Hydrogen sensor

Science.gov (United States)

Duan, Yixiang; Jia, Quanxi; Cao, Wenqing

2010-11-23

A hydrogen sensor for detecting/quantitating hydrogen and hydrogen isotopes includes a sampling line and a microplasma generator that excites hydrogen from a gas sample and produces light emission from excited hydrogen. A power supply provides power to the microplasma generator, and a spectrometer generates an emission spectrum from the light emission. A programmable computer is adapted for determining whether or not the gas sample includes hydrogen, and for quantitating the amount of hydrogen and/or hydrogen isotopes are present in the gas sample.

Sustainability of Hydrogen Supply Chain. Part II: Prioritizing and Classifying the Sustainability of Hydrogen Supply Chains based on the Combination of Extension Theory and AHP

DEFF Research Database (Denmark)

Ren, Jingzheng; Manzardo, Alessandro; Toniolo, Sara

2013-01-01

The purpose of this study is to develop a method for prioritizing and classifying the sustainability of hydrogen supply chains and assist decision-making for the stakeholders/decision-makers. Multiple criteria for sustainability assessment of hydrogen supply chains are considered and multiple...... decision-makers are allowed to participate in the decision-making using linguistic terms. In this study, extension theory and analytic hierarchy process are combined to rate the sustainability of hydrogen supply chains. The sustainability of hydrogen supply chains could be identified according...

Gas supply planning for new gas-fired electricity generation facilities

International Nuclear Information System (INIS)

Slocum, J.C.

1990-01-01

This paper explores several key issues in gas supply planning for new gas fired electric generation facilities. This paper will have two main sections, as follows: developing the gas supply plan for a gas-fired electricity generation facility and exploring key gas supply contract pricing issues

Vancouver Island gas supply

International Nuclear Information System (INIS)

Des Brisay, C.

2005-01-01

Terasen Gas is pursuing alternatives for the supply of additional natural gas capacity to Vancouver Island. Its subsidiary, Terasen Gas (Vancouver Island) Inc. (TGVI), is responding to the need for delivery of increased gas supply and, is supporting plans for new gas-fired power generation on Vancouver Island. TGVI's proposal for new natural gas capacity involves a combination of compression and pipeline loops as well as the addition of a storage facility for liquefied natural gas (LNG) at Mt. Hayes to help manage price volatility. This presentation outlined the objectives and components of the resource planning process, including demand forecast scenarios and the preferred infrastructure options. tabs., figs

The use of the natural-gas pipeline infrastructure for hydrogen transport in a changing market structure

International Nuclear Information System (INIS)

Haeseldonckx, Dries; D'haeseleer, William

2007-01-01

In this paper, the transport and distribution aspects of hydrogen during the transition period towards a possible full-blown hydrogen economy are carefully looked at. Firstly, the energetic and material aspects of hydrogen transport through the existing natural-gas (NG) pipeline infrastructure is discussed. Hereby, only the use of centrifugal compressors and the short-term security of supply seem to constitute a problem for the NG to hydrogen transition. Subsequently, the possibility of percentwise mixing of hydrogen into the NG bulk is dealt with. Mixtures containing up to 17 vol% of hydrogen should not cause difficulties. As soon as more hydrogen is injected, replacement of end-use applications and some pipelines will be necessary. Finally, the transition towards full-blown hydrogen transport in (previously carrying) NG pipelines is treated. Some policy guidelines are offered, both in a regulated and a liberalised energy (gas) market. As a conclusion, it can be stated that the use of hydrogen-natural gas mixtures seems well suited for the transition from natural gas to hydrogen on a distribution (low pressure) level. However, getting the hydrogen gas to the distribution grid, by means of the transport grid, remains a major issue. In the end, the structure of the market, regulated or liberalised, turns out not to be important. (author)

Reconstruction of Low Pressure Gas Supply System

Directory of Open Access Journals (Sweden)

S. N. Osipov

2013-01-01

Full Text Available The current reconstruction of residential areas in large cities especially with the developed heat-supply systems from thermal power stations and reduction of heat consumption for heating due to higher thermal resistance of building enclosing structures requires new technical solutions in respect of gas-supply problems. While making reconstruction of a gas-supply system of the modernized or new buildings in the operating zone of one gas-distribution plant it is necessary to change hot water-supply systems from gas direct-flow water heaters to centralized heat-supply and free gas volumes are to be used for other needs or gas-supply of new buildings with the current external gas distribution network.Selection of additional gas-line sections and points of gas-supply systems pertaining to new and reconstructed buildings for their connection to the current distribution system of gas-supply is to be executed in accordance with the presented methodology.

Hydrogen gas sample environment for TOSCA

International Nuclear Information System (INIS)

Kibble, Mark G; Ramirez-Cuesta, Anibal J; Goodway, Chris M; Evans, Beth E; Kirichek, Oleg

2014-01-01

The idea of using hydrogen as a fuel has gained immense popularity over many years. Hydrogen is abundant, can be produced from renewable resources and is not a greenhouse gas. However development of hydrogen based technology is impossible without understanding of physical and chemical processes that involve hydrogen sometime in extreme conditions such as high pressure or low and high temperatures. Neutron spectroscopy allows measurement of a hydrogen atom motion in variety of samples. Here we describe and discuss a sample environment kit developed for hydrogen gas experiment in a broad range of pressure up to 7 kbar and temperatures from 4 K to 473 K. We also describe para-hydrogen rig which produces para-hydrogen gas required for studying the rotational line of molecular hydrogen

Hydrogen pellet injection device

International Nuclear Information System (INIS)

Kanno, Masahiro.

1992-01-01

In a hydrogen pellet injection device, a nozzle block having a hydrogen gas supply channel is disposed at the inner side of a main cryogenic housing, and an electric resistor is attached to the block. Further, a nozzle block and a hydrogen gas introduction pipe are attached by way of a thermal insulating spacer. Electric current is supplied to the resistor to positively heat the nozzle block and melt remaining solid hydrogen in the hydrogen gas supply channel. Further, the effect of temperature elevation due to the resistor is prevented from reaching the side of the hydrogen gas introduction pipe by the thermal insulation spacer. That is, the temperature of the nozzle block is directly and positively elevated, to melt the solid hydrogen rapidly. Preparation operation from the injection of the hydrogen pellet to the next injection can be completed in a shorter period of time compared with a conventional case thereby enabling to make the test more efficient. Further, only the temperature of the nozzle block is elevated with no effect of temperature elevation due to the resistor to other components by the thermal insulation flange. (N.H.)

Balancing gas supply and demand with a sustainable gas supply chain : a study based on field data

NARCIS (Netherlands)

Bekkering, Jan; Broekhuis, A. A.; van Gemert, Wim; Hengeveld, Evert Jan

The possibilities of balancing gas supply and demand with a green gas supply chain were analyzed. The considered supply chain is based on co-digestion of cow manure and maize, the produced biogas is upgraded to (Dutch) natural gas standards. The applicability of modeling yearly gas demand data in a

Balancing gas supply and demand with a sustainable gas supply chain : A study based on field data

NARCIS (Netherlands)

Bekkering, J.; Broekhuis, A. A.; van Gemert, W. J. T.; Hengeveld, E. J.

2013-01-01

The possibilities of balancing gas supply and demand with a green gas supply chain were analyzed. The considered supply chain is based on co-digestion of cow manure and maize, the produced biogas is upgraded to (Dutch) natural gas standards. The applicability of modeling yearly gas demand data in a

Generation of oxy-hydrogen gas and its effect on performance of spark ignition engine

Science.gov (United States)

Patil, N. N.; Chavan, C. B.; More, A. S.; Baskar, P.

2017-11-01

Considering the current scenario of petroleum fuels, it has been observed that, they will last for few years from now. On the other hand, the ever increasing cost of a gasoline fuels and their related adverse effects on environment caught the attention of researchers to find a supplementary source. For commercial fuels, supplementary source is not about replacing the entire fuel, instead enhancing efficiency by simply making use of it in lesser amount. From the recent research that has been carried out, focus on the use of Hydrogen rich gas as a supplementary source of fuel has increased. But the problem related to the storage of hydrogen gas confines the application of pure hydrogen in petrol engine. Using oxy-hydrogen gas (HHO) generator the difficulties of storing the hydrogen have overcome up to a certain limit. The present study highlights on performance evaluation of conventional petrol engine by using HHO gas as a supplementary fuel. HHO gas was generated from the electrolysis of water. KOH solution of 3 Molar concentration was used which act as a catalyst and accelerates the rate of generation of HHO gas. Quantity of gas to be supplied to the engine was controlled by varying amount of current. It was observed that, engine performance was improved on the introduction of HHO gas.

Fiscal 1999 phase 2 R and D report of WE-NET (International Clean Energy Network Using Hydrogen Conversion). Task 7. Development of hydrogen supply station; 1999 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) dainiki kenkyu kaihatsu seika hokokusho. Task 7. Suiso kyokyu station no kaihatsu

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

This report summarizes the fiscal 1999 research result on element technologies and system technology for hydrogen supply stations. In 1999, study was made on the total system of hydrogen supply stations, and basic specifications and total designs were studied for such main component systems of hydrogen supply stations as hydrogen production equipment with a reformer of natural gas, polymer electrolyte water electrolyzer hydrogen supply system, hydrogen absorbing alloy tank, and hydrogen dispenser unit. From the study result on the optimum operation condition of the hydrogen production equipment, a S/C (ratio of steam/mol of material carbon) of 2.5, reforming temperature of 700 degrees C, recycling gas ratio of 0.21, and air-fuel ratio of 1.3-2.0 were obtained. In the study on optimum hydrogen absorbing alloy, LaNi{sub 5} alloy system with Mn as additive were selected. For the polymer electrolyte water electrolyzer hydrogen supply station, the basic specification of a total system, and the remote control system of the station were studied and established. R and D themes in the future were also presented. (NEDO)

Gas markets and security of supply

International Nuclear Information System (INIS)

Gibot, G.

1997-01-01

In the natural gas business, some European states and companies seem to be concerned by security of supply. Security of supply for a governmental organisation is discussed, to share the author's conception and experience. The targets of a security of supply policy and the measures that can be set are described. The possible changes in implementing this policy are considered, according to recent developments in the field of gas security. The specificity of European gas markets justify the concern in security of supply, as concluded the Commission and the IEA. The integration of national gas markets in Europe will give new opportunities for managing this security of supply. (R.P.)

Oil and gas. Gas supply under pressure

International Nuclear Information System (INIS)

Forbes, A.

2008-01-01

The latest review of natural gas markets from the International Energy Agency (IEA) paints a picture of growing demand in the face of rising prices, a strengthening link between gas and electricity markets, and a globalising influence from increasingly flexible LNG supplies. But there are growing signs that security of supply is under threat from underinvestment, delays and cost escalation

The challenge of implementing green gas into the gas supply

NARCIS (Netherlands)

Bekkering, Jan

2014-01-01

In order to gain a more mature share in the future energy supply, green gas supply chains face some interesting challenges. In this thesis green gas supply chains, based on codigestion of cow manure and maize, are considered. The produced biogas is upgraded to natural gas quality and injected into

Natural gas supply - a producer's perspective

International Nuclear Information System (INIS)

Papa, M.G.

1994-01-01

The supply of natural gas from the producers standpoint is discussed. The following factors in the marketing demand for natural gas are considered to be important: gas demand is growing, U.S. gas resource base is large, chronic gas bubble has shrunk, and North American supply is more resilient than expected

Natural-gas supply-and-demand problems

International Nuclear Information System (INIS)

Hatamian, H.

1998-01-01

World natural-gas consumption quadrupled in the 30 years from 1966 to 1996, and natural gas now provides 22% of the total world energy demand. The security of natural-gas supply is paramount and rests with the suppliers and the consumers. This paper gives an overview of world natural-gas supply and demand and examines the main supply problems. The most important nonpredictable variables in natural-gas supply are worldwide gas price and political stability, particularly in regions with high reserves. Other important considerations are the cost of development/processing and the transport of natural gas to market, which can be difficult to maintain if pipelines pass through areas of political instability. Another problem is that many countries lack the infrastructure and capital for effective development of their natural-gas industry. Unlike oil, the cost of transportation of natural gas is very high, and, surprisingly, only approximately 16% of the total world production currently is traded internationally

BC gas takes new approach to gas supply optimization

International Nuclear Information System (INIS)

Cawdery, J.; Swoveland, C.

1992-01-01

Wide-ranging changes have taken place in the US and Canada since the mid-1980s in the way that local gas distribution utilities and large industrial customers contract for their gas supplies. This paper reports that these changes have been brought about by open-access policies, the intent of which was to allow customers more latitude to make their gas purchase and transportation arrangements and to improve the access of shippers to available gas transmission capacity. The effects of the new open-access regime have been profound on both sides of the border. More than 70% of North American gas supplies are now sold under unbundled arrangements in which gas supply is contracted under separate commodity and transportation agreements. For local distribution utilities, the numbers of potential supply options have become extremely large. Analysis of these options has become increasingly complex with the need to take account of complicated contract provisions, a wider range of storage options and swap arrangements with other utilities, opportunities for some customers to purchase gas directly and uncertainty about future demand, prices and supplier reliability

46 CFR 197.340 - Breathing gas supply.

Science.gov (United States)

2010-10-01

... 46 Shipping 7 2010-10-01 2010-10-01 false Breathing gas supply. 197.340 Section 197.340 Shipping... GENERAL PROVISIONS Commercial Diving Operations Equipment § 197.340 Breathing gas supply. (a) A primary breathing gas supply for surface-supplied diving must be sufficient to support the following for the...

Gas engine driven freon-free heat supply system complying with multiple fuels (eco-energy city project)

Energy Technology Data Exchange (ETDEWEB)

Yagyu, Sumio; Maekawa, Koich; Sugawara, Koich; Hayashida, Masaru; Fujishima, Ichiro; Fukuyama, Yuji; Morikawa, Tomoyuki; Yamato, Tadao; Obata, Norio [Advanced Technology Lab., Kubota Corp., Amagasaki, Hyogo (Japan)

1999-07-01

This paper describes recent results at Kubota to develop a gas engine driven freon-free heat supply system. Utilizing a gas mixture which consists of CO and H{sub 2} supplied from a broad area energy utilization network, the system produces four heat sources (263 K, 280 K, 318 K, and 353 K) for air-conditioning, hot water supply, and refrigeration in a single system. It also conforms to fuel systems that utilize methane and hydrogen. This multi-functional heat supply system is composed of an efficient gas engine (methanol gas engine) and a freon-free heat pump (heat-assisted Stirling heat pump). The heat-assisted Stirling heat pump is mainly driven by engine shaft power and is partially assisted by thermal power provided by engine exhaust heat. By proportioning the two energy sources to match the characteristics of the driving engine, the heat pump is supplied with the maximum share of the original energy fueling the engine. Developing the system will establish freon-free thermal utilization system technology that satisfies both wide heat demands and various fuel systems. (orig.)

North American natural gas supply dynamics: A focus on U.S. supply

International Nuclear Information System (INIS)

George, R.

1999-01-01

This paper discusses US natural gas supply dynamics in the context of the North American gas marketplace. Supply fundamentals are examined, methodology is briefly presented, regional supply outlooks are discussed. Assumptions, drivers and issues are highlighted. The analysis and outlook indicate that the sizeable North American resource base can be economically developed to supply growing US natural gas requirements. The major incremental supply sources are likely to come from deepwater Gulf of Mexico, Rocky Mountain regions, onshore Texas and imports from Canada. Given this outlook, major business and investment opportunities exist for the gas upstream and midstream sectors despite some short-term challenges

Variable composition hydrogen/natural gas mixtures for increased engine efficiency and decreased emissions

Energy Technology Data Exchange (ETDEWEB)

Sierens, R.; Rosseel, E.

2000-01-01

It is well known that adding hydrogen to natural gas extends the lean limit of combustion and that in this way extremely low emission levels can be obtained: even the equivalent zero emission vehicle (EZEV) requirements can be reached. The emissions reduction is especially important at light engine loads. In this paper results are presented for a GM V8 engine. Natural gas, pure hydrogen and different blends of these two fuels have been tested. The fuel supply system used provides natural gas/hydrogen mixtures in variable proportion, regulated independently of the engine operating condition. The influence of the fuel composition on the engine operating characteristics and exhaust emissions has been examined, mainly but not exclusively for 10 and 20% hydrogen addition. At least 10% hydrogen addition is necessary for a significant improvement in efficiency. Due to the conflicting requirements for low hydrocarbons and low NO{sub x} determining the optimum hythane composition is not straight-forward. For hythane mixtures with a high hydrogen fraction, it is found that a hydrogen content of 80% or less guarantees safe engine operation (no backfire nor knock), whatever the air excess factor. It is shown that to obtain maximum engine efficiency for the whole load range while taking low exhaust emissions into account, the mixture composition should be varied with respect to engine load.

Exergy and thermoeconomic evaluation of hydrogen production from natural gas; Avaliacao exergetica e termo-economica da producao de hidrogenio a partir do gas natural

Energy Technology Data Exchange (ETDEWEB)

Cruz, Flavio Eduardo da [PROMON Engenharia Ltda., Sao Paulo, SP (Brazil); Oliveira Junior, Silvio de [Universidade de Sao Paulo (USP), SP (Brazil). Escola Politecnica

2008-07-01

Some specific processes are required to obtain pure hydrogen and the most usual one is the natural gas reforming, where natural gas reacts with superheated steam producing H{sub 2}, CO, CO{sub 2} and H{sub 2}O. This paper presents exergy and thermoeconomic analysis of a complete hydrogen production unit of a petroleum refinery. The hydrogen production unit analysed in this paper has to supply 550,000 Nm{sup 3} of hydrogen per day to purify diesel oil. Based on a synthesis plant of the hydrogen production unit, the exergy efficiency of each component and of the overall plant are calculated. The hydrogen production cost is determined by means of a thermoeconomic analysis in which the equality cost partition method is employed, including capital and operational costs, in order to determine the production cost of hydrogen and other products of the plant.(author)

Study on introduction scenario of the high temperature gas-cooled reactor hydrogen cogeneration system (GTHTR300C). Part 1

International Nuclear Information System (INIS)

Nishihara, Tetsuo; Takeda, Tetsuaki

2005-09-01

Japan Atomic Energy Research Institute is carrying out the research and development of the high temperature gas-cooled reactor hydrogen cogeneration system (GTHTR300C) aiming at the practical use around 2030. Preconditions of GTHTR300C introduction are the increase of hydrogen demand and the needs of new nuclear power plants. In order to establish the introduction scenario, it should be clarified that the operational status of existing nuclear power plants, the introduction number of fuel cell vehicles as a main user of hydrogen and the capability of hydrogen supply by existing plants. In this report, estimation of the nuclear power plants that will be decommissioned with a high possibility by 2030 and selection of the model district where the GTHTR300C can be introduced as an alternative system are conducted. Then the hydrogen demand and the capability of hydrogen supply in this district are investigated and the hydrogen supply scenario in 2030 is considered. (author)

U.S. gas supply overview

International Nuclear Information System (INIS)

George, R.

1999-01-01

The most recent outlook by Purvin and Gertz regarding the long-term supply potential of oil and gas producing basins in the United States was presented. The role that technology will play in extending their economic reach was also discussed. The focus of this paper was on regional supply, inter regional gas flows and related issues such as pricing. A series of maps depicting production (in Tcf) of various basins in North America showed that the important supply sources are in the deepwater Gulf of Mexico, Rocky Mountains, onshore Texas and Canada. Natural gas pricing from 1990 to 2020 has been forecasted to steadily increase. 1 tab., 11 figs

Impact of hydrogen insertion on vehicular natural gas

Energy Technology Data Exchange (ETDEWEB)

Strangueto, Karina Maretti; Silva, Ennio Peres da [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Fac. of Mechanical Engineering. Energy Dept.], Email: karinakms@fem.unicamp.br

2010-07-01

This article aims to analyze the possibility of insertion of hydrogen in the vehicular natural gas or even the insertion of the hydrogen in the compressed natural gas used in Brazil. For the production of this hydrogen, the spilled turbinable energy from Itaipu would be harnessed. The calculation of production can be extended to other power plants which are close to the natural gas pipelines, where the hydrogen would be introduced. Then, it was analyzed the consumption of natural gas in vehicles in Brazil, the regulation of transportation, the sales of compressed natural gas to fuelling station, the specifications that the piped gas should follow to be sold, and how much hydrogen could be accepted in the mix. (author)

The Influence of Hydrogen Gas on the Measures of Efficiency of Diesel Internal Combustion Engine

Directory of Open Access Journals (Sweden)

Jurgis Latakas

2014-12-01

Full Text Available In this research paper energy and ecological parameters of diesel engine which works under addition of hydrogen (10, 20, 30 l/ min are presented. A survey of research literature has shown that addition of hydrogen gases improve diesel combustion; increase indicated pressure; decrease concentration of carbon dioxide (CO2, hydrocarbons (HC, particles; decrease fuel consumptions. Results of the experiment revealed that hydrogen gas additive decreased pressure in cylinder in kinetic combustion phase. Concentration of CO2 and nitrous oxides (NOx decreased not significantly, HC – increased. Concentration of particles in engine exhaust gases significantly decreased. In case when hydrogen gas as additive was supplied, the fuel consumptions decreased a little. Using AVL BOOST software combustion process analysis was made. It was determined that in order to optimize engine work process under hydrogen additive usage, it is necessary to adjust diesel injection angle.

Gas supplies of interstate natural gas pipeline companies 1990

International Nuclear Information System (INIS)

1992-01-01

This publication provides information on the interstate pipeline companies' supply of natural gas in the United States during calendar year 1990, for use by the Federal Energy Regulatory Commission for regulatory purposes. It also provides information to other Government agencies, the natural gas industry, as well as policy makers, analysts, and consumers interested in current levels of interstate supplies of natural gas and trends over recent years

Gas-chromatographic separation of hydrogen isotopic mixtures

International Nuclear Information System (INIS)

Preda, Anisoara; Bidica, Nicolae

2005-01-01

Full text: Gas chromatographic separation of hydrogen isotopes have been reported in the literature since late of 1950's. Gas chromatography is primarily an analytical method, but because of its properties it may be used in many other fields with excellent results. A simple method is proposed for the gas-chromatographic analysis of complex gas mixtures containing hydrogen isotopes; the method is based on the substantial difference in the thermal conductivity of these isotopes. One of the main disadvantages of the conventional gas chromatography is the long retention times required for the analysis of hydrogen gas mixtures while the column is operated at very low temperature. The method described in this paper was based on using a capillary molecular sieve 5A column operated for this kind of separation at 173 K. The carrier gas was Ne and the detector was TCD. In the paper chromatograms for various carrier flow rates and various hydrogen isotope mixtures are presented. (authors)

WATER-GAS SHIFT WITH INTEGRATED HYDROGEN SEPARATION; A

International Nuclear Information System (INIS)

Maria Flytzani-Stephanopoulos; Jerry Meldon; Xiaomei Qi

2001-01-01

Optimization of the water-gas shift (WGS) reaction system for hydrogen production for fuel cells is of particular interest to the energy industry. To this end, it is desirable to couple the WGS reaction to hydrogen separation using a semi-permeable membrane, with both processes carried out at high temperature to improve reaction kinetics. Reduced equilibrium conversion of the WGS reaction at high temperatures is overcome by product H(sub 2) removal via the membrane. This project involves fundamental research and development of novel cerium oxide-based catalysts for the water-gas-shift reaction and the integration of these catalysts with Pd-alloy H(sub 2)-separation membranes supplying high purity hydrogen for fuel cell use. Conditions matching the requirements of coal gasifier-exit gas streams will be examined in the project. In the first year of the project, we prepared a series of nanostructured Cu- and Fe-containing ceria catalysts by a special gelation/precipitation technique followed by air calcination at 650 C. Each sample was characterized by ICP for elemental composition analysis, BET-N2 desorption for surface area measurement, and by temperature-programmed reduction in H(sub 2) to evaluate catalyst reducibility. Screening WGS tests with catalyst powders were conducted in a flow microreactor at temperatures in the range of 200-550 C. On the basis of both activity and stability of catalysts in simulated coal gas, and in CO(sub 2)-rich gases, a Cu-CeO(sub 2) catalyst formulation was selected for further study in this project. Details from the catalyst development and testing work are given in this report. Also in this report, we present H(sub 2) permeation data collected with unsupported flat membranes of pure Pd and Pd-alloys over a wide temperature window

Gas in Europe: supply

International Nuclear Information System (INIS)

Anon.

1994-01-01

It is predicted that natural gas consumption in western Europe could rise by more than 55% over the next two decades, from 290bn cubic metres (cm) in 1991 to 450bn cm in 2010. This growth, projected by the consultants, Arthur D Little, reflects the environmental and economic attractions of natural gas, particularly in the power generation sector. Another consultant, Poten and Partners, predicts an even greater rise in gas consumption, from 301bn cm in 1992 to 482 bn cm in 2010. However, while demand is forecast to increase in all major European gas markets, indigenous production within Europe is expected to remain stable for the foreseeable future, with indigenous supplies projected to peak at approximately 350bn cubic metres per year (cm/y) in the late 1990s. This raises the prospect of significant supply constraints emerging in Europe. (author)

Seasonal storage and alternative carriers: A flexible hydrogen supply chain model

International Nuclear Information System (INIS)

Reuß, M.; Grube, T.; Robinius, M.; Preuster, P.; Wasserscheid, P.; Stolten, D.

2017-01-01

Highlights: •Techno-economic model of future hydrogen supply chains. •Implementation of liquid organic hydrogen carriers into a hydrogen mobility analysis. •Consideration of large-scale seasonal storage for fluctuating renewable hydrogen production. •Implementation of different technologies for hydrogen storage and transportation. -- Abstract: A viable hydrogen infrastructure is one of the main challenges for fuel cells in mobile applications. Several studies have investigated the most cost-efficient hydrogen supply chain structure, with a focus on hydrogen transportation. However, supply chain models based on hydrogen produced by electrolysis require additional seasonal hydrogen storage capacity to close the gap between fluctuation in renewable generation from surplus electricity and fuelling station demand. To address this issue, we developed a model that draws on and extends approaches in the literature with respect to long-term storage. Thus, we analyse Liquid Organic Hydrogen Carriers (LOHC) and show their potential impact on future hydrogen mobility. We demonstrate that LOHC-based pathways are highly promising especially for smaller-scale hydrogen demand and if storage in salt caverns remains uncompetitive, but emit more greenhouse gases (GHG) than other gaseous or hydrogen ones. Liquid hydrogen as a seasonal storage medium offers no advantage compared to LOHC or cavern storage since lower electricity prices for flexible operation cannot balance the investment costs of liquefaction plants. A well-to-wheel analysis indicates that all investigated pathways have less than 30% GHG-emissions compared to conventional fossil fuel pathways within a European framework.

BIG hydrogen: hydrogen technology in the oil and gas sector

International Nuclear Information System (INIS)

2006-01-01

The BIG Hydrogen workshop was held in Calgary, Alberta, Canada on February 13, 2006. About 60 representatives of industry, academia and government attended this one-day technical meeting on hydrogen production for the oil and gas industry. The following themes were identified from the presentations and discussion: the need to find a BIG hydrogen replacement for Steam Methane Reformer (SMR) because of uncertainty regarding cost and availability of natural gas, although given the maturity of SMR process (reliability, known capital cost) how high will H2 prices have to rise?; need for a national strategy to link the near-term and the longer-term hydrogen production requirements, which can take hydrogen from chemical feedstock to energy carrier; and in the near-term Canada should get involved in demonstrations and build expertise in large hydrogen systems including production and carbon capture and sequestration

Analysis of natural gas supply strategies at Fort Drum

International Nuclear Information System (INIS)

Stucky, D.J.; Shankle, S.A.; Anderson, D.M.

1992-07-01

This analysis investigates strategies for Fort Drum to acquire a reliable natural gas supply while reducing its gas supply costs. The purpose of this study is to recommend an optimal supply mix based on the life-cycle costs of each strategy analyzed. In particular, this study is intended to provide initial guidance as to whether or not the building and operating of a propane-air mixing station is a feasible alternative to the current gas acquisition strategy. The analysis proceeded by defining the components of supply (gas purchase, gas transport, supplemental fuel supply); identifying alternative options for each supply component; constructing gas supply strategies from different combinations of the options available for each supply component and calculating the life-cycle costs of each supply strategy under a set of different scenarios reflecting the uncertainty of future events

Adsorption process to recover hydrogen from feed gas mixtures having low hydrogen concentration

Science.gov (United States)

Golden, Timothy Christopher; Weist, Jr., Edward Landis; Hufton, Jeffrey Raymond; Novosat, Paul Anthony

2010-04-13

A process for selectively separating hydrogen from at least one more strongly adsorbable component in a plurality of adsorption beds to produce a hydrogen-rich product gas from a low hydrogen concentration feed with a high recovery rate. Each of the plurality of adsorption beds subjected to a repetitive cycle. The process comprises an adsorption step for producing the hydrogen-rich product from a feed gas mixture comprising 5% to 50% hydrogen, at least two pressure equalization by void space gas withdrawal steps, a provide purge step resulting in a first pressure decrease, a blowdown step resulting in a second pressure decrease, a purge step, at least two pressure equalization by void space gas introduction steps, and a repressurization step. The second pressure decrease is at least 2 times greater than the first pressure decrease.

Indicators of security of natural gas supply in Asia

International Nuclear Information System (INIS)

Cabalu, Helen

2010-01-01

Natural gas has become an increasingly valuable resource and a global commodity. The demand for it has significantly increased. Japan, Korea and Taiwan heavily rely on liquefied natural gas (LNG) imports for their gas supplies from Malaysia, Brunei, Indonesia, Australia and the Middle East. On the other hand, countries like Thailand and Singapore import gas via trans-border pipelines. Gas supply interruptions, volatile gas prices, transportation and distribution bottlenecks, and a growing reliance on imports over longer distances have renewed interest on gas security in Asia. This paper examines the relative vulnerability to natural gas supply disruptions of seven gas-importing countries in Asia for year 2008. Based on four indicators of security of gas supply, a composite gas supply security index is estimated as an overall indication of gas vulnerability for our sample countries. The results demonstrate that there are differences in the values of the overall indicator of gas vulnerability among countries and the assessment is useful in developing an effective strategy of natural gas supply security in countries in the Asian region. (author)

Application of gas chromatography in hydrogen isotope separation

International Nuclear Information System (INIS)

Ye Xiaoqiu; Sang Ge; Peng Lixia; Xue Yan; Cao Wei

2008-01-01

The principle of gas chromatographic separation of hydrogen isotopes was briefly introduced. The main technology and their development of separating hydrogen isotopes, including elution chromatography, hydrogen-displacement chromatography, self-displacement chromatography and frontal chromatography were discussed in detail. The prospect of hydrogen isotope separation by gas chromatography was presented. (authors)

Life cycle assessment of hydrogen production from S-I thermochemical process coupled to a high temperature gas reactor

Energy Technology Data Exchange (ETDEWEB)

Giraldi, M. R.; Francois, J. L.; Castro-Uriegas, D. [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac No. 8532, Col. Progreso, C.P. 62550, Jiutepec, Morelos (Mexico)

2012-07-01

The purpose of this paper is to quantify the greenhouse gas (GHG) emissions associated to the hydrogen produced by the sulfur-iodine thermochemical process, coupled to a high temperature nuclear reactor, and to compare the results with other life cycle analysis (LCA) studies on hydrogen production technologies, both conventional and emerging. The LCA tool was used to quantify the impacts associated with climate change. The product system was defined by the following steps: (i) extraction and manufacturing of raw materials (upstream flows), (U) external energy supplied to the system, (iii) nuclear power plant, and (iv) hydrogen production plant. Particular attention was focused to those processes where there was limited information from literature about inventory data, as the TRISO fuel manufacture, and the production of iodine. The results show that the electric power, supplied to the hydrogen plant, is a sensitive parameter for GHG emissions. When the nuclear power plant supplied the electrical power, low GHG emissions were obtained. These results improve those reported by conventional hydrogen production methods, such as steam reforming. (authors)

Harvesting and redistributing renewable energy: on the role of gas and electricity grids to overcome intermittency through the generation and storage of hydrogen

International Nuclear Information System (INIS)

Anderson, Dennis; Leach, Matthew

2004-01-01

If intermittent renewable energy technologies such as those based on solar, wind, wave and tidal resources are eventually to supply significant shares of total energy supplies, it is crucial that the energy storage problem is solved. There are several (long-recognised) possibilities ahead including compressed air, pumped storage, further developments in batteries, regenerable fuel cells, 'super-capacitors' and so forth. But one that is being revisited extensively by industry and research establishments is the production and storage of hydrogen from electricity at off-peak times, and in times when there would be a surplus of renewable energy, for reuse in the electricity, gas and transport markets; short-term and even seasonal and longer-term storage is technically feasible with this option. This paper looks at the costs of the option both in the near-term and the long-term relative to the current costs of electricity and natural gas supplies. While the costs of hydrogen would necessarily be greater than those of natural gas (though not disruptively so), when used in conjunction with emerging technologies for decentralised generation and combined heat and power there is scope for appreciable economies in electricity supply. A lot will depend on innovation at the systems level, and on how we operate our electricity and gas grids and regulate our electricity and gas industries. We have also suggested that we now need to experiment more, at the commercial level, and in the laboratories, with the hydrogen option

Internal dosimetry of tritiated hydrogen gas

International Nuclear Information System (INIS)

Peterman, B.F.; Johnson, J.R.; Dunford, D.W.; McElroy, R.G.C.

1985-02-01

This document is a report on experiments to quantify the doses that may occur from the tritium gas that is converted 'in vivo' to tritiated water following the exposure to tritiated hydrogen gas contaminated air. This report also includes theoretical evaluation of the radiological hazards from the uptake through skin of tritium from tritiated hydrogen adsorbed on surfaces

Role of stranded gas in increasing global gas supplies

Science.gov (United States)

Attanasi, E.D.; Freeman, P.A.

2013-01-01

This report synthesizes the findings of three regional studies in order to evaluate, at the global scale, the contribution that stranded gas resources can make to global natural gas supplies. Stranded gas, as defined for this study, is natural gas in discovered conventional gas and oil fields that is currently not commercially producible for either physical or economic reasons. The regional studies evaluated the cost of bringing the large volumes of undeveloped gas in stranded gas fields to selected markets. In particular, stranded gas fields of selected Atlantic Basin countries, north Africa, Russia, and central Asia are screened to determine whether the volumes are sufficient to meet Europe’s increasing demand for gas imports. Stranded gas fields in Russia, central Asia, Southeast Asia, and Australia are also screened to estimate development, production, and transport costs and corresponding gas volumes that could be supplied to Asian markets in China, India, Japan, and South Korea. The data and cost analysis presented here suggest that for the European market and the markets examined in Asia, the development of stranded gas provides a way to meet projected gas import demands for the 2020-to-2040 period. Although this is a reconnaissance-type appraisal, it is based on volumes of gas that are associated with individual identified fields. Individual field data were carefully examined. Some fields were not evaluated because current technology was insufficient or it appeared the gas was likely to be held off the export market. Most of the evaluated stranded gas can be produced and delivered to markets at costs comparable to historical prices. Moreover, the associated volumes of gas are sufficient to provide an interim supply while additional technologies are developed to unlock gas diffused in shale and hydrates or while countries transition to making a greater use of renewable energy sources.

North American natural gas supply and demand

International Nuclear Information System (INIS)

Goobie, G.

2006-01-01

This presentation was given by leading energy analysts Pervin and Gertz, and provided their outlook on the North American natural gas supply and demand as well as transportation and processing options for the Mackenzie Valley project and the Alaska natural gas project. Arctic gas development was discussed in relation to larger North American and world energy markets. The impacts of liquefied natural gas (LNG) infrastructure development were compared with the potential impacts of the Alaska and Mackenzie Valley pipelines. A review of North American gas supplies was presented. LNG imports to the United States are expected to exceed 8 BCF/D by 2010. In addition, huge growth in the LNG markets is expected in middle eastern countries as well as in Africa. There is currently strong growth in liquefaction capacity in most regions. However, many proposed LNG terminals will not proceed due to opposition on the west coast of North America. It is also expected that natural gas liquids (NGL) delivered to Alberta from the Mackenzie Valley Gas project are expected to be used by the heavy oil industry. Canadian crude supplies are expected to grow to nearly 4 million barrels per day by 2015. The impacts of Alaska and Mackenzie Valley gas projects on western NGL markets and the petrochemicals industry were reviewed. It was concluded that major investments in supply and infrastructure are need in order to develop Arctic gas, as LNG is likely to be the largest source of incremental supply. tabs., figs

Feasibility study of hydrogen determination in blended gas mixture by an indigenously developed hydrogen determinator

International Nuclear Information System (INIS)

Gaikwad, Revati; Sonar, V.R.; Pandey, R.K.; Karekar, C.D.; Raul, Seema; Mahanty, B.; Kelkar, A.; Bhatt, R.B.; Behere, P.G.

2017-01-01

It is required to determine accurately the percentage composition of hydrogen in the blended gas of N 2 and H 2 prior to deliver to the sintering furnace. A feasibility study has been carried out to determine the percentage composition of hydrogen in the blended gas by using an indigenously developed hydrogen determinator. The instrument uses gas chromatograph-thermal conductivity (GC-TCD) technique to determine hydrogen. The flow of carrier gas was kept at 100 mL min -1 during the analysis. A very close agreement between the determined value and the reported value of hydrogen content in the commercially available N 2 -H 2 mixed cylinder was found by using the indigenous hydrogen determinator. (author)

Impacts of seasonality on hydrogen production using natural gas pressure letdown stations. Paper no. IGEC-1-083

International Nuclear Information System (INIS)

Maddaloni, J.; Rowe, A.; Bailey, R.; McDonald, D.

2005-01-01

One of the difficulties associated with the development of a hydrogen economy is the creation of a supply infrastructure. A means for distributed hydrogen generation through a process using the exergy in high pressure natural gas streams has been proposed. The system recovers energy via expansion of natural gas through a turbo-expander at existing pressure reduction systems. Generated electric power is then used to drive an electrolyzer and create hydrogen. A model of the process is used to determine production rates for electricity and hydrogen given flow data for a number of pressure letdown sites in BC. Like many traditional renewable energy sources, most letdown stations have strong annual variations in flow conditions. Annual variations in stream flow rate, inlet pressure and inlet temperature can greatly affect hydrogen production rates. In the model, component efficiencies are scaled for operation at part-load, or away from optimum design conditions. Results indicate a significant reduction in predicted hydrogen production rates as compared to installed component name-plate capacity. Operating the system with a 'grid-tie' can increase the capacity factor, but economic viability will depend on local electricity and natural gas prices. (author)

Power to gas. The final breakthrough for the hydrogen economy?

Energy Technology Data Exchange (ETDEWEB)

Winkler-Goldstein, Raphael [Germany Trade and Invest (GTAI), Paris (France); Rastetter, Aline [Alphea Hydrogene, Forbach (France)

2013-04-01

In Germany more than 20% of the energy mix is made up of renewable energy and its share is rapidly increasing. The federal government expects renewables to account for 35% of Germany's electricity consumption by 2020, 50% by 2030 and 80% by 2050. According to the German Energy Agency, multi-billion euro investments in energy storage are expected by 2020 in order to reach these goals. The growth of this fluctuating energy supply has created demand for innovative storage options in Germany and it is accelerating the development of technologies in this field. Along with batteries and smart grids, hydrogen is expected to be one of the lead technologies. 2010 a commercialization roadmap for wind hydrogen was set up by the two northern federal states of Hamburg and Schleswig-Holstein with the goal of utilizing surplus wind power for the electrolytic production of hydrogen. With the creation of the 'performing energy initiative', 2011, Brandenburg and Lower Saxony joined this undertaking. The aim of this initiative is to set up demonstration projects in order to develop and optimize wind-hydrogen hybrid systems and prepare their commercialization for the time after 2020. Beside the conversion of hydrogen into electricity and fuel for cars, further markets like raw material for the chemical, petrochemical, metallurgy and food industry are going to be addressed. Considering the fact there are over 40 caves currently used for natural gas storage with a total volume of 23.5 billion cubic meters and 400 000 km gas grid available in Germany, the German Technical and Scientific Association for Gas and Water sees opportunities for hydrogen to be fed into the existing natural gas grid network. The name of this concept is power-to-gas. According to the current DVGW-Standards natural gas in Germany can contain up to 5% hydrogen. The GERG, European Group on the Gas Research sees potential to increase this amount up to 6% to 20%. Power-to-gas could serve both for fuel and for the

Hydrogen-Enhanced Natural Gas Vehicle Program

Energy Technology Data Exchange (ETDEWEB)

Hyde, Dan; Collier, Kirk

2009-01-22

The project objective is to demonstrate the viability of HCNG fuel (30 to 50% hydrogen by volume and the remainder natural gas) to reduce emissions from light-duty on-road vehicles with no loss in performance or efficiency. The City of Las Vegas has an interest in alternative fuels and already has an existing hydrogen refueling station. Collier Technologies Inc (CT) supplied the latest design retrofit kits capable of converting nine compressed natural gas (CNG) fueled, light-duty vehicles powered by the Ford 5.4L Triton engine. CT installed the kits on the first two vehicles in Las Vegas, trained personnel at the City of Las Vegas (the City) to perform the additional seven retrofits, and developed materials for allowing other entities to perform these retrofits as well. These vehicles were used in normal service by the City while driver impressions, reliability, fuel efficiency and emissions were documented for a minimum of one year after conversion. This project has shown the efficacy of operating vehicles originally designed to operate on compressed natural gas with HCNG fuel incorporating large quantities of exhaust gas recirculation (EGR). There were no safety issues experienced with these vehicles. The only maintenance issue in the project was some rough idling due to problems with the EGR valve and piping parts. Once the rough idling was corrected no further maintenance issues with these vehicles were experienced. Fuel economy data showed no significant changes after conversion even with the added power provided by the superchargers that were part of the conversions. Driver feedback for the conversions was very favorable. The additional power provided by the HCNG vehicles was greatly appreciated, especially in traffic. The drivability of the HCNG vehicles was considered to be superior by the drivers. Most of the converted vehicles showed zero oxides of nitrogen throughout the life of the project using the State of Nevada emissions station.

Condensation in gas transmission pipelines. Phase behavior of mixtures of hydrogen with natural gas

Energy Technology Data Exchange (ETDEWEB)

Schouten, J.A.; Michels, J.P.J. [Amsterdam Univ. (Netherlands). Van der Waals-Zeeman Inst.; Rosmalen, R.J. van [Energy, Roden (Netherlands)

2005-05-01

Several pressure and temperature reductions occur along gas transmission lines. Since the pressure and temperature conditions of the natural gas in the pipeline are often close to the dew point curve, liquid dropout can occur. Injection of hydrogen into the natural gas will change the phase envelope and thus the liquid dropout. This condensation of the heavy hydrocarbons requires continuous operational attention and a positive effect of hydrogen may affect the decision to introduce hydrogen. In this paper we report on calculations of the amount of condensate in a natural gas and in this natural gas mixed with 16.7% hydrogen. These calculations have been performed at conditions prevailing in gas transport lines. The results will be used to discuss the difference in liquid dropout in a natural gas and in a mixture with hydrogen at pressure reduction stations, at crossings under waterways, at side-branching, and at separators in the pipelines. (author)

Outlook for Noth American natural gas supplies

International Nuclear Information System (INIS)

Kuuskraa, V.A.

