WorldWideScience

Sample records for surface air mass

  1. Mineralization of bacterial cell mass on a photocatalytic surface in air

    International Nuclear Information System (INIS)

    Jacoby, W.A.; Maness, P.C.; Wolfrum, E.J.; Blake, D.M.; Fennell, J.A.

    1998-01-01

    Whole cells deposited on a titanium dioxide-coated surface have been oxidized in air to carbon dioxide via photocatalysis. This paper provides the first evidence that the organic matter in whole cells can be completely oxidized. Three experimental techniques were employed to monitor this reaction: scanning electron microscopy, 14 C radioisotope labeling experiments establish that the carbon content of E. coli is oxidized to form carbon dioxide with substantial closure of the mass balance. The batch reactor experiments corroborate the mass balance and provide a preliminary indication of the rate of the oxidation reaction. These results provide evidence that a photocatalytic surface used for disinfection can also be self-cleaning in an air-solid system

  2. The influence of surface treatment on mass transfer between air and building material

    DEFF Research Database (Denmark)

    Kwiatkowski, Jerzy; Rode, Carsten; Hansen, Kurt Kielsgaard

    2008-01-01

    for the experiments: gypsum board and calcium silicate. The wallpaper and paint were used as finishing materials. Impact of the following parameters for changes of RH was studied: coating, temperature and air movement. The measurements showed that acryl paint (diffusion open) can significantly decrease mass uptake......The processes of mass transfer between air and building structure and in the material influence not only the conditions within the material but also inside the connected air spaces. The material which absorbs and desorbs water vapour can be used to moderate the amplitude of indoor relative humidity...... and therefore to participate in the improvement of the indoor air quality and energy saving. Many parameters influence water vapour exchange between indoor air and building material. The aim of this work is to present the change of mass transfer under different climatic and material conditions. The measurements...

  3. Ozone-surface interactions: Investigations of mechanisms, kinetics, mass transport, and implications for indoor air quality

    Energy Technology Data Exchange (ETDEWEB)

    Morrison, Glenn Charles [Univ. of California, Berkeley, CA (United States)

    1999-12-01

    -7, 10-5, and 10-5 respectively. To understand how internal surface area influences the equivalent reaction probability of whole carpet, a model of ozone diffusion into and reaction with internal carpet components was developed. This was then used to predict apparent reaction probabilities for carpet. He combines this with a modified model of turbulent mass transfer developed by Liu, et al. to predict deposition rates and indoor ozone concentrations. The model predicts that carpet should have an equivalent reaction probability of about 10-5, matching laboratory measurements of the reaction probability. For both carpet and duct materials, surfaces become progressively quenched (aging), losing the ability to react or otherwise take up ozone. He evaluated the functional form of aging and find that the reaction probability follows a power function with respect to the cumulative uptake of ozone. To understand ozone aging of surfaces, he developed several mathematical descriptions of aging based on two different mechanisms. The observed functional form of aging is mimicked by a model which describes ozone diffusion with internal reaction in a solid. He shows that the fleecy nature of carpet materials in combination with the model of ozone diffusion below a fiber surface and internal reaction may explain the functional form and the magnitude of power function parameters observed due to ozone interactions with carpet. The ozone induced aldehyde emissions, measured from duct materials, were combined with an indoor air quality model to show that concentrations of aldehydes indoors may approach odorous levels. He shows that ducts are unlikely to be a significant sink for ozone due to the low reaction probability in combination with the short residence time of air in ducts.

  4. Mass transfer behavior of tritium from air to water through the water surface

    International Nuclear Information System (INIS)

    Takata, Hiroki; Nishikawa, Masabumi; Kamimae, Kozo

    2005-01-01

    It is anticipated that a certain amount of tritiated water exists in the atmosphere of tritium handling facilities, and it is recognized that the hazardous potential of tritiated water is rather high. Then, it is important to grasp the behavior of tritiated water for preserving of the radiation safety. The mass transfer behavior of tritium from air to water through the water surface was discussed in this study. The evaporation rate of water and the condensation rate of water were experimentally examined from measurement of change of the weight of distilled water. The tritium transfer rate from the tritiated water in air to the distilled water was also experimentally examined by using a liquid scintillation counter. Experimental results about change of tritium level in a small beaker placed in the atmosphere with tritiated water showed that diffusion of tritium in water and gas flow in the atmosphere gives considerable effect on tritium transfer. The estimation method of the tritium transfer made in this study was applied to explain the data at The Japan Atomic Power Company second power station at Tsuruga and good agreement was obtained. (author)

  5. Simultaneous heat and mass transfer to air from a compact heat exchanger with water spray precooling and surface deluge cooling

    International Nuclear Information System (INIS)

    Zhang, Feini; Bock, Jessica; Jacobi, Anthony M.; Wu, Hailing

    2014-01-01

    Various methods are available to enhance heat exchanger performance with evaporative cooling. In this study, evaporative mist precooling, deluge cooling, and combined cooling schemes are examined experimentally and compared to model predictions. A flexible model of a compact, finned-tube heat exchanger with a wetted surface is developed by applying the governing conservation and rate equations and invoking the heat and mass transfer analogy. The model is applicable for dry, partially wet, or fully wet surface conditions and capable of predicting local heat/mass transfer, wetness condition, and pressure drop of the heat exchanger. Experimental data are obtained from wind tunnel experiments using a louver-fin flat-tube heat exchanger with single-phase tube-side flow. Total capacity, pressure drop, and water drainage behavior under various water usage rates and air face velocities are analyzed and compared to data for dry-surface conditions. A heat exchanger partitioning method for evaporative cooling is introduced to study partially wet surface conditions, as part of a consistent and general method for interpreting wet-surface performance data. The heat exchanger is partitioned into dry and wet portions by introducing a wet surface factor. For the wet part, the enthalpy potential method is used to determine the air-side sensible heat transfer coefficient. Thermal and hydraulic performance is compared to empirical correlations. Total capacity predictions from the model agree with the experimental results with an average deviation of 12.6%. The model is also exercised for four water augmentation schemes; results support operating under a combined mist precooling and deluge cooling scheme. -- Highlights: • A new spray-cooled heat exchanger model is presented and is validated with data. • Heat duty is shown to be asymptotic with spray flow rate. • Meaningful heat transfer coefficients for partially wet conditions are obtained. • Colburn j wet is lower than j dry

  6. Air and Surface Sampling Method for Assessing Exposures to Quaternary Ammonium Compounds Using Liquid Chromatography Tandem Mass Spectrometry.

    Science.gov (United States)

    LeBouf, Ryan F; Virji, Mohammed Abbas; Ranpara, Anand; Stefaniak, Aleksandr B

    2017-07-01

    This method was designed for sampling select quaternary ammonium (quat) compounds in air or on surfaces followed by analysis using ultraperformance liquid chromatography tandem mass spectrometry. Target quats were benzethonium chloride, didecyldimethylammonium bromide, benzyldimethyldodecylammonium chloride, benzyldimethyltetradecylammonium chloride, and benzyldimethylhexadecylammonium chloride. For air sampling, polytetrafluoroethylene (PTFE) filters are recommended for 15-min to 24-hour sampling. For surface sampling, Pro-wipe® 880 (PW) media was chosen. Samples were extracted in 60:40 acetonitrile:0.1% formic acid for 1 hour on an orbital shaker. Method detection limits range from 0.3 to 2 ng/ml depending on media and analyte. Matrix effects of media are minimized through the use of multiple reaction monitoring versus selected ion recording. Upper confidence limits on accuracy meet the National Institute for Occupational Safety and Health 25% criterion for PTFE and PW media for all analytes. Using PTFE and PW analyzed with multiple reaction monitoring, the method quantifies levels among the different quats compounds with high precision (detection limits to capture quats on air sampling filters with only a 15-min sample duration with a maximum assessed storage time of 103 days before sample extraction. This method will support future exposure assessment and quantitative epidemiologic studies to explore exposure-response relationships and establish levels of quats exposures associated with adverse health effects. © The Author 2017. Published by Oxford University Press on behalf of the British Occupational Hygiene Society.

  7. Brief Communication: Upper Air Relaxation in RACMO2 Significantly Improves Modelled Interannual Surface Mass Balance Variability in Antarctica

    Science.gov (United States)

    van de Berg, W. J.; Medley, B.

    2016-01-01

    The Regional Atmospheric Climate Model (RACMO2) has been a powerful tool for improving surface mass balance (SMB) estimates from GCMs or reanalyses. However, new yearly SMB observations for West Antarctica show that the modelled interannual variability in SMB is poorly simulated by RACMO2, in contrast to ERA-Interim, which resolves this variability well. In an attempt to remedy RACMO2 performance, we included additional upper-air relaxation (UAR) in RACMO2. With UAR, the correlation to observations is similar for RACMO2 and ERA-Interim. The spatial SMB patterns and ice-sheet-integrated SMB modelled using UAR remain very similar to the estimates of RACMO2 without UAR. We only observe an upstream smoothing of precipitation in regions with very steep topography like the Antarctic Peninsula. We conclude that UAR is a useful improvement for regional climate model simulations, although results in regions with steep topography should be treated with care.

  8. Real-time measurement of plutonium in air by direct-inlet surface ionization mass spectrometry. Status report

    International Nuclear Information System (INIS)

    Stoffels, J.J.

    1980-04-01

    A new technique is being developed for monitoring low-level airborne plutonium on a real-time basis. The technique is based on surface ionization mass spectrometry of airborne particles. It will be capable of measuring plutonium concentrations below the maximum permissible concentration (MPC) level. A complete mass spectrometer was designed and constructed for this purpose. Major components which were developed and made operational for the instrument include an efficient inlet for directly sampling particles in air, a wide dynamic range ion detector and a minicomputer-based ion-burst measurement system. Calibration of the direct-inlet mass spectrometer (DIMS) was initiated to establish the instrument's response to plutonium dioxide as a function of concentration and particle size. This work revealed an important problem - bouncing of particles upon impact with the ionizing filament. Particle bounce results in a significant loss of measurement sensitivity. The feasibility of using an oven ionizer to overcome the particle bounce problem has been demonstrated. A rhenium oven ionizer was designed and constructed for the purpose of trapping particles which enter via the direct inlet. High-speed particles were trapped in the oven yielding a measurement sensitivity comparable to that for particles which are preloaded. Development of the Pu DIMS can now be completed by optimizing the oven design and calibrating the instrument's performance with UO 2 and CeO 2 particles as analogs to PuO 2 particles

  9. Surface Flux Modeling for Air Quality Applications

    Directory of Open Access Journals (Sweden)

    Limei Ran

    2011-08-01

    Full Text Available For many gasses and aerosols, dry deposition is an important sink of atmospheric mass. Dry deposition fluxes are also important sources of pollutants to terrestrial and aquatic ecosystems. The surface fluxes of some gases, such as ammonia, mercury, and certain volatile organic compounds, can be upward into the air as well as downward to the surface and therefore should be modeled as bi-directional fluxes. Model parameterizations of dry deposition in air quality models have been represented by simple electrical resistance analogs for almost 30 years. Uncertainties in surface flux modeling in global to mesoscale models are being slowly reduced as more field measurements provide constraints on parameterizations. However, at the same time, more chemical species are being added to surface flux models as air quality models are expanded to include more complex chemistry and are being applied to a wider array of environmental issues. Since surface flux measurements of many of these chemicals are still lacking, resistances are usually parameterized using simple scaling by water or lipid solubility and reactivity. Advances in recent years have included bi-directional flux algorithms that require a shift from pre-computation of deposition velocities to fully integrated surface flux calculations within air quality models. Improved modeling of the stomatal component of chemical surface fluxes has resulted from improved evapotranspiration modeling in land surface models and closer integration between meteorology and air quality models. Satellite-derived land use characterization and vegetation products and indices are improving model representation of spatial and temporal variations in surface flux processes. This review describes the current state of chemical dry deposition modeling, recent progress in bi-directional flux modeling, synergistic model development research with field measurements, and coupling with meteorological land surface models.

  10. A Warming Surface but a Cooling Top of Atmosphere Associated with Warm, Moist Air Mass Advection over the Ice and Snow Covered Arctic

    Science.gov (United States)

    Sedlar, J.

    2015-12-01

    Atmospheric advection of heat and moisture from lower latitudes to the high-latitude Arctic is a critical component of Earth's energy cycle. Large-scale advective events have been shown to make up a significant portion of the moist static energy budget of the Arctic atmosphere, even though such events are typically infrequent. The transport of heat and moisture over surfaces covered by ice and snow results in dynamic changes to the boundary layer structure, stability and turbulence, as well as to diabatic processes such as cloud distribution, microphysics and subsequent radiative effects. Recent studies have identified advection into the Arctic as a key mechanism for modulating the melt and freeze of snow and sea ice, via modification to all-sky longwave radiation. This paper examines the radiative impact during summer of such Arctic advective events at the top of the atmosphere (TOA), considering also the important role they play for the surface energy budget. Using infrared sounder measurements from the AIRS satellite, the summer frequency of significantly stable and moist advective events from 2003-2014 are characterized; justification of AIRS profiles over the Arctic are made using radiosoundings during a 3-month transect (ACSE) across the Eastern Arctic basin. One such event was observed within the East Siberian Sea in August 2014 during ACSE, providing in situ verification on the robustness and capability of AIRS to monitor advective cases. Results will highlight the important surface warming aspect of stable, moist instrusions. However a paradox emerges as such events also result in a cooling at the TOA evident on monthly mean TOA radiation. Thus such events have a climatic importance over ice and snow covered surfaces across the Arctic. ERA-Interim reanalyses are examined to provide a longer term perspective on the frequency of such events as well as providing capability to estimate meridional fluxes of moist static energy.

  11. The Effective Mass of a Ball in the Air

    Science.gov (United States)

    Messer, J.; Pantaleone, J.

    2010-01-01

    The air surrounding a projectile affects the projectile's motion in three very different ways: the drag force, the buoyant force, and the added mass. The added mass is an increase in the projectile's inertia from the motion of the air around it. Here we experimentally measure the added mass of a spherical projectile in air. The results agree well…

  12. Tritiated water vapor in the surface air at Tokyo

    International Nuclear Information System (INIS)

    Inoue, Hisayuki; Katsuragi, Yukio; Shigehara, Koji

    1984-01-01

    Tritium concentration in water vapor in the air near the surface and in the precipitation at Tokyo was measured during the period from 9 August to 20 November in 1974. From August to the middle of October, tritium mixing ratios in the surface air had relatively higher values except those in air masses which were associated with a typhoon. The mixing ratios of tritium in the air decreased abruptly at the middle of October, which indicates the decrease of tritium influx from aloft. These data exhibit the salient feature that variations in tritium concentration in TR are linear to the reciprocal of the content of water vapor during each period. Tritium concentrations in vapor and rain water collected simultaneously show nearly equal values. One of the reasons for the good correlation of tritium concentration between falling drops and ambient air is considered to be the result of the rapid isotopic exchange. (author)

  13. Development and validation of a highly sensitive gas chromatographic-mass spectrometric screening method for the simultaneous determination of nanogram levels of fentanyl, sufentanil and alfentanil in air and surface contamination wipes.

    Science.gov (United States)

    Van Nimmen, Nadine F J; Veulemans, Hendrik A F

    2004-05-07

    A highly sensitive gas chromatographic-mass spectrometric (GC-MS) analytical method for the determination of the opioid narcotics fentanyl, alfentanil, and sufentanil in industrial hygiene personal air samples and surface contamination wipes was developed and comprehensively validated. Sample preparation involved a single step extraction of the samples with methanol, fortified with a fixed amount of the penta-deuterated analogues of the opioid narcotics as internal standard. The GC-MS analytical procedure using selected ion monitoring (SIM) was shown to be highly selective. Linearity was shown for levels of extracted wipe and air samples corresponding to at least 0.1-2 times their surface contamination limit (SCL) and accordingly to 0.1-2 times their time weighted average occupational exposure limit (OEL-TWA) based on a full shift 9601 air sample. Extraction recoveries were determined for spiked air samples and surface wipes and were found to be quantitative for both sampling media in the entire range studied. The air sampling method's limit of detection (LOD) was determined to be 0.4 ng per sample for fentanyl and sufentanil and 1.6 ng per sample for alfentanil, corresponding to less than 1% of their individual OEL for a full shift air sample (9601). The limit of quantification (LOQ) was found to be 1.4, 1.2, and 5.0 ng per filter for fentanyl, sufentanil, and alfentanil, respectively. The wipe sampling method had LODs of 4 ng per wipe for fentanyl and sufentanil and 16 ng per wipe for alfentanil and LOQs of respectively, 14, 12, and 50 ng per wipe. The analytical intra-assay precision of the air sampling and wipe sampling method, defined as the coefficient of variation on the analytical result of six replicate spiked media was below 10 and 5%, respectively, for all opioids at all spike levels. Accuracy expressed as relative error was determined to be below 10%, except for alfentanil at the lowest spike level (-13.1%). The stability of the opioids during simulated

  14. Clean Air Markets - Monitoring Surface Water Chemistry

    Science.gov (United States)

    Learn about how EPA uses Long Term Monitoring (LTM) and Temporily Integrated Monitoring of Ecosystems (TIME) to track the effect of the Clean Air Act Amendments on acidity of surface waters in the eastern U.S.

  15. Dynamic air layer on textured superhydrophobic surfaces

    KAUST Repository

    Vakarelski, Ivan Uriev

    2013-09-03

    We provide an experimental demonstration that a novel macroscopic, dynamic continuous air layer or plastron can be sustained indefinitely on textured superhydrophobic surfaces in air-supersaturated water by a natural gas influx mechanism. This type of plastron is an intermediate state between Leidenfrost vapor layers on superheated surfaces and the equilibrium Cassie-Baxter wetting state on textured superhydrophobic surfaces. We show that such a plastron can be sustained on the surface of a centimeter-sized superhydrophobic sphere immersed in heated water and variations of its dynamic behavior with air saturation of the water can be regulated by rapid changes of the water temperature. The simple experimental setup allows for quantification of the air flux into the plastron and identification of the air transport model of the plastron growth. Both the observed growth dynamics of such plastrons and millimeter-sized air bubbles seeded on the hydrophilic surface under identical air-supersaturated solution conditions are consistent with the predictions of a well-mixed gas transport model. © 2013 American Chemical Society.

  16. Radon-222 as an indicator of continental air masses and air mass boundaries over ocean areas

    International Nuclear Information System (INIS)

    Larson, R.E.; Bressan, D.J.

    1980-01-01

    Radon ( 222 Rn) has proven to be an excellent indicator of the continental nature of over-ocean air and air mass boundaries. Radon is almost exclusively of continental origin, and low-level real-time monitoring is possible with our improved radon measurement techniques. The transition from continental to maritime air in offshore and onshore winds is rather obvious and can easily be established near large islands or continents as an order-of-magnitude change in radon concentration from a few tens of picocuries per cubic meter or more to a few picocuries per cubic meter or less. Sharply changing radon concentrations are usually associated with frontal areas. Our data have offered insights into air movements, and hence transport of continental materials and pollutants over oceanic areas

  17. Comparison between polluted and clean air masses over Lake Michigan

    International Nuclear Information System (INIS)

    Alkezweeny, A.J.; Laulainen, N.S.

    1981-01-01

    Clean and polluted air masses, advected over Lake Michigan, were studied using instrumental aircraft during the summers of 1976 and 1978. The results show that regardless of the degree of pollution, the particle size distribution is bimodal. The concentrations of sulfate, nitrate and trace metals in a clean air mass are more than an order of magnitude lower than those in polluted air masses. Furthermore, these concentrations are comparable with those measured in remote areas of the world. In clean air the ratio of the total light scattering to Rayleigh scattering is very close to one, indicating very low concentrations of particulates in the optically active size classes

  18. Surface ionization mass spectrometry of opiates

    International Nuclear Information System (INIS)

    Usmanov, D.T.

    2009-07-01

    Key words: surface ionization, adsorption, heterogeneous reactions, surface ionization mass spectrometry, thermodesorption surface ionization spectroscopy, thermoemitter, opiates, extracts of biosamples. Subjects of study. The mass - spectrometric study of thermal - ion emission: surface ionization of opiates by on the surface of oxidized refractory metals. Purpose of work is to establish the regularities of surface ionization (SI) of multi-atomic molecule opiates and their mixtures develop the scientific base of SI methods for high sensitive and selective detection and analysis of these substances in the different objects, including biosamples. Methods of study: surface ionization mass spectrometry, thermodesorption surface ionization spectroscopy. The results obtained and their novelty. For the first time, SI of molecule opiates on the oxidized tungsten surface has been studied and their SI mass-spectra and temperature dependences of ion currents have been obtained, the characteristic heterogeneous reactions of an adsorbed molecules and the channels of monomolecular decays vibrationally-excited ions on their way in mass-spectrometry have been revealed, sublimation energy has been defined, the activation energy of E act , of these decays has been estimated for given period of time. Additivity of the SI mass-spectra of opiate mixtures of has been established under conditions of joint opiate adsorption. High selectivity of SI allows the extracts of biosamples to be analyzed without their preliminary chromatographic separation. The opiates are ionized by SI with high efficiency (from 34 C/mol to 112 C/mol), which provides high sensitivity of opiate detection by SI/MS and APTDSIS methods from - 10 -11 g in the samples under analysis. Practical value. The results of these studies create the scientific base for novel SI methods of high sensitive detection and analysis of the trace amounts of opiates in complicated mixtures, including biosamples without their preliminary

  19. A coupled surface/subsurface flow model accounting for air entrapment and air pressure counterflow

    DEFF Research Database (Denmark)

    Delfs, Jens Olaf; Wang, Wenqing; Kalbacher, Thomas

    2013-01-01

    wave) shallow flow and two-phase flow in a porous medium. The simultaneous mass transfer between the soil, overland, and atmosphere compartments is achieved by upgrading a fully established leakance concept for overland-soil liquid exchange to an air exchange flux between soil and atmosphere. In a new...... algorithm, leakances operate as a valve for gas pressure in a liquid-covered porous medium facilitating the simulation of air out-break events through the land surface. General criteria are stated to guarantee stability in a sequential iterative coupling algorithm and, in addition, for leakances to control...

  20. Surface Mass Balance Contributions to Acceleration of Antarctic Ice Mass Loss during 2003- 2013

    Science.gov (United States)

    Seo, K. W.; Wilson, C. R.; Scambos, T. A.; Kim, B. M.; Waliser, D. E.; Tian, B.; Kim, B.; Eom, J.

    2015-12-01

    Recent observations from satellite gravimetry (the GRACE mission) suggest an acceleration of ice mass loss from the Antarctic Ice Sheet (AIS). The contribution of surface mass balance changes (due to variable precipitation) is compared with GRACE-derived mass loss acceleration by assessing the estimated contribution of snow mass from meteorological reanalysis data. We find that over much of the continent, the acceleration can be explained by precipitation anomalies. However, on the Antarctic Peninsula and other parts of West Antarctica mass changes are not explained by precipitation and are likely associated with ice discharge rate increases. The total apparent GRACE acceleration over all of the AIS between 2003 and 2013 is -13.6±7.2 GTon/yr2. Of this total, we find that the surface mass balance component is -8.2±2.0 GTon/yr2. However, the GRACE estimate appears to contain errors arising from the atmospheric pressure fields used to remove air mass effects. The estimated acceleration error from this effect is about 9.8±5.8 GTon/yr2. Correcting for this yields an ice discharge acceleration of -15.1±6.5 GTon/yr2.

  1. Study on heat and mass transfer characteristics of humid air-flow in a fin bundle

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Dong-Hwi [Air-Conditioner Research Laboratory, LG Electronics, Seoul 153-082 (Korea); Koyama, Shigeru; Kuwahara, Ken [Department of Energy and Environmental Engineering, Kyushu University, Kasuga, Fukuoka 816-8580 (Japan); Kwon, Jeong-Tae [Department of Mechanical Engineering, Hoseo University, Asan, Chungnam 336-795 (Korea); Park, Byung-Duck [School of Mechanical and Automotive Engineering, Kyungpook National University, Sangju, Gyeongbuk 742-711 (Korea)

    2010-11-15

    This paper deals with the heat and mass transfer characteristics of humid air-flow under frosting conditions. A slit fin bundle was used for the simulation of fins of a heat exchanger. The effects of the cooling block temperature, air humidity and air velocity on the frosting characteristics were experimentally investigated. The frosted mass was affected considerably by the cooling block temperature and air humidity. However, the effect of air velocity on it was not so large. The pressure drop was affected remarkably by all experimental parameters in this study. Local heat flux distribution and frost thickness distribution on each fin were predicted from the measured fin temperatures and the mass and energy conservation equations on the frost surface and inside the frost layer. (author)

  2. Biphilic Surfaces for Enhanced Water Collection from Humid Air

    Science.gov (United States)

    Benkoski, Jason; Gerasopoulos, Konstantinos; Luedeman, William

    Surface wettability plays an important role in water recovery, distillation, dehumidification, and heat transfer. The efficiency of each process depends on the rate of droplet nucleation, droplet growth, and mass transfer. Unfortunately, hydrophilic surfaces are good at nucleation but poor at shedding. Hydrophobic surfaces are the reverse. Many plants and animals overcome this tradeoff through biphilic surfaces with patterned wettability. For example, the Stenocara beetle uses hydrophilic patches on a superhydrophobic background to collect fog from air. Cribellate spiders similarly collect fog on their webs through periodic spindle-knot structures. In this study, we investigate the effects of wettability patterns on the rate of water collection from humid air. The steady state rate of water collection per unit area is measured as a function of undercooling, angle of inclination, water contact angle, hydrophilic patch size, patch spacing, area fraction, and patch height relative to the hydrophobic background. We then model each pattern by comparing the potential and kinetic energy of a droplet as it rolls downwards at a fixed angle. The results indicate that the design rules for collecting fog differ from those for condensation from humid air. The authors gratefully acknowledge the Office of Naval Research for financial support through Grant Number N00014-15-1-2107.

  3. Isopleths of surface air concentration and surface air kerma rate due to a radioactive cloud released from a stack (3)

    International Nuclear Information System (INIS)

    Tachibana, Haruo; Kikuchi, Masamitsu; Sekita, Tsutomu; Yamaguchi, Takenori

    2004-06-01

    This report is a revised edition of 'Isopleths of Surface Air Concentration and Surface Air Absorbed Dose Rate due to a Radioactive Cloud Released from a Stack(II) '(JAERI-M 90-206) and based on the revised Nuclear Safety Guidelines reflected the ICRP1990 Recommendation. Characteristics of this report are the use of Air Karma Rate (Gy/h) instead of Air Absorbed Dose Rate (Gy/h), and the record of isopleths of surface air concentration and surface air karma rate on CD-ROM. These recorded data on CD-ROM can be printed out on paper and/or pasted on digital map by personal computer. (author)

  4. Particle desorption mass spectrometric surface characterization

    International Nuclear Information System (INIS)

    Summers, W.R.

    1986-01-01

    The feasibility of utilizing 252 Cf-Particle Desorption Mass Spectrometry (PDMS) to characterize the surface region of solid samples has been evaluated. The PDMS experiment was adapted to an ultrahigh vacuum (UHV) environment and was configured so as to allow the analysis of thick as well as thin samples. This apparatus included an in situ sputter cleaning/depth profiling facility. The mass resolution was variable from 300 to 200 at 133 daltons by changing the drift length from 27 cm to 20 cm. Desorbed ions were focused by using either a dual grid assembly or an einzel lens. The overall instrumental transmission efficiency with the einzel lens operative was approximately 50%. The applicability of 252 Cf-PDMS to samples that were thick and insulating was demonstrated in the analysis of geological specimens. Pollucite, Microcline, Amblygonite, and Lepidolite were analyzed without complications associated with sample thickness or charge accumulation. Substitution occurring between the alkali metals in the environment was observed by PDMS and was corroborated by SIMS, XPS, and EMP analyses. The analysis of NBM SRM glasses addressed the suitability of combining the PDMS technique was sputter etching. This application demonstrated the ability of this technique to sense changes in the chemical environment brought about by sputter cleaning. The analysis of these samples also allowed the estimation of detection limits for lithium, rubidium, and cesium in a glass matrix as 300 ppm, 400 ppm, and 400 ppm, respectively. Sputter depth profiling combined with 252 Cf-PDMS analysis of an aluminum layer on a silicon substrate established the utility of the PDMS technique in surface characterization

  5. Device for measuring mass of air. Einrichtung zur Luftmassenmessung

    Energy Technology Data Exchange (ETDEWEB)

    Sass, W

    1989-09-28

    In a device for measuring the mass of air, particularly for vehicles with internal combustion engines, with a measurement bridge, in one branch of which an air flow resistance, particularly a hot film sensor, which has air flowing round it, is connected in series with a measuring resistance and in another branch of which a compensation resistance measuring the air temperature is connected in series with a fixed resistor, where the bridge differential voltage is measured in the zero branch of the measuring bridge and the resulting signal is used to control a transistor valve situated in the bridge supply path of a bridge supply source with an emitter connected to the bridge via the transistor base for bridge compensation and where the voltage at the measurement resistance after bridge compensation is evaluated as a measure of the air flow, the invention proposes that the transistor valve should be made as an npn transistor blocking for negative voltage peaks in the bridge supply path. This ensures that for netgative voltage peaks in the supply line, the transistor valve closes temporarily and overheating of the measurement bridge is prevented. Such overheating would lead to measurement of too great air mass flow and therefore to a dangerously too rich fuel/air mixture, for example (instead the negative voltage peaks give a safe temporary lean mixture).

  6. Dynamic air layer on textured superhydrophobic surfaces

    KAUST Repository

    Vakarelski, Ivan Uriev; Chan, Derek Y C; Marston, Jeremy; Thoroddsen, Sigurdur T

    2013-01-01

    -sized superhydrophobic sphere immersed in heated water and variations of its dynamic behavior with air saturation of the water can be regulated by rapid changes of the water temperature. The simple experimental setup allows for quantification of the air flux

  7. climatology of air mass trajectories and aerosol optical thickness ...

    African Journals Online (AJOL)

    George

    We present in this paper a climatological study of back trajectories of air masses ... obtained by inversion of photometric measurements of AERONET network. ... the arid Sahel region adjacent in the north to the Sahara ... the city a strategic position in the study of the .... atmospheric emergencies, diagnostic case studies and.

  8. Dusty air masses transport between Amazon Basin and Caribbean Islands

    Science.gov (United States)

    Euphrasie-Clotilde, Lovely; Molinie, Jack; Prospero, Joseph; Feuillard, Tony; Brute, Francenor; Jeannot, Alexis

    2015-04-01

    Depend on the month, African desert dust affect different parts of the North Atlantic Ocean. From December to April, Saharan dust outbreaks are often reported over the amazon basin and from May to November over the Caribbean islands and the southern regions of USA. This annual oscillation of Saharan dust presence, related to the ITCZ position, is perturbed some time, during March. Indeed, over Guadeloupe, the air quality network observed between 2007 and 2012 several dust events during March. In this paper, using HISPLIT back trajectories, we analyzed air masses trajectories for March dust events observed in Guadeloupe, from 2007 to 2012.We observed that the high pressure positions over the Atlantic Ocean allow the transport of dusty air masses from southern region of West Africa to the Caribbean Sea with a path crossing close to coastal region of French Guyana. Complementary investigations including the relationship between PM10 concentrations recorded in two sites Pointe-a-Pitre in the Caribbean, and Cayenne in French Guyana, have been done. Moreover we focus on the mean delay observed between the times arrival. All the results show a link between pathway of dusty air masses present over amazon basin and over the Caribbean region during several event of March. The next step will be the comparison of mineral dust composition for this particular month.

  9. Evaporation rates and surface profiles on heterogeneous surfaces with mass transfer and surface reaction

    Energy Technology Data Exchange (ETDEWEB)

    Flytzani-Stephanopoulos, M; Schmidt, L D

    1979-01-01

    Simple models incorporating surface reaction and diffusion of volatile products through a boundary layer are developed to calculate effective rates of evaporation and local surface profiles on surfaces having active and inactive regions. The coupling between surface heterogeneities with respect to a particular reaction and external mass transfer may provide a mechanism for the surface rearrangement and metal loss encountered in several catalytic systems of practical interest. Calculated transport rates for the volatilization of platinum in oxidizing environments and the rearrangement of this metal during the ammonia oxidation reaction agree well with published experimental data.

  10. Concentration of 7Be in surface air at Suva, Fiji

    International Nuclear Information System (INIS)

    Garimella, S.; Koshy, K.

    1998-01-01

    A high-volume air sampler and a high-resolution gamma-ray spectrometer have been in use since August 1997 at the University of the South Pacific to measure the activity of 7 Be in surface air at Suva, the capital city of Fiji. Preliminary measurements during August - November 1997 indicate that the average concentration of 7 Be in surface air is approximately 4.0 mBq m -3 . Further measurements are in progress

  11. Total reflection x-ray fluorescence (TXRF) - a tool to obtain information about different air masses and air pollution

    International Nuclear Information System (INIS)

    Schmeling, M.

    2000-01-01

    Aerosols are solid particles dissolved in the atmosphere and have strong influence in the earth climate. Their solid surfaces are the only atmospheric medium for condensation of water leading to cloud formation and ultimately to precipitation. Besides their role in cloud formation, the elemental composition of aerosols reveals useful information about air masses and their transport patterns as well as air pollution. The elemental composition can be considered like a fingerprint of an air mass telling the story about its origin and fate. The presence of Al, Ti and Fe for instance indicates a source located in a highly exposed soil or often desert region, whereas Ni, V and Pb can be traced back to anthropogenic activities like fuel combustion or industrial processes. Other important source regions are the oceans, which emit the main aerosol constituents Na, Cl, and S. The concentrations of these elements in the atmosphere are extremely low and long sampling times are necessary to gain reliable results with most of the common analysis techniques. In contrast to this total reflection x-ray fluorescence (TXRF), as a technique capable to cope with tiny sample amounts, offers the unique possibility to reduce collection times to a minimum of minutes to hours. Such short sampling times in turn render it possible to monitor different air masses either passing through a ground based station or -in the ideal case- flown into by a small research aircraft. Different aerosol samples were taken by aircraft during the second aerosol characterization experiment (ACE-2) with sampling times ranging from 15 minutes up to one hour. These filter samples were analyzed by TXRF for trace elements subsequently. Together with background information about back trajectories and size distribution covering the time of sampling the presence of different air masses could be detected. In another project, short-term samples in the Chicago/Lake Michigan area are collected to study the air mass

  12. A directional passive air sampler for monitoring polycyclic aromatic hydrocarbons (PAHs) in air mass

    International Nuclear Information System (INIS)

    Tao, S.; Liu, Y.N.; Lang, C.; Wang, W.T.; Yuan, H.S.; Zhang, D.Y.; Qiu, W.X.; Liu, J.M.; Liu, Z.G.; Liu, S.Z.; Yi, R.; Ji, M.; Liu, X.X.

    2008-01-01

    A passive air sampler was developed for collecting polycyclic aromatic hydrocarbons (PAHs) in air mass from various directions. The airflow velocity within the sampler was assessed for its responses to ambient wind speed and direction. The sampler was examined for trapped particles, evaluated quantitatively for influence of airflow velocity and temperature on PAH uptake, examined for PAH uptake kinetics, calibrated against active sampling, and finally tested in the field. The airflow volume passing the sampler was linearly proportional to ambient wind speed and sensitive to wind direction. The uptake rate for an individual PAH was a function of airflow velocity, temperature and the octanol-air partitioning coefficient of the PAH. For all PAHs with more than two rings, the passive sampler operated in a linear uptake phase for three weeks. Different PAH concentrations were obtained in air masses from different directions in the field test. - A novel directional passive air sampler was developed and tested for monitoring PAHs in air masses from different directions

  13. Surface analysis by imaging mass spectrometry

    Czech Academy of Sciences Publication Activity Database

    Vidová, Veronika; Volný, Michael; Lemr, Karel; Havlíček, Vladimír

    2009-01-01

    Roč. 74, 7-8 (2009), s. 1101-1116 ISSN 0010-0765 Institutional research plan: CEZ:AV0Z50200510 Keywords : secondary ion mass spectrometry * matrix assisted laser desorption ionization * mass spectrometry Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 0.856, year: 2009

  14. Landscape seasons and air mass dynamics in Latvia

    International Nuclear Information System (INIS)

    Krauklis, A.; Draveniece, A.

    2004-01-01

    Latvia is located in the middle of an area where the boreal and nemoral zones and the regions of oceanic and continental climate meet, and it was studied as a model territory of the most typical variation of boreo-nemoral ecotone. The subject of this study was seasonal dynamics of the state of landscapes and diachronous links between seasons. It was found that landscapes undergo 12 seasonal states or seasons during the annual cycle of insulation and air mass occurrence. Each season may be distinguished by a definite amount of solar radiation, distinctive state of heat and water balance, phenological state of vegetation, and a distinctive occurrence of different air mass types and their particular 'association'. During each season these variables show a particular combination of numerical values and a distinctive landscape pattern

  15. Transport and transformation of surface water masses across the ...

    African Journals Online (AJOL)

    Transport and transformation of surface water masses across the Mascarene Plateau during the Northeast Monsoon season. ... Mixing occurs in the central gap between intermediate water masses (Red Sea Water [RSW] and Antarctic Intermediate Water [AAIW]) as well as in the upper waters (Subtropical Surface Water ...

  16. Radionuclides and trace metals in surface air. Appendix C

    International Nuclear Information System (INIS)

    Feely, H.W.; Toonkel, L.E.; Larsen, R.J.

    1981-01-01

    Since January 1963, the Environmental Measurements Laboratory (EML), formerly the Health and Safety Laboratory (HASL), has been conducting the Surface Air Sampling Program. This study is a direct outgrowth of a program initiated by the US Naval Research Laboratory (NRL) in 1957 and continued through 1962. The primary objective of this program is to study the spatial and temporal distribution of specific natural and man-made radioisotopes, and of trace metals in the surface air. Other special studies of surface air contamination have been performed during the course of the program

  17. Estimation of bare soil surface temperature from air temperature and ...

    African Journals Online (AJOL)

    Soil surface temperature has critical influence on climate, agricultural and hydrological activities since it serves as a good indicator of the energy budget of the earth's surface. Two empirical models for estimating soil surface temperature from air temperature and soil depth temperature were developed. The coefficient of ...

  18. Surface-MALDI mass spectrometry in biomaterials research

    DEFF Research Database (Denmark)

    Griesser, H.J.; Kingshott, P.; McArthur, S.L.

    2004-01-01

    Matrix-assisted laser desorption ionization mass spectrometry (MALDI-MS) has been used for over a decade for the determination of purity and accurate molecular masses of macromolecular analytes, such as proteins, in solution. In the last few years the technique has been adapted to become a new...... surfaces and detecting their molecular ions with high mass resolution and at levels much below monolayer coverage. Thus, Surface-MALDI-MS offers unique means of addressing biomaterial surface analysis needs, such as identification of the proteins and lipids that adsorb from multicomponent biological...... solutions in vitro and in vivo, the study of interactions between biomaterial surfaces and biomolecules, and identification of surface-enriched additives and contaminants. Surface-MALDI-MS is rapid, experimentally convenient, overcomes limitations in mass resolution and sensitivity of established...

  19. Fabrication of Hierarchically Micro- and Nano-structured Mold Surfaces Using Laser Ablation for Mass Production of Superhydrophobic Surfaces

    Science.gov (United States)

    Noh, Jiwhan; Lee, Jae-Hoon; Na, Suckjoo; Lim, Hyuneui; Jung, Dae-Hwan

    2010-10-01

    Many studies have examined the formation of surfaces with mixed patterns of micro- and nano-sized lotus leaves that have hydrophobic properties. In this study, micro- and nano-shapes such as lotus leaves were fabricated on a metal mold surface using laser ablation and ripple formation. A microstructure on the mold surface was replicated onto poly(dimethylsiloxane) (PDMS) using the polymer casting method to manufacture low-cost hydrophobic surfaces. A PDMS surface with micro- and nano-structures that were the inverse image of a lotus leaf showed hydrophobic characteristics (water contact angle: 157°). From these results, we deduced that portions of the microstructures were wet and that air gaps existed between the microstructures and the water drops. In this paper we suggest the possibility of the mass production of hydrophobic plastic surfaces and the development of a methodology for the hydrophobic texturing of various polymer surfaces, using the polymer casting method with laser-processed molds.

  20. Plutonium isotopes in the surface air in Japan

    International Nuclear Information System (INIS)

    Hirose, K.; Sugimura, Y.

    1990-01-01

    Plutonium isotope concentrations in the surface air at Tsukuba, Japan are reported during the period from 1981 to the end of 1986. The 239,240 Pu concentration in the surface air, which showed a marked seasonal variation with a spring maximum and fall minimum, decreased until the end of 1985 according to the stratospheric residence time of 1.15 years. In May 1986, elevated 239,240 Pu concentrations with high 238 Pu/ 239,240 Pu activity ratios were observed. The serial trend of plutonium concentration in the surface air is similar to the concentrations of the Chernobyl-released radionuclides. These findings suggest that a significant part of the plutonium in the surface air in May 1986 was due to the Chernobyl fallout. (author) 15 refs.; 2 figs.; 3 tabs

  1. Concentration of 7Be in surface air at Suva, Fiji

    International Nuclear Information System (INIS)

    Garimella, S.; Koshy, K.

    1998-01-01

    A high-volume air sampler and a high-resolution gamma-ray spectrometer have been in use since August 1997 at the University of the South Pacific to measure the activity of 7 Be in surface air at Suva, the capital city of Fiji. Preliminary measurements during August-November 1997 indicate that the average concentration of 7 Be in surface air is approximately 4.0 mBq m -3 . Further measurements are in progress. (author). 4 refs., 1 fig

  2. Hyperthermal surface ionization mass spectrometry of organic molecules: monoterpenes

    International Nuclear Information System (INIS)

    Kishi, Hiroshi; Fujii, Toshihiro.

    1997-01-01

    This paper describes an experimental study on the influence of kinetic energy of fast monoterpene molecules on the surface ionization efficiency and on the mass spectral patterns, using rhenium oxide (ReO 2 ) surface. Molecular kinetic energy, given to the molecules through the acceleration in the seeded supersonic molecular beam, ranged from 1 to 10 eV. Hyperthermal surface ionization mass spectra (HSIMS) were taken for various incident kinetic energies and surface temperatures. The observed mass spectra were interpreted in a purely empirical way, by means of evidence from the previous investigations, and they were compared with conventional EI techniques and with the thermal energy surface ionization technique (SIOMS; Surface Ionization Organic Mass Spectrometry). Ionization efficiency (β) was also studied. Under hyperthermal surface ionization (HSI) conditions, many kinds of fragment ions, including quite abundant odd electron ions (OE +· ) are observed. HSIMS patterns of monoterpenes are different among 6-isomers, contrary to those of SIOMS and EIMS, where very similar patterns for isomers are observed. HSIMS patterns are strongly dependent on the molecular kinetic energies. The surface temperature does not affect much the spectral patterns, but it controls the total amount of ion formation. We conclude from these mass spectral findings, HSI-mechanism contains an impulsive process of ion formation, followed by the fragmentation process as a results of the internal energies acquired through the collision processes. (author)

  3. Surface mass balance contributions to acceleration of Antarctic ice mass loss during 2003-2013

    OpenAIRE

    Seo, Ki-Weon; Wilson, Clark R.; Scambos, Ted; Kim, Baek-Min; Waliser, Duane E.; Tian, Baijun; Kim, Byeong-Hoon; Eom, Jooyoung

    2015-01-01

    Abstract Recent observations from satellite gravimetry (the Gravity Recovery and Climate Experiment (GRACE) mission) suggest an acceleration of ice mass loss from the Antarctic Ice Sheet (AIS). The contribution of surface mass balance changes (due to variable precipitation) is compared with GRACE?derived mass loss acceleration by assessing the estimated contribution of snow mass from meteorological reanalysis data. We find that over much of the continent, the acceleration can be explained by ...

  4. High surface area carbon for bifunctional air electrodes applied in zinc-air batteries

    Energy Technology Data Exchange (ETDEWEB)

    Arai, H [on leave from NTT Laboratories (Japan); Mueller, S; Haas, O [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1999-08-01

    Bifunctional air electrodes with high surface area carbon substrates showed low reduction overpotential, thus are promising for enhancing the energy efficiency and power capability of zinc-air batteries. The improved performance is attributed to lower overpotential due to diffusion of the reaction intermediate, namely the peroxide ion. (author) 1 fig., 2 refs.

  5. Aerosol concentration measurements and correlations with air mass trajectories at the Pierre Auger Observatory

    Science.gov (United States)

    Micheletti, M. I.; Louedec, K.; Freire, M.; Vitale, P.; Piacentini, R. D.

    2017-06-01

    Aerosols play an important role in radiative transfer processes involved in different fields of study. In particular, their influence is crucial in the attenuation of light at astronomical and astrophysical observatories, and has to be taken into account in light transfer models employed to reconstruct the signals. The Andean Argentinean region is increasingly being considered as a good candidate to host such facilities, as well as the ones for solar-energy resources, and an adequate knowledge of aerosols characteristics there is needed, but it is not always possible due to the vast area involved and the scarce atmospheric data at ground. The aim of this work is to find correlations between aerosol data and particle trajectories that can give an insight into the origin and behaviour of aerosols in this zone and can be employed in situations in which one does not have local aerosol measurements. For this purpose, an aerosol spectrometer and dust monitor (Grimm 1.109) was installed at the Pierre Auger Observatory of ultra-high-energy cosmic rays, to record aerosol concentrations in different size intervals, at surface level. These measurements are analysed and correlated with air mass trajectories obtained from HYSPLIT (NOAA) model calculations. High aerosol concentrations are registered predominantly when air masses have travelled mostly over continental areas, mainly from the NE direction, while low aerosol concentrations are found in correspondence with air masses coming from the Pacific Ocean, from the NW direction. Different size distribution patterns were found for the aerosols depending on their origin: marine or continental. This work shows for the first time the size distribution of aerosols registered at the Pierre Auger Observatory. The correlations found between mass and particle concentrations (total and for different size ranges) and HYSPLIT air mass trajectories, confirm that the latter can be employed as a useful tool to infer the sources, evolution

  6. Impact of indoor surface material on perceived air quality.

    Science.gov (United States)

    Senitkova, I

    2014-03-01

    The material combination impact on perceived indoor air quality for various surface interior materials is presented in this paper. The chemical analysis and sensory assessments identifies health adverse of indoor air pollutants (TVOCs). In this study, emissions and odors from different common indoor surface materials were investigated in glass test chamber under standardized conditions. Chemical measurements (TVOC concentration) and sensory assessments (odor intensity, air acceptability) were done after building materials exposure to standardized conditions. The results of the chemical and sensory assessment of individual materials and their combinations are compared and discussed within the paper. The using possibility of individual material surface sorption ability was investigated. The knowledge of targeted sorption effects can be used in the interior design phase. The results demonstrate the various sorption abilities of various indoor materials as well as the various sorption abilities of the same indoor material in various combinations. Copyright © 2013 Elsevier B.V. All rights reserved.

  7. Study of mass transfer at the air-water interface by an isotopic method

    International Nuclear Information System (INIS)

    Merlivat, L.

    1975-01-01

    It is shown by analysing the hydrogen and oxygen stable isotopes distribution in liquid and water vapor, that the processes taking place on a very small scale near the liquid can be investigated. The effect of molecular mass transfer is directly obtained without having to perform difficult measurements in the air in the immediate vicinity of the water surface. Experiments are carried out in the air-water tunnel especially designed for the simulation of ocean atmosphere energy exchanges. The wind velocities vary from 0.7 to 7m/sec. The experimental results obtained do not support the classical Reynolds' analogy between momentum and mass transfer down to the interface and the theory proposed by Sheppard, but they are in agreement with Sverdrup's, Kitaigorodskiy and Volkov's and Brutsaert's theories, all of which involve a layer just above the air-water interface through which mass transfer is dominated by molecular diffusion. The thickness of this layer in the two first theories is shown to decrease with increasing wind velocity. Direct application of Brutsaert's theory for roughness Reynolds numbers smaller than one is in good agreement with the experimental data obtained [fr

  8. EML Surface Air Sampling Program, 1990--1993 data

    Energy Technology Data Exchange (ETDEWEB)

    Larsen, R.J.; Sanderson, C.G.; Kada, J.

    1995-11-01

    Measurements of the concentrations of specific atmospheric radionuclides in air filter samples collected for the Environmental Measurements Laboratory`s Surface Air Sampling Program (SASP) during 1990--1993, with the exception of April 1993, indicate that anthropogenic radionuclides, in both hemispheres, were at or below the lower limits of detection for the sampling and analytical techniques that were used to collect and measure them. The occasional detection of {sup 137}Cs in some air filter samples may have resulted from resuspension of previously deposited debris. Following the April 6, 1993 accident and release of radionuclides into the atmosphere at a reprocessing plant in the Tomsk-7 military nuclear complex located 16 km north of the Siberian city of Tomsk, Russia, weekly air filter samples from Barrow, Alaska; Thule, Greenland and Moosonee, Canada were selected for special analyses. The naturally occurring radioisotopes that the authors measure, {sup 7}Be and {sup 210}Pb, continue to be detected in most air filter samples. Variations in the annual mean concentrations of {sup 7}Be at many of the sites appear to result primarily from changes in the atmospheric production rate of this cosmogenic radionuclide. Short-term variations in the concentrations of {sup 7}Be and {sup 210}Pb continued to be observed at many sites at which weekly air filter samples were analyzed. The monthly gross gamma-ray activity and the monthly mean surface air concentrations of {sup 7}Be, {sup 95}Zr, {sup 137}Cs, {sup 144}Ce, and {sup 210}Pb measured at sampling sites in SASP during 1990--1993 are presented. The weekly mean surface air concentrations of {sup 7}Be, {sup 95}Zr, {sup 137}Cs, {sup 144}Ce, and {sup 210}Pb for samples collected during 1990--1993 are given for 17 sites.

  9. EML Surface Air Sampling Program, 1990--1993 data

    International Nuclear Information System (INIS)

    Larsen, R.J.; Sanderson, C.G.; Kada, J.

    1995-11-01

    Measurements of the concentrations of specific atmospheric radionuclides in air filter samples collected for the Environmental Measurements Laboratory's Surface Air Sampling Program (SASP) during 1990--1993, with the exception of April 1993, indicate that anthropogenic radionuclides, in both hemispheres, were at or below the lower limits of detection for the sampling and analytical techniques that were used to collect and measure them. The occasional detection of 137 Cs in some air filter samples may have resulted from resuspension of previously deposited debris. Following the April 6, 1993 accident and release of radionuclides into the atmosphere at a reprocessing plant in the Tomsk-7 military nuclear complex located 16 km north of the Siberian city of Tomsk, Russia, weekly air filter samples from Barrow, Alaska; Thule, Greenland and Moosonee, Canada were selected for special analyses. The naturally occurring radioisotopes that the authors measure, 7 Be and 210 Pb, continue to be detected in most air filter samples. Variations in the annual mean concentrations of 7 Be at many of the sites appear to result primarily from changes in the atmospheric production rate of this cosmogenic radionuclide. Short-term variations in the concentrations of 7 Be and 210 Pb continued to be observed at many sites at which weekly air filter samples were analyzed. The monthly gross gamma-ray activity and the monthly mean surface air concentrations of 7 Be, 95 Zr, 137 Cs, 144 Ce, and 210 Pb measured at sampling sites in SASP during 1990--1993 are presented. The weekly mean surface air concentrations of 7 Be, 95 Zr, 137 Cs, 144 Ce, and 210 Pb for samples collected during 1990--1993 are given for 17 sites

  10. Probing Interfacial Processes on Graphene Surface by Mass Detection

    Science.gov (United States)

    Kakenov, Nurbek; Kocabas, Coskun

    2013-03-01

    In this work we studied the mass density of graphene, probed interfacial processes on graphene surface and examined the formation of graphene oxide by mass detection. The graphene layers were synthesized by chemical vapor deposition method on copper foils and transfer-printed on a quartz crystal microbalance (QCM). The mass density of single layer graphene was measured by investigating the mechanical resonance of the QCM. Moreover, we extended the developed technique to probe the binding dynamics of proteins on the surface of graphene, were able to obtain nonspecific binding constant of BSA protein of graphene surface in aqueous solution. The time trace of resonance signal showed that the BSA molecules rapidly saturated by filling the available binding sites on graphene surface. Furthermore, we monitored oxidation of graphene surface under oxygen plasma by tracing the changes of interfacial mass of the graphene controlled by the shifts in Raman spectra. Three regimes were observed the formation of graphene oxide which increases the interfacial mass, the release of carbon dioxide and the removal of small graphene/graphene oxide flakes. Scientific and Technological Research Council of Turkey (TUBITAK) grant no. 110T304, 109T209, Marie Curie International Reintegration Grant (IRG) grant no 256458, Turkish Academy of Science (TUBA-Gebip).

  11. Heat and mass transfer in air-fed pressurised suits

    International Nuclear Information System (INIS)

    Tesch, K.; Collins, M.W.; Karayiannis, T.G.; Atherton, M.A.; Edwards, P.

    2009-01-01

    Air-fed pressurised suits are used to protect workers against contamination and hazardous environments. The specific application here is the necessity for regular clean-up maintenance within the torus chamber of fusion reactors. The current design of suiting has been developed empirically. It is, therefore, very desirable to formulate a thermo-fluids model, which will be able to define optimum designs and operating parameters. Two factors indicate that the modelling should be as comprehensive as possible. Firstly, the overall thermo-fluids problem is three-dimensional and includes mass as well as heat transfer. The fluid field is complex, bounded on one side by the human body and on the other by what may be distensible, porous and multi-layer clothing. In this paper, we report firstly the modelling necessary for the additional mass and heat transport processes. This involves the use of Fick's and Fourier's laws and conjugate heat transfer. The results of an initial validation study are presented. Temperatures at the outlet of the suits were obtained experimentally and compared with those predicted by the overall CFD model. Realistic three-dimensional geometries were used for the suit and human body. Calculations were for turbulent flow with single- and two-component (species) models

  12. Symmetric scaling properties in global surface air temperature anomalies

    Science.gov (United States)

    Varotsos, Costas A.; Efstathiou, Maria N.

    2015-08-01

    We have recently suggested "long-term memory" or internal long-range correlation within the time-series of land-surface air temperature (LSAT) anomalies in both hemispheres. For example, an increasing trend in the LSAT anomalies is followed by another one at a different time in a power-law fashion. However, our previous research was mainly focused on the overall long-term persistence, while in the present study, the upward and downward scaling dynamics of the LSAT anomalies are analysed, separately. Our results show that no significant fluctuation differences were found between the increments and decrements in LSAT anomalies, over the whole Earth and over each hemisphere, individually. On the contrary, the combination of land-surface air and sea-surface water temperature anomalies seemed to cause a departure from symmetry and the increments in the land and sea surface temperature anomalies appear to be more persistent than the decrements.

  13. Climate Prediction Center (CPC) Global Land Surface Air Temperature Analysis

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A station observation-based global land monthly mean surface air temperature dataset at 0.5 0.5 latitude-longitude resolution for the period from 1948 to the present...

  14. Climate Prediction Center (CPC) Global Land Surface Air Temperature Analysis

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A station observation-based global land monthly mean surface air temperature dataset at 0.5 x 0.5 latitude-longitude resolution for the period from 1948 to the...

  15. Interrelationships Between Walkability, Air Pollution, Greenness, and Body Mass Index.

    Science.gov (United States)

    James, Peter; Kioumourtzoglou, Marianthi-Anna; Hart, Jaime E; Banay, Rachel F; Kloog, Itai; Laden, Francine

    2017-11-01

    Recent studies have linked urban environmental factors and body mass index (BMI); however, such factors are often examined in isolation, ignoring correlations across exposures. Using data on Nurses' Health Study participants living in the Northeastern United States in 2006, we estimated associations between neighborhood walkability (a composite of population density, street connectivity, and business access), greenness (from satellite imagery), and ambient air pollution (from satellite-based spatiotemporally resolved PM2.5 predictions and weighted monthly average concentrations of NO2 from up to five nearest monitors) and self-reported BMI using generalized additive models, allowing for deviations from linearity using penalized splines. Among 23,435 women aged 60-87 years, we observed nonlinear associations between walkability and BMI and between PM2.5 and BMI in single-exposure models adjusted for age, race, and individual- and area-level socioeconomic status. When modeling all exposures simultaneously, only the association between walkability and BMI remained nonlinear and nonmonotonic. Increasing walkability was associated with increasing BMI at lower levels of walkability (walkability index walkability was linked to lower BMI in areas of higher walkability (walkability index >1.8). A 10 percentile increase in walkability, right above 1.8 was associated with a 0.84% decrease in log BMI. The relationship between walkability and BMI existed only among younger participants (walkability was nonlinearly linked to lower BMI independent of air pollution and greenness. Our findings highlight the importance of accounting for nonlinear confounding by interrelated urban environmental factors when investigating associations between the environment and BMI.

  16. Time lag between the tropopause height and the levels of 7Be concentration in near surface air

    Science.gov (United States)

    Ioannidou, A.; Vasileiadis, A.; Melas, D.

    2012-04-01

    The concentration of 7Be at near surface air has been determined over 2009, a year of a deep solar minimum, in the region of Thessaloniki, Greece at 40°62' N, 22°95'E. In geomagnetic latitudes over 40° N, the elevation of the tropopause during the warm summer months and the vertical exchange of air masses within the troposphere cause greater mixture of the air masses resulting in higher concentration levels for 7Be in surface air. The positive correlation between the monthly activity concentration of 7Be and the tropopause height (0.94, p rate of vertical transport within the troposphere, especially during warmer summer months, has as a result the descent to surface of air masses enriched in 7Be. However, the 7Be concentration levels in near surface air are not expected to respond immediately to the change of elevation of the tropopause. It was found that there's a time lag of ~ 3 days between the change in the daily surface concentrations of 7Be the change in the elevation of the tropopause.

  17. Time lag between the tropopause height and the levels of 7Be concentration in near surface air

    Directory of Open Access Journals (Sweden)

    Melas D.

    2012-04-01

    Full Text Available The concentration of 7Be at near surface air has been determined over 2009, a year of a deep solar minimum, in the region of Thessaloniki, Greece at 40°62′ N, 22°95'E. In geomagnetic latitudes over 40° N, the elevation of the tropopause during the warm summer months and the vertical exchange of air masses within the troposphere cause greater mixture of the air masses resulting in higher concentration levels for 7Be in surface air. The positive correlation between the monthly activity concentration of 7Be and the tropopause height (0.94, p < 0.0001, and also between 7Be concentration and the temperature T (°C (R = 0.97, p < 0.001, confirm that the increased rate of vertical transport within the troposphere, especially during warmer summer months, has as a result the descent to surface of air masses enriched in 7Be. However, the 7Be concentration levels in near surface air are not expected to respond immediately to the change of elevation of the tropopause. It was found that there's a time lag of ~ 3 days between the change in the daily surface concentrations of 7Be the change in the elevation of the tropopause.

  18. Microbial air quality in mass transport buses and work-related illness among bus drivers of Bangkok Mass Transit Authority.

    Science.gov (United States)

    Luksamijarulkul, Pipat; Sundhiyodhin, Viboonsri; Luksamijarulkul, Soavalug; Kaewboonchoo, Orawan

    2004-06-01

    The air quality in mass transport buses, especially air-conditioned buses may affect bus drivers who work full time. Bus numbers 16, 63, 67 and 166 of the Seventh Bus Zone of Bangkok Mass Transit Authority were randomly selected to investigate for microbial air quality. Nine air-conditioned buses and 2-4 open-air buses for each number of the bus (36 air-conditioned buses and 12 open-air buses) were included. Five points of in-bus air samples in each studied bus were collected by using the Millipore A ir Tester Totally, 180 and 60 air samples collected from air-conditioned buses and open-air buses were cultured for bacterial and fungal counts. The bus drivers who drove the studied buses were interviewed towards histories of work-related illness while working. The results revealed that the mean +/- SD of bacterial counts in the studied open-air buses ranged from 358.50 +/- 146.66 CFU/m3 to 506 +/- 137.62 CFU/m3; bus number 16 had the highest level. As well as the mean +/- SD of fungal counts which ranged from 93.33 +/- 44.83 CFU/m3 to 302 +/- 294.65 CFU/m3; bus number 166 had the highest level. Whereas, the mean +/- SD of bacterial counts in the studied air-conditioned buses ranged from 115.24 +/- 136.01 CFU/m3 to 244.69 +/- 234.85 CFU/m3; bus numbers 16 and 67 had the highest level. As well as the mean +/- SD of fungal counts which rangedfrom 18.84 +/- 39.42 CFU/m3 to 96.13 +/- 234.76 CFU/m3; bus number 166 had the highest level. When 180 and 60 studied air samples were analyzed in detail, it was found that 33.33% of the air samples from open-air buses and 6.11% of air samples from air-conditioned buses had a high level of bacterial counts (> 500 CFU/m3) while 6.67% of air samples from open-air buses and 2.78% of air samples from air-conditioned buses had a high level of fungal counts (> 500 CFU/m3). Data from the history of work-related illnesses among the studied bus drivers showed that 91.67% of open-air bus drivers and 57.28% of air-conditioned bus drivers had

  19. Mass casualty tracking with air traffic control methodologies.

    Science.gov (United States)

    Hoskins, Jason D; Graham, Ross F; Robinson, Duane R; Lutz, Clifford C; Folio, Les R

    2009-06-01

    An intrahospital casualty throughput system modeled after air traffic control (ATC) tracking procedures was tested in mass casualty exercises. ATC uses a simple tactile process involving informational progress strips representing each aircraft, which are held in bays representing each stage of flight to prioritize and manage aircraft. These strips can be reordered within the bays to indicate a change in priority of aircraft sequence. In this study, a similar system was designed for patient tracking. We compared the ATC model and traditional casualty tracking methods of paper and clipboard in 18 four-hour casualty scenarios, each with 5 to 30 mock casualties. The experimental and control groups were alternated to maximize exposure and minimize training effects. Results were analyzed with Mann-Whitney statistical analysis with p value < 0.05 (two-sided). The ATC method had significantly (p = 0.017) fewer errors in critical patient data (eg, name, social security number, diagnosis). Specifically, the ATC method better tracked the mechanism of injury, working diagnosis, and disposition of patients. The ATC method also performed considerably better with patient accountability during mass casualty scenarios. Data strips were comparable with the control method in terms of ease of use. In addition, participants preferred the ATC method to the control (p = 0.003) and preferred using the ATC method (p = 0.003) to traditional methods in the future. The ATC model more effectively tracked patient data with fewer errors when compared with the clipboard method. Application of these principles can enhance trauma management and can have application in civilian and military trauma centers and emergency rooms.

  20. Quantification of air plasma chemistry for surface disinfection

    International Nuclear Information System (INIS)

    Pavlovich, Matthew J; Clark, Douglas S; Graves, David B

    2014-01-01

    Atmospheric-pressure air plasmas, created by a variety of discharges, are promising sources of reactive species for the emerging field of plasma biotechnology because of their convenience and ability to operate at ambient conditions. One biological application of ambient-air plasma is microbial disinfection, and the ability of air plasmas to decontaminate both solid surfaces and liquid volumes has been thoroughly established in the literature. However, the mechanism of disinfection and which reactive species most strongly correlate with antimicrobial effects are still not well understood. We describe quantitative gas-phase measurements of plasma chemistry via infrared spectroscopy in confined volumes, focusing on air plasma generated via surface micro-discharge (SMD). Previously, it has been shown that gaseous chemistry is highly sensitive to operating conditions, and the measurements we describe here extend those findings. We quantify the gaseous concentrations of ozone (O 3 ) and nitrogen oxides (NO and NO 2 , or NO x ) throughout the established ‘regimes’ for SMD air plasma chemistry: the low-power, ozone-dominated mode; the high-power, nitrogen oxides-dominated mode; and the intermediate, unstable transition region. The results presented here are in good agreement with previously published experimental studies of aqueous chemistry and parameterized models of gaseous chemistry. The principal finding of the present study is the correlation of bacterial inactivation on dry surfaces with gaseous chemistry across these time and power regimes. Bacterial decontamination is most effective in ‘NO x mode’ and less effective in ‘ozone mode’, with the weakest antibacterial effects in the transition region. Our results underscore the dynamic nature of air plasma chemistry and the importance of careful chemical characterization of plasma devices intended for biological applications. (paper)

  1. Quantification of air plasma chemistry for surface disinfection

    Science.gov (United States)

    Pavlovich, Matthew J.; Clark, Douglas S.; Graves, David B.

    2014-12-01

    Atmospheric-pressure air plasmas, created by a variety of discharges, are promising sources of reactive species for the emerging field of plasma biotechnology because of their convenience and ability to operate at ambient conditions. One biological application of ambient-air plasma is microbial disinfection, and the ability of air plasmas to decontaminate both solid surfaces and liquid volumes has been thoroughly established in the literature. However, the mechanism of disinfection and which reactive species most strongly correlate with antimicrobial effects are still not well understood. We describe quantitative gas-phase measurements of plasma chemistry via infrared spectroscopy in confined volumes, focusing on air plasma generated via surface micro-discharge (SMD). Previously, it has been shown that gaseous chemistry is highly sensitive to operating conditions, and the measurements we describe here extend those findings. We quantify the gaseous concentrations of ozone (O3) and nitrogen oxides (NO and NO2, or NOx) throughout the established ‘regimes’ for SMD air plasma chemistry: the low-power, ozone-dominated mode; the high-power, nitrogen oxides-dominated mode; and the intermediate, unstable transition region. The results presented here are in good agreement with previously published experimental studies of aqueous chemistry and parameterized models of gaseous chemistry. The principal finding of the present study is the correlation of bacterial inactivation on dry surfaces with gaseous chemistry across these time and power regimes. Bacterial decontamination is most effective in ‘NOx mode’ and less effective in ‘ozone mode’, with the weakest antibacterial effects in the transition region. Our results underscore the dynamic nature of air plasma chemistry and the importance of careful chemical characterization of plasma devices intended for biological applications.

  2. Surface Ionization and Soft Landing Techniques in Mass Spectrometry

    International Nuclear Information System (INIS)

    Futrell, Jean H.; Laskin, Julia

    2010-01-01

    The advent of soft ionization techniques, notably electrospray and laser desorption ionization methods, has extended mass spectrometric methods to large molecules and molecular complexes. This both greatly expands applications of mass spectrometry and makes the activation and dissociation of complex ions an integral part of large molecule mass spectrometry. A corollary of the much greater number of internal degrees of freedom and high density of states associated with molecular complexity is that internal energies much higher than the dissociation energies for competing fragmentation processes are required for observable fragmentation in time scales sampled by mass spectrometers. This article describes the kinetics of surface-induced dissociation (SID), a particularly efficient activation method for complex ions. Two very important characteristics of SID are very rapid, sub-picosecond activation and precise control of ion internal energy by varying ion collision energy. The nature of the surface plays an important role in SID, determining both efficiency and mechanism of ion activation. Surface composition and morphology strongly influence the relative importance of competing reactions of SID, ion capture (soft-landing), surface reaction and neutralization. The important features of SID and ion soft-landing are described briefly in this review and more fully in the recommended reading list.

  3. Performance characteristics of solar air heater with surface mounted obstacles

    International Nuclear Information System (INIS)

    Bekele, Adisu; Mishra, Manish; Dutta, Sushanta

    2014-01-01

    Highlights: • Solar air heater with delta shaped obstacles have been studied. • Obstacle angle of incidence strongly affects the thermo-hydraulic performance. • Thermal performance of obstacle mounted collectors is superior to smooth collectors. • Thermo-hydraulic performance of the present SAH is higher than those in previous studies. - Abstract: The performance of conventional solar air heaters (SAHs) can be improved by providing obstacles on the heated wall (i.e. on the absorber plate). Experiments have been performed to collect heat transfer and flow-friction data from an air heater duct with delta-shaped obstacles mounted on the absorber surface and having an aspect ratio 6:1 resembling the conditions close to the solar air heaters. This study encompassed for the range of Reynolds number (Re) from 2100 to 30,000, relative obstacle height (e/H) from 0.25 to 0.75, relative obstacle longitudinal pitch (P l /e) from 3/2 to 11/2, relative obstacle transverse pitch (P t /b) from 1 to 7/3 and the angle of incidence (α) varied from 30° to 90°. The thermo-hydraulic performance characteristics of SAH have been compared with the previous published works and the optimum range of the geometries have been explored for the better performance of such air-heaters compared to the other designs of solar air heaters

  4. Water vapor mass balance method for determining air infiltration rates in houses

    Science.gov (United States)

    David R. DeWalle; Gordon M. Heisler

    1980-01-01

    A water vapor mass balance technique that includes the use of common humidity-control equipment can be used to determine average air infiltration rates in buildings. Only measurements of the humidity inside and outside the home, the mass of vapor exchanged by a humidifier/dehumidifier, and the volume of interior air space are needed. This method gives results that...

  5. The fabrication of plastic cages for suspension in mass air flow racks.

    Science.gov (United States)

    Nielsen, F H; Bailey, B

    1979-08-01

    A cage for suspension in mass air flow racks was constructed of plastic and used to house rats. Little or no difficulty was encountered with the mass air flow rack-suspended cage system during the 4 years it was used for the study of trace elements.

  6. Responses of Surface Ozone Air Quality to Anthropogenic Nitrogen Deposition

    Science.gov (United States)

    Zhang, L.; Zhao, Y.; Tai, A. P. K.; Chen, Y.; Pan, Y.

    2017-12-01

    Human activities have substantially increased atmospheric deposition of reactive nitrogen to the Earth's surface, inducing unintentional effects on ecosystems with complex environmental and climate consequences. One consequence remaining unexplored is how surface air quality might respond to the enhanced nitrogen deposition through surface-atmosphere exchange. We combine a chemical transport model (GEOS-Chem) and a global land model (Community Land Model) to address this issue with a focus on ozone pollution in the Northern Hemisphere. We consider three processes that are important for surface ozone and can be perturbed by addition of atmospheric deposited nitrogen: emissions of biogenic volatile organic compounds (VOCs), ozone dry deposition, and soil nitrogen oxide (NOx) emissions. We find that present-day anthropogenic nitrogen deposition (65 Tg N a-1 to the land), through enhancing plant growth (represented as increases in vegetation leaf area index (LAI) in the model), could increase surface ozone from increased biogenic VOC emissions, but could also decrease ozone due to higher ozone dry deposition velocities. Meanwhile, deposited anthropogenic nitrogen to soil enhances soil NOx emissions. The overall effect on summer mean surface ozone concentrations show general increases over the globe (up to 1.5-2.3 ppbv over the western US and South Asia), except for some regions with high anthropogenic NOx emissions (0.5-1.0 ppbv decreases over the eastern US, Western Europe, and North China). We compare the surface ozone changes with those driven by the past 20-year climate and historical land use changes. We find that the impacts from anthropogenic nitrogen deposition can be comparable to the climate and land use driven surface ozone changes at regional scales, and partly offset the surface ozone reductions due to land use changes reported in previous studies. Our study emphasizes the complexity of biosphere-atmosphere interactions, which can have important

  7. Relating surface chemistry and oxygen surface exchange in LnBaCo2O(5+δ) air electrodes.

    Science.gov (United States)

    Téllez, Helena; Druce, John; Kilner, John A; Ishihara, Tatsumi

    2015-01-01

    The surface and near-surface chemical composition of electroceramic materials often shows significant deviations from that of the bulk. In particular, layered materials, such as cation-ordered LnBaCo2O(5+δ) perovskites (Ln = lanthanide), undergo surface and sub-surface restructuring due to the segregation of the divalent alkaline-earth cation. These processes can take place during synthesis and processing steps (e.g. deposition, sintering or annealing), as well as at temperatures relevant for the operation of these materials as air electrodes in solid oxide fuel cells and electrolysers. Furthermore, the surface segregation in these double perovskites shows fast kinetics, starting at temperatures as low as 400 °C over short periods of time and leading to a decrease in the transition metal surface coverage exposed to the gas phase. In this work, we use a combination of stable isotope tracer labeling and surface-sensitive ion beam techniques to study the oxygen transport properties and their relationship with the surface chemistry in ordered LnBaCo2O(5+δ) perovskites. Time-of-Flight Secondary-Ion Mass Spectrometry (ToF-SIMS) combined with (18)O isotope exchange was used to determine the oxygen tracer diffusion (D*) and surface exchange (k*) coefficients. Furthermore, Low Energy Ion Scattering (LEIS) was used for the analysis of the surface and near surface chemistry as it provides information from the first mono-atomic layer of the materials. In this way, we could relate the compositional modifications (e.g. cation segregation) taking place at the electrochemically-active surface during the exchange at high temperatures and the oxygen transport properties in double perovskite electrode materials to further our understanding of the mechanism of the surface exchange process.

