; He, Yifei; Kruczenski, Martin

    2016-08-01

    The AdS/CFT correspondence relates Wilson loops in {N}=4 SYM to minimal area surfaces in AdS 5 × S 5 space. Recently, a new approach to study minimal area surfaces in AdS 3 ⊂ AdS 5 was discussed based on a Schroedinger equation with a periodic potential determined by the Schwarzian derivative of the shape of the Wilson loop. Here we use the Mathieu equation, a standard example of a periodic potential, to obtain a class of Wilson loops such that the area of the dual minimal area surface can be computed analytically in terms of eigenvalues of such equation. As opposed to previous examples, these minimal surfaces have an umbilical point (where the principal curvatures are equal) and are invariant under λ-deformations. In various limits they reduce to the single and multiple wound circular Wilson loop and to the regular light-like polygons studied by Alday and Maldacena. In this last limit, the periodic potential becomes a series of deep wells each related to a light-like segment. Small corrections are described by a tight-binding approximation. In the circular limit they are well approximated by an expansion developed by A. Dekel. In the particular case of no umbilical points they reduce to a previous solution proposed by J. Toledo. The construction works both in Euclidean and Minkowski signature of AdS 3.

  14. Lp-dual affine surface area forms of Busemann–Petty type problems

    Indian Academy of Sciences (India)

    (Math. Sci.) Vol. 125, No. 1, February 2015, pp. 71–77. c Indian Academy of Sciences. Lp-dual affine surface area forms of Busemann–Petty type problems ..... problem in three dimensions,. Ann. Math. 140(2) (1994) 435–447. [4] Gardner R J, Geometric tomography, 2nd edn (2006) (Cambridge, UK: Cambridge Univ. Press).

  15. Specific surface area behavior of a dissolving population of particles. Augmenting Mercer Dissolution Theory

    International Nuclear Information System (INIS)

    Scripsick, R.C.; Rothenberg, S.J.

    1986-01-01

    Specific surface area (Sp) measurements were made on two uranium oxide aerosol materials before and after in vitro dissolution s