1995-01-01

The underlying resource base for North America natural gas is large, sufficient for nearly 100 years of current consumption. As such, the issues are not the size of the resource, but how to convert this resource into economically competitive supply. The key questions are: Will the cost (price) of natural gas remain competitive? What is the status of near-term deliverability? Will there be enough supply to meet growing demand? These economic and market issues frame the outlook for gas supplies in North America. Most importantly, they will determine how natural gas emerges from its competition for markets with other fuels and electricity. The paper addresses these questions by examining: (1) the underlying nature of the natural gas resource base; (2) the current status and trends in deliverability; and, (3) the potential of new technologies for producing gas more cost-effectively. (author)

Low-cost storage options for solar hydrogen systems for remote area power supply

International Nuclear Information System (INIS)

Suhaib Muhammad Ali; John Andrews

2006-01-01

Equipment for storing hydrogen gas under pressure typically accounts for a significant proportion of the total capital cost of solar-hydrogen systems for remote area power supply (RAPS). RAPS remain a potential early market for renewable energy - hydrogen systems because of the relatively high costs of conventional energy sources in remote regions. In the present paper the storage requirements of PV-based solar-hydrogen RAPS systems employing PEM electrolysers and fuel cells to meet a range of typical remote area daily and annual demand profiles are investigated using a spread sheet-based simulation model. It is found that as the costs of storage are lowered the requirement for longer-term storage from summer to winter is increased with consequent potential gains in the overall economics of the solar-hydrogen system. In many remote applications, there is ample space for hydrogen storages with relatively large volumes. Hence it may be most cost-effective to store hydrogen at low to medium pressures achievable by using PEM electrolysers directly to generate the hydrogen at the pressures required, without a requirement for separate electrically-driven compressors. The latter add to system costs while requiring significant parasitic electricity consumption. Experimental investigations into a number of low-cost storage options including plastic tanks and low-to-medium pressure metal and composite cylinders are reported. On the basis of these findings, the economics of solar-hydrogen RAPS systems employing large-volume low-cost storage are investigated. (authors)

Operational modeling of a sustainable gas supply chain

NARCIS (Netherlands)

Bekkering, Jan; Broekhuis, A. A.; van Gemert, Wim

2010-01-01

Biogas production from codigestion of cattle manure and biomass can have a significant contribution to a sustainable gas supply when this gas is upgraded to specifications prescribed for injection into the national gas grid and injected into this grid. In this study, we analyzed such a gas supply

Greenhouse gas reduction benefits and costs of a large-scale transition to hydrogen in the USA

International Nuclear Information System (INIS)

Dougherty, William; Kartha, Sivan; Lazarus, Michael; Fencl, Amanda; Rajan, Chella; Bailie, Alison; Runkle, Benjamin

2009-01-01

Hydrogen is an energy carrier able to be produced from domestic, zero-carbon sources and consumed by zero-pollution devices. A transition to a hydrogen-based economy could therefore potentially respond to climate, air quality, and energy security concerns. In a hydrogen economy, both mobile and stationary energy needs could be met through the reaction of hydrogen (H 2 ) with oxygen (O 2 ). This study applies a full fuel cycle approach to quantify the energy, greenhouse gas emissions (GHGs), and cost implications associated with a large transition to hydrogen in the United States. It explores a national and four metropolitan area transitions in two contrasting policy contexts: a 'business-as-usual' (BAU) context with continued reliance on fossil fuels, and a 'GHG-constrained' context with policies aimed at reducing greenhouse gas emissions. A transition in either policy context faces serious challenges, foremost among them from the highly inertial investments over the past century or so in technology and infrastructure based on petroleum, natural gas, and coal. A hydrogen transition in the USA could contribute to an effective response to climate change by helping to achieve deep reductions in GHG emissions by mid-century across all sectors of the economy; however, these reductions depend on the use of hydrogen to exploit clean, zero-carbon energy supply options. (author)

Greenhouse gas reduction benefits and costs of a large-scale transition to hydrogen in the USA

Energy Technology Data Exchange (ETDEWEB)

Dougherty, William; Kartha, Sivan; Lazarus, Michael; Fencl, Amanda [Stockholm Environment Institute - US Center, 11 Curtis Avenue, Somerville, MA 02143 (United States); Rajan, Chella [Indian Institute of Technology Madras, I.I.T. Post Office, Chennai 600 036 (India); Bailie, Alison [The Pembina Institute, 200, 608 - 7th Street, S.W. Calgary, AB (Canada); Runkle, Benjamin [Department of Civil and Environmental Engineering, University of California, Berkeley, CA 94720 (United States)

2009-01-15

Hydrogen is an energy carrier able to be produced from domestic, zero-carbon sources and consumed by zero-pollution devices. A transition to a hydrogen-based economy could therefore potentially respond to climate, air quality, and energy security concerns. In a hydrogen economy, both mobile and stationary energy needs could be met through the reaction of hydrogen (H{sub 2}) with oxygen (O{sub 2}). This study applies a full fuel cycle approach to quantify the energy, greenhouse gas emissions (GHGs), and cost implications associated with a large transition to hydrogen in the United States. It explores a national and four metropolitan area transitions in two contrasting policy contexts: a 'business-as-usual' (BAU) context with continued reliance on fossil fuels, and a 'GHG-constrained' context with policies aimed at reducing greenhouse gas emissions. A transition in either policy context faces serious challenges, foremost among them from the highly inertial investments over the past century or so in technology and infrastructure based on petroleum, natural gas, and coal. A hydrogen transition in the USA could contribute to an effective response to climate change by helping to achieve deep reductions in GHG emissions by mid-century across all sectors of the economy; however, these reductions depend on the use of hydrogen to exploit clean, zero-carbon energy supply options. (author)

Potential of the HTGR hydrogen cogeneration system in Japan

International Nuclear Information System (INIS)

Nishihara, Tetsuo; Mouri, Tomoaki; Kunitomi, Kazuhiko

2007-01-01

A high temperature gas cooled reactor (HTGR) is one of the next generation nuclear systems. The HTGR hydrogen cogeneration system can produce not only electricity but also hydrogen. Then it has a potential to supply massive low-cost hydrogen without greenhouse gas emission for the future hydrogen society. Japan Atomic Energy Agency (JAEA) has been carried out the design study of the HTGR hydrogen cogeneration system (GTHTR300C). The thermal power of the reactor is 600 MW. The hydrogen production plant utilizes 370 MW and can supply 52,000 m 3 /h (0.4 Bm 3 /y) of hydrogen. Present industrial hydrogen production capacity in Japan is about 18 Bm 3 /y and it will decrease by 15 Bm 3 /y in 2030 due to the aging facilities. On the other hand, the hydrogen demand for fuel cell vehicle (FCV) in 2030 is estimated at 15 Bm 3 /y at a maximum. Since the hydrogen supply may be short after 2030, the additional hydrogen should be produced by clean hydrogen process to reduce greenhouse gas emission. This hydrogen shortage is a potential market for the GTHTR300C. The hydrogen production cost of GTHTR300C is estimated at 20.5 JPY/Nm 3 which has an economic competitiveness against other industrial hydrogen production processes. 38 units of the GTHTR300C can supply a half of this shortage which accounts for the 33% of hydrogen demand for FCV in 2100. According to the increase of hydrogen demand, the GTHTR300C should be constructed after 2030. (author)

Hydrogen separation membranes annual report for FY 2010.

Energy Technology Data Exchange (ETDEWEB)

Balachandran, U.; Dorris, S. E; Emerson, J. E.; Lee, T. H.; Lu, Y.; Park, C. Y.; Picciolo, J. J. (Energy Systems)

2011-03-14

The objective of this work is to develop dense ceramic membranes for separating hydrogen from other gaseous components in a nongalvanic mode, i.e., without using an external power supply or electrical circuitry. The goal of this project is to develop dense hydrogen transport membranes (HTMs) that nongalvanically (i.e., without electrodes or external power supply) separate hydrogen from gas mixtures at commercially significant fluxes under industrially relevant operating conditions. These membranes will be used to separate hydrogen from gas mixtures such as the product streams from coal gasification, methane partial oxidation, and water-gas shift reactions. Potential ancillary uses of HTMs include dehydrogenation and olefin production, as well as hydrogen recovery in petroleum refineries and ammonia synthesis plants, the largest current users of deliberately produced hydrogen. This report describes the results from the development and testing of HTM materials during FY 2010.

Southwest British Columbia natural gas supply and deliverability: Discussion paper

International Nuclear Information System (INIS)

1994-02-01

A review is presented of energy in British Columbia, the role of natural gas, and options available to enhance gas supply security in the province's most densely populated area, the southwest. British Columbia has abundant natural gas supplies, and production exceeds domestic demand. In 1992, natural gas supplied ca 25% of total provincial end-use energy requirements, but this share is expected to rise to 30% by 2015. Although some say that the province's natural gas production and transmission system should serve only domestic needs, this would have significant negative impacts. Domestic gas supply policy allows gas consumers to contract their own supplies, but contract security is required. Provincial guidelines allow demand-side programs to compete with supply sources to ensure that the resource profile is achieved at least cost. In the southwest, natural gas demand is projected to increase from 189 PJ in 1991 to 262 PJ by 2005. Most gas supplied to this region comes from northeast British Columbia through pipelines that are generally fully contracted. Short-term deliverability can be a problem, especially in peak winter demand periods. The gas industry's contingency plans for shortages are outlined and alternatives to enhance deliverability to the southwest are assessed, including storage, expansion of the pipeline system, supply curtailment, and peaking supply contracts. Aspects of provincial natural gas planning are discussed, including security of supply and deliverability, economic and environmental impacts, consumer costs, safety, and the public interest. A least-cost option for enhancing deliverability (underground storage and an additional liquefied natural gas plant) is estimated to cost consumers $3.69/GJ over 20 years. 9 figs., 1 tab

The hydrogen economy - an opportunity for gas

International Nuclear Information System (INIS)

Soederbaum, J.; Martin, G.; O'Neill, C.

2003-01-01

Natural gas could play a pivotal role in any transition to a hydrogen economy-that is one of the findings of the recently-released National Hydrogen Study, commissioned by the Commonwealth Department of Industry, Tourism and Resources, and undertaken by the consulting firms ACIL Tasman and Parsons Brinckerhoff. The key benefits of hydrogen include zero emissions at the point of combustion (water is the main by-product) and its abundance Hydrogen can be produced from a range of primary energy sources including gas and coal, or through the electrolysis of water. Depending on the process used to manufacture hydrogen (especially the extent to which any associated carbon can be captured and sequestered), life-cycle emissions associated with its production and use can be reduced or entirely eliminated

Wingas in natural gas supply in Belgium

International Nuclear Information System (INIS)

2003-01-01

Recently Wingas has become active in the transport and supply of natural gas in Belgium and succeeded in entering contracts for the supply of natural gas which cover 6% of the Belgian market. Wingas is a German-Russian joint venture between BASF-daughter Wintershall and OAO Gasprom [nl

Tritium removal by hydrogen isotopic exchange between hydrogen gas and water on hydrophobic catalyst

International Nuclear Information System (INIS)

Morishita, T.; Isomura, S.; Izawa, H.; Nakane, R.

1980-01-01

Many kinds of the hydrophobic catalysts for hydrogen isotopic exchange between hydrogen gas and water have been prepared. The carriers are the hydrophobic organic materials such as polytetrafluoroethylene(PTFE), monofluorocarbon-PTFE mixture(PTFE-FC), and styrene-divinylbenzene copolymer(SDB). 0.1 to 2 wt % Pt is deposited on the carriers. The Pt/SDB catalyst has much higher activity than the Pt/PTFE catalyst and the Pt/PTFE-FC catalyst shows the intermediate value of catalytic activity. The observation of electron microscope shows that the degrees of dispersion of Pt particles on the hydrophobic carriers result in the difference of catalytic activities. A gas-liquid separated type column containing ten stages is constructed. Each stage is composed of both the hydrophobic catalyst bed for the hydrogen gas/water vapor isotopic exchange and the packed column type bed for the water vapor/liquid water isotopic exchange. In the column hydrogen gas and water flow countercurrently and hydrogen isotopes are separated

Gas supplies of interstate natural gas pipeline companies, 1991

International Nuclear Information System (INIS)

1992-01-01

This publication provides information on the total reserves, production, and deliverability capabilities of the 64 interstate pipeline companies required to file the Federal Energy Regulatory Commission (FERC) Form 15, ''Interstate Pipeline's Annual Report of Gas Supply.'' Data reported on this form are not considered to be confidential. This publication is the 29th in a series of annual reports on the total gas supplies of interstate pipeline companies since the inception of individual company reports to the Federal Power Commission (FPC) in 1964 for report year 1963

Mackenzie Gas Project : gas resource and supply study

International Nuclear Information System (INIS)

Harris, D.G.; Braaten, K.M.

2004-01-01

A study was conducted to assess the future gas supply for the Mackenzie Gas Project. The economically recoverable gas resources and deliverability in the region were assessed in order to support construction of the Mackenzie Valley pipeline and the associated gathering system. This supply study was based on a 25 year timeframe for resource development. Production forecasts were also prepared for 50 years following the date of the study. Natural gas forecasts for the general area to be served by the proposed pipeline were also presented. This report includes an introduction to the final gas resource and supply study as well as the regional geology relating to discovered and undiscovered resources. The following regions were included in the study area: onshore Mackenzie Delta including the Niglintgak, Parsons Lake and Taglu anchor fields; central Mackenzie Valley region extending from the Mackenzie Delta south to 63 degrees latitude; northern portion of the Yukon Territory; and, portions of the offshore Mackenzie Delta region limited to a water depth of 30 metres. Forecasts and economic analyses were prepared for the following 3 scenarios: contingent onshore resources only; contingent and prospective onshore resources; and, contingent and prospective onshore and offshore resources. Sensitivity forecasts were prepared for a fully expanded pipeline capacity of 1.8 bcf/day with an equal capacity gathering system. In addition, the National Energy Board estimates of resources for the 3 anchor field were used in place of the operator's estimates. A geological review was included for the plays in the study area. 15 refs., 43 tabs., 38 figs

Canadian gas supply : an update

International Nuclear Information System (INIS)

Rochefort, T.

1998-01-01

An overview of the daily production from the Western Canada Sedimentary Basin (WCSB) from 1986 to 1997 was presented. This presentation also outlined Canadian production trends, Canadian reserves and resources, and supply challenges. Ultimate conventional marketable gas from the WCSB, the Scotian Shelf, the Beaufort Sea and Canada's Arctic region was estimated at 591 TCF. Issues regarding supply and demand of natural gas such as the impact of electricity restructuring on pricing, generation fuel mix, the capacity of the U.S. market to absorb Canadian heavy oil production, and the influence of the rate of technological advances on supply and demand were outlined. The overall conclusion confirmed the health and competitiveness of the Canadian upstream sector and expressed confidence that the WCSB can support rising levels of production to meet the expected continued market growth. tabs., figs

Clean energy and the hydrogen economy.

Science.gov (United States)

Brandon, N P; Kurban, Z

2017-07-28

In recent years, new-found interest in the hydrogen economy from both industry and academia has helped to shed light on its potential. Hydrogen can enable an energy revolution by providing much needed flexibility in renewable energy systems. As a clean energy carrier, hydrogen offers a range of benefits for simultaneously decarbonizing the transport, residential, commercial and industrial sectors. Hydrogen is shown here to have synergies with other low-carbon alternatives, and can enable a more cost-effective transition to de-carbonized and cleaner energy systems. This paper presents the opportunities for the use of hydrogen in key sectors of the economy and identifies the benefits and challenges within the hydrogen supply chain for power-to-gas, power-to-power and gas-to-gas supply pathways. While industry players have already started the market introduction of hydrogen fuel cell systems, including fuel cell electric vehicles and micro-combined heat and power devices, the use of hydrogen at grid scale requires the challenges of clean hydrogen production, bulk storage and distribution to be resolved. Ultimately, greater government support, in partnership with industry and academia, is still needed to realize hydrogen's potential across all economic sectors.This article is part of the themed issue 'The challenges of hydrogen and metals'. © 2017 The Author(s).

Gas supply and Yorkshire Electricity

Energy Technology Data Exchange (ETDEWEB)

Anon.

1995-04-01

Yorkshire Electricity, among other independent suppliers of gas, now competes for a share of the United Kingdom gas market, previously monopolised by British Gas. The experience of this successful electric utility company, expanding into the industrial and domestic gas supply market is described in the article. The company`s involvement stems partly from the fact that significant volumes of gas are landed at three terminals within its franchise area. The company will also seek to use subsidaries to generate electric power from gas turbine power plants and explore the possibilities of developing combined heat and power (CHP) plants where appropriate. (UK)

Two-stage coal liquefaction without gas-phase hydrogen

Science.gov (United States)

Stephens, H.P.

1986-06-05

A process is provided for the production of a hydrogen-donor solvent useful in the liquefaction of coal, wherein the water-gas shift reaction is used to produce hydrogen while simultaneously hydrogenating a donor solvent. A process for the liquefaction of coal using said solvent is also provided. The process enables avoiding the use of a separate water-gas shift reactor as well as high pressure equipment for liquefaction. 3 tabs.

Canadian gas supply: going up? or down?

International Nuclear Information System (INIS)

Woronuk, R. H.

1999-01-01

With regard to Canada's gas reserves there are clear indications that the gas market is moving from a supply/demand balance controlled by demand to one that is controlled by supply. There is evidence of a recognition that the Western Canadian Sedimentary Basin (WCSB) , the source of most of Canada's gas supply is a mature basin, with over half of its reserves already discovered, that consumption has exceeded reserve additions for all but one of the last sixteen years, and that under these conditions consumption cannot grow, or even be maintained indefinitely. The central argument advanced in this paper is that the era of ever increasing production from the WCSB is nearing its end and that a more aggressive approach to exploration and development in the WCSB, especially in the deeper and more environmentally sensitive areas, together with the exploitation of conventional gas in frontier areas and unconventional resources will be necessary to prevent projected declines in supply. Identification of new geological plays, exploration for and connection of reserves from frontier regions and the development of technologies for enhanced recoveries will involve increasingly long lead times, therefore, initiatives to address forthcoming supply issues must begin immediately. 4 refs., 17 figs

Optimisation of a green gas supply chain--a review.

Science.gov (United States)

Bekkering, J; Broekhuis, A A; van Gemert, W J T

2010-01-01

In this review the knowledge status of and future research options on a green gas supply based on biogas production by co-digestion is explored. Applications and developments of the (bio)gas supply in The Netherlands have been considered, whereafter literature research has been done into the several stages from production of dairy cattle manure and biomass to green gas injection into the gas grid. An overview of a green gas supply chain has not been made before. In this study it is concluded that on installation level (micro-level) much practical knowledge is available and on macro-level knowledge about availability of biomass. But on meso-level (operations level of a green gas supply) very little research has been done until now. Future research should include the modeling of a green gas supply chain on an operations level, i.e. questions must be answered as where to build digesters based on availability of biomass. Such a model should also advise on technology of upgrading depending on scale factors. Future research might also give insight in the usability of mixing (partly upgraded) biogas with natural gas. The preconditions for mixing would depend on composition of the gas, the ratio of gases to be mixed and the requirements on the mixture.

Diversification of gas supplies to Romania: options and constraints

International Nuclear Information System (INIS)

Kramer, A.

1996-01-01

The issue of diversifying natural gas supply to Romania gained importance after 1989. Currently, there are several factors which reinforce the need for the diversification: energy consumption structure; ratio of domestic production to import and traditionally strong natural gas industry. The mentioned points lead to the conclusion that ROMGAZ has to integrate further into the European gas market, to diversify sources of supply and to attract foreign investments. It is clear that the supply diversification depends on three crucial factors: economic recovery (partially achieved after 1992); general price stability (ending permanent depreciation of lev against US dollar); and raising natural gas prices to economic levels. Once those factors are in place, the possibility of gas supply diversification would become more tangible

Natural gas supply and demand in Italy

International Nuclear Information System (INIS)

Comaschi, C.; Di Giulio, E.; Sormani, E.

2007-01-01

This article explores the dynamics between natural gas supply and demand in Italy. In order to supply Italy with increasing volumes of gas, several new pipelines and re gasification plants are expected in the next future, but their implementation is uncertain. Thus, there exist the possibility of natural gas shortage in the future. On the other hand, if all the expected projects will be implemented, situations of oversupply cannot be excluded. A system dynamics model deepens such as issue [it

Fueling our future: four steps to a new, reliable, cleaner, decentralized energy supply based on hydrogen and fuel cells

International Nuclear Information System (INIS)

Evers, A.A.

2004-01-01

'Full text:' This manuscript demonstrates the possible driving factors and necessary elements needed to move Hydrogen and Fuel Cells (H2/FC) to worldwide commercialisation. Focusing not only on the technology itself, we look at the 'bigger picture' explaining how certain trends have impacted the progress of new technologies developments in the past. In this process, the consumer has played and will continue to play the key and leading role. We also examine different Distributed Generation scenarios including distributed generation via fuel cells for automotive applications which may be the catalyst to the Hydrogen Economy. One possible step could be the use of Personal Power Cars equipped with Fuel Cells which not only drive on Hydrogen, but also supply (while standing) electricity /heat to residential and commercial buildings. With 1.3 billion potential customers, P.R. China is one country where such a scenario may fit. The up-and-coming Chinese H2/FC industry deals with applied fundamental research such as advances in Hydrogen production from Natural Gas, Methanol and Gasoline. The current activities in P.R. China certain to further accelerate the trend towards the coming Hydrogen Economy, together with the steps necessary to achieve a new reliable, cleaner and decentralized Energy Supply based on H2/FC are examined. (author)

Documentation of the Oil and Gas Supply Module (OGSM)

Energy Technology Data Exchange (ETDEWEB)

NONE

1998-01-01

The purpose of this report is to define the objectives of the Oil and Gas Supply Model (OGSM), to describe the model`s basic approach, and to provide detail on how the model works. This report is intended as a reference document for model analysts, users, and the public. Projected production estimates of US crude oil and natural gas are based on supply functions generated endogenously within National Energy Modeling System (NEMS) by the OGSM. OGSM encompasses domestic crude oil and natural gas supply by both conventional and nonconventional recovery techniques. Nonconventional recovery includes enhanced oil recovery (EOR), and unconventional gas recovery (UGR) from tight gas formations, Devonian/Antrim shale and coalbeds. Crude oil and natural gas projections are further disaggregated by geographic region. OGSM projects US domestic oil and gas supply for six Lower 48 onshore regions, three offshore regions, and Alaska. The general methodology relies on forecasted profitability to determine exploratory and developmental drilling levels for each region and fuel type. These projected drilling levels translate into reserve additions, as well as a modification of the production capacity for each region. OGSM also represents foreign trade in natural gas, imports and exports by entry region. Foreign gas trade may occur via either pipeline (Canada or Mexico), or via transport ships as liquefied natural gas (LNG). These import supply functions are critical elements of any market modeling effort.

Combustible gas concentration control facility and operation method therefor

International Nuclear Information System (INIS)

Yoshikawa, Kazuhiro; Ando, Koji; Kinoshita, Shoichiro; Yamanari, Shozo; Moriya, Kimiaki; Karasawa, Hidetoshi

1998-01-01

The present invention provides a hydrogen gas-control facility by using a fuel battery-type combustible gas concentration reducing device as a countermeasure for controlling a hydrogen gas in a reactor container. Namely, a hydrogen electrode adsorb hydrogen by using an ion exchange membrane comprising hydrogen ions as a charge carrier. An air electrode adsorb oxygen in the air. A fuel battery converts recombining energy of hydrogen and oxygen to electric energy. Hydrogen in this case is supplied from an atmosphere in the container. Oxygen in this case is supplied from the air outside of the container. If hydrogen gas should be generated in the reactor, power generation of is performed by the fuel battery by using hydrogen gas, as a fuel, on the side of the hydrogen electrode of the fuel battery and using oxygen, as a fuel, in the air outside of the container on the side of the air electrode. Then, the hydrogen gas is consumed thereby controlling the hydrogen gas concentration in the container. Electric current generated in the fuel battery is used as an emergency power source for the countermeasure for a severe accident. (I.S.)

Combustible gas concentration control facility and operation method therefor

Energy Technology Data Exchange (ETDEWEB)

Yoshikawa, Kazuhiro; Ando, Koji; Kinoshita, Shoichiro; Yamanari, Shozo; Moriya, Kimiaki; Karasawa, Hidetoshi

1998-09-25

The present invention provides a hydrogen gas-control facility by using a fuel battery-type combustible gas concentration reducing device as a countermeasure for controlling a hydrogen gas in a reactor container. Namely, a hydrogen electrode adsorb hydrogen by using an ion exchange membrane comprising hydrogen ions as a charge carrier. An air electrode adsorb oxygen in the air. A fuel battery converts recombining energy of hydrogen and oxygen to electric energy. Hydrogen in this case is supplied from an atmosphere in the container. Oxygen in this case is supplied from the air outside of the container. If hydrogen gas should be generated in the reactor, power generation of is performed by the fuel battery by using hydrogen gas, as a fuel, on the side of the hydrogen electrode of the fuel battery and using oxygen, as a fuel, in the air outside of the container on the side of the air electrode. Then, the hydrogen gas is consumed thereby controlling the hydrogen gas concentration in the container. Electric current generated in the fuel battery is used as an emergency power source for the countermeasure for a severe accident. (I.S.)

A new technique for pumping hydrogen gas

Science.gov (United States)

Friedman, I.; Hardcastle, K.

1970-01-01

A system for pumping hydrogen gas without isotopic fractionation has been developed. The pump contains uranium metal, which when heated to about 80??C reacts with hydrogen to form UH3. The UH3 is heated to above 500??C to decompose the hydride and regenerate the hydrogen. ?? 1970.

Heat supply analysis of steam reforming hydrogen production process in conventional and nuclear

International Nuclear Information System (INIS)

Siti Alimah; Djati Hoesen Salimy

2015-01-01

Tile analysis of heat energy supply in the production of hydrogen by natural gas steam reforming process has been done. The aim of the study is to compare the energy supply system of conventional and nuclear heat. Methodology used in this study is an assessment of literature and analysis based on the comparisons. The study shows that the heat sources of fossil fuels (natural gas) is able to provide optimum operating conditions of temperature and pressure of 850-900 °C and 2-3 MPa, as well as the heat transfer is dominated by radiation heat transfer, so that the heat flux that can be achieved on the catalyst tube relatively high (50-80 kW/m"2) and provide high thermal efficiency of about 85 %. While in the system with nuclear energy, due to the demands of safety, process operating at less than optimum conditions of temperature and pressure of 800-850 °C and 4.5 MPa, as well as the heat transfer is dominated by convection heat transfer, so that the heat flux that can be achieved catalyst tube is relatively low (1020 kW/m"2) and it provides a low thermal efficiency of about 50 %. Modifications of reformer and heat utilization can increase the heat flux up to 40 kW/m"2 so that the thermal efficiency can reach 78 %. Nevertheless, the application of nuclear energy to hydrogen production with steam reforming process is able to reduce the burning of fossil fuels which has implications for the potential decrease in the rate of CO2 emissions into the environment. (author)

Will implementation of green gas into the gas supply be feasible in the future?

International Nuclear Information System (INIS)

Bekkering, J.; Hengeveld, E.J.; Gemert, W.J.T. van; Broekhuis, A.A.

2015-01-01

Highlights: • The relation between energy efficiency, greenhouse gas reduction and cost price of a green gas supply chain was analyzed. • Opportunities for improving a green gas supply chain were evaluated. • Fossil and renewable energy resources are made explicit in energy efficiency definition. • Switching to green electricity is the major contributor to improving the energy efficiency and greenhouse gas reduction. - Abstract: The energy efficiency, greenhouse gas reduction and cost price of a green gas supply chain were evaluated. The considered supply chain is based on co-digestion of dairy cattle manure and maize, biogas upgrading and injection into a distribution gas grid. A reference scenario was defined which reflects the current state of practice, assuming that input energy is from fossil origin. Possible improvements of this reference scenario were investigated. For this analysis two new definitions for energy input–output ratio were introduced; one based on input of primary energy from all origin, and one related to energy from fossil origin only. The influence of the improvements on greenhouse gas reduction and cost price was assessed too. Results show that electricity (from fossil origin) is the major contributor to energy input in the reference scenario. Switching to green electricity significantly improves the energy efficiency (both definitions) and greenhouse gas reduction. Preventing methane leakage during digestion and upgrading, and re-using heat within the supply chain also show improvements on these parameters as well as on cost price, although their influence is smaller. Decreasing the share of energy crops in the substrate mix shows a negative effect. It is shown that greenhouse gas reduction of more than 80% is possible with current technology. To meet this high sustainability level, multiple improvement options will have to be implemented in the green gas supply chain. Doing so will result in a modest decrease of the green gas

Compact hydrogen production systems for solid polymer fuel cells

Science.gov (United States)

Ledjeff-Hey, K.; Formanski, V.; Kalk, Th.; Roes, J.

Generally there are several ways to produce hydrogen gas from carbonaceous fuels like natural gas, oil or alcohols. Most of these processes are designed for large-scale industrial production and are not suitable for a compact hydrogen production system (CHYPS) in the power range of 1 kW. In order to supply solid polymer fuel cells (SPFC) with hydrogen, a compact fuel processor is required for mobile applications. The produced hydrogen-rich gas has to have a low level of harmful impurities; in particular the carbon monoxide content has to be lower than 20 ppmv. Integrating the reaction step, the gas purification and the heat supply leads to small-scale hydrogen production systems. The steam reforming of methanol is feasible at copper catalysts in a low temperature range of 200-350°C. The combination of a small-scale methanol reformer and a metal membrane as purification step forms a compact system producing high-purity hydrogen. The generation of a SPFC hydrogen fuel gas can also be performed by thermal or catalytic cracking of liquid hydrocarbons such as propane. At a temperature of 900°C the decomposition of propane into carbon and hydrogen takes place. A fuel processor based on this simple concept produces a gas stream with a hydrogen content of more than 90 vol.% and without CO and CO2.

Natural gas supply strategies for European energy market actors

International Nuclear Information System (INIS)

Girault, Vincent

2007-06-01

The liberalization of the European energy markets leads to the diversification of supplies. Hence, we analyse the natural gas importation problem in a power producer point of view. Upstream and downstream natural gas markets are concentrated. In this oligopoly context, our topic is to focus on strategies which modify natural gas sourcing price. This by studying the surplus sharing on the natural gas chain. A European firm can bundle gas and electricity outputs to increase its market share. Therefore, a bundling strategy of a power producer in competition with a natural gas reseller on the final European energy market increases upstream natural gas price. Bundling also acts as a raising rival cost strategy and reduces the rivals' profit. Profits opportunities incite natural gas producers to enter the final market. Vertical integration between a natural gas producer and a European gas reseller is a way, for producers, to catch end consumer surplus. Vertical integration results in the foreclosure of the power producer on the upstream natural gas market. To be active on the natural gas market, the power producer could supply bundles. But, this strategy reallocates the rent. The integrated firm on natural gas gets the rent of electricity market in expenses of the power producer. Then, a solution for the power producer is to supply gas and electricity as complements. Then, we consider a case where vertical integration is not allowed. Input price discrimination by a monopolist leads to a lower natural gas price for the actor which diversifies its supplying sources. Furthermore, a bundling strategy increases the gap between the price proposed to the firm which also diversify its output and the firm which is fully dependent from the producer to supply natural gas on final market. (author)

German natural gas market and the international supply situation. Pt. 1. Supply market for natural gas

Energy Technology Data Exchange (ETDEWEB)

Dolinski, U [Deutsches Inst. fuer Wirtschaftsforschung, Berlin (Germany, F.R.). Abt. Bergbau und Energie

1978-01-01

Since the oil crisis the buyers's market started to change to a seller's market as a result of the worldwide rising demand for natural gas. This development will be amplified with the increasing significance and volume of LNG trade. This depends upon the availability of handling and tanker capacities. It is considered that technical solutions are available. The internationalisation of the world natural gas market imposes changes in terms of trade for the Federal Republic of Germany. In the sixties, terms of trade made under sales considerations presented no problems. But gas buyers today are forced to accept sellers' terms looking for the buyer offering the highest prices and other sales advantages. The world gas market has assumed the features of a polypolistic market. The security of supply is not a matter of adequate reserves, but almost entirely that of terms of contract on which the natural gas supply can be ensured. It is thereby decisive, whether it will be possible in future to procure the required amount of gas at such terms that it can be sold on the German energy market at competetive rates.

Role of a natural gas utility in the hydrogen economy

International Nuclear Information System (INIS)

Bayko, J.

2004-01-01

'Full text:' Enbridge Gas Distribution is the largest natural gas distribution company in Canada at about 1.7 million residential, commercial and industrial customers. Enbridge will speak to the role of a natural gas utility in the hydrogen economy, and outline the benefits of hydrogen production from natural gas reformation for both stationary and mobile applications. Hydrocarbon reformation will act at least as a bridge until a more fully developed hydrogen economy infrastructure is developed. Reformation allows immediate leveraging of the reliability of vast existing natural gas distribution systems, and a reduced need for on-site hydrogen storage. Natural gas powered fuel cells provide improved emissions over traditional internal combustion engines, and in the stationary market provide smarter use of resources through the higher efficiencies of cogeneration (the capture and use of otherwise waste heat). (author)

Will implementation of green gas into the gas supply be feasible in the future?

NARCIS (Netherlands)

Bekkering, J.; Hengeveld, E. J.; van Gemert, W. J. T.; Broekhuis, A. A.

2015-01-01

The energy efficiency, greenhouse gas reduction and cost price of a green gas supply chain were evaluated. The considered supply chain is based on co-digestion of dairy cattle manure and maize, biogas upgrading and injection into a distribution gas grid. A reference scenario was defined which

DEVELOPMENT OF TECHNICAL DECISIONS FOR HEAT SUPPLY WITH TUBULAR GAS HEATERS

Directory of Open Access Journals (Sweden)

IRODOV V. F.

2017-05-01

Full Text Available Annotation. Problems formulation. The problem that is solved is the development of autonomous heat supply systems that reduce the capital costs of construction and increase the efficiency of the use of energy resources. One of the ways to solve this problem is the use of tubular gas heaters. For this, it is necessary to develop new technical solutions for heat supply with tubular gas heaters, as well as scientific and methodological support for the development, construction and operation of heat supply systems with tubular gas heaters. Analysis of recent research. Preliminary studies of infrared tubular gas heaters are considered, which were used to heat industrial enterprises with sufficiently high premises. The task was to extend the principles of heat supply by means of tubular heaters for heating air, water and heating medium in relatively low rooms. Goal and tasks. To lay out the development of technical solutions for heat supply with tubular gas heaters, which increase the efficiency and reliability of heat supply systems and extend the use of tubular gas heaters in heat supply. Results. Technical solutions for heat supply with tubular gas heaters have made it possible to extend their applications for heating air, water and heating medium in relatively low rooms. Scientific novelty. New technical solutions for heat supply with tubular gas heaters increase the efficiency of using fuel and energy resources at low capital costs. Practical significance. Technical solutions for heat supply using tubular heaters have the potential for wide application in the heat supply of industrial, public and residential facilities. Conclusions. For two decades, new technical solutions for heat supply with tubular gas heaters have been developed, which increase the efficiency and reliability of heat supply systems and can be widely used for autonomous heating.

Will implementation of green gas into the gas supply be feasible in the future?

NARCIS (Netherlands)

Bekkering, Jan; Hengeveld, Evert Jan; van Gemert, Wim; Broekhuis, A.A.

Energy efficiency, greenhouse gas reduction and cost price of a green gas supply chain were evaluated. This supply chain is based on co-digestion of dairy cattle manure and maize, biogas upgrading and injection into a distribution gas grid. A defined reference scenario reflects the current state of

Will implementation of green gas into the gas supply be feasible in the future?

NARCIS (Netherlands)

Ir. J. Bekkering; prof. dr. Wim van Gemert; A.A. Broekhuis; Drs. E.J. Hengeveld

2015-01-01

energy efficiency, greenhouse gas reduction and cost price of a green gas supply chain were evaluated. This supply chain is based on co-digestion of dairy cattle manure and maize, biogas upgrading and injection into a distribution gas grid. A defined reference scenario reflects the current state of

Process for the production of hydrogen/deuterium-containing gas

International Nuclear Information System (INIS)

Nitschke, E.; Desai, A.; Ilgner, H.

1978-01-01

A process for the production of hydrogen/deuterium-containing gas is described in which the enriched condensate obtained from the production of a hydrogen/deuterium-containing gas mixture is collected and subjected to a direct exchange of isotopes with the feedsteam admitted to the process. Such condensate can be brought into direct exchange of isotopes with the gas water vapor mixture within the process, viz. ahead of the CO conversion section. The exchange of isotopes may be performed according to the counter-current principle. If it is intended to maintain in the hydrogen/deuterium-containing gas a certain definite content of water vapor whose phase condition is superior to the condition achieved when using normal cooling water, this gas, at least 0.6 kg/m 3 of gas, is subjected to an exchange of isotopes with the water fed additionally into the process

Silicon Carbide-Based Hydrogen Gas Sensors for High-Temperature Applications

Directory of Open Access Journals (Sweden)

Sangchoel Kim

2013-10-01

Full Text Available We investigated SiC-based hydrogen gas sensors with metal-insulator-semiconductor (MIS structure for high temperature process monitoring and leak detection applications in fields such as the automotive, chemical and petroleum industries. In this work, a thin tantalum oxide (Ta2O5 layer was exploited with the purpose of sensitivity improvement, because tantalum oxide has good stability at high temperature with high permeability for hydrogen gas. Silicon carbide (SiC was used as a substrate for high-temperature applications. We fabricated Pd/Ta2O5/SiC-based hydrogen gas sensors, and the dependence of their I-V characteristics and capacitance response properties on hydrogen concentrations were analyzed in the temperature range from room temperature to 500 °C. According to the results, our sensor shows promising performance for hydrogen gas detection at high temperatures.

Development Of A Centrifugal Hydrogen Pipeline Gas Compressor

Energy Technology Data Exchange (ETDEWEB)

Di Bella, Francis A. [Concepts NREC, White River Junction, VY (United States)

2015-04-16

Concepts NREC (CN) has completed a Department of Energy (DOE) sponsored project to analyze, design, and fabricate a pipeline capacity hydrogen compressor. The pipeline compressor is a critical component in the DOE strategy to provide sufficient quantities of hydrogen to support the expected shift in transportation fuels from liquid and natural gas to hydrogen. The hydrogen would be generated by renewable energy (solar, wind, and perhaps even tidal or ocean), and would be electrolyzed from water. The hydrogen would then be transported to the population centers in the U.S., where fuel-cell vehicles are expected to become popular and necessary to relieve dependency on fossil fuels. The specifications for the required pipeline hydrogen compressor indicates a need for a small package that is efficient, less costly, and more reliable than what is available in the form of a multi-cylinder, reciprocating (positive displacement) compressor for compressing hydrogen in the gas industry.

Experimental study on flame propagation characteristics of Hydrogen premixed gas in gas pipeline

Science.gov (United States)

Ma, Danzhu; Li, Zhuang; Jia, Fengrui; Li, Zhou

2018-06-01

Hydrogen is the cleanest high-energy gas fuel, and also is the main industrial material. However, hydrogen is more explosive and more powerful than conventional gas fuels, which restricts its application. In particular, the expansion of premixed combustion under a strong constraint is more complicated, the reaction spreads faster. The flame propagation characteristics of premixed hydrogen/air were investigated by experiment. The mechanism of reaction acceleration is discussed, and then the speed of the flame propagation and the reaction pressure were tested and analysed.

Microwave interaction with nonuniform hydrogen gas in carbon nanotubes

International Nuclear Information System (INIS)

Babaei, S.; Babaei, Sh.

2009-01-01

In this paper we study the reflection, absorption, and transmission of microwave from nonuniform hydrogen gas in carbon nanotubes, grown by iron-catalyzed high-pressure carbon monoxide disproportionate (HiPco) process. A discussion on the effect of various hydrogen gas parameters on the reflected power, absorbed power, and transmitted power is presented. The nonuniform hydrogen gas slab is modeled by a series of subslabs. The overall number density profile across the whole slab follows a parabolic function. The total reflected, absorbed, and transmitted powers are then deduced and their functional dependence on the number density, collision frequency, and angle of propagation is studied

Field effect-gas sensor for hydrogen

Energy Technology Data Exchange (ETDEWEB)

Plihal, M [Siemens A.G., Muenchen (Germany, F.R.). Forschungslaboratorium

1977-01-01

MIS diodes with palladium gate can be used to detect and to measure quantitatively the hydrogen concentration in gas mixtures. The dependence of the differential capacitance of these diodes on the partial pressure of hydrogen in nitrogen, oxygen and air is investigated. A theoretical model is developed which gives satisfactory agreement with most of the experimental results.

City gas supply management system. Toshi gas kyokyu kanri system

Energy Technology Data Exchange (ETDEWEB)

Ota, S [Tokyo Gas Co. Ltd., Tokyo (Japan)

1991-07-05

Supply and control system of city gas (about 90% is LNG) at Tokyo Gas Company is summarized. The LNG is delivered from the high pressure, A-middle pressure and B-middle pressure stations through the low pressure governors at about 3,000 locations to the low-pressure conduit networks. The information system department uses a large-size general purpose IBM computer as a host computer, control computers at each station, and communication networks consisted mainly of the in-house wireless networks. The trunk lines are all looped, and the important facilities are dualized. Characteristic functions include the supply prediction, which takes into account the past supply and ambient temperature records, a day of the week for a particular date, and demand fluctuation trends; adjustments of each holder based on the prediction and restrictions; and piping network simulation to decide gas manufacturing patterns, and determine reasonability of local construction of complicated conduits. The monitoring and control system as the central nerve includes a quick block-wide operation at an accident from earthquake and the like to prevent wide area disasters. 8 figs., 1 tab.

Radiolytic and thermolytic bubble gas hydrogen composition

Energy Technology Data Exchange (ETDEWEB)

Woodham, W. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

2017-12-11

This report describes the development of a mathematical model for the estimation of the hydrogen composition of gas bubbles trapped in radioactive waste. The model described herein uses a material balance approach to accurately incorporate the rates of hydrogen generation by a number of physical phenomena and scale the aforementioned rates in a manner that allows calculation of the final hydrogen composition.

Zeolite Membrane Reactor for Water Gas Shift Reaction for Hydrogen Production

Energy Technology Data Exchange (ETDEWEB)

Lin, Jerry Y.S. [Arizona State Univ., Mesa, AZ (United States)

2013-01-29

Gasification of biomass or heavy feedstock to produce hydrogen fuel gas using current technology is costly and energy-intensive. The technology includes water gas shift reaction in two or more reactor stages with inter-cooling to maximize conversion for a given catalyst volume. This project is focused on developing a membrane reactor for efficient conversion of water gas shift reaction to produce a hydrogen stream as a fuel and a carbon dioxide stream suitable for sequestration. The project was focused on synthesizing stable, hydrogen perm-selective MFI zeolite membranes for high temperature hydrogen separation; fabricating tubular MFI zeolite membrane reactor and stable water gas shift catalyst for membrane reactor applications, and identifying experimental conditions for water gas shift reaction in the zeolite membrane reactor that will produce a high purity hydrogen stream. The project has improved understanding of zeolite membrane synthesis, high temperature gas diffusion and separation mechanisms for zeolite membranes, synthesis and properties of sulfur resistant catalysts, fabrication and structure optimization of membrane supports, and fundamentals of coupling reaction with separation in zeolite membrane reactor for water gas shift reaction. Through the fundamental study, the research teams have developed MFI zeolite membranes with good perm-selectivity for hydrogen over carbon dioxide, carbon monoxide and water vapor, and high stability for operation in syngas mixture containing 500 part per million hydrogen sulfide at high temperatures around 500°C. The research teams also developed a sulfur resistant catalyst for water gas shift reaction. Modeling and experimental studies on the zeolite membrane reactor for water gas shift reaction have demonstrated the effective use of the zeolite membrane reactor for production of high purity hydrogen stream.

Adsorption of hydrogen gas and redox processes in clays.