  8. A Comparison of the Red Green Blue Air Mass Imagery and Hyperspectral Infrared Retrieved Profiles

    Science.gov (United States)

    Berndt, E. B.; Folmer, Michael; Dunion, Jason

    2014-01-01

    The Red Green Blue (RGB) Air Mass imagery is derived from multiple channels or paired channel differences. Multiple channel products typically provide additional information than a single channel can provide alone. The RGB Air Mass imagery simplifies the interpretation of temperature and moisture characteristics of air masses surrounding synoptic and mesoscale features. Despite the ease of interpretation of multiple channel products, the combination of channels and channel differences means the resulting product does not represent a quantity or physical parameter such as brightness temperature in conventional single channel satellite imagery. Without a specific quantity to reference, forecasters are often confused as to what RGB products represent. Hyperspectral infrared retrieved profiles of temperature, moisture, and ozone can provide insight about the air mass represented on the RGB Air Mass product and provide confidence in the product and representation of air masses despite the lack of a quantity to reference for interpretation. This study focuses on RGB Air Mass analysis of Hurricane Sandy as it moved north along the U.S. East Coast, while transitioning to a hybrid extratropical storm. Soundings and total column ozone retrievals were analyzed using data from the Cross-track Infrared and Advanced Technology Microwave Sounder Suite (CrIMSS) on the Suomi National Polar Orbiting Partnership satellite and the Atmospheric Infrared Sounder (AIRS) on the National Aeronautics and Space Administration Aqua satellite along with dropsondes that were collected from National Oceanic and Atmospheric Administration and Air Force research aircraft. By comparing these datasets to the RGB Air Mass, it is possible to capture quantitative information that could help in analyzing the synoptic environment enough to diagnose the onset of extratropical transition. This was done by identifying any stratospheric air intrusions (SAIs) that existed in the vicinity of Sandy as the wind

  9. Air Mass Origin in the Arctic and its Response to Future Warming

    Science.gov (United States)

    Orbe, Clara; Newman, Paul A.; Waugh, Darryn W.; Holzer, Mark; Oman, Luke; Polvani, Lorenzo M.; Li, Feng

    2014-01-01

    We present the first climatology of air mass origin in the Arctic in terms of rigorously defined air mass fractions that partition air according to where it last contacted the planetary boundary layer (PBL). Results from a present-day climate integration of the GEOSCCM general circulation model reveal that the Arctic lower troposphere below 700 mb is dominated year round by air whose last PBL contact occurred poleward of 60degN, (Arctic air, or air of Arctic origin). By comparison, approx. 63% of the Arctic troposphere above 700 mb originates in the NH midlatitude PBL, (midlatitude air). Although seasonal changes in the total fraction of midlatitude air are small, there are dramatic changes in where that air last contacted the PBL, especially above 700 mb. Specifically, during winter air in the Arctic originates preferentially over the oceans, approx. 26% in the East Pacific, and approx. 20% in the Atlantic PBL. By comparison, during summer air in the Arctic last contacted the midlatitude PBL primarily over land, overwhelmingly so in Asia (approx. 40 %) and, to a lesser extent, in North America (approx. 24%). Seasonal changes in air-mass origin are interpreted in terms of seasonal variations in the large-scale ventilation of the midlatitude boundary layer and lower troposphere, namely changes in the midlatitude tropospheric jet and associated transient eddies during winter and large scale convective motions over midlatitudes during summer.

  10. A study on the effects of system pressure on heat and mass transfer rates of an air cooler

    International Nuclear Information System (INIS)

    Jung, Hyung Ho

    2002-01-01

    In the present paper, the effects of inlet pressure on the heat and mass transfer rates of an air cooler are numerically predicted by a local analysis method. The pressures of the moist air vary from 2 to 4 bars. The psychometric properties such as dew point temperature, relative humidity and humidity ratio are employed to treat the condensing water vapor in the moist air when the surface temperatures are dropped below the dew point. The effects of the inlet pressures on the heat transfer rate, the dew point temperature, the rate of condensed water, the outlet temperature of air and cooling water are calculated. The condensation process of water vapor is discussed in detail. The results of present calculations are compared with the test data and shows good agreements

  11. Evaluation of entrance surface air kerma in pediatric chest radiography

    International Nuclear Information System (INIS)

    Porto, L.; Lunelli, N.; Paschuk, S.; Oliveira, A.; Ferreira, J.L.; Schelin, H.; Miguel, C.; Denyak, V.; Kmiecik, C.; Tilly, J.; Khoury, H.

    2014-01-01

    The objective of this study was to evaluate the entrance surface air kerma in pediatric chest radiography. An evaluation of 301 radiographical examinations in anterior–posterior (AP) and posterior–anterior (PA) (166 examinations) and lateral (LAT) (135 examinations) projections was performed. The analyses were performed on patients grouped by age; the groups included ages 0–1 y, 1–5 y, 5–10 y, and 10–15 y. The entrance surface air kerma was determined with DoseCal software (Radiological Protection Center of Saint George's Hospital, London) and thermoluminescent dosimeters. Two different exposure techniques were compared. The doses received by patients who had undergone LAT examinations were 40% higher, on average, those in AP/PA examinations because of the difference in tube voltage. A large high-dose “tail” was observed for children up to 5 y old. An increase in tube potential and corresponding decrease in current lead to a significant dose reduction. The difference between the average dose values for different age ranges was not practically observed, implying that the exposure techniques are still not optimal. Exposure doses received using the higher tube voltage and lower current-time product correspond to the international diagnostic reference levels. - Highlights: • The entrance surface air kerma of chest X-ray examinations in pediatric patients was estimated. • The data were analyzed for patients aged up to 15 y, stratified by age. • The doses of LAT examinations were 40% higher than of AP/PA because of kV used. • An increase in kV with a decrease in mAs leads to significant dose reduction

  12. Progress Toward a Global, EOS-Era Aerosol Air Mass Type Climatology

    Science.gov (United States)

    Kahn, Ralph A.

    2012-01-01

    The MISR and MODIS instruments aboard the NASA Earth Observing System's Terra Satellite have been collecting data containing information about the state of Earth's atmosphere and surface for over eleven years. Data from these instruments have been used to develop a global, monthly climatology of aerosol amount that is widely used as a constraint on climate models, including those used for the 2007 IPCC assessment report. The next frontier in assessing aerosol radiative forcing of climate is aerosol type, and in particular, the absorption properties of major aerosol air masses. This presentation will focus on the prospects for constraining aerosol type globally, and the steps we are taking to apply a combination of satellite and suborbital data to this challenge.

  13. Directional mass transport in an atmospheric pressure surface barrier discharge.

    Science.gov (United States)

    Dickenson, A; Morabit, Y; Hasan, M I; Walsh, J L

    2017-10-25

    In an atmospheric pressure surface barrier discharge the inherent physical separation between the plasma generation region and downstream point of application reduces the flux of reactive chemical species reaching the sample, potentially limiting application efficacy. This contribution explores the impact of manipulating the phase angle of the applied voltage to exert a level of control over the electrohydrodynamic forces generated by the plasma. As these forces produce a convective flow which is the primary mechanism of species transport, the technique facilitates the targeted delivery of reactive species to a downstream point without compromising the underpinning species generation mechanisms. Particle Imaging Velocimetry measurements are used to demonstrate that a phase shift between sinusoidal voltages applied to adjacent electrodes in a surface barrier discharge results in a significant deviation in the direction of the plasma induced gas flow. Using a two-dimensional numerical air plasma model, it is shown that the phase shift impacts the spatial distribution of the deposited charge on the dielectric surface between the adjacent electrodes. The modified surface charge distribution reduces the propagation length of the discharge ignited on the lagging electrode, causing an imbalance in the generated forces and consequently a variation in the direction of the resulting gas flow.

  14. Detection of high mass cluster ions sputtered from Bi surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Shepard, A; Hewitt, R W; Slusser, G J; Baitinger, W E; Cooks, R G; Winograd, N [Purdue Univ., Lafayette, Ind. (USA). Dept. of Chemistry; Delgass, W N [Purdue Univ., Lafayette, Ind. (USA); Varon, A; Devant, G [Societe RIBER, 92 - Rueil-Malmaison (France)

    1976-12-01

    The technique of secondary ion mass spectrometry (SIMS) has been employed to detect Bi/sup 3 +/ ions and associated oxides Bi/sub 3/Osub(x)sup(+)(x=1 to 4) from a Bi foil. Using a 3 keV Ar/sup +/ ion primary beam of 5x10/sup -7/ A/cm/sup 2/, mass resolution to nearly 700 with the requisite sensitivity has been achieved. The Bi surface was also monitored by X-ray photoelectron spectroscopy (XPS or ESCA). The presence of a weak O 1s peak at 532.7 eV and a strong SIMS Bi/sup 3 +/ peak is interpreted to mean that the oxygen is weakly incorporated into the Bi lattice without disrupting metal-metal bonds.

  15. Evolution of massive stars with mass loss: surface abundances

    International Nuclear Information System (INIS)

    Greggio, L.

    1984-01-01

    The location of theoretical stellar models in the upper part of the Hertzsprung-Russell diagram depends on a variety of poorly understood physical processes which may occur during the evolution of massive stars. The comparison between theoretical predictions and observations of the surface chemical composition of these objects can help in understanding their evolution and to set more stringent limits to the mentioned parameters. To this end, evolutionary sequences corresponding to 20, 40 and 60 solar masses have been computed up to core He exhaustion, following in detail the abundance variations of CNO, Ne and Mg isotopes. (Auth.)

  16. Evaluation of entrance surface air kerma in pediatric chest radiography

    Science.gov (United States)

    Porto, L.; Lunelli, N.; Paschuk, S.; Oliveira, A.; Ferreira, J. L.; Schelin, H.; Miguel, C.; Denyak, V.; Kmiecik, C.; Tilly, J.; Khoury, H.

    2014-11-01

    The objective of this study was to evaluate the entrance surface air kerma in pediatric chest radiography. An evaluation of 301 radiographical examinations in anterior-posterior (AP) and posterior-anterior (PA) (166 examinations) and lateral (LAT) (135 examinations) projections was performed. The analyses were performed on patients grouped by age; the groups included ages 0-1 y, 1-5 y, 5-10 y, and 10-15 y. The entrance surface air kerma was determined with DoseCal software (Radiological Protection Center of Saint George's Hospital, London) and thermoluminescent dosimeters. Two different exposure techniques were compared. The doses received by patients who had undergone LAT examinations were 40% higher, on average, those in AP/PA examinations because of the difference in tube voltage. A large high-dose “tail” was observed for children up to 5 y old. An increase in tube potential and corresponding decrease in current lead to a significant dose reduction. The difference between the average dose values for different age ranges was not practically observed, implying that the exposure techniques are still not optimal. Exposure doses received using the higher tube voltage and lower current-time product correspond to the international diagnostic reference levels.

  17. Investigation of ammonia air-surface exchange processes in a ...

    Science.gov (United States)

    Recent assessments of atmospheric deposition in North America note the increasing importance of reduced (NHx = NH3 + NH4+) forms of nitrogen (N) relative to oxidized forms. This shift in in the composition of inorganic nitrogen deposition has both ecological and policy implications. Deposition budgets developed from inferential models applied at the landscape scale, as well as regional and global chemical transport models, indicate that NH3 dry deposition contributes a significant portion of inorganic N deposition in many areas. However, the bidirectional NH3 flux algorithms employed in these models have not been extensively evaluated for North American conditions (e.g, atmospheric chemistry, meteorology, biogeochemistry). Further understanding of the processes controlling NH3 air-surface exchange in natural systems is critically needed. Based on preliminary results from the Southern Appalachian Nitrogen Deposition Study (SANDS), this presentation examines processes of NH3 air-surface exchange in a deciduous montane forest at the Coweeta Hydrologic Laboratory in western North Carolina. A combination of measurements and modeling are used to investigate net fluxes of NH3 above the forest and sources and sinks of NH3 within the canopy and forest floor. Measurements of biogeochemical NH4+ pools are used to characterize emission potential and NH3 compensation points of canopy foliage (i.e., green vegetation), leaf litter, and soil and their relation to NH3 fluxes

  18. Significant OH production under surface cleaning and air cleaning conditions: Impact on indoor air quality.

    Science.gov (United States)

    Carslaw, N; Fletcher, L; Heard, D; Ingham, T; Walker, H

    2017-11-01

    We report measurements of hydroxyl (OH) and hydroperoxy (HO 2 ) radicals made by laser-induced fluorescence spectroscopy in a computer classroom (i) in the absence of indoor activities (ii) during desk cleaning with a limonene-containing cleaner (iii) during operation of a commercially available "air cleaning" device. In the unmanipulated environment, the one-minute averaged OH concentration remained close to or below the limit of detection (6.5×10 5  molecule cm -3 ), whilst that of HO 2 was 1.3×10 7  molecule cm -3 . These concentrations increased to ~4×10 6 and 4×10 8  molecule cm -3 , respectively during desk cleaning. During operation of the air cleaning device, OH and HO 2 concentrations reached ~2×10 7 and ~6×10 8  molecule cm -3 respectively. The potential of these OH concentrations to initiate chemical processing is explored using a detailed chemical model for indoor air (the INDCM). The model can reproduce the measured OH and HO 2 concentrations to within 50% and often within a few % and demonstrates that the resulting secondary chemistry varies with the cleaning activity. Whilst terpene reaction products dominate the product composition following surface cleaning, those from aromatics and other VOCs are much more important during the use of the air cleaning device. © 2017 John Wiley & Sons A/S. Published by John Wiley & Sons Ltd.

  19. Surface-ionization field mass-spectrometry studies of nonequilibrium surface ionization

    International Nuclear Information System (INIS)

    Blashenkov, Nikolai M; Lavrent'ev, Gennadii Ya

    2007-01-01

    The ionization of polyatomic molecules on tungsten and tungsten oxide surfaces is considered for quasiequilibrium or essentially nonequilibrium conditions (in the latter case, the term nonequilibrium surface ionization is used for adsorbate ionization). Heterogeneous reactions are supposed to proceed through monomolecular decay of polyatomic molecules or fragments of multimolecular complexes. The nonequilibrium nature of these reactions is established. The dependences of the current density of disordered ions on the surface temperature, electric field strength, and ionized particle energy distribution are obtained in analytical form. Heterogeneous dissociation energies, the ionization potentials of radicals, and the magnitude of reaction departure from equilibrium are determined from experimental data, as are energy exchange times between reaction products and surfaces, the number of molecules in molecular complexes, and the number of effective degrees of freedom in molecules and complexes. In collecting the data a new technique relying on surface-ionization field mass-spectrometry was applied. (instruments and methods of investigation)

  20. Columnar aerosol optical and radiative properties according to season and air mass transport pattern over East Asia.

    Science.gov (United States)

    Noh, Young M; Müller, Detlef; Lee, Hanlim; Lee, Kwonho; Kim, Young Joon

    2012-08-01

    The column-integrated optical and radiative properties of aerosols in the downwind area of East Asia were investigated based on sun/sky radiometer measurements performed from February 2004 to June 2005 at Gwangju (35.23° N, 126.84° E) and Anmyeon (36.54° N, 126.33° E), Korea. The observed aerosol data were analyzed for differences among three seasons: spring (March-May), summer (June-August), and autumn/winter (September-February). The data were also categorized into five types depending on the air mass origin in arriving in the measurement sites: (a) from a northerly direction in spring (S(N)), (b) from a westerly direction in spring (S(W)), (c) cases with a low Ångström exponent (air mass origin. The forcing efficiency in summer was -131.7 and -125.6 W m(-2) at the surface in Gwangju and Anmyeon, respectively. These values are lower than those under the atmospheric conditions of spring and autumn/winter. The highest forcing efficiencies in autumn/winter were -214.3 and -255.9 W m(-2) at the surface in Gwangju and Anmyeon, respectively, when the air mass was transported from westerly directions.

  1. Surface acoustic wave nebulization facilitating lipid mass spectrometric analysis.

    Science.gov (United States)

    Yoon, Sung Hwan; Huang, Yue; Edgar, J Scott; Ting, Ying S; Heron, Scott R; Kao, Yuchieh; Li, Yanyan; Masselon, Christophe D; Ernst, Robert K; Goodlett, David R

    2012-08-07

    Surface acoustic wave nebulization (SAWN) is a novel method to transfer nonvolatile analytes directly from the aqueous phase to the gas phase for mass spectrometric analysis. The lower ion energetics of SAWN and its planar nature make it appealing for analytically challenging lipid samples. This challenge is a result of their amphipathic nature, labile nature, and tendency to form aggregates, which readily precipitate clogging capillaries used for electrospray ionization (ESI). Here, we report the use of SAWN to characterize the complex glycolipid, lipid A, which serves as the membrane anchor component of lipopolysaccharide (LPS) and has a pronounced tendency to clog nano-ESI capillaries. We also show that unlike ESI SAWN is capable of ionizing labile phospholipids without fragmentation. Lastly, we compare the ease of use of SAWN to the more conventional infusion-based ESI methods and demonstrate the ability to generate higher order tandem mass spectral data of lipid A for automated structure assignment using our previously reported hierarchical tandem mass spectrometry (HiTMS) algorithm. The ease of generating SAWN-MS(n) data combined with HiTMS interpretation offers the potential for high throughput lipid A structure analysis.

  2. Radial distributions of surface mass density and mass-to-luminosity ratio in spiral galaxies

    Science.gov (United States)

    Sofue, Yoshiaki

    2018-03-01

    We present radial profiles of the surface mass density (SMD) in spiral galaxies directly calculated using rotation curves of two approximations of flat-disk (SMD-F) and spherical mass distribution (SMD-S). The SMDs are combined with surface brightness using photometric data to derive radial variations of the mass-to-luminosity ratio (ML). It is found that the ML generally has a central peak or a plateau, and decreases to a local minimum at R ˜ 0.1-0.2 h, where R is the radius and h is the scale radius of optical disk. The ML, then, increases rapidly until ˜0.5 h, and is followed by gradual rise till ˜2 h, remaining at around ˜2 [M_{⊙} L^{-1}_{⊙}] in the w1 band (infrared λ3.4 μm) and ˜ 10 [M_⊙ L_⊙ ^{-1}] in the r band (λ6200-7500 Å). Beyond this radius, the ML increases steeply with approaching the observed edges at R ˜ 5 h, attaining to as high values as ˜20 in w1 and ˜ 10^2 [M_⊙ L_⊙ ^{-1}] in the r band, which are indicative of dominant dark matter. The general properties of the ML distributions will be useful for constraining cosmological formation models of spiral galaxies.

  3. Direct mass spectrometric screening of antibiotics from bacterial surfaces using liquid extraction surface analysis.

    Science.gov (United States)

    Kai, Marco; González, Ignacio; Genilloud, Olga; Singh, Sheo B; Svatoš, Aleš

    2012-10-30

    There is a need to find new antibiotic agents to fight resistant pathogenic bacteria. To search successfully for novel antibiotics from bacteria cultivated under diverse conditions, we need a fast and cost-effective screening method. A combination of Liquid Extraction Surface Analysis (LESA), automated chip-based nanoelectrospray ionization, and high-resolution mass or tandem mass spectrometry using an Orbitrap XL was tested as the screening platform. Actinobacteria, known to produce well-recognized thiazolyl peptide antibiotics, were cultivated on a plate of solid medium and the antibiotics were extracted by organic solvent mixtures from the surface of colonies grown on the plate and analyzed using mass spectrometry (MS). LESA combined with high-resolution MS is a powerful tool with which to extract and detect thiazolyl peptide antibiotics from different Actinobacteria. Known antibiotics were correctly detected with high mass accuracy (antibiotics in particular and natural products in general. The method described in this paper is suitable for (1) screening the natural products produced by bacterial colonies on cultivation plates within the first 2 min following extraction and (2) detecting antibiotics at high mass accuracy; the cost is around 2 Euro per sample. Copyright © 2012 John Wiley & Sons, Ltd.

  4. Properties of the surface snow in Princess Elizabeth Land, East Antarctica - climate and non-climate dependent variability of the surface mass balance and stable water isotopic composition

    Science.gov (United States)

    Vladimirova, D.; Ekaykin, A.; Lipenkov, V.; Popov, S. V.; Petit, J. R.; Masson-Delmotte, V.

    2017-12-01

    Glaciological and meteorological observations conducted during the past four decades in Princess Elizabeth Land, East Antarctica, are compiled. The database is used to investigate spatial patterns of surface snow isotopic composition and surface mass balance, including detailed information near subglacial lake Vostok. We show diverse relationships between snow isotopic composition and surface temperature. In the most inland part (elevation 3200-3400 m a.s.l.), surface snow isotopic composition varies independently from surface temperature, and is closely related to the distance to the open water source (with a slope of 0.98±0.17 ‰ per 100 km). Surface mass balance values are higher along the ice sheet slope, and relatively evenly distributed inland. The minimum values of snow isotopic composition and surface mass balance are identified in an area XX km southwestward from Vostok station. The spatial distribution of deuterium excess delineates regions influenced by the Indian Ocean and Pacific Ocean air masses, with Vostok area being situated close to their boundary. Anomalously high deuterium excess values are observed near Dome A, suggesting high kinetic fractionation for its moisture source, or specifically high post-deposition artifacts. The dataset is available for further studies such as the assessment of skills of general circulation or regional atmospheric models, and the search for the oldest ice.

  5. Calibration of nozzle for air mass flow measurement

    Science.gov (United States)

    Uher, Jan; Kanta, Lukáš

    2017-09-01

    The effort to make calibration measurement of mass flow through a nozzle was not satisfying. Traversing across the pipe radius with Pitot probe was done. The presence of overshoot behind the bend in the pipe was found. The overshoot led to an asymmetric velocity profile.

  6. Mass balance for lead in the California South Coast Air Basin: An update

    International Nuclear Information System (INIS)

    Lankey, R.L.; Davidson, C.I.; McMichael, F.C.

    1998-01-01

    A mass balance for lead for the year 1989 in the South Coast Air Basin has inputs to the atmosphere of 600 ± 190 kg/day and outputs of 580 ± 160 kg/day, showing rough agreement. Stationary sources are responsible for only about 5% of the total lead emissions. The bulk of the lead is emitted from vehicles using leaded gasoline (37%) and unleaded gasoline (15%), as well as from resuspension of previously deposited lead on roads (43%). Over half of the total emitted lead deposits on roads and nearby soil, while about one-third is carried out of the basin by wind. A small amount, less than 10%, is deposited on surfaces throughout the basin. These percentages are approximately the same as those in a mass balance for the same region calculated for 1972, when lead emissions from leaded gasoline were about a factor of 70 greater than leaded gas emissions in 1989. When the lead emissions re used as inputs o a simple continuously stirred flow reactor model for the basin, reasonable, agreement is obtained between calculated and measured concentrations

  7. On the Influence of Air Mass Origin on Low-Cloud Properties in the Southeast Atlantic

    Science.gov (United States)

    Fuchs, Julia; Cermak, Jan; Andersen, Hendrik; Hollmann, Rainer; Schwarz, Katharina

    2017-10-01

    This study investigates the impact of air mass origin and dynamics on cloud property changes in the Southeast Atlantic (SEA) during the biomass burning season. The understanding of clouds and their determinants at different scales is important for constraining the Earth's radiative budget and thus prominent in climate system research. In this study, the thermodynamically stable SEA stratocumulus cover is observed not only as the result of local environmental conditions but also as connected to large-scale meteorology by the often neglected but important role of spatial origins of air masses entering this region. In order to assess to what extent cloud properties are impacted by aerosol concentration, air mass history, and meteorology, a Hybrid Single-Particle Lagrangian Integrated Trajectory cluster analysis is conducted linking satellite observations of cloud properties (Spinning-Enhanced Visible and Infrared Imager), information on aerosol species (Monitoring Atmospheric Composition and Climate), and meteorological context (ERA-Interim reanalysis) to air mass clusters. It is found that a characteristic pattern of air mass origins connected to distinct synoptical conditions leads to marked cloud property changes in the southern part of the study area. Long-distance air masses are related to midlatitude weather disturbances that affect the cloud microphysics, especially in the southwestern subdomain of the study area. Changes in cloud effective radius are consistent with a boundary layer deepening and changes in lower tropospheric stability (LTS). In the southeastern subdomain cloud cover is controlled by a generally higher LTS, while air mass origin plays a minor role. This study leads to a better understanding of the dynamical drivers behind observed stratocumulus cloud properties in the SEA and frames potentially interesting conditions for aerosol-cloud interactions.

  8. Clean Air Act Guidelines and Standards for Solvent Use and Surface Coating Industry

    Science.gov (United States)

    This page contains the stationary sources of air pollution for the solvent use and surface coating industries, and their corresponding air pollution regulations. To learn more about the regulations for each industry, just click on the links below.

  9. Measuring air layer volumes retained by submerged floating-ferns Salvinia and biomimetic superhydrophobic surfaces

    Directory of Open Access Journals (Sweden)

    Matthias J. Mayser

    2014-06-01

    Full Text Available Some plants and animals feature superhydrophobic surfaces capable of retaining a layer of air when submerged under water. Long-term air retaining surfaces (Salvinia-effect are of high interest for biomimetic applications like drag reduction in ship coatings of up to 30%. Here we present a novel method for measuring air volumes and air loss under water. We recorded the buoyancy force of the air layer on leaf surfaces of four different Salvinia species and on one biomimetic surface using a highly sensitive custom made strain gauge force transducer setup. The volume of air held by a surface was quantified by comparing the buoyancy force of the specimen with and then without an air layer. Air volumes retained by the Salvinia-surfaces ranged between 0.15 and 1 L/m2 depending on differences in surface architecture. We verified the precision of the method by comparing the measured air volumes with theoretical volume calculations and could find a good agreement between both values. In this context we present techniques to calculate air volumes on surfaces with complex microstructures. The introduced method also allows to measure decrease or increase of air layers with high accuracy in real-time to understand dynamic processes.

  10. Air plasma processing of poly(methyl methacrylate) micro-beads: Surface characterisations

    International Nuclear Information System (INIS)

    Liu Chaozong; Cui Naiyi; Osbeck, Susan; Liang He

    2012-01-01

    Highlights: ► PMMA micro-beads were processed using a rotary air plasma reactor. ► Surface chemistry and surface texture of PMMA micro-beads were characterised. ► Surface wettability was evaluated using “floating” water contact angle method. ► Surface oxidation and texture changes induced by air plasma attributed to the improvement of surface wettability. - Abstract: This paper reports the surface processing of poly(methyl methacrylate) (PMMA) micro-beads by using a rotary air plasma reactor, and its effects on surface properties. The surface properties, including surface wettability, surface chemistry and textures of the PMMA beads, were characterised. It was observed that the air plasma processing can improve the surface wettability of the PMMA microbeads significantly. A 15 min plasma processing can reduce the surface water contact angle of PMMA beads to about 50° from its original value of 80.3°. This was accompanied by about 8% increase in surface oxygen concentration as confirmed by XPS analysis. The optical profilometry examination revealed the air plasma processing resulted in a rougher surface that has a “delicate” surface texture. It is concluded that the surface chemistry and texture, induced by air plasma processing, co-contributed to the surface wettability improvement of PMMA micro-beads.

  11. Air mass origins influencing TTL chemical composition over West Africa during 2006 summer monsoon

    Directory of Open Access Journals (Sweden)

    K. S. Law

    2010-11-01

    Full Text Available Trace gas and aerosol data collected in the tropical tropopause layer (TTL between 12–18.5 km by the M55 Geophysica aircraft as part of the SCOUT-AMMA campaign over West Africa during the summer monsoon in August 2006 have been analysed in terms of their air mass origins. Analysis of domain filling back trajectories arriving over West Africa, and in the specific region of the flights, showed that the M55 flights were generally representative of air masses arriving over West Africa during the first 2 weeks of August, 2006. Air originating from the mid-latitude lower stratosphere was under-sampled (in the mid-upper TTL whilst air masses uplifted from central Africa (into the lower TTL were over-sampled in the latter part of the campaign. Signatures of recent (previous 10 days origins were superimposed on the large-scale westward flow over West Africa. In the lower TTL, air masses were impacted by recent local deep convection over Africa at the level of main convective outflow (350 K, 200 hPa and on certain days up to 370 K (100 hPa. Estimates of the fraction of air masses influenced by local convection vary from 10 to 50% depending on the method applied and from day to day during the campaign. The analysis shows that flights on 7, 8 and 11 August were more influenced by local convection than on 4 and 13 August allowing separation of trace gas and aerosol measurements into "convective" and "non-convective" flights. Strong signatures, particularly in species with short lifetimes (relative to CO2 like CO, NO and fine-mode aerosols were seen during flights most influenced by convection up to 350–365 K. Observed profiles were also constantly perturbed by uplift (as high as 39% of air masses from the mid to lower troposphere over Asia, India, and oceanic regions resulting in import of clean oceanic (e.g. O3-poor or polluted air masses from Asia (high O3, CO, CO2 into West Africa. Thus, recent uplift of CO

  12. A 30-year record of surface mass balance (1966-95) and motion and surface altitude (1975-95) at Wolverine Glacier, Alaska

    Science.gov (United States)

    Mayo, Lawrence R.; Trabant, Dennis C.; March, Rod S.

    2004-01-01

    Scientific measurements at Wolverine Glacier, on the Kenai Peninsula in south-central Alaska, began in April 1966. At three long-term sites in the research basin, the measurements included snow depth, snow density, heights of the glacier surface and stratigraphic summer surfaces on stakes, and identification of the surface materials. Calculations of the mass balance of the surface strata-snow, new firn, superimposed ice, and old firn and ice mass at each site were based on these measurements. Calculations of fixed-date annual mass balances for each hydrologic year (October 1 to September 30), as well as net balances and the dates of minimum net balance measured between time-transgressive summer surfaces on the glacier, were made on the basis of the strata balances augmented by air temperature and precipitation recorded in the basin. From 1966 through 1995, the average annual balance at site A (590 meters altitude) was -4.06 meters water equivalent; at site B (1,070 meters altitude), was -0.90 meters water equivalent; and at site C (1,290 meters altitude), was +1.45 meters water equivalent. Geodetic determination of displacements of the mass balance stake, and glacier surface altitudes was added to the data set in 1975 to detect the glacier motion responses to variable climate and mass balance conditions. The average surface speed from 1975 to 1996 was 50.0 meters per year at site A, 83.7 meters per year at site B, and 37.2 meters per year at site C. The average surface altitudes were 594 meters at site A, 1,069 meters at site B, and 1,293 meters at site C; the glacier surface altitudes rose and fell over a range of 19.4 meters at site A, 14.1 meters at site B, and 13.2 meters at site C.

  13. Mass and chemically speciated size distribution of Prague aerosol using an aerosol dryer - The influence of air mass origin

    Czech Academy of Sciences Publication Activity Database

    Schwarz, Jaroslav; Štefancová, Lucia; Maenhaut, W.; Smolík, Jiří; Ždímal, Vladimír

    2012-01-01

    Roč. 437, OCT 15 (2012), s. 348-362 ISSN 0048-9697 R&D Projects: GA ČR GA205/09/2055; GA ČR GAP209/11/1342; GA MŠk ME 941 Grant - others:SRF GU(BE) 01S01306 Institutional support: RVO:67985858 Keywords : atmospheric aerosols * mass size distribution * chemical composition Subject RIV: DI - Air Pollution ; Quality Impact factor: 3.258, year: 2012

  14. Influence of the relative optical air mass on ultraviolet erythemal irradiance

    Science.gov (United States)

    Antón, M.; Serrano, A.; Cancillo, M. L.; García, J. A.

    2009-12-01

    The main objective of this article is to analyze the relationship between the transmissivity for ultraviolet erythemal irradiance (UVER) and the relative optical air mass at Badajoz (Southwestern Spain). Thus, a power expression between both variables is developed, which analyses in detail how atmospheric transmission is influenced by the total ozone column (TOC) and the atmospheric clearness. The period of analysis extends from 2001 to 2005. The experimental results indicate that clearness conditions play an important role in the relationship between UVER transmissivity and the relative optical air mass, while the effect of TOC is much smaller for this data set. In addition, the results show that UVER transmissivity is more sensitive to changes in atmospheric clearness than to TOC variability. Changes in TOC values higher than 15% cause UVER trasnmissivity to vary between 14% and 22%, while changes between cloud-free and overcast conditions produce variations in UVER transmissivity between 68% and 74% depending on the relative optical air mass.

  15. Surface, Water, and Air Biocharacterization (SWAB) Flight Experiment

    Science.gov (United States)

    Castro, V. A.; Ott, C. M.; Pierson, D. L.

    2012-01-01

    The determination of risk from infectious disease during spaceflight missions is composed of several factors including both the concentration and characteristics of the microorganisms to which the crew are exposed. Thus, having a good understanding of the microbial ecology aboard spacecraft provides the necessary information to mitigate health risks to the crew. While preventive measures are taken to minimize the presence of pathogens on spacecraft, medically significant organisms have been isolated from both the Mir and International Space Station (ISS). Historically, the method for isolation and identification of microorganisms from spacecraft environmental samples depended upon their growth on culture media. Unfortunately, only a fraction of the organisms may grow on a specific culture medium, potentially omitting those microorganisms whose nutritional and physical requirements for growth are not met. To address this bias in our understanding of the ISS environment, the Surface, Water, and Air Biocharacterization (SWAB) Flight Experiment was designed to investigate and develop monitoring technology to provide better microbial characterization. For the SWAB flight experiment, we hypothesized that environmental analysis using non-culture-based technologies would reveal microorganisms, allergens, and microbial toxins not previously reported in spacecraft, allowing for a more complete health assessment. Key findings during this experiment included: a) Generally, advanced molecular techniques were able to reveal a few organisms not recovered using culture-based methods; however, there is no indication that current monitoring is "missing" any medically significant bacteria or fungi. b) Molecular techniques have tremendous potential for microbial monitoring, however, sample preparation and data analysis present challenges for spaceflight hardware. c) Analytical results indicate that some molecular techniques, such as denaturing gradient gel electrophoresis (DGGE), can

  16. Urban Air Pollution in Taiwan before and after the Installation of a Mass Rapid Transit System.

    Science.gov (United States)

    Ding, Pei-Hsiou; Wang, Gen-Shuh; Chen, Bing-Yu; Wan, Gwo-Hwa

    2016-09-01

    Urbanization causes air pollution in metropolitan areas, coupled with meteorological factors that affect air quality. Although previous studies focused on the relationships of urbanization, air pollution, and climate change in Western countries, this study evaluated long-term variations of air quality and meteorological factors in Taiwanese metropolitan areas (Taipei area, Taichung City, and Kaohsiung City) and a rural area (Hualien County) between 1993 and 2012. The influence of a mass rapid transit (MRT) system on air quality was also evaluated. Air pollutant concentrations and meteorology data were collected from Taiwan Environmental Protection Administration (TEPA) air monitoring stations and Central Weather Bureau stations in the surveyed areas, respectively. Analyses indicate that levels of air pollution in metropolitan areas were greater than in the rural area. Kaohsiung City had the highest levels of O, SO, and particulate matter 2.5 or 10 µm in diameter (PM and PM). Clear downward trends for CO, NO, PM, PM, and especially SO concentrations were found in the surveyed areas, whereas O showed no decrease. Both O and PM concentrations showed similar bimodal seasonal distributions. Taiwan's air quality has improved significantly since 1993, indicating the effectiveness of promoting air pollution strategies and policies by the TEPA. Air pollution had an obvious improvement in Taipei area after the MRT system began operations in 1996. Because global climate may potentially affect urban air pollution in Taiwan, further study to clarify the mechanisms by which air pollution may affect human health and other biological effects is warranted. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

  17. Air mass flow estimation in turbocharged diesel engines from in-cylinder pressure measurement

    Energy Technology Data Exchange (ETDEWEB)

    Desantes, J.M.; Galindo, J.; Guardiola, C.; Dolz, V. [CMT - Motores Termicos, Universidad Politecnica de Valencia (Spain)

    2010-01-15

    Air mass flow determination is needed for the control of current internal combustion engines. Current methods are based on specific sensors (as hot wire anemometers) or indirect estimation through manifold pressure. With the availability of cylinder pressure sensors for engine control, methods based on them can be used for replacing or complementing standard methods. Present paper uses in cylinder pressure increase during the intake stroke for inferring the trapped air mass. The method is validated on two different turbocharged diesel engines and compared with the standard methods. (author)

  18. Thickened boundary layer theory for air film drag reduction on a van body surface

    Science.gov (United States)

    Xie, Xiaopeng; Cao, Lifeng; Huang, Heng

    2018-05-01

    To elucidate drag reduction mechanism on a van body surface under air film condition, a thickened boundary layer theory was proposed and a frictional resistance calculation model of the van body surface was established. The frictional resistance on the van body surface was calculated with different parameters of air film thickness. In addition, the frictional resistance of the van body surface under the air film condition was analyzed by computational fluid dynamics (CFD) simulation and different air film states that influenced the friction resistance on the van body surface were discussed. As supported by the CFD simulation results, the thickened boundary layer theory may provide reference for practical application of air film drag reduction on a van body surface.

  19. Particulate matter mass concentrations produced from pavement surface abrasion

    Directory of Open Access Journals (Sweden)

    Fullova Dasa

    2017-01-01

    Full Text Available According to the latest findings particulate matter belong to the most significant pollutants in Europe together with ground-level ozone O3 and nitrogen dioxide NO2. Road traffic is one of the main sources of particulate matter. Traffic volume has unpleasant impact on longevity of the pavements and also on the environment. Vehicle motions cause mechanical wearing of the asphalt pavement surface - wearing course by vehicle tyres. The paper deals with abrasion of bituminous wearing courses of pavements. The asphalt mixtures are compared in terms of mechanically separated particulate matter. The samples of asphalt mixtures were rutted in wheel tracking machine. The particulate matter measurements were performed in laboratory conditions. The experimental laboratory measurements make it possible to sample particulates without contamination from exhaust emissions, abraded particles from vehicles, resuspension of road dust and climate affects. The paper offers partial results of measurements on six trial samples of asphalt mixtures with different composition. It presents particulate matter morphology and the comparison of rutted asphalt samples in terms of PM mass concentrations and chemical composition.

  20. The Frequency of Occurrence of Air Masses Over Twelve European Cities.

    Science.gov (United States)

    1983-01-01

    cluster analysis technique to investigate the possibility of simplifying the European "",Oskar Essermanger, 1954, Neue Methode der Zerleang von...Masses, Streamlines, and the Boreal Forest," Geographical Bulletin, Vol 8 11 J. M. Davis, 1981, The Use of Cluster Analysis in the Identification and...Atmosphere and a Proposed Model for Frontal Analysis," Tellus, Vol 5 ’’N. S. McDonald, 1975, "Etgenvectur Analisis as an Aid to Air Mass Recognition

  1. A surface structural model for ferrihydrite I: Sites related to primary charge, molar mass, and mass density

    Science.gov (United States)

    Hiemstra, Tjisse; Van Riemsdijk, Willem H.

    2009-08-01

    A multisite surface complexation (MUSIC) model for ferrihydrite (Fh) has been developed. The surface structure and composition of Fh nanoparticles are described in relation to ion binding and surface charge development. The site densities of the various reactive surface groups, the molar mass, the mass density, the specific surface area, and the particle size are quantified. As derived theoretically, molecular mass and mass density of nanoparticles will depend on the types of surface groups and the corresponding site densities and will vary with particle size and surface area because of a relatively large contribution of the surface groups in comparison to the mineral core of nanoparticles. The nano-sized (˜2.6 nm) particles of freshly prepared 2-line Fh as a whole have an increased molar mass of M ˜ 101 ± 2 g/mol Fe, a reduced mass density of ˜3.5 ± 0.1 g/cm 3, both relatively to the mineral core. The specific surface area is ˜650 m 2/g. Six-line Fh (5-6 nm) has a molar mass of M ˜ 94 ± 2 g/mol, a mass density of ˜3.9 ± 0.1 g/cm 3, and a surface area of ˜280 ± 30 m 2/g. Data analysis shows that the mineral core of Fh has an average chemical composition very close to FeOOH with M ˜ 89 g/mol. The mineral core has a mass density around ˜4.15 ± 0.1 g/cm 3, which is between that of feroxyhyte, goethite, and lepidocrocite. These results can be used to constrain structural models for Fh. Singly-coordinated surface groups dominate the surface of ferrihydrite (˜6.0 ± 0.5 nm -2). These groups can be present in two structural configurations. In pairs, the groups either form the edge of a single Fe-octahedron (˜2.5 nm -2) or are present at a single corner (˜3.5 nm -2) of two adjacent Fe octahedra. These configurations can form bidentate surface complexes by edge- and double-corner sharing, respectively, and may therefore respond differently to the binding of ions such as uranyl, carbonate, arsenite, phosphate, and others. The relatively low PZC of

  2. Relationship between air mass type and emergency department visits for migraine headache across the Triangle region of North Carolina

    Science.gov (United States)

    Elcik, Christopher; Fuhrmann, Christopher M.; Mercer, Andrew E.; Davis, Robert E.

    2017-12-01

    An estimated 240 million people worldwide suffer from migraines. Because migraines are often debilitating, understanding the mechanisms that trigger them is crucial for effective prevention and treatment. Synoptic air mass types and emergency department (ED) visits for migraine headaches were examined over a 7-year period within a major metropolitan area of North Carolina to identify potential relationships between large-scale meteorological conditions and the incidence of migraine headaches. Barometric pressure changes associated with transitional air masses, or changing weather patterns, were also analyzed for potential relationships. Bootstrapping analysis revealed that tropical air masses (moist and dry) resulted in the greatest number of migraine ED visits over the study period, whereas polar air masses led to fewer. Moist polar air masses in particular were found to correspond with the fewest number of migraine ED visits. On transitional air mass days, the number of migraine ED visits fell between those of tropical air mass days and polar air mass days. Transitional days characterized by pressure increases exhibited a greater number of migraine ED visits than days characterized by pressure decreases. However, no relationship was found between migraine ED visits and the magnitude of barometric pressure changes associated with transitional air masses.

  3. Measurements of the spatial distribution of tritium in air above a chronically contaminated surface

    International Nuclear Information System (INIS)

    Workman, W.J.G.; Davis, P.A.; Wood, M.J.; Barry, P.J.

    1993-01-01

    Tritium in air (HTO) concentrations were measured over a 13 month period above a surface that is chronically contaminated by tritium-bearing groundwater from a waste management area. The measurements were made using passive diffusion samplers, which were sited at six locations (about 100 m apart) at 0.15, 0.9, and 1.8 m above ground level. The diffusion samplers were compact, sampled at a known rate, and required no external power source. They are ideal for remote locations and require a minimum of effort to collect and analyze the data. HTO-in-air concentration peaked in the summer at 500-1500 Bq.m -3 and decreased in the winter to 1-120 Bq.m -3 . In general, concentration decreased with height above ground level, implying that HTO is being lost from the surface to the atmosphere. The flux of tritium to the atmosphere must, therefore, be taken into account to estimate the tritium mass balance for a contaminated area. (Author) 3 figs., 5 tabs., 10 refs

  4. Air/surface exchange processes of mercury and their linkage to atmospheric pools

    International Nuclear Information System (INIS)

    Bahlmann, Enno; Ebinghaus, Ralf

    2001-01-01

    The atmospheric mercury cycle is strongly linked to the terrestrial, aquatic and biologic cycle of mercury via air/surface exchange processes. In order to quantify mercury fluxes from and to the atmosphere to predict local and regional source contributions the methods for flux measurements as well as the physicochemical factors controlling air/surface exchange processes must be assessed. We will describe methods for the determination of mercury and mercury species in ambient air which are basic for investigation of air/surface exchange processes. Further on we will describe approaches for studying the physicochemical factors controlling this processes by using a new laboratory flux measurement system. (author)

  5. Colonization by Cladosporium spp. of painted metal surfaces associated with heating and air conditioning systems

    Science.gov (United States)

    Ahearn, D. G.; Simmons, R. B.; Switzer, K. F.; Ajello, L.; Pierson, D. L.

    1991-01-01

    Cladosporium cladosporioides and C. hebarum colonized painted metal surfaces of covering panels and register vents of heating, air conditioning and ventilation systems. Hyphae penetrated the paint film and developed characteristic conidiophores and conidia. The colonies were tightly appressed to the metal surface and conidia were not readily detectable via standard air sampling procedures.

  6. A groundwater mass flux model for screening the groundwater-to-indoor-air exposure pathway

    Energy Technology Data Exchange (ETDEWEB)

    McHugh, T.; Blanc, P.C. de; Connor, J. [Groundwater Services Inc, Houston, TX (United States)

    2003-07-01

    The potential for human exposure via volatilisation of groundwater contaminants into indoor air has been a focus of increasing concern in recent years. At a small number of sites, elevated indoor vapour concentrations have been measured within buildings overlying shallow groundwater contaminated with chlorinated solvents, causing public concern over the potential for similar problems at other corrective action sites. In addition, use of the screening-levelmodel developed by Johnson and Ettinger (1991) for the groundwater-to-indoor-air exposure pathway has suggested that low microgram per litre (ug/L)-range concentrations of either chlorinated or non-chlorinated volatile organic compounds dissolved in groundwater could result in indoor vapour concentrations in excess of applicable risk-based exposure limits. As an alternative screening tool, this paper presents a groundwater mass flux model for evaluation of transport to indoor air. The mass flux model is intended to serve as a highly conservative screening tool that over-predicts groundwater-to-indoor-air mass flux, yet still provides sufficient sensitivity to identify sites for which the groundwater-to-indoor air exposure pathway is not a concern. (orig.)

  7. Evaluating heat-related mortality in Korea by objective classifications of 'air masses'

    Czech Academy of Sciences Publication Activity Database

    Kyselý, Jan; Huth, Radan; Kim, J.

    2010-01-01

    Roč. 30, č. 10 (2010), s. 1484-1501 ISSN 0899-8418 R&D Projects: GA ČR GC205/07/J044 Institutional research plan: CEZ:AV0Z30420517 Keywords : weather type classifications * air masses * biometeorology * human mortality * South Korea Subject RIV: DG - Athmosphere Sciences, Meteorology Impact factor: 2.479, year: 2010

  8. ''Anomalous'' air showers from point sources: Mass limits and light curves

    International Nuclear Information System (INIS)

    Domokos, G.; Elliott, B.; Kovesi-Domokos, S.

    1993-01-01

    We describe a method to obtain upper limits on the mass of the primaries of air showers associated with point sources. One also obtains the UHE pulse shape of a pulsar if its period is observed in the signal. As an example, we analyze the data obtained during a recent burst of Hercules-X1

  9. Particle growth in an isoprene-rich forest: Influences of urban, wildfire, and biogenic air masses

    Science.gov (United States)

    Gunsch, Matthew J.; Schmidt, Stephanie A.; Gardner, Daniel J.; Bondy, Amy L.; May, Nathaniel W.; Bertman, Steven B.; Pratt, Kerri A.; Ault, Andrew P.

    2018-04-01

    Growth of freshly nucleated particles is an important source of cloud condensation nuclei (CCN) and has been studied within a variety of environments around the world. However, there remains uncertainty regarding the sources of the precursor gases leading to particle growth, particularly in isoprene-rich forests. In this study, particle growth events were observed from the 14 total events (31% of days) during summer measurements (June 24 - August 2, 2014) at the Program for Research on Oxidants PHotochemistry, Emissions, and Transport (PROPHET) tower within the forested University of Michigan Biological Station located in northern Michigan. Growth events were observed within long-range transported air masses from urban areas, air masses impacted by wildfires, as well as stagnant, forested/regional air masses. Growth events observed during urban-influenced air masses were prevalent, with presumably high oxidant levels, and began midday during periods of high solar radiation. This suggests that increased oxidation of biogenic volatile organic compounds (BVOCs) likely contributed to the highest observed particle growth in this study (8 ± 2 nm h-1). Growth events during wildfire-influenced air masses were observed primarily at night and had slower growth rates (3 ± 1 nm h-1). These events were likely influenced by increased SO2, O3, and NO2 transported within the smoke plumes, suggesting a role of NO3 oxidation in the production of semi-volatile compounds. Forested/regional air mass growth events likely occurred due to the oxidation of regionally emitted BVOCs, including isoprene, monoterpenes, and sesquiterpenes, which facilitated multiday growth events also with slower rates (3 ± 2 nm h-1). Intense sulfur, carbon, and oxygen signals in individual particles down to 20 nm, analyzed by transmission electron microscopy with energy dispersive X-ray spectroscopy (TEM-EDX), suggest that H2SO4 and secondary organic aerosol contributed to particle growth. Overall, aerosol

  10. Skating on a Film of Air: Drops Impacting on a Surface

    Science.gov (United States)

    Kolinski, John M.; Rubinstein, Shmuel M.; Mandre, Shreyas; Brenner, Michael P.; Weitz, David A.; Mahadevan, L.

    2012-02-01

    The commonly accepted description of drops impacting on a surface typically ignores the essential role of the air that is trapped between the impacting drop and the surface. Here we describe a new imaging modality that is sensitive to the behavior right at the surface. We show that a very thin film of air, only a few tens of nanometers thick, remains trapped between the falling drop and the surface as the drop spreads. The thin film of air serves to lubricate the drop enabling the fluid to skate on the air film laterally outward at surprisingly high velocities, consistent with theoretical predictions. Eventually this thin film of air breaks down as the fluid wets the surface via a spinodal-like mechanism. Our results show that the dynamics of impacting drops are much more complex than previously thought, with a rich array of unexpected phenomena that require rethinking classic paradigms.

  11. Impacts of urban land-surface forcing on ozone air quality in the Seoul metropolitan area

    Directory of Open Access Journals (Sweden)

    Y.-H. Ryu

    2013-02-01

    Full Text Available Modified local meteorology owing to heterogeneities in the urban–rural surface can affect urban air quality. In this study, the impacts of urban land-surface forcing on ozone air quality during a high ozone (O3 episode in the Seoul metropolitan area, South Korea, are investigated using a high-resolution chemical transport model (CMAQ. Under fair weather conditions, the temperature excess (urban heat island significantly modifies boundary layer characteristics/structures and local circulations. The modified boundary layer and local circulations result in an increase in O3 levels in the urban area of 16 ppb in the nighttime and 13 ppb in the daytime. Enhanced turbulence in the deep urban boundary layer dilutes pollutants such as NOx, and this contributes to the elevated O3 levels through the reduced O3 destruction by NO in the NOx-rich environment. The advection of O3 precursors over the mountains near Seoul by the prevailing valley-breeze circulation in the mid- to late morning results in the build-up of O3 over the mountains in conjunction with biogenic volatile organic compound (BVOC emissions there. As the prevailing local circulation in the afternoon changes to urban-breeze circulation, the O3-rich air masses over the mountains are advected over the urban area. The urban-breeze circulation exerts significant influences on not only the advection of O3 but also the chemical production of O3 under the circumstances in which both anthropogenic and biogenic (natural emissions play important roles in O3 formation. As the air masses that are characterized by low NOx and high BVOC levels and long OH chain length are advected over the urban area from the surroundings, the ozone production efficiency increases in the urban area. The relatively strong vertical mixing in the urban boundary layer embedded in the

  12. Estimation of surface air temperature over central and eastern Eurasia from MODIS land surface temperature

    International Nuclear Information System (INIS)

    Shen Suhung; Leptoukh, Gregory G

    2011-01-01

    Surface air temperature (T a ) is a critical variable in the energy and water cycle of the Earth–atmosphere system and is a key input element for hydrology and land surface models. This is a preliminary study to evaluate estimation of T a from satellite remotely sensed land surface temperature (T s ) by using MODIS-Terra data over two Eurasia regions: northern China and fUSSR. High correlations are observed in both regions between station-measured T a and MODIS T s . The relationships between the maximum T a and daytime T s depend significantly on land cover types, but the minimum T a and nighttime T s have little dependence on the land cover types. The largest difference between maximum T a and daytime T s appears over the barren and sparsely vegetated area during the summer time. Using a linear regression method, the daily maximum T a were estimated from 1 km resolution MODIS T s under clear-sky conditions with coefficients calculated based on land cover types, while the minimum T a were estimated without considering land cover types. The uncertainty, mean absolute error (MAE), of the estimated maximum T a varies from 2.4 °C over closed shrublands to 3.2 °C over grasslands, and the MAE of the estimated minimum T a is about 3.0 °C.

  13. Surface and upper air meteorological features during onset phase

    Indian Academy of Sciences (India)

    There was a sharp fall in the temperature difference between 850 and 500 hPa, and the height of zero degree isotherm about 2–3 days before the monsoon onset. The flux of sensible heat was positive (sea to air) over south Arabian Sea during the onset phase. Over the Bay of Bengal higher negative (air to sea) values of ...

  14. The time series variations of tritium concentration in precipitation and its relationships to the rainfall-inducing air mass

    International Nuclear Information System (INIS)

    Shimada, Jun

    1978-01-01

    The author measured the tritium concentration in precipitation of Tokyo for every ten-day period from August 1972 to May 1974. Judging from the daily synoptic weather chart, the rainfall-inducing air masses in Japan were classified into five types; polar maritime air mass (Pm), polar continental air mass (Pc), tropical maritime air mass (Tm), tropical continental air mass (Tc), and equatorial maritime air mass (Em). And the precipitation for every ten-day period sampled for tritium measurement were classified into these five types. Based on this classification, it is confirmed that there exist clear difference in the tritium concentration between the rainfall from the continental air mass and ones from the maritime air mass. It is characteristic that the tritium concentration in rainfall induced by equatorial maritime air mass such as typhoon in summer and early fall season is very low whereas the tritium concentration in rainfall and snowfall induced directly by the polar continental air mass in late winter season is very high. The regional difference of the tritium concentration in intermonthly precipitation could considerably be explained by this synoptic meteological classification of rainfall-inducing air mass. In spite of these regional difference of tritium concentration in precipitation, use of the tritium concentration of Tokyo as a representative value of Japan may be allowed because of the similarities of the changing pattern and annual mean tritium concentration. The time series variations of tritium concentration in precipitation of Tokyo from August 1972 to December 1977, Tsukuba from December 1976 to April 1978, and Nagaoka from April 1977 to March 1978 are listed. (author)

  15. New particle formation in air mass transported between two measurement sites in Northern Finland

    Directory of Open Access Journals (Sweden)

    M. Komppula

    2006-01-01

    Full Text Available This study covers four years of aerosol number size distribution data from Pallas and Värriö sites 250 km apart from each other in Northern Finland and compares new particle formation events between these sites. In air masses of eastern origin almost all events were observed to start earlier at the eastern station Värriö, whereas in air masses of western origin most of the events were observed to start earlier at the western station Pallas. This demonstrates that particle formation in a certain air mass type depends not only on the diurnal variation of the parameters causing the phenomenon (such as photochemistry but also on some properties carried by the air mass itself. The correlation in growth rates between the two sites was relatively good, which suggests that the amount of condensable vapour causing the growth must have been at about the same level in both sites. The condensation sink was frequently much higher at the downwind station. It seems that secondary particle formation related to biogenic sources dominate in many cases over the particle sinks during the air mass transport between the sites. Two cases of transport from Pallas to Värriö were further analysed with an aerosol dynamics model. The model was able to reproduce the observed nucleation events 250 km down-wind at Värriö but revealed some differences between the two cases. The simulated nucleation rates were in both cases similar but the organic concentration profiles that best reproduced the observations were different in the two cases indicating that divergent formation reactions may dominate under different conditions. The simulations also suggested that organic compounds were the main contributor to new particle growth, which offers a tentative hypothesis to the distinct features of new particles at the two sites: Air masses arriving from the Atlantic Ocean typically spent approximately only ten hours over land before arriving at Pallas, and thus the time for the

  16. The EUSTACE project: delivering global, daily information on surface air temperature

    Science.gov (United States)

    Ghent, D.; Rayner, N. A.

    2017-12-01

    Day-to-day variations in surface air temperature affect society in many ways; however, daily surface air temperature measurements are not available everywhere. A global daily analysis cannot be achieved with measurements made in situ alone, so incorporation of satellite retrievals is needed. To achieve this, in the EUSTACE project (2015-2018, https://www.eustaceproject.eu) we have developed an understanding of the relationships between traditional (land and marine) surface air temperature measurements and retrievals of surface skin temperature from satellite measurements, i.e. Land Surface Temperature, Ice Surface Temperature, Sea Surface Temperature and Lake Surface Water Temperature. Here we discuss the science needed to produce a fully-global daily analysis (or ensemble of analyses) of surface air temperature on the centennial scale, integrating different ground-based and satellite-borne data types. Information contained in the satellite retrievals is used to create globally-complete fields in the past, using statistical models of how surface air temperature varies in a connected way from place to place. This includes developing new "Big Data" analysis methods as the data volumes involved are considerable. We will present recent progress along this road in the EUSTACE project, i.e.: • identifying inhomogeneities in daily surface air temperature measurement series from weather stations and correcting for these over Europe; • estimating surface air temperature over all surfaces of Earth from surface skin temperature retrievals; • using new statistical techniques to provide information on higher spatial and temporal scales than currently available, making optimum use of information in data-rich eras. Information will also be given on how interested users can become involved.

  17. Characterising terrestrial influences on Antarctic air masses using Radon-222 measurements at King George Island

    Science.gov (United States)

    Chambers, S. D.; Hong, S.-B.; Williams, A. G.; Crawford, J.; Griffiths, A. D.; Park, S.-J.

    2014-09-01

    We report on one year of high-precision direct hourly radon observations at King Sejong Station (King George Island) beginning in February 2013. Findings are compared with historic and ongoing radon measurements from other Antarctic sites. Monthly median concentrations reduced from 72 mBq m-3 in late-summer to 44 mBq m-3 in late winter and early spring. Monthly 10th percentiles, ranging from 29 to 49 mBq m-3, were typical of oceanic baseline values. Diurnal cycles were rarely evident and local influences were minor, consistent with regional radon flux estimates one tenth of the global average for ice-free land. The predominant fetch region for terrestrially influenced air masses was South America (47-53° S), with minor influences also attributed to aged Australian air masses and local sources. Plume dilution factors of 2.8-4.0 were estimated for the most terrestrially influenced (South American) air masses, and a seasonal cycle in terrestrial influence on tropospheric air descending at the pole was identified and characterised.

  18. Gamma-ray dose rate increase at rainfall events and their air-mass origins

    International Nuclear Information System (INIS)

    Iyogi, Takashi; Hisamatsu, Shun'ichi; Inaba, Jiro

    2007-01-01

    The environmental γ-ray dose rate and precipitation rates were measured at our institute, in Rokkasho, Aomori, Japan. We analyzed 425 rainfall events in which the precipitation rate was over 0.5 mm from April through November during the years 2003 to 2005. Backward trajectories for 5 d starting from 1000 m above Rokkasho at the time of the maximum dose rate in a rainfall event, were calculated by using the HYSPLIT model of the NOAA Air Resources Laboratory. The trajectories for 5 d were classified by visual inspection according to the passage areas; Pacific Ocean, Asian Continent and Japan Islands. The increase of cumulative environmental γ-ray dose during a rainfall event was plotted against the precipitation in the event, and their relationship was separately examined according to the air-mass passage area, i.e. origin of the air-mass. Our results showed that the origin of air-mass was an important factor affecting the increase of environmental γ-ray dose rate by rainfall. (author)

  19. Influence of atmospheric rainfall to γ radiation Kerma rate in surface air

    International Nuclear Information System (INIS)

    Xu Zhe; Wan Jun; Yu Rongsheng

    2009-01-01

    Objective: To investigate the influence rule of the atmospheric Rainfall to the γ radiation Kerma rate in surface air in order to revise the result of its measurement during rainfall. Methods: The influence factors of rainfall to the measurement of the γ radiation Kerma rate in air were analyzed and then the differential equation of the correlation factors was established theoretically, and by resolving the equation, the mathematical model Was obtained. The model was discussed through several practical examples. Results: The mathematical model was coincided with the tendency of curve about the measured data on the influence rule of rainfall to the γ radiation Kerma rate in surface air. Conclusion: By using the theoretical formula in this article which is established to explain the relationship between the rainfall and the γ radiation Kerma rate in surface air, the influence of rainfall to the γ radiation Kerma rate in surface air could be correctly revised. (authors)

  20. Defining Winter and Identifying Synoptic Air Mass Change in the Northeast and Northern Plains U.S. since 1950

    Science.gov (United States)

    Chapman, C. J.; Pennington, D.; Beitscher, M. R.; Godek, M. L.

    2017-12-01

    Understanding and forecasting the characteristics of winter weather change in the northern U.S. is vital to regional economy, agriculture, tourism and resident life. This is especially true in the Northeast and Northern Plains where substantial changes to the winter season have already been documented in the atmospheric science and biological literature. As there is no single established definition of `winter', this research attempts to identify the winter season in both regions utilizing a synoptic climatological approach with air mass frequencies. The Spatial Synoptic Classification is used to determine the daily air mass/ weather type conditions since 1950 at 40 locations across the two regions. Annual frequencies are first computed as a baseline reference. Then winter air mass frequencies and departures from normal are calculated to define the season along with the statistical significance. Once the synoptic winter is established, long-term regional changes to the season and significance are explored. As evident global changes have occurred after 1975, an Early period of years prior to 1975 and a Late set for all years following this date are compared. Early and Late record synoptic changes are then examined to assess any thermal and moisture condition changes of the regional winter air masses over time. Cold to moderately dry air masses dominate annually in both regions. Northeast winters are also characterized by cold to moderate dry air masses, with coastal locations experiencing more Moist Polar types. The Northern Plains winters are dominated by cold, dry air masses in the east and cold to moderate dry air masses in the west. Prior to 1975, Northeast winters are defined by an increase in cooler and wetter air masses. Dry Tropical air masses only occur in this region after 1975. Northern Plains winters are also characterized by more cold, dry air masses prior to 1975. More Dry Moderate and Moist Moderate air masses have occurred since 1975. These results

  1. Mass spectrometry of solid samples in open air using combined laser ionization and ambient metastable ionization

    International Nuclear Information System (INIS)

    He, X.N.; Xie, Z.Q.; Gao, Y.; Hu, W.; Guo, L.B.; Jiang, L.; Lu, Y.F.

    2012-01-01

    Mass spectrometry of solid samples in open air was carried out using combined laser ionization and metastable ionization time-of-flight mass spectrometry (LI-MI-TOFMS) in ambient environment for qualitative and semiquantitative (relative analyte information, not absolute information) analysis. Ambient metastable ionization using a direct analysis in realtime (DART) ion source was combined with laser ionization time-of-flight mass spectrometry (LI-TOFMS) to study the effects of combining metastable and laser ionization. A series of metallic samples from the National Institute of Standards and Technology (NIST 494, 495, 498, 499, and 500) and a pure carbon target were characterized using LI-TOFMS in open air. LI-MI-TOFMS was found to be superior to laser-induced breakdown spectroscopy (LIBS). Laser pulse energies between 10 and 200 mJ at the second harmonic (532 nm) of an Nd:YAG laser were applied in the experiment to obtain a high degree of ionization in plasmas. Higher laser pulse energy improves signal intensities of trace elements (such as Fe, Cr, Mn, Ni, Ca, Al, and Ag). Data were analyzed by numerically calculating relative sensitivity coefficients (RSCs) and limit of detections (LODs) from mass spectrometry (MS) and LIBS spectra. Different parameters, such as boiling point, ionization potential, RSC, LOD, and atomic weight, were shown to analyze the ionization and MS detection processes in open air.

  2. Air trapping on computed tomography images of healthy individuals: effects of respiration and body mass index

    International Nuclear Information System (INIS)

    Hashimoto, M.; Tate, E.; Watarai, J.; Sasaki, M.

    2006-01-01

    Aim: To evaluate the relationships of changes in the lung area during respiration and of individual body mass index (BMI) to air trapping on expiratory computed tomography (CT) in young non-smoking adults of either gender. Methods: The volunteers were 10 women and 10 men (mean age 25.7 years) who were healthy lifelong non-smokers. We obtained both end-inspiratory and end-expiratory CT images at three levels: the upper, middle and lower lung. The ratio of cross-sectional lung area upon expiration to cross-sectional lung area upon inspiration (lung area ratio) was determined for each lung at each of the three levels. In cases showing air trapping, we calculated the percentage of area of air in relation to the total lung area in each section. BMI was calculated for each participant. Results: Air trapping was present in dependent areas of the lungs of 6 women and 5 men. The mean percentage of area of air trapped was statistically greater for men (9.8 ± 9.2%) than for women (4.9 ± 5.2%). The mean lung area ratio was 0.52 ± 0 14 among volunteers with air trapping (66 sections) and 0.69 ± 0.12 among those without air trapping (54 sections) (p < 0.001). At each lung level, the mean lung area ratio was greater in individuals with air trapping than in those without. Mean BMI was also greater in these people (p = 0.009). Conclusion: Change in the respiratory lung area and BMI contribute to development of air trapping

  3. Energy Accommodation from Surface Catalyzed Reactions in Air Plasmas

    Data.gov (United States)

    National Aeronautics and Space Administration — Understanding energy transport at the gas-surface interface between catalytic/reacting surfaces exposed to highly dissociated plasmas remains a significant research...

  4. A study of laser surface modification of polymers: A comparison in air and water

    DEFF Research Database (Denmark)

    Marla, Deepak; Andersen, Sebastian A.; Zhang, Yang

    2018-01-01

    Laser surface modification is a technique to modify polymer surfaces for various applications. In our earlier work [Physics Procedia, 83:211–217, 2016], we showed that when the laser surface modification process was carried out in water instead of air, the obtained surface characteristics were...... research. The observed images of laser modified surfaces suggest that a hemispherical hump is formed in the case of water at lower laser fluences that breakup with an increase in fluence. Such a behavior was not observed when the process was carried out in air. We explain this phenomenon by simulating...

  5. The analysis of mass and energy transfer from a surface by means of a physical model conceived as a teaching tool

    International Nuclear Information System (INIS)

    Peressotti, A.; Zerbi, G.; Delle Vedove, G.; Ham, J.H.

    1993-01-01

    A physical model representing an evapotranspirating field on a scale 1:100 is described. The model, having a moderate cost, was devised as a teaching tool for agronomy and agrometeorology classes; it permits the measurement and the continuous monitoring of the parameters involved in mass and energy transfer over an evaporating surface (radiation, turbulence, temperature of the air and of the surface, heat fluxes, vapor pressure gradients). The physical characteristics of the surface can be changed to simulate different situations of a cultivated field. The surface resistance is calculated by the measurement of the Bowen ratio and directly from the measurement of the surface temperature [it

  6. Atmospheric river impacts on Greenland Ice Sheet surface melt and mass balance

    Science.gov (United States)

    Mattingly, K.; Mote, T. L.

    2017-12-01

    Mass loss from the Greenland Ice Sheet (GrIS) has accelerated during the early part of the 21st Century. Several episodes of widespread GrIS melt in recent years have coincided with intense poleward moisture transport by atmospheric rivers (ARs), suggesting that variability in the frequency and intensity of these events may be an important driver of the surface mass balance (SMB) of the GrIS. ARs may contribute to GrIS surface melt through the greenhouse effect of water vapor, the radiative effects of clouds, condensational latent heating within poleward-advected air masses, and the energy provided by liquid precipitation. However, ARs may also provide significant positive contributions to GrIS SMB through enhanced snow accumulation. Prior research on the role of ARs in Arctic climate has consisted of case studies of ARs associated with major GrIS melt events or examined the effects of poleward moisture flux on Arctic sea ice. In this study, a long-term (1979-2016) record of intense moisture transport events affecting Greenland is compiled using a conventional AR identification algorithm as well as a self-organizing map (SOM) classification applied to integrated water vapor transport (IVT) data from several atmospheric reanalysis datasets. An analysis of AR effects on GrIS melt and SMB is then performed with GrIS surface melt data from passive microwave satellite observations and the Modèle Atmosphérique Régional (MAR) regional climate model. Results show that meltwater production is above normal during and after AR impact days throughout the GrIS during all seasons, with surface melt enhanced most by strong (> 85th percentile IVT) and extreme (> 95th percentile IVT) ARs. This relationship holds at the seasonal scale, as the total amount of water vapor transported to the GrIS by ARs is significantly greater during above-normal melt seasons. ARs exert a more complex influence on SMB. Normal (< 85th percentile IVT) ARs generally do not have a substantial impact on

  7. Air transport pilots' information priorities for surface moving maps

    Science.gov (United States)

    2003-10-13

    The use of a surface map display for operations on or near the airport surface (taxi out, takeoff, final approach and landing, taxi in) is expected to enhance safety. There is a lack of research, however, detailing how the airport surface should be d...

  8. Estimation of Surface Air Temperature Over Central and Eastern Eurasia from MODIS Land Surface Temperature

    Science.gov (United States)

    Shen, Suhung; Leptoukh, Gregory G.

    2011-01-01

    Surface air temperature (T(sub a)) is a critical variable in the energy and water cycle of the Earth.atmosphere system and is a key input element for hydrology and land surface models. This is a preliminary study to evaluate estimation of T(sub a) from satellite remotely sensed land surface temperature (T(sub s)) by using MODIS-Terra data over two Eurasia regions: northern China and fUSSR. High correlations are observed in both regions between station-measured T(sub a) and MODIS T(sub s). The relationships between the maximum T(sub a) and daytime T(sub s) depend significantly on land cover types, but the minimum T(sub a) and nighttime T(sub s) have little dependence on the land cover types. The largest difference between maximum T(sub a) and daytime T(sub s) appears over the barren and sparsely vegetated area during the summer time. Using a linear regression method, the daily maximum T(sub a) were estimated from 1 km resolution MODIS T(sub s) under clear-sky conditions with coefficients calculated based on land cover types, while the minimum T(sub a) were estimated without considering land cover types. The uncertainty, mean absolute error (MAE), of the estimated maximum T(sub a) varies from 2.4 C over closed shrublands to 3.2 C over grasslands, and the MAE of the estimated minimum Ta is about 3.0 C.

  9. Land Surface Process and Air Quality Research and Applications at MSFC

    Science.gov (United States)

    Quattrochi, Dale; Khan, Maudood

    2007-01-01

    This viewgraph presentation provides an overview of land surface process and air quality research at MSFC including atmospheric modeling and ongoing research whose objective is to undertake a comprehensive spatiotemporal analysis of the effects of accurate land surface characterization on atmospheric modeling results, and public health applications. Land use maps as well as 10 meter air temperature, surface wind, PBL mean difference heights, NOx, ozone, and O3+NO2 plots as well as spatial growth model outputs are included. Emissions and general air quality modeling are also discussed.

  10. Greenland surface mass-balance observations from the ice-sheet ablation area and local glaciers

    DEFF Research Database (Denmark)

    Machguth, Horst; Thomsen, Henrik H.; Weidick, Anker

    2016-01-01

    Glacier surface mass-balance measurements on Greenland started more than a century ago, but no compilation exists of the observations from the ablation area of the ice sheet and local glaciers. Such data could be used in the evaluation of modelled surface mass balance, or to document changes in g...