Science.gov (United States)

Didier, Mathilde; Leone, Laura; Greneche, Jean-Marc; Giffaut, Eric; Charlet, Laurent

2012-03-20

In order to assess the adsorption properties of hydrogen gas and reactivity of adsorbed hydrogen, we measured H(2)(g) adsorption on Na synthetic montmorillonite-type clays and Callovo-Oxfordian (COx) clayrock using gas chromatography. Synthetic montmorillonites with increasing structural Fe(III) substitution (0 wt %, 3.2 wt %, and 6.4 wt % Fe) were used. Fe in the synthetic montmorillonites is principally present as structural Fe(III) ions. We studied the concomitant reduction of structural Fe(III) in the clays using (57)Fe Mössbauer spectrometry. The COx, which mainly contains smectite/illite and calcite minerals, is also studied together with the pure clay fraction of this clayrock. Experiments were performed with dry clay samples which were reacted with hydrogen gas at 90 and 120 °C for 30 to 45 days at a hydrogen partial pressure close to 0.45 bar. Results indicate that up to 0.11 wt % of hydrogen is adsorbed on the clays at 90 °C under 0.45 bar of relative pressure. (57)Fe Mössbauer spectrometry shows that up to 6% of the total structural Fe(III) initially present in these synthetic clays is reduced upon adsorption of hydrogen gas. No reduction is observed with the COx sample in the present experimental conditions.

Performance evaluation of gas-power strategies for building energy conservation

International Nuclear Information System (INIS)

Gabbar, Hossam A.; Runge, Jason; Bondarenko, Daniel; Bower, Lowell; Pandya, Devarsh; Musharavati, Farayi; Pokharel, Shaligram

2015-01-01

Highlights: • Comparison of natural gas and hydrogen fuels for energy conservation in buildings. • Comparison between hydrogen and natural gas fuel cell is performed. • Simulations of building energy supply. • Performance evaluation of two potential gas-power supply scenarios in buildings. • Natural gas fuel cell showed better performance over hydrogen fuel cell. - Abstract: The work provided herein involves a comparison of natural gas and hydrogen fuels for the purpose of energy conservation for buildings via alternative energy generation methodologies. A case study simulation was developed for an average type of commercial building, a nine storey hotel located in Toronto. The two alternative energy source case studies involved the generation of hydrogen via the wind turbine for the fuel cell, and the use of natural gas directly in the steam reforming fuel cell. The simulations for both scenarios were run and the recorded results were compared to the original case study, as well as between the scenarios. To supply for the base load of the building the fuel cells were given the same kW rating for both scenarios. The identification of all existing technologies for hydrogen gas and natural gas has been carried out, and the similar technologies between the two gases were found. For the purpose of realism, only existing purchasable technologies were considered in this paper. Due to the lack of commercially available technologies for hydrogen gas, only a comparison of fuel cell systems could be accomplished. Over the course of the investigative work it was found that when there is no direct supply of hydrogen to the site of utilization, the natural gas fuel cell is beneficial to the building due to its greater efficiency and lower cost. The major drawback for the hydrogen gas fuel cell, when the on-site generation is involved, is that no thermal power extraction systems currently exist for purchase and utilization in the buildings

Blending Hydrogen into Natural Gas Pipeline Networks. A Review of Key Issues

Energy Technology Data Exchange (ETDEWEB)

Melaina, M. W. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Antonia, O. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Penev, M. [National Renewable Energy Lab. (NREL), Golden, CO (United States)

2013-03-01

This study assesses the potential to deliver hydrogen through the existing natural gas pipeline network as a hydrogen and natural gas mixture to defray the cost of building dedicated hydrogen pipelines. Blending hydrogen into the existing natural gas pipeline network has also been proposed as a means of increasing the output of renewable energy systems such as large wind farms.

North American natural gas pipeline and supply update

International Nuclear Information System (INIS)

Molyneaux, M.

1999-01-01

A series of overhead viewgraphs accompanied this presentation which presented an update of North American natural gas supply. Some of the graphs depicted the following: (1) natural gas consumption in the United States, (2) U.S. imports of Canadian natural gas, (3) natural gas prices differential: Henry Hub versus Empress, (4) natural gas production in the U.S., and (5) Baker Hughes active rig count, U.S. gas rigs. First Energy's view of U.S. natural gas supply is that the estimate of 50.0 Bcf/d for U.S. domestic production is looking too high. The first quarter 1999 exit production rates are behind expectations. U.S. domestic natural gas expenditure budgets are still down by more than 40 per cent compared to 1998 levels. The impact that this will have on prices was discussed. 21 figs

Gas supply for independent power projects: Drilling programs and reserve acquisitions

International Nuclear Information System (INIS)

Lambert, J.D.; Walker, R.K.

1990-01-01

Developers of gas-fired independent power projects, although drawn to gas as the fuel of choice for economic and environmental reasons, are finding the problem of cost-effective gas supply to be intractable. By one estimate, there are $6 billion worth of gas-fired projects languishing in the planning stage for want of long-term gas supply that is acceptable to project lenders. Worse still, as the authors are aware, some currently operating gas-fired projects lack such a supply, thus forcing the developer to rely on the spot market for gas as an interim (and unsatisfactory) solution. Although spot market prices in the deregulated natural gas industry have remained relatively low over several years, long-term gas supply has become problematic, particularly for power projects whose economics typically require an assured supply at a determined price over a multiyear period. In short, while there is an increasing demand for gas as a preferred source of fuel supply for power projects, there are discontinuities in the approaches taken to contracting for that supply by producers and developers. These concern primarily allocation of the risk of commodity-driven price increases during the term of the fuel supply contract. Without a means of accommodating price-related risk, the parties will inevitably find themselves at an impasse in contract negotiations. If there is a barrier to the independent power generation industry's vertical integration into gas production, it is the fundamental insularity of the two industries. As they have discovered, it may be indispensable for gas producers and power developers to employ intermediaries familiar with both industries in order to consummate appropriate joint-venture drilling programs and reserve acquisitions. Given the economic consequences of doing so successfully, however, they believe such programs and acquisitions may become an integral part of independent power developers' business strategy in the 1990s and beyond

Device to remove hydrogen isotopes from a gas phase

International Nuclear Information System (INIS)

Morlock, G.; Wiesemes, J.; Bachner, D.

1977-01-01

The device described here guarantees the selective removal of hydrogen isotopes from gas phases in order to prevent the occurence of explosive H 2 gas mixtures, or to separate off radioactive tritium in nuclear plants from the gas phase. It consists of a closed container whose walls are selectively penetrable by hydrogen isotopes. It is simultaneously filled compactly and presssure-resistant with a metal bulk (e.g. powder, sponges or the like of titanium or other hydrogen isotope binding metal). Walling and bulk are maintained at suitable working temperatures by means of a system according to the Peltier effect. The whole thing is safeguarded by protective walling. (RB) [de

The future of the UK gas network

International Nuclear Information System (INIS)

Dodds, Paul E.; McDowall, Will

2013-01-01

The UK has an extensive natural gas pipeline network supplying 84% of homes. Previous studies of decarbonisation pathways using the UK MARKAL energy system model have concluded that the low-pressure gas networks should be mostly abandoned by 2050, yet most of the iron pipes near buildings are currently being replaced early for safety reasons. Our study suggests that this programme will not lock-in the use of gas in the long-term. We examine potential future uses of the gas network in the UK energy system using an improved version of UK MARKAL that introduces a number of decarbonisation options for the gas network including bio-methane, hydrogen injection to the natural gas and conversion of the network to deliver hydrogen. We conclude that hydrogen conversion is the only gas decarbonisation option that might enable the gas networks to continue supplying energy to most buildings in the long-term, from a cost-optimal perspective. There is an opportunity for the government to adopt a long-term strategy for the gas distribution networks that either curtails the iron mains replacement programme or alters it to prepare the network for hydrogen conversion; both options could substantially reduce the long-term cost of supplying heat to UK buildings. - Highlights: • We examine the long-term future of the UK gas pipe networks using the UK MARKAL model. • The iron mains replacement programme will not lead to gas infrastructure lock-in. • Bio-methane and hydrogen injection have only a small role in our future scenarios. • The most cost-optimal strategy might be to convert the networks to deliver hydrogen. • Adopting a long-term gas strategy could reduce the cost of providing heat in the UK

Blending Hydrogen into Natural Gas Pipeline Networks: A Review of Key Issues

Energy Technology Data Exchange (ETDEWEB)

Melaina, M. W.; Antonia, O.; Penev, M.

2013-03-01

The United States has 11 distinct natural gas pipeline corridors: five originate in the Southwest, four deliver natural gas from Canada, and two extend from the Rocky Mountain region. This study assesses the potential to deliver hydrogen through the existing natural gas pipeline network as a hydrogen and natural gas mixture to defray the cost of building dedicated hydrogen pipelines.

Improvement of anaerobic bio-hydrogen gas production from organic sludge waste

International Nuclear Information System (INIS)

Lee, S.; Lee, Y. H.

2009-01-01

Microbial hydrogen gas production from organic matters stands out as one of the most promising alternatives for sustainable green energy production. Based on the literature review, investigation of anaerobic bio-hydrogen gas production from organic sludge waste using a mixed culture has been very limited. The objective of this study was to assess the anaerobic bio-hydrogen gas production from organic sludge waste under various conditions. (Author)

Process for hydrogen isotope exchange and concentration between liquid water and hydrogen gas and catalyst assembly therefor

International Nuclear Information System (INIS)

Stevens, W.H.

1975-01-01

A bithermal, catalytic, hydrogen isotope exchange process between liquid water and hydrogen gas to effect concentration of the deuterium isotope of hydrogen is described. Liquid water and hydrogen gas are contacted with one another and with at least one catalytically active metal selected from Group VIII of the Periodic Table; the catalyst body has a water repellent, gas and water vapor permeable, organic polymer or resin coating, preferably a fluorinated olefin polymer or silicone resin coating, so that the isotope exchange takes place by two simultaneously occurring, and closely coupled in space, steps and concentration is effected by operating two interconnected sections containing catalyst at different temperatures. (U.S.)

Long term contracts in portfolios of gas supply

International Nuclear Information System (INIS)

Burns, D.

1992-01-01

This paper promotes the idea of long-term contracting for natural gas local distributors and utilities. It presents a brief history of how the spot-market developed and the effects spot-marketing can have in times of supply shortages. This has also resulted in a drastic decrease in exploration and development in the gas industry as gas supplies have exceeding demand, driving the prices down. The paper proposes several methods to restabilize the long-term contracting of gas by considering volume and pricing flexibility. Some brief discussions of industry-wide statistics are presented to show reserve replacement costs which would be needed to preserve the industry in a profit-making situation

Natural gas supply in Denmark - A model of natural gas transmission and the liberalized gas market

International Nuclear Information System (INIS)

Bregnbaek, L.

2005-01-01

In the wake of the liberalization of European energy markets a large area of research has spawned. This area includes the development of mathematical models to analyze the impact of liberalization with respect to efficiency, supply security and environment, to name but a few subjects. This project describes the development of such a model. In Denmark the parallel liberalization of the markets of natural gas and electricity and the existence of an abundance of de-centralized combined heat and power generators of which most are natural gas fired, leads to the natural assumption that the future holds a greater deal of interdependency for these markets. A model is developed describing network flows in the natural gas transmission system, the main arteries of natural gas supply, from a technical viewpoint. This yields a technical bounding on the supply available in different parts of the country. Additionally the economic structure of the Danish natural gas market is formulated mathematically giving a description of the transmission, distribution and storage options available to the market. The supply and demand of natural gas is put into a partial equilibrium context by integrating the developed model with the Balmorel model, which describes the markets for electricity and district heat. Specifically on the demand side the consumption of natural gas for heat and power generation is emphasized. General results and three demonstration cases are presented to illustrate how the developed model can be used to analyze various energy policy issues, and to disclose the strengths and weaknesses in the formulation. (au)

Plasma steam reforming of E85 for hydrogen rich gas production

International Nuclear Information System (INIS)

Zhu Xinli; Hoang Trung; Lobban, Lance L; Mallinson, Richard G

2011-01-01

E85 (85 vol% ethanol and 15 vol% gasoline) is a partly renewable fuel that is increasing in supply availability. Hydrogen production from E85 for fuel cell or internal combustion engine applications is a potential method for reducing CO 2 emissions. Steam reforming of E85 using a nonthermal plasma (pulse corona discharge) reactor has been exploited at low temperature (200-300 0 C) without external heating, diluent gas, oxidant or catalyst in this work. Several operational parameters, including the discharge current, E85 concentration and feed flow rate, have been investigated. The results show that hydrogen rich gases (63-67% H 2 and 22-29% CO, with small amounts of CO 2 , C 2 hydrocarbons and CH 4 ) can be produced by this method. A comparison with ethanol reforming and gasoline reforming under identical conditions has also been made and the behaviour of E85 reforming is found to be close to that of ethanol reforming with slightly higher C 2 hydrocarbons yields.

Potential application of gas chromatography to the analysis of hydrogen isotopes

International Nuclear Information System (INIS)

Warner, D.K.; Sprague, R.E.; Bohl, D.R.

1976-01-01

Gas chromatography is used at Mound Laboratory for the analysis of hydrogen isotopic impurities in gas mixtures. This instrumentation was used to study the applicability of the gas chromatography technique to the determination of the major components of hydrogen isotopic gas mixtures. The results of this study, including chromatograms and precision data, are presented

Method of removing hydrogen sulphide from hot gas mixtures

Energy Technology Data Exchange (ETDEWEB)

Furimsky, E.; Yumura, M.

1987-12-22

Hydrogen sulphide can be removed from hot gas mixtures by contacting the hot gas mixture at temperatures in the range of 500-900/sup 0/C with an adsorbent consisting of managanese nodules. The nodules may contain additional calcium cations. In sulphided form, the nodules are catalytically active for hydrogen sulphide decomposition to produce hydrogen. Regeneration of the adsorbent can be accomplished by roasting in an oxidizing atmosphere. The nodules can be used to treat gaseous mixtures containing up to 20% hydrogen sulfide, for example, gases produced during pyrolysis, cracking, coking, and hydrotreating processes. Experiments using the processes described in this patent are also outlined. 6 tabs.

The life cycle greenhouse gas implications of a UK gas supply transformation on a future low carbon electricity sector

International Nuclear Information System (INIS)

Hammond, Geoffrey P.; O'Grady, Áine

2017-01-01

Natural gas used for power generation will be increasingly sourced from more geographically diverse sites, and unconventional sources such as shale and biomethane, as natural gas reserves diminish. A consequential life cycle approach was employed to examine the implications of an evolving gas supply on the greenhouse gas (GHG) performance of a future United Kingdom (UK) electricity system. Three gas supply mixes were developed based on supply trends, from present day to the year 2050. The contribution of upstream gas emissions - such as extraction, processing/refining, - is not fully reported or covered by UK government legislation. However, upstream gas emissions were seen to be very influential on the future electricity systems analysed; with upstream gas emissions per MJ rising between 2.7 and 3.4 times those of the current supply. Increased biomethane in the gas supply led to a substantial reduction in direct fossil emissions, which was found to be critical in offsetting rising upstream emissions. Accordingly, the modelled high shale gas scenario, with the lowest biomethane adoption; resulted in the highest GHG emissions on a life cycle basis. The long-term dynamics of upstream processes are explored in this work to help guide future decarbonisation policies. - Highlights: • United Kingdom is set to undergo a large gas supply transformation. • Three potential gas mix scenarios were developed based on supply trends. • A consequential life cycle approach was taken to examine the evolving gas supply. • Upstream emissions were seen to rise substantially for all gas supply scenarios. • High shale gas mix resulted in greatest emissions due to low influx of biomethane.

Hydrogen-enriched natural gas; Bridge to an ultra low carbon world

Energy Technology Data Exchange (ETDEWEB)

Samuel, Joshua; Oliver, Mike

2010-09-15

Natural gas is recognized as an important part of the solution to climate change, as it has the smallest carbon footprint among fossil fuels and can be used with high efficiency. This alone is not enough. Supplementing natural gas with hydrogen creating hydrogen-enriched natural gas (HENG), where the hydrogen comes from a low- or zero-carbon energy source. HENG, the subject of this paper, can leverage existing natural gas infrastructure to reduce CO2 and NOx, improve the efficiency of end-use equipment, and lower the overall carbon intensity of energy consumption.

Optimisation of a green gas supply chain : a review

NARCIS (Netherlands)

Bekkering, Jan; Broekhuis, A. A.; van Gemert, Wim

In this review the knowledge status of and future research options on a green gas supply based on biogas production by co-digestion is explored. Applications and developments of the (bio)gas supply in The Netherlands have been considered, whereafter literature research has been done into the several

Optimisation of a green gas supply chain - A review

NARCIS (Netherlands)

Bekkering, J.; Broekhuis, A. A.; van Gernert, W. J. T.; van Gemert, W. J. T.

In this review the Knowledge status of and future research options on a green gas supply based on biogas production by co-digestion is explored. Applications and developments of the (bio)gas supply in The Netherlands have been considered, whereafter literature research has been done into the several

a Study of Using Hydrogen Gas for Steam Boiler in CHOLOR- Alkali Manufacturing

Science.gov (United States)

Peantong, Sasitorn; Tangjitsitcharoen, Somkiat

2017-06-01

Main products of manufacturing of Cholor - Alkali, which commonly known as industrial chemical, are chlorine gas (Cl2), Sodium Hydroxide (NaOH) and hydrogen gas (H2). Chorine gas and sodium hydroxide are two main products for commercial profit; where hydrogen gas is by product. Most industries release hydrogen gas to atmosphere as it is non-profitable and less commercial scale. This study aims to make the most use of hydrogen as a substitute energy of natural gas for steam boiler to save energy cost. The second target of this study is to reduce level of CO2 release to air as a consequence of boiler combustion. This study suggests to install boiler that bases on hydrogen as main power with a high turndown ratio of at least 1:6. However, this case study uses boiler with two mode such as natural gas (NG) mode and mixed mode as they need to be flexible for production. Never the less, the best boiler selection is to use single mode energy of hydrogen. The most concerned issue about hydrogen gas is explosion during combustion stage. Stabilization measures at emergency stop is introduced to control H2 pressure to protect the explosion. This study varies ratio of natural gas to hydrogen gas to find the optimal level of two energy sources for boiler and measure total consumption through costing model; where CO2 level is measured at the boiler stack. The result of this study shows that hydrogen gas can be a substitute energy with natural gas and can reduce cost. Natural gas cost saving is 248,846 baht per month and reduce level of NOx is 80 ppm 7% O2 and 2 % of CO2 release to air as a consequence of boiler combustion.

The cost of longer-run gas supply to Europe

International Nuclear Information System (INIS)

Odell, P. R.

1996-01-01

The supply, demand and price outlook for natural gas in Europe were examined in detail. Demand for natural gas estimated to grow an average of 2.3% per annum, which will increase import dependence from 130 to 320 BCM over the next 30 years. For the immediate future profitable indigenous supply was predicted, aided by large proven and probable reserves, and technological advances. Indigenous output was forecast to increase by some 60% by 2025. Future international oil prices indicate gas-equivalent border values adequate to secure profitable supply from a variety of external sources leading to continuing competition for markets by producers and continuing diversification of imports. 30 refs., 9 tabs

Long-term trends in U.S. gas supply and prices: 1991 edition of the GRI baseline projection of U.S. energy supply and demand to 2010, April 1991. Gas research insights

International Nuclear Information System (INIS)

Woods, T.J.

1991-04-01

The report summarizes the gas supply and price outlook in the 1991 Edition of the GRI Baseline Projection of U.S. Energy Supply and Demand. Projected U.S. gas production, gas imports, and other sources of gas supply are discussed along with the sensitivity of the outlook to changes in price expectations. The critical uncertainties and issues affecting the gas supply and price outlook are discussed. Appendixes include a comparison of the 1991 and the 1989 projections of gas supply and price trends; and a description of the GRI Hydrocarbon Model

The Vision of the Role of Hydrogen in Energy Supply in the Future

International Nuclear Information System (INIS)

Barbir, F.

2008-01-01

Europe is in a very difficult situation regarding the future of energy supply because it is highly dependent on import of oil and natural gas. In addition, because of environmental pollution, global climate changes, ?nite World reserves of fossil fuels and geo-political implications of distribution of those reserves, such an energy system is not sustainable. The need for inevitable changes in energy supply is becoming more and more obvious. This includes not only a change of the energy sources, but also in energy carriers and technologies for their conversion into useful forms of energy, as well as a change in the ways energy is used today. Based on present knowledge, the only energy sources that satisfy the sustainability requirements are the renewable energy sources - direct solar insolation and its consequences (wind, hydro, biomass). As the renewable energy sources cannot be utilized directly in most of applications there is a need for such energy carriers which can be produced from renewable energy sources and which can satisfy all the energy needs at the end use, again satisfying the sustainability requirements. Electricity is one of such energy carrier which may be used in most but not in all applications. There is a need for other energy carriers in the form of fuels which can be stored and used, for example, in the transportation sector. This is a role that hydrogen can fulfill in a future energy system - hydrogen satisfies the conditions of sustainability, can be produced from renewable energy sources and together with electricity can satisfy all energy needs. Although the role of hydrogen in a future energy system can be envisioned with some certainty, the problem is the transition, i.e. switching from the present energy system based on fossil fuels to the future energy system based on renewable energy sources. Of course, such transition cannot happen overnight, but the question is where and how to start and at which pace to proceed. Insistence on short

PETROBRAS Northeast gas security of supply study

Energy Technology Data Exchange (ETDEWEB)

Faertes, Denise; Heil, Luciana; Saker, Leonardo; Vieira, Flavia; Risi, Francisco [PETROBRAS, Rio de Janeiro, RJ (Brazil); Domingues, Joaquim; Alvarenga, Tobias; Mussel, Patricia [DNV, Rio de Janeiro, RJ (Brazil)

2009-07-01

The purpose of this paper is to present the study developed jointly by PETROBRAS Gas and Power Department and Det Norske Veritas (Brazil and United Kingdom office). The study was carried out with the objective of evaluating the security of supply 2009 PETROBRAS Northeast gas network. This network provides gas to thermo plants, to vehicles and to industrial and residential consumers. The occurrence of contract shortfalls implies on heavy fines for the suppliers. To provide best in class analysis, state of the art software was used in order to count on powerful tools to model the gas supply system and to quantify the availability and the efficiency of the overall network and of its individual components. It also provides the prioritization of investment, based on cost benefit analysis, and as a by-product, contingency plans that were developed, considering the identified failure scenarios. (author)

Reliability modelling - PETROBRAS 2010 integrated gas supply chain

Energy Technology Data Exchange (ETDEWEB)

Faertes, Denise; Heil, Luciana; Saker, Leonardo; Vieira, Flavia; Risi, Francisco; Domingues, Joaquim; Alvarenga, Tobias; Carvalho, Eduardo; Mussel, Patricia

2010-09-15

The purpose of this paper is to present the innovative reliability modeling of Petrobras 2010 integrated gas supply chain. The model represents a challenge in terms of complexity and software robustness. It was jointly developed by PETROBRAS Gas and Power Department and Det Norske Veritas. It was carried out with the objective of evaluating security of supply of 2010 gas network design that was conceived to connect Brazilian Northeast and Southeast regions. To provide best in class analysis, state of the art software was used to quantify the availability and the efficiency of the overall network and its individual components.

First principles study of inert-gas (helium, neon, and argon) interactions with hydrogen in tungsten

Energy Technology Data Exchange (ETDEWEB)

Kong, Xiang-Shan [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, P. O. Box 1129, Hefei 230031 (China); Hou, Jie [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, P. O. Box 1129, Hefei 230031 (China); University of Science and Technology of China, Hefei 230026 (China); Li, Xiang-Yan [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, P. O. Box 1129, Hefei 230031 (China); Wu, Xuebang, E-mail: xbwu@issp.ac.cn [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, P. O. Box 1129, Hefei 230031 (China); Liu, C.S., E-mail: csliu@issp.ac.cn [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, P. O. Box 1129, Hefei 230031 (China); Chen, Jun-Ling; Luo, G.-N. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China)

2017-04-15

We have systematically evaluated binding energies of hydrogen with inert-gas (helium, neon, and argon) defects, including interstitial clusters and vacancy-inert-gas complexes, and their stable configurations using first-principles calculations. Our calculations show that these inert-gas defects have large positive binding energies with hydrogen, 0.4–1.1 eV, 0.7–1.0 eV, and 0.6–0.8 eV for helium, neon, and argon, respectively. This indicates that these inert-gas defects can act as traps for hydrogen in tungsten, and impede or interrupt the diffusion of hydrogen in tungsten, which supports the discussion on the influence of inert-gas on hydrogen retention in recent experimental literature. The interaction between these inert-gas defects and hydrogen can be understood by the attractive interaction due to the distortion of the lattice structure induced by inert-gas defects, the intrinsic repulsive interaction between inert-gas atoms and hydrogen, and the hydrogen-hydrogen repelling in tungsten lattice.

Experimental Study of Gas Explosions in Hydrogen Sulfide-Natural Gas-Air Mixtures

Directory of Open Access Journals (Sweden)

André Vagner Gaathaug

2014-01-01

Full Text Available An experimental study of turbulent combustion of hydrogen sulfide (H2S and natural gas was performed to provide reference data for verification of CFD codes and direct comparison. Hydrogen sulfide is present in most crude oil sources, and the explosion behaviour of pure H2S and mixtures with natural gas is important to address. The explosion behaviour was studied in a four-meter-long square pipe. The first two meters of the pipe had obstacles while the rest was smooth. Pressure transducers were used to measure the combustion in the pipe. The pure H2S gave slightly lower explosion pressure than pure natural gas for lean-to-stoichiometric mixtures. The rich H2S gave higher pressure than natural gas. Mixtures of H2S and natural gas were also studied and pressure spikes were observed when 5% and 10% H2S were added to natural gas and also when 5% and 10% natural gas were added to H2S. The addition of 5% H2S to natural gas resulted in higher pressure than pure H2S and pure natural gas. The 5% mixture gave much faster combustion than pure natural gas under fuel rich conditions.

Natural gas participation on brazilian demand supply of liquefied petroleum gas

International Nuclear Information System (INIS)

Freitas Rachid, L.B. de

1991-01-01

Natural Gas Liquids Production, Liquefied Petroleum Gas (LPG) among them, has undergone a continuous growth and technological development until the first half of the eighties. This paper presents the natural gas processing activity development in Brazil, in the last 20 years, and the increasing share of LPG produced from natural gas in the supply of LPG domestic market. Possibilities of achieving greater shares are discussed, based on economics of natural gas processing projects. Worldwide gas processing installed capacity and LPG pricing tendencies, and their influence in the construction of new Natural Gas Processing Units in Brazil, are also discussed. (author)

Measurement of laminar burning velocities and Markstein lengths of diluted hydrogen-enriched natural gas

Energy Technology Data Exchange (ETDEWEB)

Miao, Haiyan; Jiao, Qi; Huang, Zuohua; Jiang, Deming [State Key Laboratory of Multiphase Flow in Power Engineering, School of Energy and Power Eng., Xi' an Jiaotong University (China)

2009-01-15

The laminar flame characteristics of natural gas-hydrogen-air-diluent gas (nitrogen/CO{sub 2}) mixtures were studied in a constant volume combustion bomb at various diluent ratios, hydrogen fractions and equivalence ratios. Both unstretched laminar burning velocity and Markstein length were obtained. The results showed that hydrogen fraction, diluent ratio and equivalence ratio have combined influence on laminar burning velocity and flame instability. The unstretched laminar burning velocity is reduced at a rate that is increased with the increase of the diluent ratio. The reduction effect of CO{sub 2} diluent gas is stronger than that of nitrogen diluent gas. Hydrogen-enriched natural gas with high hydrogen fraction can tolerate more diluent gas than that with low hydrogen fraction. Markstein length can either increase or decrease with the increase of the diluent ratio, depending on the hydrogen fraction of the fuel. (author)

Sustainability of hydrogen supply chain. Part I: Identification of critical criteria and cause–effect analysis for enhancing the sustainability using DEMATEL

DEFF Research Database (Denmark)

Ren, Jingzheng; Manzardo, Alessandro; Toniolo, Sara

2013-01-01

The enhancement of sustainability of hydrogen supply chain is of vital importance for the stakeholders/decision-makers to design a sustainable hydrogen supply chain. The objective of this paper is to develop a method for prioritizing the influential factors, identifying the key driving factors...... that influence the sustainability of hydrogen supply chain and mapping the cause–effect relationships to improve the sustainability of hydrogen supply chain. In this paper, thirty seven criteria in four aspects including economic, technological, environmental and societal aspects are considered for enhancing...... the sustainability of hydrogen supply chain, and decision making trial and evaluation laboratory has been used to analyze the relationships among these criteria. The status of hydrogen supply chain in China has been studied by the proposed method, and the results are consistent with the actual conditions. It could...

Will implementation of green gas into the gas supply be feasible in the future?

OpenAIRE

Bekkering, J.; Gemert, van, Wim; Broekhuis, A.A.; Hengeveld, E.J.

2015-01-01

energy efficiency, greenhouse gas reduction and cost price of a green gas supply chain were evaluated. This supply chain is based on co-digestion of dairy cattle manure and maize, biogas upgrading and injection into a distribution gas grid. A defined reference scenario reflects the current state of practice, assuming that input energy is from fossil origin. Possible improvements of this reference scenario were investigated. For this analysis two new definitions for energy input-output ratio w...

Production of hydrogen by thermocatalytic cracking of natural gas

Energy Technology Data Exchange (ETDEWEB)

Muradov, N. [Florida Solar Energy Center, Cocoa, FL (United States)

1996-10-01

The conventional methods of hydrogen production from natural gas (for example, steam reforming and partial oxidation) are complex, multi-step processes that produce large quantities of CO{sub 2}. The main goal of this project is to develop a technologically simple process for hydrogen production from natural gas (NG) and other hydrocarbon fuels via single-step decomposition of hydrocarbons. This approach eliminates or significantly reduces CO{sub 2} emission. Carbon is a valuable by-product of this process, whereas conventional methods of hydrogen production from NG produce no useful by-products. This approach is based on the use of special catalysts that reduce the maximum temperature of the process from 1400-1500{degrees}C (thermal non-catalytic decomposition of methane) to 500-900{degrees}C. Transition metal based catalysts and various forms of carbon are among the candidate catalysts for the process. This approach can advantageously be used for the development of compact NG reformers for on-site production of hydrogen-methane blends at refueling stations and, also, for the production of hydrogen-rich gas for fuel cell applications. The author extended the search for active methane decomposition catalysts to various modifications of Ni-, Fe-, Mo- and Co-based catalysts. Variation in the operational parameters makes it possible to produce H{sub 2}-CH{sub 4} blends with a wide range of hydrogen concentrations that vary from 15 to 98% by volume. The author found that Ni-based catalysts are more effective at temperatures below 750{degrees}C, whereas Fe-based catalysts are effective at temperatures above 800{degrees}C for the production of hydrogen with purity of 95% v. or higher. The catalytic pyrolysis of liquid hydrocarbons (pentane, gasoline) over Fe-based catalyst was conducted. The author observed the production of a hydrogen-rich gas (hydrogen concentration up to 97% by volume) at a rate of approximately 1L/min.mL of hydrocarbon fuel.

International performance indicators: gas supply

International Nuclear Information System (INIS)

1994-12-01

This study evaluates the performance of Australian's natural gas utilities against world best practice. In particular, it examines whether Australia's traded goods sector is disadvantaged by the performance of domestic infrastructure service industries. It reports on the operating efficiency of the natural gas industry using Data Envelopment Analysis. It concludes that the Australian gas industry as a whole is performing relatively well in term of operating efficiency and that its prices are comparable with prices in North America, once differences in consumption per customer are taken into consideration. Appendixes 1 and 2 provide a summary of the structure and regulation of the gas supply industry in Australia and selected overseas countries, while the Appendix 3 gives an econometric analysis of the relationships between consumption per customer and residential price-cost margins. refs., tabs., figs

Natural gas supply and demand outlook

International Nuclear Information System (INIS)

McGill, C.B.

1998-01-01

The outlook for U.S. natural gas supply and demand in the residential, commercial, industrial/cogeneration, electricity and transportation sectors for 1995, 2000, 2005, 2010, and 2015 was presented. A summary of gas well completions from 1990 to 1997 was also provided. The Canadian natural gas resource was estimated at 184 trillion cubic feet. In 1996, Canada produced 5.6 trillion cubic feet of natural gas, half of which was exported to the U.S. New pipeline projects have been proposed to transport natural gas from eastern offshore areas and the Western Canadian Sedimentary Basin. A table representing U.S. and Canada gas trade from 1990 to 1997 and a map of proposed Canadian and U.S. natural gas pipeline routes were also included. Looking into the future, this speaker predicted continued volatility in natural gas prices. 9 tabs., 9 figs

Development of Shale Gas Supply Chain Network under Market Uncertainties

Directory of Open Access Journals (Sweden)

Jorge Chebeir

2017-02-01

Full Text Available The increasing demand of energy has turned the shale gas and shale oil into one of the most promising sources of energy in the United States. In this article, a model is proposed to address the long-term planning problem of the shale gas supply chain under uncertain conditions. A two-stage stochastic programming model is proposed to describe and optimize the shale gas supply chain network. Inherent uncertainty in final products’ prices, such as natural gas and natural gas liquids (NGL, is treated through the utilization of a scenario-based method. A binomial option pricing model is utilized to approximate the stochastic process through the generation of scenario trees. The aim of the proposed model is to generate an appropriate and realistic supply chain network configuration as well as scheduling of different operations throughout the planning horizon of a shale gas development project.

Field test of hydrogen in the natural gas grid

Energy Technology Data Exchange (ETDEWEB)

Iskov, H

2010-08-15

In order to prepare for a future use of hydrogen as a fuel gas it became evident that very little information existed regarding the compatibility between long-term exposure and transportation of hydrogen in natural gas pipelines. A program was therefore set to study the transportation in a small-scale pilot grid at the research centre in Hoersholm, Denmark. The test program included steel pipes from the Danish gas transmission grid and polymer pipes from the Danish and Swedish gas distribution grid. The test of polymer pipes was devised so that samples of all test pipes were cut out of the grid each year and analysis performed on these pipe samples; in this way any form of influence on the integrity of the polyethylene pipe would be detected. The analytical program for polymer was devised in order to detect any influence on the additivation of the polyethylene as this has an influence on oxidative resistance, as well as checking already encountered possible degradation caused by extrusion of the material. Further tools as rheology and melt flow rate were used for detecting any structural changes on the material. On the mechanical property side the tensile strength and modulus were followed as well as the most important property for the pipe line, namely slow crack growth. The results of the polymer pipe tests show no degradations of any kind related to the continuous hydrogen exposure for more than 4 years. This is a strong indication of the compatibility to hydrogen of the tested polymer materials PE 80 and PE 100. The object of the steel pipe test was to see the effect on fatigue life of existing natural gas transmission lines with hydrogen replacing the natural gas. Full-scale dynamic tests were performed using randomly selected cut-out API 5L X70 pipe sections with a diameter of 20 inches and a wall thickness of 7 millimetres from the Danish natural gas transmission system. The pipe sections contained field girth weld made during the installation of the pipe

Field test of hydrogen in the natural gas grid

Energy Technology Data Exchange (ETDEWEB)

Iskov, H.

2010-08-15

In order to prepare for a future use of hydrogen as a fuel gas it became evident that very little information existed regarding the compatibility between long-term exposure and transportation of hydrogen in natural gas pipelines. A program was therefore set to study the transportation in a small-scale pilot grid at the research centre in Hoersholm, Denmark. The test program included steel pipes from the Danish gas transmission grid and polymer pipes from the Danish and Swedish gas distribution grid. The test of polymer pipes was devised so that samples of all test pipes were cut out of the grid each year and analysis performed on these pipe samples; in this way any form of influence on the integrity of the polyethylene pipe would be detected. The analytical program for polymer was devised in order to detect any influence on the additivation of the polyethylene as this has an influence on oxidative resistance, as well as checking already encountered possible degradation caused by extrusion of the material. Further tools as rheology and melt flow rate were used for detecting any structural changes on the material. On the mechanical property side the tensile strength and modulus were followed as well as the most important property for the pipe line, namely slow crack growth. The results of the polymer pipe tests show no degradations of any kind related to the continuous hydrogen exposure for more than 4 years. This is a strong indication of the compatibility to hydrogen of the tested polymer materials PE 80 and PE 100. The object of the steel pipe test was to see the effect on fatigue life of existing natural gas transmission lines with hydrogen replacing the natural gas. Full-scale dynamic tests were performed using randomly selected cut-out API 5L X70 pipe sections with a diameter of 20 inches and a wall thickness of 7 millimetres from the Danish natural gas transmission system. The pipe sections contained field girth weld made during the installation of the pipe

Impacts of imports, government policy and technology on future natural gas supply

International Nuclear Information System (INIS)

Allison, E.

2009-01-01

This presentation discussed the impacts of imports, government policy and technology on future natural gas supply. Specifically, it discussed projections of natural gas supply and demand; the potential impact of imports on United States natural gas supply; the potential impacts of government policy on natural gas supply and demand; and the impact of technological innovations on natural gas supply such as coalbed methane and methane hydrate. Specific government policies that were examined included the American Recovery and Reinvestment Act of 2009; the American Clean Energy and Security Act of 2009; and the Clean Energy Jobs and American Power Act of 2009. It was concluded that the United States demand for natural gas will expand and that the impact of pending clean energy legislation is unclear. In addition, each potential future resource will face constraints and new resources may come on line in the next 20 years. figs.

A mathematical framework for modelling and evaluating natural gas pipeline networks under hydrogen injection

Energy Technology Data Exchange (ETDEWEB)

Tabkhi, F.; Azzaro-Pantel, C.; Pibouleau, L.; Domenech, S. [Laboratoire de Genie Chimique, UMR5503 CNRS/INP/UPS, 5 rue Paulin Talabot F-BP1301, 31106 Toulouse Cedex 1 (France)

2008-11-15

This article presents the framework of a mathematical formulation for modelling and evaluating natural gas pipeline networks under hydrogen injection. The model development is based on gas transport through pipelines and compressors which compensate for the pressure drops by implying mainly the mass and energy balances on the basic elements of the network. The model was initially implemented for natural gas transport and the principle of extension for hydrogen-natural gas mixtures is presented. The objective is the treatment of the classical fuel minimizing problem in compressor stations. The optimization procedure has been formulated by means of a nonlinear technique within the General Algebraic Modelling System (GAMS) environment. This work deals with the adaptation of the current transmission networks of natural gas to the transport of hydrogen-natural gas mixtures. More precisely, the quantitative amount of hydrogen that can be added to natural gas can be determined. The studied pipeline network, initially proposed in [1] is revisited here for the case of hydrogen-natural gas mixtures. Typical quantitative results are presented, showing that the addition of hydrogen to natural gas decreases significantly the transmitted power: the maximum fraction of hydrogen that can be added to natural gas is around 6 mass% for this example. (author)

1999 annual summary report on results. International clean energy network using hydrogen conversion (WE-NET)

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

The R and D were conducted on the international clean network (WE-NET) which aims at producing hydrogen by using renewable energy, converting it in a form suitable for transportation and supplying the hydrogen to places of quantity consumption of energy. The FY 1999 results were summed up. In the system evaluation, study was made on sodium carbonate electrolysis by-producing hydrogen, the supply amount by coke oven by-producing hydrogen and the economical efficiency, etc. As to the safety, study was made on the design of hydrogen supply stand model. Concerning the power generation technology, study was conducted on element technologies of injection valve, exhaust gas condenser, gas/liquid separator, etc. Relating to the hydrogen fueled vehicle system, the shock destructive testing, etc. were conducted on the hydrogen tank and hydrogen storage alloys. Besides, a lot of R and D were carried out of pure water use solid polymer fuel cells, hydrogen stand, hydrogen production technology, hydrogen transportation/storage technology, low temperature materials, transportation/storage using hydrogen storage alloys, innovative advanced technology, etc. (NEDO)

Gas supply from WCSB -- Matured more rapidly than expected

International Nuclear Information System (INIS)

Hawkins, D. J.

2003-01-01

A 2002 National Energy Board report forecast a decline in short-term gas deliverability from the Western Canadian Sedimentary Basin (WCSB) through 2004. However, this report contradicts a 1999 report which forecast a robust supply of natural gas through 2010. To obtain some clarity about the situation, this article undertakes an assessment of the information on gas supply in Alberta during the second half of the 1990s, in an attempt to account for the dramatic shift in outlook for gas supply in the WCSB by 2002. After a thorough examination of natural gas activities in the Basin during the 1990s, the author concludes that gas production in the WCSB has matured more rapidly than expected; moreover, there were clear indications that this might occur as early as the mid-1990s. Further curtailment in Alberta gas production might be expected as the debate on gas production in the Athabasca area heats up. The result of the assessment is that new resources of gas such as coal-bed methane and natural gas deposits in northeast British Columbia may come on stream, but governments will be challenged to provide incentives for sustaining gas pipeline activity in the WCSB. In the longer term there is potential for a gas pipeline from Alaska, but there is still much uncertainty about the route, line size, operating pressure, utilization of downstream pipelines and ultimate timing. In Canada, there is considerable support for a gas pipeline in the Mackenzie Valley, and plans for development are well advanced. 9 refs., 7 figs

Hydrogen extraction from liquid lithium-lead alloy by gas-liquid contact method

International Nuclear Information System (INIS)

Xie Bo; Weng Kuiping; Hou Jianping; Yang Guangling; Zeng Jun

2013-01-01

Hydrogen extraction experiment from liquid lithium-lead alloy by gas-liquid contact method has been carried out in own liquid lithium-lead bubbler (LLLB). Experimental results show that, He is more suitable than Ar as carrier gas in the filler tower. The higher temperature the tower is, the greater hydrogen content the tower exports. Influence of carrier gas flow rate on the hydrogen content in the export is jagged, no obvious rule. Although the difference between experimental results and literature data, but it is feasible that hydrogen isotopes extraction experiment from liquid lithium-lead by gas-liquid contact method, and the higher extraction efficiency increases with the growth of the residence time of the alloy in tower. (authors)

Hydrogen enriched gas production in a multi-stage downdraft gasification process

International Nuclear Information System (INIS)

Dutta, A.; Jarungthammachote, S.

2009-01-01

To achieve hydrogen enriched and low-tar producer gas, multi-stage air-blown and air-steam gasification were studied in this research. Results showed that the tar content from multi-stage air-blown and air-steam gasification was lower compared to the average value of that from downdraft gasification. It was also seen that an air-steam gasification process could potentially increase the hydrogen concentration in the producer gas in the expense of carbon monoxide; however, the summation of hydrogen and carbon monoxide in the producer gas was increased. (author)

Liquid hydrogen in Japan

Energy Technology Data Exchange (ETDEWEB)

Yasumi, S. [Iwatani Corp., Osaka (Japan). Dept. of Overseas Business Development

2009-07-01

Japan's Iwatani Corporation has focused its attention on hydrogen as the ultimate energy source in future. Unlike the United States, hydrogen use and delivery in liquid form is extremely limited in the European Union and in Japan. Iwatani Corporation broke through industry stereotypes by creating and building Hydro Edge Co. Ltd., Japan's largest liquid hydrogen plant. It was established in 2006 as a joint venture between Iwatani and Kansai Electric Power Group in Osaka. Hydro Edge is Japan's first combined liquid hydrogen and ASU plant, and is fully operational. Liquid oxygen, liquid nitrogen and liquid argon are separated from air using the cryogenic energy of liquefied natural gas fuel that is used for power generation. Liquid hydrogen is produced efficiently and simultaneously using liquid nitrogen. Approximately 12 times as much hydrogen in liquid form can be transported and supplied as pressurized hydrogen gas. This technology is a significant step forward in the dissemination and expansion of hydrogen in a hydrogen-based economy.

EU Security of Gas Supplies: Solidarity Runs Through the Pipeline

International Nuclear Information System (INIS)

Aoun, Marie-Claire; Rutten, Daan

2016-05-01

The ongoing efforts to lessen the European Union's (EU) vulnerability to gas shortages by adopting internal measures were triggered by the Ukrainian gas disputes of 2006 and 2009. The latter deprived several EU Member States of 20% of their gas supplies (30% of imports) for 14 days in the middle of winter due to tensions with Russia. This prompted Member States in 2010 to adopt a Regulation for the Security of Gas Supply, replacing the skeletal 2004 Directive. Since 2014, tensions have increased significantly between the EU and Russia, the block's main gas supplier. Although this has not led to any gas supply disruptions in Europe, and this time Ukraine has been able to revert to reverse flows, national production and storage withdrawals to replace the Russian gas flows, there remains a perceived elevated risk of gas supply disruptions to the EU, especially by certain Member States. This led the European Commission (EC) to publish its first-ever European Energy Security Strategy in May 2014, which was followed by the Gas Stress Tests of October 2014. In February 2015, the EC published its Energy Union Strategy Framework, which was strongly motivated by energy security concerns. In that context, the EC announced a series of proposals for its gas and electricity markets in 2016 and 2017, among which was the 'Sustainable Energy Security Package' (hereafter: Package). This Package, published in February 2016, consists of four proposals. Two of them have a legislative nature, namely a Regulation for Security of Gas Supply and a Decision on Intergovernmental Agreements on energy. The two non-legislative proposals are strategy papers dealing respectively with LNG and Gas Storage, and Heating and Cooling. The purpose of this paper is to focus on the proposed Regulation and to offer considerations on some of its provisions, in particular on the move from the national to the regional level of cooperation and on the legislative formalization of solidarity. (author)

Combustion characteristics of natural gas-hydrogen hybrid fuel turbulent diffusion flame

Energy Technology Data Exchange (ETDEWEB)

El-Ghafour, S.A.A.; El-dein, A.H.E.; Aref, A.A.R. [Mechanical Power Engineering Department, Faculty of Engineering, Suez Canal University, Port-Said (Egypt)

2010-03-15

Combustion characteristics of natural gas - hydrogen hybrid fuel were investigated experimentally in a free jet turbulent diffusion flame flowing into a slow co-flowing air stream. Experiments were carried out at a constant jet exit Reynolds number of 4000 and with a wide range of NG-H{sub 2} mixture concentrations, varied from 100%NG to 50%NG-50% H{sub 2} by volume. The effect of hydrogen addition on flame stability, flame length, flame structure, exhaust species concentration and pollutant emissions was conducted. Results showed that, hydrogen addition sustains a progressive improvement in flame stability and reduction in flame length, especially for relatively high hydrogen concentrations. Hydrogen-enriched flames found to have a higher combustion temperatures and reactivity than natural gas flame. Also, it was found that hydrogen addition to natural gas is an ineffective strategy for NO and CO reduction in the studied range, while a significant reduction in the %CO{sub 2} molar concentration by about 30% was achieved. (author)

Basic study on high temperature gas cooled reactor technology for hydrogen production

International Nuclear Information System (INIS)

Chang, Jong Hwa; Lee, W. J.; Lee, H. M.

2003-01-01

The annual production of hydrogen in the world is about 500 billion m 3 . Currently hydrogen is consumed mainly in chemical industries. However hydrogen has huge potential to be consumed in transportation sector in coming decades. Assuming that 10% of fossil energy in transportation sector is substituted by hydrogen in 2020, the hydrogen in the sector will exceed current hydrogen consumption by more than 2.5 times. Currently hydrogen is mainly produced by steam reforming of natural gas. Steam reforming process is chiefest way to produce hydrogen for mass production. In the future, hydrogen has to be produced in a way to minimize CO2 emission during its production process as well as to satisfy economic competition. One of the alternatives to produce hydrogen under such criteria is using heat source of high-temperature gas-cooled reactor. The high-temperature gas-cooled reactor represents one type of the next generation of nuclear reactors for safe and reliable operation as well as for efficient and economic generation of energy

Triboelectric Hydrogen Gas Sensor with Pd Functionalized Surface

Directory of Open Access Journals (Sweden)

Sung-Ho Shin

2016-10-01

Full Text Available Palladium (Pd-based hydrogen (H2 gas sensors have been widely investigated thanks to its fast reaction and high sensitivity to hydrogen. Various sensing mechanisms have been adopted for H2 gas sensors; however, all the sensors must be powered through an external battery. We report here an H2 gas sensor that can detect H2 by measuring the output voltages generated during contact electrification between two friction surfaces. When the H2 sensor, composed of Pd-coated ITO (indium tin oxide and PET (polyethylene Terephthalate film, is exposed to H2, its output voltage is varied in proportion to H2 concentration because the work function (WF of Pd-coated surface changes, altering triboelectric charging behavior. Specifically, the output voltage of the sensor is gradually increased as exposing H2 concentration increases. Reproducible and sensitive sensor response was observed up 1% H2 exposure. The approach introduced here can easily be adopted to development of triboelectric gas sensors detecting other gas species.

Recommendations on X80 steel for the design of hydrogen gas transmission pipelines

International Nuclear Information System (INIS)

Briottet, L.; Batisse, R.; De Dinechin, G.; Langlois, P.; Thiers, L.

2012-01-01

By limiting the pipes thickness necessary to sustain high pressure, high-strength steels could prove economically relevant for transmitting large gas quantities in pipelines on long distance. Up to now, the existing hydrogen pipelines have used lower-strength steels to avoid any hydrogen embrittlement. The CATHY-GDF project, funded by the French National Agency for Research, explored the ability of an industrial X80 grade for the transmission of pressurized hydrogen gas in large diameter pipelines. This project has developed experimental facilities to test the material under hydrogen gas pressure. Indeed, tensile, toughness, crack propagation and disc rupture tests have been performed. From these results, the effect of hydrogen pressure on the size of some critical defects has been analyzed allowing proposing some recommendations on the design of X80 pipe for hydrogen transport. Cost of Hydrogen transport could be several times higher than natural gas one for a given energy amount. Moreover, building hydrogen pipeline using high grade steels could induce a 10 to 40% cost benefit instead of using low grade steels, despite their lower hydrogen susceptibility. (authors)

Manufacturing Competitiveness and Supply Chain Analyses for Hydrogen Refueling Stations

Energy Technology Data Exchange (ETDEWEB)

Mayyas, Ahmad T [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Garland, Nancy [U.S. Department of Energy

2018-04-27

This slide deck was presented in the monthly FCTO webinar series (May 2017). The goal of this presentation was to share our latest results and remarks on the manufacturing competitiveness analysis of the hydrogen refueling stations (HRS). Manufacturing cost models were developed for major systems in the HRS such as compressors, storage tanks, chillers, heat exchangers, and dispensers. In addition to the cost models, we also discussed important remarks from our analysis for the international trade flows and global supply chain for the hydrogen refueling stations. The last part of the presentation also highlights effect of economies of scale and high production volumes on lowering the cost of the hydrogen at the pump.

Forecasting: Canada's NGL [natural gas liquids] supply outlook

International Nuclear Information System (INIS)

Anderson, A.B.

1992-01-01

A perspective is given on Canada's supply and demand balance of ethane, propane, and butane, and Canada's participation in meeting the expected increases in United States import requirements. Increases in Canadian natural gas liquids (NGL) supply depends on increases in natural gas production. Since new production (except for the Shell Caroline gas discovery) is tending to have lower yields of liquids, NGL supply will not increase as much as the increase in natural gas production. Nearly 50% of Canadian NGLs are produced in straddle plants located at the inlet of gas transmission lines. Surpluses of ethane and high capital costs means that new straddle plants will not be built in the near future, but expansions of existing plants will occur to maximize propane and butane production. The potential ethane supply will increase, notably from the Shell Caroline project. The primary market for ethane in Canada is the Alberta petrochemical industry, and a new ethylene plant to be started up in 1994 will increase demand. The use of ethane for miscible flooding will decrease to the end of the decade. Propane production is expected to increase to a total of 180,000 bbl/d by 2000; demand growth in traditional markets such as heating and cooking is expected to be marginal, and the petrochemical sector is expected to show the largest growth in propane demand. The use of butane for producing methyl tertiary butyl ether is expected to increase butane demand for the rest of the decade. Exports of NGL to the USA are largely via the Cochin pipeline system. Modest increases in NGL exports are expected. A number of gas pipeline projects are at various stages of planning, and completion of these projects would enable an increase in Canadian exports. 8 figs

Reducing greenhouse gas emissions through operations and supply chain management

International Nuclear Information System (INIS)

Plambeck, Erica L.

2012-01-01

The experiences of the largest corporation in the world and those of a start-up company show how companies can profitably reduce greenhouse gas emissions in their supply chains. The operations management literature suggests additional opportunities to profitably reduce emissions in existing supply chains, and provides guidance for expanding the capacity of new “zero emission” supply chains. The potential for companies to profitably reduce emissions is substantial but (without effective climate policy) likely insufficient to avert dangerous climate change. - Highlights: ► Describes how firms are profitably reducing greenhouse gas emissions in their supply chains ► Highlights academic literature relevant to supply chain emission reduction

Strategic gas reserves and EU security-of-supply

International Nuclear Information System (INIS)

Austvik, Ole Gunnar

2003-01-01

The author attempts to distinguish a country's ''normal'' dependence on imports of a commodity from sensitivity and vulnerability dependence. We will then discuss how the risk for disruptions in supplies may be viewed as an externality in imports and, thus, consumption of gas. The model presented demonstrates how environmental externalities as a result of increased domestic production can be evaluated together with the security-of-supply problem. Finally, it is discussed how gas reserves can be used as a means in an emergency situation

Civil unrest in North Africa—Risks for natural gas supply?

International Nuclear Information System (INIS)

Lochner, Stefan; Dieckhöner, Caroline

2012-01-01

The uprising and military confrontation in Libya that began in February 2011 has led to disruptions of gas supplies to Europe. An analysis of how Europe has compensated for these missing gas volumes shows that this situation has not affected security of supply. However, this situation would change if the North African uprising were to spread to Algeria. Since Algeria is a much more important gas supplier to Europe than is Libya, more severe consequences would be likely. Applying a natural gas infrastructure model, we investigate the impact of supplier disruptions from both countries for a summer and winter period. Our analysis shows that disruptions in the low-demand summer months could be compensated for, mainly by LNG imports into several European countries. An investigation of a similar situation at the beginning of the winter shows that security of supply would be severely compromised and that disruptions to Italian consumers would be unavoidable. The analysis thereby highlights the importance of taking the political stability of supply countries into account when assessing the security of European gas imports. - Highlights: ► Impact of political instability on security of natural gas supplies. ► Analysis of export stop during Libyan civil war in 2011. ► Model-based analysis of potential future North African crisis scenarios. ► Findings: spread of uprisings to Algeria more critical for Europe. ► Price effects and potential demand curtailment for consumers.

A comparative economic assessment of hydrogen production from coke oven gas, water electrolysis and steam reforming of natural gas

International Nuclear Information System (INIS)

Nguyen, Y.V.; Ngo, Y.A.; Tinkler, M.J.; Cowan, N.

2003-01-01

This paper presents the comparative economics of producing hydrogen for the hydrogen economy by recovering it from waste gases from the steel industry, by water electrolysis and by conventional steam reforming of natural gas. Steel makers produce coke for their blast furnace operation by baking coal at high temperature in a reduced environment in their coke ovens. These ovens produce a coke oven gas from the volatiles in the coal. The gas, containing up to 60% hydrogen, is commonly used for its heating value with some of it being flared. The feasibility of recovering this hydrogen from the gas will be presented. A comparison of this opportunity with that of hydrogen from water electrolysis using low cost off-peak electricity from nuclear energy will be made. The impact of higher daily average electricity rate in Ontario will be discussed. The benefits of these opportunities compared with those from conventional steam reforming of natural gas will be highlighted. (author)

Hydrodesulphurization of Light Gas Oil using hydrogen from the Water Gas Shift Reaction

Science.gov (United States)

Alghamdi, Abdulaziz

2009-12-01

The production of clean fuel faces the challenges of high production cost and complying with stricter environmental regulations. In this research, the ability of using a novel technology of upgrading heavy oil to treat Light Gas Oil (LGO) will be investigated. The target of this project is to produce cleaner transportation fuel with much lower cost of production. Recently, a novel process for upgrading of heavy oil has been developed at University of Waterloo. It is combining the two essential processes in bitumen upgrading; emulsion breaking and hydroprocessing into one process. The water in the emulsion is used to generate in situ hydrogen from the Water Gas Shift Reaction (WGSR). This hydrogen can be used for the hydrogenation and hydrotreating reaction which includes sulfur removal instead of the expensive molecular hydrogen. This process can be carried out for the upgrading of the bitumen emulsion which would improve its quality. In this study, the hydrodesulphurization (HDS) of LGO was conducted using in situ hydrogen produced via the Water Gas Shift Reaction (WGSR). The main objective of this experimental study is to evaluate the possibility of producing clean LGO over dispersed molybdenum sulphide catalyst and to evaluate the effect of different promoters and syn-gas on the activity of the dispersed Mo catalyst. Experiments were carried out in a 300 ml Autoclave batch reactor under 600 psi (initially) at 391°C for 1 to 3 hours and different amounts of water. After the hydrotreating reaction, the gas samples were collected and the conversion of carbon monoxide to hydrogen via WGSR was determined using a refinery gas analyzer. The sulphur content in liquid sample was analyzed via X-Ray Fluorescence. Experimental results showed that using more water will enhance WGSR but at the same time inhibits the HDS reaction. It was also shown that the amount of sulfur removed depends on the reaction time. The plan is to investigate the effect of synthesis gas (syngas

Middle east gas: supply source of Europe

International Nuclear Information System (INIS)

Vivies, P. de

1995-01-01

The evolution of gas demand, the decreasing of reserves leads to the question of European future needs satisfaction. The european market can call on the russian production or middle east production. Iran has the most important reserves but the needs of the population can limit the gas supply. Yemen and Oman which have less important reserves but also less important needs to satisfy can be a serious alternative; Abu dhabi reserves are destined to asia market. The qatar has the most important gas offshore field in the world. The LNG (liquefied natural gas) seems to have a better position than gas pipeline to dispatch gas towards Europe

Effects of hydrogen mixture into helium gas on deuterium removal from lithium titanate

Energy Technology Data Exchange (ETDEWEB)

Tsuchiya, Akihito, E-mail: tsuchiya@frontier.hokudai.ac.jp [Laboratory of Plasma Physics and Engineering, Hokkaido University, Kita-13, Nishi-8, Kita-ku, Sapporo 060-8628 (Japan); Hino, Tomoaki; Yamauchi, Yuji; Nobuta, Yuji [Laboratory of Plasma Physics and Engineering, Hokkaido University, Kita-13, Nishi-8, Kita-ku, Sapporo 060-8628 (Japan); Akiba, Masato; Enoeda, Mikio [Japan Atomic Energy Agency, 801-1, Mukoyama, Naka 311-0193 (Japan)

2013-10-15

Lithium titanate (Li{sub 2}TiO{sub 3}) pebbles were irradiated with deuterium ions with energy of 1.7 keV and then exposed to helium or helium–hydrogen mixed gas at various temperatures, in order to evaluate the effects of gas exposure on deuterium removal from the pebbles. The amounts of residual deuterium in the pebbles were measured by thermal desorption spectroscopy. The mixing of hydrogen gas into helium gas enhanced the removal amount of deuterium. In other words, the amount of residual deuterium after the helium–hydrogen mixed gas exposure at lower temperature was lower than that after the helium gas exposure. In addition, we also evaluated the pebbles exposed to the helium gas with different hydrogen mixture ratio from 0% to 1%, at 573 K. Although the amount of residual deuterium in the pebbles after the exposure decreased with increasing the hydrogen mixture ratio, the implanted deuterium partly remained after the exposure. These results suggest that the tritium inventory may occur at low temperature region in the blanket during the operation.

Demand and supply in Russian gas market

International Nuclear Information System (INIS)

Milovidov, K.N.

1997-01-01

The big volume of gas supplies for current and future energy and natural gas balances in Russia is important to understand the likely future dynamics of demand for gas. The path of future demand in Russia is uncertain and the range of possible scenarios is wide. For creating the new gas consumption structure, more deep diversification and development of the gas distribution systems, large investments and considerable periods of time are necessary. The factors usually studied in detail in the conditions of market economy can not be used here as a basis for strategic planning due to several reasons. (R.P.)

Long term outlook for gas supply and demand 2007-2030

International Nuclear Information System (INIS)

2010-05-01

Given the economic crisis and the even greater focus of energy policy in recent years on energy efficiency and renewables, earlier expectations in respect of gas demand have to be lowered. Nonetheless, there are still good prospects for gas expanding its position in the EU energy market in the medium to long term. Environmental friendliness and highly efficient technologies in all areas of energy supply give gas a key role in a realistic EU climate policy, the goals of which cannot be achieved solely through increased use of renewables. Its green qualities make gas attractive in direct utilisation in homes and businesses, in centralised power generation, in local CHP plant (including micro-CHP), and - in some member states - in the transport sector too. The current slump in demand is accompanied by strong supply pressure on European procurement markets. Experts do not predict that the present excess supply situation will continue in the long term. It is expected that imports to Europe will rise in order to compensate for the impending fall in domestic European production and to supply additional gas. The procurement challenge cannot be considered in isolation from global developments. The increasing demand for gas worldwide will intensify the competition for global gas reserves on international markets. The European gas industry emphasises the importance of fostering long-term relationships with major suppliers, transit countries and key partners in the EU as well as with multilateral organisations and structures.

Industrial natural gas supply options in British Columbia

International Nuclear Information System (INIS)

1994-01-01

Information is provided on the availability and cost of natural gas in British Columbia for use by firms interested in establishing gas-intensive industrial facilities in the province. British Columbia has an abundant supply of natural gas, originating mainly from deposits in the westernmost part of the Western Canadian Sedimentary Basin in the northeast part of the province. Recoverable resources in British Columbia are estimated at 1,000-1,400 billion m 3 . Over 200 producers compete to sell natural gas for both domestic and export markets. Gathering, processing, and transmission of the gas is undertaken mainly by the Westcoast Energy pipeline system, and distribution is undertaken by several distribution utilities. At present, all large industrial gas users buy their firm gas requirements directly from gas producers, often using gas marketers or brokers to assist in purchasing. Regulation of the gas industry is performed by the British Columbia Utilities Commission, which sets rules for energy supply contracts, and by the National Energy Board, which sets tolls for gathering, processing, and transporting gas. Factors affecting gas pricing are discussed, with reference to both the wellhead price and the cost of gathering, processing, and transportation. Firm gas costs for two hypothetical industrial loads in British Columbia are illustrated. Potential intensive uses of natural gas in the province are outlined, including power generation, liquefaction for export, manufacturing, production of direct reduced iron, and as petrochemical feedstocks. 5 figs., 2 tabs

PALLADIUM DOPED TIN OXIDE BASED HYDROGEN GAS SENSORS FOR SAFETY APPLICATIONS

International Nuclear Information System (INIS)

Kasthurirengan, S.; Behera, Upendra; Nadig, D. S.

2010-01-01

Hydrogen is considered to be a hazardous gas since it forms a flammable mixture between 4 to 75% by volume in air. Hence, the safety aspects of handling hydrogen are quite important. For this, ideally, highly selective, fast response, small size, hydrogen sensors are needed. Although sensors based on different technologies may be used, thin-film sensors based on palladium (Pd) are preferred due to their compactness and fast response. They detect hydrogen by monitoring the changes to the electrical, mechanical or optical properties of the films. We report the development of Pd-doped tin-oxide based gas sensors prepared on thin ceramic substrates with screen printed platinum (Pt) contacts and integrated nicrome wire heaters. The sensors are tested for their performances using hydrogen-nitrogen gas mixtures to a maximum of 4%H 2 in N 2 . The sensors detect hydrogen and their response times are less than a few seconds. Also, the sensor performance is not altered by the presence of helium in the test gas mixtures. By the above desired performance characteristics, field trials of these sensors have been undertaken. The paper presents the details of the sensor fabrication, electronic circuits, experimental setup for evaluation and the test results.

Fiscal 1975 Sunshine Project research report. General research on hydrogen energy subsystems and their peripheral technologies (Research on hydrogen gas turbine); 1975 nendo suiso riyo subsystem no sogoteki kento to shuhen gijutsu ni kansuru kenkyu seika hokokusho. Suiso gas turbine ni kansuru kenkyu

Energy Technology Data Exchange (ETDEWEB)

NONE

1976-03-31

This research aims at establishment of the meaning of using hydrogen as gas turbine fuel in the hydrogen energy system and various conditions for hydrogen gas turbines, and approaches to the feasibility study and R and D of hydrogen gas turbines in the future. In fiscal 1975, researches were made on (1) feasibility study on hydrogen-oxygen gas turbine, (2) establishment of various conditions for technical, social and economic realization of hydrogen gas turbines in the total energy system, and (3) study on technical troubles to be solved for realization of hydrogen gas turbines. For the above researches, study was made on hydrogen combustion based on the hydrogen combustion test result of gas mixture including hydrogen, and on the feasibility of aphodid cycle. In addition, study on the applicability of hydrogen-oxygen gas turbines, comparative study on hydrogen-oxygen gas turbine, MHD power generation and fuel cell, and the future prospect of hydrogen gas turbines for ships were made to place this hydrogen gas turbine. (NEDO)

Norwegian gas supplies for the European market

International Nuclear Information System (INIS)

Hansen, B.L.

1994-01-01

The conference paper deals with the Norwegian key role in the European gas market with increasing market shares. The supply capacity in a long-term perspective can be 65-70 bcm/year or more if export prices support the development of new and more costly gas resources. The main challenges for the Norwegian shelf are discussed. 5 figs

Security of gas supply in open markets. LNG and power at a turning point

International Nuclear Information System (INIS)

2004-01-01

Since the 'IEA Study on Security of Gas Supply' was published in 1995, many member countries have started to open their gas and electricity markets to competition. Governments progressively withdrew from directly managing the gas sector; they concentrate now on setting objectives and the framework for competition. With the continued growth of gas demand and the decline of domestic reserves, most IEA countries have to import more gas, mainly for power generation. This requires access to gas reserves at competitive conditions, as well as timely investment in new infrastructure to ensure a reliable gas supply. Reform has led to open markets, where supply and demand are balanced by the market. In the gas sector, supply is capacity-bound and large parts of the demand side are inelastic. The study looks at how governments and other stakeholders in IEA countries respond to the need to create a framework that enables the players to deliver secure and reliable gas supply at the border and all the way down to the final customer. This book analyses the most recent developments in security of gas supply and reliability in all IEA regions in the context of open markets and in view of the new demand and supply trends. A CD-Rom featuring the positions of the main stakeholders (governments, regulators, industry, customers and other organisations) is included with the publication. 'Security of Gas Supply in Open Markets' is a follow-up of 'Flexibility in Natural Gas Supply and Demand' in the IEA series on energy market reforms

Rapid hydrogen gas generation using reactive thermal decomposition of uranium hydride.

Energy Technology Data Exchange (ETDEWEB)

Kanouff, Michael P.; Van Blarigan, Peter; Robinson, David B.; Shugard, Andrew D.; Gharagozloo, Patricia E.; Buffleben, George M.; James, Scott Carlton; Mills, Bernice E.

2011-09-01

Oxygen gas injection has been studied as one method for rapidly generating hydrogen gas from a uranium hydride storage system. Small scale reactors, 2.9 g UH{sub 3}, were used to study the process experimentally. Complimentary numerical simulations were used to better characterize and understand the strongly coupled chemical and thermal transport processes controlling hydrogen gas liberation. The results indicate that UH{sub 3} and O{sub 2} are sufficiently reactive to enable a well designed system to release gram quantities of hydrogen in {approx} 2 seconds over a broad temperature range. The major system-design challenge appears to be heat management. In addition to the oxidation tests, H/D isotope exchange experiments were performed. The rate limiting step in the overall gas-to-particle exchange process was found to be hydrogen diffusion in the {approx}0.5 {mu}m hydride particles. The experiments generated a set of high quality experimental data; from which effective intra-particle diffusion coefficients can be inferred.

Hydrogen production system coupled with high-temperature gas-cooled reactor (HTTR)

International Nuclear Information System (INIS)

Shiozawa, Shusaku

2003-01-01

On the HTTR program, R and D on nuclear reactor technology and R and D on thermal application technology such as hydrogen production and so on, are advanced. When carrying out power generation and thermal application such as hydrogen production and so on, it is, at first, necessary to supply nuclear heat safely, stably and in low cost, JAERI carries out some R and Ds on nuclear reactor technology using HTTR. In parallel to this, JAERI also carries out R and D for jointing nuclear reactor system with thermal application systems because of no experience in the world on high temperature heat of about 1,000 centigrade supplied by nuclear reactor except power generation, and R and D on thermochemical decomposition method IS process for producing hydrogen from water without exhaust of carbon dioxide. Here were described summaries on R and D on nuclear reactor technology, R and D on jointing technology using HTTR hydrogen production system, R and D on IS process hydrogen production, and comparison hydrogen production with other processes. (G.K.)

Hydrogen application dynamics and networks

Energy Technology Data Exchange (ETDEWEB)

Schmidt, E. [Air Liquide Large Industries, Champigny-sur-Marne (France)

2010-12-30

The Chemical Industry consumes large volumes of hydrogen as raw material for the manufacture of numerous products (e.g. polyamides and polyurethanes account for 60% of hydrogen demand). The hydrogen demand was in the recent past and will continue to be driven by the polyurethane family. China will host about 60% of new hydrogen needs over the period 2010-2015 becoming the first hydrogen market next year and reaching 25% of market share by 2015 (vs. only 4% in 2001). Air Liquide supplies large volumes of Hydrogen (and other Industrial Gases) to customers by on-site plants and through pipeline networks which offer significant benefits such as higher safety, reliability and flexibility of supply. Thanks to its long term strategy and heavy investment in large units and pipeline networks, Air Liquide is the Industrial Gas leader in most of the world class Petrochemical basins (Rotterdam, Antwerp, US Gulf Coast, Yosu, Caojing,..) (orig.)

Device for removing hydrogen gas from the safety containment vessel of a nuclear reactor

International Nuclear Information System (INIS)

Stiefel, M.

1983-01-01

The safe processing of all concentrations of gas mixtures should be possible with such a device using a thermal recombiner of compact construction. A recombiner consisting of a metal case and diverter sheets situated in it is heated by induction. The incoming pipe for the gas mixture enriched with hydrogen and the outgoing pipe for the gas mixture with low hydrogen content are connected together by a three way valve. The third connection to the safety valve takes the larger port of the gas mixture with low hydrogen content back to the safety containment vessel. Sufficient amount of the gas mixture with low hydrogen content is taken via the three way valve to the safety containment vessel to ensure that the hydrogen content of the gas mixture taken to the recombiner remains below the 4% by volume limit. (orig./PW)

The security of gas supply-a critical issue for Europe?

International Nuclear Information System (INIS)

Weisser, Hellmuth

2007-01-01

Gas is competing with oil for being the dominant energy source. In electricity generation gas is to play as pivotal a role as oil in transportation. The security equation of gas and electricity become unseparably interrelated. Energy disruptions have considerable influence on the national accounts far beyond the direct cost of market participants (asymmetry). The present gas supply to the EU depends dangerously on too few sources and venues. There is a decided lack of optionality. The EU directly or through its members needs a clear proactive policy on 'Security of Gas Supply' with a strong multilateral direction. The measures developed for the oil industry over the last 30 years can at least serve as a starting point for a constructive debate. When discussing security of supply dependence it is useful to clearly define the various risks one wishes to protect against. Free riders relying on alternative fuels without participating in their security systems are not permissible

Improved Hydrogen Gas Getters for TRU Waste -- Final Report

International Nuclear Information System (INIS)

Mark Stone; Michael Benson; Christopher Orme; Thomas Luther; Eric Peterson

2005-01-01

Alpha radiolysis of hydrogenous waste and packaging materials generates hydrogen gas in radioactive storage containers. For that reason, the Nuclear Regulatory Commission limits the flammable gas (hydrogen) concentration in the Transuranic Package Transporter-II (TRUPACT-II) containers to 5 vol% of hydrogen in air, which is the lower explosion limit. Consequently, a method is needed to prevent the build up of hydrogen to 5 vol% during the storage and transport of the TRUPACT-II containers (up to 60 days). One promising option is the use of hydrogen getters. These materials scavenge hydrogen from the gas phase and irreversibly bind it in the solid phase. One proven getter is a material called 1,4-bis (phenylethynyl) benzene, or DEB, characterized by the presence of carbon-carbon triple bonds. Carbon may, in the presence of suitable precious metal catalysts such as palladium, irreversibly react with and bind hydrogen. In the presence of oxygen, the precious metal may also eliminate hydrogen by catalyzing the formation of water. This reaction is called catalytic recombination. DEB has the needed binding rate and capacity for hydrogen that potentially could be generated in the TRUPACT II. Phases 1 and 2 of this project showed that uncoated DEB performed satisfactorily in lab scale tests. Based upon these results, Phase 3, the final project phase, included larger scale testing. Test vessels were scaled to replicate the ratio between void space in the inner containment vessel of a TRUPACT-II container and a payload of seven 55-gallon drums. The tests were run with an atmosphere of air for 63.9 days at ambient temperature (15-27 C) and a scaled hydrogen generation rate of 2.60E-07 moles per second (0.35 cc/min). A second type of getter known as VEI, a proprietary polymer hydrogen getter characterized by carbon-carbon double bonds, was also tested in Phase 3. Hydrogen was successfully ''gettered'' by both getter systems. Hydrogen concentrations remained below 5 vol% (in

Improved Hydrogen Gas Getters for TRU Waste -- Final Report

Energy Technology Data Exchange (ETDEWEB)

Mark Stone; Michael Benson; Christopher Orme; Thomas Luther; Eric Peterson

2005-09-01

Alpha radiolysis of hydrogenous waste and packaging materials generates hydrogen gas in radioactive storage containers. For that reason, the Nuclear Regulatory Commission limits the flammable gas (hydrogen) concentration in the Transuranic Package Transporter-II (TRUPACT-II) containers to 5 vol% of hydrogen in air, which is the lower explosion limit. Consequently, a method is needed to prevent the build up of hydrogen to 5 vol% during the storage and transport of the TRUPACT-II containers (up to 60 days). One promising option is the use of hydrogen getters. These materials scavenge hydrogen from the gas phase and irreversibly bind it in the solid phase. One proven getter is a material called 1,4-bis (phenylethynyl) benzene, or DEB, characterized by the presence of carbon-carbon triple bonds. Carbon may, in the presence of suitable precious metal catalysts such as palladium, irreversibly react with and bind hydrogen. In the presence of oxygen, the precious metal may also eliminate hydrogen by catalyzing the formation of water. This reaction is called catalytic recombination. DEB has the needed binding rate and capacity for hydrogen that potentially could be generated in the TRUPACT II. Phases 1 and 2 of this project showed that uncoated DEB performed satisfactorily in lab scale tests. Based upon these results, Phase 3, the final project phase, included larger scale testing. Test vessels were scaled to replicate the ratio between void space in the inner containment vessel of a TRUPACT-II container and a payload of seven 55-gallon drums. The tests were run with an atmosphere of air for 63.9 days at ambient temperature (15-27°C) and a scaled hydrogen generation rate of 2.60E-07 moles per second (0.35 cc/min). A second type of getter known as VEI, a proprietary polymer hydrogen getter characterized by carbon-carbon double bonds, was also tested in Phase 3. Hydrogen was successfully “gettered” by both getter systems. Hydrogen concentrations remained below 5 vol% (in

The importance of North Sea gas to European energy supply

International Nuclear Information System (INIS)

Probert, R.

1992-01-01

Natural gas can, of course, be transported over very long distances but, because of the economics of gas transmission, its impact is most often local. This has certainly been the case with North Sea gas, which has clearly contributed significantly to European energy supply and will continue to do so for some time to come. The historical importance of the discovery of gas in the North Sea has been that it has enabled natural gas industries to grow rapidly in North West Europe. Without North Sea gas and Dutch gas it is difficult to see how town gas would have been replaced in North West Europe. Certainly, a much smaller natural gas industry would have emerged. North Sea gas has inevitably had the greatest impact on gas markets in the countries of the European Community and this will remain the case in future. Nevertheless, it is inevitable that gas will, in future, flow across more national boundaries than in the past, and that North Sea gas will have an important part to play in meeting the Central European demand for competitively priced, secure supplies. This paper discusses the United Kingdom market for gas and future demand both in the United Kingdom and more widely in Europe. An examination of the availability of gas supplies from the North Sea suggests that it is unlikely that there will be a surplus of gas for export from the United Kingdom continental shelf. Norway will remain the main source of exports, with the Netherlands also in a strong position. Transportation and political aspects are also considered. (author)

Supply and demand of natural gas in the world and in Europe

International Nuclear Information System (INIS)

Rissik, S.A.

1992-01-01

Based on data from the July 1991 published report of the International Gas Union (IGU) committee Supply and Demand an overview is given of the expectations for the natural gas supply, with special attention to Western Europe and the late Soviet Union. Data are presented for natural gas reserves and natural gas supply and demand in Eastern Europe (mainly USSR), Western Europe, North America (USA and Canada), and reserves in the Middle East. The conclusions drawn concern mainly Western Europe. It appears that the natural gas supplies in the world are still very large and sufficient for decades. Western Europe however must rely on foreign reserves more and more, which will have an impact on the natural gas prices. The reserves in the Soviet Union (mainly Siberia and the Arctic area) will be of great importance to the West European countries. 6 figs., 4 ill

Nitrogen gas supply device in nuclear power plant

International Nuclear Information System (INIS)

Nishino, Masami

1991-01-01

The present invention concerns a nitrogen gas supply device in a nuclear power plant for supplying nitrogen gases to a reactor container and equipments working with the nitrogen gas as the load. A liquid nitrogen storage pool is disposed to a concrete nuclear buildings and has a two-vessel structure of inner and outer vessels, in which heat insulators are disposed between the inner and the outer vessels. Further, the nitrogen gas supply mechanism is disposed in an evaporation chamber disposed in adjacent with the liquid nitrogen storage pool in the reator building. Accordingly, since liquid nitrogen is stored in the liquid nitrogen storage pool having a structure surrounded by concrete walls, direct sunlight is completely interrupted, thereby enabling to prevent the heat caused by the direct sunlight from conducting to the liquid nitrogen. Further, since the outer vessel is not exposed to the surrounding atmosphere, heat conduction rate relative to the external air is small. This can reduce the amount of liquid nitrogen released to the atmospheric air due to natural evaporation. (I.N.)

Construction and performance testing of a secondary cooling system with hydrogen gas (I)

International Nuclear Information System (INIS)

Hishida, M.; Nekoya, S.; Takizuka, T.; Emori, K.; Ogawa, M.; Ouchi, M.; Okamoto, Y.; Sanokawa, K.; Nakano, T.; Hagiwara, T.

1979-08-01

An experimental multi-purpose High-Temperature Gas Cooled Reactor (VHTR) which is supposed to be used for a direct steel-making is now being developed in JAeRI. In order to simulate the heat exchanging system between the primary helium gas and the secondary reducing gas system of VHTR, a hydrogen gas loop was constructed as a secondary cooling system of the helium gas loop. The maximum temperature and the maximum pressure of the hydrogen gas are 900 degrees C and 42 kg/cm 2 x G respectively. The construction of the hydrogen gas loop was completed in January, 1977, and was successfully operated for 1.000 h. Various performance tests, such as the hydrogen permeation test of a He/H2 heat exchanger and the thermal performance test of heat exchangers, were made. Especially, it was proved that hydrogen permeation rate through the heat exchanger was reduced to 1/30 to approximately 1/50 by a method of calorized coating, and the coating was stable during 1.000 h's operation. It was also stable against the temperature changes. This report describes the outline of the facility and performance of the components. (orig.) [de

Producing hydrogen from coke-oven gas: the Solmer project. [PSA process

Energy Technology Data Exchange (ETDEWEB)

Bernard, G; Vidal, J

1984-05-01

After presenting the energy situation at the Solmer plant, where coke-oven gas is produced to excess, the authors examine the technical and economic possibilities of utilizing this gas for hydrogen extraction. They describe a project (based on the PSA process) for producing some 65 t/d of hydrogen and present the technical features of the scheme. An evaluation of the energy and financial costs of producing the hydrogen confirms the competitive status of the process.

Density evaluation of remotely-supplied hydrogen radicals produced via tungsten filament method for SiCl4 reduction

Science.gov (United States)

Zohra Dahmani, Fatima; Okamoto, Yuji; Tsutsumi, Daiki; Ishigaki, Takamasa; Koinuma, Hideomi; Hamzaoui, Saad; Flazi, Samir; Sumiya, Masatomo

2018-05-01

Effect of the hydrogen radical on the reduction of a silicon tetrachloride (SiCl4) source was studied. The hydrogen radicals were generated using a tungsten (W) filament in a generation chamber, and were remotely supplied to another reaction chamber. The density of the hydrogen radical was estimated from the optical transmittance of 600-nm-wavelength light through phosphate glass doped with tungsten oxide (WO3). Lifetime of the hydrogen radical seemed sufficiently long, and its density as supplied to the reaction chamber was estimated to be on the order of 1012 cm‑3. Signal intensity of the peak corresponding to SiCl4 (m/z = 170) detected by quadrupole-mass measurement was confirmed to decrease owing to the reaction with the remotely-supplied hydrogen radical. This indicates the possibility that chemically-stable SiCl4, as one of the by-products of the Siemens process, can be reduced to produce silicon.

Market opening: how will European gas supply evolve?

International Nuclear Information System (INIS)

Delon, Ch.

1999-01-01

With the implementation of the gas directive, European gas companies are facing many new challenges. Some concern the upstream gas sector in particular, notably with the new rules of competition in Europe, the changes in the structure of gas industries and their adaptation to the new Europe-wide market. For this first round table to the 116. gas conference, chaired by Sophie Mayeux, journalist and editor of the Est Eco journal, four representatives of major European companies and one representative of the banking sector examined the possible future scenarios for gas supply in Europe. (authors)

North american natural gas supply forecast: the Hubbert method including the effects of institutions

International Nuclear Information System (INIS)

Reynolds, D. B.; Kolodziej, M.

2009-01-01

In this article, the U.S. and southern Canadian natural gas supply market is considered. An important model for oil and natural gas supply is the Hubbert curve. Not all regions of the world are producing oil or natural gas following a Hubbert curve, even when price and market conditions are accounted for. One reason is that institutions are affecting supply. We investigate the possible effects of oil and gas market institutions in North America on natural gas supply. A multi-cycle Hubbert curve with inflection points similar to the Soviet Union's oil production multi-cycle Hubbert curve is used to determine North American natural gas discovery rates and to analyze how market specific institutions caused the inflection points. In addition, we analyze the latest shale natural gas projections critically. While currently, unconventional resources of natural gas suggest that North American natural gas production will increase without bound, the model here suggests a peak in North American natural gas supplies could happen in 2013. (author)

Transport of a relativistic electron beam through hydrogen gas

International Nuclear Information System (INIS)

Haan, P. de.

1981-01-01

In this thesis the author describes the transport properties of an electron beam through vacuum and through hydrogen gas with pressure ranging from 25 to 1000 Pa. Maximum beam energy and current are 0.8 MeV and 6 kA, respectively. The pulse length is around 150 ns. A description is given of the experimental device. Also the diagnostics for probing the beam and the plasma, produced by the beam, are discussed, as well as the data acquisition system. The interaction between the beam and hydrogen gas with a pressure around 200 Pa is considered. A plasma with density around 10 19 m -3 is produced within a few nanoseconds. Measurements yield the atomic hydrogen temperature, electron density, beam energy loss, and induced plasma current and these are compared with the results of a model combining gas ionization and dissociation, and turbulent plasma heating. The angular distribution of the beam electrons about the magnetic field axis is discussed. (Auth.)

Hydrogen Gas Production in a Stand-Alone Wind Farm

Directory of Open Access Journals (Sweden)

M. Naziry Kordkandy

2017-04-01

Full Text Available This paper is analyzing the operation of a stand-alone wind farm with variable speed turbines, permanent magnet synchronous generators (PMSG and a system for converting wind energy during wind speed variations. On this paper, the design and modeling of a wind system which uses PMSG’s to provide the required power of a hydrogen gas electrolyzer system, is discussed. This wind farm consists of three wind turbines, boost DC-DC converters, diode full bridge rectifiers, permanent magnet synchronous generators, MPPT control and a hydrogen gas electrolyzer system. The MPPT controller based on fuzzy logic is designed to adjust the duty ratio of the boost DC-DC converters to absorb maximum power. The proposed fuzzy logic controller assimilates, with (PSF MPPT algorithm which generally used to absorb maximum power from paralleled wind turbines and stores it in form of hydrogen gas. The system is modeled and its behavior is studied using the MATLAB software.

Electricity and gas supplies under pressure. 2005 winter

International Nuclear Information System (INIS)

Lewiner, C.; David, P.; Coquet, P.

2005-10-01

Point of view on the demand for electricity and gas in light of European deregulation in 2005. Demand for electricity and gas by consumers and businesses soared to record highs as temperatures continued to fall steeply across Europe in January and February 2005. While unexpected seasonal trends have always had a major impact on electricity and gas supplies, this time, it occurred at a time when deregulation across all European markets is bringing new complexity notably in pricing and availability of supply. So what conclusions can be drawn from this acute market situation? Is deregulation delivering what it promised? What are the possible impacts on the business model of suppliers? What trends are we likely to observe in response to the challenges of operating in the new deregulated market place?

The generalized model of organization and planning of regional gas supply monitoring

Directory of Open Access Journals (Sweden)

Maria V. Shevchenko

2015-12-01

Full Text Available At the moment, gas is one of the most promising types of fuel in Ukraine. In this regard, the problems associated with its transportation in the regional system of gas supply are relevant. Now it is not completely solved and needs detailed study the problem of monitoring the regional gas supply system. Aim: The aim of the study is to improve the efficiency of the regional gas supply system at the expense of the organization and planning of gas transport monitoring and, in the future, the synthesis of the monitoring system of regional gas supply. Materials and Methods: The generalized model of organization and planning of monitoring regional gas suppliers were developed to achieve this goal. It allows making decisions on the organization of the monitoring system. In addition, this model makes it possible to plan under conditions of multicriteriality and uncertainty of the source data. Results: The basic criteria and constraints for solving the problem of organizing and planning the monitoring system of regional gas supply are proposed in this work. The corresponding computations were made to confirm the assumptions. The calculations were carried out in context of uncertainty of input data using a set of methods for the analysis of hierarchies, exhaustive search, as well as the methods of decision making in context of uncertainty.

Scaled Testing of Hydrogen Gas Getters for Transuranic Waste

International Nuclear Information System (INIS)

Kaszuba, J.; Mroz, E.; Haga, M.; Hollis, W. K.; Peterson, E.; Stone, M.; Orme, C.; Luther, T.; Benson, M.

2006-01-01

Alpha radiolysis of hydrogenous waste and packaging materials generates hydrogen gas in radioactive storage and shipment containers. Hydrogen forms a flammable mixture with air over a wide range of concentrations (5% to 75%), and very low energy is needed to ignite hydrogen-air mixtures. For these reasons, the concentration of hydrogen in waste shipment containers (Transuranic Package Transporter-II or TRUPACT-II containers) needs to remain below the lower explosion limit of hydrogen in air (5 vol%). Accident scenarios and the resulting safety analysis require that this limit not be exceeded. The use of 'hydrogen getters' is being investigated as a way to prevent the build up of hydrogen in TRUPACT-II containers. Preferred getters are solid materials that scavenge hydrogen from the gas phase and chemically and irreversibly bind it into the solid state. In this study, two getter systems are evaluated: a) 1,4-bis (phenylethynyl)benzene or DEB, characterized by the presence of carbon-carbon triple bonds; and b) a proprietary polymer hydrogen getter, VEI or TruGetter, characterized by carbon-carbon double bonds. Carbon in both getter types may, in the presence of suitable precious metal catalysts such as palladium, irreversibly react with and bind hydrogen. With oxygen present, the precious metal may also eliminate hydrogen by catalyzing the formation of water. This reaction is called catalytic recombination. DEB and VEI performed satisfactorily in lab scale tests using small test volumes (ml-scale), high hydrogen generation rates, and short time spans of hours to days. The purpose of this study is to evaluate whether DEB and VEI perform satisfactorily in actual drum-scale tests with realistic hydrogen generation rates and time frames. The two getter systems were evaluated in test vessels comprised of a Gas Generation Test Program-style bell-jar and a drum equipped with a composite drum filter. The vessels were scaled to replicate the ratio between void space in the

Safety Distances for hydrogen filling stations

Energy Technology Data Exchange (ETDEWEB)

Matthijsen, A. J. C. M.; Kooi, E. S.