  11. Greenland surface mass-balance observations from the ice-sheet ablation area and local glaciers

    NARCIS (Netherlands)

    Machguth, Horst; Thomsen, Henrik H.; Weidick, Anker; Ahlstrøm, Andreas P.; Abermann, Jakob; Andersen, Morten L.; Andersen, Signe B.; Bjørk, Anders A.; Box, Jason E.; Braithwaite, Roger J.; Bøggild, Carl E.; Citterio, Michele; Clement, Poul; Colgan, William; Fausto, Robert S.; Gleie, Karin; Gubler, Stefanie; Hasholt, Bent; Hynek, Bernhard; Knudsen, Niels T.; Larsen, Signe H.; Mernild, Sebastian H.; Oerlemans, Johannes; Oerter, Hans; Olesen, Ole B.; Smeets, C. J P Paul; Steffen, Konrad; Stober, Manfred; Sugiyama, Shin; Van As, Dirk; Van Den Broeke, Michiel R.; Van De Wal, Roderik S W

    2016-01-01

    Glacier surface mass-balance measurements on Greenland started more than a century ago, but no compilation exists of the observations from the ablation area of the ice sheet and local glaciers. Such data could be used in the evaluation of modelled surface mass balance, or to document changes in

  12. Retrieval of sea surface air temperature from satellite data over Indian Ocean: An empirical approach

    Digital Repository Service at National Institute of Oceanography (India)

    Sathe, P.V.; Muraleedharan, P.M.

    the sea surface air temperature from satellite derived sea surface humidity in the Indian Ocean. Using the insitu data on surface met parameters collected on board O.R.V. Sagar Kanya in the Indian Ocean over a period of 15 years, the relationship between...

  13. Calibration of a surface mass balance model for global-scale applications

    NARCIS (Netherlands)

    Giesen, R. H.; Oerlemans, J.

    2012-01-01

    Global applications of surface mass balance models have large uncertainties, as a result of poor climate input data and limited availability of mass balance measurements. This study addresses several possible consequences of these limitations for the modelled mass balance. This is done by applying a

  14. Neonatal Presentation of an Air-Filled Neck Mass that Enlarges with Valsalva: A Case Report

    Science.gov (United States)

    Patel, Jasminkumar Bharatbhai; Kilbride, Howard; Paulson, Lorien

    2015-01-01

    Branchial cleft cysts are common causes of congenital neck masses in the pediatric population. However, neonatal presentation of branchial cleft cysts is uncommon, but recognizable secondary to acute respiratory distress from airway compression or complications secondary to infection. We report a 1-day-old infant presenting with an air-filled neck mass that enlarged with Valsalva and was not associated with respiratory distress. The infant was found to have a third branchial cleft cyst with an internal opening into the pyriform sinus. The cyst was conservatively managed with endoscopic surgical decompression and cauterization of the tract and opening. We review the embryology of branchial cleft cysts and current management. PMID:26495186

  15. Photochemical aging of aerosol particles in different air masses arriving at Baengnyeong Island, Korea

    Science.gov (United States)

    Kang, Eunha; Lee, Meehye; Brune, William H.; Lee, Taehyoung; Park, Taehyun; Ahn, Joonyoung; Shang, Xiaona

    2018-05-01

    Atmospheric aerosol particles are a serious health risk, especially in regions like East Asia. We investigated the photochemical aging of ambient aerosols using a potential aerosol mass (PAM) reactor at Baengnyeong Island in the Yellow Sea during 4-12 August 2011. The size distributions and chemical compositions of aerosol particles were measured alternately every 6 min from the ambient air or through the highly oxidizing environment of a potential aerosol mass (PAM) reactor. Particle size and chemical composition were measured by using the combination of a scanning mobility particle sizer (SMPS) and a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS). Inside the PAM reactor, O3 and OH levels were equivalent to 4.6 days of integrated OH exposure at typical atmospheric conditions. Two types of air masses were distinguished on the basis of the chemical composition and the degree of aging: air transported from China, which was more aged with a higher sulfate concentration and O : C ratio, and the air transported across the Korean Peninsula, which was less aged with more organics than sulfate and a lower O : C ratio. For both episodes, the particulate sulfate mass concentration increased in the 200-400 nm size range when sampled through the PAM reactor. A decrease in organics was responsible for the loss of mass concentration in 100-200 nm particles when sampled through the PAM reactor for the organics-dominated episode. This loss was especially evident for the m/z 43 component, which represents less oxidized organics. The m/z 44 component, which represents further oxidized organics, increased with a shift toward larger sizes for both episodes. It is not possible to quantify the maximum possible organic mass concentration for either episode because only one OH exposure of 4.6 days was used, but it is clear that SO2 was a primary precursor of secondary aerosol in northeast Asia, especially during long-range transport from China. In addition

  16. Understanding the Role of Wind in Reducing the Surface Mass Balance Estimates over East Antarctica

    Science.gov (United States)

    Das, I.; Scambos, T. A.; Koenig, L.; Creyts, T. T.; Bell, R. E.; van den Broeke, M. R.; Lenaerts, J.; Paden, J. D.

    2014-12-01

    Accurate quantification of surface snow-accumulation over Antarctica is important for mass balance estimates and climate studies based on ice core records. An improved estimate of surface mass balance must include the significant role near-surface wind plays in the sublimation and redistribution of snow across Antarctica. We have developed an empirical model based on airborne radar and lidar observations, and modeled surface mass balance and wind fields to produce a continent-wide prediction of wind-scour zones over Antarctica. These zones have zero to negative surface mass balance, are located over locally steep ice sheet areas (>0.002) and controlled by bedrock topography. The near-surface winds accelerate over these zones, eroding and sublimating the surface snow. This scouring results in numerous localized regions (≤ 200 km2) with reduced surface accumulation. Each year, tens of gigatons of snow on the Antarctic ice sheet are ablated by persistent near-surface katabatic winds over these wind-scour zones. Large uncertainties remain in the surface mass balance estimates over East Antarctica as climate models do not adequately represent the small-scale physical processes that lead to mass loss through sublimation or redistribution over the wind-scour zones. In this study, we integrate Operation IceBridge's snow radar over the Recovery Ice Stream with a series of ice core dielectric and depth-density profiles for improved surface mass balance estimates that reflect the mass loss over the wind-scour zones. Accurate surface mass balance estimates from snow radars require spatially variable depth-density profiles. Using an ensemble of firn cores, MODIS-derived surface snow grain size, modeled accumulation rates and surface temperatures from RACMO2, we assemble spatially variable depth-density profiles and use our mapping of snow density variations to estimate layer mass and net accumulation rates from snow radar layer data. Our study improves the quantification of

  17. Distillation and Air Stripping Designs for the Lunar Surface

    Science.gov (United States)

    Boul, Peter J.; Lange, Kevin E.; Conger, Bruce; Anderson, Molly

    2009-01-01

    Air stripping and distillation are two different gravity-based methods, which may be applied to the purification of wastewater on the lunar base. These gravity-based solutions to water processing are robust physical separation techniques, which may be advantageous to many other techniques for their simplicity in design and operation. The two techniques can be used in conjunction with each other to obtain high purity water. The components and feed compositions for modeling waste water streams are presented in conjunction with the Aspen property system for traditional stage distillation models and air stripping models. While the individual components for each of the waste streams will vary naturally within certain bounds, an analog model for waste water processing is suggested based on typical concentration ranges for these components. Target purity levels for the for recycled water are determined for each individual component based on NASA s required maximum contaminant levels for potable water Distillation processes are modeled separately and in tandem with air stripping to demonstrate the potential effectiveness and utility of these methods in recycling wastewater on the Moon. Optimum parameters such as reflux ratio, feed stage location, and processing rates are determined with respect to the power consumption of the process. Multistage distillation is evaluated for components in wastewater to determine the minimum number of stages necessary for each of 65 components in humidity condensate and urine wastewater mixed streams. Components of the wastewater streams are ranked by Henry s Law Constant and the suitability of air stripping in the purification of wastewater in terms of component removal is evaluated. Scaling factors for distillation and air stripping columns are presented to account for the difference in the lunar gravitation environment. Commercially available distillation and air stripping units which are considered suitable for Exploration Life Support

  18. Condensation of atmospheric moisture from tropical maritime air masses as a freshwater resource.

    Science.gov (United States)

    Gerard, R D; Worzel, J L

    1967-09-15

    A method is proposed whereby potable water may be obtained by condensing moisture from the atmosphere in suitable seashore or island areas. Deep, cold, offshore seawater is used as a source of cold and is pumped to condensers set up on shore to intercept the flow of highly humid, tropical, maritime air masses. This air, when cooled, condenses moisture, which is conducted away and stored for use as a water supply. Windmill-driven generators would supply low-cost power for the operation. Side benefits are derived by using the nutritious deep water to support aquiculture in nearby lagoons or to enhance the productivity of the outfall area. Additional benefits are derived from the condenser as an air-conditioning device for nearby residents. The islands of the Caribbean are used as an example of a location in the trade-winds belt where nearly optimum conditions for the operation of this system can be found.

  19. Toward a better understanding of the impact of mass transit air pollutants on human health.

    Science.gov (United States)

    Kim, Ki-Hyun; Kumar, Pawan; Szulejko, Jan E; Adelodun, Adedeji A; Junaid, Muhammad Faisal; Uchimiya, Minori; Chambers, Scott

    2017-05-01

    Globally, modern mass transport systems whether by road, rail, water, or air generate airborne pollutants in both developing and developed nations. Air pollution is the primary human health concern originating from modern transportation, particularly in densely-populated urban areas. This review will specifically focus on the origin and the health impacts of carbonaceous traffic-related air pollutants (TRAP), including particulate matter (PM), volatile organic compounds (VOCs), and elemental carbon (EC). We conclude that the greatest current challenge regarding urban TRAP is understanding and evaluating the human health impacts well enough to set appropriate pollution control measures. Furthermore, we provide a detailed discussion regarding the effects of TRAP on local environments and pedestrian health in low and high traffic-density environments. Copyright © 2017 Elsevier Ltd. All rights reserved.

  20. Relationships between summer air masses and mortality in Seoul: Comparison of weather-type classifications

    Czech Academy of Sciences Publication Activity Database

    Kyselý, Jan; Huth, Radan

    2010-01-01

    Roč. 35, 9-12 (2010), s. 536-543 ISSN 1474-7065 R&D Projects: GA ČR GC205/07/J044 Grant - others: Korea Research Foundation(KR) KRF-2006-C00005 Institutional research plan: CEZ:AV0Z30420517 Keywords : Classification of weather types * Air masses * Biometeorology * Human mortality * East Asia Subject RIV: DG - Athmosphere Sciences, Meteorology Impact factor: 0.917, year: 2010

  1. Spatial variability of hailfalls in France: an analysis of air mass retro-trajectories

    Science.gov (United States)

    Hermida, Lucía; Merino, Andrés; Sánchez, José Luis; Berthet, Claude; Dessens, Jean; López, Laura; Fernández-González, Sergio; Gascón, Estíbaliz; García-Ortega, Eduardo

    2014-05-01

    Hail is the main meteorological risk in south-west France, with the strongest hailfalls being concentrated in just a few days. Specifically, this phenomenon occurs most often and with the greatest severity in the Midi-Pyrénées area. Previous studies have revealed the high spatial variability of hailfall in this part of France, even leading to different characteristics being recorded on hailpads that were relatively close together. For this reason, an analysis of the air mass trajectories was carried out at ground level and at altitude, which subsequently led to the formation of the hail recorded by these hailpads. It is already known that in the study zone, the trajectories of the storms usually stretch for long distances and are oriented towards the east, leading to hailstones with diameters in excess of 3 cm, and without any change in direction above 3 km. We analysed different days with hail precipitation where there was at least one stone with a diameter of 3 cm or larger. Using the simulations from these days, an analysis of the backward trajectories of the air masses was carried out. We used the HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory Model) to determine the origin of the air masses, and tracked them toward each of the hailpads that were hit during the day studied. The height of the final points was the height of the impacted hailpads. Similarly, the backward trajectories for different heights were also established. Finally, the results show how storms that affect neighbouring hailpads come from very different air masses; and provide a deeper understanding of the high variability that affects the characteristics of hailfalls. Acknowledgements The authors would like to thank the Regional Government of Castile-León for its financial support through the project LE220A11-2. This study was supported by the following grants: GRANIMETRO (CGL2010-15930); MICROMETEO (IPT-310000-2010-22).

  2. Mass transfer characteristics of bisporus mushroom ( Agaricus bisporus) slices during convective hot air drying

    Science.gov (United States)

    Ghanbarian, Davoud; Baraani Dastjerdi, Mojtaba; Torki-Harchegani, Mehdi

    2016-05-01

    An accurate understanding of moisture transfer parameters, including moisture diffusivity and moisture transfer coefficient, is essential for efficient mass transfer analysis and to design new dryers or improve existing drying equipments. The main objective of the present study was to carry out an experimental and theoretical investigation of mushroom slices drying and determine the mass transfer characteristics of the samples dried under different conditions. The mushroom slices with two thicknesses of 3 and 5 mm were dried at air temperatures of 40, 50 and 60 °C and air flow rates of 1 and 1.5 m s-1. The Dincer and Dost model was used to determine the moisture transfer parameters and predict the drying curves. It was observed that the entire drying process took place in the falling drying rate period. The obtained lag factor and Biot number indicated that the moisture transfer in the samples was controlled by both internal and external resistance. The effective moisture diffusivity and the moisture transfer coefficient increased with increasing air temperature, air flow rate and samples thickness and varied in the ranges of 6.5175 × 10-10 to 1.6726 × 10-9 m2 s-1 and 2.7715 × 10-7 to 3.5512 × 10-7 m s-1, respectively. The validation of the Dincer and Dost model indicated a good capability of the model to describe the drying curves of the mushroom slices.

  3. Mass concentrations of BTEX inside air environment of buses in Changsha, China

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Xiaokai; Zhang, Guoqiang; Zhang, Quan [College of Civil Engineering, Hunan University, Changsha 410082, Hunan (China); Chen, Hong [College of Environmental Science and Engineering, Hunan University, Changsha 410082, Hunan (China)

    2011-02-15

    In order to estimate the mass concentrations of benzene (B), toluene (T), ethylbenzene (E) and xylenes (X) inside air environment of buses and to analyze the influencing factors of the BTEX pollution levels, 22 public buses were investigated in Changsha, China. The interior air was collected through activated charcoal adsorption tubes and then the air samples were analyzed with thermally desorbed gas chromatograph. The mass concentrations ranged from 21.3 to 106.4 {mu}g/m{sup 3} for benzene, from 53.5 to 266.0 {mu}g/m{sup 3} for toluene, from 19.6 to 95.9 {mu}g/m{sup 3} for ethylbenzene and from 46.9 to 234.8 {mu}g/m{sup 3} for xylenes. Their mean values were 68.7, 179.7, 62.5 and 151.8 {mu}g/m{sup 3}, respectively. The rates of buses tested where the interior concentrations exceeded the limit levels of Chinese Indoor Air Quality Standard were 45.5% for toluene and 13.6% for xylenes. The BTEX levels increased when in-car temperature or relative humidity rose, and decreased when car age or travel distance increased. The BTEX concentrations were higher in leather trims buses than in non-leather trims ones, in air-conditioned buses than in non-air-conditioned ones, and in high-grade buses than in low-grade ones. According to the analysis of multiple linear regression equation, car age and in-car temperature were two most important factors influencing the BTEX pollution levels in the cabins of public buses. (author)

  4. Greenland ice sheet surface mass balance: evaluating simulations and making projections with regional climate models

    Directory of Open Access Journals (Sweden)

    J. G. L. Rae

    2012-11-01

    Full Text Available Four high-resolution regional climate models (RCMs have been set up for the area of Greenland, with the aim of providing future projections of Greenland ice sheet surface mass balance (SMB, and its contribution to sea level rise, with greater accuracy than is possible from coarser-resolution general circulation models (GCMs. This is the first time an intercomparison has been carried out of RCM results for Greenland climate and SMB. Output from RCM simulations for the recent past with the four RCMs is evaluated against available observations. The evaluation highlights the importance of using a detailed snow physics scheme, especially regarding the representations of albedo and meltwater refreezing. Simulations with three of the RCMs for the 21st century using SRES scenario A1B from two GCMs produce trends of between −5.5 and −1.1 Gt yr−2 in SMB (equivalent to +0.015 and +0.003 mm sea level equivalent yr−2, with trends of smaller magnitude for scenario E1, in which emissions are mitigated. Results from one of the RCMs whose present-day simulation is most realistic indicate that an annual mean near-surface air temperature increase over Greenland of ~ 2°C would be required for the mass loss to increase such that it exceeds accumulation, thereby causing the SMB to become negative, which has been suggested as a threshold beyond which the ice sheet would eventually be eliminated.

  5. Radioactive air and surface contamination in Czechia and Slovakia

    International Nuclear Information System (INIS)

    Rumyantsev, V.V.

    1992-01-01

    Data are presented on the radioactive substance effluents into the environment in conditions of NPP normal operation and on the air contamination by 85 Kr due to operation of the European and Soviet plants for reprocessing spent nuclear fuel. Data are given on the dosage of the Czechoslovakia population due to the Chernobyl NPP accident

  6. Effects of mass transfer between Martian satellites on surface geology

    Science.gov (United States)

    2015-12-21

    suspected. Published by Elsevier Inc.1. Introduction Several features about the surface geology on the moons of Mars remain poorly understood. The grooves on...Deimos may have an effect on Phobos’ geology ; we shall attempt to estimate the magnitude of that effect in Section 4. For impacts with Mars, Phobos or...global surface geology , particularly in the 100+ Ma since the last Voltaire-sized impact. Therefore we believe it unlikely that the red veneer of

  7. Mass transfer from smooth alabaster surfaces in turbulent flows

    Science.gov (United States)

    Opdyke, Bradley N.; Gust, Giselher; Ledwell, James R.

    1987-11-01

    The mass transfer velocity for alabaster plates in smooth-wall turbulent flow is found to vary with the friction velocity according to an analytic solution of the advective diffusion equation. Deployment of alabaster plates on the sea floor can perhaps be used to estimate the viscous stress, and transfer velocities for other species.

  8. Processes of Ammonia Air-Surface Exchange in a Fertilized Zea Mays Canopy

    Science.gov (United States)

    Recent incorporation of coupled soil biogeochemical and bi-directional NH3 air-surface exchange algorithms into regional air quality models holds promise for further reducing uncertainty in estimates of NH3 emissions from fertilized soils. While this advancement represents a sig...

  9. AirSWOT Measurements of Water Surface Elevations and Hydraulic Gradients over the Yukon Flats, Alaska

    Science.gov (United States)

    Pitcher, L. H.; Pavelsky, T.; Smith, L. C.; Moller, D.; Altenau, E. H.; Lion, C.; Bertram, M.; Cooley, S. W.

    2017-12-01

    AirSWOT is an airborne, Ka-band synthetic aperture radar interferometer (InSAR) intended to quantify surface water fluxes by mapping water surface elevations (WSE). AirSWOT will also serve as a calibration/validation tool for the Surface Water and Ocean Topography (SWOT) satellite mission (scheduled for launch in 2021). The hydrology objectives for AirSWOT and SWOT are to measure WSE with accuracies sufficient to estimate hydrologic fluxes in lakes, wetlands and rivers. However, current understanding of the performance of these related though not identical instruments when applied to complex river-lake-wetland fluvial environments remains predominantly theoretical. We present AirSWOT data acquired 15-June-2015 over the Yukon Flats, Alaska, USA, together with in situ field surveys, to assess the accuracy of AirSWOT WSE measurements in lakes and rivers. We use these data to demonstrate that AirSWOT can be used to estimate large-scale hydraulic gradients across wetland complexes. Finally, we present key lessons learned from this AirSWOT analysis for consideration in future campaigns, including: maximizing swath overlap for spatial averaging to minimize uncertainty as well as orienting flight paths parallel to river flow directions to reduce along track aircraft drift for neighboring flight paths. We conclude that spatially dense AirSWOT measurements of river and lake WSEs can improve geospatial understanding of surface water hydrology and fluvial processes.

  10. Comparison of mass and energy balances for air blown and thermally ballasted fluidized bed gasifiers

    International Nuclear Information System (INIS)

    Lysenko, Steve; Sadaka, Samy; Brown, Robert C.

    2012-01-01

    The objective of this study was to compare the mass and energy balances for a conventional air blown fluidized bed gasifier and a ballasted fluidized bed gasifier developed at Iowa State University. The ballasted gasifier is an indirectly heated gasifier that uses a single reactor for both combustion and pyrolysis. Heat accumulated in high-temperature phase change material during the combustion phase is released during the pyrolysis phase to generate producer gas. Gas composition, tar and char contents, cold gas efficiency, carbon conversion, and hydrogen yield per unit biomass input were determined as part of these evaluation. During the pyrolysis phase of ballasted gasification, higher volumetric concentrations of hydrogen and methane were obtained than during air blown gasification. Hydrogen yield for ballasted gasification was 14 g kg −1 of biomass, which was about 20% higher than that obtained during air blown gasification. The higher heating value of the producer gas also reached higher levels during the ballasted pyrolysis phase than that of air blown gasification. Heating value for air blown gasification was 5.2 MJ m −3 whereas the heating value for the ballasted pyrolysis phase averaged 5.5 MJ m −3 , reaching a maximum of 8.0 MJ m −3 . The ballasted gasifier was expected to yield producer gas with average heating value as high as 15 MJ m −3 but excessive use of nitrogen to purge and cool the fuel feeder system greatly diluted the producer gas. Relatively simple redesign of the feeder system would greatly reduce the use of purge gas and may increase the heating values to about 17.5 MJ m −3 . Higher char production per kilogram of biomass was associated with the ballasted system, producing 140 g kg −1 of biomass compared to only 53 g kg −1 of biomass during air blown gasification. On the other hand, tar concentrations in the producer gas were 6.0 g m −3 for ballasted gasification compared to 11.7 g m −3 for air blown gasification. On

  11. Dissolution of spherical cap CO2 bubbles attached to flat surfaces in air-saturated water

    Science.gov (United States)

    Peñas, Pablo; Parrales, Miguel A.; Rodriguez-Rodriguez, Javier

    2014-11-01

    Bubbles attached to flat surfaces immersed in quiescent liquid environments often display a spherical cap (SC) shape. Their dissolution is a phenomenon commonly observed experimentally. Modelling these bubbles as fully spherical may lead to an inaccurate estimate of the bubble dissolution rate. We develop a theoretical model for the diffusion-driven dissolution or growth of such multi-component SC gas bubbles under constant pressure and temperature conditions. Provided the contact angle of the bubble with the surface is large, the concentration gradients in the liquid may be approximated as spherically symmetric. The area available for mass transfer depends on the instantaneous bubble contact angle, whose dynamics is computed from the adhesion hysteresis model [Hong et al., Langmuir, vol. 27, 6890-6896 (2011)]. Numerical simulations and experimental measurements on the dissolution of SC CO2 bubbles immersed in air-saturated water support the validity of our model. We verify that contact line pinning slows down the dissolution rate, and the fact that any bubble immersed in a saturated gas-liquid solution eventually attains a final equilibrium size. Funded by the Spanish Ministry of Economy and Competitiveness through Grant DPI2011-28356-C03-0.

  12. Detailed evaluation of the natural circulation mass flow rate of water propelled by using an air injection

    International Nuclear Information System (INIS)

    Park, Rae-Joon; Ha, Kwang-Soon; Kim, Jae-Cheol; Hong, Seong-Wan; Kim, Sang-Baik

    2008-01-01

    One-dimensional (1D) air-water two-phase natural circulation flow in the thermohydraulic evaluation of reactor cooling mechanism by external self-induced flow - one-dimensional' (THERMES-1D) experiment has been verified and evaluated by using the RELAP5/MOD3 computer code. Experimental results on the 1D natural circulation mass flow rate of water propelled by using an air injection have been evaluated in detail. The RELAP5 results have shown that an increase in the air injection rate to 50% of the total heat flux leads to an increase in the water circulation mass flow rate. However, an increase in the air injection rate from 50 to 100% does not affect the water circulation mass flow rate, because of the inlet area condition. As the height increases in the air injection part, the void fraction increases. However, the void fraction in the upper part of the air injector maintains a constant value. An increase in the air injection mass flow rate leads to an increase in the local void fraction, but it has no influence on the local pressure. An increase in the coolant inlet area leads to an increase in the water circulation mass flow rate. However, the water outlet area does not have an influence on the water circulation mass flow rate. As the coolant outlet moves to a lower position, the water circulation mass flow rate decreases. (author)

  13. Numerical simulation of hydrogen-air reacting flows in rectangular channels with catalytic surface reactions

    Science.gov (United States)

    Amano, Ryoichi S.; Abou-Ellail, Mohsen M.; Elhaw, Samer; Saeed Ibrahim, Mohamed

    2013-09-01

    In this work a prediction was numerically modeled for a catalytically stabilized thermal combustion of a lean homogeneous mixture of air and hydrogen. The mixture flows in a narrow rectangular channel lined with a thin coating of platinum catalyst. The solution using an in-house code is based on the steady state partial differential continuity, momentum and energy conservation equations for the mixture and species involved in the reactions. A marching technique is used along the streamwise direction to solve the 2-D plane-symmetric laminar flow of the gas. Two chemical kinetic reaction mechanisms were included; one for the gas phase reactions consisting of 17 elementary reactions; of which 7 are forward-backward reactions while the other mechanism is for the surface reactions—which are the prime mover of the combustion under a lean mixture condition—consisting of 16 elementary reactions. The results were compared with a former congruent experimental work where temperature was measured using thermocouples, while using PLIF laser for measuring water and hydrogen mole fractions. The comparison showed good agreement. More results for the velocities, mole fractions of other species were carried out across the transverse and along the streamwise directions providing a complete picture of overall mechanism—gas and surface—and on the production, consumptions and travel of the different species. The variations of the average OH mole fraction with the streamwise direction showed a sudden increase in the region where the ignition occurred. Also the rate of reactions of the entire surface species were calculated along the streamwise direction and a surface water production flux equation was derived by calculating the law of mass action's constants from the concentrations of hydrogen, oxygen and the rate of formation of water near the surface.

  14. Influence of the convective surface transfer coefficients on the Heat, Air, and Moisture (HAM) building performance

    DEFF Research Database (Denmark)

    Steskens, Paul Wilhelmus Maria Hermanus; Janssen, Hans; Rode, Carsten

    2009-01-01

    Current models to predict heat, air and moisture (HAM) conditions in buildings assume constant boundary conditions for the temperature and relative humidity of the neighbouring air and for the surface heat and moisture transfer coefficients. These assumptions may introduce errors in the predicted...... influence on the predicted hygrothermal conditions at the surface of a building component and on the heat and vapour exchange with the indoor environment....

  15. Correlation and uncertainties evaluation in backscattering of entrance surface air kerma measurements

    Energy Technology Data Exchange (ETDEWEB)

    Teixeira, G.J.; Sousa, C.H.S.; Peixoto, J.G.P., E-mail: gt@ird.gov.br [Instituto de Radioproteção e Dosimetria (IRD/CNEN-RJ), Rio de Janeiro, RJ (Brazil)

    2017-07-01

    The air kerma measurement is important to verify the applied doses in radiodiagnostic. The literature determines some methods to measure the entrance surface air kerma or entrance surface dose but some of this methods may increase the measurement with the backscattering. Were done setups of measurements to do correlations between them. The expanded uncertainty exceeded 5% for measurements with backscattering, reaching 8.36%, while in situations where the backscattering was avoided, the uncertainty was 3.43%. (author)

  16. Origin of polluted air masses in the Alps. An overview and first results for MONARPOP

    International Nuclear Information System (INIS)

    Kaiser, August

    2009-01-01

    The contribution of ZAMG to MONAROP consists of special weather forecasts to control the SOCs sampling procedure and of the analysis of the specific transport processes for SOCs, which is still in progress. In this paper, air pollutant transport into the Alps is demonstrated by examples of inorganic pollutants: Measurements of NO x and ozone provide evidence for air pollutant transport by local wind systems (valley and slope winds), especially at low elevated sites of the Alps. In addition, trajectory analyses for the high elevation sites demonstrate the importance of large scale synoptic air pollutant transport. The effects of these transport processes with different spatial and temporal scales are governed by the physical and chemical properties of the particular pollutant. First results for the high alpine MONARPOP stations show that air masses from east Europe influence mostly Sonnblick (Austria), whereas the influence of the Po basin is strongest at Weissfluhjoch (Switzerland). - Effects of meteorological transport processes on air pollution in the Alps are demonstrated by examples of inorganic pollutants and first conclusions for SOCs are drawn.

  17. Influence of drying air parameters on mass transfer characteristics of apple slices

    Science.gov (United States)

    Beigi, Mohsen

    2016-10-01

    To efficiently design both new drying process and equipment and/or to improve the existing systems, accurate values of mass transfer characteristics are necessary. The present study aimed to investigate the influence of drying air parameters (i.e. temperature, velocity and relative humidity) on effective diffusivity and convective mass transfer coefficient of apple slices. The Dincer and Dost model was used to determine the mass transfer characteristics. The obtained Biot number indicated that the moisture transfer in the apple slices was controlled by both internal and external resistance. The effective diffusivity and mass transfer coefficient values obtained to be in the ranges of 7.13 × 10-11-7.66 × 10-10 and 1.46 × 10-7-3.39 × 10-7 m s-1, respectively and the both of them increased with increasing drying air temperature and velocity, and decreasing relative humidity. The validation of the model showed that the model predicted the experimental drying curves of the samples with a good accuracy.

  18. Validation of AIRS V6 Surface Temperature over Greenland with GCN and NOAA Stations

    Science.gov (United States)

    Lee, Jae N.; Hearty, Thomas; Cullather, Richard; Nowicki, Sophie; Susskind, Joel

    2016-01-01

    This work compares the temporal and spatial characteristics of the AIRSAMSU (Atmospheric Infrared Sounder Advanced Microwave Sounding Unit A) Version 6 and MODIS (Moderate resolution Imaging Spectroradiometer) Collection 5 derived surface temperatures over Greenland. To estimate uncertainties in space-based surface temperature measurements, we re-projected the MODIS Ice Surface Temperature (IST) to 0.5 by 0.5 degree spatial resolution. We also re-gridded AIRS Skin Temperature (Ts) into the same grid but classified with different cloud conditions and surface types. These co-located data sets make intercomparison between the two instruments relatively straightforward. Using this approach, the spatial comparison between the monthly mean AIRS Ts and MODIS IST is in good agreement with RMS 2K for May 2012. This approach also allows the detection of any long-term calibration drift and the careful examination of calibration consistency in the MODIS and AIRS temperature data record. The temporal correlations between temperature data are also compared with those from in-situ measurements from GC-Net (GCN) and NOAA stations. The coherent time series of surface temperature evident in the correlation between AIRS Ts and GCN temperatures suggest that at monthly time scales both observations capture the same climate signal over Greenland. It is also suggested that AIRS surface air temperature (Ta) can be used to estimate the boundary layer inversion.

  19. Relation of air mass history to nucleation events in Po Valley, Italy, using back trajectories analysis

    Directory of Open Access Journals (Sweden)

    L. Sogacheva

    2007-01-01

    Full Text Available In this paper, we study the transport of air masses to San Pietro Capofiume (SPC in Po Valley, Italy, by means of back trajectories analysis. Our main aim is to investigate whether air masses originate over different regions on nucleation event days and on nonevent days, during three years when nucleation events have been continuously recorded at SPC. The results indicate that nucleation events occur frequently in air masses arriving from Central Europe, whereas event frequency is much lower in the air transported from southern directions and from the Atlantic Ocean. We also analyzed the behaviour of meteorological parameters during 96 h transport to SPC, and found that, on average, event trajectories undergo stronger subsidence during the last 12 h before the arrival at SPC than nonevent trajectories. This causes a reversal in the temperature and relative humidity (RH differences between event and nonevent trajectories: between 96 and 12 h back time, temperature is lower and RH is higher for event than nonevent trajectories and between 12 and 0 h vice versa. Boundary layer mixing is stronger along the event trajectories compared to nonevent trajectories. The absolute humidity (AH is similar for the event and nonevent trajectories between about 96 h and about 60 h back time, but after that, the event trajectories AH becomes lower due to stronger rain. We also studied transport of SO2 to SPC, and conclude that although sources in Po Valley most probably dominate the measured concentrations, certain Central and Eastern European sources also make a substantial contribution.

  20. Hot-wire air flow meter for gasoline fuel-injection system. Calculation of air mass in cylinder during transient condition; Gasoline funsha system yo no netsusenshiki kuki ryuryokei. Kato untenji no cylinder juten kukiryo no keisan

    Energy Technology Data Exchange (ETDEWEB)

    Oyama, Y [Hitachi Car Engineering, Ltd., Tokyo (Japan); Nishimura, Y; Osuga, M; Yamauchi, T [Hitachi, Ltd., Tokyo (Japan)

    1997-10-01

    Air flow characteristics of hot-wire air flow meters for gasoline fuel-injection systems with supercharging and exhaust gas recycle during transient conditions were investigated to analyze a simple method for calculating air mass in cylinder. It was clarified that the air mass in cylinder could be calculated by compensating for the change of air mass in intake system by using aerodynamic models of intake system. 3 refs., 6 figs., 1 tab.

  1. Significancy in atomic mass measurements and the topography of the mass-surface

    International Nuclear Information System (INIS)

    Audi, G.

    1991-01-01

    It is discussed how to explore new regions of the chart of the nuclides through masses, and what has to be understood under significant mass measurements. In the exploratory phase of a new region of the chart, a result with almost any accuracy is appropriate. The higher the accuracy is, the better the possibility is to see finer structures. (G.P.) 24 refs.; 10 figs

  2. Multi-pollutant surface objective analyses and mapping of air quality health index over North America.

    Science.gov (United States)

    Robichaud, Alain; Ménard, Richard; Zaïtseva, Yulia; Anselmo, David

    2016-01-01

    Air quality, like weather, can affect everyone, but responses differ depending on the sensitivity and health condition of a given individual. To help protect exposed populations, many countries have put in place real-time air quality nowcasting and forecasting capabilities. We present in this paper an optimal combination of air quality measurements and model outputs and show that it leads to significant improvements in the spatial representativeness of air quality. The product is referred to as multi-pollutant surface objective analyses (MPSOAs). Moreover, based on MPSOA, a geographical mapping of the Canadian Air Quality Health Index (AQHI) is also presented which provides users (policy makers, public, air quality forecasters, and epidemiologists) with a more accurate picture of the health risk anytime and anywhere in Canada and the USA. Since pollutants can also behave as passive atmospheric tracers, they provide information about transport and dispersion and, hence, reveal synoptic and regional meteorological phenomena. MPSOA could also be used to build air pollution climatology, compute local and national trends in air quality, and detect systematic biases in numerical air quality (AQ) models. Finally, initializing AQ models at regular time intervals with MPSOA can produce more accurate air quality forecasts. It is for these reasons that the Canadian Meteorological Centre (CMC) in collaboration with the Air Quality Research Division (AQRD) of Environment Canada has recently implemented MPSOA in their daily operations.

  3. Effect of air gap on uniformity of large-scale surface-wave plasma

    International Nuclear Information System (INIS)

    Lan Chaohui; Hu Xiwei; Jiang Zhonghe; Liu Minghai

    2009-01-01

    The effect of air gap on the uniformity of large-scale surface-wave plasma (SWP) in a rectangular chamber device is studied by using three-dimensional numerical analyses based on the finite difference time-domain (FDTD) approximation to Maxwell's equations and plasma fluid model. The spatial distributions of surface wave excited by slot-antenna array and the plasma parameters such as electron density and temperature are presented. For different air gap thicknesses, the results show that the existence of air gap would severely weaken the excitations of the surface wave and thereby the SWP. Thus the air gap should be eliminated completely in the design of the SWP source, which is opposite to the former research results. (authors)

  4. Numerical simulation for the influence of laser-induced plasmas addition on air mass capture of hypersonic inlet

    Science.gov (United States)

    Zhao, Wei; Dou, Zhiguo; Li, Qian

    2012-03-01

    The theory of laser-induced plasmas addition to hypersonic airflow off a vehicle to increase air mass capture and improve the performance of hypersonic inlets at Mach numbers below the design value is explored. For hypersonic vehicles, when flying at mach numbers lower than the design one, we can increase the mass capture ratio of inlet through laser-induced plasmas injection to the hypersonic flow upstream of cowl lip to form a virtual cowl. Based on the theory, the model of interaction between laser-induced plasmas and hypersonic flow was established. The influence on the effect of increasing mass capture ratio was studied at different positions of laser-induced plasmas region for the external compression hypersonic inlet at Mach 5 while the design value is 6, the power of plasmas was in the range of 1-8mJ. The main results are as follows: 1. the best location of the plasma addition region is near the intersection of the nose shock of the vehicle with the continuation of the cowl line, and slightly below that line. In that case, the shock generated by the heating is close to the shock that is a reflection of the vehicle nose shock off the imaginary solid surface-extension of the cowl. 2. Plasma addition does increase mass capture, and the effect becomes stronger as more energy is added, the peak value appeared when the power of plasma was about 4mJ, when the plasma energy continues to get stronger, the mass capture will decline slowly.

  5. Surface charge accumulation of particles containing radionuclides in open air.

    Science.gov (United States)

    Kim, Yong-Ha; Yiacoumi, Sotira; Tsouris, Costas

    2015-05-01

    Radioactivity can induce charge accumulation on radioactive particles. However, electrostatic interactions caused by radioactivity are typically neglected in transport modeling of radioactive plumes because it is assumed that ionizing radiation leads to charge neutralization. The assumption that electrostatic interactions caused by radioactivity are negligible is evaluated here by examining charge accumulation and neutralization on particles containing radionuclides in open air. A charge-balance model is employed to predict charge accumulation on radioactive particles. It is shown that particles containing short-lived radionuclides can be charged with multiple elementary charges through radioactive decay. The presence of radioactive particles can significantly modify the particle charge distribution in open air and yield an asymmetric bimodal charge distribution, suggesting that strong electrostatic particle interactions may occur during short- and long-range transport of radioactive particles. Possible effects of transported radioactive particles on electrical properties of the local atmosphere are reported. The study offers insight into transport characteristics of airborne radionuclides. Results are useful in atmospheric transport modeling of radioactive plumes. Copyright © 2015 Elsevier Ltd. All rights reserved.

  6. Imperiling urban environment through varying air pollution rein in measures and mass transit policies - a case study of Lahore

    International Nuclear Information System (INIS)

    Aziz, A.

    2015-01-01

    Gargantuan expansion of big cities has increased motor vehicular tremendously. Lahore, a primitive green city is now gripped with swelling motor vehicular air pollution. Mass public transport, a back bone of city transportation network, due to erroneous running significantly contributes toward motor vehicular air pollution. Policy initiatives of the Government to curb motor vehicular air pollution are merely focused upon reduction of air pollution at source by the use of technology and clean fuel programmes. The policies for introduction of mass transit remained imprecise which lead to rise in transportation demand and increase in surfeit emission; Half-baked policies normally stem out to get political popularity which imperils urban environment. The paper highlights inconsistent policy measures and unsound air pollution control strategies adopted in big cities of Pakistan. Furthermore it gives guidance for sustainable mass transit policy measures. (author)

  7. Molecular dynamics simulations of water on a hydrophilic silica surface at high air pressures

    DEFF Research Database (Denmark)

    Zambrano, H.A.; Walther, Jens Honore; Jaffe, R.L.

    2014-01-01

    Wepresent a force field forMolecular Dynamics (MD) simulations ofwater and air in contactwith an amorphous silica surface. We calibrate the interactions of each species present in the systemusing dedicated criteria such as the contact angle of a water droplet on a silica surface, and the solubility...

  8. Research on mass transfer and actual performance of the membrane regeneration air-conditioning system

    International Nuclear Information System (INIS)

    Li, Xiu-Wei; Zhang, Xiao-Song; Chen, Qing

    2015-01-01

    Highlights: • Experimental research has been made on the membrane air-conditioning system. • We develop mass transfer models for the membrane regeneration process. • The paper exposes the actual performance of the system. • Increase of membrane pairs improves the performance. - Abstract: Absorption air-conditioning system has great advantages in energy conservation and environmental protection. To improve the performance of the traditional system, the membrane regeneration absorption system was proposed. Its COP could approach 6 by regenerating absorbent solution with the ion exchange membranes. However, the theoretical conclusion has not been supported by the experiment. This paper presents the experimental research of the membrane regeneration process. It has investigated the mass transfer process, energy efficiency and actual performance under different working conditions. Based on that, a mass transfer model has been developed and the influences of some key parameters have been exposed. It found the regeneration performance is mainly influenced by the current intensity. The calculation results with the model agree well the experimental data. The actual efficiency was lower than 50%, caused by energy loss in heat and electrochemical reactions. The actual COP is between 1 and 3, lower current intensity and more membrane pairs could improve it.

  9. Evolution of charged species in propane/air flames: mass-spectrometric analysis and modelling

    International Nuclear Information System (INIS)

    Rodrigues, J M; Agneray, A; Jaffrezic, X; Bellenoue, M; Labuda, S; Leys, C; Chernukho, A P; Migoun, A N; Cenian, A; Savel'ev, A M; Titova, N S; Starik, A M

    2007-01-01

    Experimental and modelling studies of ion formation during combustion of propane/air mixtures are presented. The positive and negative ions mass/charge spectra in propane/air stoichiometric flame at atmospheric pressure are recorded in the range from 0 to 512 atomic mass units. The C 2 H 3 O + and HCO 2 - ions are found to be the most abundant ionic species in the flame front region. By increasing the distance from the flame front the ion composition changes significantly. In the burnt gas region the H 3 O + , NO + , CO 3 - , HCO 3 - ions are found to be the major charged species. To explain the experimental results the extended kinetic model describing the ion formation in flame and in the extraction system of the mass-spectrometer as well as ion-soot interaction is developed. It is shown that the ionic clusters, which are observed experimentally, form during the adiabatic expansion in the extraction system, and the presence of soot particles may change the total positive and negative ion concentrations in the gas phase

  10. Experimental test of a novel multi-surface trough solar concentrator for air heating

    International Nuclear Information System (INIS)

    Zheng Hongfei; Tao Tao; Ma Ming; Kang Huifang; Su Yuehong

    2012-01-01

    Highlights: ► We made a prototype novel multi-surface trough solar concentrator for air heating. ► Circular and rectangular types of receiver were chosen for air heating in the test. ► The changes of instantaneous system efficiency with different air flow were obtained. ► The system has the advantage of high collection temperature, which can be over 140 °C. ► The average efficiency can exceed 45% at the outlet temperature of above 60 °C. - Abstract: This study presents the experimental test of a novel multi-surface trough solar concentrator for air heating. Three receivers of different air flow channels are individually combined with the solar concentrator. The air outlet temperature and solar irradiance were recorded for different air flow rates under the real weather condition and used to determine the collection efficiency and time constant of the air heater system. The characteristics of the solar air heater with different airflow channels are compared, and the variation of the daily efficiency with the normalized temperature change is also presented. The testing results indicates that the highest temperature of the air heater with a circular glass receiver can be over 140 °C. When the collection temperature is around 60 °C, the collection efficiency can be over 45%. For the rectangular receivers, the system also has a considerable daily efficiency at a larger air flow rate. The air heater based on the novel trough solar concentrator would be suitable for space heating and drying applications.

  11. Community air monitoring for pesticides-part 2: multiresidue determination of pesticides in air by gas chromatography, gas chromatography-mass spectrometry, and liquid chromatography-mass spectrometry.

    Science.gov (United States)

    Hengel, Matt; Lee, P

    2014-03-01

    Two multiresidue methods were developed to determine pesticides in air collected in California. Pesticides were trapped using XAD-4 resin and extracted with ethyl acetate. Based on an analytical method from the University of California Davis Trace Analytical Laboratory, pesticides were detected by analyzing the extract by gas chromatography-mass spectrometry (GC-MS) to determine chlorothalonil, chlorthal-dimethyl, cycloate, dicloran, dicofol, EPTC, ethalfluralin, iprodione, mefenoxam, metolachlor, PCNB, permethrin, pronamide, simazine, trifluralin, and vinclozolin. A GC with a flame photometric detector was used to determine chlorpyrifos, chlorpyrifos oxon, diazinon, diazinon oxon, dimethoate, dimethoate oxon, fonophos, fonophos oxon, malathion, malathion oxon, naled, and oxydemeton. Trapping efficiencies ranged from 78 to 92 % for low level (0.5 μg) and 37-104 % for high level (50 and 100 μg) recoveries. Little to no degradation of compounds occurred over 31 days; recoveries ranged from 78 to 113 %. In the California Department of Food and Agriculture (CDFA) method, pesticides were detected by analyzing the extract by GC-MS to determine chlorothalonil, chlorpyrifos, cypermethrin, dichlorvos, dicofol, endosulfan 1, endosulfan sulfate, oxyfluorfen, permethrin, propargite, and trifluralin. A liquid chromatograph coupled to a MS was used to determine azinphos-methyl, chloropyrifos oxon, DEF, diazinon, diazinon oxon, dimethoate, dimethoate oxon, diuron, EPTC, malathion, malathion oxon, metolachlor, molinate, norflurazon, oryzalin, phosmet, propanil, simazine and thiobencarb. Trapping efficiencies for compounds determined by the CDFA method ranged from 10 to 113, 22 to 114, and 56 to 132 % for 10, 5, and 2 μg spikes, respectively. Storage tests yielded 70-170 % recovery for up to 28 days. These multiresidue methods represent flexible, sensitive, accurate, and cost-effective ways to determine residues of various pesticides in ambient air.

  12. Air-mass flux measurement system using Doppler-shifted filtered Rayleigh scattering

    Science.gov (United States)

    Shirley, John A.; Winter, Michael

    1993-01-01

    An optical system has been investigated to measure mass flux distributions in the inlet of a high speed air-breathing propulsion system. Rayleigh scattered light from air is proportional to the number density of molecules and hence can be used to ascertain the gas density in a calibrated system. Velocity field measurements are achieved by spectrally filtering the elastically-scattered Doppler-shifted light with an absorbing molecular filter. A novel anamorphic optical collection system is used which allows optical rays from different scattering angles, that have different Doppler shifts, to be recorded separately. This is shown to obviate the need to tune the laser through the absorption to determine velocities, while retaining the ability to make spatially-resolved measurements along a line. By properly selecting the laser tuning and filter parameters, simultaneous density measurements can be made. These properties are discussed in the paper and experiments demonstrating the velocimetry capability are described.

  13. Electric wind produced by a surface dielectric barrier discharge operating in air at different pressures: aeronautical control insights

    International Nuclear Information System (INIS)

    Benard, N; Balcon, N; Moreau, E

    2008-01-01

    The effects of the ambient air pressure level on the electric wind produced by a single dielectric barrier discharge (DBD) have been investigated by Pitot velocity measurements. Pressures from 1 down to 0.2 atm were tested with a 32 kV p-p 1 kHz excitation. This preliminary study confirms the effectiveness of surface DBD at low pressure. Indeed, the induced velocity is strongly dependent on the ambient air pressure level. Quite surprisingly the produced airflow presents a local maximum at 0.6 atm. The measured velocities at 1 atm and 0.2 atm are 2.5 m s -1 and 3 m s -1 , respectively while 3.5 m s -1 is reached at 0.6 atm. The position of the maximal velocity always coincides with the plasma extension. Mass flow rate calculations indicate that the DBD is effective in real flight pressure conditions. (fast track communication)

  14. Native Liquid Extraction Surface Analysis Mass Spectrometry: Analysis of Noncovalent Protein Complexes Directly from Dried Substrates

    Science.gov (United States)

    Martin, Nicholas J.; Griffiths, Rian L.; Edwards, Rebecca L.; Cooper, Helen J.

    2015-08-01

    Liquid extraction surface analysis (LESA) mass spectrometry is a promising tool for the analysis of intact proteins from biological substrates. Here, we demonstrate native LESA mass spectrometry of noncovalent protein complexes of myoglobin and hemoglobin from a range of surfaces. Holomyoglobin, in which apomyoglobin is noncovalently bound to the prosthetic heme group, was observed following LESA mass spectrometry of myoglobin dried onto glass and polyvinylidene fluoride surfaces. Tetrameric hemoglobin [(αβ)2 4H] was observed following LESA mass spectrometry of hemoglobin dried onto glass and polyvinylidene fluoride (PVDF) surfaces, and from dried blood spots (DBS) on filter paper. Heme-bound dimers and monomers were also observed. The `contact' LESA approach was particularly suitable for the analysis of hemoglobin tetramers from DBS.

  15. Removal of PCB from indoor air and surface materials by introduction of additional sorbing materials

    DEFF Research Database (Denmark)

    Gunnarsen, Lars Bo; Lyng, Nadja; Kolarik, Barbara

    2017-01-01

    Alleviation of indoor PCB contamination is extremely expensive because PCB from old primary sources has redistributed to most other surfaces over time. This study investigates the introduction of new removable sorbing materials as a method instantly lowering the concentration of PCB in indoor air...... and slowly decontaminating old surface materials. In three bedrooms of a contaminated apartment respectively new painted gypsum boards, sheets of flexible polyurethane foam and activated carbon fabric were introduced. The PCB concentrations in room air were monitored before the intervention and several times...... during the following 10 months. The PCB concentrations in the old surface materials as well as the new materials were also measured. An immediate reduction of PCB concentration in indoor air, a gradual increase of PCB in new material and as well a gradual reduction in old surface materials were...

  16. Air and surface contamination patterns of meticillin-resistant Staphylococcus aureus on eight acute hospital wards.

    Science.gov (United States)

    Creamer, E; Shore, A C; Deasy, E C; Galvin, S; Dolan, A; Walley, N; McHugh, S; Fitzgerald-Hughes, D; Sullivan, D J; Cunney, R; Coleman, D C; Humphreys, H

    2014-03-01

    Meticillin-resistant Staphylococcus aureus (MRSA) can be recovered from hospital air and from environmental surfaces. This poses a potential risk of transmission to patients. To investigate associations between MRSA isolates recovered from air and environmental surfaces with those from patients when undertaking extensive patient and environmental sampling. This was a prospective observational study of patients and their environment in eight wards of a 700-bed tertiary care hospital during 2010 and 2011. Sampling of patients, air and surfaces was carried out on all ward bays, with more extended environmental sampling in ward high-dependency bays and at particular times of the day. The genetic relatedness of isolates was determined by DNA microarray profiling and spa typing. MRSA was recovered from 30/706 (4.3%) patients and from 19/132 (14.4%) air samples. On 9/132 (6.8%) occasions both patient and air samples yielded MRSA. In 32 high-dependency bays, MRSA was recovered from 12/161 (7.4%) patients, 8/32 (25%) air samples, and 21/644 (3.3%) environmental surface samples. On 10/132 (7.6%) occasions, MRSA was isolated from air in the absence of MRSA-positive patients. Patient demographic data combined with spa typing and DNA microarray profiling revealed four likely transmission clusters, where patient and environmental isolates were deemed to be very closely related. Air sampling yielded MRSA on frequent occasions, especially in high-dependency bays. Environmental and air sampling combined with patient demographic data, spa typing and DNA microarray profiling indicated the presence of clusters that were not otherwise apparent. Copyright © 2014 The Healthcare Infection Society. Published by Elsevier Ltd. All rights reserved.

  17. Radon derived air mass fetch regions during the ACE-Asia campaign

    International Nuclear Information System (INIS)

    Chambers, S.; Zahorowski, W.; Werczynski, S.; Wang, T.; Poon, S.; Kim, J.; Oh, S.-N.; Knag, H.; Uematsu, M.; Matsumoto, K.

    2003-01-01

    Seasonal variations in fetch regions for air masses exhibiting the greatest and least terrestrial influence at three sites in East Asia are discussed. Results are based on the first year of hourly atmospheric radon concentration observations made as part of the Asian Aerosol Characterisation Experiment (ACE-Asia). Fetch regions for Asian continental outflow to the Pacific Basin within the boundary layer are shown to be distinct from corresponding tropospheric outflow events. Analysis of the hourly radon time series in conjunction with back trajectory analysis indicates the presence of a large localised radon source in south eastern China

  18. Source attribution of Bornean air masses by back trajectory analysis during the OP3 project

    Directory of Open Access Journals (Sweden)

    N. H. Robinson

    2011-09-01

    Full Text Available Atmospheric composition affects the radiative balance of the Earth through the creation of greenhouse gases and the formation of aerosols. The latter interact with incoming solar radiation, both directly and indirectly through their effects on cloud formation and lifetime. The tropics have a major influence on incoming sunlight however the tropical atmosphere is poorly characterised, especially outside Amazonia. The origins of air masses influencing a measurement site in a protected rainforest in Borneo, South East Asia, were assessed and the likely sources of a range of trace gases and particles were determined. This was conducted by interpreting in situ measurements made at the site in the context of ECMWF backwards air mass trajectories. Two different but complementary methods were employed to interpret the data: comparison of periods classified by cluster analysis of trajectories, and inspection of the dependence of mean measured values on geographical history of trajectories. Sources of aerosol particles, carbon monoxide and halocarbons were assessed. The likely source influences include: terrestrial organic biogenic emissions; long range transport of anthropogenic emissions; biomass burning; sulphurous emissions from marine phytoplankton, with a possible contribution from volcanoes; marine production of inorganic mineral aerosol; and marine production of halocarbons. Aerosol sub- and super-saturated water affinity was found to be dependent on source (and therefore composition, with more hygroscopic aerosol and higher numbers of cloud condensation nuclei measured in air masses of marine origin. The prevailing sector during the majority of measurements was south-easterly, which is from the direction of the coast closest to the site, with a significant influence inland from the south-west. This analysis shows that marine and terrestrial air masses have different dominant chemical sources. Comparison with the AMAZE-08 project in the Amazon

  19. Air-side performance of a micro-channel heat exchanger in wet surface conditions

    Directory of Open Access Journals (Sweden)

    Srisomba Raviwat

    2017-01-01

    Full Text Available The effects of operating conditions on the air-side heat transfer, and pressure drop of a micro-channel heat exchanger under wet surface conditions were studied experimentally. The test section was an aluminum micro-channel heat exchanger, consisting of a multi-louvered fin and multi-port mini-channels. Experiments were conducted to study the effects of inlet relative humidity, air frontal velocity, air inlet temperature, and refrigerant temperature on air-side performance. The experimental data were analyzed using the mean enthalpy difference method. The test run was performed at relative air humidities ranging between 45% and 80%; air inlet temperature ranges of 27, 30, and 33°C; refrigerant-saturated temperatures ranging from 18 to 22°C; and Reynolds numbers between 128 and 166. The results show that the inlet relative humidity, air inlet temperature, and the refrigerant temperature had significant effects on heat transfer performance and air-side pressure drop. The heat transfer coefficient and pressure drop for the micro-channel heat exchanger under wet surface conditions are proposed in terms of the Colburn j factor and Fanning f factor.

  20. Analysis of the lipidated recombinant outer surface protein A from Borrelia burgdorferi by mass spectrometry

    NARCIS (Netherlands)

    Bouchon, B.; Klein, Michele; Bischoff, Rainer; Van Dorsselaer, A.; Roitsch, C.

    1997-01-01

    The outer surface protein A, OspA, from the spirochete Borrelia burgdorferi is a lipoprotein of 25 kDa. The recombinant OspA (rOspA) expressed in Escherichia coli has been purified and analyzed by electrospray mass spectrometry (ESMS). A heterogenous spectrum gave a measured mass of 28,462 +/- 9 Da

  1. The pattern of anthropogenic signal emergence in Greenland Ice Sheet surface mass balance

    NARCIS (Netherlands)

    Fyke, J.G.; Vizcaino, M.; Lipscomb, W.H.

    2014-01-01

    Surface mass balance (SMB) trends influence observed Greenland Ice Sheet (GrIS) mass loss, but the component of these trends related to anthropogenic forcing is unclear. Here we study the simulated spatial pattern of emergence of an anthropogenically derived GrIS SMB signal between 1850 and 2100

  2. The Role of the North Atlantic Oscillation (NAO) on Recent Greenland Surface Mass Loss and Mass Partitioning

    Science.gov (United States)

    Tedesco, M.; Alexander, P.; Porter, D. F.; Fettweis, X.; Luthcke, S. B.; Mote, T. L.; Rennermalm, A.; Hanna, E.

    2017-12-01

    Despite recent changes in Greenland surface mass losses and atmospheric circulation over the Arctic, little attention has been given to the potential role of large-scale atmospheric processes on the spatial and temporal variability of mass loss and partitioning of the GrIS mass loss. Using a combination of satellite gravimetry measurements, outputs of the MAR regional climate model and reanalysis data, we show that changes in atmospheric patterns since 2013 over the North Atlantic region of the Arctic (NAA) modulate total mass loss trends over Greenland together with the spatial and temporal distribution of mass loss partitioning. For example, during the 2002 - 2012 period, melting persistently increased, especially along the west coast, as a consequence of increased insulation and negative NAO conditions characterizing that period. Starting in 2013, runoff along the west coast decreased while snowfall increased substantially, when NAO turned to a more neutral/positive state. Modeled surface mass balance terms since 1950 indicate that part of the GRACE-period, specifically the period between 2002 and 2012, was exceptional in terms of snowfall over the east and northeast regions. During that period snowfall trend decreased to almost 0 Gt/yr from a long-term increasing trend, which presumed again in 2013. To identify the potential impact of atmospheric patterns on mass balance and its partitioning, we studied the spatial and temporal correlations between NAO and snowfall/runoff. Our results indicate that the correlation between summer snowfall and NAO is not stable during the 1950 - 2015 period. We further looked at changes in patterns of circulation using self organizing maps (SOMs) to identify the atmospheric patterns characterizing snowfall during different periods. We discuss potential implications for past changes and future GCM and RCM simulations.

  3. Influence of Persistent Wind Scour on the Surface Mass Balance of Antarctica

    Science.gov (United States)

    Das, Indrani; Bell, Robin E.; Scambos, Ted A.; Wolovick, Michael; Creyts, Timothy T.; Studinger, Michael; Fearson, Nicholas; Nicolas, Julien P.; Lenaerts, Jan T. M.; vandenBroeke, Michiel R.

    2013-01-01

    Accurate quantification of surface snow accumulation over Antarctica is a key constraint for estimates of the Antarctic mass balance, as well as climatic interpretations of ice-core records. Over Antarctica, near-surface winds accelerate down relatively steep surface slopes, eroding and sublimating the snow. This wind scour results in numerous localized regions (Antarctica. The scour zones are persistent because they are controlled by bedrock topography. On the basis of our Dome A observations, we develop an empirical model to predict wind-scour zones across the Antarctic continent and find that these zones are predominantly located in East Antarctica. We estimate that approx. 2.7-6.6% of the surface area of Antarctica has persistent negative net accumulation due to wind scour, which suggests that, across the continent, the snow mass input is overestimated by 11-36.5 Gt /yr in present surface-mass-balance calculations.

  4. Exceptional Air Mass Transport and Dynamical Drivers of an Extreme Wintertime Arctic Warm Event

    Science.gov (United States)

    Binder, Hanin; Boettcher, Maxi; Grams, Christian M.; Joos, Hanna; Pfahl, Stephan; Wernli, Heini

    2017-12-01

    At the turn of the years 2015/2016, maximum surface temperature in the Arctic reached record-high values, exceeding the melting point, which led to a strong reduction of the Arctic sea ice extent in the middle of the cold season. Here we show, using a Lagrangian method, that a combination of very different airstreams contributed to this event: (i) warm low-level air of subtropical origin, (ii) initially cold low-level air of polar origin heated by surface fluxes, and (iii) strongly descending air heated by adiabatic compression. The poleward transport of these warm airstreams occurred along an intense low-level jet between a series of cyclones and a quasi-stationary anticyclone. The complex 3-D configuration that enabled this transport was facilitated by continuous warm conveyor belt ascent into the upper part of the anticyclone. This study emphasizes the combined role of multiple transport processes and transient synoptic-scale dynamics for establishing an extreme Arctic warm event.

  5. Liquid extraction surface analysis (LESA) of food surfaces employing chip-based nano-electrospray mass spectrometry.

    Science.gov (United States)

    Eikel, Daniel; Henion, Jack

    2011-08-30

    An automated surface-sampling technique called liquid extraction surface analysis (LESA), coupled with infusion nano-electrospray high-resolution mass spectrometry and tandem mass spectrometry (MS/MS), is described and applied to the qualitative determination of surface chemical residues resulting from the artificial spraying of selected fresh fruits and vegetables with representative pesticides. Each of the targeted pesticides was readily detected with both high-resolution and full-scan collision-induced dissociation (CID) mass spectra. In the case of simazine and sevin, a mass resolution of 100,000 was insufficient to distinguish the isobaric protonated molecules for these compounds. When the surface of a spinach leaf was analyzed by LESA, trace levels of diazinon were readily detected on the spinach purchased directly from a supermarket before they were sprayed with the five-pesticide mixture. A 30 s rinse under hot running tap water appeared to quantitatively remove all remaining residues of this pesticide. Diazinon was readily detected by LESA analysis on the skin of the artificially sprayed spinach. Finally, incurred pyrimethanil at a level of 169 ppb in a batch slurry of homogenized apples was analyzed by LESA and this pesticide was readily detected by both high-resolution mass spectrometry and full-scan CID mass spectrometry, thus showing that pesticides may also be detected in whole fruit homogenized samples. This report shows that representative pesticides on fruit and vegetable surfaces present at levels 20-fold below generally allowed EPA tolerance levels are readily detected and confirmed by the title technologies making LESA-MS as interesting screening method for food safety purposes. Copyright © 2011 John Wiley & Sons, Ltd.

  6. Modelling the climate and surface mass balance of polar ice sheets using RACMO2 - Part 2: Antarctica (1979-2016)

    Science.gov (United States)

    Melchior van Wessem, Jan; van de Berg, Willem Jan; Noël, Brice P. Y.; van Meijgaard, Erik; Amory, Charles; Birnbaum, Gerit; Jakobs, Constantijn L.; Krüger, Konstantin; Lenaerts, Jan T. M.; Lhermitte, Stef; Ligtenberg, Stefan R. M.; Medley, Brooke; Reijmer, Carleen H.; van Tricht, Kristof; Trusel, Luke D.; van Ulft, Lambertus H.; Wouters, Bert; Wuite, Jan; van den Broeke, Michiel R.

    2018-04-01

    We evaluate modelled Antarctic ice sheet (AIS) near-surface climate, surface mass balance (SMB) and surface energy balance (SEB) from the updated polar version of the regional atmospheric climate model, RACMO2 (1979-2016). The updated model, referred to as RACMO2.3p2, incorporates upper-air relaxation, a revised topography, tuned parameters in the cloud scheme to generate more precipitation towards the AIS interior and modified snow properties reducing drifting snow sublimation and increasing surface snowmelt. Comparisons of RACMO2 model output with several independent observational data show that the existing biases in AIS temperature, radiative fluxes and SMB components are further reduced with respect to the previous model version. The model-integrated annual average SMB for the ice sheet including ice shelves (minus the Antarctic Peninsula, AP) now amounts to 2229 Gt y-1, with an interannual variability of 109 Gt y-1. The largest improvement is found in modelled surface snowmelt, which now compares well with satellite and weather station observations. For the high-resolution ( ˜ 5.5 km) AP simulation, results remain comparable to earlier studies. The updated model provides a new, high-resolution data set of the contemporary near-surface climate and SMB of the AIS; this model version will be used for future climate scenario projections in a forthcoming study.

  7. An anthropometric model to estimate neonatal fat mass using air displacement plethysmography

    Directory of Open Access Journals (Sweden)

    Deierlein Andrea L

    2012-03-01

    Full Text Available Abstract Background Current validated neonatal body composition methods are limited/impractical for use outside of a clinical setting because they are labor intensive, time consuming, and require expensive equipment. The purpose of this study was to develop an anthropometric model to estimate neonatal fat mass (kg using an air displacement plethysmography (PEA POD® Infant Body Composition System as the criterion. Methods A total of 128 healthy term infants, 60 females and 68 males, from a multiethnic cohort were included in the analyses. Gender, race/ethnicity, gestational age, age (in days, anthropometric measurements of weight, length, abdominal circumference, skin-fold thicknesses (triceps, biceps, sub scapular, and thigh, and body composition by PEA POD® were collected within 1-3 days of birth. Backward stepwise linear regression was used to determine the model that best predicted neonatal fat mass. Results The statistical model that best predicted neonatal fat mass (kg was: -0.012 -0.064*gender + 0.024*day of measurement post-delivery -0.150*weight (kg + 0.055*weight (kg2 + 0.046*ethnicity + 0.020*sum of three skin-fold thicknesses (triceps, sub scapular, and thigh; R2 = 0.81, MSE = 0.08 kg. Conclusions Our anthropometric model explained 81% of the variance in neonatal fat mass. Future studies with a greater variety of neonatal anthropometric measurements may provide equations that explain more of the variance.

  8. Analysis of volatile compounds by open-air ionization mass spectrometry.

    Science.gov (United States)

    Meher, Anil Kumar; Chen, Yu-Chie

    2017-05-08

    This study demonstrates a simple method for rapid and in situ identification of volatile and endogenous compounds in culinary spice samples through mass spectrometry (MS). This method only requires a holder for solid spice sample (2-3 mm) that is placed close to a mass spectrometer inlet, which is applied with a high voltage. Volatile species responsible for the aroma of the spice samples can be readily detected by the mass spectrometer. Sample pretreatment is not required prior to MS analysis, and no solvent was used during MS analysis. The high voltage applied to the inlet of the mass spectrometer induces the ionization of volatile compounds released from the solid spice samples. Furthermore, moisture in the air also contributes to the ionization of volatile compounds. Dried spices including cinnamon and cloves are used as the model sample to demonstrate this straightforward MS analysis, which can be completed within few seconds. Furthermore, we also demonstrate the suitability of the current method for rapid screening of cinnamon quality through detection of the presence of a hepatotoxic agent, i.e. coumarin. Copyright © 2017 Elsevier B.V. All rights reserved.

  9. Estimating surface solar radiation from upper-air humidity

    Energy Technology Data Exchange (ETDEWEB)

    Kun Yang [Telecommunications Advancement Organization of Japan, Tokyo (Japan); Koike, Toshio [University of Tokyo (Japan). Dept. of Civil Engineering

    2002-07-01

    A numerical model is developed to estimate global solar irradiance from upper-air humidity. In this model, solar radiation under clear skies is calculated through a simple model with radiation-damping processes under consideration. A sky clearness indicator is parameterized from relative humidity profiles within three atmospheric sublayers, and the indicator is used to connect global solar radiation under clear skies and that under cloudy skies. Model inter-comparisons at 18 sites in Japan suggest (1) global solar radiation strongly depends on the sky clearness indicator, (2) the new model generally gives better estimation to hourly-mean solar irradiance than the other three methods used in numerical weather predictions, and (3) the new model may be applied to estimate long-term solar radiation. In addition, a study at one site in the Tibetan Plateau shows vigorous convective activities in the region may cause some uncertainties to radiation estimations due to the small-scale and short life of convective systems. (author)

  10. Air-sea fluxes and satellite-based estimation of water masses formation

    Science.gov (United States)

    Sabia, Roberto; Klockmann, Marlene; Fernandez-Prieto, Diego; Donlon, Craig

    2015-04-01

    Recent work linking satellite-based measurements of sea surface salinity (SSS) and sea surface temperature (SST) with traditional physical oceanography has demonstrated the capability of generating routinely satellite-derived surface T-S diagrams [1] and analyze the distribution/dynamics of SSS and its relative surface density with respect to in-situ measurements. Even more recently [2,3], this framework has been extended by exploiting these T-S diagrams as a diagnostic tool to derive water masses formation rates and areas. A water mass describes a water body with physical properties distinct from the surrounding water, formed at the ocean surface under specific conditions which determine its temperature and salinity. The SST and SSS (and thus also density) at the ocean surface are largely determined by fluxes of heat and freshwater. The surface density flux is a function of the latter two and describes the change of the density of seawater at the surface. To obtain observations of water mass formation is of great interest, since they serve as indirect observations of the thermo-haline circulation. The SSS data which has become available through the SMOS [4] and Aquarius [5] satellite missions will provide the possibility of studying also the effect of temporally-varying SSS fields on water mass formation. In the present study, the formation of water masses as a function of SST and SSS is derived from the surface density flux by integrating the latter over a specific area and time period in bins of SST and SSS and then taking the derivative of the total density flux with respect to density. This study presents a test case using SMOS SSS, OSTIA SST, as well as Argo ISAS SST and SSS for comparison, heat fluxes from the NOCS Surface Flux Data Set v2.0, OAFlux evaporation and CMORPH precipitation. The study area, initially referred to the North Atlantic, is extended over two additional ocean basins and the study period covers the 2011-2012 timeframe. Yearly, seasonal

  11. Carbapenem-Resistant Acinetobacter baumannii: Concomitant Contamination of Air and Environmental Surfaces.

    Science.gov (United States)

    Shimose, Luis A; Masuda, Eriko; Sfeir, Maroun; Berbel Caban, Ana; Bueno, Maria X; dePascale, Dennise; Spychala, Caressa N; Cleary, Timothy; Namias, Nicholas; Kett, Daniel H; Doi, Yohei; Munoz-Price, L Silvia

    2016-07-01

    OBJECTIVE To concomitantly determine the differential degrees of air and environmental contamination by Acinetobacter baumannii based on anatomic source of colonization and type of ICU layout (single-occupancy vs open layout). DESIGN Longitudinal prospective surveillance study of air and environmental surfaces in patient rooms. SETTING A 1,500-bed public teaching hospital in Miami, Florida. PATIENTS Consecutive A. baumannii-colonized patients admitted to our ICUs between October 2013 and February 2014. METHODS Air and environmental surfaces of the rooms of A. baumannii-colonized patients were sampled daily for up to 10 days. Pulsed-field gel electrophoresis (PFGE) was used to type and match the matching air, environmental, and clinical A. baumannii isolates. RESULTS A total of 25 A. baumannii-colonized patients were identified during the study period; 17 were colonized in the respiratory tract and 8 were colonized in the rectum. In rooms with rectally colonized patients, 38.3% of air samples were positive for A. baumannii; in rooms of patients with respiratory colonization, 13.1% of air samples were positive (P=.0001). In rooms with rectally colonized patients, 15.5% of environmental samples were positive for A. baumannii; in rooms of patients with respiratory colonization, 9.5% of environmental samples were positive (P=.02). The rates of air contamination in the open-layout and single-occupancy ICUs were 17.9% and 21.8%, respectively (P=.5). Environmental surfaces were positive in 9.5% of instances in open-layout ICUs versus 13.4% in single-occupancy ICUs (P=.09). CONCLUSIONS Air and environmental surface contaminations were significantly greater among rectally colonized patients; however, ICU layout did not influence the rate of contamination. Infect Control Hosp Epidemiol 2016;37:777-781.

  12. The contribution to surface dose form air scatter in mega voltage photon beams

    International Nuclear Information System (INIS)

    Carolan, M.G.; Butson, M.; Metcalfe, P.

    1996-01-01

    Full text: The minimisation of surface dose is an important requirement in radiotherapy in order to avoid undesirable skin reactions. For this reason significant effort has been expended to avoid and understand photon and electron scatter in the heads of linear accelerators which may contribute to surface dose. In this study we have examined the contribution to surface dose which arises due to scatter in the air above the patient. Experimental investigations of air contributions are difficult to design and execute. Therefore we have used Monte Carlo calculations to determine the effect that the presence of air has on surface dose. Methods: The Los Alamos Monte Carlo Neutron and Photon transport code, MCNP4A which incorporates the ETRAN electron transport code from the Integrated TIGER Series of codes was used for our simulations. The geometry used in the model was a 30 cm cube of water. The dose was tallied in cylindrical elements of 7 cm diameter along the axis of the photon beam. For the first millimetre along the beam axis in the phantom, the dose was determined at 0.1 mm increments in 0.1 mm thick volumes. For depths between 1.0 mm and 15.0 mm the dose was determined every 1 mm in 1 mm cylindrical volumes. This yields a depth dose profile with fine spatial resolution near the phantom surface. Dose was also tallied at depths of 5.0, 10.0, 15.0 and 20.0 cm. The simulations were done assuming a 6 MV photon source with a diameter of 1.5 cm, a gaussian intensity profile and a photon energy spectrum based on Mohan et al. (Med. Phys. 12 (1985) 592). No accelerator head geometry was modelled. The field size was defined by virtual collimators which were simply thin regions of zero photon importance and therefore do not contribute to photon or electron scatter. All simulations were run for sufficient particle histories (∼2x10 7 - 5x10 7 source photons) to give statistical uncertainties of ≤ 10% and in most cases ≤ 5%. Fields of size 10, 15, 20 and 25 cm were used

  13. Mathematical estimation of the level of microbial contamination on spacecraft surfaces by volumetric air sampling

    Science.gov (United States)

    Oxborrow, G. S.; Roark, A. L.; Fields, N. D.; Puleo, J. R.