2005-07-01

In the Netherlands there is a growing interest in using natural gas as a transport fuel. The most important drivers behind this development are formed by poor inner city air quality and the decision to close several LPG filling stations. Dwellings are not allowed within the safety distances of 45 or 110 meters from the tanker filling point of these LPG stations, depending on the capacity of the station. Another driver is global warming. We are carrying out a study on station supply, compression, storage and filling for natural gas stations, and a similar, simultaneous study on hydrogen as a followup to our risk analysis for the hydrogen filling station in Amsterdam. Here, three buses drive on hydrogen as part of the European CUTE project. Driving on natural gas is an important step in the transition to cars on hydrogen. This study was commissioned by the Dutch Ministry of Spatial Planning, Housing and the Environment to advise on external safety aspects of future hydrogen filling stations. According to Dutch law homes may not be built within an individual risk contour of 10-6 per year of a dangerous object, such as a plant with hazardous materials or a filling station. An individual risk contour of 10-6 is represented by a line around a dangerous object that connects locations with an individual risk level of 10-6 per year. An individual 'located' within this contour line has a chance of one per million per year or more to be killed as a result of an accident caused by this object. The longest distance between the object and such a contour is called a 'safety distance'. A study on safety distances is now in progress for different kinds of hydrogen filling stations (e. g. gaseous and liquid hydrogen) and for different capacities, such as big, medium and small stations. The focus is on different kinds of hydrogen production and the hydrogen supply of the filling station. To decide on the design and supply of the hydrogen station, we examined the

Metal/glass composites for analysis of hydrogen isotopes by gas-chromatography

International Nuclear Information System (INIS)

Nicolae, Constantin Adrian; Sisu, Claudia; Stefanescu, Doina; Stanciu, Vasile

1999-01-01

The separation process of hydrogen isotopes by cryogenic distillation or thermal diffusion is a key technology for tritium separation from heavy water in CANDU reactor and for tritium fuel cycle in thermonuclear fusion reactor. In each process, analytical techniques for analyzing the hydrogen isotope mixture are required. An extensive experimental research has been carried out in order to produce the most suitable adsorbents and to establish the best operating conditions for selective separation and analysis of hydrogen isotopes by gas-chromatography. This paper describes the preparation of adsorbent materials used as stationary phases in the gas-chromatographic column for hydrogen isotope separation and the treatment (activation) of stationary phases. Modified thermoresisting glass with Fe(NH 4 ) 2 (SO 4 ) 2 ·6H 2 O and Cr 2 O 3 respectively have been experimentally investigated at 77 K for H 2 , HD and D 2 separation and the results of chromatographic runs are reported and discussed. The gas-chromatographic apparatus used in this study is composed of a Hewlett-Packard 7620A gas-chromatograph equipped with a gas carrier flow rate controller and a thermal conductivity detector. The apparatus comprises also a Dewar vessel containing the separation column. The hydrogen isotopes, H 2 , HD, D 2 , and their mixture have been obtained in our laboratories. The best operating conditions and parameters of the Fe 3+ /glass adsorbent column , i.e. granulometry, column length, pressure-drop along the column, carrier gas flow rate and sample volume have been studied by means of the analysis of the retention times, separation factors and HETP. (authors)

Integrated energy systems for hydrogen and electricity supply

Energy Technology Data Exchange (ETDEWEB)

Muradov, N. [Univ. of Central Florida, Cocoa, FL (United States). Florida Solar Energy Center; Manikowski, A.; Noland, G. [Procyon Power Systems Inc., Alameda, CA (United States)

2002-07-01

The United States will soon need an increase in electric generating capacity along with an increase in the distribution capacity of the electricity grid. The cost and time required to build additional electrical distribution and transmission systems can be avoided by using distributed power generation. This paper examines the development of an integrated stand-alone energy system that can produce hydrogen, electricity and heat. The concept is based on integrated operation of a thermocatalytic pyrolysis (TCP) reactor and a solid oxide fuel cell (SOFC). The benefits include high overall energy efficiency, the production of high quality hydrogen (90 to 95 per cent free of carbon oxides), low emissions, and fuel flexibility. Experimental data is presented regarding the thermocatalytic pyrolysis of methane compared with an iron-based catalyst (which is sulfur resistant) and gasification of the resulting carbon with steam and carbon dioxide. With distributed generation, additional electrical generating capacity can be added in small increments distributed over the grid. An integrated energy system will be applicable to any type of hydrocarbon fuel, such as natural gas, liquid propane gas, gasoline, kerosene, jet fuel, diesel fuel and sulfurous residual oils. The suitable range of operating parameters needed to decoke a catalyst bed using steam and carbon dioxide as a degasifying agent was also determined. The Fe-catalyst was efficient in both methane pyrolysis and steam/CO{sub 2} gasification of carbon. It was shown that the TCP and SOFC complement each other in may ways. With the IES, high quality hydrogen is delivered to the end user. IES can also operate as either a hydrogen production unit or as an electrical power generator. The energy efficiency of the IES is estimated at 45-55 per cent. 6 refs., 8 figs.

A simulation approach for analysis of short-term security of natural gas supply in Colombia

International Nuclear Information System (INIS)

Villada, Juan; Olaya, Yris

2013-01-01

Achieving security of gas supply implies diversifying gas sources, while having enough supply, transportation, and storage capacity to meet demand peaks and supply interruptions. Devising a strategy for securing gas supply is not straightforward because gas supply depends on complex interactions of production, demand and infrastructure, and it is exposed to economic, regulatory, political, environmental and technical risks. To address this complexity, we propose a simulation approach that replicates the structure of the gas supply chain, including transportation constraints and demand fluctuations. We build and calibrate a computer model for the Colombian gas sector, and run the model to assess the impact of expanding transportation capacity and increasing market flexibility on the security of supply. Our analysis focuses on the operation and planned and proposed expansions of the transportation infrastructure because adequate regulation and development of this infrastructure can contribute to increase the security of supply in the gas sector. We find that proposed import facilities, specifically LNG import terminals at Buenaventura, increase system's security under the current market structure. - Highlights: ► We build a simulation model for analyzing natural gas trade in Colombia. ► The model captures the structure of the gas network and on market rules. ► We simulate investment decisions to increase short-term security of supply. ► Securing supply would need LNG imports and expansion of pipeline capacity.

Documentation of the oil and gas supply module (OGSM)

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-01-01

The purpose of this report is to define the objectives of the Oil and Gas Supply Model (OGSK, to describe the model`s basic approach, and to provide detail on how the model works. This report is intended as a reference document for model analysts, users, and the public. It is prepared in accordance with the Energy Information Administration`s (EIA) legal obligation to provide adequate documentation in support of its statistical and forecast reports (Public Law 93-275, Section 57(b)(2). OGSM is a comprehensive framework with which to analyze oil and gas supply potential and related issues. Its primary function is to produce forecast of crude oil, natural gas production, and natural gas imports and exports in response to price data received endogenously (within NEMS) from the Natural Gas Transmission and Distribution Model (NGTDM) and the Petroleum Market Model (PMM). To accomplish this task, OGSM does not provide production forecasts per se, but rather parameteres for short-term domestic oil and gas production functions and natural gas import functions that reside in PMM and NGTDM.

Documentation of the oil and gas supply module (OGSM)

International Nuclear Information System (INIS)

1996-01-01

The purpose of this report is to define the objectives of the Oil and Gas Supply Model (OGSK, to describe the model's basic approach, and to provide detail on how the model works. This report is intended as a reference document for model analysts, users, and the public. It is prepared in accordance with the Energy Information Administration's (EIA) legal obligation to provide adequate documentation in support of its statistical and forecast reports (Public Law 93-275, Section 57(b)(2). OGSM is a comprehensive framework with which to analyze oil and gas supply potential and related issues. Its primary function is to produce forecast of crude oil, natural gas production, and natural gas imports and exports in response to price data received endogenously (within NEMS) from the Natural Gas Transmission and Distribution Model (NGTDM) and the Petroleum Market Model (PMM). To accomplish this task, OGSM does not provide production forecasts per se, but rather parameteres for short-term domestic oil and gas production functions and natural gas import functions that reside in PMM and NGTDM

Co-pyrolysis of coal with hydrogen-rich gases. 1. Coal pyrolysis under coke-oven gas and synthesis gas

Energy Technology Data Exchange (ETDEWEB)

Liao, H.; Li, B.; Zhang, B. [Chinese Academy of Sciences, Taiyuan (China). State Key Lab. of Coal Conversion

1998-06-01

To improve the economics of the hydropyrolysis process, it has been suggested that cheaper hydrogen-rich gases (such as coke oven gas, synthesis gas) could be used instead of pure hydrogen. Pyrolysis of Chinese Xianfeng lignite was carried out with coke oven gas (COG) and synthesis gas (SG) as reactive gases at 0.1-5 MPa and at a final temperature up to 650{degree}C with a heating rate of 5-25{degree}C min{sup -1} in a 10 g fixed-bed reactor. The results indicate that it is possible to use COG and SG instead of pure hydrogen in hydropyrolysis, but that the experimental conditions must be adjusted to optimize the yields of the valuable chemicals. 14 refs., 3 figs., 6 tabs.

Transition to hydrogen: pathways toward clean transportation

National Research Council Canada - National Science Library

Wokaun, Alexander; Wilhelm, Erik

2011-01-01

..., industrial stakeholders and researchers alike. Using hydrogen as a fuel offers a possible solution to satisfying global mobility needs, including sustainability of supply and the potential reduction of greenhouse gas emissions...

Hysec Process: production of high-purity hydrogen from coke oven gas

Energy Technology Data Exchange (ETDEWEB)

Nishida, S

1984-01-01

An account is given of the development of the Hysec Process by the Kansai Netsukagaku and Mitsubishi Kakoki companies. The process is outlined and its special features noted. The initial development aim was to obtain high-purity hydrogen from coke oven gas by means of PSA. To achieve this, ways had to be found for removing the impurities in the coke oven gas and the trace amounts of oxygen which are found in the product hydrogen. The resulting hydrogen is 99.9999% pure. 3 references.

Extensive Atrophic Gastritis Increases Intraduodenal Hydrogen Gas

Directory of Open Access Journals (Sweden)

Yoshihisa Urita

2008-01-01

Full Text Available Objective. Gastric acid plays an important part in the prevention of bacterial colonization of the gastrointestinal tract. If these bacteria have an ability of hydrogen (H2 fermentation, intraluminal H2 gas might be detected. We attempted to measure the intraluminal H2 concentrations to determine the bacterial overgrowth in the gastrointestinal tract. Patients and methods. Studies were performed in 647 consecutive patients undergoing upper endoscopy. At the time of endoscopic examination, we intubated the stomach and the descending part of the duodenum without inflation by air, and 20 mL of intraluminal gas samples of both sites was collected through the biopsy channel. Intraluminal H2 concentrations were measured by gas chromatography. Results. Intragastric and intraduodenal H2 gas was detected in 566 (87.5% and 524 (81.0% patients, respectively. The mean values of intragastric and intraduodenal H2 gas were 8.5±15.9 and 13.2±58.0 ppm, respectively. The intraduodenal H2 level was increased with the progression of atrophic gastritis, whereas the intragastric H2 level was the highest in patients without atrophic gastritis. Conclusions. The intraduodenal hydrogen levels were increased with the progression of atrophic gastritis. It is likely that the influence of hypochlorhydria on bacterial overgrowth in the proximal small intestine is more pronounced, compared to that in the stomach.

Hydrogen Production by Steam Reforming of Natural Gas Over Vanadium-Nickel-Alumina Catalysts.

Science.gov (United States)

Yoo, Jaekyeong; Park, Seungwon; Song, Ji Hwan; Song, In Kyu

2018-09-01

A series of vanadium-nickel-alumina (xVNA) catalysts were prepared by a single-step sol-gel method with a variation of vanadium content (x, wt%) for use in the hydrogen production by steam reforming of natural gas. The effect of vanadium content on the physicochemical properties and catalytic activities of xVNA catalysts in the steam reforming of natural gas was investigated. It was found that natural gas conversion and hydrogen yield showed volcano-shaped trends with respect to vanadium content. It was also revealed that natural gas conversion and hydrogen yield increased with decreasing nickel crystallite size.

Fiscal 1999 phase 2 R and D report of WE-NET (International Clean Energy Network Using Hydrogen Conversion). Task 6. Development of the polymer electrolyte membrane fuel cell supplied with pure hydrogen; 1999 nendo suiso riyo kokusai clean energy system gijutsu (WE-NET) dainiki kenkyu kaihatsu seika hokokusho. Task 6. Junsuiso kyokyu kotai kobunshigata nenryo denchi no kaihatsu

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-03-01

This report summarizes the fiscal 1999 research result on development of element technologies for a pure hydrogen fuel cell power system of nearly 45% in efficiency at terminal, and demonstration test result on the 30kW class polymer electrolyte membrane fuel cell system supplied with pure hydrogen. On cell voltage characteristics in high-utilization operation, study was made on degradation and corrosion caused by short supply of hydrogen by using a single cell. As a result, it was found out that reverse polarization of -3.0V has small effect, however, that of -0.7V causes corrosion and deterioration of cell characteristics in a short time. In operation using actual-size cells for the 30kW class plant, it was effective to wet cells on the air side. On hydrogen high-utilization operation technique, study was made on hydrogen recovery and recycle operation, anode outlet line closed operation, and anode recycle operation. In addition, some studies were made on specifications of auxiliary facilities for fuel cells, safety measures for fuel cells and humidity control of supplied hydrogen gas. (NEDO)

Laser-driven nuclear-polarized hydrogen internal gas target

International Nuclear Information System (INIS)

Seely, J.; Crawford, C.; Clasie, B.; Xu, W.; Dutta, D.; Gao, H.

2006-01-01

We report the performance of a laser-driven polarized internal hydrogen gas target (LDT) in a configuration similar to that used in scattering experiments. This target used the technique of spin-exchange optical pumping to produce nuclear spin polarized hydrogen gas that was fed into a cylindrical storage (target) cell. We present in this paper the performance of the target, methods that were tried to improve the figure-of-merit (FOM) of the target, and a Monte Carlo simulation of spin-exchange optical pumping. The dimensions of the apparatus were optimized using the simulation and the experimental results were in good agreement with the results from the simulation. The best experimental result achieved was at a hydrogen flow rate of 1.1x10 18 atoms/s, where the sample beam exiting the storage cell had 58.2% degree of dissociation and 50.5% polarization. Based on this measurement, the atomic fraction in the storage cell was 49.6% and the density averaged nuclear polarization was 25.0%. This represents the highest FOM for hydrogen from an LDT and is higher than the best FOM reported by atomic beam sources that used storage cells

Hydrogen and Hydrogen/Natural Gas Station and Vehicle Operations - 2006 Summary Report

Energy Technology Data Exchange (ETDEWEB)

Francfort; Donald Karner; Roberta Brayer

2006-09-01

This report is a summary of the operations and testing of internal combustion engine vehicles that were fueled with 100% hydrogen and various blends of hydrogen and compressed natural gas (HCNG). It summarizes the operations of the Arizona Public Service Alternative Fuel Pilot Plant, which produces, compresses, and dispenses hydrogen fuel. Other testing activities, such as the destructive testing of a CNG storage cylinder that was used for HCNG storage, are also discussed. This report highlights some of the latest technology developments in the use of 100% hydrogen fuels in internal combustion engine vehicles. Reports are referenced and WWW locations noted as a guide for the reader that desires more detailed information. These activities are conducted by Arizona Public Service, Electric Transportation Applications, the Idaho National Laboratory, and the U.S. Department of Energy’s Advanced Vehicle Testing Activity.

Chemically modified glasses for analysis of hydrogen isotopes by gas-chromatography

International Nuclear Information System (INIS)

Stanciu, Vasile; Stefanescu, Doina

1999-01-01

Hydrogen isotope separation process by such methods as cryogenic distillation or thermal diffusion method is one of the key technologies of the tritium separation from heavy water of CANDU reactors and in the tritium fuel cycle for a thermonuclear fusion reactor. In each process, the analytical techniques for measuring contents of hydrogen isotope mixture are necessary. An extensive experimental research has been carried out in order to produce the most suitable absorbent and define the best operating conditions for selective separation and analysis of hydrogen isotope by gas-chromatography. This paper describes the preparation of adsorbent materials utilised as stationary phase in the gas-chromatographic column for hydrogen isotope separation and treatment (activation) of stationary phase. Modified thermo-resisting glass with Fe(NH 4 ) 2 (SO 4 ) 2 6H 2 O and Cr 2 O 3 , respectively, have been experimentally investigated at 77 K for H 2 , HD and D 2 separation and the results of chromatographic runs are also reported and discussed. The gas-chromatographic apparatus used is composed of a Hewlett-Packard 7620A gas-chromatograph equipped with a gas carrier flow rate controller and a thermal conductivity detector (TCD). The apparatus comprises also a Dewar vessel containing the separation column. The hydrogen isotopes H 2 , HD, D 2 and their mixture have been obtained in our laboratories. The best operating conditions of the adsorbent column Fe (III)/glass and Cr 2 O 3 /glass, i.e. granulometry, column length, pressure-drop along the column, carrier gas flow rate, sample volume have been studied by means of the analysis of the retention times, separation factors and HETP. (authors)

Production of hydrogen gas from novel chemical hydrides

Energy Technology Data Exchange (ETDEWEB)

Aiello, R.; Matthews, M.A. [South Carolina Univ., Chemical Engineering Dept., Columbia, SC (United States); Reger, D.L.; Collins, J.E. [South Carolina Univ., Chemistry and Biochemistry Dept., Columbia, SC (United States)

1998-12-01

Six ligand-stabilized complexes have been synthesized and tested for use as hydrogen storage media for portable fuel cell applications. The new hydrides are: [HC(3,5-Me{sub 2}pz){sub 3}]LiBH{sub 4} (1), [[H{sub 2}C(3,5-Me{sub 2}pz){sub 2}]LiBH{sub 4})]{sub 2} (2) (pz = pyrazolyl), [(TMEDA)Li(BH{sub 4})]{sub 2} (3) (TMEDA (CH{sub 3}){sub 2}NCH{sub 2}CH{sub 2}N(CH{sub 3}){sub 2}), [HC(pz){sub 3}]LiBH{sub 4} (4), [[H{sub 2}C(pz){sub 2}]Li(BH{sub 4})]{sub 2} (5) and Mg(BH{sub 4}){sub 2}3THF (6) (THF = tetrahydrofuran). Hydrolysis reactions of the compounds liberate hydrogen in quantities which range from 56 to 104 ({+-}5%) of the theoretical yield. Gas chromatographic analysis of the product gases from these reactions indicate that hydrogen is the only gas produced. Thermally initiated reactions of the novel compounds with NH{sub 4}Cl were unsuccessful. Although the amount of hydrogen energy which can be theoretically obtained per unit weight is lower than that of the classical hydrides such as LiBH{sub 4} and NaBH{sub 4}, the reactions are less violent and hydrolysis of compounds 1, 2, 4, 5 and 6 releases less heat per mole of hydrogen generated. (Author)

Production of dissociated hydrogen gas by electro-magnetically driven shock

International Nuclear Information System (INIS)

Kondo, Kotaro; Moriyama, Takao; Hasegawa, Jun; Horioka, Kazuhiko; Oguri, Yoshiyuki

2013-01-01

Evaluation of ion stopping power which has a dependence on target temperature and density is an essential issue for heavy-ion-driven high energy density experiment. We focus on experimentally unknown dissociated hydrogen atoms as target for stopping power measurement. The precise measurement of shock wave velocity is required because the dissociated gas is produced by electro-magnetically driven shock. For beam-dissociated hydrogen gas interaction experiment, shock velocity measurement using laser refraction is proposed. (author)

A strategic model of European gas supply

International Nuclear Information System (INIS)

Holz, Franziska; Hirschhausen, Christian von; Kemfert, Claudia

2005-01-01

Structural changes in the European natural gas market such as liberalization, increasing demand, and growing import dependency have triggered new attempts to model these markets accurately. This paper proposes a model of the European natural gas supply including the possibility of strategic behavior of the agents along the value-added chain. We structure it as a two-stage-game of successive natural gas exports to Europe (first stage) and wholesale trade within Europe (second stage). In the case of non-cooperative Cournot competition at both stages, which is the most realistic scenario, this yields a market outcome with double marginalization, that is suppliers at both stages generate a mark-up, at the expense of the final customers. Our results suggest that the main suppliers of natural gas to Europe remain dominant (Norway, the Netherlands), although some lose market shares (Algeria, UK, and especially Russia). Traditional exports will be complemented in the future by overseas supplies of LNG from the Middle East, Nigeria, Trinidad and Tobago which are becoming competitive. The model also enables us to identify transport infrastructure bottlenecks; we find that transport capacity on the upstream market is sufficient but the capacity constraint is binding for many intra-EU trade relations. (Author)

Gas-supply strategy until 2020; Strategija opskrbe plinom do 2020. godine

Energy Technology Data Exchange (ETDEWEB)

Kolundzic, S; Sekulic, G [Zagreb (Croatia)

1997-12-31

Development of Croatian economy manifests itself through more rapid (as distinguished from the last 5 years) and more effective development of energy sector. There is a substantial impact of gas which makes already 27% (in 1995) of energy consumption. According to consumption estimates, this share will continue to grow till 2020. That is the main reason for both gas industry and the state to find an appropriate gas-supply strategy. In this report there are gas-consumption estimates and possible supply-sources. Furthermore, essential conditions and strategies are analysed here, necessary for the increase of gas consumption, matching with global European and world trends of expanding the gas industry world-wide and balancing conditions of gas transactions and development. One of the most important condition is safety of delivery and the corresponding activities. Then there is the issue of gas prices: how to achieve the necessary price-increase, which makes the main source of financing the future infrastructure facilities and gas projects. It will be necessary to devise and apply the adequate regulations (such as price rates system, taxes, privatisation, safety measures, etc.) promptly, and thus successfully realize the gas-supply strategy. These regulations would resemble those in countries with market economy according to global importance of gas industry and Croatian orientation to more intensive participation in world economy. (author). 5 tabs., 4 figs., 24 refs.

Construction and performance tests of a secondary hydrogen gas cooling system

International Nuclear Information System (INIS)

Sanokawa, K.; Hishida, M.

1980-01-01

With the aim of a multi-purpose use of nuclear energy, such as direct steel-making, an experimental multi-purpose high-temperature gas-cooled reactor (VHTR) is now being developed by the Japan Atomic Energy Research Institute (JAERI). In order to simulate a heat exchanging system between the primary helium gas loop and the secondary reducing gas system of the VHTR, a hydrogen gas loop as a secondary cooling system of the existing helium gas loop was completed in 1977, and was successfully operated for over 2000 hours. The objectives of constructing the H 2 secondary loop were: (1) To get basic knowledge for designing, constructing and operating a high-temperature and high-pressure gas facility; (2) To perform the following tests: (a) hydrogen permeation at the He/H 2 heat exchanger (the surfaces of the heat exchanger tubes are coated by calorizing to reduce hydrogen permeation), (b) thermal performance tests of the He/H 2 heat exchanger and the H 2 /H 2 regenerative heat exchanger, (c) performance test of internal insulation, and (d) performance tests of the components such as a H 2 gas heater and gas purifiers. These tests were carried out at He gas temperature of approximately 1000 0 C, H 2 gas temperature of approximately 900 0 C and gas pressures of approximately 40 kg/cm 2 G, which are almost the same as the operating conditions of the VHTR

Measurements of hydrogen concentration in liquid sodium by using an inert gas carrier method

International Nuclear Information System (INIS)

Funada, T.; Nihei, I.; Yuhara, S.; Nakasuji, T.

1979-01-01

A technique was developed to measure the hydrogen level in liquid sodium using an inert gas carrier method. Hydrogen was extracted into an inert gas from sodium through a thin nickel membrane in the form of a helically wound tube. The amount of hydrogen in the inert gas was analyzed by gas chromatography. The present method is unique in that it can be used over the wide range of sodium temperatures (150 to 700 0 C) and has no problems associated with vacuum systems. The partial pressure of hydrogen in sodium was determined as a function of cold-trap temperature (T/sub c/). Sieverts' constant (K/sub s/) was determined as a function of sodium temperature (T). From Sieverts' constant, the solubility of hydrogen in sodium is calculated. It was found that other impurities in sodium, such as (O) and (OH), have little effect on the hydrogen pressure in the sodium loop

Hydrogen. A small molecule with large impact

Energy Technology Data Exchange (ETDEWEB)

Gehrke, H.; Ruthardt, K.; Mathiak, J.; Roosen, C. [Uhde GmbH, Dortmund (Germany)

2010-12-30

The first section of the presentation will provide general information about hydrogen including physical data, natural abundance, production and consumption figures. This will be followed by detailed information about current industrial production routes for hydrogen. Main on-purpose production for hydrogen is by classical steam reforming (SR) of natural gas. A brief overview of most important steps in stream reforming is given including reforming section, CO conversion and gas purification. Also the use of heavier than methane feedstocks and refinery off-gases is discussed. Alternative routes for hydrogen production or production of synthesis gas are autothermal reforming (ATR) or partial oxidation (POX). Pros and Cons for each specific technology are given and discussed. Gasification, especially gasification of renewable feedstocks, is a further possibility to produce hydrogen or synthesis gas. New developments and current commercial processes are presented. Hydrogen from electrolysis plants has only a small share on the hydrogen production slate, but in some cases this hydrogen is a suitable feedstock for niche applications with future potential. Finally, production of hydrogen by solar power as a new route is discussed. The final section focuses on the use of hydrogen. Classical applications are hydrogenation reactions in refineries, like HDS, HDN, hydrocracking and hydrofinishing. But, with an increased demand for liquid fuels for transportation or power supply, hydrogen becomes a key player in future as an energy source. Use of hydrogen in synthesis gas for the production of liquid fuels via Fischer-Tropsch synthesis or coal liquefaction is discussed as well as use of pure hydrogen in fuel cells. Additional, new application for biomass-derived feedstocks are discussed. (orig.)

Control device for combustible gas concentration

International Nuclear Information System (INIS)

Osawa, Yasuo.

1988-01-01

Purpose: To control the concentration of combustible gases such as hydrogen evolved in a reactor container upon loss-of-coolant accidents. Constitution: Combustible gases evolved from the lower area of a drywell in which a combustible atmosphere is liable to be formed locally are taken out through a take-out pipeway to the outside of a reactor container and processed by a hydrogen-oxygen recombiner. Combustible gases in other areas of the drywell are also introduced to the lower area of the drywell and then taken-out externally for procession. Further, combustible gases in the suppression chamber are introduced by the opening of a vacuum breaking valve through a gas supply pipe to the lower area of the drywell and fluids in the drywell are stirred and diluted with fluids exhausted from the gas supply pipe. Disposition of such take-out pipeway and gas supply pipe can reduce the possibility of forming local combustible atmosphere to improve the integrity of the reactor container. (Kamimura, M.)

The development of natural gas supply costs to Europe, the United States and Japan in a globalizing gas market-Model-based analysis until 2030

International Nuclear Information System (INIS)

Lochner, Stefan; Bothe, David

2009-01-01

Quickly declining natural gas reserves in some parts of the world, increasing demand in today's major gas consuming regions, the emergence of new demand centres and the globalization of natural gas markets caused by the rising importance of liquefied natural gas (LNG) are changing global gas supply structures and will continue to do so over the next decades. Applying a global gas market model, we produce a forecast for global gas supply to 2030 and determine the supplier-specific long-run average costs of gas supplied to three major consuming regions. Results for the three regions are compared and analysed with a focus on costs, supply diversification and the different roles of LNG. We find that while European and Japanese external gas supply will be less diversified in international comparison, gas can be supplied at relatively low costs due to the regions' favourable locations in geographic proximity to large gas producers. The US market's supply structure on the other hand will significantly change from its current situation. The growing dependency on LNG imports from around the world will lead to significantly higher supply costs but will also increase diversification as gas will originate from an increasing number of LNG exporting countries

Can aqueous hydrogen peroxide be used as a stand-alone energy source?

International Nuclear Information System (INIS)

Disselkamp, Robert S.

2010-01-01

A novel electrochemical scheme to convert a stand-alone supply of aqueous hydrogen peroxide into a fuel cell-ready stream of hydrogen gas plus aqueous hydrogen peroxide is described. The electrochemical cell, consisting of a solid base and solid acid electrocatalyst, together with a proton exchange membrane, comprise the system that converts aqueous hydrogen peroxide into separate gas streams of oxygen and hydrogen. Aqueous hydrogen peroxide is contained in the anode compartment only and exists in the region where oxygen gas is formed, whereas the cathode compartment is where hydrogen gas is generated and therefore exists in a reduced state. A near zero theoretical over-potential can be achieved by the choice of basicity and acidity of the electrode materials. The primary cost of the electrochemical cell is electrode construction and the aqueous hydrogen peroxide energy storage compound. Additional research effort is required to experimentally validate the concept and explore the full economic impact should initial studies, based on the design presented here, prove promising. (author)

Natural gas supply, demand and price outlook

International Nuclear Information System (INIS)

Anon.

1992-01-01

Natural gas consumption in the US grew 15.9 percent between 1986 and 1989. Its share of total primary energy use in the US grew from 22.5 percent to 23.8 percent. Despite unusually warm weather and an economic downturn, natural gas use in the first eight months of 1990 fell only modestly from its 1989 pace - while its market share of US total primary energy use has remained stable. The American Gas Association's Total Energy Resource Analysis energy modeling system (A.G.A.-TERA) projects continued growth in natural gas demand and supply. Natural gas is projected to gain a growing share of total US primary use. Natural gas prices are projected to be sufficient to encourage growth in well completions and reserve additions, yet competitive with electricity, fuel oil and other alternative forms of energy

A New EU Gas Security of Supply Architecture?

Energy Technology Data Exchange (ETDEWEB)

De Jong, J. [Clingendael International Energy Programme CIEP, The Hague (Netherlands); Glachant, J.M.; Ahner, N. [European University Institute EUI, San Domenico di Fiesole (Italy); Hafner, M.; Tagliapietra, S. [Fondazione Eni Enrico Mattei FEEM, Milan (Italy)

2012-07-15

A series of workshops has been organized in order to take stock and discuss a possible new architecture for EU gas security. Discussions and reflections reported from the workshops held under this project have developed into the concluding ideas and recommendations for a new EU gas security of supply architecture, which are reflected in this article.

Security of supply and retail competition in the European gas market

Energy Technology Data Exchange (ETDEWEB)

Abada, Ibrahim, E-mail: ibrahim.abada@polytechnique.edu [IFP Energies nouvelles, 1 et 4 avenue de Bois Preau, 92852 Rueil-Malmaison (France); EDF Research and Development, 1 avenue du General de Gaulle, 92140 Clamart (France); EconomiX-CNRS, University of Paris Ouest (France); Massol, Olivier, E-mail: olivier.massol@ifpen.fr [Center for Economics and Management, IFP School, 228-232 av. Napoleon Bonaparte, 92852 Rueil-Malmaison (France); Department of Economics, City University London, Northampton Square, London EC1V 0HB (United Kingdom)

2011-07-15

In this paper, we analyze the impact of uncertain disruptions in gas supply upon gas retailer contracting behavior and consequent price and welfare implications in a gas market characterized by long-term gas contracts using a static Cournot model. In order to most realistically describe the economical situation, our representation divides the market into two stages: the upstream market that links, by means of long-term contracts, producers in exporting countries (Russia, Algeria, etc.) to local retailers who bring gas to the consuming countries to satisfy local demands in the downstream market. Disruption costs are modeled using short-run demand functions. First we mathematically develop a general model and write the associated KKT conditions, then we propose some case studies, under iso-elasticity assumptions, for the long-short-run inverse-demand curves in order to predict qualitatively and quantitatively the impacts of supply disruptions on Western European gas trade. In the second part, we study in detail the German gas market of the 1980s to explain the supply choices of the German retailer, and we derive interesting conclusions and insights concerning the amounts and prices of natural gas brought to the market. The last part of the paper is dedicated to a study of the Bulgarian gas market, which is greatly dependent on the Russian gas supplies and hence very sensitive to interruption risks. Some interesting conclusions are derived concerning the necessity to economically regulate the market, by means of gas amounts control, if the disruption probability is high enough. - Highlights: > We model retail competition using a Nash-Cournot framework. > Risk-neutral retailers decide their import policy among a set of risky producers. > Case 1: the German gas trade of the 1980s to understand the gas sources' choices. > Case 2: the current Bulgarian gas trade to study the market properties. > Conclusions about the market regulation for welfare optimization reasons.

Security of supply and retail competition in the European gas market

International Nuclear Information System (INIS)

Abada, Ibrahim; Massol, Olivier

2011-01-01

In this paper, we analyze the impact of uncertain disruptions in gas supply upon gas retailer contracting behavior and consequent price and welfare implications in a gas market characterized by long-term gas contracts using a static Cournot model. In order to most realistically describe the economical situation, our representation divides the market into two stages: the upstream market that links, by means of long-term contracts, producers in exporting countries (Russia, Algeria, etc.) to local retailers who bring gas to the consuming countries to satisfy local demands in the downstream market. Disruption costs are modeled using short-run demand functions. First we mathematically develop a general model and write the associated KKT conditions, then we propose some case studies, under iso-elasticity assumptions, for the long-short-run inverse-demand curves in order to predict qualitatively and quantitatively the impacts of supply disruptions on Western European gas trade. In the second part, we study in detail the German gas market of the 1980s to explain the supply choices of the German retailer, and we derive interesting conclusions and insights concerning the amounts and prices of natural gas brought to the market. The last part of the paper is dedicated to a study of the Bulgarian gas market, which is greatly dependent on the Russian gas supplies and hence very sensitive to interruption risks. Some interesting conclusions are derived concerning the necessity to economically regulate the market, by means of gas amounts control, if the disruption probability is high enough. - Highlights: → We model retail competition using a Nash-Cournot framework. → Risk-neutral retailers decide their import policy among a set of risky producers. → Case 1: the German gas trade of the 1980s to understand the gas sources' choices. → Case 2: the current Bulgarian gas trade to study the market properties. → Conclusions about the market regulation for welfare optimization

Engineering Development of Ceramic Membrane Reactor System for Converting Natural Gas to Hydrogen and Synthesis Gas for Liquid Transportation Fuels

Energy Technology Data Exchange (ETDEWEB)

Air Products and Chemicals

2008-09-30

An Air Products-led team successfully developed ITM Syngas technology from the concept stage to a stage where a small-scale engineering prototype was about to be built. This technology produces syngas, a gas containing carbon monoxide and hydrogen, by reacting feed gas, primarily methane and steam, with oxygen that is supplied through an ion transport membrane. An ion transport membrane operates at high temperature and oxygen ions are transported through the dense membrane's crystal lattice when an oxygen partial pressure driving force is applied. This development effort solved many significant technical challenges and successfully scaled-up key aspects of the technology to prototype scale. Throughout the project life, the technology showed significant economic benefits over conventional technologies. While there are still on-going technical challenges to overcome, the progress made under the DOE-funded development project proved that the technology was viable and continued development post the DOE agreement would be warranted.

Hydrogen gas reduces hyperoxic lung injury via the Nrf2 pathway in vivo

Science.gov (United States)

Kawamura, Tomohiro; Wakabayashi, Nobunao; Shigemura, Norihisa; Huang, Chien-Sheng; Masutani, Kosuke; Tanaka, Yugo; Noda, Kentaro; Peng, Ximei; Takahashi, Toru; Billiar, Timothy R.; Okumura, Meinoshin; Toyoda, Yoshiya; Kensler, Thomas W.

2013-01-01

Hyperoxic lung injury is a major concern in critically ill patients who receive high concentrations of oxygen to treat lung diseases. Successful abrogation of hyperoxic lung injury would have a huge impact on respiratory and critical care medicine. Hydrogen can be administered as a therapeutic medical gas. We recently demonstrated that inhaled hydrogen reduced transplant-induced lung injury and induced heme oxygenase (HO)-1. To determine whether hydrogen could reduce hyperoxic lung injury and investigate the underlying mechanisms, we randomly assigned rats to four experimental groups and administered the following gas mixtures for 60 h: 98% oxygen (hyperoxia), 2% nitrogen; 98% oxygen (hyperoxia), 2% hydrogen; 98% balanced air (normoxia), 2% nitrogen; and 98% balanced air (normoxia), 2% hydrogen. We examined lung function by blood gas analysis, extent of lung injury, and expression of HO-1. We also investigated the role of NF-E2-related factor (Nrf) 2, which regulates HO-1 expression, by examining the expression of Nrf2-dependent genes and the ability of hydrogen to reduce hyperoxic lung injury in Nrf2-deficient mice. Hydrogen treatment during exposure to hyperoxia significantly improved blood oxygenation, reduced inflammatory events, and induced HO-1 expression. Hydrogen did not mitigate hyperoxic lung injury or induce HO-1 in Nrf2-deficient mice. These findings indicate that hydrogen gas can ameliorate hyperoxic lung injury through induction of Nrf2-dependent genes, such as HO-1. The findings suggest a potentially novel and applicable solution to hyperoxic lung injury and provide new insight into the molecular mechanisms and actions of hydrogen. PMID:23475767

The life cycle greenhouse gas emissions implications of power and hydrogen production for oil sands operations

International Nuclear Information System (INIS)

McKellar, J.M.; Bergerson, J.A.; MacLean, H.L.

2009-01-01

'Full text:' The Alberta Oil Sands represent a major economic opportunity for Canada, but the industry is also a significant source of greenhouse gas (GHG) emissions. One of the sources of these emissions is the use of natural gas for the production of electricity, steam and hydrogen. Due to concerns around resource availability and price volatility, there has been considerable discussion regarding the potential replacement of natural gas with an alternative fuel. While some of the options are non-fossil and could potentially reduce GHG emissions (e.g., nuclear, geothermal, biomass), others have the potential to increase emissions. A comparative life cycle assessment was completed to investigate the relative GHG emissions, energy consumption and financial implications of replacing natural gas with coal, coke, asphaltenes or bitumen for the supply of electricity, steam and hydrogen to oil sands operations. The potential use of carbon capture and storage (CCS) was also investigated as a means of reducing GHG emissions. Preliminary results indicate that, without CCS, the natural gas systems currently in use have lower life cycle GHG emissions than gasification systems using any of the alternative fuels analysed. However, when CCS is implemented in both the coke gasification and natural gas systems, the coke systems have lower GHG emissions and financial costs than the natural gas systems (assuming a 30-year project life and a natural gas price of 6.5 USD/gigajoule). The use of CCS does impose a financial penalty though, indicating that it is unlikely to be implemented without some financial incentive. While this study has limitations and uncertainties, the preliminary results indicate that although the GHG emissions of oil sands development pose a challenge to Canada, there are opportunities available for their abatement. (author)

New models needed to manage gas supply, APPrO conference hears

International Nuclear Information System (INIS)

Anon.

2005-01-01

Details of a 1 day conference designed to create more efficient interactions between the gas supply and electricity systems in Ontario and new models for gas supply and the electricity system were presented. Market efficiency, generators' perspectives on critical gas issues, an overview of the North American gas and an outline of issues concerning Ontario were discussed. A natural gas industry forecast and issues concerning marketers and producers were presented. The terms on which gas is bought and sold were discussed. Regulatory tools, cost allocation and issues relating to unbundling were also presented. Infrastructure needs were reviewed, as well as basic market structures. It was suggested that appropriate commercial service options need to be developed and approved, including cross-utility services

Production of bioplastics and hydrogen gas by photosynthetic microorganisms

Science.gov (United States)

Yasuo, Asada; Masato, Miyake; Jun, Miyake

1998-03-01

Our efforts have been aimed at the technological basis of photosynthetic-microbial production of materials and an energy carrier. We report here accumulation of poly-(3-hydroxybutyrate) (PHB), a raw material of biodegradable plastics and for production of hydrogen gas, and a renewable energy carrier by photosynthetic microorganisms (tentatively defined as cyanobacteria plus photosynthetic bateria, in this report). A thermophilic cyanobacterium, Synechococcus sp. MA19 that accumulates PHB at more than 20% of cell dry wt under nitrogen-starved conditions was isolated and microbiologically identified. The mechanism of PHB accumulation was studied. A mesophilic Synechococcus PCC7942 was transformed with the genes encoding PHB-synthesizing enzymes from Alcaligenes eutrophus. The transformant accumulated PHB under nitrogen-starved conditions. The optimal conditions for PHB accumulation by a photosynthetic bacterium grown on acetate were studied. Hydrogen production by photosynthetic microorganisms was studied. Cyanobacteria can produce hydrogen gas by nitrogenase or hydrogenase. Hydrogen production mediated by native hydrogenase in cyanobacteria was revealed to be in the dark anaerobic degradation of intracellular glycogen. A new system for light-dependent hydrogen production was targeted. In vitro and in vivo coupling of cyanobacterial ferredoxin with a heterologous hydrogenase was shown to produce hydrogen under light conditions. A trial for genetic trasformation of Synechococcus PCC7942 with the hydrogenase gene from Clostridium pasteurianum is going on. The strong hydrogen producers among photosynthetic bacteria were isolated and characterized. Co-culture of Rhodobacter and Clostriumdium was applied to produce hydrogen from glucose. Conversely in the case of cyanobacteria, genetic regulation of photosynthetic proteins was intended to improve conversion efficiency in hydrogen production by the photosynthetic bacterium, Rhodobacter sphaeroides RV. A mutant acquired by

Optimization of the green gas supply chain. Identification of critical choices in designing an efficient (from an energetic and economic perspective) green gas supply chain.

NARCIS (Netherlands)

Grond, Lukas

2010-01-01

Summary Global climate change and the need for security of energy supply drive the development of bio-energy production and utilization. Green gas is defined as bio-based gas that has been upgraded to natural gas quality. Amongst other energy carriers, g

Metering in the gas supply sector; Metering in der Gasversorgung

Energy Technology Data Exchange (ETDEWEB)

Wernekinck, U. [RWE Westfalen-Weser-Ems, Recklinghausen (Germany)

2007-10-15

The new conditions of competition in the gas supply sector have strongly increased the requirements on gas grid operators. Mainly an exact gas metering and -accouting will become more and more important. The systems and procedures are presented in detail in this contribution. (GL)

Hydrogen energy systems studies

Energy Technology Data Exchange (ETDEWEB)

Ogden, J.M.; Steinbugler, M.; Dennis, E. [Princeton Univ., NJ (United States)] [and others

1995-09-01

For several years, researchers at Princeton University`s Center for Energy and Environmental Studies have carried out technical and economic assessments of hydrogen energy systems. Initially, we focussed on the long term potential of renewable hydrogen. More recently we have explored how a transition to renewable hydrogen might begin. The goal of our current work is to identify promising strategies leading from near term hydrogen markets and technologies toward eventual large scale use of renewable hydrogen as an energy carrier. Our approach has been to assess the entire hydrogen energy system from production through end-use considering technical performance, economics, infrastructure and environmental issues. This work is part of the systems analysis activity of the DOE Hydrogen Program. In this paper we first summarize the results of three tasks which were completed during the past year under NREL Contract No. XR-11265-2: in Task 1, we carried out assessments of near term options for supplying hydrogen transportation fuel from natural gas; in Task 2, we assessed the feasibility of using the existing natural gas system with hydrogen and hydrogen blends; and in Task 3, we carried out a study of PEM fuel cells for residential cogeneration applications, a market which might have less stringent cost requirements than transportation. We then give preliminary results for two other tasks which are ongoing under DOE Contract No. DE-FG04-94AL85803: In Task 1 we are assessing the technical options for low cost small scale production of hydrogen from natural gas, considering (a) steam reforming, (b) partial oxidation and (c) autothermal reforming, and in Task 2 we are assessing potential markets for hydrogen in Southern California.

Membrane reforming in converting natural gas to hydrogen (part one)

Energy Technology Data Exchange (ETDEWEB)

Barba, D; Giacobbe, F; De Cesaris, A [Faculty of Chemical Engineering and Materials, University of L' Aquila (Italy); Farace, A; Iaquaniello, G; Pipino, A [TECHNIP-KTI S.p.a., Rome (Italy)

2008-07-15

Membrane reforming reactors (MRR) could play a key role in converting natural gas into hydrogen. The major advantage of MRR architecture is the possibility to shift the chemical equilibrium toward the right-hand side of the reaction, improving hydrogen production and allowing, the same time high methane conversion at relatively low temperatures such as 650 C. Such a low operating temperature makes it possible to locate the MRR downstream of a gas turbine, achieving an efficient hybrid system (power+hydrogen) with a significant reduction in energy consumption (around 10%). This paper discusses the whole innovative architecture where conventional tubular reforming is integrated with hydrogen permeable palladium membrane separators. The fundamental concepts are analyzed and integrated into a process scheme; the structural effects of variables design such as reactor temperature outlet, S/C ratio and recycle ratio throughout pinch and sensitivity analysis are described, and a comparison of the process economics with conventional hydrogen technology is presented at the end of the second part of this paper. The production of highly reliable, defect-free and reproducible, Pd-alloy membranes for selective hydrogen separation is a key issue in the proposed hybrid architecture. (author)

Long-term trends in U.S. gas supply and prices: 1992 edition of the GRI baseline projection of U.S. energy supply and demand to 2010

International Nuclear Information System (INIS)

Woods, T.J.

1991-12-01

The paper summarizes the gas supply outlook in the 1992 Edition of the GRI Baseline Projection of U.S. Energy Supply and Demand, which has been adopted as a major input to the planning cycle leading to the development of the Gas Research Institute (GRI) 1993 research and development program. The 1992 projection presents the GRI planning outlook for the economic and the energy supply and demand situation to the year 2010. It was prepared independently by GRI using publicly available data and a framework of commercially available models that GRI has developed over several years. It is not derived from the views of GRI member companies. The 1992 Edition of the GRI Baseline Projection presents an optimistic outlook for the U.S. gas industry in which increased gas supply can be obtained at competitive prices. The gas prices in the 1992 projection support growth in all major U.S. gas supply sources: lower-48, Alaska, Canada, Mexico, and LNG. By about 2005, U.S. gas supply is at its highest level ever. By 2010, U.S. gas supply has grown to almost 25 quads. U.S. gas production increases 2.6 quads between 1990 and 2010; imports increase 2.2 quads. Although imports do not increase as much as U.S. gas production, they account for an increased share of U.S. gas supply. The import share grows from 7 percent to 12 percent over the projection period. Supplemental gas sources provide about 1 percent of U.S. gas supply

Applications of Nuclear Energy to Oil Sands and Hydrogen Production

International Nuclear Information System (INIS)

Duffey, R.B.; Miller, A.; Kuran, S.

2011-01-01

Many novel and needed applications of nuclear energy arise in today's energy-hungry, economically challenged world, and in solving tomorrow's search for a globally carbon-constrained and sustainable energy supply. Not only can nuclear power produce low cost electricity, it can provide co-generation of process heat, desalinated water, and hydrogen with negligible greenhouse gas emissions. In each of these new applications, nuclear energy is competing against, or displacing conventional and established use of natural gas or coal in thermal power plants and boilers. Therefore, there must be a compelling case, in terms of supply certainty, stability, safety, security, and acceptability. In addition, a synergistic relation must exist or be created with the existing power and energy markets, the use of windpower, and the needs for low-cost supply with negligible greenhouse gas emissions and carbon 'footprint'. The development of Canada's oil sands resource depends on a substantial energy input for extraction and upgrading. So far, this input has been supplied by natural gas, a resource that (a) is a premium fuel; (b) has constrained availability; and (c) produces significant CO 2 emissions. For the oil sands extraction process, natural gas is the current energy source used to generate the steam for in-situ heating, the power to drive the separation equipment, and the hydrogen for varying degrees of upgrading before piping. Nothwithstanding the current imbalance between supply and demand for gas within North America, the very demand of the oil sands for prodigious amounts of natural gas has itself the potential to force higher prices and create supply constraints for natural gas. Rooted in the energy equivalence of oil and gas, there is a long-established link between American gas prices whereby one bbl of oil is worth 7 GJ of natural gas. Temporary supply/demand imbalances apart, only cheap oil can maintain cheap gas. Only the improbability of cheap oil will maintain low

Hydrogen generation from natural gas for the fuel cell systems of tomorrow

Science.gov (United States)

Dicks, Andrew L.

In most cases hydrogen is the preferred fuel for use in the present generation of fuel cells being developed for commercial applications. Of all the potential sources of hydrogen, natural gas offers many advantages. It is widely available, clean, and can be converted to hydrogen relatively easily. When catalytic steam reforming is used to generate hydrogen from natural gas, it is essential that sulfur compounds in the natural gas are removed upstream of the reformer and various types of desulfurisation processes are available. In addition, the quality of fuel required for each type of fuel cell varies according to the anode material used, and the cell temperature. Low temperature cells will not tolerate high concentrations of carbon monoxide, whereas the molten fuel cell (MCFC) and solid oxide fuel cell (SOFC) anodes contain nickel on which it is possible to electrochemically oxidise carbon monoxide directly. The ability to internally reform fuel gas is a feature of the MCFC and SOFC. Internal reforming can give benefits in terms of increased electrical efficiency owing to the reduction in the required cell cooling and therefore parasitic system losses. Direct electrocatalysis of hydrocarbon oxidation has been the elusive goal of fuel cell developers over many years and recent laboratory results are encouraging. This paper reviews the principal methods of converting natural gas into hydrogen, namely catalytic steam reforming, autothermic reforming, pyrolysis and partial oxidation; it reviews currently available purification techniques and discusses some recent advances in internal reforming and the direct use of natural gas in fuel cells.

Probabilistic modelling of security of supply in gas networks and evaluation of new infrastructure

International Nuclear Information System (INIS)

Praks, Pavel; Kopustinskas, Vytis; Masera, Marcelo

2015-01-01

The paper presents a probabilistic model to study security of supply in a gas network. The model is based on Monte-Carlo simulations with graph theory, and is implemented in the software tool ProGasNet. The software allows studying gas networks in various aspects including identification of weakest links and nodes, vulnerability analysis, bottleneck analysis, evaluation of new infrastructure etc. In this paper ProGasNet is applied to a benchmark network based on a real EU gas transmission network of several countries with the purpose of evaluating the security of supply effects of new infrastructure, either under construction, recently completed or under planning. The probabilistic model enables quantitative evaluations by comparing the reliability of gas supply in each consuming node of the network. - Highlights: • A Monte-Carlo algorithm for stochastic flow networks is presented. • Network elements can fail according to a given probabilistic model. • Priority supply pattern of gas transmission networks is assumed. • A real-world EU gas transmission network is presented and analyzed. • A risk ratio is used for security of supply quantification of a new infrastructure.

The production of high dose hydrogen gas by the AMS-H-01 for treatment of disease

OpenAIRE

Richard Camara; Lei Huang; John H Zhang

2016-01-01

Hydrogen gas is a new and promising treatment option for a variety of diseases including stroke. Here, we introduce the AMS-H-01, a medically approved machine capable of safely producing ~66% hydrogen gas. Furthermore, we propose the significance of this machine in the future of hydrogen gas research.

World natural gas supply and demand: Brief pause in production

International Nuclear Information System (INIS)

Coccia, G.

1993-01-01

With reference to the 1992 CEDIGAZ (Centre International sur le Gas Naturel et tous Hydrocarbures Gazeux) report on world natural gas supply and demand, this paper assesses current market and production trends in this industry. The slight drop in production in 1992, the first which has which has occurred after many consecutive years of steady increases, is ascribed to ownership disputes among the former-USSR republics and major changes in the organizational structure of the former-USSR's natural gas industry. Strong increases in demand are forecasted due to expected strong population growth and increased industrialization to take place in China and India. Price trends in natural gas should remain steady as a result of plentiful supplies of this fuel and coal, a major competitor. The use of relatively clean natural gas is suggested as a practical alternative to energy taxes now being proposed as a means for the reduction of greenhouse gas emissions

[Feasibility investigation of hydrogen instead of helium as carrier gas in the determination of five organophosphorus pesticides by gas chromatography-mass spectrometry].

Science.gov (United States)

Liu, Zhenxue; Zhou, Shixue

2015-01-01

Helium is almost the only choosable carrier gas used in gas chromatography-mass spectrometry (GC-MS). A mixed standard solution of five organophosphorus pesticides was analyzed by using GC-MS, and hydrogen or helium as carrier gas, so as to study the feasibility of hydrogen instead of helium as carrier gas for the determination of organophosphorus pesticides. Combining a mass spectrum database built by ourselves, the results were deconvolved and identified by Automated Mass Spectral Deconvolution & Identification System (AMDIS32), a software belonging to the workstation of the instrument. Then, the statistical software, IBM SPSS Statistics 19.0 was used for the clustering analysis of the data. The results indicated that when hydrogen was used as carrier gas, the peaks of the pesticides detected were slightly earlier than those when helium used as carrier gas, but the resolutions of the chromatographic peaks were lower, and the fraction good indices (Frac. Good) were lower, too. When hydrogen was used as carrier gas, the signals of the pesticides were unstable, the measuring accuracies of the pesticides were reduced too, and even more, some compounds were undetectable. Therefore, considering the measuring accuracy, the signal stability, and the safety, etc., hydrogen should be cautiously used as carrier gas in the determination of organophosphorus pesticides by GC-MS.

Full speed ahead on the Western Canada gas supply treadmill

International Nuclear Information System (INIS)

Flint, D.; Dixon, B.

2005-01-01

The sustainability of natural gas supply in Western Canada was discussed and a background of the Forward Energy Group Inc., was provided, including details of goals, investments and assets. Various challenges to sustainable supply were outlined, including details of total production, competing processes of decline and growth, rate additions from new wells and the fact that since 1989, wells onstream produce 80 per cent of all natural gas. Annual challenges include production and decline rates, as well as additional declines in base volumes of pre-1990 wells. Various industry responses were presented. Rate additions have responded to prices, cash flow, acquisition and capital markets. Growth has been punctuated by low investment. A composite decline was presented, revealing that the decline rate of all wells onstream were increasing. In addition, production gaps grow larger due to the increase of composite decline rates. It was noted that composite decline rates may stabilize. Other factors contributing to decline rates were reserves-based contracts, the absence of pipeline capacity and storage, as well as recession. Rate losses and rate additions were presented. Solution to address these challenges include low deliverability zones, new pools, new areas, tight gas, and technology. It was noted that all activity growth is from low deliverability wells. Rate additions by deliverability class, discovery period, and fracturing were provided. In addition, rate additions per foot drilled were also discussed. Various drivers of the Western Canada Sedimentary (WCSB) rate additions include world gas demand; North American gas supply; capital investment in WCSB; WCSB projects and competition; and capital efficiency. A chart of gas cash flow and investment was presented, as well as a forecast of increasing costs. It was concluded that the WCSB is an important supply source for North America and that the key challenge is to sustain production profitably. Higher prices and

Safety assessment of envisaged systems for automotive hydrogen supply and utilization

Energy Technology Data Exchange (ETDEWEB)

Landucci, Gabriele [Dipartimento di Ingegneria Chimica, Chimica Industriale e Scienza dei Materiali, Universita di Pisa, via Diotisalvi n.2, 56126 Pisa (Italy); Tugnoli, Alessandro; Cozzani, Valerio [Dipartimento di Ingegneria Chimica, Mineraria e delle Tecnologie Ambientali, Alma Mater Studiorum - Universita di Bologna, via Terracini n.28, 40131 Bologna (Italy)

2010-02-15

A novel consequence-based approach was applied to the inherent safety assessment of the envisaged hydrogen production, distribution and utilization systems, in the perspective of the widespread hydrogen utilization as a vehicle fuel. Alternative scenarios were assessed for the hydrogen system chain from large scale production to final utilization. Hydrogen transportation and delivery was included in the analysis. The inherent safety fingerprint of each system was quantified by a set of Key Performance Indicators (KPIs). Rules for KPIs aggregation were considered for the overall assessment of the system chains. The final utilization stage resulted by large the more important for the overall expected safety performance of the system. Thus, comparison was carried out with technologies proposed for the use of other low emission fuels, as LPG and natural gas. The hazards of compressed hydrogen-fueled vehicles resulted comparable, while reference innovative hydrogen technologies evidenced a potentially higher safety performance. Thus, switching to the inherently safer technologies currently under development may play an important role in the safety enhancement of hydrogen vehicles, resulting in a relevant improvement of the overall safety performance of the entire hydrogen system. (author)

Magnetic resonance studies of atomic hydrogen gas at low temperatures

International Nuclear Information System (INIS)

Hardy, W.N.; Morrow, M.; Jochemsen, R.; Statt, B.W.; Kubik, P.R.; Marsolais, R.M.; Berlinsky, A.J.; Landesman, A.

1980-01-01

Using a pulsed low temperature discharge in a closed cell containing H 2 and 4 He, we have been able to store a low density (approximately 10 12 atoms/cc) gas of atomic hydrogen for periods of order one hour in zero magnetic field and T=1 K. Pulsed magnetic resonance at the 1420 MHz hyperfine transition has been used to study a number of the properties of the gas, including the recombination rate H + H + 4 He→H 2 + 4 He, the hydrogen spin-exchange relaxation rates, the diffusion coefficient of H in 4 He gas and the pressure shift of the hyperfine frequency due to the 4 He buffer gas. Here we discuss the application of hyperfine frequency shifts as a probe of the H-He potential, and as a means for determining the binding energy of H on liquid helium

Demand grows in N. America as gas supply sources shift

International Nuclear Information System (INIS)

Carson, M.M.

1996-01-01

Growing demand for gas as a power-generation fuel is combining with changing patterns of gas transportation to present North American producers and pipelines with a series of new challenges. Results of a recent Enron study show how natural gas supplies available to US markets continue to shift their center of gravity toward Canadian and western sources. These changes--demand growth paced by electricity generation and supply source relocation--plus extraordinary gas basin price differentials this winter, point to (a) the opportunities for and risks of adding pipeline capacity in the US and Canada, on the one hand, and (b) tough decisions that may need to be made by Gulf of Mexico and Midcontinent area producers, on the other, to compete in an environment of changing economics and infrastructure

Natural gas, NGL's and crude: supply, demand and price forecasts

International Nuclear Information System (INIS)

Stauft, T.L.

2003-01-01

This paper presents an overview of the major issues to watch in the crude oil, natural gas, and natural gas liquids (NGL) markets in North America. The presentation began with background information concerning Purvin and Gertz, an employee-owned consulting firm whose employees are chemical engineers, holders of a Master of Business Administration (MBA), or economists. They specialize in providing strategic, commercial, and technical advice to the international energy industry. A closer look at each individual market was provided, looking at demand, supply, price drivers and others. The author concluded that world oil prices continue to be influenced by a war premium. Oil prices support natural gas, as well as the possibility of a supply issue. The gas processing margins have remained strong. The unknown quantities are the weather and economic recovery. figs

The Eastring gas pipeline in the context of the Central and Eastern European gas supply challenge

Science.gov (United States)

Mišík, Matúš; Nosko, Andrej

2017-11-01

Ever since the 2009 natural gas crisis, energy security has been a crucial priority for countries of Central and Eastern Europe. Escalating in 2014, the conflict between Ukraine and Russia further fuelled negative expectations about the future development of energy relations for the region predominantly supplied by Russia. As a response to the planned cessation of gas transit through the Brotherhood pipeline, which brings Russian gas to Europe via Ukraine and Slovakia, the Slovak transmission system operator Eustream proposed the Eastring pipeline. This Perspective analyses this proposal and argues that neither the perceived decrease in Slovak energy security nor the loss of economic rent from the international gas transit should be the main policy driver behind such a major infrastructure project. Although marketed as an answer to current Central and Eastern European gas supply security challenges, the Eastring pipeline is actually mainly focused on issues connected to the Slovak gas transit.

Determining air quality and greenhouse gas impacts of hydrogen infrastructure and fuel cell vehicles.

Science.gov (United States)

Stephens-Romero, Shane; Carreras-Sospedra, Marc; Brouwer, Jacob; Dabdub, Donald; Samuelsen, Scott

2009-12-01

Adoption of hydrogen infrastructure and hydrogen fuel cell vehicles (HFCVs) to replace gasoline internal combustion engine (ICE) vehicles has been proposed as a strategy to reduce criteria pollutant and greenhouse gas (GHG) emissions from the transportation sector and transition to fuel independence. However, it is uncertain (1) to what degree the reduction in criteria pollutants will impact urban air quality, and (2) how the reductions in pollutant emissions and concomitant urban air quality impacts compare to ultralow emission gasoline-powered vehicles projected for a future year (e.g., 2060). To address these questions, the present study introduces a "spatially and temporally resolved energy and environment tool" (STREET) to characterize the pollutant and GHG emissions associated with a comprehensive hydrogen supply infrastructure and HFCVs at a high level of geographic and temporal resolution. To demonstrate the utility of STREET, two spatially and temporally resolved scenarios for hydrogen infrastructure are evaluated in a prototypical urban airshed (the South Coast Air Basin of California) using geographic information systems (GIS) data. The well-to-wheels (WTW) GHG emissions are quantified and the air quality is established using a detailed atmospheric chemistry and transport model followed by a comparison to a future gasoline scenario comprised of advanced ICE vehicles. One hydrogen scenario includes more renewable primary energy sources for hydrogen generation and the other includes more fossil fuel sources. The two scenarios encompass a variety of hydrogen generation, distribution, and fueling strategies. GHG emissions reductions range from 61 to 68% for both hydrogen scenarios in parallel with substantial improvements in urban air quality (e.g., reductions of 10 ppb in peak 8-h-averaged ozone and 6 mug/m(3) in 24-h-averaged particulate matter concentrations, particularly in regions of the airshed where concentrations are highest for the gasoline scenario).

Attenuation of hydrogen radicals traveling under flowing gas conditions through tubes of different materials

International Nuclear Information System (INIS)

Grubbs, R.K.; George, S.M.

2006-01-01

Hydrogen radical concentrations traveling under flowing gas conditions through tubes of different materials were measured using a dual thermocouple probe. The source of the hydrogen radicals was a toroidal radio frequency plasma source operating at 2.0 and 3.3 kW for H 2 pressures of 250 and 500 mTorr, respectively. The dual thermocouple probe was comprised of exposed and covered Pt/Pt13%Rh thermocouples. Hydrogen radicals recombined efficiently on the exposed thermocouple and the energy of formation of H 2 heated the thermocouple. The second thermocouple was covered by glass and was heated primarily by the ambient gas. The dual thermocouple probe was translated and measured temperatures at different distances from the hydrogen radical source. These temperature measurements were conducted at H 2 flow rates of 35 and 75 SCCM (SCCM denotes cubic centimeter per minute at STP) inside cylindrical tubes made of stainless steel, aluminum, quartz, and Pyrex. The hydrogen radical concentrations were obtained from the temperatures of the exposed and covered thermocouples. The hydrogen concentration decreased versus distance from the plasma source. After correcting for the H 2 gas flow using a reference frame transformation, the hydrogen radical concentration profiles yielded the atomic hydrogen recombination coefficient, γ, for the four materials. The methodology of measuring the hydrogen radical concentrations, the analysis of the results under flowing gas conditions, and the determination of the atomic hydrogen recombination coefficients for various materials will help facilitate the use of hydrogen radicals for thin film growth processes

Security of Gas Supply in the Countries of the Visegrád Group

Directory of Open Access Journals (Sweden)

Michał Tarnawski

2015-12-01

Full Text Available In spite of efforts on the part of the European Union to promote renewable sources of energy, conventional resources such as oil, natural gas and coal still dominate in individual EU energy mixes. With the rising costs of resources, their uneven distribution and limited supply, each state is busy trying to ensure its energy security. Secure and stable supply of energy resources has becoming the main preoccupation, especially in the countries of Central and Eastern Europe. Over the recent years, the Visegrád Group states have made particularly intensive efforts to ensure their supply of natural gas. The unstable political situation in the east of Europe as well as changes in natural gas markets (shale gas revolution in the USA, increased importance of LNG gave rise to new challenges when it comes to ensuring gas security, but also new opportunities to become independent of eastern imports. It is precisely the fact of being dependent on natural gas imported from Russia that determines the situation of Visegrád Group states. The present paper tries to analyse the situation in Poland, the Czech Republic, Slovakia and Hungary in terms of security of their natural gas supply.

Crude oil and natural gas supplies and demands for Denmark

International Nuclear Information System (INIS)

Mackay, R.M.; Probert, S.D.

1995-01-01

A novel technique for forecasting the supply and extraction life-cycle of a depleting fossil fuel resource has been developed. The supply side utilises a 'skewed-normal production-profile' model that yields a better representation than earlier approaches. A simple model for extrapolating crude oil and natural gas demands has also been devised, based on the so called 'modified logit function'. The predicted crude oil and natural gas balances for the period up to AD 2010 indicate the disparity between indigenous production and future consumption for Denmark. These forecasts depend on current estimates of remaining oil and gas reserves. It will consequently be necessary to revise periodically the present projections as more reliable reserve estimates become available. (author)

Warm Pressurant Gas Effects on the Liquid Hydrogen Bubble Point

Science.gov (United States)

Hartwig, Jason W.; McQuillen, John B.; Chato, David J.

2013-01-01

This paper presents experimental results for the liquid hydrogen bubble point tests using warm pressurant gases conducted at the Cryogenic Components Cell 7 facility at the NASA Glenn Research Center in Cleveland, Ohio. The purpose of the test series was to determine the effect of elevating the temperature of the pressurant gas on the performance of a liquid acquisition device. Three fine mesh screen samples (325 x 2300, 450 x 2750, 510 x 3600) were tested in liquid hydrogen using cold and warm noncondensible (gaseous helium) and condensable (gaseous hydrogen) pressurization schemes. Gases were conditioned from 0 to 90 K above the liquid temperature. Results clearly indicate a degradation in bubble point pressure using warm gas, with a greater reduction in performance using condensable over noncondensible pressurization. Degradation in the bubble point pressure is inversely proportional to screen porosity, as the coarsest mesh demonstrated the highest degradation. Results here have implication on both pressurization and LAD system design for all future cryogenic propulsion systems. A detailed review of historical heated gas tests is also presented for comparison to current results.

Hydrogen Addition for Improved Lean Burn Capability on Natural Gas Engine

Energy Technology Data Exchange (ETDEWEB)

Andersson, Tobias [Lund Inst. of Technology (Sweden). Dept. of Heat and Power Engineering

2002-12-01

Lean burn spark ignition (SI) engines powered by natural gas is an attractive alternative to the Diesel engine, especially in urban traffic, where reduction of tailpipe emissions are of great importance. A major benefit is the large reduction in soot (PM). Lean burn spark ignition (SI) engines yield high fuel conversion efficiency and also relatively low NO{sub x} emissions at full load. In order to improve the engine operating characteristics at lower loads, the {lambda}-value is normally reduced to some degree, with increased NO{sub x} emissions and reduced efficiency as a result. This is a drawback for the lean burn engines, especially in urban applications such as in city buses and distribution trucks for urban use. So, it is desirable to find ways to extend the lean limit at low loads. One way to improve these part load properties is to add hydrogen to the natural gas in order to improve the combustion characteristics of the fuel. It is possible to extend the lean limit of a natural gas engine by addition of hydrogen to the primary fuel. This report presents measurements made on a single cylinder 1.6 liter natural gas engine. Two combustion chambers, one slow and one fast burning, were tested with various amounts of hydrogen (0 to 20 %-vol) added to natural gas. Three operating conditions were investigated for each combustion chamber and each hydrogen content level; idle, wide open throttle (WOT) and a high load condition (simulated turbo charging). For all three operating conditions, the air/fuel ratio was varied between stoichiometric and the lean limit. For each operating point, the ignition timing was swept in order to find maximum brake torque (MBT) timing. In some cases were the ignition timing limited by knock. Heat release rate calculations were made in order to assess the influence of hydrogen addition on burn rate. Addition of hydrogen showed an increase in burn rate for both combustion chambers, resulting in more stable combustion close to the lean

Hydrogen Separation by Natural Zeolite Composite Membranes: Single and Multicomponent Gas Transport.

Science.gov (United States)

Farjoo, Afrooz; Kuznicki, Steve M; Sadrzadeh, Mohtada

2017-10-06

Single and multicomponent gas permeation tests were used to evaluate the performance of metal-supported clinoptilolite membranes. The efficiency of hydrogen separation from lower hydrocarbons (methane, ethane, and ethylene) was studied within the temperature and pressure ranges of 25-600 °C and 110-160 kPa, respectively. The hydrogen separation factor was found to reduce noticeably in the gas mixture compared with single gas experiments at 25 °C. The difference between the single and multicomponent gas results decreased as the temperature increased to higher than 300 °C, which is when the competitive adsorption-diffusion mechanism was replaced by Knudsen diffusion or activated diffusion mechanisms. To evaluate the effect of gas adsorption, the zeolite surface isotherms of each gas in the mixture were obtained from 25 °C to 600 °C. The results indicated negligible adsorption of individual gases at temperatures higher than 300 °C. Increasing the feed pressure resulted in a higher separation efficiency for the individual gases compared with the multicomponent mixture, due to the governing effect of the adsorptive mechanism. This study provides valuable insight into the application of natural zeolites for the separation of hydrogen from a mixture of hydrocarbons.

Long term contracts in portfolios of core LDC gas supply

International Nuclear Information System (INIS)

John, F.E.

1992-01-01

This paper recommends that local distribution companies (LDCs) should use a portfolio approach for their gas supply strategy. The author recommends that LDCs not rely on spot supplies to meet the peak needs of the core residential and commercial markets. He recommends that a secure supply through long-term contracts are better sources than spot or even intermediate term suppliers. The paper provides a brief outline format of the advantages to the use of a portfolio approach which include the rapid restructuring of the market, general changes in the market, and general market performance. By maintaining a portfolio, a list of available natural gas suppliers is always available. This portfolio also acts to compare pricing between short, medium, and long-term pricing for the LDCs

Apparatus and method for treating pollutants in a gas using hydrogen peroxide and UV light

Science.gov (United States)

Cooper, Charles David (Inventor); Clausen, Christian Anthony (Inventor)

2005-01-01

An apparatus for treating pollutants in a gas may include a source of hydrogen peroxide, and a treatment injector for creating and injecting dissociated hydrogen peroxide into the flow of gas. The treatment injector may further include an injector housing having an inlet, an outlet, and a hollow interior extending therebetween. The inlet may be connected in fluid communication with the source of hydrogen peroxide so that hydrogen peroxide flows through the hollow interior and toward the outlet. At least one ultraviolet (UV) lamp may be positioned within the hollow interior of the injector housing. The at least one UV lamp may dissociate the hydrogen peroxide flowing through the tube. The dissociated hydrogen peroxide may be injected into the flow of gas from the outlet for treating pollutants, such as nitrogen oxides.

Commercial gas utilization in the Netherlands. Six years of the Marketing Plan Public Gas Supply (MOG)

International Nuclear Information System (INIS)

Hoelen, Q.E.J.J.M.; Bartholomeus, P.H.J.; Mallon, W.Ch.

1998-01-01

In 1992, Gasunie (Dutch natural gas trading company) started its marketing plan for the public natural gas supply (MOG, abbreviated in Dutch). The aim is to promote the use of natural gas in cooperation with gas utilities. For the commercial sector many different gas appliances are available: high-efficiency deep-frying pans for the catering sector, gas-fired air humidifiers for office and public buildings, gas-fired tumble dryers for small and medium-sized businesses, etc

Hydrogen perspectives in Japan

International Nuclear Information System (INIS)

Furutani, H.

2000-01-01

Hydrogen energy is considered to present a potential effective options for achieving the greenhouse gas minimization. The MITI (Ministry of International Trade and Industry) of Japanese Government is promoting the WE-NET (World Energy Network System) Project which envisions (1) construction of a global energy network for effective supply, transportation, storage and utilization of renewable energy using hydrogen as an energy carrier as a long-term options of sustainable energy economy, and (2) promotion of market entry of hydrogen energy in near and/or mid future even before construction of a WE-NET system. In this paper, I would like to report how far the hydrogen energy technology development addressed under Phase I has progressed, and describe the outline of the Phase II Plan. (author)

Europe's gas consumption and imports to increase with adequate low cost supplies

International Nuclear Information System (INIS)

Odell, P.R.

1997-01-01

Gas in Europe has always been sold above its long-run supply price. Lower prices, however, still permit profitable indigeneous supply expansion. As further reductions in production and transport costs from technological advances are expected, this will continue based on the exploitation of large proven and probable reserves. By 2025, indigeneous output will be 60% up on 1995. Nevertheless, an average 2.2%/annum growth in gas demand will increase import dependence from 130 to 320 BCM over this period. Future international oil prices indicate gas-equivalent border values adequate to secure profitable supply from a range of external sources, leading to continuing competition for markets and the diversification of imports. (9 tables; 31 references). (author)

A strategic model of European gas supply (GASMOD)

International Nuclear Information System (INIS)

Holz, Franziska; Hirschhausen, Christian von; Kemfert, Claudia

2008-01-01

This paper presents a model of the European natural gas supply, GASMOD, which is structured as a two-stage-game of successive natural gas exports to Europe (upstream market) and wholesale trade within Europe (downstream market) and which explicitly includes infrastructure capacities. We compare three possible market scenarios: Cournot competition in both markets, perfect competition in both markets, and perfect competition in the downstream with Cournot competition in the upstream market (EU liberalization). We find that Cournot competition in both markets is the most accurate representation of today's European natural gas market, where suppliers at both stages generate a mark-up at the expense of the final customer (double marginalization). Our results yield a diversified supply portfolio with newly emerging (LNG) exporters gaining market shares. Enforcing competition in the European downstream market would lead to lower prices and higher quantities by avoiding the welfare-reducing effects of double marginalization. Binding infrastructure capacity restrictions strongly influence the results, and we identify bottlenecks mainly for intra-European trade relations whereas transport capacity in the upstream market is globally sufficient in the Cournot scenario. (author)

Marketing with regards to the opening of new areas for the supply of gas

Energy Technology Data Exchange (ETDEWEB)

Knapp, U [Westfaelische Ferngas-A.G., Dortmund (Germany, F.R.)

1978-08-01

During the last years more and more areas have been opened up for the supply of gas in the Federal Republic of Germany. As a rule, the density of consumption here is lower than in the traditionally supplied areas. Special activities in the marketing field are therefore necessary. The report relates the marketing measures of a regional gas supplying company in their sequential progress. Other measures regarding the opening-up of new areas for the supply of gas which lie outside the area of marketing are drawn into the presentation in order to clarify their objective and progressional association with the marketing activities.

Inspection of the hydrogen gas pressure with metal shield by cold neutron radiography at CMRR

Energy Technology Data Exchange (ETDEWEB)

Li, Hang; Cao, Chao; Huo, Heyong; Wang, Sheng; Wu, Yang; Yin, Wei; Sun, Yong; Liu, Bin; Tang, Bin [Institute of Nuclear Physics and Chemistry, Chinese Academy of Engineering Physics, Mianyang (China); Key Laboratory of Neutron Physics, Chinese Academy of Engineering Physics, Mianyang (China)

2017-04-11

The inspection of the process of gas pressure change is important for some applications (e.g. gas tank stockpile or two phase fluid model) which need quantitative and non-touchable measurement. Neutron radiography provides a suitable tool for such investigations with nice resolution. The quantitative cold neutron radiography (CNR) is developed at China Mianyang Research Reactor (CMRR) to measure the hydrogen gas pressure with metal shield. Because of the high sensitivity to hydrogen, even small change of the hydrogen pressure can be inspected by CNR. The dark background and scattering neutron effect are both corrected to promote measurement precision. The results show that CNR can measure the hydrogen gas pressure exactly and the pressure value average relative error between CNR and barometer is almost 1.9%.

A NEW APPROACH TO THE ASSESSMENT OF EFFECTIVE MANAGEMENT OF GAS SUPPLY DIVERSIFICATION

Directory of Open Access Journals (Sweden)

Oleh Dzoba

2017-11-01

Full Text Available The purpose of the paper is to study the current state and trends in the development of the basic indicators of the EU gas sector, to generalize the theoretical and methodological approaches to calculating the gas diversification factor, assess and analyze its level in the EU countries in 2001-2015, and study the experience of European countries in addressing the diversification problems. Methodology. The methodological basis of the study was the works of domestic and foreign scientists devoted to the issues of gas supply diversification. The study is based on the analysis of the gas sector indicators and used analysis, synthesis, combination grouping and statistical-economic methods. Results of the of the study showed that in the EU countries in recent years there has been a noticeable tendency to reduce natural gas reserves, reduce the level of its production and increase consumption, which leads to an increase in import dependence. The largest consumers of natural gas in the EU are the United Kingdom, Germany, Italy, the Netherlands and France. The main external importers of pipeline gas to the EU countries are the Russian Federation, Algeria and Norway, and liquefied gas – Qatar, Algeria and Nigeria. It is established that at the end of 2015, the most diversified gas supply is to countries such as France, Belgium and Italy; a low level of gas supply diversification is observed in Hungary, Poland and Greece. Practical implications. The analysis of basic indicators which characterize the state and development of trends of the European gas market in 2000-2015 is carried out. The assessment and analysis of the level of diversification of natural gas supplies in the EU countries in 2001-2015 have been analyzed. Value/originality. It was proposed an original approach to calculate the gas diversification factor, which takes into account both the number of sources and the structure of the volumes of supplies from different sources.

A study on the role of nuclear energy in the demand-supply structure in the 21st century. Towards the use of hydrogen and electricity energy

Energy Technology Data Exchange (ETDEWEB)

Morikawa, Shinichi; Kawanami, Jun [Institute of Nuclear Safety System Inc., Mihama, Fukui (Japan)

2001-09-01

It is said that global warming has been caused by the massive consumption of fossil fuel such as oil and coal. As a fundamental measure to solve this problem, hydrogen is highly expected to be the next-generation energy source, the by-product after combustion of which is water. Previous studies have concentrated on the examination of hydrogen-producing systems that use such means as sunlight or wind power generation and transporting liquefied hydrogen to Japan (NEDO WE-NET Plan). In this study, a simulation using the energy demand-supply model was conducted in view of the advent of an energy system that is based on hydrogen and electrical energy while taking hydrogen production by means of nuclear power such as a high-temperature gas reactor into consideration. On the basis of the results, the conditions for dissemination of use of hydrogen and the role of nuclear power were examined. As a result, we found that widespread use of hydrogen will be promoted by environmental regulations and that hydrogen produced by means of nuclear power, which does not produce carbon dioxide at the time of production, will likely play an important role. (author)

18 CFR 2.105 - Gas supply charges.

Science.gov (United States)

2010-04-01

... 18 Conservation of Power and Water Resources 1 2010-04-01 2010-04-01 false Gas supply charges. 2.105 Section 2.105 Conservation of Power and Water Resources FEDERAL ENERGY REGULATORY COMMISSION... prior to nominations by the customers a firm price or pricing formula for the service, and hold that...

Gas centrifuge power supplies (inverters): Key components and subassemblies

International Nuclear Information System (INIS)

1987-08-01

This document was prepared to serve as a guide for export control officials in their interpretation, understanding, and implementation of exports laws that relate to the international trigger list entry for gas centrifuge power supplies (also known as frequency changers, convertors, or inverters) and parts, components, and subassemblies of such power supplies. Particular emphasis is placed on descriptions of the key parts, components, and subassemblies of such power supplies, which were previously unspecified, so as to clarify the intent of the international trigger list entry

Determination of hydrogen in uranium-niobium-zirconium alloy by inert-gas fusion

International Nuclear Information System (INIS)

Carden, W.F.

1979-12-01

An improved method has been developed using inert-gas fusion for determining the hydrogen content in uranium-niobium-zirconium (U-7.5Nb-2.5Zr) alloy. The method is applicable to concentrations of hydrogen ranging from 1 to 250 micrograms per gram and may be adjusted for analysis of greater hydrogen concentrations. Hydrogen is determined using a hydrogen determinator. The limit of error for a single determination at the 95%-confidence level (at the 3.7-μg/g-hydrogen level) is +-1.4 micrograms per gram hydrogen

Advances of zeolite based membrane for hydrogen production via water gas shift reaction

Science.gov (United States)

Makertihartha, I. G. B. N.; Zunita, M.; Rizki, Z.; Dharmawijaya, P. T.

2017-07-01

Hydrogen is considered as a promising energy vector which can be obtained from various renewable sources. However, an efficient hydrogen production technology is still challenging. One technology to produce hydrogen with very high capacity with low cost is through water gas shift (WGS) reaction. Water gas shift reaction is an equilibrium reaction that produces hydrogen from syngas mixture by the introduction of steam. Conventional WGS reaction employs two or more reactors in series with inter-cooling to maximize conversion for a given volume of catalyst. Membrane reactor as new technology can cope several drawbacks of conventional reactor by removing reaction product and the reaction will favour towards product formation. Zeolite has properties namely high temperature, chemical resistant, and low price makes it suitable for membrane reactor applications. Moreover, it has been employed for years as hydrogen selective layer. This review paper is focusing on the development of membrane reactor for efficient water gas shift reaction to produce high purity hydrogen and carbon dioxide. Development of membrane reactor is discussed further related to its modification towards efficient reaction and separation from WGS reaction mixture. Moreover, zeolite framework suitable for WGS membrane reactor will be discussed more deeply.

All quiet on the eastern front? Disruption scenarios of Russian natural gas supply to Europe

International Nuclear Information System (INIS)

Richter, Philipp M.; Holz, Franziska

2015-01-01

The 2014 Russian–Ukrainian crisis reignited European concerns about natural gas supply security recalling the experiences of 2006 and 2009. However, the European supply situation, regulation and infrastructure have changed, with better diversified import sources, EU member states being better connected and a common regulation on the security of supply has been introduced. Nevertheless, European dependency on natural gas remained high. This paper investigates different Russian natural gas export disruptions scenarios and analyses short- and long-term reactions in Europe. We use the Global Gas Model (GGM), a large-scale mixed complementarity representation of the natural gas sector with a high level of technical granularity with respect to storage and transportation infrastructure. While we find that most of the EU member states are not severely affected by Russian disruptions, some East European countries are very vulnerable. Prioritizing the removal of infrastructure bottlenecks is critical for securing a sufficient natural gas supply to all EU member states. - Highlights: • We analyze disruption scenarios of Russian natural gas exports to Europe. • Most EU countries are only weakly affected by a complete Russian supply disruption. • We find that Eastern Europe is vulnerable to Russian supply disruptions. • We identify infrastructure bottlenecks in the European natural gas network. • We find that the large EU LNG import capacity is not sufficiently connected

Kinetic Models Study of Hydrogenation of Aromatic Hydrocarbons in Vacuum Gas Oil and Basrah Crude Oil Reaction

Directory of Open Access Journals (Sweden)

Muzher M. Ibraheem

2013-05-01

Full Text Available             The aim of this research is to study the kinetic reaction models for catalytic hydrogenation of aromatic content for Basrah crude oil (BCO and vacuum gas oil (VGO derived from Kirkuk crude oil which has the boiling point rang of (611-833K.            This work is performed using a hydrodesulphurization (HDS pilot plant unit located in AL-Basil Company. A commercial (HDS catalyst cobalt-molybdenum (Co-Mo supported in alumina (γ-Al2O3 is used in this work. The feed is supplied by North Refinery Company in Baiji. The reaction temperatures range is (600-675 K over liquid hourly space velocity (LHSV range of (0.7-2hr-1 and hydrogen pressure is 3 MPa with H2/oil ratio of 300 of Basrah Crude oil (BCO, while the corresponding conditions for vacuum gas oil (VGO are (583-643 K, (1.5-3.75 hr-1, 3.5 MPa and 250  respectively .            The results showed that the reaction kinetics is of second order for both types of feed. Activation energies are found to be 30.396, 38.479 kJ/mole for Basrah Crude Oil (BCO and Vacuum Gas Oil (VGO respectively.

Hydrogen energy assessment

Energy Technology Data Exchange (ETDEWEB)

Salzano, F J; Braun, C [eds.

1977-09-01

The purpose of this assessment is to define the near term and long term prospects for the use of hydrogen as an energy delivery medium. Possible applications of hydrogen are defined along with the associated technologies required for implementation. A major focus in the near term is on industrial uses of hydrogen for special applications. The major source of hydrogen in the near term is expected to be from coal, with hydrogen from electric sources supplying a smaller fraction. A number of potential applications for hydrogen in the long term are identified and the level of demand estimated. The results of a cost benefit study for R and D work on coal gasification to hydrogen and electrolytic production of hydrogen are presented in order to aid in defining approximate levels of R and D funding. A considerable amount of data is presented on the cost of producing hydrogen from various energy resources. A key conclusion of the study is that in time hydrogen is likely to play a role in the energy system; however, hydrogen is not yet competitive for most applications when compared to the cost of energy from petroleum and natural gas.

Hydrogen from nuclear power

International Nuclear Information System (INIS)

Miller, A.I.

2006-01-01

A few years ago, one frequently heard the view that LNG would cap the price of natural gas in North America at around 5 or 6 US$/GJ just as soon as sufficient terminal capacity could be installed. Recent experience with international LNG prices suggests that this is unlikely. While oil and gas prices have proven almost impossible to predict it seems likely that the price of gas will in future broadly track its energy equivalent in oil. Consequently, planning for natural gas at 10 $/GJ would seem prudent. Using steam-methane reforming, this produces hydrogen at 1500 $/t. If CO 2 has to be sequestered, adding another 500 $/t H 2 is a likely additional cost. So is water electrolysis now competitive? Electrolysis would deliver hydrogen at 2000$/t if electricity costs 3.7 US cents/kWh. This is lower than the Alberta Pool average supply price but very close to AECL's estimated cost for power from a new reactor. However, electricity prices in deregulated markets vary hugely and there would be large leverage on the hydrogen price in delivering a mix of electricity (when the Pool price is high) and hydrogen (when it is low). The key to that possibility - as well as other issues of interruptibility - is low-cost cavern storage, similar to that used for natural gas. One long-standing example for hydrogen storage exists in the UK. The nuclear-electrolysis route offers long-term price stability. It also has co-product possibilities if a use can be found for oxygen (equivalent to about 300 $/t H 2 ) and to produce heavy water (provided the scale is at least 100 MW)

Management of natural gas supply reliability and modulation in France

International Nuclear Information System (INIS)

Dupas, D.

1995-01-01

France imports most of its gas, and demand for gas varies considerably between summer and winter. Faced with insufficient flexibility in its supply contracts to deal with the gas balance, Gaz de France decided to develop a policy based on combined and consistent use of a large-scale underground storage system, a suspendable clientele, and a rate policy to maintain the balance. It was the integrated character of the company that makes it possible to optimize the arrangement of these adjustment facilities. Most of the seasonal modulation is taken up by underground storage in water tables, and the peak cold complement comes from salt dome storage. Underground storage also contributes, as does the suspendable clientele, to supply reliability, with a specific quality due to their speed and versatility of use. The prime purpose of the suspendable clientele portfolio is rather to respond to supply failures, but the demand too, during periods of extreme cold, is reduced by curtailing deliveries whose contractual suspension notice time is short. (author). 3 figs

TRANSPETRO gas security of supply program; Programa de confiabilidade de suprimento de gas natural da TRANSPETRO

Energy Technology Data Exchange (ETDEWEB)

Faertes, Denise [PETROBRAS Transporte S.A. (TRANSPETRO), Rio de Janeiro, RJ (Brazil)

2005-07-01

The purpose of this paper is to present the Gas Security of Supply Program that is being implemented at TRANSPETRO since 2002. It includes the application of the state of the art techniques and models related to reliability engineering. The main objective of the program is to evaluate and optimize overall gas network performance and to provide gas to different consumers (industrial, residential, thermo-plants and vehicles) in compliance with stated reliability levels. Heavy fines will be applied to PETROBRAS in case of occurrence of shortfalls. We hope that this paper can contribute to a wider discussion about this subject of performance indicators involving security of supply, safety and environment preservation. (author)

Emergency management in the gas and water supply; Notfallmanagement in der Gas- und Wasserversorgung

Energy Technology Data Exchange (ETDEWEB)

Boy, Stephan [KKI GmbH, Kompetenzzentrum Kritische Infrastrukturen GmbH, Berlin (Germany)

2013-06-15

Gas and water pipes belong to the critical infrastructure in Germany. Their protection requires a holistic risk analysis, which also keep an eye on the dependence of the power supply. [German] Gas- und Wasserleitungen gehoeren zu den kritischen Infrastrukturen in Deutschland. Ihr Schutz erfordert eine ganzheitliche Risikoanalyse, die auch die Abhaengigkeit von der Stromversorgung im Blick hat.