    1974-01-01

    Microbiological sampling methods presently used for enumeration of microorganisms on spacecraft surfaces require contact with easily damaged components. Estimation of viable particles on surfaces using air sampling methods in conjunction with a mathematical model would be desirable. Parameters necessary for the mathematical model are the effect of angled surfaces on viable particle collection and the number of viable cells per viable particle. Deposition of viable particles on angled surfaces closely followed a cosine function, and the number of viable cells per viable particle was consistent with a Poisson distribution. Other parameters considered by the mathematical model included deposition rate and fractional removal per unit time. A close nonlinear correlation between volumetric air sampling and airborne fallout on surfaces was established with all fallout data points falling within the 95% confidence limits as determined by the mathematical model.

  14. Molecular Dynamics Simulation of Water Nanodroplets on Silica Surfaces at High Air Pressures

    DEFF Research Database (Denmark)

    Zambrano, Harvey A; Jaffe, Richard Lawrence; Walther, Jens Honore

    2010-01-01

    e.g., nanobubbles. In the present work we study the role of air on the wetting of hydrophilic systems. We conduct molecular dynamics simulations of a water nanodroplet on an amorphous silica surface at different air pressures. The interaction potentials describing the silica, water, and air......Silicon dioxides-water systems are abundant in nature and play fundamental roles in a diversity of novel science and engineering applications. Although extensive research has been devoted to study the nature of the interaction between silica and water a complete understanding of the system has...... perform extensive simulations of the water- air equilibrium and calibrate the water-air interaction to match the experimental solubility of N2 and O2 in water. For the silica-water system we calibrate the water-silica interaction to match the experimental contact angle of 27º. We subsequently study...

  15. Analysis of 210Pb and 210Po concentrations in surface air by an α spectrometric method

    International Nuclear Information System (INIS)

    Winkler, R.; Hoetzl, H.; Chatterjee, B.

    1981-01-01

    A method is presented for determining the concentrations of airborne 210 Pb and 210 Po. The method employs α spectrometry to measure the count rate of 210 Po present on an electrostatic filter sample at two post-sampling times. The individual air concentrations of 210 Po and 210 Pb can be calculated from equations given. Sensitivity of the procedure is about 0.2 fCi 210 Po per m 3 of air. The method was applied to the study of long-term variations and frequency distributions of 210 Po and 210 Pb concentrations in surface air at a nonpolluted location about 10 km outside of Munich, F.R.G., from 1976 through 1979. During this period the average concentration levels were found to be 14.2 fCi 210 Pb per m 3 of air and 0.77 fCi 210 Po per m 3 of air, respectively. (author)

  16. Differential optical absorption spectroscopy (DOAS and air mass factor concept for a multiply scattering vertically inhomogeneous medium: theoretical consideration

    Directory of Open Access Journals (Sweden)

    V. V. Rozanov

    2010-06-01

    Full Text Available The Differential Optical Absorption Spectroscopy (DOAS technique is widely used to retrieve amounts of atmospheric species from measurements of the direct solar light transmitted through the Earth's atmosphere as well as of the solar light scattered in the atmosphere or reflected from the Earth's surface. For the transmitted direct solar light the theoretical basis of the DOAS technique represented by the Beer-Lambert law is well studied. In contrast, scarcely investigated is the theoretical basis and validity range of the DOAS method for those cases where the contribution of the multiple scattering processes is not negligible. Our study is intended to fill this gap by means of a theoretical investigation of the applicability of the DOAS technique for the retrieval of amounts of atmospheric species from observations of the scattered solar light with a non-negligible contribution of the multiple scattering.

    Starting from the expansion of the intensity logarithm in the functional Taylor series we formulate the general form of the DOAS equation. The thereby introduced variational derivative of the intensity logarithm with respect to the variation of the gaseous absorption coefficient, which is often referred to as the weighting function, is demonstrated to be closely related to the air mass factor. Employing some approximations we show that the general DOAS equation can be rewritten in the form of the weighting function (WFDOAS, the modified (MDOAS, and the standard DOAS equations. For each of these forms a specific equation for the air mass factor follows which, in general, is not suitable for other forms of the DOAS equation. Furthermore, the validity range of the standard DOAS equation is quantitatively investigated using a suggested criterion of a weak absorption.

    The results presented in this study are intended to provide a basis for a better understanding of the applicability range of different forms of the DOAS equation as

  17. Numerical investigation of mist/air impingement cooling on ribbed blade leading-edge surface.

    Science.gov (United States)

    Bian, Qingfei; Wang, Jin; Chen, Yi-Tung; Wang, Qiuwang; Zeng, Min

    2017-12-01

    The working gas turbine blades are exposed to the environment of high temperature, especially in the leading-edge region. The mist/air two-phase impingement cooling has been adopted to enhance the heat transfer on blade surfaces and investigate the leading-edge cooling effectiveness. An Euler-Lagrange particle tracking method is used to simulate the two-phase impingement cooling on the blade leading-edge. The mesh dependency test has been carried out and the numerical method is validated based on the available experimental data of mist/air cooling with jet impingement on a concave surface. The cooling effectiveness on three target surfaces is investigated, including the smooth and the ribbed surface with convex/concave columnar ribs. The results show that the cooling effectiveness of the mist/air two-phase flow is better than that of the single-phase flow. When the ribbed surfaces are used, the heat transfer enhancement is significant, the surface cooling effectiveness becomes higher and the convex ribbed surface presents a better performance. With the enhancement of the surface heat transfer, the pressure drop in the impingement zone increases, but the incremental factor of the flow friction is smaller than that of the heat transfer enhancement. Copyright © 2017 Elsevier Ltd. All rights reserved.

  18. Aerosol composition in a stagnant air mass impacted by dense fogs: preliminary results

    Energy Technology Data Exchange (ETDEWEB)

    Jacob, D.J.; Munger, J.W.; Waldman, J.M.; Hoffman, M.R.

    1984-01-01

    Over the last two winters, our research group has been investigating the chemical composition of fogwater and haze aerosol during wintertime stagnation episodes in the San Joaquin Valley of California. The valley is encompassed by mountain ranges. During the winter a strong subsidence inversion based below the natural boundaries of the valley restricts the ventilation of the air masses below the inversion. The residence time of an air parcel in the valley under these stagnation conditions is on the order of 8 days. Because the trapped air is very humid, stagnation episodes are associated with a persistent thick haze and frequent widespread nighttime fogs. During the winter 1982-1983 the authors sampled fog and haze at one site (Bakersfield); results from this preliminary study have been discussed in detail in a previous report. In the winter 1983-1984 the scale of the program was expanded in order to test hypotheses formulated as a result of first year data. The present paper first reports briefly on the 1982-1983 results and outlines the essential conclusions. They then describe the large-scale experiment conducted during the winter of 1983-1984, and discuss some preliminary fogwater data.

  19. Surface oxygenation of polypropylene using an air dielectric barrier discharge: the effect of different electrode-platen combinations

    International Nuclear Information System (INIS)

    Upadhyay, D.J.; Cui, N.-Y.; Anderson, C.A.; Brown, N.M.D.

    2004-01-01

    Polypropylene film has been modified in an air dielectric barrier discharge using two different electrode-platen configurations: stainless steel wire electrode-rubber platen or ceramic electrode-aluminium platen combinations. Modified films were characterised by static contact angle measurements, X-ray photoelectron spectroscopy (XPS), secondary ion mass spectrometry (SIMS) and Fourier transform infrared spectroscopy (ATR-FT-IR). Surface hydrophilic modification appears to be governed by the presence of low-molecular weight oxidised functionalities using XPS and SIMS techniques. Irrespective of the type of electrode-platen combination used to obtain the discharge, oxygenated functionalities of identical nature are formed on the polymer surface. However, the degree of oxidation obtained by the discharge using the wire electrodes with the rubber platen was considerably greater. Further increase in the observed hydrophilicity due to molecular rearrangement and development of stable oxygenated functionalities was evident after 1 month of post-processing analysis

  20. Impact of Bay-Breeze Circulations on Surface Air Quality and Boundary Layer Export

    Science.gov (United States)

    Loughner, Christopher P.; Tzortziou, Maria; Follette-Cook, Melanie; Pickering, Kenneth E.; Goldberg, Daniel; Satam, Chinmay; Weinheimer, Andrew; Crawford, James H.; Knapp, David J.; Montzka, Denise D.; hide

    2014-01-01

    Meteorological and air-quality model simulations are analyzed alongside observations to investigate the role of the Chesapeake Bay breeze on surface air quality, pollutant transport, and boundary layer venting. A case study was conducted to understand why a particular day was the only one during an 11-day ship-based field campaign on which surface ozone was not elevated in concentration over the Chesapeake Bay relative to the closest upwind site and why high ozone concentrations were observed aloft by in situ aircraft observations. Results show that southerly winds during the overnight and early-morning hours prevented the advection of air pollutants from the Washington, D.C., and Baltimore, Maryland, metropolitan areas over the surface waters of the bay. A strong and prolonged bay breeze developed during the late morning and early afternoon along the western coastline of the bay. The strength and duration of the bay breeze allowed pollutants to converge, resulting in high concentrations locally near the bay-breeze front within the Baltimore metropolitan area, where they were then lofted to the top of the planetary boundary layer (PBL). Near the top of the PBL, these pollutants were horizontally advected to a region with lower PBL heights, resulting in pollution transport out of the boundary layer and into the free troposphere. This elevated layer of air pollution aloft was transported downwind into New England by early the following morning where it likely mixed down to the surface, affecting air quality as the boundary layer grew.

  1. Reliability Evaluation for the Surface to Air Missile Weapon Based on Cloud Model

    Directory of Open Access Journals (Sweden)

    Deng Jianjun

    2015-01-01

    Full Text Available The fuzziness and randomness is integrated by using digital characteristics, such as Expected value, Entropy and Hyper entropy. The cloud model adapted to reliability evaluation is put forward based on the concept of the surface to air missile weapon. The cloud scale of the qualitative evaluation is constructed, and the quantitative variable and the qualitative variable in the system reliability evaluation are corresponded. The practical calculation result shows that it is more effective to analyze the reliability of the surface to air missile weapon by this way. The practical calculation result also reflects the model expressed by cloud theory is more consistent with the human thinking style of uncertainty.

  2. Finite element analysis of an inflatable torus considering air mass structural element

    Science.gov (United States)

    Gajbhiye, S. C.; Upadhyay, S. H.; Harsha, S. P.

    2014-01-01

    Inflatable structures, also known as gossamer structures, are at high boom in the current space technology due to their low mass and compact size comparing to the traditional spacecraft designing. Internal pressure becomes the major source of strength and rigidity, essentially stiffen the structure. However, inflatable space based membrane structure are at high risk to the vibration disturbance due to their low structural stiffness and material damping. Hence, the vibration modes of the structure should be known to a high degree of accuracy in order to provide better control authority. In the past, most of the studies conducted on the vibration analysis of gossamer structures used inaccurate or approximate theories in modeling the internal pressure. The toroidal shaped structure is one of the important key element in space application, helps to support the reflector in space application. This paper discusses the finite-element analysis of an inflated torus. The eigen-frequencies are obtained via three-dimensional small-strain elasticity theory, based on extremum energy principle. The two finite-element model (model-1 and model-2) have cases have been generated using a commercial finite-element package. The structure model-1 with shell element and model-2 with the combination of the mass of enclosed fluid (air) added to the shell elements have been taken for the study. The model-1 is computed with present analytical approach to understand the convergence rate and the accuracy. The convergence study is made available for the symmetric modes and anti-symmetric modes about the centroidal-axis plane, meeting the eigen-frequencies of an inflatable torus with the circular cross section. The structural model-2 is introduced with air mass element and analyzed its eigen-frequency with different aspect ratio and mode shape response using in-plane and out-plane loading condition are studied.

  3. Fullerene Soot in Eastern China Air: Results from Soot Particle-Aerosol Mass Spectrometer

    Science.gov (United States)

    Wang, J.; Ge, X.; Chen, M.; Zhang, Q.; Yu, H.; Sun, Y.; Worsnop, D. R.; Collier, S.

    2015-12-01

    In this work, we present for the first time, the observation and quantification of fullerenes in ambient airborne particulate using an Aerodyne Soot Particle - Aerosol Mass Spectrometer (SP-AMS) deployed during 2015 winter in suburban Nanjing, a megacity in eastern China. The laser desorption and electron impact ionization techniques employed by the SP-AMS allow us to differentiate various fullerenes from other aerosol components. Mass spectrum of the identified fullerene soot is consisted by a series of high molecular weight carbon clusters (up to m/z of 2000 in this study), almost identical to the spectral features of commercially available fullerene soot, both with C70 and C60 clusters as the first and second most abundant species. This type of soot was observed throughout the entire study period, with an average mass loading of 0.18 μg/m3, accounting for 6.4% of the black carbon mass, 1.2% of the total organic mass. Temporal variation and diurnal pattern of fullerene soot are overall similar to those of black carbon, but are clearly different in some periods. Combining the positive matrix factorization, back-trajectory and analyses of the meteorological parameters, we identified the petrochemical industrial plants situating upwind from the sampling site, as the major source of fullerene soot. In this regard, our findings imply the ubiquitous presence of fullerene soot in ambient air of industry-influenced area, especially the oil and gas production regions. This study also offers new insights into the characterization of fullerenes from other environmental samples via the advanced SP-AMS technique.

  4. SEMIC: an efficient surface energy and mass balance model applied to the Greenland ice sheet

    Directory of Open Access Journals (Sweden)

    M. Krapp

    2017-07-01

    Full Text Available We present SEMIC, a Surface Energy and Mass balance model of Intermediate Complexity for snow- and ice-covered surfaces such as the Greenland ice sheet. SEMIC is fast enough for glacial cycle applications, making it a suitable replacement for simpler methods such as the positive degree day (PDD method often used in ice sheet modelling. Our model explicitly calculates the main processes involved in the surface energy and mass balance, while maintaining a simple interface and requiring minimal data input to drive it. In this novel approach, we parameterise diurnal temperature variations in order to more realistically capture the daily thaw–freeze cycles that characterise the ice sheet mass balance. We show how to derive optimal model parameters for SEMIC specifically to reproduce surface characteristics and day-to-day variations similar to the regional climate model MAR (Modèle Atmosphérique Régional, version 2 and its incorporated multilayer snowpack model SISVAT (Soil Ice Snow Vegetation Atmosphere Transfer. A validation test shows that SEMIC simulates future changes in surface temperature and surface mass balance in good agreement with the more sophisticated multilayer snowpack model SISVAT included in MAR. With this paper, we present a physically based surface model to the ice sheet modelling community that is general enough to be used with in situ observations, climate model, or reanalysis data, and that is at the same time computationally fast enough for long-term integrations, such as glacial cycles or future climate change scenarios.

  5. Surface treatment of aramid fiber by air dielectric barrier discharge plasma at atmospheric pressure

    International Nuclear Information System (INIS)

    Jia Caixia; Chen Ping; Liu Wei; Li Bin; Wang Qian

    2011-01-01

    Aramid fiber samples are treated by air dielectric barrier discharge (DBD) plasma at atmospheric pressure; the plasma treatment time is investigated as the major parameter. The effects of this treatment on the fiber surface physical and chemical properties are studied by using surface characterization techniques. Scanning electron microscopy (SEM) is performed to determine the surface morphology changes, X-ray photoelectron spectroscopy (XPS) is analyzed to reveal the surface chemical composition variations and dynamic contact angle analysis (DCAA) is used to examine the changes of the fiber surface wettability. In addition, the wetting behavior of a kind of thermoplastic resin, poly(phthalazinone ether sulfone ketone) (PPESK), on aramid fiber surface is also observed by SEM photos. The study shows that there seems to be an optimum treatment condition for surface modification of aramid fiber by the air DBD plasma. In this paper, after the 12 s, 27.6 W/cm 3 plasma treatment the aramid fiber surface roughness is significantly improved, some new oxygen-containing groups such as C-O, C=O and O=C-O are generated on the fiber surface and the fiber surface wettability is greatly enhanced, which results in the better wetting behavior of PPESK resin on the plasma-treated aramid fiber.

  6. Identifying anthropogenic anomalies in air, surface and groundwater temperatures in Germany.

    Science.gov (United States)

    Benz, Susanne A; Bayer, Peter; Blum, Philipp

    2017-04-15

    Human activity directly influences ambient air, surface and groundwater temperatures. The most prominent phenomenon is the urban heat island effect, which has been investigated particularly in large and densely populated cities. This study explores the anthropogenic impact on the thermal regime not only in selected urban areas, but on a countrywide scale for mean annual temperature datasets in Germany in three different compartments: measured surface air temperature, measured groundwater temperature, and satellite-derived land surface temperature. Taking nighttime lights as an indicator of rural areas, the anthropogenic heat intensity is introduced. It is applicable to each data set and provides the difference between measured local temperature and median rural background temperature. This concept is analogous to the well-established urban heat island intensity, but applicable to each measurement point or pixel of a large, even global, study area. For all three analyzed temperature datasets, anthropogenic heat intensity grows with increasing nighttime lights and declines with increasing vegetation, whereas population density has only minor effects. While surface anthropogenic heat intensity cannot be linked to specific land cover types in the studied resolution (1km×1km) and classification system, both air and groundwater show increased heat intensities for artificial surfaces. Overall, groundwater temperature appears most vulnerable to human activity, albeit the different compartments are partially influenced through unrelated processes; unlike land surface temperature and surface air temperature, groundwater temperatures are elevated in cultivated areas as well. At the surface of Germany, the highest anthropogenic heat intensity with 4.5K is found at an open-pit lignite mine near Jülich, followed by three large cities (Munich, Düsseldorf and Nuremberg) with annual mean anthropogenic heat intensities >4K. Overall, surface anthropogenic heat intensities >0K and

  7. Spatially-varying surface roughness and ground-level air quality in an operational dispersion model

    International Nuclear Information System (INIS)

    Barnes, M.J.; Brade, T.K.; MacKenzie, A.R.; Whyatt, J.D.; Carruthers, D.J.; Stocker, J.; Cai, X.; Hewitt, C.N.

    2014-01-01

    Urban form controls the overall aerodynamic roughness of a city, and hence plays a significant role in how air flow interacts with the urban landscape. This paper reports improved model performance resulting from the introduction of variable surface roughness in the operational air-quality model ADMS-Urban (v3.1). We then assess to what extent pollutant concentrations can be reduced solely through local reductions in roughness. The model results suggest that reducing surface roughness in a city centre can increase ground-level pollutant concentrations, both locally in the area of reduced roughness and downwind of that area. The unexpected simulation of increased ground-level pollutant concentrations implies that this type of modelling should be used with caution for urban planning and design studies looking at ventilation of pollution. We expect the results from this study to be relevant for all atmospheric dispersion models with urban-surface parameterisations based on roughness. -- Highlights: • Spatially variable roughness improved performance of an operational model. • Scenario modelling explored effect of reduced roughness on air pollution. • Reducing surface roughness can increase modelled ground-level pollution. • Damped vertical mixing outweighs increased horizontal advection in model study. • Result should hold for any model with a land-surface coupling based on roughness. -- Spatially varying roughness improves model simulations of urban air pollutant dispersion. Reducing roughness does not always decrease ground-level pollution concentrations

  8. Match properties of heat transfer and coupled heat and mass transfer processes in air-conditioning system

    International Nuclear Information System (INIS)

    Zhang Tao; Liu Xiaohua; Zhang Lun; Jiang Yi

    2012-01-01

    Highlights: ► Investigates match properties of heat or mass transfer processes in HVAC system. ► Losses are caused by limited transfer ability, flow and parameter mismatching. ► Condition of flow matching is the same heat capacity of the fluids. ► Parameter matching is only reached along the saturation line in air–water system. ► Analytical solutions of heat and mass transfer resistance are derived. - Abstract: Sensible heat exchangers and coupled heat and mass transfer devices between humid air and water/desiccant are commonly used devices in air-conditioning systems. This paper focuses on the match properties of sensible heat transfer processes and coupled heat and mass transfer processes in an effort to understand the reasons for performance limitations in order to optimize system performance. Limited heat transfer capability and flow mismatching resulted in heat resistance of the sensible heat transfer process. Losses occurred during the heat and mass transfer processes due to limited transfer capability, flow mismatching, and parameter mismatching. Flow matching was achieved when the heat capacities of the fluids were identical, and parameter matching could only be reached along the saturation line in air–water systems or the iso-concentration line in air–desiccant systems. Analytical solutions of heat transfer resistance and mass transfer resistance were then derived. The heat and mass transfer process close to the saturation line is recommended, and heating sprayed water resulted in better humidification performance than heating inlet air in the air humidifier.

  9. Evaluation of errors for mass-spectrometric analysis with surface-ionization type mass-spectrometer (statistical evaluation of mass-discrimination effect)

    International Nuclear Information System (INIS)

    Wada, Y.

    1981-01-01

    The surface-ionization type mass-spectrometer is widely used as an apparatus for quality assurance, accountability and safeguarding of nuclear materials, and for this analysis it has become an important factor to statistically evaluate an analytical error which consists of a random error and a systematic error. The major factor of this systematic error was the mass-discrimination effect. In this paper, various assays for evaluating the factor of variation on the mass-discrimination effect were studied and the data obtained were statistically evaluated. As a result of these analyses, it was proved that the factor of variation on the mass-discrimination effect was not attributed to the acid concentration of sample, sample size on the filament and supplied voltage for a multiplier, but mainly to the filament temperature during the mass-spectrometric analysis. The mass-discrimination effect values β which were usually calculated from the measured data of uranium, plutonium or boron isotopic standard sample were not so significant dependently of the difference of U-235, Pu-239 or B-10 isotopic abundance. Furthermore, in the case of U and Pu, measurement conditions and the mass range of these isotopes were almost similar, and these values β were not statistically significant between U and Pu. On the other hand, the value β for boron was about a third of the value β for U or Pu, but compared with the coefficient of the correction on the mass-discrimination effect for the difference of mass-number, ΔM, these coefficient values were almost the same among U, Pu, and B.As for the isotopic analysis error of U, Pu, Nd and B, it was proved that the isotopic abundance of these elements and the isotopic analysis error were in a relationship of quadratic curves on a logarithmic-logarithmic scale

  10. Air-spun PLA nanofibers modified with reductively sheddable hydrophilic surfaces for vascular tissue engineering: synthesis and surface modification.

    Science.gov (United States)

    Ko, Na Re; Sabbatier, Gad; Cunningham, Alexander; Laroche, Gaétan; Oh, Jung Kwon

    2014-02-01

    Polylactide (PLA) is a class of promising biomaterials that hold great promise for various biological and biomedical applications, particularly in the field of vascular tissue engineering where it can be used as a fibrous mesh to coat the inside of vascular prostheses. However, its hydrophobic surface providing nonspecific interactions and its limited ability to further modifications are challenges that need to be overcome. Here, the development of new air-spun PLA nanofibers modified with hydrophilic surfaces exhibiting reduction response is reported. Surface-initiated atom transfer radical polymerization allows for grafting pendant oligo(ethylene oxide)-containing polymethacrylate (POEOMA) from PLA air-spun fibers labeled with disulfide linkages. The resulting PLA-ss-POEOMA fibers exhibit enhanced thermal stability and improved surface properties, as well as thiol-responsive shedding of hydrophilic POEOMA by the cleavage of its disulfide linkages in response to reductive reactions, thus tuning the surface properties. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Effects of air dielectric barrier discharge plasma treatment time on surface properties of PBO fiber

    International Nuclear Information System (INIS)

    Wang Qian; Chen Ping; Jia Caixia; Chen, Mingxin; Li Bin

    2011-01-01

    In this paper, the effects of air dielectric barrier discharge (DBD) plasma treatment time on surface properties of poly(p-phenylene benzobisoxazole) (PBO) fiber were investigated. The surface characteristics of PBO fiber before and after the plasma treatments were analyzed by dynamic contact angle (DCA) analysis, scanning electron microscopy (SEM), atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS). DCA measurements indicated that the surface wettability of PBO fiber was improved significantly by increasing the fiber surface free energy via air DBD plasma treatments. The results were confirmed by the improvement of adhesion of a kind of thermoplastic resin to PBO fiber which was observed by SEM, showing that more resin was adhering evenly to the fiber surface. AFM measurement revealed that the surface topography of PBO fiber became more complicated and the surface roughness was greatly enhanced after the plasma treatments, and XPS analysis showed that some new polar groups (e.g. -O-C=O) were introduced on plasma treated PBO fiber surface. The results of this study also showed that the surface properties of PBO fiber changed with the elongation of plasma treatment time.

  12. Interaction of the Helium, Hydrogen, Air, Argon, and Nitrogen Bubbles with Graphite Surface in Water.

    Science.gov (United States)

    Bartali, Ruben; Otyepka, Michal; Pykal, Martin; Lazar, Petr; Micheli, Victor; Gottardi, Gloria; Laidani, Nadhira

    2017-05-24

    The interaction of the confined gas with solid surface immersed in water is a common theme of many important fields such as self-cleaning surface, gas storage, and sensing. For that reason, we investigated the gas-graphite interaction in the water medium. The graphite surface was prepared by mechanical exfoliation of highly oriented pyrolytic graphite (HOPG). The surface chemistry and morphology were studied by X-ray photoelectron spectroscopy, profilometry, and atomic force microscopy. The surface energy of HOPG was estimated by contact angle measurements using the Owens-Wendt method. The interaction of gases (Ar, He, H 2 , N 2 , and air) with graphite was studied by a captive bubble method, in which the gas bubble was in contact with the exfoliated graphite surface in water media. The experimental data were corroborated by molecular dynamics simulations and density functional theory calculations. The surface energy of HOPG equaled to 52.8 mJ/m 2 and more of 95% of the surface energy was attributed to dispersion interactions. The results on gas-surface interaction indicated that HOPG surface had gasphilic behavior for helium and hydrogen, while gasphobic behavior for argon and nitrogen. The results showed that the variation of the gas contact angle was related to the balance between the gas-surface and gas-gas interaction potentials. For helium and hydrogen the gas-surface interaction was particularly high compared to gas-gas interaction and this promoted the favorable interaction with graphite surface.

  13. Measurement of air cooling characteristics for the several surface types of Li-ion battery

    International Nuclear Information System (INIS)

    Byelyayev, Andrey A.; Fedorchenko, Dmitrij V.; Khazhmuradov, Manap A.; Lukhanin, Olekdandr A.; Lukhanin, Oleksiy A.; Martynov, Sergey O.; Rudychev, Yegor V.; Sporov, Eugen O.; Rohatgi, Upendra S.

    2013-01-01

    The system of air cooling for Li-Ion batteries is considered. Experimental setup included thermal chamber and Li-Ion battery cell simulators with temperature sensors. We investigated static and dynamic cooling regimes for several types of cooling surfaces, for different gaps between the simulators and flow rates. Experimental results are compared to the data of computer modelling using SolidWorks Flow Simulation software. The cooling efficiencies of the various surfaces for static and transient heat emission modes are compared.

  14. Formic and Acetic Acid Observations over Colorado by Chemical Ionization Mass Spectrometry and Organic Acids' Role in Air Quality

    Science.gov (United States)

    Treadaway, V.; O'Sullivan, D. W.; Heikes, B.; Silwal, I.; McNeill, A.

    2015-12-01

    Formic acid (HFo) and acetic acid (HAc) have both natural and anthropogenic sources and a role in the atmospheric processing of carbon. These organic acids also have an increasing importance in setting the acidity of rain and snow as precipitation nitrate and sulfate concentrations have decreased. Primary emissions for both organic acids include biomass burning, agriculture, and motor vehicle emissions. Secondary production is also a substantial source for both acids especially from biogenic precursors, secondary organic aerosols (SOAs), and photochemical production from volatile organic compounds (VOCs) and oxygenated volatile organic compounds (OVOCs). Chemical transport models underestimate organic acid concentrations and recent research has sought to develop additional production mechanisms. Here we report HFo and HAc measurements during two campaigns over Colorado using the peroxide chemical ionization mass spectrometer (PCIMS). Iodide clusters of both HFo and HAc were recorded at mass-to-charge ratios of 173 and 187, respectively. The PCIMS was flown aboard the NCAR Gulfstream-V platform during the Deep Convective Clouds and Chemistry Experiment (DC3) and aboard the NCAR C-130 during the Front Range Air Pollution and Photochemistry Experiment (FRAPPE). The DC3 observations were made in May and June 2012 extending from the surface to 13 km over the central and eastern United States. FRAPPE observations were made in July and August 2014 from the surface to 7 km over Colorado. DC3 measurements reported here are focused over the Colorado Front Range and complement the FRAPPE observations. DC3 HFo altitude profiles are characterized by a decrease up to 6 km followed by an increase either back to boundary layer mixing ratio values or higher (a "C" shape). Organic acid measurements from both campaigns are interpreted with an emphasis on emission sources (both natural and anthropogenic) over Colorado and in situ photochemical production especially ozone precursors.

  15. Analysis of surface air temperature variations and local urbanization effects on central Yunnan Plateau, SW China

    Science.gov (United States)

    He, Yunling; Wu, Zhijie; Liu, Xuelian; Deng, Fuying

    2018-01-01

    With the surface air temperature (SAT) data at 37 stations on Central Yunnan Plateau (CYP) for 1961-2010 and the Defense Meteorological Satellite Program/Operational Linescan System (DMSP/OLS) nighttime light data, the temporal-spatial patterns of the SAT trends are detected using Sen's Nonparametric Estimator of Slope approach and MK test, and the impact of urbanization on surface warming is analyzed by comparing the differences between the air temperature change trends of urban stations and their corresponding rural stations. Results indicated that annual mean air temperature showed a significant warming trend, which is equivalent to a rate of 0.17 °C/decade during the past 50 years. Seasonal mean air temperature presents a rising trend, and the trend was more significant in winter (0.31 °C/decade) than in other seasons. Annual/seasonal mean air temperature tends to increase in most areas, and higher warming trend appeared in urban areas, notably in Kunming city. The regional mean air temperature series was significantly impacted by urban warming, and the urbanization-induced warming contributed to approximately 32.3-62.9 % of the total regional warming during the past 50 years. Meantime, the urbanization-induced warming trend in winter and spring was more significant than that in summer and autumn. Since 1985, the urban heat island (UHI) intensity has gradually increased. And the urban temperatures always rise faster than rural temperatures on the CYP.

  16. Improving the indoor air quality by using a surface emissions trap

    Science.gov (United States)

    Markowicz, Pawel; Larsson, Lennart

    2015-04-01

    The surface emissions trap, an adsorption cloth developed for reducing emissions of volatile organic compounds and particulate matter from surfaces while allowing evaporation of moisture, was used to improve the indoor air quality of a school building with elevated air concentrations of 2-ethyl-1-hexanol. An improvement of the perceived air quality was noticed a few days after the device had been attached on the PVC flooring. In parallel, decreased air concentrations of 2-ethyl-1-hexanol were found as well as a linear increase of the amounts of the same compound adsorbed on the installed cloth as observed up to 13 months after installation. Laboratory studies revealed that the performance of the device is not affected by differences in RH (35-85%), temperature (30-40 °C) or by accelerated aging simulating up to 10 years product lifetime, and, from a blinded exposure test, that the device efficiently blocks chemical odors. This study suggests that the device may represent a fast and efficient means of restoring the indoor air quality in a building e.g. after water damage leading to irritating and potentially harmful emissions from building material surfaces indoors.

  17. Statistics of surface divergence and their relation to air-water gas transfer velocity

    Science.gov (United States)

    Asher, William E.; Liang, Hanzhuang; Zappa, Christopher J.; Loewen, Mark R.; Mukto, Moniz A.; Litchendorf, Trina M.; Jessup, Andrew T.

    2012-05-01

    Air-sea gas fluxes are generally defined in terms of the air/water concentration difference of the gas and the gas transfer velocity,kL. Because it is difficult to measure kLin the ocean, it is often parameterized using more easily measured physical properties. Surface divergence theory suggests that infrared (IR) images of the water surface, which contain information concerning the movement of water very near the air-water interface, might be used to estimatekL. Therefore, a series of experiments testing whether IR imagery could provide a convenient means for estimating the surface divergence applicable to air-sea exchange were conducted in a synthetic jet array tank embedded in a wind tunnel. Gas transfer velocities were measured as a function of wind stress and mechanically generated turbulence; laser-induced fluorescence was used to measure the concentration of carbon dioxide in the top 300 μm of the water surface; IR imagery was used to measure the spatial and temporal distribution of the aqueous skin temperature; and particle image velocimetry was used to measure turbulence at a depth of 1 cm below the air-water interface. It is shown that an estimate of the surface divergence for both wind-shear driven turbulence and mechanically generated turbulence can be derived from the surface skin temperature. The estimates derived from the IR images are compared to velocity field divergences measured by the PIV and to independent estimates of the divergence made using the laser-induced fluorescence data. Divergence is shown to scale withkLvalues measured using gaseous tracers as predicted by conceptual models for both wind-driven and mechanically generated turbulence.

  18. Monitoring the on-surface synthesis of graphene nanoribbons by mass spectrometry

    KAUST Repository

    Zhang, Wen

    2017-06-14

    We present a mass spectrometric approach to monitor and characterize the intermediates of graphene nanoribbon (GNR) formation by chemical vapor deposition (CVD) on top of Au(111) surfaces. Information regarding the repeating units, lengths, and termini can be obtained directly from the surface sample by a modified matrix assisted laser desorption/ionization (MALDI) method. The mass spectrometric results reveal ample oxidative side reactions under CVD conditions which can, however, be diminished drastically by introduction of protective H2 gas at ambient pressure. Simultaneously, addition of hydrogen extends the lengths of the oligophenylenes and thus the final GNRs. Moreover, the prematurely formed cyclodehydrogenation products during the oligomer growth can be assigned by the mass spectrometric method. The obtained mechanistic insights provide valuable information for optimizing and upscaling the bottom-up fabrication of GNRs. Given the important role of GNRs as semiconductors, the mass spectrometric characterization provides a readily available tool to improve and characterize their structural perfection.

  19. Quantifying the resolution level where the GRACE satellites can separate Greenland's glacial mass balance from surface mass balance

    Science.gov (United States)

    Bonin, J. A.; Chambers, D. P.

    2015-09-01

    Mass change over Greenland can be caused by either changes in the glacial dynamic mass balance (DMB) or the surface mass balance (SMB). The GRACE satellite gravity mission cannot directly separate the two physical causes because it measures the sum of the entire mass column with limited spatial resolution. We demonstrate one theoretical way to indirectly separate cumulative SMB from DMB with GRACE, using a least squares inversion technique with knowledge of the location of the glaciers. However, we find that the limited 60 × 60 spherical harmonic representation of current GRACE data does not provide sufficient resolution to adequately accomplish the task. We determine that at a maximum degree/order of 90 × 90 or above, a noise-free gravity measurement could theoretically separate the SMB from DMB signals. However, current GRACE satellite errors are too large at present to separate the signals. A noise reduction of a factor of 10 at a resolution of 90 × 90 would provide the accuracy needed for the interannual cumulative SMB and DMB to be accurately separated.

  20. ARIMA representation for daily solar irradiance and surface air temperature time series

    Science.gov (United States)

    Kärner, Olavi

    2009-06-01

    Autoregressive integrated moving average (ARIMA) models are used to compare long-range temporal variability of the total solar irradiance (TSI) at the top of the atmosphere (TOA) and surface air temperature series. The comparison shows that one and the same type of the model is applicable to represent the TSI and air temperature series. In terms of the model type surface air temperature imitates closely that for the TSI. This may mean that currently no other forcing to the climate system is capable to change the random walk type variability established by the varying activity of the rotating Sun. The result should inspire more detailed examination of the dependence of various climate series on short-range fluctuations of TSI.

  1. Morphing Surfaces Enable Acoustophoretic Contactless Transport of Ultrahigh-Density Matter in Air

    Science.gov (United States)

    Foresti, Daniele; Sambatakakis, Giorgio; Bottan, Simone; Poulikakos, Dimos

    2013-01-01

    The controlled contactless transport of heavy drops and particles in air is of fundamental interest and has significant application potential. Acoustic forces do not rely on special material properties, but their utility in transporting heavy matter in air has been restricted by low power and poor controllability. Here we present a new concept of acoustophoresis, based on the morphing of a deformable reflector, which exploits the low reaction forces and low relaxation time of a liquid with enhanced surface tension through the use of thin overlaid membrane. An acoustically induced, mobile deformation (dimple) on the reflector surface enhances the acoustic field emitted by a line of discretized emitters and enables the countinuos motion of heavy levitated samples. With such interplay of emitters and reflecting soft-structure, a 5 mm steel sphere (0.5 grams) was contactlessly transported in air solely by acoustophoresis. PMID:24212104

  2. Temporal Changes in the Observed Relationship between Cloud Cover and Surface Air Temperature.

    Science.gov (United States)

    Sun, Bomin; Groisman, Pavel Ya.; Bradley, Raymond S.; Keimig, Frank T.

    2000-12-01

    The relationship between cloud cover and near-surface air temperature and its decadal changes are examined using the hourly synoptic data for the past four to six decades from five regions of the Northern Hemisphere: Canada, the United States, the former Soviet Union, China, and tropical islands of the western Pacific. The authors define the normalized cloud cover-surface air temperature relationship, NOCET or dT/dCL, as a temperature anomaly with a unit (one-tenth) deviation of total cloud cover from its average value. Then mean monthly NOCET time series (night- and daytime, separately) are area-averaged and parameterized as functions of surface air humidity and snow cover. The day- and nighttime NOCET variations are strongly anticorrelated with changes in surface humidity. Furthermore, the daytime NOCET changes are positively correlated to changes in snow cover extent. The regionally averaged nighttime NOCET varies from 0.05 K tenth1 in the wet Tropics to 1.0 K tenth1 at midlatitudes in winter. The daytime regional NOCET ranges from 0.4 K tenth1 in the Tropics to 0.7 K tenth1 at midlatitudes in winter.The authors found a general strengthening of a daytime surface cooling during the post-World War II period associated with cloud cover over the United States and China, but a minor reduction of this cooling in higher latitudes. Furthermore, since the 1970s, a prominent increase in atmospheric humidity has significantly weakened the effectiveness of the surface warming (best seen at nighttime) associated with cloud cover.The authors apportion the spatiotemporal field of interactions between total cloud cover and surface air temperature into a bivariate relationship (described by two equations, one for daytime and one for nighttime) with surface air humidity and snow cover and two constant factors. These factors are invariant in space and time domains. It is speculated that they may represent empirical estimates of the overall cloud cover effect on the surface air

  3. OPTIMIZATION OF MICROWAVE AND AIR DRYING CONDITIONS OF QUINCE (CYDONIA OBLONGA, MILLER USING RESPONSE SURFACE METHODOLOGY

    Directory of Open Access Journals (Sweden)

    Cem Baltacioglu

    2015-03-01

    Full Text Available Effects of slice thickness of quince (Cydonia oblonga Miller , microwave incident power and air drying temperature on antioxidant activity and total phenolic content of quince were investigated during drying in microwave and air drying. Optimum conditions were found to be: i for microwave drying, 285 W and 4.14 mm thick (maximum antioxidant activity and 285 W and 6.85 mm thick (maximum total phenolic content, and ii for air drying, 75 ºC and 1.2 mm thick (both maximum antioxidant activity and total phenolic content. Drying conditions were optimized by using the response surface methodology. 13 experiments were carried out considering incident microwave powers from 285 to 795 W, air temperature from 46 to 74 ºC and slice thickness from 1.2 to 6.8 mm.

  4. Design and evaluation of an inexpensive radiation shield for monitoring surface air temperatures

    Science.gov (United States)

    Zachary A. Holden; Anna E. Klene; Robert F. Keefe; Gretchen G. Moisen

    2013-01-01

    Inexpensive temperature sensors are widely used in agricultural and forestry research. This paper describes a low-cost (~3 USD) radiation shield (radshield) designed for monitoring surface air temperatures in harsh outdoor environments. We compared the performance of the radshield paired with low-cost temperature sensors at three sites in western Montana to several...

  5. Environmental survey to assess viral contamination of air and surfaces in hospital settings.

    Science.gov (United States)

    Carducci, A; Verani, M; Lombardi, R; Casini, B; Privitera, G

    2011-03-01

    The presence of pathogenic viruses in healthcare settings represents a serious risk for both staff and patients. Direct viral detection in the environment poses significant technical problems and the indirect indicators currently in use suffer from serious limitations. The aim of this study was to monitor surfaces and air in hospital settings to reveal the presence of hepatitis C virus, human adenovirus, norovirus, human rotavirus and torque teno virus by nucleic acid assays, in parallel with measurements of total bacterial count and haemoglobin presence. In total, 114 surface and 62 air samples were collected. Bacterial contamination was very low (air was 282 cfu/m(3). Overall, 19 (16.7%) surface samples tested positive for viral nucleic acids: one for norovirus, one for human adenovirus and 17 (14.9%) for torque teno virus (TTV). Only this latter virus was directly detected in 10 air samples (16.1%). Haemoglobin was found on two surfaces. No relationship was found between viral, biochemical or bacterial indicators. The data obtained confirm the difficulty of assessing viral contamination using bacterial indicators. The frequent detection of TTV suggests its possible use as an indicator for general viral contamination of the environment. Copyright © 2010 The Hospital Infection Society. Published by Elsevier Ltd. All rights reserved.

  6. Laser ablation of liquid surface in air induced by laser irradiation through liquid medium

    Science.gov (United States)

    Utsunomiya, Yuji; Kajiwara, Takashi; Nishiyama, Takashi; Nagayama, Kunihito; Kubota, Shiro; Nakahara, Motonao

    2010-10-01

    The pulse laser ablation of a liquid surface in air when induced by laser irradiation through a liquid medium has been experimentally investigated. A supersonic liquid jet is observed at the liquid-air interface. The liquid surface layer is driven by a plasma plume that is produced by laser ablation at the layer, resulting in a liquid jet. This phenomenon occurs only when an Nd:YAG laser pulse (wavelength: 1064 nm) is focused from the liquid onto air at a low fluence of 20 J/cm2. In this case, as Fresnel’s law shows, the incident and reflected electric fields near the liquid surface layer are superposed constructively. In contrast, when the incident laser is focused from air onto the liquid, a liquid jet is produced only at an extremely high fluence, several times larger than that in the former case. The similarities and differences in the liquid jets and atomization processes are studied for several liquid samples, including water, ethanol, and vacuum oil. The laser ablation of the liquid surface is found to depend on the incident laser energy and laser fluence. A pulse laser light source and high-resolution film are required to observe the detailed structure of a liquid jet.

  7. Assessment of broiler surface temperature variation when exposed to different air temperatures

    Directory of Open Access Journals (Sweden)

    GR Nascimento

    2011-12-01

    Full Text Available This study was conducted to determine the effect of the air temperature variation on the mean surface temperature (MST of 7- to 35-day-old broiler chickens using infrared thermometry to estimate MST, and to study surface temperature variation of the wings, head, legs, back and comb as affected by air temperature and broiler age. One hundred Cobb® broilers were used in the experiment. Starting on day 7, 10 birds were weekly selected at random, housed in an environmental chamber and reared under three distinct temperatures (18, 25 and 32 ºC to record their thermal profile using an infrared thermal camera. The recorded images were processed to estimate MST by selecting the whole area of the bird within the picture and comparing it with the values obtained using selected equations in literature, and to record the surface temperatures of the body parts. The MST estimated by infrared images were not statistically different (p > 0.05 from the values obtained by the equations. MST values significantly increased (p < 0.05 when the air temperature increased, but were not affected by bird age. However, age influenced the difference between MST and air temperature, which was highest on day 14. The technique of infrared thermal image analysis was useful to estimate the mean surface temperature of broiler chickens.

  8. The influence of air temperature inversions on snowmelt and glacier mass-balance simulations, Ammassalik island, SE Greenland

    Energy Technology Data Exchange (ETDEWEB)

    Mernild, Sebastian Haugard [Los Alamos National Laboratory; Liston, Glen [COLORADO STATE UNIV.

    2009-01-01

    In many applications, a realistic description of air temperature inversions is essential for accurate snow and glacier ice melt, and glacier mass-balance simulations. A physically based snow-evolution modeling system (SnowModel) was used to simulate eight years (1998/99 to 2005/06) of snow accumulation and snow and glacier ice ablation from numerous small coastal marginal glaciers on the SW-part of Ammassalik Island in SE Greenland. These glaciers are regularly influenced by inversions and sea breezes associated with the adjacent relatively low temperature and frequently ice-choked fjords and ocean. To account for the influence of these inversions on the spatiotemporal variation of air temperature and snow and glacier melt rates, temperature inversion routines were added to MircoMet, the meteorological distribution sub-model used in SnowModel. The inversions were observed and modeled to occur during 84% of the simulation period. Modeled inversions were defined not to occur during days with strong winds and high precipitation rates due to the potential of inversion break-up. Field observations showed inversions to extend from sea level to approximately 300 m a.s.l., and this inversion level was prescribed in the model simulations. Simulations with and without the inversion routines were compared. The inversion model produced air temperature distributions with warmer lower elevation areas and cooler higher elevation areas than without inversion routines due to the use of cold sea-breeze base temperature data from underneath the inversion. This yielded an up to 2 weeks earlier snowmelt in the lower areas and up to 1 to 3 weeks later snowmelt in the higher elevation areas of the simulation domain. Averaged mean annual modeled surface mass-balance for all glaciers (mainly located above the inversion layer) was -720 {+-} 620 mm w.eq. y{sup -1} for inversion simulations, and -880 {+-} 620 mm w.eq. y{sup -1} without the inversion routines, a difference of 160 mm w.eq. y

  9. Investigation of tungsten mass transfer in rarefied air oxygen and water vapors

    International Nuclear Information System (INIS)

    Evsikov, A.S.; Makeev, A.A.; Lyubimova, L.L.; Sinyavskij, V.V.

    1989-01-01

    The results of experimental investigations of oxygen and water vapor effect on the rate of tungsten evaporation are presented. Methods for carrying out an experiment are presented. The experiments are carried out at the 2600 degC tungsten wire temperature and the pressure of oxygen and water vapors (2x10 -3 -5) Pa. Registration of final products of mass transfer is carried out by the DRON-2.0 diffractometer using a detachable substrate. Empirical dependence taking into account oxygen and water vapor effect on the rate of tungsten evaporation is suggested. It is marked that air oxygen and water vapor increase evaporation rate uniformly the difference is observed only in final products of interaction

  10. Effects of Northern Hemisphere Sea Surface Temperature Changes on the Global Air Quality

    Science.gov (United States)

    Yi, K.; Liu, J.

    2017-12-01

    The roles of regional sea surface temperature (SST) variability on modulating the climate system and consequently the air quality are investigated using the Community Earth System Model (CESM). Idealized, spatially uniform SST anomalies of +/- 1 °C are superimposed onto the North Pacific, North Atlantic, and North Indian Oceans individually. Ignoring the response of natural emissions, our simulations suggest large seasonal and regional variability of surface O3 and PM2.5 concentrations in response to SST anomalies, especially during boreal summers. Increasing the SST by 1 °C in one of the oceans generally decreases the surface O3 concentrations from 1 to 5 ppbv while increases the anthropogenic PM2.5 concentrations from 0.5 to 3 µg m-3. We implement the integrated process rate (IPR) analysis in CESM and find that meteorological transport in response to SST changes is the key process causing air pollutant perturbations in most cases. During boreal summers, the increase in tropical SST over different ocean basins enhances deep convection, which significantly increases the air temperature over the upper troposphere and trigger large-scale subsidence over nearby and remote regions. These processes tend to increase tropospheric stability and suppress rainfall at lower mid-latitudes. Consequently, it reduces the vertical transport of O3 to the surface while facilitating the accumulation of PM2.5 concentrations over most regions. In addition, this regional SST warming may also considerably suppress intercontinental transport of air pollution as confirmed with idealized CO-like tracers. Our findings indicate a robust linkage between basin-scale SST variability and regional air quality, which can help local air quality management.

  11. Identification of aerosol types over an urban site based on air-mass trajectory classification

    Science.gov (United States)

    Pawar, G. V.; Devara, P. C. S.; Aher, G. R.

    2015-10-01

    Columnar aerosol properties retrieved from MICROTOPS II Sun Photometer measurements during 2010-2013 over Pune (18°32‧N; 73°49‧E, 559 m amsl), a tropical urban station in India, are analyzed to identify aerosol types in the atmospheric column. Identification/classification is carried out on the basis of dominant airflow patterns, and the method of discrimination of aerosol types on the basis of relation between aerosol optical depth (AOD500 nm) and Ångström exponent (AE, α). Five potential advection pathways viz., NW/N, SW/S, N, SE/E and L have been identified over the observing site by employing the NOAA-HYSPLIT air mass back trajectory analysis. Based on AE against AOD500 nm scatter plot and advection pathways followed five major aerosol types viz., continental average (CA), marine continental average (MCA), urban/industrial and biomass burning (UB), desert dust (DD) and indeterminate or mixed type (MT) have been identified. In winter, sector SE/E, a representative of air masses traversed over Bay of Bengal and Eastern continental Indian region has relatively small AOD (τpλ = 0.43 ± 0.13) and high AE (α = 1.19 ± 0.15). These values imply the presence of accumulation/sub-micron size anthropogenic aerosols. During pre-monsoon, aerosols from the NW/N sector have high AOD (τpλ = 0.61 ± 0.21), and low AE (α = 0.54 ± 0.14) indicating an increase in the loading of coarse-mode particles over Pune. Dominance of UB type in winter season for all the years (i.e. 2010-2013) may be attributed to both local/transported aerosols. During pre-monsoon seasons, MT is the dominant aerosol type followed by UB and DD, while the background aerosols are insignificant.

  12. Preservation of atomically clean silicon surfaces in air by contact bonding

    DEFF Research Database (Denmark)

    Grey, Francois; Ljungberg, Karin

    1997-01-01

    When two hydrogen-passivated silicon surfaces are placed in contact under cleanroom conditions, a weak bond is formed. Cleaving this bond under ultrahigh vacuum (UHV) conditions, and observing the surfaces with low energy electron diffraction and scanning tunneling microscopy, we find that the or...... reconstruction from oxidation in air, Contact bonding opens the way to novel applications of reconstructed semiconductor surfaces, by preserving their atomic structure intact outside of a UHV chamber. (C) 1997 American Institute of Physics.......When two hydrogen-passivated silicon surfaces are placed in contact under cleanroom conditions, a weak bond is formed. Cleaving this bond under ultrahigh vacuum (UHV) conditions, and observing the surfaces with low energy electron diffraction and scanning tunneling microscopy, we find...... that the ordered atomic structure of the surfaces is protected from oxidation, even after the bonded samples have been in air for weeks. Further, we show that silicon surfaces that have been cleaned and hydrogen-passivated in UHV can be contacted in UHV in a similarly hermetic fashion, protecting the surface...

  13. Improvement of Polytetrafluoroethylene Surface Energy by Repetitive Pulse Non-Thermal Plasma Treatment in Atmospheric Air

    International Nuclear Information System (INIS)

    Yang Guoqing; Zhang Guanjun; Zhang Wenyuan

    2011-01-01

    Improvement of polytetrafluoroethylene surface energy by non-thermal plasma treatment is presented, using a nanosecond-positive-edge repetitive pulsed dielectric barrier discharge generator in atmospheric air. The electrical parameters including discharging power, peak and density of micro-discharge current were calculated, and the electron energy was estimated. Surface treatment experiments of polytetrafluoroethylene films were conducted for both different applied voltages and different treating durations. Results show that the surface energy of polytetrafluoroethylene film could be improved to 40 mJ/m 2 or more by plasma treatment. Surface roughness measurement and surface X-ray photoelectron spectroscopy analysis indicate that there are chemical etching and implantation of polar oxygen groups in the sample surface treating process, resulting in the improvement of the sample surface energy. Compared with an AC source of 50 Hz, the dielectric barrier discharges generated by a repetitive pulsed source could provide higher peak power, lower mean power, larger micro-discharge current density and higher electron energy. Therefore, with the same applied peak voltage and treating duration, the improvement of polytetrafluoroethylene surface energy using repetitive pulsed plasma is more effective, and the plasma treatment process based on repetitive pulsed dielectric barrier discharges in air is thus feasible and applicable.

  14. Multitechnique characterisation of 304L surface states oxidised at high temperature in steam and air atmospheres

    Energy Technology Data Exchange (ETDEWEB)

    Mamede, Anne-Sophie, E-mail: anne-sophie.mamede@ensc-lille.fr [University Lille, CNRS, ENSCL, Centrale Lille, University Artois, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide, F-59000 Lille (France); Nuns, Nicolas, E-mail: nicolas.nuns@univ-lille1.fr [University Lille, CNRS, ENSCL, Centrale Lille, University Artois, UMR 8181 – UCCS – Unité de Catalyse et Chimie du Solide, F-59000 Lille (France); Cristol, Anne-Lise, E-mail: anne-lise.cristol@ec-lille.fr [University Lille, CNRS, Centrale Lille, Arts et Métiers Paris Tech, FRE 3723 – LML – Laboratoire de Mécanique de Lille, F-59000 Lille (France); Cantrel, Laurent, E-mail: laurent.cantrel@irsn.fr [Institut de Radioprotection et de Sûreté Nucléaire, PSN-RES, Cadarache, Saint Paul lez Durance, 13115 (France); Laboratoire de Recherche Commun IRSN-CNRS-Lille 1: «Cinétique Chimique, Combustion, Réactivité» (C3R), Cadarache, Saint Paul lez Durance, 13115 (France); Souvi, Sidi, E-mail: sidi.souvi@irsn.fr [Institut de Radioprotection et de Sûreté Nucléaire, PSN-RES, Cadarache, Saint Paul lez Durance, 13115 (France); Laboratoire de Recherche Commun IRSN-CNRS-Lille 1: «Cinétique Chimique, Combustion, Réactivité» (C3R), Cadarache, Saint Paul lez Durance, 13115 (France); and others

    2016-04-30

    Graphical abstract: - Highlights: • Mutitechnique characterisation of oxidised 304L. • Oxidation at high temperature under steam and air conditions of 304L stainless steel. • Chromium and manganese oxides formed in the outer layer. • Oxide profiles differ in air or steam atmosphere. - Abstract: In case of a severe accident occurring in a nuclear reactor, surfaces of the reactor coolant system (RCS), made of stainless steel (304L) rich in Cr (>10%) and Ni (8–12%), are oxidised. Fission products (FPs) are released from melt fuel and flow through the RCS. A part of them is deposited onto surfaces either by vapour condensation or by aerosol deposition mechanisms. To be able to understand the nature of interactions between these FPs and the RCS surfaces, a preliminary step is to characterize the RSC surface states in steam and air atmosphere at high temperatures. Pieces of 304L stainless steel have been treated in a flow reactor at two different temperatures (750 °C and 950 °C) for two different exposition times (24 h and 72 h). After surfaces analysing by a unique combination of surface analysis techniques (XPS, ToF-SIMS and LEIS), for 304L, the results show a deep oxide scale with multi layers and the outer layer is composed of chromium and manganese oxides. Oxide profiles differ in air or steam atmosphere. Fe{sub 2}O{sub 3} oxide is observed but in minor proportion and in all cases no nickel is detected near the surface. Results obtained are discussed and compared with the literature data.

  15. Ring waves as a mass transport mechanism in air-driven core-annular flows.

    Science.gov (United States)

    Camassa, Roberto; Forest, M Gregory; Lee, Long; Ogrosky, H Reed; Olander, Jeffrey

    2012-12-01

    Air-driven core-annular fluid flows occur in many situations, from lung airways to engineering applications. Here we study, experimentally and theoretically, flows where a viscous liquid film lining the inside of a tube is forced upwards against gravity by turbulent airflow up the center of the tube. We present results on the thickness and mean speed of the film and properties of the interfacial waves that develop from an instability of the air-liquid interface. We derive a long-wave asymptotic model and compare properties of its solutions with those of the experiments. Traveling wave solutions of this long-wave model exhibit evidence of different mass transport regimes: Past a certain threshold, sufficiently large-amplitude waves begin to trap cores of fluid which propagate upward at wave speeds. This theoretical result is then confirmed by a second set of experiments that show evidence of ring waves of annular fluid propagating over the underlying creeping flow. By tuning the parameters of the experiments, the strength of this phenomenon can be adjusted in a way that is predicted qualitatively by the model.

  16. Chemical separation of plutonium from air filters and preparation of filaments for resonance ionization mass spectroscopy

    International Nuclear Information System (INIS)

    Eberhardt, K.; Erdmann, N.; Funk, H.; Herrmann, G.; Naehler, A.; Passler, G.; Trautmann, N.; Urban, F.

    1995-01-01

    Resonance ionization mass spectroscopy (RIMS) is used for the determination of plutonium in environmental samples. A chemical procedure based on an ion-exchange technique for the separation of plutonium from a polycarbonate filter is described. The overall yield is about 60% as determined by α-particle spectroscopy. A technique for the subsequent preparation of samples for RIMS measurements is developed. Plutonium is electrode-posited as hydroxide and covered with a thin metallic layer. While heating such a sandwich filament the plutonium hydroxide is reduced to the metal and an atomic beam is evaporated from the surface, as required for RIMS. copyright American Institute of Physics 1995

  17. Heat Transfer and Mass Diffusion in Nanofluids over a Moving Permeable Convective Surface

    Directory of Open Access Journals (Sweden)

    Muhammad Qasim

    2013-01-01

    Full Text Available Heat transfer and mass diffusion in nanofluid over a permeable moving surface are investigated. The surface exhibits convective boundary conditions and constant mass diffusion. Effects of Brownian motion and thermophoresis are considered. The resulting partial differential equations are reduced into coupled nonlinear ordinary differential equations using suitable transformations. Shooting technique is implemented for the numerical solution. Velocity, temperature, and concentration profiles are analyzed for different key parameters entering into the problem. Performed comparative study shows an excellent agreement with the previous analysis.

  18. Volumes, Masses, and Surface Areas for Shippingport LWBR Spent Nuclear Fuel in a DOE SNF Canister

    International Nuclear Information System (INIS)

    J.W. Davis

    1999-01-01

    The purpose of this calculation is to estimate volumes, masses, and surface areas associated with (a) an empty Department of Energy (DOE) 18-inch diameter, 15-ft long spent nuclear fuel (SNF) canister, (b) an empty DOE 24-inch diameter, 15-ft long SNF canister, (c) Shippingport Light Water Breeder Reactor (LWBR) SNF, and (d) the internal basket structure for the 18-in. canister that has been designed specifically to accommodate Seed fuel from the Shippingport LWBR. Estimates of volumes, masses, and surface areas are needed as input to structural, thermal, geochemical, nuclear criticality, and radiation shielding calculations to ensure the viability of the proposed disposal configuration

  19. Sensitivity of Greenland Ice Sheet surface mass balance to surface albedo parameterization: a study with a regional climate model

    OpenAIRE

    Angelen, J. H.; Lenaerts, J. T. M.; Lhermitte, S.; Fettweis, X.; Kuipers Munneke, P.; Broeke, M. R.; Meijgaard, E.; Smeets, C. J. P. P.

    2012-01-01

    We present a sensitivity study of the surface mass balance (SMB) of the Greenland Ice Sheet, as modeled using a regional atmospheric climate model, to various parameter settings in the albedo scheme. The snow albedo scheme uses grain size as a prognostic variable and further depends on cloud cover, solar zenith angle and black carbon concentration. For the control experiment the overestimation of absorbed shortwave radiation (+6%) at the K-transect (west Greenland) for the period 2004–2009 is...

  20. Air-sea heat flux control on the Yellow Sea Cold Water Mass intensity and implications for its prediction

    Science.gov (United States)

    Zhu, Junying; Shi, Jie; Guo, Xinyu; Gao, Huiwang; Yao, Xiaohong

    2018-01-01

    The Yellow Sea Cold Water Mass (YSCWM), which occurs during summer in the central Yellow Sea, plays an important role in the hydrodynamic field, nutrient cycle and biological species. Based on water temperature observations during the summer from 1978 to 1998 in the western Yellow Sea, five specific YSCWM years were identified, including two strong years (1984 and 1985), two weak years (1989 and 1995) and one normal year (1992). Using a three-dimensional hydrodynamic model, the YSCWM formation processes in these five years were simulated and compared with observations. In general, the YSCWM began forming in spring, matured in summer and gradually disappeared in autumn of every year. The 8 °C isotherm was used to indicate the YSCWM boundary. The modelled YSCWM areas in the two strong years were approximately two times larger than those in the two weak years. Based on the simulations in the weak year of 1995, ten numerical experiments were performed to quantify the key factors influencing the YSCWM intensity by changing the initial water condition in the previous autumn, air-sea heat flux, wind, evaporation, precipitation and sea level pressure to those in the strong year of 1984, respectively. The results showed that the air-sea heat flux was the dominant factor influencing the YSCWM intensity, which contributed about 80% of the differences of the YSCWM average water temperature at a depth of 50 m. In addition, the air-sea heat flux in the previous winter had a determining effect, contributing more than 50% of the differences between the strong and weak YSCWM years. Finally, a simple formula for predicting the YSCWM intensity was established by using the key influencing factors, i.e., the sea surface temperature before the cooling season and the air-sea heat flux during the cooling season from the previous December to the current February. With this formula, instead of a complicated numerical model, we were able to roughly predict the YSCWM intensity for the

  1. Trace and surface analysis of ceramic layers of solid oxide fuel cells by mass spectrometry.

    Science.gov (United States)

    Becker, J S; Breuer, U; Westheide, J; Saprykin, A I; Holzbrecher, H; Nickel, H; Dietze, H J

    1996-06-01

    For the trace analysis of impurities in thick ceramic layers of a solid oxide fuel cell (SOFC) sensitive solid-state mass spectrometric methods, such as laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and radiofrequency glow discharge mass spectrometry (rf-GDMS) have been developed and used. In order to quantify the analytical results of LA-ICP-MS, the relative sensitivity coefficients of elements in a La(0.6)Sr(0.35)MnO(3) matrix have been determined using synthetic standards. Secondary ion mass spectrometry (SIMS) - as a surface analytical method - has been used to characterize the element distribution and diffusion profiles of matrix elements on the interface of a perovskite/Y-stabilized ZrO(2) layer. The application of different mass spectrometric methods for process control in the preparation of ceramic layers for the SOFC is described.

  2. Estimation of Daily Air Temperature Based on MODIS Land Surface Temperature Products over the Corn Belt in the US

    Directory of Open Access Journals (Sweden)

    Linglin Zeng

    2015-01-01

    Full Text Available Air temperature (Ta is a key input in a wide range of agroclimatic applications. Moderate Resolution Imaging Spectroradiometer (MODIS Ts (Land Surface Temperature (LST products are widely used to estimate daily Ta. However, only daytime LST (Ts-day or nighttime LST (Ts-night data have been used to estimate Tmax/Tmin (daily maximum or minimum air temperature, respectively. The relationship between Tmax and Ts-night, and the one between Tmin and Ts-day has not been studied. In this study, both the ability of Ts-night data to estimate Tmax and the ability of Ts-day data to estimate Tmin were tested and studied in the Corn Belt during the growing season (May–September from 2008 to 2012, using MODIS daily LST products from both Terra and Aqua. The results show that using Ts-night for estimating Tmax could result in a higher accuracy than using Ts-day for a similar estimate. Combining Ts-day and Ts-night, the estimation of Tmax was improved by 0.19–1.85, 0.37–1.12 and 0.26–0.93 °C for crops, deciduous forest and developed areas, respectively, when compared with using only Ts-day or Ts-night data. The main factors influencing the Ta estimation errors spatially and temporally were analyzed and discussed, such as satellite overpassing time, air masses, irrigation, etc.

  3. Meso-scale wrinkled coatings to improve heat transfers of surfaces facing ambient air

    International Nuclear Information System (INIS)

    Kakiuchida, Hiroshi; Tajiri, Koji; Tazawa, Masato; Yoshimura, Kazuki; Shimono, Kazuaki; Nakagawa, Yukio; Takahashi, Kazuhiro; Fujita, Keisuke; Myoko, Masumi

    2015-01-01

    Meso-scale (micrometer-to submillimeter-scale) wrinkled surfaces coated on steel sheets used in outdoor storage and transport facilities for industrial low-temperature liquids were discovered to efficiently increase convective heat transfer between ambient air and the surface. The radiative and convective heat transfer coefficients of various wrinkled surfaces, which were formed by coating steel sheets with several types of shrinkable paints, were examined. The convective heat transfer coefficient of a surface colder than ambient air monotonically changed with average height difference and interval distance of the wrinkle undulation, where the proportions were 0.0254 and 0.0054 W/m 2 /K/μm, respectively. With this wrinkled coating, users can lower the possibility of condensation and reduce rust and maintenance cost of facilities for industrial low-temperature liquids. From the point of view of manufacturers, this coating method can be easily adapted to conventional manufacturing processes. - Highlights: • Various wrinkled surfaces were fabricated by a practical process. • Topographical effect on convection was parameterized separately from radiation. • Meso-scale wrinkled coatings increased convective heat transfer with ambient air. • Maintenance cost of outdoor steel sheets due to condensation can be reduced

  4. Bioaccumulation Potential Of Air Contaminants: Combining Biological Allometry, Chemical Equilibrium And Mass-Balances To Predict Accumulation Of Air Pollutants In Various Mammals

    Energy Technology Data Exchange (ETDEWEB)

    Veltman, Karin; McKone, Thomas E.; Huijbregts, Mark A.J.; Hendriks, A. Jan

    2009-03-01

    In the present study we develop and test a uniform model intended for single compartment analysis in the context of human and environmental risk assessment of airborne contaminants. The new aspects of the model are the integration of biological allometry with fugacity-based mass-balance theory to describe exchange of contaminants with air. The developed model is applicable to various mammalian species and a range of chemicals, while requiring few and typically well-known input parameters, such as the adult mass and composition of the species, and the octanol-water and air-water partition coefficient of the chemical. Accumulation of organic chemicals is typically considered to be a function of the chemical affinity forlipid components in tissues. Here, we use a generic description of chemical affinity for neutral and polar lipids and proteins to estimate blood-air partition coefficients (Kba) and tissue-air partition coefficients (Kta) for various mammals. This provides a more accurate prediction of blood-air partition coefficients, as proteins make up a large fraction of total blood components. The results show that 75percent of the modeled inhalation and exhalation rate constants are within a factor of 2 from independent empirical values for humans, rats and mice, and 87percent of the predicted blood-air partition coefficients are within a factor of 5 from empirical data. At steady-state, the bioaccumulation potential of air pollutants is shown to be mainly a function of the tissue-air partition coefficient and the biotransformation capacity of the species and depends weakly on the ventilation rate and the cardiac output of mammals.

  5. Holographic optical tweezers for object manipulations at an air-liquid surface.

    Science.gov (United States)

    Jesacher, Alexander; Fürhapter, Severin; Maurer, Christian; Bernet, Stefan; Ritsch-Marte, Monika

    2006-06-26

    We investigate holographic optical tweezers manipulating micro-beads at a suspended air-liquid interface. Axial confinement of the particles in the two-dimensional interface is maintained by the interplay between surface tension and gravity. Therefore, optical trapping of the micro-beads is possible even with a long distance air objective. Efficient micro-circulation of the liquid can be induced by fast rotating beads, driven by the orbital angular momentum transfer of incident Laguerre-Gaussian (doughnut) laser modes. Our setup allows various ways of creating a tailored dynamic flow of particles and liquid within the surface. We demonstrate examples of surface manipulations like efficient vortex pumps and mixers, interactive particle flow steering by arrays of vortex pumps, the feasibility of achieving a "clocked" traffic of micro beads, and size-selective guiding of beads along optical "conveyor belts".

  6. Study of surface atmospheric pressure glow discharge plasma based on ultrathin laminated electrodes in air

    Science.gov (United States)

    Zhao, Luxiang; Liu, Wenzheng; Li, Zhiyi; Ma, Chuanlong

    2018-05-01

    A method to generate large-area surface plasma in air by micro-discharge is proposed. Two ultrathin laminated electrode structures of non-insulating and insulating types were formed by using the nanoscale ITO conductive layer. The surface glow discharge in atmospheric air is realized in low discharge voltage by constructing the special electric field of two-dimensional unidirectional attenuation. In particular, the insulating electrode structure can avoid the loss of ITO electrodes so that the discharge stability can be increased, and the treated objects can be prevented from metal ion pollution caused by the electrode in the discharge. It has broad application prospects in the fields of aerodynamics and material surface treatment.

  7. Influence of air mass source sector on variations in CO2 mixing ratio at a boreal site in northern Finland

    International Nuclear Information System (INIS)

    Aalto, T.; Hatakka, J.; Viisanen, Y.

    2003-01-01

    CO 2 mixing ratio in air masses coming from different source sectors was studied at Pallas measurement station in Lapland. Source sectors were defined using back trajectories and wind direction measurements. Air masses from the North and West sectors showed an annual variation of 17 ppm, possibly affected by a long range transported marine air. A larger variation of 20 ppm was observed in air masses from the more continental South and East sectors. During late autumn mixing ratios in air masses from the South sector were high in comparison with the other sectors. Different methods for a source sector definition were considered for the site, located in a contoured terrain. 52%-73% of wind direction-based source sector definitions agreed with trajectory- based definitions. However, the number of cases with reliable sector definitions may remain low when considering all observations. Different definition methods can cause differences of the order of 1 ppm in sectorially selected monthly mean CO 2 mixing ratios. (orig.)

  8. Surface topography of cylindrical gear wheels after smoothing in abrasive mass, honing and shot peening

    International Nuclear Information System (INIS)

    Michalski, J; Pawlus, P; Zelasko, W

    2011-01-01

    The present paper presents the analysis of surface topography of gear teeth as the result of final machining processes. Teeth of multiple cylindrical gears shaped by grinding were smoothed in abrasive mass, honed or shot peened. The measurement of gears were made using coordinate measuring machine and 3D surface topography stylus instrument. The following deviations were studied; pitch deviation, total pitches deviations, variation of teeth thickness and deviation of gear radial run-out. Changes in teeth surface topography during machining process were determined. 3D surface topography parameters, surface directionality as well as areal autocorrelation and power spectral density functions were taken into consideration. As the results of the analysis, the best surface topography with regard to gear operational properties was recommended.

  9. Physical aerosol properties and their relation to air mass origin at Monte Cimone (Italy during the first MINATROC campaign

    Directory of Open Access Journals (Sweden)

    R. Van Dingenen

    2005-01-01

    Full Text Available Aerosol physical properties were measured at the Monte Cimone Observatory (Italy from 1 June till 6 July 2000. The measurement site is located in the transition zone between the continental boundary layer and the free troposphere (FT, at the border between the Mediterranean area and Central Europe, and is exposed to a variety of air masses. Sub-μm number size distributions, aerosol hygroscopicity near 90% RH, refractory size distribution at 270°C and equivalent black carbon mass were continuously measured. Number size distributions and hygroscopic properties indicate that the site is exposed to aged continental air masses, however during daytime it is also affected by upslope winds. The mixing of this transported polluted boundary layer air masses with relatively clean FT air leads to frequent nucleation events around local noon. Night-time size distributions, including fine and coarse fractions for each air mass episode, have been parameterized by a 3-modal lognormal distribution. Number and volume concentrations in the sub-μm modes are strongly affected by the air mass origin, with highest levels in NW-European air masses, versus very clean, free tropospheric air coming from the N-European sector. During a brief but distinct dust episode, the coarse mode is clearly enhanced. The observed hygroscopic behavior of the aerosol is consistent with the chemical composition described by Putaud et al. (2004, but no closure between known chemical composition and measured hygroscopicity could be made because the hygroscopic properties of the water-soluble organic matter (WSOM are not known. The data suggest that WSOM is slightly-to-moderately hygroscopic (hygroscopic growth factor GF at 90% relative humidity between 1.05 and 1.51, and that this property may well depend on the air mass origin and history. External mixing of aerosol particles is observed in all air masses through the occurrence of two hygroscopicity modes (average GF of 1.22 and 1

  10. The secondary electron yield of air exposed metal surfaces at the example of niobium

    CERN Document Server

    Scheuerlein, C; Taborelli, M

    2002-01-01

    The secondary electron yield (SEY) variation of atomically clean metal surfaces due to air exposures and during subsequent heat treatments is described with the example of a sputter-deposited Nb thin film. Corresponding variations of the surface chemical composition have been monitored using AES and SSIMS. On the basis of these results and of previously obtained SEY results on metals and metal oxides the origin of the SEY variations is discussed. The SEY increase, which is generally observed during long lasting air exposures of clean metals, is mainly caused by the adsorption of an airborne carbonaceous contamination layer. The estimated value of about 3 for the maximum SEY of this layer is higher than that of all pure metals. Only in some cases the air-formed oxide can contribute to the air exposure induced SEY increase while many oxides have a lower SEY than their parent metals. From the experimental data it can also be excluded that the SEY increase during air exposures is mainly due to an increased second...