Hydrogen Gas Inhalation Attenuates Seawater Instillation-Induced Acute Lung Injury via the Nrf2 Pathway in Rabbits.

Science.gov (United States)

Diao, Mengyuan; Zhang, Sheng; Wu, Lifeng; Huan, Le; Huang, Fenglou; Cui, Yunliang; Lin, Zhaofen

2016-12-01

Seawater instillation-induced acute lung injury involves oxidative stress and apoptosis. Although hydrogen gas inhalation is reportedly protective in multiple types of lung injury, the effect of hydrogen gas inhalation on seawater instillation-induced acute lung injury remains unknown. This study investigated the effect of hydrogen gas on seawater instillation-induced acute lung injury and explored the mechanisms involved. Rabbits were randomly assigned to control, hydrogen (2 % hydrogen gas inhalation), seawater (3 mL/kg seawater instillation), and seawater + hydrogen (3 mL/kg seawater instillation + 2 % hydrogen gas inhalation) groups. Arterial partial oxygen pressure and lung wet/dry weight ratio were detected. Protein content in bronchoalveolar lavage fluid (BALF) and serum as well as tumor necrosis factor (TNF)-α, interleukin (IL)-1β, and IL-6 levels were determined. Hematoxylin-eosin staining was used to monitor changes in lung specimens, and malondialdehyde (MDA) content and myeloperoxidase (MPO) activity were assayed. In addition, NF-E2-related factor (Nrf) 2 and heme oxygenase (HO)-1 mRNA and protein expression were measured, and apoptosis was assessed by measuring caspase-3 expression and using terminal deoxy-nucleotidyl transferase dUTP nick end-labeling (TUNEL) staining. Hydrogen gas inhalation markedly improved lung endothelial permeability and decreased both MDA content and MPO activity in lung tissue; these changes were associated with decreases in TNF-α, IL-1β, and IL-6 in BALF. Hydrogen gas also alleviated histopathological changes and cell apoptosis. Moreover, Nrf2 and HO-1 expressions were significantly activated and caspase-3 expression was inhibited. These results demonstrate that hydrogen gas inhalation attenuates seawater instillation-induced acute lung injury in rabbits and that the protective effects observed may be related to the activation of the Nrf2 pathway.

Application of Hydrogen Assisted Lean Operation to Natural Gas-Fueled Reciprocating Engines (HALO)

Energy Technology Data Exchange (ETDEWEB)

Chad Smutzer

2006-01-01

Two key challenges facing Natural Gas Engines used for cogeneration purposes are spark plug life and high NOx emissions. Using Hydrogen Assisted Lean Operation (HALO), these two keys issues are simultaneously addressed. HALO operation, as demonstrated in this project, allows stable engine operation to be achieved at ultra-lean (relative air/fuel ratios of 2) conditions, which virtually eliminates NOx production. NOx values of 10 ppm (0.07 g/bhp-hr NO) for 8% (LHV H2/LHV CH4) supplementation at an exhaust O2 level of 10% were demonstrated, which is a 98% NOx emissions reduction compared to the leanest unsupplemented operating condition. Spark ignition energy reduction (which will increase ignition system life) was carried out at an oxygen level of 9%, leading to a NOx emission level of 28 ppm (0.13 g/bhp-hr NO). The spark ignition energy reduction testing found that spark energy could be reduced 22% (from 151 mJ supplied to the coil) with 13% (LHV H2/LHV CH4) hydrogen supplementation, and even further reduced 27% with 17% hydrogen supplementation, with no reportable effect on NOx emissions for these conditions and with stable engine torque output. Another important result is that the combustion duration was shown to be only a function of hydrogen supplementation, not a function of ignition energy (until the ignitability limit was reached). The next logical step leading from these promising results is to see how much the spark energy reduction translates into increase in spark plug life, which may be accomplished by durability testing.

Essays on the economics of energy markets. Security of supply and greenhouse gas abatement

International Nuclear Information System (INIS)

Dieckhoener, Caroline

2013-01-01

In summary, the presented thesis analyzes two distinct economic subjects: security of supply in natural gas markets and greenhouse gas abatement potentials in the residential heating market. These subjects considered both reflect key points in the triangle of energy policy and are both associated with transnational market failures within energy markets. The security of supply analyses in an intermeshed network are approached from a rather normative, top-down perspective of a social planner. On the contrary, the analyses of greenhouse gases emitted by households are positive analyses of consumer choices. The normative analyses of security of supply in natural gas markets and the positive analyses on greenhouse gas abatement in the residential heating market are organized in two parts of the thesis. 1. Normative analyses - Security of supply in natural gas markets: The two papers of the first part of the dissertation thesis are based on a normative approach with the European natural gas market and infrastructure model TIGER that allows for security of supply analyses. The general idea behind the modeling approach is based on the assumption of a social planner and finds an efficient utilization of the natural gas infrastructure. More precisely, the security of supply analyses conducted in the first part of the thesis refer to scenario simulations of disrupted supply routes in the European natural gas network. The effects of these security of supply scenarios on the usage of other infrastructure components, on marginal supply costs and disruptions to consumers are investigated. 2. Positive analyses of greenhouse gas abatement potentials - Econometric modeling of consumer choices and evaluation of public policies: The second part of the thesis includes two positive analyses which investigate household choices to derive greenhouse gas abatement potentials. In the residential heating market, the energy efficiency level exhibited and the type of energy carrier used are

Essays on the economics of energy markets. Security of supply and greenhouse gas abatement

Energy Technology Data Exchange (ETDEWEB)

Dieckhoener, Caroline

2013-02-01

In summary, the presented thesis analyzes two distinct economic subjects: security of supply in natural gas markets and greenhouse gas abatement potentials in the residential heating market. These subjects considered both reflect key points in the triangle of energy policy and are both associated with transnational market failures within energy markets. The security of supply analyses in an intermeshed network are approached from a rather normative, top-down perspective of a social planner. On the contrary, the analyses of greenhouse gases emitted by households are positive analyses of consumer choices. The normative analyses of security of supply in natural gas markets and the positive analyses on greenhouse gas abatement in the residential heating market are organized in two parts of the thesis. 1. Normative analyses - Security of supply in natural gas markets: The two papers of the first part of the dissertation thesis are based on a normative approach with the European natural gas market and infrastructure model TIGER that allows for security of supply analyses. The general idea behind the modeling approach is based on the assumption of a social planner and finds an efficient utilization of the natural gas infrastructure. More precisely, the security of supply analyses conducted in the first part of the thesis refer to scenario simulations of disrupted supply routes in the European natural gas network. The effects of these security of supply scenarios on the usage of other infrastructure components, on marginal supply costs and disruptions to consumers are investigated. 2. Positive analyses of greenhouse gas abatement potentials - Econometric modeling of consumer choices and evaluation of public policies: The second part of the thesis includes two positive analyses which investigate household choices to derive greenhouse gas abatement potentials. In the residential heating market, the energy efficiency level exhibited and the type of energy carrier used are

High Temperature Gas-cooled Reactor Projected Markets and Scoping Economics

Energy Technology Data Exchange (ETDEWEB)

Larry Demick

2010-08-01

The NGNP Project has the objective of developing the high temperature gas-cooled reactor (HTGR) technology to supply high temperature process heat to industrial processes as a substitute for burning of fossil fuels, such as natural gas. Applications of the HTGR technology that have been evaluated by the NGNP Project for supply of process heat include supply of electricity, steam and high-temperature gas to a wide range of industrial processes, and production of hydrogen and oxygen for use in petrochemical, refining, coal to liquid fuels, chemical, and fertilizer plants.

The use of PEM united regenerative fuel cells in solar- hydrogen systems for remote area power supply

International Nuclear Information System (INIS)

Arun K Doddathimmaiah; John Andrews

2006-01-01

Remote area power supply (RAPS) is a potential early market for renewable energy - hydrogen systems because of the relatively high costs of conventional energy sources in remote regions. Solar hydrogen RAPS systems commonly employ photovoltaic panels, a Proton Exchange Membrane (PEM) electrolyser, a storage for hydrogen gas, and a PEM fuel cell. Currently such systems are more costly than conventional RAPS systems employing diesel generator back up or battery storage. Unitized regenerative fuel cells (URFCs) have the potential to lower the costs of solar hydrogen RAPS systems since a URFC employs the same hardware for both the electrolyser and fuel cell functions. The need to buy a separate electrolyser and a separate fuel cell, both expensive items, is thus avoided. URFCs are in principle particularly suited for use in RAPS applications since the electrolyser function and fuel cell function are never required simultaneously. The present paper reports experimental findings on the performance of a URFC compared to that of a dedicated PEM electrolyser and a dedicated fuel cell. A design for a single-cell PEM URFC for use in experiments is described. The experimental data give a good quantitative description of the performance characteristics of all the devices. It is found that the performance of the URFC in the electrolyser mode is closely similar to that of the stand-alone electrolyser. In the fuel cell mode the URFC performance is, however, lower than that of the stand-alone fuel cell. The wider implications of these findings for the economics of future solar-hydrogen RAPS systems are discussed, and a design target of URFCs for renewable-energy RAPS applications proposed. (authors)

Hydrogen Separation by Natural Zeolite Composite Membranes: Single and Multicomponent Gas Transport

Directory of Open Access Journals (Sweden)

Afrooz Farjoo

2017-10-01

Full Text Available Single and multicomponent gas permeation tests were used to evaluate the performance of metal-supported clinoptilolite membranes. The efficiency of hydrogen separation from lower hydrocarbons (methane, ethane, and ethylene was studied within the temperature and pressure ranges of 25–600 °C and 110–160 kPa, respectively. The hydrogen separation factor was found to reduce noticeably in the gas mixture compared with single gas experiments at 25 °C. The difference between the single and multicomponent gas results decreased as the temperature increased to higher than 300 °C, which is when the competitive adsorption–diffusion mechanism was replaced by Knudsen diffusion or activated diffusion mechanisms. To evaluate the effect of gas adsorption, the zeolite surface isotherms of each gas in the mixture were obtained from 25 °C to 600 °C. The results indicated negligible adsorption of individual gases at temperatures higher than 300 °C. Increasing the feed pressure resulted in a higher separation efficiency for the individual gases compared with the multicomponent mixture, due to the governing effect of the adsorptive mechanism. This study provides valuable insight into the application of natural zeolites for the separation of hydrogen from a mixture of hydrocarbons.

Natural gas supply and demand projections for the Asia-Pacific region

International Nuclear Information System (INIS)

Khin, J.A.

1992-01-01

The phenomenon of rapid economic growth in the Asia Pacific has inevitably led the countries of this region to expand and diversify their energy sources in order to satisfy their burgeoning energy demands. Natural gas has become an increasingly marketable energy source in this region benefitting from vast reserves and its advantages as an environmentally clean fuel. As a result of the impact of the two oil shocks of the 1970's on the Asia Pacific economy, the governments in the region set about the development of energy strategies which would make their national economies more resilient to the instabilities of world energy price and supply. The Japanese Gas Industry has estimated that the overall rise in demand for energy in Asia, set at an average rate of 3.7% per annum, will see a corresponding growth in demand for natural gas at 5%. Experts from a number of major oil companies, such as Exxon, expect an annual growth in the Asian natural gas market of 6.0 to 6.3%. These figures are over shadowed by the worldwide demand for natural gas which is expected to gain an 8% increase within the next two decades. Approximately 8.75% of the world's proven natural gas reserves are held in Asia-Pacific region (Table I). Most of the region's natural gas production will provide over 100 years of supply. A review of natural gas supply/demand in the Asia-Pacific region is presented in sub-regions, namely ASIAN, Northeast Asia, the Indian Subcontinent and Oceania

Zero emission distributed hydrogen production

International Nuclear Information System (INIS)

Maddaloni, J.; Rowe, A.; Bailey, R.; McDonald, J.D.

2004-01-01

The need for distributed production facilities has become a critical issue in developing a hydrogen infrastructure. Hydrogen generation using processes that make effective use of what would normally be considered waste streams or process inefficiencies can have more favorable economics than stand-alone technologies. Currently, natural gas is distributed to industrial and residential customers through a network of pipelines. High pressure main lines move gas to the vicinity of consumers where the pressure is reduced for local, low pressure distribution. Often, the practice is to use an isenthalpic expansion which results in a cooling of the gas stream. Some of the natural gas is burned to preheat the fuel so that the temperature after the expansion is near ambient. This results in the destruction of exergy in the high pressure gas stream and produces CO 2 in the process. If, instead, a turbo-expander is used to reduce the stream pressure, work can be recovered using a generator and hydrogen can be produced via electrolysis. This method of hydrogen production is free of green-house gas emissions, makes use of existing gas distribution facilities, and uses exergy that would otherwise be destroyed. Pressure reduction using the work producing process (turbo-expander) is accompanied by a large drop in temperature, on the average of 70 K. The local gas distributor requires the gas temperature to be raised again to near 8 o C to prevent damage to valve assemblies. The required heating power after expansion can be on the order of megawatts (site dependent.) Supplying the heat can be seen as a cost if energy is taken from the system to reheat the fuel; however, the low temperature stream may also be considered an asset if the cooling power can be used for a local process. This analysis is the second stage of a study to examine the technical and economic feasibility of using pressure let-down sites as hydrogen production facilities. This paper describes a proposed

Current supply/demand outlook and its impact on gas marketing strategies

International Nuclear Information System (INIS)

Maffitt, D.

1994-01-01

The current supply/demand outlook for natural gas in Canada is discussed, starting with a review of natural gas supply trends since the deregulation of the market in 1985/86. Market demand trends and expansion of export pipeline capacity are summarized to demonstrate how radically the North American gas marketing industry has changed in the last decade. As of January 1st 1993, Canada ranked eleventh in the world with respect to remaining natural gas reserves (96 Tft 3 ), which represents only 2% of global gas reserves. Canada ranks third in gas production (5 Tft 3 /y), behind the USA and former Soviet Union (19 and 29 Tft 3 /y, respectively). In western Canada, gas production rates have increased 75% since deregulation. Canadian domestic demand has grown 24% since 1985 to the 1993 level of 2.1 Tft 3 /y, while exports to the USA have grown 144% to 2.2 Tft 3 /y. The present environment requires a 'just in time' attitude towards developing new gas reserves and arranging transportation and storage. Long term gas marketing transacations are increasingly deliverability-based, firm delivery commitments which include harsh penalties for nonperformance. 7 figs

EMF 9 scenarios Canadian natural gas: Potential demand and supply

International Nuclear Information System (INIS)

Anon.

1989-01-01

The basic analytical perspectives of this work are: (1) Canada is a price taker on the US natural gas market; (2) Gas competes with HFO in both markets, and Canada is integrated into the international oil market; (3) Canadian and US income growth rates are consistent with each other, given the major influence of US economic performance on that of the Canadian economy; and (4) Given the price, income and other assumptions, we used the Board's Energy Demand Model to calculate annual demand for natural gas in each price case. We used the Board's models for reserves additions and productive capacity estimation to calculate potential annual supply. The difference between demand and potential supply is the potential exportable volume. The annual productive capacity curve assumes, agnostically, that all potential production is sold yearly

Empirical Method to Estimate Hydrogen Embrittlement of Metals as a Function of Hydrogen Gas Pressure at Constant Temperature

Science.gov (United States)

Lee, Jonathan A.

2010-01-01

High pressure Hydrogen (H) gas has been known to have a deleterious effect on the mechanical properties of certain metals, particularly, the notched tensile strength, fracture toughness and ductility. The ratio of these properties in Hydrogen as compared to Helium or Air is called the Hydrogen Environment Embrittlement (HEE) Index, which is a useful method to classify the severity of H embrittlement and to aid in the material screening and selection for safety usage H gas environment. A comprehensive world-wide database compilation, in the past 50 years, has shown that the HEE index is mostly collected at two conveniently high H pressure points of 5 ksi and 10 ksi near room temperature. Since H embrittlement is directly related to pressure, the lack of HEE index at other pressure points has posed a technical problem for the designers to select appropriate materials at a specific H pressure for various applications in aerospace, alternate and renewable energy sectors for an emerging hydrogen economy. Based on the Power-Law mathematical relationship, an empirical method to accurately predict the HEE index, as a function of H pressure at constant temperature, is presented with a brief review on Sievert's law for gas-metal absorption.

Development of the Raman lidar system for remote hydrogen gas detection

Energy Technology Data Exchange (ETDEWEB)

Choi, In Young; Baik, Sung Hoon; Park, Seung Kyu; Park, Nak Gyu; Choi, Young Soo [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2016-10-15

Detection of hydrogen (H{sub 2}) gas leakage is very important for safety of the nuclear power plant because H{sub 2} gas is very flammable and explosive. H{sub 2} gas is generated by oxidizing the nuclear fuel cladding during the critical accident and generated H{sub 2} gas leads to serious secondary damages in the containment building of nuclear power plant. Thus, various H{sub 2} gas detection techniques are used in the nuclear power plant such as catalytic combustion sensors, semiconducting oxide sensors, thermal conductivity sensors and electrochemical sensor. A Raman lidar (Light Detection And Ranging) system for remote detection of the H{sub 2} gas can cover the area in the containment building of a nuclear power plant. H{sub 2} gas has a very strong Raman Effect, and H{sub 2} Raman cells have been widely used for laser wavelength conversion. In this study, Raman lidar system was developed for H{sub 2} gas detection used in the containment building of nuclear power plant. In this study, remote hydrogen gas detection devices and measuring algorithm are developed by using the Raman lidar method. Through the experiment, we proved that our developed Raman lidar system was possible to measure the N{sub 2} and H{sub 2} gas scattering signal remotely.

Application of CFRP with High Hydrogen Gas Barrier Characteristics to Fuel Tanks of Space Transportation System

Science.gov (United States)

Yonemoto, Koichi; Yamamoto, Yuta; Okuyama, Keiichi; Ebina, Takeo

In the future, carbon fiber reinforced plastics (CFRPs) with high hydrogen gas barrier performance will find wide applications in all industrial hydrogen tanks that aim at weight reduction; the use of such materials will be preferred to the use of conventional metallic materials such as stainless steel or aluminum. The hydrogen gas barrier performance of CFRP will become an important issue with the introduction of hydrogen-fuel aircraft. It will also play an important role in realizing fully reusable space transportation system that will have high specific tensile CFRP structures. Such materials are also required for the manufacture of high-pressure hydrogen gas vessels for use in the fuel cell systems of automobiles. This paper introduces a new composite concept that can be used to realize CFRPs with high hydrogen gas barrier performance for applications in the cryogenic tanks of fully reusable space transportation system by the incorporation of a nonmetallic crystal layer, which is actually a dense and highly oriented clay crystal laminate. The preliminary test results show that the hydrogen gas barrier characteristics of this material after cryogenic heat shocks and cyclic loads are still better than those of other polymer materials by approximately two orders of magnitude.

Hydrogen in a global long-term perspective

International Nuclear Information System (INIS)

Quakernaat, J.

1994-01-01

For many countries, the hydrogen economy offers an operational objective for their long-term energy structure. At the end of the next century, the world will depend on the predominate use of carbon-free and carbon-neutral sources of energy, such as flow energy, energy from modern biomass, and safe nuclear energy. The direct and indirect costs involved in the use of traditional energy supplies will increase sharply in the process of time, so that the economic feasibility of a less intensive use of energy and the introduction of alternative energy supply systems will no longer be insurmountable problems. The supply and demand structures of energy will be optimally blended by the use of hydrogen and electricity, an almost ideal combination of secondary energy carriers. With these carriers, practically every centralized or decentralized, environmentally sound energy supply can be permanently maintained, both within and outside of industrialized, metropolitan areas. The economic development of developing countries will depend on the predominate use of relatively 'cheap' fossil energy carriers (coal, petroleum and natural gas), as well as on the accompanying energy supplies structures. Yet those countries as well, similar to the wealthy industrial countries, will have to start using the highly capital intensive and very energy efficient energy supply systems and energy consumption technologies. This requires innovative strategies that are aimed at compensating developing countries (temporarily) for their lack of purchasing power and knowledge infrastructure. The costs involved in the hydrogen chain are still too high, and the world energy prices are still too low for such a transfer to take place. The attention, however, will focus on drastic energy saving, decarbonization of fossil fuels, substitution to natural gas, the opening up of flow energy, biomass production, and the development of inherent, safe nuclear energy. 49 refs

Role of technology in the U. K. gas industry. past, present, future

Energy Technology Data Exchange (ETDEWEB)

Evans, J W

1979-06-01

A discussion covers the beginning of public gas supply in the U.K.; the production of gas during coal combustion and the oil era; the development of LNG transport technology; the development of the Dent processes for producing gases from hydrocarbon feedstocks including the Catalytic Rich Gas and the Gas Recycle Hydrogenation processes; the growth of the natural gas transmission and distribution industry; the organization and functions of the British Gas Corp. Research and Development Division and Scientific Services; the various technological innovations being used in the transmission, distribution, domestic and industrial utilization sectors of the gas industry; the various efforts leading to the development of a commercial SNG process, based on the Lurgi coal gasifier operated under slagging conditions, that can handle a wide range of coals; and the outlook for future gas supply and demand, a hydrogen economy-based gas industry, and new developments affecting gas transmission and distribution, conservation and utilization.

Heat pump cycle by hydrogen-absorbing alloys to assist high-temperature gas-cooled reactor in producing hydrogen

International Nuclear Information System (INIS)

Satoshi, Fukada; Nobutaka, Hayashi

2010-01-01

A chemical heat pump system using two hydrogen-absorbing alloys is proposed to utilise heat exhausted from a high-temperature source such as a high-temperature gas-cooled reactor (HTGR), more efficiently. The heat pump system is designed to produce H 2 based on the S-I cycle more efficiently. The overall system proposed here consists of HTGR, He gas turbines, chemical heat pumps and reaction vessels corresponding to the three-step decomposition reactions comprised in the S-I process. A fundamental research is experimentally performed on heat generation in a single bed packed with a hydrogen-absorbing alloy that may work at the H 2 production temperature. The hydrogen-absorbing alloy of Zr(V 1-x Fe x ) 2 is selected as a material that has a proper plateau pressure for the heat pump system operated between the input and output temperatures of HTGR and reaction vessels of the S-I cycle. Temperature jump due to heat generated when the alloy absorbs H 2 proves that the alloy-H 2 system can heat up the exhaust gas even at 600 deg. C without any external mechanical force. (authors)

Microbial Electrolysis Cells for High Yield Hydrogen Gas Production from Organic Matter

KAUST Repository

Logan, Bruce E.

2008-12-01

The use of electrochemically active bacteria to break down organic matter, combined with the addition of a small voltage (>0.2 V in practice) in specially designed microbial electrolysis cells (MECs), can result in a high yield of hydrogen gas. While microbial electrolysis was invented only a few years ago, rapid developments have led to hydrogen yields approaching 100%, energy yields based on electrical energy input many times greater than that possible by water electrolysis, and increased gas production rates. MECs used to make hydrogen gas are similar in design to microbial fuel cells (MFCs) that produce electricity, but there are important differences in architecture and analytical methods used to evaluate performance. We review here the materials, architectures, performance, and energy efficiencies of these MEC systems that show promise as a method for renewable and sustainable energy production, and wastewater treatment. © 2008 American Chemical Society.

Dominant rate process of silicon surface etching by hydrogen chloride gas

International Nuclear Information System (INIS)

Habuka, Hitoshi; Suzuki, Takahiro; Yamamoto, Sunao; Nakamura, Akio; Takeuchi, Takashi; Aihara, Masahiko

2005-01-01

Silicon surface etching and its dominant rate process are studied using hydrogen chloride gas in a wide concentration range of 1-100% in ambient hydrogen at atmospheric pressure in a temperature range of 1023-1423 K, linked with the numerical calculation accounting for the transport phenomena and the surface chemical reaction in the entire reactor. The etch rate, the gaseous products and the surface morphology are experimentally evaluated. The dominant rate equation accounting for the first-order successive reactions at silicon surface by hydrogen chloride gas is shown to be valid. The activation energy of the dominant surface process is evaluated to be 1.5 x 10 5 J mol - 1 . The silicon deposition by the gaseous by-product, trichlorosilane, is shown to have a negligible influence on the silicon etch rate

Integrating climate forecasts and natural gas supply information into a natural gas purchasing decision

Science.gov (United States)

Changnon, David; Ritsche, Michael; Elyea, Karen; Shelton, Steve; Schramm, Kevin

2000-09-01

This paper illustrates a key lesson related to most uses of long-range climate forecast information, namely that effective weather-related decision-making requires understanding and integration of weather information with other, often complex factors. Northern Illinois University's heating plant manager and staff meteorologist, along with a group of meteorology students, worked together to assess different types of available information that could be used in an autumn natural gas purchasing decision. Weather information assessed included the impact of ENSO events on winters in northern Illinois and the Climate Prediction Center's (CPC) long-range climate outlooks. Non-weather factors, such as the cost and available supplies of natural gas prior to the heating season, contribute to the complexity of the natural gas purchase decision. A decision tree was developed and it incorporated three parts: (a) natural gas supply levels, (b) the CPC long-lead climate outlooks for the region, and (c) an ENSO model developed for DeKalb. The results were used to decide in autumn whether to lock in a price or ride the market each winter. The decision tree was tested for the period 1995-99, and returned a cost-effective decision in three of the four winters.

Effect of bioleaching on hydrogen-rich gas production by steam gasification of sewage sludge

International Nuclear Information System (INIS)

Li, Hanhui; Chen, Zhihua; Huo, Chan; Hu, Mian; Guo, Dabin; Xiao, Bo

2015-01-01

Highlights: • Bioleaching can modify the physicochemical property of sewage sludge. • The enhancement is mainly hydrogen. • Bioleaching can enhance the gas production in gasification of sewage sludge. • Study provides an insight for future application of bioleached sewage sludge. - Abstract: Effect of bioleaching on hydrogen-rich gas production by steam gasification of sewage sludge was carried out in a lab-scale fixed-bed reactor. The influence of sewage sludge solids concentrations (6–14% (w/v) in 2% increments) during the bioleaching process and reactor temperature (600–900 °C in 100 °C increments) on gasification product yields and gas composition were studied. Characterization of samples showed that bioleaching treatment, especially in 6% (w/v) sludge solids concentration, led to metal removal effectively and modifications in the physicochemical property of sewage sludge which was favored for gasification. The maximum gas yield (49.4%) and hydrogen content (46.4%) were obtained at 6% (w/v) sludge solids concentration and reactor temperature of 900 °C. Sewage sludge after the bioleaching treatment may be a feasible feedstock for hydrogen-rich gas product.

Fuel hydrogen retention of tungsten and the reduction by inert gas glow discharges

Energy Technology Data Exchange (ETDEWEB)

Hino, T., E-mail: tomhino@qe.eng.hokudai.ac.jp [Laboratory of Plasma Physics and Engineering, Hokkaido University, Sapporo 060-8628 (Japan); Yamauchi, Y.; Kimura, Y. [Laboratory of Plasma Physics and Engineering, Hokkaido University, Sapporo 060-8628 (Japan); Nishimura, K. [National Institute for Fusion Science, Toki-shi, Gifu-ken 509-5292 (Japan); Ueda, Y. [Graduate School of Engineering, Osaka University, Suita-shi 565-0872 (Japan)

2012-08-15

Highlights: Black-Right-Pointing-Pointer The performances of inert gas glow discharges for reduction of fuel hydrogen retention in tungsten were systematically investigated. Black-Right-Pointing-Pointer For the tungsten with rough surface structure, the reduction of fuel hydrogen retention by inert gas discharges is quite small. Black-Right-Pointing-Pointer The deuterium glow discharge is quite useful to reduce the tritium retention in plasma facing walls in fusion reactor. Black-Right-Pointing-Pointer The wall baking with temperature higher than 700-800 K is also useful to reduce the tritium retention in plasma facing walls. - Abstract: Polycrystalline tungsten was exposed to deuterium glow discharge followed by He, Ne or Ar glow discharge. The amount of retained deuterium in the tungsten was measured using residual gas analysis. The amount of desorbed deuterium during the inert gas glow discharge was also measured. The amount of retained deuterium was 2-3 times larger compared with a case of stainless steel. The ratios of desorbed amount of deuterium by He, Ne and Ar glow discharges were 4.6, 3.1 and 2.9%, respectively. These values were one order of magnitude smaller compared with the case of stainless steel. The inert gas glow discharge is not suitable to reduce the fuel hydrogen retention for tungsten walls. However, the wall baking with a temperature higher than 700 K is suitable to reduce the fuel hydrogen retention. It is also shown that the use of deuterium glow discharge is effective to reduce the in-vessel tritium inventory in fusion reactors through the hydrogen isotope exchange.

Role of membranes and membrane reactors in the hydrogen supply of fuel cells for transports

Energy Technology Data Exchange (ETDEWEB)

Julbe, A.; Guizard, Ch. [Institut Europeen des Membranes, UMII, Lab. des Materiaux et des Procedes Membranaires, CNRS UMR 5635, 34 - Montpellier (France)

2000-07-01

Production, storage and supply of high-purity hydrogen as a clean and efficient fuel is central to fuel cells technology, in particular in vehicle traction. Actually, technologies for handling liquefied or gaseous hydrogen in transports are not available so that a number of alternative fuels are considered with the aim of in-situ generation of hydrogen through catalytic processes. The integrated concept of membrane reactors (MRs) can greatly benefit to these technologies. Particular emphasis is put on inorganic membranes and their role in MRs performance for H{sub 2} production.

Investigation on the production of hydrogen rich gas in a plasma converter for motorcycle applications

International Nuclear Information System (INIS)

Horng, R.-F.; Chang, Y.-P.; Wu, S.-C.

2006-01-01

A plasma fuel converter producing a hydrogen rich gas fuel has been designed and constructed. The methodology included using a high voltage electric arc generator to ionize the mixture of methane fuel and air, which was then reformed into a hydrogen rich gas. It transpired from the experiment that the higher the arc frequency, the higher was the generated hydrogen concentration, with a maximum concentration of 43 vol.% attained with an arc frequency of 200 Hz and an O/C (O 2 /CH 4 ) ratio of 0.10. The maximum hydrogen yield of 0.55 was obtained with an arc frequency of 200 Hz and an O/C ratio between 0.20 and 0.25. By fueling a four stroke motorcycle engine with the hydrogen rich gas, low emissions during the cold start idle condition can be obtained

Structure and development of the natural gas supply in Bavaria: chances and risks

International Nuclear Information System (INIS)

Bozem, K.

1994-01-01

Despite its structural handicap of being a large state, the gas supply in Bavaria has developed very favourabley. Strategies have been worked out for a successful future. What the gas economy needs above all are clear and reliable energy-political framework conditions. Experiments endangering the current security of supply must be dismissed. (orig.) [de

Development and industrial application of catalyzer for low-temperature hydrogenation hydrolysis of Claus tail gas

Directory of Open Access Journals (Sweden)

Honggang Chang

2015-10-01

Full Text Available With the implementation of more strict national environmental protection laws, energy conservation, emission reduction and clean production will present higher requirements for sulfur recovery tail gas processing techniques and catalyzers. As for Claus tail gas, conventional hydrogenation catalyzers are gradually being replaced by low-temperature hydrogenation catalyzers. This paper concentrates on the development of technologies for low-temperature hydrogenation hydrolysis catalyzers, preparation of such catalyzers and their industrial application. In view of the specific features of SO2 hydrogenation and organic sulfur hydrolysis during low-temperature hydrogenation, a new technical process involving joint application of hydrogenation catalyzers and hydrolysis catalyzers was proposed. In addition, low-temperature hydrogenation catalyzers and low-temperature hydrolysis catalyzers suitable for low-temperature conditions were developed. Joint application of these two kinds of catalyzers may reduce the inlet temperatures in the conventional hydrogenation reactors from 280 °C to 220 °C, at the same time, hydrogenation conversion rates of SO2 can be enhanced to over 99%. To further accelerate the hydrolysis rate of organic sulfur, the catalyzers for hydrolysis of low-temperature organic sulfur were developed. In lab tests, the volume ratio of the total sulfur content in tail gas can be as low as 131 × 10−6 when these two kinds of catalyzers were used in a proportion of 5:5 in volumes. Industrial application of these catalyzers was implemented in 17 sulfur recovery tail gas processing facilities of 15 companies. As a result, Sinopec Jinling Petrochemical Company had outstanding application performances with a tail gas discharging rate lower than 77.9 mg/m3 and a total sulfur recovery of 99.97%.

Nitrogen Gas Heating and Supply System for SST-1 Tokamak

International Nuclear Information System (INIS)

Khan, Ziauddin; Pathan, Firozkhan; Paravastu, Yuvakiran; George, Siju; Ramesh, Gattu; Bindu, Hima; Raval, Dilip C.; Thankey, Prashant; Dhanani, Kalpesh; Pradhan, Subrata

2013-01-01

Steady State Tokamak (SST-1) vacuum vessel baking as well as baking of the first wall components of SST-1 are essential to plasma physics experiments. Under a refurbishment spectrum of SST-1, the nitrogen gas heating and supply system has been fully refurbished. The SST-1 vacuum vessel consists of ultra-high vacuum (UHV) compatible eight modules and eight sectors. Rectangular baking channels are embedded on each of them. Similarly, the SST-1 plasma facing components (PFC) are comprised of modular graphite diverters and movable graphite based limiters. The nitrogen gas heating and supply system would bake the plasma facing components at 350°C and the SST-1 vacuum vessel at 150°C over an extended duration so as to remove water vapour and other absorbed gases. An efficient PLC based baking facility has been developed and implemented for monitoring and control purposes. This paper presents functional and operational aspects of a SST-1 nitrogen gas heating and supply system. Some of the experimental results obtained during the baking of SST-1 vacuum modules and sectors are also presented here. (fusion engineering)

Geochemical modelling of hydrogen gas migration in an unsaturated bentonite buffer

NARCIS (Netherlands)

Sedighi, M.; Thomas, H.R.; Al Masum, S.; Vardon, P.J.; Nicholson, D.; Chen, Q.

2014-01-01

This paper presents an investigation of the transport and fate of hydrogen gas through compacted bentonite buffer. Various geochemical reactions that may occur in the multiphase and multicomponent system of the unsaturated bentonite buffer are considered. A reactive gas transport model, developed

Experimental study on the natural gas dual fuel engine test and the higher the mixture ratio of hydrogen to natural gas

Energy Technology Data Exchange (ETDEWEB)

Kim, B.S.; Lee, Y.S.; Park, C.K. [Cheonnam University, Kwangju (Korea); Masahiro, S. [Kyoto University, Kyoto (Japan)

1999-05-28

One of the unsolved problems of the natural gas dual fuel engine is that there is too much exhaust of Total Hydrogen Carbon(THC) at a low equivalent mixture ratio. To fix it, a natural gas mixed with hydrogen was applied to engine test. The results showed that the higher the mixture ratio of hydrogen to natural gas, the higher the combustion efficiency. And when the amount of the intake air is reached to 90% of WOT, the combustion efficiency was promoted. But, like a case making the injection timing earlier, the equivalent mixture ratio for the nocking limit decreases and the produce of NOx increases. 5 refs., 9 figs., 1 tab.

Review of Design Data for Safety Assessment of Tokai Reprocessing Plant. Control of hydrogen gas produced by radiolysis of reprocessing solutions at Tokai Reprocessing Plant

International Nuclear Information System (INIS)

Omori, E.; Surugaya, N.; Takaya, A.; Nakamura, H.; Maki, A.; Yamanouchi, T.

1999-10-01

Radioactive materials in aqueous solution at a nuclear fuel reprocessing plant causes radiolytic generation of several gases including hydrogen. Hydrogen accumulating in equipment can be an explosion hazard. In such plants, though the consideration in the design has been fundamentally made in order to remove the ignition source from the equipment, the hydrogen concentration in the equipment should not exceed the explosion threshold. It is, therefore, desired to keep the hydrogen concentration lower than the explosion threshold by dilution with the air introduced into equipment, from the viewpoint which previously prevents the explosion. This report describes the calculation of hydrogen generation, evaluation of hydrogen concentration under abnormal operation and consideration of possible improvement at Tokai Reprocessing Plant. The amount of hydrogen generation was calculated for each equipment from available data on radiolysis induced by radioactive materials. Taking into consideration for abnormal condition that is single failure of air supply and loss of power supply, the investigation was made on the method for controlling so that the hydrogen concentration may not exceed the explosion threshold. Possible means which can control the concentration of hydrogen gas under the explosion threshold have been also investigated. As the result, it was found that hydrogen concentration of most equipment was kept under the explosion threshold. It was also shown that improvement of the facility was necessary on the equipment in which the concentration of the hydrogen may exceed the explosion threshold. Proposals based on the above results are also given in this report. The above content has been described in 'Examination of the hydrogen produced by the radiolysis' which is a part of 'Reviews of Design Data for Safety Assessment of Tokai Reprocessing Plant' (JNC TN8410 99-002) published in February 1999. This report incorporates the detail evaluation so that operation

Well-to-wheel analysis of renewable transport fuels: synthetic natural gas from wood gasification and hydrogen from concentrated solar energy[Dissertation 17437

Energy Technology Data Exchange (ETDEWEB)

Felder, R.

2007-07-01

In order to deal with problems such as climate change, an increasing energy demand and the finiteness of fossil resources, alternative CO{sub 2}-low technologies have to be found for a sustainable growing future. Laboratories at PSI are conducting research on two pathways delivering such car fuels: synthetic natural gas from wood gasification (SNG) and hydrogen from solar thermochemical ZnO dissociation (STD). The biofuel SNG is produced using wood in an auto-thermal gasification reactor. It can be supplied to the natural-gas grid and be used in a compressed natural gas (CNG) vehicle. STD is a long-term option, using concentrated solar radiation in a thermochemical reactor, producing zinc as solar energy carrier. Zinc can be used for hydrolysis, in order to produce hydrogen as a locally low-polluting future car fuel. In the frame of the thesis, both fuels are assessed using a life cycle assessment, i.e. investigating all environmental interactions from the extraction of resources over the processing and usage steps to the final disposal. Different methodologies are applied for a rating, compared to alternatives and standard fuels of today. In addition, costs of the technologies are calculated in order to assess economic competitiveness. The thesis is structured as follows: After an introduction giving an overview (chapter A), the methodology is presented (chapter B). It includes various life cycle impact assessment methods such as greenhouse gas emissions, the cumulative energy demand or comprehensive rating approaches. Calculations of the production and supply costs of the assessed fuels are included as well as the eco-efficiency, a combination of environmental with economic indicators. In addition, external costs caused by the emissions are quantified. Sensitivity studies investigate the importance of different parameters and substantiate conclusions. In chapter C, the production, supply and use of the assessed fuels is discussed, following the well

Measurement of percent hydrogen in the mechanical vacuum pump gas stream during BWR startup

International Nuclear Information System (INIS)

Garcia, Susan E.; Odell, Andrew D.; Giannelli, Joseph F.

2012-09-01

All U.S BWRs use a Mechanical Vacuum Pump (MVP) to establish condenser vacuum during start-ups, normally from the initial heat-up to the point where sufficient reactor steam pressure and flow is available to place the Steam Jet Air Ejector (SJAE) and off-gas treatment system in service. MVP operation is restricted to <5% power and gas stream concentrations of <4% H 2 , the lower flammability limit (LFL) for hydrogen/air mixtures. For a particular plant startup prior to hydrogen injection for hydrogen water chemistry (HWC), the MVP %H 2 would depend on the air in-leakage rate, the H 2 gas generation rate from radiolysis and the gas/steam transport rate from the reactor vessel to the main condenser. The radiolysis rate at low power, which is not precisely known and has not been modeled for the BWR, is normally assumed to increase in proportion to thermal power. Two thirds of the radiolytic gas by volume would be H 2 and one third O 2 . The MVP is not equipped with %H 2 sampling and measurement capability, and many MVP systems include no flow measurement. No U.S plant or literature data on MVP %H 2 were found. The industry-first Early Hydrogen Water Chemistry (EHWC) demonstration at the Peach Bottom 3 nuclear power plant involved hydrogen gas injection into the reactor vessel during startup while the MVP was in service. To support the EHWC project, it was necessary to collect baseline MVP %H 2 data during a startup without hydrogen injection and to monitor MVP %H 2 during the startup with EHWC. The MVP system had no normal sample point, but included test taps in the suction and discharge piping. A sampling method and apparatus was invented (EPRI patent pending), designed, built and applied to obtain %H 2 measurements in the MVP gas stream. The apparatus allowed a gas sample stream to be taken from either the suction (vacuum) or discharge side of the MVP. The gas sample stream was preconditioned to remove moisture (the MVP uses water as a liquid compressant), flowed to

Improvements in gas supply systems for heavy-water moderated reactors

International Nuclear Information System (INIS)

Aubert, G.; Hassig, J.M.; Laurent, N.; Thomas, B.

1964-01-01

In a heavy-water moderated reactor cooled by pressurized gas, an important problem from the point of view, of the reactor block and its economics is the choice of the gas supply system. In the pressure tube solution, the whole of the reactor block structure is at a relatively low temperature, whereas the gas supply equipment is at that of the gas, which is much higher. These parts, through which passes the heat carrying fluid have to present as low a resistance as possible to it so as to avoid costly extra blowing power. Finally, they may only be placed in the reactor block after it has been built; the time required for putting them in position should therefore not be too long. The work reported here concerns the various problems arising in the case of each channel being supplied individually by a tube at the entry and the exit which is connected to a main circuit made up of large size collectors. This individual tubing is sufficiently flexible to absorb the differential expansion and the movement of its ends without stresses or prohibitive reactions being produced; the tubing is also of relatively short length so as to reduce the pressure head of the pressurized gas outside the channels; the small amount of space taken up by the tubing makes it possible to assemble it in a manner which is satisfactory from the point of view both of the time required and of the technical quality. (authors) [fr

Studies on the separation of hydrogen isotopes and spin isomers by gas chromatography

International Nuclear Information System (INIS)

Pushpa, K.K.; Annaji Rao, K.

2000-08-01

Separation and analysis of mixture of hydrogen isotopes has gained considerable importance because of various applications needing different isotopes in lasers, nuclear reactions and tracer or labelled compounds. In the literature gas chromatographic methods are reported using columns packed with partly dehydrated or thoroughly dehydrated alumina/molecular sieve stationary phase at 77 deg K with helium, neon and even hydrogen or deuterium as carrier gas. In the present study an attempt is made to compare the chromatographic behaviour of these two stationary phases using virgin and Fe doped form in partly dehydrated and thoroughly dehydrated state, using helium, neon, hydrogen and deuterium as carrier gas. The results of this study show that helium or neon carrier gas behave similarly broad peaks with some tailing. Sharp symmetric peaks are obtained with hydrogen or deuterium carrier gas. This is attributed to large hold up capacity for H 2 or D 2 at 77 deg K in these materials as compared to helium or neon. Spin isomers of H 2 or D 2 are separated on Fe free stationary phases, though ortho H 2 and HD are not resolved. Using a combination of Fe doped short column and plain alumina column, both maintained in dehydrated form, the effect of Fe doping on thermal equilibrium of ortho/para forms at 77 deg K is clearly demonstrated. (author)

Hydrogen Gas from Serpentinite, Ophiolites and the Modern Ocean Floor as a Source of Green Energy

Science.gov (United States)

Coveney, R. M.