  11. Polytetrafluoroethylene surface modification by filamentary and homogeneous dielectric barrier discharges in air

    International Nuclear Information System (INIS)

    Fang Zhi; Hao Lili; Yang Hao; Xie Xiangqian; Qiu Yuchang; Edmund, Kuffel

    2009-01-01

    In this paper, polytetrafluoroethylene (PTFE) films are modified using non-equilibrium plasma generated by homogeneous DBD in air at medium pressure, and the results are compared to those treated by using filamentary DBD in air at atmospheric pressure. The surface properties of PTFE films before and after the treatments are studied using contact angle and surface energy measurement, X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). It is found that the plasma treatments modify the PTFE surface in both morphology and composition. The PTFE films modified in both treatments show a remarkable decrease in water contact and a remarkable increase in surface energy. XPS analysis reveals that oxygen-containing polar groups are introduced onto the PTFE surface, and SEM analysis shows that the surfaces of the films are etched after both the treatments. It is found that homogeneous DBD is more effective in PTFE surface modification than filamentary DBD as it can make the contact angle decline to a lower level by introducing more oxygen-containing groups, and the possible reason for this effect is discussed.

  12. Air Entrainment and Surface Ripples in a Turbulent Ship Hull Boundary Layer

    Science.gov (United States)

    Masnadi, Naeem; Erinin, Martin; Duncan, James H.

    2017-11-01

    The air entrainment and free-surface fluctuations caused by the interaction of a free surface and the turbulent boundary layer of a vertical surface-piercing plate is studied experimentally. In this experiment, a meter-wide stainless steel belt travels horizontally in a loop around two rollers with vertically oriented axes. This belt device is mounted inside a large water tank with the water level set just below the top edge of the belt. The belt, rollers, and supporting frame are contained within a sheet metal box to keep the device dry except for one 6-meter-long straight test section. The belt is accelerated suddenly from rest until reaching constant speed in order to create a temporally evolving boundary layer analogous to the spatially evolving boundary layer that would exist along a surface-piercing towed flat plate. Surface ripples are measured using a cinematic laser-induced fluorescence technique with the laser sheet oriented parallel or normal to the belt surface. Air entrainment events and bubble motions are recorded from underneath the water surface using a stereo imaging system. Measurements of small bubbles, that tend to stay submerged for a longer time, are planned via a high-speed digital in-line holographic system. The support of the Office of Naval Research is gratefully acknowledged.

  13. Condensation of steam on the underside of a horizontal surface in the presence of air and helium

    International Nuclear Information System (INIS)

    Stein, R.P.; Cho, D.H.; Lambert, G.A.

    1987-01-01

    Experiments and data analysis for the condensation of steam on the underside of a horizontal surface in a closed vessel are described. Previously reported results for film condensation with air as a noncondensable gas are reviewed and compared with new data with helium as the noncondensable in the same apparatus. Observations, including photographs of the condensate configurations, related to the occurrence of dropwise condensation are also discussed. It is noted that data reproducibility over long periods of time were possible only with film condensation and that with dropwise condensation condensing surface temperatures exhibited large nonuniformities and random fluctuations with time. The well known mass transfer calculational model for accounting for the presence of noncondensable gases had been shown previously to be successful with air. The same model when applied to the helium data was not successful except for small gas contents. It appears that the suppression of convection that would be expected to occur with the less dense gas is counteracted by convection induced by fog or mist formation

  14. Computational Analysis of Droplet Mass and Size Effect on Mist/Air Impingement Cooling Performance

    Directory of Open Access Journals (Sweden)

    Zhenglei Yu

    2013-01-01

    Full Text Available Impingement cooling has been widely employed to cool gas turbine hot components such as combustor liners, combustor transition pieces, turbine vanes, and blades. A promising technology is proposed to enhance impingement cooling with water droplets injection. However, previous studies were conducted on blade shower head film cooling, and less attention was given to the transition piece cooling. As a continuous effort to develop a realistic mist impingement cooling scheme, this paper focuses on simulating mist impingement cooling under typical gas turbine operating conditions of high temperature and pressure in a double chamber model. Furthermore, the paper presents the effect of cooling effectiveness by changing the mass and size of the droplets. Based on the heat-mass transfer analogy, the results of these experiments prove that the mass of 3E – 3 kg/s droplets with diameters of 5–35 μm could enhance 90% cooling effectiveness and reduce 122 K of wall temperature. The results of this paper can provide guidance for corresponding experiments and serve as the qualification reference for future more complicated studies with convex surface cooling.

  15. Surface mass balance and runoff modeling using HIRHAM4 RCM at Kangerlussuaq (Søndre Strømfjord), West Greenland, 1950-2080

    DEFF Research Database (Denmark)

    Mernild, Sebastian H.; Liston, Glen E.; Hiemstra, Christopher A.

    2011-01-01

    A regional atmospheric model, the HIRHAM4 regional climate model (RCM) using boundary conditions from the ECHAM5 atmosphere-ocean general circulation model (AOGCM), was downscaled to a 500-m gridcell increment using SnowModel to simulate 131 yr (1950-2080) of hydrologic cycle evolution in west...... Greenland's Kangerlussuaq drainage. Projected changes in the Greenland Ice Sheet (GrIS) surface mass balance (SMB) and runoff are relevant for potential hydropower production and prediction of ecosystem changes in sensitive Kangerlussuaq Fjord systems. Mean annual surface air temperatures and precipitation...

  16. Effects of platinum stagnation surface on the lean extinction limits of premixed methane/air flames at moderate surface temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Wiswall, J.T.; Li, J.; Wooldridge, M.S.; Im, H.G. [Department of Mechanical Engineering, University of Michigan, Ann Arbor, MI (United States)

    2011-01-15

    A stagnation flow reactor was used to study the effects of platinum on the lean flammability limits of atmospheric pressure premixed methane/air flames at moderate stagnation surface temperatures. Experimental and computational methods were used to quantify the equivalence ratio at the lean extinction limit ({phi}{sub ext}) and the corresponding stagnation surface temperature (T{sub s}). A range of flow rates (57-90 cm/s) and corresponding strain rates were considered. The results indicate that the gas-phase methane/air flames are sufficiently strong relative to the heterogeneous chemistry for T{sub s} conditions less than 750 K that the platinum does not affect {phi}{sub ext}. The computational results are in good agreement with the experimentally observed trends and further indicate that higher reactant flow rates (>139 cm/s) and levels of dilution (>{proportional_to}10% N{sub 2}) are required to weaken the gas-phase flame sufficiently for surface reaction to play a positive role on extending the lean flammability limits. (author)

  17. The surface emissions trap: a new approach in indoor air purification.

    Science.gov (United States)

    Markowicz, Pawel; Larsson, Lennart

    2012-11-01

    A new device for stopping or reducing potentially irritating or harmful emissions from surfaces indoors is described. The device is a surface emissions trap prototype and consists of an adsorbent sheet with a semipermeable barrier surrounded by two thin nonwoven layers. The trap may be applied directly at the source of the emissions e.g. at moisture-affected floors and walls, surfaces contaminated by chemical spills etc. This results in an immediate stop or reduction of the emitting pollutants. The trap has a very low water vapor resistance thus allowing drying of wet surfaces. In laboratory experiments typically 98% reduction of air concentrations of volatile organic compounds and a virtually total reduction of mold particle-associated mycotoxins was observed. The surface emissions trap may represent a convenient and efficient way of restoring indoor environments polluted by microbial and other moisture-associated emissions. Copyright © 2012 Elsevier B.V. All rights reserved.

  18. Experimental Study on the Tensile Strength and Linear Expansion Coefficient of Air Tunnel Terrazzo Surface

    Directory of Open Access Journals (Sweden)

    Boping Li

    2015-01-01

    Full Text Available At present, studies on the surface tension of air tunnel terrazzo under wind load and how regularly it is affected by temperature are relatively less, and the measured results of the thermal expansion coefficient of terrazzo have not yet been given. In this paper, based on the top terrazzo surface structure of the inner wall of the wind tunnel, the tensile performance tests of terrazzo surface layer are conducted, while the thermal expansion coefficient of the six terrazzo test blocks were tested. The tests and analysis show that the construction of terrazzo surface, based on the proposed construction process, can effectively guarantee the reliable cement performance for the binding layer between mortar and concrete base layer, terrazzo surface layer and the cement mortar layer. And the thermal expansion coefficient of terrazzo can be valued at 1.06e-5/ºC.

  19. Surface analysis of lipids by mass spectrometry: more than just imaging.

    Science.gov (United States)

    Ellis, Shane R; Brown, Simon H; In Het Panhuis, Marc; Blanksby, Stephen J; Mitchell, Todd W

    2013-10-01

    Mass spectrometry is now an indispensable tool for lipid analysis and is arguably the driving force in the renaissance of lipid research. In its various forms, mass spectrometry is uniquely capable of resolving the extensive compositional and structural diversity of lipids in biological systems. Furthermore, it provides the ability to accurately quantify molecular-level changes in lipid populations associated with changes in metabolism and environment; bringing lipid science to the "omics" age. The recent explosion of mass spectrometry-based surface analysis techniques is fuelling further expansion of the lipidomics field. This is evidenced by the numerous papers published on the subject of mass spectrometric imaging of lipids in recent years. While imaging mass spectrometry provides new and exciting possibilities, it is but one of the many opportunities direct surface analysis offers the lipid researcher. In this review we describe the current state-of-the-art in the direct surface analysis of lipids with a focus on tissue sections, intact cells and thin-layer chromatography substrates. The suitability of these different approaches towards analysis of the major lipid classes along with their current and potential applications in the field of lipid analysis are evaluated. Copyright © 2013 Elsevier Ltd. All rights reserved.

  20. Basin-scale heterogeneity in Antarctic precipitation and its impact on surface mass variability

    Directory of Open Access Journals (Sweden)

    J. Fyke

    2017-11-01

    Full Text Available Annually averaged precipitation in the form of snow, the dominant term of the Antarctic Ice Sheet surface mass balance, displays large spatial and temporal variability. Here we present an analysis of spatial patterns of regional Antarctic precipitation variability and their impact on integrated Antarctic surface mass balance variability simulated as part of a preindustrial 1800-year global, fully coupled Community Earth System Model simulation. Correlation and composite analyses based on this output allow for a robust exploration of Antarctic precipitation variability. We identify statistically significant relationships between precipitation patterns across Antarctica that are corroborated by climate reanalyses, regional modeling and ice core records. These patterns are driven by variability in large-scale atmospheric moisture transport, which itself is characterized by decadal- to centennial-scale oscillations around the long-term mean. We suggest that this heterogeneity in Antarctic precipitation variability has a dampening effect on overall Antarctic surface mass balance variability, with implications for regulation of Antarctic-sourced sea level variability, detection of an emergent anthropogenic signal in Antarctic mass trends and identification of Antarctic mass loss accelerations.

  1. Apparent Surface Free Energy of Polymer/Paper Composite Material Treated by Air Plasma

    Directory of Open Access Journals (Sweden)

    Konrad Terpiłowski

    2017-01-01

    Full Text Available Surface plasma treatment consists in changes of surface properties without changing internal properties. In this paper composite polymer/paper material is used for production of packaging in cosmetic industry. There are problems with bonding this material at the time of packaging production due to its properties. Composite surface was treated by air plasma for 1, 10, 20, and 30 s. The advancing and receding contact angles of water, formamide, and diiodomethane were measured using both treated and untreated samples. Apparent surface free energy was estimated using the hysteresis (CAH and Van Oss, Good, Chaudhury approaches (LWAB. Surface roughness was investigated using optical profilometry and identification of after plasma treatment emerging chemical groups was made by means of the XPS (X-ray photoelectron spectroscopy technique. After plasma treatment the values of contact angles decreased which is particularly evident for polar liquids. Apparent surface free energy increased compared to that of untreated samples. Changes of energy value are due to the electron-donor parameter of energy. This parameter increases as a result of adding polar groups at the time of surface plasma activation. Changes of surface properties are combination of increase of polar chemical functional groups, increase on the surface, and surface roughness increase.

  2. Improving Hydrophobicity of Glass Surface Using Dielectric Barrier Discharge Treatment in Atmospheric Air

    International Nuclear Information System (INIS)

    Fang Zhi; Qiu Yuchang; Wang Hui; Kuffel, E

    2007-01-01

    Non-thermal plasmas under atmospheric pressure are of great interest in industrial applications, especially in material surface treatment. In this paper, the treatment of a glass surface for improving hydrophobicity using the non-thermal plasma generated by dielectric barrier discharge (DBD) at atmospheric pressure in ambient air is conducted, and the surface properties of the glass before and after the DBD treatment are studied by using contact angle measurement, surface resistance measurement and wet flashover voltage tests. The effects of the applied voltage and time duration of DBD on the surface modification are studied, and the optimal conditions for the treatment are obtained. It is found that a layer of hydrophobic coating is formed on the glass surface after spraying a thin layer of silicone oil and undergoing the DBD treatment, and the improvement of hydrophobicity depends on DBD voltage and treating time. It seems that there exists an optimum treating time for a certain applied voltage of DBD during the surface treatment. The test results of thermal aging and chemical aging show that the hydrophobic layer has quite stable characteristics. The interaction mechanism between the DBD plasma and the glass surface is discussed. It is concluded that CH 3 and large molecule radicals can react with the radicals in the glass surface to replace OH, and the hydrophobicity of the glass surface is improved accordingly

  3. Higher surface mass balance of the Greenland ice sheet revealed by high - resolution climate modeling

    NARCIS (Netherlands)

    Ettema, Janneke; van den Broeke, Michiel R.; van Meijgaard, Erik; van de Berg, Willem Jan; Bamber, Jonathan L.; Box, Jason E.; Bales, Roger C.

    2009-01-01

    High‐resolution (∼11 km) regional climate modeling shows total annual precipitation on the Greenland ice sheet for 1958–2007 to be up to 24% and surface mass balance up to 63% higher than previously thought. The largest differences occur in coastal southeast Greenland, where the much higher

  4. An experimental study on mass loading of soil particles on plant surfaces

    International Nuclear Information System (INIS)

    Li, J. G.; Gerzabek, M. H.; Mueck, K.

    1994-01-01

    Radionuclide contaminated soil adhered to plant surfaces can contribute to human ingestion dose. To determine this contribution, a method of 46 Sc neutron activation analysis was established and tested, by which a detection limit of 0.05 mg soil per g dry plant biomass can be obtained. In the field and greenhouse experiment the mass loading of soil on ryegrass (Lolium perenne L.) and broadbean (Vicia faba L.) was investigated and the contribution from rainsplash and wind erosion were evaluated separately. Soil retained on plant surfaces in field conditions in Seibersdorf/Austria was 5.77 ± 1.44 mg soil per g dry plant for ryegrass and 9.51 ± 0.73 mg soil per g dry plant for broadbean. Estimates of contribution from rainsplash and wind erosion to soil contamination of plants during the experimental period are 68 % and 32 % for broadbean 47 % and 53 % for ryegrass respectively. Mass loading results from field studies indicate that soil adhesion on plant surfaces can contribute up to 23 % of plant 137 Cs contamination, the transfer factors modified by mass loading decline differently, depending on 137 Cs concentration of the soil and the soil mass adhered to plant surfaces. (author)

  5. An experimental study on mass loading of soil particles on plant surfaces

    International Nuclear Information System (INIS)

    Li, J.; Gerzabek, M.H.; Mueck, K.

    1994-03-01

    Radionuclide contaminated soil adhered to plant surfaces can contribute to human ingestion dose. To determine this contribution, a method of 46 Sc neutron activation analysis was established and tested, by which a detection limit of 0.05 mg soil per g dry plant biomass can be obtained. In the field and greenhouse experiment the mass loading of soil on ryegrass (Lolium perenne L.) and broad bean (Vicia faba L.) was investigated and the contribution from rainsplash and wind erosion were evaluated separately. Soil retained on plant surfaces in field conditions in Seibersdorf/Austria was 5.77 ± 1.44 mg soil per g dry plant for ryegrass and 9.51 ± 0.73 mg soil per g dry plant for broad bean. Estimates of contribution from rainsplash and wind erosion to soil contamination of plant during the experimental period are 68 % and 32 % for broadbean, 47 % and 53 % for ryegrass, respectively. Mass loading results from field studies indicate that soil adhesion on plant surfaces can contribute up to 23 % of plant 137 Cs contamination, the transfer factors modified by mass loading decline differently, depending on 137 Cs concentration of the soil and the soil mass adhered to plant surfaces. (authors)

  6. Ultrasensitive probing of the protein resistance of PEG surfaces by secondary ion mass spectrometry

    DEFF Research Database (Denmark)

    Kingshott, P.; McArthur, S.; Thissen, H.

    2002-01-01

    The highly sensitive surface analytical techniques X-ray photoelectron spectroscopy (XPS) and time-of-flight static secondary ion mass spectrometry (ToF-SIMS) were used to test the resistance of poly(ethylene glycol) (PEG) coatings towards adsorption of lysozyme (LYS) and fibronectin (FN). PEG co...

  7. Signal and noise in Gravity Recovery and Climate Experiment (GRACE) observed surface mass variations

    NARCIS (Netherlands)

    Schrama, E.J.O.; Wouters, B.; Lavallée, D.A.

    2007-01-01

    The Gravity Recovery and Climate Experiment (GRACE) product used for this study consists of 43 monthly potential coefficient sets released by the GRACE science team which are used to generate surface mass thickness grids expressed as equivalent water heights (EQWHs). We optimized both the smoothing

  8. Future climate warming increases Greenland ice sheet surface mass balance variability

    NARCIS (Netherlands)

    Fyke, J.G.; Vizcaino, M.; Lipscomb, W.; Price, S.

    2014-01-01

    The integrated surface mass balance (SMB) of the Greenland ice sheet (GrIS) has large interannual variability. Long-term future changes to this variability will affect GrIS dynamics, freshwater fluxes, regional oceanography, and detection of changes in ice volume trends. Here we analyze a simulated

  9. Greenland ice sheet surface mass balance: evaluating simulations and making projections with regional climate models

    NARCIS (Netherlands)

    Rae, J.G.L.; Aðalgeirsdóttir, G.; Edwards, T.L.; Fettweis, X.; Gregory, J.M.; Hewitt, H.T.; Lowe, J.A.; Lucas-Picher, P.; Mottram, R.H.; Payne, A.J.; Ridley, J.K.; Shannon, S.R.; van de Berg, W.J.; van de Wal, R.S.W.; van den Broeke, M.R.

    2012-01-01

    Four high-resolution regional climate models (RCMs) have been set up for the area of Greenland, with the aim of providing future projections of Greenland ice sheet surface mass balance (SMB), and its contribution to sea level rise, with greater accuracy than is possible from coarser-resolution

  10. Microbes at Surface-Air Interfaces: The Metabolic Harnessing of Relative Humidity, Surface Hygroscopicity, and Oligotrophy for Resilience

    Science.gov (United States)

    Stone, Wendy; Kroukamp, Otini; Korber, Darren R.; McKelvie, Jennifer; Wolfaardt, Gideon M.

    2016-01-01

    The human environment is predominantly not aqueous, and microbes are ubiquitous at the surface-air interfaces with which we interact. Yet microbial studies at surface-air interfaces are largely survival-oriented, whilst microbial metabolism has overwhelmingly been investigated from the perspective of liquid saturation. This study explored microbial survival and metabolism under desiccation, particularly the influence of relative humidity (RH), surface hygroscopicity, and nutrient availability on the interchange between these two phenomena. The combination of a hygroscopic matrix (i.e., clay or 4,000 MW polyethylene glycol) and high RH resulted in persistent measurable microbial metabolism during desiccation. In contrast, no microbial metabolism was detected at (a) hygroscopic interfaces at low RH, and (b) less hygroscopic interfaces (i.e., sand and plastic/glass) at high or low RH. Cell survival was conversely inhibited at high RH and promoted at low RH, irrespective of surface hygroscopicity. Based on this demonstration of metabolic persistence and survival inhibition at high RH, it was proposed that biofilm metabolic rates might inversely influence whole-biofilm resilience, with ‘resilience’ defined in this study as a biofilm’s capacity to recover from desiccation. The concept of whole-biofilm resilience being promoted by oligotrophy was supported in desiccation-tolerant Arthrobacter spp. biofilms, but not in desiccation-sensitive Pseudomonas aeruginosa biofilms. The ability of microbes to interact with surfaces to harness water vapor during desiccation was demonstrated, and potentially to harness oligotrophy (the most ubiquitous natural condition facing microbes) for adaptation to desiccation. PMID:27746774

  11. Air and Ground Surface Temperature Relations in a Mountainous Basin, Wolf Creek, Yukon Territory

    Science.gov (United States)

    Roadhouse, Emily A.

    The links between climate and permafrost are well known, but the precise nature of the relationship between air and ground temperatures remains poorly understood, particularly in complex mountain environments. Although previous studies indicate that elevation and potential incoming solar radiation (PISR) are the two leading factors contributing to the existence of permafrost at a given location, additional factors may also contribute significantly to the existence of mountain permafrost, including vegetation cover, snow accumulation and the degree to which individual mountain landscapes are prone to air temperature inversions. Current mountain permafrost models consider only elevation and aspect, and have not been able to deal with inversion effects in a systematic fashion. This thesis explores the relationship between air and ground surface temperatures and the presence of surface-based inversions at 27 sites within the Wolf Creek basin and surrounding area between 2001 and 2006, as a first step in developing an improved permafrost distribution TTOP model. The TTOP model describes the relationship between the mean annual air temperature and the temperature at the top of permafrost in terms of the surface and thermal offsets (Smith and Riseborough, 2002). Key components of this model are n-factors which relate air and ground climate by establishing the ratio between air and surface freezing (winter) and thawing (summer) degree-days, thus summarizing the surface energy balance on a seasonal basis. Here we examine (1) surface offsets and (2) freezing and thawing n-factor variability at a number of sites through altitudinal treeline in the southern Yukon. Thawing n-factors (nt) measured at individual sites remained relatively constant from one year to the next and may be related to land cover. During the winter, the insulating effect of a thick snow cover results in higher surface temperatures, while thin snow cover results in low surface temperatures more closely

  12. Exploring surface photoreaction dynamics using pixel imaging mass spectrometry (PImMS)

    Science.gov (United States)

    Kershis, Matthew D.; Wilson, Daniel P.; White, Michael G.; John, Jaya John; Nomerotski, Andrei; Brouard, Mark; Lee, Jason W. L.; Vallance, Claire; Turchetta, Renato

    2013-08-01

    A new technique for studying surface photochemistry has been developed using an ion imaging time-of-flight mass spectrometer in conjunction with a fast camera capable of multimass imaging. This technique, called pixel imaging mass spectrometry (PImMS), has been applied to the study of butanone photooxidation on TiO2(110). In agreement with previous studies of this system, it was observed that the main photooxidation pathway for butanone involves ejection of an ethyl radical into vacuum which, as confirmed by our imaging experiment, undergoes fragmentation after ionization in the mass spectrometer. This proof-of-principle experiment illustrates the usefulness and applicability of PImMS technology to problems of interest within the surface science community.

  13. Corporal surface as indicator of muscular mass in the adult of the masculine sex

    International Nuclear Information System (INIS)

    Fernandez Vieitez, Jorge Alberto

    2003-01-01

    With the objective of finding out the body surface area equation (BSA, m2) that is most suitable as indicator of musculature because of its higher correlation with the muscle mass (MM,kg), a correlation analysis was made between the MM and the BSA estimated by 11 weight and height-based formulae. Primary weight, height and MM data were obtained from these studies (N=41) in which MM was determined by cadaver dissection or by computerized axial tomography. A remarkable variability was observed in the BSA values estimated by 11 equations (F=59,7; p< 0,05). The correlation coefficients between the body surface estimated by different equations and the muscle mass were statistically significant and very similar. It was concluded that there is no BSA equation that is far better than the rest as muscle mass indicator. Mostellers equation is recommended due to its calculation simplicity

  14. Mass spectrum of secondary ions knocked-out from copper surface by argon ion beam

    International Nuclear Information System (INIS)

    Koval', A.G.; Bobkov, V.V.; Klimovskij, Yu.A.; Fogel', Ya.M.

    1976-01-01

    The mass-spectrum of secondary ions was studied within a mass range of 1-400. The ions were knocked-out by the beam of ions Ar + from the copper surface with different content of oxygen and sulphur solved in the volume. The studies were conducted at three temperatures of the target. The atomic and molecular ions of the metal matrix, volumetric impurities of metal and ions of chemical compounds molecules of the metal under study with gas particles adsorbed on its surface and atoms of the metal volumetric admixtures may be observed in the mass spectrum. Detection of secondary ions of the copper multi-atomic complexes and ions of these complexes compounds with the adsorbed molecules is of interest

  15. Physical modeling of the impingement of an air jet on a water surface; Modelado fisico de la incidencia de un chorro de aire sobre una superficie de agua

    Energy Technology Data Exchange (ETDEWEB)

    Solorzano-Lopez, J.; Ramirez-Argaez, M.A.; Zenit, R.

    2010-07-01

    The use of gas jets (oxygen) plays a key role in several steelmaking processes as in the Basic Oxygen Furnace (BOF) or in the Electric Arc Furnace (EAF). Those jets improve heat, mass and momentum transfer in the liquid metal, mixing of chemical species enhancing and govern the formation of foaming slag. In this work experimental measurements were performed to determine the dimensions of the cavity formed at the liquid free surface caused by a gas jet impinging on it; also velocities vectors were measured in the zone affected by the gas jet. avities were measured from images from high speed camera and the vector maps were obtained with a Particle Image Velocimetry (PIV) technique. Both velocities and cavities were determined as a function of the main process variables: gas flow rate, distance of the nozzle from the free surface and lance angle. Cavity dimensions were statistically processed treated as a function of the process variables and also as a function of the proper dimensionless numbers that govern these phenomena. It was found that Weber and Froude numbers govern the cavity geometry. Liquid flow driven by the jet is mainly affected by the air flow rate, lance height and angle. (Author).

  16. Past and future sea-level change from the surface mass balance of glaciers

    Directory of Open Access Journals (Sweden)

    B. Marzeion

    2012-11-01

    Full Text Available We present estimates of sea-level change caused by the global surface mass balance of glaciers, based on the reconstruction and projection of the surface mass balance of all the individual glaciers of the world, excluding the ice sheets in Greenland and Antarctica. The model is validated using a leave-one-glacier-out cross-validation scheme against 3997 observed surface mass balances of 255 glaciers, and against 756 geodetically observed, temporally integrated volume and surface area changes of 341 glaciers. When forced with observed monthly precipitation and temperature data, the glaciers of the world are reconstructed to have lost mass corresponding to 114 ± 5 mm sea-level equivalent (SLE between 1902 and 2009. Using projected temperature and precipitation anomalies from 15 coupled general circulation models from the Coupled Model Intercomparison Project phase 5 (CMIP5 ensemble, they are projected to lose an additional 148 ± 35 mm SLE (scenario RCP26, 166 ± 42 mm SLE (scenario RCP45, 175 ± 40 mm SLE (scenario RCP60, or 217 ± 47 mm SLE (scenario RCP85 during the 21st century. Based on the extended RCP scenarios, glaciers are projected to approach a new equilibrium towards the end of the 23rd century, after having lost either 248 ± 66 mm SLE (scenario RCP26, 313 ± 50 mm SLE (scenario RCP45, or 424 ± 46 mm SLE (scenario RCP85. Up until approximately 2100, ensemble uncertainty within each scenario is the biggest source of uncertainty for the future glacier mass loss; after that, the difference between the scenarios takes over as the biggest source of uncertainty. Ice mass loss rates are projected to peak 2040 ∼ 2050 (RCP26, 2050 ∼ 2060 (RCP45, 2070 ∼ 2090 (RCP60, or 2070 ∼ 2100 (RCP85.

  17. Characterization of simultaneous heat and mass transfer phenomena for water vapour condensation on a solid surface in an abiotic environment--application to bioprocesses.

    Science.gov (United States)

    Tiwari, Akhilesh; Kondjoyan, Alain; Fontaine, Jean-Pierre

    2012-07-01

    The phenomenon of heat and mass transfer by condensation of water vapour from humid air involves several key concepts in aerobic bioreactors. The high performance of bioreactors results from optimised interactions between biological processes and multiphase heat and mass transfer. Indeed in various processes such as submerged fermenters and solid-state fermenters, gas/liquid transfer need to be well controlled, as it is involved at the microorganism interface and for the control of the global process. For the theoretical prediction of such phenomena, mathematical models require heat and mass transfer coefficients. To date, very few data have been validated concerning mass transfer coefficients from humid air inflows relevant to those bioprocesses. Our study focussed on the condensation process of water vapour and developed an experimental set-up and protocol to study the velocity profiles and the mass flux on a small size horizontal flat plate in controlled environmental conditions. A closed circuit wind tunnel facility was used to control the temperature, hygrometry and hydrodynamics of the flow. The temperature of the active surface was controlled and kept isothermal below the dew point to induce condensation, by the use of thermoelectricity. The experiments were performed at ambient temperature for a relative humidity between 35-65% and for a velocity of 1.0 ms⁻¹. The obtained data are analysed and compared to available theoretical calculations on condensation mass flux.

  18. Role of urbanization and air pollution in adolescent asthma: a mass screening in Taiwan.

    Science.gov (United States)

    Lin, R S; Sung, F C; Huang, S L; Gou, Y L; Ko, Y C; Gou, H W; Shaw, C K

    2001-10-01

    The prevalence of asthma in school children in Taiwan is increasing. This study used mass screening among middle school children in Taiwan to determine the prevalence of asthma and related factors. Data were collected from parents using a self-reported questionnaire and from children using the International Study of Asthma and Allergies in Childhood (ISAAC) video questionnaire. Six study teams conducted the survey nationwide in 1995-1996, with the assistance of middle school nurses and teachers. Among the 1,018,031 students at 795 middle schools who returned questionnaires, 8.5% had a history of asthma (ranging in prevalence from 4.2% to 13% in 25 areas). The prevalence of asthma was higher in boys than in girls (10.0% vs 7%) and was highest in more urbanized areas (11.2%), followed by moderately urbanized areas (7.4%) and less urbanized and rural areas (6.5%). Controlling for age, family smoking, family incense burning, and parental education level, multivariate logistic regression models indicated that children living in an area with heavy air pollution were more likely to have asthma than those in an area with no or light pollution (odds ratio, OR = 2.01 and 95% confidence interval, CI = 1.94-2.09 based on parental ranking of pollution level, or OR = 1.30 and 95% CI = 1.18-1.42 based on pollution level reported by the Environmental Protection Administration). Adolescent asthma in Taiwan is most prevalent in the most urbanized areas and decreases in prevalence in less urbanized areas. This study also found that higher parental education level and higher area air pollution were associated with higher adolescent asthma prevalence.

  19. Extending and refining the nuclear mass surface with ISOLTRAP and MISTRAL

    CERN Document Server

    Lunney, M D

    2000-01-01

    Through the nuclear binding energy the atomic mass gives us important information about nuclear structure. Viewing the ensemble of mass data over the nuclear chart, we can examine the hills and valleys that form this surface and make hypotheses about the effects of certain nuclear configurations. To unveil these effects, mass measurements of very high precision (10$^{-6}$) are required. Two experiments at ISOLDE pursue this effort of nuclear cartography the tandem Penning trap spectrometer ISOLTRAP and the radiofrequency transmission spectrometer MISTRAL. Between them, the masses of almost 150 nuclides have been measured from stable isotopes to those with half-lives as short as 30 ms. Both experiments rely on good optical properties of a low energy ion beam and are thus well suited to the ISOLDE facility. (30 refs).

  20. Southeast Atlantic Cloud Properties in a Multivariate Statistical Model - How Relevant is Air Mass History for Local Cloud Properties?

    Science.gov (United States)

    Fuchs, Julia; Cermak, Jan; Andersen, Hendrik

    2017-04-01

    This study aims at untangling the impacts of external dynamics and local conditions on cloud properties in the Southeast Atlantic (SEA) by combining satellite and reanalysis data using multivariate statistics. The understanding of clouds and their determinants at different scales is important for constraining the Earth's radiative budget, and thus prominent in climate-system research. In this study, SEA stratocumulus cloud properties are observed not only as the result of local environmental conditions but also as affected by external dynamics and spatial origins of air masses entering the study area. In order to assess to what extent cloud properties are impacted by aerosol concentration, air mass history, and meteorology, a multivariate approach is conducted using satellite observations of aerosol and cloud properties (MODIS, SEVIRI), information on aerosol species composition (MACC) and meteorological context (ERA-Interim reanalysis). To account for the often-neglected but important role of air mass origin, information on air mass history based on HYSPLIT modeling is included in the statistical model. This multivariate approach is intended to lead to a better understanding of the physical processes behind observed stratocumulus cloud properties in the SEA.

  1. Interaction Mechanisms between Air Bubble and Molybdenite Surface: Impact of Solution Salinity and Polymer Adsorption.

    Science.gov (United States)

    Xie, Lei; Wang, Jingyi; Yuan, Duowei; Shi, Chen; Cui, Xin; Zhang, Hao; Liu, Qi; Liu, Qingxia; Zeng, Hongbo

    2017-03-07

    The surface characteristics of molybdenite (MoS 2 ) such as wettability and surface interactions have attracted much research interest in a wide range of engineering applications, such as froth flotation. In this work, a bubble probe atomic force microscope (AFM) technique was employed to directly measure the interaction forces between an air bubble and molybdenite mineral surface before/after polymer (i.e., guar gum) adsorption treatment. The AFM imaging showed that the polymer coverage on the surface of molybdenite could achieve ∼5.6, ∼44.5, and ∼100% after conditioning in 1, 5, and 10 ppm polymer solution, respectively, which coincided with the polymer coverage results based on contact angle measurements. The electrolyte concentration and surface treatment by polymer adsorption were found to significantly affect bubble-mineral interaction and attachment. The experimental force results on bubble-molybdenite (without polymer treatment) agreed well with the calculations using a theoretical model based on the Reynolds lubrication theory and augmented Young-Laplace equation including the effect of disjoining pressure. The overall surface repulsion was enhanced when the NaCl concentration decreased from 100 to 1 mM, which inhibited the bubble-molybdenite attachment. After conditioning the molybdenite surface in 1 ppm polymer solution, it was more difficult for air bubbles to attach to the molybdenite surface due to the weakened hydrophobic interaction with a shorter decay length. Increasing the polymer concentration to 5 ppm effectively inhibited bubble attachment on mineral surface, which was mainly due to the much reduced hydrophobic interaction as well as the additional steric repulsion between the extended polymer chains and bubble surface. The results provide quantitative information on the interaction mechanism between air bubbles and molybdenite mineral surfaces on the nanoscale, with useful implications for the development of effective polymer

  2. Surface plasmons based terahertz modulator consisting of silicon-air-metal-dielectric-metal layers

    Science.gov (United States)

    Wang, Wei; Yang, Dongxiao; Qian, Zhenhai

    2018-05-01

    An optically controlled modulator of the terahertz wave, which is composed of a metal-dielectric-metal structure etched with circular loop arrays on both the metal layers and a photoexcited silicon wafer separated by an air layer, is proposed. Simulation results based on experimentally measured complex permittivities predict that modification of complex permittivity of the silicon wafer through excitation laser leads to a significant tuning of transmission characteristics of the modulator, forming the modulation depths of 59.62% and 96.64% based on localized surface plasmon peak and propagating surface plasmon peak, respectively. The influences of the complex permittivity of the silicon wafer and the thicknesses of both the air layer and the silicon wafer are numerically studied for better understanding the modulation mechanism. This study proposes a feasible methodology to design an optically controlled terahertz modulator with large modulation depth, high speed and suitable insertion loss, which is useful for terahertz applications in the future.

  3. The air bubble entrapped under a drop impacting on a solid surface

    Science.gov (United States)

    Thoroddsen, S. T.; Etoh, T. G.; Takehara, K.; Ootsuka, N.; Hatsuki, Y.

    2005-12-01

    We present experimental observations of the disk of air caught under a drop impacting onto a solid surface. By imaging the impact through an acrylic plate with an ultra-high-speed video camera, we can follow the evolution of the air disk as it contracts into a bubble under the centre of the drop. The initial size and contraction speed of the disk were measured for a range of impact Weber and Reynolds numbers. The size of the initial disk is related to the bottom curvature of the drop at the initial contact, as measured in free-fall. The initial contact often leaves behind a ring of micro-bubbles, marking its location. The air disk contracts at a speed comparable to the corresponding air disks caught under a drop impacting onto a liquid surface. This speed also seems independent of the wettability of the liquid, which only affects the azimuthal shape of the contact line. For some impact conditions, the dynamics of the contraction leaves a small droplet at the centre of the bubble. This arises from a capillary wave propagating from the edges of the contracting disk towards the centre. As the wave converges its amplitude grows until it touches the solid substrate, thereby pinching off the micro-droplet at the plate, in the centre of the bubble. The effect of increasing liquid viscosity is to slow down the contraction speed and to produce a more irregular contact line leaving more micro-bubbles along the initial ring.

  4. Observationally constrained surface mass balance of Larsen C ice shelf, Antarctica

    Directory of Open Access Journals (Sweden)

    P. Kuipers Munneke

    2017-11-01

    Full Text Available The surface mass balance (SMB of the Larsen C ice shelf (LCIS, Antarctica, is poorly constrained due to a dearth of in situ observations. Combining several geophysical techniques, we reconstruct spatial and temporal patterns of SMB over the LCIS. Continuous time series of snow height (2.5–6 years at five locations allow for multi-year estimates of seasonal and annual SMB over the LCIS. There is high interannual variability in SMB as well as spatial variability: in the north, SMB is 0.40 ± 0.06 to 0.41 ± 0.04 m w.e. year−1, while farther south, SMB is up to 0.50 ± 0.05 m w.e. year−1. This difference between north and south is corroborated by winter snow accumulation derived from an airborne radar survey from 2009, which showed an average snow thickness of 0.34 m w.e. north of 66° S, and 0.40 m w.e. south of 68° S. Analysis of ground-penetrating radar from several field campaigns allows for a longer-term perspective of spatial variations in SMB: a particularly strong and coherent reflection horizon below 25–44 m of water-equivalent ice and firn is observed in radargrams collected across the shelf. We propose that this horizon was formed synchronously across the ice shelf. Combining snow height observations, ground and airborne radar, and SMB output from a regional climate model yields a gridded estimate of SMB over the LCIS. It confirms that SMB increases from north to south, overprinted by a gradient of increasing SMB to the west, modulated in the west by föhn-induced sublimation. Previous observations show a strong decrease in firn air content toward the west, which we attribute to spatial patterns of melt, refreezing, and densification rather than SMB.

  5. Ozone production using a power modulated surface dielectric barrier discharge in dry synthetic air

    Czech Academy of Sciences Publication Activity Database

    Šimek, Milan; Pekárek, S.; Prukner, Václav

    2012-01-01

    Roč. 32, č. 4 (2012), s. 743-754 ISSN 0272-4324 R&D Projects: GA ČR(CZ) GA202/09/0176 Institutional research plan: CEZ:AV0Z20430508 Keywords : ozone * surface DBD * synthetic air * nitrogen oxides * production efficiency Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 1.728, year: 2012 http://www.springerlink.com/content/h7p1j46381150510/fulltext.pdf

  6. Characterization of an atmospheric pressure air plasma source for polymer surface modification

    Science.gov (United States)

    Yang, Shujun; Tang, Jiansheng

    2013-10-01

    An atmospheric pressure air plasma source was generated through dielectric barrier discharge (DBD). It was used to modify polyethyleneterephthalate (PET) surfaces with very high throughput. An equivalent circuit model was used to calculate the peak average electron density. The emission spectrum from the plasma was taken and the main peaks in the spectrum were identified. The ozone density in the down plasma region was estimated by Absorption Spectroscopy. NSF and ARC-ODU

  7. A statistical method to get surface level air-temperature from satellite observations of precipitable water

    Digital Repository Service at National Institute of Oceanography (India)

    Pankajakshan, T.; Shikauchi, A; Sugimori, Y.; Kubota, M.

    -T a and precipitable water. The rms errors of the SSMI-T a , in this case are found to be reduced to 1.0°C. 1. Introduction Satellite derived surface-level meteorological parameters are considered to be a better alternative to sparse ship... Vol. 49, pp. 551 to 558. 1993 A Statistical Method to Get Surface Level Air-Temperature from Satellite Observations of Precipitable Water PANKAJAKSHAN THADATHIL*, AKIRA SHIKAUCHI, YASUHIRO SUGIMORI and MASAHISA KUBOTA School of Marine Science...

  8. Observed Screen (Air) and GCM Surface/Screen Temperatures: Implications for Outgoing Longwave Fluxes at the Surface.

    Science.gov (United States)

    Garratt, J. R.

    1995-05-01

    There is direct evidence that excess net radiation calculated in general circulation models at continental surfaces [of about 11-17 W m2 (20%-27%) on an annual ~1 is not only due to overestimates in annual incoming shortwave fluxes [of 9-18 W m2 (6%-9%)], but also to underestimates in outgoing longwave fluxes. The bias in the outgoing longwave flux is deduced from a comparison of screen-air temperature observations, available as a global climatology of mean monthly values, and model-calculated surface and screen-air temperatures. An underestimate in the screen temperature computed in general circulation models over continents, of about 3 K on an annual basis, implies an underestimate in the outgoing longwave flux, averaged in six models under study, of 11-15 W m2 (3%-4%). For a set of 22 inland stations studied previously, the residual bias on an annual basis (the residual is the net radiation minus incoming shortwave plus outgoing longwave) varies between 18 and 23 W m2 for the models considered. Additional biases in one or both of the reflected shortwave and incoming longwave components cannot be ruled out.

  9. Radiative warming of the air observed near a bare-soil surface on calm clear nights

    International Nuclear Information System (INIS)

    Sang, N.; Kobayahsi, T.

    1999-01-01

    The radiative flux in the lowest three meters above a bare-soil surface was directly measured on calm nights with little cloud cover. Although divergence of upward radiative flux occurred above 1m, convergence was often observed between 0.2m and 1m all through the night. Almost the same results were obtained for the net flux except that the transitional height between divergence and convergence was some tens of centimeters, which means that radiative warming occurred just above the bare-soil surface during the night. This phenomenon can be explained by postulating that cold air is produced by conduction at the surface of small heat-insulated projections (HIPs) such as soil grains on the ground surface, while the ground releases the heat stored during the day by radiation through the pores between HIPs and warms the air immediately above the surface at night. This “HIP hypothesis” can also account for the so-called “raised minimum (RM)” phenomenon. (author)

  10. The intraseasonal variability of winter semester surface air temperature in Antarctica

    Directory of Open Access Journals (Sweden)

    Lejiang Yu

    2011-02-01

    Full Text Available This study investigates systematically the intraseasonal variability of surface air temperature over Antarctica by applying empirical orthogonal function (EOF analysis to the National Centers for Environmental Prediction, US Department of Energy, Reanalysis 2 data set for the period of 1979 through 2007. The results reveal the existence of two major intraseasonal oscillations of surface temperature with periods of 26–30 days and 14 days during the Antarctic winter season in the region south of 60°S. The first EOF mode shows a nearly uniform spatial pattern in Antarctica and the Southern Ocean associated with the Antarctic Oscillation. The mode-1 intraseasonal variability of the surface temperature leads that of upper atmosphere by one day with the largest correlation at 300-hPa level geopotential heights. The intraseasonal variability of the mode-1 EOF is closely related to the variations of surface net longwave radiation the total cloud cover over Antarctica. The other major EOF modes reveal the existence of eastward propagating phases over the Southern Ocean and marginal region in Antarctica. The leading two propagating modes respond to Pacific–South American modes. Meridional winds induced by the wave train from the tropics have a direct influence on the surface air temperature over the Southern Ocean and the marginal region of the Antarctic continent.

  11. Microbial air quality and bacterial surface contamination in ambulances during patient services.

    Science.gov (United States)

    Luksamijarulkul, Pipat; Pipitsangjan, Sirikun

    2015-03-01

    We sought to assess microbial air quality and bacterial surface contamination on medical instruments and the surrounding areas among 30 ambulance runs during service. We performed a cross-sectional study of 106 air samples collected from 30 ambulances before patient services and 212 air samples collected during patient services to assess the bacterial and fungal counts at the two time points. Additionally, 226 surface swab samples were collected from medical instrument surfaces and the surrounding areas before and after ambulance runs. Groups or genus of isolated bacteria and fungi were preliminarily identified by Gram's stain and lactophenol cotton blue. Data were analyzed using descriptive statistics, t-test, and Pearson's correlation coefficient with a p-value of less than 0.050 considered significant. The mean and standard deviation of bacterial and fungal counts at the start of ambulance runs were 318±485cfu/m(3) and 522±581cfu/m(3), respectively. Bacterial counts during patient services were 468±607cfu/m(3) and fungal counts were 656±612cfu/m(3). Mean bacterial and fungal counts during patient services were significantly higher than those at the start of ambulance runs, p=0.005 and p=0.030, respectively. For surface contamination, the overall bacterial counts before and after patient services were 0.8±0.7cfu/cm(2) and 1.3±1.1cfu/cm(2), respectively (pair samples and bacterial counts on medical instruments and allocated areas. This study revealed high microbial contamination (bacterial and fungal) in ambulance air during services and higher bacterial contamination on medical instrument surfaces and allocated areas after ambulance services compared to the start of ambulance runs. Additionally, bacterial and fungal counts in ambulance air showed a significantly positive correlation with the bacterial surface contamination on medical instruments and allocated areas. Further studies should be conducted to determine the optimal intervention to reduce

  12. Cluster Analysis of the Organic Peaks in Bulk Mass Spectra Obtained During the 2002 New England Air Quality Study with an Aerodyne Aerosol Mass Spectrometer

    Science.gov (United States)

    Marcolli, C.; Canagaratna, M. R.; Worsnop, D. R.; Bahreini, R.; de Gouw, J. A.; Warneke, C.; Goldan, P. D.; Kuster, W. C.; Williams, E. J.; Lerner, B. M.; Roberts, J. M.; Meagher, J. F.; Fehsenfeld, F. C.; Marchewka, M.; Bertman, S. B.; Middlebrook, A. M.

    2006-12-01

    We applied hierarchical cluster analysis to an Aerodyne aerosol mass spectrometer (AMS) bulk mass spectral dataset collected aboard the NOAA research vessel R. H. Brown during the 2002 New England Air Quality Study off the east coast of the United States. Emphasizing the organic peaks, the cluster analysis yielded a series of categories that are distinguishable with respect to their mass spectra and their occurrence as a function of time. The differences between the categories mainly arise from relative intensity changes rather than from the presence or absence of specific peaks. The most frequent category exhibits a strong signal at m/z 44 and represents oxidized organic matter probably originating from both anthropogenic as well as biogenic sources. On the basis of spectral and trace gas correlations, the second most common category with strong signals at m/z 29, 43, and 44 contains contributions from isoprene oxidation products. The third through the fifth most common categories have peak patterns characteristic of monoterpene oxidation products and were most frequently observed when air masses from monoterpene rich regions were sampled. Taken together, the second through the fifth most common categories represent on average 17% of the total organic mass that stems likely from biogenic sources during the ship's cruise. These numbers have to be viewed as lower limits since the most common category was attributed to anthropogenic sources for this calculation. The cluster analysis was also very effective in identifying a few contaminated mass spectra that were not removed during pre-processing. This study demonstrates that hierarchical clustering is a useful tool to analyze the complex patterns of the organic peaks in bulk aerosol mass spectra from a field study.

  13. Cluster Analysis of the Organic Peaks in Bulk Mass Spectra Obtained During the 2002 New England Air Quality Study with an Aerodyne Aerosol Mass Spectrometer

    Directory of Open Access Journals (Sweden)

    C. Marcolli

    2006-01-01

    Full Text Available We applied hierarchical cluster analysis to an Aerodyne aerosol mass spectrometer (AMS bulk mass spectral dataset collected aboard the NOAA research vessel R. H. Brown during the 2002 New England Air Quality Study off the east coast of the United States. Emphasizing the organic peaks, the cluster analysis yielded a series of categories that are distinguishable with respect to their mass spectra and their occurrence as a function of time. The differences between the categories mainly arise from relative intensity changes rather than from the presence or absence of specific peaks. The most frequent category exhibits a strong signal at m/z 44 and represents oxidized organic matter probably originating from both anthropogenic as well as biogenic sources. On the basis of spectral and trace gas correlations, the second most common category with strong signals at m/z 29, 43, and 44 contains contributions from isoprene oxidation products. The third through the fifth most common categories have peak patterns characteristic of monoterpene oxidation products and were most frequently observed when air masses from monoterpene rich regions were sampled. Taken together, the second through the fifth most common categories represent on average 17% of the total organic mass that stems likely from biogenic sources during the ship's cruise. These numbers have to be viewed as lower limits since the most common category was attributed to anthropogenic sources for this calculation. The cluster analysis was also very effective in identifying a few contaminated mass spectra that were not removed during pre-processing. This study demonstrates that hierarchical clustering is a useful tool to analyze the complex patterns of the organic peaks in bulk aerosol mass spectra from a field study.

  14. Development of a Linear Ion Trap Mass Spectrometer (LITMS) Investigation for Future Planetary Surface Missions

    Science.gov (United States)

    Brinckerhoff, W.; Danell, R.; Van Ameron, F.; Pinnick, V.; Li, X.; Arevalo, R.; Glavin, D.; Getty, S.; Mahaffy, P.; Chu, P.; hide

    2014-01-01

    Future surface missions to Mars and other planetary bodies will benefit from continued advances in miniature sensor and sample handling technologies that enable high-performance chemical analyses of natural samples. Fine-scale (approx.1 mm and below) analyses of rock surfaces and interiors, such as exposed on a drill core, will permit (1) the detection of habitability markers including complex organics in association with their original depositional environment, and (2) the characterization of successive layers and gradients that can reveal the time-evolution of those environments. In particular, if broad-based and highly-sensitive mass spectrometry techniques could be brought to such scales, the resulting planetary science capability would be truly powerful. The Linear Ion Trap Mass Spectrometer (LITMS) investigation is designed to conduct fine-scale organic and inorganic analyses of short (approx.5-10 cm) rock cores such as could be acquired by a planetary lander or rover arm-based drill. LITMS combines both pyrolysis/gas chromatograph mass spectrometry (GCMS) of sub-sampled core fines, and laser desorption mass spectrometry (LDMS) of the intact core surface, using a common mass analyzer, enhanced from the design used in the Mars Organic Molecule Analyzer (MOMA) instrument on the 2018 ExoMars rover. LITMS additionally features developments based on the Sample Analysis at Mars (SAM) investigation on MSL and recent NASA-funded prototype efforts in laser mass spectrometry, pyrolysis, and precision subsampling. LITMS brings these combined capabilities to achieve its four measurement objectives: (1) Organics: Broad Survey Detect organic molecules over a wide range of molecular weight, volatility, electronegativity, concentration, and host mineralogy. (2) Organic: Molecular Structure Characterize internal molecular structure to identify individual compounds, and reveal functionalization and processing. (3) Inorganic Host Environment Assess the local chemical

  15. Air, water, and surface bacterial contamination in a university-hospital autopsy room.

    Science.gov (United States)

    Maujean, Géraldine; Malicier, Daniel; Fanton, Laurent

    2012-03-01

    Today, little is known about the bacteriological environment of the autopsy room and its potential interest for medico-legal practices. Seven hundred fifty microbiological samples were taken from surface (n = 660), air (n = 48), and water (n = 42) to evaluate it in a French University Forensic Department. Median bacterial counts were compared before and during autopsy for air samples, and before and after autopsy for surface samples, using Wilcoxon matched pairs signed ranks test. Bacterial identification relied on traditional phenotypic methods. Bacterial counts in the air were low before autopsy, increased significantly during procedure, and seemed more linked to the number of people in the room than to an important production of aerosol-containing bacteria. Despite cleaning, human fecal flora was omnipresent on surfaces, which revealed insufficient disinfection. Bacteriological sampling is an easy way to monitor cleaning practices in postmortem rooms, but chiefly a way to improve the reliability of medico-legal proofs of infectious deaths. © 2012 American Academy of Forensic Sciences.

  16. Filamentary superhydrophobic Teflon surfaces: Moderate apparent contact angle but superior air-retaining properties.

    Science.gov (United States)

    Di Mundo, Rosa; Bottiglione, Francesco; Palumbo, Fabio; Notarnicola, Michele; Carbone, Giuseppe

    2016-11-15

    Micro-scale textured Teflon surfaces, resulting from plasma etching modification, show extremely high water contact angle values and fairly good resistance to water penetration when hit by water drops at medium-high speed. This behavior is more pronounced when these surfaces present denser and smaller micrometric reliefs. Tailoring the top of these reliefs with a structure which further stabilizes the air may further increase resistance to wetting (water penetration) under static and dynamic conditions. Conditions of the oxygen fed plasma were tuned in order to explore the possibility of obtaining differently topped structures on the surface of the polymer. Scanning Electron Microscopy (SEM) was used to explore topography and X-ray Photoelectron Spectroscopy (XPS) to assess chemical similarity of the modified surfaces. Beside the usual advancing and receding water contact angle (WCA) measurements, surfaces were subjected to high speed impacting drops and immersion in water. At milder, i.e. shorter time and lower input power, plasma conditions formation of peculiar filaments is observed on the top of the sculpted reliefs. Filamentary topped surfaces result in a lower WCA than the spherical ones, appearing in this sense less superhydrophobic. However, these surfaces give rise to the formation of a more pronounced air layer when placed underwater. Further, when hit by water drops falling at medium/high speed, they show a higher resistance to water penetration and a sensitively lower surface-liquid contact time. The contact time is as low as previously observed only on heated solids. This behavior may be ascribed to the cavities formed beneath the filaments which, similarly with the salvinia leaf structures, require a surplus of pressure to be filled by water. Also, it suggests a different concept of superhydrophobicity, which cannot be expected on the basis of the conventional water contact angle characterization. Copyright © 2016 Elsevier Inc. All rights reserved.

  17. Surface modification on a glass surface with a combination technique of sol–gel and air brushing processes

    KAUST Repository

    Tsai, Meng-Yu; Hsu, Chin-Chi; Chen, Ping-Hei; Lin, Chao-Sung; Chen, Alexander

    2011-01-01

    This study fabricated the large area and optically transparent superhydrophobic silica based films on glass surface with optimized hardness. A silane coupling agent, tetraethoxysilane (TEOS), effectively bonds silica particles onto the glass substrate. Desired surface roughness was obtained by adjusting nano silica particles concentration of the precursors prepared by the sol-gel process. Silica suspension was coated onto the glass substrate by the air brushing methods. This method can deposit a uniform, transparent coating on the glass substrate efficiently. Diluting the precursor by adding ethanol or a mixture of D.I. water and ethanol further improved the transmittance and superhydrophobicity efficiency. The results showed that as the silica particle concentration and the thickness of the coating were increased, the surface roughness was enhanced. Rougher surface displayed a higher superhydrophobicity and lower transmittance. Therefore, the concentration of silica particle, volume of coatings, and the ratio of ethanol and D.I. water are of great importance to deposit a transparent, superhydrophobic coating on glass. © 2011 Elsevier B.V. All rights reserved.

  18. Surface modification on a glass surface with a combination technique of sol–gel and air brushing processes

    KAUST Repository

    Tsai, Meng-Yu

    2011-08-01

    This study fabricated the large area and optically transparent superhydrophobic silica based films on glass surface with optimized hardness. A silane coupling agent, tetraethoxysilane (TEOS), effectively bonds silica particles onto the glass substrate. Desired surface roughness was obtained by adjusting nano silica particles concentration of the precursors prepared by the sol-gel process. Silica suspension was coated onto the glass substrate by the air brushing methods. This method can deposit a uniform, transparent coating on the glass substrate efficiently. Diluting the precursor by adding ethanol or a mixture of D.I. water and ethanol further improved the transmittance and superhydrophobicity efficiency. The results showed that as the silica particle concentration and the thickness of the coating were increased, the surface roughness was enhanced. Rougher surface displayed a higher superhydrophobicity and lower transmittance. Therefore, the concentration of silica particle, volume of coatings, and the ratio of ethanol and D.I. water are of great importance to deposit a transparent, superhydrophobic coating on glass. © 2011 Elsevier B.V. All rights reserved.

  19. Mass

    International Nuclear Information System (INIS)

    Quigg, Chris

    2007-01-01

    In the classical physics we inherited from Isaac Newton, mass does not arise, it simply is. The mass of a classical object is the sum of the masses of its parts. Albert Einstein showed that the mass of a body is a measure of its energy content, inviting us to consider the origins of mass. The protons we accelerate at Fermilab are prime examples of Einsteinian matter: nearly all of their mass arises from stored energy. Missing mass led to the discovery of the noble gases, and a new form of missing mass leads us to the notion of dark matter. Starting with a brief guided tour of the meanings of mass, the colloquium will explore the multiple origins of mass. We will see how far we have come toward understanding mass, and survey the issues that guide our research today.

  20. Application of gas chromatography-surface ionization organic mass spectrometry to forensic toxicology.

    Science.gov (United States)

    Ishii, Akira; Watanabe-Suzuki, Kanako; Seno, Hiroshi; Suzuki, Osamu; Katsumata, Yoshinao

    2002-08-25

    Surface ionization (SI), which consists in the formation of positive and negative ions along the course of thermal desorption of particles from a solid surface, was first applied as a detector for gas chromatography (GC), GC-surface ionization detection (SID); we developed many new sensitive methods for the determination of abused and other drugs by GC-SID. Recently, Fujii has devised a combination of SI and a quadrupole mass spectrometer and named this system a surface ionization organic mass spectrometer (SIOMS), which is highly selective and sensitive for organic compounds containing tertiary amino groups. We have tried to apply this mass spectrometer to forensic toxicological study; so far we have succeeded in determining important drugs-of-abuse and toxic compounds, such as phencyclidine (PCP), pethidine, pentazocine, MPTP and its derivatives from human body fluids with high sensitivity and selectivity. In this review, we describe our recent studies on the application of GC-SIOMS to forensic toxicology. Copyright 2002 Elsevier Science B.V.

  1. Air mass exchange across the polar vortex edge during a simulated major stratospheric warming

    Directory of Open Access Journals (Sweden)

    G. Günther

    Full Text Available The dynamics of the polar vortex in winter and spring play an important role in explaining observed low ozone values. A quantification of physical and chemical processes is necessary to obtain information about natural and anthropogenic causes of fluctuations of ozone. This paper aims to contribute to answering the question of how permeable the polar vortex is. The transport into and out of the vortex ("degree of isolation" remains the subject of considerable debate. Based on the results of a three-dimensional mechanistic model of the middle atmosphere, the possibility of exchange of air masses across the polar vortex edge is investigated. Additionally the horizontal and vertical structure of the polar vortex is examined. The model simulation used for this study is related to the major stratospheric warming observed in February 1989. The model results show fair agreement with observed features of the major warming of 1989. Complex structures of the simulated polar vortex are illustrated by horizontal and vertical cross sections of potential vorticity and inert tracer. A three-dimensional view of the polar vortex enables a description of the vortex as a whole. During the simulation two vortices and an anticyclone, grouped together in a very stable tripolar structure, and a weaker, more amorphous anticyclone are formed. This leads to the generation of small-scale features. The results also indicate that the permeability of the vortex edges is low because the interior of the vortices remain isolated during the simulation.

  2. Air mass exchange across the polar vortex edge during a simulated major stratospheric warming

    Directory of Open Access Journals (Sweden)

    G. Günther

    1995-07-01

    Full Text Available The dynamics of the polar vortex in winter and spring play an important role in explaining observed low ozone values. A quantification of physical and chemical processes is necessary to obtain information about natural and anthropogenic causes of fluctuations of ozone. This paper aims to contribute to answering the question of how permeable the polar vortex is. The transport into and out of the vortex ("degree of isolation" remains the subject of considerable debate. Based on the results of a three-dimensional mechanistic model of the middle atmosphere, the possibility of exchange of air masses across the polar vortex edge is investigated. Additionally the horizontal and vertical structure of the polar vortex is examined. The model simulation used for this study is related to the major stratospheric warming observed in February 1989. The model results show fair agreement with observed features of the major warming of 1989. Complex structures of the simulated polar vortex are illustrated by horizontal and vertical cross sections of potential vorticity and inert tracer. A three-dimensional view of the polar vortex enables a description of the vortex as a whole. During the simulation two vortices and an anticyclone, grouped together in a very stable tripolar structure, and a weaker, more amorphous anticyclone are formed. This leads to the generation of small-scale features. The results also indicate that the permeability of the vortex edges is low because the interior of the vortices remain isolated during the simulation.

  3. Assessment of air mass ventilation potential in and around Bhabha Atomic Research Centre Trombay

    International Nuclear Information System (INIS)

    Jana, R.; Vinod Kumar, A.

    2016-01-01

    Aim of the present study is quantification of airborne pollutant dispersion potential in and around Bhabha Atomic Research Centre Trombay, a coastal belt of Arabian sea. Apart from synoptic atmospheric circulation, there is local land-sea interactive breezes diurnally in the area for which air mass ventilation potential is assessed here. For this purpose, a micro-meteorological station was established at Mandala hill top representing Trombay area to measure 3 dimensional wind components, i.e. Zonal: u, meridional: v and vertical: w, using ultrasonic anemometer. Hourly wind speed and wind direction are derived in this study for a period of 1 year, January-December 2013. Accuracy of wind components measurement is 0.1 m/s. This covers low wind condition too, i.e. wind speed below 1 m/s. Hourly statistics of year-long as well as seasonal period of wind field and associated parameters reveals the uniqueness of wind field phenomenon at the site being situated in west coast. Seasonal Wind Roses captures various frequencies of wind speed and wind direction for the respective periods

  4. THE INITIAL MASS FUNCTION AND THE SURFACE DENSITY PROFILE OF NGC 6231

    Energy Technology Data Exchange (ETDEWEB)

    Sung, Hwankyung [Department of Astronomy and Space Science, Sejong University, 98, Kunja-dong, Kwangjin-gu, Seoul 143-747 (Korea, Republic of); Sana, Hugues [Astronomical Institute ' Anton Pannekeok' , Amsterdam University, Science Park 904, 1098-XH Amsterdam (Netherlands); Bessell, Michael S., E-mail: sungh@sejong.ac.kr, E-mail: H.Sana@uva.nl, E-mail: bessell@mso.anu.edu.au [Research School of Astronomy and Astrophysics, Australian National University, MSO, Cotter Road, Weston, ACT 2611 (Australia)

    2013-02-01

    We have performed new wide-field photometry of the young open cluster NGC 6231 to study the shape of the initial mass function (IMF) and mass segregation. We also investigated the reddening law toward NGC 6231 from optical to mid-infrared color excess ratios, and found that the total-to-selective extinction ratio is R{sub V} = 3.2, which is very close to the normal value. But many early-type stars in the cluster center show large color excess ratios. We derived the surface density profiles of four member groups, and found that they reach the surface density of field stars at about 10', regardless of stellar mass. The IMF of NGC 6231 is derived for the mass range 0.8-45 M{sub Sun }. The slope of the IMF of NGC 6231 ({Gamma} = -1.1 {+-} 0.1) is slightly shallower than the canonical value, but the difference is marginal. In addition, the mass function varies systematically, and is a strong function of radius-it is very shallow at the center, and very steep at the outer ring suggesting the cluster is mass segregated. We confirm the mass segregation for the massive stars (m {approx}> 8 M{sub Sun }) by a minimum spanning tree analysis. Using a Monte Carlo method, we estimate the total mass of NGC 6231 to be about 2.6 ({+-} 0.6) Multiplication-Sign 10{sup 3} M{sub Sun }. We constrain the age of NGC 6231 by comparison with evolutionary isochrones. The age of the low-mass stars ranges from 1 to 7 Myr with a slight peak at 3 Myr. However, the age of the high-mass stars depends on the adopted models and is 3.5 {+-} 0.5 Myr from the non-rotating or moderately rotating models of Brott et al. as well as the non-rotating models of Ekstroem et al. But the age is 4.0-7.0 Myr if the rotating models of Ekstroem et al. are adopted. This latter age is in excellent agreement with the timescale of ejection of the high-mass runaway star HD 153919 from NGC 6231, albeit the younger age cannot be entirely excluded.

  5. Application of »Mass Titration« to Determination of Surface Charge of Metal Oxides

    OpenAIRE

    1998-01-01

    The mass titration method, used for the point of zero charge determination, was extended to the measurement of the surface charge density. The results agree with the common method, which is the acid-base titration of the colloidal suspension. The advantage of mass titration is that one does not need to perform blank titration, instead one simply adds metal oxide powder to the electrolyte aqueous solution of known pH. To cover the pH range above and below the point of zero charge, two experime...

  6. Mass composition studies using the surface detector of the Pierre Auger Observatory

    International Nuclear Information System (INIS)

    Wahlberg, Hernan

    2009-01-01

    The mass composition of ultra-high energy cosmic rays is a critical issue to understand their origin and nature. The Pierre Auger Observatory is a hybrid instrument which provides a powerful environment for the determination of the primary mass. The Surface Detector of the Pierre Auger Observatory alone allows the study of several shower parameters with high discriminating power between primary elements. Novel analysis techniques using different features of signals in the Cherenkov stations are discussed. These are the signal risetime, the azimuthal time asymmetry and the muon density of the showers.

  7. Effect of mass density on surface morphology of electrodeposited manganese oxide films

    Science.gov (United States)

    Singh, Avtar; Kumar, Davinder; Thakur, Anup; Kaur, Raminder

    2018-05-01

    This work focus on high surface area morphology of manganese oxide films which are currently required for electrochemical capacitor electrode to enhance their performance. Electrodeposition of manganese oxide films was carried out using Chronoamperometry for different deposition time ranging from 30 to 120 sec. Cronoamperomertic I-T integrated data have been used to analyze active mass of all electrodeposited films. Morphological study of the deposited films with different mass was carried out through scanning electron microscopy. Film deposited for 30 sec time show highest porous morphology than others. Manganese oxide films with high porosity are suitable for electrochemical capacitor electrode.

  8. The impact of mass flow and masking on the pressure drop of air filter in heavy-duty diesel engine

    Directory of Open Access Journals (Sweden)

    Gorji-Bandpy Mofid

    2012-04-01

    Full Text Available This paper presents a computational fluid dynamics (CFD calculation approach to predict and evaluate the impact of the mass-flow inlet on the pressure drop of turbocharger`s air filtfer in heavy-duty diesel engine. The numerical computations were carried out using a commercial CFD program whereas the inlet area of the air filter consisted of several holes connected to a channel. After entering through the channel, the air passes among the holes and enters the air filter. The effect of masking holes and hydraulic diameter is studied and investigated on pressure drop. The results indicate that pressure drop increase with decreasing of hydraulic diameter and masking of the holes has considerable affect on the pressure drop.

  9. Evaluating Greenland glacial isostatic adjustment corrections using GRACE, altimetry and surface mass balance data

    International Nuclear Information System (INIS)

    Sutterley, Tyler C; Velicogna, Isabella; Csatho, Beata; Rezvan-Behbahani, Soroush; Babonis, Greg; Van den Broeke, Michiel

    2014-01-01

    Glacial isostatic adjustment (GIA) represents a source of uncertainty for ice sheet mass balance estimates from the Gravity Recovery and Climate Experiment (GRACE) time-variable gravity measurements. We evaluate Greenland GIA corrections from Simpson et al (2009 Quat. Sci. Rev. 28 1631–57), A et al (2013 Geophys. J. Int. 192 557–72) and Wu et al (2010 Nature Geosci. 3 642–6) by comparing the spatial patterns of GRACE-derived ice mass trends calculated using the three corrections with volume changes from ICESat (Ice, Cloud, and land Elevation Satellite) and OIB (Operation IceBridge) altimetry missions, and surface mass balance products from the Regional Atmospheric Climate Model (RACMO). During the period September 2003–August 2011, GRACE ice mass changes obtained using the Simpson et al (2009 Quat. Sci. Rev. 28 1631–57) and A et al (2013 Geophys. J. Int. 192 557–72) GIA corrections yield similar spatial patterns and amplitudes, and are consistent with altimetry observations and surface mass balance data. The two GRACE estimates agree within 2% on average over the entire ice sheet, and better than 15% in four subdivisions of Greenland. The third GRACE estimate corrected using the (Wu et al 2010 Nature Geosci. 3 642–6)) GIA shows similar spatial patterns, but produces an average ice mass loss for the entire ice sheet that is 64 − 67 Gt yr −1 smaller. In the Northeast the recovered ice mass change is 46–49 Gt yr −1 (245–270%) more positive than that deduced from the other two corrections. By comparing the spatial and temporal variability of the GRACE estimates with trends of volume changes from altimetry and surface mass balance from RACMO, we show that the Wu et al (2010 Nature Geosci. 3 642–6) correction leads to a large mass increase in the Northeast that is inconsistent with independent observations. (paper)

  10. Surface modification of chitosan/PEO nanofibers by air dielectric barrier discharge plasma for acetylcholinesterase immobilization

    Energy Technology Data Exchange (ETDEWEB)

    Dorraki, Naghme, E-mail: n.dorraki@web.sbu.ac.ir [Laser and Plasma Research Institute, Shahid Beheshti University, Evin 1983963113, Tehran (Iran, Islamic Republic of); Safa, Nasrin Navab [Laser and Plasma Research Institute, Shahid Beheshti University, Evin 1983963113, Tehran (Iran, Islamic Republic of); Jahanfar, Mehdi [Protein Research Center, Shahid Beheshti University, Evin 1983963113, Tehran (Iran, Islamic Republic of); Ghomi, Hamid [Laser and Plasma Research Institute, Shahid Beheshti University, Evin 1983963113, Tehran (Iran, Islamic Republic of); Ranaei-Siadat, Seyed-Omid [Protein Research Center, Shahid Beheshti University, Evin 1983963113, Tehran (Iran, Islamic Republic of)

    2015-09-15

    Highlights: • We used an economical and effective method for surface modification. • Chitosan/PEO nanofibrous membranes were modified by air-DBD plasma. • The most NH{sub 3}{sup +} group was generated on the 6 min plasma modified membrane. • We immobilized acetylcholinesterase on the plasma modified and unmodified membranes. • More enzyme activity was detected on the modified membrane by plasma. - Abstract: There are different methods to modify polymer surfaces for biological applications. In this work we have introduced air-dielectric barrier discharge (DBD) plasma at atmospheric pressure as an economical and safe method for modifying the surface of electrospun chitosan/PEO (90/10) nanofibers for acetylcholinesterase (AChE) immobilization. According to the contact angle measurement results, the nanofibers become highly hydrophilic when they are exposed to the DBD plasma for 6 min in compared to unmodified membrane. Attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR) results reveal hydroxyl, C=O and NH{sub 3}{sup +} polar groups increment after 6 min plasma treatment. Contact angle measurements and ATR-FTIR results are confirmed by X-ray photoelectron spectroscopy (XPS). AChE at pH 7.4 carries a negative charge and after immobilization on the surface of plasma-treated nanofibrous membrane attracts the NH{sub 3}{sup +} group and more enzyme activity is detected on the plasma-modified nanofibers for 6 min in compared to unmodified nanofibers. Atomic force microscopy (AFM) and scanning electron microscopy (SEM) are used for the surface topography and morphology characterization. The results have proved that air-DBD plasma is a suitable method for chitosan/PEO nanofibrous membrane modification as a biodegradable and functionalized substrate for enzyme immobilization.

  11. Mass spectrometric investigation of synthetic glycoside of muramyl dipeptide immobilized on fumed silica surface

    Energy Technology Data Exchange (ETDEWEB)

    Kulik, Tetiana V., E-mail: tanyakulyk@gala.net [O.O. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, 17 Generala Naumova Str., Kyiv 03164 (Ukraine); Azizova, Liana R., E-mail: liana_azizova@ukr.net [O.O. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, 17 Generala Naumova Str., Kyiv 03164 (Ukraine); Palyanytsya, Borys B. [O.O. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, 17 Generala Naumova Str., Kyiv 03164 (Ukraine); Zemlyakov, Alexander E.; Tsikalova, Victoria N. [Vernadsky Tauric National University, pr. Akademika Vernadskogo 4, Simferopol, 95007 (Ukraine)

    2010-05-25

    N-Acetylmuramyl-L-alanyl-D-isoglutamine or muramyl dipeptide is a cleavage product of peptidoglycan by lysozyme. This study explored the use of the temperature-programmed desorption mass spectrometry (TPDMS) in analysis of glycoside of muramyl dipeptide: O-{l_brace}(4-tert-butylcyclohexyl)-2-acetamido-2, 3-dideoxy-{beta}-D-glucopyranoside-3-yl{r_brace}-D-lactoyl-L-alanyl-D-isoglutamine (MDP) on the surface of fumed silica. Stages of pyrolysis of MDP in condensed state and on the silica surface have been determined. Three stages have been clear identified under pyrolysis of MDP on the silica surface. Kinetic parameters of thermal reactions on the fumed silica surface and in the condensed state have been calculated.

  12. Detachment of polystyrene particles from collector surfaces by surface tension forces induced by air-bubble passage through a parallel plate flow chamber

    NARCIS (Netherlands)

    Wit, PJ; vanderMei, HC; Busscher, HJ

    1997-01-01

    By allowing an air-bubble to pass through a parallel plate flow chamber with negatively charged, colloidal polystyrene particles adhering to the bottom collector plate of the chamber, the detachment of adhering particles stimulated by surface tension forces induced by the passage of a liquid-air

  13. Greenland Ice Sheet Surface Temperature, Melt, and Mass Loss: 2000-2006

    Science.gov (United States)

    Hall, Dorothy K.; Williams, Richard S., Jr.; Luthcke, Scott B.; DiGirolamo, Nocolo

    2007-01-01

    Extensive melt on the Greenland Ice Sheet has been documented by a variety of ground and satellite measurements in recent years. If the well-documented warming continues in the Arctic, melting of the Greenland Ice Sheet will likely accelerate, contributing to sea-level rise. Modeling studies indicate that an annual or summer temperature rise of 1 C on the ice sheet will increase melt by 20-50% therefore, surface temperature is one of the most important ice-sheet parameters to study for analysis of changes in the mass balance of the ice-sheet. The Greenland Ice Sheet contains enough water to produce a rise in eustatic sea level of up to 7.0 m if the ice were to melt completely. However, even small changes (centimeters) in sea level would cause important economic and societal consequences in the world's major coastal cities thus it is extremely important to monitor changes in the ice-sheet surface temperature and to ultimately quantify these changes in terms of amount of sea-level rise. We have compiled a high-resolution, daily time series of surface temperature of the Greenland Ice Sheet, using the I-km resolution, clear-sky land-surface temperature (LST) standard product from the Moderate-Resolution Imaging Spectroradiometer (MODIS), from 2000 - 2006. We also use Gravity Recovery and Climate Experiment (GRACE) data, averaged over 10-day periods, to measure change in mass of the ice sheet as it melt and snow accumulates. Surface temperature can be used to determine frequency of surface melt, timing of the start and the end of the melt season, and duration of melt. In conjunction with GRACE data, it can also be used to analyze timing of ice-sheet mass loss and gain.

  14. Surface ignition behaviors of methane–air mixture in a gas oven burner

    International Nuclear Information System (INIS)

    Ryu, Jungwan; Kwon, Jongseo; Kim, Ryanggyun; Kim, Minseong; Kim, Youngsoo; Jeon, Chunghwan; Song, Juhun

    2014-01-01

    In a gas oven burner, commonly used as a residential appliance, a surface igniter is a critical component for creating a pilot flame near the surface that can propagate safely back to the nozzle of the burner. The igniter should meet critical operating requirements: a lower surface temperature needed to ignite a methane–air mixture and a stable/safe ignition sustained. Otherwise, such failure would result in an instantaneous peak in carbon monoxide emission and a safety hazard inside a closed oven. Several theoretical correlations have been used to predict ignition temperature as well as the critical ignition/extinction limit for a stagnation flow ignition. However, there have only been a few studies on ignition modes or relevant stability analysis, and therefore a more detailed examination of the transient ignition process is required. In this study, a high-speed flame visualization technique with temperature measurement was employed to reveal a surface ignition phenomenon and subsequent flame propagation of a cold combustible methane–air mixture in a gas oven burner. The operating parameters were the temperature–time history of the igniter surface, mixture velocity, and the distance of the igniter from the nozzle. The surface ignition temperatures were analyzed for such parameters under a safe ignition mode, while several abnormal modes leading to ignition failure were also recognized. - Highlights: •We revealed a surface ignition behavior of combustible mixture in gas oven burner. •We employed a flame visualization technique with temperature measurement. •We evaluated effects of parameters such as lifetime, mixture velocity and igniter distance. •We recognized several abnormal modes leading to ignition failure

  15. Uncertainties in surface mass and energy flux estimates due to different eddy covariance sensors and technical set-up

    Science.gov (United States)

    Arriga, Nicola; Fratini, Gerardo; Forgione, Antonio; Tomassucci, Michele; Papale, Dario

    2010-05-01

    Eddy covariance is a well established and widely used methodology for the measurement of turbulent fluxes of mass and energy in the atmospheric boundary layer, in particular to estimate CO2/H2O and heat exchange above ecologically relevant surfaces (Aubinet 2000, Baldocchi 2003). Despite its long term application and theoretical studies, many issues are still open about the effect of different experimental set-up on final flux estimates. Open issues are the evaluation of the performances of different kind of sensors (e.g. open path vs closed path infra-red gas analysers, vertical vs horizontal mounting ultrasonic anemometers), the quantification of the impact of corresponding physical corrections to be applied to get robust flux estimates taking in account all processes concurring to the measurement (e.g. the so-called WPL term, signal attenuation due to air sampling system for closed path analyser, relative position of analyser and anemometer) and the differences between several data transmission protocols used (analogue, digital RS-232, SDM). A field experiment was designed to study these issues using several instruments among those most used within the Fluxnet community and to compare their performances under conditions supposed to be critical: rainy and cold weather conditions for open-path analysers (Burba 2008), water transport and absorption at high air relative humidity conditions for closed-path systems (Ibrom, 2007), frequency sampling limits and recorded data robustness due to different transmission protocols (RS232, SDM, USB, Ethernet) and finally the effect of the displacement between anemometer and analyser using at least two identical analysers placed at different horizontal and vertical distances from the anemometer. Aim of this experiment is to quantify the effect of several technical solutions on the final estimates of fluxes measured at a point in the space and if they represent a significant source of uncertainty for mass and energy cycle

  16. Highly sensitive determination of polycyclic aromatic hydrocarbons in ambient air dust by gas chromatography-mass spectrometry after molecularly imprinted polymer extraction

    Energy Technology Data Exchange (ETDEWEB)

    Krupadam, Reddithota J.; Bhagat, Bhagyashree; Khan, Muntazir S. [National Environmental Engineering Research Institute, Nagpur (India)

    2010-08-15

    A method based on solid-phase extraction with a molecularly imprinted polymer (MIP) has been developed to determine five probable human carcinogenic polycyclic aromatic hydrocarbons (PAHs) in ambient air dust by gas chromatography-mass spectrometry (GC-MS). Molecularly imprinted poly(vinylpyridine-co-ethylene glycol dimethacrylate) was chosen as solid-phase extraction (SPE) material for PAHs. The conditions affecting extraction efficiency, for example surface properties, concentration of PAHs, and equilibration times were evaluated and optimized. Under optimum conditions, pre-concentration factors for MIP-SPE ranged between 80 and 93 for 10 mL ambient air dust leachate. PAHs recoveries from MIP-SPE after extraction from air dust were between 85% and 97% and calibration graphs of the PAHs showed a good linearity between 10 and 1000 ng L{sup -1} (r=0.99). The extraction efficiency of MIP for PAHs was compared with that of commercially available SPE materials - powdered activated carbon (PAC) and polystyrene-divinylbenzene resin (XAD) - and it was shown that the extraction capacity of the MIP was better than that of the other two SPE materials. Organic matter in air dust had no effect on MIP extraction, which produced a clean extract for GC-MS analysis. The detection limit of the method proposed in this article is 0.15 ng L{sup -1} for benzo[a]pyrene, which is a marker molecule of air pollution. The method has been applied to the determination of probable carcinogenic PAHs in air dust of industrial zones and satisfactory results were obtained. (orig.)

  17. Highly sensitive determination of polycyclic aromatic hydrocarbons in ambient air dust by gas chromatography-mass spectrometry after molecularly imprinted polymer extraction.

    Science.gov (United States)

    Krupadam, Reddithota J; Bhagat, Bhagyashree; Khan, Muntazir S

    2010-08-01

    A method based on solid--phase extraction with a molecularly imprinted polymer (MIP) has been developed to determine five probable human carcinogenic polycyclic aromatic hydrocarbons (PAHs) in ambient air dust by gas chromatography-mass spectrometry (GC-MS). Molecularly imprinted poly(vinylpyridine-co-ethylene glycol dimethacrylate) was chosen as solid-phase extraction (SPE) material for PAHs. The conditions affecting extraction efficiency, for example surface properties, concentration of PAHs, and equilibration times were evaluated and optimized. Under optimum conditions, pre-concentration factors for MIP-SPE ranged between 80 and 93 for 10 mL ambient air dust leachate. PAHs recoveries from MIP-SPE after extraction from air dust were between 85% and 97% and calibration graphs of the PAHs showed a good linearity between 10 and 1000 ng L(-1) (r = 0.99). The extraction efficiency of MIP for PAHs was compared with that of commercially available SPE materials--powdered activated carbon (PAC) and polystyrene-divinylbenzene resin (XAD)--and it was shown that the extraction capacity of the MIP was better than that of the other two SPE materials. Organic matter in air dust had no effect on MIP extraction, which produced a clean extract for GC-MS analysis. The detection limit of the method proposed in this article is 0.15 ng L(-1) for benzo[a]pyrene, which is a marker molecule of air pollution. The method has been applied to the determination of probable carcinogenic PAHs in air dust of industrial zones and satisfactory results were obtained.

  18. Atmospheric pressure surface sampling/ionization techniques for direct coupling of planar separations with mass spectrometry.

    Science.gov (United States)

    Pasilis, Sofie P; Van Berkel, Gary J

    2010-06-18

    Planar separations, which include thin layer chromatography and gel electrophoresis, are in widespread use as important and powerful tools for conducting separations of complex mixtures. To increase the utility of planar separations, new methods are needed that allow in situ characterization of the individual components of the separated mixtures. A large number of atmospheric pressure surface sampling and ionization techniques for use with mass spectrometry have emerged in the past several years, and several have been investigated as a means for mass spectrometric read-out of planar separations. In this article, we review the atmospheric pressure surface sampling and ionization techniques that have been used for the read-out of planar separation media. For each technique, we briefly explain the operational basics and discuss the analyte type for which it is appropriate and some specific applications from the literature. Copyright (c) 2010 Elsevier B.V. All rights reserved.

  19. Re-discovering surface mass spectrometry: chemical mapping from micro to macro

    Energy Technology Data Exchange (ETDEWEB)

    Lloyd, K.G.; O' Keefe, D.P

    2004-06-15

    New developments in electronics, devices, micro-encapsulation, and other areas demand the ability to acquire molecularly-specific information from smaller and smaller features. ToF-SIMS provides molecularly-specific mass spectral data, but sufficient high-mass signal has historically been difficult to obtain from organic/polymeric surfaces in the point-mapping mode of operation. Use of chemometric data reduction methods and the development of heavier primary ion sources enhance and extend the chemical information in the mapping data. Large-area chemical mapping via sample stage rastering has also opened up new applications. This capability allows single-experiment mapping of large or multiple features, provides information on surface uniformity over end-use-relevant areas, and offers potential for combinatorial and other screening applications. Examples of these applications are presented.

  20. Investigation of Simultaneous Effects of Aerosol Properties and Aerosol Peak Height on the Air Mass Factors for Space-Borne NO2 Retrievals

    Directory of Open Access Journals (Sweden)

    Hyunkee Hong

    2017-02-01

    Full Text Available We investigate the simultaneous effects of aerosol peak height (APH, aerosol properties, measurement geometry, and other factors on the air mass factor for NO2 retrieval at sites with high NO2 concentration. A comparison of the effects of high and low surface reflectance reveals that NO2 air mass factor (AMF values over a snowy surface (surface reflectance 0.8 are generally higher than those over a deciduous forest surface (surface reflectance 0.05. Under high aerosol optical depth (AOD conditions, the aerosol shielding effect over a high-albedo surface is revealed to reduce the path-length of light at the surface, whereas high single scattering albedo (SSA conditions (e.g., SSA = 0.95 lead to an increase in the aerosol albedo effect, which results in an increased AMF over areas with low surface reflectance. We also conducted an in-depth study of the APH effect on AMF. For an AOD of 0.1 and half width (HW of 5 km, NO2 AMF decreases by 29% from 1.36 to 0.96 as APH changes from 0 to 2 km. In the case of high-AOD conditions (0.9 and HW of 5 km, the NO2 AMF decreases by 240% from 1.85 to 0.54 as APH changes from 0 to 2 km. The AMF variation due to error in the model input parameters (e.g., AOD, SSA, aerosol shape, and APH is also examined. When APH is 0 km with an AOD of 0.4, SSA of 0.88, and surface reflectance of 0.05, a 30% error in AOD induces an AMF error of between 4.85% and −3.67%, an SSA error of 0.04 leads to NO2 VCD errors of between 4.46% and −4.77%, and a 30% error in AOD induces an AMF error of between −9.53% and 8.35% with an APH of 3 km. In addition to AOD and SSA, APH is an important factor in calculating AMF, due to the 2 km error in APH under high-SZA conditions, which leads to an NO2 VCD error of over 60%. Aerosol shape is also found to have a measureable effect on AMF under high-AOD and small relative azimuth angle (RAA conditions. The diurnal effect of the NO2 profile is also examined and discussed.

  1. A passive air sampler for characterizing the vertical concentration profile of gaseous phase polycyclic aromatic hydrocarbons in near soil surface air

    International Nuclear Information System (INIS)

    Zhang Yuzhong; Deng Shuxing; Liu Yanan; Shen Guofeng; Li Xiqing; Cao Jun; Wang Xilong; Reid, Brian; Tao Shu

    2011-01-01

    Air-soil exchange is an important process governing the fate of polycyclic aromatic hydrocarbons (PAHs). A novel passive air sampler was designed and tested for measuring the vertical concentration profile of 4 low molecular weight PAHs in gaseous phase (PAH LMW4 ) in near soil surface air. Air at various heights from 5 to 520 mm above the ground was sampled by polyurethane foam disks held in down-faced cartridges. The samplers were tested at three sites: A: an extremely contaminated site, B: a site near A, and C: a background site on a university campus. Vertical concentration gradients were revealed for PAH LMW4 within a thin layer close to soil surface at the three sites. PAH concentrations either decreased (Site A) or increased (Sites B and C) with height, suggesting either deposition to or evaporation from soils. The sampler is a useful tool for investigating air-soil exchange of gaseous phase semi-volatile organic chemicals. - Research highlights: → Design, field test and calibration of the novel passive air sampler, PAS-V-I. → Vertical concentration gradients of PAH LMW4 within a thin layer close to soil. → Comparison of results between PAS-V-I measurement and fugacity approach. → Potential application of PAS-V-I and further modifications. - A novel passive sampling device was developed and tested for measuring vertical concentration profile of gaseous phase polycyclic aromatic hydrocarbons in near soil surface air.

  2. Quantitative Caffeine Analysis Using a Surface Sampling Probe Electrospray Ionization Tandem Mass Spectrometry System

    Energy Technology Data Exchange (ETDEWEB)

    Ford, Michael J [ORNL; Deibel, Michael A. [Earlham College; Tomkins, Bruce A [ORNL; Van Berkel, Gary J [ORNL

    2005-01-01

    Quantitative determination of caffeine on reversed-phase C8 thin-layer chromatography plates using a surface sampling electrospray ionization system with tandem mass spectrometry detection is reported. The thin-layer chromatography/electrospray tandem mass spectrometry method employed a deuterium-labeled caffeine internal standard and selected reaction monitoring detection. Up to nine parallel caffeine bands on a single plate were sampled in a single surface scanning experiment requiring 35 min at a surface scan rate of 44 {mu}m/s. A reversed-phase HPLC/UV caffeine assay was developed in parallel to assess the mass spectrometry method performance. Limits of detection for the HPLC/UV and thin-layer chromatography/electrospray tandem mass spectrometry methods determined from the calibration curve statistics were 0.20 ng injected (0.50 {mu}L) and 1.0 ng spotted on the plate, respectively. Spike recoveries with standards and real samples ranged between 97 and 106% for both methods. The caffeine content of three diet soft drinks (Diet Coke, Diet Cherry Coke, Diet Pepsi) and three diet sport drinks (Diet Turbo Tea, Speed Stack Grape, Speed Stack Fruit Punch) was measured. The HPLC/UV and mass spectrometry determinations were in general agreement, and these values were consistent with the quoted values for two of the three diet colas. In the case of Diet Cherry Coke and the diet sports drinks, the determined caffeine amounts using both methods were consistently higher (by 8% or more) than the literature values.

  3. Characterization of NOx-Ox relationships during daytime interchange of air masses over a mountain pass in the Mexico City megalopolis

    Science.gov (United States)

    García-Yee, J. S.; Torres-Jardón, R.; Barrera-Huertas, H.; Castro, T.; Peralta, O.; García, M.; Gutiérrez, W.; Robles, M.; Torres-Jaramillo, J. A.; Ortínez-Álvarez, A.; Ruiz-Suárez, L. G.

    2018-03-01

    The role of the Tenango del Aire mountain pass, located southeast of the Mexico City Metropolitan Area (MCMA), in venting the city's air pollution has already been studied from a meteorological standpoint. To better understand the transport of gaseous air pollutants through the Tenango del Aire Pass (TAP), and its influence on the air quality of the MCMA, three mobile air quality monitoring units were deployed during a 31-day field campaign between February and March of 2011. Surface O3, NOx, and meteorological variables were continuously measured at the three sites. Vertical profiles of O3 and meteorological variables were also obtained at one of the sites using a tethered balloon. Days were classified as being under low pressure synoptic systems (LPS, 13 days), high pressure synoptic systems (HPS, 13 days), or as transition days (TR). The Mexican ozone standards at the Pass were not exceeded during LPS days, but were exceeded on almost all HPS days. A detailed analysis was performed using data from two typical days, one representative of LPS and the other of HPS. In both cases, morning vertical profiles of O3 showed a strong thermal inversion layer and near-surface O3 titration due to fresh NOx. In the LPS early morning, a single O3 layer of close to 45 ppb was observed from 150 to 700 magl. In the HPS early morning, 50 ppb was observed from 150 to 400 magl followed by a 400-m-thick layer with up to 80 ppb. These layers were the source of the morning increase of O3, with a simultaneous sharp decrease of NOx and CO as the mixing layer started to rise. During the LPS day, a southerly wind dominated throughout most of the daytime, with surface O3 lower than 60 ppb. The same was observed for the well-mixed midday and afternoon vertical profiles. Under HPS, northerly winds transported photochemically active air masses from the MCMA all morning, as observed by a smoother increase of Ox and O3, reaching 110 ppb of O3. Just after midday, the wind shifted back, carrying

  4. Stark effect of excitons in corrugated lateral surface superlattices: effect of centre-of-mass quantization

    International Nuclear Information System (INIS)

    Hong Sun

    1998-11-01

    The quantum confined Stark effect (QCSE) of excitons in GaAs/AlAs corrugated lateral surface superlattices (CLSSLs) is calculated. Blue and red shifts in the exciton energies are predicted for the heavy- and light-excitons in the CLSSLs, respectively, comparing with those in the unmodulated quantum well due to the different effective hole masses in the parallel direction. Sensitive dependence of the QCSE on the hole effective mass in the parallel direction is expected because of the ''centre-of-mass'' quantization (CMQ) induced by the periodic corrugated interfaces of the CLSSLs. The effect of the CMQ on the exciton mini-bands and the localization of the excitons in the CLSSLs is discussed. (author)

  5. Modeling the improvement of ultrafiltration membrane mass transfer when using biofiltration pretreatment in surface water applications.

    Science.gov (United States)

    Netcher, Andrea C; Duranceau, Steven J

    2016-03-01

    In surface water treatment, ultrafiltration (UF) membranes are widely used because of their ability to supply safe drinking water. Although UF membranes produce high-quality water, their efficiency is limited by fouling. Improving UF filtrate productivity is economically desirable and has been attempted by incorporating sustainable biofiltration processes as pretreatment to UF with varying success. The availability of models that can be applied to describe the effectiveness of biofiltration on membrane mass transfer are lacking. In this work, UF water productivity was empirically modeled as a function of biofilter feed water quality using either a quadratic or Gaussian relationship. UF membrane mass transfer variability was found to be governed by the dimensionless mass ratio between the alkalinity (ALK) and dissolved organic carbon (DOC). UF membrane productivity was optimized when the biofilter feed water ALK to DOC ratio fell between 10 and 14. Copyright © 2015 Elsevier Ltd. All rights reserved.

  6. Estructura vertical, temporal y espacial de las masas de aire extremas en la República Argentina en invierno Vertical, temporal and spatial structure of the extreme air masses in Argentine during winter

    Directory of Open Access Journals (Sweden)

    Alejandra S Coronel

    2006-12-01

    Full Text Available Se identificó la masa de aire a través de la temperatura potencial adiabática equivalente (θae en 850 hPa, en Resistencia, Ezeiza y Comodoro Rivadavia, en los inviernos del período 1959/1991. Se definieron las masas extremas frías y cálidas a partir del primer y último quintil de θae en 850 hPa., respectivamente, y se analizó el primer día de ocurrencia de estas masas: evento frío y evento cálido. La selección de eventos extremos realizada es un discriminante estadísticamente significativo en el comportamiento de los parámetros de superficie como temperatura, presión y humedad en diferentes horas del día. En los días previos y posteriores a la ocurrencia del evento frío se identificó: en superficie un máximo de presión, un mínimo de temperatura que ocurre el día del evento y una mayor probabilidad de precipitación previa a la ocurrencia del evento. En la tropósfera se manifestó un máximo enfriamiento y estabilización de la masa de aire a partir del día del evento. Con referencia al evento cálido se pudo identificar: en superficie un mínimo de presión y un máximo de temperatura y una mayor probabilidad de precipitación posterior a la ocurrencia del evento. En la tropósfera se observó el máximo calentamiento el día del evento.Using the potential equivalent adiabatic temperature in 850 hPa at Resistencia, Ezeiza y Comodoro Rivadavia the air mass is identified. Extreme cold and warm air masses were defined, both identified using quantiles classification of θae at 850 hPa. The relationship of the values of θae at 850 hPa of extreme cold and warm air masses with surface parameters as temperature, pressure and humidity at different hours of the day is statistically significant using a discriminant analysis. The temporal evolution of the variables at surface as well as in the troposphere during the days before and after the occurrence of the cold event helped to identify that: on the surface a pressure maximum

  7. Ambient mass spectrometry: From the planar to the non-planar surface analysis

    Czech Academy of Sciences Publication Activity Database

    Rejšek, Jan; Vrkoslav, Vladimír; Cvačka, Josef

    2017-01-01

    Roč. 15, č. 1 (2017), s. 31 ISSN 2336-7202. [Mezioborové setkání mladých biologů, biochemiků a chemiků /17./. 30.05.2017-01.06.2017, Milovy] Institutional support: RVO:61388963 Keywords : ambient mass spectrometry * thin layer chromatography * non-planar surface analysis Subject RIV: CB - Analytical Chemistry, Separation

  8. Satellite skill in detecting extreme episodes in near-surface air quality

    Science.gov (United States)

    Ruiz, D. J.; Prather, M. J.

    2017-12-01

    Ozone (O3) contributes to ambient air pollution, adversely affecting public health, agriculture, and ecosystems. Reliable, long-term, densely distributed surface networks are required to establish the scale, intensity and repeatability of major pollution events (designated here in a climatological sense as air quality extremes, AQX as defined in Schnell's work). Regrettably, such networks are only available for North America (NA) and Europe (EU), which does not include many populated regions where the deaths associated with air pollution exposure are alarmingly high. Directly measuring surface pollutants from space without lidar is extremely difficult. Mapping of daily pollution events requires cross-track nadir scanners and these have limited sensitivity to surface O3 levels. This work examines several years of coincident surface and OMI satellite measurements over NA-EU, in combination with a chemistry-transport model (CTM) hindcast of that period to understand how the large-scale AQX episodes may extend into the free troposphere and thus be more amenable to satellite mapping. We show how extreme NA-EU episodes are measured from OMI and then look for such patterns over other polluted regions of the globe. We gather individual high-quality O3 surface site measurements from these other regions, to check on our satellite detection. Our approach with global satellite detection would avoid issues associated with regional variations in seasonality, chemical regime, data product biases; and it does not require defining a separate absolute threshold for each data product (surface site and satellite). This also enables coherent linking of the extreme events into large-scale pollution episodes whose magnitude evolves over 100's of km for several days. Tools used here include the UC Irvine CTM, which shows that much of the O3 surface variability is lost at heights above 2 km, but AQX local events are readily seen in a 0-3 km column average. The OMI data are taken from X

  9. Mechanical Q-factor measurements on a test mass with a structured surface

    Energy Technology Data Exchange (ETDEWEB)

    Nawrodt, R [Institut fuer Festkoerperphysik, Friedrich-Schiller-Universitaet Jena, Helmholtzweg 5, D-07743 Jena (Germany); Zimmer, A [Institut fuer Festkoerperphysik, Friedrich-Schiller-Universitaet Jena, Helmholtzweg 5, D-07743 Jena (Germany); Koettig, T [Institut fuer Festkoerperphysik, Friedrich-Schiller-Universitaet Jena, Helmholtzweg 5, D-07743 Jena (Germany); Clausnitzer, T [Institut fuer Angewandte Physik, Friedrich-Schiller-Universitaet Jena, Max-Wien-Platz 1, D-07743 Jena (Germany); Bunkowski, A [Max-Planck-Institut fuer Gravitationsphysik (Albert-Einstein-Institut) and Institut fuer Gravitationsphysik, Leibniz Universitaet Hannover, Callinstr. 38, D-30167 Hannover (Germany); Kley, E B [Institut fuer Angewandte Physik, Friedrich-Schiller-Universitaet Jena, Max-Wien-Platz 1, D-07743 Jena (Germany); Schnabel, R [Max-Planck-Institut fuer Gravitationsphysik (Albert-Einstein-Institut) and Institut fuer Gravitationsphysik, Leibniz Universitaet Hannover, Callinstr. 38, D-30167 Hannover (Germany); Danzmann, K [Max-Planck-Institut fuer Gravitationsphysik (Albert-Einstein-Institut) and Institut fuer Gravitationsphysik, Leibniz Universitaet Hannover, Callinstr. 38, D-30167 Hannover (Germany); Nietzsche, S [Institut fuer Festkoerperphysik, Friedrich-Schiller-Universitaet Jena, Helmholtzweg 5, D-07743 Jena (Germany); Vodel, W [Institut fuer Festkoerperphysik, Friedrich-Schiller-Universitaet Jena, Helmholtzweg 5, D-07743 Jena (Germany); Tuennermann, A [Institut fuer Angewandte Physik, Friedrich-Schiller-Universitaet Jena, Max-Wien-Platz 1, D-07743 Jena (Germany); Seidel, P [Institut fuer Festkoerperphysik, Friedrich-Schiller-Universitaet Jena, Helmholtzweg 5, D-07743 Jena (Germany)

    2007-07-15

    We present mechanical Q-factors (quality factors) of a crystalline quartz test mass with a nano-structured surface, measured in the temperature regime from 5 to 300 K. The nano-structure was a grating with a period of 2 {mu}m and a depth of about 0.1 {mu}m. Comparative measurements were performed on the plain substrate and on the structured test mass with different numbers of SiO{sub 2}/Ta{sub 2}O{sub 5} coating layers. The measurements at different stages of the test mass fabrication process show that the surface distortion induced by the nanostructure does not severely lower the mechanical Q-factor of the substrate. Damping due to a multi-layer coating stack was found to be orders of magnitude higher. The results provide vital information concerning the potential usage of low-thermal noise nano-structured test masses in future generations of high-precision laser interferometers and in current attempts to measure quantum effects of macroscopic mirror oscillators.

  10. Slip length measurement of confined air flow on three smooth surfaces.

    Science.gov (United States)

    Pan, Yunlu; Bhushan, Bharat; Maali, Abdelhamid

    2013-04-02

    An experimental measurement of the slip length of air flow close to three different solid surfaces is presented. The substrate was driven by a nanopositioner moving toward an oscillating glass sphere glued to an atomic force microscopy (AFM) cantilever. A large separation distance was used to get more effective data. The slip length value was obtained by analyzing the amplitude and phase data of the cantilever. The measurements show that the slip length does not depend on the oscillation amplitude of the cantilever. Because of the small difference among the slip lengths of the three surfaces, a simplified analysis method was used. The results show that on glass, graphite, and mica surfaces the slip lengths are 98, 234, and 110 nm, respectively.

  11. Study of the interaction of liquid with the surface of mass standards of high accuracy stainless steel

    International Nuclear Information System (INIS)

    Ramirez Varas, Lautaro; Castro, Claudio S.C.; Cacais, Fabio L.; Pires, Manoel J. M.; Loayza Mendoza, Victor M.

    2011-01-01

    The long term stability of mass standards depends on the interaction between the surface and environment molecules. From this point of view, a study was investigated of the effect on stainless steel surfaces by liquids frequently used in hydrostatic weighing (FC40) and in cleaning procedures of mass standards (isopropyl alcohol). Firstly, mass weighing difference was measured as function of time with a gravimetric method. Additionally, stainless steel samples were analyzed by X-ray Photoelectron Spectroscopy (XPS). The standard used for the gravimetric mass difference determination was immersed in FC40. The samples analyzed by XPS were previously immersed in both FC40 and isopropyl alcohol. Mass differences were obtained with an uncertainty of 1 μg when FC40 was used. Preliminary results have suggested that FC40 is not chemically bound to stainless steel surfaces and the mass gain was due to physisorbed molecules on the surface. (author) [es

  12. Ultrashort laser pulses and electromagnetic pulse generation in air and on dielectric surfaces

    International Nuclear Information System (INIS)

    Sprangle, P.; Penano, J.R.; Hafizi, B.; Kapetanakos, C.A.

    2004-01-01

    Intense, ultrashort laser pulses propagating in the atmosphere have been observed to emit sub-THz electromagnetic pulses (EMPS). The purpose of this paper is to analyze EMP generation from the interaction of ultrashort laser pulses with air and with dielectric surfaces and to determine the efficiency of conversion of laser energy to EMP energy. In our self-consistent model the laser pulse partially ionizes the medium, forms a plasma filament, and through the ponderomotive forces associated with the laser pulse, drives plasma currents which are the source of the EMP. The propagating laser pulse evolves under the influence of diffraction, Kerr focusing, plasma defocusing, and energy depletion due to electron collisions and ionization. Collective effects and recombination processes are also included in the model. The duration of the EMP in air, at a fixed point, is found to be a few hundred femtoseconds, i.e., on the order of the laser pulse duration plus the electron collision time. For steady state laser pulse propagation the flux of EMP energy is nonradiative and axially directed. Radiative EMP energy is present only for nonsteady state or transient laser pulse propagation. The analysis also considers the generation of EMP on the surface of a dielectric on which an ultrashort laser pulse is incident. For typical laser parameters, the power and energy conversion efficiency from laser radiation to EMP radiation in both air and from dielectric surfaces is found to be extremely small, -8 . Results of full-scale, self-consistent, numerical simulations of atmospheric and dielectric surface EMP generation are presented. A recent experiment on atmospheric EMP generation is also simulated

  13. Overview of aerosol properties associated with air masses sampled by the ATR-42 during the EUCAARI campaign (2008

    Directory of Open Access Journals (Sweden)

    S. Crumeyrolle

    2013-05-01

    Full Text Available Within the frame of the European Aerosol Cloud Climate and Air Quality Interactions (EUCAARI project, the Météo-France aircraft ATR-42 performed 22 research flights over central Europe and the North Sea during the intensive observation period in May 2008. For the campaign, the ATR-42 was equipped to study the aerosol physical, chemical, hygroscopic and optical properties, as well as cloud microphysics. For the 22 research flights, retroplume analyses along the flight tracks were performed with FLEXPART in order to classify air masses into five sectors of origin, allowing for a qualitative evaluation of emission influence on the respective air parcel. This study shows that the extensive aerosol parameters (aerosol mass and number concentrations show vertical decreasing gradients and in some air masses maximum mass concentrations (mainly organics in an intermediate layer (1–3 km. The observed mass concentrations (in the boundary layer (BL: between 10 and 30 μg m−3; lower free troposphere (LFT: 0.8 and 14 μg m−3 are high especially in comparison with the 2015 European norms for PM2.5 (25 μg m−3 and with previous airborne studies performed over England (Morgan et al., 2009; McMeeking et al., 2012. Particle number size distributions show a larger fraction of particles in the accumulation size range in the LFT compared to BL. The chemical composition of submicron aerosol particles is dominated by organics in the BL, while ammonium sulphate dominates the submicron aerosols in the LFT, especially in the aerosol particles originated from north-eastern Europe (~ 80%, also experiencing nucleation events along the transport. As a consequence, first the particle CCN acting ability, shown by the CCN/CN ratio, and second the average values of the scattering cross sections of optically active particles (i.e. scattering coefficient divided by the optical active particle concentration are increased in the LFT compared to BL.

  14. Cold air plasma to decontaminate inanimate surfaces of the hospital environment.

    Science.gov (United States)

    Cahill, Orla J; Claro, Tânia; O'Connor, Niall; Cafolla, Anthony A; Stevens, Niall T; Daniels, Stephen; Humphreys, Hilary

    2014-03-01

    The hospital environment harbors bacteria that may cause health care-associated infections. Microorganisms, such as multiresistant bacteria, can spread around the patient's inanimate environment. Some recently introduced biodecontamination approaches in hospitals have significant limitations due to the toxic nature of the gases and the length of time required for aeration. This study evaluated the in vitro use of cold air plasma as an efficient alternative to traditional methods of biodecontamination of hospital surfaces. Cultures of methicillin-resistant Staphylococcus aureus (MRSA), vancomycin-resistant enterococci (VRE), extended-spectrum-β-lactamase (ESBL)-producing Escherichia coli, and Acinetobacter baumannii were applied to different materials similar to those found in the hospital environment. Artificially contaminated sections of marmoleum, mattress, polypropylene, powder-coated mild steel, and stainless steel were then exposed to a cold air pressure plasma single jet for 30 s, 60 s, and 90 s, operating at approximately 25 W and 12 liters/min flow rate. Direct plasma exposure successfully reduced the bacterial load by log 3 for MRSA, log 2.7 for VRE, log 2 for ESBL-producing E. coli, and log 1.7 for A. baumannii. The present report confirms the efficient antibacterial activity of a cold air plasma single-jet plume on nosocomial bacterially contaminated surfaces over a short period of time and highlights its potential for routine biodecontamination in the clinical environment.

  15. Visualization of an air-water interface on superhydrophobic surfaces in turbulent channel flows

    Science.gov (United States)

    Kim, Hyunseok; Park, Hyungmin

    2017-11-01

    In the present study, three-dimensional deformation of air-water interface on superhydrophobic surfaces in turbulent channel flows at the Reynolds numbers of Re = 3000 and 10000 is measured with RICM (Reflection Interference Contrast Microscopy) technique. Two different types of roughness feature of circular hole and rectangular grate are considered, whose depth is 20 μm and diameter (or width) is varied between 20-200 μm. Since the air-water interface is always at de-pinned state at the considered condition, air-water interface shape and its sagging velocity is maintained to be almost constant as time goes one. In comparison with the previous results under the laminar flow, due to turbulent characteristics of the flow, sagging velocity is much faster. Based on the measured sagging profiles, a modified model to describe the air-water interface dynamics under turbulent flows is suggested. Supported by City of Seoul through Seoul Urban Data Science Laboratory Project (Grant No 0660-20170004) administered by SNU Big Data Institute.

  16. Time-resolved imaging of a compressible air disc under a drop impacting on a solid surface

    KAUST Repository

    Li, Erqiang

    2015-09-07

    When a drop impacts on a solid surface, its rapid deceleration is cushioned by a thin layer of air, which leads to the entrapment of a bubble under its centre. For large impact velocities the lubrication pressure in this air layer becomes large enough to compress the air. Herein we use high-speed interferometry, with 200 ns time-resolution, to directly observe the thickness evolution of the air layer during the entire bubble entrapment process. The initial disc radius and thickness shows excellent agreement with available theoretical models, based on adiabatic compression. For the largest impact velocities the air is compressed by as much as a factor of 14. Immediately following the contact, the air disc shows rapid vertical expansion. The radial speed of the surface minima just before contact, can reach 50 times the impact velocity of the drop.

  17. Influence of the ozone profile above Madrid (Spain) on Brewer estimation of ozone air mass factor

    Energy Technology Data Exchange (ETDEWEB)

    Anton, M. [Univ. de Extremadura, Badajoz (Spain). Dept. de Fisica; Evora Univ. (PT). Goephysics Centre of Evora (CGE); Lopez, M.; Banon, M. [Agenica Estatal de Meteorologia (AEMET), Madrid (Spain); Costa, M.J.; Silva, A.M. [Evora Univ. (PT). Goephysics Centre of Evora (CGE); Evora Univ. (Portugal). Dept. of Physics; Serrano, A. [Univ. de Extremadura, Badajoz (Spain). Dept. de Fisica; Bortoli, D. [Evora Univ. (PT). Goephysics Centre of Evora (CGE); Vilaplana, J.M. [Instituto Nacional de Tecnica Aeroespacial (INTA), Huelva (Spain). Estacion de Sondeos Atmosferico ' ' El Arenosillo' '

    2009-07-01

    The methodology used by Brewer spectroradiometers to estimate the ozone column is based on differential absorption spectroscopy. This methodology employs the ozone air mass factor (AMF) to derive the total ozone column from the slant path ozone amount. For the calculating the ozone AMF, the Brewer algorithm assumes that the ozone layer is located at a fixed height of 22 km. However, for a real specific site the ozone presents a certain profile, which varies spatially and temporally depending on the latitude, altitude and dynamical conditions of the atmosphere above the site of measurements. In this sense, this work address the reliability of the mentioned assumption and analyses the influence of the ozone profiles measured above Madrid (Spain) in the ozone AMF calculations. The approximated ozone AMF used by the Brewer algorithm is compared with simulations obtained using the libRadtran radiative transfer model code. The results show an excellent agreement between the simulated and the approximated AMF values for solar zenith angle lower than 75 . In addition, the relative differences remain lower than 2% at 85 . These good results are mainly due to the fact that the altitude of the ozone layer assumed constant by the Brewer algorithm for all latitudes notably can be considered representative of the real profile of ozone above Madrid (average value of 21.7{+-}1.8 km). The operational ozone AMF calculations for Brewer instruments are limited, in general, to SZA below 80 . Extending the usable SZA range is especially relevant for Brewer instruments located at high mid-latitudes. (orig.)

  18. Elemental composition of air masses under different altitudes in Azores, central north Atlantic

    International Nuclear Information System (INIS)

    Vieira, B.J.; Wolterbeek, H.Th.

    2012-01-01

    Between 8th July 2002 and 18th June 2004, aerosol samples were collected in Azores. Their inorganic composition was obtained by neutron activation analysis in order to study the differences of aerosols in two atmospheric altitudes of the central north Atlantic: (1) PICO-NARE observatory (Lower Free Troposphere-LFT) at Pico mountain summit (38,470 deg N, 28,404 deg W, 2,225 m a.s.l.) in Pico Island, Azores, where air masses from the surrounding continents (Africa, Europe, Central and North America) pass through, carrying aerosols with anthropogenic (Sb, Br, Mo, U, Se and Tb) and/or natural emissions (Fe, Co, La, Na, Sm, Cr, Zn, Hf, K and Th); (2) TERCEIRA-NARE station (Marine Boundary Layer) at Serreta (38,69 deg N, 27,36 deg W, 50 m a.s.l.), in Terceira Island, Azores, where natural aerosols (I, Cl, Na, Br and other soil related elements) are predominant. However, a combined interpretation of the data points out to a co-existence of the anthropogenic elements Sb and Mo, eventually with similar origins as the ones passing Pico Mountain summit. Very high concentrations and enrichment factors for Sb, Mo and Br in LFT, higher than the ones found in other areas, confirm atmospheric long-range transport mainly from the west boundary of north Atlantic; this may indicate eventual accumulation and persistence of those elements in the area due to the presence of Azores high pressures or the Hadley cells effect. A significant correlation between Fe and Yb and the enrichment of rare earth elements (La, Sm, Tb and Yb) and Th in LFT aerosols, both reflect a mineral dust intrusions from north Africa (Sahara and Sahel region). (author)

  19. The machined surface of magnesium AZ31 after rotary turning at air cooling condition

    Science.gov (United States)

    Akhyar, G.; Purnomo, B.; Hamni, A.; Harun, S.; Burhanuddin, Y.

    2018-04-01

    Magnesium is a lightweight metal that is widely used as an alternative to iron and steel. Magnesium has been applied in the automotive industry to reduce the weight of a component, but the machining process has the disadvantage that magnesium is highly flammable because it has a low flash point. High temperature can cause the cutting tool wear and contributes to the quality of the surface roughness. The purpose of this study is to obtain the value of surface roughness and implement methods of rotary cutting tool and air cooling output vortex tube cooler to minimize the surface roughness values. Machining parameters that is turning using rotary cutting tool at speed the workpiece of (Vw) 50, 120, 160 m/min, cutting speed of rotary tool of (Vt) 25, 50, 75 m/min, feed rate of (f) 0.1, 0.15, 0.2 mm/rev, and depth of cut of 0.3 mm. Type of tool used is a carbide tool diameter of 16 mm and air cooling pressure of 6 bar. The results show the average value of the lowest surface roughness on the speed the workpiece of 80 m/min, cutting speed of rotary tool of 50 m/min, feed rate of 0.2 mm/rev, and depth of cut of 0.3 mm. While the average value of the highest surface roughness on the speed the workpiece of 160 m/min, cutting speed of rotary tool of 50 m/min, feed rate of 0.2 mm/rev, and depth of cut of 0.3 mm. The influence of machining parameters concluded the higher the speed of the workpiece the surface roughness value higher. Otherwise the higher cutting speed of rotary tool then the lower the surface roughness value. The observation on the surface of the rotary tool, it was found that no uniform tool wear which causes non-uniform surface roughness. The use of rotary cutting tool contributing to lower surface roughness values generated.

  20. Surface treatment of polyethylene terephthalate film using atmospheric pressure glow discharge in air

    International Nuclear Information System (INIS)

    Fang Zhi; Qiu Yuchang; Wang Hui

    2004-01-01

    Non-thermal plasmas under atmospheric pressure are of great interest in polymer surface processing because of their convenience, effectiveness and low cost. In this paper, the treatment of Polyethylene terephthalate (PET) film surface for improving hydrophilicity using the non-thermal plasma generated by atmospheric pressure glow discharge (APGD) in air is conducted. The discharge characteristics of APGD are shown by measurement of their electrical discharge parameters and observation of light-emission phenomena, and the surface properties of PET before and after the APGD treatment are studied using contact angle measurement, x-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). It is found that the APGD is homogeneous and stable in the whole gas gap, which differs from the commonly filamentary dielectric barrier discharge (DBD). A short time (several seconds) APGD treatment can modify the surface characteristics of PET film markedly and uniformly. After 10 s APGD treatment, the surface oxygen content of PET surface increases to 39%, and the water contact angle decreases to 19 degree, respectively. (authors)

  1. Intense air-sea exchanges and heavy orographic precipitation over Italy: The role of Adriatic sea surface temperature uncertainty

    Science.gov (United States)

    Stocchi, Paolo; Davolio, Silvio

    2017-11-01

    Strong and persistent low-level winds blowing over the Adriatic basin are often associated with intense precipitation events over Italy. Typically, in case of moist southeasterly wind (Sirocco), rainfall affects northeastern Italy and the Alpine chain, while with cold northeasterly currents (Bora) precipitations are localized along the eastern slopes of the Apennines and central Italy coastal areas. These events are favoured by intense air-sea interactions and it is reasonable to hypothesize that the Adriatic sea surface temperature (SST) can affect the amount and location of precipitation. High-resolution simulations of different Bora and Sirocco events leading to severe precipitation are performed using a convection-permitting model (MOLOCH). Sensitivity experiments varying the SST initialization field are performed with the aim of evaluating the impact of SST uncertainty on precipitation forecasts, which is a relevant topic for operational weather predictions, especially at local scales. Moreover, diagnostic tools to compute water vapour fluxes across the Italian coast and atmospheric water budget over the Adriatic Sea have been developed and applied in order to characterize the air mass that feeds the precipitating systems. Finally, the investigation of the processes through which the SST influences location and intensity of heavy precipitation allows to gain a better understanding on mechanisms conducive to severe weather in the Mediterranean area and in the Adriatic basin in particular. Results show that the effect of the Adriatic SST (uncertainty) on precipitation is complex and can vary considerably among different events. For both Bora and Sirocco events, SST does not influence markedly the atmospheric water budget or the degree of moistening of air that flows over the Adriatic Sea. SST mainly affects the stability of the atmospheric boundary layer, thus influencing the flow dynamics and the orographic flow regime, and in turn, the precipitation pattern.

  2. Mass transfer of CO2 to groundwaters from a near-surface waste disposal site

    International Nuclear Information System (INIS)

    Caron, F.; Wilkinson, S.R.; Manni, G.; Torok, J.

    1995-01-01

    Gaseous 14 CO 2 originating from buried low-level radioactive wastes (LLRW) in a near-surface disposal site can be released to the environment via two major paths: gas-phase diffusion through soils to the atmosphere, and dissolution in groundwater, followed by aqueous migration. Aqueous migration would give the highest dose to an individual, especially if C-14 was converted to an organic form and ingested. Gaseous diffusion would give a lower dose, largely because of atmospheric dispersion and dilution. The objective of this study was to develop the capability to estimate which of the two paths will likely be dominant for typical near-surface disposal facilities. The main missing parameter for making this estimate was a mass-transfer coefficient (K L ) of 14 CO 2 to groundwaters, which was determined experimentally using a large sand box. The K L thus determined was approximately 10 to 20 times smaller than for an open liquid surface. This suggests that there is a potential resistance to mass transfer, probably caused by the capillary fringe. The value obtained was incorporated into a simple model of CO 2 transport around a typical near-surface disposal site. The model suggests that CO 2 transport via both gaseous release and aqueous migration paths are of similar magnitude for a repository located ∼2 m above the water table. (author). 11 refs., 2 tabs., 2 figs

  3. A Comprehensive Probabilistic Framework to Learn Air Data from Surface Pressure Measurements

    Directory of Open Access Journals (Sweden)

    Ankur Srivastava

    2015-01-01

    Full Text Available Use of probabilistic techniques has been demonstrated to learn air data parameters from surface pressure measurements. Integration of numerical models with wind tunnel data and sequential experiment design of wind tunnel runs has been demonstrated in the calibration of a flush air data sensing anemometer system. Development and implementation of a metamodeling method, Sequential Function Approximation (SFA, are presented which lies at the core of the discussed probabilistic framework. SFA is presented as a tool capable of nonlinear statistical inference, uncertainty reduction by fusion of data with physical models of variable fidelity, and sequential experiment design. This work presents the development and application of these tools in the calibration of FADS for a Runway Assisted Landing Site (RALS control tower. However, the multidisciplinary nature of this work is general in nature and is potentially applicable to a variety of mechanical and aerospace engineering problems.

  4. Mass balance and surface movement of the Greenland Ice Sheet at Summit, Central Greenland

    DEFF Research Database (Denmark)

    Hvidberg, C.S.; Keller, K.; Gundestrup, N.S.

    1997-01-01

    During the GRIP deep drilling in Central Greenland, the ice sheet topography and surface movement at Summit has been mapped with GPS. Measurements of the surface velocity are presented for a strain net consisting of 13 poles at distances of 25-60 km from the GRIP site. Some results are: The GRIP...... site is located approximately 2 km NW of the topographic summit; the surface velocity at the GISP 2 site is 1.7 m/yr in the W direction. The present mass balance at Summit is calculated to be -0.03+/-0.04 m/yr, i.e. close to steady state. This result is the best now available for Summit. A small...... thinning rate might be a transient response of the Greenland Ice Sheet due to the temperature increase at the Wisconsin-Holocene transition....

  5. Air Mass Factor Formulation for Spectroscopic Measurements from Satellites: Application to Formaldehyde Retrievals from the Global Ozone Monitoring Experiment

    Science.gov (United States)

    Palmer, Paul I.; Jacob, Daniel J.; Chance, Kelly; Martin, Randall V.; Spurr, Robert J. D.; Kurosu, Thomas P.; Bey, Isabelle; Yantosca, Robert; Fiore, Arlene; Li, Qinbin

    2004-01-01

    We present a new formulation for the air mass factor (AMF) to convert slant column measurements of optically thin atmospheric species from space into total vertical columns. Because of atmospheric scattering, the AMF depends on the vertical distribution of the species. We formulate the AMF as the integral of the relative vertical distribution (shape factor) of the species over the depth of the atmosphere, weighted by altitude-dependent coefficients (scattering weights) computed independently from a radiative transfer model. The scattering weights are readily tabulated, and one can then obtain the AMF for any observation scene by using shape factors from a three dimensional (3-D) atmospheric chemistry model for the period of observation. This approach subsequently allows objective evaluation of the 3-D model with the observed vertical columns, since the shape factor and the vertical column in the model represent two independent pieces of information. We demonstrate the AMF method by using slant column measurements of formaldehyde at 346 nm from the Global Ozone Monitoring Experiment satellite instrument over North America during July 1996. Shape factors are cumputed with the Global Earth Observing System CHEMistry (GEOS-CHEM) global 3-D model and are checked for consistency with the few available aircraft measurements. Scattering weights increase by an order of magnitude from the surface to the upper troposphere. The AMFs are typically 20-40% less over continents than over the oceans and are approximately half the values calculated in the absence of scattering. Model-induced errors in the AMF are estimated to be approximately 10%. The GEOS-CHEM model captures 50% and 60% of the variances in the observed slant and vertical columns, respectively. Comparison of the simulated and observed vertical columns allows assessment of model bias.

  6. Durable and mass producible polymer surface structures with different combinations of micro–micro hierarchy

    International Nuclear Information System (INIS)

    Jiang, Yu; Suvanto, Mika; Pakkanen, Tapani A

    2016-01-01

    Extensive studies have been performed with the aim of fabricating hierarchical surface structures inspired by nature. However, synthetic hierarchical structures have to sacrifice mechanical resistance to functionality by introducing finer scaled structures. Therefore, surfaces are less durable. Surface micro–micro hierarchy has been proven to be effective in replacing micro–nano hierarchy in the sense of superhydrophobicity. However, less attention has been paid to the combined micro–micro hierarchies with surface pillars and pits incorporated together. The fabrication of this type of hierarchy may be less straightforward, with the possibility of being a complicated multi-step process. In this study, we present a simple yet mass producible fabrication method for hierarchical structures with different combinations of surface pillars and pits. The fabrication was based on only one aluminum (Al) mold with sequential mountings. The fabricated structures exhibit high mechanical durability and structural stabilities with a normal load up to 100 kg. In addition, the theoretical estimation of the wetting state shows a promising way of stabilizing a water droplet on the surface pit structures with a more stable Cassie–Baxter state. (paper)

  7. LASER PLASMA: Experimental confirmation of the erosion origin of pulsed low-threshold surface optical breakdown of air

    Science.gov (United States)

    Min'ko, L. Ya; Chumakou, A. N.; Chivel', Yu A.

    1988-08-01

    Nanosecond kinetic spectroscopy techniques were used to identify the erosion origin of pulsed low-threshold surface optical breakdown of air as a result of interaction of microsecond neodymium and CO2 laser pulses with some metals (indium, lead).

  8. Time-resolved imaging of a compressible air disc under a drop impacting on a solid surface

    KAUST Repository

    Li, Erqiang; Thoroddsen, Sigurdur T

    2015-01-01

    When a drop impacts on a solid surface, its rapid deceleration is cushioned by a thin layer of air, which leads to the entrapment of a bubble under its centre. For large impact velocities the lubrication pressure in this air layer becomes large

  9. Single-shot femtosecond laser ablation of gold surface in air and isopropyl alcohol

    Science.gov (United States)

    Kudryashov, S. I.; Saraeva, I. N.; Lednev, V. N.; Pershin, S. M.; Rudenko, A. A.; Ionin, A. A.

    2018-05-01

    Single-shot IR femtosecond-laser ablation of gold surfaces in ambient air and liquid isopropyl alcohol was studied by scanning electron microscopy characterization of crater topographies and time-resolved optical emission spectroscopy of ablative plumes in regimes, typical for non-filamentary and non-fragmentation laser production of nanoparticle sols. Despite one order of magnitude shorter (few nanoseconds) lifetimes and almost two orders of magnitude lower intensities of the quenched ablative plume emission in the alcohol ambient at the same peak laser fluence, craters for the dry and wet conditions appeared with rather similar nanofoam-like spallative topographies and the same thresholds. These facts envision the underlying surface spallation as one of the basic ablation mechanisms relevant for both dry and wet advanced femtosecond laser surface nano/micro-machining and texturing, as well as for high-throughput femtosecond laser ablative production of colloidal nanoparticles by MHz laser-pulse trains via their direct nanoscale jetting from the nanofoam in air and fluid environments.

  10. BOREAS AFM-08 ECMWF Hourly Surface and Upper Air Data for the SSA and NSA

    Science.gov (United States)

    Viterbo, Pedro; Betts, Alan; Hall, Forrest G. (Editor); Newcomer, Jeffrey A.; Smith, David E. (Technical Monitor)

    2000-01-01

    The Boreal Ecosystem-Atmosphere Study (BOREAS) Airborne Fluxes and Meteorology (AFM)-8 team focused on modeling efforts to improve the understanding of the diurnal evolution of the convective boundary layer over the boreal forest. This data set contains hourly data from the European Center for for Medium-Range Weather Forecasts (ECMWF) operational model from below the surface to the top of the atmosphere, including the model fluxes at the surface. Spatially, the data cover a pair of the points that enclose the rawinsonde sites at Candle Lake, Saskatchewan, in the Southern Study Area (SSA) and Thompson, Manitoba, in the Northern Study Area (NSA). Temporally, the data include the two time periods of 13 May 1994 to 30 Sept 1994 and 01 Mar 1996 to 31 Mar 1997. The data are stored in tabular ASCII files. The number of records in the upper air data files may exceed 20,000, causing a problem for some software packages. The ECMWF hourly surface and upper air data are available from the Earth Observing System Data and Information System (EOSDIS) Oak Ridge National Laboratory (ORNL) Distributed Active Archive Center (DAAC). The data files are available on a CD-ROM (see document number 20010000884).

  11. Transfer coefficients of energy in mass for X radiation-air: the kV relation and effective energy

    International Nuclear Information System (INIS)

    Teixeira, G.J.; Sousa, C.H.S.; Peixoto, J.G.P.

    2014-01-01

    The objective was to determine, through specific software, the mass-energy transfer coefficients by X-ray beams in air between 30-150 kV. Were generated by the Spectrum Processor program, the spectra and calculated their mass coefficients. The results behaved numerically decreasing order, ranging between 0.3733 and 0.0439 cm 2 /g, inversely proportional to the voltage used and differing behavior of mono-energetic beams above 100 keV. Values align with literal definitions of the interaction of radiation with matter, being useful for dosimetry in diagnostic radiology, including for systems not using an ionization chamber. (author)

  12. Calibrating a surface mass-balance model for Austfonna ice cap, Svalbard

    Science.gov (United States)

    Schuler, Thomas Vikhamar; Loe, Even; Taurisano, Andrea; Eiken, Trond; Hagen, Jon Ove; Kohler, Jack

    2007-10-01

    Austfonna (8120 km2) is by far the largest ice mass in the Svalbard archipelago. There is considerable uncertainty about its current state of balance and its possible response to climate change. Over the 2004/05 period, we collected continuous meteorological data series from the ice cap, performed mass-balance measurements using a network of stakes distributed across the ice cap and mapped the distribution of snow accumulation using ground-penetrating radar along several profile lines. These data are used to drive and test a model of the surface mass balance. The spatial accumulation pattern was derived from the snow depth profiles using regression techniques, and ablation was calculated using a temperature-index approach. Model parameters were calibrated using the available field data. Parameter calibration was complicated by the fact that different parameter combinations yield equally acceptable matches to the stake data while the resulting calculated net mass balance differs considerably. Testing model results against multiple criteria is an efficient method to cope with non-uniqueness. In doing so, a range of different data and observations was compared to several different aspects of the model results. We find a systematic underestimation of net balance for parameter combinations that predict observed ice ablation, which suggests that refreezing processes play an important role. To represent these effects in the model, a simple PMAX approach was included in its formulation. Used as a diagnostic tool, the model suggests that the surface mass balance for the period 29 April 2004 to 23 April 2005 was negative (-318 mm w.e.).

  13. Centrifugal Compressor Surge Margin Improved With Diffuser Hub Surface Air Injection

    Science.gov (United States)

    Skoch, Gary J.

    2002-01-01

    Aerodynamic stability is an important parameter in the design of compressors for aircraft gas turbine engines. Compression system instabilities can cause compressor surge, which may lead to the loss of an aircraft. As a result, engine designers include a margin of safety between the operating line of the engine and the stability limit line of the compressor. The margin of safety is typically referred to as "surge margin." Achieving the highest possible level of surge margin while meeting design point performance objectives is the goal of the compressor designer. However, performance goals often must be compromised in order to achieve adequate levels of surge margin. Techniques to improve surge margin will permit more aggressive compressor designs. Centrifugal compressor surge margin improvement was demonstrated at the NASA Glenn Research Center by injecting air into the vaned diffuser of a 4:1-pressure-ratio centrifugal compressor. Tests were performed using injector nozzles located on the diffuser hub surface of a vane-island diffuser in the vaneless region between the impeller trailing edge and the diffuser-vane leading edge. The nozzle flow path and discharge shape were designed to produce an air stream that remained tangent to the hub surface as it traveled into the diffuser passage. Injector nozzles were located near the leading edge of 23 of the 24 diffuser vanes. One passage did not contain an injector so that instrumentation located in that passage would be preserved. Several orientations of the injected stream relative to the diffuser vane leading edge were tested over a range of injected flow rates. Only steady flow (nonpulsed) air injection was tested. At 100 percent of the design speed, a 15-percent improvement in the baseline surge margin was achieved with a nozzle orientation that produced a jet that was bisected by the diffuser vane leading edge. Other orientations also improved the baseline surge margin. Tests were conducted at speeds below the

  14. Daily Cycle of Air Temperature and Surface Temperature in Stone Forest

    Science.gov (United States)

    Wang, K.; Li, Y.; Wang, X.; Yuan, M.

    2013-12-01

    Urbanization is one of the most profound human activities that impact on climate change. In cities, where are highly artificial areas, the conflict between human activity and natural climate is particularly prominent. Urban areas always have the larger area of impervious land, the higher consumption of greenhouse gases, more emissions of anthropogenic heat and air pollution, all contribute to the urban warming phenomena. Understanding the mechanisms causing a variety of phenomena involved in the urban warming is critical to distinguish the anthropogenic effect and natural variation in the climate change. However, the exact dynamics of urban warming were poorly understood, and effective control strategies are not available. Here we present a study of the daily cycle of air temperature and surface temperature in Stone Forest. The specific heat of the stones in the Stone Forest and concrete of the man-made structures within the cities are approximate. Besides, the height of the Stone Forest and the height of buildings within the city are also similar. As a scenic area, the Stone Forest is being preserved and only opened for sightseeing. There is no anthropogenic heat, as well air pollution within the Stone Forest. The thermal environment in Stone Forest can be considered to be a simulation of thermal environment in the city, which can reveal the effect of man-made structures on urban thermal environment. We conducted the field studies and numerical analysis in the Stone Forest for 4 typical urban morphology and environment scenarios, including high-rise compact cities, low-rise sparse cities, garden cities and isolated single stone. Air temperature and relative humidity were measured every half an hour in 15 different locations, which within different spatial distribution of stones and can represent the four urban scenarios respectively. At the same time, an infrared camera was used to take thermal images and get the hourly surface temperatures of stones and

  15. Monitoring of 7Be in surface air of varying PM10 concentrations

    International Nuclear Information System (INIS)

    Chao, J.H.; Liu, C.C.; Cho, I.C.; Niu, H.

    2014-01-01

    In this study, beryllium-7 ( 7 Be) concentrations of surface air were monitored throughout a span of 23 years (1992–2012) in the Taiwanese cities Yilan, Taipei, Taichung, and Kaohsiung. During this period, particulate matter (PM) concentrations, in terms of PM 10 , were collected monthly from the nearest air-quality pollutant monitoring stations and compared against 7 Be concentrations. Seasonal monsoons influenced 7 Be concentrations in all cities, resulting in high winter and low summer concentrations. In addition, the meteorological conditions caused seasonal PM 10 variations, yielding distinct patterns among the cities. There was no correlation between 7 Be and PM 10 in the case cities. The average annual 7 Be concentrations varied little among the cities, ranging from 2.9 to 3.5 mBq/m 3 , while the PM 10 concentrations varied significantly from 38 μg/m 3 in Yilan to 92 μg/m 3 in Kaohsiung depending on the degree of air pollution and meteorological conditions. The correlation between the 7 Be concentration and gross-beta activities (A β ) in air implied that the 7 Be was mainly attached to crustal PM and its concentration varied little among the cities, regardless of the increase in anthropogenic PM in air-polluted areas. - Highlights: • Both 7 Be and PM 10 concentrations were monitored in four Taiwanese cities from 1992 to 2012. • Seasonal variations of 7 Be and PM 10 were explained based on on meteorological and pollution conditions. • The annual concentrations of 7 Be varied little among the four cities even in high PM environment. • 7 Be is believed to mainly attach to natural PM in the cities that exhibited varying PM 10 concentrations

  16. Plasma surface treatment of Cu by nanosecond-pulse diffuse discharges in atmospheric air

    Science.gov (United States)

    Cheng, ZHANG; Jintao, QIU; Fei, KONG; Xingmin, HOU; Zhi, FANG; Yu, YIN; Tao, SHAO

    2018-01-01

    Nanosecond-pulse diffuse discharges could provide high-density plasma and high-energy electrons at atmospheric pressure. In this paper, the surface treatment of Cu by nanosecond-pulse diffuse discharges is conducted in atmospheric air. Factors influencing the water contact angle (WCA), chemical composition and microhardness, such as the gap spacing and treatment time, are investigated. The results show that after the plasma surface treatment, the WCA considerably decreases from 87° to 42.3°, and the surface energy increases from 20.46 mJ m-2 to 66.28 mJ m-2. Results of energy dispersive x-ray analysis show that the concentration of carbon decreases, but the concentrations of oxygen and nitrogen increase significantly. Moreover, the microhardness increases by approximately 30% after the plasma treatment. The aforementioned changes on the Cu surface indicate the plasma surface treatment enhances the hydrophilicity and microhardness, and it cleans the carbon and achieves oxidization on the Cu surface. Furthermore, by increasing the gap spacing and treatment time, better treatment effects can be obtained. The microhardness in the case of a 2.5 cm gap is higher than that in the case of a 3 cm gap. More oxygen and nitrogen species appear on the Cu surface for the 2.5 cm gap treatment than for the 3 cm gap treatment. The WCA significantly decreases with the treatment time when it is no longer than 90 s, and then it reaches saturation. In addition, more oxygen-containing and nitrogen-containing groups appear after extended plasma treatment time. They contribute to the improvement of the hydrophilicity and oxidation on the Cu surface.

  17. Constraining Aerosol Optical Models Using Ground-Based, Collocated Particle Size and Mass Measurements in Variable Air Mass Regimes During the 7-SEAS/Dongsha Experiment

    Science.gov (United States)

    Bell, Shaun W.; Hansell, Richard A.; Chow, Judith C.; Tsay, Si-Chee; Wang, Sheng-Hsiang; Ji, Qiang; Li, Can; Watson, John G.; Khlystov, Andrey

    2012-01-01

    During the spring of 2010, NASA Goddard's COMMIT ground-based mobile laboratory was stationed on Dongsha Island off the southwest coast of Taiwan, in preparation for the upcoming 2012 7-SEAS field campaign. The measurement period offered a unique opportunity for conducting detailed investigations of the optical properties of aerosols associated with different air mass regimes including background maritime and those contaminated by anthropogenic air pollution and mineral dust. What appears to be the first time for this region, a shortwave optical closure experiment for both scattering and absorption was attempted over a 12-day period during which aerosols exhibited the most change. Constraints to the optical model included combined SMPS and APS number concentration data for a continuum of fine and coarse-mode particle sizes up to PM2.5. We also take advantage of an IMPROVE chemical sampler to help constrain aerosol composition and mass partitioning of key elemental species including sea-salt, particulate organic matter, soil, non sea-salt sulphate, nitrate, and elemental carbon. Our results demonstrate that the observed aerosol scattering and absorption for these diverse air masses are reasonably captured by the model, where peak aerosol events and transitions between key aerosols types are evident. Signatures of heavy polluted aerosol composed mostly of ammonium and non sea-salt sulphate mixed with some dust with transitions to background sea-salt conditions are apparent in the absorption data, which is particularly reassuring owing to the large variability in the imaginary component of the refractive indices. Extinctive features at significantly smaller time scales than the one-day sample period of IMPROVE are more difficult to reproduce, as this requires further knowledge concerning the source apportionment of major chemical components in the model. Consistency between the measured and modeled optical parameters serves as an important link for advancing remote

  18. Surface Energy and Mass Balance Model for Greenland Ice Sheet and Future Projections

    Science.gov (United States)

    Liu, Xiaojian

    The Greenland Ice Sheet contains nearly 3 million cubic kilometers of glacial ice. If the entire ice sheet completely melted, sea level would raise by nearly 7 meters. There is thus considerable interest in monitoring the mass balance of the Greenland Ice Sheet. Each year, the ice sheet gains ice from snowfall and loses ice through iceberg calving and surface melting. In this thesis, we develop, validate and apply a physics based numerical model to estimate current and future surface mass balance of the Greenland Ice Sheet. The numerical model consists of a coupled surface energy balance and englacial model that is simple enough that it can be used for long time scale model runs, but unlike previous empirical parameterizations, has a physical basis. The surface energy balance model predicts ice sheet surface temperature and melt production. The englacial model predicts the evolution of temperature and meltwater within the ice sheet. These two models can be combined with estimates of precipitation (snowfall) to estimate the mass balance over the Greenland Ice Sheet. We first compare model performance with in-situ observations to demonstrate that the model works well. We next evaluate how predictions are degraded when we statistically downscale global climate data. We find that a simple, nearest neighbor interpolation scheme with a lapse rate correction is able to adequately reproduce melt patterns on the Greenland Ice Sheet. These results are comparable to those obtained using empirical Positive Degree Day (PDD) methods. Having validated the model, we next drove the ice sheet model using the suite of atmospheric model runs available through the CMIP5 atmospheric model inter-comparison, which in turn built upon the RCP 8.5 (business as usual) scenarios. From this exercise we predict how much surface melt production will increase in the coming century. This results in 4-10 cm sea level equivalent, depending on the CMIP5 models. Finally, we try to bound melt water

  19. FLOW VISUALIZATION OF RECTANGULAR SLOT AIR JET IMPINGEMENT ON FLAT SURFACES

    OpenAIRE

    Satheesha V *1, B. K. Muralidhra2, Abhilash N3, C. K. Umesh4

    2018-01-01

    Jet impingement near the mid-chord of the gas turbine blade is treated as a flat plate. Experimental and numerical investigations are carried out for a single slot air jet impinging on flat surface for two different rectangular slots of dimension (3mm x 65 mm) and (5mm x 65 mm). Experimentation is done to study the flow pattern topography on the flat target plate, with varying the flow rate from 20 LPM to 50 LPM by varying the nozzle to plate distance from 9 mm to 24 mm for slot jet of 3mm an...

  20. Study of dispersion of mass distribution of ultra-high energy cosmic rays using a surface array of muon and electromagnetic detectors

    Science.gov (United States)

    Vícha, Jakub; Trávníček, Petr; Nosek, Dalibor; Ebr, Jan

    2015-09-01

    We consider a hypothetical observatory of ultra-high energy cosmic rays consisting of two surface detector arrays that measure independently electromagnetic and muon signals induced by air showers. Using the constant intensity cut method, sets of events ordered according to each of both signal sizes are compared giving the number of matched events. Based on its dependence on the zenith angle, a parameter sensitive to the dispersion of the distribution of the logarithmic mass of cosmic rays is introduced. The results obtained using two post-LHC models of hadronic interactions are very similar and indicate a weak dependence on details of these interactions.

  1. GAMA/H-ATLAS: THE DUST OPACITY-STELLAR MASS SURFACE DENSITY RELATION FOR SPIRAL GALAXIES

    Energy Technology Data Exchange (ETDEWEB)

    Grootes, M. W.; Tuffs, R. J.; Andrae, E. [Max-Planck-Institut fuer Kernphysik, Saupfercheckweg 1, D-69117 Heidelberg (Germany); Popescu, C. C.; Pastrav, B. [Jeremiah Horrocks Institute, University of Central Lancashire, Preston PR1 2HE (United Kingdom); Gunawardhana, M.; Taylor, E. N. [Sydney Institute for Astronomy, School of Physics, University of Sydney, NSW 206 (Australia); Kelvin, L. S.; Driver, S. P. [Scottish Universities' Physics Alliance (SUPA), School of Physics and Astronomy, University of St. Andrews, North Haugh, St. Andrews KY16 9SS (United Kingdom); Liske, J. [European Southern Observatory, Karl-Schwarzschild Str. 2, D-85748 Garching (Germany); Seibert, M. [Observatories of the Carnegie Institution for Science, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); Graham, Alister W. [Centre for Astrophysics and Supercomputing, Swinburne University of Technology, Hawthorn, Victoria 3122 (Australia); Baes, M. [Sterrenkundig Observatorium, Universiteit Gent, Krijgslaan 281 S9, B-9000 Gent (Belgium); Baldry, I. K. [Astrophysics Research Institute, Liverpool John Moores University, Twelve Quays House, Egerton Wharf, Birkenhead CH41 1LD (United Kingdom); Bourne, N. [Centre for Astronomy and Particle Theory, The School of Physics and Astronomy, Nottingham University, University Park Campus, Nottingham NG7 2RD (United Kingdom); Brough, S. [Australian Astronomical Observatory, P.O. Box 296, Epping, NSW 1710 (Australia); Cooray, A. [Department of Physics and Astronomy, University of California, Irvine, CA 92697 (United States); Dariush, A. [Physics Department, Imperial College, Prince Consort Road, London SW7 2AZ (United Kingdom); De Zotti, G. [INAF-Osservatorio Astronomico di Padova, Vicolo Osservatorio 5, I-35122 Padova (Italy); Dunne, L., E-mail: meiert.grootes@mpi-hd.mpg.de [Department of Physics and Astronomy, University of Canterbury, Private Bag 4800, Christchurch 8140 (New Zealand); and others

    2013-03-20

    We report the discovery of a well-defined correlation between B-band face-on central optical depth due to dust, {tau}{sup f}{sub B}, and the stellar mass surface density, {mu}{sub *}, of nearby (z {<=} 0.13) spiral galaxies. This relation was derived from a sample of spiral galaxies taken from the Galaxy and Mass Assembly (GAMA) survey, which were detected in the FIR/submillimeter (submm) in the Herschel-ATLAS science demonstration phase field. Using a quantitative analysis of the NUV attenuation-inclination relation for complete samples of GAMA spirals categorized according to stellar mass surface density, we demonstrate that this correlation can be used to statistically correct for dust attenuation purely on the basis of optical photometry and Sersic-profile morphological fits. Considered together with previously established empirical relationships of stellar mass to metallicity and gas mass, the near linearity and high constant of proportionality of the {tau}{sub B}{sup f} - {mu}{sub *} relation disfavors a stellar origin for the bulk of refractory grains in spiral galaxies, instead being consistent with the existence of a ubiquitous and very rapid mechanism for the growth of dust in the interstellar medium. We use the {tau}{sub B}{sup f} - {mu}{sub *} relation in conjunction with the radiation transfer model for spiral galaxies of Popescu and Tuffs to derive intrinsic scaling relations between specific star formation rate (SFR), stellar mass, and stellar surface density, in which attenuation of the UV light used for the measurement of SFR is corrected on an object-to-object basis. A marked reduction in scatter in these relations is achieved which we demonstrate is due to correction of both the inclination-dependent and face-on components of attenuation. Our results are consistent with a general picture of spiral galaxies in which most of the submm emission originates from grains residing in translucent structures, exposed to UV in the diffuse interstellar

  2. Estimation of surface area concentration of workplace incidental nanoparticles based on number and mass concentrations

    Science.gov (United States)

    Park, J. Y.; Ramachandran, G.; Raynor, P. C.; Kim, S. W.