2008-12-01

Hydrogen gas is emitted by springs associated with serpentinites and extensive carbonate deposits in Oman, The Philippines, the USA and other continental locations. The hydrogen springs contain unusually alkaline fluids with pH values between 11 and 12.5. Other workers have described off-ridge submarine springs with comparably alkaline fluid compositions, serpentinite, abundant free hydrogen gas, and associated carbonate edifices such as Lost City on the Atlantis Massif 15 km west of the Mid-Atlantic Ridge (D.S. Kelley and associates, Science 2005). The association of hydrogen gas with ultramafites is a consistent one that has been attributed to a redox couple involving oxidation of divalent iron to the trivalent state during serpentinization, although other possibilities exist. Some of the hydrogen springs on land are widespread. For example in Oman dozens of alkaline springs (Neal and Stanger, EPSL 1983) can be found over thousands of sq km of outcropping ophiolite. While the deposits in Oman and the Philippines are well-known to much of the geochemical community, little interest seems to have been displayed toward either the ophiolitic occurrences or the submarine deposits for energy production. This may be a mistake as the showings because they could lead to an important source of green energy. Widespread skepticism currently exists about hydrogen as a primary energy source. It is commonly said that free hydrogen does not occur on earth and that it is therefore necessary to use other sources of energy to produce hydrogen, obviating the general environmental benefit. However the existence of numerous occurrences of hydrogen gas associated with ophiolites and submarine occurrences of hydrogen suggests the likelihood that natural hydrogen gas may be an important source of clean energy for modern society remaining to be tapped. Calculations in progress should establish whether or not this is likely to be the case.

Advanced IGCC/Hydrogen Gas Turbine Development

Energy Technology Data Exchange (ETDEWEB)

York, William [General Electric Company, Schenectady, NY (United States); Hughes, Michael [General Electric Company, Schenectady, NY (United States); Berry, Jonathan [General Electric Company, Schenectady, NY (United States); Russell, Tamara [General Electric Company, Schenectady, NY (United States); Lau, Y. C. [General Electric Company, Schenectady, NY (United States); Liu, Shan [General Electric Company, Schenectady, NY (United States); Arnett, Michael [General Electric Company, Schenectady, NY (United States); Peck, Arthur [General Electric Company, Schenectady, NY (United States); Tralshawala, Nilesh [General Electric Company, Schenectady, NY (United States); Weber, Joseph [General Electric Company, Schenectady, NY (United States); Benjamin, Marc [General Electric Company, Schenectady, NY (United States); Iduate, Michelle [General Electric Company, Schenectady, NY (United States); Kittleson, Jacob [General Electric Company, Schenectady, NY (United States); Garcia-Crespo, Andres [General Electric Company, Schenectady, NY (United States); Delvaux, John [General Electric Company, Schenectady, NY (United States); Casanova, Fernando [General Electric Company, Schenectady, NY (United States); Lacy, Ben [General Electric Company, Schenectady, NY (United States); Brzek, Brian [General Electric Company, Schenectady, NY (United States); Wolfe, Chris [General Electric Company, Schenectady, NY (United States); Palafox, Pepe [General Electric Company, Schenectady, NY (United States); Ding, Ben [General Electric Company, Schenectady, NY (United States); Badding, Bruce [General Electric Company, Schenectady, NY (United States); McDuffie, Dwayne [General Electric Company, Schenectady, NY (United States); Zemsky, Christine [General Electric Company, Schenectady, NY (United States)

2015-07-30

The objective of this program was to develop the technologies required for a fuel flexible (coal derived hydrogen or syngas) gas turbine for IGCC that met DOE turbine performance goals. The overall DOE Advanced Power System goal was to conduct the research and development (R&D) necessary to produce coal-based IGCC power systems with high efficiency, near-zero emissions, and competitive capital cost. To meet this goal, the DOE Fossil Energy Turbine Program had as an interim objective of 2 to 3 percentage points improvement in combined cycle (CC) efficiency. The final goal is 3 to 5 percentage points improvement in CC efficiency above the state of the art for CC turbines in IGCC applications at the time the program started. The efficiency goals were for NOx emissions of less than 2 ppm NOx (@15 % O2). As a result of the technologies developed under this program, the DOE goals were exceeded with a projected 8 point efficiency improvement. In addition, a new combustion technology was conceived of and developed to overcome the challenges of burning hydrogen and achieving the DOE’s NOx goal. This report also covers the developments under the ARRA-funded portion of the program that include gas turbine technology advancements for improvement in the efficiency, emissions, and cost performance of gas turbines for industrial applications with carbon capture and sequestration. Example applications could be cement plants, chemical plants, refineries, steel and aluminum plants, manufacturing facilities, etc. The DOE’s goal for more than 5 percentage point improvement in efficiency was met with cycle analyses performed for representative IGCC Steel Mill and IGCC Refinery applications. Technologies were developed in this program under the following areas: combustion, larger latter stage buckets, CMC and EBC, advanced materials and coatings, advanced configurations to reduce cooling, sealing and rotor purge flows, turbine aerodynamics, advanced sensors, advancements in first

Long term natural gas supply in North America: prospects for mexican exports

International Nuclear Information System (INIS)

Elizalde Baltierra, A.

1999-01-01

The aim of this work is to discuss the most important factors and uncertainties likely to affect future Mexican natural gas exports to the United States. Firstly, we study the long term natural gas supply/demand balance in North America over the period from 2000 to 2020. Secondly, we analyze the main driving forces determining future natural gas supply and demand in Mexico, which also allows us to discuss the prospects for Mexican gas exports. Finally, our analysis suggests that: in the short and medium term (2000-2010), Mexico will probably continue to increase imports of USA gas in order to satisfy increasing demand and will probably not export large volumes of gas to the USA; in the long term (2020-2020), Mexico could resume exports to the USA in sizeable quantities. Two main conditions appear necessary to resume exports: Premex's budgetary constraints should be relaxed and/or new foreign investment should be able to participate in the Mexican upstream oil and gas sector. (author)

Conversion of Claus plants of Kirkuk-Iraq to produce hydrogen and sulfur

International Nuclear Information System (INIS)

Naman, S.A.; Veziroglu, A.

2009-01-01

'Full text': Hydrogen production from rich sub-quality natural gas (SQNG) is visible technically with assessment of cost, safety and environmental toxicology analysis of hydrogen sulfide, is summarized. There are two Claus plants in Kirkuk-Iraq, converting hydrogen sulfide to elemental sulfur capacity of 2200 ton/day. One of these plants is working with only 400 ton/day and it is an old Claus process. The other is a modified Claus sulfur recovery process with a capacity of 1800 ton/day. Both of these plants operate with low efficiency due to lack of maintenance and the present situation in Iraq. Therefore, the agricultural area around Kirkuk is very polluted by this gas. Two pilot plants have been constructed inside the modified Claus plant in Kirkuk The first one is based on the flow system tube furnace reactor containing mixed Titanium oxide/sulfide with a cold trap for sulfur separation and a bath of 30% dithanolamine to separate and recycle H 2 S from hydrogen. The second pilot plant consists of a thermal diffusion ceramic rod inside a silica column containing Zeolit 5A as a catalyst. This pilot plant also consists of a trap for continuous separation of sulfur and a system for separation of hydrogen from unreacted H 2 S to recycle. The efficiency of conversion of H 2 S to hydrogen and sulfur has been optimized as a function of catalyst type and mixture, temperature of furnace, flow rate of gas and reactor materials until the efficiency reaches more than 97%. The Kirkuk natural gas consists of a mixture of CO 2 10% and H 2 S 12%. We found that these pilot plants were suitable with Cadmium chalcogens catalysts to produce hydrogen, methane, ethane and sulphur, but with lower efficiency than H 2 S decomposition only. Our aim in the second pilot plant, which consists of a silica column, was to supply the heat by solar energy concentrator instead of electricity as our catalyst needs 450 o C. and the solar intensity is about 1000 w/m 2 during the summer. The idea of

Supply prospects and network integration in the European natural gas sector

International Nuclear Information System (INIS)

Bergmann, B.

1998-01-01

At least for the next 10-15 years, natural gas will be the fastest growing energy form in Europe, with a higher rate of growth in consumption (from a lower base) in central Europe than in western Europe. Although most of the prospective demand until 2010 is covered by signed import contracts and indigenous production, important additional gas supply capacity still has to be developed out of a plenitude of reserves within and (in the long run primarily) outside western and central Europe. The real problem is how to mobilise the reserves economically and direct them towards the European market, in competition with other markets. Europe has a sophisticated transmission system whose development has gone hand-in-hand with long-term import agreements. Among the missing links is the Interconnector, which, at the end of 1998, is due to integrate the UK and Ireland into mainland Europe. This is expected to enhance security of supply in both areas, to balance prices and maybe also to foster ideas of liberalisation. Overall, the European gas industry is in an excellent position to develop the supply of gas in an environmentally benign way. The future belongs all the more to natural gas, the fewer the mistakes that are made when it comes to matters of legal frameworks and taxation

Reduction of greenhouse gas emission on a medium-pressure boiler using hydrogen-rich fuel control

International Nuclear Information System (INIS)

Hsieh, S.-C.; Jou, Chih-Ju G.

2007-01-01

The increasing emission of greenhouse gases from the combustion of fossil fuel is believed to be responsible for global warming. A study was carried out to probe the influence of replacing fuel gas with hydrogen-rich refinery gas (R.G.) on the reduction of gas emission (CO 2 and NO x ) and energy saving. Test results show that the emission of CO 2 can be reduced by 16.4% annually (or 21,500 tons per year). The NO x emission can be 8.2% lower, or 75 tons less per year. Furthermore, the use of refinery gas leads to a saving of NT$57 million (approximately US$1.73 million) on fuel costs each year. There are no CO 2 , CO, SO x , unburned hydrocarbon, or particles generated from the combustion of added hydrogen. The hydrogen content in R.G. employed in this study was between 50 and 80 mol%, so the C/H ratio of the feeding fuel was reduced. Therefore, the use of hydrogen-rich fuel has practical benefits for both energy saving and the reduction of greenhouse gas emission

Hydrogen gettering the overpressure gas from highly radioactive liquids

International Nuclear Information System (INIS)

Riley, D.L.; Schicker, J.R.

1996-04-01

Remediation of current inventories of high-activity radioactive liquid waste (HALW) requires transportation of Type-B quantities of radioactive material, possibly up to several hundred liters. However, the only currently certified packaging is limited to quantities of 50 ml (0.01 gal) quantities of Type-B radioactive liquid. Efforts are under way to recertify the existing packaging to allow the shipment of up to 4 L (1.1 gal) of Type-B quantities of HALW, but significantly larger packaging could be needed in the future. Scoping studies and preliminary designs have identified the feasibility of retrofitting an insert into existing casks, allowing the transport of up to 380 L (100 gal) of HALW. However, the insert design and ultimate certification strategy depend heavily on the gas-generating attributes of the HALW. A non-vented containment vessel filled with HALW, in the absence of any gas-mitigation technologies, poses a deflagration threat and, therefore, gas generation, specifically hydrogen generation, must be reliably controlled during all phases of transportation. Two techniques are available to mitigate hydrogen accumulation: recombiners and getters. Getters have an advantage over recombiners in that oxides are not required to react with the hydrogen. A test plan was developed to evaluate three forms of getter material in the presence of both simulated HALW and the gases that are produced by the HALW. These tests demonstrated that getters can react with hydrogen in the presence of simulated waste and in the presence of several other gases generated by the HALW, such as nitrogen, ammonia, nitrous oxide, and carbon monoxide. Although the use of such a gettering system has been shown to be technically feasible, only a preliminary design for its use has been completed. No further development is planned until the requirement for bulk transport of Type-B quantities of HALW is more thoroughly defined

H2@Scale: Technical and Economic Potential of Hydrogen as an Energy Intermediate

Energy Technology Data Exchange (ETDEWEB)

Ruth, Mark F [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Jadun, Paige [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Pivovar, Bryan S [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

2017-11-09

The H2@Scale concept is focused on developing hydrogen as an energy carrier and using hydrogen's properties to improve the national energy system. Specifically hydrogen has the abilities to (1) supply a clean energy source for industry and transportation and (2) increase the profitability of variable renewable electricity generators such as wind turbines and solar photovoltaic (PV) farms by providing value for otherwise potentially-curtailed electricity. Thus the concept also has the potential to reduce oil dependency by providing a low-carbon fuel for fuel cell electric vehicles (FCEVs), reduce emissions of carbon dioxide and pollutants such as NOx, and support domestic energy production, manufacturing, and U.S. economic competitiveness. The analysis reported here focuses on the potential market size and value proposition for the H2@Scale concept. It involves three analysis phases: 1. Initial phase estimating the technical potential for hydrogen markets and the resources required to meet them; 2. National-scale analysis of the economic potential for hydrogen and the interactions between willingness to pay by hydrogen users and the cost to produce hydrogen from various sources; and 3. In-depth analysis of spatial and economic issues impacting hydrogen production and utilization and the markets. Preliminary analysis of the technical potential indicates that the technical potential for hydrogen use is approximately 60 million metric tons (MMT) annually for light duty FCEVs, heavy duty vehicles, ammonia production, oil refining, biofuel hydrotreating, metals refining, and injection into the natural gas system. The technical potential of utility-scale PV and wind generation independently are much greater than that necessary to produce 60 MMT / year hydrogen. Uranium, natural gas, and coal reserves are each sufficient to produce 60 MMT / year hydrogen in addition to their current uses for decades to centuries. National estimates of the economic potential of

Evaluation of Technical Feasibility of Homogeneous Charge Compression Ignition (HCCI) Engine Fueled with Hydrogen, Natural Gas, and DME

Energy Technology Data Exchange (ETDEWEB)

John Pratapas; Daniel Mather; Anton Kozlovsky

2007-03-31

The objective of the proposed project was to confirm the feasibility of using blends of hydrogen and natural gas to improve the performance, efficiency, controllability and emissions of a homogeneous charge compression ignition (HCCI) engine. The project team utilized both engine simulation and laboratory testing to evaluate and optimize how blends of hydrogen and natural gas fuel might improve control of HCCI combustion. GTI utilized a state-of-the art single-cylinder engine test platform for the experimental work in the project. The testing was designed to evaluate the feasibility of extending the limits of HCCI engine performance (i.e., stable combustion, high efficiency and low emissions) on natural gas by using blends of natural gas and hydrogen. Early in the project Ricardo provided technical support to GTI as we applied their engine performance simulation program, WAVE, to our HCCI research engine. Modeling support was later provided by Digital Engines, LLC to use their proprietary model to predict peak pressures and temperatures for varying operating parameters included in the Design of Experiments test plan. Digital Engines also provided testing support for the hydrogen and natural gas blends. Prof. David Foster of University of Wisconsin-Madison participated early in the project by providing technical guidance on HCCI engine test plans and modeling requirements. The main purpose of the testing was to quantify the effects of hydrogen addition to natural gas HCCI. Directly comparing straight natural gas with the hydrogen enhanced test points is difficult due to the complexity of HCCI combustion. With the same air flow rate and lambda, the hydrogen enriched fuel mass flow rate is lower than the straight natural gas mass flow rate. However, the energy flow rate is higher for the hydrogen enriched fuel due to hydrogen's significantly greater lower heating value, 120 mJ/kg for hydrogen compared to 45 mJ/kg for natural gas. With these caveats in mind, an

Long term Gas Supply Security in an Enlarged Europe. Final Report ENGAGED Project

International Nuclear Information System (INIS)

Van Oostvoorn, F.; Likachev, V.; Morgan, T.

2004-12-01

The title project concerned a study on the long-term gas supply security in Europe with a focus on the developments, risks and policies in the candidate countries in Eastern Europe. For that reason the report not only includes a European and EU-30 wide scenario analysis but also chapters on specific topics. One study (a chapter in this report) concerns the gas market and regulation developments in a number of relevant candidate countries. Another chapter presents a Russian vision on gas demand, production and supplies from Russia and also includes a paragraph on the supplies from other neighbours and the transit issues in the Ukraine. Finally, the report contains a chapter discussing the required network infrastructure for bringing the gas from external gas suppliers to the EU-30 markets. Hereby it analysis and tests the network flexibility to cope with some unlikely and unexpected supply interruptions in main pipelines to EU markets. The background information of the studies underlying the chapters can be partly found in the annexes and in the individual task reports. During the project the results of the study were discussed at several seminars in candidate countries and particularly on the final seminar in Prague, in June 2003, with different and important stakeholders and market actors

EUV tools: hydrogen gas purification and recovery strategies

Science.gov (United States)

Landoni, Cristian; Succi, Marco; Applegarth, Chuck; Riddle Vogt, Sarah

2015-03-01

The technological challenges that have been overcome to make extreme ultraviolet lithography (EUV) a reality have been enormous1. This vacuum driven technology poses significant purity challenges for the gases employed for purging and cleaning the scanner EUV chamber and source. Hydrogen, nitrogen, argon and ultra-high purity compressed dry air (UHPCDA) are the most common gases utilized at the scanner and source level. Purity requirements are tighter than for previous technology node tools. In addition, specifically for hydrogen, EUV tool users are facing not only gas purity challenges but also the need for safe disposal of the hydrogen at the tool outlet. Recovery, reuse or recycling strategies could mitigate the disposal process and reduce the overall tool cost of operation. This paper will review the types of purification technologies that are currently available to generate high purity hydrogen suitable for EUV applications. Advantages and disadvantages of each purification technology will be presented. Guidelines on how to select the most appropriate technology for each application and experimental conditions will be presented. A discussion of the most common approaches utilized at the facility level to operate EUV tools along with possible hydrogen recovery strategies will also be reported.

Proposal for a Northeast Asian Hydrogen Highway: From a Natural-gas-based to a Hydrogen-based Society

International Nuclear Information System (INIS)

Kazuhiko O Hashi; Masaru Hirata; William C Leighty; D Eng

2006-01-01

In Northeast Asia, East Siberia and Sakhalin are rich in natural gas (NG). The environmental protection and energy security of the Northeast Asian region requires constructing an energy infrastructure network that can transport and distribute NG throughout the region in the near term, and renewable-source gaseous hydrogen (GH2) in the long term. We have promoted the construction of an NG pipeline network, the principal component of the energy infrastructure essential to our evolution toward a hydrogen-based society, through the Northeast Asia Natural Gas and Pipeline Forum (NAGPF). Our ultimate goal is a clean and sustainable society based on renewable energy sources, wherein hydrogen is produced from the vast potential of renewable energy in Siberia and China. The hydrogen thus produced would be transmitted through the pipeline network, progressively replacing NG as it is depleted. Over three-quarters of commercially exploitable hydroelectric power (hydro) resources of all Russia is in East Siberia. The areas from Kamchatka through the Kurilskiye Islands (called the Chishima Islands, in Japan) to Sakhalin is a world-class wind energy resource. West China has huge potential for solar energy. (authors)

A fatigue initiation parameter for gas pipe steel submitted to hydrogen absorption

Energy Technology Data Exchange (ETDEWEB)

Capelle, J; Gilgert, J; Pluvinage, G [LaBPS - Ecole Nationale d' Ingenieurs de Metz et Universite Paul Verlaine Metz, Ile du Saulcy, 57045 Metz (France)

2010-01-15

Fatigue initiation resistance has been determined on API 5L X52 gas pipe steel. Tests have been performed on Roman Tile (RT) specimen and fatigue initiation was detected by acoustic emission. A comparison between specimens electrolytically charged with hydrogen and specimens without hydrogen absorption were made and it has been noted that fatigue initiation time is reduced of about 3 times when hydrogen embrittlement occurs. It has been proposed to use the concept of Notch Stress Intensity Factor as parameter to describe the fatigue initiation process. Due to the fact that hydrogen is localised in area with high hydrostatic pressure, definitions of local effective stress and distance have been modified when hydrogen is absorbed. This modification can be explained by existence of a ductile-brittle transition with hydrogen concentration. The fatigue initiation resistance curve allows that to determine a threshold for large number of cycles of fatigue non initiation. This parameter introduced in a Failure Assessment Diagram (FAD) provides supplementary information about defect nocivity in gas pipes: a non-critical defect can be detected as dormant or not dormant defect i.e., as non propagating defect. (author)

Informing hazardous zones for on-board maritime hydrogen liquid and gas systems

Energy Technology Data Exchange (ETDEWEB)

Blaylock, Myra L. [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Pratt, Joseph William [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Bran Anleu, Gabriela A. [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Proctor, Camron [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

2018-01-01

The significantly higher buoyancy of hydrogen compared to natural gas means that hazardous zones defined in the IGF code may be inaccurate if applied to hydrogen. This could place undue burden on ship design or could lead to situations that are unknowingly unsafe. We present dispersion analyses to examine three vessel case studies: (1) abnormal external vents of full blowdown of a liquid hydrogen tank due to a failed relief device in still air and with crosswind; (2) vents due to naturally-occurring boil-off of liquid within the tank; and (3) a leak from the pipes leading into the fuel cell room. The size of the hydrogen plumes resulting from a blowdown of the tank depend greatly on the wind conditions. It was also found that for normal operations releasing a small amount of "boil- off" gas to regulate the pressure in the tank does not create flammable concentrations.

Natural gas industry optimistic for U.S. and Canadian supply

International Nuclear Information System (INIS)

Anon.

2000-01-01

According to a survey conducted by the Ziff Energy Group, industry insiders are optimistic about natural gas supply and demand during 2000. The survey, which was designed to provide an integrated description of the North American gas industry from wellhead to burner tip, covered 124 companies across North America. Slightly more than half of the U.S. respondents expect to produce at least five per cent more natural gas in 2000 than the previous year, while 19 per cent of the respondents expect production increases to exceed 15 per cent. Among Canadian respondents, some 70 per cent expect production to increase five per cent; another 25 per cent anticipate increases in production to reach or exceed 15 per cent. Canadian natural gas export to the United States are expected to grow by up to 700 million cubic feet per day by almost 50 per cent of Canadian respondents; one third of the respondents expect exports to increase by 700 to 900 million cubic feet per day. Growth in U.S. demand for natural gas are predicted to be moderate in 2000, and increase somewhat in 2001. Canadian growth in sales is expected to be in the one-to-two per cent range. Few of the respondents expect gas prices to decline, and few are concerned that gas prices may put sales at risk. The majority of respondents believe that gas supply growth poses the greatest challenge to increasing pipeline capacity

The growth of GaN films by alternate source gas supply hot-mesh CVD method

Energy Technology Data Exchange (ETDEWEB)

Komae, Yasuaki; Saitou, Takeshi [Nagaoka University of Technology, Nagaoka 940-2188 (Japan); Suemitsu, Maki; Ito, Takashi [Center of Interdisciplinary Research, Tohoku University, Sendai 980-8578 (Japan); Endoh, Tetsuo [Research Institute of Electrical Communication, Tohoku University, Sendai 980-8577 (Japan); Nakazawa, Hideki [Faculty of Science and Technology, Hirosaki University, Hirosaki 036-8561 (Japan); Narita, Yuzuru [Faculty of Engineering, Yamagata University, Yonezawa 992-8510 (Japan); Takata, Masasuke; Akahane, Tadashi [Nagaoka University of Technology, Nagaoka 940-2188 (Japan); Yasui, Kanji, E-mail: kyasui@vos.nagaokaut.ac.j [Nagaoka University of Technology, Nagaoka 940-2188 (Japan)

2009-04-30

Gallium nitride (GaN) films and Aluminium nitride (AlN) layers were deposited on SiC/Si (111) substrates by an alternating source gas supply or an intermittent supply of a source gas such as ammonia (NH{sub 3}), trimethylgallium (TMG) or trimethylaluminum (TMA) in a hot-mesh chemical vapor deposition (CVD) apparatus. The AlN layer was deposited as a buffer layer using NH{sub 3} and TMA on a SiC layer grown by carbonization on Si substrates using propane (C{sub 3}H{sub 8}). GaN films were grown on an AlN layer by a reaction between NH{sub x} radicals generated on a ruthenium (Ru) coated tungsten (W)-mesh and TMG molecules. An alternating source gas supply or an intermittent supply of one of the source gases during the film growth are expected to be effective for the suppression of gas phase reactions and for the enhancement of precursor migration on the substrate surface. By the intermittent supply of alkylmetal gas only during the growth of the AlN layer, the defect generation in the GaN films was reduced. GaN film growth by intermittent supply on an AlN buffer layer, however, did not lead to the improvement of the film quality.

Radioactive gas and hydrogen removal after a LOCE at the LOFT Facility

International Nuclear Information System (INIS)

McCormick-Barger, J.W.; Sumpter, K.C.

1979-01-01

The use of a silver-zeolite halogen adsorber placed in series with a hydrogen catalytic recombiner and a cryogenic noble gas adsorber assembly constitutes a waste gas processing system (WGPS) capable of handling hydrogen and fission product gases following a Loss-of-Coolant Experiment (LOCE). This paper describes: the types and quantities of gases expected to be found at the facility after a failed-fuel LOCE; the purpose of the WGPS; and the general configuration and expected decontamination factors associated with the LOFT WGPS

Electric power supply: the viability of natural gas cogeneration

International Nuclear Information System (INIS)

Paula, C.P. de; Ennes, S.A.W.

1991-01-01

The technical and economical aspects of Natural Gas conversion into electricity through cogeneration, analysing the potentials and costs of the power systems connections to downstream processes is related. The insertion impacts of these cogeneration potentials into the Electrical Network are also analysed, with special emphasis on the supply deficit risk reduction. The generation conditions for both auto-sufficiency and exceeding supply to network are determined, regarding the purposes of attendance efficiency improvement and the necessary new service stimulus. (author)

Performance of a hydrogen/deuterium polarized gas target in a storage ring

NARCIS (Netherlands)

van Buuren, L.D.; Szczerba, D.; van den Brand, J.F.J.; Bulten, H.J.; Klous, S.; Mul, F.A.; Poolman, H.R.; Simani, M.C.

2001-01-01

The performance of a hydrogen/deuterium polarized gas target in a storage ring is presented. The target setup consisted of an atomic beam source, a cryogenic storage cell and a Breit-Rabi polarimeter. High frequency transition units were constructed to produce vector polarized hydrogen and

Performance Improvement of V-Fe-Cr-Ti Solid State Hydrogen Storage Materials in Impure Hydrogen Gas.

Science.gov (United States)

Ulmer, Ulrich; Oertel, Daria; Diemant, Thomas; Bonatto Minella, Christian; Bergfeldt, Thomas; Dittmeyer, Roland; Behm, R Jürgen; Fichtner, Maximilian

2018-01-17

Two approaches of engineering surface structures of V-Ti-based solid solution hydrogen storage alloys are presented, which enable improved tolerance toward gaseous oxygen (O 2 ) impurities in hydrogen (H 2 ) gas. Surface modification is achieved through engineering lanthanum (La)- or nickel (Ni)-rich surface layers with enhanced cyclic stability in an H 2 /O 2 mixture. The formation of a Ni-rich surface layer does not improve the cycling stability in H 2 /O 2 mixtures. Mischmetal (Mm, a mixture of La and Ce) agglomerates are observed within the bulk and surface of the alloy when small amounts of this material are added during arc melting synthesis. These agglomerates provide hydrogen-transparent diffusion pathways into the bulk of the V-Ti-Cr-Fe hydrogen storage alloy when the remaining oxidized surface is already nontransparent for hydrogen. Thus, the cycling stability of the alloy is improved in an O 2 -containing hydrogen environment as compared to the same alloy without addition of Mm. The obtained surface-engineered storage material still absorbs hydrogen after 20 cycles in a hydrogen-oxygen mixture, while the original material is already deactivated after 4 cycles.

Computer simulation for risk management: Hydrogen refueling stations and water supply of a large region

DEFF Research Database (Denmark)

Markert, Frank; Kozine, Igor

2012-01-01

in applying DES models to the analysis of large infrastructures for refueling stations and water supply. Two case studies are described which are concerned with the inherently safer supply and storage of hydrogen at refueling stations and an established drinking water supply system of a large metropolitan...... area, respectively. For both, the simulation aims at identifying points of potential improvement from the reliability point of view. This allows setting up a list of activities and safety measures to reduce risk and possible losses and mitigate the consequences of accidents. Based on the cases...

Utilization of hydrogen gas production for electricity generation in ...

African Journals Online (AJOL)

Utilization of hydrogen gas production for electricity generation in fuel cell by Enterobacter aerogenes ADH 43 with many kinds of carbon sources in batch stirred tank reactor. MA Rachman, LD Eniya, Y Liasari, MM Nasef, A Ahmad, H Saidi ...

Conference Proceedings: The Quest for gas: tapping additional supplies for a growing market

International Nuclear Information System (INIS)

2000-01-01

The two-day conference attracted 375 attendees from 19 U.S. states, 10 Canadian provinces and territories and several delegates from Europe. The conference reviewed the supply picture in Western Canada and the U.S., the market outlook with special reference to the robust electricity and industrial market, the outlook on gas prices and how the recent high prices impact on gas producers, royalty owners, industrial process users, the expansion of frontier gas, and competing sources of electrical generation, mainly existing coal and nuclear plants. The focus of the discussions centered on the so-called '30 Tcf vision' the recent National Petroleum Council Study in the United States. Further integration of the US and Canadian gas industry, primarily in the area of gas supply, was predicted. Evidence for this integration is the tremendous expansion of the role of frontier gas supplies from the Gulf of Mexico, LNG and coal seam gas in the USA and from the Scotian Shelf, the Liard Valley, north of the sixtieth parallel, Alaska's North Slope and Canada's Mackenzie Delta, to meet North American market demand. A resurgence in the role of large companies was also predicted, displacing the variety of independents, large and small, that have sprung up during the past decade

Natural gas and local heat supply. Erdgas und Nahwaerme

Energy Technology Data Exchange (ETDEWEB)

Berge, W. (Gasversorgungsgesellschaft Filstal mbH (Germany, F.R.) Stadtwerke Goeppingen (Germany, F.R.))

Local heat supply consists of a thermal power station of a dual-purpose plant, a heat destribution system and the heating systems of the users. A combination of gas heat-pumps, cogeneration plant and gas turbine operated as basic load aggregates is a precondition for the flexible application of energy-saving though investment-intensive technologies. Several existing plants are described in order to explain the structure and functioning of various types of plants. (BWI).

Evaluation of Technical Feasibility of Homogeneous Charge Compression Ignition (HCCI) Engine Fueled with Hydrogen, Natural Gas, and DME

Energy Technology Data Exchange (ETDEWEB)

Pratapas, John; Mather, Daniel; Kozlovsky, Anton

2013-03-31

The objective of the proposed project was to confirm the feasibility of using blends of hydrogen and natural gas to improve the performance, efficiency, controllability and emissions of a homogeneous charge compression ignition (HCCI) engine. The project team utilized both engine simulation and laboratory testing to evaluate and optimize how blends of hydrogen and natural gas fuel might improve control of HCCI combustion. GTI utilized a state-of-the art single-cylinder engine test platform for the experimental work in the project. The testing was designed to evaluate the feasibility of extending the limits of HCCI engine performance (i.e., stable combustion, high efficiency and low emissions) on natural gas by using blends of natural gas and hydrogen. Early in the project Ricardo provided technical support to GTI as we applied their engine performance simulation program, WAVE, to our HCCI research engine. Modeling support was later provided by Digital Engines, LLC to use their proprietary model to predict peak pressures and temperatures for varying operating parameters included in the Design of Experiments test plan. Digital Engines also provided testing support for the hydrogen and natural gas blends. Prof. David Foster of University of Wisconsin-Madison participated early in the project by providing technical guidance on HCCI engine test plans and modeling requirements. The main purpose of the testing was to quantify the effects of hydrogen addition to natural gas HCCI. Directly comparing straight natural gas with the hydrogen enhanced test points is difficult due to the complexity of HCCI combustion. With the same air flow rate and lambda, the hydrogen enriched fuel mass flow rate is lower than the straight natural gas mass flow rate. However, the energy flow rate is higher for the hydrogen enriched fuel due to hydrogen’s significantly greater lower heating value, 120 mJ/kg for hydrogen compared to 45 mJ/kg for natural gas. With these caveats in mind, an

Hydrogen production by water dissociation using ceramic membranes - annual report for FY 2010.

Energy Technology Data Exchange (ETDEWEB)

Balachandran, U.; Dorris, S. E.; Emerson, J. E.; Lee, T. H.; Lu, Y.; Park, C. Y.; Picciolo, J. J. (Energy Systems)

2011-03-14

The objective of this project is to develop dense ceramic membranes that can produce hydrogen via coal/coal gas-assisted water dissociation without using an external power supply or circuitry. This project grew from an effort to develop a dense ceramic membrane for separating hydrogen from gas mixtures such as those generated during coal gasification, methane partial oxidation, and water-gas shift reactions. That effort led to the development of various cermet (i.e., ceramic/metal composite) membranes that enable hydrogen production by two methods. In one method, a hydrogen transport membrane (HTM) selectively removes hydrogen from a gas mixture by transporting it through either a mixed protonic/electronic conductor or a hydrogen transport metal. In the other method, an oxygen transport membrane (OTM) generates hydrogen mixed with steam by removing oxygen that is generated through water splitting. This project focuses on the development of OTMs that efficiently produce hydrogen via the dissociation of water. Supercritical boilers offer very high-pressure steam that can be decomposed to provide pure hydrogen using OTMs. Oxygen resulting from the dissociation of steam can be used for coal gasification, enriched combustion, or synthesis gas production. Hydrogen and sequestration-ready CO{sub 2} can be produced from coal and steam by using the membrane being developed in this project. Although hydrogen can also be generated by high-temperature steam electrolysis, producing hydrogen by water splitting with a mixed-conducting membrane requires no electric power or electrical circuitry.

Hydrogenation of cyclohexene with LaNi5−xAlxHn metal hydrides suspended in cyclohexane or ethanol

NARCIS (Netherlands)

Snijder, E.D.; Versteeg, G.F.; Swaaij, W.P.M. van

1993-01-01

The hydrogenation of cyclohexene on the metal hydride forming alloys LaNi4.8Al0.2, LaNi4.9Al0.1 and LaNi5, all suspended in cyclohexane and LaNi5 suspended in ethanol, has been investigated. Two sources for hydrogen are recognized: hydrogen supplied by the gas phase and hydrogen which is available

Hydrogenation of cyclohexene with LaNi@#5@#-@#x@#Al@#x@#Hn metal hydrides, suspended in cyclohexane or ethanol

NARCIS (Netherlands)

Snijder, E.D.; Snijder, E.D.; Versteeg, Geert; van Swaaij, Willibrordus Petrus Maria

1993-01-01

The hydrogenation of cyclohexene on the metal hydride forming alloys LaNi4.8Al0.2, LaNi4.9Al0.1 and LaNi5, all suspended in cyclohexane and LaNi5 suspended in ethanol, has been investigated. Two sources for hydrogen are recognized: hydrogen supplied by the gas phase and hydrogen which is available

Proceedings of a Canadian Hydrogen Association workshop in support of the transition to the hydrogen age : Greening the fleet : the status of hydrogen-powered vehicles for fleet applications

Energy Technology Data Exchange (ETDEWEB)

NONE

2007-07-01

The Canadian Hydrogen Association (CHA) endorses hydrogen as an energy carrier and promotes the development of a supporting hydrogen infrastructure. It promotes the research, development and commercialization of innovative ways to accelerate the application of hydrogen technologies to reduce greenhouse gas emissions. The presentations at this conference described new technologies and the companies that are developing hydrogen-powered vehicles, including hybrid-electric powered vehicles for fleet application. Some international activities were also covered, including lessons learned from the California experience and European fuel cell fleets. The benefits of fuel cell hybrids were highlighted along with methods to overcome the barriers to the introduction of new vehicle fuels. A review of current and future hydrogen supply infrastructure systems was also provided. The conference featured 14 presentations, of which 2 have been catalogued separately for inclusion in this database. refs., tabs., figs.

Simulating security of supply effects of the Nabucco and South Stream projects for the European natural gas market

Energy Technology Data Exchange (ETDEWEB)

Dieckhoener, Caroline

2010-12-15

Due to the increasing European import dependency, significant additional natural gas volumes will be required. In addition to the Nord Stream pipeline, the Nabucco and South Stream pipeline are projects planned for the next decade to provide further gas supplies to the European market. As one of the European Union's energy policies' foci is security of supply, the question can be raised if and how these projects contribute to this objective not only in terms of diversification but also in case of supply disruptions such as occurred in 2009 during the Russia-Ukraine gas crisis. This paper discusses the impact of these two major gas import pipeline projects on the South-Eastern Europe gas supply and analyzes their effects on gas flows and marginal cost prices in general and in case of gas supply disruptions via Ukraine in a model-based analysis with the European natural gas infrastructure and dispatch model TIGER. (orig.)

Long-term trends in US gas supply and prices: 1993 edition of the GRI baseline projection of US energy supply and demand to 2010

International Nuclear Information System (INIS)

Woods, T.J.

1993-03-01

A Summary of the gas supply outlook in the 1993 Edition of the GRI Baseline Projection of U.S. Energy Supply and Demand, adopted as a major input to the planning cycle of the 1994 research and development program, is presented. Significant changes were made in developing the gas supply and price trends for the 1993 edition of the projection. The GRI Hydrocarbon Model was expanded to include the Canadian hydrocarbon resource base. Thus, Canadian and lower-48 gas production and prices were developed on a fully integrated basis in the 1993 projection. The lower-48 hydrocarbon resource estimate was increased, reflecting the results of the recent National Petroleum Council gas study and ongoing GRI resource work. The effects of new technology and practice on drilling costs and exploration efficiency were included for the first time. Appendices include comparisons of supply and price trends

Sustainable supply of global energy needs and greenhouse gas reductions

International Nuclear Information System (INIS)

Miller, A.I.; Duffey, R.B.

2009-01-01

Nuclear plants emit virtually no greenhouse gases over their full life-cycle. Consequently, continued operation of existing nuclear plants is recognized as essential to meeting even the modest greenhouse gas reduction targets of the Kyoto Accord. However, much expanded nuclear deployment will be needed as developing economies aggressively grow GDP with its associated growth in electrical power. Projecting to 2040 and based on the scenarios of the United Nations Intergovernmental Panel on Climate Change's (IPCC), we have examined deploying increased non-carbon energy sources for electricity production, including further conversion of electricity to hydrogen using conventional low-temperature water electrolysis. Our NuWind model has been used to calculate the production costs for hydrogen in typical potential markets, using the actual prices of electricity paid by the Alberta Power Pool and by the Ontario Grid. The analysis shows clearly that by optimizing the co-production of hydrogen and electricity (referred to as the H2/e process) the cost for hydrogen produced can comfortably meet the US Department of Energy's target for realistic nuclear investment costs, hydrogen generation systems, and wind capacity factors. The synergy of nuclear plus wind power for hydrogen generation plus co-production of electricity improves the economics of harnessing wind energy to produce hydrogen. (author)

Role of sodium hydroxide in the production of hydrogen gas from the hydrothermal gasification of biomass

Energy Technology Data Exchange (ETDEWEB)

Onwudili, Jude A.; Williams, Paul T. [Energy and Resources Research Institute, University of Leeds, Leeds, LS2 9JT (United Kingdom)

2009-07-15

The role of sodium hydroxide as a promoter of hydrogen gas production during the hydrothermal gasification of glucose and other biomass samples has been investigated. Experiments were carried out in a batch reactor with glucose and also in the presence of the alkali from 200 C, 2 MPa to 450 C, 34 MPa at constant water loading. Without sodium hydroxide, glucose decomposed to produce mainly carbon dioxide, water, char and tar. Furfural, its derivatives and reaction products dominated the ethyl acetate extract of the water (organic fraction) at lower reaction conditions. This indicated that the dehydration of glucose to yield these products was unfavourable to hydrogen gas production. In the presence of sodium hydroxide however, glucose initially decomposed to form mostly alkylated and hydroxylated carbonyl compounds, whose further decomposition yielded hydrogen gas. It was observed that at 350 C, 21.5 MPa, half of the optimum hydrogen gas yield had formed and at 450 C, 34 MPa, more than 80 volume percent of the gaseous effluent was hydrogen gas, while the balance was hydrocarbon gases, mostly methane ({>=}10 volume percent). Other biomass samples were also comparably reacted at the optimum conditions observed for glucose. The rate of hydrogen production for the biomass samples was in the following order; glucose > cellulose, starch, rice straw > potato > rice husk. (author)

Biogas supply to the natural gas supply grid. Study; Einspeisung von Biogas in das Erdgasnetz. Studie

Energy Technology Data Exchange (ETDEWEB)

Klinski, S. [DBI Gas- und Umwelttechnik GmbH, Leipzig (Germany)

2006-07-01

Biogas supply to the public gas grid is a new option discussed in the most recent publication of Fachagentur Nachwachsende Rohstoffe (FNR) e.V. The biogas is purified, upgraded to natural gas quality and fed into an existing gas grid. Once there, it can be transported across long distances and also used for electric power generation at the consumer side. The study investigates inhowfar and in what instances this method is feasible and promising. It discusses the technical background and the regional potential of biogas. Seven model biogas systems are presented as examples. (orig.)

The effect of hydrogen enrichment towards the flammability limits of natural gas in conventional combustion

International Nuclear Information System (INIS)

Izirwan Izhab; Nur Syuhada Mohd Shokri; Nurul Saadah Sulaiman; Mohd Zulkifli Mohamad Noor; Siti Zubaidah Sulaiman; Rosmawati Naim; Norida Ridzuan, Mohd Masri Razak; Abdul Halim Abdul Razik; Zulkafli Hassan

2010-01-01

The use of hydrogenated fuels shows a considerable promise for the applications in gas turbines and internal combustion engines. The aims of this study are to determine the flammability limits of natural gas/ air mixtures and to investigate the effect of hydrogen enrichment on the flammability limits of natural gas/ air mixtures up to 60 vol % of hydrogen/fuel volume ratio at atmospheric pressure and ambient temperature. The experiments were performed in a 20 L closed explosion vessel where the mixtures were ignited by using a spark permanent wire that was placed at the centre of the vessel. The pressure-time variations during explosions of natural gas/ air mixtures in an explosion vessel were recorded. Moreover, the explosion pressure data is used to determine the flammability limits that flame propagation is considered to occur if explosion pressure is greater than 0.1 bar. Therefore, in this study, the results show that the range of flammability limits are from 6 vol % to 15 vol % and by the addition of hydrogen in natural gas proved to extend the initial lower flammability limit of 6 vol % to 2 vol % of methane. (author)

Liberalisation and the security of gas supply in the UK

International Nuclear Information System (INIS)

Wright, Philip

2005-01-01

This paper contests the view held by the current UK government and its industry regulator, OFGEM, that liberalisation is good for security of supply. Focusing on the downstream aspects of the security of UK gas supply, on system security, it considers the impact of the different aspects of liberalisation: of legal governance, supply competition, de-integration, market simulation, regulation and the interaction of liberalised gas and electricity markets. Categorising these impacts in terms of security threats and threats to security response, it finds that individually and as a complex collectivity they have increased the risks of supply failure, either potential or already realised, in a variety of ways: from creating increased uncertainty and failing to signal adequate or appropriate investment, to legal ambiguity which divorces responsibility from liability and renders legal liability indeterminate ex ante. Moreover, one of the UK government's responses to these increased dangers, which it does appear to perceive, is revealed as itself paralysed by the liberalisation paradigm: the government can only intervene pre-emptively with information in attempt to persuade the market to behave as it thinks it should. Meanwhile, however, the government has also had to recognise its default responsibility for security of supply and make preparations to intervene in an emergency situation: liberalisation can only be challenged when it is already too late

Gas--liquid equilibria in mixtures of hydrogen and thianaphthene

Energy Technology Data Exchange (ETDEWEB)

Sebastian, H M; Simnick, J J; Lin, H M; Chao, K C

1978-12-01

Gas--liquid equilibrium conditions in binary mixtures of hydrogen and thianaphthene were experimentally determined at temperature of 190 to 430/sup 0/C and pressures to 250 atm in a flow apparatus. The same apparatus was also employed to measure the vapor pressure of thianaphthene. Comparisons of the new mixture data with Chao--Seader and Grayson--Streed correlations show that both correlations predict the thianaphthene equilibrium ratios well but are in error by up to about 45 and 35% respectively for K-values of hydrogen. 4 figures, 2 tables.

Hydrogen Gas Sensing Characteristics of Nanostructured NiO Thin Films Synthesized by SILAR Method