    2011-10-01

    Surface area was estimated by three different methods using number and/or mass concentrations obtained from either two or three instruments that are commonly used in the field. The estimated surface area concentrations were compared with reference surface area concentrations (SAREF) calculated from the particle size distributions obtained from a scanning mobility particle sizer and an optical particle counter (OPC). The first estimation method (SAPSD) used particle size distribution measured by a condensation particle counter (CPC) and an OPC. The second method (SAINV1) used an inversion routine based on PM1.0, PM2.5, and number concentrations to reconstruct assumed lognormal size distributions by minimizing the difference between measurements and calculated values. The third method (SAINV2) utilized a simpler inversion method that used PM1.0 and number concentrations to construct a lognormal size distribution with an assumed value of geometric standard deviation. All estimated surface area concentrations were calculated from the reconstructed size distributions. These methods were evaluated using particle measurements obtained in a restaurant, an aluminum die-casting factory, and a diesel engine laboratory. SAPSD was 0.7-1.8 times higher and SAINV1 and SAINV2 were 2.2-8 times higher than SAREF in the restaurant and diesel engine laboratory. In the die casting facility, all estimated surface area concentrations were lower than SAREF. However, the estimated surface area concentration using all three methods had qualitatively similar exposure trends and rankings to those using SAREF within a workplace. This study suggests that surface area concentration estimation based on particle size distribution (SAPSD) is a more accurate and convenient method to estimate surface area concentrations than estimation methods using inversion routines and may be feasible to use for classifying exposure groups and identifying exposure trends.

  3. Estimation of surface area concentration of workplace incidental nanoparticles based on number and mass concentrations

    International Nuclear Information System (INIS)

    Park, J. Y.; Ramachandran, G.; Raynor, P. C.; Kim, S. W.

    2011-01-01

    Surface area was estimated by three different methods using number and/or mass concentrations obtained from either two or three instruments that are commonly used in the field. The estimated surface area concentrations were compared with reference surface area concentrations (SA REF ) calculated from the particle size distributions obtained from a scanning mobility particle sizer and an optical particle counter (OPC). The first estimation method (SA PSD ) used particle size distribution measured by a condensation particle counter (CPC) and an OPC. The second method (SA INV1 ) used an inversion routine based on PM1.0, PM2.5, and number concentrations to reconstruct assumed lognormal size distributions by minimizing the difference between measurements and calculated values. The third method (SA INV2 ) utilized a simpler inversion method that used PM1.0 and number concentrations to construct a lognormal size distribution with an assumed value of geometric standard deviation. All estimated surface area concentrations were calculated from the reconstructed size distributions. These methods were evaluated using particle measurements obtained in a restaurant, an aluminum die-casting factory, and a diesel engine laboratory. SA PSD was 0.7–1.8 times higher and SA INV1 and SA INV2 were 2.2–8 times higher than SA REF in the restaurant and diesel engine laboratory. In the die casting facility, all estimated surface area concentrations were lower than SA REF . However, the estimated surface area concentration using all three methods had qualitatively similar exposure trends and rankings to those using SA REF within a workplace. This study suggests that surface area concentration estimation based on particle size distribution (SA PSD ) is a more accurate and convenient method to estimate surface area concentrations than estimation methods using inversion routines and may be feasible to use for classifying exposure groups and identifying exposure trends.

  4. Summer U.S. Surface Air Temperature Variability: Controlling Factors and AMIP Simulation Biases

    Science.gov (United States)

    Merrifield, A.; Xie, S. P.

    2016-02-01

    This study documents and investigates biases in simulating summer surface air temperature (SAT) variability over the continental U.S. in the Coupled Model Intercomparison Project (CMIP5) Atmospheric Model Intercomparison Project (AMIP). Empirical orthogonal function (EOF) and multivariate regression analyses are used to assess the relative importance of circulation and the land surface feedback at setting summer SAT over a 30-year period (1979-2008). In observations, regions of high SAT variability are closely associated with midtropospheric highs and subsidence, consistent with adiabatic theory (Meehl and Tebaldi 2004, Lau and Nath 2012). Preliminary analysis shows the majority of the AMIP models feature high SAT variability over the central U.S., displaced south and/or west of observed centers of action (COAs). SAT COAs in models tend to be concomitant with regions of high sensible heat flux variability, suggesting an excessive land surface feedback in these models modulate U.S. summer SAT. Additionally, tropical sea surface temperatures (SSTs) play a role in forcing the leading EOF mode for summer SAT, in concert with internal atmospheric variability. There is evidence that models respond to different SST patterns than observed. Addressing issues with the bulk land surface feedback and the SST-forced component of atmospheric variability may be key to improving model skill in simulating summer SAT variability over the U.S.

  5. Shapes of an Air Taylor Bubble in Stagnant Liquids Influenced by Different Surface Tensions

    Science.gov (United States)

    Lertnuwat, B.

    2018-02-01

    The aim of this work is to propose an empirical model for predicting shapes of a Taylor bubble, which is a part of slug flows, under different values of the surface tension in stagnant liquids by employing numerical simulations. The k - Ɛ turbulence model was used in the framework of finite volume method for simulating flow fields in a unit of slug flow and also the pressure distribution on a Taylor bubble surface. Assuming that an air pressure distribution inside the Taylor bubble must be uniform, a grid search method was exploited to find an appropriate shape of a Taylor bubble for six values of surface tension. It was found that the shape of a Taylor bubble would be blunter if the surface tension was increased. This was because the surface tension affected the Froude number, controlling the flow around a Taylor bubble. The simulation results were also compared with the Taylor bubble shape, created by the Dumitrescu-and-Taylor model and former studies in order to ensure that they were consistent. Finally, the empirical model was presented from the simulation results.

  6. Supercavitating flow around high-speed underwater projectile near free surface induced by air entrainment

    Directory of Open Access Journals (Sweden)

    Chang Xu

    2018-03-01

    Full Text Available Cavitating flow near free surface is a complicated issue and may provide new inspiration on high-speed surface cruising. This study observes stable supercavitating flow as a new phenomenon in a launch experiment of axisymmetric projectile when the upper side of the projectile coincides with the free surface. A numerical approach is established using large eddy-simulation and volume-of-fluid methods, and good agreements are achieved between numerical and experimental results. Supercavity formation mechanism is revealed by analyzing the experiment photographs and the iso-surface of 90% water volume fraction in numerical results. The entrainment of a large amount of air into the cavity can cause the pressure inside the cavity to similarly increase with the pressure outside the cavity, which makes the actual cavitation number close to zero and is similar to supercavitation. Cases with various headforms of the projectile and cavitation numbers on the cavitating flow, as well as the drag reduction effects are further examined. Results indicate that the present strategy near the free surface could possibly be a new effective approach for high-speed cruising after vigorous design optimization in the future.

  7. Central configurations of the collinear three-body problem and singular surfaces in the mass space

    Energy Technology Data Exchange (ETDEWEB)

    Xie, Zhifu, E-mail: zxie@vsu.edu [Department of Mathematics and Computer Science, Virginia State University, Petersburg, VA 23806 (United States)

    2011-09-12

    This Letter is to provide a new approach to study the phenomena of degeneracy of the number of the collinear central configurations under geometric equivalence. A direct and simple explicit parametric expression of the singular surface H{sub 3} is constructed in the mass space (m{sub 1},m{sub 2},m{sub 3}) element of (R{sup +}){sup 3}. The construction of H{sub 3} is from an inverse respective, that is, by specifying positions for the bodies and then determining the masses that are possible to yield a central configuration. It reveals the relationship between the phenomena of degeneracy and the inverse problem of central configurations. We prove that the number of central configurations is decreased to 3!/2-1=2, m{sub 1}, m{sub 2}, and m{sub 3} are mutually distinct if m element of H{sub 3}. Moreover, we know not only the number of central configurations but also what the nonequivalent central configurations are. -- Highlights: → Provide a new method to study the degeneracy of number of CC. → Results advanced the understanding of number of central configurations. → Singular mass surface H{sub 3} is given by a direct and simple parametric expression. → The proof only requires some basic knowledge of linear algebra. → The method can be applied to some other collinear n-body problem.

  8. Composite Fermi surface in the half-filled Landau level with anisotropic electron mass

    Science.gov (United States)

    Ippoliti, Matteo; Geraedts, Scott; Bhatt, Ravindra

    We study the problem of interacting electrons in the lowest Landau level at half filling in the quantum Hall regime, when the electron dispersion is given by an anisotropic mass tensor. Based on experimental observations and theoretical arguments, the ground state of the system is expected to consist of composite Fermions filling an elliptical Fermi sea, with the anisotropy of the ellipse determined by the competing effects of the isotropic Coulomb interaction and anisotropic electron mass tensor. We test this idea quantitatively by using a numerical density matrix renormalization group method for quantum Hall systems on an infinitely long cylinder. Singularities in the structure factor allow us to map the Fermi surface of the composite Fermions. We compute the composite Fermi surface anisotropy for several values of the electron mass anisotropy which allow us to deduce the functional dependence of the former on the latter. This research was supported by Department of Energy Office of Basic Energy Sciences through Grant No. DE-SC0002140.

  9. Effect of environmental dust particles on laser textured yttria-stabilized zirconia surface in humid air ambient

    Science.gov (United States)

    Yilbas, B. S.; Ali, H.; Al-Sharafi, A.; Al-Sulaiman, F.; Karatas, C.

    2018-05-01

    Zirconium nitride is used as a selective surface for concentrated solar heating applications and one of the methods to form a zirconium nitride is texturing of zirconia surface by a high intensity laser beam under high pressure nitrogen gas environment. Laser texturing also provides hydrophobic surface characteristics via forming micro/nano pillars at the surface; however, environmental dust settlement on textured surface influences the surface characteristics significantly. In the present study, laser texturing of zirconia surface and effects of the dust particles on the textured surface in a humid air ambient are investigated. Analytical tools are used to assess the morphological changes on the laser textured surface prior and after the dust settlement in the humid air ambient. It is found that laser textured surface has hydrophobic characteristics. The mud formed during condensate of water on the dust particles alters the characteristics of the laser textured surface. The tangential force required to remove the dry mud from the textured surface remains high; in which case, the dried liquid solution at the mud-textured surface interface is responsible for the strong adhesion of the dry mud on the textured surface. The textured surface becomes hydrophilic after the dry mud was removed from the surface by a desalinated water jet.

  10. Air mass origins by back trajectory analysis for evaluating atmospheric 210Pb concentrations at Rokkasho, Aomori, Japan

    International Nuclear Information System (INIS)

    Akata, N.; Kawabata, H.; Hasegawa, H.; Kondo, K.; Chikuchi, Y.; Hisamatsu, S.; Inaba, J.; Sato, T.

    2009-01-01

    Atmospheric concentrations of 210 Pb change with various factors such as meso-scale meteorological conditions. We have already reported the biweekly atmospheric 210 Pb concentrations in Rokkasho, Japan for 5 years and found that they had clear seasonal variations: low concentrations in summer and high values in winter to spring. To study the reasons for the seasonal variations, the origins of the air mass flowing to Rokkasho were analyzed by 3-D backward air mass trajectory analysis. Routes of the calculated trajectories were classified into four regions: northeastern and southeastern Asian Continent, sea and other regions. The atmospheric 210 Pb concentrations were well correlated with the frequency of the routes through the northeastern Asian Continent. A non-linear multiple regression analysis of the 210 Pb concentrations and the relative frequencies of the four routes showed good fitting of the predicted values to the observed ones, and indicated that the atmospheric 210 Pb concentrations in Rokkasho depended on the frequency of the air mass from the northeastern Asian Continent. (author)

  11. Features of air masses associated with the deposition of Pseudomonas syringae and Botrytis cinerea by rain and snowfall.

    Science.gov (United States)

    Monteil, Caroline L; Bardin, Marc; Morris, Cindy E

    2014-11-01

    Clarifying the role of precipitation in microbial dissemination is essential for elucidating the processes involved in disease emergence and spread. The ecology of Pseudomonas syringae and its presence throughout the water cycle makes it an excellent model to address this issue. In this study, 90 samples of freshly fallen rain and snow collected from 2005-2011 in France were analyzed for microbiological composition. The conditions favorable for dissemination of P. syringae by this precipitation were investigated by (i) estimating the physical properties and backward trajectories of the air masses associated with each precipitation event and by (ii) characterizing precipitation chemistry, and genetic and phenotypic structures of populations. A parallel study with the fungus Botrytis cinerea was also performed for comparison. Results showed that (i) the relationship of P. syringae to precipitation as a dissemination vector is not the same for snowfall and rainfall, whereas it is the same for B. cinerea and (ii) the occurrence of P. syringae in precipitation can be linked to electrical conductivity and pH of water, the trajectory of the air mass associated with the precipitation and certain physical conditions of the air mass (i.e. temperature, solar radiation exposure, distance traveled), whereas these predictions are different for B. cinerea. These results are pertinent to understanding microbial survival, emission sources and atmospheric processes and how they influence microbial dissemination.

  12. Simulation of heat and mass transfer processes in the experimental section of the air-condensing unit of Scientific Production Company "Turbocon"

    Science.gov (United States)

    Artemov, V. I.; Minko, K. B.; Yan'kov, G. G.; Kiryukhin, A. V.

    2016-05-01

    A mathematical model was developed to be used for numerical analysis of heat and mass transfer processes in the experimental section of the air condenser (ESAC) created in the Scientific Production Company (SPC) "Turbocon" and mounted on the territory of the All-Russia Thermal Engineering Institute. The simulations were performed using the author's CFD code ANES. The verification of the models was carried out involving the experimental data obtained in the tests of ESAC. The operational capability of the proposed models to calculate the processes in steam-air mixture and cooling air and algorithms to take into account the maldistribution in the various rows of tube bundle was shown. Data on the influence of temperature and flow rate of the cooling air on the pressure in the upper header of ESAC, effective heat transfer coefficient, steam flow distribution by tube rows, and the dimensions of the ineffectively operating zones of tube bundle for two schemes of steam-air mixture flow (one-pass and two-pass ones) were presented. It was shown that the pressure behind the turbine (in the upper header) increases significantly at increase of the steam flow rate and reduction of the flow rate of cooling air and its temperature rise, and the maximum value of heat transfer coefficient is fully determined by the flow rate of cooling air. Furthermore, the steam flow rate corresponding to the maximum value of heat transfer coefficient substantially depends on the ambient temperature. The analysis of the effectiveness of the considered schemes of internal coolant flow was carried out, which showed that the two-pass scheme is more effective because it provides lower pressure in the upper header, despite the fact that its hydraulic resistance at fixed flow rate of steam-air mixture is considerably higher than at using the one-pass schema. This result is a consequence of the fact that, in the two-pass scheme, the condensation process involves the larger internal surface of tubes

  13. New air Cherenkov light detectors to study mass composition of cosmic rays with energies above knee region

    Energy Technology Data Exchange (ETDEWEB)

    Tsunesada, Yoshiki, E-mail: tsunesada@cr.phys.titech.ac.jp [Graduate School of Science and Engineering, Tokyo Institute of Technology, Meguro, Tokyo 152-8550 Japan (Japan); Katsuya, Ryoichi, E-mail: katsuya@cr.phys.titech.ac.jp [Graduate School of Science and Engineering, Tokyo Institute of Technology, Meguro, Tokyo 152-8550 Japan (Japan); Mitsumori, Yu; Nakayama, Keisuke; Kakimoto, Fumio; Tokuno, Hisao [Graduate School of Science and Engineering, Tokyo Institute of Technology, Meguro, Tokyo 152-8550 Japan (Japan); Tajima, Norio [RIKEN, Wako, Saitama 351-0198 (Japan); Miranda, Pedro; Salinas, Juan; Tavera, Wilfredo [Instituto de Investigaciones Físicas, Universidad Mayor de San Andrés, La Paz (Bolivia, Plurinational State of)

    2014-11-01

    We have installed a hybrid detection system for air showers generated by cosmic rays with energies greater than 3×10{sup 15}eV at Mount Chacaltaya (5200 m above the sea level), in order to study the mass composition of cosmic rays above the knee region. This detection system comprises an air shower array with 49 scintillation counters in an area of 500 m×650 m, and seven new Cherenkov light detectors installed in a radial direction from the center of the air shower array with a separation of 50 m. It is known that the longitudinal development of a particle cascade in the atmosphere strongly depends on the type of the primary nucleus, and an air shower initiated by a heavier nucleus develops faster than that by a lighter primary of the same energy, because of the differences in the interaction cross-section and the energy per nucleon. This can be measured by detecting the Cherenkov radiation emitted from charged particles in air showers at higher altitudes. In this paper we describe the design and performance of our new non-imaging Cherenkov light detectors at Mount Chacaltaya that are operated in conjunction with the air shower array. The arrival directions and energies of air showers are determined by the shower array, and information about the primary masses is obtained from the Cherenkov light data including the time profiles and lateral distributions. The detector consists of photomultiplier tube (PMT), high-speed ADCs, other control modules, and data storage device. The Cherenkov light signals from an air shower are typically 10–100 ns long, and the waveforms are digitized with a sampling frequency of 1 GHz and recorded in situ without long-distance analog signal transfers. All the Cherenkov light detectors record their time-series data by receiving a triggering signal transmitted from the trigger module of the air shower array, which is fired by a coincidence of shower signals in four neighboring scintillation counters. The optical characteristics of the

  14. Aluminum surface modification by a non-mass-analyzed nitrogen ion beam

    Science.gov (United States)

    Ohira, Shigeo; Iwaki, Masaya

    Non-mass-analyzed nitrogen ion implantation into polycrystal and single crystal aluminum sheets has been carried out at an accelerating voltage of 90 kV and a dose of 1 × 10 18 N ions/cm 2 using a Zymet implanter model Z-100. The pressure during implantation rose to 10 -3 Pa due to the influence of N gas feeding into the ion source. The characteristics of the surface layers were investigated by means of Auger electron spectroscopy (AES), X-ray diffraction (XRD), transmission electron diffraction (TED), and microscopy (TEM). The AES depth profiling shows a rectangular-like distribution of N atoms and little migration of O atoms near the surface. The high dose N-implantation forms c-axis oriented aluminum nitride (AIN) crystallines, and especially irradiation of Al single crystals with N ions leads to the formation of a hcp AlN single crystal. It is concluded that the high dose N-implantation in Al can result in the formation of AlN at room temperature without any thermal annealing. Furthermore, non-mass-analyzed N-implantation at a pressure of 10 -3 Pa of the nitrogen atmosphere causes the formation of pure AlN single crystals in the Al surface layer and consequently it can be practically used for AlN production.

  15. Mass Redistribution in the Core and Time-varying Gravity at the Earth's Surface

    Science.gov (United States)

    Kuang, Wei-Jia; Chao, Benjamin F.; Fang, Ming

    2003-01-01

    The Earth's liquid outer core is in convection, as suggested by the existence of the geomagnetic field in much of the Earth's history. One consequence of the convection is the redistribution of mass resulting from relative motion among fluid parcels with slightly different densities. This time dependent mass redistribution inside the core produces a small perturbation on the gravity field of the Earth. With our numerical dynamo solutions, we find that the mass redistribution (and the resultant gravity field) symmetric about the equator is much stronger than that anti-symmetric about the equator. In particular, J(sub 2) component is the strongest. In addition, the gravity field variation increases with the Rayleigh number that measures the driving force for the geodynamo in the core. With reasonable scaling from the current dynamo solutions, we could expect that at the surface of the Earth, the J(sub 2) variation from the core is on the order of l0(exp -16)/year relative to the mean (i.e. spherically symmetric) gravity field of the Earth. The possible shielding effect due to core-mantle boundary pressure variation loading is likely much smaller and is therefore negligible. Our results suggest that time-varying gravity field perturbation due to core mass redistribution may be measured with modem space geodetic observations, which will result a new means of detecting dynamical processes in the Earth's deep interior.

  16. Surface-assisted laser desorption ionization mass spectrometry techniques for application in forensics.

    Science.gov (United States)

    Guinan, Taryn; Kirkbride, Paul; Pigou, Paul E; Ronci, Maurizio; Kobus, Hilton; Voelcker, Nicolas H

    2015-01-01

    Matrix-assisted laser desorption ionization (MALDI) mass spectrometry (MS) is an excellent analytical technique for the rapid and sensitive analysis of macromolecules (>700 Da), such as peptides, proteins, nucleic acids, and synthetic polymers. However, the detection of smaller organic molecules with masses below 700 Da using MALDI-MS is challenging due to the appearance of matrix adducts and matrix fragment peaks in the same spectral range. Recently, nanostructured substrates have been developed that facilitate matrix-free laser desorption ionization (LDI), contributing to an emerging analytical paradigm referred to as surface-assisted laser desorption ionization (SALDI) MS. Since SALDI enables the detection of small organic molecules, it is rapidly growing in popularity, including in the field of forensics. At the same time, SALDI also holds significant potential as a high throughput analytical tool in roadside, work place and athlete drug testing. In this review, we discuss recent advances in SALDI techniques such as desorption ionization on porous silicon (DIOS), nano-initiator mass spectrometry (NIMS) and nano assisted laser desorption ionization (NALDI™) and compare their strengths and weaknesses with particular focus on forensic applications. These include the detection of illicit drug molecules and their metabolites in biological matrices and small molecule detection from forensic samples including banknotes and fingerprints. Finally, the review highlights recent advances in mass spectrometry imaging (MSI) using SALDI techniques. © 2014 Wiley Periodicals, Inc.

  17. Sequential estimation of surface water mass changes from daily satellite gravimetry data

    Science.gov (United States)

    Ramillien, G. L.; Frappart, F.; Gratton, S.; Vasseur, X.

    2015-03-01

    We propose a recursive Kalman filtering approach to map regional spatio-temporal variations of terrestrial water mass over large continental areas, such as South America. Instead of correcting hydrology model outputs by the GRACE observations using a Kalman filter estimation strategy, regional 2-by-2 degree water mass solutions are constructed by integration of daily potential differences deduced from GRACE K-band range rate (KBRR) measurements. Recovery of regional water mass anomaly averages obtained by accumulation of information of daily noise-free simulated GRACE data shows that convergence is relatively fast and yields accurate solutions. In the case of cumulating real GRACE KBRR data contaminated by observational noise, the sequential method of step-by-step integration provides estimates of water mass variation for the period 2004-2011 by considering a set of suitable a priori error uncertainty parameters to stabilize the inversion. Spatial and temporal averages of the Kalman filter solutions over river basin surfaces are consistent with the ones computed using global monthly/10-day GRACE solutions from official providers CSR, GFZ and JPL. They are also highly correlated to in situ records of river discharges (70-95 %), especially for the Obidos station where the total outflow of the Amazon River is measured. The sparse daily coverage of the GRACE satellite tracks limits the time resolution of the regional Kalman filter solutions, and thus the detection of short-term hydrological events.

  18. EXPERIMENTAL COMPARISON OF THE AEROSOL METHOD OF DISINFECTION OF AIR AND SURFACES CONTAMINATED BY M. TUBERCULOSIS

    Directory of Open Access Journals (Sweden)

    V. V. Kuzin

    2018-01-01

    Full Text Available The objective of the study: to analyze efficiency of an aerosol method of M. tuberculosis deactivation in the air and on surfaces versus the conventional methods of the disinfectants' application.Subjects and Methods. The article describes the evaluation of efficiency of the aerosol method of M. tuberculosis, H37Rv strain, deactivation on surfaces (tested objects made of linoleum and in the air using the disinfectant of Green Dez based on chlorine dioxide versus deactivation through wiping and irrigation.The efficiency of disinfectant was tested by the device of 099С А4224 manufactured by Glas-Col, USA, using the air sampler of PU-1B, Russia.The Mobile Hygienic Center (MNC, Russia, was used for application of the disinfectant, wiping and irrigation was done using the disperser of Avtomaks AO-2, Russia.The bacterial aerosol was generated in the Glass-Col chamber with the concentration 5 ± 2.5 × 102 CFU/cm3, by spraying the suspension of M. tuberculosis, H37Rv strain. After that, the disinfectant spray was supplied to the chamber, where linoleum objects were placed horizontally on a variety of surfaces. In order to evaluate efficiency of surface treatment by wiping, the test objects were wiped with a tissue, soaked with the solution of Green Dez, based on consumption of 100-150 ml/m2. In 15, 30 and 60 minutes, the samples of inactivated M. tuberculosis aerosol were collected using an aspirator, chambers with test objects were closed and placed in the vent hood. To monitor efficiency of disinfection of the test object surfaces, the rinse blanks were done by wiping the surface with a sterile gauze wad, soaked with 0.5% of sodium thiosulfate solution.The samples of deactivated aerosol and rinse blanks from the surfaces of test objects were put into Petri dishes with Middlebrook 7H11 medium. The cultures were incubated in the thermostat at the temperature of 37 ± 1° C for 10-21 days, and the number of colonies was counted.Sterile water was used

  19. Quantifying changes in spatial patterns of surface air temperature dynamics over several decades

    Science.gov (United States)

    Zappalà, Dario A.; Barreiro, Marcelo; Masoller, Cristina

    2018-04-01

    We study daily surface air temperature (SAT) reanalysis in a grid over the Earth's surface to identify and quantify changes in SAT dynamics during the period 1979-2016. By analysing the Hilbert amplitude and frequency we identify the regions where relative variations are most pronounced (larger than ±50 % for the amplitude and ±100 % for the frequency). Amplitude variations are interpreted as due to changes in precipitation or ice melting, while frequency variations are interpreted as due to a northward shift of the inter-tropical convergence zone (ITCZ) and to a widening of the rainfall band in the western Pacific Ocean. The ITCZ is the ascending branch of the Hadley cell, and thus by affecting the tropical atmospheric circulation, ITCZ migration has far-reaching climatic consequences. As the methodology proposed here can be applied to many other geophysical time series, our work will stimulate new research that will advance the understanding of climate change impacts.

  20. Numerical investigation of the energy performance of a guideless irregular heat and mass exchanger with corrugated heat transfer surface for dew point cooling

    International Nuclear Information System (INIS)

    Xu, Peng; Ma, Xiaoli; Diallo, Thierno M.O.; Zhao, Xudong; Fancey, Kevin; Li, Deying; Chen, Hongbing

    2016-01-01

    The paper presents an investigation into the energy performance of a novel irregular heat and mass exchanger for dew point cooling which, compared to the existing flat-plate heat exchangers, removed the use of the channel supporting guides and implemented the corrugated heat transfer surface, thus expecting to achieve the reduced air flow resistance, increased heat transfer area, and improved energy efficiency (i.e. Coefficient of Performance (COP)) of the air cooling process. CFD simulation was carried out to determine the flow resistance (K) factors of various elements within the dry and wet channels of the exchanger, while the ‘finite-element’ based ‘Newton-iteration’ numerical simulation was undertaken to investigate its cooling capacity, cooling effectiveness and COP at various geometrical and operational conditions. Compared to the existing flat-plate heat and mass exchangers with the same geometrical dimensions and operational conditions, the new irregular exchanger could achieve 32.9%–37% higher cooling capacity, dew-point and wet-bulb effectiveness, 29.7%–33.3% higher COP, and 55.8%–56.2% lower pressure drop. While undertaking dew point air cooling, the irregular heat and mass exchanger had the optimum air velocity of 1 m/s within the flow channels and working-to-intake air ratio of 0.3, which allowed the highest cooling capacity and COP to be achieved. In terms of the exchanger dimensions, the optimum height of the channel was 5 mm while its length was in the range 1–2 m. Overall, the proposed irregular heat and mass exchanger could lead to significant enhanced energy performance compared to the existing flat-plate dew point cooling heat exchanger of the same geometrical dimensions. To achieve the same amount cooling output, the irregular heat and mass exchanger had the reduced size and cost against the flat-plate ones. - Highlights: • Numerical investigation of an irregular heat and mass exchanger was undertaken. • A

  1. Aeromobile Sprawl. Mass Air Travel and its Socio-Environmental Impact in 1970s Canada

    Directory of Open Access Journals (Sweden)

    Bret Edwards

    2017-12-01

    Full Text Available This article examines the rise of aeromobile sprawl, which is defined here as aviation’s socio-environmental impact on people, places, and things, in Canada during the 1970s. It links aeromobile sprawl largely to state-led airport development and the effect that upgrading, expanding, and building new airports had on communities and landscapes. Accordingly, it shows that while aeromobile sprawl was to some extent an outcome of postwar developments not limited to aviation, the Canadian government and its partners also contributed to sprawl by endorsing various policies and strategies that shifted over the period in question. At the same time, these actions did not go unnoticed. Public critiques of aeromobile sprawl emerged as people increasingly objected to larger and busier airports operating near populated and non-industrial areas. This article demonstrates that debates in Canada about airport development and the rapid growth of aviation revealed sharply diverging views about how to best accommodate the mobility requirements of mass air travel within the country’s natural and built environments in the 1970s. *** Dieser Aufsatz untersucht für Kanada in den 1970er-Jahren die gesteigerte Ausdehnung der Aeromobilität, verstanden als Gesamtheit der sozialen und ökologischen Wirkungen der Luftfahrt für Menschen, Orte und Dinge. Die Expansion des Flugverkehrs war vornehmlich ein Resultat des staatlich geförderten Aus- und Neubaus von Flughäfen – mit gravierenden Effekten für Gesellschaften und Landschaften im jeweiligen Einzugsgebiet. Zwar hing der Anstieg des Flugverkehrs auch mit generellen Trends der Nachkriegszeit zusammen, doch verstärkten die kanadische Regierung und ihre Partner dies noch durch verschiedene Strategien, die sich im Untersuchungszeitraum änderten. Zugleich blieb diese Politik nicht unbeobachtet und nicht unumstritten. Öffentliche Kritik richtete sich vor allem gegen Großflughäfen in der Nähe dicht besiedelter

  2. Improving Surface Mass Balance Over Ice Sheets and Snow Depth on Sea Ice

    Science.gov (United States)

    Koenig, Lora Suzanne; Box, Jason; Kurtz, Nathan

    2013-01-01

    Surface mass balance (SMB) over ice sheets and snow on sea ice (SOSI) are important components of the cryosphere. Large knowledge gaps remain in scientists' abilities to monitor SMB and SOSI, including insufficient measurements and difficulties with satellite retrievals. On ice sheets, snow accumulation is the sole mass gain to SMB, and meltwater runoff can be the dominant single loss factor in extremely warm years such as 2012. SOSI affects the growth and melt cycle of the Earth's polar sea ice cover. The summer of 2012 saw the largest satellite-recorded melt area over the Greenland ice sheet and the smallest satellite-recorded Arctic sea ice extent, making this meeting both timely and relevant.

  3. Large scale mass redistribution and surface displacement from GRACE and SLR

    Science.gov (United States)

    Cheng, M.; Ries, J. C.; Tapley, B. D.

    2012-12-01

    Mass transport between the atmosphere, ocean and solid earth results in the temporal variations in the Earth gravity field and loading induced deformation of the Earth. Recent space-borne observations, such as GRACE mission, are providing extremely high precision temporal variations of gravity field. The results from 10-yr GRACE data has shown a significant annual variations of large scale vertical and horizontal displacements occurring over the Amazon, Himalayan region and South Asia, African, and Russian with a few mm amplitude. Improving understanding from monitoring and modeling of the large scale mass redistribution and the Earth's response are a critical for all studies in the geosciences, in particular for determination of Terrestrial Reference System (TRS), including geocenter motion. This paper will report results for the observed seasonal variations in the 3-dimentional surface displacements of SLR and GPS tracking stations and compare with the prediction from time series of GRACE monthly gravity solution.

  4. Heat and mass transfer in magnetohydrodynamic Casson fluid over an exponentially permeable stretching surface

    Directory of Open Access Journals (Sweden)

    C.S.K. Raju

    2016-03-01

    Full Text Available In this study we analyzed the flow, heat and mass transfer behavior of Casson fluid past an exponentially permeable stretching surface in presence of thermal radiation, magneticfield, viscous dissipation, heat source and chemical reaction. We presented dual solutions by comparing the results of the Casson fluid with the Newtonian fluid. The governing partial nonlinear differential equations of the flow, heat and mass transfer are transformed into ordinary differential equations by using similarity transformation and solved numerically by using Matlab bvp4c package. The effects of various non-dimensional governing parameters on velocity, temperature and concentration profiles are discussed and presented graphically. Also, the friction factor, Nusselt and Sherwood numbers are analyzed and presented in tabular form for both Casson and Newtonian fluids separately. Under some special conditions the results of the present study have an excellent agreement with existing studies for both Casson and Newtonian fluid cases.

  5. Ion optics of a new time-of-flight mass spectrometer for quantitative surface analysis

    International Nuclear Information System (INIS)

    Veryovkin, Igor V.; Calaway, Wallis F.; Pellin, Michael J.

    2004-01-01

    A new time-of-flight instrument for quantitative surface analysis was developed and constructed at Argonne National Laboratory. It implements ion sputtering and laser desorption for probing analyzed samples and can operate in regimes of secondary neutral mass spectrometry with laser post-ionization and secondary ion mass spectrometry. The instrument incorporates two new ion optics developments: (1) 'push-pull' front end ion optics and (2) focusing and deflecting lens. Implementing these novel elements significantly enhance analytical capabilities of the instrument. Extensive three-dimensional computer simulations of the instrument were conducted in SIMION 3D (c) to perfect its ion optics. The operating principles of the new ion optical systems are described, and a scheme of the new instrument is outlined together with its operating modes

  6. MOIRCS DEEP SURVEY. V. A UNIVERSAL RELATION FOR STELLAR MASS AND SURFACE BRIGHTNESS OF GALAXIES

    International Nuclear Information System (INIS)

    Ichikawa, Takashi; Kajisawa, Masaru; Yamada, Toru; Akiyama, Masayuki; Yoshikawa, Tomohiro; Onodera, Masato; Konishi, Masahiro

    2010-01-01

    We present a universal linear correlation between the stellar mass and surface brightness (SB) of galaxies at 0.3 -2.0∼-0.8 , in addition to dimming as (1 + z) 4 by the cosmological expansion effect. The brightening depends on galaxy color and stellar mass. The blue population (rest-frame U - V -0.8±0.3 in the rest-V band. On the other hand, the red population (U - V>0) and the massive galaxies (M * >10 10 M sun ) show stronger brightening, (1 + z) -1.5±0.1 . By comparison with galaxy evolution models, the phenomena are well understood by the pure luminosity evolution of galaxies out to z ∼ 3.

  7. Electric field measurements in nanosecond pulse discharges in air over liquid water surface

    Science.gov (United States)

    Simeni Simeni, Marien; Baratte, Edmond; Zhang, Cheng; Frederickson, Kraig; Adamovich, Igor V.

    2018-01-01

    Electric field in nanosecond pulse discharges in ambient air is measured by picosecond four-wave mixing, with absolute calibration by a known electrostatic field. The measurements are done in two geometries, (a) the discharge between two parallel cylinder electrodes placed inside quartz tubes, and (b) the discharge between a razor edge electrode and distilled water surface. In the first case, breakdown field exceeds DC breakdown threshold by approximately a factor of four, 140 ± 10 kV cm-1. In the second case, electric field is measured for both positive and negative pulse polarities, with pulse durations of ˜10 ns and ˜100 ns, respectively. In the short duration, positive polarity pulse, breakdown occurs at 85 kV cm-1, after which the electric field decreases over several ns due to charge separation in the plasma, with no field reversal detected when the applied voltage is reduced. In a long duration, negative polarity pulse, breakdown occurs at a lower electric field, 30 kV cm-1, after which the field decays over several tens of ns and reverses direction when the applied voltage is reduced at the end of the pulse. For both pulse polarities, electric field after the pulse decays on a microsecond time scale, due to residual surface charge neutralization by transport of opposite polarity charges from the plasma. Measurements 1 mm away from the discharge center plane, ˜100 μm from the water surface, show that during the voltage rise, horizontal field component (Ex ) lags in time behind the vertical component (Ey ). After breakdown, Ey is reduced to near zero and reverses direction. Further away from the water surface (≈0.9 mm), Ex is much higher compared to Ey during the entire voltage pulse. The results provide insight into air plasma kinetics and charge transport processes near plasma-liquid interface, over a wide range of time scales.

  8. Surface modification of polyester fabrics by atmospheric-pressure air/He plasma for color strength and adhesion enhancement

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Chunming, E-mail: zcm1229@126.com [College of Textiles and Clothing, Qingdao University, Qingdao 266071 (China); Sunvim Grp Co Ltd, Gaomi 261500 (China); Zhao, Meihua; Wang, Libing; Qu, Lijun [College of Textiles and Clothing, Qingdao University, Qingdao 266071 (China); Men, Yajing [Sunvim Grp Co Ltd, Gaomi 261500 (China)

    2017-04-01

    Highlights: • Air/He plasma gave hydrophilicity on polyester surface and decreased contact angle to 18°. • The roughness of polyester increased and pit-like structures appeared on the surface after plasma treatment. • XPS confirmed the generation of new functional groups on polyester fabric. • The improved pigment color yield and anti-bleeding performance were contributed by the alteration of pigment adhesion. • The air/He plasma was more effective than air plasma at the same treatment time. - Abstract: Surface properties of water-based pigmented inks for ink-jet printed polyester fabrics were modified with atmospheric-pressure air/He plasma to improve the color strength and pigment adhesion of the treated surfaces. The influence of various parameters, including the surface morphology, chemical compositions, surface energy and dynamic contact angles of the control and plasma treated samples was studied. Color strength and edge definition were used to evaluate the ink-jet printing performance of fabrics. The change in pigment adhesion to polyester fibers was analyzed by SEM (scanning electron microscopy). AFM (Atomic force microscope) and XPS (X-ray photoelectron spectroscopy) analyses indicated the increase in surface roughness and the oxygen-containing polar groups(C=O, C−OH and COOH) reinforced the fixation of pigments on the fiber surface. The result from this study suggested that the improved pigment color yield was clearly affected by alteration of pigment adhesion enhanced by plasma surface modification. Polyester fabrics exhibited better surface property and ink-jet printing performance after the air/He mixture plasma treatment comparing with those after air plasma treatment.

  9. Surface modification of polyester fabrics by atmospheric-pressure air/He plasma for color strength and adhesion enhancement

    International Nuclear Information System (INIS)

    Zhang, Chunming; Zhao, Meihua; Wang, Libing; Qu, Lijun; Men, Yajing

    2017-01-01

    Highlights: • Air/He plasma gave hydrophilicity on polyester surface and decreased contact angle to 18°. • The roughness of polyester increased and pit-like structures appeared on the surface after plasma treatment. • XPS confirmed the generation of new functional groups on polyester fabric. • The improved pigment color yield and anti-bleeding performance were contributed by the alteration of pigment adhesion. • The air/He plasma was more effective than air plasma at the same treatment time. - Abstract: Surface properties of water-based pigmented inks for ink-jet printed polyester fabrics were modified with atmospheric-pressure air/He plasma to improve the color strength and pigment adhesion of the treated surfaces. The influence of various parameters, including the surface morphology, chemical compositions, surface energy and dynamic contact angles of the control and plasma treated samples was studied. Color strength and edge definition were used to evaluate the ink-jet printing performance of fabrics. The change in pigment adhesion to polyester fibers was analyzed by SEM (scanning electron microscopy). AFM (Atomic force microscope) and XPS (X-ray photoelectron spectroscopy) analyses indicated the increase in surface roughness and the oxygen-containing polar groups(C=O, C−OH and COOH) reinforced the fixation of pigments on the fiber surface. The result from this study suggested that the improved pigment color yield was clearly affected by alteration of pigment adhesion enhanced by plasma surface modification. Polyester fabrics exhibited better surface property and ink-jet printing performance after the air/He mixture plasma treatment comparing with those after air plasma treatment.

  10. Surface acoustic wave nebulization of peptides as a microfluidic interface for mass spectrometry.

    Science.gov (United States)

    Heron, Scott R; Wilson, Rab; Shaffer, Scott A; Goodlett, David R; Cooper, Jonathan M

    2010-05-15

    We describe the fabrication of a surface acoustic wave (SAW) device on a LiNbO(3) piezoelectric transducer for the transfer of nonvolatile analytes to the gas phase at atmospheric pressure (a process referred to as nebulization or atomization). We subsequently show how such a device can be used in the field of mass spectrometry (MS) detection, demonstrating that SAW nebulization (SAWN) can be performed either in a discontinuous or pulsed mode, similar to that for matrix assisted laser desorption ionization (MALDI) or in a continuous mode like electrospray ionization (ESI). We present data showing the transfer of peptides to the gas phase, where ions are detected by MS. These peptide ions were subsequently fragmented by collision-induced dissociation, from which the sequence was assigned. Unlike MALDI mass spectra, which are typically contaminated with matrix ions at low m/z, the SAWN generated spectra had no such interference. In continuous mode, the SAWN plume was sampled on a microsecond time scale by a linear ion trap mass spectrometer and produced multiply charged peptide precursor ions with a charge state distribution shifted to higher m/z compared to an identical sample analyzed by ESI. The SAWN technology also provides the opportunity to re-examine a sample from a flat surface, repeatedly. The process can be performed without the need for capillaries, which can clog, reservoirs, which dilute the sample, and electrodes, which when in direct contact with sample, cause unwanted electrochemical oxidation. In both continuous and pulsed sampling modes, the quality of precursor ion scans and tandem mass spectra of peptides was consistent across the plume's lifetime.

  11. International system of units traceable results of Hg mass concentration at saturation in air from a newly developed measurement procedure.

    Science.gov (United States)

    Quétel, Christophe R; Zampella, Mariavittoria; Brown, Richard J C; Ent, Hugo; Horvat, Milena; Paredes, Eduardo; Tunc, Murat

    2014-08-05

    Data most commonly used at present to calibrate measurements of mercury vapor concentrations in air come from a relationship known as the "Dumarey equation". It uses a fitting relationship to experimental results obtained nearly 30 years ago. The way these results relate to the international system of units (SI) is not known. This has caused difficulties for the specification and enforcement of limit values for mercury concentrations in air and in emissions to air as part of national or international legislation. Furthermore, there is a significant discrepancy (around 7% at room temperature) between the Dumarey data and data calculated from results of mercury vapor pressure measurements in the presence of only liquid mercury. As an attempt to solve some of these problems, a new measurement procedure is described for SI traceable results of gaseous Hg concentrations at saturation in milliliter samples of air. The aim was to propose a scheme as immune as possible to analytical biases. It was based on isotope dilution (ID) in the liquid phase with the (202)Hg enriched certified reference material ERM-AE640 and measurements of the mercury isotope ratios in ID blends, subsequent to a cold vapor generation step, by inductively coupled plasma mass spectrometry. The process developed involved a combination of interconnected valves and syringes operated by computer controlled pumps and ensured continuity under closed circuit conditions from the air sampling stage onward. Quantitative trapping of the gaseous mercury in the liquid phase was achieved with 11.5 μM KMnO4 in 2% HNO3. Mass concentrations at saturation found from five measurements under room temperature conditions were significantly higher (5.8% on average) than data calculated from the Dumarey equation, but in agreement (-1.2% lower on average) with data based on mercury vapor pressure measurement results. Relative expanded combined uncertainties were estimated following a model based approach. They ranged from 2

  12. An updated global grid point surface air temperature anomaly data set: 1851--1990

    Energy Technology Data Exchange (ETDEWEB)

    Sepanski, R.J.; Boden, T.A.; Daniels, R.C.

    1991-10-01

    This document presents land-based monthly surface air temperature anomalies (departures from a 1951--1970 reference period mean) on a 5{degree} latitude by 10{degree} longitude global grid. Monthly surface air temperature anomalies (departures from a 1957--1975 reference period mean) for the Antarctic (grid points from 65{degree}S to 85{degree}S) are presented in a similar way as a separate data set. The data were derived primarily from the World Weather Records and the archives of the United Kingdom Meteorological Office. This long-term record of temperature anomalies may be used in studies addressing possible greenhouse-gas-induced climate changes. To date, the data have been employed in generating regional, hemispheric, and global time series for determining whether recent (i.e., post-1900) warming trends have taken place. This document also presents the monthly mean temperature records for the individual stations that were used to generate the set of gridded anomalies. The periods of record vary by station. Northern Hemisphere station data have been corrected for inhomogeneities, while Southern Hemisphere data are presented in uncorrected form. 14 refs., 11 figs., 10 tabs.

  13. Temporal and spatial assessments of minimum air temperature using satellite surface temperature measurements in Massachusetts, USA.

    Science.gov (United States)

    Kloog, Itai; Chudnovsky, Alexandra; Koutrakis, Petros; Schwartz, Joel

    2012-08-15

    Although meteorological stations provide accurate air temperature observations, their spatial coverage is limited and thus often insufficient for epidemiological studies. Satellite data expand spatial coverage, enhancing our ability to estimate near surface air temperature (Ta). However, the derivation of Ta from surface temperature (Ts) measured by satellites is far from being straightforward. In this study, we present a novel approach that incorporates land use regression, meteorological variables and spatial smoothing to first calibrate between Ts and Ta on a daily basis and then predict Ta for days when satellite Ts data were not available. We applied mixed regression models with daily random slopes to calibrate Moderate Resolution Imaging Spectroradiometer (MODIS) Ts data with monitored Ta measurements for 2003. Then, we used a generalized additive mixed model with spatial smoothing to estimate Ta in days with missing Ts. Out-of-sample tenfold cross-validation was used to quantify the accuracy of our predictions. Our model performance was excellent for both days with available Ts and days without Ts observations (mean out-of-sample R(2)=0.946 and R(2)=0.941 respectively). Furthermore, based on the high quality predictions we investigated the spatial patterns of Ta within the study domain as they relate to urban vs. non-urban land uses. Copyright © 2012 Elsevier B.V. All rights reserved.

  14. Corresponding Relation between Warm Season Precipitation Extremes and Surface Air Temperature in South China

    Institute of Scientific and Technical Information of China (English)

    SUN; Wei; LI; Jian; YU; Ru-Cong

    2013-01-01

    Hourly data of 42 rain gauges over South China during 1966–2005 were used to analyze the corresponding relation between precipitation extremes and surface air temperature in the warm season(May to October).The results show that below 25℃,both daily and hourly precipitation extremes in South China increase with rising temperature.More extreme events transit to the two-time Clausius-Clapeyron(CC)relationship at lower temperatures.Daily as well as hourly precipitation extremes have a decreasing tendency nearly above 25℃,among which the decrease of hourly extremes is much more significant.In order to investigate the efects of rainfall durations,hourly precipitation extremes are presented by short duration and long duration precipitation,respectively.Results show that the dramatic decrease of hourly rainfall intensities above 25℃ is mainly caused by short duration precipitation,and long duration precipitation extremes rarely occur in South China when surface air temperature surpasses 28℃.

  15. Biodegradable polyester films from renewable aleuritic acid: surface modifications induced by melt-polycondensation in air

    International Nuclear Information System (INIS)

    Benítez, José Jesús; De Vargas-Parody, María Inmaculada; Cruz-Carrillo, Miguel Antonio; Heredia-Guerrero, José Alejandro; Morales-Flórez, Victor; De la Rosa-Fox, Nicolás; Heredia, Antonio

    2016-01-01

    Good water barrier properties and biocompatibility of long-chain biopolyesters like cutin and suberin have inspired the design of synthetic mimetic materials. Most of these biopolymers are made from esterified mid-chain functionalized ω-long chain hydroxyacids. Aleuritic (9,10,16-trihydroxypalmitic) acid is such a polyhydroxylated fatty acid and is also the major constituent of natural lac resin, a relatively abundant and renewable resource. Insoluble and thermostable films have been prepared from aleuritic acid by melt-condensation polymerization in air without catalysts, an easy and attractive procedure for large scale production. Intended to be used as a protective coating, the barrier's performance is expected to be conditioned by physical and chemical modifications induced by oxygen on the air-exposed side. Hence, the chemical composition, texture, mechanical behavior, hydrophobicity, chemical resistance and biodegradation of the film surface have been studied by attenuated total reflection–Fourier transform infrared spectroscopy (ATR–FTIR), atomic force microscopy (AFM), nanoindentation and water contact angle (WCA). It has been demonstrated that the occurrence of side oxidation reactions conditions the surface physical and chemical properties of these polyhydroxyester films. Additionally, the addition of palmitic acid to reduce the presence of hydrophilic free hydroxyl groups was found to have a strong influence on these parameters. (paper)

  16. Data acquisition and processing system for surface ionization mass spectrometers (types MS5 and R20)

    International Nuclear Information System (INIS)

    Dubois, J.-C.; Retali, G.; Grandcollot, P.; Hagemann, R.

    1977-01-01

    The data acquisition and processing system developed for surface ionization mass spectrometers is described. The main interest of the system is to shorten significantly the duration of isotopic analysis, the results of which are printed almost immediately after the end of the acquisition of the data. The quality of the results is also improved, particularly for isotopes at low concentration owing to an automatic range selection unit driven by the computer. The processing program, which includes several options, is adapted to all types of isotopic analysis. This system, in use for more than two years, has demonstrated its versatility and its safety [fr

  17. A coupled mass transfer and surface complexation model for uranium (VI) removal from wastewaters

    International Nuclear Information System (INIS)

    Lenhart, J.; Figueroa, L.A.; Honeyman, B.D.

    1994-01-01

    A remediation technique has been developed for removing uranium (VI) from complex contaminated groundwater using flake chitin as a biosorbent in batch and continuous flow configurations. With this system, U(VI) removal efficiency can be predicted using a model that integrates surface complexation models, mass transport limitations and sorption kinetics. This integration allows the reactor model to predict removal efficiencies for complex groundwaters with variable U(VI) concentrations and other constituents. The system has been validated using laboratory-derived kinetic data in batch and CSTR systems to verify the model predictions of U(VI) uptake from simulated contaminated groundwater

  18. Monitoring glacier albedo as a proxy to derive summer and annual surface mass balances from optical remote-sensing data

    Science.gov (United States)

    Davaze, Lucas; Rabatel, Antoine; Arnaud, Yves; Sirguey, Pascal; Six, Delphine; Letreguilly, Anne; Dumont, Marie

    2018-01-01

    Less than 0.25 % of the 250 000 glaciers inventoried in the Randolph Glacier Inventory (RGI V.5) are currently monitored with in situ measurements of surface mass balance. Increasing this archive is very challenging, especially using time-consuming methods based on in situ measurements, and complementary methods are required to quantify the surface mass balance of unmonitored glaciers. The current study relies on the so-called albedo method, based on the analysis of albedo maps retrieved from optical satellite imagery acquired since 2000 by the MODIS sensor, on board the TERRA satellite. Recent studies revealed substantial relationships between summer minimum glacier-wide surface albedo and annual surface mass balance, because this minimum surface albedo is directly related to the accumulation-area ratio and the equilibrium-line altitude. On the basis of 30 glaciers located in the French Alps where annual surface mass balance data are available, our study conducted on the period 2000-2015 confirms the robustness and reliability of the relationship between the summer minimum surface albedo and the annual surface mass balance. For the ablation season, the integrated summer surface albedo is significantly correlated with the summer surface mass balance of the six glaciers seasonally monitored. These results are promising to monitor both annual and summer glacier-wide surface mass balances of individual glaciers at a regional scale using optical satellite images. A sensitivity study on the computed cloud masks revealed a high confidence in the retrieved albedo maps, restricting the number of omission errors. Albedo retrieval artifacts have been detected for topographically incised glaciers, highlighting limitations in the shadow correction algorithm, although inter-annual comparisons are not affected by systematic errors.

  19. Effects of ozone-vegetation coupling on surface ozone air quality via biogeochemical and meteorological feedbacks

    Science.gov (United States)

    Sadiq, Mehliyar; Tai, Amos P. K.; Lombardozzi, Danica; Martin, Maria Val

    2017-02-01

    Tropospheric ozone is one of the most hazardous air pollutants as it harms both human health and plant productivity. Foliage uptake of ozone via dry deposition damages photosynthesis and causes stomatal closure. These foliage changes could lead to a cascade of biogeochemical and biogeophysical effects that not only modulate the carbon cycle, regional hydrometeorology and climate, but also cause feedbacks onto surface ozone concentration itself. In this study, we implement a semi-empirical parameterization of ozone damage on vegetation in the Community Earth System Model to enable online ozone-vegetation coupling, so that for the first time ecosystem structure and ozone concentration can coevolve in fully coupled land-atmosphere simulations. With ozone-vegetation coupling, present-day surface ozone is simulated to be higher by up to 4-6 ppbv over Europe, North America and China. Reduced dry deposition velocity following ozone damage contributes to ˜ 40-100 % of those increases, constituting a significant positive biogeochemical feedback on ozone air quality. Enhanced biogenic isoprene emission is found to contribute to most of the remaining increases, and is driven mainly by higher vegetation temperature that results from lower transpiration rate. This isoprene-driven pathway represents an indirect, positive meteorological feedback. The reduction in both dry deposition and transpiration is mostly associated with reduced stomatal conductance following ozone damage, whereas the modification of photosynthesis and further changes in ecosystem productivity are found to play a smaller role in contributing to the ozone-vegetation feedbacks. Our results highlight the need to consider two-way ozone-vegetation coupling in Earth system models to derive a more complete understanding and yield more reliable future predictions of ozone air quality.

  20. Sea Surface Temperature from MODIS during Saharan Air Layer outbreaks: Multichannel vs Optimal Estimation.

    Science.gov (United States)

    Szczodrak, G.; Minnett, P. J.

    2017-12-01

    The current Sea-Surface Temperature (SST) retrieval algorithms applied to MODIS and VIIRS data are build on the Non-Linear SST algorithm (NLSST Walton et al., 1998). This algorithm is based on combination of top-of-atmosphere brightness temperatures, T11 and T12 measured at λ= 11µm and 12µm. The algorithm has a set of coefficients derived using collocated measurements of SST temperature from drifting buoys (Match-Up Data Base - MUDB). NLSST produces accurate SST retrievals in conditions that are similar to those of the represented in the MUDB. When conditions deviate from typical, the errors are larger. An alternative approach of estimating the SST from radiance measurements is based on the Optimal Estimation (OE). The OE approach is not tied to a MUDB so OESST should be free of the systematic biases seen in NLSST retrievals in anomalous conditions. OE uses prior knowledge or estimation of a system as an input of a forward model to simulate `observations' and seeks to minimize the difference between these simulated observation and actual measurements in the space of the state variables. One situation that leads to significant bias in NLSST occurs in Northern Atlantic near the African coast during Saharan Air Layer (SAL) outbreaks. Typically, the atmosphere in this region is moist and these conditions are represented in the coefficients of the NLSST algorithm. During SAL events, moist air is replaced by a layer of very dry air; the established coefficients are no longer representative. During a number of research cruises in the North Atlantic affected by the SAL, we have collected radiometric SST measurements from ships using the Marine Atmosphere Emitted Radiance Interferometer (M-AERI), and frequent measurements of the atmospheric state with radiosondes launched from the ships. Using these data, we investigate if the OE approach is capable of improving the accuracy of the SST retrieval from MODIS under the conditions of the dry air outbreak from the Sahara.

  1. Surface modification of bone char for removal of formaldehyde from air

    Energy Technology Data Exchange (ETDEWEB)

    Rezaee, Abbas, E-mail: rezaee@modares.ac.ir [Environmental Health Department, Faculty of Medical Sciences, Tarbiat Modares University, Tehran (Iran, Islamic Republic of); Rangkooy, Hosseinali [Environmental Health Department, Faculty of Medical Sciences, Tarbiat Modares University, Tehran (Iran, Islamic Republic of); Occupational Health Department, Faculty of Health, Jondishapor Medical Sciences University, Ahvaz (Iran, Islamic Republic of); Jonidi-Jafari, Ahmad; Khavanin, Ali [Environmental Health Department, Faculty of Medical Sciences, Tarbiat Modares University, Tehran (Iran, Islamic Republic of)

    2013-12-01

    The aim of this study was to evaluate the adsorption performance of bone char (BC) modified with acetic acid for formaldehyde removal from polluted air. The porous structure, surface characteristics and functional groups involved in formaldehyde adsorption were determined using the Brunauer–Emmett–Teller (BET) method, scanning electron microscope (SEM) equipped with energy dispersive X-ray (EDX) and Fourier transform infrared spectroscopy (FTIR), respectively. It was found that the modified BC has a higher specific surface area than the original BC. The maximum surface area of the modified BC was 118.58 m{sup 2}/g. The FTIR spectrum of modified BC indicated that the hydroxyl and carboxyl groups on the BC surface played a significant role in the adsorption of formaldehyde by modified BC. The breakthrough, equilibrium time and adsorption capacity of modified BC were greater than the original BC. Moreover, the results showed that at initial concentrations of 20, 50, 100 and 200 mg/L, the equilibrium times for BC and modified BC were 85, 75, 65 and 45 min and 95, 85, 70 and 50 min, respectively. It seems that the formaldehyde adsorption capacity of modified BC depends on both physical and chemical properties. These results showed that modified BC can be used as an efficient adsorbent for formaldehyde removal.

  2. Surface deposition of radon decay products with and without enhanced air motion

    International Nuclear Information System (INIS)

    Rudnick, S.N.; Maher, E.F.; Hinds, W.C.; First, M.W.

    1983-01-01

    The effectiveness of fan-induced air motion in reducing airborne activity of short-lived radon decay products was evaluated in a 78-m 3 chamber. Observed reductions were as high as 50% for RaA ( 218 Po), 79% for RaB ( 214 Pb), and 86% for RaC ( 214 Bi). Activity Measurements of these nuclides on chamber and fan surfaces, along with airborne activity, were used to calculate material balances. Greater than about 90% of deposited activity was found on chamber surfaces, although areal activity density was higher on fan surfaces. Deposition velocity and diffusional boundary thickness were also determined. When no fans were used, boundary layer thickness was estimated to be 25 times the recoil distance of a RaB atom and, with fans, about 4 times the recoil distance, suggesting that recoiling of RaB atoms probably do not play a significant role in the relationship between surface and airborne activity. The results of this study have relevance for all habitable spaces having excessive radon concentration

  3. Nanofluidic transport over a curved surface with viscous dissipation and convective mass flux

    Energy Technology Data Exchange (ETDEWEB)

    Mehmood, Zaffar; Iqbal, Z.; Azhar, Ehtsham; Maraj, E.N. [HITEC Univ., Taxila (Pakistan). Dept. of Mathematics

    2017-06-01

    This article is a numerical investigation of boundary layer flow of nanofluid over a bended stretching surface. The study is carried out by considering convective mass flux condition. Contribution of viscous dissipation is taken into the account along with thermal radiation. Suitable similarity transformations are employed to simplify the system of nonlinear partial differential equations into a system of nonlinear ordinary differential equations. Computational results are extracted by means of a shooting method embedded with a Runge-Kutta Fehlberg technique. Key findings include that velocity is a decreasing function of curvature parameter K. Moreover, Nusselt number decreases with increase in curvature of the stretching surface while skin friction and Sherwood number enhance with increase in K.

  4. Effect of humidity and particle hygroscopicity on the mass loading capacity of high efficiency particulate air (HEPA) filters

    International Nuclear Information System (INIS)

    Gupta, A.; Biswas, P.; Monson, P.R.; Novick, V.J.

    1993-01-01

    The effect of humidity, particle hygroscopicity, and size on the mass loading capacity of glass fiber high efficiency particulate air filters was studied. Above the deliquescent point, the pressure drop across the filter increased nonlinearly with areal loading density (mass collected/filtration area) of a NaCl aerosol, thus significantly reducing the mass loading capacity of the filter compared to dry hygroscopic or nonhygroscopic particle mass loadings. The specific cake resistance K 2 was computed for different test conditions and used as a measure of the mass loading capacity. K 2 was found to decrease with increasing humidity for nonhygroscopic aluminum oxide particles and for hygroscopic NaCl particles (at humidities below the deliquescent point). It is postulated that an increase in humidity leads to the formation of a more open particulate cake which lowers the pressure drop for a given mass loading. A formula for predicting K 2 for lognormally distributed aerosols (parameters obtained from impactor data) was derived. The resistance factor, R, calculated using this formula was compared to the theoretical R calculated using the Rudnick-Happel expression. For the nonhygroscopic aluminum oxide, the agreement was good but for the hygroscopic sodium chloride, due to large variation in the cake porosity estimates, the agreement was poor. 17 refs., 6 figs., 3 tabs

  5. The surface activity of purified ocular mucin at the air-liquid interface and interactions with meibomian lipids.

    Science.gov (United States)

    Millar, Thomas J; Tragoulias, Sophia T; Anderton, Philip J; Ball, Malcolm S; Miano, Fausto; Dennis, Gary R; Mudgil, Poonam

    2006-01-01

    Ocular mucins are thought to contribute to the stability of the tear film by reducing surface tension. The purpose of this study was to compare the effect of different mucins and hyaluronic acid (HA) alone and mixed with meibomian lipids on the surface pressure at an air-liquid interface. A Langmuir trough and Wilhelmy balance were used to measure and compare the surface activity of bovine submaxillary gland mucin (BSM), purified BSM, purified bovine ocular mucin and HA, and mixtures of these with meibomian lipids, phosphatidylcholine, and phosphatidylglycerol. Their appearance at the surface of an air-buffer interface was examined using epifluorescence microscopy. Purified ocular mucin had no surface activity even at concentrations that were 100 times more than normally occur in tears. By contrast, commercial BSM caused changes to surface pressure that were concentration dependent. The surface pressure-area profiles showed surface activity with maximum surface pressures of 12.3-22.5 mN/m depending on the concentration. Purified BSM showed no surface activity at low concentrations, whereas higher concentrations reached a maximum surface pressure of 25 mN/m. HA showed no surface activity, at low or high concentrations. Epifluorescence showed that the mucins were located at the air-buffer interface and changed the appearance of lipid films. Purified bovine ocular mucin and HA have no surface activity. However, despite having no surface activity in their own right, ocular mucins are likely to be present at the surface of the tear film, where they cause an increase in surface pressure by causing a compression of the lipids (a reorganization of the lipids) and alter the viscoelastic properties at the surface.

  6. A Comparison of the Red Green Blue (RGB) Air Mass Imagery and Hyperspectral Infrared Retrieved Profiles and NOAA G-IV Dropsondes

    Science.gov (United States)

    Berndt, Emily; Folmer, Michael; Dunion, Jason

    2014-01-01

    RGB air mass imagery is derived from multiple channels or paired channel differences. The combination of channels and channel differences means the resulting imagery does not represent a quantity or physical parameter such as brightness temperature in conventional single channel imagery. Without a specific quantity to reference, forecasters are often confused as to what RGB products represent. Hyperspectral infrared retrieved profiles and NOAA G-IV dropsondes provide insight about the vertical structure of the air mass represented on the RGB air mass imagery and are a first step to validating the imagery.

  7. SURFACE BRIGHTNESS PROFILES OF DWARF GALAXIES. II. COLOR TRENDS AND MASS PROFILES

    Energy Technology Data Exchange (ETDEWEB)

    Herrmann, Kimberly A. [Penn State Mont Alto, 1 Campus Drive, Mont Alto, PA 17237 (United States); Hunter, Deidre A. [Lowell Observatory, 1400 West Mars Hill Road, Flagstaff, AZ 86001 (United States); Elmegreen, Bruce G., E-mail: kah259@psu.edu, E-mail: dah@lowell.edu, E-mail: bge@us.ibm.com [IBM T. J. Watson Research Center, 1101 Kitchawan Road, Yorktown Heights, NY 10598 (United States)

    2016-06-01

    In this second paper of a series, we explore the B  −  V , U  −  B , and FUV−NUV radial color trends from a multi-wavelength sample of 141 dwarf disk galaxies. Like spirals, dwarf galaxies have three types of radial surface brightness profiles: (I) single exponential throughout the observed extent (the minority), (II) down-bending (the majority), and (III) up-bending. We find that the colors of (1) Type I dwarfs generally become redder with increasing radius, unlike spirals which have a blueing trend that flattens beyond ∼1.5 disk scale lengths, (2) Type II dwarfs come in six different “flavors,” one of which mimics the “U” shape of spirals, and (3) Type III dwarfs have a stretched “S” shape where the central colors are flattish, become steeply redder toward the surface brightness break, then remain roughly constant beyond, which is similar to spiral Type III color profiles, but without the central outward bluing. Faint (−9 >  M{sub B}  > −14) Type II dwarfs tend to have continuously red or “U” shaped colors and steeper color slopes than bright (−14 >  M{sub B}  > −19) Type II dwarfs, which additionally have colors that become bluer or remain constant with increasing radius. Sm dwarfs and BCDs tend to have at least some blue and red radial color trend, respectively. Additionally, we determine stellar surface mass density (Σ) profiles and use them to show that the break in Σ generally remains in Type II dwarfs (unlike Type II spirals) but generally disappears in Type III dwarfs (unlike Type III spirals). Moreover, the break in Σ is strong, intermediate, and weak in faint dwarfs, bright dwarfs, and spirals, respectively, indicating that Σ may straighten with increasing galaxy mass. Finally, the average stellar surface mass density at the surface brightness break is roughly 1−2  M {sub ⊙} pc{sup −2} for Type II dwarfs but higher at 5.9  M {sub ⊙} pc{sup −2} or 27  M {sub ⊙} pc{sup −2} for

  8. Atmospheric summer teleconnections and Greenland Ice Sheet surface mass variations: insights from MERRA-2

    International Nuclear Information System (INIS)

    Lim, Young-Kwon; Schubert, Siegfried D; Molod, Andrea M; Cullather, Richard I; Zhao, Bin; Nowicki, Sophie M J; Lee, Jae N; Velicogna, Isabella

    2016-01-01

    The relationship between leading atmospheric teleconnection patterns and Greenland Ice Sheet (GrIS) temperature, precipitation, and surface mass balance (SMB) are investigated for the last 36 summers (1979–2014) based on Modern-Era Retrospective analysis for Research and Applications version 2 reanalyses. The results indicate that the negative phase of both the North Atlantic Oscillation (NAO) and Arctic Oscillation, associated with warm and dry conditions for the GrIS, lead to SMB decreases within 0–1 months. Furthermore, the positive phase of the East Atlantic (EA) pattern often lags the negative NAO, reflecting a dynamical linkage between these modes that acts to further enhance the warm and dry conditions over the GrIS, leading to a favorable environment for enhanced surface mass loss. The development of a strong negative NAO in combination with a strong positive EA in recent years leads to significantly larger GrIS warming compared to when the negative NAO occurs in combination with a negative or weak positive EA (0.69 K versus 0.13 K anomaly). During 2009 and 2011, weakened (as compared to conditions during the severe surface melt cases of 2010 and 2012) local high pressure blocking produced colder northerly flow over the GrIS inhibiting warming despite the occurrence of a strong negative NAO, reflecting an important role for the EA during those years. In particular, the EA acts with the NAO to enhance warming in 2010 and 2012, and weaken high pressure blocking in 2009 and 2011. In general, high pressure blocking primarily impacts the western areas of the GrIS via advective temperature increases, while changes in net surface radiative fluxes account for both western and eastern GrIS temperature changes. (letter)

  9. Influence of air-powder polishing on bond strength and surface-free energy of universal adhesive systems.

    Science.gov (United States)

    Tamura, Yukie; Takamizawa, Toshiki; Shimamura, Yutaka; Akiba, Shunsuke; Yabuki, Chiaki; Imai, Arisa; Tsujimoto, Akimasa; Kurokawa, Hiroyasu; Miyazaki, Masashi

    2017-11-29

    The influences of air-powder polishing with glycine or sodium bicarbonate powders on shear bond strengths (SBS) and surface-free energies of universal adhesives were examined. Scotchbond Universal Adhesive (SU, 3M ESPE), G-Premio Bond (GP, GC), Adhese Universal (AU, Ivoclar Vivadent), and All-Bond Universal (AB, Bisco) were used in this study. Bovine dentin surfaces were air polished with glycine or sodium bicarbonate powders prior to the bonding procedure, and resin pastes were bonded to the dentin surface using universal adhesives. SBSs were determined after 24-h storage in distilled water at 37°C. Surface-free energy was then determined by measuring contact angles using three test liquids on dentin surfaces. Significantly lower SBSs were observed for dentin that was air-powder polished and surface-free energies were concomitantly lowered. This study indicated that air-powder polishing influences SBSs and surface-free energies. However, glycine powder produced smaller changes in these surface parameters than sodium bicarbonate.

  10. Total reference air kerma can accurately predict isodose surface volumes in cervix cancer brachytherapy. A multicenter study

    DEFF Research Database (Denmark)

    Nkiwane, Karen S; Andersen, Else; Champoudry, Jerome

    2017-01-01

    PURPOSE: To demonstrate that V60 Gy, V75 Gy, and V85 Gy isodose surface volumes can be accurately estimated from total reference air kerma (TRAK) in cervix cancer MRI-guided brachytherapy (BT). METHODS AND MATERIALS: 60 Gy, 75 Gy, and 85 Gy isodose surface volumes levels were obtained from treatm...

  11. Decadal-scale teleconnection between South Atlantic SST and southeast Australia surface air temperature in austral summer

    Science.gov (United States)

    Xue, Jiaqing; Li, Jianping; Sun, Cheng; Zhao, Sen; Mao, Jiangyu; Dong, Di; Li, Yanjie; Feng, Juan

    2018-04-01

    Austral summer (December-February) surface air temperature over southeast Australia (SEA) is found to be remotely influenced by sea surface temperature (SST) in the South Atlantic at decadal time scales. In austral summer, warm SST anomalies in the southwest South Atlantic induce concurrent above-normal surface air temperature over SEA. This decadal-scale teleconnection occurs through the eastward propagating South Atlantic-Australia (SAA) wave train triggered by SST anomalies in the southwest South Atlantic. The excitation of the SAA wave train is verified by forcing experiments based on both linear barotropic and baroclinic models, propagation pathway and spatial scale of the observed SAA wave train are further explained by the Rossby wave ray tracing analysis in non-uniform basic flow. The SAA wave train forced by southwest South Atlantic warming is characterized by an anomalous anticyclone off the eastern coast of the Australia. Temperature diagnostic analyses based on the thermodynamic equation suggest anomalous northerly flows on western flank of this anticyclone can induce low-level warm advection anomaly over SEA, which thus lead to the warming of surface air temperature there. Finally, SST-forced atmospheric general circulation model ensemble experiments also demonstrate that SST forcing in the South Atlantic is associated with the SAA teleconnection wave train in austral summer, this wave train then modulate surface air temperature over SEA on decadal timescales. Hence, observations combined with numerical simulations consistently demonstrate the decadal-scale teleconnection between South Atlantic SST and summertime surface air temperature over SEA.

  12. Response of surface air temperature to small-scale land clearing across latitudes

    International Nuclear Information System (INIS)

    Zhang, Mi; Wang, Wei; Lee, Xuhui; Yu, Guirui; Wang, Huimin; Han, Shijie; Yan, Junhua; Zhang, Yiping; Li, Yide; Ohta, Takeshi; Hirano, Takashi; Kim, Joon; Yoshifuji, Natsuko

    2014-01-01

    Climate models simulating continental scale deforestation suggest a warming effect of land clearing on the surface air temperature in the tropical zone and a cooling effect in the boreal zone due to different control of biogeochemical and biophysical processes. Ongoing land-use/cover changes mostly occur at local scales (hectares), and it is not clear whether the local-scale deforestation will generate temperature patterns consistent with the climate model results. Here we paired 40 and 12 flux sites with nearby weather stations in North and South America and in Eastern Asia, respectively, and quantified the temperature difference between these paired sites. Our goal was to investigate the response of the surface air temperature to local-scale (hectares) land clearing across latitudes using the surface weather stations as proxies for localized land clearing. The results show that north of 10°N, the annual mean temperature difference (open land minus forest) decreases with increasing latitude, but the temperature difference shrinks with latitude at a faster rate in the Americas [−0.079 (±0.010) °C per degree] than in Asia [−0.046 (±0.011) °C per degree]. Regression of the combined data suggests a transitional latitude of about 35.5°N that demarks deforestation warming to the south and cooling to the north. The warming in latitudes south of 35°N is associated with increase in the daily maximum temperature, with little change in the daily minimum temperature while the reverse is true in the boreal latitudes. (paper)

  13. Re-assessment of recent (2008–2013 surface mass balance over Dome Argus, Antarctica

    Directory of Open Access Journals (Sweden)

    Minghu Ding

    2016-04-01

    Full Text Available At Dome Argus, East Antarctica, the surface mass balance (SMB from 2008 to 2013 was evaluated using 49 stakes installed across a 30×30 km area. Spatial analysis showed that at least 12 and 20 stakes are needed to obtain reliable estimates of SMB at local scales (a few hundred square metres and regional scales (tens of square kilometres, respectively. The estimated annual mean SMB was 22.9±5.9 kg m−2 yr−1, including a net loss by sublimation of −2.22±0.02 kg m−2 yr−1 and a mass gain by deposition of 1.37±0.01 kg m−2 yr−1. Therefore, ca. 14.3% of precipitation was modified after deposition, which should be considered when interpreting snow or ice core records produced by future drilling projects. The surface snow density and SMB in the western portion of Dome Argus are higher than in other areas, and these differences are likely related to the katabatic wind, which is strengthened by topography in this sector. A new digital elevation model (DEM of Dome Argus was generated, confirming that both peaks of the dome can be considered as the summit of the East Antarctic Ice Sheet. Findings from this study should be valuable for validating SMB estimates obtained from regional climate models and DEMs established using remote-sensing data.

  14. Mercury fluxes from air/surface interfaces in paddy field and dry land

    Energy Technology Data Exchange (ETDEWEB)

    Zhu Jinshan [Key Laboratory of Eco-Environments in Three Gorges Reservoir Region (Ministry of Education), College of Resources and Environment, Southwest University, No. 216, Tiansheng Street, Beibei, Chongqing 400715 (China); Wang Dingyong, E-mail: dywang@swu.edu.cn [Key Laboratory of Eco-Environments in Three Gorges Reservoir Region (Ministry of Education), College of Resources and Environment, Southwest University, No. 216, Tiansheng Street, Beibei, Chongqing 400715 (China)] [Chongqing Key Laboratory of Agricultural Resources and Environment, Chongqing 400716 (China); Liu Xiao; Zhang Yutong [Key Laboratory of Eco-Environments in Three Gorges Reservoir Region (Ministry of Education), College of Resources and Environment, Southwest University, No. 216, Tiansheng Street, Beibei, Chongqing 400715 (China)

    2011-02-15

    Research highlights: {yields} It was found that agricultural fields are important local atmospheric Hg sources in the region. {yields} The Hg emissions from dry cornfield were higher than those from the flooded rice paddy, higher mercury emissions in the warm season than the cold season, and during daytime than at night. {yields} Mercury evasion is strongly related to solar radiation which is important in the emission of Hg at both sites. - Abstract: In order to provide insight into the characteristics of Hg exchange in soil/water-air surface from cropland (including paddy field and dry land), Hg fluxes were measured in Chengjiang. Mercury fluxes were measured using the dynamic flux chamber method, coupled with a Lumex (registered) multifunctional Hg analyzer RA-915{sup +} (Lumex Ltd., Russia). The Hg fluxes from paddy field and dry land were alternatively measured every 30 min. Data were collected for 24-48 h once per month for 5 months. Mercury fluxes in both fields were synchronously measured under the same conditions to compare Hg emissions between paddy field and dry land over diurnal and seasonal periods and find out what factors affect Hg emission on each surface. These results indicated that air Hg concentrations at the monitoring site was double the value observed at the global background sites in Europe and North America. The Hg release fluxes were 46.5 {+-} 22.8 ng m{sup -2} h{sup -1} in the warm season, 15.5 {+-} 18.8 ng m{sup -2} h{sup -1} in the cold season for dry land, and 23.8 {+-} 15.6 ng m{sup -2} h{sup -1} in the warm season, 6.3 {+-} 11.9 ng m{sup -2} h{sup -1} in the cold season for paddy field. Solar radiation is important in the emission of Hg over both sites. Hg exchange at the soil/air and water/air interfaces showed temporal variations. The amount of Hg emission from dry land was higher than that from the paddy field, and the emission in daytime was higher than that at night. Moreover, Hg emissions from land covered by crops, was lower

  15. Upper limit of the muon-neutrino mass and charged-pion mass from the momentum analysis of a surface muon beam

    Energy Technology Data Exchange (ETDEWEB)

    Kettle, P R [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1996-11-01

    Using a surface muon beam and a magnetic spectrometer equipped with a position-sensitive detector, we have measured the muon momentum from pion decay at rest {pi}{sup +}{yields}{mu}{sup +}{nu}{sub {mu}}, to be p{sub {mu}{sup +}}=(29.79200{+-}0.00011)MeV/c. This value together with the muon mass and the favoured pion mass leads to an upper limit of 0.17 MeV (90%CL) for the muon-neutrino mass. (author) 4 figs., 5 refs.

  16. Strong orientation dependence of surface mass density profiles of dark haloes at large scales

    Science.gov (United States)

    Osato, Ken; Nishimichi, Takahiro; Oguri, Masamune; Takada, Masahiro; Okumura, Teppei

    2018-06-01

    We study the dependence of surface mass density profiles, which can be directly measured by weak gravitational lensing, on the orientation of haloes with respect to the line-of-sight direction, using a suite of N-body simulations. We find that, when major axes of haloes are aligned with the line-of-sight direction, surface mass density profiles have higher amplitudes than those averaged over all halo orientations, over all scales from 0.1 to 100 Mpc h-1 we studied. While the orientation dependence at small scales is ascribed to the halo triaxiality, our results indicate even stronger orientation dependence in the so-called two-halo regime, up to 100 Mpc h-1. The orientation dependence for the two-halo term is well approximated by a multiplicative shift of the amplitude and therefore a shift in the halo bias parameter value. The halo bias from the two-halo term can be overestimated or underestimated by up to {˜ } 30 per cent depending on the viewing angle, which translates into the bias in estimated halo masses by up to a factor of 2 from halo bias measurements. The orientation dependence at large scales originates from the anisotropic halo-matter correlation function, which has an elliptical shape with the axis ratio of ˜0.55 up to 100 Mpc h-1. We discuss potential impacts of halo orientation bias on other observables such as optically selected cluster samples and a clustering analysis of large-scale structure tracers such as quasars.

  17. Probing protein surface with a solvent mimetic carbene coupled to detection by mass spectrometry.

    Science.gov (United States)

    Gómez, Gabriela E; Mundo, Mariana R; Craig, Patricio O; Delfino, José M

    2012-01-01

    Much knowledge into protein folding, ligand binding, and complex formation can be derived from the examination of the nature and size of the accessible surface area (SASA) of the polypeptide chain, a key parameter in protein science not directly measurable in an experimental fashion. To this end, an ideal chemical approach should aim at exerting solvent mimicry and achieving minimal selectivity to probe the protein surface regardless of its chemical nature. The choice of the photoreagent diazirine to fulfill these goals arises from its size comparable to water and from being a convenient source of the extremely reactive methylene carbene (:CH(2)). The ensuing methylation depends primarily on the solvent accessibility of the polypeptide chain, turning it into a valuable signal to address experimentally the measurement of SASA in proteins. The superb sensitivity and high resolution of modern mass spectrometry techniques allows us to derive a quantitative signal proportional to the extent of modification (EM) of the sample. Thus, diazirine labeling coupled to electrospray mass spectrometry (ESI-MS) detection can shed light on conformational features of the native as well as non-native states, not easily addressable by other methods. Enzymatic fragmentation of the polypeptide chain at the level of small peptides allows us to locate the covalent tag along the amino acid sequence, therefore enabling the construction of a map of solvent accessibility. Moreover, by subsequent MS/MS analysis of peptides, we demonstrate here the feasibility of attaining amino acid resolution in defining the target sites. © American Society for Mass Spectrometry, 2011

  18. Controlled Dissolution of Surface Layers for Elemental Analysis by Inductively Coupled Plasma-Mass Spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Lorge, Susan Elizabeth [Iowa State Univ., Ames, IA (United States)

    2007-01-01

    Determining the composition of thin layers is increasingly important for a variety of industrial materials such as adhesives, coatings and microelectronics. Secondary ion mass spectrometry (SIMS), Auger electron spectroscopy (AES), X-ray photoelectron spectroscopy (XPS), glow discharge optical emission spectroscopy (GDOES), glow discharge mass spectrometry (GDMS), and laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) are some of the techniques that are currently employed for the direct analysis of the sample surface. Although these techniques do not suffer from the contamination problems that often plague sample dissolution studies, they do require matrix matched standards for quantification. Often, these standards are not readily available. Despite the costs of clean hoods, Teflon pipette tips and bottles, and pure acids, partial sample dissolution is the primary method used in the semiconductor industry to quantify surface impurities. Specifically, vapor phase decomposition (VPD) coupled to ICP-MS or total reflection x-ray fluorescence (TXRF) provides elemental information from the top most surface layers at detection sensitivities in the 107-1010atoms/cm2 range. The ability to quantify with standard solutions is a main advantage of these techniques. Li and Houk applied a VPD-like technique to steel. The signal ratio of trace element to matrix element was used for quantification. Although controlled dissolution concentrations determined for some of the dissolved elements agreed with the certified values, concentrations determined for refractory elements (Ti, Nb and Ta) were too low. LA-ICP-MS and scanning electron microscopy (SEM) measurements indicated that carbide grains distributed throughout the matrix were high in these refractory elements. These elements dissolved at a slower rate than the matrix element, Fe. If the analyte element is not removed at a rate similar to the matrix element a true

  19. Extending and refining the mass surface around $^{208}$Pb by high-precision Penning-trap mass spectrometry with ISOLTRAP

    CERN Multimedia

    Herfurth, F; Stora, T; Blaum, K; Beck, D; Kowalska, M; Schwarz, S; Stanja, J; Herlert, A J; Yamaguchi, T

    We propose high-precision mass spectrometry of nuclides around the doubly magic $^{208}$Pb. On the neutron-rich side, we aim to extend the knowledge of Fr, At, Hg, and Au masses to study the robustness of the N = 126 shell closure and to provide mass data necessary for modeling the rapid-neutron-capture process. On the proton-rich side, we aim at high-resolution mass spectrometry of selected Au, At, and Fr isotopes to verify the predicted existence of very low-lying isomeric states. The proposal will make use of newly-available laser-ionization schemes for Au and At. Finally, the recently implemented multi-reflection time-of-flight mass separator for auxiliary isobaric purification now allows measurements which were not feasible before.

  20. Variability of aerosol, gaseous pollutants and meteorological characteristics associated with changes in air mass origin at the SW Atlantic coast of Iberia

    Science.gov (United States)

    Diesch, J.-M.; Drewnick, F.; Zorn, S. R.; von der Weiden-Reinmüller, S.-L.; Martinez, M.; Borrmann, S.

    2012-04-01

    Measurements of the ambient aerosol were performed at the Southern coast of Spain, within the framework of the DOMINO (Diel Oxidant Mechanisms In relation to Nitrogen Oxides) project. The field campaign took place from 20 November until 9 December 2008 at the atmospheric research station "El Arenosillo" (37°5'47.76" N, 6°44'6.94" W). As the monitoring station is located at the interface between a natural park, industrial cities (Huelva, Seville) and the Atlantic Ocean, a variety of physical and chemical parameters of aerosols and gas phase could be characterized in dependency on the origin of air masses. Backwards trajectories were examined and compared with local meteorology to classify characteristic air mass types for several source regions. Aerosol number and mass as well as polycyclic aromatic hydrocarbons and black carbon concentrations were measured in PM1 and size distributions were registered covering a size range from 7 nm up to 32 μm. The chemical composition of the non-refractory submicron aerosol (NR-PM1) was measured by means of an Aerosol Mass Spectrometer (Aerodyne HR-ToF-AMS). Gas phase analyzers monitored various trace gases (O3, SO2, NO, NO2, CO2) and a weather station provided meteorological parameters. Lowest average submicron particle mass and number concentrations were found in air masses arriving from the Atlantic Ocean with values around 2 μg m-3 and 1000 cm-3. These mass concentrations were about two to four times lower than the values recorded in air masses of continental and urban origins. For some species PM1-fractions in marine air were significantly larger than in air masses originating from Huelva, a closely located city with extensive industrial activities. The largest fraction of sulfate (54%) was detected in marine air masses and was to a high degree not neutralized. In addition, small concentrations of methanesulfonic acid (MSA), a product of biogenic dimethyl sulfate (DMS) emissions, could be identified in the particle phase

  1. Integrated CLOS and PN Guidance for Increased Effectiveness of Surface to Air Missiles

    Directory of Open Access Journals (Sweden)

    Binte Fatima Tuz ZAHRA

    2017-06-01

    Full Text Available In this paper, a novel approach has been presented to integrate command to line-of-sight (CLOS guidance and proportional navigation (PN guidance in order to reduce miss distance and to increase the effectiveness of surface to air missiles. Initially a comparison of command to line-of-sight guidance and proportional navigation has been presented. Miss distance, variation of angle-of-attack, normal and lateral accelerations and error of missile flight path from direct line-of-sight have been used as noteworthy criteria for comparison of the two guidance laws. Following this comparison a new approach has been proposed for determining the most suitable guidance gains in order to minimize miss distance and improve accuracy of the missile in delivering the warhead, while using CLOS guidance. This proposed technique is based on constrained nonlinear minimization to optimize the guidance gains. CLOS guidance has a further limitation of significant increase in normal and lateral acceleration demands during the terminal phase of missile flight. Furthermore, at large elevation angles, the required angle-of-attack during the terminal phase increases beyond design specifications. Subsequently, a missile with optical sensors only and following just the CLOS guidance has less likelihood to hit high speed targets beyond 45º in elevation plane. A novel approach has thus been proposed to overcome such limitations of CLOS-only guidance for surface to air missiles. In this approach, an integrated guidance algorithm has been proposed whereby the initial guidance law during rocket motor burnout phase remains CLOS, whereas immediately after this phase, the guidance law is automatically switched to PN guidance. This integrated approach has not only resulted in slight increase in range of the missile but also has significantly improved its likelihood to hit targets beyond 30 degrees in elevation plane, thus successfully overcoming various limitations of CLOS

  2. Liquid phase mass production of air-stable black phosphorus/phospholipids nanocomposite with ultralow tunneling barrier

    Science.gov (United States)

    Zhang, Qiankun; Liu, Yinan; Lai, Jiawei; Qi, Shaomian; An, Chunhua; Lu, Yao; Duan, Xuexin; Pang, Wei; Zhang, Daihua; Sun, Dong; Chen, Jian-Hao; Liu, Jing

    2018-04-01

    Few-layer black phosphorus (FLBP), a recently discovered two-dimensional semiconductor, has attracted substantial attention in the scientific and technical communities due to its great potential in electronic and optoelectronic applications. However, reactivity of FLBP flakes with ambient species limits its direct applications. Among various methods to passivate FLBP in ambient environment, nanocomposites mixing FLBP flakes with stable matrix may be one of the most promising approaches for industry applications. Here, we report a simple one-step procedure to mass produce air-stable FLBP/phospholipids nanocomposite in liquid phase. The resultant nanocomposite is found to have ultralow tunneling barrier for charge carriers which can be described by an Efros-Shklovskii variable range hopping mechanism. Devices made from such mass-produced FLBP/phospholipids nanocomposite show highly stable electrical conductivity and opto-electrical response in ambient conditions, indicating its promising applications in both electronic and optoelectronic applications. This method could also be generalized to the mass production of nanocomposites consisting of other air-sensitive 2D materials, such as FeSe, NbSe2, WTe2, etc.

  3. Confinement of surface waves at the air-water interface to control aerosol size and dispersity

    Science.gov (United States)

    Nazarzadeh, Elijah; Wilson, Rab; King, Xi; Reboud, Julien; Tassieri, Manlio; Cooper, Jonathan M.

    2017-11-01

    The precise control over the size and dispersity of droplets, produced within aerosols, is of great interest across many manufacturing, food, cosmetic, and medical industries. Amongst these applications, the delivery of new classes of high value drugs to the lungs has recently attracted significant attention from pharmaceutical companies. This is commonly achieved through the mechanical excitation of surface waves at the air liquid interface of a parent liquid volume. Previous studies have established a correlation between the wavelength on the surface of liquid and the final aerosol size. In this work, we show that the droplet size distribution of aerosols can be controlled by constraining the liquid inside micron-sized cavities and coupling surface acoustic waves into different volumes of liquid inside micro-grids. In particular, we show that by reducing the characteristic physical confinement size (i.e., either the initial liquid volume or the cavities' diameters), higher harmonics of capillary waves are revealed with a consequent reduction of both aerosol mean size and dispersity. In doing so, we provide a new method for the generation and fine control of aerosols' sizes distribution.

  4. Recent Improvements in Retrieving Near-Surface Air Temperature and Humidity Using Microwave Remote Sensing

    Science.gov (United States)

    Roberts, J. Brent

    2010-01-01

    Detailed studies of the energy and water cycles require accurate estimation of the turbulent fluxes of moisture and heat across the atmosphere-ocean interface at regional to basin scale. Providing estimates of these latent and sensible heat fluxes over the global ocean necessitates the use of satellite or reanalysis-based estimates of near surface variables. Recent studies have shown that errors in the surface (10 meter)estimates of humidity and temperature are currently the largest sources of uncertainty in the production of turbulent fluxes from satellite observations. Therefore, emphasis has been placed on reducing the systematic errors in the retrieval of these parameters from microwave radiometers. This study discusses recent improvements in the retrieval of air temperature and humidity through improvements in the choice of algorithms (linear vs. nonlinear) and the choice of microwave sensors. Particular focus is placed on improvements using a neural network approach with a single sensor (Special Sensor Microwave/Imager) and the use of combined sensors from the NASA AQUA satellite platform. The latter algorithm utilizes the unique sampling available on AQUA from the Advanced Microwave Scanning Radiometer (AMSR-E) and the Advanced Microwave Sounding Unit (AMSU-A). Current estimates of uncertainty in the near-surface humidity and temperature from single and multi-sensor approaches are discussed and used to estimate errors in the turbulent fluxes.

  5. New and Emerging Technologies for Real-Time Air and Surface Beryllium Monitoring

    Energy Technology Data Exchange (ETDEWEB)

    Phifer, B.E. Jr.; Churnetski, E.L.; Cooke, L.E.; Reed, J.J.; Howell, M.L.; Smith, V.D.

    2001-09-01

    In this study, five emerging technologies were identified for real-time monitoring of airborne beryllium: Microwave-Induced Plasma Spectroscopy (MIPS), Aerosol Beam-Focused Laser-Induced Plasma Spectroscopy (ABFLIPS), Laser-Induced Breakdown Spectroscopy (LIBS), Surfaced-Enhanced Raman Scattering (SERS) Spectroscopy, and Micro-Calorimetric Spectroscopy (CalSpec). Desired features of real-time air beryllium monitoring instrumentation were developed from the Y-12 CBDPP. These features were used as guidelines for the identification of potential technologies as well as their unique demonstrated capability to provide real-time monitoring of similar materials. However, best available technologies were considered, regardless of their ability to comply with the desired features. None of the five technologies have the capability to measure the particle size of airborne beryllium. Although reducing the total concentration of airborne beryllium is important, current literature suggests that reducing or eliminating the concentration of respirable beryllium is critical for worker health protection. Eight emerging technologies were identified for surface monitoring of beryllium. CalSpec, MIPS, SERS, LIBS, Laser Ablation, Absorptive Stripping Voltametry (ASV), Modified Inductively Coupled Plasma (ICP) Spectroscopy, and Gamma BeAST. Desired features of real-time surface beryllium monitoring were developed from the Y-12 CBDPP. These features were used as guidelines for the identification of potential technologies. However, the best available technologies were considered regardless of their ability to comply with the desired features.

  6. Surface deposition of 222Rn decay products with and without enhanced air motion

    International Nuclear Information System (INIS)

    Rudnick, S.N.; Maher, E.F.

    1986-01-01

    The effectiveness of fan-induced air motion in reducing airborne activities of short-lived 222 Rn decay products was evaluated in a 78.5-m3 chamber. Observed reductions were as high as 50% for 218Po (RaA), 79% for 214 Pb (RaB), and 86% for 214 Bi (RaC). Activity measurements of these nuclides on chamber and fan surfaces, along with airborne activities, were used to calculate material balances. Greater than about 90% of deposited activity was found on chamber surfaces, although areal activity densities were higher on fan surfaces. Deposition velocities for decay products not attached to particles were 2.3 mm s-1 when no fans were in operation and 9.2 to 13 mm s-1 when fans were used. Mean boundary layer thicknesses for unattached decay products were estimated to be about four times the recoil distance of a 214 Pb atom when no fans were used and about equal to the recoil distance when fans were used

  7. Measurement of volatile plant compounds in field ambient air by thermal desorption-gas chromatography-mass spectrometry.

    Science.gov (United States)

    Cai, Xiao-Ming; Xu, Xiu-Xiu; Bian, Lei; Luo, Zong-Xiu; Chen, Zong-Mao

    2015-12-01

    Determination of volatile plant compounds in field ambient air is important to understand chemical communication between plants and insects and will aid the development of semiochemicals from plants for pest control. In this study, a thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) method was developed to measure ultra-trace levels of volatile plant compounds in field ambient air. The desorption parameters of TD, including sorbent tube material, tube desorption temperature, desorption time, and cold trap temperature, were selected and optimized. In GC-MS analysis, the selected ion monitoring mode was used for enhanced sensitivity and selectivity. This method was sufficiently sensitive to detect part-per-trillion levels of volatile plant compounds in field ambient air. Laboratory and field evaluation revealed that the method presented high precision and accuracy. Field studies indicated that the background odor of tea plantations contained some common volatile plant compounds, such as (Z)-3-hexenol, methyl salicylate, and (E)-ocimene, at concentrations ranging from 1 to 3400 ng m(-3). In addition, the background odor in summer was more abundant in quality and quantity than in autumn. Relative to previous methods, the TD-GC-MS method is more sensitive, permitting accurate qualitative and quantitative measurements of volatile plant compounds in field ambient air.

  8. Assessing modeled Greenland surface mass balance in the GISS Model E2 and its sensitivity to surface albedo

    Science.gov (United States)

    Alexander, Patrick; LeGrande, Allegra N.; Koenig, Lora S.; Tedesco, Marco; Moustafa, Samiah E.; Ivanoff, Alvaro; Fischer, Robert P.; Fettweis, Xavier

    2016-04-01

    The surface mass balance (SMB) of the Greenland Ice Sheet (GrIS) plays an important role in global sea level change. Regional Climate Models (RCMs) such as the Modèle Atmosphérique Régionale (MAR) have been employed at high spatial resolution with relatively complex physics to simulate ice sheet SMB. Global climate models (GCMs) incorporate less sophisticated physical schemes and provide outputs at a lower spatial resolution, but have the advantage of modeling the interaction between different components of the earth's oceans, climate, and land surface at a global scale. Improving the ability of GCMs to represent ice sheet SMB is important for making predictions of future changes in global sea level. With the ultimate goal of improving SMB simulated by the Goddard Institute for Space Studies (GISS) Model E2 GCM, we compare simulated GrIS SMB against the outputs of the MAR model and radar-derived estimates of snow accumulation. In order to reproduce present-day climate variability in the Model E2 simulation, winds are constrained to match the reanalysis datasets used to force MAR at the lateral boundaries. We conduct a preliminary assessment of the sensitivity of the simulated Model E2 SMB to surface albedo, a parameter that is known to strongly influence SMB. Model E2 albedo is set to a fixed value of 0.8 over the entire ice sheet in the initial configuration of the model (control case). We adjust this fixed value in an ensemble of simulations over a range of 0.4 to 0.8 (roughly the range of observed summer GrIS albedo values) to examine the sensitivity of ice-sheet-wide SMB to albedo. We prescribe albedo from the Moderate Resolution Imaging Spectroradiometer (MODIS) MCD43A3 v6 to examine the impact of a more realistic spatial and temporal variations in albedo. An age-dependent snow albedo parameterization is applied, and its impact on SMB relative to observations and the RCM is assessed.

  9. Experimental characterization of mass, work and heat flows in an air cooled, single cylinder engine

    International Nuclear Information System (INIS)

    Perez-Blanco, H.

    2004-01-01

    Small air cooled engines, although large in numbers, receive scant attention in the literature. Experimental data for a four stroke, air cooled, single cylinder engine are presented in this report. Air to fuel ratios, indicated and output power, exhaust composition and heat loss are determined to result in suitable thermal and mechanical efficiencies. The data obtained are discussed with the perspective obtained from other literature references. Exhaust composition figures appear reasonable, but the measurement of the transient exhaust flows is still a concern. Based on the measurements, a graph illustrating the different energy transformations in the engine is produced. Undergraduate students in the curriculum routinely use the engine and the present work allows one to conclude that the measurement approach produces reasonable results. These results could be used by engine modelers and others interested in this wide field of technology

  10. Modeling 3D conjugate heat and mass transfer for turbulent air drying of Chilean papaya in a direct contact dryer

    Science.gov (United States)

    Lemus-Mondaca, Roberto A.; Vega-Gálvez, Antonio; Zambra, Carlos E.; Moraga, Nelson O.

    2017-01-01

    A 3D model considering heat and mass transfer for food dehydration inside a direct contact dryer is studied. The k- ɛ model is used to describe turbulent air flow. The samples thermophysical properties as density, specific heat, and thermal conductivity are assumed to vary non-linearly with temperature. FVM, SIMPLE algorithm based on a FORTRAN code are used. Results unsteady velocity, temperature, moisture, kinetic energy and dissipation rate for the air flow are presented, whilst temperature and moisture values for the food also are presented. The validation procedure includes a comparison with experimental and numerical temperature and moisture content results obtained from experimental data, reaching a deviation 7-10 %. In addition, this turbulent k- ɛ model provided a better understanding of the transport phenomenon inside the dryer and sample.

  11. A passive air sampler for characterizing the vertical concentration profile of gaseous phase polycyclic aromatic hydrocarbons in near soil surface air.

    Science.gov (United States)

    Zhang, Yuzhong; Deng, Shuxing; Liu, Yanan; Shen, Guofeng; Li, Xiqing; Cao, Jun; Wang, Xilong; Reid, Brian; Tao, Shu

    2011-03-01

    Air-soil exchange is an important process governing the fate of polycyclic aromatic hydrocarbons (PAHs). A novel passive air sampler was designed and tested for measuring the vertical concentration profile of 4 low molecular weight PAHs in gaseous phase (PAH(LMW4)) in near soil surface air. Air at various heights from 5 to 520 mm above the ground was sampled by polyurethane foam disks held in down-faced cartridges. The samplers were tested at three sites: A: an extremely contaminated site, B: a site near A, and C: a background site on a university campus. Vertical concentration gradients were revealed for PAH(LMW4) within a thin layer close to soil surface at the three sites. PAH concentrations either decreased (Site A) or increased (Sites B and C) with height, suggesting either deposition to or evaporation from soils. The sampler is a useful tool for investigating air-soil exchange of gaseous phase semi-volatile organic chemicals. Copyright © 2010 Elsevier Ltd. All rights reserved.

  12. Synchronous NDVI and Surface Air Temperature Trends in Newfoundland: 1982 to 2003

    Science.gov (United States)

    Neigh, C. S. R.; Tucker, C. J.; Townshend, J. R. G.

    2007-01-01

    The northern regions of the earth are currently experiencing rapid change in temperature and precipitation. This region contains -40% of carbon stored in the world's soil which has accumulated from the last ice age (over 10,000 years ago). The carbon has remained to this point due to reduced decomposition from the short growing seasons and subfreezing temperatures. The influence of climate upon plant growth can have significant consequences to the carbon cycle balance in this region and could potentially alter and release this long term store of carbon to the atmosphere, resulting in a negative feedback enhancing climate warming. These changes have the potential to alter ecosystems processes, which impact human well being. This paper investigated a global satellite record of increases in vegetation growth from 1982 to 2003 developed at GSFC. It was found that, Newfoundland's vegetation growth during the 1990s exceeded global measurements. A number of potential causes were investigated to understand the mechanistic environmental drivers that could alter the productivity of this ecosystem. Possible drivers of change included: human influence of land use change on vegetation cover; changes in precipitation; temperature; cloud cover; snow cover; and growing season length. We found that humans had a minimal influence on vegetation growth in Newfoundland. Less than 6% of the island was logged during the investigation. We found a strong correlation of vegetation growth to a lengthening of the growing season of -9 and -17 days from 1982-1990 and 1991-1999. A distinct drop in plant growth and air temperature was found in 1990 to 1991 from the volcanic eruption of Mt. Pinatubo that reduced global surface air temperatures. These results document the influences of air temperature upon northern forest plant growth and the cooling effects of major volcanic eruptions in this ecological system.

  13. Satellite-derived, melt-season surface temperature of the Greenland Ice Sheet (2000-2005) and its relationship to mass balance

    Science.gov (United States)

    Hall, D.K.; Williams, R.S.; Casey, K.A.; DiGirolamo, N.E.; Wan, Z.

    2006-01-01

    Mean, clear-sky surface temperature of the Greenland Ice Sheet was measured for each melt season from 2000 to 2005 using Moderate-Resolution Imaging Spectroradiometer (MODIS)–derived land-surface temperature (LST) data-product maps. During the period of most-active melt, the mean, clear-sky surface temperature of the ice sheet was highest in 2002 (−8.29 ± 5.29°C) and 2005 (−8.29 ± 5.43°C), compared to a 6-year mean of −9.04 ± 5.59°C, in agreement with recent work by other investigators showing unusually extensive melt in 2002 and 2005. Surface-temperature variability shows a correspondence with the dry-snow facies of the ice sheet; a reduction in area of the dry-snow facies would indicate a more-negative mass balance. Surface-temperature variability generally increased during the study period and is most pronounced in the 2005 melt season; this is consistent with surface instability caused by air-temperature fluctuations.

  14. Seasonal fluctuations of the uranium and thorium contents in aerosols in surface air

    International Nuclear Information System (INIS)

    Kolb, W.

    1985-01-01

    An estimate in the UNSCEAR report the only source considered for the uranium and thorium contents is ground dust. A significant portion of the aerosols, however, comes from chimneys. Aerosol samples taken monthly in Brunswick, Berlin, Skibotn (Northern Norway) were, therefore, scrutinized alpha-spectrometrically for U-238, U-234, Th-230, and Th-232. The activity concentration in surface air of Northern Norway is only about 30 nBq/cm 3 . In Brunswick and Berlin, the concentration was higher by a factor of one to two due to the higher specific activity of the mineral aerosols. Significant differences of the isotope ratios allow conclusions as to the origin of the aerosols. The activity concentrations measured and their seasonal fluctuations must be taken into account in the evaluation of environment monitoring of nuclear fuel factories. (orig./HP) [de

  15. Statistical analysis of global surface air temperature and sea level using cointegration methods

    DEFF Research Database (Denmark)

    Schmith, Torben; Johansen, Søren; Thejll, Peter

    Global sea levels are rising which is widely understood as a consequence of thermal expansion and melting of glaciers and land-based ice caps. Due to physically-based models being unable to simulate observed sea level trends, semi-empirical models have been applied as an alternative for projecting...... of future sea levels. There is in this, however, potential pitfalls due to the trending nature of the time series. We apply a statistical method called cointegration analysis to observed global sea level and surface air temperature, capable of handling such peculiarities. We find a relationship between sea...... level and temperature and find that temperature causally depends on the sea level, which can be understood as a consequence of the large heat capacity of the ocean. We further find that the warming episode in the 1940s is exceptional in the sense that sea level and warming deviates from the expected...

  16. Composition of Surface Adsorbed Layer of TiO2 Stored in Ambient Air

    Directory of Open Access Journals (Sweden)

    Zakharenko V.S.

    2017-11-01

    Full Text Available The processes of dark, UV, and visible light promoted desorption of surface species were investigated for three different TiO2 samples: TiO2 prepared by dispersion of the titania single crystal, TiO2 prepared by combustion of a pyrotechnic mixture in air, and commercial TiO2 P25. The composition of the adsorbed layer was identified in the dark and under UV and visible light irradiation. The composition of desorption products showed the dependence of the adsorption layer state on the TiO2 nature. Methane photodesorption was detected only for the commercial TiO2 P25. Possible reasons for methane emission include the capturing of complete molecules during the TiO2 production process and photocatalytic hydrogenation of CO2 under UV-light.

  17. Aerosol composition and properties variation at the ground and over the column under different air masses advection in South Italy.

    Science.gov (United States)

    Pavese, G; Lettino, A; Calvello, M; Esposito, F; Fiore, S

    2016-04-01

    Aerosol composition and properties variation under the advection of different air masses were investigated, as case studies, by contemporary measurements over the atmospheric column and at the ground in a semi-rural site in South Italy. The absence of local strong sources in this area allowed to characterize background aerosol and to compare particle mixing effects under various atmospheric circulation conditions. Aerosol optical depth (AOD) and Ǻngström parameters from radiometric measurements allowed the detection and identification of polluted, dust, and volcanic atmospheric conditions. AODs were the input for a suitable model to evaluate the columnar aerosol composition, according to six main atmospheric components (water-soluble, soot, sea salt accumulation, sea salt coarse, mineral dus,t and biological). Scanning electron microscope (SEM) analysis of particulate sampled with a 13-stage impactor at the ground showed not only fingerprints typical of the different air masses but also the effects of transport and aging on atmospheric particles, suggesting processes that changed their chemical and optical properties. Background columnar aerosol was characterized by 72% of water-soluble and soot, in agreement with ground-based findings that highlighted 60% of contribution from anthropogenic carbonate particles and soot. In general, a good agreement between ground-based and columnar results was observed. Under the advection of trans-boundary air masses, water-soluble and soot were always present in columnar aerosol, whereas, in variable percentages, sea salt and mineral particles characterized both dust and volcanic conditions. At the ground, sulfates characterized the amorphous matrix produced in finer stages by the evaporation of solutions of organic and inorganic aerosols. Sulfates were also one of the key players involved in heterogeneous chemical reactions, producing complex secondary aerosol, as such clay-sulfate internally mixed particle externally mixed

  18. Man-made radioactivity of surface air and precipitation Munich-Neuherberg 1970-1975

    International Nuclear Information System (INIS)

    Hoetzl, H.; Rosner, G.; Winkler, R.

    1976-07-01

    The activity concentration of a number of artificial radionuclides and of Be 7 in surface air and the deposition of these nuclides to the ground by the precipitation is measured since 1970 resp. 1971 at Neuherberg near Munich. Air dust filters are compressed to give a pellet and precipitation is evaporated to a small volume before γ-spectrometry using a Ge(Li)-detector. After ashing of the samples Pusup(238, 239, 240) and Fe 55 are separated radiochemically and measured by alpha respectively X-ray spectrometry. The results, presented as monthly mean resp. sum values, are discussed and compared with results published by other authors (HASL, UKAEA, PTB, DWD a.o.). The contribution of artificial radioactivity to the radiation exposure from fallout nuclides during the years 1970 to 1975 was very low. Their concentration levels led to values of the annual intake, which are far beyond the admissible values according to the new Radiation Protection Ordinance of the FRG. With regard to the intake by inhalation Pu 239 is the most important of all observed nuclides, whereas in the case of ingestion Sr 90 is the critical nuclide. At this time the level of the activity concentration is mainly represented by the residual radioactivity from nuclear bomb tests. A continuous control is necessary because of the growth of nuclear power production and the increasing use of radionuclides. (orig.) [de

  19. Investigation of the fluctuation range of activity concentrations of natural radionuclides in surface air

    International Nuclear Information System (INIS)

    Winkler, R.; Hoetzl, H.

    1985-01-01

    Daily and seasonal concentration fluctuations of short-lived Rn fission products observed and the seasonal and long-term concentration fluctuations of Pb-210, Po-210, Ra-226, Ra-228, K-40 and Be-7 are discussed; the frequency distributions of the concentration values are illustrated. For a period of several years, the following mean values of activity concentrations were found (μBq/m 3 ): Pb-210: 600 Ra-226: 1.3 K-40: 13, Po-210: 33 Ra-228: 0.5 Be-7: 3700. In accordance with the origin from the soil, there is a significant correlation between the respective activity concentration and air-borne dust concentration for Ra-226, Ra-228, and K-40. The investigation revealed a most significant correlation between the Pb-210 concentration and the stagnancy index, the latter being a measure for the degree of blending of the surface layer of air. The resuspension factors found for Ra-226 and Pb-210 are discussed. (orig./HP) [de

  20. An analysis of surface air temperature trends and variability along the Andes

    Science.gov (United States)

    Franquist, Eric S.

    Climate change is difficult to study in mountainous regions such as the Andes since steep changes in elevation cannot always be resolved by climate models. However, it is important to examine temperature trends in this region as rises in surface air temperature are leading to the melting of tropical glaciers. Local communities rely on the glacier-fed streamflow to get their water for drinking, irrigation, and livestock. Moreover, communities also rely on the tourism of hikers who come to the region to view the glaciers. As the temperatures increase, these glaciers are no longer in equilibrium with their current climate and are receding rapidly and decreasing the streamflow. This thesis examines surface air temperature from 858 weather stations across Ecuador, Peru, and Chile in order to analyze changes in trends and variability. Three time periods were studied: 1961--1990, 1971--2000, and 1981--2010. The greatest warming occurred during the period of 1971--2000 with 92% of the stations experiencing positive trends with a mean of 0.24°C/decade. There was a clear shift toward cooler temperatures at all latitudes and below elevations of 500 m during the most recent time period studied (1981--2010). Station temperatures were more strongly correlated with the El Nino Southern Oscillation (ENSO), than the Pacific Decadal Oscillation (PDO), and the Southern Annular Mode (SAM). A principal component analysis confirmed ENSO as the main contributor of variability with the most influence in the lower latitudes. There were clear multidecadal changes in correlation strength for the PDO. The PDO contributed the most to the increases in station temperature trends during the 1961--1990 period, consistent with the PDO shift to the positive phase in the middle of this period. There were many strong positive trends at individual stations during the 1971--2000 period; however, these trends could not fully be attributed to ENSO, PDO, or SAM, indicating anthropogenic effects of

  1. Remote Sensing Global Surface Air Pressure Using Differential Absorption BArometric Radar (DiBAR)

    Science.gov (United States)

    Lin, Bing; Harrah, Steven; Lawrence, Wes; Hu, Yongxiang; Min, Qilong

    2016-01-01

    Tropical storms and severe weathers are listed as one of core events that need improved observations and predictions in World Meteorological Organization and NASA Decadal Survey (DS) documents and have major impacts on public safety and national security. This effort tries to observe surface air pressure, especially over open seas, from space using a Differential-absorption BArometric Radar (DiBAR) operating at the 50-55 gigahertz O2 absorption band. Air pressure is among the most important variables that affect atmospheric dynamics, and currently can only be measured by limited in-situ observations over oceans. Analyses show that with the proposed space radar the errors in instantaneous (averaged) pressure estimates can be as low as approximately 4 millibars (approximately 1 millibar under all weather conditions). With these sea level pressure measurements, the forecasts of severe weathers such as hurricanes will be significantly improved. Since the development of the DiBAR concept about a decade ago, NASA Langley DiBAR research team has made substantial progress in advancing the concept. The feasibility assessment clearly shows the potential of sea surface barometry using existing radar technologies. The team has developed a DiBAR system design, fabricated a Prototype-DiBAR (P-DiBAR) for proof-of-concept, conducted lab, ground and airborne P-DiBAR tests. The flight test results are consistent with the instrumentation goals. Observational system simulation experiments for space DiBAR performance based on the existing DiBAR technology and capability show substantial improvements in tropical storm predictions, not only for the hurricane track and position but also for the hurricane intensity. DiBAR measurements will lead us to an unprecedented level of the prediction and knowledge on global extreme weather and climate conditions.

  2. 21st century changes in the surface mass balance of the Greenland ice sheet simulated with the global model CESM

    Science.gov (United States)

    Vizcaíno, M.; Lipscomb, W. H.; Van den Broeke, M.

    2012-04-01

    We present here the first projections of 21st century surface mass balance change of the Greenland ice sheet simulated with the Community Earth System Model (CESM). CESM is a fully-coupled, global climate model developed at many research centers and universities, primarily in the U.S. The model calculates the surface mass balance in the land component (the Community Land Model, CLM), at the same resolution as the atmosphere (1 degree), with an energy-balance scheme. The snow physics included in CLM for non-glaciated surfaces (SNiCAR model, Flanner and Zender, 2005) are used over the ice sheet. The surface mass balance is calculated for 10 elevation classes, and then downscaled to the grid of the ice sheet model (5 km in this case) via vertical linear interpolation between elevation classes combined with horizontal bilinear interpolation. The ice sheet topography is fixed at present-day values for the simulations presented here. The use of elevation classes reduces computational costs while giving results that reproduce well the mass balance gradients at the steep margins of the ice sheet. The simulated present-day surface mass balance agrees well with results from regional models. We focus on the regional model RACMO (Ettema et al. 2009) to compare the results on 20th-century surface mass balance evolution and two-dimensional patterns. The surface mass balance of the ice sheet under RCP8.5. forcing becomes negative in the last decades of the 21st century. The equilibrium line becomes ~500 m higher on average. Accumulation changes are positive in the accumulation zone. We examine changes in refreezing, accumulation, albedo, surface fluxes, and the timing of the melt season.

  3. Estimation of the ability to use a mass of air from a moving vehicle in wind turbine propulsion

    Directory of Open Access Journals (Sweden)

    Adam BAWORSKI

    2015-09-01

    Full Text Available This work presents division and classification of wind turbines according to the location of the axis of rotation and generated power. The work introduces applications of the wind turbines in electric energy generation with their direct development. The paper discusses indicators and exploitation parameters that characterize particular types of wind rotators. Dimension and construction factors, as well as work parameters, have been analyzed in order to choose the optimal rotator in the road infrastructure application. The aim of the analysis was to conduct further investigation to restore a mass of air from passing vehicles.

  4. Detection of biological particles in ambient air using Bio-Aerosol Mass Spectrometry

    International Nuclear Information System (INIS)

    McJimpsey, E L; Steele, P T; Coffee, K R; Fergenson, D P; Riot, V J; Woods, B W; Gard, E E; Frank, M; Tobias, H J; Lebrilla, C

    2006-01-01

    The Bio-Aerosol Mass Spectrometry (BAMS) system is an instrument used for the real time detection and identification of biological aerosols. Particles are drawn from the atmosphere directly into vacuum and tracked as they scatter light from several continuous wave lasers. After tracking, the fluorescence of individual particles is excited by a pulsed 266nm or 355nm laser. Molecules from those particles with appropriate fluorescence properties are subsequently desorbed and ionized using a pulsed 266nm laser. Resulting ions are analyzed in a dual polarity mass spectrometer. During two field deployments at the San Francisco International Airport, millions of ambient particles were analyzed and a small but significant fraction were found to have fluorescent properties similar to Bacillus spores and vegetative cells. Further separation of non-biological background particles from potential biological particles was accomplished using laser desorption/ionization mass spectrometry. This has been shown to enable some level of species differentiation in specific cases, but the creation and observation of higher mass ions is needed to enable a higher level of specificity across more species. A soft ionization technique, matrix-assisted laser desorption/ionization (MALDI) is being investigated for this purpose. MALDI is particularly well suited for mass analysis of biomolecules since it allows for the generation of molecular ions from large mass compounds that would fragment under normal irradiation. Some of the initial results from a modified BAMS system utilizing this technique are described

  5. Air

    International Nuclear Information System (INIS)

    Gugele, B.; Scheider, J.; Spangl, W.

    2001-01-01

    In recent years several regulations and standards for air quality and limits for air pollution were issued or are in preparation by the European Union, which have severe influence on the environmental monitoring and legislation in Austria. This chapter of the environmental control report of Austria gives an overview about the legal situation of air pollution control in the European Union and in specific the legal situation in Austria. It gives a comprehensive inventory of air pollution measurements for the whole area of Austria of total suspended particulates, ozone, volatile organic compounds, nitrogen oxides, sulfur dioxide, carbon monoxide, heavy metals, benzene, dioxin, polycyclic aromatic hydrocarbons and eutrophication. For each of these pollutants the measured emission values throughout Austria are given in tables and geographical charts, the environmental impact is discussed, statistical data and time series of the emission sources are given and legal regulations and measures for an effective environmental pollution control are discussed. In particular the impact of fossil-fuel power plants on the air pollution is analyzed. (a.n.)

  6. Gases Emission From Surface Layers of Sand Moulds and Cores Stored Under the Humid Air Conditions

    Directory of Open Access Journals (Sweden)

    Kaźnica N.

    2017-12-01

    Full Text Available A large number of defects of castings made in sand moulds is caused by gases. There are several sources of gases: gases emitted from moulds, cores or protective coatings during pouring and casting solidification; water in moulding sands; moisture adsorbed from surroundings due to atmospheric conditions changes. In investigations of gas volumetric emissions of moulding sands amounts of gases emitted from moulding sand were determined - up to now - in dependence of the applied binders, sand grains, protective coatings or alloys used for moulds pouring. The results of investigating gas volumetric emissions of thin-walled sand cores poured with liquid metal are presented in the hereby paper. They correspond to the surface layer in the mould work part, which is decisive for the surface quality of the obtained castings. In addition, cores were stored under conditions of a high air humidity, where due to large differences in humidity, the moisture - from surroundings - was adsorbed into the surface layer of the sand mould. Due to that, it was possible to asses the influence of the adsorbed moisture on the gas volumetric emission from moulds and cores surface layers by means of the new method of investigating the gas emission kinetics from thin moulding sand layers heated by liquid metal. The results of investigations of kinetics of the gas emission from moulding sands with furan and alkyd resins as well as with hydrated sodium silicate (water glass are presented. Kinetics of gases emissions from these kinds of moulding sands poured with Al-Si alloy were compared.

  7. Global Validation of MODIS Atmospheric Profile-Derived Near-Surface Air Temperature and Dew Point Estimates

    Science.gov (United States)

    Famiglietti, C.; Fisher, J.; Halverson, G. H.

    2017-12-01

    This study validates a method of remote sensing near-surface meteorology that vertically interpolates MODIS atmospheric profiles to surface pressure level. The extraction of air temperature and dew point observations at a two-meter reference height from 2001 to 2014 yields global moderate- to fine-resolution near-surface temperature distributions that are compared to geographically and temporally corresponding measurements from 114 ground meteorological stations distributed worldwide. This analysis is the first robust, large-scale validation of the MODIS-derived near-surface air temperature and dew point estimates, both of which serve as key inputs in models of energy, water, and carbon exchange between the land surface and the atmosphere. Results show strong linear correlations between remotely sensed and in-situ near-surface air temperature measurements (R2 = 0.89), as well as between dew point observations (R2 = 0.77). Performance is relatively uniform across climate zones. The extension of mean climate-wise percent errors to the entire remote sensing dataset allows for the determination of MODIS air temperature and dew point uncertainties on a global scale.

  8. Greenland Surface Mass Balance as Simulated by the Community Earth System Model. Part II: Twenty-First-Century Changes

    NARCIS (Netherlands)

    Vizcaino, M.; Lipscomb, W.H.; Sacks, W.J.; van den Broeke, M.R.

    2014-01-01

    This study presents the first twenty-first-century projections of surface mass balance (SMB) changes for the Greenland Ice Sheet (GIS) with the Community Earth System Model (CESM), which includes a new ice sheet component. For glaciated surfaces, CESM includes a sophisticated calculation of energy

  9. Elevation change of the Greenland Ice Sheet due to surface mass balance and firn processes, 1960-2014

    NARCIS (Netherlands)

    Kuipers Munneke, P.; Ligtenberg, S. R M; Noël, B. P Y; Howat, I. M.; Box, J. E.; Mosley-Thompson, E.; McConnell, J. R.; Steffen, K.; Harper, J. T.; Das, S. B.; Van Den Broeke, M. R.

    2015-01-01

    Observed changes in the surface elevation of the Greenland Ice Sheet are caused by ice dynamics, basal elevation change, basal melt, surface mass balance (SMB) variability, and by compaction of the overlying firn. The last two contributions are quantified here using a firn model that includes

  10. The Response of the Ocean Thermal Skin Layer to Air-Sea Surface Heat Fluxes

    Science.gov (United States)

    Wong, Elizabeth Wing-See

    There is much evidence that the ocean is heating as a result of an increase in concentrations of greenhouse gases (GHGs) in the atmosphere from human activities. GHGs absorb infrared radiation and re-emit infrared radiation back to the ocean's surface which is subsequently absorbed. However, the incoming infrared radiation is absorbed within the top micrometers of the ocean's surface which is where the thermal skin layer exists. Thus the incident infrared radiation does not directly heat the upper few meters of the ocean. We are therefore motivated to investigate the physical mechanism between the absorption of infrared radiation and its effect on heat transfer at the air-sea boundary. The hypothesis is that since heat lost through the air-sea interface is controlled by the thermal skin layer, which is directly influenced by the absorption and emission of infrared radiation, the heat flow through the thermal skin layer adjusts to maintain the surface heat loss, assuming the surface heat loss does not vary, and thus modulates the upper ocean heat content. This hypothesis is investigated through utilizing clouds to represent an increase in incoming longwave radiation and analyzing retrieved thermal skin layer vertical temperature profiles from a shipboard infrared spectrometer from two research cruises. The data are limited to night-time, no precipitation and low winds of less than 2 m/s to remove effects of solar radiation, wind-driven shear and possibilities of thermal skin layer disruption. The results show independence of the turbulent fluxes and emitted radiation on the incident radiative fluxes which rules out the immediate release of heat from the absorption of the cloud infrared irradiance back into the atmosphere through processes such as evaporation and increase infrared emission. Furthermore, independence was confirmed between the incoming and outgoing radiative flux which implies the heat sink for upward flowing heat at the air-sea interface is more

  11. The composition of pollutted air in Moscow based on surface observations

    Science.gov (United States)

    Pankratova, Natalia; Elansky, Nikolai; Skorokhod, Andrey

    2013-04-01

    Moscow is the one of the biggest world megacities. Population, industry, transport are strong sources of air pollution. This pollution influences on the air quality in the city and in the neighbor regions due to spreading by the wind. Here we present an analysis of variations of atmospheric compounds in Moscow since 2002 until the present in its dependence on different atmospheric characteristics, particularly cyclonic and anticyclonic conditions, heat waves and anthropogenic factors. The following variables are considered: NO2, NO, CO, CO2, O3, SO2, NMHC. The monitoring site is located at Moscow State University meteorological observatory on the South-West of Moscow. All observations are provided by A.M. Obukhov Institute of Atmospheric Physics RAS. Due to these continuous measurements, the typical (ore basic) level of pollution as well as the extreme cases have been studied. The temporal variability of the atmospheric compounds, and the chemical interaction of ozone and nitrogen oxides are investigated. High concentrations of nitrogen oxides are observed throughout the year. During some months the 90th NO2 percentile exceeds 60 ppb, NO - 80 ppb. Based on surface observations, we show that extremes of pollutant concentrations correspond with anticyclonic conditions and anthropogenic processes. These often increase the impact on the weather. These situations correspond with the anomalous cold winter in 2006 and heat wave in 2002. In these periods, concentrations of air pollutions exceed MAC, but the ozone concentration usually decreases due to interaction with NOx. Only two times, ozone concentration exceeded MAC - the heat waves 2002 and 2010. Also in the study we obtain the logarithmic dependence between ozone mix ratio and NO2/NO, which can be used for prediction of the surface ozone concentrations in Moscow: [O3] = 12.22Ln([NO2]/[NO]) + 15.3 However, this equation is not possible to use in smog conditions. From 29 July to 15 August Moscow was in a dense smoke

  12. Prediction of lake surface temperature using the air2water model: guidelines, challenges, and future perspectives

    Directory of Open Access Journals (Sweden)

    Sebastiano Piccolroaz

    2016-04-01

    Full Text Available Water temperature plays a primary role in controlling a wide range of physical, geochemical and ecological processes in lakes, with considerable influences on lake water quality and ecosystem functioning. Being able to reliably predict water temperature is therefore a desired goal, which stimulated the development of models of different type and complexity, ranging from simple regression-based models to more sophisticated process-based numerical models. However, both types of models suffer of some limitations: the first are not able to address some fundamental physical processes as e.g., thermal stratification, while the latter generally require a large amount of data in input, which are not always available. In this work, lake surface temperature is simulated by means of air2water, a hybrid physically-based/statistical model, which is able to provide a robust, predictive understanding of LST dynamics knowing air temperature only. This model showed performances that are comparable with those obtained by using process based models (a root mean square error on the order of 1°C, at daily scale, while retaining the simplicity and parsimony of regression-based models, thus making it a good candidate for long-term applications.The aim of the present work is to provide the reader with useful and practical guidelines for proper use of the air2water model and for critical analysis of results. Two case studies have been selected for the analysis: Lake Superior and Lake Erie. These are clear and emblematic examples of a deep and a shallow temperate lake characterized by markedly different thermal responses to external forcing, thus are ideal for making the results of the analysis the most general and comprehensive. Particular attention is paid to assessing the influence of missing data on model performance, and to evaluating when an observed time series is sufficiently informative for proper model calibration or, conversely, data are too scarce thus

  13. Near-surface air temperature lapse rates in Xinjiang, northwestern China

    Science.gov (United States)

    Du, Mingxia; Zhang, Mingjun; Wang, Shengjie; Zhu, Xiaofan; Che, Yanjun

    2018-02-01

    Lapse rates of near-surface (2 m) air temperature are important parameters in hydrologic and climate simulations, especially for the mountainous areas without enough in-situ observations. In Xinjiang, northwestern China, the elevations range from higher than 7000 m to lower than sea level, but the existing long-term meteorological measurements are limited and distributed unevenly. To calculate lapse rates in Xinjiang, the daily data of near-surface air temperature ( T min, T ave, and T max) were measured by automatic weather stations from 2012 to 2014. All the in situ observation stations were gridded into a network of 1.5° (latitude) by 1.5° (longitude), and the spatial distribution and the daily, monthly, seasonal variations of lapse rates for T min, T ave, and T max in Xinjiang are analyzed. The Urumqi River Basin has been considered as a case to study the influence of elevation, aspect, and the wet and dry air conditions to the T min, T ave, and T max lapse rates. Results show that (1) the lapse rates for T min, T ave, and T max vary spatially during the observation period. The spatial diversity of T min lapse rates is larger than that of T ave, and that of T max is the smallest. For each season, T max lapse rates have more negative values than T ave lapse rates which are steeper than T min lapse rates. The weakest spatial diversity usually appears in July throughout a year. (2) The comparison for the three subregions (North, Middle, and South region) exhibits that lapse rates have similar day-to-day and month-to-month characteristics which present shallower values in winter months and steeper values in summer months. The T ave lapse rates in North region are shallower than those in Middle and South region, and the steepest T ave lapse rates of the three regions all appear in April. T min lapse rates are shallower than T max lapse rates. The maximum medians of T min and T max lapse rates for each grid in the three regions all appear in January, whereas the

  14. Quality control for total evaporation technique by surface/thermal ionization mass spectrometer

    International Nuclear Information System (INIS)

    Kato, Seikou; Inoue, Sinichi; Yamaguchi, Katsuyuki; Tsutaki, Yasuhiro

    2007-01-01

    For the measurement of uranium and plutonium isotopic composition, the surface/thermal ionization mass spectrometry is widely used at the both nuclear facilities and safeguards verification laboratories. The progress of instrument specification makes higher sensitivity. The total evaporation technique is one of the latest measurement techniques by using this progress, in which all of uranium or plutonium on the filament would be evaporated by increasing the filament current. The accuracy and precision of this technique is normally checked by using the certified isotope reference materials measurement. But the fluctuation of ion beam is very different by each filament, depending on the chemical form of evaporation. So, it should be considered how to check the measurement quality of unknown samples which has no certified values. This presentation is focused on the monitoring of ion yields and pattern of isotope ratio fluctuation to attain the traceability between reference material and unknown sample as quality control approach of total evaporation technique. (author)

  15. Automatic extraction of discontinuity orientation from rock mass surface 3D point cloud

    Science.gov (United States)

    Chen, Jianqin; Zhu, Hehua; Li, Xiaojun

    2016-10-01

    This paper presents a new method for extracting discontinuity orientation automatically from rock mass surface 3D point cloud. The proposed method consists of four steps: (1) automatic grouping of discontinuity sets using an improved K-means clustering method, (2) discontinuity segmentation and optimization, (3) discontinuity plane fitting using Random Sample Consensus (RANSAC) method, and (4) coordinate transformation of discontinuity plane. The method is first validated by the point cloud of a small piece of a rock slope acquired by photogrammetry. The extracted discontinuity orientations are compared with measured ones in the field. Then it is applied to a publicly available LiDAR data of a road cut rock slope at Rockbench repository. The extracted discontinuity orientations are compared with the method proposed by Riquelme et al. (2014). The results show that the presented method is reliable and of high accuracy, and can meet the engineering needs.

  16. Mass balance of the Greenland ice sheet - a study of ICESat data, surface density and firn compaction modelling

    DEFF Research Database (Denmark)

    Sørensen, L. S.; Simonsen, Sebastian Bjerregaard; Nielsen, K.

    2010-01-01

    ICESat has provided surface elevation measurements of the ice sheets since the launch in January 2003, resulting in a unique data set for monitoring the changes of the cryosphere. Here we present a novel method for determining the mass balance of the Greenland ice sheet derived from ICESat...... in estimating the mass balance of the Greenland ice sheet. We find firn dynamics and surface densities to be important factors in deriving the mass loss from remote sensing altimetry. The volume change derived from ICESat data is corrected for firn compaction, vertical bedrock movement and an intercampaign...... boundary conditions. We find an annual mass loss of the Greenland ice sheet of 210 ± 21 Gt yr-1 in the period from October 2003 to March 2008. This result is in good agreement with other studies of the Greenland ice sheet mass balance, based on different remote sensing techniques....

  17. Mass transfer inside a flux hood for the sampling of gaseous emissions from liquid surfaces - Experimental assessment and emission rate rescaling

    Science.gov (United States)

    Prata, Ademir A.; Lucernoni, Federico; Santos, Jane M.; Capelli, Laura; Sironi, Selena; Le-Minh, Nhat; Stuetz, Richard M.

    2018-04-01

    This study assesses the mass transfer of compounds inside the US EPA flux hood, one of the enclosure devices most commonly employed for the direct measurement of atmospheric emissions from liquid surfaces in wastewater treatment plants (WWTPs). Experiments comprised the evaporation of water and the volatilisation of a range of volatile organic compounds (VOCs). Special attention was given to the evaluation of the mass transfer coefficients in the microenvironment created by the flux hood and the effects of concentration build up in the hood's headspace. The VOCs emission rates and the water evaporation rates generally increased with the sweep air flow rate, as did the mass transfer coefficients for all compounds. The emission of compounds whose volatilisation is significantly influenced by the gas phase was greatly affected by concentration build up, whereas this effect was not significant for liquid phase-controlled compounds. The gas-film mass transfer coefficient (kG) estimated inside the US EPA flux hood was of the same order as the respective kG reported in the literature for wind tunnel-type devices, but the emission rates measured by the flux hood can be expected to be lower, due to the concentration build-up. Compared against an emission model for the passive surfaces in WWTPs, the mass transfer of acetic acid (representing a gas phase-dominated compound) inside the US EPA flux hood was equivalent to conditions of wind speeds at 10 m height (U10) of 0.27, 0.51 and 0.99 m s-1, respectively, for sweep air flow rates of 2, 5 and 10 L min-1. On the other hand, for higher wind speeds, the emission rates of gas phase-controlled compounds obtained with the flux hood can be considerably underestimated: for instance, at U10 = 5 m s-1, the emission rates of acetic acid inside the flux hood would be approximately 23, 12 and 6 times lower than the emission rates in the field, for sweep air flow rates of 2, 5 and 10 L min-1, respectively. A procedure is presented in

  18. Impacts of land use and land cover on surface and air temperature in urban landscapes

    Science.gov (United States)

    Crum, S.; Jenerette, D.

    2015-12-01

    Accelerating urbanization affects regional climate as the result of changing land cover and land use (LCLU). Urban land cover composition may provide valuable insight into relationships among urbanization, air, and land-surface temperature (Ta and LST, respectively). Climate may alter these relationships, where hotter climates experience larger LULC effects. To address these hypotheses we examined links between Ta, LST, LCLU, and vegetation across an urban coastal to desert climate gradient in southern California, USA. Using surface temperature radiometers, continuously measuring LST on standardized asphalt, concrete, and turf grass surfaces across the climate gradient, we found a 7.2°C and 4.6°C temperature decrease from asphalt to vegetated cover in the coast and desert, respectively. There is 131% more temporal variation in asphalt than turf grass surfaces, but 37% less temporal variation in concrete than turf grass. For concrete and turf grass surfaces, temporal variation in temperature increased from coast to desert. Using ground-based thermal imagery, measuring LST for 24 h sequences over citrus orchard and industrial use locations, we found a 14.5°C temperature decrease from industrial to orchard land use types (38.4°C and 23.9°C, respectively). Additionally, industrial land use types have 209% more spatial variation than orchard (CV=0.20 and 0.09, respectively). Using a network of 300 Ta (iButton) sensors mounted in city street trees throughout the region and hyperspectral imagery data we found urban vegetation greenness, measured using the normalized difference vegetation index (NDVI), was negatively correlated to Ta at night across the climate gradient. Contrasting previous findings, the closest coupling between NDVI and Ta is at the coast from 0000 h to 0800 h (highest r2 = 0.6, P urbanized regions of southern California, USA decrease Ta and LST and spatial variation in LST, while built surfaces and land uses have the opposite effect. Furthermore

  19. Mass transfer during sulfuric acid concentration by evaporation into the air flow

    Directory of Open Access Journals (Sweden)

    V. K. Lukashov

    2016-12-01

    Full Text Available This article shows the results of the study of mass transfer under periodic concentration of sulfuric acid by evaporation inthe gas flow, neutral with respect to the components of acid.Used mathematical model for mass transferbases on the proposed simplified physical representations.This model has allowed to construct an algorithm for calculation the coefficient of mass transfer from the liquid phase into the gas flow. The algorithm uses the experimental data of change the amount of acid and concentration of the water taken from the laboratory tests. Time-based Nusselt diffusion criterion represent the results of the study at different modes of the evaporation process.It has been found that the character of the influence of temperature and initial acid concentration on Nusselt diffusion criterion depends on the variation range of the mass fraction of water in the acid.It is shown that these dependences are well approximated by an exponential function from the dimensionless parameters of the process. This allows usingthem for calculation the mass transfer coefficient into the gas phase in a batch process of concentrating in the range of investigated modes.

  20. Isotope dilution surface ionization mass spectrometry of silver in environmental materials

    Energy Technology Data Exchange (ETDEWEB)

    Murozumi, M; Nakamura, S; Suga, K [Muroran Inst. of Tech., Hokkaido (Japan)

    1981-03-01

    Surface ionization mass spectrometry has been developed to measure isotopic abundances and concentrations of silver in commercial high-purity metals, environmental materials such as rocks and plants, and /sup 109/Ag and /sup 107/Ag spikes. A minute amount of silver is extracted into a dithizone chloroform solution from a nitric acid solution of above samples. After the silver is back-extracted into 6.0 ml of a 7 mol/l HNO/sub 3/ solution, the solution is evaporated to dryness under the nitrogen atmosphere. Silver nitrate thus formed is dissolved in a mixture of 60 ..mu..l of an 0.003% silica gel suspended water and 5 ..mu..l of a 2% phosphoric acid. An aliquot of this solution is applied to the mass spectrometry using a rhenium single filament as an ion emitter. The proposed method can detect the presence of 10/sup -14/ g of silver on the ion emitter, and measure the /sup 109/Ag//sup 107/Ag isotopic ratio in environmental materials with the accuracy of 0.1 -- 0.2% in the coefficient of variation. Isotope dilution mass spectrometry using a /sup 107/Ag spike has revealed the silver concentration in the environmental standard materials, which were prepared by the National Bureau of Standards, U.S.A. and National Institute of Environmental Studies of Japan, as follows; 27.9 +- 0.2 ppb for the Orchard Leaves and 34.3 +- 0.3 ppb in the Pepper Bush. The determined values of silver in the Granodiorite, JG-1, and Basalt, JB-1 powders made by the Geological Survey of Japan are 25.4 +- 0.4 ppb and 41.3 +- 0.1 ppb respectively. Silver concentration in a coastal sea water sample is found to be at the level of 2.5 +- 0.4 ppt.

  1. Surface modification of thermoplastic poly(vinyl alcohol)/saponite nanocomposites via surface-initiated atom transfer radical polymerization enhanced by air dielectric discharges barrier plasma treatment

    International Nuclear Information System (INIS)

    Zhen Weijun; Lu Canhui

    2012-01-01

    To improve the water resistance of thermoplastic poly(vinyl alcohol)/saponite nanocomposites (TPVA), a simple two-step method was developed for the covalent immobilization of atom transfer radical polymerization (ATRP) initiators on the TPVA surfaces enhanced by air dielectric barrier discharges (DBD) plasma treatment, and hydrophobic poly(methyl methacrylate) (PMMA) brushes were then grafted onto the surface of TPVA via surface-initiated atom transfer radical polymerization (SI-ATRP). The chemical composition, morphology and hydrophobicity of the modified TPVA surfaces were characterized by X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM), respectively. The water resistance of the surface-functionalized PMMA was evaluated by the contact angle and water adsorption method. It was shown that air DBD plasma treatment activated the TPVA surface and accelerated the immobilization of ATRP initiator on the TPVA surface. Compared with TPVA control, TPVA modified by SI-ATRP can be grafted well-defined and covalently tethered network PMMA brushes onto the surface and the hydrophobicity of TPVA were significantly enhanced.

  2. Stress response of Escherichia coli induced by surface streamer discharge in humid air

    International Nuclear Information System (INIS)

    Doležalová, Eva; Prukner, Václav; Lukeš, Petr; Šimek, Milan

    2016-01-01

    Inactivation of Escherichia coli by means of surface streamer discharge has been investigated to obtain new insights into the key mechanisms involved, with a particular emphasis placed on the microbial response to plasma-induced stress. The surface streamer discharge was produced in coplanar dielectric barrier discharge electrode geometry, and was driven by an amplitude-modulated ac high voltage in humid synthetic air at atmospheric pressure. The response to plasma-induced stress was evaluated by using conventional cultivation, sublethal injury and resazurin assay and the LIVE/DEAD ® BacLight ™ Bacterial Viability kit. Compared to conventional cultivation, the LIVE/DEAD ® test labels bacteria with damaged membranes, while resazurin assay tracks their metabolic activity. Our results clearly demonstrate that the treated bacteria partly lost their ability to grow properly, i.e. they became injured and culturable, or even viable but nonculturable (VBNC). The ability to develop colonies could have been lost due to damage of the bacterial membrane. Damage of the membranes was mainly caused by the lipid peroxidation, evidencing the key role of oxygen reactive species, in particular ozone. We conclude that the conventional cultivation method overestimates the decontamination efficiency of various plasma sources, and must therefore be complemented by alternative techniques capable of resolving viable but nonculturable bacteria. (paper)

  3. ENSO shifts and their link to Southern Africa surface air temperature in summer

    Science.gov (United States)

    Manatsa, D.; Mukwada, G.; Makaba, L.

    2018-05-01

    ENSO has been known to influence the trends of summer warming over Southern Africa. In this work, we used observational and reanalysis data to analyze the relationship between ENSO and maximum surface air temperature (SATmax) trends during the three epochs created by the ENSO phase shifts around 1977 and 1997 for the period 1960 to 2014. We observed that while ENSO and cloud cover remains the dominant factor controlling SATmax variability, the first two epochs had the predominant La Niña (El Niño)-like events connected to robust positive (negative) trends in cloud fraction. However, this established relationship reversed in the post-1997 La Niña-like dominated epoch which coincided with a falling cloud cover trend. It is established that this deviation from the previously established link within the previous epochs could be due to the post-1998 era in which SATmin was suppressed while SATmax was enhanced. The resulting increase in diurnal temperature range (DTR) could have discouraged the formation of low-level clouds which have relatively more extensive areal coverage and hence allowing more solar energy to reach the surface to boost daytime SATmax. It is noted that these relationships are more pronounced from December to March.

  4. Plasma flame for mass purification of contaminated air with chemical and biological warfare agents

    International Nuclear Information System (INIS)

    Uhm, Han S.; Shin, Dong H.; Hong, Yong C.

    2006-01-01

    An elimination of airborne simulated chemical and biological warfare agents was carried out by making use of a plasma flame made of atmospheric plasma and a fuel-burning flame, which can purify the interior air of a large volume in isolated spaces such as buildings, public transportation systems, and military vehicles. The plasma flame generator consists of a microwave plasma torch connected in series to a fuel injector and a reaction chamber. For example, a reaction chamber, with the dimensions of a 22 cm diameter and 30 cm length, purifies an airflow rate of 5000 lpm contaminated with toluene (the simulated chemical agent) and soot from a diesel engine (the simulated aerosol for biological agents). Large volumes of purification by the plasma flame will free mankind from the threat of airborne warfare agents. The plasma flame may also effectively purify air that is contaminated with volatile organic compounds, in addition to eliminating soot from diesel engines as an environmental application

  5. Mass and elemental concentrations of air bone particles at Kuala Lumpur site in 2000 to 2006

    International Nuclear Information System (INIS)

    Abdul Khalik Wood; Mohd Suhaimi Hamzah; Shamsiah Abdul Rahman

    2008-01-01

    Atmospheric Pollution due to air bone particle is a major concern to many cities in the Southeast Asian region, including Kuala Lumpur. Within the last six years air particulate samples have been collected from a site in Kuala Lumpur and measured for their PM10, PM2.5 and elemental concentrations. The results showed that the daily PM10 (<10μ diameter) concentrations were generally acceptable but the values occasionally very high, especially during the haze episodes. The PM10 annual average values were just below the national set standard and these values were mostly contributed by the fine particles (<2μ diameter) concentration. The annual average for PM2.5 (fine particle) concentrations over the past few years were considerably high where elemental carbon, sulfur and potassium were the main components. (Author)

  6. Air Force Intelligence Role in Combating Weapons of Mass Destruction (Maxwell Paper, Number 39)

    Science.gov (United States)

    2006-11-01

    Zielinski , National Counterproliferation Center chief of staff, interview by the author, 3 February 2006. 42...Col Joe Pridotkas, NASIC/CC, interview by the author, 28 Febru- ary 2006. 29 78. Report to the President, 6. 79. Sandi Zielinski , National...Force C-CBRNE Master Plan, 30 June 2004, 5. 84. Dave Coffey, Air Combat Command IS/FPI, interview by the author, 2 February 2006. 85. Col

  7. BAERLIN2014 – the influence of land surface types on and the horizontal heterogeneity of air pollutant levels in Berlin

    Directory of Open Access Journals (Sweden)

    B. Bonn

    2016-06-01

    -wise measurement of volatile organic compounds (VOCs at representative sites for traffic- and vegetation-affected sites. The quantification d